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Sample records for knoevenagel condensation kinetic

  1. Diastereoselective one-pot Knoevenagel condensation/Corey-Chaykovsky cyclopropanation.

    PubMed

    Clemens, Jeremy J; Asgian, Juliana L; Busch, Brett B; Coon, Timothy; Ernst, Justin; Kaljevic, Leonard; Krenitsky, Paul J; Neubert, Timothy D; Schweiger, Edwin J; Termin, Andreas; Stamos, Dean

    2013-01-18

    Efforts to substitute the cyclopropane ring in a series of aryl cyclopropylnitriles led to the discovery of an operationally simple one-pot method for Knoevenagel condensation and subsequent Corey-Chaykovsky cyclopropanation giving diastereomerically pure products as a racemic mixture of enantiomers. Method development and results for variably substituted aryl acetonitriles and aldehydes in the reaction are reported. A concise synthesis of (±)-bicifadine in two steps is provided to demonstrate the utility of the method. PMID:23252964

  2. A DFT study of IRMOF-3 catalysed Knoevenagel condensation.

    PubMed

    Cortese, Remedios; Duca, Dario

    2011-09-21

    It has been recently reported that IRMOF-3 [Gascon et al., J. Catal, 2009, 261, 75] may behave as a basic catalyst, active in the Knoevenagel condensation. In particular, it has been shown that the basicity of aniline-like amino moieties is enhanced, along with the catalytic activity, when incorporated into MOF structures. The computational study here was aimed at finding possible atomistic explanations of the increased basicity and catalytic activity of the IRMOF-3 embedded aniline groups, experimentally claimed. It was, moreover, aimed at guessing a reaction mechanism for the IRMOF-3 catalysed Knoevenagel condensation of benzaldehyde and ethyl-cyanoacetate. Within the DFT framework we have studied structure and basicity properties of IRMOF-3 and we have analysed the energetics of the catalytic cycle as well as of possible deactivation paths, including it. The increased basicity of IRMOF-3 over other amminic catalysts has been explained via the formation of protonated conjugate derivatives, involving hydrogen-bonds and originating quasi-planar 6-term rings. Several plausible reaction steps have been moreover taken into account and a mechanism for the Knoevenagel condensation, including catalyst deactivation, has been proposed for aniline molecules and embedded aniline moieties. This allowed us to suggest that the increased IRMOF-3 activity, as a basic catalyst, should be mostly related to its water adsorption ability, preserving the properties of the catalytically active amino moieties. PMID:21814670

  3. Classical Keggin Intercalated into Layered Double Hydroxides: Facile Preparation and Catalytic Efficiency in Knoevenagel Condensation Reactions.

    PubMed

    Jia, Yueqing; Fang, Yanjun; Zhang, Yingkui; Miras, Haralampos N; Song, Yu-Fei

    2015-10-12

    The family of polyoxometalate (POM) intercalated layered double hydroxide (LDH) composite materials has shown great promise for the design of functional materials with numerous applications. It is known that intercalation of the classical Keggin polyoxometalate (POM) of [PW12 O40 ](3-) (PW12 ) into layered double hydroxides (LDHs) is very unlikely to take place by conventional ion exchange methods due to spatial and geometrical restrictions. In this paper, such an intercalated compound of Mg0.73 Al0.22 (OH)2 [PW12 O40 ]0.04 ⋅0.98 H2 O (Mg3 Al-PW12 ) has been successfully obtained by applying a spontaneous flocculation method. The Mg3 Al-PW12 has been fully characterized by using a wide range of methods (XRD, SEM, TEM, XPS, EDX, XPS, FT-IR, NMR, BET). XRD patterns of Mg3 Al-PW12 exhibit no impurity phase usually observed next to the (003) diffraction peak. Subsequent application of the Mg3 Al-PW12 as catalyst in Knoevenagel condensation reactions of various aldehydes and ketones with Z-CH2 -Z' type substrates (ethyl cyanoacetate and malononitrile) at 60 °C in mixed solvents (V2-propanol :Vwater =2:1) demonstrated highly efficient catalytic activity. The synergistic effect between the acidic and basic sites of the Mg3 Al-PW12 composite proved to be crucial for the efficiency of the condensation reactions. Additionally, the Mg3 Al-PW12 -catalyzed Knoevenagel condensation of benzaldehyde with ethyl cyanoacetate demonstrated the highest turnover number (TON) of 47 980 reported so far for this reaction. PMID:26337902

  4. Fast Knoevenagel Condensations Catalyzed by an Artificial Schiff-Base-Forming Enzyme.

    PubMed

    Garrabou, Xavier; Wicky, Basile I M; Hilvert, Donald

    2016-06-01

    The simple catalytic motifs utilized by enzymes created by computational design and directed evolution constitute a potentially valuable source of chemical promiscuity. Here we show that the artificial retro-aldolase RA95.5-8 is able to use a reactive lysine in a hydrophobic pocket to accelerate promiscuous Knoevenagel condensations of electron-rich aldehydes and activated methylene donors. Optimization of this activity by directed evolution afforded an efficient enzyme variant with a catalytic proficiency of 5 × 10(11) M(-1) and a >10(8)-fold catalytic advantage over simple primary and secondary amines. Divergent evolution of de novo enzymes in this way could be a promising strategy for creating tailored biocatalysts for many synthetically useful reactions. PMID:27196438

  5. The synthesis of a bifunctional copper metal organic framework and its application in the aerobic oxidation/Knoevenagel condensation sequential reaction.

    PubMed

    Miao, Zongcheng; Luan, Yi; Qi, Chao; Ramella, Daniele

    2016-09-21

    A novel one-pot aerobic oxidation/Knoevenagel condensation reaction system was developed employing a Cu(ii)/amine bifunctional, basic metal-organic framework (MOF) as the catalyst. The sequential aerobic alcohol oxidation/Knoevenagel condensation reaction was efficiently promoted by the Cu3TATAT MOF catalyst in the absence of basic additives. The benzylidenemalononitrile product was produced in high yield and selectivity from an inexpensive benzyl alcohol starting material under an oxygen atmosphere. The role of the basic functionality was studied to demonstrate its role in the aerobic oxidation and Knoevenagel condensation reactions. The reaction progress was monitored in order to identify the reaction intermediate and follow the accumulation of the desired product. Lastly, results showed that the yield was not significantly compromised by the reuse of a batch of catalyst, even after more than five cycles. PMID:27523776

  6. Schiff base structured acid-base cooperative dual sites in an ionic solid catalyst lead to efficient heterogeneous knoevenagel condensations.

    PubMed

    Zhang, Mingjue; Zhao, Pingping; Leng, Yan; Chen, Guojian; Wang, Jun; Huang, Jun

    2012-10-01

    An acid-base bifunctional ionic solid catalyst [PySaIm](3)PW was synthesized by the anion exchange of the ionic-liquid (IL) precursor 1-(2-salicylaldimine)pyridinium bromide ([PySaIm]Br) with the Keggin-structured sodium phosphotungstate (Na(3) PW). The catalyst was characterized by FTIR, UV/Vis, XRD, SEM, Brunauer-Emmett-Teller (BET) theory, thermogravimetric analysis, (1)H NMR spectroscopy, ESI-MS, elemental analysis, and melting points. Together with various counterparts, [PySaIm](3)PW was evaluated in Knoevenagel condensation under solvent and solvent-free conditions. The Schiff base structure attached to the IL cation of [PySaIm](3)PW involves acidic salicyl hydroxyl and basic imine, and provides a controlled nearby position for the acid-base dual sites. The high melting and insoluble properties of [PySaIm](3)PW are relative to the large volume and high valence of PW anions, as well as the intermolecular hydrogen-bonding networks among inorganic anions and IL cations. The ionic solid catalyst [PySaIm](3)PW leads to heterogeneous Knoevenagel condensations. In solvent-free condensation of benzaldehyde with ethyl cyanoacetate, it exhibits a conversion of 95.8 % and a selectivity of 100 %; the conversion is even much higher than that (78.2 %) with ethanol as a solvent. The solid catalyst has a convenient recoverability with only a slight decrease in conversion following subsequent recyclings. Furthermore, the new catalyst is highly applicable to many substrates of aromatic aldehydes with activated methylene compounds. On the basis of the characterization and reaction results, a unique acid-base cooperative mechanism within a Schiff base structure is proposed and discussed, which thoroughly explains not only the highly efficient catalytic performance of [PySaIm](3)PW, but also the lower activities of various control catalysts. PMID:22907828

  7. Curcumin-I Knoevenagel's condensates and their Schiff's bases as anticancer agents: synthesis, pharmacological and simulation studies.

    PubMed

    Ali, Imran; Haque, Ashanul; Saleem, Kishwar; Hsieh, Ming Fa

    2013-07-01

    Pyrazolealdehydes (4a-d), Knoevenagel's condensates (5a-d) and Schiff's bases (6a-d) of curcumin-I were synthesized, purified and characterized. Hemolysis assays, cell line activities, DNA bindings and docking studies were carried out. These compounds were lesser hemolytic than standard drug doxorubicin. Minimum cell viability (MCF-7; wild) observed was 59% (1.0 μg/mL) whereas the DNA binding constants ranged from 1.4×10(3) to 8.1×10(5) M(-1). The docking energies varied from -7.30 to -13.4 kcal/mol. It has been observed that DNA-compound adducts were stabilized by three governing forces (Van der Wall's, H-bonding and electrostatic attractions). It has also been observed that compounds 4a-d preferred to enter minor groove while 5a-d and 6a-d interacted with major grooves of DNA. The anticancer activities of the reported compounds might be due to their interactions with DNA. These results indicated the bright future of the reported compounds as anticancer agents. PMID:23643901

  8. Lasing the DNA fragments through β-diketimine framed Knoevenagel condensed Cu(II) and Zn(II) complexes - An in vitro and in vivo approach

    NASA Astrophysics Data System (ADS)

    Raman, Natarajan; Pravin, Narayanaperumal

    2014-01-01

    The syntheses, structures and spectroscopic properties of Cu(II) and Zn(II) complexes having Knoevenagel condensate β-diketimine Schiff base ligands have been investigated in this paper. Characterization of these complexes was carried out using FTIR, NMR, UV-Vis, elemental analysis, mass and EPR techniques. Absorption titration, electrochemical analyses and viscosity measurements have also been carried out to determine the mode of binding. The shift in ΔEp, E1/2 and Ipc values explores the interaction of CT DNA with the above metal complexes. Interaction of ligands and their complexes with DNA revealed an intercalative mode of binding between them. Antimicrobial studies showed an effective antimicrobial activity of the metal ions after coordination with the ligands. The antioxidant properties of the Schiff base ligands and their complexes were evaluated in a series of in vitro tests by using 1,1-diphenyl-2-picrylhydrazyl (DPPHrad ) and H2O2 free radical scavengers. In vivo and in vitro antitumor functions of the complexes against Ehrlich ascites carcinoma tumor model have also been investigated. All the results support that β-diketone derived Knoevenagel condensate Schiff base complexes may act as novel antitumor drugs and suggest that their potent cell life inhibition may contribute to their anti-cancer efficacy.

  9. Lasing the DNA fragments through β-diketimine framed Knoevenagel condensed Cu(II) and Zn(II) complexes--an in vitro and in vivo approach.

    PubMed

    Raman, Natarajan; Pravin, Narayanaperumal

    2014-01-24

    The syntheses, structures and spectroscopic properties of Cu(II) and Zn(II) complexes having Knoevenagel condensate β-diketimine Schiff base ligands have been investigated in this paper. Characterization of these complexes was carried out using FTIR, NMR, UV-Vis, elemental analysis, mass and EPR techniques. Absorption titration, electrochemical analyses and viscosity measurements have also been carried out to determine the mode of binding. The shift in ΔEp, E1/2 and Ipc values explores the interaction of CT DNA with the above metal complexes. Interaction of ligands and their complexes with DNA revealed an intercalative mode of binding between them. Antimicrobial studies showed an effective antimicrobial activity of the metal ions after coordination with the ligands. The antioxidant properties of the Schiff base ligands and their complexes were evaluated in a series of in vitro tests by using 1,1-diphenyl-2-picrylhydrazyl (DPPH) and H2O2 free radical scavengers. In vivo and in vitro antitumor functions of the complexes against Ehrlich ascites carcinoma tumor model have also been investigated. All the results support that β-diketone derived Knoevenagel condensate Schiff base complexes may act as novel antitumor drugs and suggest that their potent cell life inhibition may contribute to their anti-cancer efficacy. PMID:24161850

  10. Preparation of neuroprotective condensed 1,4-benzoxazepines by regio- and diastereoselective domino Knoevenagel-[1,5]-hydride shift cyclization reaction.

    PubMed

    Tóth, László; Fu, Yan; Zhang, Hai Yan; Mándi, Attila; Kövér, Katalin E; Illyés, Tünde-Zita; Kiss-Szikszai, Attila; Balogh, Balázs; Kurtán, Tibor; Antus, Sándor; Mátyus, Péter

    2014-01-01

    Condensed O,N-heterocycles containing tetrahydro-1,4-benzoxazepine and tetrahydroquinoline moieties were prepared by a regio- and diastereoselective domino Knoevenagel-[1,5]-hydride shift cyclization reaction of a 4-aryl-2-phenyl-1,4-benzoxazepine derivative obtained from flavanone. The relative configuration of products were determined by the correlation of (3) J H,H coupling data with the geometry of major conformers accessed by DFT conformational analysis. Separated enantiomers of the products were characterized by HPLC-ECD data, which allowed their configurational assignment on the basis of TDDFT-ECD calculation of the solution conformers. Two compounds showed neuroprotective activities against hydrogen peroxide (H2O2) or β-amyloid25-35 (Aβ25-35)-induced cellular injuries in human neuroblastoma SH-SY5Y cells in the range of those of positive controls. PMID:25550721

  11. New Difluoro Knoevenagel Condensates of Curcumin, Their Schiff Bases and Copper Complexes as Proteasome Inhibitors and Apoptosis Inducers in Cancer Cells

    PubMed Central

    Padhye, Subhash; Yang, Huanjie; Jamadar, Abeda; Cui, Qiuzhi Cindy; Chavan, Deepak; Dominiak, Kristin; McKinney, Jaclyn; Banerjee, Sanjeev; Dou, Q. Ping; Sarkar, Fazlul H.

    2013-01-01

    Purpose Emerging evidence clearly suggests the potential chemopreventive and anti-tumor activity of a well known “natural agent” curcumin. However, studies have shown that curcumin is not readily bioavailable, and thus the tissue bioavailability of curcumin is also poor except for gastrointestinal track. Because of the potential biological activity of curcumin, many studies have attempted for making a better analog of cucumin that is equally effective or better with increased bioavailability, which was the purpose of our current study. Methods We have designed and synthesized new difluoro Knoevenagel condensates of curcumin and Schiff bases along with their copper (II) complexes and evaluated their biological activities with respect to the inhibitory effects on purified rabbit 26S proteasome, and growth inhibition and induction of apoptosis in colon and pancreatic cancer cell lines. Results All copper complexes possess distorted square planar geometries with 1:1 metal to ligand stoichiometry with reversible copper redox couple. The difluoro compound CDF exhibited inhibitory effects on purified rabbit 20S proteasome or cellular 26S proteasome, and caused both growth inhibition of cancer cell lines and induced apoptotic cell death in our preliminary assessment. Conclusion Our results suggest that our newly synthesized classes of curcumin analogs could be useful as chemopreventive and/or therapeutic agents against cancers. PMID:19421843

  12. Studies on the self-catalyzed Knoevenagel condensation, characterization, DPPH radical scavenging activity, cytotoxicity, and molecular properties of 5-arylidene-2,2-dimethyl-1,3-dioxane-4,6-diones using single crystal XRD and DFT techniques

    NASA Astrophysics Data System (ADS)

    Suresh Kumar, G. S.; Antony Muthu Prabhu, A.; Bhuvanesh, N.

    2014-10-01

    We have studied the self-catalyzed Knoevenagel condensation, spectral characterization, DPPH radical scavenging activity, cytotoxicity, and molecular properties of 5-arylidene-2,2-dimethyl-1,3-dioxane-4,6-diones using single crystal XRD and DFT techniques. In the absence of any catalyst, a series of novel 5-arylidene-2,2-dimethyl-1,3-dioxane-4,6-diones were synthesized using Meldrum’s acid and formylphenoxyaliphatic acid(s) in water. These molecules are arranged in the dimer form through intermolecular H-bonding in the single crystal XRD structure. Compounds have better DPPH radical scavenging activity and cytotoxicity against A431 cancer cell line. The optimized molecular structure, natural bond orbital analysis, electrostatic potential map, HOMO-LUMO energies, molecular properties, and atomic charges of these molecules have been studied by performing DFT/B3LYP/3-21G(*) level of theory in gas phase.

  13. DNA incision evaluation, binding investigation and biocidal screening of novel metallonucleases of 1,7-bis(4-hydroxy-3-methoxyphenyl)hepta-1,6-diene-3,5-dione based Knoevenagel condensate having methionine: Synthesis and structural validation

    NASA Astrophysics Data System (ADS)

    Chandrasekar, Thiravidamani; Pravin, Narayanaperumal; Raman, Natarajan

    2015-02-01

    Four new metallonucleases of the composition [MLCl] (where M = Cu(II), Ni(II), Zn(II) and Co(II); L = Knoevenagel condensate Schiff base, obtained by the condensation reaction of 1,7-bis(4-hydroxy-3-methoxyphenyl)hepta-1,6-diene-3,5-dione with p-nitrobenzaldehyde and methionine amino acid) have been synthesised and characterized thoroughly by microanalytical data, magnetic susceptibility, molar conductivity, UV-Vis., IR, 1H NMR, 13C NMR and EPR spectral techniques. Their geometry is investigated and established to have square planar geometry. Electronic absorption spectroscopy, cyclic voltammetry and viscosity measurements reveal that the complexes strongly bind to calf thymus DNA via an intercalation mechanism. DNA cleavage efficiency of these complexes is explored by gel electrophoresis, and they are found to endorse the cleavage of pBR322 DNA in presence of oxidant H2O2. These results reveal that all the complexes show better nuclease activity. Moreover, the biological screening against few pathogens reveals that that the complexes have potent biocidal activity than the free ligand.

  14. Knoevenagel Reaction of Unprotected Sugars

    NASA Astrophysics Data System (ADS)

    Scherrmann, Marie-Christine

    The Knoevenagel reaction of unprotected sugars was investigated in the 1950s using zinc chloride as promoter. The so-called Garcia Gonzalez reaction had been almost forgotten for 50 years, until the emergence of new water tolerant catalysts having Lewis acid behavior. The reaction was thus reinvestigated and optimal conditions have been found to prepare trihydroxylated furan derivatives from pentose or β-tetrahydrofuranylfuran from hexoses with non-cyclic β-keto ester or β-diketones. Other valuable compounds such as β-linked tetrahydrobenzofuranyl glycosides or hydroxyalkyl-3,3,6,6,-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione can be obtained using cyclic β-dicarbonylic derivatives. Apart from one report in the 1950s, the Knoevenagel reaction of unprotected carbohydrate in basic condition has been studied only in the mid-1980s to prepare C-glycosyl barbiturates from barbituric acids and, later on, from non-cyclic β-diketones, β-C-glycosidic ketones. The efficient method exploited to prepare such compounds has found an industrial development in cosmetics.

  15. Microporous polyurethane material for size selective heterogeneous catalysis of the Knoevenagel reaction.

    PubMed

    Dey, Sandeep Kumar; de Sousa Amadeu, Nader; Janiak, Christoph

    2016-06-14

    The first polyurethane material which is microporous (BET surface area of 312 m(2) g(-1)) is prepared by solvothermal synthesis and acts as highly efficient and recyclable heterogeneous catalyst in the Knoevenagel condensation showing size selectivity, and in the Henry reaction showing substrate selectivity under mild reaction conditions. PMID:27240738

  16. Kinetic approach to a relativistic Bose-Einstein condensate

    NASA Astrophysics Data System (ADS)

    Meistrenko, Alex; van Hees, Hendrik; Zhou, Kai; Greiner, Carsten

    2016-03-01

    We apply a Boltzmann approach to the kinetic regime of a relativistic Bose-Einstein condensate of scalar bosons by decomposing the one-particle distribution function in a condensate part and a nonzero momentum part of excited modes, leading to a coupled set of evolution equations which are then solved efficiently with an adaptive higher order Runge-Kutta scheme. We compare our results to the partonic cascade Monte Carlo simulation BAMPS for a critical but far from equilibrium case of massless bosons. Motivated by the color glass condensate initial conditions in QCD with a strongly overpopulated initial glasma state, we also discuss the time evolution starting from an overpopulated initial distribution function of massive scalar bosons. In this system a self-similar evolution of the particle cascade with a nonrelativistic turbulent scaling in the infrared sector is observed as well as a relativistic exponent for the direct energy cascade, confirming a weak wave turbulence in the ultraviolet region.

  17. Kinetic Isotopic Fractionation of Cd and Zn During Condensation

    NASA Astrophysics Data System (ADS)

    Cloquet, C.; Carignan, J.; Libourel, G.

    2005-12-01

    the first gas fraction to condense is depleted relative to the bulk composition of the gas. This is only compatible with kinetic isotopic fractionation which is mass dependant only. As the temperature dropped, most of the Cd and Zn gas condensed and mixed so that the isotopic composition of condensates is very similar to the bulk gas. The very last gas fraction had an isotopic composition enriched in heavy isotopes as a result of progressive condensation and isolation of condensates from the residual gas. It condensed on the cold plate of the heat transfer system and was included in the ash fraction having high metal concentrations. Considering the information on the behaviour observed during the gas cooling and the short time of the reactions, the Cd and Zn isotopic fractionation observed in the fly ashes are interpreted as the result of kinetic isotopic fractionation during condensation.

  18. Wave-kinetic description of finite temperature Bose–Einstein condensates

    NASA Astrophysics Data System (ADS)

    Mendonça, J. T.

    2016-07-01

    We derive a system of two coupled wave-kinetic equations for the condensate and for the thermal gas. This provides a simple and elegant model, based on a two fluid interaction, in the spirit of the traditional theory of superfluidity. One of the fluids is the condensed gas, and the other is the fluid of bogolon quasi-particles. As an illustration, we apply this wave-kinetic model to the description of the second-sound.

  19. KINETIC CONDENSATION AND EVAPORATION OF METALLIC IRON AND IMPLICATIONS FOR METALLIC IRON DUST FORMATION

    SciTech Connect

    Tachibana, Shogo; Nagahara, Hiroko; Ozawa, Kazuhito; Ikeda, Youhei; Nomura, Ryuichi; Tatsumi, Keisuke; Joh, Yui

    2011-07-20

    Metallic iron is one of the most abundant condensing materials in systems of solar abundance. Because metallic iron is responsible for the continuum opacity of dust particles, it has a large contribution to the thermal structure of circumstellar environments and hence to dust evolution itself. In order to understand the formation processes of metallic iron in circumstellar environments, condensation and evaporation kinetics of metallic iron were studied experimentally. Metallic iron condenses at the maximum rate with the condensation coefficient (a parameter ranging from 0 to 1 to represent kinetic hindrance for surface reaction) of unity under high supersaturation conditions, and evaporates nearly ideally (evaporation coefficient of unity) in vacuum. On the other hand, evaporation of metallic iron takes place with more kinetic hindrance in the presence of metallic iron vapor. It is also found that metallic iron atoms nucleate heterogeneously on Al{sub 2}O{sub 3}. Metallic iron does not necessarily condense homogeneously in circumstellar environments, but might condense through heterogeneous nucleation on pre-existing dust. Metallic iron formation proceeds with little kinetic hindrance for highly unequilibrated conditions, but the effects of kinetic hindrance may appear for evaporation and condensation occurring near equilibrium with a timescale of months to years in protoplanetary disks.

  20. Kinetic Evolution and Bose-Einstein Condensation in the Glasma

    NASA Astrophysics Data System (ADS)

    Liao, Jinfeng

    2013-10-01

    We study the evolution of a dense system of gluons, such as those produced in the early stages (the Glasma) of ultra-relativistic heavy ion collisions. We describe the approach to thermal equilibrium using the small angle approximation for gluon scattering in a Boltzmann equation that includes the effects of Bose statistics. Simple power counting arguments indicate that the gluon system as in the Glasma is over-occupied and driven towards the formation of a Bose-Einstein condensate. We derive and solve the transport equation for initial conditions that correspond to the overpopulated Glasma and present numerical evidence that such over-populated systems reach the onset of Bose-Einstein condensation in a finite time. The approach to condensation is characterized by a scaling behavior that we briefly analyze. Finally we analyze the effects of the inelastic, number changing, processes on the dynamical formation of the Bose-Einstein condensate by analytically deriving the 2 <--> 3 kernel under the collinear and small angle approximations and numerically solving it. References: J. Blaizot, J. Liao and L. McLerran, arXiv:1305.2119; X. Huang and J. Liao, arXiv:1303.7214; J. Blaizot, F. Gelis, J. Liao, L. McLerran and R. Venugopalan, arXiv:1107.5296. I thank the RIKEN BNL Research Center for partial support.

  1. The ZONMET thermodynamic and kinetic model of metal condensation

    NASA Astrophysics Data System (ADS)

    Petaev, Michail I.; Wood, John A.; Meibom, Anders; Krot, Alexander N.; Keil, Klaus

    2003-05-01

    The ZONMET model of metal condensation is a FORTRAN computer code that calculates condensation with partial isolation-type equilibrium partitioning of the 19 most abundant elements among 203 gaseous and 488 condensed phases and growth in the nebula of a zoned metal grain by condensation from the nebular gas accompanied by diffusional redistribution of Ni, Co, and Cr. Of five input parameters of the ZONMET model (chemical composition of the system expressed as the dust/gas [ D/ G] ratio, nebular pressure [ Ptot], isolation degree [ξ], cooling rate ( CR), and seed size), only two—the D/ G ratio and the CR of the nebular source region of a zoned Fe,Ni grain—are important in determining the grain radius and Ni, Co, and Cr zoning profiles. We found no evidence for the supercooling during condensation of Fe,Ni metal that is predicted by the homogeneous nucleation theory. The model allows estimates to be made of physicochemical parameters in the CH chondrite nebular source regions. Modeling growth and simultaneous diffusional redistribution of Ni, Co, and Cr in the zoned metal grains of CH chondrites reveals that the condensation zoning profiles were substantially modified by diffusion while the grains were growing in the nebula. This means that previous estimates of the physicochemical conditions in the nebular source regions of CH and CB chondrites, based on measured zoning profiles of Ni, Co, Cr, and platinum group elements in Fe,Ni metal grains, need to be corrected. The two zoned metal grains in the PAT 91456 and NWA 470 CH chondrites studied so far require nebular source regions with different chemical compositions ( D/ G = 1 and D/ G = 4, respectively) and thermal histories characterized by variable cooling rates ( CR = 0.011 + 0.0022 × Δ T K/h and CR = 0.05 + 0.0035 × Δ T K/h, respectively). It appears that the metal grains of the CH chondrites were formed in multiple nebular source regions or in different events within the same source region as the CB

  2. A Kinetic Approach to Bose-Einstein Condensates: Self-Phase Modulation and Bogoliubov Oscillations

    SciTech Connect

    Mendonca, J.T.; Bingham, R.; Shukla, P.K.

    2005-11-01

    A kinetic approach to Bose-Einstein condensates (BECs) is proposed based on the Wigner-Moyal equation (WME). In the semiclassical limit, the WME reduces to the particle-number conservation equation. Two examples of applications are (i) a self-phase modulation of a BE condensate beam, where we show that part of the beam is decelerated and eventually stops as a result of the gradient of the effective self-potential, and (ii) the derivation of a kinetic dispersion relation for sound waves in BECs, including collisionless Landau damping.

  3. Chemistry and kinetics of I2 loss in urine distillate and humidity condensate

    NASA Technical Reports Server (NTRS)

    Atwater, James E.; Wheeler, Richard R., Jr.; Olivadoti, J. T.; Sauer, Richard L.

    1992-01-01

    Time-resolved molecular absorption spectrophotometry of iodinated ersatz humidity condensates and iodinated ersatz urine distillates across the UV and visible spectral regions are used to investigate the chemistry and kinetics of I2 loss in urine distillate and humidity condensate. Single contaminant systems at equivalent concentrations are also employed to study rates of iodine. Pseudo-first order rate constants are identified for ersatz contaminant model mixtures and for individual reactive constituents. The second order bimolecular reaction of elemental iodine with formic acid, producing carbon dioxide and iodine anion, is identified as the primary mechanism underlying the decay of residual I2 in ersatz humidity concentrate.

  4. Numerical analysis of kinetic boundary conditions at net evaporation/condensation interfaces in various liquid temperatures based on mean-field kinetic theory

    NASA Astrophysics Data System (ADS)

    Kon, Misaki; Kobayashi, Kazumichi; Watanabe, Masao

    2014-12-01

    This study aims to investigate the liquid temperature dependency of the kinetic boundary condition at a vapor-liquid interface in net evaporation/condensation. The numerical simulations based on the mean-field kinetic theory and the molecular gas dynamics in the cases of various liquid temperatures were carried out. We focused on two important issues for the kinetic boundary condition; one is to investigate the applicable limit of the kinetic boundary condition which is assumed to be the isotropic velocity distribution at the liquid temperature and the other is to estimate the value of the condensation coefficient included in the kinetic boundary condition. The simulation results showed that the applicable limit of the isotropic velocity distribution in net evaporation/condensation practically independent from the liquid temperature. Furthermore, the condensation coefficients in net evaporation/condensation depend significantly on the liquid temperature; the condensation coefficient is constant and equal to the evaporation coefficient in net evaporation, while, in net condensation, the condensation coefficient increases with the increase of the degree of nonequilibrium.

  5. Mass accommodation of water: bridging the gap between molecular dynamics simulations and kinetic condensation models.

    PubMed

    Julin, Jan; Shiraiwa, Manabu; Miles, Rachael E H; Reid, Jonathan P; Pöschl, Ulrich; Riipinen, Ilona

    2013-01-17

    The condensational growth of submicrometer aerosol particles to climate relevant sizes is sensitive to their ability to accommodate vapor molecules, which is described by the mass accommodation coefficient. However, the underlying processes are not yet fully understood. We have simulated the mass accommodation and evaporation processes of water using molecular dynamics, and the results are compared to the condensation equations derived from the kinetic gas theory to shed light on the compatibility of the two. Molecular dynamics simulations were performed for a planar TIP4P-Ew water surface at four temperatures in the range 268-300 K as well as two droplets, with radii of 1.92 and 4.14 nm at T = 273.15 K. The evaporation flux from molecular dynamics was found to be in good qualitative agreement with that predicted by the simple kinetic condensation equations. Water droplet growth was also modeled with the kinetic multilayer model KM-GAP of Shiraiwa et al. [Atmos. Chem. Phys. 2012, 12, 2777]. It was found that, due to the fast transport across the interface, the growth of a pure water droplet is controlled by gas phase diffusion. These facts indicate that the simple kinetic treatment is sufficient in describing pure water condensation and evaporation. The droplet size was found to have minimal effect on the value of the mass accommodation coefficient. The mass accommodation coefficient was found to be unity (within 0.004) for all studied surfaces, which is in agreement with previous simulation work. Additionally, the simulated evaporation fluxes imply that the evaporation coefficient is also unity. Comparing the evaporation rates of the mass accommodation and evaporation simulations indicated that the high collision flux, corresponding to high supersaturation, present in typical molecular dynamics mass accommodation simulations can under certain conditions lead to an increase in the evaporation rate. Consequently, in such situations the mass accommodation coefficient

  6. Mass Accommodation of Water: Bridging the Gap Between Molecular Dynamics Simulations and Kinetic Condensation Models

    PubMed Central

    2012-01-01

    The condensational growth of submicrometer aerosol particles to climate relevant sizes is sensitive to their ability to accommodate vapor molecules, which is described by the mass accommodation coefficient. However, the underlying processes are not yet fully understood. We have simulated the mass accommodation and evaporation processes of water using molecular dynamics, and the results are compared to the condensation equations derived from the kinetic gas theory to shed light on the compatibility of the two. Molecular dynamics simulations were performed for a planar TIP4P-Ew water surface at four temperatures in the range 268–300 K as well as two droplets, with radii of 1.92 and 4.14 nm at T = 273.15 K. The evaporation flux from molecular dynamics was found to be in good qualitative agreement with that predicted by the simple kinetic condensation equations. Water droplet growth was also modeled with the kinetic multilayer model KM-GAP of Shiraiwa et al. [Atmos. Chem. Phys.2012, 117, 2777]. It was found that, due to the fast transport across the interface, the growth of a pure water droplet is controlled by gas phase diffusion. These facts indicate that the simple kinetic treatment is sufficient in describing pure water condensation and evaporation. The droplet size was found to have minimal effect on the value of the mass accommodation coefficient. The mass accommodation coefficient was found to be unity (within 0.004) for all studied surfaces, which is in agreement with previous simulation work. Additionally, the simulated evaporation fluxes imply that the evaporation coefficient is also unity. Comparing the evaporation rates of the mass accommodation and evaporation simulations indicated that the high collision flux, corresponding to high supersaturation, present in typical molecular dynamics mass accommodation simulations can under certain conditions lead to an increase in the evaporation rate. Consequently, in such situations the mass accommodation

  7. Kinetics of acid-catalyzed aldol condensation reactions of aliphatic aldehydes

    NASA Astrophysics Data System (ADS)

    Casale, Mia T.; Richman, Aviva R.; Elrod, Matthew J.; Garland, Rebecca M.; Beaver, Melinda R.; Tolbert, Margaret A.

    Field observations of atmospheric aerosols have established that organic compounds compose a large fraction of the atmospheric aerosol mass. However, the physical/chemical pathway by which organic compounds are incorporated into atmospheric aerosols remains unclear. The potential role of acid-catalyzed reactions of organic compounds on acidic aerosols has been explored as a possible chemical pathway for the incorporation of organic material into aerosols. In the present study, ultraviolet-visible (UV-vis) spectroscopy was used to monitor the kinetics of formation of the products of the acid-catalyzed aldol condensation reaction of a range of aliphatic aldehydes (C 2-C 8). The experiments were carried out at various sulfuric acid concentrations and a range of temperatures in order to estimate the rate constants of such reactions on sulfuric acid aerosols under tropospheric conditions. The rate constants were generally found to decrease as the chain length of the aliphatic aldehyde increased (except for acetaldehyde, which had an unusually small rate constant), increase as a function of sulfuric acid concentration as predicted by excess acidity theory, and showed normal Arrhenius behavior as a function of temperature. While the kinetic data are generally consistent with previous laboratory reports of aldehyde reactivity in various sulfuric acid media, the aldol condensation reactions involving aliphatic aldehydes do not appear fast enough to be responsible for significant transfer of organic material into atmospheric aerosols.

  8. Kinetics of Acid-Catalyzed Aldol Condensation Reactions of Aliphatic Aldehydes

    NASA Astrophysics Data System (ADS)

    Elrod, M. J.; Casale, M. T.; Richman, A. R.; Beaver, M. R.; Garland, R. M.; Tolbert, M. A.

    2006-12-01

    While it is well established that organic compounds compose a large fraction of the atmospheric aerosol mass, the mechanisms through which organics are incorporated into atmospheric aerosols are not well understood. Acid-catalyzed reactions of compounds with carbonyl groups have recently been suggested as important pathways for transfer of volatile organics into acidic aerosols. In the present study, ultraviolet-visible (UV-Vis) spectroscopy was used to monitor the kinetics of formation of the products of the aldol condensation reaction of a range of aliphatic aldehydes (C2-C8) The experiments were carried out at various sulfuric acid concentrations and a range of temperatures in order to estimate the rate constants of such reactions on sulfuric acid aerosols under tropospheric conditions. The rate constants were generally found to decrease as the chain length of the aliphatic aldehyde increased (except for acetaldehyde, which had an unusually small rate constant), increase as a function of sulfuric acid concentration as predicted by excess acidity theory, and showed normal Arrhenius behavior as a function of temperature.

  9. Magnon Kinetics and Bose-Einstein Condensation Studied in Phase Space

    SciTech Connect

    Demidov, V. E.; Dzyapko, O.; Buchmeier, M.; Demokritov, S. O.; Stockhoff, T.; Schmitz, G.; Melkov, G. A.

    2008-12-19

    Using a novel technique providing simultaneous resolution with respect to the wave vector and frequency of magnons, we observed the formation of a Bose-Einstein condensate documented by the narrowing of the magnon distribution in phase space. Based on the measured width of the distribution we determined the effective correlation length of the condensate, which appears to be anisotropic, reflecting the anisotropy of the magnon dispersion spectrum.

  10. A Knoevenagel Initiated Annulation Reaction Using Room Temperature or Microwave Conditions

    ERIC Educational Resources Information Center

    Cook, A. Gilbert

    2007-01-01

    An experiment is presented that has the student execute a Knoevenagel initiated annulation reaction. The reaction can be carried out either through use of a microwave reactor or by allowing the mixture to stand at room temperature for two days. The student is then challenged to identify the reaction product through a guided prelab exercise of the…

  11. Kinetic boundary layers in gas mixtures: Systems described by nonlinearly coupled kinetic and hydrodynamic equations and applications to droplet condensation and evaporation

    SciTech Connect

    Widder, M.E.; Titulaer, U.M. )

    1993-03-01

    The authors consider a mixture of heavy vapor molecules and a light carrier gas surrounding a liquid droplet. The vapor is described by a variant of the Klein-Kramers equation; the gas is described by the Navier-Stokes equations; the droplet acts as a heat source due to the released heat of condensation. The exchange of momentum and energy between the constituents of the mixture is taken into account by force terms in the kinetic equation and source terms in the Navier-Stokes equations. These are chosen to obtain maximal agreement with the irreversible thermodynamics of a gas mixture. The structure of the kinetic boundary layer around the sphere is determined from the self-consistent solution of this set of coupled equations with appropriate boundary conditions at the surface of the sphere. The kinetic equation is rewritten as a set of coupled moment equations. A complete set of solutions of these moment equations is constructed by numerical integration inward from the region far away from the droplet, where the background inhomogeneities are small. A technique developed earlier is used to deal with the numerical instability of the moment equations. The solutions obtained for given temperature and pressure profiles in the gas are then combined linearly such that they obey the boundary conditions at the droplet surface; from this solution source terms for the Navier-Stokes equation of the gas are constructed and used to determine improved temperature and pressure profiles for the background gas. For not too large temperature differneces between the droplet and the gas at infinity, self-consistency is reached after a few iterations. The method is applied to the condensation of droplets from a supersaturated vapor as well as to strong evaporation of droplets under the influence of an external heat source, where corrections of up to 40% are obtained.

  12. Thermal Desorption Kinetics of Volatiles on Silicate ``Smokes:'' Analog to Micrometeoric Impact Vapor Condensates

    NASA Astrophysics Data System (ADS)

    McLain, J. L.; Sarantos, M.; Johnson, N. M.; Keller, J. W.; Nuth, J. A.; Farrell, W. M.

    2015-11-01

    Laboratory measurements of the thermal desorption kinetics of Ar, H2O and other common lunar volatiles on silicate smokes will be presented, with a focus on comparing the desorption energies and surface chemistry with other regolith analogs.

  13. Kinetics of chromosome condensation in the presence of topoisomerases: a phantom chain model.

    PubMed Central

    Sikorav, J L; Jannink, G

    1994-01-01

    We discuss the requirement of type II DNA topoisomerase in the process of mitotic chromosome condensation. Using a known model describing the collapse of homopolymers, we propose that the compaction process necessitates a change in the topological state (i.e., a self-knotting) of the chromosomal chain. We argue that the enzymes are necessary to reach the compact metaphase state in a time interval that is much smaller than the time expected in the uncatalyzed process. The folding process is such that the potential entanglement points are localized at particular regions of the chromosome known as the scaffold-associated regions. The concentration of entanglements in the metaphase chromosome is related to the average size of the radial loops. A phantom chain model for the condensation process, in which each potential entanglement point is dealt with by a topoisomerase II molecule, is proposed. PMID:8011915

  14. Light-absorbing aldol condensation products in acidic aerosols: Spectra, kinetics, and contribution to the absorption index

    NASA Astrophysics Data System (ADS)

    Nozière, Barbara; Esteve, William

    The radiative properties of aerosols that are transparent to light in the near-UV and visible, such as sulfate aerosols, can be dramatically modified when mixed with absorbing material such as soot. In a previous work we had shown that the aldol condensation of carbonyl compounds produces light-absorbing compounds in sulfuric acid solutions. In this work we report the spectroscopic and kinetic parameters necessary to estimate the effects of these reactions on the absorption index of sulfuric acid aerosols in the atmosphere. The absorption spectra obtained from the reactions of six different carbonyl compounds (acetaldehyde, acetone, propanal, butanal, 2-butanone, and trifluoroacetone) and their mixtures were compared over 190-1100 nm. The results indicated that most carbonyl compounds should be able to undergo aldol condensation. The products are oligomers absorbing light in the 300-500 nm region where few other compounds absorb, making them important for the radiative properties of aerosols. Kinetic experiments in 96-75 wt% H 2SO 4 solutions and between 273 and 314 K gave an activation energy for the rate constant of formation of the aldol products of acetaldehyde of -(70±15) kJ mol -1 in 96 wt% solution and showed that the effect of acid concentration was exponential. A complete expression for this rate constant is proposed where the absolute value in 96 wt% H 2SO 4 and at 298 K is scaled to the Henry's law coefficient for acetaldehyde and the absorption cross-section for the aldol products assumed in this work. The absorption index of stratospheric sulfuric acid aerosols after a 2-year residence time was estimated to 2×10 -4, optically equivalent to a content of 0.5% of soot and potentially significant for the radiative forcing of these aerosols and for satellite observations in channels where the aldol products absorb.

  15. Bio-inspired immobilization of metal oxides on monolithic microreactor for continuous Knoevenagel reaction.

    PubMed

    Song, Wentong; Shi, Da; Tao, Shengyang; Li, Zhaoliang; Wang, Yuchao; Yu, Yongxian; Qiu, Jieshan; Ji, Min; Wang, Xinkui

    2016-11-01

    A facile method is reported to construct monolithic microreactor with high catalytic performance for Knoevenagel reaction. The microreactor is based on hierarchically porous silica (HPS) which has interconnected macro- and mesopores. Then the HPS is surface modified by pyrogallol (PG) polymer. Al(NO3)3 and Mg(NO3)2 are loaded on the surface of HPS through coordination with -OH groups of PG. After thermal treatment, Al(NO3)3 and Mg(NO3)2 are converted Al2O3 and MgO. The as-synthesized catalytic microreactor shows a high and stable performance in Knoevenagel reaction. The microreactor possess large surface area and interconnected pore structures which are beneficial for reactions. Moreover, this economic, facile and eco-friendly surface modification method can be used in loading more metal oxides for more reactions. PMID:27459172

  16. The carbon-bond mechanism: a condensed kinetic mechanism for photochemical smog

    SciTech Connect

    Whitten, G.Z.; Hog, H.; Killus, J.P.

    1980-06-01

    Efforts to develop a model that can simulate photochemical smog with kinetic mechanisms are discussed. The carbon-bond mechanism is a set of generalized reactions that can be used to model photochemical oxidant formation. The theoretical framework of carbon-bond mechanism is outlined. Chemical variables that are incorporated into the carbon-bond mechanism model are described. Further work that is needed on the carbon-bond mechanism model is considered. (1 diagram, 13 graphs, 30 references, 2 tables)

  17. Nonequilibrium fixed points in longitudinally expanding scalar theories: Infrared cascade, Bose condensation, and a challenge for kinetic theory

    NASA Astrophysics Data System (ADS)

    Berges, J.; Boguslavski, K.; Schlichting, S.; Venugopalan, R.

    2015-11-01

    In [Phys. Rev. Lett. 114, 061601 (2015)], we reported on a new universality class for longitudinally expanding systems, encompassing strongly correlated non-Abelian plasmas and N -component self-interacting scalar field theories. Using classical-statistical methods, we showed that these systems share the same self-similar scaling properties for a wide range of momenta in a limit where particles are weakly coupled but their occupancy is high. Here we significantly expand on our previous work and delineate two further self-similar regimes. One of these occurs in the deep infrared (IR) regime of very high occupancies, where the nonequilibrium dynamics leads to the formation of a Bose-Einstein condensate. The universal IR scaling exponents and the spectral index characterizing the isotropic IR distributions are described by an effective theory derived from a systematic large-N expansion at next-to-leading order. Remarkably, this effective theory can be cast as a vertex-resummed kinetic theory. The other novel self-similar regime occurs close to the hard physical scale of the theory, and sets in only at later times. We argue that the important role of the infrared dynamics ensures that key features of our results for scalar and gauge theories cannot be reproduced consistently in conventional kinetic theory frameworks.

  18. Nonequilibrium fixed points in longitudinally expanding scalar theories: Infrared cascade, Bose condensation and a challenge for kinetic theory

    DOE PAGESBeta

    Berges, J.; Schlichting, S.; Boguslavski, K.; Venugopalan, R.

    2015-11-05

    In [Phys. Rev. Lett. 114, 061601 (2015)], we reported on a new universality class for longitudinally expanding systems, encompassing strongly correlated non-Abelian plasmas and N-component self-interacting scalar field theories. Using classical-statistical methods, we showed that these systems share the same self-similar scaling properties for a wide range of momenta in a limit where particles are weakly coupled but their occupancy is high. Here we significantly expand on our previous work and delineate two further self-similar regimes. One of these occurs in the deep infrared (IR) regime of very high occupancies, where the nonequilibrium dynamics leads to the formation of amore » Bose-Einstein condensate. The universal IR scaling exponents and the spectral index characterizing the isotropic IR distributions are described by an effective theory derived from a systematic large-N expansion at next-to-leading order. Remarkably, this effective theory can be cast as a vertex-resummed kinetic theory. The other novel self-similar regime occurs close to the hard physical scale of the theory, and sets in only at later times. In this study, we argue that the important role of the infrared dynamics ensures that key features of our results for scalar and gauge theories cannot be reproduced consistently in conventional kinetic theory frameworks.« less

  19. Nonequilibrium fixed points in longitudinally expanding scalar theories: Infrared cascade, Bose condensation and a challenge for kinetic theory

    SciTech Connect

    Berges, J.; Schlichting, S.; Boguslavski, K.; Venugopalan, R.

    2015-11-05

    In [Phys. Rev. Lett. 114, 061601 (2015)], we reported on a new universality class for longitudinally expanding systems, encompassing strongly correlated non-Abelian plasmas and N-component self-interacting scalar field theories. Using classical-statistical methods, we showed that these systems share the same self-similar scaling properties for a wide range of momenta in a limit where particles are weakly coupled but their occupancy is high. Here we significantly expand on our previous work and delineate two further self-similar regimes. One of these occurs in the deep infrared (IR) regime of very high occupancies, where the nonequilibrium dynamics leads to the formation of a Bose-Einstein condensate. The universal IR scaling exponents and the spectral index characterizing the isotropic IR distributions are described by an effective theory derived from a systematic large-N expansion at next-to-leading order. Remarkably, this effective theory can be cast as a vertex-resummed kinetic theory. The other novel self-similar regime occurs close to the hard physical scale of the theory, and sets in only at later times. In this study, we argue that the important role of the infrared dynamics ensures that key features of our results for scalar and gauge theories cannot be reproduced consistently in conventional kinetic theory frameworks.

  20. Two-stream Maxwellian kinetic theory of cloud droplet growth by condensation

    NASA Technical Reports Server (NTRS)

    Robinson, N. F.; Scott, W. T.

    1981-01-01

    A new growth rate formula (NGRF) is developed for the rate of growth of cloud droplets by condensation. The theory used is a modification of the Lees-Shankar theory in which the two-stream Maxwellian distribution function of Lees is used in Maxwell's method of moments to determine the transport of water vapor to and heat away from the droplet. Boundary conditions at the droplet are the usual conditions set in terms of accommodation coefficients, and the solution passes smoothly into diffusion flow in the far region. Comparisons are given between NGRF and the conventional formula showing close agreement (approximately 0.1%) for large radii with significant difference (approximately 5%) for small radii (not greater than 1 micron). Growth times for haze droplets in a Laktionov chamber are computed.

  1. A numerical method for integrating the kinetic equations of droplet spectra evolution by condensation/evaporation and by coalescence/breakup processes

    NASA Technical Reports Server (NTRS)

    Emukashvily, I. M.

    1982-01-01

    An extension of the method of moments is developed for the numerical integration of the kinetic equations of droplet spectra evolution by condensation/evaporation and by coalescence/breakup processes. The number density function n sub k (x,t) in each separate droplet packet between droplet mass grid points (x sub k, x sub k+1) is represented by an expansion in orthogonal polynomials with a given weighting function. In this way droplet number concentrations, liquid water contents and other moments in each droplet packet are conserved and the problem of solving the kinetic equations is replaced by one of solving a set of coupled differential equations for the number density function moments. The method is tested against analytic solutions of the corresponding kinetic equations. Numerical results are obtained for different coalescence/breakup and condensation/evaporation kernels and for different initial droplet spectra. Also droplet mass grid intervals, weighting functions, and time steps are varied.

  2. Exploration of cellular DNA lesion, DNA-binding and biocidal ordeal of novel curcumin based Knoevenagel Schiff base complexes incorporating tryptophan: Synthesis and structural validation

    NASA Astrophysics Data System (ADS)

    Chandrasekar, Thiravidamani; Raman, Natarajan

    2016-07-01

    A few novel Schiff base transition metal complexes of general formula [MLCl] (where, L = Schiff base, obtained by the condensation reaction of Knoevenagel condensate of curcumin, L-tryptophan and M = Cu(II), Ni(II), Co(II), and Zn(II)), were prepared by stencil synthesis. They were typified using UV-vis, IR, EPR spectral techniques, micro analytical techniques, magnetic susceptibility and molar conductivity. Geometry of the metal complexes was examined and recognized as square planar. DNA binding and viscosity studies revealed that the metal(II) complexes powerfully bound via an intercalation mechanism with the calf thymus DNA. Gel-electrophoresis technique was used to investigate the DNA cleavage competence of the complexes and they establish to approve the cleavage of pBR322 DNA in presence of oxidant H2O2. This outcome inferred that the synthesized complexes showed better nuclease activity. Moreover, the complexes were monitored for antimicrobial activities. The results exposed that the synthesized compounds were forceful against all the microbes under exploration.

  3. Exploration of cellular DNA lesion, DNA-binding and biocidal ordeal of novel curcumin based Knoevenagel Schiff base complexes incorporating tryptophan: Synthesis and structural validation

    NASA Astrophysics Data System (ADS)

    Chandrasekar, Thiravidamani; Raman, Natarajan

    2016-07-01

    A few novel Schiff base transition metal complexes of general formula [MLCl] (where, L = Schiff base, obtained by the condensation reaction of Knoevenagel condensate of curcumin, L-tryptophan and M = Cu(II), Ni(II), Co(II), and Zn(II)), were prepared by stencil synthesis. They were typified using UV-vis, IR, EPR spectral techniques, micro analytical techniques, magnetic susceptibility and molar conductivity. Geometry of the metal complexes was examined and recognized as square planar. DNA binding and viscosity studies revealed that the metal(II) complexes powerfully bound via an intercalation mechanism with the calf thymus DNA. Gel-electrophoresis technique was used to investigate the DNA cleavage competence of the complexes and they establish to approve the cleavage of pBR322 DNA in presence of oxidant H2O2. This outcome inferred that the synthesized complexes showed better nuclease activity. Moreover, the complexes were monitored for antimicrobial activities. The results exposed that the synthesized compounds were forceful against all the microbes under exploration.

  4. Golden rule kinetics of transfer reactions in condensed phase: The microscopic model of electron transfer reactions in disordered solid matrices

    SciTech Connect

    Basilevsky, M. V.; Mitina, E. A.; Odinokov, A. V.; National Research Nuclear University “MEPhI,” 31, Kashirskoye shosse, Moscow ; Titov, S. V.

    2013-12-21

    kinetic regimes, which are usually postulated in the existing theories of the ET. Our alternative dynamic ET model for local modes immersed in the continuum harmonic medium is formulated for both classical and quantum regimes, and accounts explicitly for the mode/medium interaction. The kinetics of the energy exchange between the local ET subsystem and the surrounding environment essentially determine the total ET rate. The efficient computer code for rate computations is elaborated on. The computations are available for a wide range of system parameters, such as the temperature, external field, local mode frequency, and characteristics of mode/medium interaction. The relation of the present approach to the Marcus ET theory and to the quantum-statistical reaction rate theory [V. G. Levich and R. R. Dogonadze, Dokl. Akad. Nauk SSSR, Ser. Fiz. Khim. 124, 213 (1959); J. Ulstrup, Charge Transfer in Condensed Media (Springer, Berlin, 1979); M. Bixon and J. Jortner, Adv. Chem. Phys. 106, 35 (1999)] underlying it is discussed and illustrated by the results of computations for practically important target systems.

  5. Chitosan as a Renewable Heterogeneous Catalyst for the Knoevenagel Reaction in Ionic Liquid as Green Solvent

    PubMed Central

    Phan, Nam T. S.; Le, Ky K. A.; Nguyen, Thien V.; Le, Nhan T. H.

    2012-01-01

    The combination of chitosan as a renewable heterogeneous catalyst and ionic liquid as a “green” solvent was employed for the Knoevenagel reaction. The chitosan catalyst was characterized by various techniques, including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), and elemental analysis. Excellent conversions were achieved under mild conditions without the need for an inert atmosphere. There was no contribution from leached active species, and conversion was only being possible in the presence of the solid catalyst. The chitosan catalyst as well as the ionic liquid solvent could be recovered in essentially pure form after being used in the reaction, and each of them could be reused several times without a significant degradation in efficiency. PMID:24052856

  6. Kinetics and energy states of nanoclusters in the initial stage of homogeneous condensation at high supersaturation degrees

    SciTech Connect

    Vorontsov, A. G.; Gel'chinskii, B. R.; Korenchenko, A. E.

    2012-11-15

    The condensation of metal vapor in an inert gas is studied by the molecular dynamics method. Two condensation regimes are investigated: with maintenance of partial pressure of the metal vapor and with a fixed number of metal atoms in the system. The main focus is the study of the cluster energy distribution over the degrees of freedom and mechanisms of the establishment of thermal equilibrium. It is shown that the internal temperature of a cluster considerably exceeds the buffer gas temperature and the thermal balance is established for a time considerably exceeding the nucleation time. It is found that, when the metal vapor concentration exceeds 0.1 of the argon concentration, the growth of clusters with the highest possible internal energy occurs, the condensation rate being determined only by the rate of heat removal from clusters.

  7. TiCl4-promoted condensation of methyl acetoacetate, isobutyraldehyde, and indole: a theoretical and experimental study.

    PubMed

    Renzetti, Andrea; Marrone, Alessandro; Gérard, Stéphane; Sapi, Janos; Nakazawa, Hiroshi; Re, Nazzareno; Fontana, Antonella

    2015-04-14

    The mechanism of the TiCl4-promoted condensation of methyl acetoacetate, isobutyraldehyde, and indole was studied by a combination of theoretical and experimental techniques. The energy profile of plausible reaction paths was evaluated by DFT calculations, and various reaction intermediates were isolated or observed in solution by NMR spectroscopy. Theoretical and experimental results indicate that the reaction proceeds in three steps, all promoted by titanium: (1) formation of the enolate ion of methyl acetoacetate, (2) Knoevenagel condensation of the enolate ion and aldehyde, and (3) Michael addition of indole to the Knoevenagel adduct. The study sheds light on the role of titanium in the reaction, providing a mechanistic model for analogous reactions. PMID:25746215

  8. Kinetics and binding capacity of six soils for structurally defined hydrolyzable and condensed tannins and related phenols

    Technology Transfer Automated Retrieval System (TEKTRAN)

    We investigated tannin-soil interactions by assessing the kinetics of sorption and sorption capacities, and their relationship to the chemical properties of six polyphenolic compounds and the textures of six soils. We developed a new extraction procedure for recovering tannins from soil samples by ...

  9. The kinetics of the bimolecular A+B --> 0 reaction in condensed matter: Effects of non-equilibrium charge screening

    NASA Astrophysics Data System (ADS)

    Kuzovkov, V. N.; Kotomin, E. A.; von Niessen, W.

    1996-12-01

    The kinetics of the bimolecular A+B→0 reaction between charged reactants is studied in two dimensions, i.e., on a surface. The theory is based on the Kirkwood superposition approximation for three-particle densities and the self-consistent treatment of the electrostatic interactions defined by the non-uniform spatial distribution of similar and dissimilar reactants. Special attention is paid to pattern formation and many-particle effects arising from reaction-induced formation of loose domains containing similar reactants only. It is shown that the critical exponent α characterizing the algebraic concentration decay law, n(t)∝t-α, differs strongly between symmetric (DA=DB) and asymmetric (DA=0) reactant mobilities. This effect is abnormal from the point of view of standard chemical kinetics. It arises directly from the specific spatial distribution in the system as in ``raisins A in a dough B.'' At long reaction times the asymptotics of the interaction potentials is of non-equilibrium type at large relative distances. The accumulation kinetics in the presence of a permanent source is studied. Results of the microscopic formalism are compared with a previous mesoscopic theory.

  10. Heterogeneous oxidation of saturated organic aerosols by hydroxyl radicals: uptake kinetics, condensed-phase products, and particle size change

    NASA Astrophysics Data System (ADS)

    George, I. J.; Vlasenko, A.; Slowik, J. G.; Broekhuizen, K.; Abbatt, J. P. D.

    2007-08-01

    The kinetics and reaction mechanism for the heterogeneous oxidation of saturated organic aerosols by gas-phase OH radicals were investigated under NOx-free conditions. The reaction of 150 nm diameter Bis(2-ethylhexyl) sebacate (BES) particles with OH was studied as a proxy for chemical aging of atmospheric aerosols containing saturated organic matter. An aerosol reactor flow tube combined with an Aerodyne time-of-flight aerosol mass spectrometer (ToF-AMS) and scanning mobility particle sizer (SMPS) was used to study this system. Hydroxyl radicals were produced by 254 nm photolysis of O3 in the presence of water vapour. The kinetics of the heterogeneous oxidation of the BES particles was studied by monitoring the loss of a mass fragment of BES with the ToF-AMS as a function of OH exposure. We measured an initial OH uptake coefficient of γ0=1.3 (±0.4), confirming that this reaction is highly efficient. The density of BES particles increased by up to 20% of the original BES particle density at the highest OH exposure studied, consistent with the particle becoming more oxidized. Electrospray ionization mass spectrometry analysis showed that the major particle-phase reaction products are multifunctional carbonyls and alcohols with higher molecular weights than the starting material. Volatilization of oxidation products accounted for a maximum of 17% decrease of the particle volume at the highest OH exposure studied. Tropospheric organic aerosols will become more oxidized from heterogeneous photochemical oxidation, which may affect not only their physical and chemical properties, but also their hygroscopicity and cloud nucleation activity.

  11. Steady-state kinetics and inhibition studies of the aldol condensation reaction catalyzed by bovine liver and Escherichia coli 2-keto-4-hydroxyglutarate aldolase.

    PubMed

    Grady, S R; Wang, J K; Dekker, E E

    1981-04-28

    Two sensitive assays, one which fluorometrically measures only the L isomer of 2-keto-4-hydroxyglutarate after decarboxylation to L-malate and the other which spectrophotometrically determines both enantiomers by reductive amination with glutamate dehydrogenase, are described. By use of these assays, the steady-state kinetics of the aldol condensation of pyruvate with glyoxylate, as catalyzed by 2-keto-4-hydroxyglutarate aldolase from either bovine liver or Escherichia coli, were studied as was the inhibition of this reaction by glyoxylate and other anions. For the E. coli aldolase, double-reciprocal plots are linear except at high (above 5 mM) glyoxylate concentrations; apparent Km values increase with increasing concentrations of the fixed substrate. The data are consistent with an ordered reaction sequence. Inhibition by halides follows the lyotropic or Hofmeister series. Esters are not good inhibitors; mono-, di-, and tricarboxylic acids are increasingly inhibitory. Of the substrate analogues tested, hydroxypyruvate is the most potent inhibitor. Inhibition studies with citrate, acetaldehyde, and glyoxylate (all competitive inhibitors) suggest there are two domains at the active site-the Schiff base forming lysyl residue which interacts with carbonyl analogues (like acetaldehyde) and a center of positive charge which binds anions (like citrate). In contrast to the bacterial enzyme, liver 2-keto-4-hydroxyglutarate aldolase is inhibited in a competitive manner by much lower concentrations (0.1 mM or even lower) of glyoxylate. Many salts and some carboxylic acids activate the liver enzyme. Similarly, substrate analogues like 2-ketobutyrate and fluoropyruvate are mild activators; no effect is seen with acetaldehyde. Besides glyoxylate, only glyoxal, 2-ketoglutarate, and hydroxypyruvate inhibit the aldol condensation reaction. A uniform value of 1 is found for the number of inhibitor molecules bound per active site of either liver or E. coli 2-keto-4-hydroxyglutarate

  12. Cloud condensation nuclei activity, droplet growth kinetics, and hygroscopicity of biogenic and anthropogenic secondary organic aerosol (SOA)

    NASA Astrophysics Data System (ADS)

    Zhao, D. F.; Buchholz, A.; Kortner, B.; Schlag, P.; Rubach, F.; Fuchs, H.; Kiendler-Scharr, A.; Tillmann, R.; Wahner, A.; Watne, Å. K.; Hallquist, M.; Flores, J. M.; Rudich, Y.; Kristensen, K.; Hansen, A. M. K.; Glasius, M.; Kourtchev, I.; Kalberer, M.; Mentel, Th. F.

    2016-02-01

    Interaction of biogenic volatile organic compounds (VOCs) with Anthropogenic VOC (AVOC) affects the physicochemical properties of secondary organic aerosol (SOA). We investigated cloud droplet activation (CCN activity), droplet growth kinetics, and hygroscopicity of mixed anthropogenic and biogenic SOA (ABSOA) compared to pure biogenic SOA (BSOA) and pure anthropogenic SOA (ASOA). Selected monoterpenes and aromatics were used as representative precursors of BSOA and ASOA, respectively.

    We found that BSOA, ASOA, and ABSOA had similar CCN activity despite the higher oxygen to carbon ratio (O/C) of ASOA compared to BSOA and ABSOA. For individual reaction systems, CCN activity increased with the degree of oxidation. Yet, when considering all different types of SOA together, the hygroscopicity parameter, κCCN, did not correlate with O/C. Droplet growth kinetics of BSOA, ASOA, and ABSOA were comparable to that of (NH4)2SO4, which indicates that there was no delay in the water uptake for these SOA in supersaturated conditions.

    In contrast to CCN activity, the hygroscopicity parameter from a hygroscopic tandem differential mobility analyzer (HTDMA) measurement, κHTDMA, of ASOA was distinctively higher (0.09-0.10) than that of BSOA (0.03-0.06), which was attributed to the higher degree of oxidation of ASOA. The ASOA components in mixed ABSOA enhanced aerosol hygroscopicity. Changing the ASOA fraction by adding biogenic VOC (BVOC) to ASOA or vice versa (AVOC to BSOA) changed the hygroscopicity of aerosol, in line with the change in the degree of oxidation of aerosol. However, the hygroscopicity of ABSOA cannot be described by a simple linear combination of pure BSOA and ASOA systems. This indicates that additional processes, possibly oligomerization, affected the hygroscopicity.

    Closure analysis of CCN and HTDMA data showed κHTDMA was lower than κCCN by 30-70 %. Better closure was achieved for ASOA compared to BSOA. This

  13. Invited papers presented to a workshop on thermodynamics and kinetics of dust formation in the space medium. [condensation, nucleation, and interstellar dust

    NASA Technical Reports Server (NTRS)

    Robertson, P. C.

    1978-01-01

    Abstracts of 25 papers relating to condensation processes in the early solar system are presented. Special emphasis is given to the transition of an initial vapor phase in the space medium, the characterization of condensation environments, and condensation processes in the space medium. The question of whether some fraction of the solar system solids (particularly exemplified by meteoritic solids) may be interstellar grains that gathered in the region of the proto-sun, rather than being products of local condensation is addressed.

  14. Au@Cu(II)-MOF: Highly Efficient Bifunctional Heterogeneous Catalyst for Successive Oxidation-Condensation Reactions.

    PubMed

    Wang, Jing-Si; Jin, Fa-Zheng; Ma, Hui-Chao; Li, Xiao-Bo; Liu, Ming-Yang; Kan, Jing-Lan; Chen, Gong-Jun; Dong, Yu-Bin

    2016-07-01

    A new composite Au@Cu(II)-MOF catalyst has been synthesized via solution impregnation and full characterized by HRTEM, SEM-EDS, XRD, gas adsorption-desorption, XPS, and ICP analysis. It has been shown here that the Cu(II)-framework can be a useful platform to stabilize and support gold nanoparticles (Au NPs). The obtained Au@Cu(II)-MOF exhibits a bifunctional catalytic behavior and is able to promote selective aerobic benzyl alcohol oxidation-Knoevenagel condensation in a stepwise way. PMID:27322613

  15. Effects of pulling forces, osmotic pressure, condensing agents and viscosity on the thermodynamics and kinetics of DNA ejection from bacteriophages to bacterial cells: a computational study

    NASA Astrophysics Data System (ADS)

    Petrov, Anton S.; Douglas, Scott S.; Harvey, Stephen C.

    2013-03-01

    In this work, we report on simulations of double-stranded DNA (dsDNA) ejection from bacteriophage ϕ29 into a bacterial cell. The ejection was studied with a coarse-grained model, in which viral dsDNA was represented by beads on a torsion-less string. The bacteriophage’s capsid and the bacterial cell were defined by sets of spherical constraints. To account for the effects of the viscous medium inside the bacterial cell, the simulations were carried out using a Langevin dynamics protocol. Our simplest simulations (involving constant viscosity and no external biasing forces) produced results compatible with the push-pull model of DNA ejection, with an ejection rate significantly higher in the first part of ejection than in the latter parts. Additionally, we performed more complicated simulations, in which we included additional factors such as external forces, osmotic pressure, condensing agents and ejection-dependent viscosity. The effects of these factors (independently and in combination) on the thermodynamics and kinetics of DNA ejection were studied. We found that, in general, the dependence of ejection forces and ejection rates on the amount of DNA ejected becomes more complex if the ejection is modeled with a broader, more realistic set of parameters and influences (such as variation in the solvent’s viscosity and the application of an external force). However, certain combinations of factors and numerical parameters led to the opposition of some ejection-driving and ejection-inhibiting influences, ultimately causing an apparent simplification of the ejection profiles.

  16. Catalytic performance of Metal-Organic-Frameworks vs. extra-large pore zeolite UTL in condensation reactions

    PubMed Central

    Shamzhy, Mariya; Opanasenko, Maksym; Shvets, Oleksiy; Čejka, Jiří

    2013-01-01

    Catalytic behavior of isomorphously substituted B-, Al-, Ga-, and Fe-containing extra-large pore UTL zeolites was investigated in Knoevenagel condensation involving aldehydes, Pechmann condensation of 1-naphthol with ethylacetoacetate, and Prins reaction of β-pinene with formaldehyde and compared with large-pore aluminosilicate zeolite beta and representative Metal-Organic-Frameworks Cu3(BTC)2 and Fe(BTC). The yield of the target product over the investigated catalysts in Knoevenagel condensation increases in the following sequence: (Al)beta < (Al)UTL < (Ga)UTL < (Fe)UTL < Fe(BTC) < (B)UTL < Cu3(BTC)2 being mainly related to the improving selectivity with decreasing strength of active sites of the individual catalysts. The catalytic performance of Fe(BTC), containing the highest concentration of Lewis acid sites of the appropriate strength is superior over large-pore zeolite (Al)beta and B-, Al-, Ga-, Fe-substituted extra-large pore zeolites UTL in Prins reaction of β-pinene with formaldehyde and Pechmann condensation of 1-naphthol with ethylacetoacetate. PMID:24790940

  17. CONDENSATION CAN

    DOEpatents

    Booth, E.T. Jr.; Pontius, R.B.; Jacobsohn, B.A.; Slade, C.B.

    1962-03-01

    An apparatus is designed for condensing a vapor to a solid at relatively low back pressures. The apparatus comprises a closed condensing chamber, a vapor inlet tube extending to the central region of the chamber, a co-axial tubular shield surrounding the inlet tube, means for heating the inlet tube at a point outside the condensing chamber, and means for refrigeratirg the said chamber. (AEC)

  18. Preparation of acid-base bifunctional mesoporous KIT-6 (KIT: Korea Advanced Institute of Science and Technology) and its catalytic performance in Knoevenagel reaction

    SciTech Connect

    Xu, Ling; Wang, Chunhua; Guan, Jingqi

    2014-05-01

    Acid-base bifunctional mesoporous catalysts Al-KIT-6-NH{sub 2} containing different aluminum content have been synthesized through post synthetic grafting method. The materials were characterized by X-ray diffraction (XRD), scanning electron micrographs (SEM), transmission electron micrographs (TEM), Fourier-transform infrared spectroscopy (FTIR), IR spectra of pyridine adsorption, NH{sub 3}-TPD and TG analysis. The characterization results indicated that the pore structure of KIT-6 was well kept after the addition of aluminum and grafting of aminopropyl groups. The acid amount of Al-KIT-6 increased with enhancing aluminum content. Catalytic results showed that weak acid and weak base favor the Knoevenagel reaction, while catalysts with strong acid and weak base exhibited worse catalytic behavior. - Graphical abstract: The postulated steps of mechanism for the acid-base catalyzed process are as follows: (1) the aldehyde gets activated by the surface acidic sites which allow the amine undergoes nucleophilic to attack the carbonyl carbon of benzaldehyde. (2) Water is released in the formation of imine intermediate. (3) The ethyl cyanoacetate reacts with the intermediate. (4) The benzylidene ethyl cyanoacetate is formed and the amine is regenerated. - Highlights: • KIT-6 and Al-KIT-6-NH{sub 2} with different Si/Al ratios has been successfully prepared. • 79.4% Yield was obtained over 46-Al-KIT-6-NH{sub 2} within 20 min in Knoevenagel reaction. • Low Al-content Al-KIT-6-NH{sub 2} shows better catalytic stability than high Al-content catalysts. • There is acid-base synergistic effect in Knoevenagel reaction.

  19. Synthesis of magnetically recyclable ZIF-8@SiO{sub 2}@Fe{sub 3}O{sub 4} catalysts and their catalytic performance for Knoevenagel reaction

    SciTech Connect

    Li, Qingyuan; Jiang, Sai; Ji, Shengfu Ammar, Muhammad; Zhang, Qingmin; Yan, Junlei

    2015-03-15

    Novel magnetic ZIF-8@SiO{sub 2}@Fe{sub 3}O{sub 4} catalysts were synthesized by encapsulating magnetic SiO{sub 2}@Fe{sub 3}O{sub 4} nanoparticles into ZIF-8 through in situ method. The structures of the catalysts were characterized by TEM, SEM, XRD, FT-IR, VSM, N{sub 2} adsorption/desorption and CO{sub 2}-TPD technology. The catalytic activity and recovery properties of the catalysts for the Knoevenagel reaction of p-chlorobenzaldehyde with malononitrile were evaluated. The results showed that the magnetic ZIF-8@SiO{sub 2}@Fe{sub 3}O{sub 4} catalysts had the larger surface areas, the suitable superparamagnetism, and good catalytic activity for Knoevenagel reaction. The conversion of p-chlorobenzaldehyde can reach ~98% and the selectivity of the production can reach ~99% over35.8%ZIF-8@SiO{sub 2}@Fe{sub 3}O{sub 4} (MZC-5) catalyst under the reaction condition of 25 °C and 4 h. The magnetic ZIF-8@SiO{sub 2}@Fe{sub 3}O{sub 4} catalysts also had good substrates adaptation. After reaction, the catalyst can be easily separated from the reaction mixture by an external magnet. The recovery catalyst can be reused five times and the conversion of p-chlorobenzaldehyde can be kept over 90%. - Graphical abstract: Novel magnetically recyclable ZIF-8@SiO{sub 2}@Fe{sub 3}O{sub 4} catalysts were synthesized by encapsulating magnetic SiO{sub 2}@Fe{sub 3}O{sub 4} nanoparticles into ZIF-8 and the as-synthesized catalysts exhibited a good catalytic activity for the Knoevenagel reaction. - Highlights: • A series of novel magnetic ZIF-8@SiO{sub 2}@Fe{sub 3}O{sub 4} catalysts were synthesized. • The catalysts had the larger surface areas and the suitable superparamagnetism. • The catalysts exhibited good catalytic activity for the Knoevenagel reaction. • After reaction the catalyst can be easily separated by an external magnet. • The recovery catalyst can be reused five times and can keep its catalytic activity.

  20. Condensation polyimides

    NASA Technical Reports Server (NTRS)

    Hergenrother, P. M.

    1989-01-01

    Polyimides belong to a class of polymers known as polyheterocyclics. Unlike most other high temperature polymers, polyimides can be prepared from a variety of inexpensive monomers by several synthetic routes. The glass transition and crystalline melt temperature, thermooxidative stability, toughness, dielectric constant, coefficient of thermal expansion, chemical stability, mechanical performance, etc. of polyimides can be controlled within certain boundaries. This versatility has permitted the development of various forms of polyimides. These include adhesives, composite matrices, coatings, films, moldings, fibers, foams and membranes. Polyimides are synthesized through both condensation (step-polymerization) and addition (chain growth polymerization) routes. The precursor materials used in addition polyimides or imide oligomers are prepared by condensation method. High molecular weight polyimide made via polycondensation or step-growth polymerization is studied. The various synthetic routes to condensation polyimides, structure/property relationships of condensation polyimides and composite properties of condensation polyimides are all studied. The focus is on the synthesis and chemical structure/property relationships of polyimides with particular emphasis on materials for composite application.

  1. Rapid access to novel 1,2,3-triazolo-heterocyclic scaffolds via tandem Knoevenagel condensation/azide-alkyne 1,3-dipolar cycloaddition reaction in one pot.

    PubMed

    Maurya, Ram Awatar; Adiyala, Praveen Reddy; Chandrasekhar, D; Reddy, Chada Narsimha; Kapure, Jeevak Sopanrao; Kamal, Ahmed

    2014-09-01

    An operationally simple, one-pot, two-step cascade method has been developed to afford biologically important fused 1,2,3-triazolo-heterocyclic scaffolds from 2-alkynyl aryl(heteroaryl) aldehydes and phenacyl azides. This unique atom economical transformation engages four reactive centers (aldehyde, alkyne, active methylene, and azide) under metal-free catalysis. PMID:24945583

  2. Acidic Condensation of BODIPYs with Aldehydes: A Quick and Versatile Route to Alkenyl-BODIPYs and C(sp(3) )-Connected DYEmers.

    PubMed

    Ahrens, Johannes; Cordes, Birte; Wicht, Richard; Wolfram, Benedikt; Bröring, Martin

    2016-07-18

    The condensation of aldehydes with BODIPY (boron dipyrrin) luminophores was investigated. Formaldehyde can be used to connect two BODIPYs at each of the three pyrrolic C positions (α-, β-, and β'-positions) in a quick and highly selective manner, yielding new DYEmers (di- and oligomeric BODIPY derivatives) with varied photophysical properties. Benzaldehydes form DYEmers only at the β- and the β'-positions. For aliphatic aldehydes the DYEmer formation competes with the elimination of water from a proposed alcohol intermediate, leading to the formation of α- and β-alkenyl-BODIPYs. 2-Phenylacetaldehyde and similar precursors exclusively yield elimination products. These acid-mediated transformations are valuable alternatives to the well-established, base-promoted Knoevenagel condensation protocol that is typically employed in the preparation of BODIPYs with near infrared (NIR)-shifted absorptions. PMID:27140934

  3. The Complete Mechanism of an Aldol Condensation.

    PubMed

    Perrin, Charles L; Chang, Kuei-Lin

    2016-07-01

    Although aldol condensation is one of the most important organic reactions, capable of forming new C-C bonds, its mechanism has never been fully established. We now conclude that the rate-limiting step in the base-catalyzed aldol condensation of benzaldehydes with acetophenones, to produce chalcones, is the final loss of hydroxide and formation of the C═C bond. This conclusion is based on a study of the partitioning ratios of the intermediate ketols and on the solvent kinetic isotope effects, whereby the condensations are faster in D2O than in H2O, regardless of substitution. PMID:27281298

  4. Condensation model for the ESBWR passive condensers

    SciTech Connect

    Revankar, S. T.; Zhou, W.; Wolf, B.; Oh, S.

    2012-07-01

    In the General Electric's Economic simplified boiling water reactor (GE-ESBWR) the passive containment cooling system (PCCS) plays a major role in containment pressure control in case of an loss of coolant accident. The PCCS condenser must be able to remove sufficient energy from the reactor containment to prevent containment from exceeding its design pressure following a design basis accident. There are three PCCS condensation modes depending on the containment pressurization due to coolant discharge; complete condensation, cyclic venting and flow through mode. The present work reviews the models and presents model predictive capability along with comparison with existing data from separate effects test. The condensation models in thermal hydraulics code RELAP5 are also assessed to examine its application to various flow modes of condensation. The default model in the code predicts complete condensation well, and basically is Nusselt solution. The UCB model predicts through flow well. None of condensation model in RELAP5 predict complete condensation, cyclic venting, and through flow condensation consistently. New condensation correlations are given that accurately predict all three modes of PCCS condensation. (authors)

  5. Gluon transport equations with condensate in the small angle approximation

    NASA Astrophysics Data System (ADS)

    Blaizot, Jean-Paul; Liao, Jinfeng

    2016-05-01

    We derive the set of kinetic equations that control the evolution of gluons in the presence of a condensate. We show that the dominant singularities remain logarithmic when the scattering involves particles in the condensate. This allows us to define a consistent small angle approximation.

  6. Optimizing process vacuum condensers

    SciTech Connect

    Lines, J.R.; Tice, D.W.

    1997-09-01

    Vacuum condensers play a critical role in supporting vacuum processing operations. Although they may appear similar to atmospheric units, vacuum condensers have their own special designs, considerations and installation needs. By adding vacuum condensers, precondensers and intercondensers, system cost efficiency can be optimized. Vacuum-condensing systems permit reclamation of high-value product by use of a precondenser, or reduce operating costs with intercondensers. A precondenser placed between the vacuum vessel and ejector system will recover valuable process vapors and reduce vapor load to an ejector system--minimizing the system`s capital and operating costs. Similarly, an intercondenser positioned between ejector stages can condense motive steam and process vapors and reduce vapor load to downstream ejectors as well as lower capital and operating costs. The paper describes vacuum condenser systems, types of vacuum condensers, shellside condensing, tubeside condensing, noncondensable gases, precondenser pressure drop, system interdependency, equipment installation, and equipment layout.

  7. Condensate Mixtures and Tunneling

    SciTech Connect

    Timmermans, E.

    1998-09-14

    The experimental study of condensate mixtures is a particularly exciting application of the recently developed atomic-trap Bose-Einstein condensate (BEC) technology: such multiple condensates represent the first laboratory systems of distinguishable boson superfluid mixtures. In addition, as the authors point out in this paper, the possibility of inter-condensate tunneling greatly enhances the richness of the condensate mixture physics. Not only does tunneling give rise to the oscillating particle currents between condensates of different chemical potentials, such as those studied extensively in the condensed matter Josephson junction experiments, it also affects the near-equilibrium dynamics and stability of the condensate mixtures. In particular, the stabilizing influence of tunneling with respect to spatial separation (phase separation) could be of considerable practical importance to the atomic trap systems. Furthermore, the creation of mixtures of atomic and molecular condensates could introduce a novel type of tunneling process, involving the conversion of a pair of atomic condensate bosons into a single molecular condensate boson. The static description of condensate mixtures with such type of pair tunneling suggests the possibility of observing dilute condensates with the liquid-like property of a self-determined density.

  8. Condensates in Jovian Atmospheres

    NASA Technical Reports Server (NTRS)

    West, R.

    1999-01-01

    Thermochemical equilibrium theory which starts with temperature/pressure profiles, compositional information and thermodynamic data for condensable species in the jovian planet atmospheres predicts layers of condensate clouds in the upper troposphere.

  9. THERMOCHEMISTRY AND KINETICS OF SULFUR CONTAINING MOLECULES AND RADICALS

    EPA Science Inventory

    The relevant thermochemistry of sulfur oxides is discussed, and selected 'best' thermochemical values for use in kinetic systems are presented. Although the kinetics of air pollution and combustion involve mostly homogeneous gas phase reactions, the data taken from condensed phas...

  10. Boundary conditions on the vapor liquid interface at strong condensation

    NASA Astrophysics Data System (ADS)

    Kryukov, A. P.; Levashov, V. Yu.

    2016-07-01

    The problem of the formulation of boundary conditions on the vapor-liquid interface is considered. The different approaches to this problem and their difficulties are discussed. Usually, a quasi-equilibrium scheme is used. At sufficiently large deviations from thermodynamic equilibrium, a molecular kinetics approach should be used for the description of the vapor flow at condensation. The formulation of the boundary conditions at the vapor liquid interface to solve the Boltzmann kinetic equation for the distribution of molecules by velocity is a sophisticated problem. It appears that molecular dynamics simulation (MDS) can be used to provide this solution at the interface. The specific problems occur in the realization of MDS on large time and space scales. Some of these problems, and a hierarchy of continuum, kinetic and molecular dynamic time scales, are discussed in the paper. A description of strong condensation at the kinetic level is presented for the steady one-dimensional problem. A formula is provided for the calculation of the limiting condensation coefficient. It is shown that as the condensation coefficient approaches the limiting value, the vapor pressure rises significantly. The results of the corresponding calculations for the Mach number and temperature at different vapor flows are demonstrated. As a result of the application of the molecular kinetics method and molecular dynamics simulation to the problem of the determination of argon condensation coefficients in the range of temperatures of vapor and liquid ratio 1.0-4.0, it is concluded that the condensation coefficient is close to unity.

  11. Evolutionary games of condensates in coupled birth-death processes

    NASA Astrophysics Data System (ADS)

    Weber, Markus F.; Knebel, Johannes; Krueger, Torben; Frey, Erwin

    2015-03-01

    Condensation phenomena occur in many systems, both in a classical and a quantum mechanical context. Typically, the entities that constitute a system collectively concentrate in one distinct state during condensation. For example, cooling of an equilibrated bosonic gas may lead to condensation into the quantum ground state. Notably, the mathematical theory of this Bose-Einstein condensation is not limited to quantum theory but was also successfully applied to condensation in random networks. In our work, we follow the opposite path. We apply the theory of evolutionary dynamics to describe condensation in a bosonic system that is driven and dissipative. It was shown that the system may condense into multiple quantum states, but into which states has remained elusive. We find that vanishing of relative entropy production determines these states. We illuminate the physical principles underlying the condensation and show that the condensates do not need to be static but may engage in ``evolutionary games'' with exchange of particles. On the mathematical level, the condensation is described by coupled birth-death processes. The generic structure of these processes implies that our results also apply to condensation in other systems, ranging from population biology to chemical kinetics.

  12. Polycondensation kinetics of furfuryl alcohol solutions

    NASA Astrophysics Data System (ADS)

    Zherebtsov, D. A.; Galimov, D. M.; Zagorul'ko, O. V.; Frolova, E. V.; Bol'shakov, O. I.; Zakharov, V. G.; Mikhailov, G. G.

    2016-01-01

    Changes in the viscosity, electrical conductivity, monomer concentration, and the size of growing molecules of polycondensed furfuryl alcohol are studied in solutions containing triethylene glycol and isooctylphenyldecaethylene glycol. The effect the solution compositions have on the condensation kinetics is considered.

  13. Homogeneous gas-phase formation of polychlorinated naphthalene from dimerization of 4-chlorophenoxy radicals and cross-condensation of phenoxy radical with 4-chlorophenoxy radical: Mechanism and kinetics study

    NASA Astrophysics Data System (ADS)

    Xu, Fei; Zhang, Ruiming; Li, Yunfeng; Zhang, Qingzhu

    2015-10-01

    A direct density functional theory (DFT) calculation was performed for the formation of polychlorinated naphthalenes (PCNs) from dimerization of 4-chlorophenoxy radicals (4-CPRs) and cross-condensation of phenoxy radical (PhR) with 4-CPR, respectively. Several energetically feasible formation routes were proposed. The rate constants were computed by the canonical variational transition-state theory (CVT) with the small curvature tunneling (SCT) contribution over temperature range of 600-1200 K. This study shows that PCN productions from the dimerization of 4-CPRs just contain DCNs. All the monochlorinated naphthalene (MCN) detected in the experiment from 4-chlorophenol (4-CP) as precursor are formed form the cross-condensation of PhR with 4-CPR.

  14. Comparative analysis of condensation models within DSMC

    SciTech Connect

    Bykov, Nikolay Y.; Gorbachev, Yuriy E.

    2014-12-09

    Two condensation process modeling approaches within DSMC methodology are compared. The first is based on the modified nucleation theory which correctly describes small clusters and the second on the kinetic theory and considers not only supercritical clusters, but clusters of all sizes including dimers. The relaxation of the size distribution function is calculated for the spatially homogeneous cases, where the monomer parameters are kept constant. As an example the vapour of Cu atoms is considered and importance of taking into account of the internal energies of clusters is shown. Peculiarities of the classical and kinetic approaches are discussed herein.

  15. Aerosol kinetic code "AERFORM": Model, validation and simulation results

    NASA Astrophysics Data System (ADS)

    Gainullin, K. G.; Golubev, A. I.; Petrov, A. M.; Piskunov, V. N.

    2016-06-01

    The aerosol kinetic code "AERFORM" is modified to simulate droplet and ice particle formation in mixed clouds. The splitting method is used to calculate condensation and coagulation simultaneously. The method is calibrated with analytic solutions of kinetic equations. Condensation kinetic model is based on cloud particle growth equation, mass and heat balance equations. The coagulation kinetic model includes Brownian, turbulent and precipitation effects. The real values are used for condensation and coagulation growth of water droplets and ice particles. The model and the simulation results for two full-scale cloud experiments are presented. The simulation model and code may be used autonomously or as an element of another code.

  16. Measure Guideline: Evaporative Condensers

    SciTech Connect

    German, A; Dakin, B.; Hoeschele, M.

    2012-03-01

    This measure guideline on evaporative condensers provides information on properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices.

  17. Geothermal steam condensate reinjection

    NASA Technical Reports Server (NTRS)

    Chasteen, A. J.

    1974-01-01

    Geothermal electric generating plants which use condensing turbines and generate and excess of condensed steam which must be disposed of are discussed. At the Geysers, California, the largest geothermal development in the world, this steam condensate has been reinjected into the steam reservoir since 1968. A total of 3,150,000,000 gallons of steam condensate has been reinjected since that time with no noticeable effect on the adjacent producing wells. Currently, 3,700,000 gallons/day from 412 MW of installed capacity are being injected into 5 wells. Reinjection has also proven to be a satisfactory method of disposing of geothermal condensate a Imperial Valley, California, and at the Valles Caldera, New Mexico.

  18. Freeze-Tolerant Condensers

    NASA Technical Reports Server (NTRS)

    Crowley, Christopher J.; Elkouhk, Nabil

    2004-01-01

    Two condensers designed for use in dissipating heat carried by working fluids feature two-phase, self-adjusting configurations such that their working lengths automatically vary to suit their input power levels and/or heat-sink temperatures. A key advantage of these condensers is that they can function even if the temperatures of their heat sinks fall below the freezing temperatures of their working fluids and the fluids freeze. The condensers can even be restarted from the frozen condition. The top part of the figure depicts the layout of the first condenser. A two-phase (liquid and vapor) condenser/vapor tube is thermally connected to a heat sink typically, a radiatively or convectively cooled metal panel. A single-phase (liquid) condensate-return tube (return artery) is also thermally connected to the heat sink. At intervals along their lengths, the condenser/vapor tube and the return artery are interconnected through porous plugs. This condenser configuration affords tolerance of freezing, variable effective thermal conductance (such that the return temperature remains nearly constant, independently of the ultimate sink temperature), and overall pressure drop smaller than it would be without the porous interconnections. An additional benefit of this configuration is that the condenser can be made to recover from the completely frozen condition either without using heaters, or else with the help of heaters much smaller than would otherwise be needed. The second condenser affords the same advantages and is based on a similar principle, but it has a different configuration that affords improved flow of working fluid, simplified construction, reduced weight, and faster recovery from a frozen condition.

  19. Sub-Equimolar Hydrolysis and Condensation of Organophosphates

    DOE PAGESBeta

    Alam, Todd M.; Kinnan, Mark K.; Wilson, Brendan W.; Wheeler, David R.

    2016-07-16

    We characterized the in-situ hydrolysis and subsequent condensation reaction of the chemical agent simulant diethyl chlorophosphate (DECP) by high-resolution 31P NMR spectroscopy following the addition of water in sub-equimolar concentrations. Moreover, the identification and quantification of the multiple pyrophosphate and larger polyphosphate chemical species formed through a series of self-condensation reactions are reported. Finally, the DECP hydrolysis kinetics and distribution of breakdown species was strongly influenced by the water concentration and reaction temperature.

  20. Alpha Condensates in Atomic Nuclei

    SciTech Connect

    Suzuki, Y.; Matsumura, H.

    2005-11-21

    Recent issues on Bose-Einstein condensation (BEC) of {alpha}-particles in nuclei are reviewed. A candidate of condensates is discussed for some states in 12C and 16O by defining the amount of {alpha} condensation.

  1. Sedimentary condensation and authigenesis

    NASA Astrophysics Data System (ADS)

    Föllmi, Karl

    2016-04-01

    Most marine authigenic minerals form in sediments, which are subjected to condensation. Condensation processes lead to the formation of well individualized, extremely thin (< 1m) beds, which were accumulated during extremely long time periods (> 100ky), and which experienced authigenesis and the precipitation of glaucony, verdine, phosphate, iron and manganese oxyhydroxides, iron sulfide, carbonate and/or silica. They usually show complex internal stratigraphies, which result from an interplay of sediment accumulation, halts in sedimentation, sediment winnowing, erosion, reworking and bypass. They may include amalgamated faunas of different origin and age. Hardgrounds may be part of condensed beds and may embody strongly condensed beds by themselves. Sedimentary condensation is the result of a hydrodynamically active depositional regime, in which sediment accumulation, winnowing, erosion, reworking and bypass are processes, which alternate as a function of changes in the location and intensity of currents, and/or as the result of episodic high-energy events engendered by storms and gravity flow. Sedimentary condensation has been and still is a widespread phenomenon in past and present-day oceans. The present-day distribution of glaucony and verdine-rich sediments on shelves and upper slopes, phosphate-rich sediments and phosphorite on outer shelves and upper slopes, ferromanganese crusts on slopes, seamounts and submarine plateaus, and ferromanganese nodules on abyssal seafloors is a good indication of the importance of condensation processes today. In the past, we may add the occurrence of oolitic ironstone, carbonate hardgrounds, and eventually also silica layers in banded iron formations as indicators of the importance of condensation processes. Besides their economic value, condensed sediments are useful both as a carrier of geochemical proxies of paleoceanographic and paleoenvironmental change, as well as the product of episodes of paleoceanographic and

  2. Electrolyte vapor condenser

    DOEpatents

    Sederquist, Richard A.; Szydlowski, Donald F.; Sawyer, Richard D.

    1983-01-01

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

  3. Electrolyte vapor condenser

    DOEpatents

    Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

    1983-02-08

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

  4. Ghost condensate busting

    SciTech Connect

    Bilic, Neven; Tupper, Gary B; Viollier, Raoul D E-mail: gary.tupper@uct.ac.za

    2008-09-15

    Applying the Thomas-Fermi approximation to renormalizable field theories, we construct ghost condensation models that are free of the instabilities associated with violations of the null-energy condition.

  5. Measure Guideline: Evaporative Condensers

    SciTech Connect

    German, A.; Dakin, B.; Hoeschele, M.

    2012-03-01

    The purpose of this measure guideline on evaporative condensers is to provide information on a cost-effective solution for energy and demand savings in homes with cooling loads. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices. This document has been prepared to provide a process for properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs.

  6. Condensate dark matter stars

    SciTech Connect

    Li, X.Y.; Harko, T.; Cheng, K.S. E-mail: harko@hkucc.hku.hk

    2012-06-01

    We investigate the structure and stability properties of compact astrophysical objects that may be formed from the Bose-Einstein condensation of dark matter. Once the critical temperature of a boson gas is less than the critical temperature, a Bose-Einstein Condensation process can always take place during the cosmic history of the universe. Therefore we model the dark matter inside the star as a Bose-Einstein condensate. In the condensate dark matter star model, the dark matter equation of state can be described by a polytropic equation of state, with polytropic index equal to one. We derive the basic general relativistic equations describing the equilibrium structure of the condensate dark matter star with spherically symmetric static geometry. The structure equations of the condensate dark matter stars are studied numerically. The critical mass and radius of the dark matter star are given by M{sub crit} ≈ 2(l{sub a}/1fm){sup 1/2}(m{sub χ}/1 GeV){sup −3/2}M{sub s}un and R{sub crit} ≈ 1.1 × 10{sup 6}(l{sub a}/1 fm){sup 1/2}(m{sub χ}/1 GeV){sup −3/2} cm respectively, where l{sub a} and m{sub χ} are the scattering length and the mass of dark matter particle, respectively.

  7. On the nature of Bose-Einstein condensation enhanced by localization

    SciTech Connect

    Jaeck, Thomas; Pule, Joseph V.; Zagrebnov, Valentin A.

    2010-10-15

    In a previous paper we established that for the perfect Bose gas and the mean-field Bose gas with an external random or weak potential, whenever there is generalized Bose-Einstein condensation in the eigenstates of the single particle Hamiltonian, there is also generalized condensation in the kinetic-energy states. In these cases Bose-Einstein condensation is produced or enhanced by the external potential. In the present paper we establish a criterion for the absence of condensation in single kinetic-energy states and prove that this criterion is satisfied for a class of random potentials and weak potentials. This means that the condensate is spread over an infinite number of states with low kinetic-energy without any of them being macroscopically occupied.

  8. Enhanced condensation heat transfer

    NASA Astrophysics Data System (ADS)

    Michel, J. W.; Murphy, R. W.

    1980-07-01

    Work has centered on optimizing the design variables associated with fluted surfaces on vertical tubes and comparing the tube performance with available enhanced tubes either for vertical or horizontal operation. Data with seven fluids including a hydrocarbon, fluorocarbons, and ammonia condensing on up to 30 different tubes were obtained. Data for tubes of different effective lengths (1/2 to 4 ft) and inclination were also obtained. The primary conclusion is that the best fluted tubes can provide an enhancement in condensation coefficient by a factor of approximately 6 over smooth vertical tube performance and a factor of approximately 2 over the best enhanced commercial tubes either operating vertically or horizontally. These data, together with field test data, have formed the basis for designing two prototype condensers, one for the 60 kWe Raft River, Idaho, pilot plant and one for the 500 kWe East Mesa, California, direct contact demonstration plant.

  9. Keeping condensers clean

    SciTech Connect

    Wicker, K.

    2006-04-15

    The humble condenser is among the biggest contributors to a steam power plant's efficiency. But although a clean condenser can provide great economic benefit, a dirty one can raise plant heat rate, resulting in large losses of generation revenue and/or unnecessarily high fuel bills. Conventional methods for cleaning fouled tubes range form chemicals to scrapers to brushes and hydro-blasters. This article compares the available options and describes how one power station, Omaha Public Power District's 600 MW North Omaha coal-fired power station, cleaned up its act. The makeup and cooling water of all its five units comes from the Missouri River. 6 figs.

  10. Kinetic Demonstration.

    ERIC Educational Resources Information Center

    Burgardt, Erik D.; Ryan, Hank

    1996-01-01

    Presents a unit on chemical reaction kinetics that consists of a predemonstration activity, the demonstration, and a set of postdemonstration activities that help students transfer the concepts to actual chemical reactions. Simulates various aspects of chemical reaction kinetics. (JRH)

  11. Kinetic Atom.

    ERIC Educational Resources Information Center

    Wilson, David B.

    1981-01-01

    Surveys the research of scientists like Joule, Kelvin, Maxwell, Clausius, and Boltzmann as it comments on the basic conceptual issues involved in the development of a more precise kinetic theory and the idea of a kinetic atom. (Author/SK)

  12. Simple Simulations of DNA Condensation

    SciTech Connect

    STEVENS,MARK J.

    2000-07-12

    Molecular dynamics simulations of a simple, bead-spring model of semiflexible polyelectrolytes such as DNA are performed. All charges are explicitly treated. Starting from extended, noncondensed conformations, condensed structures form in the simulations with tetravalent or trivalent counterions. No condensates form or are stable for divalent counterions. The mechanism by which condensates form is described. Briefly, condensation occurs because electrostatic interactions dominate entropy, and the favored Coulombic structure is a charge ordered state. Condensation is a generic phenomena and occurs for a variety of polyelectrolyte parameters. Toroids and rods are the condensate structures. Toroids form preferentially when the molecular stiffness is sufficiently strong.

  13. Enzyme Kinetics.

    ERIC Educational Resources Information Center

    Moe, Owen; Cornelius, Richard

    1988-01-01

    Conveys an appreciation of enzyme kinetic analysis by using a practical and intuitive approach. Discusses enzyme assays, kinetic models and rate laws, the kinetic constants (V, velocity, and Km, Michaels constant), evaluation of V and Km from experimental data, and enzyme inhibition. (CW)

  14. Detail of Bright Angel stone vault, containing condenser, Hoffman condensation ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Detail of Bright Angel stone vault, containing condenser, Hoffman condensation pump, Jennings vacuum heating pump, and misc. pipes and valves. - Grand Canyon Village Utilities, Grand Canyon National Park, Grand Canyon Village, Coconino County, AZ

  15. Experimental evidence of condensation-driven airflow

    NASA Astrophysics Data System (ADS)

    Bunyard, P.; Hodnett, M.; Poveda, G.; Burgos Salcedo, J. D.; Peña, C.

    2015-10-01

    The dominant "convection" model of atmospheric circulation is based on the premise that hot air expands and rises, to be replaced by colder air, thereby creating horizontal surface winds. A recent theory put forward by Makarieva and Gorshkov (2007, 2013) maintains that the primary motive force of atmospheric circulation derives from the intense condensation and sharp pressure reduction that is associated with regions where a high rate of evapotranspiration from natural closed-canopy forests provides the "fuel" for cloud formation. The net result of the "biotic pump" theory is that moist air flows from ocean to land, drawn in by the pressure changes associated with a high rate of condensation. To test the physics underpinning the biotic pump theory, namely that condensation of water vapour, at a sufficiently high rate, results in an uni-directional airflow, a 5 m tall experimental apparatus was designed and built, in which a 20 m3 body of atmospheric air is enclosed inside an annular 14 m long space (a "square donut") around which it can circulate freely, allowing for rotary air flows. One vertical side of the apparatus contains some 17 m of copper refrigeration coils, which cause condensation. The apparatus contains a series of sensors measuring temperature, humidity and barometric pressure every five seconds, and air flow every second. The laws of Newtonian physics are used in calculating the rate of condensation inside the apparatus. The results of more than one hundred experiments show a highly significant correlation, with r2 > 0.9, of airflow and the rate of condensation. The rotary air flows created appear to be consistent both in direction and velocity with the biotic pump hypothesis, the critical factor being the rate change in the partial pressure of water vapour in the enclosed body of atmospheric air. Air density changes, in terms of kinetic energy, are found to be orders of magnitude smaller than the kinetic energy of partial pressure change. The

  16. Inflation from gravitino condensates

    NASA Astrophysics Data System (ADS)

    Mavromatos, Nick E.

    2015-07-01

    We review work on the formation of gravitino condensates via the super-Higgs effect in the early Universe. This is a scenario for both inflating the early universe and breaking local supersymmetry(supergravity), entirely independent of any coupling to external matter. The goldstino mode associated with the breaking of (global) supersymmetry is “eaten” by the gravitino field, which becomes massive (via its own vacuum condensation) and breaks supergravity dynamically. The most natural association of gravitino condensates with inflation proceeds in an indirect way, via a Starobinsky-type inflation, in the massive gravitino phase. This inflationary phase is associated with scalar modes hidden in the higher order curvature corrections of the effective action arising from integrating out massive gravitino degrees of freedom. The scenario is in agreement with Planck data phenomenology in a natural and phenomenologically-relevant range of parameters, namely Grand-Unified-Theory values for the supersymmetry breaking energy scale and dynamically-induced gravitino mass. A hill-top inflation, on the other hand, which could also occur in the model, whereby the role of the inflaton field is played by the gravitino condensate itself, would require significant fine tuning in the inflaton's wave function renormalisation and thus may be discarded on naturalness grounds.

  17. Condensate removal device

    DOEpatents

    Maddox, James W.; Berger, David D.

    1984-01-01

    A condensate removal device is disclosed which incorporates a strainer in unit with an orifice. The strainer is cylindrical with its longitudinal axis transverse to that of the vapor conduit in which it is mounted. The orifice is positioned inside the strainer proximate the end which is remoter from the vapor conduit.

  18. Thermalization of gluons with Bose-Einstein condensation.

    PubMed

    Xu, Zhe; Zhou, Kai; Zhuang, Pengfei; Greiner, Carsten

    2015-05-01

    We study the thermalization of gluons far from thermal equilibrium in relativistic kinetic theory. The initial distribution of gluons is assumed to resemble that in the early stage of ultrarelativistic heavy ion collisions. Only elastic scatterings in static, nonexpanding gluonic matter are considered. At first we show that the occurrence of condensation in the limit of vanishing particle mass requires a general constraint for the scattering matrix element. Then the thermalization of gluons with Bose-Einstein condensation is demonstrated in a transport calculation. We see a continuously increasing overpopulation of low energy gluons, followed by a decrease to the equilibrium distribution, when the condensation occurs. The times of the completion of the gluon condensation and of the entropy production are calculated. These times scale inversely with the energy density. PMID:26000996

  19. Influence of organic films on the evaporation and condensation of water in aerosol

    PubMed Central

    Davies, James F.; Miles, Rachael E. H.; Haddrell, Allen E.; Reid, Jonathan P.

    2013-01-01

    Uncertainties in quantifying the kinetics of evaporation and condensation of water from atmospheric aerosol are a significant contributor to the uncertainty in predicting cloud droplet number and the indirect effect of aerosols on climate. The influence of aerosol particle surface composition, particularly the impact of surface active organic films, on the condensation and evaporation coefficients remains ambiguous. Here, we report measurements of the influence of organic films on the evaporation and condensation of water from aerosol particles. Significant reductions in the evaporation coefficient are shown to result when condensed films are formed by monolayers of long-chain alcohols [CnH(2n+1)OH], with the value decreasing from 2.4 × 10−3 to 1.7 × 10−5 as n increases from 12 to 17. Temperature-dependent measurements confirm that a condensed film of long-range order must be formed to suppress the evaporation coefficient below 0.05. The condensation of water on a droplet coated in a condensed film is shown to be fast, with strong coherence of the long-chain alcohol molecules leading to islanding as the water droplet grows, opening up broad areas of uncoated surface on which water can condense rapidly. We conclude that multicomponent composition of organic films on the surface of atmospheric aerosol particles is likely to preclude the formation of condensed films and that the kinetics of water condensation during the activation of aerosol to form cloud droplets is likely to remain rapid. PMID:23674675

  20. Multilayer graphene condenser microphone

    NASA Astrophysics Data System (ADS)

    Todorović, Dejan; Matković, Aleksandar; Milićević, Marijana; Jovanović, Djordje; Gajić, Radoš; Salom, Iva; Spasenović, Marko

    2015-12-01

    Vibrating membranes are the cornerstone of acoustic technology, forming the backbone of modern loudspeakers and microphones. Acoustic performance of a condenser microphone is derived mainly from the membrane’s size, surface mass and achievable static tension. The widely studied and available nickel has been a dominant membrane material for professional microphones for several decades. In this paper we introduce multilayer graphene as a membrane material for condenser microphones. The graphene device outperforms a high end commercial nickel-based microphone over a significant part of the audio spectrum, with a larger than 10 dB enhancement of sensitivity. Our experimental results are supported with numerical simulations, which also show that a 300 layer thick graphene membrane under maximum tension would offer excellent extension of the frequency range, up to 1 MHz.

  1. Gravitational vacuum condensate stars

    PubMed Central

    Mazur, Pawel O.; Mottola, Emil

    2004-01-01

    A new final state of gravitational collapse is proposed. By extending the concept of Bose–Einstein condensation to gravitational systems, a cold, dark, compact object with an interior de Sitter condensate pv = -ρv and an exterior Schwarzschild geometry of arbitrary total mass M is constructed. These regions are separated by a shell with a small but finite proper thickness ℓ of fluid with equation of state p = +ρ, replacing both the Schwarzschild and de Sitter classical horizons. The new solution has no singularities, no event horizons, and a global time. Its entropy is maximized under small fluctuations and is given by the standard hydrodynamic entropy of the thin shell, which is of the order kBℓMc/, instead of the Bekenstein–Hawking entropy formula, SBH = 4πkBGM2/c. Hence, unlike black holes, the new solution is thermodynamically stable and has no information paradox. PMID:15210982

  2. CW laser light condensation.

    PubMed

    Zhurahov, Michael; Bekker, Alexander; Levit, Boris; Weill, Rafi; Fischer, Baruch

    2016-03-21

    We present a first experimental demonstration of classical CW laser light condensation (LC) in the frequency (mode) domain that verifies its prediction (Fischer and Weill, Opt. Express20, 26704 (2012)). LC is based on weighting the modes in a noisy environment in a loss-gain measure compared to an energy (frequency) scale in Bose-Einstein condensation (BEC). It is characterized by a sharp transition from multi- to single-mode oscillation, occurring when the spectral-filtering (loss-trap) has near the lowest-loss mode ("ground-state") a power-law dependence with an exponent smaller than 1. An important meaning of the many-mode LC system stems from its relation to lasing and photon-BEC. PMID:27136845

  3. Bose-Einstein Condensation

    SciTech Connect

    El-Sherbini, Th.M.

    2005-03-17

    This article gives a brief review of Bose-Einstein condensation. It is an exotic quantum phenomenon that was observed in dilute atomic gases for the first time in 1995. It exhibits a new state of matter in which a group of atoms behaves as a single particle. Experiments on this form of matter are relevant to many different areas of physics- from atomic clocks and quantum computing to super fluidity, superconductivity and quantum phase transition.

  4. Asymmetric condensed dark matter

    NASA Astrophysics Data System (ADS)

    Aguirre, Anthony; Diez-Tejedor, Alberto

    2016-04-01

    We explore the viability of a boson dark matter candidate with an asymmetry between the number densities of particles and antiparticles. A simple thermal field theory analysis confirms that, under certain general conditions, this component would develop a Bose-Einstein condensate in the early universe that, for appropriate model parameters, could survive the ensuing cosmological evolution until now. The condensation of a dark matter component in equilibrium with the thermal plasma is a relativistic process, hence the amount of matter dictated by the charge asymmetry is complemented by a hot relic density frozen out at the time of decoupling. Contrary to the case of ordinary WIMPs, dark matter particles in a condensate must be lighter than a few tens of eV so that the density from thermal relics is not too large. Big-Bang nucleosynthesis constrains the temperature of decoupling to the scale of the QCD phase transition or above. This requires large dark matter-to-photon ratios and very weak interactions with standard model particles.

  5. Effect of spontaneous condensation on condensation heat transfer in the presence of non-condensable gases

    SciTech Connect

    Karl, J.; Hein, D.

    1999-07-01

    The presence of non condensable gases like nitrogen or air reduces the condensation heat transfer during condensation of binary steam mixtures. The non condensable gas accumulates in the vapor phase boundary layer and causes a high heat transfer resistance. Especially with high pressures and low water temperatures spontaneous condensation reduces heat transfer additionally. Fog forms within the steam-nitrogen boundary layer and the steam condenses on the water droplets of the fog layer. The convective mass transfer to the cooling water interface diminishes. Raman spectroscopy and film theory are used to quantify this effect locally. The calculation of overall condensation rates in large steam nitrogen systems requires to use three dimensional CFD codes. The paper presents equations to predict fog formation in the boundary layer which can be implemented in CFD codes.

  6. Condensed Matter Nuclear Science

    NASA Astrophysics Data System (ADS)

    Biberian, Jean-Paul

    2006-02-01

    1. General. A tribute to gene Mallove - the "Genie" reactor / K. Wallace and R. Stringham. An update of LENR for ICCF-11 (short course, 10/31/04) / E. Storms. New physical effects in metal deuterides / P. L. Hagelstein ... [et al.]. Reproducibility, controllability, and optimization of LENR experiments / D. J. Nagel -- 2. Experiments. Electrochemistry. Evidence of electromagnetic radiation from Ni-H systems / S. Focardi ... [et al.]. Superwave reality / I. Dardik. Excess heat in electrolysis experiments at energetics technologies / I. Dardik ... [et al.]. "Excess heat" during electrolysis in platinum/K[symbol]CO[symbol]/nickel light water system / J. Tian ... [et al.]. Innovative procedure for the, in situ, measurement of the resistive thermal coefficient of H(D)/Pd during electrolysis; cross-comparison of new elements detected in the Th-Hg-Pd-D(H) electrolytic cells / F. Celani ... [et al.]. Emergence of a high-temperature superconductivity in hydrogen cycled Pd compounds as an evidence for superstoihiometric H/D sites / A. Lipson ... [et al.]. Plasma electrolysis. Calorimetry of energy-efficient glow discharge - apparatus design and calibration / T. B. Benson and T. O. Passell. Generation of heat and products during plasma electrolysis / T. Mizuno ... [et al.]. Glow discharge. Excess heat production in Pd/D during periodic pulse discharge current in various conditions / A. B. Karabut. Beam experiments. Accelerator experiments and theoretical models for the electron screening effect in metallic environments / A. Huke, K. Czerski, and P. Heide. Evidence for a target-material dependence of the neutron-proton branching ratio in d+d reactions for deuteron energies below 20keV / A. Huke ... [et al.]. Experiments on condensed matter nuclear events in Kobe University / T. Minari ... [et al.]. Electron screening constraints for the cold fusion / K. Czerski, P. Heide, and A. Huke. Cavitation. Low mass 1.6 MHz sonofusion reactor / R. Stringham. Particle detection. Research

  7. Gravitational Condensate Stars

    NASA Astrophysics Data System (ADS)

    Mazur, P.; Mottola, E.

    The issue of the final state of the gravitational collapse will be addressed. Ishall present physical arguments to the effect that the remnant of the gravitationalcollapse of super-massive stars is a cold and dark super-dense object which isthermodynamically and dynamically stable: a Gravitational Condensate Star orQuasi Black Hole (QBH). A QBH is characterized by a huge, but not an infinite,surface redshift. This surface redshift depends universally on the total mass of aQBH and the proper thickness of a thin shell of an exotic matter described bythe Zel'dovich equation of state p = c2 . The velocity of sound in a thin shell isequal to the velocity of light. Hence, this thin shell replaces the event horizon of amathematical black hole ( = 0). Inside a thin shell the zero entropy gravitationalcondensate characterized by the cosmological equation of state p = -c2 resides.A QBH is described by a new static and spherically symmetric solution of Ein-stein's equations supplemented with the proper boundary conditions based on mi-crophysics considerations. The new solution has no singularities and no eventhorizons. Its entropy is maximized under small fluctuations and is given by thestandard hydrodynamic entropy of the thin shell which is proportional to the to-tal mass instead of the Bekenstein-Hawking entropy which is proportional to thesquare of the total mass. This resolves the paradox of an excessively high en-tropy of black holes as compared to their progenitors. The formation of such acold gravitational condensate stellar remnant very likely would require a violentcollapse process with an explosive output of energy. Some observational conse-quences of the formation of gravitational condensate stars will be described.

  8. Expansion in condensates

    SciTech Connect

    Chakrabarti, J.; Sajjad Zahir, M.

    1985-03-01

    We show that the product of local current operators in quantum chromodynamics (QCD), when expanded in terms of condensates, such as psi-barpsi, G/sup a//sub munu/ G/sup a//sub munu/, psi-barGAMMA psipsi-barGAMMApsi, f/sub a/bcG/sup a//sub munu/G/sup b//sub nualpha/ x G/sup c//sub alphamu/, etc., yields a series in Planck's constant. This, however, provides no hint that the higher terms in such an expansion may be less significant.

  9. Confinement Contains Condensates

    SciTech Connect

    Brodsky, Stanley J.; Roberts, Craig D.; Shrock, Robert; Tandy, Peter C.

    2012-03-12

    Dynamical chiral symmetry breaking and its connection to the generation of hadron masses has historically been viewed as a vacuum phenomenon. We argue that confinement makes such a position untenable. If quark-hadron duality is a reality in QCD, then condensates, those quantities that have commonly been viewed as constant empirical mass-scales that fill all spacetime, are instead wholly contained within hadrons; i.e., they are a property of hadrons themselves and expressed, e.g., in their Bethe-Salpeter or light-front wave functions. We explain that this paradigm is consistent with empirical evidence, and incidentally expose misconceptions in a recent Comment.

  10. Condensed Plasmas under Microgravity

    NASA Technical Reports Server (NTRS)

    Morfill, G. E.; Thomas, H. M.; Konopka, U.; Rothermel, H.; Zuzic, M.; Ivlev, A.; Goree, J.; Rogers, Rick (Technical Monitor)

    1999-01-01

    Experiments under microgravity conditions were carried out to study 'condensed' (liquid and crystalline) states of a colloidal plasma (ions, electrons, and charged microspheres). Systems with approximately 10(exp 6) microspheres were produced. The observed systems represent new forms of matter--quasineutral, self-organized plasmas--the properties of which are largely unexplored. In contrast to laboratory measurements, the systems under microgravity are clearly three dimensional (as expected); they exhibit stable vortex flows, sometimes adjacent to crystalline regions, and a central 'void,' free of microspheres.

  11. Growth dynamics of a Bose-Einstein condensate in a dimple trap without cooling

    SciTech Connect

    Garrett, Michael C.; Davis, Matthew J.; Ratnapala, Adrian; Ooijen, Eikbert D. van; Vale, Christopher J.; Weegink, Kristian; Schnelle, Sebastian K.; Vainio, Otto; Heckenberg, Norman R.; Rubinsztein-Dunlop, Halina

    2011-01-15

    We study the formation of a Bose-Einstein condensate in a cigar-shaped three-dimensional harmonic trap, induced by the controlled addition of an attractive ''dimple'' potential along the weak axis. In this manner we are able to induce condensation without cooling due to a localized increase in the phase-space density. We perform a quantitative analysis of the thermodynamic transformation in both the sudden and adiabatic regimes for a range of dimple widths and depths. We find good agreement with equilibrium calculations based on self-consistent semiclassical Hartree-Fock theory describing the condensate and thermal cloud. We observe that there is an optimal dimple depth that results in a maximum in the condensate fraction. We also study the nonequilibrium dynamics of condensate formation in the sudden turn-on regime, finding good agreement for the observed time dependence of the condensate fraction with calculations based on quantum kinetic theory.

  12. Gravitational vacuum condensate stars.

    PubMed

    Mazur, Pawel O; Mottola, Emil

    2004-06-29

    A new final state of gravitational collapse is proposed. By extending the concept of Bose-Einstein condensation to gravitational systems, a cold, dark, compact object with an interior de Sitter condensate p(v) = -rho(v) and an exterior Schwarzschild geometry of arbitrary total mass M is constructed. These regions are separated by a shell with a small but finite proper thickness l of fluid with equation of state p = +rho, replacing both the Schwarzschild and de Sitter classical horizons. The new solution has no singularities, no event horizons, and a global time. Its entropy is maximized under small fluctuations and is given by the standard hydrodynamic entropy of the thin shell, which is of the order k(B)lMc/Planck's over 2 pi, instead of the Bekenstein-Hawking entropy formula, S(BH) = 4 pi k(B)GM(2)/Planck's over 2 pi c. Hence, unlike black holes, the new solution is thermodynamically stable and has no information paradox. PMID:15210982

  13. Cosmic curvature and condensation

    NASA Technical Reports Server (NTRS)

    Harwit, Martin

    1992-01-01

    It is shown that the universe may consist of a patchwork of domains with different Riemann curvature constants k = 0, +/-1. Features of a phase transition in which flat space breaks up in a transition 2k0 - k(-) + k(+) with initial scale factors R(-) = R(+) are postulated and explored. It is shown that such a transition is energetically permitted, has the equivalent of a Curie temperature, and can lead in a natural way to the formation of voids and galaxies. It is predicted that, if the ambient universe on average is well fitted by a purely k(-) space, with only occasional domains of k(+) containing galaxies, a density parameter of (A(z sub c + 1)) super -1 should be expected, where z sub c represents the redshift of the earliest objects to have condensed, and A takes on values ranging from about 5 to 3. Present observations of quasars would suggest a density of about 0.03 or 0.05, respectively, but it could be lower if earlier condensation took place.

  14. Pion condensation in holographic QCD

    SciTech Connect

    Albrecht, Dylan; Erlich, Joshua

    2010-11-01

    We study pion condensation at zero temperature in a hard-wall holographic model of hadrons with isospin chemical potential. We find that the transition from the hadronic phase to the pion condensate phase is first order except in a certain limit of model parameters. Our analysis suggests that immediately across the phase boundary the condensate acts as a stiff medium approaching the Zel'dovich limit of equal energy density and pressure.

  15. Electric-field-enhanced condensation on superhydrophobic nanostructured surfaces.

    PubMed

    Miljkovic, Nenad; Preston, Daniel J; Enright, Ryan; Wang, Evelyn N

    2013-12-23

    When condensed droplets coalesce on a superhydrophobic nanostructured surface, the resulting droplet can jump due to the conversion of excess surface energy into kinetic energy. This phenomenon has been shown to enhance condensation heat transfer by up to 30% compared to state-of-the-art dropwise condensing surfaces. However, after the droplets jump away from the surface, the existence of the vapor flow toward the condensing surface increases the drag on the jumping droplets, which can lead to complete droplet reversal and return to the surface. This effect limits the possible heat transfer enhancement because larger droplets form upon droplet return to the surface, which impedes heat transfer until they can be either removed by jumping again or finally shedding via gravity. By characterizing individual droplet trajectories during condensation on superhydrophobic nanostructured copper oxide (CuO) surfaces, we show that this vapor flow entrainment dominates droplet motion for droplets smaller than R ≈ 30 μm at moderate heat fluxes (q″ > 2 W/cm(2)). Subsequently, we demonstrate electric-field-enhanced condensation, whereby an externally applied electric field prevents jumping droplet return. This concept leverages our recent insight that these droplets gain a net positive charge due to charge separation of the electric double layer at the hydrophobic coating. As a result, with scalable superhydrophobic CuO surfaces, we experimentally demonstrated a 50% higher overall condensation heat transfer coefficient compared to that on a jumping-droplet surface with no applied field for low supersaturations (<1.12). This work not only shows significant condensation heat transfer enhancement but also offers avenues for improving the performance of self-cleaning and anti-icing surfaces as well as thermal diodes. PMID:24261667

  16. Calculations of condensation and chemistry in an aircraft contrail

    NASA Technical Reports Server (NTRS)

    Miake-Lye, Richard C.; Brown, R. C.; Anderson, M. R.; Kolb, C. E.

    1994-01-01

    The flow field, chemistry, and condensation nucleation behind a transport airplane are calculated in two regimes using two separate reacting flow codes: first the axisymmetric plume, then the three dimensional vortex wake. The included chemical kinetics equations follow the evolution of the NO(y) and SO(x) chemical families. In the plume regime, the chemistry is coupled with the binary homogeneous formation of sulfate condensation nuclei, where the calculated nucleation rates predict that copious quantities of H2SO4/H2O nuclei are produced in subnanometer sizes. These sulfate aerosols could play a major role in the subsequent condensation of water vapor and the formation of contrails under favorable atmospheric conditions.

  17. Efficient kinetic macrocyclization.

    PubMed

    Feng, Wen; Yamato, Kazuhiro; Yang, Liuqing; Ferguson, Joseph S; Zhong, Lijian; Zou, Shuliang; Yuan, Lihua; Zeng, Xiao Cheng; Gong, Bing

    2009-02-25

    In this article, the highly efficient formation of a series of recently discovered aromatic oligoamide macrocycles consisting of six meta-linked residues is first discussed. The macrocycles, with their backbones rigidified by three-center hydrogen bonds, were found to form in high yields that deviate dramatically from the theoretically allowed value obtained from kinetic simulation of a typical kinetically controlled macrocyclization reaction. The folding of the uncyclized six-residue oligomeric precursors, which belong to a class of backbone-rigidified oligoamides that have been demonstrated by us to adopt well-defined crescent conformations, plays a critical role in the observed high efficiency. Out of two possible mechanisms, one is consistent with experimental results obtained from the coupling of crescent oligoamides of different lengths, which suggests a remote steric effect that discourages the formation of oligomers having lengths longer than the backbone of the six-residue precursors. The suggested mechanism is supported by the efficient formation of very large aromatic oligoamide macrocycles consisting of alternating meta- and para-linked residues. These large macrocycles, having H-bond-rigidified backbones and large internal lumens, are formed in high (>80%) yields on the basis of one-step, multicomponent macrocyclization reactions. The condensation of monomeric meta-diamines and a para-diacid chloride leads to the efficient formation of macrocycles with 14, 16, and 18 residues, corresponding to 70-, 80-, and 90-membered rings that contain internal cavities of 2.2, 2.5, and 2.9 nm across. In addition, the condensation between trimeric or pentameric diamines and a monomeric diacid chloride had resulted in the selective formation of single macrocyclic products with 16 or 18 residues. The efficient formation of the macrocycles, along with the absence of other noncyclic oligomeric and polymeric byproducts, is in sharp contrast to the poor yields associated

  18. Inverse Kinetics

    Energy Science and Technology Software Center (ESTSC)

    2000-03-20

    Given the space-independent, one energy group reactor kinetics equations and the initial conditions, this prgram determines the time variation of reactivity required to produce the given input of flux-time data.

  19. Black Hole Bose Condensation

    NASA Astrophysics Data System (ADS)

    Vaz, Cenalo; Wijewardhana, L. C. R.

    2013-12-01

    General consensus on the nature of the degrees of freedom responsible for the black hole entropy remains elusive despite decades of effort dedicated to the problem. Different approaches to quantum gravity disagree in their description of the microstates and, more significantly, in the statistics used to count them. In some approaches (string theory, AdS/CFT) the elementary degrees of freedom are indistinguishable, whereas they must be treated as distinguishable in other approaches to quantum gravity (eg., LQG) in order to recover the Bekenstein-Hawking area-entropy law. However, different statistics will imply different behaviors of the black hole outside the thermodynamic limit. We illustrate this point by quantizing the Bañados-Teitelboim-Zanelli (BTZ) black hole, for which we argue that Bose condensation will occur leading to a "cold", stable remnant.

  20. Microgravity condensing heat exchanger

    NASA Technical Reports Server (NTRS)

    Thomas, Christopher M. (Inventor); Ma, Yonghui (Inventor); North, Andrew (Inventor); Weislogel, Mark M. (Inventor)

    2011-01-01

    A heat exchanger having a plurality of heat exchanging aluminum fins with hydrophilic condensing surfaces which are stacked and clamped between two cold plates. The cold plates are aligned radially along a plane extending through the axis of a cylindrical duct and hold the stacked and clamped portions of the heat exchanging fins along the axis of the cylindrical duct. The fins extend outwardly from the clamped portions along approximately radial planes. The spacing between fins is symmetric about the cold plates, and are somewhat more closely spaced as the angle they make with the cold plates approaches 90.degree.. Passageways extend through the fins between vertex spaces which provide capillary storage and communicate with passageways formed in the stacked and clamped portions of the fins, which communicate with water drains connected to a pump externally to the duct. Water with no entrained air is drawn from the capillary spaces.

  1. Thermalization and condensation in an incoherently pumped passive optical cavity

    NASA Astrophysics Data System (ADS)

    Michel, C.; Haelterman, M.; Suret, P.; Randoux, S.; Kaiser, R.; Picozzi, A.

    2011-09-01

    We study theoretically and numerically the condensation and the thermalization of classical optical waves in an incoherently pumped passive Kerr cavity. We show that the dynamics of the cavity exhibits a turbulent behavior that can be described by the wave turbulence theory. A mean-field kinetic equation is derived, which reveals that, in its high finesse regime, the cavity behaves essentially as a conservative Hamiltonian system. In particular, the intracavity turbulent field is shown to relax adiabatically toward a thermodynamic equilibrium state of energy equipartition. As a consequence of this effect of wave thermalization, the incoherent optical field undergoes a process of condensation, characterized by the spontaneous emergence of a plane wave from the incoherently pumped cavity. The condensation process is an equilibrium phase transition that occurs below a critical value of the (kinetic) energy of the incoherent pump. In spite of the dissipative nature of the cavity dynamics, the condensate fraction of the high-finesse cavity field is found in quantitative agreement with the theory inherited from the purely conservative (Hamiltonian) nonlinear Schrödinger equation.

  2. 1 and 2 Dimensional Bose Einstein Condensates

    NASA Astrophysics Data System (ADS)

    Vogels, Johnny; Gorlitz, Axel; Raman, Chandra; Gustavson, Todd; Drndic, Marija; Leanhardt, Aaron; Abo-Shaeer, Jamil; Loew, Robert; Ketterle, Wolfgang

    2001-05-01

    We have created condensates in which the zero point motion exceeds the mean field enegy in either 2 (1D-condensate) or 1 dimension (2D-condensate). We describe the optical traps and magnetic traps being used, their limitations, and the regimes that are accessible. Some of our 1D condensates should have limited coherence properties (quasi-condensates).

  3. Amine catalyzed condensation of tetraethylorthosilicate

    NASA Technical Reports Server (NTRS)

    Jones, S.

    2001-01-01

    The catalysis of the condensation of hydrolyzed metal alkoxides by amines has been mentioned in the literature, but there has been no systematic study of their influence on the rate of the condensation reaction of the alkoxide and the microstructure of the resultant gel.

  4. APPARATUS FOR CONDENSATION AND SUBLIMATION

    DOEpatents

    Schmidt, R.J.; Fuis, F. Jr.

    1958-10-01

    An apparatus is presented for the sublimation and condensation of uranium compounds in order to obtain an improved crystalline structure of this material. The apparatus comprises a vaporizing chamber and condensing structure connected thereto. There condenser is fitted with a removable liner having a demountable baffle attached to the liner by means of brackets and a removable pin. The baffle is of spiral cross-section and is provided with cooling coils disposed between the surfaces of the baffle for circulation of a temperature controlling liquid within the baffle. The cooling coll provides for controlllng the temperature of the baffle to insure formatlon of a satisfactory condensate, and the removable liner facilitates the removal of condensate formed during tbe sublimation process.

  5. Excitonic condensation in bilayer systems

    NASA Astrophysics Data System (ADS)

    Su, Jung-Jung

    Among the many examples of Bose condensation considered in physics, electron-hole-pair (exciton) condensation has maintained special interest because it has been difficult to realize experimentally, and because of controversy about condensate properties. In this thesis, we studied the various aspects of spontaneous symmetry broken state of exciton in bilayer using mean field theory. We calculated the photoluminescence of excitonic condensation created by laser. We developed a one-dimensional toy model of excitonic supercurrent using mean field theory plus non-equilibrium Green's function (NEGF) which give qualitatively consistent results with experiments. We proposed graphene bilayer as a novel system for excitonic condensation to occur and estimate it to exist even at temperature as high as room temperature.

  6. /sup 13/C and /sup 1/H NMR spectra and structure of the products from the condensation of 1,3-dicarbonyl compounds with aldehydes

    SciTech Connect

    Emelina, E.E.; Gindin, V.A.; Ershov, B.A.

    1988-05-20

    The structure of the diadducts formed in the reaction of 1,3-dicarbonyl compounds with aldehydes in a ratio of 2:1 under the conditions of the Knoevenagel condensation was studied by /sup 13/C and /sup 1/H NMR spectroscopy. It was shown that acyclic tetracarbonyl compounds are formed in the absence of a catalyst while substituted cyclohexanones are formed in the presence of piperidine. The acyclic tetracarbonyl compounds exist mainly in the tetraketo form in solution, and the presence of the monoenol form was established for dimethyl 2,4-diacetylpentanedioate in CD/sub 2/Cl/sub 2/. The most characteristic signals which distinguish between the cyclic diadducts and the acyclic products are the signals of the C/sup 5/ (delta 72 ppm) and C/sup 6/ (delta 52 ppm) atoms. The presence of a keto-enol equilibrium in 2,4-diacetyl-5-hydroxy-3-(p-methoxyphenyl)-5-methylcyclohexanone was demonstrated by /sup 13/C NMR.

  7. Condensed Matter Theories: Volume 25

    NASA Astrophysics Data System (ADS)

    Ludeña, Eduardo V.; Bishop, Raymond F.; Iza, Peter

    2011-03-01

    dynamics and density functional theory. Exchange-correlation functionals from the identical-particle Ornstein-Zernike equation: Basic formulation and numerical algorithms / R. Cuevas-Saavedra and P. W. Ayers. Features and catalytic properties of RhCu: A review / S. Gonzalez, C. Sousa and F. Illas. Kinetic energy functionals: Exact ones from analytic model wave functions and approximate ones in orbital-free molecular dynamics / V. V. Karasiev ... [et al.]. Numerical analysis of hydrogen storage in carbon nanopores / C. Wexler ... [et al.] -- pt. F. Superconductivity. Generalized Bose-Einstein condensation in superconductivity / M. de Llano. Kohn anomaly energy in conventional superconductors equals twice the energy of the superconducting gap: How and why? / R. Chaudhury and M. P. Das. Collective excitations in superconductors and semiconductors in the presence of a condensed phase / Z. Koinov. Thermal expansion of ferromagnetic superconductors: Possible application to UGe[symbol] / N. Hatayama and R. Konno. Generalized superconducting gap in a Boson-Fermion model / T. A. Mamedov and M. de Llano. Influence of domain walls in the superconductor/ferromagnet proximity effect / E. J. Patino. Spin singlet and triplet superconductivity induced by correlated hopping interactions / L. A. Perez, J. S. Millan and C. Wang -- pt. G. Statistical mechanics, relativistic quantum mechanics. Boltzmann's ergodic hypothesis: A meeting place for two cultures / M. H. Lee. Electron-electron interaction in the non-relativistic limit / F. B. Malik.

  8. On the late-time cosmology of a condensed scalar field

    NASA Astrophysics Data System (ADS)

    Ghalee, Amir

    2016-04-01

    We study the late-time cosmology of a scalar field with a kinetic term non-minimally coupled to gravity. It is demonstrated that the scalar field dominate the radiation matter and the cold dark matter (CDM). Moreover, we show that eventually the scalar field will be condensed and results in an accelerated expansion. The metric perturbations around the condensed phase of the scalar field are investigated and it has been shown that the ghost instability and gradient instability do not exist.

  9. Characterization of spacecraft humidity condensate

    NASA Technical Reports Server (NTRS)

    Muckle, Susan; Schultz, John R.; Sauer, Richard L.

    1994-01-01

    When construction of Space Station Freedom reaches the Permanent Manned Capability (PMC) stage, the Water Recovery and Management Subsystem will be fully operational such that (distilled) urine, spent hygiene water, and humidity condensate will be reclaimed to provide water of potable quality. The reclamation technologies currently baselined to process these waste waters include adsorption, ion exchange, catalytic oxidation, and disinfection. To ensure that the baseline technologies will be able to effectively remove those compounds presenting a health risk to the crew, the National Research Council has recommended that additional information be gathered on specific contaminants in waste waters representative of those to be encountered on the Space Station. With the application of new analytical methods and the analysis of waste water samples more representative of the Space Station environment, advances in the identification of the specific contaminants continue to be made. Efforts by the Water and Food Analytical Laboratory at JSC were successful in enlarging the database of contaminants in humidity condensate. These efforts have not only included the chemical characterization of condensate generated during ground-based studies, but most significantly the characterization of cabin and Spacelab condensate generated during Shuttle missions. The analytical results presented in this paper will be used to show how the composition of condensate varies amongst enclosed environments and thus the importance of collecting condensate from an environment close to that of the proposed Space Station. Although advances were made in the characterization of space condensate, complete characterization, particularly of the organics, requires further development of analytical methods.

  10. Condensation in Nanoporous Packed Beds.

    PubMed

    Ally, Javed; Molla, Shahnawaz; Mostowfi, Farshid

    2016-05-10

    In materials with tiny, nanometer-scale pores, liquid condensation is shifted from the bulk saturation pressure observed at larger scales. This effect is called capillary condensation and can block pores, which has major consequences in hydrocarbon production, as well as in fuel cells, catalysis, and powder adhesion. In this study, high pressure nanofluidic condensation studies are performed using propane and carbon dioxide in a colloidal crystal packed bed. Direct visualization allows the extent of condensation to be observed, as well as inference of the pore geometry from Bragg diffraction. We show experimentally that capillary condensation depends on pore geometry and wettability because these factors determine the shape of the menisci that coalesce when pore filling occurs, contrary to the typical assumption that all pore structures can be modeled as cylindrical and perfectly wetting. We also observe capillary condensation at higher pressures than has been done previously, which is important because many applications involving this phenomenon occur well above atmospheric pressure, and there is little, if any, experimental validation of capillary condensation at such pressures, particularly with direct visualization. PMID:27115446

  11. Water condensation: a multiscale phenomenon.

    PubMed

    Jensen, Kasper Risgaard; Fojan, Peter; Jensen, Rasmus Lund; Gurevich, Leonid

    2014-02-01

    The condensation of water is a phenomenon occurring in multiple situations in everyday life, e.g., when fog is formed or when dew forms on the grass or on windows. This means that this phenomenon plays an important role within the different fields of science including meteorology, building physics, and chemistry. In this review we address condensation models and simulations with the main focus on heterogeneous condensation of water. The condensation process is, at first, described from a thermodynamic viewpoint where the nucleation step is described by the classical nucleation theory. Further, we address the shortcomings of the thermodynamic theory in describing the nucleation and emphasize the importance of nanoscale effects. This leads to the description of condensation from a molecular viewpoint. Also presented is how the nucleation can be simulated by use of molecular models, and how the condensation process is simulated on the macroscale using computational fluid dynamics. Finally, examples of hybrid models combining molecular and macroscale models for the simulation of condensation on a surface are presented. PMID:24749461

  12. Theoretical studies of Bose-Einstein condensates

    NASA Astrophysics Data System (ADS)

    Das, Kunal Kashyap

    Landau decay rise rapidly at low n and then declines, while the Beliaev widths rise slowly with n. As temperature → 0, the Beliaev widths reach a constant (>0 for n > 0), while the Landau widths go to zero. The decay rate has a roughly linear dependence on the s-wave scattering length. iii. For condensates with extreme anisotropy the kinetic energy in the squeezed direction cannot be neglected unless the atom number is extremely large. Therefore, the usual Thomas-Fermi approximation (TFA) breaks down. Alternative analytic forms valid for such condensates are presented for the condensate wavefunction and various physical parameters, and they are compared with results from accurate numerical methods and the TFA. These analytic expressions are used to estimate the eigenvalues and eigenfunctions of excitations of highly anisotropic condensates and to obtain semi-analytic expressions for their widths.

  13. Steam generators, turbines, and condensers. Volume six

    SciTech Connect

    Not Available

    1986-01-01

    Volume six covers steam generators (How steam is generated, steam generation in a PWR, vertical U-tube steam generators, once-through steam generators, how much steam do steam generators make.), turbines (basic turbine principles, impulse turbines, reaction turbines, turbine stages, turbine arrangements, turbine steam flow, steam admission to turbines, turbine seals and supports, turbine oil system, generators), and condensers (need for condensers, basic condenser principles, condenser arrangements, heat transfer in condensers, air removal from condensers, circulating water system, heat loss to the circulating water system, factors affecting condenser performance, condenser auxiliaries).

  14. Coulomb interactions and fermion condensation

    SciTech Connect

    Capstick, S.; Cutkosky, R.E.; Joensen, M.A. ); Wang, K.C. )

    1990-08-15

    The influence of the Coulomb interaction in states containing massless and flavorless fermion-antifermion pairs is studied, using a continuum formulation within the finite volume {ital S}{sup 3}. Several different forms for the Coulomb interaction are examined, including confining potentials as well as nonconfining potentials. The calculations show that if the interaction is strong enough, the Coulomb interaction leads to condensation of pairs, and that this condensation has a chiral character. The condensation does not depend on whether the interaction is confining. It is found that simplified variational approximations are not accurate enough for an adequate description of the states.

  15. Using condenser performance measurements to optimize condenser cleaning

    SciTech Connect

    Wolff, P.J.; March, A.; Pearson, H.S.

    1996-05-01

    Because plant personnel perform condenser monitoring primarily to determine cleaning schedules, the accuracy and repeatability of a technique should be viewed within the context of a condenser cleaning schedule. Lower accuracy is acceptable if the cleaning schedule arising from that system is identical to a cleaning schedule arising from a technique with higher accuracy. Three condenser performance monitors were implemented and compared within the context of a condenser cleaning schedule to determine the relative advantages of different condenser monitoring techniques. These systems include a novel on-line system that consists of an electromagnetic flowmeter and an RTD mounted in a compact waterproof cylinder, an overall on-line system, and routine plant tests. The fouling measurements from each system are used in an optimization program which automatically computes a cleaning schedule that minitrack the combined cost of cleaning and the cost of increased fuel consumption caused by condenser fouling. The cleaning schedules resulting from each system`s measurements are compared. The optimization routine is also used to evaluate the sensitivity of optimal cleaning schedules to fouling rate and of the cost in dollars for non-optimal cleaning.

  16. Non-equilibrium effects on the chemistry of nebular condensates - Implications for the planets and asteroids

    NASA Technical Reports Server (NTRS)

    Blander, M.

    1979-01-01

    Kinetic effects, for example nucleation constraints and slow reactions, should have been important in nebular condensation. Consideration of these effects leads to the prediction of pressure-dependent compositions and physical properties of nebular condensates which is consistent with (1) the differences between different classes of chondritic meteorites, (2) some of the differences between planets, and (3) the presence of oxidized iron on the moon and in the eucrite parent body (presumably an asteroid) despite the low abundance of volatiles. Diffusion effects appear to be important for understanding oxygen isotope anomalies in refractory inclusions in Allende. The consideration of kinetic effects leads to more information concerning nebular processes than if equilibrium is assumed.

  17. Condensed Matter Nuclear Science

    NASA Astrophysics Data System (ADS)

    Biberian, Jean-Paul

    2006-02-01

    1. General. A tribute to gene Mallove - the "Genie" reactor / K. Wallace and R. Stringham. An update of LENR for ICCF-11 (short course, 10/31/04) / E. Storms. New physical effects in metal deuterides / P. L. Hagelstein ... [et al.]. Reproducibility, controllability, and optimization of LENR experiments / D. J. Nagel -- 2. Experiments. Electrochemistry. Evidence of electromagnetic radiation from Ni-H systems / S. Focardi ... [et al.]. Superwave reality / I. Dardik. Excess heat in electrolysis experiments at energetics technologies / I. Dardik ... [et al.]. "Excess heat" during electrolysis in platinum/K[symbol]CO[symbol]/nickel light water system / J. Tian ... [et al.]. Innovative procedure for the, in situ, measurement of the resistive thermal coefficient of H(D)/Pd during electrolysis; cross-comparison of new elements detected in the Th-Hg-Pd-D(H) electrolytic cells / F. Celani ... [et al.]. Emergence of a high-temperature superconductivity in hydrogen cycled Pd compounds as an evidence for superstoihiometric H/D sites / A. Lipson ... [et al.]. Plasma electrolysis. Calorimetry of energy-efficient glow discharge - apparatus design and calibration / T. B. Benson and T. O. Passell. Generation of heat and products during plasma electrolysis / T. Mizuno ... [et al.]. Glow discharge. Excess heat production in Pd/D during periodic pulse discharge current in various conditions / A. B. Karabut. Beam experiments. Accelerator experiments and theoretical models for the electron screening effect in metallic environments / A. Huke, K. Czerski, and P. Heide. Evidence for a target-material dependence of the neutron-proton branching ratio in d+d reactions for deuteron energies below 20keV / A. Huke ... [et al.]. Experiments on condensed matter nuclear events in Kobe University / T. Minari ... [et al.]. Electron screening constraints for the cold fusion / K. Czerski, P. Heide, and A. Huke. Cavitation. Low mass 1.6 MHz sonofusion reactor / R. Stringham. Particle detection. Research

  18. Flow Boiling and Condensation Experiment

    NASA Video Gallery

    The Flow Boiling and Condensation Experiment is another investigation that examines the flow of a mixture of liquids and the vapors they produce when in contact with hot space system equipment. Coo...

  19. Hierarchical condensation near phase equilibrium

    NASA Astrophysics Data System (ADS)

    Olemskoi, A. I.; Yushchenko, O. V.; Borisyuk, V. N.; Zhilenko, T. I.; Kosminska, Yu. O.; Perekrestov, V. I.

    2012-06-01

    A novel mechanism of new phase formation is studied both experimentally and theoretically in the example of quasi-equilibrium stationary condensation in an ion-plasma sputterer. Copper condensates are obtained to demonstrate that a specific network structure is formed as a result of self-assembly in the course of deposition. The fractal pattern related is inherent in the phenomena of diffusion limited aggregation. Condensate nuclei are shown to form statistical ensemble of hierarchically subordinated objects distributed in ultrametric space. The Langevin equation and the Fokker-Planck equation related are found to describe stationary distribution of thermodynamic potential variations at condensation. Time dependence of the formation probability of branching structures is found to clarify the experimental situation.

  20. Condensed Matter Nuclear Science

    NASA Astrophysics Data System (ADS)

    Takahashi, Akito; Ota, Ken-Ichiro; Iwamura, Yashuhiro

    Preface -- 1. General. Progress in condensed matter nuclear science / A. Takahashi. Summary of ICCF-12 / X. Z. Li. Overview of light water/hydrogen-based low-energy nuclear reactions / G. H. Miley and P. J. Shrestha -- 2. Excess heat and He detection. Development of "DS-reactor" as the practical reactor of "cold fusion" based on the "DS-cell" with "DS-cathode" / Y. Arata and Y.-C. Zhang. Progress in excess of power experiments with electrochemical loading of deuterium in palladium / V. Violante ... [et al.]. Anomalous energy generation during conventional electrolysis / T. Mizuno and Y. Toriyabe. "Excess heat" induced by deuterium flux in palladium film / B. Liu ... [et al.]. Abnormal excess heat observed during Mizuno-type experiments / J.-F. Fauvarque, P. P. Clauzon and G. J.-M. Lallevé. Seebeck envelope calorimetry with a Pd|D[symbol]O + H[symbol]SO[symbol] electrolytic cell / W.-S. Zhang, J. Dash and Q. Wang. Observation and investigation of nuclear fusion and self-induced electric discharges in liquids / A. I. Koldamasov ... [et al.]. Description of a sensitive seebeck calorimeter used for cold fusion studies / E. Storms. Some recent results at ENEA / M. Apicella ... [et al.]. Heat measurement during plasma electrolysis / K. Iizumi ... [et al.]. Effect of an additive on thermal output during electrolysis of heavy water with a palladium cathode / Q. Wang and J. Dash. Thermal analysis of calorimetric systems / L. D'Aulerio ... [et al.]. Surface plasmons and low-energy nuclear reactions triggering / E. Castagna ... [et al.]. Production method for violent TCB jet plasma from cavity / F. Amini. New results and an ongoing excess heat controversy / L. Kowalski ... [et al.] -- 3. Transmutation. Observation of surface distribution of products by X-ray fluorescence spectrometry during D[symbol] gas permeation through Pd Complexes / Y. Iwamura ... [et al.]. Discharge experiment using Pd/CaO/Pd multi-layered cathode / S. Narita ... [et al.]. Producing transmutation

  1. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  2. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 3 2014-01-01 2014-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  3. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 3 2011-01-01 2011-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  4. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 3 2012-01-01 2012-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  5. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 3 2013-01-01 2013-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  6. Generalized Bose-Einstein Condensation

    NASA Astrophysics Data System (ADS)

    Mullin, William J.; Sakhel, Asaad R.

    2012-02-01

    Generalized Bose-Einstein condensation (GBEC) involves condensates appearing simultaneously in multiple states. We review examples of the three types in an ideal Bose gas with different geometries. In Type I there is a discrete number of quantum states each having macroscopic occupation; Type II has condensation into a continuous band of states, with each state having macroscopic occupation; in Type III each state is microscopically occupied while the entire condensate band is macroscopically occupied. We begin by discussing Type I or "normal" BEC into a single state for an isotropic harmonic oscillator potential. Other geometries and external potentials are then considered: the "channel" potential (harmonic in one dimension and hard-wall in the other), which displays Type II, the "cigar trap" (anisotropic harmonic potential), and the "Casimir prism" (an elongated box), the latter two having Type III condensations. General box geometries are considered in an appendix. We particularly focus on the cigar trap, which Van Druten and Ketterle first showed had a two-step condensation: a GBEC into a band of states at a temperature T c and another "one-dimensional" transition at a lower temperature T 1 into the ground state. In a thermodynamic limit in which the ratio of the dimensions of the anisotropic harmonic trap is kept fixed, T 1 merges with the upper transition, which then becomes a normal BEC. However, in the thermodynamic limit of Beau and Zagrebnov, in which the ratio of the boundary lengths increases exponentially, T 1 becomes fixed at the temperature of a true Type I phase transition. The effects of interactions on GBEC are discussed and we show that there is evidence that Type III condensation may have been observed in the cigar trap.

  7. Condensed Matter Nuclear Science

    NASA Astrophysics Data System (ADS)

    Takahashi, Akito; Ota, Ken-Ichiro; Iwamura, Yashuhiro

    Preface -- 1. General. Progress in condensed matter nuclear science / A. Takahashi. Summary of ICCF-12 / X. Z. Li. Overview of light water/hydrogen-based low-energy nuclear reactions / G. H. Miley and P. J. Shrestha -- 2. Excess heat and He detection. Development of "DS-reactor" as the practical reactor of "cold fusion" based on the "DS-cell" with "DS-cathode" / Y. Arata and Y.-C. Zhang. Progress in excess of power experiments with electrochemical loading of deuterium in palladium / V. Violante ... [et al.]. Anomalous energy generation during conventional electrolysis / T. Mizuno and Y. Toriyabe. "Excess heat" induced by deuterium flux in palladium film / B. Liu ... [et al.]. Abnormal excess heat observed during Mizuno-type experiments / J.-F. Fauvarque, P. P. Clauzon and G. J.-M. Lallevé. Seebeck envelope calorimetry with a Pd|D[symbol]O + H[symbol]SO[symbol] electrolytic cell / W.-S. Zhang, J. Dash and Q. Wang. Observation and investigation of nuclear fusion and self-induced electric discharges in liquids / A. I. Koldamasov ... [et al.]. Description of a sensitive seebeck calorimeter used for cold fusion studies / E. Storms. Some recent results at ENEA / M. Apicella ... [et al.]. Heat measurement during plasma electrolysis / K. Iizumi ... [et al.]. Effect of an additive on thermal output during electrolysis of heavy water with a palladium cathode / Q. Wang and J. Dash. Thermal analysis of calorimetric systems / L. D'Aulerio ... [et al.]. Surface plasmons and low-energy nuclear reactions triggering / E. Castagna ... [et al.]. Production method for violent TCB jet plasma from cavity / F. Amini. New results and an ongoing excess heat controversy / L. Kowalski ... [et al.] -- 3. Transmutation. Observation of surface distribution of products by X-ray fluorescence spectrometry during D[symbol] gas permeation through Pd Complexes / Y. Iwamura ... [et al.]. Discharge experiment using Pd/CaO/Pd multi-layered cathode / S. Narita ... [et al.]. Producing transmutation

  8. Busulfan kinetics.

    PubMed

    Ehrsson, H; Hassan, M; Ehrnebo, M; Beran, M

    1983-07-01

    Busulfan kinetics were studied in patients with chronic myelocytic leukemia after oral doses of 2, 4, and 6 mg. The plasma concentration-time data could be fitted to a zero-order absorption one-compartment open model. The elimination rate constant averaged 0.27 +/- 0.05 hr-1 (SD). The plasma AUC was linearly related to the dose. The lag time for the start of absorption, the time absorption ends, and the absorption rate constant showed some interindividual variations. About 1% of busulfan is excreted unchanged in urine over 24 hr. PMID:6574831

  9. Spacecraft Crew Cabin Condensation Control

    NASA Technical Reports Server (NTRS)

    Carrillo, Laurie Y.; Rickman, Steven L.; Ungar, Eugene K.

    2013-01-01

    A report discusses a new technique to prevent condensation on the cabin walls of manned spacecraft exposed to the cold environment of space, as such condensation could lead to free water in the cabin. This could facilitate the growth of mold and bacteria, and could lead to oxidation and weakening of the cabin wall. This condensation control technique employs a passive method that uses spacecraft waste heat as the primary wallheating mechanism. A network of heat pipes is bonded to the crew cabin pressure vessel, as well as the pipes to each other, in order to provide for efficient heat transfer to the cabin walls and from one heat pipe to another. When properly sized, the heat-pipe network can maintain the crew cabin walls at a nearly uniform temperature. It can also accept and distribute spacecraft waste heat to maintain the pressure vessel above dew point.

  10. Holes in the ghost condensate

    SciTech Connect

    Krotov, D.; Rebbi, C.; Rubakov, V.; Zakharov, V.

    2005-02-15

    In a recently proposed model of 'ghost condensation', spatially homogeneous states may mix, via tunneling, with inhomogeneous states which are somewhat similar to bubbles in the theory of false vacuum decay, the corresponding bubble nucleation rate being exponentially sensitive to the ultraviolet completion of the model. The conservation of energy and charge requires that the energy density is negative and the field is strongly unstable in a part of the nucleated bubble. Unlike in the theory of false vacuum decay, this region does not expand during subsequent real-time evolution. In the outer part, positive energy outgoing waves develop, which eventually form shocks. Behind the outgoing waves and away from the bubble center, the background settles down to its original value. The outcome of the entire process is thus a microscopic region of negative energy and strong field - 'hole in the ghost condensate' - plus a collection of outgoing waves (particles of the ghost condensate field) carrying away finite energy.

  11. Condensed Astatine: Monatomic and Metallic

    NASA Astrophysics Data System (ADS)

    Hermann, Andreas; Hoffmann, Roald; Ashcroft, N. W.

    2013-09-01

    The condensed matter properties of the nominal terminating element of the halogen group with atomic number 85, astatine, are as yet unknown. In the intervening more than 70 years since its discovery significant advances have been made in substrate cooling and the other techniques necessary for the production of the element to the point where we might now enquire about the key properties astatine might have if it attained a condensed phase. This subject is addressed here using density functional theory and structural selection methods, with an accounting for relativistic physics that is essential. Condensed astatine is predicted to be quite different in fascinating ways from iodine, being already at 1 atm a metal, and monatomic at that, and possibly a superconductor (as is dense iodine).

  12. Condensed astatine: monatomic and metallic.

    PubMed

    Hermann, Andreas; Hoffmann, Roald; Ashcroft, N W

    2013-09-13

    The condensed matter properties of the nominal terminating element of the halogen group with atomic number 85, astatine, are as yet unknown. In the intervening more than 70 years since its discovery significant advances have been made in substrate cooling and the other techniques necessary for the production of the element to the point where we might now enquire about the key properties astatine might have if it attained a condensed phase. This subject is addressed here using density functional theory and structural selection methods, with an accounting for relativistic physics that is essential. Condensed astatine is predicted to be quite different in fascinating ways from iodine, being already at 1 atm a metal, and monatomic at that, and possibly a superconductor (as is dense iodine). PMID:24074111

  13. Bose-Einstein condensation mechanism in economic system

    NASA Astrophysics Data System (ADS)

    Xu, Jianping

    2015-06-01

    This paper starts from modifying the kinetic exchange model and ends with making a parallel between economic crisis and the Bose-Einstein condensation. By introducing a parameter δ, we incorporate the time influence into the Bose-Einstein statistics. And δ is found to represent the technology level in an economy. δ's growth in time enlarges the rich and poor gap and induces economic crisis in free market despite the fact that average living standard is raised. Then we find the “δ-Te-Entropy” dilemma which features a strong implication of the second law of thermodynamics. The dilemma means when an economy is isolated the entropy grows and synergetically Te and δ grow inducing the Bose-Einstein condensation, i.e., economic crisis while for open economy the dilemma breaks. Then we raise the question: What would happen if the world economy as a whole became isolated with ultimately omnibearing globalization?

  14. Origin of uranium isotope variations in early solar nebula condensates

    PubMed Central

    Tissot, François L. H.; Dauphas, Nicolas; Grossman, Lawrence

    2016-01-01

    High-temperature condensates found in meteorites display uranium isotopic variations (235U/238U), which complicate dating the solar system’s formation and whose origin remains mysterious. It is possible that these variations are due to the decay of the short-lived radionuclide 247Cm (t1/2 = 15.6 My) into 235U, but they could also be due to uranium kinetic isotopic fractionation during condensation. We report uranium isotope measurements of meteoritic refractory inclusions that reveal excesses of 235U reaching ~+6% relative to average solar system composition, which can only be due to the decay of 247Cm. This allows us to constrain the 247Cm/235U ratio at solar system formation to (1.1 ± 0.3) × 10−4. This value provides new clues on the universality of the nucleosynthetic r-process of rapid neutron capture. PMID:26973874

  15. Spinor condensate of {sup 87}Rb as a dipolar gas

    SciTech Connect

    Swislocki, Tomasz; Gajda, Mariusz; RzaPzewski, Kazimierz

    2010-03-15

    We consider a spinor condensate of {sup 87}Rb atoms in the F=1 hyperfine state confined in an optical dipole trap. Putting initially all atoms in the m{sub F}=0 component, we find that the system evolves toward a state of thermal equilibrium with kinetic energy equally distributed among all magnetic components. We show that this process is dominated by the dipolar interaction of magnetic spins rather than spin-mixing contact potential. Our results show that because of a dynamical separation of magnetic components, the spin-mixing dynamics in the {sup 87}Rb condensate is governed by the dipolar interaction which plays no role in a single-component rubidium system in a magnetic trap.

  16. Origin of uranium isotope variations in early solar nebula condensates.

    PubMed

    Tissot, François L H; Dauphas, Nicolas; Grossman, Lawrence

    2016-03-01

    High-temperature condensates found in meteorites display uranium isotopic variations ((235)U/(238)U), which complicate dating the solar system's formation and whose origin remains mysterious. It is possible that these variations are due to the decay of the short-lived radionuclide (247)Cm (t 1/2 = 15.6 My) into (235)U, but they could also be due to uranium kinetic isotopic fractionation during condensation. We report uranium isotope measurements of meteoritic refractory inclusions that reveal excesses of (235)U reaching ~+6% relative to average solar system composition, which can only be due to the decay of (247)Cm. This allows us to constrain the (247)Cm/(235)U ratio at solar system formation to (1.1 ± 0.3) × 10(-4). This value provides new clues on the universality of the nucleosynthetic r-process of rapid neutron capture. PMID:26973874

  17. On the onset of surface condensation: formation and transition mechanisms of condensation mode

    NASA Astrophysics Data System (ADS)

    Sheng, Qiang; Sun, Jie; Wang, Qian; Wang, Wen; Wang, Hua Sheng

    2016-08-01

    Molecular dynamics simulations have been carried out to investigate the onset of surface condensation. On surfaces with different wettability, we snapshot different condensation modes (no-condensation, dropwise condensation and filmwise condensation) and quantitatively analyze their characteristics by temporal profiles of surface clusters. Two different types of formation of nanoscale droplets are identified, i.e. the formations with and without film-like condensate. We exhibit the effect of surface tensions on the formations of nanoscale droplets and film. We reveal the formation mechanisms of different condensation modes at nanoscale based on our simulation results and classical nucleation theory, which supplements the ‘classical hypotheses’ of the onset of dropwise condensation. We also reveal the transition mechanism between different condensation modes based on the competition between surface tensions and reveal that dropwise condensation represents the transition states from no-condensation to filmwise condensation.

  18. On the onset of surface condensation: formation and transition mechanisms of condensation mode

    PubMed Central

    Sheng, Qiang; Sun, Jie; Wang, Qian; Wang, Wen; Wang, Hua Sheng

    2016-01-01

    Molecular dynamics simulations have been carried out to investigate the onset of surface condensation. On surfaces with different wettability, we snapshot different condensation modes (no-condensation, dropwise condensation and filmwise condensation) and quantitatively analyze their characteristics by temporal profiles of surface clusters. Two different types of formation of nanoscale droplets are identified, i.e. the formations with and without film-like condensate. We exhibit the effect of surface tensions on the formations of nanoscale droplets and film. We reveal the formation mechanisms of different condensation modes at nanoscale based on our simulation results and classical nucleation theory, which supplements the ‘classical hypotheses’ of the onset of dropwise condensation. We also reveal the transition mechanism between different condensation modes based on the competition between surface tensions and reveal that dropwise condensation represents the transition states from no-condensation to filmwise condensation. PMID:27481071

  19. On the onset of surface condensation: formation and transition mechanisms of condensation mode.

    PubMed

    Sheng, Qiang; Sun, Jie; Wang, Qian; Wang, Wen; Wang, Hua Sheng

    2016-01-01

    Molecular dynamics simulations have been carried out to investigate the onset of surface condensation. On surfaces with different wettability, we snapshot different condensation modes (no-condensation, dropwise condensation and filmwise condensation) and quantitatively analyze their characteristics by temporal profiles of surface clusters. Two different types of formation of nanoscale droplets are identified, i.e. the formations with and without film-like condensate. We exhibit the effect of surface tensions on the formations of nanoscale droplets and film. We reveal the formation mechanisms of different condensation modes at nanoscale based on our simulation results and classical nucleation theory, which supplements the 'classical hypotheses' of the onset of dropwise condensation. We also reveal the transition mechanism between different condensation modes based on the competition between surface tensions and reveal that dropwise condensation represents the transition states from no-condensation to filmwise condensation. PMID:27481071

  20. Condensation in Titan's lower atmosphere

    NASA Astrophysics Data System (ADS)

    Lavvas, P.; Griffith, C. A.; Yelle, R. V.

    2011-10-01

    We present a self-consistent description of Titan's aerosols-clouds-gases system and compare our results with the optical properties retrieved from measurements made by the Descent Imager / Spectral Radiometer (DISR) experiment on the Huygens probe [4]. Our calculations include the condensation of methane, ethane and hydrogen cyanide on photochemical aerosols produced in the thermosphere. Our results suggest that the two distinct extinction layers observed by DISR below 80 km are produced by HCN and methane condensation, respectively, while for the Huygens' equatorial conditions simulated here, the contribution of ethane clouds to the total opacity is negligible

  1. Gravity Effects in Condensing and Evaporating Films

    NASA Technical Reports Server (NTRS)

    Hermanson, J. C.; Som, S. M.; Allen, J. S.; Pedersen, P. C.

    2004-01-01

    A general overview of gravity effects in condensing and evaporating films is presented. The topics include: 1) Research Overview; 2) NASA Recognizes Critical Need for Condensation & Evaporation Research to Enable Human Exploration of Space; 3) Condensation and Evaporation Research in Reduced Gravity is Enabling for AHST Technology Needs; 4) Differing Role of Surface Tension on Condensing/Evaporating Film Stability; 5) Fluid Mechanisms in Condensing and Evaporating Films in Reduced Gravity; 6) Research Plan; 7) Experimental Configurations for Condensing Films; 8) Laboratory Condensation Test Cell; 9) Aircraft Experiment; 10) Condensation Study Current Test Conditions; 11) Diagnostics; 12) Shadowgraph Images of Condensing n- pentane Film in Unstable (-1g) Configuration; 13) Condensing n-Pentane Film in Normal Gravity (-1g) at Constant Pressure; 14) Condensing n-Pentane Film in Normal Gravity (-1g) with Cyclic Pressure; 15) Non-condensing Pumped Film in Normal Gravity (-1g); 16) Heat Transfer Coefficient in Developing, Unstable Condensing Film in Normal Gravity; 17) Heat Transfer for Unsteady Condensing Film (-1g); 18) Ultrasound Measurement of Film Thickness N-pentane Film, Stable (+1g) Configuration; and 19) Ultrasound Measurement of Film Thickness N-pentane Film, Unstable (-1g) Configuration.

  2. On Localized Vapor Pressure Gradients Governing Condensation and Frost Phenomena.

    PubMed

    Nath, Saurabh; Boreyko, Jonathan B

    2016-08-23

    Interdroplet vapor pressure gradients are the driving mechanism for several phase-change phenomena such as condensation dry zones, interdroplet ice bridging, dry zones around ice, and frost halos. Despite the fundamental nature of the underlying pressure gradients, the majority of studies on these emerging phenomena have been primarily empirical. Using classical nucleation theory and Becker-Döring embryo formation kinetics, here we calculate the pressure field for all possible modes of condensation and desublimation in order to gain fundamental insight into how pressure gradients govern the behavior of dry zones, condensation frosting, and frost halos. Our findings reveal that in a variety of phase-change systems the thermodynamically favorable mode of nucleation can switch between condensation and desublimation depending upon the temperature and wettability of the surface. The calculated pressure field is used to model the length of a dry zone around liquid or ice droplets over a broad parameter space. The long-standing question of whether the vapor pressure at the interface of growing frost is saturated or supersaturated is resolved by considering the kinetics of interdroplet ice bridging. Finally, on the basis of theoretical calculations, we propose that there exists a new mode of frost halo that is yet to be experimentally observed; a bimodal phase map is developed, demonstrating its dependence on the temperature and wettability of the underlying substrate. We hope that the model and predictions contained herein will assist future efforts to exploit localized vapor pressure gradients for the design of spatially controlled or antifrosting phase-change systems. PMID:27463696

  3. Tolrestat kinetics

    SciTech Connect

    Hicks, D.R.; Kraml, M.; Cayen, M.N.; Dubuc, J.; Ryder, S.; Dvornik, D.

    1984-10-01

    The kinetics of tolrestat, a potent inhibitor of aldose reductase, were examined. Serum concentrations of tolrestat and of total /sup 14/C were measured after dosing normal subjects and subjects with diabetes with /sup 14/C-labeled tolrestat. In normal subjects, tolrestat was rapidly absorbed and disappearance from serum was biphasic. Distribution and elimination t 1/2s were approximately 2 and 10 to 12 hr, respectively, after single and multiple doses. Unchanged tolrestat accounted for the major portion of /sup 14/C in serum. Radioactivity was rapidly and completely excreted in urine and feces in an approximate ratio of 2:1. Findings were much the same in subjects with diabetes. In normal subjects, the kinetics of oral tolrestat were independent of dose in the 10 to 800 mg range. Repetitive dosing did not result in unexpected cumulation. Tolrestat was more than 99% bound to serum protein; it did not compete with warfarin for binding sites but was displaced to some extent by high concentrations of tolbutamide or salicylate.

  4. Chemical Looping Combustion Kinetics

    SciTech Connect

    Edward Eyring; Gabor Konya

    2009-03-31

    One of the most promising methods of capturing CO{sub 2} emitted by coal-fired power plants for subsequent sequestration is chemical looping combustion (CLC). A powdered metal oxide such as NiO transfers oxygen directly to a fuel in a fuel reactor at high temperatures with no air present. Heat, water, and CO{sub 2} are released, and after H{sub 2}O condensation the CO{sub 2} (undiluted by N{sub 2}) is ready for sequestration, whereas the nickel metal is ready for reoxidation in the air reactor. In principle, these processes can be repeated endlessly with the original nickel metal/nickel oxide participating in a loop that admits fuel and rejects ash, heat, and water. Our project accumulated kinetic rate data at high temperatures and elevated pressures for the metal oxide reduction step and for the metal reoxidation step. These data will be used in computational modeling of CLC on the laboratory scale and presumably later on the plant scale. The oxygen carrier on which the research at Utah is focused is CuO/Cu{sub 2}O rather than nickel oxide because the copper system lends itself to use with solid fuels in an alternative to CLC called 'chemical looping with oxygen uncoupling' (CLOU).

  5. Approaching Bose-Einstein Condensation

    ERIC Educational Resources Information Center

    Ferrari, Loris

    2011-01-01

    Bose-Einstein condensation (BEC) is discussed at the level of an advanced course of statistical thermodynamics, clarifying some formal and physical aspects that are usually not covered by the standard pedagogical literature. The non-conventional approach adopted starts by showing that the continuum limit, in certain cases, cancels out the crucial…

  6. Theoretical response of condenser microphones

    NASA Technical Reports Server (NTRS)

    Zuckerwar, A. J.

    1978-01-01

    Modifications to prior theory yield expressions for the frequency response and equivalent lumped elements of a condenser microphone in terms of its fundamental geometrical and material properties. Results of the analysis show excellent agreement with experimental data taken on B&K pressure microphone types 4134 and 4146.

  7. Condensing Algebra for Technical Mathematics.

    ERIC Educational Resources Information Center

    Greenfield, Donald R.

    Twenty Algebra-Packets (A-PAKS) were developed by the investigator for technical education students at the community college level. Each packet contained a statement of rationale, learning objectives, performance activities, performance test, and performance test answer key. The A-PAKS condensed the usual sixteen weeks of algebra into a six-week…

  8. Counterion condensation and ionic conductivity

    NASA Astrophysics Data System (ADS)

    Penafiel, L. Miguel; Litovitz, Theodore A.

    1992-02-01

    The occurrence of counterion condensation is demonstrated through measurements of the incremental ionic conductivity of pH buffered Na polyacrylate solutions. pH values were selected to allow variation of the charge density parameter ξ in the range between 0.4 and 2.8, that is, across ξ=1, the theoretical critical level for counterion condensation. The results show two regions where the incremental conductivity, ΔσP, varies differently with ξ. For ξ<1.3, ΔσP remains relatively constant. A sharp drop in ΔσP is observed between ξ=1.3 and ξ=1.7 corresponding to the onset of counterion condensation. It is suggested that this discontinuity reflects a drastic change in the polyion mobility caused by a structural rearrangement of the macromolecule. For ξ≳1.7, ΔσP decreases with approximately constant slope. This latter behavior agrees qualitatively but not quantitatively with the prediction of the counterion condensation model.

  9. Cylindrical Couette flows of a rarefied gas with evaporation and condensation: Reversal and bifurcation of flows

    NASA Astrophysics Data System (ADS)

    Sone, Yoshio; Sugimoto, Hiroshi; Aoki, Kazuo

    1999-02-01

    A rarefied gas between two coaxial circular cylinders made of the condensed phase of the gas is considered, where each cylinder is kept at a uniform temperature and is rotating at a constant angular velocity around its axis (cylindrical Couette flows of a rarefied gas with evaporation or condensation on the cylinders). The steady behavior of the gas, with special interest in bifurcation of a flow, is studied on the basis of kinetic theory from the continuum to the Knudsen limit. The solution shows profound variety: reversal of direction of evaporation-condensation with variation of the speed of rotation of the cylinders; contrary to the conventional cylindrical Couette flow without evaporation and condensation, bifurcation of a flow in a simple case where the state of the gas is circumferentially and axially uniform.

  10. Microscopic droplet formation and energy transport analysis of condensation on scalable superhydrophobic nanostructured copper oxide surfaces.

    PubMed

    Li, GuanQiu; Alhosani, Mohamed H; Yuan, ShaoJun; Liu, HaoRan; Ghaferi, Amal Al; Zhang, TieJun

    2014-12-01

    Utilization of nanotechnologies in condensation has been recognized as one opportunity to improve the efficiency of large-scale thermal power and desalination systems. High-performance and stable dropwise condensation in widely-used copper heat exchangers is appealing for energy and water industries. In this work, a scalable and low-cost nanofabrication approach was developed to fabricate superhydrophobic copper oxide (CuO) nanoneedle surfaces to promote dropwise condensation and even jumping-droplet condensation. By conducting systematic surface characterization and in situ environmental scanning electron microscope (ESEM) condensation experiments, we were able to probe the microscopic formation physics of droplets on irregular nanostructured surfaces. At the early stages of condensation process, the interfacial surface tensions at the edge of CuO nanoneedles were found to influence both the local energy barriers for microdroplet growth and the advancing contact angles when droplets undergo depinning. Local surface roughness also has a significant impact on the volume of the condensate within the nanostructures and overall heat transfer from the vapor to substrate. Both our theoretical analysis and in situ ESEM experiments have revealed that the liquid condensate within the nanostructures determines the amount of the work of adhesion and kinetic energy associated with droplet coalescence and jumping. Local and global droplet growth models were also proposed to predict how the microdroplet morphology within nanostructures affects the heat transfer performance of early-stage condensation. Our quantitative analysis of microdroplet formation and growth within irregular nanostructures provides the insight to guide the anodization-based nanofabrication for enhancing dropwise and jumping-droplet condensation performance. PMID:25419845

  11. Grain formation in astronomical systems: A critical review of condensation processes

    NASA Technical Reports Server (NTRS)

    Donn, B.

    1978-01-01

    An analysis is presented of the assumption and the applicability of the three theoretical methods for calculating condensations in cosmic clouds where no pre-existing nuclei exist. The three procedures are: thermodynamic equilibrium calculations, nucleation theory, and a kinetic treatment which would take into account the characteristics of each individual collision. Thermodynamics provide detailed results on the composition temperature and composition of the condensate provided the system attains equilibrium. Because of the cosmic abundance mixture of elements, large supersaturations in some cases and low pressures, equilibrium is not expected in astronomical clouds. Nucleation theory, a combination of thermodynamics and kinetics, has the limitations of each scheme. Kinetics, not requiring equilibrium, avoids nearly all the thermodynamics difficulties but requires detailed knowledge of many reactions which thermodynamics avoids. It appears to be the only valid way to treat grain formation in space. A review of experimental studies is given.

  12. Class I Histone Deacetylase Thd1p Promotes Global Chromatin Condensation in Tetrahymena thermophila▿

    PubMed Central

    Parker, Kathryn; Maxson, Julia; Mooney, Alissa; Wiley, Emily A.

    2007-01-01

    Class I histone deacetylases (HDACs) regulate DNA-templated processes such as transcription. They act both at specific loci and more generally across global chromatin, contributing to acetylation patterns that may underlie large-scale chromatin dynamics. Although hypoacetylation is correlated with highly condensed chromatin, little is known about the contribution of individual HDACs to chromatin condensation mechanisms. Using the ciliated protozoan Tetrahymena thermophila, we investigated the role of a specific class I HDAC, Τhd1p, in the reversible condensation of global chromatin. In this system, the normal physiological response to cell starvation includes the widespread condensation of the macronuclear chromatin and general repression of gene transcription. We show that the chromatin in Thd1p-deficient cells failed to condense during starvation. The condensation failure correlated with aberrant hyperphosphorylation of histone H1 and the overexpression of CDC2, encoding the major histone H1 kinase. Changes in the rate of acetate turnover on core histones and in the distribution of acetylated lysines 9 and 23/27 on histone H3 isoforms that were found to correlate with normal chromatin condensation were absent from Thd1p mutant cells. These results point to a role for a class I HDAC in the formation of reversible higher-order chromatin structures and global genome compaction through mechanisms involving the regulation of H1 phosphorylation and core histone acetylation/deacetylation kinetics. PMID:17715364

  13. Internally drained condenser for spacecraft thermal management

    NASA Technical Reports Server (NTRS)

    Valenzuela, Javier A.; Drew, Brian C.

    1989-01-01

    This paper presents the results obtained to date in a program to develop a high heat flux condenser for use in two-phase spacecraft thermal management loops. The objective is to obtain a several fold increase in condensation heat transfer coefficient over those which can be achieved with shear-controlled or capillary-wick condensers. The internally drained condenser relies on shaped fins to develop a capillary pressure gradient over the surface of the fins and drive the condensate toward narrow drainage grooves separating the fins. The condensate then flows through a drainage network embedded in the condenser walls. Heat transfer coefficients of up to 8 W/sq cm C were measured in steam, providing a heat transfer enhancement ratio greater than a factor of 8. In the paper the proof-of-concept experiments are described and simplified models to predict the performance of the internally drained condenser are presented.

  14. Condensation of dust in supernova ejecta

    NASA Astrophysics Data System (ADS)

    Sarangi, A.; Cherchneff, I.

    Observations in the infrared and submm indicate the presence of molecules and dust in the ejecta of type II-P supernovae. The mass of dust formed in the ejecta of supernovae is still uncertain and highly debated: Infrared observations indicate smaller dust masses (10-5 to 10-3 M ) before 500 days post-explosion, compared to submm observations with Herschel revealing supernova remnants as large reservoirs of cool dust (10-2 to 0.7 M ). We study the ejecta of a typical type II-P supernova with a chemical kinetic approach considering a 15 M progenitor as a benchmark. The synthesis of molecules (e.g., CO, SiO, O2, AlO, SiS, FeS, SiC, SO) and small clusters (e.g., silicates, carbon, metal oxides, metallic clusters etc.) in the gas phase is considered. The clusters form gradually over time in different ejecta zones, small dust masses form in the first 600 days (˜ 10-4 M ), that gradually increase up to ˜ 0.1 M at 1500 days post-explosion. The small clusters condense to form dust grains in the gas phase. The size distributions of different dust components are derived from the study.

  15. Polariton Condensation in Dynamic Acoustic Lattices

    NASA Astrophysics Data System (ADS)

    Cerda-Méndez, E. A.; Krizhanovskii, D. N.; Wouters, M.; Bradley, R.; Biermann, K.; Guda, K.; Hey, R.; Santos, P. V.; Sarkar, D.; Skolnick, M. S.

    2010-09-01

    We demonstrate that the tunable potential introduced by a surface acoustic wave on a homogeneous polariton condensate leads to fragmentation of the condensate into an array of wires which move with the acoustic velocity. Reduction of the spatial coherence of the condensate emission along the surface acoustic wave direction is attributed to the suppression of coupling between the spatially modulated condensates. Interparticle interactions observed at high polariton densities screen the acoustic potential, partially reversing its effect on spatial coherence.

  16. Bose-Einstein condensation at constant temperature

    NASA Astrophysics Data System (ADS)

    Erhard, M.; Schmaljohann, H.; Kronjäger, J.; Bongs, K.; Sengstock, K.

    2004-09-01

    We present an experimental approach to Bose-Einstein condensation by increasing the particle number of the system at almost constant temperature. In particular, the emergence of a new condensate is observed in multicomponent F=1 spinor condensates of Rb87 . Furthermore, we develop a simple rate-equation model for multicomponent Bose-Einstein condensate thermodynamics at finite temperature which well reproduces the measured effects.

  17. Film condensation in a horizontal rectangular duct

    NASA Technical Reports Server (NTRS)

    Lu, Qing; Suryanarayana, N. V.

    1992-01-01

    Condensation heat transfer in an annular flow regime with and without interfacial waves was experimentally investigated. The study included measurements of heat transfer rate with condensation of vapor flowing inside a horizontal rectangular duct and experiments on the initiation of interfacial waves in condensation, and adiabatic air-liquid flow. An analytical model for the condensation was developed to predict condensate film thickness and heat transfer coefficients. Some conclusions drawn from the study are that the condensate film thickness was very thin (less than 0.6 mm). The average heat transfer coefficient increased with increasing the inlet vapor velocity. The local heat transfer coefficient decreased with the axial distance of the condensing surface, with the largest change at the leading edge of the test section. The interfacial shear stress, which consisted of the momentum shear stress and the adiabatic shear stress, appeared to have a significant effect on the heat transfer coefficients. In the experiment, the condensate flow along the condensing surface experienced a smooth flow, a two-dimensional wavy flow, and a three-dimensional wavy flow. In the condensation experiment, the local wave length decreased with the axial distance of the condensing surface and the average wave length decreased with increasing inlet vapor velocity, while the wave speed increased with increasing vapor velocity. The heat transfer measurements are reliable. And, the ultrasonic technique was effective for measuring the condensate film thickness when the surface was smooth or had waves of small amplitude.

  18. Condensed matter analogues of cosmology

    NASA Astrophysics Data System (ADS)

    Kibble, Tom; Srivastava, Ajit

    2013-10-01

    It is always exciting when developments in one branch of physics turn out to have relevance in a quite different branch. It would be hard to find two branches farther apart in terms of energy scales than early-universe cosmology and low-temperature condensed matter physics. Nevertheless ideas about the formation of topological defects during rapid phase transitions that originated in the context of the very early universe have proved remarkably fruitful when applied to a variety of condensed matter systems. The mathematical frameworks for describing these systems can be very similar. This interconnection has led to a deeper understanding of the phenomena in condensed matter systems utilizing ideas from cosmology. At the same time, one can view these condensed matter analogues as providing, at least in a limited sense, experimental access to the phenomena of the early universe for which no direct probe is possible. As this special issue well illustrates, this remains a dynamic and exciting field. The basic idea is that when a system goes through a rapid symmetry-breaking phase transition from a symmetric phase into one with spontaneously broken symmetry, the order parameter may make different choices in different regions, creating domains that when they meet can trap defects. The scale of those domains, and hence the density of defects, is constrained by the rate at which the system goes through the transition and the speed with which order parameter information propagates. This is what has come to be known as the Kibble-Zurek mechanism. The resultant scaling laws have now been tested in a considerable variety of different systems. The earliest experiments illustrating the analogy between cosmology and condensed matter were in liquid crystals, in particular on the isotropic-to-nematic transition, primarily because it is very easy to induce the phase transition (typically at room temperature) and to image precisely what is going on. This field remains one of the

  19. Wealth condensation in pareto macroeconomies

    NASA Astrophysics Data System (ADS)

    Burda, Z.; Johnston, D.; Jurkiewicz, J.; Kamiński, M.; Nowak, M. A.; Papp, G.; Zahed, I.

    2002-02-01

    We discuss a Pareto macroeconomy (a) in a closed system with fixed total wealth and (b) in an open system with average mean wealth, and compare our results to a similar analysis in a super-open system (c) with unbounded wealth [J.-P. Bouchaud and M. Mézard, Physica A 282, 536 (2000)]. Wealth condensation takes place in the social phase for closed and open economies, while it occurs in the liberal phase for super-open economies. In the first two cases, the condensation is related to a mechanism known from the balls-in-boxes model, while in the last case, to the nonintegrable tails of the Pareto distribution. For a closed macroeconomy in the social phase, we point to the emergence of a ``corruption'' phenomenon: a sizeable fraction of the total wealth is always amassed by a single individual.

  20. Anderson and Condensed Matter Physics

    NASA Astrophysics Data System (ADS)

    Ramakrishnan, T. V.

    The legacy of P. W. Anderson, perhaps the most fertile and influential condensed matter physicist of the second half of the twentieth century, is briefly mentioned here. I note three pervasive values. They are: emergence with its constant tendency to surprise us and to stretch our imagination, the Baconian emphasis on the experimental moorings of modern science, and mechanism as the explanatory core. Out of his work, which is spread over more than six decades and in many ways has charted modern condensed matter physics, nearly a dozen seminal contributions, chosen idiosyncratically, are mentioned at the risk of leaving out many which may also have started subfields. Some of these are: antiferromagnestism and broken symmetry, superexchange and strong electron correlations, localization in disordered systems, gauge invariance and mass, and the resonating valence bond in magnetic systems as well as in high-temperature superconductivity...

  1. Interplay between tightly focused excitation and ballistic propagation of polariton condensates in a ZnO microcavity

    NASA Astrophysics Data System (ADS)

    Hahe, R.; Brimont, C.; Valvin, P.; Guillet, T.; Li, F.; Leroux, M.; Zuniga-Perez, J.; Lafosse, X.; Patriarche, G.; Bouchoule, S.

    2015-12-01

    The formation and propagation of a polariton condensate under tightly focused excitation is investigated in a ZnO microcavity both experimentally and theoretically. Two-dimensional (2D) near-field and far-field images of the condensate are measured under quasicontinuous nonresonant excitation. The corresponding spatial profiles are compared to a model based on the Gross-Pitaevskii equation under cylindrical geometry. This paper allows one to connect the experiments performed with a small excitation laser spot and the previous kinetic models of condensation in a 2D infinite microcavity and to determine the relevant parameters of both the interaction and the relaxation between the reservoir and the condensate. Two main parameters are identified: The exciton-photon detuning through the polariton effective mass and the temperature, which determines the efficiency of the relaxation from the reservoir to the condensate.

  2. Atomistic modeling of dropwise condensation

    NASA Astrophysics Data System (ADS)

    Sikarwar, B. S.; Singh, P. L.; Muralidhar, K.; Khandekar, S.

    2016-05-01

    The basic aim of the atomistic modeling of condensation of water is to determine the size of the stable cluster and connect phenomena occurring at atomic scale to the macroscale. In this paper, a population balance model is described in terms of the rate equations to obtain the number density distribution of the resulting clusters. The residence time is taken to be large enough so that sufficient time is available for all the adatoms existing in vapor-phase to loose their latent heat and get condensed. The simulation assumes clusters of a given size to be formed from clusters of smaller sizes, but not by the disintegration of the larger clusters. The largest stable cluster size in the number density distribution is taken to be representative of the minimum drop radius formed in a dropwise condensation process. A numerical confirmation of this result against predictions based on a thermodynamic model has been obtained. Results show that the number density distribution is sensitive to the surface diffusion coefficient and the rate of vapor flux impinging on the substrate. The minimum drop radius increases with the diffusion coefficient and the impinging vapor flux; however, the dependence is weak. The minimum drop radius predicted from thermodynamic considerations matches the prediction of the cluster model, though the former does not take into account the effect of the surface properties on the nucleation phenomena. For a chemically passive surface, the diffusion coefficient and the residence time are dependent on the surface texture via the coefficient of friction. Thus, physical texturing provides a means of changing, within limits, the minimum drop radius. The study reveals that surface texturing at the scale of the minimum drop radius does not provide controllability of the macro-scale dropwise condensation at large timescales when a dynamic steady-state is reached.

  3. Confinement from constant field condensates

    NASA Astrophysics Data System (ADS)

    Gaete, Patricio; Guendelman, Eduardo; Spallucci, Euro

    2007-01-01

    For (2 + 1)- and (3 + 1)-dimensional reformulated SU (2) Yang-Mills theory, we compute the interaction potential within the framework of the gauge-invariant but path-dependent variables formalism. This reformulation is due to the presence of a constant gauge field condensate. Our results show that the interaction energy contains a linear term leading to the confinement of static probe charges. This result is equivalent to that of the massive Schwinger model.

  4. Condensation on Slippery Asymmetric Bumps

    NASA Astrophysics Data System (ADS)

    Park, Kyoo-Chul; Kim, Philseok; Aizenberg, Joanna

    Controlling dropwise condensation by designing surfaces that enable droplets to grow rapidly and be shed as quickly as possible is fundamental to water harvesting systems, thermal power generation, distillation towers, etc. However, cutting-edge approaches based on micro/nanoscale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach based on principles derived from Namib desert beetles, cacti, and pitcher plants that synergistically couples both aspects of condensation and outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle's bump geometry in promoting condensation, we show how to maximize vapor diffusion flux at the apex of convex millimetric bumps by optimizing curvature and shape. Integrating this apex geometry with a widening slope analogous to cactus spines couples rapid drop growth with fast directional transport, by creating a free energy profile that drives the drop down the slope. This coupling is further enhanced by a slippery, pitcher plant-inspired coating that facilitates feedback between coalescence-driven growth and capillary-driven motion. We further observe an unprecedented six-fold higher exponent in growth rate and much faster shedding time compared to other surfaces. We envision that our fundamental understanding and rational design strategy can be applied to a wide range of phase change applications.

  5. Extreme-UV lithography condenser

    DOEpatents

    Sweatt, William C.; Sweeney, Donald W.; Shafer, David; McGuire, James

    2001-01-01

    Condenser system for use with a ringfield camera in projection lithography where the condenser includes a series of segments of a parent aspheric mirror having one foci at a quasi-point source of radiation and the other foci at the radius of a ringfield have all but one or all of their beams translated and rotated by sets of mirrors such that all of the beams pass through the real entrance pupil of a ringfield camera about one of the beams and fall onto the ringfield radius as a coincident image as an arc of the ringfield. The condenser has a set of correcting mirrors with one of the correcting mirrors of each set, or a mirror that is common to said sets of mirrors, from which the radiation emanates, is a concave mirror that is positioned to shape a beam segment having a chord angle of about 25 to 85 degrees into a second beam segment having a chord angle of about 0 to 60 degrees.

  6. Quark and gluon condensates in isospin matter

    SciTech Connect

    He Lianyi; Jiang Yin; Zhuang Pengfei

    2009-04-15

    By applying the Hellmann-Feynman theorem to a charged pion gas, the quark and gluon condensates at low isospin density are determined by precise pion properties. At intermediate density around f{sub {pi}}{sup 2}m{sub {pi}}, from both the estimation for the dilute pion gas and the calculation with the Nambu-Jona-Lasinio model, the quark condensate is strongly and monotonously suppressed, while the gluon condensate is enhanced and can be larger than its vacuum value. This unusual behavior of the gluon condensate is universal for Bose condensed matter of mesons. Our results can be tested by lattice calculations at finite isospin density.

  7. Compressible Heating in the Condense Phase due to Pore Collapse in HMX

    NASA Astrophysics Data System (ADS)

    Zhang, Ju; Jackson, Thomas

    Axisymmetric pore collapse in HMX is studied numerically by solving multi-phase reactive Euler equations. The generation of hot spots in the condense phase due to compressible heating is examined. The motivation is to improve the understanding of the role of embedded cavities in the initiation of reaction in explosives, and to investigate the effect of hot spots in the condense phase due to compressible heating alone, complementing previous study on hot spots due to the reaction in the gas phase and at the interface. It is found that the shock-cavity interaction results in pressures and thus temperatures that are substantially higher than the post-shock values in the condense phase. However, these hot spots in the condense phase due to compressible heating alone do not seem to be sufficiently hot to lead to ignition at shock pressures of 1-3 GPa. Thus, compressible heating in the condense phase may be excluded as a mechanism for initiation of explosives. It should be pointed out that the ignition threshold for the temperature, the so-called ``switch-on'' temperature, of hot spots depend on chemistry kinetics parameters. Switch-on temperature is lower for faster reaction rate. The current chemistry kinetics parameters are based on previous experimental work. This work was supported in part by the Defense Threat Reduction Agency and by the U.S. Department of Energy.

  8. R410A condensation inside a commercial brazed plate heat exchanger

    SciTech Connect

    Longo, Giovanni A.

    2009-01-15

    This paper presents the heat transfer coefficients and the pressure drop measured during HFC-410A condensation inside a commercial brazed plate heat exchanger: the effects of saturation temperature, refrigerant mass flux and vapour super-heating are investigated. The heat transfer coefficients show weak sensitivity to saturation temperature and great sensitivity to refrigerant mass flux and vapour super-heating. At low refrigerant mass flux (<20 kg/m{sup 2} s) the saturated vapour condensation heat transfer coefficients are not dependent on mass flux and are well predicted by Nusselt [W. Nusselt, Die oberflachenkondensation des wasserdampfes, Energy 60 (1916) 541-546, 569-575] analysis for vertical surface: the condensation process is gravity controlled. For higher refrigerant mass flux (>20 kg/m{sup 2}s) the saturated vapour condensation heat transfer coefficients depend on mass flux and are well predicted by Akers et al. [W.W. Akers, H.A. Deans, O.K. Crosser, Condensing heat transfer within horizontal tubes, Chem. Eng. Prog. Symp. Series 55 (1959) 171-176] equation: forced convection condensation occurs. In the forced convection condensation region the heat transfer coefficients show a 30% increase for a doubling of the refrigerant mass flux. The condensation heat transfer coefficients of super-heated vapour are 8-10% higher than those of saturated vapour and are well predicted by Webb [R.L. Webb, Convective condensation of superheated vapor, ASME J. Heat Transfer 120 (1998) 418-421] model. A simple linear equation based on the kinetic energy per unit volume of the refrigerant flow is proposed for the computation of the frictional pressure drop. (author)

  9. Exact periodic and solitonic states of the spinor condensates in a uniform external potential

    NASA Astrophysics Data System (ADS)

    Zhang, Zhi-Hai; Yang, Shi-Jie

    2016-08-01

    We propose a method to analytically solve the one-dimensional coupled nonlinear Gross-Pitaevskii equations which govern the motion of the spinor Bose-Einstein condensates. In a uniform external potential, several classes of exact periodic and solitonic solutions, either in real or in complex forms, are obtained for both the F=1 and F=2 condensates for the Hamiltonian comprising the kinetic energy, the linear and the quadratic Zeeman energies. Real solutions take the form of composite soliton trains. Complex solutions correspond to the mass counter-flows as well as spin currents. These solutions are general that contains neither approximations nor constraints on the system parameters.

  10. BOOK REVIEW: Soft Condensed Matter

    NASA Astrophysics Data System (ADS)

    Jones, Richard A. L.

    2002-11-01

    The author states in the preface of the book that the aim is '...to give a unified overview of the various aspects of the physics of soft condensed matter'. The book succeeds in fulfilling this aim in many respects. i) The style is fluent and concise and gives the necessary explanations to make its content understandable to people with some knowledge of the basic principles of physics. ii) The content of the book is complete enough to give a panoramic view of the landscape of soft condensed matter. The first two chapters give, respectively, a short introduction and a presentation of forces, energies and timescales, giving a general overview and pointing out the particular importance of different aspects such as timescales, which are much more important in soft condensed matter than in traditional or 'hard' condensed matter. The next chapter, devoted to phase transition, recalls that the equilibrium between two phases is controlled by free energy considerations. Spinodal decomposition is presented as a counterpart of nucleation and growth. Again, characteristic length scales are considered and applied to a phase separation mixture of polymers in a common solvent. The following three chapters are devoted respectively to specific topics: colloidal dispersion, polymers and gelation. The stability and phase behaviour of colloids are related to the interaction between colloidal particles. Properties of colloidal crystals as well as colloidal dispersion are depicted in terms of stabilization of crystalline colloids. The flow properties of colloidal dispersion are presented in terms of free energy minimization and the structure of the dispersion. After a brief introduction to polymer chemistry and architecture, the coil-globule transition is discussed. Viscoelasticity of polymers is described and discussed by introducing the notion of entanglement. This leads to the introduction of the tube model and the theory of reptation. The sol-gel transition is presented

  11. CDW-Exciton Condensate Competition and a Condensate Driven Force

    NASA Astrophysics Data System (ADS)

    Özgün, Ege; Hakioğlu, Tuğrul

    2016-08-01

    We examine the competition between the charge-density wave (CDW) instability and the excitonic condensate (EC) in spatially separated layers of electrons and holes. The CDW and the EC order parameters (OPs), described by two different mechanisms and hence two different transition temperatures TcCDW and TcEC, are self-consistently coupled by a microscopic mean field theory. We discuss the results in our model specifically focusing on the transition-metal dichalcogenides which are considered as the most typical examples of strongly coupled CDW/EC systems with atomic layer separations where the electronic energy scales are large with the critical temperatures in the range TcEC ˜ TcCDW ˜ 100-200 K. An important consequence of this is that the excitonic energy gap, hence the condensed free energy, vary with the layer separation resulting in a new type of force FEC. We discuss the possibility of this force as the possible driver of the structural lattice deformation observed in some TMDCs with a particular attention on the 1T-TiSe2 below 200 K.

  12. Condensing efficiency of the truncated cone condenser and its comparison with the Winston cone condenser in terahertz region

    NASA Astrophysics Data System (ADS)

    Aoki, Makoto; Hiromoto, Norihisa

    2015-01-01

    The angle-dependent condensing efficiency of a truncated cone condenser (TCC) in the terahertz (THz) region has been examined by 2D ray tracing and 3D electromagnetic simulation. The condensing efficiency in the THz region is transferred to that in the optical region by theoretical dispersive reflection from a rough surface, and it is confirmed that the latter is consistent with the measured condensing efficiency in the optical region. Although the TCC has a gradual field of view (FOV) compared with the Winston cone condenser (WCC), we improved the steepness of the FOV by adding a baffle before the input aperture of the TCC. We also proved that the TCC has a high condensing efficiency at around normal incidence in comparison with the WCC in the THz region.

  13. Condensation on slippery asymmetric bumps

    NASA Astrophysics Data System (ADS)

    Park, Kyoo-Chul; Kim, Philseok; Grinthal, Alison; He, Neil; Fox, David; Weaver, James C.; Aizenberg, Joanna

    2016-03-01

    Controlling dropwise condensation is fundamental to water-harvesting systems, desalination, thermal power generation, air conditioning, distillation towers, and numerous other applications. For any of these, it is essential to design surfaces that enable droplets to grow rapidly and to be shed as quickly as possible. However, approaches based on microscale, nanoscale or molecular-scale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach—based on principles derived from Namib desert beetles, cacti, and pitcher plants—that synergistically combines these aspects of condensation and substantially outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle’s bumpy surface geometry in promoting condensation, and using theoretical modelling, we show how to maximize vapour diffusion fluxat the apex of convex millimetric bumps by optimizing the radius of curvature and cross-sectional shape. Integrating this apex geometry with a widening slope, analogous to cactus spines, directly couples facilitated droplet growth with fast directional transport, by creating a free-energy profile that drives the droplet down the slope before its growth rate can decrease. This coupling is further enhanced by a slippery, pitcher-plant-inspired nanocoating that facilitates feedback between coalescence-driven growth and capillary-driven motion on the way down. Bumps that are rationally designed to integrate these mechanisms are able to grow and transport large droplets even against gravity and overcome the effect of an unfavourable temperature gradient. We further observe an unprecedented sixfold-higher exponent of growth rate, faster onset, higher steady-state turnover rate, and a greater volume of water collected compared to other surfaces. We envision that this fundamental understanding and rational design strategy can be

  14. Condensation on slippery asymmetric bumps.

    PubMed

    Park, Kyoo-Chul; Kim, Philseok; Grinthal, Alison; He, Neil; Fox, David; Weaver, James C; Aizenberg, Joanna

    2016-03-01

    Controlling dropwise condensation is fundamental to water-harvesting systems, desalination, thermal power generation, air conditioning, distillation towers, and numerous other applications. For any of these, it is essential to design surfaces that enable droplets to grow rapidly and to be shed as quickly as possible. However, approaches based on microscale, nanoscale or molecular-scale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach--based on principles derived from Namib desert beetles, cacti, and pitcher plants--that synergistically combines these aspects of condensation and substantially outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle's bumpy surface geometry in promoting condensation, and using theoretical modelling, we show how to maximize vapour diffusion fluxat the apex of convex millimetric bumps by optimizing the radius of curvature and cross-sectional shape. Integrating this apex geometry with a widening slope, analogous to cactus spines, directly couples facilitated droplet growth with fast directional transport, by creating a free-energy profile that drives the droplet down the slope before its growth rate can decrease. This coupling is further enhanced by a slippery, pitcher-plant-inspired nanocoating that facilitates feedback between coalescence-driven growth and capillary-driven motion on the way down. Bumps that are rationally designed to integrate these mechanisms are able to grow and transport large droplets even against gravity and overcome the effect of an unfavourable temperature gradient. We further observe an unprecedented sixfold-higher exponent of growth rate, faster onset, higher steady-state turnover rate, and a greater volume of water collected compared to other surfaces. We envision that this fundamental understanding and rational design strategy can be

  15. Condensing osteitis in oral region.

    PubMed

    Holly, D; Jurkovic, R; Mracna, J

    2009-01-01

    Condensing osteitis is defined as pathologic growth of maxillomandibular bones characterized by mild clinical symptoms. The bone thickening reflects the impaired bone rearrangement in response to mild infection of dental pulp. This clinical study describes case reports of patients sent to us with radiological findings and clinical examination that failed to lead to definitive diagnosis. On differential diagnosis, all bone tissue tumors were considered. Based on clinical and radiological findings (bone density and trabeculation of the bone) we settled on the diagnosis of osteitis condensans, which allowed us to remain in conservative therapy in terms of observing the patient (Fig. 3, Ref. 26). Full Text (Free, PDF) www.bmj.sk. PMID:20120441

  16. Turbulent Distortion of Condensate Accretion

    NASA Technical Reports Server (NTRS)

    Hazoume, R.; Orou Chabi, J.; Johnson, J. A., III

    1997-01-01

    When a simple model for the relationship between the density-temperature fluctuation correlation and mean values is used, we determine that the rate of change of turbulent intensity can influence directly the accretion rate of droplets. Considerable interest exists in the accretion rate for condensates in nonequilibrium flow with icing and the potential role which reactant accretion can play in nonequilibrium exothermic reactant processes. Turbulence is thought to play an important role in such flows. It has already been experimentally determined that turbulence influences the sizes of droplets in the heterogeneous nucleation of supersaturated vapors. This paper addresses the issue of the possible influence of turbulence on the accretion rate of droplets.

  17. Condensing Non-Abelian Quasiparticles

    SciTech Connect

    Hermanns, M.

    2010-02-05

    A most interesting feature of certain fractional quantum Hall states is that their quasiparticles obey non-Abelian fractional statistics. So far, candidate non-Abelian wave functions have been constructed from conformal blocks in cleverly chosen conformal field theories. In this work we present a hierarchy scheme by which we can construct daughter states by condensing non-Abelian quasiparticles (as opposed to quasiholes) in a parent state, and show that the daughters have a non-Abelian statistics that differs from the parent. In particular, we discuss the daughter of the bosonic, spin-polarized Moore-Read state at nu=4/3 as an explicit example.

  18. Predictive thermodynamics for condensed phases.

    PubMed

    Glasser, Leslie; Jenkins, H Donald Brooke

    2005-10-01

    Thermodynamic information is central to assessment of the stability and reactivity of materials. However, because of both the demanding nature of experimental thermodynamics and the virtually unlimited number of conceivable compounds, experimental data is often unavailable or, for hypothetical materials, necessarily impossible to obtain. We describe simple procedures for thermodynamic prediction for condensed phases, both ionic and organic covalent, principally via formula unit volumes (or density); our volume-based approach (VBT) provides a new thermodynamic tool for such assessment. These methods, being independent of detailed knowledge of crystal structures, are applicable to liquids and amorphous materials as well as to crystalline solids. Examples of their use are provided. PMID:16172676

  19. Velocity Condensation for Magnetotactic Bacteria.

    PubMed

    Rupprecht, Jean-François; Waisbord, Nicolas; Ybert, Christophe; Cottin-Bizonne, Cécile; Bocquet, Lydéric

    2016-04-22

    Magnetotactic swimmers tend to align along magnetic field lines against stochastic reorientations. We show that the swimming strategy, e.g., active Brownian motion versus run-and-tumble dynamics, strongly affects the orientation statistics. The latter can exhibit a velocity condensation whereby the alignment probability density diverges. As a consequence, we find that the swimming strategy affects the nature of the phase transition to collective motion, indicating that Lévy run-and-tumble walks can outperform active Brownian processes as strategies to trigger collective behavior. PMID:27152825

  20. Velocity Condensation for Magnetotactic Bacteria

    NASA Astrophysics Data System (ADS)

    Rupprecht, Jean-François; Waisbord, Nicolas; Ybert, Christophe; Cottin-Bizonne, Cécile; Bocquet, Lydéric

    2016-04-01

    Magnetotactic swimmers tend to align along magnetic field lines against stochastic reorientations. We show that the swimming strategy, e.g., active Brownian motion versus run-and-tumble dynamics, strongly affects the orientation statistics. The latter can exhibit a velocity condensation whereby the alignment probability density diverges. As a consequence, we find that the swimming strategy affects the nature of the phase transition to collective motion, indicating that Lévy run-and-tumble walks can outperform active Brownian processes as strategies to trigger collective behavior.

  1. Bio-oil fractionation and condensation

    DOEpatents

    Brown, Robert C; Jones, Samuel T; Pollard, Anthony

    2013-07-02

    A method of fractionating bio-oil vapors which involves providing bio-oil vapors comprising bio-oil constituents is described. The bio-oil vapors are cooled in a first stage which comprises a condenser having passages for the bio-oil separated by a heat conducting wall from passages for a coolant. The coolant in the condenser of the first stage is maintained at a substantially constant temperature, set at a temperature in the range of 75 to 100.degree. C., to condense a first liquid fraction of liquefied bio-oil constituents in the condenser of the first stage. The first liquid fraction of liquified bio-oil constituents from the condenser in the first stage is collected. Also described are steps for subsequently recovering further liquid fractions of liquefied bio-oil constituents. Particular compositions of bio-oil condensation products are also described.

  2. Axions: Bose Einstein condensate or classical field?

    NASA Astrophysics Data System (ADS)

    Davidson, Sacha

    2015-05-01

    The axion is a motivated dark matter candidate, so it would be interesting to find features in Large Scale Structures specific to axion dark matter. Such features were proposed for a Bose Einstein condensate of axions, leading to confusion in the literature (to which I contributed) about whether axions condense due to their gravitational interactions. This note argues that the Bose Einstein condensation of axions is a red herring: the axion dark matter produced by the misalignment mechanism is already a classical field, which has the distinctive features attributed to the axion condensate (BE condensates are described as classical fields). This note also estimates that the rate at which axion particles condense to the field, or the field evaporates to particles, is negligible.

  3. Bose condensation in topologically ordered quantum liquids

    NASA Astrophysics Data System (ADS)

    Neupert, Titus; He, Huan; von Keyserlingk, Curt; Sierra, German; Bernevig, Andrei

    The condensation of bosons can induce transitions between topological quantum field theories (TQFTs). This as been previously investigated through the formalism of Frobenius algebras and with the use of Vertex lifting coefficients. We discuss an alternative, algebraic approach to boson condensation in TQFTs that is physically motivated and computationally efficient. With a minimal set of assumptions, such as commutativity of the condensation with the fusion of anyons, we can prove a number of theorems linking boson condensation in TQFTs with algebra extensions in conformal field theories and with the problem of factorization of completely positive matrices over the positive integers. We propose an algorithm for obtaining a condensed theory fusion algebra and its modular matrices. For example, this formalism can be used to build multi-layer TQFTs which could be a starting point to build three-dimensional topologically ordered phases. Using this formalism, we also give examples of bosons that cannot undergo a condensation transition due to topological obstructions.

  4. Multichannel quench-flow microreactor chip for parallel reaction monitoring.

    PubMed

    Bula, Wojciech P; Verboom, Willem; Reinhoudt, David N; Gardeniers, Han J G E

    2007-12-01

    This paper describes a multichannel silicon-glass microreactor which has been utilized to investigate the kinetics of a Knoevenagel condensation reaction under different reaction conditions. The reaction is performed on the chip in four parallel channels under identical conditions but with different residence times. A special topology of the reaction coils overcomes the common problem arising from the difference in pressure drop of parallel channels having different length. The parallelization of reaction coils combined with chemical quenching at specific locations results in a considerable reduction in experimental effort and cost. The system was tested and showed good reproducibility in flow properties and reaction kinetic data generation. PMID:18030392

  5. The condensate from torus knots

    NASA Astrophysics Data System (ADS)

    Gorsky, A.; Milekhin, A.; Sopenko, N.

    2015-09-01

    We discuss recently formulated instanton-torus knot duality in Ω-deformed 5D SQED on {{R}}^4× {S}^1 focusing at the microscopic aspects of the condensate formation in the instanton ensemble. Using the chain of dualities and geometric transitions we embed the SQED with a surface defect into the SU(2) SQCD with N f = 4 and identify the numbers ( n, m) of the torus T n, m knot as instanton charge and electric charge. The HOMFLY torus knot invariants in the fundamental representation provide entropic factor in the condensate of the massless flavor counting the degeneracy of the instanton-W-boson web with instanton and electric numbers ( n, m) but different spin and flavor content. Using the inverse geometrical transition we explain how our approach is related to the evaluation of the HOMFLY invariants in terms of Wilson loop in 3d CS theory. The reduction to 4D theory is briefly considered and some analogy with baryon vertex is conjectured.

  6. Condensation induced water hammer safety

    SciTech Connect

    Gintner, M.A.

    1997-03-10

    Condensation induced water hammer events in piping systems can cause catastrophic steam system failures which can result in equipment damage, personal injury, and even death. As an industry, we have learned to become accustomed to the ''banging'' that we often hear in our steam piping systems, and complacent in our actions to prevent it. It is unfortunate that lives are lost needlessly, as this type of water hammer event is preventable if one only applies some basic principles when operating and maintaining their steam systems. At the U. S. Department of Energy's Hanford Site where I work, there was one such accident that occurred in 1993 which took the life of a former co-worker and friend of mine. Hanford was established as part of the Manhattan Project during World War II. it is a 560 square mile complex located along the banks of the Columbia River in Southeastern Washington State. For almost 45 years, hanford's mission was to produce weapons grade plutonium for our nations defense programs. Today, Hanford no longer produces plutonium, but is focused on site clean-up and economic diversification. Hanford still uses steam for heating and processing activities, utilizing over 20 miles of piping distribution systems similar to those found in industry. Although these aging systems are still sound, they cannot stand up to the extreme pressure pulses developed by a condensation induced water hammer.

  7. High-temperature condensates in carbonaceous chondrites

    NASA Technical Reports Server (NTRS)

    Grossman, L.

    1977-01-01

    Equilibrium thermodynamic calculations of the sequence of condensation of minerals from a cooling gas of solar composition play an important role in explaining the mineralogy and trace element content of different types of inclusions in carbonaceous chondrites. Group IV B iron meteorites and enstatite chondrites may also be direct condensates from the solar nebula. Condensation theory provides a framework within which chemical fractionations between different classes of chondrites may be understood.

  8. Bose-Einstein condensation of 84Sr.

    PubMed

    Martinez de Escobar, Y N; Mickelson, P G; Yan, M; DeSalvo, B J; Nagel, S B; Killian, T C

    2009-11-13

    We report Bose-Einstein condensation of (84)Sr in an optical dipole trap. Efficient laser cooling on the narrow intercombination line and an ideal s-wave scattering length allow the creation of large condensates (N(0) approximately 3 x 10(5)) even though the natural abundance of this isotope is only 0.6%. Condensation is heralded by the emergence of a low-velocity component in time-of-flight images. PMID:20365965

  9. Increased Availability From Improved Condenser Design

    SciTech Connect

    Harpster, Joseph W.

    2002-07-01

    Performance parameters and flow characteristics on the shell side of surface condensers are becoming better understood. Contributing to this knowledge base is the recent ability to measure the physical properties as well as the quantity of gases being removed from the condenser by air removal equipment. Reviewed here are the commonality of these data from many operating condensers obtained over the past six years and other known condenser measurements, theory and laboratory experiments. These are combined to formulate global theoretical description of condenser dynamics describing the mechanism responsible for aeration and de-aeration, excess back pressure buildup due to air ingress or generation of other noncondensable gases, and the dissolubility of corrosive gases in condensate. The theoretical description supports a dynamic model useful for deciding condenser configuration design and design improvements. Features of design found in many operating condensers that promote aeration and resulting corrosion are presented. The benefits of the model and engineering design modifications to plant life cycle management, improved condenser performance, outage reduction and reliability improvements, lost load recovery and fuel savings are discussed. (author)

  10. Vapor condensation on a turbulent liquid interface

    NASA Technical Reports Server (NTRS)

    Helmick, M. R.; Khoo, B. C.; Sonin, A. A.

    1987-01-01

    An experimental investigation which seeks the fundamental relationship between the interfacial condensation rate and the parameters which control it when the liquid side is turbulent is discussed. The scaling laws for free-surface condensation are discussed for this case. It is argued that the condensation of cryogenic liquids can, in principle, be simulated in experiments using steam and water. Data are presented for the condensation rate in terms of the dimensionless scaling parameters which involve the fluid properties and the liquid-side turbulence velocity and length scales.

  11. Enhanced condensation heat transfer with wettability patterning

    NASA Astrophysics Data System (ADS)

    Sinha Mahapatra, Pallab; Ghosh, Aritra; Ganguly, Ranjan; Megaridis, Constantine

    2015-11-01

    Condensation of water vapor on metal surfaces is useful for many engineering applications. A facile and scalable method is proposed for removing condensate from a vertical plate during dropwise condensation (DWC) in the presence of non-condensable gases (NCG). We use wettability-patterned superhydrophilic tracks (filmwise condensing domains) on a mirror-finish (hydrophilic) aluminum surface that promotes DWC. Tapered, horizontal ``collection'' tracks are laid to create a Laplace pressure driven flow, which collects condensate from the mirror-finish domains and sends it to vertical ``drainage tracks'' for gravity-induced shedding. An optimal design is achieved by changing the fractional area of superhydrophilic tracks with respect to the overall plate surface, and augmenting capillary-driven condensate-drainage by adjusting the track spatial layout. The design facilitates pump-less condensate drainage and enhances DWC heat transfer on the mirror-finish regions. The study highlights the relative influences of the promoting and retarding effects of dropwise and filmwise condensation zones on the overall heat transfer improvement on the substrate. The study demonstrated ~ 34% heat transfer improvement on Aluminum surface for the optimized design.

  12. Treatment of evaporator condensates by pervaporation

    DOEpatents

    Blume, Ingo; Baker, Richard W.

    1990-01-01

    A pervaporation process for separating organic contaminants from evaporator condensate streams is disclosed. The process employs a permselective membrane that is selectively permeable to an organic component of the condensate. The process involves contacting the feed side of the membrane with a liquid condensate stream, and withdrawing from the permeate side a vapor enriched in the organic component. The driving force for the process is the in vapor pressure across the membrane. This difference may be provided for instance by maintaining a vacuum on the permeate side, or by condensing the permeate. The process offers a simple, economic alternative to other separation techniques.

  13. Advances in modelling of condensation phenomena

    SciTech Connect

    Liu, W.S.; Zaltsgendler, E.; Hanna, B.

    1997-07-01

    The physical parameters in the modelling of condensation phenomena in the CANDU reactor system codes are discussed. The experimental programs used for thermal-hydraulic code validation in the Canadian nuclear industry are briefly described. The modelling of vapour generation and in particular condensation plays a key role in modelling of postulated reactor transients. The condensation models adopted in the current state-of-the-art two-fluid CANDU reactor thermal-hydraulic system codes (CATHENA and TUF) are described. As examples of the modelling challenges faced, the simulation of a cold water injection experiment by CATHENA and the simulation of a condensation induced water hammer experiment by TUF are described.

  14. ENVIRONMENTAL TECHNOLOGY VERIFICATION REPORT: NEW CONDENSATOR, INC.--THE CONDENSATOR DIESEL ENGINE RETROFIT CRANKCASE VENTILATION SYSTEM

    EPA Science Inventory

    EPA's Environmental Technology Verification Program has tested New Condensator Inc.'s Condensator Diesel Engine Retrofit Crankcase Ventilation System. Brake specific fuel consumption (BSFC), the ratio of engine fuel consumption to the engine power output, was evaluated for engine...

  15. Optimized evaporative cooling for sodium Bose-Einstein condensation against three-body loss

    SciTech Connect

    Shobu, Takahiko; Yamaoka, Hironobu; Imai, Hiromitsu; Morinaga, Atsuo; Yamashita, Makoto

    2011-09-15

    We report on a highly efficient evaporative cooling optimized experimentally. We successfully created sodium Bose-Einstein condensates with 6.4x10{sup 7} atoms starting from 6.6x10{sup 9} thermal atoms trapped in a magnetic trap by employing a fast linear sweep of radio frequency at the final stage of evaporative cooling so as to overcome the serious three-body losses. The experimental results such as the cooling trajectory and the condensate growth quantitatively agree with the numerical simulations of evaporative cooling on the basis of the kinetic theory of a Bose gas carefully taking into account our specific experimental conditions. We further discuss theoretically a possibility of producing large condensates, more than 10{sup 8} sodium atoms, by simply increasing the number of initial thermal trapped atoms and the corresponding optimization of evaporative cooling.

  16. Field measurements suggest the mechanism of laser-assisted water condensation

    PubMed Central

    Henin, S.; Petit, Y.; Rohwetter, P.; Stelmaszczyk, K.; Hao, Z.Q.; Nakaema, W.M.; Vogel, A.; Pohl, T.; Schneider, F.; Kasparian, J.; Weber, K.; Wöste, L.; Wolf, J.-P.

    2011-01-01

    Because of the potential impact on agriculture and other key human activities, efforts have been dedicated to the local control of precipitation. The most common approach consists of dispersing small particles of dry ice, silver iodide, or other salts in the atmosphere. Here we show, using field experiments conducted under various atmospheric conditions, that laser filaments can induce water condensation and fast droplet growth up to several μm in diameter in the atmosphere as soon as the relative humidity exceeds 70%. We propose that this effect relies mainly on photochemical formation of p.p.m.-range concentrations of hygroscopic HNO3, allowing efficient binary HNO3–H2O condensation in the laser filaments. Thermodynamic, as well as kinetic, numerical modelling based on this scenario semiquantitatively reproduces the experimental results, suggesting that particle stabilization by HNO3 has a substantial role in the laser-induced condensation. PMID:21878910

  17. Contrasting the Evaporation and Condensation of Water from Glassy and Amorphous Aerosol Particles

    NASA Astrophysics Data System (ADS)

    Reid, J. P.; Bones, D. L.; Power, R.; Lienhard, D.; Krieger, U. K.

    2012-04-01

    The partitioning of water between the condensed and gas phases in atmospheric aerosol is usually assumed to occur instantaneously and to be regulated by solution thermodynamics. However, the persistence of high viscosity, glassy and amorphous aerosol to low relative humidity without crystallisation occurring is now widely recognised, suggesting that the timescale for water transport to or from the particle during condensation or evaporation may be significant. A kinetic limitation on water transport could have important implications for understanding hygroscopic growth measurements made on ambient particles, the ability of particles to act as ice nuclei or cloud condensation nuclei, the kinetics of chemical aging/heterogeneous chemistry, and the rate or condensation/evaporation of semi-volatile organic components. In this study we will report on measurements of the timescale of water transport to and from glassy aerosol and ultra-high viscosity solution droplets using aerosol optical tweezers to investigate the time-response of single particles to changes in relative humidity. As a benchmark system, mixed component aerosol particles containing sucrose and sodium chloride have been used; varying the mole fractions of the two solutes allows a wide range of solution viscosities to be studied. We will show that coarse particles can take many thousands of seconds to equilibrate in size and that the timescale correlates with the estimated bulk viscosity of the particle. We will also confirm that significant inhomogeneities in particle composition can be established during evaporation or condensation. Using the experimental data to benchmark a model for equilibration time, predictions can be made of the timescale for the equilibration of accumulation mode particles during water condensation or evaporation and these predictions will be described and their significance explored. Finally, the coalescence dynamics of highly viscous aerosol particles will be reported

  18. Gravitino condensation in fivebrane backgrounds

    NASA Astrophysics Data System (ADS)

    Kitazawa, Noriaki

    2002-04-01

    We calculate the tension of the D3-brane in the fivebrane background which is described by the exactly solvable SU(2)k×U(1) world-sheet conformal field theory with large Kač-Moody level k. The D3-brane tension is extracted from the amplitude of one closed string exchange between two parallel D3-branes, and the amplitude is calculated by utilizing the open-closed string duality. The tension of the D3-brane in the background does not coincide with the one in the flat space-time even in the flat space-time limit: k-->∞. The finite curvature effect should vanish in the flat space-time limit and only the topological effect can remain. Therefore, the deviation suggests the condensation of the gravitino and/or dilatino which has been expected in the fivebrane background as a gravitational instanton.

  19. Prebiotic condensation reactions using cyanamide

    NASA Technical Reports Server (NTRS)

    Sherwood, E.; Nooner, D. W.; Eichberg, J.; Epps, D. E.; Oro, J.

    1978-01-01

    Condensation reactions in cyanamide, 4-amino-5-imidazole-carboxamide and cyanamide, imidazole systems under dehydrating conditions at moderate temperatures (60 to 100 deg C) were investigated. The cyanamide, imidazole system was used for synthesis of palmitoylglycerols from ammonium palmitate and glycerol. With the addition of deoxythymidine to the former system, P1, P2-dideoxythymidine 5 prime-phosphate was obtained; the same cyanamide, 4-amino-5-imidazole-carboxamide system was used to synthesize deoxythymidine oligonucleotides using deoxythymidine 5 prime-phosphate and deoxythymidine 5 prime-triphosphate, and peptides using glycine, phenylalanine or isoleucine with adenosine 5 prime-triphosphate. The pH requirements for these reactions make their prebiotic significance questionable; however, it is conceivable that they could occur in stable pockets of low interlayer acidity in a clay such as montmorillonite.

  20. Transient nucleation in condensed systems

    NASA Technical Reports Server (NTRS)

    Kelton, K. F.; Greer, A. L.; Thompson, C. V.

    1983-01-01

    Using classical nucleation theory we consider transient nucleation occurring in a one-component, condensed system under isothermal conditions. We obtain an exact closed-form expression for the time dependent cluster populations. In addition, a more versatile approach is developed: a numerical simulation technique which models directly the reactions by which clusters are produced. This simulation demonstrates the evolution of cluster populations and nucleation rate in the transient regime. Results from the simulation are verified by comparison with exact analytical solutions for the steady state. Experimental methods for measuring transient nucleation are assessed, and it is demonstrated that the observed behavior depends on the method used. The effect of preexisting cluster distributions is studied. Previous analytical and numerical treatments of transient nucleation are compared to the solutions obtained from the simulation. The simple expressions of Kashchiev are shown to give good descriptions of the nucleation behavior.

  1. Comparing the mechanism of water condensation and evaporation in glassy aerosol

    PubMed Central

    Bones, David L.; Reid, Jonathan P.; Lienhard, Daniel M.; Krieger, Ulrich K.

    2012-01-01

    Atmospheric models generally assume that aerosol particles are in equilibrium with the surrounding gas phase. However, recent observations that secondary organic aerosols can exist in a glassy state have highlighted the need to more fully understand the kinetic limitations that may control water partitioning in ambient particles. Here, we explore the influence of slow water diffusion in the condensed aerosol phase on the rates of both condensation and evaporation, demonstrating that significant inhibition in mass transfer occurs for ultraviscous aerosol, not just for glassy aerosol. Using coarse mode (3–4 um radius) ternary sucrose/sodium chloride/aqueous droplets as a proxy for multicomponent ambient aerosol, we demonstrate that the timescale for particle equilibration correlates with bulk viscosity and can be ≫103 s. Extrapolation of these timescales to particle sizes in the accumulation mode (e.g., approximately 100 nm) by applying the Stokes-Einstein equation suggests that the kinetic limitations imposed on mass transfer of water by slow bulk phase diffusion must be more fully investigated for atmospheric aerosol. Measurements have been made on particles covering a range in dynamic viscosity from < 0.1 to > 1013 Pa s. We also retrieve the radial inhomogeneities apparent in particle composition during condensation and evaporation and contrast the dynamics of slow dissolution of a viscous core into a labile shell during condensation with the slow percolation of water during evaporation through a more homogeneous viscous particle bulk. PMID:22753520

  2. Tunable Vapor-Condensed Nanolenses

    PubMed Central

    2015-01-01

    Nanostructured optical components, such as nanolenses, direct light at subwavelength scales to enable, among others, high-resolution lithography, miniaturization of photonic circuits, and nanoscopic imaging of biostructures. A major challenge in fabricating nanolenses is the appropriate positioning of the lens with respect to the sample while simultaneously ensuring it adopts the optimal size and shape for the intended use. One application of particular interest is the enhancement of contrast and signal-to-noise ratio in the imaging of nanoscale objects, especially over wide fields-of-view (FOVs), which typically come with limited resolution and sensitivity for imaging nano-objects. Here we present a self-assembly method for fabricating time- and temperature-tunable nanolenses based on the condensation of a polymeric liquid around a nanoparticle, which we apply to the high-throughput on-chip detection of spheroids smaller than 40 nm, rod-shaped particles with diameter smaller than 20 nm, and biofunctionalized nanoparticles, all across an ultralarge FOV of >20 mm2. Previous nanoparticle imaging efforts across similar FOVs have detected spheroids no smaller than 100 nm, and therefore our results demonstrate the detection of particles >15-fold smaller in volume, which in free space have >240 times weaker Rayleigh scattering compared to the particle sizes detected in earlier wide-field imaging work. This entire platform, with its tunable nanolens condensation and wide-field imaging functions, is also miniaturized into a cost-effective and portable device, which might be especially important for field use, mobile sensing, and diagnostics applications, including, for example, the measurement of viral load in bodily fluids. PMID:24979060

  3. Molecular attraction of condensed bodies

    NASA Astrophysics Data System (ADS)

    Derjaguin, B. V.; Abrikosova, I. I.; Lifshitz, E. M.

    2015-09-01

    From the Editorial Board. As a contribution to commemorating the 100th anniversary of the birth of Evgenii Mikhailovich Lifshitz, it was found appropriate by the Editorial Board of Uspekhi Fizicheskikh Nauk (UFN) [Physics-Uspekhi] journal that the materials of the jubilee-associated Scientific Session of the Physical Sciences Division of the Russian Academy of Sciences published in this issue (pp. 877-905) be augmented by the review paper "Molecular attraction of condensed bodies" reproduced from a 1958 UFN issue. Included in this review, in addition to an account by Evgenii Mikhailovich Lifshitz of his theory of molecular attractive forces between condensed bodies (first published in Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki (ZhETF) in 1955 and in its English translation Journal of Experimental and Theoretical Physics (JETP) in 1956), is a summary of a series of experimental studies beginning in 1949 by Irina Igorevna Abrikosova at the Institute of Physical Chemistry of the Academy of Sciences of the USSR in a laboratory led by Boris Vladimirovich Derjaguin (1902-1994), a Corresponding Member of the USSR Academy of Sciences. In 1958, however, UFN was not yet available in English translation, so the material of the review is insufficiently accessible to the present-day English-speaking reader. This is the reason why the UFN Editorial Board decided to contribute to celebrating the 100th anniversary of E M Lifshitz's birthday by reproducing on the journal's pages a 1958 review paper which contains both E M Lifshitz's theory itself and the experimental data that underpinned it (for an account of how Evgenii Mikhailovich Lifshitz was enlisted to explain the experimental results of I I Abrikosova and B V Derjaguin, see the letter to the editors N P Danilova on page 925 of this jubilee collection of publications).

  4. CFD simulation of water vapour condensation in the presence of non-condensable gas in vertical cylindrical condensers.

    PubMed

    Li, Jun-De

    2013-02-01

    This paper presents the simulation of the condensation of water vapour in the presence of non-condensable gas using computational fluid dynamics (CFD) for turbulent flows in a vertical cylindrical condenser tube. The simulation accounts for the turbulent flow of the gas mixture, the condenser wall and the turbulent flow of the coolant in the annular channel with no assumptions of constant wall temperature or heat flux. The condensate film is assumed to occupy a negligible volume and its effect on the condensation of the water vapour has been taken into account by imposing a set of boundary conditions. A new strategy is used to overcome the limitation of the currently available commercial CFD package to solve the simultaneous simulation of flows involving multispecies and fluids of gas and liquid in separate channels. The results from the CFD simulations are compared with the experimental results from the literature for the condensation of water vapour with air as the non-condensable gas and for inlet mass fraction of the water vapour from 0.66 to 0.98. The CFD simulation results in general agree well with the directly measured quantities and it is found that the variation of heat flux in the condenser tube is more complex than a simple polynomial curve fit. The CFD results also show that, at least for flows involving high water vapour content, the axial velocity of the gas mixture at the interface between the gas mixture and the condensate film is in general not small and cannot be neglected. PMID:24850953

  5. CFD simulation of water vapour condensation in the presence of non-condensable gas in vertical cylindrical condensers

    PubMed Central

    Li, Jun-De

    2013-01-01

    This paper presents the simulation of the condensation of water vapour in the presence of non-condensable gas using computational fluid dynamics (CFD) for turbulent flows in a vertical cylindrical condenser tube. The simulation accounts for the turbulent flow of the gas mixture, the condenser wall and the turbulent flow of the coolant in the annular channel with no assumptions of constant wall temperature or heat flux. The condensate film is assumed to occupy a negligible volume and its effect on the condensation of the water vapour has been taken into account by imposing a set of boundary conditions. A new strategy is used to overcome the limitation of the currently available commercial CFD package to solve the simultaneous simulation of flows involving multispecies and fluids of gas and liquid in separate channels. The results from the CFD simulations are compared with the experimental results from the literature for the condensation of water vapour with air as the non-condensable gas and for inlet mass fraction of the water vapour from 0.66 to 0.98. The CFD simulation results in general agree well with the directly measured quantities and it is found that the variation of heat flux in the condenser tube is more complex than a simple polynomial curve fit. The CFD results also show that, at least for flows involving high water vapour content, the axial velocity of the gas mixture at the interface between the gas mixture and the condensate film is in general not small and cannot be neglected. PMID:24850953

  6. Bose-Einstein-condensate heating by atomic losses

    SciTech Connect

    Dziarmaga, Jacek; Sacha, Krzysztof

    2003-10-01

    Atomic Bose-Einstein condensate is heated by atomic losses. The losses act as a heat reservoir for the condensate. The condensate is approaching a state of thermal equilibrium with a thermal depletion ranging from 1% for a uniform three-dimensional (3D) condensate to around 13% for a quasi-1D condensate in a harmonic trap.

  7. Quantum metrology with Bose-Einstein condensates

    SciTech Connect

    Boixo, Sergio; Datta, Animesh; Davis, Matthew J.; Flammia, Steven T.; Shaji, Anil; Tacla, Alexandre B.; Caves, Carlton M.

    2009-04-13

    We show how a generalized quantum metrology protocol can be implemented in a two-mode Bose-Einstein condensate of n atoms, achieving a sensitivity that scales better than 1/n and approaches 1/n{sup 3/2} for appropriate design of the condensate.

  8. Dielectric strength of sulfur hexafluoride upon condensation

    SciTech Connect

    Antonov, A.V.; Lyapin, A.G.; Popkov, V.I.

    1983-01-01

    The behavior of sulfur hexafluoride in a sealed high-voltage device has been modeled for cooling to the condensation point of the insulating medium. The temperature dependences of the breakdown voltages of sulfur hexafluoride have been investigated for several interelectrode separations. The dielectric strength has been shown to decrease upon condensation with formation of a bridge of boiling liquid phase between the electrodes.

  9. Alignment and tolerancing of a cardioid condenser

    NASA Astrophysics Data System (ADS)

    Prince, S. M.; McGuigan, W. G.

    2007-09-01

    Design details of a cardioid dark field condenser are shown ranging from the theoretical performance of a cardioid to the best-fit spherical surface. The manufacturing tolerances, fabrication techniques and debug methods are discussed for this condenser. The primary tolerances to be achieved are center thickness of the cardioid element and maintenance of its center of curvature relative to the focal plane.

  10. Fragmentation of Bose-Einstein condensates

    NASA Astrophysics Data System (ADS)

    Mueller, Erich J.; Ho, Tin-Lun; Ueda, Masahito; Baym, Gordon

    2006-09-01

    We present the theory of bosonic systems with multiple condensates, providing a unified description of various model systems that are found in the literature. We discuss how degeneracies, interactions, and symmetries conspire to give rise to this unusual behavior. We show that as degeneracies multiply, so do the varieties of fragmentation, eventually leading to strongly correlated states with no trace of condensation.

  11. Hydrophilic structures for condensation management in appliances

    DOEpatents

    Kuehl, Steven John; Vonderhaar, John J.; Wu, Guolian; Wu, Mianxue

    2016-02-02

    An appliance that includes a cabinet having an exterior surface; a refrigeration compartment located within the cabinet; and a hydrophilic structure disposed on the exterior surface. The hydrophilic structure is configured to spread condensation. The appliance further includes a wicking structure located in proximity to the hydrophilic structure, and the wicking structure is configured to receive the condensation.

  12. Soliton resonance in bose-einstein condensate

    NASA Technical Reports Server (NTRS)

    Zak, Michail; Kulikov, I.

    2002-01-01

    A new phenomenon in nonlinear dispersive systems, including a Bose-Einstein Condensate (BEC), has been described. It is based upon a resonance between an externally induced soliton and 'eigen-solitons' of the homogeneous cubic Schrodinger equation. There have been shown that a moving source of positive /negative potential induces bright /dark solitons in an attractive / repulsive Bose condensate.

  13. Condensation of liquid metals under low pressures

    SciTech Connect

    Elafify, M.M.

    1988-01-01

    The Direct Simulation Monte Carlo (DSMC) method is used to study one-dimensional condensation phenomena for a pure vapor or vapor/gas mixture. The results are fitted to an interpolation formula describing the condensation mass flux to provide a usable engineering correlation. For pure vapor, the DSMC results are compared with the available experimental data for condensation of mercury under low pressure. Results are compared also with some of the theoretical models. The comparison shows that the DSMC method is able to detect the qualitative behavior of the condensation mass flux, although it overestimates the mass flux by 20-30%. Compared with other introduced theoretical models, the DSMC method has the most-consistent representation of the qualitative behavior of the condensation mass flux. The method was also used to represent condensation in the presence of a noncondensable gas. A formal proof for choosing collision partners was introduced and applied in the case of condensation in the presence of a noncondensable gas. The method is applied to condensation of mercury in the presence of different monatomic noncondensable gases at different partial pressures.

  14. Collision of Bose Condensate Dark Matter structures

    SciTech Connect

    Guzman, F. S.

    2008-12-04

    The status of the scalar field or Bose condensate dark matter model is presented. Results about the solitonic behavior in collision of structures is presented as a possible explanation to the recent-possibly-solitonic behavior in the bullet cluster merger. Some estimates about the possibility to simulate the bullet cluster under the Bose Condensate dark matter model are indicated.

  15. Cooling-Trough Condenser for Sublimation Tubes

    NASA Astrophysics Data System (ADS)

    Eisenbraun, E. J.; Lucas, J. M.

    1995-11-01

    A wrap-around, trough condenser for use with large diameter (2.5") sublimation tubes is described. The design permits attachment of the condenser to the sublimation tube without removing the tube from the heater. It also permits the use of a variety of liquid (tap water, Dry Ice, and alcohol or acetone) or solid (ice or Dry Ice) coolants.

  16. Direct condensation refrigerant recovery and restoration system

    SciTech Connect

    Grant, D.C.H.

    1992-03-10

    This patent describes a refrigerant recovery and purification system for removing gaseous refrigerant from a disabled refrigeration unit, cleaning the refrigerant of contaminants, and converting the gaseous refrigerant to a liquid state for storage. It comprises a low pressure inlet section; a high pressure storage section; the low pressure inlet section comprising: an oil and refrigerant gas separator, including a separated oil removal means, first conduit means for connecting an inlet of the separator to the disabled refrigerant unit, a slack-sided accumulator, second conduit means connecting the separator to the slack-sided accumulator, a reclaim condenser, third conduit means connecting the separator and the reclaim condenser in series, an evaporator coil in the reclaim condenser connectable to a conventional operating refrigeration system for receiving a liquid refrigerant under pressure for expansion therein, the evaporator coil forming a condensing surface for condensing the refrigerant gas at near atmospheric pressure in the condenser, a liquid receiver, a reclaimed refrigerant storage tank, fourth conduit means further connecting the liquid receiver in series with the reclaim condenser, downstream thereof, means between the reclaim condenser and the liquid receiver.

  17. Dual condensate and QCD phase transition

    SciTech Connect

    Zhang Bo; Bruckmann, Falk; Fodor, Zoltan; Szabo, Kalman K.; Gattringer, Christof

    2011-05-23

    The dual condensate is a new QCD phase transition order parameter, which connnects confinement and chiral symmetry breaking as different mass limits. We discuss the relation between the fermion spectrum at general boundary conditions and the dual condensate and show numerical results for the latter from unquenched SU(3) lattice configurations.

  18. Bose–Einstein condensation of positronium: modification of the s-wave scattering length below to the critical temperature

    NASA Astrophysics Data System (ADS)

    Morandi, O.; Hervieux, P.-A.; Manfredi, G.

    2016-04-01

    The production of a Bose–Einstein condensate made of positronium may be feasible in the near future. Below the condensation temperature, the positronium collision process is modified by the presence of the condensate. This makes the theoretical description of the positronium kinetics at low temperature challenging. Based on the quasi-particle Bogoliubov theory, we describe the many-body particle–particle collision in a simple manner. We find that, in a good approximation, the full positronium–positronium interaction can be described by an effective scattering length. Our results are general and apply to different species of bosons. The correction to the bare scattering length is expressed in terms of a single dimensionless parameter that completely characterizes the condensate.

  19. Fundamental electrode kinetics

    NASA Technical Reports Server (NTRS)

    Elder, J. P.

    1968-01-01

    Report presents the fundamentals of electrode kinetics and the methods used in evaluating the characteristic parameters of rapid-charge transfer processes at electrode-electrolyte interfaces. The concept of electrode kinetics is outlined, followed by the principles underlying the experimental techniques for the investigation of electrode kinetics.

  20. Film condensation in a horizontal rectangular duct

    NASA Technical Reports Server (NTRS)

    Lu, Qing; Suryanarayana, N. V.

    1993-01-01

    Condensation heat transfer in a horizontal rectangular duct was experimentally and analytically investigated. To prevent the dripping of condensate on the film, the experiment was conducted inside a horizontal rectangular duct with vapor condensing only on the bottom cooled plate of the duct. R-113 and FC-72 (Fluorinert Electronic Fluid developed by the 3M Company) were used as the condensing fluids. The experimental program included measurements of film thickness, local and average heat transfer coefficients, wave length, wave speed, and a study of wave initiation. The measured film thickness was used to obtain the local heat transfer coefficient. The wave initiation was studied both with condensation and with an adiabatic air-liquid flow. The test sections used in both experiments were identical.

  1. Preliminary design of condenser cleansing schedule

    SciTech Connect

    Warberg, J.; Foraker, E.K.; Civera, A.G.; Daley, M.L.

    1995-04-01

    Analysis of the operations of a fossil power plant for a 5-year period revealed a year-round trend of operating inefficiently due to elevated condenser back pressure, particularly during the summer months. A further 5-month longitudinal study between May and September of an individual condenser unit revealed a positive correlation between increasing inlet-circulating water temperature and above-design condenser back pressure. Moreover, condenser cleansing resulted in a return to approximately the design operating condition. A physical analysis of increased heat-rate and lost power generation from inefficient condenser back pressure was accomplished. Based on these observations and economic analysis, a preliminary cleansing schedule for periods of increasing circulating water temperature was derived. Further studies are planned to validate the proposed cleansing schedule.

  2. Condensed Matter Theories - Volume 22

    NASA Astrophysics Data System (ADS)

    Reinholz, Heidi; Röpke, Gerd; de Llano, Manuel

    2007-09-01

    pt. A. Fermi liquids. Pressure comparison between the spherical cellular model and the Thomas-Fermi model / G.A. Baker, Jr. Pair excitations and vertex corrections in Fermi fluids and the dynamic structure function of two-dimension 3He / H.M. Böhm, H. Godfrin, E. Krotscheck, H.J. Lauter, M. Meschke and M. Panholzer. Condensation of helium in wedges / E.S. Hernádez ... [et al.]. Non-Fermi liquid behavior from the Fermi-liquid approach / V.A. Khodel ... [et al.]. Theory of third sound and stability of thin 3He-4He superfluid films / E. Krotscheck and M.D. Miller. Pairing in asymmetrical Fermi systems / K.F. Quader and R. Liao. Ground-state properties of small 3He drops from quantum Monte Carlo simulations / E. Sola, J. Casulleras and J. Boronat. Ground-state energy and compressibility of a disordered two-dimensional electron gas / Tanatar ... [et al.]. Quasiexcitons in photoluminescence of incompressible quantum liquids / A. Wójs, A.G ladysiewicz and J.J. Quinn -- pt. B. Bose liquids. Quantum Boltzmann liquids / K.A. Gernoth, M L. Ristig and T. Lindenau. Condensate fraction in the dynamic structure function of Bose fluids / M. Saarela, F. Mazzanti and V. Apaja -- pt. C. Strongly-correlated electronic systems. Electron gas in high-field nanoscopic transport: metallic carbon nanotubes / F. Green and D. Neilson. Evolution and destruction of the Kondo effect in a capacitively coupled double dot system / D.E. Logan and M.R. Galpin. The method of increments-a wavefunction-based Ab-Initio correlation method for solids / B. Paulus. Fractionally charged excitations on frustrated lattices / E. Runge, F. Pollmann and P. Fulde. 5f Electrons in actinides: dual nature and photoemission spectra / G. Zwicknagl -- pt. D. Magnetism. Magnetism in disordered two-dimensional Kondo-Necklace / W. Brenig. On the de Haas-can Alphen oscillation in 2D / S. Fujita and D.L. Morabito. Dynamics in one-dimensional spin systems-density matrix reformalization group study / S. Nishimoto and M

  3. 3D Imaging of Water-Drop Condensation on Hydrophobic and Hydrophilic Lubricant-Impregnated Surfaces

    PubMed Central

    Kajiya, Tadashi; Schellenberger, Frank; Papadopoulos, Periklis; Vollmer, Doris; Butt, Hans-Jürgen

    2016-01-01

    Condensation of water from the atmosphere on a solid surface is an ubiquitous phenomenon in nature and has diverse technological applications, e.g. in heat and mass transfer. We investigated the condensation kinetics of water drops on a lubricant-impregnated surface, i.e., a micropillar array impregnated with a non-volatile ionic liquid. Growing and coalescing drops were imaged in 3D using a laser scanning confocal microscope equipped with a temperature and humidity control. Different stages of condensation can be discriminated. On a lubricant-impregnated hydrophobic micropillar array these are: (1) Nucleation on the lubricant surface. (2) Regular alignment of water drops between micropillars and formation of a three-phase contact line on a bottom of the substrate. (3) Deformation and bridging by coalescence which eventually leads to a detachment of the drops from the bottom substrate. The drop-substrate contact does not result in breakdown of the slippery behaviour. Contrary, on a lubricant-impregnated hydrophilic micropillar array, the condensed water drops replace the lubricant. Consequently, the surface loses its slippery property. Our results demonstrate that a Wenzel-like to Cassie transition, required to maintain the facile removal of condensed water drops, can be induced by well-chosen surface hydrophobicity. PMID:27040483

  4. 3D Imaging of Water-Drop Condensation on Hydrophobic and Hydrophilic Lubricant-Impregnated Surfaces

    NASA Astrophysics Data System (ADS)

    Kajiya, Tadashi; Schellenberger, Frank; Papadopoulos, Periklis; Vollmer, Doris; Butt, Hans-Jürgen

    2016-04-01

    Condensation of water from the atmosphere on a solid surface is an ubiquitous phenomenon in nature and has diverse technological applications, e.g. in heat and mass transfer. We investigated the condensation kinetics of water drops on a lubricant-impregnated surface, i.e., a micropillar array impregnated with a non-volatile ionic liquid. Growing and coalescing drops were imaged in 3D using a laser scanning confocal microscope equipped with a temperature and humidity control. Different stages of condensation can be discriminated. On a lubricant-impregnated hydrophobic micropillar array these are: (1) Nucleation on the lubricant surface. (2) Regular alignment of water drops between micropillars and formation of a three-phase contact line on a bottom of the substrate. (3) Deformation and bridging by coalescence which eventually leads to a detachment of the drops from the bottom substrate. The drop-substrate contact does not result in breakdown of the slippery behaviour. Contrary, on a lubricant-impregnated hydrophilic micropillar array, the condensed water drops replace the lubricant. Consequently, the surface loses its slippery property. Our results demonstrate that a Wenzel-like to Cassie transition, required to maintain the facile removal of condensed water drops, can be induced by well-chosen surface hydrophobicity.

  5. 3D Imaging of Water-Drop Condensation on Hydrophobic and Hydrophilic Lubricant-Impregnated Surfaces.

    PubMed

    Kajiya, Tadashi; Schellenberger, Frank; Papadopoulos, Periklis; Vollmer, Doris; Butt, Hans-Jürgen

    2016-01-01

    Condensation of water from the atmosphere on a solid surface is an ubiquitous phenomenon in nature and has diverse technological applications, e.g. in heat and mass transfer. We investigated the condensation kinetics of water drops on a lubricant-impregnated surface, i.e., a micropillar array impregnated with a non-volatile ionic liquid. Growing and coalescing drops were imaged in 3D using a laser scanning confocal microscope equipped with a temperature and humidity control. Different stages of condensation can be discriminated. On a lubricant-impregnated hydrophobic micropillar array these are: (1) Nucleation on the lubricant surface. (2) Regular alignment of water drops between micropillars and formation of a three-phase contact line on a bottom of the substrate. (3) Deformation and bridging by coalescence which eventually leads to a detachment of the drops from the bottom substrate. The drop-substrate contact does not result in breakdown of the slippery behaviour. Contrary, on a lubricant-impregnated hydrophilic micropillar array, the condensed water drops replace the lubricant. Consequently, the surface loses its slippery property. Our results demonstrate that a Wenzel-like to Cassie transition, required to maintain the facile removal of condensed water drops, can be induced by well-chosen surface hydrophobicity. PMID:27040483

  6. Initial Reaction Steps in the Condensed-Phase Decomposition of Propellants

    SciTech Connect

    Melius, C F; Piqueras, M C

    2001-12-11

    Understanding the reaction mechanisms for the decomposition of energetic materials in the condensed phase is critical to our development of detailed kinetic models of propellant combustion. To date, the reaction mechanisms in the condensed phase have been represented by global, reactions. The detailed elementary reactions subsequent to the initial NO{sub 2} bond scissioning are not known. Using quantum chemical calculations, we have investigated the possible early steps in the decomposition of energetic materials that can occur in the condensed phase. We have used methylnitrate, methylnitramine, and nitroethane as prototypes for O-NO{sub 2}, N-NO{sub 2} and C-NO{sub 2} nitro compounds. We find the energetic radicals formed from the initial NO{sub 2} bond scissioning can be converted to unsaturated non-radical intermediates as an alternative to the unzipping of the energetic radical. We propose a new, prompt oxidation mechanism in which the trapped HONO can add back onto the energetic molecule. This produces oxidation products in the condensed phase that normally would not be produced until much later in the flame. We have shown that this prompt oxidation mechanism is a general feature of both nitramines and nitrate esters. The resulting HONO formed by the H-atom abstraction will be strongly influenced by the cage effect of the condensed phase. The applicability of this mechanism is demonstrated for decomposition of ethylnitrate, illustrating the importance of the cage effect in enabling this mechanism to occur at low temperatures.

  7. 26. DETAIL VIEW OF MARISCAL WORKS CONDENSER STACK, THE END ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    26. DETAIL VIEW OF MARISCAL WORKS CONDENSER STACK, THE END OF THE CONDENSING SYSTEM, REUSED BY VIVIANNA WORKS AS THE END OF THEIR CONDENSING SYSTEM, LOOKING SOUTHWEST. - Mariscal Quicksilver Mine & Reduction Works, Terlingua, Brewster County, TX

  8. DETAIL VIEW OF MARISCAL WORKS CONDENSER STACK, THE END OF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    DETAIL VIEW OF MARISCAL WORKS CONDENSER STACK, THE END OF THE CONDENSING SYSTEM, REUSED BY VIVIANNA WORKS AS THE END OF THEIR CONDENSING SYSTEM, LOOKING SOUTHWEST. - Mariscal Quicksilver Mine & Reduction Works, Terlingua, Brewster County, TX

  9. Kinetic theory of diffusion-limited nucleation

    NASA Astrophysics Data System (ADS)

    Philippe, T.; Bonvalet, M.; Blavette, D.

    2016-05-01

    We examine binary nucleation in the size and composition space {R,c} using the formalism of the multivariable theory [N. V. Alekseechkin, J. Chem. Phys. 124, 124512 (2006)]. We show that the variable c drops out of consideration for very large curvature of the new phase Gibbs energy with composition. Consequently nuclei around the critical size have the critical composition, which is derived from the condition of criticality for the canonical variables and is found not to depend on surface tension. In this case, nucleation kinetics can be investigated in the size space only. Using macroscopic kinetics, we determine the general expression for the condensation rate when growth is limited by bulk diffusion, which accounts for both diffusion and capillarity and exhibits a different dependence with the critical size, as compared with the interface-limited regime. This new expression of the condensation rate for bulk diffusion-limited nucleation is the counterpart of the classical interface-limited result. We then extend our analysis to multicomponent solutions.

  10. Kinetic theory of diffusion-limited nucleation.

    PubMed

    Philippe, T; Bonvalet, M; Blavette, D

    2016-05-28

    We examine binary nucleation in the size and composition space {R,c} using the formalism of the multivariable theory [N. V. Alekseechkin, J. Chem. Phys. 124, 124512 (2006)]. We show that the variable c drops out of consideration for very large curvature of the new phase Gibbs energy with composition. Consequently nuclei around the critical size have the critical composition, which is derived from the condition of criticality for the canonical variables and is found not to depend on surface tension. In this case, nucleation kinetics can be investigated in the size space only. Using macroscopic kinetics, we determine the general expression for the condensation rate when growth is limited by bulk diffusion, which accounts for both diffusion and capillarity and exhibits a different dependence with the critical size, as compared with the interface-limited regime. This new expression of the condensation rate for bulk diffusion-limited nucleation is the counterpart of the classical interface-limited result. We then extend our analysis to multicomponent solutions. PMID:27250310

  11. Black holes in the ghost condensate

    SciTech Connect

    Mukohyama, Shinji

    2005-05-15

    We investigate how the ghost condensate reacts to black holes immersed in it. A ghost condensate defines a hypersurface-orthogonal congruence of timelike curves, each of which has the tangent vector u{sup {mu}}=-g{sup {mu}}{sup {nu}}{partial_derivative}{sub {nu}}{phi}. It is argued that the ghost condensate in this picture approximately corresponds to a congruence of geodesics. In other words, the ghost condensate accretes into a black hole just like a pressureless dust. Correspondingly, if the energy density of the ghost condensate at large distance is set to an extremely small value by cosmic expansion then the late-time accretion rate of the ghost condensate should be negligible. The accretion rate remains very small even if effects of higher derivative terms are taken into account, provided that the black hole is sufficiently large. It is also discussed how to reconcile the black-hole accretion with the possibility that the ghost condensate might behave like dark matter.

  12. Critical condensate saturation in porous media

    SciTech Connect

    Wang, X.; Mohanty, K.K.

    1999-06-15

    The understanding of gas and condensate flow in porous media is critical to the optimum exploitation of gas-condensate reservoirs. Critical condensate saturation and relative permeabilities are the key parameters for the evaluation of possible recovery strategies. This work is aimed at developing a mechanistic network model for the critical condensate saturation in which phase trapping and connectivity in the pore corners are critically examined. Porous media are modeled by networks of pore bodies interconnected by pore throats. Bodies and throats are characterized by their connectivity, shapes, and radii distributions. Pore-level laws are identified from micromodel experiments with near-critical fluids. A nonzero critical condensate saturation can be obtained in the absence of contact angle hysteresis due to the converging-diverging nature of the throats. The critical saturation at which the condensate flows is found to be a function of pore geometry, water saturation, and interfacial tension (or the Bond number). The modified sphere-pack model underpredicts the critical condensate saturation of typical sandstones. The cubic model adequately predicts the critical saturation and its experimentally observed trends.

  13. Boson condensation in topologically ordered quantum liquids

    NASA Astrophysics Data System (ADS)

    Neupert, Titus; He, Huan; von Keyserlingk, Curt; Sierra, Germán; Bernevig, B. Andrei

    2016-03-01

    Boson condensation in topological quantum field theories (TQFT) has been previously investigated through the formalism of Frobenius algebras and the use of vertex lifting coefficients. While general, this formalism is physically opaque and computationally arduous: analyses of TQFT condensation are practically performed on a case by case basis and for very simple theories only, mostly not using the Frobenius algebra formalism. In this paper, we provide a way of treating boson condensation that is computationally efficient. With a minimal set of physical assumptions, such as commutativity of lifting and the definition of confined particles, we can prove a number of theorems linking Boson condensation in TQFT with chiral algebra extensions, and with the factorization of completely positive matrices over Z+. We present numerically efficient ways of obtaining a condensed theory fusion algebra and S matrices; and we then use our formalism to prove several theorems for the S and T matrices of simple current condensation and of theories which upon condensation result in a low number of confined particles. We also show that our formalism easily reproduces results existent in the mathematical literature such as the noncondensability of five and ten layers of the Fibonacci TQFT.

  14. Condenser on-line fouling monitor

    SciTech Connect

    Tsou, J.L.; Garey, J.F.; Wiebe, D.H.

    1994-12-31

    Biological and/or chemical fouling in utility condensers is a major cause of reduced efficiency and substantially affects availability and increases operational costs. Performance losses due to water side fouling are difficult to measure and, usually, quantitative assessment of the economic impact of condenser fouling is impossible. Plant operators typically examine steam backpressure and perform complex calculations for condenser cleanliness. These direct estimates are often imprecise due to inadequate instrumentation. In addition, these data provide information on overall condenser performance which may be influenced by a number of parameters which are independent of water side fouling. Indirect (side-stream) methods are also used to isolate/measure biological or chemical fouling in condensers. This approach is extremely useful to document site/seasonal fouling rates, and for the simultaneous evaluation of treatment options. In collaboration with the Electric Power Research Institute, instrumentation has been developed which meets requirements for the direct, on-line measurement of condenser fouling. This monitor may be installed in any location within the condenser, does not interfere with routine plant operations, including on-line mechanical and chemical treatment methods, and provides continuous, real-time readings of the heat transfer efficiency of the instrumented tube. Three prototype assemblies were installed at the New England Power Company, Brayton Point Generating Station in 1993. This paper discusses the design, construction, preliminary test results, and subsequent data collected in 1994 with a redesigned system.

  15. Diquark Bose-Einstein condensation

    SciTech Connect

    Nawa, K.; Nakano, E.; Yabu, H.

    2006-08-01

    Bose-Einstein condensation of composite diquarks in quark matter (the color superconductor phase) is discussed using the quasichemical equilibrium theory at a relatively low-density region near the deconfinement phase transition, where dynamical quark-pair fluctuations are assumed to be described as bosonic degrees of freedom (diquarks). A general formulation is given for the diquark formation and particle-antiparticle pair-creation processes in the relativistic framework, and some interesting properties are shown, which are characteristic for the relativistic many-body system. Behaviors of transition temperature and phase diagram of the quark-diquark matter are generally presented in model parameter space, and their asymptotic behaviors are also discussed. As an application to the color superconductivity, the transition temperatures and the quark and diquark density profiles are calculated in case with constituent/current quarks, where the diquark is in the bound/resonant state. We obtained T{sub C}{approx}60-80 MeV for constituent quarks and T{sub C}{approx}130 MeV for current quarks at a moderate density ({rho}{sub b}{approx}3{rho}{sub 0}). The method is also developed to include interdiquark interactions into the quasichemical equilibrium theory within a mean-field approximation, and it is found that a possible repulsive diquark-diquark interaction lowers the transition temperature by {approx}50%.

  16. Condensation Processes in Astrophysical Environments

    NASA Technical Reports Server (NTRS)

    Nuth, Joseph A., III; Rietmeijer, Frans J. M.; Hill, Hugh G. M.

    2002-01-01

    Astrophysical systems present an intriguing set of challenges for laboratory chemists. Chemistry occurs in regions considered an excellent vacuum by laboratory standards and at temperatures that would vaporize laboratory equipment. Outflows around Asymptotic Giant Branch (AGB) stars have timescales ranging from seconds to weeks depending on the distance of the region of interest from the star and, on the way significant changes in the state variables are defined. The atmospheres in normal stars may only change significantly on several billion-year timescales. Most laboratory experiments carried out to understand astrophysical processes are not done at conditions that perfectly match the natural suite of state variables or timescales appropriate for natural conditions. Experimenters must make use of simple analog experiments that place limits on the behavior of natural systems, often extrapolating to lower-pressure and/or higher-temperature environments. Nevertheless, we argue that well-conceived experiments will often provide insights into astrophysical processes that are impossible to obtain through models or observations. This is especially true for complex chemical phenomena such as the formation and metamorphism of refractory grains under a range of astrophysical conditions. Data obtained in our laboratory has been surprising in numerous ways, ranging from the composition of the condensates to the thermal evolution of their spectral properties. None of this information could have been predicted from first principals and would not have been credible even if it had.

  17. Stellar matter with pseudoscalar condensates

    NASA Astrophysics Data System (ADS)

    Andrianov, A. A.; Andrianov, V. A.; Espriu, D.; Kolevatov, S. S.

    2016-03-01

    In this work we consider how the appearance of gradients of pseudoscalar condensates in dense systems may possibly influence the transport properties of photons in such a medium as well as other thermodynamic characteristics. We adopt the hypothesis that in regions where the pseudoscalar density gradient is large the properties of photons and fermions are governed by the usual lagrangian extended with a Chern-Simons interaction for photons and a constant axial field for fermions. We find that these new pieces in the lagrangian produce non-trivial reflection coefficients both for photons and fermions when entering or leaving a region where the pseudoscalar has a non-zero gradient. A varying pseudoscalar density may also lead to instability of some fermion and boson modes and modify some properties of the Fermi sea. We speculate that some of these modifications could influence the cooling rate of stellar matter (for instance in compact stars) and have other observable consequences. While quantitative results may depend on the precise astrophysical details most of the consequences are quite universal and consideration should be given to this possibility.

  18. Ice-condenser aerosol tests

    SciTech Connect

    Ligotke, M.W.; Eschbach, E.J.; Winegardner, W.K. )

    1991-09-01

    This report presents the results of an experimental investigation of aerosol particle transport and capture using a full-scale height and reduced-scale cross section test facility based on the design of the ice compartment of a pressurized water reactor (PWR) ice-condenser containment system. Results of 38 tests included thermal-hydraulic as well as aerosol particle data. Particle retention in the test section was greatly influenced by thermal-hydraulic and aerosol test parameters. Test-average decontamination factor (DF) ranged between 1.0 and 36 (retentions between {approximately}0 and 97.2%). The measured test-average particle retentions for tests without and with ice and steam ranged between DF = 1.0 and 2.2 and DF = 2.4 and 36, respectively. In order to apparent importance, parameters that caused particle retention in the test section in the presence of ice were steam mole fraction (SMF), noncondensible gas flow rate (residence time), particle solubility, and inlet particle size. Ice-basket section noncondensible flows greater than 0.1 m{sup 3}/s resulted in stable thermal stratification whereas flows less than 0.1 m{sup 3}/s resulted in thermal behavior termed meandering with frequent temperature crossovers between flow channels. 10 refs., 66 figs., 16 tabs.

  19. Orbital diamagnetic susceptibility in excitonic condensation phase

    NASA Astrophysics Data System (ADS)

    Sugimoto, Koudai; Ohta, Yukinori

    2016-08-01

    We study the orbital diamagnetic susceptibility in excitonic condensation phase using the mean-field approximation for a two-band model defined on a square lattice. We find that, in semiconductors, the excitonic condensation acquires a finite diamagnetic susceptibility due to spontaneous hybridization between the valence and the conduction bands, whereas in semimetals, the diamagnetic susceptibility in the normal phase is suppressed by the excitonic condensation. We also study the orbital diamagnetic and Pauli paramagnetic susceptibilities of Ta2NiSe5 using a two-dimensional three-band model and find that the calculated temperature dependence of the magnetic susceptibility is in qualitative agreement with experiment.

  20. Vortices and turbulence in trapped atomic condensates

    PubMed Central

    White, Angela C.; Anderson, Brian P.; Bagnato, Vanderlei S.

    2014-01-01

    After more than a decade of experiments generating and studying the physics of quantized vortices in atomic gas Bose–Einstein condensates, research is beginning to focus on the roles of vortices in quantum turbulence, as well as other measures of quantum turbulence in atomic condensates. Such research directions have the potential to uncover new insights into quantum turbulence, vortices, and superfluidity and also explore the similarities and differences between quantum and classical turbulence in entirely new settings. Here we present a critical assessment of theoretical and experimental studies in this emerging field of quantum turbulence in atomic condensates. PMID:24704880

  1. Bose-Einstein Condensation of Yb atoms

    SciTech Connect

    Takasu, Y.; Maki, K.; Komori, K.; Takano, T.; Honda, K.; Kumakura, M.; Yabuzaki, T.; Takahashi, Y.

    2005-05-05

    We could recently achieve the Bose Einstein condensation (BEC) of Yb atoms. Yb differs from most of the elements that have previously been condensed, because it is a two-electron atom with the singlet S ground state. Furthermore the Bosonic isotopes of Yb, like 174Yb which we succeeded to condensate, has no nuclear spin, so that the ground state is completely spin-less state and hence insensitive to magnetic fields. Thus a new type of atom could join the group of atoms for BEC studies. We would like to report how we could achieve the BEC of Yb atoms.

  2. Quasihole condensates in quantum Hall liquids

    SciTech Connect

    Suorsa, J.; Viefers, S.; Hansson, T. H.

    2011-06-15

    We develop a formalism to describe quasihole condensates in quantum Hall liquids and thereby extend the conformal field theory approach to the full hierarchy of spin-polarized Abelian states and to several classes of non-Abelian hierarchical states. Most previously proposed spin-polarized quantum Hall wave functions appear as special cases. In this paper we explain the physical motivations for the approach, and exemplify it by explicitly constructing the level-two quasihole condensate state at filling fraction 2/3, and the two level-three states at 5/13 and 5/7 which are built from combinations of quasielectron and quasihole condensates.

  3. Nanoparticle shape, thermodynamics and kinetics

    NASA Astrophysics Data System (ADS)

    Marks, L. D.; Peng, L.

    2016-02-01

    Nanoparticles can be beautiful, as in stained glass windows, or they can be ugly as in wear and corrosion debris from implants. We estimate that there will be about 70 000 papers in 2015 with nanoparticles as a keyword, but only one in thirteen uses the nanoparticle shape as an additional keyword and research focus, and only one in two hundred has thermodynamics. Methods for synthesizing nanoparticles have exploded over the last decade, but our understanding of how and why they take their forms has not progressed as fast. This topical review attempts to take a critical snapshot of the current understanding, focusing more on methods to predict than a purely synthetic or descriptive approach. We look at models and themes which are largely independent of the exact synthetic method whether it is deposition, gas-phase condensation, solution based or hydrothermal synthesis. Elements are old dating back to the beginning of the 20th century—some of the pioneering models developed then are still relevant today. Others are newer, a merging of older concepts such as kinetic-Wulff constructions with methods to understand minimum energy shapes for particles with twins. Overall we find that while there are still many unknowns, the broad framework of understanding and predicting the structure of nanoparticles via diverse Wulff constructions, either thermodynamic, local minima or kinetic has been exceedingly successful. However, the field is still developing and there remain many unknowns and new avenues for research, a few of these being suggested towards the end of the review.

  4. Condensation heat transfer in rotating heat pipes in the presence of a non-condensable gas

    NASA Technical Reports Server (NTRS)

    Daniels, T. C.; Medwell, J. O.; Williams, R. J.

    1977-01-01

    An analysis of condensation problems in rotating heat pipes containing vapors with different concentrations of non-condensable gases is given. In situations such as this, temperature and concentration gradients are set up in the vapor-gas mixture. There is a transport of mass due to temperature gradients accompanied by an energy transport phenomena due to a concentration gradient. A Nusselt type analysis is not suited to this type of problem; however, a boundary layer type approach has successfully been used to analyze stationary condensation systems with non-condensable gases present. The present boundary layer analysis is presented for condensation processes on the inside of a rotating heat pipe in the presence of non-condensable gases.

  5. Simulation of Homogeneous Condensation of Ethanol in High Pressure Supersonic Nozzle Flows using BGK Condensation Model

    NASA Astrophysics Data System (ADS)

    Kumar, Rakesh; Levin, D. A.

    2011-05-01

    In the present work, we have simulated the homogeneous condensation flow of ethanol using the Bhatnagar-Gross-Krook (BGK) based condensation model for the experimental conditions of Wegener et al. [1]. In an earlier work carried out by Gallagher-Rogers et al. [2], it was found not possible to simulate the experimental conditions using the direct simulation Monte-Carlo (DSMC) based condensation model. In this work we use a statistical-BGK approach to model condensation and compare our simulated predictions of the point of condensation onset and the distribution of mass fraction along the nozzle centerline with experiments. The experiments provide data for different cases corresponding to varying amounts of ethanol concentration, compared to air, for total mixture pressures which remains mostly constant for all cases. Our numerical results show good agreement with the experiments, thus validating our BGK based condensation model for high pressure flow applications.

  6. HIGH TEMPERATURE CONDENSED PHASE MASS SPECTROMETRIC ANALYSIS

    EPA Science Inventory

    Our current studies with high temperature ion emitting materials have demonstrated a significant lack of methods for determining chemical species in condensed phase materials in general, and at elevated temperatures in particular. We have developed several new research techniques...

  7. Condensation Front Migration in a Protoplanetary Nebula

    NASA Technical Reports Server (NTRS)

    Davis, Sanford S.

    2004-01-01

    Condensation front dynamics are investigated in the mid-solar nebula region. A quasi-steady model of the evolving nebula is combined with equilibrium vapor pressure curves to determine evolutionary condensation fronts for selected species. These fronts are found to migrate inwards from the far-nebula to final positions during a period of 10(exp 7) years. The physical process governing this movement is a combination of local viscous heating and luminescent heating from the central star. Two luminescent heating models are used and their effects on the ultimate radial position of the condensation front are discussed. At first the fronts move much faster than the nebular accretion velocity, but after a time the accreting gas and dust overtakes the slowing condensation front.

  8. Quantum theory of multimode polariton condensation

    NASA Astrophysics Data System (ADS)

    Racine, David; Eastham, P. R.

    2014-08-01

    We develop a theory for the dynamics of the density matrix describing a multimode polariton condensate. In such a condensate several single-particle orbitals become highly occupied, due to stimulated scattering from reservoirs of high-energy excitons. A generic few-parameter model for the system leads to a Lindblad equation which includes saturable pumping, decay, and condensate interactions. We show how this theory can be used to obtain the population distributions, and the time-dependent first- and second-order coherence functions, in such a multimode condensate. As a specific application, we consider a polaritonic Josephson junction, formed from a double-well potential. We obtain the population distributions, emission line shapes, and widths (first-order coherence functions), and predict the dephasing time of the Josephson oscillations.

  9. Accretion of Ghost Condensate by Black Holes

    SciTech Connect

    Frolov, A

    2004-06-02

    The intent of this letter is to point out that the accretion of a ghost condensate by black holes could be extremely efficient. We analyze steady-state spherically symmetric flows of the ghost fluid in the gravitational field of a Schwarzschild black hole and calculate the accretion rate. Unlike minimally coupled scalar field or quintessence, the accretion rate is set not by the cosmological energy density of the field, but by the energy scale of the ghost condensate theory. If hydrodynamical flow is established, it could be as high as tenth of a solar mass per second for 10MeV-scale ghost condensate accreting onto a stellar-sized black hole, which puts serious constraints on the parameters of the ghost condensate model.

  10. Condensation and Hydrolysis - An Optical Problem?

    ERIC Educational Resources Information Center

    Kellett, N. C.; Johnstone, A. H.

    1974-01-01

    Recent surveys have shown that pupils find the topics of esterification and condensation difficult. Reasons for the difficulty are not clear. Described is research designed to determine where the difficulties were visual or conceptual in origin. (RH)

  11. POLLUTION PREVENTION IN INDUSTRIAL CONDENSATION REACTIONS

    EPA Science Inventory

    The objective of this project is to develop heterogeneous acid-base catalysts to increase the economic and environmental performance of the current homogeneous catalysts used to make industrially important condensation products. Such products include methyl isobutyl ketone ...

  12. Potential Condensed Fuel for the Milky Way

    NASA Astrophysics Data System (ADS)

    Putman, M. E.

    2006-07-01

    Potential condensed clouds of gas in the Galactic halo are examined in the context of the recent models of cooling, fragmenting clouds building up the baryonic mass of the Galaxy. Five hundred and eighty-two high-velocity clouds are defined as the potential condensed clouds, and the sample's spatial and velocity distributions are presented. With the majority of the hydrogen in the clouds ionized (~85%), the clouds at a distribution of distances within 150 kpc, and their individual total masses below 107 Msolar, the total mass in potentially condensed clouds is (1.1-1.4)×109 Msolar. If the tighter distance constraint of <60 kpc is adopted, this mass range drops to (4.5-6.1)×108 Msolar. The implications for the condensing cloud models, as well as feedback and additional accretion methods, are discussed.

  13. Condensation of Chondrules: Conditions for "Fiery Rain"

    NASA Astrophysics Data System (ADS)

    Grossman, L.; Fedkin, A. V.

    2012-09-01

    Equilibrium calculations at total pressures ≥1 bar in systems with CI dust enrichments of 1000 relative to solar composition, yield condensate assemblages whose olivine and coexisting silicate liquid have compositions found in primitive chondrules.

  14. Recent developments in Bose-Einstein condensation

    SciTech Connect

    Kalman, G.

    1997-09-22

    This paper contains viewgraphs on developments on Bose-Einstein condensation. Some topics covered are: strongly coupled coulomb systems; standard response functions of the first and second kind; dynamical mean field theory; quasi localized charge approximation; and the main equations.

  15. Cold condensation of dust in the ISM.

    PubMed

    Rouillé, Gaël; Jäger, Cornelia; Krasnokutski, Serge A; Krebsz, Melinda; Henning, Thomas

    2014-01-01

    The condensation of complex silicates with pyroxene and olivine composition under conditions prevailing in molecular clouds has been experimentally studied. For this purpose, molecular species comprising refractory elements were forced to accrete on cold substrates representing the cold surfaces of surviving dust grains in the interstellar medium. The efficient formation of amorphous and homogeneous magnesium iron silicates at temperatures of about 12 K has been monitored by IR spectroscopy. The gaseous precursors of such condensation processes in the interstellar medium are formed by erosion of dust grains in supernova shock waves. In the laboratory, we have evaporated glassy silicate dust analogs and embedded the released species in neon ice matrices that have been studied spectroscopically to identify the molecular precursors of the condensing solid silicates. A sound coincidence between the 10 microm band of the interstellar silicates and the 10 microm band of the low-temperature siliceous condensates can be noted. PMID:25302393

  16. Performance investigation of finned tube condensers

    SciTech Connect

    Mathur, G.D.

    1996-12-31

    A computer program has been developed to optimize the performance of finned tube condensers. The developed program is used to predict the thermal and hydrodynamic performance of finned tube condensers. The model is based on a steady-state finite difference model. The correlations for predicting the heat transfer and pressure drop are used from the literature. In this paper, the performance of a condenser of a 2-1/2 ton residential air conditioning system (split type) is optimized. The working fluid used in this investigation is R-22. ASHRAE`s condition A [Outside 95 F DBT/75 F WBT; Inside 80 F/67 F WBT] is used in this investigation. The predicted performance of the condenser is within {+-}5% of the experimental data.

  17. Kaon condensation in dense stellar matter

    SciTech Connect

    Lee, Chang-Hwan; Rho, M. |

    1995-03-01

    This article combines two talks given by the authors and is based on Works done in collaboration with G.E. Brown and D.P. Min on kaon condensation in dense baryonic medium treated in chiral perturbation theory using heavy-baryon formalism. It contains, in addition to what was recently published, astrophysical backgrounds for kaon condensation discussed by Brown and Bethe, a discussion on a renormalization-group analysis to meson condensation worked out together with H.K. Lee and S.J. Sin, and the recent results of K.M. Westerberg in the bound-state approach to the Skyrme model. Negatively charged kaons are predicted to condense at a critical density 2 {approx_lt} {rho}/{rho}o {approx_lt} 4, in the range to allow the intriguing new phenomena predicted by Brown and Bethe to take place in compact star matter.

  18. Magnons in a box: Condensation and Application

    NASA Astrophysics Data System (ADS)

    Fang, Fang; Olf, Ryan; Wu, Shun; Kadau, Holger; Marti, G. Edward; Stamper-Kurn, Dan

    2016-05-01

    Ultracold gases offer us a remarkable window into the quantum world, allowing direct access to a wide range of manybody and condensed matter phenomena at convenient macroscopic length and time scales. However, producing ultracold gases at ever lower entropy, and measuring statistical properties such as temperature in these low entropy regimes, is a persistent challenge. Magnons, gapless spin excitations of spinor Bose Einstein Condensate (BEC), are expected to behave like free particles. We show that magnons can be used to cool BEC in a deep trap and serve as a thermometer to measure temperatures at extremely low entropy-per-particle. Unlike atoms trapped in a harmonic trap, trapped magnons experience a box potential due to near exact cancellation of the trapping potential by the mean-field interaction within the condensate. We observe the quasi-condensation of magnon excitations within this nature-made box.

  19. Insulate Steam Distribution and Condensate Return Lines

    SciTech Connect

    Not Available

    2006-01-01

    This revised ITP tip sheet on insulating steam distribution and condensate return lines provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  20. Atomic phase conjugation from a Bose condensate

    SciTech Connect

    Goldstein, E.V.; Plaettner, K.; Meystre, P.

    1996-08-01

    The authors discuss the possibility of observing atomic phase conjugation from Bose condensates, and using it as a diagnostic tool to access the spatial coherence properties and to measure the lifetime of the condensate. They argue that since phase conjugation results from the scattering of a partial matter wave off the spatial grating produced by two other waves, it offers a natural way to directly measure such properties, and as such provides an attractive alternative to the optical methods proposed in the past.

  1. Condensate polishers add operating reliability and flexibility

    SciTech Connect

    Layman, C.M.; Bennett, L.L.

    2008-08-15

    Many of today's advanced steam generators favour either an all-volatile treatment or oxygenated treatment chemistry programme, both of which require strict maintenance of an ultra-pure boiler fedwater ro condensate system. Those requirements are many times at odds with the lower-quality water sources, such as greywater, available for plant makeup and cooling water. Adding a condensate polisher can be a simple, cost-effective solution. 4 figs.

  2. Dynamic simulation recalls condensate piping event

    SciTech Connect

    Farrell, R.J.; Reneberg, K.O. ); Moy, H.C. )

    1994-05-01

    This article describes how experience gained from simulating and reconstructing a condensate piping event will be used by Consolidated Edison to analyze control system problems. A cooperative effort by Con Edison and the Chemical Engineering Department at Polytechnic University used modular modeling system to investigate the probable cause of a Con Edison condensate piping event. Con Edison commissioned the work to serve as a case study for the more general problem of control systems analysis using dynamic simulation and MMS.

  3. Spatial Control of Condensation using Chemical Micropatterns

    NASA Astrophysics Data System (ADS)

    Murphy, Kevin; Hansen, Ryan; Nath, Saurabh; Retterer, Scott; Collier, Patrick; Boreyko, Jonathan; Nature-Inspired Fluids; Interfaces Team; CenterNanophase Materials Sciences Team

    2015-11-01

    Surfaces exhibiting wettability patterns can spatially control the nucleation of condensation to enable enhanced fog harvesting and phase-change heat transfer. To date, studies of patterned condensation have utilized a combination of chemical and topographical features, making it difficult to isolate the effects of intrinsic wettability versus surface roughness on spatially controlling the condensate. Here, we fabricate chemical micropatterns consisting of hydrophilic silicon oxide and a smooth hydrophobic silane monolayer to isolate the effects of changes in intrinsic wettability on the spatial control of condensation. Complete spatial control, defined as every nucleation and growth event occurring exclusively on the hydrophilic features, was observed even for supercooled droplets at high water vapor supersaturation. However, this complete spatial control was found to break down beyond a critical spacing that depended upon the extent of supersaturation. The average diameter of condensate was found to be smaller for the chemically micropatterned surfaces compared to a uniformly hydrophobic surface. Control of inter-droplet spacing between supercooled condensate through chemical patterning can be employed to minimize the growth of inter-droplet frost on cold surfaces.

  4. Dual condensates at finite isospin chemical potential

    NASA Astrophysics Data System (ADS)

    Zhang, Zhao; Miao, Qing

    2016-02-01

    The dual observables as order parameters for center symmetry are tested at finite isospin chemical potential μI in a Polyakov-loop enhanced chiral model of QCD with physical quark masses. As a counterpart of the dressed Polyakov-loop, the first Fourier moment of pion condensate is introduced for μI >mπ / 2 under the temporal twisted boundary conditions for quarks. We demonstrate that this dual condensate exhibits the similar temperature dependence as the conventional Polyakov-loop. We confirm that its rapid increase with T is driven by the evaporating of pion condensation. On the other hand, the dressed Polyakov-loop shows abnormal thermal behavior, which even decreases with T at low temperatures due to the influence of pion condensate. We also find that the dressed Polyakov-loop always rises most steeply at the chiral transition temperature, which is consistent with the previous results in Nambu-Jona-Lasinio (NJL) model and its variants without considering the center symmetry. Since both quantities are strongly affected by the chiral symmetry and pion condensation, we conclude that it is difficult to clarify the deconfinement transition from the dual condensates in this situation within this model.

  5. Condensation of the air-steam mixture in a vertical tube condenser

    NASA Astrophysics Data System (ADS)

    Havlík, Jan; Dlouhý, Tomáš

    2016-03-01

    This paper deals with the condensation of water vapour in the presence of non-condensable air. Experimental and theoretical solutions of this problem are presented here. A heat exchanger for the condensation of industrial waste steam containing infiltrated air was designed. The condenser consists of a bundle of vertical tubes in which the steam condenses as it flows downwards with cooling water flowing outside the tubes in the opposite direction. Experiments with pure steam and with mixtures of steam with added air were carried out to find the dependence of the condensation heat transfer coefficient (HTC) on the air concentration in the steam mixture. The experimental results were compared with the theoretical formulas describing the cases. The theoretical determination of the HTC is based on the Nusselt model of steam condensation on a vertical wall, where the analogy of heat and mass transfer is used to take into account the behaviour of air in a steam mixture during the condensation process. The resulting dependencies obtained from the experiments and obtained from the theoretical model have similar results. The significant decrease in the condensation HTC, which begins at very low air concentrations in a steam mixture, was confirmed.

  6. Implementation of non-condensable gases condensation suppression model into the WCOBRA/TRAC-TF2 LOCA safety evaluation code

    SciTech Connect

    Liao, J.; Cao, L.; Ohkawa, K.; Frepoli, C.

    2012-07-01

    The non-condensable gases condensation suppression model is important for a realistic LOCA safety analysis code. A condensation suppression model for direct contact condensation was previously developed by Westinghouse using first principles. The model is believed to be an accurate description of the direct contact condensation process in the presence of non-condensable gases. The Westinghouse condensation suppression model is further revised by applying a more physical model. The revised condensation suppression model is thus implemented into the WCOBRA/TRAC-TF2 LOCA safety evaluation code for both 3-D module (COBRA-TF) and 1-D module (TRAC-PF1). Parametric study using the revised Westinghouse condensation suppression model is conducted. Additionally, the performance of non-condensable gases condensation suppression model is examined in the ACHILLES (ISP-25) separate effects test and LOFT L2-5 (ISP-13) integral effects test. (authors)

  7. Condensation and Evaporation of Solar System Materials

    NASA Astrophysics Data System (ADS)

    Davis, A. M.; Richter, F. M.

    2003-12-01

    It is widely believed that the materials making up the solar system were derived from a nebular gas and dust cloud that went through an early high-temperature stage during which virtually all of the material was in the gas phase. At one time, it was thought that the entire inner solar nebula was hot, but it is now believed that most material was processed through regions where high temperatures were achieved. Certainly some material, such as presolar grains (cf., Mendybaev et al., 2002a), has never been exposed to high temperatures. As the system cooled, solids and perhaps liquids began to condense, but at some point the partially condensed materials became isolated from the remaining gas. Various lines of evidence support this view. At the largest scale, there is the observation that the Earth, Moon, Mars, and all chondritic meteorites except for the CI chondrites are depleted to varying degrees in the abundances of moderately volatile elements relative to bulk solar system composition. The CI chondrites reflect the bulk composition of the solar system for all but hydrogen, carbon, nitrogen, oxygen, and the rare gases, the most volatile elements (see Chapter 1.03; Palme et al., 1988; McDonough and Sun, 1995; Humayun and Cassen, 2000). The depletions in moderately volatile elements are, to a significant degree, correlated with condensation temperature, suggesting progressive removal of gas as condensation proceeded ( Cassen, 1996). Additional observations that can be explained by partial condensation are that various particularly primitive components of meteorites (e.g., calcium-, aluminum-rich refractory inclusions, and certain metal grains) have mineralogy and/or details of their chemical composition that are remarkably similar to what is calculated for equilibrium condensates from a solar composition gas. For example, the calcium-, aluminum-rich inclusions (CAIs) in chondritic meteorites have compositions very similar to that calculated for the first 5% of total

  8. Mitotic chromosome condensation in vertebrates

    SciTech Connect

    Vagnarelli, Paola

    2012-07-15

    Work from several laboratories over the past 10-15 years has revealed that, within the interphase nucleus, chromosomes are organized into spatially distinct territories [T. Cremer, C. Cremer, Chromosome territories, nuclear architecture and gene regulation in mammalian cells, Nat. Rev. Genet. 2 (2001) 292-301 and T. Cremer, M. Cremer, S. Dietzel, S. Muller, I. Solovei, S. Fakan, Chromosome territories-a functional nuclear landscape, Curr. Opin. Cell Biol. 18 (2006) 307-316]. The overall compaction level and intranuclear location varies as a function of gene density for both entire chromosomes [J.A. Croft, J.M. Bridger, S. Boyle, P. Perry, P. Teague,W.A. Bickmore, Differences in the localization and morphology of chromosomes in the human nucleus, J. Cell Biol. 145 (1999) 1119-1131] and specific chromosomal regions [N.L. Mahy, P.E. Perry, S. Gilchrist, R.A. Baldock, W.A. Bickmore, Spatial organization of active and inactive genes and noncoding DNA within chromosome territories, J. Cell Biol. 157 (2002) 579-589] (Fig. 1A, A'). In prophase, when cyclin B activity reaches a high threshold, chromosome condensation occurs followed by Nuclear Envelope Breakdown (NEB) [1]. At this point vertebrate chromosomes appear as compact structures harboring an attachment point for the spindle microtubules physically recognizable as a primary constriction where the two sister chromatids are held together. The transition from an unshaped interphase chromosome to the highly structured mitotic chromosome (compare Figs. 1A and B) has fascinated researchers for several decades now; however a definite picture of how this process is achieved and regulated is not yet in our hands and it will require more investigation to comprehend the complete process. From a biochemical point of view a vertebrate mitotic chromosomes is composed of DNA, histone proteins (60%) and non-histone proteins (40%) [6]. I will discuss below what is known to date on the contribution of these two different classes of

  9. Improved Cloud Condensation Nucleus Spectrometer

    NASA Technical Reports Server (NTRS)

    Leu, Ming-Taun

    2010-01-01

    An improved thermal-gradient cloud condensation nucleus spectrometer (CCNS) has been designed to provide several enhancements over prior thermal- gradient counters, including fast response and high-sensitivity detection covering a wide range of supersaturations. CCNSs are used in laboratory research on the relationships among aerosols, supersaturation of air, and the formation of clouds. The operational characteristics of prior counters are such that it takes long times to determine aerosol critical supersaturations. Hence, there is a need for a CCNS capable of rapid scanning through a wide range of supersaturations. The present improved CCNS satisfies this need. The improved thermal-gradient CCNS (see Figure 1) incorporates the following notable features: a) The main chamber is bounded on the top and bottom by parallel thick copper plates, which are joined by a thermally conductive vertical wall on one side and a thermally nonconductive wall on the opposite side. b) To establish a temperature gradient needed to establish a supersaturation gradient, water at two different regulated temperatures is pumped through tubes along the edges of the copper plates at the thermally-nonconductive-wall side. Figure 2 presents an example of temperature and supersaturation gradients for one combination of regulated temperatures at the thermally-nonconductive-wall edges of the copper plates. c) To enable measurement of the temperature gradient, ten thermocouples are cemented to the external surfaces of the copper plates (five on the top plate and five on the bottom plate), spaced at equal intervals along the width axis of the main chamber near the outlet end. d) Pieces of filter paper or cotton felt are cemented onto the interior surfaces of the copper plates and, prior to each experimental run, are saturated with water to establish a supersaturation field inside the main chamber. e) A flow of monodisperse aerosol and a dilution flow of humid air are introduced into the main

  10. Buckling condensation in constrained growth

    NASA Astrophysics Data System (ADS)

    Dervaux, Julien; Ben Amar, Martine

    2011-03-01

    The multiple complexities inherent to living objects have motivated the search for abiotic substitutes, able to mimic some of their relevant physical properties. Hydrogels provide a highly monitorable counterpart and have thus found many applications in medicine and bioengineering. Recently, it has been recognized that their ability to swell could be used to unravel some of the universal physical processes at work during biological growth. However, it is yet unknown how the microscopic distinctions between swelling and biological growth affect macroscopic changes (shape, stresses) induced by volume variations. To answer this question, we focus on a clinically motivated example of growth. Some solid tumors such as melanoma or glioblastoma undergo a shape transition during their evolution. This bifurcation appears when growth is confined at the periphery of the tumor and is concomitant with the transition from the avascular to the vascular stage of the tumor evolution. To model this phenomenon, we consider in this paper the deformation of an elastic ring enclosing a core of different stiffness. When the volume of the outer ring increases, the system develops a periodic instability. We consider two possible descriptions of the volume variation process: either by imposing a homogeneous volumetric strain (biological growth) or through migration of solvent molecules inside a solid network (swelling). For thin rings, both theories are in qualitative agreement. When the interior is soft, we predict the emergence of a large wavelength buckling. Upon increasing the stiffness of the inner disc, the wavelength of the instability decreases until a condensation of the buckles occurs at the free boundary. This short wavelength pattern is independent of the stiffness of the disc and is only limited by the presence of surface tension. For thicker rings, two scenarios emerge. When a volumetric strain is prescribed, compressive stresses accumulate in the vicinity of the core and the

  11. Infinite statistics condensate as a model of dark matter

    SciTech Connect

    Ebadi, Zahra; Mirza, Behrouz; Mohammadzadeh, Hosein E-mail: b.mirza@cc.iut.ac.ir

    2013-11-01

    In some models, dark matter is considered as a condensate bosonic system. In this paper, we prove that condensation is also possible for particles that obey infinite statistics and derive the critical condensation temperature. We argue that a condensed state of a gas of very weakly interacting particles obeying infinite statistics could be considered as a consistent model of dark matter.

  12. 46 CFR 56.50-35 - Condensate pumps.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Condensate pumps. 56.50-35 Section 56.50-35 Shipping... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-35 Condensate pumps. Two means shall be provided for discharging the condensate from the main condenser, one of which shall be...

  13. 46 CFR 56.50-35 - Condensate pumps.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Condensate pumps. 56.50-35 Section 56.50-35 Shipping... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-35 Condensate pumps. Two means shall be provided for discharging the condensate from the main condenser, one of which shall be...

  14. 46 CFR 56.50-35 - Condensate pumps.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Condensate pumps. 56.50-35 Section 56.50-35 Shipping... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-35 Condensate pumps. Two means shall be provided for discharging the condensate from the main condenser, one of which shall be...

  15. 46 CFR 56.50-35 - Condensate pumps.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Condensate pumps. 56.50-35 Section 56.50-35 Shipping... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-35 Condensate pumps. Two means shall be provided for discharging the condensate from the main condenser, one of which shall be...

  16. 46 CFR 56.50-35 - Condensate pumps.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Condensate pumps. 56.50-35 Section 56.50-35 Shipping... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-35 Condensate pumps. Two means shall be provided for discharging the condensate from the main condenser, one of which shall be...

  17. Enhanced tubes for steam condensers. Volume 1, Summary of condensation and fouling; Volume 2, Detailed study of steam condensation

    SciTech Connect

    Webb, R.L.; Chamra, L.; Jaber, H.

    1992-02-01

    Electric utility steam condensers typically use plain tubes made of titanium, stainless steel, or copper alloys. Approximately two-thirds of the total thermal resistance is on the water side of the plain tube. This program seeks to conceive and develop a tube geometry that has special enhancement geometries on the tube (water) side and the steam (shell) side. This ``enhanced`` tube geometry, will provide increased heat transfer coefficients. The enhanced tubes will allow the steam to condense at a lower temperature. The reduced condensing temperature will reduce the turbine heat rate, and increase the plant peak load capability. Water side fouling and fouling control is a very important consideration affecting the choice of the tube side enhancement. Hence, we have consciously considered fouling potential in our selection of the tube side surface geometry. Using appropriate correlations and theoretical models, we have designed condensation and water side surface geometries that will provide high performance and be cleanable using sponge ball cleaning. Commercial tube manufacturers have made the required tube geometries for test purposes. The heat transfer test program includes measurement of the condensation and water side heat transfer coefficients. Fouling tests are being run to measure the waterside fouling resistance, and to the test the ability of the sponge ball cleaning system to clean the tubes.

  18. Microbial reduction of sulfate injected to gas condensate plumes in cold groundwater

    NASA Astrophysics Data System (ADS)

    Van Stempvoort, Dale R.; Armstrong, James; Mayer, Bernhard

    2007-07-01

    Despite a rapid expansion over the past decade in the reliance on intrinsic bioremediation to remediate petroleum hydrocarbon plumes in groundwater, significant research gaps remain. Although it has been demonstrated that bacterial sulfate reduction can be a key electron accepting process in many petroleum plumes, little is known about the rate of this reduction process in plumes derived from crude oil and gas condensates at cold-climate sites (mean temperature < 10 °C), and in complex hydrogeological settings such as silt/clay aquitards. In this field study, sulfate was injected into groundwater contaminated by gas condensate plumes at two petroleum sites in Alberta, Canada to enhance in-situ bioremediation. In both cases the groundwater near the water table had low temperature (6-9 °C). Monitoring data had provided strong evidence that bacterial sulfate reduction was a key terminal electron accepting process (TEAP) in the natural attenuation of dissolved hydrocarbons at these sites. At each site, water with approximately 2000 mg/L sulfate and a bromide tracer was injected into a low-sulfate zone within a condensate-contaminant plume. Monitoring data collected over several months yielded conservative estimates for sulfate reduction rates based on zero-order kinetics (4-6 mg/L per day) or first-order kinetics (0.003 and 0.01 day - 1 ). These results favor the applicability of in-situ bioremediation techniques in this region, under natural conditions or with enhancement via sulfate injection.

  19. Deepak Condenser Model (DeCoM)

    NASA Technical Reports Server (NTRS)

    Patel, Deepak

    2013-01-01

    Development of the DeCoM comes from the requirement of analyzing the performance of a condenser. A component of a loop heat pipe (LHP), the condenser, is interfaced with the radiator in order to reject heat. DeCoM simulates the condenser, with certain input parameters. Systems Improved Numerical Differencing Analyzer (SINDA), a thermal analysis software, calculates the adjoining component temperatures, based on the DeCoM parameters and interface temperatures to the radiator. Application of DeCoM is (at the time of this reporting) restricted to small-scale analysis, without the need for in-depth LHP component integrations. To efficiently develop a model to simulate the LHP condenser, DeCoM was developed to meet this purpose with least complexity. DeCoM is a single-condenser, single-pass simulator for analyzing its behavior. The analysis is done based on the interactions between condenser fluid, the wall, and the interface between the wall and the radiator. DeCoM is based on conservation of energy, two-phase equations, and flow equations. For two-phase, the Lockhart- Martinelli correlation has been used in order to calculate the convection value between fluid and wall. Software such as SINDA (for thermal analysis analysis) and Thermal Desktop (for modeling) are required. DeCoM also includes the ability to implement a condenser into a thermal model with the capability of understanding the code process and being edited to user-specific needs. DeCoM requires no license, and is an open-source code. Advantages to DeCoM include time dependency, reliability, and the ability for the user to view the code process and edit to their needs.

  20. Condensate and feedwater systems, pumps, and water chemistry. Volume seven

    SciTech Connect

    Not Available

    1986-01-01

    Subject matter includes condensate and feedwater systems (general features of condensate and feedwater systems, condenser hotwell level control, condensate flow, feedwater flow), pumps (principles of fluid flow, types of pumps, centrifugal pumps, positive displacement pumps, jet pumps, pump operating characteristics) and water chemistry (water chemistry fundamentals, corrosion, scaling, radiochemistry, water chemistry control processes, water pretreatment, PWR water chemistry, BWR water chemistry, condenser circulating water chemistry.

  1. Observation of Vortex Phase Singularities in Bose-Einstein Condensates

    SciTech Connect

    Inouye, S.; Gupta, S.; Rosenband, T.; Chikkatur, A. P.; Goerlitz, A.; Gustavson, T. L.; Leanhardt, A. E.; Pritchard, D. E.; Ketterle, W.

    2001-08-20

    We have observed phase singularities due to vortex excitation in Bose-Einstein condensates. Vortices were created by moving a laser beam through a condensate. They were observed as dislocations in the interference fringes formed by the stirred condensate and a second unperturbed condensate. The velocity dependence for vortex excitation and the time scale for re-establishing a uniform phase across the condensate were determined.

  2. GENOTOXICITY OF TEN CIGARETTE SMOKE CONDENSATES IN FOUR TEST SYSTEMS: COMPARISONS BETWEEN ASSAYS AND CONDENSATES

    EPA Science Inventory

    What is the study?
    This the first assessment of a set of cigarette smoke condensates from a range of cigarette types in a variety (4) of short-term genotoxicity assays.
    Why was it done?
    No such comparative study of cigarette smoke condensates has been reported. H...

  3. Infrared applications for steam turbine condenser systems

    NASA Astrophysics Data System (ADS)

    Lanius, Mark A.

    2000-03-01

    Infrared inspection of the main steam condensers at the Peach Bottom Atomic Power Station has been utilized successfully in detecting condenser air in-leakage problems. Air in-leakage lowers the condenser's vacuum, thus decreasing the condenser's efficiency. This creates backpressure on the turbine which lowers its efficiency, resulting in fewer megawatts generated. Air in-leakage also creates an increase in off-gas flow which is a radiological concern for both the plant and the public. Inspections are normally performed on the condenser's manway covers and rupture disks prior to an outage during coast down and post outage. The optimum conditions are 100% power and temperature, however, a high radiation field prevents the inspection until reactor power is down to 65% or less. Anomalies are typically indicated by cooling in the effected areas of the air in-leakage. The anomalies are not limited to air in-leakage. Intermittent water out-leakage, due to a heater dump valve cycling, has been detected when visual inspections field nothing.

  4. Laser Isotope Separation Employing Condensation Repression

    SciTech Connect

    Eerkens, Jeff W.; Miller, William H.

    2004-09-15

    Molecular laser isotope separation (MLIS) techniques using condensation repression (CR) harvesting are reviewed and compared with atomic vapor laser isotope separation (AVLIS), gaseous diffusion (DIF), ultracentrifuges (UCF), and electromagnetic separations (EMS). Two different CR-MLIS or CRISLA (Condensation Repression Isotope Separation by Laser Activation) approaches have been under investigation at the University of Missouri (MU), one involving supersonic super-cooled free jets and dimer formation, and the other subsonic cold-wall condensation. Both employ mixtures of an isotopomer (e.g. {sup i}QF{sub 6}) and a carrier gas, operated at low temperatures and pressures. Present theories of VT relaxation, dimerization, and condensation are found to be unsatisfactory to explain/predict experimental CRISLA results. They were replaced by fundamentally new models that allow ab-initio calculation of isotope enrichments and predictions of condensation parameters for laser-excited and non-excited vapors which are in good agreement with experiment. Because of supersonic speeds, throughputs for free-jet CRISLA are a thousand times higher than cold-wall CRISLA schemes, and thus preferred for large-quantity Uranium enrichments. For small-quantity separations of (radioactive) medical isotopes, the simpler coldwall CRISLA method may be adequate.

  5. The NSF Condensed Matter Physics Program

    NASA Astrophysics Data System (ADS)

    Sokol, Paul

    The Condensed Matter Physics (CMP) program in the NSF Division of Materials Research (DMR) supports experimental, as well as combined experiment and theory projects investigating the fundamental physics behind phenomena exhibited by condensed matter systems. CMP is the largest Individual Investigator Award program in DMR and supports a broad portfolio of research spanning both hard and soft condensed matter. Representative research areas include: 1) phenomena at the nano- to macro-scale including: transport, magnetic, and optical phenomena; classical and quantum phase transitions; localization; electronic, magnetic, and lattice structure or excitations; superconductivity; topological insulators; and nonlinear dynamics. 2) low-temperature physics: quantum fluids and solids; 1D & 2D electron systems. 3) soft condensed matter: partially ordered fluids, granular and colloid physics, liquid crystals, and 4) understanding the fundamental physics of new states of matter as well as the physical behavior of condensed matter under extreme conditions e.g., low temperatures, high pressures, and high magnetic fields. In this talk I will review the current CMP portfolio and discuss future funding trends for the program. I will also describe recent activities in the program aimed at addressing the challenges facing current and future principal investigators.

  6. Why double-stranded RNA resists condensation

    PubMed Central

    Tolokh, Igor S.; Pabit, Suzette A.; Katz, Andrea M.; Chen, Yujie; Drozdetski, Aleksander; Baker, Nathan; Pollack, Lois; Onufriev, Alexey V.

    2014-01-01

    The addition of small amounts of multivalent cations to solutions containing double-stranded DNA leads to inter-DNA attraction and eventual condensation. Surprisingly, the condensation is suppressed in double-stranded RNA, which carries the same negative charge as DNA, but assumes a different double helical form. Here, we combine experiment and atomistic simulations to propose a mechanism that explains the variations in condensation of short (25 base-pairs) nucleic acid (NA) duplexes, from B-like form of homopolymeric DNA, to mixed sequence DNA, to DNA:RNA hybrid, to A-like RNA. Circular dichroism measurements suggest that duplex helical geometry is not the fundamental property that ultimately determines the observed differences in condensation. Instead, these differences are governed by the spatial variation of cobalt hexammine (CoHex) binding to NA. There are two major NA-CoHex binding modes—internal and external—distinguished by the proximity of bound CoHex to the helical axis. We find a significant difference, up to 5-fold, in the fraction of ions bound to the external surfaces of the different NA constructs studied. NA condensation propensity is determined by the fraction of CoHex ions in the external binding mode. PMID:25123663

  7. Simulation Prediction of Transient Dropwise Condensation

    NASA Astrophysics Data System (ADS)

    Macner, Ashley; Daniel, Susan; Steen, Paul

    2014-11-01

    In order to design effective surfaces for large-scale dropwise condensation, an understanding of how surface functionalization affects drop growth and coalescence is needed. The long term technological goal is a set of design conditions to help NASA achieve maximum heat transfer rates of waste heat generated from electronics and habitable environments under microgravity conditions. Prediction of condenser surface heat transfer performance requires accurate simulation and modeling of the evolution of populations of drops in time. At shorter times, drops are primarily isolated and grow mainly by condensation onto the liquid-gas interface. At longer times, drops grow mainly by coalescence with neighbors. Simulation of dropwise condensation on a neutrally wetting surface and comparison with our previous experimental results is reported. A steady-state single drop conduction model is empirically fitted to determine a temperature profile that captures the drop size evolution. The simulation accurately predicts the continuous time evolution of number-density of drops, drop-size distributions, total condensate volume, fractional coverage, and median drop-size for both transient and steady states, all with no free parameters. This work was supported by a NASA Office of the Chief Technologist's Space Technology Research Fellowship.

  8. Rotating trapped Bose-Einstein condensates

    NASA Astrophysics Data System (ADS)

    Fetter, A. L.

    2008-01-01

    Trapped Bose-Einstein condensates (BECs) differ considerably from the standard textbook example of a uniform Bose gas. In an isotropic harmonic potential V( r) = ½ Mω2 r 2, the single-particle ground state introduces a new intrinsic scale of length [the ground-state size d = √ ℏ/( Mω)] and energy [the ground-state energy E 0 = frac{3} {2} ℏω]. When the trap rotates at a low angular velocity, the behavior of a single vortex illustrates the crucial role of discrete quantized vorticity. For more rapid rotation, the condensate contains a vortex array. The resulting centrifugal forces expand the condensate radially and shrink it axially; thus, the condensate becomes effectively two dimensional. If the external rotation speed approaches the frequency of the radial harmonic confining potential, the condensate enters the "lowest-Landau-level" regime, and a simple description again becomes possible. Eventually, the system is predicted to make a quantum phase transition to a highly correlated state analogous to the fractional quantum Hall states of electrons in a strong magnetic field.

  9. Employing Magnetic Levitation to Monitor Reaction Kinetics and Measure Activation Energy

    ERIC Educational Resources Information Center

    Benz, Lauren; Cesafsky, Karen E.; Le, Tran; Park, Aileen; Malicky, David

    2012-01-01

    This article describes a simple and inexpensive undergraduate-level kinetics experiment that uses magnetic levitation to monitor the progress and determine the activation energy of a condensation reaction on a polymeric solid support. The method employs a cuvette filled with a paramagnetic solution positioned between two strong magnets. The…

  10. Preoperational test report, recirculation condenser cooling systems

    SciTech Connect

    Clifton, F.T.

    1997-11-04

    This represents a preoperational test report for Recirculation Condenser Systems, Project W-030. Project W-030 provides a ventilation upgrade for the four Aging Waste Facility tanks. The four system provide condenser cooling water for vapor space cooling of tanks AY1O1, AY102, AZ1O1, AZ102. Each system consists of a valved piping loop, a pair of redundant recirculation pumps, a closed-loop evaporative cooling tower, and supporting instrumentation; equipment is located outside the farm on concrete slabs. Piping is routed to the each ventilation condenser inside the farm via below-grade concrete trenches. The tests verify correct system operation and correct indications displayed by the central Monitor and Control System.

  11. Efficient cell migration requires global chromatin condensation

    PubMed Central

    Gerlitz, Gabi; Bustin, Michael

    2010-01-01

    Cell migration is a fundamental process that is necessary for the development and survival of multicellular organisms. Here, we show that cell migration is contingent on global condensation of the chromatin fiber. Induction of directed cell migration by the scratch-wound assay leads to decreased DNaseI sensitivity, alterations in the chromatin binding of architectural proteins and elevated levels of H4K20me1, H3K27me3 and methylated DNA. All these global changes are indicative of increased chromatin condensation in response to induction of directed cell migration. Conversely, chromatin decondensation inhibited the rate of cell migration, in a transcription-independent manner. We suggest that global chromatin condensation facilitates nuclear movement and reshaping, which are important for cell migration. Our results support a role for the chromatin fiber that is distinct from its known functions in genetic processes. PMID:20530575

  12. Condensing heat exchangers for maximum boiler efficiency

    SciTech Connect

    Johnson, D.W.; DiVitto, J.G.; Rakocy, M.E.

    1994-12-31

    Until now, boiler efficiency has been limited due to the minimum temperature allowed at the stack. Heat lost up the stack was in exchange for keeping the flue gas temperature above the water vapor dew point. If water vapor was allowed to condense out, rapid deterioration, due to acid corrosion, of the outlet duct and stack would result. With the development of the condensing heat exchanger, boiler efficiency can now exceed 90%. Approximately 1% gain in boiler efficiency can be expected for every 40 F (4.5 C) reduction in flue gas stack temperature. In the CHX{reg_sign} condensing heat exchanger, all gas wetted surfaces are covered with DuPont Teflon{reg_sign}. The Teflon covered heat exchanger surfaces are impervious to all acids normally resulting from the combustion of fossil fuels. This allows the flue gas to be cooled to below the water vapor dew point with no subsequent corrosion of the heat exchanger surfaces.

  13. DROPWISE CONDENSATION ON MICRO- AND NANOSTRUCTURED SURFACES

    SciTech Connect

    Enright, R; Miljkovic, N; Alvarado, JL; Kim, K; Rose, JW

    2014-07-23

    In this review we cover recent developments in the area of surface-enhanced dropwise condensation against the background of earlier work. The development of fabrication techniques to create surface structures at the micro-and nanoscale using both bottom-up and top-down approaches has led to increased study of complex interfacial phenomena. In the heat transfer community, researchers have been extensively exploring the use of advanced surface structuring techniques to enhance phase-change heat transfer processes. In particular, the field of vapor-to-liquid condensation and especially that of water condensation has experienced a renaissance due to the promise of further optimizing this process at the micro-and nanoscale by exploiting advances in surface engineering developed over the last several decades.

  14. Optimization of evaporative cooling towards a large number of Bose-Einstein-condensed atoms

    SciTech Connect

    Yamashita, Makoto; Mukai, Tetsuya; Mukai, Takaaki; Koashi, Masato; Mitsunaga, Masaharu; Imoto, Nobuyuki

    2003-02-01

    We study the optimization of evaporative cooling in trapped bosonic atoms on the basis of quantum kinetic theory of a Bose gas. The optimized cooling trajectory for {sup 87}Rb atoms indicates that the acceleration of evaporative cooling around the transition point of Bose-Einstein condensation is very effective against loss of trapped atoms caused by three-body recombination. The number of condensed atoms is largely enhanced by the optimization, more than two orders of magnitude in our present calculation using relevant experimental parameters, as compared with the typical value given by the conventional evaporative cooling where the frequency of radio-frequency magnetic field is swept exponentially. In addition to this optimized cooling, it is also shown that highly efficient evaporative cooling can be achieved by an initial exponential and then a rapid linear sweep of frequency.

  15. Why double-stranded RNA resists condensation

    SciTech Connect

    Tolokh, Igor S.; Pabit, Suzette; Katz, Andrea M.; Chen, Yujie; Drozdetski, Aleksander; Baker, Nathan A.; Pollack, Lois; Onufriev, Alexey

    2014-09-15

    The addition of small amounts of multivalent cations to solutions containing double-stranded DNA leads to attraction between the negatively charged helices and eventually to condensation. Surprisingly, this effect is suppressed in double-stranded RNA, which carries the same charge as the DNA, but assumes a different double helical form. However, additional characterization of short (25 base-pairs) nucleic acid (NA) duplex structures by circular dichroism shows that measured differences in condensation are not solely determined by duplex helical geometry. Here we combine experiment, theory, and atomistic simulations to propose a mechanism that connects the observed variations in condensation of short NA duplexes with the spatial variation of cobalt hexammine (CoHex) binding at the NA duplex surface. The atomistic picture that emerged showed that CoHex distributions around the NA reveals two major NA-CoHex binding modes -- internal and external -- distinguished by the proximity of bound CoHex to the helical axis. Decreasing trends in experimentally observed condensation propensity of the four studied NA duplexes (from B-like form of homopolymeric DNA, to mixed sequence DNA, to DNA:RNA hybrid, to A-like RNA) are explained by the progressive decrease of a single quantity: the fraction of CoHex ions in the external binding mode. Thus, while NA condensation depends on a complex interplay between various structural and sequence features, our coupled experimental and theoretical results suggest a new model in which a single parameter connects the NA condensation propensity with geometry and sequence dependence of CoHex binding.

  16. Condensation of gauge interacting massless fermions

    SciTech Connect

    Siringo, Fabio

    2004-09-15

    A single massless fermionic field with an Abelian U(1) gauge interaction (electrodynamics of a massless Dirac fermion) is studied by a variational method. Even without the insertion of any extra interaction the vacuum is shown to be unstable towards a particle-antiparticle condensate. The single particle excitations do acquire a mass and behave as massive Fermi particles. An explicit low-energy gap equation has been derived and numerically solved. Some consequences of condensation and mass generation are discussed in the framework of the standard model.

  17. The antireflective potential of dropwise condensation.

    PubMed

    Tow, Emily W

    2014-03-01

    The transmissivity of fogged glass to visible light incident on the dry side is studied with ray tracing to show that condensation can act as an optically thick antireflective coating. A new simulation method is described that uses symmetry relations and analytical expressions for the intersection of rays and surfaces to include all drop-drop and drop-surface interactions between an infinite number of drops. Angle of incidence, droplet contact angle, and surface coverage are varied. The simulation reveals that in the optimal contact angle range, dropwise condensation can decrease the reflectance of glass to below even that of glass coated with a water film. PMID:24690645

  18. Experimental Investigation of Flow Condensation in Microgravity

    NASA Technical Reports Server (NTRS)

    Lee, Hyoungsoon; Park, Ilchung; Konishi, Christopher; Mudawar, Issam; May, Rochelle I.; Juergens, Jeffery R.; Wagner, James D.; Hall, Nancy R.; Nahra, Henry K.; Hasan, Mohammed M.; Mackey, Jeffery R.

    2013-01-01

    Future manned missions to Mars are expected to greatly increase the space vehicle's size, weight, and heat dissipation requirements. An effective means to reducing both size and weight is to replace single-phase thermal management systems with two-phase counterparts that capitalize upon both latent and sensible heat of the coolant rather than sensible heat alone. This shift is expected to yield orders of magnitude enhancements in flow boiling and condensation heat transfer coefficients. A major challenge to this shift is a lack of reliable tools for accurate prediction of two-phase pressure drop and heat transfer coefficient in reduced gravity. Developing such tools will require a sophisticated experimental facility to enable investigators to perform both flow boiling and condensation experiments in microgravity in pursuit of reliable databases. This study will discuss the development of the Flow Boiling and Condensation Experiment (FBCE) for the International Space Station (ISS), which was initiated in 2012 in collaboration between Purdue University and NASA Glenn Research Center. This facility was recently tested in parabolic flight to acquire condensation data for FC-72 in microgravity, aided by high-speed video analysis of interfacial structure of the condensation film. The condensation is achieved by rejecting heat to a counter flow of water, and experiments were performed at different mass velocities of FC-72 and water and different FC-72 inlet qualities. It is shown that the film flow varies from smooth-laminar to wavy-laminar and ultimately turbulent with increasing FC-72 mass velocity. The heat transfer coefficient is highest near the inlet of the condensation tube, where the film is thinnest, and decreases monotonically along the tube, except for high FC-72 mass velocities, where the heat transfer coefficient is enhanced downstream. This enhancement is attributed to both turbulence and increased interfacial waviness. One-ge correlations are shown to

  19. Neutron star cooling and pion condensation

    NASA Technical Reports Server (NTRS)

    Umeda, Hideyuki; Nomoto, Ken'ichi; Tsuruta, Sachiko; Muto, Takumi; Tatsumi, Toshitaka

    1994-01-01

    The nonstandard cooling of a neutron star with the central pion core is explored. By adopting the latest results from the pion condensation theory, neutrino emissivity is calulated for both pure charged pions and a mixture of charged and neutral pions, and the equations of state are constructed for the pion condensate. The effect of superfluidity on cooling is investigated, adopting methods more realistic than in previous studies. Our theoretical models are compared with the currently updated observational data, and possible implications are explored.

  20. Condensation-induced jumping water drops

    NASA Astrophysics Data System (ADS)

    Narhe, R. D.; Khandkar, M. D.; Shelke, P. B.; Limaye, A. V.; Beysens, D. A.

    2009-09-01

    Water droplets can jump during vapor condensation on solid benzene near its melting point. This phenomenon, which can be viewed as a kind of micro scale steam engine, is studied experimentally and numerically. The latent heat of condensation transferred at the drop three phase contact line melts the substrate during a time proportional to R (the drop radius). The wetting conditions change and a spontaneous jump of the drop results in random direction over length ˜1.5R , a phenomenon that increases the coalescence events and accelerates the growth. Once properly rescaled by the jump length scale, the growth dynamics is, however, similar to that on a solid surface.

  1. Condensation-induced jumping water drops.

    PubMed

    Narhe, R D; Khandkar, M D; Shelke, P B; Limaye, A V; Beysens, D A

    2009-09-01

    Water droplets can jump during vapor condensation on solid benzene near its melting point. This phenomenon, which can be viewed as a kind of micro scale steam engine, is studied experimentally and numerically. The latent heat of condensation transferred at the drop three phase contact line melts the substrate during a time proportional to R (the drop radius). The wetting conditions change and a spontaneous jump of the drop results in random direction over length approximately 1.5R , a phenomenon that increases the coalescence events and accelerates the growth. Once properly rescaled by the jump length scale, the growth dynamics is, however, similar to that on a solid surface. PMID:19905120

  2. An Overview of Tachyon Condensation and SFT

    NASA Astrophysics Data System (ADS)

    Bonora, L.

    2010-07-01

    This is short review of tachyon condensation and open strig field theory. After a brief introduction to open string theory, the SFT action is introduced and illustrated. Next comes tachyon condensation in the level truncation approach, which introduces the main topic: the description of the analytic solution and the proof of the first two conjectures by Sen. The third conjecture is discussed in the framework of vacuum SFT. Finally the subject of open--closed string duality is tackled by commenting about an attempt at showing a more explicit connection between open and closed strings.

  3. Cloud condensation nuclei near marine stratus

    NASA Technical Reports Server (NTRS)

    Hudson, James G.; Frisbie, Paul R.

    1991-01-01

    Extensive airborne measurements of cloud condensation nucleus (CCN) spectra and concentrations of total particles, or condensation nuclei (CN), below, in, and above the stratus cloud decks off the southern California coast point to important aerosol-cloud interactions. Consistently low CCN concentrations below cloud appear to be due to cloud scavenging processes which include Brownian coagulation, nucleation, coalescence, and drizzle. The higher CCN and CN concentrations above cloud are associated with ambient ozone concentrations which suggest a link with continental, probably anthropogenic, sources, even at distances of 500 km from the California coast.

  4. Condensing furnaces: Lessons from a utility

    SciTech Connect

    Beers, J.

    1994-11-01

    for the last several years about 90% of the new natural gas furnaces installed in Wisconsin have been condensing furnaces and a number of lessons have been learned. If you avoid the common mistakes, condensing furnaces typically can deliver heating savings of 20-35 % assuming the old furnace was in the 60% AFUE range. This article describes the common mistakes and how to avoid them: outside air needed 100%; benefits of sealed combustion; follow the installation manual scrupulously; how to avoid potential problems; tips on venting.

  5. Composition of gases vented from a condenser

    SciTech Connect

    Lyon, R.N.

    1980-08-01

    Designers of systems that involve condensers often need to predict the amount of process vapor that accompanies the noncondensable gases that are vented from the condensers. An approximation is given that appears to provide, in many cases, reasonably accurate values for the mole ratio of process vapor to noncondensable gases in the vented mixture. The approximation is particularly applicable to flash and direct-contact power systems for geothermal brines and ocean thermal energy conversion (OTEC). More regorous relationships are available for exceptional cases.

  6. The onset of molecular condensation: hydrogen.

    PubMed

    Morilla, J H; Fernández, J M; Tejeda, G; Montero, S

    2010-10-14

    The very first steps of condensation as studied experimentally in the simplest molecular system (para-H(2)) are reported. The fast time-space evolution of the nascent clusters have been measured using state-of-the-art Raman spectroscopy implemented on cryogenic supersonic jets. The time-dependent onset of condensation is presented in a non-equilibrium pressure-temperature phase diagram. Dimer and trimer formation are found to obey three-body processes whose rates have been determined. PMID:20683514

  7. Double-Stranded RNA Resists Condensation

    NASA Astrophysics Data System (ADS)

    Li, Li; Pabit, Suzette A.; Meisburger, Steve P.; Pollack, Lois

    2011-03-01

    Much attention has been focused on DNA condensation because of its fundamental biological importance. The recent discovery of new roles for RNA duplexes demands efficient packaging of double-stranded RNA for therapeutics. Here we report measurements of short DNA and RNA duplexes in the presence of trivalent ions. Under conditions where UV spectroscopy indicates condensation of DNA duplexes into (insoluble) precipitates, RNA duplexes remain soluble. Small angle x-ray scattering results suggest that the differing surface topologies of RNA and DNA may be crucial in generating the attractive forces that result in precipitation.

  8. Condenser optic with sacrificial reflective surface

    DOEpatents

    Tichenor, Daniel A.; Kubiak, Glenn D.; Lee, Sung Hun

    2007-07-03

    Employing collector optics that has a sacrificial reflective surface can significantly prolong the useful life of the collector optics and the overall performance of the condenser in which the collector optics are incorporated. The collector optics is normally subject to erosion by debris from laser plasma source of radiation. The presence of an upper sacrificial reflective surface over the underlying reflective surface effectively increases the life of the optics while relaxing the constraints on the radiation source. Spatial and temporally varying reflectivity that results from the use of the sacrificial reflective surface can be accommodated by proper condenser design.

  9. Condenser optic with sacrificial reflective surface

    DOEpatents

    Tichenor, Daniel A.; Kubiak, Glenn D.; Lee, Sang Hun

    2006-07-25

    Employing collector optics that have a sacrificial reflective surface can significantly prolong the useful life of the collector optics and the overall performance of the condenser in which the collector optics are incorporated. The collector optics are normally subject to erosion by debris from laser plasma source of radiation. The presence of an upper sacrificial reflective surface over the underlying reflective surface effectively increases the life of the optics while relaxing the constraints on the radiation source. Spatial and temporally varying reflectivity that results from the use of the sacrificial reflective surface can be accommodated by proper condenser design.

  10. Chromosome condensation and decondensation during mitosis.

    PubMed

    Antonin, Wolfram; Neumann, Heinz

    2016-06-01

    During eukaryotic cell division, nuclear chromatin undergoes marked changes with respect to shape and degree of compaction. Although already significantly compacted during interphase, upon entry into mitosis chromatin further condenses and individualizes to discrete chromosomes that are captured and moved independently by the mitotic spindle apparatus. Once segregated by the spindle, chromatin decondenses to re-establish its interphase structure competent for DNA replication and transcription. Although cytologically described a long time ago, the underlying molecular mechanisms of mitotic chromatin condensation and decondensation are still ill-defined. Here we summarize our current knowledge of mitotic chromatin restructuring and recent progress in the field. PMID:26895139

  11. QCD quark condensate in external magnetic fields

    NASA Astrophysics Data System (ADS)

    Bali, G. S.; Bruckmann, F.; Endrődi, G.; Fodor, Z.; Katz, S. D.; Schäfer, A.

    2012-10-01

    We present a comprehensive analysis of the light condensates in QCD with 1+1+1 sea quark flavors (with mass-degenerate light quarks of different electric charges) at zero and nonzero temperatures of up to 190 MeV and external magnetic fields B<1GeV2/e. We employ stout smeared staggered fermions with physical quark masses and extrapolate the results to the continuum limit. At low temperatures we confirm the magnetic catalysis scenario predicted by many model calculations while around the crossover the condensate develops a complex dependence on the external magnetic field, resulting in a decrease of the transition temperature.

  12. Signatures for Multi-{alpha}-Condensed States

    SciTech Connect

    Kokalova, Tz.; Wheldon, C.; Itagaki, N.; Oertzen, W. von

    2006-05-19

    An experimental way of testing Bose-Einstein condensation of {alpha} clusters in the atomic nucleus is reported. The enhancement of cluster emission and the multiplicity partition of possible emitted clusters could be direct signatures for the condensed states. The barrier for the emission of clusters, such as {sup 8}Be and {sup 12}C{sup *}(0{sub 2}{sup +}), is calculated and compared with the barrier for the sequential emission of 2 or 3{alpha} particles from the compound nucleus. For the calculations, a simple approach using a folded Woods-Saxon potential is used.

  13. Bose-Einstein condensation. Twenty years after

    SciTech Connect

    Bagnato, V. S.; Frantzeskakis, D. J.; Kevrekidis, P. G.; Malomed, B. A.; Mihalache, D.

    2015-02-23

    The aim of this introductory article is two-fold. First, we aim to offer a general introduction to the theme of Bose-Einstein condensates, and briefly discuss the evolution of a number of relevant research directions during the last two decades. Second, we introduce and present the articles that appear in this Special Volume of Romanian Reports in Physics celebrating the conclusion of the second decade since the experimental creation of Bose-Einstein condensation in ultracold gases of alkali-metal atoms.

  14. Bose-Einstein Condensation of Strontium

    SciTech Connect

    Stellmer, Simon; Huang Bo; Grimm, Rudolf; Tey, Meng Khoon; Schreck, Florian

    2009-11-13

    We report on the attainment of Bose-Einstein condensation with ultracold strontium atoms. We use the {sup 84}Sr isotope, which has a low natural abundance but offers excellent scattering properties for evaporative cooling. Accumulation in a metastable state using a magnetic-trap, narrowline cooling, and straightforward evaporative cooling in an optical trap lead to pure condensates containing 1.5x10{sup 5} atoms. This puts {sup 84}Sr in a prime position for future experiments on quantum-degenerate gases involving atomic two-electron systems.

  15. Improved plant performance through evaporative steam condensing

    SciTech Connect

    Hutton, D.

    1998-07-01

    Combining an open cooling tower and a steam condenser into one common unit is a proven technology with many advantages in power generation application, including reduced first cost of equipment, reduced parasitic energy consumption, simplified design, reduced maintenance, and simplified water treatment, Performance of the steam turbine benefits from the direct approach to wet bulb temperature, and operating flexibility and reliability improve compared to a system with a cooling tower and surface condenser. System comparisons and case histories will be presented to substantiate improved systems economies.

  16. Analytical Treatment of Normal Condensation Shock

    NASA Technical Reports Server (NTRS)

    Heybey

    1947-01-01

    The condensation of water vapor in an air consequences: acquisition of heat (liberated heat vaporization; loss of mass on the part of the flowing gas (water vapor is converted to liquid); change in the specific gas constants and of the ratio k of the specific heats (caused by change of gas composition). A discontinuous change of state is therefore connected with the condensation; schlieren photographs of supersonic flows in two-dimensional Laval nozzles show two intersecting oblique shock fronts that in the case of high humidities may merge near the point of intersection into one normal shock front.

  17. Novel insights into mitotic chromosome condensation

    PubMed Central

    Piskadlo, Ewa; Oliveira, Raquel A.

    2016-01-01

    The fidelity of mitosis is essential for life, and successful completion of this process relies on drastic changes in chromosome organization at the onset of nuclear division. The mechanisms that govern chromosome compaction at every cell division cycle are still far from full comprehension, yet recent studies provide novel insights into this problem, challenging classical views on mitotic chromosome assembly. Here, we briefly introduce various models for chromosome assembly and known factors involved in the condensation process (e.g. condensin complexes and topoisomerase II). We will then focus on a few selected studies that have recently brought novel insights into the mysterious way chromosomes are condensed during nuclear division. PMID:27508072

  18. Rayleigh-Taylor instability in binary condensates

    SciTech Connect

    Gautam, S.; Angom, D.

    2010-05-15

    We propose a well-controlled experimental scheme to initiate and examine the Rayleigh-Taylor instability in two-species Bose-Einstein condensates. We identify the {sup 85}Rb-{sup 87}Rb mixture as an excellent candidate to observe experimentally. The instability is initiated by tuning the {sup 85}Rb-{sup 85}Rb interaction through a magnetic Feshbach resonance. We show that the observable signature of the instability is the damping of the radial oscillations. We also propose a semianalytic scheme to determine the stationary state of binary condensates with the Thomas-Fermi approximation for axisymmetric traps.

  19. Kinetics of red blood cell aggregation: an example of geometric polymerization

    SciTech Connect

    Perelson, A.S.; Samsel, R.W.

    1984-04-02

    The kinetics of the process by which red blood cells aggregate into long cylindrical, and sometimes branched, structures called rouleaux is studied within the framework of both reversible and irreversible addition and condensation polymerization reactions. However, unlike usual polymer kinetics, here we take into account the geometry of the subunits and the geometry of the growing structure. Geometric factors such as the amount of reactive wall area influence the probability of branching and hence the final shape of the aggregate. The inclusion of loop formation reactions is shown to be crucial in obtaining physically realistic equilibrium solutions of the kinetic equations. 11 references, 3 figures.

  20. Comparing the mechanism of water condensation and evaporation in glassy aerosol.

    PubMed

    Bones, David L; Reid, Jonathan P; Lienhard, Daniel M; Krieger, Ulrich K

    2012-07-17

    Atmospheric models generally assume that aerosol particles are in equilibrium with the surrounding gas phase. However, recent observations that secondary organic aerosols can exist in a glassy state have highlighted the need to more fully understand the kinetic limitations that may control water partitioning in ambient particles. Here, we explore the influence of slow water diffusion in the condensed aerosol phase on the rates of both condensation and evaporation, demonstrating that significant inhibition in mass transfer occurs for ultraviscous aerosol, not just for glassy aerosol. Using coarse mode (3-4 um radius) ternary sucrose/sodium chloride/aqueous droplets as a proxy for multicomponent ambient aerosol, we demonstrate that the timescale for particle equilibration correlates with bulk viscosity and can be ≫10(3) s. Extrapolation of these timescales to particle sizes in the accumulation mode (e.g., approximately 100 nm) by applying the Stokes-Einstein equation suggests that the kinetic limitations imposed on mass transfer of water by slow bulk phase diffusion must be more fully investigated for atmospheric aerosol. Measurements have been made on particles covering a range in dynamic viscosity from < 0.1 to > 10(13) Pa s. We also retrieve the radial inhomogeneities apparent in particle composition during condensation and evaporation and contrast the dynamics of slow dissolution of a viscous core into a labile shell during condensation with the slow percolation of water during evaporation through a more homogeneous viscous particle bulk. PMID:22753520

  1. Ammonium nitrate evaporation and nitric acid condensation in DMT CCN counters

    NASA Astrophysics Data System (ADS)

    Romakkaniemi, S.; Jaatinen, A.; Laaksonen, A.; Nenes, A.; Raatikainen, T.

    2014-05-01

    The effect of inorganic semivolatile aerosol compounds on the cloud condensation nucleus (CCN) activity of aerosol particles was studied by using a computational model for a DMT-CCN counter, a cloud parcel model for condensation kinetics and experiments to quantify the modelled results. Concentrations of water vapour and semivolatiles as well as aerosol trajectories in the CCN column were calculated by a computational fluid dynamics model. These trajectories and vapour concentrations were then used as an input for the cloud parcel model to simulate mass transfer kinetics of water and semivolatiles between aerosol particles and the gas phase. Two different questions were studied: (1) how big a fraction of semivolatiles is evaporated from particles after entering but before particle activation in the DMT-CCN counter? (2) How much can the CCN activity be increased due to condensation of semivolatiles prior to the maximum water supersaturation in the case of high semivolatile concentration in the gas phase? Both experimental and modelling results show that the evaporation of ammonia and nitric acid from ammonium nitrate particles causes a 10 to 15 nm decrease to the critical particle size in supersaturations between 0.1% and 0.7%. On the other hand, the modelling results also show that condensation of nitric acid or similar vapour can increase the CCN activity of nonvolatile aerosol particles, but a very high gas phase concentration (as compared to typical ambient conditions) would be needed. Overall, it is more likely that the CCN activity of semivolatile aerosol is underestimated than overestimated in the measurements conducted in ambient conditions.

  2. Experiments on condensation over in-line and staggered condenser tubes in the presence of non-condensable gases

    NASA Astrophysics Data System (ADS)

    Ramadan, Abdulghani; Yamali, Cemil

    2013-12-01

    The problem of the forced film condensation heat transfer of pure steam and steam-air mixture flowing downward a tier of horizontal cylinders is investigated experimentally. An experimental setup was manufactured and mounted at Middle East Technical University workshop. A set of experiments were conducted to observe the condensation heat transfer phenomenon and to verify the theoretical results. The results of the experimental investigation are presented to show the effect of different parameters on the film condensation heat transfer phenomenon over bundle of tubes. These parameters include; free stream velocity, free stream non-condensable gas (air) mass fractions, free stream temperature to wall temperature difference, the angle of inclination. heat transfer coefficients are evaluated at different working conditions for both inline and staggered arrangements. Results show that; a remarked reduction in the vapor side heat transfer coefficient is noticed when very small amounts of air mass fractions present in the vapor. In addition, it decreases by increasing the temperature difference. On the other hand, it increases by increasing the free stream velocity (Reynolds number). Average heat transfer coefficient at the middle and the bottom cylinders increases by increasing the angle of inclination, whereas, no significant change is observed for that of the upper cylinder. Although some discrepancies are noticed, the present study results are inline and in a reasonable agreement with the theory and experiment in the literature.

  3. Bose-Einstein Condensation and Condensation of q-Particles in Equilibrium and Nonequilibrium Thermodynamics

    NASA Astrophysics Data System (ADS)

    Accardi, Luigi; Fidaleo, Francesco

    2016-04-01

    In the setting of the principle of local equilibrium which asserts that the temperature is a function of energy levels of the system, we exhibit plenty of steady states describing condensation of free bosons which are not in thermal equilibrium. The surprising facts are that the condensation can occur both in dimension less than 3 in configuration space, and even in excited energy levels. The investigation relative to nonequilibrium suggests a new approach to the condensation which allows a unified analysis involving also condensation of q-particles, -1 ≤ q ≤ 1, where q = ±1 corresponds to the Bose/Fermi alternative. For such q-particles, it is shown that condensation can occur only if 0 condensation. In this more general approach, completely new and unexpected states exhibiting condensation phenomena naturally occur even in the usual situation of equilibrium thermodynamics involving bosons. The new approach proposed in the present paper for the situation of second quantisation of free particles, is based on the theory of distributions, which might hopefully be extended to more general cases.

  4. Kinetics of wet sodium vapor complex plasma

    SciTech Connect

    Mishra, S. K.; Sodha, M. S.

    2014-04-15

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  5. Chemical Kinetics Database

    National Institute of Standards and Technology Data Gateway

    SRD 17 NIST Chemical Kinetics Database (Web, free access)   The NIST Chemical Kinetics Database includes essentially all reported kinetics results for thermal gas-phase chemical reactions. The database is designed to be searched for kinetics data based on the specific reactants involved, for reactions resulting in specified products, for all the reactions of a particular species, or for various combinations of these. In addition, the bibliography can be searched by author name or combination of names. The database contains in excess of 38,000 separate reaction records for over 11,700 distinct reactant pairs. These data have been abstracted from over 12,000 papers with literature coverage through early 2000.

  6. A "Stationery" Kinetics Experiment.

    ERIC Educational Resources Information Center

    Hall, L.; Goberdhansingh, A.

    1988-01-01

    Describes a simple redox reaction that occurs between potassium permanganate and oxalic acid that can be used to prepare an interesting disappearing ink for demonstrating kinetics for introductory chemistry. Discusses laboratory procedures and factors that influence disappearance times. (CW)

  7. Enzyme Kinetics in Microgravity

    NASA Astrophysics Data System (ADS)

    Liu, C. C.; Licata, V. J.

    2010-04-01

    The kinetics of some enzymes have been found to be enhanced by the microgravity environment. This is a relatively small effect, but is sufficient to have physiological effects and to impact pharmaceutical therapy in microgravity.

  8. Enhancing Condensers for Geothermal Systems: the Effect of High Contact Angles on Dropwise Condensation Heat Transfer

    SciTech Connect

    Kennedy, John M.; Kim, Sunwoo; Kim, Kwang J.

    2009-10-06

    Phase change heat transfer is notorious for increasing the irreversibility of, and therefore decreasing the efficiency of, geothermal power plants. Its significant contribution to the overall irreversibility of the plant makes it the most important source of inefficiency in the process. Recent studies here have shown the promotion of drop wise condensation in the lab by means of increasing the surface energy density of a tube with nanotechnology. The use of nanotechnology has allowed the creation of surface treatments which discourage water from wetting a tube surface during a static test. These surface treatments are unique in that they create high- contact angles on the condensing tube surfaces to promote drop wise condensation.

  9. Mechanisms for O/sup -/ electron stimulated desorption via dissociative attachment in condensed CO

    SciTech Connect

    Azria, R.; Parenteau, L.; Sanche, L.

    1988-04-15

    The formation of O/sup -/ ions via dissociative attachment (DA) in electron stimulated desorption from condensed CO is reported. The /sup 2/Pi states of CO/sup -/ previously observed in the gas phase and CO/sup -/ states with the forbidden symmetry ..sigma../sup -/ are involved below and above 13 eV, respectively, in the DA processes. Measurements of the kinetic energy of O/sup -/ ions indicate that they suffer post dissociation interactions with the neighboring CO molecules before leaving the solid.

  10. Nonlinear vortex-phonon interactions in a Bose–Einstein condensate

    NASA Astrophysics Data System (ADS)

    Mendonça, J. T.; Haas, F.; Gammal, A.

    2016-07-01

    We consider the nonlinear coupling between an exact vortex solution in a Bose–Einstein condensate and a spectrum of elementary excitations in the medium. These excitations, or Bogoliubov–de Gennes modes, are indeed a special kind of phonons. We treat the spectrum of elementary excitations in the medium as a gas of quantum particles, sometimes also called bogolons. An exact kinetic equation for the bogolon gas is derived, and an approximate form of this equation, valid in the quasi-classical limit, is also obtained. We study the energy transfer between the vortex and the bogolon gas, and establish conditions for vortex instability and damping.

  11. Condensate-removal device for heat exchangers

    NASA Technical Reports Server (NTRS)

    Trusch, R. B.; Oconnor, E. W.

    1973-01-01

    Device comprises array of perforated tubes manifolded together and connected to a vacuum suction device. Vacuum applied to these tubes pulls mixture of condensate and effluent gas through perforations and along length of tubes to discharge device. Discharge device may be a separator which separates water vapor from effluent air and allows recirculation of both of them.

  12. TREATMENT OF AMMONIA PLANT PROCESS CONDENSATE EFFLUENT

    EPA Science Inventory

    The report gives results of an examination of contaminant content and selected treatment techniques for process condensate from seven different ammonia plants. Field tests were performed and data collected on an in-plant steam stripping column with vapor injection into the reform...

  13. THE COLOR GLASS CONDENSATE, RHIC AND HERA.

    SciTech Connect

    MCLERRAN,L.

    2002-04-30

    In this talk, I discuss a universal form of matter, the Color Glass Condensate. It is this matter which composes the low x part of all hadronic wavefunctions. The experimental programs at RHIC and HERA, and future programs at LHC and eRHIC may allow us to probe and study the properties of this matter.

  14. CLOUD CONDENSATION NUCLEI MEASUREMENTS WITHIN CLOUDS

    EPA Science Inventory

    Measurements of the spectra of cloud condensation nuclei (CCN) within and near the boundaries of clouds are presented. Some of the in-cloud measurements excluded the nuclei within cloud droplets (interstitial CCN) while others included all nuclei inside the cloud (total CCN). The...

  15. MOBILE BED FLUX FORCE/CONDENSATION SCRUBBERS

    EPA Science Inventory

    The report gives results of an experimental determination of fine particle collection in mobile bed scrubbers. Particle collection efficiency increased greatly as the gas-phase pressure drop increased. With no water vapor condensation, the performance capability of a mobile bed s...

  16. Electroweak Symmetry Breaking from Monopole Condensation

    SciTech Connect

    Csaki, Csaba; Shirman, Yuri; Terning, John

    2011-01-28

    We argue that the electroweak symmetry of the standard model (SM) could be broken via condensation of magnetic monopole bilinears. We present an extension of the SM where this could indeed happen, and where the heavy top mass is also a consequence of the magnetic interactions.

  17. A Moment-Based Condensed History Algorithm

    SciTech Connect

    Tolar, D.R.; Larsen, E.W.

    2000-06-15

    ''Condensed History'' algorithms are Monte Carlo models for electron transport problems, They describe the aggregate effect of multiple collisions that occur when an electron travels a path length s{sub 0}. This path length is the distance each Monte Carlo electron travels between Condensed History steps. Conventional Condensed History schemes employ a splitting routine over the range 0 {le} s {le} s{sub 0}. For example, the Random Hinge method splits each path length step into two substeps; one with length {xi}s{sub 0} and one with length (1-{xi})s{sub 0}, where {xi} is a random number from 0 < {xi} < 1. Here we develop a new Condensed History algorithm to improve the accuracy of electron transport simulations by preserving the mean position and the variance in the mean of electrons that have traveled a path length s and are traveling with the direction cosine {mu}. These means and variances are obtained from the zeroth-, first-, and second-order spatial moments of the Boltzmann transport equation. Hence, our method is a Monte Carlo application of the ''Method of Moments''.

  18. Imaging of DNA/Nanosphere Condensates

    NASA Astrophysics Data System (ADS)

    Krishnan, R.

    2005-03-01

    DNA forms condensates in a variety of environments. In chromatin, DNA is condensed around 10-nm-diameter, positively-charged histone complexes. To model chromatin formation in cells, lambda-phage (16 microns long) and herring sperm (0.03 to1 micron) DNAs were mixed with polystyrene nanospheres of diameter 40nm and 930nm containing 1.8x10^4 and 2.6x10^8 positive surface charges, respectively, to form condensates. Sphere concentrations were 1-2 times the isoelectric concentration. Condensation vs time was imaged at various concentrations, pH's, viscosities, and ionic strengths. Bright-field and fluorescence (YOYO-1 dye bound to DNA) images were recorded. In general HS DNA aggregate size increased with time. Except in 0.5-0.8 M KCl, herring sperm DNA formed one huge aggregate (100's of microns) and depleted other areas, both in 10% and 20% glycerol. Phage DNA samples rapidly formed longer, fiber-like aggregates. Within 2 hours it formed ordered structures and in most samples, empty, apparently depleted regions were found in the viewing area. Shapes of the phage-DNA aggregates in 20% glycerol, in contrast, formed small clumps like HS DNA.

  19. Three lectures on the Color Glass Condensate

    SciTech Connect

    Venugopalan, Raju

    2004-12-02

    We summarize the theory and phenomenology of the Color Glass Condensate reviewed previously by E. Iancu and the author in hep-ph/0303204. We discuss some of the subsequent developments in the past year both in theory and in phenomenological applications.

  20. VOLATILE COMPONENT RECOVERY FROM SULFITE EVAPORATOR CONDENSATE

    EPA Science Inventory

    This study is on the operation and modification of a demonstration unit to remove sulfur dioxide, methanol, furfural, and acetic acid from its sulfite evaporator condensate. This unit consisted of a steam stripper, vent tank SO2 recovery, activated carbon adsorption columns, and ...

  1. Free convective condensation in a vertical enclosure

    SciTech Connect

    Fox, R.J.; Peterson, P.F.; Corradini, M.L.; Pernsteiner, A.P.

    1995-09-01

    Free convective condensation in a vertical enclosure was studied numerically and the results were compared with experiments. In both the numerical and experimental investigations, mist formation was observed to occur near the cooling wall, with significant droplet concentrations in the bulk. Large recirculation cells near the end of the condensing section were generated as the heavy noncondensing gas collecting near the cooling wall was accelerated downward. Near the top of the enclosure the recirculation cells became weaker and smaller than those below, ultimately disappearing near the top of the condenser. In the experiment the mist density was seen to be highest near the wall and at the bottom of the condensing section, whereas the numerical model predicted a much more uniform distribution. The model used to describe the formation of mist was based on a Modified Critical Saturation Model (MCSM), which allows mist to be generated once the vapor pressure exceeds a critical value. Equilibrium, nonequilibrium, and MCSM calculations were preformed, showing the experimental results to lie somewhere in between the equilibrium and nonequilibrium predictions of the numerical model. A single adjustable constant (indicating the degree to which equilibrium is achieved) is used in the model in order to match the experimental results.

  2. Activity, purification, and analysis of condensed tannins

    Technology Transfer Automated Retrieval System (TEKTRAN)

    As a class of plant polyphenolic compounds contained in some forages (i.e., sanfoin, big trefoil, birdfoot trefoil), condensed tannins (CTs), also referred to as proanthocyanidins (PAs), exhibit a variety of biological effects on ruminants and on the dairy farm nitrogen cycle. Interest in CTs stems ...

  3. Convection in Condensible-rich Atmospheres

    NASA Astrophysics Data System (ADS)

    Ding, F.; Pierrehumbert, R. T.

    2016-05-01

    Condensible substances are nearly ubiquitous in planetary atmospheres. For the most familiar case—water vapor in Earth’s present climate—the condensible gas is dilute, in the sense that its concentration is everywhere small relative to the noncondensible background gases. A wide variety of important planetary climate problems involve nondilute condensible substances. These include planets near or undergoing a water vapor runaway and planets near the outer edge of the conventional habitable zone, for which CO2 is the condensible. Standard representations of convection in climate models rely on several approximations appropriate only to the dilute limit, while nondilute convection differs in fundamental ways from dilute convection. In this paper, a simple parameterization of convection valid in the nondilute as well as dilute limits is derived and used to discuss the basic character of nondilute convection. The energy conservation properties of the scheme are discussed in detail and are verified in radiative-convective simulations. As a further illustration of the behavior of the scheme, results for a runaway greenhouse atmosphere for both steady instellation and seasonally varying instellation corresponding to a highly eccentric orbit are presented. The latter case illustrates that the high thermal inertia associated with latent heat in nondilute atmospheres can damp out the effects of even extreme seasonal forcing.

  4. Condensation in a two-phase pool

    SciTech Connect

    Duffey, R.B.; Hughes, E.D.

    1991-12-31

    We consider the case of vapor condensation in a liquid pool, when the heat transfer is controlled by heat losses through the walls. The analysis is based on drift flux theory for phase separation in the pool, and determines the two-phase mixture height for the pool. To our knowledge this is the first analytical treatment of this classic problem that gives an explicit result, previous work having established the result for the evaporative case. From conservation of mass and energy in a one-dimensional steady flow, together with a void relation between the liquid and vapor fluxes, we determine the increase in the mixture level from the base level of the pool. It can be seen that the thermal and hydrodynamic influences are separable. Thus, the thermal influence of the wall heat transfer appears through its effect on the condensing length L*, so that at high condensation rates the pool is all liquid, and at low rates overflows (the level swell or foaming effect). Similarly, the phase separation effect hydrodynamically determines the height via the relative velocity of the mixture to the entering flux. We examine some practical applications of this result to level swell in condensing flows, and also examine some limits in ideal cases.

  5. Condensation in a two-phase pool

    SciTech Connect

    Duffey, R.B. ); Hughes, E.D. )

    1991-01-01

    We consider the case of vapor condensation in a liquid pool, when the heat transfer is controlled by heat losses through the walls. The analysis is based on drift flux theory for phase separation in the pool, and determines the two-phase mixture height for the pool. To our knowledge this is the first analytical treatment of this classic problem that gives an explicit result, previous work having established the result for the evaporative case. From conservation of mass and energy in a one-dimensional steady flow, together with a void relation between the liquid and vapor fluxes, we determine the increase in the mixture level from the base level of the pool. It can be seen that the thermal and hydrodynamic influences are separable. Thus, the thermal influence of the wall heat transfer appears through its effect on the condensing length L*, so that at high condensation rates the pool is all liquid, and at low rates overflows (the level swell or foaming effect). Similarly, the phase separation effect hydrodynamically determines the height via the relative velocity of the mixture to the entering flux. We examine some practical applications of this result to level swell in condensing flows, and also examine some limits in ideal cases.

  6. Condensation of topological defects and confinement

    NASA Astrophysics Data System (ADS)

    Gaete, Patricio; Wotzasek, Clovis

    2004-11-01

    We study the static quantum potential for a theory of antisymmetric tensor fields that results from the condensation of topological defects, within the framework of the gauge-invariant but path-dependent variables formalism. Our calculations show that the interaction energy is the sum of a Yukawa and a linear potentials, leading to the confinement of static probe charges.

  7. MINIATURE ACID CONDENSATION SYSTEM: DESIGN AND OPERATION

    EPA Science Inventory

    An extractive source sampling system was designed and constructed. The sampling system measures gaseous sulfuric acid and sulfur dioxide in combustion emissions. The miniature acid condensation system (MACS) includes a high-temperature quartz probe and quartz-filter holder. Since...

  8. 242-A evaporator vacuum condenser system

    SciTech Connect

    Smith, V.A.

    1994-09-28

    This document is written for the 242-A evaporator vacuum condenser system (VCS), describing its purpose and operation within the evaporator. The document establishes the operating parameters specifying pressure, temperature, flow rates, interlock safety features and interfacing sub-systems to support its operation.

  9. A new experiment for investigating evaporation and condensation of cryogenic propellants

    NASA Astrophysics Data System (ADS)

    Bellur, K.; Médici, E. F.; Kulshreshtha, M.; Konduru, V.; Tyrewala, D.; Tamilarasan, A.; McQuillen, J.; Leão, J. B.; Hussey, D. S.; Jacobson, D. L.; Scherschligt, J.; Hermanson, J. C.; Choi, C. K.; Allen, J. S.

    2016-03-01

    Passive and active technologies have been used to control propellant boil-off, but the current state of understanding of cryogenic evaporation and condensation in microgravity is insufficient for designing large cryogenic depots critical to the long-term space exploration missions. One of the key factors limiting the ability to design such systems is the uncertainty in the accommodation coefficients (evaporation and condensation), which are inputs for kinetic modeling of phase change. A novel, combined experimental and computational approach is being used to determine the accommodation coefficients for liquid hydrogen and liquid methane. The experimental effort utilizes the Neutron Imaging Facility located at the National Institute of Standards and Technology (NIST) in Gaithersburg, Maryland to image evaporation and condensation of hydrogenated propellants inside of metallic containers. The computational effort includes numerical solution of a model for phase change in the contact line and thin film regions as well as an CFD effort for determining the appropriate thermal boundary conditions for the numerical solution of the evaporating and condensing liquid. Using all three methods, there is the possibility of extracting the accommodation coefficients from the experimental observations. The experiments are the first known observation of a liquid hydrogen menisci condensing and evaporating inside aluminum and stainless steel cylinders. The experimental technique, complimentary computational thermal model and meniscus shape determination are reported. The computational thermal model has been shown to accurately track the transient thermal response of the test cells. The meniscus shape determination suggests the presence of a finite contact angle, albeit very small, between liquid hydrogen and aluminum oxide.

  10. Cloud Condensation in Titan's Lower Stratosphere

    NASA Technical Reports Server (NTRS)

    Romani, Paul N.; Anderson, Carrie M.

    2011-01-01

    A 1-D condensation model is developed for the purpose of reproducing ice clouds in Titan's lower stratosphere observed by the Composite Infrared Spectrometer (CIRS) onboard Cassini. Hydrogen cyanide (HCN), cyanoacetylene (HC3N), and ethane (C2H6) vapors are treated as chemically inert gas species that flow from an upper boundary at 500 km to a condensation sink near Titan's tropopause (-45 km). Gas vertical profiles are determined from eddy mixing and a downward flux at the upper boundary. The condensation sink is based upon diffusive growth of the cloud particles and is proportional to the degree of supersaturation in the cloud formation regIOn. Observations of the vapor phase abundances above the condensation levels and the locations and properties of the ice clouds provide constraints on the free parameters in the model. Vapor phase abundances are determined from CIRS mid-IR observations, whereas cloud particle sizes, altitudes, and latitudinal distributions are derived from analyses of CIRS far-IR observations of Titan. Specific cloud constraints include: I) mean particle radii of2-3 J.lm inferred from the V6 506 cm- band of HC3N, 2) latitudinal abundance distributions of condensed nitriles, inferred from a composite emission feature that peaks at 160/cm , and 3) a possible hydrocarbon cloud layer at high latitudes, located near an altitude of 60 km, which peaks between 60 and 80 cm l . Nitrile abundances appear to diminish substantially at high northern latitudes over the time period 2005 to 2010 (northern mid winter to early spring). Use of multiple gas species provides a consistency check on the eddy mixing coefficient profile. The flux at the upper boundary is the net column chemical production from the upper atmosphere and provides a constraint on chemical pathways leading to the production of these compounds. Comparison of the differing lifetimes, vapor phase transport, vapor phase loss rate, and particle sedimentation, sheds light on temporal stability

  11. Plate-fin condenser for condensation of low pressure steam in the presence of noncondensable gases

    SciTech Connect

    Panchal, C.B.; Vega, L.; Bell, K.J.

    1997-08-01

    Condensation of steam in the presence of noncondensable gases was carried out in a plate-fin condenser. A three-water pass test unit was designed for the ocean-thermal energy conversion system in Hawaii. A point-wise calculation method was used for the cross-flow arrangement and the local heat- and mass-flux calculation was carried out on the basis of the Colburn-Hougen analysis. The test unit consisted of extruded water passages and finned surface on the steam side. The core unit was bonded with a thermally conductive epoxy (Loctite{reg_sign}) with welded joints along seam lines. The present investigation provides a design basis for the development of plate-fin condensers for condensation of multicomponent vapor mixtures in the process industry.

  12. A Computational Method for Compressible Flows with Condensation in Power Plant Condensers

    NASA Astrophysics Data System (ADS)

    Takahashi, Fumio; Harada, Iwao

    A computational method for compressible flows with condensation was developed. Condensation was formulated by two thermodynamic equations of state for pressure and energy. These equations of state were simultaneously solved with the Euler equation and heat transfer equations. A finite volume method based on an approximate Riemann solver was adopted to solve the Euler equation. The computational method was applied to compressible flows in a condenser and a turbine exhaust hood. The flow regime changed widely from subsonic flow to transonic flow during a small decrease of cooling water temperature. Subcooling temperature from the annulus of the turbine blades to the condensate in the hot well was investigated. Results showed the subcooling temperature could be reduced by using an advanced steam guide which was designed to improve diffuser performance under widely changing conditions.

  13. Rarefied gas flow between two cylinders caused by the evaporation and condensation on their surfaces

    NASA Astrophysics Data System (ADS)

    Gramani Cumin, Liliana M.; Sharipov, Felix M.; Kremer, Gilberto M.

    1998-12-01

    The rarefied gas flow between two coaxial cylinders caused by the evaporation and condensation on their surfaces is investigated on the basis of the kinetic and hydrodynamical equations. It is assumed that the cylinders may rotate with equal angular velocity. The equilibrium is perturbed by the small density difference of evaporated particles on the inner cylinder. The hydrodynamical equation has been solved analytically and the kinetic equation has been solved by the discrete velocity method modified for the discontinuous distribution function. The fields of the density, the velocity and the temperature are presented for a wide range of the Knudsen number. An analysis of the influence of the rotation of the cylinders on the flow field is given.

  14. Condensation of water vapor in the gravitational field

    SciTech Connect

    Gorshkov, V. G.; Makarieva, A. M.; Nefiodov, A. V.

    2012-10-15

    Physical peculiarities of water vapor condensation under conditions of hydrostatic equilibrium are considered. The power of stationary dynamic air fluxes and the vertical temperature distribution caused by condensation on large horizontal scales are estimated.

  15. 39. GENERAL VIEW OF VIVIANNA WORKS CONDENSING CHANNEL CONNECTING TO ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    39. GENERAL VIEW OF VIVIANNA WORKS CONDENSING CHANNEL CONNECTING TO MARISCAL WORKS STACK BEING REUSED AS FINAL CONDENSER LOOKING EAST, NORTHEAST. STONE STRUCTURE IN FOREGROUND UNKNOWN. - Mariscal Quicksilver Mine & Reduction Works, Terlingua, Brewster County, TX

  16. Molecular dynamics studies to understand the mechanism of heat accommodation in homogeneous condensing flow of carbon dioxide.

    PubMed

    Kumar, Rakesh; Li, Zheng; van Duin, Adri; Levin, Deborah

    2011-08-14

    Using molecular dynamics (MD), we have studied the mechanism of heat accommodation between carbon dioxide clusters and monomers for temperatures and cluster size conditions that exist in homogeneous condensing supersonic expansion plumes. The work was motivated by our meso-scale direct simulation Monte Carlo and Bhatnagar-Gross-Krook based condensation simulations where we found that the heat accommodation model plays a key role in the near-field of the nozzle expansion particularly as the degree of condensation increases [R. Kumar, Z. Li, and D. Levin, Phys. Fluids 23, 052001 (2011)]. The heat released by nucleation and condensation and the heat removed by cluster evaporation can be transferred or removed from either the kinetic or translational modes of the carbon dioxide monomers. The molecular dynamics results show that the time required for gas-cluster interactions to establish an equilibrium from an initial state of non-equilibrium is less than the time step used in meso-scale analyses [R. Kumar, Z. Li, and D. Levin, Phys. Fluids 23, 052001 (2011)]. Therefore, the good agreement obtained between the measured cluster and gas number density and gas temperature profiles with the meso-scale modeling using the second energy exchange mechanism is not fortuitous but is physically based. Our MD simulations also showed that a dynamic equilibrium is established by the gas-cluster interactions in which condensation and evaporation processes take place constantly to and from a cluster. PMID:21842939

  17. Experimental study on steam condensation with non-condensable gas in horizontal microchannels

    NASA Astrophysics Data System (ADS)

    Ma, Xuehu; Fan, Xiaoguang; Lan, Zhong; Jiang, Rui; Tao, Bai

    2013-07-01

    This paper experimentally studied steam condensation with non-condensable gas in trapezoidal microchannels. The effect of noncondensable gas on condensation two-phase flow patterns and the characteristics of heat transfer and frictional pressure drop were investigated. The visualization study results showed that the special intermittent annular flow was found in the microchannel under the condition of larger mole fraction of noncondensable gas and lower steam mass flux; the apical area of injection was much larger and the neck of injection was longer for mixture gas with lower mole fraction of noncondensable gas in comparison with pure steam condensation; meanwhile, the noncondensable gas resulted in the decrease of flow patterns transitional steam mass flux and quality. The experimental results also indicated that the frictional pressure drop increased with the increasing mole fraction of noncondensable gas when the steam mass flux was fixed. Unlike nature convective condensation heat transfer, the mole fraction of noncondensable gas had little effect on Nusselt number. Based on experimental data, the predictive correlation of Nusselt number for mixture gas condensation in microchannels was established showed good agreement with experimental data.

  18. Investigation of flow structures during HFE-7100 refrigerant condensation

    NASA Astrophysics Data System (ADS)

    Bohdal, Tadeusz; Sikora, Małgorzata; Widomska, Katarzyna; Radchenko, Andrii M.

    2015-12-01

    The experimental research of environmentally friendly refrigerant HFE-7100 condensation in pipe minichannels was conducted. During the investigations of HFE-7100 condensation in a minichannel with internal diameter 2 mm together with visualization of flow patterns was made. Visualization results were compared with existing flow structure maps. The identification of the range of flow patterns occurrence during the condensation process of low-pressure refrigerant HFE-7100 was made. The tests were performed throughout the whole range of condensation process.

  19. Inhomogeneous Polyakov loop induced by inhomogeneous chiral condensates

    NASA Astrophysics Data System (ADS)

    Hayata, Tomoya; Yamamoto, Arata

    2015-05-01

    We study the spatial inhomogeneity of the Polyakov loop induced by inhomogeneous chiral condensates. We formulate an effective model of gluons on the background fields of chiral condensates, and perform its lattice simulation. On the background of inhomogeneous chiral condensates, the Polyakov loop exhibits an in-phase spatial oscillation with the chiral condensates. We also analyze the heavy quark potential and show that the inhomogeneous Polyakov loop indicates the inhomogeneous confinement of heavy quarks.

  20. Multiple alternative substrate kinetics.

    PubMed

    Anderson, Vernon E

    2015-11-01

    The specificity of enzymes for their respective substrates has been a focal point of enzyme kinetics since the initial characterization of metabolic chemistry. Various processes to quantify an enzyme's specificity using kinetics have been utilized over the decades. Fersht's definition of the ratio kcat/Km for two different substrates as the "specificity constant" (ref [7]), based on the premise that the important specificity existed when the substrates were competing in the same reaction, has become a consensus standard for enzymes obeying Michaelis-Menten kinetics. The expansion of the theory for the determination of the relative specificity constants for a very large number of competing substrates, e.g. those present in a combinatorial library, in a single reaction mixture has been developed in this contribution. The ratio of kcat/Km for isotopologs has also become a standard in mechanistic enzymology where kinetic isotope effects have been measured by the development of internal competition experiments with extreme precision. This contribution extends the theory of kinetic isotope effects to internal competition between three isotopologs present at non-tracer concentrations in the same reaction mix. This article is part of a special issue titled: Enzyme Transition States from Theory and Experiment. PMID:26051088

  1. 40 CFR 721.10146 - Partially fluorinated condensation polymer (generic).

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Partially fluorinated condensation... Specific Chemical Substances § 721.10146 Partially fluorinated condensation polymer (generic). (a) Chemical... as partially fluorinated condensation polymer (PMN P-07-87) is subject to reporting under...

  2. 40 CFR 721.10146 - Partially fluorinated condensation polymer (generic).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Partially fluorinated condensation... Specific Chemical Substances § 721.10146 Partially fluorinated condensation polymer (generic). (a) Chemical... as partially fluorinated condensation polymer (PMN P-07-87) is subject to reporting under...

  3. 40 CFR 721.10146 - Partially fluorinated condensation polymer (generic).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Partially fluorinated condensation... Specific Chemical Substances § 721.10146 Partially fluorinated condensation polymer (generic). (a) Chemical... as partially fluorinated condensation polymer (PMN P-07-87) is subject to reporting under...

  4. 40 CFR 721.639 - Amine aldehyde condensate.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Amine aldehyde condensate. 721.639... Substances § 721.639 Amine aldehyde condensate. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as an amine aldehyde condensate (PMN...

  5. 40 CFR 721.639 - Amine aldehyde condensate.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Amine aldehyde condensate. 721.639... Substances § 721.639 Amine aldehyde condensate. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as an amine aldehyde condensate (PMN...

  6. 40 CFR 721.639 - Amine aldehyde condensate.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Amine aldehyde condensate. 721.639... Substances § 721.639 Amine aldehyde condensate. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as an amine aldehyde condensate (PMN...

  7. 40 CFR 721.639 - Amine aldehyde condensate.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Amine aldehyde condensate. 721.639... Substances § 721.639 Amine aldehyde condensate. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as an amine aldehyde condensate (PMN...

  8. 40 CFR 721.639 - Amine aldehyde condensate.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Amine aldehyde condensate. 721.639... Substances § 721.639 Amine aldehyde condensate. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as an amine aldehyde condensate (PMN...

  9. 21 CFR 131.120 - Sweetened condensed milk.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 2 2012-04-01 2012-04-01 false Sweetened condensed milk. 131.120 Section 131.120... FOR HUMAN CONSUMPTION MILK AND CREAM Requirements for Specific Standardized Milk and Cream § 131.120 Sweetened condensed milk. (a) Description. Sweetened condensed milk is the food obtained by partial...

  10. 21 CFR 131.120 - Sweetened condensed milk.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 2 2014-04-01 2014-04-01 false Sweetened condensed milk. 131.120 Section 131.120... FOR HUMAN CONSUMPTION MILK AND CREAM Requirements for Specific Standardized Milk and Cream § 131.120 Sweetened condensed milk. (a) Description. Sweetened condensed milk is the food obtained by partial...

  11. 21 CFR 131.120 - Sweetened condensed milk.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Sweetened condensed milk. 131.120 Section 131.120... FOR HUMAN CONSUMPTION MILK AND CREAM Requirements for Specific Standardized Milk and Cream § 131.120 Sweetened condensed milk. (a) Description. Sweetened condensed milk is the food obtained by partial...

  12. 21 CFR 131.120 - Sweetened condensed milk.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 2 2011-04-01 2011-04-01 false Sweetened condensed milk. 131.120 Section 131.120... FOR HUMAN CONSUMPTION MILK AND CREAM Requirements for Specific Standardized Milk and Cream § 131.120 Sweetened condensed milk. (a) Description. Sweetened condensed milk is the food obtained by partial...

  13. 7 CFR 58.237 - Condensed surge supply.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 3 2011-01-01 2011-01-01 false Condensed surge supply. 58.237 Section 58.237... Procedures § 58.237 Condensed surge supply. Surge tanks or balance tanks if used between the evaporators and dryer shall be used to hold only the minimum amount of condensed product necessary for a uniform flow...

  14. 7 CFR 58.237 - Condensed surge supply.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 3 2013-01-01 2013-01-01 false Condensed surge supply. 58.237 Section 58.237... Procedures § 58.237 Condensed surge supply. Surge tanks or balance tanks if used between the evaporators and dryer shall be used to hold only the minimum amount of condensed product necessary for a uniform flow...

  15. 7 CFR 58.238 - Condensed storage tanks.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 3 2012-01-01 2012-01-01 false Condensed storage tanks. 58.238 Section 58.238 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.238 Condensed storage tanks. (a) Excess production of condensed product over that which...

  16. 7 CFR 58.238 - Condensed storage tanks.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 3 2011-01-01 2011-01-01 false Condensed storage tanks. 58.238 Section 58.238 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.238 Condensed storage tanks. (a) Excess production of condensed product over that which...

  17. 7 CFR 58.238 - Condensed storage tanks.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 3 2014-01-01 2014-01-01 false Condensed storage tanks. 58.238 Section 58.238 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.238 Condensed storage tanks. (a) Excess production of condensed product over that which...

  18. 7 CFR 58.238 - Condensed storage tanks.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 3 2013-01-01 2013-01-01 false Condensed storage tanks. 58.238 Section 58.238 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.238 Condensed storage tanks. (a) Excess production of condensed product over that which...

  19. 7 CFR 58.237 - Condensed surge supply.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 3 2014-01-01 2014-01-01 false Condensed surge supply. 58.237 Section 58.237... Procedures § 58.237 Condensed surge supply. Surge tanks or balance tanks if used between the evaporators and dryer shall be used to hold only the minimum amount of condensed product necessary for a uniform flow...

  20. 7 CFR 58.238 - Condensed storage tanks.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Condensed storage tanks. 58.238 Section 58.238 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.238 Condensed storage tanks. (a) Excess production of condensed product over that which...

  1. 7 CFR 58.237 - Condensed surge supply.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Condensed surge supply. 58.237 Section 58.237... Procedures § 58.237 Condensed surge supply. Surge tanks or balance tanks if used between the evaporators and dryer shall be used to hold only the minimum amount of condensed product necessary for a uniform flow...

  2. 7 CFR 58.237 - Condensed surge supply.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 3 2012-01-01 2012-01-01 false Condensed surge supply. 58.237 Section 58.237... Procedures § 58.237 Condensed surge supply. Surge tanks or balance tanks if used between the evaporators and dryer shall be used to hold only the minimum amount of condensed product necessary for a uniform flow...

  3. 21 CFR 886.1380 - Diagnostic condensing lens.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Diagnostic condensing lens. 886.1380 Section 886...) MEDICAL DEVICES OPHTHALMIC DEVICES Diagnostic Devices § 886.1380 Diagnostic condensing lens. (a) Identification. A diagnostic condensing lens is a device used in binocular indirect ophthalmoscopy (a...

  4. 21 CFR 886.1380 - Diagnostic condensing lens.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Diagnostic condensing lens. 886.1380 Section 886...) MEDICAL DEVICES OPHTHALMIC DEVICES Diagnostic Devices § 886.1380 Diagnostic condensing lens. (a) Identification. A diagnostic condensing lens is a device used in binocular indirect ophthalmoscopy (a...

  5. 40 CFR 721.5713 - Phenol - biphenyl polymer condensate (generic).

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Phenol - biphenyl polymer condensate... Specific Chemical Substances § 721.5713 Phenol - biphenyl polymer condensate (generic). (a) Chemical... as a phenol - biphenyl polymer condensate (PMN P-00-1220) is subject to reporting under this...

  6. 40 CFR 721.5713 - Phenol - biphenyl polymer condensate (generic).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Phenol - biphenyl polymer condensate... Specific Chemical Substances § 721.5713 Phenol - biphenyl polymer condensate (generic). (a) Chemical... as a phenol - biphenyl polymer condensate (PMN P-00-1220) is subject to reporting under this...

  7. 40 CFR 721.5713 - Phenol - biphenyl polymer condensate (generic).

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Phenol - biphenyl polymer condensate... Specific Chemical Substances § 721.5713 Phenol - biphenyl polymer condensate (generic). (a) Chemical... as a phenol - biphenyl polymer condensate (PMN P-00-1220) is subject to reporting under this...

  8. 40 CFR 721.5713 - Phenol - biphenyl polymer condensate (generic).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Phenol - biphenyl polymer condensate... Specific Chemical Substances § 721.5713 Phenol - biphenyl polymer condensate (generic). (a) Chemical... as a phenol - biphenyl polymer condensate (PMN P-00-1220) is subject to reporting under this...

  9. 40 CFR 65.151 - Condensers used as control devices.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... parts per million by volume outlet concentration requirements as specified in § 65.63(a)(2), or 40 CFR... 40 Protection of Environment 16 2013-07-01 2013-07-01 false Condensers used as control devices. 65... System or a Process § 65.151 Condensers used as control devices. (a) Condenser equipment and...

  10. Spatial Dependence of Condensates in Strongly Coupled Gauge Theories

    SciTech Connect

    Brodsky, Stanley J.; Shrock, Robert; /SUNY, Stony Brook

    2008-03-25

    We analyze quark and gluon condensates in quantum chromodynamics. We suggest that these are localized inside hadrons, because the particles whose interactions are responsible for them are confined within these hadrons. This can explain the results of recent studies of gluon condensate contributions to vacuum correlators. We also give a general discussion of condensates in asymptotically free vectorial and chiral gauge theories.

  11. 40 CFR 721.5713 - Phenol - biphenyl polymer condensate (generic).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Phenol - biphenyl polymer condensate... Specific Chemical Substances § 721.5713 Phenol - biphenyl polymer condensate (generic). (a) Chemical... as a phenol - biphenyl polymer condensate (PMN P-00-1220) is subject to reporting under this...

  12. Hydrogen-bond kinetics in liquid water

    NASA Astrophysics Data System (ADS)

    Luzar, Alenka; Chandler, David

    1996-01-01

    HYDROGEN bonds play a crucial role in the behaviour of water1-4 their spatial patterns and fluctuations characterize the structure and dynamics of the liquid5-7. The processes of breaking and making hydrogen bonds in the condensed phase can be probed indirectly by a variety of experimental techniques8, and more quantitative information can be obtained from computer simulations9. In particular, simulations have revealed that on long timescales the relaxation behaviour of hydrogen bonds in liquid water exhibit non-exponential kinetics7,10-13, suggesting that bond making and breaking are not simple processes characterized by well defined rate constants. Here we show that these kinetics can be understood in terms of an interplay between diffusion and hydrogen-bond dynamics. In our model, which can be extended to other hydrogen-bonded liquids, diffusion governs whether a specific pair of water molecules are near neighbours, and hydrogen bonds between such pairs form and persist at random with average lifetimes determined by rate constants for bond making and breaking.

  13. Erbium hydride decomposition kinetics.

    SciTech Connect

    Ferrizz, Robert Matthew

    2006-11-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

  14. Synthesis, characterization and biological evaluation of anti-cancer indolizine derivatives via inhibiting β-catenin activity and activating p53.

    PubMed

    Moon, Seong-Hee; Jung, Youngeun; Kim, Seong Hwan; Kim, Ikyon

    2016-01-01

    Diversity-oriented construction of new indolizine scaffolds was accomplished by utilizing domino Knoevenagel condensation/intramolecular aldol cyclization. Biological evaluation revealed anticancer activity of these compounds through inhibition of β-catenin and activation of p53. PMID:26608553

  15. Kinetic theory viscosity

    NASA Astrophysics Data System (ADS)

    Clarke, C. J.; Pringle, J. E.

    2004-07-01

    We show how the viscous evolution of Keplerian accretion discs can be understood in terms of simple kinetic theory. Although standard physics texts give a simple derivation of momentum transfer in a linear shear flow using kinetic theory, many authors, as detailed by Hayashi & Matsuda, have had difficulties applying the same considerations to a circular shear flow. We show here how this may be done, and note that the essential ingredients are to take proper account of, first, isotropy locally in the frame of the fluid and, secondly, the geometry of the mean flow.

  16. Bose Condensation at He-4 Interfaces

    NASA Technical Reports Server (NTRS)

    Draeger, E. W.; Ceperley, D. M.

    2003-01-01

    Path Integral Monte Carlo was used to calculate the Bose-Einstein condensate fraction at the surface of a helium film at T = 0:77 K, as a function of density. Moving from the center of the slab to the surface, the condensate fraction was found to initially increase with decreasing density to a maximum value of 0.9, before decreasing. Long wavelength density correlations were observed in the static structure factor at the surface of the slab. A surface dispersion relation was calculated from imaginary-time density-density correlations. Similar calculations of the superfluid density throughout He-4 droplets doped with linear impurities (HCN)(sub n) are presented. After deriving a local estimator for the superfluid density distribution, we find a decreased superfluid response in the first solvation layer. This effective normal fluid exhibits temperature dependence similar to that of a two-dimensional helium system.

  17. Cloud condensation nuclei near marine cumulus

    NASA Technical Reports Server (NTRS)

    Hudson, James G.

    1993-01-01

    Extensive airborne measurements of cloud condensation nucleus (CCN) spectra and condensation nuclei below, in, between, and above the cumulus clouds near Hawaii point to important aerosol-cloud interactions. Consistent particle concentrations of 200/cu cm were found above the marine boundary layer and within the noncloudy marine boundary layer. Lower and more variable CCN concentrations within the cloudy boundary layer, especially very close to the clouds, appear to be a result of cloud scavenging processes. Gravitational coagulation of cloud droplets may be the principal cause of this difference in the vertical distribution of CCN. The results suggest a reservoir of CCN in the free troposphere which can act as a source for the marine boundary layer.

  18. Noble gas trapping by laboratory carbon condensates

    NASA Technical Reports Server (NTRS)

    Niemeyer, S.; Marti, K.

    1982-01-01

    Trapping of noble gases by carbon-rich matter was investigated by synthesizing carbon condensates in a noble gas atmosphere. Laser evaporation of a solid carbon target yielded submicron grains which proved to be efficient noble gas trappers (Xe distribution coefficients up to 13 cu cm STP/g-atm). The carbon condensates are better noble gas trappers than previously reported synthetic samples, except one, but coefficients inferred for meteoritic acid-residues are still orders of magnitude higher. The trapped noble gases are loosely bound and elementally strongly fractionated, but isotopic fractionations were not detected. Although this experiment does not simulate nebular conditions, the results support the evidence that carbon-rich phases in meteorites may be carriers of noble gases from early solar system reservoirs. The trapped elemental noble gas fractionations are remarkably similar to both those inferred for meteorites and those of planetary atmospheres for earth, Mars and Venus.

  19. Transonic flow past an airfoil with condensation

    NASA Technical Reports Server (NTRS)

    Schmidt, B.

    1978-01-01

    In connection with investigations conducted to determine the influence of water vapor on experiments in wind tunnels, the question arose as to what changes due to vapor condensation might be expected in airfoil measurements. Density measurements on circular-arc airfoils aided by an interferometer in choked tunnels with parallel walls show that increasing humidity produces increasing changes in the flow field. The flow becomes nonstationary at high humidity. At the airfoil, however, the influence of the condensation is only felt, inasmuch as the shock bounding the local supersonic region moves upstream with increasing humidity while its intensity decreases. The density distribution upstream of the shock remains unchanged. Even if the flow becomes nonstationary in the vicinity of the airfoil, no changes occur at the airfoil.

  20. Coupling a Bose condensate to micromechanical oscillators

    NASA Astrophysics Data System (ADS)

    Kemp, Chandler; Fox, Eli; Flanz, Scott; Vengalattore, Mukund

    2011-05-01

    We describe the construction of a compact apparatus to investigate the interaction of a spinor Bose-Einstein condensate and a micromechanical oscillator. The apparatus uses a double magneto-optical trap, Raman sideband cooling, and evaporative cooling to rapidly produce a 87Rb BEC in close proximity to a high Q membrane. The micromotion of the membrane results in small Zeeman shifts at the location of the BEC due to a magnetic domain attached to the oscillator. Detection of this micromotion by the condensate results in a backaction on the membrane. We investigate prospects of using this backaction to generate nonclassical states of the mechanical oscillator. This work was funded by the DARPA ORCHID program.

  1. Condensation induced water hammer driven sterilization

    DOEpatents

    Kullberg, Craig M.

    2004-05-11

    A method and apparatus (10) for treating a fluid or materials therein with acoustic energy has a vessel (14) for receiving the fluid with inner walls shaped to focus acoustic energy to a target zone within the vessel. One or more nozzles (26) are directed into the vessel (14) for injecting a condensable vapor, such as steam, into the vessel (14). The system may include a steam source (18) for providing steam as the condensable vapor from an industrial waste heat source. Steam drums (88) are disposed between the steam source (18) and nozzles (26) to equalize and distribute the vapor pressure. A cooling source (30) provides a secondary fluid for maintaining the liquid in the vessel (14) in subcooled conditions. A heating jacket (32) surrounds the vessel (14) to heat the walls of the vessel (14) and prevent biological growth thereon. A pressurizer (33) may operate the system at elevated pressures.

  2. Condensing Heat Exchanger with Hydrophilic Antimicrobial Coating

    NASA Technical Reports Server (NTRS)

    Thomas, Christopher M. (Inventor); Ma, Yonghui (Inventor)

    2014-01-01

    A multi-layer antimicrobial hydrophilic coating is applied to a substrate of anodized aluminum, although other materials may form the substrate. A silver layer is sputtered onto a thoroughly clean anodized surface of the aluminum to about 400 nm thickness. A layer of crosslinked, silicon-based macromolecular structure about 10 nm thickness overlies the silver layer, and the outermost surface of the layer of crosslinked, silicon-based macromolecular structure is hydroxide terminated to produce a hydrophilic surface with a water drop contact angle of less than 10.degree.. The coated substrate may be one of multiple fins in a condensing heat exchanger for use in the microgravity of space, which has narrow channels defined between angled fins such that the surface tension of condensed water moves water by capillary flow to a central location where it is pumped to storage. The antimicrobial coating prevents obstruction of the capillary passages.

  3. Hydrogen behavior in ice condenser containments

    SciTech Connect

    Lundstroem, P.; Hongisto, O.; Theofanous, T.G.

    1995-09-01

    A new hydrogen management strategy is being developed for the Loviisa ice condenser containment. The strategy relies on containment-wide natural circulations that develop, once the ice condenser doors are forced open, to effectively produce a well-mixed behavior, and a correspondingly slow rise in hydrogen concentration. Levels can then be kept low by a distributed catalytic recombiner system, and (perhaps) an igniter system as a backup, while the associated energy releases can be effectively dissipated in the ice bed. Verification and fine-tuning of the approach is carried out experimentally in the VICTORIA facility and by associated scaling/modelling studies. VICTORIA represents an 1/15th scale model of the Loviisa containment, hydrogen is simulated by helium, and local concentration measurements are obtained by a newly developed instrument specifically for this purpose, called SPARTA. This paper is focused on experimental results from several key experiments that provide a first delineation of key behaviors.

  4. Geysers advanced direct contact condenser results

    SciTech Connect

    Henderson, J.; Bahning, T.

    1997-12-31

    The world`s first geothermal application of the Advanced Direct Contact Condenser (ADCC) technology developed by the National Renewable Energy Laboratory (NREL) is now operational at The Geysers Power Plant Unit 11. This major research effort was supported through the combined efforts of NREL, The Department of Energy (DOE), and Pacific Gas and Electric (PG&E). The project was the first geothermal adaptation of an advanced condenser design originally demonstrated at the Ocean Thermal Energy Conversion (OTEC) plant in Kona, Hawaii. PG&E expects this technology to improve power plant performance and to help extend the life of the steam field by using steam more efficiently. Successful application of this technology at The Geysers will provide a basis for NREL to continue to develop this technology for other geothermal and fossil power plant systems.

  5. Cosmic rays from cosmic strings with condensates

    SciTech Connect

    Vachaspati, Tanmay

    2010-02-15

    We revisit the production of cosmic rays by cusps on cosmic strings. If a scalar field ('Higgs') has a linear interaction with the string world sheet, such as would occur if there is a bosonic condensate on the string, cusps on string loops emit narrow beams of very high energy Higgses which then decay to give a flux of ultrahigh energy cosmic rays. The ultrahigh energy flux and the gamma to proton ratio agree with observations if the string scale is {approx}10{sup 13} GeV. The diffuse gamma ray and proton fluxes are well below current bounds. Strings that are lighter and have linear interactions with scalars produce an excess of direct and diffuse cosmic rays and are ruled out by observations, while heavier strings ({approx}10{sup 15} GeV) are constrained by their gravitational signatures. This leaves a narrow window of parameter space for the existence of cosmic strings with bosonic condensates.

  6. Bose-Einstein condensation in microgravity.

    PubMed

    van Zoest, T; Gaaloul, N; Singh, Y; Ahlers, H; Herr, W; Seidel, S T; Ertmer, W; Rasel, E; Eckart, M; Kajari, E; Arnold, S; Nandi, G; Schleich, W P; Walser, R; Vogel, A; Sengstock, K; Bongs, K; Lewoczko-Adamczyk, W; Schiemangk, M; Schuldt, T; Peters, A; Könemann, T; Müntinga, H; Lämmerzahl, C; Dittus, H; Steinmetz, T; Hänsch, T W; Reichel, J

    2010-06-18

    Albert Einstein's insight that it is impossible to distinguish a local experiment in a "freely falling elevator" from one in free space led to the development of the theory of general relativity. The wave nature of matter manifests itself in a striking way in Bose-Einstein condensates, where millions of atoms lose their identity and can be described by a single macroscopic wave function. We combine these two topics and report the preparation and observation of a Bose-Einstein condensate during free fall in a 146-meter-tall evacuated drop tower. During the expansion over 1 second, the atoms form a giant coherent matter wave that is delocalized on a millimeter scale, which represents a promising source for matter-wave interferometry to test the universality of free fall with quantum matter. PMID:20558713

  7. Silicotitanate molecular sieve and condensed phases

    DOEpatents

    Nenoff, Tina M.; Nyman, May D.

    2002-01-01

    A new microporous crystalline molecular sieve material having the formula Cs.sub.3 TiSi.sub.3 O.sub.95.cndot.3H.sub.2 O and its hydrothermally condensed phase, Cs.sub.2 TiSi.sub.6 O.sub.15, are disclosed. The microporous material can adsorb divalent ions of radionuclides or other industrial metals such as chromium, nickel, lead, copper, cobalt, zinc, cadmium, barium, and mercury, from aqueous or hydrocarbon solutions. The adsorbed metal ions can be leached out for recovery purposes or the microporous material can be hydrothermally condensed to a radiation resistant, structurally and chemically stable phase which can serve as a storage waste form for radionuclides.

  8. Models for water steam condensing flows

    NASA Astrophysics Data System (ADS)

    Wróblewski, Włodzimierz; Dykas, Sławomir; Chmielniak, Tadeusz

    2012-08-01

    The paper presents a description of selected models dedicated to steam condensing flow modelling. The models are implemented into an in-house computational fluid dynamics code that has been successfully applied to wet steam flow calculation for many years now. All models use the same condensation model that has been validated against the majority of available experimental data. The state equations for vapour and liquid water, the physical model as well as the numerical techniques of solution to flow governing equations have been presented. For the single-fluid model, the Reynolds-averaged Navier-Stokes equations for vapour/liquid mixture are solved, whereas the two-fluid model solves separate flow governing equations for the compressible, viscous and turbulent vapour phase and for the compressible and inviscid liquid phase. All described models have been compared with relation to the flow through the Laval nozzle.

  9. Spin-liquid condensate of spinful bosons.

    PubMed

    Lian, Biao; Zhang, Shoucheng

    2014-08-22

    We introduce the concept of a bosonic spin liquid condensate (SLC), where spinful bosons in a lattice form a zero-temperature spin disordered charge condensate that preserves the spin rotation symmetry, but breaks the U(1) symmetry due to a spinless order parameter with charge one. It has an energy gap to all the spin excitations. We show that such SLC states can be realized in a system of spin S ≥ 2 bosons. In particular, we analyze the SLC phase diagram in the spin 2 case using a mean-field variational wave function method. We show there is a direct analogy between the SLC and the resonating-valence-bond state. PMID:25192078

  10. Condensation in hypersonic nitrogen wind tunnels

    NASA Technical Reports Server (NTRS)

    Lederer, Melissa A.; Yanta, William J.; Ragsdale, William C.; Hudson, Susan T.; Griffith, Wayland C.

    1990-01-01

    Experimental observations and a theoretical model for the onset and disappearance of condensation are given for hypersonic flows of pure nitrogen at M = 10, 14 and 18. Measurements include Pitot pressures, static pressures and laser light scattering experiments. These measurements coupled with a theoretical model indicate a substantial non-equilibrium supercooling of the vapor phase beyond the saturation line. Typical results are presented with implications for the design of hypersonic wind tunnel nozzles.

  11. Condensed matter physicists shrink their horizons.

    PubMed

    Flam, F

    1993-04-01

    In the world of the condensed matter physicist, a micron is a chasm and a millimeter an ocean. At the March American Physical Society meeting in Seattle, some of the 4500 physicists probed the hazards of the micro world, where weird quantum effects can scramble information. Others outlined its opportunities: Molecular engineering that is leading to new information storage materials, and minute structures that could form tethers and containers in some future nanotechnology. PMID:17807173

  12. Spin selective filtering of polariton condensate flow

    SciTech Connect

    Gao, T.; Antón, C.; Martín, M. D.; Liew, T. C. H.; Hatzopoulos, Z.; Viña, L.; Eldridge, P. S.; Savvidis, P. G.

    2015-07-06

    Spin-selective spatial filtering of propagating polariton condensates, using a controllable spin-dependent gating barrier, in a one-dimensional semiconductor microcavity ridge waveguide is reported. A nonresonant laser beam provides the source of propagating polaritons, while a second circularly polarized weak beam imprints a spin dependent potential barrier, which gates the polariton flow and generates polariton spin currents. A complete spin-based control over the blocked and transmitted polaritons is obtained by varying the gate polarization.

  13. Parton Saturation and the Color Glass Condensate

    NASA Astrophysics Data System (ADS)

    Kovchegov, Yuri V.

    2007-03-01

    We review recent developments in the field of parton saturation and the Color Glass Condensate. We discuss the classical gluon fields of McLerran-Venugopalan model. We explain how small- x non-linear quantum evolution corrections can be included into the total cross section for deep inelastic scattering. We proceed by reviewing saturation physics predictions for the particle production in p( d) A collisions and conclude by demonstrating how such predictions were confirmed by the RHIC experiments.

  14. Condensing Hybrid Water Heater Monitoring Field Evaluation

    SciTech Connect

    Maguire, J.; Earle, L.; Booten, C.; Hancock, C. E.

    2011-10-01

    This paper summarizes the Mascot home, an abandoned property that was extensively renovated. Several efficiency upgrades were integrated into this home, of particular interest, a unique water heater (a Navien CR240-A). Field monitoring was performed to determine the in-use efficiency of the hybrid condensing water heater. The results were compared to the unit's rated efficiency. This unit is Energy Star qualified and one of the most efficient gas water heaters currently available on the market.

  15. Schrodinger Leopards in Bose-Einstein Condensates

    NASA Astrophysics Data System (ADS)

    Carr, Lincoln D.; Dounas-Frazer, Dimitri R.

    2008-03-01

    We present the complex quantum dynamics of vortices in Bose-Einstein condensates in a double well via exact diagonalization of a discretized Hamiltonian. When the barrier is high, vortices evolve into macroscopic superposition (NOON) states of a vortex in either well -- a Schrodinger cat with spots. Such Schrodinger leopard states are more robust than previously proposed NOON states, which only use two single particle modes of the double well potential.

  16. Interference and isospin of disoriented chiral condensates

    SciTech Connect

    Suzuki, M.

    1995-09-01

    If coherent states describe the disoriented chiral condensates (DCC`s), many states of different chiral orientations should equally contribute to a given hadronic process. However, in the classical field description, we ignore the interference between the different DCC amplitudes. It results in a disregard of isospin invariance. We examine quantitatively how good this approximation is for the DCC`s of a typical size.

  17. Quantum phenomenology for the disoriented chiral condensate

    SciTech Connect

    Amado, R.D. ); Kogan, I.I. )

    1995-01-01

    We consider the quantum state describing the disoriented chiral condensate (DCC), which may be produced in high energy collisions. We show how a mean field treatment of the quantum equations corresponding to the classical linear [sigma] model leads to a squeezed state description of the pions emerging from the DCC. We examine various squeezed and coherent state descriptions of those pions with particular attention to charge and number fluctuations. We also study the phenomenology of multiple DCC domains.

  18. THE COLOUR GLASS CONDENSATE: AN INTRODUCTION

    SciTech Connect

    IANCU,E.; LEONIDOV,A.; MCLERRAN,L.

    2001-08-06

    In these lectures, the authors develop the theory of the Colour Glass Condensate. This is the matter made of gluons in the high density environment characteristic of deep inelastic scattering or hadron-hadron collisions at very high energy. The lectures are self contained and comprehensive. They start with a phenomenological introduction, develop the theory of classical gluon fields appropriate for the Colour Glass, and end with a derivation and discussion of the renormalization group equations which determine this effective theory.

  19. Diffusion in Condensed Matter: Methods, Materials, Models

    NASA Astrophysics Data System (ADS)

    Heitjans, Paul; Kärger, Jög

    This comprehensive, handbook-style survey of diffusion in condensed matter gives detailed insight into diffusion as the process of particle transport due to stochastic movement. It is understood and presented as a phenomenon of crucial relevance for a large variety of processes and materials. In this book, all aspects of the theoretical fundamentals, experimental techniques, highlights of current developments and results for solids, liquids and interfaces are presented.

  20. Promotion of dropwise condensation of ethyl alcohol, methyl alcohol, and acetone by polytetrafluoroethylene

    NASA Technical Reports Server (NTRS)

    Kirby, C. E.

    1972-01-01

    Coating condensing surfaces with thin layer of nonpolar Teflon results in dropwise condensation of polar organic vapor. Greater heat transfer coefficients are produced increasing effectiveness of condensing system. Investigation shows that vapors with strong dipole moment tend to condense dropwise.

  1. The moon as a high temperature condensate

    NASA Technical Reports Server (NTRS)

    Anderson, D. L.

    1972-01-01

    The accretion during condensation mechanism is used to explain the differences in composition of the terrestrial planets and the moon. Many of the properties of the moon, including the enrichment in Ca, Al, Ti, U, Th, Ba, Sr and the REE and the depletion in Fe, Rb, K, Na and other volatiles can be understood if the moon represents a high temperature condensate from the solar nebula. Thermodynamic calculations show that Ca, Al and Ti rich compounds condense first in a cooling nebula. The high temperature mineralogy is gehlenite, spinel perovskite, Ca-Al-rich pyroxenes and anorthite. The model is consistent with extensive early melting, shallow melting at 3 A.E. and with presently high speed internal temperatures. It is predicted that the outer 250 km is rich in plagioclase and FeO. The low iron content of the interior in this model raises the interior temperatures estimated from electrical conductivity by some 800 C. The lunar crust is 80 percent gabbroic anorthosite, 20 percent basalt and is about 250-270 km thick. The lunar mantle is probably composed of spinel, merwinite and diopside with a density of 3.4 g/cu cm.

  2. Modeling of Bulk Evaporation and Condensation

    NASA Technical Reports Server (NTRS)

    Anghaie, S.; Ding, Z.

    1996-01-01

    This report describes the modeling and mathematical formulation of the bulk evaporation and condensation involved in liquid-vapor phase change processes. An internal energy formulation, for these phase change processes that occur under the constraint of constant volume, was studied. Compared to the enthalpy formulation, the internal energy formulation has a more concise and compact form. The velocity and time scales of the interface movement were obtained through scaling analysis and verified by performing detailed numerical experiments. The convection effect induced by the density change was analyzed and found to be negligible compared to the conduction effect. Two iterative methods for updating the value of the vapor phase fraction, the energy based (E-based) and temperature based (T-based) methods, were investigated. Numerical experiments revealed that for the evaporation and condensation problems the E-based method is superior to the T-based method in terms of computational efficiency. The internal energy formulation and the E-based method were used to compute the bulk evaporation and condensation processes under different conditions. The evolution of the phase change processes was investigated. This work provided a basis for the modeling of thermal performance of multi-phase nuclear fuel elements under variable gravity conditions, in which the buoyancy convection due to gravity effects and internal heating are involved.

  3. The moon as a high temperature condensate.

    NASA Technical Reports Server (NTRS)

    Anderson, D. L.

    1973-01-01

    The accretion during condensation mechanism, if it occurs during the early over-luminous stage of the sun, can explain the differences in composition of the terrestrial planets and the moon. An important factor is the variation of pressure and temperature with distance from the sun, and in the case of the moon and captured satellites of other planets, with distance from the median plane. Current estimates of the temperature and pressure in the solar nebula suggest that condensation will not be complete in the vicinity of the terrestrial planets, and that depending on location, iron, magnesium silicates and the volatiles will be at least partially held in the gaseous phase and subject to separation from the dust by solar wind and magnetic effects associated with the transfer of angular momentum just before the sun joins the Main Sequence. Many of the properties of the moon, including the 'enrichment' in Ca, Al, Ti, U, Th, Ba, Sr and the REE and the 'depletion' in Fe, Rb, K, Na and other volatiles can be understood if the moon represents a high temperature condensate from the solar nebula.

  4. Condensing osteitis of the clavicle in children

    PubMed Central

    Andreacchio, Antonio; Marengo, Lorenza; Canavese, Federico

    2016-01-01

    AIM To confirm the rarity of this disorder and then to evaluate the effects of antibiotic treatment alone and assess whether this could produce a complete remission of symptoms in children and adolescents. METHODS We made a retrospective review of all cases of condensing osteitis of the clavicle in children and adolescents between January 2007 and January 2016. Outpatient and inpatient medical records, with radiographs, magnetic resonance imaging, triphasic bone scan and computed tomography scans were retrospectively reviewed. All the patients underwent biopsy of the affected clavicle and were treated with intra venous (IV) antibiotics followed by oral antibiotics. RESULTS Seven cases of condensing osteitis of the clavicle were identified. All the patients presented with swelling of the medial end of the clavicle, and 5 out of 7 reported persisting pain. The patients’ mean age at presentation was 11.5 years (range 10.5-13). Biopsy confirmed the diagnosis in all cases. All the patients completed the treatment with IV and oral antibiotics. At last follow-up visit none of the patients complained of residual pain; all had a clinically evident reduction in the swelling of the medial end of the affected clavicle. The mean follow-up was 4 years (range 2-7). CONCLUSION Our findings show that condensing osteitis of the clavicle is a rare condition. Biopsy is needed to confirm diagnosis. The condition should be managed with IV and oral antibiotics. Aggressive surgery should be avoided. PMID:27622150

  5. Geysers advanced direct contact condenser research

    SciTech Connect

    Henderson, J.; Bahning, T.; Bharathan, D.

    1997-12-31

    The first geothermal application of the Advanced Direct Contact Condenser (ADCC) technology developed by the National Renewable Energy Laboratory (NREL) is now operational and is being tested at The Geysers Power Plant Unit 11. This major research effort is being supported through the combined efforts of NREL, The Department of Energy (DOE), and Pacific Gas and Electric (PG&E). NREL and PG&E have entered into a Cooperative Research And Development Agreement (CRADA) for a project to improve the direct-contact condenser performance at The Geysers Power Plant. This project is the first geothermal adaptation of an advanced condenser design developed for the Ocean Thermal Energy Conversion (OTEC) systems. PG&E expects this technology to improve power plant performance and to help extend the life of the steam field by using steam more efficiently. In accordance with the CRADA, no money is transferred between the contracting parties. In this case the Department of Energy is funding NREL for their efforts in this project and PG&E is contributing funds in kind. Successful application of this technology at The Geysers will provide a basis for NREL to continue to develop this technology for other geothermal and fossil power plant systems.

  6. Condenser performance recovery in nuclear power plants

    SciTech Connect

    Saxon, G. Jr.; Putman, R.E.

    1996-12-31

    Fouling of the tubes in the main condenser can have a significant impact on nuclear plant performance. Recent experiences suggest that the effects of fouling have been underestimated and that the results of an effective tube cleaning can be measured in improved unit capacity. In particular two nuclear power plants have reported recovery of 20 and 25 MW respectively. While the types of deposition often vary as they did in these two cases, the deposit elements were accurately identified, the deposits` impact on heat transfer was evaluated and an effective cleaning methodology was developed for successful deposit removal. These experiences have prompted the development of a number of diagnostic monitoring and inspection methods which can be utilized in the field or in the laboratory; to detect, identify and quantify the presence of fouling and its impact on heat transfer, to determine the relative effectiveness of a cleaning method and to evaluate condenser performance as related to MW capacity for both single and multiple compartment condensers.

  7. A 'dry' condensation origin for circumstellar carbonates.

    PubMed

    Toppani, Alice; Robert, François; Libourel, Guy; de Donato, Philippe; Barres, Odile; d'Hendecourt, Louis; Ghanbaja, Jaafar

    2005-10-20

    The signature of carbonate minerals has long been suspected in the mid-infrared spectra of various astrophysical environments such as protostars. Abiogenic carbonates are considered as indicators of aqueous mineral alteration in the presence of CO2-rich liquid water. The recent claimed detection of calcite associated with amorphous silicates in two planetary nebulae and protostars devoid of planetary bodies questions the relevance of this indicator; but in the absence of an alternative mode of formation under circumstellar conditions, this detection remains controversial. The main dust component observed in circumstellar envelopes is amorphous silicates, which are thought to have formed by non-equilibrium condensation. Here we report experiments demonstrating that carbonates can be formed with amorphous silicates during the non-equilibrium condensation of a silicate gas in a H2O-CO2-rich vapour. We propose that the observed astrophysical carbonates have condensed in H2O(g)-CO2(g)-rich, high-temperature and high-density regions such as evolved stellar winds, or those induced by grain sputtering upon shocks in protostellar outflows. PMID:16237436

  8. Condensate removal device for heat exchanger

    NASA Technical Reports Server (NTRS)

    Trusch, R. B.; Oconnor, E. W. (Inventor)

    1975-01-01

    A set of perforated tubes disposed at the gas output side of a heat exchanger, in a position not to affect the rate of flow of the air or other gas is described. The tubes are connected to a common manifold which is connected to a sucking device. Where it is necessary to conserve and recirculate the air sucked through the tubes, the output of the manifold is run through a separator to remove the condensate from the gas. The perforations in the slurper tubes are small, lying in the range of 0.010 inch to 0.100 inch. The tubes are disposed in contact with the surfaces of the heat exchanger on which the condensate is precipitated, whether fins or plates, so that the water may be directed to the tube openings by means of surface effects, together with the assistance of the air flow. Only about 5 percent of the air output need be thus diverted, and it effectively removes virtually all of the condensate.

  9. Selective condensation of DNA by aminoglycoside antibiotics.

    PubMed

    Kopaczynska, M; Schulz, A; Fraczkowska, K; Kraszewski, S; Podbielska, H; Fuhrhop, J H

    2016-05-01

    The condensing effect of aminoglycoside antibiotics on the structure of double-stranded DNA was examined. The selective condensation of DNA by small molecules is an interesting approach in biotechnology. Here, we present the interaction between calf thymus DNA and three types of antibiotic molecules: tobramycin, kanamycin, and neomycin. Several techniques were applied to study this effect. Atomic force microscopy, transmission electron microscopy images, and nuclear magnetic resonance spectra showed that the interaction of tobramycin with double-stranded DNA caused the rod, toroid, and sphere formation and very strong condensation of DNA strands, which was not observed in the case of other aminoglycosides used in the experiment. Studies on the mechanisms by which small molecules interact with DNA are important in understanding their functioning in cells, in designing new and efficient drugs, or in minimizing their adverse side effects. Specific interactions between tobramycin and DNA double helix was modeled using molecular dynamics simulations. Simulation study shows the aminoglycoside specificity to bend DNA double helix, shedding light on the origins of toroid formation. This phenomenon may lighten the ototoxicity or nephrotoxicity issues, but also other adverse reactions of aminoglycoside antibiotics in the human body. PMID:26646261

  10. Measuring non-condensable gases in steam

    SciTech Connect

    Doornmalen, J. P. C. M. van; Kopinga, K.

    2013-11-15

    In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1 %) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3M{sup TM} Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation.

  11. Measuring non-condensable gases in steam.

    PubMed

    van Doornmalen, J P C M; Kopinga, K

    2013-11-01

    In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1%) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3M(TM) Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation. PMID:24289436

  12. Measuring non-condensable gases in steam

    NASA Astrophysics Data System (ADS)

    van Doornmalen, J. P. C. M.; Kopinga, K.

    2013-11-01

    In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1 %) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3MTM Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation.

  13. Majorana fermions in condensed-matter physics

    NASA Astrophysics Data System (ADS)

    Leggett, A. J.

    2016-06-01

    It is an honor and a pleasure to have been invited to give a talk in this conference celebrating the memory of the late Professor Abdus Salam. To my regret, I did not know Professor Salam personally, but I am very aware of his work and of his impact on my area of specialization, condensed matter physics, both intellectually through his ideas on spontaneously broken symmetry and more practically through his foundation of the ICTP. Since I assume that most of this audience are not specialized in condensed-matter physics, I thought I would talk about one topic which to some extent bridges this field and the particle-physics interests of Salam, namely Majorana fermions (M.F.s). However, as we shall see, the parallels which are often drawn in the current literature may be a bit too simplistic. I will devote most of this talk to a stripped-down exposition of the current orthodoxy concerning M.F.s. in condensed-matter physics and their possible applications to topological quantum computing (TQC), and then at the end briefly indicate why I believe this orthodoxy may be seriously misleading.

  14. Simulation of Inviscid Compressible Multi-Phase Flow with Condensation

    NASA Technical Reports Server (NTRS)

    Kelleners, Philip

    2003-01-01

    Condensation of vapours in rapid expansions of compressible gases is investigated. In the case of high temperature gradients the condensation will start at conditions well away from thermodynamic equilibrium of the fluid. In those cases homogeneous condensation is dominant over heterogeneous condensation. The present work is concerned with development of a simulation tool for computation of high speed compressible flows with homogeneous condensation. The resulting ow solver should preferably be accurate and robust to be used for simulation of industrial flows in general geometries.

  15. Impurity Crystal in a Bose-Einstein Condensate

    SciTech Connect

    Roberts, David C.; Rica, Sergio

    2009-01-16

    We investigate the behavior of impurity fields immersed in a larger condensate field in various dimensions. We discuss the localization of a single impurity field within a condensate and note the effects of surface energy. We derive the functional form of the attractive condensate-mediated interaction between two impurities. Generalizing the analysis to N impurity fields, we show that within various parameter regimes a crystal of impurity fields can form spontaneously in the condensate. Finally, the system of condensate and crystallized impurity structure is shown to have nonclassical rotational inertia, which is characteristic of superfluidity; i.e., the system can be seen to exhibit supersolid behavior.

  16. Condensate fluctuations of interacting Bose gases within a microcanonical ensemble

    SciTech Connect

    Wang Jianhui; He Jizhou; Ma Yongli

    2011-05-15

    Based on counting statistics and Bogoliubov theory, we present a recurrence relation for the microcanonical partition function for a weakly interacting Bose gas with a finite number of particles in a cubic box. According to this microcanonical partition function, we calculate numerically the distribution function, condensate fraction, and condensate fluctuations for a finite and isolated Bose-Einstein condensate. For ideal and weakly interacting Bose gases, we compare the condensate fluctuations with those in the canonical ensemble. The present approach yields an accurate account of the condensate fluctuations for temperatures close to the critical region. We emphasize that the interactions between excited atoms turn out to be important for moderate temperatures.

  17. Compact heat exchangers for condensation applications: Yesterday, today and tomorrow

    SciTech Connect

    Panchal, C.B.

    1993-07-01

    Compact heat exchangers are being increasingly considered for condensation applications in the process, cryogenic, aerospace, power and refrigeration industries. In this paper, different configurations available for condensation applications are analyzed and the current state-of-the-knowledge for the design of compact condensers is evaluated. The key technical issues for the design and development of compact heat exchangers for condensation applications are analyzed and major advantages are identified. The experimental data and performance prediction methods reported in the literature are analyzed to evaluate the present design capabilities for different compact heat-exchanger configurations. The design flexibility is evaluated for the development of new condensation applications, including integration with other process equipment.

  18. 46. VIEW LOOKING NORTHEAST OF CONDENSER NUMBER 2 (LEFT BACKGROUND) ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    46. VIEW LOOKING NORTHEAST OF CONDENSER NUMBER 2 (LEFT BACKGROUND) AND MOTOR FOR PUMPING CONDENSER HOT WELL (LOWER CENTER OF PHOTOGRAPH). SPENT STEAM EXHAUSTED FROM THE TURBINE WAS CONDENSED BY A SPRAY OF BRACKISH WATER. THIS CREATED A PARTIAL VACUUM WHICH IMPROVED TURBINE EFFICIENCY. THE MIXTURE OF CONDENSED STEAM AND COOL BRACKISH WATER FELL TO THE BOTTOM OF THE CONDENSER INTO A HOT WELL. FROM THE WELL IT WAS PUMPED TO THE MAIN DISCHARGE FLUME. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

  19. Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols

    NASA Astrophysics Data System (ADS)

    Riedel, T. P.; Lin, Y.-H.; Zhang, Z.; Chu, K.; Thornton, J. A.; Vizuete, W.; Gold, A.; Surratt, J. D.

    2015-10-01

    Isomeric epoxydiols from isoprene photooxidation (IEPOX) have been shown to produce substantial amounts of secondary organic aerosol (SOA) mass and are therefore considered a major isoprene-derived SOA precursor. Heterogeneous reactions of IEPOX on atmospheric aerosols form various aerosol-phase components or "tracers" that contribute to the SOA mass burden. A limited number of the reaction rate constants for these acid-catalyzed aqueous-phase tracer formation reactions have been constrained through bulk laboratory measurements. We have designed a chemical box model with multiple experimental constraints to explicitly simulate gas- and aqueous-phase reactions during chamber experiments of SOA growth from IEPOX uptake onto acidic sulfate aerosol. The model is constrained by measurements of the IEPOX reactive uptake coefficient, IEPOX and aerosol chamber wall-losses, chamber-measured aerosol mass and surface area concentrations, aerosol thermodynamic model calculations, and offline filter-based measurements of SOA tracers. By requiring the model output to match the SOA growth and offline filter measurements collected during the chamber experiments, we derive estimates of the tracer formation reaction rate constants that have not yet been measured or estimated for bulk solutions.

  20. Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols

    NASA Astrophysics Data System (ADS)

    Riedel, T. P.; Lin, Y.-H.; Zhang, Z.; Chu, K.; Thornton, J. A.; Vizuete, W.; Gold, A.; Surratt, J. D.

    2016-02-01

    Isomeric epoxydiols from isoprene photooxidation (IEPOX) have been shown to produce substantial amounts of secondary organic aerosol (SOA) mass and are therefore considered a major isoprene-derived SOA precursor. Heterogeneous reactions of IEPOX on atmospheric aerosols form various aerosol-phase components or "tracers" that contribute to the SOA mass burden. A limited number of the reaction rate constants for these acid-catalyzed aqueous-phase tracer formation reactions have been constrained through bulk laboratory measurements. We have designed a chemical box model with multiple experimental constraints to explicitly simulate gas- and aqueous-phase reactions during chamber experiments of SOA growth from IEPOX uptake onto acidic sulfate aerosol. The model is constrained by measurements of the IEPOX reactive uptake coefficient, IEPOX and aerosol chamber wall losses, chamber-measured aerosol mass and surface area concentrations, aerosol thermodynamic model calculations, and offline filter-based measurements of SOA tracers. By requiring the model output to match the SOA growth and offline filter measurements collected during the chamber experiments, we derive estimates of the tracer formation reaction rate constants that have not yet been measured or estimated for bulk solutions.

  1. Inflationary buildup of a vector field condensate and its cosmological consequences

    SciTech Connect

    Sanchez, Juan C. Bueno; Dimopoulos, Konstantinos E-mail: k.dimopoulos1@lancaster.ac.uk

    2014-01-01

    Light vector fields during inflation obtain a superhorizon perturbation spectrum when their conformal invariance is appropriately broken. Such perturbations, by means of some suitable mechanism (e.g. the vector curvaton mechanism), can contribute to the curvatue perturbation in the Universe and produce characteristic signals, such as statistical anisotropy, on the microwave sky, most recently surveyed by the Planck satellite mission. The magnitude of such characteristic features crucially depends on the magnitude of the vector condensate generated during inflation. However, in the vast majority of the literature the expectation value of this condensate has so-far been taken as a free parameter, lacking a definite prediction or a physically motivated estimate. In this paper, we study the stochastic evolution of the vector condensate and obtain an estimate for its magnitude. Our study is mainly focused in the supergravity inspired case when the kinetic function and mass of the vector boson is time-varying during inflation, but other cases are also explored such as a parity violating axial theory or a non-minimal coupling between the vector field and gravity. As an example, we apply our findings in the context of the vector curvaton mechanism and contrast our results with current observations.

  2. Reservoir interactions of a vortex in a trapped three-dimensional Bose-Einstein condensate

    NASA Astrophysics Data System (ADS)

    Rooney, S. J.; Allen, A. J.; Zülicke, U.; Proukakis, N. P.; Bradley, A. S.

    2016-06-01

    We simulate the dissipative evolution of a vortex in a trapped finite-temperature dilute-gas Bose-Einstein condensate using first-principles open-systems theory. Simulations of the complete stochastic projected Gross-Pitaevskii equation for a partially condensed Bose gas containing a single quantum vortex show that the transfer of condensate energy to the incoherent thermal component without population transfer provides an important channel for vortex decay. For the lower temperatures considered, this effect is significantly larger that the population transfer process underpinning the standard theory of vortex decay, and is the dominant determinant of the vortex lifetime. A comparison with the Zaremba-Nikuni-Griffin kinetic (two-fluid) theory further elucidates the role of the particle transfer interaction, and suggests the need for experimental testing of reservoir interaction theory. The dominance of this particular energetic decay mechanism for this open quantum system should be testable with current experimental setups, and its observation would have broad implications for the dynamics of atomic matter waves and experimental studies of dissipative phenomena.

  3. Kinetics of small particle activation in supersaturated vapors

    SciTech Connect

    McGraw, R.; Wang, J.

    2010-08-29

    We examine the nucleated (with barrier) activation of perfectly wetting (zero contact angle) particles ranging from bulk size down to one nanometer. Thermodynamic properties of the particles, coated with liquid layers of varying thickness and surrounded by vapor, are analyzed. Nano-size particles are predicted to activate at relative humidity below the Kelvin curve on crossing a nucleation barrier, located at a critical liquid layer thickness such that the total particle size (core + liquid layer) equals the Kelvin radius (Fig. 1). This barrier vanishes precisely as the critical layer thickness approaches the thin layer limit and the Kelvin radius equals the radius of the particle itself. These considerations are similar to those included in Fletcher's theory (Fletcher, 1958) however the present analysis differs in several important respects. Firstly, where Fletcher used the classical prefactor-exponent form for the nucleation rate, requiring separate estimation of the kinetic prefactor, we solve a diffusion-drift equation that is equivalent to including the full Becker-Doering (BD) multi-state kinetics of condensation/evaporation along the growth coordinate. We also determine the mean first passage time (MFPT) for barrier crossing (Wedekind et al., 2007), which is shown to provide a generalization of BD nucleation kinetics especially useful for barrier heights that are considerably lower than those typically encountered in homogeneous vapor-liquid nucleation, and make explicit comparisons between the MFPT and BD kinetic models. Barrier heights for heterogeneous nucleation are computed by a thermo-dynamic area construction introduced recently to model deliquescence and efflorescence of small particles (McGraw and Lewis, 2009). In addition to providing a graphical representation of the activation process that offers new insights, the area construction provides a molecular approach that avoids explicit use of the interfacial tension. Typical barrier profiles for

  4. Formation Mechanism of Fe Nanocubes by Magnetron Sputtering Inert Gas Condensation.

    PubMed

    Zhao, Junlei; Baibuz, Ekaterina; Vernieres, Jerome; Grammatikopoulos, Panagiotis; Jansson, Ville; Nagel, Morten; Steinhauer, Stephan; Sowwan, Mukhles; Kuronen, Antti; Nordlund, Kai; Djurabekova, Flyura

    2016-04-26

    In this work, we study the formation mechanisms of iron nanoparticles (Fe NPs) grown by magnetron sputtering inert gas condensation and emphasize the decisive kinetics effects that give rise specifically to cubic morphologies. Our experimental results, as well as computer simulations carried out by two different methods, indicate that the cubic shape of Fe NPs is explained by basic differences in the kinetic growth modes of {100} and {110} surfaces rather than surface formation energetics. Both our experimental and theoretical investigations show that the final shape is defined by the combination of the condensation temperature and the rate of atomic deposition onto the growing nanocluster. We, thus, construct a comprehensive deposition rate-temperature diagram of Fe NP shapes and develop an analytical model that predicts the temporal evolution of these properties. Combining the shape diagram and the analytical model, morphological control of Fe NPs during formation is feasible; as such, our method proposes a roadmap for experimentalists to engineer NPs of desired shapes for targeted applications. PMID:26962973

  5. Kinetic tetrazolium microtiter assay

    NASA Technical Reports Server (NTRS)

    Pierson, Duane L. (Inventor); Stowe, Raymond P. (Inventor); Koeing, David W. (Inventor)

    1992-01-01

    A method for conducting an in vitro cell assay using a tetrazolium indicator is disclosed. The indicator includes a nonionic detergent which solubilizes a tetrazolium reduction product in vitro and has low toxicity for the cells. The incubation of test cells in the presence of zolium bromide and octoxynol (TRITON X-100) permits kinetics of the cell metabolism to be determined.

  6. Kinetics and Catalysis Demonstrations.

    ERIC Educational Resources Information Center

    Falconer, John L.; Britten, Jerald A.

    1984-01-01

    Eleven videotaped kinetics and catalysis demonstrations are described. Demonstrations include the clock reaction, oscillating reaction, hydrogen oxidation in air, hydrogen-oxygen explosion, acid-base properties of solids, high- and low-temperature zeolite reactivity, copper catalysis of ammonia oxidation and sodium peroxide decomposition, ammonia…

  7. A Local Condensation Analysis Representing Two-phase Annular Flow in Condenser/radiator Capillary Tubes

    NASA Technical Reports Server (NTRS)

    Karimi, Amir

    1991-01-01

    NASA's effort for the thermal environmental control of the Space Station Freedom is directed towards the design, analysis, and development of an Active Thermal Control System (ATCS). A two phase, flow through condenser/radiator concept was baselined, as a part of the ATCS, for the radiation of space station thermal load into space. The proposed condenser rejects heat through direct condensation of ATCS working fluid (ammonia) in the small diameter radiator tubes. Analysis of the condensation process and design of condenser tubes are based on the available two phase flow models for the prediction of flow regimes, heat transfer, and pressure drops. The prediction formulas use the existing empirical relationships of friction factor at gas-liquid interface. An attempt is made to study the stability of interfacial waves in two phase annular flow. The formulation is presented of a stability problem in cylindrical coordinates. The contribution of fluid viscosity, surface tension, and transverse radius of curvature to the interfacial surface is included. A solution is obtained for Kelvin-Helmholtz instability problem which can be used to determine the critical and most dangerous wavelengths for interfacial waves.

  8. A macrothermodynamic approach to the limit of reversible capillary condensation.

    PubMed

    Trens, Philippe; Tanchoux, Nathalie; Galarneau, Anne; Brunel, Daniel; Fubini, Bice; Garrone, Edoardo; Fajula, François; Di Renzo, Francesco

    2005-08-30

    The threshold of reversible capillary condensation is a well-defined thermodynamic property, as evidenced by corresponding states treatment of literature and experimental data on the lowest closure point of the hysteresis loop in capillary condensation-evaporation cycles for several adsorbates. The nonhysteretical filling of small mesopores presents the properties of a first-order phase transition, confirming that the limit of condensation reversibility does not coincide with the pore critical point. The enthalpy of reversible capillary condensation can be calculated by a Clausius-Clapeyron approach and is consistently larger than the condensation heat in unconfined conditions. Calorimetric data on the capillary condensation of tert-butyl alcohol in MCM-41 silica confirm a 20% increase of condensation heat in small mesopores. This enthalpic advantage makes easier the overcoming of the adhesion forces by the capillary forces and justifies the disappearing of the hysteresis loop. PMID:16114972

  9. Multidimensional reactor kinetics modeling

    SciTech Connect

    Diamond, D.J.

    1996-11-01

    There is general agreement that for many light water reactor transient calculations, it is-necessary to use a multidimensional neutron kinetics model coupled to a thermal-hydraulics model for satisfactory results. These calculations are needed for a variety of applications for licensing safety analysis, probabilistic risk assessment (PRA), operational support, and training. The latter three applications have always required best-estimate models, but in the past applications for licensing could be satisfied with relatively simple models. By using more sophisticated best-estimate models, the consequences of these calculations are better understood, and the potential for gaining relief from restrictive operating limits increases. Hence, for all of the aforementioned applications, it is important to have the ability to do best-estimate calculations with multidimensional neutron kinetics models. coupled to sophisticated thermal-hydraulic models. Specifically, this paper reviews the status of multidimensional neutron kinetics modeling which would be used in conjunction with thermal-hydraulic models to do core dynamics calculations, either coupled to a complete NSSS representation or in isolation. In addition, the paper makes recommendations as to what should be the state-of-the-art for the next ten years. The review is an update to a previous review of the status as of ten years ago. The general requirements for a core dynamics code and the modeling available for such a code, discussed in that review, are still applicable. The emphasis in the current review is on the neutron kinetics assuming that the necessary thermal-hydraulic capability exists. In addition to discussing the basic neutron kinetics, discussion is given of related modeling (other than thermal- hydraulics). The capabilities and limitations of current computer codes are presented to understand the state-of-the-art and to help clarify the future direction of model development in this area.

  10. Flue gases conditioning in gas-fired condensing boilers to avoid water vapor condensing in flue ducts

    SciTech Connect

    Rosa, L.; Tosato, R.

    1984-08-01

    This paper presents experimental results of a new gas-fired condensing boiler designed for domestic applications (output 23 kW). It is an advanced boiler based on a light weight cast-iron heat exchanger with low water content. Return water, coming from hot water plant, first flows through an additional heat exchanger (condenser) before entering the main zone of the boiler. Two solutions are suggested in order to reduce or avoid the condensing problems on the flue surfaces, either by mixing flue gases exiting the condenser with new pre-heated air, or, by mixing them with hot flue gases by-passing the condenser.

  11. Learning Chemical Kinetics with Spreadsheets.

    ERIC Educational Resources Information Center

    Blickensderfer, Roger

    1990-01-01

    Presented are several simple kinetic systems together with the spreadsheets used to solve them. A set of exercises in chemical kinetics appropriate for an introductory course in physical chemistry is given. Error propagation calculations with experimental data are illustrated. (CW)

  12. How fast do hydrocarbons condense in Titan's atmosphere? Insights from the laboratory

    NASA Astrophysics Data System (ADS)

    Biennier, L.; Bourgalais, J.; Capron, M.; Roussel, V.; Le Picard, S. D.

    2014-04-01

    Titan's dense atmosphere shows a complex photochemistry initiated by the dissociation of its two most abundant components, nitrogen N2 and methane CH4. This cold chemistry generates a plethora of hydrocarbons and nitriles and takes part in the production of a thick haze. According to a recent scenario constructed from Cassini-Huygens measurements, the chemical reactions and physical processes occurring at high altitudes near 1000 km could be the haze source [1]. This haze material could act as a nucleus for the condensation of organic vapors in Titan's stratosphere and troposphere. However, the pathways leading to the formation and growth of haze aerosols remain far to be well understood. Hydrocarbons, which are formed in Titan's cold atmosphere, starting with ethane C2H6, ethylene C2H4, acetylene C2H2, propane C3H8… up to benzene C6H6, play also some active role in aerosol production, cloud processes, rain generation and Titan's lakes formation. Our goal is to study in the laboratory the kinetics of the first steps of condensation of these hydrocarbon molecules. Several studies have investigated the phase of e.g. ethane and propane and their spectral signatures. At the exception of our recent studies on the dimerization of pyrene C16H10 [2] and anthracene C14H10 [3] performed over the 50-300 K temperature range, there is however no other work on the first elementary steps of the kinetics of nucleation for hydrocarbons. Here we present the first experimental kinetics study of the dimerization of a small hydrocarbon: propane C3H8. We have performed experiments to identify the temperature range over which small propane clusters form in saturated uniform supersonic flows. Using our unique reactor based on a Laval nozzle [4], the kinetics of the formation has also been investigated over the 15-300 K temperature range. The chemical species present in the reactor are probed by a time of flight mass spectrometer equipped with an electron gun for soft ionization of the

  13. LLNL Chemical Kinetics Modeling Group

    SciTech Connect

    Pitz, W J; Westbrook, C K; Mehl, M; Herbinet, O; Curran, H J; Silke, E J

    2008-09-24

    The LLNL chemical kinetics modeling group has been responsible for much progress in the development of chemical kinetic models for practical fuels. The group began its work in the early 1970s, developing chemical kinetic models for methane, ethane, ethanol and halogenated inhibitors. Most recently, it has been developing chemical kinetic models for large n-alkanes, cycloalkanes, hexenes, and large methyl esters. These component models are needed to represent gasoline, diesel, jet, and oil-sand-derived fuels.

  14. Thermodynamic and kinetic theory of nucleation, deliquescence and efflorescence transitions in the ensemble of droplets on soluble particles.

    PubMed

    Shchekin, Alexander K; Shabaev, Ilya V; Hellmuth, Olaf

    2013-02-01

    Thermodynamic and kinetic peculiarities of nucleation, deliquescence and efflorescence transitions in the ensemble of droplets formed on soluble condensation nuclei from a solvent vapor have been considered. The interplay of the effects of solubility and the size of condensation nuclei has been analyzed. Activation barriers for the deliquescence and phase transitions and for the reverse efflorescence transition have been determined as functions of the relative humidity of the vapor-gas atmosphere, initial size, and solubility of condensation nuclei. It has been demonstrated that, upon variations in the relative humidity of the atmosphere, the crossover in thermodynamically stable and unstable variables of the droplet state takes place. The physical meaning of stable and unstable variables has been clarified. The kinetic equations for establishing equilibrium and steady distributions of binary droplets have been solved. The specific times for relaxation, deliquescence and efflorescence transitions have been calculated. PMID:23406138

  15. An Introductory Level Kinetics Investigation.

    ERIC Educational Resources Information Center

    McGarvey, J. E. B.; Knipe, A. C.

    1980-01-01

    Provides a list of the reactions commonly used for introductory kinetics studies. These reactions illustrate the kinetics concepts of rate law, rate constant, and reaction order. Describes a kinetic study of the hydrolysis of 3-bromo-3-phenylpropanoic acid which offers many educational advantages. (CS)

  16. Evolutionary games of condensates in driven and dissipative bosonic systems

    NASA Astrophysics Data System (ADS)

    Knebel, Johannes; Weber, Markus F.; Krüger, Torben; Frey, Erwin

    2015-03-01

    Condensation is a collective behavior of particles observed in both classical and quantum physics. For example, when an equilibrated, dilute gas of bosonic particles is cooled to a temperature near absolute zero, the ground state becomes macroscopically occupied (Bose-Einstein condensation). Whether novel condensation phenomena occur far from equilibrium is a topic of vivid research. Only recently has it been proposed that a driven and dissipative gas of bosons can condense not only into a single, but also into multiple non-degenerate states. This phenomenon may occur when a system of non-interacting bosons is weakly coupled to a reservoir and is driven by an external time-periodic force (Floquet system). Coherence becomes negligible and the condensation is described by a Pauli master equation, which also arises in the evolutionary dynamics of classical agents. In our work, we apply concepts from evolutionary dynamics to determine the states that become condensates. This condensate selection is guided by the vanishing of relative entropy production. We find that the system of condensates never comes to rest: The occupation numbers of condensates oscillate, which we demonstrate for a rock-paper-scissors game of condensates. Deutsche Forschungsgemeinschaft (SFB-TR12), German Excellence Initiative (Nanosystems Initiative Munich), Center for NanoScience Munich, Studienstiftung des Deutschen Volkes.

  17. Bose-Einstein Condensation in Extended Microgravity

    NASA Astrophysics Data System (ADS)

    Scharringhausen, Marco; Quantus Team; Rasel, Ernst Maria

    2012-07-01

    The setup and the envisaged experiment timeline of the QUANTUS-III experiment onboard a sounding rocket to be started in the near future are presented. The major intention of QUANTUS-III is the stable generation of a number of Bose-Einstein condensates as a source for atom interferometry during several minutes of microgravity onboard the sounding rocket. Later missions aim at the realization of atom interferoemeters as precursor satellite missions. These condesates will be generated serially, allowing a large number of repeatable tests. Within such Bose-Einstein condensates, millions of atoms lose their identity and can be described by a single macroscopic wave function. During the expansion over several seconds, the atoms form a giant coherent matter wave that is delocalized on a millimeter scale, which represents a promising source for matter-wave interferometry to test the universality of free fall with quantum matter. Cold quantum gases and, in particular, Bose-Einstein condensates represent a new state of matter which is nowadays established in many laboratories. They offer unique insights into a broad range of fundamental physics as well as prospects for novel quantum sensors. Microgravity will substantially extend the science of quantum gases towards nowadays inaccessible regimes at lowest temperatures, to macroscopic dimensions, and to unequalled durations of unperturbed evolution of these distinguished quantum objects. Right now, the QUANTUS-III experiment is in the development phase, taking heritage from QUANTUS-I and QUANTUS-II. Major components of the engineering model are available. Boundary conditions of the rocket, requirements of the experiment and interface considerations are presented. This include laser stabilization, vacuum technology and magnetic shielding. The planned trajectory of the rocket will have an apogee of 200 - 300 km and a total microgravity time of 4 - 7 minutes, both depending on the total experiment mass.

  18. Condensation on Aerosol Particles and its Inhibition.

    NASA Astrophysics Data System (ADS)

    Liu, Peter Shen King

    The atmospheric aerosol is of primary importance in the formation of precipitation. Except in the neighbourhood of large sources of pollution most of the atmospheric particles are of natural origin, but human contribution is increasing at such a rate that within a comparatively short time it may equal nature's. Such an increase in the atmospheric particulate load may have significant effects on the distribution and intensity of precipitation. There is a general perception that most of the atmospheric particulate load is soluble in water or has some soluble component and soluble particles condense water more readily than insoluble. In this work a study is made of the solubility of the atmospheric aerosol at various relative humidities. The results confirm that much of the atmospheric aerosol is indeed soluble, but that the soluble proportion is highly variable. This result has significant implications for studies of air pollution in which the respirable fraction of the atmospheric aerosol is deduced from the results of long term dichotomous sampling. Results are also presented of studies in which an attempt was made to inhibit the condensation of water on man-made and adventitious particles with a view to modifying their possible climatic effects. This work has demonstrated that certain agents, notably long chain amines, do indeed have an inhibiting effect on the condensation of water on particles which have been exposed to them, but that the effect of the agents so far tested is not sufficiently great to be of immediate practical importance. It is concluded that further advances must await more precise methods of producing small supersaturations reliably and reproducibly.

  19. Condensing the Moon from a MAD Earth

    NASA Astrophysics Data System (ADS)

    Lock, S. J.; Stewart, S. T.; Petaev, M. I.; Leinhardt, Z. M.; Mace, M.; Jacobsen, S. B.; Cuk, M.

    2015-12-01

    The favored theory for lunar origin is the giant impact hypothesis, where a protoplanet collides with the growing Earth and creates an orbiting disk of material that forms the Moon. However, the astonishing isotopic similarity between the Earth and Moon cannot be explained by current giant impact models without appealing to highly specific circumstances. Here, we demonstrate that a condensation model for lunar origin, achieved via a previously unrecognized class of post-impact states, produces the Moon's major characteristics. The required class of post-impact states is defined by (i) a high degree of vaporization and (ii) rapid rotation. When these two criteria are met, the mantle, atmosphere and disk (MAD) form a dynamically and thermodynamically continuous structure that quickly mixes, thereby diluting initial compositional heterogeneities. Then, partial condensation from the pressure-supported mass beyond the Roche limit produces a Moon that is isotopically similar to the bulk silicate Earth and depleted in volatile and moderately volatile elements. Initially, the condensed liquid is composed of silicates. As the structure cools, metal exsolves in the accreting Moon and moonlets. We calculate ~2wt% metal is exsolved from a bulk silicate Earth composition, which is consistent with estimates of the mass of the lunar core. Thus, similar tungsten isotopes are established in the Earth and Moon as metal is exsolved in both bodies after mixing. In our model, the criterion for lunar origin shifts, away from specific impact parameters that inject terrestrial material into orbit, to any collision that transforms the Earth into a rapidly rotating and substantially vaporized MAD planet. Impacts that can transform the Earth are common during the end stages of planet formation. Therefore, the characteristics of our Moon are a natural consequence of forming the Earth.

  20. Condensation on nanorods by molecular dynamics

    NASA Astrophysics Data System (ADS)

    Suh, Donguk; Yasuoka, Kenji

    2016-06-01

    Many recent experimental studies have been conducted on constructing nanorods and nanowires to use in a wide range of applications. In this study, molecular dynamics is used to directly examine the condensation rate of nanorods and the results are compared with other basic configurations such as cubes or spheres. According to previous studies conducted by Suh and Yasuoka [J. Phys. Chem. B 115, 10631 (2011); 116, 14637 (2012)], a simple change in the configuration of the seed produces a shape effect, where the curvature of the solid seed surface directly affects the growth generating an orderly difference depending on the curvature. Nanoscale cuboids or nanorods were studied to find an aspect ratio effect when condensation occurs on the surface. Various aspect ratios were examined for different nanorod sizes over a wide range of supersaturation ratios. The results show that the growth rate of the nanorod is independent of the supersaturation ratio, which was also observed for the sphere and cube. The growth rate for the rod fell between those of the cube and the sphere, and this is due to an increase in the surface area of the nanorod compared to the cube and curvature effect in comparison with the sphere. A clear size dependence of the seed was observed, which is also similar to the cube and sphere. Furthermore, no aspect ratio influence was seen for the growth rate. This does not mean that the actual amount of condensation is the same for longer seeds, but rather from the definition of the growth rate, the amount of accumulation per unit area is the same for all seed lengths.

  1. Kinetic Tetrazolium Microtiter Assay

    NASA Technical Reports Server (NTRS)

    Pierson, Duane L.; Stowe, Raymond; Koenig, David

    1993-01-01

    Kinetic tetrazolium microtiter assay (KTMA) involves use of tetrazolium salts and Triton X-100 (or equivalent), nontoxic, in vitro color developer solubilizing colored metabolite formazan without injuring or killing metabolizing cells. Provides for continuous measurement of metabolism and makes possible to determine rate of action of antimicrobial agent in real time as well as determines effective inhibitory concentrations. Used to monitor growth after addition of stimulatory compounds. Provides for kinetic determination of efficacy of biocide, greatly increasing reliability and precision of results. Also used to determine relative effectiveness of antimicrobial agent as function of time. Capability of generating results on day of test extremely important in treatment of water and waste, disinfection of hospital rooms, and in pharmaceutical, agricultural, and food-processing industries. Assay also used in many aspects of cell biology.

  2. Precipitating Condensation Clouds in Substellar Atmospheres

    NASA Technical Reports Server (NTRS)

    Ackerman, Andrew S.; Marley, Mark S.; Gore, Warren J. (Technical Monitor)

    2000-01-01

    We present a method to calculate vertical profiles of particle size distributions in condensation clouds of giant planets and brown dwarfs. The method assumes a balance between turbulent diffusion and precipitation in horizontally uniform cloud decks. Calculations for the Jovian ammonia cloud are compared with previous methods. An adjustable parameter describing the efficiency of precipitation allows the new model to span the range of predictions from previous models. Calculations for the Jovian ammonia cloud are found to be consistent with observational constraints. Example calculations are provided for water, silicate, and iron clouds on brown dwarfs and on a cool extrasolar giant planet.

  3. Condensate Accretion in Shock Tube's Expansion Fan

    NASA Technical Reports Server (NTRS)

    Mezonlin, Ephrem-Denis; DeSilva, Upul P.; Hunte, F.; Johnson, Joseph A., III

    1997-01-01

    It has been shown that turbulence and temperature influence the droplet sizes in expansion fan induced condensation by studying the Rayleigh scattering from one port in our shock tube's test section. We have modified our set-up so as to allow, using two ports, the real time measurement of the influence of turbulence and temperature on the rate at which these droplets grow. To do this, we looked at the Rayleigh scattering from two different ports for ten Reynolds numbers at five different temperatures. We modeled the time of flight of droplets, using the equations of one-dimensional gas dynamics and the measured shock wave speed in shock tube's driven section.

  4. Condensation Of Volatile Contaminant In An Instrument

    NASA Technical Reports Server (NTRS)

    Hansen, Patricia A.; Jenkins, Teresa K.; Maag, Carl R.; Taylor, Daniel M.

    1992-01-01

    Report describes investigation of deposition of contaminant of cooled optical detectors in Wide-Field/Planetary Camera (WF/PC), an instrument in Hubble Space Telescope. To understand phenomenon, initially thought to be deposition of water from graphite/epoxy optical-bench material in instrument, researchers mounted several diagnostic instruments on access plate to monitor interior of WF/PC housing and optical bench. Temperature-controlled quartz-crystal microbalance (TQCM) measures adsorbed and desorbed volatile condensible material on surfaces in WF/PC.

  5. A beam condenser for infrared spectrophotometers.

    PubMed

    Brandt, R C

    1969-02-01

    The design and performance of a beam condenser for ir spectrophotometers such as the Beckman model IR-11 is described. The instrument has an image size of 4 mm x 8 mm and permits the use of samples mounted in the tail of a cryostat whose outside dimension is as large as 7 cm square. Applications to negative light flux spectroscopy are described, in particular, the direct measurement of the longitudinal optical frequency of lattice vibration for AgBr and AgCl. PMID:20072220

  6. Solitonic axion condensates modeling dark matter halos

    NASA Astrophysics Data System (ADS)

    Castañeda Valle, David; Mielke, Eckehard W.

    2013-09-01

    Instead of fluid type dark matter (DM), axion-like scalar fields with a periodic self-interaction or some truncations of it are analyzed as a model of galaxy halos. It is probed if such cold Bose-Einstein type condensates could provide a viable soliton type interpretation of the DM 'bullets' observed by means of gravitational lensing in merging galaxy clusters. We study solitary waves for two self-interacting potentials in the relativistic Klein-Gordon equation, mainly in lower dimensions, and visualize the approximately shape-invariant collisions of two 'lump' type solitons.

  7. HADRONIC SCATTERING IN THE COLOR GLASS CONDENSATE.

    SciTech Connect

    VENUGOPALAN, R.

    2005-05-15

    Multi-particle production in QCD is dominated by higher twist contributions. The operator product expansion is not very effective here because the number of relevant operators grow rapidly with increasing twist. The Color Glass Condensate (CGC) provides a framework in QCD to systematically discuss ''classical'' (multiple scattering) and ''quantum'' evolution (shadowing) effects in multi-particle production. The apparently insuperable problem of nucleus-nucleus scattering in QCD simplifies greatly in the CGC. A few examples are discussed with emphasis on open problems.

  8. System Study: Isolation Condenser 1998-2014

    SciTech Connect

    Schroeder, John Alton

    2015-12-01

    This report presents an unreliability evaluation of the isolation condenser (ISO) system at four U.S. boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2014 for selected components were obtained from the Institute of Nuclear Power Operations (INPO) Consolidated Events Database (ICES). The unreliability results are trended for the most recent 10 year period, while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing trends were identified. A statistically significant decreasing trend was identified for ISO unreliability. The magnitude of the trend indicated a 1.5 percent decrease in system unreliability over the last 10 years.

  9. Resonant gas oscillation with evaporation and condensation

    NASA Astrophysics Data System (ADS)

    Inaba, Masashi; Yano, Takeru; Watanabe, Masao; Kobayashi, Kazumichi; Fujikawa, Shigeo

    2012-09-01

    Resonant gas oscillation in a closed tube bounded by an oscillating plate and a vaporliquid interface is theoretically analyzed by applying the asymptotic theory to the ES-BGK Boltzmann equation for the case of M2≃Kn≪1 and a small evaporation coefficient α = O(Kn), where M and Kn are the typical Mach number and the Knudsen number, respectively. As a result, we derive a nonlinear integro-differential equation for determining the wave profile with the evaporation and condensation in the form including α.

  10. Condensate Recycling in Closed Plant Growth Chambers

    NASA Technical Reports Server (NTRS)

    Bledsoe, J. O.; Sager, J. C.; Fortson, R. E.

    1994-01-01

    Water used in the the Controlled Ecological Life Support System (CELSS) Breadboard Project at the Kennedy Space Center is being recycled. Condensation is collected in the air ducts, filtered and deionized, and resupplied to the system for nutrient solutions, supplemental humidification, solvents and diluents. While the system functions well from a process control standpoint, precise and accurate tracking of water movement through the system to answer plant physiological questions is not consistent. Possible causes include hardware errors, undetected vapor loss from chamber leakage, and unmeasured changes in water volume in the plant growth trays.

  11. Guide to a condensed form of NASTRAN

    NASA Technical Reports Server (NTRS)

    Rogers, J. L., Jr.

    1978-01-01

    A limited capability form of NASTRAN level 16 is presented to meet the needs of universities and small consulting firms. The input cards, the programming language of the direct matrix abstraction program, the plotting, the problem definition, and the modules' diagnostic messages are described. Sample problems relating to the analysis of linear static, vibration, and buckling are included. This guide can serve as a handbook for instructional courses in the use of NASTRAN or for users who need only the capability provided by the condensed form.

  12. System Study: Isolation Condenser 1998–2013

    SciTech Connect

    Schroeder, John Alton

    2015-01-31

    This report presents an unreliability evaluation of the isolation condenser (ISO) system at four U.S. boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2013 for selected components were obtained from the Institute of Nuclear Power Operations (INPO) Consolidated Events Database (ICES). The unreliability results are trended for the most recent 10-year period, while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the ISO results.

  13. Potentially Prebiotic Syntheses of Condensed Phosphates

    NASA Technical Reports Server (NTRS)

    Keefe, Anthony D.; Miller, Stanley L.

    1996-01-01

    In view of the importance of a prebiotic source of high energy phosphates, we have investigated a number of potentially prebiotic processes to produce condensed phosphates from orthophosphate and cyclic trimetaphosphate from tripolyphosphate. The reagents investigated include polymerizing nitriles, acid anhydrides, lactones, hexamethylene tetramine and carbon suboxide. A number of these processes give substantial yields of pyrophosphate from orthophosphate and trimetaphosphate from tripolyphosphate. Although these reactions may have been applicable in local areas, they are not sufficiently robust to have been of importance in the prebiotic open ocean.

  14. Disoriented chiral condensate: Theory and phenomenology

    SciTech Connect

    Bjorken, J.D.

    1997-12-01

    These notes are an abbreviated version of lectures given at the 1997 Zakopane School. They contain two topics. The first is a description in elementary terms of the basic ideas underlying the speculative hypothesis that pieces of strong-interaction vacuum with a rotated chiral order parameter, disoriented chiral condensate or DCC, might be produced in high energy elementary particle collisions. The second topic is a discussion of the phenomenological techniques which may be applied to data in order to experimentally search for the existence of DCC.

  15. Topologically nontrivial time-dependent chiral condensates

    SciTech Connect

    Suzuki, M.

    1996-11-01

    Topologically nontrivial time-dependent solutions of the classical nonlinear {sigma} model are studied as candidates of the disoriented chiral condensate (DCC) in 3+1 dimensions. Unlike the analytic solutions so far discussed, these solutions cannot be transformed into isospin-uniform ones by chiral rotations. If they are produced as DCC{close_quote}s, they can be detected by a distinct pattern in the angle-rapidity distribution of the neutral-to-charged pion ratio. {copyright} {ital 1996 The American Physical Society.}

  16. Glassy dynamics in condensed isolated polymer chains.

    PubMed

    Tress, Martin; Mapesa, Emmanuel U; Kossack, Wilhelm; Kipnusu, Wycliffe K; Reiche, Manfred; Kremer, Friedrich

    2013-09-20

    In the course of miniaturization down to the nanometer scale, much remains unknown concerning how and to what extent the properties of materials are changed. To learn more about the dynamics of condensed isolated polymer chains, we used broadband dielectric spectroscopy and a capacitor with nanostructured electrodes separated by 35 nanometers. We measured the dynamic glass transition of poly(2-vinylpyridine) and found it to be bulk-like; only segments closer than 0.5 nanometer to the substrate were weakly slowed. Our approach paves the way for numerous experiments on the dynamics of isolated molecules. PMID:24052303

  17. Rapid mixing kinetic techniques.

    PubMed

    Martin, Stephen R; Schilstra, Maria J

    2013-01-01

    Almost all of the elementary steps in a biochemical reaction scheme are either unimolecular or bimolecular processes that frequently occur on sub-second, often sub-millisecond, time scales. The traditional approach in kinetic studies is to mix two or more reagents and monitor the changes in concentrations with time. Conventional spectrophotometers cannot generally be used to study reactions that are complete within less than about 20 s, as it takes that amount of time to manually mix the reagents and activate the instrument. Rapid mixing techniques, which generally achieve mixing in less than 2 ms, overcome this limitation. This chapter is concerned with the use of these techniques in the study of reactions which reach equilibrium; the application of these methods to the study of enzyme kinetics is described in several excellent texts (Cornish-Bowden, Fundamentals of enzyme kinetics. Portland Press, 1995; Gutfreund, Kinetics for the life sciences. Receptors, transmitters and catalysis. Cambridge University Press, 1995).There are various ways to monitor changes in concentration of reactants, intermediates and products after mixing, but the most common way is to use changes in optical signals (absorbance or fluorescence) which often accompany reactions. Although absorbance can sometimes be used, fluorescence is often preferred because of its greater sensitivity, particularly in monitoring conformational changes. Such methods are continuous with good time resolution but they seldom permit the direct determination of the concentrations of individual species. Alternatively, samples may be taken from the reaction volume, mixed with a chemical quenching agent to stop the reaction, and their contents assessed by techniques such as HPLC. These methods can directly determine the concentrations of different species, but are discontinuous and have a limited time resolution. PMID:23729251

  18. Experimental determination and theoretical framework of kinetic fractionation at the water vapour-ice interface at low temperature

    NASA Astrophysics Data System (ADS)

    Casado, Mathieu; Cauquoin, Alexandre; Landais, Amaelle; Israel, Dan; Orsi, Anaïs; Pangui, Edouard; Landsberg, Janek; Kerstel, Erik; Prie, Frederic; Doussin, Jean-François

    2016-02-01

    Water isotopes are commonly used for climate reconstruction from ice cores. The different heavy isotopes of water such as H218O, H217O or HDO give information about local temperature but also temperature and humidity of water vapour sources. Quantification of these parameters relies on the good knowledge of equilibrium and kinetic isotopic fractionation at each step of the water cycle. One of the strongest limitations when interpreting water isotopes in remote Antarctic ice cores is the formulation of the isotopic fractionation at solid condensation (vapour to ice). This classical formulation also implies a good knowledge of coefficients for equilibrium fractionation and water vapour diffusion in air as well as supersaturation in clouds. The uncertainties associated with these different parameters make the formulation of isotopic fractionation at solid condensation only empirical. Here, we make use (1) of recent development in the measurements of water isotopes in the water vapour through infra-red spectroscopy and (2) of the possibility to measure accurately 17O-excess of water to test the classical formulation and parameterization of isotopic fractionation at solid condensation. A first experiment involving very strong supersaturation evidences a strong kinetic effect on 17O-excess at solid condensation, similar to d-excess. It also shows the limits of the classical formulation of water isotopic fractionation during solid condensation estimation at very low temperature. A second experiment performed in a cloud chamber under controlled conditions uses cavity ring down spectrometers (CRDS) to determine the spatial variability of water vapour isotopic composition due to diffusion (kinetic effect) during solid condensation. The spatial variability of water vapour isotopic composition can be relatively well reproduced by the resolution of diffusion toward a cold plate. This preliminary study opens new perspectives to revisit the classical formulation of water isotopic

  19. Experimental determination and theoretical framework of kinetic fractionation at the water vapour - ice interface at low temperature.

    NASA Astrophysics Data System (ADS)

    Casado, M.; Prie, F.

    2015-12-01

    Isotopic fraction of water enables climate reconstruction from ice cores. The use of different heavy isotopes of water such as H218O, H217O or HDO gives information about local temperature but also temperature and humidity of water vapour sources. Quantification of these parameters relies on the good knowledge of equilibrium and kinetic isotopic fractionation at each step of the water cycle. The strongest limitation when interpreting water isotopes in remote Antarctic ice cores is the formulation of the isotopic fractionation at solid condensation (vapour to ice). This classical formulation also implies a good knowledge of coefficients for equilibrium fractionation and water vapour diffusion in air as well as supersaturation in clouds. The uncertainties lying on these different parameters make the formulation of isotopic fractionation at solid condensation only empirical. Here, we make use (1) of recent development in the measurements of water isotopes in the water vapour through infra-red spectroscopy and (2) of the possibility to measure accurately 17O-excess of water to test the classical formulation and parameterization of isotopic fractionation at solid condensation. A first experiment involving very strong supersaturation evidences a strong kinetic effect on 17O-excess on solid condensation, similar to d-excess. It also shows the limits of the classical formulation of water isotopic fractionation during solid condensation estimation at very low temperature. A second experiment performed in a cloud chamber in controlled conditions uses CRDS instruments to depict the spatial variability of water vapour isotopic composition due to diffusion (kinetic effect) during solid condensation. These experiments are in agreement with a new theoretical model that we present for the competition between diffusions of different isotopes. This preliminary study opens new perspectives to revisit the classical formulation of water isotopic fractionation during solid condensation

  20. Kinetics of Reactive Wetting

    SciTech Connect

    YOST, FREDERICK G.

    1999-09-09

    The importance of interfacial processes in materials joining has a long history. A significant amount of work has suggested that processes collateral to wetting can affect the extent of wetting and moderate or retard wetting rate. Even very small additions of a constituent, known to react with the substrate, cause pronounced improvement in wetting and are exploited in braze alloys, especially those used for joining to ceramics. The wide diversity of processes, such as diffusion, chemical reaction, and fluxing, and their possible combinations suggest that various rate laws should be expected for wetting kinetics depending on the controlling processes. These rate laws are expected to differ crucially from the standard fluid controlled wetting models found in the literature. Voitovitch et al. and Mortensen et al. have shown data that suggests diffusion control for some systems and reaction control for others. They also presented a model of wetting kinetics controlled by the diffusion of a constituent contained by the wetting fluid. In the following a model will be constructed for the wetting kinetics of a small droplet of metal containing a constituent that diffuses to the wetting line and chemically reacts with a flat, smooth substrate. The model is similar to that of Voitovitch et al. and Mortensen et al. but incorporates chemical reaction kinetics such that the result contains both diffusion and reaction kinetics. The model is constructed in the circular cylinder coordinate system, satisfies the diffusion equation under conditions of slow flow, and considers diffusion and reaction at the wetting line to be processes in series. This is done by solving the diffusion equation with proper initial and boundary conditions, computing the diffusive flux at the wetting line and equating this to both the convective flux and reaction flux. This procedure is similar to equating the current flowing in components of a series circuit. The wetting rate will be computed versus time