Science.gov

Sample records for innovative high thermal

  1. An Innovative High Thermal Conductivity Fuel Design

    SciTech Connect

    PI: James S. Tulenko; Co-PI: Ronald H. Baney,

    2007-10-14

    Uranium dioxide (UO2) is the most common fuel material in commercial nuclear power reactors. UO2 has the advantages of a high melting point, good high-temperature stability, good chemical compatibility with cladding and coolant, and resistance to radiation. The main disadvantage of UO2 is its low thermal conductivity. During a reactor’s operation, because the thermal conductivity of UO2 is very low, for example, about 2.8 W/m-K at 1000 oC [1], there is a large temperature gradient in the UO2 fuel pellet, causing a very high centerline temperature, and introducing thermal stresses, which lead to extensive fuel pellet cracking. These cracks will add to the release of fission product gases after high burnup. The high fuel operating temperature also increases the rate of fission gas release and the fuel pellet swelling caused by fission gases bubbles. The amount of fission gas release and fuel swelling limits the life time of UO2 fuel in reactor. In addition, the high centerline temperature and large temperature gradient in the fuel pellet, leading to a large amount of stored heat, increase the Zircaloy cladding temperature in a lost of coolant accident (LOCA). The rate of Zircaloy-water reaction becomes significant at the temperature above 1200 oC [2]. The ZrO2 layer generated on the surface of the Zircaloy cladding will affect the heat conduction, and will cause a Zircaloy cladding rupture. The objective of this research is to increase the thermal conductivity of UO2, while not affecting the neutronic property of UO2 significantly. The concept to accomplish this goal is to incorporate another material with high thermal conductivity into the UO2 pellet. Silicon carbide (SiC) is a good candidate, because the thermal conductivity of single crystal SiC is 60 times higher than that of UO2 at room temperature and 30 times higher at 800 oC [3]. Silicon carbide also has the properties of low thermal neutron absorption cross section, high melting point, good chemical

  2. An Innovative High Thermal Conductivity Fuel Design

    SciTech Connect

    Jamil A. Khan

    2009-11-21

    Thermal conductivity of the fuel in today's Light Water Reactors, Uranium dioxide, can be improved by incorporating a uniformly distributed heat conducting network of a higher conductivity material, Silicon Carbide. The higher thermal conductivity of SiC along with its other prominent reactor-grade properties makes it a potential material to address some of the related issues when used in UO2 [97% TD]. This ongoing research, in collaboration with the University of Florida, aims to investigate the feasibility and develop a formal methodology of producing the resultant composite oxide fuel. Calculations of effective thermal conductivity of the new fuel as a function of %SiC for certain percentages and as a function of temperature are presented as a preliminary approach. The effective thermal conductivities are obtained at different temperatures from 600K to 1600K. The corresponding polynomial equations for the temperature-dependent thermal conductivities are given based on the simulation results. Heat transfer mechanism in this fuel is explained using a finite volume approach and validated against existing empirical models. FLUENT 6.1.22 was used for thermal conductivity calculations and to estimate reduction in centerline temperatures achievable within such a fuel rod. Later, computer codes COMBINE-PC and VENTURE-PC were deployed to estimate the fuel enrichment required, to maintain the same burnup levels, corresponding to a volume percent addition of SiC.

  3. INNOVATIVE THERMAL TREATMENT PROCESSES

    EPA Science Inventory

    The paper contains discussions of several innovative thermal processes for treating or destroying hazardous wastes. Processes discussed can be included in the categories wet oxidation, molten glass, fluidized bed incineration, pyrolysis, molten salt, electric reactors, and plasma...

  4. INNOVATIVE THERMAL DESTRUCTION TECHNOLOGIES

    EPA Science Inventory

    Ten innovative technologies for thermally destroying hazardous wastes were selected and described in this paper. hese technologies were either supported by EPA's RCRA or SARA programs or developed by industry since 1980. wo of the important criteria used in selecting these techno...

  5. Innovative hybrid heat sink materials with high thermal conductivities and tailored CTE

    NASA Astrophysics Data System (ADS)

    Kitzmantel, M.; Neubauer, E.

    2015-02-01

    This paper talks about high performance heat sinks and heat spreaders made by hybrid structures based on metaldiamond composites. Thermal conductivities can be tuned between 450 and 650 W/mK while maintaining customizable thermal expansion of 6-10 ppm/K (@30°C). Using different hybrid structures in combination with the metal-diamond core significant changes in thermal properties can be identified. Applications targeted are LED, disc laser and laser diode heatsinks with these high performance inserts without the need of CTE matched submounts.

  6. COMPARISON OF INNOVATIVE TECHNOLOGY FOR THERMAL DESTRUCTION OF HAZARDOUS WASTE

    EPA Science Inventory

    This paper briefly summaries and compares six technologies which are considered to be innovative to the thermal destruction of hazardous wastes. The six technologies are: Fluidized Bed, Molten Salt, High Temperature Fluid Wall, Plasma Arc, Wet Air Oxidation and Supercritical Wate...

  7. Flameless thermal oxidation. Innovative technology summary report

    SciTech Connect

    1995-09-01

    The Flameless Thermal Oxidizer (FTO) is a commercial technology offered by Thermatrix, Inc. The FTO has been demonstrated to be an effective destructive technology for process and waste stream off-gas treatment of volatile organic compounds (VOCs), and in the treatment of VOC and chlorinated volatile organic compounds (CVOCs) off-gases generated during site remediation using either baseline or innovative in situ environmental technologies. The FTO process efficiently converts VOCs and CVOCs to carbon dioxide, water, and hydrogen chloride. When FTO is coupled with a baseline technology, such as soil vapor extraction (SVE), an efficient in situ soil remediation system is produced. The innovation is in using a simple, reliable, scalable, and robust technology for the destruction of VOC and CVOC off-gases based on a design that generates a uniform thermal reaction zone that prevents flame propagation and efficiently oxidizes off-gases without forming products of incomplete combustion (PICs).

  8. Flameless Thermal Oxidation. Innovative Technology Summary Report

    SciTech Connect

    1995-09-01

    The Flameless Thermal Oxidizer (FTO) is a commercial technology offered by Thermatrix, Inc. The FTO has been demonstrated to be an effective destructive technology for process and waste stream off-gas treatment of volatile organic compounds (VOCs), and in the treatment of VOC and chlorinated volatile organic compounds (CVOCs) off-gases generated during site remediation using either baseline or innovative in situ environmental technologies. The FTO process efficiently converts VOCs and CVOCs to carbon dioxide, water, and hydrogen chloride. When FTO is coupled with a baseline technology, such as soil vapor extraction (SVE), an efficient in situ soil remediation system is produced. The innovation is in using a simple, reliable, scalable, and robust technology for the destruction of VOC and CVOC off-gases based on a design that generates a uniform thermal reaction zone that prevents flame propagation and efficiently oxidizes off-gases without forming products of incomplete combustion (Plcs ).

  9. Development of Innovative Accident Tolerant High Thermal Conductivity UO2-Diamond Composite Fuel Pellets

    SciTech Connect

    Tulenko, James; Subhash, Ghatu

    2016-01-01

    The University of Florida (UF) evaluated a composite fuel consisting of UO2 powder mixed with diamond micro particles as a candidate as an accident-tolerant fuel (ATF). The research group had previous extensive experience researching with diamond micro particles as an addition to reactor coolant for improved plant thermal performance. The purpose of this research work was to utilize diamond micro particles to develop UO2-Diamond composite fuel pellets with significantly enhanced thermal properties, beyond that already being measured in the previous UF research projects of UO2 – SiC and UO2 – Carbon Nanotube fuel pins. UF is proving with the current research results that the addition of diamond micro particles to UO2 may greatly enhanced the thermal conductivity of the UO2 pellets producing an accident-tolerant fuel. The Beginning of life benefits have been proven and fuel samples are being irradiated in the ATR reactor to confirm that the thermal conductivity improvements are still present under irradiation.

  10. Innovative approach to retrieve land surface emissivity and land surface temperature in areas of highly dynamic emissivity changes by using thermal infrared data

    NASA Astrophysics Data System (ADS)

    Heinemann, S.

    2015-12-01

    The land surface temperature (LST) is an extremely significant parameter in order to understand the processes of energetic interactions between Earth's surface and atmosphere. This knowledge is significant for various environmental research questions, particularly with regard to the recent climate change. This study shows an innovative approach to retrieve land surface emissivity (LSE) and LST by using thermal infrared (TIR) data from satellite sensors, such as SEVIRI and AATSR. So far there are no methods to derive LSE/LST particularly in areas of highly dynamic emissivity changes. Therefore especially for regions with large surface temperature amplitude in the diurnal cycle such as bare and uneven soil surfaces but also for regions with seasonal changes in vegetation cover including various surface areas such as grassland, mixed forests or agricultural land different methods were investigated to identify the most appropriate one. The LSE is retrieved by using the day/night Temperature-Independent Spectral Indices (TISI) method, and the Generalised Split-Window (GSW) method is used to retrieve the LST. Nevertheless different GSW algorithms show that equal LSEs lead to large LST differences. Additionally LSE is also measured using a NDVI-based threshold method (NDVITHM) to distinguish between soil, dense vegetation cover and pixel composed of soil and vegetation. The data used for this analysis were derived from MODIS TIR. The analysis is implemented with IDL and an intercomparison is performed to determine the most effective methods. To compensate temperature differences between derived and ground truth data appropriate correction terms by comparing derived LSE/LST data with ground-based measurements are developed. One way to calibrate LST retrievals is by comparing the canopy leaf temperature of conifers derived from TIR data with the surrounding air temperature (e.g. from synoptic stations). Prospectively, the derived LSE/LST data become validated with near

  11. Innovative approach to retrieve land surface emissivity and land surface temperature in areas of highly dynamic emissivity changes by using thermal infrared data

    NASA Astrophysics Data System (ADS)

    Heinemann, Sascha; Muro, Javier; Burkart, Andreas; Schultz, Johannes; Thonfeld, Frank; Menz, Gunter

    2016-04-01

    The land surface temperature (LST) is an extremely significant parameter in order to understand the processes of energetic interactions between the Earth's surface and the atmosphere. This knowledge is significant for various environmental research questions, particularly with regard to climate change. The current challenge is to reduce the higher deviations during daytime especially for bare areas with a maximum of 5.7 Kelvin. These temperature differences are time and vegetation cover dependent. This study shows an innovative approach to retrieve land surface emissivity (LSE) and LST by using thermal infrared (TIR) data from satellite sensors, such as SEVIRI and AATSR. So far there are no methods to derive LSE/LST particularly in areas of highly dynamic emissivity changes. Therefore especially for regions with large surface temperature amplitude in the diurnal cycle such as bare and uneven soil surfaces but also for regions with seasonal changes in vegetation cover including various surface areas such as grassland, mixed forests or agricultural land different methods were investigated to identify the most appropriate one. The LSE is retrieved by using the day/night Temperature-Independent Spectral Indices (TISI) method, while the Generalised Split-Window (GSW) method is used to retrieve the LST. Nevertheless different GSW algorithms show that equal LSEs lead to large LST differences. For bare surfaces during daytime the difference is about 6 Kelvin. Additionally LSE is also measured using a NDVI-based threshold method (NDVITHM) to distinguish between soil, dense vegetation cover and pixel composed of soil and vegetation. The data used for this analysis were derived from MODIS TIR. The analysis is implemented with IDL and an intercomparison is performed to determine the most effective methods. To compensate temperature differences between derived and ground truth data appropriate correction terms, by comparing derived LSE/LST data with ground-based measurements

  12. Highly directional thermal emitter

    DOEpatents

    Ribaudo, Troy; Shaner, Eric A; Davids, Paul; Peters, David W

    2015-03-24

    A highly directional thermal emitter device comprises a two-dimensional periodic array of heavily doped semiconductor structures on a surface of a substrate. The array provides a highly directional thermal emission at a peak wavelength between 3 and 15 microns when the array is heated. For example, highly doped silicon (HDSi) with a plasma frequency in the mid-wave infrared was used to fabricate nearly perfect absorbing two-dimensional gratings structures that function as highly directional thermal radiators. The absorption and emission characteristics of the HDSi devices possessed a high degree of angular dependence for infrared absorption in the 10-12 micron range, while maintaining high reflectivity of solar radiation (.about.64%) at large incidence angles.

  13. Development of an Innovative High-Thermal Conductivity UO2 Ceramic Composites Fuel Pellets with Carbon Nano-Tubes Using Spark Plasma Sintering

    SciTech Connect

    Subhash, Ghatu; Wu, Kuang-Hsi; Tulenko, James

    2014-03-10

    Uranium dioxide (UO2) is the most common fuel material in commercial nuclear power reactors. Despite its numerous advantages such as high melting point, good high-temperature stability, good chemical compatibility with cladding and coolant, and resistance to radiation, it suffers from low thermal conductivity that can result in large temperature gradients within the UO2 fuel pellet, causing it to crack and release fission gases. Thermal swelling of the pellets also limits the lifetime of UO2 fuel in the reactor. To mitigate these problems, we propose to develop novel UO2 fuel with uniformly distributed carbon nanotubes (CNTs) that can provide high-conductivity thermal pathways and can eliminate fuel cracking and fission gas release due to high temperatures. CNTs have been investigated extensively for the past decade to explore their unique physical properties and many potential applications. CNTs have high thermal conductivity (6600 W/mK for an individual single- walled CNT and >3000 W/mK for an individual multi-walled CNT) and high temperature stability up to 2800°C in vacuum and about 750°C in air. These properties make them attractive candidates in preparing nano-composites with new functional properties. The objective of the proposed research is to develop high thermal conductivity of UO2–CNT composites without affecting the neutronic property of UO2 significantly. The concept of this goal is to utilize a rapid sintering method (5–15 min) called spark plasma sintering (SPS) in which a mixture of CNTs and UO2 powder are used to make composites with different volume fractions of CNTs. Incorporation of these nanoscale materials plays a fundamentally critical role in controlling the performance and stability of UO2 fuel. We will use a novel in situ growth process to grow CNTs on UO2 particles for rapid sintering and develop UO2-CNT composites. This method is expected to provide a uniform distribution of CNTs at various volume fractions so that a high

  14. Highly Thermal Conductive Nanocomposites

    NASA Technical Reports Server (NTRS)

    Sun, Ya-Ping (Inventor); Connell, John W. (Inventor); Veca, Lucia Monica (Inventor)

    2015-01-01

    Disclosed are methods for forming carbon-based fillers as may be utilized in forming highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. Disclosed carbon nanosheets can be functionalized and/or can be incorporated in nanocomposites with extremely high thermal conductivities. Disclosed methods and materials can prove highly valuable in many technological applications including, for instance, in formation of heat management materials for protective clothing and as may be useful in space exploration or in others that require efficient yet light-weight and flexible thermal management solutions.

  15. Innovative site remediation technology: Thermal desorption. Volume 6

    SciTech Connect

    Anderson, W.C.

    1993-11-01

    The monograph on thermal desorption is one of a series of eight on innovative site and waste remediation technologies that are the culmination of a multiorganization effort involving more than 100 experts over a two-year period. The thermal desorption processes addressed in this monograph use heat, either direct or indirect, ex situ, as the principal means to physically separate and transfer contaminants from soils, sediments, sludges, filter cakes, or other media. Thermal desorption is part of a treatment train; some pre- and postprocessing is necessary.

  16. High-Thermal-Conductivity Fabrics

    NASA Technical Reports Server (NTRS)

    Chibante, L. P. Felipe

    2012-01-01

    Heat management with common textiles such as nylon and spandex is hindered by the poor thermal conductivity from the skin surface to cooling surfaces. This innovation showed marked improvement in thermal conductivity of the individual fibers and tubing, as well as components assembled from them. The problem is centered on improving the heat removal of the liquid-cooled ventilation garments (LCVGs) used by astronauts. The current design uses an extensive network of water-cooling tubes that introduces bulkiness and discomfort, and increases fatigue. Range of motion and ease of movement are affected as well. The current technology is the same as developed during the Apollo program of the 1960s. Tubing material is hand-threaded through a spandex/nylon mesh layer, in a series of loops throughout the torso and limbs such that there is close, form-fitting contact with the user. Usually, there is a nylon liner layer to improve comfort. Circulating water is chilled by an external heat exchanger (sublimator). The purpose of this innovation is to produce new LCVG components with improved thermal conductivity. This was addressed using nanocomposite engineering incorporating high-thermalconductivity nanoscale fillers in the fabric and tubing components. Specifically, carbon nanotubes were added using normal processing methods such as thermoplastic melt mixing (compounding twin screw extruder) and downstream processing (fiber spinning, tubing extrusion). Fibers were produced as yarns and woven into fabric cloths. The application of isotropic nanofillers can be modeled using a modified Nielsen Model for conductive fillers in a matrix based on Einstein s viscosity model. This is a drop-in technology with no additional equipment needed. The loading is limited by the ability to maintain adequate dispersion. Undispersed materials will plug filtering screens in processing equipment. Generally, the viscosity increases were acceptable, and allowed the filled polymers to still be

  17. Thermal Denitration. Innovative Technology Summary Report

    SciTech Connect

    2001-09-01

    The major object of this work was to provide data for identifying and demonstrating a technically viable and cost-effective approach to condition LAW for immobilization. Pacific Northwest National Laboratory evaluated an approach that consisted of distillation followed by low-temperature denitration with a reductant addition. This process option minimizes volatilization of radionuclides and hazardous constituents, and converts most of the nitrate in the water to at least 50% nitrogen gas instead of NOx during LAW calcination, while still producing a groutable product. INEEL investigated high-temperature calcination for the LAW, a process already selected by INEEL for calcining high-level waste. Why is it necessary to remove the nitrate (denitrification)? The low-activity waste derived from the separation work performed on the sodium-bearing waste will be very acidic as will the high-activity waste from the redissolution of calcine. In addition, these waste streams will contain very high levels of nitrates; these nitrates are detrimental to grout waste forms. Thus, the nitrate must be removed from these waste streams before they are encapsulated in grout.

  18. Thermal conductance measurement of windows: An innovative radiative method

    SciTech Connect

    Arpino, F.; Buonanno, G.; Giovinco, G.

    2008-09-15

    Heat transfer through window surfaces is one of the most important contributions to energy losses in buildings. Therefore, great efforts are made to design new window frames and glass assemblies with low thermal conductance. At the same time, it is also necessary to develop accurate measurement techniques in thermal characterisation of the above-mentioned building components. In this paper the authors show an innovative measurement method mainly based on radiative heat transfer (instead of the traditional convective one) which allows window thermal conductance measurements with corresponding uncertainty budget evaluation. The authors used the 3D finite volume software FLUENT {sup registered} to design the experimental apparatus. The numerical results have been employed for the system optimisation and metrological characterisation. (author)

  19. Innovative Multi-Environment, Multimode Thermal Control System

    NASA Technical Reports Server (NTRS)

    Singh, Bhim S.; Hasan, Mohammad H.

    2007-01-01

    Innovative multi-environment multimode thermal management architecture has been described that is capable of meeting widely varying thermal control requirements of various exploration mission scenarios currently under consideration. The proposed system is capable of operating in a single-phase or two-phase mode rejecting heat to the colder environment, operating in a two-phase mode with heat pump for rejecting heat to a warm environment, as well as using evaporative phasechange cooling for the mission phases where the radiator is incapable of rejecting the required heat. A single fluid loop can be used internal and external to the spacecraft for the acquisition, transport and rejection of heat by the selection of a working fluid that meets NASA safety requirements. Such a system may not be optimal for each individual mode of operation but its ability to function in multiple modes may permit global optimization of the thermal control system. The architecture also allows flexibility in partitioning of components between the various Constellation modules to take advantage of operational requirements in various modes consistent with the mission needs. Preliminary design calculations using R-134 as working fluid show the concept to be feasible to meet the heat rejection requirements that are representative of the Crew Exploration Vehicle and Lunar Access Module for nominal cases. More detailed analyses to establish performance under various modes and environmental conditions are underway.

  20. High velocity pulsed plasma thermal spray

    NASA Astrophysics Data System (ADS)

    Witherspoon, F. D.; Massey, D. W.; Kincaid, R. W.; Whichard, G. C.; Mozhi, T. A.

    2002-03-01

    The quality and durability of coatings produced by many thermal spray techniques could be improved by increasing the velocity with which coating particles impact the substrate. Additionally, better control of the chemical and thermal environment seen by the particles during flight is crucial to the quality of the coating. A high velocity thermal spray device is under development through a Ballistic Missile Defense Organization Small Business Innovation Research (SBIR) project, which provides significantly higher impact velocity for accelerated particles than is currently available with existing thermal spray devices. This device utilizes a pulsed plasma as the accelerative medium for powders introduced into the barrel. Recent experiments using a particle imaging diagnostic system showed that the device can accelerate stainless steel and WC-Co powders to velocities ranging from 1500 to 2200 m/s. These high velocities are accomplished without the use of combustible gases and without the need of a vacuum chamber, while maintaining an inert atmosphere for the particles during acceleration. The high velocities corresponded well to modeling predictions, and these same models suggest that velocities as high as 3000 m/s or higher are possible.

  1. High temperature solar thermal technology

    NASA Technical Reports Server (NTRS)

    Leibowitz, L. P.; Hanseth, E. J.; Peelgren, M. L.

    1980-01-01

    Some advanced technology concepts under development for high-temperature solar thermal energy systems to achieve significant energy cost reductions and performance gains and thus promote the application of solar thermal power technology are presented. Consideration is given to the objectives, current efforts and recent test and analysis results in the development of high-temperature (950-1650 C) ceramic receivers, thermal storage module checker stoves, and the use of reversible chemical reactions to transport collected solar energy. It is pointed out that the analysis and testing of such components will accelerate the commercial deployment of solar energy.

  2. Thermal analysis of an innovative heat pump operated desalination plant

    SciTech Connect

    Site, V.D.

    1995-12-31

    Sea and brackish water desalination can contribute to solve the problem of fresh water shortage in many and regions of the world. Nowadays most of the installed desalination plants employ distillation processes, like Multistage Flash (MSF), Multi effect Distillation (MED) and Vapor Compression (VC). VC process is called Mechanical Vapor Compression (MVC) when it employs a mechanical compressor, while it is called Thermal Compression when it employs a steam-ejector compressor. In this paper a new distillation plant for the treatment of sea water for drinking water purposes is presented. The most innovative feature of this system is the use of a heat pump as part of the desalting unit. The use of the heat pump in the proposed system enables desalting water evaporation and steam condensation at the same temperature, unlike conventional VC desalting systems where a steam compression stage is necessary. A thermal analysis of the heat pump-operated desalination (HPD) plant and a comparison between the HPD and a conventional MVC plant is presented, in order to determine the main advantages and disadvantages of the new system.

  3. Innovators.

    ERIC Educational Resources Information Center

    NEA Today, 2001

    2001-01-01

    Describes various innovations that have been developed to enhance education. These innovations include: helping educators help at-risk students succeed; promoting high school journalism; ensuring quality online learning experiences; developing a student performing group that uses theater to address social issues; and having students design their…

  4. Innovative coal gasification system with high temperature air

    SciTech Connect

    Yoshikawa, K.; Katsushima, H.; Kasahara, M.; Hasegawa, T.; Tanaka, R.; Ootsuka, T.

    1997-12-31

    This paper proposes innovative coal gasification power generation systems where coal is gasified with high temperature air of about 1300K produced by gasified coal fuel gas. The main features of these systems are high thermal efficiency, low NO{sub x} emission, compact desulfurization and dust removal equipment and high efficiency molten slag removal with a very compact gasifier. Recent experimental results on the pebble bed coal gasifier appropriate for high temperature air coal gasification are reported, where 97.7% of coal ash is successfully caught in the pebble bed and extracted without clogging. A new concept of high temperature air preheating system is proposed which is characterized by its high reliability and low cost.

  5. MAOS: An Innovative Way to Teach High School.

    ERIC Educational Resources Information Center

    Harray, Nancy; And Others

    1997-01-01

    Describes an innovative high school program that uses oceanography, mathematics, and science as common threads in the instructional program. The program utilizes an innovative class structure, community involvement, and hands on activities. (DDR)

  6. Teaching Innovation in High School Technology Classes

    ERIC Educational Resources Information Center

    Wright, Geoffrey A.; Skaggs, Paul; West, Richard E.

    2013-01-01

    Innovation is central to modern industry. It can and should be taught in schools. Not only does providing students a background in innovation benefit them later in life and industry, but it also promotes and further develops their critical thinking and collaboration skills. Despite the need for innovation, many have struggled with how to teach it.…

  7. Thermal, optical, and electrical engineering of an innovative tunable white LED light engine

    NASA Astrophysics Data System (ADS)

    Trivellin, Nicola; Meneghini, Matteo; Ferretti, Marco; Barbisan, Diego; Dal Lago, Matteo; Meneghesso, Gaudenzio; Zanoni, Enrico

    2014-02-01

    Color temperature, intensity and blue spectrum of the light affects the ganglion receptors in human brain stimulating the human nervous system. With this work we review different methods for obtaining tunable light emission spectra and propose an innovative white LED lighting system. By an in depth study of the thermal, electrical and optical characteristics of GaN and GaP based compound semiconductors for optoelectronics a specific tunable spectra has been designed. The proposed tunable white LED system is able to achieve high CRI (above 95) in a large CCT range (3000 - 5000K).

  8. High thermal conductivity of diamond

    NASA Technical Reports Server (NTRS)

    Stephan, Patrick M.

    1993-01-01

    The objectives of this educational exercise were to demonstrate the high rate of heat flow from a synthetic diamond coupon and to compare it to a commonly used thermal conductor, such as copper. The principles of heat transfer by conduction and convection may also be demonstrated. A list of equipment and supplies and the procedure for the experiment are presented.

  9. Innovative methodologies and technologies for thermal energy release measurement.

    NASA Astrophysics Data System (ADS)

    Marotta, Enrica; Peluso, Rosario; Avino, Rosario; Belviso, Pasquale; Caliro, Stefano; Carandente, Antonio; Chiodini, Giovanni; Mangiacapra, Annarita; Petrillo, Zaccaria; Sansivero, Fabio; Vilardo, Giuseppe; Marfe, Barbara

    2016-04-01

    Volcanoes exchange heat, gases and other fluids between the interrior of the Earth and its atmosphere influencing processes both at the surface and above it. This work is devoted to improve the knowledge on the parameters that control the anomalies in heat flux and chemical species emissions associated with the diffuse degassing processes of volcanic and hydrothermal zones. We are studying and developing innovative medium range remote sensing technologies to measure the variations through time of heat flux and chemical emissions in order to boost the definition of the activity state of a volcano and allowing a better assessment of the related hazard and risk mitigation. The current methodologies used to measure heat flux (i.e. CO2 flux or temperature gradient) are either poorly efficient or effective, and are unable to detect short to medium time (days to months) variation trends in the heat flux. Remote sensing of these parameters will allow for measurements faster than already accredited methods therefore it will be both more effective and efficient in case of emergency and it will be used to make quick routine monitoring. We are currently developing a method based on drone-born IR cameras to measure the ground surface temperature that, in a purely conductive regime, is directly correlated to the shallow temperature gradient. The use of flying drones will allow to quickly obtain a mapping of areas with thermal anomalies and a measure of their temperature at distance in the order of hundreds of meters. Further development of remote sensing will be done through the use, on flying drones, of multispectral and/or iperspectral sensors, UV scanners in order to be able to detect the amount of chemical species released in the athmosphere.

  10. Building America Top Innovations 2012: Thermal Bypass Air Barriers in the 2009 International Energy Conservation Code

    SciTech Connect

    none,

    2013-01-01

    This Building America Top Innovations profile describes Building America research supporting Thermal Bypass Air Barrier requirements. Since these were adopted in the 2009 IECC, close to one million homes have been mandated to include this vitally important energy efficiency measure.

  11. High temperature solar thermal receiver

    NASA Technical Reports Server (NTRS)

    1979-01-01

    A design concept for a high temperature solar thermal receiver to operate at 3 atmospheres pressure and 2500 F outlet was developed. The performance and complexity of windowed matrix, tube-header, and extended surface receivers were evaluated. The windowed matrix receiver proved to offer substantial cost and performance benefits. An efficient and cost effective hardware design was evaluated for a receiver which can be readily interfaced to fuel and chemical processes or to heat engines for power generation.

  12. An innovative thermal system approach significantly increases system reliability and power and packaging densities

    SciTech Connect

    Burns, K.K.; Alexander, R.; Burns, J.R.

    1996-12-31

    An innovative self-contained active cooling system for electronic products, which increases power and packaging densities and improves reliability, was investigated. The cooling technology uses low cost, readily available, and reliable components. While this thermal control method can be applied to many applications, a simple power system cooling application will be demonstrated. The application demonstrates increased power density of a common 48 Vdc to 5Vdc high density DC-DC power converter module having standard dimensions of 2.4in.x4.6in.x0.5in. An increase in power density from 50W/in{sup 3} to over 80W/in{sup 3} was realized. In addition, significantly high calculated MTBF, from 300K hours to greater than 3M hours, was realized with low temperature operation.

  13. Innovative hybrid optics: combining the thermal stability of glass with low manufacturing cost of polymers

    NASA Astrophysics Data System (ADS)

    Doushkina, Valentina

    2010-08-01

    Innovative hybrid glass-polymer optical solutions on a component, module, or system level offer thermal stability of glass with low manufacturing cost of polymers reducing component weight, enhancing the safety and appeal of the products. Narrow choice of polymer materials is compensated by utilizing sophisticated optical surfaces such as refractive, reflective, and diffractive substrates with spherical, aspherical, cylindrical, and freeform prescriptions. Current advancements in polymer technology and injection molding capabilities placed polymer optics in the heart of many high tech devices and applications including Automotive Industry, Defense & Aerospace; Medical/Bio Science; Projection Displays, Sensors, Information Technology, Commercial and Industrial. This paper is about integration of polymer and glass optics for enhanced optical performance with reduced number of components, thermal stability, and low manufacturing cost. The listed advantages are not achievable when polymers or glass optics are used as stand-alone. The author demonstrates that integration of polymer and glass on component or optical system level on one hand offers high resolution and diffraction limited image quality, similar to the glass optics with stable refractive index and stable thermal performance when design is athermalized within the temperature range. On the other hand, the integrated hybrid solution significantly reduces cost, weight, and complexity, just like the polymer optics. The author will describe the design and analyzes process of combining glass and polymer optics for variety of challenging applications such as fast optics with low F/#, wide field of view lenses or systems, free form optics, etc.

  14. High thermal expansion, sealing glass

    DOEpatents

    Brow, R.K.; Kovacic, L.

    1993-11-16

    A glass composition is described for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na[sub 2]O, between about 10 and about 25 mole percent K[sub 2]O, between about 5 and about 15 mole percent Al[sub 2]O[sub 3], between about 35 and about 50 mole percent P[sub 2]O[sub 5] and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe[sub 2]O[sub 3] and between 0 and about 10 mole percent B[sub 2]O[sub 3], has a thermal expansion coefficient in a range of between about 160 and 210[times]10[sup [minus]7]/C and a dissolution rate in a range of between about 2[times]10[sup [minus]7] and 2[times]10[sup [minus]9]g/cm[sup 2]-min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  15. High thermal expansion, sealing glass

    DOEpatents

    Brow, Richard K.; Kovacic, Larry

    1993-01-01

    A glass composition for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na.sub.2 O, between about 10 and about 25 mole percent K.sub.2 O, between about 5 and about 15 mole percent Al.sub.2 O.sub.3, between about 35 and about 50 mole percent P.sub.2 O.sub.5 and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe.sub.2 O.sub.3 and between 0 and about 10 mole percent B.sub.2 O.sub.3, has a thermal expansion coefficient in a range of between about 160 and 210.times.10-7/.degree.C. and a dissolution rate in a range of between about 2.times.10.sup.- 7 and 2.times.10.sup.-9 g/cm.sup.2 -min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  16. Feasibility Study on Thermal-Hydraulic Performance of Innovative Water Reactor for Flexible Fuel Cycle (FLWR)

    SciTech Connect

    Akira, Ohnuki; Kazuyuki, Takase; Masatoshi, Kureta; Hiroyuki, Yoshida; Hidesada, Tamai; Wei, Liu; Toru, Nakatsuka; Takeharu, Misawa; Hajime, Akimoto

    2006-07-01

    R and D project to investigate thermal-hydraulic performance in tight-lattice rod bundles of Innovative Water Reactor for Flexible Fuel Cycle (FLWR) is started at Japan Atomic Energy Agency (JAEA) in collaboration with power company, reactor vendors, universities since 2002. The FLWR can attain the favorable characteristics such as effective utilization of uranium resources, multiple recycling of plutonium, high burn-up and long operation cycle, based on matured LWR technologies. MOX fuel assemblies with tight lattice arrangement are used to increase the conversion ratio by reducing the moderation of neutron. Increasing the in-core void fraction also contributes to the reduction of neutron moderation. The confirmation of thermal-hydraulic feasibility is one of the most important R and D items for the FLWR because of the tight lattice configuration. In this paper, we will show the R and D plan and summarize experimental studies. The experimental study is performed mainly using large-scale (37-rod bundle) test facility. Most important objective of the large-scale test is to resolve a fundamental subject whether the core cooling under a tight-lattice configuration is feasible. The characteristics of critical power and flow behavior are investigated under different geometrical configuration and boundary conditions. The configuration parameter is the gap between rods (FY2004) and the rod bowing (FY2005). We have confirmed the thermal-hydraulic feasibility from the experimental results. (authors)

  17. Building America Top Innovations 2012: High-R Walls

    SciTech Connect

    none,

    2013-01-01

    This Building America Top Innovations profile describes Building America research on high-R-value walls showing the difference between rated and whole wall R values and the need for vented cladding to reduce condensation potential with some insulation types.

  18. Value innovation: the strategic logic of high growth.

    PubMed

    Kim, W C; Mauborgne, R

    1997-01-01

    Why are some companies able to sustain high growth in revenues and profits--and others are not? To answer that question, the authors, both of INSEAD, spent five years studying more than 30 companies around the world. They found that the difference between the high-growth companies and their less successful competitors was in each group's assumptions about strategy. Managers of the less successful companies followed conventional strategic logic. Managers of the high-growth companies followed what the authors call the logic of value innovation. Conventional strategic logic and value innovation differ along the basic dimensions of strategy. Many companies take their industry's conditions as given; value innovators don't. Many companies let competitors set the parameters of their strategic thinking; value innovators do not use rivals as benchmarks. Rather than focus on the differences among customers, value innovators look for what customers value in common. Rather than view opportunities through the lens of existing assets and capabilities, value innovators ask, What if we start anew? The authors tell the story of the French hotelier Accor, which discarded the notion of what a hotel is supposed to look like in order to offer what most customers want: a good night's sleep at a low price. And Virgin Atlantic challenged industry conventions by eliminating first-class service and channeling savings into innovations for business-class passengers. Those companies didn't set out to build advantages over the competition, but they ended up achieving the greatest competitive advantages. PMID:10174449

  19. Innovative method for the thermal cycling of large spacecraft systems

    NASA Technical Reports Server (NTRS)

    Steimer, C. H.; Hale, A. D.

    1984-01-01

    The use of low cost, off the shelf prefabricated enclosures for spacecraft system thermal cycling applications was indicated. The enclosures are erected in the satellite integration areas without disturbing the test article, electrical test set, or RF interfaces. They are assembled by metal clad, modular urethane panels. These panels are self supporting, and are locked and sealed to each other on assembly. Penetrations for interconnecting cables, coaxial and waveguide services; and temperature conditioning inlet and outlet ducts are easily incorporated where required. The facility and its advantages and intrinsic benefits are described.

  20. Innovative space-saving device for high-temperature piping systems

    NASA Astrophysics Data System (ADS)

    Racki, Daniel J.

    1991-01-01

    Innovative, compact, simple piping supports have been developed for ultra-high-temperature nuclear and nonnuclear piping systems that require a large degree of structural reliability. These supports, originally designed for the SP-100 Ground Engineering System (GES) Nuclear Assembly Test (NAT) power system, can be used in both thin and thick wall piping systems. This paper discusses the design of these piping supports and the supporting thermal and structural analyses.

  1. In situ vitrification: An innovative thermal treatment technology

    SciTech Connect

    Fitzpatrick, V.F.; Timmerman, C.L.; Buelt, J.L.

    1987-03-01

    In situ vitrification is a thermal treatment process that converts contaminated soil into a chemically inert, stable glass and crystalline product. A square array of four electrodes are inserted into the ground to the desired treatment depth. Because the soil is not electrically conductive once the moisture has been driven off, a conductive mixture of flaked graphite and glass frit is placed among the electrodes to act as the starter path. An electrical potential is applied to the electrodes, which establishes an electrical current in the starter path. The resultant power heats the starter path and surrounding soil up to 3600F, well above the initial melting temperature or fusion temperature of soils. The normal fusion temperature of soil ranges between 2000 and 2500F. The graphite starter path is eventually consumed by oxidation, and the current is transferred to the molten soil, which is now electrically conductive. As the vitrified zone grows, it incorporates nonvolatile elements and destroys organic components by pyrolysis. The pyrolyzed byproducts migrate to the surface of the vitrified zone, where they combust in the presence of oxygen. A hood placed over the processing area provides confinement for the combustion gases, and the gases are drawn into the off-gas treatment system.

  2. The nuclear thermal electric rocket: a proposed innovative propulsion concept for manned interplanetary missions

    NASA Astrophysics Data System (ADS)

    Dujarric, C.; Santovincenzo, A.; Summerer, L.

    2013-03-01

    Conventional propulsion technology (chemical and electric) currently limits the possibilities for human space exploration to the neighborhood of the Earth. If farther destinations (such as Mars) are to be reached with humans on board, a more capable interplanetary transfer engine featuring high thrust, high specific impulse is required. The source of energy which could in principle best meet these engine requirements is nuclear thermal. However, the nuclear thermal rocket technology is not yet ready for flight application. The development of new materials which is necessary for the nuclear core will require further testing on ground of full-scale nuclear rocket engines. Such testing is a powerful inhibitor to the nuclear rocket development, as the risks of nuclear contamination of the environment cannot be entirely avoided with current concepts. Alongside already further matured activities in the field of space nuclear power sources for generating on-board power, a low level investigation on nuclear propulsion has been running since long within ESA, and innovative concepts have already been proposed at an IAF conference in 1999 [1, 2]. Following a slow maturation process, a new concept was defined which was submitted to a concurrent design exercise in ESTEC in 2007. Great care was taken in the selection of the design parameters to ensure that this quite innovative concept would in all respects likely be feasible with margins. However, a thorough feasibility demonstration will require a more detailed design including the selection of appropriate materials and the verification that these can withstand the expected mechanical, thermal, and chemical environment. So far, the predefinition work made clear that, based on conservative technology assumptions, a specific impulse of 920 s could be obtained with a thrust of 110 kN. Despite the heavy engine dry mass, a preliminary mission analysis using conservative assumptions showed that the concept was reducing the required

  3. Influence of thermal treatment on color, enzyme activities, and antioxidant capacity of innovative pastelike parsley products.

    PubMed

    Kaiser, Andrea; Brinkmann, Maike; Carle, Reinhold; Kammerer, Dietmar R

    2012-03-28

    Conventional spice powders are often characterized by low sensory quality and high microbial loads. Furthermore, genuine enzymes are only inhibited but not entirely inactivated upon drying, so that they may regain their activity upon rehydration of dried foods. To overcome these problems, initial heating was applied in the present study as the first process step for the production of innovative pastelike parsley products. For this purpose, fresh parsley was blanched (80, 90, and 100 °C for 1-10 min) and subsequently comminuted to form a paste. Alternatively, mincing was carried out prior to heat treatment. Regardless of temperature, the color of the latter product did not show any change after heating for 1 min. With progressing exposure time the green color turned to olive hues due to marked pheophytin formation. Inactivation of genuine peroxidase (POD) and polyphenol oxidase (PPO) was achieved at all temperature-time regimes applied. In contrast, the parsley products obtained after immediate water-blanching were characterized by brighter green colors and enhanced pigment retention. With the exception of the variants water-blanched at 80 °C, POD and PPO were completely inactivated at any of the thermal treatments. Furthermore, in water-blanched samples, antioxidant capacities as determined by the TEAC and FRAP assays were even enhanced compared to unheated parsley, whereas a decrease of phenolic contents could not be prevented. Consequently, the innovative process presented in this study allows the production of novel herb and spice products characterized by improved sensory quality as compared to conventional spice products. PMID:22375822

  4. Successful Magnet High Schools. Innovations in Education

    ERIC Educational Resources Information Center

    US Department of Education, 2008

    2008-01-01

    Lack of relevant course work is a top reason why high school students drop out, and studies have shown that low-income and minority students are less likely to be enrolled in college preparatory curricula than their more affluent peers. In today's world, it is critical to ensure that all students have access to a rigorous, high-quality education…

  5. High Spatial Resolution Thermal Satellite Technologies

    NASA Technical Reports Server (NTRS)

    Ryan, Robert

    2003-01-01

    This document in the form of viewslides, reviews various low-cost alternatives to high spatial resolution thermal satellite technologies. There exists no follow-on to Landsat 7 or ASTER high spatial resolution thermal systems. This document reviews the results of the investigation in to the use of new technologies to create a low-cost useful alternative. Three suggested technologies are examined. 1. Conventional microbolometer pushbroom modes offers potential for low cost Landsat Data Continuity Mission (LDCM) thermal or ASTER capability with at least 60-120 ground sampling distance (GSD). 2. Backscanning could produce MultiSpectral Thermal Imager performance without cooled detectors. 3. Cooled detector could produce hyperspectral thermal class system or extremely high spatial resolution class instrument.

  6. Thermal disconnect for high-temperature batteries

    DOEpatents

    Jungst, Rudolph George; Armijo, James Rudolph; Frear, Darrel Richard

    2000-01-01

    A new type of high temperature thermal disconnect has been developed to protect electrical and mechanical equipment from damage caused by operation at extreme temperatures. These thermal disconnects allow continuous operation at temperatures ranging from 250.degree. C. to 450.degree. C., while rapidly terminating operation at temperatures 50.degree. C. to 150.degree. C. higher than the continuous operating temperature.

  7. High intensity, pulsed thermal neutron source

    DOEpatents

    Carpenter, J.M.

    1973-12-11

    This invention relates to a high intensity, pulsed thermal neutron source comprising a neutron-producing source which emits pulses of fast neutrons, a moderator block adjacent to the last neutron source, a reflector block which encases the fast neutron source and the moderator block and has a thermal neutron exit port extending therethrough from the moderator block, and a neutron energy- dependent decoupling reflector liner covering the interior surfaces of the thermal neutron exit port and surrounding all surfaces of the moderator block except the surface viewed by the thermal neutron exit port. (Official Gazette)

  8. Innovations in high-temperature particulate filtration

    SciTech Connect

    Lippert, T.

    1997-05-01

    Fluidized-bed combustion and coal gasification expose sensitive equipment, such as high-speed turbines, to hot combustion offgases. In order to prevent erosion, corrosion, and other damage to sensitive equipment, such systems now incorporate high-temperature particulate filters. One device often considered for such applications uses a design similar to a baghouse (i.e., multiple banks of porous filter bags that remove particulate from gas streams). In this case, however, instead of polyester or teflon fabric, the filter elements are made of rigid ceramic or similar materials. These devices are sometimes called `candle filters,` and the individual ceramic filter elements are frequently called `candles.` Three high-temperature applications of candle filters are described here. 2 refs., 3 figs.

  9. Innovations in high power fiber laser applications

    NASA Astrophysics Data System (ADS)

    Beyer, Eckhard; Mahrle, Achim; Lütke, Matthias; Standfuss, Jens; Brückner, Frank

    2012-02-01

    Diffraction-limited high power lasers represent a new generation of lasers for materials processing, characteristic traits of which are: smaller, cost-effective and processing "on the fly". Of utmost importance is the high beam quality of fiber lasers which enables us to reduce the size of the focusing head incl. scanning mirrors. The excellent beam quality of the fiber laser offers a lot of new applications. In the field of remote cutting and welding the beam quality is the key parameter. By reducing the size of the focusing head including the scanning mirrors we can reach scanning frequencies up to 1.5 kHz and in special configurations up to 4 kHz. By using these frequencies very thin and deep welding seams can be generated experienced so far with electron beam welding only. The excellent beam quality of the fiber laser offers a high potential for developing new applications from deep penetration welding to high speed cutting. Highly dynamic cutting systems with maximum speeds up to 300 m/min and accelerations up to 4 g reduce the cutting time for cutting complex 2D parts. However, due to the inertia of such systems the effective cutting speed is reduced in real applications. This is especially true if complex shapes or contours are cut. With the introduction of scanner-based remote cutting systems in the kilowatt range, the effective cutting speed on the contour can be dramatically increased. The presentation explains remote cutting of metal foils and sheets using high brightness single mode fiber lasers. The presentation will also show the effect of optical feedback during cutting and welding with the fiber laser, how those feedbacks could be reduced and how they have to be used to optimize the cutting or welding process.

  10. Innovative thermal energy harvesting for future autonomous applications

    NASA Astrophysics Data System (ADS)

    Monfray, Stephane

    2013-12-01

    As communicating autonomous systems market is booming, the role of energy harvesting will be a key enabler. As example, heat is one of the most abundant energy sources that can be converted into electricity in order to power circuits. Harvesting systems that use wasted heat open new ways to power autonomous sensors when the energy consumption is low, or to create systems of power generators when the conversion efficiency is high. The combination of different technologies (low power μ-processors, μ-batteries, radio, sensors...) with new energy harvesters compatible with large varieties of use-cases with allow to address this booming market. Thanks to the conjunction of ultra-low power electronic development, 3D technologies & Systems in Package approaches, the integration of autonomous sensors and electronics with ambient energy harvesting will be achievable. The applications are very wide, from environment and industrial sensors to medical portable applications, and the Internet of things may also represent in the future a several billions units market.

  11. Interactive Leadership in High School Innovation.

    ERIC Educational Resources Information Center

    Clarke, John; Aiken, Judith A.; Sullivan, Mary J.

    1999-01-01

    Every year, a Vermont high school teacher uses laws of physics to teach students how to design, field test, and calibrate a weapon that fires tennis balls to 100-yard distances. This article explains how the "physics war" grew to accommodate the new Vermont curriculum standards at various organizational levels. (22 references) (MLH)

  12. High Reynolds Number Thermal Stability Experiments

    NASA Technical Reports Server (NTRS)

    Emens, Jessica M.; Brown, Sarah P.; Frederick Robert A., Jr.; Wood, A. John

    2004-01-01

    This work represents preliminary thermal stability results for liquid hydrocarbon fuels. High Reynolds Number Thermal Stability experiments with Jet A and RP-1 resulted in a quantitative measurement of the thermal stability. Each fuel flowed through a heated capillary tube that held the outlet temperature at 290 C. An optical pyrometer measured the surface temperature of the tube at 12 locations as a function of time. The High Reynolds Number Thermal Stability number was then determined using standards published by the American Society for Testing and Materials. The results for Jet A showed lower thermal stability than similar tests conducted at another facility. The RP-1 results are the first reported using this technique. Because the temperature rise on the capillary tube during testing for the RP-1 fuels was not significant, a new standard for the testing conditions should be developed for these types of fuels.

  13. Information support for high technologies: issues of innovation

    NASA Astrophysics Data System (ADS)

    Piskorskaya, S. Yu; Goncharov, A. E.; Prohorovich, G. A.; Perantseva, A. V.

    2016-04-01

    The current development of high technologies and innovative projects requires systematic information support. This article describes examples of information support and promotion of regional technological platforms of the Krasnoiarskii krai on the base of communications projects which are being realized by students at SibSAU. These technological platforms correspond to the prioritized fields of developing science and research in the Russian Federation.

  14. Factors Supporting or Inhibiting Innovative Practices in Senior High Schools.

    ERIC Educational Resources Information Center

    Daresh, John C.

    Semistructured interviews were used to query school staffs, administrators, and school board members in this exploratory field study of successful high schools implementing an individualized program. Analysis of results suggest these possible findings regarding factors that may support or inhibit the implementation of innovations: (1) The most…

  15. High precision innovative micropump for artificial pancreas

    NASA Astrophysics Data System (ADS)

    Chappel, E.; Mefti, S.; Lettieri, G.-L.; Proennecke, S.; Conan, C.

    2014-03-01

    The concept of artificial pancreas, which comprises an insulin pump, a continuous glucose meter and a control algorithm, is a major step forward in managing patient with type 1 diabetes mellitus. The stability of the control algorithm is based on short-term precision micropump to deliver rapid-acting insulin and to specific integrated sensors able to monitor any failure leading to a loss of accuracy. Debiotech's MEMS micropump, based on the membrane pump principle, is made of a stack of 3 silicon wafers. The pumping chamber comprises a pillar check-valve at the inlet, a pumping membrane which is actuated against stop limiters by a piezo cantilever, an anti-free-flow outlet valve and a pressure sensor. The micropump inlet is tightly connected to the insulin reservoir while the outlet is in direct communication with the patient skin via a cannula. To meet the requirement of a pump dedicated to closed-loop application for diabetes care, in addition to the well-controlled displacement of the pumping membrane, the high precision of the micropump is based on specific actuation profiles that balance effect of pump elasticity in low-consumption push-pull mode.

  16. Innovative Field Emitters for High-Voltage Electronic Devices

    NASA Astrophysics Data System (ADS)

    Sominski, G. G.; Sezonov, V. E.; Taradaev, E. P.; Tumareva, T. A.; Zadiranov, Yu. M.; Kornishin, S. Yu.; Stepanova, A. N.

    2015-12-01

    We describe multitip field emitters with protective coatings, which were developed in Peter the Great St. Petersburg Polytechnic University. The coatings ensure long-term operation of the emitters under high currents and technical vacuum. Innovative multi-layer emitters composed of contacting nanolayers of materials with different work functions are presented as well. The possibility by using the developed emitters in high-voltage electronic devices is demonstrated.

  17. Polyethylene nanofibres with very high thermal conductivities.

    PubMed

    Shen, Sheng; Henry, Asegun; Tong, Jonathan; Zheng, Ruiting; Chen, Gang

    2010-04-01

    Bulk polymers are generally regarded as thermal insulators, and typically have thermal conductivities on the order of 0.1 W m(-1) K(-1). However, recent work suggests that individual chains of polyethylene--the simplest and most widely used polymer--can have extremely high thermal conductivity. Practical applications of these polymers may also require that the individual chains form fibres or films. Here, we report the fabrication of high-quality ultra-drawn polyethylene nanofibres with diameters of 50-500 nm and lengths up to tens of millimetres. The thermal conductivity of the nanofibres was found to be as high as approximately 104 W m(-1) K(-1), which is larger than the conductivities of about half of the pure metals. The high thermal conductivity is attributed to the restructuring of the polymer chains by stretching, which improves the fibre quality toward an 'ideal' single crystalline fibre. Such thermally conductive polymers are potentially useful as heat spreaders and could supplement conventional metallic heat-transfer materials, which are used in applications such as solar hot-water collectors, heat exchangers and electronic packaging. PMID:20208547

  18. High precision thermal neutron detectors

    SciTech Connect

    Radeka, V.; Schaknowski, N.A.; Smith, G.C.; Yu, B.

    1994-12-31

    Two-dimensional position sensitive detectors are indispensable in neutron diffraction experiments for determination of molecular and crystal structures in biology, solid-state physics and polymer chemistry. Some performance characteristics of these detectors are elementary and obvious, such as the position resolution, number of resolution elements, neutron detection efficiency, counting rate and sensitivity to gamma-ray background. High performance detectors are distinguished by more subtle characteristics such as the stability of the response (efficiency) versus position, stability of the recorded neutron positions, dynamic range, blooming or halo effects. While relatively few of them are needed around the world, these high performance devices are sophisticated and fairly complex, their development requires very specialized efforts. In this context, we describe here a program of detector development, based on {sup 3}He filled proportional chambers, which has been underway for some years at the Brookhaven National Laboratory. Fundamental approaches and practical considerations are outlined that have resulted in a series of high performance detectors with the best known position resolution, position stability, uniformity of response and reliability over time, for devices of this type.

  19. Innovative nuclear thermal propulsion technology evaluation - Results of the NASA/DOE task team study

    NASA Technical Reports Server (NTRS)

    Howe, Steven D.; Borowski, Stanley; Motloch, Chet; Helms, Ira; Diaz, Nils; Anghaie, Samim; Latham, Thomas

    1991-01-01

    In response to findings from two NASA/DOE nuclear propulsion workshops, six task teams were created to continue evaluation of various propulsion concepts, from which evolved an innovative concepts subpanel to evaluate thermal propulsion concepts which did not utilize solid fuel. This subpanel endeavored to evaluate each concept on a level technology basis, and to identify critical issues, technologies, and early proof-of-concept experiments. Results of the concept studies including the liquid core fission, the gas core fission, the fission foil reactors, explosively driven systems, fusion, and antimatter are presented.

  20. High thermal conductivity connector having high electrical isolation

    DOEpatents

    Nieman, Ralph C.; Gonczy, John D.; Nicol, Thomas H.

    1995-01-01

    A method and article for providing a low-thermal-resistance, high-electrical-isolation heat intercept connection. The connection method involves clamping, by thermal interference fit, an electrically isolating cylinder between an outer metallic ring and an inner metallic disk. The connection provides durable coupling of a heat sink and a heat source.

  1. Innovative nuclear thermal propulsion technology evaluation: Results of the NASA/DOE Task Team study

    SciTech Connect

    Howe, S. ); Borowski, S. . Lewis Research Center); Motloch, C. ); Helms, I. ); Diaz, N.; Anghaie, S. ); Latham, T. (United

    1991-01-01

    In response to findings from two NASA/DOE nuclear propulsion workshops held in the summer of 1990, six task teams were formed to continue evaluation of various nuclear propulsion concepts. The Task Team on Nuclear Thermal Propulsion (NTP) created the Innovative Concepts Subpanel to evaluate thermal propulsion concepts which did not utilize solid fuel. The Subpanel endeavored to evaluate each of the concepts on a level technological playing field,'' and to identify critical technologies, issues, and early proof-of-concept experiments. The concepts included the liquid core fission, the gas core fission, the fission foil reactors, explosively driven systems, fusion, and antimatter. The results of the studies by the panel will be provided. 13 refs., 6 figs., 2 tabs.

  2. High-Temperature Adhesives for Thermally Stable Aero-Assist Technologies

    NASA Technical Reports Server (NTRS)

    Eberts, Kenneth; Ou, Runqing

    2013-01-01

    Aero-assist technologies are used to control the velocity of exploration vehicles (EVs) when entering Earth or other planetary atmospheres. Since entry of EVs in planetary atmospheres results in significant heating, thermally stable aero-assist technologies are required to avoid the high heating rates while maintaining low mass. Polymer adhesives are used in aero-assist structures because of the need for high flexibility and good bonding between layers of polymer films or fabrics. However, current polymer adhesives cannot withstand temperatures above 400 C. This innovation utilizes nanotechnology capabilities to address this need, leading to the development of high-temperature adhesives that exhibit high thermal conductivity in addition to increased thermal decomposition temperature. Enhanced thermal conductivity will help to dissipate heat quickly and effectively to avoid temperature rising to harmful levels. This, together with increased thermal decomposition temperature, will enable the adhesives to sustain transient high-temperature conditions.

  3. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect

    2011-12-01

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  4. Thermal modeling of high efficiency AMTEC cells

    SciTech Connect

    Ivanenok, J.F. III; Sievers, R.K.; Crowley, C.J.

    1995-12-31

    Remotely condensed Alkali Metal Thermal to Electric Conversion (AMTEC) cells achieve high efficiency by thermally isolating the hot {beta} Alumina Solid Electrolyte (BASE) tube from the cold condensing region. In order to design high efficiency AMTEC cells the designer must understand the heat losses associated with the AMTEC process. The major parasitic heat losses are due to conduction and radiation, and significant coupling of the two mechanisms occurs. This paper describes an effort to characterize the thermal aspects of the model PL-6 AMTEC cell and apply this understanding to the design of a higher efficiency AMTEC cell, model PL-8. Two parallel analyses were used to model the thermal characteristics of PL-6. The first was a lumped node model using the classical electric circuit analogy and the second was a detailed finite-difference model. The lumped node model provides high speed and reasonable accuracy, and the detailed finite-difference model provides a more accurate, as well as visual, description of the cell temperature profiles. The results of the two methods are compared to the as-measured PL-6 data. PL-6 was the first cell to use a micromachined condenser to lower the radiation losses to the condenser, and it achieved a conversion efficiency of 15% (3 W output/20 W Input) at a temperature of 1050 K.

  5. High-performance flat-panel solar thermoelectric generators with high thermal concentration.

    PubMed

    Kraemer, Daniel; Poudel, Bed; Feng, Hsien-Ping; Caylor, J Christopher; Yu, Bo; Yan, Xiao; Ma, Yi; Wang, Xiaowei; Wang, Dezhi; Muto, Andrew; McEnaney, Kenneth; Chiesa, Matteo; Ren, Zhifeng; Chen, Gang

    2011-07-01

    The conversion of sunlight into electricity has been dominated by photovoltaic and solar thermal power generation. Photovoltaic cells are deployed widely, mostly as flat panels, whereas solar thermal electricity generation relying on optical concentrators and mechanical heat engines is only seen in large-scale power plants. Here we demonstrate a promising flat-panel solar thermal to electric power conversion technology based on the Seebeck effect and high thermal concentration, thus enabling wider applications. The developed solar thermoelectric generators (STEGs) achieved a peak efficiency of 4.6% under AM1.5G (1 kW m(-2)) conditions. The efficiency is 7-8 times higher than the previously reported best value for a flat-panel STEG, and is enabled by the use of high-performance nanostructured thermoelectric materials and spectrally-selective solar absorbers in an innovative design that exploits high thermal concentration in an evacuated environment. Our work opens up a promising new approach which has the potential to achieve cost-effective conversion of solar energy into electricity. PMID:21532584

  6. Thermal interface pastes nanostructured for high performance

    NASA Astrophysics Data System (ADS)

    Lin, Chuangang

    Thermal interface materials in the form of pastes are needed to improve thermal contacts, such as that between a microprocessor and a heat sink of a computer. High-performance and low-cost thermal pastes have been developed in this dissertation by using polyol esters as the vehicle and various nanoscale solid components. The proportion of a solid component needs to be optimized, as an excessive amount degrades the performance, due to the increase in the bond line thickness. The optimum solid volume fraction tends to be lower when the mating surfaces are smoother, and higher when the thermal conductivity is higher. Both a low bond line thickness and a high thermal conductivity help the performance. When the surfaces are smooth, a low bond line thickness can be even more important than a high thermal conductivity, as shown by the outstanding performance of the nanoclay paste of low thermal conductivity in the smooth case (0.009 mum), with the bond line thickness less than 1 mum, as enabled by low storage modulus G', low loss modulus G" and high tan delta. However, for rough surfaces, the thermal conductivity is important. The rheology affects the bond line thickness, but it does not correlate well with the performance. This study found that the structure of carbon black is an important parameter that governs the effectiveness of a carbon black for use in a thermal paste. By using a carbon black with a lower structure (i.e., a lower DBP value), a thermal paste that is more effective than the previously reported carbon black paste was obtained. Graphite nanoplatelet (GNP) was found to be comparable in effectiveness to carbon black (CB) pastes for rough surfaces, but it is less effective for smooth surfaces. At the same filler volume fraction, GNP gives higher thermal conductivity than carbon black paste. At the same pressure, GNP gives higher bond line thickness than CB (Tokai or Cabot). The effectiveness of GNP is limited, due to the high bond line thickness. A

  7. Charter Schools and Innovation: The High Tech High Model

    ERIC Educational Resources Information Center

    Neumann, Richard

    2008-01-01

    This article examines the High Tech High charter school, the ideas and practices that influenced its development, and the school's impact on San Diego Unified School District, which authorized the charter. The Discussion analyzes the school's program using frameworks of social bonding theory and progressive educational theory and practice. Since…

  8. Another Innovation from High Tech High--Embedded Teacher Training

    ERIC Educational Resources Information Center

    Griswold, Janie; Riordan, Rob

    2016-01-01

    High Tech High School's teaching internship program blends on-the-job work with classroom theory. Interns spend two years working as full teachers as they take courses. The program serves three large purposes: Train new teachers and build capacity in the HTH organization; train teachers in and beyond HTH for success in a wide range of contexts;…

  9. Thermal fuse for high-temperature batteries

    DOEpatents

    Jungst, Rudolph G.; Armijo, James R.; Frear, Darrel R.

    2000-01-01

    A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

  10. Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Phase 1 Final Report

    SciTech Connect

    Qiu, Songgang

    2013-05-15

    The primary purpose of this project is to develop and validate an innovative, scalable phase change salt thermal energy storage (TES) system that can interface with Infinia’s family of free-piston Stirling engines (FPSE). This TES technology is also appropriate for Rankine and Brayton power converters. Solar TES systems based on latent heat of fusion rather than molten salt temperature differences, have many advantages that include up to an order of magnitude higher energy storage density, much higher temperature operation, and elimination of pumped loops for most of Infinia’s design options. DOE has funded four different concepts for solar phase change TES, including one other Infinia awarded project using heat pipes to transfer heat to and from the salt. The unique innovation in this project is an integrated TES/pool boiler heat transfer system that is the simplest approach identified to date and arguably has the best potential for minimizing the levelized cost of energy (LCOE). The Phase 1 objectives are to design, build and test a 1-hour TES proof-of-concept lab demonstrator integrated with an Infinia 3 kW Stirling engine, and to conduct a preliminary design of a 12-hour TES on-sun prototype.

  11. Reservoir modeling of the Solvent Thermal Resource Innovation Process for enhanced oil recovery

    NASA Astrophysics Data System (ADS)

    James, S. C.; Lucia, A.; Voskov, D.; Schneider, A.

    2012-12-01

    The Automatic Differentiation General Purpose Research Simulator (ADGPRS) has been improved to more accurately simulate multiphase, multi-component flow in porous media. ADGPRS has been augmented with a general, multi-scale framework for multi-component, multi-phase equilibrium flash calculations, which uses information at the molecular and bulk fluid length scales. The key attributes of this multi-scale Gibbs-Helmholtz Constrained Equation of State (GHC EOS) approach are (1) the use of coarse-grained, fixed-particle, temperature, and pressure Monte Carlo simulations to gather pure component internal energies of departure, (2) a linear mixing rule for internal energies of departure for mixtures, (3) a novel expression for partial fugacity coefficients, and (4) a flash algorithm based on complex-valued compressibility factors and densities to assist in phase existence determination. Our thermal nonlinear formulation for solution of reservoir equations is based on saturations and phase concentrations and uses variable substitution to handle phase appearances and disappearances in systems with an arbitrary number of phases. This coupled ADGPRS-GHC framework simulates multi-component, thermal flow at equilibrium conditions, which is important for modeling thermally enhanced oil recovery including steam and CO2 co-solvent injection. The coupled code is applied to an example problem where heat and mass (steam and CO2) are added to a "depleted" oil-bearing formation. Results demonstrate the improved efficiency of the Solvent Thermal Resource Innovation Process (STRIP) oil recovery method over standard steam injection without CO2. Also, STRIP operating parameters are optimized based on simulation results.

  12. Safety improvements in high pressure thermal machines

    SciTech Connect

    Otters, J.L.

    1988-02-09

    In a thermal machine of the type including a machine body having a main axis extending between a thermal end and a work end, a working fluid at relatively high pressure in a working fluid chamber defined in the body and a displacer element reciprocable within the chamber for subjecting the fluid to a thermodynamic cycle in cooperation with a reciprocable work piston, the improvement is described comprising outer shell means enclosing the machine body for maintaining a substantially sealed atmosphere about the machine body, and diffuser means arranged between the machine body and the outer shell means for diffusing a shock wave traveling towards the outer shell means resulting from explosive failure of the machine body and for shielding the outer shell means against fragments projected upon such failure.

  13. Innovative Application of Maintenance-Free Phase-Change Thermal Energy Storage for Dish-Engine Solar Power Generation

    SciTech Connect

    Qui, Songgang; Galbraith, Ross

    2013-01-23

    This final report summarizes the final results of the Phase II Innovative Application of Maintenance-Free Phase-Change Thermal Energy Storage for Dish-Engine Solar Power Generation project being performed by Infinia Corporation for the U.S. Department of Energy under contract DE-FC36-08GO18157 during the project period of September 1, 2009 - August 30, 2012. The primary objective of this project is to demonstrate the practicality of integrating thermal energy storage (TES) modules, using a suitable thermal salt phase-change material (PCM) as its medium, with a dish/Stirling engine; enabling the system to operate during cloud transients and to provide dispatchable power for 4 to 6 hours after sunset. A laboratory prototype designed to provide 3 kW-h of net electrical output was constructed and tested at Infinia's Ogden Headquarters. In the course of the testing, it was determined that the system's heat pipe network - used to transfer incoming heat from the solar receiver to both the Stirling generator heater head and to the phase change salt - did not perform to expectations. The heat pipes had limited capacity to deliver sufficient heat energy to the generator and salt mass while in a charging mode, which was highly dependent on the orientation of the device (vertical versus horizontal). In addition, the TES system was only able to extract about 30 to 40% of the expected amount of energy from the phase change salt once it was fully molten. However, the use of heat pipes to transfer heat energy to and from a thermal energy storage medium is a key technical innovation, and the project team feels that the limitations of the current device could be greatly improved with further development. A detailed study of manufacturing costs using the prototype TES module as a basis indicates that meeting DOE LCOE goals with this hardware requires significant efforts. Improvement can be made by implementing aggressive cost-down initiatives in design and materials, improving system

  14. Development and Testing of an Innovative Two-Arm Focal-Plane Thermal Strap (TAFTS)

    NASA Technical Reports Server (NTRS)

    Urquiza, E.; Vasquez, C.; Rodriguez, J.; Van Gorp, B.

    2011-01-01

    Maintaining temperature stability in optical focal planes comes with the intrinsic challenge of creating a pathway that is both extremely flexible mechanically and highly conductive thermally. The task is further complicated because science-caliber optical focal planes are extremely delicate, yet their mechanical resiliency is rarely tested and documented. The mechanical engineer tasked with the thermo-mechanical design must then create a highly conductive thermal link that minimizes the tensile and shear stresses transmitted to the focal plane without design parameters on an acceptable stiffness. This paper will describe the development and testing of the thermal link developed for the Portable Remote Imaging Spectrometer (PRISM) instrument. It will provide experimentally determined mechanical stiffness plots in the three axes of interest. Analytical and experimental thermal conductance results for the two-arm focal-plane thermal strap (TAFTS), from cryogenic to room temperatures, are also presented. The paper also briefly describes some elements of the fabrication process followed in developing a novel design solution, which provides high conductance and symmetrical mechanical loading, while providing enhanced flexibility in all three degrees of freedom.

  15. Advanced Liquid-Cooling Garment Using Highly Thermally Conductive Sheets

    NASA Technical Reports Server (NTRS)

    Ruemmele, Warren P.; Bue, Grant C.; Orndoff, Evelyne; Tang, Henry

    2010-01-01

    This design of the liquid-cooling garment for NASA spacesuits allows the suit to remove metabolic heat from the human body more effectively, thereby increasing comfort and performance while reducing system mass. The garment is also more flexible, with fewer restrictions on body motion, and more effectively transfers thermal energy from the crewmember s body to the external cooling unit. This improves the garment s performance in terms of the maximum environment temperature in which it can keep a crewmember comfortable. The garment uses flexible, highly thermally conductive sheet material (such as graphite), coupled with cooling water lines of improved thermal conductivity to transfer the thermal energy from the body to the liquid cooling lines more effectively. The conductive sheets can be layered differently, depending upon the heat loads, in order to provide flexibility, exceptional in-plane heat transfer, and good through-plane heat transfer. A metal foil, most likely aluminum, can be put between the graphite sheets and the external heat source/sink in order to both maximize through-plane heat transfer at the contact points, and to serve as a protection to the highly conductive sheets. Use of a wicking layer draws excess sweat away from the crewmember s skin and the use of an outer elastic fabric ensures good thermal contact of the highly conductive underlayers with the skin. This allows the current state of the art to be improved by having cooling lines that can be more widely spaced to improve suit flexibility and to reduce weight. Also, cooling liquid does not have to be as cold to achieve the same level of cooling. Specific areas on the human body can easily be targeted for greater or lesser cooling to match human physiology, a warmer external environment can be tolerated, and spatial uniformity of the cooling garment can be improved to reduce vasoconstriction limits. Elements of this innovation can be applied to other embodiments to provide effective heat

  16. Development of a high force thermal latch

    NASA Astrophysics Data System (ADS)

    Nygren, William D.

    1995-05-01

    This paper describes the preliminary development of a high force thermal latch (HFTL). The HFTL has one moving part which is restrained in the latched position by a low melting temperature or fusible metal alloy. When heated the fusible alloy flows to a receiving chamber and in so doing at first releases the tension load in the latch bolt and later releases the bolt itself. The HFTL can be used in place of pyrotechnically activated spacecraft release devices in those instances where the elimination of both pyrotechnic shock-loading and rapid strain-energy release take precedence over the near instantaneous release offered by ordnance initiated devices.

  17. Development of a high force thermal latch

    NASA Technical Reports Server (NTRS)

    Nygren, William D.

    1995-01-01

    This paper describes the preliminary development of a high force thermal latch (HFTL). The HFTL has one moving part which is restrained in the latched position by a low melting temperature or fusible metal alloy. When heated the fusible alloy flows to a receiving chamber and in so doing at first releases the tension load in the latch bolt and later releases the bolt itself. The HFTL can be used in place of pyrotechnically activated spacecraft release devices in those instances where the elimination of both pyrotechnic shock-loading and rapid strain-energy release take precedence over the near instantaneous release offered by ordnance initiated devices.

  18. Innovation on high-power long-pulse gyrotrons

    NASA Astrophysics Data System (ADS)

    Litvak, Alexander; Sakamoto, Keishi; Thumm, Manfred

    2011-12-01

    Progress in the worldwide development of high-power gyrotrons for magnetic confinement fusion plasma applications is described. After technology breakthroughs in research on gyrotron components in the 1990s, significant progress has been achieved in the last decade, in particular, in the field of long-pulse and continuous wave (CW) gyrotrons for a wide range of frequencies. At present, the development of 1 MW-class CW gyrotrons has been very successful; these are applicable for self-ignition experiments on fusion plasmas and their confinement in the tokamak ITER, for long-pulse confinement experiments in the stellarator Wendelstein 7-X (W7-X) and for EC H&CD in the future tokamak JT-60SA. For this progress in the field of high-power long-pulse gyrotrons, innovations such as the realization of high-efficiency stable oscillation in very high order cavity modes, the use of single-stage depressed collectors for energy recovery, highly efficient internal quasi-optical mode converters and synthetic diamond windows have essentially contributed. The total tube efficiencies are around 50% and the purity of the fundamental Gaussian output mode is 97% and higher. In addition, activities for advanced gyrotrons, e.g. a 2 MW gyrotron using a coaxial cavity, multi-frequency 1 MW gyrotrons and power modulation technology, have made progress.

  19. Influence of High Cycle Thermal Loads on Thermal Fatigue Behavior of Thick Thermal Barrier Coatings

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Miller, Robert A.

    1997-01-01

    Thick thermal barrier coating systems in a diesel engine experience severe thermal Low Cycle Fatigue (LCF) and High Cycle Fatigue (HCF) during engine operation. In the present study, the mechanisms of fatigue crack initiation and propagation, as well as of coating failure, under thermal loads which simulate engine conditions, are investigated using a high power CO2 laser. In general, surface vertical cracks initiate early and grow continuously under LCF and HCF cyclic stresses. It is found that in the absence of interfacial oxidation, the failure associated with LCF is closely related to coating sintering and creep at high temperatures, which induce tensile stresses in the coating after cooling. Experiments show that the HCF cycles are very damaging to the coating systems. The combined LCF and HCF tests produced more severe coating surface cracking, microspallation and accelerated crack growth, as compared to the pure LCF test. It is suggested that the HCF component cannot only accelerate the surface crack initiation, but also interact with the LCF by contributing to the crack growth at high temperatures. The increased LCF stress intensity at the crack tip due to the HCF component enhances the subsequent LCF crack growth. Conversely, since a faster HCF crack growth rate will be expected with lower effective compressive stresses in the coating, the LCF cycles also facilitate the HCF crack growth at high temperatures by stress relaxation process. A surface wedging model has been proposed to account for the HCF crack growth in the coating system. This mechanism predicts that HCF damage effect increases with increasing temperature swing, the thermal expansion coefficient and the elastic modulus of the ceramic coating, as well as the HCF interacting depth. A good agreement has been found between the analysis and experimental evidence.

  20. Thermal Conductivity of Argon at High Pressures and High Temperatures

    NASA Astrophysics Data System (ADS)

    Wong, M. L.; Goncharov, A. F.; Dalton, D. A.; Ojwang, J.; Struzhkin, V.; Konopkova, Z.; Lazor, P.

    2010-12-01

    Accurate data on the thermal conductivity of argon at high pressures and high temperatures is essential to unraveling the nature of the Earth’s interior. Argon is a common pressure-transmitting medium in diamond anvil cell (DAC) experiments, which is commonly used for studying the properties of minerals at pressures and temperatures native to the mantel and core. We used a transient heating technique (Beck et al., 2007) in a symmetric DAC up to 50 GPa and 2500 K. A thin iridium foil (1 μm thick) positioned in a recessed gasket hole filled with argon served as a heat absorber (coupler) to pump thermal energy into the sample. We used 6 μs width pulses from electronically modulated Yb-based fiber laser. We determined the temperature of the coupler with 500 ns time resolution by applying the Planck function to its thermal emission spectrum, and doing this over time yields temperature verses time for the coupler. Using finite element (FE) calculation methods we simulated the heat flux transfer in the DAC cavity using the experimentally determined geometric and laser heating parameters. The thermochemical parameters of Ir and Ar were determined by scaling the ambient pressure data using the available equations of state. The temperature dependent thermal conductivity of Ar was determined by fitting the results of FE calculations to the experimentally determined time dependent coupler temperature. We used the results of the theoretical calculations (Tretiakov & Scandolo, 2004) as the initial input. The results for the pressure and temperature dependent thermal conductivity of Ar will be reported at the meeting. This work is supported by NSF EAR 0711358, NSF-REU, Carnegie Institution of Washington, and DOE-NNSA (CDAC). Beck, P; Goncharov, A.F., Struzhkin, V.V., Militzer, B, Mao, H.K, Hemley, R.J. (2007). Measurement of thermal diffusivity at high pressure using a transient heating technique, Appl Phys. Lett. 91, 181914-(1-3). Tretiakov, K. V. & S. Scandolo (2004

  1. High Cycle Thermal Fatigue in French PWR

    SciTech Connect

    Blondet, Eric; Faidy, Claude

    2002-07-01

    Different fatigue-related incidents which occurred in the world on the auxiliary lines of the reactor coolant system (SIS, RHR, CVC) have led EDF to search solutions in order to avoid or to limit consequences of thermodynamic phenomenal (Farley-Tihange, free convection loop and stratification, independent thermal cycling). Studies are performed on mock-up and compared with instrumentation on nuclear power stations. At the present time, studies allow EDF to carry out pipe modifications and to prepare specifications and recommendations for next generation of nuclear power plants. In 1998, a new phenomenal appeared on RHR system in Civaux. A crack was discovered in an area where hot and cold fluids (temperature difference of 140 deg. C) were mixed. Metallurgic studies concluded that this crack was caused by high cycle thermal fatigue. Since 1998, EDF is making an inventory of all mixing areas in French PWR on basis of criteria. For all identified areas, a method was developed to improve the first classifying and to keep back only potential damage pipes. Presently, studies are performing on the charging line nozzle connected to the reactor pressure vessel. In order to evaluate the load history, a mock-up has been developed and mechanical calculations are realised on this nozzle. The paper will make an overview of EDF conclusions on these different points: - dead legs and vortex in a no flow connected line; - stratification; - mixing tees with high {delta}T. (authors)

  2. High Temperature Aerogels for Thermal Protection Systems

    NASA Technical Reports Server (NTRS)

    Hurwitz, Frances I.; Mbah, Godfrey C.

    2008-01-01

    High temperature aerogels in the Al2O3-SiO2 system are being investigated as possible constituents for lightweight integrated thermal protection system (TPS) designs for use in supersonic and hypersonic applications. Gels are synthesized from ethoxysilanes and AlCl3.6H2O, using an epoxide catalyst. The influence of Al:Si ratio, solvent, water to metal and water to alcohol ratios on aerogel composition, morphology, surface area, and pore size distribution were examined, and phase transformation on heat treatment characterized. Aerogels have been fabricated which maintain porous, fractal structures after brief exposures to 1000 C. Incorporation of nanofibers, infiltration of aerogels into SiC foams, use of polymers for crosslinking the aerogels, or combinations of these, offer potential for toughening and integration of TPS with composite structure. Woven fabric composites having Al2O3-SiO2 aerogels as a matrix also have been fabricated. Continuing work is focused on reduction in shrinkage and optimization of thermal and physical properties.

  3. Adventures in supercomputing: An innovative program for high school teachers

    SciTech Connect

    Oliver, C.E.; Hicks, H.R.; Summers, B.G.; Staten, D.G.

    1994-12-31

    Within the realm of education, seldom does an innovative program become available with the potential to change an educator`s teaching methodology. Adventures in Supercomputing (AiS), sponsored by the U.S. Department of Energy (DOE), is such a program. It is a program for high school teachers that changes the teacher paradigm from a teacher-directed approach of teaching to a student-centered approach. {open_quotes}A student-centered classroom offers better opportunities for development of internal motivation, planning skills, goal setting and perseverance than does the traditional teacher-directed mode{close_quotes}. Not only is the process of teaching changed, but the cross-curricula integration within the AiS materials is remarkable. Written from a teacher`s perspective, this paper will describe the AiS program and its effects on teachers and students, primarily at Wartburg Central High School, in Wartburg, Tennessee. The AiS program in Tennessee is sponsored by Oak Ridge National Laboratory (ORNL).

  4. Deployment of an innovative thermally enhanced soil mixing process augmented with zero-valent iron.

    SciTech Connect

    Lynch, P. L.

    1999-01-15

    An innovative in-situ soil treatment process, referred to as soil mixing/thermally enhanced soil vapor extraction (SM/TESVE), was used to remediate the 317 Area of Argonne National Laboratory-East (i.e., Argonne), which is contaminated with volatile organic compounds (VOCs). Following the initial soil treatment, polishing was required to reduce residual concentrations of contaminants. A study of polishing methods was conducted. It determined that injecting metallic iron particles into the soil, in conjunction with soil mixing, would reduce residual VOC concentrations more effectively than the original conventional soil ventilation approach. After the effectiveness of iron injection was verified, it replaced the soil ventilation step. The modified process involved mixing the soil while hot air and steam were injected into it. Off-gases were captured in a hood over the treatment area. During this process, an iron slurry, consisting of up to 50% iron particles in water with guar gum added as a thickening agent, was injected and mixed into the soil by the mixing equipment. Approximately 6,246 m{sup 3} (8, 170 yd{sup 3}) of soil was treated during this project. Confirmatory samples were then collected. In these samples, VOC concentrations were usually reduced by more than 80%.

  5. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    SciTech Connect

    Tanaka, Hiromasa; Mizuno, Masaaki; Toyokuni, Shinya; Maruyama, Shoichi; Kodera, Yasuhiro; Terasaki, Hiroko; Adachi, Tetsuo; Kato, Masashi; Kikkawa, Fumitaka; Hori, Masaru

    2015-12-15

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established.

  6. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    NASA Astrophysics Data System (ADS)

    Tanaka, Hiromasa; Mizuno, Masaaki; Toyokuni, Shinya; Maruyama, Shoichi; Kodera, Yasuhiro; Terasaki, Hiroko; Adachi, Tetsuo; Kato, Masashi; Kikkawa, Fumitaka; Hori, Masaru

    2015-12-01

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established.

  7. Ultra low thermal expansion, highly thermal shock resistant ceramic

    DOEpatents

    Limaye, Santosh Y.

    1996-01-01

    Three families of ceramic compositions having the given formula: .phi..sub.1+X Zr.sub.4 P.sub.6-2X Si.sub.2X O.sub.24, .phi..sub.1+X Zr.sub.4-2X Y.sub.2X P.sub.6 O.sub.24 and .phi..sub.1+X Zr.sub.4-X Y.sub.X P.sub.6-2X Si.sub.X O.sub.24 wherein .phi. is either Strontium or Barium and X has a value from about 0.2 to about 0.8 have been disclosed. Ceramics formed from these compositions exhibit very low, generally near neutral, thermal expansion over a wide range of elevated temperatures.

  8. Ultra low thermal expansion, highly thermal shock resistant ceramic

    DOEpatents

    Limaye, S.Y.

    1996-01-30

    Three families of ceramic compositions having the given formula: {phi}{sub 1+X}Zr{sub 4}P{sub 6{minus}2X}Si{sub 2X}O{sub 24}, {phi}{sub 1+X}Zr{sub 4{minus}2X}Y{sub 2X}P{sub 6}O{sub 24} and {phi}{sub 1+X}Zr{sub 4{minus}X}Y{sub X}P{sub 6{minus}2X}Si{sub X}O{sub 24} wherein {phi} is either strontium or barium and X has a value from about 0.2 to about 0.8 have been disclosed. Ceramics formed from these compositions exhibit very low, generally near neutral, thermal expansion over a wide range of elevated temperatures. 7 figs.

  9. Innovation, Innovation, Innovation

    ERIC Educational Resources Information Center

    Schuller, Tom

    2007-01-01

    Innovation, Universities and Skills. The new title of the department offers much food for thought. The title is indeed an intriguing and important one. Bringing the idea of innovation right to the fore is, to use an overworked term, challenging. Pinning down what innovation means is not at all easy. There are three different lines of argument. The…

  10. Innovative nanostructures for highly sensitive vibrational biosensing (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Popp, Juergen; Mayerhöfer, Thomas; Cialla-May, Dana; Weber, Karina; Huebner, Uwe

    2016-03-01

    Employing vibrational spectroscopy (IR-absorption and Raman spectroscopy) allows for the labelfree detection of molecular specific fingerprints of inorganic, organic and biological substances. The sensitivity of vibrational spectroscopy can be improved by several orders of magnitude via the application of plasmonic active surfaces. Within this contribution we will discuss two such approaches, namely surface enhanced Raman spectroscopy (SERS) as well as surface enhanced IR absorption (SEIRA). It will be shown that SERS using metal colloids as SERS active substrate in combination with a microfluidic lab-on-a-chip (LOC) device enables high throughput and reproducible measurements with highest sensitivity and specificity. The application of such a LOC-SERS approach for therapeutic drug monitoring (e.g. quantitative detection of antibiotics in a urine matrix) will be presented. Furthermore, we will introduce innovative bottom-up strategies to prepare SERS-active nanostructures coated with a lipophilic sensor layer as one-time use SERS substrates for specific food analysis (e.g. quantitative detection of toxic food colorants). The second part of this contribution presents a slit array metamaterial perfect absorber for IR sensing applications consisting of a dielectric layer sandwiched between two metallic layers of which the upper layer is perforated with a periodic array of slits. Light-matter interaction is greatly amplified in the slits, where also the analyte is concentrated, as the surface of the substrate is covered by a thin silica layer. Thus, already small concentrations of analytes down to a monolayer can be detected by refractive index sensing and identified by their spectral fingerprints with a standard mid-infrared lab spectrometer.

  11. High temperature dependence of thermal transport in graphene foam.

    PubMed

    Li, Man; Sun, Yi; Xiao, Huying; Hu, Xuejiao; Yue, Yanan

    2015-03-13

    In contrast to the decreased thermal property of carbon materials with temperature according to the Umklapp phonon scattering theory, highly porous free-standing graphene foam (GF) exhibits an abnormal characteristic that its thermal property increases with temperature above room temperature. In this work, the temperature dependence of thermal properties of free-standing GF is investigated by using the transient electro-thermal technique. Significant increase for thermal conductivity and thermal diffusivity from ∼0.3 to 1.5 W m(-1) K(-1) and ∼4 × 10(-5) to ∼2 × 10(-4) m(2) s(-1) respectively is observed with temperature from 310 K to 440 K for three GF samples. The quantitative analysis based on a physical model for porous media of Schuetz confirms that the thermal conductance across graphene contacts rather than the heat conductance inside graphene dominates thermal transport of our GFs. The thermal expansion effect at an elevated temperature makes the highly porous structure much tighter is responsible for the reduction in thermal contact resistance. Besides, the radiation heat exchange inside the pores of GFs improves the thermal transport at high temperatures. Since free-standing GF has great potential for being used as supercapacitor and battery electrode where the working temperature is always above room temperature, this finding is beneficial for thermal design of GF-based energy applications. PMID:25683178

  12. High conductance thermal interface concept for space applications

    NASA Technical Reports Server (NTRS)

    Poulin, Elizabeth C.; Horan, D. C.

    1991-01-01

    An interface concept has been developed which produces high conductance at a thermal/mechanical joint without resorting to high clamping forces or potentially contaminating fillers such as thermal grease. This paper discusses the characteristics of several variations of the high conductance interface concept and compares them to those of existing interface concepts proposed for several Space Station applications. The application of the high conductance concept to thermal joints such as internal coldplate interfaces and external equipment module to heat acquisition plate interfaces would reduce the weight and complexity and increase the efficiency of the Space Station Thermal Management System.

  13. Resilient thermal barrier for high temperatures

    NASA Technical Reports Server (NTRS)

    Frye, J. A.

    1977-01-01

    Abrasion-resistant thermal barrier, consisting of two layers of woven fabric or braided sleeving with bulk insulation sandwiched between, shows excellent resilience even after compression at temperatures above 980C.

  14. The Development of Innovative Chemistry Learning Material for Bilingual Senior High School Students in Indonesia

    ERIC Educational Resources Information Center

    Situmorang, Manihar; Sitorus, Marham; Hutabarat, Wesly; Situmorang, Zakarias

    2015-01-01

    The development of innovative chemistry learning material for bilingual Senior High School (SHS) students in Indonesia is explained. The study is aimed to obtain an innovative chemistry learning material based on national curriculum in Indonesia to be used as a learning media in the teaching and learning activities. The learning material is…

  15. Spaces of Innovation: Experiences from Two Small High-Tech Firms

    ERIC Educational Resources Information Center

    Heiskanen, Tuula; Heiskanen, Hannu

    2011-01-01

    Purpose: By comparing two small high-tech firms specialising in medical technology this article seeks to answer the following questions: What are the key characteristics of innovation processes in the case firms? How do the mutual relationships between mental, social and physical spaces explain the different pathways in the innovation processes in…

  16. Putative extremely high rate of proteome innovation in lancelets might be explained by high rate of gene prediction errors

    PubMed Central

    Bányai, László; Patthy, László

    2016-01-01

    A recent analysis of the genomes of Chinese and Florida lancelets has concluded that the rate of creation of novel protein domain combinations is orders of magnitude greater in lancelets than in other metazoa and it was suggested that continuous activity of transposable elements in lancelets is responsible for this increased rate of protein innovation. Since morphologically Chinese and Florida lancelets are highly conserved, this finding would contradict the observation that high rates of protein innovation are usually associated with major evolutionary innovations. Here we show that the conclusion that the rate of proteome innovation is exceptionally high in lancelets may be unjustified: the differences observed in domain architectures of orthologous proteins of different amphioxus species probably reflect high rates of gene prediction errors rather than true innovation. PMID:27476717

  17. A New and Innovative Use of the Thermal Knife and Kevlar Cord Components in a Restraint and Release System

    NASA Technical Reports Server (NTRS)

    Stewart, Alphonso; Brodeur, Stephen J. (Technical Monitor)

    2001-01-01

    A Kevlar cord and two thermal knives are key components in the Soar Array Restraint and Release System (SARRS) on the Microwave Anisotropy Probe (MAP) spacecraft at NASA's Goddard Space Flight Center. The SARRS uses a 25-foot (7.62 m) length Kevlar cord that encircles the spacecraft and secures the solar panels in stowed configuration for launch. Once in orbit, one of two redundantly configured thermal knives severs the Kevlar cord and permits the panels to deploy. The purpose of this paper is to present the details of the design, development test results, and the various innovations that were created during the development of this novel use of the thermal knife and Kevlar cord.

  18. Thermal stress in high temperature cylindrical fasteners

    NASA Technical Reports Server (NTRS)

    Blosser, Max L.

    1988-01-01

    Uninsulated structures fabricated from carbon or silicon-based materials, which are allowed to become hot during flight, are attractive for the design of some components of hypersonic vehicles. They have the potential to reduce weight and increase vehicle efficiency. Because of manufacturing contraints, these structures will consist of parts which must be fastened together. The thermal expansion mismatch between conventional metal fasteners and carbon or silicon-based structural materials may make it difficult to design a structural joint which is tight over the operational temperature range without exceeding allowable stress limits. In this study, algebraic, closed-form solutions for calculating the thermal stresses resulting from radial thermal expansion mismatch around a cylindrical fastener are developed. These solutions permit a designer to quickly evaluate many combinations of materials for the fastener and the structure. Using the algebraic equations developed, material properties and joint geometry were varied to determine their effect on thermal stresses. Finite element analyses were used to verify that the closed-form solutions derived give the correct thermal stress distribution around a cylindrical fastener and to investigate the effect of some of the simplifying assumptions made in developing the closed-form solutions for thermal stresses.

  19. High-Stakes & Assessment Innovation: A Negative Correlation? Research Report.

    ERIC Educational Resources Information Center

    Ananda, Sri; Rabinowitz, Stanley

    This paper makes the case that, as implemented so far, there has been an inverse correlation between innovation and accountability in statewide assessment systems. The higher the stakes attached to the assessment results, the more conservative the assessment methodology ultimately used. Case studies of two state assessment programs were carried…

  20. Thermal Cyclic Behavior of Thermal and Environmental Barrier Coatings Investigated Under High-Heat-Flux Conditions

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Lee, Kang N.; Miller, Robert A.

    2002-01-01

    Environmental barrier coatings (EBC's) have been developed to protect silicon-carbide- (SiC) based ceramic components in gas turbine engines from high-temperature environmental attack. With continuously increasing demands for significantly higher engine operating temperature, future EBC systems must be designed for both thermal and environmental protection of the engine components in combustion gases. In particular, the thermal barrier functions of EBC's become a necessity for reducing the engine-component thermal loads and chemical reaction rates, thus maintaining the required mechanical properties and durability of these components. Advances in the development of thermal and environmental barrier coatings (TBC's and EBC's, respectively) will directly impact the successful use of ceramic components in advanced engines. To develop high-performance coating systems, researchers must establish advanced test approaches. In this study, a laser high-heat-flux technique was employed to investigate the thermal cyclic behavior of TBC's and EBC's on SiC-reinforced SiC ceramic matrix composite substrates (SiC/SiC) under high thermal gradient and thermal cycling conditions. Because the laser heat flux test approach can monitor the coating's real-time thermal conductivity variations at high temperature, the coating thermal insulation performance, sintering, and delamination can all be obtained during thermal cycling tests. Plasma-sprayed yttria-stabilized zirconia (ZrO2-8 wt% Y2O3) thermal barrier and barium strontium aluminosilicate-based environmental barrier coatings (BSAS/BSAS+mullite/Si) on SiC/SiC ceramic matrix composites were investigated in this study. These coatings were laser tested in air under thermal gradients (the surface and interface temperatures were approximately 1482 and 1300 C, respectively). Some coating specimens were also subject to alternating furnace cycling (in a 90-percent water vapor environment at 1300 C) and laser thermal gradient cycling tests

  1. Thermal Regime of High-power Laser Diodes

    NASA Astrophysics Data System (ADS)

    Bezotosnyi, V. V.; Krokhin, O. N.; Oleshchenko, V. A.; Pevtsov, V. F.; Popov, Yu. M.; Cheshev, E. A.

    We discuss the design and application perspectives of different crystal, ceramic and composite-type submounts with thermo-compensating properties as well as submounts from materials with high thermal conductivity for overcoming thermal problem in high-power laser diodes (LD) and improving thermal management of other high-power optoelectronic and electronic semiconductor devices. Thermal fields in high-power laser diodes were calculated in 3 D thermal model at CW operation for some heatsink designs taking into account the experimental dependence of laser total efficiency against pumping current in order to extend the range of reliable operation up to thermal loads 20-30 W and corresponding output optical power up to 15-20 W for 100 μm stripe laser diodes.

  2. Innovative Airbreathing Propulsion Concepts for High-speed Applications

    NASA Technical Reports Server (NTRS)

    Whitlow, Woodrow, Jr.

    2002-01-01

    The current cost to launch payloads to low earth orbit (LEO) is approximately loo00 U.S. dollars ($) per pound ($22000 per kilogram). This high cost limits our ability to pursue space science and hinders the development of new markets and a productive space enterprise. This enterprise includes NASA's space launch needs and those of industry, universities, the military, and other U.S. government agencies. NASA's Advanced Space Transportation Program (ASTP) proposes a vision of the future where space travel is as routine as in today's commercial air transportation systems. Dramatically lower launch costs will be required to make this vision a reality. In order to provide more affordable access to space, NASA has established new goals in its Aeronautics and Space Transportation plan. These goals target a reduction in the cost of launching payloads to LEO to $lo00 per pound ($2200 per kilogram) by 2007 and to $100' per pound by 2025 while increasing safety by orders of magnitude. Several programs within NASA are addressing innovative propulsion systems that offer potential for reducing launch costs. Various air-breathing propulsion systems currently are being investigated under these programs. The NASA Aerospace Propulsion and Power Base Research and Technology Program supports long-term fundamental research and is managed at GLenn Research Center. Currently funded areas relevant to space transportation include hybrid hyperspeed propulsion (HHP) and pulse detonation engine (PDE) research. The HHP Program currently is addressing rocket-based combined cycle and turbine-based combined cycle systems. The PDE research program has the goal of demonstrating the feasibility of PDE-based hybrid-cycle and combined cycle propulsion systems that meet NASA's aviation and access-to-space goals. The ASTP also is part of the Base Research and Technology Program and is managed at the Marshall Space Flight Center. As technologies developed under the Aerospace Propulsion and Power Base

  3. High Thermal Conductivity Aligned Polyethylene-Graphene Nanocomposites

    NASA Astrophysics Data System (ADS)

    Garg, Jivtesh; Saeidijavash, Mortaza

    We investigate enhancement of thermal conductivity in polyethylene-graphene nanocomposites. The effect of alignment of both the polymer chains and the dispersed graphene flakes on thermal conductivity enhancement will be reported. In this work nanocomposites are prepared through microextrusion of polyethylene pellets and graphene nanopowder. Alignment is achieved through mechanical stretching of the nanocomposites. Thermal conductivity is measured using both Angstrom method and Laser flash. Variables involved in the study are the draw ratio and the weight percentage of graphene nanopowder. Results will shed light on the role of alignment of graphene flakes on enhancing thermal transport and provide new avenues to achieve ultra-high thermal conductivity in polymeric materials.

  4. Flexible Fabrics with High Thermal Conductivity for Advanced Spacesuits

    NASA Technical Reports Server (NTRS)

    Trevino, Luis A.; Bue, Grant; Orndoff, Evelyne; Kesterson, Matt; Connel, John W.; Smith, Joseph G., Jr.; Southward, Robin E.; Working, Dennis; Watson, Kent A.; Delozier, Donovan M.

    2006-01-01

    This paper describes the effort and accomplishments for developing flexible fabrics with high thermal conductivity (FFHTC) for spacesuits to improve thermal performance, lower weight and reduce complexity. Commercial and additional space exploration applications that require substantial performance enhancements in removal and transport of heat away from equipment as well as from the human body can benefit from this technology. Improvements in thermal conductivity were achieved through the use of modified polymers containing thermally conductive additives. The objective of the FFHTC effort is to significantly improve the thermal conductivity of the liquid cooled ventilation garment by improving the thermal conductivity of the subcomponents (i.e., fabric and plastic tubes). This paper presents the initial system modeling studies, including a detailed liquid cooling garment model incorporated into the Wissler human thermal regulatory model, to quantify the necessary improvements in thermal conductivity and garment geometries needed to affect system performance. In addition, preliminary results of thermal conductivity improvements of the polymer components of the liquid cooled ventilation garment are presented. By improving thermal garment performance, major technology drivers will be addressed for lightweight, high thermal conductivity, flexible materials for spacesuits that are strategic technical challenges of the Exploration

  5. Microbial Biosignatures in High Iron Thermal Springs

    NASA Astrophysics Data System (ADS)

    Parenteau, M. N.; Embaye, T.; Jahnke, L. L.; Cady, S. L.

    2003-12-01

    The emerging anoxic source waters at Chocolate Pots hot springs in Yellowstone National Park contain 2.6 to 11.2 mg/L Fe(II) and are 51-54° C and pH 5.5-6.0. These waters flow down the accumulating iron deposits and over three major phototrophic mat communities: Synechococcus/Chloroflexus at 51-54° C, Pseudanabaena at 51-54° C, and a narrow Oscillatoria at 36-45° C. We are assessing the contribution of the phototrophs to biosignature formation in this high iron system. These biosignatures can be used to assess the biological contribution to ancient iron deposits on Earth (e.g. Precambrian Banded Iron Formations) and, potentially, to those found on Mars. Most studies to date have focused on chemotrophic iron-oxidizing communities; however, recent research has demonstrated that phototrophs have a significant physiological impact on these iron thermal springs (Pierson et al. 1999, Pierson and Parenteau 2000, and Trouwborst et al., 2003). We completed a survey of the microfossils, biominerals, biofabrics, and lipid biomarkers in the phototrophic mats and stromatolitic iron deposits using scanning and transmission electron microscopy (SEM and TEM), energy dispersive spectrometry (EDS), powder X-ray diffraction (XRD), and gas chromatography-mass spectroscopy (GC-MS). The Synechococcus/Chloroflexus mat was heavily encrusted with iron silicates while the narrow Oscillatoria mat was encrusted primarily with iron oxides. Encrustation of the cells increased with depth in the mats. Amorphous 2-line ferrihydrite is the primary precipitate in the spring and the only iron oxide mineral associated with the mats. Goethite, hematite, and siderite were detected in dry sediment samples on the face of the main iron deposit. Analysis of polar lipid fatty acid methyl esters (FAME) generated a suite of lipid biomarkers. The Synechococcus/Chloroflexus mat contained two mono-unsaturated isomers of n-C18:1 with smaller amounts of polyunsaturated n-C18:2, characteristic of cyanobacteria

  6. The Origin of High Thermal Conductivity and Ultralow Thermal Expansion in Copper-Graphite Composites.

    PubMed

    Firkowska, Izabela; Boden, André; Boerner, Benji; Reich, Stephanie

    2015-07-01

    We developed a nanocomposite with highly aligned graphite platelets in a copper matrix. Spark plasma sintering ensured an excellent copper-graphite interface for transmitting heat and stress. The resulting composite has superior thermal conductivity (500 W m(-1) K(-1), 140% of copper), which is in excellent agreement with modeling based on the effective medium approximation. The thermal expansion perpendicular to the graphite platelets drops dramatically from ∼20 ppm K(-1) for graphite and copper separately to 2 ppm K(-1) for the combined structure. We show that this originates from the layered, highly anisotropic structure of graphite combined with residual stress under ambient conditions, that is, strain-engineering of the thermal expansion. Combining excellent thermal conductivity with ultralow thermal expansion results in ideal materials for heat sinks and other devices for thermal management. PMID:26083322

  7. Simple high-temperature thermal diffusivity apparatus

    NASA Technical Reports Server (NTRS)

    Wood, C.; Zoltan, A.

    1984-01-01

    A simple and inexpensive thermal diffusivity apparatus is described for measurement up to 1600 K. The novel features of apparatus include a light pipe, a long furnace, and a differential thermocouple. A low heat-load sample holder for clamping the sample in a vertical position is also described. The results of measurements on AXM-5Q graphite are reported.

  8. Thermal barrier coating having high phase stability

    DOEpatents

    Subramanian, Ramesh

    2002-01-01

    A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating characterized by a microstructure having gaps (28) where the thermal barrier coating comprises a first thermal barrier layer (40), and a second thermal barrier layer (30) with a pyrochlore crystal structure having a chemical formula of A.sup.n+.sub.2-x B.sup.m+.sub.2+x O.sub.7-y, where A is selected from the group of elements consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof, where B is selected from the group of elements consisting of Zr, Hf, Ti and mixtures thereof, where n and m are the valence of A and B respectively, and for -0.5.ltoreq.x.ltoreq.0.5, ##EQU1## and excluding the following combinations for x=0, y=0: A=La and B=Zr; A=La and B=Hf; A=Gd and B=Hf; and A=Yb and B=Ti.

  9. Thermal Shock Behavior of Single Crystal Oxide Refractive Concentrators for High Temperatures Solar Thermal Propulsion

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Choi, Sung R.; Jacobson, Nathan S.; Miller, Robert A.

    1999-01-01

    Single crystal oxides such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium-aluminum-garnet (Y3Al5O12, or YAG), magnesium oxide (MgO) and sapphire (Al2O3) have been considered as refractive secondary concentrator materials for high temperature solar propulsion applications. However, thermal mechanical reliability of the oxide components in severe thermal environments during space mission sun/shade transitions is of great concern. In this paper, critical mechanical properties of these oxide crystals are determined by the indentation technique. Thermal shock resistance of the oxides is evaluated using a high power CO, laser under high temperature-high thermal gradients. Thermal stress fracture behavior and failure mechanisms of these oxide materials are investigated under various temperature and heating conditions.

  10. [The venture financing of scientifically-innovative projects: teaching experience in medical high school].

    PubMed

    Grachev, S V; Gorodnova, E A

    2008-01-01

    The authors presented an original material, devoted to first experience of teaching of theoretical bases of venture financing of scientifically-innovative projects in medical high school. The results and conclusions were based on data of the questionnaire performed by the authors. More than 90% of young scientist physicians recognized actuality of this problem for realization of their research work results into practice. Thus, experience of teaching of theoretical bases of venture financing of scientifically-innovative projects in medical high school proves reasonability of further development and inclusion the module "The venture financing of scientifically-innovative projects in biomedicine" in the training plan. PMID:18589734

  11. HIGH VOLTAGE ENVIRONMENTAL APPLICATIONS, INC.ELECTRON BEAM TECHNOLOGY - INNOVATIVE TECHNOLOGY EVALUATION REPORT

    EPA Science Inventory

    This report evaluates a high-voltage electron beam (E-beam) technology's ability to destroy volatile organic compounds (VOCs) and other contaminants present in liquid wastes. Specifically, this report discusses performance and economic data from a Superfund Innovative Technology...

  12. An Innovative Approach To Teaching High School Students about Indoor Air Quality.

    ERIC Educational Resources Information Center

    Neumann, Catherine M.; Bloomfield, Molly M.; Harding, Anna K.; Sherburne, Holly

    1999-01-01

    Describes an innovative approach used to help high school students develop critical thinking and real-world problem-solving skills while learning about indoor air quality. (Contains 13 references.) (Author/WRM)

  13. Factor Pattern Comparisons of EPPS Scales of High School, College, and Innovative College Program Students

    ERIC Educational Resources Information Center

    Dixon, Paul W.; Ahern, Elsie H.

    1973-01-01

    EPPS scores from 167 high school seniors (Study 1, S1), 137 introductory psychology students (S2), and students from an innovative college program (S3) were compared using analysis of variance, image analysis, and factor pattern comparison. (Editor)

  14. WSN system design by using an innovative neural network model to perform thermals forecasting in a urban canyon scenario

    NASA Astrophysics Data System (ADS)

    Giuseppina, Nicolosi; Salvatore, Tirrito

    2015-12-01

    Wireless Sensor Networks (WSNs) were studied by researchers in order to manage Heating, Ventilating and Air-Conditioning (HVAC) indoor systems. WSN can be useful specially to regulate indoor confort in a urban canyon scenario, where the thermal parameters vary rapidly, influenced by outdoor climate changing. This paper shows an innovative neural network approach, by using WSN data collected, in order to forecast the indoor temperature to varying the outdoor conditions based on climate parameters and boundary conditions typically of urban canyon. In this work more attention will be done to influence of traffic jam and number of vehicles in queue.

  15. Design and modelling of an innovative three-stage thermal storage system for direct steam generation CSP plants

    NASA Astrophysics Data System (ADS)

    Garcia, Pierre; Vuillerme, Valéry; Olcese, Marco; El Mourchid, Nadim

    2016-05-01

    Thermal Energy Storage systems (TES) for a Direct Steam Generation (DSG) solar plant feature preferably three stages in series including a latent heat storage module so that steam can be recovered with a limited temperature loss. The storage system designed within the Alsolen Sup project is characterized by an innovative combination of sensible and latent modules. A dynamic model of this three-stage storage has been developed and applied to size the storage system of the Alsolen Sup® plant demonstrator at CEA Cadarache. Results of this simulation show that this promising concept is an efficient way to store heat in DSG solar plants.

  16. High speed heterodyne infrared thermography applied to thermal diffusivity identification

    NASA Astrophysics Data System (ADS)

    Pradere, C.; Clerjaud, L.; Batsale, J. C.; Dilhaire, S.

    2011-05-01

    We have combined InfraRed thermography and thermal wave techniques to perform microscale, ultrafast (microsecond) temperature field measurements. The method is based on an IR camera coupled to a microscope and synchronized to the heat source by means of phase locked function generators. The principle is based on electronic stroboscopic sampling where the low IR camera acquisition frequency facq (25 Hz) undersamples a high frequency thermal wave. This technique permits the measurement of the emissive thermal response at a (microsecond) short time scale (microsecond) with the full frame mode of the IR camera with a spatial thermal resolution of 7 μm. Then it becomes possible to study 3D transient heat transfer in heterogeneous and high thermal conductive thin layers. Thus it is possible for the first time in our knowledge to achieve temperature field measurements in heterogeneous media within a wide range of time domains. The IR camera is now a suitable instrument for multiscale thermal analysis.

  17. Development of Mitsubishi High Thermal Performance Grid

    NASA Astrophysics Data System (ADS)

    Ikeda, Kazuo; Hoshi, Masaya

    Mitsubishi has developed a new zircalloy grid spacer for PWR fuel with higher thermal performance. Computational Fluid Dynamics (CFD) evaluation method has been applied for designing of the new lower pressure loss and higher Departure from Nucleate Boiling (DNB) benefit grid spacer. Reduction of pressure loss of grid structures has been examined by CFD. Also, CFD has been developed as a design tool to predict the coolant mixing ability of vane structures, which is to compare the relative peak spot temperatures around fuel rods at the same heat flux condition. Prototype grids were manufactured and several tests, which were pressure loss measurements, cross-flow measurements and freon DNB tests, were conducted to verify CFD predictions. It is concluded that the applicability of the CFD evaluation method for the thermal hydraulic design of the grid is confirmed.

  18. Thermal distribution in high power optical devices with power-law thermal conductivity

    NASA Astrophysics Data System (ADS)

    Zhou, Chuanle; Grayson, M.

    2012-01-01

    We introduce a power-law approximation to model non-linear ranges of the thermal conductivity, and under this approximation derive a simple analytical expression for calculating the temperature profile in high power quantum cascade lasers and light emitting diodes. The thermal conductivity of a type II InAs/GaSb superlattice (T2SL) is used as an example, having negative or positive power-law exponents depending on the thermal range of interest. The result is an increase or decrease in the temperature, respectively, relative to the uniform thermal conductivity assumption.

  19. High Growth Rate YSZ Thermal Barrier Coatings Deposited by MOCVD Demonstrate High Thermal Cycling Lifetime

    SciTech Connect

    Varanasi, Venu G; Besmann, Theodore M; Payzant, E Andrew; Pint, Bruce A; Lothian, Janet L; Anderson, Timothy J

    2011-01-01

    Yttria-stabilized zirconia (YSZ) thermal barrier coatings (TBC) were prepared by metalorganic chemical vapor deposition (MOCVD) using Y(OBut{sup n}){sub 3}, Zr(OBut{sup n}){sub 4} precursors and O{sub 2} carrier gas. A thermodynamic analysis guided experiments by optimizing elemental molar (n) stoichiometric ratios for the (Zr-Y-O-C-H system). This analysis showed single-phase YSZ was favored at 950 C, 1 kPa, n{sub O}/(n{sub Y} + n{sub Zr}) > 30, n{sub Y}/(n{sub Y} + n{sub Zr}) = 0.06-0.10 (fixed n{sub C}, n{sub H}). Experimental YSZ growth had multiple phases (fcc, monoclinic), had a relatively high growth rate (43 {micro}m/h, 1005 C), had an Arrhenius dependence (845-950 C, E{sub a} = 53.8 {+-} 7.9 kJ/mol), had columnar grains (SEM analysis), and had a coating through-thickness n{sub Y}/(n{sub Y} + n{sub Zr}) = 0.04 (EPMA analysis). Doubling the inlet yttrium precursor mole fraction resulted in fcc YSZ growth with a coating through-thickness n{sub Y}/(n{sub Y} + n{sub Zr}) = 0.07. Hot-insertion thermal cycling of YSZ coatings on FeCrAlY bond coats showed >1000 h lifetime, matching current standards for EB-PVD YSZ coatings.

  20. High performance thermal imaging for the 21st century

    NASA Astrophysics Data System (ADS)

    Clarke, David J.; Knowles, Peter

    2003-01-01

    In recent years IR detector technology has developed from early short linear arrays. Such devices require high performance signal processing electronics to meet today's thermal imaging requirements for military and para-military applications. This paper describes BAE SYSTEMS Avionics Group's Sensor Integrated Modular Architecture thermal imager which has been developed alongside the group's Eagle 640×512 arrays to provide high performance imaging capability. The electronics architecture also supprots High Definition TV format 2D arrays for future growth capability.

  1. Measuring Thermal Diffusivity Of A High-Tc Superconductor

    NASA Technical Reports Server (NTRS)

    Powers, Charles E.; Oh, Gloria; Leidecker, Henning

    1992-01-01

    Technique for measuring thermal diffusivity of superconductor of high critical temperature based on Angstrom's temperature-wave method. Peltier junction generates temperature oscillations, which propagate with attenuation up specimen. Thermal diffusivity of specimen calculated from distance between thermocouples and amplitudes and phases of oscillatory components of thermocouple readings.

  2. Long life high reliability thermal control systems study data handbook

    NASA Technical Reports Server (NTRS)

    Scollon, T. R., Jr.; Carpitella, M. J.

    1971-01-01

    The development of thermal control systems with high reliability and long service life is discussed. Various passive and semi-active thermal control systems which have been installed on space vehicles are described. The properties of the various coatings are presented in tabular form.

  3. High-Resolution Thermal Inertia Mapping from the Mars Global Surveyor Thermal Emission Spectrometer

    USGS Publications Warehouse

    Mellon, M.T.; Jakosky, B.M.; Kieffer, H.H.; Christensen, P.R.

    2000-01-01

    High-resolution thermal inertia mapping results are presented, derived from Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) observations of the surface temperature of Mars obtained during the early portion of the MGS mapping mission. Thermal inertia is the key property controlling the diurnal surface temperature variations, and is dependent on the physical character of the top few centimeters of the surface. It represents a complex combination of particle size, rock abundance, exposures of bedrock, and degree of induration. In this work we describe the derivation of thermal inertia from TES data, present global scale analysis, and place these results into context with earlier work. A global map of nighttime thermal-bolometer-based thermal inertia is presented at 14?? per pixel resolution, with approximately 63% coverage between 50??S and 70??N latitude. Global analysis shows a similar pattern of high and low thermal inertia as seen in previous Viking low-resolution mapping. Significantly more detail is present in the high-resolution TES thermal inertia. This detail represents horizontal small-scale variability in the nature of the surface. Correlation with albedo indicates the presence of a previously undiscovered surface unit of moderate-to-high thermal inertia and intermediate albedo. This new unit has a modal peak thermal inertia of 180-250 J m-2 K-1 s-12 and a narrow range of albedo near 0.24. The unit, covering a significant fraction of the surface, typically surrounds the low thermal inertia regions and may comprise a deposit of indurated fine material. Local 3-km-resolution maps are also presented as examples of eolian, fluvial, and volcanic geology. Some impact crater rims and intracrater dunes show higher thermal inertias than the surrounding terrain; thermal inertia of aeolian deposits such as intracrater dunes may be related to average particle size. Outflow channels and valleys consistently show higher thermal inertias than the

  4. Kapitza thermal resistance studied by high-frequency photothermal radiometry

    NASA Astrophysics Data System (ADS)

    Horny, Nicolas; Chirtoc, Mihai; Fleming, Austin; Hamaoui, Georges; Ban, Heng

    2016-07-01

    Kapitza thermal resistance is determined using high-frequency photothermal radiometry (PTR) extended for modulation up to 10 MHz. Interfaces between 50 nm thick titanium coatings and silicon or stainless steel substrates are studied. In the used configuration, the PTR signal is not sensitive to the thermal conductivity of the film nor to its optical absorption coefficient, thus the Kapitza resistance is directly determined from single thermal parameter fits. Results of thermal resistances show the significant influence of the nature of the substrate, as well as of the presence of free electrons at the interface.

  5. Thermal barrier coating having high phase stability

    DOEpatents

    Subramanian, Ramesh

    2001-01-01

    A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating layer (20) characterized by a microstructure having gaps (28) where the thermal barrier coating (20) consists essentially of a pyrochlore crystal structure having a chemical formula consisting essentially of A.sup.n+.sub.2-x B.sup.m+.sub.2+x O.sub.7-y, where A is selected from the group of elements selected from La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof; where B is selected from the group of elements selected from Zr, Hf, Ti and mixtures thereof; n and m are the valence of A and B respectively, and for -0.5.ltoreq.x.ltoreq.0.5, ##EQU1## and excluding the following combinations for x=0, y=0: A=La and B=Zr; A=La and B=Hf; A=Gd and B=Hf; and A=Yb and B=Ti.

  6. Investigation of Thermal High Cycle and Low Cycle Fatigue Mechanisms of Thick Thermal Barrier Coatings

    NASA Technical Reports Server (NTRS)

    Zhu, Dong-Ming; Miller, Robert A.

    1998-01-01

    Ceramic thermal barrier coatings have attracted increased attention for diesel engine applications. The advantages of using the ceramic coatings include a potential increase in efficiency and power density and a decrease in maintenance cost. Zirconia-based ceramics are the most important coating materials for such applications because of their low thermal conductivity, relatively high thermal expansivity and excellent mechanical properties. However, durability of thick thermal barrier coatings (TBCS) under severe temperature cycling encountered in engine conditions, remains a major question. The thermal transients associated with the start/stop and no-load/full-load engine cycle, and with the in-cylinder combustion process, generate thermal low cycle fatigue (LCF) and thermal high cycle fatigue (HCF) in the coating system. Therefore, the failure mechanisms of thick TBCs are expected to be quite different from those of thin TBCs under these temperature transients. The coating failure is related not only to thermal expansion mismatch and oxidation of the bond coats and substrates, but also to the steep thermal stress gradients induced in the coating systems. Although it has been reported that stresses generated by thermal transients can initiate surface and interface cracks in a coating system, the mechanisms of the crack propagation and of coating failure under the complex LCF and HCF conditions are still not understood. In this paper, the thermal fatigue behavior of an yttria partially stabilized zirconia coating system under simulated LCF and HCF engine conditions is investigated. The effects of LCF and HCF on surface crack initiation and propagation are also discussed.

  7. Highly anisotropic thermal conductivity of arsenene: An ab initio study

    NASA Astrophysics Data System (ADS)

    Zeraati, Majid; Vaez Allaei, S. Mehdi; Abdolhosseini Sarsari, I.; Pourfath, Mahdi; Donadio, Davide

    2016-02-01

    Elemental two-dimensional (2D) materials exhibit intriguing heat transport and phononic properties. Here we have investigated the lattice thermal conductivity of newly proposed arsenene, the 2D honeycomb structure of arsenic, using ab initio calculations. Solving the Boltzmann transport equation for phonons, we predict a highly anisotropic thermal conductivity of 30.4 and 7.8 W/mK along the zigzag and armchair directions, respectively, at room temperature. Our calculations reveal that phonons with mean free paths between 20 nm and 1 μ m provide the main contribution to the large thermal conductivity in the zigzag direction; mean free paths of phonons contributing to heat transport in the armchair directions range between 20 and 100 nm. The obtained anisotropic thermal conductivity and feasibility of synthesis, in addition to high electron mobility reported elsewhere, make arsenene a promising material for nanoelectronic applications and thermal management.

  8. Ultralow thermal conductivity in highly anion-defective aluminates.

    PubMed

    Wan, Chunlei; Qu, Zhixue; He, Yong; Luan, Dong; Pan, Wei

    2008-08-22

    Ultralow thermal conductivity (1.1 W/m.K, 1000 degrees C) in anion-deficient Ba2RAlO5 (R=Dy, Er, Yb) compounds was reported. The low thermal conductivity was then analyzed by kinetic theory. The highly defective structure of Ba2RAlO5 results in weak atomic bond strength and low sound speeds, and phonon scattering by large concentration of oxygen vacancies reduces the phonon mean free path to the order of interatomic distance. Ba2DyAlO5 exhibits the shortest phonon mean free path and lowest thermal conductivity among the three compositions investigated, which can be attributed to additional phonon scattering by DyO6 octahedron tilting as a result of a low tolerance factor. The Ba2RAlO5 (R=Dy, Er, Yb) compounds have shown great potential in high-temperature thermal insulation applications, particularly as a thermal barrier coating material. PMID:18764638

  9. High thermal conductivity lossy dielectric using a multi layer configuration

    DOEpatents

    Tiegs, Terry N.; Kiggans, Jr., James O.

    2003-01-01

    Systems and methods are described for loss dielectrics. A loss dielectric includes at least one high dielectric loss layer and at least one high thermal conductivity-electrically insulating layer adjacent the at least one high dielectric loss layer. A method of manufacturing a loss dielectric includes providing at least one high dielectric loss layer and providing at least one high thermal conductivity-electrically insulating layer adjacent the at least one high dielectric loss layer. The systems and methods provide advantages because the loss dielectrics are less costly and more environmentally friendly than the available alternatives.

  10. Innovations in high-pressure liquid injection technique for gas chromatography: pressurized liquid injection system.

    PubMed

    Luong, Jim; Gras, Ronda; Tymko, Richard

    2003-01-01

    In gas chromatography (GC), highly volatile liquefied hydrocarbons are commonly injected using devices such as high-pressure syringes, piston valves, liquid rotary sampling valves, or vaporizing regulators. Although these techniques are adequate in some cases, there are known deficiencies. A new generation of sampling valve has been recently innovated and commercialized. Some of the highlights of the pressurized liquid injection system (PLIS) include compact size, the capability to directly couple to an injection port without the need for preinjection vaporization and transfer lines, and sample sizes ranging from 0.2 to 2.0 micro L. Although the valve has a specification of helium leak-free rating of 82.7 bar (1200 psig), the valve passes a hydrostatic pressure test of up to 414 bar (6000 psig). In the unheated version of PLIS, vaporization of solutes occur mainly because of the sheering effect of carrier gas in combination with thermal energy drawn from an injection port or a heated adaptor. This was found to be adequate for solutes with high to medium volatility of up to nC14 hydrocarbon. A higher molecular weight range of up to nC44 hydrocarbon can be achieved with the implementation of a heated version of PLIS, in which the channel of the shaft can be resistively heated at a rate of up to 400 degrees C/s. With its first introduction in May 2002, PLIS has gained acceptance amongst practitioners in GC because it addresses a key unarticulated need in sample introduction/enrichment and by specifically targeting many deficiencies encountered in contemporary high-pressure injection devices. In this paper, the design and performance of the various valve systems of PLIS, as well as industrial chromatographic applications, is presented. PMID:14629794

  11. High reflector absorptance measurements by the surface thermal lensing technique

    SciTech Connect

    Chow, R.; Taylor, J.R.; Wu, Z.L.; Krupka, R.; Yang, T.

    1996-11-01

    Surface thermal lensing is an alternate configuration of a photothermal deflection system that was used to measure low levels of optical absorption. The thermal lensing configuration facilitated the alignment of the pump and probe laser beams by using a larger diameter probe beam. This technique was applied to high performance optical coatings, specifically high reflectors at 511 nm, zero degrees angle of incidence. The absorptance of these coatings was previously measured using a high power copper vapor laser system. A high power copper laser beam is focused onto a -2 mm diameter spot. A thermal camera senses the temperature rise with respect to the rest of the coating. The temperature change, power density and beam diameter were used with an empirical formula that yields optical absorption. The surface thermal lensing technique was able to resolve absorption levels lower than that achieved with the copper laser method.

  12. Fibers innovative burning and reuse by Self-propagating High temperature Synthesis (SHS)

    NASA Astrophysics Data System (ADS)

    Caratto, Valentina; Belfortini, Claudio; Musi, Luigi; Gaggero, Laura; Ferretti, Maurizio

    2016-04-01

    The treatment of asbestos containing waste deriving from civil building and industrial applications is a social alert and an environmental problem. The project LIFE12 ENV/IT 000295 FIBERS "Fibers innovative burning and reuse by Self-propagating High temperature Synthesis (SHS)" has developed an innovative technique alternative to conventional high T processes. The University of Genoa has developed an apparatus and a technique for triggering the breakdown reaction of chrysotile by means of an alumino-thermic reaction in a process of combustion synthesis well known as Self-propagating High temperature Synthesis or SHS. This approach yielded interesting results and allowed the development of an efficient method for inerting natural asbestos fibers and man-made products carrying fibers at the scale of some grams [1]. The experiments were based on the couples Fe2O3/Mg by implementation of two prototype plants. The varying parameters were: 1) different Asbestos-Containing Waste (ACW) massive (Eternit, linoleum) and friable asbestos; 2) ACW abundance; 3) size of the pellet 4) under two triggering systems (induction by a W coil and oxyacetylene torch). The reactions were carried in two configurations: a) discontinuous, allowed us to obtain data for the development and fine-tuning of the reaction, b) continuous, was indispensable for the development and fine-tuning of the process parameters towards industrial scale up. After the combustive reaction all samples were characterized by SEM-EDS and XRPD analysis. All experiments demonstrated effective in destructing the fibrous habit of chrysotile, turning its composition to stubby olivine grains. We optimized the parameters to achieve complete conversion of the asbestos to mineral grains in all the cases. The efficiency of the SHS reaction in the discontinuous and continuous configurations was highlighted by the characterization of the post-combustion material under SEM-EDS and XRPD that verified the absence of fibers within

  13. A high temperature molten salt thermal electrochemical cell

    NASA Astrophysics Data System (ADS)

    Plichta, Edward J.; Behl, Wishvender K.

    1990-02-01

    This invention relates in general to a high temperature molten salt thermal electrochemical cell and in particular to such a cell including cobalt oxide (Co3O4) as the cathode material. High temperature molten salt thermal electrochemical cells are widely used as power sources for projectiles, rockets, bombs, mines, missiles, decoys, jammers, and torpedoes. These are also used as fuses. Thermal electrochemical cells are reserve-type cells that can be activated by heating with a pyrotechnic heat source such as zirconium and barium chromate powders or mixtures of iron powder and potassium perchlorate.

  14. High Density Thermal Energy Storage with Supercritical Fluids

    NASA Technical Reports Server (NTRS)

    Ganapathi, Gani B.; Wirz, Richard

    2012-01-01

    A novel approach to storing thermal energy with supercritical fluids is being investigated, which if successful, promises to transform the way thermal energy is captured and utilized. The use of supercritical fluids allows cost-affordable high-density storage with a combination of latent heat and sensible heat in the two-phase as well as the supercritical state. This technology will enhance penetration of several thermal power generation applications and high temperature water for commercial use if the overall cost of the technology can be demonstrated to be lower than the current state-of-the-art molten salt using sodium nitrate and potassium nitrate eutectic mixtures.

  15. Thermal High- and Low-Cycle Fatigue Behavior of Thick Thermal Barrier Coating Systems

    NASA Technical Reports Server (NTRS)

    Miller, Robert A.

    1998-01-01

    Ceramic thermal barrier coatings have received increasing attention for advanced gas turbine and diesel engine applications because of their ability to provide thermal insulation to engine components. However, the durability of these coatings under the severe thermal cycling conditions encountered in a diesel engine (ref. 1) still remains a major issue. In this research at the NASA Lewis Research Center, a high-power laser was used to investigate the thermal fatigue behavior of a yttria-stabilized zirconia coating system under simulated diesel engine conditions. The mechanisms of fatigue crack initiation and propagation, and of coating failure under complex thermal low-cycle fatigue (LCF, representing stop/start cycles) and thermal high-cycle fatigue (HCF, representing operation at 1300 rpm) are described. Continuous wave and pulse laser modes were used to simulate pure LCF and combined LCF/HCF, respectively (ref. 2). The LCF mechanism was found to be closely related to the coating sintering and creep at high temperatures. These creep strains in the ceramic coating led to a tensile stress state during cooling, thus providing the major driving force for crack growth under LCF conditions. The combined LCF/HCF tests induced more severe coating surface cracking, microspallation, and accelerated crack growth than did the pure LCF test. HCF thermal loads also facilitated lateral crack branching and ceramic/bond coat interface delaminations. HCF is associated with the cyclic stresses originating from the high-frequency temperature fluctuation at the ceramic coating surface. The HCF thermal loads act on the crack by a wedging mechanism (ref. 1), resulting in continuous crack growth at temperature. The HCF stress intensity factor amplitude increases with the interaction depth and temperature swing, and decreases with the crack depth. HCF damage also increases with the thermal expansion coefficient and the Young's modulus of the ceramic coating (refs. 1 and 3).

  16. Applications of high thermal conductivity composites to electronics and spacecraft thermal design

    NASA Technical Reports Server (NTRS)

    Sharp, G. Richard; Loftin, Timothy A.

    1990-01-01

    Recently, high thermal conductivity graphite fiber-reinforced metal matrix composites (MMCs) have become available that can save weight over present methods of heat conduction. Another significant advantage is that these materials can be used without the plumbing and testing complexities that accompany the use of liquid heat pipes. A spinoff of this research was the development of other MMCs as electronic device heat sinks. These use particulates rather than fibers and are formulated to match the coefficient of thermal expansion of electronic substrates in order to alleviate thermally induced stresses. The development of both types of these materials as viable weight-saving substitutes for the traditional methods of thermal control for electronics packaging and also for spacecraft thermal control applications are the subjects of this report.

  17. Innovative Miniaturized Heat Pumps for Buildings: Modular Thermal Hub for Building Heating, Cooling and Water Heating

    SciTech Connect

    2010-09-01

    BEETIT Project: Georgia Tech is using innovative components and system design to develop a new type of absorption heat pump. Georgia Tech’s new heat pumps are energy efficient, use refrigerants that do not emit greenhouse gases, and can run on energy from combustion, waste heat, or solar energy. Georgia Tech is leveraging enhancements to heat and mass transfer technology possible in microscale passages and removing hurdles to the use of heat-activated heat pumps that have existed for more than a century. Use of microscale passages allows for miniaturization of systems that can be packed as monolithic full-system packages or discrete, distributed components enabling integration into a variety of residential and commercial buildings. Compared to conventional heat pumps, Georgia Tech’s design innovations will create an absorption heat pump that is much smaller, has higher energy efficiency, and can also be mass produced at a lower cost and assembly time.

  18. OVERVIEW OF CONVENTIONAL AND INNOVATIVE LAND-BASED THERMAL TECHNOLOGIES FOR WASTE DISPOSAL

    EPA Science Inventory

    For more than the past two decades, the USEPA has been aggressive in its research, development, performance testing, and in encouragement of the regulated use of proven thermal destruction (or incineration) technologies for the environmentally acceptable treatment and disposal of...

  19. Development and Demonstration of an Innovative Thermal Energy Storage System for Baseload Power Generation

    SciTech Connect

    Goswami, D. Yogi

    2012-09-04

    The objective of this project is to research and develop a thermal energy storage system (operating range 300°C - 450°C) based on encapsulated phase change materials (PCM) that can meet the utility-scale base-load concentrated solar power plant requirements at much lower system costs compared to the existing thermal energy storage (TES) concepts. The major focus of this program is to develop suitable encapsulation methods for existing low-cost phase change materials that would provide a cost effective and reliable solution for thermal energy storage to be integrated in solar thermal power plants. This project proposes a TES system concept that will allow for an increase of the capacity factor of the present CSP technologies to 75% or greater and reduce the cost to less than $20/kWht.

  20. Experimental measurements of thermal properties of high-temperature refractory materials used for thermal energy storage

    NASA Astrophysics Data System (ADS)

    El-Leathy, Abdelrahman; Jeter, Sheldon; Al-Ansary, Hany; Abdel-Khalik, Said; Golob, Matthew; Danish, Syed Noman; Saeed, Rageh; Djajadiwinata, Eldwin; Al-Suhaibani, Zeyad

    2016-05-01

    This paper builds on studies conducted on thermal energy storage (TES) systems that were built as a part of the work performed for a DOE-funded SunShot project titled "High Temperature Falling Particle Receiver". In previous studies, two small-scale TES systems were constructed for measuring heat loss at high temperatures that are compatible with the falling particle receiver concept, both of which had shown very limited heat loss. Through the course of those studies, it became evident that there was a lack of information about the thermal performance of some of the insulating refractory materials used in the experiments at high temperatures, especially insulating firebrick and perlite concrete. This work focuses on determining the thermal conductivities of those materials at high temperatures. The apparatus consists of a prototype cylindrical TES bin built with the same wall construction used in previous studies. An electric heater is placed along the centerline of the bin, and thermocouples are used to measure temperature at the interfaces between all layers. Heat loss is measured across one of the layers whose thermal conductivity had already been well established using laboratory experiments. This value is used to deduce the thermal conductivity of other layers. Three interior temperature levels were considered; namely, 300°C, 500°C, and 700°C. Results show that the thermal conductivity of insulating firebrick remains low (approximately 0.22 W/m.K) at an average layer temperature as high as 640°C, but it was evident that the addition of mortar had an impact on its effective thermal conductivity. Results also show that the thermal conductivity of perlite concrete is very low, approximately 0.15 W/m.K at an average layer temperature of 360°C. This is evident by the large temperature drop that occurs across the perlite concrete layer. These results should be useful for future studies, especially those that focus on numerical modeling of TES bins.

  1. High-resolution QWIP thermal imager for AFV upgrade

    NASA Astrophysics Data System (ADS)

    Dahlberg, Anders G. M.

    2004-08-01

    Following on the success of the BIRC clip on thermal imaging sight for the BILL Anti-Tank Missile System, which was in fact the world's first military QWIP based thermal imager, and which has been successfully delivered to the Swedish Army in serial quantities, several new QWIP-based products from FLIR Systems AB in Sweden are now under contract for defense customers worldwide. These include the new Forward Observation Systems for Norway and Sweden, Airborne Search & Rescue Systems, and a new clip on thermal imager for the Bofors RBS 70 Air Defense Missile System. The latest of these products is the development of a High Resolution QWIP Thermal Imager, LIRC, under contract for an upgrade of a number of Swedish CV9040C Armored Fighting Vehicles for Swedish Army International Operations. The paper will focus on the rationale behind the system selection, the development of the military qualified QWIP Thermal Imagers and the current status of the program.

  2. Thermal Transport in High-Strength Polymethacrylimide (PMI) Foam Insulations

    NASA Astrophysics Data System (ADS)

    Qiu, L.; Zheng, X. H.; Zhu, J.; Tang, D. W.; Yang, S. Y.; Hu, A. J.; Wang, L. L.; Li, S. S.

    2015-11-01

    Thermal transport in high-strength polymethacrylimide (PMI) foam insulations is described, with special emphasis on the density and temperature effects on the thermal transport performance. Measurements of the effective thermal conductivity are performed by a freestanding sensor-based 3ω method. A linear relationship between the density and the effective thermal conductivity is observed. Based on the analysis of the foam insulation morphological structures and the corresponding geometrical cell model, the quantitative contribution of the solid conductivity and the gas conductivity as well as the radiative conductivity to the total effective thermal conductivity as a function of the density and temperature is calculated. The agreement between the curves of the results from the developed model and experimental data indicate the model can be used for PMI foam insulating performance optimization.

  3. Detection of a buried horizon with a high thermal diffusivity using thermal remote sensing

    NASA Technical Reports Server (NTRS)

    Nash, David B.

    1988-01-01

    A field investigation using thermal remote sensing was performed to test the feasibility of detecting the surface topography of granite bedrock beneath a thin cover of alluvium. Imagery of a region of the Mojave Desert were taken with an airborne multispectral scanner with thermal spectral bandwidths of 10.4 and 12.5 microns an instantaneous field of view of 2.5 mrad. It is suggested that a buried high thermal diffusivity horizon measurably lowers the surface temperature of the overlying lower diffusivity material during the peak of the annual heating cycle.

  4. High Road Partnerships Report: Innovations in Building Good Jobs and Strong Communities.

    ERIC Educational Resources Information Center

    American Federation of Labor and Congress of Industrial Organizations, Washington, DC. Working for America Inst.

    When deciding how to compete in the new global economy, employers can opt for "low-road" strategies such as low wages and no job security. Alternatively, they can choose the "high road" and compete by offering quality goods and services, innovation, and value. Fourteen successful "high-road" partnerships were examined to identify elements likely…

  5. Highly directional thermal emission from two-dimensional silicon structures.

    PubMed

    Ribaudo, Troy; Peters, David W; Ellis, A Robert; Davids, Paul S; Shaner, Eric A

    2013-03-25

    We simulate, fabricate, and characterize near perfectly absorbing two-dimensional grating structures in the thermal infrared using heavily doped silicon (HdSi) that supports long wave infrared surface plasmon polaritons (LWIR SPP's). The devices were designed and optimized using both finite difference time domain (FDTD) and rigorous coupled wave analysis (RCWA) simulation techniques to satisfy stringent requirements for thermal management applications requiring high thermal radiation absorption over a narrow angular range and low visible radiation absorption over a broad angular range. After optimization and fabrication, characterization was performed using reflection spectroscopy and normal incidence emissivity measurements. Excellent agreement between simulation and experiment was obtained. PMID:23546065

  6. Design of a High Thermal Gradient Bridgman Furnace

    NASA Technical Reports Server (NTRS)

    LeCroy, J. E.; Popok, D. P.

    1994-01-01

    The Advanced Automated Directional Solidification Furnace (AADSF) is a Bridgman-Stockbarger microgravity processing facility, designed and manifested to first fly aboard the second United States Microgravity Payload (USMP-2) Space Shuttle mission. The AADSF was principally designed to produce high axial thermal gradients, and is particularly suitable for metals solidification experiments, including non-dilute alloys. To accommodate a wider range of experimental conditions, the AADSF is equipped with a reconfigurable gradient zone. The overall design of the AADSF and the relationship between gradient zone design and furnace performance are described. Parametric thermal analysis was performed and used to select gradient zone design features that fulfill the high thermal gradient requirements of the USMP-2 experiment. The thermal model and analytical procedure, and parametric results leading to the first flight gradient zone configuration, are presented. Performance for the USMP-2 flight experiment is also predicted, and analysis results are compared to test data.

  7. High pressure elasticity and thermal properties of depleted uranium

    NASA Astrophysics Data System (ADS)

    Jacobsen, M. K.; Velisavljevic, N.

    2016-04-01

    Studies of the phase diagram of uranium have revealed a wealth of high pressure and temperature phases. Under ambient conditions the crystal structure is well defined up to 100 gigapascals (GPa), but very little information on thermal conduction or elasticity is available over this same range. This work has applied ultrasonic interferometry to determine the elasticity, mechanical, and thermal properties of depleted uranium to 4.5 GPa. Results show general strengthening with applied load, including an overall increase in acoustic thermal conductivity. Further implications are discussed within. This work presents the first high pressure studies of the elasticity and thermal properties of depleted uranium metal and the first real-world application of a previously developed containment system for making such measurements.

  8. Innovative Methodologies for thermal Energy Release Measurement: case of La Solfatara volcano (Italy)

    NASA Astrophysics Data System (ADS)

    Marfe`, Barbara; Avino, Rosario; Belviso, Pasquale; Caliro, Stefano; Carandente, Antonio; Marotta, Enrica; Peluso, Rosario

    2015-04-01

    This work is devoted to improve the knowledge on the parameters that control the heat flux anomalies associated with the diffuse degassing processes of volcanic and hydrothermal areas. The methodologies currently used to measure heat flux (i.e. CO2 flux or temperature gradient) are either poorly efficient or effective, and are unable to detect short to medium time (days to months) variation trends in the heat flux. A new method, based on the use of thermal imaging cameras, has been applied to estimate the heat flux and its time variations. This approach will allow faster heat flux measurement than already accredited methods, improving in this way the definition of the activity state of a volcano and allowing a better assessment of the related hazard and risk mitigation. The idea is to extrapolate the heat flux from the ground surface temperature that, in a purely conductive regime, is directly correlated to the shallow temperature gradient. We use thermal imaging cameras, at short distances (meters to hundreds of meters), to quickly obtain a mapping of areas with thermal anomalies and a measure of their temperature. Preliminary studies have been carried out throughout the whole of the La Solfatara crater in order to investigate a possible correlation between the surface temperature and the shallow thermal gradient. We have used a FLIR SC640 thermal camera and K type thermocouples to assess the two measurements at the same time. Results suggest a good correlation between the shallow temperature gradient ΔTs and the surface temperature Ts depurated from background, and despite the campaigns took place during a period of time of a few years, this correlation seems to be stable over the time. This is an extremely motivating result for a further development of a measurement method based only on the use of small range thermal imaging camera. Surveys with thermal cameras may be manually done using a tripod to take thermal images of small contiguous areas and then joining

  9. Applications of high thermal conductivity composites to electronics and spacecraft thermal design

    NASA Technical Reports Server (NTRS)

    Sharp, G. Richard; Loftin, Timothy A.

    1990-01-01

    Recently, high thermal conductivity continuous graphite fiber reinforced metal matrix composites (MMC's) have become available that can save much weight over present methods of heat conduction. These materials have two or three times higher thermal conductivity in the fiber direction than the pure metals when compared on a thermal conductivity to weight basis. Use of these materials for heat conduction purposes can result in weight savings of from 50 to 70 percent over structural aluminum. Another significant advantage is that these materials can be used without the plumbing and testing complexities that accompany the use of liquid heat pipes. A spinoff of this research was the development of other MMC's as electronic device heat sinks. These use particulates rather than fibers and are formulated to match the coefficient of thermal expansion of electronic substrates in order to alleviate thermally induced stresses. The development of both types of these materials as viable weight saving substitutes for traditional methods of thermal control for electronics packaging and also for spacecraft thermal control applications are the subject of this report.

  10. High-Efficiency Solar Thermal Vacuum Demonstration Completed for Refractive Secondary Concentrator

    NASA Technical Reports Server (NTRS)

    Wong, Wayne A.

    2001-01-01

    Common to many of the space applications that utilize solar thermal energy--such as electric power conversion, thermal propulsion, and furnaces--is a need for highly efficient, solar concentration systems. An effort is underway at the NASA Glenn Research Center to develop the refractive secondary concentrator, which uses refraction and total internal reflection to efficiently concentrate and direct solar energy. When used in combination with advanced lightweight primary concentrators, the refractive secondary concentrator enables very high system concentration ratios (10,000 to 1) and very high temperatures (>2000 K). The innovative refractive secondary concentrator offers significant advantages over all other types of secondary concentrators. The refractive secondary offers the highest throughput efficiency, provides for flux tailoring, requires no active cooling, relaxes the pointing and tracking requirements of the primary concentrator, and enables very high system concentration ratios. This technology has broad applicability to any system that requires the conversion of solar energy to heat. Glenn initiated the development of the refractive secondary concentrator in support of Shooting Star, a solar thermal propulsion flight experiment, and continued the development in support of Space Solar Power.

  11. Thermal Conductivity Measurements in Metals at High Pressures and Temperatures.

    NASA Astrophysics Data System (ADS)

    Konopkova, Z.; McWilliams, R. S.; Goncharov, A.

    2014-12-01

    The transport properties of iron and iron alloys at high pressures and temperatures are crucial parameters in planetary evolution models, yet are difficult to determine both theoretically and experimentally. Estimates of thermal conductivity in the Earth's core range from 30 to 150 W/mK, a substantial range leaving many open questions regarding the age of the inner core, the thermal structure of the outer core, and the conditions for a working geodynamo. Most experiments have measured electrical resistivity rather than directly measuring thermal conductivity, and have used models to extrapolate from low-temperature data to the high temperature conditions of the core. Here we present direct, in-situ high-pressure and high-temperature measurements of the thermal conductivity of metals in the diamond-anvil cell. Double-sided continuous laser heating is combined with one-side flash heating of a metallic foil, while the time-resolved temperature is measured from both sides with spectral radiometry in an optical streak camera. Emission and temperature perturbations measured on opposite sides of the foil were modeled using finite element calculations in order to extract thermal diffusivity and conductivity of foils. Results on platinum and iron at high pressures and temperatures will be presented.

  12. Thermal design and flight validation for high precision camera

    NASA Astrophysics Data System (ADS)

    Meng, Henghui; Sun, Lixia; Zhang, Chuanqiang; Geng, Liyin

    2015-10-01

    High precision camera, designed for advanced optical system, with a wide field of vision, high resolution and fast response, has a wild range of applications. As the main payload for spacecraft, the optical remote sensor is mounted exposed to the space, which means it should have a reliable optical performance in harsh space environment during lifetime. Because of the special optical characteristic, imaging path should be accurate, and less thermal deformation for the optical parts is required in the working process, so the high precision camera has a high level requirement for temperature. High resolution space camera is generally required to own the capability of adapting to space thermal environments. The flexible satellite's change of rolling attitude affects the temperature distribution of the camera and makes a difference to optical performance. The thermal control design of space camera is presented, and analysis the temperature data in orbit to prove the thermal design correct. It is proved that the rolling attitude has more influence on outer parts and less influence on inner parts, and active thermal control can weaken the influence of rolling attitude.

  13. Adoption of a High-Impact Innovation in a Homogeneous Population

    NASA Astrophysics Data System (ADS)

    Weiss, Curtis H.; Poncela-Casasnovas, Julia; Glaser, Joshua I.; Pah, Adam R.; Persell, Stephen D.; Baker, David W.; Wunderink, Richard G.; Nunes Amaral, Luís A.

    2014-10-01

    Adoption of innovations, whether new ideas, technologies, or products, is crucially important to knowledge societies. The landmark studies of adoption dealt with innovations having great societal impact (such as antibiotics or hybrid crops) but where determining the utility of the innovation was straightforward (such as fewer side effects or greater yield). Recent large-scale studies of adoption were conducted within heterogeneous populations and focused on products with little societal impact. Here, we focus on a case with great practical significance: adoption by small groups of highly trained individuals of innovations with large societal impact but for which it is impractical to determine the true utility of the innovation. Specifically, we study experimentally the adoption by critical care physicians of a diagnostic assay that complements current protocols for the diagnosis of life-threatening bacterial infections and for which a physician cannot estimate the true accuracy of the assay based on personal experience. We show through computational modeling of the experiment that infection-spreading models—which have been formalized as generalized contagion processes—are not consistent with the experimental data, while a model inspired by opinion models is able to reproduce the empirical data. Our modeling approach enables us to investigate the efficacy of different intervention schemes on the rate and robustness of innovation adoption in the real world. While our study is focused on critical care physicians, our findings have implications for other settings in education, research, and business, where small groups of highly qualified peers make decisions about the adoption of innovations whose utility is difficult if not impossible to gauge.

  14. Adoption of a High-Impact Innovation in a Homogeneous Population.

    PubMed

    Weiss, Curtis H; Poncela-Casasnovas, Julia; Glaser, Joshua I; Pah, Adam R; Persell, Stephen D; Baker, David W; Wunderink, Richard G; Nunes Amaral, Luís A

    2014-10-15

    Adoption of innovations, whether new ideas, technologies, or products, is crucially important to knowledge societies. The landmark studies of adoption dealt with innovations having great societal impact (such as antibiotics or hybrid crops) but where determining the utility of the innovation was straightforward (such as fewer side effects or greater yield). Recent large-scale studies of adoption were conducted within heterogeneous populations and focused on products with little societal impact. Here, we focus on a case with great practical significance: adoption by small groups of highly trained individuals of innovations with large societal impact but for which it is impractical to determine the true utility of the innovation. Specifically, we study experimentally the adoption by critical care physicians of a diagnostic assay that complements current protocols for the diagnosis of life-threatening bacterial infections and for which a physician cannot estimate the true accuracy of the assay based on personal experience. We show through computational modeling of the experiment that infection-spreading models-which have been formalized as generalized contagion processes-are not consistent with the experimental data, while a model inspired by opinion models is able to reproduce the empirical data. Our modeling approach enables us to investigate the efficacy of different intervention schemes on the rate and robustness of innovation adoption in the real world. While our study is focused on critical care physicians, our findings have implications for other settings in education, research, and business, where small groups of highly qualified peers make decisions about the adoption of innovations whose utility is difficult if not impossible to gauge. PMID:25392742

  15. Innovation in Student Services: Planning for Models Blending High Touch/High Tech.

    ERIC Educational Resources Information Center

    Burnett, Darlene J., Ed.; Oblinger, Diana G., Ed.

    This collection is intended to help planners, administrators, and student service professionals gain a better understanding of the changes emerging in student services as it demonstrates how innovative leaders are responding to these challenges. Part 1, "Creating the Student-Centered Experience," contains: (1) "Innovation in Student Services" Best…

  16. Thermal Conductivity and Elastic Modulus Evolution of Thermal Barrier Coatings under High Heat Flux Conditions

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Miller, Robert A.

    1999-01-01

    Laser high heat flux test approaches have been established to obtain critical properties of ceramic thermal barrier coatings (TBCs) under near-realistic temperature and thermal gradients that may he encountered in advanced engine systems. Thermal conductivity change kinetics of a thin ceramic coating were continuously monitored in real time at various test temperatures. A significant thermal conductivity increase was observed during the laser simulated engine heat flux tests. For a 0.25 mm thick ZrO2-8%Y2O3 coating system, the overall thermal conductivity increased from the initial value of 1.0 W/m-K to 1. 15 W/m-K, 1. 19 W/m-K and 1.5 W/m-K after 30 hour testing at surface temperatures of 990C, 1100C, and 1320C. respectively. Hardness and modulus gradients across a 1.5 mm thick TBC system were also determined as a function of laser testing time using the laser sintering/creep and micro-indentation techniques. The coating Knoop hardness values increased from the initial hardness value of 4 GPa to 5 GPa near the ceramic/bond coat interface, and to 7.5 GPa at the ceramic coating surface after 120 hour testing. The ceramic surface modulus increased from an initial value of about 70 GPa to a final value of 125 GPa. The increase in thermal conductivity and the evolution of significant hardness and modulus gradients in the TBC systems are attributed to sintering-induced micro-porosity gradients under the laser-imposed high thermal gradient conditions. The test techniques provide a viable means for obtaining coating data for use in design, development, stress modeling, and life prediction for various thermal barrier coating applications.

  17. Measurement of thermal diffusivity of rocks at high pressure

    SciTech Connect

    Mirkovich, V.V.; Durham, W.B.; Heard, H.C.

    1982-10-01

    A method for measurement of thermal diffusivity at high hydrostatic pressure was developed by adapting a radial symmetry heat flow method wherein a sinusoidal heat wave is applied to the cylindrical surface of the sample. The accuracy of the measuring system was tested using Pyroceram 9606. Data obtained were within 5% of published values at all temperatures to 400/sup 0/C and no dependence upon pressure was observed. Thermal diffusivity of three crystalline igneous rock specimens was measured at temperatures from 32 to 400/sup 0/C and pressures from 0.1 to 200 MPa. The results for Creighton quartz diorite showed only limited temperature and pressure dependence. In the case of Stripa and Westerly granites, this dependence was found to be more substantial. Thermal diffusivity of Stripa granite decreased by more than 50% from 32 to 400/sup 0/C and that of Westerly granite decreased by approximately 40% over the same range. At 32/sup 0/C and 200 MPa, thermal diffusivity for both rocks was higher by approximately 10% than that measured at 0.1 MPa. At higher temperatures the difference in thermal diffusivity between the two pressure levels increased. An anomaly was observed in Stripa and Westerly granite in the temperature range 32 to 65/sup 0/C: thermal diffusivity increased with increasing temperature. The anomaly is consistent with recently observed thermal expansivity in these rocks as a function of pressure and temperature.

  18. Research on Innovative Practice Teaching System Based on the High-End Practice Teaching Environment for Software Engineering Speciality

    NASA Astrophysics Data System (ADS)

    Dong, Jianli; Li, Cunhua; Ji, Zhaohui; Wu, Junming

    Through the analysis of current culture status of undergraduate engineering applied talents, the paper points out that the main reason causing the lack of student integrated application and practice innovation abilities is the poor construction of high-end practice environment. And then, how to enhance the practice environment construction and practical teaching innovation as well as building an appropriate innovation practice teaching system for engineering applied talents are systematically discussed. It is very obvious that the application and promotion of this kind of innovative practice teaching system could enhance the practice innovation abilities and entrepreneurial and employment awareness of the graduates.

  19. Highly thermally conductive papers with percolative layered boron nitride nanosheets.

    PubMed

    Zhu, Hongli; Li, Yuanyuan; Fang, Zhiqiang; Xu, Jiajun; Cao, Fangyu; Wan, Jiayu; Preston, Colin; Yang, Bao; Hu, Liangbing

    2014-04-22

    In this work, we report a dielectric nanocomposite paper with layered boron nitride (BN) nanosheets wired by one-dimensional (1D) nanofibrillated cellulose (NFC) that has superior thermal and mechanical properties. These nanocomposite papers are fabricated from a filtration of BN and NFC suspensions, in which NFC is used as a stabilizer to stabilize BN nanosheets. In these nanocomposite papers, two-dimensional (2D) nanosheets form a thermally conductive network, while 1D NFC provides mechanical strength. A high thermal conductivity has been achieved along the BN paper surface (up to 145.7 W/m K for 50 wt % of BN), which is an order of magnitude higher than that in randomly distributed BN nanosheet composites and is even comparable to the thermal conductivity of aluminum alloys. Such a high thermal conductivity is mainly attributed to the structural alignment within the BN nanosheet papers; the effects of the interfacial thermal contact resistance are minimized by the fact that the heat transfer is in the direction parallel to the interface between BN nanosheets and that a large contact area occurs between BN nanosheets. PMID:24601534

  20. Investigation of Thermal High Cycle and Low Cycle Fatigue Mechanisms of Thick Thermal Barrier Coatings

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Miller, Robert A.

    1998-01-01

    Thick thermal barrier coating systems in a diesel engine experience severe thermal low cycle fatigue (LCF) and high cycle fatigue (HCF) during engine operation. In this paper, the mechanisms of fatigue crack initiation and propagation in a ZrO2-8wt% Y2O3 thermal barrier coating, under simulated engine thermal LCF and HCF conditions, are investigated using a high power CO2 laser. Experiments showed that the combined LCF-HCF tests induced more severe coating surface cracking, microspallation and accelerated crack growth, as compared to the pure LCF test. Lateral crack branching and the ceramic/bond coat interface delaminations were also facilitated by HCF thermal loads, even in the absence of severe interfacial oxidation. Fatigue damage at crack wake surfaces, due to such phenomena as asperity/debris contact induced cracking and splat pull-out bending during cycling, was observed especially for the combined LCF-HCF tests. It is found that the failure associated with LCF is closely related to coating sintering and creep at high temperatures, which induce tensile stresses in the coating after cooling. The failure associated with HCF process, however, is mainly associated with a surface wedging mechanism. The interaction between the LCF, HCF and ceramic coating creep, and the relative importance of LCF and HCF in crack propagation are also discussed based on the experimental evidence.

  1. Investigation of Thermal High Cycle and Low Cycle Fatigue Mechanisms of Thick Thermal Barrier Coatings

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Miller, Robert A.

    1998-01-01

    Thick thermal barrier coating systems in a diesel engine experience severe thermal low cycle fatigue (LCF) and high cycle fatigue (HCF) during engine operation. In this paper, the mechanisms of fatigue crack initiation and propagation in a ZrO2-8wt.% Y2O3 thermal barrier coating, under simulated engine thermal LCF and HCF conditions, are investigated using a high power CO2 laser. Experiments showed that the combined LCF/HCF tests induced more severe coating surface cracking, microspallation and accelerated crack growth, as compared to the pure LCF test. Lateral crack branching and the ceramic/bond coat interface delaminations were also facilitated by HCF thermal loads, even in the absence of severe interfacial oxidation. Fatigue damages at crack wake surfaces, due to such phenomena as asperity/debris contact induced cracking and splat pull-out bending during cycling, were observed especially for the combined LCF/HCF tests. It is found that the failure associated with LCF is closely related to coating sintering and creep at high temperatures, which induce tensile stresses in the coating after cooling. The failure associated with HCF process, however, is mainly associated with a surface wedging mechanism. The interaction between the LCF, HCF and ceramic coating creep, and the relative importance of LCF and HCF in crack propagation are also discussed based on the experimental evidence.

  2. Wooden concrete: High thermal efficiency using waste wood

    SciTech Connect

    Kosny, J.

    1994-09-01

    Wood concrete mixture of wood shavings, lime and cement is widely used in European building construction. In spite of many advantages, this material is almost unknown in the US. Eventual application of wooden concrete in building block production is discussed in this paper. Based on finite difference computer modeling, the thermal performance of several masonry wall systems and their components have been analyzed. The total wall system thermal performance for a typical single-story ranch house also has been determined. At present, typical experimental wall measurements and calculations do not include the effects of building envelope subsystems such as comers, window and door openings, and structural joints with roofs, floors, ceilings, and other walls. In masonry wall systems, these details may represent significant thermal bridges because of the highly conductive structural concrete. Many of the typical thermal bridges may be reduced by application of wood concrete elements.

  3. Thermal stability of high temperature structural alloys

    SciTech Connect

    Jordan, C.E.; Rasefske, R.K.; Castagna, A.

    1999-03-01

    High temperature structural alloys were evaluated for suitability for long term operation at elevated temperatures. The effect of elevated temperature exposure on the microstructure and mechanical properties of a number of alloys was characterized. Fe-based alloys (330 stainless steel, 800H, and mechanically alloyed MA 956), and Ni-based alloys (Hastelloy X, Haynes 230, Alloy 718, and mechanically alloyed MA 758) were evaluated for room temperature tensile and impact toughness properties after exposure at 750 C for 10,000 hours. Of the Fe-based alloys evaluated, 330 stainless steel and 800H showed secondary carbide (M{sub 23}C{sub 6}) precipitation and a corresponding reduction in ductility and toughness as compared to the as-received condition. Within the group of Ni-based alloys tested, Alloy 718 showed the most dramatic structure change as it formed delta phase during 10,000 hours of exposure at 750 C with significant reductions in strength, ductility, and toughness. Haynes 230 and Hastelloy X showed significant M{sub 23}C{sub 6} carbide precipitation and a resulting reduction in ductility and toughness. Haynes 230 was also evaluated after 10,000 hours of exposure at 850, 950, and 1050 C. For the 750--950 C exposures the M{sub 23}C{sub 6} carbides in Haynes 230 coarsened. This resulted in large reductions in impact strength and ductility for the 750, 850 and 950 C specimens. The 1050 C exposure specimens showed the resolution of M{sub 23}C{sub 6} secondary carbides, and mechanical properties similar to the as-received solution annealed condition.

  4. Process for fabricating composite material having high thermal conductivity

    DOEpatents

    Colella, Nicholas J.; Davidson, Howard L.; Kerns, John A.; Makowiecki, Daniel M.

    2001-01-01

    A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

  5. Improving SFR Economics through Innovations from Thermal Design and Analysis Aspects

    SciTech Connect

    Haihua Zhao; Hongbin Zhang; Vincent Mousseau; Per F. Peterson

    2008-06-01

    Achieving economic competitiveness as compared to LWRs and other Generation IV (Gen-IV) reactors is one of the major requirements for large-scale investment in commercial sodium cooled fast reactor (SFR) power plants. Advances in R&D for advanced SFR fuel and structural materials provide key long-term opportunities to improve SFR economics. In addition, other new opportunities are emerging to further improve SFR economics. This paper provides an overview on potential ideas from the perspective of thermal hydraulics to improve SFR economics. These include a new hybrid loop-pool reactor design to further optimize economics, safety, and reliability of SFRs with more flexibility, a multiple reheat and intercooling helium Brayton cycle to improve plant thermal efficiency and reduce safety related overnight and operation costs, and modern multi-physics thermal analysis methods to reduce analysis uncertainties and associated requirements for over-conservatism in reactor design. This paper reviews advances in all three of these areas and their potential beneficial impacts on SFR economics.

  6. Improving SFR Economics Through Innovations from Thermal Design and Analysis Aspects

    SciTech Connect

    Haihua Zhao; Hongbin Zhang; Vincent Mousseau; Per F. Peterson

    2009-06-01

    Achieving economic competitiveness as compared to LWRs and other Generation IV (Gen-IV) reactors is one of the major requirements for large-scale investment in commercial sodium cooled fast reactor (SFR) power plants. Advances in R&D for advanced SFR fuel and structural materials provide key long-term opportunities to improve SFR economics. In addition, other new opportunities are emerging to further improve SFR economics. This paper provides an overview on potential ideas from the perspective of thermal hydraulics to improve SFR economics. These include a new hybrid loop-pool reactor design to further optimize economics, safety, and reliability of SFRs with more flexibility, a multiple reheat and intercooling helium Brayton cycle to improve plant thermal efficiency and reduce safety related overnight and operation costs, and modern multi-physics thermal analysis methods to reduce analysis uncertainties and associated requirements for over-conservatism in reactor design. This paper reviews advances in all three of these areas and their potential beneficial impacts on SFR economics.

  7. Thermal Expansion and Thermophysical Properties of Materials and Minerals at High Temperature and High Pressure

    NASA Astrophysics Data System (ADS)

    Wang, Kai

    1995-11-01

    The knowledge of thermal expansion at high temperature and high pressure is necessary for modeling the equation of the state in the Earth's interior. It is an important parameter for materials science and is critical for understanding the nature of the residual stress in materials. Also, thermal expansion is a factor in the equations that describe many thermoelastic parameters. Errors in thermal expansion will propagate in thermodynamic calculations. This dissertation is based on a semi-empirical, quasi-harmonic, lattice dynamic thermal expansion model, its extension to high temperatures and high pressures and the role of defects on thermal expansion. A modified quasi -harmonic model is proposed to calculate high temperature thermal expansion of alkali halides. An empirical parabolic relationship is found at high temperatures. The contributions of thermal defects at high temperatures are employed to explain the differences between experimental data and the perfect quasi-harmonic crystal model. Expressions for defect contributions on thermal expansion and expansivity are given and applied to obtain the formation energies of thermal defects. Defect ordering is proposed for ionic crystals at high temperatures. A simplified model is derived for predicting high pressure thermal expansion. A detailed expression for defect contributions at high temperatures and high pressures is provided. Thermal expansion of MgO is predicted for pressures as high as at the core-mantle boundary. This model is also applied to alkali halides, and the thermophysical properties of NaCl are given as an example. Then a general model is proposed for evaluating and predicting high temperature thermal expansion. The product of thermal expansion, bulk modulus, and volume, alpha_{V}K_{T }V, or the partial temperature derivative of the work done by thermal pressure, resembles a specific heat curve. A modified Einstein model is applied to express the alpha_{V}K_{T }V data. After assuming a linear

  8. Thermal modelling of various thermal barrier coatings in a high heat flux rocket engine

    NASA Technical Reports Server (NTRS)

    Nesbitt, James A.

    1989-01-01

    Traditional Air Plasma Sprayed (APS) ZrO2-Y2O3 Thermal Barrier Coatings (TBC's) and Low Pressure Plasma Sprayed (LPPS) ZrO2-Y2O3/Ni-Cr-Al-Y cermet coatings were tested in a H2/O2 rocked engine. The traditional ZrO2-Y2O3 (TBC's) showed considerable metal temperature reductions during testing in the hydrogen-rich environment. A thermal model was developed to predict the thermal response of the tubes with the various coatings. Good agreement was observed between predicted temperatures and measured temperatures at the inner wall of the tube and in the metal near the coating/metal interface. The thermal model was also used to examine the effect of the differences in the reported values of the thermal conductivity of plasma sprayed ZrO2-Y2O3 ceramic coatings, the effect of 100 micron (0.004 in.) thick metallic bond coat, the effect of tangential heat transfer around the tube, and the effect or radiation from the surface of the ceramic coating. It was shown that for the short duration testing in the rocket engine, the most important of these considerations was the effect of the uncertainty in the thermal conductivity of temperatures (greater than 100 C) predicted in the tube. The thermal model was also used to predict the thermal response of the coated rod in order to quantify the difference in the metal temperatures between the two substrate geometries and to explain the previously-observed increased life of coatings on rods over that on tubes. A thermal model was also developed to predict heat transfer to the leading edge of High Pressure Fuel Turbopump (HPFTP) blades during start-up of the space shuttle main engines. The ability of various TBC's to reduce metal temperatures during the two thermal excursions occurring on start-up was predicted. Temperature reductions of 150 to 470 C were predicted for 165 micron (0.0065 in.) coatings for the greater of the two thermal excursions.

  9. Thermal conductivity and elastic modulus evolution of thermal barrier coatings under high heat flux conditions

    NASA Astrophysics Data System (ADS)

    Zhu, Dongming; Miller, Robert A.

    2000-06-01

    Laser high heat flux test approaches have been established to obtain critical properties of ceramic thermal barrier coatings (TBCs) under near-realistic temperature and thermal gradients that may be encountered in advanced engine systems. Thermal conductivity change kinetics of a thin ceramic coating were continuously monitored in real time at various test temperatures. A significant thermal conductivity increase was observed during the laser-simulated engine heat flux tests. For a 0.25 mm thick ZrO2-8% Y2O3 coating system, the overall thermal conductivity increased from the initial value of 1.0 W/m K to 1.15, 1.19, and 1.5 W/m K after 30 h of testing at surface temperatures of 990, 1100, and 1320 °C, respectively, Hardness and elastic modulus gradients across a 1.5 mm thick TBC system were also determined as a function of laser testing time using the laser sintering/creep and microindentation techniques. The coating Knoop hardness values increased from the initial hardness value of 4 GPa to 5 GPa near the ceramic/bond coat interface and to 7.5 GPa at the ceramic coating surface after 120 h of testing. The ceramic surface modulus increased from an initial value of about 70 GPa to a final value of 125 GPa. The increase in thermal conductivity and the evolution of significant hardness and modulus gradients in the TBC systems are attributed to sintering-induced microporosity gradients under the laser-imposed high thermal gradient conditions. The test techniques provide a viable means for obtaining coating data for use in design, development, stress modeling, and life prediction for various TBC applications.

  10. Proposal Sets Out "i3" Rules: Education Department Eyeing High Bar in Innovation Grant Awards

    ERIC Educational Resources Information Center

    McNeil, Michele

    2009-01-01

    The U.S. Department of Education is proposing high hurdles for school districts and nonprofit groups that want a piece of the $650 million Investing in Innovation grant program, including evidence of past success in helping students most in need and significant financial commitments from the private sector. The grants, which are meant to expand…

  11. Innovative technology summary report: High-speed clamshell pipe cutter

    SciTech Connect

    1998-09-01

    The Hanford Site C Reactor Technology Demonstration Group demonstrated the High-Speed Clamshell Pipe Cutter technology, developed and marketed by Tri Tool Inc. (Rancho Cordova, California). The models demonstrated are portable, split-frame pipe lathes that require minimal radial and axial clearances for severing and/or beveling in-line pipe with ranges of 25 cm to 41 cm and 46 cm to 61 cm nominal diameter. The radial clearance requirement from the walls, floors, or adjacent pipes is 18 cm. The lathes were supplied with carbide insert conversion kits for the cutting bits for the high-speed technique that was demonstrated. Given site-specific factors, this demonstration showed the cost of the improved technology to be approximately 30% higher than the traditional (baseline) technology (oxyacetylene torch) cost of $14,400 for 10 cuts of contaminated 41-cm and 61-cm-diameter pipe at C Reactor. Actual cutting times were faster than the baseline technology; however, moving/staging the equipment took longer. Unlike the baseline torch, clamshell lathes do not involve applied heat, flames, or smoke and can be operated remotely, thereby helping personal exposures to be as low as reasonably achievable. The baseline technology was demonstrated at the C Reactor north and south water pipe tunnels August 19--22, 1997. The improved technology was demonstrated in the gas pipe tunnel December 15--19.

  12. THERMAL ANALYSIS OF GEOLOGIC HIGH-LEVEL RADIOACTIVE WASTE PACKAGES

    SciTech Connect

    Hensel, S.; Lee, S.

    2010-04-20

    The engineering design of disposal of the high level waste (HLW) packages in a geologic repository requires a thermal analysis to provide the temperature history of the packages. Calculated temperatures are used to demonstrate compliance with criteria for waste acceptance into the geologic disposal gallery system and as input to assess the transient thermal characteristics of the vitrified HLW Package. The objective of the work was to evaluate the thermal performance of the supercontainer containing the vitrified HLW in a non-backfilled and unventilated underground disposal gallery. In order to achieve the objective, transient computational models for a geologic vitrified HLW package were developed by using a computational fluid dynamics method, and calculations for the HLW disposal gallery of the current Belgian geological repository reference design were performed. An initial two-dimensional model was used to conduct some parametric sensitivity studies to better understand the geologic system's thermal response. The effect of heat decay, number of co-disposed supercontainers, domain size, humidity, thermal conductivity and thermal emissivity were studied. Later, a more accurate three-dimensional model was developed by considering the conduction-convection cooling mechanism coupled with radiation, and the effect of the number of supercontainers (3, 4 and 8) was studied in more detail, as well as a bounding case with zero heat flux at both ends. The modeling methodology and results of the sensitivity studies will be presented.

  13. Modeling thermally driven energetic response of high explosives

    SciTech Connect

    Sharp, R; Couch, R; McCallen, R C; Nichols III, A L; Otero, I

    1998-02-01

    We have improved our ability to model the response of energetic materials to thermal stimuli and the processes involved in the energetic response. Traditionally, the analyses of energetic materials have involved coupled thermal transport/chemical reaction codes. This provides only a reasonable estimate of the time and location of ensuing rapid reaction. To predict the violence of the reaction, the mechanical motion must be included in the wide range of time scales associated with the thermal hazard. The ALE3D code has been modified to assess the hazards associated with heating energetic materials in weapons by coupling to thermal transport model and chemistry models. We have developed an implicit time step option to efficiently and accurately compute the hours of heating to reaction of the energetic material. Since, on these longer time scales materials can be expected to have significant motion, it is even more important to provide high-order advection for all components, including the chemical species. We show two examples of coupled thermal/mechanical/chemical models of energetic materials in thermal environments.

  14. Modeling thermally driven energetic response of high explosives

    SciTech Connect

    Couch, R; McCallen, R C; Nichols III, A L; Otero, I; Sharp, R

    1998-08-17

    We have improved our ability to model the response of energetic materials to thermal stimuli and the processes involved in the energetic response. Traditionally, the analyses of energetic materials have involved coupled thermal transport/chemical reaction codes. This provides only a reasonable estimate of the time and location of ensuing rapid reaction. To predict the violence of the reaction, the mechanical motion must be included in the wide range of time scales associated with the thermal hazard. The ALE3D code has been modified to assess the hazards associated with heating energetic materials in weapons by coupling to thermal transport model and chemistry models. We have developed an implicit time step option to efficiently and accurately compute the hours of heating to reaction of the energetic material. Since, on these longer time scales materials can be expected to have significant motion, it is even more important to provide high-order advection for all components, including the chemical species. We show two examples of coupled thermal/mechanical/chemical models of energetic materials in thermal environments.

  15. GPS World, Innovation: Autonomous Navigation at High Earth Orbits

    NASA Technical Reports Server (NTRS)

    Bamford, William; Winternitz, Luke; Hay, Curtis

    2005-01-01

    Calculating a spacecraft's precise location at high orbital altitudes-22,000 miles (35,800 km) and beyond-is an important and challenging problem. New and exciting opportunities become possible if satellites are able to autonomously determine their own orbits. First, the repetitive task of periodically collecting range measurements from terrestrial antennas to high altitude spacecraft becomes less important-this lessens competition for control facilities and saves money by reducing operational costs. Also, autonomous navigation at high orbital altitudes introduces the possibility of autonomous station keeping. For example, if a geostationary satellite begins to drift outside of its designated slot it can make orbit adjustments without requiring commands from the ground. Finally, precise onboard orbit determination opens the door to satellites flying in formation-an emerging concept for many scientific space applications. The realization of these benefits is not a trivial task. While the navigation signals broadcast by GPS satellites are well suited for orbit and attitude determination at lower altitudes, acquiring and using these signals at geostationary (GEO) and highly elliptical orbits is much more difficult. The light blue trace describes the GPS orbit at approximately 12,550 miles (20,200 km) altitude. GPS satellites were designed to provide navigation signals to terrestrial users-consequently the antenna array points directly toward the earth. GEO and HE0 orbits, however, are well above the operational GPS constellation, making signal reception at these altitudes more challenging. The nominal beamwidth of a Block II/IIA GPS satellite antenna array is approximately 42.6 degrees. At GEO and HE0 altitudes, most of these primary beam transmissions are blocked by the Earth, leaving only a narrow region of nominal signal visibility near opposing limbs of the earth. This region is highlighted in gray. If GPS receivers at GEO and HE0 orbits were designed to use these

  16. Fundamental kinetics and innovative applications of nonequilibrium atomic vibration in thermal energy transport and conversion

    NASA Astrophysics Data System (ADS)

    Shin, Seungha

    All energy conversion inefficiencies begin with emission of resonant atomic motions, e.g., vibrations, and are declared as waste heat once these motions thermalize to equilibrium. The nonequilibrium energy occupancy of the vibrational modes can be targeted as a harvestable, low entropy energy source for direct conversion to electric energy. Since the lifetime of these resonant vibrations is short, special nanostructures are required with the appropriate tuning of the kinetics. These in turn require multiscale, multiphysics treatments. Atomic vibration is described with quasiparticle phonon in solid, and the optical phonon emission is dominant relaxation channel in semiconductors. These optical modes become over-occupied when their emission rate becomes larger than their decay rate, thus hindering energy relaxation and transport in devices. Effective removal of these phonons by drifting electrons is investigated by manipulating the electron distribution to have higher population in the low-energy states, thus allowing favorable phonon absorption. This is done through introduction, design and analysis of a heterobarrier conducting current, where the band gap is controlled by alloying, thus creating a spatial variation which is abrupt followed by a linear gradient (to ensure directed current). Self-consistent ensemble Monte Carlo simulations based on interaction kinetics between electron and phonon show that up to 19% of the phonon energy is converted to electric potential with an optimized GaAs/AlxGa1-xAs barrier structure over a range of current and electron densities, and this system is also verified through statistical entropy analysis. This direct energy conversion improves the device performance with lower operation temperature and enhances overall energy conversion efficiency. Through this study, the paradigm for harvesting the resonant atomic vibration is proposed, reversing the general role of phonon as only causing electric potential drop. Fundamentals

  17. Supercritical Water Nuclear Steam Supply System: Innovations In Materials, Neutronics & Thermal-Hydraulics

    SciTech Connect

    Mark Anderson; M.L. Corradini; K. Sridharan; P. WIlson; D. Cho; T.K. Kim; S. Lomperski

    2004-09-02

    In the 1990's supercritical light-water reactors were considered in conceptual designs. A nuclear reactor cooled by supercritical waster would have a much higher thermal efficiency with a once-through direct power cycle, and could be based on standardized water reactor components (light water or heavy water). The theoretical efficiency could be improved by more than 33% over that of other water reactors and could be simplified with higher reliability; e.g., a boiling water reactor without steam separators or dryers.

  18. Thermal design concept for a high resolution UV spectrometer

    NASA Technical Reports Server (NTRS)

    Caruso, P.; Stipandic, E.

    1979-01-01

    The thermal design concept described has been developed for the High Resolution UV Spectrometer/Polarimeter to be flown on the Solar Maximum Mission. Based on experience gained from a similar Orbiting Solar Observatory mission payload, it has been recognized that initial protection of the optical elements, contamination control, reduction of scattered light, tight bulk temperature, and gradient constraints are key elements that must be accommodated in any thermal control concept for this class of instrument. Salient features of the design include: (1) a telescope door providing contamination protection of an aplanatic Gregorian telescope; (2) a rastering system for the secondary mirror; (3) a unique solar heat absorbing device; (4) heat pipes and special radiators; (5) heaters for active temperature control and optics contamination protection; and (6) high precision platinum resistance thermometers. Viability of the design concept has been established by extensive thermal analysis and some subsystem testing. A summary of analytical and test results is included.

  19. High Fidelity Probe and Mitigation of Mirror Thermal Fluctuations

    NASA Astrophysics Data System (ADS)

    Chalermsongsak, Tara

    Thermal noise arising from mechanical loss in high reflective dielectric coatings is a significant source of noise in precision optical measurements. In particular, Advanced LIGO, a large scale interferometer aiming to observed gravitational wave, is expected to be limited by coating thermal noise in the most sensitive region around 30-300 Hz. Various theoretical calculations for predicting coating Brownian noise have been proposed. However, due to the relatively limited knowledge of the coating material properties, an accurate approximation of the noise cannot be achieved. A testbed that can directly observed coating thermal noise close to Advanced LIGO band will serve as an indispensable tool to verify the calculations, study material properties of the coating, and estimate the detector's performance. This dissertation reports a setup that has sensitivity to observe wide band (10Hz to 1kHz) thermal noise from fused silica/tantala coating at room temperature from fixed-spacer Fabry-Perot cavities. Important fundamental noises and technical noises associated with the setup are discussed. The coating loss obtained from the measurement agrees with results reported in the literature. The setup serves as a testbed to study thermal noise in high reflective mirrors from different materials. One example is a heterostructure of Al xGa1-xAs (AlGaAs). An optimized design to minimize thermo-optic noise in the coating is proposed and discussed in this work.

  20. High-temperature molten salt thermal energy storage systems

    NASA Technical Reports Server (NTRS)

    Petri, R. J.; Claar, T. D.; Tison, R. R.; Marianowski, L. G.

    1980-01-01

    The results of comparative screening studies of candidate molten carbonate salts as phase change materials (PCM) for advanced solar thermal energy storage applications at 540 to 870 C (1004 to 1600 F) and steam Rankine electric generation at 400 to 540 C (752 to 1004 F) are presented. Alkali carbonates are attractive as latent heat storage materials because of their relatively high storage capacity and thermal conductivity, low corrosivity, moderate cost, and safe and simple handling requirements. Salts were tested in 0.1 kWhr lab scale modules and evaluated on the basis of discharge heat flux, solidification temperature range, thermal cycling stability, and compatibility with containment materials. The feasibility of using a distributed network of high conductivity material to increase the heat flux through the layer of solidified salt was evaluated. The thermal performance of an 8 kWhr thermal energy storage (TES) module containing LiKCO3 remained very stable throughout 5650 hours and 130 charge/discharge cycles at 480 to 535 C (896 to 995 F). A TES utilization concept of an electrical generation peaking subsystem composed of a multistage condensing steam turbine and a TES subsystem with a separate power conversion loop was defined. Conceptual designs for a 100 MW sub e TES peaking system providing steam at 316 C, 427 C, and 454 C (600 F, 800 F, and 850 F) at 3.79 million Pa (550 psia) were developed and evaluated. Areas requiring further investigation have also been identified.

  1. Sintering Characteristics of Multilayered Thermal Barrier Coatings Under Thermal Gradient and Isothermal High Temperature Annealing Conditions

    NASA Technical Reports Server (NTRS)

    Rai, Amarendra K.; Schmitt, Michael P.; Bhattacharya, Rabi; Zhu, Dongming; Wolfe, Douglas E.

    2014-01-01

    Pyrochlore oxides have most of the relevant attributes for use as next generation thermal barrier coatings such as phase stability, low sintering kinetics and low thermal conductivity. One of the issues with the pyrochlore oxides is their lower toughness and therefore higher erosion rate compared to the current state-of-the-art TBC material, yttria (6 to 8 wt%) stabilized zirconia (YSZ). In this work, sintering characteristics were investigated for novel multilayered coating consisted of alternating layers of pyrochlore oxide viz Gd2Zr2O7 and t' low k (rare earth oxide doped YSZ). Thermal gradient and isothermal high temperature (1316 C) annealing conditions were used to investigate sintering and cracking in these coatings. The results are then compared with that of relevant monolayered coatings and a baseline YSZ coating.

  2. Long-duration thermal storage for solar-thermal high-pressure steam IPH

    SciTech Connect

    Copeland, R.J.; Stern, C.; Leach, J.W.

    1982-12-01

    Solar-thermal central-receiver systems are cost effective for electric-power and industrial process-heat applications. Systems employing molten nitrate salt as both receiver working fluid and storage have previously been evaluated for diurnal thermal storage. This study evaluates the potential of employing a molten salt receiver for a baseload industrial process plant requiring saturated steam at 68 atm (1000 psi). Two types of thermal storage are evaluated: molten salt, and air and rock. When thermal storage of six hours or less is used, molten nitrate salt alone is the optimum storage. For more than six hours, the optimum storage is a combination of molten salt and air and rock. The air and rock system uses a molten-salt-to-air heat exchanger and a thermocline rock bed heated and cooled by the air. The economic potential of the system is determined. The results depend on the relative cost of fossil fuel and the solar thermal energy costs. The optimum quantity of storage is highly variable, and the range is from no storage to a long duration capacity - 48 hours.

  3. Metal stud wall systems -- Thermal disaster, or modern wall systems with highly efficient thermal insulation?

    SciTech Connect

    Kosny, J.; Christian, J.E.; Desjarlais, A.O.

    1997-11-01

    Because steel has higher thermal conductivity than wood and intense heat transfer occurs through the metal wall components, thermal performances of a metal stud wall are significantly lower than for similar wood stud walls. A reduction of the in-cavity R-value caused by the wood studs is about 10% in wood stud walls. That is why metal stud walls are believed to be considerably less thermally effective than similar made of wood. However, properly designed metal stud walls can be as thermally effective as wood stud walls. Relatively high R-values may be achieved by installing insulating sheathing, which is widely used as a remedy for a weak thermal performance of metal stud walls. A series of the promising metal stud wall configurations is analyzed using results of finite difference computer modeling and guarded hotbox tests. Some of these walls were designed and tested in the ORNL Building Technology Center, some were tested in other laboratories, and some walls were developed and forgotten long time ago. Also, a novel concept of combined foam-metal studs is considered. The main aim of the present paper is to prove that it is possible to build metal stud walls which perform as well as wood stud walls. The key lies in designing; metal stud wall systems have to be treated in a special way with particular consideration to the high thermal conduction of metal components. In the discussed collection of the efficient metal stud wall configurations, reductions of the in-cavity R-value caused by metal studs are between 10 and 20%.

  4. Glass ceramics for sealing to high-thermal-expansion metals

    SciTech Connect

    Wilder, Jr., J. A.

    1980-10-01

    Glass ceramics were studied, formulated in the Na/sub 2/O CaO.P/sub 2/O/sub 5/, Na/sub 2/O.BaOP/sub 2/O/sub 5/, Na/sub 2/O.Al/sub 2/O/sub 3/.P/sub 2/O/sub 5/, and Li/sub 2/O.BaO.P/sub 2/O/sub 5/ systems to establish their suitability for sealing to high thermal expansion metals, e.g. aluminum, copper, and 300 series stainless steels. Glass ceramics in Na/sub 2/O.CaO.P/sub 2/O/sub 5/ and Na/sub 2/O.BaO.P/sub 2/O/sub 5/ systems have coefficients of thermal expansion in the range 140 x 10/sup -1/ per /sup 0/C less than or equal to ..cap alpha.. less than or equal to 225 x 10/sup -7/ per /sup 0/C and fracture toughness values generally greater than those of phosphate glasses; they are suitable for fabricating seals to high thermal expansion metals. Crystal phases include NaPo/sub 3/, (NaPO/sub 3/)/sub 3/, NaBa(PO/sub 3/)/sub 3/, and NaCa(PO/sub 3/)/sub 3/. Glass ceramics formed in the Na/sub 2/O.Al/sub 2/O/sub 3/.P/sub 2/O/sub 5/ systems have coefficients of thermal expansion greater than 240 x 10/sup -7/ per /sup 0/C, but they have extensive microcracking. Due to their low thermal expansion values (..cap alpha.. less than or equal to 120 x 10/sup -7/ per /sup 0/C), glass ceramics in the Li/sub 2/O.BaO.P/sub 2/O/sub 5/ system are unsuitable for sealing to high thermal expansion metals.

  5. Analysis of Thermal Expansivity of Solids Under High Pressures

    NASA Astrophysics Data System (ADS)

    Sunil, K.; Singh, P. K.; Sharma, B. S.

    2012-08-01

    For investigating the thermal expansivity of solids under high pressures we have developed a formulation using the relationship between the reciprocal of pressure derivative of bulk modulus and the ratio of pressure and bulk modulus. The formulation presented here satisfies the boundary conditions both at zero-pressure and also in the limit of infinite pressure at extreme compression. A physically acceptable relationship has been obtained between the Anderson-Grüneisen parameter and the pressure derivatives of bulk modulus. The formulation has been applied to determine the pressure dependence of thermal expansivity of NaCl, MgO and the earth lower mantle minerals.

  6. Thermal performance of windows having high solar transmittance

    SciTech Connect

    Rubin, M.; Selkowitz, S.

    1981-07-01

    Antireflected polyester films and low-iron glass sheets have values of solar transmittance that are substantially higher than those of their untreated counterparts. The plastic films utilize coatings to reduce loses due to surface reflectance and the glass is made with low levels of impurities to reduce adsorption within the material itself. The optical and thermal properties of these materials are discussed and the solar and thermal characteristics of windows incorporating high-transmittance glazing layers are derived. Comparisons among these and other types of windows are made on the basis of net energy use for residential buildings in winter.

  7. Thermal management system options for high power space platforms

    NASA Technical Reports Server (NTRS)

    Sadunas, J. A.; Lehtinen, A.; Parish, R.

    1985-01-01

    Thermal Management System (TMS) design options for a high power (75kWe), low earth orbit, multimodule space platform were investigated. The approach taken was to establish a baseline TMS representative of current technology, and to make incremental improvements through successive subsystem trades that lead to a candidate TMS. The TMS trades included centralized and decentralized transport, single-phase and two-phase transport, alternate working fluids, liquid loop and heat pipe radiators, deployed fixed, body mounted and steerable radiators, and thermal storage. The subsystem options were evaluated against criteria such as weight, TMS power requirement, reliability, system isothermality penalty, and growth potential.

  8. High temperature underground thermal energy storage system for solar energy

    NASA Technical Reports Server (NTRS)

    Collins, R. E.

    1980-01-01

    The activities feasibility of high temperature underground thermal storage of energy was investigated. Results indicate that salt cavern storage of hot oil is both technically and economically feasible as a method of storing huge quantities of heat at relatively low cost. One particular system identified utilizes a gravel filled cavern leached within a salt dome. Thermal losses are shown to be less than one percent of cyclically transferred heat. A system like this having a 40 MW sub t transfer rate capability and over eight hours of storage capacity is shown to cost about $13.50 per KWh sub t.

  9. Obtaining high thermally conductive materials by pressing from the granulate

    NASA Astrophysics Data System (ADS)

    Ditts, A.; Revva, I.; Pautova, Y.; Pogrebenkov, V.; Nepochatov, Y.; Galashov, E.; Tarnovskiy, R.

    2015-01-01

    This work contains results of investigation of obtaining high thermally conductive ceramics from commercial powders of aluminum nitride and yttrium oxide by the method of monoaxial compaction of granulate. The principal scheme of preparation is proposed and technological properties of granulate are defined. Compaction conditions for simple items to use as heat removal in microelectronics and power electrical engineering have been established. Investigations of thermophysical properties of obtained ceramics and its structure by the XRD and SEM methods have been carried out. Ceramics with thermal conductivity from 172 to 174 W/m·K has been obtained as result of this work.

  10. Electromagnetic inhibition of high frequency thermal bonding machine

    NASA Astrophysics Data System (ADS)

    He, Hong; Zhang, Qing-qing; Li, Hang; Zhang, Da-jian; Hou, Ming-feng; Zhu, Xian-wei

    2011-12-01

    The traditional high frequency thermal bonding machine had serious radiation problems at dominant frequency, two times frequency and three times frequency. Combining with its working principle, the problems of electromagnetic compatibility were studied, three following measures were adopted: 1.At the head part of the high frequency thermal bonding machine, resonant circuit attenuator was designed. The notch groove and reaction field can make the radiation being undermined or absorbed; 2.The electromagnetic radiation shielding was made for the high frequency copper power feeder; 3.Redesigned the high-frequency oscillator circuit to reduce the output of harmonic oscillator. The test results showed that these measures can make the output according with the national standard of electromagnetic compatibility (GB4824-2004-2A), the problems of electromagnetic radiation leakage can be solved, and good social, environmental and economic benefits would be brought.

  11. Directional solidification at ultra-high thermal gradient

    NASA Technical Reports Server (NTRS)

    Flemings, M. C.; Lee, D. S.; Neff, M. A.

    1980-01-01

    A high gradient controlled solidification (HGC) furnace was designed and operated at gradients up to 1800 C/cm to continuously produce aluminum alloys. Rubber '0' rings for the water cooling chamber were eliminated, while still maintaining water cooling directly onto the solidified metal. An HGC unit for high temperature ferrous alloys was also designed. Successful runs were made with cast iron, at thermal gradients up to 500 C/cm.

  12. High-efficiency photonic crystal narrowband thermal emitters

    NASA Astrophysics Data System (ADS)

    Farfan, G. B.; Su, M. F.; Reda Taha, M. M.; El-Kady, I.

    2010-02-01

    Photonic crystals (PhC) are artificial structures fabricated with a periodicity in the dielectric function. This periodic electromagnetic potential results in creation of energy bandgaps where photon propagation is prohibited. PhC structures have promising use in thermal applications if optimized to operate at specific thermal emission spectrum. Here, novel utilization of optimized PhC's in thermal applications is presented. We demonstrate through numerical simulation the modification of the thermal emission spectrum by a metallic photonic crystal (PhC) to create high-efficiency multispectral thermal emitters. These emitters funnel radiation from a broad emission spectrum associated with a Plancklike distribution into a prescribed narrow emission band. A detailed quantitative evaluation of the spectral and power efficiencies of a PhC thermal emitter and its portability across infrared (IR) spectral bands are provided. We show an optimized tungsten PhC with a predominant narrow-band emission profile with an emitter efficiency that is more than double that of an ideal blackbody and ~65-75% more power-efficiency across the IR spectrum. We also report on using optimal three-dimensional Lincoln log photonic crystal (LL-PhC) emitters for thermophotovoltaic (TPV) generation as opposed to using a passive filtering approach to truncate the broadband thermal source emission to match the bandgap of a photovoltaic (PV) cell. The emitter performance is optimized for the 1-2μm PV band using different PhC materials, specifically copper, silver and gold. The use of the proposed PhC in TPV devices can produce significant energy savings not reported before. The optimal design of the PhC geometry is obtained by implementing a variety of optimization methods integrated with artificial intelligence (AI) algorithms.

  13. High conductivity, low cost aluminum composite for thermal management

    SciTech Connect

    Sommer, J.L.

    1997-04-01

    In order to produce an inexpensive packaging material that exhibits high thermal conductivity and low CTE, Technical Research Associates, Inc. (TRA) has shown in Phase I the feasibility of incorporating natural flake graphite in an aluminum matrix. TRA has developed a proprietary coating technique where graphite flakes have been coated with a thin layer of molybdenum/molybdenum carbide (approximately 0.2 microns). This barrier coating can protect the graphite flake from chemical reaction and high temperature degradation in molten aluminum silicon alloys. Methods to successfully vacuum infiltrate coated flake with molten aluminum alloys were developed. The resulted metal matrix composites exhibited lower CTE than aluminum metal. The CTE of the composites were significantly lower than aluminum and its alloys. The CTE can potentially be tailored for specific applications. The in plane thermal conductivity was higher than the aluminum matrix alloy. The thermal conductivity and CTE of the composite may be significantly improved by improving the bond strength of the molybdenum coating on the graphite flake. The flake can potentially be incorporated in the molten aluminum and pressure die cast to align the flakes within the aluminum matrix. By preferentially aligning high conductivity graphite flakes within a plane or direction, the thermal conductivity of the resulting composite will be above pure aluminum in the alignment direction.

  14. Organic underlayer materials with exceptionally high thermal stability

    NASA Astrophysics Data System (ADS)

    Cheon, Hwan-Sung; Yoon, Kyong-Ho; Kim, Min-Soo; Oh, Sung Bae; Song, Jee-Yun; Tokareva, Nataliya; Kim, Jong-Seob; Chang, Tuwon

    2009-03-01

    Multilayer hardmask (MLHM) schemes have been implemented as an indispensable process for ArF lithography which continues to demand thinner photoresist films. There are many variations of MLHM and semiconductor manufacturers choose to adopt their own designs, depending on their specific needs and technical advances. The quad-layer stack consisting of photoresist, organic ARC, CVD Si hardmask, and spin-on carbon underlayer is one of them. Despite the need for wafer transporting between the spin track and CVD equipment, this scheme is attractive because it can avoid laborious elaboration of sophisticated etching chemistries for spin-on Si-ARC and carbon underlayer. One of the issues arising from the mixed film forming process is the thermal stability of carbon underlayer at high temperatures during the CVD process of the Si hardmask. Organic underlayer which shows high thermal stability is crucial for this mixed hardmask process. These types of thermally stable organic film can also be used for other applications such as the spacer patterning technique for pitch size shrinkage. In this paper, we discuss the development of organic resins with high thermal stability, their physical properties, and their lithographic behaviors in the MLHM schemes.

  15. Applications of heat pipes for high thermal load beam lines

    SciTech Connect

    Shu, D.; Mortazavi, P.; Rarback, H.; Howells, M.R.

    1985-01-01

    The high flux beam produced by insertion devices often requires special heat removal techniques. For the optical elements used in such high thermal load beam lines, the required precision demands a highly accurate design. Heat pipe cooling of critical elements of the X-1 beam line at the National Synchrotron Light Source is described. This method reduces vibrations caused by water cooling systems and simplifies the design. In some of these designs, deposited heat must be transferred through unbonded contact interfaces. A pinhole assembly and a beam position monitor designed for the X-1 beam line both transfer heat through such interfaces in an ultrahigh vacuum environment. The fundamental design objective is that of removing the heat with minimal interface thermal resistance. We present our test method and results for measuring the thermal resistance across metallic interfaces as a function of contact pressure. The design of some devices which utilize both heat pipes and thermal contact interfaces will also be described. 12 refs., 8 figs.

  16. Thermal lensing compensation optics for high power lasers

    NASA Astrophysics Data System (ADS)

    Scaggs, Michael; Haas, Gil

    2011-03-01

    Athermalization of focusing objectives is a common technique for optimizing imaging systems in the infrared where thermal effects are a major concern. The athermalization is generally done within the spectrum of interest and not generally applied to a single wavelength. The predominate glass used with high power infrared lasers in the near infrared of one micron, such as Nd:YAG and fiber lasers, is fused silica which has excellent thermal properties. All glasses, however, have a temperature coefficient of index of refraction (dn/dT) where as the glass heats up its index of refraction changes. Most glasses, fused silica included, have a positive dn/dT. A positive dn/dT will cause the focal length of the lens to decrease with a temperature rise. Many of the fluoride glasses, like CaF2, BaF2, LiF2, etc. have a negative dn/dT. By applying athermalization techniques of glass selection and optical design, the thermal lensing in a laser objective of a high power laser system can be substantially mitigated. We describe a passive method for minimizing thermal lensing of high power laser optics.

  17. High-field thermal transport properties of REBCO coated conductors

    NASA Astrophysics Data System (ADS)

    Bonura, Marco; Senatore, Carmine

    2015-02-01

    The use of REBCO coated conductors (CCs) is envisaged for many applications, extending from power cables to high-field magnets. Whatever the case, thermal properties of REBCO tapes play a key role for the stability of superconducting devices. In this work, we present the first study on the longitudinal thermal conductivity (κ) of REBCO CCs in magnetic fields up to 19 T applied both parallel and perpendicularly to the thermal-current direction. Copper-stabilized tapes from six industrial manufacturers have been investigated. We show that zero-field κ of CCs can be calculated with an accuracy of +/- 15% from the residual resistivity ratio of the stabilizer and the Cu/non-Cu ratio. Measurements performed at high fields have allowed us to evaluate the consistency of the procedures generally used for estimating in-field κ in the framework of the Wiedemann-Franz law from an electrical characterization of the materials. In-field data are intended to provide primary ingredients for the thermal stability analysis of high-temperature superconductor-based magnets.

  18. IMPULSE---an advanced, high performance nuclear thermal propulsion system

    SciTech Connect

    Petrosky, L.J.; Disney, R.K.; Mangus, J.D. ); Gunn, S.A.; Zweig, H.R. )

    1993-01-10

    IMPULSE is an advanced nuclear propulsion engine for future space missions based on a novel conical fuel. Fuel assemblies are formed by stacking a series of truncated (U, Zr)C cones with non-fueled lips. Hydrogen flows radially inward between the cones to a central plenum connected to a high performance bell nozzle. The reference IMPULSE engine rated at 75,000 lb thrust and 1800 MWt weighs 1360 kg and is 3.65 meters in height and 81 cm in diameter. Specific impulse is estimated to be 1000 for a 15 minute life at full power. If longer life times are required, the operating temperature can be reduced with a concomitant decrease in specific impulse. Advantages of this concept include: well defined coolant paths without outlet flow restrictions; redundant orificing; very low thermal gradients and hence, thermal stresses, across the fuel elements; and reduced thermal stresses because of the truncated conical shape of the fuel elements.

  19. Antioxidant-Based Phase-Change Thermal Interface Materials with High Thermal Stability

    NASA Astrophysics Data System (ADS)

    Aoyagi, Yasuhiro; Chung, D. D. L.

    2008-04-01

    This work provides phase-change thermal interface materials (TIMs) with high thermal stability and high heat of fusion. They are based on antioxidants mainly in the form of hydrocarbons with linear segments. The thermal stability is superior to paraffin wax and four commercial phase-change materials (PCMs). The use of 98.0 wt.% thiopropionate antioxidant (SUMILIZER TP-D) with 2.0 wt.% sterically half-hindered phenolic antioxidant (GA80) as the matrix and the use of 16 vol.% boron nitride particles as the solid component give a PCM with a 100°C lifetime indicator of 5.3 years, in contrast to 0.95 year or less for the commercial PCMs. The heat of fusion is much higher than those of commercial PCMs; the values for antioxidants with nonbranched molecular structures exceed that of wax; the value for one with a branched structure is slightly below that of wax. The phase-change properties are degraded by heating at 150°C much less than those of the commercial PCMs. The stability of the heat of fusion upon phase-change cycling is also superior. The viscosity is essentially unaffected by heating at 150°C. Commercial PCMs give slightly lower values of the thermal contact conductance for the case of rough (12 μm) mating surfaces, in spite of the lower values of the bond-line thickness.

  20. High thermal conductivity of chain-oriented amorphous polythiophene.

    PubMed

    Singh, Virendra; Bougher, Thomas L; Weathers, Annie; Cai, Ye; Bi, Kedong; Pettes, Michael T; McMenamin, Sally A; Lv, Wei; Resler, Daniel P; Gattuso, Todd R; Altman, David H; Sandhage, Kenneth H; Shi, Li; Henry, Asegun; Cola, Baratunde A

    2014-05-01

    Polymers are usually considered thermal insulators, because the amorphous arrangement of the molecular chains reduces the mean free path of heat-conducting phonons. The most common method to increase thermal conductivity is to draw polymeric fibres, which increases chain alignment and crystallinity, but creates a material that currently has limited thermal applications. Here we show that pure polythiophene nanofibres can have a thermal conductivity up to ∼ 4.4 W m(-1) K(-1) (more than 20 times higher than the bulk polymer value) while remaining amorphous. This enhancement results from significant molecular chain orientation along the fibre axis that is obtained during electropolymerization using nanoscale templates. Thermal conductivity data suggest that, unlike in drawn crystalline fibres, in our fibres the dominant phonon-scattering process at room temperature is still related to structural disorder. Using vertically aligned arrays of nanofibres, we demonstrate effective heat transfer at critical contacts in electronic devices operating under high-power conditions at 200 °C over numerous cycles. PMID:24681778

  1. An innovative system for heating and cooling a gymnasium using integrated photovoltaic-thermal solar collectors

    SciTech Connect

    Fanchiotti, A.; Herkel, S.; Laukamp, H.; Priolo, C.

    1996-11-01

    The paper describes a new solar energy based system to heat and cool a gymnasium and to generate electricity in the city of Palermo, Italy. The gymnasium will be built in 1996 as part of the structures that will host the Universiadi Games in 1997. Main objectives of the project are: (a) to grant better environmental conditions in the area occupied by the public, with limited use of fossil energy; (b) to reduce the temperature of the photovoltaic elements, thus increasing their efficiency. The system consists of an array of 203 m{sup 2} integrated photovoltaic-thermal solar air collectors. In the winter mode of operation, the heated air is passed through the concrete benches where the public is seated. In the summer mode of operation outside air is evaporatively cooled, passed through the benches, then exhausted to the outside after passing through the collectors. The paper presents some of the results obtained by simulating the system at the design stage for winter conditions.

  2. Highly thermally conductive and mechanically strong graphene fibers.

    PubMed

    Xin, Guoqing; Yao, Tiankai; Sun, Hongtao; Scott, Spencer Michael; Shao, Dali; Wang, Gongkai; Lian, Jie

    2015-09-01

    Graphene, a single layer of carbon atoms bonded in a hexagonal lattice, is the thinnest, strongest, and stiffest known material and an excellent conductor of heat and electricity. However, these superior properties have yet to be realized for graphene-derived macroscopic structures such as graphene fibers. We report the fabrication of graphene fibers with high thermal and electrical conductivity and enhanced mechanical strength. The inner fiber structure consists of large-sized graphene sheets forming a highly ordered arrangement intercalated with small-sized graphene sheets filling the space and microvoids. The graphene fibers exhibit a submicrometer crystallite domain size through high-temperature treatment, achieving an enhanced thermal conductivity up to 1290 watts per meter per kelvin. The tensile strength of the graphene fiber reaches 1080 megapascals. PMID:26339027

  3. Highly thermally conductive and mechanically strong graphene fibers

    NASA Astrophysics Data System (ADS)

    Xin, Guoqing; Yao, Tiankai; Sun, Hongtao; Scott, Spencer Michael; Shao, Dali; Wang, Gongkai; Lian, Jie

    2015-09-01

    Graphene, a single layer of carbon atoms bonded in a hexagonal lattice, is the thinnest, strongest, and stiffest known material and an excellent conductor of heat and electricity. However, these superior properties have yet to be realized for graphene-derived macroscopic structures such as graphene fibers. We report the fabrication of graphene fibers with high thermal and electrical conductivity and enhanced mechanical strength. The inner fiber structure consists of large-sized graphene sheets forming a highly ordered arrangement intercalated with small-sized graphene sheets filling the space and microvoids. The graphene fibers exhibit a submicrometer crystallite domain size through high-temperature treatment, achieving an enhanced thermal conductivity up to 1290 watts per meter per kelvin. The tensile strength of the graphene fiber reaches 1080 megapascals.

  4. The high-order quantum coherence of thermal light

    NASA Astrophysics Data System (ADS)

    Chen, Hui

    Thermal light, such as sunlight, is usually considered classical light. In a macroscopic picture, classical theory successfully explained the first-order coherence phenomena of thermal light. The macroscopic theory, based on the statistical behavior of light intensity fluctuations, however, can only phenomenologically explain the second- or higher-order coherence phenomena of thermal light. This thesis introduces a microscopic quantum picture, based on the interferences of a large number of randomly distributed and randomly radiated subfields, wavepackets or photons, to the study of high-order coherence of thermal light. This thesis concludes that the second-order intensity fluctuation correlation is caused by nonlocal interference: a pair of wavepackets, which are randomly paired together, interferes with the pair itself at two distant space-time coordinates. This study has the following practical motivations: (1) to simulate N-qbits. Practical quantum computing requires quantum bits(qubits) of N-digit to represent all possible integers from 0 to 2N-1 simultaneously. A large number of independent particles can be prepared to represent a large set of N orthogonal |0> and |1> bits. In fact, based on our recent experiments of simulating the high-order correlation of entangled photons, thermal radiation is suggested as a promising source for quantum information processing. (2) to achieve sunlight ghost imaging. Ghost imaging has three attractive non-classical features: (a) the ghost camera can "see" targets that can never be seen by a classic camera; (2) it is turbulence-free; and (3) its spatial resolution is mainly determined by the angular diameter of the light source. For example, a sunlight ghost image of an object on earth may achieve a spatial resolution of 200 micrometer because the angular diameter of sun is 0.53 degree with respect to Earth. Although ghost imaging has been experimental demonstrated by using entangled photon pairs and "pseudo-thermal light

  5. Graphene oxide immobilized enzymes show high thermal and solvent stability

    NASA Astrophysics Data System (ADS)

    Hermanová, Soňa; Zarevúcká, Marie; Bouša, Daniel; Pumera, Martin; Sofer, Zdeněk

    2015-03-01

    The thermal and solvent tolerance of enzymes is highly important for their industrial use. We show here that the enzyme lipase from Rhizopus oryzae exhibits exceptionally high thermal stability and high solvent tolerance and even increased activity in acetone when immobilized onto a graphene oxide (GO) nanosupport prepared by Staudenmaier and Brodie methods. We studied various forms of immobilization of the enzyme: by physical adsorption, covalent attachment, and additional crosslinking. The activity recovery was shown to be dependent on the support type, enzyme loading and immobilization procedure. Covalently immobilized lipase showed significantly better resistance to heat inactivation (the activity recovery was 65% at 70 °C) in comparison with the soluble counterpart (the activity recovery was 65% at 40 °C). Physically adsorbed lipase achieved over 100% of the initial activity in a series of organic solvents. These findings, showing enhanced thermal stability and solvent tolerance of graphene oxide immobilized enzyme, will have a profound impact on practical industrial scale uses of enzymes for the conversion of lipids into fuels.The thermal and solvent tolerance of enzymes is highly important for their industrial use. We show here that the enzyme lipase from Rhizopus oryzae exhibits exceptionally high thermal stability and high solvent tolerance and even increased activity in acetone when immobilized onto a graphene oxide (GO) nanosupport prepared by Staudenmaier and Brodie methods. We studied various forms of immobilization of the enzyme: by physical adsorption, covalent attachment, and additional crosslinking. The activity recovery was shown to be dependent on the support type, enzyme loading and immobilization procedure. Covalently immobilized lipase showed significantly better resistance to heat inactivation (the activity recovery was 65% at 70 °C) in comparison with the soluble counterpart (the activity recovery was 65% at 40 °C). Physically adsorbed

  6. Innovative high pressure gas MEM's based neutron detector for ICF and active SNM detection.

    SciTech Connect

    Martin, Shawn Bryan; Derzon, Mark Steven; Renzi, Ronald F.; Chandler, Gordon Andrew

    2007-12-01

    An innovative helium3 high pressure gas detection system, made possible by utilizing Sandia's expertise in Micro-electrical Mechanical fluidic systems, is proposed which appears to have many beneficial performance characteristics with regards to making these neutron measurements in the high bremsstrahlung and electrical noise environments found in High Energy Density Physics experiments and especially on the very high noise environment generated on the fast pulsed power experiments performed here at Sandia. This same system may dramatically improve active WMD and contraband detection as well when employed with ultrafast (10-50 ns) pulsed neutron sources.

  7. High-temperature ceramic heat exchanger element for a solar thermal receiver

    NASA Technical Reports Server (NTRS)

    Strumpf, H. J.; Kotchick, D. M.; Coombs, M. G.

    1982-01-01

    A study has been completed on the development of a high-temperature ceramic heat exchanger element to be integrated into a solar reciver producing heated air. A number of conceptual designs were developed for heat exchanger elements of differing configuration. These were evaluated with respect to thermal performance, pressure drop, structural integrity, and fabricability. The final design selection identified a finned ceramic shell as the most favorable concept. The ceramic shell is surrounded by a larger metallic shell. The flanges of the two shells are sealed to provide a leak-tight pressure vessel. The ceramic shell is fabricated by an innovative combination of slip casting the receiver walls and precision casting the heat transfer finned plates. The fins are bonded to the shell during firing. Fabrication of a one-half scale demonstrator ceramic receiver has been completed.

  8. High-Rise Buildings versus Outdoor Thermal Environment in Chongqing

    PubMed Central

    Lu, Jun; Chen, Jin-hua; Tang, Ying; Feng, Yuan; Wang, Jin-sha

    2007-01-01

    This paper gives a brief description of the over quick urbanization since Chongqing, one of the biggest cities in China, has been a municipality directly under the Central Government in 1997, excessive development and exceeding increase of high-rise buildings because of its special geographical position which finally leads to the worsening of the urban outdoor thermal environment. Then, this paper makes a bright balance to the field measurement and simulated results of the wind speed field, temperature field of one multifunctional high-rise building in Chongqing university located in the city center, and the contrasted results validate the correctness of CFD in the outdoor thermal environmental simulation, expose the disadvantages of high-rise buildings on the aspects of blocking the wind field, decreasing wind speed which results in accumulation of the air-conditioning heat revolving around and periscian region where sunshine can not rip into. Finally, in order to improve the urban outdoor thermal environment near the high-rise buildings especially for the angle of natural ventilation, this paper simulates the wind environment in different architectural compositions and architectural layouts by CFD, and the simulated results show that freestyle and tower buildings which can guarantee the wind speed and take the air-conditioning heat away are much suitable and reasonable for the special Chongqing geography. These conclusions can also be used as a reference in other mountain cities, especially for the one with a great number of populations.

  9. High-field electrical and thermal transport in suspended graphene.

    PubMed

    Dorgan, Vincent E; Behnam, Ashkan; Conley, Hiram J; Bolotin, Kirill I; Pop, Eric

    2013-10-01

    We study the intrinsic transport properties of suspended graphene devices at high fields (≥1 V/μm) and high temperatures (≥1000 K). Across 15 samples, we find peak (average) saturation velocity of 3.6 × 10(7) cm/s (1.7 × 10(7) cm/s) and peak (average) thermal conductivity of 530 W m(-1) K(-1) (310 W m(-1) K(-1)) at 1000 K. The saturation velocity is 2-4 times and the thermal conductivity 10-17 times greater than in silicon at such elevated temperatures. However, the thermal conductivity shows a steeper decrease at high temperature than in graphite, consistent with stronger effects of second-order three-phonon scattering. Our analysis of sample-to-sample variation suggests the behavior of "cleaner" devices most closely approaches the intrinsic high-field properties of graphene. This study reveals key features of charge and heat flow in graphene up to device breakdown at ~2230 K in vacuum, highlighting remaining unknowns under extreme operating conditions. PMID:23387323

  10. High-Field Electrical and Thermal Transport in Suspended Graphene

    NASA Astrophysics Data System (ADS)

    Dorgan, Vincent E.; Behnam, Ashkan; Conley, Hiram J.; Bolotin, Kirill I.; Pop, Eric

    2013-10-01

    We study the intrinsic transport properties of suspended graphene devices at high fields (>1 V/um) and high temperatures (>1000 K). Across 15 samples, we find peak (average) saturation velocity of 3.6x10^7 cm/s (1.7x10^7 cm/s), and peak (average) thermal conductivity of 530 W/m/K (310 W/m/K), at 1000 K. The saturation velocity is 2-4 times and the thermal conductivity 10-17 times greater than in silicon at such elevated temperatures. However, the thermal conductivity shows a steeper decrease at high temperature than in graphite, consistent with stronger effects of second-order three-phonon scattering. Our analysis of sample-to-sample variation suggests the behavior of "cleaner" devices most closely approaches the intrinsic high-field properties of graphene. This study reveals key features of charge and heat flow in graphene up to device breakdown at ~2230 K in vacuum, highlighting remaining unknowns under extreme operating conditions.

  11. Ultra high energy neutrinos: absorption, thermal effects and signatures

    SciTech Connect

    Lunardini, Cecilia; Sabancilar, Eray; Yang, Lili E-mail: Eray.Sabancilar@asu.edu

    2013-08-01

    We study absorption of ultra high energy neutrinos by the cosmic neutrino background, with full inclusion of the effect of the thermal distribution of the background on the resonant annihilation channel. For a hierarchical neutrino mass spectrum (with at least one neutrino with mass below ∼ 10{sup −2} eV), thermal effects are important for ultra high energy neutrino sources at z∼>16. The neutrino transmission probability shows no more than two separate suppression dips since the two lightest mass eigenstates contribute as a single species when thermal effects are included. Results are applied to a number of models of ultra high energy neutrino emission. Suppression effects are strong for sources that extend beyond z ∼ 10, which can be realized for certain top down scenarios, such as superheavy dark matter decays, cosmic strings and cosmic necklaces. For these, a broad suppression valley should affect the neutrino spectrum at least in the energy interval 10{sup 12}−10{sup 13} GeV — which therefore is disfavored for ultra high energy neutrino searches — with only a mild dependence on the neutrino mass spectrum and hierarchy. The observation of absorption effects would indicate a population of sources beyond z ∼ 10, and favor top-down mechanisms; it would also be an interesting probe of the physics of the relic neutrino background in the unexplored redshift interval z ∼ 10–100.

  12. High-Fidelity Coupled Monte-Carlo/Thermal-Hydraulics Calculations

    NASA Astrophysics Data System (ADS)

    Ivanov, Aleksandar; Sanchez, Victor; Ivanov, Kostadin

    2014-06-01

    Monte Carlo methods have been used as reference reactor physics calculation tools worldwide. The advance in computer technology allows the calculation of detailed flux distributions in both space and energy. In most of the cases however, those calculations are done under the assumption of homogeneous material density and temperature distributions. The aim of this work is to develop a consistent methodology for providing realistic three-dimensional thermal-hydraulic distributions by coupling the in-house developed sub-channel code SUBCHANFLOW with the standard Monte-Carlo transport code MCNP. In addition to the innovative technique of on-the fly material definition, a flux-based weight-window technique has been introduced to improve both the magnitude and the distribution of the relative errors. Finally, a coupled code system for the simulation of steady-state reactor physics problems has been developed. Besides the problem of effective feedback data interchange between the codes, the treatment of temperature dependence of the continuous energy nuclear data has been investigated.

  13. Strength of VGCF/Al Composites for High Thermal Conductivity

    NASA Astrophysics Data System (ADS)

    Fukuchi, Kohei; Sasaki, Katsuhiko; Imanishi, Terumitsu; Katagiri, Kazuaki; Kakitsuji, Atsushi; Shimizu, Akiyuki

    In this paper, the evaluation of the strength of the VGCF/Aluminum composites which have high thermal conductivity is reported. VGCF (Vapor Growth Carbon Fiber) is a kind of the Carbon nanotube (CNT) which has very high thermal conductivity as well as CNT. The composites are made by spark plasma sintering. The stress-strain curves of the composites are obtained by the tensile tests and show that the composites have brittle behavior. The brittleness of the composites increases with increase in the volume fraction of VGCF. A numerical simulation based on the micromechanics is conducted to estimate nonlinear behavior in the elastic deformation and plastic deformation of the stress-strain relations of the composites. The theories of Eshelby, Mori-Tanaka, Weibull, and Ramberg-Osgood are employed for the numerical simulation. The simulations give some information of the microstructural change in the composite related to the volume fraction of VGCF.

  14. Thermal effects in high average power optical parametric amplifiers.

    PubMed

    Rothhardt, Jan; Demmler, Stefan; Hädrich, Steffen; Peschel, Thomas; Limpert, Jens; Tünnermann, Andreas

    2013-03-01

    Optical parametric amplifiers (OPAs) have the reputation of being average power scalable due to the instantaneous nature of the parametric process (zero quantum defect). This Letter reveals serious challenges originating from thermal load in the nonlinear crystal caused by absorption. We investigate these thermal effects in high average power OPAs based on beta barium borate. Absorption of both pump and idler waves is identified to contribute significantly to heating of the nonlinear crystal. A temperature increase of up to 148 K with respect to the environment is observed and mechanical tensile stress up to 40 MPa is found, indicating a high risk of crystal fracture under such conditions. By restricting the idler to a wavelength range far from absorption bands and removing the crystal coating we reduce the peak temperature and the resulting temperature gradient significantly. Guidelines for further power scaling of OPAs and other nonlinear devices are given. PMID:23455291

  15. The coefficient of thermal expansion of highly enriched 28Si

    NASA Astrophysics Data System (ADS)

    Bartl, Guido; Nicolaus, Arnold; Kessler, Ernest; Schödel, René; Becker, Peter

    2009-10-01

    For the new definition of the SI unit of mass based on a fundamental constant, a redetermination of Avogadro's constant is the goal of an international collaboration of numerous national laboratories and universities. Since a relative uncertainty of about 2 × 10-8 is aimed at, the macroscopic density, the isotopic composition and the volume of the unit cell of a silicon single crystal have to be measured with high precision. One step to improve the precision was the production of a silicon crystal of highly enriched 28Si. This paper addresses the effect of thermal expansion of that material in order to account for a possible discrepancy between the coefficient of thermal expansion (CTE) of natural silicon and that of 28Si. The results of two independent CTE measuring methods are presented and compared in this paper.

  16. High temperature solar thermal technology: The North Africa Market

    SciTech Connect

    Not Available

    1990-12-01

    High temperature solar thermal (HTST) technology offers an attractive option for both industrialized and non-industrialized countries to generate electricity and industrial process steam. The purpose of this report is to assess the potential market for solar thermal applications in the North African countries of Algeria, Egypt, Morocco and Tunisia. North Africa was selected because of its outstanding solar resource base and the variety of applications to be found there. Diminishing oil and gas resources, coupled with expanding energy needs, opens a large potential market for the US industry. The US high temperature solar trough industry has little competition globally and could build a large market in these areas. The US is already familiar with certain solar markets in North Africa due to the supplying of substantial quantities of US-manufactured flat plate collectors to this region.

  17. Thermal lens effects on highly pumped Yb:glass

    NASA Astrophysics Data System (ADS)

    Nishimura, Akihiko; Akaoka, Katsuaki; Ohzu, Akira; Sugiyama, Akira; Usami, Tsutomu; Matoba, Tohru

    2000-04-01

    Thermal lens effects on highly pumped Yb doped phosphate glass was measured by a Shack-Hartmann wavefront sensor for the development of compact chirped pulse amplification systems. High energy pump pulses of 1 - 2 Joules were produced by a flashlamp pumped Ti-sapphire laser. The pumping intensity on the Yb:glass surface exceeded 800 kW/cm2. The pulse energy of 330 mJ from Yb:glass was obtained with 53% slope efficiency with 0.5 Hz reputation. The absorbed pump energy generated the thermal lens effects inside the Yb:glass. The wavefront distortion completely disappeared after 300 ms of pump pulse. Neither heat accumulation nor pumping damage was observed on the Yb:glass.

  18. Do high-velocity clouds form by thermal instability?

    NASA Astrophysics Data System (ADS)

    Binney, James; Nipoti, Carlo; Fraternali, Filippo

    2009-08-01

    We examine the proposal that the HI `high-velocity' clouds (HVCs) surrounding the Milky Way and other disc galaxies form by condensation of the hot galactic corona via thermal instability. Under the assumption that the galactic corona is well represented by a non-rotating, stratified atmosphere, we find that for this formation mechanism to work the corona must have an almost perfectly flat entropy profile. In all other cases, the growth of thermal perturbations is suppressed by a combination of buoyancy and thermal conduction. Even if the entropy profile were nearly flat, cold clouds with sizes smaller than 10kpc could form in the corona of the Milky Way only at radii larger than 100kpc, in contradiction with the determined distances of the largest HVC complexes. Clouds with sizes of a few kpc can form in the inner halo only in low-mass systems. We conclude that unless even slow rotation qualitatively changes the dynamics of a corona, thermal instability is unlikely to be a viable mechanism for formation of cold clouds around disc galaxies.

  19. Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives

    SciTech Connect

    baney, Ronald; Tulenko, James

    2012-11-20

    The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:

  20. Thermal transport measurements in high-energy-density matter

    NASA Astrophysics Data System (ADS)

    Ping, Yuan

    2015-11-01

    Thermal conductivity is one of the most fundamental physical properties of matter. It determines the heat transport rate and has an enormous impact on a variety of mechanical, electrical, chemical, and nuclear systems. Thermal conduction is important in high energy density (HED) matter such as laboratory fusion plasmas, planetary cores, compact stars, and other celestial objects. Examples are in the ablation and instability growth in inertial confinement fusion (ICF) capsules, in energy loss from ICF hot spot, and in the evolution of Earth's core-mantle boundary. Despite the importance of thermal conductivity in HED systems, experimental measurements under relevant conditions are scarce and challenging. We have developed a method of differential heating for thermal conductivity measurements. In this talk, experimental designs will be described for four different platforms: optical laser heating, proton heating, laser-generated x-ray heating and XFEL heating. Data from various facilities will be presented and comparison with models will be discussed. This work was performed under DOE contract DE-AC52-07NA27344 with support from OFES Early Career program and LLNL LDRD program.

  1. High temperature thermal energy storage in steel and sand

    NASA Technical Reports Server (NTRS)

    Turner, R. H.

    1979-01-01

    The technical and economic potential for high temperature (343 C, 650 F) thermal energy storage in hollow steel ingots, pipes embedded in concrete, and for pipes buried in sand was evaluated. Because it was determined that concrete would separate from pipes due to thermal stresses, concrete was replaced by sand, which is free from thermal stresses. Variations of the steel ingot concept were not cost effective compared to the sand-pipe approach, therefore, the sand-pipe thermal storage unit (TSU) was evaluated in depth to assess the approximate tube spacing requirements consistent with different system performance characteristics and also attendant system costs. For large TSUs which do not require fast response times, the sand-pipe approach offers attractive possibilities. A pipe diameter about 9 cm (3.5 in) and pipe spacing of approximately 25 cm (10 in), with sand filling the interspaces, appears appropriate. Such a TSU system designed for 8 hours charge/discharge cycle has an energy unit storage cost (CE) of $2.63/kWhr-t and a power unit storage cost (Cp) of $42/kW-t (in 1977 dollars).

  2. Organic transistors with high thermal stability for medical applications

    NASA Astrophysics Data System (ADS)

    Kuribara, Kazunori; Wang, He; Uchiyama, Naoya; Fukuda, Kenjiro; Yokota, Tomoyuki; Zschieschang, Ute; Jaye, Cherno; Fischer, Daniel; Klauk, Hagen; Yamamoto, Tatsuya; Takimiya, Kazuo; Ikeda, Masaaki; Kuwabara, Hirokazu; Sekitani, Tsuyoshi; Loo, Yueh-Lin; Someya, Takao

    2012-03-01

    The excellent mechanical flexibility of organic electronic devices is expected to open up a range of new application opportunities in electronics, such as flexible displays, robotic sensors, and biological and medical electronic applications. However, one of the major remaining issues for organic devices is their instability, especially their thermal instability, because low melting temperatures and large thermal expansion coefficients of organic materials cause thermal degradation. Here we demonstrate the fabrication of flexible thin-film transistors with excellent thermal stability and their viability for biomedical sterilization processes. The organic thin-film transistors comprise a high-mobility organic semiconductor, dinaphtho[2,3-b:2‧,3‧-f]thieno[3,2-b]thiophene, and thin gate dielectrics comprising a 2-nm-thick self-assembled monolayer and a 4-nm-thick aluminium oxide layer. The transistors exhibit a mobility of 1.2 cm2 V-1s-1 within a 2 V operation and are stable even after exposure to conditions typically used for medical sterilization.

  3. Thermal conductance of metal-diamond interfaces at high pressure.

    PubMed

    Hohensee, Gregory T; Wilson, R B; Cahill, David G

    2015-01-01

    The thermal conductance of interfaces between metals and diamond, which has a comparatively high Debye temperature, is often greater than can be accounted for by two-phonon processes. The high pressures achievable in a diamond anvil cell (DAC) can significantly extend the metal phonon density of states to higher frequencies, and can also suppress extrinsic effects by greatly stiffening interface bonding. Here we report time-domain thermoreflectance measurements of metal-diamond interface thermal conductance up to 50 GPa in the DAC for Pb, Au0.95Pd0.05, Pt and Al films deposited on type 1A natural [100] and type 2A synthetic [110] diamond anvils. In all cases, the thermal conductances increase weakly or saturate to similar values at high pressure. Our results suggest that anharmonic conductance at metal-diamond interfaces is controlled by partial transmission processes, where a diamond phonon that inelastically scatters at the interface absorbs or emits a metal phonon. PMID:25744853

  4. Fabrication of High Temperature Cermet Materials for Nuclear Thermal Propulsion

    NASA Technical Reports Server (NTRS)

    Hickman, Robert; Panda, Binayak; Shah, Sandeep

    2005-01-01

    Processing techniques are being developed to fabricate refractory metal and ceramic cermet materials for Nuclear Thermal Propulsion (NTP). Significant advances have been made in the area of high-temperature cermet fuel processing since RoverNERVA. Cermet materials offer several advantages such as retention of fission products and fuels, thermal shock resistance, hydrogen compatibility, high conductivity, and high strength. Recent NASA h d e d research has demonstrated the net shape fabrication of W-Re-HfC and other refractory metal and ceramic components that are similar to UN/W-Re cermet fuels. This effort is focused on basic research and characterization to identify the most promising compositions and processing techniques. A particular emphasis is being placed on low cost processes to fabricate near net shape parts of practical size. Several processing methods including Vacuum Plasma Spray (VPS) and conventional PM processes are being evaluated to fabricate material property samples and components. Surrogate W-Re/ZrN cermet fuel materials are being used to develop processing techniques for both coated and uncoated ceramic particles. After process optimization, depleted uranium-based cermets will be fabricated and tested to evaluate mechanical, thermal, and hot H2 erosion properties. This paper provides details on the current results of the project.

  5. NEUTRONIC REACTOR HAVING LOCALIZED AREAS OF HIGH THERMAL NEUTRON DENSITIES

    DOEpatents

    Newson, H.W.

    1958-06-01

    A nuclear reactor for the irradiation of materials designed to provide a localized area of high thermal neutron flux density in which the materials to be irradiated are inserted is described. The active portion of the reactor is comprised of a cubicle graphite moderator of about 25 feet in length along each axis which has a plurality of cylindrical channels for accommodatirg elongated tubular-shaped fuel elements. The fuel elements have radial fins for spacing the fuel elements from the channel walls, thereby providing spaces through which a coolant may be passed, and also to serve as a heatconductirg means. Ducts for accommnodating the sample material to be irradiated extend through the moderator material perpendicular to and between parallel rows of fuel channels. The improvement is in the provision of additional fuel element channels spaced midway between 2 rows of the regular fuel channels in the localized area surrounding the duct where the high thermal neutron flux density is desired. The fuel elements normally disposed in the channels directly adjacent the duct are placed in the additional channels, and the channels directly adjacent the duct are plugged with moderator material. This design provides localized areas of high thermal neutron flux density without the necessity of providing additional fuel material.

  6. High temperature thermal properties for metals used in LWR vessels

    NASA Astrophysics Data System (ADS)

    Rempe, J. L.; Knudson, D. L.

    2008-01-01

    Because of the impact that melt relocation and vessel failure has on subsequent progression and associated consequences of a light water reactor (LWR) accident, it is important to accurately predict the heatup and relocation of materials within the reactor vessel and heat transfer to and from the reactor vessel. Accurate predictions of such heat transfer phenomena require high temperature thermal properties. However, a review of vessel and structural steel material properties in severe accident analysis codes reveals that the required high temperature material properties are extrapolated with little, if any, data above 700 °C. To reduce uncertainties in predictions relying upon this extrapolated high temperature data, INL obtained data using laser-flash thermal diffusivity techniques for two metals used in LWR vessels: SA 533 Grade B, Class 1 (SA533B1) low alloy steel, which is used to fabricate most US LWR reactor vessels; and Type 304 Stainless Steel SS304, which is used in LWR vessel piping, penetration tubes, and internal structures. This paper summarizes the new data, compares it to existing data in the literature, and provides recommended correlations for thermal properties based on this data.

  7. Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems

    SciTech Connect

    2011-12-05

    HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun is not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNL’s metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800°C). A high-temperature tank in PNNL’s storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNL’s thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

  8. High Energy Density Thermal Batteries: Thermoelectric Reactors for Efficient Automotive Thermal Storage

    SciTech Connect

    2011-11-15

    HEATS Project: Sheetak is developing a new HVAC system to store the energy required for heating and cooling in EVs. This system will replace the traditional refrigerant-based vapor compressors and inefficient heaters used in today’s EVs with efficient, light, and rechargeable hot-and-cold thermal batteries. The high energy density thermal battery—which does not use any hazardous substances—can be recharged by an integrated solid-state thermoelectric energy converter while the vehicle is parked and its electrical battery is being charged. Sheetak’s converters can also run on the electric battery if needed and provide the required cooling and heating to the passengers—eliminating the space constraint and reducing the weight of EVs that use more traditional compressors and heaters.

  9. Highly defective oxides as sinter resistant thermal barrier coating

    DOEpatents

    Subramanian, Ramesh

    2005-08-16

    A thermal barrier coating material formed of a highly defective cubic matrix structure having a concentration of a stabilizer sufficiently high that the oxygen vacancies created by the stabilizer interact within the matrix to form multi-vacancies, thereby improving the sintering resistance of the material. The concentration of stabilizer within the cubic matrix structure is greater than that concentration of stabilizer necessary to give the matrix a peak ionic conductivity value. The concentration of stabilizer may be at least 30 wt. %. Embodiments include a cubic matrix of zirconia stabilized by at least 30-50 wt. % yttria, and a cubic matrix of hafnia stabilized by at least 30-50 wt. % gadolinia.

  10. LEDA - A HIGH-POWER TEST BED OF INNOVATION AND OPPORTUNITY

    SciTech Connect

    J. SCHNEIDER; R. SHEFFIELD

    2000-08-01

    The low-energy demonstration accelerator (LEDA) is an operational 6.7-MeV. 100-mA proton accelerator consisting of an injector, radio-frequency quadrupole (RFQ), and all associated integration equipment. In order to achieve this unprecedented level of performance (670-kW of beam power) from an RFQ, a number of design innovations were required. They will highlight a number of those more significant technical advances, including those in the proton injector, the RFQ configuration, the RF klystrons, the beam stop, and the challenges of beam measurements. In addition to identifying the importance of these innovations to LEDA performance, they will summarize the plans for further testing, and the possibilities for addition of more accelerating structures, including the planned use of very-low-beta super-conducting structures. LEDA's current and upgradable configuration is appropriate for several future high-power accelerators, including those for the transmutation of radioactive waste.

  11. Effective Thermal Conductivity of High Porosity Open Cell Nickel Foam

    NASA Technical Reports Server (NTRS)

    Sullins, Alan D.; Daryabeigi, Kamran

    2001-01-01

    The effective thermal conductivity of high-porosity open cell nickel foam samples was measured over a wide range of temperatures and pressures using a standard steady-state technique. The samples, measuring 23.8 mm, 18.7 mm, and 13.6 mm in thickness, were constructed with layers of 1.7 mm thick foam with a porosity of 0.968. Tests were conducted with the specimens subjected to temperature differences of 100 to 1000 K across the thickness and at environmental pressures of 10(exp -4) to 750 mm Hg. All test were conducted in a gaseous nitrogen environment. A one-dimensional finite volume numerical model was developed to model combined radiation/conduction heat transfer in the foam. The radiation heat transfer was modeled using the two-flux approximation. Solid and gas conduction were modeled using standard techniques for high porosity media. A parameter estimation technique was used in conjunction with the measured and predicted thermal conductivities at pressures of 10(exp -4) and 750 mm Hg to determine the extinction coefficient, albedo of scattering, and weighting factors for modeling the conduction thermal conductivity. The measured and predicted conductivities over the intermediate pressure values differed by 13%.

  12. High-precision thermal and electrical characterization of thermoelectric modules

    SciTech Connect

    Kolodner, Paul

    2014-05-15

    This paper describes an apparatus for performing high-precision electrical and thermal characterization of thermoelectric modules (TEMs). The apparatus is calibrated for operation between 20 °C and 80 °C and is normally used for measurements of heat currents in the range 0–10 W. Precision thermometry based on miniature thermistor probes enables an absolute temperature accuracy of better than 0.010 °C. The use of vacuum isolation, thermal guarding, and radiation shielding, augmented by a careful accounting of stray heat leaks and uncertainties, allows the heat current through the TEM under test to be determined with a precision of a few mW. The fractional precision of all measured parameters is approximately 0.1%.

  13. High thermal-transport capacity heat pipes for space radiators

    NASA Technical Reports Server (NTRS)

    Carlson, Albert W.; Gustafson, Eric; Roukis, Susan L.

    1987-01-01

    This paper presents the results of performance tests of several dual-slot heat pipe test articles. The dual-slot configuration has a very high thermal transport capability and has been identified as a very promising candidate for the radiator system for the NASA Space Station solar dynamic power modules. Two six-foot long aluminum heat pipes were built and tested with ammonia and acetone. A 20-ft long heat pipe was also built and tested with ammonia. The test results have been compared with performance predictions. A thermal transport capacity of 2000 W at an adverse tilt of 1 in. and a 1000 W capacity at an adverse tilt of 2 in. were achieved on the 20-ft long heat pipe. These values are in close agreement with the predicted performance limits.

  14. Thermal Hydraulics of the Very High Temperature Gas Cooled Reactor

    SciTech Connect

    Chang Oh; Eung Kim; Richard Schultz; Mike Patterson; Davie Petti

    2009-10-01

    The U.S Department of Energy (DOE) is conducting research on the Very High Temperature Reactor (VHTR) design concept for the Next Generation Nuclear Plant (NGNP) Project. The reactor design will be a graphite moderated, thermal neutron spectrum reactor that will produce electricity and hydrogen in a highly efficient manner. The NGNP reactor core will be either a prismatic graphite block type core or a pebble bed core. The NGNP will use very high-burnup, low-enriched uranium, TRISO-coated fuel, and have a projected plant design service life of 60 years. The VHTR concept is considered to be the nearest-term reactor design that has the capability to efficiently produce hydrogen. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during reactor core-accidents. The objectives of the NGNP Project are to: Demonstrate a full-scale prototype VHTR that is commercially licensed by the U.S. Nuclear Regulatory Commission, and Demonstrate safe and economical nuclear-assisted production of hydrogen and electricity. The DOE laboratories, led by the INL, perform research and development (R&D) that will be critical to the success of the NGNP, primarily in the areas of: • High temperature gas reactor fuels behavior • High temperature materials qualification • Design methods development and validation • Hydrogen production technologies • Energy conversion. This paper presents current R&D work that addresses fundamental thermal hydraulics issues that are relevant to a variety of possible NGNP designs.

  15. Thermal Protective Coating for High Temperature Polymer Composites

    NASA Technical Reports Server (NTRS)

    Barron, Andrew R.

    1999-01-01

    The central theme of this research is the application of carboxylate-alumoxane nanoparticles as precursors to thermally protective coatings for high temperature polymer composites. In addition, we will investigate the application of carboxylate-alumoxane nanoparticle as a component to polymer composites. The objective of this research was the high temperature protection of polymer composites via novel chemistry. The significance of this research is the development of a low cost and highly flexible synthetic methodology, with a compatible processing technique, for the fabrication of high temperature polymer composites. We proposed to accomplish this broad goal through the use of a class of ceramic precursor material, alumoxanes. Alumoxanes are nano-particles with a boehmite-like structure and an organic periphery. The technical goals of this program are to prepare and evaluate water soluble carboxylate-alumoxane for the preparation of ceramic coatings on polymer substrates. Our proposed approach is attractive since proof of concept has been demonstrated under the NRA 96-LeRC-1 Technology for Advanced High Temperature Gas Turbine Engines, HITEMP Program. For example, carbon and Kevlar(tm) fibers and matting have been successfully coated with ceramic thermally protective layers.

  16. Extremely High Thermal Conductivity of Aligned Carbon Nanotube-Polyethylene Composites

    PubMed Central

    Liao, Quanwen; Liu, Zhichun; Liu, Wei; Deng, Chengcheng; Yang, Nuo

    2015-01-01

    The ultra-low thermal conductivity of bulk polymers may be enhanced by combining them with high thermal conductivity materials such as carbon nanotubes. Different from random doping, we find that the aligned carbon nanotube-polyethylene composites has a high thermal conductivity by non-equilibrium molecular dynamics simulations. The analyses indicate that the aligned composite not only take advantage of the high thermal conduction of carbon nanotubes, but enhance thermal conduction of polyethylene chains. PMID:26552843

  17. Extremely High Thermal Conductivity of Aligned Carbon Nanotube-Polyethylene Composites

    NASA Astrophysics Data System (ADS)

    Liao, Quanwen; Liu, Zhichun; Liu, Wei; Deng, Chengcheng; Yang, Nuo

    2015-11-01

    The ultra-low thermal conductivity of bulk polymers may be enhanced by combining them with high thermal conductivity materials such as carbon nanotubes. Different from random doping, we find that the aligned carbon nanotube-polyethylene composites has a high thermal conductivity by non-equilibrium molecular dynamics simulations. The analyses indicate that the aligned composite not only take advantage of the high thermal conduction of carbon nanotubes, but enhance thermal conduction of polyethylene chains.

  18. Innovative Instrumentation and Analysis of the Temperature Measurement for High Temperature Gasification

    SciTech Connect

    Seong W. Lee

    2005-10-01

    The objectives of this project during this semi-annual reporting period are to test the effects of coating layer of the thermal couple on the temperature measurement and to screen out the significant factors affecting the temperature reading under different operational conditions. The systematic tests of the gasifier simulator on the high velocity oxygen fuel (HVOF) spray coated thermal couples were completed in this reporting period. The comparison tests of coated and uncoated thermal couples were conducted under various operational conditions. The temperature changes were recorded and the temperature differences were calculated to describe the thermal spray coating effect on the thermal couples. To record the temperature data accurately, the computerized data acquisition system (DAS) was adopted to the temperature reading. The DAS could record the data with the accuracy of 0.1 C and the recording parameters are configurable. In these experiments, DAS was set as reading one data for every one (1) minute. The operational conditions are the combination of three parameters: air flow rate, water/ammonia flow rate and the amount of fine dust particles. The results from the temperature readings show the temperature of uncoated thermal couple is uniformly higher than that of coated thermal couple for each operational condition. Analysis of Variances (ANOVA) was computed based on the results from systematic tests to screen out the significant factors and/or interactions. The temperature difference was used as dependent variable and three operational parameters (i.e. air flow rate, water/ammonia flow rate and amount of fine dust particle) were used as independent factors. The ANOVA results show that the operational parameters are not the statistically significant factors affecting the temperature readings which indicate that the coated thermal couple could be applied to temperature measurement in gasifier. The actual temperature reading with the coated thermal couple in

  19. MAGI-L: A Space-Based High-Performance Thermal Infrared Imaging Spectrometer

    NASA Astrophysics Data System (ADS)

    Hall, J. L.; Hackwell, J. A.; Tratt, D. M.; Warren, D. W.; Young, S. J.

    2009-12-01

    An innovative multi-channel, thermal-band imager is proposed for space-based Earth science measurement applications. The low-earth-orbit instrument, MAGI-L (Mineral and Gas Identifier - LEO), would use 28 spectral bands between 7 and 12 microns to both exceed the capabilities of existing spaceborne thermal IR imagers and to enable additional applications, such as detection of gases from natural and anthropogenic sources. The higher spectral resolution, compared to ASTER-type (5 band) sensors, will improve discrimination of rock types, greatly expand the gas-detection capability, and result in more accurate land-surface temperature retrieval (important in evapotranspiration and drought studies) by enabling in-scene atmospheric compensation methods. The smaller pixel size and improved temperature sensitivity of MAGI-L will enable smaller thermal changes to be tracked and weaker gas-emission sources to be monitored, both of which will aid in emission inventory characterization of volcanoes and large industrial complexes, for example. The inclusion of spectral channels near 7 microns will permit better detection of contaminating cirrus clouds at night, when visible sensors are compromised, and will provide a second sulfur dioxide detection channel. To maximize swath width, MAGI-L will use a whiskbroom scanner. The optical design for MAGI-L will incorporate a novel Dyson spectrometer mated to a high-frame-rate 2-D HgCdTe focal plane array. The compact Dyson spectrometer design permits operation at low f-numbers while maintaining very low optical distortions. Data from our airborne SEBASS thermal IR sensor have been used to examine the trade-offs between spectral resolution, spectral range, and instrument sensitivity for the proposed MAGI-L sensor. These studies are being used to guide the design and construction of an airborne demonstrator sensor, MAGI, which is being funded by NASA’s Instrument Incubator Program.

  20. High-strength, thermally-stable nanostructured materials

    NASA Astrophysics Data System (ADS)

    Shankar, Ravi

    The properties of two technologically important precipitation-treatable alloys - Al 6061 and Inconel 718, that are deformed to large plastic strains at room temperature by machining, are presented. The strong effect of prior density of precipitates on the consequent microstructure refinement during chip formation was determined by deforming Al 6061 of different tempers to varying levels of strain, by varying the tool rake angle. Chips cut from peak-aged 6061, consisting of a fine dispersion of precipitates, produced the finest microstructure and are composed of sub-100 nm grains. On the other hand, coarser precipitate distributions in over-aged 6061 and an absence of precipitates in solution-treated 6061 resulted in much coarser microstructures. Thermal stability of such nanostructured chips with different levels of strain and precipitate distributions is analyzed by studying evolution of Vickers micro-hardness and microstructure after different heat treatments. Chips produced from the peak-aged temper and over-aged temper soften following heat treatment while those from the solution-treated state first, gain strength before softening. The results are rationalized based on prior studies of the characteristics and kinetics of precipitation and coarsening in Al-Mg-Si systems. It is then demonstrated that precipitate-stabilized nanostructured materials synthesized from a prototypical alloy system - Inconel 718, are extremely stable even after prolonged heat treatment for 240 hours at temperatures as high as one-half of the melting point. This extraordinary thermal stability is traced to the retention of a fine dispersion of precipitates in a nanostructured matrix even after extended heat treatment. It is anticipated that general design principles garnered from understanding of the causal phenomena determining strengthening and thermal stability, can lead to the development of alloy systems for the manufacture of high-strength, thermally-stable nanostructured materials.

  1. Low Thermal Conductivity, High Durability Thermal Barrier Coatings for IGCC Environments

    SciTech Connect

    Jordan, Eric; Gell, Maurice

    2015-01-15

    Advanced thermal barrier coatings (TBC) are crucial to improved energy efficiency in next generation gas turbine engines. The use of traditional topcoat materials, e.g. yttria-stabilized zirconia (YSZ), is limited at elevated temperatures due to (1) the accelerated undesirable phase transformations and (2) corrosive attacks by calcium-magnesium-aluminum-silicate (CMAS) deposits and moisture. The first goal of this project is to use the Solution Precursor Plasma Spray (SPPS) process to further reduce the thermal conductivity of YSZ TBCs by introducing a unique microstructural feature of layered porosity, called inter-pass boundaries (IPBs). Extensive process optimization accompanied with hundreds of spray trials as well as associated SEM cross-section and laser-flash measurements, yielded a thermal conductivity as low as 0.62 Wm⁻¹K⁻¹ in SPPS YSZ TBCs, approximately 50% reduction of APS TBCs; while other engine critical properties, such as cyclic durability, erosion resistance and sintering resistance, were characterized to be equivalent or better than APS baselines. In addition, modifications were introduced to SPPS TBCs so as to enhance their resistance to CMAS under harsh IGCC environments. Several mitigation approaches were explored, including doping the coatings with Al₂O₃ and TiO₂, applying a CMAS infiltration-inhibiting surface layer, and filling topcoat cracks with blocking substances. The efficacy of all these modifications was assessed with a set of novel CMAS-TBC interaction tests, and the moisture resistance was tested in a custom-built high-temperature moisture rig. In the end, the optimal low thermal conductivity TBC system was selected based on all evaluation tests and its processing conditions were documented. The optimal coating consisted on a thick inner layer of YSZ coating made by the SPPS process having a thermal conductivity 50% lower than standard YSZ coatings topped with a high temperature tolerant CMAS resistant gadolinium

  2. Equilibrium statistical-thermal models in high-energy physics

    NASA Astrophysics Data System (ADS)

    Tawfik, Abdel Nasser

    2014-05-01

    We review some recent highlights from the applications of statistical-thermal models to different experimental measurements and lattice QCD thermodynamics that have been made during the last decade. We start with a short review of the historical milestones on the path of constructing statistical-thermal models for heavy-ion physics. We discovered that Heinz Koppe formulated in 1948, an almost complete recipe for the statistical-thermal models. In 1950, Enrico Fermi generalized this statistical approach, in which he started with a general cross-section formula and inserted into it, the simplifying assumptions about the matrix element of the interaction process that likely reflects many features of the high-energy reactions dominated by density in the phase space of final states. In 1964, Hagedorn systematically analyzed the high-energy phenomena using all tools of statistical physics and introduced the concept of limiting temperature based on the statistical bootstrap model. It turns to be quite often that many-particle systems can be studied with the help of statistical-thermal methods. The analysis of yield multiplicities in high-energy collisions gives an overwhelming evidence for the chemical equilibrium in the final state. The strange particles might be an exception, as they are suppressed at lower beam energies. However, their relative yields fulfill statistical equilibrium, as well. We review the equilibrium statistical-thermal models for particle production, fluctuations and collective flow in heavy-ion experiments. We also review their reproduction of the lattice QCD thermodynamics at vanishing and finite chemical potential. During the last decade, five conditions have been suggested to describe the universal behavior of the chemical freeze-out parameters. The higher order moments of multiplicity have been discussed. They offer deep insights about particle production and to critical fluctuations. Therefore, we use them to describe the freeze-out parameters

  3. Thermal Control Method for High-Current Wire Bundles by Injecting a Thermally Conductive Filler

    NASA Technical Reports Server (NTRS)

    Rodriguez-Ruiz, Juan; Rowles, Russell; Greer, Greg

    2011-01-01

    A procedure was developed to inject thermal filler material (a paste-like substance) inside the power wire bundle coming from solar arrays. This substance fills in voids between wires, which enhances the heat path and reduces wire temperature. This leads to a reduced amount of heat generated. This technique is especially helpful for current and future generation high-power spacecraft (1 kW or more), because the heat generated by the power wires is significant enough to cause unacceptable overheating to critical components that are in close contact with the bundle.

  4. Innovations at Miami practice show promise for treating high-risk Medicare patients.

    PubMed

    Tanio, Craig; Chen, Christopher

    2013-06-01

    Patients with five or more chronic conditions drive most Medicare costs. Our organization, ChenMed, developed a scalable primary care-led delivery model that focuses on this population while getting reimbursed through full-risk capitation by Medicare Advantage plans. ChenMed is a primary care-led group practice based in Florida that serves low-to-moderate-income elderly patients, largely through the Medicare Advantage program. Our model includes a number of innovations: a one-stop-shop approach for delivering multispecialty services in the community, smaller physician panel sizes of 350-450 patients that allow for intensive health coaching and preventive care, on-site physician pharmacy dispensing, a collaborative physician culture with peer review, and customized information technology. These innovations have improved patient medication adherence, increased the time doctors and patients spend together, and led to high rates of patient satisfaction. Additionally, our Medicare patients have substantially lower rates of hospital use than their peers in the Miami Medicare market. Creating chronic disease centers focused on seniors with multiple chronic conditions is a promising delivery system innovation with major potential to improve the cost and quality of care. PMID:23733982

  5. A new high speed thermal imaging concept based on a logarithmic CMOS imager technology

    NASA Astrophysics Data System (ADS)

    Hutter, Franz X.; Brosch, Daniel; Burghartz, Joachim N.; Graf, Heinz-Gerd; Strobel, Markus

    2008-04-01

    HDRC (high dynamic range CMOS) allows for more than 120 dB signal range in image processing. Scene details with both very high and extremely low radiant flux may thus appear within the same image. Color constancy over the entire signal range and good high speed performance are further aspects of this logarithmic imager technology. These features qualify HDRC cameras for thermography, since the signal range of Planck's temperature radiation in a two dimensional array is comparable to HDRC's intensity range. Especially in material welding and laser cutting processes, in high power light sources and in high temperature material processing, fast monitoring of the spacial and dynamic temperature distributions present a challenge to conventional thermal imaging and thus call for innovative concepts. A particular challenge is in the compensation of the emissivity of the radiating surface. Here, we present a new concept based on a modified HDRC VGA color camera, allowing for visualization and measurement of temperatures from about 800 °C up to 2300 °C. The modifications include an optical filter for minimizing UV and IR straylight and a notch filter for clipping off the green optical range in order to separate the blue and red RGB regions. An enhanced and adapted software provides a division of the neighboured red and blue pixel signals by means of simply subtracting the HDRC signals. As a result the local temperature information of the visualized scene spot is independent of emissivity. This is, to our knowledge, the first demonstration of a high speed thermal imager to date.

  6. Thermal Conductance Engineering for High-Speed TES Microcalorimeters

    NASA Astrophysics Data System (ADS)

    Hays-Wehle, J. P.; Schmidt, D. R.; Ullom, J. N.; Swetz, D. S.

    2016-07-01

    Many current and future applications for superconducting transition-edge sensor (TES) microcalorimeters require significantly faster pulse response than is currently available. X-ray spectroscopy experiments at next-generation synchrotron light sources need to successfully capture very large fluxes of photons, while detectors at free-electron laser facilities need pulse response fast enough to match repetition rates of the source. Additionally, neutrino endpoint experiments such as HOLMES need enormous statistics, yet are extremely sensitive to pile-up effects that can distort spectra. These issues can be mitigated only by fast rising and falling edges. To address these needs, we have designed high-speed TES detectors with novel geometric enhancements to increase the thermal conductance of pixels suspended on silicon nitride membranes. This paper shows that the thermal conductivity can be precisely engineered to values spanning over an order of magnitude to achieve fast thermal relaxation times tailored to the relevant applications. Using these pixel prototypes, we demonstrate decay time constants faster than 100 μ s, while still maintaining spectral resolution of 3 eV FWHM at 1.5 keV. This paper also discusses the trade-offs inherent in reducing the pixel time constant, such as increased bias current leading to degradation in energy resolution, and potential modifications to improve performance.

  7. Thermal Conductance Engineering for High-Speed TES Microcalorimeters

    NASA Astrophysics Data System (ADS)

    Hays-Wehle, J. P.; Schmidt, D. R.; Ullom, J. N.; Swetz, D. S.

    2016-01-01

    Many current and future applications for superconducting transition-edge sensor (TES) microcalorimeters require significantly faster pulse response than is currently available. X-ray spectroscopy experiments at next-generation synchrotron light sources need to successfully capture very large fluxes of photons, while detectors at free-electron laser facilities need pulse response fast enough to match repetition rates of the source. Additionally, neutrino endpoint experiments such as HOLMES need enormous statistics, yet are extremely sensitive to pile-up effects that can distort spectra. These issues can be mitigated only by fast rising and falling edges. To address these needs, we have designed high-speed TES detectors with novel geometric enhancements to increase the thermal conductance of pixels suspended on silicon nitride membranes. This paper shows that the thermal conductivity can be precisely engineered to values spanning over an order of magnitude to achieve fast thermal relaxation times tailored to the relevant applications. Using these pixel prototypes, we demonstrate decay time constants faster than 100 μ s, while still maintaining spectral resolution of 3 eV FWHM at 1.5 keV. This paper also discusses the trade-offs inherent in reducing the pixel time constant, such as increased bias current leading to degradation in energy resolution, and potential modifications to improve performance.

  8. High thermal power density heat transfer apparatus providing electrical isolation at high temperature using heat pipes

    NASA Technical Reports Server (NTRS)

    Morris, J. F. (Inventor)

    1985-01-01

    This invention is directed to transferring heat from an extremely high temperature source to an electrically isolated lower temperature receiver. The invention is particularly concerned with supplying thermal power to a thermionic converter from a nuclear reactor with electric isolation. Heat from a high temperature heat pipe is transferred through a vacuum or a gap filled with electrically nonconducting gas to a cooler heat pipe. If the receiver requires gratr thermal power density, geometries are used with larger heat pipe areas for transmitting and receiving energy than the area for conducting the heat to the thermionic converter. In this way the heat pipe capability for increasing thermal power densities compensates for the comparative low thermal power densities through the electrically nonconducting gap between the two heat pipes.

  9. Measurement of thermal conductivity of Bi2Te3 nanowire using high-vacuum scanning thermal wave microscopy

    NASA Astrophysics Data System (ADS)

    Park, Kyungbae; Hwang, Gwangseok; Kim, Hayeong; Kim, Jungwon; Kim, Woochul; Kim, Sungjin; Kwon, Ohmyoung

    2016-02-01

    With the increasing application of nanomaterials in the development of high-efficiency thermoelectric energy conversion materials and electronic devices, the measurement of the intrinsic thermal conductivity of nanomaterials in the form of nanowires and nanofilms has become very important. However, the current widely used methods for measuring thermal conductivity have difficulties in eliminating the influence of interfacial thermal resistance (ITR) during the measurement. In this study, by using high-vacuum scanning thermal wave microscopy (HV-STWM), we propose a quantitative method for measuring the thermal conductivity of nanomaterials. By measuring the local phase lag of high-frequency (>10 kHz) thermal waves passing through a nanomaterial in a high-vacuum environment, HV-STWM eliminates the measurement errors due to ITR and the distortion due to heat transfer through air. By using HV-STWM, we measure the thermal conductivity of a Bi2Te3 nanowire. Because HV-STWM is quantitatively accurate and its specimen preparation is easier than in the thermal bridge method, we believe that HV-STWM will be widely used for measuring the thermal properties of various types of nanomaterials.

  10. Thermal Stabilization in a High Vacuum Cryogenic Optical System

    NASA Astrophysics Data System (ADS)

    Wallace, Rosa; Cripe, Jonathan; Corbitt, Thomas

    2016-03-01

    The existing technology for gravitational wave detection is limited in part by quantum noise. In our tabletop experiments, we are attempting to lower the noise floor to the quantum limit through the use of a seismically isolated cryogenic high vacuum environment, with the intention of exploring different methods to reduce quantum noise. In the development phase of this environment, we have implemented a customized strategy of ultraviolet irradiation combined with cryogenically cooled radiation shielding to reduce the impact of water vapor and blackbody radiation on the thermal stability of the cryogenic micro-components. Supported by National Science Foundation REU Site #1262890 and CAREER Award #1150531.

  11. Miniaturized high-performance starring thermal imaging system

    NASA Astrophysics Data System (ADS)

    Cabanski, Wolfgang A.; Breiter, Rainer; Mauk, Karl-Heinz; Rode, Werner; Ziegler, Johann; Ennenga, L.; Lipinski, Ulrich M.; Wehrhahn, T.

    2000-07-01

    A high resolution thermal imaging system was developed based on a 384 X 288 mercury cadmium telluride (MCT) mid wave (MWIR) infrared (IR) detection module with a 2 X 2 microscan for improved geometrical resolution. Primary design goal was a long identification range of 3 km and high system performance for adverse weather conditions achieved by a system with small entrance pupil and minimized dimensions to fit for integration in existing apertures of armored vehicles, reconnaissance systems and stabilized platforms. A staring FPA module with its potential for long integration times together with a microscan for improved geometrical resolution provides the answers best fit to these requirements. A robust microscanner was developed to fit for military requirements and integrated with AIM's 384 X 288 MCT MWIR module and data processing. The modules allow for up to 2 ms integration time with 25 Hz frame rate and output a 768 X 576 high resolution CCIR standard image. The video image processing (VIP) provides the calculation power for scene based self learning nonuniformity correction (NUC) algorithms to save calibration sources. This NUC algorithm allows take into account non linear effects for unsurpassed performance in highly dynamic scenes. The detection module and VIP are designed to interface with STN's mature system electronics, used e.g. in hundreds of OPHELIOS thermal camera sets fielded. The system electronics provides a lot of different interface features like double serial control bus (CANBUS) interface, analog and digital outputs as well as different video outputs. The integrated graphic generation part allows to put advanced graphic overlays to the thermal image and also to external video signals via the video input feature. This electronics provides the power supply for the whole thermal imaging system as well as different processor controlled algorithms for field of view or zoom drives, focus drives, athermalization and temperature control of the FLIR. A

  12. Process of making cryogenically cooled high thermal performance crystal optics

    SciTech Connect

    Kuzay, T.M.

    1990-06-29

    A method for constructing a cooled optic wherein one or more cavities are milled, drilled or formed using casting or ultrasound laser machining techniques in a single crystal base and filled with porous material having high thermal conductivity at cryogenic temperatures. A non-machined strain-free single crystal can be bonded to the base to produce superior optics. During operation of the cooled optic, N{sub 2} is pumped through the porous material at a sub-cooled cryogenic inlet temperature and with sufficient system pressure to prevent the fluid bulk temperature from reaching saturation.

  13. Process of making cryogenically cooled high thermal performance crystal optics

    DOEpatents

    Kuzay, T.M.

    1992-06-23

    A method is disclosed for constructing a cooled optic wherein one or more cavities are milled, drilled or formed using casting or ultrasound laser machining techniques in a single crystal base and filled with porous material having high thermal conductivity at cryogenic temperatures. A non-machined strain-free single crystal can be bonded to the base to produce superior optics. During operation of the cooled optic, N[sub 2] is pumped through the porous material at a sub-cooled cryogenic inlet temperature and with sufficient system pressure to prevent the fluid bulk temperature from reaching saturation. 7 figs.

  14. Process of making cryogenically cooled high thermal performance crystal optics

    DOEpatents

    Kuzay, Tuncer M.

    1992-01-01

    A method for constructing a cooled optic wherein one or more cavities are milled, drilled or formed using casting or ultrasound laser machining techniques in a single crystal base and filled with porous material having high thermal conductivity at cryogenic temperatures. A non-machined strain-free single crystal can be bonded to the base to produce superior optics. During operation of the cooled optic, N.sub.2 is pumped through the porous material at a sub-cooled cryogenic inlet temperature and with sufficient system pressure to prevent the fluid bulk temperature from reaching saturation.

  15. Fiber Bragg Gratings for High-Temperature Thermal Characterization

    SciTech Connect

    Stinson-Bagby, Kelly L.; Fielder, Robert S.

    2004-07-01

    Fiber Bragg grating (FBG) sensors were used as a characterization tool to study the SAFE-100 thermal simulator at the Nasa Marshal Space Flight Center. The motivation for this work was to support Nasa space nuclear power initiatives through the development of advanced fiber optic sensors for space-based nuclear power applications. Distributed high temperature measurements, up to 1150 deg. C, were made with FBG temperature sensors. Additionally, FBG strain measurements were taken at elevated temperatures to provide a strain profile of the core during operation. This paper will discuss the contribution of these measurements to meet the goals of Nasa Marshall Space Flight Center's Propulsion Research Center. (authors)

  16. Process gases for high velocity oxy-fuel thermal spraying

    SciTech Connect

    Creffield, G.K.; Chapman, I.F.; Cole, M.A.; Page, W.J.; McDonough, T.

    1994-12-31

    The importance of fuel and other process gases for high velocity oxy-fuel (HVOF) thermal spraying and especially the delivery of them to the point of use is well recognized. Problems associated with the supply of liquid fuel gases, at the high flow rates and pressures required by this process, have been addressed. Considerable development work has gone into designing an appropriate liquid withdrawal and vaporizer system for propylene, which overcomes these previous difficulties and enables users to maintain adequate fuel gas flow rates in order to ensure optimum operating conditions for the production of high quality coatings. A feature of the thermal spray process is that the temperature of the workpiece is kept low, typically below 150 C, in order to reduce residual stresses in the coating and to protect heat sensitive substrates. Traditionally this has been by compressed air, however, improved cooling has been achieved using carbon dioxide. Specially designed equipment is now available which provides and directs a cold mixture of carbon dioxide gas and solid particles (snow) via suitable nozzles, on the workpiece. The position of the cooling stream can be varied, depending on the application. These developments emphasize the importance now attached to providing dedicated gas installation packages for HVOF.

  17. High sensitivity of positron annihilation to thermal oxidation of polyethylene

    NASA Astrophysics Data System (ADS)

    Ito, Kenji; Kobayashi, Yoshinori; Nanasawa, Atsushi

    2003-01-01

    We demonstrate the high sensitivity of positron annihilation to compositional changes related to the thermal degradation of polyethylene (PE). Positron annihilation γ-ray and lifetime measurements were conducted for PE films with and without antioxidant (1000-ppm Ciba® IRGANOX® 1076), subjected to heat treatment at 100 °C for different periods, to a maximum of 30 days. For the film without antioxidant, the positron Doppler parameter (S) and ortho-positronium formation probability (Io-Ps) appreciably decreased with increased heat treatment times, whereas they barely changed for the film with antioxidant. This, together with the Fourier transform infrared measurements, demonstrated that the variations of S and Io-Ps are caused by the thermal oxidation of PE. The S parameter was found to be sensitive to the early stage of degradation, where the carbonyl concentration is inferred to be lower than 100 ppm. The high sensitivity results from the large positron mobility in PE and from the high positron affinity of oxygen-containing polar groups. This work provides the basis for an application of positron annihilation to sensitive detection of the initial degradation of PE and other nonpolar polymers.

  18. Application of thermal spray coatings using high deposition rate equipment

    SciTech Connect

    Novak, H.L.

    1995-12-01

    Reusable launch vehicles located by the ocean are subject to harsh seacoast environments before launch and immersion after splashdown at sea and towback to the refurbishment facility. High strength aluminum and non-corrosion resistant steel alloys are prone to general corrosion and pitting due to galvanic couples and protective coating damage. Additional protection of structural materials with thermally sprayed pure aluminum coatings was evaluated for plasma, arc spray and high velocity oxy-fuel (HVOF) processes. Comparisons are made for corrosion rates of various coated aluminum alloy and steel substrates when exposed to ASTM B-117 neutral salt fog testing and also to beach exposure tests performed at Kennedy Space Center, Florida. Recent development work involved the use of high deposition rate thermal arc-spray equipment. The use of an inverter power supply reduced powdering and enhanced operator visibility. Deposition rates of 45.36--68.04 kilograms/hour are obtainable using 4.76--6.35 millimeter diameter wire electrodes.

  19. Certification challenges in the development of an innovative high payload capacity spent fuel transportation cask

    SciTech Connect

    Mair, B.R.; Severson, M.J.; Ciez, A.P. )

    1990-01-01

    The design approach and certification strategy used in the development of an innovative transportation cask for legal weight truck shipments of spent nuclear fuel is presented. The proposed approach represents a significant departure from conventional cask designs in that it uses titanium alloy, a material with a high strength-to-weight ratio which has no precedent in transportation cask certification. The significant increase in payload obtainable with the proposed approach, and the associated benefits such as reduced life cycle costs, lower personnel exposure, and lower transportation accident risks are discussed. 8 refs., 3 figs., 1 tab.

  20. Microradarnet: AN Innovative High-Resolution Low-Cost X-Band Weather Radar Network

    NASA Astrophysics Data System (ADS)

    Turso, S.; Zambotto, M.; Gabella, M.; Orione, F.; Notarpietro, R.; Perona, G.

    2009-09-01

    In this paper, an innovative micro radar network for meteorological purposes has been presented. The key aspects of this network, named MicroRadarNet (MRN), are a short range strategy (about thirty kilometers) and the implementation of effective enhancing techniques. High resolution spatial and temporal data is processed in real-time, yielding a synthetic and consistent evaluation of the information coming from the sensor network. This approach implies in turn a sensible reduction of the overall operational costs, including management and maintenance aspects, if compared to the traditional long range C-band approach.

  1. Innovative use of controlled availability fertilizers with high performance for intensive agriculture and environmental conservation.

    PubMed

    Shoji, Sadao

    2005-12-01

    A variety of slow release fertilizers, controlled release (availability) fertilizers (CAFs), and stability fertilizers have been developed in response to the serious drawbacks of the conventional fertilizers since the early 1960's. Of these fertilizers, CAFs which are coated with resin are consumed in the largest quantity in the world. Selecting CAFs with higher performance, the author will discuss about: 1) Innovation of agro-technologies for various field crops including new concepts of fertilizer application, 2) high yielding of field crops, 3) enhancing quality and safety of farm products, and 4) controlling the adverse effect of intensive agriculture on the environment. PMID:16512212

  2. Innovative use of controlled availability fertilizers with high performance for intensive agriculture and environmental conservation.

    PubMed

    Shoji, Sadao

    2005-09-01

    A variety of slow release fertilizers, controlled release (availability) fertilizers (CAFs), and stability fertilizers have been developed in response to the serious drawbacks of the conventional fertilizers since the early 1960's. Of these fertilizers, CAFs which are coated with resin are consumed in the largest quantity in the world. Selecting CAFs with higher performance, the author will discuss about: 1) Innovation of agro-technologies for various field crops including new concepts of fertilizer application, 2) high yielding of field crops, 3) enhancing quality and safety of farm products, and 4) controlling the adverse effect of intensive agriculture on the environment. PMID:20549445

  3. Cooling history of Earth's core with high thermal conductivity

    NASA Astrophysics Data System (ADS)

    Davies, Christopher J.

    2015-10-01

    Thermal evolution models of Earth's core constrain the power available to the geodynamo process that generates the geomagnetic field, the evolution of the solid inner core and the thermal history of the overlying mantle. Recent upward revision of the thermal conductivity of liquid iron mixtures by a factor of 2-3 has drastically reduced the estimated power available to generate the present-day geomagnetic field. Moreover, this high conductivity increases the amount of heat that is conducted out of the core down the adiabatic gradient, bringing it into line with the highest estimates of present-day core-mantle boundary heat flow. These issues raise problems with the standard scenario of core cooling in which the core has remained completely well-mixed and relatively cool for the past 3.5 Ga. This paper presents cooling histories for Earth's core spanning the last 3.5 Ga to constrain the thermodynamic conditions corresponding to marginal dynamo evolution, i.e. where the ohmic dissipation remains just positive over time. The radial variation of core properties is represented by polynomials, which gives good agreement with radial profiles derived from seismological and mineralogical data and allows the governing energy and entropy equations to be solved analytically. Time-dependent evolution of liquid and solid light element concentrations, the melting curve, and gravitational energy are calculated for an Fe-O-S-Si model of core chemistry. A suite of cooling histories are presented by varying the inner core boundary density jump, thermal conductivity and amount of radiogenic heat production in the core. All models where the core remains superadiabatic predict an inner core age of ≲ 600Myr , about two times younger than estimates based on old (lower) thermal conductivity estimates, and core temperatures that exceed present estimates of the lower mantle solidus prior to the last 0.5-1.5 Ga. Allowing the top of the core to become strongly subadiabatic in recent times

  4. Thermal management in high average power pulsed compression systems

    SciTech Connect

    Wavrik, R.W.; Reed, K.W.; Harjes, H.C.; Weber, G.J.; Butler, M.; Penn, K.J.; Neau, E.L.

    1992-08-01

    High average power repetitively pulsed compression systems offer a potential source of electron beams which may be applied to sterilization of wastes, treatment of food products, and other environmental and consumer applications. At Sandia National Laboratory, the Repetitive High Energy Pulsed Power (RHEPP) program is developing a 7 stage magnetic pulse compressor driving a linear induction voltage adder with an electron beam diode load. The RHEPP machine is being design to deliver 350 kW of average power to the diode in 60 ns FWHM, 2.5 MV, 3 kJ pulses at a repetition rate of 120 Hz. In addition to the electrical design considerations, the repetition rate requires thermal management of the electrical losses. Steady state temperatures must be kept below the material degradation temperatures to maximize reliability and component life. The optimum design is a trade off between thermal management, maximizing overall electrical performance of the system, reliability, and cost effectiveness. Cooling requirements and configurations were developed for each of the subsystems of RHEPP. Finite element models that combine fluid flow and heat transfer were used to screen design concepts. The analysis includes one, two, and three dimensional heat transfer using surface heat transfer coefficients and boundary layer models. Experiments were conducted to verify the models as well as to evaluate cooling channel fabrication materials and techniques in Metglas wound cores. 10 refs.

  5. Thermal management in high average power pulsed compression systems

    SciTech Connect

    Wavrik, R.W.; Reed, K.W.; Harjes, H.C.; Weber, G.J.; Butler, M.; Penn, K.J.; Neau, E.L.

    1992-01-01

    High average power repetitively pulsed compression systems offer a potential source of electron beams which may be applied to sterilization of wastes, treatment of food products, and other environmental and consumer applications. At Sandia National Laboratory, the Repetitive High Energy Pulsed Power (RHEPP) program is developing a 7 stage magnetic pulse compressor driving a linear induction voltage adder with an electron beam diode load. The RHEPP machine is being design to deliver 350 kW of average power to the diode in 60 ns FWHM, 2.5 MV, 3 kJ pulses at a repetition rate of 120 Hz. In addition to the electrical design considerations, the repetition rate requires thermal management of the electrical losses. Steady state temperatures must be kept below the material degradation temperatures to maximize reliability and component life. The optimum design is a trade off between thermal management, maximizing overall electrical performance of the system, reliability, and cost effectiveness. Cooling requirements and configurations were developed for each of the subsystems of RHEPP. Finite element models that combine fluid flow and heat transfer were used to screen design concepts. The analysis includes one, two, and three dimensional heat transfer using surface heat transfer coefficients and boundary layer models. Experiments were conducted to verify the models as well as to evaluate cooling channel fabrication materials and techniques in Metglas wound cores. 10 refs.

  6. Thermal design studies of high-power heterojunction bipolar transistors

    NASA Astrophysics Data System (ADS)

    Gao, Guang-Bo; Wang, Ming-Zhu; Gui, Xiang; Morkoc, Hadis

    1989-05-01

    A theoretical thermoelectro-feedback model has been developed for the thermal design of high-power GaAlAs/GaAs heterojunction bipolar transistors (HBTs). The power-handling capability, thermal instability, junction temperature, and current distributions of HBTs with multiple emitter fingers have been numerically studied. The calculated results indicate that power HBTs on Si substrates (or with Si as the collector) have excellent potential power performance and reliability. The power-handling capability on Si is 3.5 and 2.7 times as large as that on GaAs and InP substrates, respectively. The peak junction temperature and temperature difference on the chip decrease in comparison to the commonly used Si homostructure power transistors with the same geometry and power dissipation. Thereby HBTs are promising for high-speed microwave and millimeter-wave applications. It has been also found that the nonuniform distribution of junction temperature and current can be greatly improved by a balasting technique that uses unequal-value emitter resistors.

  7. Corrections for Thermal Expansion in Thermal Conductivity Measurement of Insulations Using the High-Temperature Guarded Hot-Plate Method

    NASA Astrophysics Data System (ADS)

    Wu, Jiyu; Morrell, Roger

    2012-02-01

    The anticipation of recently published European product standards for industrial thermal insulation has driven improvements in high-temperature thermal conductivity measurements in an attempt to obtain overall measurement uncertainties better than 5 % ( k = 2). The two measurement issues that are focused on in this article are the effect of thermal expansion on in situ thickness measurement and on determining the metering area at high temperatures. When implementing in situ thickness measurements, it is vital to correct the thermal expansion of components in a high-temperature guarded hot plate (HTGHP). For example, in the NPL HTGHP this could cause 3.2 % measurement error for a 50 mm thick specimen at 800 °C. The thermal expansion data for nickel 201 measured by NPL are presented, and the effect of this on the metering area of NPL's heater plate (nickel 201) is discussed.

  8. Highly efficient blue electroluminescence based on thermally activated delayed fluorescence.

    PubMed

    Hirata, Shuzo; Sakai, Yumi; Masui, Kensuke; Tanaka, Hiroyuki; Lee, Sae Youn; Nomura, Hiroko; Nakamura, Nozomi; Yasumatsu, Mao; Nakanotani, Hajime; Zhang, Qisheng; Shizu, Katsuyuki; Miyazaki, Hiroshi; Adachi, Chihaya

    2015-03-01

    Organic compounds that exhibit highly efficient, stable blue emission are required to realize inexpensive organic light-emitting diodes for future displays and lighting applications. Here, we define the design rules for increasing the electroluminescence efficiency of blue-emitting organic molecules that exhibit thermally activated delayed fluorescence. We show that a large delocalization of the highest occupied molecular orbital and lowest unoccupied molecular orbital in these charge-transfer compounds enhances the rate of radiative decay considerably by inducing a large oscillator strength even when there is a small overlap between the two wavefunctions. A compound based on our design principles exhibited a high rate of fluorescence decay and efficient up-conversion of triplet excitons into singlet excited states, leading to both photoluminescence and internal electroluminescence quantum yields of nearly 100%. PMID:25485987

  9. Highly efficient blue electroluminescence based on thermally activated delayed fluorescence

    NASA Astrophysics Data System (ADS)

    Hirata, Shuzo; Sakai, Yumi; Masui, Kensuke; Tanaka, Hiroyuki; Lee, Sae Youn; Nomura, Hiroko; Nakamura, Nozomi; Yasumatsu, Mao; Nakanotani, Hajime; Zhang, Qisheng; Shizu, Katsuyuki; Miyazaki, Hiroshi; Adachi, Chihaya

    2015-03-01

    Organic compounds that exhibit highly efficient, stable blue emission are required to realize inexpensive organic light-emitting diodes for future displays and lighting applications. Here, we define the design rules for increasing the electroluminescence efficiency of blue-emitting organic molecules that exhibit thermally activated delayed fluorescence. We show that a large delocalization of the highest occupied molecular orbital and lowest unoccupied molecular orbital in these charge-transfer compounds enhances the rate of radiative decay considerably by inducing a large oscillator strength even when there is a small overlap between the two wavefunctions. A compound based on our design principles exhibited a high rate of fluorescence decay and efficient up-conversion of triplet excitons into singlet excited states, leading to both photoluminescence and internal electroluminescence quantum yields of nearly 100%.

  10. High accuracy thermal conductivity measurement of aqueous cryoprotective agents and semi-rigid biological tissues using a microfabricated thermal sensor

    PubMed Central

    Liang, Xin M.; Sekar, Praveen K.; Zhao, Gang; Zhou, Xiaoming; Shu, Zhiquan; Huang, Zhongping; Ding, Weiping; Zhang, Qingchuan; Gao, Dayong

    2015-01-01

    An improved thermal-needle approach for accurate and fast measurement of thermal conductivity of aqueous and soft biomaterials was developed using microfabricated thermal conductivity sensors. This microscopic measuring device was comprehensively characterized at temperatures from 0 °C to 40 °C. Despite the previous belief, system calibration constant was observed to be highly temperature-dependent. Dynamic thermal conductivity response during cooling (40 °C to –40 °C) was observed using the miniaturized single tip sensor for various concentrations of CPAs, i.e., glycerol, ethylene glycol and dimethyl sulfoxide. Chicken breast, chicken skin, porcine limb, and bovine liver were assayed to investigate the effect of anatomical heterogeneity on thermal conductivity using the arrayed multi-tip sensor at 20 °C. Experimental results revealed distinctive differences in localized thermal conductivity, which suggests the use of approximated or constant property values is expected to bring about results with largely inflated uncertainties when investigating bio-heat transfer mechanisms and/or performing sophisticated thermal modeling with complex biological tissues. Overall, the presented micro thermal sensor with automated data analysis algorithm is a promising approach for direct thermal conductivity measurement of aqueous solutions and soft biomaterials and is of great value to cryopreservation of tissues, hyperthermia or cryogenic, and other thermal-based clinical diagnostics and treatments. PMID:25993037

  11. High accuracy thermal conductivity measurement of aqueous cryoprotective agents and semi-rigid biological tissues using a microfabricated thermal sensor

    NASA Astrophysics Data System (ADS)

    Liang, Xin M.; Sekar, Praveen K.; Zhao, Gang; Zhou, Xiaoming; Shu, Zhiquan; Huang, Zhongping; Ding, Weiping; Zhang, Qingchuan; Gao, Dayong

    2015-05-01

    An improved thermal-needle approach for accurate and fast measurement of thermal conductivity of aqueous and soft biomaterials was developed using microfabricated thermal conductivity sensors. This microscopic measuring device was comprehensively characterized at temperatures from 0 °C to 40 °C. Despite the previous belief, system calibration constant was observed to be highly temperature-dependent. Dynamic thermal conductivity response during cooling (40 °C to -40 °C) was observed using the miniaturized single tip sensor for various concentrations of CPAs, i.e., glycerol, ethylene glycol and dimethyl sulfoxide. Chicken breast, chicken skin, porcine limb, and bovine liver were assayed to investigate the effect of anatomical heterogeneity on thermal conductivity using the arrayed multi-tip sensor at 20 °C. Experimental results revealed distinctive differences in localized thermal conductivity, which suggests the use of approximated or constant property values is expected to bring about results with largely inflated uncertainties when investigating bio-heat transfer mechanisms and/or performing sophisticated thermal modeling with complex biological tissues. Overall, the presented micro thermal sensor with automated data analysis algorithm is a promising approach for direct thermal conductivity measurement of aqueous solutions and soft biomaterials and is of great value to cryopreservation of tissues, hyperthermia or cryogenic, and other thermal-based clinical diagnostics and treatments.

  12. Design of a high temperature subsurface thermal energy storage system

    NASA Astrophysics Data System (ADS)

    Zheng, Qi

    Solar thermal energy is taking up increasing proportions of future power generation worldwide. Thermal energy storage technology is a key method for compensating for the inherent intermittency of solar resources and solving the time mismatch between solar energy supply and electricity demand. However, there is currently no cost-effective high-capacity compact storage technology available (Bakker et al., 2008). The goal of this work is to propose a high temperature subsurface thermal energy storage (HSTES) technology and demonstrate its potential energy storage capability by developing a solar-HSTES-electricity generation system. In this work, main elements of the proposed system and their related state-of-art technologies are reviewed. A conceptual model is built to illustrate the concept, design, operating procedure and application of such a system. A numerical base model is built within the TOUGH2-EOS1 multiphase flow simulator for the evaluation of system performance. Additional models are constructed and simulations are done to identify the effect of different operational and geological influential factors on the system performance. Our work shows that when the base model is run with ten years operation of alternate injection and production processes - each for a month - with a thermal power input of 10.85 MW, about 83% of the injected thermal energy could be recovered within each working cycle from a stabilized HSTES system. After the final conversion into electrical energy, a relative (compared with the direct use of hot water) electricity generation efficiency of 73% is obtained. In a typical daily storage scenario, the simulated thermal storage efficiency could exceed 78% and the relative electricity generation efficiency is over 66% in the long run. In a seasonal storage scenario, these two efficiencies reach 69% and 53% respectively by the end of the simulation period of 10 years. Additional simulations reveal a thinner storage aquifer with a higher

  13. Thermal design and test of a high power spacecraft transponder platform

    NASA Technical Reports Server (NTRS)

    Stipandic, E. A.; Gray, A. M.; Gedeon, L.

    1975-01-01

    The high power transponder subsystem on board the Communications Technology Satellite (CTS) requires some unique thermal control techniques to maintain the required temperature limits throughout all mission phases. The transponder subsystem includes redundant 20-W output travelling wave tubes and a single 200-W output TWT with highly concentrated thermal dissipations of 70 W and 143 W, respectively. A thermal control system which maintains all components within the required temperature ranges has been designed and verified in thermal balance testing. Included in the design are second surface quartz mirrors on an aluminum honeycomb platform, high thermal conductivity aluminum doubler plates, commandable thermal control heaters and a Variable Conductance Heat Pipe System (VCHPS).

  14. High-temperature turbopump assembly for space nuclear thermal propulsion

    SciTech Connect

    Overholt, D.M. )

    1993-01-20

    The development of a practical, high-performance nuclear rocket by the U.S. Air Force Space Nuclear Thermal Propulsion (SNTP) program places high priority on maximizing specific impulse (ISP) and thrust-to-weight ratio. The operating parameters arising from these goals drive the propellant-pump design. The liquid hydrogen propellant is pressurized and pumped to the reactor inlet by the turbopump assembly (TPA). Rocket propulsion is effected by rapid heating of the propellant from 100 K to thousands of degrees in the particle-bed reactor (PBR). The exhausted propellant is then expanded through a high-temperature nozzle. One approach to achieve high performance is to use an uncooled carbon-carbon nozzle and duct turbine inlet. The high-temperature capability is obtained by using carbon-carbon throughout the TPA hot section. Carbon-carbon components in development include structural parts, turbine nozzles/stators, and turbine rotors. The technology spinoff is applicable to conventional liquid propulsion engines plus a wide variety of other turbomachinery applications.

  15. Optical Diagnostics for High-Temperature Thermal Barrier Coatings

    NASA Technical Reports Server (NTRS)

    Eldridge, Jeffrey I.

    2009-01-01

    Thermal barrier coatings (TBCs) are typically composed of translucent ceramic oxides that provide thermal protection for metallic components exposed to high-temperature environments, such as in jet turbine engines. Taking advantage of the translucent nature of TBCs, optical diagnostics have been developed that can provide an informed assessment of TBC health that will allow mitigating action to be taken before TBC degradation threatens performance or safety. In particular, rare-earth-doped luminescent sublayers have been integrated into the TBC structure to produce luminescence that monitors TBC erosion, delamination, and temperature gradients. Erosion monitoring of TBC-coated specimens is demonstrated by utilizing visible luminescence that is excited from a sublayer that is exposed by erosion. TBC delamination monitoring is achieved in TBCs with a base rare-earth-doped luminescent sublayer by the reflectance-enhanced increase in luminescence produced in regions containing buried delamination cracks. TBC temperature monitoring is demonstrated using the temperature-dependent decay time for luminescence originating from the specific coating depth associated with a rare-earth-doped luminescent sublayer. The design and implementation of these TBCs with integrated luminescent sublayers is discussed, including co-doping strategies to produce more penetrating near-infrared luminescence. It is demonstrated that integration of the rare-earth-doped sublayers is achieved with no reduction in TBC life. In addition, results for multilayer TBCs designed to also perform as radiation barriers are also presented.

  16. High-Q mid-infrared thermal emitters operating with high power-utilization efficiency.

    PubMed

    Inoue, Takuya; De Zoysa, Menaka; Asano, Takashi; Noda, Susumu

    2016-06-27

    We demonstrate a single-mode high-Q (Q>100) mid-infrared thermal emitter operating with high power-utilization efficiency. The emitter consists of a rod-type photonic crystal (PC) slab interacting with GaAs/AlGaAs multiple quantum wells (MQWs), a GaAs substrate frame supporting the PC slab, and electric wires for Joule heating of the device. We carefully design the structure of the PC slab and the supporting frame/wires to minimize unwanted thermal losses and realize narrowband thermal emission having a peak intensity, under a given electrical input power, that is an order of magnitude higher than that of a reference blackbody emitter due to the efficient increase of the device temperature. PMID:27410661

  17. An investigation of thermal comfort at high humidities

    SciTech Connect

    Fountain, M.E.; Arens, E. Xu, T.; Bauman, F.S.; Oguru, Masayuki

    1999-07-01

    Climate chamber experiments were performed to investigate thermal comfort at high humidities. Subjective reports were recorded for a total of 411 subjects at frequent intervals during the three-hour experiments with 65 selected subjects equipped with instrumentation to record skin wettedness and skin temperature. The exposures ranged from 20 C/60% RH to 26 C/90% RH with two clothing levels, 0.5 and 0.9 clo, and three levels of metabolic activity, 1.2, 1.6, and 4 met. Clear differences in humidity response were not found for sedentary subjects; however, non-sedentary activities produced differences on several subjective scales. These differences, though, are dictated via heat balance and thermoregulation and cannot be separated from humidity-related effects. For metabolic rates 1.6 met and above, these data suggest that no practical limit on humidity will lower the percent dissatisfied below 25%.

  18. Simulating the Mineral Scale by High Pressure Thermal Vessel

    NASA Astrophysics Data System (ADS)

    Huang, Y. H.; Liu, H. L.; Chen, H. F.; Song, S. R.

    2014-12-01

    The generating capacity of Chingshui geothermal power plant decreased rapidly after it had operated three years. Chinese Petroleum Corporation (CPC) attributed the main reason was the depletion of reservoir. One reason was that the reservoir did not be recharged. And the other was the mineral scale in reservoir and pipes which caused flow rate decreased. There are abundant geothermal energy in Taiwan. But in Chingshui, the spring has amount content of carbonate. Most scaling are calcium carbonate and silica. These two materials have different solubility in various pH and physical conditions. Because the pressure reduced in the process of upwelling, the hot spring from the reservoir deposited calcium carbonate immediately by large carbon dioxide escape. This result caused the diameter of pipeline reduced. Besides, as the temperature decreased, the silica would scaling in the part of heat exchanger. To avoid the failure experience in Chingshui , how to prevent the mineral scaling is the key point that we need to solve. Our study will use hydrothermal experiments by High Pressure Thermal Vessel to simulate the process of spring water upwelling from reservoir to surface, to understand whether calcium carbonate and silica scaling or not in different temperature and pressure. This study choose the Hongchailin well as objects to simulate, and the target layers of drilling well were set as Szeleng sandstone and Lushan slate. We used pure water and saturated water pressure in our experiments. There were four vessels in High thermal vessel. The first vessel was used to simulate the condition of reservoir. The second and third vessel were simulated the conditions in the well when spring water upwelling to the surface. And the last vessel was simulated the conditions on surface surroundings. We hope to get the temperature and pressure when the scaling occurred, and verified with the computing result, thus we can inhibit the scaling.

  19. High-pressure compressibility and thermal expansion of aragonite

    NASA Astrophysics Data System (ADS)

    Palaich, S.; Heffern, R. A.; Kavner, A.; Manning, C. E.; Merlini, M.; Hanfland, M.

    2015-12-01

    An important component of Earth's deep carbon cycle is the return of surficial carbon to the planet's interior. Most recycled carbon is bound in CaCO3 minerals, of which aragonite is the most significant at upper mantle pressures. It is therefore essential to understand the phase stability and compressibility of aragonite at high pressures and temperatures. Aragonite has an orthorhombic 2/m 2/m 2/m structure and a Z of 4. The high-pressure behavior of aragonite has been studied under dynamic and static compression using both X-ray diffraction and spectroscopic techniques, but these results have been contradictory and inconclusive. To address these issues, a single-crystal synchrotron X-ray diffraction study of aragonite under hydrostatic compression was performed to 40 GPa in a diamond anvil cell at ambient temperature. To supplement the compressional experiment, thermal expansion was also measured via powder X-ray diffraction at ambient pressure between 298-673 K. Ambient-pressure single-crystal measurements confirm the orthorhombic 2/m 2/m 2/m structure and yield a unit cell volume of 226.932(5) Å3. At room temperature, aragonite is stable in the orthorhombic structure to 40 GPa, with an isothermal bulk modulus of 66.5(7) GPa and K' = 5.0(1). The a-axis is most compressible and the c-axis is the least compressible. The b-axis is intermediate, but starts to decrease in compressibility at ~15 GPa. Between 25-30 GPa the aragonite unit cell distorts due to the stiffening of the b-axis, which is controlled by the orientation and distortion of the carbonate groups, layered in the aragonite structure parallel to the a-axis. The carbonate groups elongate and deform from equilateral to isosceles between 15 and 30 GPa, thus influencing the compressibility of the b-axis. The thermal expansion measurements yield expansion coefficients a0 = 4.9(2) x 10-5 and a1 =3.7(5) x 10-8, in agreement with previous data. The combination of the isothermal and isobaric studies allows the

  20. High Strength and Thermally Stable Nanostructured Magnesium Alloys and Nanocomposites

    NASA Astrophysics Data System (ADS)

    Chang, Yuan-Wei

    Magnesium and its alloys are currently in the spotlight of global research because of the need to limit energy consumption and reduce the environmental impact. In particular, their low densities compared to other structural metals make them a very attractive alternative in the automobile and aerospace industries. However, their low strength compared to other structural materials (e.g. Al and steels) has limited their widespread application. This dissertation presents the results of developing and investigation of a high strength nanostructured magnesium-aluminum alloy and composite. The nanostructured magnesium alloy is prepared by cryomilling and consolidated by spark-plasma-sintering. Focused ion beam is used to prepare micropillars with different diameters ranging from 1.5 to 8 mum and micro-compression test is conducted by nanoindenter in order to evaluate the mechanical properties. The yield strength obtained in the present study is around three times higher than conventional magnesium alloys (120 MPa vs. 370 MPa). The yield strength of the nanostructured magnesium alloy is further improved through hot extrusion, resulting in a yield strength of 550 MPa and an ultimate strength of 580 MPa. The nanostructured magnesium alloy exhibits a strong size-dependence, and a significant improvement in strength is observed when the pillar diameter is reduced to below 3.5 mum. The deformation mechanisms of the compressed pillars were characterized using transmission electron microscopy. The size-induced strengthening is attributed to a less number of dislocation sources along with a higher activity of non-basal deformation mechanisms. We have also developed a high strength and thermally stable nanostructured magnesium composite by adding diamantane. A yield strength of 500 MPa is achieved, moreover, excellent thermal stability is demonstrated in the magnesium alloy containing diamantanes. The strength and grain size are thermally stable after annealing at 400°C for 100

  1. Groundwater Management Innovations in the High Plains Aquifer, USA: A possible path towards sustainability? (Invited)

    NASA Astrophysics Data System (ADS)

    Sophocleous, M. A.

    2009-12-01

    The U.S. High Plains aquifer, one of the largest freshwater aquifer systems in the world covering parts of eight US states, continues to decline, threatening the long-term viability of the region’s irrigation-based economy. The theory of the commons has meaningful messages for High-Plains jurisdictions as no private incentive exists to save for tomorrow, and agricultural prosperity depends on mining water from large portions of the aquifer. The eight High Plains states take different approaches to the development and management of the aquifer based on each state’s body of water laws that abide by different legal doctrines, on which Federal laws are superposed, thus creating difficulties in integrated regional water management efforts. Although accumulating hydrologic stresses and competing demands on groundwater resources are making groundwater management increasingly complex, they are also leading to innovative approaches to the management of groundwater supplies, and those are highlighted in this presentation as good examples for emulation in managing groundwater resources. The highlighted innovations include (1) the Texas Groundwater Availability Modeling program, (2) Colorado’s water-augmentation program, (3) Kansas’ Intensive Groundwater Use Control Area policy, (4) the Kansas Groundwater Management Districts’ “safe yield” policies, (5) the water-use reporting program in Kansas, (6) the Aquifer Storage and Recovery program of the City of Wichita, Kansas, and (7) Nebraska’s Natural Resources Districts. It is concluded that the fragmented and piecemeal institutional arrangements for managing the supplies and quality of water are unlikely to be sufficient to meet the water challenges of the future. A number of recommendations for enhancing the sustainability of the aquifer are presented, including the formation of an interstate groundwater commission for the High Plains aquifer along the lines of the Delaware and Susquehanna River Basins

  2. High thermal conductivity of hexagonal boron nitride laminates

    NASA Astrophysics Data System (ADS)

    Zheng, Jin-Cheng; Zhang, Liang; Kretinin, A. V.; Morozov, S. V.; Wang, Yi Bo; Wang, Tun; Li, Xiaojun; Ren, Fei; Zhang, Jingyu; Lu, Ching-Yu; Chen, Jia-Cing; Lu, Miao; Wang, Hui-Qiong; Geim, A. K.; Novoselov, K. S.

    2016-03-01

    Two-dimensional materials are characterised by a number of unique physical properties which can potentially make them useful to a wide diversity of applications. In particular, the large thermal conductivity of graphene and hexagonal boron nitride (hBN) has already been acknowledged and these materials have been suggested as novel core materials for thermal management in electronics. However, it was not clear if mass produced flakes of hBN would allow one to achieve an industrially-relevant value of thermal conductivity. Here we demonstrate that laminates of hBN exhibit thermal conductivity of up to 20 W/m·K, which is significantly larger than that currently used in thermal management. We also show that the thermal conductivity of laminates increases with the increasing volumetric mass density, which creates a way of fine tuning its thermal properties.

  3. High technology in medicine: lessons from cardiovascular innovations and future perspective.

    PubMed

    Beyar, Rafael

    2013-04-01

    Four decades of innovations in the field of interventional cardiology are presented as an example for the great growth of high technology in medicine, side by side with the development of general technology and science. The field of percutaneous coronary intervention (PCI) was enabled by the development of X-ray systems, allowing us to view the pathology, and was critically dependent on courageous and imaginative physicians and scientists who developed percutaneous transluminal coronary angioplasty (PTCA), stents, and transarterial aortic valve replacement (TAVR). Today, outstanding research continues to progress, with stem cell research and IPC technologies presenting new challenges and yet taller mountains to climb. The rapid development we have witnessed was due to tight collaborations between clinical and academic institutions and industry. The combination of all these elements, with a proper mechanism to handle conflict of interest, is an essential linkage for any progress in this field. We will continue to see exponential growth of innovations and must be prepared with appropriate bodies to encourage such developments and to provide early-stage funding and support for novel ideas. PMID:23908859

  4. High Technology in Medicine: Lessons from Cardiovascular Innovations and Future Perspective

    PubMed Central

    Beyar, Rafael

    2013-01-01

    Four decades of innovations in the field of interventional cardiology are presented as an example for the great growth of high technology in medicine, side by side with the development of general technology and science. The field of percutaneous coronary intervention (PCI) was enabled by the development of X-ray systems, allowing us to view the pathology, and was critically dependent on courageous and imaginative physicians and scientists who developed percutaneous transluminal coronary angioplasty (PTCA), stents, and transarterial aortic valve replacement (TAVR). Today, outstanding research continues to progress, with stem cell research and IPC technologies presenting new challenges and yet taller mountains to climb. The rapid development we have witnessed was due to tight collaborations between clinical and academic institutions and industry. The combination of all these elements, with a proper mechanism to handle conflict of interest, is an essential linkage for any progress in this field. We will continue to see exponential growth of innovations and must be prepared with appropriate bodies to encourage such developments and to provide early-stage funding and support for novel ideas. PMID:23908859

  5. Thermal barrier coatings (TBC's) for high heat flux thrust chambers

    NASA Astrophysics Data System (ADS)

    Bradley, Christopher M.

    -section components has become critical, but at the same time the service conditions have put our best alloy systems to their limits. As a result, implementation of cooling holes and thermal barrier coatings are new advances in hot-section technologies now looked at for modifications to reach higher temperature applications. Current thermal barrier coatings used in today's turbine applications is known as 8%yttria-stabilized zirconia (YSZ) and there are no coatings for current thrust chambers. Current research is looking at the applicability of 8%yttria-stabilized hafnia (YSH) for turbine applications and the implementation of 8%YSZ onto thrust chambers. This study intends to determine if the use of thermal barrier coatings are applicable for high heat flux thrust chambers using industrial YSZ will be advantageous for improvements in efficiency, thrust and longer service life by allowing the thrust chambers to be used more than once.

  6. Performance of thermal barrier coatings in high heat flux environments

    NASA Technical Reports Server (NTRS)

    Miller, R. A.; Berndt, C. C.

    1984-01-01

    Thermal barrier coatings were exposed to the high temperature and high heat flux produced by a 30 kW plasma torch. Analysis of the specimen heating rates indicates that the temperature drop across the thickness of the 0.038 cm ceramic layer was about 1100 C after 0.5 sec in the flame. An as-sprayed ZrO2-8 percent Y203 specimens survived 3000 of the 0.5 sec cycles with failing. Surface spalling was observed when 2.5 sec cycles were employed but this was attributed to uneven heating caused by surface roughness. This surface spalling was prevented by smoothing the surface with silicon carbide paper or by laser glazing. A coated specimen with no surface modification but which was heat treated in argon also did not surface spall. Heat treatment in air led to spalling in as early as 2 cycle from heating stresses. Failures at edges were investigated and shown to be a minor source of concern. Ceramic coatings formed from ZrO2-12 percent Y2O3 or ZrO2-20 percent Y2O3 were shown to be unsuited for use under the high heat flux conditions of this study.

  7. Performance of thermal barrier coatings in high heat flux environments

    NASA Technical Reports Server (NTRS)

    Miller, R. A.; Berndt, C. C.

    1984-01-01

    Thermal barrier coatings were exposed to the high temperature and high heat flux produced by a 30 kW plasma torch. Analysis of the specimen heating rates indicates that the temperature drop across the thickness of the 0.038 cm ceramic layer was about 1100 C after 0.5 sec in the flame. An as-sprayed ZrO2-8 percent Y2O3 specimens survived 3000 of the 0.5 sec cycles with falling. Surface spalling was observed when 2.5 sec cycles were employed but this was attributed to uneven heating caused by surface roughness. This surface spalling was prevented by smoothing the surface with silicon carbide paper or by laser glazing. A coated specimen with no surface modification but which was heat treated in argon also did not surface spall. Heat treatment in air led to spalling in as early as 1 cycle from heating stresses. Failures at edges were investigated and shown to be a minor source of concern. Ceramic coatings formed from ZrO2-12 percent Y2O3 or ZrO2-2O percent Y2O3 were shown to be unsuited for use under the high heat flux conditions of this study.

  8. Performance of thermal barrier coatings in high heat flux environments

    NASA Technical Reports Server (NTRS)

    Miller, R. A.; Berndt, C. C.

    1984-01-01

    Thermal barrier coatings were exposed to the high temperature and high heat flux produced by a 30 kW plasma torch. Analysis of the specimen heating rates indicates that the temperature drop across the thickness of the 0.038 cm ceramic layer was about 1100 C after 0.5 sec in the flame. An as-sprayed ZrO2-8%Y2O3 specimens survived 3000 of the 0.5 sec cycles with failing. Surface spalling was observed when 2.5 sec cycles were employed but this was attributed to uneven heating caused by surface roughness. This surface spalling was prevented by smoothing the surface with silicon carbide paper or by laser glazing. A coated specimen with no surface modification but which was heat treated in argon also did not surface spall. Heat treatment in air led to spalling in as early as 2 cycle from heating stresses. Failures at edges were investigated and shown to be a minor source of concern. Ceramic coatings formed from ZrO2-12%Y2O3 or ZrO2-20%Y2O3 were shown to be unsuited for use under the high heat flux conditions of this study.

  9. Applications and Innovations for Use of High Definition and High Resolution Digital Motion Imagery in Space Operations

    NASA Technical Reports Server (NTRS)

    Grubbs, Rodney

    2016-01-01

    The first live High Definition Television (HDTV) from a spacecraft was in November, 2006, nearly ten years before the 2016 SpaceOps Conference. Much has changed since then. Now, live HDTV from the International Space Station (ISS) is routine. HDTV cameras stream live video views of the Earth from the exterior of the ISS every day on UStream, and HDTV has even flown around the Moon on a Japanese Space Agency spacecraft. A great deal has been learned about the operations applicability of HDTV and high resolution imagery since that first live broadcast. This paper will discuss the current state of real-time and file based HDTV and higher resolution video for space operations. A potential roadmap will be provided for further development and innovations of high-resolution digital motion imagery, including gaps in technology enablers, especially for deep space and unmanned missions. Specific topics to be covered in the paper will include: An update on radiation tolerance and performance of various camera types and sensors and ramifications on the future applicability of these types of cameras for space operations; Practical experience with downlinking very large imagery files with breaks in link coverage; Ramifications of larger camera resolutions like Ultra-High Definition, 6,000 [pixels] and 8,000 [pixels] in space applications; Enabling technologies such as the High Efficiency Video Codec, Bundle Streaming Delay Tolerant Networking, Optical Communications and Bayer Pattern Sensors and other similar innovations; Likely future operations scenarios for deep space missions with extreme latency and intermittent communications links.

  10. High-resolution and high-conductive electrode fabrication on a low thermal resistance flexible substrate

    NASA Astrophysics Data System (ADS)

    Kang, Bongchul; Kno, Jinsung; Yang, Minyang

    2011-07-01

    Processes based on the liquid-state pattern transfer, like inkjet printing, have critical limitations including low resolution and low electrical conductivity when fabricating electrodes on low thermal resistance flexible substrates such as polyethylene terephthalate (PET). Those are due to the nonlinear transfer mechanism and the limit of the sintering temperature. Although the laser direct curing (LDC) of metallic inks is an alternative process to improve the resolution, it is also associated with the disadvantages of causing thermal damage to the polymer substrate. This paper suggests the laser induced pattern adhesion transfer method to fabricate electrodes of both high electrical conductivity and high resolution on a PET substrate. First, solid patterns are cost-effectively created by the LDC of the organometallic silver ink on a glass that is optically and thermally stable. The solid patterns sintered on the glass are transferred to the PET substrate by the photo-thermally generated adhesion force of the substrate. Therefore, we achieved electrodes with a minimum line width of 10 µm and a specific resistance of 3.6 μΩcm on the PET substrate. The patterns also showed high mechanical reliability.

  11. Innovative ammonia stripping with an electrolyzed water system as pretreatment of thermally hydrolyzed wasted sludge for anaerobic digestion.

    PubMed

    Park, Seyong; Kim, Moonil

    2015-01-01

    In this study, the anaerobic digestion of thermally hydrolyzed wasted sludge (THWS) with a high concentration of ammonia was carried out through combining with an ammonia stripping and an electrolyzed water system (EWS). The EWS produced acidic water (pH 2-3) at the anode and alkaline water (pH 11-12) at the cathode with an electro-diaphragm between the electrodes that could be applied to ammonia stripping. The ammonia stripping efficiency was strongly dependent on the pH and aeration rate, and the ammonium ion removal rate followed pseudo-first-order kinetics. From the BMP test, the methane yield of THWS after ammonia stripping using the EWS was 2.8 times higher than that of the control process (raw THWS without ammonia stripping). Furthermore, both methane yield and ammonium removal efficiency were higher in this study than in previous studies. Since ammonia stripping with the EWS does not require any chemicals for pH control, no precipitated sludge is produced and anaerobic microorganisms are not inhibited by cations. Therefore, ammonia stripping using the EWS could be an effective method for digestion of wastewater with a high concentration of ammonium nitrogen. PMID:25462764

  12. Metal matrix-metal nanoparticle composites with tunable melting temperature and high thermal conductivity for phase-change thermal storage.

    PubMed

    Liu, Minglu; Ma, Yuanyu; Wu, Hsinwei; Wang, Robert Y

    2015-02-24

    Phase-change materials (PCMs) are of broad interest for thermal storage and management applications. For energy-dense storage with fast thermal charging/discharging rates, a PCM should have a suitable melting temperature, large enthalpy of fusion, and high thermal conductivity. To simultaneously accomplish these traits, we custom design nanocomposites consisting of phase-change Bi nanoparticles embedded in an Ag matrix. We precisely control nanoparticle size, shape, and volume fraction in the composite by separating the nanoparticle synthesis and nanocomposite formation steps. We demonstrate a 50-100% thermal energy density improvement relative to common organic PCMs with equivalent volume fraction. We also tune the melting temperature from 236-252 °C by varying nanoparticle diameter from 8.1-14.9 nm. Importantly, the silver matrix successfully prevents nanoparticle coalescence, and no melting changes are observed during 100 melt-freeze cycles. The nanocomposite's Ag matrix also leads to very high thermal conductivities. For example, the thermal conductivity of a composite with a 10% volume fraction of 13 nm Bi nanoparticles is 128 ± 23 W/m-K, which is several orders of magnitude higher than typical thermal storage materials. We complement these measurements with calculations using a modified effective medium approximation for nanoscale thermal transport. These calculations predict that the thermal conductivity of composites with 13 nm Bi nanoparticles varies from 142 to 47 W/m-K as the nanoparticle volume fraction changes from 10 to 35%. Larger nanoparticle diameters and/or smaller nanoparticle volume fractions lead to larger thermal conductivities. PMID:25610944

  13. Designing CNR, a very high thermal neutron flux facility

    SciTech Connect

    Difilippo, F.C.

    1986-01-01

    According to a recent study (Eastman-Seitz Committee, National Academy of Science) there is a need for a new generation of steady neutron sources with a thermal neutron flux peak between 5 to 10 times 10/sup 15//cm/sup 2/ sec. Ideally the neutron source would have to operate continuously for several days (two weeks at least) with minimum time (2 to 3 days) for refueling and/or maintenance and it would also be used to irradiate materials and produce isotopes. This paper describes the preliminary design of the nuclear reactor for the proposed Center for Neutron Research (CNR). A duplication of existing designs (HFIR, (ORNL), ILL (Grenoble, France)) would imply high total power and small core life; the necessity of higher efficiencies (in terms of peak-flux-per-unit source or power) then becomes apparent. We have found analytical expressions for the efficiency in terms of a few parameters such as the volume of the source and the Fermi age and diffusion length of thermal neutrons in both the source and reflector regions. A single analytical expression can then be used for scoping the design and to intercompare radically different designs. Higher efficiencies can be achieved by reducing the volume and the moderation of a core immersed in a very low absorbing reflector; on the contrary a very long core life has a negative effect on the efficiency at beginning of life. Consequently, and after detailed calculations, we have found a candidate design with the following characteristics: core, U/sub 3/Si/sub 2/, 93% enriched, 18.1-kg /sup 235/U, metal fraction 50%, Al cladding, and 35-L volume; reflector and moderator, D/sub 2/O; efficiency at end of life (EOL) with respect to the ILL reactor, 1.29; flux at EOL, 10 x 10/sup 15//cm/sup 2/ sec (power in core 270. MW); core life, 14 days; burnup 28.4%.

  14. Thermal Expansion Studies of Selected High-Temperature Thermoelectric Materials

    NASA Astrophysics Data System (ADS)

    Ravi, Vilupanur; Firdosy, Samad; Caillat, Thierry; Brandon, Erik; van der Walde, Keith; Maricic, Lina; Sayir, Ali

    2009-07-01

    Radioisotope thermoelectric generators (RTGs) generate electrical power by converting the heat released from the nuclear decay of radioactive isotopes (typically plutonium-238) into electricity using a thermoelectric converter. RTGs have been successfully used to power a number of space missions and have demonstrated their reliability over an extended period of time (tens of years) and are compact, rugged, radiation resistant, scalable, and produce no noise, vibration or torque during operation. System conversion efficiency for state-of-practice RTGs is about 6% and specific power ≤5.1 W/kg. A higher specific power would result in more onboard power for the same RTG mass, or less RTG mass for the same onboard power. The Jet Propulsion Laboratory has been leading, under the advanced thermoelectric converter (ATEC) project, the development of new high-temperature thermoelectric materials and components for integration into advanced, more efficient RTGs. Thermoelectric materials investigated to date include skutterudites, the Yb14MnSb11 compound, and SiGe alloys. The development of long-lived thermoelectric couples based on some of these materials has been initiated and is assisted by a thermomechanical stress analysis to ensure that all stresses under both fabrication and operation conditions will be within yield limits for those materials. Several physical parameters are needed as input to this analysis. Among those parameters, the coefficient of thermal expansion (CTE) is critically important. Thermal expansion coefficient measurements of several thermoelectric materials under consideration for ATEC are described in this paper. The stress response at the interfaces in material stacks subjected to changes in temperature is discussed, drawing on work from the literature and project-specific tools developed here. The degree of CTE mismatch and the associated effect on the formation of stress is highlighted.

  15. Thermal Expansion Studies of Selected High Temperature Thermoelectric Materials

    NASA Technical Reports Server (NTRS)

    Ravi, Vilupanur; Firdosy, Samad; Caillat, Thierry; Brandon, Erik; Van Der Walde, Keith; Maricic, Lina; Sayir, Ali

    2008-01-01

    Radioisotope thermoelectric generators (RTGs) generate electrical power by converting the heat released from the nuclear decay of radioactive isotopes (typically plutonium-238) into electricity using a thermoelectric converter. RTGs have been successfully used to power a number of space missions and have demonstrated their reliability over an extended period of time (tens of years) and are compact, rugged, radiation resistant, scalable, and produce no noise, vibration or torque during operation. System conversion efficiency for state-of-practice RTGs is about 6% and specific power less than or equal to 5.1 W/kg. Higher specific power would result in more on-board power for the same RTG mass, or less RTG mass for the same on-board power. The Jet Propulsion Laboratory has been leading, under the advanced thermoelectric converter (ATEC) project, the development of new high-temperature thermoelectric materials and components for integration into advanced, more efficient RTGs. Thermoelectric materials investigated to date include skutterudites, the Yb14MnSb11 compound, and SiGe alloys. The development of long-lived thermoelectric couples based on some of these materials has been initiated and is assisted by a thermo-mechanical stress analysis to ensure that all stresses under both fabrication and operation conditions will be within yield limits for those materials. Several physical parameters are needed as input to this analysis. Among those parameters, the coefficient of thermal expansion (CTE) is critically important. Thermal expansion coefficient measurements of several thermoelectric materials under consideration for ATEC are described in this paper. The stress response at the interfaces in material stacks subjected to changes in temperature is discussed, drawing on work from the literature and project-specific tools developed here. The degree of CTE mismatch and the associated effect on the formation of stress is highlighted.

  16. Thermophysical Properties of Polymer Materials with High Thermal Conductivity

    NASA Astrophysics Data System (ADS)

    Lebedev, S. M.; Gefle, O. S.; Dneprovskii, S. N.; Amitov, E. T.

    2015-06-01

    Results of studies on the main thermophysical properties of new thermally conductive polymer materials are presented. It is shown that modification of polymer dielectrics by micron-sized fillers allows thermally conductive materials with thermal conductivity not less than 2 W/(m K) to be produced, which makes it possible to use such materials as cooling elements of various electrical engineering and semiconductor equipment and devices.

  17. Piezo-thermal Probe Array for High Throughput Applications

    PubMed Central

    Gaitas, Angelo; French, Paddy

    2012-01-01

    Microcantilevers are used in a number of applications including atomic-force microscopy (AFM). In this work, deflection-sensing elements along with heating elements are integrated onto micromachined cantilever arrays to increase sensitivity, and reduce complexity and cost. An array of probes with 5–10 nm gold ultrathin film sensors on silicon substrates for high throughput scanning probe microscopy is developed. The deflection sensitivity is 0.2 ppm/nm. Plots of the change in resistance of the sensing element with displacement are used to calibrate the probes and determine probe contact with the substrate. Topographical scans demonstrate high throughput and nanometer resolution. The heating elements are calibrated and the thermal coefficient of resistance (TCR) is 655 ppm/K. The melting temperature of a material is measured by locally heating the material with the heating element of the cantilever while monitoring the bending with the deflection sensing element. The melting point value measured with this method is in close agreement with the reported value in literature. PMID:23641125

  18. UHPFRC at high temperatures - Simultaneous thermal analysis and thermodilatometry

    NASA Astrophysics Data System (ADS)

    Trník, Anton; Fořt, Jan; Pavlíková, Milena; Čáchová, Monika; Čítek, David; Kolísko, Jiří; Černý, Robert; Pavlík, Zbyšek

    2016-07-01

    Simultaneous Thermal Analysis (STA) and Thermodilatometry Analysis (TDA) are done to reveal the structural and chemical changes in UHPFRC during its high-temperature load. Based on the measured results, several physical and chemical processes that studied material underwent at high-temperatures are recognized. In the temperature interval from 25 to 300 °C, the liberation of physically bound water from pores and the dehydration reaction of C-S-H take place. Additionally, AFt and AFm phases dehydrate at 110 - 156 °C. Endothermic peat at 460 °C corresponds to the portlandite decomposition. At 575 °C, the α → β transformation of quartz is found. This reaction is accompanied by a sharp endothermic heat flow peak and a volume expansion, whereas no change of mass is measured. In the temperature interval 580-800 °C, the calcite and C-S-H gels decomposition is monitored. At the temperature above 800 °C, there is one significant exothermal peak corresponding to a crystallization of wollastonite. In summary, STA and TDA data pointed out the structural changes in studied UHPFRC and allowed identification of critical temperatures for its damage.

  19. High bandwidth piezoresistive force probes with integrated thermal actuation

    PubMed Central

    Doll, Joseph C.; Pruitt, Beth L.

    2012-01-01

    We present high-speed force probes with on-chip actuation and sensing for the measurement of pN-scale forces at the microsecond time scale. We achieve a high resonant frequency in water (1–100 kHz) with requisite low spring constants (0.3–40 pN/nm) and low integrated force noise (1–100 pN) by targeting probe dimensions on the order of 300 nm thick, 1–2 μm wide and 30–200 μm long. Forces are measured using silicon piezoresistors while the probes are actuated thermally with an aluminum unimorph and silicon heater. The piezoresistive sensors are designed using open source numerical optimization code that incorporates constraints on operating temperature. Parylene passivation enables operation in ionic media and we demonstrate simultaneous actuation and sensing. The improved design and fabrication techniques that we describe enable a 10–20 fold improvement in force resolution or measurement bandwidth over prior piezoresistive cantilevers of comparable thickness. PMID:23175616

  20. High-precision micropipette thermal sensor for measurement of thermal conductivity of carbon nanotubes thin film

    NASA Astrophysics Data System (ADS)

    Shrestha, Ramesh

    The thesis describes novel glass micropipette thermal sensor fabricated in cost-effective manner and thermal conductivity measurement of carbon nanotubes (CNT) thin film using the developed sensor. Various micrometer-sized sensors, which range from 2 microm to 30 microm, were produced and tested. The capability of the sensor in measuring thermal fluctuation at micro level with an estimated resolution of +/-0.002°C is demonstrated. The sensitivity of sensors was recorded from 3.34 to 8.86 microV/°C, which is independent of tip size and dependent on the coating of Nickel. The detailed experimental setup for thermal conductivity measurement of CNT film is discussed and 73.418 W/m°C was determined as the thermal conductivity of the CNT film at room temperature.

  1. New American High Schools: Preparing Students for College and Careers. Seventh Annual Business Week Awards for Instructional Innovation.

    ERIC Educational Resources Information Center

    McGraw-Hill Book Co., New York, NY.

    A "New American High School" is a place that prepares students for a global, knowledge-based economy, helping them to be effective citizens, parents, and workers. Case histories are provided for 10 high schools that received awards for instructional innovation. These schools were chosen by the United States Department of Education and the National…

  2. Thermal conductor for high-energy electrochemical cells

    DOEpatents

    Hoffman, Joseph A.; Domroese, Michael K.; Lindeman, David D.; Radewald, Vern E.; Rouillard, Roger; Trice, Jennifer L.

    2000-01-01

    A thermal conductor for use with an electrochemical energy storage device is disclosed. The thermal conductor is attached to one or both of the anode and cathode contacts of an electrochemical cell. A resilient portion of the conductor varies in height or position to maintain contact between the conductor and an adjacent wall structure of a containment vessel in response to relative movement between the conductor and the wall structure. The thermal conductor conducts current into and out of the electrochemical cell and conducts thermal energy between the electrochemical cell and thermally conductive and electrically resistive material disposed between the conductor and the wall structure. The thermal conductor may be fabricated to include a resilient portion having one of a substantially C-shaped, double C-shaped, Z-shaped, V-shaped, O-shaped, S-shaped, or finger-shaped cross-section. An elastomeric spring element may be configured so as to be captured by the resilient conductor for purposes of enhancing the functionality of the thermal conductor. The spring element may include a protrusion that provides electrical insulation between the spring conductor and a spring conductor of an adjacently disposed electrochemical cell in the presence of relative movement between the cells and the wall structure. The thermal conductor may also be fabricated from a sheet of electrically conductive material and affixed to the contacts of a number of electrochemical cells.

  3. High-temperature ceramic heat exchanger element for a solar thermal receiver

    NASA Technical Reports Server (NTRS)

    Strumpf, H. J.; Kotchick, D. M.; Coombs, M. G.

    1982-01-01

    A study was performed by AiResearch Manufacturing Company, a division of The Garrett Corporation, on the development a high-temperature ceramic heat exchanger element to be integrated into a solar receiver producing heated air. A number of conceptual designs were developed for heat exchanger elements of differing configuration. These were evaluated with respect to thermal performance, pressure drop, structural integrity, and fabricability. The final design selection identified a finned ceramic shell as the most favorable concept. The shell is surrounded by a larger metallic shell. The flanges of the two shells are sealed to provide a leak-tight pressure vessel. The ceramic shell is to be fabricated by an innovative combination of slip casting the receiver walls and precision casting the heat transfer finned plates. The fins are bonded to the shell during firing. The unit is sized to produce 2150 F ar at 2.7 atm pressure, with a pressure drop of about 2 percent of the inlet pressure. This size is compatible with a solar collector providing a receiver input of 85 kw(th). Fabrication of a one-half scale demonstrator ceramic receiver has been completed.

  4. A high temperature ceramic heat exchanger element for a solar thermal receiver

    NASA Technical Reports Server (NTRS)

    Strumpf, H. J.; Kotchick, D. M.; Coombs, M. G.

    1982-01-01

    The development of a high-temperature ceramic heat exchanger element to be integrated into a solar receiver producing heated air was studied. A number of conceptual designs were developed for heat exchanger elements of differing configuration. These were evaluated with respect to thermal performance, pressure drop, structural integrity, and fabricability. The final design selection identified a finned ceramic shell as the most favorable concept. The shell is surrounded by a larger metallic shell. The flanges of the two shells are sealed to provide a leak-tight pressure vessel. The ceramic shell is to be fabricated by a innovative combination of slip casting the receiver walls and precision casting the heat transfer finned plates. The fins are bonded to the shell during firing. The unit is sized to produce 2150 F air at 2.7 atm pressure, with a pressure drop of about 2 percent of the inlet pressure. This size is compatible with a solar collector providing a receiver input of 85 kw(th). Fabrication of a one-half scale demonstrator ceramic receiver was completed.

  5. Development of a Thermal Rectifier Usable at High Temperature

    NASA Astrophysics Data System (ADS)

    Takeuchi, Tsunehiro; Goto, Hiroki; Toyama, Yasuhiro; Itoh, Takashi; Mikami, Masashi

    2011-05-01

    By using Al-based metallic alloys characterized by a disordered structure and a narrow pseudogap of a few hundred meV in energy width persisting at the Fermi level, we succeeded in preparing materials possessing a large increase of thermal conductivity with increasing temperature. This unusual increase of thermal conductivity is caused by the electronic structure effect known as the bipolar diffusion effect (BDE) in the context of the two-band model. A thermal rectifier was constructed using materials exhibiting the BDE. By showing the thermal rectification of the bulk sample prepared in this study, we demonstrate that our newly proposed idea of a thermal rectifier using the BDE is applicable for practical use.

  6. Glass-ceramic hermetic seals to high thermal expansion metals

    DOEpatents

    Kramer, D.P.; Massey, R.T.

    1987-04-28

    A process for forming glass-ceramic materials from an alkaline silica-lithia glass composition comprising 60-72 mole-% SiO/sub 2/, 18-27 mole-% Li/sub 2/O, 0-5 mole-% Al/sub 2/O/sub 3/, 0-6 mole-% K/sub 2/O, 0-3 mole-% B/sub 2/O/sub 3/, and 0.5-2.5 mole-% P/sub 2/O/sub 5/, which comprises heating said glass composition at a first temperature within the 950-1050/degree/C range for 5-60 minutes, and then at a devitrification temperature within the 700-900/degree/C range for about 5-300 minutes to obtain a glass-ceramic having a thermal expansion coefficient of up to 210 x 10/sup /minus/7///degree/C. These ceramics form strong, hermetic seals with high expansion metals such as stainless steel alloys. An intermediate nucleation heating step conducted at a temperature within the range of 675-750/degree/C for 10-120 minutes may be employed between the first stage and the devitrification stage. 1 fig., 2 tabs.

  7. High voltage thermally diffused p(+)n solar cells

    NASA Technical Reports Server (NTRS)

    Faur, M.; Faur, M.; Flood, D. J.; Brinker, D. J.; Weinberg, I.; Goradia, C.; Fatemi, N.; Goradia, M.; Thesling, W.

    1991-01-01

    The possibility of fabricating thermally diffused p(+)n InP solar-cells with high open-circuit voltage without sacrificing the short circuit current is discussed. The p(+)n InP junctions were formed by Cd and Zn diffusion through a 3-5-nm-thick anodic or chemical phosphorus-rich oxide cap layer grown on n:InP:S (with ND-NA = 3.5 x 10 exp 16 and 4.5 x 10 exp 17/cu cm) Czochralski LEC-grown substrates. After thinning the emitter from its initial thickness of 1 to 2.5 micron down to 0.06-0.15 micron, the maximum efficiency was found when the emitter was 0.2 to 0.3 micron thick. Typical AM0, 25 C values of 854-860 mV were achieved for Voc, Jsc values were from 25.9 to 29.1 mA/sq cm using only the P-rich passivating layer left after the thinning process as an antireflection coating.

  8. The thermal radiative properties of metals at high temperature

    SciTech Connect

    Self, S.A. . Dept. of Mechanical Engineering)

    1990-01-01

    A knowledge of the optical radiative properties of the surfaces of various metals at high temperatures, up to and above the melting point, is of considerable technical importance for a number of applications. These include smelting and casting, welding by TIG, E-beam and laser methods, and thermal and E-beam evaporative sources for thin film and composite deposition. The optical/radiative properties are important in modeling the energy balance in such applications. Accurate information is required on the surface absorptivity, reflectivity and emissivity as a function of wavelength, temperature and angle relative to the surface normal. These parameters are known to be sensitive functions of the state of the surface, including crystalline state and surface roughness for the solid phase, and the oxidation state of the surface for both solid and liquid metals. The principal thrust of this work is to obtain detailed and accurate data on the optical/radiative properties of pure aluminum and uranium at temperatures up through their melting points. However, it should be added that with the development of apparatus techniques and expertise completed, the facility will be available for optical/radiative property measurements on a variety of materials of interest to various programs at LLNL.

  9. Thermal Desorption Analysis of Hydrogen in High Strength Martensitic Steels

    NASA Astrophysics Data System (ADS)

    Enomoto, M.; Hirakami, D.; Tarui, T.

    2012-02-01

    Thermal desorption analyses (TDA) were conducted in high strength martensitic steels containing carbon from 0.33 to 1.0 mass pct, which were charged with hydrogen at 1223 K (950 °C) under hydrogen of one atmospheric pressure and quenched to room temperature. In 0.33C steel, which had the highest M s temperature, only one desorption peak was observed around 373 K (100 °C), whereas two peaks, one at a similar temperature and the other around and above 573 K (300 °C), were observed in the other steels, the height of the second peak increasing with carbon content. In 0.82C steel, both peaks disappeared during exposure at room temperature in 1 week, whereas the peak heights decreased gradually over 2 weeks in specimens electrolytically charged with hydrogen and aged for varying times at room temperature. From computer simulation, by means of the McNabb-Foster theory coupled with theories of carbon segregation, these peaks are likely to be due to trapping of hydrogen in the strain fields and cores of dislocations, and presumably to a lesser extent in prior austenite grain boundaries. The results also indicate that carbon atoms prevent and even expel hydrogen from trapping sites during quenching and aging in these steels.

  10. High Tech, High Touch: An Innovative Approach to Professional Development for CDA Candidates

    ERIC Educational Resources Information Center

    Whitehead, Linda C.; Rudick, Sherrie; South, Kathy

    2011-01-01

    As barriers to online learning, such as lack of access to high-speed Internet connections, disappear, online learning opportunities are likely to become more and more available to early childhood educators. The eCDA program provides an individualized approach to training and support for earning the Child Development Associate (CDA) Credential,…

  11. History of the development and industrial production of low thermal emissivity coatings for high heat insulating glass units.

    PubMed

    Gläser, Hans J

    2008-05-01

    Low-emissivity (low-E) coatings play a dominate role in high heat insulating multiple glass units with which an essential part of heat energy can be saved in buildings. With such coatings as the main part, and to a lesser part with low thermal conductive filling gases of the units' interspaces, their heat transmittance can be reduced from 6.0 W/m(2)? K for a single glazing--still glazed to a high degree--to 0.4 W/m(2) K for a triple insulating glass unit. This astonishing development is regarded as one of the most important innovations of the flat glass industry in the past century. The roots of low-E coatings in the 1960s, their startup for production in the 1970s, and, most important, further development steps accompanied by, and partly also codesigned actively by the author, are depicted. PMID:18449246

  12. Investigation of Potential Thermal Processing Techniques for the Enhancement of PS300 High Temperature Solid Lubricant Coatings

    NASA Technical Reports Server (NTRS)

    Benoy, Patricia A.

    2000-01-01

    Contemporary trends in rotating machinery development have produced a continuous evolution towards ever increasing speeds and higher operating temperatures. This process has been particularly evident in aerospace and automotive applications such as turbochargers. The combination of high temperature and high speed has exceeded the capacity of mainstream liquid lubrication technology. The NASA Glenn Research Center has been at the forefront in developing innovative solid lubricants for the oil free protection of rotating machinery under these extreme environmental conditions. The most recent of these is the PS 300 series of plasma sprayed solid lubricant coatings. St Louis University and NASA Glenn Research Center entered into this cooperative agreement to investigate potential thermal processing techniques for the enhancement of the PS 304 solid lubricant.

  13. Reduction of thermal emission background in high temperature microheaters

    NASA Astrophysics Data System (ADS)

    Armstrong, Philip R.; Mah, Merlin L.; Olson, Kyle D.; Taylor, Lucas N.; Talghader, Joseph J.

    2016-05-01

    High temperature microheaters have been designed and constructed to reduce the background thermal emission radiation produced by the heater. Such heaters allow one to probe luminescence with very low numbers of photons where the background emission would overwhelm the desired signal. Two methods to reduce background emission are described: one with low emission materials and the other with interference coating design. The first uses platforms composed of material that is transparent to mid-infrared light and therefore of low emissivity. Heating elements are embedded in the periphery of the heater. The transparent platform is composed of aluminum oxide, which is largely transparent for wavelengths less than about 8 μm. In the luminescent microscopy used to test the heater, an optical aperture blocks emission from the heating coils while passing light from the heated objects on the transparent center of the microheater. The amount of infrared light transmitted through the aperture was reduced by 90% as the aperture was moved from the highly emissive heater coils at 450 °C to the largely transparent center at the same temperature. The second method uses microheaters with integrated multilayer interference structures designed to limit background emission in the spectral range of the low-light luminescence object being measured. These heaters were composed of aluminum oxide, titanium dioxide, and platinum and were operated over a large range of temperatures, from 50 °C to 600 °C. At 600 °C, they showed a background photon emission only 1/800 that of a comparison heater without the multilayer interference structure. In this structure, the radiation background was sufficiently reduced to easily monitor weak thermoluminescent emission from CaSO4:Ce,Tb microparticles.

  14. Thin Thermal-Insulation Blankets for Very High Temperatures

    NASA Technical Reports Server (NTRS)

    Choi, Michael K.

    2003-01-01

    Thermal-insulation blankets of a proposed type would be exceptionally thin and would endure temperatures up to 2,100 C. These blankets were originally intended to protect components of the NASA Solar Probe spacecraft against radiant heating at its planned closest approach to the Sun (a distance of 4 solar radii). These blankets could also be used on Earth to provide thermal protection in special applications (especially in vacuum chambers) for which conventional thermal-insulation blankets would be too thick or would not perform adequately.

  15. An Innovative High-Temperature High-Pressure Measurement While Drilling (MWD) Tool

    SciTech Connect

    Brian Boling

    2007-06-01

    Measurement while drilling (MWD) tools specified to 150 C (302 F) that provide wellbore surveys, real-time inclination, and natural gamma ray detection are a commodity item in the oilfield services industry. MWD tools specified to 175 C (347 F) that routinely demonstrate highly reliable operation are available from only a few service companies. Commercial MWD tools that reliably operate to 200 C (392 F) for extended periods of time and offer features like real-time gamma ray, retrievability, and reseatability are nonexistent. Need for these higher temperature tools will increase as wells become hotter in the search for new oil and gas resources. The goal of this project was to design a retrievable and reseatable high-pressure/high-temperature MWD tool with real-time continuous inclination, vibration detection, annular pressure, and gamma ray detection. This report describes the development of such a tool from concept, through feasibility, and into field testing and preliminary development planning. It describes the challenges encountered in the design of the tool, along with testing results and decisions about the commercial viability of the tool in the configuration in which it was developed. The decision was made not to commercialize the tool developed under this project because of a combination of battery technology problems and modulation power consumption at the required depths.

  16. The thermal regime around buried submarine high-voltage cables

    NASA Astrophysics Data System (ADS)

    Emeana, C. J.; Hughes, T. J.; Dix, J. K.; Gernon, T. M.; Henstock, T. J.; Thompson, C. E. L.; Pilgrim, J. A.

    2016-08-01

    The expansion of offshore renewable energy infrastructure and the need for trans-continental shelf power transmission require the use of submarine high-voltage (HV) cables. These cables have maximum operating surface temperatures of up to 70 °C and are typically buried 1-2 m beneath the seabed, within the wide range of substrates found on the continental shelf. However, the heat flow pattern and potential effects on the sedimentary environments around such anomalously high heat sources in the near-surface sediments are poorly understood. We present temperature measurements from a 2-D laboratory experiment representing a buried submarine HV cable, and identify the thermal regimes generated within typical unconsolidated shelf sediments-coarse silt, fine sand and very coarse sand. We used a large (2 × 2.5 m2) tank filled with water-saturated spherical glass beads (ballotini) and instrumented with a buried heat source and 120 thermocouples to measure the time-dependent 2-D temperature distributions. The observed and corresponding Finite Element Method simulations of the steady state heat flow regimes and normalized radial temperature distributions were assessed. Our results show that the heat transfer and thus temperature fields generated from submarine HV cables buried within a range of sediments are highly variable. Coarse silts are shown to be purely conductive, producing temperature increases of >10 °C up to 40 cm from the source of 60 °C above ambient; fine sands demonstrate a transition from conductive to convective heat transfer between cf. 20 and 36 °C above ambient, with >10 °C heat increases occurring over a metre from the source of 55 °C above ambient; and very coarse sands exhibit dominantly convective heat transfer even at very low (cf. 7 °C) operating temperatures and reaching temperatures of up to 18 °C above ambient at a metre from the source at surface temperatures of only 18 °C. These findings are important for the surrounding near

  17. The thermal regime around buried submarine high voltage cables

    NASA Astrophysics Data System (ADS)

    Emeana, C. J.; Hughes, T. J.; Dix, J. K.; Gernon, T. M.; Henstock, T. J.; Thompson, C. E. L.; Pilgrim, J. A.

    2016-05-01

    The expansion of offshore renewable energy infrastructure and the need for trans-continental shelf power transmission require the use of submarine High Voltage (HV) cables. These cables have maximum operating surface temperatures of up to 70°C and are typically buried 1-2 m beneath the seabed, within the wide range of substrates found on the continental shelf. However, the heat flow pattern and potential effects on the sedimentary environments around such anomalously high heat sources in the near surface sediments are poorly understood. We present temperature measurements from a 2D laboratory experiment representing a buried submarine HV cable, and identify the thermal regimes generated within typical unconsolidated shelf sediments-coarse silt, fine sand and very coarse sand. We used a large (2 × 2.5 m) tank filled with water-saturated spherical glass beads (ballotini) and instrumented with a buried heat source and 120 thermocouples, to measure the time-dependent 2D temperature distributions. The observed and corresponding Finite Element Method (FEM) simulations of the steady state heat flow regimes, and normalised radial temperature distributions were assessed. Our results show that the heat transfer and thus temperature fields generated from submarine HV cables buried within a range of sediments are highly variable. Coarse silts are shown to be purely conductive, producing temperature increases of >10°C up to 40 cm from the source of 60°C above ambient; fine sands demonstrate a transition from conductive to convective heat transfer between c. 20°C and 36°C above ambient, with >10°C heat increases occurring over a metre from the source of 55°C above ambient; and very coarse sands exhibit dominantly convective heat transfer even at very low (c. 7°C) operating temperatures and reaching temperatures of up to 18°C above ambient at a metre from the source at surface temperatures of only 18°C. These findings are important for the surrounding near surface

  18. PRAXIS: low thermal emission high efficiency OH suppressed fibre spectrograph

    NASA Astrophysics Data System (ADS)

    Content, Robert; Bland-Hawthorn, Joss; Ellis, Simon; Gers, Luke; Haynes, Roger; Horton, Anthony; Lawrence, Jon; Leon-Saval, Sergio; Lindley, Emma; Min, Seong-Sik; Shortridge, Keith; Staszak, Nick; Trinh, Christopher; Xavier, Pascal; Zhelem, Ross

    2014-07-01

    PRAXIS is a second generation instrument that follows on from GNOSIS, which was the first instrument using fibre Bragg gratings for OH suppression to be deployed on a telescope. The Bragg gratings reflect the NIR OH lines while being transparent to the light between the lines. This gives in principle a much higher signal-noise ratio at low resolution spectroscopy but also at higher resolutions by removing the scattered wings of the OH lines. The specifications call for high throughput and very low thermal and detector noise so that PRAXIS will remain sky noise limited even with the low sky background levels remaining after OH suppression. The optical and mechanical designs are presented. The optical train starts with fore-optics that image the telescope focal plane on an IFU which has 19 hexagonal microlenses each feeding a multi-mode fibre. Seven of these fibres are attached to a fibre Bragg grating OH suppression system while the others are reference/acquisition fibres. The light from each of the seven OH suppression fibres is then split by a photonic lantern into many single mode fibres where the Bragg gratings are imprinted. Another lantern recombines the light from the single mode fibres into a multi-mode fibre. A trade-off was made in the design of the IFU between field of view and transmission to maximize the signal-noise ratio for observations of faint, compact objects under typical seeing. GNOSIS used the pre-existing IRIS2 spectrograph while PRAXIS will use a new spectrograph specifically designed for the fibre Bragg grating OH suppression and optimised for 1.47 μm to 1.7 μm (it can also be used in the 1.09 μm to 1.26 μm band by changing the grating and refocussing). This results in a significantly higher transmission due to high efficiency coatings, a VPH grating at low incident angle and optimized for our small bandwidth, and low absorption glasses. The detector noise will also be lower thanks to the use of a current generation HAWAII-2RG detector

  19. Silphenylene elastomers have high thermal stability and tensile strength

    NASA Technical Reports Server (NTRS)

    1969-01-01

    Two polymeric silphenylene ethers, when cured by reactions with ethyl silicates and metal salts at room temperature, form elastomers having excellent thermal stability and tensile properties. The highest tensile strength obtained in a reinforced elastomer was 2800 psi.

  20. Thermal barrier coating on high temperature industrial gas turbine engines

    NASA Technical Reports Server (NTRS)

    Carlson, N.; Stoner, B. L.

    1977-01-01

    The thermal barrier coating used was a yttria stabilized zirconia material with a NiCrAlY undercoat, and the base engine used to establish improvements was the P&WA FT50A-4 industrial gas turbine engine. The design benefits of thermal barrier coatings include simplified cooling schemes and the use of conventional alloys in the engine hot section. Cooling flow reductions and improved heating rates achieved with thermal barrier coating result in improved performance. Economic benefits include reduced power production costs and reduced fuel consumption. Over the 30,000 hour life of the thermal barrier coated parts, fuel savings equivalent to $5 million are projected and specific power (megawatts/mass of engine airflow) improvements on the order of 13% are estimated.

  1. High temperature polyimide foams for shuttle upper surface thermal insulation

    NASA Technical Reports Server (NTRS)

    Ball, G. L., III; Leffingwell, J. W.; Salyer, I. O.; Werkmeister, D. W.

    1974-01-01

    Polyimide foams developed by Monsanto Company were examined for use as upper surface space shuttle thermal insulation. It was found that postcured polyimide foams having a density of 64 kg/cu m (4 lb/cu ft) had acceptable physical properties up to and exceeding 700 K (800 F). Physical tests included cyclic heating and cooling in vacuum, weight and dimensional stability, mechanical strength and impact resistance, acoustic loading and thermal conductivity. Molding and newly developed postcuring procedures were defined.

  2. Reliability of high I/O high density CCGA interconnect electronic packages under extreme thermal environments

    NASA Astrophysics Data System (ADS)

    Ramesham, Rajeshuni

    2012-03-01

    Ceramic column grid array (CCGA) packages have been increasing in use based on their advantages such as high interconnect density, very good thermal and electrical performances, compatibility with standard surfacemount packaging assembly processes, and so on. CCGA packages are used in space applications such as in logic and microprocessor functions, telecommunications, payload electronics, and flight avionics. As these packages tend to have less solder joint strain relief than leaded packages or more strain relief over lead-less chip carrier packages, the reliability of CCGA packages is very important for short-term and long-term deep space missions. We have employed high density CCGA 1152 and 1272 daisy chained electronic packages in this preliminary reliability study. Each package is divided into several daisy-chained sections. The physical dimensions of CCGA1152 package is 35 mm x 35 mm with a 34 x 34 array of columns with a 1 mm pitch. The dimension of the CCGA1272 package is 37.5 mm x 37.5 mm with a 36 x 36 array with a 1 mm pitch. The columns are made up of 80% Pb/20%Sn material. CCGA interconnect electronic package printed wiring polyimide boards have been assembled and inspected using non-destructive x-ray imaging techniques. The assembled CCGA boards were subjected to extreme temperature thermal atmospheric cycling to assess their reliability for future deep space missions. The resistance of daisy-chained interconnect sections were monitored continuously during thermal cycling. This paper provides the experimental test results of advanced CCGA packages tested in extreme temperature thermal environments. Standard optical inspection and x-ray non-destructive inspection tools were used to assess the reliability of high density CCGA packages for deep space extreme temperature missions.

  3. Lattice thermal conductivity of dense silicate glass at high pressures

    NASA Astrophysics Data System (ADS)

    Chang, Y. Y.; Hsieh, W. P.

    2015-12-01

    The layered structure of the Earth's interior is generally believed to develop through the magma ocean differentiation in the early Earth. Previous seismic studies revealed the existence of ultra low velocity zones above the core mantle boundary (CMB) which was inferred to be associated with the remnant of a deep magma ocean. The heat flux through the core mantle boundary therefore would strongly depend on the thermal conductivity, both lattice (klat) and radiative (krad) of dense silicate melts and major constituent minerals of the lower mantle. Recent experimental results on the radiative thermal conductivity of dense silicate glasses and lower-mantle minerals suggest that krad of dense silicate glasses could be remarkably lower than krad of the surrounding solid mantle phases. In this case, the dense silicate melts will act as a trap for heat from the Earth's outer core. However, this conclusion remains uncertain because of the lack of direct measurements on lattice thermal conductivities of silicate glasses/melts under lower mantle pressures up to date. Here we report experimental results on lattice thermal conductivities of dense silicate glass with basaltic composition under pressures relevant to the Earth's lower mantle in a diamond-anvil cell using time-domain thermoreflectance method. The study will assist the comprehension of thermal transport properties of silicate melts in the Earth's deep interior and is crucial for understanding the dynamic and thermal evolution of the Earth's internal structure.

  4. Reliability of High I/O High Density CCGA Interconnect Electronic Packages under Extreme Thermal Environment

    NASA Technical Reports Server (NTRS)

    Ramesham, Rajeshuni

    2012-01-01

    This paper provides the experimental test results of advanced CCGA packages tested in extreme temperature thermal environments. Standard optical inspection and x-ray non-destructive inspection tools were used to assess the reliability of high density CCGA packages for deep space extreme temperature missions. Ceramic column grid array (CCGA) packages have been increasing in use based on their advantages such as high interconnect density, very good thermal and electrical performances, compatibility with standard surface-mount packaging assembly processes, and so on. CCGA packages are used in space applications such as in logic and microprocessor functions, telecommunications, payload electronics, and flight avionics. As these packages tend to have less solder joint strain relief than leaded packages or more strain relief over lead-less chip carrier packages, the reliability of CCGA packages is very important for short-term and long-term deep space missions. We have employed high density CCGA 1152 and 1272 daisy chained electronic packages in this preliminary reliability study. Each package is divided into several daisy-chained sections. The physical dimensions of CCGA1152 package is 35 mm x 35 mm with a 34 x 34 array of columns with a 1 mm pitch. The dimension of the CCGA1272 package is 37.5 mm x 37.5 mm with a 36 x 36 array with a 1 mm pitch. The columns are made up of 80% Pb/20%Sn material. CCGA interconnect electronic package printed wiring polyimide boards have been assembled and inspected using non-destructive x-ray imaging techniques. The assembled CCGA boards were subjected to extreme temperature thermal atmospheric cycling to assess their reliability for future deep space missions. The resistance of daisy-chained interconnect sections were monitored continuously during thermal cycling. This paper provides the experimental test results of advanced CCGA packages tested in extreme temperature thermal environments. Standard optical inspection and x-ray non

  5. High latitude hydrological changes during the Eocene Thermal Maximum 2

    NASA Astrophysics Data System (ADS)

    Krishnan, Srinath; Pagani, Mark; Huber, Matthew; Sluijs, Appy

    2014-10-01

    The Eocene hyperthermals, including the Paleocene-Eocene Thermal Maximum (PETM) and Eocene Thermal Maximum 2 (ETM2), represent extreme global warming events ∼56 and 54 million years ago associated with rapid increases in atmospheric greenhouse gas concentrations. An initial study on PETM characteristics in the Arctic region argued for intensification of the hydrological cycle and a substantial increase in poleward moisture transport during global warming based on compound-specific carbon and hydrogen isotopic (2H/1H) records from sedimentary leaf-wax lipids. In this study, we apply this isotopic and hydrological approach on sediments deposited during ETM2 from the Lomonosov Ridge (Integrated Ocean Drilling Program Expedition 302). Our results show similar 2H/1H changes during ETM2 as during the PETM, with a period of 2H-enrichment (∼20‰) relative to “pre-event” values just prior to the negative carbon isotope shift (CIE) that is often taken as the onset of the hyperthermal, and more negative lipid δ2H values (∼-15‰) during peak warming. Notably, lipid 2H-enrichment at the base of the event is coeval with colder TEX86H temperatures. If 2H/1H values of leaf waxes primarily reflect the hydrogen isotopic composition of precipitation, the observed local relationship between temperature and 2H/1H values for the body of ETM2 is precisely the opposite of what would be predicted using a simple Rayleigh isotope distillation model, assuming a meridional vapor trajectory and a reduction in equator-pole temperature gradients. Overall, a negative correlation exists between the average chain length of n-alkanes and 2H/1H suggesting that local changes in ecology could have impacted the hydrogen isotopic compositions of leaf waxes. The negative correlation falls across three separate intervals - the base of the event, the initial CIE, and during the H2 hyperthermal (of which the assignment is not fully certain). Three possible mechanisms potentially explain 2H

  6. HPTLC-aptastaining - Innovative protein detection system for high-performance thin-layer chromatography.

    PubMed

    Morschheuser, Lena; Wessels, Hauke; Pille, Christina; Fischer, Judith; Hünniger, Tim; Fischer, Markus; Paschke-Kratzin, Angelika; Rohn, Sascha

    2016-01-01

    Protein analysis using high-performance thin-layer chromatography (HPTLC) is not commonly used but can complement traditional electrophoretic and mass spectrometric approaches in a unique way. Due to various detection protocols and possibilities for hyphenation, HPTLC protein analysis is a promising alternative for e.g., investigating posttranslational modifications. This study exemplarily focused on the investigation of lysozyme, an enzyme which is occurring in eggs and technologically added to foods and beverages such as wine. The detection of lysozyme is mandatory, as it might trigger allergenic reactions in sensitive individuals. To underline the advantages of HPTLC in protein analysis, the development of innovative, highly specific staining protocols leads to improved sensitivity for protein detection on HPTLC plates in comparison to universal protein derivatization reagents. This study aimed at developing a detection methodology for HPTLC separated proteins using aptamers. Due to their affinity and specificity towards a wide range of targets, an aptamer based staining procedure on HPTLC (HPTLC-aptastaining) will enable manifold analytical possibilities. Besides the proof of its applicability for the very first time, (i) aptamer-based staining of proteins is applicable on different stationary phase materials and (ii) furthermore, it can be used as an approach for a semi-quantitative estimation of protein concentrations. PMID:27220270

  7. HPTLC-aptastaining – Innovative protein detection system for high-performance thin-layer chromatography

    NASA Astrophysics Data System (ADS)

    Morschheuser, Lena; Wessels, Hauke; Pille, Christina; Fischer, Judith; Hünniger, Tim; Fischer, Markus; Paschke-Kratzin, Angelika; Rohn, Sascha

    2016-05-01

    Protein analysis using high-performance thin-layer chromatography (HPTLC) is not commonly used but can complement traditional electrophoretic and mass spectrometric approaches in a unique way. Due to various detection protocols and possibilities for hyphenation, HPTLC protein analysis is a promising alternative for e.g., investigating posttranslational modifications. This study exemplarily focused on the investigation of lysozyme, an enzyme which is occurring in eggs and technologically added to foods and beverages such as wine. The detection of lysozyme is mandatory, as it might trigger allergenic reactions in sensitive individuals. To underline the advantages of HPTLC in protein analysis, the development of innovative, highly specific staining protocols leads to improved sensitivity for protein detection on HPTLC plates in comparison to universal protein derivatization reagents. This study aimed at developing a detection methodology for HPTLC separated proteins using aptamers. Due to their affinity and specificity towards a wide range of targets, an aptamer based staining procedure on HPTLC (HPTLC-aptastaining) will enable manifold analytical possibilities. Besides the proof of its applicability for the very first time, (i) aptamer-based staining of proteins is applicable on different stationary phase materials and (ii) furthermore, it can be used as an approach for a semi-quantitative estimation of protein concentrations.

  8. HPTLC-aptastaining – Innovative protein detection system for high-performance thin-layer chromatography

    PubMed Central

    Morschheuser, Lena; Wessels, Hauke; Pille, Christina; Fischer, Judith; Hünniger, Tim; Fischer, Markus; Paschke-Kratzin, Angelika; Rohn, Sascha

    2016-01-01

    Protein analysis using high-performance thin-layer chromatography (HPTLC) is not commonly used but can complement traditional electrophoretic and mass spectrometric approaches in a unique way. Due to various detection protocols and possibilities for hyphenation, HPTLC protein analysis is a promising alternative for e.g., investigating posttranslational modifications. This study exemplarily focused on the investigation of lysozyme, an enzyme which is occurring in eggs and technologically added to foods and beverages such as wine. The detection of lysozyme is mandatory, as it might trigger allergenic reactions in sensitive individuals. To underline the advantages of HPTLC in protein analysis, the development of innovative, highly specific staining protocols leads to improved sensitivity for protein detection on HPTLC plates in comparison to universal protein derivatization reagents. This study aimed at developing a detection methodology for HPTLC separated proteins using aptamers. Due to their affinity and specificity towards a wide range of targets, an aptamer based staining procedure on HPTLC (HPTLC-aptastaining) will enable manifold analytical possibilities. Besides the proof of its applicability for the very first time, (i) aptamer-based staining of proteins is applicable on different stationary phase materials and (ii) furthermore, it can be used as an approach for a semi-quantitative estimation of protein concentrations. PMID:27220270

  9. Microstructural modeling of thermal conductivity of high burn-up mixed oxide fuel

    NASA Astrophysics Data System (ADS)

    Teague, Melissa; Tonks, Michael; Novascone, Stephen; Hayes, Steven

    2014-01-01

    Predicting the thermal conductivity of oxide fuels as a function of burn-up and temperature is fundamental to the efficient and safe operation of nuclear reactors. However, modeling the thermal conductivity of fuel is greatly complicated by the radially inhomogeneous nature of irradiated fuel in both composition and microstructure. In this work, radially and temperature-dependent models for effective thermal conductivity were developed utilizing optical micrographs of high burn-up mixed oxide fuel. The micrographs were employed to create finite element meshes with the OOF2 software. The meshes were then used to calculate the effective thermal conductivity of the microstructures using the BISON [1] fuel performance code. The new thermal conductivity models were used to calculate thermal profiles at end of life for the fuel pellets. These results were compared to thermal conductivity models from the literature, and comparison between the new finite element-based thermal conductivity model and the Duriez-Lucuta model was favorable.

  10. Facile Method to Fabricate Highly Thermally Conductive Graphite/PP Composite with Network Structures.

    PubMed

    Feng, Changping; Ni, Haiying; Chen, Jun; Yang, Wei

    2016-08-01

    Thermally conductive polymer composites have aroused significant academic and industrial interest for several decades. Herein, we report a novel fabrication method of graphite/polypropylene (PP) composites with high thermal conductivity in which graphite flakes construct a continuous thermally conductive network. The thermal conductivity coefficient of the graphite/PP composites is markedly improved to be 5.4 W/mK at a graphite loading of 21.2 vol %. Such a great improvement of the thermal conductivity is ascribed to the occurrence of orientations of crystalline graphite flakes with large particles around PP resin particles and the formation of a perfect thermally conductive network. The model of Hashin-Shtrikman (HS) is adopted to interpret the outstanding thermally conductive property of the graphite/PP composites. This work provides a guideline for the easy fabrication of thermally conductive composites with network structures. PMID:27391206

  11. Microstructural Modeling of Thermal Conductivity of High Burn-up Mixed Oxide Fuel

    SciTech Connect

    Melissa Teague; Michael Tonks; Stephen Novascone; Steven Hayes

    2014-01-01

    Predicting the thermal conductivity of oxide fuels as a function of burn-up and temperature is fundamental to the efficient and safe operation of nuclear reactors. However, modeling the thermal conductivity of fuel is greatly complicated by the radially inhomogeneous nature of irradiated fuel in both composition and microstructure. In this work, radially and temperature-dependent models for effective thermal conductivity were developed utilizing optical micrographs of high burn-up mixed oxide fuel. The micrographs were employed to create finite element meshes with the OOF2 software. The meshes were then used to calculate the effective thermal conductivity of the microstructures using the BISON fuel performance code. The new thermal conductivity models were used to calculate thermal profiles at end of life for the fuel pellets. These results were compared to thermal conductivity models from the literature, and comparison between the new finite element-based thermal conductivity model and the Duriez–Lucuta model was favorable.

  12. Examining the Relationship Between Information Acquisition, Entrepreneurial Opportunity Recognition, and Innovation Performance in the High Technology Sector in Taiwan

    ERIC Educational Resources Information Center

    Wang, Yu-Lin; Ellinger, Andrea D.

    2007-01-01

    The purpose of this study was to investigate the relationships between information acquisition, entrepreneurial opportunity recognition, and innovation performance in the high technology sector in Taiwan. The results suggest that both information acquisition and entrepreneurial opportunity recognition positively contribute to individual-level and…

  13. A Study of Attitude Change and Achievement in an Innovative Program at the Junior High School Level.

    ERIC Educational Resources Information Center

    Dugan, C. Lawrence

    The Small House program at Slauson Junior High School, Ann Arbor, Michigan, during the 1971-72 school year was evaluated. Two purposes of the evaluation study were to assess developments in the Small House program and to develop a prototype or model for evaluating innovative educational programs that delineates the evaluation, design, and analytic…

  14. Leadership for Sustaining Pedagogical Innovations in ICT Implementation: A Case Study of a Taiwanese Vocational High School

    ERIC Educational Resources Information Center

    Chen, Yih-Shyuan; Chen, Yu-Horng; Wu, Shun-Jyh; Tang, Fang-Kai

    2013-01-01

    This paper is a case study of a vocational high school in Taiwan. The main purpose of the present study is to investigate the key determinants of a school's success in initiating and sustaining pedagogical innovations in Information and Communications Technology (ICT) implementation, with a specific focus on the effect of leadership approaches in…

  15. Solar Thermal Energy Storage Device: Hybrid Nanostructures for High-Energy-Density Solar Thermal Fuels

    SciTech Connect

    2012-01-09

    HEATS Project: MIT is developing a thermal energy storage device that captures energy from the sun; this energy can be stored and released at a later time when it is needed most. Within the device, the absorption of sunlight causes the solar thermal fuel’s photoactive molecules to change shape, which allows energy to be stored within their chemical bonds. A trigger is applied to release the stored energy as heat, where it can be converted into electricity or used directly as heat. The molecules would then revert to their original shape, and can be recharged using sunlight to begin the process anew. MIT’s technology would be 100% renewable, rechargeable like a battery, and emissions-free. Devices using these solar thermal fuels—called Hybrisol—can also be used without a grid infrastructure for applications such as de-icing, heating, cooking, and water purification.

  16. Thermal Modelling of Various Thermal Barrier Coatings in a High Flux Rocket Engine

    NASA Technical Reports Server (NTRS)

    Nesbitt, James A.

    1998-01-01

    A thermal model was developed to predict the thermal response of coated and uncoated tubes tested in a H2/O2 rocket engine. Temperatures were predicted for traditional APS ZrO2-Y2O3 thermal barrier coatings, as well as APS and LPPS ZrO2-Y2O3/NiCrAlY cermet coatings. Good agreement was observed between predicted and measured metal temperatures at locations near the tube surface or at the inner tube wall. The thermal model was also used to quantitatively examine the effect of various coating system parameters on the temperatures in the substrate and coating. Accordingly, the effect of the presence a metallic bond coat and the effect of radiation from the surface of the ceramic layer were examined. In addition, the effect of a variation in the values of the thermal conductivity of the ceramic layer was also investigated. It was shown that a variation in the thermal conductivity of the ceramic layer, on the order of that reported in the literature for plasma sprayed ZrO2-Y2O3 coatings, can result in temperature differences in the substrate greater than 100 C, a much greater effect than that due to the presence of a bond coat or radiation from the ceramic layer. The thermal model was also used to predict the thermal response of a coated rod in order to quantify the difference in the metal temperatures between the two substrate geometries in order to explain the previously-observed increased life of coatings on rods over that on tubes. It was shown that for the short duration testing in the rocket engine, the temperature in a tube could exceed that in a rod by more than 100 C. Lastly, a two-dimensional model was developed to evaluate the effect of tangential heat transfer around the tube and its impact on reducing the stagnation point temperature. It was also shown that tangential heat transfer does not significantly reduce the stagnation point temperature, thus allowing application of a simpler, one-dimensional model for comparing measured and predicted stagnation point

  17. Thermal modelling of high-power laser diodes mounted using various types of submounts

    SciTech Connect

    Bezotosnyi, V V; Krokhin, O N; Oleshchenko, V A; Pevtsov, V F; Popov, Yu M; Cheshev, E A

    2014-10-31

    Using three-dimensional thermal modelling of a highpower 980-nm laser diode with a stripe contact width of 100 μm as an example, we analyse the thermal parameters of high-power laser diodes mounted using submounts. We consider a range of thermal conductivities of submounts that includes parameters of widely used thermal compensators based on AlN, BeO and SiC, as well as on CuW and CuMo composites and polycrystalline and single-crystal synthetic diamond with high thermal conductivity. Taking into account experimental overall efficiency vs. pump current data, we calculate the temperature of the active layer as a function of the width, thickness and thermal conductivity of the submount at thermal loads corresponding to cw output powers of 10, 15 and 20 W. (lasers)

  18. Insulation Performance of Heat-Resistant Material for High-Speed Aircraft Under Thermal Environments

    NASA Astrophysics Data System (ADS)

    Wu, Dafang; Wang, Yuewu; Gao, Zhentong; Yang, Jialing

    2015-09-01

    Lightweight insulation materials are widely used to thermally protect high-speed aircraft, such as missiles. Thermal conductivity is an important parameter used to evaluate the efficiency of a material's thermal insulation performance. Since thermal conductivities provided from material handbooks or manufacturers are discrete data for different temperature ranges, there is a deviation between those and actual parameters in terms of continuous nonlinear variations. Therefore, this study measures the thermal conductivities of lightweight thermal insulation materials at high temperatures, and the relationship between the thermal conductivity and temperature is obtained. A finite element model of the thermal insulation materials is also established and applied to numerically calculate the thermal insulation properties for high-temperature ceramic fiber insulation materials using the experimentally obtained nonlinear relationship between thermal conductivity and temperature. Additionally, a transient aerodynamic heating experiment simulation system is used to thermally test the same materials; the calculated and experimental results for the same materials are compared, which exhibit good consistency that demonstrates that accurate results can be obtained from the numerical computation using the relationship established from the experimentally measured conductivity and temperature.

  19. On-chip integration and high-speed switching of multi-wavelength narrowband thermal emitters

    NASA Astrophysics Data System (ADS)

    Inoue, Takuya; De Zoysa, Menaka; Asano, Takashi; Noda, Susumu

    2016-02-01

    We experimentally demonstrate the high-speed, on-chip wavelength switching of thermal emission in the mid-infrared region. Our device consists of multiple integrated thermal emitters of different colors, each of which is composed of quantum wells and a photonic crystal. On current injection, the device exhibits narrowband (Q > 70) thermal emission with low electric power consumption. By applying a reverse bias to each section of the device, we achieve high-speed (>kHz) switching of multiple thermal emission wavelengths, opening a route towards compact, highly efficient mid-infrared light sources for various sensing applications.

  20. Thermal sharpening in agricultural environments and the utility of high resolution HyspIRI thermal data

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Many agricultural fields in Europe and developing countries are relatively small on the order of 1- 10 hectares, and even though in the U.S. agricultural fields tend to be larger, the resolution of thermal-infrared temperature (TIR) sensors from operational satellites are still generally too coarse...

  1. High temperature insulation materials for reradiative thermal protection systems

    NASA Technical Reports Server (NTRS)

    Hughes, T. A.

    1972-01-01

    Results are presented of a two year program to evaluate packaged thermal insulations for use under a metallic radiative TPS of a shuttle orbiter vehicle. Evaluations demonstrated their survival for up to 100 mission reuse cycles under shuttle acoustic and thermal loads with peak temperatures of 1000 F, 1800 F, 2000 F, 2200 F and 2500 F. The specimens were composed of low density refractory fiber felts, packaged in thin gage metal foils. In addition, studies were conducted on the venting requirements of the packages, salt spray resistance of the metal foils, and the thermal conductivity of many of the insulations as a function of temperature and ambient air pressure. Data is also presented on the radiant energy transport through insulations, and back-scattering coefficients were experimentally determined as a function of source temperature.

  2. A thermally baffled device for highly stabilized convective PCR.

    PubMed

    Chang, Hsiao-Fen Grace; Tsai, Yun-Long; Tsai, Chuan-Fu; Lin, Ching-Ko; Lee, Pei-Yu; Teng, Ping-Hua; Su, Chen; Jeng, Chien-Chung

    2012-05-01

    Rayleigh-Bénard convective PCR is a simple and effective design for amplification of DNA. Convective PCR is, however, extremely sensitive to environmental temperature fluctuations, especially when using small- diameter test tubes. Therefore, this method is inherently unstable with limited applications. Here, we present a convective PCR device that has been modified by adding thermal baffles. With this thermally baffled device the influence from fluctuations in environmental temperature were significantly reduced, even in a wind tunnel (1 m/s). The thermally baffled PCR instrument described here has the potential to be used as a low-cost, point-of-care device for PCR-based molecular diagnostics in the field. PMID:22241586

  3. Building America Top Innovations 2012: High-Performance with Solar Electric Reduced Peak Demand

    SciTech Connect

    none,

    2013-01-01

    This Building America Top Innovations profile describes Building America solar home research that has demonstrated the ability to reduce peak demand by 75%. Numerous field studies have monitored power production and system effectiveness.

  4. Building America Top Innovations 2012: High-Performance Affordable Housing with Habitat for Humanity

    SciTech Connect

    none,

    2013-01-01

    This Building America Top Innovations profile describes Building America support of Habitat for Humanity including researchers who wrote Habitat construction guides and teams that have worked with affiliates on numerous field projects.

  5. Building America Top Innovations 2013 Profile – High-Efficiency Window Air Conditioners

    SciTech Connect

    none,

    2013-09-01

    This Top Innovation profile explains how comprehensive performance testing by the National Renewable Energy Laboratory led to simple, affordable methods that homeowners could employ for increasing the energy efficiency of window air conditioners.

  6. The Public Health Reach of High Fluoride Vehicles: Examples of Innovative Approaches.

    PubMed

    Tellez, Marisol; Wolff, Mark S

    2016-01-01

    Fluorides and sealants have been shown to reduce caries in populations, making fluoride interventions a large part of the dental public health effort. Although public health programs have traditionally focused on fluoride vehicles delivering less than 1,000 ppm of fluoride, more recent efforts have shifted toward the use of high fluoride vehicles such as varnishes and prescription toothpastes. In the USA, states are developing innovative strategies to increase access to dental services by using primary care medical providers to deliver early preventive services as part of well-child care visits. Currently, Medicaid programs in 43 states reimburse medical providers for preventive services including varnish application. Still, there is uncertainty about the cost-effectiveness of such interventions. In many resource-strained environments, with shortages of dental health care providers, lack of fluoridated water and lower dental awareness, it is necessary to develop sustainable programs utilizing already established programs, like primary school education, where caries prevention may be set as a priority. Dental caries among the elderly is an ongoing complex problem. The 5,000-ppm F toothpaste may be a reasonable approach for developing public health programs where root caries control is the main concern. Fluoride varnish and high concentration fluoride toothpaste are attractive because they can easily be incorporated into well-child visits and community-based geriatric programs. Additional research on the effectiveness and costs associated with population-based programs of this nature for high risk groups is needed, especially in areas where a community-based fluoride delivery program is not available. PMID:27099929

  7. Innovative Educational Aerospace Research at the Northeast High School Space Research Center

    NASA Technical Reports Server (NTRS)

    Luyet, Audra; Matarazzo, Anthony; Folta, David

    1997-01-01

    Northeast High Magnet School of Philadelphia, Pennsylvania is a proud sponsor of the Space Research Center (SPARC). SPARC, a model program of the Medical, Engineering, and Aerospace Magnet school, provides talented students the capability to successfully exercise full simulations of NASA manned missions. These simulations included low-Earth Shuttle missions and Apollo lunar missions in the past, and will focus on a planetary mission to Mars this year. At the end of each scholastic year, a simulated mission, lasting between one and eight days, is performed involving 75 students as specialists in seven teams The groups are comprised of Flight Management, Spacecraft Communications (SatCom), Computer Networking, Spacecraft Design and Engineering, Electronics, Rocketry, Robotics, and Medical teams in either the mission operations center or onboard the spacecraft. Software development activities are also required in support of these simulations The objective of this paper is to present the accomplishments, technology innovations, interactions, and an overview of SPARC with an emphasis on how the program's educational activities parallel NASA mission support and how this education is preparing student for the space frontier.

  8. Sterilization of liquid foods by pulsed electric fields–an innovative ultra-high temperature process

    PubMed Central

    Reineke, Kai; Schottroff, Felix; Meneses, Nicolas; Knorr, Dietrich

    2015-01-01

    The intention of this study was to investigate the inactivation of endospores by a combined thermal and pulsed electric field (PEF) treatment. Therefore, self-cultivated spores of Bacillus subtilis and commercial Geobacillus stearothermophilus spores with certified heat resistance were utilized. Spores of both strains were suspended in saline water (5.3 mS cm−1), skim milk (0.3% fat; 5.3 mS cm−1) and fresh prepared carrot juice (7.73 mS cm−1). The combination of moderate preheating (70–90°C) and an insulated PEF-chamber, combined with a holding tube (65 cm) and a heat exchanger for cooling, enabled a rapid heat up to 105–140°C (measured above the PEF chamber) within 92.2–368.9 μs. To compare the PEF process with a pure thermal inactivation, each spore suspension was heat treated in thin glass capillaries and D-values from 90 to 130°C and its corresponding z-values were calculated. For a comparison of the inactivation data, F-values for the temperature fields of both processes were calculated by using computational fluid dynamics (CFD). A preheating of saline water to 70°C with a flow rate of 5 l h−1, a frequency of 150 Hz and an energy input of 226.5 kJ kg−1, resulted in a measured outlet temperature of 117°C and a 4.67 log10 inactivation of B. subtilis. The thermal process with identical F-value caused only a 3.71 log10 inactivation. This synergism of moderate preheating and PEF was even more pronounced for G. stearothermophilus spores in saline water. A preheating to 95°C and an energy input of 144 kJ kg−1 resulted in an outlet temperature of 126°C and a 3.28 log10 inactivation, whereas nearly no inactivation (0.2 log10) was achieved during the thermal treatment. Hence, the PEF technology was evaluated as an alternative ultra-high temperature process. However, for an industrial scale application of this process for sterilization, optimization of the treatment chamber design is needed to reduce the occurring inhomogeneous temperature

  9. Sterilization of liquid foods by pulsed electric fields-an innovative ultra-high temperature process.

    PubMed

    Reineke, Kai; Schottroff, Felix; Meneses, Nicolas; Knorr, Dietrich

    2015-01-01

    The intention of this study was to investigate the inactivation of endospores by a combined thermal and pulsed electric field (PEF) treatment. Therefore, self-cultivated spores of Bacillus subtilis and commercial Geobacillus stearothermophilus spores with certified heat resistance were utilized. Spores of both strains were suspended in saline water (5.3 mS cm(-1)), skim milk (0.3% fat; 5.3 mS cm(-1)) and fresh prepared carrot juice (7.73 mS cm(-1)). The combination of moderate preheating (70-90°C) and an insulated PEF-chamber, combined with a holding tube (65 cm) and a heat exchanger for cooling, enabled a rapid heat up to 105-140°C (measured above the PEF chamber) within 92.2-368.9 μs. To compare the PEF process with a pure thermal inactivation, each spore suspension was heat treated in thin glass capillaries and D-values from 90 to 130°C and its corresponding z-values were calculated. For a comparison of the inactivation data, F-values for the temperature fields of both processes were calculated by using computational fluid dynamics (CFD). A preheating of saline water to 70°C with a flow rate of 5 l h(-1), a frequency of 150 Hz and an energy input of 226.5 kJ kg(-1), resulted in a measured outlet temperature of 117°C and a 4.67 log10 inactivation of B. subtilis. The thermal process with identical F-value caused only a 3.71 log10 inactivation. This synergism of moderate preheating and PEF was even more pronounced for G. stearothermophilus spores in saline water. A preheating to 95°C and an energy input of 144 kJ kg(-1) resulted in an outlet temperature of 126°C and a 3.28 log10 inactivation, whereas nearly no inactivation (0.2 log10) was achieved during the thermal treatment. Hence, the PEF technology was evaluated as an alternative ultra-high temperature process. However, for an industrial scale application of this process for sterilization, optimization of the treatment chamber design is needed to reduce the occurring inhomogeneous temperature fields

  10. Thermal conductivity of earth materials at high temperatures.

    NASA Technical Reports Server (NTRS)

    Schatz, J. F.; Simmons, G.

    1972-01-01

    The total thermal conductivity (lattice plus radiative) of several important earth materials is measured in the temperature range from 500 to 1900 K. A new technique is used in which a CO2 laser generates a low-frequency temperature wave at one face of a small disk-shaped sample, and an infrared detector views the opposite face to detect the phase of the emerging radiation. Phase data at several frequencies yield the simultaneous determination of the thermal diffusivity and the mean extinction coefficient of the material. The lattice, radiative, and total thermal conductivities are then calculated. Results for single-crystal and polycrystalline forsterite-rich olivines and an enstatite indicate that, even in relatively pure large-grained material, the radiative conductivity does not increase rapidly with temperature. The predicted maximum total thermal conductivity at a depth of 400 km in an olivine mantle is 0.020 cal/cm/sec/deg C, which is less than twice the surface value.

  11. Microcracks Characterization for Thermal Barrier Coatings at High Temperature

    NASA Astrophysics Data System (ADS)

    Hua, J. J.; Wu, W.; Lin, C. C.; Zeng, Y.; Wang, H.; Zheng, X. B.

    2013-08-01

    Thermal barrier coatings (TBCs), used in gas turbine blades, are exposed to oxidation and thermal fatigue conditions. The characterization of TBCs was often performed in laboratory experiments, therefore, its detail failure mechanism is not quite obvious. For better understanding of the phenomenon, it is recommended to observe it under the condition simulating the real service conditions of gas turbines. In the present work, ZrO2 coatings were prepared by air plasma spraying (APS). Scanning electron microscope (SEM), equipped with a heating system, was used to study the in situ microstructure change of TBCs at service temperature at which the aircraft is operated. The bond coat (BC) layer's thickening process and thermally grown oxide (TGO) generation along with the cracks growth are revealed. Moreover, the influence of the service temperature and holding time on the failure mechanism of TBCs is discussed. The crack healing produced during the coating re-melting reaction is observed, and it is the key factor to increase the thermal conductivity of the coating.

  12. High-Performance Home Technologies: Solar Thermal & Photovoltaic Systems

    SciTech Connect

    Baechler, M.; Gilbride, T.; Ruiz, K.; Steward, H.; Love, P.

    2007-06-01

    This document is the sixth volume of the Building America Best Practices Series. It presents information that is useful throughout the United States for enhancing the energy efficiency practices in the specific climate zones that are presented in the first five Best Practices volumes. It provides an introduction to current photovoltaic and solar thermal building practices. Information about window selection and shading is included.

  13. High heating rate thermal desorption for molecular surface sampling

    DOEpatents

    Ovchinnikova, Olga S.; Van Berkel, Gary J.

    2016-03-29

    A method for analyzing a sample having at least one analyte includes the step of heating the sample at a rate of at least 10.sup.6 K/s to thermally desorb at least one analyte from the sample. The desorbed analyte is collected. The analyte can then be analyzed.

  14. Thin Thermal-Insulation Blankets for Very High Temperatures

    NASA Technical Reports Server (NTRS)

    Choi, Michael K.

    2003-01-01

    Thermal-insulation blankets of a proposed type would be exceptionally thin and would endure temperatures up to 2,100 C. These blankets were originally intended to protect components of the NASA Solar Probe spacecraft against radiant heating at its planned closest approach to the Sun (a distance of 4 solar radii). These blankets could also be used on Earth to provide thermal protection in special applications (especially in vacuum chambers) for which conventional thermal-insulation blankets would be too thick or would not perform adequately. A blanket according to the proposal (see figure) would be made of molybdenum, titanium nitride, and carbon- carbon composite mesh, which melt at temperatures of 2,610, 2,930, and 2,130 C, respectively. The emittance of molybdenum is 0.24, while that of titanium nitride is 0.03. Carbon-carbon composite mesh is a thermal insulator. Typically, the blanket would include 0.25-mil (.0.00635-mm)-thick hot-side and cold-side cover layers of molybdenum. Titanium nitride would be vapor-deposited on both surfaces of each cover layer. Between the cover layers there would be 10 inner layers of 0.15-mil (.0.0038-mm)-thick molybdenum with vapor-deposited titanium nitride on both sides of each layer. The thickness of each titanium nitride coat would be about 1,000 A. The cover and inner layers would be interspersed with 0.25-mil (0.00635-mm)-thick layers of carbon-carbon composite mesh. The blanket would have total thickness of 4.75 mils (approximately equal to 0.121 mm) and an areal mass density of 0.7 kilograms per square meter. One could, of course, increase the thermal- insulation capability of the blanket by increasing number of inner layers (thereby unavoidably increasing the total thickness and mass density).

  15. Thermal Mechanical Stability of Single-Crystal-Oxide Refractive Concentrators Evaluated for High-Temperature Solar-Thermal Propulsion

    NASA Technical Reports Server (NTRS)

    Jacobson, Nathan S.; Jacobson, Nathan S.; Miller, Robert A.

    1999-01-01

    Recently, refractive secondary solar concentrator systems were developed for solar thermal power and propulsion (ref. 1). Single-crystal oxides-such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO), and sapphire (Al2O3)-are candidate refractive secondary concentrator materials. However, the refractive concentrator system will experience high-temperature thermal cycling in the solar thermal engine during the sun/shade transition of a space mission. The thermal mechanical reliability of these components in severe thermal environments is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions. In this research at the NASA Lewis Research Center, a controlled heat flux test approach was developed for investigating the thermal mechanical stability of the candidate oxide. This approach used a 3.0-kW continuous-wave (wavelength, 10.6 mm) carbon dioxide (CO2) laser (ref. 2). The CO2 laser is especially well-suited for single-crystal thermal shock tests because it can directly deliver well-characterized heat energy to the oxide surfaces. Since the oxides are opaque at the 10.6-mm wavelength of the laser beam, the light energy is absorbed at the surfaces rather than transmitting into the crystals, and thus generates the required temperature gradients within the specimens. The following figure is a schematic diagram of the test rig.

  16. Thermal analysis of thermal barrier coatings in a high heat flux environment

    NASA Technical Reports Server (NTRS)

    Nesbitt, James A.; Brindley, William J.

    1988-01-01

    Gas temperatures and pressures were measured around the second test position in the H2/O2 rocket engine at NASA-Lewis. Measured gas temperatures generally varied from 1210 to 1390 C. Measured pressures were in good agreement with other studies for throat tubes in a square chamber rocket engine. Heat transfer coefficients were measured at 90 and 180 degrees from the stagnation point and resulted in values of 27.5 and 8.5 kW/sq m C, respectively. A thermal model was developed to predict temperatures in bare and coated tubes and rods. Agreement between measured and predicted temperatures below the surface of a bare Mar-M 246 tube was very good for most of the heat up and cool down period. Predicted temperatures were significantly below measured temperatures for the coated tubes. A thermal model to simulate heat transfer to the leading edge of an HPFTP blade was developed and showed that TBCs can significantly dampen the thermal transient which occurs in the HPFTP during the startup of the SSME.

  17. High-field and thermal transport in 2D atomic layer devices

    NASA Astrophysics Data System (ADS)

    Serov, Andrey; Dorgan, Vincent E.; Behnam, Ashkan; English, Chris D.; Li, Zuanyi; Islam, Sharnali; Pop, Eric

    2014-06-01

    This paper reviews our recent results of high-field electrical and thermal properties of atomically thin two-dimensional materials. We show how self-heating affects velocity saturation in suspended and supported graphene. We also demonstrate that multi-valley transport must be taken into account to describe high-field transport in MoS2. At the same time we characterized thermal properties of suspended and nanoscale graphene samples over a wide range of temperatures. We uncovered the effects of edge scattering and grain boundaries on thermal transport in graphene, and showed how the thermal conductivity varies between diffusive and ballistic heat flow limits.

  18. Thermal activation at moderate-to-high and high damping: finite barrier effects and force spectroscopy.

    PubMed

    Mazo, J J; Fajardo, O Y; Zueco, D

    2013-03-14

    We study the thermal escape problem in the moderate-to-high and high damping regime of a system with a parabolic barrier. We present a formula that matches our numerical results accounting for finite barrier effects, and compare it with previous works. We also show results for the full damping range. We quantitatively study some aspects on the relation between mean first passage time and the definition of an escape rate. To finish, we apply our results and considerations in the framework of force spectroscopy problems. We study the differences on the predictions using the different theories and discuss the role of γF[over dot] as the relevant parameter at high damping. PMID:23514463

  19. Thermal activation at moderate-to-high and high damping: Finite barrier effects and force spectroscopy

    NASA Astrophysics Data System (ADS)

    Mazo, J. J.; Fajardo, O. Y.; Zueco, D.

    2013-03-01

    We study the thermal escape problem in the moderate-to-high and high damping regime of a system with a parabolic barrier. We present a formula that matches our numerical results accounting for finite barrier effects, and compare it with previous works. We also show results for the full damping range. We quantitatively study some aspects on the relation between mean first passage time and the definition of an escape rate. To finish, we apply our results and considerations in the framework of force spectroscopy problems. We study the differences on the predictions using the different theories and discuss the role of γ dot{F} as the relevant parameter at high damping.

  20. Technological Innovations for High-Throughput Approaches to In Vitro Allergy Diagnosis

    PubMed Central

    Wuenschmann, Sabina; King, Eva; Pomés, Anna

    2016-01-01

    Allergy diagnostics is being transformed by the advent of in vitro IgE testing using purified allergen molecules, combined with multiplex technology and biosensors, to deliver discriminating, sensitive, and high-throughput molecular diagnostics at the point of care. Essential elements of IgE molecular diagnostics are purified natural or recombinant allergens with defined purity and IgE reactivity, planar or bead-based multiplex systems to enable IgE to multiple allergens to be measured simultaneously, and, most recently, nanotechnology-based biosensors that facilitate rapid reaction rates and delivery of test results via mobile devices. Molecular diagnostics relies on measurement of IgE to purified allergens, the “active ingredients” of allergenic extracts. Typically, this involves measuring IgE to multiple allergens which is facilitated by multiplex technology and biosensors. The technology differentiates between clinically significant cross-reactive allergens (which could not be deduced by conventional IgE assays using allergenic extracts) and provides better diagnostic outcomes. Purified allergens are manufactured under good laboratory practice and validated using protein chemistry, mass spectrometry, and IgE antibody binding. Recently, multiple allergens (from dog) were expressed as a single molecule with high diagnostic efficacy. Challenges faced by molecular allergy diagnostic companies include generation of large panels of purified allergens with known diagnostic efficacy, access to flexible and robust array or sensor technology, and, importantly, access to well-defined serum panels form allergic patients for product development and validation. Innovations in IgE molecular diagnostics are rapidly being brought to market and will strengthen allergy testing at the point of care. PMID:26143391

  1. Thermal-contact-conductance measurement for high-heat-load optics components at SPring-8

    NASA Astrophysics Data System (ADS)

    Takeuchi, T.; Tanaka, M.; Senba, Y.; Ohashi, H.; Goto, S.

    2011-09-01

    Thermal contact in water-cooling or cryogenic cooling-cooling condition is used for forming a high-heat-load component at the synchrotron radiation beamline. In SPring-8, for example, cryogenic cooling is used for silicon monochromator crystal with an indium insertion metal at the interface between a copper block and a silicon crystal. To reduce the strain on the silicon crystal with a low contact pressure and a high thermal conductivity, we require a silicon-indium-copper system and an alternative insertion material such as a graphite foil. To measure the thermal contact conductance in a quick measurement cycle under various thermal-contact conditions, we improve the thermal-contact-conductance measurement system in terms of the setup facilitation, precise temperature measurement, and thermal insulation around a sample.

  2. High-performance uncooled handheld thermal imager for law enforcement

    NASA Astrophysics Data System (ADS)

    Stout, Arthur; Rittenberg, Elliott F.

    1997-02-01

    Nighttime surveillance is a key task for all law enforcement organizations. Traditional light intensification night vision systems suffer from poor sensitivity in extremely low light level situations, and are prone to blooming if an unexpected bright source intrudes upon the field of view. Thermal imagers detect infrared radiation emitted by all objects in proportion to the target's temperature, and are effective even in total darkness. However, until recently, most commercially available systems required cryogenic cooling, resulting in long start up times as Stirling engines drove the infrared detectors down to operating temperatures. This operational delay, combined with the audible noise emitted by many cryogenically cooled systems, resulted in systems which were less than optimum for law enforcement applications. This paper will describe a new uncooled microbolometer based infrared camera suitable for surveillance requirements. Basic microbolometer focal plane technology will be reviewed, and a description of its implementation into a hand held uncooled thermal imaging systems will be presented.

  3. Toward nanofluids of ultra-high thermal conductivity

    PubMed Central

    2011-01-01

    The assessment of proposed origins for thermal conductivity enhancement in nanofluids signifies the importance of particle morphology and coupled transport in determining nanofluid heat conduction and thermal conductivity. The success of developing nanofluids of superior conductivity depends thus very much on our understanding and manipulation of the morphology and the coupled transport. Nanofluids with conductivity of upper Hashin-Shtrikman (H-S) bound can be obtained by manipulating particles into an interconnected configuration that disperses the base fluid and thus significantly enhancing the particle-fluid interfacial energy transport. Nanofluids with conductivity higher than the upper H-S bound could also be developed by manipulating the coupled transport among various transport processes, and thus the nature of heat conduction in nanofluids. While the direct contributions of ordered liquid layer and particle Brownian motion to the nanofluid conductivity are negligible, their indirect effects can be significant via their influence on the particle morphology and/or the coupled transport. PMID:21711677

  4. High Resolution Viscosity Measurement by Thermal Noise Detection

    PubMed Central

    Aguilar Sandoval, Felipe; Sepúlveda, Manuel; Bellon, Ludovic; Melo, Francisco

    2015-01-01

    An interferometric method is implemented in order to accurately assess the thermal fluctuations of a micro-cantilever sensor in liquid environments. The power spectrum density (PSD) of thermal fluctuations together with Sader’s model of the cantilever allow for the indirect measurement of the liquid viscosity with good accuracy. The good quality of the deflection signal and the characteristic low noise of the instrument allow for the detection and corrections of drawbacks due to both the cantilever shape irregularities and the uncertainties on the position of the laser spot at the fluctuating end of the cantilever. Variation of viscosity below 0.03 mPa·s was detected with the alternative to achieve measurements with a volume as low as 50 μL. PMID:26540061

  5. High Resolution Viscosity Measurement by Thermal Noise Detection.

    PubMed

    Sandoval, Felipe Aguilar; Sepúlveda, Manuel; Bellon, Ludovic; Melo, Francisco

    2015-01-01

    An interferometric method is implemented in order to accurately assess the thermal fluctuations of a micro-cantilever sensor in liquid environments. The power spectrum density (PSD) of thermal fluctuations together with Sader's model of the cantilever allow for the indirect measurement of the liquid viscosity with good accuracy. The good quality of the deflection signal and the characteristic low noise of the instrument allow for the detection and corrections of drawbacks due to both the cantilever shape irregularities and the uncertainties on the position of the laser spot at the fluctuating end of the cantilever. Variation of viscosity below 0:03mPa·s was detected with the alternative to achieve measurements with a volume as low as 50 µL. PMID:26540061

  6. Limits to Fourier theory in high thermal conductivity single crystals

    NASA Astrophysics Data System (ADS)

    Wilson, R. B.; Cahill, David G.

    2015-11-01

    We report the results of time-domain thermoreflectance (TDTR) experiments that examine the ability of Fourier theory to predict the thermal response in single crystals when heater dimensions are small. We performed TDTR measurements on Al-coated diamond, 6H-SiC, GaP, Ge, MgO, GaAs, and GaSb single crystals with a wide range of laser spot size radii, 0.7 μm < w 0 < 12 μm. When the laser spot-size is large, w 0 ≈ 12 μm, TDTR data for all crystals are in agreement with predictions of Fourier theory with bulk thermal conductivity values. When the laser spot-size is small, w 0 < 2 μm, there are significant differences between the predictions of Fourier theory and TDTR data for all crystals except MgO.

  7. Light thermal structures and materials for high speed flight

    NASA Technical Reports Server (NTRS)

    Thornton, Earl A.

    1992-01-01

    Over the last twenty years, unified viscoplastic constitutive models have evolved to meet this need. These constitutive models provide a means for representing a material's response from the elastic through the plastic range including strain-rate dependent plastic flow, creep, and stress relaxation. Rate-dependent plasticity effects are known to be important at elevated temperatures. The purpose of this paper is to describe computational and experimental research programs underway at the Light Thermal Structures Center focused on the investigation of the response of structures and materials to local heating. In the first part of the paper, finite element thermoviscoplastic analysis is highlighted. In the second part of the paper, the thermal-structures experimental program is outlined.

  8. Thermal dissipation media for high power electronic devices using a carbon nanotube-based composite

    NASA Astrophysics Data System (ADS)

    Thang Bui, Hung; Chuc Nguyen, Van; Trinh Pham, Van; Thanh Tam Ngo, Thi; Phan, Ngoc Minh

    2011-06-01

    Challenges in the thermal dissipation of an electronic package arise from the continuous increase in power density of higher-power devices. Carbon nanotubes (CNTs) are known as the highest thermal conductivity material (2000 W mK‑1). This excellent thermal property suggests an approach in applying the CNTs in thermal dispersion materials to solve the aforementioned problems. In this work, we present an effect of thermal dissipation of the CNTs in the high-brightness light emitting diode (HB-LED) and micro-processor. For the thermal dissipation of the HB-LED, a vertically aligned carbon nanotube (VA-CNT) film on a Cu substrate was applied. Meanwhile, for the thermal dissipation of a micro-processor, the composite of commercial thermal paste/CNTs was used instead of the VA-CNTs. The experimental and simulation results have confirmed the advantages of the VA-CNT film and thermal paste/CNT composite as excellent thermal dissipation media for HB-LEDs, μ-processors and other high power electronic devices.

  9. High-Emittance, Low-Absorbance Thermal-Control Coating

    NASA Technical Reports Server (NTRS)

    Le, Huong G.; Obrien, Dudley L.

    1993-01-01

    Modified process for anodizing 5657 aluminum alloy results in Al2O3 surfaces with infrared emissivities as great as 0.92 and solar absorptivities as small as 0.2. Coating enables fabrication of radiators requiring less surface, and hence less weight: radiators with coating weigh approximately 7 percent less than thermally equivalent radiators made with older anodizing processes. Coating applied easily and economically, and retains all of desirable properties of standard anodized coatings.

  10. High gas pressure: an innovative method for the inactivation of dried bacterial spores.

    PubMed

    Colas de la Noue, A; Espinasse, V; Perrier-Cornet, J-M; Gervais, P

    2012-08-01

    In this article, an original non-thermal process to inactivate dehydrated bacterial spores is described. The use of gases such as nitrogen or argon as transmission media under high isostatic pressure led to an inactivation of over 2 logs CFU/g of Bacillus subtilis spores at 430 MPa, room temperature, for a 1 min treatment. A major requirement for the effectiveness of the process resided in the highly dehydrated state of the spores. Only a water activity below 0.3 led to substantial inactivation. The solubility of the gas in the lipid components of the spore and its diffusion properties was essential to inactivation. The main phenomenon involved seems to be the sorption of the gas under pressure by the spores' structures such as residual pores and plasma membranes, followed by a sudden drop in pressure. Observation by phase-contrast microscopy suggests that internal structures have been affected by the treatment. Some parallels with polymer permeability to gas and rigidity at various water activities offer a few clues about the behavior of the outer layers of spores in response to this parameter and provide a good explanation for the sensitivity of spores to high gas pressure discharge at low hydration levels. Specificity of microorganisms such as size, organization, and composition could help in understanding the differences between spores and yeast regarding the parameters required for inactivation, such as pressure or maintenance time. PMID:22362566

  11. High-speed thermal cycling system and method of use

    DOEpatents

    Hansen, Anthony D. A.; Jaklevic, Joseph M.

    1996-01-01

    A thermal cycling system and method of use are described. The thermal cycling system is based on the-circulation of temperature-controlled water directly to the underside of thin-walled polycarbonate microtiter plates. The water flow is selected from a manifold fed by pumps from heated reservoirs. The plate wells are loaded with typically 15-20 .mu.l of reagent mix for the PCR process. Heat transfer through the thin polycarbonate is sufficiently rapid that the contents reach thermal equilibrium with the water in less than 15 seconds. Complete PCR amplification runs of 40 three-step cycles have been performed in as little as 14.5 minutes, with the results showing substantially enhanced specificity compared to conventional technology requiring run times in excess of 100 minutes. The plate clamping station is designed to be amenable to robotic loading and unloading of the system. It includes a heated lid, thus eliminating the need for mineral oil overlay of the reactants. The present system includes three or more plate holder stations, fed from common reservoirs but operating with independent switching cycles. The system can be modularly expanded.

  12. High-speed thermal cycling system and method of use

    DOEpatents

    Hansen, A.D.A.; Jaklevic, J.M.

    1996-04-16

    A thermal cycling system and method of use are described. The thermal cycling system is based on the circulation of temperature-controlled water directly to the underside of thin-walled polycarbonate plates. The water flow is selected from a manifold fed by pumps from heated reservoirs. The plate wells are loaded with typically 15-20 microliters of reagent mix for the PCR process. Heat transfer through the thin polycarbonate is sufficiently rapid that the contents reach thermal equilibrium with the water in less than 15 seconds. Complete PCR amplification runs of 40 three-step cycles have been performed in as little as 14.5 minutes, with the results showing substantially enhanced specificity compared to conventional technology requiring run times in excess of 100 minutes. The plate clamping station is designed to be amenable to robotic loading and unloading of the system. It includes a heated lid, thus eliminating the need for mineral oil overlay of the reactants. The present system includes three or more plate holder stations, fed from common reservoirs but operating with independent switching cycles. The system can be modularly expanded. 13 figs.

  13. High-Powered, Ultrasonically Assisted Thermal Stir Welding

    NASA Technical Reports Server (NTRS)

    Ding, Robert

    2013-01-01

    This method is a solid-state weld process capable of joining metallic alloys without melting. The weld workpieces to be joined by thermal stir welding (TSW) are drawn, by heavy forces, between containment plates past the TSW stir tool that then causes joining of the weld workpiece. TSW is similar to friction stir welding (FSW) in that material is heated into a plastic state (not melted) and stirred using a stir rod. The FSW pin tool is an integrated geometrical structure consisting of a large-diameter shoulder, and a smaller-diameter stir pin protruding from the shoulder. When the pin is plunged into a weld workpiece, the shoulder spins on the surface of the weld workpiece, thus inducing frictional heat into the part. The pin stirs the fraying surfaces of the weld joint, thus joining the weld workpiece into one structure. The shoulder and stir pin of the FSW pin tool must rotate together at a desired rotational speed. The induced frictional energy control and stir pin control of the pin tool cannot be de-coupled. The two work as one integrated unit. TSW, on the other hand, de-couples the heating and stirring of FSW, and allows for independent control of each process element. A uniquely designed induction coil heats the weld workpiece to a desired temperature, and once heated, the part moves into a stir rod whose RPM is also independently controlled. As the weld workpiece moves into the stir rod, the piece is positioned, or sandwiched, between upper and lower containment plates. The plate squeezes together, thus compressing the upper and lower surfaces of the weld workpiece. This compressive force, also called consolidation force, consolidates the plastic material within the weld nugget material as it is being stirred by the stir rod. The stir rod is positioned through the center of the top containment plate and protrudes midway through the opposite lower containment plate where it is mechanically captured. The upper and lower containment plates are separated by a

  14. High-Flux, High-Temperature Thermal Vacuum Qualification Testing of a Solar Receiver Aperture Shield

    NASA Technical Reports Server (NTRS)

    Kerslake, Thomas W.; Mason, Lee S.; Strumpf, Hal J.

    1997-01-01

    As part of the International Space Station (ISS) Phase 1 program, NASA Lewis Research Center (LERC) and the Russian Space Agency (RSA) teamed together to design, build and flight test the world's first orbital Solar Dynamic Power System (SDPS) on the Russian space station Mir. The Solar Dynamic Flight Demonstration (SDFD) program was to operate a nominal 2 kWe SDPS on Mir for a period up to 1-year starting in late 1997. Unfortunately, the SDFD mission was demanifested from the ISS phase 1 shuttle program in early 1996. However, substantial flight hardware and prototypical flight hardware was built including a heat receiver and aperture shield. The aperture shield comprises the front face of the cylindrical cavity heat receiver and is located at the focal plane of the solar concentrator. It is constructed of a stainless steel plate with a 1-m outside diameter, a 0.24-m inside diameter and covered with high-temperature, refractory metal Multi-Foil Insulation (MFI). The aperture shield must minimize heat loss from the receiver cavity, provide a stiff, high strength structure to accommodate shuttle launch loads and protect receiver structures from highly concentrated solar fluxes during concentrator off-pointing events. To satisfy Mir operational safety protocols, the aperture shield was required to accommodate direct impingement of the intensely concentrated solar image for a 1-hour period. To verify thermal-structural durability under the anticipated high-flux, high-temperature loading, an aperture shield test article was constructed and underwent a series of two tests in a large thermal vacuum chamber configured with a reflective, point-focus solar concentrator and a solar simulator. The test article was positioned near the focal plane and exposed to concentrated solar flux for a period of 1-hour. In the first test, a near equilibrium temperature of 1862 K was attained in the center of the shield hot spot. In the second test, with increased incident flux, a near

  15. High-flux, high-temperature thermal vacuum qualification testing of a solar receiver aperture shield

    SciTech Connect

    Kerslake, T.W.; Mason, L.S.; Strumpf, H.J.

    1997-12-31

    As part of the International Space Station (ISS) Phase 1 program, NASA Lewis Research Center (LeRC) and the Russian Space Agency (RSA) teamed together to design, build and flight test the world`s first orbital Solar Dynamic Power System (SDPS) on the Russian space station Mir. The Solar Dynamic Flight Demonstration (SDFD) program was to operate a nominal 2 kWe SDPS on Mir for a period up to 1-year starting in late 1997. Unfortunately, the SDFD mission was demanifested from the ISS Phase 1 shuttle program in early 1996. However, substantial flight hardware and prototypical flight hardware was built including a heat receiver and aperture shield. The aperture shield comprises the front face of the cylindrical cavity heat receiver and is located at the focal plane of the solar concentrator. It is constructed of a stainless steel plate with a 1-m outside diameter, a 0.24-m inside diameter and covered with high-temperature, refractory metal multi-foil insulation (MFI). The aperture shield must minimize heat loss from the receiver cavity, provide a stiff, high strength structure to accommodate shuttle launch loads and protect receiver structures from highly concentrated solar fluxes during concentrator off-pointing events. To satisfy Mir operational safety protocols, the aperture shield was required to accommodate direct impingement of the intensely concentrated solar image for a 1-hour period. To verify thermal-structural durability under the anticipated high-flux, high-temperature loading, an aperture shield test article was constructed and underwent a series of two tests in a large thermal vacuum chamber configured with a reflective, point-focus solar concentrator and a solar simulator. The test article was positioned near the focal plane and exposed to concentrated solar flux for a period of 1-hour. In the first test, a near equilibrium temperature of 1862 K was attained in the center of the shield hot spot. In the second test, with increased incident flux, a near

  16. Monitoring and analysis of thermal deformation waves with a high-speed phase measurement system.

    PubMed

    Taylor, Lucas; Talghader, Joseph

    2015-10-20

    Thermal effects in optical substrates are vitally important in determining laser damage resistance in long-pulse and continuous-wave laser systems. Thermal deformation waves in a soda-lime-silica glass substrate have been measured using high-speed interferometry during a series of laser pulses incident on the surface. Two-dimensional images of the thermal waves were captured at a rate of up to six frames per thermal event using a quantitative phase measurement method. The system comprised a Mach-Zehnder interferometer, along with a high-speed camera capable of up to 20,000 frames-per-second. The sample was placed in the interferometer and irradiated with 100 ns, 2 kHz Q-switched pulses from a high-power Nd:YAG laser operating at 1064 nm. Phase measurements were converted to temperature using known values of thermal expansion and temperature-dependent refractive index for glass. The thermal decay at the center of the thermal wave was fit to a function derived from first principles with excellent agreement. Additionally, the spread of the thermal distribution over time was fit to the same function. Both the temporal decay fit and the spatial fit produced a thermal diffusivity of 5×10-7  m2/s. PMID:26560391

  17. Development of a high-power and high-energy thermal battery

    SciTech Connect

    GUIDOTTI,RONALD A.; SCHARRER,GREGORY L.; REINHARDT,FREDERICK W.

    2000-04-18

    The Li(Si)/FeS{sub 2} and Li(Si)/CoS{sub 2} couples were evaluated with a low-melting LiBr-KBr-LiF eutectic and all-Li LiCl-LiBr-LiF electrolyte for a battery application that required both high energy and high power for short duration. Screening studies were carried out with 1.25 inch-dia. triple cells and with 10-cell batteries. The Li(Si)/LiCl-LiBr-LiF/CoS{sub 2} couple performed the best under the power load and the Li(Si)/LiCl-LiBr-LiF/FeS{sub 2} was better under the energy load. The former system was selected as the best overall performer for the wide range of temperatures for both loads, because of the higher thermal stability of CoS{sub 2}.

  18. High thermal stability and sluggish crystallization kinetics of high-entropy bulk metallic glasses

    NASA Astrophysics Data System (ADS)

    Yang, M.; Liu, X. J.; Ruan, H. H.; Wu, Y.; Wang, H.; Lu, Z. P.

    2016-06-01

    Metallic glasses are metastable and their thermal stability is critical for practical applications, particularly at elevated temperatures. The conventional bulk metallic glasses (BMGs), though exhibiting high glass-forming ability (GFA), crystallize quickly when being heated to a temperature higher than their glass transition temperature. This problem may potentially be alleviated due to the recent developments of high-entropy (or multi-principle-element) bulk metallic glasses (HE-BMGs). In this work, we demonstrate that typical HE-BMGs, i.e., ZrTiHfCuNiBe and ZrTiCuNiBe, have higher kinetic stability, as compared with the benchmark glass Vitreoy1 (Zr41.2Ti13.8Cu12.5Ni10Be22.5) with a similar chemical composition. The measured activation energy for glass transition and crystallization of the HE-BMGs is nearly twice that of Vitreloy 1. Moreover, the sluggish crystallization region ΔTpl-pf, defined as the temperature span between the last exothermic crystallization peak temperature Tpl and the first crystallization exothermic peak temperature Tpf, of all the HE-BMGs is much wider than that of Vitreloy 1. In addition, high-resolution transmission electron microscopy characterization of the crystallized products at different temperatures and the continuous heating transformation diagram which is proposed to estimate the lifetime at any temperature below the melting point further confirm high thermal stability of the HE-BMGs. Surprisingly, all the HE-BMGs show a small fragility value, which contradicts with their low GFA, suggesting that the underlying diffusion mechanism in the liquid and the solid of HE-BMGs is different.

  19. Integration of high-resolution field-based thermal data with synoptic spaceborne thermal data for surface characterization

    NASA Astrophysics Data System (ADS)

    Byrnes, J. M.

    2012-12-01

    High spatial- (~0.03 m/pixel) and temporal- (30 s or better) resolution thermal data collected in the field with a FLIR broadband (7.5-14 μm) thermal imaging camera is integrated with a day-night pair of thermal datasets acquired by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument (90 m/pixel) in order to address the question of the extent to which linear (a.k.a. checkerboard) mixing of blocks and fines can be distinguished from minor/moderate mantling of fines over blocks? This thermophysical effect is important for characterizing surfaces on the Earth and other planetary bodies because if it is not addressed, it can result in errors in deconvolution of thermal infrared data. Additionally, the ability to recognize mantling of rocks with relatively fine-grained material is important for characterizing a range of geologic processes that may modify a surface, including fluvial, aeolian, and hill slope processes. For this study, the Amboy Crater cinder cone and lava flow field (~ 70 sq. km in the Mojave Desert, southern California) is analyzed primarily because (1) it displays both well-exposed and mantled volcanic surfaces with low vegetation, and (2) volcanic surface units such as those displayed at Amboy Crater are widespread on the surfaces of rocky planetary bodies. Apparent thermal inertia is calculated for the flow field from ASTER data both with and without the FLIR ground data to quantify the improvement derived from integrating the datasets. In order to analyze the FLIR data, a new methodology for automated co-registration of calibrated data frames has been developed (required due to field conditions during data acquisition). Preliminary analysis indicates that the diurnal range measured with the FLIR instrument is not accurately represented in the ASTER data and significantly affects interpretations of surface characteristics, including block size distribution and extent of mantling.

  20. Thermally efficient and highly scalable In2Se3 nanowire phase change memory

    NASA Astrophysics Data System (ADS)

    Jin, Bo; Kang, Daegun; Kim, Jungsik; Meyyappan, M.; Lee, Jeong-Soo

    2013-04-01

    The electrical characteristics of nonvolatile In2Se3 nanowire phase change memory are reported. Size-dependent memory switching behavior was observed in nanowires of varying diameters and the reduction in set/reset threshold voltage was as low as 3.45 V/6.25 V for a 60 nm nanowire, which is promising for highly scalable nanowire memory applications. Also, size-dependent thermal resistance of In2Se3 nanowire memory cells was estimated with values as high as 5.86×1013 and 1.04×106 K/W for a 60 nm nanowire memory cell in amorphous and crystalline phases, respectively. Such high thermal resistances are beneficial for improvement of thermal efficiency and thus reduction in programming power consumption based on Fourier's law. The evaluation of thermal resistance provides an avenue to develop thermally efficient memory cell architecture.

  1. Highly Efficient, Simplified, Solution-Processed Thermally Activated Delayed-Fluorescence Organic Light-Emitting Diodes.

    PubMed

    Kim, Young-Hoon; Wolf, Christoph; Cho, Himchan; Jeong, Su-Hun; Lee, Tae-Woo

    2016-01-27

    Highly efficient, simplified, solution-processed thermally activated delayed-fluorescence organic light-emitting diodes can be realized by using pure-organic thermally activated delayed fluorescence emitters and a multifunctional buffer hole-injection layer, in which high EQE (≈24%) and current efficiency (≈73 cd A(-1) ) are demonstrated. High-efficiency fluorescence red-emitting and blue-emitting devices can also be fabricated in this manner. PMID:26619309

  2. Study of thermal effects and optical properties of an innovative absorber in integrated collector storage solar water heater

    NASA Astrophysics Data System (ADS)

    Taheri, Yaser; Alimardani, Kazem; Ziapour, Behrooz M.

    2015-10-01

    Solar passive water heaters are potential candidates for enhanced heat transfer. Solar water heaters with an integrated water tank and with the low temperature energy resource are used as the simplest and cheapest recipient devices of the solar energy for heating and supplying hot water in the buildings. The solar thermal performances of one primitive absorber were determined by using both the experimental and the simulation model of it. All materials applied for absorber such as the cover glass, the black colored sands and the V shaped galvanized plate were submerged into the water. The water storage tank was manufactured from galvanized sheet of 0.0015 m in thickness and the effective area of the collector was 0.67 m2. The absorber was installed on a compact solar water heater. The constructed flat-plate collectors were tested outdoors. However the simulation results showed that the absorbers operated near to the gray materials and all experimental results showed that the thermal efficiencies of the collector are over than 70 %.

  3. Thermal distortion analysis for silicon reflectors irradiated by high-power laser

    NASA Astrophysics Data System (ADS)

    Liu, Liang; Lou, ShuLi; He, YouJin; Li, HaiYan; Ren, JianCun; Yang, Jianqian

    2015-10-01

    The thermal distortion of silicon reflector irradiated by high-power laser were analyzed by numerical simulation. The results indicate that the contributions from the thermo optic effect, photoelastic effect and deformation are about 97.4%, 0.65%, 1.95% for the transmitted beam. The ratio of thermal distortion between reflected beam and transmitted beam is 0.09.

  4. Silicon Oxycarbide Aerogels for High-Temperature Thermal Insulation

    NASA Technical Reports Server (NTRS)

    Evans, Owen; Rhine, Wendell; Coutinho, Decio

    2010-01-01

    This work has shown that the use of SOC-A35 leads to aerogel materials containing a significant concentration of carbidic species and limited amorphous free carbon. Substitution of the divalent oxide species in silica with tetravalent carbidic carbon has directly led to materials that exhibit increased network viscosity, reduced sintering, and limited densification. The SiOC aerogels produced in this work have the highest carbide content of any dense or porous SiOC glass reported in the literature at that time, and exhibit tremendous long-term thermal stability.

  5. Chemically Locked Bicelles with High Thermal and Kinetic Stability.

    PubMed

    Matsui, Ryoichi; Ohtani, Masataka; Yamada, Kuniyo; Hikima, Takaaki; Takata, Masaki; Nakamura, Takashi; Koshino, Hiroyuki; Ishida, Yasuhiro; Aida, Takuzo

    2015-11-01

    In situ polymerization of a bicellar mixture composed of a phospholipid and polymerizable surfactants afforded unprecedented stable bicelles. The polymerized composite showed an aligned phase over a wide thermal range (25 to >90 °C) with excellent (2)H quadrupole splitting of the solvent signal, thus implying versatility as an alignment medium for NMR studies. Crosslinking of the surfactants also brought favorable effects on the kinetic stability and alignment morphology of the bicelles. This system could thus offer a new class of scaffolds for biomembrane models. PMID:26373898

  6. High temperature polymers - A review of novel thermally stable hexafluoroisopropylidene-containing polymers

    NASA Technical Reports Server (NTRS)

    Kane, K. M.; Cassidy, P. E.; Tullos, G. L.; Reynolds, D. W.

    1990-01-01

    The synthesis and properties to date of several novel HFIP-containing polymers and copolymers are presented. Thermal analyses of polyether ketones (PEK), aromatic polyesters, and polymers from a novel 18F-diacid were performed on a thermal analyzer. All three polymer types exhibited enhanced solubility, thermal stability, and low dielectric constants that are predicted for polymers containing the HFIP moiety. The moderate thermal stability observed in the polymers derived from the 18F-diacid is attributed to the oxidatively weak methylene linkage between the HFIP groups and the phenyl rings. PEKs and polyarylates show potential as high emissivity coatings under conditions where atomic oxygen is present.

  7. The Physical-Mechanism Based High-Temperature Thermal Contact Conductance Model with Experimental Verification

    NASA Astrophysics Data System (ADS)

    Liu, Dong-Huan; Shang, Xin-Chun

    2013-03-01

    The physical-mechanism based high-temperature thermal contact conductance model is proposed, in which the temperature effect on the material properties and interface radiation effect are considered. A testing platform of high temperature thermal contact conductance is also established, and the thermal contact conductance between three-dimensional braid C/C composite material and superalloy GH600 is tested under different interface roughness and temperatures. Experimental results verify the rationality of the present model. Results also show that it is necessary to take the effect of temperature into account especially at high temperatures, and the interface radiation effect is negligible compared to spot conduction under 850 K.

  8. Low-thermal-resistance, high-electrical-isolation heat intercept connection

    SciTech Connect

    Niemann, R.C.; Gonczy, J.D.; Nicol, T.H.

    1993-07-01

    A method for providing a low-thermal-resistance, high-electrical-isolation heat intercept connection is presented. Electrical conductors often require the removal of heat produced from their normal operation. The heat can be removed by mechanical connection to a refrigeration source. Such connections require both effective heat removal (low thermal resistance) and effective electrical isolation (high electrical resistance and high dielectric strength). Such connections should be straightforward to fabricate and provide reliable performance that is independent of operating temperature. The connection method described here involves clamping, by thermal interference fit, an electrically insulating cylinder between an outer metallic ring and an inner metallic disk.

  9. Low-thermal-resistance, high-electrical-isolation heat intercept connection

    SciTech Connect

    Niemann, R.C.; Gonczy, J.D. ); Nicol, T.H. )

    1993-01-01

    A method for providing a low-thermal-resistance, high-electrical-isolation heat intercept connection is presented. Electrical conductors often require the removal of heat produced from their normal operation. The heat can be removed by mechanical connection to a refrigeration source. Such connections require both effective heat removal (low thermal resistance) and effective electrical isolation (high electrical resistance and high dielectric strength). Such connections should be straightforward to fabricate and provide reliable performance that is independent of operating temperature. The connection method described here involves clamping, by thermal interference fit, an electrically insulating cylinder between an outer metallic ring and an inner metallic disk.

  10. Thermal conductivity reduction of crystalline silicon by high-pressure torsion

    NASA Astrophysics Data System (ADS)

    Harish, Sivasankaran; Tabara, Mitsuru; Ikoma, Yoshifumi; Horita, Zenji; Takata, Yasuyuki; Cahill, David G.; Kohno, Masamichi

    2014-06-01

    We report a dramatic and irreversible reduction in the lattice thermal conductivity of bulk crystalline silicon when subjected to intense plastic strain under a pressure of 24 GPa using high-pressure torsion (HPT). Thermal conductivity of the HPT-processed samples were measured using picosecond time domain thermoreflectance. Thermal conductivity measurements show that the HPT-processed samples have a lattice thermal conductivity reduction by a factor of approximately 20 (from intrinsic single crystalline value of 142 Wm-1 K-1 to approximately 7.6 Wm-1 K-1). Thermal conductivity reduction in HPT-processed silicon is attributed to the formation of nanograin boundaries and metastable Si-III/XII phases which act as phonon scattering sites, and because of a large density of lattice defects introduced by HPT processing. Annealing the samples at 873 K increases the thermal conductivity due to the reduction in the density of secondary phases and lattice defects.

  11. Thermophysical Properties of a Hot-Work Tool-Steel with High Thermal Conductivity

    NASA Astrophysics Data System (ADS)

    Kaschnitz, E.; Hofer, P.; Funk, W.

    2013-05-01

    In the highly productive permanent mold-casting process, the released enthalpy of the solidifying metal has to be transported through the surrounding hot-work tool-steel to the cooling system. For that reason, the thermal conductivity is a key property of the employed tool-steel. Recently, a new type of steel (Rovalma HTCS 130) has been developed and superior thermal properties have been claimed. In this study, measurements of the thermal diffusivity, heat capacity, and thermal expansion as a function of temperature are described for this steel and results of the computed thermal conductivity are reported. There is quite a discrepancy between the specification of the steel supplier and the results of this study; however, an improvement of the thermal conductivity for this type of steel can be confirmed.

  12. High-temperature thermal treatment of the uterus

    NASA Astrophysics Data System (ADS)

    Ryan, Thomas P.; Xiao, Jia Hua; Chung, Juh Yun

    2003-06-01

    More than 200,000 hysterectomies are performed annually in the US due to abnormal uterine bleeding from excessive menstrual flow. A minimally invasive procedure has been developed using thermal treatment combined with pressure to the endometrial lining of the uterus. Results from a 3-D finite element model will be shown, as well as experimental data. Good correlation was seen between simulations and experiments. The study found similar results then temperatures were increased and times for treatment were shortened.More than 200,000 hysterectomies are performed annually in the US due to abnormal uterine bleeding from excessive menstrual flow. A minimally invasive procedure has been developed using a balloon-based thermal treatment combined with pressure to the endometrial lining of the uterus. A 3D finite element model was set up to simulate the balloon ablation device in the human uterus as used in over 150,000 patients to date. Several additional simulations were made at higher temperatures to seek alternative combinations with higher temperature and shorter time intervals for the same depth of penetration, or deeper penetration at longer times and elevated temperatures. A temperature range of 87 to 150°C was explored. The Bioheat Equation was used in the simulations to predict temperature distributions in tissue. The Damage Integral was also used to characterize the location at depth of irreversible damage in the uterus. Treatment safety issues were also analyzed as the simulations showed the depth of penetration into the myometrium, towards the serosa.

  13. Numerical simulations of thermal convection at high Prandtl numbers

    NASA Astrophysics Data System (ADS)

    Silano, Gabriella

    2008-11-01

    Direct numerical simulations of thermal convection are conducted for a cylindrical cell of aspect ratio .5ex1-.1em/ -.15em.25ex2 . The Prandtl number (Pr) varies from 10^0 to 10^4 and the Rayleigh numbers (Ra) are moderate (10^5 < Ra < 10^9). This study is motivated by the fact that the role of the Prandtl number in convective heat transport is not yet fully understood. The three-dimensional behaviors of the temperature and velocity fields, of the viscous and thermal dissipation fields, and of the diffusive and convective heat fluxes are explored. In the ranges of Pr and Ra considered, we find steady, periodic and chaotic regimes, and large-scale structures which are more complex than the single recirculation cell filling the whole volume. Multiple flow structures are found to be associated with a given set of conditions. The multiple solutions seem to be more probable at higher Pr numbers and could explain the scatter in some data trends. In collaboration with Katepalli Raju Sreenivasan, The Abdus Salam International Centre for Theoretical Physics - Trieste, and Roberto Verzicco, DIM, Universitàdegli Studi di Roma Tor Vergata - Roma.

  14. Multifunctional cyclotriphosphazene/hexagonal boron nitride hybrids and their flame retarding bismaleimide resins with high thermal conductivity and thermal stability.

    PubMed

    Jin, Wenqin; Yuan, Li; Liang, Guozheng; Gu, Aijuan

    2014-09-10

    A novel hybridized multifunctional filler (CPBN), cyclotriphosphazene/hexagonal boron nitride (hBN) hybrid, was synthesized by chemically coating hBN with hexachlorocyclotriphosphazene and p-phenylenediamine, its structure was systemically characterized. Besides, CPBN was used to develop new flame retarding bismaleimide/o,o'-diallylbisphenol A (BD) resins with simultaneously high thermal conductivity and thermal stability. The nature of CPBN has a strong influence on the flame behavior of the composites. With the addition of only 5 wt % CPBN to BD resin, the thermal conductivity increases 2 times; meanwhile the flame retardancy of BD resin is remarkably increased, reflected by the increased limited oxygen index, much longer time to ignition, significantly reduced heat release rate. The thermogravimetric kinetics, structures of chars and pyrolysis gases, and cone calorimeter tests were investigated to reveal the unique flame retarding mechanism of CPBN/BD composites. CPBN provides multieffects on improving the flame retardancy, especially in forming a protective char layer, which means a more thermally stable and condensed barrier for heat and mass transfer, and thus protecting the resin from further combustion. PMID:25140735

  15. Thermal-Mechanical Stability of Single Crystal Oxide Refractive Concentrators for High-Temperature Solar Thermal Propulsion

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Jacobson, Nathan S.; Miller, Robert A.

    1999-01-01

    Single crystal oxides such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO) and sapphire (Al2O3) are candidate refractive secondary concentrator materials for high temperature solar propulsion applications. However, thermo-mechanical reliability of these components in severe thermal environments during the space mission sun/shade transition is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions, and thus provide vital information for the component design. In this paper, a controlled heat flux thermal shock test approach is established for the single crystal oxide materials using a 3.0 kW continuous wave CO2 laser, with a wavelength 10.6 micron. Thermal fracture behavior and failure mechanisms of these oxide materials are investigated and critical temperature gradients are determined under various temperature and heating conditions. The test results show that single crystal sapphire is able to sustain the highest temperature gradient and heating-cooling rate, and thus exhibit the best thermal shock resistance, as compared to the yttria-stabilized zirconia, yttrium aluminum garnet and magnesium oxide.

  16. Thermal-Mechanical Stability of Single Crystal Oxide Refractive Concentrators for High-Temperature Solar Thermal Propulsion

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Jacobson, Nathan S.; Miller, Robert A.

    1999-01-01

    Single crystal oxides such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO) and sapphire (Al2O3) are candidate refractive secondary concentrator materials for high temperature solar propulsion applications. However, thermo-mechanical reliability of these components in severe thermal environments during the space mission sun/shade transition is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions, and thus provide vital information for the component design. In this paper, a controlled heat flux thermal shock test approach is established for the single crystal oxide materials using a 3.0 kW continuous wave CO2 laser, with a wavelength 10.6 micron. Thermal fracture behavior and failure mechanisms of these oxide materials are investigated and critical temperature gradients are determined under various temperature and heating conditions. The test results show that single crystal sapphire is able to sustain the highest temperature gradient and heating-cooling rate, and thus exhibit the best thermal shock resistance, as compared to the yttria-stabilized zirconia, yttrium aluminum garnet, and magnesium oxide.

  17. Building America Top Innovations 2012: Affordable High Performance in Production Homes: Artistic Homes

    SciTech Connect

    none,

    2013-01-01

    This Building America Top Innovations profile describes Artistic Homes, a successful New Mexico production builder, who went from code-minimum to under HERS 50 standard on every home, with optional PV upgrades to HERS 35 or true net zero on every home plan offered.

  18. Building America Top Innovations 2013 Profile – High-Performance Furnace Blowers

    SciTech Connect

    none,

    2013-09-01

    This Top Innovations profile describes Lawrence Berkeley National Laboratory's work with furnace blower design that led to the creation of a standard for rating blowers, credits for the use of good blowers in Federal tax credit programs and energy codes, and consideration in current federal rulemaking procedures.

  19. Building America Top Innovations 2012: Reduced Call-Backs with High-Performance Production Builders

    SciTech Connect

    none,

    2013-01-01

    This Building America Top Innovations profile describes ways Building America teams have helped builders cut call-backs. Harvard University study found builders who worked with Building America had a 50% drop in call-backs. One builder reported a 50-fold reduction in the incidence of pipe freezing, a 50% reduction in drywall cracking, and a 60% decline in call-backs.

  20. Building America Top Innovations 2012: Community Scale High Performance with Solar - Pulte Homes

    SciTech Connect

    none,

    2013-01-01

    This Building America Top Innovations profile describes Pulte Homes of Tucson’s work with Building America to apply a suite of energy-efficiency measures integrated with passive solar design and solar water heating that reduced energy use more than 50% for a community of more than 1,000 homes.

  1. The Baby TALK Model: An Innovative Approach to Identifying High-Risk Children and Families

    ERIC Educational Resources Information Center

    Villalpando, Aimee Hilado; Leow, Christine; Hornstein, John

    2012-01-01

    This research report examines the Baby TALK model, an innovative early childhood intervention approach used to identify, recruit, and serve young children who are at-risk for developmental delays, mental health needs, and/or school failure, and their families. The report begins with a description of the model. This description is followed by an…

  2. Building America Top Innovations 2012: High-Performance Home Cost Performance Trade-offs: Production Builders

    SciTech Connect

    none,

    2013-01-01

    This Building America Top Innovations profile describes Building America research showing how some energy-efficiency measure cost increases can balance against measures that reduce up-front costs: Advanced framing cuts lumber costs, right sizing can mean downsizing the HVAC, moving HVAC into conditioned space cuts installation costs, designing on a 2-foot grid reduces materials waste, etc.

  3. Development of Advanced Thermal and Environmental Barrier Coatings Using a High-Heat-Flux Testing Approach

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Miller, Robert A.

    2003-01-01

    The development of low conductivity, robust thermal and environmental barrier coatings requires advanced testing techniques that can accurately and effectively evaluate coating thermal conductivity and cyclic resistance at very high surface temperatures (up to 1700 C) under large thermal gradients. In this study, a laser high-heat-flux test approach is established for evaluating advanced low conductivity, high temperature capability thermal and environmental barrier coatings under the NASA Ultra Efficient Engine Technology (UEET) program. The test approach emphasizes the real-time monitoring and assessment of the coating thermal conductivity, which initially rises under the steady-state high temperature thermal gradient test due to coating sintering, and later drops under the cyclic thermal gradient test due to coating cracking/delamination. The coating system is then evaluated based on damage accumulation and failure after the combined steady-state and cyclic thermal gradient tests. The lattice and radiation thermal conductivity of advanced ceramic coatings can also be evaluated using laser heat-flux techniques. The external radiation resistance of the coating is assessed based on the measured specimen temperature response under a laser- heated intense radiation-flux source. The coating internal radiation contribution is investigated based on the measured apparent coating conductivity increases with the coating surface test temperature under large thermal gradient test conditions. Since an increased radiation contribution is observed at these very high surface test temperatures, by varying the laser heat-flux and coating average test temperature, the complex relation between the lattice and radiation conductivity as a function of surface and interface test temperature may be derived.

  4. Simulating thermal stress features on hot planetary surfaces in vacuum at high temperature facility in the PEL laboratory

    NASA Astrophysics Data System (ADS)

    Maturilli, A.; Ferrari, S.; Helbert, J.; D'Incecco, P.; D'Amore, M.

    2011-12-01

    In the Planetary Emissivity Laboratory (PEL) at the Institute for Planetary Research of the German Aerospace Center (DLR) in Berlin, we set-up a simulation chamber for the spectroscopic investigation of minerals separates under Mercurial conditions. The chamber can be evacuated to 10-4 bar and the target samples heated to 700 K within few minutes, thanks to the innovative inductive heating system. While developing the protocol for the high temperature spectroscopy measurements we discovered interesting "morphologies" on the sample surfaces. The powders are poured into stainless steel cups of 50 mm internal diameter, 8 mm height and 3 mm depth, having a 5 mm thick base (thus leaving 3 mm free space for the minerals), and rim 1 mm thick. We selected several minerals of interest for Mercurial surface composition and for each of them we analyzed various grain size separates, to study the influence of grain dimensions to the process of thermal stressing. We observed that for the smaller grain size separate (0-25 μm) the thermal stress mainly induces large depressions and fractures, while on larger grain sizes (125-250 μm) small depressions and a cratered surface. Our current working hypothesis is that these features are mainly caused by thermal stress induced by a radiatively quickly cooling surface layer covering the much hotter bulk material. Further investigation is ongoing to understand the processes better. The observed morphologies exhibit surprising similarities to features observed at planetary scale size for example on Mercury and even on Venus. Especially the high resolution images provided currently from MESSENGER'S Mercury Dual Imaging System (MDIS) instrument has revealed plains dominated by polygonal fractures whose origin still have to be determined. Our laboratory analogue studies might in the future provide some insight into the processes creating those features

  5. A Study on High Thermal Conductive Insulation for Claw Teeth Motors

    NASA Astrophysics Data System (ADS)

    Yoshitake, Yuichiro; Obata, Koji; Enomoto, Yuji; Okabe, Yoshiaki

    To increase the power density of motors in a wide range of fields from home appliance to power industry, we proposed two new high thermal conductive insulation systems for the motors. They were a glass cross insulation system and a resin coated insulation system without forced cooling devices such as a cooling fan. Their thermal and insulation characteristics were measured and analyzed, and optimum thermal conductive structures for claw teeth motors were discussed through robust design and thermal network analysis. Experiment on prototype motors with the highest thermal conductive epoxy resin (5 W/mK) and the proposed systems, revealed that the temperature rise of motor coils was decreased; their temperature reached 73 % of that of the motor coils with standard insulation and normal resin (0.6 W/mK). Furthermore, partial discharge inception voltage (PDIV) and breakdown voltage (BDV) were measured, and we verified that resin coated insulation motors could withstand as high a voltage as normal insulation motors.

  6. Utility of Thermal Sharpening Over Texas High Plains Irrigated Agricultural Fields

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Irrigated crop production in the Texas High Plains (THP) is dependent on water extracted from the Ogallala Aquifer, an area suffering from sever water shortage. Water management in this area is therefore highly important. Thermal satellite imagery at high-temporal (~daily) and high-spatial (~100 m...

  7. Joule-Thomson cryogenic cooler with extremely high thermal stability

    NASA Technical Reports Server (NTRS)

    Bard, Steven; Wu, J. J.; Trimble, Curt

    1991-01-01

    An 80-K Joule-Thomson (J-T) cooling system designed for the Probe Infrared Laser Spectrometer (PIRLS) proposed for the Huygens Titan Probe of the Cassini Saturn orbiter mission is presented. The cryogenic cooling requirements of the PIRLS instrument are listed, and the cooler system design including details of a J-T cryostat, cold head, and dewar design is described along with the results of a thermal modeling effort and lab cooler performance testing. It is shown that by using active feedback temperature control of the cold head in combination with the self-regulating action of the J-T cryostat, a temperature stability of less than 0.1 mK/min is achieved by the cooler weighting 1.8 kg.

  8. High temperature electromagnetic characterization of thermal protection system tile materials

    NASA Technical Reports Server (NTRS)

    Heil, Garrett G.

    1993-01-01

    This study investigated the impact of elevated temperatures on the electromagnetic performance of the LI-2200 thermal protection system. A 15-kilowatt CO2 laser was used to heat an LI-2200 specimen to 3000 F while electromagnetic measurements were performed over the frequency range of l9 to 21 GHz. The electromagnetic measurement system consisted of two Dual-Lens Spot-Focusing (DLSF) antennas, a sample support structure, and an HP-8510B vector network analyzer. Calibration of the electromagnetic system was accomplished with a Transmission-Reflection-Line (TRL) procedure and was verified with measurements on a two-layer specimen of known properties. The results of testing indicated that the LI-2200 system's electromagnetic performance is slightly temperature dependent at temperatures up to 3000 F.

  9. Low-temperature thermal conductivity of highly porous copper

    NASA Astrophysics Data System (ADS)

    Tomás, G.; Martins, D.; Cooper, A.; Bonfait, G.

    2015-12-01

    The development and characterization of new materials is of extreme importance in the design of cryogenic apparatus. Recently Versarien® PLC developed a technique capable of producing copper foam with controlled porosity and pore size. Such porous materials could be interesting for cryogenic heat exchangers as well as of special interest in some devices used in microgravit.y environments where a cryogenic liquid is confined by capillarity. In the present work, a system was developed to measure the thermal conductivity by the differential steady-state mode of four copper foam samples with porosity between 58% and 73%, within the temperatures range 20 - 260 K, using a 2 W @ 20 K cryocooler. Our measurements were validated using a copper control sample and by the estimation of the Lorenz number obtained from electrical resistivity measurements at room temperature. With these measurements, the Resistivity Residual Ratio and the tortuosity were obtained.

  10. Innovative Instrumentation and Analysis of the Temperature Measurement for High Temperature Gasification

    SciTech Connect

    Seong W. Lee

    2006-09-30

    The project entitled, ''Innovative Instrumentation and Analysis of the Temperature Measurement for High Temperature Gasification'', was successfully completed by the Principal Investigator, Dr. S. Lee and his research team in the Center for Advanced Energy Systems and Environmental Control Technologies at Morgan State University. The major results and outcomes were presented in semi-annual progress reports and annual project review meetings/presentations. Specifically, the literature survey including the gasifier temperature measurement, the ultrasonic application in cleaning application, and spray coating process and the gasifier simulator (cold model) testing has been successfully conducted during the first year. The results show that four factors (blower voltage, ultrasonic application, injection time intervals, particle weight) were considered as significant factors that affect the temperature measurement. Then the gasifier simulator (hot model) design and the fabrication as well as the systematic tests on hot model were completed to test the significant factors on temperature measurement in the second year. The advanced Industrial analytic methods such as statistics-based experimental design, analysis of variance (ANOVA) and regression methods were applied in the hot model tests. The results show that operational parameters (i.e. air flow rate, water flow rate, fine dust particle amount, ammonia addition) presented significant impact on the temperature measurement inside the gasifier simulator. The experimental design and ANOVA are very efficient way to design and analyze the experiments. The results show that the air flow rate and fine dust particle amount are statistically significant to the temperature measurement. The regression model provided the functional relation between the temperature and these factors with substantial accuracy. In the last year of the project period, the ultrasonic and subsonic cleaning methods and coating materials were tested

  11. Thermal Impact of Fasteners in High-Performance Wood-Framed Walls

    SciTech Connect

    Dane Christensen

    2011-01-01

    This paper discusses high-performance wood-framed walls that use much less than 40% of the energy consumed by similar homes built to minimum code, and evaluates the thermal impact of fasteners used to construct these walls.

  12. Amyloglucosidase hydrolysis of high-pressure and thermally gelatinized corn and wheat starches.

    PubMed

    Selmi, B; Marion, D; Perrier Cornet, J M; Douzals, J P; Gervais, P

    2000-07-01

    The study of glucose production using amyloglucosidase as a biocatalyst was carried out using high-pressure and thermally gelatinized corn and wheat starches. For corn starch, the measured initial rate of glucose production obtained from thermal gelatinization is faster than that obtained from the two high-pressure treatments, but the equilibrium yield of glucose was found to be similar for the three treatments. High-pressure treatments of wheat starch significantly improve the equilibrium yield of glucose compared with those obtained from the thermally gelatinized wheat starch. This difference has been related to the formation of amylose-lipid complexes during heating and could also explain previous physicochemical differences observed between high-pressure and thermally gelatinized starch. PMID:11032475

  13. 2012 ARPA-E Energy Innovation Summit: Profiling Foro Energy: High Power Lasers - Long Distances (Performer Video)

    ScienceCinema

    None Available

    2012-03-21

    The third annual ARPA-E Energy Innovation Summit was held in Washington D.C. in February, 2012. The event brought together key players from across the energy ecosystem - researchers, entrepreneurs, investors, corporate executives, and government officials - to share ideas for developing and deploying the next generation of energy technologies. A few videos were selected for showing during the Summit to attendees. These 'performer videos' highlight innovative research that is ongoing and related to the main topics of the Summit's sessions. Featured in this video from Foro Energy are Joel Moxley, Founder and CEO, Mark Zediker, Founder and CTO, and Paul Deutch, President and COO. Steven Chu, Secretary of Energy, also appears briefly in this video to praise the accomplishment of a high powered laser that can transmit that power long distances for faster and more powerful drilling of geothermal, oil, and gas wells.

  14. Visual Comfort Analysis of Innovative Interior and Exterior Shading Systems for Commercial Buildings using High Resolution Luminance Images

    SciTech Connect

    Konis, Kyle; Lee, Eleanor; Clear, Robert

    2011-01-11

    The objective of this study was to explore how calibrated high dynamic range (HDR) images (luminance maps) acquired in real world daylit environments can be used to characterize, evaluate, and compare visual comfort conditions of innovative facade shading and light-redirecting systems. Detailed (1536 x 1536 pixel) luminance maps were time-lapse acquired from two view positions in an unoccupied full scale testbed facility. These maps were analyzed using existing visual comfort metrics to quantify how innovative interior and exterior shading systems compare to conventional systems under real sun and sky conditions over a solstice-to-solstice test interval. The results provide a case study in the challenges and potential of methods of visualizing, evaluating and summarizing daily and seasonal variation of visual comfort conditions computed from large sets of image data.

  15. 2012 ARPA-E Energy Innovation Summit: Profiling Foro Energy: High Power Lasers - Long Distances (Performer Video)

    SciTech Connect

    None Available

    2012-02-28

    The third annual ARPA-E Energy Innovation Summit was held in Washington D.C. in February, 2012. The event brought together key players from across the energy ecosystem - researchers, entrepreneurs, investors, corporate executives, and government officials - to share ideas for developing and deploying the next generation of energy technologies. A few videos were selected for showing during the Summit to attendees. These 'performer videos' highlight innovative research that is ongoing and related to the main topics of the Summit's sessions. Featured in this video from Foro Energy are Joel Moxley, Founder and CEO, Mark Zediker, Founder and CTO, and Paul Deutch, President and COO. Steven Chu, Secretary of Energy, also appears briefly in this video to praise the accomplishment of a high powered laser that can transmit that power long distances for faster and more powerful drilling of geothermal, oil, and gas wells.

  16. Bimodal sintered silver nanoparticle paste with ultrahigh thermal conductivity and shear strength for high temperature thermal interface material applications.

    PubMed

    Li, Mingyu; Xiao, Yong; Zhang, Zhihao; Yu, Jie

    2015-05-01

    A bimodal silver nanoparticle (AgNP) paste has been synthesized via the simple ultrasonic mixing of two types of unimodal AgNPs (10 and 50 nm in diameter). By sintering this paste at 250 °C for 30 min, we obtained an ultrahigh thermal conductivity of 278.5 W m(-1) K(-1), approximately 65% of the theoretical value for bulk Ag. The shear strength before and after thermal cycling at 50-200 °C for 1000 cycles was approximately 41.80 and 28.75 MPa, respectively. The results show that this excellent performance is attributable to the unique sintered structures inside the bimodal AgNP paste, including its low but stable porosity and the high density coherent twins. In addition, we systematically discuss the sintering behavior of this paste, including the decomposition of the organic layers and the formation of the coherent twins. On the basis of these results, we confirm that our bimodal AgNP paste has excellent potential as a thermal interface material for high temperature power device applications. PMID:25890996

  17. Combining high temporal and high spatial resolution thermal infrared datasets to detect volcanic precursors

    NASA Astrophysics Data System (ADS)

    Reath, K. A.; Dehn, J.; Ramsey, M. S.

    2013-12-01

    Most volcanoes produce some level of precursory activity prior to an eruption. In certain cases, the precursors can be interpreted to make forecasts about the time and magnitude of the impending eruption. Furthermore, subtle changes in this activity can be used to determine the style of an eruption at volcanoes known for differing eruption types. This study focuses on the effectiveness of using thermal infrared (TIR) spaceborne sensors to track volcanic precursors from thermal changes at the summit of volcanoes using data from both the ASTER and AVHRR sensors by focusing on the Kamchatka (Russia) region. At Bezymianny volcano, a clear increase in activity commonly occurs before an eruption, which has allowed predictions to be made months ahead of time. In other cases, such as the Tolbachik eruption in 2012, no precursors were detected before the large scale effusive eruption. However, most volcanoes do not fall into these extremes, as is the case with Kliuchevskoi volcano. Three large eruptions (e.g., 2005, 2007, 2009) have occurred at Kliuchevskoi in the past decade. Before each of these eruptions, AVHRR and ASTER detected thermal anomalies (pixels with radiant energy significantly above the background). High temporal but low spatial resolution (i.e., hours; 1 km) AVHRR data are ideal for detecting high energy events occurring over short time periods. In contrast, high spatial but low temporal resolution (i.e., days to weeks; 90 m) ASTER data enables the detection of much lower levels of activity. These smaller thermal anomalies are more commonly associated with the longer time scale pre-eruptive phase at Kliuchevskoi. The problem occurs where attempting to detect patterns in these anomalies over time. Only volcanic activity that produces a large amount of radiant energy can be seen with the relatively poor spatial resolution of AVHRR, and ASTER will commonly miss shorter duration activity. In this study, we use ASTER data to track low-level anomalies months prior

  18. Thermal response of large area high temperature superconducting YBaCuO infrared bolometer

    NASA Technical Reports Server (NTRS)

    Khalil, Ali E.

    1990-01-01

    Thermal analysis of large area high temperature superconducting infrared detector operating in the equilibrium mode (bolometer) was performed. An expression for the temperature coefficient beta=1/R(dR/dT) in terms of the thermal conductance and the thermal time constant of the detector were derived. A superconducting transition edge bolometer is a thermistor consisting of a thin film superconducting YBaCuO evaporated into a suitable thermally isolated substrate. The operating temperature of the bolometer is maintained close to the midpoint of the superconducting transition region where the resistance R has a maximum dynamic range. A detector with a strip configuration was analyzed and an expression for the temperature rise (delta T) above the ambient due to a uniform illumination with a source of power density P(sub i) was calculated. An expression for the thermal responsivity of the detector was derived using the thermal diffusion analysis with appropriate boundary conditions. It was found that the thermal responsibility depends upon the spatial modulation frequency and the angular frequency of the incoming radiation. The problem of the thermal cross talk between different detector elements was addressed. In the case of monolithic HTS detector array with a row of square elements of dimensions 2a and CCD or CID readout electronics the thermal spread function was derived for different spacing between elements. This analysis can be critical for future design and applications of large area focal plane arrays as broad band optical detectors made of granular thin films HTS YBaCuO.

  19. Comprehensive transient-state study for CARMENES NIR high-thermal stability

    NASA Astrophysics Data System (ADS)

    Becerril, Santiago; Sánchez, Miguel A.; Cárdenas, M. C.; Rabaza, Ovidio; Ramón, Alejandro; Abril, Miguel; Costillo, Luis P.; Morales, Rafael; Rodríguez, Alicia; Amado, Pedro J.

    2010-07-01

    CARMENES has been proposed as a next-generation instrument for the 3.5m Calar Alto Telescope. Its objective is finding habitable exoplanets around M dwarfs through radial velocity measurements (m/s level) in the near-infrared. Consequently, the NIR spectrograph is highly constraint regarding thermal/mechanical requirements. Indeed, the requirements used for the present study limit the thermal stability to +/-0.01K (within year period) over a working temperature of 243K in order to minimise radial velocity drifts. This can be achieved by implementing a solution based on several temperature-controlled rooms (TCR), whose smallest room encloses the vacuum vessel which houses the spectrograph's optomechanics. Nevertheless, several options have been taken into account to minimise the complexity of the thermal design: 1) Large thermal inertia of the system, where, given a thermal instability of the environment (typically, +/-0.1K), the optomechanical system remains stable within +/-0.01K in the long run; 2) Environment thermal control, where thermal stability is ensured by controlling the temperature of the environment surrounding the vacuum vessel. The present article also includes the comprehensive transient-state thermal analyses which have been implemented in order to make the best choice, as well as to give important inputs for the thermal layout of the instrument.

  20. High-speed quantitative phase imaging of dynamic thermal deformation in laser irradiated films

    NASA Astrophysics Data System (ADS)

    Taylor, Lucas N.; Brown, Andrew K.; Olson, Kyle D.; Talghader, Joseph J.

    2015-11-01

    We present a technique for high-speed imaging of the dynamic thermal deformation of transparent substrates under high-power laser irradiation. Traditional thermal sensor arrays are not fast enough to capture thermal decay events. Our system adapts a Mach-Zender interferometer, along with a high-speed camera to capture phase images on sub-millisecond time-scales. These phase images are related to temperature by thermal expansion effects and by the change of refractive index with temperature. High power continuous-wave and long-pulse laser damage often hinges on thermal phenomena rather than the field-induced effects of ultra-short pulse lasers. Our system was able to measure such phenomena. We were able to record 2D videos of 1 ms thermal deformation waves, with 6 frames per wave, from a 100 ns, 10 mJ Q-switched Nd:YAG laser incident on a yttria-coated glass slide. We recorded thermal deformation waves with peak temperatures on the order of 100 degrees Celsius during non-destructive testing.

  1. Thermal Impact on the Performance of Highly Efficient Multi-stage Depressed Collector for Space TWT

    NASA Astrophysics Data System (ADS)

    Gahlaut, Vishant; Latha, A. Mercy; Alvi, Parvez Ahmad; Ghosh, Sanjay Kumar

    2014-01-01

    In a travelling wave tube, much of the waste power is dumped into the collector. If the waste heat is not properly managed, it might pose a serious problem causing even failure of tube. In this paper, the optimal choice of thermal management of a highly efficient multistage depressed collector designed for a space TWT has been made based on several criteria. The structural deformations and stresses developed due to thermal impact have been evaluated. The influence of thermal deformations on the collector electrical performance and high voltage withstanding capability has been studied during hot condition.

  2. High aspect ratio composite structures with 48.5% thermal neutron detection efficiency

    SciTech Connect

    Shao, Q.; Voss, L. F.; Conway, A. M.; Nikolic, R. J.; Dar, M. A.; Cheung, C. L.

    2013-02-11

    The pillar structured thermal neutron detector is based on the combination of high aspect ratio silicon p-i-n pillars surrounded by the neutron converter material {sup 10}B. By etching high aspect ratio pillar structures into silicon, the result is a device that efficiently absorbs the thermal neutron flux by accommodating a large volume fraction of {sup 10}B within the silicon pillar array. Here, we report a thermal neutron detection efficiency of 48.5% using a 50 {mu}m pillar array with an aspect ratio of 25:1.

  3. Experimental study of thermal crisis in connection with Tokamak reactor high heat flux components

    NASA Astrophysics Data System (ADS)

    Gallo, D.; Giardina, M.; Castiglia, F.; Celata, G. P.; Mariani, A.; Zummo, G.; Cumo, M.

    2000-04-01

    The results of an experimental research on high heat flux thermal crisis in forced convective subcooled water flow, under operative conditions of interest to the thermal-hydraulic design of TOKAMAK fusion reactors, are here reported. These experiments, carried out in the framework of a collaboration between the Nuclear Engineering Department of Palermo University and the National Institute of Thermal - Fluid Dynamics of the ENEA - Casaccia (Rome), were performed on the STAF (Scambio Termico Alti Flussi) water loop and consisted, essentially, in a high speed photographic study which enabled focusing several information on bubble characteristics and flow patterns taking place during the burnout phenomenology.

  4. Silver Nanoparticle-Deposited Boron Nitride Nanosheets as Fillers for Polymeric Composites with High Thermal Conductivity

    PubMed Central

    Wang, Fangfang; Zeng, Xiaoliang; Yao, Yimin; Sun, Rong; Xu, Jianbin; Wong, Ching-Ping

    2016-01-01

    Polymer composites with high thermal conductivity have recently attracted much attention, along with the rapid development of the electronic devices toward higher speed and performance. However, a common method to enhance polymer thermal conductivity through an addition of high thermally conductive fillers usually cannot provide an expected value, especially for composites requiring electrical insulation. Here, we show that polymeric composites with silver nanoparticle-deposited boron nitride nanosheets as fillers could effectively enhance the thermal conductivity of polymer, thanks to the bridging connections of silver nanoparticles among boron nitride nanosheets. The thermal conductivity of the composite is significantly increased from 1.63 W/m-K for the composite filled with the silver nanoparticle-deposited boron nitride nanosheets to 3.06 W/m-K at the boron nitride nanosheets loading of 25.1 vol %. In addition, the electrically insulating properties of the composite are well preserved. Fitting the measured thermal conductivity of epoxy composite with one physical model indicates that the composite with silver nanoparticle-deposited boron nitride nanosheets outperforms the one with boron nitride nanosheets, owning to the lower thermal contact resistance among boron nitride nanosheets’ interfaces. The finding sheds new light on enhancement of thermal conductivity of the polymeric composites which concurrently require the electrical insulation. PMID:26783258

  5. Silver Nanoparticle-Deposited Boron Nitride Nanosheets as Fillers for Polymeric Composites with High Thermal Conductivity.

    PubMed

    Wang, Fangfang; Zeng, Xiaoliang; Yao, Yimin; Sun, Rong; Xu, Jianbin; Wong, Ching-Ping

    2016-01-01

    Polymer composites with high thermal conductivity have recently attracted much attention, along with the rapid development of the electronic devices toward higher speed and performance. However, a common method to enhance polymer thermal conductivity through an addition of high thermally conductive fillers usually cannot provide an expected value, especially for composites requiring electrical insulation. Here, we show that polymeric composites with silver nanoparticle-deposited boron nitride nanosheets as fillers could effectively enhance the thermal conductivity of polymer, thanks to the bridging connections of silver nanoparticles among boron nitride nanosheets. The thermal conductivity of the composite is significantly increased from 1.63 W/m-K for the composite filled with the silver nanoparticle-deposited boron nitride nanosheets to 3.06 W/m-K at the boron nitride nanosheets loading of 25.1 vol %. In addition, the electrically insulating properties of the composite are well preserved. Fitting the measured thermal conductivity of epoxy composite with one physical model indicates that the composite with silver nanoparticle-deposited boron nitride nanosheets outperforms the one with boron nitride nanosheets, owning to the lower thermal contact resistance among boron nitride nanosheets' interfaces. The finding sheds new light on enhancement of thermal conductivity of the polymeric composites which concurrently require the electrical insulation. PMID:26783258

  6. Silver Nanoparticle-Deposited Boron Nitride Nanosheets as Fillers for Polymeric Composites with High Thermal Conductivity

    NASA Astrophysics Data System (ADS)

    Wang, Fangfang; Zeng, Xiaoliang; Yao, Yimin; Sun, Rong; Xu, Jianbin; Wong, Ching-Ping

    2016-01-01

    Polymer composites with high thermal conductivity have recently attracted much attention, along with the rapid development of the electronic devices toward higher speed and performance. However, a common method to enhance polymer thermal conductivity through an addition of high thermally conductive fillers usually cannot provide an expected value, especially for composites requiring electrical insulation. Here, we show that polymeric composites with silver nanoparticle-deposited boron nitride nanosheets as fillers could effectively enhance the thermal conductivity of polymer, thanks to the bridging connections of silver nanoparticles among boron nitride nanosheets. The thermal conductivity of the composite is significantly increased from 1.63 W/m-K for the composite filled with the silver nanoparticle-deposited boron nitride nanosheets to 3.06 W/m-K at the boron nitride nanosheets loading of 25.1 vol %. In addition, the electrically insulating properties of the composite are well preserved. Fitting the measured thermal conductivity of epoxy composite with one physical model indicates that the composite with silver nanoparticle-deposited boron nitride nanosheets outperforms the one with boron nitride nanosheets, owning to the lower thermal contact resistance among boron nitride nanosheets’ interfaces. The finding sheds new light on enhancement of thermal conductivity of the polymeric composites which concurrently require the electrical insulation.

  7. Multiscale modeling of thermal conductivity of high burnup structures in UO2 fuels

    SciTech Connect

    Bai, Xian -Ming; Tonks, Michael R.; Zhang, Yongfeng; Hales, Jason D.

    2015-12-22

    The high burnup structure forming at the rim region in UO2 based nuclear fuel pellets has interesting physical properties such as improved thermal conductivity, even though it contains a high density of grain boundaries and micron-size gas bubbles. To understand this counterintuitive phenomenon, mesoscale heat conduction simulations with inputs from atomistic simulations and experiments were conducted to study the thermal conductivities of a small-grain high burnup microstructure and two large-grain unrestructured microstructures. We concluded that the phonon scattering effects caused by small point defects such as dispersed Xe atoms in the grain interior must be included in order to correctly predict the thermal transport properties of these microstructures. In extreme cases, even a small concentration of dispersed Xe atoms such as 10-5 can result in a lower thermal conductivity in the large-grain unrestructured microstructures than in the small-grain high burnup structure. The high-density grain boundaries in a high burnup structure act as defect sinks and can reduce the concentration of point defects in its grain interior and improve its thermal conductivity in comparison with its large-grain counterparts. Furthermore, an analytical model was developed to describe the thermal conductivity at different concentrations of dispersed Xe, bubble porosities, and grain sizes. Upon calibration, the model is robust and agrees well with independent heat conduction modeling over a wide range of microstructural parameters.

  8. Multiscale modeling of thermal conductivity of high burnup structures in UO2 fuels

    DOE PAGESBeta

    Bai, Xian -Ming; Tonks, Michael R.; Zhang, Yongfeng; Hales, Jason D.

    2015-12-22

    The high burnup structure forming at the rim region in UO2 based nuclear fuel pellets has interesting physical properties such as improved thermal conductivity, even though it contains a high density of grain boundaries and micron-size gas bubbles. To understand this counterintuitive phenomenon, mesoscale heat conduction simulations with inputs from atomistic simulations and experiments were conducted to study the thermal conductivities of a small-grain high burnup microstructure and two large-grain unrestructured microstructures. We concluded that the phonon scattering effects caused by small point defects such as dispersed Xe atoms in the grain interior must be included in order to correctlymore » predict the thermal transport properties of these microstructures. In extreme cases, even a small concentration of dispersed Xe atoms such as 10-5 can result in a lower thermal conductivity in the large-grain unrestructured microstructures than in the small-grain high burnup structure. The high-density grain boundaries in a high burnup structure act as defect sinks and can reduce the concentration of point defects in its grain interior and improve its thermal conductivity in comparison with its large-grain counterparts. Furthermore, an analytical model was developed to describe the thermal conductivity at different concentrations of dispersed Xe, bubble porosities, and grain sizes. Upon calibration, the model is robust and agrees well with independent heat conduction modeling over a wide range of microstructural parameters.« less

  9. Multiscale modeling of thermal conductivity of high burnup structures in UO2 fuels

    NASA Astrophysics Data System (ADS)

    Bai, Xian-Ming; Tonks, Michael R.; Zhang, Yongfeng; Hales, Jason D.

    2016-03-01

    The high burnup structure forming at the rim region in UO2 based nuclear fuel pellets has interesting physical properties such as improved thermal conductivity, even though it contains a high density of grain boundaries and micron-size gas bubbles. To understand this counterintuitive phenomenon, mesoscale heat conduction simulations with inputs from atomistic simulations and experiments were conducted to study the thermal conductivities of a small-grain high burnup microstructure and two large-grain unrestructured microstructures. We concluded that the phonon scattering effects caused by small point defects such as dispersed Xe atoms in the grain interior must be included in order to correctly predict the thermal transport properties of these microstructures. In extreme cases, even a small concentration of dispersed Xe atoms such as 10-5 can result in a lower thermal conductivity in the large-grain unrestructured microstructures than in the small-grain high burnup structure. The high-density grain boundaries in a high burnup structure act as defect sinks and can reduce the concentration of point defects in its grain interior and improve its thermal conductivity in comparison with its large-grain counterparts. An analytical model was developed to describe the thermal conductivity at different concentrations of dispersed Xe, bubble porosities, and grain sizes. Upon calibration, the model is robust and agrees well with independent heat conduction modeling over a wide range of microstructural parameters.

  10. High Heat Insulating Thermal Barrier Coating Designed with Large Two-Dimensional Inter-lamellar Pores

    NASA Astrophysics Data System (ADS)

    Liu, Tao; Zhang, Shan-Lin; Luo, Xiao-Tao; Yang, Guan-Jun; Li, Cheng-Xin; Li, Chang-Jiu

    2016-01-01

    Atmospheric plasma-sprayed ceramic coatings with a lamellar structure exhibit low thermal conductivity. However, high-temperature exposure causes sintering, which heals inter-lamellar two-dimensional (2D) pores and intra-splat pores. Such sintering effect increases the thermal conductivity of the coatings and consequently reduces the thermal insulation ability of TBCs. In this study, inter-lamellar 2D pores with a large opening width were introduced into the La2Zr2O7 (LZO) coating through the spraying of a LZO-SrO coating and the removal of the SrO splats in water. Then, the conventional LZO coating and the porous LZO coating were subjected to high-temperature exposure at 1300 °C, for different durations. It was found that the 2D pores resulting from SrO splats present little healing during high-temperature exposure, while the conventional 2D inter-lamellar pores with a small opening width heal rapidly. Thus, the thermal conductivity of the conventional LZO coating increased rapidly, while the unhealed 2D pores in the highly porous LZO coating contributed to the coating low thermal conductivity. The present results indicated that a high heat insulating thermal barrier coating with high stability can be fabricated though the introduction of inter-lamellar 2D pores with large opening width.

  11. Results of innovative communication processes on productivity gains in a high technology environment

    NASA Technical Reports Server (NTRS)

    Kelly, B. J.

    1985-01-01

    The technology which resulted in performance breakthroughs at engineering and management services is discussed. As a result of the innovative approaches of communicating productivity concepts to the employees, specific outcomes can now be pinpointed at all levels of the organization such as: (1) employee-headed program; (2) performance feedback processes; and (3) an investigative approach to creating leadership. The Lockheed Corporation began the innovative trend in 1974 when they became the first company to introduce quality circles in America. Although some of Lockheed-EMSCO's processes may sound different from traditional improvement processes, the context out of which those to be presented evolved has sustained more than 10 years of positive results through employee involvement activities.

  12. [Considerations and ideas on teaching reform of stomatology for cultivating innovative talents of high quality].

    PubMed

    Zheng, Jia-wei; Cao, Xia; Feng, Xi-ping; Zhang, Zhi-yuan; Zhang, Jian-zhong

    2009-10-01

    The past decade has shown increasing demands for reforming dental education that would produce a graduate better equipped to work in the rapidly changing world of the twenty-first century. With the rapid development of social economy and more and more fierce competitive environment, teaching reform on stomatology is imperative nowadays. The existing curriculum of courses, teaching method, teaching medium, and mode of training must be improved and innovated based on cultivation of innovative talents with all-round development of moral, intellectual, physical, and aesthetic education. All the teaching should be student-centered rather than teacher-centered, with the purpose of enhancing the students' research ability, English ability, and clinical skills. PMID:19907864

  13. Innovative technologies of waste recycling with production of high performance products

    NASA Astrophysics Data System (ADS)

    Gilmanshin, R.; Ferenets, A. V.; Azimov, Yu I.; Galeeva, A. I.; Gilmanshina, S. I.

    2015-06-01

    The innovative ways of recycling wastes as a tool for sustainable development are presented in the article. The technology of the production of a composite material based on the rubber fiber composite waste tire industry is presented. The results of experimental use of the products in the real conditions. The comparative characteristics of the composite material rubber fiber composite are given. The production technology of construction and repairing materials on the basis of foamed glass is presented.

  14. High-power thermal management issues in space-based systems

    NASA Astrophysics Data System (ADS)

    Ponnappan, Rengasamy; Donovan, Brian; Chow, Louis

    2002-01-01

    There are several initiatives currently active or planned to enable future military directed energy, surveillance and communication missions. These missions require a very high level of electric power and sophisticated power conditioning systems. In almost all of these systems, there are unique thermal management requirements from electronics and payload operational considerations such as isothermality, high-heat flux, low-pressure drop, efficient fluid management and high heat transfer coefficient. The other space related requirements and issues affecting thermal management are microgravity, scalability based on weight, volume, reliability, safety, and cost considerations. In meeting these requirements for space systems, the thermal designer is faced with many technical challenges and issues. This paper describes some of these key issues and presents the need for initiating advanced developments in certain areas such as spray cooling, two-phase pumped loop and heat pump systems. In addition, it is emphasized to focus attention on extended microgravity effects of thermal systems. .

  15. Highly Thermally Conductive Composite Papers Prepared Based on the Thought of Bioinspired Engineering.

    PubMed

    Yao, Yimin; Zeng, Xiaoliang; Sun, Rong; Xu, Jian-Bin; Wong, Ching-Ping

    2016-06-22

    The rapid development of modern electronics and three-dimensional integration sets stringent requirements for efficient heat removal of thermal-management materials to ensure the long lifetime of the electronics. However, conventional polymer composites that have been used widely as thermal-management materials suffer from undesired thermal conductivity lower than 10 W m(-1) K(-1). In this work, we report a novel thermally conductive composite paper based on the thought of bioinspired engineering. The advantage of the bioinspired papers over conventional composites lies in that they possess a very high in-plane thermal conductivity up to 21.7 W m(-1) K(-1) along with good mechanical properties and high electrical insulation. We attribute the high thermal conductivity to the improved interfacial interaction between assembled components through the introduction of silver nanoparticles and the oriented structure based on boron nitride nanosheets and silicon carbide nanowires. This thought based on bioinspired engineering provides a creative opportunity for design and fabrication of novel thermally conductive materials, and this kind of composite paper has potential applications in powerful integrated microelectronics. PMID:27253387

  16. Innovative, High-Pressure, Cryogenic Control Valve: Short Face-to-Face, Reduced Cost

    NASA Technical Reports Server (NTRS)

    2002-01-01

    A control valve that can throttle high-pressure cryogenic fluid embodies several design features that distinguish it over conventional valves designed for similar applications. Field and design engineers worked together to create a valve that would simplify installation, trim changes, and maintenance, thus reducing overall cost. The seals and plug stem packing were designed to perform optimally in cryogenic temperature ranges. Unlike conventional high-pressure cryogenic valves, the trim size can be changed independent of the body. The design feature that provides flexibility for changing the trim is a split body. The body is divided into an upper and a lower section with the seat ring sandwiched in between. In order to maintain the plug stem packing at an acceptable sealing temperature during cryogenic service, heat-exchanging fins were added to the upper body section. The body is made of stainless steel. The seat ring is made of a nickel-based alloy having a coefficient of thermal expansion less than that of the body material. Consequently, when the interior of the valve is cooled cryogenically, the body surrounding the seat ring contracts more than the seat ring. This feature prevents external leakage at the body-seat joint. The seat ring has been machined to have small, raised-face sealing surfaces on both sides of the seal groove. These sealing surfaces concentrate the body bolt load over a small area, thereby preventing external leakage. The design of the body bolt circle is different from that of conventional highpressure control valves. Half of the bolts clamp the split body together from the top, and half from the bottom side. This bolt-circle design allows a short, clean flow path, which minimizes frictional flow losses. This bolt-circle design also makes it possible to shorten the face-toface length of the valve, which is 25.5 in. (65 cm). In contrast, a conventional, high-pressure control valve face-to-face dimension may be greater than 40 in. (>1 m

  17. Interfacial thermal resistance between high-density polyethylene (HDPE) and sapphire

    NASA Astrophysics Data System (ADS)

    Zheng, Kun; Zhu, Jie; Ma, Yong-Mei; Tang, Da-Wei; Wang, Fo-Song

    2014-10-01

    To improve the thermal conductivity of polymeric composites, the numerous interfacial thermal resistance (ITR) inside is usually considered as a bottle neck, but the direct measurement of the ITR is hardly reported. In this paper, a sandwich structure which consists of transducer/high density polyethylene (HDPE)/sapphire is prepared to study the interface characteristics. Then, the ITRs between HDPE and sapphire of two samples with different HDPE thickness values are measured by time-domain thermoreflectance (TDTR) method and the results are ~ 2 × 10-7 m2·K·W-1. Furthermore, a model is used to evaluate the importance of ITR for the thermal conductivity of composites. The model's analysis indicates that reducing the ITR is an effective way of improving the thermal conductivity of composites. These results will provide valuable guidance for the design and manufacture of polymer-based thermally conductive materials.

  18. High thermal conductivity in amorphous polymer blends by engineered interchain interactions

    NASA Astrophysics Data System (ADS)

    Kim, Gun-Ho; Lee, Dongwook; Shanker, Apoorv; Shao, Lei; Kwon, Min Sang; Gidley, David; Kim, Jinsang; Pipe, Kevin P.

    2015-03-01

    Thermal conductivity is an important property for polymers, as it often affects product reliability (for example, electronics packaging), functionality (for example, thermal interface materials) and/or manufacturing cost. However, polymer thermal conductivities primarily fall within a relatively narrow range (0.1-0.5 W m-1 K-1) and are largely unexplored. Here, we show that a blend of two polymers with high miscibility and appropriately chosen linker structure can yield a dense and homogeneously distributed thermal network. A sharp increase in cross-plane thermal conductivity is observed under these conditions, reaching over 1.5 W m-1 K-1 in typical spin-cast polymer blend films of nanoscale thickness, which is approximately an order of magnitude larger than that of other amorphous polymers.

  19. Phase transitions, prominent dielectric anomalies, and negative thermal expansion in three high thermally stable ammonium magnesium-formate frameworks.

    PubMed

    Shang, Ran; Xu, Guan-Cheng; Wang, Zhe-Ming; Gao, Song

    2014-01-20

    We present three Mg-formate frameworks, incorporating three different ammoniums: [NH4][Mg(HCOO)3] (1), [CH3CH2NH3][Mg(HCOO)3] (2) and [NH3(CH2)4NH3][Mg2(HCOO)6] (3). They display structural phase transitions accompanied by prominent dielectric anomalies and anisotropic and negative thermal expansion. The temperature-dependent structures, covering the whole temperature region in which the phase transitions occur, reveal detailed structural changes, and structure-property relationships are established. Compound 1 is a chiral Mg-formate framework with the NH4(+) cations located in the channels. Above 255 K, the NH4(+) cation vibrates quickly between two positions of shallow energy minima. Below 255 K, the cations undergo two steps of freezing of their vibrations, caused by the different inner profiles of the channels, producing non-compensated antipolarization. These lead to significant negative thermal expansion and a relaxor-like dielectric response. In perovskite 2, the orthorhombic phase below 374 K possesses ordered CH3CH2NH3(+) cations in the cubic cavities of the Mg-formate framework. Above 374 K, the structure becomes trigonal, with trigonally disordered cations, and above 426 K, another phase transition occurs and the cation changes to a two-fold disordered state. The two transitions are accompanied by prominent dielectric anomalies and negative and positive thermal expansion, contributing to the large regulation of the framework coupled the order-disorder transition of CH3CH2NH3(+). For niccolite 3, the gradually enhanced flipping movement of the middle ethylene of [NH3(CH2)4NH3](2+) in the elongated framework cavity finally leads to the phase transition with a critical temperature of 412 K, and the trigonally disordered cations and relevant framework change, providing the basis for the very strong dielectric dispersion, high dielectric constant (comparable to inorganic oxides), and large negative thermal expansion. The spontaneous polarizations

  20. Advantages of a Vertical High-Resolution Distributed-Temperature-Sensing System Used to Evaluate the Thermal Behavior of Green Roofs

    NASA Astrophysics Data System (ADS)

    Hausner, M. B.; Suarez, F. I.; Cousiño, J. A.; Victorero, F.; Bonilla, C. A.; Gironas, J. A.; Vera, S.; Bustamante, W.; Rojas, V.; Leiva, E.; Pasten, P.

    2015-12-01

    Technological innovations used for sustainable urban development, green roofs offer a range of benefits, including reduced heat island effect, rooftop runoff, roof surface temperatures, energy consumption, and noise levels inside buildings, as well as increased urban biodiversity. Green roofs feature layered construction, with the most important layers being the vegetation and the substrate layers located above the traditional roof. These layers provide both insulation and warm season cooling by latent heat flux, reducing the thermal load to the building. To understand and improve the processes driving this thermal energy reduction, it is important to observe the thermal dynamics of a green roof at the appropriate spatial and temporal scales. Traditionally, to observe the thermal behavior of green roofs, a series of thermocouples have been installed at discrete depths within the layers of the roof. Here, we present a vertical high-resolution distributed-temperature-sensing (DTS) system installed in different green roof modules of the Laboratory of Vegetated Infrastructure for Buildings (LIVE -its acronym in Spanish) of the Pontifical Catholic University of Chile. This DTS system allows near-continuous measurement of the thermal profile at spatial and temporal resolutions of approximately 1 cm and 30 s, respectively. In this investigation, the temperature observations from the DTS system are compared with the measurements of a series of thermocouples installed in the green roofs. This comparison makes it possible to assess the value of thermal observations at better spatial and temporal resolutions. We show that the errors associated with lower resolution observations (i.e., from the thermocouples) are propagated in the calculations of the heat fluxes through the different layers of the green roof. Our results highlight the value of having a vertical high-resolution DTS system to observe the thermal dynamics in green roofs.

  1. Thermal Behavior of High-Speed Helical Gear Trains Investigated

    NASA Technical Reports Server (NTRS)

    Handschuh, Robert F.

    2003-01-01

    High-speed and heavily loaded gearing are commonplace in the rotorcraft systems employed in helicopter and tiltrotor transmissions. The components are expected to deliver high power from the gas turbine engines to the high-torque, low-speed rotor, reducing the shaft rotational speed in the range of 25:1 to 100:1. These components are designed for high power-to-weight ratios, thus the components are fabricated as light as possible with the best materials and processing to transmit the required torque and carry the resultant loads without compromising the reliability of the drive system. This is a difficult task that is meticulously analyzed and thoroughly tested experimentally prior to being applied on a new or redesigned aircraft.

  2. Aromatic poly(arylene ether urea) with high dipole moment for high thermal stability and high energy density capacitors

    NASA Astrophysics Data System (ADS)

    Cheng, Zhaoxi; Lin, Minren; Wu, Shan; Thakur, Yash; Zhou, Yue; Jeong, Dae-Yong; Shen, Qundong; Zhang, Q. M.

    2015-05-01

    Developing dielectric polymers with higher dielectric constant without sacrificing loss and thermal stability is of great importance for next generation of high energy density capacitors. We show here that by replacing the CH2 group in the aromatic polyurea (ArPU) with the polar ether group, thus raising the dipole moment of the molecular unit, poly(arylene ether urea) (PEEU) shows an increased dielectric constant of 4.7, compared with 4.2 of ArPU. Moreover, PEEU maintains the low dielectric loss and is thermally stable up to 250 °C. As a result, the polymer delivers 13 J/cm3 discharged energy density at room temperature and 9 J/cm3 at 120 °C. The high quality films perform well in terms of both breakdown strength (at 700 MV/m at room temperature) and leakage current from room temperature to elevated temperature. At 120 °C, the breakdown strength is 600 MV/m and the conductivity is 1.58 × 10-14 S/cm measured under 100 MV/m.

  3. High-precision thermal strain measurements using surface-mounted fiber Bragg grating sensors

    NASA Astrophysics Data System (ADS)

    Mueller, Uwe C.; Both, Jan; Roths, Johannes; Baier, Horst

    2010-03-01

    Thermal strain measurements by fiber Bragg grating (FBG) sensors mounted onto different host materials are demonstrated for low coefficients of thermal expansion (CTE). Such low CTEs are typically found in carbon fiber reinforced plastics (CFRP). This work has application potential for FBG sensor networks in the highprecision control of thermal deformations in structures or in curing monitoring. For this purpose, a thermal error model of the FBG sensor, which accounts for the thermo-optic coefficient and the thermal expansion of the FBG, was characterized experimentally. The error-model characterization method is based on reference measurements of FBGs bonded to ZERODUR ceramics. Using this error model, thermal strain can be measured by surface-mounted FBGs on any given host structure using an external temperature reference and the FBG's wavelength shift. This method is demonstrated successfully for unidirectional layers of CFRP with a CTE of -0.4 . 10-6 1/K in fiber direction and for steel (316 Ti), which is commonly used in cryogenic applications. Measurements are performed for temperatures from 100K to 320K and the results are verified by high-precision dilatometer measurements. Accuracy limits of the FBG-based thermal strain measurements are discussed, as well as the minimization of errors induced by the FBG's structural interface. Further, the reduction of errors in the adhesive bonding is discussed. This work expands the understanding of the separation of thermal and mechanical effects in the signals obtained by FBGs.

  4. Evaluation of high temperature superconductive thermal bridges for space borne cryogenic detectors

    NASA Technical Reports Server (NTRS)

    Scott, Elaine P.

    1996-01-01

    Infrared sensor satellites are used to monitor the conditions in the earth's upper atmosphere. In these systems, the electronic links connecting the cryogenically cooled infrared detectors to the significantly warmer amplification electronics act as thermal bridges and, consequently, the mission lifetimes of the satellites are limited due to cryogenic evaporation. High-temperature superconductor (HTS) materials have been proposed by researchers at the National Aeronautics and Space Administration Langley's Research Center (NASA-LaRC) as an alternative to the currently used manganin wires for electrical connection. The potential for using HTS films as thermal bridges has provided the motivation for the design and the analysis of a spaceflight experiment to evaluate the performance of this superconductive technology in the space environment. The initial efforts were focused on the preliminary design of the experimental system which allows for the quantitative comparison of superconductive leads with manganin leads, and on the thermal conduction modeling of the proposed system. Most of the HTS materials were indicated to be potential replacements for the manganin wires. In the continuation of this multi-year research, the objectives of this study were to evaluate the sources of heat transfer on the thermal bridges that have been neglected in the preliminary conductive model and then to develop a methodology for the estimation of the thermal conductivities of the HTS thermal bridges in space. The Joule heating created by the electrical current through the manganin wires was incorporated as a volumetric heat source into the manganin conductive model. The radiative heat source on the HTS thermal bridges was determined by performing a separate radiant interchange analysis within a high-T(sub c) superconductor housing area. Both heat sources indicated no significant contribution on the cryogenic heat load, which validates the results obtained in the preliminary conduction

  5. Determination of Creep Behavior of Thermal Barrier Coatings Under Laser Imposed High Thermal and Stress Gradient Conditions

    NASA Technical Reports Server (NTRS)

    Zhu, Dongming; Miller, Robert A.

    1999-01-01

    A laser sintering/creep technique has been established to determine the creep behavior of thermal barrier coatings under steady-state high heat flux conditions. For a plasma sprayed zirconia-8 wt. % yttria coating, a significant primary creep strain and a low apparent creep activation energy were observed. Possible creep mechanisms involved include stress induced mechanical sliding and temperature and stress enhanced cation diffusion through the splat and grain boundaries. The elastic modulus evolution, stress response, and total accumulated creep strain variation across the ceramic coating are simulated using a finite difference approach. The modeled creep response is consistent with experimental observations.

  6. Development of High Fidelity, Fuel-Like Thermal Simulators for Non-Nuclear Testing

    SciTech Connect

    Bragg-Sitton, Shannon M.; Dickens, Ricky; Adams, Mike; Davis, Joe; Kapernick, Richard

    2007-01-30

    Non-nuclear testing can be a valuable tool in the development of a space nuclear power or propulsion system. In a non-nuclear test bed, electric heaters are used to simulate the heat from nuclear fuel. Work at the NASA Marshall Space Flight Center seeks to develop high fidelity thermal simulators that not only match the static power profile that would be observed in an operating, fueled nuclear reactor, but also match the dynamic fuel pin performance during feasible transients. Comparison between the fuel pins and thermal simulators is made at the outer fuel clad surface, which corresponds to the outer sheath surface in the thermal simulator. The thermal simulators that are currently being developed are designed to meet the geometric and power requirements of a proposed surface power reactor design, accommodate testing of various axial power profiles, and incorporate imbedded instrumentation. Static and dynamic fuel pin performances for a proposed reactor design have been determined using SINDA/FLUINT thermal analysis software, and initial comparison has been made between the expected nuclear performance and the performance of conceptual thermal simulator designs. Through a series of iterative analysis, a conceptual high fidelity design will be developed, followed by engineering design, fabrication, and testing to validate the overall design process. Although the resulting thermal simulator will be designed for a specific reactor concept, establishing this rigorous design process will assist in streamlining the thermal simulator development for other reactor concepts. This paper presents the current status of high fidelity thermal simulator design relative to a SNAP derivative reactor design that could be applied for Lunar surface power.

  7. Magnetic and thermal properties of high Tc superconductors

    SciTech Connect

    Lee, Wonchoon.

    1990-09-21

    Measurements of the normal state magnetic susceptibility {chi}(T) of YBa{sub 2}Cu{sub 3}O{sub 7}, Bi{sub 1.8}Pb{sub 0.2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}}, and Bi{sub 2{minus}x}Pb{sub x}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10+{delta}} (x = 0.2 and 0.25) were carried out. All {chi}(T) data show negative curvature below {approximately}2{Tc}. The data for YBa{sub 2}Cu{sub 3}O{sub 7} are in excellent agreement with a new calculation of the superconducting fluctuation diamagnetism. From the analysis, we infer s-wave pairing and microscopic parameters are obtained. For {chi}(T) of YBa{sub 2}Cu{sub 3}O{sub 7}, part of the negative curvature is inferred to arise from the normal state background. We find a strong temperature dependent anisotropy {delta}{chi} {equivalent to} {chi}{sub c} {minus} {chi}{sub ab} and estimate the normal state spin contributions to {chi}(T). The heat capacity C(T) of YBa{sub 2}Cu{sub 3}O{sub 7} is reported for 0.4 K < T < 400 K in zero and 70 kG magnetic fields. In addition to the feature associated with the onset of the superconductivity at {Tc}, two anomalies in C(T) were observed near 74 K and 330 K, with another possible anomaly near 102 K; the temperatures at which they occur correlate with anomalies in {chi}(T) and ultransonic measurements. The occurrence of the anomaly at {approx equal} 330 K is found to be sample-dependent. The influences of a magnetic field and the thermal and/or magnetic field treatment history dependence of a pellet sample on C(T), the entropy and the influence of superconducting fluctuations on C(T) near {Tc}, and the possible source of the observed intrinsic nonzero {gamma}(0) at low T are discussed.

  8. New high spin isomers obtained in thermal fission

    SciTech Connect

    Fogelberg, B.; Mach, H.; Gausemel, H.; Omtvedt, J. P.; Mezilev, K. A.

    1998-10-26

    The product nuclei following fission often are initially highly excited and have high angular momenta. As a consequence, there is a substantial probability for the population of isomeric yrast traps in the vicinity of closed shells. The excitation energies and decay properties of such isomers give important formation regarding the shell structure and interaction energies. Recent experiments at the OSIRIS mass separator have revealed a number of isomers in the {sup 132}Sn region having angular momenta exceeding 10 units. A brief presentation is given of some experimental results and their interpretation.

  9. Thermal diffusivity of Swedish meatballs, pork meat pate and tomato puree during high pressure processing

    NASA Astrophysics Data System (ADS)

    Landfeld, Ales; Strohalm, Jan; Stancl, Jaromir; Houska, Milan

    2011-06-01

    Our study is directed at the effects of high pressure on the thermal diffusivity of selected food samples - a fresh meat formulation for Swedish meatballs, pork meat pate and tomato puree. Preheated food samples were placed in a copper cell and tested at nominal pressures of 400 and 500 MPa in a high pressure chamber. The thermal diffusivity was estimated from the recorded time course of temperatures (at the center of the food sample, at the wall of the copper cell, and 7.5 mm from the wall) during the high pressure holding time. Measured time-temperature profiles were compared with predictions using the finite-element model to solve the problem of uneven heat conduction in an infinite, solid, linear cylinder using the linear temperature dependence of apparent thermal conductivity. Optimal parameters of the linear temperature dependence of apparent thermal conductivity were evaluated by comparing measured temperatures and temperatures calculated from the model. To minimize differences between measured and calculated temperatures, at the center of the sample, the Marquardt-Levenberg optimization method was used. The thermal diffusivity values of all food samples were linearly correlated with temperature for two levels of pressure. Thermal diffusivity values increased with increased pressure and temperature. † This paper was presented at the XLVIIIth European High Pressure Research Group (EHPRG 48) Meeting at Uppsala (Sweden), 25-29 July 2010.

  10. X-ray Crystallographic Structure of Thermophilic Rhodopsin: IMPLICATIONS FOR HIGH THERMAL STABILITY AND OPTOGENETIC FUNCTION.

    PubMed

    Tsukamoto, Takashi; Mizutani, Kenji; Hasegawa, Taisuke; Takahashi, Megumi; Honda, Naoya; Hashimoto, Naoki; Shimono, Kazumi; Yamashita, Keitaro; Yamamoto, Masaki; Miyauchi, Seiji; Takagi, Shin; Hayashi, Shigehiko; Murata, Takeshi; Sudo, Yuki

    2016-06-01

    Thermophilic rhodopsin (TR) is a photoreceptor protein with an extremely high thermal stability and the first characterized light-driven electrogenic proton pump derived from the extreme thermophile Thermus thermophilus JL-18. In this study, we confirmed its high thermal stability compared with other microbial rhodopsins and also report the potential availability of TR for optogenetics as a light-induced neural silencer. The x-ray crystal structure of TR revealed that its overall structure is quite similar to that of xanthorhodopsin, including the presence of a putative binding site for a carotenoid antenna; but several distinct structural characteristics of TR, including a decreased surface charge and a larger number of hydrophobic residues and aromatic-aromatic interactions, were also clarified. Based on the crystal structure, the structural changes of TR upon thermal stimulation were investigated by molecular dynamics simulations. The simulations revealed the presence of a thermally induced structural substate in which an increase of hydrophobic interactions in the extracellular domain, the movement of extracellular domains, the formation of a hydrogen bond, and the tilting of transmembrane helices were observed. From the computational and mutational analysis, we propose that an extracellular LPGG motif between helices F and G plays an important role in the thermal stability, acting as a "thermal sensor." These findings will be valuable for understanding retinal proteins with regard to high protein stability and high optogenetic performance. PMID:27129243

  11. Science, Technology, and Innovation Policy: High-tech Industry Growth in China

    NASA Astrophysics Data System (ADS)

    Parker, Rachel

    This dissertation is an analysis of the ways in which Chinese central government science, technology, and innovation (STI) policies are shaping the country's development trajectory in the 21st century. The study investigates the relationship between STI policy and development in China in order to understand whether the two are in congruence as the Country continues the rapid growth trajectory it has experienced over recent years. This work uses nanotechnology as a case study to analyze whether efforts by the Chinese central government have been successful in elevating the research and development output of the emerging economy. 72 semi-structured interviews were conducted in China, Hong Kong, Taiwan, and the United States and additional data was collected and analyzed in order to understand the impact of state-led nanotechnology policy. China (among other emerging economies) is convinced that it must strengthen its capabilities across the entire value chain rather than focusing on its manufacturing sector alone. The country's overarching goal is to become an "innovation-oriented" society by the year 2020. The importance placed on innovation in China's approach to growth and development---as compared with the strategy of the U.S. through its National Nanotechnology Initiative is of central concern to this study. In China, as in the U.S., nanotechnology is being funded largely through government sources, with much of the funding being directed toward basic research despite the fact that both countries have placed significant hope on the commercialization potential of the emerging technology area. This project examines the role played by government policies in fostering advances in nanotechnology from multiple locations along the nanotechnology value chain in looking at the promises and pitfalls of state-led economic development.

  12. High-temperature molten salt thermal energy storage systems for solar applications

    NASA Technical Reports Server (NTRS)

    Petri, R. J.; Claar, T. D.

    1980-01-01

    Alkali and alkaline earth carbonate latent-heat storage salts, metallic containment materials, and thermal conductivity enhancement materials were investigated to satisfy the high temperature (704 to 871 C) thermal energy storage requirements of advanced solar-thermal power generation concepts are described. Properties of the following six salts selected for compatibility studies are given: three pure carbonates, K2CO3, Li2CO3 and Na2CO3; two eutectic mixtures, BaCO3/Na2CO3 and K2CO3/NaCO3, and one off-eutectic mixture of Na2CO3/K2CO3.

  13. High-Tc thermal bridges for space-borne cryogenic infrared detectors

    NASA Technical Reports Server (NTRS)

    Wise, S. A.; Buckley, J. D.; Nolt, I.; Hooker, M. W.; Haertling, G. H.; Selim, R.; Caton, R.; Buoncristiani, A. M.

    1993-01-01

    The potential for using high-temperature superconductive elements, screen-printed onto ceramic substrates, as thermal bridges to replace the currently employed manganin wires is studied at NASA-LaRC. Substrate selection is considered to be the most critical parameter in device production. Due to the glass-like thermal behavior of yttria-stabilized-zirconia (YSZ) and fused silica substrates, these materials are found to reduce the heat load significantly. The estimated thermal savings for superconductive leads printed onto YSZ or fused silica substrates range from 6 to 14 percent.

  14. Highly Anisotropic Thermal Expansion in Molecular Films of Dicarboxylic Fatty Acids

    SciTech Connect

    Tamam L.; Ocko B.; Kraack, H.; Sloutskin, E.; Deutsch, M.

    2012-05-25

    Angstrom-resolution x-ray measurements reveal the existence of two-dimensional (2D) crystalline order in molecularly thin films of surface-parallel-oriented fatty diacid molecules supported on a liquid mercury surface. The thermal expansion coefficients along the two unit cell vectors are found to differ 17-fold. The high anisotropy of the 2D thermal expansion and the crystalline coherence length are traced to the different bonding in the two directions: van der Waals normal to, and covalent plus hydrogen bonding along the molecular backbone axis. Similarities with, and differences from, negative thermal expansion materials are discussed.

  15. Expanded polytetrafluoroethylene reinforced polyvinylidenefluoride-hexafluoropropylene separator with high thermal stability for lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Xiong, Ming; Tang, Haolin; Wang, Yadong; Lin, Yu; Sun, Meiling; Yin, Zhuangfei; Pan, Mu

    2013-11-01

    PVDF-HFP/ePTFE composite separator with high thermal stability and low thermal shrinkage characteristic has been developed. The PVDF-HFP acts to absorb the electrolyte and shutdown at elevated temperature. The thermally stable ePTFE matrix is adopted to improve the mechanical strength and sustain the insulation after the shutdown. This novel separator presents good ion conductivity (up to 1.29 mS cm-1) and has a low thermal shrinkage of 8.8% at 162 °C. The composite separator shutdown at 162 °C and keep its integrity before 329 °C. Cells based on the composite separator show excellent capacities at high rate discharge and stable cycling performance.

  16. On high-continuity transfinite element formulations for linear-nonlinear transient thermal problems

    NASA Technical Reports Server (NTRS)

    Tamma, Kumar K.; Railkar, Sudhir B.

    1987-01-01

    This paper describes recent developments in the applicability of a hybrid transfinite element methodology with emphasis on high-continuity formulations for linear/nonlinear transient thermal problems. The proposed concepts furnish accurate temperature distributions and temperature gradients making use of a relatively smaller number of degrees of freedom; and the methodology is applicable to linear/nonlinear thermal problems. Characteristic features of the formulations are described in technical detail as the proposed hybrid approach combines the major advantages and modeling features of high-continuity thermal finite elements in conjunction with transform methods and classical Galerkin schemes. Several numerical test problems are evaluated and the results obtained validate the proposed concepts for linear/nonlinear thermal problems.

  17. The thermal properties of Martian surface materials at high lattitudes: Possible evidence for permafrost

    NASA Technical Reports Server (NTRS)

    Paige, D. A.; Kieffer, H. H.

    1987-01-01

    Evidence is presented from analysis of Viking thermal mapping results that suggests a transition to high thermal inertial material at a depth of approx. 12 cm at +75 deg latitude. This was interpreted as reflecting the transition from ice poor soil to hard frozen permafrost. It was pointed out that such a transition would be expected on the basis of theoretical models of hard frozen permafrost distribution. Although permafrost is not the only plausible martian surface material with high thermal inertia, polar thermal mapping may turn out to be a powerful tool for determining the distribution of permafrost deposits and understanding their behavior. At this point, the circumstantial case for permafrost deposits in the north pole region of Mars is very strong.

  18. Modeling of thermal processes in high pressure liquid chromatography. I. Low pressure onset of thermal heterogeneity

    SciTech Connect

    Kaczmarski, Krzysztof; Guiochon, Georges A

    2009-01-01

    Heat due to viscous friction is generated in chromatographic columns. When these columns are operated at high flow rates, under a high inlet pressure, this heat causes the formation of significant axial and radial temperature gradients. Consequently, these columns become heterogeneous and several physico-chemical parameters, including the retention factors and the parameters of the mass transfer kinetics of analytes are no longer constant along and across the columns. A robust modeling of the distributions of the physico-chemical parameters allows the analysis of the impact of the heat generated on column performance. We developed a new model of the coupled heat and mass transfers in chromatographic columns, calculated the axial and radial temperature distributions in a column, and derived the distributions of the viscosity and the density of the mobile phase, hence of the axial and radial mobile phase velocities. The coupling of the mass and the heat balances in chromatographic columns was used to model the migration of a compound band under linear conditions. This process yielded the elution band profiles of analytes, hence the column efficiency under two different sets of experimental conditions: (1) the column is operated under natural convection conditions; (2) the column is dipped in a stream of thermostated fluid. The calculated results show that the column efficiency is remarkably lower in the second than in the first case. The inconvenience of maintaining constant the temperature of the column wall (case 2) is that retention factors and mobile phase velocities vary much more significantly across the column than if the column is kept under natural convection conditions (case 1).

  19. High temperature thermal energy storage in moving sand

    NASA Technical Reports Server (NTRS)

    Turner, R. H.; Awaya, H. I.

    1978-01-01

    Several high-temperature (to 500 C) heat-storage systems using sand as the storage medium are described. The advantages of sand as a storage medium include low cost for sand, widespread availability, non-toxicity, non-degradation characteristics, easy containment, and safety. The systems considered include: stationary sand with closely spaced tubes throughout the volume, the use of a fluidized bed, use of conveyor belt transporter, and the use of a blower rapid transport system. For a stationary sand bed, very close spacing of heat transfer tubes throughout the volume is required, manifesting as high power related system cost. The suggestion of moving sand past or around pipes is intended to reduce the power related costs at the penalty of added system complexity. Preliminary system cost estimates are offered. These rough calculations indicate that mobile sand heat storage systems cost less than the stationary sand approach.

  20. High efficiency thermal to electric energy conversion using selective emitters and spectrally tuned solar cells

    NASA Technical Reports Server (NTRS)

    Chubb, Donald L.; Flood, Dennis J.; Lowe, Roland A.

    1992-01-01

    Thermophotovoltaic (TPV) systems are attractive possibilities for direct thermal-to-electric energy conversion, but have typically required the use of black body radiators operating at high temperatures. Recent advances in both the understanding and performance of solid rare-earth oxide selective emitters make possible the use of TPV at temperatures as low as 1500 K. Depending on the nature of parasitic losses, overall thermal-to-electric conversion efficiencies greater than 20 percent are feasible.

  1. Thermal analysis of Yucca Mountain commercial high-level waste packages

    SciTech Connect

    Altenhofen, M.K.; Eslinger, P.W.

    1992-10-01

    The thermal performance of commercial high-level waste packages was evaluated on a preliminary basis for the candidate Yucca Mountain repository site. The purpose of this study is to provide an estimate for waste package component temperatures as a function of isolation time in tuff. Several recommendations are made concerning the additional information and modeling needed to evaluate the thermal performance of the Yucca Mountain repository system.

  2. High Thermal Conductivity NARloy-Z-Diamond Composite Combustion Chamber Liner For Advanced Rocket Engines

    NASA Technical Reports Server (NTRS)

    Bhat, Biliyar N.; Ellis, David; Singh, Jogender

    2014-01-01

    Advanced high thermal conductivity materials research conducted at NASA Marshall Space Flight Center (MSFC) with state of the art combustion chamber liner material NARloy-Z showed that its thermal conductivity can be increased significantly by adding diamond particles and sintering it at high temperatures. For instance, NARloy-Z containing 40 vol. percent diamond particles, sintered at 975C to full density by using the Field assisted Sintering Technology (FAST) showed 69 percent higher thermal conductivity than baseline NARloy-Z. Furthermore, NARloy-Z-40vol. percent D is 30 percent lighter than NARloy-Z and hence the density normalized thermal conductivity is 140 percent better. These attributes will improve the performance and life of the advanced rocket engines significantly. By one estimate, increased thermal conductivity will directly translate into increased turbopump power up to 2X and increased chamber pressure for improved thrust and ISP, resulting in an expected 20 percent improvement in engine performance. Follow on research is now being conducted to demonstrate the benefits of this high thermal conductivity NARloy-Z-D composite for combustion chamber liner applications in advanced rocket engines. The work consists of a) Optimizing the chemistry and heat treatment for NARloy-Z-D composite, b) Developing design properties (thermal and mechanical) for the optimized NARloy-Z-D, c) Fabrication of net shape subscale combustion chamber liner, and d) Hot fire testing of the liner for performance. FAST is used for consolidating and sintering NARlo-Z-D. The subscale cylindrical liner with built in channels for coolant flow is also fabricated near net shape using the FAST process. The liner will be assembled into a test rig and hot fire tested in the MSFC test facility to determine performance. This paper describes the development of this novel high thermal conductivity NARloy-Z-D composite material, and the advanced net shape technology to fabricate the combustion

  3. A high efficiency thermal ionization source adapted to mass spectrometers

    SciTech Connect

    Chamberlin, E.P.; Olivares, J.A.

    1994-07-01

    The high-temperature ion source used on the isotope separators at Los Alamos is unsuitable for mass spectrometry use, because it is bulky, expensive to fabricate, requires careful assembly, etc. A modified source was designed, using the following objectives: reduced number of parts and complexity, one-piece crucible, modular construction, little or no water cooling. The source is shown mounted on a quadrupole mass spectrometer; the ion beam is matched into a sector-type mass spectrometer.

  4. Power efficiency for very high temperature solar thermal cavity receivers

    DOEpatents

    McDougal, Allan R.; Hale, Robert R.

    1984-01-01

    This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this arrangement, a high percentage of the solar power input is retained in the cavity; thus, high internal temperatures are attained.

  5. Earthquake effects in thermal neutron variations at the high-altitude station of Northern

    NASA Astrophysics Data System (ADS)

    Antonova, Valentina; Chubenko, Alexandr; Kryukov, Sergey; Lutsenko, Vadim

    2016-04-01

    Results of study of thermal neutron variations under various space and geophysical conditions on the basis of measurements on stationary installations with high statistical accuracy are presented. Installations are located close to the fault of the earth's crust at the high-altitude station of cosmic rays (3340 m above sea level, 43.02 N, 76.56 E, 20 km from Almaty) in the mountains of Northern Tien-Shan. Responses of the most effective gelio- and geophysical events (variations of atmospheric pressure, coronal mass ejections, earthquakes) has consistently considered in the variations of the thermal neutron flux and compared with variations of high-energy neutrons (standard monitor 18NM64) of galactic origin during these periods. Coefficients of correlation were calculated between data of thermal neutron detectors and data of the neutron monitor, recording the intensity of high-energy particles. High correlation coefficients and similarity of responses to changes of space and geophysical conditions are obtained, that confirms the conclusion of the genetic connection of thermal neutrons with high-energy neutrons of galactic origin and suggests same sources of disturbances in the absence of seismic activity. Observations and analysis of experimental data during the activation of seismic activity in the vicinity of Almaty showed the frequent breakdown of the correlation between the intensity of thermal and high-energy neutrons and the absence of similarity between variations during these periods. We suppose that the additional thermal neutron flux of the lithospheric origin appears under these conditions. Method of separating of thermal neutron flux variations of the lithospheric origin from neutrons variations generated in the atmosphere by subtracting the normalized data is proposed, taking into account the conclusion that variations caused with the atmospheric and interplanetary origins in thermal neutron detectors are similar to variations of high-energy neutrons

  6. Development of a high-voltage, high-power thermal battery

    SciTech Connect

    Guidotti, R.A.; Scharrer, G.L.; Binasiewicz, E.; Reinhardt, F.W.

    1998-04-01

    The power requirements for an inverter application were specified to be 500 V at 360 A, or 180 kW per each of six 1-s pulses delivered over a period of 10 minutes. Conventional high-power sources (e.g., flywheels) could not meet these requirements and the use of a thermal battery was considered. The final design involved four, 125-cell, 50-kW modules connected in series. A module using the LiSi/CoS{sub 2} couple and all-Li (LiCI-LiBr-LiF minimum-melting) electrolyte was successfully developed and tested. A power level of over 40 kW was delivered during a 0.5-s pulse. This translates into a specific power level of over 9 kW/kg or 19.2 kW/L delivered from a module. The module was still able to deliver over 30 kW during a 1-s pulse after 10 minutes.

  7. High Thermal Conductivity Polymer Matrix Composites (PMC) for Advanced Space Radiators

    NASA Technical Reports Server (NTRS)

    Shin, E. Eugene; Bowman, Cheryl; Beach, Duane

    2007-01-01

    High temperature polymer matrix composites (PMC) reinforced with high thermal conductivity (approx. 1000 W/mK) pitch-based carbon fibers are evaluated for a facesheet/fin structure of large space radiator systems. Significant weight reductions along with improved thermal performance, structural integrity and space durability toward its metallic counterparts were envisioned. Candidate commercial resin systems including Cyanate Esters, BMIs, and polyimide were selected based on thermal capabilities and processability. PMC laminates were designed to match the thermal expansion coefficient of various metal heat pipes or tubes. Large, but thin composite panels were successfully fabricated after optimizing cure conditions. Space durability of PMC with potential degradation mechanisms was assessed by simulated thermal aging tests in high vacuum, 1-3 x 10(exp -6) torr, at three temperatures, 227 C, 277 C, and 316 C for up to one year. Nanocomposites with vapor-grown carbon nano-fibers and exfoliated graphite flakes were attempted to improve thermal conductivity (TC) and microcracking resistance. Good quality nanocomposites were fabricated and evaluated for TC and durability including radiation resistance. TC was measured in both in-plan and thru-the-thickness directions, and the effects of microcracks on TC are also being evaluated. This paper will discuss the systematic experimental approaches, various performance-durability evaluations, and current subcomponent design and fabrication/manufacturing efforts.

  8. KENIS: a high-performance thermal imager developed using the OSPREY IR detector

    NASA Astrophysics Data System (ADS)

    Goss, Tristan M.; Baker, Ian M.

    2000-07-01

    `KENIS', a complete, high performance, compact and lightweight thermal imager, is built around the `OSPREY' infrared detector from BAE systems Infrared Ltd. The `OSPREY' detector uses a 384 X 288 element CMT array with a 20 micrometers pixel size and cooled to 120 K. The relatively small pixel size results in very compact cryogenics and optics, and the relatively high operating temperature provides fast start-up time, low power consumption and long operating life. Requiring single input supply voltage and consuming less than 30 watts of power, the thermal imager generates both analogue and digital format outputs. The `KENIS' lens assembly features a near diffraction limited dual field-of-view optical system that has been designed to be athermalized and switches between fields in less than one second. The `OSPREY' detector produces near background limited performance with few defects and has special, pixel level circuitry to eliminate crosstalk and blooming effects. This, together with signal processing based on an effective two-point fixed pattern noise correction algorithm, results in high quality imagery and a thermal imager that is suitable for most traditional thermal imaging applications. This paper describes the rationale used in the development of the `KENIS' thermal imager, and highlights the potential performance benefits to the user's system, primarily gained by selecting the `OSPREY' infra-red detector within the core of the thermal imager.

  9. Calorimeter probes for measuring high thermal flux. [in arc jets

    NASA Technical Reports Server (NTRS)

    Russell, L. D.

    1979-01-01

    Expendable, slug-type calorimeter probes were developed for measuring high heat-flux levels of 10-30 kW/sq cm in electric-arc jet facilities. The probes were constructed with thin tungsten caps mounted on Teflon bodies. The temperature of the back surface of the tungsten cap is measured, and its time rate of change gives the steady-state absorbed heat flux as the calorimeter probe heats to destruction when inserted into the arc jet. Design, construction, test, and performance data are presented.

  10. Modelling of segmented high-performance thermoelectric generators with effects of thermal radiation, electrical and thermal contact resistances

    NASA Astrophysics Data System (ADS)

    Ouyang, Zhongliang; Li, Dawen

    2016-04-01

    In this study, segmented thermoelectric generators (TEGs) have been simulated with various state-of-the-art TE materials spanning a wide temperature range, from 300 K up to 1000 K. The results reveal that by combining the current best p-type TE materials, BiSbTe, MgAgSb, K-doped PbTeS and SnSe with the strongest n-type TE materials, Cu-Doped BiTeSe, AgPbSbTe and SiGe to build segmented legs, TE modules could achieve efficiencies of up to 17.0% and 20.9% at ΔT = 500 K and ΔT = 700 K, respectively, and a high output power densities of over 2.1 Watt cm‑2 at the temperature difference of 700 K. Moreover, we demonstrate that successful segmentation requires a smooth change of compatibility factor s from one end of the TEG leg to the other, even if s values of two ends differ by more than a factor of 2. The influence of the thermal radiation, electrical and thermal contact effects have also been studied. Although considered potentially detrimental to the TEG performance, these effects, if well-regulated, do not prevent segmentation of the current best TE materials from being a prospective way to construct high performance TEGs with greatly enhanced efficiency and output power density.

  11. Modelling of segmented high-performance thermoelectric generators with effects of thermal radiation, electrical and thermal contact resistances

    PubMed Central

    Ouyang, Zhongliang; Li, Dawen

    2016-01-01

    In this study, segmented thermoelectric generators (TEGs) have been simulated with various state-of-the-art TE materials spanning a wide temperature range, from 300 K up to 1000 K. The results reveal that by combining the current best p-type TE materials, BiSbTe, MgAgSb, K-doped PbTeS and SnSe with the strongest n-type TE materials, Cu-Doped BiTeSe, AgPbSbTe and SiGe to build segmented legs, TE modules could achieve efficiencies of up to 17.0% and 20.9% at ΔT = 500 K and ΔT = 700 K, respectively, and a high output power densities of over 2.1 Watt cm−2 at the temperature difference of 700 K. Moreover, we demonstrate that successful segmentation requires a smooth change of compatibility factor s from one end of the TEG leg to the other, even if s values of two ends differ by more than a factor of 2. The influence of the thermal radiation, electrical and thermal contact effects have also been studied. Although considered potentially detrimental to the TEG performance, these effects, if well-regulated, do not prevent segmentation of the current best TE materials from being a prospective way to construct high performance TEGs with greatly enhanced efficiency and output power density. PMID:27052592

  12. Sound velocity of high-strength polymer with negative thermal expansion coefficient

    NASA Astrophysics Data System (ADS)

    Nomura, R.; Ueno, M.; Okuda, Y.; Burmistrov, S.; Yamanaka, A.

    2003-05-01

    Sound velocities of fiber reinforced plastics (FRPs) were measured along the fiber axis at temperatures between 360 and 77 K. We used two kinds of the high-strength crystalline polymer fibers, polyethylene (Dyneema) and polybenzobisoxazole (Zylon), which have negative thermal expansion coefficients. They also have high thermal conductivities and high resistances for flash over voltage, and are expected as new materials for coil bobbins or spacers at cryogenic temperatures. They have very large sound velocities of about 9000 (m/s) at 77 K, which are 4.5 times larger than that of the ordinary polyethylene fiber.

  13. Influences on shallow ground temperatures in high flux thermal systems

    NASA Astrophysics Data System (ADS)

    Lubenow, Brady L.; Fairley, Jerry P.; Lindsey, Cary R.; Larson, Peter B.

    2016-09-01

    Ground temperature measurements are a useful indication of subsurface processes and heat flux, particularly in volcanic and hydrothermal systems, but obtaining reliable data at sufficient resolution can be difficult. Investigators commonly use temperature measurements at 1 m depths to minimize land surface boundary impacts; however, these measurements are time-consuming and invasive, limiting the number of points that can be surveyed. Alternatively, shallow ground temperature measurements (≤ 25 cm depth) offer a rapid and minimally-invasive way to collect a large number of observations in a target area. Although this method has obvious appeal, changing atmospheric conditions can impact the observed temperatures, and thus may reasonably be expected to influence interpretations arising from the data. Here we examine the impact of precipitation and changing air temperature on shallow ground temperatures in the vicinity of a group of hot springs located in Yellowstone National Park, Wyoming. We find that the mean, the range, and the skewness of the observed temperatures were decreased by changing atmospheric conditions; however, the model variogram representing data taken after several days of moderate precipitation adequately described the spatial correlation of data taken before precipitation. We therefore conclude that the ability to differentiate between high- and low-flux areas may be somewhat reduced by moderate precipitation and changing atmospheric conditions, but that interpretations made on the basis of characteristics of the inferred variograms are likely to be robust to such perturbations in high heat flux environments.

  14. Ni-based nanoalloys: Towards thermally stable highly magnetic materials

    NASA Astrophysics Data System (ADS)

    Palagin, Dennis; Doye, Jonathan P. K.

    2014-12-01

    Molecular dynamics simulations and density functional theory calculations have been used to demonstrate the possibility of preserving high spin states of the magnetic cores within Ni-based core-shell bimetallic nanoalloys over a wide range of temperatures. We show that, unlike the case of Ni-Al clusters, Ni-Ag clusters preserve high spin states (up to 8 μB in case of Ni13Ag32 cluster) due to small hybridization between the electronic levels of two species. Intriguingly, such clusters are also able to maintain geometrical and electronic integrity of their cores at temperatures up to 1000 K (e.g., for Ni7Ag27 cluster). Furthermore, we also show the possibility of creating ordered arrays of such magnetic clusters on a suitable support by soft-landing pre-formed clusters on the surface, without introducing much disturbance in geometrical and electronic structure of the cluster. We illustrate this approach with the example of Ni13Ag38 clusters adsorbed on the Si(111)-(7×7) surface, which, having two distinctive halves to the unit cell, acts as a selective template for cluster deposition.

  15. Thermal management of high power space based systems

    NASA Technical Reports Server (NTRS)

    Hwangbo, H.; Mcever, W. S.

    1985-01-01

    Conventional techniques of using a portion of the spacecraft skin for radiation of waste heat will be inadequate for high powered payloads (50 to 100 kWe) due to the lack of sufficient area. A Shuttle type system using a pumped single phase fluid loop could be scaled up to higher power but this type of system would require excessive pump power and weight. A pumped two-phase heat transfer loop has a much lower pumping requirement due to the higher latent heat of vaporization of the fluid in comparison to the sensible heat it can absorb through a temperature change. Concepts for an evaporator and a condenser for a pumped two-phase system are described. The condenser uses capillary grooves and a separate pumped condensate return line to achieve high heat transfer coefficients and stable operation due to the separation of the vapor and liquid flows. The cold plate evaporator uses wicks to contain the liquid and transport it to the heated surface. It can also function as a condenser for warming components. Control concepts for the cold plate are discussed. Concepts for deployment or erection of large space radiators are also considered.

  16. Ni-based nanoalloys: Towards thermally stable highly magnetic materials

    SciTech Connect

    Palagin, Dennis Doye, Jonathan P. K.

    2014-12-07

    Molecular dynamics simulations and density functional theory calculations have been used to demonstrate the possibility of preserving high spin states of the magnetic cores within Ni-based core-shell bimetallic nanoalloys over a wide range of temperatures. We show that, unlike the case of Ni–Al clusters, Ni–Ag clusters preserve high spin states (up to 8 μ{sub B} in case of Ni{sub 13}Ag{sub 32} cluster) due to small hybridization between the electronic levels of two species. Intriguingly, such clusters are also able to maintain geometrical and electronic integrity of their cores at temperatures up to 1000 K (e.g., for Ni{sub 7}Ag{sub 27} cluster). Furthermore, we also show the possibility of creating ordered arrays of such magnetic clusters on a suitable support by soft-landing pre-formed clusters on the surface, without introducing much disturbance in geometrical and electronic structure of the cluster. We illustrate this approach with the example of Ni{sub 13}Ag{sub 38} clusters adsorbed on the Si(111)–(7×7) surface, which, having two distinctive halves to the unit cell, acts as a selective template for cluster deposition.

  17. Spontaneous high piezoelectricity in poly(vinylidene fluoride) nanoribbons produced by iterative thermal size reduction technique.

    PubMed

    Kanik, Mehmet; Aktas, Ozan; Sen, Huseyin Sener; Durgun, Engin; Bayindir, Mehmet

    2014-09-23

    We produced kilometer-long, endlessly parallel, spontaneously piezoelectric and thermally stable poly(vinylidene fluoride) (PVDF) micro- and nanoribbons using iterative size reduction technique based on thermal fiber drawing. Because of high stress and temperature used in thermal drawing process, we obtained spontaneously polar γ phase PVDF micro- and nanoribbons without electrical poling process. On the basis of X-ray diffraction (XRD) analysis, we observed that PVDF micro- and nanoribbons are thermally stable and conserve the polar γ phase even after being exposed to heat treatment above the melting point of PVDF. Phase transition mechanism is investigated and explained using ab initio calculations. We measured an average effective piezoelectric constant as -58.5 pm/V from a single PVDF nanoribbon using a piezo evaluation system along with an atomic force microscope. PVDF nanoribbons are promising structures for constructing devices such as highly efficient energy generators, large area pressure sensors, artificial muscle and skin, due to the unique geometry and extended lengths, high polar phase content, high thermal stability and high piezoelectric coefficient. We demonstrated two proof of principle devices for energy harvesting and sensing applications with a 60 V open circuit peak voltage and 10 μA peak short-circuit current output. PMID:25133594

  18. Development of Thermally Stable and Highly Fluorescent IR Dyes

    NASA Technical Reports Server (NTRS)

    Bu, Xiu R.

    2004-01-01

    Fluorophores are the core component in various optical applications such as sensors and probes. Fluorphores with low-energy or long wavelength emission, in particular, in NIR region, possess advantages of low interference and high sensitivity. In this study, we has explored several classes of imidazole-based compounds for NIR fluorescent properties and concluded: (1) thiazole-based imidazole compounds are fluorescent; (2) emission energy is tunable by additional donor groups; (3) they also possess impressive two- photon absorption properties; and (4) fluorescence emission can be induced by two- photon input. This report summarizes (1) synthesis of new series of fluorophore; (2) impact of electron-withdrawing groups on fluorescent property; (3) unique property of two-photon absorption; and (4) on-going development.

  19. Developing Multilayer Thin Film Strain Sensors With High Thermal Stability

    NASA Technical Reports Server (NTRS)

    Wrbanek, John D.; Fralick, Gustave C.; Gonzalez, Jose M., III

    2006-01-01

    A multilayer thin film strain sensor for large temperature range use is under development using a reactively-sputtered process. The sensor is capable of being fabricated in fine line widths utilizing the sacrificial-layer lift-off process that is used for micro-fabricated noble-metal sensors. Tantalum nitride films were optimized using reactive sputtering with an unbalanced magnetron source. A first approximation model of multilayer resistance and temperature coefficient of resistance was used to set the film thicknesses in the multilayer film sensor. Two multifunctional sensors were fabricated using multilayered films of tantalum nitride and palladium chromium, and tested for low temperature resistivity, TCR and strain response. The low temperature coefficient of resistance of the films will result in improved stability in thin film sensors for low to high temperature use.

  20. Refractory porcelain enamel passive-thermal-control coating for high-temperature superalloys

    NASA Technical Reports Server (NTRS)

    Levin, H.; Auker, B. H.; Gardos, M. N.

    1973-01-01

    Study was conducted to match thermal expansion coefficients thereby preventing enamels from cracking. Report discusses various enamel coatings that are applied to two different high-temperature superalloys. Study may be of interest to manufacturers of chemical equipment, furnaces, and metal components intended for high-temperature applications.

  1. Preliminary Thermal Stress Analysis of a High-Pressure Cryogenic Storage Tank

    NASA Technical Reports Server (NTRS)

    Baker, J. Mark

    2003-01-01

    The thermal stresses on a cryogenic storage tank strongly affect the condition of the tank and its ability to withstand operational stresses. These thermal stresses also affect the growth of any surface damage that might occur in the tank walls. These stresses are particularly of concern during the initial cooldown period for a new tank placed into service, and during any subsequent thermal cycles. A preliminary thermal stress analysis of a high-pressure cryogenic storage tank was performed. Stresses during normal operation were determined, as well as the transient temperature distribution. An elastic analysis was used to determine the thermal stresses in the inner wall based on the temperature data. The results of this elastic analysis indicate that the inner wall of the storage tank will experience thermal stresses of approximately 145,000 psi (1000 MPa). This stress level is well above the room-temperature yield strength of 304L stainless steel, which is about 25,000 psi (170 MPa). For this preliminary analysis, several important factors have not yet been considered. These factors include increased strength of 304L stainless steel at cryogenic temperatures, plastic material behavior, and increased strength due to strain hardening. In order to more accurately determine the thermal stresses and their affect on the tank material, further investigation is required, particularly in the area of material properties and their relationship to stress.

  2. Advancement in thermal interface materials for future high-performance electronic applications. Part 1.

    SciTech Connect

    Jakaboski, Blake Elaine; Wong, Chung-Nin Channy; Huber, Dale L.; Rightley, Michael J.; Emerson, John Allen

    2006-02-01

    As electronic assemblies become more compact and increase in processing bandwidth, escalating thermal energy has become more difficult to manage. The major limitation has been nonmetallic joining using poor thermal interface materials (TIM). The interfacial, versus bulk, thermal conductivity of an adhesive is the major loss mechanism and normally accounts for an order magnitude loss in conductivity per equivalent thickness. The next generation TIM requires a sophisticated understanding of material and surface sciences, heat transport at submicron scales, and the manufacturing processes used in packaging of microelectronics and other target applications. Only when this relationship between bond line manufacturing processes, structure, and contact resistance is well-understood on a fundamental level will it be possible to advance the development of miniaturized microsystems. This report examines using thermal and squeeze-flow modeling as approaches to formulate TIMs incorporating nanoscience concepts. Understanding the thermal behavior of bond lines allows focus on the interfacial contact region. In addition, careful study of the thermal transport across these interfaces provides greatly augmented heat transfer paths and allows the formulation of very high resistance interfaces for total thermal isolation of circuits. For example, this will allow the integration of systems that exhibit multiple operational temperatures, such as cryogenically cooled detectors.

  3. Thermal response of large area high temperature superconducting YBaCuO infrared bolometers

    NASA Technical Reports Server (NTRS)

    Khalil, Ali E.

    1991-01-01

    Thermal analysis of large area high temperature superconducting infrared detector operating in the equilibrium mode (bolometer) was performed. An expression for the temperature coefficient beta = 1/R(dR/dT) in terms of the thermal conductance and the thermal time constant of the detector were derived. A superconducting transition edge bolometer is a thermistor consisting of a thin film superconducting YBaCuO evaporated into a suitable thermally isolated substrate. The operating temperature of the bolometer is maintained close to the midpoint of the superconducting transition region where the resistance R has a maximum dynamic range. A detector with a strip configuration was analyzed and an expression for the temperature rise (delta T) above the ambient due to a uniform illumination with a source of power density was calculated. An expression for the thermal responsibility depends upon the spatial modulation frequency and the angular frequency of the incoming radiation. The problem of the thermal cross talk between different detector elements was addressed. In the case of monolithic HTS detector array with a row of square elements of dimensions 2a and CCD or CID readout electronics the thermal spread function was derived for different spacing between elements.

  4. Hybrid Multifoil Aerogel Thermal Insulation

    NASA Technical Reports Server (NTRS)

    Sakamoto, Jeffrey; Paik, Jong-Ah; Jones, Steven; Nesmith, Bill

    2008-01-01

    This innovation blends the merits of multifoil insulation (MFI) with aerogel-based insulation to develop a highly versatile, ultra-low thermally conductive material called hybrid multifoil aerogel thermal insulation (HyMATI). The density of the opacified aerogel is 240 mg/cm3 and has thermal conductivity in the 20 mW/mK range in high vacuum and 25 mW/mK in 1 atmosphere of gas (such as argon) up to 800 C. It is stable up to 1,000 C. This is equal to commercially available high-temperature thermal insulation. The thermal conductivity of the aerogel is 36 percent lower compared to several commercially available insulations when tested in 1 atmosphere of argon gas up to 800 C.

  5. Sprayable Aerogel Bead Compositions With High Shear Flow Resistance and High Thermal Insulation Value

    NASA Technical Reports Server (NTRS)

    Ou, Danny; Trifu, Roxana; Caggiano, Gregory

    2013-01-01

    A sprayable aerogel insulation has been developed that has good mechanical integrity and lower thermal conductivity than incumbent polyurethane spray-on foam insulation, at similar or lower areal densities, to prevent insulation cracking and debonding in an effort to eliminate the generation of inflight debris. This new, lightweight aerogel under bead form can be used as insulation in various thermal management systems that require low mass and volume, such as cryogenic storage tanks, pipelines, space platforms, and launch vehicles.

  6. High fidelity modeling of thermal relaxation and dissociation of oxygen

    NASA Astrophysics Data System (ADS)

    Andrienko, Daniil A.; Boyd, Iain D.

    2015-11-01

    A master equation study of vibrational relaxation and dissociation of oxygen is conducted using state-specific O2-O transition rates, generated by extensive trajectory simulations. Both O2-O and O2-O2 collisions are concurrently simulated in the evolving nonequilibrium gas system under constant heat bath conditions. The forced harmonic oscillator model is incorporated to simulate the state-to-state relaxation of oxygen in O2-O2 collisions. The system of master equations is solved to simulate heating and cooling flows. The present study demonstrates the importance of atom-diatom collisions due to the extremely efficient energy randomization in the intermediate O3 complex. It is shown that the presence of atomic oxygen has a significant impact on vibrational relaxation time at temperatures observed in hypersonic flow. The population of highly-excited O2 vibrational states is affected by the amount of atomic oxygen when modeling the relaxation under constant heat bath conditions. A model of coupled state-to-state vibrational relaxation and dissociation of oxygen is also discussed.

  7. High fidelity modeling of thermal relaxation and dissociation of oxygen

    SciTech Connect

    Andrienko, Daniil A. Boyd, Iain D.

    2015-11-15

    A master equation study of vibrational relaxation and dissociation of oxygen is conducted using state-specific O{sub 2}–O transition rates, generated by extensive trajectory simulations. Both O{sub 2}–O and O{sub 2}–O{sub 2} collisions are concurrently simulated in the evolving nonequilibrium gas system under constant heat bath conditions. The forced harmonic oscillator model is incorporated to simulate the state-to-state relaxation of oxygen in O{sub 2}–O{sub 2} collisions. The system of master equations is solved to simulate heating and cooling flows. The present study demonstrates the importance of atom-diatom collisions due to the extremely efficient energy randomization in the intermediate O{sub 3} complex. It is shown that the presence of atomic oxygen has a significant impact on vibrational relaxation time at temperatures observed in hypersonic flow. The population of highly-excited O{sub 2} vibrational states is affected by the amount of atomic oxygen when modeling the relaxation under constant heat bath conditions. A model of coupled state-to-state vibrational relaxation and dissociation of oxygen is also discussed.

  8. Development of High Fidelity, Fuel-Like Thermal Simulators for Non-Nuclear Testing

    NASA Technical Reports Server (NTRS)

    Bragg-Sitton, S. M.; Farmer, J.; Dixon, D.; Kapernick, R.; Dickens, R.; Adams, M.

    2007-01-01

    Non-nuclear testing can be a valuable tool in development of a space nuclear power or propulsion system. In a non-nuclear test bed, electric heaters are used to simulate the heat from nuclear fuel. Work at the NASA Marshall Space Flight Center seeks to develop high fidelity thermal simulators that not only match the static power profile that would be observed in an operating, fueled nuclear reactor, but to also match the dynamic fuel pin performance during feasible transients. Comparison between the fuel pins and thermal simulators is made at the fuel clad surface, which corresponds to the sheath surface in the thermal simulator. Static and dynamic fuel pin performance was determined using SINDA-FLUINT analysis, and the performance of conceptual thermal simulator designs was compared to the expected nuclear performance. Through a series of iterative analysis, a conceptual high fidelity design will be developed, followed by engineering design, fabrication, and testing to validate the overall design process. Although the resulting thermal simulator will be designed for a specific reactor concept, establishing this rigorous design process will assist in streamlining the thermal simulator development for other reactor concepts.

  9. A thermal porosimetry method to estimate pore size distribution in highly porous insulating materials.

    PubMed

    Félix, V; Jannot, Y; Degiovanni, A

    2012-05-01

    Standard pore size determination methods such as mercury porosimetry, nitrogen sorption, microscopy, or x-ray tomography are not always applicable to highly porous, low density, and thus very fragile materials. For this kind of materials, a method based on thermal characterization is proposed. Indeed, the thermal conductivity of a highly porous and insulating medium is significantly dependent on the thermal conductivity of the interstitial gas that depends on both gas pressure and size of the considered pore (Knudsen effect). It is also possible to link the pore size with the thermal conductivity of the medium. Thermal conductivity measurements are realized on specimens placed in an enclosure where the air pressure is successively set to different values varying from 10(-1) to 10(5) Pa. Knowing the global porosity ratio, an effective thermal conductivity model for a two-phase air-solid material based on a combined serial-parallel model is established. Pore size distribution can be identified by minimizing the sum of the quadratic differences between measured values and modeled ones. The results of the estimation process are the volume fractions of the chosen ranges of pore size. In order to validate the method, measurements done on insulating materials are presented. The results are discussed and show that pore size distribution estimated by the proposed method is coherent. PMID:22667640

  10. A thermal porosimetry method to estimate pore size distribution in highly porous insulating materials

    NASA Astrophysics Data System (ADS)

    Félix, V.; Jannot, Y.; Degiovanni, A.

    2012-05-01

    Standard pore size determination methods such as mercury porosimetry, nitrogen sorption, microscopy, or x-ray tomography are not always applicable to highly porous, low density, and thus very fragile materials. For this kind of materials, a method based on thermal characterization is proposed. Indeed, the thermal conductivity of a highly porous and insulating medium is significantly dependent on the thermal conductivity of the interstitial gas that depends on both gas pressure and size of the considered pore (Knudsen effect). It is also possible to link the pore size with the thermal conductivity of the medium. Thermal conductivity measurements are realized on specimens placed in an enclosure where the air pressure is successively set to different values varying from 10-1 to 105 Pa. Knowing the global porosity ratio, an effective thermal conductivity model for a two-phase air-solid material based on a combined serial-parallel model is established. Pore size distribution can be identified by minimizing the sum of the quadratic differences between measured values and modeled ones. The results of the estimation process are the volume fractions of the chosen ranges of pore size. In order to validate the method, measurements done on insulating materials are presented. The results are discussed and show that pore size distribution estimated by the proposed method is coherent.

  11. A thermal porosimetry method to estimate pore size distribution in highly porous insulating materials

    SciTech Connect

    Felix, V.; Jannot, Y.; Degiovanni, A.

    2012-05-15

    Standard pore size determination methods such as mercury porosimetry, nitrogen sorption, microscopy, or x-ray tomography are not always applicable to highly porous, low density, and thus very fragile materials. For this kind of materials, a method based on thermal characterization is proposed. Indeed, the thermal conductivity of a highly porous and insulating medium is significantly dependent on the thermal conductivity of the interstitial gas that depends on both gas pressure and size of the considered pore (Knudsen effect). It is also possible to link the pore size with the thermal conductivity of the medium. Thermal conductivity measurements are realized on specimens placed in an enclosure where the air pressure is successively set to different values varying from 10{sup -1} to 10{sup 5} Pa. Knowing the global porosity ratio, an effective thermal conductivity model for a two-phase air-solid material based on a combined serial-parallel model is established. Pore size distribution can be identified by minimizing the sum of the quadratic differences between measured values and modeled ones. The results of the estimation process are the volume fractions of the chosen ranges of pore size. In order to validate the method, measurements done on insulating materials are presented. The results are discussed and show that pore size distribution estimated by the proposed method is coherent.

  12. Characterization of rock thermal conductivity by high-resolution optical scanning

    USGS Publications Warehouse

    Popov, Y.A.; Pribnow, D.F.C.; Sass, J.H.; Williams, C.F.; Burkhardt, H.

    1999-01-01

    We compared thress laboratory methods for thermal conductivity measurements: divided-bar, line-source and optical scanning. These methods are widely used in geothermal and petrophysical studies, particularly as applied to research on cores from deep scientific boreholes. The relatively new optical scanning method has recently been perfected and applied to geophysical problems. A comparison among these methods for determining the thermal conductivity tensor for anisotropic rocks is based on a representative collection of 80 crystalline rock samples from the KTB continental deep borehole (Germany). Despite substantial thermal inhomogeneity of rock thermal conductivity (up to 40-50% variation) and high anisotropy (with ratios of principal values attaining 2 and more), the results of measurements agree very well among the different methods. The discrepancy for measurements along the foliation is negligible (<1%). The component of thermal conductivity normal to the foliation reveals somewhat larger differences (3-4%). Optical scanning allowed us to characterize the thermal inhomogeneity of rocks and to identify a three-dimensional anisotropy in thermal conductivity of some gneiss samples. The merits of optical scanning include minor random errors (1.6%), the ability to record the variation of thermal conductivity along the sample, the ability to sample deeply using a slow scanning rate, freedom from constraints for sample size and shape, and quality of mechanical treatment of the sample surface, a contactless mode of measurement, high speed of operation, and the ability to measure on a cylindrical sample surface. More traditional methods remain superior for characterizing bulk conductivity at elevated temperature.Three laboratory methods including divided-bar, line-source and optical scanning are widely applied in geothermal and petrophysical studies. In this study, these three methods were compared for determining the thermal conductivity tensor for anisotropic rocks

  13. High-thermal-stability white light-emitting-diodes employing broadband glass phosphor

    NASA Astrophysics Data System (ADS)

    Cheng, Wood-Hi; Chen, Li-Yin; Cheng, Wei-Chih

    2014-09-01

    We report the high-thermal-stability white light-emitting-diodes (WLEDs) employing broadband glass phosphors. The broadband glass phosphors were fabricated by sintering the mixture of multiple phosphors and SiO2-based glass (SiO2-Na2O-Al2O3-CaO) at 680°. Y3Al5O12:Ce 3+ (YAG), Lu3Al5O12:Ce3+ (LuAG), and CaAlSiN3: Eu2+ (Nitride) phosphor crystals were chosen as the yellow, green, and red emitters of the glass phosphors, respectively. The results showed that the broadband phosphors exhibited high quantum-yield of 54% and color-rendering index (CRI) of 90. The lumen degradation, chromaticity shift, and transmittance loss in the broadband glass-based WLEDs under thermal aging temperature at 150, 250, 350 and 450° were also presented and compared with those of silicone-based WLEDs under thermal aging temperature at 150 and 250°. The results demonstrated that the broadband glass-based WLEDs exhibited better thermal stability in lumen degradation, chromaticity shift, and transmittance loss than the silicone-based WLEDs. The excellent thermal stability of the broadband glass-based WLEDs with high CRI is essentially beneficial to the applications for next-generation solid-state indoor lighting, especially in the area where high power and absolute reliability are required.

  14. A New Guarded Hot Plate Designed for Thermal-Conductivity Measurements at High Temperature

    NASA Astrophysics Data System (ADS)

    Scoarnec, V.; Hameury, J.; Hay, B.

    2015-03-01

    The Laboratoire National de Métrologie et d'Essais has developed a new guarded hot-plate apparatus operating from to in the thermal-conductivity range from to . This facility has been specifically designed for measuring medium thermal-conductivity materials at high temperature on square specimens (100 mm side), which are easier to machine than circular ones. The hot plate and cold plates are similar with a metering section independent from the guard ring. The specimens are laterally isolated by an air gap of 4 mm width and can be instrumented by temperature sensors in order to reduce effects of thermal contact resistances between the specimens and the heating plates. Measurements have been performed on certified reference materials and on "calibrated" materials. Relative deviations between thermal conductivities measured and reference values are less than 5 % in the operating range.

  15. A steady-state high-temperature method for measuring thermal conductivity of refractory materials

    NASA Astrophysics Data System (ADS)

    Manzolaro, M.; Corradetti, S.; Andrighetto, A.; Ferrari, L.

    2013-05-01

    A new methodology and an instrumental setup for the thermal conductivity estimation of isotropic bulk graphite and different carbides at high temperatures are presented. The method proposed in this work is based on the direct measurement of temperature and emissivity on the top surface of a sample disc of known dimensions. Temperatures measured under steady-state thermal equilibrium are then used to estimate the thermal conductivity of the sample by making use of the inverse parameter estimation technique. Thermal conductivity values obtained in this way are then compared to the material data sheets and values found in literature. The reported work has been developed within the Research and Development framework of the SPES (Selective Production of Exotic Species) project at INFN-LNL (Istituto Nazionale di Fisica Nucleare - Laboratori Nazionali di Legnaro).

  16. Fabrication and thermal effects of highly transparent polycrystalline Nd:YAG ceramics

    NASA Astrophysics Data System (ADS)

    Fu, Yuelong; Li, Jiang; Liu, Yang; Wang, Zhe; Liu, Lei; Zhao, Hong; Pan, Yubai

    2015-11-01

    Highly transparent polycrystalline 2.0 at.% Nd:YAG ceramics were fabricated by a solid-state reactive sintering method using commercial α-Al2O3, Y2O3 and Nd2O3 powders as starting materials. The in-line transmittances of the Nd:YAG ceramics vacuum sintered at 1750 °C for 50 h with the thickness of 5.8 mm are 83.9% at 1064 nm and 82.5% at 400 nm. The thermal effects in the Nd:YAG ceramics were mainly investigated in detail. It is found that the thermal focal length decreases with the increase of pump power. The experimental results of thermal focal lengths are in accordance with the theoretical calculations. The observed depolarized beam patterns and depolarization phenomena illustrate the detailed change of thermally induced birefringence in Nd:YAG ceramics. The depolarization shows a obvious nonlinear change tendency at low pump power.

  17. In-operando high-speed tomography of lithium-ion batteries during thermal runaway.

    PubMed

    Finegan, Donal P; Scheel, Mario; Robinson, James B; Tjaden, Bernhard; Hunt, Ian; Mason, Thomas J; Millichamp, Jason; Di Michiel, Marco; Offer, Gregory J; Hinds, Gareth; Brett, Dan J L; Shearing, Paul R

    2015-01-01

    Prevention and mitigation of thermal runaway presents one of the greatest challenges for the safe operation of lithium-ion batteries. Here, we demonstrate for the first time the application of high-speed synchrotron X-ray computed tomography and radiography, in conjunction with thermal imaging, to track the evolution of internal structural damage and thermal behaviour during initiation and propagation of thermal runaway in lithium-ion batteries. This diagnostic approach is applied to commercial lithium-ion batteries (LG 18650 NMC cells), yielding insights into key degradation modes including gas-induced delamination, electrode layer collapse and propagation of structural degradation. It is envisaged that the use of these techniques will lead to major improvements in the design of Li-ion batteries and their safety features. PMID:25919582

  18. Thermal lensing characterization of a high-radiance 946nm planar waveguide laser

    NASA Astrophysics Data System (ADS)

    Ng, S. P.; Mackenzie, J. I.

    2012-06-01

    We present the characterization of the in-plane thermal lens in a quasi-four-level Nd:YAG planar waveguide (PW) laser configured for high-radiance operation with an external stable-cavity. Our approach utilises the measurement of the laser's output irradiance distribution at the near- and far-field positions concurrently in order to obtain the "real time" beam propagation parameter and thus beam quality factor, M2. Coupled with the knowledge of the intra-cavity-thermal-lens- dependent beam sizes at an intra-cavity beam waist, the power dependent effective thermal lens focal length was characterized. A thermal lens focal length of >450 mm was obtained at all incident pump powers up to the maximum level of 87 W. This characterization enabled the build of a 29 W 946 nm PW laser with a record output radiance of 4.3 TWm-2sr-1.

  19. Application Of High Conductivity Carbon Fibre Materials For Flexible Thermal Straps

    NASA Astrophysics Data System (ADS)

    Usinger, R.; Delouard, P.; Miller, G.

    2012-07-01

    In a recently completed ESA GSTP project RUAG Space successfully demonstrated that thermal straps made from high conductivity carbon fibres can provide larger heat transport capability than conventional metallic designs at reduced mass. To prove the feasibility of the concept, breadboard models of flexible carbon fibre straps were manufactured and tested in laboratory environment. The end- to-end conductance measured in a thermal vacuum test correlated well with the prediction made with a simple thermal mathematical model. Mechanical tests were performed on the straps to check whether and to which extent the thermal performance is degraded by mechanical loads. The results from these tests indicate that the selected strap design is surprisingly tolerant against mechanical damage.

  20. In-operando high-speed tomography of lithium-ion batteries during thermal runaway

    NASA Astrophysics Data System (ADS)

    Finegan, Donal P.; Scheel, Mario; Robinson, James B.; Tjaden, Bernhard; Hunt, Ian; Mason, Thomas J.; Millichamp, Jason; di Michiel, Marco; Offer, Gregory J.; Hinds, Gareth; Brett, Dan J. L.; Shearing, Paul R.

    2015-04-01

    Prevention and mitigation of thermal runaway presents one of the greatest challenges for the safe operation of lithium-ion batteries. Here, we demonstrate for the first time the application of high-speed synchrotron X-ray computed tomography and radiography, in conjunction with thermal imaging, to track the evolution of internal structural damage and thermal behaviour during initiation and propagation of thermal runaway in lithium-ion batteries. This diagnostic approach is applied to commercial lithium-ion batteries (LG 18650 NMC cells), yielding insights into key degradation modes including gas-induced delamination, electrode layer collapse and propagation of structural degradation. It is envisaged that the use of these techniques will lead to major improvements in the design of Li-ion batteries and their safety features.