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Sample records for industrial scale coal

  1. Statistical modeling of spontaneous combustion in industrial-scale coal stockpiles

    SciTech Connect

    Ozdeniz, H

    2009-07-01

    Companies consuming large amounts of coal should work with coal stocks in order to not face problems due to production delays. The industrial-scale stockpiles formed for the aforementioned reasons cause environmental problems and economic losses for the companies. This study was performed in a coal stock area of a large company in Konya, which uses large amounts of coal in its manufacturing units. The coal stockpile with 5 m width, 10 m length, 3 m height, and having 120 tons of weight was formed in the coal stock area of the company. The inner temperature data of the stockpile was recorded by 17 temperature sensors placed inside the stockpile at certain points. Additionally, the data relating to the air temperature, air humidity, atmospheric pressure, wind velocity, and wind direction that are the parameters affecting the coal stockpile were also recorded. A statistical model applicable for a spontaneous combustion event was developed during this study after applying multi-regression analyses to the data recorded in the stockpile during the spontaneous combustion event. The correlation coefficients obtained by the developed statistical model were measured approximately at a 0.95 level. Thus, the prediction of temperature variations influential in the spontaneous combustion event of the industrial-scale coal stockpiles will be possible.

  2. Compare pilot-scale and industry-scale models of pulverized coal combustion in an ironmaking blast furnace

    NASA Astrophysics Data System (ADS)

    Shen, Yansong; Yu, Aibing; Zulli, Paul

    2013-07-01

    In order to understand the complex phenomena of pulverized coal injection (PCI) process in blast furnace (BF), mathematical models have been developed at different scales: pilot-scale model of coal combustion and industry-scale model (in-furnace model) of coal/coke combustion in a real BF respectively. This paper compares these PCI models in aspects of model developments and model capability. The model development is discussed in terms of model formulation, their new features and geometry/regions considered. The model capability is then discussed in terms of main findings followed by the model evaluation on their advantages and limitations. It is indicated that these PCI models are all able to describe PCI operation qualitatively. The in-furnace model is more reliable for simulating in-furnace phenomena of PCI operation qualitatively and quantitatively. These models are useful for understanding the flow-thermo-chemical behaviors and then optimizing the PCI operation in practice.

  3. Coal industry annual 1997

    SciTech Connect

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  4. Coal industry annual 1996

    SciTech Connect

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  5. Coal Industry Annual 1995

    SciTech Connect

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  6. Coal industry annual 1993

    SciTech Connect

    Not Available

    1994-12-06

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  7. Development and Testing of Industrial Scale Coal Fired Combustion System, Phase 3

    SciTech Connect

    Bert Zauderer

    1998-09-30

    Coal Tech Corp's mission is to develop, license & sell innovative, lowest cost, solid fuel fired power systems & total emission control processes using proprietary and patented technology for domestic and international markets. The present project 'DEVELOPMENT & TESTING OF INDUSTRIAL SCALE, COAL FIRED COMBUSTION SYSTEM, PHASE 3' on DOE Contract DE-AC22-91PC91162 was a key element in achieving this objective. The project consisted of five tasks that were divided into three phases. The first phase, 'Optimization of First Generation 20 MMBtu/hr Air-Cooled Slagging Coal Tech Combustor', consisted of three tasks, which are detailed in Appendix 'A' of this report. They were implemented in 1992 and 1993 at the first generation, 20 MMBtu/hour, combustor-boiler test site in Williamsport, PA. It consisted of substantial combustor modifications and coal-fired tests designed to improve the combustor's wall cooling, slag and ash management, automating of its operation, and correcting severe deficiencies in the coal feeding to the combustor. The need for these changes was indicated during the prior 900-hour test effort on this combustor that was conducted as part of the DOE Clean Coal Program. A combination of combustor changes, auxiliary equipment changes, sophisticated multi-dimensional combustion analysis, computer controlled automation, and series of single and double day shift tests totaling about 300 hours, either resolved these operational issues or indicated that further corrective changes were needed in the combustor design. The key result from both analyses and tests was that the combustor must be substantially lengthened to maximize combustion efficiency and sharply increase slag retention in the combustor. A measure of the success of these modifications was realized in the third phase of this project, consisting of task 5 entitled: 'Site Demonstration with the Second Generation 20 MMBtu/hr Air-Cooled Slagging Coal Tech Combustor'. The details of the task 5 effort are

  8. Artificial neural network modeling of the spontaneous combustion occurring in the industrial-scale coal stockpiles with 10-18 mm coal grain sizes

    SciTech Connect

    Ozdeniz, A.H.; Yilmaz, N.

    2009-07-01

    Companies consuming large amounts of coal should work with coal stocks in order to not face problems due to production delays. The industrial-scale stockpiles formed for the aforementioned reasons cause environmental problems and economic losses for the companies. This study was performed in a coal stock area of a large company in Konya, which uses large amounts of coal in its manufacturing units. The coal stockpile with 5 m width, 10 m length, 3 m height, and having 120 tons of weight was formed in the coal stock area of the company. The inner temperature data of the stockpile was recorded by 17 temperature sensors placed inside the stockpile at certain points. In order to achieve this goal, the electrical signal conversion of temperatures sensed by 17 temperature sensors placed in certain points inside the coal stockpile, the transfer of these electrical signals into computer media by using analog-digital conversion unit after applying necessary filtration and upgrading processes, and the record of these information into a database in particular time intervals are provided. Additionally, the data relating to the air temperature, air humidity, atmospheric pressure, wind velocity, and wind direction that are the parameters affecting the coal stockpile were also recorded. Afterwards, these measurement values were used for training and testing of an artificial neural network model. Comparison of the experimental and artificial neural network results, accuracy rates of training and testing were found to be 99.5% and 99.17%, respectively. It is shown that possible coal stockpile behavior with this artificial neural network model is powerfully estimated.

  9. Baseload, industrial-scale wind power: An alternative to coal in China

    SciTech Connect

    Lew, D.J.; Williams, R.H.; Xie Shaoxiong; Zhang Shihui

    1996-12-31

    This report presents a novel strategy for developing wind power on an industrial-scale in China. Oversized wind farms, large-scale electrical storage and long-distance transmission lines are integrated to deliver {open_quotes}baseload wind power{close_quotes} to distant electricity demand centers. The prospective costs for this approach to developing wind power are illustrated by modeling an oversized wind farm at Huitengxile, Inner Mongolia. Although storage adds to the total capital investment, it does not necessarily increase the cost of the delivered electricity. Storage makes it possible to increase the capacity factor of the electric transmission system, so that the unit cost for long-distance transmission is reduced. Moreover, baseload wind power is typically more valuable to the electric utility than intermittent wind power, so that storage can be economically attractive even in instances where the cost per kWh is somewhat higher than without storage. 9 refs., 3 figs., 2 tabs.

  10. Industrial- and utility-scale coal-water fuel demonstration projects

    SciTech Connect

    Hathi, V.; Ramezan, M.; Winslow, J.

    1993-01-01

    Laboratory-, pilot-, and large-scale CWF combustion work has been performed primarily in Canada, China, Italy, Japan, Korea, Sweden, and the United States, and several projects are still active. Sponsors have included governments, utilities and their research arms, engine manufacturers, equipment suppliers, and other organizations in attempts to show that CWF is a viable alternative to premium fuels, both in cost and performance. The objective of this report is to present brief summaries of past and current industrial- and utility-scale CWF demonstrations in order to determine what lessons can be learned from these important, highly visible projects directed toward the production of steam and electricity. Particular emphasis is placed on identifying the CWF characteristics; boiler type, geometry, size, and location; length of the combustion tests; and the results concerning system performance, including emissions.

  11. Development and Testing of Industrial Scale, Coal-Fired Combustion System: Phase 3.

    SciTech Connect

    Zauderer, B.

    1997-04-21

    In the first quarter of calendar year 1997, 17 days of combustor- boiler tests were performed, including one day of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days required to meet the task 5 project plan. The key project objectives in the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NO{sub x} emissions as low as 0.07 lb/MMBtu and SO{sub 2} emissions as low as 0.2 lb/MMBtu have been measured in tests in this quarter. Tests in the present quarter have resulted in further optimizing the sorbent injection and NO{sub x} control processes. A very important milestone in this quarter was two successful combustor tests on a very high ash (37%) Indian coal. Work in the next quarter will focus on commercialization of the combustor- boiler system. In addition, further tests of the NO{sub x} and SO{sub 2} control process and on the Indian coal will be performed.

  12. Coal conversion products industrial applications

    NASA Technical Reports Server (NTRS)

    Dunkin, J. H.; Warren, D.

    1980-01-01

    Coal-based synthetic fuels complexes under development consideration by NASA/MSFC will produce large quantities of synthetic fuels, primarily medium BTU gas, which could be sold commercially to industries located in South Central Tennessee and Northern Alabama. The complexes would be modular in construction, and subsequent modules may produce liquid fuels or fuels for electric power production. Current and projected industries in the two states which have a propensity for utilizing coal-based synthetic fuels were identified, and a data base was compiled to support MFSC activities.

  13. Development and testing of industrial scale, coal fired combustion system: Phase 3, Progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Zauderer, B.

    1995-10-12

    The primary objective of the present Phase 3 effort is to perform the final testing, at a 20 MMBtu/hr commercial scale, of an air cooled, slagging coal combustor for application to industrial steam boilers and power plants. The focus of the test effort is on combustor durability, automatic control of the combustor`s operation, and optimum environmental control of emissions inside the combustor. In connection with the latter, the goal is to achieve 0.4lb/MMBtu of SO{sub 2} emissions, 0.2 lb./MMBtu of NO{sub x}, emissions, and 0.02 lb. particulates/MMBtu. To meet the particulate goal a baghouse will be used to augment the slag retention in the combustor. The NO{sub x} emission goal will require a modest improvement over maximum reduction achieved to date in the combustor to a level of 0.26 lb. /MMBtu. To reach the SO{sub 2} emissions goal may require a combination of sorbent injection inside the combustor and sorbent injection inside the boiler, or stack. In the third quarter of calendar year 1995 work continued on task 5, ``Site Demonstration``, with emphasis on installation of the 20 MMBtu/hr combustor and auxiliary equipment at the Philadelphia test site. The task 5 effort involve testing the combustor over extended periods under conditions that fully simulate commercial operation and that meet the combustion and environmental specifications for this project. During the present quarterly reporting period, over 90% of the components needed to implement the initial 100 hours of testing were installed at the test site.

  14. Environmental protecting effect of industrial coal briquette

    SciTech Connect

    Zhao, Y.; Chen, L.

    1999-07-01

    This paper has analyzed the necessity of developing industrial coal briquette in China and introduced the present development of coal briquette and its environmental protecting effect in the country. The laboratory research shows that the rate of captured sulfur of coal briquette produced with calcium oxide as a capturing agent is up to 82%. Comparing with the combustion of raw coal, coal briquette produced in briquette cohesive agent made of magnesium oxide etc, can reduce the amount of sulfur dioxide by 78% and the amount of dust smoke by 29.3% when the coal briquette is burned in industrial boiler. When it is used as raw material of coal gasification, the amount of hydrogen sulfide in the gas generated by the gasification of mixed coal composed of 25% coal briquette and 75% lumps is lowered by 6.8% (volume ration) compared with that generated by the gasification of full lumps. Moreover, the sodium sulfocyanide is discovered in the boiler ashes and the amount of sodium sulfocyanide is up to 10% of the total (weight ration) when the boiler ashes are tested with x-ray diffractometer. The discovery shows that the coal briquette has the function of nitrogen fixation. The rate of captured sulfur of coal briquette which is briquetting at the front of industrial boiler and in which limestone is used as a capturing agent is up to 48% when it is burned in industrial boiler.

  15. Coal conversion products Industrial applications

    NASA Technical Reports Server (NTRS)

    Warren, D.; Dunkin, J.

    1980-01-01

    The synfuels economic evaluation model was utilized to analyze cost and product economics of the TVA coal conversion facilities. It is concluded that; (1) moderate yearly future escalations ( 6%) in current natural gas prices will result in medium-Btu gas becoming competitive with natural gas at the plant boundary; (2) utilizing DRI price projections, the alternate synfuel products, except for electricity, will be competitive with their counterparts; (3) central site fuel cell generation of electricity, utilizing MBG, is economically less attractive than the other synthetic fuels, given projected price rises in electricity produced by other means; and (4) because of estimated northern Alabama synfuels market demands, existing conventional fuels, infrastructure and industrial synfuels retrofit problems, a diversity of transportable synfuels products should be produced by the conversion facility.

  16. Continuing consolidation in the coal industry

    SciTech Connect

    Gaalaas, T.

    2006-08-15

    Extensive consolidation has occurred in the coal industry over the past decade. The greatest degree of consolidation has occurred in Northern Appalachia, the Illinois Basin, and the Wyoming portion of the Powder River Basin (PRB), which are the coal supply regions where most observers expect the greatest growth in coal production over the next decade. In addition to reducing the number of alternative suppliers, high level of concentration also tend to result in higher prices, more volatile spot markets, and lower levels of reliability. Therefore, coal-fired generators purchasing in these regions need to respond proactively and strategically to these market trends. 2 figs.

  17. Industrial unionism and the Oklahoma coal industry, 1870-1935

    SciTech Connect

    Sewall, S.L.

    1992-01-01

    This study traces the development of industrial unionism in Oklahoma's coal industry from the beginnings of the industry in 1870 to its decline in 1935. Chapter topics include the early years of the coal industry, life in the coal towns, and the series of strikes that occurred from 1894 to 1932. The study draws from both labor and management materials, but also from primary sources that reflect the role of both the state and federal governments during strikes. The study also utilizes the newspapers of the coal towns. They are a bountiful source on life in Oklahoma's coal towns. Study concludes that Oklahoma's coal towns were a perfect breeding ground for industrial unionism. Working in the most dangerous mines in the United States, the miners of Oklahoma turned to unionism in their efforts to improve working conditions and to secure a living wage. Above ground, the miners battled to break the company towns system. There the union achieved success in eliminating the company store and company housing, the two principal components of the company town system. At the same time, the miners created a union culture under which miners of all nationalities were welcome.

  18. 1982-1983 world coal industry report and directory

    SciTech Connect

    Not Available

    1982-01-01

    The coal industry in Australia, Canada, China, West Germany, India, Poland, South Africa, the USSR, England, and the United States are reported. The directory listings for each country are a compilation of information from government ministries, coal boards, bureaus of mines, and individual coal mining companies. More than 100 individual coal mines are listed, along with such information as coal seam thickness, coal analysis, and major equipment. (JMT)

  19. Status and outlook of industrial coal briquetting technology in China

    SciTech Connect

    Liu, S.; Xu, Z.; Li, W.; Tian, B.

    1997-12-31

    Considering that the lump coal supply falls short of demands, great amounts of fine coal and slime are stockpiled, waste energy is extensive, and environmental pollution is serious, this paper summarizes the present situation of industrial coal briquetting technologies and their applications, and evaluates the advantages and disadvantages of several different coal briquette technologies widely used. The authors think that the energetic development of industrial coal briquetting technology is an effective and feasible option to fully utilize fine coal and slime, mitigate the contradiction between supply and demand for lump coal, reduce the production cost of users, as well as decrease and control environmental pollution caused by coal utilization. It is a practical solution for clean coal in China. At present, the research for developing industrial coal briquetting technologies is in the selection and adoption of suitable binders which need dry processing and can produce high strength and waterproof briquettes.

  20. Small Scale Industries.

    ERIC Educational Resources Information Center

    Rural Development Detwork Bulletin, 1977

    1977-01-01

    Innovative programs for the promotion of small-scale enterprise are being conducted by a variety of organizations, including universities, government agencies, international research institutes, and voluntary assistance agencies. Their activities encompass basic extension services, management of cooperatives, community action programs, and…

  1. Development and testing of industrial scale, coal fired combustion system, Phase 3. Fifth quarterly technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Zauderer, B.

    1993-05-17

    In the present reporting period, the first quarter of calendar year 1993, the effort was divided between Task 2. ``Pre Systems Tests`` and Task 4 ``Economics and Commercialization Plan.`` A major part of the task 2 effort was devoted converting the nozzle from adiabatic to air cooted operation. This conversion will allow immediate implementation of the longer duration task 3.2 tests after the completion of the task 2 tests. Therefore, a significant pan of the exit nozzle conversion effort is also part of task 3.1, ``Combustor Refurbishment.`` In task 1 the only activity remaining is to receive the results of the BYU combustion modeling. The results are anticipated this Spring. One of the three remaining tests in task 2 was implemented in late January under freezing weather and snow conditions. Ice plugged the coal feed lines and stack scrubber water outlet and ice jammed and damaged the coal metering auger. While these lines were thawed, the combustor was fired with oil. The coal used in this test contained fine fibrous tramp material which passed through the two tramp material retaining screens and eventually plugged several of the coal feed lines to the combustor. This cut the planned coal feed rate in half. As a result it was decided for the next test to increase the number of coal injection ports by 50% in order to provide excess capacity in the pneumatic feed feed. This will allow continued operation even in the presence of fine tramp material in the coal.

  2. Elevation (typical EBT Coal Hopper Car) with scale. 3 Bay ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Elevation (typical EBT Coal Hopper Car) with scale. 3 Bay Steel Hopper Car with side extensions raising coal carrying capacity to 80,000 pounds. Note cars on either side lack extensions limiting their coal capacity to 70,000 pounds - East Broad Top Railroad & Coal Company, State Route 994, West of U.S. Route 522, Rockhill Furnace, Huntingdon County, PA

  3. Development and testing of industrial scale coal fired combustion systems, Phase 3. Sixth quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Zauderer, B.

    1993-09-22

    The most significant effort in the quarter was the completion of the conversion of the exit nozzle from adiabatic operation to air cooled operation. This conversion was implemented midway in the task 2 test effort, and the final two tests in task 2 were with the cooled nozzle. It performed as per design. The second significant result was the successful implementation of a computer controlled combustor wall cooling procedure. The hot side combustor liner temperature can now be maintained within a narrow range of less than 5OF at the nominal wall temperature of 2000F. This is an essential requirement for long term durability of the combustor wall. The first tests with the computer control system were implemented in June 1993. A third development in this period was the decision to replace the coal feeder that had been in use since coal fired operation began in late 1987. Since that time, this commercial device has been modified numerous times in order to achieve uniform coal feed. Uniform feed was achieved in 1991. However, the feeder operation was not sufficiently reliable for commercial use. The new feeder has the same design as the sorbent feeders that have been successfully used since 1987. This design has much better speed control and it can be rapidly restarted when the feed auger becomes jammed with tramp material. The last task 2 test was a long duration coal fired test with almost 12 hours of coal fired operation until the 4 ton coal bin was empty. It was the longest coal firing period of the task 2 tests. The exit nozzle cooling maintained the wall temperature in the desired operating range.

  4. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  5. Coking partially briquetted coal charge under industrial conditions

    SciTech Connect

    Sukhorukov, V.I.; Bezdvernyi, G.N.; Kopeliovich, L.V.; Mishchikhin, V.G.; Berkutov, A.N.; Stepanov, Y.; Abramicheva, A.I.; Topchii, M.P.

    1982-01-01

    The partial briquetting of low grade coals ordinarily unsuitable for coking, has been found to allow use of these materials in the coking process under industrial conditions, with an improvement in coke quality. Coke oven capacity is increased. The binder used is medium temperature coal tar.

  6. PROSPECTS FOR INCREASING THE DIRECT USE OF COAL IN INDUSTRIAL BOILERS

    EPA Science Inventory

    The report gives a comprehensive evaluation of factors (environmental, technical, economic, and institutional) influencing solid coal use in industrial boilers. Trends in coal use, recent legislative warrants, and technical and logistic problems in coal use at industrial plants a...

  7. SOURCE ASSESSMENT: DRY BOTTOM INDUSTRIAL BOILERS FIRING PULVERIZED BITUMINOUS COAL

    EPA Science Inventory

    The report describes and assesses the potential impact of air emissions, wastewater effluents, and solid wastes from the operation of dry bottom industrial boilers firing pulverized bituminous coal. Air emissions were characterized by a literature survey and field sampling. Signi...

  8. Commissioning an Engineering Scale Coal Gasifier

    SciTech Connect

    Reid, Douglas J.; Bearden, Mark D.; Cabe, James E.

    2010-07-01

    This report explains the development, commissioning, and testing of an engineering scale slagging coal gasifier at PNNL. The initial objective of this project was to commission the gasifier with zero safety incidents. The commissioning work was primarily an empirical study that required an engineering design approach. After bringing the gasifier on-line, tests were conducted to assess the impact of various operating parameters on the synthesis gas (syngas) product composition. The long-term intent of this project is to produce syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in catalyst, materials, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for greater than 4 hours using coal feedstock. In addition, alternate designs that allow for increased flexibility regarding the fuel sources that can be used for syngas production is desired. Continued modifications to the fuel feed system will be pursued to address these goals. Alternative feed mechanisms such as a coal/methanol slurry are being considered.

  9. Preliminary assessment of coal-based industrial energy systems

    SciTech Connect

    Not Available

    1980-01-01

    This report presents the results of a study, performed by Mittelhauser Corp. and Resource Engineering, Inc. to identify the potential economic, environmental, and energy impacts of possible New Source Performance Standards for industrial steam generators on the use of coal and coal-derived fuels. A systems-level approach was used to take mine-mouth coal and produce a given quantity of heat input to a new boiler at an existing Chicago industrial-plant site. The technologies studied included post-combustion clean-up, atmospheric fluidized-bed combustion, solvent-refined coal liquids, substitute natural gas, and low-Btu gas. Capital and operating costs were prepared on a mid-1985 basis from a consistent set of economic guidelines. The cases studied were evaluated using three levels of air emission controls, two coals, two boiler sizes, and two operating factors. Only those combinations considered likely to make a significant impact on the 1985 boiler population were considered. The conclusions drawn in the report are that the most attractive applications of coal technology are atmospheric fluidized-bed combustion and post-combustion clean-up. Solvent-refined coal and probably substitute natural gas become competitive for the smaller boiler applications. Coal-derived low-Btu gas was found not to be a competitive boiler fuel at the sizes studied. It is recommended that more cases be studied to broaden the applicability of these results.

  10. Digging Deeper: Crisis Management in the Coal Industry

    ERIC Educational Resources Information Center

    Miller, Barbara M.; Horsley, J. Suzanne

    2009-01-01

    This study explores crisis management/communication practices within the coal industry through the lens of high reliability organization (HRO) concepts and sensemaking theory. In-depth interviews with industry executives and an analysis of an emergency procedures manual were used to provide an exploratory examination of the status of crisis…

  11. Coal combustion: Science and technology of industrial and utility applications

    SciTech Connect

    Feng, J.

    1988-01-01

    Despite the competition of oil and gas and the increasing importance of nuclear power, coal is still one of the main sources of energy in the world. In some regions of the world, the reserve of oil and natural gas is nearly depleted. The supply of such fuels relies on shipment from foreign countries, and may be vulnerable to political crisis, while coals are still abundant and easily available. Therefore, the technology of burning coal for energy, which seems rather old, has not lost its vitality and is in fact developing fast. Because of industry development, especially in developing countries, more and more coal is burned each year. If coal is not burned properly, it may pollute the environment and affect the ecological balance of the surrounding regions. Great attention has been paid to curb these issues, and significant progress has been achieved. Technology of desulfurization of flue gases, low nitrogen oxide coal burners, and also the technology of clean burning of coal by fluidized-bed combustion have all been developed and commercialized. Further improvements are under development. At the same time, new techniques have been used in the measurements and diagnoses of coal combustion. These new techniques facilitate more efficient and cleaner burning of coal. Although coal combustion is a very complicated physiochemical phenomenon, the use of the computer enables and pushes forward the theoretical analysis of coal combustion. Besides, the mathematical modelling of the coal combustion process is also a fast progressing field of research and encouraging results have been obtained by scientists throughout the world. This book compiles the papers presented in the conference on the subject of clean cool technology and fluidized-bed combustion.

  12. Development and testing of industrial scale, coal fired combustion system, Phase 3. Third quarterly technical progress report, July 1, 1992--September 30, 1992

    SciTech Connect

    Zauderer, B.

    1992-10-17

    In the third quarter of calendar year 1992, work continued on Task l. ``Design, Installation, and Shakedown of the Modifications to the 20 MMBtu/hr Air Cooled Combustor and Boiler Components``. Task 2. ``Preliminary Systems Tests`` and Task 4 ``Economics and Commercialization Plan``. In task 1, the design of the planned modifications were mostly completed. The equipment to implement these modifications was procured, and most of the installation of this equipment was completed. Finally, a series of two shakedown tests was performed to test the operability of these modifications. As previously reported, no modifications to the combustor were made. All the changes were improvements in overall combustor-boiler operation, maintenance and repair of components, and addition of diagnostics. In addition, during shakedown tests of these modifications the need for additional improvements or modifications became apparent, and these were or a-re being implemented. The major improvements focused on coal and sorbent storage, transport, and combustor injection, real time control of ash deposition in the boiler, unproved combustor wall cooling, expanded computer control and diagnostics, and refurbishment of the scrubber and combustor temperature measurements. AD this work has been described in a detailed topical report on task 1, which was recently submitted to DOE, and it will not be repeated here. Instead the focus of this report will be on the analysis of the test results obtained in the two shakedown tests. This work was partly reported in the 7th 8th and 9th monthly reports. An important result of these tests has been the observation of high (over 85%) SO{sub 2} reduction obtained with sorbent injection in the combustor.

  13. Coal.

    ERIC Educational Resources Information Center

    Brant, Russell A.; Glass, Gary B.

    1983-01-01

    Principle work of 23 state geological surveys is summarized. Work includes mapping/estimating coal resources, centralizing data in National Coal Resources Data System through cooperative programs, exploration drilling, and others. Comments on U.S. Geological Survey activities, coal-related conferences/meetings, and industry research activities are…

  14. Managing Scarce Water Resources in China's Coal Power Industry.

    PubMed

    Zhang, Chao; Zhong, Lijin; Fu, Xiaotian; Zhao, Zhongnan

    2016-06-01

    Coal power generation capacity is expanding rapidly in the arid northwest regions in China. Its impact on water resources is attracting growing concerns from policy-makers, researchers, as well as mass media. This paper briefly describes the situation of electricity-water conflict in China and provides a comprehensive review on a variety of water resources management policies in China's coal power industry. These policies range from mandatory regulations to incentive-based instruments, covering water withdrawal standards, technological requirements on water saving, unconventional water resources utilization (such as reclaimed municipal wastewater, seawater, and mine water), water resources fee, and water permit transfer. Implementing these policies jointly is of crucial importance for alleviating the water stress from the expanding coal power industry in China. PMID:26908125

  15. Managing Scarce Water Resources in China's Coal Power Industry

    NASA Astrophysics Data System (ADS)

    Zhang, Chao; Zhong, Lijin; Fu, Xiaotian; Zhao, Zhongnan

    2016-06-01

    Coal power generation capacity is expanding rapidly in the arid northwest regions in China. Its impact on water resources is attracting growing concerns from policy-makers, researchers, as well as mass media. This paper briefly describes the situation of electricity-water conflict in China and provides a comprehensive review on a variety of water resources management policies in China's coal power industry. These policies range from mandatory regulations to incentive-based instruments, covering water withdrawal standards, technological requirements on water saving, unconventional water resources utilization (such as reclaimed municipal wastewater, seawater, and mine water), water resources fee, and water permit transfer. Implementing these policies jointly is of crucial importance for alleviating the water stress from the expanding coal power industry in China.

  16. Industry Wage Survey: Bituminous Coal, January 1976-March 1981.

    ERIC Educational Resources Information Center

    Bush, Joseph C.

    Production and related workers in the nation's bituminous coal mines averaged $6.94 an hour in January 1976, which represents an increase of 110% since the Bureau of Labor Statistics' 1967 survey in the industry. Over the same period, the Hourly Earnings Index rose by 84% for private nonagricultural workers. Earnings for most of the 128,390…

  17. New petrochemical compositions for use in the coal industry

    SciTech Connect

    D.O. Safieva; E.V. Surov; O.G. Safiev

    2008-12-15

    Various aspects of the use of antifreezing agents in the coal industry are considered. It has been found that, unlike previously proposed compositions, these agents can be prepared based on the products of a single process, the vacuum distillation of fuel oil.

  18. EVALUATION OF LOW EMISSION COAL BURNER TECHNOLOGY ON INDUSTRIAL BOILERS

    EPA Science Inventory

    The report summarizes the second year's effort under EPA Contract 68-02-3127. The objective of the program is to conduct field evaluations of the distributed mixing burner (DMB) on two industrial size boilers. The DMB concept provides for controlled mixing of coal with combustion...

  19. Early opportunities of CO₂ geological storage deployment in coal chemical industry in China

    DOE PAGESBeta

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, R. T.; Davidson, C. L.

    2014-12-31

    Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO₂ emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO₂ sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation. These emission sources together emit 430 million tons CO₂more » per year, of which about 30% are emit high-purity and pure CO₂ (CO₂ concentration >80% and >98.5% respectively). Four typical source-sink pairs are chosen for techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO₂ capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO₂. When a 15USD/t CO₂ tax and 20USD/t for CO₂ sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.« less

  20. Early opportunities of CO₂ geological storage deployment in coal chemical industry in China

    SciTech Connect

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, R. T.; Davidson, C. L.

    2014-12-31

    Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO₂ emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO₂ sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation. These emission sources together emit 430 million tons CO₂ per year, of which about 30% are emit high-purity and pure CO₂ (CO₂ concentration >80% and >98.5% respectively). Four typical source-sink pairs are chosen for techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO₂ capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO₂. When a 15USD/t CO₂ tax and 20USD/t for CO₂ sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.

  1. Possibilities for dry adsorption of hydrocarbons in the coal industry

    SciTech Connect

    Peukert, W.

    1995-12-31

    For coal burning and gasification mostly inorganic waste gases like SO{sub 2}, NO{sub x}, H{sub 2}S, COS and others are relevant as emissions. During coal hydrogenation and pyrolysis substantial concentration of solid, liquid or gaseous hydrocarbons are generated besides other pollutants. The hydrocarbons may cover a wide range of different components with boiling points ranging from below {minus}100 C up to 600 C. Among the most dangerous species are polyaromatic hydrocarbons (PAH) with carcinogenic potential. The amount and composition of the hydrocarbons depend on the process under consideration. This paper describes both fundamentals and possibilities for dry collection of hydrocarbons in the coal industry. The evaluation of these processes require sophisticated measurement techniques for determination of gaseous components (e.g. GC-analysis) and modern techniques for characterization of adsorption processes of multi-component gas mixtures. Examples of realized fume treatment systems are given for anode baking systems and coke ovens.

  2. Development program to support industrial coal gasification. Quarterly report 1

    SciTech Connect

    1982-01-15

    The Development Program to Support Industrial Coal Gasification is on schedule. The efforts have centered on collecting background information and data, planning, and getting the experimental program underway. The three principal objectives in Task I-A were accomplished. The technical literature was reviewed, the coals and binders to be employed were selected, and tests and testing equipment to be used in evaluating agglomerates were developed. The entire Erie Mining facility design was reviewed and a large portion of the fluidized-bed coal gasification plant design was completed. Much of the work in Task I will be experimental. Wafer-briquette and roll-briquette screening tests will be performed. In Task II, work on the fluidized-bed gasification plant design will be completed and work on a plant design involving entrained-flow gasifiers will be initiated.

  3. Wood/coal cofiring in industrial stoker boilers

    SciTech Connect

    Cobb, J.T. Jr.; Elder, W.W.; Freeman, M.C.

    1999-07-01

    Realizing that a significant reduction in the global emissions of fossil carbon dioxide may require the installation of a wide variety of control technologies, options for large and small boilers are receiving attention. With over 1,500 coal-fired stoker boilers in the US, biomass co-firing is of interest, which would also open markets for waste wood which is presently landfilled at significant costs ranging from $20--200/ton. While much cofiring occurs inside the fence, where industrial firms burn wastes in their site boilers, other opportunities exist. Emphasis has been placed on stoker boilers in the northeastern US, where abundant supplies of urban wood waste are generally known to exist. Broken pallets form a significant fraction of this waste. In 1997, the cofiring of a volumetric mixture of 30% ground broken pallet material and 70% coal was demonstrated successfully at the traveling-grate stoker boilerplant of the Pittsburgh Brewing Company. Fourteen test periods, with various wood/coal mixtures blended on site, and two extended test periods, using wood/coal mixtures blended at the coal terminal and transported by truck to the brewery, were conducted. The 30% wood/70% coal fuel was conveyed through the feed system without difficulty, and combusted properly on the grate while meeting opacity requirements with low SO{sub 2} and NO{sub x} emissions. Efforts are underway to commercialize a wood/coal blend at the brewery, to identify specific urban wood supplies in the Pittsburgh region and to conduct a demonstration at a spreader stoker.

  4. Summary of mineral industry activities in Colorado. Part I: coal

    SciTech Connect

    Pascoe, D.M.

    1981-01-01

    Coal production for 1981 was a record, with production at 19,701,496 tons of coal mined and reported to the Division of Mines. This was a 4.95% increase over 1980. Statewide Divisional efforts to support a practical type of health and safety training program while encouraging skill education appropriate to mining needs, saw extensive accomplishment in 1981. The Division gave direct or monetary support through training grant funds, largely used for reimbursed tuition from strategically located state vocational schools who taught on campus as well as at mine sites. Total miner training reported by area schools to the Division of Mines indicates that 8408 students received 86,251 hours of classroom and on-the-job training. It is hoped that the education and training programs throughout the state will be continued in an effort to educate both the new and old miners. We believe this is the best approach to the coal industry's never ending task of reducing both lost-time and fatal accidents. Coal mine certification in all categories totaled 780 certificates issued. This was a decrease from 1980, and will probably decrease again in 1982 with the initiation of the $25.00 fee for each examination. Coal mining activity is reported by district.

  5. Continuous bench-scale slurry catalyst testing direct coal liquefaction rawhide sub-bituminous coal

    SciTech Connect

    Bauman, R.F.; Coless, L.A.; Davis, S.M.

    1995-12-31

    In 1992, the Department of Energy (DOE) sponsored research to demonstrate a dispersed catalyst system using a combination of molybdenum and iron precursors for direct coal liquefaction. This dispersed catalyst system was successfully demonstrated using Black Thunder sub-bituminous coal at Wilsonville, Alabama by Southern Electric International, Inc. The DOE sponsored research continues at Exxon Research and Development Laboratories (ERDL). A six month continuous bench-scale program using ERDL`s Recycle Coal Liquefaction Unit (RCLU) is planned, three months in 1994 and three months in 1995. The initial conditions in RCLU reflect experience gained from the Wilsonville facility in their Test Run 263. Rawhide sub-bituminous coal which is similar to the Black Thunder coal tested at Wilsonville was used as the feed coal. A slate of five dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal has been tested. Throughout the experiments, the molybdenum addition rate was held constant at 100 wppm while the iron oxide addition rate was varied from 0.25 to 1.0 weight percent (dry coal basis). This report covers the 1994 operations and accomplishments.

  6. The coal industry and its industrial relations. Some union/nonunion comparisons

    SciTech Connect

    Hannah, R.; Mangum, G.

    1985-01-01

    This book addresses the following questions: how do product markets and labor markets interact in a labor intensive industry; how can a union whose members once mined 90 percent of the coal and now mines 40 percent, still dominate the industrial relations system of the industry, bargaining for member, nonmember, miners and management; how did a union which came into being to take wages out of competition eventually come to shield prices from competition as well and what is causing the erosion of that power; how can the environmental threats of an industry be compromised with its essential resource role; with all of its traditional markets dead or dying, how coal has survived through electric power generation; and what is the future of the industry.

  7. Microcomputer based simulation of coal preparation plants: a planning and performance analysis tool for operating personnel in the coal industry

    SciTech Connect

    Chaves, M.M.

    1983-01-01

    The performance of a coal preparation plant can be simulated using an existing process simulation program and a large mainframe computer. Large computers, however, are not common in a preparation plant environment. The objective of this study was to transfer the simulation technology from a large scale mainframe computer environment to a small scale microcomputer environment. This was accomplished by logically decomposing and physically restructuring the existing program; adding interactive data entry/revision modules; providing a series of modules to control the execution of the individual programs; and adding the facility to review summary output on-line. The completed project was assessed by representatives from industry, government, and academia. The assessors state that the microcomputer based simulator is a valuable planning and analysis tool for design and operations engineers in the coal industry. The simulator created during this project utilized the microcomputer technolgy which was available in 1981-1982. Since that time, technological advances in the field of microcomputers have appeared in the marketplace. These advances involve extended memory capacities, higher density storage disks and faster execution times.

  8. The role of coal in industrialization: A case study of Nigeria

    SciTech Connect

    Akarakiri, J.B. )

    1989-01-01

    Coal is a mineral matter found in layers or beds in sedimentary rocks. It is a very highly variable substance. In addition to the variations from lignite to bituminous and anthracite, there are vast differences in its heating value, amount of volatiles, sulfur, moisture and so on. The chemical and physical properties of coal make it an important industrial raw material. There is proven 639 million tonnes of coal reserves in Nigeria. This paper examines the potential and current role of coal in the industrialization of Nigeria. Industries are now dependent on fuel oil as a source of fuel because of its economic and technological advantages over coal. Coal is a source of industrial energy for the future after the known oil reserves might have been exhausted. In the short term, coal can be used as a material for chemicals, iron and steel production as well as a substitute for wood energy in the process of industrialization.

  9. Economics of the coal industry east of the Mississippi, 1973-1982

    USGS Publications Warehouse

    Bhagwat, S.B.

    1987-01-01

    Government regulations on health, safety and environment have been poppular blamed for the declining productivity in U.S. coal mines since 1970. The stagnation in the coal industry east of the Mississippi is alleged to have been caused by this declining productivity and by the growth of cheaper and cleaner coal production west of the Mississippi. Economic evidence suggests, however, that productivity declines were more due to a relative lowering of labor costs in comparison with coal prices and due to work stoppages. The development of western coals fields was spurred by growth in local demand and had only a relatively small impact on coal production east of the Mississippi. Problems of the eastern coal industry are rooted mainly in slow economic growth in eastern U.S. which must be addressed in the long-term interests of the eastern coal industry. ?? 1987.

  10. Early opportunities of CO2 geological storage deployment in coal chemical industry in China

    SciTech Connect

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, Robert T.; Davidson, Casie L.

    2014-11-12

    Abstract: Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO2 emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO2 sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation or in late planning stages. These emission sources together emit 430 million tons CO2 per year, of which about 30% are emit high-purity and pure CO2 (CO2 concentration >80% and >99% respectively).Four typical source-sink pairs are studied by a techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and experienced economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO2 capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO2. When a 15USD/t CO2 tax and 15USD/t for CO2 sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a net economic benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.

  11. Development of a retrofit coal combustor for industrial applications, (Phase 2)

    SciTech Connect

    Not Available

    1989-07-01

    The objective of Phase I of the program for the development of a retrofit pulse coal combustor for industrial applications was to design, fabricate, test and evaluate advanced chamber designs at the laboratory-scale utilizing several fuels (Task 1). The activities were structured to provide design criteria for scaling up to the pilot-scale level for the demonstration of a pulse combustor fired with coal-water mixtures for industrial boiler and process heater retrofit applications. The design data and information acquired during Task 1 of the initial phase was to develop scale-up design criteria for scaling the laboratory-scale design to pilot-scale including interface requirements for the field demonstration. The scale-up pilot unit design was to be sufficiently developed to allow fabrication of the unit for testing in the existing test facility upon DOE exercising its option for the follow-on activities of this program. These follow-on activities (Phase II) included the fabrication, test, and engineering evaluation of the pilot-scale combustor as well as technical and laboratory test support activities for reducing the technical risks and costs of development at the pilot-scale. Based on the information, test, data and technical support activities, a retrofit combustor system was to be designed for field demonstration. An additional effort was added to the contract by modification A005. This modification added a Phase IA in place of the original Task 2 of Phase I activity. This interim phase consisted of three technical tasks described in previous quarterly reports. Phase II was initiated in April 1989.

  12. Some Problems of Industrial Scale-Up.

    ERIC Educational Resources Information Center

    Jackson, A. T.

    1985-01-01

    Scientific ideas of the biological laboratory are turned into economic realities in industry only after several problems are solved. Economics of scale, agitation, heat transfer, sterilization of medium and air, product recovery, waste disposal, and future developments are discussed using aerobic respiration as the example in the scale-up…

  13. Microfine coal firing results from a retrofit gas/oil-designed industrial boiler

    SciTech Connect

    Patel, R.; Borio, R.W.; Liljedahl, G.

    1995-11-01

    Under US Department of Energy, Pittsburgh Energy Technology Center (PETC) support, the development of a High Efficiency Advanced Coal Combustor (HEACC) has been in progress since 1987 at the ABB Power Plant Laboratories. The initial work on this concept produced an advanced coal firing system that was capable of firing both water-based and dry pulverized coal in an industrial boiler environment.

  14. Non traditional uses of coal ash: Steel industry applications

    SciTech Connect

    Hauke, D.

    1997-09-01

    Coal fly ash is used by the steel industry as an insulating cover to retain heat in ladles of molten steel and as a slag foamer in electric arc furnaces (EAFs) to prolong the life of consumable components and to aid extraction of impurities from the molten steel. The fly ashes that are used in the steel industry are generated from stoker boilers and have a relatively wide particle-size distribution. The powder-type materials used by steel mills to insulate ladles of molten metal include rice hull ash, a heat treated montmorillonite clay mineral (calcined clay), a fly ash from a stoker boiler called LadleJacket, and coke breeze. These ladle insulators should be flowable, coarse, and have a wide particle-size distribution. A study to compare the insulating characteristics of ladle insulators, conducted by the American Foundrymen`s Society Cast Metals Institute, indicated that the ladle insulated with LadleJacket exhibited a lower rate of heat loss than either the rice hull ash or calcined clay. To prolong the life of carbon electrodes and refractory in EAFs and to promote extraction of contaminants from the steel, carbon-based ingredients are injected into the slag to cause it to foam. Typically, high-carbon products such as coke breeze (coke fines) are used as slag foamers. A new product called Carbon Plus, which is a coarse, high-carbon fly ash from a coal-fired stoker boiler, is now being used as a slag foamer in the steel industry.

  15. ISO 9000 and its effects on the coal industry

    SciTech Connect

    Vardys, R.K.

    1996-12-31

    It is asserted that organizations that do not implement a formal quality program by the year 2000 will not survive. The ISO 9000 quality management standards provide the model for many companies that have determined a quality program is vital not only for their survival, but their growth, in an increasingly competitive business environment. The U.S. coal industry has been hit hard with utility de-regulation and global competition. More emphasis is being placed on bold cost savings measures by utilities and coal producers alike. These measures range from subcontracting analytical work to subcontracting power plant maintenance. Unfortunately, quality management systems are still seen as an expense instead of a cost saving measure and are not being addressed by those who most desperately need quality management systems. What must be understood is that through the implementation of a quality management program, companies can recover costs that were previously accepted as unrecoverable. Prevention costs (documentation, internal auditing, training, management review, etc.) will increase slightly, due to an increased emphasis on a quality management system, but, a net savings is realized through a decrease in failure costs, e.g., waste, scrap, meetings to discuss failures/place blame, worry, re-work, client loss, client doubt, etc.

  16. The research of distributed interactive simulation based on HLA in coal mine industry inherent safety

    NASA Astrophysics Data System (ADS)

    Dou, Zhi-Wu

    2010-08-01

    To solve the inherent safety problem puzzling the coal mining industry, analyzing the characteristic and the application of distributed interactive simulation based on high level architecture (DIS/HLA), a new method is proposed for developing coal mining industry inherent safety distributed interactive simulation adopting HLA technology. Researching the function and structure of the system, a simple coal mining industry inherent safety is modeled with HLA, the FOM and SOM are developed, and the math models are suggested. The results of the instance research show that HLA plays an important role in developing distributed interactive simulation of complicated distributed system and the method is valid to solve the problem puzzling coal mining industry. To the coal mining industry, the conclusions show that the simulation system with HLA plays an important role to identify the source of hazard, to make the measure for accident, and to improve the level of management.

  17. Development of Affordable, Low-Carbon Hydrogen Supplies at an Industrial Scale

    ERIC Educational Resources Information Center

    Roddy, Dermot J.

    2008-01-01

    An existing industrial hydrogen generation and distribution infrastructure is described, and a number of large-scale investment projects are outlined. All of these projects have the potential to generate significant volumes of low-cost, low-carbon hydrogen. The technologies concerned range from gasification of coal with carbon capture and storage…

  18. Time scales of organic contaminant dissolution from complex source zones: coal tar pools vs. blobs

    NASA Astrophysics Data System (ADS)

    Eberhardt, Christina; Grathwohl, Peter

    2002-11-01

    Groundwater contamination due to complex organic mixtures such as coal tar, creosote and fuels is a widespread problem in industrialized regions. Although most compounds in these mixtures are biodegradable, the contaminant sources are very persistent for many decades after the contamination occurred (e.g., more than 100 years ago at gasworks sites). This limited bioavailability is due to slow dissolution processes. This study presents results from a large scale tank experiment (8 m long) on the long-term (354 days) dissolution kinetics of BTEX and PAHs from a 2.5 m long coal tar pool and 0.5 m long (smear) zone containing coal tar blobs distributed in a coarse sand. The results indicate (1) that Raoult's law holds for estimation of the saturation aqueous concentrations of the coal tar constituents, (2) that for the dissolution of smear zones longer than approximately 0.1 m and with more than 3-5% residual saturation, the local equilibrium assumption is valid and (3) that although very small (<0.1 mm), the transverse vertical dispersivity dominates the pool dissolution processes. Typical time scales for removal of the pollutants from the blob zone and the pool are in the order of a few weeks to more than 10,000 years, respectively.

  19. Time scales of organic contaminant dissolution from complex source zones: coal tar pools vs. blobs.

    PubMed

    Eberhardt, Christina; Grathwohl, Peter

    2002-11-01

    Groundwater contamination due to complex organic mixtures such as coal tar, creosote and fuels is a widespread problem in industrialized regions. Although most compounds in these mixtures are biodegradable, the contaminant sources are very persistent for many decades after the contamination occurred (e.g., more than 100 years ago at gasworks sites). This limited bioavailability is due to slow dissolution processes. This study presents results from a large scale tank experiment (8 m long) on the long-term (354 days) dissolution kinetics of BTEX and PAHs from a 2.5 m long coal tar pool and 0.5 m long (smear) zone containing coal tar blobs distributed in a coarse sand. The results inidicate (1) that Raoult's law holds for estimation of the saturation aqueous concentrations of the coal tar constituents, (2) that for the dissolution of smear zones longer than approximately 0.1 m and with more than 3-5% residual saturation, the local equilibrium assumption is valid and (3) that although very small (< 0.1 mm), the transverse vertical dispersivity dominates the pool dissolution processes. Typical time scales for removal of the pollutants from the blob zone and the pool are in the order of a few weeks to more than 10,000 years, respectively. PMID:12683639

  20. A coal-fired combustion system for industrial process heating applications

    SciTech Connect

    Not Available

    1992-10-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashesand industrial wastes. ne primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order toevaluate its potential marketability. During the current reporting period, three preliminary coal-fired tests were successfully completed. These tests used industrial boiler flyash, sewer sludge ash, and waste glass collet as feedstocks. The coal-fired ash vitrification tests are considered near term potential commercial applications of the CMS technology. The waste glass cullet provided necessary dam on the effect of coal firing with respect to vitrified product oxidation state. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the proof-of-concept tests are continuing. The economic evaluation of commercial scale CMS processes is continuing. Preliminary designs for 15, 25, 100 and 400 ton/day systems are in progress. This dam will serve as input data to the life cycle cost analysis which will be-an integral part of the CMS commercialization plan.

  1. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1991--June 1992

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump & Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  2. Productivity, job satisfaction, and health and safety in the coal industry: the participatory alternative

    SciTech Connect

    Not Available

    1982-01-01

    This is a conference which presents results and ideas on workplace participation in the coal industry. It discusses the theory of the quality circle groups for developing their own production rates and design goals. It presents the results of different coal company participation in this idea and how to implement this option. Individual topics are entered into the Data Base as separate items.

  3. Effective Communication and Training. A Guide for Workplace Trainers in the Australian Coal Industry.

    ERIC Educational Resources Information Center

    Lukin, Annabelle

    This guide is designed to help workplace trainers in Australia's coal industry improve coal miners' operator and general communication skills through a curriculum that integrates training in language, literacy, and numeracy. The following topics are discussed in the guide's seven sections: the changing workplace (changing work environment;…

  4. BENCH SCALE DEVELOPMENT OF MEYERS PROCESS FOR COAL DESULFURIZATION

    EPA Science Inventory

    The report gives results of coal desulfurization experiments to determine the feasibility and advantages of combining gravity separation of coal with chemical desulfurization. The investigations led to the definition of the Gravichem Process, a combination physical/chemical coal ...

  5. Upgrading selected Czech coals for home and industrial heating

    SciTech Connect

    Musich, M.A.; Young, B.C.

    1995-12-31

    The Czech Republic has large coal reserves, particularly brown coal and lignite, and to a lesser extent, bituminous coal. Concurrent with the recent political changes, there has been a reassessment of the role of coal for electrical and heating energy in the future economy, owing to the large dependence on brown coal and lignite and the implementation of more stringent environmental regulations. These coals have a relatively high sulfur content, typically 1-3 wt%, and ash content, leading to significant SO{sub 2} and other gaseous and particulate emissions. Some of the bituminous coals also exhibit high ash content. Against this background, the Energy & Environmental Research Center, on behalf of the U.S. Agency for International Development and the U.S. Department of Energy Office of Fossil Energy, undertook a project on upgrading Czech coals to achieve desired fuel properties. The purpose of the project was to assist the city of Usti nad Labem in Northern Bohemia in developing cost-effective alternatives for reducing environmental emissions from district and home heating systems.

  6. Ash characterization in laboratory-scale oxy-coal combustor

    EPA Science Inventory

    Oxygen enriched coal (oxy-coal) combustion is a developing technology. During oxy-coal combustion, combustion air is separated and the coal is burned in a mixture of oxygen and recycled flue gas. The resulting effluent must be further processed before the C02 can be compressed, t...

  7. Solid-liquid separation for liquefied coal industries. Final report

    SciTech Connect

    Tiller, F.M.; Leu, W.

    1984-07-01

    This book has been written for engineers concerned with separation processes related to liquefied coal slurries. Difficulties in removing mineral residues and unconverted carbon represent a major obstacle to economic production of liquefied coal products. Reactor slurries in which hydrogenation has been used to upgrade coal generally contain 5 to 10 weight percents of solids which must be removed. Various kinds of equipment employed for particulate removal include rotary drum pressure, candle, and leaf filters, solid bowl centrifuges, hydrocyclones, and critical solvent de-ashers. Although emphasis has been given to filtration of solvent refined coal, much of the material is of a fundamental character and is applicable to other fields. Analysis of filtration data requires an understanding of the principles of frictional flow through compressible beds of particulates. Much of the analysis appearing in the literature must be carefully evaluated as errors and misinterpretations abound.

  8. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  9. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1990-07-01

    The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. This quarter, work was centered on design, fabrication, and testing of the combustor, cleanup, fuel specifications, and hot end simulation rig. 2 refs., 59 figs., 29 tabs.

  10. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect

    B.K. PAREKH; D. TAO; J.G. GROPPO

    1998-02-03

    The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean-coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high-sulfur and low-sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals.

  11. The development of a coal-fired combustion system for industrial process heating applications

    SciTech Connect

    Not Available

    1992-07-16

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  12. Do coal consumption and industrial development increase environmental degradation in China and India?

    PubMed

    Shahbaz, Muhammad; Farhani, Sahbi; Ozturk, Ilhan

    2015-03-01

    The present study is aimed to explore the relationship between coal consumption, industrial production, and CO2 emissions in China and India for the period of 1971-2011. The structural break unit root test and cointegrating approach have been applied. The direction of causal relationship between the variables is investigated by applying the VECM Granger causality test. Our results validate the presence of cointegration among the series in both countries. Our results also validate the existence of inverted U-shaped curve between industrial production and CO2 emissions for India, but for China, it is a U-shaped relationship. Coal consumption adds in CO2 emissions. The causality analysis reveals that industrial production and coal consumption Granger cause CO2 emissions in India. In the case of China, the feedback effect exists between coal consumption and CO2 emissions. Due to the importance of coal in China and India, any reduction in coal consumption will negatively affect their industrial value added as well as economic growth. PMID:25277709

  13. Scale effects on strength of geomaterials, case study: Coal

    NASA Astrophysics Data System (ADS)

    Scholtès, Luc; Donzé, Frédéric-Victor; Khanal, Manoj

    2011-05-01

    Scale effects on the strength of coal are studied using a discrete element model. The key point of the model is its capability to discriminate between the "strictly sample size" effect and the "Discrete Fracture Network (DFN) density" effect on the mechanical response. Simulations of true triaxial compression tests are carried out to identify their respective roles. The possible bias due to the discretization size distribution of the discrete element model is investigated in detail by considering low-resolution configurations. The model is shown to be capable of quantitatively reproducing the dependency of the maximum strength on the size of the sample. This relationship mainly relies on the DFN density. For all given sizes, as long as the DFN density remains constant with a uniform distribution or if discontinuities are absent in the considered medium, the maximum strength of the material remains constant.

  14. Corrosion performance of alumina scales in coal gasification environments

    SciTech Connect

    Natesan, K.

    1997-02-01

    Corrosion of metallic structural materials in complex gas environments of coal gasification is a potential problem. The corrosion process is dictated by concentrations of two key constituents: sulfur as H{sub 2}S and Cl as HCl. This paper examines the corrosion performance of alumina scales that are thermally grown on Fe-base alloys during exposure to O/S mixed-gas environments. The results are compared with the performance of chromia-forming alloys in similar environments. The paper also discusses the available information on corrosion performance of alloys whose surfaces were enriched with Al by the pack-diffusion process, by the electrospark deposition process, or by weld overlay techniques.

  15. Estimates and Predictions of Coal Workers' Pneumoconiosis Cases among Redeployed Coal Workers of the Fuxin Mining Industry Group in China: A Historical Cohort Study.

    PubMed

    Han, Bing; Liu, Hongbo; Zhai, Guojiang; Wang, Qun; Liang, Jie; Zhang, Mengcang; Cui, Kai; Shen, Fuhai; Yi, Hongbo; Li, Yuting; Zhai, Yuhan; Sheng, Yang; Chen, Jie

    2016-01-01

    This research was aimed at estimating possible Coal workers' pneumoconiosis (CWP) cases as of 2012, and predicting future CWP cases among redeployed coal workers from the Fuxin Mining Industry Group. This study provided the scientific basis for regulations on CWP screening and diagnosis and labor insurance policies for redeployed coal workers of resource-exhausted mines. The study cohort included 19,116 coal workers. The cumulative incidence of CWP was calculated by the life-table method. Possible CWP cases by occupational category were estimated through the average annual incidence rate of CWP and males' life expectancy. It was estimated that 141 redeployed coal workers might have suffered from CWP as of 2012, and 221 redeployed coal workers could suffer from CWP in the future. It is crucial to establish a set of feasible and affordable regulations on CWP screening and diagnosis as well as labor insurance policies for redeployed coal workers of resource-exhausted coal mines in China. PMID:26845337

  16. Estimates and Predictions of Coal Workers’ Pneumoconiosis Cases among Redeployed Coal Workers of the Fuxin Mining Industry Group in China: A Historical Cohort Study

    PubMed Central

    Han, Bing; Liu, Hongbo; Zhai, Guojiang; Wang, Qun; Liang, Jie; Zhang, Mengcang; Cui, Kai; Shen, Fuhai; Yi, Hongbo; Li, Yuting; Zhai, Yuhan; Sheng, Yang; Chen, Jie

    2016-01-01

    This research was aimed at estimating possible Coal workers’ pneumoconiosis (CWP) cases as of 2012, and predicting future CWP cases among redeployed coal workers from the Fuxin Mining Industry Group. This study provided the scientific basis for regulations on CWP screening and diagnosis and labor insurance policies for redeployed coal workers of resource-exhausted mines. The study cohort included 19,116 coal workers. The cumulative incidence of CWP was calculated by the life-table method. Possible CWP cases by occupational category were estimated through the average annual incidence rate of CWP and males’ life expectancy. It was estimated that 141 redeployed coal workers might have suffered from CWP as of 2012, and 221 redeployed coal workers could suffer from CWP in the future. It is crucial to establish a set of feasible and affordable regulations on CWP screening and diagnosis as well as labor insurance policies for redeployed coal workers of resource-exhausted coal mines in China. PMID:26845337

  17. Response of an industrial coal flotation circuit to changing reagent dosages

    SciTech Connect

    Suardini, P.J.; Kawatra, S.K.

    1995-10-01

    A number of on-stream coal slurry analyzers are presently being developed and commercialized for measuring ash and solids in coal process streams, particularly around flotation circuits. The eventual goal of these efforts is to develop on-line quality control systems for flotation circuits and other fine-coal cleaning operations. As part of this on-line monitoring and control effort, it is important to gain a better understanding of the response of industrial flotation circuits to changing operating conditions. This paper summarizes the results from a detailed sampling program performed at an industrial coal flotation circuit in western Pennsylvania. The testing focused on evaluating the response of the circuit to changes in reagent dosages, operating conditions sand feed compositions. The testing indicated that it is desirable to maintain high collector-to-frother ratios to enhance coarse particle flotation. The recovery of fine impurity particles was also proportional to water recovery, due to hydraulic entrainment.

  18. Guide to federal export assistance activities applicable to the US coal and coal technologies industry

    SciTech Connect

    Not Available

    1989-09-01

    The federal government provides a complete range of programs and services that can assist United States (US) coal and coal-technology firms as they expand into the foreign marketplace. These programs cover the spectrum of business export needs, which include: providing assistance in identifying target markets, locating specific business opportunities and foreign joint-venture partners, arranging business appointments, organizing trade missions, sponsoring feasibility studies, conducting trade analyses, providing financing, insuring investments, and providing in-country training and assistance. Under the sponsorship of the Department of Energy's (DOE) Office of Fossil Energy (FE), this Guide has been developed to address this problem. It is intended to provide coal and coal technology firms with a single reference source for identifying US government agencies, programs, and contacts that might aid in exporting. The Guide contains an in-depth discussion of the eight major agencies offering export assistance: the Agency for International Development (AID), the Departments of Commerce (DOC) and State (DOS), the Export-Import Bank (Eximbank), the Overseas Private Investment Corporation (OPIC), the Small Business Administration (SBA), the Trade and Development Program (TDP), and the Office of the US Trade Representative (USTR). In addition, this guide identifies pertinent activities performed by other federal agencies that might assist coal and coal-technologies exporters, including the Departments of Defense (DOD), Education, Energy (DOE), and Labor (DOL).

  19. Development of a retrofit coal combustor for industrial applications, (Phase 2). Technical progress report, April--June 1989

    SciTech Connect

    Not Available

    1989-07-01

    The objective of Phase I of the program for the development of a retrofit pulse coal combustor for industrial applications was to design, fabricate, test and evaluate advanced chamber designs at the laboratory-scale utilizing several fuels (Task 1). The activities were structured to provide design criteria for scaling up to the pilot-scale level for the demonstration of a pulse combustor fired with coal-water mixtures for industrial boiler and process heater retrofit applications. The design data and information acquired during Task 1 of the initial phase was to develop scale-up design criteria for scaling the laboratory-scale design to pilot-scale including interface requirements for the field demonstration. The scale-up pilot unit design was to be sufficiently developed to allow fabrication of the unit for testing in the existing test facility upon DOE exercising its option for the follow-on activities of this program. These follow-on activities (Phase II) included the fabrication, test, and engineering evaluation of the pilot-scale combustor as well as technical and laboratory test support activities for reducing the technical risks and costs of development at the pilot-scale. Based on the information, test, data and technical support activities, a retrofit combustor system was to be designed for field demonstration. An additional effort was added to the contract by modification A005. This modification added a Phase IA in place of the original Task 2 of Phase I activity. This interim phase consisted of three technical tasks described in previous quarterly reports. Phase II was initiated in April 1989.

  20. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.; Rawls, P.

    1995-11-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  1. Linkage with Industry on a National Scale.

    ERIC Educational Resources Information Center

    Shoemaker, Byrl R.

    1985-01-01

    Examines how the automobile industry, through the National Institute for Automotive Service Excellence and the National Automotive Technical Education Foundation, has accepted a set of standards developed by the Industry Planning Council of the American Vocational Association Trade and Industrial Division and made them a basis for certification of…

  2. CFD study of temperature distribution in full scale boiler adopting in-furnace coal blending

    NASA Astrophysics Data System (ADS)

    Fadhil, S. S. A.; Hasini, H.; Shuaib, N. H.

    2013-06-01

    This paper describes the investigation of temperature characteristics of an in-furnace combustion using different coals in a 700 MW full scale boiler. Single mixture fraction approach is adopted for combustion model of both primary and secondary coals. The primary coal was based on the properties of Adaro which has been used as the design coal for the boiler under investigation. The secondary blend coal was selected based on sub-bituminous coal with higher calorific value. Both coals are simultaneously injected into the furnace at alternate coal burner elevations. The general prediction of the temperature contours at primary combustion zone shows identical pattern compared with conventional single coal combustion in similar furnace. Reasonable agreement was achieved by the prediction of the average temperature at furnace exit. The temperature distribution is at different furnace elevation is non-uniform with higher temperature predicted at circumferential "ring-like" region at lower burner levels for both cases. The maximum flame temperature is higher at the elevation where coal of higher calorific value is injected. The temperature magnitude is within the accepTable limit and the variations does not differ much compared to the conventional single coal combustion.

  3. Abandoned coal mining sites: using ecotoxicological tests to support an industrial organic sludge amendment.

    PubMed

    Chiochetta, Claudete G; Radetski, Marilice R; Corrêa, Albertina X R; Tischer, Vinícius; Tiepo, Erasmo N; Radetski, Claudemir M

    2013-11-01

    The different stages involved in coal mining-related activities result in a degraded landscape and sites associated with large amounts of dumped waste material. Remediation of these contaminated soils can be carried out by application of industrial organic sludge if the concerns regarding the potential negative environmental impacts of this experimental practice are properly addressed. In this context, the objective of this study was to use ecotoxicological tests to determine the quantity of organic industrial sludge that is required as a soil amendment to restore soil production while avoiding environmental impact. Chemical analysis of the solids (industrial sludge and soil) and their leachates was carried out as well as a battery of ecotoxicity tests on enzymes (hydrolytic activity), bacteria, algae, daphnids, earthworms, and higher plants, according to standardized methodologies. Solid and leachate samples of coal-contaminated soil were more toxic than those of industrial sludge towards enzyme activity, bacteria, algae, daphnids, and earthworms. In the case of the higher plants (lettuce, corn, wild cabbage, and Surinam cherry) the industrial sludge was more toxic than the coal-contaminated soil, and a soil/sludge mixture (66:34% dry weight basis) had a stimulatory effect on the Surinam cherry biomass. The ecotoxicological assessment of the coal-contaminated soil remediation using sludge as an amendment is very important to determine application rates that could promote a stimulatory effect on agronomic species without negatively affecting the environment. PMID:23114837

  4. Evaluation of the Impact of Chlorine on Mercury Oxidation in a Pilot-Scale Coal Combustor--The Effect of Coal Blending

    EPA Science Inventory

    A study has been undertaken to investigate the effect of blending PRB coal with an Eastern bituminous coal on the speciation of Hg across an SCR catalyst. In this project, a pilot-scale (1.2 MWt) coal combustor equipped with an SCR reactor for NOx control was used for evaluating ...

  5. Catalytic multi-stage liquefaction of coal at HTI: Bench-scale studies in coal/waste plastics coprocessing

    SciTech Connect

    Pradhan, V.R.; Lee, L.K.; Stalzer, R.H.

    1995-12-31

    The development of Catalytic Multi-Stage Liquefaction (CMSL) at HTI has focused on both bituminous and sub-bituminous coals using laboratory, bench and PDU scale operations. The crude oil equivalent cost of liquid fuels from coal has been curtailed to about $30 per barrel, thus achieving over 30% reduction in the price that was evaluated for the liquefaction technologies demonstrated in the late seventies and early eighties. Contrary to the common belief, the new generation of catalytic multistage coal liquefaction process is environmentally very benign and can produce clean, premium distillates with a very low (<10ppm) heteroatoms content. The HTI Staff has been involved over the years in process development and has made significant improvements in the CMSL processing of coals. A 24 month program (extended to September 30, 1995) to study novel concepts, using a continuous bench scale Catalytic Multi-Stage unit (30kg coal/day), has been initiated since December, 1992. This program consists of ten bench-scale operations supported by Laboratory Studies, Modelling, Process Simulation and Economic Assessments. The Catalytic Multi-Stage Liquefaction is a continuation of the second generation yields using a low/high temperature approach. This paper covers work performed between October 1994- August 1995, especially results obtained from the microautoclave support activities and the bench-scale operations for runs CMSL-08 and CMSL-09, during which, coal and the plastic components for municipal solid wastes (MSW) such as high density polyethylene (HDPE)m, polypropylene (PP), polystyrene (PS), and polythylene terphthlate (PET) were coprocessed.

  6. The changing structure of the US coal industry: An update, July 1993

    SciTech Connect

    Not Available

    1993-07-29

    Section 205(a)(2) of the Department of Energy Organization Act of 1977 requires the Administrator of the Energy Information Administration (EIA) to carry out a central, comprehensive, and unified energy data and information program that will collect, evaluate, assemble, analyze, and disseminate data and information relevant to energy resources, reserves, production, demand, technology, and related economic and statistical information. The purpose of this report is to provide a comprehensive overview of changes in the structure of the US coal industry between 1976 and 1991. The structural elements examined include the number of mines, average mine size, the size distribution of mines, and the size distribution of coal firms. The report measures changes in the market shares of the largest coal producers at the national level and in various regions. The Central Appalachian low-sulfur coal market is given special attention, and the market for coal reserves is examined. A history of mergers in the coal industry is presented, and changes in the proportions of US coal output that are produced by various types of companies, including foreign-controlled firms, are described. Finally, the impact of post-1991 mergers on the structure of the industry is estimated. The legislation that created the EIA vested the organization with an element of statutory independence. The EIA does not take positions on policy questions. The EIA`s responsibility is to provide timely, high-quality information and to perform objective, credible analyses in support of deliberations by both public and private decisionmakers. Accordingly, this report does not purport to represent the policy positions of the US Department of Energy or the Administration.

  7. REVIEW OF CONCURRENT MASS EMISSION AND OPACITY MEASUREMENTS FOR COAL-BURNING UTILITY AND INDUSTRIAL BOILERS

    EPA Science Inventory

    The report gives results of concurrent particulate emissions and opacity measurements based on visual observations and/or in-stack transmissometry for more than 400 compliance, acceptance, or experimental tests on coal-fired utility and industrial boilers. The sampling, which inc...

  8. EVALUATION OF LOW EMISSION COAL BURNER TECHNOLOGY ON INDUSTRIAL BOILERS. THIRD ANNUAL REPORT (1981)

    EPA Science Inventory

    The report summarizes the third year's effort under EPA Contract 68-02-3127. The objective of the program is to conduct a field evaluation of the distributed mixing burner (DMB) on an industrial size boiler. The DMB concept provides for controlled mixing of coal with combustion a...

  9. ENVIRONMENTAL ASSESSMENT OF A COAL/WATER SLURRY FIRED INDUSTRIAL BOILER. VOLUME 2. DATA SUPPLEMENT

    EPA Science Inventory

    The report gives results of comprehensive emission measurements and analyses for a 7.6 kg/s (60,000 lb/hr) watertube industrial boiler firing a coal/water slurry. Measurements included continuous monitoring of flue gas; quantitation of semivolatile organics and 73 trace elements;...

  10. ENVIRONMENTAL ASSESSMENT OF A COAL/WATER SLURRY FIRED INDUSTRIAL BOILER. VOLUME 1. TECHNICAL RESULTS

    EPA Science Inventory

    The report gives results of comprehensive emission measurements and analyses for a 7.6 kg/s (60,000 lb/hr) watertube industrial boiler firing a coal/water slurry. Measurements included continuous monitoring of flue gas; quantitation of semivolatile organics and 73 trace elements;...

  11. Liquid Fuels from Coal: From R&D to an Industry

    ERIC Educational Resources Information Center

    Swabb, L. E., Jr.

    1978-01-01

    Government support of coal liquefaction Research and Development has created the conditions that make possible the development of needed technology. With the proper government incentives, pioneer plants will lead to lower costs, and this, plus rising prices, will create the conditions necessary to develop a multi-plant industry. (Author/MA)

  12. Bench-scale testing of a micronized magnetite, fine-coal cleaning process

    SciTech Connect

    Suardini, P.J.

    1995-11-01

    Custom Coals, International has installed and is presently testing a 500 lb/hr. micronized-magnetite, fine-coal cleaning circuit at PETC`s Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program`s, High Efficiency Preparation Subprogram. The project includes design, construction, testing, and decommissioning of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense medium cycloning of the 300 by 30 micron feed coal using a nominal minus 10 micron size magnetite medium, and medium recovery using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

  13. Coal-fired boiler costs for industrial applications

    SciTech Connect

    Kurzius, S.C.; Barnes, R.W.

    1982-04-01

    Several of the current sources of information provide data on coal-fired steam boiler costs. As published, these data give widely varying and possibly inconsistent conclusions. This study was undertaken to determine the extent to which the differences in the various sets of published data bases could be resolved and, if possible, to arrive at more reliable cost correlations to be used in Oak Ridge Energy Demand Models. Our principal finding is that it is indeed possible to restate the costs within each data base on a more consistent basis. When this is done, reasonable engineering correlations of all the cost data versus steam plant capacity can be made over the 10,000 to 5000,000 lb/hr range.

  14. Analysis of the holistic impact of the Hydrogen Economy on the coal industry

    NASA Astrophysics Data System (ADS)

    Lusk, Shannon Perry

    As gas prices soar and energy demand continues to grow amidst increasingly stringent environmental regulations and an assortment of global pressures, implementing alternative energy sources while considering their linked economic, environmental and societal impacts becomes a more pressing matter. The Hydrogen Economy has been proposed as an answer to meeting the increasing energy demand for electric power generation and transportation in an environmentally benign way. Based on current hydrogen technology development, the most practical feedstock to fuel the Hydrogen Economy may prove to be coal via hydrogen production at FutureGen plants. The planned growth of the currently conceived Hydrogen Economy will cause dramatic impacts, some good and some bad, on the economy, the environment, and society, which are interlinked. The goal of this research is to provide tools to inform public policy makers in sorting out policy options related to coal and the Hydrogen Economy. This study examines the impact of a transition to a Hydrogen Economy on the coal industry by creating FutureGen penetration models, forecasting coal MFA's which clearly provide the impact on coal production and associated environmental impacts, and finally formulating a goal programming model that seeks the maximum benefit to society while analyzing the trade-offs between environmental, social, and economical concerns related to coal and the Hydrogen Economy.

  15. Industrial pulverized coal low NO{sub x} burner. Phase 1

    SciTech Connect

    Not Available

    1993-02-23

    The objective of Phase 1 of this program is to develop a novel low NO{sub x} pulverized coal burner, which offers near-term commercialization potential, uses preheated combustion air of up to 1000{degree}F, and which can be applied to high-temperature industrial heating furnaces, chemical process furnaces, fired heaters, and boilers. In the low NO{sub x} coal burner concept, the flue gas is recycled to the burner by jet pump action provided by the momentum of the primary air flow. The recycled flue gas is used to convey the pulverized coal to the jet pump where mixing with the primary air takes place. Ignition occurs downstream of the jet mixing section. The recycled flue gas is at high temperature. When the pulverized coal is entrained, it is heated by conduction from the flue gas. The coal is pyrolyzed to a large extent before being mixed with the primary air. These pyrolysis products are the source of energy for the downstream flame. In this process, the fuel nitrogen associated with pyrolysis products can be converted to molecular nitrogen in the pyrolysis flame if the oxygen is held to substoichiometric concentrations based upon the burning species (pyrolysis products and some char). Pyrolysis products combustion is believed to be the primary source of NO{sub x} emissions in coal combustors. Progress is described.

  16. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1992--September 1992

    SciTech Connect

    Not Available

    1992-10-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashesand industrial wastes. ne primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order toevaluate its potential marketability. During the current reporting period, three preliminary coal-fired tests were successfully completed. These tests used industrial boiler flyash, sewer sludge ash, and waste glass collet as feedstocks. The coal-fired ash vitrification tests are considered near term potential commercial applications of the CMS technology. The waste glass cullet provided necessary dam on the effect of coal firing with respect to vitrified product oxidation state. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the proof-of-concept tests are continuing. The economic evaluation of commercial scale CMS processes is continuing. Preliminary designs for 15, 25, 100 and 400 ton/day systems are in progress. This dam will serve as input data to the life cycle cost analysis which will be-an integral part of the CMS commercialization plan.

  17. Microfine coal firing results from a retrofit gas/oil-designed industrial boiler

    SciTech Connect

    Patel, R.; Borio, R.W.; Liljedahl, G.; Miller, B.G.; Scaroni, A.W.; McGowan, J.G.

    1995-12-31

    The development of a High Efficiency Advanced Coal Combustor (HEACC) has been in progress since 1987 and the ABB Power Plant Laboratories. The initial work on this concept produced an advanced coal firing system that was capable of firing both water-based and dry pulverized coal in an industrial boiler environment. Economics may one day dictate that it makes sense to replace oil or natural gas with coal in boilers that were originally designed to burn these fuels. The objective of the current program is to demonstrate the technical and economic feasibility of retrofitting a gas/oil designed boiler to burn micronized coal. In support of this overall objective, the following specific areas were targeted: A coal handling/preparation system that can meet the technical requirements for retrofitting microfine coal on a boiler designed for burning oil or natural gas; Maintaining boiler thermal performance in accordance with specifications when burning oil or natural gas; Maintaining NOx emissions at or below 0.6 lb/MBtu; Achieving combustion efficiencies of 98% or higher; and Calculating economic payback periods as a function of key variables. The overall program has consisted of five major tasks: (1) A review of current state-of-the-art coal firing system components; (2) Design and experimental testing of a prototype HEACC burner; (3) Installation and testing of a HEACC system in a commercial retrofit application; (4) Economic evaluation of the HEACC concept for retrofit applications; and (5) Long term demonstration under commercial user demand conditions. This paper will summarize the latest key experimental results (Task 3) and the economic evaluation (Task 4) of the HEACC concept for retrofit applications. 28 figs., 6 tabs.

  18. Sources and Distribution of Trace Elements in Soils Near Coal-Related Industries.

    PubMed

    Shangguan, Yuxian; Wei, Yuan; Wang, Linquan; Hou, Hong

    2016-04-01

    The degree of contamination of soil and the potential ecological risks associated with five different coal-burning industries were assessed in Shanxi Province, China. Results showed that the trace element concentrations in soil close to the coal industries were higher than those in the background soils, and the enrichment factors were >1. The potential ecological risk indexes ranged from 99 to 328 for the five coal-related industries. Results also illustrated that the trace elements were transported through the atmosphere. Concentrations of B, Hg, Mo, Pb, Se, Cr, Cu, Ni, V, Zn, and Mn were high in the area around the steel plant. Principal component analysis and redundancy analysis indicated that the sources of Se, Mo, Hg, Cd, As, Cr, B, Ni, and Cu were mainly anthropogenic, whereas Pb, V, Cu, Zn, and Mn were from natural sources. The soil Hg and Se contents were simulated by an artificial neural network model, which showed that Hg and Se in soils were from atmospheric deposits and their spatial distributions were related to the dominant wind direction. The potential ecological risk from Hg was much higher (one order of magnitude) than that from the other trace elements, which highlights the fact that it deserves urgent attention. Control of emissions from the burning of coal and other raw materials (such as iron and phosphate ores) should also be prioritized. PMID:26428004

  19. The mine management professions in the twentieth-century Scottish coal mining industry

    SciTech Connect

    Perchard, A.

    2007-07-01

    This book seeks to redress the exclusion of colliery managers and other mining professionals from the history of British, and particularly Scottish, coal industries. This is accomplished by examining these groups within the most crucial period of their ascendancy in the Scottish coal mining industry, 1930-1966. This work seeks to place such persons within their context and to examine their roles, statuses and behaviours through their relationships with employees and the execution of their functions, also examining their terms and conditions of employment, the outlook of their professional associations, and that of their union. Through all this, Dr. Perchard illustrates how this growing consciousness amongst managerial employees in the industry was accompanied by an intense public discussion, within the mining professions, over their future shape, principles and occupational standards.

  20. Large-scale studies of spontaneous combustion of coal. Rept. of investigations/1991

    SciTech Connect

    Smith, A.C.; Miron, Y.; Lazzara, C.P.

    1991-01-01

    The U.S. Bureau of Mines constructed a large-scale facility to study the self-heating of a large coal mass under conditions that simulate a gob area of a mine. The insulated coal chamber can hold up to 13 short tons (st) of coal and is provided with a forced ventilation system and computer-controlled temperature and gas measurement systems to monitor the heat and mass transfer phenomena that occur in the coalbed. Three experiments were completed with high-volatile C bituminous coals that exhibited high spontaneous combustion potentials in laboratory-scale tests. In the first two tests, a sustained heating was not achieved. In the third test, temperatures throughout the coalbed increased steadily from the start, with thermal runaway occurring near the center of the coalbed after 23 days. The thermal reaction zone then moved toward the front of the coalbed. The results of these tests showed that the self-heating of a large coal mass depends not just on the reactivity of the coal, but also on the particle size of the coal, the freshness of the coal surfaces, the heat-of-wetting effect, and the availability of O2 at optimum ventilation rates.

  1. Partners in health: Injury prevention and the coal mining industry

    SciTech Connect

    Hoerner, E.F.

    1996-12-31

    It is necessary to solve many of the work-related problems and areas of concern that are present in the mining industry. An overview of concerns and how to attack the problems is discussed. Some of the worker`s injury problems, such as back pain syndromes, are by no means unique to the industry. However, other problems such as bolter shoulder syndrome problems, are job specific and need biomechanical investigation to determine specific causal relation of job task to injury. The goal would be defined as twofold. The primary goal is to identify the specific job contribution to high risk occupations, and secondly, to implement a total work force injury prevention program. These goals are discussed.

  2. Bio-coal briquette

    SciTech Connect

    Honda, Hiroshi

    1993-12-31

    Some of the developing nations aim to earn foreign currency by exporting oil and/or gas and to increase the domestic consumption of coal to ensure a secure energy supply. Therefore, it is very important to promote effective coal utilization in these nations. Currently, these countries experience problems associated with coal use for household cooking and household industries. For household cooking, coal creates too much smoke and smells unpleasant. In addition, illegally obtained firewood is almost free in local agricultural regions. Coal is also used in household industries; however, simple stoker boilers are inefficient, since unburned coal particles tend to drop through screens during the combustion process. The bio-coal briquette, on the other hand, is an effective and efficient fuel, since it utilizes coal, which is to be used extensively in households and in small and medium-scale industry sectors in some coal-producing countries, as a primary fuel and bamboos (agricultural waste) as a secondary fuel. In addition, the use of bio-coal briquettes will greatly help reduce unburned coal content.

  3. Strategy for large scale solubilization of coal - characterization of Neurospora protein and gene

    SciTech Connect

    Patel, A.; Chen, Y.P.; Mishra, N.C.

    1995-12-31

    Low grade coal placed on mycelial mat of Neurospora crassa growing on Petri plate was found to be solubilized by this fungus. A heat stable protein has been purified to near homogeneity which can solubilize low grade coal in in vitro. The biochemical properties of the Neurospora protein will be presented. The nature of the product obtained after solubilization of coal by Neurospora protein in vivo and in vitro will also be presented. The N-terminus sequence of the amino acids of this protein will be used to design primer for possible cloning of gene for Neurospora protein capable of solubilization of coal in order to develop methodology for coal solubilization on a large scale.

  4. An explanation of large-scale coal and gas outbursts in underground coal mines: the effect of low-permeability zones on abnormally abundant gas

    NASA Astrophysics Data System (ADS)

    An, F. H.; Cheng, Y. P.

    2013-09-01

    Large-scale coal and gas outbursts post a risk of fatal disasters in underground mines. Large-scale outbursts (outburst of coal and rock greater than 500 t) in recent years in China indicate that there is abundant gas in areas of outbursts containing large amounts of potential energy. The adequate sealing properties of the roof and floor of a coal seam are required for local abundant gas around the site of an outburst, but an annular low-permeability zone in a coal seam, which prevents the loss by gas migration through the coal seam itself, is also required. The distribution of coal gas with this annular zone of low permeability is described, and it is proposed that the annular zone of low permeability creates conditions for confining the coal gas. The effect of this low-permeability zone on the gas distribution is analyzed after allowing for simplifications in the model. The results show that the permeability and length of the low-permeability zone have a great impact on the gas distribution. A steep gradient of gas pressure in the low-permeability zone and the high gas pressure in the abundant zone of gas can promote coal mass failure and coal wall deformation, thereby accelerating the coal and gas outburst. The high pressure gas in abundant zone of gas will lead to a large-scale outburst if an outburst occurs.

  5. [Emission characteristics of PM10 from coal-fired industrial boiler].

    PubMed

    Li, Chao; Li, Xing-Hua; Duan, Lei; Zhao, Meng; Duan, Jing-Chun; Hao, Ji-Ming

    2009-03-15

    Through ELPI (electrical low-pressure impactor) based dilution sampling system, the emission characteristics of PM10 and PM2.5 was studied experimentally at the inlet and outlet of dust catchers at eight different coal-fired industrial boilers. Results showed that a peak existed at around 0.12-0.20 microm of particle size for both number size distribution and mass size distribution of PM10 emitted from most of the boilers. Chemical composition analysis indicated that PM2.5 was largely composed of organic carbon, elementary carbon, and sulfate, with mass fraction of 3.7%-21.4%, 4.2%-24.6%, and 1.5%-55.2% respectively. Emission factors of PM10 and PM2.5 measured were 0.13-0.65 kg x t(-1) and 0.08-0.49 kg x t(-1) respectively for grate boiler using raw coal, and 0.24 kg x t(-1) and 0.22 kg x t(-1) for chain-grate boiler using briquette. In comparison, the PM2.5 emission factor of fluidized bed boiler is 1.14 kg x t(-1), much her than that of grate boiler. Due to high coal consumption and low efficiency of dust separator, coal-fired industrial boiler may become the most important source of PM10, and should be preferentially controlled in China. PMID:19432307

  6. The production of high load coal-water mixtures on the base of Kansk-Achinsk Coal Basin

    SciTech Connect

    Demidov, Y.; Bruer, G.; Kolesnikova, S.

    1995-12-01

    The results of the {open_quotes}KATEKNIIugol{close_quotes} work on the problems of high load coal-water mixtures are given in this article. General principles of the mixture production, short characteristics of Kansk-Achinsk coals, the experimental results of the coal mixture production on a test-industrial scale, the suspension preparation on the base of coal mixtures, technical-economical indexes of tested coal pipeline variants based on Kansk-Achinsk coals are described.

  7. 78 FR 26337 - Notice of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-06

    ... of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial Fuel Use Act... a coal capability self- certification to the Department of Energy (DOE) pursuant to Sec. 201(d) of... 501.60, 61. FUA and regulations thereunder require DOE to publish a notice of filing of...

  8. 77 FR 74473 - Notice of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-14

    ... of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial Fuel Use Act... a coal capability self- certification to the Department of Energy (DOE) pursuant to Sec. 201(d) of... 501.60, 61. FUA and regulations thereunder require DOE to publish a notice of filing of...

  9. Ash transformations in the real-scale pulverized coal combustion of South African and Colombian coals

    SciTech Connect

    Lind, T.; Kauppinen, E.I.; Valmari, T.; Klippel, N.; Mauritzson, C.

    1996-12-31

    In this work, the formation of ash particles in the combustion of South African Klein Kropie coal and a Colombian coal was studied by measuring the ash particle characteristics upstream of the electrostatic precipitator (ESP) at a 510 MW{sub e} pulverized coal fired power plant. The authors measured the ash particle mass size distributions in the size range 0.01--50 {micro}m using low-pressure impactors and precutter cyclones. Also, samples were collected for computer controlled scanning electron microscopy (CCSEM) with a cyclone with an aerodynamic cut-diameter of about 1 {micro}m. The cyclone-collected samples were analyzed with standard CCSEM procedure by depositing the particles on a filter, and by embedding the particles in epoxy hence acquiring the cross-section analysis of the sample. All major mineral classes in both coals were found to undergo extensive coalescence during combustion. Iron, calcium and magnesium rich particles resulting from the decomposition of pyrite, calcite and dolomite were found to coalesce with quartz and aluminosilicate particles. The size distributions of the fly ash determined with CCSEM and low-pressure impactor-cyclone sampler were found to be similar.

  10. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1995-11-01

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both the ash and sulfur contents of run-of-mine coals. The extent of cleaning depends on the liberation characteristics of the coal, which generally improve with reducing particle size. however, since most of the advanced technologies are wet processes, the clean coal product must be dewatered before it can be transported and burned in conventional boilers. This additional treatment step significantly increases the processing cost and makes the industrial applicability of these advanced technologies much less attractive. In order to avoid problems associated with fine coal dewatering, researchers at the Pittsburgh Energy Technology Center (PETC) developed a novel triboelectrostatic separation (TES) process that can remove mineral matter from dry coal. In this technique, finely pulverized coal is brought into contact with a material (such as copper) having a work function intermediate to that of the carbonaceous material and associated mineral matter. Carbonaceous particles having a relatively low work function become positively charged, while particles of mineral matter having significantly higher work functions become negatively charged. once the particles become selectively charged, a separation can be achieved by passing the particle stream through an electrically charged field. Details related to the triboelectrostatic charging phenomenon have been discussed elsewhere (Inculet, 1984).

  11. ENVIRONMENTAL ASSESSMENT OF COAL-AND OIL-FIRING IN A CONTROLLED INDUSTRIAL BOILER. VOLUME I. EXECUTIVE SUMMARY

    EPA Science Inventory

    The report gives results of a comparative multimedia assessment of coal versus oil firing in a controlled industrial boiler. Relative environmental, energy, economic, and societal impacts were identified. Comprehensive sampling and analyses of gaseous, liquid, and solid emissions...

  12. FTIR monitoring of industrial scale CVD processes

    NASA Astrophysics Data System (ADS)

    Hopfe, V.; Mosebach, H.; Meyer, M.; Sheel, D.; Grählert, W.; Throl, O.; Dresler, B.

    1998-06-01

    The goal is to improve chemical vapour deposition (CVD) and infiltration (CVI) process control by a multipurpose, knowledge based feedback system. For monitoring the CVD/CVI process in-situ FTIR spectroscopic data has been identified as input information. In the presentation, three commonly used, and distinctly different, types of industrial CVD/CVI processes are taken as test cases: (i) a thermal high capacity CVI batch process for manufacturing carbon fibre reinforced SiC composites for high temperature applications, (ii) a continuously driven CVD thermal process for coating float glass for energy protection, and (iii) a laser stimulated CVD process for continuously coating bundles of thin ceramic fibers. The feasibility of the concept with FTIR in-situ monitoring as a core technology has been demonstrated. FTIR monitoring sensibly reflects process conditions.

  13. Coal fly ash: the most powerful tool for sustainability of the concrete industry

    SciTech Connect

    Mehta, P.K.

    2008-07-01

    In the last 15 years the global cement industry has almost doubled its annual rate of direct emissions of carbon dioxide. These can be cut back by reducing global concrete consumption, reducing the volume of cement paste in mixtures and reducing the proportion of portland clinker in cement. It has recently been proved that use of high volumes of coal fly ash can produce low cost, durable, sustainable cement and concrete mixtures that would reduce the carbon footprint of both the cement and the power generation industries. 2 photos.

  14. Global emissions of hydrogen chloride and chloromethane from coal combustion, incineration and industrial activities: Reactive Chlorine Emissions Inventory

    NASA Astrophysics Data System (ADS)

    McCulloch, Archie; Aucott, Michael L.; Benkovitz, Carmen M.; Graedel, Thomas E.; Kleiman, Gary; Midgley, Pauline M.; Li, Yi-Fan

    1999-04-01

    Much if not all of the chlorine present in fossil fuels is released into the atmosphere as hydrogen chloride (HCl) and chloromethane (CH3Cl, methyl chloride). The chlorine content of oil-based fuels is so low that these sources can be neglected, but coal combustion provides significant releases. On the basis of national statistics for the quantity and quality of coal burned during 1990 in power and heat generation, industrial conversion and residential and commercial heating, coupled with information on the chlorine contents of coals, a global inventory of national HCl emissions from this source has been constructed. This was combined with an estimate of the national emissions of HCl from waste combustion (both large-scale incineration and trash burning) which was based on an estimate of the global quantity released from this source expressed per head of population. Account was taken of reduced emissions where flue gases were processed, for example to remove sulphur dioxide. The HCl emitted in 1990, comprising 4.6 ± 4.3 Tg Cl from fossil fuel and 2 ± 1.9 Tg Cl from waste burning, was spatially distributed using available information on point sources such as power generation utilities and population density by default. Also associated with these combustion sources are chloromethane emissions, calculated to be 0.075 ± 0.07 Tg as Cl (equivalent) from fossil fuels and 0.032 ± 0.023 Tg Cl (equivalent) from waste combustion. These were distributed spatially exactly as the HCl emissions, and a further 0.007 Tg Cl in chloromethane from industrial process activity was distributed by point sources.

  15. Source profiles of particulate matter emissions from a pilot-scale boiler burning North American coal blends.

    PubMed

    Lee, S W

    2001-11-01

    Recent awareness of suspected adverse health effects from ambient particulate matter (PM) emission has prompted publication of new standards for fine PM with aerodynamic diameter less than 2.5 microm (PM2.5). However, scientific data on fine PM emissions from various point sources and their characteristics are very limited. Source apportionment methods are applied to identify contributions of individual regional sources to tropospheric particulate concentrations. The existing industrial database developed using traditional source measurement techniques provides total emission rates only, with no details on chemical nature or size characteristics of particulates. This database is inadequate, in current form, to address source-receptor relationships. A source dilution system was developed for sampling and characterization of total PM, PM2.5, and PM10 (i.e., PM with aerodynamic diameter less than 10 pm) from residual oil and coal combustion. This new system has automatic control capabilities for key parameters, such as relative humidity (RH), temperature, and sample dilution. During optimization of the prototype equipment, three North American coal blends were burned using a 0.7-megawatt thermal (MWt) pulverized coal-fired, pilot-scale boiler. Characteristic emission profiles, including PM2.5 and total PM soluble acids, and elemental and carbon concentrations for three coal blends are presented. Preliminary results indicate that volatile trace elements such as Pb, Zn, Ti, and Se are preferentially enriched in PM2.5. PM2.5 is also more concentrated in soluble sulfates relative to total PM. Coal fly ash collected at the outlet of the electrostatic precipitator (ESP) contains about 85-90% PM10 and 30-50% PM2.5. Particles contain the highest elemental concentrations of Si and Al while Ca, Fe, Na, Ba, and K also exist as major elements. Approximately 4-12% of the materials exists as soluble sulfates in fly ash generated by coal blends containing 0.2-0.8% sulfur by mass

  16. Vulnerability of industrial natural-gas markets to electricity and coal: a context for R and D planning. Working paper

    SciTech Connect

    Lerner, M.O.; Kothari, V.S.; Salama, S.Y.

    1982-11-01

    Current trends in electric- and coal-technology developments and the outlook for natural-gas prices indicate the possibility of strong competition and possible natural-gas market-share losses in the industrial sector. The report develops an initial classification of industrial energy-consuming processes and estimates the extent to which future natural-gas consumption in each class is vulnerable to competition from electricity and coal. The discussion also addresses reasons why specific gas markets are considered vulnerable.

  17. Mineralogical and geochemical composition of particulate matter (PM10) in coal and non-coal industrial cities of Henan Province, North China

    NASA Astrophysics Data System (ADS)

    Song, Xiaoyan; Shao, Longyi; Zheng, Qiming; Yang, Shushen

    2014-06-01

    A total of 19 24-h PM10 samples, the 11 for a typical coal industrial city and 8 for a non-coal industrial city, were collected by a TSP-PM10 sampler during a serious and continuous haze event in Henan Province, North China. An X-ray diffractometer (XRD) was used to determine the mineralogy and a scanning electron microscope equipped with an energy-dispersive X-ray spectrometer (SEM-EDS) was used to determine the morphology and chemical composition of the PM10 samples. The crystalline phases that were identified by XRD mainly include sulfate (dominated by koktaite, boussingaultite, gypsum, etc.) and silicate (quartz and kaolinite) as well as small amount of chloride (sal-ammoniac). Silicate particles mainly originate from crust as well as waste dumps for coal industrial cities, and usually have an irregular shape, while sulfate particles occur as individual sheets or needles, and have an anthropogenic origin, which are the products of chemical reaction of preexisting carbonate with SO2 emitted by coal combustion. Nitrogen, S and Cl occurring in particulate matter are considered to have an anthropogenic origin due to their high enrichment factors, and their abundance in particulate matter is associated with coal industrial activities. Nitrogen mainly occurs as NH4+ in sulfate, as well as in small amount of organic matter. Sulfur mainly occurs as SO42 - in sulfate. Chlorine mainly occurs in chloride.

  18. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    SciTech Connect

    Yoon, R.-H.; Yan, E.S.; Luttrell, G.H.; Adel, G.T.

    1996-12-31

    It is the objective of the present project to further develop the triboelectrostatic separation (TES) process developed at the Federal Energy Technology Center and test the process at a proof-of-concept (POC) scale. This process has a distinct advantage over other coal cleaning processes in that it does not entail costly steps of dewatering. The POC-scale unit is to developed based on (1) the charge characteristics of coal and mineral matter that can be determined using the novel online tribocharge measuring device developed at Virginia Tech, and (2) the results obtained from bench-scale TES tests conducted on three different coals. At present, the project is at the stage of engineering design, which has three subtasks, Charger Tests, Separator Tests, and Final POC Design. Work accomplished during the current reporting period pertains to the first two subtasks.

  19. Industry perspectives on increasing the efficiency of coal-fired power generation

    SciTech Connect

    Torrens, I.M.; Stenzel, W.C.

    1997-12-31

    Independent power producers will build a substantial fraction of expected new coal-fired power generation in developing countries over the coming decades. To reduce perceived risk and obtain financing for their projects, they are currently building and plan to continue to build subcritical coal-fired plants with generating efficiency below 40%. Up-to-date engineering assessment leads to the conclusion that supercritical generating technology, capable of efficiencies of up to 45%, can produce electricity at a lower total cost than conventional plants. If such plants were built in Asia over the coming decades, the savings in carbon dioxide emissions over their lifetime would be measured in billions of tons. IPPs perceive supercritical technology as riskier and higher cost than conventional technology. The truth needs to be confirmed by discussions with additional experienced power engineering companies. Better communication among the interested parties could help to overcome the IPP perception issue. Governments working together with industry might be able to identify creative financing arrangements which can encourage the use of more efficient pulverized clean coal technologies, while awaiting the commercialization of advanced clean coal technologies like gasification combined cycle and pressurized fluidized bed combustion.

  20. Use of sorbents of hot-contact coal carbonization in the power industry

    SciTech Connect

    A.I. Blokhin; F.E. Keneman; A.V. Sklyarov; B.S. Fedoseev

    2003-11-15

    The many years of experience in the use of sorbents of hot-contact coal carbonization (HCCC) in the power industry is used for substantiation of their prospects for solving problems of power and materials saving and improving the reliability and safety of operation of power equipment. Results of tests of sorbents in systems of water conditioning of thermal power plants, cleaning of return condensates, mazut- and oil-contaminated process wastewaters, makeup water in heat networks, and biosorption cleaning of sewerage are presented. The sorption methods of cleaning are shown to have many advantages, to save expensive ion-exchange resins and reagents, to decrease the cost of desalinated water, and to prolong the service of power equipment. Comparative data are presented for basic commercial kinds of activated carbon and HCCC (sorbents activated crushed brown-coal coke (ABD)). The technical characteristics of sorbents of hot-contact coal carbonization are shown to be at the level of commercial sorbents or be higher at a much lower cost (by a factor of 2.5 - 3). It is shown that the creation of several HCCC installations with an output of 25 - 30 thousand tons of sorbents a year at coal-fired power plants will solve many water-cleaning problems of the 'EES Rossii' Co. ('The United Power Systems of Russia') and make it a monopolistic producer of activated carbon in the Russian market.

  1. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  2. H. R. 3413: Coal Industry Health Benefit Stabilization Act of 1989. Introduced in the House of Representatives, One Hundredth First Congress, First Session, October 5, 1989

    SciTech Connect

    Not Available

    1989-01-01

    The bill would provide for stabilization of the process of providing coal industry health benefits and would clarify Federal tax treatment of the transfer of excess coal pension plan assets to coal health plans. The bill describes the authorization of surplus assets from coal pension plan to coal health plan; the continuing obligation to contribute to multi-employer plans; and the relationship to collective bargaining agreements.

  3. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect

    X.H. Wang; J. Wiseman; D.J. Sung; D. McLean; William Peters; Jim Mullins; John Hugh; G. Evans; Vince Hamilton; Kenneth Robinette; Tim Krim; Michael Fleet

    1999-08-01

    Dewatering of ultra-fine (minus 150 {micro}m) coal slurry to less than 20% moisture is difficult using the conventional dewatering techniques. The main objective of the project was to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions and surfactants in combination for the dewatering of ultra-fine clean-coal slurries using various dewatering techniques on a proof-of-concept (POC) scale of 0.5 to 2 tons per hour. The addition of conventional reagents and the application of coal surface modification technique were evaluated using vacuum filtration, hyperbaric (pressure) filtration, ceramic plate filtration and screen-bowl centrifuge techniques. The laboratory and pilot-scale dewatering studies were conducted using the fine-size, clean-coal slurry produced in the column flotation circuit at the Powell Mountain Coal Company, St. Charles, VA. The pilot-scale studies were conducted at the Mayflower preparation plant in St. Charles, VA. The program consisted of nine tasks, namely, Task 1--Project Work Planning, Task 2--Laboratory Testing, Task 3--Engineering Design, Task 4--Procurement and Fabrication, Task 5--Installation and Shakedown, Task 6--System Operation, Task 7--Process Evaluation, Task 8--Equipment Removal, and Task 9--Reporting.

  4. Conceptual design study of a coal gasification combined-cycle powerplant for industrial cogeneration

    NASA Technical Reports Server (NTRS)

    Bloomfield, H. S.; Nelson, S. G.; Straight, H. F.; Subramaniam, T. K.; Winklepleck, R. G.

    1981-01-01

    A conceptual design study was conducted to assess technical feasibility, environmental characteristics, and economics of coal gasification. The feasibility of a coal gasification combined cycle cogeneration powerplant was examined in response to energy needs and to national policy aimed at decreasing dependence on oil and natural gas. The powerplant provides the steam heating and baseload electrical requirements while serving as a prototype for industrial cogeneration and a modular building block for utility applications. The following topics are discussed: (1) screening of candidate gasification, sulfur removal and power conversion components; (2) definition of a reference system; (3) quantification of plant emissions and waste streams; (4) estimates of capital and operating costs; and (5) a procurement and construction schedule. It is concluded that the proposed powerplant is technically feasible and environmentally superior.

  5. Conceptual design study of a coal gasification combined-cycle powerplant for industrial cogeneration

    NASA Astrophysics Data System (ADS)

    Bloomfield, H. S.; Nelson, S. G.; Straight, H. F.; Subramaniam, T. K.; Winklepleck, R. G.

    1981-03-01

    A conceptual design study was conducted to assess technical feasibility, environmental characteristics, and economics of coal gasification. The feasibility of a coal gasification combined cycle cogeneration powerplant was examined in response to energy needs and to national policy aimed at decreasing dependence on oil and natural gas. The powerplant provides the steam heating and baseload electrical requirements while serving as a prototype for industrial cogeneration and a modular building block for utility applications. The following topics are discussed: (1) screening of candidate gasification, sulfur removal and power conversion components; (2) definition of a reference system; (3) quantification of plant emissions and waste streams; (4) estimates of capital and operating costs; and (5) a procurement and construction schedule. It is concluded that the proposed powerplant is technically feasible and environmentally superior.

  6. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect

    R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

    2001-04-30

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would

  7. An explanation of large-scale coal and gas outbursts in underground coal mines: the effect of low-permeability zones on abnormally abundant gas

    NASA Astrophysics Data System (ADS)

    An, F. H.; Cheng, Y. P.

    2014-08-01

    Large-scale coal and gas outbursts pose a risk of fatal disasters in underground mines. Large-scale outbursts (outburst of coal and rock greater than 500 t) in recent years in China indicate that there is abundant gas in areas of outbursts containing large amounts of potential energy. The adequate sealing properties of the roof and floor of a coal seam are required for local abundant gas around the site of an outburst, but an annular low-permeability zone in a coal seam, which prevents the loss by gas migration through the coal seam itself, is also required. The distribution of coal gas with this annular zone of low permeability is described, and it is proposed that the annular zone of low permeability creates conditions for confining the coal gas. The effect of this low-permeability zone on the gas distribution is analyzed after allowing for simplifications in the model. The results show that the permeability and length of the low-permeability zone have a great impact on the gas distribution, and the permeability is required to be several orders of magnitude less than that of normal coal and enough length is also in demand. A steep gradient of gas pressure in the low-permeability zone and the high-pressure gas in the abundant zone of gas can promote coal mass failure and coal wall deformation, thereby accelerating the coal and gas outburst. The high-pressure gas in abundant zone of gas will lead to a large-scale outburst if an outburst occurs.

  8. South Africa, a new perspective: How the coal industry of RSA looks to an observer from the USA

    SciTech Connect

    Arthur, S.P.

    1994-09-01

    A microcosm of what was, what is, and hopefully what will be, is embodied in South Africa`s coal industry-the sixth largest in the world, the third largest in coal exports behind the United States and Australia, and the second largest in the world`s steam coal trade behind Australia. Mining is the international, economic life blood of South Africa. In total, the country exports 60 minerals to 80 countries, providing on a raw basis for 43% of the nation`s international trade, and as much as 60% when beneficiated products are included. The nation`s coal fields lie in the northeastern section of the country, running south from the Botswana-Zimbabwe-Mozambique borders, principally in the Transvaal, Natal, and Orange Free State provinces. The coal seams run in thickness from 2.5 to 8 m, with an average overburden thickness of 80 m. The coal industry provides 83% of the country`s commercial energy and 52% of all the electric power consumed on the entire continent. Seen from the air, the veld around Johannesburg is dotted with power plants-virtually all coal-fired. There is only one nuclear plant and two hydroelectric produced in South Africa comes from Eskom, the state-owned utility, and 90% total comes from coal-fired units.

  9. Pilot scale single stage fine coal dewatering and briquetting process. Technical report, September 1--November 30, 1995

    SciTech Connect

    Wilson, J.W.; Ding, Y.; Honaker, R.Q.

    1995-12-31

    The primary goal of the current coal preparation research is to reduce the ash and sulfur content from coal, using fine grinding and various coal cleaning processes to separate finely disseminated mineral matter and pyrite from coal. Small coal particles are produced by the grinding operation, thus the ultrafine coal becomes very difficult to dewater. In addition, the ultrafine coal also creates problems during its transportation, storage and handling at utility plants. The current research is seeking to combine ultrafine coal dewatering and briquetting processes into a single stage operation, using hydrophobic binders as coal dewatering and binding reagents with the help of a compaction device. From previous tests, it has been found that coal pellets with a moisture content of less than 15% and good wear and water resistance can be successfully fabricated at pressures of less than 6,000 psi using a lab scale ram extruder. The primary objective of the research described in this quarter has been to extend the lab scale ultrafine coal dewatering and briquetting process into a pilot scale operation, based on the test data obtained from earlier research. A standard roller briquetting machine was used to dewater fine coal-binder mixtures during the briquetting process. The operating parameters, including moisture content of feed, feed rate, and roller speed, were evaluated on the basis of the performance of the briquettes. Briquettes fabricated at rates of up to 108 pellets per minute exhibited satisfactory water and wear resistance, i.e., less than 7.5% cured moisture and less than 8.3% weight loss after 6 min. of tumbling. Also, coal-binder samples with moisture contents of 40 percent have been successfully dewatered and briquetted. Briquetting of fine coal was possible under current feeding conditions, however, a better feeding system must be designed to further improve the quality of dewatered coal briquettes.

  10. POC-SCALE TESTING OF OIL AGGLOMERATION TECHNIQUES AND EQUIPMENT FOR FINE COAL PROCESSING

    SciTech Connect

    1998-01-01

    This report covers the technical progress achieved from October 1, 1997 to December 31, 1997 on the POC-Scale Testing of Oil Agglomeration Techniques and Equipment for Fine Coal Processing project. Experimental test procedures and the results related to the processing of coal fines originating from process streams generated at the Shoal Creek Mine preparation plant, owned and operated by the Drummond Company Inc. of Alabama, are described. Two samples of coal fines, namely Cyclone Overflow and Pond Fines were investigated. The batch test results showed that by applying the Aglofloat technology a significant ash removal might be achieved at a very high combustible matter recovery: · for the Cyclone Overflow sample the ash reduction was in the range 50 to 55% at combustible matter recovery about 98% · for the Pond Fines sample the ash reduction was up to 48% at combustible matter recovery up to 85%. Additional tests were carried out with the Alberta origin Luscar Mine coal, which will be used for the parametric studies of agglomeration equipment at the 250 kg/h pilot plant. The Luscar coal is very similar to the Mary Lee Coal Group (processed at Shoal Creek Mine preparation plant) in terms of rank and chemical composition.

  11. COAL: DRDF (DENSIFIED REFUSE DERIVED FUEL) DEMONSTRATION TEST IN AN INDUSTRIAL SPREADER STOKER BOILER. USE OF COAL: DRDF BLENDS IN STOKER-FIRED BOILERS. VOLUME I

    EPA Science Inventory

    This study program has the overall objective of evaluating boiler performance and environmental feasibility when combusting densified forms of refuse derived fuels (dRDF) blended with coal and fired in a modern industrial spreader stoker-fired boiler. The results reported herein ...

  12. Managing produced water from coal seam gas projects: implications for an emerging industry in Australia.

    PubMed

    Davies, Peter J; Gore, Damian B; Khan, Stuart J

    2015-07-01

    This paper reviews the environmental problems, impacts and risks associated with the generation and disposal of produced water by the emerging coal seam gas (CSG) industry and how it may be relevant to Australia and similar physical settings. With only limited independent research on the potential environmental impacts of produced water, is it necessary for industry and government policy makers and regulators to draw upon the experiences of related endeavours such as mining and groundwater extraction accepting that the conclusions may not always be directly transferrable. CSG is widely touted in Australia as having the potential to provide significant economic and energy security benefits, yet the environmental and health policies and the planning and regulatory setting are yet to mature and are continuing to evolve amidst ongoing social and environmental concerns and political indecision. In this review, produced water has been defined as water that is brought to the land surface during the process of recovering methane gas from coal seams and includes water sourced from CSG wells as well as flowback water associated with drilling, hydraulic fracturing and gas extraction. A brief overview of produced water generation, its characteristics and environmental issues is provided. A review of past lessons and identification of potential risks, including disposal options, is included to assist in planning and management of this industry. PMID:25783163

  13. Temporal trends and spatial variation characteristics of primary air pollutants emissions from coal-fired industrial boilers in Beijing, China.

    PubMed

    Xue, Yifeng; Tian, Hezhong; Yan, Jing; Zhou, Zhen; Wang, Junling; Nie, Lei; Pan, Tao; Zhou, Junrui; Hua, Shenbing; Wang, Yong; Wu, Xiaoqing

    2016-06-01

    Coal-fired combustion is recognized as a significant anthropogenic source of atmospheric compounds in Beijing, causing heavy air pollution events and associated deterioration in visibility. Obtaining an accurate understanding of the temporal trends and spatial variation characteristics of emissions from coal-fired industrial combustion is essential for predicting air quality changes and evaluating the effectiveness of current control measures. In this study, an integrated emission inventory of primary air pollutants emitted from coal-fired industrial boilers in Beijing is developed for the period of 2007-2013 using a technology-based approach. Future emission trends are projected through 2030 based on current energy-related and emission control policies. Our analysis shows that there is a general downward trend in primary air pollutants emissions because of the implementation of stricter local emission standards and the promotion by the Beijing municipal government of converting from coal-fired industrial boilers to gas-fired boilers. However, the ratio of coal consumed by industrial boilers to total coal consumption has been increasing, raising concerns about the further improvement of air quality in Beijing. Our estimates indicate that the total emissions of PM10, PM2.5, SO2, NOx, CO and VOCs from coal-fired industrial boilers in Beijing in 2013 are approximately 19,242 t, 13,345 t, 26,615 t, 22,965 t, 63,779 t and 1406 t, respectively. Under the current environmental policies and relevant energy savings and emission control plans, it may be possible to reduce NOx and other air pollutant emissions by 94% and 90% by 2030, respectively, if advanced flue gas purification technologies are implemented and coal is replaced with natural gas in the majority of existing boilers. PMID:27023281

  14. PROCEEDINGS: EPA/INDUSTRY FORUM ON COAL LIQUEFACTION HELD AT CHICAGO, ILLINOIS ON OCTOBER 23 AND 24, 1979

    EPA Science Inventory

    The proceedings document presentations made at the EPA/Industry Forum on Coal Liquefaction, October 23 and 24, 1979, in Chicago. The forum brought together representatives of government and industry with the goal of sharing information and increasing cooperation between the two g...

  15. Water-carbon trade-off in China's coal power industry.

    PubMed

    Zhang, Chao; Anadon, Laura Diaz; Mo, Hongpin; Zhao, Zhongnan; Liu, Zhu

    2014-10-01

    The energy sector is increasingly facing water scarcity constraints in many regions around the globe, especially in China, where the unprecedented large-scale construction of coal-fired thermal power plants is taking place in its extremely arid northwest regions. As a response to water scarcity, air-cooled coal power plants have experienced dramatic diffusion in China since the middle 2000s. By the end of 2012, air-cooled coal-fired thermal power plants in China amounted to 112 GW, making up 14% of China's thermal power generation capacity. But the water conservation benefit of air-cooled units is achieved at the cost of lower thermal efficiency and consequently higher carbon emission intensity. We estimate that in 2012 the deployment of air-cooled units contributed an additional 24.3-31.9 million tonnes of CO2 emissions (equivalent to 0.7-1.0% of the total CO2 emissions by China's electric power sector), while saving 832-942 million m(3) of consumptive water use (about 60% of the total annual water use of Beijing) when compared to a scenario with water-cooled plants. Additional CO2 emissions from air-cooled plants largely offset the CO2 emissions reduction benefits from Chinese policies of retiring small and outdated coal plants. This water-carbon trade-off is poised to become even more significant by 2020, as air-cooled units are expected to grow by a factor of 2-260 GW, accounting for 22% of China's total coal-fired power generation capacity. PMID:25215622

  16. Synthesis of hydroxy sodalite from coal fly ash using waste industrial brine solution.

    PubMed

    Musyoka, Nicholas M; Petrik, Leslie F; Balfour, Gillian; Gitari, Wilson M; Hums, Eric

    2011-01-01

    The effect of using industrial waste brine solution instead of ultra pure water was investigated during the synthesis of zeolites using three South African coal fly ashes as Si feedstock. The high halide brine was obtained from the retentate effluent of a reverse osmosis mine water treatment plant. Synthesis conditions applied were; ageing of fly ash was at 47 ° C for 48 hours, and while the hydrothermal treatment temperature was set at 140 ° C for 48 hours. The use of brine as a solvent resulted in the formation of hydroxy sodalite zeolite although unconverted mullite and hematite from the fly ash feedstock was also found in the synthesis product. PMID:22175873

  17. Use of Sorbents of Hot-Contact Coal Carbonization in the Power Industry

    SciTech Connect

    Blokhin, A. I.; Keneman, F. E.; Sklyarov, A. V.; Fedoseev, B. S.

    2003-11-15

    The many years of experience in the use of sorbents of hot-contact coal carbonization in the power industry is used for substantiation of their prospects for solving problems of power and materials saving and improving the reliability and safety of operation of power equipment. Results of tests of sorbents in systems of water conditioning of thermal power plants, cleaning of return condensates, mazut- and oil-contaminated process wastewaters, makeup water in heat networks, and biosorption cleaning of sewerage are presented. The sorption methods of cleaning are shown to have many advantages, to save expensive ion-exchange resins and reagents, to decrease the cost of desalinated water, and to prolong the service of power equipment. Comparative data are presented for basic commercial kinds of activated carbon and HCCC sorbents (ABD). The technical characteristics of sorbents of hot-contact coal carbonization are shown to be at the level of commercial sorbents or be higher at a much lower cost (by a factor of 2.5 - 3). It is shown that the creation of several HCCC installations with an output of 25 - 30 thousand tons of sorbents a year at coal-fired power plants will solve many water-cleaning problems of the 'EES Rossii' Co. ('The United Power Systems of Russia') and make it a monopolistic producer of activated carbon in the Russian market.

  18. Cost-effectiveness Analysis on Measures to Improve China's Coal-fired Industrial Boiler

    DOE PAGESBeta

    Liu, Manzhi; Shen, Bo; Han, Yafeng; Price, Lynn; Xu, Mingchao

    2015-08-01

    Tackling coal-burning industrial boiler is becoming one of the key programs to solve the environmental problem in China. Assessing the economics of various options to address coal-fired boiler is essential to identify cost-effective solutions. This paper discusses our work in conducting a cost-effectiveness analysis on various types of improvement measures ranging from energy efficiency retrofits to switch from coal to other fuels in China. Sensitivity analysis was also performed in order to understand the impacts of some economic factors such as discount rate and energy price on the economics of boiler improvement options. The results show that nine out ofmore » 14 solutions are cost-effective, and a lower discount rate and higher energy price will result in more energy efficiency measures being cost-effective. Both monetary and non-monetary barriers to energy-efficiency improvement are discussed and policies to tackle these barriers are recommended. Our research aims at providing a methodology to assess cost-effective solutions to boiler problems.« less

  19. Cost-effectiveness Analysis on Measures to Improve China's Coal-fired Industrial Boiler

    SciTech Connect

    Liu, Manzhi; Shen, Bo; Han, Yafeng; Price, Lynn; Xu, Mingchao

    2015-08-01

    Tackling coal-burning industrial boiler is becoming one of the key programs to solve the environmental problem in China. Assessing the economics of various options to address coal-fired boiler is essential to identify cost-effective solutions. This paper discusses our work in conducting a cost-effectiveness analysis on various types of improvement measures ranging from energy efficiency retrofits to switch from coal to other fuels in China. Sensitivity analysis was also performed in order to understand the impacts of some economic factors such as discount rate and energy price on the economics of boiler improvement options. The results show that nine out of 14 solutions are cost-effective, and a lower discount rate and higher energy price will result in more energy efficiency measures being cost-effective. Both monetary and non-monetary barriers to energy-efficiency improvement are discussed and policies to tackle these barriers are recommended. Our research aims at providing a methodology to assess cost-effective solutions to boiler problems.

  20. Study of application of ERTS-A imagery to fracture-related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.; Leshendok, T. V.

    1974-01-01

    The author has identified the following significant results. The mine refuse inventory maps were prepared in response to a need by both the State and the coal industry. The lack of information on the scope of the problem handicapped all people concerned in drafting realistic legislation for a severance tax on coal production to raise funds for restoration of refuse sites. The inventory was conducted rapidly and economically, and demonstrated the benefits which can be derived through remote sensing methods.

  1. Capital and the state in regional economic development: the case of the coal industry in central Appalachia

    SciTech Connect

    Duncan, C.L.

    1985-01-01

    This study examines theories of development policy to assess their relevance for the problems of persistently poor regions within advanced capitalist societies. The central premises of three sets of theories are explored using a multi-method approach that combines quantitative analysis of the impact of growth in the coal industry in rural Kentucky between 1960 and 1980, and qualitative analysis of the perspectives of coal industry executives on development in the coal fields. Theories are categorized into neoclassical, redistributionist and critical paradigms because this typology clarifies the differences in the role of capital and the state in development strategies. Results of analyses of economic and social change in rural Kentucky challenge neoclassical development theory. Greater economic growth in coal counties did not bring greater social progress. The analysis supports the redistributionist and critical theorists' thesis that widespread distribution of economic benefits is important to development. Counties with better distribution of income and work had better conditions in 1980, and coal counties have the greatest economic inequality. Comments of coal industry executives confirm the critical theorists' argument that capital resists State policies to redistribute economic surplus for investment in development.

  2. A coal-fired combustion system for industrial process heating applications

    SciTech Connect

    Not Available

    1992-09-03

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Phase III development contract DE-AC22-91PC91161 for a Coal-Fired Combustion System for Industrial Process Heating Applications'' is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec's Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  3. Integrated process control for recirculating cooling water treatment in the coal chemical industry.

    PubMed

    Pei, Y S; Guo, W; Yang, Z F

    2011-01-01

    This work focused on the integrated process of the recirculating cooling water (RCW) treatment to achieve approximate zero emission in the coal chemical industry. The benefits of fractional and comprehensive RCW treatment were quantified and qualified by using a water and mass balance approach. Limits of cycle of concentrations and some encountered bottlenecks were used to ascertain set target limits for different water sources. Makeup water was mixed with water produced from reverse osmosis (RO) in the proportion of 6:4, which notably reduced salts discharge. Side infiltration, which settled down suspended solids, can reduce energy consumption by over 40%. An automated on-line monitoring organic phosphorus inhibitor feed maintains the RCW system stability in comparison to the manual feed. Two-step electrosorb technology (EST) instead of an acid feed can lead cycle of concentration of water to reach 7.0. The wastewater from RO, EST and filter was transferred into a concentration treatment system where metallic ions were adsorbed by permanent magnetic materials. Separation of water and salts was completed by using a magnetic disc separator. Applying the integrated process in a coal chemical industry, a benefit of 1.60 million Yuan annually in 2 years was gained and approximate zero emission was achieved. Moreover, both technical and economic feasibility were demonstrated in detail. PMID:21977648

  4. THE SCALE-UP OF LARGE PRESSURIZED FLUIDIZED BEDS FOR ADVANCED COAL FIRED PROCESSES

    SciTech Connect

    Leon Glicksman; Hesham Younis; Richard Hing-Fung Tan; Michel Louge; Elizabeth Griffith; Vincent Bricout

    1998-04-30

    Pressurized fluidization is a promising new technology for the clean and efficient combustion of coal. Its principle is to operate a coal combustor at high inlet gas velocity to increase the flow of reactants, at an elevated pressure to raise the overall efficiency of the process. Unfortunately, commercialization of large pressurized fluidized beds is inhibited by uncertainties in scaling up units from the current pilot plant levels. In this context, our objective is to conduct a study of the fluid dynamics and solid capture of a large pressurized coal-fired unit. The idea is to employ dimensional similitude to simulate in a cold laboratory model the flow in a Pressurized Circulating Fluid Bed ''Pyrolyzer,'' which is part of a High Performance Power System (HIPPS) developed by Foster Wheeler Development Corporation (FWDC) under the DOE's Combustion 2000 program.

  5. Mercury emissions control in coal combustion systems using potassium iodide: bench-scale and pilot-scale studies

    SciTech Connect

    Ying Li; Michael Daukoru; Achariya Suriyawong; Pratim Biswas

    2009-01-15

    Bench- and pilot-scale experiments were conducted using potassium iodide (KI) for capture and removal of Hg in air and coal combustion exhaust. Two bench-scale reactor systems were used: (1) a packed-bed reactor (PBR) packed with granular or powder KI and (2) an aerosol flow reactor (AFR) with injection of KI particles. It was found that a higher temperature, a higher concentration of KI, and a longer gas residence time resulted in a higher Hg removal efficiency. A 100% Hg removal was achieved in the PBR above 300{sup o}C using 0.5 g of powder KI and in the AFR above 500{sup o}C with a KI/Hg molar ratio of 600 at a 5.8 s residence time. The low KI injection ratio relative to Hg indicated that KI is highly effective for Hg removal in air. Formation of I{sub 2} vapor by the oxidation of KI by O{sub 2} at high temperatures, which then reacts with Hg to produce HgI{sub 2}, was identified as the pathway for removal. The pilot-scale experiments were conducted in a 160 kW pulverized coal combustor. KI was introduced in two ways: as a powder mixed with coal and by spraying KI solution droplets into the flue gas. In both cases the Hg removal efficiency increased with an increase in the feed rate of KI. Mixing KI powder with coal was found to be more effective than spraying KI into the flue gas. The Hg removal by KI was less efficient in the pilot-scale tests than in the bench-scale tests probably due to certain flue gas components reacting with KI or I{sub 2}. Hg speciation measurements in both bench- and pilot-scale experiments indicated no oxidized mercury in the gas phase upon introduction of KI, indicating that the oxidation product HgI2 was captured in the particulate phase. This is very beneficial in coal-fired power plants equipped with electrostatic precipitators where particulate-bound Hg can be efficiently removed. 27 refs., 8 figs., 4 tabs.

  6. Corrosivities in a pilot-scale combustor of a British and two Illinois coals with varying chlorine contents

    USGS Publications Warehouse

    Chou, I.-Ming; Lytle, J.M.; Kung, S.C.; Ho, K.K.

    2000-01-01

    Many US boiler manufacturers have recommended limits on the chlorine (Cl) content (< 0.25% or < 0.3%) of coals to be used in their boilers. These limits were based primarily on extrapolation of British coal data to predict the probable corrosion behavior of US coals. Even though Cl-related boiler corrosion has not been reported by US utilities burning high-Cl Illinois coals, the manufacturer's limits affect the marketability of high-Cl Illinois coals. This study measured the relative rates of corrosion caused by two high-Cl coals (British and Illinois) and one low-Cl Illinois baseline coal under identical pilot-scale combustion conditions for about 1000 h which gave reliable comparisons. Temperatures used reflected conditions in boiler superheaters. The corrosion probes were fabricated from commercial alloy 304SS frequently used at the hottest superheater section of utility boilers. The results showed no evidence of direct correlation between the coal chlorine content and rate of corrosion. A correlation between the rate of corrosion and the metal temperature was obvious. The results suggested that the different field histories of corrosivity from burning high-Cl Illinois coal and high-Cl British coal occurred because of different metal temperatures operated in US and UK utility boilers. The results of this study can be combined into a database, which could be used for lifting the limits on chlorine contents of coals burned in utility boilers in the US.

  7. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect

    R.-H. Yoon; G.H. Luttrell; B. Luvsansambuu; A.D. Walters

    2000-10-01

    Work continued during the past quarter to improve the performance of the POC-scale unit. For the charging system, a more robust ''turbocharger'' has been fabricated and installed. All of the internal components of the charger have been constructed from the same material (i.e., Plexiglas) to prevent particles from contacting surfaces with different work functions. For the electrode system, a new set of vinyl-coated electrodes have been constructed and tested. The coated electrodes (i) allow higher field strengths to be tested without of risk of arcing and (ii) minimize the likelihood of charge reversal caused by particles colliding with the conducting surfaces of the uncoated electrodes. Tests are underway to evaluate these modifications. Several different coal samples were collected for testing during this reporting period. These samples included (i) a ''reject'' material that was collected from the pyrite trap of a pulverizer at a coal-fired power plant, (ii) an ''intermediate'' product that was selectively withdrawn from the grinding chamber of a pulverizer at a power plant, and (iii) a run-of-mine feed coal from an operating coal preparation plant. Tests were conducted with these samples to investigate the effects of several key parameters (e.g., particle size, charger type, sample history, electrode coatings, etc.) on the performance of the bench-scale separator.

  8. Ever-shifting ground: work and labor relations in the anthracite coal industry, 1968-1903

    SciTech Connect

    Blatz, P.K.

    1987-01-01

    This dissertation traces the work experience of the mine workers of the anthracite coal industry of northeastern Pennsylvania from the final three decades of the nineteenth century, during which several attempts to unionize the mines failed, to the industry-wide anthracite strikes of 1900 and 1902, which brought to a successful conclusion the United Mine Workers' drive for unionization. The correspondence of corporate executives shows that a pervasive philosophy of antiunionism characterized management's approach to labor relations. During the nonunion era, the state, rather than any labor organization, served as the most effective counterpoise to corporate power through its enactment of an extensive code of mining regulation. Nevertheless, mine workers still confronted a perilous workplace which, along with chronic underemployment and an utterly unsystematized congeries of work rules, combined to create a work experience fraught with insecurity. The United Mine Workers proposed an industry-wide contract as the means to solve these problems, and effective organization as the prod to force the corporations to negotiate such a contract. However, the union succeeded in its organizing only in the wake of numerous wildcat strikes protesting the many manifestations of the paternalistic, individualized style of labor relations which had always characterized the industry.

  9. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 2

    SciTech Connect

    Miller, Bruce; Winton, Shea

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the

  10. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 3

    SciTech Connect

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the

  11. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 4

    SciTech Connect

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to

  12. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 1

    SciTech Connect

    Miller, Bruce; Winton, Shea

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the

  13. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 5

    SciTech Connect

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to

  14. Occupational health and safety regulation in the coal mining industry: public health at the workplace.

    PubMed

    Weeks, J L

    1991-01-01

    The strategy for preventing occupational disease and injury in the coal mining industry employs several elements. Standards are set and enforced; technical assistance, research, and development are provided; and surveillance is conducted. Compensation for black lung is a vivid reminder of the consequences of failure to prevent disease. And, workers are represented by a union that encourages active participation in all aspects of this strategy. There are significant problems in each of these elements. Regulatory reform threatens to weaken many standards, there is a decline in government research budgets, surveillance is not well monitored, and compensation for black lung is significantly more difficult to obtain now than in the past. Moreover, the conservative governments of the past decade are not friendly towards unions. Nevertheless, the fundamental structure of disease and injury prevention remains intact and, more importantly, it has a historical record of success. The Mine Safety and Health Act provided for a wide array of basic public health measures to prevent occupational disease and injury in the mining industry. These measures have been effective in reducing both risk of fatal injury and exposure to respirable coal mine dust. They are also associated with temporary declines in productivity. In recent years, however, productivity has increased, while risk of fatal injury and exposure to respirable dust have declined. At individual mines, productivity with longwall mining methods appear to be associated with increases in exposure to respirable dust. These trends are not inconsistent with similar trends following implementation of regulations by OSHA. When OSHA promulgated regulations to control exposure to vinyl chloride monomer, enforcement of the standard promoted significant efficiencies in vinyl chloride production (5). Similarly, when OSHA promulgated its standard regulating exposure to cotton dust, this effort provoked modernization in the cotton

  15. Semi industrial scale RVNRL preparation, products manufacturing and properties

    NASA Astrophysics Data System (ADS)

    Zin, Wan Manshol Bin W.

    1998-06-01

    Natural rubber latex vulcanisation by radiation aims towards the preparation of prevulcanised natural rubber latex in the name of RVNRL for use to produce chemical-free and environment-friendly latex products. Scale up RVNRL preparation is proven possible when a semi-commercial latex irradiator was commissioned in MINT in March 1996. The plant is designed to irradiate up to 6 000 cubic meters per annum of natural rubber latex. RVNRL has the required properties and successfully used on industrial scale production of quality gloves and balloons.

  16. Development and scale-up of particle agglomeration processes for coal beneficiation

    NASA Astrophysics Data System (ADS)

    Shen, Meiyu

    The development of two modified agglomeration processes for coal beneficiation is presented separately in Parts I and II of this dissertation. Part I is based on research which was conducted to study the mechanism and characteristics of a gas-promoted oil agglomeration process. Part II is based on research which was carried out to develop a newer and more innovative method for agglomerating coal particles with microscopic gas bubbles in aqueous suspensions. In Part I, the development of a gas-promoted oil agglomeration process for cleaning coal was carried out with scale model mixing systems in which aqueous suspensions of ultrafine coal particles were treated with a liquid hydrocarbon and a small amount of air. The resulting agglomerates were recovered by screening. During batch agglomeration tests the progress of agglomeration was monitored by observing changes in agitator torque in the case of concentrated suspension. A key parameter turned out to be the minimum time te required to produce compact spherical agglomerates. Other important parameters included the projected area mean particle diameter of the agglomerates recovered at the end of a test as well as the ash content and yield of agglomerates. Batch agglomeration tests were conducted with geometrically similar mixing tanks which ranged in volume from 0.346 to 11.07 liters. It was shown that gas bubbles trigger the process of agglomeration and participate in a very complex mechanism involving the interaction of particles, oil droplets, and gas bubbles. The process takes place in stages involving dispersion of oil and gas, flocculation, coagulation, and agglomerate building. Numerous agglomeration tests were conducted with two kinds of coal in concentrated suspensions to determine the important characteristics of the process and to study the effects of the following operating parameters: i-octane concentration, air concentration, particle concentration, tank diameter, impeller diameter, and impeller speed

  17. Large scale solubilization of coal and bioconversion to utilizable energy. Fifth quarterly technical report, January 1, 1995--March 31, 1995

    SciTech Connect

    Mishra, N.C.

    1995-12-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, we plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. We also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  18. Large scale solubilization of coal and bioconversion to utilizable energy. Quarterly report, October 1--December 31, 1996

    SciTech Connect

    Mishra, N.C.

    1996-12-22

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, the author plans to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. He also plans to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  19. Impending impacts of Title III and Title V of the Clean Air Act Amendments of 1990 on the coal industry

    SciTech Connect

    Kerch, R.L.

    1994-12-31

    The coal industry has already begun to feel the affects of the acid deposition title, particularly in Illinois. Two challenges to the producers and sellers of coal; i.e., (1) Title III, Hazardous Air Pollutants and what is in store for customers, and (2) Title V, Operating Permits, which may affect production facilities are discussed. The utilities are temporarily exempted from Title III. The Great Waters report suggests that mercury will be regulated, and it looks like risk assessments will be based on coal analysis rather than on actual emission measurements. Stack sampling is difficult, expensive and slow. Coal cleaning is important in reducing trace elements. Electrostatic precipitators also remove trace elements. ESPs are less effective for mercury and selenium because they are emitted in the gas phase. FGD can remove hazardous air pollutants, but it is not well documented.

  20. EVALUATION OF THE IMPACT OF CHLORINE ON MERCURY OXIDATION IN A PILOT-SCALE COAL COMBUSTION--THE EFFECT OF COAL BLENDING

    EPA Science Inventory

    Coal-fired power plants are a major source of mercury (Hg) released into the environment and the utility industry is currently investigating options to reduce Hg emissions. The EPA Clean Air Mercury Rule (CAMR) depends heavily on the co-benefit of mercury removal by existing and ...

  1. Evaluation of water resources around Barapukuria coal mine industrial area, Dinajpur, Bangladesh

    NASA Astrophysics Data System (ADS)

    Howladar, M. Farhad; Deb, Pulok Kanti; Muzemder, A. T. M. Shahidul Huqe; Ahmed, Mushfique

    2014-09-01

    Water is a very important natural resource which can be utilized in renewable or non-renewable forms but before utilizing, the evaluation of the quality of this resource is crucial for a particular use. However, the problems of water quality are more severe in areas where the mining and mineral processes' industries are present. In mining processes, several classes of wastes are produced which may turn into ultimately the sources of water quality and environmental degradation. In consequences, the evaluations of water quality for livestock, drinking, irrigation purposes and environmental implications have been carried out around the Barapukuria Coal Mining Industry under different methods and techniques such as primarily the field investigation; secondly the laboratory chemical analysis and thirdly justified the suitability of the laboratory analysis with statistical representation and correlation matrix, Schoeller plot, Piper's Trilinear diagram, Expanded Durov diagram, Wilcox diagram, US salinity diagram, Doneen's chart and others. The results of all surface and ground water samples analysis show that the characteristics and concentrations of all the major physical and chemical parameters such as pH, EC, TDS, Na+, K+, Ca2+, Mg2+, Fetotal, Cl-, HCO3 -, CO3 2- and SO4 2- are varied from one sample to other but well analogous with the WHO and EQS standard limit for all purposes in the area where the abundance of the major ions is as follows: Ca2+ > Na+ > Mg2+ > K+ > Fetotal = HCO3 - > SO4 2- > Cl- > CO3 2-. The graphical exposition of analytical data demonstrates two major hydrochemical facies for example: calcium-bicarbonate (Ca2+- HCO3 -) and magnesium-bicarbonate (Mg2+- HCO3 -) type facies which directly support the shallow recently recharged alkaline water around the industry. The calculated values for the evaluation classification of water based on TDS, Na%, EC, SAR, PI, RSC, MH, and TH replicate good to excellent use of water for livestock, drinking and

  2. Performance of a high efficiency advanced coal combustor. Task 2, Pilot scale combustion tests: Final report

    SciTech Connect

    Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M.

    1989-12-01

    Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R&D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the ``primary act,`` and three further annuli for the supply of the ``secondary air.`` The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

  3. Development and testing of commercial-scale, coal-fired combustion systems: Phase 3

    SciTech Connect

    Not Available

    1992-01-01

    The US Department of Energy's Pittsburgh Energy Technology Center (PETC) is actively pursuing the development and testing of coal-fired combustion systems for residential, commercial, and industrial market sectors. In response, MTCI initiated the development of a new combustor technology based on the principle of pulse combustion under the sponsorship of PETC (Contract No. AC22-83PC60419). The initial pulse combustor development program was conducted in three phases (MTCI, Development of a Pulsed Coal Combustor Fired with CWM, Phase III Final Report, DOE Contract No. AC22-83PC60419, November 1986). Phase I included a review of the prior art in the area of pulse combustion and the development of pulse combustor design concepts. It led to the conclusion that pulse combustors offer technical and base-of-operation advantages over conventional burners and also indicated favorable economics for replacement of oil- and gas-fired equipment.

  4. Analysis of atomic scale chemical environments of boron in coal by 11B solid state NMR.

    PubMed

    Takahashi, Takafumi; Kashiwakura, Shunsuke; Kanehashi, Koji; Hayashi, Shunichi; Nagasaka, Tetsuya

    2011-02-01

    Atomic scale chemical environments of boron in coal has been studied by solid state NMR spectroscopy including magic angle spinning (MAS), satellite transition magic angle spinning (STMAS), and cross-polarization magic angle spinning (CPMAS). The (11)B NMR spectra can be briefly classified according to the degree of coalification. On the (11)B NMR spectra of lignite, bituminous, and sub-bituminous coals (carbon content of 70-90mass%), three sites assigned to four-coordinate boron ([4])B with small quadrupolar coupling constants (≤0.9 MHz) are observed. Two of the ([4])B sites in downfield are considered organoboron complexes with aromatic ligands, while the other in the most upper field is considered inorganic tetragonal boron (BO(4)). By contrast, on the (11)B NMR spectra of blind coal (carbon content >90mass%), the ([4])B which substitutes tetrahedral silicon of Illite is observed as a representative species. It has been considered that the organoboron is decomposed and released from the parent phase with the advance of coal maturation, and then the released boron reacts with the inorganic phase to substitute an element of inorganic minerals. Otherwise boron contained originally in inorganic minerals might remain preserved even under the high temperature condition that is generated during coalification. PMID:21175186

  5. Fields of Coal: An analysis of industry and sedimentology in Dolores, Texas

    NASA Astrophysics Data System (ADS)

    Oaden, A.; Besonen, M. R.

    2013-12-01

    characterize the sediments is underway. Basic conclusions indicate the present environment to be minimally affected by the coal operations and resulting tipple pile, but with a large variance over time in mineralogy and composition of sediment, with further research necessary to determine the full effects of industry in the area.

  6. A coal-fired combustion system for industrial process heating applications

    SciTech Connect

    Not Available

    1993-01-29

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashesand industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, a majority of the effort was spent relining the separator/reservoir and the cyclone melter. The relinings were completed, the cyclonemelter was reinstalled, and the test system was returned to operational status. The wet ESP was delivered and placed on its foundation. The focus during the upcoming months will be completing the integration ofthe wet ESP and conducting the first industrial proof-of-concept test. The other system modifications are well underway with the designs of the recuperator installation and the batch/coal feed system progressing smoothly. The program is still slightly behind the original schedule but it is anticipated that it will be back on schedule by the end of the year. The commercialization planning is continuing with the identification of seven potential near-term commercial demonstration opportunities.

  7. Identifying Catchment-Scale Predictors of Coal Mining Impacts on New Zealand Stream Communities

    NASA Astrophysics Data System (ADS)

    Clapcott, Joanne E.; Goodwin, Eric O.; Harding, Jon S.

    2016-03-01

    Coal mining activities can have severe and long-term impacts on freshwater ecosystems. At the individual stream scale, these impacts have been well studied; however, few attempts have been made to determine the predictors of mine impacts at a regional scale. We investigated whether catchment-scale measures of mining impacts could be used to predict biological responses. We collated data from multiple studies and analyzed algae, benthic invertebrate, and fish community data from 186 stream sites, including un-mined streams, and those associated with 620 mines on the West Coast of the South Island, New Zealand. Algal, invertebrate, and fish richness responded to mine impacts and were significantly higher in un-mined compared to mine-impacted streams. Changes in community composition toward more acid- and metal-tolerant species were evident for algae and invertebrates, whereas changes in fish communities were significant and driven by a loss of nonmigratory native species. Consistent catchment-scale predictors of mining activities affecting biota included the time post mining (years), mining density (the number of mines upstream per catchment area), and mining intensity (tons of coal production per catchment area). Mining was associated with a decline in stream biodiversity irrespective of catchment size, and recovery was not evident until at least 30 years after mining activities have ceased. These catchment-scale predictors can provide managers and regulators with practical metrics to focus on management and remediation decisions.

  8. Identifying Catchment-Scale Predictors of Coal Mining Impacts on New Zealand Stream Communities.

    PubMed

    Clapcott, Joanne E; Goodwin, Eric O; Harding, Jon S

    2016-03-01

    Coal mining activities can have severe and long-term impacts on freshwater ecosystems. At the individual stream scale, these impacts have been well studied; however, few attempts have been made to determine the predictors of mine impacts at a regional scale. We investigated whether catchment-scale measures of mining impacts could be used to predict biological responses. We collated data from multiple studies and analyzed algae, benthic invertebrate, and fish community data from 186 stream sites, including un-mined streams, and those associated with 620 mines on the West Coast of the South Island, New Zealand. Algal, invertebrate, and fish richness responded to mine impacts and were significantly higher in un-mined compared to mine-impacted streams. Changes in community composition toward more acid- and metal-tolerant species were evident for algae and invertebrates, whereas changes in fish communities were significant and driven by a loss of nonmigratory native species. Consistent catchment-scale predictors of mining activities affecting biota included the time post mining (years), mining density (the number of mines upstream per catchment area), and mining intensity (tons of coal production per catchment area). Mining was associated with a decline in stream biodiversity irrespective of catchment size, and recovery was not evident until at least 30 years after mining activities have ceased. These catchment-scale predictors can provide managers and regulators with practical metrics to focus on management and remediation decisions. PMID:26467674

  9. A coal-fired combustion system for industrial processing heating applications. Quarterly technical progress report, January 1995--March 1995

    SciTech Connect

    1995-04-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a {open_quotes}Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes} is a project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The test program consisted of one test run, with a duration of 100 hours at a nominal feed rate of 1000 lbs/hr. Throughout the test, the CMS was fired with coal and a coal by-product (i.e. coal-fired boiler fly ash) as the primary fuels. Natural gas was used as an auxiliary fuel as necessary to provide process trim. The feedstock consisted of a coal-fired utility boiler fly ash and dolomite and produced a stable, fully-reacted vitrified product. The fly ash, supplied by PENELEC, contained between 6 and 12% by weight of carbon because of the low NOx burners on the PENELEC boilers. Therefore, a substantial portion of the required thermal input came from the fly ash.

  10. Industrial-Scale Processes For Stabilizing Radioactively Contaminated Mercury Wastes

    SciTech Connect

    Broderick, T. E.; Grondin, R.

    2003-02-24

    This paper describes two industrial-scaled processes now being used to treat two problematic mercury waste categories: elemental mercury contaminated with radionuclides and radioactive solid wastes containing greater than 260-ppm mercury. The stabilization processes were developed by ADA Technologies, Inc., an environmental control and process development company in Littleton, Colorado. Perma-Fix Environmental Services has licensed the liquid elemental mercury stabilization process to treat radioactive mercury from Los Alamos National Laboratory and other DOE sites. ADA and Perma-Fix also cooperated to apply the >260-ppm mercury treatment technology to a storm sewer sediment waste collected from the Y-12 complex in Oak Ridge, TN.

  11. Solvent-Refined Coal (SRC) process. Health programs: industrial hygiene, clinical and toxicological programs. Final report

    SciTech Connect

    Hubis, W.

    1982-03-01

    This final report summarizes the Health Program under the Solvent Refined Coal (SRC) Process Contract from January 1, 1976 through December 31, 1981 with particular emphasis on the period January 1, 1980 through December 31, 1981. The major areas of activity within the Health program were: an industrial hygiene monitoring program, a clinical medical examination program, a personal hygiene and educational program, an epidemiology program, and a toxicological program. The industrial hygiene monitoring program during the past two years continued evaluation of occupational exposures to various air contaminants. The major emphasis was directed to the development, refinement and implementation of the skin contamination evaluation project. The medical examination program continued to indicate the absence of discernible occupationally related changes in employee medical profiles. In addition, appreciable effort was expended on efforts to develop a single layered garment which would prevent the appearance of black specks on the anterior thighs of plant operators working in areas of high particulate concentrations. The employee personal hygiene and educational program was extended to include both temporary and contract personnel. An epidemiology program was initiated during the period and efforts were concentrated primarily on program design and data collection. In the toxicological program, acute and genetic studies were completed on most of the SRC-II materials but no studies were initiated in the SRC-I portion of the program because of unavailability of test materials.

  12. Analysis of the interaction of the coal and transportation industries in 1990

    SciTech Connect

    Not Available

    1981-09-01

    This study analyzes the impacts of major developments in coal transportation on coal production, prices and markets. Coal and coal transportation markets have special characteristics that must be accommodated if an analysis is to be useful. First, coal of differing energy and sulfur contents is produced in different regions in the United States. The transportation options from these supply regions to the various coal demand regions also differ. The market boundary between coal supply regions depends on the end-use cost to the final purchaser of using coal from each source. The differences in coals and transportation options imply that no simple rule of thumb will yield the end-use cost from competing supply regions at a given site, so market boundaries cannot be identified simply. Second, at most sites, one fuel, say coal from a given region, will clearly have a lower end-use cost than the others. However, there is no unique answer to the question of how the benefits from this lower cost at a given site are shared among the parties involved. Finally, the current status of the coal market is not a reliable guide to the future, because of ongoing changes in relative real fuel prices, the regulatory rules that railroads follow, and environmental constraints on utilities. The implication of these characteristics is that no one can predict what actual future coal markets and transportation rates will be using only a theoretical model or statistical analysis of historical data.

  13. Development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January--March 1994

    SciTech Connect

    Not Available

    1994-04-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system, controls, and then test the complete system in order to evaluate its potential marketability. The past quarter began with a two-day test performed in January to determine the cause of pulsations in the batch feed system observed during pilot-scale testing of surrogate TSCA incinerator ash performed in December of 1993. Two different batch feedstocks were used during this test: flyash and cullet. The cause of the pulsations was traced to a worn part in the feeder located at the bottom of the batch feed tank. The problem was corrected by replacing the wom part with the corresponding part on the existing coal feed tank. A new feeder for the existing coal tank, which had previously been ordered as part of the new coal handling system, was procured and installed. The data from the pilot-scale tests performed on surrogate TSCA incinerator ash during December of 1993 was collected and analyzed. All of the glass produced during the test passed both the Toxicity characteristics Leach Procedure (TCLP) and the Product Consistency Test (PCT) by approximately two orders of magnitude.

  14. Industrial Large Scale Applications of Superconductivity -- Current and Future Trends

    NASA Astrophysics Data System (ADS)

    Amm, Kathleen

    2011-03-01

    Since the initial development of NbTi and Nb3Sn superconducting wires in the early 1960's, superconductivity has developed a broad range of industrial applications in research, medicine and energy. Superconductivity has been used extensively in NMR low field and high field spectrometers and MRI systems, and has been demonstrated in many power applications, including power cables, transformers, fault current limiters, and motors and generators. To date, the most commercially successful application for superconductivity has been the high field magnets required for magnetic resonance imaging (MRI), with a global market well in excess of 4 billion excluding the service industry. The unique ability of superconductors to carry large currents with no losses enabled high field MRI and its unique clinical capabilities in imaging soft tissue. The rapid adoption of high field MRI with superconducting magnets was because superconductivity was a key enabler for high field magnets with their high field uniformity and image quality. With over 30 years of developing MRI systems and applications, MRI has become a robust clinical tool that is ever expanding into new and developing markets. Continued innovation in system design is continuing to address these market needs. One of the key questions that innovators in industrial superconducting magnet design must consider today is what application of superconductivity may lead to a market on the scale of MRI? What are the key considerations for where superconductivity can provide a unique solution as it did in the case of MRI? Many companies in the superconducting industry today are investigating possible technologies that may be the next large market like MRI.

  15. Production cost and air emissions impacts of coal cycling in power systems with large-scale wind penetration

    NASA Astrophysics Data System (ADS)

    Oates, David Luke; Jaramillo, Paulina

    2013-06-01

    Wind power introduces variability into electric power systems. Due to the physical characteristics of wind, most of this variability occurs at inter-hour time-scales and coal units are therefore technically capable of balancing wind. Operators of coal-fired units have raised concerns that additional cycling will be prohibitively costly. Using PJM bid-data, we observe that coal operators are likely systematically under-bidding their startup costs. We then consider the effects of a 20% wind penetration scenario in the coal-heavy PJM West area, both when coal units bid business as usual startup costs, and when they bid costs accounting for the elevated wear and tear that occurs during cycling. We conclude that while 20% wind leads to increased coal cycling and reduced coal capacity factors under business as usual startup costs, including full startup costs shifts the burden of balancing wind onto more flexible units. This shift has benefits for CO2, NOX, and SO2 emissions as well as for the profitability of coal plants, as calculated by our dispatch model.

  16. CFD modeling of commercial-scale entrained-flow coal gasifiers

    SciTech Connect

    Ma, J.; Zitney, S.

    2012-01-01

    Optimization of an advanced coal-fired integrated gasification combined cycle system requires an accurate numerical prediction of gasifier performance. Computational fluid dynamics (CFD) has been used to model the turbulent multiphase reacting flow inside commercial-scale entrained-flow coal gasifiers. Due to the complexity of the physical and chemical processes involved, the accuracy of sub-models requires further improvement. Built upon a previously developed CFD model for entrained-flow gasification, the advanced physical and chemical sub-models presented in this paper include a moisture vaporization model with consideration of high mass transfer rate and a coal devolatilization model with more species to represent coal volatiles and the heating rate effect on volatile yield. The global gas phase reaction kinetics is also carefully selected. To predict a reasonable peak temperature of the coal/O{sub 2} flame inside an entrained-flow gasifier, the reserve reaction of H{sub 2} oxidation is included in the gas phase reaction model. The enhanced CFD model is applied to simulate two typical commercial-scale oxygen-blown entrained-flow configurations including a single-stage down-fired gasifier and a two-stage up-fired gasifier. The CFD results are reasonable in terms of predicted carbon conversion, syngas exit temperature, and syngas exit composition. The predicted profiles of velocity, temperature, and species mole fractions inside the entrained-flow gasifier models show trends similar to those observed in a diffusion-type flame. The predicted distributions of mole fractions of major species inside both gasifiers can be explained by the heterogeneous combustion and gasification reactions and the homogeneous gas phase reactions. It was also found that the syngas compositions at the CFD model exits are not in chemical equilibrium, indicating the kinetics for both heterogeneous and gas phase homogeneous reactions are important. Overall, the results achieved here

  17. Large-Scale Digital Geologic Map Databases and Reports of the North Coal District in Afghanistan

    USGS Publications Warehouse

    Hare, Trent M.; Davis, Philip A.; Nigh, Devon; Skinner, James A.; SanFilipo, John R.; Bolm, Karen S.; Fortezzo, Corey M.; Galuszka, Donna; Stettner, William R.; Sultani, Shafiqullah; Nader, Billal

    2008-01-01

    members of the coal team: Engineer Saifuddin Aminy (Team Leader); Engineer Gul Pacha Azizi; Engineer Abdul Haq Barakati; Engineer Abdul Basir; Engineer Mohammad Daoud; Engineer Abdullah Ebadi; Engineer Abdul Ahad Omaid; Engineer Spozmy; and Engineer Shapary Tokhi. The ongoing efforts of Engineer Mir M. Atiq Kazimi (Team leader); Engineer M. Anwar Housinzada; and Engineer Shereen Agha of the AGS Records Department to organize and catalogue the AGS material were invaluable in locating and preserving these data. The efforts of the entire AGS staff to personally preserve these data during war time, in the absence of virtually any supporting infrastructure, was truly remarkable. The efforts by the British Geological Survey (BGS) to assist the AGS in archiving these data, and the personal assistance provided by BGS (notably Robert McIntosh), to the USGS teams were also appreciated. The logistical support provided by the U.S. Embassy in Kabul, particularly the Afghanistan Reconstruction Group, was critical to the success of the USGS teams while in Afghanistan. Finally, the efforts of the Minister of the Ministry of Mines and Industries (M. Ibrahim Adel) to support the USGS coal resource assessment in Afghanistan, in both his current and former role as President of the Mines Affairs Department was vital to this effort.

  18. Effect of Temperature Gradient on Industrial Coal Slag Infiltration into Porous Refractory Materials in Slagging Gasifiers

    SciTech Connect

    Kaneko, Tetsuya Kenneth; Bennett, James P.; Dridhar, Seetharaman

    2011-12-01

    Infiltration characteristics of industrial coal slag into alumina (Al{sub 2}O{sub 3}) refractory material with a temperature gradient induced along the slag's penetration direction are compared to those obtained under near-isothermal conditions. Experiments were conducted with a hot-face temperature of 1450°C and a CO/CO{sub 2} ratio of 1.8, which corresponds to an oxygen partial pressure of ~10{sup −8} atm. The refractory under the near-isothermal temperature profile, with higher average temperatures, demonstrated a greater penetration depth than its counterpart that was under the steeper temperature gradient. Slag that did not infiltrate into the refractory due to the induced temperature gradient, pooled and solidified on the top of the sample. Within the pool, a conglomerated mass of troilite (FeS) formed separately from the surrounding slag. Microscopy of the cross-sectioned infiltrated refractories revealed that the slag preferentially corroded the matrix regions closer to the top surface. Furthermore, the formation of a thick layer of hercynite (FeAl{sub 2}O{sub 4}) at the top of refractory/slag interface significantly depleted the slag of its iron-oxide content with respect to its virgin composition. A qualitative description of the penetration process is provided in this article.

  19. The effect of unionization and firm structure on health and safety in the bituminous coal industry

    SciTech Connect

    Reardon, J.E.

    1991-01-01

    The increase in the number of conglomerate mergers during the 1980's has prompted renewed debate on the effects of such mergers. This study investigates the effect of the conglomerate firm on the ability of the labor union to achieve safe working conditions in the bituminous coal industry. An index of union strength is constructed to replace the dummy union variable, traditionally included in econometric models to indicate whether or not the work place is unionized. The index is able to differentiate between situations in which the union has the ability to achieve a desired result from situations in which it does not. The principal data set constructed consists of 2,748 injuries in 270 mines from the states of: West Virginia, Pennsylvania, Virginia, Illinois, Kentucky, and Colorado for the year 1988. One finding was that the index of union strength has a negative but insignificant effect on the injury rate and the severity of the injury. Another principal finding was that conglomerate firms reduce the severity of the injury, but not the injury frequency rate. It was also found that conglomerate firms have a higher incidence of occupational illness than independent firms.

  20. "Rule of Thumb Methods No Longer Suffice": Development of British Coal Industry Education and Training 1900-circa 1970 and Lessons for Present-Day Education Policy-Makers

    ERIC Educational Resources Information Center

    Walker, Martyn A.

    2015-01-01

    This paper traces the origins and development of coal mining education and training in Britain from 1900 to the 1970s, by which time the coal industry had substantially declined. It looks at the progress from working-class self-help to national policy in support of education and training. The research makes use of college prospectuses and…

  1. Recovery Act: Oxy-Combustion Techology Development for Industrial-Scale Boiler Applications

    SciTech Connect

    Levasseur, Armand

    2014-04-30

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: • Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs. • Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF). • Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools. • Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems. • Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost. • Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project completion date was April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a

  2. THE SCALE-UP OF LARGE PRESSURIZED FLUIDIZED BEDS FOR ADVANCED COAL-FIRED POWER PROCESSES

    SciTech Connect

    Leon R. Glicksman; Michael Louge; Hesham F. Younis; Richard Tan; Mathew Hyre; Mark Torpey

    2003-11-24

    This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor an agency thereof, nor any of the their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, A combined-cycle High Performance Power System (HIPPS) capable of overall cycle efficiencies approaching 50% has been proposed and designed by Foster Wheeler Development Corporation (FWDC). A pyrolyzer in the first stage of the HIPPS process converts a coal feedstock into fuel gas and char at an elevated pressure of 1.4 Map. (206 psia) and elevated temperature of 930 C (1700 F). The generated char serves as the feedstock for a Pulverized Coal (PC) boiler operating at atmospheric pressure, and the fuel gas is directly fired in a gas turbine. The hydrodynamic behavior of the pyrolyzer strongly influences the quality of both the fuel gas and the generated char, the energy split between the gas turbine and the steam turbine, and hence the overall efficiency of the system. By utilizing a simplified set of scaling parameters (Glicksman et al.,1993), a 4/7th labscale cold model of the pyrolyzer operating at ambient temperature and pressure was constructed and tested. The scaling parameters matched include solid to gas density ratio, Froude number, length to diameter ratio; dimensionless superficial gas velocity and solid recycle rate, particle sphericity and particle size distribution (PSD).

  3. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, October 1993--December 1993

    SciTech Connect

    1994-01-30

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a {open_quotes}Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes} is a project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was completing the system modification installation designs, completing the TSCA ash testing, and conducting additional industry funded testing. Final detailed installation designs for the integrated test system configuration are being completed.

  4. China's Coal: Demand, Constraints, and Externalities

    SciTech Connect

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01

    likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

  5. Chlor-Alkali Industry: A Laboratory Scale Approach

    ERIC Educational Resources Information Center

    Sanchez-Sanchez, C. M.; Exposito, E.; Frias-Ferrer, A.; Gonzalez-Garaia, J.; Monthiel, V.; Aldaz, A.

    2004-01-01

    A laboratory experiment for students in the last year of degree program in chemical engineering, chemistry, or industrial chemistry is presented. It models the chlor-alkali process, one of the most important industrial applications of electrochemical technology and the second largest industrial consumer of electricity after aluminium industry.

  6. Novel approach for extinguishing large-scale coal fires using gas-liquid foams in open pit mines.

    PubMed

    Lu, Xinxiao; Wang, Deming; Qin, Botao; Tian, Fuchao; Shi, Guangyi; Dong, Shuaijun

    2015-12-01

    Coal fires are a serious threat to the workers' security and safe production in open pit mines. The coal fire source is hidden and innumerable, and the large-area cavity is prevalent in the coal seam after the coal burned, causing the conventional extinguishment technology difficult to work. Foams are considered as an efficient means of fire extinguishment in these large-scale workplaces. A noble foam preparation method is introduced, and an original design of cavitation jet device is proposed to add foaming agent stably. The jet cavitation occurs when the water flow rate and pressure ratio reach specified values. Through self-building foaming system, the high performance foams are produced and then infused into the blast drilling holes at a large flow. Without complicated operation, this system is found to be very suitable for extinguishing large-scale coal fires. Field application shows that foam generation adopting the proposed key technology makes a good fire extinguishment effect. The temperature reduction using foams is 6-7 times higher than water, and CO concentration is reduced from 9.43 to 0.092‰ in the drilling hole. The coal fires are controlled successfully in open pit mines, ensuring the normal production as well as the security of personnel and equipment. PMID:26370817

  7. Large scale solubilization of coal and bioconversion to utilizable energy. Technical progress report, January 1--March 31, 1996

    SciTech Connect

    Mishra, N.C.

    1996-05-01

    In order develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, the authors plan to clone the genes encoding Neurospora protein that facilitates depolymerization of coal. They also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the products of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein. Results are presented for the cloning of genes for Neurospora CSA-protein.

  8. Estimation of Scale Deposition in the Water Walls of an Operating Indian Coal Fired Boiler: Predictive Modeling Approach Using Artificial Neural Networks

    NASA Astrophysics Data System (ADS)

    Kumari, Amrita; Das, Suchandan Kumar; Srivastava, Prem Kumar

    2016-04-01

    Application of computational intelligence for predicting industrial processes has been in extensive use in various industrial sectors including power sector industry. An ANN model using multi-layer perceptron philosophy has been proposed in this paper to predict the deposition behaviors of oxide scale on waterwall tubes of a coal fired boiler. The input parameters comprises of boiler water chemistry and associated operating parameters, such as, pH, alkalinity, total dissolved solids, specific conductivity, iron and dissolved oxygen concentration of the feed water and local heat flux on boiler tube. An efficient gradient based network optimization algorithm has been employed to minimize neural predictions errors. Effects of heat flux, iron content, pH and the concentrations of total dissolved solids in feed water and other operating variables on the scale deposition behavior have been studied. It has been observed that heat flux, iron content and pH of the feed water have a relatively prime influence on the rate of oxide scale deposition in water walls of an Indian boiler. Reasonably good agreement between ANN model predictions and the measured values of oxide scale deposition rate has been observed which is corroborated by the regression fit between these values.

  9. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, October 1994--December 1994

    SciTech Connect

    1995-03-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a {open_quotes}Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes} is a project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was concentrated on conducting the 100 hour demonstration test. The test was successfully conducted from September 12th through the 16th. The test program consisted of one test run, with a duration of 100 hours at a nominal feed rate of 1000 lbs/hr. Throughout the test, the CMS was fired with coal and a coal by-product (i.e. coal-fired boiler flyash) as the primary fuels. Natural gas was used as an auxiliary fuel as necessary to provide process trim. The feedstock consisted of a coal-fired utility boiler flyash and dolomite and produced a stable, fully-reacted vitrified product. The fly ash, supplied by PENELEC, contained between 6 and 12% by weight of carbon because of the low NO{sub x} burners on the PENELEC boilers.

  10. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect

    Not Available

    1993-11-01

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  11. Development of a retrofit coal combustor for industrial applications, (Phase 1-A)

    SciTech Connect

    Not Available

    1988-10-01

    During this past quarter, two tandem-fired pulse combustors were designed to fire at a nominal rate of 3.5 to 5.5 MMBtu/hr under continuation of Phase I work on DOE project DE-AC22-87PC79654. In prior work, MTCI demonstrated the operation of a 1--2 MMBtu/h coal-fired tandem pulse combustor that is intended for small industrial applications. These component tests emphasized verification of key design issues such as combustor coupling, slag rejection, and staged air addition. The current work, which represents an extension of the Phase I effort, focuses on integrated testing of the tandem pulse combustor with a fire-tube boiler, and the addition of a slag quench vessel. A tandem-fired pulse combustion unit designed to fire at a nominal rate of 3.5-5 MMBtu/hr was designed and fabricated. The configuration includes two combustion chambers cast in a single monolith, tailpipes cast separately with annular air preheating capability, and a cyclonic decoupler. Design analysis and evaluations were performed to optimize the system with respect to minimizing heat losses, size, and cost. Heat losses from the combustor and decoupler walls are predicted to be approximately 3 percent. The final designs for the ancillary items (slag quench, tertiary air addition, scrubber and sampling system) were completed and fabrication and installation initiated. A Cleaver-Brooks 150 hp-4 pass boiler was delivered and installed and modifications for interfacing with the retrofit pulse combustor unit completed. A below-ground slag collection pit was excavated to permit direct in-line coupling of the combustor to the boiler and to reduce head-room requirements. The pit is 30 inches deep and lined with waterproof and fireproof siding.

  12. Small-Scale Coal-Biomass to Liquids Production Using Highly Selective Fischer-Tropsch Synthesis

    SciTech Connect

    Gangwal, Santosh K.; McCabe, Kevin

    2015-04-30

    The research project advanced coal-to-liquids (CTL) and coal-biomass to liquids (CBTL) processes by testing and validating Chevron’s highly selective and active cobalt-zeolite hybrid Fischer-Tropsch (FT) catalyst to convert gasifier syngas predominantly to gasoline, jet fuel and diesel range hydrocarbon liquids, thereby eliminating expensive wax upgrading operations The National Carbon Capture Center (NCCC) operated by Southern Company (SC) at Wilsonville, Alabama served as the host site for the gasifier slip-stream testing/demonstration. Southern Research designed, installed and commissioned a bench scale skid mounted FT reactor system (SR-CBTL test rig) that was fully integrated with a slip stream from SC/NCCC’s transport integrated gasifier (TRIGTM). The test-rig was designed to receive up to 5 lb/h raw syngas augmented with bottled syngas to adjust the H2/CO molar ratio to 2, clean it to cobalt FT catalyst specifications, and produce liquid FT products at the design capacity of 2 to 4 L/day. It employed a 2-inch diameter boiling water jacketed fixed-bed heat-exchange FT reactor incorporating Chevron’s catalyst in Intramicron’s high thermal conductivity micro-fibrous entrapped catalyst (MFEC) packing to efficiently remove heat produced by the highly exothermic FT reaction.

  13. Selenium And Arsenic Speciation in Fly Ash From Full-Scale Coal-Burning Utility Plants

    SciTech Connect

    Huggins, F.E.; Senior, C.L.; Chu, P.; Ladwig, K.; Huffman, G.P.; /Kentucky U. /Reaction Engin. Int. /Elect. Power Res. Inst., Palo Alto

    2007-07-09

    X-ray absorption fine structure spectroscopy has been used to determine directly the oxidation states and speciation of selenium and arsenic in 10 fly ash samples collected from full-scale utility plants. Such information is needed to assess the health risk posed by these elements in fly ash and to understand their behavior during combustion and in fly ash disposal options, such as sequestration in tailings ponds. Selenium is found predominantly as Se(IV) in selenite (SeO{sub 3}{sup 2-}) species, whereas arsenic is found predominantly as As(V) in arsenate (AsO{sub 4}{sup 3-}) species. Two distinct types of selenite and arsenate spectra were observed depending upon whether the fly ash was derived from eastern U.S. bituminous (Fe-rich) coals or from western subbituminous or lignite (Ca-rich) coals. Similar spectral details were observed for both arsenic and selenium in the two different types of fly ash, suggesting that the post-combustion behavior and capture of both of these elements are likely controlled by the same dominant element or phase in each type of fly ash.

  14. Characterization of ash deposition and heat transfer behavior of coals during combustion in a pilot-scale facility and full-scale utility

    SciTech Connect

    Sushil Gupta; Rajender Gupta; Gary Bryant; Terry Wall; Shinji Watanabe; Takashi Kiga; Kimihito Narukawa

    2009-05-15

    Experimental measurements as well as theoretical models were used to investigate the impact of mineral matter of three coals on ash deposition and heat transfer for pulverized coal fired boilers. The ash deposition experiments were conducted in a pulverized fuel combustion pilot-scale facility and a full-scale unit. A mathematical model with input from computer-controlled scanning electron microscopy analysis of coal minerals was used to predict the effect of ash deposition on heat transfer. The predicted deposit thickness and heat flux from the model are shown to be consistent with the measurements in the test facility. The model differentiates the coals according to the deposits they form and their effect on heat transfer. The heat transfer predictions in the full-scale unit were found to be most suitable for the water wall under the furnace nose. The study demonstrates that the measurements in a full-scale unit can differ significantly from those in pilot-scale furnaces due to soot-blowing operations. 9 refs., 12 figs., 3 tabs.

  15. Pilot scale single stage fine coal dewatering and briquetting process. Final technical report, September 1, 1995--August 31, 1996

    SciTech Connect

    Wilson, J.W.; Honaker, R.Q.; Ding, Y.

    1997-05-01

    The primary goal of the ongoing ICCI coal preparation research project is to reduce ash and sulfur content in coal by using fine grinding and other coal cleaning processes. The ultrafine coal particles that result from the grinding and cleaning operations are difficult to dewater, and create problems in their storage, handling and transportation. The objective of this research is to combine the dewatering and briquetting processes of fine coal preparation into a single stage operation, thereby enhancing the economic viability of utilizing fine coal. A bitumen based emulsion, Orimulsion, has proven to be an effective hydrophobic binder, which helps not only with the briquetting process but also in the expulsion of water from the coal. Encouraging results from the use of a ram extruder briquetting device led to experimentation in the production of briquettes using a lab scale roll briquetting device. In the first quarter of this reporting year, a commercially available lab scale roll briquetting machine was employed (Komarek B-100). Further testing was conducted for the rest of the year with the use of a pilot scale model (Komarek B220-A). Briquettes were produced and evaluated by comparing results developed by adjusting various parameters of the briquetting machines and feed material. Results further substantiate previous findings that curing time dictates both moisture content and strengths of briquettes, and slower roll speeds produce more robust briquettes. A statistical model was set up to determine the optimal range of operating parameters. The statistical model generated from these results provided basic relationships between the roll speed and briquette form pressure.

  16. Operation of industrial-scale electron beam wastewater treatment plant

    NASA Astrophysics Data System (ADS)

    Han, Bumsoo; Kyu Kim, Jin; Kim, Yuri; Seung Choi, Jang; Young Jeong, Kwang

    2012-09-01

    Textile dyeing processes consume large amount of water, steam and discharge filthy and colored wastewater. A pilot scale e-beam plant with an electron accelerator of 1 MeV, 40 kW had constructed at Daegu Dyeing Industrial Complex (DDIC) in 1997 for treating 1,000 m3 per day. Continuous operation of this plant showed the preliminary e-beam treatment reduced bio-treatment time and resulted in more significant decreasing TOC, CODCr, and BOD5. Convinced of the economics and efficiency of the process, a commercial plant with 1 MeV, 400 kW electron accelerator has constructed in 2005. This plant improves the removal efficiency of wastewater with decreasing the retention time in bio-treatment at around 1 kGy. This plant is located on the area of existing wastewater treatment facility in DDIC and the treatment capacity is 10,000 m3 of wastewater per day. The total construction cost for this plant was USD 4 M and the operation cost has been obtained was not more than USD 1 M per year and about USD 0.3 per each m3 of wastewater.

  17. POC-scale testing of oil agglomeration techniques and equipment for fine coal processing

    SciTech Connect

    W. Pawlak; K. Szymocha

    1999-07-01

    The information presented in this manual is solely for the purpose of operating the POC-scale equipment for fine coal processing as described herein. This manual provides a general description of the process technology and guidelines for plant operating procedures. It is intended for use by the operators and maintenance personnel who will be responsible for the operations of the plant. No attempt should be made to operate the plant until the principles of the process and operating instructions contained in this manual are fully understood. Operating personnel should thoroughly familiarize themselves with all processing equipment prior to commencing plant operation. All equipment is skid mounted to provide a self-contained unit. The dimensions of the unit are comply with standard guidelines. A minimum distance of 2 feet is provided between equipment for walkway and maintenance.

  18. Pilot-scale test for electron beam purification of flue gas from coal-combustion boiler

    NASA Astrophysics Data System (ADS)

    Namba, Hideki; Tokunaga, Okihiro; Hashimoto, Shoji; Tanaka, Tadashi; Ogura, Yoshimi; Doi, Yoshitaka; Aoki, Shinji; Izutsu, Masahiro

    1995-09-01

    A pilot-scale test for electron beam treatment of flue gas (12,000m3N/hr) from coal-fired boiler was conducted by Japan Atomic Energy Research Institute, Chubu Electric Power Company and Ebara Corporation, in the site of Shin-Nagoya Thermal Power Plant in Nagoya, Japan. During 14 months operation, it was proved that the method is possible to remove SO2 and NOX simultaneously in wide concentration range of SO2 (250-2,000ppm) and NOX (140-240ppm) with higher efficiency than the conventional methods, with appropriate operation conditions (dose, temperature etc.). The pilot plant was easily operated with well controllability and durability, and was operated for long period of time without serious problems. The byproduct, ammonium sulfate and ammonium nitrate, produced by the treatment was proved to be a nitrogenous fertilizer with excellent quality.

  19. Old Dominion, industrial commonwealth: coal, politics, and economy in Antebellum America

    SciTech Connect

    Adams, S.P.

    2005-05-15

    The political economies of coal in Virginia and Pennsylvania from the late eighteenth century through the Civil War are compared, and the divergent paths these two states took in developing their ample coal reserves during a critical period of American industrialisation are examined. State economic policies played a major role. Virginia's failure to exploit the rich coal fields in the western part of the state can be traced to the legislature's over riding concern to protect and promote the interests of the agrarian, slaveholding elite of eastern Virginia. Pennsylvania's more fractious legislature enthusiastically embraced a policy of economic growth that resulted in the construction of an extensive transportation network, a statewide geological survey, and support for private investment in its coal fields.

  20. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  1. A new partnership to enhance international competitiveness for coal-related industries

    SciTech Connect

    Schobert, H.H.; Mitchell, G.D.; Finkelman, R.B.

    1999-07-01

    Conducting business in countries with significant indigenous coal supplies and expected economic growth (China, Indonesia, India, Russia, Ukraine, South Africa, Columbia, Brazil, and Venezuela) is extremely difficult, not only from a socio-economic/cultural standpoint, but because little reliable information is available on the properties and quality of raw materials. The question is how to compete and create opportunities in these countries when little or nothing is known about the properties of the indigenous raw materials. To address this concern the Penn State University and the U.S. Geological Survey (USGS) are partnering to develop an integrated database and sample bank of international coal and limestone samples of commercial value to power generation. The purpose of this partnership is to provide a reliable database linked to a convenient sample bank that would aid in resource evaluation and testing with regard to coal utilization including, but not limited to, combustion and combustion engineering, coke making, liquefaction, gasification, coalbed methane recovery, coal preparation, and mining. The Penn State-USGS-Private Sector partnership offers unique potential to provide this valuable service. The Penn State Energy Institute maintains a wide variety of analytical and testing equipment and expertise in coal-related engineering, chemistry and geology and has access to much more throughout the University system. For several decades the Institute has successfully maintained a large domestic coal sample bank. The USGS maintains a state-of-the-art analytical facility and a comprehensive domestic coal quality database. The USGS is actively working in about thirty countries to develop a reliable international coal quality database. Private sector will bring insights into the issues of competitiveness, certain knowledge of the marketplace and financial support.

  2. Pilot Scale Single Stage Fine Coal Dewatering and Briquetting Process. Technical report, March 1, 1996 - May 31, 1996

    SciTech Connect

    Wilson, J.W.; Honaker, R.Q.; Ding, Y.; Ho, K.

    1996-12-31

    The primary goal for this ICCI coal research project is to effectively liberate coal from fnely disseminated minerals for Illinois Basin coal by using fine grinding and cleaning processes. However, because of the large surface area generated during the cleaning processes, it is difficult and uneconomic for conventional techniques to dewater the coal fines. In addition, these coal fine pose transportation, storage and handling problems at cleaning and utility facilities. The objective of this research is to combine dewatering and briquetting processes into a single stage operation that will solve the problems mentioned above. To build on the promising results obtained from the previous studies, a pilot scale commercial briquetting machine was used to evaluate this technique. The primary objective of the research in this reporting period is to determine the effectiveness of a single stage dewatering and briquetting technique using a commercial briquetting device. Two types of samples were prepared and the results of the -28 x 100 mesh samples are presented in this report. Modifications were made to the machine in an attempt to solve the back drainage problem. A total of six experiments were conducted and the results indicate that water resistance of coal briquettes increased as curing time increased. However, due to a deficiency of fine particles to bridge the gaps between the coarse particles, the wear resistance of the products declined. Also, at high roll speeds and compaction pressures, the coal briquettes produced tended to have higher moisture content and lower strength. On the other hand, at high feed rates, because of the screw extrusion effect, coal briquettes were produced with lower moisture content and higher strengths.

  3. The true cost of renewables: An analytic response to the coal industry`s attack on renewable energy

    SciTech Connect

    Swezey, B G; Wan, Yih-huei

    1995-10-01

    In April 1995, the Center for Energy and Economic Development (CEED), an umbrella organization of pro-coal interests, released a report entitled Energy Choices in a Competitive Era: The Role of Renewable and Traditional Energy Resources in America`s Electric Generation Mix. The report purports to show that a very modest growth in the use of renewable energy in the U.S. power sector would entail unaffordable costs for the nation`s electricity ratepayers. The National Renewable Energy Laboratory (NREL) was commissioned by the U.S. Department of Energy (DOE) to review the assumptions contained in the report, which was prepared for CEED by Resource Data International, Inc. (RDI). The NREL analysis finds that the conclusions of the CEED/RDI study are based on faulty data and assumptions regarding the comparative economics of coal and renewable energy development. After correcting these errors, NREL finds that a modest growth path of renewable resource development would essentially cost the nation little more than projected electricity market costs for coal-fired generation, even before considering the environmental benefits that would accompany this development.

  4. Multi-scale radiographic applications in microelectronic industry

    NASA Astrophysics Data System (ADS)

    Gluch, J.; Löffler, M.; Meyendorf, N.; Oppermann, M.; Röllig, M.; Sättler, P.; Wolter, K. J.; Zschech, E.

    2016-02-01

    New concepts in assembly technology boost our daily life in an unknown way. High end semiconductor industry today deals with functional structures down to a few nanometers. ITRS roadmap predicts an ongoing decrease of the "DRAM half pitch" over the next decade. Packaging of course is not intended to realize pitches at the nanometer scale, but has to face the challenges of integrating such semiconductor devices with smallest pitch and high pin counts into systems. System integration (SiP, SoP, Hetero System Integration etc.) into the third dimension is the only way to reduce the gap between semiconductor level and packaging level interconnection. The described development is mainly driven by communication technology but also other branches like power electronics benefit from the vast progress in integration and assembly technology. The challenge of advanced packaging requires new nondestructive evaluation (NDE) techniques for technology development and production control. In power electronics production the condition monitoring receives a lot of interest to avoid electrical shortcuts, dead solder joints and interface cracking. It is also desired to detect and characterize very small defects like transportation phenomenon or Kirkendall voids. For this purpose imaging technologies with resolutions in the sub-micron range are required. Our presentation discusses the potentials and the limits of X-ray NDE techniques, illustrated by crack observation in solder joints, evaluation of micro vias in PCBs and interposers and the investigation of solder material composition and other aftermaths of electro migration in solder joints. Applied radiographic methods are X-ray through transmission, multi-energy techniques, laminography, CT and nano-CT.

  5. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1993--September 1993

    SciTech Connect

    Not Available

    1994-01-30

    The Pittsburgh Energy Technology Center (PETC) of the US Department of Energy awarded Vortec Corporation this Phase III contract (No. DE-AC22-91PC91161) for the development of {open_quotes}A Coal-Fired Combustion System for Industrial Process Heating Applications{close_quotes}. The effective contrast start date was September 3, 1991. The contract period of performance is 36 months. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. Final detailed installation designs for the integrated test system configuration are being completed. The equipment is being fabricated and deliveries have begun. The industry funded testing consisted of vitrifying Spent Aluminum Potliner (SPL) which is a listed hazardous waste. This testing has verified that SPL can be vitrified into a safe recyclable glass product.

  6. Clean coal technology: The new coal era

    SciTech Connect

    Not Available

    1994-01-01

    The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

  7. The development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January 1992--March 1992

    SciTech Connect

    Not Available

    1992-07-16

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  8. Pilot-scale fluidized-bed combustor testing cofiring animal-tissue biomass with coal as a carcass disposal option

    SciTech Connect

    Bruce G. Miller; Sharon Falcone Miller; Elizabeth M. Fedorowicz; David W. Harlan; Linda A. Detwiler; Michelle L. Rossman

    2006-10-15

    This study was performed to demonstrate the technical viability of cofiring animal-tissue biomass (ATB) in a coal-fired fluidized-bed combustor (FBC) as an option for disposing of specified risk materials (SRMs) and carcasses. The purpose of this study was to assess the technical issues of feeding/combusting ATB and not to investigate prion deactivation/pathogen destruction. Overall, the project successfully demonstrated that carcasses and SRMs can be cofired with coal in a bubbling FBC. Feeding ATB into the FBC did, however, present several challenges. Specifically, handling/feeding issues resulting from the small scale of the equipment and the extremely heterogeneous nature of the ATB were encountered during the testing. Feeder modifications and an overbed firing system were necessary. Through statistical analysis, it was shown that the ATB feed location had a greater effect on CO emissions, which were used as an indication of combustion performance, than the fuel type due to the feeding difficulties. Baseline coal tests and tests cofiring ATB into the bed were statistically indistinguishable. Fuel feeding issues would not be expected at the full scale since full-scale units routinely handle low-quality fuels. In a full-scale unit, the disproportionate ratio of feed line size to unit diameter would be eliminated thereby eliminating feed slugging. Also, the ATB would either be injected into the bed, thereby ensuring uniform mixing and complete combustion, or be injected directly above the bed with overfire air ports used to ensure complete combustion. Therefore, it is anticipated that a demonstration at the full scale, which is the next activity in demonstrating this concept, should be successful. As the statistical analysis shows, emissions cofiring ATB with coal would be expected to be similar to that when firing coal only. 14 refs., 5 figs., 6 tabs.

  9. PM10 mass concentration, chemical composition, and sources in the typical coal-dominated industrial city of Pingdingshan, China.

    PubMed

    Song, Xiaoyan; Yang, Shushen; Shao, Longyi; Fan, Jingsen; Liu, Yanfei

    2016-11-15

    The atmospheric pollution created by coal-dominated industrial cities in China cannot be neglected. This study focuses on the atmospheric PM10 in the typical industrial city of Pingdingshan City in North China. A total of 44 PM10 samples were collected from three different sites (power plant, mining area, and roadside) in Pingdingshan City during the winter of 2013, and were analyzed gravimetrically and chemically. The Pingdingshan PM10 samples were composed of mineral matter (average of 118.0±58.6μg/m(3), 20.6% of the total PM10 concentration), secondary crystalline particles (338.7±122.0μg/m(3), 59.2%), organic matter (77.3±48.5μg/m(3), 13.5%), and elemental carbon (38.0±28.3μg/m(3), 6.6%). Different sources had different proportions of these components in PM10. The power plant pollutant source was characterized by secondary crystalline particles (377.1μg/m(3)), elemental carbon (51.5μg/m(3)), and organic matter (90.6μg/m(3)) due to coal combustion. The mining area pollutant source was characterized by mineral matter (124.0μg/m(3)) due to weathering of waste dumps. The roadside pollutant source was characterized by mineral matter (130.0μg/m(3)) and organic matter (81.0μg/m(3)) due to road dust and vehicle exhaust, respectively. A positive matrix factorization (PMF) analysis was performed for PM10 source apportionment to identify major anthropogenic sources of PM10 in Pingdingshan. Six factors-crustal matter, coal combustion, vehicle exhaust and abrasion, local burning, weathering of waste dumps, and industrial metal smelting-were identified and their contributions to Pingdingshan PM10 were 19.0%, 31.6%, 7.4%, 6.3%, 9.8%, and 25.9%, respectively. Compared to other major cities in China, the source of PM10 in Pingdingshan was characterized by coal combustion, weathering of waste dumps, and industrial metal smelting. PMID:27450962

  10. Outlook and Challenges for Chinese Coal

    SciTech Connect

    Aden, Nathaniel T.; Fridley, David G.; Zheng, Nina

    2008-06-20

    China has been, is, and will continue to be a coal-powered economy. The rapid growth of coal demand since 2001 has created deepening strains and bottlenecks that raise questions about supply security. Although China's coal is 'plentiful,' published academic and policy analyses indicate that peak production will likely occur between 2016 and 2029. Given the current economic growth trajectory, domestic production constraints will lead to a coal gap that is not likely to be filled with imports. Urbanization, heavy industry growth, and increasing per-capita consumption are the primary drivers of rising coal usage. In 2006, the power sector, iron and steel, and cement accounted for 71% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units could save only 14% of projected 2025 coal demand. If China follows Japan, steel production would peak by 2015; cement is likely to follow a similar trajectory. A fourth wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. New demand from coal-to-liquids and coal-to-chemicals may add 450 million tonnes of coal demand by 2025. Efficient growth among these drivers indicates that China's annual coal demand will reach 4.2 to 4.7 billion tonnes by 2025. Central government support for nuclear and renewable energy has not been able to reduce China's growing dependence on coal for primary energy. Few substitution options exist: offsetting one year of recent coal demand growth would require over 107 billion cubic meters of natural gas, 48 GW of nuclear, or 86 GW of hydropower capacity. While these alternatives will continue to grow, the scale of development using existing technologies will be insufficient to substitute significant coal demand before 2025. The central role of heavy industry in GDP growth and the difficulty of substituting other fuels suggest that coal consumption is inextricably entwined with

  11. Environmental impact of coal industry and thermal power plants in India.

    PubMed

    Mishra, U C

    2004-01-01

    Coal is the only natural resource and fossil fuel available in abundance in India. Consequently, it is used widely as a thermal energy source and also as fuel for thermal power plants producing electricity. India has about 90,000 MW installed capacity for electricity generation, of which more than 70% is produced by coal-based thermal power plants. Hydro-electricity contributes about 25%, and the remaining is mostly from nuclear power plants (NPPs). The problems associated with the use of coal are low calorific value and very high ash content. The ash content is as high as 55-60%, with an average value of about 35-40%. Further, most of the coal is located in the eastern parts of the country and requires transportation over long distances, mostly by trains, which run on diesel. About 70% oil is imported and is a big drain on India's hard currency. In the foreseeable future, there is no other option likely to be available, as the nuclear power programme envisages installing 20,000 MWe by the year 2020, when it will still be around 5% of the installed capacity. Hence, attempts are being made to reduce the adverse environmental and ecological impact of coal-fired power plants. The installed electricity generating capacity has to increase very rapidly (at present around 8-10% per annum), as India has one of the lowest per capita electricity consumptions. Therefore, the problems for the future are formidable from ecological, radio-ecological and pollution viewpoints. A similar situation exists in many developing countries of the region, including the People's Republic of China, where coal is used extensively. The paper highlights some of these problems with the data generated in the author's laboratory and gives a brief description of the solutions being attempted. The extent of global warming in this century will be determined by how developing countries like India manage their energy generation plans. Some of the recommendations have been implemented for new plants

  12. CAPSULE REPORT: PARTICULATE CONTROL BY FABRIC FILTRATION ON COAL-FIRED INDUSTRIAL BOILERS

    EPA Science Inventory

    Interest in fabric filtration for boiler particulate control has increased due to the conversion of oil- and gas- to coal-fired boilers and the promulgation of more stringent particulate emission regulations. his report describes the theory, applications, performance, and economi...

  13. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report 3, April--June 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1995-08-05

    Economical dewatering of an ultra-fine clean coal product to a 20% or lower level moisture will be an important step in successful implementation of the advanced fine coal cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept (POC) scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals. During this quarter, addition of reagents such as ferric ions and a novel concept of in-situ polymerization (ISP) was studied in the laboratory. Using the ISP approach with vacuum filtration provided 25% moisture filter cake compared to 65.5% moisture obtained conventionally without using the ISP. A series of dewatering tests were conducted using the Andritz hyperbaric pilot filter unit with high sulfur clean coal slurry.

  14. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1992--June 1992

    SciTech Connect

    Not Available

    1992-09-03

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec`s Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  15. Coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect

    1995-08-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. This includes new installations and those existing installations that were originally designed for oil or gas firing. The data generated by these projects must be sufficient for private-sector decisions on the feasibility of using coal as the fuel of choice. This work should also provide incentives for the private sector to continue and expand the development, demonstration, and application of these combustion systems. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications is being developed under contract DE-AC22-91PC91161 as part of this DOE development program. The current contract represents the third phase of a three-phase development program. Phase I of the program addressed the technical and economic feasibility of the process, and was initiated in 1987 and completed 1989. Phase II was initiated in 1989 and completed in 1990. During Phase II of the development, design improvements were made to critical components and the test program addressed the performance of the process using several different feedstocks. Phase III of the program was initiated September 1991 and is scheduled for completion in 1994. The Phase III research effort is being focused on the development of a process heater system to be used for producing value-added vitrified glass products from boiler/incinerator ashes and selected industrial wastes.

  16. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1993--June 1993

    SciTech Connect

    Not Available

    1993-07-30

    Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the designs of the remaining major components of the integrated system were completed and the equipment was ordered. DOE has elected to modify the scope of the existing R&D program being conducted under this contract to include testing of a simulated TSCA incinerator ash. The modification will be in the form of an additional Task (Task 8 -- TSCA Ash Testing) to the original Statement of Work.

  17. Particle scale modelling of the multiphase flow in a dense medium cyclone: Effect of medium-to-coal ratio

    NASA Astrophysics Data System (ADS)

    Chu, Kaiwei; Chen, Jiang; Yu, Aibing; Vince, Andrew

    2013-06-01

    The effect of solids loading ratio or the medium-to-coal (M:C) ratio is the most important operational parameter of the Dense Medium Cyclones (DMC) that are widely used in the coal industry to upgrade the run-of-mine coal by separating gangue from product coal. However, its effect is still not well understood so far, since the flow pattern within a DMC is complicated due to the size and density distributions of the feed and process medium solids, and the turbulent vortex formed. Recently, it is shown that the particle-laden flow in a DMC can be modelled by the so-called combined Computational Fluid Dynamics (CFD) and Discrete Element Method (DEM) (CFD-DEM) in which the flow of coal particles is modelled by DEM which applies Newton's laws of motion to individual particles and that of medium flow by the conventional CFD which solves the local-averaged Navier-Stokes equations, allowing consideration of particle-fluid mutual interaction and particle-particle collisions. In this work, the effect of medium-to-coal (M:C) ratio is studied by a two-way coupling CFD-DEM approach for a large diameter DMC. The flow structure, and particle-particle and particle-fluid forces are analysed to understand the fundamentals governing this effect. The results suggest that the solids volume fraction of 20% (or M:C ratio of 4 by volume) is a critical point for the DMC performance under the conditions considered.

  18. Study of application of ERTS-A imagery to fracture related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.

    1973-01-01

    The author has identified the following significant results. The 70mm black and white infrared photography acquired in March 1973 at an approximate scale of 1:115,000 permits the identification of areas of mine subsidence not readily evident on other films. This is largely due to the high contrast rendition of water and land by this film and the excessive surface moisture conditions prevalent in the area at the time of photography. Subsided areas consist of shallow depressions which have impounded water. Patterns with a regularity indicative of the room and pillar configuration used in subsurface coal mining are evident.

  19. Development and testing of commercial-scale, coal-fired combustion systems: Phase III. Final report

    SciTech Connect

    1996-03-01

    Based on studies that indicated a large potential for significantly increased coal-firing in the commercial sector, the U.S. Department of Energy`s Pittsburgh Energy Technology Center (PETC) sponsored a multi-phase development effort for advanced coal combustion systems. This Final Report presents the results of the last phase (Phase III) of a project for the development of an advanced coal-fired system for the commercial sector of the economy. The project performance goals for the system included dual-fuel capability (i.e., coal as primary fuel and natural gas as secondary fuel), combustion efficiency exceeding 99 percent, thermal efficiency greater than 80 percent, turndown of at least 3:1, dust-free and semi-automatic dry ash removal, fully automatic start-up with system purge and ignition verification, emissions performance exceeding New Source Performance Standards (NSPS) and approaching those produced by oil-fired, Commercial-sized units, and reliability, safety, operability, maintainability, and service life comparable to oil-fired units. The program also involved a site demonstration at a large facility owned by Striegel Supply Company, a portion of which was leased to MTCI. The site, mostly warehouse space, was completely unheated and the advanced coal-fired combustion system was designed and sized to heat this space. Three different coals were used in the project, one low and one high sulfur pulverized Pittsburgh No. 8 coal, and a micronized low volatile, bituminous coal. The sorbents used were Pfizer dolomitic limestone and an Anvil lime. More than 100 hours of screening test`s were performed to characterize the system. The parameters examined included coal firing rate, excess air level, ash recycle rate, coal type, dolomitic limestone feed rate, and steam injection rate. These tests indicated that some additional modifications for coal burning in the system were required.

  20. Industrial Scale Energy Systems Integration; NREL (National Renewable Energy Laboratory)

    SciTech Connect

    Ruth, Mark

    2015-07-28

    The industrial sector consumes 25% of the total energy in the U.S. and produces 18% of the greenhouse gas (GHG) emissions. Energy Systems Integration (ESI) opportunities can reduce those values and increase the profitability of that sector. This presentation outlines several options. Combined heat and power (CHP) is an option that is available today for many applications. In some cases, it can be extended to trigeneration by adding absorbtion cooling. Demand response is another option in use by the industrial sector - in 2012, industry provided 47% of demand response capacity. A longer term option that combines the benefits of CHP with those of demand response is hybrid energy systems (HESs). Two possible HESs are described and development implications discussed. extended to trigeneration by adding absorbtion cooling. Demand response is another option in use by the industrial sector - in 2012, industry provided 47% of demand response capacity. A longer term option that combines the benefits of CHP with those of demand response is hybrid energy systems (HESs). Two possible HESs are described and development implications discussed.

  1. Economics of scale in the electric-utility industry: a review. Final report

    SciTech Connect

    Not Available

    1982-09-01

    Purpose of this paper is to examine the literature dealing with the issue of economy of scale, outline its effects on, and implications for, the electric utility industry, and to review the economies of scale for both conventional and renewable (or inexhaustible) utility technologies. The key characteristics of utility technology and other factors which influence economies of scale are included to provide historical and future perspective on the importance of the economy-of-scale issue. Intent of this paper is to review the role of scale economies in the electric utility industry in order to structure the discussion on and gain perspective on their continued importance.

  2. Performance evaluation of a ceramic cross-flow filter on a bench-scale coal gasifier

    SciTech Connect

    Ciliberti, D.F.; Lippert, T.E.

    1985-01-01

    The Department of Energy is currently sporting a program that will aid in the development of cross flow filtration technology as applied to combined cycle power generation with coal gasification. The stated overall goal is to gain information on both the operational and economic feasibility of the implementation of cross flow filtration in various gasifier options. Westinghouse has prepared a comprehensive program that will lead directly to these program goals in an efficient manner. the proposed program is composed of three major technical task. Task 1 is directed at the design and actual test of a cross flow filter at a DOE bench scale gasifier. Task 2 is composed of several smaller theoretical and experimental efforts that are intended to firm up areas where engineering and design principles are lacking or considered inadequate. The third task is intended to integrate the results of the first two tasks in a conceptual design and cost analysis such that proper economic perspective for the filter concept can be gained. A brief summary of the approach taken in the technical tasks is presented in the following discussion.

  3. Performance evaluation of a ceramic cross-flow filter on a bench-scale coal gasifier

    SciTech Connect

    Lippert, T.E.; Bachovchin, D.M.; Smeltzer, E.E.; Meyer, J.H.; Vidt, E.J.

    1989-09-01

    The ceramic cross-flow filter (CXF) system is a promising method to be used in advanced coal based power systems for high temperature, high pressure (HTHP) particle removal. Using a subpilot scale pressurized fluid-bed combustor (PFBC) at Argonne National Laboratory and various PFBC simulators, prior projects have indicated that CXF systems can be used in oxidizing environments at PFBC conditions. To extend the use of CXF systems, this project completed an economic analysis comparing the cost of various oxygen and air blown gasification systems with the CXF system incorporated, initiated the scaleup of the CXF element from development to commercial size, predicted the characteristics of gasifier dust cake, evaluated cleaning pulse characteristics in a large multielement simulation, upgraded pulse cleaning mathematical model, and completed additional testing of the CXF elements under gasification (reducing) and PFBC conditions. Coors Ceramic Company and GTE Products Corporation were integrally involved in this program through the development and fabrication of the CXF elements. 39 figs., 23 tabs.

  4. O absorption measurements in an engineering-scale high-pressure coal gasifier

    NASA Astrophysics Data System (ADS)

    Sun, Kai; Sur, Ritobrata; Jeffries, Jay B.; Hanson, Ronald K.; Clark, Tommy; Anthony, Justin; Machovec, Scott; Northington, John

    2014-10-01

    A real-time, in situ water vapor (H2O) sensor using a tunable diode laser near 1,352 nm was developed to continuously monitor water vapor in the synthesis gas of an engineering-scale high-pressure coal gasifier. Wavelength-scanned wavelength-modulation spectroscopy with second harmonic detection (WMS-2 f) was used to determine the absorption magnitude. The 1 f-normalized, WMS-2 f signal (WMS-2 f/1 f) was insensitive to non-absorption transmission losses including beam steering and light scattering by the particulate in the synthesis gas. A fitting strategy was used to simultaneously determine the water vapor mole fraction and the collisional-broadening width of the transition from the scanned 1 f-normalized WMS-2 f waveform at pressures up to 15 atm, which can be used for large absorbance values. This strategy is analogous to the fitting strategy for wavelength-scanned direct absorption measurements. In a test campaign at the US National Carbon Capture Center, the sensor demonstrated a water vapor detection limit of ~800 ppm (25 Hz bandwidth) at conditions with more than 99.99 % non-absorption transmission losses. Successful unattended monitoring was demonstrated over a 435 h period. Strong correlations between the sensor measurements and transient gasifier operation conditions were observed, demonstrating the capability of laser absorption to monitor the gasification process.

  5. Performance evaluation of a ceramic cross-flow filter on a bench-scale coal gasifier

    SciTech Connect

    Ciliberti, D.F.; Lippert, T.E.

    1985-01-01

    The Department of Energy is currently supporting a program that will aid in the development of cross flow filtration technology as applied to combined cycle power generation with coal gasification. The stated overall goal is to gain information on both the operational and economic feasibility of the implementation of cross flow filtration in various gasifier options. Westinghouse has prepared a comprehensive program that will lead directly to these program goals in an efficient manner. The proposed program is composed of three major technical tasks. Task 1 is directed at the design and actual test of a cross flow filter at a DOE bench scale gasifier. Task 2 is composed of several smaller theoretical and experimental efforts that are intended to firm up areas where engineering and design principles are lacking or considered inadequate. The third task is intended to integrate the results of the first two tasks in a conceptual design and cost analysis such that proper economic perspective for the filter concept can be gained. A brief summary of the approach taken in the technical tasks is presented in the following discussion.

  6. Performance evaluation of a ceramic cross-flow filter on a bench- scale coal gasifier

    SciTech Connect

    Ciliberti, D.F.; Lippert, T.E.

    1985-01-01

    The Department of Energy is currently supporting a program that will aid in the development of cross flow filtration technology as applied to combined cycle power generation with coal gasification. The stated overall goal is to gain information on both the operational and economic feasibility of the implementation of cross flow filtration in various gasifier options. Westinghouse has prepared a comprehensive program that will lead directly to these program goals in an efficient manner. The proposed program is composed of three major technical tasks. Task 1 is directed at the design and actual test of a cross flow filter at a DOE bench scale gasifier. Task 2 is composed of several smaller theoretical and experimental efforts that are intended to firm up areas where engineering and design principles are lacking or considered inadequate. The third task is intended to integrate the results of the first two tasks in a conceptual design and cost analysis such that proper economic perspective for the filter concept can be gained. A brief summary of the approach taken in the technical tasks is presented in the following discussion. (VC)

  7. Regional-scale geomechanical impact assessment of underground coal gasification by coupled 3D thermo-mechanical modeling

    NASA Astrophysics Data System (ADS)

    Otto, Christopher; Kempka, Thomas; Kapusta, Krzysztof; Stańczyk, Krzysztof

    2016-04-01

    Underground coal gasification (UCG) has the potential to increase the world-wide coal reserves by utilization of coal deposits not mineable by conventional methods. The UCG process involves combusting coal in situ to produce a high-calorific synthesis gas, which can be applied for electricity generation or chemical feedstock production. Apart from its high economic potentials, UCG may induce site-specific environmental impacts such as fault reactivation, induced seismicity and ground subsidence, potentially inducing groundwater pollution. Changes overburden hydraulic conductivity resulting from thermo-mechanical effects may introduce migration pathways for UCG contaminants. Due to the financial efforts associated with UCG field trials, numerical modeling has been an important methodology to study coupled processes considering UCG performance. Almost all previous UCG studies applied 1D or 2D models for that purpose, that do not allow to predict the performance of a commercial-scale UCG operation. Considering our previous findings, demonstrating that far-field models can be run at a higher computational efficiency by using temperature-independent thermo-mechanical parameters, representative coupled simulations based on complex 3D regional-scale models were employed in the present study. For that purpose, a coupled thermo-mechanical 3D model has been developed to investigate the environmental impacts of UCG based on a regional-scale of the Polish Wieczorek mine located in the Upper Silesian Coal Basin. The model size is 10 km × 10 km × 5 km with ten dipping lithological layers, a double fault and 25 UCG reactors. Six different numerical simulation scenarios were investigated, considering the transpressive stress regime present in that part of the Upper Silesian Coal Basin. Our simulation results demonstrate that the minimum distance between the UCG reactors is about the six-fold of the coal seam thickness to avoid hydraulic communication between the single UCG

  8. COAL: DRDF (DENSIFIED REFUSE DERIVED FUEL) DEMONSTRATION TEST IN AN INDUSTRIAL SPREADER STOKER BOILER. USE OF COAL: DRDF BLENDS IN STOKER-FIRED BOILERS, APPENDICES A, B, C, AND D. VOLUME II

    EPA Science Inventory

    This study program has the overall objective of evaluating boiler performance and environmental feasibility when combusting densified forms of refuse derived fuels (dRDF) blended with coal and fired in a modern industrial spreader stoker-fired boiler. The results reported herein ...

  9. Using MSD prevention for cultural change in mining: Queensland Government/Anglo Coal Industry partnership.

    PubMed

    Tilbury, Trudy; Sanderson, Liz

    2012-01-01

    Queensland Mining has a strong focus on safety performance, but risk management of health, including Musculoskeletal Disorders (MSDs) continues to have a lower priority. The reliance on individual screening of workers and lower level approaches such as manual handling training is part of the coal mining 'culture'. Initiatives such as the New South Wales and Queensland Mining joint project to develop good practice guidance for mining has allowed for a more consistent message on participatory ergonomics and prevention of MSD. An evidence based practice approach, including the introduction of participatory ergonomics and safe design principles, was proposed to Anglo American Coal operations in Queensland. The project consisted of a skills analysis of current health personnel, design of a facilitated participatory ergonomics training program, site visits to identify good practice and champions, and a graduated mentoring program for health personnel. Early results demonstrate a number of sites are benefiting from site taskforces with a focus on positive performance outcomes. PMID:22317407

  10. Surface runoff from full-scale coal combustion product pavements during accelerated loading

    SciTech Connect

    Cheng, C.M.; Taerakul, P.; Tu, W.; Zand, B.; Butalia, T.; Wolfe, W.; Walker, H.

    2008-08-15

    In this study, the release of metals and metalloids from full-scale portland cement concrete pavements containing coal combustion products (CCPs) was evaluated by laboratory leaching tests and accelerated loading of full-scale pavement sections under well-controlled conditions. An equivalent of 20 years of highway traffic loading was simulated at the OSU/OU Accelerated Pavement Load Facility (APLF). Three types of portland cement concrete driving surface layers were tested, including a control section (i.e., ordinary portland cement (PC) concrete) containing no fly ash and two sections in which fly ash was substituted for a fraction of the cement; i.e., 30% fly ash (FA30) and 50% fly ash (FA50). In general, the concentrations of minor and trace elements were higher in the toxicity characteristic leaching procedure (TCLP) leachates than in the leachates obtained from synthetic precipitation leaching procedure and ASTM leaching procedures. Importantly, none of the leachate concentrations exceeded the TCLP limits or primary drinking water standards. Surface runoff monitoring results showed the highest release rates of inorganic elements from the FA50 concrete pavement, whereas there were little differences in release rates between PC and FA30 concretes. The release of elements generally decreased with increasing pavement loading. Except for Cr, elements were released as particulates (>0.45 {mu} m) rather than dissolved constituents. The incorporation of fly ash in the PC cement concrete pavements examined in this study resulted in little or no deleterious environmental impact from the leaching of inorganic elements over the lifetime of the pavement system.

  11. Large scale solubilization of coal and bioconversion to utilizable energy. Seventh quarterly technical progress report, April 1, 1995--June 30, 1995

    SciTech Connect

    Mishra, N.C.

    1995-12-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, we plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. We also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  12. Large scale solubilization of coal and bioconversion to utilizable energy. Fifth quarterly technical progress report, October 1, 1994--December 31, 1994

    SciTech Connect

    Mishra, N.C.

    1995-02-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, the authors plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. The authors also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  13. Large scale solubilization of coal and bioconversion to utilizable energy. Technical progress report, July 1, 1994--September 30, 1994, fourth quarterly

    SciTech Connect

    Mishra, N.C.

    1994-11-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, we plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. We also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms (Faison, 1991). In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  14. Large scale solubilization of coal and bioconversion to utilizable energy. Eighth quarterly technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Mishra, N.C.

    1996-02-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, we plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. We also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  15. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly progress report, July - September 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-10-01

    The advanced fine-coal cleaning techniques such as column flotation, recovers a low-ash ultra-fine size clean-coal product. However, economical dewatering of the clean coal product to less than 20 percent moisture using conventional technology is difficult. This research program objective is to evaluate a novel coal surface modification technique developed at the University of Kentucky Center for Applied Energy Research in conjunction with conventional and advanced dewatering technique at a pilot scale. The study which is in progress is being conducted at the Powell Mountain Coal Company`s Mayflower preparation plant located in St. Charles, VA. During this quarter laboratory dewatering studies were conducted using a 4-in diameter laboratory chemical centrifuge. The baseline data provided a filter cake with about 32% moisture. Addition of 0.3 kg/t of a cationic surfactant lowered the moisture to 29%. Addition of anionic and non-ionic surfactant was not effective in reducing the filter cake moisture content. In the pilot scale studies, a comparison was conducted between the high pressure and vacuum dewatering techniques. The base line data with high pressure and vacuum filtration provided filter cakes with 23.6% and 27.8% moisture, respectively. Addition of 20 g/t of cationic flocculent provided 21% filter cake moisture using the high pressure filter. A 15% moisture filter cake was obtained using 1.5 kg/t of non-ionic surfactant. Vacuum filter provided about 23% to 25% moisture product with additional reagents. The high pressure filter processed about 3 to 4 times more solids compared to vacuum filter.

  16. Large scale solubilization of coal and bioconversion to utilizable energy. Third quarterly technical progress report, April 1, 1994--June 30, 1994

    SciTech Connect

    Mishra, N.C.

    1994-08-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, the investigators plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. They also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein. Main objectives are: (1) cloning of Neurospora gene for coal depolymerization protein controlling solubilization in different host cells, utilizing Neurospora plasmid and other vector(s); (2) (a) development of a large scale electrophoretic separation of coal drived products obtained after microbial solubilization; (b) identification of the coal derived products obtained after biosolubilization by Neurospora cultures or obtained after Neurospora enzyme catalyzed reaction in in vitro by the wildtype and mutant enzymes; (3) bioconversion of coal drived products into utilizable fuel; and (4) characterization of Neurospora wildtype and mutant CSA protein(s) involved in solubilization of coal in order to assess the nature of the mechanism of solubilization and the role of Neurospora proteins in this process.

  17. Laboratory scale studies on removal of chromium from industrial wastes.

    PubMed

    Baig, M A; Mir, Mohsin; Murtaza, Shazad; Bhatti, Zafar I

    2003-05-01

    Chromium being one of the major toxic pollutants is discharged from electroplating and chrome tanning processes and is also found in the effluents of dyes, paint pigments, manufacturing units etc. Chromium exists in aqueous systems in both trivalent (Cr(3+)) and hexavalent (Cr(6+)) forms. The hexavalent form is carcinogenic and toxic to aquatic life, whereas Cr(3+) is however comparatively less toxic. This study was undertaken to investigate the total chromium removal from industrial effluents by chemical means in order to achieve the Pakistan NEQS level of 1 mg/L by the methods of reduction and precipitation. The study was conducted in four phases. In phase I, the optimum pH and cost effective reducing agent among the four popular commercial chemicals was selected. As a result, pH of 2 was found to be most suitable and sodium meta bisulfate was found to be the most cost effective reducing agent respectively. Phase II showed that lower dose of sodium meta bisulfate was sufficient to obtain 100% efficiency in reducing Cr(6+) to Cr(3+), and it was noted that reaction time had no significance in the whole process. A design curve for reduction process was established which can act as a tool for treatment of industrial effluents. Phase III studies indicated the best pH was 8.5 for precipitation of Cr(3+) to chromium hydroxide by using lime. An efficiency of 100% was achievable and a settling time of 30 minutes produced clear effluent. Finally in Phase IV actual waste samples from chrome tanning and electroplating industries, when precipitated at pH of 12 gave 100% efficiency at a settling time of 30 minutes and confined that chemical means of reduction and precipitation is a feasible and viable solution for treating chromium wastes from industries. PMID:12938996

  18. Development and testing of a high efficiency advanced coal combustor Phase III industrial boiler retrofit. Quarterly technical progress report, July 1, 1995--September 30, 1995 No. 16

    SciTech Connect

    Borio, R.W.

    1995-12-15

    The objective of this project is to retrofit a burner, capable of firing microfine coal, to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the sixteenth quarter (July `95 through September `95) of the program. The overall program has consisted of five major tasks: (1) A review of current state-of-the-art coal firing system components. (2) Design and experimental testing of a prototype HEACC (High Efficiency Advanced Coal Combustor) burner. (3) Installation and testing of a prototype HEACC system in a commercial retrofit application. (4) Economics evaluation of the HEACC concept for retrofit applications. (5) Long term demonstration under commercial user demand conditions.

  19. POC-Scale Testing of an Advanced Fine Coal Dewatering Equipment/Technique

    SciTech Connect

    Karekh, B K; Tao, D; Groppo, J G

    1998-08-28

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 mm) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy's program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 45 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 - March 31, 1998.

  20. Integrated low emissions cleanup system for coal fueled turbines Phase III bench-scale testing and evaluation

    SciTech Connect

    Newby, R.A.; Alvin, M.A.; Bachovchin, D.M.

    1995-08-01

    The United States Department of Energy, Morgantown Energy Research Center (DOE/METC), is sponsoring the development of coal-fired turbine technologies such as Pressurized Fluidized Bed Combustion (PFBC), coal Gasification Combined Cycles (GCC), and Direct Coal-Fired Turbines (DCFT). A major technical development challenge remaining for coal-fired turbine systems is high-temperature gas cleaning to meet environmental emissions standards, as well as to ensure acceptable turbine life. The Westinghouse Electric Corporation, Science & Technology Center, has evaluated an Integrated Low Emissions Cleanup (ILEC) concept that has been configured to meet this technical challenge. This ceramic hot gas filter (HGF), ILEC concept controls particulate emissions, while simultaneously contributing to the control of sulfur and alkali vapor contaminants in high-temperature, high-pressure, fuel gases or combustion gases. This document reports on the results of Phase III of the ILEC evaluation program, the final phase of the program. In Phase III, a bench-scale ILEC facility has been tested to (1) confirm the feasibility of the ILEC concept, and (2) to resolve some major filter cake behavior issues identified in PFBC, HGF applications.

  1. Optical and chemical characterization of aerosols emitted from coal, heavy and light fuel oil, and small-scale wood combustion.

    PubMed

    Frey, Anna K; Saarnio, Karri; Lamberg, Heikki; Mylläri, Fanni; Karjalainen, Panu; Teinilä, Kimmo; Carbone, Samara; Tissari, Jarkko; Niemelä, Ville; Häyrinen, Anna; Rautiainen, Jani; Kytömäki, Jorma; Artaxo, Paulo; Virkkula, Aki; Pirjola, Liisa; Rönkkö, Topi; Keskinen, Jorma; Jokiniemi, Jorma; Hillamo, Risto

    2014-01-01

    Particle emissions affect radiative forcing in the atmosphere. Therefore, it is essential to know the physical and chemical characteristics of them. This work studied the chemical, physical, and optical characteristics of particle emissions from small-scale wood combustion, coal combustion of a heating and power plant, as well as heavy and light fuel oil combustion at a district heating station. Fine particle (PM1) emissions were the highest in wood combustion with a high fraction of absorbing material. The emissions were lowest from coal combustion mostly because of efficient cleaning techniques used at the power plant. The chemical composition of aerosols from coal and oil combustion included mostly ions and trace elements with a rather low fraction of absorbing material. The single scattering albedo and aerosol forcing efficiency showed that primary particles emitted from wood combustion and some cases of oil combustion would have a clear climate warming effect even over dark earth surfaces. Instead, coal combustion particle emissions had a cooling effect. Secondary processes in the atmosphere will further change the radiative properties of these emissions but are not considered in this study. PMID:24328080

  2. Pilot-Scale Demonstration of ALTA for NOx Control in Pulverized Coal-Fired Boilers

    SciTech Connect

    Andrew Fry; Devin Davis; Marc Cremer; Bradley Adams

    2008-04-30

    This report describes computational fluid dynamics (CFD) modeling and pilot-scale testing conducted to demonstrate the ability of the Advanced Layered Technology Approach (ALTA) to reduce NO{sub x} emissions in a pulverized coal (PC) boiler. Testing specifically focused on characterizing NO{sub x} behavior with deep burner staging combined with Rich Reagent Injection (RRI). Tests were performed in a 4 MBtu/hr pilot-scale furnace at the University of Utah. Reaction Engineering International (REI) led the project team which included the University of Utah and Combustion Components Associates (CCA). Deep burner staging and RRI, combined with selective non-catalytic reduction (SNCR), make up the Advanced Layered Technology Approach (ALTA) for NO{sub x} reduction. The application of ALTA in a PC environment requires homogenization and rapid reaction of post-burner combustion gases and has not been successfully demonstrated in the past. Operation of the existing low-NO{sub x} burner and design and operation of an application specific ALTA burner was guided by CFD modeling conducted by REI. Parametric pilot-scale testing proved the chemistry of RRI in a PC environment with a NOx reduction of 79% at long residence times and high baseline NOx rate. At representative particle residence times, typical operation of the dual-register low-NO{sub x} burner provided an environment that was unsuitable for NO{sub x} reduction by RRI, showing no NOx reduction. With RRI, the ALTA burner was able to produce NO{sub x} emissions 20% lower than the low-NO{sub x} burner, 76 ppmv vs. 94 ppmv, at a burner stoichiometric ratio (BSR) of 0.7 and a normalized stoichiometric ratio (NSR) of 2.0. CFD modeling was used to investigate the application of RRI for NO{sub x} control on a 180 MW{sub e} wall-fired, PC boiler. A NO{sub x} reduction of 37% from baseline (normal operation) was predicted using ALTA burners with RRI to produce a NO{sub x} emission rate of 0.185 lb/MBtu at the horizontal nose of

  3. Coal supply/demand, 1980 to 2000. Task 3. Resource applications industrialization system data base. Final review draft. [USA; forecasting 1980 to 2000; sector and regional analysis

    SciTech Connect

    Fournier, W.M.; Hasson, V.

    1980-10-10

    This report is a compilation of data and forecasts resulting from an analysis of the coal market and the factors influencing supply and demand. The analyses performed for the forecasts were made on an end-use-sector basis. The sectors analyzed are electric utility, industry demand for steam coal, industry demand for metallurgical coal, residential/commercial, coal demand for synfuel production, and exports. The purpose is to provide coal production and consumption forecasts that can be used to perform detailed, railroad company-specific coal transportation analyses. To make the data applicable for the subsequent transportation analyses, the forecasts have been made for each end-use sector on a regional basis. The supply regions are: Appalachia, East Interior, West Interior and Gulf, Northern Great Plains, and Mountain. The demand regions are the same as the nine Census Bureau regions. Coal production and consumption in the United States are projected to increase dramatically in the next 20 years due to increasing requirements for energy and the unavailability of other sources of energy to supply a substantial portion of this increase. Coal comprises 85 percent of the US recoverable fossil energy reserves and could be mined to supply the increasing energy demands of the US. The NTPSC study found that the additional traffic demands by 1985 may be met by the railways by the way of improved signalization, shorter block sections, centralized traffic control, and other modernization methods without providing for heavy line capacity works. But by 2000 the incremental traffic on some of the major corridors was projected to increase very significantly and is likely to call for special line capacity works involving heavy investment.

  4. Community Economic Identity: The Coal Industry and Ideology Construction in West Virginia

    ERIC Educational Resources Information Center

    Bell, Shannon Elizabeth; York, Richard

    2010-01-01

    Economic changes and the machinations of the treadmill of production have dramatically reduced the number of jobs provided by extractive industries, such as mining and timber, in the United States and other affluent nations in the post-World War II era. As the importance of these industries to national, regional, and local economies wanes,…

  5. Industrial-scale radio frequency treatments for insect control in lentils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Radio frequency (RF) treatments are considered as a potential postharvest technology for disinfesting legumes. After treatment protocols are validated to control postharvest insects without significant quality degradation, it is important to scale-up laboratory RF treatments to industrial applicatio...

  6. Co-firing of paper mill sludge and coal in an industrial circulating fluidized bed boiler.

    PubMed

    Tsai, Meng-Yuan; Wu, Keng-Tung; Huang, Chin-Cheng; Lee, Hom-Ti

    2002-01-01

    Co-firing of coal and paper mill sludge was conducted in a 103 MWth circulating fluidized bed boiler to investigate the effect of the sludge feeding rate on emissions of SOx, NOx, and CO. The preliminary results show that emissions of SOx and Nx decrease with increasing sludge feeding rate, but CO shows the reverse tendency due to the decrease in combustion temperature caused by a large amount of moisture in the sludge. All emissions met the local environmental requirements. The combustion ashes could be recycled as feed materials in the cement manufacturing process. PMID:12099502

  7. (Performance evaluation of fabric bag filters on a bench-scale coal gasifier)

    SciTech Connect

    Not Available

    1986-01-15

    The objective of the proposed work is to demonstrate the operational and economic feasibility of using high-temperature ceramic filters for particulate control in a variety of coal gasification power generating systems.

  8. Speed up the development and popularization of coal in Shanxi and Taiyuan areas

    SciTech Connect

    Hu, Y.; Ma, Q.; Fan, R.

    1997-12-31

    Clean coal utilization is a key step of sustainable development in China. In the period of ninth Five-Year-Plan, China will greatly enhance the development and adoption of clean coal technology, in which the industrial coal briquetting plays an important role. Compared with burning pulverized coal, burning coal briquettes in stoker boilers raises heat efficiency 10--14%, saves 15--21% of the coal, reduces particulate emission by 80--91% and SO{sub 2} by 20--36%. Consequently, development and popularization of coal briquette for boilers have been listed as one of the key projects in the ninth Five-Year-Plan. Owing to mechanized coal mining, the lump coal proportion is being reduced. On the other hand, thousands of gas producers in the small and medium scale ammonia plants increasingly demand lump anthracite. This discrepancy between supply and demand on lump coal can be resolved by coal briquetting. This paper describes the features and superiority of coal briquettes for gasification; it has uniform size, larger porosity, and higher reactivity. Some of its properties can be upgraded. Many Chinese organizations are being devoted to coal briquetting research, development and production. How to coordinate them in their efforts to form a coal briquetting industry with suitable production capacity and active market is a topic worth studying. This paper describes the current situation on briquette research, production and marketing. Some proposals to speed up the development and popularization of the coal briquettes are given.

  9. DEVELOPMENT AND DEMONSTRATION OF A PILOT SCALE FACILITY FOR FABRICATION AND MARKETING OF LIGHTWEIGHT-COAL COMBUSTION BYPRODUCTS-BASED SUPPORTS AND MINE VENTILATION BLOCKS FOR UNDERGROUND MINES

    SciTech Connect

    Yoginder P. Chugh

    2002-10-01

    The overall goal of this program was to develop a pilot scale facility, and design, fabricate, and market CCBs-based lightweight blocks for mine ventilation control devices, and engineered crib elements and posts for use as artificial supports in underground mines to replace similar wooden elements. This specific project was undertaken to (1) design a pilot scale facility to develop and demonstrate commercial production techniques, and (2) provide technical and marketing support to Fly Lite, Inc to operate the pilot scale facility. Fly Lite, Inc is a joint venture company of the three industrial cooperators who were involved in research into the development of CCBs-based structural materials. The Fly-Lite pilot scale facility is located in McLeansboro, Illinois. Lightweight blocks for use in ventilation stoppings in underground mines have been successfully produced and marketed by the pilot-scale facility. To date, over 16,000 lightweight blocks (30-40 pcf) have been sold to the mining industry. Additionally, a smaller width (6-inch) full-density block was developed in August-September 2002 at the request of a mining company. An application has been submitted to Mine Safety and Health Administration for the developed block approval for use in mines. Commercialization of cribs and posts has also been accomplished. Two generations of cribs have been developed and demonstrated in the field. MSHA designated them suitable for use in mines. To date, over 2,000 crib elements have been sold to mines in Illinois. Two generations of posts were also demonstrated in the field and designated as suitable for use in mines by MSHA. Negotiations are currently underway with a mine in Illinois to market about 1,000 posts per year based on a field demonstration in their mine. It is estimated that 4-5 million tons CCBs (F-fly ash or FBC fly ash) may be utilized if the developed products can be commercially implemented in U.S. coal and non-coal mines.

  10. Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal

    SciTech Connect

    Barton, Tom

    2013-06-30

    The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

  11. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, October 1992--December 1992

    SciTech Connect

    Not Available

    1993-01-29

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashesand industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, a majority of the effort was spent relining the separator/reservoir and the cyclone melter. The relinings were completed, the cyclonemelter was reinstalled, and the test system was returned to operational status. The wet ESP was delivered and placed on its foundation. The focus during the upcoming months will be completing the integration ofthe wet ESP and conducting the first industrial proof-of-concept test. The other system modifications are well underway with the designs of the recuperator installation and the batch/coal feed system progressing smoothly. The program is still slightly behind the original schedule but it is anticipated that it will be back on schedule by the end of the year. The commercialization planning is continuing with the identification of seven potential near-term commercial demonstration opportunities.

  12. Coal-Based Oxy-Fuel System Evaluation and Combustor Development; Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications

    SciTech Connect

    Hollis, Rebecca

    2013-03-31

    Clean Energy Systems, Inc. (CES) partnered with the U.S. Department of Energy’s National Energy Technology Laboratory in 2005 to study and develop a competing technology for use in future fossil-fueled power generation facilities that could operate with near zero emissions. CES’s background in oxy-fuel (O-F) rocket technology lead to the award of Cooperative Agreement DE-FC26-05NT42645, “Coal-Based Oxy-Fuel System Evaluation and Combustor Development,” where CES was to first evaluate the potential of these O-F power cycles, then develop the detailed design of a commercial-scale O-F combustor for use in these clean burning fossil-fueled plants. Throughout the studies, CES found that in order to operate at competitive cycle efficiencies a high-temperature intermediate pressure turbine was required. This led to an extension of the Agreement for, “Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications” where CES was to also develop an intermediate-pressure O-F turbine (OFT) that could be deployed in O-F industrial plants that capture and sequester >99% of produced CO2, at competitive cycle efficiencies using diverse fuels. The following report details CES’ activities from October 2005 through March 2013, to evaluate O-F power cycles, develop and validate detailed designs of O-F combustors (main and reheat), and to design, manufacture, and test a commercial-scale OFT, under the three-phase Cooperative Agreement.

  13. Annual Coal Report

    EIA Publications

    2016-01-01

    Provides information about U.S. coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience, including Congress, federal and state agencies, the coal industry, and the general public.

  14. Indonesian coal mining

    SciTech Connect

    2008-11-15

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  15. Brevion: the new small-scale industrial gamma irradiator

    NASA Astrophysics Data System (ADS)

    McKinney, Dan; Perrins, Robert; Gibson, Wayne; Levesque, Daniel

    2002-03-01

    The economical processing of low-volume products has been a challenge to the gamma industry since inception, influencing customers to send their products to contractors or choose alternative technologies. With the introduction of the Brevion irradiator (patent pending), economical gamma processing of low annual volume product lines is now possible. This innovative design is specifically targeted at plants processing product volumes of up to 20,000 m 3/yr. Brevion provides good cobalt efficiency and good dose uniformity, thus processing these volumes efficiently and economically. The Brevion facility has the distinct advantage of a low capital cost, compared to medium-sized automatic tote plants, while maintaining similar performance. Lead-time for the construction phase is also considerably shorter, resulting in significantly lower start-up costs. Companies with low-volume product lines can now achieve the control provided by in-house processing, and eliminate transportation time and costs associated with shipping products off-site.

  16. An Experiment Study of the Propagation of Radio Waves in a Scaled Model of Long-Wall Coal Mining Tunnels

    SciTech Connect

    Han, G.R.; Zhang, W.M.; Zhang, Y.P.

    2009-07-01

    A long-wall coal mining tunnel is the most important working area in a coal mine. It has long been realized that radio communications can improve both productivity and safety in this dangerous area. Hence, many attempts to use radio communications in such an environment have been made. Unfortunately, no radio system has satisfactorily provided communication services there, which, we believe, is partially due to poor understanding of the propagation characteristics of radio waves in the long-wall mining tunnel. To have deeper physical insight into the propagation problem, a scaled model of the long-wall mining tunnel was built, and the propagation characteristics of UHF radio waves were measured. The experiment and the measured results are presented and discussed.

  17. Coal use by industry and the associated air pollution emissions in the period from 1980 to 2000 under alternative market and regulatory conditions

    SciTech Connect

    Roach, C.R.

    1983-01-01

    This study develops methods and data necessary to forecast both coal use and the associated air pollution emissions from US manufacturing industries in the period from 1980 to 2000 under alternative market and regulatory conditions. For the forecast and sensitivity analyses, a process model was developed to simulate industry's investment decisions for energy using equipment. Embodied in the process model are judgments on several practical issues of applied microeconomics, the most important being those concerning methods of investment decision making by industry. Under basecase assumptions, rapid growth in industrial coal use is forecast, a 9.8% compound rate of growth over the 1980 to 2000 period. If the base-case level of coal use was achieved and current air pollution rules were continued, a substantial increase in SO/sub 2/ and NO/sub x/ emissions would be realized; a 219% increase in industrial emissions of SO/sub 2/ and a 100% increase in NO/sub x/ emissions by the year 2000. To block this increase in emissions, a series of stricter air pollution regulations was simulated in the process model. With the high oil and gas prices assumed in the basecase, the stricter regulations did not slow the increase in coal use. However, the cost of stricter regulations may be a problem. The incremental cost of air pollution control (the cost per ton of pollutant reduction) rises steeply as stricter rules are imposed. A total cost of $4 billion could be incurred if very strict regulations (scrubber devices on all coal-fired systems) were imposed instead of continuing current policy.

  18. Playing the Scales: Regional Transformations and the Differentiation of Rural Space in the Chilean Wine Industry

    ERIC Educational Resources Information Center

    Overton, John; Murray, Warwick E.

    2011-01-01

    Globalization and industrial restructuring transform rural places in complex and often contradictory ways. These involve both quantitative changes, increasing the size and scope of operation to achieve economies of scale, and qualitative shifts, sometimes leading to a shift up the quality/price scale, towards finer spatial resolution and…

  19. Field scale characterization and modeling of contaminant release from a coal tar source zone

    NASA Astrophysics Data System (ADS)

    D'Affonseca, Fernando M.; Blum, Philipp; Finkel, Michael; Melzer, Reiner; Grathwohl, Peter

    2008-11-01

    A coal tar contaminated site was characterized using traditional and innovative investigation methods. A careful interpretation of hydrogeological and hydrogeochemical data allowed for the conceptualization of the heterogeneous coal tar distribution in the subsurface. Past and future contaminant release from the source zone was calculated using a modeling framework consisting of a three-dimensional steady-state groundwater flow model (MODFLOW) and two hydrogeochemical models (MIN3P). Computational time of long-term simulations was reduced by simplifying the coal tar composition using 3 composite and 2 individual constituents and sequential application of a 2D centerline model (for calibration and predictions) and a 3D model (only for predictions). Predictions were carried out for a period of 1000 years. The results reveal that contaminant mass flux is governed by the geometry of zones containing residual coal tar, amount of coal tar, its composition and the physicochemical properties of the constituents. The long-term predictions made using the 2D model show that even after 1000 years, source depletion will be small with respect to phenanthrene, 89% of initial mass will be still available, and for the moderately and sparingly soluble composite constituents, 60% and 98%, respectively.

  20. Have government regulations improved workplace safety? A test of the asynchronous regulatory effects in China's coal industry, 1995-2006

    SciTech Connect

    Shi, X.P.

    2009-07-01

    Empirical studies on the effectiveness of workplace safety regulations are inconclusive. This study hypothesizes that the asynchronous effects of safety regulations occur because regulations need time to become effective. Safety regulations will work initially by reducing the most serious accidents, and later by improving overall safety performance. The hypothesis is tested by studying a provincial level aggregate panel dataset for China's coal industry using two different models with different sets of dependent variables: a fixed-effects model on mortality rate, which is defined as fatalities per 1,000 employees; and a negative binominal model on the annual number (frequency) of disastrous accidents. Safety regulations can reduce the frequency of disastrous accidents, but have not reduced mortality rate, which represents overall safety performance. Policy recommendations are made, including shifting production from small to large mines through industrial consolidation, improving the safety performance of large mines, addressing consequences of decentralization, and facilitating the implementation of regulations through carrying on institutional actions and supporting legislation.

  1. Efficient and large scale synthesis of graphene from coal and its film electrical properties studies.

    PubMed

    Wu, Yingpeng; Ma, Yanfeng; Wang, Yan; Huang, Lu; Li, Na; Zhang, Tengfei; Zhang, Yi; Wan, Xiangjian; Huang, Yi; Chen, Yongsheng

    2013-02-01

    Coal, which is abundant and has an incompact structure, is a good candidate to replace graphite as the raw material for the production of graphene. Here, a new solution phase technique for the preparation of graphene from coal has been developed. The precursor: graphene oxide got from coal was examined by atomic force microscopy, dynamic light scattering and X-ray diffraction, the results showed the GO was a small and single layer sheet. The graphene was examined by X-ray photoelectron spectroscopy, and Raman spectroscopy. Furthermore, graphene films have been prepared using direct solution process and the electrical conductivity and Hall effect have been studied. The results showed the conductivity of the films could reach as high as 2.5 x 10(5) Sm(-1) and exhibited an n-type behavior. PMID:23646544

  2. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect

    1998-09-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 pm) clean coal. Economical dewatering of an ultra-fine clean-coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 30, 1997.

  3. Combination of metamorphism and deformation affect the nano-scale pore structures and macromolecule characteristics of high-rank deformed coals

    NASA Astrophysics Data System (ADS)

    Zhang, W.; Li, H.; Ju, Y.

    2013-12-01

    experiments indicates that adsorption/desorption capacity shows a 'U' type with nano-pores volume and specific surface area, coals with best adsorption capacity contained both vitrinite and inertinite with an approximate ratio of 4:1 or 1:4, the increase of aromatic and aliphatic content individually facilitated the adsorption of CBM. Generally speaking, the adsorption/desorption capacity of ductile deformed coals is higher than that of brittle ones, but metamorphism could dramatically affects the final results. To enhance CBM production and reduce carbon emission, the appropriate coal-bearing strata need to be chosen. Our research shows that metamorphism and deformation affect the nano-scale pore structures and macromolecule characteristics of different coals. Therefore brittle-ductile superposed zone with medium-high rank coals has high gas content and permeability which is promising to exploit and helpful to environmental protection.

  4. Numerical simulation of ash vaporization during pulverized coal combustion in the laboratory-scale single-burner furnace

    SciTech Connect

    Jiancai Sui; Minghou Xu; Jihua Qiu; Yu Qiao; Yun Yu; Xiaowei Liu; Xiangpeng Gao

    2005-08-01

    CFD tools have been developed to effectively simulate complex, reacting, multiphase flows that exist in utility boilers. In this paper, a model of ash vaporization was established and integrated into a self-developed CFD code to predict ash vaporization in the coal combustion process. Experimental data from a single-particle combustion was used to validate the above model. The calibrated model was then applied to simulate the ash vaporization in a 92.9 kW laboratory-scale single-burner furnace. The effects of different combustion conditions, including air staging, on the ash vaporization were investigated. The results showed that the fraction of ash vaporization is mostly sensitive to coal particle temperature. Ash vaporization primarily occurred after a short interval along the coal particle trajectories when the particle temperatures increased to 1800 K. Air staging influenced the ash vaporization by changing the gas temperature distribution in the furnace. The simulation results showed that the more extreme the staging condition, the lower the overall peak temperature, and hence the lower the amount of ash vaporization. 26 refs., 9 figs.

  5. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1993--September 1993

    SciTech Connect

    Not Available

    1993-10-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase 3 research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was completing some of the system modification installation designs, completing industry funded testing, developing a surrogate TSCA ash composition, and completing the TSCA ash Test Plan. The installation designs will be used for the equipment modifications planned for the end of CY 93. The industry funded testing consisted of vitrifying Spent Aluminum Potliner (SPL) which is a listed hazardous waste. This testing has verified that SPL can be vitrified into a safe, recyclable glass product. Some results from this testing are provided in Section 2.2.1. The surrogate TSCA ash composition was developed with input from various DOE laboratories and subcontractors. The surrogate ash consists of a mixture of MSW fly ash and bottom ash spiked with heavy metal contaminants. The levels of metal additives are sufficient to ascertain the partitioning of the contaminants between the glass and effluent flow streams. Details of the surrogate composition and the planned testing is provided in Section 4.2.2.

  6. Pulse-jet fabric filters for coal-fired utility and industrial boilers: Final report

    SciTech Connect

    Dean, A.H.; Cushing, K.M.

    1987-09-01

    Pulse-jet fabric filters rely on the filtration of dirty flue gas by the outside surface of the bags, which are then cleaned by a shock wave from an air pulse entering each bag from the top. The shock wave travels down each bag, flexing the bag and dislodging dustcake as it travels the length of the bag downward and then upward. A venturi may or may not be used to enhance the pulse, and cleaning may be on-line or off-line. This study provides a convenient and versatile information base about pulse-jet fabric filters on coal-fired boilers. Features include an overview of the pulse-jet concept, a discussion of the advantages and disadvantages of pulse-jet cleaning, a survey of vendors and design and hardware features of pulse-jet installations, discussion of these design and hardware characteristics for several vendors, case histories of a wide variety of installations as examples, and a list of pertinent references. The most important part of the study is an exhaustive table of pulse-jet installations and their features, sorted several different ways for accessibility. Predominant features of the installations in the list are analyzed and presented in graphic form.

  7. Experimental characterization of an industrial pulverized coal-fired furnace under deep staging conditions

    SciTech Connect

    Costa, M.; Azevedo, J.L.T.

    2007-07-01

    Measurements have been performed in a 300 MWe, front-wall-fired, pulverized-coal, utility boiler. This boiler was retrofitted with boosted over fire air injectors that allowed the operation of the furnace under deeper staging conditions. New data are reported for local mean gas species concentration of O{sub 2}, CO, CO{sub 2}, NOx, gas temperatures and char burnout measured at several ports in the boiler including those in the main combustion and staged air regions. Comparisons of the present data with our previous measurements in this boiler, prior to the retrofitting with the new over fire system, show lower O{sub 2} and higher CO concentrations for the new situation as a consequence of the lower stoichiometry in the main combustion zone associated with the present boiler operating condition. Consistently, the measured mean NOx concentrations in the main combustion zone are now lower than those obtained previously, yielding emissions below 500 mg/Nm{sup 3}at 6% O{sub 2}. Finally, the measured values of particle burnout at the furnace exit are acceptable being those measured in the main combustion zone comparable with those obtained with the conventional over fire system.

  8. Experimental evidence for convergent evolution of maternal care heuristics in industrialized and small-scale populations

    PubMed Central

    Kushnick, Geoff; Hanowell, Ben; Kim, Jun-Hong; Langstieh, Banrida; Magnano, Vittorio; Oláh, Katalin

    2015-01-01

    Maternal care decision rules should evolve responsiveness to factors impinging on the fitness pay-offs of care. Because the caretaking environments common in industrialized and small-scale societies vary in predictable ways, we hypothesize that heuristics guiding maternal behaviour will also differ between these two types of populations. We used a factorial vignette experiment to elicit third-party judgements about likely caretaking decisions of a hypothetical mother and her child when various fitness-relevant factors (maternal age and access to resources, and offspring age, sex and quality) were varied systematically in seven populations—three industrialized and four small-scale. Despite considerable variation in responses, we found that three of five main effects, and the two severity effects, exhibited statistically significant industrialized/ small-scale population differences. All differences could be explained as adaptive solutions to industrialized versus small-scale caretaking environments. Further, we found gradients in the relationship between the population-specific estimates and national-level socio-economic indicators, further implicating important aspects of the variation in industrialized and small-scale caretaking environments in shaping heuristics. Although there is mounting evidence for a genetic component to human maternal behaviour, there is no current evidence for interpopulation variation in candidate genes. We nonetheless suggest that heuristics guiding maternal behaviour in diverse societies emerge via convergent evolution in response to similar selective pressures. PMID:26543577

  9. Experimental evidence for convergent evolution of maternal care heuristics in industrialized and small-scale populations.

    PubMed

    Kushnick, Geoff; Hanowell, Ben; Kim, Jun-Hong; Langstieh, Banrida; Magnano, Vittorio; Oláh, Katalin

    2015-06-01

    Maternal care decision rules should evolve responsiveness to factors impinging on the fitness pay-offs of care. Because the caretaking environments common in industrialized and small-scale societies vary in predictable ways, we hypothesize that heuristics guiding maternal behaviour will also differ between these two types of populations. We used a factorial vignette experiment to elicit third-party judgements about likely caretaking decisions of a hypothetical mother and her child when various fitness-relevant factors (maternal age and access to resources, and offspring age, sex and quality) were varied systematically in seven populations-three industrialized and four small-scale. Despite considerable variation in responses, we found that three of five main effects, and the two severity effects, exhibited statistically significant industrialized/ small-scale population differences. All differences could be explained as adaptive solutions to industrialized versus small-scale caretaking environments. Further, we found gradients in the relationship between the population-specific estimates and national-level socio-economic indicators, further implicating important aspects of the variation in industrialized and small-scale caretaking environments in shaping heuristics. Although there is mounting evidence for a genetic component to human maternal behaviour, there is no current evidence for interpopulation variation in candidate genes. We nonetheless suggest that heuristics guiding maternal behaviour in diverse societies emerge via convergent evolution in response to similar selective pressures. PMID:26543577

  10. Multimodal ultrafine particles from pulverized coal combustion in a laboratory scale reactor

    SciTech Connect

    Carbone, Francesco; Beretta, Federico; D'Anna, Andrea

    2010-07-15

    Particle size distribution functions have been measured in a ethanol fueled flame reactor fed with a low amount of pulverized coal particles. The reactor is operated in low (5.0 vol.%) and high (76.5 vol.%) oxygen concentrations using two high volatile bituminous Colombian and Indonesian coals. A carbon black powder is also oxidized in the same conditions. Generated particles are sampled using rapid-dilution probes and the size distribution functions are measured on-line by a high resolution Differential Mobility Analyzer. Results clearly show that ultrafine particles, those with sizes lower than 100 nm, have a multimodal size distribution function. These particles have huge number concentrations in both investigated conditions whereas their formation is enhanced in the oxygen enriched condition. Ultrafine particles are almost totally dominated in number by the fraction having sizes below 30 nm. Nanoparticles also account for a significant fraction of total particle mass and slowly coagulate in the reactor. The shape of the size distribution functions is not affected by the coal type, at least for the two investigated coals. Results suggest that ultrafine particles form through the vaporization-nucleation-growth pathway involving inorganic ashes. Moreover the contribution of carbonaceous particles seems particularly important for size smaller than 5 nm. (author)

  11. PROTOTYPE SCALE TESTING OF LIMB TECHNOLOGY FOR A PULVERIZED-COAL-FIRED BOILER

    EPA Science Inventory

    The report summarizes results of an evaluation of furnace sorbent injection (FSI) to control sulfur dioxide (SO2) emissions from coal-fired utility boilers. (NOTE: FSI of calcium-based sorbents has shown promise as a moderate SO2 removal technology.) The Electric Power Research I...

  12. Accomplishments in genome-scale in silico modeling for industrial and medical biotechnology

    PubMed Central

    Milne, Caroline B.; Kim, Pan-Jun; Eddy, James A.; Price, Nathan D.

    2011-01-01

    Driven by advancements in high-throughput biological technologies and the growing number of sequenced genomes, the construction of in silico models at the genome scale has provided powerful tools to investigate a vast array of biological systems and applications. Here, we review comprehensively the uses of such models in industrial and medical biotechnology, including biofuel generation, food production, and drug development. While the use of in silico models is still in its early stages for delivering to industry, significant initial successes have been achieved. For the cases presented here, genome-scale models predict engineering strategies to enhance properties of interest in an organism or to inhibit harmful mechanisms of pathogens or in disease. Going forward, genome-scale in silico models promise to extend their application and analysis scope to become a transformative tool in biotechnology. As such, genome-scale models can provide a basis for rational genome-scale engineering and synthetic biology. PMID:19946878

  13. Investigation of Spread dynamics, Carbon emissions and Suppression Efficiency of smouldering coal fires using small-scale experiments

    NASA Astrophysics Data System (ADS)

    Hadden, Rory; Garcia Saez, Jose; Rein, Guillermo

    2010-05-01

    Coal fires are driven by smouldering which is defined as a slow, low temperature flameless form of combustion sustained by the heat evolved when oxygen directly attacks the surface of a condensed fuel. Once these fires have been ignited, they are difficult to detect, locate and extinguish. Despite extensive fire-fighting attempts in hundreds of cases around the globe, very few cases of successful extinction by human intervention have been confirmed. This work reports two sets of small-scale laboratory experiments that have been used to investigate ignition, spread, emissions and suppression of coal fires. The combustion reaction was characterised by reaching maximum temperatures of 700-1000 C with an average spread rate of 0.11 mm/min. A repeatable coal fire is defined in the smouldering apparatus and suppression is attempt after 300 min of free burning. The effectiveness of three water suppression methods is investigated (pipe,shower, and spray). Water was identified as a good extinguishing agent and it is shown that significant differences in extinguishing efficiency arise from different methods. The amount of water required was measured to be on the order of 1 to 2 litres of water per kg of burning coal. The CO and CO2 emissions are measured using a fire propagation calorimeter and mass flow, yields and the CO to CO2 ratio are reported as a function of the burning conditions. These experiments aim to provide a fundamental step into the understanding of subsurface fires, asses their impact in global emissions and find the best method to extinguish them.

  14. Emissions from carpet combustion in a pilot-scale rotary kiln: comparison with coal and particle-board combustion

    SciTech Connect

    Stephanie Lucero Konopa; James A. Mulholland; Matthew J. Realff; Paul M. Lemieux

    2008-08-15

    The use of post-consumer carpet as a potential fuel substitute in cement kilns and other high-temperature processes is being considered to address the problem of huge volumes of carpet waste and the opportunity of waste-to-energy recovery. Carpet represents a high volume waste stream, provides high energy value, and contains other recoverable materials for the production of cement. This research studied the emission characteristics of burning 0.46-kg charges of chopped nylon carpet squares, pulverized coal, and particle-board pellets in a pilot-scale natural gas-fired rotary kiln. Carpet was tested with different amounts of water added. Emissions of oxygen, carbon dioxide, nitric oxide (NO), sulfur dioxide (SO{sub 2}), carbon monoxide (CO), and total hydrocarbons and temperatures were continuously monitored. It was found that carpet burned faster and more completely than coal and particle board, with a rapid volatile release that resulted in large and variable transient emission peaks. NO emissions from carpet combustion ranged from 0.06 to 0.15 g/MJ and were inversely related to CO emissions. Carpet combustion yielded higher NO emissions than coal and particleboard combustion, consistent with its higher nitrogen content. S{sub 2} emissions were highest for coal combustion, consistent with its higher sulfur content than carpet or particle board. Adding water to carpet slowed its burn time and reduced variability in the emission transients, reducing the CO peak but increasing NO emissions. Results of this study indicate that carpet waste can be used as an effective alternative fuel, with the caveats that it might be necessary to wet carpet or chop it finely to avoid excessive transient puff emissions due to its high volatility compared with other solid fuels, and that controlled mixing of combustion air might be used to control NO emissions from nylon carpet. 13 refs., 5 figs., 1 tab.

  15. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1996-02-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

  16. POC-scale testing of an advanced fine coal dewatering equipment/technique: Quarterly technical progress report No. 9, October 1996--December 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1997-01-21

    The advanced fine-coal cleaning techniques such as column flotation, recovers a low-ash ultra-fine size clean-coal product. However, economical dewatering of the clean coal product to less than 20 percent moisture using conventional technology is difficult. This research program objective is to evaluate a novel coal surface modification technique developed at the University of Kentucky Center for Applied Energy Research in conjunction with conventional and advanced dewatering technique at a pilot scale at the Powell Mountain Coal Company`s Mayflower preparation plant located in St. Charles, VA. During this quarter in the laboratory dewatering studies were conducted using copper and aluminum ions showed that for the low sulfur clean coal slurry addition of 0.1 Kg/t of copper ions was effective in lowering the filter cake moisture from 29 percent to 26.3 percent. Addition of 0.3 Kg/t of aluminum ions provided filter cake with 28 percent moisture. For the high sulfur clean coal slurry 0.5 Kg/t of copper and 0.1 Kg/t of aluminum ions reduced cake moisture from 30.5 percent to 28 percent respectively. Combined addition of anionic (10 g/t) and cationic (10 g/t) flocculants was effective in providing a filter cake with 29.8 percent moisture. Addition of flocculants was not effective in centrifuge dewatering. In pilot scale screen bowl centrifuge dewatering studies it was found that the clean coal slurry feed rate of 30 gpm was optimum to the centrifuge, which provided 65 percent solids capture. Addition of anionic or cationic flocculants was not effective in lowering of filter cake moisture, which remained close to 30 percent for both clean coal slurries.

  17. Cyclone reburn using coal-water fuel: Pilot-scale development and testing. Final report

    SciTech Connect

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  18. Cyclone reburn using coal-water fuel: Pilot-scale development and testing

    SciTech Connect

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  19. Measurement and capture of fine and ultrafine particles from a pilot-scale pulverized coal combustor with an electrostatic precipitator.

    PubMed

    Li, Ying; Suriyawong, Achariya; Daukoru, Michael; Zhuang, Ye; Biswas, Pratim

    2009-05-01

    Experiments were carried out in a pilot-scale pulverized coal combustor at the Energy and Environmental Research Center (EERC) burning a Powder River Basin (PRB) subbituminous coal. A scanning mobility particle sizer (SMPS) and an electrical low-pressure impactor (ELPI) were used to measure the particle size distributions (PSDs) in the range of 17 nm to 10 microm at the inlet and outlet of the electrostatic precipitator (ESP). At the ESP inlet, a high number concentration of ultrafine particles was found, with the peak at approximately 75 nm. A trimodal PSD for mass concentration was observed with the modes at approximately 80-100 nm, 1-2 microm, and 10 microm. The penetration of ultrafine particles through the ESP increased dramatically as particle size decreased below 70 nm, attributable to insufficient or partial charging of the ultrafine particles. Injection of nanostructured fine-particle sorbents for capture of toxic metals in the flue gas caused high penetration of the ultrafine particles through the ESP. The conventional ESP was modified to enhance charging using soft X-ray irradiation. A slipstream of flue gas was introduced from the pilot-scale facility and passed through this modified ESP. Enhancement of particle capture was observed with the soft X-ray irradiation when moderate voltages were used in the ESP, indicating more efficient charging of fine particles. PMID:19583155

  20. Clean and Secure Energy from Coal

    SciTech Connect

    Smith, Philip; Davies, Lincoln; Kelly, Kerry; Lighty, JoAnn; Reitze, Arnold; Silcox, Geoffrey; Uchitel, Kirsten; Wendt, Jost; Whitty, Kevin

    2014-08-31

    The University of Utah, through their Institute for Clean and Secure Energy (ICSE), performed research to utilize the vast energy stored in our domestic coal resources and to do so in a manner that will capture CO2 from combustion from stationary power generation. The research was organized around the theme of validation and uncertainty quantification (V/UQ) through tightly coupled simulation and experimental designs and through the integration of legal, environment, economics and policy issues. The project included the following tasks: • Oxy-Coal Combustion – To ultimately produce predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. • High-Pressure, Entrained-Flow Coal Gasification – To ultimately provide a simulation tool for industrial entrained-flow integrated gasification combined cycle (IGCC) gasifier with quantified uncertainty. • Chemical Looping Combustion (CLC) – To develop a new carbon-capture technology for coal through CLC and to transfer this technology to industry through a numerical simulation tool with quantified uncertainty bounds. • Underground Coal Thermal Treatment – To explore the potential for creating new in-situ technologies for production of synthetic natural gas (SNG) from deep coal deposits and to demonstrate this in a new laboratory-scale reactor. • Mercury Control – To understand the effect of oxy-firing on the fate of mercury. • Environmental, Legal, and Policy Issues – To address the legal and policy issues associated with carbon management strategies in order to assess the appropriate role of these technologies in our evolving national energy portfolio. • Validation/Uncertainty Quantification for Large Eddy Simulations of the Heat Flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility – To produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers.

  1. Performance evaluation of a ceramic cross-flow filter on a bench- scale coal gasifier

    SciTech Connect

    Ciliberti, D.F.; Lippert, T.E.

    1985-01-01

    The Department of Energy is currently supporting a program that will aid in the development of cross flow filtration technology as applied to combined cycle power generation with coal gasification. The stated overall goal is to gain information on both the operational and economic feasibility of the implementation of cross flow filtration in various gasifier options. Westinghouse has prepared a comprehensive program that will lead directly to these program goals in an efficient manner.

  2. Performance evaluation of a ceramic cross-flow filter on a bench- scale coal gasifier

    SciTech Connect

    Ciliberti, D.F.; Lippert, T.E.

    1984-01-01

    The Department of Energy is currently supporting a program that will aid in the development of cross flow filtration technology as applied to combined cycle power generation with coal gasification. The stated overall goal is to gain information on both the operational and economic feasibility of the implementation of cross flow filtration in various gasifier options. Westinghouse has prepared a comprehensive program that will lead directly to these program goals in an efficient manner.

  3. Performance evaluation of a ceramic cross-flow filter on a bench- scale coal gasifier

    SciTech Connect

    Ciliberti, D.F.; Lippert, T.E.

    1986-01-01

    The Department of Energy is currently supporting a program that will aid in the development of cross flow filtration technology as applied to combined cycle power generation with coal gasification. The stated overall goal is to gain information on both the operational and economic feasibility of the implementation of cross flow filtration in various gasifier options. Westinghouse has prepared a comprehensive program that will lead directly to these program goals in an efficient manner.

  4. Preparation and characterization of high-strength calcium silicate boards from coal-fired industrial solid wastes

    NASA Astrophysics Data System (ADS)

    Cao, Zhao; Cao, Yong-dan; Zhang, Jin-shan; Sun, Chun-bao; Li, Xian-long

    2015-08-01

    To realize the comprehensive utilization of coal-fired industrial solid wastes, a novel high-strength board was prepared from calcium silicate slag, fly ash, and flue gas desulfurization (FGD) gypsum. The changes in mineral phases, chemical structure, and morphology during hydration were investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). A traditional board made from quartz and lime was prepared as a reference. The novel board not only consumes a lot of solid wastes, but also meets the strength requirement of the class-five calcium silicate board according to the Chinese Standard JC/T 564.2—2008. Microanalysis showed that hydrated calcium silicate gel (C-S-H(I)), ettringite, tobermorite, and xonotlite were successively generated in the novel board by synergistic hydration of the mixed solid wastes. The board strength was improved by the formation of tobermorite and xonotlite but decreased by unhydrated quartz. It was demonstrated that quartz was not completely hydrated in the traditional board. As a result, the flexural strength of the traditional board was much lower than that of the novel board.

  5. Coal production 1989

    SciTech Connect

    Not Available

    1990-11-29

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  6. Catalytic Two-Stage Liquefaction (CTSL{trademark}) process bench studies and PDU scale-up with sub-bituminous coal. Final report

    SciTech Connect

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.T.; Stalzer, R.H.; Smith, T.O.

    1993-03-01

    Reported are the details and results of Laboratory and Bench-Scale experiments using sub-bituminous coal conducted at Hydrocarbon Research, Inc., under DOE Contract No. DE-AC22-88PC88818 during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with testing of the baseline Catalytic Two-Stage Liquefaction (CTSL{trademark}) process with comparisons with other two stage process configurations, catalyst evaluations and unit operations such as solid separation, pretreatments, on-line hydrotreating, and an examination of new concepts. In the overall program, three coals were evaluated, bituminous Illinois No. 6, Burning Star and sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The runs (experiments) concern process variables, variable reactor volumes, catalysts (both supported, dispersed and rejuvenated), coal cleaned by agglomeration, hot slurry treatments, reactor sequence, on-line hydrotreating, dispersed catalyst with pretreatment reactors and CO{sub 2}/coal effects. The tests involving the Wyoming and New Mexico Coals are reported herein, and the tests involving the Illinois coal are described in Topical Report No. 2. On a laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO{sub 2} addition and sulfur compound effects were conducted and reported in Topical Report No. 3. Other microautoclave tests are described in the Bench Run sections to which they refer such as: rejuvenated catalyst, coker liquids and cleaned coals. The microautoclave tests conducted for modelling the CTSL{trademark} process are described in the CTSL{trademark} Modelling section of Topical Report No. 3 under this contract.

  7. Clean coal technologies market potential

    SciTech Connect

    Drazga, B.

    2007-01-30

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  8. Nano-Scale Interpenetrating Phase Composites (IPC S) for Industrial and Vehicle Applications

    SciTech Connect

    Hemrick, James Gordon; Hu, Michael Z.

    2010-06-01

    A one-year project was completed at Oak Ridge National Laboratory (ORNL) to explore the technical and economic feasibility of producing nano-scale Interpenetrating Phase Composite (IPC) components of a usable size for actual testing/implementation in a real applications such as high wear/corrosion resistant refractory shapes for industrial applications, lightweight vehicle braking system components, or lower cost/higher performance military body and vehicle armor. Nano-scale IPC s with improved mechanical, electrical, and thermal properties have previously been demonstrated at the lab scale, but have been limited in size. The work performed under this project was focused on investigating the ability to take the current traditional lab scale processes to a manufacturing scale through scaling of these processes or through the utilization of an alternative high-temperature process.

  9. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications

    SciTech Connect

    Levasseur, Armand

    2014-01-01

    This Topical Report outlines guidelines and key considerations for design and operation of pulverized coal-fired boilers for oxy-combustion. The scope addressed includes only the boiler island, not the entire oxy-fired CO{sub 2} capture plant. These guidelines are primarily developed for tangential-fired boilers and focus on designs capable of dual air and oxy-fired operation. The guidelines and considerations discussed are applicable to both new units and existing boiler retrofits. These guidelines are largely based on the findings from the extensive 15 MW{sub th} pilot testing and design efforts conducted under this project. A summary level description is provided for each major aspect of boiler design impacted by oxy-combustion, and key considerations are discussed for broader application to different utility and industrial designs. Guidelines address the boiler system arrangement, firing system, boiler thermal design, ducting, materials, control system, and other key systems.

  10. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal, Annual Progress Report, October 1, 2003 through September 30, 2004

    SciTech Connect

    Andresen, John; Schobert, Harold; Miller, Bruce G

    2006-03-01

    Since 1998, The Pennsylvania State University (PSU) has been successfully operating the Consortium for Premium Carbon Products from Coal (CPCPC), which is a vehicle for industry-driven research on the promotion, development, and transfer of innovative technology on premium carbon produces from coal to the U.S. industry. The CPCPC is an initiative being led by PSU, its co-charter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provides the base funding for the program, with PSU responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity has continued under the present cooperative agreement, No. DE-FC26-03NT41874, which started October 1, 2003. The objective of the second agreement is to continue the successful operation of the CPCPC. The CPCPC has enjoyed tremendous success with its organizational structure, that includes PSU and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC is its industry-led council that selects proposals submitted by CPCPC members to ensure CPCPC target areas have strong industrial support. A second contract was executed with DOE NETL starting in October 2003 to continue the activities of CPCPC. An annual funding meeting was held in October 2003 and the council selected 10 projects for funding. Base funding for the projects is provided by NETL with matching funds from industry. Subcontracts were let from Penn State to the various subcontractors on March 1, 2004.

  11. Continuous bench-scale slurry catalyst testing: Direct coal liquification of Rawhide sub-bituminous coal. Technical report, July 1995--December 1995

    SciTech Connect

    Coless, L.A.; Poole, M.C.; Wen, M.Y.

    1996-05-24

    In 1994 extensive tests were conducted in the Exxon Research and Engineering Recycle Coal Liquefaction Unit (RCLU) in Baton Rouge, Louisiana. The work conducted in 1994 explored a variety of dispersed iron molybdenum promoted catalyst systems for direct coal liquefaction of Rawhide subbituminus coal. The goal was to identify the preferred iron system. We learned that among the catalysts tested, all were effective; however, none showed a large process advantage over the others. In 1995, we tested dispersed molybdenum catalysts systems for direct coal liquefaction on a second subbituminous coal, Black Thunder. Catalyst properties are shown in Table 1. We also checked a molybdenum promoted iron case, as well as the impact of process variables, such as sulfur type, hydrogen treat rate, and catalyst addition rate, as shown in Table 2. In 1995, we ran 18 material balances over a 7 week period, covering 7 conditions. This report covers the 1995 operations and results.

  12. An assessment of the long-term environmental impacts of reusing alkaline clay on coal refuse piles with a dynamic solute transport model at a watershed scale

    NASA Astrophysics Data System (ADS)

    Xu, Y.; Liang, X.; Davis, T. W.; Patterson, J.; Jaw, F. K.; Koranchie-Boah, P.

    2011-12-01

    Coal refuse piles play a significant role in producing acid mining drainage (AMD) that deteriorates water quality at a watershed scale. The waste produced from coal refuse piles results in a decrease of the pH value in soil water and river flow. Metal compounds, such as ferric and ferrous solutions, are also continuously released from the coal pile due to the extensive and complicated chemical reactions in the acidic environment. Alkaline clay, a byproduct of alumina refining process, has a high residual pH in the material. If the alkaline clay is used innovatively with the coal mine refuse, the problems associated with each (e.g., high and low pH values) are likely to be effectively resolved. In addition, the solubility of the sulfur and iron will be reduced significantly. This will effectively eliminate the AMD problem at the coal refuse pile and improve the water quality at the watershed scale. This study investigates the long-term impacts of the combined mixture (i.e., alkaline clay + coal refuse) on the environment (e.g., in the soil column and in the river system) through systematic modeling simulations in a combination with field measurements. In particular, a dynamic solute transport model that accounts for processes of the pyrite oxidation, oxygen diffusion, absorption, desorption, and advection is developed and is coupled with the Distributed Hydrology Soil and Vegetation Model (DHSVM) to assess the environmental impacts at the watershed scale. The model-simulated sulfur and iron concentrations are compared with field observations and the long-term impacts of the combined mixture (i.e., alkaline clay + coal refuse) on the environment are investigated. This study paves the way for monitoring and assessing the impacts of the reuse of the alkaline clay and refuse mixture on the environment at a watershed scale.

  13. Software sensor design considering oscillating conditions as present in industrial scale fed-batch cultivations.

    PubMed

    Lyubenova, V; Junne, S; Ignatova, M; Neubauer, P

    2013-07-01

    Investigations of inhomogeneous dynamics in industrial-scale bioreactors can be realized in laboratory simulators. Such studies will be improved by on line observation of the growth of microorganisms and their product synthesis at oscillating substrate availability which represents the conditions in industrial-scale fed-batch cultivations. A method for the kinetic monitoring of such processes, supported by on line measurements accessible in industrial practice, is proposed. It consists of a software sensor (SS) system composed of a cascade structure. Process kinetics are simulated in models with a structure including time-varying yield coefficients. SSs for measured variable kinetics have classical structures. The SS design of unmeasured variables is realized after a linear transformation using a logarithmic function. For these software sensors, a tuning procedure is proposed, at which an arbitrary choice of one tuning parameter value that guarantees stability of the monitoring system allows the calculation of the optimal values of six parameters. The effectiveness of the proposed monitoring approach is demonstrated with experimental data from a glucose-limited fed-batch process of Bacillus subtilis in a laboratory two-compartment scale down reactor which tries to mimic the conditions present in industrial scale nutrient-limited fed-batch cultivations. PMID:23436309

  14. Insect control and walnut quality following large-scale industrial radio frequency treatments

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Industrial-scale radio frequency (RF) treatments producing a minimum temperature of 52°C for 5 min were developed to control insect pests in in-shell walnuts. RF treatments for both unwashed and air dried walnuts resulted in 100% mortality of fifth-instar navel orangeworm larvae, the most heat toler...

  15. Economies of scale and vertical integration in the investor-owed electric utility industry

    SciTech Connect

    Thompson, H.G.; Islam, M.; Rose, K.

    1996-01-01

    This report analyzes the nature of costs in a vertically integrated electric utility. Findings provide new insights into the operations of the vertically integrated electric utility and supports earlier research on economics of scale and density; results also provide insights for policy makers dealing with electric industry restructuring issues such as competitive structure and mergers. Overall, results indicate that for most firms in the industry, average costs would not be reduced through expansion of generation, numbers of customers, or the delivery system. Evidently, the combination of benefits from large-scale technologies, managerial experience, coordination, or load diversity have been exhausted by the larger firms in the industry; however many firms would benefit from reducing their generation-to-sales ratio and by increasing sales to their existing customer base. Three cost models were used in the analysis.

  16. H.R. 2877: A Bill to require the Secretary of the Interior to determine the impact of leasing Federal lands for coal mining, on the existing mining industry prior to issuing Federal coal mining leases, and for other purposes. Introduced in the House of Representatives, One Hundred Third Congress, First Session, August 5, 1993

    SciTech Connect

    1993-12-31

    The report H.R. 2877 is a bill to require the Secretary of the Interior to determine the impact of leasing Federal lands for coal mining, on the existing mining industry prior to issuing Federal coal mining leases. The proposed legislative text is included.

  17. Coal Extraction - Environmental Prediction

    USGS Publications Warehouse

    Cecil, C. Blaine; Tewalt, Susan J.

    2002-01-01

    Coal from the Appalachian region has supplied energy to the Nation for more than 200 years. Appalachian coal fueled America through a civil war and helped win two world wars. Appalachian coal has also provided fuel for keeping America warm in the winter and cool in the summer and has served as the basis for the steel, automobile, organic chemicals, chlorine, and aluminum industries. These benefits have not come without environmental costs, however. Coal extraction and utilization have had significant environmental impacts.

  18. Study of application of ERTS-A imagery to fracture-related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J.; Russell, O. R.; Martin, K. R. (Principal Investigator)

    1973-01-01

    The author has identified the following significant results. Mined land reclamation analysis procedures developed within the Indiana portion of the Illinois Coal Basin were independently tested in Ohio utilizing 1:80,000 scale enlargements of ERTS-1 image 1029-15361-7 (dated August 21, 1972). An area in Belmont County was selected for analysis due to the extensive surface mining and the different degrees of reclamation occurring in this area. Contour mining in this area provided the opportunity to extend techniques developed for analysis of relatively flat mining areas in Indiana to areas of rolling topography in Ohio. The analysts had no previous experience in the area. Field investigations largely confirmed office analysis results although in a few areas estimates of vegetation percentages were found to be too high. In one area this error approximated 25%. These results suggest that systematic ERTS-1 analysis in combination with selective field sampling can provide reliable vegetation percentage estimates in excess of 25% accuracy with minimum equipment investment and training. The utility of ERTS-1 for practical and reasonably reliable update of mined lands information for groups with budget limitations is suggested. Many states can benefit from low cost updates using ERTS-1 imagery from public sources.

  19. Coal Activities for Secondary Students.

    ERIC Educational Resources Information Center

    American Coal Foundation, Washington, DC.

    This collection of lesson plans designed for teachers of 4th- through 12th-grade students utilizes an assortment of teaching strategies for topics related to coal and the coal industry. Activities cover the following topics: coal formation; coal identification; "the geologist's dilemma" (a supply and demand activity); geologic time and the…

  20. Coal market momentum converts skeptics

    SciTech Connect

    Fiscor, S.

    2006-01-15

    Tight supplies, soaring natural gas prices and an improving economy bode well for coal. Coal Age presents it 'Forecast 2006' a survey of 200 US coal industry executives. Questions asked included predicted production levels, attitudes, expenditure on coal mining, and rating of factors of importance. 7 figs.

  1. Computer Aided Design of Advanced Turbine Airfoil Alloys for Industrial Gas Turbines in Coal Fired Environments

    SciTech Connect

    G.E. Fuchs

    2007-12-31

    Recent initiatives for fuel flexibility, increased efficiency and decreased emissions in power generating industrial gas turbines (IGT's), have highlighted the need for the development of techniques to produce large single crystal or columnar grained, directionally solidified Ni-base superalloy turbine blades and vanes. In order to address the technical difficulties of producing large single crystal components, a program has been initiated to, using computational materials science, better understand how alloy composition in potential IGT alloys and solidification conditions during processing, effect castability, defect formation and environmental resistance. This program will help to identify potential routes for the development of high strength, corrosion resistant airfoil/vane alloys, which would be a benefit to all IGT's, including small IGT's and even aerospace gas turbines. During the first year, collaboration with Siemens Power Corporation (SPC), Rolls-Royce, Howmet and Solar Turbines has identified and evaluated about 50 alloy compositions that are of interest for this potential application. In addition, alloy modifications to an existing alloy (CMSX-4) were also evaluated. Collaborating with SPC and using computational software at SPC to evaluate about 50 alloy compositions identified 5 candidate alloys for experimental evaluation. The results obtained from the experimentally determined phase transformation temperatures did not compare well to the calculated values in many cases. The effects of small additions of boundary strengtheners (i.e., C, B and N) to CMSX-4 were also examined. The calculated phase transformation temperatures were somewhat closer to the experimentally determined values than for the 5 candidate alloys, discussed above. The calculated partitioning coefficients were similar for all of the CMSX-4 alloys, similar to the experimentally determined segregation behavior. In general, it appears that computational materials science has become a

  2. Numerical investigation of pyrolysis of a Loy Yang coal in a lab-scale furnace at elevated pressures

    NASA Astrophysics Data System (ADS)

    Hart, James; Al-Abbas, Audai Hussein; Naser, Jamal

    2013-12-01

    A computational fluid dynamics (CFD) model of the pyrolysis of a Loy Yang low-rank coal in a pressurised drop tube furnace (pdtf) was undertaken evaluating Arrhenius reaction rate constants. The paper also presents predictions of an isothermal flow through the drop tube furnace. In this study, a pdtf reactor operated at pressures up to 15 bar and at a temperature of 1,173 K with particle heating rates of approximately 105 K s-1 was used. The CFD model consists of two geometrical sections; flow straightner and injector. The single reaction and two competing reaction models were employed for this numerical investigation of the pyrolysis process. The results are validated against the available experimental data in terms of velocity profiles for the drop tube furnace and the particle mass loss versus particle residence times. The isothermal flow results showed reasonable agreement with the available experimental data at different locations from the injector tip. The predicted results of both the single reaction and competing reaction modes showed slightly different results. In addition, several reaction rate constants were tested and validated against the available experimental data. The most accurate results were being Badzioch and Hawksley (Ind Eng Chem Process Des Dev 9:521-530, 1970) with a single reaction model and Ubhayakar et al. (Symp (Int) Combust 16:427-436, 1977) for two competing reactions. These numerical results can provide useful information towards future modelling of the behaviour of Loy Yang coal in a full scale tangentially-fired furnace.

  3. Development of a retrofit coal combustor for industrial applications, (Phase 1-A). Technical progress report, July--September 1988

    SciTech Connect

    Not Available

    1988-10-01

    During this past quarter, two tandem-fired pulse combustors were designed to fire at a nominal rate of 3.5 to 5.5 MMBtu/hr under continuation of Phase I work on DOE project DE-AC22-87PC79654. In prior work, MTCI demonstrated the operation of a 1--2 MMBtu/h coal-fired tandem pulse combustor that is intended for small industrial applications. These component tests emphasized verification of key design issues such as combustor coupling, slag rejection, and staged air addition. The current work, which represents an extension of the Phase I effort, focuses on integrated testing of the tandem pulse combustor with a fire-tube boiler, and the addition of a slag quench vessel. A tandem-fired pulse combustion unit designed to fire at a nominal rate of 3.5-5 MMBtu/hr was designed and fabricated. The configuration includes two combustion chambers cast in a single monolith, tailpipes cast separately with annular air preheating capability, and a cyclonic decoupler. Design analysis and evaluations were performed to optimize the system with respect to minimizing heat losses, size, and cost. Heat losses from the combustor and decoupler walls are predicted to be approximately 3 percent. The final designs for the ancillary items (slag quench, tertiary air addition, scrubber and sampling system) were completed and fabrication and installation initiated. A Cleaver-Brooks 150 hp-4 pass boiler was delivered and installed and modifications for interfacing with the retrofit pulse combustor unit completed. A below-ground slag collection pit was excavated to permit direct in-line coupling of the combustor to the boiler and to reduce head-room requirements. The pit is 30 inches deep and lined with waterproof and fireproof siding.

  4. Potential for improved radiation thermometry measurement uncertainty through implementing a primary scale in an industrial laboratory

    NASA Astrophysics Data System (ADS)

    Willmott, Jon R.; Lowe, David; Broughton, Mick; White, Ben S.; Machin, Graham

    2016-09-01

    A primary temperature scale requires realising a unit in terms of its definition. For high temperature radiation thermometry in terms of the International Temperature Scale of 1990 this means extrapolating from the signal measured at the freezing temperature of gold, silver or copper using Planck’s radiation law. The difficulty in doing this means that primary scales above 1000 °C require specialist equipment and careful characterisation in order to achieve the extrapolation with sufficient accuracy. As such, maintenance of the scale at high temperatures is usually only practicable for National Metrology Institutes, and calibration laboratories have to rely on a scale calibrated against transfer standards. At lower temperatures it is practicable for an industrial calibration laboratory to have its own primary temperature scale, which reduces the number of steps between the primary scale and end user. Proposed changes to the SI that will introduce internationally accepted high temperature reference standards might make it practicable to have a primary high temperature scale in a calibration laboratory. In this study such a scale was established by calibrating radiation thermometers directly to high temperature reference standards. The possible reduction in uncertainty to an end user as a result of the reduced calibration chain was evaluated.

  5. Development of a coal-fired combustion system for industrial process heating applications. Phase 3 final report, November 1992--December 1994

    SciTech Connect

    1995-09-26

    A three phase research and development program has resulted in the development and commercialization of a Cyclone Melting System (CMS{trademark}), capable of being fueled by pulverized coal, natural gas, and other solid, gaseous, or liquid fuels, for the vitrification of industrial wastes. The Phase 3 research effort focused on the development of a process heater system to be used for producing value added glass products from the vitrification of boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project was to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential for successful commercialization. The demonstration test consisted of one test run with a duration of 105 hours, approximately one-half (46 hours) performed with coal as the primary fuel source (70% to 100%), the other half with natural gas. Approximately 50 hours of melting operation were performed vitrifying approximately 50,000 lbs of coal-fired utility boiler flyash/dolomite mixture, producing a fully-reacted vitrified product.

  6. Development of pressurized coal partial combustor

    SciTech Connect

    Yoshida, K.; Ino, T.; Yamamoto, T.; Kimura, N.

    1995-12-31

    The integrated gasification combined cycle (IGCC), an environment-friendly power generation system of high thermal efficiency, is being developed via various approaches around the world. The oxygen-blown entrained flow gasification process is a relatively simple method of producing medium calorie coal gas suitable for application to gas turbines. Various systems for this process have been developed to a demonstration level in Europe and America. Japan has actively been developing the air-blown process. However, taking stable molten slag discharge into consideration, coal must be supplied at two stages to raise the combustor temperature in ash molten part. Only two reports have been presented regarding two-stage coal supply. One is the report on an experiment with the Hycol gasifier, in which air feed ratio is varied, with coal feed fixed. The other is report on a simulation study with various gasifier coal feed ratios, conducted at Central Research Institute of Electric Power Industry. It seems that the appropriate feed ratio has not yet been established. Through this activity, a unique furnace construction has been established, and these influences of stoichiometric air ratio, of oxygen enrichment, of char recycling and of coal types on performance have been clarified. The purpose of the present study is to apply this developed CPC techniques to a Pressurized CPC (PCPC), thereby improving the IGCC technology. For the present study, we conducted systematic experiments on the air-blown process with a two stage dry feed system, using a 7 t/d-coal bench scale PCPC test facility, operated at the pressure of 0.4 MPa, and clarified the influence of coal feed ratio on coal gasification performance. This report describes the above-mentioned bench scale test procedures and results, and also some informations about a plan of a 25 t/d-coal pilot test system.

  7. Evaluation of Multiple-Scale 3D Characterization for Coal Physical Structure with DCM Method and Synchrotron X-Ray CT

    PubMed Central

    Yang, Yushuang; Yang, Jianli; Nie, Yihang; Jia, Jing; Wang, Yudan

    2015-01-01

    Multiscale nondestructive characterization of coal microscopic physical structure can provide important information for coal conversion and coal-bed methane extraction. In this study, the physical structure of a coal sample was investigated by synchrotron-based multiple-energy X-ray CT at three beam energies and two different spatial resolutions. A data-constrained modeling (DCM) approach was used to quantitatively characterize the multiscale compositional distributions at the two resolutions. The volume fractions of each voxel for four different composition groups were obtained at the two resolutions. Between the two resolutions, the difference for DCM computed volume fractions of coal matrix and pores is less than 0.3%, and the difference for mineral composition groups is less than 0.17%. This demonstrates that the DCM approach can account for compositions beyond the X-ray CT imaging resolution with adequate accuracy. By using DCM, it is possible to characterize a relatively large coal sample at a relatively low spatial resolution with minimal loss of the effect due to subpixel fine length scale structures. PMID:25861674

  8. Elastic and optical anisotropy of the single-coal monolithic high-temperature (HT) carbonization products obtained on a laboratory scale

    SciTech Connect

    Marta Krzesinska; Slawomira Pusz; Andrzej Koszorek

    2005-10-01

    The aim of the present study was to investigate the directional dependences of the elastic and optical properties of monolithic single-coal high-temperature (HT) carbonization products obtained on a laboratory scale (with very slow heating rate) from coals of different caking propensity. Sixteen monolithic HT carbonization products, mainly cokes, were produced in the Jenkner retort furnace using 16 various types of coals of varying rank (from 83.1 wt % carbon to 98.3 wt % carbon) with a Roga index (RI) in the range of 0-76. Coals were carbonized in the form of monolithic blocks. The physical parameters such as true density, porosity, ultrasonic velocity, and dynamic elastic moduli, as well as optical reflectance parameters (R{sub max}, R{sub min}, R{sub am}), were determined for the resultant products. The elastic and optical properties of the HT carbonization products were related to their porosity and the rank of the parent coals. It was determined that the HT carbonization products exhibit the different directional properties of the studied parameters, and they can be divided into three groups, with respect to the observed differences. The properties of these groups were related to the parent coal rank and the caking propensity (i.e., to the RI value). Anisotropy of the coke matrix structure was determined to be important for discussion about the anisotropic properties of cokes. 50 refs., 9 figs., 4 tabs.

  9. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Wenglarz, R.A.

    1994-08-01

    Several technology advances since the early coal-fueled turbine programs that address technical issues of coal as a turbine fuel have been developed in the early 1980s: Coal-water suspensions as fuel form, improved methods for removing ash and contaminants from coal, staged combustion for reducing NO{sub x} emissions from fuel-bound nitrogen, and greater understanding of deposition/erosion/corrosion and their control. Several Advanced Coal-Fueled Gas Turbine Systems programs were awarded to gas turbine manufacturers for for components development and proof of concept tests; one of these was Allison. Tests were conducted in a subscale coal combustion facility and a full-scale facility operating a coal combustor sized to the Allison Model 501-K industrial turbine. A rich-quench-lean (RQL), low nitrogen oxide combustor design incorporating hot gas cleanup was developed for coal fuels; this should also be applicable to biomass, etc. The combustor tests showed NO{sub x} and CO emissions {le} levels for turbines operating with natural gas. Water washing of vanes from the turbine removed the deposits. Systems and economic evaluations identified two possible applications for RQL turbines: Cogeneration plants based on Allison 501-K turbine (output 3.7 MW(e), 23,000 lbs/hr steam) and combined cycle power plants based on 50 MW or larger gas turbines. Coal-fueled cogeneration plant configurations were defined and evaluated for site specific factors. A coal-fueled turbine combined cycle plant design was identified which is simple, compact, and results in lower capital cost, with comparable efficiency and low emissions relative to other coal technologies (gasification, advanced PFBC).

  10. Cooperative coal marketing arrangement in eastern Kentucky: a feasibility report

    SciTech Connect

    Not Available

    1981-07-01

    The purpose of this study is to assess the feasibility of establishing coal cooperatives in Appalachian Kentucky. To survive in today's coal market, the small independent sector of the coal industry, defined as operators producing no more than two-hundred thousand tons per year, must gain access to long-term contract markets and to economies of scale in coal transportation. In both of these areas, the larger coal producers enjoy a substantial competitive advantage. Also, the small operators must find ways of coping with drastically increased costs of permitting, production and reclamation. In recent years, cooperative marketing and production arrangements have increasingly been seen as possible mechanisms for enabling small operators to remain viable in today's coal market while retaining for the coal industry and the economy in general the independence, efficient production, recovery of coal from marginal deposits, and local orientation and entrepreneurship of the small operator. Although cooperative endeavors in permitting, meeting health and safety requirements, increasing mining efficiency, and joint purchase of materials and equipment can decrease costs for the small operator, the greatest need is for cooperative marketing mechanisms which will enable small operators to amass sufficient reserves and productive capacity to jointly gain large-volume, long-term sales contracts and to command the efficiencies and lower costs of coal shipment by unit train.

  11. Scale development of safety management system evaluation for the airline industry.

    PubMed

    Chen, Ching-Fu; Chen, Shu-Chuan

    2012-07-01

    The airline industry relies on the implementation of Safety Management System (SMS) to integrate safety policies and augment safety performance at both organizational and individual levels. Although there are various degrees of SMS implementation in practice, a comprehensive scale measuring the essential dimensions of SMS is still lacking. This paper thus aims to develop an SMS measurement scale from the perspective of aviation experts and airline managers to evaluate the performance of company's safety management system, by adopting Schwab's (1980) three-stage scale development procedure. The results reveal a five-factor structure consisting of 23 items. The five factors include documentation and commands, safety promotion and training, executive management commitment, emergency preparedness and response plan and safety management policy. The implications of this SMS evaluation scale for practitioners and future research are discussed. PMID:22405247

  12. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning. Third quarterly technical progress report, April 1996--June 30, 1996

    SciTech Connect

    Yoon, R.-H.; Mesenyashin, A.; Yan, E.S.; Luttrell, G.H.; Adel, G.T.

    1996-10-01

    The Pittsburgh Energy Technology Center (PETC) developed a triboelectrostatic separation (TES) process which is capable of removing mineral matter from coal without using water. A distinct advantage of this dry coal cleaning process is that it does not entail costly steps of dewatering which is a common problem associated with conventional fine coal cleaning processes. It is the objective of this project to conduct a series of proof-of-concept (POC) scale tests at a throughput of 200--250 kg/hr and obtain scale- up information. Prior to the POC testing, bench-scale test work will be conducted with the objective of increasing the separation efficiency and throughput, for which changes in the basic designs for the charger and the separator may be necessary. The bench- and POC- scale test work will be carried out to evaluate various operating parameters and establish a reliable scale-up procedure. The scale-up data will be used to analyze the economic merits of the TES process. At present, the project is at the stage of engineering design (Task 3). Work accomplished during this reporting period include the construction of a Faraday Cage for measurement of particle charges (Subtask 3.1), construction of a bench-scale triboelectrostatic separator (Subtask 3.2) and development of a theoretical model for predicting motion of charged particles in a non-uniform electrostatic field (Subtask 3.2). This model will be useful for designing the POC module.

  13. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect

    R.-H. Yoon; G.H. Luttrell; A.D. Walters

    2000-01-01

    During the past quarter, several modifications were made to the TES unit and the materials handling system. The cylindrical electrodes were replaced by a set of screen electrodes to provide a more uniform electrostatic field. The problem with the recycle conveyor neutralizing the particle charge was also corrected by replacing it with a bucket elevator. In addition, problems with the turbocharger were corrected by increasing the number of charging stages from one to two. These modifications have significantly improved the separation performance and have permitted the POC-scale unit to achieve results in line with those obtained by the bench-scale separator. The testing phase of the project was continued at a rapid pace during this quarter. The test work showed that the modifications to the TES unit and the reduction in feed size from 28 mesh to 35 mesh resulted in significant overall improvement in yield and combustible recovery compared to the data reported in the last quarter. At that time, there was a significant discrepancy between the bench-scale and the pilot-scale results. The pilot-scale test work is now approaching the bench scale test results. However, further pilot-scale test work is required to further improve the results and duplicate the bench-scale test work.

  14. Development and testing of commercial-scale, coal-fired combustion systems: Phase 3, Technical progress report, October 1993--December 1993

    SciTech Connect

    1993-12-31

    The objective of this Phase III program for the development of a commercial scale, coal-fired combustion system is to develop and integrate all system components from fuel through total system controls building upon the prior Phase I and II development accomplishments of the MTCI pulse combustion technology and to then field test the complete system in order to evaluate its potential marketability. During this 13th quarter, a steam generation cost model was developed to compare the economics of steam production in the commercial-scale, coal-fired pulse combustion system with that in a natural gas- or oil-fired system. The purpose of this model is to define the competitive capital cost range for the MTCI system under a specified set of technical and economic conditions. A current preliminary estimate of the MTCI pulse coal combustion system capital cost turns out to be about $120,000 and this is within the target range of the US commercial boiler market sector. European differential fuel costs are expected to be more favorable. Several conceptual arrangements for coal reburn and char burnout were evaluated. The arrangement was selected based on the following considerations viz. utilization of the existing pulse combustor as is, minimization of footprint and vertical space requirement, good mixing of coal, steam and combustion products in the reburn section, and adequate char residence time in the char burnout section.

  15. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semiannual technical progress report, February 15, 1994--August 15, 1994

    SciTech Connect

    Miller, B.G.; Scaroni, A.W.

    1994-11-30

    The Pennsylvania State University is conducting a coal-water slurry fuel (CWSF) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the viability of firing CWSF in an industrial boiler designed for heavy fuel oil. The project will also provide information to help in the design of new system specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) expanded demonstration and evaluation (installing a CWSF preparation circuit, conducting an additional 1,000 hours of testing, and installing an advanced flue gas treatment system). The boiler testing and evaluation will determine if the CWSF combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion tendencies, and fuel transport, storage, and handling characteristics can be accommodated in a boiler system designed to fire heavy fuel oil. In addition, the proof-of-concept demonstration will generate data to determine how the properties of a CWSF and its parent coal affect boiler performance. The economic factors associated with retrofitting boilers will also be evaluated. During this reporting period, the construction of the CWSF preparation circuit (as well as a dry, micronized coal circuit) continued. The CWSF preparation circuit will be completed by November 1,1994. Additional activities included receiving a coal-designed burner and installing it on the demonstration boiler, and working with DOE in selecting pollution control systems to install on the boiler.

  16. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semi-annual technical progress report, February 15--September 15, 1995

    SciTech Connect

    Miller, B.G.; Scaroni, A.W.

    1997-06-02

    A coal-water slurry fuel (CWSF) program is being undertaken to determine if CWSFs prepared from cleaned coal (containing approximately 3.5 wt.% ash and 0.9 wt.% sulfur) can be burned effectively in a heavy fuel oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. Information will also be generated to help in the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) expanded demonstration and evaluation (installing a CWSF preparation circuit, conducting an additional 1,000 hours of testing, and installing an advanced flue gas treatment system). The boiler testing and evaluation will determine if the CWSF combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion tendencies, and fuel transport, storage, and handling characteristics can be accommodated In a boiler system designed to fire heavy fuel oil. In addition, the proof-of-concept demonstration will generate data to determine how the properties of a CWSF and its parent coal affect boiler performance. The economic factors associated with retrofitting boilers will also be evaluated. The first three phases have been completed and the combustion performance of the burner that was provided with the boiler did not meet performance goals. A maximum coal combustion efficiency of 95% (target is 98%) was achieved; however, natural gas cofiring was necessary to maintain a stable flame. Consequently, the first demonstration was terminated after 500 hours. The second demonstration (Phase 4) will be conducted after a proven CWSF-designed burner is installed on the boiler. Prior to starting the second demonstration, a CWSF preparation circuit was constructed to provide flexibility in CWSF production.

  17. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semiannual technical progress report, August 15, 1994--February 15, 1995

    SciTech Connect

    Miller, B.G.

    1995-05-12

    The Pennsylvania State University is conducting a coal-water slurry fuel (CWSF) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the viability of firing CWSF in an industrial boiler designed for heavy fuel oil. Penn State and DOE have entered into a cooperative agreement to determine if CWSFs prepared from cleaned coal (containing approximately 3.5 wt.% ash and 0.9 wt.% sulfur) can be burned effectively in a heavy fuel oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will also provide information to help in the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) expanded demonstration and evaluation (installing a CWSF preparation circuit, conducting an additional 1,000 hours of testing, and installing an advanced flue gas treatment system). The boiler testing and evaluation will determine if the CWSF combustion characteristics, heat release rate, fouling and stagging behavior, corrosion and erosion tendencies, and fuel transport, storage, and handling characteristics can be accommodated in a boiler system designed to fire heavy fuel oil. In addition, the proof-of-concept demonstration will generate data to determine how the properties of a CWSF and its parent coal affect boiler performance. The economic factors associated with retrofitting boilers will also be evaluated. The first three phases (i.e., the first demonstration) have been completed and the combustion performance of the burner that was provided with the boiler did not meet performance goals. Consequently, the first demonstration has been concluded at 500 hours.

  18. The development of an industrial-scale fed-batch fermentation simulation.

    PubMed

    Goldrick, Stephen; Ştefan, Andrei; Lovett, David; Montague, Gary; Lennox, Barry

    2015-01-10

    This paper describes a simulation of an industrial-scale fed-batch fermentation that can be used as a benchmark in process systems analysis and control studies. The simulation was developed using a mechanistic model and validated using historical data collected from an industrial-scale penicillin fermentation process. Each batch was carried out in a 100,000 L bioreactor that used an industrial strain of Penicillium chrysogenum. The manipulated variables recorded during each batch were used as inputs to the simulator and the predicted outputs were then compared with the on-line and off-line measurements recorded in the real process. The simulator adapted a previously published structured model to describe the penicillin fermentation and extended it to include the main environmental effects of dissolved oxygen, viscosity, temperature, pH and dissolved carbon dioxide. In addition the effects of nitrogen and phenylacetic acid concentrations on the biomass and penicillin production rates were also included. The simulated model predictions of all the on-line and off-line process measurements, including the off-gas analysis, were in good agreement with the batch records. The simulator and industrial process data are available to download at www.industrialpenicillinsimulation.com and can be used to evaluate, study and improve on the current control strategy implemented on this facility. PMID:25449107

  19. Development of interactive workplace improvement programs in collaboration with trade associations of small-scale industries.

    PubMed

    Ito, Akiyoshi; Sakai, Kazuhiro; Kogi, Kazutaka

    2006-01-01

    Serial participatory action programs for reducing occupational safety and health risks were undertaken to know the types of support suited for small-scale industries. Working groups were formed with workplace people and occupational safety and health experts. It was agreed to develop an action-oriented strategy focusing on improving both work environment and productivity by making low-cost improvements through group work. Many workplace improvements achieved by participating enterprises and the group work procedures taken were analyzed. As supporting tools for effectively implementing the workplace improvement action programs, we developed action checklists according to industry and workplace implementation guides. Collections of local good examples also served as part of these support tools. These experiences show that keys to the sustainable action in small-scale industries are: (1) mobilization of the industry-wise network by trade associations, (2) an output-oriented strategy based on interactive group work and (3) the effective use of support tools such as low-cost action checklists and group work methods. PMID:16610539

  20. Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale.

    PubMed

    Barbot, Yann Nicolas; Thomsen, Claudia; Thomsen, Laurenz; Benz, Roland

    2015-09-01

    The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP) and biomethane recovery of industrial Laminaria japonica waste (LJW) in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC), as well as a co-digestion approach with maize silage (MS) did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g(-1) volatile solids (VS) were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g(-1) VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH₄ recovery of 189 L kg(-1) VS was achieved and a biogas composition of 55% CH₄ and 38% CO₂ was recorded. PMID:26393620

  1. Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale

    PubMed Central

    Barbot, Yann Nicolas; Thomsen, Claudia; Thomsen, Laurenz; Benz, Roland

    2015-01-01

    The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP) and biomethane recovery of industrial Laminaria japonica waste (LJW) in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC), as well as a co-digestion approach with maize silage (MS) did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g−1 volatile solids (VS) were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g−1 VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH4 recovery of 189 L kg−1 VS was achieved and a biogas composition of 55% CH4 and 38% CO2 was recorded. PMID:26393620

  2. China's post-coal growth

    NASA Astrophysics Data System (ADS)

    Qi, Ye; Stern, Nicholas; Wu, Tong; Lu, Jiaqi; Green, Fergus

    2016-08-01

    Slowing GDP growth, a structural shift away from heavy industry, and more proactive policies on air pollution and clean energy have caused China's coal use to peak. It seems that economic growth has decoupled from growth in coal consumption.

  3. Bioprocess development for kefiran production by Lactobacillus kefiranofaciens in semi industrial scale bioreactor.

    PubMed

    Dailin, Daniel Joe; Elsayed, Elsayed Ahmed; Othman, Nor Zalina; Malek, Roslinda; Phin, Hiew Siaw; Aziz, Ramlan; Wadaan, Mohamad; El Enshasy, Hesham Ali

    2016-07-01

    Lactobacillus kefiranofaciens is non-pathogenic gram positive bacteria isolated from kefir grains and able to produce extracellular exopolysaccharides named kefiran. This polysaccharide contains approximately equal amounts of glucose and galactose. Kefiran has wide applications in pharmaceutical industries. Therefore, an approach has been extensively studied to increase kefiran production for pharmaceutical application in industrial scale. The present work aims to maximize kefiran production through the optimization of medium composition and production in semi industrial scale bioreactor. The composition of the optimal medium for kefiran production contained sucrose, yeast extract and K2HPO4 at 20.0, 6.0, 0.25 g L(-1), respectively. The optimized medium significantly increased both cell growth and kefiran production by about 170.56% and 58.02%, respectively, in comparison with the unoptimized medium. Furthermore, the kinetics of cell growth and kefiran production in batch culture of L. kefiranofaciens was investigated under un-controlled pH conditions in 16-L scale bioreactor. The maximal cell mass in bioreactor culture reached 2.76 g L(-1) concomitant with kefiran production of 1.91 g L(-1). PMID:27298582

  4. Coal Production 1992

    SciTech Connect

    Not Available

    1993-10-29

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  5. Farewell, king coal!

    PubMed

    Seaton, Anthony

    2016-04-01

    Coal mining provided the power for the industrial development of the West, at great cost to the health of the workforce and, from industrial pollution, of the population. Medical appreciation of the diseases of miners was slow to develop and has been marked by controversy relating to the roles of coal and quartz and the causation of emphysema. Research by the MRC and the British coal industry resolved these issues as the industry itself declined. However, from the research has come an understanding of the influence of inhalation of different inhaled pollutants on human health that has been applied to predicting and preventing possible hazards of developing nanotechnologies. PMID:26856364

  6. Ultra scale-down prediction using microwell technology of the industrial scale clarification characteristics by centrifugation of mammalian cell broths.

    PubMed

    Tait, A S; Aucamp, J P; Bugeon, A; Hoare, M

    2009-10-01

    This article describes how a combination of an ultra scale-down (USD) shear device feeding a microwell centrifugation plate may be used to provide a prediction of how mammalian cell broth will clarify at scale. In particular a method is described that is inherently adaptable to a robotic platform and may be used to predict how the flow rate and capacity (equivalent settling area) of a centrifuge and the choice of feed zone configuration may affect the solids carry over in the supernatant. This is an important consideration as the extent of solids carry over will determine the required size and lifetime of a subsequent filtration stage or the passage of fine particulates and colloidal material affecting the performance and lifetime of chromatography stages. The extent of solids removal observed in individual wells of a microwell plate during centrifugation is shown to correlate with the vertical and horizontal location of the well on the plate. Geometric adjustments to the evaluation of the equivalent settling area of individual wells (Sigma(M)) results in an improved prediction of solids removal as a function of centrifuge capacity. The USD centrifuge settling characteristics need to be as for a range of equivalent flow rates as may be experienced at an industrial scale for a machine of different shear characteristics in the entry feed zone. This was shown to be achievable with two microwell-plate based measurements and the use of varying fill volumes in the microwells to allow the rapid study of a fivefold range of equivalent flow rates (i.e., at full scale for a particular industrial centrifuge) and the effect of a range of feed configurations. The microwell based USD method was used to examine the recovery of CHO-S cells, prepared in a 5 L reactor, at different points of growth and for different levels of exposure to shear post reactor. The combination of particle size distribution measurements of the cells before and after shear and the effect of shear on the

  7. Regional scale selenium loading associated with surface coal mining, Elk Valley, British Columbia, Canada.

    PubMed

    Wellen, Christopher C; Shatilla, Nadine J; Carey, Sean K

    2015-11-01

    Selenium (Se) concentrations in surface water downstream of surface mining operations have been reported at levels in excess of water quality guidelines for the protection of wildlife. Previous research in surface mining environments has focused on downstream water quality impacts, yet little is known about the fundamental controls on Se loading. This study investigated the relationship between mining practices, stream flows and Se concentrations using a SPAtially Referenced Regression On Watershed attributes (SPARROW) model. This work is part of a R&D program examining the influence of surface coal mining on hydrological and water quality responses in the Elk Valley, British Columbia, Canada, aimed at informing effective management responses. Results indicate that waste rock volume, a product of mining activity, accounted for roughly 80% of the Se load from the Elk Valley, while background sources accounted for roughly 13%. Wet years were characterized by more than twice the Se load of dry years. A number of variables regarding placement of waste rock within the catchments, length of buried streams, and the construction of rock drains did not significantly influence the Se load. The age of the waste rock, the proportion of waste rock surface reclaimed, and the ratio of waste rock pile side area to top area all varied inversely with the Se load from watersheds containing waste rock. These results suggest operational practices that are likely to reduce the release of Se to surface waters. PMID:26136156

  8. Characteristics of fly ashes from full-scale coal-fired power plants and their relationship to mercury adsorption

    USGS Publications Warehouse

    Lu, Y.; Rostam-Abadi, M.; Chang, R.; Richardson, C.; Paradis, J.

    2007-01-01

    Nine fly ash samples were collected from the particulate collection devices (baghouse or electrostatic precipitator) of four full-scale pulverized coal (PC) utility boilers burning eastern bituminous coals (EB-PC ashes) and three cyclone utility boilers burning either Powder River Basin (PRB) coals or PRB blends,(PRB-CYC ashes). As-received fly ash samples were mechanically sieved to obtain six size fractions. Unburned carbon (UBC) content, mercury content, and Brunauer-Emmett-Teller (BET)-N2 surface areas of as-received fly ashes and their size fractions were measured. In addition, UBC particles were examined by scanning electron microscopy, high-resolution transmission microscopy, and thermogravimetry to obtain information on their surface morphology, structure, and oxidation reactivity. It was found that the UBC particles contained amorphous carbon, ribbon-shaped graphitic carbon, and highly ordered graphite structures. The mercury contents of the UBCs (Hg/UBC, in ppm) in raw ash samples were comparable to those of the UBC-enriched samples, indicating that mercury was mainly adsorbed on the UBC in fly ash. The UBC content decreased with a decreasing particle size range for all nine ashes. There was no correlation between the mercury and UBC contents of different size fractions of as-received ashes. The mercury content of the UBCs in each size fraction, however, generally increased with a decreasing particle size for the nine ashes. The mercury contents and surface areas of the UBCs in the PRB-CYC ashes were about 8 and 3 times higher than UBCs in the EB-PC ashes, respectively. It appeared that both the particle size and surface area of UBC could contribute to mercury capture. The particle size of the UBC in PRB-CYC ash and thus the external mass transfer was found to be the major factor impacting the mercury adsorption. Both the particle size and surface reactivity of the UBC in EB-PC ash, which generally had a lower carbon oxidation reactivity than the PRB

  9. Minimizing Waste from the Oil Industry: Scale Treatment and Scrap Recycling

    SciTech Connect

    Lindberg, M.

    2002-02-26

    Naturally occurring radioactive material is technologically concentrated in the piping in systems in the oil and gas industry, especially in the offshore facilities. The activity, mainly Ra-226, in the scales in the systems are often at levels classified as low level radioactive waste (LSA) in the industry. When the components and pipes are descaled for maintenance or recycling purposes, usually by high-pressure water jetting, the LSA scales arising constitute a significant quantity of radioactive waste for disposal. A new process is under development for the treatment of scales, where the radioactive solids are separated from the inactive. This would result in a much smaller fraction to be deposited as radioactive waste. The radioactive part recovered from the scales will be reduced to a stable non-metallic salt and because the volume is significantly smaller then the original material, will minimize the cost for disposal. The pipes, that have been cleaned by high pressure water jetting can either be reused or free released by scrapping and melting for recycling.

  10. Utilization of artificial recharged effluent as makeup water for industrial cooling system: corrosion and scaling.

    PubMed

    Wei, Liangliang; Qin, Kena; Zhao, Qingliang; Noguera, Daniel R; Xin, Ming; Liu, Chengcai; Keene, Natalie; Wang, Kun; Cui, Fuyi

    2016-01-01

    The secondary effluent from wastewater treatment plants was reused for industrial cooling water after pre-treatment with a laboratory-scale soil aquifer treatment (SAT) system. Up to a 95.3% removal efficiency for suspended solids (SS), 51.4% for chemical oxygen demand (COD), 32.1% for Cl(-) and 30.0% SO4(2-) were observed for the recharged secondary effluent after the SAT operation, which is essential for controlling scaling and corrosion during the cooling process. As compared to the secondary effluent, the reuse of the 1.5 m depth SAT effluent decreased the corrosion by 75.0%, in addition to a 55.1% decline of the scales/biofouling formation (with a compacted structure). The experimental results can satisfy the Chinese criterion of Design Criterion of the Industrial Circulating Cooling Water Treatment (GB 50050-95), and was more efficient than tertiary effluent which coagulated with ferric chloride. In addition, chemical structure of the scales/biofouling obtained from the cooling system was analyzed. PMID:27191579

  11. Investigation of the relationship between particulate-bound mercury and properties of fly ash in a full-scale 100 MWe pulverized coal combustion boiler

    SciTech Connect

    Sen Li; Chin-Min Cheng; Bobby Chen; Yan Cao; Jacob Vervynckt; Amanda Adebambo; Wei-Ping Pan

    2007-12-15

    The properties of fly ash in coal-fired boilers influence the emission of mercury from power plants into the environment. In this study, seven different bituminous coals were burned in a full-scale 100 MWe pulverized coal combustion boiler and the derived fly ash samples were collected from a mechanical hopper (MH) and an electrostatic precipitator hopper (ESP). The mercury content, specific surface area (SSA), unburned carbon, and elemental composition of the fly ash samples were analyzed to evaluate the correlation between the concentration of particulate-bound mercury and the properties of coal and fly ash. For a given coal, it was found that the mercury content in the fly ash collected from the ESP was greater than in the fly ash samples collected from the MHP. This phenomenon may be due to a lower temperature of flue gas at the ESP (about 135{sup o}C) compared to the temperature at the air preheater (about 350{sup o}C). Also, a significantly lower SSA observed in MH ash might also contribute to the observation. A comparison of the fly ash samples generated from seven different coals using statistical methods indicates that the mercury adsorbed on ESP fly ashes has a highly positive correlation with the unburned carbon content, manganese content, and SSA of the fly ash. Sulfur content in coal showed a significant negative correlation with the Hg adsorption. Manganese in fly ash is believed to participate in oxidizing volatile elemental mercury (Hg{sup 0}) to ionic mercury (Hg{sup 2+}). The oxidized mercury in flue gas can form a complex with the fly ash and then get removed before the flue gas leaves the stack of the boiler.

  12. Healy Clean Coal Project: Healy coal firing at TRW Cleveland Test Facility. Final report

    SciTech Connect

    Koyama, T.; Petrill, E.; Sheppard, D.

    1991-08-01

    A test burn of two Alaskan coals was conducted at TRW`s Cleveland test facility in support of the Healy Clean Coal Project, as part of Clean Coal Technology III Program in which a new power plant will be constructed using a TRW Coal Combustion System. This system features ash slagging technology combined with NO{sub x} and SO{sub x} control. The tests, funded by the Alaska Industrial Development and Export Authority (AIDEA) and TRW, were conducted to verify that the candidate Healy station coals could be successfully fired in the TRW coal combustor, to provide data required for scale-up to the utility project size requirements, and to produce sufficient flash-calcined material (FCM) for spray dryer tests to be conducted by Joy/NIRO. The tests demonstrated that both coals are viable candidates for the project, provided the data required for scale-up, and produced the FCM material. This report describes the modifications to the test facility which were required for the test burn, the tests run, and the results of the tests.

  13. Healy Clean Coal Project: Healy coal firing at TRW Cleveland Test Facility

    SciTech Connect

    Koyama, T.; Petrill, E.; Sheppard, D.

    1991-08-01

    A test burn of two Alaskan coals was conducted at TRW's Cleveland test facility in support of the Healy Clean Coal Project, as part of Clean Coal Technology III Program in which a new power plant will be constructed using a TRW Coal Combustion System. This system features ash slagging technology combined with NO{sub x} and SO{sub x} control. The tests, funded by the Alaska Industrial Development and Export Authority (AIDEA) and TRW, were conducted to verify that the candidate Healy station coals could be successfully fired in the TRW coal combustor, to provide data required for scale-up to the utility project size requirements, and to produce sufficient flash-calcined material (FCM) for spray dryer tests to be conducted by Joy/NIRO. The tests demonstrated that both coals are viable candidates for the project, provided the data required for scale-up, and produced the FCM material. This report describes the modifications to the test facility which were required for the test burn, the tests run, and the results of the tests.

  14. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal, Annual Progress Report, October 1, 2005 through September 30, 2006

    SciTech Connect

    Miller, Bruce G

    2006-09-29

    Since 1998, The Pennsylvania State University has been successfully managing the Consortium for Premium Carbon Products from Coal (CPCPC), which is a vehicle for industry-driven research on the promotion, development, and transfer of innovative technology on premium carbon produces from coal to the U.S. industry. The CPCPC is an initiative being led by Penn State, its co-charter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provides the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity has continued under the present cooperative agreement, No. DE-FC26-03NT41874, which started October 1, 2003. The objective of the second agreement is to continue the successful operation of the CPCPC. The CPCPC has enjoyed tremendous success with its organizational structure, that includes Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC is its industry-led council that selects proposals submitted by CPCPC members to ensure CPCPC target areas have strong industrial support. Base funding for the selected projects is provided by NETL with matching funds from industry. At the annual funding meeting held in October 2003, ten projects were selected for funding. Subcontracts were let from Penn State to the subcontractors on March 1, 2004. Nine of the ten 2004 projects were completed during the previous annual reporting period and their final reports were submitted with the previous annual report (i.e., 10/01/04-09/30/05). The final report for the remaining project, which was submitted during this reporting

  15. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal, Annual Progress Report, October 1, 2004 through September 30, 2005

    SciTech Connect

    Miller, Bruce G

    2006-03-01

    Since 1998, The Pennsylvania State University (PSU) has been successfully operating the Consortium for Premium Carbon Products from Coal (CPCPC), which is a vehicle for industry-driven research on the promotion, development, and transfer of innovative technology on premium carbon produces from coal to the U.S. industry. The CPCPC is an initiative being led by PSU, its co-charter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provides the base funding for the program, with PSU responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity has continued under the present cooperative agreement, No. DE-FC26-03NT41874, which started October 1, 2003. The objective of the second agreement is to continue the successful operation of the CPCPC. The CPCPC has enjoyed tremendous success with its organizational structure, that includes PSU and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC is its industry-led council that selects proposals submitted by CPCPC members to ensure CPCPC target areas have strong industrial support. A second contract was executed with DOE NETL starting in October 2003 to continue the activities of CPCPC. An annual funding meeting was held in October 2003 and the council selected ten projects for funding. Base funding for the projects is provided by NETL with matching funds from industry. Subcontracts were let from Penn State to the subcontractors on March 1, 2004. Nine of the ten projects have been completed and the final reports for these 2004 projects are attached. An annual funding meeting was held in November 2004 and the council selected

  16. POC-scale testing of oil agglomeration techniques and equipment for fine coal processing. Technical report number 2, October 1--December 31, 1995

    SciTech Connect

    1996-07-01

    The objective of this project is to develop and demonstrate a Proof-of-Concept (POC) scale oil agglomeration technology capable of increasing the recovery and improving the quality of fine coal streams. Two distinct agglomeration devices will be tested, namely, a conventional high shear mixer and a tubular (jet) processor. To meet the overall objective an 11 task work plan has been designed. The work will range from batch and continuous bench-scale testing through the design, commissioning and field testing of POC-scale agglomeration equipment. The project includes the following tasks: Project planning and management; host site selection and plan formulation; preliminary engineering and design of POC equipment; coal characterization and laboratory (batch) and bench-scale testing; final engineering and design of POC equipment; proof-of-concept (POC) equipment procurement and fabrication; POC equipment inspection; POC equipment installation, shakedown and operation; process evaluation; dismantling of the system; final report. Accomplishments to date are described on the site selection, a work plan for bench-scale testing, preliminary engineering and design of POC equipment, and coal characterization.

  17. Analysis of the financial impacts to the industrial energy user of using coal or municipal solid waste in a new process-steam-generating plant

    SciTech Connect

    Not Available

    1983-10-01

    An analysis is presented of the financial impacts to the industrial energy user of using either coal or MSW in a new process-steam-generating plant. The results of the analysis indicate that the use of coal or solid waste, rather than oil, in a new energy production plant represents an attractive investment. The financial analysis is based on replacing an existing oil-fired plant with a new plant financed via 100-percent debt. The analysis was structured to cover a range of steam demands, different plant ownership and operating structures, and the tax benefits available to these types of plants. Information is also provided on the types of technologies that would be appropriate given the assumed steam demands. In addition, information is provided on available tax benefits in light of recent tax law changes. Nine options for new coal and MSW plants were analyzed, reflecting a matching of technology and energy output to various process steam demands, as well as different ownership and operating structures.

  18. Probing Rubber Cross-Linking Generation of Industrial Polymer Networks at Nanometer Scale.

    PubMed

    Gabrielle, Brice; Gomez, Emmanuel; Korb, Jean-Pierre

    2016-06-23

    We present improved analyses of rheometric torque measurements as well as (1)H double-quantum (DQ) nuclear magnetic resonance (NMR) buildup data on polymer networks of industrial compounds. This latter DQ NMR analysis allows finding the distribution of an orientation order parameter (Dres) resulting from the noncomplete averaging of proton dipole-dipole couplings within the cross-linked polymer chains. We investigate the influence of the formulation (filler and vulcanization systems) as well as the process (curing temperature) ending to the final polymer network. We show that DQ NMR follows the generation of the polymer network during the vulcanization process from a heterogeneous network to a very homogeneous one. The time variations of microscopic Dres and macroscopic rheometric torques present power-law behaviors above a threshold time scale with characteristic exponents of the percolation theory. We observe also a very good linear correlation between the kinetics of Dres and rheometric data routinely performed in industry. All these observations confirm the description of the polymer network generation as a critical phenomenon. On the basis of all these results, we believe that DQ NMR could become a valuable tool for investigating in situ the cross-linking of industrial polymer networks at the nanometer scale. PMID:27254797

  19. Continuous bench-scale slurry catalyst testing: Direct coal liquefaction of rawhide sub-bituminous coal. Final topical report, June 1994--December 1994

    SciTech Connect

    Coless, L.A.; Poole, M.C.; Wen, M.Y.

    1995-11-21

    Supported catalysts, either in fixed bed or ebullating bed reactors, are subject to deactivation with time, especially if the feed contains deactivating species, such as metals and coke precursors. Dispersed catalyst systems avoid significant catalyst deactivation because there are no catalyst pores to plug, hence no pore mouth plugging, and hopefully, no relevant decline of catalyst surface area or pore volume. The tests carried out in 1994, at the Exxon Research and Development Laboratories (ERDL) for DOE covered a slate of 5 dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal, which is similar to the Black Thunder coal tested earlier at Wilsonville. The catalysts included three iron and two molybdenum types. The Bailey iron oxide and the two molybdenum catalysts have previously been tested in DOE-sponsored research. These known catalysts will be used to help provide a base line and tie-in to previous work. The two new catalysts, Bayferrox PK 5210 and Mach-1`s Nanocat are very finely divided iron oxides. The iron oxide addition rate was varied from 1.0 to 0.25 wt % (dry coal basis) but the molybdenum addition rate remained constant at 100 wppm throughout the experiments. The effect of changing recycle rate, sulfur and iron oxide addition rates, first stage reactor temperature, mass velocity and catalyst type were tested in the 1994 operations of ERDL`s recycle coal liquefaction unit (RCLU). DOE will use these results to update economics and plan future work. The test program will resume in mid 1995, with another 2-3 months of pilot plant testing.

  20. Reuse of pretreated coal gasification condensate in a pilot scale cooling tower

    SciTech Connect

    Johnson, M.D.; Schweitzer, G.W.

    1987-01-01

    The recycle of wastewaters to cooling water systems is practiced in many industrial sectors. The Great Plains Gasification Plant (GPGP) located near Beulah, North Dakota, for example, was designed to reuse treated gas liquor as the primary source of makeup water. In other industrial plants, the concentration of contaminants in the makeup water is very low or the wastewater comprises only a small fraction of the total makeup to the cooling system. The Great Plains system is unique in that the stripped gas liquor (SGL) used as makeup contains relatively high concentrations of dissolved organics, ammonia and acid gases. In addition, the SGL constitutes over 90% of the total makeup to the system. The use of pretreated gas liquor in open, circulating cooling systems is an untried approach to wastewater recycle. The plant not only eliminates a large discharge problem but gains a valuable makeup source for the cooling towers. Because of the large heat duties for the cooling system in these types of plants and their location of regions of water shortages, this approach can be very beneficial. However, there are several environmental and operational concerns that have yet to be resolved. These include atmospheric emissions, fouling of heat transfer surfaces and cooling tower equipment, and excessive corrosion of system components.

  1. Anaerobic sequencing batch reactor in pilot scale for treatment of tofu industry wastewater

    SciTech Connect

    Rahayu, Suparni Setyowati; Purwanto, Budiyono

    2015-12-29

    The small industry of tofu production process releases the waste water without being processed first, and the wastewater is directly discharged into water. In this study, Anaerobic Sequencing Batch Reactor in Pilot Scale for Treatment of Tofu Industry was developed through an anaerobic process to produce biogas as one kind of environmentally friendly renewable energy which can be developed into the countryside. The purpose of this study was to examine the fundamental characteristics of organic matter elimination of industrial wastewater with small tofu effective method and utilize anaerobic active sludge with Anaerobic Sequencing Bath Reactor (ASBR) to get rural biogas as an energy source. The first factor is the amount of the active sludge concentration which functions as the decomposers of organic matter and controlling selectivity allowance to degrade organic matter. The second factor is that HRT is the average period required substrate to react with the bacteria in the Anaerobic Sequencing Bath Reactor (ASBR).The results of processing the waste of tofu production industry using ASBR reactor with active sludge additions as starter generates cumulative volume of 5814.4 mL at HRT 5 days so that in this study it is obtained the conversion 0.16 L of CH{sub 4}/g COD and produce biogas containing of CH{sub 4}: 81.23% and CO{sub 2}: 16.12%. The wastewater treatment of tofu production using ASBR reactor is able to produce renewable energy that has economic value as well as environmentally friendly by nature.

  2. Anaerobic sequencing batch reactor in pilot scale for treatment of tofu industry wastewater

    NASA Astrophysics Data System (ADS)

    Rahayu, Suparni Setyowati; Purwanto, Budiyono

    2015-12-01

    The small industry of tofu production process releases the waste water without being processed first, and the wastewater is directly discharged into water. In this study, Anaerobic Sequencing Batch Reactor in Pilot Scale for Treatment of Tofu Industry was developed through an anaerobic process to produce biogas as one kind of environmentally friendly renewable energy which can be developed into the countryside. The purpose of this study was to examine the fundamental characteristics of organic matter elimination of industrial wastewater with small tofu effective method and utilize anaerobic active sludge with Anaerobic Sequencing Bath Reactor (ASBR) to get rural biogas as an energy source. The first factor is the amount of the active sludge concentration which functions as the decomposers of organic matter and controlling selectivity allowance to degrade organic matter. The second factor is that HRT is the average period required substrate to react with the bacteria in the Anaerobic Sequencing Bath Reactor (ASBR).The results of processing the waste of tofu production industry using ASBR reactor with active sludge additions as starter generates cumulative volume of 5814.4 mL at HRT 5 days so that in this study it is obtained the conversion 0.16 L of CH4/g COD and produce biogas containing of CH4: 81.23% and CO2: 16.12%. The wastewater treatment of tofu production using ASBR reactor is able to produce renewable energy that has economic value as well as environmentally friendly by nature.

  3. Development and testing of a high efficiency advanced coal combustor phase III industrial boiler retrofit. Technical progress report No. 17, 18 and 19, September 30, 1991--December 31, 1996

    SciTech Connect

    Borio, R.W.; Patel, R.L.; Thornock, D.E.

    1996-07-29

    The objective of this project is to retrofit a burner, capable of firing microfine coal, to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the last three quarters [seventeenth (October `95 through December `95), eighteenth (January `96 through March `96), and nineteenth (April `96 through June `96)] of the program.

  4. Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

    SciTech Connect

    Not Available

    1982-01-01

    Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

  5. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semiannual technical progress report, August 15, 1993--February 15, 1994

    SciTech Connect

    Miller, B.G.; Morrison, J.L.; Poe, R.L.; Scaroni, A.W.

    1994-11-30

    The Pennsylvania State University is conducting a coal-water slurry fuel (CWSF) program with the objective of determining the viability of firing CWSF in an industrial boiler designed for heavy fuel oil. The project will also provide information to help in the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) expanded demonstration and evaluation (installing a CWSF preparation circuit, conducting an additional 1,000 hours of testing, and installing an advanced flue gas treatment system). The boiler testing and evaluation will determine if the CWSF combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion tendencies, and fuel transport, storage, and handling characteristics can be accommodated in a boiler system designed to fire heavy fuel oil. In addition, the proof-of-concept demonstration will generate data to determine how the properties of a CWSF and its parent coal affect boiler performance. The economic factors associated with retrofitting boilers will also be evaluated. The first demonstrations been completed and the combustion performance of the burner that was provided with the boiler has been determined to be unacceptable. Consequently, the first demonstration has been concluded at 500 hours. The second demonstration will be conducted after a proven CWSF-designed burner is installed on the boiler. During this reporting period, the construction of the fuel preparation facility that will contain the CWSF circuit (as well as a dry, micronized coal circuit) was completed. Proposals from potential suppliers of the flue gas treatment systems were reviewed by Penn State and DOE.

  6. Ethanol production by Zymomonas mobilis and its application on an industrial scale

    SciTech Connect

    Bringer, S.; Sahm, H.; Swyzen, W.

    1984-01-01

    A continuous culture of Zymomonas mobilis produced 60 g/l ethanol over a test period of 39 days. In the presence of oxygen and at ethanol concentrations exceeding 64 g/l, the substrate conversion was incomplete due to growth inhibition. The Zymomonas fermentation was used for ethanol production from an industrial, enzymatically hydrolyzed wheat starch fraction. Continuous cultures converted this substrate with productivities of up to 4.5 g/l.h at ethanol concentrations of 56-60 g/l. The fermentation of glucose derived from wheat starch has been scaled up to 50 cubic m in an industrial plant. Continuous operation has been possible up to 20 days. Disturbances to the process may be mainly due to the presence of lactic acid bacteria in the substrate feed.

  7. Petroleum and petroleum/coal blends as feedstocks in laboratory-scale and pilot-scale cokers to obtain carbons of potentially high value

    NASA Astrophysics Data System (ADS)

    Escallon, Maria M.

    2008-12-01

    biphenyls. Five-membered ring compounds were not detected in decant oils EI-134 and EI-138. The viscosity of the system has been reported to be crucial for the coke quality, via mesophase growth. This study was performed by using a laboratory-scale coker operated under autogenous pressure and 465°C (LSCclose), which keeps the gases in the reactor so that the viscosity of the system is reduced. The hierarchy in coke quality was found to be completely different to when the LSCopen was used. The coke EI-107, which is derived from the highest polycondensed feedstock, displayed the highest quality. The cokes EI-134, EI-135 and EI-138, which are the cokes derived from the hydrotreated decant oils, displayed the lowest. In summary, there is an optimum viscosity to obtain a high coke quality. When viscosity is too low, mesophase spheres do not coalesce. Last but not least, this work also studied blends of coal and the four selected decant oils as a feedstock to produce coke; the blend was pyrolyzed using the reactors LSCopen, LSCclose and the pilot-scale coker (PSC). Miscibility and chemical interactions (hydrogen transferability) between coal and decant oil were calculated in order to study their influence on the co-coke quality. When the reactors operated under atmospheric and near-atmospheric pressure (LSCopen and PSC), no correlation was found between miscibility or chemical interactions with co-coke quality. However, chemical interaction appears to correlate when LSCclose is used. This is attributed to the higher contact time between coal and decant oil, which occurs at the operational conditions of the reactor LSCclose.

  8. Polycyclic aromatic hydrocarbons (PAHs) in atmospheric PM2.5 and PM10 at a coal-based industrial city: Implication for PAH control at industrial agglomeration regions, China

    NASA Astrophysics Data System (ADS)

    Wu, Di; Wang, Zongshuang; Chen, Jianhua; Kong, Shaofei; Fu, Xiao; Deng, Hongbing; Shao, Guofan; Wu, Gang

    2014-11-01

    Eighteen polycyclic aromatic hydrocarbons (PAHs) in PM2.5 and PM10 are identified and quantified at five sites of E'erduosi in 2005 by GC-MS. Total PAH concentrations in PM2.5 and PM10 are in the ranges of 0.58-145.01 ng m- 3 and 5.80-180.32 ng m- 3 for the five sites, decreasing as coal-chemical base site (ZGE) > heavy industrial site (QPJ) > residential site with heavy traffic (DS) > suburban site surrounded by grassland (HJQ) > background site (QGN) for both PM2.5 and PM10. PAH concentrations in the coal-chemical base site are 250 and 31.1 times of those in the background site. Flu, Pyr, Chr, BbF, BeP, IND and BghiP are abundant for the coal-chemical base site, totally accounting for 75% of the PAH concentrations. 4, 5 and 6 rings PAHs are dominant, accounting for 88.9-94.2% and 90.5-94.1% of PAHs in PM2.5 and PM10, respectively. Combustion-derived PAH concentrations cover 42%-84% and 75%-82% of PAHs in PM2.5 and PM10, indicating large amounts of combustion sources existed for them in E'erduosi. PAH compositions between PM2.5 and PM10 are quite different from each other for sites with few human activities (HJQ and QGN) by coefficient of divergence analysis. Results obtained from principal component analysis and diagnostic ratios indicate that coal combustion, vehicle emission, wood combustion and industrial processes are the main sources for PAHs in E'erduosi. According to BaP equivalent concentration, the potential health risk of PAHs in PM2.5 at the two industrial sites ZGE and QPJ are 537 and 460 times of those for the background site. And they are 4.3 and 3.7 times of those for the residential site. The potential PAH pollution in particles at other industrial agglomeration regions that occurred in China in recent years should be paid attention by the local government.

  9. Development and testing of a high efficiency advanced coal combustor: Phase 3 industrial boiler retrofit. Final report

    SciTech Connect

    Patel, R.L.; Thornock, D.E.; Miller, B.G.; Scaroni, A.W.; McGowan, J.G.

    1998-03-01

    Economics and/or political intervention may one day dictate the conversion from oil or natural gas to coal in boilers that were originally designed to burn oil or gas. In recognition of this future possibility the US Department of Energy, Federal Energy Technical Center (DOE-FETC) supported a program led by ABB Power Plant Laboratories with support from the Energy and Fuels Research Center of Penn State University with the goal of demonstrating the technical and economic feasibility of retrofitting a gas/oil designed boiler to burn micronized coal. In support of the overall goal the following specific objectives were targeted: develop a coal handling/preparation system that can meet the technical and operational requirements for retrofitting microfine coal on a boiler designed for burning oil or natural gas; maintain boiler thermal performance in accordance with specifications when burning oil or natural gas; maintain NOx emissions at or below 0.6 lb NO{sub 2} per million Btu; achieve combustion efficiencies of 98% or higher; and determine economic payback periods as a function of key variables.

  10. FIELD TESTS OF INDUSTRIAL STOKER COAL-FIRED BOILERS FOR EMISSIONS CONTROL AND EFFICIENCY IMPROVEMENT - SITE H

    EPA Science Inventory

    The report gives test results on a coal-fired, overfeed, traveling-grate stoker. The boiler tested is rated at 45,000 lb/hr saturated steam at 140 psig. Measurements include gaseous emissions (O2, CO2, CO, NO, NO2, SO3, and HC), uncontrolled particulate mass loading, particle siz...

  11. FIELD TESTS OF INDUSTRIAL STOKER COAL-FIRED BOILERS FOR EMISSIONS CONTROL AND EFFICIENCY IMPROVEMENT--SITE I

    EPA Science Inventory

    The report gives results of field measurements made on a 70,000 lb steam/hr coal-fired overfeed stoker with traveling grate. The effects of various parameters on boiler emissions and efficiency were studied. Parameters include overfire air, excess oxygen, grate heat release, and ...

  12. FIELD TESTS OF INDUSTRIAL STOKER COAL-FIRED BOILERS FOR EMISSIONS CONTROL AND EFFICIENCY IMPROVEMENT - SITES L1-L7

    EPA Science Inventory

    The report gives results of field measurements to determine particulate emission rate and particle size distribution for seven institutional-type stoker-fired boilers firing bituminous coals. Operational data were recorded during the tests to provide information for evaluating bo...

  13. FIELD TESTS OF INDUSTRIAL STOKER COAL-FIRED BOILERS FOR EMISSIONS CONTROL AND EFFICIENCY IMPROVEMENT - SITE K

    EPA Science Inventory

    The report gives results of field measurements made on a 50,000 lb stream/hr coal-fired overfeed stoker with traveling grate. The effects of various parameters on boiler emissions and efficiency were studied. Parameters include overfire air, excess oxygen, grate heat release, and...

  14. Premium carbon products from coal

    SciTech Connect

    Rusinko, F. Jr.; Morrison, J.L.

    2000-07-01

    The face of the US coal industry and its markets are changing. Environmental concerns over global warming and plant emissions are two factors that will continue to gain national attention and consequently will challenge the use of coal in the US within its traditional markets. The decline of coke production in the US has lead to high quality metallurgical-grade coal being used to generate electricity. One could argue this is a waste of a limited valuable resource. The debate over global warming and the generation of greenhouse gases, particularly CO{sub 2}, will undoubtedly negatively impact the use of coal in newly constructed power plants. What is the future of the US coal industry and the industries that benefit from coal? This paper will review the use of coal and coal-derived materials in new, non-fuel markets. It will review a new industrial consortium that has recently been formed to stimulate the use of coal in value-added carbon markets. One of the questions the reader should ask when reading this paper is: Is coal more valuable for its carbon content or its BTU content? Carbon materials such as carbon fibers, carbon-carbon composites, specialty and mechanical graphite, activated carbon, carbon black, and carbon foams may provide new markets for the coal industry. These markets are expanding and some of these markets are in their infancy. These new material applications offer an exciting, but little recognized, opportunity for the expanded use of coal.

  15. State coal profiles, January 1994

    SciTech Connect

    Not Available

    1994-02-02

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  16. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semiannual technical progress report, February 15, 1993--August 15, 1993

    SciTech Connect

    Miller, B.G.; Morrison, J.L.; Poe, R.L.; Scaroni, A.W.

    1993-09-24

    The Pennsylvania State University is conducting a coal-water slurry fuel (CWSF) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the viability of firing CWSF in an industrial boiler designed for heavy fuel oil. Penn State and DOE have entered into a cooperative agreement with the purpose of determining if CWSF prepared from a cleaned coal (containing approximately 3.5 wt % ash and 0.9 wt % sulfur) can be effectively burned in a heavy fuel oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will also generate information to help in the design of new systems specifically configured to fire these clean coal-based fuels. The approach being used in the program is as follows: 1. Install a natural gas/fuel oil-designed package boiler and generate baseline data firing natural gas; 2. Shake down the system with CWSF and begin the first 1,000 hours of testing using the burner/atomizer system provided with the boiler. The first 1,000-hour demonstration was to consist of boiler operation testing and combustion performance evaluation using CWSF preheat, a range of atomizing air pressures (up to 200 psig as compared to the 100 psig boiler manufacturer design pressure), and steam as the atomizing medium; 3. If the combustion performance was not acceptable based on the combustion efficiency obtained and the level of gas support necessary to maintain flame stabilization, then low-cost modifications were to be implemented, such as installing a quarl and testing alternative atomizers; 4. If acceptable combustion performance was not obtained with the low-cost modifications, then the first demonstration was to be terminated and the burner system replaced with one of proven CWSF design.

  17. Treatment of aqueous streams containing strong oxidants using bituminous coal

    SciTech Connect

    Doyle, F.M.; Bodine, D.L.

    1995-12-31

    Certain oxidizing contaminants, notably Cr(VI) and Mn(VII), are attenuated by reduction and sorption on organic matter in soils. Coals have some chemical similarity with this organic matter, and might be used on an industrial scale to treat effluents. We have studied the ability of acidic KMnO{sub 4} to oxidize Upper Freeport, bituminous coal with concurrent sorption of the resulting Mn(IV) and Mn(II). The oxidizing ability of Cr(VI) was briefly investigated. The ability of the oxidized coal to sorb Cu{sup 2+} and Cd{sup 2+} was then studied, and compared with coal oxidized by hydrogen peroxide. The effect of oxidation treatment, metal ion concentration, and solution pH on metal uptake kinetics and coal loading was investigated. Potential applications for treating effluents containing oxidizing ions are discussed.

  18. Applications for silica-based aerogel products on an industrial scale

    SciTech Connect

    Schmidt, M.; Schwertfeger, F.

    1998-12-31

    Aerogels, nanoporous lightweight materials, were discovered more than 60 years ago. The supercritical manufacturing process and expensive raw materials typically used to produce aerogels prohibited commercialization on an industrial scale. Recently a commercially attractive ambient pressure production process was developed which will allow broader commercialization of silica-aerogel products. Some aerogel products for insulation applications and their preparation are described. Sound insulation properties including a remarkable absorption in the difficult low frequency range was found. In the case of insulation plates performance depends on binder and can be positively influenced by choosing the right binding material.

  19. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    SciTech Connect

    R.-H. Yoon; G.H. Luttrell; A.D. Walters

    1999-10-01

    During the past quarter, the installation, testing and shakedown phases of commissioning the TES unit were completed (Tasks 4, 5.1 and 5.2). A representative from Carpco Inc. was on site to provide training in the operation of the test unit and assist with the initial test runs. Problems have been encountered with the recycle conveyor generating dust that neutralizes the particle charge. Testing has continued by batch feeding the unit while the recycle conveying problem is being solved. Good separations have been achieved while operating in this mode. Comparison tests have also been carried out using a bench-scale triboelectrostatic separator in parallel with the POC Carpco unit.

  20. Coal Cleaning by Gas Agglomeration

    SciTech Connect

    Meiyu Shen; Royce Abbott; T. D. Wheelock

    1998-03-01

    The gas agglomeration method of coal cleaning was demonstrated with laboratory scale mixing equipment which made it possible to generate microscopic gas bubbles in aqueous suspensions of coal particles. A small amount of i-octane was introduced to enhance the hydrophobicity of the coal. Between 1.0 and 2.5 v/w% i-octane was sufficient based on coal weight. Coal agglomerates or aggregates were produced which were bound together by small gas bubbles.

  1. Experimental investigation of mobile small-scale liquefier for 10000 NM3/D of coal bed methane gas

    NASA Astrophysics Data System (ADS)

    Sun, Zhaohu; Wu, J. F.; Gong, Maoqiong; Guo, Ping

    2012-06-01

    There is a growing recognition that unconventional sources of gas, such as shale gas, coal bed methane (CBM) and deep tight gas will contribute a significant component of future gas supplies as technologies evolve. In recent years, the interest in such source of gas utilization technologies based on small-scale LNG production has been rising steeply. In this paper, a mobile liquefier prototype for 10000 Nm3/d of CBM has been designed, constructed and tested. It has two cascade refrigeration systems. The high-temperature refrigeration system will pre-cool the resource gas to 5oC, and the low-temperature refrigeration system will continue to cool the resource gas to the liquefied point with a Mixed Refrigerant Cycle (MRC). The kernel compressor is a conventional oil-lubricated air-conditioning compressor with the discharge pressure of 2.0 MPa. The main heat exchanger is plate-fin heat exchanger with four passages. A series of experiments have been done on the prototype liquefier at different resource gas pressures and environmental temperatures. It is less than one hour from the start of the equipment to the existence of LNG. The maximum production of LNG is about 20 m3/d when a stream of about 12500 Nm3/d of pure CBM at a process pressure of 1.3 MPa is liquefied. The energy consumption of liquefying 1 Nm3 methane is 0.612 kWh.

  2. An analysis of markets for small-scale, advanced coal-combustion technology in Spain, Italy, and Turkey

    SciTech Connect

    Placet, M.; Gerry, P.A.; Kenski, D.M.; Kern, D.M.; Nehring, J.L.; Szpunar, C.B.

    1989-09-01

    This report discusses the examination of potential overseas markets for using small-scale, US-developed, advanced coal-combustion technologies (ACTs). In previous work, member countries of the Organization for Economic Cooperation and Development (OECD) were rated on their potential for using ACTs through a comprehensive screening methodology. The three most promising OECD markets were found to be Spain, Italy, and Turkey. This report provides in-depth analyses of these three selected countries. First, it addresses changes in the European Community with particular reference to the 1992 restructuring and its potential effect on the energy situation in Europe, specifically in the three subject countries. It presents individual country studies that examine demographics, economics, building infrastructures, and energy-related factors. Potential niches for ACTs are explored for each country through regional analyses. Marketing channels, strategies, and the trading environments in each country are also discussed. The information gathered indicates that Turkey is a most promising market, Spain is a fairly promising market, and Italy appears to be a somewhat limited market for US ACTs. 76 refs., 16 figs., 14 tabs.

  3. Bench-scale demonstration of biological production of ethanol from coal synthesis gas. Topical report 5, Process analysis

    SciTech Connect

    1995-11-01

    The economics of converting coal to ethanol by a biological process is quite attractive. When processing 1500 tons of coal per day, the plant generates 85 million gallons of ethanol per year. The return on investment for the process is 110 percent and the payout is 0.9 years.

  4. Industrial scale microwave processing of tomato juice using a novel continuous microwave system.

    PubMed

    Stratakos, Alexandros Ch; Delgado-Pando, Gonzalo; Linton, Mark; Patterson, Margaret F; Koidis, Anastasios

    2016-01-01

    This study evaluated the effect of an industrial scale continuous flow microwave volumetric heating system in comparison to conventional commercial scale pasteurisation for the processing of tomato juice in terms of physicochemical properties, microbial characteristics and antioxidant capacity. The effect against oxidative stress in Caco-2 cells, after in vitro digestion was also investigated. Physicochemical and colour characteristics of juices were very similar between technologies and during storage. Both conventional and microwave pasteurisation inactivated microorganisms and kept them in low levels throughout storage. ABTS[Symbol: see text](+) values, but not ORAC, were higher for the microwave pasteurised juice at day 0 however no significant differences between juices were observed during storage. Juice processed with the microwave system showed an increased cytoprotective effect against H2O2 induced oxidation in Caco-2 cells. Organoleptic analysis revealed that the two tomato juices were very similar. The continuous microwave volumetric heating system appears to be a viable alternative to conventional pasteurisation. PMID:26213019

  5. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    SciTech Connect

    Joseph Rabovitser

    2009-06-30

    , pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  6. Scaling characteristics of the aerodynamics and low-NOx properties of industrial natural gas burners: The scaling 400 study. Part 3. The 30kw test results

    SciTech Connect

    Driscoll, J.F.; Dahm, W.J.A.; Wu, M.S.

    1993-08-15

    The objective of the SCALING 400 study is to assist in the development of new ultra-low NOx natural gas burners for industrial and utility operations so as to maintain and expand future demand for natural gas as the fuel of choice for clean combustion applications. The study is determining the scaling characteristics of near-burner aerodynamics and low-NOx properties of industrial natural gas burners, thereby yielding valuable new engineering information on the scaling of natural gas burners to contribute to the development of new low-NOx designs.

  7. Tri-State Synfuels Project Commercial Scale Coal Test: Volume 2C. Collection and shipment photographic review. [Bulk coal sample; Kentucky, USA to Sasolburg, SA

    SciTech Connect

    Not Available

    1982-06-01

    This report is a photographic review of the collection and shipment phase of the project during February through April 1981. It covers the locations at Morganfield and Uniontown, Kentucky; Darrow, Louisiana; and Port Elizabeth and Sasolburg, Republic of South Africa. The final detailed program planning and tour of the mine, belt and barge loading facilities occurred on February 11 and 12 (Section 2.0). The coal was ampled and selected from the Camp 1 mine at Morganfield (Section 3.0) and transported on the nine-mile conveyor belt to Uniontown, February 23-25 (Section 4.0). The coal was inspected and loaded at Uniontown on a 15-barge tow, February 23-25, for the 900-mile trip on the Ohio and Mississippi River systems to Darrow (Section 5.0). The barges were inspected and top sampled prior to transloading the bulk carrier M.S. Bonita at Darrow during March 17-20 for shipment to Port Elizabeth (Section 6.0). The ship was offloaded and rail cars sampled April 15-24 at Port Elizabeth before leaving for Sasolburg (Section 7.0). The rail cars were offloaded and partially sampled and trucked to Sasolburg in late April and stockpiled until the gasification test program started in July. After the July and September phases of the coal test, the remaining stockpile was relocated and compacted prior to the November tests to prevent spontaneous ignition.

  8. Size distribution of rare earth elements in coal ash

    USGS Publications Warehouse

    Scott, Clinton T.; Deonarine, Amrika; Kolker, Allan; Adams, Monique; Holland, James F.

    2015-01-01

    Rare earth elements (REEs) are utilized in various applications that are vital to the automotive, petrochemical, medical, and information technology industries. As world demand for REEs increases, critical shortages are expected. Due to the retention of REEs during coal combustion, coal fly ash is increasingly considered a potential resource. Previous studies have demonstrated that coal fly ash is variably enriched in REEs relative to feed coal (e.g, Seredin and Dai, 2012) and that enrichment increases with decreasing size fractions (Blissett et al., 2014). In order to further explore the REE resource potential of coal ash, and determine the partitioning behavior of REE as a function of grain size, we studied whole coal and fly ash size-fractions collected from three U.S commercial-scale coal-fired generating stations burning Appalachian or Powder River Basin coal. Whole fly ash was separated into , 5 um, to 5 to 10 um and 10 to 100 um particle size fractions by mechanical shaking using trace-metal clean procedures. In these samples REE enrichments in whole fly ash ranges 5.6 to 18.5 times that of feedcoals. Partitioning results for size separates relative to whole coal and whole fly ash will also be reported. 

  9. Full scale measurements to validate mathematical models and to monitor the combustion behavior of bituminous and brown coal-fired boilers

    SciTech Connect

    Maier, J.; Kluger, F.; Heinzel, T.; Spliethoff, H.; Hein, K.R.G.

    1999-07-01

    In recent years, the Institute for Process Engineering and Power Plant Technology (IVD) carried out measurement campaigns on three full-scale-bituminous- and brown-coal-fired boilers between 80 and 500 MW{sub el}. One boiler was designed as a boxer firing system, configured with swirl burner, and the other two were tangentially fired with jet burner. Aim of the measurement campaigns was to evaluate the suitability of bituminous- and brown-coal-fired boilers (500 and 320 MW {sub el}) for alternative coals and their blends. To monitor changes in the combustion and emission behavior, suction probes to measure flue gas concentrations and temperatures along the furnace were inserted. Shifts in heat transfer between the radiative and convective part of the boiler were correlated with the kind of coal, the injected water mass flow in the superheater steam and the flue gas temperature. Also changes with the unburned carbon and of the NO{sub x}, SO{sub 2} and CO emission behavior were measured and correlated with coal types and their variable share. The second objective of the measurement campaigns in the bituminous-coal-fired boilers (500 MW{sub el} and 80 MW{sub el}) was the acquisition of combustion data to validate the mathematical combustion model AIOLOS, which has been successfully developed by the IVD during the last ten years. For this purpose flue-gas-concentration and temperature measurements have been carried out at IVD in the near burner zone and in front of the superheaters. Furthermore, the suitability of 3-color pyrometry, thermocouples and acoustic temperature measurement systems will be compared and discussed in this paper.

  10. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    SciTech Connect

    R.-H. Yoon; G.H. Luttrell; G.T. Adel; A.D. Walters

    1999-07-01

    The Proof-of-Concept (POC) triboelectrostatic separator (TES) has now been successfully installed at the Virginia Tech pilot-plant. As a result, most of the personnel assigned to this project during the past quarter have been performing work elements associated with the installation and shakedown testing of the electrostatic separator, tribocharger system, product conveying systems and nitrogen purge system (Tasks 4, 5.1 and 5.2). A representative from Carpco also carried out training in the operating features of the unit during the past month. Most of the shakedown test work has now been successfully completed. However, several minor operational problems associated with the pilot-scale equipment are currently in the process of being resolved.

  11. DEMONSTRATION OF THE USE OF CHARGED FOG IN CONTROLLING FUGITIVE DUST FROM LARGE-SCALE INDUSTRIAL SOURCES

    EPA Science Inventory

    The report gives results of a full-scale demonstration of a charged fogger (Ritten Corporation's Fogger IV) on several industrial fugitive emission sources. (Although charged foggers have been widely applied to industrial sources of fugitive dust, little data are available on fog...

  12. Education, Training and Employment in Small-Scale Enterprises: Three Industries in Sao Paulo, Brazil. IIEP Research Report No. 63.

    ERIC Educational Resources Information Center

    Leite, Elenice M.; Caillods, Francoise

    Despite the prophecies forecasting their probable disappearance or annihilation, small-scale enterprises have persisted in the Brazilian industrial structure since 1950. To account for the survival of small firms in Brazil, specifically in the state of Sao Paulo, a study examined 100 small firms in three industrial sectors: clothing, mechanical…

  13. Coal Gasification (chapter only)

    SciTech Connect

    Shadle, L.J.; Berry, D.A.; Syamlal, Madhava

    2002-11-15

    Coal gasification is presented in terms of the chemistry of coal conversion and the product gas characteristics, the historical development of coal gasifiers, variations in the types and performance of coal gasifiers, the configuration of gasification systems, and the status and economics of coal gasification. In many ways, coal gasification processes have been tailored to adapt to the different types of coal feedstocks available. Gasification technology is presented from a historical perspective considering early uses of coal, the first practical demonstration and utilization of coal gasification, and the evolution of the various processes used for coal gasification. The development of the gasification industry is traced from its inception to its current status in the world economy. Each type of gasifier is considered focusing on the process innovations required to meet the changing market needs. Complete gasification systems are described including typical system configurations, required system attributes, and aspects of the industry's environmental and performance demands. The current status, economics of gasification technology, and future of gasification are also discussed.

  14. Exergy analysis of an industrial-scale ultrafiltrated (UF) cheese production plant: a detailed survey

    NASA Astrophysics Data System (ADS)

    Nasiri, Farshid; Aghbashlo, Mortaza; Rafiee, Shahin

    2016-05-01

    In this study, a detailed exergy analysis of an industrial-scale ultrafiltrated (UF) cheese production plant was conducted based on actual operational data in order to provide more comprehensive insights into the performance of the whole plant and its main subcomponents. The plant included four main subsystems, i.e., steam generator (I), above-zero refrigeration system (II), Bactocatch-assisted pasteurization line (III), and UF cheese production line (IV). In addition, this analysis was aimed at quantifying the exergy destroyed in processing a known quantity of the UF cheese using the mass allocation method. The specific exergy destruction of the UF cheese production was determined at 2330.42 kJ/kg. The contributions of the subsystems I, II, III, and IV to the specific exergy destruction of the UF cheese production were computed as 1337.67, 386.18, 283.05, and 323.51 kJ/kg, respectively. Additionally, it was observed through the analysis that the steam generation system had the largest contribution to the thermodynamic inefficiency of the UF cheese production, accounting for 57.40 % of the specific exergy destruction. Generally, the outcomes of this survey further manifested the benefits of applying exergy analysis for design, analysis, and optimization of industrial-scale dairy processing plants to achieve the most cost-effective and environmentally-benign production strategies.

  15. Coal char fragmentation during pulverized coal combustion

    SciTech Connect

    Baxter, L.L.

    1995-07-01

    A series of investigations of coal and char fragmentation during pulverized coal combustion is reported for a suite of coals ranging in rank from lignite to low-volatile (lv) bituminous coal under combustion conditions similar to those found in commercial-scale boilers. Experimental measurements are described that utilize identical particle sizing characteristics to determine initial and final size distributions. Mechanistic interpretation of the data suggest that coal fragmentation is an insignificant event and that char fragmentation is controlled by char structure. Chars forming cenospheres fragment more extensively than solid chars. Among the chars that fragment, large particles produce more fine material than small particles. In all cases, coal and char fragmentation are seen to be sufficiently minor as to be relatively insignificant factors influencing fly ash size distribution, particle loading, and char burnout.

  16. Dielectric elastomer based active layer for macro-scaled industrial application in roto-flexographic printing

    NASA Astrophysics Data System (ADS)

    Pinto, F.; D'Oriano, G.; Meo, M.

    2014-03-01

    The use of dielectric elastomer (DE) for the realisation of new generation actuators has attracted the interest of many researchers in the last ten years due to their high efficiency, a very good electromechanical coupling and large achievable strains [1-3]. Although these properties constitute a very important advantage, the industrial exploitation of such systems is hindered by the high voltages required for the actuation [4] that could potentially constitute also a risk for the operators. In this work we present a DE based active layer that can be used in different macro-scaled parts of industrial equipment for roto-flexographic printing substituting traditional mechanical devices, reducing manufacturing costs and enhancing its reliability. Moreover, the specific configuration of the system requires the driving voltage to be applied only in the mounting/dismounting step thus lowering further the operative costs without posing any threat for the workers. Starting from the industrial requirements, a complete thermo-mechanical characterisation using DSC and DMA was undertaken on acrylic elastomer films in order to investigate their behaviour under the operative frequencies and solicitations. Validation of the active layer was experimentally evaluated by manufacturing a DE actuator controlling both prestrain and nature of the complaint electrodes, and measuring the electrically induced Maxwell's strain using a laser vibrometer to evaluate the relative displacement along the z-axis.

  17. Do we have to consider temperature-dependent material properties in large-scale environmental impact assessments of underground coal gasification?

    NASA Astrophysics Data System (ADS)

    Otto, Christopher; Kempka, Thomas

    2015-04-01

    Underground coal gasification (UCG) can increase the world-wide coal reserves by utilization of coal deposits not mineable by conventional methods. The UCG process involves combusting coal in situ to produce a high-calorific synthesis gas which can be applied for electricity generation or chemical feedstock production. Apart from its high economic potentials, UCG may induce environmental impacts such as ground subsidence associated with groundwater pollution due to generation of hydraulic connectivities between the UCG reactor and adjacent aquifers. These changes overburden conductivity may introduce potential migration pathways for UCG contaminants such as organic (phenols, benzene, PAHs and heterocyclics) and inorganic (ammonia, sulphates, cyanides, and heavy metals) pollutants. Mitigation of potential environmental UCG impacts can be achieved by improving the understanding of coupled thermo-hydro-mechanical processes in the rocks surrounding the UCG reactor. In the present study, a coupled thermo-mechanical model has been developed to carry out a parameter sensitivity analysis and assess permeability changes derived from volumetric strain increments in the UCG reactor overburden. Our simulation results demonstrate that thermo-mechanical rock behavior is mainly influenced by the thermal expansion coefficient, tensile strength and elastic modulus of the surrounding rock. A comparison of temperature-dependent and temperature-independent simulation results indicates high variations in the distribution of total displacements in the UCG reactor vicinity related to thermal stress, but only negligible differences in permeability changes. Hence, temperature-dependent thermo-mechanical parameters have to be considered in the assessment of near-field UCG impacts, while far-field models can achieve a higher computational efficiency by using temperature-independent thermo-mechanical parameters. Considering the findings of the present study in the large-scale assessment of

  18. Clean coal reference plants: Pulverized coal boiler with flue gas desulfurization. Topical report

    SciTech Connect

    1995-09-01

    The Clean Coal Technology Demonstration Program (CCT) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the U.S. energy marketplace with a number of advanced, more efficient, and environmentally responsive coal-using technologies. To achieve this goal, a multiphased effort consisting of five separate solicitations has been completed. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which, in general, correspond to the center`s areas of technology development. Primarily the categories of METC CCT projects are: atmospheric fluid bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications.

  19. Status of health and environmental research relative to coal gasification 1976 to the present

    SciTech Connect

    Wilzbach, K.E.; Reilly, C.A. Jr.

    1982-10-01

    Health and environmental research relative to coal gasification conducted by Argonne National Laboratory, the Inhalation Toxicology Research Institute, and Oak Ridge National Laboratory under DOE sponsorship is summarized. The studies have focused on the chemical and toxicological characterization of materials from a range of process streams in five bench-scale, pilot-plant and industrial gasifiers. They also address ecological effects, industrial hygiene, environmental control technology performance, and risk assessment. Following an overview of coal gasification technology and related environmental concerns, integrated summaries of the studies and results in each area are presented and conclusions are drawn. Needed health and environmental research relative to coal gasification is identified.

  20. Quantitative relations between exposure to respirable coalmine dust and coalworkers' simple pneumoconiosis in men who have worked as miners but have left the coal industry.

    PubMed Central

    Soutar, C A; Maclaren, W M; Annis, R; Melville, A W

    1986-01-01

    Present estimates of the quantitative relations between exposure to mixed respirable coalmine dust and risk of developing coalworkes' simple pneumoconiosis are based on studies of working miners. These studies did not include men who had been miners but had left the coal industry, and it was not known whether the estimates of risk were also appropriate for these men. The results are reported of a study in which the dust/disease relations in men who have been miners but have left the industry have been compared with those in men who have remained in it. A sample of 17738 men who were first examined when working in 24 British collieries in the 1950s has been followed up about 22 years later. It was possible to examine 61% of the survivors, 44% of the original sample. Simple pneumoconiosis was more frequent among men (particularly older men) who had left the industry than among those who had stayed in it. A detailed analysis did not show any systematic or statistically significant difference between men who stayed and men who left in the quantitative relations between dust exposure and simple pneumoconiosis. Present estimates of risk of simple pneumoconiosis in relation to exposure to mixed respirable dust in working miners adequately describe the relation found in men who have been miners but have left the industry. PMID:3947559

  1. Application of ERTS-1 imagery to fracture related mine safety hazards in the coal mining industry. [Indiana

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.; Leshendok, T. V.

    1974-01-01

    The author has identified the following significant results. New fracture detail of Indiana has been observed and mapped from ERTS-1 imagery. Studies so far indicate a close relationship between the directions of fracture traces mapped from the imagery, fractures measured on bedrock outcrops, and fractures measured in the underground mines. First hand observations and discussions with underground mine operators indicate good correlation of mine hazard maps prepared from ERTS-1/aircraft imagery and actual roof falls. The inventory of refuse piles/slurry ponds of the coal field of Indiana has identified over 225 such sites from past mining operations. These data will serve the State Legislature in making tax decisions on coal mining which take on increased importance because of the energy crisis.

  2. Fluidized bed coal desulfurization

    NASA Technical Reports Server (NTRS)

    Ravindram, M.

    1983-01-01

    Laboratory scale experiments were conducted on two high volatile bituminous coals in a bench scale batch fluidized bed reactor. Chemical pretreatment and posttreatment of coals were tried as a means of enhancing desulfurization. Sequential chlorination and dechlorination cum hydrodesulfurization under modest conditions relative to the water slurry process were found to result in substantial sulfur reductions of about 80%. Sulfur forms as well as proximate and ultimate analyses of the processed coals are included. These studies indicate that a fluidized bed reactor process has considerable potential for being developed into a simple and economic process for coal desulfurization.

  3. Safety analysis of the CSTR-1 bench-scale coal liquefaction unit

    SciTech Connect

    Hulburt, D.A.

    1981-05-01

    The objective of the program reported herein was to provide a Safety Analysis of the CSTR-1 bench scale unit located in Building 167 at the Pittsburgh Energy Technology Center. It was apparent that considerable effort was expended in the design and construction of the unit, and in the development of operating procedures, with regard to safety. Exhaust ventilation, H/sub 2/ and H/sub 2/S monitoring, overpressure protection, overtemperature protection, and interlock systems have been provided. Present settings on the pressure and temperature safety systems are too high, however, to insure prevention of vessel deformation or damage in all cases. While the occurrence of catastrophic rupture of a system pressure vessel (e.g., reactor, high pressure separators) is unlikely, the potential consequences to personnel are severe. Feasibility of providing shielding for these components should be considered. A more probable mode of vessel failure in the event of overpressure or overtemperature and failure of the safety system is yielding of the closure bolts followed by high pressure flow across the mating surfaces. As a minimum, shielding should be designed to restrict travel of resultant spray. The requirements for personal protective equipment are presently stated in rather broad and general terms in the operating procedures. Safe practices and procedures would be more assured if specific requirements were stated and included for each operational step. Recommendations were developed for all hazards triggered by the guidelines.

  4. Hydrometallurgical recovery of germanium from coal gasification fly ash: pilot plant scale evaluation

    SciTech Connect

    Arroyo, F.; Fernandez-Pereira, C.; Olivares, J.; Coca, P.

    2009-04-15

    In this article, a hydrometallurgical method for the selective recovery of germanium from fly ash (FA) has been tested at pilot plant scale. The pilot plant flowsheet comprised a first stage of water leaching of FA, and a subsequent selective recovery of the germanium from the leachate by solvent extraction method. The solvent extraction method was based on Ge complexation with catechol in an aqueous solution followed by the extraction of the Ge-catechol complex (Ge(C{sub 6}H{sub 4}O{sub 2}){sub 3}{sup 2-}) with an extracting organic reagent (trioctylamine) diluted in an organic solvent (kerosene), followed by the subsequent stripping of the organic extract. The process has been tested on a FA generated in an integrated gasification with combined cycle (IGCC) process. The paper describes the designed 5 kg/h pilot plant and the tests performed on it. Under the operational conditions tested, approximately 50% of germanium could be recovered from FA after a water extraction at room temperature. Regarding the solvent extraction method, the best operational conditions for obtaining a concentrated germanium-bearing solution practically free of impurities were as follows: extraction time equal to 20 min; aqueous phase/organic phase volumetric ratio equal to 5; stripping with 1 M NaOH, stripping time equal to 30 min, and stripping phase/organic phase volumetric ratio equal to 5. 95% of germanium were recovered from water leachates using those conditions.

  5. THE DEVELOPMENT OF COAL-BASED TECHNOLOGIES FOR DEPARTMENT OF DEFENSE FACILITIES

    SciTech Connect

    Bruce G. Miller; Sharon Falcone Miller; Sarma V. Pisupati; Chunshan Song; Ronald S. Wasco; Ronald T. Wincek; Xiaochun Xu; Alan W. Scaroni; Richard Hogg; Subhash Chander; M. Thaddeus Ityokumbul; Mark S. Klima; Peter T. Luckie; Adam Rose; Richard L. Gordon; Jeffrey Lazo; A. Michael Schaal

    2004-01-30

    The third phase of a three-phase project investigating the development of coal-based technologies for US Department of Defense (DOD) facilities was completed. The objectives of the project were to: decrease DOD's dependence on foreign oil and increase its use of coal; promote public and private sector deployment of technologies for utilizing coal-based fuels in oil-designed combustion equipment; and provide a continuing environment for research and development of coal-based fuel technologies for small-scale applications at a time when market conditions in the US are not favorable for the introduction of coal-fired equipment in the commercial and industrial capacity ranges. The Phase III activities were focused on evaluating deeply-cleaned coals as fuels for industrial boilers and investigating emissions control strategies for providing ultra-low emissions when firing coal-based fuels. This was addressed by performing coal beneficiation and preparation studies, and bench- to demonstration-scale emissions reduction studies. In addition, economic studies were conducted focused on determining cost and market penetration, selection of incentives, and regional economic impacts of coal-based technologies.

  6. Development and testing of commercial-scale, coal-fired combustion systems: Phase 3. Technical progress report, January 1992--March 1992

    SciTech Connect

    Not Available

    1992-08-01

    The US Department of Energy`s Pittsburgh Energy Technology Center (PETC) is actively pursuing the development and testing of coal-fired combustion systems for residential, commercial, and industrial market sectors. In response, MTCI initiated the development of a new combustor technology based on the principle of pulse combustion under the sponsorship of PETC (Contract No. AC22-83PC60419). The initial pulse combustor development program was conducted in three phases (MTCI, Development of a Pulsed Coal Combustor Fired with CWM, Phase III Final Report, DOE Contract No. AC22-83PC60419, November 1986). Phase I included a review of the prior art in the area of pulse combustion and the development of pulse combustor design concepts. It led to the conclusion that pulse combustors offer technical and base-of-operation advantages over conventional burners and also indicated favorable economics for replacement of oil- and gas-fired equipment.

  7. Coal science for the clean use of coal

    SciTech Connect

    Harrison, J.S.

    1994-12-31

    Coal will need to be retained as a major source of energy in the next century. It will need to be used more effectively and more cleanly. In order to achieve this, it is necessary to introduce new technology supported by a local community of science and technology. Only in this way can the full benefits of international advances in coal utilization be fully achieved. It is important that full advantage be taken of the advances that have been achieved in laboratory techniques and in the better understanding of fundamental coal science. This paper reviews available technologies in power generation, industrial process heat, coal combustion, coal gasification, and coal analytical procedures.

  8. Rheology of coal-water slurries prepared by the HP roll mill grinding of coal

    SciTech Connect

    Fuerstenau, D.W.

    1992-12-01

    The objective of the research is the development of improved technology for the preparation of coal-water slurries, which have potential for replacing fuel oil in direct combustion. The fine grinding of coal is a crucial step in the manufacture of coal-water slurries. In this context, currently available grinding mills exhibit poor energy efficiency for size reduction and non-optimum packing characteristics of the ground coal. The first increases the cost of manufacture of coal-water slurries and the second adversely affects their rheological properties. The newly invented choke-fed, high-pressure roll mill is up to 50% more energy efficient and, moreover, there are reasons to believe that it produces a size distribution of ground particles which is closer to the dense packing composition. The high-pressure roll mill (which is perhaps the only really significant innovation in industrial comminution in this century) has lower capital cost, occupies less floor space, shows negligible wear rate, accepts feed with a wide range of moisture contents and, of particular importance, it can be scaled up to grind hundreds of tons of solids per hour. The high-pressure roll mill provides a unique opportunity to develop an improved technology for preparing coal-water slurries. Our research group in the University of California at Berkeley not only has a fully instrumented, laboratory-scale, choke-fed. high-pressure roll mill (the only one of its kind in the United States) but also fully instrumented laboratory ball mills for comparative fine coal preparation purposes. In this research program, our plans are to systematically investigate comminution energy consumption, deagglomeration procedures, and the stability and rheology of coal-water slurry fuel prepared with high-pressure roll mill, and to compare the results with slurry prepared with ball-milled coal.

  9. Evaluation of an enhanced gravity-based fine-coal circuit for high-sulfur coal

    SciTech Connect

    Mohanty, M.K.; Samal, A.R.; Palit, A.

    2008-02-15

    One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m{sup 2}, an enhanced gravity separator having a bowl diameter of 250 mm and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The 'linear screen + enhanced gravity separator + screen-bowl circuit' provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61 %, respectively.

  10. Coal: the new black

    SciTech Connect

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  11. Bench-Scale and Pilot-Scale Treatment Technologies for the Removal of Total Dissolved Solids from Coal Mine Water: A Review

    EPA Science Inventory

    Coal mine water (CMW) is typically treated to remove suspended solids, acidity, and soluble metals, but high concentrations of total dissolved solids (TDS) have been reported to impact the environment at several CMW discharge points. Consequently, various states have establishe...

  12. Industrial-scale demonstration of a new sorbent reactivation technology for fluidized bed combustors.

    PubMed

    Anthony, Edward J; McCleave, Robert; Gandolfi, Eduardo; Wang, Jinsheng

    2003-10-01

    To minimize the disposal of highly reactive spent sorbent from a fluidized bed combustor, a new method for reactivation has been developed. The method consists of grinding the spent ash in a rotary mill, hydrating the ash with an excess of water, and mixing the wet ground ash with dry solids to absorb the excess water. The mixing process eliminates the formation of a concrete-like product that normally results as wet fluidized bed combustor ash ages. Pilot-scale combustion trials proved to be successful, and the process was scaled up using a 35MWt utility boiler at Purdue University. The test lasted for 3 days and resulted in net reduction of limestone sorbent use of 18%. The results generated in this work have been used to develop an economic evaluation for a 165MWe circulating fluidized bed (CFB) boiler, which projects significant savings due to reduction of limestone supply and ash disposal costs. The evaluation also suggests that the process is cost competitive with other processes, albeit that those processes have not been demonstrated at industrial scale. Furthermore, it also has the potential to make a small net reduction in CO(2) emissions, due to reduced limestone usage. PMID:14550660

  13. Comparison of lab, pilot, and industrial scale low consistency mechanical refining for improvements in enzymatic digestibility of pretreated hardwood.

    PubMed

    Jones, Brandon W; Venditti, Richard; Park, Sunkyu; Jameel, Hasan

    2014-09-01

    Mechanical refining has been shown to improve biomass enzymatic digestibility. In this study industrial high-yield sodium carbonate hardwood pulp was subjected to lab, pilot and industrial refining to determine if the mechanical refining improves the enzymatic hydrolysis sugar conversion efficiency differently at different refining scales. Lab, pilot and industrial refining increased the biomass digestibility for lignocellulosic biomass relative to the unrefined material. The sugar conversion was increased from 36% to 65% at 5 FPU/g of biomass with industrial refining at 67.0 kWh/t, which was more energy efficient than lab and pilot scale refining. There is a maximum in the sugar conversion with respect to the amount of refining energy. Water retention value is a good predictor of improvements in sugar conversion for a given fiber source and composition. Improvements in biomass digestibility with refining due to lab, pilot plant and industrial refining were similar with respect to water retention value. PMID:25016156

  14. Coal supply for California

    NASA Technical Reports Server (NTRS)

    Yancik, J. J.

    1978-01-01

    The potential sources and qualities of coals available for major utility and industrial consumers in California are examined and analyzed with respect to those factors that would affect the reliability of supplies. Other considerations, such as the requirements and assurances needed by the coal producers to enter into long-term contracts and dedicate large reserves of coal to these contracts are also discussed. Present and potential future mining contraints on coal mine operators are identified and analyzed with respect to their effect on availability of supply.

  15. Large scale solubilization of coal and bioconversion to utilizable energy. Quarterly report, October 1, 1995--December 31, 1995

    SciTech Connect

    Mishra, N.C.

    1995-12-31

    The ability of Neurospora to solubilize and bioconvert coal was investigated. The coal solubilizing activity (CSA) was fractionated to isolate the enzyme responsible for this activity. The enzyme was purified in order to obtain the amino acid sequence. From that sequence potential oligonucleotide probes were synthesized and used to screen genomic library of Neurospora. The gene so identified was isolated. CSA appears to be an phenol oxidase or is tyrosinase.

  16. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30

    evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to

  17. Coal chemicals -- The Indian scenario

    SciTech Connect

    Bhattacharya, R.N.

    1998-12-31

    Presently the production of coal chemicals in India is primarily based on by-products of high temperature and low temperature carbonization of coal/lignite. There are seven major steel plants in different parts of the country, each having their own coking plants. The total production figures of coal tar and benzole from these plants are about 373,400 tonnes (te) and 40,500 te respectively. In addition, about 4,000 te of coal tar is available from the small and medium scale coking plants. There exists about 15 coal tar distillation units, mostly in the steel plants, having facilities for the recovery and processing of by-products. The total tar distillation capacity is about 1,530 tpd including 230 tpd available in the state and private sectors. Currently, only seven important chemicals, namely ammonium sulfate, benzene, toluene, xylenes, naphthalene, phenol and cresols are recovered from high temperature tar. In addition, three low temperature carbonization units are in operation. The installed capacity of the briquetting and carbonization plant at Neyveli (Tamil Nadu) is 1.5 million tpa of raw lignite designated to produce about 33,800 te of tar apart from 3,350 te of neutral oil and 2,820 te of phenols. The other two units at Ramakrishnapuram (Andhra Pradesh) and Dankuni (West Bengal) have throughputs of 900 te and 1,500 te of non-coking coal per day respectively. Chemicals likely to be available from these units are phenol, cresols, xylenols and high boiling tar acids. The by-products of coal carbonization are, however, not sufficient to meet the present day demand of organic chemicals in the country so that many of these chemicals are now obtained from petro-sources including natural gas as well as by synthetic route. This paper presents the current status of technology available in India and discusses how a change in the outlook to consider coal as a chemical feedstock rather than a fuel can make coal chemicals a viable option for chemical industry, at least

  18. Microbial desulfurization of coal

    NASA Technical Reports Server (NTRS)

    Dastoor, M. N.; Kalvinskas, J. J.

    1978-01-01

    Experiments indicate that several sulfur-oxidizing bacteria strains have been very efficient in desulfurizing coal. Process occurs at room temperature and does not require large capital investments of high energy inputs. Process may expand use of abundant reserves of high-sulfur bituminous coal, which is currently restricted due to environmental pollution. On practical scale, process may be integrated with modern coal-slurry transportation lines.

  19. Directory of coal production ownership, 1979

    SciTech Connect

    Thompson, B.

    1981-10-01

    Ownership patterns in the coal industry are highly complex. Many producers are diversified into other lines of activity. The pattern and extent of this diversification has varied through time. In the past, steel and nonferrous metals companies had major coal industry involvement. This is still true today. However, other types of enterprises have entered the industry de novo or through merger. Those of greatest significance in recent times have involved petroleum and particularly public utility companies. This report attempts to identify, as accurately as possible, production ownership patterns in the coal industry. The audience for this Directory is anyone who is interested in accurately tracing the ownership of coal companies to parent companies, or who is concerned about the structure of ownership in the US coal industry. This audience includes coal industry specialists, coal industry policy analysts, economists, financial analysts, and members of the investment community.

  20. Metabolic Profiling of Geobacter sulfurreducens during Industrial Bioprocess Scale-Up

    PubMed Central

    Muhamadali, Howbeer; Xu, Yun; Ellis, David I.; Allwood, J. William; Rattray, Nicholas J. W.; Correa, Elon; Alrabiah, Haitham

    2015-01-01

    During the industrial scale-up of bioprocesses it is important to establish that the biological system has not changed significantly when moving from small laboratory-scale shake flasks or culturing bottles to an industrially relevant production level. Therefore, during upscaling of biomass production for a range of metal transformations, including the production of biogenic magnetite nanoparticles by Geobacter sulfurreducens, from 100-ml bench-scale to 5-liter fermentors, we applied Fourier transform infrared (FTIR) spectroscopy as a metabolic fingerprinting approach followed by the analysis of bacterial cell extracts by gas chromatography-mass spectrometry (GC-MS) for metabolic profiling. FTIR results clearly differentiated between the phenotypic changes associated with different growth phases as well as the two culturing conditions. Furthermore, the clustering patterns displayed by multivariate analysis were in agreement with the turbidimetric measurements, which displayed an extended lag phase for cells grown in a 5-liter bioreactor (24 h) compared to those grown in 100-ml serum bottles (6 h). GC-MS analysis of the cell extracts demonstrated an overall accumulation of fumarate during the lag phase under both culturing conditions, coinciding with the detected concentrations of oxaloacetate, pyruvate, nicotinamide, and glycerol-3-phosphate being at their lowest levels compared to other growth phases. These metabolites were overlaid onto a metabolic network of G. sulfurreducens, and taking into account the levels of these metabolites throughout the fermentation process, the limited availability of oxaloacetate and nicotinamide would seem to be the main metabolic bottleneck resulting from this scale-up process. Additional metabolite-feeding experiments were carried out to validate the above hypothesis. Nicotinamide supplementation (1 mM) did not display any significant effects on the lag phase of G. sulfurreducens cells grown in the 100-ml serum bottles. However

  1. Metabolic Profiling of Geobacter sulfurreducens during Industrial Bioprocess Scale-Up.

    PubMed

    Muhamadali, Howbeer; Xu, Yun; Ellis, David I; Allwood, J William; Rattray, Nicholas J W; Correa, Elon; Alrabiah, Haitham; Lloyd, Jonathan R; Goodacre, Royston

    2015-05-15

    During the industrial scale-up of bioprocesses it is important to establish that the biological system has not changed significantly when moving from small laboratory-scale shake flasks or culturing bottles to an industrially relevant production level. Therefore, during upscaling of biomass production for a range of metal transformations, including the production of biogenic magnetite nanoparticles by Geobacter sulfurreducens, from 100-ml bench-scale to 5-liter fermentors, we applied Fourier transform infrared (FTIR) spectroscopy as a metabolic fingerprinting approach followed by the analysis of bacterial cell extracts by gas chromatography-mass spectrometry (GC-MS) for metabolic profiling. FTIR results clearly differentiated between the phenotypic changes associated with different growth phases as well as the two culturing conditions. Furthermore, the clustering patterns displayed by multivariate analysis were in agreement with the turbidimetric measurements, which displayed an extended lag phase for cells grown in a 5-liter bioreactor (24 h) compared to those grown in 100-ml serum bottles (6 h). GC-MS analysis of the cell extracts demonstrated an overall accumulation of fumarate during the lag phase under both culturing conditions, coinciding with the detected concentrations of oxaloacetate, pyruvate, nicotinamide, and glycerol-3-phosphate being at their lowest levels compared to other growth phases. These metabolites were overlaid onto a metabolic network of G. sulfurreducens, and taking into account the levels of these metabolites throughout the fermentation process, the limited availability of oxaloacetate and nicotinamide would seem to be the main metabolic bottleneck resulting from this scale-up process. Additional metabolite-feeding experiments were carried out to validate the above hypothesis. Nicotinamide supplementation (1 mM) did not display any significant effects on the lag phase of G. sulfurreducens cells grown in the 100-ml serum bottles. However

  2. Identification of iron oxide impurities in earliest industrial-scale processed platinum

    SciTech Connect

    Weerd, Jaap van der; Rehren, Thilo . E-mail: th.rehren@ucl.ac.uk; Firth, Steven; Clark, Robin J.H. . E-mail: r.j.h.clark@ucl.ac.uk

    2004-09-15

    A detailed investigation of iron oxide inclusions in a 19th century Russian platinum coin is presented. Such coins represent the products of the first industrial-scale purification of platinum metal. The processed metal is far from pure, however, and two types of iron oxide inclusions are identified by electron microprobe and Raman microscopy. The results show that the inclusions mainly consist of magnetite and haematite. The Raman band of magnetite at 668 cm{sup -1} was found to shift to about 680 cm{sup -1} with an increase in the average oxidation state of the iron. It is concluded that the iron oxides are formed during the heating of the platinum metal powder in the manufacturing process.

  3. Drivers and barriers to e-invoicing adoption in Greek large scale manufacturing industries

    SciTech Connect

    Marinagi, Catherine E-mail: ptrivel@yahoo.com Trivellas, Panagiotis E-mail: ptrivel@yahoo.com Reklitis, Panagiotis E-mail: ptrivel@yahoo.com; Skourlas, Christos

    2015-02-09

    This paper attempts to investigate the drivers and barriers that large-scale Greek manufacturing industries experience in adopting electronic invoices (e-invoices), based on three case studies with organizations having international presence in many countries. The study focuses on the drivers that may affect the increase of the adoption and use of e-invoicing, including the customers demand for e-invoices, and sufficient know-how and adoption of e-invoicing in organizations. In addition, the study reveals important barriers that prevent the expansion of e-invoicing, such as suppliers’ reluctance to implement e-invoicing, and IT infrastructures incompatibilities. Other issues examined by this study include the observed benefits from e-invoicing implementation, and the financial priorities of the organizations assumed to be supported by e-invoicing.

  4. Functionality Enhancement of Industrialized Optical Fiber Sensors and System Developed for Full-Scale Pavement Monitoring

    PubMed Central

    Wang, Huaping; Liu, Wanqiu; He, Jianping; Xing, Xiaoying; Cao, Dandan; Gao, Xipeng; Hao, Xiaowei; Cheng, Hongwei; Zhou, Zhi

    2014-01-01

    Pavements always play a predominant role in transportation. Health monitoring of pavements is becoming more and more significant, as frequently suffering from cracks, rutting, and slippage renders them prematurely out of service. Effective and reliable sensing elements are thus in high demand to make prognosis on the mechanical properties and occurrence of damage to pavements. Therefore, in this paper, various types of functionality enhancement of industrialized optical fiber sensors for pavement monitoring are developed, with the corresponding operational principles clarified in theory and the performance double checked by basic experiments. Furthermore, a self-healing optical fiber sensing network system is adopted to accomplish full-scale monitoring of pavements. The application of optical fiber sensors assembly and self-healing network system in pavement has been carried out to validate the feasibility. It has been proved that the research in this article provides a valuable method and meaningful guidance for the integrity monitoring of civil structures, especially pavements. PMID:24854060

  5. Low frequency ultrasonic device Sonitube: A possible gate to pilot and industrial scale applications

    NASA Astrophysics Data System (ADS)

    Leveque, J. M.; Duclaux, Laurent; Fontvieille, Dominique; Gondrexon, Nicolas; Vibert, Raphael; Perrier, Arnaud

    2014-10-01

    One of the first commercially available low frequency ultrasonic devices working on continuous mode, Sonitube®, is presented and described here below. This apparatus, unique in its design, is not only of an easy handling but also does require neither heavy maintenance nor high energy input. In addition the great advantage to work on continuous mode allows to foreseen potential pilot and even small scale industrial applications with flow-rates from 50 to 800L/h. Its potential has been so far explored in protein disaggregation, dispersion of aggregates and particles and transesterification processes. Here, some preliminary results done on biogas processing will be presented and discussed, highlighting the high potential of this device.

  6. Torrefaction of cedarwood in a pilot scale rotary kiln and the influence of industrial flue gas.

    PubMed

    Mei, Yanyang; Liu, Rujie; Yang, Qing; Yang, Haiping; Shao, Jingai; Draper, Christopher; Zhang, Shihong; Chen, Hanping

    2015-02-01

    Torrefaction of cedarwood was performed in a pilot-scale rotary kiln at various temperatures (200, 230, 260 and 290°C). The torrefaction properties, the influence on the grindability and hydroscopicity of the torrefied biomass were investigated in detail as well as the combustion performance. It turned out that, compared with raw biomass, the grindability and the hydrophobicity of the torrefied biomass were significantly improved, and the increasing torrefaction temperature resulted in a decrease in grinding energy consumption and an increase in the proportion of smaller-sized particles. The use of industrial flue gas had a significant influence on the behavior of cedarwood during torrefaction and the properties of the resultant solid products. To optimize the energy density and energy yield, the temperature of torrefaction using flue gas should be controlled within 260°C. Additionally, the combustion of torrefied samples was mainly the combustion of chars, with similar combustion characteristics to lignite. PMID:25497055

  7. Industrial scale garage-type dry fermentation of municipal solid waste to biogas.

    PubMed

    Qian, M Y; Li, R H; Li, J; Wedwitschka, H; Nelles, M; Stinner, W; Zhou, H J

    2016-10-01

    The objectives of this study was to through monitoring the 1st industrial scale garage-type dry fermentation (GTDF) MSW biogas plant in Bin County, Harbin City, Heilongjiang Province, China, to investigate its anaerobic digestion (AD) performance and the stability of process. After a monitoring period of 180days, the results showed that the volumetric biogas production of the digesters and percolate tank was 0.72 and 2.22m(3) (m(3)d)(-1), respectively, and the specific biogas yield of the feedstock was about 270m(3)CH4tVS(-1), which indicated that the GTDF is appropriate for the Chinese MSW. This paper also raised some problems aimed at improving the process stability and AD efficiency. PMID:26970693

  8. Application of a constructed wetland for industrial wastewater treatment: a pilot-scale study.

    PubMed

    Chen, T Y; Kao, C M; Yeh, T Y; Chien, H Y; Chao, A C

    2006-06-01

    The main objective of this study was to examine the efficacy and capacity of using constructed wetlands on industrial pollutant removal. Four parallel pilot-scale modified free water surface (FWS) constructed wetland systems [dimension for each system: 4-m (L)x1-m (W)x1-m (D)] were installed inside an industrial park for conducting the proposed treatability study. The averaged influent contains approximately 170 mg l(-1) chemical oxygen demand (COD), 80 mg l(-1) biochemical oxygen demand (BOD), 90 mg l(-1) suspend solid (SS), and 32 mg l(-1) NH(3)-N. In the plant-selection study, four different wetland plant species including floating plants [Pistia stratiotes L. (P. stratiotes) and Ipomoea aquatica (I. aquatica)] and emergent plants [Phragmites communis L. (P. communis) and Typha orientalis Presl. (T. orientalis)] were evaluated. Results show that only the emergent plant (P. communis) could survive and reproduce with a continuous feed of 0.4m(3)d(-1) of the raw wastewater. Thus, P. communis was used in the subsequent treatment study. Two different control parameters including hydraulic retention time (HRT) (3, 5, and 7d) and media [vesicles ceramic bioballs and small gravels, 1cm in diameter] were examined in the treatment study. Results indicate that the system with a 5-d HRT (feed rate of 0.4m(3)d(-1)) and vesicles ceramic bioballs as the media had the acceptable and optimal pollutant removal efficiency. If operated under conditions of the above parameters, the pilot-plant wetland system can achieve removal of 61% COD, 89% BOD, 81% SS, 35% TP, and 56% NH(3)-N. The treated wastewater meets the current industrial wastewater discharge standards in Taiwan. PMID:16413595

  9. Full-scale Daramend{trademark} bioremediation of industrial soils containing chlorinated phenols and PAHs

    SciTech Connect

    Seech, A.G.; Bucens, P.G.; Bergeron, D.

    1994-12-31

    Daramend{trademark} bioremediation was developed under the sponsorship of, and is owned by, the Government of Canada. Grace Dearborn Inc. has acquired the license for worldwide application of this technology; which has been successfully used at full-scale to remediate soils containing chlorophenols, polynuclear aromatic hydrocarbons (PAHS) and petroleum hydrocarbons. Over the course of four years (1991--1994), soil was treated under a variety of conditions. During ex-situ treatment, the mean total chlorophenol concentration in excavated soil was reduced from 702 mg/kg to less than the criterion established by the Canadian Council of Ministers of the Environment (CCME) for industrial soil (5 mg/kg). In the same soil the total PAH concentration was reduced from 1.442 me/kg to 35 mg/kg. and the concentrations of all PAH isomers were reduced to less than the CCME criteria for industrial soil (i.e. 10 mg/kg for carcinogenic isomers). Standard toxicological tests, including earthworm mortality and seed germination, were performed on soil taken from the treated area and the control area after completion of the bioremediation. The tests indicated that Daramend treatment had reduced or eliminated the soil`s toxicity.

  10. Processes for non-destructive transfer of graphene: widening the bottleneck for industrial scale production

    NASA Astrophysics Data System (ADS)

    Zaretski, Aliaksandr V.; Lipomi, Darren J.

    2015-05-01

    The exceptional charge-transport, mechanical, and barrier properties of graphene are well known. High-quality films of single-layer graphene produced over large areas, however, are extremely expensive. The high cost of graphene precludes its use in industries--such as transparent electrodes and flexible packaging--that might take full advantage of its properties. This minireview presents several strategies for the transfer of graphene from the substrates used for growth to substrates used for the final application. Each strategy shares the characteristic of being non-destructive: that is, the growth substrate remains reusable for further synthesis of new graphene. These processes have the potential to lower significantly the costs of manufacturing graphene, to increase production yields, and to minimize environmental impact. This article is divided into sections on (i) the synthesis of high-quality single-layer graphene and (ii) its non-destructive transfer to a host substrate. Section (ii) is further divided according to the substrate from which graphene is transferred: single-crystalline wafers or flexible copper foils. We also comment, wherever possible, on defects produced as a result of the transfer, and potential strategies to mitigate these defects. We conclude that several methods for the green synthesis and transfer of graphene have several of the right characteristics to be useful in industrial scale production.

  11. Processes for non-destructive transfer of graphene: widening the bottleneck for industrial scale production.

    PubMed

    Zaretski, Aliaksandr V; Lipomi, Darren J

    2015-06-14

    The exceptional charge-transport, mechanical, and barrier properties of graphene are well known. High-quality films of single-layer graphene produced over large areas, however, are extremely expensive. The high cost of graphene precludes its use in industries-such as transparent electrodes and flexible packaging-that might take full advantage of its properties. This minireview presents several strategies for the transfer of graphene from the substrates used for growth to substrates used for the final application. Each strategy shares the characteristic of being non-destructive: that is, the growth substrate remains reusable for further synthesis of new graphene. These processes have the potential to lower significantly the costs of manufacturing graphene, to increase production yields, and to minimize environmental impact. This article is divided into sections on (i) the synthesis of high-quality single-layer graphene and (ii) its non-destructive transfer to a host substrate. Section (ii) is further divided according to the substrate from which graphene is transferred: single-crystalline wafers or flexible copper foils. We also comment, wherever possible, on defects produced as a result of the transfer, and potential strategies to mitigate these defects. We conclude that several methods for the green synthesis and transfer of graphene have several of the right characteristics to be useful in industrial scale production. PMID:25924926

  12. Technological Change and Its Labor Impact in Five Energy Industries. Coal Mining/Oil and Gas Extraction/Petroleum Refining/Petroleum Pipeline Transportation/Electric and Gas Utilities.

    ERIC Educational Resources Information Center

    Bureau of Labor Statistics (DOL), Washington, DC.

    This bulletin appraises major technological changes emerging in five American industries (coal mining, oil and gas extraction, petroleum refining, petroleum pipeline transportation, and electric and gas utilities) and discusses the impact of these changes on productivity and occupations over the next five to ten years. Its separate reports on each…

  13. The Clean Coal Technology Program: Lessons learned

    SciTech Connect

    Not Available

    1994-07-01

    The Clean Coal Technology (CCT) Program is a unique partnership between the federal government and industry that has as its primary goal the successful introduction of new clean coal utilization technologies into the energy marketplace. Clean coal technologies being demonstrated under the CCT Program are establishing a technology base that will enable the nation to meet more stringent energy and environmental goals. Most of the, demonstrations are being conducted at commercial scale, in actual user environments, and under circumstances typical of commercial operations. These features allow the potential of the technologies to be evaluated in their intended commercial applications. Each application addresses one of the following four market sectors: advanced electric power generation; environmental control devices; coal processing for clean fuels; and industrial applications. The purpose of this report is fourfold: Explain the CCT program as a model for successful joint government industry partnership for selecting and demonstrating technologies that have promise for adaptation to the energy marketplace; set forth the process by which the process has been implemented and the changes that have been made to improve that process; outline efforts employed to inform potential users and other interested parties about the technologies being developed; and examine some of the questions which must be considered in determining if the CCT Program model can be applied to other programs.

  14. GIS Representation of Coal-Bearing Areas in Africa

    USGS Publications Warehouse

    Merrill, Matthew D.; Tewalt, Susan J.

    2008-01-01

    The African continent contains approximately 5 percent of the world's proven recoverable reserves of coal (World Energy Council, 2007). Energy consumption in Africa is projected to grow at an annual rate of 2.3 percent from 2004 through 2030, while average consumption in first-world nations is expected to rise at 1.4 percent annually (Energy Information Administration, 2007). Coal reserves will undoubtedly continue to be part of Africa's energy portfolio as it grows in the future. A review of academic and industrial literature indicates that 27 nations in Africa contain coal-bearing rock. South Africa accounts for 96 percent of Africa's total proven recoverable coal reserves, ranking it sixth in the world. This report is a digital compilation of information on Africa's coal-bearing geology found in the literature and is intended to be used in small scale spatial investigations in a Geographic Information System (GIS) and as a visual aid for the discussion of Africa's coal resources. Many maps of African coal resources often include points for mine locations or regional scale polygons with generalized borders depicting basin edges. Point locations are detailed but provide no information regarding extent, and generalized polygons do not have sufficient detail. In this dataset, the polygons are representative of the actual coal-bearing lithology both in location and regional extent. Existing U.S. Geological Survey (USGS) digital geology datasets provide the majority of the base geologic polygons. Polygons for the coal-bearing localities were clipped from the base geology that represented the age and extent of the coal deposit as indicated in the literature. Where the 1:5,000,000-scale geology base layer's ages conflicted with those in the publications, polygons were generated directly from the regional African coal maps (1:500,000 scale, approximately) in the published material. In these cases, coal-bearing polygons were clipped to the literature's indicated coal

  15. Iron and zinc fortification of corn tortilla made either at the household or at industrial scale.

    PubMed

    Tovar, Luis Raul; Larios-Saldaña, Alfredo

    2005-03-01

    Fe and Zn deficiencies among the Mexican population are widespread, and one-third of children and women of childbearing age are anemic. Since diets that are Fe-deficient are most probably also Zn-deficient, a proprietary process was developed to fortify corn tortilla with these trace elements at the first stage of treatment with lime. Phytic acid (PA), Ca, Fe, and Zn content were determined, as well as the molar ratios of phytate/Fe, phytate/Zn, and Ca x phytate to Zn in traditional and fortified tortillas; the Student's t-test was used to detect differences between the treatments (p < 0.001). Contents of Fe and Zn in the fortified tortilla relative to the traditional tortilla were 1.9 and 3.4 times greater than the latter, whereas PA contents showed the opposite result, i.e. traditional tortillas had 1.65 times more PA than the fortified tortilla. Consequently the calculated molar ratios were statistically more favorable for fortified than for traditional tortillas (p < 0.001). The process developed allows making iron- and zinc-fortified tortillas by lime-treating or nixtamalizing corn either at the household, at small-scale tortilla shops, or at industrial scale by using lime fortified with both trace elements. The cost of this fortification is negligible. PMID:15929635

  16. Non-destructive monitoring of fiber orientation using AC-IS: An industrial-scale application

    SciTech Connect

    Ozyurt, Nilufer . E-mail: ozyurtnil@itu.edu.tr; Mason, Thomas O.; Shah, Surendra P.

    2006-09-15

    A comprehensive study has been undertaken to investigate the ability of AC-impedance spectroscopy (AC-IS) to non-destructively monitor the fiber dispersion of conductive fiber-reinforced cement-based materials. Previous work showed that AC-IS effectively monitors various fiber dispersion issues in lab-scale steel fiber-reinforced specimens. In this part of the study, AC-IS was used to study fiber orientation in an industrial-scale pre-cast concrete beam. A conventional method-image analysis (IA)-was used to verify the results of AC-IS measurements. The results of AC-IS and IA were found to match very well in experimental uncertainty. Splitting tensile tests and bending tests were conducted on the parts of the beam to study the effects of fiber orientation on the mechanical performance. The results of the mechanical tests also confirmed the results of AC-IS with splitting tensile strengths increasing as the alignment of fibers increased.

  17. Vertical profile, source apportionment, and toxicity of PAHs in sediment cores of a wharf near the coal-based steel refining industrial zone in Kaohsiung, Taiwan.

    PubMed

    Chen, Chih-Feng; Chen, Chiu-Wen; Ju, Yun-Ru; Dong, Cheng-Di

    2016-03-01

    Three sediment cores were collected from a wharf near a coal-based steel refining industrial zone in Kaohsiung, Taiwan. Analyses for 16 polycyclic aromatic hydrocarbons (PAHs) of the US Environmental Protection Agency priority list in the core sediment samples were conducted using gas chromatography-mass spectrometry. The vertical profiles of PAHs in the core sediments were assessed, possible sources and apportionment were identified, and the toxicity risk of the core sediments was determined. The results from the sediment analyses showed that total concentrations of the 16 PAHs varied from 11774 ± 4244 to 16755 ± 4593 ng/g dry weight (dw). Generally, the vertical profiles of the PAHs in the sediment cores exhibited a decreasing trend from the top to the lower levels of the S1 core and an increasing trend of PAHs from the top to the lower levels of the S2 and S3 cores. Among the core sediment samples, the five- and six-ring PAHs were predominantly in the S1 core, ranging from 42 to 54 %, whereas the composition of the PAHs in the S2 and S3 cores were distributed equally across three groups: two- and three-ring, four-ring, and five- and six-ring PAHs. The results indicated that PAH contamination at the site of the S1 core had a different source. The molecular indices and principal component analyses with multivariate linear regression were used to determine the source contributions, with the results showing that the contributions of coal, oil-related, and vehicle sources were 38.6, 35.9, and 25.5 %, respectively. A PAH toxicity assessment using the mean effect range-median quotient (m-ERM-q, 0.59-0.79), benzo[a]pyrene toxicity equivalent (TEQ(carc), 1466-1954 ng TEQ/g dw), and dioxin toxicity equivalent (TEQ(fish), 3036-4174 pg TEQ/g dw) identified the wharf as the most affected area. The results can be used for regular monitoring, and future pollution prevention and management should target the coal-based industries in this region for pollution reduction

  18. Industry

    SciTech Connect

    Bernstein, Lenny; Roy, Joyashree; Delhotal, K. Casey; Harnisch, Jochen; Matsuhashi, Ryuji; Price, Lynn; Tanaka, Kanako; Worrell, Ernst; Yamba, Francis; Fengqi, Zhou; de la Rue du Can, Stephane; Gielen, Dolf; Joosen, Suzanne; Konar, Manaswita; Matysek, Anna; Miner, Reid; Okazaki, Teruo; Sanders, Johan; Sheinbaum Parado, Claudia

    2007-12-01

    This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of

  19. The Full Scale Seal Experiment - A Seal Industrial Prototype for Cigeo - 13106

    SciTech Connect

    Lebon, P.; Bosgiraud, J.M.; Foin, R.; Armand, G.

    2013-07-01

    The Full Scale Seal (FSS) Experiment is one of various experiments implemented by Andra, within the frame of the Cigeo (the French Deep Geological Repository) Project development, to demonstrate the technical construction feasibility and performance of seals to be constructed, at time of Repository components (shafts, ramps, drifts, disposal vaults) progressive closure. FSS is built inside a drift model fabricated on surface for the purpose. Prior to the scale 1:1 seal construction test, various design tasks are scheduled. They include the engineering work on the drift model to make it fit with the experimental needs, on the various work sequences anticipated for the swelling clay core emplacement and the concrete containment plugs construction, on the specialized handling tools (and installation equipment) manufactured and delivered for the purpose, and of course on the various swelling clay materials and low pH (below 11) concrete formulations developed for the application. The engineering of the 'seal-as-built' commissioning means (tools and methodology) must also be dealt with. The FSS construction experiment is a technological demonstrator, thus it is not focused on the phenomenological survey (and by consequence, on the performance and behaviour forecast). As such, no hydration (forced or natural) is planned. However, the FSS implementation (in particular via the construction and commissioning activities carried out) is a key milestone in view of comforting phenomenological extrapolation in time and scale. The FSS experiment also allows for qualifying the commissioning methods of a real sealing system in the Repository, as built, at time of industrial operations. (authors)

  20. Modeling and full-scale tests of vortex plasma-fuel systems for igniting high-ash power plant coal

    NASA Astrophysics Data System (ADS)

    Messerle, V. E.; Ustimenko, A. B.; Karpenko, Yu. E.; Chernetskiy, M. Yu.; Dekterev, A. A.; Filimonov, S. A.

    2015-06-01

    The processes of supplying pulverized-coal fuel into a boiler equipped with plasma-fuel systems and its combustion in the furnace of this boiler are investigated. The results obtained from 3D modeling of conventional coal combustion processes and its firing with plasma-assisted activation of combustion in the furnace space are presented. The plasma-fuel system with air mixture supplied through a scroll is numerically investigated. The dependence of the swirled air mixture flow trajectory in the vortex plasma-fuel system on the scroll rotation angle is revealed, and the optimal rotation angle at which stable plasma-assisted ignition of pulverized coal flame is achieved is determined.

  1. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications. Task 4 - Testing in Alstom's 15 MWth Boiler Simulation Facility

    SciTech Connect

    Levasseur, Armand

    2014-04-30

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs; Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF); Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools; Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems; Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost; and, Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project is scheduled for completion by April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a matrix of

  2. Mercury speciation and emissions from coal combustion in Guiyang, southwest China

    SciTech Connect

    Tang, S.L.; Feng, X.B.; Qiu, H.R.; Yin, G.X.; Yang, Z.C.

    2007-10-15

    Although China has been regarded as one of the largest anthropogenic mercury emission source with coal combustion, so far the actual measurements of Hg species and Hg emissions from the combustion and the capture of Hg in Chinese emission control devices were very limited. Aiming at Hg mercury species measurements in Guiyang, the capital city of Guizhou province in Southwest China, we studied flue gases of medium-to-small-sized industrial steam coal-firing boiler (10-30 t/h) with no control devices, medium-to-small-sized industrial steam coal-firing boiler with WFGD and large-scale coal combustion with ESPs using Ontario Hytro method. We obtained mercury emission factors of the three representative coal combustion and estimated mercury emissions in Guiyang in 2003, as well as the whole province from 1986 to 2002. Coal combustion in Guiyang emitted 1898 kg mercury to the atmosphere, of which 36% Hg is released from power plants, 41% from industrial coal combustion, and 23% from domestic users, and 267 kg is Hg{sup P}, 813 kg is Hg{sup 2+} and 817 kg is Hg{sup 0}. Mercury emission in Guizhou province increased sharply from 5.8 t in 1986 to 16.4 t in 2002. With the implementation of national economic strategy of China's Western Development, the annual mercury emission from coal combustion in the province is estimated to be about 32 t in 2015.

  3. Mercury speciation and emissions from coal combustion in Guiyang, Southwest China.

    PubMed

    Tang, Shunlin; Feng, Xinbin; Qiu, Jianrong; Yin, Guoxun; Yang, Zaichan

    2007-10-01

    Although China has been regarded as one of the largest anthropogenic mercury emission source with coal combustion, so far the actual measurements of Hg species and Hg emissions from the combustion and the capture of Hg in Chinese emission control devices were very limited. Aiming at Hg mercury species measurements in Guiyang, the capital city of Guizhou province in Southwest China, we studied flue gases of medium-to-small-sized industrial steam coal-firing boiler (10-30 t/h) with no control devices, medium-to-small-sized industrial steam coal-firing boiler with WFGD and large-scale coal combustion with ESPs using Ontario Hytro method. We obtained mercury emission factors of the three representative coal combustion and estimated mercury emissions in Guiyang in 2003, as well as the whole province from 1986 to 2002. Coal combustion in Guiyang emitted 1898 kg mercury to the atmosphere, of which 36% Hg is released from power plants, 41% from industrial coal combustion, and 23% from domestic users, and 267 kg is Hg(p), 813 kg is Hg(2+) and 817 kg is Hg0. Mercury emission in Guizhou province increased sharply from 5.8 t in 1986 to 16.4 t in 2002. With the implementation of national economic strategy of China's Western Development, the annual mercury emission from coal combustion in the province is estimated to be about 32 t in 2015. PMID:17517388

  4. Clean coal

    SciTech Connect

    Liang-Shih Fan; Fanxing Li

    2006-07-15

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  5. Zero Emission Coal

    NASA Astrophysics Data System (ADS)

    Ziock, H.; Guthrie, G. D.; Lackner, K. S.; Harrison, D. P.; Johnson, A. A.

    2002-05-01

    Unless the economic development of the majority of the world's population is prohibited, thereby forcing thereby forcing them to remain in poverty, world energy consumption and therefore carbon dioxide greenhouse gas emission rates could easily increase by an order of magnitude during this century. Given that we have already increased global atmospheric concentrations by 30% compared to their pre-industrial age level, without massive intervention, we will completely overwhelm Nature's ability to cope. In order to stabilize atmospheric CO2 levels, while allowing desired world economic development, the future allowable US per capita CO2 emissions are only 3 % of today's value. This is effectively zero, and thus what is required is the development of technologies that aim for emission of zero CO2 as well as other pollutants. If we continue to rely on our lowest cost, readily available, and dominant energy source, this will involve both a separation of the energy from the fossil fuel carbon followed by a permanent disposal of the CO2. To set the scale, today's yearly global emissions are approaching 25 cubic kilometers of CO2 at liquid densities, and these could grow by an order of magnitude by the end of the century. We describe a zero emission coal technology that would be able to deal with both the scope of the problem and the emission goal. The energy production process is a chemical conversion of coal to electricity or hydrogen, which involves no combustion and thus no smoke stack. The process provides a pure stream of CO2 for disposal while simultaneously achieving fuel to electricity conversion efficiencies that are two times better than today's value. This high efficiency by itself extends cuts pollutant production by a factor of two while also extending the lifetime of our fossil fuel reserves by a factor of two to many hundreds of years. By concentrating on coal, we also lay the groundwork for energy security and complete independence for the US, given the

  6. Early Implementation of Large Scale Carbon Dioxide Removal Projects through the Cement Industry

    NASA Astrophysics Data System (ADS)

    Zeman, F. S.

    2014-12-01

    The development of large-scale carbon dioxide reduction projects requires high purity CO2and a reactive cation source. A project seeking to provide both of these requirements will likely face cost barriers with current carbon prices. The cement industry is a suitable early implementation site for such projects by virtue of the properties of its exhaust gases and those of waste concrete. Cement plants are the second largest source of industrial CO2 emissions, globally. It is also the second largest commodity after water, has no ready substitute and is literally the foundation of society. Finally, half of the CO2 emissions originate from process reactions rather than fossil fuel combustion resulting in higher flue gas CO2concentrations. These properties, with the co-benefits of oxygen combustion, create a favorable environment for spatially suitable projects. Oxygen combustion involves substituting produced oxygen for air in a combustion reaction. The absence of gaseous N2 necessitates the recirculation of exhaust gases to maintain kiln temperatures, which increase the CO2 concentrations from 28% to 80% or more. Gas exit temperatures are also elevated (>300oC) and can reach higher temperatures if the multi stage pre-heater towers, that recover heat, are re-designed in light of FGR. A ready source of cations can be found in waste concrete, a by-product of construction and demolition activities. These wastes can be processed to remove cations and then reacted with atmospheric CO2 to produce carbonate minerals. While not carbon negative, they represent a demonstration opportunity for binding atmospheric CO2while producing a saleable product (precipitated calcium carbonate). This paper will present experimental results on PCC production from waste concrete along with modeling results for oxygen combustion at cement facilities. The results will be presented with a view to mineral sequestration process design and implementation.

  7. Effect of processing techniques at industrial scale on orange juice antioxidant and beneficial health compounds.

    PubMed

    Gil-Izquierdo, Angel; Gil, Maria I; Ferreres, Federico

    2002-08-28

    Phenolic compounds, vitamin C (L-ascorbic acid and L-dehydroascorbic acid), and antioxidant capacity were evaluated in orange juices manufactured by different techniques. Five processes at industrial scale (squeezing, mild pasteurization, standard pasteurization, concentration, and freezing) used in commercial orange juice manufacturing were studied. In addition, domestic squeezing (a hand processing technique) was compared with commercial squeezing (an industrial FMC single-strength extraction) to evaluate their influences on health components of orange juice. Whole orange juice was divided into soluble and cloud fractions after centrifugation. Total and individual phenolics were analyzed in both fractions by HPLC. Commercial squeezing extracted 22% more phenolics than hand squeezing. The freezing process caused a dramatic decrease in phenolics, whereas the concentration process caused a mild precipitation of these compounds to the juice cloud. In pulp, pasteurization led to degradation of several phenolic compounds, that is, caffeic acid derivatives, vicenin 2 (apigenin 6,8-di-C-glucoside), and narirutin (5,7,4'-trihydroxyflavanone-7-rutinoside) with losses of 34.5, 30.7, and 28%, respectively. Regarding vitamin C, orange juice produced by commercial squeezing contained 25% more of this compound than domestic squeezing. Mild and standard pasteurization slightly increased the total vitamin C content as the contribution from the orange solids parts, whereas concentration and freezing did not show significant changes. The content of L-ascorbic acid provided 77-96% of the total antioxidant capacity of orange juice. Mild pasteurization, standard pasteurization, concentration, and freezing did not affect the total antioxidant capacity of juice, but they did, however, in pulp, where it was reduced by 47%. PMID:12188615

  8. Create a Consortium and Develop Premium Carbon Products from Coal

    SciTech Connect

    Frank Rusinko; John Andresen; Jennifer E. Hill; Harold H. Schobert; Bruce G. Miller

    2006-01-01

    The objective of these projects was to investigate alternative technologies for non-fuel uses of coal. Special emphasis was placed on developing premium carbon products from coal-derived feedstocks. A total of 14 projects, which are the 2003 Research Projects, are reported herein. These projects were categorized into three overall objectives. They are: (1) To explore new applications for the use of anthracite in order to improve its marketability; (2) To effectively minimize environmental damage caused by mercury emissions, CO{sub 2} emissions, and coal impounds; and (3) To continue to increase our understanding of coal properties and establish coal usage in non-fuel industries. Research was completed in laboratories throughout the United States. Most research was performed on a bench-scale level with the intent of scaling up if preliminary tests proved successful. These projects resulted in many potential applications for coal-derived feedstocks. These include: (1) Use of anthracite as a sorbent to capture CO{sub 2} emissions; (2) Use of anthracite-based carbon as a catalyst; (3) Use of processed anthracite in carbon electrodes and carbon black; (4) Use of raw coal refuse for producing activated carbon; (5) Reusable PACs to recycle captured mercury; (6) Use of combustion and gasification chars to capture mercury from coal-fired power plants; (7) Development of a synthetic coal tar enamel; (8) Use of alternative binder pitches in aluminum anodes; (9) Use of Solvent Extracted Carbon Ore (SECO) to fuel a carbon fuel cell; (10) Production of a low cost coal-derived turbostratic carbon powder for structural applications; (11) Production of high-value carbon fibers and foams via the co-processing of a low-cost coal extract pitch with well-dispersed carbon nanotubes; (12) Use of carbon from fly ash as metallurgical carbon; (13) Production of bulk carbon fiber for concrete reinforcement; and (14) Characterizing coal solvent extraction processes. Although some of the

  9. Environmentally conscious coal combustion

    SciTech Connect

    Hickmott, D.D.; Brown, L.F.; Currier, R.P.

    1997-08-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of this project was to evaluate the environmental impacts of home-scale coal combustion on the Navajo Reservation and develop strategies to reduce adverse health effects associated with home-scale coal combustion. Principal accomplishments of this project were: (1) determination of the metal and gaseous emissions of a representative stove on the Navajo Reservation; (2) recognition of cyclic gaseous emissions in combustion in home-scale combustors; (3) `back of the envelope` calculation that home-scale coal combustion may impact Navajo health; and (4) identification that improved coal stoves require the ability to burn diverse feedstocks (coal, wood, biomass). Ultimately the results of Navajo home-scale coal combustion studies will be extended to the Developing World, particularly China, where a significant number (> 150 million) of households continue to heat their homes with low-grade coal.

  10. Bench-scale demonstration of biological production of ethanol from coal synthesis gas. Quarterly report, January 1, 1994--March 31, 1994

    SciTech Connect

    Not Available

    1994-06-01

    This report presents results from the solvent selection, fermentation, and product recovery studies performed thus far in the development of a bench scale unit for the production of ethanol from coal-derived synthesis gas. Several additional solvents have been compared for their ability to extract ethanol from aqueous solutions of ethanol in water and fermentation permeate. The solvent 2,6-dimethyl-4-heptanol still appears to be the solvent of choice. Liquid-liquid equilibrium data have been collected for ethanol and 2,6-dimethyl-4-heptanol.

  11. Impact of the addition of chicken litter on mercury speciation and emissions from coal combustion in a laboratory-scale fluidized bed combustor

    SciTech Connect

    Songgeng Li; Shuang Deng; Andy Wu; Wei-ping Pan

    2008-07-15

    Co-combustion of chicken litter with coal was performed in a laboratory-scale fluidized bed combustor to investigate the effect of chicken litter addition on the partitioning behavior of mercury. Gaseous total and elemental mercury concentrations in the flue gas were measured online, and ash was analyzed for particle-bound mercury along with other elemental and surface properties. The mercury mass balance was between 85 and 105%. The experimental results show that co-combustion of chicken litter decreases the amount of elemental and total mercury in the gas phase. Mercury content in fly ash increases with an increasing chicken litter share. 22 refs., 6 figs., 5 tabs.

  12. EMISSION OF ORGANIC HAZARDOUS AIR POLLUTANTS FROM THE COMBUSION OF PULVERIZED COAL IN A SMALL-SCALE COMBUSTOR

    EPA Science Inventory

    The emissions of hazardous air pollutants (HAPs) from the combustion of pulverized coal have become an important issue in light of the requirements of Title I11 of the 1990 Clean Air Act Amendments, which impose emission limits on 189 compounds and compound classes. Although pre...

  13. Dry sorbent injection of trona to control acid gases from a pilot-scale coal-fired combustion facility

    EPA Science Inventory

    Gaseous and particulate emissions from the combustion of coal have been associated with adverse effects on human and environmental health, and have for that reason been subject to regulation by federal and state governments. Recent regulations by the United States Environmental ...

  14. Large scale solubilization of coal and bioconversion to utilizable energy. Quarterly report, July 1, 1996--September 30 1996

    SciTech Connect

    Mishra, N.C.

    1996-12-31

    A purification of the Neurospora protein with coal solubilization activity (CSA) using DEAE cellulose chromatography is described. The protein is heavily glycosylated suggesting that it is different than tyrosinase or common phenol oxidases even though it resembles these proteins in enzyme activity and molecular weight.

  15. Bench-scale testing of DOE/PETC`s GranuFlow Process for fine coal dewatering and handling. 1: Results using a high-gravity solid-bowl centrifuge

    SciTech Connect

    Wen, W.W.; Killmeyer, R.P.; Lowman, R.H.; Elstrodt, R.

    1995-12-31

    Most advanced fine-coal cleaning processes involve the use of water. Utility companies are concerned not only with the lower Btu content of the resulting wet, cleaned coal, but more importantly with its handleability problems. Solutions to these problems would enhance the utilization of fine-coal cleaning processes in the utility industry. This paper describes testing of the GranuFlow Process, developed and patented by the Pittsburgh Energy Technology Center (PETC) of the US Department of Energy, using a high-gravity solid bowl centrifuge for dewatering and reconstitution of fine-cleaned-coal slurry at 300 lb per hour in PETC`s Coal Preparation Process Research Facility. Fine-cleaned-coal slurry was treated with a bitumen emulsion before dewatering in a high-gravity solid-bowl centrifuge. The treated products appeared to be dry and in a free-flowing granular form, while the untreated products were wet, lumpy, sticky, and difficult to handle. Specifically, test results indicated that the moisture content, handleability, and dust reduction of the dewatered coal product improved as the addition of emulsion increased from 2% to 8%. The improvement in handleability was most visible for the 200 mesh (75 micron) x 0 coal, when compared with 150 mesh (106 micron) x 0, 65 mesh (212 micron) x 0 or 28 mesh (600 micron) x 0 coals. Test results also showed that the moisture content was dramatically reduced (26--37% reduction) for the four different sizes of coals at 6 or 8% emulsion addition. Because of the moisture reduction and the granular form of the product, the freezing problem was also alleviated.

  16. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  17. Dry cleaning of Turkish coal

    SciTech Connect

    Cicek, T.

    2008-07-01

    This study dealt with the upgrading of two different type of Turkish coal by a dry cleaning method using a modified air table. The industrial size air table used in this study is a device for removing stones from agricultural products. This study investigates the technical and economical feasibility of the dry cleaning method which has never been applied before on coals in Turkey. The application of a dry cleaning method on Turkish coals designated for power generation without generating environmental pollution and ensuring a stable coal quality are the main objectives of this study. The size fractions of 5-8, 3-5, and 1-3 mm of the investigated coals were used in the upgrading experiments. Satisfactory results were achieved with coal from the Soma region, whereas the upgrading results of Hsamlar coal were objectionable for the coarser size fractions. However, acceptable results were obtained for the size fraction 1-3 mm of Hsamlar coal.

  18. A Comparison of Texture Development in an Experimental and Industrial Tertiary Oxide Scale in a Hot Strip Mill

    NASA Astrophysics Data System (ADS)

    Yu, Xianglong; Jiang, Zhengyi; Zhao, Jingwei; Wei, Dongbin; Zhou, Ji; Zhou, Cunlong; Huang, Qingxue

    2015-12-01

    Electron backscatter diffraction (EBSD) has been used to investigate the microstructure and texture-based features of an industrial tertiary oxide scale formed on a micro-alloyed low-carbon steel from a hot strip mill. EBSD-derived maps demonstrate that the oxide scale consists primarily of magnetite (Fe3O4) with a small amount of hematite ( α-Fe2O3) which scatters near the surface, at the oxide/steel interface and at the cracking edges. The results extracted from these maps reveal that there is a significant difference between the industrial and the laboratory oxide scales in their grain boundaries, phase boundaries, and texture evolutions. There are high proportions of special coincidence site lattice boundaries Σ3 and Σ13b in the magnetite of the industrial oxide scale, rather than the lower orders of Σ5, Σ7, and Σ17b, which develop in the experimental oxide scale. Within the phase boundaries, the orientation relationships between the magnetite and the hematite correspond to the matching planes and directions {111}Fe3O4||{0001} α-Fe2O3 and {110}Fe3O4||{110} α-Fe2O3. Magnetite in both of these oxide scales develops a relatively weak {001} fiber texture component including a strong {001}<100> cube and a slightly strong {100}<210> texture components. Unlike the {001}<110> rotated cube component in the experimental oxide scale, the magnetite in the industrial tertiary oxide scale develops a strong {112}<110> and a relatively strong {113}<110> and {111}<110> texture components. These findings have the potential to provide a convincing step forward for oxidation research.

  19. The development of coal-based technologies for Department of Defense facilities: Phase 1 final report. Volume 1: Technical report

    SciTech Connect

    Miller, B.G.; Morrison, J.L.; Pisupati, S.V.

    1997-01-31

    The first phase of a three-phase project investigating the development of coal-based technologies for Department of Defense facilities has been completed. The objectives of the project are to: decrease DOD`s dependence on foreign oil and increase its use of coal; promote public and private sector deployment of technologies for utilizing coal-based fuels in oil-designed combustion equipment; and provide a continuing environment for research and development of coal-based fuel technologies for small-scale applications at a time when market conditions in the US are not favorable for the introduction of coal-fired equipment in the commercial and industrial capacity ranges. The Phase 1 activities were focused on developing clean, coal-based combustion technologies for the utilization of both micronized coal-water mixtures (MCWMs) and dry, micronized coal (DMC) in fuel oil-designed industrial boilers. The specific objective in Phase 1 was to deliver fully engineered retrofit options for a fuel oil-designed watertube boiler located on a DOD installation to fire either MCWM or DMC. This was achieved through a project consisting of fundamental, pilot-sale, and demonstration-scale activities investigating coal beneficiation and preparation, and MCWM and DMC combustion performance. In addition, detailed engineering designs and an economic analysis were conducted for a boiler located at the Naval Surface Warfare Center, near Crane, Indiana. Results are reported on MCWM and DMC combustion performance evaluation; engineering design; and cost/economic analysis.

  20. Coal distribution, January--June 1990

    SciTech Connect

    Not Available

    1990-10-17

    The Coal Distribution report provides information on coal production, distribution, and stocks in the United States to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. This issue presents information for January through June 1990. Coal distribution data are shown (in tables 1--34) by coal-producing state of origin, consumer use, method of transportation, and state of destination. 6 figs., 34 tabs.

  1. Commercialization of Coal-to-Liquids Technology

    SciTech Connect

    2007-08-15

    The report provides an overview of the current status of coal-to-liquids (CTL) commercialization efforts, including an analysis of efforts to develop and implement large-scale, commercial coal-to-liquids projects to create transportation fuels. Topics covered include: an overview of the history of coal usage and the current market for coal; a detailed description of what coal-to-liquids technology is; the history of coal-to-liquids development and commercial application; an analysis of the key business factors that are driving the increased interest in coal-to-liquids; an analysis of the issues and challenges that are hindering the commercialization of coal-to-liquids technology; a review of available coal-to-liquids technology; a discussion of the economic drivers of coal-to-liquids project success; profiles of key coal-to-liquids developers; and profiles of key coal-to-liquids projects under development.

  2. A large scale investigation into changes in coal quality caused by dolerite dykes in Secunda, South Africa-implications for the use of proximate analysis on a working mine

    NASA Astrophysics Data System (ADS)

    Bussio, John P.; Roberts, James R.

    2016-05-01

    The coalfields of South Africa contain numerous dolerite intrusions, which affected the quality of the surrounding coal through thermal processes, commonly believed to be controlled by the size of the magmatic body. Data gathered from a working coalfield in Secunda, South Africa, suggest that the relationship between intrusive sills and coal is complex and factors other than intrusion width must be considered in relation to the contact metamorphic effect. The study area contains multiple dolerite intrusions of Karoo age, of which three intrusions occur as sills intruded close to the main coal seam of the. A large database (>8000 boreholes) of coal quality data was used to investigate the presence or absence of a change in coal quality relative to dolerite proximity. Reduction in coal quality was defined using three proximate analysis values, namely the ash, volatile content and dry ash free volatile (DAFV) as defined in the coal industry. The resultant investigation showed no correlation between the position and thickness of the dolerites, and changes in coal quality as measured by proximate analysis. In the absence of a linear relationship between coal quality and dolerite proximity, two processes are proposed to explain the absence of the contact metamorphic effects expected from previous studies. Firstly dolerite emplacement dynamics may influence the size of the metamorphic aureole produced by an intrusion, invalidating intrusion size as a measure of thermal output. Secondly, hydrothermal fluids mobilised by the dolerite intrusions, either from the country rock or the intrusion itself may percolate through the coal and act as the metamorphic agent responsible for changing coal quality, by dissolving the volatile and semi-volatile components of the coal and transporting them to other locations. These two processes are sufficient to explain the lack of a clear "metamorphic effect" related to the dolerite intrusions. However, the perceived lack of a clear

  3. Zero Discharge Performance of an Industrial Pilot-Scale Plant Treating Palm Oil Mill Effluent

    PubMed Central

    Mahmood, Qaisar; Qiu, Jiang-Ping; Li, Yin-Sheng; Chang, Yoon-Seong; Chi, Li-Na; Li, Xu-Dong

    2015-01-01

    Palm oil is one of the most important agroindustries in Malaysia. Huge quantities of palm oil mill effluent (POME) pose a great threat to aqueous environment due to its very high COD. To make full use of discharged wastes, the integrated “zero discharge” pilot-scale industrial plant comprising “pretreatment-anaerobic and aerobic process-membrane separation” was continuously operated for 1 year. After pretreatment in the oil separator tank, 55.6% of waste oil in raw POME could be recovered and sold and anaerobically digested through 2 AnaEG reactors followed by a dissolved air flotation (DAF); average COD reduced to about 3587 mg/L, and biogas production was 27.65 times POME injection which was used to generate electricity. The aerobic effluent was settled for 3 h or/and treated in MBR which could remove BOD3 (30°C) to less than 20 mg/L as required by Department of Environment of Malaysia. After filtration by UF and RO membrane, all organic compounds and most of the salts were removed; RO permeate could be reused as the boiler feed water. RO concentrate combined with anaerobic surplus sludge could be used as biofertilizer. PMID:25685798

  4. A full-scale biological treatment system application in the treated wastewater of pharmaceutical industrial park.

    PubMed

    Lei, Ge; Ren, Hongqiang; Ding, Lili; Wang, Feifei; Zhang, Xingsong

    2010-08-01

    A full-scale combined biological system is used for the treatment of treated wastewater discharged from a pharmaceutical industrial park. This treated water is rich in NH(4)(+)-N (average in 86.4 mg/L), low in COD/NH(4)(+)-N (average in 3.4) and low in BOD(5)/COD ratio (average in 0.24) with pH varying from 7.16 to 7.78. The final effluent of the combined treatment process was stably below 100mg/L COD and 20mg/L NH(4)(+)-N, separately, with organic loading rate of 4954 kg COD/d and 92.5 kg NH(4)(+)-N/d. It is found that the BOD(5)/COD ratio could be raised from 0.24 to 0.35, and the production of total VFAs account for 9.57% of the total COD via the treatment of hydrolysis/acidification. MBBR and oxidation ditch represent 35.4% and 60.7% of NH(4)(+)-N removal, 30.2% and 61.5% of COD removal, separately, of the total treatment process. PCR-DGGE is used for microbial community analysis of MBBR and oxidation ditch. PMID:20335031

  5. Gaseous Oxidized Mercury Flux from Substrates Associated with Industrial Scale Gold Mining in Nevada, USA

    NASA Astrophysics Data System (ADS)

    Miller, M. B.

    2015-12-01

    Gaseous elemental and oxidized mercury (Hg) fluxes were measured in a laboratory setting from substrate materials derived from industrial-scale open pit gold mining operations in Nevada, USA. Mercury is present in these substrates at a range of concentrations (10 - 40000 ng g-1), predominantly of local geogenic origin in association with the mineralized gold ores, but altered and redistributed to a varying degree by subsequent ore extraction and processing operations, including deposition of Hg recently emitted to the atmosphere from large point sources on the mines. Waste rock, heap leach, and tailings material usually comprise the most extensive and Hg emission relevant substrate surfaces. All three of these material types were collected from active Nevada mine sites in 2010 for previous research, and have since been stored undisturbed at the University of Nevada, Reno. Gaseous elemental Hg (GEM) flux was previously measured from these materials under a variety of conditions, and was re-measured in this study, using Teflon® flux chambers and Tekran® 2537A automated ambient air analyzers. GEM flux from dry undisturbed materials was comparable between the two measurement periods. Gaseous oxidized Hg (GOM) flux from these materials was quantified using an active filter sampling method that consisted of polysulfone cation-exchange membranes deployed in conjunction with the GEM flux apparatus. Initial measurements conducted within greenhouse laboratory space indicate that in dry conditions GOM is deposited to relatively low Hg cap and leach materials, but may be emitted from the much higher Hg concentration tailings material.

  6. Zero discharge performance of an industrial pilot-scale plant treating palm oil mill effluent.

    PubMed

    Wang, Jin; Mahmood, Qaisar; Qiu, Jiang-Ping; Li, Yin-Sheng; Chang, Yoon-Seong; Chi, Li-Na; Li, Xu-Dong

    2015-01-01

    Palm oil is one of the most important agroindustries in Malaysia. Huge quantities of palm oil mill effluent (POME) pose a great threat to aqueous environment due to its very high COD. To make full use of discharged wastes, the integrated "zero discharge" pilot-scale industrial plant comprising "pretreatment-anaerobic and aerobic process-membrane separation" was continuously operated for 1 year. After pretreatment in the oil separator tank, 55.6% of waste oil in raw POME could be recovered and sold and anaerobically digested through 2 AnaEG reactors followed by a dissolved air flotation (DAF); average COD reduced to about 3587 mg/L, and biogas production was 27.65 times POME injection which was used to generate electricity. The aerobic effluent was settled for 3 h or/and treated in MBR which could remove BOD3 (30°C) to less than 20 mg/L as required by Department of Environment of Malaysia. After filtration by UF and RO membrane, all organic compounds and most of the salts were removed; RO permeate could be reused as the boiler feed water. RO concentrate combined with anaerobic surplus sludge could be used as biofertilizer. PMID:25685798

  7. Large-Scale Selection and Breeding To Generate Industrial Yeasts with Superior Aroma Production

    PubMed Central

    Steensels, Jan; Meersman, Esther; Snoek, Tim; Saels, Veerle

    2014-01-01

    The concentrations and relative ratios of various aroma compounds produced by fermenting yeast cells are essential for the sensory quality of many fermented foods, including beer, bread, wine, and sake. Since the production of these aroma-active compounds varies highly among different yeast strains, careful selection of variants with optimal aromatic profiles is of crucial importance for a high-quality end product. This study evaluates the production of different aroma-active compounds in 301 different Saccharomyces cerevisiae, Saccharomyces paradoxus, and Saccharomyces pastorianus yeast strains. Our results show that the production of key aroma compounds like isoamyl acetate and ethyl acetate varies by an order of magnitude between natural yeasts, with the concentrations of some compounds showing significant positive correlation, whereas others vary independently. Targeted hybridization of some of the best aroma-producing strains yielded 46 intraspecific hybrids, of which some show a distinct heterosis (hybrid vigor) effect and produce up to 45% more isoamyl acetate than the best parental strains while retaining their overall fermentation performance. Together, our results demonstrate the potential of large-scale outbreeding to obtain superior industrial yeasts that are directly applicable for commercial use. PMID:25192996

  8. Industrial-scale proteomics: from liters of plasma to chemically synthesized proteins.

    PubMed

    Rose, Keith; Bougueleret, Lydie; Baussant, Thierry; Böhm, Günter; Botti, Paolo; Colinge, Jacques; Cusin, Isabelle; Gaertner, Hubert; Gleizes, Anne; Heller, Manfred; Jimenez, Silvia; Johnson, Andrew; Kussmann, Martin; Menin, Laure; Menzel, Christoph; Ranno, Frederic; Rodriguez-Tomé, Patricia; Rogers, John; Saudrais, Cedric; Villain, Matteo; Wetmore, Diana; Bairoch, Amos; Hochstrasser, Denis

    2004-07-01

    Human blood plasma is a useful source of proteins associated with both health and disease. Analysis of human blood plasma is a challenge due to the large number of peptides and proteins present and the very wide range of concentrations. In order to identify as many proteins as possible for subsequent comparative studies, we developed an industrial-scale (2.5 liter) approach involving sample pooling for the analysis of smaller proteins (M(r) generally < ca. 40 000 and some fragments of very large proteins). Plasma from healthy males was depleted of abundant proteins (albumin and IgG), then smaller proteins and polypeptides were separated into 12 960 fractions by chromatographic techniques. Analysis of proteins and polypeptides was performed by mass spectrometry prior to and after enzymatic digestion. Thousands of peptide identifications were made, permitting the identification of 502 different proteins and polypeptides from a single pool, 405 of which are listed here. The numbers refer to chromatographically separable polypeptide entities present prior to digestion. Combining results from studies with other plasma pools we have identified over 700 different proteins and polypeptides in plasma. Relatively low abundance proteins such as leptin and ghrelin and peptides such as bradykinin, all invisible to two-dimensional gel technology, were clearly identified. Proteins of interest were synthesized by chemical methods for bioassays. We believe that this is the first time that the small proteins in human blood plasma have been separated and analyzed so extensively. PMID:15221774

  9. Large-scale selection and breeding to generate industrial yeasts with superior aroma production.

    PubMed

    Steensels, Jan; Meersman, Esther; Snoek, Tim; Saels, Veerle; Verstrepen, Kevin J

    2014-11-01

    The concentrations and relative ratios of various aroma compounds produced by fermenting yeast cells are essential for the sensory quality of many fermented foods, including beer, bread, wine, and sake. Since the production of these aroma-active compounds varies highly among different yeast strains, careful selection of variants with optimal aromatic profiles is of crucial importance for a high-quality end product. This study evaluates the production of different aroma-active compounds in 301 different Saccharomyces cerevisiae, Saccharomyces paradoxus, and Saccharomyces pastorianus yeast strains. Our results show that the production of key aroma compounds like isoamyl acetate and ethyl acetate varies by an order of magnitude between natural yeasts, with the concentrations of some compounds showing significant positive correlation, whereas others vary independently. Targeted hybridization of some of the best aroma-producing strains yielded 46 intraspecific hybrids, of which some show a distinct heterosis (hybrid vigor) effect and produce up to 45% more isoamyl acetate than the best parental strains while retaining their overall fermentation performance. Together, our results demonstrate the potential of large-scale outbreeding to obtain superior industrial yeasts that are directly applicable for commercial use. PMID:25192996

  10. Application of ERTS-A imagery to fracture related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator)

    1973-01-01

    The author has identified the following significant results. The most important result to date is the demonstration of the special value of repetitive ERTS-1 multiband coverage for detecting previously unknown fracture lineaments despite the presence of a deep glacial overburden. The Illinois Basin is largely covered with glacial drift and few rock outcrops are present. A contribution to the geological understanding of Illinois and Indiana has been made. Analysis of ERTS-1 imagery has provided useful information to the State of Indiana concerning the surface mined lands. The contrast between healthy vegetation and bare ground as imaged by Band 7 is sharp and substantial detail can be obtained concerning the extent of disturbed lands, associated water bodies, large haul roads, and extent of mined lands revegetation. Preliminary results of analysis suggest a reasonable correlation between image-detected fractures and mine roof fall accidents for a few areas investigated. ERTS-1 applications to surface mining operations appear probable, but further investigations are required. The likelihood of applying ERTS-1 derived fracture data to improve coal mine safety in the entire Illinois Basin is suggested from studies conducted in Indiana.

  11. Co-firing of oil sludge with coal-water slurry in an industrial internal circulating fluidized bed boiler.

    PubMed

    Liu, Jianguo; Jiang, Xiumin; Zhou, Lingsheng; Wang, Hui; Han, Xiangxin

    2009-08-15

    Incineration has been proven to be an alternative for disposal of sludge with its unique characteristics to minimize the volume and recover energy. In this paper, a new fluidized bed (FB) incineration system for treating oil sludge is presented. Co-firing of oil sludge with coal-water slurry (CWS) was investigated in the new incineration system to study combustion characteristics, gaseous pollutant emissions and ash management. The study results show the co-firing of oil sludge with CWS in FB has good operating characteristic. CWS as an auxiliary fuel can flexibly control the dense bed temperatures by adjusting its feeding rate. All emissions met the local environmental requirements. The CO emission was less than 1 ppm or essentially zero; the emissions of SO(2) and NO(x) were 120-220 and 120-160 mg/Nm(3), respectively. The heavy metal analyses of the bottom ash and the fly ash by ICP/AES show that the combustion ashes could be recycled as soil for farming. PMID:19249155

  12. Industrial-scale radio frequency treatments for insect control in walnuts I. Heating uniformity and energy efficiency

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Conducting industrial-scale confirmatory treatments is the final step in developing commercially and environmentally sound insect control technologies for in-shell walnuts using radio frequency (RF) energy as an alternative to chemical fumigation. Improving heating uniformity of in-shell walnuts in ...

  13. Industrial Scale Isolation, Structural and Spectroscopic Characterization of Epiisopiloturine from Pilocarpus microphyllus Stapf Leaves: A Promising Alkaloid against Schistosomiasis

    PubMed Central

    Véras, Leiz M. C.; Cunha, Vanessa R. R.; Lima, Filipe C. D. A.; Guimarães, Maria A.; Vieira, Marianne M.; Campelo, Yuri D. M.; Sakai, Vanessa Y.; Lima, David F.; Carvalho Jr, Paulo S.; Ellena, Javier A.; Silva, Paulo R. P.; Vasconcelos, Luciene C.; Godejohann, Markus; Petrilli, Helena M.; Constantino, Vera R. L.; Mascarenhas, Yvonne P.; de Souza de Almeida Leite, José Roberto

    2013-01-01

    This paper presents an industrial scale process for extraction, purification, and isolation of epiisopiloturine (EPI) (2(3H)-Furanone,dihydro-3-(hydroxyphenylmethyl)-4-[(1-methyl-1H-imidazol-4-yl)methyl]-, [3S-[3a(R*),4b

  14. Industrial Scale Isolation, Structural and Spectroscopic Characterization of Epiisopiloturine from Pilocarpus microphyllus Stapf Leaves: A Promising Alkaloid against Schistosomiasis.

    PubMed

    Véras, Leiz M C; Cunha, Vanessa R R; Lima, Filipe C D A; Guimarães, Maria A; Vieira, Marianne M; Campelo, Yuri D M; Sakai, Vanessa Y; Lima, David F; Carvalho, Paulo S; Ellena, Javier A; Silva, Paulo R P; Vasconcelos, Luciene C; Godejohann, Markus; Petrilli, Helena M; Constantino, Vera R L; Mascarenhas, Yvonne P; de Souza de Almeida Leite, José Roberto

    2013-01-01

    This paper presents an industrial scale process for extraction, purification, and isolation of epiisopiloturine (EPI) (2(3H)-Furanone,dihydro-3-(hydroxyphenylmethyl)-4-[(1-methyl-1H-imidazol-4-yl)methyl]-, [3S-[3a(R*),4b

  15. Advantages of city-scale emission inventory for urban air quality research and policy: the case of Nanjing, a typical industrial city in the Yangtze River Delta, China

    NASA Astrophysics Data System (ADS)

    Zhao, Y.; Qiu, L.; Xu, R.; Xie, F.; Zhang, Q.; Yu, Y.; Nielsen, C. P.; Qin, H.; Wang, H.; Wu, X.; Li, W.; Zhang, J.

    2015-07-01

    With most eastern Chinese cities facing major air quality challenges, there is a strong need for city-scale emission inventories for use in both chemical transport modeling and the development of pollution control policies. In this paper, a high-resolution emission inventory of air pollutants and CO2 for Nanjing, a typical large city in the Yangtze River Delta, is developed incorporating the best available information on local sources. Emission factors and activity data at the unit or facility level are collected and compiled using a thorough onsite survey of major sources. Over 900 individual plants, which account for 97 % of the city's total coal consumption, are identified as point sources, and all of the emission-related parameters including combustion technology, fuel quality, and removal efficiency of air pollution control devices (APCD) are analyzed. New data-collection approaches including continuous emission monitoring systems and real-time monitoring of traffic flows are employed to improve spatiotemporal distribution of emissions. Despite fast growth of energy consumption between 2010 and 2012, relatively small inter-annual changes in emissions are found for most air pollutants during this period, attributed mainly to benefits of growing APCD deployment and the comparatively strong and improving regulatory oversight of the large point sources that dominate the levels and spatial distributions of Nanjing emissions overall. The improvement of this city-level emission inventory is indicated by comparisons with observations and other inventories at larger spatial scale. Relatively good spatial correlations are found for SO2, NOx, and CO between the city-scale emission estimates and concentrations at 9 state-opertated monitoring sites (R = 0.58, 0.46, and 0.61, respectively). The emission ratios of specific pollutants including BC to CO, OC to EC, and CO2 to CO compare well to top-down constraints from ground observations. The inter-annual variability and

  16. Full-scale laboratory simulation facility to test particulate and organic emissions from a Third World residential combustion process. III. Evaluation of a potential technique for the control of emissions from the indoor, open-hearth combustion of coal. Rept. for Jul 91-Feb 92

    SciTech Connect

    Lutes, C.C.; Ryan, J.V.; Harris, D.B.; Chapman, R.S.

    1992-01-01

    The paper reports controlled full-scale laboratory studies designed to determine if clay addition holds promise as a technique to control emissions from higher grade coals. (NOTE: Abnormally high rates of lung cancer are observed among persons in Xuan Wei County, China, who burn bituminous 'smoky' coal as compared with those who burn 'smokeless' coal, which is produced by mixing low grade coals with clay.) Statistically significant reductions in emissions of total particulate (70%), gravimetrically determined (nonvolatile) organics (70%), total chromatographable (semivolatile) organics (90%), and benzo(a)pyrene (65%) were observed (measured on a mass emitted/mass coal combusted basis) when clay binder material was added to a ground smoky coal. These reductions, however, did not fully account for the order of magnitude lower pollutant levels previously observed in homes burning smokeless (as compared to smoky) coal. Thus, the authors believe that the composition of the low rank coals used to produce smokeless coal also helps to control emissions.

  17. Review of a Proposed Quarterly Coal Publication

    SciTech Connect

    Not Available

    1981-01-01

    This Review of a Proposed Quartery Coal Publication contains findings and recommendations regarding the content of a new summary Energy Information Administration (EIA) coal and coke publication entitled The Quarterly Coal Review (QCR). It is divided into five sections: results of interviews with selected EIA data users; identification of major functions of the coal and coke industries; analysis of coal and coke data collection activities; evaluation of issues conerning data presentation including recommendations for the content of the proposed QCR; and comparison of the proposed QCR with other EIA publications. Major findings and recommendations are as follows: (1) User interviews indicate a definite need for a compehensive publication that would support analyses and examine economic, supply and demand trends in the coal industry; (2) the organization of the publication should reflect the natural order of activities of the coal and coke industries. Based on an analysis of the industries, these functions are: production, stocks, imports, exports, distribution, and consumption; (3) current EIA coal and coke surveys collect sufficient data to provide a summary of the coal and coke industries on a quarterly basis; (4) coal and coke data should be presented separately. Coke data could be presented as an appendix; (5) three geographic aggregations are recommended in the QCR. These are: US total, coal producing districts, and state; (6) coal consumption data should be consolidated into four major consumer categories: electric utilities, coke plants, other industrial, and residential commercial; (7) several EIA publications could be eliminated by the proposed QCR.

  18. Study of application of ERTS-A imagery to fracture related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.

    1973-01-01

    The author has identified the following significant results. The utility of ERTS-1/high altitude aircraft imagery to detect underground mine hazards is strongly suggested. A 1:250,000 scale mined lands map of the Vincennes Quadrangle, Indiana has been prepared. This map is a prototype for a national mined lands inventory and will be distributed to State and Federal offices.

  19. Coal-fueled diesels for modular power generation

    SciTech Connect

    Wilson, R.P.; Rao, A.K.; Smith, W.C.

    1993-11-01

    Interest in coal-fueled heat engines revived after the sharp increase in the prices of natural gas and petroleum in the 1970`s. Based on the success of micronized coal water slurry combustion tests in an engine in the 1980`s, Morgantown Energy Technology Center (METC) of the US Department of Energy. initiated several programs for the development of advanced coal-fueled diesel and gas turbine engines for use in cogeneration, small utilities, industrial applications and transportation. Cooper-Bessemer and Arthur D. Little have been developing technology since 1985, under the sponsor of METC, to enable coal water slurry (CWS) to be utilized in large bore, medium-speed diesel engines. Modular power generation applications in the 10--100 MW size (each plant typically using from two to eight engines) are the target applications for the late 1990`s and beyond when, according to the US DOE and other projections, oil and natural gas prices are expected to escalate much more rapidly compared to the price of coal. As part of this program over 7.50 hours of prototype engine operation has been achieved on coal water slurry (CWS), including over 100 hours operation of a six-cylinder full scale engine with Integrated Emissions Control System in 1993. In this paper, the authors described the project cost of the CWS fuel used, the heat rate of the engine operating on CWS, the projected maintenance cost for various engine components, and the demonstrated low emissions characteristics of the coal diesel system.

  20. Development of an Ultra-fine Coal Dewatering Technology and an Integrated Flotation-Dewatering System for Coal Preparation Plants

    SciTech Connect

    Wu Zhang; David Yang; Amar Amarnath; Iftikhar Huq; Scott O'Brien; Jim Williams

    2006-12-22

    The project proposal was approved for only the phase I period. The goal for this Phase I project was to develop an industrial model that can perform continuous and efficient dewatering of fine coal slurries of the previous flotation process to fine coal cake of {approx}15% water content from 50-70%. The feasibility of this model should be demonstrated experimentally using a lab scale setup. The Phase I project was originally for one year, from May 2005 to May 2006. With DOE approval, the project was extended to Dec. 2006 without additional cost from DOE to accomplish the work. Water has been used in mining for a number of purposes such as a carrier, washing liquid, dust-catching media, fire-retardation media, temperature-control media, and solvent. When coal is cleaned in wet-processing circuits, waste streams containing water, fine coal, and noncombustible particles (ash-forming minerals) are produced. In many coal preparation plants, the fine waste stream is fed into a series of selection processes where fine coal particles are recovered from the mixture to form diluted coal fine slurries. A dewatering process is then needed to reduce the water content to about 15%-20% so that the product is marketable. However, in the dewatering process currently used in coal preparation plants, coal fines smaller than 45 micrometers are lost, and in many other plants, coal fines up to 100 micrometers are also wasted. These not-recovered coal fines are mixed with water and mineral particles of the similar particle size range and discharged to impoundment. The wasted water from coal preparation plants containing unrecoverable coal fine and mineral particles are called tailings. With time the amount of wastewater accumulates occupying vast land space while it appears as threat to the environment. This project developed a special extruder and demonstrated its application in solid-liquid separation of coal slurry, tailings containing coal fines mostly less than 50 micron. The

  1. Application of Pulse Spark Discharges for Scale Prevention and Continuous Filtration Methods in Coal-Fired Power Plant

    SciTech Connect

    Cho, Young; Fridman, Alexander

    2012-06-30

    The overall objective of the present work was to develop a new scale-prevention technology by continuously precipitating and removing dissolved mineral ions (such as calcium and magnesium) in cooling water while the COC could be doubled from the present standard value of 3.5. The hypothesis of the present study was that if we could successfully precipitate and remove the excess calcium ions in cooling water, we could prevent condenser-tube fouling and at the same time double the COC. The approach in the study was to utilize pulse spark discharges directly in water to precipitate dissolved mineral ions in recirculating cooling water into relatively large suspended particles, which could be removed by a self-cleaning filter. The present study began with a basic scientific research to better understand the mechanism of pulse spark discharges in water and conducted a series of validation experiments using hard water in a laboratory cooling tower. Task 1 of the present work was to demonstrate if the spark discharge could precipitate the mineral ions in water. Task 2 was to demonstrate if the selfcleaning filter could continuously remove these precipitated calcium particles such that the blowdown could be eliminated or significantly reduced. Task 3 was to demonstrate if the scale could be prevented or minimized at condenser tubes with a COC of 8 or (almost) zero blowdown. In Task 1, we successfully completed the validation study that confirmed the precipitation of dissolved calcium ions in cooling water with the supporting data of calcium hardness over time as measured by a calcium ion probe. In Task 2, we confirmed through experimental tests that the self-cleaning filter could continuously remove precipitated calcium particles in a simulated laboratory cooling tower such that the blowdown could be eliminated or significantly reduced. In addition, chemical water analysis data were obtained which were used to confirm the COC calculation. In Task 3, we conducted a series

  2. Investigation of industrial-scale carbon dioxide reduction using pulsed electron beams

    NASA Astrophysics Data System (ADS)

    Petrov, G. M.; Apruzese, J. P.; Petrova, Tz. B.; Wolford, M. F.

    2016-03-01

    Carbon dioxide is the most important greenhouse gas contributing to global warming. To help mitigate increasing CO2 concentrations, we investigate a method of carbon dioxide reduction using high-power electron beams, which can be used on an industrial scale. A series of experiments are conducted in which the reduction of CO2 is measured for different gas compositions and power deposition rates. An electron beam deposition model is applied to compute reduction rates of CO2 and energy cost for breaking a CO2 molecule in flue gas and pure carbon dioxide at atmospheric pressure. For flue gas consisting of 82% N2, 6% O2, and 12% CO2, the calculated energy cost is 85 eV per molecule. In order to dissociate 50% of the CO2 molecules, beam energy density deposition on the order of 20 J/cm3 is required. Electron beam irradiation of 12.6 liter gas volume containing 90% CO2 and 10% CH4 at beam energy density deposition of 4.2 J/cm3, accumulated over 43 shots in a 20 min interval, reduced the CO2 concentration to 78%. Analogous experiments with a gas mixture containing 11.5% CO2, 11.5% CH4, and balance of Ar, reduced the CO2 concentration to below 11% with energy deposition 0.71 J/cm3, accumulated over 10 shots in a 5 min interval. The experimental data and the theoretical predictions of CO2 reduction using pulsed electron beams are in agreement within the experimental error. Other techniques to enhance the removal of CO2 with pulsed electron beams are also explored, yielding new possible avenues of research.

  3. Environmental studies of materials from the H-coal liquefaction process development unit

    SciTech Connect

    Cada, G.F.

    1982-12-01

    H-coal is a process for the direct liquefaction of coal to produce synthetic fuels. Its development has progressed from bench-scale testing through operation of a 2.7 Mg/d (3 ton/d) Process Development Unit. A large-scale H-Coal pilot plant is presently operating at Catlettsburg, Kentucky, and there are plans for the construction of a commercial H-Coal liquefaction facility by the end of the decade. Two of the environmental concerns of the developing direct coal liquefaction industry are accidental spills of synthetic oils and treatment/storage of solid wastes. As a means of obtaining preliminary information on the severity of these potential impacts well in advance of commercialization, samples of product oils and solid wastes were obtained from the H-Coal Process Development Unit (PDU). These samples were subjected to a battery of rapid screening tests, including chemical characterization and bioassays with a variety of aquatic and terrestrial organisms. Water-soluble fraction (WSFs) of H-Coal PDU oils had considerably higher concentrations of phenols and anilines and were commonly one to two orders of magnitude more toxic to aquatic organisms than WSFs of analogous petroleum crude oil. Whole H-Coal PDU oils were also more toxic to the cricket than petroleum-based oils, and some H-Coal samples showed evidence of teratogenicity. Leachates from H-Coal PDU solid wastes, on the other hand, had relatively low concentrations of selected elements and had essentially no acute toxicity to a variety of aquatic and terrestrial species. These studies indicate that environmental effects of product oil spills from a commercial H-Coal liquefaction plant are likely to be more severe than those of conventional petroleum spills. Product upgrading or special transportation and storage techniques may be needed to ensure environmentally sound commercialization of the H-Coal process.

  4. Non-contact multi-frequency magnetic induction spectroscopy system for industrial-scale bio-impedance measurement

    NASA Astrophysics Data System (ADS)

    O'Toole, M. D.; Marsh, L. A.; Davidson, J. L.; Tan, Y. M.; Armitage, D. W.; Peyton, A. J.

    2015-03-01

    Biological tissues have a complex impedance, or bio-impedance, profile which changes with respect to frequency. This is caused by dispersion mechanisms which govern how the electromagnetic field interacts with the tissue at the cellular and molecular level. Measuring the bio-impedance spectra of a biological sample can potentially provide insight into the sample’s properties and its cellular structure. This has obvious applications in the medical, pharmaceutical and food-based industrial domains. However, measuring the bio-impedance spectra non-destructively and in a way which is practical at an industrial scale presents substantial challenges. The low conductivity of the sample requires a highly sensitive instrument, while the demands of industrial-scale operation require a fast high-throughput sensor of rugged design. In this paper, we describe a multi-frequency magnetic induction spectroscopy (MIS) system suitable for industrial-scale, non-contact, spectroscopic bio-impedance measurement over a bandwidth of 156 kHz-2.5 MHz. The system sensitivity and performance are investigated using calibration and known reference samples. It is shown to yield rapid and consistently sensitive results with good long-term stability. The system is then used to obtain conductivity spectra of a number of biological test samples, including yeast suspensions of varying concentration and a range of agricultural produce, such as apples, pears, nectarines, kiwis, potatoes, oranges and tomatoes.

  5. LIBS Analysis for Coal

    NASA Astrophysics Data System (ADS)

    E. Romero, Carlos; De Saro, Robert

    Coal is a non-uniform material with large inherent variability in composition, and other important properties, such as calorific value and ash fusion temperature. This quality variability is very important when coal is used as fuel in steam generators, since it affects boiler operation and control, maintenance and availability, and the extent and treatment of environmental pollution associated with coal combustion. On-line/in situ monitoring of coal before is fed into a boiler is a necessity. A very few analytical techniques like X-ray fluorescence and prompt gamma neutron activation analysis are available commercially with enough speed and sophistication of data collection for continuous coal monitoring. However, there is still a need for a better on-line/in situ technique that has higher selectivity, sensitivity, accuracy and precision, and that is safer and has a lower installation and operating costs than the other options. Laser induced breakdown spectroscopy (LIBS) is ideal for coal monitoring in boiler applications as it need no sample preparation, it is accurate and precise it is fast, and it can detect all of the elements of concern to the coal-fired boiler industry. LIBS data can also be adapted with advanced data processing techniques to provide real-time information required by boiler operators nowadays. This chapter summarizes development of LIBS for on-line/in situ coal applications in utility boilers.

  6. Villacidro solar demo plant: Integration of small-scale CSP and biogas power plants in an industrial microgrid

    NASA Astrophysics Data System (ADS)

    Camerada, M.; Cau, G.; Cocco, D.; Damiano, A.; Demontis, V.; Melis, T.; Musio, M.

    2016-05-01

    The integration of small scale concentrating solar power (CSP) in an industrial district, in order to develop a microgrid fully supplied by renewable energy sources, is presented in this paper. The plant aims to assess in real operating conditions, the performance, the effectiveness and the reliability of small-scale concentrating solar power technologies in the field of distributed generation. In particular, the potentiality of small scale CSP with thermal storage to supply dispatchable electricity to an industrial microgrid will be investigated. The microgrid will be realized in the municipal waste treatment plant of the Industrial Consortium of Villacidro, in southern Sardinia (Italy), which already includes a biogas power plant. In order to achieve the microgrid instantaneous energy balance, the analysis of the time evolution of the waste treatment plant demand and of the generation in the existing power systems has been carried out. This has allowed the design of a suitable CSP plant with thermal storage and an electrochemical storage system for supporting the proposed microgrid. At the aim of obtaining the expected energy autonomy, a specific Energy Management Strategy, which takes into account the different dynamic performances and characteristics of the demand and the generation, has been designed. In this paper, the configuration of the proposed small scale concentrating solar power (CSP) and of its thermal energy storage, based on thermocline principle, is initially described. Finally, a simulation study of the entire power system, imposing scheduled profiles based on weather forecasts, is presented.

  7. Development of an advanced high efficiency coal combustor for boiler retrofit

    SciTech Connect

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.

    1989-10-01

    The overall objective of this program is to develop a high efficiency advanced coal combustor (HEACC) for coal-based fuels capable of being retrofitted to industrial boilers originally designed for firing natural gas, distillate, and/or residual oil. The HEACC system is to be capable of firing microfine coal water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system are that it be simple to operate and will offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal fired combustor technology. The specific objective of this report is to document the work carried out under Task 1.0 of this contract, Cold Flow Burner Development''. As are detailed in the report, key elements of this work included primary air swirler development, burner register geometry design, cold flow burner model testing, and development of burner scale up criteria.

  8. Coal Research

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Coal slurries are "clean" pulverized coal mixed with oil or water. Significant fuel savings can be realized when using coal slurries. Advanced Fuels Technology (AFT) utilized a COSMIC program, (Calculation of Complex Chemical Equilibrium Compositions), which provides specific capabilities for determining combustion products. The company has developed a cleaning process that removes much of the mineral sulphur and ash from the coals.

  9. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor

    SciTech Connect

    Yan Cao; Hongcang Zhou; Junjie Fan; Houyin Zhao; Tuo Zhou; Pauline Hack; Chia-Chun Chan; Jian-Chang Liou; Wei-ping Pan

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150{sup o}C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650{sup o}C in the upper part of the fluidized bed combustor seemed to be responsible for the reduction of gaseous chlorine and, consequently, limited mercury emissions reduction during cofiring. 36 refs., 3 figs. 1 tab.

  10. Thermobaric investigations of coal mixtures

    SciTech Connect

    Kosinskii, V.A.

    1983-01-01

    The dynamics of the evolution of gas when coals of various types from the Donbass and binary and ternary mixtures of them are heated have been studied. The discrete nature of the evolution of gas has been established, the temperature intervals of which depend primarily on the ratio of the coals in the mixtures. The possibility of using the results obtained in determining rational schemes for the industrial processing of coals is suggested.

  11. New developments in coal briquetting technology

    SciTech Connect

    Tucker, P.V.; Bosworth, G.B.; Kalb, G.W.

    1993-12-31

    Briquetting of coal has been with us for well over a century. In the earliest applications of coal briquetting, less valuable fine coal was agglomerated into briquettes using a wide variety of binders, including coal tar, pitch and asphalt. Eventually, roll briquetters came into more widespread use, permitting the process to become a continuous one. Coal briquetting went out of favor during the 1950s in most of the industrialized world. The major reason for this decline in use was the discovery that the coal gas distillates used for binders were harmful to human health. Also, the abundance of cheap petroleum made coal briquettes a less attractive alternative as an industrial or domestic fuel. The re-emergence of coal as a primary industrial fuel and also its increased prominence as a fuel for thermal electric power stations led to a large increase in the annual volume of coal being mined worldwide. Coal preparation technology steadily improved over the years with the general exception of fine coal preparation. The processes available for treating this size range were considerably more expensive per unit mass of coal treated than coarse coal processes. Also, costly dewatering equipment was required after cleaning to remove surface moisture. Even with dewatering, the high surface area per unit mass of fine coal versus coarse coal resulted in high moisture contents. Therefore, little incentive existed to improve the performance of fine coal processes since this would only increase the amount of wet coal fines which would have to be dealt with. With such an ever-increasing volume of coal fines being created each year, there emerged an interest in recovering this valuable product. Several schemes were developed to recover coal fines discarded in abandoned tailings impoundments by previous operations.

  12. Coals of the Brazil Formation (Pennsylvanian) in Indiana: Observations of correlation inconsistencies and their implications

    USGS Publications Warehouse

    Mastalerz, Maria; Ames, P.R.; Padgett, P.L.

    2003-01-01

    The coals of the upper part of the Mansfield, Brazil, and the lower part of the Staunton Formations (Atokan and Desmoinesian, Pennsylvanian) in Indiana (Illinois Basin) are characteristically thin and discontinuous. As a result, problems with correlation and identification of the seams have persisted for both researchers and industry. These discrepancies affect coal exploration, mine planning, and subsequently coal-fired utilities. This study presents exploration and operational examples demonstrating some of the correlation problems associated with the coals of the Brazil Formation, and the Upper Block and Lower Block, in particular, and the surrounding upper part of the Mansfield Formation and lower part of the Staunton Formations. Based on exploration boreholes, mine scale observations, and coal quality and petrographic data, this study suggests that (1) the coal mapped as the Upper Block Coal Member of Clay County may, in fact, be the same seam as the Lower Block Coal Member of Daviess County; and (2) the Lower Block coal of Clay County is not present south of the Switz City area of central Greene County, IN. ?? 2003 Elsevier Science B.V. All rights reserved.

  13. Comparing Antonovsky's sense of coherence scale across three UK post-industrial cities

    PubMed Central

    Walsh, David; McCartney, Gerry; McCullough, Sarah; Buchanan, Duncan; Jones, Russell

    2014-01-01

    Objectives High levels of ‘excess’ mortality (ie, that seemingly not explained by deprivation) have been shown for Scotland compared to England and Wales and, especially, for its largest city, Glasgow, compared to the similarly deprived English cities of Liverpool and Manchester. It has been suggested that this excess may be related to differences in ‘Sense of Coherence’ (SoC) between the populations. The aim of this study was to ascertain whether levels of SoC differed between these cities and whether, therefore, this could be a plausible explanation for the ‘excess’. Setting Three post-industrial UK cities: Glasgow, Liverpool and Manchester. Participants A representative sample of more than 3700 adults (over 1200 in each city). Primary and secondary outcome measures SoC was measured using Antonovsky's 13-item scale (SOC-13). Multivariate linear regression was used to compare SoC between the cities while controlling for characteristics (age, gender, SES etc) of the samples. Additional modelling explored whether differences in SoC moderated city differences in levels of self-assessed health (SAH). Results SoC was higher, not lower, among the Glasgow sample. Fully adjusted mean SoC scores for residents of Liverpool and Manchester were, respectively, 5.1 (−5.1 (95% CI −6.0 to −4.1)) and 8.1 (−8.1 (−9.1 to −7.2)) lower than those in Glasgow. The additional modelling confirmed the relationship between SoC and SAH: a 1 unit increase in SoC predicted approximately 3% lower likelihood of reporting bad/very bad health (OR=0.97 (95% CI 0.96 to 0.98)): given the slightly worse SAH in Glasgow, this resulted in slightly lower odds of reporting bad/very bad health for the Liverpool and Manchester samples compared to Glasgow. Conclusions The reasons for the high levels of ‘excess’ mortality seen in Scotland and particularly Glasgow remain unclear. However, on the basis of these analyses, it appears unlikely that a low SoC provides any explanation

  14. Coal-to-liquids: Potential impact on U.S. coal reserves

    USGS Publications Warehouse

    Milici, R.C.

    2009-01-01

    The production of liquid fuels from coal will very likely become an important part of the hydrocarbon energy mix of the future, provided that technical and environmental obstacles are overcome economically. The coal industry should be able to handle a coal-to-liquids (CTL) industry of modest size, using 60-70 million short tons or 54-64 million metric tonnes of coal per annum, without premature depletion of the country's coal reserves. However, attempts to use CTL technology to replace all petroleum imports would deplete the nation's coal reserves by the end of the century. ?? 2009 U.S. Government.

  15. Curbing variations in packaging process through Six Sigma way in a large-scale food-processing industry

    NASA Astrophysics Data System (ADS)

    Desai, Darshak A.; Kotadiya, Parth; Makwana, Nikheel; Patel, Sonalinkumar

    2015-08-01

    Indian industries need overall operational excellence for sustainable profitability and growth in the present age of global competitiveness. Among different quality and productivity improvement techniques, Six Sigma has emerged as one of the most effective breakthrough improvement strategies. Though Indian industries are exploring this improvement methodology to their advantage and reaping the benefits, not much has been presented and published regarding experience of Six Sigma in the food-processing industries. This paper is an effort to exemplify the application of Six Sigma quality improvement drive to one of the large-scale food-processing sectors in India. The paper discusses the phase wiz implementation of define, measure, analyze, improve, and control (DMAIC) on one of the chronic problems, variations in the weight of milk powder pouch. The paper wraps up with the improvements achieved and projected bottom-line gain to the unit by application of Six Sigma methodology.

  16. Clean Coal Technology Demonstration Program. Program update 1994

    SciTech Connect

    1995-04-01

    The Clean Coal Technology Demonstration Program (CCT Program) is a $7.14 billion cost-shared industry/government technology development effort. The program is to demonstrate a new generation of advanced coal-based technologies, with the most promising technologies being moved into the domestic and international marketplace. Clean coal technologies being demonstrated under the CCT program are creating the technology base that allows the nation to meet its energy and environmental goals efficiently and reliably. The fact that most of the demonstrations are being conducted at commercial scale, in actual user environments, and under conditions typical of commercial operations allows the potential of the technologies to be evaluated in their intended commercial applications. The technologies are categorized into four market sectors: advanced electric power generation systems; environmental control devices; coal processing equipment for clean fuels; and industrial technologies. Sections of this report describe the following: Role of the Program; Program implementation; Funding and costs; The road to commercial realization; Results from completed projects; Results and accomplishments from ongoing projects; and Project fact sheets. Projects include fluidized-bed combustion, integrated gasification combined-cycle power plants, advanced combustion and heat engines, nitrogen oxide control technologies, sulfur dioxide control technologies, combined SO{sub 2} and NO{sub x} technologies, coal preparation techniques, mild gasification, and indirect liquefaction. Industrial applications include injection systems for blast furnaces, coke oven gas cleaning systems, power generation from coal/ore reduction, a cyclone combustor with S, N, and ash control, cement kiln flue gas scrubber, and pulse combustion for steam coal gasification.

  17. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor.

    PubMed

    Cao, Yan; Zhou, Hongcang; Fan, Junjie; Zhao, Houyin; Zhou, Tuo; Hack, Pauline; Chan, Chia-Chun; Liou, Jian-Chang; Pan, Wei-Ping

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150 degrees C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. This was also true when limestone was added while cofiring coal and chicken waste because the gaseous chlorine was reduced in the freeboard of the fluidized bed combustor, where the temperature was generally below 650 degrees C without addition of the secondary air. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650 degrees C in the upper part of the fluidized bed combustor seemed to be

  18. SULFUR RETENTION IN COAL ASH

    EPA Science Inventory

    The report gives results of an analytical study to assess the potential for sulfur retention in various types of coal-fired boilers. Results of a field test of 10 industrial coal-fired boilers were used to evaluate the impact on sulfur retention of the operating variables (load a...

  19. The ENCOAL Mild Coal Gasification Project, A DOE Assessment

    SciTech Connect

    National Energy Technology Laboratory

    2002-03-15

    This report is a post-project assessment of the ENCOAL{reg_sign} Mild Coal Gasification Project, which was selected under Round III of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Demonstration Program. The CCT Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of commercial-scale facilities. The ENCOAL{reg_sign} Corporation, a wholly-owned subsidiary of Bluegrass Coal Development Company (formerly SMC Mining Company), which is a subsidiary of Ziegler Coal Holding Company, submitted an application to the DOE in August 1989, soliciting joint funding of the project in the third round of the CCT Program. The project was selected by DOE in December 1989, and the Cooperative Agreement (CA) was approved in September 1990. Construction, commissioning, and start-up of the ENCOAL{reg_sign} mild coal gasification facility was completed in June 1992. In October 1994, ENCOAL{reg_sign} was granted a two-year extension of the CA with the DOE, that carried through to September 17, 1996. ENCOAL{reg_sign} was then granted a six-month, no-cost extension through March 17, 1997. Overall, DOE provided 50 percent of the total project cost of $90,664,000. ENCOAL{reg_sign} operated the 1,000-ton-per-day mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming, for over four years. The process, using Liquids From Coal (LFC{trademark}) technology originally developed by SMC Mining Company and SGI International, utilizes low-sulfur Powder River Basin (PRB) coal to produce two new fuels, Process-Derived Fuel (PDF{trademark}) and Coal-Derived Liquids (CDL{trademark}). The products, as alternative fuel sources, are capable of significantly lowering current sulfur emissions at industrial and utility boiler sites throughout the nation thus reducing pollutants causing acid rain. In support of this overall objective

  20. Combustion and fuel characterization of coal-water fuels

    SciTech Connect

    Chow, O.K.; Gralton, G.W.; Lachowicz, Y.V.; Laflesh, R.C.; Levasseur, A.A.; Liljedahl, G.N.

    1989-02-01

    This five-year research project was established to provide sufficient data on coal-water fuel (CWF) chemical, physical, and combustion properties to assess the potential for commercial firing in furnaces designed for gas or oil firing. Extensive laboratory testing was performed at bench-scale, pilot-scale (4 {times} 10{sup 6}Btu/hr) and commercial-scale (25 {times} 10{sup 6} to 50 {times} 10{sup 6}Btu/hr) on a cross-section of CWFs. Fuel performance characteristics were assessed with respect to coal properties, level of coal beneficiation, and slurry formulation. The performance of four generic burner designs was also assessed. Boiler performance design models were applied to analyze the impacts associated with conversion of seven different generic unit designs to CWF firing. Equipment modifications, operating limitations, and retrofit costs were determined for each design when utilizing several CWFs. Unit performance analyses showed significantly better load capacity for utility and industrial boilers as the CWF feed coal ash content is reduced to 5% or 2.6%. In general, utility units had more attractive capacity limits and retrofit costs than the industrial boilers and process heaters studied. Economic analyses indicated that conversion to CWF firing generally becomes feasible when differential fuel costs are above $1.00/10{sup 6}Btu. 60 figs., 24 tabs.

  1. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and

  2. Coal-based synthetic asphalts

    SciTech Connect

    Kang, J.H.

    1986-01-01

    The study investigated the technical and economic feasibility of producing a specification-grade, local-based asphalt from a raw coal available in the United States. Bench-scale hydrogenation experiments were performed in a one-gallon autoclave to produce asphalts from Illinois No. 6 bituminous coal and Clovis Point subbituminous coal. Samples from the process streams of a continuous coal liquefaction pilot plant at Wilsonville, AL were also evaluated to determine the potential for making a paving asphalt. The results showed that coal-based asphalts have a higher age-hardening rate than petroleum asphalts; also, they have a higher viscosity-temperature susceptibility (VTS) number. The high age-hardening rate of coal-based asphalts could be offset satisfactorily via catalytic hydrogenation. The VTS of these asphalts could be markedly reduced by adding a certain amount of styrene/butadiene copolymer. As a result, a specification grade, coal-based asphalt was successfully made via catalytic hydrogenation of coal combined with the incorporation of ca. 3 wt% styrene/butadiene copolymer into the coal-based asphalt. Marshall stability testing showed that coal based asphalt/aggregate compacted mixes had excellent resistance to plastic flow. Immersion compression testing revealed that the compacted mixes had a high initial compression strength and retained strength. A two-stage coal-based asphalt process was designed for producing 1000 tons/day. Economic analyses showed that the coal-based asphalt would be more expensive than currently used petroleum asphalt.

  3. Coal mine directory: United States and Canada

    SciTech Connect

    2004-07-01

    The directory gives a state-by-state listing of all US and Canadian coal producers. It contains contact information as well as the type of mine, production statistics, coal composition, transportation methods etc. A statistical section provides general information about the US coal industry, preparation plants, and longwall mining operations.

  4. Connect the Spheres with the Coal Cycle

    ERIC Educational Resources Information Center

    Clary, Renee; Wandersee, James

    2010-01-01

    Coal fueled the Industrial Revolution and, as a result, changed the course of human history. However, the geologic history of coal is much, much longer than that which is recorded by humans. In your classroom, the coal cycle can be used to trace the formation of this important economic resource from its plant origins, through its lithification, or…

  5. Combustion of black coal in the form of coal-water slurry in low-capacity boilers

    NASA Astrophysics Data System (ADS)

    Maltsev, L. I.; Kravchenko, I. V.; Lazarev, S. I.; Lapin, D. A.

    2014-07-01

    The present paper describes the examples of experimental and industrial implementation of technologies of flame-droplet combustion of the coal-water mixture in furnaces above a bed consisting of burning coal and in a swirling-type furnace chamber. For preparing coal-water fuel (CWF), Kuznetsk coals of G and D ranks, as well as tailings of coking coals, were used. The future prospect of both technologies of coal combustion has been shown from both economic and environmental standpoints.

  6. W versus Co-Al as Gate Fill-Metal for Aggressively Scaled Replacement High-k/Metal Gate Devices for (Sub-)22 nm Technology Nodes

    NASA Astrophysics Data System (ADS)

    Veloso, Anabela; Aik Chew, Soon; Schram, Tom; Dekkers, Harold; Van Ammel, Annemie; Witters, Thomas; Tielens, Hilde; Heylen, Nancy; Devriendt, Katia; Sebaai, Farid; Brus, Stephan; Ragnarsson, Lars-Åke; Pantisano, Luigi; Eneman, Geert; Carbonell, Laure; Richard, Olivier; Favia, Paola; Geypen, Jef; Bender, Hugo; Higuchi, Yuichi; Phatak, Anup; Thean, Aaron; Horiguchi, Naoto

    2013-04-01

    In this work we provide a comprehensive evaluation of a novel, low-resistance Co-Al alloy vs W to fill aggressively scaled gates with high aspect-ratios [gate height (Hgate) ˜50-60 nm, gate length (Lgate) ≥20-25 nm]. We demonstrate that, with careful liner/barrier materials selection and tuning, well-behaved devices are obtained, showing: tight gate resistance (Rgate) distributions down to Lgate˜20 nm, low threshold voltage (VT) values, comparable DC and bias temperature instability (BTI) behavior, and improved RF response. The impact of fill-metals intrinsic stress, including the presence of occasional voids in narrow W-gates, on devices fabrication and performance is also explored.

  7. National Coal Quality Inventory (NACQI)

    SciTech Connect

    Robert Finkelman

    2005-09-30

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  8. Semiconductor Nanocrystal Quantum Dot Synthesis Approaches Towards Large-Scale Industrial Production for Energy Applications

    NASA Astrophysics Data System (ADS)

    Hu, Michael Z.; Zhu, Ting

    2015-12-01

    This paper reviews the experimental synthesis and engineering developments that focused on various green approaches and large-scale process production routes for quantum dots. Fundamental process engineering principles were illustrated. In relation to the small-scale hot injection method, our discussions focus on the non-injection route that could be scaled up with engineering stir-tank reactors. In addition, applications that demand to utilize quantum dots as "commodity" chemicals are discussed, including solar cells and solid-state lightings.

  9. Designing Clothing for Coal Miners

    ERIC Educational Resources Information Center

    Watkins, Susan M.

    1977-01-01

    Describes procedures taken by apparel design students, working in an industrial setting, in designing functional clothing for coal miners as part of the Armco Steel Corporation's Student Design Program. (TA)

  10. Quarterly coal report

    SciTech Connect

    Young, P.

    1996-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  11. Novel single stripper with side-draw to remove ammonia and sour gas simultaneously for coal-gasification wastewater treatment and the industrial implementation

    SciTech Connect

    Feng, D.C.; Yu, Z.J.; Chen, Y.; Qian, Y.

    2009-06-15

    A large amount of wastewater is produced in the Lurgi coal-gasification process with the complex compounds carbon dioxide, ammonia, phenol, etc., which cause a serious environmental problem. In this paper, a novel stripper operated at elevated pressure is designed to improve the pretreatment process. In this technology, two noticeable improvements were established. First, the carbon dioxide and ammonia were removed simultaneously in a single stripper where sour gas (mainly carbon dioxide) is removed from the tower top and the ammonia vapor is drawn from the side and recovered by partial condensation. Second, the ammonia is removed before the phenol recovery to reduce the pH value of the subsequent extraction units, so as the phenol removal performance of the extraction is greatly improved. To ensure the operational efficiency, some key operational parameters are analyzed and optimized though simulation. It is shown that when the top temperature is kept at 40 C and the weight ratio of the side draw to the feed is above 9%, the elevated pressures can ensure the removal efficiency of NH{sub 3} and carbon dioxide and the desired purified water as the bottom product of the unit is obtained. A real industrial application demonstrates the attractiveness of the new technique: it removes 99.9% CO{sub 2} and 99.6% ammonia, compared to known techniques which remove 66.5% and 94.4%, respectively. As a result, the pH value of the wastewater is reduced from above 9 to below 7. This ensures that the phenol removal ratio is above 93% in the following extraction units. The operating cost is lower than that of known techniques, and the operation is simplified.

  12. Fieldston coal transportation manual, 1991

    SciTech Connect

    Not Available

    1991-01-01

    This book reports on coal production and movements contains up-to-day statistics and analysis of the coal transportation industry. It contains railroad rates and tonnages hauled, along with the contracting point. Rail systems and mine origin maps for traffic analysis are also included. The book also covers coal transfer points on inland waterways, transfer capabilities, coal hauling barge lines in 1988, 1989, and 1990, spot barge rates and key contacts. Details of US and Canadian ports, Great Lakes docks and foreign ocean docks are listed. Port loading statistics, ocean shipping rates, port authorities and listings are given along with regional maps of rail lines and schematic drawings of loading facilities.

  13. FULL-SCALE LABORATORY SIMULATION FACILITY TO TEST PARTICULATE AND ORGANIC EMISSIONS FROM A THIRD WORLD RESIDENTIAL COMBUSTION PROCESS. III. EVALUATIO OF A POTENTIAL TECHNIQUE FOR THE CONTROL OF EMISSIONS FROM THE INDOOR, OPEN HEARTH COMBUSTION OF COAL

    EPA Science Inventory

    The paper reports controlled full-scale laboratory studies designed to determine if clay addition holds promise as a technique to control emissions from higher grade coals. NOTE: bnormally high rates of lung cancer are observed among persons in Xuan Wei County, China, who burn bi...

  14. EVALUATION OF PILOT-SCALE AIR POLLUTION CONTROL DEVICES ON A REFUSE AND COAL-FIRED BOILER

    EPA Science Inventory

    The project report describes the operation of pilot-scale air pollution control devices to gather data on air pollution efficiency versus several different operating parameters on various waste-as-fuel combustio processes. It also includes a test of a full scale fabric filter use...

  15. Inventory compilation and distribution of heavy metals in wastewater from small-scale industrial areas of Delhi, India.

    PubMed

    Rawat, Manju; Moturi, Mechah Charles Zuriels; Subramanian, Vaidyanathan

    2003-12-01

    Delhi has the highest cluster of small-scale industries (SSI) in India. There are generally less stringent rules for the treatment of waste in SSI due to less waste generation within each individual industry. This results in SSI disposing of their wastewater untreated into drains and subsequently into the river Yamuna, which is a major source of potable water in Delhi, thus posing a potential health and environmental risk to the people living in Delhi and downstream. To study the quantity, quality and distribution of heavy metals in liquid waste from industrial areas, wastewater, suspended materials and bed sediments were collected from industrial areas and from the river Yamuna in Delhi. This study has also focused on the efficiency of production processes in small-scale industries in India. Heavy metals such as Fe, Mn, Cu, Zn, Ni, Cr, Cd, Co and Pb were detected using a GBC 902 atomic absorption spectrometer. The concentration of heavy metals observed was as follows: Fe 2-212, Mn 0.3-39, Cu 0.2-20, Zn 0.2-5, Ni 0.6-6, Cr 0.2-53, Cd 0.08-0.2, Co 0.013-0.55, Pb 0.3-0.7 mg L(-1) in wastewater; Fe 5842-78 000, Mn 585-10 889, Cu 206-7201, Zn 406-9000, Ni 22-3621, Cr 178-10 533, Co 17-114, Cd 13-141, Pb 67-50 171 mg kg(-1) in suspended material; and Fe 3000-84000, Mn 479-1230, Cu 378-8127, Zn 647-4010, Ni 164-1582, Cr 139-3281, Co 20-54, Cd 37-65, Pb 228-293 mg kg(-1) in bed residues. This indicates that SSI could be one of the point sources of metals pollution in the river system. PMID:14710931

  16. Liquefaction of calcium-containing subbituminous coals and coals of lower rank

    DOEpatents

    Brunson, Roy J.

    1979-01-01

    An improved process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation of scale, made up largely of calcium carbonate which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. An oxide of sulfur, in liquid phase, is contacted with a coal feed sufficient to impregnate the pores of the coal. The impregnated coal, in particulate form, can thereafter be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of scale.

  17. A Synergistic Combination of Advanced Separation and Chemical Scale Inhibitor Technologies for Efficient Use of Imparied Water As Cooling Water in Coal-based Power Plants

    SciTech Connect

    Jasbir Gill

    2010-08-30

    Nalco Company is partnering with Argonne National Laboratory (ANL) in this project to jointly develop advanced scale control technologies that will provide cost-effective solutions for coal-based power plants to operate recirculating cooling water systems at high cycles using impaired waters. The overall approach is to use combinations of novel membrane separations and scale inhibitor technologies that will work synergistically, with membrane separations reducing the scaling potential of the cooling water and scale inhibitors extending the safe operating range of the cooling water system. The project started on March 31, 2006 and ended in August 30, 2010. The project was a multiyear, multi-phase project with laboratory research and development as well as a small pilot-scale field demonstration. In Phase 1 (Technical Targets and Proof of Concept), the objectives were to establish quantitative technical targets and develop calcite and silica scale inhibitor chemistries for high stress conditions. Additional Phase I work included bench-scale testing to determine the feasibility of two membrane separation technologies (electrodialysis ED and electrode-ionization EDI) for scale minimization. In Phase 2 (Technology Development and Integration), the objectives were to develop additional novel scale inhibitor chemistries, develop selected separation processes, and optimize the integration of the technology components at the laboratory scale. Phase 3 (Technology Validation) validated the integrated system's performance with a pilot-scale demonstration. During Phase 1, Initial evaluations of impaired water characteristics focused on produced waters and reclaimed municipal wastewater effluents. Literature and new data were collected and evaluated. Characteristics of produced waters vary significantly from one site to another, whereas reclaimed municipal wastewater effluents have relatively more uniform characteristics. Assessment to date confirmed that calcite and silica

  18. FULL-SCALE DEMONSTRATION OF INDUSTRIAL WASTEWATER TREATMENT UTILIZING DU PONT'S PACT (TRADE NAME) PROCESS

    EPA Science Inventory

    Operating and cost data on startup and the initial 30 months of operation of a 150,000 cu m/day (40-MGD) industrial wastewater treatment plant using Du Pont's PACT process are reported. The process effectively provides secondary/tertiary treatment by adding powdered activated car...

  19. FULL-SCALE LABORATORY SIMULATION FACILITY TO TEST PARTICULATE AND ORGANIC EMISSIONS FROM A THIRD WORLD RESIDENTIAL COMBUSTION PROCESS. I. FACILITY DESCRIPTION AND RESULTS OF TESTS OF THREE RURAL CHINA RESIDENTIAL COALS, A U.S. COAL, AND WOOD

    EPA Science Inventory

    The paper gives results of a series of 12 tests for 3 coals from a rural area of China with abnormally high lung cancer rates, a U. S. coal, and pine wood fuel. It also discusses a residential combustion simulator, built at EPA's Research Triangle Park, NC, facility to conduct em...

  20. Coal pump

    DOEpatents

    Bonin, John H.; Meyer, John W.; Daniel, Jr., Arnold D.

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.