Lateral boundary conditions for the Klein-Gordon-Fock equation
NASA Astrophysics Data System (ADS)
Tulenov, Kanat S.; Dauitbek, Dostilek
2016-08-01
In this paper we consider an initial-boundary value problem for the Klein-Gordon-Fock equation. We prove the uniqueness of the solution and find lateral boundary conditions for the Klein-Gordon-Fock equation.
Klein-Gordon Equation in Hydrodynamical Form
Wong, Cheuk-Yin
2010-01-01
We follow and modify the Feshbach-Villars formalism by separating the Klein-Gordon equation into two coupled time-dependent Schroedinger equations for the particle and antiparticle wave functions with positive probability densities. We find that the equation of motion for the probability densities is in the form of relativistic hydrodynamics where various forces have their physical and classical counterparts. An additional element is the presence of the quantum stress tensor that depends on the derivatives of the amplitude of the wave function.
Perturbative Solutions of the Einstein Klein-Gordon Equations
NASA Astrophysics Data System (ADS)
Puliti, Gianluca; Jennings, Mara; Mamo, Vincent; Vuille, Chris
2005-11-01
As the Klein-Gordon equation is important in quantum theory and describes spin-0 particles, it is of interest to discover the nature of the gravity field such particles would be expected to create. In this paper, we solve the static, massive Einstein-Klein-Gordon (EKG) equations in perturbation, and compare the results with a similar calculation developed for the Einstein-Proca system. Subsequently, we study the massless static Klein-Gordon equation, and compare the result to the Reissner-Nordstrom metric.
Variational principles for eigenvalues of the Klein-Gordon equation
Langer, Matthias; Tretter, Christiane
2006-10-15
In this paper variational principles for eigenvalues of an abstract model of the Klein-Gordon equation with electromagnetic potential are established. They are used to characterize and estimate eigenvalues in cases where the essential spectrum has a gap around 0, even in the presence of complex eigenvalues. As a consequence, a comparison between eigenvalues of the Klein-Gordon equation in R{sup d} and eigenvalues of certain Schroedinger operators is obtained. The results are illustrated on examples including the Klein-Gordon equation with Coulomb and square-well potential.
Electromagnetic Klein-Gordon and Dirac Equations in Scale Relativity
NASA Astrophysics Data System (ADS)
Célérier, Marie-Noëlle; Nottale, Laurent
We present a new step in the foundation of quantum field theory with the tools of scale relativity. Previously, quantum motion equations (Schrödinger, Klein-Gordon, Dirac, Pauli) have been derived as geodesic equations written with a quantum-covariant derivative operator. Then, the nature of gauge transformations, of gauge fields and of conserved charges have been given a geometric meaning in terms of a scale-covariant derivative tool. Finally, the electromagnetic Klein-Gordon equation has been recovered with a covariant derivative constructed by combining the quantum-covariant velocity operator and the scale-covariant derivative. We show here that if one tries to derive the electromagnetic Dirac equation from the Klein-Gordon one as for the free particle motion, i.e. as a square root of the time part of the Klein-Gordon operator, one obtains an additional term which is the relativistic analog of the spin-magnetic field coupling term of the Pauli equation. However, if one first applies the quantum covariance, then implements the scale covariance through the scale-covariant derivative, one obtains the electromagnetic Dirac equation in its usual form. This method can also be applied successfully to the derivation of the electromagnetic Klein-Gordon equation. This suggests it rests on more profound roots of the theory, since it encompasses naturally the spin-charge coupling.
Quadratic nonlinear Klein-Gordon equation in one dimension
NASA Astrophysics Data System (ADS)
Hayashi, Nakao; Naumkin, Pavel I.
2012-10-01
We study the initial value problem for the quadratic nonlinear Klein-Gordon equation vtt + v - vxx = λv2, t ∈ R, x ∈ R, with initial conditions v(0, x) = v0(x), vt(0, x) = v1(x), x ∈ R, where v0 and v1 are real-valued functions, λ ∈ R. Using the method of normal forms of Shatah ["Normal forms and quadratic nonlinear Klein-Gordon equations," Commun. Pure Appl. Math. 38, 685-696 (1985)], we obtain a sharp asymptotic behavior of small solutions without the condition of a compact support on the initial data, which was assumed in the previous work of J.-M. Delort ["Existence globale et comportement asymptotique pour l'équation de Klein-Gordon quasi-linéaire á données petites en dimension 1," Ann. Sci. Ec. Normale Super. 34(4), 1-61 (2001)].
Klein-Gordon oscillator in Kaluza-Klein theory
NASA Astrophysics Data System (ADS)
Carvalho, Josevi; Carvalho, Alexandre M. de M.; Cavalcante, Everton; Furtado, Claudio
2016-07-01
In this contribution we study the Klein-Gordon oscillator on the curved background within the Kaluza-Klein theory. The problem of the interaction between particles coupled harmonically with topological defects in Kaluza-Klein theory is studied. We consider a series of topological defects, then we treat the Klein-Gordon oscillator coupled to this background, and we find the energy levels and corresponding eigenfunctions in these cases. We show that the energy levels depend on the global parameters characterizing these spacetimes. We also investigate a quantum particle described by the Klein-Gordon oscillator interacting with a cosmic dislocation in Som-Raychaudhuri spacetime in the presence of homogeneous magnetic field in a Kaluza-Klein theory. In this case, the energy spectrum is determined, and we observe that these energy levels represent themselves as the sum of the terms related with Aharonov-Bohm flux and of the parameter associated to the rotation of the spacetime.
Classification of integrable discrete Klein-Gordon models
NASA Astrophysics Data System (ADS)
Habibullin, Ismagil T.; Gudkova, Elena V.
2011-04-01
The Lie algebraic integrability test is applied to the problem of classification of integrable Klein-Gordon-type equations on quad graphs. The list of equations passing the test is presented, containing several well-known integrable models. A new integrable example is found; its higher symmetry is presented.
Fractional Klein-Gordon Equations and Related Stochastic Processes
NASA Astrophysics Data System (ADS)
Garra, Roberto; Orsingher, Enzo; Polito, Federico
2014-03-01
This paper presents finite-velocity random motions driven by fractional Klein-Gordon equations of order α in (0,1] . A key tool in the analysis is played by the McBride's theory which converts fractional hyper-Bessel operators into Erdélyi-Kober integral operators. Special attention is payed to the fractional telegraph process whose space-dependent distribution solves a non-homogeneous fractional Klein-Gordon equation. The distribution of the fractional telegraph process for α = 1 coincides with that of the classical telegraph process and its driving equation converts into the homogeneous Klein-Gordon equation. Fractional planar random motions at finite velocity are also investigated, the corresponding distributions obtained as well as the explicit form of the governing equations. Fractionality is reflected into the underlying random motion because in each time interval a binomial number of deviations B(n,α ) (with uniformly-distributed orientation) are considered. The parameter n of B(n,α ) is itself a random variable with fractional Poisson distribution, so that fractionality acts as a subsampling of the changes of direction. Finally the behaviour of each coordinate of the planar motion is examined and the corresponding densities obtained. Extensions to N -dimensional fractional random flights are envisaged as well as the fractional counterpart of the Euler-Poisson-Darboux equation to which our theory applies.
Extended Klein-Gordon action, gravity and nonrelativistic fluid
Hassaiene, Mokhtar
2006-03-15
We consider a scalar field action for which the Lagrangian density is a power of the massless Klein-Gordon Lagrangian. The coupling of gravity to this matter action is considered. In this case, we show the existence of nontrivial scalar field configurations with vanishing energy-momentum tensor on any static, spherically symmetric vacuum solutions of the Einstein equations. These configurations in spite of being coupled to gravity do not affect the curvature of space-time. The properties of this particular matter action are also analyzed. For a particular value of the exponent, the extended Klein-Gordon action is shown to exhibit a conformal invariance without requiring the introduction of a nonminimal coupling. We also establish a correspondence between this action and a nonrelativistic isentropic fluid in one fewer dimension. This fluid can be identified with the (generalized) Chaplygin gas for a particular value of the power. It is also shown that the nonrelativistic fluid admits, apart from the Galileo symmetry, an additional symmetry whose action is a rescaling of the time.
Numerical computation of travelling breathers in Klein Gordon chains
NASA Astrophysics Data System (ADS)
Sire, Yannick; James, Guillaume
2005-05-01
We numerically study the existence of travelling breathers in Klein-Gordon chains, which consist of one-dimensional networks of nonlinear oscillators in an anharmonic on-site potential, linearly coupled to their nearest neighbors. Travelling breathers are spatially localized solutions having the property of being exactly translated by p sites along the chain after a fixed propagation time T (these solutions generalize the concept of solitary waves for which p=1). In the case of even on-site potentials, the existence of small amplitude travelling breathers superposed on a small oscillatory tail has been proved recently [G. James, Y. Sire, Travelling breathers with exponentially small tails in a chain of nonlinear oscillators, Commun. Math. Phys., 2005, in press (available online at http://www.springerlink.com)], the tail being exponentially small with respect to the central oscillation size. In this paper, we compute these solutions numerically and continue them into the large amplitude regime for different types of even potentials. We find that Klein-Gordon chains can support highly localized travelling breather solutions superposed on an oscillatory tail. We provide examples where the tail can be made very small and is difficult to detect at the scale of central oscillations. In addition, we numerically observe the existence of these solutions in the case of non-even potentials.
Dissipative effects in nonlinear Klein-Gordon dynamics
NASA Astrophysics Data System (ADS)
Plastino, A. R.; Tsallis, C.
2016-03-01
We consider dissipation in a recently proposed nonlinear Klein-Gordon dynamics that admits exact time-dependent solutions of the power-law form e_qi(kx-wt) , involving the q-exponential function naturally arising within the nonextensive thermostatistics (e_qz \\equiv [1+(1-q)z]1/(1-q) , with e_1^z=ez ). These basic solutions behave like free particles, complying, for all values of q, with the de Broglie-Einstein relations p=\\hbar k , E=\\hbar ω and satisfying a dispersion law corresponding to the relativistic energy-momentum relation E2 = c^2p2 + m^2c4 . The dissipative effects explored here are described by an evolution equation that can be regarded as a nonlinear generalization of the celebrated telegraph equation, unifying within one single theoretical framework the nonlinear Klein-Gordon equation, a nonlinear Schrödinger equation, and the power-law diffusion (porous-media) equation. The associated dynamics exhibits physically appealing traveling solutions of the q-plane wave form with a complex frequency ω and a q-Gaussian square modulus profile.
Emergence of Compact Structures in a Klein-Gordon Model
Rosenau, Philip; Kashdan, Eugene
2010-01-22
The Klein-Gordon model (KG) squarephi=P{sup '}(|phi|)(phi/|phi|) is Lorenz invariant and has a finite wave speed, yet its localized modes, whether Q balls or vortices, suffer from the same fundamental flaw as all other solitons--they extend indefinitely. Using the KG model as a case study, we demonstrate that appending the site potential, P{sub a}(|phi|), with a subquadratic part P(|{phi}|)=b{sup 2}|{phi}|{sup 1+{delta}}+P{sub a}(|{phi}|), 0<={delta}<1, induces particlelike modes with strictly compact support. These modes are robust and shorten in the direction of motion. Their interactions, which occur only on contact, are studied in two and three dimensions and are shown to span the whole range from being nearly elastic to plastic.
Spacetimes with a separable Klein-Gordon equation in higher dimensions
NASA Astrophysics Data System (ADS)
Kolář, Ivan; Krtouš, Pavel
2016-01-01
We study spacetimes that lead to a separable Klein-Gordon equation in a general number of dimensions. We introduce an ansatz for the metric in higher dimensions motivated by analogical work by Carter in four dimensions and find solutions of the Klein-Gordon equation. For such a metric we solve the Einstein equations and regain the Kerr-NUT-(A)dS spacetime as one of our results. Other solutions lead to the Einstein-Kähler metric of a Euclidean signature. Next we investigate a warped geometry of two Klein-Gordon separable spaces with a properly chosen warped factor. We show that the resulting metric leads also to a separable Klein-Gordon equation and we find the corresponding solutions. Finally, we solve the Einstein equations for the warped geometry and obtain new solutions.
Lie group symmetries and Riemann function of Klein-Gordon-Fock equation with central symmetry
NASA Astrophysics Data System (ADS)
Kochetov, Bogdan A.
2014-06-01
In the present paper Lie symmetry group method is applied to find new exact invariant solutions for Klein-Gordon-Fock equation with central symmetry. The found invariant solutions are important for testing finite-difference computational schemes of various boundary value problems of Klein-Gordon-Fock equation with central symmetry. The classical admitted symmetries of the equation are found. The infinitesimal symmetries of the equation are used to find the Riemann function constructively.
The Klein-Gordon equation of a rotating charged hairy black hole in (2 + 1) dimensions
NASA Astrophysics Data System (ADS)
Pourhassan, B.
2016-03-01
In this paper, we consider the Klein-Gordon equation in a 3D charged rotating hairy black hole background to study behavior of a massive scalar field. In the general case, we find periodic-like behavior for the scalar field which may vanish at the black hole horizon or far from the black hole horizon. For the special cases of non-rotating or near horizon approximation, we find radial solution of Klein-Gordon equation in terms of hypergeometric and Kummer functions. Also for the case of uncharged black hole, we find numerical solution of the Klein-Gordon equation as periodic function which may enhance out of the black hole or vanish at horizon. We find allowed boundary conditions which may yield to the identical bosons described by scalar field.
Wigner function for Klein-Gordon oscillator in commutative and noncommutative spaces
NASA Astrophysics Data System (ADS)
Hassanabadi, S.; Ghominejad, M.
2016-06-01
As a quasi-probability distribution function in phase-space and a special representation of the density matrix, the Wigner function is of great significance in physics. In this work, the Wigner function for the Klein-Gordon oscillator is studied in commutative and noncommutative spaces. We first study the Wigner function for Klein-Gordon oscillator in commutative space then, by using a generalized Bopp's shift method, we obtain the corresponding Wigner function in noncommutative space. The additional terms in Wigner function on a NC space is related to the noncommutativity of space.
A Note on Exact Travelling Wave Solutions for the Klein-Gordon- Zakharov Equations
NASA Astrophysics Data System (ADS)
Zhang, Zai-Yun; Zhang, Ying-Hui; Gan, Xiang-Yang; Yu, De-Ming
2012-04-01
In this paper, we investigate the travelling wave solutions for the Klein-Gordon-Zakharov equations by using the modified trigonometric function series method benefited to the ideas of Z. Y. Zhang, Y. X. Li, Z. H. Liu, and X. J. Miao, Commun. Nonlin. Sci. Numer. Simul. , 3097 (2011). Exact travelling wave solutions are obtained
On the radius of spatial analyticity for the 1d Dirac-Klein-Gordon equations
NASA Astrophysics Data System (ADS)
Selberg, Sigmund; Tesfahun, Achenef
2015-11-01
We study the well-posedness of the Dirac-Klein-Gordon system in one space dimension with initial data that have an analytic extension to a strip around the real axis. It is proved that the radius of analyticity σ (t) of the solutions at time t cannot decay faster than 1 /t4 as | t | → ∞.
Scattering theory for the Klein-Gordon equation with nondecreasing potentials
Cruz, Maximino; Arredondo R, Juan H.
2008-11-15
The Klein-Gordon equation is considered in the case of nondecreasing potentials. The energy inner product is nonpositive on a subspace of infinite dimension, not consisting entirely of eigenvectors of the associated operator. A scattering theory for this case is developed and asymptotic completeness for generalized Moeller operators is proven.
The statistical properties of Klein-Gordon oscillator in noncommutative space
Hassanabadi, H. Hosseini, S. S.; Boumali, A.; Zarrinkamar, S.
2014-03-15
We study the relativistic spin-zero bosons influenced by the Klein-Gordon oscillator and an external magnetic field in noncommutative formulation. The problem is considered in two dimensions and is solved in an exact analytical manner. Having found the spectrum of the system, the statistical properties of an N-boson system are reported.
NASA Astrophysics Data System (ADS)
Onyeaju, M. C.; Ikot, A. N.; Chukwuocha, E. O.; Obong, H. P.; Zare, S.; Hassanabadi, H.
2016-06-01
Scattering and bound states solution for the one-dimensional Klein-Gordon particle with Hylleraas potential is presented within the frame work of position dependent effective mass formalism. We calculate in detail the reflection and transmission coefficients using the properties of hypergeometric functions and the equation of continuity of the wave functions.
Stability of Schwarzschild-AdS for the Spherically Symmetric Einstein-Klein-Gordon System
NASA Astrophysics Data System (ADS)
Holzegel, Gustav; Smulevici, Jacques
2013-01-01
In this paper, we study the global behavior of solutions to the spherically symmetric coupled Einstein-Klein-Gordon (EKG) system in the presence of a negative cosmological constant. For the Klein-Gordon mass-squared satisfying a ≥ -1 (the Breitenlohner-Freedman bound being a > -9/8), we prove that the Schwarzschild-AdS spacetimes are asymptotically stable: Small perturbations of Schwarzschild-AdS initial data again lead to regular black holes, with the metric on the black hole exterior approaching, at an exponential rate, a Schwarzschild-AdS spacetime. The main difficulties in the proof arise from the lack of monotonicity for the Hawking mass and the asymptotically AdS boundary conditions, which render even (part of) the orbital stability intricate. These issues are resolved in a bootstrap argument on the black hole exterior, with the redshift effect and weighted Hardy inequalities playing the fundamental role in the analysis. Both integrated decay and pointwise decay estimates are obtained. As a corollary of our estimates on the Klein-Gordon field, one obtains in particular exponential decay in time of spherically-symmetric solutions to the linear Klein-Gordon equation on Schwarzschild-AdS.
NASA Astrophysics Data System (ADS)
Ghafourian, M.; Hassanabadi, H.
2016-06-01
The Shannon information entropies for the Klein-Gordon equations are evaluated for the Poschl-Teller potential, and the position-space information entropies for the ground and the excited states are calculated.
Orbital instability of standing waves for the quadratic-cubic Klein-Gordon-Schrödinger system
NASA Astrophysics Data System (ADS)
Natali, Fábio; Pastor, Ademir
2015-08-01
We consider the Klein-Gordon-Schrödinger system with quadratic and cubic interactions. Smooth curves of periodic- and solitary-wave solutions are obtained via the implicit function theorem. Orbital instability of such waves is then established.
Kovalyov, Mikhail
2010-06-15
In this article the sets of solutions of the sine-Gordon equation and its linearization the Klein-Gordon equation are discussed and compared. It is shown that the set of solutions of the sine-Gordon equation possesses a richer structure which partly disappears during linearization. Just like the solutions of the Klein-Gordon equation satisfy the linear superposition principle, the solutions of the sine-Gordon equation satisfy a nonlinear superposition principle.
Effects of parity-time symmetry in nonlinear Klein-Gordon models and their stationary kinks.
Demirkaya, A; Frantzeskakis, D J; Kevrekidis, P G; Saxena, A; Stefanov, A
2013-08-01
In this work, we introduce some basic principles of PT-symmetric Klein-Gordon nonlinear field theories. By formulating a particular antisymmetric gain and loss profile, we illustrate that the stationary states of the model do not change. However, the stability critically depends on the gain and loss profile. For a symmetrically placed solitary wave (in either the continuum model or a discrete analog of the nonlinear Klein-Gordon type), there is no effect on the steady state spectrum. However, for asymmetrically placed solutions, there exists a measurable effect of which a perturbative mathematical characterization is offered. It is generally found that asymmetry towards the lossy side leads towards stability, while towards the gain side produces instability. Furthermore, a host of finite size effects, which disappear in the infinite domain limit, are illustrated in connection to the continuous spectrum of the problem. PMID:24032958
Nonlinear self-adjointness and conservation laws of Klein-Gordon-Fock equation with central symmetry
NASA Astrophysics Data System (ADS)
Abdulwahhab, Muhammad Alim
2015-05-01
The concept of nonlinear self-adjointness, introduced by Ibragimov, has significantly extends approaches to constructing conservation laws associated with symmetries since it incorporates the strict self-adjointness, the quasi self-adjointness as well as the usual linear self-adjointness. Using this concept, the nonlinear self-adjointness condition for the Klein-Gordon-Fock equation was established and subsequently used to construct simplified but infinitely many nontrivial and independent conserved vectors. The Noether's theorem was further applied to the Klein-Gordon-Fock equation to explore more distinct first integrals, result shows that conservation laws constructed through this approach are exactly the same as those obtained under strict self-adjointness of Ibragimov's method.
NASA Astrophysics Data System (ADS)
Donker, H. C.; Katsnelson, M. I.; De Raedt, H.; Michielsen, K.
2016-09-01
The logical inference approach to quantum theory, proposed earlier De Raedt et al. (2014), is considered in a relativistic setting. It is shown that the Klein-Gordon equation for a massive, charged, and spinless particle derives from the combination of the requirements that the space-time data collected by probing the particle is obtained from the most robust experiment and that on average, the classical relativistic equation of motion of a particle holds.
Klein-Gordon equations for energy-momentum of the relativistic particle in rapidity space
Yamaleev, R. M.
2013-10-15
The notion of four-rapidity is defined as a four-vector with one time-like and three space-like coordinates. It is proved, the energy and momentum defined in the space of four-rapidity obey Klein-Gordon equations constrained by the classical trajectory of a relativistic particle. It is shown, for small values of a proper mass influence of the constraint is weakened and the classical motion gains features of a wave motion.
The Einstein-Klein-Gordon Equations, Wave Dark Matter, and the Tully-Fisher Relation
NASA Astrophysics Data System (ADS)
Goetz, Andrew S.
2015-01-01
We examine the Einstein equation coupled to the Klein-Gordon equation for a complex-valued scalar field. These two equations together are known as the Einstein-Klein-Gordon system. In the low-field, non-relativistic limit, the Einstein-Klein-Gordon system reduces to the Poisson-Schrodinger system. We describe the simplest solutions of these systems in spherical symmetry, the spherically symmetric static states, and some scaling properties they obey. We also describe some approximate analytic solutions for these states. The EKG system underlies a theory of wave dark matter, also known as scalar field dark matter (SFDM), boson star dark matter, and Bose-Einstein condensate (BEC) dark matter. We discuss a possible connection between the theory of wave dark matter and the baryonic Tully-Fisher relation, which is a scaling relation observed to hold for disk galaxies in the universe across many decades in mass. We show how fixing boundary conditions at the edge of the spherically symmetric static states implies Tully-Fisher-like relations for the states. We also catalog other ``scaling conditions'' one can impose on the static states and show that they do not lead to Tully-Fisher-like relations--barring one exception which is already known and which has nothing to do with the specifics of wave dark matter.
Wave operators to a quadratic nonlinear Klein-Gordon equation in two space dimensions revisited
NASA Astrophysics Data System (ADS)
Hayashi, Nakao; Naumkin, Pavel I.; Tonegawa, Satoshi
2012-08-01
We continue to study the existence of the wave operators for the nonlinear Klein-Gordon equation with quadratic nonlinearity in two space dimensions {(partialt2-Δ+m2) u=λ u2,( t,x) in{R}×{R}2}. We prove that if u1+in{H}^{3/2+3γ,1}( {R}2),{ }u2+in{H}^{1/2+3γ,1}( {R} 2), where {γin( 0,1/4)} and the norm {Vert u1+Vert_{{H}1^{3/2+γ}}+Vert u2+Vert_{{H}1^{1/2+γ}}≤ρ,} then there exist ρ > 0 and T > 1 such that the nonlinear Klein-Gordon equation has a unique global solution {uin{C}( [ T,infty) ;{H}^{1/2}( {R}2) ) } satisfying the asymptotics Vert u( t) -u0 ( t) Vert _{{H}^{1/2}} ≤ Ct^{-1/2-γ} for all t > T, where u 0 denotes the solution of the free Klein-Gordon equation.
First Order Solutions for Klein-Gordon-Maxwell Equations in a Specific Curved Manifold Case
Murariu, Gabriel
2009-05-22
The aim of this paper is to study the SO(3,1)xU(1) gauge minimally coupled charged spinless field to a spherically symmetric curved space-time. It is derived the first order analytically approximation solution for the system of Klein-Gordon-Maxwell equations. Using these solutions, it evaluated the system electric charge density. The considered space -time manifold generalize an anterior studied one. The chosen space time configuration is of S diagonal type from the MAPLE GRTensor II metrics package.
Relativistic superfluidity and vorticity from the nonlinear Klein-Gordon equation
NASA Astrophysics Data System (ADS)
Xiong, Chi; Good, Michael R. R.; Guo, Yulong; Liu, Xiaopei; Huang, Kerson
2014-12-01
We investigate superfluidity, and the mechanism for creation of quantized vortices, in the relativistic regime. The general framework is a nonlinear Klein-Gordon equation in curved spacetime for a complex scalar field, whose phase dynamics gives rise to superfluidity. The mechanisms discussed are local inertial forces (Coriolis and centrifugal), and current-current interaction with an external source. The primary application is to cosmology, but we also discuss the reduction to the nonrelativistic nonlinear Schrödinger equation, which is widely used in describing superfluidity and vorticity in liquid helium and cold-trapped atomic gases.
NASA Astrophysics Data System (ADS)
Koide, T.; Kodama, T.
2015-09-01
The stochastic variational method (SVM) is the generalization of the variational approach to systems described by stochastic variables. In this paper, we investigate the applicability of SVM as an alternative field-quantization scheme, by considering the complex Klein-Gordon equation. There, the Euler-Lagrangian equation for the stochastic field variables leads to the functional Schrödinger equation, which can be interpreted as the Euler (ideal fluid) equation in the functional space. The present formulation is a quantization scheme based on commutable variables, so that there appears no ambiguity associated with the ordering of operators, e.g., in the definition of Noether charges.
Analytical solution of the Klein Gordon equation for a quadratic exponential-type potential
NASA Astrophysics Data System (ADS)
Ezzatpour, Somayyeh; Akbarieh, Amin Rezaei
2016-07-01
In this research study, analytical solutions of the Klein Gordon equation by considering the potential as a quadratic exponential will be presented. However, the potential is assumed to be within the framework of an approximation for the centrifugal potential in any state. The Nikiforov-Uvarov method is used to calculate the wave function, as well as corresponding exact energy equation, in bound states. We finally concluded that the quadratic exponential-type potential under which the results were deduced, led to outcomes that were comparable to the results obtained from the well-known potentials in some special cases.
Efficient and accurate numerical methods for the Klein-Gordon-Schroedinger equations
Bao, Weizhu . E-mail: bao@math.nus.edu.sg; Yang, Li . E-mail: yangli@nus.edu.sg
2007-08-10
In this paper, we present efficient, unconditionally stable and accurate numerical methods for approximations of the Klein-Gordon-Schroedinger (KGS) equations with/without damping terms. The key features of our methods are based on: (i) the application of a time-splitting spectral discretization for a Schroedinger-type equation in KGS (ii) the utilization of Fourier pseudospectral discretization for spatial derivatives in the Klein-Gordon equation in KGS (iii) the adoption of solving the ordinary differential equations (ODEs) in phase space analytically under appropriate chosen transmission conditions between different time intervals or applying Crank-Nicolson/leap-frog for linear/nonlinear terms for time derivatives. The numerical methods are either explicit or implicit but can be solved explicitly, unconditionally stable, and of spectral accuracy in space and second-order accuracy in time. Moreover, they are time reversible and time transverse invariant when there is no damping terms in KGS, conserve (or keep the same decay rate of) the wave energy as that in KGS without (or with a linear) damping term, keep the same dynamics of the mean value of the meson field, and give exact results for the plane-wave solution. Extensive numerical tests are presented to confirm the above properties of our numerical methods for KGS. Finally, the methods are applied to study solitary-wave collisions in one dimension (1D), as well as dynamics of a 2D problem in KGS.
NASA Astrophysics Data System (ADS)
Konkowski, Deborah A.; Arndt, Valerie; Helliwell, Thomas M.
2002-04-01
Klein-Gordon, Maxwell and Dirac fields are studied in quasiregular spacetimes, spacetimes with a classical quasiregular singularity, the mildest true classical singularity [G.F.R. Ellis and B.G. Schmidt, Gen. Rel. Grav.8, 915 (1977)]. A class of static quasiregular spacetimes possessing disclinations and dislocations [R.A. Puntigam and H.H. Soleng, Class. Quantum Grav. 14, 1129 (1997)] is shown to have field operators which are not essentially self-adjoint. This class of spacetimes includes an idealized cosmic string, i.e., a four-dimensional spacetime with a conical singularity [L.H. Ford and A. Vilenkin, J. Phys. A: Math. Gen. 14, 2353 (1981)], and a Galtsov/Letelier/Tod spacetime featuring a screw dislocation [K.P. Tod, Class. Quantum Grav. 11, 1331 (1994); D.V. Galtsov and P.S. Letelier, Phys. Rev. D47, 4273 (1993)]. The definition of G. T. Horowitz and D. Marolf [Phys. Rev. D52, 5670 (1995)] for a quantum-mechanically singular spacetime as one in which the spatial-derivative operator in the Klein-Gordon equation for a massive scalar field is not essentially self-adjoint is extended in the case of quasiregular spacetimes to include Maxwell and Dirac fields. Therefore, the class of static quasiregular spacetimes under consideration is quantum-mechanically singular independent of the type of test field.
NASA Astrophysics Data System (ADS)
Villalba, Víctor M.; Catalá, Esteban Isasi
2002-10-01
We solve the Klein-Gordon and Dirac equations in an open cosmological universe with a partially horn topology in the presence of a time dependent magnetic field. Since the exact solution cannot be obtained explicitly for arbitrary time dependence of the field, we discuss the asymptotic behavior of the solutions with the help of the relativistic Hamilton-Jacobi equation.
NASA Astrophysics Data System (ADS)
Ita, B. I.; Obong, H. P.; Ehi-Eromosele, C. O.; Edobor-Osoh, A.; Ikeuba, A. I.
2014-11-01
The solutions of the Klein-Gordon equation with equal scalar and vector harmonic oscillator plus inverse quadratic potential for S-waves have been presented using the Nikiforov-Uvarov method. The bound state energy eigenvalues and the corresponding un-normalized eigenfunctions are obtained in terms of the Laguerre polynomials.
NASA Astrophysics Data System (ADS)
Nakanishi, K.; Schlag, W.
2012-03-01
We extend our result Nakanishi and Schlag in J. Differ. Equ. 250(5):2299-2333, 2011) to the non-radial case, giving a complete classification of global dynamics of all solutions with energy that is at most slightly above that of the ground state for the nonlinear Klein-Gordon equation with the focusing cubic nonlinearity in three space dimensions.
Eab, C. H.; Lim, S. C.; Teo, L. P.
2007-08-15
This paper studies the Casimir effect due to fractional massless Klein-Gordon field confined to parallel plates. A new kind of boundary condition called fractional Neumann condition which involves vanishing fractional derivatives of the field is introduced. The fractional Neumann condition allows the interpolation of Dirichlet and Neumann conditions imposed on the two plates. There exists a transition value in the difference between the orders of the fractional Neumann conditions for which the Casimir force changes from attractive to repulsive. Low and high temperature limits of Casimir energy and pressure are obtained. For sufficiently high temperature, these quantities are dominated by terms independent of the boundary conditions. Finally, validity of the temperature inversion symmetry for various boundary conditions is discussed.
Klein-Gordon equation and reflection of Alfven waves in nonuniform media
NASA Technical Reports Server (NTRS)
Musielak, Z. E.; Fontenla, J. M.; Moore, R. L.
1992-01-01
A new analytical approach is presented for assessing the reflection of linear Alfven waves in smoothly nonuniform media. The general one-dimensional case in Cartesian coordinates is treated. It is shown that the wave equations, upon transformation into the form of the Klein-Gordon equation, display a local critical frequency for reflection. At any location in the medium, reflection becomes strong as the wave frequency descends past this characteristic frequency set by the local nonuniformity of the medium. This critical frequecy is given by the transformation as an explicit function of the Alfven velocity and its first and second derivatives, and hence as an explicit spatial function. The transformation thus directly yields, without solution of the wave equations, the location in the medium at which an Alfven wave of any given frequency becomes strongly reflected and has its propagation practically cut off.
Sharp comparison theorems for the Klein-Gordon equation in d dimensions
NASA Astrophysics Data System (ADS)
Hall, Richard L.; Zorin, Petr
2016-06-01
We establish sharp (or ’refined’) comparison theorems for the Klein-Gordon equation. We show that the condition Va ≤ Vb, which leads to Ea ≤ Eb, can be replaced by the weaker assumption Ua ≤ Ub which still implies the spectral ordering Ea ≤ Eb. In the simplest case, for d = 1, Ui(x) =∫0xV i(t)dt, i = a or b and for d > 1, Ui(r) =∫0rV i(t)td‑1dt, i = a or b. We also consider sharp comparison theorems in the presence of a scalar potential S (a ‘variable mass’) in addition to the vector term V (the time component of a four-vector). The theorems are illustrated by a variety of explicit detailed examples.
Dynamical Hamiltonian-Hopf instabilities of periodic traveling waves in Klein-Gordon equations
NASA Astrophysics Data System (ADS)
Marangell, R.; Miller, P. D.
2015-07-01
We study the unstable spectrum close to the imaginary axis for the linearization of the nonlinear Klein-Gordon equation about a periodic traveling wave in a co-moving frame. We define dynamical Hamiltonian-Hopf instabilities as points in the stable spectrum that are accumulation points for unstable spectrum, and show how they can be determined from the knowledge of the discriminant of Hill's equation for an associated periodic potential. This result allows us to give simple criteria for the existence of dynamical Hamiltonian-Hopf instabilities in terms of instability indices previously shown to be useful in stability analysis of periodic traveling waves. We also discuss how these methods can be applied to more general nonlinear wave equations.
Klein-Gordon Solutions on Non-Globally Hyperbolic Standard Static Spacetimes
NASA Astrophysics Data System (ADS)
Bullock, David M. A.
2012-11-01
We construct a class of solutions to the Cauchy problem of the Klein-Gordon equation on any standard static spacetime. Specifically, we have constructed solutions to the Cauchy problem based on any self-adjoint extension (satisfying a technical condition: "acceptability") of (some variant of) the Laplace-Beltrami operator defined on test functions in an L2-space of the static hypersurface. The proof of the existence of this construction completes and extends work originally done by Wald. Further results include: the uniqueness of these solutions; their support properties; the construction of the space of solutions and the energy and symplectic form on this space; an analysis of certain symmetries on the space of solutions; and various examples of this method, including the construction of a non-bounded below acceptable self-adjoint extension generating the dynamics.
Didactic derivation of the special theory of relativity from the Klein-Gordon equation
NASA Astrophysics Data System (ADS)
Arodź, H.
2014-09-01
We present a didactic derivation of the special theory of relativity in which Lorentz transformations are ‘discovered’ as symmetry transformations of the Klein-Gordon equation. The interpretation of Lorentz boosts as transformations to moving inertial reference frames is not assumed at the start, but it naturally appears at a later stage. The relative velocity v of two inertial reference frames is defined in terms of the elements of the pertinent Lorentz matrix, and the bound |{\\bf v}| is presented as a simple theorem that follows from the structure of the Lorentz group. The polar decomposition of Lorentz matrices is used to explain noncommutativity and nonassociativity of the relativistic composition (‘addition’) of velocities.
NASA Astrophysics Data System (ADS)
Wu, Xinyuan; Liu, Changying
2016-02-01
In this paper, we are concerned with the initial boundary value problem of arbitrarily high-dimensional Klein-Gordon equations, posed on a bounded domain Ω ⊂ ℝd for d ≥ 1 and equipped with the requirement of boundary conditions. We derive and analyze an integral formula which is proved to be adapted to different boundary conditions for general Klein-Gordon equations in arbitrarily high-dimensional spaces. The formula gives a closed-form solution to arbitrarily high-dimensional homogeneous linear Klein-Gordon equations, which is totally different from the well-known D'Alembert, Poisson, and Kirchhoff formulas. Some applications are included as well.
NASA Astrophysics Data System (ADS)
Nakao, Mitsuhiro
We prove the existence of global decaying solutions to the exterior problem for the Klein-Gordon equation with a nonlinear localized dissipation and a derivative nonlinearity. To derive the required estimates of solutions we employ a 'loan' method.
NASA Astrophysics Data System (ADS)
Vitória, R. L. L.; Furtado, C.; Bakke, K.
2016-07-01
The relativistic quantum dynamics of an electrically charged particle subject to the Klein-Gordon oscillator and the Coulomb potential is investigated. By searching for relativistic bound states, a particular quantum effect can be observed: a dependence of the angular frequency of the Klein-Gordon oscillator on the quantum numbers of the system. The meaning of this behaviour of the angular frequency is that only some specific values of the angular frequency of the Klein-Gordon oscillator are permitted in order to obtain bound state solutions. As an example, we obtain both the angular frequency and the energy level associated with the ground state of the relativistic system. Further, we analyse the behaviour of a relativistic position-dependent mass particle subject to the Klein-Gordon oscillator and the Coulomb potential.
NASA Astrophysics Data System (ADS)
Ikot, A. N.; Obong, H. P.; Abbey, T. M.; Zare, S.; Ghafourian, M.; Hassanabadi, H.
2016-05-01
In this article we use supersymmetry quantum mechanics and factorization methods to study the bound and scattering state of Klein-Gordon equation with deformed Hulthen plus deformed hyperbolical potential for arbitrary state in D-dimensions. The analytic relativistic bound state eigenvalues and the scattering phase factor are found in closed form. We report on the numerical results for the bound state energy in D-dimensions.
NASA Astrophysics Data System (ADS)
Mu, Xiyu; Cheng, Hao; Liu, Guoqing
2016-04-01
It is often difficult to provide the exact boundary condition in the practical use of variational method. The Euler equation derived from variational method cannot be solved without boundary condition. However, in some application problems such as the assimilation of remote sensing data, the values can be easily obtained in the inner region of the domain. Since the solution of elliptic partial differential equations continuously depends on the boundary condition, the boundary condition can be retrieved using part solutions in the inner area. In this paper, the variational problem of remote sensing data assimilation within a circular area is first established. The Klein-Gordon elliptic equation is derived from the Euler method of variational problems with assumed boundary condition. Secondly, a computer-friendly Green function is constructed for the Dirichlet problem of two-dimensional Klein-Gordon equation, with the formal solution according to Green formula. Thirdly, boundary values are retrieved by solving the optimal problem which is constructed according to the smoothness of boundary value function and the best approximation between formal solutions and high-accuracy measurements in the interior of the domain. Finally, the assimilation problem is solved on substituting the retrieved boundary values into the Klein-Gordon equation. It is a type of inverse problem in mathematics. The advantage of our method lies in that it needs no assumptions of the boundary condition. It thus alleviates the error introduced by artificial boundary condition in data fusion using variational method in the past.
A local energy-preserving scheme for Klein-Gordon-Schrödinger equations
NASA Astrophysics Data System (ADS)
Cai, Jia-Xiang; Wang, Jia-Lin; Wang, Yu-Shun
2015-05-01
A local energy conservation law is proposed for the Klein-Gordon-Schrödinger equations, which is held in any local time-space region. The local property is independent of the boundary condition and more essential than the global energy conservation law. To develop a numerical method preserving the intrinsic properties as much as possible, we propose a local energy-preserving (LEP) scheme for the equations. The merit of the proposed scheme is that the local energy conservation law can hold exactly in any time-space region. With the periodic boundary conditions, the scheme also possesses the discrete change and global energy conservation laws. A nonlinear analysis shows that the LEP scheme converges to the exact solutions with order 𝒪(τ2 + h2). The theoretical properties are verified by numerical experiments. Project supported by the National Natural Science Foundation of China (Grant Nos. 11201169, 11271195, and 41231173) and the Project of Graduate Education Innovation of Jiangsu Province, China (Grant No. CXLX13 366).
Critical and noncritical long-range entanglement in Klein-Gordon fields
Marcovitch, S.; Reznik, B.; Retzker, A.; Plenio, M. B.
2009-07-15
We investigate the entanglement between two spatially separated intervals in the vacuum state of a free one-dimensional Klein-Gordon field by means of explicit computations in the continuum limit of the linear harmonic chain. We demonstrate that the entanglement, which we quantify by the logarithmic negativity, is finite with no further need for renormalization. We find that in the critical regime, the quantum correlations are scale invariant as they depend only on the ratio of distance to length. They decay much faster than the classical correlations as in the critical limit long-range entanglement decays exponentially for separations larger than the size of the blocks, while classical correlations follow a power-law decay. With decreasing distance of the blocks, the entanglement diverges as a power law in the distance. The noncritical regime manifests richer behavior, as the entanglement depends both on the size of the blocks and on their separation. In correspondence with the von Neumann entropy also long-range entanglement distinguishes critical from noncritical systems.
Hunting the ghosts of a 'strictly quantum field': the Klein-Gordon equation
NASA Astrophysics Data System (ADS)
Bertozzi, Eugenio
2010-11-01
This paper aims to identify and tackle some problems related to teaching quantum field theory (QFT) at university level. In particular, problems arising from the canonical quantization are addressed by focusing on the Klein-Gordon equation (KGE). After a brief description of the status of the KGE in teaching as it emerges from an analysis of a selected sample of university textbooks, an analysis of the applications of the KGE in contexts different from the QFT is presented. The results of the analysis show that, while in the real case the solutions of the equation can be easily interpreted from a physical point of view, in the complex case the coherence with relativistic quantum mechanics and the electrodynamics framework brings to light interpretative problems related to the classical complex KG field. The comparison between the classical cases investigated and the QFT framework, where the equation finds a coherent particle interpretation, leads to share Ryder's statement asserting that the KG field is a 'strictly quantum field'. Implications of the results in terms of remarks about the canonical procedure currently utilized for teaching are underlined.
Hydromagnetic waves in a compressed-dipole field via field-aligned Klein-Gordon equations
NASA Astrophysics Data System (ADS)
Zheng, Jinlei; Hu, Qiang; Webb, Gary M.; McKenzie, James F.
2016-05-01
Hydromagnetic waves, especially those of frequencies in the range of a few millihertz to a few hertz observed in the Earth's magnetosphere, are categorized as ultra low-frequency (ULF) waves or pulsations. They have been extensively studied due to their importance in the interaction with radiation belt particles and in probing the structures of the magnetosphere. We developed an approach to examining the toroidal standing Aflvén waves in a background magnetic field by recasting the wave equation into a Klein-Gordon (KG) form along individual field lines. The eigenvalue solutions to the system are characteristic of a propagation type when the corresponding eigenfrequency is greater than a critical frequency and a decaying type otherwise. We apply the approach to a compressed-dipole magnetic field model of the inner magnetosphere and obtain the spatial profiles of relevant parameters and the spatial wave forms of harmonic oscillations. We further extend the approach to poloidal-mode standing Alfvén waves along field lines. In particular, we present a quantitative comparison with a recent spacecraft observation of a poloidal standing Alfvén wave in the Earth's magnetosphere. Our analysis based on the KG equation yields consistent results which agree with the spacecraft measurements of the wave period and the amplitude ratio between the magnetic field and electric field perturbations.
Quantum breathers in Klein-Gordon lattice: Non-periodic boundary condition approach
NASA Astrophysics Data System (ADS)
Mandal, Subhra Jyoti; Choudhary, Kamal; Biswas, Arindam; Bandyopadhyay, A. K.; Bhattacharjee, A. K.; Mandal, D.
2011-12-01
The presence of classical breathers and two-phonon bound state (TPBS) or quantum breather (QB) state through detailed quantum calculations have already been shown in technologically important ferroelectric materials, such as lithium niobate with antisite niobium charge defects concerning pinning transition, its control, and application. The latter was done in a periodic boundary condition with Bloch function in terms of significant variations of TPBS parameters against impurity, which is related to nonlinearity. In further extension of this work, in a non-periodic boundary condition and number-conserving approach, apart from various techniques available, only the temporal evolution of the number of quanta (i.e., phonons) in more sites is detailed in this present investigation for a generalized Klein-Gordon system with applications in ferroelectrics, metamaterials, and DNA. The critical time of redistribution of quanta that is proportional to the QB's lifetime in these materials shows different types of behavior in the femtosecond range, which gives rise to the possibilities for making various devices.
Solitons and chaos of the Klein-Gordon-Zakharov system in a high-frequency plasma
NASA Astrophysics Data System (ADS)
Zhen, Hui-Ling; Tian, Bo; Sun, Ya; Chai, Jun; Wen, Xiao-Yong
2015-10-01
In this paper, we study the Klein-Gordon-Zakharov (KGZ) system, which describes the interaction between the Langmuir wave and ion sound wave in a high-frequency plasma. By means of the Hirota method and symbolic computation, bright and mixed-type soliton solutions are obtained. For the one soliton, amplitude of E is positively related to β 2 , and that of n is inversely related to β 2 , while they are both positively related to α, where E refers to the high-frequency part of the electrostatic potential of the electric field raised by the electrons, and n represents the deviation of ion density from its equilibrium, β 2 and α are the plasma frequency and ion sound speed, respectively. Head-on interactions between the two bright solitons and two mixed-type ones are respectively displayed. With β 2 increasing, the head-on interaction is transformed into an overtaking one. Bright bound-state solitons are investigated, and the interaction period decreases with α increasing. Furthermore, with the external forces Γ 1 ( t ) and Γ 2 ( t ) introduced, the perturbed KGZ system is studied numerically for its associated chaotic motions. Both the weak and developed chaotic motions can be observed. Γ 1 ( t ) and Γ 2 ( t ) have different effects on the chaotic motions: the chaotic motion can be weakened by decreasing the amplitude of Γ 1 ( t ) or increasing the amplitude and frequency of Γ 2 ( t ) .
Generalized and functional separable solutions to nonlinear delay Klein-Gordon equations
NASA Astrophysics Data System (ADS)
Polyanin, Andrei D.; Zhurov, Alexei I.
2014-08-01
We describe a number of generalized separable, functional separable, and some other exact solutions to nonlinear delay Klein-Gordon equations of the formutt=kuxx+F(u,w), where u=u(x,t) and w=u(x,t-τ), with τ denoting the delay time. The generalized separable solutions are sought in the form u=∑n=1NΦn(x)Ψn(t), where the functions Φn(x) and Ψn(t) are to be determined subsequently. Most of the equations considered contain one or two arbitrary functions of a single argument or one arbitrary function of two arguments of special form. We present a substantial number of new exact solutions, including periodic and antiperiodic ones, as well as composite solutions resulting from a nonlinear superposition of generalized separable and traveling wave solutions. All solutions involve free parameters (in some cases, infinitely many) and so can be suitable for solving certain problems and testing approximate analytical and numerical methods for nonlinear delay PDEs.
Huygens' principle for the Klein-Gordon equation in the de Sitter spacetime
Yagdjian, Karen
2013-09-15
In this article we prove that the Klein-Gordon equation in the de Sitter spacetime obeys the Huygens' principle only if the physical mass m of the scalar field and the dimension n⩾ 2 of the spatial variable are tied by the equation m{sup 2}= (n{sup 2}−1)/4. Moreover, we define the incomplete Huygens' principle, which is the Huygens' principle restricted to the vanishing second initial datum, and then reveals that the massless scalar field in the de Sitter spacetime obeys the incomplete Huygens' principle and does not obey the Huygens' principle, for the dimensions n= 1, 3, only. Thus, in the de Sitter spacetime the existence of two different scalar fields (in fact, with m= 0 and m{sup 2}= (n{sup 2}−1)/4), which obey incomplete Huygens' principle, is equivalent to the condition n= 3, the spatial dimension of the physical world. In fact, Paul Ehrenfest in 1917 addressed the question: “Why has our space just three dimensions?”. For n= 3 these two values of the mass are the endpoints of the so-called in quantum field theory the Higuchi bound. The value m{sup 2}= (n{sup 2}−1)/4 of the physical mass allows us also to obtain complete asymptotic expansion of the solution for the large time.
Gromov, E.M.; Talanov, V.I.
1992-01-01
Questions relating to the penetration of fields into supercritical regions of inhomogeneous media are of considerable interest both for fundamental studies in wave theory and for applied problems in various areas of physics. In strong fields this penetration is related to nonlinear restructuring of the parameters of the medium under the action of the field itself. In weak fields penetration is possible when a strong wave in the parameters of the medium is present and are facilitated if the dynamic states undergo frequency shifts in the inhomogeneous medium in the presence of this wave. Such states have been quite well studied for fields described by equations such as the Schroedinger equation. At the same time it was noted that dynamic field states can exist which are described by the Klein-Gordon equation. In the present work we study the dynamic states of such fields in the presence of a parameter wave. We point out the possibility of entraining packets of the field by this wave. The efficiency with which these entrained states are excited is determined for a parameter wave in the form of a discontinuous shock. 12 refs.
NASA Astrophysics Data System (ADS)
LeFloch, Philippe G.; Ma, Yue
2016-01-01
The Hyperboloidal Foliation Method (introduced by the authors in 2014) is extended here and applied to the Einstein equations of general relativity. Specifically, we establish the nonlinear stability of Minkowski spacetime for self-gravitating massive scalar fields, while existing methods only apply to massless scalar fields. First of all, by analyzing the structure of the Einstein equations in wave coordinates, we exhibit a nonlinear wave-Klein-Gordon model defined on a curved background, which is the focus of the present paper. For this model, we prove here the existence of global-in-time solutions to the Cauchy problem, when the initial data have sufficiently small Sobolev norms. A major difficulty comes from the fact that the class of conformal Killing fields of Minkowski space is significantly reduced in the presence of a massive scalar field, since the scaling vector field is not conformal Killing for the Klein-Gordon operator. Our method relies on the foliation (of the interior of the light cone) of Minkowski spacetime by hyperboloidal hypersurfaces and uses Lorentz-invariant energy norms. We introduce a frame of vector fields adapted to the hyperboloidal foliation and we establish several key properties: Sobolev and Hardy-type inequalities on hyperboloids, as well as sup-norm estimates, which correspond to the sharp time decay for the wave and the Klein-Gordon equations. These estimates allow us to control interaction terms associated with the curved geometry and the massive field by distinguishing between two levels of regularity and energy growth and by a successive use of our key estimates in order to close a bootstrap argument.
NASA Astrophysics Data System (ADS)
Xu, Xiao-Ge; Gao, Yi-Tian; Wei, Guang-Mei
In this paper, the nonlinear Klein-Gordon equation describing the propagation of pulse waves in plasma or waveguide is investigated. With symbolic computation, the generalized Bäcklund Transformations (BTs) for this equation are constructed under different conditions. It is shown that the BTs published in the previous literature for the Sine-Gordon equation, Sinh-Gordon equation, and Liouville equation all turn out to be special cases of the results in the present paper. Moreover, the corresponding Lax pairs are explicitly derived from the obtained BTs through some transformations.
NASA Astrophysics Data System (ADS)
Alonso-Mallo, I.; Portillo, A. M.
2016-04-01
Klein-Gordon equations on an unbounded domain are considered in one dimensional and two dimensional cases. Numerical computation is reduced to a finite domain by using the Hagstrom-Warburton (H-W) high-order absorbing boundary conditions (ABCs). Time integration is made by means of exponential splitting schemes that are efficient and easy to implement. In this way, it is possible to achieve a negligible error due to the time integration and to study the behavior of the absorption error. Numerical experiments displaying the accuracy of the numerical solution for the two dimensional case are provided. The influence of the dispersion coefficient on the error is also studied.
NASA Astrophysics Data System (ADS)
Saha Ray, S.; Sahoo, S.
2016-07-01
In this paper, homotopy perturbation transform method and modified homotopy analysis method have been applied to obtain the approximate solutions of the time fractional coupled Klein-Gordon-Zakharov equations. We consider fractional coupled Klein-Gordon-Zakharov equation with appropriate initial values using homotopy perturbation transform method and modified homotopy analysis method. Here we obtain the solution of fractional coupled Klein-Gordon-Zakharov equation, which is obtained by replacing the time derivatives with a fractional derivatives of order α ∈ (1, 2], β ∈ (1, 2]. Through error analysis and numerical simulation, we have compared approximate solutions obtained by two present methods homotopy perturbation transform method and modified homotopy analysis method. The fractional derivatives here are described in Caputo sense.
NASA Astrophysics Data System (ADS)
Suárez, Abril; Chavanis, Pierre-Henri
2015-07-01
Using a generalization of the Madelung transformation, we derive the hydrodynamic representation of the Klein-Gordon-Einstein equations in the weak field limit. We consider a complex self-interacting scalar field with a λ |φ |4 potential. We study the evolution of the spatially homogeneous background in the fluid representation and derive the linearized equations describing the evolution of small perturbations in a static and in an expanding Universe. We compare the results with simplified models in which the gravitational potential is introduced by hand in the Klein-Gordon equation, and assumed to satisfy a (generalized) Poisson equation. Nonrelativistic hydrodynamic equations based on the Schrödinger-Poisson equations or on the Gross-Pitaevskii-Poisson equations are recovered in the limit c →+∞. We study the evolution of the perturbations in the matter era using the nonrelativistic limit of our formalism. Perturbations whose wavelength is below the Jeans length oscillate in time while perturbations whose wavelength is above the Jeans length grow linearly with the scale factor as in the cold dark matter model. The growth of perturbations in the scalar field model is substantially faster than in the cold dark matter model. When the wavelength of the perturbations approaches the cosmological horizon (Hubble length), a relativistic treatment is mandatory. In that case, we find that relativistic effects attenuate or even prevent the growth of perturbations. This paper exposes the general formalism and provides illustrations in simple cases. Other applications of our formalism will be considered in companion papers.
NASA Astrophysics Data System (ADS)
Hack, Thomas-Paul
2014-11-01
We quantize the linearized Einstein-Klein-Gordon system on arbitrary on-shell backgrounds in a manifestly covariant and gauge-invariant manner. For the special case of perturbations in inflation, i.e. on-shell backgrounds of Friedmann-Lemaître-Robertson-Walker type, we compare our general quantization construction with the standard approach to the quantum theory of perturbations in inflation. We find that not all local quantum observables of the linearized Einstein-Klein-Gordon system can be split into local observables of scalar and tensor type as in the standard approach. However, we argue that this subclass of observables is sufficient for measuring perturbations that vanish at spatial infinity, which is in line with standard assumptions. Finally, we comment on a recent observation that, upon standard quantization, the quantum Bardeen potentials display a non-local behaviour and argue that a similar phenomenon occurs in any local quantum field theory. It is the hope of the author that the present work may constitute a bridge between the generally applicable and thus powerful framework of algebraic quantum field theory in curved spacetimes and the standard treatment of perturbations in inflation.
Numerical Studies of Nonlinear Schrodinger and Klein-Gordon Systems: Techniques and Applications
NASA Astrophysics Data System (ADS)
Choi, Dae-Il
The continuing proliferation of computational resources makes it more and more powerful to conduct numerical studies on physics problems for which either analytic methods fail, or well-controlled experiments are very difficult, if not impossible. In particular, a finite-difference based numerical approach. has been an indispensable tool in the three areas of physics that, I study in this thesis: numerical relativity (boson stars), Bose-Einstein condensates, and atomic hydrogen in strong laser fields. Numerical relativity (NR) enables us to tackle problems of astrophysical interest which are difficult or impossible to study using analytic methods. Many of these problems involve strong and dynamical gravitational fields, and many involve the dynamics of one or more gravitationally compact objects such as black holes, neutron stars or, more speculatively, boson stars. A long term goal of NR, then (and of this research) is the accurate simulation of the dynamics of one or more compact objects. Here, as a step in that direction, I present some of the first results for a fully coupled Einstein/Klein-Gordon system in 3D, wherein I attempt to evolve a static relativistic boson star using the full equations of motion. A key motivation for the study of self-gravitating bosonic matter (in both the Newtonian and Einsteinian regimes) is the observation that, even though any direct physical relevance has yet to be demonstrated, boson star systems provide excellent numerical laboratories in which to develop techniques for NR. Specifically, the boson star model provides an ideal vehicle with which to implement and evaluate (1) various coordinate conditions in the context of the ADM formalism and (2) multidimensional adaptive mesh refinement techniques which appear crucial for many problems in 3D numerical relativity. Again, as a step towards studying the fully relativistic problem, I first consider boson stars in the Newtonian regime, which are described by the solutions of Schr
NASA Astrophysics Data System (ADS)
Sergyeyev, Artur; Krtouš, Pavel
2008-02-01
We consider the Klein-Gordon equation in generalized higher-dimensional Kerr-NUT-(A)dS spacetime without imposing any restrictions on the functional parameters characterizing the metric. We establish commutativity of the second-order operators constructed from the Killing tensors found in [J. High Energy Phys.JHEPFG1029-8479 02 (2007) 00410.1088/1126-6708/2007/02/004] and show that these operators, along with the first-order operators originating from the Killing vectors, form a complete set of commuting symmetry operators (i.e., integrals of motion) for the Klein-Gordon equation. Moreover, we demonstrate that the separated solutions of the Klein-Gordon equation obtained in [J. High Energy Phys.JHEPFG1029-8479 02 (2007) 00510.1088/1126-6708/2007/02/005] are joint eigenfunctions for all of these operators. We also present an explicit form of the zero mode for the Klein-Gordon equation with zero mass. In the semiclassical approximation we find that the separated solutions of the Hamilton-Jacobi equation for geodesic motion are also solutions for a set of Hamilton-Jacobi-type equations which correspond to the quadratic conserved quantities arising from the above Killing tensors.
Sergyeyev, Artur; Krtous, Pavel
2008-02-15
We consider the Klein-Gordon equation in generalized higher-dimensional Kerr-NUT-(A)dS spacetime without imposing any restrictions on the functional parameters characterizing the metric. We establish commutativity of the second-order operators constructed from the Killing tensors found in [J. High Energy Phys. 02 (2007) 004] and show that these operators, along with the first-order operators originating from the Killing vectors, form a complete set of commuting symmetry operators (i.e., integrals of motion) for the Klein-Gordon equation. Moreover, we demonstrate that the separated solutions of the Klein-Gordon equation obtained in [J. High Energy Phys. 02 (2007) 005] are joint eigenfunctions for all of these operators. We also present an explicit form of the zero mode for the Klein-Gordon equation with zero mass. In the semiclassical approximation we find that the separated solutions of the Hamilton-Jacobi equation for geodesic motion are also solutions for a set of Hamilton-Jacobi-type equations which correspond to the quadratic conserved quantities arising from the above Killing tensors.
NASA Astrophysics Data System (ADS)
Tang, Bing; Li, De-Jun
2016-05-01
A theoretical work on quantum breathers in a nonlinear Klein-Gordon lattice model with nearest and next-nearest neighbor interactions is presented. The semiclassical and the full quantum cases are respectively considered. For the semiclassical case, we obtain the analytical solution of discrete breather, and find that the wave number corresponding to the appearance of discrete breather changes when the ratio of the next-nearest- to -nearest - neighbor harmonic force constants is greater than 1/4. For the full quantum case, by calculating the energy spectrum of the system containing two quanta, we prove numerically the existence of quantum breathers (two-quanta bound states) and find the shape of energy spectrum changes dramatically as the value of next -nearest neighbor harmonic force constant increasing.
NASA Astrophysics Data System (ADS)
Babin, Anatoli; Figotin, Alexander
2013-09-01
Einstein's relation E = Mc 2 between the energy E and the mass M is the cornerstone of the relativity theory. This relation is often derived in a context of the relativistic theory for closed systems which do not accelerate. By contrast, the Newtonian approach to the mass is based on an accelerated motion. We study here a particular neoclassical field model of a particle governed by a nonlinear Klein-Gordon (KG) field equation. We prove that if a solution to the nonlinear KG equation and its energy density concentrate at a trajectory, then this trajectory and the energy must satisfy the relativistic version of Newton's law with the mass satisfying Einstein's relation. Therefore the internal energy of a localized wave affects its acceleration in an external field as the inertial mass does in Newtonian mechanics. We demonstrate that the "concentration" assumptions hold for a wide class of rectilinear accelerating motions.
NASA Astrophysics Data System (ADS)
Vigier, Jean-Pierre
1991-02-01
Starting from a nonlinear relativistic Klein-Gordon equation derived from the stochastic interpretation of quantum mechanics (proposed by Bohm-Vigier, (1) Nelson, (2) de Broglie, (3) Guerra et al. (4) ), one can construct joint wave and particle, soliton-like solutions, which follow the average de Broglie-Bohm (5) real trajectories associated with linear solutions of the usual Schrödinger and Klein-Gordon equations.
NASA Astrophysics Data System (ADS)
Pesci, Adriana I.; Goldstein, Raymond E.; Uys, Hermann
2005-05-01
In previous work we have shown that the quantum potential can be derived from the classical kinetic equations both for particles with and without spin. Here, we extend these mappings to the relativistic case. The essence of the analysis consists of Fourier transforming the momentum coordinate of the distribution function. This procedure introduces a natural parameter η with units of angular momentum. In the non-relativistic case the ansatz of either separability, or separability and additivity, imposed on the probability distribution function produces mappings onto the Schrödinger equation and the Pauli equation, respectively. The former corresponds to an irrotational flow, the latter to a fluid with non-zero vorticity. In this work we show that the relativistic mappings lead to the Klein-Gordon equation in the irrotational case and to the second-order Dirac equation in the rotational case. These mappings are irreversible; an approximate inverse is the Wigner function. Taken together, these results provide a statistical interpretation of quantum mechanics.
Complex structures for an S-matrix of Klein-Gordon theory on AdS spacetimes
NASA Astrophysics Data System (ADS)
Dohse, Max; Oeckl, Robert
2015-05-01
While the standard construction of the S-matrix fails on anti-de Sitter (AdS) spacetime, a generalized S-matrix makes sense, based on the hypercylinder geometry induced by the boundary of AdS. In contrast to quantum field theory in Minkowski spacetime, there is not yet a standard way to resolve the quantization ambiguities arising in its construction. These ambiguities are conveniently encoded in the choice of a complex structure. We explore in this paper the space of complex structures for real scalar Klein-Gordon theory based on a number of criteria. These are: invariance under AdS isometries, induction of a positive definite inner product, compatibility with the standard S-matrix picture and recovery of standard structures in Minkowski spacetime under a limit of vanishing curvature. While there is no complex structure that satisfies all demands, we emphasize two interesting candidates that satisfy most: in one case we have to give up part of the isometry invariance, and in the other case the induced inner product is indefinite.
Gallet, Basile; Nazarenko, Sergey; Dubrulle, Bérengère
2015-07-01
In field theory, particles are waves or excitations that propagate on the fundamental state. In experiments or cosmological models, one typically wants to compute the out-of-equilibrium evolution of a given initial distribution of such waves. Wave turbulence deals with out-of-equilibrium ensembles of weakly nonlinear waves, and is therefore well suited to address this problem. As an example, we consider the complex Klein-Gordon equation with a Mexican-hat potential. This simple equation displays two kinds of excitations around the fundamental state: massive particles and massless Goldstone bosons. The former are waves with a nonzero frequency for vanishing wave number, whereas the latter obey an acoustic dispersion relation. Using wave-turbulence theory, we derive wave kinetic equations that govern the coupled evolution of the spectra of massive and massless waves. We first consider the thermodynamic solutions to these equations and study the wave condensation transition, which is the classical equivalent of Bose-Einstein condensation. We then focus on nonlocal interactions in wave-number space: we study the decay of an ensemble of massive particles into massless ones. Under rather general conditions, these massless particles accumulate at low wave number. We study the dynamics of waves coexisting with such a strong condensate, and we compute rigorously a nonlocal Kolmogorov-Zakharov solution, where particles are transferred nonlocally to the condensate, while energy cascades towards large wave numbers through local interactions. This nonlocal cascading state constitutes the intermediate asymptotics between the initial distribution of waves and the thermodynamic state reached in the long-time limit. PMID:26274249
NASA Astrophysics Data System (ADS)
Jia, Chun-Sheng; Chen, Tao; He, Su
2013-03-01
By employing the improved Greene-Aldrich approximation scheme to deal with the centrifugal term, we solve approximately the Klein-Gordon equation with the improved expression of the Manning-Rosen empirical potential energy model. The bound state energy equation and the unnormalized radial wave functions have been approximately obtained by using the supersymmetric WKB approach and the function analysis method. The relativistic vibrational transition frequencies for the a3Σu+ state of 7Li2 molecule have been computed by using the Manning-Rosen potential model. The relativistic vibrational transition frequencies are in good agreement with the observed data.
NASA Astrophysics Data System (ADS)
Chen, Chang-Yuan; Lu, Fa-Lin; Sun, Dong-Sheng
2008-12-01
In this paper, using the exponential function transformation approach along with an approximation for the centrifugal potential, the radial Klein-Gordon equation with the vector and scalar Hulthén potential is transformed to a hypergeometric differential equation. The approximate analytical solutions of t-waves scattering states are presented. The normalized wave functions expressed in terms of hypergeometric functions of scattering states on the “ k/2π scale” and the calculation formula of phase shifts are given. The physical meaning of the approximate analytical solution is discussed.
NASA Astrophysics Data System (ADS)
Chen, Chang-Yuan; Lu, Fa-Lin; Sun, Dong-Sheng
2008-12-01
In this paper, using the exponential function transformation approach along with an approximation for the centrifugal potential, the radial Klein-Gordon equation with the vector and scalar Hulthén potential is transformed to a hypergeometric differential equation. The approximate analytical solutions of t-waves scattering states are presented. The normalized wave functions expressed in terms of hypergeometric functions of scattering states on the "k/2π scale" and the calculation formula of phase shifts are given. The physical meaning of the approximate analytical solution is discussed.
NASA Astrophysics Data System (ADS)
Bialynicki-Birula, Iwo
2013-03-01
General solutions of the Klein-Gordon equation satisfying the Dirichlet boundary conditions on one fixed wall and the other wall moving with a constant velocity are derived. These solutions are specified by an arbitrary periodic function whose period is equal to twice the value of the rapidity of the moving wall. Choosing this function as a combination of trigonometric functions one obtains the solutions derived recently by Koehn. The method is also tested in the case of the d'Alembert equation where it reproduces in a simple manner well-known results.
NASA Astrophysics Data System (ADS)
Aggoun, L.; Benamira, F.; Guechi, L.; Sadoun, M. A.
2016-04-01
The Green's function associated with a Klein-Gordon particle moving in a D-dimensional space under the action of vector plus scalar q-deformed Hulthén potentials is constructed by path integration for {q ≥ 1} and {1/α ln q < r < infty}. An appropriate approximation of the centrifugal potential term and the technique of space-time transformation are used to reduce the path integral for the generalized Hulthén potentials into a path integral for q-deformed Rosen-Morse potential. Explicit path integration leads to the radial Green's function for any l state in closed form. The energy spectrum and the correctly normalized wave functions, for a state of orbital quantum number {l ≥ 0}, are obtained. Eventually, the vector q-deformed Hulthén potential and the Coulomb potentials in D dimensions are considered as special cases.
NASA Astrophysics Data System (ADS)
Ballesteros, Miguel; Weder, Ricardo
2016-04-01
The study of obstacle scattering for the Klein-Gordon equation in the presence of long-range magnetic potentials is addressed. Previous results of the authors are extended to the long-range case and the results the authors previously proved for high-momenta long-range scattering for the Schrödinger equation are brought to the relativistic scenario. It is shown that there are important differences between relativistic and non-relativistic scattering concerning the long range. In particular, it is proven that the electric potential can be recovered without assuming the knowledge of the long-range part of the magnetic potential, which has to be supposed in the non-relativistic case. The electric potential and the magnetic field are recovered from the high-momenta limit of the scattering operator, as well as fluxes modulo 2π around the handles of the obstacle. Moreover, it is proven that for every \\hat{{v}}\\in {{{S}}}2, {A}∞ (\\hat{{v}})+{A}∞ (-\\hat{{v}}) can be reconstructed, where {A}∞ is the long-range part of the magnetic potential. A simple formula for the high-momenta limit of the scattering operator is given in terms of magnetic fluxes over handles of the obstacle and long-range magnetic fluxes at infinity, that are introduced in this paper. The appearance of these long-range magnetic fluxes is a new effect in scattering theory. Research partially supported by the project PAPIIT-DGAPA UNAM IN102215.
A Klein-Gordon acoustic theory
Anno, P.D.
1992-12-01
Geophysicists do not associate traveltime variation with density variation in acoustic or elastic wavefield interpretation. Rather, given a constant index of refraction, density variation within the medium of propagation is associated only with amplitudes. This point of view prevails because density does not occur as a variable in classical results such as Snell's Law or the eikonal equation. Nevertheless, in this paper I predict, analytically, a continuum of density effects on acoustic wavefields-including a dispersive traveltime delay when density variation is rapid. I also examine the ability of a common imaging algorithm to cope with this time delay.
A Klein-Gordon acoustic theory
Anno, P.D.
1992-12-01
Geophysicists do not associate traveltime variation with density variation in acoustic or elastic wavefield interpretation. Rather, given a constant index of refraction, density variation within the medium of propagation is associated only with amplitudes. This point of view prevails because density does not occur as a variable in classical results such as Snell`s Law or the eikonal equation. Nevertheless, in this paper I predict, analytically, a continuum of density effects on acoustic wavefields-including a dispersive traveltime delay when density variation is rapid. I also examine the ability of a common imaging algorithm to cope with this time delay.
A Symmetrical Interpretation of the Klein-Gordon Equation
NASA Astrophysics Data System (ADS)
Heaney, Michael B.
2013-06-01
This paper presents a new Symmetrical Interpretation (SI) of relativistic quantum mechanics which postulates: quantum mechanics is a theory about complete experiments, not particles; a complete experiment is maximally described by a complex transition amplitude density; and this transition amplitude density never collapses. This SI is compared to the Copenhagen Interpretation (CI) for the analysis of Einstein's bubble experiment. This SI makes several experimentally testable predictions that differ from the CI, solves one part of the measurement problem, resolves some inconsistencies of the CI, and gives intuitive explanations of some previously mysterious quantum effects.
Nonlinear instabilities of multi-site breathers in Klein-Gordon lattices
Cuevas-Maraver, Jesus; Kevrekidis, Panayotis G.; Pelinovsky, Dmitry E.
2015-12-14
Here, we explore the possibility of multi-site breather states in a nonlinear Klein–Gordon lattice to become nonlinearly unstable, even if they are found to be spectrally stable. The mechanism for this nonlinear instability is through the resonance with the wave continuum of a multiple of an internal mode eigenfrequency in the linearization of excited breather states. For the nonlinear instability, the internal mode must have its Krein signature opposite to that of the wave continuum. This mechanism is not only theoretically proposed, but also numerically corroborated through two concrete examples of the Klein–Gordon lattice with a soft (Morse) and amore » hard (Φ4) potential. Compared to the case of the nonlinear Schrödinger lattice, the Krein signature of the internal mode relative to that of the wave continuum may change depending on the period of the multi-site breather state. For the periods for which the Krein signatures of the internal mode and the wave continuum coincide, multi-site breather states are observed to be nonlinearly stable.« less
Perturbed Coulomb potentials in the Klein-Gordon equation via the asymptotic iteration method
Barakat, T.
2009-03-15
The asymptotic iteration method is used to construct the exact energy eigenvalues for a Lorentz vector or a Lorentz scalar, and an equally mixed Lorentz vector and Lorentz scalar Coulombic potentials. Highly accurate and rapidly converging ground-state energies for Lorentz vector Coulomb with a Lorentz vector or a Lorentz scalar linear potential, V(r)=-{lambda}{sub 1}/r+krandV(r)=-{lambda}{sub 1}/randW(r)=kr, respectively, are obtained.
Nonlinear instabilities of multi-site breathers in Klein-Gordon lattices
Cuevas-Maraver, Jesus; Kevrekidis, Panayotis G.; Pelinovsky, Dmitry E.
2015-12-14
Here, we explore the possibility of multi-site breather states in a nonlinear Klein–Gordon lattice to become nonlinearly unstable, even if they are found to be spectrally stable. The mechanism for this nonlinear instability is through the resonance with the wave continuum of a multiple of an internal mode eigenfrequency in the linearization of excited breather states. For the nonlinear instability, the internal mode must have its Krein signature opposite to that of the wave continuum. This mechanism is not only theoretically proposed, but also numerically corroborated through two concrete examples of the Klein–Gordon lattice with a soft (Morse) and a hard (Φ^{4}) potential. Compared to the case of the nonlinear Schrödinger lattice, the Krein signature of the internal mode relative to that of the wave continuum may change depending on the period of the multi-site breather state. For the periods for which the Krein signatures of the internal mode and the wave continuum coincide, multi-site breather states are observed to be nonlinearly stable.
Generalized Klein-Gordon models: behavior around the ground state condensate.
Kuetche, Victor K
2014-07-01
In this work, we investigate the balance between the nonlinear and linear interaction energy of an interparticle anharmonic system in the vicinity of the ground state condensate. As a result, we find that the nonlinear interaction energy is very significant in the vicinity of each degree of freedom. We address some potential applications of the findings to miscellaneous areas of interests such as soliton theory, hydrodynamics, solid state physics, ferromagnetic and ferroelectric domain walls, condensed matter physics, and particle physics, among others. PMID:25122243
NASA Astrophysics Data System (ADS)
Bialynicki-Birula, Iwo
2004-05-01
New solutions in the classical and quantum theory of relativistic charged particles will be presented. They describe a beam of particles guided by an electromagnetic vortex. The beam stabilization is caused by the same mechanism that confines particles in the Paul trap and the Trojan wave packets of electrons in atoms.
Separability of Hamilton-Jacobi and Klein-Gordon equations in general Kerr-NUT-AdS spacetimes
NASA Astrophysics Data System (ADS)
Frolov, Valeri P.; Krtous, Pavel; Kubiznák, David
2007-02-01
We demonstrate the separability of the Hamilton-Jacobi and scalar field equations in general higher dimensional Kerr-NUT-AdS spacetimes. No restriction on the parameters characterizing these metrics is imposed.
NASA Astrophysics Data System (ADS)
Suárez, Abril; Matos, Tonatiuh
2014-02-01
In this paper, the thermal evolution of scalar field dark matter (SFDM) particles at finite cosmological temperatures is studied. Starting with a real SF in a thermal bath and using the one-loop quantum corrections potential, we rewrite Klein-Gordon’s equation in its hydrodynamical representation and study the phase transition of this SF due to a Z2 symmetry breaking of its potential. A very general version of a nonlinear Schrödinger equation is obtained. When introducing Madelung’s representation, the continuity and momentum equations for a non-ideal SFDM fluid are formulated, and the cosmological scenario with the SFDM described in analogy to an imperfect fluid is then considered where dissipative contributions are obtained in a natural way. Additional terms appear in the results compared to those in the classical version commonly used to describe the ΛCDM model, i.e., the ideal fluid. The equations and parameters that characterize the physical properties of the system such as its energy, momentum and viscous flow are related to the temperature of the system, scale factor, Hubble’s expansion parameter and the matter energy density. Finally, some details on how galaxy halos and smaller structures might be able to form by condensation of this SF are given.
Baczewski, Andrew David; Vikram, Melapudi; Shanker, Balasubramaniam; Kempel, Leo
2010-08-27
Diffusion, lossy wave, and Klein–Gordon equations find numerous applications in practical problems across a range of diverse disciplines. The temporal dependence of all three Green’s functions are characterized by an infinite tail. This implies that the cost complexity of the spatio-temporal convolutions, associated with evaluating the potentials, scales as O(Ns2Nt2), where Ns and Nt are the number of spatial and temporal degrees of freedom, respectively. In this paper, we discuss two new methods to rapidly evaluate these spatio-temporal convolutions by exploiting their block-Toeplitz nature within the framework of accelerated Cartesian expansions (ACE). The first scheme identifies a convolution relation inmore » time amongst ACE harmonics and the fast Fourier transform (FFT) is used for efficient evaluation of these convolutions. The second method exploits the rank deficiency of the ACE translation operators with respect to time and develops a recursive numerical compression scheme for the efficient representation and evaluation of temporal convolutions. It is shown that the cost of both methods scales as O(NsNtlog2Nt). Furthermore, several numerical results are presented for the diffusion equation to validate the accuracy and efficacy of the fast algorithms developed here.« less
Baczewski, Andrew David; Vikram, Melapudi; Shanker, Balasubramaniam; Kempel, Leo
2010-08-27
Diffusion, lossy wave, and Klein–Gordon equations find numerous applications in practical problems across a range of diverse disciplines. The temporal dependence of all three Green’s functions are characterized by an infinite tail. This implies that the cost complexity of the spatio-temporal convolutions, associated with evaluating the potentials, scales as O(N_{s}^{2}N_{t}^{2}), where N_{s} and N_{t} are the number of spatial and temporal degrees of freedom, respectively. In this paper, we discuss two new methods to rapidly evaluate these spatio-temporal convolutions by exploiting their block-Toeplitz nature within the framework of accelerated Cartesian expansions (ACE). The first scheme identifies a convolution relation in time amongst ACE harmonics and the fast Fourier transform (FFT) is used for efficient evaluation of these convolutions. The second method exploits the rank deficiency of the ACE translation operators with respect to time and develops a recursive numerical compression scheme for the efficient representation and evaluation of temporal convolutions. It is shown that the cost of both methods scales as O(N_{s}N_{t}log^{2}N_{t}). Furthermore, several numerical results are presented for the diffusion equation to validate the accuracy and efficacy of the fast algorithms developed here.
NASA Astrophysics Data System (ADS)
Wu, Shuang-Qing
2009-03-01
It is shown that the Dirac equation is separable by variables in a five-dimensional rotating Kerr (anti-)de Sitter black hole with two independent angular momenta. A first-order symmetry operator that commutes with the Dirac operator is constructed in terms of a rank-3 Killing Yano tensor whose square is a second-order symmetric Stäckel Killing tensor admitted by the five-dimensional Kerr (anti-)de Sitter spacetime. We highlight the construction procedure of such a symmetry operator. In addition, the first law of black hole thermodynamics has been extended to the case that the cosmological constant can be viewed as a thermodynamical variable.
NASA Astrophysics Data System (ADS)
Sammelson, Robert Erik; Heidari, Alireza; Tayyari, Sayyed Faramarz
2010-05-01
This article has been retracted at the request of the Editor-in-Chief and Author. Please see Elsevier Policy on Article Withdrawal. Reason: The authors have plagiarized part of a paper that had already appeared in Iranian Journal of Physics Research. One of the conditions of submission of a paper for publication is that authors declare explicitly that their work is original and has not appeared in a publication elsewhere. Re-use of any data should be appropriately cited. As such this article represents a severe abuse of the scientific publishing system. The scientific community takes a very strong view on this matter and we apologize to readers of the journal that this was not detected during the submission process.
Bialynicki-Birula, Iwo
2004-07-01
It is shown that electromagnetic vortices can act as beam guides for charged particles. The confinement in the transverse directions is due to the rotation of the electric and magnetic fields around the vortex line. A large class of exact solutions describing various types of relativistic beams formed by an electromagnetic wave with a simple vortex line is found both in the classical and in the quantum case. In the second case, the motion in the transverse direction is fully quantized. Particle trajectories trapped by a vortex are very similar to those in a helical undulator. PMID:15323882
Relative unitary implementability of perturbed quantum field dynamics on de-Sitter space
NASA Astrophysics Data System (ADS)
Poon, Gary K.
In this article, we study the quantum dynamics of a Klein-Gordon field on de-Sitter space. We prove time evolution is not unitarily implementable. We also consider a Klein-Gordon field perturbed by a local potential V. In this case we prove that the deviation from the V = 0 dynamics is unitarily implementable.
NASA Astrophysics Data System (ADS)
Woltjer, L.
1987-06-01
En la reunion celebrada en diciembre dei ano pasado informe al Consejo de mi deseo de terminar mi contrato como Director General de la ESO una vez que fuera aprobado el proyecto dei VLT, que se espera sucedera hacia fines de este aAo. Cuando fue renovada mi designacion hace tres aAos, el Consejo conocia mi intencion de no completar los cinco aAos dei contrato debido a mi deseo de disponer de mas tiempo para otras actividades. Ahora, una vez terminada la fase preparatoria para el VLT, Y habiendose presentado el proyecto formalmente al Consejo el dia 31 de marzo, y esperando su muy probable aprobacion antes dei termino de este ano, me parece que el 10 de enero de 1988 presenta una excelente fecha para que se produzca un cambio en la administracion de la ESO.
Noncommutativity and the Friedmann Equations
NASA Astrophysics Data System (ADS)
Sabido, M.; Guzmán, W.; Socorro, J.
2010-07-01
In this paper we study noncommutative scalar field cosmology, we find the noncommutative Friedmann equations as well as the noncommutative Klein-Gordon equation, interestingly the noncommutative contributions are only present up to second order in the noncommutitive parameter.
Hawking Temperature of an Arbitrarily Accelerating Black Hole
NASA Astrophysics Data System (ADS)
Pan, Wei-Zhen; Liu, Wei
2014-09-01
Hawking temperature of an arbitrarily accelerating black hole with electric and magnetic charges are obtained based on the Klein-Gordon equation with a correct-dimension new tortoise coordinate transformation.
Superradiance from a charged dilation black hole
Shiraishi, K. )
1992-12-07
In this paper, the authors study the behavior of the wave function of charged Klein-Gordon field around a charge dilaton black hole. The rate of spontaneous charge loss is estimated for large black hole case.
Dielectric permittivity of quantum plasma. Part I
NASA Astrophysics Data System (ADS)
Bobylev, Yu. V.; Kuzelev, M. V.
2014-05-01
Collisionless quantum plasma models based on the Schröbinger, Klein-Gordon, Dirac, and Pauli equations are considered. The transverse and longitudinal dielectric permittivities of isotropic quantum plasma are calculated in the frameworks of the models based on the Schröbinger and Klein-Gordon equations without allowance for the particle spin. Dispersion relations for transverse-longitudinal waves in beams of spinless quantum particles are derived, and the simplest quantum waves are analyzed.
Quantum Radiation of a Non-stationary Kerr Newman Black Hole in de Sitter Space Time
NASA Astrophysics Data System (ADS)
Jiang, Qing-Quan; Yang, Shu-Zheng
2006-12-01
Hawking radiation of Klein-Gordon and Dirac particles in a non-stationary Kerr-Newman-de-Sitter black hole is studied by introducing a new tortoise coordinate transformation. The result shows that the Fermi-Dirac radiant spectrum displays a new term that represents the interaction between the spin of spinor particles and the rotation of black holes, which is absent in the Bose-Einstein distribution of Klein-Gordon particles.
A Lagrangian for mass dimension one fermionic dark matter
NASA Astrophysics Data System (ADS)
Lee, Cheng-Yang
2016-09-01
The mass dimension one fermionic field associated with Elko satisfies the Klein-Gordon but not the Dirac equation. However, its propagator is not a Green's function of the Klein-Gordon operator. We propose an infinitesimal deformation to the propagator such that it admits an operator in which the deformed propagator is a Green's function. The field is still of mass dimension one, but the resulting Lagrangian is modified in accordance with the operator.
Hawking radiation of scalars from accelerating and rotating black holes with NUT parameter
NASA Astrophysics Data System (ADS)
Jan, Khush; Gohar, H.
2014-03-01
We study the quantum tunneling of scalars from charged accelerating and rotating black hole with NUT parameter. For this purpose we use the charged Klein-Gordon equation. We apply WKB approximation and the Hamilton-Jacobi method to solve charged Klein-Gordon equation. We find the tunneling probability of outgoing charged scalars from the event horizon of this black hole, and hence the Hawking temperature for this black hole
Separating para and ortho water.
Horke, Daniel A; Chang, Yuan-Pin; Długołęcki, Karol; Küpper, Jochen
2014-10-27
Water exists as two nuclear-spin isomers, para and ortho, determined by the overall spin of its two hydrogen nuclei. For isolated water molecules, the conversion between these isomers is forbidden and they act as different molecular species. Yet, these species are not readily separated, and no pure para sample has been produced. Accordingly, little is known about their specific physical and chemical properties, conversion mechanisms, or interactions. The production of isolated samples of both spin isomers is demonstrated in pure beams of para and ortho water in their respective absolute ground state. These single-quantum-state samples are ideal targets for unraveling spin-conversion mechanisms, for precision spectroscopy and fundamental symmetry-breaking studies, and for spin-enhanced applications, for example laboratory astrophysics and astrochemistry or hypersensitized NMR experiments. PMID:25196938
El astronauta de la NASA José Hernández alienta a los estudiantes a que sigan sus sueños. Hernández también habla acerca del papel que juegan los padres para ayudar a que sus hijos hagan realidad s...
NASA Astrophysics Data System (ADS)
Belich, H.; Bakke, K.
2016-03-01
The behavior of a relativistic scalar particle subject to a scalar potential under the effects of the violation of the Lorentz symmetry in the cosmic string space-time is discussed. It is considered two possible scenarios of the Lorentz symmetry breaking in the CPT-even gauge sector of the Standard Model Extension defined by a tensor (KF)μναβ. Then, by introducing a scalar potential as a modification of the mass term of the Klein-Gordon equation, it is shown that the Klein-Gordon equation in the cosmic string space-time is modified by the effects of the Lorentz symmetry violation backgrounds and bound state solution to the Klein-Gordon equation can be obtained.
The two faces of sound in BECs
NASA Astrophysics Data System (ADS)
Barceló, C.; Garay, L. J.; Jannes, G.
2010-12-01
Fluctuations around a Bose-Einstein condensate can be described by means of Bogolubov theory leading to the notion of quasiparticle and antiquasiparticle familiar to non-relativistic condensed matter practitioners. On the other hand, we already know that these perturbations evolve according to a relativistic Klein-Gordon equation in the long wavelength approximation. For shorter wavelengths, we show that this equation acquires nontrivial corrections which modify the Klein-Gordon product. In this approach, quasiparticles can also be defined (up to the standard ambiguities due to observer-dependence). We demonstrate that—in the low as well as in the high energy regimes—both concepts of quasiparticle are actually the same, regardless of the formalism (Bogolubov or Klein-Gordon) used to describe them. These results also apply to any barotropic, inviscid, irrotational fluid, with or without quantum potential.
NASA Astrophysics Data System (ADS)
Ikhdair, Sameer; Sever, Ramazan
2008-03-01
The Klein-Gordon equation in D-dimensions for a recently proposed ring-shaped Kratzer potential is solved analytically by means of the conventional Nikiforov-Uvarov method. The exact energy bound states and the corresponding wave functions of the Klein-Gordon are obtained in the presence of the non-central equal scalar and vector potentials. The results obtained in this work are more general and can be reduced to the standard forms in three dimensions given by other works.
Uniqueness of conserved currents in quantum mechanics
NASA Astrophysics Data System (ADS)
Holland, P.
2003-10-01
It is proved by a functional method that the conventional expression for the Dirac current is the only conserved 4-vector implied by the Dirac equation that is a function of just the quantum state. The demonstration is extended to derive the unique conserved currents implied by the coupled Maxwell-Dirac equations and the Klein-Gordon equation. The uniqueness of the usual Pauli and Schrödinger currents follows by regarding these as the non-relativistic limits of the Dirac and Klein-Gordon currents, respectively. The existence and properties of further conserved vectors that are not functions of just the state is examined.
Massless Spin-Zero Particle and the Classical Action via Hamilton-Jacobi Equation in Gödel Universe
NASA Astrophysics Data System (ADS)
Bahrehbakhsh, A. F.; Momeni, D.; Myrzakulov, R.
2012-08-01
In this letter we investigate the separability of the Klein-Gordon and Hamilton-Jacobi equation in Gödel universe. We show that the Klein-Gordon eigen modes are quantized and the complete spectrum of the particle's energy is a mixture of an azimuthal quantum number, m and a principal quantum number, n and a continuous wave number k. We also show that the Hamilton-Jacobi equation gives a closed function for classical action. These results may be used to calculate the Casimir vacuum energy in Gödel universe.
Functional Expression of Drosophila para Sodium Channels
Warmke, Jeffrey W.; Reenan, Robert A.G.; Wang, Peiyi; Qian, Su; Arena, Joseph P.; Wang, Jixin; Wunderler, Denise; Liu, Ken; Kaczorowski, Gregory J.; Ploeg, Lex H.T. Van der; Ganetzky, Barry; Cohen, Charles J.
1997-01-01
The Drosophila para sodium channel α subunit was expressed in Xenopus oocytes alone and in combination with tipE, a putative Drosophila sodium channel accessory subunit. Coexpression of tipE with para results in elevated levels of sodium currents and accelerated current decay. Para/TipE sodium channels have biophysical and pharmacological properties similar to those of native channels. However, the pharmacology of these channels differs from that of vertebrate sodium channels: (a) toxin II from Anemonia sulcata, which slows inactivation, binds to Para and some mammalian sodium channels with similar affinity (Kd ≅ 10 nM), but this toxin causes a 100-fold greater decrease in the rate of inactivation of Para/TipE than of mammalian channels; (b) Para sodium channels are >10-fold more sensitive to block by tetrodotoxin; and (c) modification by the pyrethroid insecticide permethrin is >100-fold more potent for Para than for rat brain type IIA sodium channels. Our results suggest that the selective toxicity of pyrethroid insecticides is due at least in part to the greater affinity of pyrethroids for insect sodium channels than for mammalian sodium channels. PMID:9236205
Laparoscopic extraperitoneal para-aortic lymphadenectomy
Iserte, Pablo Padilla; Minig, Lucas; Zorrero, Cristina
2015-01-01
Lymph nodes are the main pathway in the spread of gynaecological malignancies, being a well-known prognostic factor. Lymph node dissection is a complex surgical procedure and requires surgical expertise to perform the procedure, thereby minimising complications. In addition, lymphadenectomy has value in the diagnosis, prognosis, and treatment of patients with gynaecologic cancer. Therefore, a video focused on the para-aortic retroperitoneal anatomy and the surgical technique of the extraperitoneal para-aortic lymphadenectomy is presented. PMID:26435746
Process for para-ethyltoluene dehydrogenation
Chu, C.C.
1986-06-03
A process is described of dehydrogenating para-ethyltoluene to selectively form para-methylstyrene comprising contacting to para-ethyltoluene under dehydrogenation reaction conditions with a catalyst composition comprising: (a) from about 30% to 60% by weight of iron oxide, calculated as ferric oxide; (b) from about 13% to 48% by weight of a potassium compound, calculated as potassium oxide; and (c) from about 0% to 5% by weight of a chromium compound, calculated as chromic oxide. The improvement is described comprising dehydrogenating the para-ethyltoluene with a catalyst composition comprising, in addition to the components (a), (b) and (c), a modifying component (d) capable of rendering the para-methylstyrene-containing dehydrogenation reaction effluent especially resistant to the subsequent formation of popcorn polymers when the dehydrogenation of para-ethyltoluene is conducted over the modified catalyst, the modifying component (d) being a bismuth compound present to the extent of from about 1% to 20% by weight of the catalyst composition, calculated as bismuth trioxide.
Nuevos aspectos en el estudio de la particula D en el experimento FOCUS de Fermilab
Quinones Gonzalez, Jose A.; /Puerto Rico U., Mayaguez
2005-01-01
The purpose of this work is to improve the reconstruction techniques of the decays of the particles that contain charm in the quark composition using the information of the Target Silicon Detector of the experiment E831 (FOCUS). That experiment runs during 1997 to 1998 in Fermilab National Laboratory. The objective of the experiment was improving the understanding of the particles that contain charm. Adding the Target Silicon Detector information in the reconstruction process of the primary vertex the position error. This reduction produces an improvement in the mass signal and the knowledge of the charm particles properties. This ad to the possibility's that in other analysis will use the techniques developed in this work.
The ParaScope parallel programming environment
NASA Technical Reports Server (NTRS)
Cooper, Keith D.; Hall, Mary W.; Hood, Robert T.; Kennedy, Ken; Mckinley, Kathryn S.; Mellor-Crummey, John M.; Torczon, Linda; Warren, Scott K.
1993-01-01
The ParaScope parallel programming environment, developed to support scientific programming of shared-memory multiprocessors, includes a collection of tools that use global program analysis to help users develop and debug parallel programs. This paper focuses on ParaScope's compilation system, its parallel program editor, and its parallel debugging system. The compilation system extends the traditional single-procedure compiler by providing a mechanism for managing the compilation of complete programs. Thus, ParaScope can support both traditional single-procedure optimization and optimization across procedure boundaries. The ParaScope editor brings both compiler analysis and user expertise to bear on program parallelization. It assists the knowledgeable user by displaying and managing analysis and by providing a variety of interactive program transformations that are effective in exposing parallelism. The debugging system detects and reports timing-dependent errors, called data races, in execution of parallel programs. The system combines static analysis, program instrumentation, and run-time reporting to provide a mechanical system for isolating errors in parallel program executions. Finally, we describe a new project to extend ParaScope to support programming in FORTRAN D, a machine-independent parallel programming language intended for use with both distributed-memory and shared-memory parallel computers.
Oxidative para-triflation of acetanilides.
Pialat, Amélie; Liégault, Benoît; Taillefer, Marc
2013-04-01
Direct triflation of acetanilide derivatives with silver triflate has been accomplished under mild iodine(III)-mediated oxidative conditions. The reaction shows excellent regioselectivity for the para position and tolerates a range of ortho and meta substituents on the aromatic ring. This method is also compatible with the preparation of arylnonaflates in synthetically useful yields. PMID:23534500
FDA aprueba la primera inmunoterapia para linfoma
La FDA ha aprobado nivolumab (Opdivo®) para el tratamiento de pacientes con el linfoma clásico de Hodgkin que ha recaído o empeorado después de recibir un trasplante autólogo hematopoyético seguido de brentuximab vedotin (Adcetris®)
Notes on oscillator-like interactions of various spin relativistic particles
NASA Technical Reports Server (NTRS)
Dvoeglazov, Valeri V.; Delsolmesa, Antonio
1995-01-01
The equations for various spin particles with oscillator-like interactions are discussed in this talk. Topics discussed include: (1) comment on 'The Klein-Gordon Oscillator'; (2) the Dirac oscillator in quaternion form; (3) the Dirac-Dowker oscillator; (4) the Weinberg oscillator; and (5) note on the two-body Dirac oscillator.
Hawking Temperature of Acoustic Black Hole
NASA Astrophysics Data System (ADS)
Xie, Zhi Kun
2014-09-01
Using a new tortoise coordinate transformation, the Hawking radiation of the acoustic black hole was discussed by studying the Klein-Gordon equation of scalar particles in the curve space-time. It was found that the Hawking temperature is connected with time and position on the event horizon.
A new method dealing with hawking effects of evaporating black holes
Zhao, Z.; Dai, X. )
1992-06-28
This paper reports that, both the location and the temperature of event horizons of evaporating black holes can be easily given if one proposes the Klein-Gordon equation approaches the standard form of wave equation near event horizons by using tortoise-type coordinates.
Relativistic wave mechanics of spinless particles in a curved space-time.
NASA Astrophysics Data System (ADS)
Cognola, G.; Vanzo, L.; Zerbini, S.
1986-09-01
Starting from the Klein-Gordon equation, the single-particle approximation for a reiativistic scalar particle in the presence of external electromagnetic and gravitational fields is performed. The nonrelativistic limit is obtained by a Foldy-Wouthuysen transformation on a Schrödinger-type equation. The results are then compared with those obtained in classical mechanics.
Positive particle frequencies in some time-periodic universes
NASA Astrophysics Data System (ADS)
Droz-Vincent, Philippe
1996-03-01
We consider the Klein-Gordon equation in FRW-like universes which are periodic in a suitable scale of time. In a remarkable sector of solutions, the Floquet theory of differential equations allows for generalizing the notion of particle frequency. In this sense, the sesquilinear form associated with Gordon's current is positive definite when restricted to the sub-sector of positive frequencies.
Lower bounds for sums of eigenvalues of elliptic operators and systems
Ilyin, Aleksei A
2013-04-30
Two-term lower bounds of Berzin-Li-Yau type are obtained for the sums of eigenvalues of elliptic operators and systems with constant coefficients and Dirichlet boundary conditions. The polyharmonic operator, the Stokes system and its generalizations, the two-dimensional buckling problem, and also the Klein-Gordon operator are considered. Bibliography: 32 titles.
Scalar field conformally coupled to a charged BTZ black hole
NASA Astrophysics Data System (ADS)
Valtancoli, P.
2016-06-01
We study the Klein-Gordon equation of a scalar field conformally coupled to a charged BTZ black hole. The background metric is obtained by coupling a non-linear and conformal invariant Maxwell field to (2 + 1) gravity. We show that the radial part is generally solved by a Heun function and, in the pure gravity limit, by a hypergeometric function.
Non-commutative relativistic equation with a Coulomb potential
Zaim, Slimane; Khodja, Lamine; Delenda, Yazid
2012-06-27
We improve the previous study of the Klein-Gordon equation in a non-commutative space-time as applied to the Hydrogen atom to extract the energy levels, by considering the secondorder corrections in the non-commutativity parameter. Phenomenologically we show that noncommutativity plays the role of spin.
Emission of scalar particles from cylindrical black holes
NASA Astrophysics Data System (ADS)
Gohar, H.; Saifullah, K.
2013-01-01
We study quantum tunneling of scalar particles from black strings. For this purpose we apply WKB approximation and Hamilton-Jacobi method to solve the Klein-Gordon equation for outgoing trajectories. We find the tunneling probability of outgoing charged and uncharged scalars from the event horizon of black strings, and hence the Hawking temperature for these black configurations.
Scalar field radiation from dilatonic black holes
NASA Astrophysics Data System (ADS)
Gohar, H.; Saifullah, K.
2012-12-01
We study radiation of scalar particles from charged dilaton black holes. The Hamilton-Jacobi method has been used to work out the tunneling probability of outgoing particles from the event horizon of dilaton black holes. For this purpose we use WKB approximation to solve the charged Klein-Gordon equation. The procedure gives Hawking temperature for these black holes as well.
Plasma analog of particle-pair production
Tsidulko, Yu.A.; Berk, H.L.
1996-09-01
It is shown that the plasma axial shear flow instability satisfies the Klein-Gordon equation. The plasma instability is then shown to be analogous to spontaneous particle-pair production when a potential energy is present that is greater than twice the particle rest mass energy. Stability criteria can be inferred based on field theoretical conservation laws.
Notes on oscillator-like interactions of various spin relativistic particles
Dvoeglazov, V.V.; Delsolmesa, A.
1995-01-01
The equations for various spin particles with oscillator-like interactions are discussed in this talk. Topics discussed include: (1) comment on `The Klein-Gordon Oscillator`; (2) the Dirac oscillator in quaternion form; (3) the Dirac-Dowker oscillator; (4) the Weinberg oscillator; and (5) note on the two-body Dirac oscillator.
Method of Improving the Teaching of Particle Physics in a Noncalculus Course of Physics
NASA Astrophysics Data System (ADS)
Chen, Robert L. W.
The Klein Gordon equation-which describes mesons-can be reformulated to suit students who have no calculus background. The method is arrived at from a review and a reinterpretation of the mechanics of small oscillations. It may serve as a model for the design of new instructions for other areas of particle physics.
Centro para la Salud Mundial (CGH) del NCI
El Centro para la Salud Mundial (CGH) del NCI coordina actividades de investigación y trabaja con socios nacionales e internacionales para comprender y enfrentar la carga que representa el cáncer a nivel mundial.
Para-hydrogen perspectives in hyperpolarized NMR.
Glöggler, Stefan; Colell, Johannes; Appelt, Stephan
2013-10-01
The first instance of para-hydrogen induced polarization (PHIP) in an NMR experiment was serendipitously observed in the 1980s while investigating a hydrogenation reaction (Seldler et al., 1983; Bowers and Weitekamp, 1986, 1987; Eisenschmid et al., 1987) [1-4]. Remarkably a theoretical investigation of the applicability of para-hydrogen as a hyperpolarization agent was being performed in the 1980's thereby quickly providing a theoretical basis for the PHIP-effect (Bowers and Weitekamp, 1986) [2]. The discovery of signal amplification by a non-hydrogenating interaction with para-hydrogen has recently extended the interest to exploit the PHIP effect, as it enables investigation of compounds without structural alteration while retaining the advantages of spectroscopy with hyperpolarized compounds [5]. In this article we will place more emphasis of the future applications of the method while only briefly discussing the efforts that have been made in the understanding of the phenomenon and the development of the method so far. PMID:23932399
Allergic contact dermatitis to para-phenylenediamine.
Jenkins, David; Chow, Elizabeth T
2015-02-01
Exposure to hair dye is the most frequent route of sensitisation to para-phenylenediamine (PPD), a common contact allergen. International studies have examined the profile of PPD, but Australian-sourced information is lacking. Patients are often dissatisfied with advice to stop dyeing their hair. This study examines patients' characteristics, patch test results and outcomes of PPD allergy from a single Australian centre, through a retrospective analysis of patch test data from 2006 to 2013 at the Liverpool Hospital Dermatology Department. It reviews the science of hair dye allergy, examines alternative hair dyes and investigates strategies for hair dyeing. Of 584 patients, 11 were allergic to PPD. Our PPD allergy prevalence rate of 2% is at the lower end of international reported rates. About half these patients also react to para-toluenediamine (PTD). Affected patients experience a significant lifestyle disturbance. In all, 78% tried alternative hair dyes after the patch test diagnosis and more than half continued to dye their hair. Alternative non-PPD hair dyes are available but the marketplace can be confusing. Although some patients are able to tolerate alternative hair dyes, caution is needed as the risk of developing an allergy to other hair dye ingredients, especially PTD, is high. PMID:25302475
On Lightlike Geometry of Para-Sasakian Manifolds
Acet, Bilal Eftal; Kılıç, Erol
2014-01-01
We study lightlike hypersurfaces of para-Sasakian manifolds tangent to the characteristic vector field. In particular, we define invariant lightlike hypersurfaces and screen semi-invariant lightlike hypersurfaces, respectively, and give examples. Integrability conditions for the distributions on a screen semi-invariant lightlike hypersurface of para-Sasakian manifolds are investigated. We obtain a para-Sasakian structure on the leaves of an integrable distribution of a screen semi-invariant lightlike hypersurface. PMID:24892072
Dipolar induced para-hydrogen-induced polarization.
Buntkowsky, Gerd; Gutmann, Torsten; Petrova, Marina V; Ivanov, Konstantin L; Bommerich, Ute; Plaumann, Markus; Bernarding, Johannes
2014-01-01
Analytical expressions for the signal enhancement in solid-state PHIP NMR spectroscopy mediated by homonuclear dipolar interactions and single pulse or spin-echo excitation are developed and simulated numerically. It is shown that an efficient enhancement of the proton NMR signal in solid-state NMR studies of chemisorbed hydrogen on surfaces is possible. Employing typical reaction efficacy, enhancement-factors of ca. 30-40 can be expected both under ALTADENA and under PASADENA conditions. This result has important consequences for the practical application of the method, since it potentially allows the design of an in-situ flow setup, where the para-hydrogen is adsorbed and desorbed from catalyst surfaces inside the NMR magnet. PMID:25218522
Cooling by Para-to-Ortho-Hydrogen Conversion
NASA Technical Reports Server (NTRS)
Sherman, A.; Nast, T.
1983-01-01
Catalyst speeds conversion, increasing capacity of solid hydrogen cooling system. In radial-flow catalytic converter, para-hydrogen is converted to equilibrium mixture of para-hydrogen and ortho-hydrogen as it passes through porous cylinder of catalyst. Addition of catalyst increases capacity of hydrogen sublimation cooling systems for radiation detectors.
Requisitos para utilizar el enlace | Smokefree Español
Espanol.smokefree.gov ofrece apoyo y recursos para norteamericanos que hablan español y quieren dejar de fumar. Este sitio en la red fue creada por la División de Investigación para el Control del Tabaco del Instituto Nacional del Cáncer.
Construction of a Para-Ortho Hydrogen Test Cryostat
NASA Astrophysics Data System (ADS)
Essler, J.; Haberstroh, Ch.
2010-04-01
In a prospective hydrogen economy it is necessary to verify the para concentration of the employed hydrogen. In case of a short storage time of about a few days only it has been shown that a partial conversion into para-hydrogen gives an optimized overall efficiency. Hence, an easy and reliable method of measuring the para-hydrogen concentration is needed. In this paper, the concept and construction of a small test cryostat are described and first results are presented. The measuring principle is based on a catalytic induced adiabatic ortho-para conversion of a hydrogen gas flow starting from a known temperature. The operation of the system only requires a certain amount of liquid nitrogen as coolant. To determine the concentration of para-hydrogen it is only necessary to measure the temperature of the gas before and after the adiabatic catalyst cell. The measuring cryostat is used for further investigation of the spontaneous para-ortho conversion in the supercritical state. In addition, the design of the cryostat allows the investigation of different catalyst materials regarding the catalytic activity and possible degradation by using a known para concentration for the measurement.
a New Equation of State for Solid para-HYDROGEN
NASA Astrophysics Data System (ADS)
Wang, Lecheng; Le Roy, Robert J.; Roy, Pierre-Nicholas
2015-06-01
Solid para-H_2 is a popular accommodating host for impurity spectroscopy due to its unique softness and the spherical symmetry of para-H_2 in its J}=0 rotational level. To simulate the properties of impurity-doped solid para-H_2, a reliable model for the `soft' pure solid para-H_2 at different pressures is highly desirable. While a couple of experimental and theoretical studies aimed at elucidating the equation of state (EOS) of solid para-H_2 have been reported, the calculated EOS was shown to be heavily dependent on the potential energy surface (PES) between two para-H_2 that was used in the simulations. The current study also demonstrates that different choices of the parameters governing the Quantum Monte Carlo simulation could produce different EOS curves. To obtain a reliable model for pure solid para-H_2, we used a new 1-D para-H_2 PES reported by Faruk et al. that was obtained by averaging over Hinde's highly accurate 6-D H_2--H_2 PES. The EOS of pure solid para-H_2 was calculated using the PIMC algorithm with periodic boundary conditions (PBC). To precisely determine the equilibrium density of solid para-H_2, both the value of the PIMC time step (τ) and the number of particles in the PBC cell were extrapolated to convergence. The resulting EOS agreed well with experimental observations, and the hcp structured solid para-H_2 was found to be more stable than the fcc one at 4.2K, in agreement with experiment. The vibrational frequency shift of para-H_2 as a function of the density of the pure solid was also calculated, and the value of the shift at the equilibrium density is found to agree well with experiment. T. Momose, H. Honshina, M. Fushitani and H. Katsuki, Vib. Spectrosc. 34, 95(2004). M. E. Fajardo, J. Phys. Chem. A 117, 13504 (2013). I. F. Silvera, Rev. Mod. Phys. 52, 393(1980). F. Operetto and F. Pederiva, Phys. Rev. B 73, 184124(2006). T. Omiyinka and M. Boninsegni, Phys. Rev. B 88, 024112(2013). N. Faruk, M. Schmidt, H. Li, R. J. Le Roy, and P
ParaDiS-FEM dislocation dynamics simulation code primer
Tang, M; Hommes, G; Aubry, S; Arsenlis, A
2011-09-27
The ParaDiS code is developed to study bulk systems with periodic boundary conditions. When we try to perform discrete dislocation dynamics simulations for finite systems such as thin films or cylinders, the ParaDiS code must be extended. First, dislocations need to be contained inside the finite simulation box; Second, dislocations inside the finite box experience image stresses due to the free surfaces. We have developed in-house FEM subroutines to couple with the ParaDiS code to deal with free surface related issues in the dislocation dynamics simulations. This primer explains how the coupled code was developed, the main changes from the ParaDiS code, and the functions of the new FEM subroutines.
Cooling by conversion of para to ortho-hydrogen
NASA Technical Reports Server (NTRS)
Sherman, A. (Inventor)
1983-01-01
The cooling capacity of a solid hydrogen cooling system is significantly increased by exposing vapor created during evaporation of a solid hydrogen mass to a catalyst and thereby accelerating the endothermic para-to-ortho transition of the vapor to equilibrium hydrogen. Catalyst such as nickel, copper, iron or metal hydride gels of films in a low pressure drop catalytic reactor are suitable for accelerating the endothermic para-to-ortho conversion.
Para hydrogen equilibration in the atmospheres of the outer planets
NASA Technical Reports Server (NTRS)
Conrath, Barney J.
1986-01-01
The thermodynamic behavior of the atmospheres of the Jovian planets is strongly dependent on the extent to which local thermal equilibration of the ortho and para states of molecular hydrogen is achieved. Voyager IRIS data from Jupiter imply substantial departures of the para hydrogen fraction from equilibrium in the upper troposphere at low latitudes, but with values approaching equilibrium at higher latitudes. Data from Saturn are less sensitive to the orth-para ratio, but suggest para hydrogen fractions near the equilibrium value. Above approximately the 200 K temperature level, para hydrogen conversion can enhance the efficiency of convection, resulting in a substantial increase in overturning times on all of the outer planets. Currently available data cannot definitively establish the ortho-para ratios in the atmospheres of Uranus and Neptune, but suggest values closer to local equilibrium than to the 3.1 normal ratio. Modeling of sub-millimeter wavelength measurements of these planets suggest thermal structures with frozen equilibrium lapse rates in their convective regions.
A Comparative Usage-Based Approach to the Reduction of the Spanish and Portuguese Preposition "Para"
ERIC Educational Resources Information Center
Gradoville, Michael Stephen
2013-01-01
This study examines the frequency effect of two-word collocations involving "para" "to," "for" (e.g. "fui para," "para que") on the reduction of "para" to "pa" (in Spanish) and "pra" (in Portuguese). Collocation frequency effects demonstrate that language speakers…
ParaText : scalable text modeling and analysis.
Dunlavy, Daniel M.; Stanton, Eric T.; Shead, Timothy M.
2010-06-01
Automated processing, modeling, and analysis of unstructured text (news documents, web content, journal articles, etc.) is a key task in many data analysis and decision making applications. As data sizes grow, scalability is essential for deep analysis. In many cases, documents are modeled as term or feature vectors and latent semantic analysis (LSA) is used to model latent, or hidden, relationships between documents and terms appearing in those documents. LSA supplies conceptual organization and analysis of document collections by modeling high-dimension feature vectors in many fewer dimensions. While past work on the scalability of LSA modeling has focused on the SVD, the goal of our work is to investigate the use of distributed memory architectures for the entire text analysis process, from data ingestion to semantic modeling and analysis. ParaText is a set of software components for distributed processing, modeling, and analysis of unstructured text. The ParaText source code is available under a BSD license, as an integral part of the Titan toolkit. ParaText components are chained-together into data-parallel pipelines that are replicated across processes on distributed-memory architectures. Individual components can be replaced or rewired to explore different computational strategies and implement new functionality. ParaText functionality can be embedded in applications on any platform using the native C++ API, Python, or Java. The ParaText MPI Process provides a 'generic' text analysis pipeline in a command-line executable that can be used for many serial and parallel analysis tasks. ParaText can also be deployed as a web service accessible via a RESTful (HTTP) API. In the web service configuration, any client can access the functionality provided by ParaText using commodity protocols ... from standard web browsers to custom clients written in any language.
Bosonic pair creation and the Schiff-Snyder-Weinberg effect
NASA Astrophysics Data System (ADS)
Lv, Q. Z.; Bauke, Heiko; Su, Q.; Keitel, C. H.; Grobe, R.
2016-01-01
Interactions between different bound states in bosonic systems can lead to pair creation. We study this process in detail by solving the Klein-Gordon equation on space-time grids in the framework of time-dependent quantum field theory. By choosing specific external field configurations, two bound states can become pseudodegenerate, which is commonly referred to as the Schiff-Snyder-Weinberg effect. These pseudodegenerate bound states, which have complex energy eigenvalues, are related to the pseudo-Hermiticity of the Klein-Gordon Hamiltonian. In this work, the influence of the Schiff-Snyder-Weinberg effect on pair production is studied. A generalized Schiff-Snyder-Weinberg effect, where several pairs of pseudodegenerate states appear, is found in combined electric and magnetic fields. The generalized Schiff-Snyder-Weinberg effect likewise triggers pair creation. The particle number in these situations obeys an exponential growth law in time enhancing the creation of bosons, which cannot be found in fermionic systems.
Photon mirror acceleration in the quantum regime
Mendonça, J. T.; Fedele, R.
2014-12-15
Reflection of an electron beam by an intense laser pulse is considered. This is the so-called photon mirror configuration for laser acceleration in vacuum, where the energy of the incident electron beam is nearly double-Doppler shifted due to reflection on the laser pulse front. A wave-electron optical description for electron reflection and resonant backscattering, due to both linear electric field force and quadratic ponderomotive force, is provided beyond the paraxial approximation. This is done by assuming that the single electron of the beam is spin-less and therefore its motion can be described by a quantum scalar field whose spatiotemporal evolution is governed by the Klein-Gordon equation (Klein-Gordon field). Our present model, not only confirms the classical results but also shows the occurrence of purely quantum effects, such as partial reflection of the incident electron beam and enhanced backscattering due to Bragg resonance.
Bose-Einstein condensates and scalar fields; exploring the similitudes
NASA Astrophysics Data System (ADS)
Castellanos, E.; Macías, A.; Núñez, D.
2014-01-01
We analyze the the remarkable analogy between the classical Klein-Gordon equation for a test scalar field in a flat and also in a curved background, and the Gross-Pitaevskii equation for a Bose-Einstein condensate trapped by an external potential. We stress here that the solution associated with the Klein-Gordon equation (KG) in a flat space time has the same mathematical structure, under certain circumstances, to those obtained for the Gross-Pitaevskii equation, that is, a static soliton solution. Additionally, Thomas-Fermi approximation is applied to the 3-dimensional version of this equation, in order to calculate some thermodynamical properties of the system in curved a space-time back ground. Finally, we stress the fact that a gravitational background provides, in some cases, a kind of confining potential for the scalar field, allowing us to remarks even more the possible connection between scalar fields and the phenomenon of Bose-Einstein condensation.
Second order perturbations during inflation beyond slow-roll
Huston, Ian; Malik, Karim A. E-mail: k.malik@qmul.ac.uk
2011-10-01
We numerically calculate the evolution of second order cosmological perturbations for an inflationary scalar field without resorting to the slow-roll approximation or assuming large scales. In contrast to previous approaches we therefore use the full non-slow-roll source term for the second order Klein-Gordon equation which is valid on all scales. The numerical results are consistent with the ones obtained previously where slow-roll is a good approximation. We investigate the effect of localised features in the scalar field potential which break slow-roll for some portion of the evolution. The numerical package solving the second order Klein-Gordon equation has been released under an open source license and is available for download.
Nonrelativistic quantum dynamics on a cone with and without a constraining potential
Filgueiras, C.; Silva, E. O.; Andrade, F. M.
2012-12-15
In this paper we investigate the bound state problem of nonrelativistic quantum particles on a conical surface. This kind of surface appears as a topological defect in ordinary semiconductors as well as in graphene sheets. Specifically, we compare and discuss the results stemming from two different approaches. In the first one, it is assumed that the charge carriers are bound to the surface by a constraining potential, while the second one is based on the Klein-Gordon type equation on surfaces, without the constraining potential. The main difference between both theories is the presence/absence of a potential which contains the mean curvature of a given surface. This fact changes the dependence of the bound states on the angular momentum l. Moreover, there are bound states that are absent in the Klein-Gordon theory, which instead appear in the Schroedinger one.
Strong-field Breit-Wheeler pair production in short laser pulses: Relevance of spin effects
NASA Astrophysics Data System (ADS)
Jansen, M. J. A.; Kamiński, J. Z.; Krajewska, K.; Müller, C.
2016-07-01
Production of electron-positron pairs in the collision of a high-energy photon with a high-intensity few-cycle laser pulse is studied. By utilizing the frameworks of laser-dressed spinor and scalar quantum electrodynamics, a comparison between the production of pairs of Dirac and Klein-Gordon particles is drawn. Positron energy spectra and angular distributions are presented for various laser parameters. We identify conditions under which predictions from Klein-Gordon theory either closely resemble or largely differ from those of the proper Dirac theory. In particular, we address the question to which extent the relevance of spin effects is influenced by the short duration of the laser pulse.
Scalar waves in the Witten bubble spacetime
Bhawal, B. Raman Research Institute, Bangalore ); Vishveshwara, C.V. )
1990-09-15
Massless scalar waves in the Witten bubble spacetime are studied. The timelike and angular parts of the separated Klein-Gordon equation are written in terms of hyperbolic harmonics characterized by the generalized frequency {omega}. The radial equation is cast into the Schroedinger form. The above mathematical formulation is applied to study the scattering problem, the bound states, and the corresponding stability criteria. The results confirm the concept of a bubble wall as a perfectly reflecting expanding sphere.
Duality of coordinates and matter fields in curved spacetime
NASA Astrophysics Data System (ADS)
De Andrade, M. A.; Vancea, I. V.
2000-02-01
We show that there exists a duality between the local coordinates and the solutions of the Klein-Gordon equation in curved spacetime in the same sense as in the Minkowski spacetime. However, the duality in curved spacetime does not have the same generality as in flat spacetime and it holds only if the system satisfies certain constraints. We derive these constraints and the basic equations of duality and discuss the implications in the quantum theory.
Gravity and duality between coordinates and matter fields
NASA Astrophysics Data System (ADS)
Vancea, I. V.
2000-05-01
We use the duality between the local Cartezian coordinates and the solutions of the Klein-Gordon equation to parametrize locally the spacetime in terms of wave functions and prepotentials. The components of metric, metric connection, curvature as well as the Einstein equation are given in this parametrization. We also discuss the local duality between coordinates and quantum fields and the metric in this later reparametrization.
NASA Astrophysics Data System (ADS)
Bauke, Heiko; Klaiber, Michael; Yakaboylu, Enderalp; Hatsagortsyan, Karen Z.; Ahrens, Sven; Müller, Carsten; Keitel, Christoph H.
2013-05-01
Computational methods are indispensable to study the quantum dynamics of relativistic light-matter interactions in parameter regimes where analytical methods become inapplicable. We present numerical methods for solving the time-dependent Dirac equation and the time-dependent Klein-Gordon equation and their implementation on high performance graphics cards. These methods allow us to study tunneling from hydrogen-like highly charged ions in strong laser fields and Kapitza-Dirac scattering in the relativistic regime.
Hertz Vectors and the Electromagnetic-Quantum Equations
NASA Astrophysics Data System (ADS)
Kouzaev, Guennadi A.
In this letter, a new form of electromagnetic-quantum equations is proposed. The electric and magnetic potentials are expressed through a single Hertz vector, and the systems of quantum and Maxwell equations are transformed into more compact integro-differential ones. These new forms are given for the Schrödinger, Pauli, Dirac and Klein-Gordon equations, and a practical way to calculate them by available software tools is considered.
Rindler effect for a nonuniformly accelerating observer
Zhu Jian-yang; Bao Aidong; Zhao Zheng
1995-10-01
Both the Klein-Gordon equation and the Dirac equation are dealt with in the generalized Rindler space-time of a nonuniformly accelerating observer. Making use of a new method and introducing a tortoise-type coordinate transformation, it is proved that there exist an event horizon and thermal radiation depending on time in the space-time. The Hawking-Unruh temperature is proportional to the variable acceleration.
Negative energy waves and quantum relativistic Buneman instabilities.
Haas, F; Eliasson, B; Shukla, P K
2012-09-01
The quantum relativistic Buneman instability is investigated theoretically using a collective Klein-Gordon model for the electrons and a cold fluid model for the ions. The growth rate and unstable wave spectrum is investigated in different parameter regimes corresponding to various degrees of relativistic and quantum effects. The results may be important for streaming instabilities involving ion dynamics in very dense plasmas. PMID:23031033
Blowup results for the KGS system with higher order Yukawa coupling
Shi, Qi-Hong; Li, Wan-Tong; Wang, Shu
2015-10-15
In this paper, we investigate the Klein-Gordon-Schrödinger (KGS) system with higher order Yukawa coupling in spatial dimensions N ≥ 3. We establish a perturbed virial type identity and prove blowup results relied on Lyapunov functionals for KGS system with a negative energy level. Additionally, we give a result with respect to the blowup rate in finite time for the radial solution in 3 spatial dimensions.
Acoustic black holes: massless scalar field analytic solutions and analogue Hawking radiation
NASA Astrophysics Data System (ADS)
Vieira, H. S.; Bezerra, V. B.
2016-07-01
We obtain the analytic solutions of the radial part of the massless Klein-Gordon equation in the spacetime of both three dimensional rotating and four dimensional canonical acoustic black holes, which are given in terms of the confluent Heun functions. From these solutions, we obtain the scalar waves near the acoustic horizon. We discuss the analogue Hawking radiation of massless scalar particles and the features of the spectrum associated with the radiation emitted by these acoustic black holes.
On the correspondence between quantum and classical variational principles
Ruiz, D. E.; Dodin, I. Y.
2015-06-10
Here, classical variational principles can be deduced from quantum variational principles via formal reparameterization of the latter. It is shown that such reparameterization is possible without invoking any assumptions other than classicality and without appealing to dynamical equations. As examples, first principle variational formulations of classical point-particle and cold-fluid motion are derived from their quantum counterparts for Schrodinger, Pauli, and Klein-Gordon particles.
Quantum tunneling from scalar fields in rotating black strings
NASA Astrophysics Data System (ADS)
Gohar, H.; Saifullah, K.
2013-08-01
Using the Hamilton-Jacobi method of quantum tunneling and complex path integration, we study Hawking radiation of scalar particles from rotating black strings. We discuss tunneling of both charged and uncharged scalar particles from the event horizons. For this purpose, we use the Klein-Gordon equation and find the tunneling probability of outgoing scalar particles. The procedure gives Hawking temperature for rotating charged black strings as well.
Resolution of curvature singularities from quantum mechanical and loop perspective
NASA Astrophysics Data System (ADS)
Tahamtan, T.; Svítek, O.
2014-08-01
We analyze the persistence of curvature singularities when analyzed using quantum theory. First, quantum test particles obeying the Klein-Gordon and Chandrasekhar-Dirac equation are used to probe the classical timelike naked singularity. We show that the classical singularity is felt even by our quantum probes. Next, we use loop quantization to resolve a singularity hidden beneath the horizon. The singularity is resolved in this case.
The Green function for the Duffin-Kemmer-Petiau equation
NASA Astrophysics Data System (ADS)
Boutabia-Chéraitia, B.; Boudjedaa, T.
2012-10-01
We present a calculation of the Green function for the Duffin-Kemmer-Petiau equation in the case of scalar and vectorial particles interacting with a square barrier potential, and relate it to that of the Klein-Gordon equation. A formal Hamiltonian of the Duffin-Kemmer-Petiau theory is first developed using the Feshbach-Villars analogy and the Sakata and Taketani decomposition. The coefficients of reflection and transmission are deduced.
On the correspondence between quantum and classical variational principles
Ruiz, D. E.; Dodin, I. Y.
2015-10-01
Classical variational principles can be deduced from quantum variational principles via formal reparameterization of the latter. It is shown that such reparameterization is possible without invoking any assumptions other than classicality and without appealing to dynamical equations. As examples, first principle variational formulations of classical point-particle and cold-fluid motion are derived from their quantum counterparts for Schrodinger, Pauli, and Klein-Gordon particles. (C) 2015 Elsevier B.V. All rights reserved.
On the correspondence between quantum and classical variational principles
NASA Astrophysics Data System (ADS)
Ruiz, D. E.; Dodin, I. Y.
2015-10-01
Classical variational principles can be deduced from quantum variational principles via formal reparameterization of the latter. It is shown that such reparameterization is possible without invoking any assumptions other than classicality and without appealing to dynamical equations. As examples, first principle variational formulations of classical point-particle and cold-fluid motion are derived from their quantum counterparts for Schrödinger, Pauli, and Klein-Gordon particles.
Una técnica para filtrar patrones de fringing
NASA Astrophysics Data System (ADS)
Ostrov, P. G.
Se presenta una nueva técnica para filtrar los patrones de fringing producidos en los CCDs tipo RCA. El método consiste en construir un mapa con los ángulos de inclinación de las franjas en cada punto de la imagen. Este mapa es ulteriormente utilizado para alinear con el patrón de interferencia una ventana estrecha, sobre la que se aplica un filtro de mediana. Este procedimiento permite eliminar la mayor parte del ruido del patrón de fringing sin destruirlo.
Quantum singularities in (2+1) dimensional matter coupled black hole spacetimes
Unver, O.; Gurtug, O.
2010-10-15
Quantum singularities considered in the 3D Banados-Teitelboim-Zanelli (BTZ) spacetime by Pitelli and Letelier [Phys. Rev. D 77, 124030 (2008)] is extended to charged BTZ and 3D Einstein-Maxwell-dilaton gravity spacetimes. The occurrence of naked singularities in the Einstein-Maxwell extension of the BTZ spacetime both in linear and nonlinear electrodynamics as well as in the Einstein-Maxwell-dilaton gravity spacetimes are analyzed with the quantum test fields obeying the Klein-Gordon and Dirac equations. We show that with the inclusion of the matter fields, the conical geometry near r=0 is removed and restricted classes of solutions are admitted for the Klein-Gordon and Dirac equations. Hence, the classical central singularity at r=0 turns out to be quantum mechanically singular for quantum particles obeying the Klein-Gordon equation but nonsingular for fermions obeying the Dirac equation. Explicit calculations reveal that the occurrence of the timelike naked singularities in the considered spacetimes does not violate the cosmic censorship hypothesis as far as the Dirac fields are concerned. The role of horizons that clothes the singularity in the black hole cases is replaced by repulsive potential barrier against the propagation of Dirac fields.
NASA Astrophysics Data System (ADS)
Barceló, C.; Garay, L. J.; Jannes, G.
2010-08-01
Fluctuations around a Bose-Einstein condensate can be described by means of Bogolubov theory leading to the notion of quasiparticle and antiquasiparticle familiar to nonrelativistic condensed-matter practitioners. On the other hand, we already know that these perturbations evolve according to a relativistic Klein-Gordon equation in the long-wavelength approximation. For shorter wavelengths, we show that this equation acquires nontrivial corrections which modify the Klein-Gordon product. In this approach, quasiparticles can also be defined (up to the standard ambiguities due to observer dependence). We demonstrate that—in the low-energy as well as in the high-energy regimes—both concepts of quasiparticle are actually the same, regardless of the formalism (Bogolubov or Klein-Gordon) used to describe them. These results also apply to any barotropic, inviscid, irrotational fluid, with or without quantum potential. Finally, we illustrate how the quantization of these systems of quasiparticles proceeds by analyzing a stationary configuration containing an acoustic horizon. We show that there are several possible choices of a regular vacuum state, including a regular generalization of the Boulware vacuum. Issues such us Hawking radiation crucially depend on this vacuum choice.
Analyzing and Visualizing Cosmological Simulations with ParaView
Woodring, Jonathan; Heitmann, Katrin; Ahrens, James P; Fasel, Patricia; Hsu, Chung-Hsing; Habib, Salman; Pope, Adrian
2011-01-01
The advent of large cosmological sky surveys - ushering in the era of precision cosmology - has been accompanied by ever larger cosmological simulations. The analysis of these simulations, which currently encompass tens of billions of particles and up to a trillion particles in the near future, is often as daunting as carrying out the simulations in the first place. Therefore, the development of very efficient analysis tools combining qualitative and quantitative capabilities is a matter of some urgency. In this paper, we introduce new analysis features implemented within ParaView, a fully parallel, open-source visualization toolkit, to analyze large N-body simulations. A major aspect of ParaView is that it can live and operate on the same machines and utilize the same parallel power as the simulation codes themselves. In addition, data movement is in a serious bottleneck now and will become even more of an issue in the future; an interactive visualization and analysis tool that can handle data in situ is fast becoming essential. The new features in ParaView include particle readers and a very efficient halo finder that identifies friends-of-friends halos and determines common halo properties, including spherical overdensity properties. In combination with many other functionalities already existing within ParaView, such as histogram routines or interfaces to programming languages like Python, this enhanced version enables fast, interactive, and convenient analyses of large cosmological simulations. In addition, development paths are available for future extensions.
Cabozantinib y lenvatinib para cáncer renal
Artículo del blog del NCI sobre la aprobación reciente de la FDA de cabozantinib (Cabometyx®) y de lenvatinib (Lenvima®) para el tratamiento de pacientes cuyo cáncer avanzado de riñón ha evolucionado después de tratamiento con terapias antiangiogénicas.
Leucemia—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento de la leucemia, así como referencias a estudios clínicos, investigación, estadísticas y otros temas relacionados con este tipo de cáncer.
ACUTE TOXICITY OF PARA-NONYLPHENOL TO SALTWATER ANIMALS
?para-Nonylphenol (PNP), a mixture of alkylphenols used in producing nonionic surfactants, is distributed widely in surface waters and aquatic sediments, where it can affect saltwater species. This article describes a database for acute toxicity of PNP derived for calculating a n...
Hacer frente - Para la familia y los amigos
Si usted ayuda a su familiar o amigo durante el tratamiento del cáncer, usted es quien le cuida. Estar al cuidado de una persona con cáncer puede incluir muchas tensiones. Sugerencias para que se cuide usted cuando cuida a otros.
Tumores cerebrales—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento de los tumores cerebrales, así como referencias a estudios clínicos, estadísticas y otros temas relacionados con estos tipos de cáncer.
Linfoma—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del linfoma, así como referencias a estudios clínicos, investigación, estadísticas y otros temas relacionados con este tipo de cáncer.
Fatiga (PDQ®)—Versión para pacientes
Resumen de información revisada por expertos acerca de la fatiga, una afección caracterizada por extremo cansancio e incapacidad para funcionar por la falta de energía, que a menudo se observa como una complicación del cáncer y su tratamiento.
Delirio (PDQ®)—Versión para pacientes
Resumen de información revisada por expertos acerca del delirio como una complicación del cáncer o su tratamiento. Se tratan enfoques de los cuidados médicos de apoyo y los abordajes farmacológicos para el manejo del delirio.
Mesotelioma maligno—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento y las causas del mesotelioma maligno, así como referencias a estudios clínicos y otros temas relacionados con este tipo de cáncer.
Retinoblastoma—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del retinoblastoma, así como referencias a estudios clínicos, estadísticas y otros temas relacionados con este tipo de cáncer.
Analyzing and Visualizing Cosmological Simulations with ParaView
NASA Astrophysics Data System (ADS)
Woodring, Jonathan; Heitmann, Katrin; Ahrens, James; Fasel, Patricia; Hsu, Chung-Hsing; Habib, Salman; Pope, Adrian
2011-07-01
The advent of large cosmological sky surveys—ushering in the era of precision cosmology—has been accompanied by ever larger cosmological simulations. The analysis of these simulations, which currently encompass tens of billions of particles and up to a trillion particles in the near future, is often as daunting as carrying out the simulations in the first place. Therefore, the development of very efficient analysis tools combining qualitative and quantitative capabilities is a matter of some urgency. In this paper, we introduce new analysis features implemented within ParaView, a fully parallel, open-source visualization toolkit, to analyze large N-body simulations. A major aspect of ParaView is that it can live and operate on the same machines and utilize the same parallel power as the simulation codes themselves. In addition, data movement is in a serious bottleneck now and will become even more of an issue in the future; an interactive visualization and analysis tool that can handle data in situ is fast becoming essential. The new features in ParaView include particle readers and a very efficient halo finder that identifies friends-of-friends halos and determines common halo properties, including spherical overdensity properties. In combination with many other functionalities already existing within ParaView, such as histogram routines or interfaces to programming languages like Python, this enhanced version enables fast, interactive, and convenient analyses of large cosmological simulations. In addition, development paths are available for future extensions.
Neuroblastoma—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento y los exámenes de detección del neuroblastoma, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
Sistemas Correctores de Campo Para EL Telescopio Cassegrain IAC80
NASA Astrophysics Data System (ADS)
Galan, M. J.; Cobos, F. J.
1987-05-01
El proyecto de instrumentación de mayor importancia que ha tenido el Instituto de Astrofisica de Canarias en los últimos afios ha sido el diseflo y construcción del te1escopio IAC8O. Este requería del esfuerzo con junto en mec´nica, óptica y electrónica, lo que facilitó la estructuración y el crecimiento de los respectivos grupos de trabajo, que posteriormente se integraron en departamentos En su origen (1977), el telescopio IAC80 fue concebido como un sistema clásico tipo Cassegrain, con una razón focal F/i 1.3 para el sistema Casse grain y una razón focal F/20 para el sistema Coudé. Posteriormente, aunque se mantuvo la filosofia de que el sistema básico fuera el F/11.3, se consideró conveniente el diseño de secundarios para razones focales F/16 y F/32, y se eliminó el de F/20. Sin embargo, dada la importancia relativa que un foco estrictamente fotográfico tiene en un telescopio moderno, diseñado básicamente para fotometría fotoeléctrica y con un campo util mínimamente de 40 minutos de arco, se decídió Ilevar a cabo el diseño de un secundario F/8 con un sistema corrector de campo, pero que estuviera formado únicamente por lentes con superficies esféricas para que asl su construcción fuera posible en España ó en México. La creciente utilización de detectores bidimensionales para fines de investigación astron6mica y la viabilidad de que en un futuro cercano éstos tengan un área sensible cada vez mayor, hicieron atractiva la idea de tener diseñado un sistema corrector de campo para el foco primario (F/3), con un campo útil mínimo de un grado, y también con la limitante de que sus componentes tuvieron sólamente supérficies esféricas. Ambos diseños de los sis-temas correctores de campo se llevaron a cabo, en gran medida, como parte de un proyecto de colaboración e intercambio en el área de diseño y evaluación de sistemas ópticos.
DESIGN NOTE: A compact catalytic converter for the production of para-hydrogen
NASA Astrophysics Data System (ADS)
Juarez, A. M.; Cubric, D.; King, G. C.
2002-05-01
The design and operation of a compact converter to produce a constant flow of para-hydrogen from normal hydrogen is described. The converter features a paramagnetic compound (nickel sulfate) that catalyses the conversion of ortho- to para-hydrogen at temperatures of 14-21 K. The converter has been tested by measuring rotationally resolved photoelectron spectra in the para-hydrogen produced. The percentage of the para-hydrogen species in the converted gas was determined to be >97%.
Control del dolor: Apoyo para las personas con cáncer
Contiene información sobre las medicinas contra el dolor para pacientes con cáncer, los planes para controlarlo, cómo hablar con su equipo de atención médica sobre el dolor que usted siente y qué hacer para controlar los efectos físicos y emocionales del
ParA resolvase catalyzes site-specific excision of DNA from the Arabidopsis genome
Technology Transfer Automated Retrieval System (TEKTRAN)
The small serine resolvase ParA from bacterial plasmids RK2 and RP4 catalyzes the recombination of two identical 133 bp recombination sites known as MRS. Previously, we reported that ParA is active in the fission yeast Schizosaccharomyces pombe. In this work, the parA recombinase gene was placed un...
The Regulation of para-Nitrophenol Degradation in Pseudomonas putida DLL-E4
Chen, Qiongzhen; Tu, Hui; Luo, Xue; Zhang, Biying; Huang, Fei; Li, Zhoukun; Wang, Jue; Shen, Wenjing; Wu, Jiale; Cui, Zhongli
2016-01-01
Pseudomonas putida DLL-E4 can efficiently degrade para-nitrophenol and its intermediate metabolite hydroquinone. The regulation of para-nitrophenol degradation was studied, and PNP induced a global change in the transcriptome of P. putida DLL-E4. When grown on PNP, the wild-type strain exhibited significant downregulation of 2912 genes and upregulation of 845 genes, whereas 2927 genes were downregulated and 891 genes upregulated in a pnpR-deleted strain. Genes related to two non-coding RNAs (ins1 and ins2), para-nitrophenol metabolism, the tricarboxylic acid cycle, the outer membrane porin OprB, glucose dehydrogenase Gcd, and carbon catabolite repression were significantly upregulated when cells were grown on para-nitrophenol plus glucose. pnpA, pnpR, pnpC1C2DECX1X2, and pnpR1 are key genes in para-nitrophenol degradation, whereas pnpAb and pnpC1bC2bDbEbCbX1bX2b have lost the ability to degrade para-nitrophenol. Multiple components including transcriptional regulators and other unknown factors regulate para-nitrophenol degradation, and the transcriptional regulation of para-nitrophenol degradation is complex. Glucose utilization was enhanced at early stages of para-nitrophenol supplementation. However, it was inhibited after the total consumption of para-nitrophenol. The addition of glucose led to a significant enhancement in para-nitrophenol degradation and up-regulation in the expression of genes involved in para-nitrophenol degradation and carbon catabolite repression (CCR). It seemed that para-nitrophenol degradation can be regulated by CCR, and relief of CCR might contribute to enhanced para-nitrophenol degradation. In brief, the regulation of para-nitrophenol degradation seems to be controlled by multiple factors and requires further study. PMID:27191401
Para rubber seed oil: new promising unconventional oil for cosmetics.
Lourith, Nattaya; Kanlayavattanakul, Mayuree; Sucontphunt, Apirada; Ondee, Thunnicha
2014-01-01
Para rubber seed was macerated in petroleum ether and n-hexane, individually, for 30 min. The extraction was additionally performed by reflux and soxhlet for 6 h with the same solvent and proportion. Soxhlet extraction by petroleum ether afforded the greatest extractive yield (22.90 ± 0.92%). Although antioxidant activity by means of 1, 1-diphenyl-2-picrylhydrazyl (DPPH) assay was insignificantly differed in soxhleted (8.90 ± 1.15%) and refluxed (9.02 ± 0.71%) by n-hexane, soxhlet extraction by n-hexane was significantly (p < 0.05) potent scavenged 2,2'-azino-bis(3-ethylbenzothaiazoline)-6-sulfonic acid) or ABTS radical with trolox equivalent antioxidant capacity (TEAC) of 66.54 ± 6.88 mg/100 g oil. This extract was non cytotoxic towards normal human fibroblast cells. In addition, oleic acid and palmitic acid were determined at a greater content than in the seed of para rubber cultivated in Malaysia, although linoleic and stearic acid contents were not differed. This bright yellow extract was further evaluated on other physicochemical characters. The determined specific gravity, refractive index, iodine value, peroxide value and saponification value were in the range of commercialized vegetable oils used as cosmetic raw material. Therefore, Para rubber seed oil is highlighted as the promising ecological ingredient appraisal for cosmetics. Transforming of the seed that is by-product of the important industrial crop of Thailand into cosmetics is encouraged accordingly. PMID:24976614
TELEMEDICINA: UN DESAFÍO PARA AMÉRICA LATINA
Litewka, Sergio
2011-01-01
La telemedicina es una tendencia creciente en la prestación de los servicios médicos. Aunque la eficacia de esta práctica no ha estado bien establecida, es probable que los países en desarrollo compartirán este nuevo paradigma con los desarrollados. Los defensores de la telemedicina en América Latina sostienen que será una herramienta útil para reducir las disparidades y mejorar la accesibilidad de atención de salud. Aunque América Latina quizá se convierta en un lugar para la investigación e investigación de estos procedimientos, no está claro cómo la telemedicina podría contribuir a mejorar la accesibilidad para las poblaciones desfavorecidas, o coexistir con sistemas de atención de salud públicos crónicamente enfermos. Telemedicine is a growing trend in the provision of medical services. Although the effectiveness of this practice has not been well established, it is likely that developing countries will share this new paradigm with developed ones. Supporters of telemedicine in Latin America maintain that it will be a useful tool for reducing disparities and improving health care accessibility. Although Latin America might become a place for research and investigation of these procedures, it is not clear how telemedicine could contribute to improving accessibility for disadvantaged populations, or coexist with chronically ill-funded public healthcare systems. PMID:21625326
ORTHO-PARA SELECTION RULES IN THE GAS-PHASE CHEMISTRY OF INTERSTELLAR AMMONIA
Faure, A.; Hily-Blant, P.; Le Gal, R.; Rist, C.
2013-06-10
The ortho-para chemistry of ammonia in the cold interstellar medium is investigated using a gas-phase chemical network. Branching ratios for the primary reaction chain involved in the formation and destruction of ortho- and para-NH{sub 3} were derived using angular momentum rules based on the conservation of the nuclear spin. We show that the 'anomalous' ortho-to-para ratio of ammonia ({approx}0.7) observed in various interstellar regions is in fact consistent with nuclear spin selection rules in a para-enriched H{sub 2} gas. This ratio is found to be independent of temperature in the range 5-30 K. We also predict an ortho-to-para ratio of {approx}2.3 for NH{sub 2}. We conclude that a low ortho-to-para ratio of H{sub 2} naturally drives the ortho-to-para ratios of nitrogen hydrides below the statistical values.
ParA resolvase catalyzes site-specific excision of DNA from the Arabidopsis genome.
Thomson, James G; Yau, Yuan-Yeu; Blanvillain, Robert; Nunes, Wylla M; Chiniquy, Dawn; Thilmony, Roger; Ow, David W
2009-04-01
The small serine resolvase ParA from bacterial plasmids RK2 and RP4 catalyzes the recombination of two identical 133 bp recombination sites known as MRS. Previously, we reported that ParA is active in the fission yeast Schizosaccharomyces pombe. In this work, the parA recombinase gene was placed under the control of the Arabidopsis OXS3 promoter and introduced into Arabidopsis lines harboring a chromosomally integrated MRS-flanked target. The ParA recombinase excised the MRS-flanked DNA and the excision event was detected in subsequent generations in the absence of ParA, indicating germinal transmission of the excision event. The precise site-specific deletion by the ParA recombination system in planta demonstrates that the ParA recombinase can be used to remove transgenic DNA, such as selectable markers or other introduced transgenes that are no longer desired in the final product. PMID:18704739
Song, Sung Ho; Park, Soo Yeun; Park, Jun Seok; Kim, Hye Jin; Yang, Chun-Seok
2016-01-01
Purpose Treatment of patients with para-aortic lymph node metastasis from colorectal cancer is controversial. The goal of this study was to investigate the technical feasibility of laparoscopic intrarenal para-aortic lymph node dissection in patients with colorectal cancer and clinically suspected para-aortic lymph node dissection. Methods The inclusion criteria for the laparoscopic approach were patients with infrarenal para-aortic lymph node metastasis from colorectal cancer. Patients who had any other distant metastatic lesion or metachronous para-aortic lymph node metastasis were excluded from this study. Perioperative outcomes and survival outcomes were analyzed. Results Between November 2004 and October 2013, 40 patients underwent laparoscopic para-aortic lymph node dissection. The mean operating time was 192.3 ± 68.8 minutes (range, 100-400 minutes) and the mean estimated blood loss was 65.6 ± 52.6 mL (range, 20-210 mL). No patient required open conversion. The postoperative complication rate was 15.0%. Sixteen patients (40.0%) had pathologically positive lymph nodes. In patients with metastatic para-aortic lymph nodes, the 3-year overall survival rate and disease-free survival rate were 65.7% and 40.2%, respectively. Conclusion The results of our study suggest that a laparoscopic approach for patients with colorectal cancer with metastatic para-aortic lymph nodes can be a reasonable option for selected patients. PMID:26793690
Centro para la Salud Mundial del NCI anuncia becas de investigación para tecnologías portátiles
El Centro para la Salud Mundial del NCI (CGH) anunció el otorgamiento de subvenciones que apoyarán el desarrollo y la validación de tecnologías portátiles y de bajo costo para mejorar la detección temprana, el diagnóstico y el tratamiento del cáncer.
Wave Dark Matter and Dwarf Spheroidal Galaxies
NASA Astrophysics Data System (ADS)
Parry, Alan R.
We explore a model of dark matter called wave dark matter (also known as scalar field dark matter and boson stars) which has recently been motivated by a new geometric perspective by Bray. Wave dark matter describes dark matter as a scalar field which satisfies the Einstein-Klein-Gordon equations. These equations rely on a fundamental constant Upsilon (also known as the "mass term'' of the Klein-Gordon equation). Specifically, in this dissertation, we study spherically symmetric wave dark matter and compare these results with observations of dwarf spheroidal galaxies as a first attempt to compare the implications of the theory of wave dark matter with actual observations of dark matter. This includes finding a first estimate of the fundamental constant Upsilon. In the introductory Chapter 1, we present some preliminary background material to define and motivate the study of wave dark matter and describe some of the properties of dwarf spheroidal galaxies. In Chapter 2, we present several different ways of describing a spherically symmetric spacetime and the resulting metrics. We then focus our discussion on an especially useful form of the metric of a spherically symmetric spacetime in polar-areal coordinates and its properties. In particular, we show how the metric component functions chosen are extremely compatible with notions in Newtonian mechanics. We also show the monotonicity of the Hawking mass in these coordinates. Finally, we discuss how these coordinates and the metric can be used to solve the spherically symmetric Einstein-Klein-Gordon equations. In Chapter 3, we explore spherically symmetric solutions to the Einstein-Klein-Gordon equations, the defining equations of wave dark matter, where the scalar field is of the form f(t, r) = eiotF(r) for some constant o ∈ R and complex-valued function F(r). We show that the corresponding metric is static if and only if F( r) = h(r)eia for some constant alpha ∈ R and real-valued function h(r). We describe the
TELEMEDICINA: UN DESAFÍO PARA AMÉRICA LATINA.
Litewka, Sergio
2005-01-01
La telemedicina es una tendencia creciente en la prestación de los servicios médicos. Aunque la eficacia de esta práctica no ha estado bien establecida, es probable que los países en desarrollo compartirán este nuevo paradigma con los desarrollados. Los defensores de la telemedicina en América Latina sostienen que será una herramienta útil para reducir las disparidades y mejorar la accesibilidad de atención de salud. Aunque América Latina quizá se convierta en un lugar para la investigación e investigación de estos procedimientos, no está claro cómo la telemedicina podría contribuir a mejorar la accesibilidad para las poblaciones desfavorecidas, o coexistir con sistemas de atención de salud públicos crónicamente enfermos.Telemedicine is a growing trend in the provision of medical services. Although the effectiveness of this practice has not been well established, it is likely that developing countries will share this new paradigm with developed ones. Supporters of telemedicine in Latin America maintain that it will be a useful tool for reducing disparities and improving health care accessibility. Although Latin America might become a place for research and investigation of these procedures, it is not clear how telemedicine could contribute to improving accessibility for disadvantaged populations, or coexist with chronically ill-funded public healthcare systems. PMID:21625326
Amazon Land Wars in the South of Para
NASA Technical Reports Server (NTRS)
Simmons, Cynthia S.; Walker, Robert T.; Arima, Eugenio Y.; Aldrich, Stephen P.; Caldas, Marcellus M.
2007-01-01
The South of Para, located in the heart of the Brazilian Amazon, has become notorious for violent land struggle. Although land conflict has a long history in Brazil, and today impacts many parts of the country, violence is most severe and persistent here. The purpose of this article is to examine why. Specifically, we consider how a particular Amazonian place, the so-called South of Para has come to be known as Brazil's most dangerous badland. We begin by considering the predominant literature, which attributes land conflict to the frontier expansion process with intensified struggle emerging in the face of rising property values and demand for private property associated with capitalist development. From this discussion, we distill a concept of the frontier, based on notions of property rights evolution and locational rents. We then empirically test the persistence of place-based violence in the region, and assess the frontier movement through an analysis of transportation costs. The findings from the analyses indicate that the prevalent theorization of frontier violence in Amazonia does little to explain its persistent and pervasive nature in the South of Para. To fill this gap in understanding, we develop an explanation based the geographic conception of place, and we use contentious politics theory heuristically to elucidate the ways in which general processes interact with place specific history to engender a landscape of violence. In so doing, we focus on environmental, cognitive, and relational mechanisms (and implicated structures), and attempt to deploy them in an explanatory framework that allows direct observation of the accumulating layers of the region's tragic history. We end by placing our discussion within a political ecological context, and consider the implications of the Amazon Land War for the environment.
RVA: A Plugin for ParaView 3.14
2015-09-04
RVA is a plugin developed for the 64-bit Windows version of the ParaView 3.14 visualization package. RVA is designed to provide support in the visualization and analysis of complex reservoirs being managed using multi-fluid EOR techniques. RVA, for Reservoir Visualization and Analysis, was developed at the University of Illinois at Urbana-Champaign, with contributions from the Illinois State Geological Survey, Department of Computer Science and National Center for Supercomputing Applications. RVA was designed to utilize and enhance the state-of-the-art visualization capabilities within ParaView, readily allowing joint visualization of geologic framework and reservoir fluid simulation model results. Particular emphasis was placed on enabling visualization and analysis of simulation results highlighting multiple fluid phases, multiple properties for each fluid phase (including flow lines), multiple geologic models and multiple time steps. Additional advanced functionality was provided through the development of custom code to implement data mining capabilities. The built-in functionality of ParaView provides the capacity to process and visualize data sets ranging from small models on local desktop systems to extremely large models created and stored on remote supercomputers. The RVA plugin that we developed and the associated User Manual provide improved functionality through new software tools, and instruction in the use of ParaView-RVA, targeted to petroleum engineers and geologists in industry and research. The RVA web site (http://rva.cs.illinois.edu) provides an overview of functions, and the development web site (https://github.com/shaffer1/RVA) provides ready access to the source code, compiled binaries, user manual, and a suite of demonstration data sets. Key functionality has been included to support a range of reservoirs visualization and analysis needs, including: sophisticated connectivity analysis, cross sections through simulation results between
Spectroscopy of Single Dibenzoterrylene Molecules in para-Dichlorobenzene.
Verhart, Nico R; Müller, Mathias; Orrit, Michel
2016-05-18
We study single dibenzoterrylene (DBT) molecules embedded in 1,4-dichlorobenzene (para-dichlorobenzene, pDCB) at 1.2 K. Due to the relatively low melting point of pDCB (53 °C), this host-guest system can be easily prepared from the molten phase. Narrow linewidths, stable molecular lines and high saturation count rates of single DBT molecules were observed. For this reason, we consider this host-guest system a promising candidate for the study of interactions of single molecules with other small objects such as waveguides or nanoparticles. PMID:26840901
RVA: A Plugin for ParaView 3.14
Energy Science and Technology Software Center (ESTSC)
2015-09-04
RVA is a plugin developed for the 64-bit Windows version of the ParaView 3.14 visualization package. RVA is designed to provide support in the visualization and analysis of complex reservoirs being managed using multi-fluid EOR techniques. RVA, for Reservoir Visualization and Analysis, was developed at the University of Illinois at Urbana-Champaign, with contributions from the Illinois State Geological Survey, Department of Computer Science and National Center for Supercomputing Applications. RVA was designed to utilize andmore » enhance the state-of-the-art visualization capabilities within ParaView, readily allowing joint visualization of geologic framework and reservoir fluid simulation model results. Particular emphasis was placed on enabling visualization and analysis of simulation results highlighting multiple fluid phases, multiple properties for each fluid phase (including flow lines), multiple geologic models and multiple time steps. Additional advanced functionality was provided through the development of custom code to implement data mining capabilities. The built-in functionality of ParaView provides the capacity to process and visualize data sets ranging from small models on local desktop systems to extremely large models created and stored on remote supercomputers. The RVA plugin that we developed and the associated User Manual provide improved functionality through new software tools, and instruction in the use of ParaView-RVA, targeted to petroleum engineers and geologists in industry and research. The RVA web site (http://rva.cs.illinois.edu) provides an overview of functions, and the development web site (https://github.com/shaffer1/RVA) provides ready access to the source code, compiled binaries, user manual, and a suite of demonstration data sets. Key functionality has been included to support a range of reservoirs visualization and analysis needs, including: sophisticated connectivity analysis, cross sections through simulation results
Biodegradation of Para Amino Acetanilide by Halomonas sp. TBZ3
Hajizadeh, Nader; Sefidi Heris, Youssof; Zununi Vahed, Sepideh; Vallipour, Javad; Hejazi, Mohammad Amin; Golabi, Sayyed Mahdi; Asadpour-Zeynali, Karim; Hejazi, Mohammad Saeid
2015-01-01
Background: Aromatic compounds are known as a group of highly persistent environmental pollutants. Halomonas sp. TBZ3 was isolated from the highly salty Urmia Lake of Iran. In this study, characterization of a new Halomonas isolate called Halomonas sp. TBZ3 and its employment for biodegradation of para-amino acetanilide (PAA), as an aromatic environmental pollutant, is described. Objectives: This study aimed to characterize the TBZ3 isolate and to elucidate its ability as a biodegradative agent that decomposes PAA. Materials and Methods: Primarily, DNA-DNA hybridization between TBZ3, Halomonas denitrificans DSM18045T and Halomonas saccharevitans LMG 23976T was carried out. Para-amino acetanilide biodegradation was assessed using spectrophotometry and confirmed by gas chromatography-mass spectroscopy (GC-MS). Parameters effective on biodegradation of PAA were optimized by the Response Surface Methodology (RSM). Results: The DNA-DNA hybridization experiments between isolate TBZ3, H. denitrificans and H. saccharevitans revealed relatedness levels of 57% and 65%, respectively. According to GC-MS results, TBZ3 degrades PAA to benzene, hexyl butanoate, 3-methyl-1-heptanol and hexyl hexanoate. Temperature 32.92°C, pH 6.76, and salinity 14% are the optimum conditions for biodegradation with a confidence level of 95% (at level α = 0.05). Conclusions: According to our results, Halomonas sp. TBZ3 could be considered as a biological agent for bioremediation of PAA and possibly other similar aromatic compounds. PMID:26495103
Kilgore, Matthew B.; Augustin, Megan M.; May, Gregory D.; Crow, John A.; Kutchan, Toni M.
2016-01-01
The Amaryllidaceae alkaloids are a family of amino acid derived alkaloids with many biological activities; examples include haemanthamine, haemanthidine, galanthamine, lycorine, and maritidine. Central to the biosynthesis of the majority of these alkaloids is a C-C phenol-coupling reaction that can have para-para', para-ortho', or ortho-para' regiospecificity. Through comparative transcriptomics of Narcissus sp. aff. pseudonarcissus, Galanthus sp., and Galanthus elwesii we have identified a para-para' C-C phenol coupling cytochrome P450, CYP96T1, capable of forming the products (10bR,4aS)-noroxomaritidine and (10bS,4aR)-noroxomaritidine from 4′-O-methylnorbelladine. CYP96T1 was also shown to catalyzed formation of the para-ortho' phenol coupled product, N-demethylnarwedine, as less than 1% of the total product. CYP96T1 co-expresses with the previously characterized norbelladine 4′-O-methyltransferase. The discovery of CYP96T1 is of special interest because it catalyzes the first major branch in Amaryllidaceae alkaloid biosynthesis. CYP96T1 is also the first phenol-coupling enzyme characterized from a monocot. PMID:26941773
Ortho-para mixing hyperfine interaction in the H2O+ ion and nuclear spin equilibration.
Tanaka, Keiichi; Harada, Kensuke; Oka, Takeshi
2013-10-01
The ortho to para conversion of water ion, H2O(+), due to the interaction between the magnetic moments of the unpaired electron and protons has been theoretically studied to calculate the spontaneous emission lifetime between the ortho- and para-levels. The electron spin-nuclear spin interaction term, Tab(SaΔIb + SbΔIa) mixes ortho (I = 1) and para (I = 0) levels to cause the "forbidden" ortho to para |ΔI| = 1 transition. The mixing term with Tab = 72.0 MHz is 4 orders of magnitude higher for H2O(+) than for its neutral counterpart H2O where the magnetic field interacting with proton spins is by molecular rotation rather than the free electron. The resultant 10(8) increase of ortho to para conversion rate possibly makes the effect of conversion in H2O(+) measurable in laboratories and possibly explains the anomalous ortho to para ratio recently reported by Herschel heterodyne instrument for the far-infrared (HIFI) observation. Results of our calculations show that the ortho ↔ para mixings involving near-degenerate ortho and para levels are high (∼10(-3)), but they tend to occur at high energy levels, ∼300 K. Because of the rapid spontaneous emission, such high levels are not populated in diffuse clouds unless the radiative temperature of the environment is very high. The low-lying 101 (para) and 111 (ortho) levels of H2O(+) are mixed by ∼10(-4) making the spontaneous emission lifetime for the para 101 → ortho 000 transition 520 years and 5200 years depending on the F value of the hyperfine structure. Thus the ortho ↔ para conversion due to the unpaired electron is not likely to seriously affect thermalization of interstellar H2O(+) unless either the radiative temperature is very high or number density of the cloud is very low. PMID:23530629
ParaText : scalable text analysis and visualization.
Dunlavy, Daniel M.; Stanton, Eric T.; Shead, Timothy M.
2010-07-01
Automated analysis of unstructured text documents (e.g., web pages, newswire articles, research publications, business reports) is a key capability for solving important problems in areas including decision making, risk assessment, social network analysis, intelligence analysis, scholarly research and others. However, as data sizes continue to grow in these areas, scalable processing, modeling, and semantic analysis of text collections becomes essential. In this paper, we present the ParaText text analysis engine, a distributed memory software framework for processing, modeling, and analyzing collections of unstructured text documents. Results on several document collections using hundreds of processors are presented to illustrate the exibility, extensibility, and scalability of the the entire process of text modeling from raw data ingestion to application analysis.
Pneumatic protection applied to an airbag for para-gliders
NASA Astrophysics Data System (ADS)
Raievski, V.; Valladas, G.
1998-02-01
We present a theory of pneumatic protection based on the laws of thermodynamics, elasticity and fluid mechanics. A general pneumatic protection system is made up of several communicating compartments, the differences in pressure of the compartments generating a transfer of mass and energy between them. The transfer offers interesting possibilities to improve the performance of the system. An example of this type of protection in aerial sport is the airbag for para-gliders, it is used in this paper to illustrate the theory. As the pressure in the airbag depends uniquely on its volume, the geometric model in the theory can be simplified. Experiments carried out with crash-test dummies equipped with sensors have confirmed the theoretical predictions.
Spectroscopy of Defects in Epitaxially Grown Para-sexiphenyl Nanostructures
NASA Astrophysics Data System (ADS)
Kadashchuk, A.; Schols, S.; Skryshevski, Yu.; Beynik, I.; Teichert, C.; Hernandez-Sosa, G.; Sitter, H.; Andreev, A.; Frank, P.; Winkler, A.
We present a study of steady-state- and time-resolved photoluminescence of para-sexiphenyl (PSP) films on KCl grown by organic molecular beam epitaxy (OMBE). Using different OMBE growth conditions has enabled us to vary greatly the morphology of the PSP crystallites but keeping virtually untouched their chemical structure. By this comparative study we prove that the broad red-shifted emission band has a structure-related origin rather than being due to monomolecular oxidative defects. The relative intensity of the defect emission band observed in the delayed spectra was found to be drastically suppressed in the OMBE-grown films dominated by growth mounds composed of upright standing molecules as opposed to the films consisting of crystallites formed by molecules lying parallel to the substrate.
Para-Hydrogen-Enhanced Gas-Phase Magnetic Resonance Imaging
Bouchard, Louis-S.; Kovtunov, Kirill V.; Burt, Scott R.; Anwar,M. Sabieh; Koptyug, Igor V.; Sagdeev, Renad Z.; Pines, Alexander
2007-02-23
Herein, we demonstrate magnetic resonance imaging (MRI) inthe gas phase using para-hydrogen (p-H2)-induced polarization. A reactantmixture of H2 enriched in the paraspin state and propylene gas is flowedthrough a reactor cell containing a heterogenized catalyst, Wilkinson'scatalyst immobilized on modified silica gel. The hydrogenation product,propane gas, is transferred to the NMR magnet and is spin-polarized as aresult of the ALTADENA (adiabatic longitudinal transport and dissociationengenders net alignment) effect. A polarization enhancement factor of 300relative to thermally polarized gas was observed in 1D1H NMR spectra.Enhancement was also evident in the magnetic resonance images. This isthe first demonstration of imaging a hyperpolarized gaseous productformed in a hydrogenation reaction catalyzed by a supported catalyst.This result may lead to several important applications, includingflow-through porous materials, gas-phase reaction kinetics and adsorptionstudies, and MRI in low fields, all using catalyst-free polarizedfluids.
Nuevos sistemas de frecuencia intermedia para el IAR
NASA Astrophysics Data System (ADS)
Olalde, J. C.; Perilli, D.; Larrarte, J. J.
Se presenta el diagrama en bloques de los nuevos sistemas de Frecuencia Intermedia para los dos radiómetros instalados en el IAR. Entre las características más importantes del sistema podemos mencionar la posibilidad de conectar cualquiera de las dos antenas a los ``backend" disponibles: analizador espectral de alta resolución (META II) de 0,05 Hz, autocorrelador de 1008 canales y contínuo. Se incorporan al sistema nuevos sintetizadores de frecuencia implementados con PLL y la moderna técnica de síntesis digital directa. Por último, el conjunto del sistema es susceptible de ser configurado por las computadoras de adquisición de datos, supervisadas por otra, que entrega el estado de funcionamiento actual y evita la selección de configuraciones incorrectas por parte del usuario.
Wave intensity analysis of para-aortic counterpulsation.
Lu, Pong-Jeu; Yang, Chi-Fu Jeffrey; Wu, Meng-Yu; Hung, Chun-Hao; Chan, Ming-Yao; Hsu, Tzu-Cheng
2012-04-01
Wave intensity analysis (WIA) was used to delineate and maximize the efficacy of a newly developed para-aortic blood pump (PABP). The intra-aortic balloon pump (IABP) was employed as the comparison benchmark. Acute porcine experiments using eight pigs, randomly divided into IABP (n = 4) and PABP (n = 4) groups, were conducted to compare the characteristics of intra- and para-aortic counterpulsation. We measured pressure and velocity with probes installed in the left anterior descending coronary artery and aorta, during and without PABP assistance. Wave intensity for aortic and left coronary waves were derived from pressure and flow measurements with synchronization correction applied. To achieve maximized support efficacy, deflation timings ranging from 25 ms ahead of to 35 ms after the R-wave were tested. Similar to those associated with IABP counterpulsation, the PABP-generated backward-traveling waves predominantly drove aortic and coronary blood flows. However, in contrast with IABP counterpulsation, the nonocclusive nature of the PABP allowed systolic unloading to be delayed into early systole, which resulted in near elimination of coronary blood steal without diminution of systolic left ventricular ejection wave intensities. WIA can elucidate subtleties among different counterpulsatile support means with high sensitivity. Total accelerating wave intensity (TAWI), which was defined as the sum of the time integration of accelerated parts of the positive and negative wave intensities, was used to quantify counterpulsation efficacy. In general, the larger the TAWI gain, the better the counter-pulsatile support efficacy. However, when PABP deflation timings were delayed to after the R-wave, the TAWI was found to be inversely correlated with coronary perfusion. In this delayed deflation timing setting, greater wave cancellation occurred, which led to decreased TAWI but increased coronary perfusion attributed to blood regurgitation reduction. PMID:22227124
The Clearance of Creatinine, Inulin, Para-aminohippurate and Phenosulphothalein in the Cat
Osbaldiston, G. W.; Fuhrman, W.
1970-01-01
Endogenous creatinine, inulin, para-amino-hippurate and phenolsulphothalein clearances for healthy cats are presented. The values for inulin and para-aminohippurate clearances (ml/kg/min) are similar to those for the dog. Creatinine clearance was less than inulin clearance values. Pnenolsulphothalein clearance may be a better index of glomerular rather than tubular function in the cat. PMID:4246836
Chiral phosphoric acid catalyzed asymmetric addition of naphthols to para-quinone methides.
Wong, Yuk Fai; Wang, Zhaobin; Sun, Jianwei
2016-06-28
An asymmetric addition of naphthols to in situ generated para-quinone methides catalyzed by a chiral phosphoric acid is described. A range of useful triarylmethanes can be generated from stable general para-hydroxybenzyl alcohols with good efficiency and enantioselectivity. PMID:26932597
Para-meatal urethral cyst with bladder calculi: A case report and review of the literature.
Patil, Siddangouda B; Patil, Nikhil Ashok; Kundargi, Vinay S; Biradar, Ashok N
2015-01-01
Para-meatal urethral cyst or median raphe cyst of the glans penis is a benign cystic lesion uncommonly encountered in prepubertal age group. Approximately, about 50 cases have been reported till date in the world literature. Herein we report a case of para-meatal urethral cyst concurrent with urinary bladder calculi. PMID:26539378
The parA resolvase performs site-specific genomic excision in Arabidopsis
Technology Transfer Automated Retrieval System (TEKTRAN)
We have designed a site-specific excision detection system in Arabidopsis to study the in planta activity of the small serine recombinase ParA. Using a transient expression assay as well as stable transgenic plant lines, we show that the ParA recombinase is catalytically active and capable of perfo...
Para-meatal urethral cyst with bladder calculi: A case report and review of the literature
Patil, Siddangouda B.; Patil, Nikhil Ashok; Kundargi, Vinay S.; Biradar, Ashok N.
2015-01-01
Para-meatal urethral cyst or median raphe cyst of the glans penis is a benign cystic lesion uncommonly encountered in prepubertal age group. Approximately, about 50 cases have been reported till date in the world literature. Herein we report a case of para-meatal urethral cyst concurrent with urinary bladder calculi. PMID:26539378
Nohynek, Gerhard J; Duche, Daniel; Garrigues, Alexia; Meunier, Pierre-Alain; Toutain, Herve; Leclaire, Jacques
2005-09-15
We investigated the biotransformation of the oxidative arylamine (AA) hair dye ingredients [14C]-para-aminophenol (PAP) and [14C]-para-phenylenediamine (PPD) in reconstructed human epidermis and human hepatocytes. Human epidermis quantitatively transformed PAP to its N-acetylated derivative (APAP), whereas hepatocytes transformed PAP to sulfate or glucuronic acid conjugates of APAP or PAP as well as free APAP. Epidermis and hepatocytes converted PPD to N-mono- (MAPPD) and N,N'-di-acetylated (DAPPD) derivatives. At higher concentrations of PPD (250-1000 microM), epidermis or hepatocytes produced more of the MAPPD, whereas concentrations below 250 microM and lower favoured formation of the DAPPD metabolite. When compared with epidermis, human hepatocytes had a three-fold or eight-fold greater capacity for generation of MAPPD or DAPPD, respectively. No evidence of transformation of PAP or PPD to N-hydroxylated derivatives was found in epidermis or hepatocytes. Our results suggest that (i) after dermal absorption of PAP or PPD, humans are systemically exposed to acetylated derivatives; (ii) current in vitro skin absorption studies may be inadapated for determination of human systemic exposure to AAs due to reduced or absent metabolic capacity of non-viable skin; (iii) due to qualitative differences between dermal and hepatic metabolism, oral toxicity studies may be unsuited for the hazard assessment of dermal exposure to AAs; and (iv) use of induced rodent liver S9 metabolic activation systems for in vitro genotoxicity studies may produce misleading results on the hazard of human dermal exposure to AAs. In conclusion, our data support the growing evidence that AAs are transformed in human skin and suggest that current practices of safety assessment of AAs should take these findings into account. PMID:15890478
ERIC Educational Resources Information Center
Raval, Harini; McKenney, Susan; Pieters, Jules
2012-01-01
The appointment of para-professionals to overcome skill shortages and/or make efficient use of expensive resources is well established in both developing and developed countries. The present research concerns para-teachers in India. The literature on para-teachers is dominated by training for special needs settings, largely in developed societies.…
Bourne, Godfrey R; Breden, Felix; Allen, Teresa C
2003-09-01
The first results of female preference and chosen male mating success in a new model organism, the pentamorphic livebearing fish, Poecilia parae, are presented. Poecilia parae is a relative of the guppy, P. reticulata, and is assumed to have similar reproductive behavior. We tested the hypothesis that P. parae females, like female guppies, prefer carotenoid colored males as mates. Here we show that the time a female spent with males was significantly greater for carotenoid coloration in red and yellow melanzona, but time with these two morphs did not differ. The preferred red and yellow males mated significantly more often with their choosing females than did the non-preferred blue and parae males. The few blue melanzona and parae males that mated did so without performing courtship displays. Some females mated with all phenotypes including immaculata males during open group trials. Female P. parae clearly preferred males with carotenoid coloration, thereby corroborating the hypothesis. Alternative male mating tactics by blue melanzona, parae, and immaculata morphs and promiscuous mating by females also resembled features of reproductive behaviors exhibited by guppies. PMID:14504782
Quantum fluctuations increase the self-diffusive motion of para-hydrogen in narrow carbon nanotubes.
Kowalczyk, Piotr; Gauden, Piotr A; Terzyk, Artur P; Furmaniak, Sylwester
2011-05-28
Quantum fluctuations significantly increase the self-diffusive motion of para-hydrogen adsorbed in narrow carbon nanotubes at 30 K comparing to its classical counterpart. Rigorous Feynman's path integral calculations reveal that self-diffusive motion of para-hydrogen in a narrow (6,6) carbon nanotube at 30 K and pore densities below ∼29 mmol cm(-3) is one order of magnitude faster than the classical counterpart. We find that the zero-point energy and tunneling significantly smoothed out the free energy landscape of para-hydrogen molecules adsorbed in a narrow (6,6) carbon nanotube. This promotes a delocalization of the confined para-hydrogen at 30 K (i.e., population of unclassical paths due to quantum effects). Contrary the self-diffusive motion of classical para-hydrogen molecules in a narrow (6,6) carbon nanotube at 30 K is very slow. This is because classical para-hydrogen molecules undergo highly correlated movement when their collision diameter approached the carbon nanotube size (i.e., anomalous diffusion in quasi-one dimensional pores). On the basis of current results we predict that narrow single-walled carbon nanotubes are promising nanoporous molecular sieves being able to separate para-hydrogen molecules from mixtures of classical particles at cryogenic temperatures. PMID:21503294
Para-nitrobenzyl esterases with enhanced activity in aqueous and nonaqueous media
Arnold, F.H.; Moore, J.C.
1999-05-25
A method is disclosed for isolating and identifying modified para-nitrobenzyl esterases which exhibit improved stability and/or esterase hydrolysis activity toward selected substrates and under selected reaction conditions relative to the unmodified para-nitrobenzyl esterase. The method involves preparing a library of modified para-nitrobenzyl esterase nucleic acid segments (genes) which have nucleotide sequences that differ from the nucleic acid segment which encodes for unmodified para-nitrobenzyl esterase. The library of modified para-nitrobenzyl nucleic acid segments is expressed to provide a plurality of modified enzymes. The clones expressing modified enzymes are then screened to identify which enzymes have improved esterase activity by measuring the ability of the enzymes to hydrolyze the selected substrate under the selected reaction conditions. Specific modified para-nitrobenzyl esterases are disclosed which have improved stability and/or ester hydrolysis activity in aqueous or aqueous-organic media relative to the stability and/or ester hydrolysis activity of unmodified naturally occurring para-nitrobenzyl esterase. 43 figs.
Para-nitrobenzyl esterases with enhanced activity in aqueous and nonaqueous media
Arnold, Frances H.; Moore, Jeffrey C.
1999-01-01
A method for isolating and identifying modified para-nitrobenzyl esterases which exhibit improved stability and/or esterase hydrolysis activity toward selected substrates and under selected reaction conditions relative to the unmodified para-nitrobenzyl esterase. The method involves preparing a library of modified para-nitrobenzyl esterase nucleic acid segments (genes) which have nucleotide sequences that differ from the nucleic acid segment which encodes for unmodified para-nitrobenzyl esterase. The library of modified para-nitrobenzyl nucleic acid segments is expressed to provide a plurality of modified enzymes. The clones expressing modified enzymes are then screened to identify which enzymes have improved esterase activity by measuring the ability of the enzymes to hydrolyze the selected substrate under the selected reaction conditions. Specific modified para-nitrobenzyl esterases are disclosed which have improved stability and/or ester hydrolysis activity in aqueous or aqueous-organic media relative to the stability and/or ester hydrolysis activity of unmodified naturally occurring para-nitrobenzyl esterase.
Para-nitrobenzyl esterases with enhanced activity in aqueous and nonaqueous media
Arnold, Frances H.; Moore, Jeffrey C.
1998-01-01
A method for isolating and identifying modified para-nitrobenzyl esterases which exhibit improved stability and/or esterase hydrolysis activity toward selected substrates and under selected reaction conditions relative to the unmodified para-nitrobenzyl esterase. The method involves preparing a library of modified para-nitrobenzyl esterase nucleic acid segments (genes) which have nucleotide sequences that differ from the nucleic acid segment which encodes for unmodified para-nitrobenzyl esterase. The library of modified para-nitrobenzyl nucleic acid segments is expressed to provide a plurality of modified enzymes. The clones expressing modified enzymes are then screened to identify which enzymes have improved esterase activity by measuring the ability of the enzymes to hydrolyze the selected substrate under the selected reaction conditions. Specific modified para-nitrobenzyl esterases are disclosed which have improved stability and/or ester hydrolysis activity in aqueous or aqueous-organic media relative to the stability and/or ester hydrolysis activity of unmodified naturally occurring para-nitrobenzyl esterase.
Para-nitrobenzyl esterases with enhanced activity in aqueous and nonaqueous media
Arnold, F.H.; Moore, J.C.
1998-04-21
A method is disclosed for isolating and identifying modified para-nitrobenzyl esterases. These enzymes exhibit improved stability and/or esterase hydrolysis activity toward selected substrates and under selected reaction conditions relative to the unmodified para-nitrobenzyl esterase. The method involves preparing a library of modified para-nitrobenzyl esterase nucleic acid segments (genes) which have nucleotide sequences that differ from the nucleic acid segment which encodes for unmodified para-nitrobenzyl esterase. The library of modified para-nitrobenzyl nucleic acid segments is expressed to provide a plurality of modified enzymes. The clones expressing modified enzymes are then screened to identify which enzymes have improved esterase activity by measuring the ability of the enzymes to hydrolyze the selected substrate under the selected reaction conditions. Specific modified para-nitrobenzyl esterases are disclosed which have improved stability and/or ester hydrolysis activity in aqueous or aqueous-organic media relative to the stability and/or ester hydrolysis activity of unmodified naturally occurring para-nitrobenzyl esterase. 43 figs.
Para-hydrogen induced polarization in heterogeneous hydrogenationreactions
Koptyug, Igor V.; Kovtunov, Kirill; Burt, Scott R.; Anwar, M.Sabieh; Hilty, Christian; Han, Song-I; Pines, Alexander; Sagdeev, Renad Z.
2007-01-31
We demonstrate the creation and observation ofpara-hydrogen-induced polarization in heterogeneous hydrogenationreactions. Wilkinson's catalyst, RhCl(PPh3)3, supported on eithermodified silica gel or a polymer, is shown to hydrogenate styrene intoethylbenzene and to produce enhanced spin polarizations, observed throughNMR, when the reaction was performed with H2 gas enriched in the paraspinisomer. Furthermore, gaseous phase para-hydrogenation of propylene topropane with two catalysts, the Wilkinson's catalyst supported onmodified silica gel and Rh(cod)(sulfos) (cod = cycloocta-1,5-diene;sulfos) - O3S(C6H4)CH2C(CH2PPh2)3) supported on silica gel, demonstratesheterogeneous catalytic conversion resulting in large spin polarizations.These experiments serve as a direct verification of the mechanism ofheterogeneous hydrogenation reactions involving immobilized metalcomplexes and can be potentially developed into a practical tool forproducing catalyst-free fluids with highly polarized nuclear spins for abroad range of hyperpolarized NMR and MRI applications.
DYNA3D/ParaDyn Regression Test Suite Inventory
Lin, J I
2011-01-25
The following table constitutes an initial assessment of feature coverage across the regression test suite used for DYNA3D and ParaDyn. It documents the regression test suite at the time of production release 10.1 in September 2010. The columns of the table represent groupings of functionalities, e.g., material models. Each problem in the test suite is represented by a row in the table. All features exercised by the problem are denoted by a check mark in the corresponding column. The definition of ''feature'' has not been subdivided to its smallest unit of user input, e.g., algorithmic parameters specific to a particular type of contact surface. This represents a judgment to provide code developers and users a reasonable impression of feature coverage without expanding the width of the table by several multiples. All regression testing is run in parallel, typically with eight processors. Many are strictly regression tests acting as a check that the codes continue to produce adequately repeatable results as development unfolds, compilers change and platforms are replaced. A subset of the tests represents true verification problems that have been checked against analytical or other benchmark solutions. Users are welcomed to submit documented problems for inclusion in the test suite, especially if they are heavily exercising, and dependent upon, features that are currently underrepresented.
Anise oil as para-methoxyamphetamine (PMA) precursor.
Waumans, Dieter; Bruneel, Noël; Tytgat, Jan
2003-04-23
These days, MDMA is one of the most popular drugs of abuse. Due to its illegality, MDMA and its chemical precursors are watched by governmental organizations in many countries. To avoid conflicts with legal instances, underground chemists have tried to market several new unregulated amphetamine analogues, such as 4-MTA. Para-methoxyamphetamine (PMA), on the other hand, is regulated by law but its precursors are easily obtained since they are cheap and unwatched. This article presents such a case, namely the large scale synthesis of PMA using anethole, a main constituent of anise oil, as precursor. Anethole has been converted to its phenyl acetone analogue via peracid oxidation, while PMA itself has been synthesized using this ketone as precursor in the Leuckart synthesis. The synthesis of PMA using anethole as starting product has been investigated applying GC/MS and GC-HSPME/MS techniques, hereby discovering new specific (4-methoxyphenol) and already identified synthesis impurities (4-methyl-5-(4-methoxyphenyl)pyrimidine, N-(beta-4-methoxyphenylisopropyl)-4-methoxybenzyl methyl ketimine, 1-(4-methoxyphenyl)-N-(2-(4-methoxyphenyl)-1-methylethyl-2-propanamine, 1-(4-methoxyphenyl)-N-methyl-N-(2-(4-methoxyphenyl)-1-methylethyl-2-propanamine, N-(beta-4-methoxyphenylisopropyl)-4-methoxybenzaldimine). The new impurity 4-methoxyphenol is specific for the application of a peracid oxidation method where anethole is used as precursor. PMID:12742705
Metabolism of para-aminophenol by rat hepatocytes.
Yan, Z; Nikelly, J G; Killmer, L; Tarloff, J B
2000-08-01
Autoxidation of para-aminophenol (PAP) has been proposed to account for the selective nephrotoxicity of this compound. However, other studies suggest that hepatic metabolites of PAP rather than the parent compound may be responsible for renal damage. These studies were designed to investigate PAP metabolism in isolated hepatocytes. We synthesized several proposed metabolites for analysis by HPLC/mass spectrometry and compared those results with HPLC/mass spectrometric analyses of metabolites found after incubating hepatocytes with PAP. Hepatocytes prepared from male Sprague-Dawley rats were incubated in Krebs-Henseleit buffer at 37 degrees C for 5 h with 2.3 mM PAP under an atmosphere of 5% CO2/95% O2. Aliquots were withdrawn at 0.1 h of incubation and then hourly through 5 h of incubation. Reactions were terminated by the addition of acetonitrile. Hepatocyte viability was unaltered with PAP present in the incubation medium. We found that hepatocytes converted PAP to two major metabolites (PAP-GSH conjugates and PAP-N-acetylcysteine conjugates) and several minor metabolites [PAP-O-glucuronide, acetaminophen (APAP), APAP-O-glucuronide, APAP-GSH conjugates, and 4-hydroxyformanilide]. Preincubating hepatoyctes with 1-aminobenzotriazole, an inhibitor of cytochromes P450, did not alter the pattern of PAP metabolism. In conclusion, we found that PAP was metabolized in hepatocytes predominantly to PAP-GSH conjugates and PAP-N-acetylcysteine conjugates in sufficient quantities to account for the nephrotoxicity of PAP. PMID:10901695
Conformation of ionizable poly Para phenylene ethynylene in dilute solutions
Wijesinghe, Sidath; Maskey, Sabina; Perahia, Dvora; Grest, Gary S.
2015-11-03
The conformation of dinonyl poly para phenylene ethynylenes (PPEs) with carboxylate side chains, equilibrated in solvents of different quality is studied using molecular dynamics simulations. PPEs are of interest because of their tunable electro-optical properties, chemical diversity, and functionality which are essential in wide range of applications. The polymer conformation determines the conjugation length and their assembly mode and affects electro-optical properties which are critical in their current and potential uses. The current study investigates the effect of carboxylate fraction on PPEs side chains on the conformation of chains in the dilute limit, in solvents of different quality. The dinonylmore » PPE chains are modeled atomistically, where the solvents are modeled both implicitly and explicitly. Dinonyl PPEs maintained a stretched out conformation up to a carboxylate fraction f of 0.7 in all solvents studied. The nonyl side chains are extended and oriented away from the PPE backbone in toluene and in implicit good solvent whereas in water and implicit poor solvent, the nonyl side chains are collapsed towards the PPE backbone. Thus, rotation around the aromatic ring is fast and no long range correlations are seen within the backbone.« less
Evidence for para dechlorination of polychlorobiphenyls by methanogenic bacteria
Ye, D.; Quensen, J.F.; Tiedje, J.M.
1995-06-01
When microorganisms eluted from upper Hudson River sediment were cultured without any substrate except polychlorobiphenyl (PCB)-free Hudson River sediment, methane formation was the terminal step of the anaerobic food chain. In sediments containing Aroclor 1242, addition of eubacterium-inhibiting antibiotics, which should have directly inhibited fermentative bacteria and thereby should have indirectly inhibited methanogens, resulted in no dechlorination activity or methane production. However, when substrates for methanogenic bacteria were provided along with the antibiotics (to free the methanogens from dependence on eubacteria), concomitant methane production and dechlorination of PCBs were observed. The dechlorination of Aroclor 1242 was from the para positions, a pattern distinctly different from, and more limited than, the pattern observed with untreated or pasteurized inocula. Both methane production and dechlorination in cultures amended with antibiotics plus methanogenic substrates were inhibited by 2-bromoethanesulfonic acid. These results suggest that the methanogenic bacteria are among the physiological groups capable of anaerobic dechlorination of PCBs, but that the dechlorination observed with methanogenic bacteria is less extensive than the dechlorination observed with more complex anaerobic consortia. 27 refs., 5 figs., 1 tab.
Uninfected Para-Anastomotic Aneurysms after Infrarenal Aortic Grafting
Nano, Giovanni; Cusmai, Francesco; Ramponi, Fabio; Stegher, Silvia; Dell'Aglio, Daniela; Malacrida, Giovanni; Tealdi, Domenico G.
2009-01-01
Purpose This single-institution retrospective review examines the management of uninfected para-anastomotic aneurysms of the abdominal aorta (PAAA), developed after infrarenal grafting. Materials and Methods From October 1979 to November 2005, 31 PAAA were observed in our Department. Twenty-six uninfected PAAA of degenerative etiology, including 24 false and 2 true aneurysms, were candidates for intervention and retrospectively included in our database for management and outcome evaluation. Six (23%) patients were treated as emergencies. Surgery included tube graft interposition (n = 12), new reconstruction (n = 8), and graft removal with extra-anatomic bypass (n = 3). Endovascular management (n = 3) consisted of free-flow tube endografts. Results The mortality rate among the elective and emergency cases was 5% and 66.6%, respectively (p = 0.005). The morbidity rate in elective cases was 57.8%, whereas 75% in emergency cases (p = 0.99). The survival rate during the follow-up was significantly higher for elective cases than for emergency cases. Conclusion Uninfected PAAA is a late complication of aortic grafting, tends to evolve silently and is difficult to diagnose. The prevalence is underestimated and increases with time since surgery. The mortality rate is higher among patients treated as an emergency than among patients who undergo elective surgery, therefore, elective treatment and aggressive management in the case of pseudoaneurysm are the keys to obtain a good outcome. Endovascular treatment could reduce mortality. Patients who undergo infrarenal aortic grafting require life-long surveillance after surgery. PMID:19430556
Sélley, Eszter; Kun, Szilárd; Kürthy, Mária; Kovács, Tibor; Wittmann, István; Molnár, Gergo A
2015-01-01
Former data of our workgroup indicated that the accumulation of oxidized amino acids (meta- and ortho-tyrosine) due to oxidative stress may play an important role in the impaired insulininduced vasoactive properties of different arterial segments. There are evidences, that incorporation of these amino acids into cellular proteins leads to certain hormonal resistances, which might be restored by supplementation with the physiologic isoform, para-tyrosine. Rats in the control group were kept on a regular diet, rats in the cholesterol-fed group received high-fat diet, while the third group of rats received high-fat diet with para-tyrosine supplementation for 16 weeks. Plasma cholesterol level was significantly higher in the cholesterol-fed group, while the level of cholesterol in the cholesterol+para-tyrosine group did not differ significantly from that of the controls. Plasma level of insulin after glucose stimulation was decreased in the cholesterol-fed group, while that in the para-tyrosine supplemented group did not differ significantly from the controls. Vascular para-, meta- and ortho-tyrosine content was measured with HPLC. Elevated vascular meta-tyrosine/para-tyrosine ratio of cholesterol fed rats could be avoided by para-tyrosine supplementation. Vascular response of the thoracic aorta to insulin and liraglutide was assessed by a DMT multi-myograph. Cholesterol feeding resulted in vascular insulin-and liraglutide resistance, which was restored by para-tyrosine supplementation. Incorporation of the oxidative stress induced pathological tyrosine isoforms leads to vascular-hormone-resistances. We show that the physiological amino acid para-tyrosine is capable of restoring hypercholesterolemia-induced increased meta-tyrosine content of the vascular wall, thus attenuating functional vascular damage. PMID:26202368
Endovascular Treatment of a Ruptured Para-Anastomotic Aneurysm of the Abdominal Aorta
Sfyroeras, Giorgos S.; Lioupis, Christos Bessias, Nikolaos; Maras, Dimitris; Pomoni, Maria; Andrikopoulos, Vassilios
2008-07-15
We report a case of a ruptured para-anastomotic aortic aneurysm treated with implantation of a bifurcated stent-graft. A 72-year-old patient, who had undergone aortobifemoral bypass for aortoiliac occlusive disease 16 years ago, presented with a ruptured para-anastomotic aortic aneurysm. A bifurcated stent-graft was successfully deployed into the old bifurcated graft. This is the first report of a bifurcated stent-graft being placed through an 'end-to-side' anastomosed old aortobifemoral graft. Endovascular treatment of ruptured para-anastomotic aortic aneurysms can be accomplished successfully, avoiding open surgery which is associated with increased mortality and morbidity.
Measurement of the formaldehyde ortho to para ratio in three molecular clouds
NASA Technical Reports Server (NTRS)
Kahane, C.; Lucas, R.; Frerking, M. A.; Langer, W. D.; Encrenaz, P.
1984-01-01
Observations of ortho and para H2CO in two types of clouds, a warm cloud (Orion A) and two cold clouds (L183 and TMC1), are presented. The ortho to para ratio in Orion deduced from the H2(C-13)O data is about three, while that for TMC1 is about one and that for L183 is 1-2. The former value is in agreement with the value calculated from chemical models of ortho and para H2CO production. The values for the cold clouds are consistent with thermal equilibrium at a temperature slightly smaller than 10 K.
ERIC Educational Resources Information Center
California State Polytechnic Univ., Pomona.
The Intermediate Science Curriculum Study Spanish language science instruction manual for the intermediate grades focuses on energy of many types. The soft bound volume uses self-pacing and individualized learning to guide the students through a series of experiments. Basically, the students are asked to think about what they do and see, evaluate…
Management of large para-esophageal hiatal hernias.
Collet, D; Luc, G; Chiche, L
2013-12-01
Para-esophageal hernias are relatively rare and typically occur in elderly patients. The various presenting symptoms are non-specific and often occur in combination. These include symptoms of gastro-esophageal reflux (GERD) in 26 to 70% of cases, microcytic anemia in 17 to 47%, and respiratory symptoms in 9 to 59%. Respiratory symptoms are not completely resolved by surgical intervention. Acute complications such as gastric volvulus with incarceration or strangulation are rare (estimated incidence of 1.2% per patient per year) but gastric ischemia leading to perforation is the main cause of mortality. Only patients with symptomatic hernias should undergo surgery. Prophylactic repair to prevent acute incarceration should only be undertaken in patients younger than 75 in good condition; surgical indications must be discussed individually beyond this age. The laparoscopic approach is now generally accepted. Resection of the hernia sac is associated with a lower incidence of recurrence. Repair of the hiatus can be reinforced with prosthetic material (either synthetic or biologic), but the benefit of prosthetic repair has not been clearly shown. Results of prosthetic reinforcement vary in different studies; it has been variably associated with four times fewer recurrences or with no measurable difference. A Collis type gastroplasty may be useful to lengthen a foreshortened esophagus, but no objective criteria have been defined to support this approach. The anatomic recurrence rate can be as high as 60% at 12years. But most recurrences are asymptomatic and do not affect the quality of life index. It therefore seems more appropriate to evaluate functional results and quality of life measures rather than to gauge success by a strict evaluation of anatomic hernia reduction. PMID:24060742
Successful Mnemonics for "por"/"para" and Affirmative Commands with Pronouns.
ERIC Educational Resources Information Center
Mason, Keith
1992-01-01
Two mnemonic devices, "4A Rule" and "PERFECT," are described to simplify the learning of two grammar points: the placement of object pronouns with respect to commands and the distinction between "por" and "para." (five references) (LB)
Tumores carcinoides gastrointestinales—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del tumor carcinoide gastrointestinal, así como referencias a estudios clínicos y otros temas relacionados.
Carcinoma de tumor primario desconocido—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del carcinoma de tumor primario desconocido, así como referencias a estudios clínicos y otros temas relacionados.
Efficient ortho-para conversion of H2 on interstellar grain surfaces
NASA Astrophysics Data System (ADS)
Bron, Emeric; Le Petit, Franck; Le Bourlot, Jacques
2016-04-01
Context. Fast surface conversion between ortho- and para-H2 has been observed in laboratory studies, and it has been proposed that this mechanism plays a role in the control of the ortho-para ratio in the interstellar medium. Observations of rotational lines of H2 in photo-dissociation regions (PDRs) have indeed found significantly lower ortho-para ratios than expected at equilibrium. The mechanisms controlling the balance of the ortho-para ratio in the interstellar medium thus remain incompletely understood, while this ratio can affect the thermodynamical properties of the gas (equation of state, cooling function). Aims: We aim to build an accurate model of ortho-para conversion on dust surfaces based on the most recent experimental and theoretical results, and to validate it by comparison to observations of H2 rotational lines in PDRs. Methods: We propose a statistical model of ortho-para conversion on dust grains with fluctuating dust temperatures. It is based on a master equation approach. This computation is then coupled to full PDR models and compared to PDR observations. Results: We show that the observations of rotational H2 lines indicate a high conversion efficiency on dust grains and that this high efficiency can be accounted for if taking dust temperature fluctuations into account with our statistical model of surface conversion. Simpler models that neglect the dust temperature fluctuations do not reach the high efficiency deduced from the observations. Moreover, this high efficiency induced by dust temperature fluctuations is very insensitive to the values of the model's microphysical parameters. Conclusions: Ortho-para conversion on grains is thus an efficient mechanism in most astrophysical conditions and can play a significant role in controlling the ortho-para ratio.
Pakish, Janelle; Soliman, Pamela T.; Frumovitz, Michael; Westin, Shannon N.; Schmeler, Kathleen M.; dos Reis, Ricardo; Munsell, Mark F.; Ramirez, Pedro T.
2014-01-01
Objective The objective of our study was to compare the surgical outcomes of extraperitoneal laparoscopic, transperitoneal laparoscopic, and robotic transperitoneal para-aortic lymphadenectomy in endometrial cancer staging. Methods A retrospective review was performed from January 2007 to November 2012. Three groups were compared: extraperitoneal laparoscopic para-aortic lymphadenectomy and robotic hysterectomy and pelvic lymphadenectomy (“extraperitoneal group”; N=34); laparoscopic hysterectomy and transperitoneal pelvic and para-aortic lymphadenectomy (“transperitoneal laparoscopic group”; N=108); and robotic hysterectomy and transperitoneal pelvic and para-aortic lymphadenectomy (“transperitoneal robotic group”; N=52). Fisher’s exact test and Kruskal-Wallis test were used for statistical analysis, and statistical significance was defined as P< 0.05. Results Median number of para-aortic lymph nodes obtained was higher in the extraperitoneal group than in the transperitoneal laparoscopic and robotic groups (10, 5, and 4.5 nodes, respectively; P<0.001). Among patients with BMI <35 kg/m2, the median number of para-aortic nodes harvested was higher in the extraperitoneal group than in the transperitoneal laparoscopic and robotic groups (9, 4, and 5 nodes, respectively; P<0.01). The same pattern was observed among patients with BMI ≥35 kg/m2 (10, 6, and 3 nodes, respectively) (P=0.001). There was no significant difference in median estimated blood loss between the extraperitoneal group and either the transperitoneal laparoscopic group (100 vs. 112.5 mL; P=0.06) or the transperitoneal robotic group (100 vs. 67.5 mL; P=0.23). Conclusion Extraperitoneal laparoscopic para-aortic lymphadenectomy resulted in a higher number of para-aortic lymph nodes removed than transperitoneal laparoscopic or robotic lymphadenectomy. The extraperitoneal approach should be considered for endometrial cancer staging. PMID:24361579
NASA Astrophysics Data System (ADS)
Tanaka, Keiichi; Hayashi, Masato; Ohtsuki, Mitsuhiko; Harada, Kensuke; Tanaka, Takehiko
2010-06-01
Ortho-para mixing interaction due to the coupling of nuclear and electron spins was detected for the first time by millimeter-wave spectroscopy of deuterated vinyl radicals, H_2CCD and D_2CCD, of which the ground states are split by the tunneling motion of the α deuteron into two components 0^+ and 0^-, whose separations have been determined to be Δ E_0 = 1186.644(16) and 771.978(18) MHz, respectively. The observed tunneling-rotation spectra are significantly perturbed by the othro-para mixing interaction expressed by < 0^± |H'|0^mprangle = (δ aF(β)/2) S \\cdot(I_β 1-I_β 2), where I_β 1 and I_β 2 are spins of the two hydrogen nuclei in the β position and S is the electron spin, which connects rotational levels in the 0^+ and 0^- states, one being an ortho level and the other a para level. The δ aF(β) constants for H_2CCD and D_2CCD have been determined to be 68.06(53) and 10.63(94) MHz, respectively, consistent each other within the isotopic mass relation. The othro and para states are mixed by about 0.097% and 0.0123% due to this interaction. The δ aF constant for H_2CCH should be similar to that for H_2CCD because of the same probability density of the unpaired electron at the β protons, but could not be determined independently in our previous study. It is because the mixing of para- and ortho-levels of about 0.00044% is much smaller than that for H_2CCD due to the large tunneling splitting of Δ E_0=16271.8429(59) MHz. The rate constant of para to ortho (I_β = 0 → 1) conversion is predicted as 1.2× 10^5 s-1 torr-1 for H_2CCD, suggesting extremely rapid mutual conversion between ortho and para nuclear spin isomers of H_2CCD, which is more than 106 times faster compared with that in closed shell molecules such as H_2CO and H_2CCH_2. K. Tanaka, M. Hayashi, M. Ohtsuki, K. Harada, T. Tanaka, J. Chem. Phys., 131, 111101 (2009). K. Tanaka, M. Toshimitsu, K. Harada, T. Tanaka, J. Chem. Phys., 120, 3604 (2004).
Roka, Eszter; Vecsernyes, Miklos; Bacskay, Ildiko; Félix, Caroline; Rhimi, Moez; Coleman, Anthony W; Perret, Florent
2015-06-01
The passage of Lucifer Yellow across the Caco-2 intestinal model membrane has been studied for the para-sulphonato-calix[n]arenes, the results show that para-sulphonato-calix[4]arene and para-sulphonato-calix[8]arene activate membrane passage when used simultaneously with a transport probe, Lucifer Yellow, whereas para-sulphonato-calix[6]arene has no effect. PMID:25958962
Space-time curvature signatures in Bose-Einstein condensates
NASA Astrophysics Data System (ADS)
Matos, Tonatiuh; Gomez, Eduardo
2015-05-01
We derive a generalized Gross-Pitaevski (GP) equation for a Bose Einstein Condensate (BEC) immersed in a weak gravitational field starting from the covariant Complex Klein-Gordon field in a curved space-time. We compare it with the traditional GP equation where the gravitational field is added by hand as an external potential. We show that there is a small difference of order gz/c2 between them that could be measured in the future using Bose-Einstein Condensates. This represents the next order correction to the Newtonian gravity in a curved space-time.
Relativity and Quantum Mechanics
Braendas, Erkki J.
2007-12-26
The old dilemma of quantum mechanics versus the theory of relativity is reconsidered via a first principles relativistically invariant theory. By analytic extension of quantum mechanics into the complex plane one may (i) include dynamical features such as time- and length-scales and (ii) examine the possibility and flexibility of so-called general Jordan block formations. The present viewpoint asks for a new perspective on the age-old problem of quantum mechanics versus the theory of relativity. To bring these ideas together, we will establish the relation with the Klein-Gordon-Dirac relativistic theory and confirm some dynamical features of both the special and the general relativity theory.
MAPLE Procedures For Boson Fields System On Curved Space - Time
Murariu, Gabriel
2007-04-23
Systems of interacting boson fields are an important subject in the last years. From the problem of dark matter to boson stars' study, boson fields are involved. In the general configuration, it is considered a Klein-Gordon-Maxwell-Einstein fields system for a complex scalar field minimally coupled to a gravitational one. The necessity of studying a larger number of space-time configurations and the huge volume of computations for each particular situation are some reasons for building a MAPLE procedures set for this kind of systems.
Discrete-time quantum walks: Continuous limit and symmetries
Molfetta, G. di; Debbasch, F.
2012-12-15
The continuous limit of one-dimensional discrete-time quantum walks with time-and space-dependent coefficients is investigated. A given quantum walk does not generally admit a continuous limit but some families (1-jets) of quantum walks do. All families (1-jets) admitting a continuous limit are identified. The continuous limit is described by a Dirac-like equation or, alternately, a couple of Klein-Gordon equations. Variational principles leading to these equations are also discussed, together with local invariance properties.
The Invariant Operator Theory, and the Unification of the Fundamental Interactions
NASA Astrophysics Data System (ADS)
Nduka, Amagh
2002-10-01
This paper established explicitly and unambiguously that the Invariant Operator Theory is the most general physical theory that can be constructed in a pseudo-euclidean (space-time) background. Specifically, we show that the field theories of Isaac Newton, Clarke Maxwell, Erwin Schrodinger, Klein-Gordon, and Paul A. M. Dirac are mere derivatives of the new Theory. Finally we discuss the unification of the fundamental interactions. We find that the NEW Physics has succesfully resolved all the outstanding problems of Physics, with the exception of the problem of mass.
Octonic Gravitational Field Equations
NASA Astrophysics Data System (ADS)
Demir, Süleyman; Tanişli, Murat; Tolan, Tülay
2013-08-01
Generalized field equations of linear gravity are formulated on the basis of octons. When compared to the other eight-component noncommutative hypercomplex number systems, it is demonstrated that associative octons with scalar, pseudoscalar, pseudovector and vector values present a convenient and capable tool to describe the Maxwell-Proca-like field equations of gravitoelectromagnetism in a compact and simple way. Introducing massive graviton and gravitomagnetic monopole terms, the generalized gravitational wave equation and Klein-Gordon equation for linear gravity are also developed.
New scale-relativistic derivations of Pauli and Dirac equations
NASA Astrophysics Data System (ADS)
Hammad, F.
2008-02-01
In scale relativity, quantum mechanics is recovered by transcribing the classical equations of motion to fractal spaces and demanding, as dictated by the principle of scale relativity, that the form of these equations be preserved. In the framework of this theory, however, the form of the classical energy equations both in the relativistic and nonrelativistic cases are not preserved. Aiming to get full covariance, i.e., to restore to these equations their classical forms, we show that the scale-relativistic form of the Schrödinger equation yields the Pauli equation, whilst the Pissondes's scale-relativistic form of the Klein-Gordon equation gives the Dirac equation.
Dielectric permittivity of quantum plasma. Part II
NASA Astrophysics Data System (ADS)
Bobylev, Yu. V.; Kuzelev, M. V.
2014-05-01
The transverse and longitudinal dielectric permittivities of isotropic quantum plasma are calculated in the quantum plasma models based on the Dirac and Pauli equations. The dispersion relations for transverse-longitudinal waves in quantum particle beams are derived. Relativistic longitudinal and transverse waves in cold isotropic quantum plasma in models based on the Klein-Gordon and Dirac equations, as well as spin waves in the model based on the Pauli equation, are considered. Conditions for wave-particle resonance interactions in relativistic quantum plasma are analyzed.
Holographic de Sitter Geometry from Entanglement in Conformal Field Theory
NASA Astrophysics Data System (ADS)
de Boer, Jan; Heller, Michal P.; Myers, Robert C.; Neiman, Yasha
2016-02-01
We demonstrate that, for general conformal field theories (CFTs), the entanglement for small perturbations of the vacuum is organized in a novel holographic way. For spherical entangling regions in a constant time slice, perturbations in the entanglement entropy are solutions of a Klein-Gordon equation in an auxiliary de Sitter (dS) spacetime. The role of the emergent timelike direction in dS spacetime is played by the size of the entangling sphere. For CFTs with extra conserved charges, e.g., higher-spin charges, we show that each charge gives rise to a separate dynamical scalar field in dS spacetime.
New tortoise coordinate transformation and Hawking's radiation in de Sitter space
NASA Astrophysics Data System (ADS)
Ibohal, N.; Ibungochouba, T.
2013-01-01
Hawking's radiation effect of Klein-Gordon equation, Dirac particles and Maxwell's electromagnetic fields in the non-stationary rotating de Sitter cosmological space-time is investigated by using a new method of generalized tortoise coordinate transformation. It is found that the new transformation produces constant additional terms in the expressions of the surface gravities and the Hawking's temperatures. If the constant terms are set to zero, then the surface gravities and Hawking's temperatures will be equal to those obtained from the old generalized tortoise coordinate transformations. This shows that the new transformations are more reasonable. The Fermionic spectrum of Dirac particles displays a new spin-rotation coupling effect.
Tortoise Coordinates and Hawking Radiation in a Dynamical Spherically Symmetric Spacetime
NASA Astrophysics Data System (ADS)
Yang, Jian; Zhao, Zheng; Tian, Gui-Hua; Liu, Wen-Biao
2009-12-01
Hawking effect from dynamical spherical Vaidya black hole, Vaidya-Bonner black hole, and Vaidya-de Sitter black hole is investigated using the improved Damour-Ruffini method. After the new tortoise coordinate transformation in which the position r of event horizon is an undetermined function and the temperature parameter κ is an undetermined constant, the Klein-Gordon equation can be written as the standard form at the event horizon, and both r and κ can be determined automatically. Then extending the outgoing wave from outside to inside of the horizon analytically, the Hawking temperature can also be obtained automatically.
NASA Astrophysics Data System (ADS)
Feng, Zhongwen; Li, Guoping; Jiang, Pengying; Pan, Yang; Zu, Xiaotao
2016-07-01
In this paper, we derive the deformed Hamilton-Jacobi equations from the generalized Klein-Gordon equation and generalized Dirac equation. Then, we study the tunneling rate, Hawking temperature and entropy of the higher-dimensional Reissner-Nordström de Sitter black hole via the deformed Hamilton-Jacobi equation. Our results show that the deformed Hamilton-Jacobi equations for charged scalar particles and charged fermions have the same expressions. Besides, the modified Hawking temperatures and entropy are related to the mass and charge of the black hole, the cosmology constant, the quantum number of emitted particles, and the term of GUP effects β.
Spinless Particle in a Magnetic Field Under Minimal Length Scenario
NASA Astrophysics Data System (ADS)
Amirfakhrian, S. M.
2016-06-01
In this article, we studied the Klein-Gordon equation in a generalised uncertainty principle (GUP) framework which predicts a minimal uncertainty in position. We considered a spinless particle in this framework in the presence of a magnetic field, applied in the z-direction, which varies as {1 over {{x^2}}}. We found the energy eigenvalues of this system and also obtained the correspounding eigenfunctions, using the numerical method. When GUP parameter tends to zero, our solutions were in agreement with those obtained in the absence of GUP.
Parametric resonance of intrinsic localized modes in coupled cantilever arrays
NASA Astrophysics Data System (ADS)
Kimura, Masayuki; Matsushita, Yasuo; Hikihara, Takashi
2016-08-01
In this study, the parametric resonances of pinned intrinsic localized modes (ILMs) were investigated by computing the unstable regions in parameter space consisting of parametric excitation amplitude and frequency. In the unstable regions, the pinned ILMs were observed to lose stability and begin to fluctuate. A nonlinear Klein-Gordon, Fermi-Pasta-Ulam-like, and mixed lattices were investigated. The pinned ILMs, particularly in the mixed lattice, were destabilized by parametric resonances, which were determined by comparing the shapes of the unstable regions with those in the Mathieu differential equation. In addition, traveling ILMs could be generated by parametric excitation.
Sausage Mode Propagation in a Thick Magnetic Flux Tube
NASA Astrophysics Data System (ADS)
Pardi, A.; Ballai, I.; Marcu, A.; Orza, B.
2014-04-01
The aim of this paper is to model the propagation of slow magnetohydrodynamic (MHD) sausage waves in a thick expanding magnetic flux tube in the context of the quiescent (VAL-C) solar atmosphere. The propagation of these waves is found to be described by the Klein-Gordon equation. Using the governing MHD equations and the VAL-C atmosphere model we study the variation of the cut-off frequency along and across the magnetic tube guiding the waves. Due to the radial variation of the cut-off frequency the flux tubes act as low frequency filters for the waves.
Solitonic axion condensates modeling dark matter halos
NASA Astrophysics Data System (ADS)
Castañeda Valle, David; Mielke, Eckehard W.
2013-09-01
Instead of fluid type dark matter (DM), axion-like scalar fields with a periodic self-interaction or some truncations of it are analyzed as a model of galaxy halos. It is probed if such cold Bose-Einstein type condensates could provide a viable soliton type interpretation of the DM 'bullets' observed by means of gravitational lensing in merging galaxy clusters. We study solitary waves for two self-interacting potentials in the relativistic Klein-Gordon equation, mainly in lower dimensions, and visualize the approximately shape-invariant collisions of two 'lump' type solitons.
Post-measurement bipartite entanglement entropy in conformal field theories
NASA Astrophysics Data System (ADS)
Rajabpour, M. A.
2015-08-01
We derive exact formulas for bipartite von Neumann entanglement entropy after partial projective local measurement in (1 +1 ) -dimensional conformal field theories with periodic and open boundary conditions. After defining the setup we will check numerically the validity of our results in the case of Klein-Gordon field theory (coupled harmonic oscillators) and spin-1 /2 X X chain in a magnetic field. The agreement between analytical results and the numerical calculations is very good. We also find a lower bound for localizable entanglement in coupled harmonic oscillators.
The question of the realizability of the Landau scenario for the development of turbulence
NASA Astrophysics Data System (ADS)
Glyzin, S. D.; Kolesov, A. Yu.; Rozov, N. Kh.
2009-02-01
We suggest a phenomenological model for the development of turbulence in the form of the nonlinear Klein-Gordon equation perturbed by nonconservative disturbances. Combining analytic and numerical methods, we establish that the transition to turbulence in this equation can follow both the Landau and the Landau-Sell scenarios. As is known, the first scenario is related to a cascade of bifurcations of stable invariant tori of increasing dimensions. The other scenario is related to a chaotic attractor whose Lyapunov dimension increases indefinitely under variation of a certain control parameter.
Separability of test fields equations on the C -metric background
NASA Astrophysics Data System (ADS)
KofroÅ, David
2015-12-01
In the Kerr-Newman spacetime the Teukolsky master equation, governing the fundamental test fields, is of great importance. We derive an analogous master equation for the nonrotating C -metric which encompasses a massless Klein-Gordon field, neutrino field, Maxwell field, Rarita-Schwinger field and gravitational perturbations. This equation is shown to be separable in terms of "accelerated spin-weighted spherical harmonics." It is shown that, contrary to ordinary spin-weighted spherical harmonics, the "accelerated" ones are different for different spins. In some cases, the equations for eigenfunctions and eigenvalues are explicitly solved.
Rotating black holes can have short bristles
NASA Astrophysics Data System (ADS)
Hod, Shahar
2014-12-01
The elegant 'no short hair' theorem states that, if a spherically-symmetric static black hole has hair, then this hair must extend beyond 3/2 the horizon radius. In the present paper we provide evidence for the failure of this theorem beyond the regime of spherically-symmetric static black holes. In particular, we show that rotating black holes can support extremely short-range stationary scalar configurations (linearized scalar 'clouds') in their exterior regions. To that end, we solve analytically the Klein-Gordon-Kerr-Newman wave equation for a linearized massive scalar field in the regime of large scalar masses.
Scalar-field theory of dark matter
NASA Astrophysics Data System (ADS)
Huang, Kerson; Xiong, Chi; Zhao, Xiaofei
2014-05-01
We develop a theory of dark matter based on a previously proposed picture, in which a complex vacuum scalar field makes the universe a superfluid, with the energy density of the superfluid giving rise to dark energy, and variations from vacuum density giving rise to dark matter. We formulate a nonlinear Klein-Gordon equation to describe the superfluid, treating galaxies as external sources. We study the response of the superfluid to the galaxies, in particular, the emergence of the dark-matter galactic halo, contortions during galaxy collisions and the creation of vortices due to galactic rotation.
Spacetime alternatives in the quantum mechanics of a relativistic particle
Whelan, J.T. Isaac Newton Institute for Mathematical Sciences, 20 Clarkson Road, Cambridge, CB3 0EH )
1994-11-15
Hartle's generalized quantum mechanics formalism is used to examine spacetime coarse grainings, i.e., sets of alternatives defined with respect to a region extended in time as well as space, in the quantum mechanics of a free relativistic particle. For a simple coarse graining and suitable initial conditions, tractable formulas are found for branch wave functions. Despite the nonlocality of the positive-definite version of the Klein-Gordon inner product, which means that nonoverlapping branches are not sufficient to imply decoherence, some initial conditions are found to give decoherence and allow the consistent assignment of probabilities.
Effective photon mass and exact translating quantum relativistic structures
NASA Astrophysics Data System (ADS)
Haas, Fernando; Manrique, Marcos Antonio Albarracin
2016-04-01
Using a variation of the celebrated Volkov solution, the Klein-Gordon equation for a charged particle is reduced to a set of ordinary differential equations, exactly solvable in specific cases. The new quantum relativistic structures can reveal a localization in the radial direction perpendicular to the wave packet propagation, thanks to a non-vanishing scalar potential. The external electromagnetic field, the particle current density, and the charge density are determined. The stability analysis of the solutions is performed by means of numerical simulations. The results are useful for the description of a charged quantum test particle in the relativistic regime, provided spin effects are not decisive.
Annihilation of the scalar pair into a photon in a de Sitter universe
NASA Astrophysics Data System (ADS)
Băloi, Mihaela-Andreea
2016-05-01
The annihilation of massive scalar particles in one photon in de Sitter expanding universe is studied, using perturbative QED. The amplitude and probability corresponding to this process is computed using the exact solutions of the Klein-Gordon and Maxwell equations on de Sitter geometry. Our results show that the expression of the total probability of photon emission is a function dependent on the ratio mass/expansion factor. We perform a graphical study of the total probability in terms of the parameter mass/expansion factor, showing that this effect is significant only in strong gravitational fields. We also obtain that the total probability for this process vanishes in the Minkowski limit.
NASA Astrophysics Data System (ADS)
Oluwadare, O. J.; Oyewumi, K. J.; Akoshile, C. O.; Babalola, O. A.
2012-09-01
By employing the Pekeris-type (or a new improved approximation) to deal with the (pseudo or) centrifugal term, we solve the Klein-Gordon and Dirac equations with equally mixed scalar and vector Deng-Fan molecular potentials for all values of l (orbital the angular momentum quantum number) and κ (spin-orbit coupling quantum number), respectively. Using the formalism of the Nikiforov-Uvarov method, the approximate analytical bound state energy equations and the associated two-component spinors corresponding to the two relativistic equations are obtained. Also, special cases including the non-relativistic limits of the relativistic equation are obtained.
Evolution and stability Φ4 oscillatons
NASA Astrophysics Data System (ADS)
Ureña-López, L. Arturo; Valdez-Alvarado, Susana; Becerril, Ricardo
2012-03-01
We solve numerically the Einstein-Klein-Gordon (EKG) system, assuming spherical symmetry, for a real scalar field endowed with a quartic self-interaction potential, and obtain the so-called oscillatons: oscillating soliton stars. We obtain the equilibrium configurations for Φ4oscillatons. Also, we analyze numerically the evolution of the EKG equations to study the stability of such oscillatons. We present the influence of the quartic potential on the behavior of both the stable (S-oscillatons) and unstable (U-oscillatons) branches, under the influence of small and large radial perturbations.
Wu, Shuang-Qing
2008-03-28
I present the general exact solutions for nonextremal rotating charged black holes in the Gödel universe of five-dimensional minimal supergravity theory. They are uniquely characterized by four nontrivial parameters: namely, the mass m, the charge q, the Kerr equal rotation parameter a, and the Gödel parameter j. I calculate the conserved energy, angular momenta, and charge for the solutions and show that they completely satisfy the first law of black hole thermodynamics. I also study the symmetry and separability of the Hamilton-Jacobi and the massive Klein-Gordon equations in these Einstein-Maxwell-Chern-Simons-Gödel black hole backgrounds. PMID:18517852
Scalar particles emission from black holes with topological defects using Hamilton-Jacobi method
NASA Astrophysics Data System (ADS)
Jusufi, Kimet
2015-11-01
We study quantum tunneling of charged and uncharged scalar particles from the event horizon of Schwarzschild-de Sitter and Reissner-Nordström-de Sitter black holes pierced by an infinitely long spinning cosmic string and a global monopole. In order to find the Hawking temperature and the tunneling probability we solve the Klein-Gordon equation by using the Hamilton-Jacobi method and WKB approximation. We show that Hawking temperature is independent of the presence of topological defects in both cases.
Tunnelling of relativistic particles from new type black hole in new massive gravity
NASA Astrophysics Data System (ADS)
Gecim, Ganim; Sucu, Yusuf
2013-02-01
In the framework of the three dimensional New Massive Gravity theory introduced by Bergshoeff, Hohm and Townsend, we analyze the behavior of relativistic spin-1/2 and spin-0 particles in the New-type Black Hole backgroud, solution of the New Massive Gravity.We solve Dirac equation for spin-1/2 and Klein-Gordon equation for spin-0. Using Hamilton-Jacobi method, we discuss tunnelling probability and Hawking temperature of the spin-1/2 and spin-0 particles for the black hole. We observe that the tunnelling probability and Hawking temperature are same for the spin-1/2 and spin-0.
NASA Astrophysics Data System (ADS)
Wu, Shuang-Qing
2008-03-01
I present the general exact solutions for nonextremal rotating charged black holes in the Gödel universe of five-dimensional minimal supergravity theory. They are uniquely characterized by four nontrivial parameters: namely, the mass m, the charge q, the Kerr equal rotation parameter a, and the Gödel parameter j. I calculate the conserved energy, angular momenta, and charge for the solutions and show that they completely satisfy the first law of black hole thermodynamics. I also study the symmetry and separability of the Hamilton-Jacobi and the massive Klein-Gordon equations in these Einstein-Maxwell-Chern-Simons-Gödel black hole backgrounds.
Spectral domains for bosonic pair creation in static electromagnetic fields
NASA Astrophysics Data System (ADS)
Lv, Q. Z.; Li, Y. J.; Grobe, R.; Su, Q.
2016-04-01
We study the emission spectrum of bosons created from the vacuum by combined static electric and magnetic fields. Depending on the spatial extension of the magnetic field, we find four regimes of pair creation, characterized by different growth behaviors of the number of the produced particles. We show that these regimes manifest themselves in the eigenenergy spectrum of the Klein-Gordon Hamiltonian. The regimes also lead to rather different kinetic energy spectra of the emitted bosons, whose peak positions can be obtained from a generalized Fano-like perturbative approach.
Quantized scalar field as DM: the axion's case
Barranco, J.; Bernal, A.
2008-12-04
We derive a rough estimation of the radius and the mass of a self-gravitating system made of axions. The system is a stationary solution of the Einstein-Klein-Gordon equations with a source term given by the vacuum expectation value of the energy-momentum operator constructed from the axion field. We found that such system would have masses of the order of asteroids ({approx}10{sup -10} M{sub {center_dot}}) and radius of the order of few centimeters. Some implications of such type of objects are discussed.
Hidden symmetries of higher-dimensional black holes and uniqueness of the Kerr-NUT-(A)dS spacetime
Krtous, Pavel; Frolov, Valeri P.; Kubiznak, David
2008-09-15
We prove that the most general solution of the Einstein equations with the cosmological constant which admits a principal conformal Killing-Yano tensor is the Kerr-NUT-(A)dS metric. Even when the Einstein equations are not imposed, any spacetime admitting such hidden symmetry can be written in a canonical form which guarantees the following properties: it is of the Petrov type D, it allows the separation of variables for the Hamilton-Jacobi, Klein-Gordon, and Dirac equations, the geodesic motion in such a spacetime is completely integrable. These results naturally generalize the results obtained earlier in four dimensions.
Closed conformal Killing Yano tensor and the uniqueness of generalized Kerr NUT de Sitter spacetime
NASA Astrophysics Data System (ADS)
Houri, Tsuyoshi; Oota, Takeshi; Yasui, Yukinori
2009-02-01
The higher-dimensional Kerr NUT de Sitter spacetime describes the general rotating asymptotically de Sitter black hole with NUT parameters. It is known that such a spacetime possesses a rank-2 closed conformal Killing Yano (CKY) tensor as a 'hidden' symmetry which provides the separation of variables for the geodesic equations and Klein Gordon equations. We present a classification of higher-dimensional spacetimes admitting a rank-2 closed CKY tensor. This provides a generalization of the Kerr NUT de Sitter spacetime. In particular, we show that the Kerr NUT de Sitter spacetime is the only spacetime with a non-degenerate CKY tensor.
Hidden Symmetries of Higher-Dimensional Black Hole Spacetimes
NASA Astrophysics Data System (ADS)
Frolov, V. P.
The paper contains a brief review of recent results onhidden symmetries in higher dimensional black hole spacetimes. We show how the existence of a principal CKY tensor (that is a closed non-degenerate conformal Killing-Yano 2-form) allows one to generate a `tower' of Killing-Yano and Killing tensors responcible for hidden symmetries. These symmetries imply complete integrability of geodesic equations and the complete separation of variables in the Hamilton-Jacobi, Klein-Gordon and Dirac equations in the general Kerr-NUT-(A)dS metrics.
A Killing tensor for higher dimensional Kerr-AdS black holes with NUT charge
NASA Astrophysics Data System (ADS)
Davis, Paul
2006-05-01
In this paper, we study the recently discovered family of higher dimensional Kerr-AdS black holes with an extra NUT-like parameter. We show that the inverse metric is additively separable after multiplication by a simple function. This allows us to separate the Hamilton Jacobi equation, showing that geodesic motion is integrable on this background. The separation of the Hamilton Jacobi equation is intimately linked to the existence of an irreducible Killing tensor, which provides an extra constant of motion. We also demonstrate that the Klein Gordon equation for this background is separable.
Hidden symmetries of higher-dimensional black holes and uniqueness of the Kerr-NUT-(A)dS spacetime
NASA Astrophysics Data System (ADS)
Krtouš, Pavel; Frolov, Valeri P.; Kubizňák, David
2008-09-01
We prove that the most general solution of the Einstein equations with the cosmological constant which admits a principal conformal Killing-Yano tensor is the Kerr-NUT-(A)dS metric. Even when the Einstein equations are not imposed, any spacetime admitting such hidden symmetry can be written in a canonical form which guarantees the following properties: it is of the Petrov type D, it allows the separation of variables for the Hamilton-Jacobi, Klein-Gordon, and Dirac equations, the geodesic motion in such a spacetime is completely integrable. These results naturally generalize the results obtained earlier in four dimensions.
Two-charge rotating black holes in four-dimensional gauged supergravity
NASA Astrophysics Data System (ADS)
Chow, David D. K.
2011-09-01
We obtain an asymptotically AdS, non-extremal, electrically charged and rotating black hole solution of four-dimensional U(1)4 gauged supergravity with two non-zero and independent U(1) charges. The thermodynamical quantities are computed. We find BPS solutions that are nakedly singular. The solution is generalized to include a NUT parameter and dyonic gauge fields. The string frame metric has a rank-2 Killing-Stäckel tensor and has completely integrable geodesic motion, and the massless Klein-Gordon equation separates for the Einstein frame metric.
Hidden symmetries and black holes
NASA Astrophysics Data System (ADS)
Frolov, Valeri P.
2009-10-01
The paper contains a brief review of recent results on hidden symmetries in higher dimensional black hole spacetimes. We show how the existence of a principal CKY tensor (that is a closed conformal Killing-Yano 2-form) allows one to generate a `tower' of Killing-Yano and Killing tensors responsible for hidden symmetries. These symmetries imply complete integrability of geodesic equations and the complete separation of variables in the Hamilton-Jacobi, Klein-Gordon, Dirac and gravitational perturbation equations in the general Kerr-NUT-(A)dS metrics. Equations of the parallel transport of frames along geodesics in these spacetimes are also integrable.
Topological quantum scattering under the influence of a nontrivial boundary condition
NASA Astrophysics Data System (ADS)
Mota, Herondy
2016-04-01
We consider the quantum scattering problem of a relativistic particle in (2 + 1)-dimensional cosmic string spacetime under the influence of a nontrivial boundary condition imposed on the solution of the Klein-Gordon equation. The solution is then shifted as consequence of the nontrivial boundary condition and the role of the phase shift is to produce an Aharonov-Bohm-like effect. We examine the connection between this phase shift and the electromagnetic and gravitational analogous of the Aharonov-Bohm effect and compare the present results with previous ones obtained in the literature, also considering non-relativistic cases.
Experimental determination of the relativistic fine-structure splitting in pionic Ti and Fe atoms
Wang, K.; Boehm, F.; Bovet, E.; Hahn, A.A.; Henrikson, H.E.; Miller, J.P.; Powers, R.J.; Vogel, P.; Vuilleumier, J.; Kunselman, A.R.
1980-09-01
Using a high-resolution crystal spectrometer we have measured the relativistic angular-momentum splittings of the 5g-4f and 5f-4d transitions in pionic Ti and Fe atoms. The observed fine-structure splittings of 85.3 +- 3.0 eV in ..pi../sup -/ Ti and 158.5 +- 7.8 eV in ..pi../sup -/ Fe agree with the calculated splittings of 88.5 and 167.6 eV, respectively, arising from the Klein-Gordon equation and from small corrections due to vacuum polarization, strong interaction, and electron screening.
Kato Smoothing and Strichartz Estimates for Wave Equations with Magnetic Potentials
NASA Astrophysics Data System (ADS)
D'Ancona, Piero
2015-04-01
Let H be a selfadjoint operator and A a closed operator on a Hilbert space . If A is H-(super)smooth in the sense of Kato-Yajima, we prove that is -(super)smooth. This allows us to include wave and Klein-Gordon equations in the abstract theory at the same level of generality as Schrödinger equations. We give a few applications and in particular, based on the resolvent estimates of Erdogan, Goldberg and Schlag (Forum Mathematicum 21:687-722, 2009), we prove Strichartz estimates for wave equations perturbed with large magnetic potentials on , n ≥ 3.
The propagation of particles and fields in wormhole geometries
NASA Astrophysics Data System (ADS)
Sarbach, Olivier; Zannias, Thomas
2012-08-01
We discuss several properties of static, spherically symmetric wormholes with particular emphasis on the behavior of causal geodesics and the propagation of linear fields. We show there always exist null geodesics which are trapped in a region close to the throat. Depending upon the detailed structure of the wormhole geometry, these trapped geodesics can be stable, unlike the case of the Schwarzschild black hole. We also show that test scalar fields propagating on such wormholes are stable. However, when a mixture of ghost and Klein-Gordon scalar fields is used as a source of the Einstein equations we prove that the resulting static, spherically symmetric wormhole configurations are linearly unstable.
Quantum singularities in a model of f( R) gravity
NASA Astrophysics Data System (ADS)
Gurtug, O.; Tahamtan, T.
2012-07-01
The formation of a naked singularity in a model of f( R) gravity having as source a linear electromagnetic field is considered in view of quantum mechanics. Quantum test fields obeying the Klein-Gordon, Dirac and Maxwell equations are used to probe the classical timelike naked singularity developed at r=0. We prove that the spatial derivative operator of the fields fails to be essentially self-adjoint. As a result, the classical timelike naked singularity remains quantum mechanically singular when it is probed with quantum fields having different spin structures.
Quasinormal frequencies of asymptotically anti-de Sitter black holes in two dimensions
NASA Astrophysics Data System (ADS)
Cordero, R.; López-Ortega, A.; Vega-Acevedo, I.
2012-04-01
We calculate exactly the quasinormal frequencies of Klein-Gordon and Dirac test fields propagating in 2D uncharged Achucarro-Ortiz black hole. For both test fields we study whether the quasinormal frequencies are well defined in the massless limit. We use their values to discuss the classical stability of the quasinormal modes in uncharged Achucarro-Ortiz black hole and to check the recently proposed Time Times Temperature bound. Furthermore we extend some of these results to the charged Achucarro-Ortiz black hole.
Quantum singularities in spherically symmetric, conformally static spacetimes
NASA Astrophysics Data System (ADS)
Helliwell, T. M.; Konkowski, D. A.
2013-05-01
A definition of quantum singularity for the case of static spacetimes has recently been extended to conformally static spacetimes. Here the theory behind quantum singularities in conformally static spacetimes is reviewed and then applied to a class of spherically symmetric, conformally static spacetimes, including as special cases those studied by Roberts, by Fonarev, and by Husain et al. We use solutions of the generally coupled, massless Klein-Gordon equation as test fields. In this way we find the ranges of metric parameters and coupling coefficients for which classical timelike singularities in these spacetimes are healed quantum mechanically.
Quantum resolution of timelike singularities in spherically symmetric, self-similar spacetimes
NASA Astrophysics Data System (ADS)
Konkowski, Deborah; Helliwell, Thomas; Williams, Jon
2015-04-01
A definition of quantum singularity for the case of static spacetimes has recently been extended to conformally static spacetimes. Here the theory behind quantum singularities in conformally static spacetimes is reviewed, and then applied to a class of spherically symmetric, self-similar spacetimes. We use solutions of the massless Klein-Gordon equation as test fields. In this way we find the ranges of metric parameters for which classical timelike singularities in these spacetimes are resolved quantum mechanically, in the sense that the Hamiltonian operator is essentially self-adjoint, so the evolution of quantum wave packets lacks the usual ambiguity associated with scattering off singulartities.
Visinescu, M.
2012-10-15
Hidden symmetries in a covariant Hamiltonian framework are investigated. The special role of the Stackel-Killing and Killing-Yano tensors is pointed out. The covariant phase-space is extended to include external gauge fields and scalar potentials. We investigate the possibility for a higher-order symmetry to survive when the electromagnetic interactions are taken into account. Aconcrete realization of this possibility is given by the Killing-Maxwell system. The classical conserved quantities do not generally transfer to the quantized systems producing quantum gravitational anomalies. As a rule the conformal extension of the Killing vectors and tensors does not produce symmetry operators for the Klein-Gordon operator.
Modulational instability of charge transport in the Peyrard-Bishop-Holstein model.
Tabi, Conrad Bertrand; Mohamadou, Alidou; Kofané, Timoléon Crépin
2009-08-19
We report on modulational instability (MI) on a DNA charge transfer model known as the Peyrard-Bishop-Holstein (PBH) model. In the continuum approximation, the system reduces to a modified Klein-Gordon-Schrödinger (mKGS) system through which linear stability analysis is performed. This model shows some possibilities for the MI region and the study is carried out for some values of the nearest-neighbor transfer integral. Numerical simulations are then performed, which confirm analytical predictions and give rise to localized structure formation. We show how the spreading of charge deeply depends on the value of the charge-lattice-vibrational coupling. PMID:21828595
Stochastic eternal inflation in a Bianchi type I universe
NASA Astrophysics Data System (ADS)
Kohli, Ikjyot Singh; Haslam, Michael C.
2016-01-01
The phenomenon of stochastic eternal inflation is studied for a chaotic inflation potential in a Bianchi type I spacetime background. After deriving the appropriate stochastic Klein-Gordon equation, we give details on the conditions for eternal inflation. It is shown that for eternal inflation to occur, the amount of anisotropy must be small. In fact, it is shown that eternal inflation will only take place if the shear anisotropy variables take on values within a small region of the interior of the Kasner circle. We then calculate the probability of eternal inflation occurring based on techniques from stochastic calculus.
Partially Strong Transparency Conditions and a Singular Localization Method In Geometric Optics
NASA Astrophysics Data System (ADS)
Lu, Yong; Zhang, Zhifei
2016-03-01
This paper focuses on the stability analysis of WKB approximate solutions in geometric optics with the absence of strong transparency conditions under the terminology of Joly, Métivier and Rauch. We introduce a compatible condition and a singular localization method which allows us to prove the stability of WKB solutions over long time intervals. This compatible condition is weaker than the strong transparency condition. The singular localization method allows us to do delicate analysis near resonances. As an application, we show the long time approximation of Klein-Gordon equations by Schrödinger equations in the non-relativistic limit regime.
Hot Fluids and Nonlinear Quantum Mechanics
NASA Astrophysics Data System (ADS)
Mahajan, Swadesh M.; Asenjo, Felipe A.
2015-05-01
A hot relativistic fluid is viewed as a collection of quantum objects that represent interacting elementary particles. We present a conceptual framework for deriving nonlinear equations of motion obeyed by these hypothesized objects. A uniform phenomenological prescription, to affect the quantum transition from a corresponding classical system, is invoked to derive the nonlinear Schrödinger, Klein-Gordon, and Pauli-Schrödinger and Feynman-GellMaan equations. It is expected that the emergent hypothetical nonlinear quantum mechanics would advance, in a fundamental way, both the conceptual understanding and computational abilities, particularly, in the field of extremely high energy-density physics.
On the Pauli-Weisskopf anti-Dirac paper
NASA Astrophysics Data System (ADS)
Dittrich, Walter
2015-03-01
We review in this article the role which the work of Pauli and Weisskopf played in formulating a quantum field theory of spinless particles. To make our computations as transparent as possible, we offer a physicist's derivation of the Klein-Gordon-Fock equation. Since invariant functions play a significant part in our paper, we will discuss them in great detail. We emphasize Pauli's and Weisskopf's view that Dirac's hole theory is totally obsolete in formulating a consistent quantum field theory, be it for scalar or spinor particles. As an important example we present the calculation for producing charged scalar particles in an external electric field.
Energy Criterion for the Spectral Stability of Discrete Breathers.
Kevrekidis, Panayotis G; Cuevas-Maraver, Jesús; Pelinovsky, Dmitry E
2016-08-26
Discrete breathers are ubiquitous structures in nonlinear anharmonic models ranging from the prototypical example of the Fermi-Pasta-Ulam model to Klein-Gordon nonlinear lattices, among many others. We propose a general criterion for the emergence of instabilities of discrete breathers analogous to the well-established Vakhitov-Kolokolov criterion for solitary waves. The criterion involves the change of monotonicity of the discrete breather's energy as a function of the breather frequency. Our analysis suggests and numerical results corroborate that breathers with increasing (decreasing) energy-frequency dependence are generically unstable in soft (hard) nonlinear potentials. PMID:27610856
Vesicular erythema multiforme-like reaction to para-phenylenediamine in a henna tattoo.
Sidwell, Rachel U; Francis, Nick D; Basarab, Tamara; Morar, Nilesh
2008-01-01
Allergic contact dermatitis reaction to topical "black henna" tattoo is usually described secondary to the organic dye para-phenylenediamine, a derivative of analine. Allergic contact dermatitis reactions to para-phenylenediamine are well recognized and most commonly involve an eczematous reaction that may become generalized and an acute angio-edema. Only four previous instances have been reported of an erythema multiforme-like reaction to para-phenylenediamine and its derivatives, including only one mild reaction to a tattoo. A vesicular erythema multiforme-like reaction has not been reported. An erythema multiforme-like reaction to contact allergens is usually caused by potent allergens including plant quinolones in Compositae and sesquiterpene lactones in exotic woods, and it is also reported to topical drugs, epoxy resin, metals (particularly nickel), and various chemicals. A generalized vesicular erythema multiforme-like reaction is unusual, and rarely reported. We describe a 6-year-old boy who developed a localized, eczematous and severe generalized vesicular erythema multiforme-like contact allergy to para-phenylenediamine secondary to a henna tattoo. As henna tattoos are becoming increasingly popular, one should be aware of the possibility of such a reaction. This presentation also highlights the call to ban the use of para-phenylenediamine and its derivatives in dyes. PMID:18429780
Sistemas Correctores de Campo Para EL Telescopio Ritchey-Chretien UNAM212
NASA Astrophysics Data System (ADS)
Cobos, F. J.; Galan, M. J.
1987-05-01
El telescopio UNAM2l2 fue inaugurado hace siete años y concebido para trabajar en las razones focales: f/7.5, F/13.5, F/27 y F/98. El diseño Ritchey-Chretién corresponde a la razón focal F/7.5 y el foco primario (F/2.286) no se consideró como utilizable para fotografía directa. En el Instituto de Astronomía de la UNAM, se diseñó y construyó un sistema corrector de campo para la razón focal F/7.5, que actualmente está en funcionamiento. Dentro de un programa de colaboración en diseflo y evaluación de sistemas ópticos, entre el Instituto de Astrofísica de Canarias y el Instituto de Astronomía de la UNAM, decidimos intentar el diseño de una correctora de campo para el foco primario del tȩlescopio UNAM212 bajo la consideración de que no son insalvables los problemas que implicaría su instalación y de que es muy posible que, en un futuro relativamente cercano, podamom tener un detector bidimenmional tipo Mepsicrón cuya área sensible haga tentadora la idea de construir la cámara directa para foco primario
On the Ortho:Para Ratio of H+ 3 in Diffuse Molecular Clouds
NASA Astrophysics Data System (ADS)
Crabtree, Kyle N.; Indriolo, Nick; Kreckel, Holger; Tom, Brian A.; McCall, Benjamin J.
2011-03-01
The excitation temperature T 01 derived from the relative intensities of the J = 0 (para) and J = 1 (ortho) rotational levels of H2 has been assumed to be an accurate measure of the kinetic temperature in interstellar environments. In diffuse molecular clouds, the average value of T 01 is ~70 K. However, the excitation temperature T(H+ 3) derived from the (J, K) = (1, 1) (para) and (1, 0) (ortho) rotational levels of H+ 3 has been observed to be ~30 K in the same types of environments. In this work, we present observations of H+ 3 in three additional diffuse cloud sight lines for which H2 measurements are available, showing that in four of five cases T 01 and T(H+ 3) are discrepant. We then examine the thermalization mechanisms for the ortho:para ratios of H+ 3 and H2, concluding that indeed T 01 is an accurate measure of the cloud kinetic temperature, while the ortho:para ratio of H+ 3 need not be thermal. By constructing a steady-state chemical model taking into account the nuclear spin dependence of reactions involving H+ 3, we show that the ortho:para ratio of H+ 3 in diffuse molecular clouds is likely governed by a competition between dissociative recombination with electrons and thermalization via reactive collisions with H2. Based in part on observations made with ESO Telescopes at the La Silla or Paranal Observatories under program ID 384.C-0618.
The formaldehyde ortho/para ratio as a probe of dark cloud chemistry and evolution
NASA Technical Reports Server (NTRS)
Dickens, J. E.; Irvine, W. M.
1999-01-01
We present measurements of the H2CO ortho/para ratio toward four star-forming cores, L723, L1228, L1527, and L43, and one quiescent core, L1498. Combining these data with earlier results by Minh et al., three quiescent cores are found to have ortho/para ratios near 3, the ratio of statistical weights expected for gas-phase formation processes. In contrast, ortho/para ratios are 1.5-2.1 in five star-forming cores, suggesting thermalization at a kinetic temperature of 10 K. We attribute modification of the ortho/para ratio in the latter cores to formation and/or equilibration of H2CO on grains with sub-sequent release back into the gas phase due to the increased energy inputs from the forming star and outflow. We see accompanying enhancements in the H2CO abundance relative to H, to support this idea. The results suggest that the formaldehyde ortho/para ratio can differentiate between quiescent cores and those in which low-mass star formation has occurred.
NASA Astrophysics Data System (ADS)
Xin, X.; Altan, H.; Saint, A.; Matten, D.; Alfano, R. R.
2006-11-01
Terahertz time-domain spectroscopy has been used to measure the absorption of water vapor in 0.2-2.4THz range from low to high humidity at room temperature. The observed absorption lines are due to the water molecular rotations in the ground vibrational state. We find that the absorption strength of para transitions increases as humidity increases, while the absorption strength of ortho transitions increases and then decreases in intensity with increasing humidity. We explain this difference based on the nuclear spin statistics based ratio of ortho to para water monomer populations at room temperature. The preferential adsorption on the solid surfaces of para water leads to an ortho dominated vapor cloud whose monomer rotational absorption intensity decreases due to the effects of dimerization, molecular collisions, clustering, and interactions with liquid droplets at high concentrations.
Production and characterization of para-hydrogen gas for matrix isolation infrared spectroscopy
NASA Astrophysics Data System (ADS)
Sundararajan, K.; Sankaran, K.; Ramanathan, N.; Gopi, R.
2016-08-01
Normal hydrogen (n-H2) has 3:1 ortho/para ratio and the production of enriched para-hydrogen (p-H2) from normal hydrogen is useful for many applications including matrix isolation experiments. In this paper, we describe the design, development and fabrication of the ortho-para converter that is capable of producing enriched p-H2. The p-H2 thus produced was probed using infrared and Raman techniques. Using infrared measurement, the thickness and the purity of the p-H2 matrix were determined. The purity of p-H2 was determined to be >99%. Matrix isolation infrared spectra of trimethylphosphate (TMP) and acetylene (C2H2) were studied in p-H2 and n-H2 matrices and the results were compared with the conventional inert matrices.
Electrical detection of ortho-para conversion in fullerene-encapsulated water
NASA Astrophysics Data System (ADS)
Meier, Benno; Mamone, Salvatore; Concistrè, Maria; Alonso-Valdesueiro, Javier; Krachmalnicoff, Andrea; Whitby, Richard J.; Levitt, Malcolm H.
2015-08-01
Water exists in two spin isomers, ortho and para, that have different nuclear spin states. In bulk water, rapid proton exchange and hindered molecular rotation obscure the direct observation of two spin isomers. The supramolecular endofullerene H2O@C60 provides freely rotating, isolated water molecules even at cryogenic temperatures. Here we show that the bulk dielectric constant of this substance depends on the ortho/para ratio, and changes slowly in time after a sudden temperature jump, due to nuclear spin conversion. The attribution of the effect to ortho-para conversion is validated by comparison with nuclear magnetic resonance and quantum theory. The change in dielectric constant is consistent with an electric dipole moment of 0.51+/-0.05 Debye for an encapsulated water molecule, indicating the partial shielding of the water dipole by the encapsulating cage. The dependence of bulk dielectric constant on nuclear spin isomer composition appears to be a previously unreported physical phenomenon.
Bonano, J S; Banks, M L; Kolanos, R; Sakloth, F; Barnier, M L; Glennon, R A; Cozzi, N V; Partilla, J S; Baumann, M H; Negus, S S
2015-01-01
Background and Purpose Methcathinone (MCAT) is a potent monoamine releaser and parent compound to emerging drugs of abuse including mephedrone (4-CH3 MCAT), the para-methyl analogue of MCAT. This study examined quantitative structure–activity relationships (QSAR) for MCAT and six para-substituted MCAT analogues on (a) in vitro potency to promote monoamine release via dopamine and serotonin transporters (DAT and SERT, respectively), and (b) in vivo modulation of intracranial self-stimulation (ICSS), a behavioural procedure used to evaluate abuse potential. Neurochemical and behavioural effects were correlated with steric (Es), electronic (σp) and lipophilic (πp) parameters of the para substituents. Experimental Approach For neurochemical studies, drug effects on monoamine release through DAT and SERT were evaluated in rat brain synaptosomes. For behavioural studies, drug effects were tested in male Sprague-Dawley rats implanted with electrodes targeting the medial forebrain bundle and trained to lever-press for electrical brain stimulation. Key Results MCAT and all six para-substituted analogues increased monoamine release via DAT and SERT and dose- and time-dependently modulated ICSS. In vitro selectivity for DAT versus SERT correlated with in vivo efficacy to produce abuse-related ICSS facilitation. In addition, the Es values of the para substituents correlated with both selectivity for DAT versus SERT and magnitude of ICSS facilitation. Conclusions and Implications Selectivity for DAT versus SERT in vitro is a key determinant of abuse-related ICSS facilitation by these MCAT analogues, and steric aspects of the para substituent of the MCAT scaffold (indicated by Es) are key determinants of this selectivity. PMID:25438806
Experiments at Scale with In-Situ Visualization Using ParaView/Catalyst in RAGE
Kares, Robert John
2014-10-31
In this paper I describe some numerical experiments performed using the ParaView/Catalyst in-situ visualization infrastructure deployed in the Los Alamos RAGE radiation-hydrodynamics code to produce images from a running large scale 3D ICF simulation on the Cielo supercomputer at Los Alamos. The detailed procedures for the creation of the visualizations using ParaView/Catalyst are discussed and several images sequences from the ICF simulation problem produced with the in-situ method are presented. My impressions and conclusions concerning the use of the in-situ visualization method in RAGE are discussed.
Simulation Studies of the Vibrational Dynamics of para-HYDROGEN Clusters
NASA Astrophysics Data System (ADS)
Faruk, Nabil F.; Yang, Jing; Le Roy, Robert J.; Roy, Pierre-Nicholas
2011-06-01
This paper discusses the construction and application of reduced-dimensional potential energy surfaces for use in performing simulation of para-hydrogen clusters. Simple spherical averaging and `adiabatic-hindered-rotor' averaging treatments of the angular degrees of freedom are considered and compared. The resulting one-dimensional surface is used in quantum Monte Carlo simulations of para-hydrogen clusters of varying sizes. Energetic, and structural properties are computed and compared to previously published results, and vibrational frequency shifts are predicted and compared to available experimental measurements. H. Li, P.N. Roy and R.J. Le Roy, J. Chem. Phys. 133, 104305 (2010).
Le lipome para testiculaire: à propos d'un cas rare
Lasri, Abdelouahed; Lamchahab, Hamza; Lahyani, Mounir; Karmouni, Tarik; Elkhader, Khalid; Koutani, Abdellatif; Andaloussi, Ahmed Ibn Attya
2015-01-01
Les tumeurs para testiculaires sont des tumeurs rares et complexes qui ont une symptomatologie insidieuse et pauvre. Les formes bénignes représentent 70%. Le lipome para testiculaire étant le type le plus fréquent. L'examen clinique est peu spécifique. L'examen échographique est la pierre angulaire pour assoir le diagnostic. Le traitement chirurgical s'impose en cas de tumeur symptomatique, l'histologie étant habituellement typique permet la confirmation diagnostique. Le pronostic est bon malgré d’éventuelles récidives. PMID:26175802
Quantum rotation of ortho and para-water encapsulated in a fullerene cage
Beduz, Carlo; Carravetta, Marina; Chen, Judy Y.-C.; Concistrè, Maria; Denning, Mark; Frunzi, Michael; Horsewill, Anthony J.; Johannessen, Ole G.; Lawler, Ronald; Lei, Xuegong; Levitt, Malcolm H.; Li, Yongjun; Mamone, Salvatore; Murata, Yasujiro; Nagel, Urmas; Nishida, Tomoko; Ollivier, Jacques; Rols, Stéphane; Rõõm, Toomas; Sarkar, Riddhiman; Turro, Nicholas J.; Yang, Yifeng
2012-01-01
Inelastic neutron scattering, far-infrared spectroscopy, and cryogenic nuclear magnetic resonance are used to investigate the quantized rotation and ortho–para conversion of single water molecules trapped inside closed fullerene cages. The existence of metastable ortho-water molecules is demonstrated, and the interconversion of ortho-and para-water spin isomers is tracked in real time. Our investigation reveals that the ground state of encapsulated ortho water has a lifted degeneracy, associated with symmetry-breaking of the water environment. PMID:22837402
[PDS cord fixation of sternoclavicular dislocation and para-articular clavicular fractures].
Friedl, W; Fritz, T
1994-05-01
Sternoclavicular joint dislocation and para-articular fractures of the clavicle are rare injuries. Because severe complications of dorsal dislocations have often been seen and because functional impairment has often followed ventral dislocations, we treat most patients with such injuries operatively. Internal fixation with K-wires frequently leads to severe complications. We present our operation techniques with a resorbable 2 mm polydioxanon cord. This pack up technique can be used in both dislocations and para-articular fractures with no risk of implant dislocation. PMID:8052863
ERIC Educational Resources Information Center
Marcato, Carla
1997-01-01
Describes and analyzes the language of young people in Italy today. Particular focus is on the expressions using "para" (e.g., "in para totale" = to be very bored or worried) and the phrase "una cosa da panico" (something terrible or its opposite something wonderful). (CFM)
The paper reports results of dynamic and static chamber tests to evaluate para-dichlorobenzene emission rates from mothcakes. he data were analyzed by a model that assumes that the para-dichlorobenzene emission from mothcakes is a temperature-sensitive sublimation process. ull-sc...
Mothcakes made of para-dichlorobenzene have been widely available for the general population to be used as a moth repellant to protect garments from insect damage. Usually, a mothcake is expected to last for weeks or even months during which the para-dichlorobenzene emits slowly ...
Experimental and theoretical investigation of para-aminophenol ionization in corona discharge
NASA Astrophysics Data System (ADS)
Bahrami, H.; Salehabadi, H.
2015-03-01
Ionization of para-aminophenol was investigated using an ion mobility spectrometer equipped with a corona discharge as ionization source. The experimental results were confirmed with the use of theoretical method, based on density functional theory. Two peaks were observed in the ion mobility spectrum in the positive ion mode which was corresponded to the protonated isomers of para-aminophenol. It was observed that the relative intensities of the peaks depend on the sample concentration and the nature of the reactant ions. The relative energies of ions derived from protonation of para-aminophenol and its topical proton affinities were determined for different sites in the gas phase. The peak with the lower drift time was assigned to the oxygen protonated isomer and the other peak was ascribed to the nitrogen protonated isomer of para-aminophenol. The calculated dipole moment and localized charge of each isomer were used to verify the ion mobility peak separation. It was shown that combination of theoretical and experimental tools leads to reliable prediction of reactive protonation sites of chemicals in a corona discharge.
Synthesis and properties of para-substituted NCN-pincer palladium and platinum complexes.
Slagt, Martijn Q; Rodríguez, Gema; Grutters, Michiel M P; Klein Gebbink, Robertus J M; Klopper, Wim; Jenneskens, Leonardus W; Lutz, Martin; Spek, Anthony L; van Koten, Gerard
2004-03-19
A variety of para-substituted NCN-pincer palladium(II) and platinum(II) complexes [MX(NCN-Z)] (M=Pd(II), Pt(II); X=Cl, Br, I; NCN-Z=[2,6-(CH(2)NMe(2))(2)C(6)H(2)-4-Z](-); Z=NO(2), COOH, SO(3)H, PO(OEt)(2), PO(OH)(OEt), PO(OH)(2), CH(2)OH, SMe, NH(2)) were synthesised by routes involving substitution reactions, either prior to or, notably, after metalation of the ligand. The solubility of the pincer complexes is dominated by the nature of the para substituent Z, which renders several complexes water-soluble. The influence of the para substituent on the electronic properties of the metal centre was studied by (195)Pt NMR spectroscopy and DFT calculations. Both the (195)Pt chemical shift and the calculated natural population charge on platinum correlate linearly with the sigma(p) Hammett substituent constants, and thus the electronic properties of predesigned pincer complexes can be predicted. The sigma(p) value for the para-PtI group itself was determined to be -1.18 in methanol and -0.72 in water/methanol (1/1). Complexes substituted with protic functional groups (CH(2)OH, COOH) exist as dimers in the solid state due to intermolecular hydrogen-bonding interactions. PMID:15034878
Cáncer de páncreas—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de páncreas, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
Cáncer de vagina—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de vagina, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
An Analysis of Interlanguage Development Over Time: Part 1, "por" and "para".
ERIC Educational Resources Information Center
Guntermann, Gail
1992-01-01
The first part of a larger planned investigation, this study examines the use of "por" and "para" by nine Peace Corps volunteers in oral interviews at the end of training and roughly one year later, to trace their acquisition over time, in two learning contexts. (24 references) (LB)
ERIC Educational Resources Information Center
Lafford, Barbara A.; Ryan, John M.
1995-01-01
Examination of the development of form/function relations of the prepositions "por" and "para" at different levels of proficiency in the interlanguage of study-abroad students in Granada, Spain, revealed "noncanonical" as well as "canonical" uses of these prepositions. The most common noncanonical uses were as substitutions for other prepositions…
Preguntas para hacerle al doctor acerca del cáncer
Serie de preguntas, organizadas por tema, que los pacientes con cáncer pueden hacer al médico o a otros miembros de su equipo de atención médica para conocer más acerca de su tipo de cáncer y lo que pueden esperar.
Terapia hormonal para la menopausia y el cáncer
Hoja informativa acerca de los resultados de los estudios sobre el uso de la terapia hormonal para la menopausia. Incluye información sobre el efecto de esta terapia en el cuerpo y explica los riesgos y beneficios del uso de hormonas.
Resultados de estudio para cáncer de pulmón indica
El Instituto Nacional del Cáncer (NCI) da a conocer hoy resultados iniciales de un estudio de gran envergadura sobre métodos de detección para reducir el número de muertes por cáncer de pulmón al detectar cánceres en estadios relativamente iniciales.
Factor Structure of the "Escala de Autoeficacia para la Depresion en Adolescentes" (EADA)
ERIC Educational Resources Information Center
Diaz-Santos, Mirella; Cumba-Aviles, Eduardo; Bernal, Guillermo; Rivera-Medina, Carmen
2011-01-01
The current concept and measures of self-efficacy for depression in adolescents do not consider developmental and cultural aspects essential to understand and assess this construct in Latino youth. We examined the factor structure of the "Escala de Autoeficacia para la Depresion en Adolescentes" (EADA), a Spanish instrument designed to assess this…
Sarcoma de tejido blando—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del sarcoma de tejido blando, así como referencias a estudios clínicos, investigación, estadísticas y otros temas relacionados con este tipo de cáncer.
Cannabis y canabinoides (PDQ®)—Versión para profesionales de salud
Resumen de información revisada por expertos sobre el uso del Cannabis y canabinoides para el tratamiento de los efectos secundarios relacionados con el tratamiento del cáncer, como la náusea y el vómito.
Cannabis y canabinoides (PDQ®)—Versión para pacientes
Resumen de información revisada por expertos sobre el uso del Cannabis y canabinoides para el tratamiento de los efectos secundarios relacionados con el tratamiento del cáncer como la náusea y el vómito.
Cáncer de intestino delgado—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de intestino delgado, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
ERIC Educational Resources Information Center
Paolantonio, Mario Di
2011-01-01
Recently, a few buildings within the "Espacio para la memoria" in Buenos Aires have been designated as a UNESCO Centre where, amongst other educational activities, evidentiary materials of the past repression are to be stored and displayed. Another building in the complex houses a Community Centre operated by the Mothers of the Plaza de Mayo,…
Cáncer colorrectal—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento, la prevención, las causas y los exámenes de detección del cáncer de colon y recto, así como referencias a estudios clínicos, estadísticas y otros temas.
Estudios ALCHEMIST para el cáncer de pulmón en estadio inicial
ALCHEMIST comprende tres estudios clínicos integrados de medicina de precisión diseñados para identificar a personas con cáncer de pulmón en estadio inicial cuyos tumores tienen ciertos cambios genéticos poco comunes.
Can para-aryl-dithiols cross-link two plasmonic noble nanoparticles as monolayer dithiolate spacers
Technology Transfer Automated Retrieval System (TEKTRAN)
Para-aryl-dithiols (PADTs, HS-(C6H4)n-SH, n = 1, 2, and 3) have been used extensively in molecular electronics, surface-enhanced Raman spectroscopy (SERS), and quantum electron tunneling between two gold or silver nanoparticles (AuNPs and AgNPs). One popular belief is that these dithiols cross-link ...
Cáncer de la corteza suprarrenal—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del carcinoma de corteza suprarrenal, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
Tumores de hipófisis—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del tumor de hipófisis, así como referencias a estudios clínicos, investigación y otros temas relacionados.
Cáncer de útero—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento, la prevención, las causas y los exámenes de detección del cáncer uterino, así como referencias a estudios clínicos, investigación, estadísticas y otros temas.
Tumores extracraneales de células germinativas—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del tumor extracraneal de células germinativas en los niños, así como referencias a estudios clínicos y otros temas relacionados.
Cáncer de ano—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de ano, así como referencias a estudios clínicos y otros temas relacionados con este tipo de cáncer.
Cáncer de tiroides—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de tiroides, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
Cáncer de pene—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de pene, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
Cáncer de testículo—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento, las causas y los exámenes de detección del cáncer de testículo, así como referencias a estudios clínicos, investigación y otros temas.
Cáncer de vejiga—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento, las causas y los exámenes de detección del cáncer de vejiga, así como referencias a estudios clínicos, investigación, estadísticas y otros temas.
Cáncer de vulva—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de vulva, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
Cáncer de paratiroides—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de paratiroides, así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
Cáncer de uretra—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de uretra, así como referencias a estudios clínicos y otros temas relacionados con este tipo de cáncer.
Malík, Ivan; Bukovský, Marián; Andriamainty, Fils; Gališinová, Jana
2013-01-01
In current research, nine basic esters of para-alkoxyphenylcarbamic acid with incorporated 4-(4-fluoro-/3-trifluoromethylphenyl)piperazin-1-yl fragment, 6i–6m and 8f–8i, were screened for their in vitro antimicrobial activity against Candida albicans, Staphylococcus aureus and Escherichia coli, respectively. Taking into account the minimum inhibitory concentration assay (MIC), as the most active against given yeast was evaluated 8i (MIC = 0.20 mg/mL), the most lipophilic structure containing para-butoxy and trifluoromethyl substituents. Investigating the efficiency of the compounds bearing only a single atom of fluorine and appropriate para-alkoxy side chain against Candida albicans, the cut-off effect was observed. From evaluated homological series, the maximum of the effectiveness was noticed for the stucture 6 k (MIC = 0.39 mg/mL), containing para-propoxy group attached to phenylcarbamoyloxy fragment, beyond which the compounds ceased to be active. On the contrary, all the tested molecules were against Staphylococcus aureus and Escherichia coli (MICs > 1.00 mg/mL) practically inactive. PMID:24294237
Delirio (PDQ®)—Versión para profesionales de salud
Resumen de información revisada por expertos acerca del delirio como una complicación a causa del cáncer o su tratamiento. Se discuten los enfoques de los cuidados médicos de apoyo, asi como farmacológicos para el manejo del delirio.
Irradiation of para-aortic lymph node metastases from carcinoma of the cervix or endometrium
Komaki, R.; Mattingly, R.F.; Hoffman, R.G.; Barber, S.W.; Satre, R.; Greenberg, M.
1983-04-01
Twenty-two patients with biopsy-proved para-aortic lymph node metastases from carcinoma of the cervix (15 patients) or endometrium (7 patients) received a median dose of 5,000 rad/25 fractions. Para-aortic nodal metastases were controlled in 77% of cases. Control was significantly lower following radical retroperitoneal lymph node dissection than less extensive sampling procedures. Obstruction of the small bowel developed in 3 patients with tumor recurrence in the para-aortic region. Eight of the 10 patients who were disease-free at 2 years received >5,000 rad. Three patients were still alive without disease at 129, 63, and 60 months, respectively. The 5-year disease-free survival rate was 40% for cervical cancer and 60% for endometrial cancer: in the former group, it was significantly different depending on whether the para-aortic nodes were irradiated (40%) or not (0%). The authors suggest that 5,000-5,500 rad in 5-5.5 weeks is well tolerated and can control aortic nodal metastases in cervical and possibly endometrial cancer.
Malík, Ivan; Bukovský, Marián; Andriamainty, Fils; Gališinová, Jana
2013-01-01
In current research, nine basic esters of para-alkoxyphenylcarbamic acid with incorporated 4-(4-fluoro-/3-trifluoromethylphenyl)piperazin-1-yl fragment, 6i-6m and 8f-8i, were screened for their in vitro antimicrobial activity against Candida albicans, Staphylococcus aureus and Escherichia coli, respectively. Taking into account the minimum inhibitory concentration assay (MIC), as the most active against given yeast was evaluated 8i (MIC = 0.20 mg/mL), the most lipophilic structure containing para-butoxy and trifluoromethyl substituents. Investigating the efficiency of the compounds bearing only a single atom of fluorine and appropriate para-alkoxy side chain against Candida albicans, the cut-off effect was observed. From evaluated homological series, the maximum of the effectiveness was noticed for the stucture 6 k (MIC = 0.39 mg/mL), containing para-propoxy group attached to phenylcarbamoyloxy fragment, beyond which the compounds ceased to be active. On the contrary, all the tested molecules were against Staphylococcus aureus and Escherichia coli (MICs > 1.00 mg/mL) practically inactive. PMID:24294237
Up from Apathy: Para-Professional Training for the Socially Disadvantaged
ERIC Educational Resources Information Center
Jones, Mark J.; Wright, Bobbye S.
1970-01-01
Describes a program of training for young men to fill a para-professional position in the growing field of social services. The program provides training in human relations, basic skills, and on-the-job techniques. Training Technology is a quarterly supplement to Educational Technology Magazine. (GR)
Ortho-para conversion of endohedral water in the fullerene C60 at cryogenic temperatures
NASA Astrophysics Data System (ADS)
Shugai, Anna; Nagel, U.; Rõõm, T.; Mamone, S.; Concistrè, M.; Meier, B.; Krachmalnicoff, A.; Whitby, R. J.; Levitt, M. H.; Lei, Xuegong; Li, Yongjun; Turro, N. J.
2015-03-01
Water displays the phenomenon of spin isomerism in which the two proton spins either couple to form a triplet (ortho water, I = 1) or a singlet nuclear spin state (para water, I = 0). Here we study the interconversion of para and ortho water. The exact mechanism of this process is still not fully understood. In order to minimize interactions between molecules we use a sample where a single H2O is trapped in the C60 molecular cage (H2O@C60)andH2O@C60iscrystallized.H2O@C60 has long-lived ortho state and ortho-para conversion kinetics is non-exponential at LHeT. We studied mixtures of H2O@C60, D2O@C60 and C60 using IR absorption, NMR and dielectric measurements. We saw the speeding up of the interconversion with the growth of H2O@C60 concentration in C60 or when D2O@C60 was added. At some temperatures the kinetics is exponential. Models are discussed in order to explain the T and concentration dependence of ortho-para interconversion kinetics. This work was supported by institutional research funding IUT23-3 of the Estonian Ministry of Education and Research.
Xu, Ren-Qi; Gu, Qing; Wu, Wen-Ting; Zhao, Zhuo-An; You, Shu-Li
2014-11-01
A novel Pd(0)-catalyzed intramolecular arylative dearomatization of para-aminophenol derivatives is described. In the presence of 1.25 mol % [Pd(C3H5)Cl]2 and 3.75 mol % RuPhos, the arylative dearomatization reaction proceeds smoothly for a broad range of substrates, offering an efficient synthetic route to erythrinane derivatives in excellent yields. PMID:25308898
Fabrication of multipotent poly-para-xylylene particles in controlled nanoscopic dimensions.
Yuan, Ruei-Hung; Li, Yi-Jye; Sun, Ho-Yi; Wu, Chih-Yu; Guan, Zhen-Yu; Ho, Hsin-Ying; Fang, Cheng-Yuan; Chen, Hsien-Yeh
2016-03-01
In this study, poly-para-xylylene-based multifunctional nanoparticles (PPX-NPs) were fabricated. Based on the solubility characteristics determined for asymmetrically substituted poly-para-xylylenes in polar solvents, well-dispersed nanocolloids with a controllable size ranging from 50 to 800nm were produced in solution by the displacement of the solvent (water). These size ranges were found to have acceptable cellular compatibility through examinations of cultured 3T3 fibroblasts and adipose-derived stem cells treated with the PPX-NPs. In addition, these nanoscale PPX-NPs exhibited versatile bioconjugation properties in that a variety of available functional groups can be adopted from their counterpart, thin-film poly-para-xylylenes, during the production of these nanoparticles. For instance, bifunctional PPX-NPs with maleimide and benzoyl moieties were produced to enable immobilization via a maleimide-thiol reaction concurrent with a photochemical reaction. A cleavable PPX-NP was also produced with a thiol-exchangeable surface property. Additionally, by performing electrohydrodynamic jetting of parallel polymer solutions of selected poly-para-xylylenes, Janus-type or multicompartment PPX-NPs were created. The PPX-NPs can potentially be used for various biomedical applications such as combined diagnostics and drug delivery, multiplexing of detection, multiple-drug loading, and the targeted delivery of biomolecules or drugs. PMID:26724467
Energia Renovable para Centros de Salud Rurales (Renewable Energy for Rural Health Clinics)
Jimenez, T.; Olson, K.
1999-07-28
Esta es la primera de una serie de guias de aplicaciones que el Programa de Energia de Villas de NREL esta comisionando para acoplar sistemas comerciales renovables con aplicaciones rurales, incluyendo agua, escuelas rurales y micro empresas. La guia esta complementada por las actividades de desarrollo del Programa de Energia de Villas de NREL, proyectos pilotos internacionales y programas de visitas profesionales.
Autoguía para el telescopio 2,15 mts de CASLEO
NASA Astrophysics Data System (ADS)
Aballay, J. A.; Casagrande, A. R.; Pereyra, P. F.; Marún, A. H.
Se está desarrollando un sistema de autoguía para el telescopio de 2,15 mts. El mismo se realizará aprovechando el Offset Guider. Al ocular móvil de éste se vinculará alguna cámara digital (ST4-ST7-CH250) para lograr la visión del objeto. El funcionamiento del equipo será el siguiente: primero, dadas las coordenadas del objeto a observar, se tomarán las coordenadas del telescopio para que, a través de una base de datos, se determine un campo de objetos que sirvan para la cámara de visión, luego, la PC obtendrá el offset entre la estrella de observación y la estrella seleccionada como guía, este valor será trasladado a los motores que posicionarán en forma automática el ocular. Una vez que la estrella es visualizada en la cámara (monitor de PC ) se correrá el programa que guiará el telescopio automáticamente.
Fatiga (PDQ®)—Versión para profesionales de salud
Resumen de información revisada por expertos acerca de la fatiga, una afección caracterizada por extremo cansancio e incapacidad para funcionar por la falta de energía, que a menudo se observa como una complicación del cáncer y su tratamiento.
Cáncer de hueso—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento del cáncer de hueso (óseo), así como referencias a estudios clínicos, investigación y otros temas relacionados con este tipo de cáncer.
Vínculos observacionais para o processo-S em estrelas gigantes de Bário
NASA Astrophysics Data System (ADS)
Smiljanic, R. H. S.; Porto de Mello, G. F.; da Silva, L.
2003-08-01
Estrelas de bário são gigantes vermelhas de tipo GK que apresentam excessos atmosféricos dos elementos do processo-s. Tais excessos são esperados em estrelas na fase de pulsos térmicos do AGB (TP-AGB). As estrelas de bário são, no entanto, menos massivas e menos luminosas que as estrelas do AGB, assim, não poderiam ter se auto-enriquecido. Seu enriquecimento teria origem em uma estrela companheira, inicialmente mais massiva, que evolui pelo TP-AGB, se auto-enriquece com os elementos do processo-s e transfere material contaminado para a atmosfera da atual estrela de bário. A companheira evolui então para anã branca deixando de ser observada diretamente. As estrelas de bário são, portanto, úteis como testes observacionais para teorias de nucleossíntese pelo processo-s, convecção e perda de massa. Análises detalhadas de abundância com dados de alta qualidade para estes objetos são ainda escassas na literatura. Neste trabalho construímos modelos de atmosferas e, procedendo a uma análise diferencial, determinamos parâmetros atmosféricos e evolutivos de uma amostra de dez gigantes de bário e quatro normais. Determinamos seus padrões de abundância para Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sr, Y, Zr, Ba, La, Ce, Nd, Sm, Eu e Gd, concluindo que algumas estrelas classificadas na literatura como gigantes de bário são na verdade gigantes normais. Comparamos dois padrões médios de abundância, para estrelas com grandes excessos e estrelas com excessos moderados, com modelos teóricos de enriquecimento pelo processo-s. Os dois grupos de estrelas são ajustados pelos mesmos parâmetros de exposição de nêutrons. Tal resultado sugere que a ocorrência do fenômeno de bário com diferentes intensidades não se deve a diferentes exposições de nêutrons. Discutimos ainda efeitos nucleossintéticos, ligados ao processo-s, sugeridos na literatura para os elementos Cu, Mn, V e Sc.
Hox and ParaHox gene expression in early body plan patterning of polyplacophoran mollusks
Fritsch, Martin; Wollesen, Tim
2016-01-01
ABSTRACT Molecular developmental studies of various bilaterians have shown that the identity of the anteroposterior body axis is controlled by Hox and ParaHox genes. Detailed Hox and ParaHox gene expression data are available for conchiferan mollusks, such as gastropods (snails and slugs) and cephalopods (squids and octopuses), whereas information on the putative conchiferan sister group, Aculifera, is still scarce (but see Fritsch et al., 2015 on Hox gene expression in the polyplacophoran Acanthochitona crinita). In contrast to gastropods and cephalopods, the Hox genes in polyplacophorans are expressed in an anteroposterior sequence similar to the condition in annelids and other bilaterians. Here, we present the expression patterns of the Hox genes Lox5, Lox4, and Lox2, together with the ParaHox gene caudal (Cdx) in the polyplacophoran A. crinita. To localize Hox and ParaHox gene transcription products, we also investigated the expression patterns of the genes FMRF and Elav, and the development of the nervous system. Similar to the other Hox genes, all three Acr‐Lox genes are expressed in an anteroposterior sequence. Transcripts of Acr‐Cdx are seemingly present in the forming hindgut at the posterior end. The expression patterns of both the central class Acr‐Lox genes and the Acr‐Cdx gene are strikingly similar to those in annelids and nemerteans. In Polyplacophora, the expression patterns of the Hox and ParaHox genes seem to be evolutionarily highly conserved, while in conchiferan mollusks these genes are co‐opted into novel functions that might have led to evolutionary novelties, at least in gastropods and cephalopods. PMID:27098677
Rotational excitation of HCN by para- and ortho-H{sub 2}
Vera, Mario Hernández; Kalugina, Yulia; Denis-Alpizar, Otoniel; Stoecklin, Thierry; Lique, François
2014-06-14
Rotational excitation of the hydrogen cyanide (HCN) molecule by collisions with para-H{sub 2}( j = 0, 2) and ortho-H{sub 2}( j = 1) is investigated at low temperatures using a quantum time independent approach. Both molecules are treated as rigid rotors. The scattering calculations are based on a highly correlated ab initio 4-dimensional (4D) potential energy surface recently published. Rotationally inelastic cross sections among the 13 first rotational levels of HCN were obtained using a pure quantum close coupling approach for total energies up to 1200 cm{sup −1}. The corresponding thermal rate coefficients were computed for temperatures ranging from 5 to 100 K. The HCN rate coefficients are strongly dependent on the rotational level of the H{sub 2} molecule. In particular, the rate coefficients for collisions with para-H{sub 2}( j = 0) are significantly lower than those for collisions with ortho-H{sub 2}( j = 1) and para-H{sub 2}( j = 2). Propensity rules in favor of even Δj transitions were found for HCN in collisions with para-H{sub 2}( j = 0) whereas propensity rules in favor of odd Δj transitions were found for HCN in collisions with H{sub 2}( j ⩾ 1). The new rate coefficients were compared with previously published HCN-para-H{sub 2}( j = 0) rate coefficients. Significant differences were found due the inclusion of the H{sub 2} rotational structure in the scattering calculations. These new rate coefficients will be crucial to improve the estimation of the HCN abundance in the interstellar medium.
Hox and ParaHox gene expression in early body plan patterning of polyplacophoran mollusks.
Fritsch, Martin; Wollesen, Tim; Wanninger, Andreas
2016-03-01
Molecular developmental studies of various bilaterians have shown that the identity of the anteroposterior body axis is controlled by Hox and ParaHox genes. Detailed Hox and ParaHox gene expression data are available for conchiferan mollusks, such as gastropods (snails and slugs) and cephalopods (squids and octopuses), whereas information on the putative conchiferan sister group, Aculifera, is still scarce (but see Fritsch et al., 2015 on Hox gene expression in the polyplacophoran Acanthochitona crinita). In contrast to gastropods and cephalopods, the Hox genes in polyplacophorans are expressed in an anteroposterior sequence similar to the condition in annelids and other bilaterians. Here, we present the expression patterns of the Hox genes Lox5, Lox4, and Lox2, together with the ParaHox gene caudal (Cdx) in the polyplacophoran A. crinita. To localize Hox and ParaHox gene transcription products, we also investigated the expression patterns of the genes FMRF and Elav, and the development of the nervous system. Similar to the other Hox genes, all three Acr-Lox genes are expressed in an anteroposterior sequence. Transcripts of Acr-Cdx are seemingly present in the forming hindgut at the posterior end. The expression patterns of both the central class Acr-Lox genes and the Acr-Cdx gene are strikingly similar to those in annelids and nemerteans. In Polyplacophora, the expression patterns of the Hox and ParaHox genes seem to be evolutionarily highly conserved, while in conchiferan mollusks these genes are co-opted into novel functions that might have led to evolutionary novelties, at least in gastropods and cephalopods. PMID:27098677
Ancient origins of axial patterning genes: Hox genes and ParaHox genes in the Cnidaria.
Finnerty, J R; Martindale, M Q
1999-01-01
Among the bilaterally symmetrical, triploblastic animals (the Bilateria), a conserved set of developmental regulatory genes are known to function in patterning the anterior-posterior (AP) axis. This set includes the well-studied Hox cluster genes, and the recently described genes of the ParaHox cluster, which is believed to be the evolutionary sister of the Hox cluster (Brooke et al. 1998). The conserved role of these axial patterning genes in animals as diverse as frogs and flies is believed to reflect an underlying homology (i.e., all bilaterians derive from a common ancestor which possessed an AP axis and the developmental mechanisms responsible for patterning the axis). However, the origin and early evolution of Hox genes and ParaHox genes remain obscure. Repeated attempts have been made to reconstruct the early evolution of Hox genes by analyzing data from the triphoblastic animals, the Bilateria (Schubert et al. 1993; Zhang and Nei 1996). A more precise dating of Hox origins has been elusive due to a lack of sufficient information from outgroup taxa such as the phylum Cnidaria (corals, hydras, jellyfishes, and sea anemones). In combination with outgroup taxa, another potential source of information about Hox origins is outgroup genes (e.g., the genes of the ParaHox cluster). In this article, we present cDNA sequences of two Hox-like genes (anthox2 and anthox6) from the sea anemone, Nematostella vectensis. Phylogenetic analysis indicates that anthox2 (= Cnox2) is homologous to the GSX class of ParaHox genes, and anthox6 is homologous to the anterior class of Hox genes. Therefore, the origin of Hox genes and ParaHox genes occurred prior to the evolutionary split between the Cnidaria and the Bilateria and predated the evolution of the anterior-posterior axis of bilaterian animals. Our analysis also suggests that the central Hox class was invented in the bilaterian lineage, subsequent to their split from the Cnidaria. PMID:11324016
NASA Astrophysics Data System (ADS)
Fletcher, Leigh N.; Irwin, Patrick G.; Sinclair, James; Giles, Rohini; Barstow, Joanna; Achterberg, Richard K.; Orton, Glenn S.
2014-11-01
Cassini/CIRS observations of Saturn’s 10-1400 cm-1 spectrum have been inverted to construct a global record of tropospheric temperature and para-hydrogen variability over the ten-year span of the Cassini mission. The data record the slow reversal of seasonal asymmetries in tropospheric conditions from northern winter (2004, Ls=293), through northern spring equinox (2009, Ls=0) to the present day (2014, Ls=60). Mid-latitude tropospheric temperatures have cooled by approximately 4-6 K in the south and warmed by 2-4 K in the north, with the seasonal contrast decreasing with depth. CIRS detected the north polar minimum 100-mbar temperatures 6-8 years after winter solstice, whereas the south polar maximum occurred 1-2 years after summer solstice, consistent with the lag times predicted by radiative equilibrium models. Warm polar cyclones and the northern hexagon persist throughout the mission, suggesting that they are permanent features of Saturn’s tropospheric circulation. The 200-mbar thermal enhancement (“knee”) that was strongest in the summer but weak or absent in winter in 2004-2006 (Fletcher et al., 2007, Icarus 189, p.457-478) has now shifted northward and is present globally in 2014, suggestive of radiative heating in Saturn’s tropospheric haze layer. Saturn’s para-H2 fraction, which serves as a tracer of both tropospheric mixing and the efficiency of re-equilibration between the ortho- and para-hydrogen states, is slowly altering: super-equilibrium conditions (para-H2 fraction exceeding equilibrium expectations and suggestive of subsiding airmasses) that dominated the southern summer hemisphere are now weakening, whereas the sub-equilibrium conditions (suggestive of uplift) of the northern winter are being replaced by equilibrium or super-equilibrium conditions in spring. The thermal ‘knee’ and the para-H2 distribution are tracking both the increased spring illumination and the increasing tropospheric haze opacity of the springtime hemisphere
Takiar, Vinita; Fontanilla, Hiral P.; Eifel, Patricia J.; Jhingran, Anuja; Kelly, Patrick; Iyer, Revathy B.; Levenback, Charles F.; Zhang, Yongbin; Dong, Lei; Klopp, Ann
2013-03-15
Purpose: Conformal treatment of para-aortic lymph nodes (PAN) in cervical cancer allows dose escalation and reduces normal tissue toxicity. Currently, data documenting the precise location of involved PAN are lacking. We define the spatial distribution of this high-risk nodal volume by analyzing fluorodeoxyglucose (FDG)-avid lymph nodes (LNs) on positron emission tomography/computed tomography (PET/CT) scans in patients with cervical cancer. Methods and Materials: We identified 72 PANs on pretreatment PET/CT of 30 patients with newly diagnosed stage IB-IVA cervical cancer treated with definitive chemoradiation. LNs were classified as left-lateral para-aortic (LPA), aortocaval (AC), or right paracaval (RPC). Distances from the LN center to the closest vessel and adjacent vertebral body were calculated. Using deformable image registration, nodes were mapped to a template computed tomogram to provide a visual impression of nodal frequencies and anatomic distribution. Results: We identified 72 PET-positive para-aortic lymph nodes (37 LPA, 32 AC, 3 RPC). All RPC lymph nodes were in the inferior third of the para-aortic region. The mean distance from aorta for all lymph nodes was 8.3 mm (range, 3-17 mm), and from the inferior vena cava was 5.6 mm (range, 2-10 mm). Of the 72 lymph nodes, 60% were in the inferior third, 36% were in the middle third, and 4% were in the upper third of the para-aortic region. In all, 29 of 30 patients also had FDG-avid pelvic lymph nodes. Conclusions: A total of 96% of PET positive nodes were adjacent to the aorta; PET positive nodes to the right of the IVC were rare and were all located distally, within 3 cm of the aortic bifurcation. Our findings suggest that circumferential margins around the vessels do not accurately define the nodal region at risk. Instead, the anatomical extent of the nodal basin should be contoured on each axial image to provide optimal coverage of the para-aortic nodal compartment.
Astronomia para/com crianças carentes em Limeira
NASA Astrophysics Data System (ADS)
Bretones, P. S.; Oliveira, V. C.
2003-08-01
Em 2001, o Instituto Superior de Ciências Aplicadas (ISCA Faculdades de Limeira) iniciou um projeto pelo qual o Observatório do Morro Azul empreendeu uma parceria com o Centro de Promoção Social Municipal (CEPROSOM), instituição mantida pela Prefeitura Municipal de Limeira para atender crianças e adolescentes carentes. O CEPROSOM contava com dois projetos: Projeto Centro de Convivência Infantil (CCI) e Programa Criança e Adolescente (PCA), que atendiam crianças e adolescentes em Centros Comunitários de diversas áreas da cidade. Esses projetos têm como prioridades estabelecer atividades prazerosas para as crianças no sentido de retirá-las das ruas. Assim sendo, as crianças passaram a ter mais um tipo de atividade - as visitas ao observatório. Este painel descreve as várias fases do projeto, que envolveu: reuniões de planejamento, curso de Astronomia para as orientadoras dos CCIs e PCAs, atividades relacionadas a visitas das crianças ao Observatório, proposta de construção de gnômons e relógios de Sol nos diversos Centros Comunitários de Limeira e divulgação do projeto na imprensa. O painel inclui discussões sobre a aprendizagem de crianças carentes, relatos que mostram a postura das orientadoras sobre a pertinência do ensino de Astronomia, relatos do monitor que fez o atendimento no Observatório e o que o número de crianças atendidas representou para as atividades da instituição desde o início de suas atividades e, em particular, em 2001. Os resultados são baseados na análise de relatos das orientadoras e do monitor do Observatório, registros de visitas e matérias da imprensa local. Conclui com uma avaliação do que tal projeto representou para as Instituições participantes. Para o Observatório, em particular, foi feita uma análise com relação às outras modalidades de atendimentos que envolvem alunos de escolas e público em geral. Também é abordada a questão do compromisso social do Observatório na educação do
Osborne, Peter W; Benoit, Gérard; Laudet, Vincent; Schubert, Michael; Ferrier, David E K
2009-03-01
The ParaHox cluster is the evolutionary sister to the Hox cluster. Like the Hox cluster, the ParaHox cluster displays spatial and temporal regulation of the component genes along the anterior/posterior axis in a manner that correlates with the gene positions within the cluster (a feature called collinearity). The ParaHox cluster is however a simpler system to study because it is composed of only three genes. We provide a detailed analysis of the amphioxus ParaHox cluster and, for the first time in a single species, examine the regulation of the cluster in response to a single developmental signalling molecule, retinoic acid (RA). Embryos treated with either RA or RA antagonist display altered ParaHox gene expression: AmphiGsx expression shifts in the neural tube, and the endodermal boundary between AmphiXlox and AmphiCdx shifts its anterior/posterior position. We identified several putative retinoic acid response elements and in vitro assays suggest some may participate in RA regulation of the ParaHox genes. By comparison to vertebrate ParaHox gene regulation we explore the evolutionary implications. This work highlights how insights into the regulation and evolution of more complex vertebrate arrangements can be obtained through studies of a simpler, unduplicated amphioxus gene cluster. PMID:19103191
Donczew, Magdalena; Mackiewicz, Paweł; Wróbel, Agnieszka; Flärdh, Klas; Zakrzewska-Czerwińska, Jolanta; Jakimowicz, Dagmara
2016-04-01
In unicellular bacteria, the ParA and ParB proteins segregate chromosomes and coordinate this process with cell division and chromosome replication. During sporulation of mycelial Streptomyces, ParA and ParB uniformly distribute multiple chromosomes along the filamentous sporogenic hyphal compartment, which then differentiates into a chain of unigenomic spores. However, chromosome segregation must be coordinated with cell elongation and multiple divisions. Here, we addressed the question of whether ParA and ParB are involved in the synchronization of cell-cycle processes during sporulation in Streptomyces To answer this question, we used time-lapse microscopy, which allows the monitoring of growth and division of single sporogenic hyphae. We showed that sporogenic hyphae stop extending at the time of ParA accumulation and Z-ring formation. We demonstrated that both ParA and ParB affect the rate of hyphal extension. Additionally, we showed that ParA promotes the formation of massive nucleoprotein complexes by ParB. We also showed that FtsZ ring assembly is affected by the ParB protein and/or unsegregated DNA. Our results indicate the existence of a checkpoint between the extension and septation of sporogenic hyphae that involves the ParA and ParB proteins. PMID:27248800
Donczew, Magdalena; Mackiewicz, Paweł; Wróbel, Agnieszka; Flärdh, Klas; Zakrzewska-Czerwińska, Jolanta
2016-01-01
In unicellular bacteria, the ParA and ParB proteins segregate chromosomes and coordinate this process with cell division and chromosome replication. During sporulation of mycelial Streptomyces, ParA and ParB uniformly distribute multiple chromosomes along the filamentous sporogenic hyphal compartment, which then differentiates into a chain of unigenomic spores. However, chromosome segregation must be coordinated with cell elongation and multiple divisions. Here, we addressed the question of whether ParA and ParB are involved in the synchronization of cell-cycle processes during sporulation in Streptomyces. To answer this question, we used time-lapse microscopy, which allows the monitoring of growth and division of single sporogenic hyphae. We showed that sporogenic hyphae stop extending at the time of ParA accumulation and Z-ring formation. We demonstrated that both ParA and ParB affect the rate of hyphal extension. Additionally, we showed that ParA promotes the formation of massive nucleoprotein complexes by ParB. We also showed that FtsZ ring assembly is affected by the ParB protein and/or unsegregated DNA. Our results indicate the existence of a checkpoint between the extension and septation of sporogenic hyphae that involves the ParA and ParB proteins. PMID:27248800
Pair creation rates for one-dimensional fermionic and bosonic vacua
Cheng, T.; Ware, M. R.; Su, Q.; Grobe, R.
2009-12-15
We compare the creation rates for particle-antiparticle pairs produced by a supercritical force field for fermionic and bosonic model systems. The rates obtained from the Dirac and Klein-Gordon equations can be computed directly from the quantum-mechanical transmission coefficients describing the scattering of an incoming particle with the supercritical potential barrier. We provide a unified framework that shows that the bosonic rates can exceed the fermionic ones, as one could expect from the Pauli-exclusion principle for the fermion system. This imbalance for small but supercritical forces is associated with the occurrence of negative bosonic transmission coefficients of arbitrary size for the Klein-Gordon system, while the Dirac coefficient is positive and bound by unity. We confirm the transmission coefficients with time-dependent scattering simulations. For large forces, however, the fermionic and bosonic pair-creation rates are surprisingly close to each other. The predicted pair creation rates also match the slopes of the time-dependent particle probabilities obtained from large-scale ab initio numerical simulations based on quantum field theory.
Slow magnetohydrodynamic waves in stratified and viscous plasmas
Ballai, Istvan; Erdelyi, Robert; Hargreaves, James
2006-04-15
The propagation of slow magnetohydrodynamic waves in vertical thin flux tubes embedded in a vertically stratified plasma in the presence of viscosity is shown here to be governed by the Klein-Gordon-Burgers (KGB) equation, which is solved in two limiting cases assuming an isothermal medium in hydrostatic equilibrium surrounded by a quiescent environment. The results presented here can be applied to, e.g., study the propagation of slow magnetohydrodynamic waves generated by the granular buffeting motion in thin magnetic photospheric tubes. When the variation in the reduced velocity occurs over typical lengths much larger than the gravitational scale height, the KGB equation can be reduced to a Klein-Gordon equation describing the propagation of an impulse followed by a wake oscillating with the frequency reduced by viscosity and the solution has no spatial or temporal decay. However, in the other limiting case, i.e., typical variations in the reduced velocity occur over characteristic lengths much smaller than the gravitational scale height, waves have a temporal and spatial decay.
Quantum classical transition in scale relativity
NASA Astrophysics Data System (ADS)
Célérier, Marie-Noëlle; Nottale, Laurent
2004-01-01
The theory of scale relativity provides a new insight into the origin of fundamental laws in physics. Its application to microphysics allows us to recover quantum mechanics as mechanics on a non-differentiable (fractal) spacetime. The Schrödinger and Klein-Gordon equations are demonstrated as geodesic equations in this framework. A development of the intrinsic properties of this theory, using the mathematical tool of Hamilton's bi-quaternions, leads us to a derivation of the Dirac equation within the scale-relativity paradigm. The complex form of the wavefunction in the Schrödinger and Klein-Gordon equations follows from the non-differentiability of the geometry, since it involves a breaking of the invariance under the reflection symmetry on the (proper) time differential element (ds harr -ds). This mechanism is generalized for obtaining the bi-quaternionic nature of the Dirac spinor by adding a further symmetry breaking due to non-differentiability, namely the differential coordinate reflection symmetry (dxmgr harr -dxmgr) and by requiring invariance under the parity and time inversion. The Pauli equation is recovered as a non-motion-relativistic approximation of the Dirac equation.
On Energy and Momentum in Contemporary Physics
NASA Astrophysics Data System (ADS)
Sujak, Peter
2014-03-01
This paper analyzes the quantities of energy and momentum in the definitional relationship of classical mechanics and relativistic mechanics, in the de Broglie momentum hypothesis and in the Klein-Gordon, Dirac and Schrodinger equation. The results of analysis shows that λ designated in the de Broglie hypothesis λ = h / mv as the wave of matter with rest state value λ = ∞ must be connected with a real dimension of a particle with rest state value λ =lo = h /mo c and that on this basis we can come to the fundamental equations of quantum mechanics that are the Klein-Gordon, Dirac and Schrodinger equation without the necessity of the wave functions. Energies in relativistic mechanics as mc2 , mvc , and moc2 , and energy of a photon hν do not represent quantities of energies, but quantity of momentums intentionally multiplied by c, so mc . c , mv . c , mo c . c , hν / c . c and merely the dimension of such quantities equals in dimension the quantity of energy.
The discrete variational derivative method based on discrete differential forms
NASA Astrophysics Data System (ADS)
Yaguchi, Takaharu; Matsuo, Takayasu; Sugihara, Masaaki
2012-05-01
As is well known, for PDEs that enjoy a conservation or dissipation property, numerical schemes that inherit this property are often advantageous in that the schemes are fairly stable and give qualitatively better numerical solutions in practice. Lately, Furihata and Matsuo have developed the so-called “discrete variational derivative method” that automatically constructs energy preserving or dissipative finite difference schemes. Although this method was originally developed on uniform meshes, the use of non-uniform meshes is of importance for multi-dimensional problems. On the other hand, the theories of discrete differential forms have received much attention recently. These theories provide a discrete analogue of the vector calculus on general meshes. In this paper, we show that the discrete variational derivative method and the discrete differential forms by Bochev and Hyman can be combined. Applications to the Cahn-Hilliard equation and the Klein-Gordon equation on triangular meshes are provided as demonstrations. We also show that the schemes for these equations are H1-stable under some assumptions. In particular, one for the nonlinear Klein-Gordon equation is obtained by combination of the energy conservation property and the discrete Poincaré inequality, which are the temporal and spacial structures that are preserved by the above methods.
Separability in cohomogeneity-2 Kerr-NUT-AdS metrics
NASA Astrophysics Data System (ADS)
Chen, Wei; Lü, Hong; Pope, Christopher N.
2006-04-01
The remarkable and unexpected separability of the Hamilton-Jacobi and Klein-Gordon equations in the background of a rotating four-dimensional black hole played an important role in the construction of generalisations of the Kerr metric, and in the uncovering of hidden symmetries associated with the existence of Killing tensors. In this paper, we show that the Hamilton-Jacobi and Klein-Gordon equations are separable in Kerr-AdS backgrounds in all dimensions, if one specialises the rotation parameters so that the metrics have cohomogeneity 2. Furthermore, we show that this property of separability extends to the NUT generalisations of these cohomogeneity-2 black holes that we obtained in a recent paper. In all these cases, we also construct the associated irreducible rank-2 Killing tensor whose existence reflects the hidden symmetry that leads to the separability. We also consider some cohomogeneity-1 specialisations of the new Kerr-NUT-AdS metrics, showing how they relate to previous results in the literature.
2+1 dimensional magnetically charged solutions in Einstein-power-Maxwell theory
NASA Astrophysics Data System (ADS)
Mazharimousavi, S. Habib; Gurtug, O.; Halilsoy, M.; Unver, O.
2011-12-01
We obtain a class of magnetically charged solutions in 2+1 dimensional Einstein-Power-Maxwell theory. In the linear Maxwell limit, such horizonless solutions are known to exist. We show that in 3D geometry, black hole solutions with magnetic charge do not exist even if it is sourced by the power-Maxwell field. Physical properties of the solution with particular power k of the Maxwell field is investigated. The true timelike naked curvature singularity develops when k>1 which constitutes one of the striking effects of the power-Maxwell field. For specific power parameter k, the occurrence of a timelike naked singularity is analyzed in the quantum mechanical point of view. Quantum test fields obeying the Klein-Gordon and the Dirac equations are used to probe the singularity. It is shown that the class of static pure magnetic spacetime in the power-Maxwell theory is quantum-mechanically singular when it is probed with fields obeying Klein-Gordon and Dirac equations in the generic case.
Metric emerging to massive modes in quantum cosmological space-times
NASA Astrophysics Data System (ADS)
Dapor, Andrea; Lewandowski, Jerzy
2013-03-01
We consider a massive quantum test Klein-Gordon field probing a homogeneous isotropic quantum cosmological space-time in the background. In particular, we derive a semiclassical space-time which emerges to a mode of the field. The method consists of a comparison between quantum field theory on a quantum background and quantum field theory on a classical curved space-time, giving rise to an emergent metric tensor (its components being computed from the equation of propagation of the quantum Klein-Gordon field in the test field approximation). If the field is massless the emergent metric is of the Friedmann-Robertson-Walker form, but if a mass term is considered it turns out that the simplest emergent metric that displays the symmetries of the system is of the Bianchi I type, deformed in the direction of propagation of the particle. This anisotropy is of a quantum nature: it is proportional to ℏ and “dresses” the isotropic classical space-time obtained in the classical limit.
Quasi-exactly solvable relativistic soft-core Coulomb models
Agboola, Davids Zhang, Yao-Zhong
2012-09-15
By considering a unified treatment, we present quasi exact polynomial solutions to both the Klein-Gordon and Dirac equations with the family of soft-core Coulomb potentials V{sub q}(r)=-Z/(r{sup q}+{beta}{sup q}){sup 1/q}, Z>0, {beta}>0, q{>=}1. We consider cases q=1 and q=2 and show that both cases are reducible to the same basic ordinary differential equation. A systematic and closed form solution to the basic equation is obtained using the Bethe ansatz method. For each case, the expressions for the energies and the allowed parameters are obtained analytically and the wavefunctions are derived in terms of the roots of a set of Bethe ansatz equations. - Highlights: Black-Right-Pointing-Pointer The relativistic bound-state solutions of the soft-core Coulomb models. Black-Right-Pointing-Pointer Quasi-exact treatments of the Dirac and Klein-Gordon equations for the soft-core Coulomb models. Black-Right-Pointing-Pointer Solutions obtained in terms of the roots to the Bethe ansatz equations. Black-Right-Pointing-Pointer The hidden Lie algebraic structure discussed for the models. Black-Right-Pointing-Pointer Results useful in describing mesonic atoms and interaction of intense laser fields with atom.
NASA Astrophysics Data System (ADS)
Choudhury, Roy; Brown, Kevin
2000-11-01
A nonlinear stability analysis using a multiple scales perturbation procedure is performed for the instability of two layers of strongly anisotropic, magnetized, inviscid, arbitrarily compressible fluids in relative motion. Such configurations are of relevance in a variety of space and astrophysical configurations. For modes near the critical point of the linear neutral curve, the nonlinear evolution is shown to be governed by a complicated nonlinear Klein-Gordon equation. The nonlinear coefficient turns out to be complex which is, to the best of our knowledge, unlike previously considered cases and leads to very different dynamics from that reported earlier. Both the spatially dependent and space-independent versions of this equation are considered to obtain the regimes where the linearly unstable solutions either evolve to final permanent envelope wave patterns resembling the empirically observed interacting vortex ensembles, or are disrupted via nonlinear modulational instability. In particular, the complex nonlinearity allows the existence of quasiperiodic and chaotic wave envelopes unlike in earlier physical models governed by nonlinear Klein-Gordon equations. In addition, a Melnikov function formulation reveals the onset of chaos as a consequence of modulation of the external magnetic field.
Aplicación del Teorema de Nekhorochev para tiempos de estabilidad en Mecánica Celeste
NASA Astrophysics Data System (ADS)
Miloni, O.; Núñez, J.; Brunini, A.
En Mecánica Celeste, uno de los problemas centrales consiste en la determinación de los tiempos de estabilidad. El teorema de Nekhorochev proporciona un método para dicho estudio, para un sistema determinado por un hamiltoniano descripto en las variables acción-ángulo. El trabajo consiste en la acotación tanto del potencial perturbador y de la matriz hessiana del hamiltoniano integrable para determinar luego el tiempo de estabilidad de dicho sistema, donde por estabilidad se entiende la separación en norma infinito en el espacio de las acciones.
Una propuesta para el desarrollo de un arreglo de síntesis de apertura
NASA Astrophysics Data System (ADS)
Arnal, E. M.
Los estudios llevados a cabo en la transición del hidrógeno neutro a λ~21-cm han contribuído a incrementar nuestro conocimiento acerca de las propiedades globales del medio interestelar, sea este galáctico o extragaláctico. Avances en este campo han sido provocados, a menudo, por la puesta en servicio de radiotelescopios que poseen una mayor resolución angular. Aquí se presenta una propuesta para desarrollar un nuevo instrumento, un interferómetro, que permitirá abrir nuevas líneas de investigación. Este instrumento combinará la técnica de síntesis de apertura con la de espectroscopía de correlación digital, para alcanzar una resolución angular de 1' y un campo de visión de ~1o.7.
Charge-transfer-directed radical substitution enables para-selective C-H functionalization.
Boursalian, Gregory B; Ham, Won Seok; Mazzotti, Anthony R; Ritter, Tobias
2016-08-01
Efficient C-H functionalization requires selectivity for specific C-H bonds. Progress has been made for directed aromatic substitution reactions to achieve ortho and meta selectivity, but a general strategy for para-selective C-H functionalization has remained elusive. Herein we introduce a previously unappreciated concept that enables nearly complete para selectivity. We propose that radicals with high electron affinity elicit arene-to-radical charge transfer in the transition state of radical addition, which is the factor primarily responsible for high positional selectivity. We demonstrate with a simple theoretical tool that the selectivity is predictable and show the utility of the concept through a direct synthesis of aryl piperazines. Our results contradict the notion, widely held by organic chemists, that radical aromatic substitution reactions are inherently unselective. The concept of radical substitution directed by charge transfer could serve as the basis for the development of new, highly selective C-H functionalization reactions. PMID:27442288
Hong, C. S.; Ganetzky, B.
1996-01-01
To elucidate the mechanisms regulating expression of para, which encodes the major class of sodium channels in the Drosophila nervous system, we have tried to locate upstream cis-acting regulatory elements by mapping the transcriptional start site and analyzing the region immediately upstream of para in region 14D of the polytene chromosomes. From these studies, we have discovered that the region contains a cluster of neurally expressing genes. Here we report the molecular characterization of the genomic organization of the 14D region and the genes within this region, which are: calnexin (Cnx), actin related protein 14D (Arp14D), calcineurin A 14D (CnnA14D), and chromosome associated protein (Cap). The tight clustering of these genes, their neuronal expression patterns, and their potential functions related to expression, modulation, or regulation of sodium channels raise the possibility that these genes represent a functionally related group sharing some coordinate regulatory mechanism. PMID:8849894
Kwon, Woosung; Do, Sungan; Kim, Ji-Hee; Seok Jeong, Mun; Rhee, Shi-Woo
2015-01-01
Carbon nanodots (C-dots) are a kind of fluorescent carbon nanomaterials, composed of polyaromatic carbon domains surrounded by amorphous carbon frames, and have attracted a great deal of attention because of their interesting properties. There are still, however, challenges ahead such as blue-biased photoluminescence, spectral broadness, undefined energy gaps and etc. In this report, we chemically modify the surface of C-dots with a series of para-substituted anilines to control their photoluminescence. Our surface functionalization endows our C-dots with new energy levels, exhibiting long-wavelength (up to 650 nm) photoluminescence of very narrow spectral widths. The roles of para-substituted anilines and their substituents in developing such energy levels are thoroughly studied by using transient absorption spectroscopy. We finally demonstrate light-emitting devices exploiting our C-dots as a phosphor, converting UV light to a variety of colors with internal quantum yields of ca. 20%. PMID:26218869
Zuriaga-Agustí, E; Mendoza-Roca, J A; Bes-Piá, A; Alonso-Molina, J L; Amorós-Muñoz, I
2016-11-01
Nowadays cost reduction is a very important issue in wastewater treatment plants. One way, is to minimize the sludge production. Microorganisms break down the organic matter into inorganic compounds through catabolism. Uncoupling metabolism is a method which promote catabolism reactions instead of anabolism ones, where adenosine triphosphate synthesis is inhibited. In this work, the influence of the addition of para-nitrophenol and a commercial reagent to a sequencing batch reactor (SBR) on sludge production and process performance has been analyzed. Three laboratory SBRs were operated in parallel to compare the effect of the addition of both reagents with a control reactor. SBRs were fed with synthetic wastewater and were operated with the same conditions. Results showed that sludge production was slightly reduced for the tested para-nitrophenol concentrations (20 and 25 mg/L) and for a LODOred dose of 1 mL/day. Biological process performance was not influenced and high COD removals were achieved. PMID:27505165
ROTATIONAL SPECTROSCOPY OF THE CO-PARA-H{sub 2} MOLECULAR COMPLEX
Potapov, A. V.; Surin, L. A.; Giesen, T. F.; Schlemmer, S.; Panfilov, V. A.; Dumesh, B. S.; Raston, P. L.; Jaeger, W.
2009-10-01
The rotational spectrum of the CO-para-H{sub 2} van der Waals complex, produced using a molecular jet expansion, was observed with two different techniques: OROTRON intracavity millimeter-wave spectroscopy and pulsed Fourier transform microwave spectroscopy. Thirteen transitions in the frequency range from 80 to 130 GHz and two transitions in the 14 GHz region were measured and assigned, allowing for a precise determination of the corresponding energy level positions of CO-para-H{sub 2}. The data obtained enable further radio astronomical searches for this molecular complex and provide a sensitive test of the currently best available intermolecular potential energy surface for the CO-H{sub 2} system.
NASA Astrophysics Data System (ADS)
Miyamoto, Ayaho; Motoshita, Minoru; Casas, Joan R.
2013-12-01
Bridge monitoring system via information technology is capable of providing more accurate knowledge of bridge performance characteristics than traditional strategies. This paper describes not only an integrated Internet monitoring system that consists of a stand-alone monitoring system (SMS) and a Web-based Internet monitoring system (IMS) for bridge maintenance but also its application to para-stressing bridge system as an intelligent structure. IMS, as a Web-based system, is capable of addressing the remote monitoring by introducing measuring information derived from SMS into the system through Internet or intranet connected by either PHS or LAN. Moreover, the key functions of IMS such as data management system, condition assessment, and decision making with the proposed system are also introduced in this paper. Another goal of this study is to establish the framework of a para-stressing bridge system which is an intelligent bridge by integrating the bridge monitoring information into the system to control the bridge performance automatically.
Wuensch, Christiane; Pavkov-Keller, Tea; Steinkellner, Georg; Gross, Johannes; Fuchs, Michael; Hromic, Altijana; Lyskowski, Andrzej; Fauland, Kerstin; Gruber, Karl; Glueck, Silvia M; Faber, Kurt
2015-01-01
We report on a ‘green’ method for the utilization of carbon dioxide as C1 unit for the regioselective synthesis of (E)-cinnamic acids via regioselective enzymatic carboxylation of para-hydroxystyrenes. Phenolic acid decarboxylases from bacterial sources catalyzed the β-carboxylation of para-hydroxystyrene derivatives with excellent regio- and (E/Z)-stereoselectivity by exclusively acting at the β-carbon atom of the C=C side chain to furnish the corresponding (E)-cinnamic acid derivatives in up to 40% conversion at the expense of bicarbonate as carbon dioxide source. Studies on the substrate scope of this strategy are presented and a catalytic mechanism is proposed based on molecular modelling studies supported by mutagenesis of amino acid residues in the active site. PMID:26190963
Charge-transfer-directed radical substitution enables para-selective C–H functionalization
NASA Astrophysics Data System (ADS)
Boursalian, Gregory B.; Ham, Won Seok; Mazzotti, Anthony R.; Ritter, Tobias
2016-08-01
Efficient C–H functionalization requires selectivity for specific C–H bonds. Progress has been made for directed aromatic substitution reactions to achieve ortho and meta selectivity, but a general strategy for para-selective C–H functionalization has remained elusive. Herein we introduce a previously unappreciated concept that enables nearly complete para selectivity. We propose that radicals with high electron affinity elicit arene-to-radical charge transfer in the transition state of radical addition, which is the factor primarily responsible for high positional selectivity. We demonstrate with a simple theoretical tool that the selectivity is predictable and show the utility of the concept through a direct synthesis of aryl piperazines. Our results contradict the notion, widely held by organic chemists, that radical aromatic substitution reactions are inherently unselective. The concept of radical substitution directed by charge transfer could serve as the basis for the development of new, highly selective C–H functionalization reactions.
Bharali, Manuj Kr; Basumatary, Rajeev; Rahman, Taibur; Dutta, Karabi
2012-05-01
Hemolytic anemia and rhabdomyolysis have been often reported to be an adverse effect of drug- and chemical-induced toxicity both in experimental and real-life scenario. para-Phenylenediamine (PPD) is a derivative of para-nitroaniline and has been found as an ingredient of almost all hair dye formulations in varying concentrations from 2% to 4% w/v. Earlier studies have reported that the accidental oral ingestion of PPD in humans can lead to acute renal failure because of rhabdomyolysis. In the present investigation, we have tested the chronic topical application of PPD and its effect on the renal histology of Sprague-Dawley rats. The experiment provides clear evidence that topically applied PPD induces hemolytic anemia as evident from the decrease in the total RBC count, packed cell volume, and hemoglobin content apart from rhabdomyolysis which subsequently causes acute renal failure in rats. PMID:22778510
NASA Astrophysics Data System (ADS)
Ferreres Sabater, Agustin
Cualquier sistema electronico que incluya un procesado o tratamiento de la senal, y ademas, algun tipo de actuador mecanico generalmente necesita, como minimo, dos tensiones diferentes de alimentacion. Excluyendo los sistemas de alimentacion distribuida, la solucion tecnica mas utilizada para proporcionar dos o mas tensiones consiste en las fuentes de alimentacion multisalida. En una fuente de alimentacion multisalida los diferentes circuitos que conforman cada salida comparten un mismo transformador de potencia optimizando coste, masa, y volumen. Las ventajas obtenidas con este procedimiento tienen en su contra el efecto que sobre cada salida individual provocan las demas en su conjunto debido, principalmente, a los efectos de los elementos parasitos de los componentes. Un cambio de carga en una de las salidas produce un transitorio que es visto por todas las demas como un efecto de impedancia cruzada, y al final del transitorio, la tension de cada salida es diferente respecto a la que tenian antes del transitorio. Este ultimo resultado se conoce como regulacion cruzada. La disminucion de los efectos de la regulacion cruzada ha sido objeto de estudio durante los ultimos anos. El objetivo ha sido el desarrollo de distintas estrategias que permiten, desde disminuir los efectos de la regulacion cruzada hasta los niveles deseables, a eliminarla completamente. El resultado final suele suponer una penalizacion sobre el diseno del sistema directamente proporcional al grado de regulacion a conseguir en las distintas salidas. Entre las soluciones propuestas para eliminar la regulacion cruzada las tecnicas de post-regulacion se han consolidado como la opcion mas aceptada ya que, pueden aplicarse a cualquier convertidor y no suponen ninguna complejidad adicional a la hora de plantear el diseno. En esta Tesis Doctoral se abordara el estudio de la tecnica conocida como postregulacion mediante transformador controlado, que si bien se ha empleado en convertidores resonantes, su
Polar Effects Control the Gas-phase Reactivity of Charged para-Benzyne Analogs
Wittrig, Ashley M.; Archibold, Enada F.; Sheng, Huaming; Nash, John J.; Kenttämaa, Hilkka I.
2014-01-01
The gas-phase reactivity of charged para-benzynes is entirely unexplored as they and/or their precursors tend to undergo ring-opening upon their generation. We report here a gas-phase reactivity study of two such benzynes, the 2,5-didehydropyridinium and 5,8-didehydroisoquinolinium cations, generated in a modified dual-linear quadrupole ion trap (DLQIT) mass spectrometer. Both biradicals were found to form diagnostic products with organic molecules, indicating the presence of two radical sites. As opposed to earlier predictions that the singlet-triplet (S-T) splitting controls the radical reactivity of such species, the 2,5-didehydropyridinium cation reacts much faster in spite of its larger S-T splitting. Calculated vertical electron affinities of the radical sites of the para-benzynes, a parameter related to the polarity of the transition states of their reactions, appears to be the most important reactivity controlling factor. PMID:25838787
Iodine(III)-Mediated para-Selective Direct Imidation of Anilides.
Pialat, Amélie; Bergès, Julien; Sabourin, Axel; Vinck, Robin; Liégault, Benoît; Taillefer, Marc
2015-07-01
The direct, nucleophilic imidation of acetanilide derivatives has been performed under mild, iodine(III)-mediated or -catalyzed conditions, employing lithium triflimide as the nitrogen source. The reaction exhibits exclusive regioselectivity for the para position and shows a good tolerance for varied functional groups at both the ortho or meta positions. Preliminary mechanistic data suggest that the LiNTf2 reagent plays a key role in the reactivity. PMID:26095155
Mei, Qinggang; Wang, Chun; Zhao, Zhigang; Yuan, Weicheng; Zhang, Guolin
2015-01-01
The hemisynthesis of the naturally occurring bioactive flavonoid glycoside icariin (1) has been accomplished in eleven steps with 7% overall yield from kaempferol. The 4'-OH methylation of kaempferol, the 8-prenylation of 3-O-methoxymethyl-4'-O-methyl-5-O-prenyl-7-O-benzylkaempferol (8) via para-Claisen-Cope rearrangement catalyzed by Eu(fod)3 in the presence of NaHCO3, and the glycosylation of icaritin (3) are the key steps. PMID:26425179
Conformerism, enantiomorphism and double catemer motifs in para-substituted nostoclide analogues
NASA Astrophysics Data System (ADS)
Teixeira, Róbson Ricardo; Barbosa, Luiz Claudio Almeida; Valero Antolinez, Isabel; de Souza Corrêa, Rodrigo; Martins, Felipe Terra; Doriguetto, Antônio Carlos
2016-02-01
We have here elucidated the crystal structures of five nostoclide analogues. A common feature in all compounds is a substituent at the para-position of the benzylidene group. Compounds with either bromine (3) or hydroxyl (4) as para-substituent crystallizes with Z' = 2 as result of conformerism. It was also observed that Z' > 1 in the compound with a para-dimethylamino substituent (1). However, its four crystallographically independent molecules are conformationally similar. They are not related by crystallographic symmetry due to the offset packing of their C-H … Odbnd C nonclassical hydrogen bonded double chains. This compound (1) has also crystallized in a chiral space group (P21) despite the lack of a stereocenter. Such enantiomorphism phenomenon is related to the presence of only one of the two mirror benzyl conformations with phenyl ring at the equatorial position opposite the lactone oxygen atom. The molecular mean plane of nostoclide analogues has been featured by high level of planarity, except in the brominated compound where two twisted conformations occurred due to rotations on the single bond axis into benzylidene group. The benzyl conformation has been the greatest difference between the two crystallographically independent molecules of the para-hydroxylated compound (4). The crystal packing of the compounds is marked by double catemer motif assembled through C-H … Odbnd C non-classical hydrogen bonds, although C-H … π interactions do play an important role in stabilizing the crystal packing of some compounds of the series.
Highly regioselective para-methylthiolation/bridging methylenation of arylamines promoted by NH4I.
Xu, Yinfeng; Cong, Tiantian; Liu, Ping; Sun, Peipei
2015-10-14
Aryl methyl thioethers and methylene-bridged arylamines were synthesized via highly regioselective para-methylthiolation/bridging methylenation of arylamines using DMSO as the methylthio or methylene source in the presence of NH4I under metal-free conditions. For the substrates with both electron-donating and electron-withdrawing substituents, the reaction proceeded smoothly and gave moderate to good yields. PMID:26337143
Stimulated rotational Raman scattering in CO2-pumped para-H2
Carlsten, J.L.; Wenzel, R.G.
1983-09-01
Stimulated rotational Raman scattering in a 300 K multipass cell filled with para-H2 with a single-mode CO2 pump laser was studied using a single-mode OPO as a probe laser at the Stokes frequency for the So(0) transition. Amplification and pump depletion are examined as a function of incident pump energy. For an incident CO2 pump laser energy of 1.5 J, a photon conversion efficiency of 47 percent is observed.
ParaDiS on Blue Gene/L: stepping up to the challenge
Hommes, G; Arsenlis, A; Bulatov, V; Cai, W; Cook, R; Hiratani, M; Oppestrup, T; Rhee, M; Tang, M
2006-06-09
This paper reports on the efforts to enable fully scalable simulations of Dislocation Line Dynamics (DLD) for direct calculations of strength of crystalline materials. DLD simulations are challenging and do not lend themselves naturally to parallel computing. Through a combinations of novel physical approaches, mathematical algorithms and computational science developments, a new DLD code ParaDiS is shown to take meaningful advantage of BG/L and, by doing so, to enable discovery class science by computation.
Cáncer de cuello uterino—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento, la prevención, las causas y los exámenes de detección del cáncer de cuello uterino, así como referencias a estudios clínicos, investigación, estadísticas y otros temas relacionados.
Cáncer de pulmón—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento, la prevención, las causas y los exámenes de detección del cáncer de pulmón, así como referencias a estudios clínicos, investigación, estadísticas y otros temas
ParaDiS on BlueGene/L: scalable line dynamics
Bulatov, V; Cai, W; Fier, J; Hiratani, M; Pierce, T; Tang, M; Rhee, M; Yates, R K; Arsenlis, A
2004-04-29
We describe an innovative highly parallel application program, ParaDiS, which computes the plastic strength of materials by tracing the evolution of dislocation lines over time. We discuss the issues of scaling the code to tens of thousands of processors, and present early scaling results of the code run on a prototype of the BlueGene/L supercomputer being developed by IBM in partnership with the US DOE's ASC program.
Stable self-trapping and ring formation in polydiacetylene para-toluene sulfonate
NASA Astrophysics Data System (ADS)
Wright, Ewan M.; Lawrence, Brian L.; Torruellas, William; Stegeman, George
1995-12-01
Numerical simulations of two-dimensional beam propagation in polydiacetylene para-toluene sulfonate measured values for n2>0 and n3<0 , where Delta n=n2I+n 3I2 , predict stable self-trapping and a new phenomenon in which a spatial ring evolves from a Gaussian input beam. We interpret the numerical results theoretically, using the variational model of nonlinear Gaussian beam propagation.
Szatylowicz, Halina; Siodla, Tomasz; Stasyuk, Olga A; Krygowski, Tadeusz M
2016-04-28
Quantum chemical modeling was used to investigate the electron-donating properties of the amino group in a series of meta- and para-X-substituted anilines (X = NMe2, NH2, OH, OMe, CH3, H, F, Cl, CF3, CN, CHO, COMe, CONH2, COOH, NO2, and NO). Different methods (HF, B3LYP, and M06-2X) and basis sets (6-31+G(d,p), 6-311++G(d,p), and aug-cc-pVDZ) were applied and compared with the MP2 approach. The B3LYP/6-311++G(d,p) method was chosen as the most appropriate one. The substituent properties were described by σ, cSAR(X) and SESE descriptors; the amino group was characterized by structural (dCN, dNH and ΣNH2) and electronic [δ(N) and cSAR(NH2)] parameters; whereas the transmitting moiety was characterized by aromaticity indices HOMA and NICS, as well as by QTAIM characteristics at the ring critical point. All the used parameters were found to be mutually interrelated with much better correlations for the para-derivatives than the meta-derivatives. It was numerically confirmed that sensitivity of the amino group to the substituent effect was greater by over three times when the substituent was located in the para-position. In the case of the meta-derivatives, variability of characteristics for both the reaction center and the substituent was small. The reverse substituent effect was clearly shown by comparison of the cSAR(X) characteristics for monosubstituted benzenes, and meta- and para-substituted anilines. PMID:26725941
Parallel Visualization and Analysis with ParaView on a Cray XT4
Patchett, John; Ahrens, James; Ahern, Sean; Pugmire, Dave
2009-01-01
Scienti c data sets produced by modern supercomputers like ORNL s Cray XT 4, Jaguar, can be extremely large, making visualization and analysis more di cult as moving large resultant data to dedicated analysis systems can be pro- hibitively expensive. We share our continuing work of integrating a parallel visu- alization system, ParaView, on ORNL s Jaguar system and our e orts to enable extreme scale interactive data visualization and analysis. We will discuss porting challenges and present performance numbers.
Atlas de aves: Un metodo para documentar distribucion y seguir poblaciones
Robbins, C.S.; Dowell, B.A.; Dawson, D.K.
1988-01-01
Los Atlas de Aves son proyectos nacionales o regionalies para trazar en mapas la distribucion en reproduccion de cada especie de ave. Ese procedimiento se esta usando en Europa, Australia, Nueva Zelanda, Norteamerica, y partes de Africa. El tama?o de los cuadrados varia de medio grado de latitud y Iongitud hasta 5 x 5 km. El trabajo de campo de cada proyecto exige aproxlmadamente cinco a?os, pero los aficionados pueden llevar a cabo la mayor parte del trabajo. Es posible almacenar los resultados en un computador personal. Hay muchos beneficios: (I) se presenta la distribucion corriente de las aves de la nacion, del estado, o de la Iocalidad; (2) se desarrolla nueva informacion especialmente sobre especies raras o en peligro; (3) se descubren areas que tienen una avlfauna sobresaliente o habitats raros y ayuda a su proteccion, (4) se documentan cambios de dlstribucion; (5) se pueden usar para documentar cambios de poblacion, especialmente en los tropicos donde otros metodos son mas dificiles de usar porque hay muchas especies y no hay muchos observadores calificados en la identificacion de sonidos de las aves; (6) son proyectos buenos de investigacion para estudiantes graduados; (7) los turistas y los jefes de excursiones de historia natural pueden contribuir con muchas informaciones
NASA Astrophysics Data System (ADS)
Andrejeva, Anna; Gardner, Adrian M.; Tuttle, William D.; Wright, Timothy G.
2016-03-01
We give a description of the phenyl-ring-localized vibrational modes of the ground states of the para-disubstituted benzene molecules including both symmetric and asymmetric cases. In line with others, we quickly conclude that the use of Wilson mode labels is misleading and ambiguous; we conclude the same regarding the related ones of Varsányi. Instead we label the modes consistently based upon the Mulliken (Herzberg) method for the modes of para-difluorobenzene (pDFB). Since we wish the labelling scheme to cover both symmetrically- and asymmetrically-substituted molecules, we apply the Mulliken labelling under C2v symmetry. By studying the variation of the vibrational wavenumbers with mass of the substituent, we are able to identify the corresponding modes across a wide range of molecules and hence provide consistent assignments. Particularly interesting are pairs of vibrations that evolve from in- and out-of-phase motions in pDFB to more localized modes in asymmetric molecules. We consider the para isomers of the following: the symmetric dihalobenzenes, xylene, hydroquinone, the asymmetric dihalobenzenes, halotoluenes, halophenols and cresol.
The ortho:para-H_2 ratio in C- and J-type shocks
NASA Astrophysics Data System (ADS)
Wilgenbus, D.; Cabrit, S.; Pineau des Forêts, G.; Flower, D. R.
2000-04-01
We have computed extensive grids of models of both C- and J-type planar shock waves, propagating in dark, cold molecular clouds, in order to study systematically the behaviour of the ortho:para-H_2 ratio. Careful attention was paid to both macroscopic (dynamical) and microscopic (chemical reactions and collisional population transfer in H_2) aspects. We relate the predictions of the models to observational determinations of the ortho:para-H_2 ratio using both pure rotational lines and rovibrational lines. As an illustration, we consider ISO and ground-based H_2 observations of HH 54. Neither planar C-type nor planar J-type shocks appear able to account fully for these observations. Given the additional constraints provided by the observed ortho:para H_2 ratios, a C-type bowshock, or a C-type precursor followed by a J-type shock, remain as plausible models. Tables~2a-f and 4a-f are only available in electronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/Abstract.html
Theoretical study of the design of a catalyst for para to ortho hydrogen conversion
NASA Technical Reports Server (NTRS)
Coffman, Robert E.
1992-01-01
The theory of Petzinger and Scalapino (1973) was thoroughly reviewed, and all of the basic equations for paramagnetic para to ortho hydrogen catalysis re-derived. There are only a few minor phase errors and errors of omission in the description of the theory. Three models (described by Petzinger and Scalapino) for the rate of para to ortho H2 catalysis were worked out, and uniform agreement obtained to within a constant factor of 2 pi. The analytical methods developed in the course of this study were then extended to two new models, which more adequately describe the process of surface catalysis including transfer of hydrogen molecules onto and off of the surface. All five equations for the para to ortho catalytic rate of conversion are described. The two new equations describe the catalytic rate for these models: H2 on the surface is a 2-D gas with lifetime tau; and H2 on the surface is a 2-D liquid undergoing Brownian motion (diffusion) with surface lifetime tau.
The ortho:para ratio of H{sub 3}{sup +} in laboratory and astrophysical plasmas
Crabtree, Kyle N.; Indriolo, Nick; Kreckel, Holger; McCall, Benjamin J.
2015-01-22
The discovery of H{sub 3}{sup +} in the diffuse interstellar medium has dramatically changed our view of the cosmic-ray ionization rate in diffuse molecular clouds. However, another surprise has been that the ortho:para ratio of H{sub 3}{sup +} in these clouds is inconsistent with the temperature derived from the excitation of H{sub 2}, the dominant species in these clouds. In an effort to understand this discrepancy, we have embarked on an experimental program to measure the nuclear spin dependence of the dissociative electron recombination rate of H{sub 3}{sup +} using the CRYRING and TSR ion storage rings. We have also performed the first measurements of the reaction H{sub 3}{sup +}+H{sub 2}→H{sub 2}+H{sub 3}{sup +} below room temperature. This reaction is likely the most common bimolecular reaction in the universe, and plays an important role in interconverting ortho- and para-H{sub 3}{sup +}. Finally, we have constructed a steady-state chemical model for diffuse clouds, which takes into account the spin-dependence of the formation of H{sub 3}{sup +}, its electron recombination, and its reaction with H{sub 2}. We find that the ortho:para ratio of H{sub 3}{sup +} in diffuse clouds is likely governed by a competition between dissociative recombination and thermalization by reactive collisions.
ParaGard gets mixed reviews at one-year anniversary.
1989-07-01
IUDs fill a need for reliable convenient contraceptives in multiparous, monogamous women who have no history of ectopic pregnancy, pelvic inflammatory disease, or sexually transmitted disease, and who are primarily interested in birth spacing or who have completed their family and do not opt for sterilization. The only IUDs currently available in the US are Progestasert, a progestin-releasing device that must be replaced after 1 year, and ParaGard, a copper-bearing device manufactured by GynoPharma, that can be left in place for up to 4 years. IUD use has declined in the US because of adverse publicity and lawsuits. Both IUDs have problems with insertion. There is an incidence of 1.8 cervical lacerations for every 100 insertions, and the ParaGard inserter is likely to drop to the floor if the clinician fails to use the thumb ring, which is designed to keep it from doing so. ParaGard is accompanied by a 5-page consent form to protect the manufacturer, which deters many women. Prophylactic administration of antibiotics before insertion is recommended, and some clinicians recommend ibuprofen to prevent inflammation. Both IUDs cost about $80. PMID:12282179
Quantum chemical and experimental study of 1,2,4-trihydroxy-para-menthane
NASA Astrophysics Data System (ADS)
Rottmannová, Lenka; Lukeš, Vladimír; Ilčin, Michal; Fodran, Peter; Herich, Peter; Kožíšek, Jozef; Liptaj, Tibor; Klein, Erik
2013-10-01
The conformational analysis of the para-menthane (PM) and 1,2,4-trihydroxy-para-menthane (TPM) is performed using the quantum chemical density functional theory (DFT) and ab initio Møller-Plesset perturbation theory up to the second order (MP2). In TPM, three hydroxyl groups generate eight stereoisomers comparing to the four para-menthane stereoisomers. From the thermodynamics point of view, the most preferred conformations show the chair-shaped configuration of the cyclohexane ring. The obtained energy barriers for the isopropyl group rotation in the chair-shaped stereoisomers are between 35 and 45 kJ mol-1. The crystal structure as well as the solvated TPM stereoisomer isolated from the Tea tree oil, Melaleuca alternifolia (Maiden & Betche) Cheel, were investigated experimentally. Isolated stereoisomer corresponds to the most energetically preferred conformation and the calculated structural data agree very well with the results from the X-ray and nuclear magnetic resonance measurements. Finally, the influence of the conformation and the presence of the intramolecular hydrogen bonds on the homolytic Osbnd H bond dissociation enthalpies and proton affinities were also discussed with respect to the simple alcohols (methanol, iso-propanol, iso-pentanol, tert-butanol, cyclohexanol) and phenol.
El diseño final del espectrógrafo de banco (EBASIM) para CASLEO
NASA Astrophysics Data System (ADS)
Simmons, J.; Levato, H.
Utilizando el código de óptica ACCOS V se ha finalizado el diseño del espectrógrafo de banco para CASLEO. En una comunicación anterior habíamos indicado que utilizaríamos un colimador de 150 mm de diámetro con un radio de curvatura de 1540 mm. Para el espejo cámara, que tiene un diámetro de 200 mm, el radio de curvatura es de 1200 mm, ambos radios con una tolerancia no mayor a los 3 mm. En la presente, se informa sobre los detalles finales del cálculo del espectrógrafo que incluye el cómputo para 5 longitudes de onda diferentes y alrededor de 100 rayos. En todos los casos el 75 % de energía está dentro de un diámetro de 13 micrones. El diseño ha sido probado entre 3500 Å hasta 9000 Å con resultados satisfactorios.
Base de linhas moleculares para síntese espectral estelar
NASA Astrophysics Data System (ADS)
Milone, A.; Sanzovo, G.
2003-08-01
A análise das abundâncias quí micas fotosféricas em estrelas do tipo solar ou tardia, através do cálculo teórico de seus espectros, emprega a espectroscopia de alta resolução e necessita de uma base representativa de linhas atômicas e moleculares com suas respectivas constantes bem determinadas. Nesse trabalho, utilizamos como ponto de partida as extensas listas de linhas espectrais de sistemas eletrônicos de algumas moléculas diatômicas compiladas por Kurucz para a construção de uma base de linhas moleculares para a sí ntese espectral estelar. Revisamos as determinações dos fatores rotacionais de Honl-London das forças de oscilador das linhas moleculares, para cada banda vibracional de alguns sistemas eletrônicos, seguindo a regra usual de normalização. Usamos as forças de oscilador eletrônicas da literatura. Os fatores vibracionais de Franck-Condon de cada banda foram especialmente recalculados empregando-se novas constantes moleculares. Reproduzimos, com êxito, as absorções espectrais de determinadas bandas eletrônicas-vibracionais das espécies moleculares C12C12, C12N14 e Mg24H em espectros de estrelas de referência como o Sol e Arcturus.
Hu, Peiguang; Chen, Limei; Deming, Christopher P; Lu, Jia-En; Bonny, Lewis W; Chen, Shaowei
2016-06-01
Stable platinum nanoparticles were successfully prepared by the self-assembly of para-substituted styrene derivatives onto the platinum surfaces as a result of platinum-catalyzed dehydrogenation and transformation of the vinyl groups to the acetylene ones, forming platinum-vinylidene/-acetylide interfacial bonds. Transmission electron microscopic measurements showed that the nanoparticles were well dispersed without apparent aggregation, suggesting sufficient protection of the nanoparticles by the organic capping ligands, and the average core diameter was estimated to be 2.0 ± 0.3 nm, 1.3 ± 0.2 nm, and 1.1 ± 0.2 nm for the nanoparticles capped with 4-tert-butylstyrene, 4-methoxystyrene, and 4-(trifluoromethyl)styrene, respectively, as a result of the decreasing rate of dehydrogenation with the increasing Taft (polar) constant of the para-substituents. Importantly, the resulting nanoparticles exhibited unique photoluminescence, where an increase of the Hammett constant of the para-substituents corresponded to a blue-shift of the photoluminescence emission, suggesting an enlargement of the HOMO-LUMO band gap of the nanoparticle-bound acetylene moieties. Furthermore, the resulting nanoparticles exhibited apparent electrocatalytic activity towards oxygen reduction in acidic media, with the best performance among the series of samples observed with the 4-tert-butylstyrene-capped nanoparticles due to an optimal combination of the nanoparticle core size and ligand effects on the bonding interactions between platinum and oxygen species. PMID:27242019
The "drinking-buddy" scale as a measure of para-social behavior.
Powell, Larry; Richmond, Virginia P; Cantrell-Williams, Glenda
2012-06-01
Para-social behavior is a form of quasi-interpersonal behavior that results when audience members develop bonds with media personalities that can resemble interpersonal social interaction, but is not usually applied to political communication. This study tested whether the "Drinking-Buddy" Scale, a simple question frequently used in political communication, could be interpreted as a single-item measure of para-social behavior with respect to political candidates in terms of image judgments related to interpersonal attraction and perceived similarity to self. The participants were college students who had voted in the 2008 election. They rated the candidates, Obama or McCain, as drinking buddies and then rated the candidates' perceived similarity to themselves in attitude and background, and also the social and task attraction to the candidate. If the drinking-buddy rating serves as a proxy measure for para-social behavior, then it was expected that participants' ratings for all four kinds of similarity to and attraction toward a candidate would be higher for the candidate they chose as a drinking buddy. The directional hypotheses were supported for interpersonal attraction, but not for perceived similarity. These results indicate that the drinking-buddy scale predicts ratings of interpersonal attraction, while voters may view perceived similarity as an important but not essential factor in their candidate preference. PMID:22897105
Single crystalline nature of para-sexiphenyl crystallites grown on KCl(100).
Haber, T; Oehzelt, M; Resel, R; Andreev, A; Thierry, A; Sitter, H; Smilgies, D M; Schaffer, B; Grogger, W; Resel, R
2006-03-01
This work focuses on studies of the single crystal nature of para-sexiphenyl structures grown on freshly cleaved KCl(100) surfaces. Two different kinds of morphologies, namely terrace like structures and needle like structures, are found by atomic force microscopy as well as by electron microscopy. Regardless of the morphology the individual crystallites show highly regular shapes. The crystalline alignment and the degree of order of the crystallites on the surface are determined by X-ray diffraction. Several epitaxial alignments of para-sexiphenyl on KCl(100) are observed and all of them are perfectly aligned on the surface. The rocking curve widths of the organic crystallites do not exceed 800" which is approximately only the four fold of the substrates' ones. The single crystalline nature of para-sexiphenyl crystallites is proven by transmission electron microscopy, diffraction patterns, dark field imaging and high resolution techniques. Single crystalline terraced mounds reach diameters of several microns and heights of 50 nm. Single crystal needles show heights and breadths of more than 100 nm and lengths of several microns. PMID:16573123
Neoplasias mieloproliferativas y síndromes mielodisplásicos—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento de las neoplasias mieloproliferativas, así como referencias a estudios clínicos y otros temas relacionados.
Melhoramentos no código Wilson-Devinney para binárias eclipsantes
NASA Astrophysics Data System (ADS)
Vieira, L. A.; Vaz, L. P. R.
2003-08-01
A análise de curvas de luz e velocidades radiais de sistemas binários eclipsantes pode ser feita por meio de vários modelos. Um desses é o Modelo Wilson-Devinney (WD). Ao longo dos anos, esse modelo sofreu várias alterações em seus códigos principais, com a finalidade de torná-lo mais consistente tanto fíisica como numericamente. O Modelo WD tem sido melhorado de várias maneiras em seus dois códigos: um para a predição das curvas de luz teórica e de velocidade radiais e outra para as soluções destas curvas. Teoricamente, na física do modelo, nós introduzimos a possibilidade de levar em conta os efeitos do movimento apsidal. Numericamente, nós introduzimos a possibilidade de usar o Método SIMPLEX no procedimento da solução, como uma alternativa para o já implementado Método de Mínimos Quadrados (Least Squares Method). Estas modificações, juntamente com outras já introduzidas pelo nosso grupo anteriormente, tornam o código mais eficiente na solução das curvas de luz e de velocidade radiais de binárias eclipsantes. Como o modelo tem sido usado para analisar sistemas com componentes pré-sequência principal (TY CrA, Casey et al. 1998, Vaz et al. 1998), SM 790, Stassun et al. 2003), este melhoramento beneficiará estes casos também. Apresentamos os resultados obtidos com a modificação do código WD por meio do uso de dados da estrela GL Carinae, comprovando, (1) que os parâmetros orbitais calculados por nós são coerentes com os obtidos anteriormente na literatura (Giménez & Clausen, 1986) e com os obtidos por Faria (1987), e (2) que a implementação do Método SIMPLEX torna o código mais lento mas completamente consistente internamente e evita os problemas gerados pelo uso do Método de Mínimos Quadrados, tais como imprecisão no cálculo das derivadas parciais e convergência para mínimos locais.
Quantum Monte Carlo Simulation of Vibrational Frequency Shifts of CO in Solid para-HYDROGEN
NASA Astrophysics Data System (ADS)
Wang, Lecheng; Le Roy, Robert; Roy, Pierre-Nicholas
2014-06-01
Stimulated by Fajardo's remarkable study of the rovibrational spectra of CO isotopologues trapped in solid para-hydrogen, we have performed quantum Monte Carlo simulations to predict his observed vibrational frequency shifts and inertial rotational constants using 2-body potentials based on the best available models for the pH_2-pH_2 and CO-pH_2, potential energy functions. We started by fitting an analytic `Morse/Long-Range' (MLR) function to the 1D ``adiabaic hindered rotor" version of Hinde's 5D pH_2-pH_2 potential developed by Faruk et al. We then modified it to take account of many-body effects by scaling it until it yielded the correct equilibrium lattice parameters for the fcc and hcp structures of pure solid para-hydrogen. A CO molecule was then placed at different interstitial or substitution sites in large equilibrated fcc or hcp para-hydrogen lattices, and the structural and dynamical behaviors of the micro-solvation environment around CO were simulated with a PIMC algorithm using a 2D effective pH_2-CO potential based on the 5D H_2--CO potential energy surface recently reported by Li et al., with a lattice sum of values of the 2D CO vibrational difference potential being use to predict the vibrational frequency shift. The effective rotational constants Beff for CO in different solid para-hydrogen structures were also calculated and compared with the experimental observations and with predicted Beff values for CO in large-sized para-hydrogen--CO clusters. M. E. Fajardo, J. Phys. Chem. A 117, 13504 (2013). R. Hinde, J. Chem. Phys., 128, 154308 (2008). H. Li, X-L. Zhang, R.J. Le Roy, and P.-N. Roy, J. Chem. Phys. 139, 164315 (2013). R.J. Le Roy, C.C. Haugen, J. Tao and Hui Li, Mol. Phys., 109, 435 (2011) N. Faruk, R.J. Le Roy, and P.-N. Roy, J. Chem. Phys. (submitted December 2013). Y. Mizumoto and Y. Ohtsuki, Chem. Phys. Lett. 501, 304 (2011).
Implementação de um algoritmo para a limpeza de mapas da RCFM
NASA Astrophysics Data System (ADS)
Souza, C. L.; Wuensche, C. A.
2003-08-01
A Radiação Cósmica de Fundo em Microondas (RCFM), descoberta por Penzias e Wilson em 1965, é uma das ferramentas mais poderosas para o estudo da cosmologia. Com a descoberta de flutuações de temperatura na RCFM, da ordem de uma parte em 105, pelo COBE (1992), uma nova era teve início. Nos últimos onze anos, diversos instrumentos fizeram novas medidas de alta precisão, refinando os resultados apresentados pelo COBE, culminando com os resultados recentes do satélite WMAP. A análise de dados da RCFM, especialmente no caso de experimentos com pequena cobertura do céu, apresenta uma série de dificuldades devido a emissões de contaminantes externos, tais como a emissão da Galáxia e de fontes pontuais, e de ruídos intrínsecos tanto ao sistema de detecção quanto à estratégia de observação do céu. Uma das soluções típicas para a filtragem de dados brutos de um experimento para medir flutuações de temperatura é aplicar um gabarito (template) e um filtro passa alta ao produzir mapas simplificados (sem considerar matrizes de correlação ou covariância). No caso de experimentos que utilizam detectores HEMT, essa combinação de filtros remove, satisfatoriamente, ruídos do tipo 1/f gerados pela instabilidade no ganho do detector acoplado ao movimento do instrumento, definido pela estratégia de observação. Entretanto, o sinal resultante medido, tanto em simulações quanto em séries temporais reais, sugere que parte do sinal cosmológico pode estar sendo removido junto com o ruído dos detectores. Este trabalho descreve as etapas para a produção de um mapa típico (simulado) e os testes preliminares de um algoritmo para remover ruídos do tipo 1/f introduzidos pela estratégia de observação sem prejudicar a qualidade do sinal cosmológico presente no mapa.
ParaDyn Implementation in the US Navy's DYSMAS Simulation System: FY08 Progress Report
Ferencz, R M; DeGroot, A J; Lin, J I; Zywicz, E; Durrenberger, J K; Sherwood, R J; Corey, I R
2008-07-29
The goal of this project is to increase the computational efficiency and capacity of the Navy's DYSMAS simulation system for full ship shock response to underwater explosion. Specifically, this project initiates migration to a parallel processing capability for the structural portion of the overall fluid-structure interaction model. The capstone objective for the first phase is to demonstrate operation of the DYSMAS simulation engine with a production model on a Naval Surface Warfare Center (IHD) parallel platform using the ParaDyn code for parallel processing of the structural dynamics. This year saw a successful launch to integrate ParaDyn, the high-parallel structural dynamics code from Lawrence Livermore National Laboratory (LLNL), into the DYSMAS system for simulating the response of ship structures to underwater explosion (UNDEX). The current LLNL version of DYNA3D, representing ten years of general development beyond the source branch used to initiate DYNA-N customization for DYSMAS, was first connected to the GEMINI flow code through DYSMAS Standard Coupler Interface (SCI). This permitted an early 'sanity check' by Naval Surface Warfare Center, Indian Head Division (NSWC-IHD) personnel that equivalent results were generated for their standard UNDEX test problems, thus ensuring the Verification & Validation pedigree they have developed remains intact. The ParaDyn code was then joined to the SCI in a manner requiring no changes to GEMINI. Three NSWC-IHD engineers were twice hosted at LLNL to become familiar with LLNL computer systems, the execution of the prototype software system, and to begin assessment of its accuracy and performance. Scaling data for the flow solver GEMINI was attained up to a one billion cell, 1000 processor run. The NSWC-IHD engineers were granted privileges to continue their evaluations through remote connections to LLNL's Open Computing Facility. Finally, the prototype changes were integrated into the mainline ParaDyn source
El uso de la neuromodulación para el tratamiento del temblor
Bendersky, Damián; Ajler, Pablo; Yampolsky, Claudio
2014-01-01
Introducción: El temblor puede ser un desorden incapacitante y el tratamiento de primera línea para estos pacientes es farmacológico. Sin embargo, este tratamiento puede llevar a una reducción satisfactoria del temblor en sólo el 50% de los pacientes con temblor esencial. La talamotomía era el tratamiento de elección para el temblor refractario al tratamiento médico hasta que comenzó a utilizarse la estimulación cerebral profunda (ECP) del núcleo ventral intermedio (Vim) del tálamo. En la actualidad, raramente se realiza la talamotomía. Métodos: Este artículo es una revisión no sistemática de las indicaciones, resultados, parámetros de programación y técnica quirúrgica de la ECP del Vim para el tratamiento del temblor. Resultados: Aunque los resultados clínicos son similares usando la talamotomía o la ECP del Vim, la primera causa más efectos adversos que la última. Además, la ECP puede ser usada bilateralmente, mientras que la talamotomía tiene un alto riesgo de causar disartria cuando se realiza de ambos lados. La ECP del Vim logró una adecuada mejoría del temblor en varias series de pacientes con temblor causado por temblor esencial, enfermedad de Parkinson o esclerosis múltiple. Además del Vim, hay otros blancos que están siendo usados por varios autores, tales como la zona incerta y las radiaciones prelemniscales. Conclusión: La ECP del Vim es un tratamiento útil para el temblor incapacitante refractario al tratamiento médico. Es esencial realizar una precisa selección de pacientes, así como utilizar una técnica quirúrgica correcta. Aún se desconoce el mejor blanco estereotáctico para el temblor, aunque el Vim es el más usado. PMID:25165613
Tanaka, Chiho; Nambu, Yoko; Endo, Takeshi
1992-08-20
New viologen derivatives having the various para-substituted benzophenone groups connected with a -(CH{sub 2}){sub 3}-linkage were effectively photoreduced by dimethyl sulfoxide by the intramolecular charge transfer complex formation between the viologen and benzophenone groups through effective stacking. The photoreduction was enhanced by the introduction of electron-donating para-substituents on the benzophenone units which were favorable for the intramolecular charge transfer complexation. 6 refs., 5 figs.
NASA Astrophysics Data System (ADS)
Danylyuk, Oksana; Monachino, Melany; Lazar, Adina N.; Suwinska, Kinga; Coleman, Anthony W.
2010-02-01
The solid-state complexes between para-sulphonato-calix[4]arene and the drugs tamoxifen and tetracaine show an unusual 4:1 guest-host stoichiometry with formation of hydrophobic layer of drug molecules held between bilayers of para-sulphonato-calix[4]arene. In both structures each of the four independent drug molecules adopts different conformation due to the different mode of interaction with the anionic host, the neighbouring drug cations and water molecules.
Zhang, Jun-Jie; Liu, Hong; Xiao, Yi; Zhang, Xian-En; Zhou, Ning-Yi
2009-01-01
Pseudomonas sp. strain WBC-3 utilizes para-nitrophenol (PNP) as a sole source of carbon, nitrogen, and energy. In order to identify the genes involved in this utilization, we cloned and sequenced a 12.7-kb fragment containing a conserved region of NAD(P)H:quinone oxidoreductase genes. Of the products of the 13 open reading frames deduced from this fragment, PnpA shares 24% identity to the large component of a 3-hydroxyphenylacetate hydroxylase from Pseudomonas putida U and PnpB is 58% identical to an NAD(P)H:quinone oxidoreductase from Escherichia coli. Both PnpA and PnpB were purified to homogeneity as His-tagged proteins, and they were considered to be a monomer and a dimer, respectively, as determined by gel filtration. PnpA is a flavin adenine dinucleotide-dependent single-component PNP 4-monooxygenase that converts PNP to para-benzoquinone in the presence of NADPH. PnpB is a flavin mononucleotide-and NADPH-dependent p-benzoquinone reductase that catalyzes the reduction of p-benzoquinone to hydroquinone. PnpB could enhance PnpA activity, and genetic analyses indicated that both pnpA and pnpB play essential roles in PNP mineralization in strain WBC-3. Furthermore, the pnpCDEF gene cluster next to pnpAB shares significant similarities with and has the same organization as a gene cluster responsible for hydroquinone degradation (hapCDEF) in Pseudomonas fluorescens ACB (M. J. Moonen, N. M. Kamerbeek, A. H. Westphal, S. A. Boeren, D. B. Janssen, M. W. Fraaije, and W. J. van Berkel, J. Bacteriol. 190:5190-5198, 2008), suggesting that the genes involved in PNP degradation are physically linked. PMID:19218392
NASA Astrophysics Data System (ADS)
Hu, Peiguang; Chen, Limei; Deming, Christopher P.; Lu, Jia-En; Bonny, Lewis W.; Chen, Shaowei
2016-06-01
Stable platinum nanoparticles were successfully prepared by the self-assembly of para-substituted styrene derivatives onto the platinum surfaces as a result of platinum-catalyzed dehydrogenation and transformation of the vinyl groups to the acetylene ones, forming platinum-vinylidene/-acetylide interfacial bonds. Transmission electron microscopic measurements showed that the nanoparticles were well dispersed without apparent aggregation, suggesting sufficient protection of the nanoparticles by the organic capping ligands, and the average core diameter was estimated to be 2.0 +/- 0.3 nm, 1.3 +/- 0.2 nm, and 1.1 +/- 0.2 nm for the nanoparticles capped with 4-tert-butylstyrene, 4-methoxystyrene, and 4-(trifluoromethyl)styrene, respectively, as a result of the decreasing rate of dehydrogenation with the increasing Taft (polar) constant of the para-substituents. Importantly, the resulting nanoparticles exhibited unique photoluminescence, where an increase of the Hammett constant of the para-substituents corresponded to a blue-shift of the photoluminescence emission, suggesting an enlargement of the HOMO-LUMO band gap of the nanoparticle-bound acetylene moieties. Furthermore, the resulting nanoparticles exhibited apparent electrocatalytic activity towards oxygen reduction in acidic media, with the best performance among the series of samples observed with the 4-tert-butylstyrene-capped nanoparticles due to an optimal combination of the nanoparticle core size and ligand effects on the bonding interactions between platinum and oxygen species.Stable platinum nanoparticles were successfully prepared by the self-assembly of para-substituted styrene derivatives onto the platinum surfaces as a result of platinum-catalyzed dehydrogenation and transformation of the vinyl groups to the acetylene ones, forming platinum-vinylidene/-acetylide interfacial bonds. Transmission electron microscopic measurements showed that the nanoparticles were well dispersed without apparent
Madres para la Salud: Design of a Theory-based Intervention for Postpartum Latinas
Keller, Colleen; Records, Kathie; Ainsworth, Barbara; Belyea, Michael; Permana, Paska; Coonrod, Dean; Vega-López, Sonia; Nagle-Williams, Allison
2011-01-01
Background Weight gain in young women suggests that childbearing may be an important contributor to the development of obesity in women. Depressive symptoms can interfere with resumption of normal activity levels following childbirth or with the initiation of or adherence to physical activity programs essential for losing pregnancy weight. Depression symptoms may function directly to promote weight gain through a physiologic mechanism. Obesity and its related insulin resistance may contribute to depressed mood physiologically. Although physical activity has well-established beneficial effects on weight management and depression, women tend to under participate in physical activity during childbearing years. Further, the mechanisms underpinning the interplay of overweight, obesity, physical activity, depression, and inflammatory processes are not clearly explained. Objectives This report describes the theoretical rationale, design considerations, and cultural relevance for “Madres para la Salud” [Mothers for Health]. Design and Methods Madres para la Salud is a 12 month prospective, randomized controlled trial exploring the effectiveness of a culturally specific intervention using “bouts” of physical activity to effect changes in body fat, systemic and fat tissue inflammation, and postpartum depression symptoms in sedentary postpartum Latinas. Summary The significance and innovation of Madres para la Salud includes use of a theory-driven approach to intervention, specification and cultural relevance of a social support intervention, use of a Promotora model to incorporate cultural approaches, use of objective measures of physical activity in post partum Latinas women, and the examination of biomarkers indicative of cardiovascular risk related to physical activity behaviors in postpartum Latinas. PMID:21238614
Supported transition metal catalysts for para- to ortho-hydrogen conversion
NASA Technical Reports Server (NTRS)
Brooks, Christopher J.; Wang, Wei; Eyman, Darrell P.
1994-01-01
The main goal of this study was to develop and improve on existing catalysts for the conversion of ortho- to para-hydrogen. Starting with a commercially available Air Products nickel silicate, which had a beta value of 20, we were trying to synthesize catalysts that would be an improvement to AP. This was accomplished by preparing silicates with various metals as well as different preparation methods. We also prepared supported ruthenium catalysts by various techniques using several metal precursors to improve present technology. What was also found was that the activation conditions prior to catalytic testing was highly important for both the silicates and the supported ruthenium catalysts. While not the initial focus of the research, we made some interesting observations into the adsorption of H2 on ruthenium. This helped us to get a better understanding of how ortho- to para-H2 conversion takes place, and what features in a catalyst are important to optimize activity. Reactor design was the final area in which some interesting conclusions were drawn. As discussed earlier, the reactor catalyst bed must be constructed using straight 1/8 feet OD stainless steel tubing. It was determined that the use of 1/4 feet OD tubing caused two problems. First, the radius from the center of the bed to the wall was too great for thermal equilibrium. Since the reaction of ortho- to para-H2 is exothermic, the catalyst bed center was warmer than the edges. Second, the catalyst bed was too shallow using a 1/4 feet tube. This caused reactant blow-by which was thought to decrease the measured activity when the flow rate was increased. The 1/8 feet tube corrected both of these concerns.
Molecular basis for H blood group deficiency in Bombay (Oh) and para-Bombay individuals.
Kelly, R J; Ernst, L K; Larsen, R D; Bryant, J G; Robinson, J S; Lowe, J B
1994-01-01
The penultimate step in the biosynthesis of the human ABO blood group oligosaccharide antigens is catalyzed by alpha-(1,2)-fucosyltransferase(s) (GDP-L-fucose: beta-D-galactoside 2-alpha-L-fucosyltransferase, EC 2.4.1.69), whose expression is determined by the H and Secretor (SE) blood group loci (also known as FUT1 and FUT2, respectively). These enzymes construct Fuc alpha 1-->2Gal beta-linkages, known as H determinants, which are essential precursors to the A and B antigens. Erythrocytes from individuals with the rare Bombay and para-Bombay blood group phenotypes are deficient in H determinants, and thus A and B determinants, as a consequence of apparent homozygosity for null alleles at the H locus. We report a molecular analysis of a human alpha-(1,2)-fucosyltransferase gene, thought to correspond to the H blood group locus, in a Bombay pedigree and a para-Bombay pedigree. We find inactivating point mutations in the coding regions of both alleles of this gene in each H-deficient individual. These results define the molecular basis for H blood group antigen deficiency in Bombay and para-Bombay phenotypes, provide compelling evidence that this gene represents the human H blood group locus, and strongly support a hypothesis that the H and SE loci represent distinct alpha-(1,2)-fucosyltransferase genes. Candidate sequences for the human SE locus are identified by low-stringency Southern blot hybridization analyses, using a probe derived from the H alpha-(1,2)-fucosyltransferase gene. Images PMID:7912436
Šimčíková, Michaela; Alves, Cláudia P A; Brito, Liliana; Prather, Kristala L J; Prazeres, Duarte M F; Monteiro, Gabriel A
2016-08-01
The use of minicircles in gene therapy applications is dependent on the availability of high-producer cell systems. In order to improve the performance of minicircle production in Escherichia coli by ParA resolvase-mediated in vivo recombination, we focus on the 5' untranslated region (5'-UTR) of parA messenger RNA (mRNA). The arabinose-inducible PBAD/araC promoter controls ParA expression and strains with improved arabinose uptake are used. The 27-nucleotide-long 5'-UTR of parA mRNA was optimized using a predictive thermodynamic model. An analysis of original and optimized mRNA subsequences predicted a decrease of 8.6-14.9 kcal/mol in the change in Gibbs free energy upon assembly of the 30S ribosome complex with the mRNA subsequences, indicating a more stable mRNA-rRNA complex and enabling a higher (48-817-fold) translation initiation rate. No effect of the 5'-UTR was detected when ParA was expressed from a low-copy number plasmid (∼14 copies/cell), with full recombination obtained within 2 h. However, when the parA gene was inserted in the bacterial chromosome, a faster and more effective recombination was obtained with the optimized 5'-UTR. Interestingly, the amount of this transcript was 2.6-3-fold higher when compared with the transcript generated from the original sequence, highlighting that 5'-UTR affects the level of the transcript. A Western blot analysis confirmed that E. coli synthesized higher amounts of ParA with the new 5'-UTR (∼1.8 ± 0.7-fold). Overall, these results show that the improvements made in the 5'-UTR can lead to a more efficient translation and hence to faster and more efficient minicircle generation. PMID:27147534
Liu, Shubin
2014-11-21
Electrophilic aromatic substitution as one of the most fundamental chemical processes is affected by atoms or groups already attached to the aromatic ring. The groups that promote substitution at the ortho/para or meta positions are, respectively, called ortho/para and meta directing groups, which are often characterized by their capability to donate electrons to or withdraw electrons from the ring. Though resonance and inductive effects have been employed in textbooks to explain this phenomenon, no satisfactory quantitative interpretation is available in the literature. Here, based on the theoretical framework we recently established in density functional reactivity theory (DFRT), where electrophilicity and nucleophilicity are simultaneously quantified by the Hirshfeld charge, the nature of ortho/para and meta group directing is systematically investigated for a total of 85 systems. We find that regioselectivity of electrophilic attacks is determined by the Hirshfeld charge distribution on the aromatic ring. Ortho/para directing groups have most negative charges on the ortho/para positions, while meta directing groups often possess the largest negative charge on the meta position. Our results do not support that ortho/para directing groups are electron donors and meta directing groups are electron acceptors. Most neutral species we studied here are electron withdrawal in nature. Anionic systems are always electron donors. There are also electron donors serving as meta directing groups. We predicted ortho/para and meta group directing behaviors for a list of groups whose regioselectivity is previously unknown. In addition, strong linear correlations between the Hirshfeld charge and the highest occupied molecular orbital have been observed, providing the first link between the frontier molecular orbital theory and DFRT.
A centroid molecular dynamics study of liquid para-hydrogen and ortho-deuterium.
Hone, Tyler D; Voth, Gregory A
2004-10-01
Centroid molecular dynamics (CMD) is applied to the study of collective and single-particle dynamics in liquid para-hydrogen at two state points and liquid ortho-deuterium at one state point. The CMD results are compared with the results of classical molecular dynamics, quantum mode coupling theory, a maximum entropy analytic continuation approach, pair-product forward- backward semiclassical dynamics, and available experimental results. The self-diffusion constants are in excellent agreement with the experimental measurements for all systems studied. Furthermore, it is shown that the method is able to adequately describe both the single-particle and collective dynamics of quantum liquids. PMID:15446940
Various Spectrum of MRI Findings in Articular and Para-articular Tuberculosis: Pictorial Assay.
Panchal, Hiten; Chiripal, Priyanka
2015-12-01
Tuberculosis continues to be a health-related issue in India. Musculoskeletal tuberculosis is noted to occur dramatically as isolates, primarily accounting for large numbers of extra-pulmonary tuberculosis since early diagnosis is always a priority; with good prognosis, it is a curable disease. Delayed treatment is associated with severe morbidity. Musculoskeletal tuberculosis accounts for a large number of extra-pulmonary tuberculosis. In this article, we describe various articular and para-articular MRI spectrum findings that are seen in patients with tuberculosis. MRI is the perfect modality to study the extent of involvement and its related complications. PMID:26730089
Kwamou, Guy M N; Sandjo, Louis P; Kuete, Victor; Wandja, Anaelle A K; Tankeo, Simplice B; Efferth, Thomas; Nkengfack, Augustin E
2015-01-01
A new unprecedented cinnamate derivative (1) was obtained from Erythrina excelsa (Leguminosae) and identified as nonadecyl para-hydroperoxycinnamate. This compound was isolated together with three known compounds, namely lupeol (2), mixture of sitosterol and stigmasterol (3), and isoneorautenol (4). Their structures were established on the basis of NMR and mass spectroscopic data in conjunction with those reported in the literature. Compound 1 was evaluated for its capability of inhibiting cancer cell lines and growth of a panel of microbial strains. It turned out that 1 is moderately to significantly cytotoxic against six cancer cell lines and shows weak to no antimicrobial activity. PMID:25220189
Stimulated rotational Raman scattering in CO/sub 2/ - pumped para - H/sub 2/
Carlsten, J.L.; Wenzel, R.
1983-09-01
Stimulated rotational Raman scattering in a 300 K multipass cell filled with para-H/sub 2/ with a single-mode CO/sub 2/ pump laser was studied using a single-mode OPO as a probe laser at the Stokes frequency for the S/sub 0/ (0) transition. Amplification and pump depletion are examined as a function of incident pump energy. For an incident CO/sub 2/ pump laser energy of 1.5 J, a photon conversion efficiency of 47 percent is observed.
Romain, Maxime; Thiery, Sébastien; Shirinskaya, Anna; Declairieux, Céline; Tondelier, Denis; Geffroy, Bernard; Jeannin, Olivier; Rault-Berthelot, Joëlle; Métivier, Rémi; Poriel, Cyril
2015-01-19
This work reports the first structure-properties relationship study of ortho [2,1-c]-, meta [1,2-a]-, and para [1,2-b]dihydroindenofluorenes, highlighting the influence of bridge rigidification on the electronic properties. This study has made it possible to devise an extended π-conjugated molecule with both a high triplet state energy level and excellent thermal and morphological stability. As a proof of concept, dihydroindenofluorenes were used as the host in sky-blue phosphorescent organic light-emitting diodes (PhOLEDs) with high performance. PMID:25469476
Munzenrider, J.E.; Doppke, K.P.; Brown, A.P.; Burman, C.; Cheng, E.; Chu, J.; Chui, C.; Drzymala, R.E.; Goitein, M.; Manolis, J.M. )
1991-05-15
Three-dimensional treatment planning has been used by four cooperating centers to prepare and analyze multiple treatment plans on two cervix cancer patients. One patient had biopsy-proven and CT-demonstrable metastasis to the para-aortic nodes, while the other was at high risk for metastatic involvement of para-aortic nodes. Volume dose distributions were analyzed, and an attempt was made to define the role of 3-D treatment planning to the para-aortic region, where moderate to high doses (50-66 Gy) are required to sterilize microscopic and gross metastasis. Plans were prepared using the 3-D capabilities for tailoring fields to the target volumes, but using standard field arrangements (3-D standard), and with full utilization of the 3-D capabilities (3-D unconstrained). In some but not all 3-D unconstrained plans, higher doses were delivered to the large nodal volume and to the volume containing gross nodal disease than in plans analyzed but not prepared with full 3-D capability (3-D standard). The small bowel was the major dose limiting organ. Its tolerance would have been exceeded in all plans which prescribed 66 Gy to the gross nodal mass, although some reduction in small bowel near-maximum dose was achieved in the 3-D unconstrained plans. All plans were able to limit doses to other normal organs to tolerance levels or less, with significant reductions seen in doses to spinal cord, kidneys, and large bowel in the 3-D unconstrained plans, as compared to the 3-D standard plans. A high probability of small bowel injury was detected in one of four 3-D standard plans prescribed to receive 50 Gy to the large para-aortic nodal volume; the small bowel dose was reduced to an acceptable level in the corresponding 3-D unconstrained plan. An optimum beam energy for treating this site was not identified, with plans using 4, 6, 10, 15, 18, and 25 MV photons all being equally acceptable. (Abstract Truncated)
NASA Astrophysics Data System (ADS)
Catelli, Francisco; Giovan, Odilon; Balen, Osvaldo; Siqueira da Silva, Fernando
2009-07-01
In this work we describe a simple optical device to project the Sun image which is useful for solar eclipses observing and for sunspots' size estimating.
Se describe un dispositivo óptico simple para proyectar la imagen del Sol, lo cual es apropiado para las observaciones de eclipses solares y para estimar las dimensiones de las manchas solares.
É descrito um dispositivo ótico simples para projetar a imagem do Sol, adequado para observações de eclipses solares e à estimativa do tamanho das manchas solares.
Kulakova, Milana A; Cook, Charles E; Andreeva, Tatiana F
2008-01-01
Background Transcription factors that encode ANTP-class homeobox genes play crucial roles in determining the body plan organization and specification of different organs and tissues in bilaterian animals. The three-gene ParaHox family descends from an ancestral gene cluster that existed before the evolution of the Bilateria. All three ParaHox genes are reported from deuterostomes and lophotrochozoans, but not to date from any ecdysozoan taxa, and there is evidence that the ParaHox genes, like the related Hox genes, were ancestrally a single chromosomal cluster. However, unlike the Hox genes, there is as yet no strong evidence that the ParaHox genes are expressed in spatial and temporal order during embryogenesis. Results We isolated fragments of the three Nereis virens ParaHox genes, then used these as probes for whole-mount in situ hybridization in larval and postlarval worms. In Nereis virens the ParaHox genes participate in antero-posterior patterning of ectodermal and endodermal regions of the digestive tract and are expressed in some cells in the segment ganglia. The expression of these genes occurs in larval development in accordance with the position of these cells along the main body axis and in postlarval development in accordance with the position of cells in ganglia along the antero-posterior axis of each segment. In none of these tissues does expression of the three ParaHox genes follow the rule of temporal collinearity. Conclusion In Nereis virens the ParaHox genes are expressed during antero-posterior patterning of the digestive system (ectodermal foregut and hindgut, and endodermal midgut) of Nereis virens. These genes are also expressed during axial specification of ventral neuroectodermal cell domains, where the expression domains of each gene are re-iterated in each neuromere except for the first parapodial segment. These expression domains are probably predetermined and may be directed on the antero-posterior axis by the Hox genes, whose
Um enfoque antropológico para o ensino de astronomia no nível médio
NASA Astrophysics Data System (ADS)
Costa, G. B.; Jafelice, L. C.
2003-08-01
Há uma enorme carência de materiais didático-pedagógicos em astronomia para professores do ensino médio, sobretudo materiais que explorem também aspectos humanísticos. A origem do Universo é um bom exemplo desta constatação central. Embora tal origem teve explicações culturais diversas, os professores não têm informações sobre isso e muito menos material que trabalhe diferentes visões de mundo e treinamento que os capacite a abordá-las devidamente. Conseqüentemente o ensino de astronomia costuma ser tecnicista e dissociado do aspecto humano que alimenta o grande interesse e curiosidade que esses temas despertam. Aqui apresentamos propostas visando contribuir para reverter esse quadro e trabalhamos distintas visões de Universo: espontâneas, autóctones e científicas. Desenvolvemos práticas, materiais instrucionais e textos para viabilizar a adoção de um enfoque antropológico para o ensino de astronomia no nível médio, no qual as culturas humanística e científica sejam integradas de uma maneira contextualizada e eficaz para aquele ensino. Estas propostas foram aplicadas em um curso de treinamento para professores da rede pública de diferentes disciplinas. A receptividade dos professores à abordagem proposta e os resultados alcançados foram muito estimulantes. Destes, destacamos: produção de roteiros de atividades; desenvolvimento de práticas didático-pedagógicas específicas (e.g., encenação de mitos; dança primordial guarani; "criação" de constelações e interpretações pluriculturais; etc.); e sugestões concretas para a efetiva realização de um ensino interdisciplinar contextualizado, onde questões cosmogônicas servem de mote para iniciar tal ensino. Discutimos estes resultados e como o enfoque adotado pode instrumentalizar os professores para leituras de mundo que incluem naturalmente aspectos culturais, sociais e históricos associados aos temas estudados. (PPGECNM/UFRN; PRONEX/FINEP; NUPA/USP; Temáticos/FAPESP)
Nakayama, Satoshi; Satou, Kunihiro; Orito, Wataru; Ogasawara, Michio
2016-07-01
The Hox and ParaHox genes of bilateria share a similar expression pattern along the body axis and are known to be associated with anterior-posterior patterning. In vertebrates, the Hox genes are also expressed in presomitic mesoderm and gut endoderm and the ParaHox genes show a restricted expression pattern in the gut-related derivatives. Regional expression patterns in the embryonic central nervous system of the basal chordates amphioxus and ascidian have been reported; however, little is known about their endodermal expression in the alimentary canal. We focus on the Hox and ParaHox genes in the ascidian Ciona intestinalis and investigate the gene expression patterns in the juvenile, which shows morphological regionality in the alimentary canal. Gene expression analyses by using whole-mount in situ hybridization reveal that all Hox genes have a regional expression pattern along the alimentary canal. Expression of Hox1 to Hox4 is restricted to the posterior region of pharyngeal derivatives. Hox5 to Hox13 show an ordered expression pattern correlated with each Hox gene number along the postpharyngeal digestive tract. This expression pattern along the anterior-posterior axis has also been observed in Ciona ParaHox genes. Our observations suggest that ascidian Hox and ParaHox clusters are dispersed; however, the ordered expression patterns along the alimentary canal appear to be conserved among chordates. PMID:26837224
Determination of the ortho to para ratio of H2Cl+ and H2O+ from submillimeter observations.
Gerin, Maryvonne; de Luca, Massimo; Lis, Dariusz C; Kramer, Carsten; Navarro, Santiago; Neufeld, David; Indriolo, Nick; Godard, Benjamin; Le Petit, Franck; Peng, Ruisheng; Phillips, Thomas G; Roueff, Evelyne
2013-10-01
The opening of the submillimeter sky with the Herschel Space Observatory has led to the detection of new interstellar molecular ions, H2O(+), H2Cl(+), and HCl(+), which are important intermediates in the synthesis of water vapor and hydrogen chloride. In this paper, we report new observations of H2O(+) and H2Cl(+) performed with both Herschel and ground-based telescopes, to determine the abundances of their ortho and para forms separately and derive the ortho-to-para ratio. At the achieved signal-to-noise ratio, the observations are consistent with an ortho-to-para ratios of 3 for both H2O(+) and H2Cl(+), in all velocity components detected along the lines-of-sight to the massive star-forming regions W31C and W49N. We discuss the mechanisms that contribute to establishing the observed ortho-to-para ratio and point to the need for a better understanding of chemical reactions, which are important for establishing the H2O(+) and H2Cl(+) ortho-to-para ratios. PMID:23869910
In-Situ Visualization Experiments with ParaView Cinema in RAGE
Kares, Robert John
2015-10-15
A previous paper described some numerical experiments performed using the ParaView/Catalyst in-situ visualization infrastructure deployed in the Los Alamos RAGE radiation-hydrodynamics code to produce images from a running large scale 3D ICF simulation. One challenge of the in-situ approach apparent in these experiments was the difficulty of choosing parameters likes isosurface values for the visualizations to be produced from the running simulation without the benefit of prior knowledge of the simulation results and the resultant cost of recomputing in-situ generated images when parameters are chosen suboptimally. A proposed method of addressing this difficulty is to simply render multiple images at runtime with a range of possible parameter values to produce a large database of images and to provide the user with a tool for managing the resulting database of imagery. Recently, ParaView/Catalyst has been extended to include such a capability via the so-called Cinema framework. Here I describe some initial experiments with the first delivery of Cinema and make some recommendations for future extensions of Cinema’s capabilities.
Semantics-based distributed I/O with the ParaMEDIC framework.
Balaji, P.; Feng, W.; Lin, H.; Mathematics and Computer Science; Virginia Tech; North Carolina State Univ.
2008-01-01
Many large-scale applications simultaneously rely on multiple resources for efficient execution. For example, such applications may require both large compute and storage resources; however, very few supercomputing centers can provide large quantities of both. Thus, data generated at the compute site oftentimes has to be moved to a remote storage site for either storage or visualization and analysis. Clearly, this is not an efficient model, especially when the two sites are distributed over a wide-area network. Thus, we present a framework called 'ParaMEDIC: Parallel Metadata Environment for Distributed I/O and Computing' which uses application-specific semantic information to convert the generated data to orders-of-magnitude smaller metadata at the compute site, transfer the metadata to the storage site, and re-process the metadata at the storage site to regenerate the output. Specifically, ParaMEDIC trades a small amount of additional computation (in the form of data post-processing) for a potentially significant reduction in data that needs to be transferred in distributed environments.
Ortho-to-para ratio in interstellar water on the sightline toward Sagittarius B2(N).
Lis, Dariusz C; Bergin, Edwin A; Schilke, Peter; van Dishoeck, Ewine F
2013-10-01
The determination of the water ortho-to-para ratio (OPR) is of great interest for studies of the formation and thermal history of water ices in the interstellar medium and protoplanetary disk environments. We present new Herschel observations of the fundamental rotational transitions of ortho- and para-water on the sightline toward Sagittarius B2(N), which allow improved estimates of the measurement uncertainties due to instrumental effects and assumptions about the excitation of water molecules. These new measurements, suggesting a spin temperature of 24-32 K, confirm the earlier findings of an OPR below the high-temperature value on the nearby sightline toward Sagittarius B2(M). The exact implications of the low OPR in the galactic center molecular gas remain unclear and will greatly benefit from future laboratory measurements involving water freeze-out and evaporation processes under low-temperature conditions, similar to those present in the galactic interstellar medium. Given the specific conditions in the central region of the Milky Way, akin to those encountered in active Galactic nuclei, gas-phase processes under the influence of strong X-ray and cosmic ray ionization also have to be carefully considered. We summarize some of the latest laboratory measurements and their implications here. PMID:23656468
Rotational relaxation of CS by collision with ortho- and para-H{sub 2} molecules
Denis-Alpizar, Otoniel; Stoecklin, Thierry Halvick, Philippe; Dubernet, Marie-Lise
2013-11-28
Quantum mechanical investigation of the rotationally inelastic collisions of CS with ortho- and para-H{sub 2} molecules is reported. The new global four-dimensional potential energy surface presented in our recent work is used. Close coupling scattering calculations are performed in the rigid rotor approximation for ortho- and para-H{sub 2} colliding with CS in the j = 0–15 rotational levels and for collision energies ranging from 10{sup −2} to 10{sup 3} cm{sup −1}. The cross sections and rate coefficients for selected rotational transitions of CS are compared with the ones previously reported for the collision of CS with He. The largest discrepancies are observed at low collision energy, below 1 cm{sup −1}. Above 10 cm{sup −1}, the approximation using the square root of the relative mass of the colliders to calculate the cross sections between a molecule and H{sub 2} from the data available with {sup 4}He is found to be a good qualitative approximation. The rate coefficients calculated with the electron gas model for the He-CS system show more discrepancy with our accurate results. However, scaling up these rates by a factor of 2 gives a qualitative agreement.
Infrapatellar Fat Pad Para-Articular Osteochondroma: A Ten-Year Follow-up and Review
Bombaci, Hasan; Bilgin, Emre
2015-01-01
Introduction: Para-articular masses are not clear enough in terms of their etiology and nomenclature. Although surgical removal of the mass is the preferred treatment, long term follow-up after surgical treatment has not been reported yet. The current study presents a patient with the osteo-cartilaginous mass of infrapatellar region, diagnosed after a trauma. This case has the longest follow-up period in the literature. Case Presentation: A 52-year-old female patient referred after falling down on her right knee. Lateral radiographs of the knee revealed a mass in the infrapatellar area. The case was treated surgically by total excision of the mass. The mass was extra-capsular with lobular and irregular shape. After mass removal the clinical course was uneventful and at the 10-year follow-up, no signs of recurrence were evident clinically or radiologically. Conclusions: Tumor-like lesions within the infrapatellar fat pad should remind the para-articular osteochondroma. Although its etiology has not yet been elicited, operative removal of the mass is the preferred treatment of choice and also curative in long-term follow-up. PMID:26566510
A non-equilibrium ortho-to-para ratio of water in the Orion PDR
NASA Astrophysics Data System (ADS)
Choi, Y.; van der Tak, F. F. S.; Bergin, E. A.; Plume, R.
2014-12-01
Context. The ortho-to-para ratio (OPR) of H2O is thought to be sensitive to the temperature of water formation. The OPR of H2O is thus useful for studying the formation mechanism of water. Aims: We investigate the OPR of water in the Orion PDR (photon-dominated region), at the Orion Bar and Orion S positions, using data from Herschel/HIFI. Methods: We detect the ground-state lines of ortho- and para-H218O in the Orion Bar and Orion S and estimate the column densities using local thermodynamical equilibrium (LTE) and non-LTE methods. Results: Based on our calculations, the OPR in the Orion Bar is 0.1-0.5, which is unexpectedly low given the gas temperature of ~85 K, and also lower than the values measured for other interstellar clouds and protoplanetary disks. Toward Orion S, our OPR estimate is below 2. Conclusions: This low OPR at 2 positions in the Orion PDR is inconsistent with gas phase formation and with thermal evaporation from dust grains, but it may be explained by photodesorption. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.Appendices are available in electronic form at http://www.aanda.org
O-Methylation of Chlorinated para-Hydroquinones by Rhodococcus chlorophenolicus
Häggblom, Max M.; Apajalahti, Juha H. A.; Salkinoja-Salonen, Mirja S.
1988-01-01
Rhodococcus chlorophenolicus PCP-I, a degrader of polychlorinated phenols, guaiacols (2-methoxyphenols), and syringols (2,6-dimethoxyphenols), was shown to O-methylate the degradation intermediate, a chlorinated para-hydroquinone, into 4-methoxyphenol. O-methylation was constitutively expressed, whereas the degradation of chlorophenols and chlorohydroquinones was inducible in R. chlorophenolicus. The O-methylating reaction required two hydroxyl groups in positions para to each other. R. chlorophenolicus selectively methylated the hydroxyl group flanked by two chlorine substituents. Tetrachlorohydroquinone, trichlorohydroquinone, and 2,6-dichlorohydroquinone were methylated into tetrachloro-4-methoxyphenol, 2,3,5-trichloro-4-methoxyphenol, and 3,5-dichloro-4-methoxyphenol, respectively. Chlorohydroquinones with only one chlorine adjacent to a hydroxyl group were methylated only in trace amounts, and no metabolite was formed from hydroquinone. The degradation intermediates formed in hydroxylation of tetrachloroguaiacol and trichlorosyringol by R. chlorophenolicus were O-methylated into two isomeric trichlorodimethoxyphenols and two isomeric dichlorotrimethoxyphenols, respectively. R. chlorophenolicus also degraded the polychlorinated methylation products (tetrachlorinated and trichlorinated 4-methoxyphenols), but not mono- and dichlorinated 4-methoxyphenols. PMID:16347691
Comparing the Well-Being of Para and Olympic Sport Athletes: A Systematic Review.
Macdougall, Hannah; O'Halloran, Paul; Shields, Nora; Sherry, Emma
2015-07-01
This systematic review included 12 studies that compared the well-being of Para and Olympic sport athletes. Meta-analyses revealed that Para athletes, compared with Olympic sport athletes, had lower levels of self-acceptance, indicated by athletic identity, d = 0.47, 95% confidence interval (CI) [0.77, 0.16], and body-image perceptions, d = 0.33, 95% CI [0.59, 0.07], and differed from Olympic sport athletes in terms of their motivation, indicated by a greater mastery-oriented climate, d = 0.74, 95% CI [0.46, 1.03]. Given an inability to pool the remaining data for meta-analysis, individual standardized mean differences were calculated for other dimensions of psychological and subjective well-being. The results have implications for professionals and coaches aiming to facilitate the well-being needs of athletes under their care. Future research would benefit from incorporating established models of well-being based on theoretical rationale combined with rigorous study designs. PMID:26113553
Resonances in the reaction ortho- and para- D2 + H at temperatures below 10 K
NASA Astrophysics Data System (ADS)
Simbotin, I.; Côté, R.
2016-05-01
In a previous study we reported cross sections for the reaction H2 + D in the temperature regime 10-6 < T < 10 K, and found pronounced shape resonances, especially in the p and d partial waves. We found that the resonant structures were sensitive to the initial rovibrational state of H2; in particular, we showed that the effect of the nuclear-spin symmetry was very important, since ortho- and para- H2 gave significantly different results. We now investigate the reaction D2 + H for vibrationally excited ortho- and para- D2, and compare and contrast these results with those for H2 + D. We remark that this benchmark system is a prototypical example of reactions with a strong barrier, which have very small cross sections in the cold and ultracold regimes. However, shape resonances can enhance the reaction cross sections by orders of magnitude for temperatures around and below T = 1 K. Moreover, resonant features would provide stringent tests for quantum chemistry calculations of potential energy surfaces. Partial support from the US Army Research Office (Grant No. W911NF-13-1-0213).
Effects of acoustic feedback training in elite-standard Para-Rowing.
Schaffert, Nina; Mattes, Klaus
2015-01-01
Assessment and feedback devices have been regularly used in technique training in high-performance sports. Biomechanical analysis is mainly visually based and so can exclude athletes with visual impairments. The aim of this study was to examine the effects of auditory feedback on mean boat speed during on-water training of visually impaired athletes. The German National Para-Rowing team (six athletes, mean ± s, age 34.8 ± 10.6 years, body mass 76.5 ± 13.5 kg, stature 179.3 ± 8.6 cm) participated in the study. Kinematics included boat acceleration and distance travelled, collected with Sofirow at two intensities of training. The boat acceleration-time traces were converted online into acoustic feedback and presented via speakers during rowing (sections with and without alternately). Repeated-measures within-participant factorial ANOVA showed greater boat speed with acoustic feedback than baseline (0.08 ± 0.01 m·s(-1)). The time structure of rowing cycles was improved (extended time of positive acceleration). Questioning of athletes showed acoustic feedback to be a supportive training aid as it provided important functional information about the boat motion independent of vision. It gave access for visually impaired athletes to biomechanical analysis via auditory information. The concept for adaptive athletes has been successfully integrated into the preparation for the Para-Rowing World Championships and Paralympics. PMID:25105858
Chaurasia, Akhilesh Kumar; Tremblay, Pier-Luc; Holmes, Dawn E; Zhang, Tian
2015-10-01
Two pathways for para-cresol (p-cresol) degradation by anaerobic bacteria have been elucidated; one involves fumarate addition at the methyl group of p-cresol by a hydroxylbenzylsuccinate synthase protein while the other utilizes a methylhydroxylase protein (PCMH) to catalyze hydroxylation of the methyl group of p-cresol. In Geobacter metallireducens, in vitro enzymatic assays showed that p-cresol is degraded via the methylhydroxylation pathway. However, prior to this study these results had not been confirmed by genetic analyses. In this work, the gene coding for benzylsuccinate-CoA dehydrogenase (bbsG), an enzyme required for toluene degradation by G. metallireducens that is homologous to the p-hydroxybenzylsuccinyl-CoA dehydrogenase involved in p-cresol degradation by Desulfobacula toluolica Tol2 via fumarate addition, and the gene encoding the alpha prime subunit of PCMH (pcmI), were deleted to investigate the possibility of co-existing p-cresol degradation pathways in G. metallireducens. The absence of a functional PcmI protein completely inhibited p-cresol degradation, while deletion of the bbsG gene had little impact. These results further support the observation that G. metallireducens utilizes a PCMH-initiated pathway for p-cresol degradation. PMID:26316547
Cao, Yang; Chen, Zhong-Jian; Jiang, Hui-Di; Chen, Jian-Zhong
2014-01-16
Catechol-O-methyltransferase (COMT, EC 2.1.1.6) plays a central role in the inactivation of neurotransmitters sharing a catecholic motif by transferring a methyl group from AdoMet. Methylation of the meta-hydroxyl is much more common than that of the para-hydroxyl in many COMT substrates, such as dopamine and norepinephrine. Our experimental data showed that quercetin preferred meta-methylation but luteolin favored a para-methylation. To elucidate the mechanism for different preferences of methylations of quercetin and luteolin, we performed a theoretical investigation on the different regioseletivities of COMT-catalyzed methylations for quercetin and luteolin by a combined approach of MD simulations, ab initio calculations, and QM/MM computations. The ab initio calculation results showed that both quercetin and luteolin have more negative charge distributions on the meta-O atom than the para-O atom, which indicated that meta-O preferred SN2 reaction for their methylation. Our QM/MM computations also confirmed that these two flavonoids have lower reaction energetic barriers for COMT-catalyzed meta-O-methylation than para-O-methylation. On the other hand, our binding free energy computation results indicated that quercetin has a more stable binding mode for meta-O-methylation than para-O-methylation but luteolin has a more stable binding mode for para-O-methylation than meta-O-methylation. We gave a comprehensive explanation considering both thermodynamics and reaction kinetics aspects and discussed the protein-inhibitor interactions as well as the O-methylation mechanism in our present work. PMID:24354565
Gauchat, Dominique; Mazet, Françoise; Berney, Cédric; Schummer, Michèl; Kreger, Sylvia; Pawlowski, Jan; Galliot, Brigitte
2000-01-01
The conservation of developmental functions exerted by Antp-class homeoproteins in protostomes and deuterostomes suggested that homologs with related functions are present in diploblastic animals. Our phylogenetic analyses showed that Antp-class homeodomains belong either to non-Hox or to Hox/paraHox families. Among the 13 non-Hox families, 9 have diploblastic homologs, Msx, Emx, Barx, Evx, Tlx, NK-2, and Prh/Hex, Not, and Dlx, reported here. Among the Hox/paraHox, poriferan sequences were not found, and the cnidarian sequences formed at least five distinct cnox families. Two are significantly related to the paraHox Gsx (cnox-2) and the mox (cnox-5) sequences, whereas three display some relatedness to the Hox paralog groups 1 (cnox-1), 9/10 (cnox-3) and the paraHox cdx (cnox-4). Intermediate Hox/paraHox genes (PG 3 to 8 and lox) did not have clear cnidarian counterparts. In Hydra, cnox-1, cnox-2, and cnox-3 were not found chromosomally linked within a 150-kb range and displayed specific expression patterns in the adult head. During regeneration, cnox-1 was expressed as an early gene whatever the polarity, whereas cnox-2 was up-regulated later during head but not foot regeneration. Finally, cnox-3 expression was reestablished in the adult head once it was fully formed. These results suggest that the Hydra genes related to anterior Hox/paraHox genes are involved at different stages of apical differentiation. However, the positional information defining the oral/aboral axis in Hydra cannot be correlated strictly to that characterizing the anterior–posterior axis in vertebrates or arthropods. PMID:10781050
Uma grade de perfis teóricos para estrelas massivas em transição
NASA Astrophysics Data System (ADS)
Nascimento, C. M. P.; Machado, M. A.
2003-08-01
Na XXVIII Reunião Anual da Sociedade Astronômica Brasileira (2002) apresentamos uma grade de perfis calculados de acordo com os pontos da trajetória evolutiva de metalicidade solar, Z = 0.02 e taxa de perda de massa () padrão, para estrelas com massa inicial de 25, 40, 60, 85 e 120 massas solares. Estes perfis foram calculados com o auxílio de um código numérico adequado para descrever os ventos de objetos massivos, supondo simetria esférica, estacionaridade e homogeneidade. No presente trabalho, apresentamos a complementação da grade com os perfis teóricos relativos às trajetórias de Z = 0.02 com taxa de perda de massa dobrada em relação a padrão (2´), e de metalicidade Z = 0.008. Para cada ponto das três trajetórias obtemos os perfis teóricos de Ha, Hb, Hg e Hd, e como esperado eles se apresentam em pura emissão, pura absorção ou em P-Cygni. Para valores de taxa de perda de massa muito baixos (~10-7) não há formação de linhas, o que é visto nos primeiros pontos em todas as trajetórias. Em geral, para um mesmo ponto a componente de emissão diminui e a absorção aumenta de Ha para Hd. É verificado que as trajetórias com Z = 0.02 e padrão possuem menos circuitos (loops) do que as com metalicidade Z = 0.02 e 2´ padrão, e seus perfis são, em geral, menos intensos. Em relação a trajetória de Z = 0.008, verifica-se menos circuitos e maior variação em luminosidade, e seus perfis mostram-se em, algumas trajetórias, mais intensos. Verificamos também que, pontos distintos em uma mesma trajetória, apresentam perfis diferentes para valores similares de luminosidade e temperatura efetiva. Sendo assim, uma grade de perfis teóricos parece ser útil para fornecer uma informação preliminar sobre o estágio evolutivo de uma estrela massiva.
Chang, J.C.S.; Krebs, K.A.
1992-01-01
The paper reports results of dynamic and static chamber tests to evaluate para-dichlorobenzene emission rates from mothcakes. The data were analyzed by a model that assumes that the emission rate is controlled by gas-phase mass transfer. Results indicate that the para-dichlorobenzene emission from mothcakes is a temperature-sensitive sublimation process. Full-scale house tests were also conducted to measure mass transfer coefficients based on the model developed. The values of the mass transfer coefficient obtained are very comparable to those estimated by theoretical heat transfer studies.
Sutherland, Liese -Marie; Knudson, James N.; Mocko, Michal; Renneke, Richard M.
2015-12-17
An experiment was designed and developed to prototype a fiber-optic-based laser system, which measures the ratio of ortho-hydrogen to para-hydrogen in an operating neutron moderator system at the Los Alamos Neutron Science Center (LANSCE) spallation neutron source. Preliminary measurements resulted in an ortho to para ratio of 3.06:1, which is within acceptable agreement with the previously published ratio. As a result, the successful demonstration of Raman Spectroscopy for this measurement is expected to lead to a practical method that can be applied for similar in-situ measurements at operating neutron spallation sources.
NASA Astrophysics Data System (ADS)
Teshigawara, M.; Harada, M.; Tatsumoto, H.; Aso, T.; Ohtsu, K.; Takada, H.; Futakawa, M.; Ikeda, Y.
2016-02-01
By sampling gaseous hydrogen from a circulating liquid hydrogen loop for Laser Raman spectroscopy, we measured the para-/ortho-hydrogen fractions in liquid hydrogen under neutron irradiation for the first time to identify whether irradiated hydrogen has an elevated ortho-hydrogen fraction. This measurement indicates that para-hydrogen equilibrium persists at 300 kW proton power in the presence of an iron(III) oxide hydroxide [Fe(OH)3] catalyst. The measurements will be repeated as the power at the Japan Proton Accelerator Research Complex (J-PARC) increases to the MW level.
NASA Astrophysics Data System (ADS)
Sutherland, Liese-Marie; Knudson, James N.; Mocko, Michal; Renneke, Richard M.
2016-02-01
An experiment was designed and developed to prototype a fiber-optic-based laser system, which measures the ratio of ortho-hydrogen to para-hydrogen in an operating neutron moderator system at the Los Alamos Neutron Science Center (LANSCE) spallation neutron source. Preliminary measurements resulted in an ortho to para ratio of 3.06:1, which is within acceptable agreement with the previously published ratio. The successful demonstration of Raman Spectroscopy for this measurement is expected to lead to a practical method that can be applied for similar in-situ measurements at operating neutron spallation sources.
Metabolism of Doubly para-Substituted Hydroxychlorobiphenyls by Bacterial Biphenyl Dioxygenases
Pham, Thi Thanh My; Sondossi, Mohammad
2015-01-01
In this work, we examined the profile of metabolites produced from the doubly para-substituted biphenyl analogs 4,4′-dihydroxybiphenyl, 4-hydroxy-4′-chlorobiphenyl, 3-hydroxy-4,4′-dichlorobiphenyl, and 3,3′-dihydroxy-4,4′-chlorobiphenyl by biphenyl-induced Pandoraea pnomenusa B356 and by its biphenyl dioxygenase (BPDO). 4-Hydroxy-4′-chlorobiphenyl was hydroxylated principally through a 2,3-dioxygenation of the hydroxylated ring to generate 2,3-dihydro-2,3,4-trihydroxy-4′-chlorobiphenyl and 3,4-dihydroxy-4′-chlorobiphenyl after the removal of water. The former was further oxidized by the biphenyl dioxygenase to produce ultimately 3,4,5-trihydroxy-4′-chlorobiphenyl, a dead-end metabolite. 3-Hydroxy-4,4′-dichlorobiphenyl was oxygenated on both rings. Hydroxylation of the nonhydroxylated ring generated 2,3,3′-trihydroxy-4′-chlorobiphenyl with concomitant dechlorination, and 2,3,3′-trihydroxy-4′-chlorobiphenyl was ultimately metabolized to 2-hydroxy-4-chlorobenzoate, but hydroxylation of the hydroxylated ring generated dead-end metabolites. 3,3′-Dihydroxy-4,4′-dichlorobiphenyl was principally metabolized through a 2,3-dioxygenation to generate 2,3-dihydro-2,3,3′-trihydroxy-4,4′-dichlorobiphenyl, which was ultimately converted to 3-hydroxy-4-chlorobenzoate. Similar metabolites were produced when the biphenyl dioxygenase of Burkholderia xenovorans LB400 was used to catalyze the reactions, except that for the three substrates used, the BPDO of LB400 was less efficient than that of B356, and unlike that of B356, it was unable to further oxidize the initial reaction products. Together the data show that BPDO oxidation of doubly para-substituted hydroxychlorobiphenyls may generate nonnegligible amounts of dead-end metabolites. Therefore, biphenyl dioxygenase could produce metabolites other than those expected, corresponding to dihydrodihydroxy metabolites from initial doubly para-substituted substrates. This finding shows that a clear
Metabolism of Doubly para-Substituted Hydroxychlorobiphenyls by Bacterial Biphenyl Dioxygenases.
Pham, Thi Thanh My; Sondossi, Mohammad; Sylvestre, Michel
2015-07-01
In this work, we examined the profile of metabolites produced from the doubly para-substituted biphenyl analogs 4,4'-dihydroxybiphenyl, 4-hydroxy-4'-chlorobiphenyl, 3-hydroxy-4,4'-dichlorobiphenyl, and 3,3'-dihydroxy-4,4'-chlorobiphenyl by biphenyl-induced Pandoraea pnomenusa B356 and by its biphenyl dioxygenase (BPDO). 4-Hydroxy-4'-chlorobiphenyl was hydroxylated principally through a 2,3-dioxygenation of the hydroxylated ring to generate 2,3-dihydro-2,3,4-trihydroxy-4'-chlorobiphenyl and 3,4-dihydroxy-4'-chlorobiphenyl after the removal of water. The former was further oxidized by the biphenyl dioxygenase to produce ultimately 3,4,5-trihydroxy-4'-chlorobiphenyl, a dead-end metabolite. 3-Hydroxy-4,4'-dichlorobiphenyl was oxygenated on both rings. Hydroxylation of the nonhydroxylated ring generated 2,3,3'-trihydroxy-4'-chlorobiphenyl with concomitant dechlorination, and 2,3,3'-trihydroxy-4'-chlorobiphenyl was ultimately metabolized to 2-hydroxy-4-chlorobenzoate, but hydroxylation of the hydroxylated ring generated dead-end metabolites. 3,3'-Dihydroxy-4,4'-dichlorobiphenyl was principally metabolized through a 2,3-dioxygenation to generate 2,3-dihydro-2,3,3'-trihydroxy-4,4'-dichlorobiphenyl, which was ultimately converted to 3-hydroxy-4-chlorobenzoate. Similar metabolites were produced when the biphenyl dioxygenase of Burkholderia xenovorans LB400 was used to catalyze the reactions, except that for the three substrates used, the BPDO of LB400 was less efficient than that of B356, and unlike that of B356, it was unable to further oxidize the initial reaction products. Together the data show that BPDO oxidation of doubly para-substituted hydroxychlorobiphenyls may generate nonnegligible amounts of dead-end metabolites. Therefore, biphenyl dioxygenase could produce metabolites other than those expected, corresponding to dihydrodihydroxy metabolites from initial doubly para-substituted substrates. This finding shows that a clear picture of the fate of polychlorinated
Shinnaka, Yoshiharu; Kawakita, Hideyo; Kobayashi, Hitomi; Boice, Daniel C.; Martinez, Susan E.
2012-04-20
The ortho-to-para abundance ratio (OPR) of cometary molecules is considered to be one of the primordial characteristics of cometary ices, and contains information concerning their formation. Water is the most abundant species in cometary ices, and OPRs of water in comets have been determined from infrared spectroscopic observations of H{sub 2}O rovibrational transitions so far. In this paper, we present a new method to derive OPR of water in comets from the high-dispersion spectrum of the rovibronic emission of H{sub 2}O{sup +} in the optical wavelength region. The rovibronic emission lines of H{sub 2}O{sup +} are sometimes contaminated by other molecular emission lines but they are not affected seriously by telluric absorption compared with near-infrared observations. Since H{sub 2}O{sup +} ions are mainly produced from H{sub 2}O by photoionization in the coma, the OPR of H{sub 2}O{sup +} is considered to be equal to that of water based on the nuclear spin conservation through the reaction. We have developed a fluorescence excitation model of H{sub 2}O{sup +} and applied it to the spectrum of comet C/2001 Q4 (NEAT). The derived OPR of water is 2.54{sup +0.32}{sub -0.25}, which corresponds to a nuclear spin temperature (T{sub spin}) of 30{sup +10}{sub -4} K. This is consistent with the previous value determined in the near-infrared for the same comet (OPR = 2.6 {+-} 0.3, T{sub spin} = 31{sup +11}{sub -5} K).
Statistical ortho-to-para ratio of water desorbed from ice at 10 kelvin
NASA Astrophysics Data System (ADS)
Hama, Tetsuya; Kouchi, Akira; Watanabe, Naoki
2016-01-01
The anomalously low ortho-to-para ratios (OPRs) exhibited by gaseous water in space have been used to determine the formation temperature (<50 kelvin) of ice on cold interstellar dust. This approach assumes that the OPR of water desorbed from ice is related to the ice formation temperature on the dust. However, we report that water desorbed from ice at 10 kelvin shows a statistical high-temperature OPR of 3, even when the ice is produced in situ by hydrogenation of O2, a known formation process of interstellar water. This invalidates the assumed relation between OPR and temperature. The necessary reinterpretation of the low OPRs will help elucidate the chemical history of interstellar water from molecular clouds and processes in the early solar system, including comet formation.
Parallel Grand Canonical Monte Carlo (ParaGrandMC) Simulation Code
NASA Technical Reports Server (NTRS)
Yamakov, Vesselin I.
2016-01-01
This report provides an overview of the Parallel Grand Canonical Monte Carlo (ParaGrandMC) simulation code. This is a highly scalable parallel FORTRAN code for simulating the thermodynamic evolution of metal alloy systems at the atomic level, and predicting the thermodynamic state, phase diagram, chemical composition and mechanical properties. The code is designed to simulate multi-component alloy systems, predict solid-state phase transformations such as austenite-martensite transformations, precipitate formation, recrystallization, capillary effects at interfaces, surface absorption, etc., which can aid the design of novel metallic alloys. While the software is mainly tailored for modeling metal alloys, it can also be used for other types of solid-state systems, and to some degree for liquid or gaseous systems, including multiphase systems forming solid-liquid-gas interfaces.
Searching for Auxetics with DYNA3D and ParaDyn
Hoover, W G; Hoover, C G
2004-09-11
We sought to simulate auxetic behavior by carrying out dynamic analyses of mesoscopic model structures. We began by generating nearly periodic cellular structures. Four-node 'Shell' elements and eight-node 'Brick' elements are the basic building blocks for each cell. The shells and bricks obey standard elastic-plastic continuum mechanics. The dynamical response of the structures was next determined for a three-stage loading process: (1) homogeneous compression; (2) viscous relaxation; (3) uniaxial compression. The simulations were carried out with both serial and parallel computer codes--DYNA3D and ParaDyn--which describe the deformation of the shells and bricks with a robust contact algorithm. We summarize the results found here.
Theoretical and Experimental Studies on the Nonlinear Optical Chromophore para Bromoacetanilide
NASA Astrophysics Data System (ADS)
Jothy, V. Bena; Vijayakumar, T.; Jayakumar, V. S.; Udayalekshmi, K.; Ramamurthy, K.; Joe, I. Hubert
2008-11-01
Vibrational spectral analysis of the hydrogen bonded non-linear optical (NLO) material para Bromo Acetanilide (PBA) is carried out using NIR FT-Raman and FT-IR spectroscopy. Ab initio molecular orbital computations have been performed at HF/6-31G(d) level to derive equilibrium geometry, vibrational wavenumbers, intensities and first hyperpolarizability. The lowering of the imino stretching wavenumbers suggests the existence of strong intermolecular N-H⋯O hydrogen bonding substantiated by the natural bond orbital (NBO) analysis. Blue shifting CH stretching wavenumbers, simultaneous activation of carbonyl stretching mode and the strong activation of low wavenumber H-bond stretching vibrations shows the presence of intramolecular charge transfer in the molecule.
NASA Astrophysics Data System (ADS)
Gu, Ruxi; Yu, Junrong; Hu, Chengcheng; Chen, Lei; Zhu, Jing; Hu, Zuming
2012-10-01
This paper is focused on influence of argon dielectric barrier discharge (DBD) plasma on the adhesive performance and wettability of para-aramid fibers and three parameters including treated power, exposure time and argon flux were detected. The interfacial shear strength (IFSS) was greatly increased by 28% with 300 W, 60 s, 2 L min-1 argon flux plasma treatment. The content of oxygen atom and oxygen-containing polar functional groups were enhanced after the argon plasma treated, so as the surface roughness, which contributed to the improvement of surface wettability and the decrease of contact angle with water. However, long-time exposure, exorbitant power or overlarge argon flux could partly destroy the prior effects of the treatment and damage the mechanical properties of fibers to some degree.
Food for Life / Comida para la Vida: creating a food festival to raise diabetes awareness.
Lancaster, Kristie; Walker, Willie; Vance, Thomas; Kaskel, Phyllis; Arniella, Guedy; Horowitz, Carol
2009-01-01
African and Latino Americans have higher rates of diabetes and its complications than White Americans. Identifying people with undiagnosed diabetes and helping them obtain care can help to prevent complications and mortality. To kick off a screening initiative, our community-academic partnership created the "Food for Life Festival," or "Festival Comida para la Vida." This article will describe the community's perspective on the Festival, which was designed to screen residents, and demonstrate that eating healthy can be fun, tasty, and affordable in a community-centered, culturally consonant setting. More than 1,000 residents attended the event; 382 adults were screened for diabetes, and 181 scored as high risk. Fifteen restaurants distributed free samples of healthy versions of their popular dishes. Community residents, restaurateurs, and clinicians commented that the event transformed many of their preconceived ideas about healthy foods and patient care. PMID:20097997
NASA Technical Reports Server (NTRS)
Fewell, L. L.
1976-01-01
Analysis of the volatiles and sublimate produced when para-polyphenylene is pyrolyzed to constant weight under vacuum in the temperature range from 380 to 1000 C indicates that the polymer undergoes thermal degradation in two stages. The first stage involved dehydrohalogenation, which is essentially a curing reaction that produces crosslinking between polyphenylene chains resulting from the loss of chlorine from the polymer in the form of hydrogen chloride. The second stage of the thermal degradation is dehydrogenation because hydrogen is the major volatile species. Increasing amounts of polycyclic aromatic hydrocarbons (phenanthrene and 9, 10 benzphenanthrene) in the sublimate, concomitant with increasing C/H ratios of the polymeric residue with pyrolysis temperature, is consistent with the buildup of polynuclear structures in the polymer matrix.
Study and manufacture of a para-/ortho-hydrogen catalytic converter for a space cryostat
NASA Astrophysics Data System (ADS)
Baston, A. H.; Bradshaw, T. W.; Butler, G.; Clark, N. S.; Chadwick, A. T.; Harris, D. H. C.; Leach, F.; Norris, J. O. W.; Price, D.
1986-01-01
The design and optimization of a para-/ortho-hydrogen converter to increase the efficiency and lifetime of the hydrogen cryogenic system of the ISO project are described. Catalyst technology and associated heat transfer technology is evaluated. Four catalyst systems were characterized. Their catalytic activity under the orbital conditions anticipated for the three radiation shields of ISO are reported. Results from experiments on in situ deactivation and reactivation are given, indicating that this is a key parameter. Iron oxide gel is the most promising catalyst system. A full scale prototype converter was designed to ESTEC specifications, and three converters were manufactured and tested. Performance, except for two small details, meets or exceeds specification. Plans for the development and testing of flight unit converters are proposed.
Beard dermatitis due to para-phenylenediamine use in Arabic men.
Hsu, T S; Davis, M D; el-Azhary, R; Corbett, J F; Gibson, L E
2001-05-01
The most common active ingredient in hair coloring is para-phenylenediamine (PPDA), which can produce contact dermatitis, particularly in persons who dye their scalp hair and in hairdressers. We have identified another group of patients also at risk, namely men from Arab countries, who commonly grow beards and dye them. We searched the computerized patient database at the Mayo Clinic for patients with beard dermatitis associated with dye use. Eight Arabic men presented to the Mayo Clinic between 1994 and 1999 with beard dermatitis and a positive patch test to PPDA. The lesions were described as pruritic, erythematous, papular eruptions that developed in the jaw area after each application of beard dye. The symptoms subsided after the patients discontinued use of the PPDA-containing dye and received treatment with topical corticosteroids. Allergic contact dermatitis in the beard area due to PPDA occurs in Arabic men as a result of their propensity to dye their beards. PMID:11312440
Perspectivas Futuras para o Observatório do Pico dos Dias
NASA Astrophysics Data System (ADS)
Bruch, Albert
2004-02-01
Com o Observatório Gemini plenamente operacional e o telescópio SOAR iniciando suas operações em breve, a astronomia observacional brasileira encontra-se no auge de uma transformação profunda que terá um impacto grave no Observatório do Pico dos Dias - OPD. Refletimos aqui sobre a natureza desse impacto e estratégias para manter a competitividade do OPD. Não queremos apresentar receitas prontas, mas idéias que poderão servir como base de discussão sobre o uso inteligente dos telescópios do OPD como parte do conjunto de instrumentos disponíveis à comunidade astronômica brasileira.
Applicability of the ParaDNA(®) Screening System to Seminal Samples.
Tribble, Nicholas D; Miller, Jamie A D; Dawnay, Nick; Duxbury, Nicola J
2015-05-01
Seminal fluid represents a common biological material recovered from sexual assault crime scenes. Such samples can be prescreened using different techniques to determine cell type and relative amount before submitting for full STR profiling. The ParaDNA(®) Screening System is a novel forensic test which identifies the presence of DNA through amplification and detection of two common STR loci (D16S539 and TH01) and the Amelogenin marker. The detection of the Y allele in samples could provide a useful tool in the triage and submission of sexual assault samples by enforcement authorities. Male template material was detected on a range of common sexual assault evidence items including cotton pillow cases, condoms, swab heads and glass surfaces and shows a detection limit of 1 in 1000 dilution of neat semen. These data indicate this technology has the potential to be a useful tool for the detection of male donor DNA in sexual assault casework. PMID:25739746
Transient effects and pump depletion in stimulated Raman scattering. [Para-hydrogen
Carlsten, J.L.; Wenzel, R.G.; Druehl, K.
1983-01-01
Stimulated rotational Raman scattering in a 300-K multipass cell filled with para-H/sub 2/ with a single-mode CO/sub 2/-pumped laser is studied using a frequency-narrowed optical parametric oscillator (OPO) as a probe laser at the Stokes frequency for the S/sub 0/(O) transition. Amplification and pump depletion are examined as a function of incident pump energy. The pump depletion shows clear evidence of transient behavior. A theoretical treatment of transient stimulated Raman scattering, including effects of both pump depletion and medium saturation is presented. In a first approximation, diffraction effects are neglected, and only plane-wave interactions are considered. The theoretical results are compared to the experimental pulse shapes.
A Very Rare Cause of a Relapsing Para-Oesophageal Abscess
Wespi, Simon Peter; Frei, Remus; Sulz, Michael Christian
2016-01-01
Oesophageal involvement in Crohn's disease (CD) is uncommon and most often accompanied by involvement of more distal parts. Its presentation is mostly non-specific, and therefore a diagnosis, especially in isolated oesophageal disease, is difficult. We present the case of a 42-year-old male patient who was referred to our gastroenterology department because of a para-oesophageal abscess. Under antibiotic treatment the abscess healed, but despite great diagnostic efforts, its aetiology remained unclear. Three years later the patient was hospitalized again because of an abscess at the same site. Endoscopy showed disseminated ulcerations of the lower oesophagus, raising suspicion of CD. After excluding other possible causes, we made the diagnosis of isolated CD of the oesophagus. We review the available literature on this topic and discuss the clinical presentation, symptoms, endoscopic findings, and histology as well as treatment of oesophageal CD. PMID:27403115
Proyecto para la medición sistemática de seeing en CASLEO
NASA Astrophysics Data System (ADS)
Fernández Lajus, E.; Forte, J. C.
La calidad del seeing astronómico es ciertamente uno de los parámetros mas importantes que caracterizan el sitio de un observatorio. Por tanto se desea determinar si el alto valor de seeing observado con el telescopio de 2.15 m se debe a efectos internos y/o del entorno a la cupula o si se debe simplemente al seeing propio del lugar. El actual mecanismo de refrigeración del espejo primario del 2.15, parece haber mejorado notablemente la calidad del seeing. Sin embargo se hace necesario saber hasta que punto el valor del seeing puede ser mejorado. La primera etapa del proyecto consistió en la puesta a punto del telescopio emplazado para este propósito y la adquisición de las primeras medidas tentativas de seeing.
Ortho/para ratio of H2O+ toward Sagittarius B2(M) revisited.
Schilke, Peter; Lis, Dariusz C; Bergin, Edwin A; Higgins, Ronan; Comito, Claudia
2013-10-01
The HIFI instrument aboard the Herschel satellite has allowed the observation and characterization of light hydrides, the building blocks of interstellar chemistry. In this article, we revisit the ortho/para ratio for H2O(+) toward the Sgr B2(M) cloud core. The line of sight toward this star forming region passes through several spiral arms and the gas in the Bar potential in the inner Galaxy. In contrast to earlier findings, which used fewer lines to constrain the ratio, we find a ratio of 3, which is uniformly consistent with high-temperature formation of the species. In view of the reactivity of this ion, this matches the expectations. PMID:23713712
Conformational study of a single molecule of poly para phenylene ethynylenes in dilute solutions
NASA Astrophysics Data System (ADS)
Maskey, Sabina; Pierce, Flint; Perahia, Dvora; Grest, Gary S.
2011-06-01
The conformation of single molecules of dialkyl poly para phenylene ethynylenes (PPEs), electro-active polymers, is studied in solutions using molecular dynamics simulations. The conformation of conjugated polymers affects their electro-optical properties and therefore is critical to their current and potential uses, though only limited theoretical knowledge is available regarding the factors that control their configuration. The present study investigates the affects of molecular parameters including molecular weight of the polymer and chemical structure of the side chains of PPEs in different solvents on the conformation of the polymers. The PPEs are modeled atomistically where the solvents are modeled both implicitly and explicitly. The study finds that PPEs assume extended configuration which is affected by the length of the polymer backbone and the nature and length of substituting side chains. While the polymer remains extended, local dynamics is retained and no long range correlations are observed within the backbone. The results are compared with scattering experiments.
Single strand dna breaks in human lymphocytes exposed to para-phenylenediamine and its derivatives.
Chye, Soi Mei; Hseu, You Cheng; Liang, Shih-Hsiung; Chen, Chin-Hui; Chen, Ssu Ching
2008-01-01
Para-Phenylenediamine (PPD), the main aromatic amines used in the hair dye formation, and its four derivatives (2-chloro-p-phenylenediamine, 4-chloro-o-phenylenediamine, 2-nitro-p-phenylenediamine, and 4-nitro-o-phenylenediamine) were examined for their potential to produce single strand DNA breaks in human lymphocytes using the alkaline comet assay. Results revealed that all the tested chemicals within the range of doses from 100 microM to 500 microM showed the genotoxicity in a dose-dependent manner after the incubation of lymphocytes with these chemicals for 2 h. In this study, we first reported that PPD and its four derivatives can elicit the type of single strand breaks in human lymphocytes. PMID:18058049
Properties of single crystal para-terphenyl as medium for high resolution TOF detector
NASA Astrophysics Data System (ADS)
De Gerone, M.; Biasotti, M.; Ceriale, V.; Corsini, D.; Gatti, F.; Orlando, A.; Pizzigoni, G.
2016-07-01
In the last years organic scintillators have been largely investigated in order to achieve high light yield together with good time response. Pure organic compound with high quality crystalline structure can achieve both this goals. Among a large type of organic compound, para-terphenyl (C18H14) have proven to have practical applications as detector medium for particle physics. In this work, the characterization of different sizes high quality mono-crystal p-terphenyl samples is presented. The optical and scintillation properties (emission spectrum, light yield, attenuation length, and decay time) are investigated. Coupling a Silicon PhotoMultiplier-based readout system to the crystal, a small prototype for a high resolution TOF detector was built; the preliminary results, obtained on a 20×30×3 mm3 sample, with dual-side read-out (Hamamatsu S10931-050P SiPMs) and irradiated with 90Sr source, show a time resolution of 35 ps.
Coordination nano-space as stage of hydrogen ortho–para conversion
Kosone, Takashi; Hori, Akihiro; Nishibori, Eiji; Kubota, Yoshiki; Mishima, Akio; Ohba, Masaaki; Tanaka, Hiroshi; Kato, Kenichi; Kim, Jungeun; Real, José Antonio; Kitagawa, Susumu; Takata, Masaki
2015-01-01
The ability to design and control properties of nano-sized space in porous coordination polymers (PCPs) would provide us with an ideal stage for fascinating physical and chemical phenomena. We found an interconversion of nuclear-spin isomers for hydrogen molecule H2 adsorbed in a Hofmann-type PCP, {Fe(pz)[Pd(CN)4]} (pz=pyrazine), by the temperature dependence of Raman spectra. The ortho (o)–para (p) conversion process of H2 is forbidden for an isolated molecule. The charge density study using synchrotron radiation X-ray diffraction reveals the electric field generated in coordination nano-space. The present results corroborate similar findings observed on different systems and confirm that o–p conversion can occur on non-magnetic solids and that electric field can induce the catalytic hydrogen o–p conversion. PMID:26587262
Cholecystocutaneous fistula: an unusual complication of a para-umbilical hernia repair
Dixon, Steven; Sharma, Mitesh; Holtham, Stephen
2014-01-01
This case describes a 94-year-old woman who presented 2 years postsutured para-umbilical hernia repair with a painful black lump protruding through her scar with blood stained discharge. This was initially thought to be either ischaemic bowel secondary to strangulated incisional hernia or a large organised haematoma. An urgent CT scan was performed following which the patient passed two large calculi and bile-stained fluid spontaneously through the wound, making the diagnosis somewhat clearer. The scan revealed an incisional hernia containing the gallbladder and two large calculi at the skin surface and an incidental large caecal cancer with surrounding lymphadenopathy. Frail health and the incidental finding of a colon cancer rendered invasive surgical management inappropriate. Therefore, she was managed conservatively with antibiotics. A catheter was inserted into the fistula tract to allow free drainage and alleviate pressure-related symptoms. The patient was discharged following a multidisciplinary team discussion. PMID:24862413
Development of a para-orthohydrogen catalytic converter for a solid hydrogen cooler
NASA Technical Reports Server (NTRS)
Nast, T. C.; Hsu, I. C.
1984-01-01
Design features of a tested catalytic converter for altering vented cryogenic parahydrogen used as a coolant on spacecraft into a para-ortho equilibrium for channeling to other cooling functions are described. The hydrogen is expected to be stored in either liquid or solid form. A high surface area Ni-on-Si catalyst was selected for tests at an operating pressure of 2 torr at a ratio of 1000 gr catalyst for a gr/sec hydrogen flow. Cylindrical and radial flow geometries were tried and measurements centered on the converter efficiencies at different operating temperatures when the converter was placed in the vent line of the H2 cooler. Efficiencies ranging from 10-100 percent were obtained for varying flow rates. Further testing is necessary to characterize the converter performance under a wider range of operating temperatures and environments.
El Proyecto Sismico "LARSE" - Trabajando Hacia un Futuro con Mas Seguridad para Los Angeles
Henyey, Thomas L.; Fuis, Gary S.; Benthien, Mark L.; Burdette, Thomas R.; Christofferson, Shari A.; Clayton, Robert W.; Criley, Edward E.; Davis, Paul M.; Hendley, James W., II; Kohler, Monica D.; Lutter, William J.; McRaney, John K.; Murphy, Janice M.; Okaya, David A.; Ryberg, Trond; Simila, Gerald W.; Stauffer, Peter H.
1999-01-01
La region de Los Angeles contiene una red de fallas activas, incluyendo muchas fallas por empuje que son profundas y no rompen la superficie de la tierra. Estas fallas ocultas incluyen la falla anteriormente desconocida que fue responsable por la devastacion que ocurrio durante el terremoto de Northridge en enero de 1994, el terremoto mas costoso en la historia de los Estados Unidos. El Experimento Sismico en la Region de Los Angeles (Los Angeles Region Seismic Experiment, LARSE), esta localizando los peligros ocultos de los terremotos debajo de la region de Los Angeles para mejorar la construccion de las estructuras que pueden apoyar terremotos que son inevitables en el futuro, y que ayudaran a los cientificos determinar donde occurira el sacudimento mas fuerte y poderoso.
Surface Temperature Dependence of Hydrogen Ortho-Para Conversion on Amorphous Solid Water
NASA Astrophysics Data System (ADS)
Ueta, Hirokazu; Watanabe, Naoki; Hama, Tetsuya; Kouchi, Akira
2016-06-01
The surface temperature dependence of the ortho-to-para conversion of H2 on amorphous solid water is first reported. A combination of photostimulated desorption and resonance-enhanced multiphoton ionization techniques allowed us to sensitively probe the conversion on the surface of amorphous solid water at temperatures of 9.2-16 K. Within a narrow temperature window of 8 K, the conversion time steeply varied from ˜4.1 ×103 to ˜6.4 ×102 s . The observed temperature dependence is discussed in the context of previously suggested models and the energy dissipation process. The two-phonon process most likely dominates the conversion rate at low temperatures.
Surface Temperature Dependence of Hydrogen Ortho-Para Conversion on Amorphous Solid Water.
Ueta, Hirokazu; Watanabe, Naoki; Hama, Tetsuya; Kouchi, Akira
2016-06-24
The surface temperature dependence of the ortho-to-para conversion of H_{2} on amorphous solid water is first reported. A combination of photostimulated desorption and resonance-enhanced multiphoton ionization techniques allowed us to sensitively probe the conversion on the surface of amorphous solid water at temperatures of 9.2-16 K. Within a narrow temperature window of 8 K, the conversion time steeply varied from ∼4.1×10^{3} to ∼6.4×10^{2} s. The observed temperature dependence is discussed in the context of previously suggested models and the energy dissipation process. The two-phonon process most likely dominates the conversion rate at low temperatures. PMID:27391719
ACT-asthma control y tratamiento para niños: a progress report.
Lewis, M A; de la Sota, A; Rachelefsky, G; Lewis, C E; Quinones, H; Richards, W
1987-01-01
A randomized clinical trial is in progress to evaluate an asthma educational program for Latino children and their parents. The intervention, "ACT-Asma Control y Tratamiento Para Niños," was adapted from ACT for Kids, an asthma self-management program for English-speaking families. Results of a pilot study indicated that socioeconomic status was a critical variable to be considered in the design of such programs. Latino children and parents encounter significant barriers to access and continuity of medical care. Therefore, the intervention was redesigned to include "linkages" using a nurse to reduce barriers and to coordinate care. The lesson plans emphasize concrete, experimental learning experiences, with repetition of key points in each session. PMID:3654235
Coordination nano-space as stage of hydrogen ortho-para conversion.
Kosone, Takashi; Hori, Akihiro; Nishibori, Eiji; Kubota, Yoshiki; Mishima, Akio; Ohba, Masaaki; Tanaka, Hiroshi; Kato, Kenichi; Kim, Jungeun; Real, José Antonio; Kitagawa, Susumu; Takata, Masaki
2015-07-01
The ability to design and control properties of nano-sized space in porous coordination polymers (PCPs) would provide us with an ideal stage for fascinating physical and chemical phenomena. We found an interconversion of nuclear-spin isomers for hydrogen molecule H2 adsorbed in a Hofmann-type PCP, {Fe(pz)[Pd(CN)4]} (pz=pyrazine), by the temperature dependence of Raman spectra. The ortho (o)-para (p) conversion process of H2 is forbidden for an isolated molecule. The charge density study using synchrotron radiation X-ray diffraction reveals the electric field generated in coordination nano-space. The present results corroborate similar findings observed on different systems and confirm that o-p conversion can occur on non-magnetic solids and that electric field can induce the catalytic hydrogen o-p conversion. PMID:26587262
Food for Life/Comida para la Vida: Creating a Food Festival to Raise Diabetes Awareness
Lancaster, Kristie; Walker, Willie; Vance, Thomas; Kaskel, Phyllis; Arniella, Guedy; Horowitz, Carol
2012-01-01
African and Latino Americans have higher rates of diabetes and its complications than White Americans. Identifying people with undiagnosed diabetes and helping them obtain care can help to prevent complications and mortality. To kick off a screening initiative, our community-academic partnership created the “Food for Life Festival,” or “Festival Comida para la Vida.” This article will describe the community’s perspective on the Festival, which was designed to screen residents, and demonstrate that eating healthy can be fun, tasty, and affordable in a community-centered, culturally consonant setting. More than 1,000 residents attended the event; 382 adults were screened for diabetes, and 181 scored as high risk. Fifteen restaurants distributed free samples of healthy versions of their popular dishes. Community residents, restaurateurs, and clinicians commented that the event transformed many of their preconceived ideas about healthy foods and patient care. PMID:20097997
A method to obtain a well-defined fraction of respirable para-aramid fibers.
Schins, R P; Gaudichet, A; Jaurand, M C
1993-10-01
We developed a preparation method to obtain respirable-sized fractions of para-aramid fibers. The procedure, based on floatability, consists of stirring and subsequent settling of p-aramid pulp in distilled water. Two distinct phases are obtained, with small fibers in the upper part of the suspension, which represents about 33% of the total volume. Optimal results were obtained when 2.0 g pulp was stirred for 15 hr in 800 ml distilled water containing 0.125% ethanol and settled for 5 hr. The mass yield ranged between 0.4 and 0.6%, more than 90% of the particles had an aspect ratio > or = 3:1. The mean fiber length was about 6 microns, and the mean fiber diameter was about 0.4 microns as determined by transmission and scanning electron microscopy. The number of fibers obtained was 4 x 10(6) fibers/micrograms under our standard conditions. PMID:8119251
Constraining the ortho-to-para ratio of H2 with anomalous H_2CO absorption
NASA Astrophysics Data System (ADS)
Troscompt, N.; Faure, A.; Maret, S.; Ceccarelli, C.; Hily-Blant, P.; Wiesenfeld, L.
2009-11-01
Context: The ortho-to-para ratio (OPR) of molecular hydrogen is a fundamental parameter in understanding the physics and chemistry of molecular clouds. In dark and cold regions, however, H2 is not directly observable and the OPR of H2 in these sources has so far remained elusive. Aims: We show that the 6 cm absorption line of ortho-formaldehyde (H2CO) can be employed to constrain both the density and the OPR of H2 in dark clouds. Methods: Green Bank Telescope (GBT) observations of ortho-H2CO toward the molecular cloud Barnard 68 (B68) are reported. Non-LTE radiative transfer calculations combined with the well-constrained structure of B68 are then employed to derive the physical conditions in the absorption region. Results: We provide the first firm confirmation of the Townes & Cheung mechanism: propensity rules for the collisions of H2CO with H2 molecules are responsible for the sub-2.7 K cooling of the 6 cm doublet. Non-LTE calculations show that in the absorption region of B68, the kinetic temperature is ˜ 10 K, the ortho-H2CO column density amounts to ˜ 2.2× 1013 cm-2, the H2 density is in the range 1.4{-}2.4× 10 4 cm-3, and the OPR of H2 is close to zero. Our observations thus provide fresh evidence that H2 is mostly in its para form in the cold gas, as expected from theoretical considerations. Our results also suggest that formaldehyde absorption originates in the edge of B68, at visual extinctions A_V⪉ 0.5 mag. This work has been inspired by our colleague and friend Pierre Valiron, who passed away in August 2008. This paper is dedicated to his memory.
Lee, Jung-Yun; Kim, Younhee; Lee, Tae-Jin; Jeon, Yong Woo; Kim, Kidong; Chung, Hyun Hoon; Park, Sang Min; Kim, Jae-Weon
2015-01-01
Objective To evaluate the cost-effectiveness of nodal staging surgery before chemoradiotherapy (CRT) for locally advanced cervical cancer in the era of positron emission tomography/computed tomography (PET/CT). Methods A modified Markov model was constructed to evaluate the cost-effectiveness of para-aortic staging surgery before definite CRT when no uptake is recorded in the para-aortic lymph nodes (PALN) on PET/CT. Survival and complication rates were estimated based on the published literature. Cost data were obtained from the Korean Health Insurance Review and Assessment Service. Strategies were compared using an incremental cost-effectiveness ratio (ICER). Sensitivity analyses were performed, including estimates for the performance of PET/CT, postoperative complication rate, and varying survival rates according to the radiation field. Results We compared two strategies: strategy 1, pelvic CRT for all patients; and strategy 2, nodal staging surgery followed by extended-field CRT when PALN metastasis was found and pelvic CRT otherwise. The ICER for strategy 2 compared to strategy 1 was $19,505 per quality-adjusted life year (QALY). Under deterministic sensitivity analyses, the model was relatively sensitive to survival reduction in patients who undergo pelvic CRT alone despite having occult PALN metastasis. A probabilistic sensitivity analysis demonstrated the robustness of the case results, with a 91% probability of cost-effectiveness at the willingness-to-pay thresholds of $60,000/QALY. Conclusion Nodal staging surgery before definite CRT may be cost-effective when PET/CT imaging shows no evidence of PALN metastasis. Prospective trials are warranted to transfer these results to guidelines. PMID:25925292
The analysis of para-cresol production and tolerance in Clostridium difficile 027 and 012 strains
2011-01-01
Background Clostridium difficile is the major cause of antibiotic associated diarrhoea and in recent years its increased prevalence has been linked to the emergence of hypervirulent clones such as the PCR-ribotype 027. Characteristically, C. difficile infection (CDI) occurs after treatment with broad-spectrum antibiotics, which disrupt the normal gut microflora and allow C. difficile to flourish. One of the relatively unique features of C. difficile is its ability to ferment tyrosine to para-cresol via the intermediate para-hydroxyphenylacetate (p-HPA). P-cresol is a phenolic compound with bacteriostatic properties which C. difficile can tolerate and may provide the organism with a competitive advantage over other gut microflora, enabling it to proliferate and cause CDI. It has been proposed that the hpdBCA operon, rarely found in other gut microflora, encodes the enzymes responsible for the conversion of p-HPA to p-cresol. Results We show that the PCR-ribotype 027 strain R20291 quantitatively produced more p-cresol in-vitro and was significantly more tolerant to p-cresol than the sequenced strain 630 (PCR-ribotype 012). Tyrosine conversion to p-HPA was only observed under certain conditions. We constructed gene inactivation mutants in the hpdBCA operon in strains R20291 and 630Δerm which curtails their ability to produce p-cresol, confirming the role of these genes in p-cresol production. The mutants were equally able to tolerate p-cresol compared to the respective parent strains, suggesting that tolerance to p-cresol is not linked to its production. Conclusions C. difficile converts tyrosine to p-cresol, utilising the hpdBCA operon in C. difficile strains 630 and R20291. The hypervirulent strain R20291 exhibits increased production of and tolerance to p-cresol, which may be a contributory factor to the virulence of this strain and other hypervirulent PCR-ribotype 027 strains. PMID:21527013
Self-assembled catalytic DNA nanostructures for synthesis of para-directed polyaniline.
Wang, Zhen-Gang; Zhan, Pengfei; Ding, Baoquan
2013-02-26
Templated synthesis has been considered as an efficient approach to produce polyaniline (PANI) nanostructures. The features of DNA molecules enable a DNA template to be an intriguing template for fabrication of emeraldine PANI. In this work, we assembled HRP-mimicking DNAzyme with different artificial DNA nanostructures, aiming to manipulate the molecular structures and morphologies of PANI nanostructures through the controlled DNA self-assembly. UV-vis absorption spectra were used to investigate the molecular structures of PANI and monitor kinetic growth of PANI. It was found that PANI was well-doped at neutral pH and the redox behaviors of the resultant PANI were dependent on the charge density of the template, which was controlled by the template configurations. CD spectra indicated that the PANI threaded tightly around the helical DNA backbone, resulting in the right handedness of PANI. These reveal the formation of the emeraldine form of PANI that was doped by the DNA. The morphologies of the resultant PANI were studied by AFM and SEM. It was concluded from the imaging and spectroscopic kinetic results that PANI grew preferably from the DNAzyme sites and then expanded over the template to form 1D PANI nanostructures. The strategy of the DNAzyme-DNA template assembly brings several advantages in the synthesis of para-coupling PANI, including the region-selective growth of PANI, facilitating the formation of a para-coupling structure and facile regulation. We believe this study contributes significantly to the fabrication of doped PANI nanopatterns with controlled complexity, and the development of DNA nanotechnology. PMID:23272944
On Ensino de Astronomia: Desafios para Implantação
NASA Astrophysics Data System (ADS)
Faria, R. Z.; Voelzke, M. R.
2008-09-01
Em 2002 o ensino de Astronomia foi proposto como um dos temas estruturadores pelos Parâmetros Curriculares Nacionais e sugerido como facilitador para que o aluno compreendesse a Física como construção humana e parte do seu mundo vivencial, mas raramente seus conceitos foram ensinados. A presente pesquisa discute dois aspectos relacionados à abordagem de Astronomia. O primeiro aspecto é se ela está sendo abordada pelos professores do Ensino Médio e o segundo, aborda a maneira como ela está sendo ensinada. Optou-se pela aplicação de um questionário a partir do 2° semestre de 2006 e durante o ano de 2007 com professores que ministram a disciplina de Física, os quais trabalham em escolas estaduais em Rio Grande da Serra, Ribeirão Pires e Mauá no estado São Paulo. Dos 66,2% dos professores que responderam ao questionário nos municípios de Rio Grande da Serra, Ribeirão Pires e Mauá, 57,4% não aplicaram nenhum tópico de astronomia, 70,2% não utilizaram laboratório, 89,4% não utilizaram qualquer tipo de programa computacional, 83,0% nunca fizeram visitas com alunos a museus e planetários e 38,3% não indicaram qualquer tipo de livro ou revista referente à astronomia aos seus alunos. Mesmo considerando a Astronomia um conteúdo potencialmente significativo, esta não fez parte dos planejamentos escolares. Portanto são necessárias propostas que visem estratégias para a educação continuada dos professores como, por exemplo, cursos específicos sobre o ensino em Astronomia.
Oliver, Thomas A A; King, Graeme A; Tew, David P; Dixon, Richard N; Ashfold, Michael N R
2012-12-27
H (Rydberg) atom photofragment translation spectroscopy and high-level ab initio electronic structure calculations are used to explore the photodissociation dynamics of three para-substituted thiophenols (p-YPhSH; Y = CH(3), F, and MeO). UV excitation in the wavelength range 305 > λ(phot) > 240 nm results in S-H bond fission and formation of p-YPhS radicals in their ground (X̃(2)B(1)) and first excited (Ã(2)B(2)) electronic states; the X̃/Ã state product branching ratio, Γ, varies with para-Y substituent and excitation wavelength. Excitation at λ(phot) < 265 nm results in direct population of the dissociative 1(1)πσ* potential energy surface (PES). Γ falls across the series p-CH(3)PhSH > p-FPhSH > p-MeOPhSH. Branching is ultimately determined at the conical intersection (CI) formed by the 1(1)πσ* and ground (S(0)) PESs at extended R(S-H) bond length but is sensitively dependent on the orientation of the S-H bond (relative to the ring plane) in the S(0) molecules prior to photoexcitation. Excitation at λ(phot) > 265 nm populates quasi-bound levels of the respective 1(1)ππ* states, which predissociate rapidly by tunneling under the lower diabats of the 1(1)ππ*/1(1)πσ* CI at short R(S-H). Less extreme X̃/Ã product branching ratios are measured, implicating intramolecular vibrational redistribution within the photoexcited 1(1)ππ* molecules prior to their sampling the region of the 1(1)πσ*/S(0) CI. PMID:23110379
Prevalence of oral trauma in Para-Pan American Games athletes.
Andrade, Rafaela Amarante; Modesto, Adriana; Evans, Patricia Louise Scabell; Almeida, Anne Louise Scabell; da Silva, Juliana de Jesus Rodrigues; Guedes, Aurelino Machado Lima; Guedes, Fábio Ribeiro; Ranalli, Dennis N; Tinoco, Eduardo Muniz Barretto
2013-08-01
The aim of this cross-sectional epidemiological survey was to assess the prevalence of oral trauma in athletes representing 25 countries competing at the most recent Para-Pan American Games (III PARAPAN) held in Rio de Janeiro, Brazil. The study was approved by the appropriate institutional review board. The examiners participated in standardization and calibration training sessions before the field phase began. Invitations were sent to >1200 participating athletes competing in eight sports and to the Medical Committee of the Para-Pan American Sports Organization before and during the III PARAPAN. A convenience sample of 120 athletes was recruited. After signing an informed consent, all athletes answered a questionnaire. Data were collected at the clinical examination and recorded in a specific trauma form. The mean age of the athletes was 32.5 years. Males comprised 79.2% of the sample; females 20.8%. The prevalence of oral trauma among the athletes was 47.5% (N = 57). However, only 15 athletes reported that these traumatic injuries were sports-related. The sport with the highest prevalence of oral trauma was judo (75%); the least was volleyball with no reported traumatic injuries. The most common traumatic injury was enamel fracture (27.4%). The teeth most affected were the maxillary permanent central incisors (N = 19), followed by the maxillary premolars (N = 8). On the basis of the results of this study of oral trauma among athletes examined at the III PARAPAN, a recommendation for enhanced educational efforts and the use of properly fitted mouthguards to prevent traumatic injuries among high-performance athletes with disabilities seems warranted. PMID:22882839
Uso de exámenes de detección como oportunidad para ayudar a fumadores a dejar el tabaco
El NCI ha publicado un anuncio de financiamiento para ayudar a estimular la investigación sobre métodos óptimos para dejar de fumar cigarrillos que se entreguen junto con los exámenes de detección.
Enfermedad trofoblástica de la gestación—Versión para profesionales de salud
Información del Instituto Nacional del Cáncer para profesionales de salud sobre el tratamiento de la enfermedad trofoblástica de la gestación, así como referencias a estudios clínicos y otros temas relacionados.
Pruebas sin beneficio comprobado se usan aún para viiglar cáncer de ovario
Artículo del blog Temas y Relatos del NCI sobre un estudio que indica que los medicos clínicos siguen usando análisis de CA-125 y exploraciones con TC para vigilar de rutina las recurrencias aunque no se ha comprobado el beneficio de estas pruebas.
NASA Astrophysics Data System (ADS)
Wu, Huayi; Guan, Xuefeng; Gong, Jianya
2011-09-01
This paper presents a robust parallel Delaunay triangulation algorithm called ParaStream for processing billions of points from nonoverlapped block LiDAR files. The algorithm targets ubiquitous multicore architectures. ParaStream integrates streaming computation with a traditional divide-and-conquer scheme, in which additional erase steps are implemented to reduce the runtime memory footprint. Furthermore, a kd-tree-based dynamic schedule strategy is also proposed to distribute triangulation and merging work onto the processor cores for improved load balance. ParaStream exploits most of the computing power of multicore platforms through parallel computing, demonstrating qualities of high data throughput as well as a low memory footprint. Experiments on a 2-Way-Quad-Core Intel Xeon platform show that ParaStream can triangulate approximately one billion LiDAR points (16.4 GB) in about 16 min with only 600 MB physical memory. The total speedup (including I/O time) is about 6.62 with 8 concurrent threads.
ERIC Educational Resources Information Center
Gomez, Francisco C., Jr.; And Others
1992-01-01
The standardization of the Escala de Inteligencia Wechsler para Adultos (EIWA) and the original Wechsler Adult Intelligence Scale (WAIS) were subjected to principal components analysis to examine their comparability for 616 EIWA subjects and 800 WAIS subjects. Similarity of factor structures of both scales is supported. (SLD)
ERIC Educational Resources Information Center
Kollins, Judith M.; Hansman, Catherine A.
2005-01-01
This study examines how the Education Office of the "Oficina Juridica Para la Mujer" [Women's Legal Office] , a community-based popular education organization in Cochabamba, Bolivia, works with women to address personal, legal, and policy issues through local leadership training and popular education methodology. We investigate the marginalization…