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Sample records for laboratory prepared thermoluminescent

  1. Method of preparing a thermoluminescent phosphor

    DOEpatents

    Lasky, Jerome B.; Moran, Paul R.

    1979-01-01

    A thermoluminescent phosphor comprising LiF doped with boron and magnesium is produced by diffusion of boron into a conventional LiF phosphor doped with magnesium. Where the boron dopant is made to penetrate only the outer layer of the phosphor, it can be used to detect shallowly penetrating radiation such as tritium beta ays in the presence of a background of more penetrating radiation.

  2. Preparation and investigation of thermoluminescence properties of CaSO4:Tm,Cu.

    PubMed

    Kása, I; Chobola, R; Mell, P; Szakács, S; Kerekes, A

    2007-01-01

    A new sort of thermoluminescent phosphor has been developed with the purpose of enlarging the range of linear dose-response. The thermoluminescence properties of CaSO(4):Tm,Cu, prepared according to our method, were studied in the dose range of 0.5 Gy-125.0 kGy. The results of the present work show that the CaSO(4):Tm,Cu is an excellent new dosimetric material due to its relatively simple glow curve, as a consequence of its simple trap system. Several applications are possible in dosimetry due to its wide range of linearity (2 x 10(-6) to 2 x 10(3) Gy), from environmental and space dosimetry to accidental and high-dose irradiation, e.g. gamma irradiation facilities, electron accelerators, nuclear power plants, radiotherapy, medical physics, and so on. PMID:16905762

  3. Preparation and characterization of thermoluminescent aluminium oxide doped with Tb3+ and Tb3+-Mg2+

    NASA Astrophysics Data System (ADS)

    Barros, V. S. M.; Azevedo, W. M.; Khoury, H. J.; Linhares Filho, P.

    2010-11-01

    This paper presents the preparation method and the thermoluminescence analysis of aluminium oxide doped with Tb3+ and Tb3+-Mg2+ obtained by Combustion Synthesis (CS). An aqueous solution containing stoichiometric amounts of aluminium, terbium, magnesium nitrates and urea were mixed and introduced in a muffle furnace pre-heated to 500°C. After combustion, the samples were thermally treated at 1300°C and irradiated with a Co-60 gamma radiation source. The TL glow curves of the annealed Al2O3:Tb and Al2O3:Tb,Mg samples presented a well defined TL peak at approximately 200 °C, whereas the samples without heat-treatment presented a large number of TL peaks in the range from 150 to 500°C. These peaks were attributed to amorphous and phase impurities (γ-Al2O3 mixed with the α-phase) still present in the sample. Dose response analysis showed a linear response in the dose range from 0.5 to 5 Gy. These results strongly suggest that CS is a suitable technique to prepare doped aluminium oxide for TL dosimetric applications.

  4. Thermoluminescence analysis of aerosols

    NASA Technical Reports Server (NTRS)

    Long, E. R., Jr.; Rogowski, R. S.

    1979-01-01

    Method is presented for identifying air pollutants in field or laboratory by technique based on thermoluminescence. Approach is useful in tracing dispersion of pollutants over geographical regions and in determining cancer causing agents in the upper atmosphere.

  5. Laboratory Preparation in the Ocular Therapy Curriculum.

    ERIC Educational Resources Information Center

    Cummings, Roger W.

    1986-01-01

    Aspects of laboratory preparation necessary for undergraduate or graduate optometric training in the use of therapeutic drugs are discussed, including glaucoma therapy, anterior segment techniques, posterior segment, and systemic procedures. (MSE)

  6. Topics in Chemical Instrumentation, Cl. Thermoluminescence: Part II. Instrumentation.

    ERIC Educational Resources Information Center

    Manche, Emanuel P.

    1979-01-01

    Presents part two on the use of the detection of thermoluminescence as an analytical tool for the chemistry laboratory and allied science. This part discusses instrumentation used and investigates recent developments in instrumentation for thermoluminescence. (HM)

  7. Effect of complete extraction and re-addition of manganese on thermoluminescence of pea Photosystem II preparations.

    PubMed

    Klimov, V V; Allakhverdiev, S I; Shafiev, M A; Demeter, S

    1985-10-01

    Thermoluminescence of Photosystem II particles isolated from pea chloroplasts using digitonin and Triton X-100 was measured after 1 min illumination at a certain temperature (T(ex)) followed by illumination during cooling (40 Cdeg/min) to a lower temperature. Glow curves of the particles are characteristic of the photosynthetic oxygen-evolving material studied earlier. Complete (more than 95%) removal of Mn from the Photosystem II particles abolishes thermoluminescence bands around 0° C, related to the oxygen-evolving system, but the thermoluminescence bands peaking around -30°C (TL(-30)), -55°C (TL_ (-55)) and between-68 and -85° C, depending on Tex(TLv), remain unaltered. The bands are characterized by different dependence on T,x. The TL(-30), TL(-55) and TL v bands can also be observed in the glow curve of isolated pea and spinach chloroplasts. Re-addition of MnCI (2) (2 μM, corresponding to nearly 4 Mn atoms per reaction center of Photosystem II) to the Mn-depleted particles does not reactivate the thermoluminescence bands around 0° C. However, it does lead to suppression of TL(-30) accompanied by parallel activation of TL(-55), revealing competition of the TL (-30) and TL(-55) for charges generated by the reaction center. These data, as well as the results on the effect of inhibitors and electron donors to Photosystem II, show that positive charges contributing to the TL(-30), TL (-55) and TL v thermoluminescence bands are located on secondary electron donors of Photosystem II which do not require Mn and are located closer to the reaction center than the Mn-containing, water-oxidizing enzyme. PMID:22860268

  8. Thermoluminescent dosimetry for LDEF experiment M0006

    NASA Technical Reports Server (NTRS)

    Chang, J. Y.; Giangano, D.; Kantorcik, T.; Stauber, M.; Snead, L.

    1992-01-01

    Experiment M0006 on the Long Duration Exposure Facility had as its objective the investigation of space radiation effects on various electronic and optical components, as well as on seed germination. The Grumman Corporate Research Center provided the radiation dosimetric measurements for M0006, comprising the preparation of thermoluminescent dosimeters (TLD) and the subsequent measurement and analysis of flight exposed and control samples. In addition, various laboratory exposures of TLD's with gamma rays and protons were performed to obtain a better understanding of the flight exposures.

  9. Preparation of Unconsolidated Sands for Microscopy Laboratory Exercises.

    ERIC Educational Resources Information Center

    Cameron, Barry; Jones, J. Richard

    1988-01-01

    Describes a technique of impregnating small amounts of sandy sediment in a quick curing resin for microscopic examination. Details the preparation of materials. Suggests laboratory exercises based on this preparation. (CW)

  10. Thermoluminescence dosimeter

    SciTech Connect

    Zendle, Robert

    1985-01-01

    A thermoluminescence dosimeter having a very small rate of decline of sensitivity during subsequent uses after heating is disclosed. The dosimeter includes a detector crystal and a glass enclosure in which the detector crystal is located. The glass enclosure is air tight and is filled with a super dry inert fill gas. The inert fill gas is nonreactive with the detector crystal when the detector crystal is heated to thermoluminescence. The fill gas is selected from the group consisting of air, nitrogen, and argon, suitable admixed with 5 to 25 percent helium. The detector crystal consists essentially of calcium fluoride. The fill gas is preferably contained at a subatmospheric pressure in the glass enclosure.

  11. Thermoluminescence dosimeter

    DOEpatents

    Zendle, R.

    1983-11-03

    A thermoluminescence dosimeter having a very small rate of decline of sensitivity during subsequent uses after heating is disclosed. The dosimeter includes a detector crystal and a glass enclosure in which the detector crystal is located. The glass enclosure is air tight and is filled with a super dry inert fill gas. The inert fill gas is nonreactive with the detector crystal when the detector crystal is heated to thermoluminescence. The fill gas is selected from the group consisting of air, nitrogen, and argon, suitable admixed with 5 to 25 percent helium. The detector crystal consists essentially of calcium fluoride. The fill gas is preferably contained at a subatmospheric pressure in the glass enclosure.

  12. Thermoluminescent phosphor

    DOEpatents

    Lasky, Jerome B.; Moran, Paul R.

    1978-01-01

    A thermoluminescent phosphor comprising LiF doped with boron and magnesium is produced by diffusion of boron into a conventional LiF phosphor doped with magnesium. Where the boron dopant is made to penetrate only the outer layer of the phosphor, it can be used to detect shallowly penetrating radiation such as tritium beta rays in the presence of a background of more penetrating radiation.

  13. Operational comparison of bubble (super heated drop) dosimetry results with routine albedo thermoluminescent dosimetry for a selected group of Pu-238 workers at Los Alamos National Laboratory

    SciTech Connect

    Romero, L.L.; Hoffman, J.M.; Foltyn, E.M.; Buhl, T.E.

    1999-03-01

    This paper is an operational study that compares the use of albedo thermoluminescent dosimeters with bubble dosimeters to determine whether bubble dosimeters do provide a useful daily ALARA tool that can yield measurements close to the dose-of-record. A group of workers at the Los Alamos National Laboratory (LANL) working on the Radioactive Thermoelectric Generators (RTG) for the NASA Cassini space mission wore both bubble dosimeters and albedo dosimeters over a period from 1993 through 1996. The bubble dosimeters were issued and read on a daily basis and the data were used as an ALARA tool. The personnel albedo dosimeter was processed on monthly basis and used as the dose-of-record. The results of this study indicated that cumulative bubble dosimetry results agreed with whole-body albedo dosimetry results within about 37% on average. However it was observed that there is a significant variability of the results on an individual basis both month-to-month and from one individual to another.

  14. Designing Online Resources in Preparation for Authentic Laboratory Experiences

    PubMed Central

    Boulay, Rachel; Parisky, Alex; Leong, Peter

    2013-01-01

    Professional development for science teachers can be benefited through active learning in science laboratories. However, how online training materials can be used to complement traditional laboratory training is less understood. This paper explores the design of online training modules to teach molecular biology and user perception of those modules that were part of an intensive molecular biology “boot camp” targeting high school biology teachers in the State of Hawaii. The John A. Burns School of Medicine at the University of Hawaii had an opportunity to design and develop professional development that prepares science teachers with an introduction of skills, techniques, and applications for their students to conduct medical research in a laboratory setting. A group of 29 experienced teachers shared their opinions of the online materials and reported on how they used the online materials in their learning process or teaching. PMID:24319698

  15. Testing hygrometers used in cytogenetics laboratories for metaphase preparation.

    PubMed

    Hartley, Thomas; Dun, Karen

    2011-07-01

    This protocol describes procedures for checking small laboratory hygrometers for accuracy at three relative humidity (rh) levels. The work arose out of the need to provide laboratory assessors with documentary evidence that the hygrometer used to monitor humidity in the vicinity of the laboratory where medical cytogenetics testing slides are prepared and dried in the ambient environment is reproducible and sufficiently accurate. The procedure is based upon the physicochemical principle that when water or certain saturated salt solutions are placed into a sealed environment, the humidity will equilibrate to well defined levels. We choose to check our hygrometers at three points: 95%, 75%, and 33% rh, using distilled water, saturated sodium chloride solution, and saturated magnesium chloride solution, respectively. Our results have demonstrated that the procedure is convenient and of sufficient accuracy to be fit for this annual hygrometer validation purpose. The procedure takes 24 hr per relative humidity point checked. PMID:21735375

  16. Comparison of leach results from field and laboratory prepared samples

    SciTech Connect

    Oblath, S.B.; Langton, C.A.

    1985-03-25

    The leach behavior of saltstone prepared in the laboratory agrees well with that from samples mixed in the field using the Littleford mixer. Leach rates of nitrates and cesium from the current reference formulation saltstone were compared. The laboratory samples were prepared using simulated salt solution; those in the field used Tank 50 decontaminated supernate. For both nitrate and cesium, the field and laboratory samples showed nearly identical leach rates for the first 30 to 50 days. For the remaining period of the test, the field samples showed higher leach rates with the maximum difference being less than a factor of three. Ruthenium and antimony were present in the Tank 50 supernate in known amounts. Antimony-125 was observed in the leachate and a fractional leach rate was calculated to be at least a factor of ten less than that of /sup 137/Cs. No /sup 106/Ru was observed in the leachate, and the release rate was not calculated. However, based on the detection limits for the analysis, the ruthenium leach rate must also be at least a factor of ten less than cesium. These data are the first measurements of the leach rates of Ru and Sb from saltstone. The nitrate leach rates for these samples were 5 x 10/sup -5/ grams of nitrate per square cm per day after 100 days for the laboratory samples and after 200 days for the field samples. These values are consistent with the previously measured leach rates for reference formulation saltstone. The relative standard deviation in the leach rate is about 15% for the field samples, which all were produced from one batch of saltstone, and about 35% for the laboratory samples, which came from different batches. These are the first recorded estimates of the error in leach rates for saltstone.

  17. Thermoluminescence dosimeter reader

    SciTech Connect

    Miyake, S.; Miura, N.

    1984-10-30

    A thermoluminescence dosimeter reader having a heater for heating a thermoluminescence element, a light measuring circuit for measuring circuit for measuring the intensity of the thermoluminescence emanated from the element when it is heated and a display device for displaying the reading of the dosage of radiation to which the element is exposed according to the intensity of the thermoluminescence is provided with a dosage information inputting means which outputs an electric signal having a value representing a predetermined reference dosage of radiation, a calculating means for calculating a calibration constant which is the ratio between the value of the electric signal and the output value of the light measuring circuit which is the measured value of the dosage of radiation of a reference thermoluminescence element which is exposed to the predetermined reference dosage of radiation, and a memory means for memorizing the calibration constant.

  18. Laboratory preparation and evaluation of a multiparameter hemocytometry control.

    PubMed

    Lombarts, A J; Leijnse, B

    1984-05-30

    A protocol for the laboratory preparation of a multiparameter hemocytometry control is given. Human platelets, stabilized by a basically simplified and inexpensive fixation procedure, are added to our previously described white and red blood cell control. Evaluation of this multiparameter control shows good precision characteristics and acceptable mechanical stability for at least 7 weeks, as measured in the Coulter counter Model S Plus-II. The control can basically contribute to the realization of the essence of internal quality control: continuous self-auditing and continuous attempts at improvement of performance. PMID:6733929

  19. Thermoluminescence: Potential Applications in Forensic Science

    NASA Technical Reports Server (NTRS)

    Ingham, J. D.; Lawson, D. D.

    1973-01-01

    In crime laboratories one of the most difficult operations is to determine unequivocally whether or not two samples of evidence of the same type were originally part of the same thing or were from the same source. It has been found that high temperature thermoluminescence (room temperature to 723 K) can be used for comparisons of this type, although work to date indicates that there is generally a finite probability for coincidental matching of glass or soil samples. Further work is required to determine and attempt to minimize these probabilities for different types of materials, and to define more clearly the scope of applicability of thermoluminescence to actual forensic situations.

  20. Thermoluminescence of lunar samples

    USGS Publications Warehouse

    Dalrymple, G.B.; Doell, Richard R.

    1970-01-01

    Appreciable natural thermoluminescence with glow curve peaks at about 350 degrees centigrade for lunar fines and breccias and above 400 degrees centigrade for crystalline rocks has been recognized in lunar samples. Plagioclase has been identified as the principal carrier of thermoluminescence, and the difference in peak temperatures indicates compositional or structural differences between the feldspars of the different rock types. The present thermoluminescence in the lunar samples is probably the result of a dynamic equilibrium between acquisition from radiation and loss in the lunar thermal environment. A progressive change in the glow curves of core samples with depth below the surface suggests the use of thermoluminescence disequilibrium to detect surfaces buried by recent surface activity, and it also indicates that the lunar diurnal temperature variation penetrates to at least 10.5 centimeters.

  1. New sintered thermoluminescent dosimeters for personnel and environmental dosimetry.

    PubMed

    Prokic, M S

    1982-06-01

    We discuss the development of an original method preparing thermoluminescent dosimeters using magnesium borate and calcium sulfate materials activated with rare earths. This method is based upon the effect of sensitized thermoluminescent emission of basic TLD phosphors as well as on the method for producing these in solid form. Our technique resulted in unique TLD's in the form of sintered thermoluminescent dosimeters. For one of these, MgB4O7:RE+, the thermoluminescent response is up to five times more sensitive than non-sensitized magnesium borate thermoluminescent material. The other TLD, CaSO4:RE+, has dosimetric characteristics which stay unchanged and are equivalent with characteristics of the well-known calcium sulfate TLD phosphors. These new types of sintered TLD's are highly promising for personnel and environmental dosimetry. PMID:7107292

  2. Iodine Standard Materials: Preparation and Inter-Laboratory Comparisons

    SciTech Connect

    D D Jenson; M L Adamic; J E Olson; M G Watrous; C Vockenhuber

    2014-08-01

    The Idaho National Laboratory is preparing to enter the community of AMS practioners who analyze for 129Iodine. We expect to take delivery of a 0.5 MV compact accelerator mass spectrometry system, built by NEC, in the early summer of 2014. The primary mission for this instrument is iodine; it is designed to analyze iodine in the +3 charge state. As part of the acceptance testing for this instrument, both at NEC and on-site in our laboratory, some sort of standard or reference material is needed to verify performance. Appropriate standard materials are not readily available in the commercial marketplace. Small quantities can sometimes be acquired from other laboratories already engaged in iodine analyses. In the longer-term, meaningful quantities of standard materials are needed for routine use in analyses, and for quality control functions1. We have prepared some standard materials, starting with elemental Woodward iodine and NIST SRM 3231 [Iodine-129 Isotopic Standard (high level)] 10-6 solution. The goal was to make mixtures at the 5x10-10, 5x10-11, 5x10-12 ratio levels, along with some unmodified Woodward, in the chemical form of silver iodide. Approximately twenty grams of each of these mixtures were prepared. The elemental Woodward iodine was dissolved in chloroform, then reduced to iodide using sodium bisulfite in water. At this point the NIST spike material was added, in the form of sodium iodide. The mixed iodides were oxidized back to iodine in chloroform using hydrogen peroxide. This oxidation step was essential for isotopic equilibration of the 127 and 129 atoms. The iodine was reduced to iodide using sodium bisulfite as before. Excess sulfites and sulfates were precipitated with barium nitrate. After decanting, silver nitrate was used to precipitate the desired silver iodide. Once the silver iodide was produced, the material was kept in darkness as much as possible to minimize photo-oxidation. The various mixtures were synthesized independently of each

  3. PHYSICAL PROPERTY MEASUREMENTS OF LABORATORY PREPARED SALTSTONE GROUT

    SciTech Connect

    Hansen, E.; Cozzi, A.; Edwards, T.

    2014-05-05

    The Saltstone Production Facility (SPF) built two new Saltstone Disposal Units (SDU), SDU 3 and SDU 5, in 2013. The variable frequency drive (VFD) for the grout transfer hose pump tripped due to high current demand by the motor during the initial radioactive saltstone transfer to SDU 5B on 12/5/2013. This was not observed during clean cap processing on July 5, 2013 to SDU 3A, which is a slightly longer distance from the SPF than is SDU 5B. Saltstone Design Authority (SDA) is evaluating the grout pump performance and capabilities to transfer the grout processed in SPF to SDU 3/5. To assist in this evaluation, grout physical properties are required. At this time, there are no rheological data from the actual SPF so the properties of laboratory prepared samples using simulated salt solution or Tank 50 salt solution will be measured. The physical properties of grout prepared in the laboratory with de-ionized water (DI) and salt solutions were obtained at 0.60 and 0.59 water to premix (W/P) ratios, respectively. The yield stress of the DI grout was greater than any salt grout. The plastic viscosity of the DI grout was lower than all of the salt grouts (including salt grout with admixture). When these physical data were used to determine the pressure drop and fluid horsepower for steady state conditions, the salt grouts without admixture addition required a higher pressure drop and higher fluid horsepower to transport. When 0.00076 g Daratard 17/g premix was added, both the pressure drop and fluid horsepower were below that of the DI grout. Higher concentrations of Daratard 17 further reduced the pressure drop and fluid horsepower. The uncertainty in the single point Bingham Plastic parameters is + 4% of the reported values and is the bounding uncertainty. Two different mechanical agitator mixing protocols were followed for the simulant salt grout, one having a total mixing time of three minutes and the other having a time of 10 minutes. The Bingham Plastic parameters

  4. Thermoluminescence of meteorites and their orbits

    NASA Astrophysics Data System (ADS)

    Melcher, C. L.

    1981-01-01

    The thermoluminescence levels of 45 ordinary chondrites are measured in order to provide information on the orbital characteristics of the meteorites before impact. Glow curves of the photon emission response of powdered samples of the meteorites to temperatures up to 550 C in the natural state and following irradiation by a laboratory test dose of 110,000 rad were obtained as functions of terrestrial age and compared to those of samples of the Pribram, Lost City and Innisfree meteorites, for which accurate orbital data is available. The thermoluminescence levels in 40 out of 42 meteorites are found to be similar to those of the three control samples, indicating that the vast majority of ordinary chondrites that survive atmospheric entry have perihelia in the range 0.8-1 AU. Of the remaining two, Farmville is observed to exhibit an unusually large gradient in thermoluminescence levels with sample depth, which may be a result of a temperature gradient arising in a slowly rotating meteorite. Finally, the thermoluminescence measured in the Malakal meteorite is found to be two orders of magnitude lower than control samples, which is best explained by thermal draining by solar heating in an orbit with a perihelion distance of 0.5 to 0.6 AU.

  5. An Alternative Approach for Preparing and Standardizing Some Common Aqueous Reagents Used in an Undergraduate Laboratory

    ERIC Educational Resources Information Center

    Melaku, Samuel; Dabke, Rajeev B.

    2014-01-01

    A guide for instructors and laboratory assistants to prepare some common aqueous reagents used in an undergraduate laboratory is presented. Dilute reagents consisting of H[superscript +](aq), I[subscript 3][superscript-](aq), Ce[superscript 4+](aq), and Ag[superscript+](aq) were prepared by electrolytic oxidation of respective precursors.…

  6. STRUCTURED LEARNING AND TRAINING ENVIRONMENTS--A PREPARATION LABORATORY FOR ADVANCED MAMMALIAN PHYSIOLOGY.

    ERIC Educational Resources Information Center

    FIEL, NICHOLAS J.; JOHNSTON, RAYMOND F.

    A PREPARATION LABORATORY WAS DESIGNED TO FAMILIARIZE STUDENTS IN ADVANCED MAMMALIAN PHYSIOLOGY WITH LABORATORY SKILLS AND TECHNIQUES AND THUS SHORTEN THE TIME THEY SPEND IN SETTING UP ACTUAL EXPERIMENTS. THE LABORATORY LASTS 30 MINUTES, IS FLEXIBLE AND SIMPLE OF OPERATION, AND DOES NOT REQUIRE A PROFESSOR'S PRESENCE. THE BASIC TRAINING UNIT IS THE…

  7. Molybdenum-99 Isotope Production Preparation at Sandia National Laboratories

    SciTech Connect

    Carson, S.D.; Longley, S.W.; McDonald, M.J.; Parma, E.J.; Vernon, M.E.

    1998-10-07

    `Q&c M. J. McDonald, S. D. Carson, S. W. Longley, E. J. Parma, M. E. Vern `~ I@ .,., Sandia National Laboratories*, P. .0. Box 5800, Albuquerque, NM, 8 W? 1$ tl?;:q `f. (3 . 8 /'~ Abstract This report was prepared as an account of work sponsored byanagency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, make any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. loading on the Cintichem targets. These tests were designed to gain process knowledge prior to processing an irradiated target. The chemical separation tests were performed in a fime hood During cold testing, several tests were performed on individual components of the process to complete, a series of `hot' tests was designed to process irradiated targets. These were designed to optimize the process, identify problems prior to processing higher inventory targets, and to the shielded containment box (SCB). Table 1 is a summary of the tests performed prior to the Test Target Power Post irradiation Total inventory 99M0 inventory (kW)/ Irradiation decay (hrs) (TBq*) /decay (TBq)/decay Time (hrs) inventory (TBq) inventory(TBq) in the processing boxes as color comparisons. Product quality control testing was conducted for all the tests and the results were compared to The production process generates a high activity acidic liquid

  8. Thermoluminescence properties of ZnO and ZnO:Yb nanophosphors

    SciTech Connect

    Pal, U.; Melendrez, R.; Chernov, V.; Barboza-Flores, M.

    2006-10-30

    ZnO and ZnO:Yb thermoluminescence nanophosphors have been developed and tested under beta radiation. Spherical nanoparticles of sizes ranging from 130 to 1200 nm were prepared through a glycol mediated chemical synthesis. The Yb doping had a thermoluminescence quenching effect compared to undoped ZnO. The 5% Yb concentration produced a low fading, a single thermoluminescence glow peak structure, and a dose linearity behavior adequate for thermoluminescence dosimetry applications. The ZnO:Yb nanophosphor has a great potential as a dosimeter for monitoring in ionizing radiation fields.

  9. Environmental radiation detection via thermoluminescence

    DOEpatents

    Miller, S.D.

    1993-03-23

    The method and apparatus of the present invention relate to cryogenically cooling a thermoluminescent material, exposing it to a low level of radiation (less than about 1 R) while it is at the cooled temperature, warming the thermoluminescent material to room temperature'' and counting the photons emitted during heating. Sufficient sensitivity is achieved without exposing the thermoluminescent material to ultraviolet light thereby simplifying the measurements.

  10. Environmental radiation detection via thermoluminescence

    DOEpatents

    Miller, Steven D.

    1993-01-01

    The method and apparatus of the present invention relate to cryogenically cooling a thermoluminescent material, exposing it to a low level of radiation (less than about 1 R) while it is at the cooled temperature, warming the thermoluminescent material to "room temperature", and counting the photons emitted during heating. Sufficient sensitivity is achieved without exposing the thermoluminescent material to ultraviolet light thereby simplifying the measurements.

  11. Upgrading the Laboratory Preparation of High School Teachers

    ERIC Educational Resources Information Center

    Powers, Jack W.; Scamehorn, Richard G.

    1970-01-01

    Describes a college program designed to upgrade the laboratory experience of selected high school chemistry teachers. Small groups of teachers work with college faculty on chemistry problems each weekend. Problems investigated include the use of pH meters, X-ray diffraction, computers, and experiments in chromatography, spectroscopy radiochemistry…

  12. Solid-Phase Organic Synthesis and Combinatorial Chemistry: A Laboratory Preparation of Oligopeptides

    NASA Astrophysics Data System (ADS)

    Truran, George A.; Aiken, Karelle S.; Fleming, Thomas R.; Webb, Peter J.; Hodge Markgraf, J.

    2002-01-01

    The principles and practice of solid-phase organic synthesis and combinatorial chemistry are utilized in a laboratory preparation of oligopeptides. A parallel synthesis scheme is used to generate a series of tripeptides. A divergent synthesis scheme is used to prepare two pentapeptides, one of which is leucine enkephalin, a neurotransmitter known to be an analgesic agent.

  13. A Three-Step Laboratory Sequence to Prepare a Carbene Complex of Silver(I) Chloride

    ERIC Educational Resources Information Center

    Canal, John P.; Ramnial, Taramatee; Langlois, Lisa D.; Abernethy, Colin D.; Clyburne, Jason A. C.

    2008-01-01

    We have developed a multistep inorganic synthesis experiment for our second-year undergraduate teaching laboratory that introduces students to modern organometallic chemistry. The ligands are prepared in two simple steps and the preparation of an air-stable silver carbene complex is accomplished in the third step. The students are introduced to…

  14. Thermoluminescence as a palaeothermometer

    NASA Technical Reports Server (NTRS)

    Guimon, R. K.; Weeks, K. S.; Keck, B. D.; Sears, D. W. G.

    1984-01-01

    The results of annealing experiments on a little-metamorphosed (type 3.5) ordinary chondrite are reported. The thermoluminescence (TL) emission characteristics of the annealed samples show trends very similar to those observed in meteorites which have been naturally metamorphosed in various degrees. The trends are also similar to those observed in annealing experiments on terrestrial albite, where the changes are associated with the low-to-high temperature transformation. These results suggest that the TL phosphor in meteorites is feldspar and that TL can be used to estimate paleotemperatures for little-metamorphosed and highly unequilibrated meteorites.

  15. Thermoluminescent aerosol analysis

    NASA Technical Reports Server (NTRS)

    Rogowski, R. S.; Long, E. R., Jr. (Inventor)

    1977-01-01

    A method for detecting and measuring trace amounts of aerosols when reacted with ozone in a gaseous environment was examined. A sample aerosol was exposed to a fixed ozone concentration for a fixed period of time, and a fluorescer was added to the exposed sample. The sample was heated in a 30 C/minute linear temperature profile to 200 C. The trace peak was measured and recorded as a function of the test aerosol and the recorded thermoluminescence trace peak of the fluorescer is specific to the aerosol being tested.

  16. Invention activities as preparation for learning laboratory data handling skills

    NASA Astrophysics Data System (ADS)

    Day, James

    2012-10-01

    Undergraduate physics laboratories are often driven by a mix of goals, and usually enough of them to cause cognitive overload for the student. Our recent findings align well with studies indicating that students often exit a physics lab without having properly learned how to handle real data. The value of having students explore the underlying structure of a problem before being able to solve it has been shown as an effective way to ready students for learning. Borrowing on findings from the fields of education and cognitive psychology, we use ``invention activities'' to precede direct instruction and bolster learning. In this talk I will show some of what we have learned about students' data handling skills, explain how an invention activity works, and share some observations of successful transfer.

  17. [LABORATORY AND EXPERIMENTAL STUDY OF THE COMPLEX PROBIOTIC PREPARATION "BIFILACT-BILS" IN CAPSULATED FORM].

    PubMed

    Neschislyaev, V A; Stolbova, M G; Mokin, P A; Orlova, E V; Ershov, A E

    2016-01-01

    The composition and technology of complex probiotic in hard gelatin capsules was developed in Perm Branch "Biomed" of "Microgen" State Company. The preparation contains three production strains: Lactobacillus plantarum 8P-A3, L. acidophilus K3W24 and Bifidobacterium bifidum 1. Laboratory and experimental (preclinical) study of the probiotic included investigation of the antagonistic activity, "acute" and "chronic" toxicity, the effect of the preparation on histology and hematology of laboratory animals. The result of these studies suggested of the probiotic had high inhibitory activity against pathogenic microflora when compared with probiotic monopreparations and had no toxic effects on laboratory animals. PMID:27301138

  18. Integration of Video-Based Demonstrations to Prepare Students for the Organic Chemistry Laboratory

    NASA Astrophysics Data System (ADS)

    Nadelson, Louis S.; Scaggs, Jonathan; Sheffield, Colin; McDougal, Owen M.

    2015-08-01

    Consistent, high-quality introductions to organic chemistry laboratory techniques effectively and efficiently support student learning in the organic chemistry laboratory. In this work, we developed and deployed a series of instructional videos to communicate core laboratory techniques and concepts. Using a quasi-experimental design, we tested the videos in five traditional laboratory experiments by integrating them with the standard pre-laboratory student preparation presentations and instructor demonstrations. We assessed the influence of the videos on student laboratory knowledge and performance, using sections of students who did not view the videos as the control. Our analysis of pre-quizzes revealed the control group had equivalent scores to the treatment group, while the post-quiz results show consistently greater learning gains for the treatment group. Additionally, the students who watched the videos as part of their pre-laboratory instruction completed their experiments in less time.

  19. Application Of The Thermoluminescent Dosemeters For The Measurement Of Low Level Background

    SciTech Connect

    Stochioiu, Ana I.; Sahagia, Maria C.; Mihai, Felicia S.; Tudor, Ion L.; Lupescu, Henrieta I.

    2007-04-23

    The results obtained in the measurement of the low level radiation background by using a thermoluminescent (TL) system, in a former salt mine, designed to be used as an underground laboratory , are presented.

  20. Thermoluminescent (TL) trap characteristics in irradiated oregano herb

    NASA Astrophysics Data System (ADS)

    Furetta, C.; Cruz-Zaragoza, E.

    The aim of this article is to investigate in a very simple way the trap characteristics of the irradiated oregano herb. The preparation of the polymineral dust obtained from the herb is described and then, through a fading experiment, the characteristics of the trapping levels responsible of the thermoluminescent emission are discussed.

  1. The impact of soil preparation on the soil erosion rates under laboratory conditions

    NASA Astrophysics Data System (ADS)

    Khaledi Darvishan, A.; Homayounfar, V.; Sadeghi, S. H. R.

    2015-03-01

    The use of laboratory methods in soil erosion studies causes soil disturbance, preparation and placement in experimental plots and has been recently considered more and more because of many advantages. However, different stages of soil removal, transfer, preparation and placement in laboratory plots cause significant changes in soil structure and subsequently, the results of runoff, sediment concentration and soil loss. Knowing the rate of changes in sediment concentration and soil loss variables with respect to the soil preparation for laboratory studies is therefore inevitable to generalize the laboratory results to field conditions. However, there has been less attention to evaluate the effects of soil preparation on sediment variables. The present study was therefore conducted to compare sediment concentration and soil loss in natural and prepared soil. To achieve the study purposes, 18 field 1 m × 1 m-plots were adopted in an 18% gradient slope with sandy-clay-loam soil in the Kojour watershed, Northern Iran. Three rainfall intensities of 40, 60 and 80 mm h-1 were simulated on both prepared and natural soil treatments with three replications. The sediment concentration and soil loss at five three-minute intervals after time-to-runoff were then measured. The results showed the significant (p ≤ 0.01) increasing effects of soil preparation on the average sediment concentration and soil loss. The increasing rates of runoff coefficient, sediment concentration and soil loss due to the study soil preparation method for laboratory soil erosion plots, were 179, 183 and 1050% (2.79, 2.83 and 11.50 times), respectively.

  2. [Thermoluminescence Slab Dosimeter].

    PubMed

    Shinsho, Kiyomitsu; Koba, Yusuke; Tamatsu, Satoshi; Sakurai, Noboru; Wakabayashi, Genichiro; Fukuda, Kazusige

    2013-01-01

    In 1953 F. Daniels et al. used the property of thermoluminescence in dosimetry for the first time. Since then, numerous TLD have been developed. 2D TLD was investigated for the first time in 1972 by P Broadhead. However, due to excessive fading, difficulties with handling and the time required for measurements, development stalled. At the current time, the majority of TLD are used in small scale, localized dosimetry with a wide dynamic range and personal dosimeters for exposure management. Urushiyama et. al. have taken advantage of the commoditization of CCD cameras in recent years--making large area, high resolution imaging easier--to introduce and develop a 2D TLD. It is expected that these developments will give rise to a new generation of applications for 2D TL dosimetry. This paper introduces the "TL Slab Dosimeter" developed jointly by Urushiyama et. al. and our team, its measurement system and several typical usage scenarios. PMID:24893451

  3. Alumina as a Thermoluminescent Material

    SciTech Connect

    Uzun, Erdem; Yarar, Yasemin

    2007-04-23

    Thermoluminescence dosimeters are extensively used for quantitative dose measurements in various irradiation fields. They are also important for environmental monitoring after nuclear accident and weapon tests. In this work, the principles of TLD dosimeter and characteristics of several TLD materials are presented. Besides, taken into account the importance as a raw material, the utilization of domestic alumina (Al2O3) in TLDs as a thermoluminescent material is discussed.

  4. Laboratory robotics -- An automated tool for preparing ion chromatography calibration standards

    SciTech Connect

    Chadwick, J.L.

    1995-04-01

    This paper describes the use of a laboratory robot as an automated tool for preparing multi-level calibration standards for On-Line Ion Chromatography (IC) Systems. The robot is designed for preparation of up to six levels of standards, with each level containing up to eleven ionic species in aqueous solution. The robot is required to add the standards` constituents as both a liquid and solid additions and to keep a record of exactly what goes into making up every standard. Utilizing a laboratory robot to prepare calibration standards provides significant benefits to the testing environment. These benefits include: accurate and precise calibration standards in individually capped containers with preparation traceability; automated and unattended multi-specie preparation for both anion and cation analytical channels; the ability to free up a test operator from a repetitive routine and re-apply those efforts to test operations; The robot uses a single channel IC to analyze each prepared standard for specie content and concentration. Those results are later used as a measure of quality control. System requirements and configurations, robotic operations, manpower requirements, analytical verification, accuracy and precision of prepared solutions, and robotic downtime are discussed in detail.

  5. [prepCheck computer-supported objective evaluation of students preparation in preclinical simulation laboratory].

    PubMed

    Lenherr, Patrik; Marinello, Carlo P

    2014-01-01

    Applications such as “prepCheck” allow objective and consistent judgments of tooth preparations. Hereby the respective preparation is matched with a standardized preparation. Whereas the learning curve in the beginning is time-consuming, after some time the faculty members will be relieved from additional mentoring time in the preclinical simulation laboratory. Students independently get an objective self-assessment by the software. Time and effort at the moment are in a misbalance since three scans (preparation, occlusion record, opposite jaw) are necessary. A simple one-scan procedure would be preferable. “prepCheck” is considered as a user-friendly software. It will play an essential role in the objective assessment of students tooth preparations in the future education. PMID:25341525

  6. TECHNIQUES OF TAPE PREPARATION AND DUPLICATION, WITH SUGGESTIONS FOR A LANGUAGE LABORATORY.

    ERIC Educational Resources Information Center

    Kansas State Dept. of Public Instruction, Topeka.

    PART ONE OF THIS BULLETIN PROVIDES HELP IN THE TWO CRITICAL AREAS OF MASTER TAPE PREPARATION AND DUPLICATION. SUPPLEMENTED BY NUMEROUS PHOTOGRAPHS AND DIAGRAMS OF EQUIPMENT AND DUPLICATION TECHNIQUES, THE BULLETIN DESCRIBES MASTER PROGRAM DUPLICATION USING LANGUAGE LABORATORY EQUIPMENT, A PROFESSIONAL MASS DUPLICATOR, A TAPE RECORDER, A RECORD…

  7. FACTORS AFFECTING THE USE OF CAF2:MN THERMOLUMINESCENT DOSIMETERS FOR LOW-LEVEL ENVIRONMENTAL RADIATION MONITORING

    EPA Science Inventory

    An investigation was made of factors affecting the use of commercially-produced CaF2:Mn thermoluminescent dosimeters for low level environmental radiation monitoring. Calibration factors and self-dosing rates were quantified for 150 thermoluminescent dosimeters. Laboratory studie...

  8. Thermoluminescence and Antarctic meteorites

    NASA Technical Reports Server (NTRS)

    Sears, D. W. G.; Hasan, F. A.

    1986-01-01

    The level of natural thermoluminescence (TL) in meteorites is the result of competition between build-up, due to exposure to cosmic radiation, and thermal decay. Antarctic meteorites tend to have lower natural TL than non-Antarctic meteorites because of their generally larger terrestrial ages. However, since a few observed falls have low TL due to a recent heating event, such as passage within approximately 0.7 astronomical units of the Sun, this could also be the case for some Antarctic meteorites. Dose rate variations due to shielding, heating during atmospheric passage, and anomalous fading also cause natural TL variations, but the effects are either relatively small, occur infrequently, or can be experimentally circumvented. The TL sensitivity of meteorites reflects the abundance and nature of the feldspar. Thus intense shock, which destroys feldspar, causes the TL sensitivity to decrease by 1 to 2 orders of magnitude, while metamorphism, which generates feldspar through the devitrification of glass, causes TL sensitivity to increase by a factor of approximately 10000. The TL-metamorphism relationship is particularly strong for the lowest levels of metamorphism. The order-disorder transformation in feldspar also affect the TL emission characteristics and thus TL provides a means of paleothermometry.

  9. Measuring the Effectiveness of Simulations in Preparing Students for the Laboratory

    NASA Astrophysics Data System (ADS)

    Paetkau, Mark; Bissonnette, Dan; Taylor, Colin

    2013-02-01

    Computer simulations (we use the word liberally here to include applets, animations, apps, etc.) have been making steady progress as teaching tools. Large collections of simulations, created by individuals1,2 and by groups,3 are freely available. More recently, research on the effectiveness of simulations as teaching tools, particularly focused on the teaching of concepts, has been an area of interest.4,5 We have been using simulations at Thompson Rivers University (TRU) to help prepare students for the physics lab for the past five years. In work by others, simulations were used in the pre-laboratory work to prepare students on a conceptual level.6 In our case the simulations are used to help prepare students for the experimental aspect. The current work focuses on students' need to take data in the lab and how students can be prepared to efficiently obtain that data.

  10. Teaching Laboratory and Research Skills as Preparation for Careers in Science and Education

    NASA Astrophysics Data System (ADS)

    Thoms, Brian

    2007-03-01

    Recipients of bachelor's degrees in physics have identified lab skills, team work, and research skills as abilities necessary for success in their jobs. However, they also report having received less than adequate preparation in these areas during their college careers. We report on the redesign of a junior physics-major modern physics laboratory course into an inquiry-based, research-like laboratory course. The overall strategy was such as to require the students to approach the experiments in a research-like fashion. In addition, experiments which explore materials properties which can't be looked up in textbooks, e.g. Hall Effect, have been added to further emphasize a research-like approach to the investigations. Laboratory reporting requirements were written to closely reproduce current practices in scientific journals. Assessment of the redesign was performed through surveys of current and graduated students and through comparison of laboratory reports.

  11. Preparation for microgravity: The role of the microgravity materials science laboratory

    NASA Technical Reports Server (NTRS)

    Johnston, J. Christopher; Rosenthal, Bruce N.; Meyer, Maryjo B.; Glasgow, Thomas K.

    1988-01-01

    A laboratory dedicated to ground based materials processing in preparation for space flight was established at the NASA Lewis Research Center. Experiments are performed to delineate the effects of gravity on processes of both scientific and commercial interest. Processes are modeled physically and mathematically. Transport model systems are used where possible to visually track convection, settling, crystal growth, phase separation, agglomeration, vapor transport, diffusive flow, and polymers reactions. The laboratory contains apparatus which functionally duplicates apparatus available for flight experiments and other pieces instrumented specifically to allow process characterization. Materials addressed include metals, alloys, salts, glasses, ceramics, and polymers. The Microgravity Materials Science Laboratory is staffed by engineers and technicians from a variety of disciplines and is open to users from industry and academia as well as the government. Examples will be given of the laboratory apparatus typical experiments and results.

  12. Laser heated thermoluminescence dosimetry

    SciTech Connect

    Justus, B.L.; Huston, A.L.

    1996-06-01

    We report a novel laser-heated thermoluminescence dosimeter that is radically different from previous laser-heated dosimeters. The dosimeter is a semiconductor and metal ion doped silica glass that has excellent optical transparency. The high optical quality of the glass essentially eliminates laser power loss due to light scattering. This efficient utilization of the laser power permits operation of the dosimeter without strong absorption of the laser, as is required in traditional laser-heated dosimetry. Our laser-heated dosimeter does not rely on the diffusion of heat from a separate, highly absorbing substrate, but operates via intimate, localized heating within the glass dosimeter due to the absorption of the laser light by rare earth ion dopants in the glass. Following absorption of the laser light, the rare earth ions transfer energy to the surrounding glass via nonradiative relaxation processes, resulting in rapid, localized temperature increases sufficient to release all the filled traps near the ions. As the heat diffuses radially away from the rare earth ions the temperature plummets dramatically on a manometer distance scale and the release of additional filled traps subsides. A key distinguishing feature of this laser-heated dosimeter is the ability to read the dose information more than once. While laser-heating provides complete information about the radiation exposure experienced by the glass due to the release of locally heated traps, the process leaves the remaining filled bulk traps undisturbed. The bulk traps can be read using traditional bulk heating methods and can provide a direct determination of an accumulated dose, measured following any number of laser-heated readouts. Laser-heated dosimetry measurements have been performed using a solid state diode laser for the readout following radiation exposure with a {sup 60}Co source.

  13. Ultimate ceramic veneer: a laboratory-guided preparation technique for minimally invasive laminate veneers.

    PubMed

    De Andrade, Oswaldo Scopin; Hirata, Ronaldo; Celestrino, Marcos; Seto, Marcio; Siqueira, Sérgio; Nahas, Rodrigo

    2012-06-01

    Clinical success of ceramic laminate veneers depends on material selection, bonding procedures, controlled laboratory steps, and enamel preservation. Enamel preservation is the most critical because excessive tooth preparation can expose dentin reducing bond strength, which is a factor that can cause a decrease in long-term clinical success. The proposed technique based on carefully treatment planning developed between clinician and dental technician helps to maximize enamel preservation, which is an important element for clinical success. PMID:22856034

  14. Phage on tap-a quick and efficient protocol for the preparation of bacteriophage laboratory stocks.

    PubMed

    Bonilla, Natasha; Rojas, Maria Isabel; Netto Flores Cruz, Giuliano; Hung, Shr-Hau; Rohwer, Forest; Barr, Jeremy J

    2016-01-01

    A major limitation with traditional phage preparations is the variability in titer, salts, and bacterial contaminants between successive propagations. Here we introduce the Phage On Tap (PoT) protocol for the quick and efficient preparation of homogenous bacteriophage (phage) stocks. This method produces homogenous, laboratory-scale, high titer (up to 10(10-11) PFU·ml(-1)), endotoxin reduced phage banks that can be used to eliminate the variability between phage propagations and improve the molecular characterizations of phage. The method consists of five major parts, including phage propagation, phage clean up by 0.22 μm filtering and chloroform treatment, phage concentration by ultrafiltration, endotoxin removal, and the preparation and storage of phage banks for continuous laboratory use. From a starting liquid lysate of > 100 mL, the PoT protocol generated a clean, homogenous, laboratory phage bank with a phage recovery efficiency of 85% within just two days. In contrast, the traditional method took upwards of five days to produce a high titer, but lower volume phage stock with a recovery efficiency of only 4%. Phage banks can be further purified for the removal of bacterial endotoxins, reducing endotoxin concentrations by over 3,000-fold while maintaining phage titer. The PoT protocol focused on T-like phages, but is broadly applicable to a variety of phages that can be propagated to sufficient titer, producing homogenous, high titer phage banks that are applicable for molecular and cellular assays. PMID:27547567

  15. Phage on tap–a quick and efficient protocol for the preparation of bacteriophage laboratory stocks

    PubMed Central

    Bonilla, Natasha; Rojas, Maria Isabel; Netto Flores Cruz, Giuliano; Hung, Shr-Hau; Rohwer, Forest

    2016-01-01

    A major limitation with traditional phage preparations is the variability in titer, salts, and bacterial contaminants between successive propagations. Here we introduce the Phage On Tap (PoT) protocol for the quick and efficient preparation of homogenous bacteriophage (phage) stocks. This method produces homogenous, laboratory-scale, high titer (up to 1010–11 PFU·ml−1), endotoxin reduced phage banks that can be used to eliminate the variability between phage propagations and improve the molecular characterizations of phage. The method consists of five major parts, including phage propagation, phage clean up by 0.22 μm filtering and chloroform treatment, phage concentration by ultrafiltration, endotoxin removal, and the preparation and storage of phage banks for continuous laboratory use. From a starting liquid lysate of > 100 mL, the PoT protocol generated a clean, homogenous, laboratory phage bank with a phage recovery efficiency of 85% within just two days. In contrast, the traditional method took upwards of five days to produce a high titer, but lower volume phage stock with a recovery efficiency of only 4%. Phage banks can be further purified for the removal of bacterial endotoxins, reducing endotoxin concentrations by over 3,000-fold while maintaining phage titer. The PoT protocol focused on T-like phages, but is broadly applicable to a variety of phages that can be propagated to sufficient titer, producing homogenous, high titer phage banks that are applicable for molecular and cellular assays. PMID:27547567

  16. Preventing and Removing Contamination in a Natural Radiocarbon Sample Preparation Laboratory

    SciTech Connect

    Zermeno, P; Kurdyla, D K; Buchholz, B A; Heller, S J; Frantz, B R; Brown, T A; Kashgarian, M

    2002-10-25

    The introduction of elevated {sup 14}C contamination into a natural radiocarbon sample preparation laboratory can occur through many different pathways. The most difficult to control is the introduction of contaminated samples from outside labs. Laboratories can remain {sup 14}C contaminated as a result of earlier tracer based research, even if ''hot'' work has not occurred in the laboratories in decades. Prior to accepting samples from outside collaborators, it is recommended that the collaborators test their labs for {sup 14}C contamination. Any surface in a lab that has high use by multiple people has the potential to be contaminated. The standard procedure for determining whether a collaborator's lab is contaminated consists of swiping lab surfaces with small glass fiber filters wetted with alcohol and measuring them for {sup 14}C content using AMS. Volatile {sup 14}C can be detected by using aerosol monitors consisting of fine soot that is depleted in {sup 14}C. These monitors can be set out in the laboratory in question to check for volatile {sup 14}C contamination. In the event that a hot sample is introduced in the natural radiocarbon sample prep laboratory, all sample submission should be stopped until the lab is declared clean. Samples already being processed should be completed along with {sup 14}C depleted material and measured by AMS. This will help determine if the contaminated samples have affected other samples in the laboratory. After a contamination event, the laboratory and associated equipment requires cleaning or disposal. All surfaces and equipment should be wiped down with acetone or ethanol. All chemicals in use should be disposed of in the appropriate waste containers and those waste containers removed from the lab. Once the natural radiocarbon laboratory has been thoroughly ''cleaned'', several background samples consisting of {sup 14}C depleted material should be processed through the lab and measured by AMS before unknown samples are

  17. Method for detecting radiation dose utilizing thermoluminescent material

    DOEpatents

    Miller, Steven D.; McDonald, Joseph C.; Eichner, Fred N.; Durham, James S.

    1992-01-01

    The amount of ionizing radiation to which a thermoluminescent material has been exposed is determined by first cooling the thermoluminescent material and then optically stimulating the thermoluminescent material by exposure to light. Visible light emitted by the thermoluminescent material as it is allowed to warm up to room temperature is detected and counted. The thermoluminescent material may be annealed by exposure to ultraviolet light.

  18. Thermoluminescence characteristics of hydrogenated amorphous zirconia

    NASA Astrophysics Data System (ADS)

    Montalvo, T. R.; Tenorio, L. O.; Nieto, J. A.; Salgado, M. B.; Estrada, A. M. S.; Furetta, C.

    2005-05-01

    This paper reports the experimental results concerning the thermoluminescent (TL) characteristics of hydrogenated amorphous zirconium oxide (a-Zr:H) powder prepared by the sol-gel method. The advantages of this method are the homogeneity and the purity of the gels associated with a relatively low sintering temperature. Hydrogenated amorphous powder was characterized by thermal analysis and X-ray diffraction. The main TL characteristics investigated were the TL response as a function of the absorbed dose, the reproducibility of the TL readings and the fading. The undoped a-Zr:H powder presents a TL glow curve with two peaks centered at 150 and 260 degrees C, respectively, after beta irradiation. The TL response a-Zr:H as a function of the absorbed dose showed a linear behavior over a wide range. The results presented open the possibility to use this material as a good TL dosimeter.

  19. An innovative blended learning approach using virtual patients as preparation for skills laboratory training: perceptions of students and tutors

    PubMed Central

    2013-01-01

    Background Currently only a few reports exist on how to prepare medical students for skills laboratory training. We investigated how students and tutors perceive a blended learning approach using virtual patients (VPs) as preparation for skills training. Methods Fifth-year medical students (N=617) were invited to voluntarily participate in a paediatric skills laboratory with four specially designed VPs as preparation. The cases focused on procedures in the laboratory using interactive questions, static and interactive images, and video clips. All students were asked to assess the VP design. After participating in the skills laboratory 310 of the 617 students were additionally asked to assess the blended learning approach through established questionnaires. Tutors’ perceptions (N=9) were assessed by semi-structured interviews. Results From the 617 students 1,459 VP design questionnaires were returned (59.1%). Of the 310 students 213 chose to participate in the skills laboratory; 179 blended learning questionnaires were returned (84.0%). Students provided high overall acceptance ratings of the VP design and blended learning approach. By using VPs as preparation, skills laboratory time was felt to be used more effectively. Tutors perceived students as being well prepared for the skills laboratory with efficient uses of time. Conclusion The overall acceptance of the blended learning approach was high among students and tutors. VPs proved to be a convenient cognitive preparation tool for skills training. PMID:23402663

  20. Method and apparatus for reading thermoluminescent phosphors

    DOEpatents

    Braunlich, Peter F.; Tetzlaff, Wolfgang

    1987-01-01

    An apparatus and method for rapidly reading thermoluminescent phosphors to determine the amount of luminescent energy stored therein. The stored luminescent energy is interpreted as a measure of the total exposure of the thermoluminescent phosphor to ionizing radiation. The thermoluminescent phosphor reading apparatus uses a laser to generate a laser beam. The laser beam power level is monitored by a laser power detector and controlled to maintain the power level nearly constant. A shutter or other laser beam interrupting means is used to control exposure of the thermoluminescent phosphor to the laser beam. The laser beam can be equalized using an optical equalizer so that the laser beam has an approximately uniform power density across the beam. The heated thermoluminescent phosphor emits a visible or otherwise detectable luminescent emission which is measured as an indication of the radiation exposure of the thermoluminescent phosphors. Also disclosed are preferred signal processing and control circuits.

  1. Administration of Substances to Laboratory Animals: Equipment Considerations, Vehicle Selection, and Solute Preparation

    PubMed Central

    Turner, Patricia V; Pekow, Cynthia; Vasbinder, Mary Ann; Brabb, Thea

    2011-01-01

    Administration of substances to laboratory animals requires careful consideration and planning to optimize delivery of the agent to the animal while minimizing potential adverse experiences from the procedure. The equipment selected to deliver substances to animals depends on the length of the study and the nature of the material being administered. This selection provides a significant opportunity for refining animal treatment. Similarly, when substances are administered as solutions or suspensions, attention should be given to selection of vehicles and methods used for preparing the solutions and suspensions. The research team, veterinarian, technical personnel, and IACUC members should be aware of reasons underlying selection of equipment for substance delivery and should consider carefully how substances will be prepared and stored prior to administration to animals. Failure to consider these factors during experimental planning may result in unintentional adverse effects on experimental animals and confounded results. PMID:22330706

  2. The Principles of Phototransferred Thermoluminescence

    SciTech Connect

    Moscovitch, Marko

    2011-05-05

    The principles of phototransferred thermoluminescence (PTTL) are described, and some of the basic theoretical ideas underlying this technique are presented. It is demonstrated that the PTTL efficiency is dependent on the photon energy as well as on the activation energies of the various traps involved in the process. A simple two-traps-one-recombination-center model is capable of predicting a variety of different PTTL behaviors, some already were observed experimentally.

  3. Thermoluminescence dating of Hawaiian basalt

    USGS Publications Warehouse

    May, Rodd James

    1979-01-01

    The thermoluminescence (TL) properties of plagioclase separates from 11 independently dated alkalic basalts 4,500 years to 3.3 million years old and 17 tholeiitic basalts 16 years to 450,000 years old from the Hawaiian Islands were investigated for the purpose of developing a TL dating method for young volcanic rocks. Ratios of natural to artificial TL intensity, when normalized for natural radiation dose rates, were used to quantify the thermoluminescence response of individual samples for age-determination purposes. The TL ratios for the alkalic basalt plagioclase were found to increase with age at a predictable exponential rate that permits the use of the equation for the best-fit line through a plot of the TL ratios relative to known age as a TL age equation. The equation is applicable to rocks ranging in composition from basaltic andesite to trachyte over the age range from about 2,000 to at least 250,000 years before present (B.P.). The TL ages for samples older than 50,000 years have a calculated precision of less than :t 10 percent and a potential estimated accuracy relative to potassium-argon ages of approximately :t 10 percent. An attempt to develop a similar dating curve for the tholeiitic basalts was not as successful, primarily because the dose rates are on the average lower than those for the alkalic basalts by a factor of 6, resulting in lower TL intensities in the tholeiitic basalts for samples of equivalent age, and also because the age distribution of dated material is inadequate. The basic TL properties of the plagioclase from the two rock types are similar, however, and TL dating of tholeiitic basalts should eventually be feasible over the age range 10,000 to at least 200,000 years B.P. The average composition of the plagioclase separates from the alkalic basalts ranges from oligoclase to andesine; compositional variations within this range have no apparent effect on the TL ratios. The average composition of the plagioclase from the tholeiitic

  4. Teaching Technical and Professional Skills Using a Laboratory Exercise: A Comparison of Two Methods of Plasmid Preparation

    ERIC Educational Resources Information Center

    Brown, Lesley R.

    2006-01-01

    This laboratory exercise encourages upper level biochemistry students to build and expand upon previously developed laboratory skills and knowledge as they conduct a comparison of two methods of plasmid preparation based upon cost, quality of product, production time, and environmental impact. Besides creating an environment that mimics a more…

  5. Test plan for preparing the Rapid Transuranic Monitoring Laboratory for field deployment

    SciTech Connect

    McIsaac, C.V.; Sill, C.W.; Gehrke, R.J.; Killian, E.W.; Watts, K.D.

    1994-04-01

    This plan describes experimental work that will be performed during fiscal year 1994 to prepare the Rapid Transuranic Monitoring Laboratory (RTML) for routine field use by US Department of Energy (DOE) Environmental Restoration and Waste Management programs. The RTML is a mobile, field-deployable laboratory developed at the Idaho National Engineering Laboratory (INEL) that provides a rapid, cost-effective means of characterizing and monitoring radioactive waste remediation sites for low-level radioactive contaminants. Analytical instruments currently installed in the RTML include an extended-range, germanium photon analysis spectrometer with an automatic sample changer; two, large-area, ionization chamber alpha spectrometers; and four alpha continuous air monitors. The RTML was field tested at the INEL during June 1993 in conjunction with the Buried Waste Integrated Demonstration`s remote retrieval demonstration. The major tasks described in this test plan are to (a) evaluate the beta detectors for use in screening soil samples for {sup 90}Sr, (b) upgrade the alpha spectral analysis software programs, and (c) upgrade the photon spectral analysis software programs.

  6. Preparation and accreditation of anti-doping laboratories for the Olympic Games.

    PubMed

    Botrè, Francesco; Wu, Moutian; Boghosian, Thierry

    2012-07-01

    This article outlines the process of preparation of an anti-doping laboratory in view of the activities to be performed on the occasion of the Olympic Games, focusing in particular on the accreditation requirements of the World Anti-Doping Agency (WADA) and ISO/IEC 17025, as well as on the additional obligations required by the International Olympic Committee, which is the testing authority responsible for the anti-doping activities at the Olympics. Due to the elevated workload expected on the occasion of the Olympic Games, the designated anti-doping laboratory needs to increase its analytical capacity (samples processed/time) and capability by increasing the laboratory's resources in terms of space, instrumentation and personnel. Two representative cases, one related to the Winter Olympic Games (Torino 2006) and one related to the Summer Olympic Games (Beijing 2008), are presented in detail, in order to discuss the main aspects of compliance with both the WADA and ISO/IEC 17025 accreditation requirements. PMID:22831478

  7. Overview of the Hanford Environmental Thermoluminescent Dosimetry Program

    SciTech Connect

    Endres, A.W.; Peters, J.D.

    1993-01-01

    The Hanford Environmental Thermoluminescent Dosimetry Program has been in operation for 30 years. The program`s main goal is to report ambient penetrating radiation levels at specified locations on the Hanford Site and at nearby and distant communities. Dosimeter processing, dose calculation, and dose-reporting functions are provided by the Instrumentation and External Dosimetry section of the Pacific Northwest Laboratory`s Health Physics Department. This presentation provides a brief historical overview of dosimeter designs, processing procedures, dose-calculation methodologies, calibration techniques, and quality control.

  8. Thermoluminescence glow curve analysis and CGCD method for erbium doped CaZrO3 phosphor

    NASA Astrophysics Data System (ADS)

    Tiwari, Ratnesh; Chopra, Seema

    2016-05-01

    The manuscript report the synthesis, thermoluminescence study at fixed concentration of Er3+ (1 mol%) doped CaZrO3 phosphor. The phosphors were prepared by modified solid state reaction method. The powder sample was characterized by thermoluminescence (TL) glow curve analysis. In TL glow curve the optimized concentration in 1mol% for UV irradiated sample. The kinetic parameters were calculated by computerized glow curve deconvolution (CGCD) techniaue. Trapping parameters gives the information of dosimetry loss in prepared phosphor and its usability in environmental monitoring and for personal monitoring. CGCD is the advance tool for analysis of complicated TL glow curves.

  9. Method for detecting radiation dose utilizing thermoluminescent material

    DOEpatents

    Miller, S.D.; McDonald, J.C.; Eichner, F.N.; Durham, J.S.

    1992-08-04

    The amount of ionizing radiation to which a thermoluminescent material has been exposed is determined by first cooling the thermoluminescent material and then optically stimulating the thermoluminescent material by exposure to light. Visible light emitted by the thermoluminescent material as it is allowed to warm up to room temperature is detected and counted. The thermoluminescent material may be annealed by exposure to ultraviolet light. 5 figs.

  10. Method for detecting radiation dose utilizing thermoluminescent material

    DOEpatents

    Miller, Steven D.; McDonald, Joseph C.; Eichner, Fred N.; Tomeraasen, Paul L.

    1991-01-01

    The amount of ionizing radiation to which a thermoluminescent material has been exposed is determined by first cooling the thermoluminescent material to a cryogenic temperature. The thermoluminescent material is then optically stimulated by exposure to ultraviolet light. Visible light emitted by the thermoluminescent material as it is allowed to warm up to room temperature is detected and counted. The thermoluminescent material may be annealed by exposure to ultraviolet light.

  11. A thermoluminescent method for aerosol characterization

    NASA Technical Reports Server (NTRS)

    Long, E. R., Jr.; Rogowski, R. S.

    1976-01-01

    A thermoluminescent method has been used to study the interactions of aerosols with ozone. The preliminary results show that ozone reacts with many compounds found in aerosols, and that the thermoluminescence curves obtained from ozonated aerosols are characteristic of the aerosol. The results suggest several important applications of the thermoluminescent method: development of a detector for identification of effluent sources; a sensitive experimental tool for study of heterogeneous chemistry; evaluation of importance of aerosols in atmospheric chemistry; and study of formation of toxic, electronically excited species in airborne particles.

  12. Initial evaluation of Sandia National Laboratory-prepared crystalline silico-titanates for cesium recovery

    SciTech Connect

    Bray, L.A.; Carson, K.J.; Elovich, R.J.

    1993-10-01

    Pacific Northwest Laboratory initiated a study of a new class of inorganic ion exchange materials that selectively extracts cesium (Cs), strontium (Sr), and plutonium (Pu) from alkaline radioactive waste solutions. These materials, identified as crystalline silico-titanates (CST), were developed by scientists at the Sandia National Laboratory (SNL) and Texas A&M. This report summarizes preliminary results for the measurement of batch distribution coefficient (K{sub d}) values for the powdered CST materials compared to previously tested ion exchange materials: IONSIV IE-96 (a zeolite produced by UOP), CS-100 (an organic resin produced by Rohm and Haas), and BIB-DJ (a new resorcinol-formaldehyde organic resin produced by Boulder Scientific). Excellent results were obtained for CST inorganic exchangers that could be significant in the development of processes for the near-term pretreatment of Hanford alkaline wastes. The following observations and conclusions resulted from this study: (1) Several CST samples prepared at SNL had a higher capacity to remove Cs from solution as compared to BIB-DJ, IE-96, and CS-100. (2) Cesium distribution results showed that CST samples TAM-40, -42, -43, -70, and -74 had {lambda} values of {approximately}2,200 ({lambda} = Cs K{sub d} {times} {rho}{sub b}; where {lambda} represents the number of exchanger bed volumes of feed that can be loaded on an ion exchange column) at a pH value >14. (3) Cesium distribution values for CST exchangers doubled as the aqueous temperature decreased from 40{degrees} to 10{degrees}C. (4) Crystalline silico-titanates have the capacity to remove Cs as well as Sr and Pu from alkaline wastes unless organic complexants are present. Experimental results indicated that complexed Sr was not removed, and Pu is not expected to be removed.

  13. Kinetic parameters of some tissue equivalent thermoluminescence materials

    NASA Astrophysics Data System (ADS)

    Kitis, G.; Furetta, C.; Prokic, M.; Prokic, V.

    2000-06-01

    The paper reports a study on the kinetic parameters of some thermoluminescent tissue equivalent materials recently prepared in Vinca Institute: Li2B4O7:Mn,Si, Li2B4O7:Cu, Li2B4O7:Cu,In and MgB4O7:Dy,Na. The kinetics parameters have been determined using several methods. The temperature lag effect, which could produce large errors in the parameters' determination when they are determined using high heating rates, has also been taken into consideration.

  14. Overview of the Hanford Environmental Thermoluminescent Dosimetry Program

    SciTech Connect

    Endres, A.W.; Peters, J.D.

    1993-01-01

    The Hanford Environmental Thermoluminescent Dosimetry Program has been in operation for 30 years. The program's main goal is to report ambient penetrating radiation levels at specified locations on the Hanford Site and at nearby and distant communities. Dosimeter processing, dose calculation, and dose-reporting functions are provided by the Instrumentation and External Dosimetry section of the Pacific Northwest Laboratory's Health Physics Department. This presentation provides a brief historical overview of dosimeter designs, processing procedures, dose-calculation methodologies, calibration techniques, and quality control.

  15. Thermoluminescence property of nano scale Al2O3: C by combustion method

    NASA Astrophysics Data System (ADS)

    Bharthasaradhi, R.; Nehru, L. C.

    2016-05-01

    In this study, thermoluminescence dosimetry material of carbon doped aluminium oxide by combustion method using Aluminium nitrate and Glycine. The Structure of the prepared Sample was carried out by XRD. The sample was nano crystalline in nature. Having hexagonal structure with unit cell parameters a=4.75Å, C=12.99Å. The surface morphology of the prepared nanopowder was carried out through (SEM). The morphology of the prepared sample is platelet structure and functional group analysis carried out through FT-IR Spectrum. The prepared sample was irradiated through γ-ray CO60 (100Gy) was used as γ-ray source. The thermoluminescence glow curve of the irradiated sample showed an isolated peak at around 200°C. The result suggest the prepared nanopowder is suitable for medical radiation dosimetry.

  16. To the Geoportal and Beyond! Preparing the Earth Observing Laboratory's Datasets for Inter-Repository Discovery

    NASA Astrophysics Data System (ADS)

    Gordon, S.; Dattore, E.; Williams, S.

    2014-12-01

    Even when a data center makes it's datasets accessible, they can still be hard to discover if the user is unaware of the laboratory or organization the data center supports. NCAR's Earth Observing Laboratory (EOL) is no exception. In response to this problem and as an inquiry into the feasibility of inter-connecting all of NCAR's repositories at a discovery layer, ESRI's Geoportal was researched. It was determined that an implementation of Geoportal would be a good choice to build a proof of concept model of inter-repository discovery around. This collaborative project between the University of Illinois and NCAR is coordinated through the Data Curation Education in Research Centers program. This program is funded by the Institute of Museum and Library Services.Geoportal is open source software. It serves as an aggregation point for metadata catalogs of earth science datasets, with a focus on geospatial information. EOL's metadata is in static THREDDS catalogs. Geoportal can only create records from a THREDDS Data Server. The first step was to make EOL metadata more accessible by utilizing the ISO 19115-2 standard. It was also decided to create DIF records so EOL datasets could be ingested in NASA's Global Change Master Directory (GCMD). To offer records for harvest, it was decided to develop an OAI-PMH server. To make a compliant server, the OAI_DC standard was also implemented. A server was written in Perl to serve a set of static records. We created a sample set of records in ISO 19115-2, FGDC, DIF, and OAI_DC. We utilized GCMD shared vocabularies to enhance discoverability and precision. The proof of concept was tested and verified by having another NCAR laboratory's Geoportal harvest our sample set. To prepare for production, templates for each standard were developed and mapped to the database. These templates will help the automated creation of records. Once the OAI-PMH server is re-written in a Grails framework a dynamic representation of EOL

  17. Comparison of the microbial dynamics and biochemistry of laboratory sourdoughs prepared with grape, apple and yogurt.

    PubMed

    Gordún, Elena; del Valle, Luis J; Ginovart, Marta; Carbó, Rosa

    2015-09-01

    The microbiological culture-dependent characterization and physicochemical characteristics of laboratory sourdough prepared with grape (GS) were evaluated and compared with apple (AS) and yogurt (YS), which are the usual Spanish sourdough ingredients. Ripe GS took longer than AS and YS to reach the appropriate acidity and achieved lower values of lactic acid. In all sourdoughs, the lactic acid bacteria (LAB) increased during processing and were the dominant microorganisms (>1E+8 CFU/g). GS, as well as AS, had high diversity of LAB species. In ripe YS, Pediococcus pentosaceus was the only species identified; in GS and AS, several Lactobacilli were also found, Lb. plantarum, Lb. brevis, and Lb. sakei; in addition, in GS Weisella cibaria also appeared. Regarding the yeast population, non-Saccharomyces yeasts from GS and AS showed a very high specific population (>1E+7 CFU/g), but this was reduced in ripe sourdough (<1E+4 CFU/g). Finally, the Saccharomyces group dominated in all sourdoughs. Starting ingredients or raw material provided microbiological specificity to sourdoughs, and grape could be considered one of them. PMID:25008077

  18. Tips and traps in the 14C Bio-AMS preparation laboratory (WSam 7)

    SciTech Connect

    Buchholz, B A; Haack, K W; Stewart, P H; Vogel, J S

    1999-10-12

    Maintaining a contamination free sample preparation lab for biological 14 C AMS requires the same or more diligence as a radiocarbon dating prep lab. Isotope ratios of materials routinely range over 4-8 orders of magnitude in a single experiment, dosing solutions contain thousands of DPM and gels used to separate proteins possess 14 C ratios of 1pMC. Radiocarbon contamination is a legacy of earlier tracer work in most biological laboratories, even if they were never hot labs. Removable surface contamination can be found and monitored using swipes. Contamination can be found on any surface routinely touched: door knobs, light switches, drawer handles, water faucets. In general, all surfaces routinely touched need to be covered with paper, foil, or plastic that can be changed frequently. Shared air supplies can also present problems by distributing hot aerosols throughout a building. Aerosols can be monitored for 14 C content using graphitized coal or fullerene soot mixed with metal powder as an absorber. The monitors can be set out in work spaces for 1-2 weeks and measured by AMS with regular samples. Frequent air changes help minimize aerosol contamination in many cases. Cross contamination of samples can be minimized by using disposable plastic or glassware in the prep lab, isolating samples from the air when possible and using positive displacement pipetters.

  19. STAR: Preparing future science and math teachers through authentic research experiences at national laboratories

    NASA Astrophysics Data System (ADS)

    Keller, John; Rebar, Bryan

    2012-11-01

    The STEM Teacher and Researcher (STAR) Program provides 9-week paid summer research experiences at national research laboratories for future science and math teachers. The program, run by the Cal Poly Center for Excellence in Science and Mathematics Education (CESaME) on behalf of the entire California State University (CSU) System, has arranged 290 research internships for 230 STEM undergraduates and credential candidates from 43 campuses over the past 6 years. The program has partnered with seven Department of Energy labs, four NASA centers, three NOAA facilities, and the National Optical Astronomy Observatory (NOAO). Primary components of the summer experience include a) conducting research with a mentor or mentor team, b) participating in weekly 2-3 hour workshops focused on translating lessons learned from summer research into classroom practice, and c) presenting a research poster or oral presentation and providing a lesson plan linked to the summer research experience. The central premise behind the STAR Program is that future science and math teachers can more effectively prepare the next generation of science, math, and engineering students if they themselves have authentic experiences as researchers.

  20. A Guide for Planning Facilities for Occupational Preparation Programs for Dental Laboratory Technicians. Research Series No. 34.

    ERIC Educational Resources Information Center

    Macconnell, James D., And Others

    The twelfth in a series also including guides for facilities for medical x-ray technologist, medical assistant, and medical secretary programs, the document is intended for use in the preparation of educational specifications for facilities for dental laboratory technician programs. Designed for use by those responsible for planning facilities,…

  1. National and international standards and calibration of thermoluminescence dosimetry systems.

    PubMed

    Soares, C G

    2002-01-01

    Radiation protection for radiation workers, the public, and the environment is of international concern. The use of thermoluminescence dosemeters (TLD) is an acceptable method for dose recording in most countries. For reasons of consistency and data gathering (research) it is important that a Sievert (Sv) in one part of the world equals an Sv on the other side of the globe. To this end, much work has gone into the development of standards and calibration practices for TLD systems so that they compare not only with similar systems, but also with other forms of radiation measurement. While most national laboratories provide calibration services for these systems some, as in the United States, depend on services of secondary calibration laboratories that are traceable to the national laboratories through accreditation programmes. The purpose of this paper is to explain how TLD measurements are traceable to their respective national standards for both personnel and environmental dosimetry. PMID:12382728

  2. Integration of Video-Based Demonstrations to Prepare Students for the Organic Chemistry Laboratory

    ERIC Educational Resources Information Center

    Nadelson, Louis S.; Scaggs, Jonathan; Sheffield, Colin; McDougal, Owen M.

    2015-01-01

    Consistent, high-quality introductions to organic chemistry laboratory techniques effectively and efficiently support student learning in the organic chemistry laboratory. In this work, we developed and deployed a series of instructional videos to communicate core laboratory techniques and concepts. Using a quasi-experimental design, we tested the…

  3. Thermoluminescence of magnesium aluminum spinel

    NASA Astrophysics Data System (ADS)

    Kim, Taekyu; Whang, Chungnam; Sakurai, Takao

    Three-dimensional thermoluminescence (TL) spectra of MgAl2O4 spinel exposed to UV light showed a TL peak with a 710nm emission band at 472K and another peak with 520nm around 490K. The algorithm of the numerical analysis based on the model of 2 recombination centers had been developed for TL glow curves of MgAl2O4. The best-fit activation energy and frequency factor were determined as 0.61 eV and 3.75 × 104s-1, respectively, with the chi squared value of 0.010073. On the contrary, the parameters fitted by the conventional theory were the activation energy of 0.66 eV and the frequency factor of 1.25 × 105s-1 with the chi squared value of 0.01358. For TL of MgAl2O4, the model of 2 recombination centers gave a better fit than the conventional theory.

  4. An Integrated Laboratory Approach toward the Preparation of Conductive Poly(phenylene vinylene) Polymers

    ERIC Educational Resources Information Center

    Knoerzer, Timm A.; Balaich, Gary J.; Miller, Hannah A.; Iacono, Scott T.

    2014-01-01

    Poly(phenylene vinylene) (PPV) represents an important class of conjugated, conducting polymers that have been readily exploited in the preparation of organic electronic materials. In this experiment, students prepare a PPV polymer via a facile multistep synthetic sequence with robust spectroscopic evaluation of synthetic intermediates and the…

  5. Thermoluminescence measurement technique using millisecond temperature pulses.

    PubMed

    Manfred, Michael E; Gabriel, Nicholas T; Yukihara, Eduardo G; Talghader, Joseph J

    2010-06-01

    A measurement technique, pulsed thermoluminescence, is described which uses short thermal pulses to excite trapped carriers leading to radiative recombination. The pulses are obtained using microstructures with approximately 500 micros thermal time constants. The technique has many of the advantages of pulsed optically stimulated luminescence without the need for optical sources and filters to isolate the luminescent signal. Charge carrier traps in alpha-Al(2)O(3):C particles on microheaters were filled using 205 nm light. Temperature pulses of 10 and 50 ms were applied to the heaters and compared with a standard thermoluminescence curve taken at a ramp rate of 5 K s(-1). This produced curves of intensity verses temperature similar to standard thermoluminescence except shifted to higher temperatures. The luminescence of single particles was read multiple times with negligible loss of population. The lower limit of the duration of useful pulses appears to be limited by particle size and thermal contact between the particle and heater. PMID:20522565

  6. Evaluation of seamless ligation cloning extract preparation methods from an Escherichia coli laboratory strain.

    PubMed

    Okegawa, Yuki; Motohashi, Ken

    2015-10-01

    Seamless ligation cloning extract (SLiCE) is a simple and efficient method for DNA cloning without the use of restriction enzymes. Instead, SLiCE uses homologous recombination activities from Escherichia coli cell lysates. To date, SLiCE preparation has been performed using an expensive commercially available lytic reagent. To expand the utility of the SLiCE method, we evaluated different methods for SLiCE preparation that avoid using this reagent. Consequently, cell extracts prepared with buffers containing Triton X-100, which is a common and low-cost nonionic detergent, exhibited sufficient cloning activity for seamless gene incorporation into a vector. PMID:26133399

  7. Preparing the Biochemistry Laboratory for the Next Outbreak: Lessons from SARS in Singapore

    PubMed Central

    2005-01-01

    Severe acute respiratory syndrome (SARS) is an emerging disease characterised by fever and atypical pneumonia and caused by a novel coronavirus. Singapore was affected by the global pandemic in early 2003, with 238 cases and 33 deaths. Samples sent to the biochemistry laboratory made up the majority (69%) of all SARS samples, yet remained a minority (29%) of total biochemistry workload. This paper describes the problems encountered and solutions adopted by the biochemistry laboratory at the designated SARS hospital in coping with this epidemic. It provides practical advice for laboratories planning for the handling of samples from future outbreaks. PMID:16450013

  8. Rock cooling history using thermoluminescence of natural radiation dosimeter

    NASA Astrophysics Data System (ADS)

    Biswas, Rabiul; Herman, Frederic

    2016-04-01

    Recently, optical luminescences from quartz and feldspar have been proposed to have great potential in low temperature thermochronology (<100°C). The present study aims to explore thermoluminescence (TL) of feldspar to determine cooling history of rock. The advantage of thermoluminescence over optical luminesce is single TL glow curve has different thermal and athermal stability at different temperature of the glow curve, which can be determined by computerized glow curve deconvolution (CGCD) method and estimation of rate of anomalous fading in the laboratory. The rock samples were collected from Alex Knob of Franz Josef glacier, New Zealand, which is expected to be one of the rapidly exhuming settings in Southern Alps. The natural luminescence levels, which are in the dynamic equilibrium because of competition between growth due to ambient radioactivity and decay due thermal and athermal loss, are determined using multiple aliquot regeneration (MAR) protocol. Multiple thermal signals with wide range of thermal stability, extracted from composite glow curve, particularly low temperature part which is more sensitive to ambient temperature, is promising for better constraint on late stage cooling history.

  9. Correlation between thermoluminescence and radiation damage in bismuth germanate

    SciTech Connect

    Melcher, C.L.

    1985-02-01

    Thermoluminescence properties of bismuth germanate and their relationship to radiation damage characteristics have been investigated. Thermoluminescence and radiation damage in bismuth germanate display several similar properties including similar responses as a function of radiation dose, similar saturation levels, and similar decay times. Also a correlation was found between the thermoluminescence sensitivities and radiation damage sensitivities of four different crystals. The traps responsible for the radiation damage and those which store the thermoluminescence signal appear to be either closely related or actually the same traps. Four trapping centers can be seen in the thermoluminescence glow curves. The depth of the dominant trap is 1.1 eV. 10 references.

  10. Natural thermoluminescence of Antarctic meteorites and related studies

    NASA Technical Reports Server (NTRS)

    Benoit, Paul H.; Sears, Derek W. G.

    1998-01-01

    The natural thermoluminescence (TL) laboratory's primary purpose is to provide data on newly recovered Antarctic meteorites that can be included in discovery announcements and to investigate the scientific implications of the data. Natural TL levels of meteorites are indicators of recent thermal history and terrestrial history, and the data can be used to study the orbital/radiation history of groups of meteorites (e.g., H chondrites) or to study the processes leading to the concentration of meteorites at certain sites in Antarctica. An important application of these data is the identification of fragments, or "pairs" of meteorites produced during atmospheric passage or during terrestrial weathering. Thermoluminescence data are particularly useful for pairing within the most common meteorite classes, which typically exhibit very limited petrographic and chemical diversity. Although not originally part of the laboratory's objectives, TL data are also useful in the identification and classification of petrographically or mineralogically unusual meteorites, including unequilibrated ordinary chondrites and some basaltic achondrites. In support of its primary mission, the laboratory also engages in TL studies of modern falls, finds from hot deserts, and terrestrial analogs and conducts detailed studies of the TL properties of certain classes of meteorites. These studies include the measurement of TL profiles in meteorites, the determination of TL levels of finds from the Sahara and the Nullarbor region of Australia, and comparison of TL data to other indicators of irradiation or terrestrial history, such as cosmogenic noble gas and radionuclide abundances. Our current work can be divided into five subcategories, (a) TL survey of Antarctic meteorites, (b) pairing and field relations of Antarctic meteorites, (c) characterization of TL systematics of meteorites, (d) comparison of natural TL and other terrestrial age indicators for Antarctic meteorites, and for meteorites

  11. Analytical Chemistry Laboratory (ACL) procedure compendium. Volume 2, Sample preparation methods

    SciTech Connect

    Not Available

    1993-08-01

    This volume contains the interim change notice for sample preparation methods. Covered are: acid digestion for metals analysis, fusion of Hanford tank waste solids, water leach of sludges/soils/other solids, extraction procedure toxicity (simulate leach in landfill), sample preparation for gamma spectroscopy, acid digestion for radiochemical analysis, leach preparation of solids for free cyanide analysis, aqueous leach of solids for anion analysis, microwave digestion of glasses and slurries for ICP/MS, toxicity characteristic leaching extraction for inorganics, leach/dissolution of activated metal for radiochemical analysis, extraction of single-shell tank (SST) samples for semi-VOC analysis, preparation and cleanup of hydrocarbon- containing samples for VOC and semi-VOC analysis, receiving of waste tank samples in onsite transfer cask, receipt and inspection of SST samples, receipt and extrusion of core samples at 325A shielded facility, cleaning and shipping of waste tank samplers, homogenization of solutions/slurries/sludges, and test sample preparation for bioassay quality control program.

  12. Dating volcanic ash by use of thermoluminescence

    SciTech Connect

    Berger, G.W. )

    1992-01-01

    The fine-silt-sized (4-11 {mu}m) grains of glass separated from four samples of independently dated, 8 to 400 ka, tephra beds provide accurate thermoluminescence (TL) ages. This demonstration of reliable TL dating of volcanic glass provides a new tephrochronometer for deposits spanning the Holocene to middle Pleistocene age range.

  13. Thermoluminescence dosimeters with narrow bandpass filters

    SciTech Connect

    Walker, Scottie W.

    2004-07-20

    A dosimetry method exposes more than one thermoluminescence crystals to radiation without using conventional filters, and reads the energy stored in the crystals by converting the energy to light in a conventional manner, and then filters each crystal output in a different portion of the spectrum generated by the crystals.

  14. Clinical Chemistry Laboratory Automation in the 21st Century - Amat Victoria curam (Victory loves careful preparation)

    PubMed Central

    Armbruster, David A; Overcash, David R; Reyes, Jaime

    2014-01-01

    The era of automation arrived with the introduction of the AutoAnalyzer using continuous flow analysis and the Robot Chemist that automated the traditional manual analytical steps. Successive generations of stand-alone analysers increased analytical speed, offered the ability to test high volumes of patient specimens, and provided large assay menus. A dichotomy developed, with a group of analysers devoted to performing routine clinical chemistry tests and another group dedicated to performing immunoassays using a variety of methodologies. Development of integrated systems greatly improved the analytical phase of clinical laboratory testing and further automation was developed for pre-analytical procedures, such as sample identification, sorting, and centrifugation, and post-analytical procedures, such as specimen storage and archiving. All phases of testing were ultimately combined in total laboratory automation (TLA) through which all modules involved are physically linked by some kind of track system, moving samples through the process from beginning-to-end. A newer and very powerful, analytical methodology is liquid chromatography-mass spectrometry/mass spectrometry (LC-MS/MS). LC-MS/MS has been automated but a future automation challenge will be to incorporate LC-MS/MS into TLA configurations. Another important facet of automation is informatics, including middleware, which interfaces the analyser software to a laboratory information systems (LIS) and/or hospital information systems (HIS). This software includes control of the overall operation of a TLA configuration and combines analytical results with patient demographic information to provide additional clinically useful information. This review describes automation relevant to clinical chemistry, but it must be recognised that automation applies to other specialties in the laboratory, e.g. haematology, urinalysis, microbiology. It is a given that automation will continue to evolve in the clinical laboratory

  15. Clinical Chemistry Laboratory Automation in the 21st Century - Amat Victoria curam (Victory loves careful preparation).

    PubMed

    Armbruster, David A; Overcash, David R; Reyes, Jaime

    2014-08-01

    The era of automation arrived with the introduction of the AutoAnalyzer using continuous flow analysis and the Robot Chemist that automated the traditional manual analytical steps. Successive generations of stand-alone analysers increased analytical speed, offered the ability to test high volumes of patient specimens, and provided large assay menus. A dichotomy developed, with a group of analysers devoted to performing routine clinical chemistry tests and another group dedicated to performing immunoassays using a variety of methodologies. Development of integrated systems greatly improved the analytical phase of clinical laboratory testing and further automation was developed for pre-analytical procedures, such as sample identification, sorting, and centrifugation, and post-analytical procedures, such as specimen storage and archiving. All phases of testing were ultimately combined in total laboratory automation (TLA) through which all modules involved are physically linked by some kind of track system, moving samples through the process from beginning-to-end. A newer and very powerful, analytical methodology is liquid chromatography-mass spectrometry/mass spectrometry (LC-MS/MS). LC-MS/MS has been automated but a future automation challenge will be to incorporate LC-MS/MS into TLA configurations. Another important facet of automation is informatics, including middleware, which interfaces the analyser software to a laboratory information systems (LIS) and/or hospital information systems (HIS). This software includes control of the overall operation of a TLA configuration and combines analytical results with patient demographic information to provide additional clinically useful information. This review describes automation relevant to clinical chemistry, but it must be recognised that automation applies to other specialties in the laboratory, e.g. haematology, urinalysis, microbiology. It is a given that automation will continue to evolve in the clinical laboratory

  16. Synthesis of a 7-Oxanorbornene Monomer: A Two-Step Sequence Preparation for the Organic Laboratory

    NASA Astrophysics Data System (ADS)

    France, Marcia B.; Alty, Lisa T.; Markley Earl, T.

    1999-05-01

    We have developed a two-step synthetic sequence for our introductory organic laboratory that demonstrates key reactions that the students learn concurrently in the lecture portion of their organic chemistry course. It represents the Diels-Alder reaction and solvolysis of an anhydride accompanied by Fischer esterification. Both of these steps produce crystals in a dramatic manner that catches the students' attention. This sequence can stand on its own as part of an organic laboratory, or the product can be utilized as a monomer for ring-opening metathesis polymerization (ROMP) studies.

  17. Preparation for microgravity - The role of the Microgravity Material Science Laboratory

    NASA Technical Reports Server (NTRS)

    Johnston, J. Christopher; Rosenthal, Bruce N.; Meyer, Maryjo B.; Glasgow, Thomas K.

    1988-01-01

    Experiments at the NASA Lewis Research Center's Microgravity Material Science Laboratory using physical and mathematical models to delineate the effects of gravity on processes of scientific and commercial interest are discussed. Where possible, transparent model systems are used to visually track convection, settling, crystal growth, phase separation, agglomeration, vapor transport, diffusive flow, and polymer reactions. Materials studied include metals, alloys, salts, glasses, ceramics, and polymers. Specific technologies discussed include the General Purpose furnace used in the study of metals and crystal growth, the isothermal dendrite growth apparatus, the electromagnetic levitator/instrumented drop tube, the high temperature directional solidification furnace, the ceramics and polymer laboratories and the center's computing facilities.

  18. Preparation of Semiconducting Materials in the Laboratory, Part 3: The One-Penny Photovoltaic Cell

    ERIC Educational Resources Information Center

    Ibanez, Jorge G.; Finck-Pastrana, Adolfo; Mugica-Barrera, Alejandra; Balderas-Hernandez, Patricia; Ibarguengoitia-Cervantes, Martha E.; Garcia-Pintor, Elizabeth; Hartasanchez-Frenk, Jose Miguel; Bonilla-Jaurez, Cesar E.; Maldonado-Cordero, Casandra; Struck-Garza, Adelwart; Suberbie-Rocha, Felipe

    2011-01-01

    Copper(I) oxide photoresponsive layers are prepared on copper surfaces (e.g., U.S. pre-1982 pennies) by simple thermal, chemical, and electrochemical procedures. An easily measurable photovoltage (up to 100 mV) is obtained in each case under visible light illumination. (Contains 2 figures.)

  19. Sedimentation Coefficient, Frictional Coefficient, and Molecular Weight: A Preparative Ultracentrifuge Experiment for the Advanced Undergraduate Laboratory.

    ERIC Educational Resources Information Center

    Halsall, H. B.; Wermeling, J. R.

    1982-01-01

    Describes an experiment using a high-speed preparative centrifuge and calculator to demonstrate effects of the frictional coefficient of a macromolecule on its rate of transport in a force field and to estimate molecular weight of the macromolecule using an empirical relationship. Background information, procedures, and discussion of results are…

  20. Preparation and Analysis of Libethenite: A Project for the First-Year Laboratory

    ERIC Educational Resources Information Center

    Ginion, Kelly E.; Yoder, Claude H.

    2004-01-01

    The preparation of libethenite, a double salt of copper(II) phosphate and copper(II) hydroxide presents the opportunity to discuss the prevalence of double salts in the environment, the relationship between solubility and stability in aqueous solution, the origin of the color of transition metal compounds and gravimetric analyses. Typical results…

  1. To What Extent Does A-Level Physics Prepare Students for Undergraduate Laboratory Work?

    ERIC Educational Resources Information Center

    Thompson, Alaric

    2012-01-01

    This paper is a summary of a small-scale research project carried out to investigate the transition from A-level to university physics, with a specific focus on practical or laboratory skills. A brief description of the methods used precedes the headline findings of the research. A non-evidential discussion of the possible reasons behind any…

  2. Preparation of Pre-Service Science Teachers in the Use of Alternate Laboratory Teacher Behaviors.

    ERIC Educational Resources Information Center

    Rezba, Richard James

    An attempt was made to develop an appropriate teaching model to aid perspective science teachers acquire teaching skills and behavioral patterns appropriate for inquiry-oriented laboratory activities and experiments. Data were collected from two groups of secondary science methods students on their verbal behavior while in the role of laboratory…

  3. A Laboratory Preparation of Aspartame Analogs Using Simultaneous Multiple Parallel Synthesis Methodology

    ERIC Educational Resources Information Center

    Qvit, Nir; Barda, Yaniv; Gilon, Chaim; Shalev, Deborah E.

    2007-01-01

    This laboratory experiment provides a unique opportunity for students to synthesize three analogues of aspartame, a commonly used artificial sweetener. The students are introduced to the powerful and useful method of parallel synthesis while synthesizing three dipeptides in parallel using solid-phase peptide synthesis (SPPS) and simultaneous…

  4. Laboratory Studies of Lead Removal from Liquid Scintillator in Preparation for KamLAND's Low Background Phase

    SciTech Connect

    Keefer, Gregory

    2011-04-27

    The removal of Radon induced Lead from liquid scintillator was extensively studied in preparation for KamLAND's low background phase. This work presents the results from laboratory experiments performed at the University of Alabama and their implications for KamLAND and future low background experiments using carbon based liquid scintillator. It was observed that distillation was the most effective purification procedure and that one must consider a non-polar and non-ionic component of Lead in order to reach the levels of radio-purity required for these new class of ultra-low background experiments.

  5. Simulated Waste for Leaching and Filtration Studies--Laboratory Preparation Procedure

    SciTech Connect

    Smith, Harry D.; Russell, Renee L.; Peterson, Reid A.

    2009-10-27

    This report discusses the simulant preparation procedure for producing multi-component simulants for leaching and filtration studies, including development and comparison activities in accordance with the test plan( ) prepared and approved in response to the Test Specification 24590-WTP-TSP-RT-06-006, Rev 0 (Smith 2006). A fundamental premise is that this approach would allow blending of the different components to simulate a wide variety of feeds to be treated in the Hanford Tank Waste Treatment and Immobilization Plant (WTP). For example, a given feed from the planned feed vector could be selected, and the appropriate components would then be blended to achieve a representation of that particular feed. Using the blending of component simulants allows the representation of a much broader spectrum of potential feeds to the Pretreatment Engineering Platform (PEP).

  6. PREPARATIONS FOR ASSEMBLY OF THE INTERNATIONAL ERL CRYOMODULE AT DARESBURY LABORATORY

    SciTech Connect

    McIntosh, P. A.; Bate, R.; Beard, C. D.; Cordwell, M. A.; Dykes, D. M.; Pattalwar, S. M.; Strachan, J.; Belomestnykh, S.; Liepe, M.; Padamsee, H.; Quigley, P.; Sears, J.; Shemelin, V.; Veshcherevich, V.; Proch, D.; Sekutowicz, J.; Buchner, A.; Gabriel, F.; Michel, P.; Corlett, J. N.; Li, D.; Lidia, S.; Kimura, T.; Smith, T. I.

    2009-04-29

    The collaborative development of an optimised cavity/cryomodule solution for application on ERL facilities has now progressed to final assembly and testing of the cavity string components and their subsequent cryomodule integration. This paper outlines the verification of the various cryomodule sub-components and details the processes utilised forfinal cavity string integration. The paper also describes the modifications needed to facilitate this new cryomodule installation and ultimate operation on the ALICE facility at Daresbury Laboratory.

  7. Radiation and Health Technology Laboratory Capabilities

    SciTech Connect

    Goles, Ronald W.; Johnson, Michelle Lynn; Piper, Roman K.; Peters, Jerry D.; Murphy, Mark K.; Mercado, Mike S.; Bihl, Donald E.; Lynch, Timothy P.

    2003-07-15

    The Radiological Standards and Calibrations Laboratory, a part of Pacific Northwest National Laboratory (PNNL)(a) performs calibrations and upholds reference standards necessary to maintain traceability to national standards. The facility supports U.S. Department of Energy (DOE) programs at the Hanford Site, programs sponsored by DOE Headquarters and other federal agencies, radiological protection programs at other DOE and commercial nuclear sites and research and characterization programs sponsored through the commercial sector. The laboratory is located in the 318 Building of the Hanford Site's 300 Area. The facility contains five major exposure rooms and several laboratories used for exposure work preparation, low-activity instrument calibrations, instrument performance evaluations, instrument maintenance, instrument design and fabrication work, thermoluminescent and radiochromic Dosimetry, and calibration of measurement and test equipment (M&TE). The major exposure facilities are a low-scatter room used for neutron and photon exposures, a source well room used for high-volume instrument calibration work, an x-ray facility used for energy response studies, a high-exposure facility used for high-rate photon calibration work, a beta standards laboratory used for beta energy response studies and beta reference calibrations and M&TE laboratories. Calibrations are routinely performed for personnel dosimeters, health physics instrumentation, photon and neutron transfer standards alpha, beta, and gamma field sources used throughout the Hanford Site, and a wide variety of M&TE. This report describes the standards and calibrations laboratory.

  8. Radiation and Health Technology Laboratory Capabilities

    SciTech Connect

    Bihl, Donald E.; Lynch, Timothy P.; Murphy, Mark K.; Myers, Lynette E.; Piper, Roman K.; Rolph, James T.

    2005-07-09

    The Radiological Standards and Calibrations Laboratory, a part of Pacific Northwest National Laboratory (PNNL)(a) performs calibrations and upholds reference standards necessary to maintain traceability to national standards. The facility supports U.S. Department of Energy (DOE) programs at the Hanford Site, programs sponsored by DOE Headquarters and other federal agencies, radiological protection programs at other DOE and commercial nuclear sites and research and characterization programs sponsored through the commercial sector. The laboratory is located in the 318 Building of the Hanford Site's 300 Area. The facility contains five major exposure rooms and several laboratories used for exposure work preparation, low-activity instrument calibrations, instrument performance evaluations, instrument maintenance, instrument design and fabrication work, thermoluminescent and radiochromic Dosimetry, and calibration of measurement and test equipment (M&TE). The major exposure facilities are a low-scatter room used for neutron and photon exposures, a source well room used for high-volume instrument calibration work, an x-ray facility used for energy response studies, a high-exposure facility used for high-rate photon calibration work, a beta standards laboratory used for beta energy response studies and beta reference calibrations and M&TE laboratories. Calibrations are routinely performed for personnel dosimeters, health physics instrumentation, photon and neutron transfer standards alpha, beta, and gamma field sources used throughout the Hanford Site, and a wide variety of M&TE. This report describes the standards and calibrations laboratory.

  9. A study of the Perkin-Elmer laboratory robotic system for analytical sample preparation

    SciTech Connect

    Hartenstein, S.D.; Delmastro, J.R.

    1988-09-01

    The purpose of this study was to evaluate the abilities of a Perkin-Elmer (PE) robotic system in performing complex analytical sample preparation procedures. Until this time, reports have been written describing the physical capabilities of the robotic arm marketed by PE and the use of this arm in a pick-and-place application at the Idaho Chemical Processing Plant (ICPP). Since the robotic arm is only capable of handling and transporting objects, the ability of the PE system is dependent upon the performance capabilities of the auxiliary devices marketed with the arm. 2 refs., 2 figs., 1 tab.

  10. Preparing the next generation of genomicists: a laboratory-style course in medical genomics.

    PubMed

    Linderman, Michael D; Bashir, Ali; Diaz, George A; Kasarskis, Andrew; Sanderson, Saskia C; Zinberg, Randi E; Mahajan, Milind; Shah, Hardik; Suckiel, Sabrina; Zweig, Micol; Schadt, Eric E

    2015-01-01

    The growing gap between the demand for genome sequencing and the supply of trained genomics professionals is creating an acute need to develop more effective genomics education. In response we developed "Practical Analysis of Your Personal Genome", a novel laboratory-style medical genomics course in which students have the opportunity to obtain and analyze their own whole genome. This report describes our motivations for and the content of a "practical" genomics course that incorporates personal genome sequencing and the lessons we learned during the first three iterations of this course. PMID:26264128

  11. Preparation and characterization of a laboratory scale selenomethionine-enriched bread. Selenium bioaccessibility.

    PubMed

    Sánchez-Martínez, María; Pérez-Corona, Teresa; Caímara, Carmen; Madrid, Yolanda

    2015-01-14

    This study focuses on the preparation at lab scale of selenomethionine-enriched white and wholemeal bread. Selenium was supplemented either by adding selenite directly to the dough or by using lab-made selenium-enriched yeast. The best results were obtained when using fresh selenium-enriched yeast. The optimum incubation time for selenomethionine-enriched yeast preparation, while keeping formation of selenium byproducts to a minimum, was 96 h. Selenium content measured by isotope dilution analysis (IDA)-ICP-MS in Se-white and Se-wholemeal bread was 1.28 ± 0.02 μg g–1 and 1.16 ± 0.02 μg g–1 (expressed as mean ± SE, 3 replicates), respectively. HPLC postcolumn IDA-ICP-MS measurements revealed that selenomethionine was the main Se species found in Se-enriched bread, which accounted for ca. 80% of total selenium. In vitro gastrointestinal digestion assay provided selenium bioaccessibility values of 100 ± 3% and 40 ± 1% for white and wholemeal Se-enriched bread, respectively, being selenomethionine the main bioaccessible Se species in white bread, while in wholemeal bread this compound was undetectable. PMID:25555185

  12. Quantitative morphological and compositional evaluation of laboratory prepared aluminoborosilicate glass surfaces

    NASA Astrophysics Data System (ADS)

    Gong, Yuxuan; Wren, Anthony W.; Mellott, Nathan P.

    2015-01-01

    Surface finishing techniques including polishing, etching and heat treatment can modify the topography and the surface chemical composition of glasses. It is widely acknowledged that atomic force microscopy (AFM) can be used to quantify the morphology of surfaces, providing various parameters including average, peak-to-valley, and apparent root-mean-square roughness. Furthermore advanced power spectral density (PSD) analysis of AFM-derived surface profiles offers quantification of the spatial homogeneity of roughness values along different wavelengths, resulting in parameters including equivalent RMS, Hurst exponent, and fractal dimension. Outermost surface (∼8 nm) chemical composition can be quantitatively measured by X-ray photoelectron spectroscopy. In this paper, we first developed a series of surface finishing methods for an aluminoborosilicate glass system by polishing, etching or heat treatment. The chemical composition and environment of prepared glass surfaces were quantified by XPS and topographical analysis was carried out by fractal and k-correlation model fitting of PSD profiles derived via AFM. The chemical environment of elements, as determined via XPS, present on the prepared surfaces are similar to those within the pristine bulk glass. The compositional evolution of polished and melt surfaces are discussed in context of corrosion phenomena associated with the grinding, polishing, and etching of surfaces and the thermal heat treatment utilized for processing, respectively. Good correlation between surface finishing methods, chemical composition and topographical parameters were observed. More importantly, extensive discussions on topographical parameters including equivalent RMS, Hurst exponent, and fractal dimension are presented as a function of processing method.

  13. Preparing Los Alamos National Laboratory's Waste Management Program for the Future - 12175

    SciTech Connect

    Jones, Scotty W.; Dorries, Alison M.; Singledecker, Steven; Henckel, George

    2012-07-01

    The waste management program at Los Alamos National Laboratory (LANL) is undergoing significant transition to establish a lean highly functioning waste management program that will succeed the large environmental cleanup waste management program. In the coming years, the environmental cleanup activities will be mostly completed and the effort will change to long-term stewardship. What will remain in waste management is a smaller program focused on direct off-site shipping to cost-effectively enable the enduring mission of the laboratory in support of the national nuclear weapons program and fundamental science and research. It is essential that LANL implement a highly functioning efficient waste management program in support of the core missions of the national weapons program and fundamental science and research - and LANL is well on the way to that goal. As LANL continues the transition process, the following concepts have been validated: - Business drivers including the loss of onsite disposal access and completion of major environmental cleanup activities will drive large changes in waste management strategies and program. - A well conceived organizational structure; formal management systems; a customer service attitude; and enthusiastic managers are core to a successful waste management program. - During times of organizational transition, a project management approach to managing change in a complex work place with numerous complex deliverables is successful strategy. - Early and effective engagement with waste generators, especially Project Managers, is critical to successful waste planning. - A well-trained flexible waste management work force is vital. Training plans should include continuous training as a strategy. - A shared fate approach to managing institutional waste decisions, such as the LANL Waste Management Recharge Board is effective. - An efficient WM program benefits greatly from modern technology and innovation in managing waste data and

  14. Issues to consider for preparing ferrets as research subjects in the laboratory.

    PubMed

    Ball, Roberta Scipioni

    2006-01-01

    The domestic or European ferret (Mustela putorius furo) has been domesticated for thousands of years. Ferrets have been used for hunting and fur production, as pets, and as models in biomedical research. Despite the relatively small numbers used in the laboratory, ferrets have some unique applications including study of human influenza and severe acute respiratory syndrome (SARS)-associated corona virus. They have served as models for peptic ulcer disease, carotenoid metabolism, cystic fibrosis, and drug emesis screening, among others. Most research ferrets are males, due to estrus-related health problems in females. They may be housed conventionally and are easy to care for when their biology and behavior are understood. Due to the small number of ferret suppliers, animals are often shipped long distances, requiring air transport and intermediate handlers. It is important to minimize shipment stress, especially with weanling and pregnant animals. Additional expertise is required for success with pregnant and whelping ferrets and for rearing of neonates. The animals have specific dietary requirements, and proper nutrition is key. Successful housing requires knowledge of ferret behaviors including social behavior, eating habits, a general inquisitive nature, and a species-typical need to burrow and hide. Regular handling is necessary to maintain well-being. A ferret health care program consists of physical examination, immunization, clinical pathology, and a working knowledge of common ferret diseases. Various research methodologies have been described, from basic procedures such as blood collection to major invasive survival surgery. Ferrets have a distinct niche in biomedical research and are hardy animals that thrive well in the laboratory. PMID:16963814

  15. Photoluminescence and thermoluminescence studies of CaAl2O4:Dy(3+) phosphor.

    PubMed

    Ziyauddin, Mohammad; Tigga, Shalinta; Brahme, Nameeta; Bisen, D P

    2016-02-01

    Calcium aluminate phosphors activated by Dy(3+) have been prepared by a combustion method at a temperature of 600°C. Photoluminescence (PL) and thermoluminescence (TL) properties of gamma-irradiated Dy-doped calcium aluminate were investigated. The PL spectrum shows a broad peak around 488 nm and 573 nm, under 347 nm excitation. Thermoluminescence studies were performed for different concentrations of Dy. Optimum intensity of photoluminescence was found for 0.02 mol% concentration of Dy. It was found that initially the peak TL intensity increases with increasing concentration of Dy in the CaAl2O4 host, attains a maximum value for 0.05 mol% concentration and decreases with further increase in the doping concentration due to concentration quenching. PMID:25920456

  16. A laboratory modification to testicular sperm preparation technique improves spermatogenic cell yield.

    PubMed

    Ozkavukcu, Sinan; Ibis, Ebru; Kizil, Sule; Isbacar, Suheyla; Aydos, Kaan

    2014-01-01

    Testicular sperm extraction is a common procedure used to find spermatogenic cells in men with nonobstructive azoospermia. The laboratory processing of biopsied testicular tissues needs to be performed meticulously to acquire a high yield of cells. In this study, the effectiveness of mincing the tissues after testicular biopsy was assessed using histological evaluation, as was the possible adverse effect of residual tissue on the migration of spermatogenic cells during density gradient centrifugation. Our results indicate that testicular residual tissue, when laid on the density gradient medium along with the sperm wash, hinders the spermatogenic cells' forming a pellet during centrifugation, and therefore impairs the intracytoplasmic sperm injection procedure. Whereas the mean number of recovered cells from the sperm wash medium (SWM) with residual tissue is 39.435 ± 24.849, it was notably higher (60.189 ± 28.214 cells) in the SWM without minced tissues. The remaining tissue contained no functional seminiferous tubules or spermatogenic cells in histological sections. In conclusion, the remaining residual tissue after mincing biopsied testicular tissue does not add any functional or cellular contribution to spermatogenic cell retrieval; in fact, it may block the cellular elements in the accompanying cell suspension from migrating through the gradient layers to form a pellet during centrifugation and cause loss of spermatogenic cells. PMID:25038178

  17. A laboratory modification to testicular sperm preparation technique improves spermatogenic cell yield

    PubMed Central

    Ozkavukcu, Sinan; Ibis, Ebru; Kizil, Sule; Isbacar, Suheyla; Aydos, Kaan

    2014-01-01

    Testicular sperm extraction is a common procedure used to find spermatogenic cells in men with nonobstructive azoospermia. The laboratory processing of biopsied testicular tissues needs to be performed meticulously to acquire a high yield of cells. In this study, the effectiveness of mincing the tissues after testicular biopsy was assessed using histological evaluation, as was the possible adverse effect of residual tissue on the migration of spermatogenic cells during density gradient centrifugation. Our results indicate that testicular residual tissue, when laid on the density gradient medium along with the sperm wash, hinders the spermatogenic cells’ forming a pellet during centrifugation, and therefore impairs the intracytoplasmic sperm injection procedure. Whereas the mean number of recovered cells from the sperm wash medium (SWM) with residual tissue is 39.435 ± 24.849, it was notably higher (60.189 ± 28.214 cells) in the SWM without minced tissues. The remaining tissue contained no functional seminiferous tubules or spermatogenic cells in histological sections. In conclusion, the remaining residual tissue after mincing biopsied testicular tissue does not add any functional or cellular contribution to spermatogenic cell retrieval; in fact, it may block the cellular elements in the accompanying cell suspension from migrating through the gradient layers to form a pellet during centrifugation and cause loss of spermatogenic cells. PMID:25038178

  18. Preparing Laboratory and Real-World EEG Data for Large-Scale Analysis: A Containerized Approach

    PubMed Central

    Bigdely-Shamlo, Nima; Makeig, Scott; Robbins, Kay A.

    2016-01-01

    Large-scale analysis of EEG and other physiological measures promises new insights into brain processes and more accurate and robust brain–computer interface models. However, the absence of standardized vocabularies for annotating events in a machine understandable manner, the welter of collection-specific data organizations, the difficulty in moving data across processing platforms, and the unavailability of agreed-upon standards for preprocessing have prevented large-scale analyses of EEG. Here we describe a “containerized” approach and freely available tools we have developed to facilitate the process of annotating, packaging, and preprocessing EEG data collections to enable data sharing, archiving, large-scale machine learning/data mining and (meta-)analysis. The EEG Study Schema (ESS) comprises three data “Levels,” each with its own XML-document schema and file/folder convention, plus a standardized (PREP) pipeline to move raw (Data Level 1) data to a basic preprocessed state (Data Level 2) suitable for application of a large class of EEG analysis methods. Researchers can ship a study as a single unit and operate on its data using a standardized interface. ESS does not require a central database and provides all the metadata data necessary to execute a wide variety of EEG processing pipelines. The primary focus of ESS is automated in-depth analysis and meta-analysis EEG studies. However, ESS can also encapsulate meta-information for the other modalities such as eye tracking, that are increasingly used in both laboratory and real-world neuroimaging. ESS schema and tools are freely available at www.eegstudy.org and a central catalog of over 850 GB of existing data in ESS format is available at studycatalog.org. These tools and resources are part of a larger effort to enable data sharing at sufficient scale for researchers to engage in truly large-scale EEG analysis and data mining (BigEEG.org). PMID:27014048

  19. Preparing Laboratory and Real-World EEG Data for Large-Scale Analysis: A Containerized Approach.

    PubMed

    Bigdely-Shamlo, Nima; Makeig, Scott; Robbins, Kay A

    2016-01-01

    Large-scale analysis of EEG and other physiological measures promises new insights into brain processes and more accurate and robust brain-computer interface models. However, the absence of standardized vocabularies for annotating events in a machine understandable manner, the welter of collection-specific data organizations, the difficulty in moving data across processing platforms, and the unavailability of agreed-upon standards for preprocessing have prevented large-scale analyses of EEG. Here we describe a "containerized" approach and freely available tools we have developed to facilitate the process of annotating, packaging, and preprocessing EEG data collections to enable data sharing, archiving, large-scale machine learning/data mining and (meta-)analysis. The EEG Study Schema (ESS) comprises three data "Levels," each with its own XML-document schema and file/folder convention, plus a standardized (PREP) pipeline to move raw (Data Level 1) data to a basic preprocessed state (Data Level 2) suitable for application of a large class of EEG analysis methods. Researchers can ship a study as a single unit and operate on its data using a standardized interface. ESS does not require a central database and provides all the metadata data necessary to execute a wide variety of EEG processing pipelines. The primary focus of ESS is automated in-depth analysis and meta-analysis EEG studies. However, ESS can also encapsulate meta-information for the other modalities such as eye tracking, that are increasingly used in both laboratory and real-world neuroimaging. ESS schema and tools are freely available at www.eegstudy.org and a central catalog of over 850 GB of existing data in ESS format is available at studycatalog.org. These tools and resources are part of a larger effort to enable data sharing at sufficient scale for researchers to engage in truly large-scale EEG analysis and data mining (BigEEG.org). PMID:27014048

  20. Retrospective time series analysis of veterinary laboratory data: preparing a historical baseline for cluster detection in syndromic surveillance.

    PubMed

    Dórea, Fernanda C; Revie, Crawford W; McEwen, Beverly J; McNab, W Bruce; Kelton, David; Sanchez, Javier

    2013-05-01

    The practice of disease surveillance has shifted in the last two decades towards the introduction of systems capable of early detection of disease. Modern biosurveillance systems explore different sources of pre-diagnostic data, such as patient's chief complaint upon emergency visit or laboratory test orders. These sources of data can provide more rapid detection than traditional surveillance based on case confirmation, but are less specific, and therefore their use poses challenges related to the presence of background noise and unlabelled temporal aberrations in historical data. The overall goal of this study was to carry out retrospective analysis using three years of laboratory test submissions to the Animal Health Laboratory in the province of Ontario, Canada, in order to prepare the data for use in syndromic surveillance. Daily cases were grouped into syndromes and counts for each syndrome were monitored on a daily basis when medians were higher than one case per day, and weekly otherwise. Poisson regression accounting for day-of-week and month was able to capture the day-of-week effect with minimal influence from temporal aberrations. Applying Poisson regression in an iterative manner, that removed data points above the predicted 95th percentile of daily counts, allowed for the removal of these aberrations in the absence of labelled outbreaks, while maintaining the day-of-week effect that was present in the original data. This resulted in the construction of time series that represent the baseline patterns over the past three years, free of temporal aberrations. The final method was thus able to remove temporal aberrations while keeping the original explainable effects in the data, did not need a training period free of aberrations, had minimal adjustment to the aberrations present in the raw data, and did not require labelled outbreaks. Moreover, it was readily applicable to the weekly data by substituting Poisson regression with moving 95th percentiles

  1. Fossil track and thermoluminescence studies of Luna 16 material.

    NASA Technical Reports Server (NTRS)

    Walker, R.; Zimmerman, D.

    1972-01-01

    Measurements of track densities and thermoluminescence have been made on two 5-mg samples (feldspar crystals) from the Luna 16 core tube. The distribution of track densities is shown graphically and is similar to that observed in heavily irradiated Apollo samples. Results of thermoluminescence measurements are plotted and also compared with similar measurements of Apollo samples.

  2. Method of analysis of asbestiform minerals by thermoluminescence

    DOEpatents

    Fisher, Gerald L.; Bradley, Edward W.

    1980-01-01

    A method for the qualitative and quantitative analysis of asbestiform minerals, including the steps of subjecting a sample to be analyzed to the thermoluminescent analysis, annealing the sample, subjecting the sample to ionizing radiation, and subjecting the sample to a second thermoluminescent analysis. Glow curves are derived from the two thermoluminescent analyses and their shapes then compared to established glow curves of known asbestiform minerals to identify the type of asbestiform in the sample. Also, during at least one of the analyses, the thermoluminescent response for each sample is integrated during a linear heating period of the analysis in order to derive the total thermoluminescence per milligram of sample. This total is a measure of the quantity of asbestiform in the sample and may also be used to identify the source of the sample.

  3. Thermoluminescence analysis of irradiated oyster shells.

    PubMed

    Cruz-Zaragoza, E; Marcazzó, J; Della Monaca, S; Boniglia, C; Gargiulo, R; Bortolin, E

    2012-12-01

    This paper reports the thermoluminescence (TL) analysis performed on the oyster shells powder. TL response of (60)Co gamma-rays irradiated samples were studied in the range from 80 Gy to 8 kGy doses. TL signal of irradiated shell powder was higher as compared to the unirradiated control samples, which allowed to identify the irradiated oysters. Results show that the oyster shells have good TL properties and can be useful for the identification of irradiated seafood as well as for the evaluation of the treatment dose. PMID:22341648

  4. Thermoluminescence of the mineral components in granite

    SciTech Connect

    Schwartzman, R.G.; Kierstead, J.A.; Levy, P.W.

    1982-01-01

    The thermoluminescence (TL) of the minerals in Climax Stock (Nevada, USA) granite has been studied. The principal mineral constituents are plagioclase, quartz, potassium feldspar and biotite. Pyrite, sphene apatite and zircon occur at one percent or less. All exhibit TL except biotite. The TL kinetics were determined for plagioclase, quartz, potassium feldspar and pyrite. Plagioclase and potassium feldspar exhibit second order and pyrite first orker kinetics. Natural TL of quartz follows second order and artificial TL first order kinetics. However, in these four minerals unrealistic kinetic parameters are often obtained; thus more general kinetics, e.g. interactive kinetics, may apply. 8 figures.

  5. Thermoluminescence of Apollo 12 lunar samples

    USGS Publications Warehouse

    Doell, Richard R.; Brent, Dalrymple G.

    1971-01-01

    Thermoluminescence (TL) glow curve and decay characteristics of Apollo 12 fines and soil samples are similar to those from Apollo 11. Interpretation of the results from the core sample is difficult because of inadequate sample, spacing, but it appears that the part of the core below about 8 cm has been undisturbed for about 104 years whereas the part of the core above 10 cm may have been disturbed by recent surface activity. TL in the Apollo 12 samples is about twice that in the Apollo 11 samples, suggesting a lower mean daytime surface temperature of a few degrees at the Apollo 12 site. ?? 1971.

  6. Thermoluminescence dating of Australian palaeo-earthquakes

    USGS Publications Warehouse

    Hutton, J.T.; Prescott, J.R.; Bowman, J.R.; Dunham, M.N.E.; Crone, A.J.; Machette, M.N.; Twidale, C.R.

    1994-01-01

    Thermoluminescence (TL) dating is a useful tool for determining the age of prehistoric earthquakes by dating deposits that are stratigraphically related to fault scarps that formed during the earthquakes. TL dating of aeolian sand in the area of the 1988 Tennant Creek, Northern Territory, earthquakes provides evidence that similar earthquakes have not ruptured the causative faults for at least 50 ka. Pilot TL measurements of deposits associated with the Roopena and Ash Ridge fault scarps near Whyalla on Eyre Peninsula, South Australia, suggest an age of 140 ka for the Quaternary deposits associated with the formation of the scarps. ?? 1994.

  7. Thermoluminescence Measurements of Medical Grade Polyethylene

    NASA Astrophysics Data System (ADS)

    Lewis, Scott; Dunlap, Greg; Palmer, Jeane; Jahan, M. S.

    1999-11-01

    Ultra-high molecular weight polyethylene (UHMWPE) is a biomaterial used in hip and knee joint replacements. Because this material is implanted into the body the material must be sterilized to prevent infection after implantation. Gamma irradiation is the most common method of sterilization, but it has one drawback; it causes the formation of free radicals and subsequent oxidative degradation of PE. By using thermoluminescence (TL) technique, free radical quenching temperature can be determined. In this study, UHMWPE was X-irradiated ( ~1 MRad at 10 keV) at 32 ^oC and subsequently heated to 200 ^oC at 1 ^oC / sec. The resulting luminescence known as thermoluminescence (TL) was recorded using a commercial TL dosimeter. The TL output, known as a glow curve, consists of two glow peaks, the prominent one occurs at 70 ^oC and a second one at 120 ^oC. It is suggested that the peak at 70 ^oC results from the recombination of free radicals due to molecular motion in the amorphous region, and the 120 ^oC peak is due to the motion of crystalline medium of the polyethylene matrix. Thermal annealing of free radicals as detected by TL can be a useful technique for diagnostic test of stabilization of radiation-sterilized medical joint components. *Supported by NSF REU Program (grant number EEC9619821) at the University of Memphis.

  8. An algorithm for pre- and post-irradiation fade in the thermo 8802 LiF:Mg,Ti thermoluminescent dosimeter.

    SciTech Connect

    Hill, Carolyn D.

    2004-08-01

    The diminished response of thermoluminescent phosphors over time is a well-documented challenge to thermoluminescent dosimetry. Wide ranges in fading rates for various phosphor types have been reported, making it necessary for many external dosimetry programs to perform individual studies on thermoluminescent fade. Sandia National Laboratories currently uses the Thermo 8802 LiF:Mg,Ti thermoluminescent dosimeter (TLD) in its personnel external dosimetry program. Doses received in the field are calculated by applying a fade algorithm published by the manufacturer to TLD readings. Since the algorithm was established by characterizing the diminished response of a TLD similar to the 8802, Sandia chose to model its fade study after the analysis done by Thermo. As a result, the parameters of each experiment were comparable, and data from the two studies were compared to determine whether or not the current algorithm should be modified specifically for use at Sandia. Cards were irradiated using an internal Sr/Y source, and pre- and post-irradiation fading rates were monitored over a period of 18 wk. While significant fading was demonstrated, results closely matched those found in the original Thermo study.

  9. An algorithm for pre- and post-irradiation fade in the Thermo 8802 LiF:Mg,Ti thermoluminescent dosimeter.

    PubMed

    Hill, Carolyn D

    2005-05-01

    The diminished response of thermoluminescent phosphors over time is a well-documented challenge to thermoluminescent dosimetry. Wide ranges in fading rates for various phosphor types have been reported, making it necessary for many external dosimetry programs to perform individual studies on thermoluminescent fade. Sandia National Laboratories currently uses the Thermo 8802 LiF:Mg,Ti thermoluminescent dosimeter (TLD) in its personnel external dosimetry program. Doses received in the field are calculated by applying a fade algorithm published by the manufacturer to TLD readings. Since the algorithm was established by characterizing the diminished response of a TLD similar to the 8802, Sandia chose to model its fade study after the analysis done by Thermo. As a result, the parameters of each experiment were comparable, and data from the two studies were compared to determine whether or not the current algorithm should be modified specifically for use at Sandia. Cards were irradiated using an internal Sr/Y source, and pre- and post-irradiation fading rates were monitored over a period of 18 wk. While significant fading was demonstrated, results closely matched those found in the original Thermo study. PMID:15824586

  10. A One-Pot Self-Assembly Reaction to Prepare a Supramolecular Palladium(II) Cyclometalated Complex: An Undergraduate Organometallic Laboratory Experiment

    ERIC Educational Resources Information Center

    Fernandez, Alberto; Lopez-Torres, Margarita; Fernandez, Jesus J.; Vazquez-Garcia, Digna; Vila, Jose M.

    2012-01-01

    A laboratory experiment for students in advanced inorganic chemistry is described. Students prepare palladium(II) cyclometalated complexes. A terdentate [C,N,O] Schiff base ligand is doubly deprotonated upon reaction with palladium(II) acetate in a self-assembly process to give a palladacycle with a characteristic tetranuclear structure. This…

  11. The natural thermoluminescence of meteorites. VI - Carbon-14, thermoluminescence and the terrestrial ages of meteorites

    NASA Technical Reports Server (NTRS)

    Benoit, P. H.; Jull, A. J. T.; Mckeever, S. W. S.; Sears, D. W. G.

    1993-01-01

    A relationship is noted between the natural thermoluminescence (TL) levels and the C-14-derived terrestrial ages for meteorite finds from the U.S. Prairie States and Roosevelt County, NM; those in the Sahara are also in accord with calculated TL decay curves, for 'storage' temperatures equal to the approximate average annual temperatures at individual sites. This discussion is limited to the empirical correspondence between the two methodologies, and to theoretical decay curves for a single 'average' ordinary chondrite.

  12. The natural thermoluminescence of meteorites. VI - Carbon-14, thermoluminescence and the terrestrial ages of meteorites

    NASA Astrophysics Data System (ADS)

    Benoit, P. H.; Jull, A. J. T.; McKeever, S. W. S.; Sears, D. W. G.

    1993-06-01

    A relationship is noted between the natural thermoluminescence (TL) levels and the C-14-derived terrestrial ages for meteorite finds from the U.S. Prairie States and Roosevelt County, NM; those in the Sahara are also in accord with calculated TL decay curves, for 'storage' temperatures equal to the approximate average annual temperatures at individual sites. This discussion is limited to the empirical correspondence between the two methodologies, and to theoretical decay curves for a single 'average' ordinary chondrite.

  13. Thermoluminescence characterization of the irradiated minerals extracted from nopal

    NASA Astrophysics Data System (ADS)

    Cruz-Zaragoza, E.; Furetta, C.; Kitis, G.; Gomez, B. T.; Polymeris, G. S.; Tsirliganis, N.; Loukou, Z.

    2006-05-01

    The mineral fraction from dehydrated nopal leaves (Opuntia ficus indica ) belonging to the Cactaceae family was extracted and selected by sizes of 10 and 74 mu m and exposed to 60 Co gamma radiation at different doses in the range 70 Gy-20 kGy. The glow-curves from these polyminerals show a thermoluminescence (TL) band with one very intense peak at a temperature around 150 degrees C and a second one emerging in the high temperature region, moving in a large zone of temperature values according to the preparation used and the level of irradiation. The XRD analysis shows a composition of both biominerals as whewellite and weddellite and a mineral fraction as anorthoclase and quartz. The main TL characteristics of the polymineral content of the nopal was analyzed, i.e . the TL response at different doses and fading during storage at room temperature. The activation energy of the traps responsible for the TL emission was also investigated and a possible continuous distribution of traps is discussed. A review of the scientific literature shows that this is the first time that a TL study on nopal ionized by irradiation has been carried out.

  14. Thermoluminescence sensitivity of daily-use materials

    NASA Astrophysics Data System (ADS)

    Correcher, V.; Garcia-Guinea, J.; Rivera, T.

    The thermoluminescence (TL) response of silicon-rich daily-use materials, namely charoite (silicate gemstone), Spanish dental crown, phone chip and Spanish glass has been investigated. All the samples previously characterised by means of X-ray diffraction, electron microscopy associated with energy-dispersion and wavelength-dispersive spectrometry and X-ray fluorescence exhibit a reasonable sensitivity to ionising radiation. The preliminary results, based on their TL properties, allow us to speculate that these materials could be potentially of interest in situations where conventional dosimetric systems are not available. The dose dependence of the 400 nm TL emission of the studied samples displays a very good linearity in the range of 0.1-10 Gy.

  15. Thermoluminescence properties of irradiated chickpea and corn

    NASA Astrophysics Data System (ADS)

    Necmeddin Yazici, A.; Bedir, Metin; Bozkurt, Halil; Bozkurt, Hüseyin

    2008-02-01

    A study was carried out to establish a detection method for irradiated chickpea and corn by thermoluminescence (TL) method. The leguminous were packed in polyethylene bags and then the packets were irradiated at room temperature at different doses by 60Co gamma source at 1, 4, 8 and 10 kGy. Minerals extracted from the leguminous were deposited onto a clean aluminum disc and TL intensities of the minerals were measured by TL. It was observed that the extracted samples from both leguminous exhibit good TL Intensity and the TL intensity of glow curves of them increased proportionally to irradiation doses. The TL glow curve of both irradiated leguminous presents a single broad peak below 400 °C. The TL trapping parameters glow peaks were estimated by the additive dose (AD), Tm(Ea)-Tstop and computerized glow curve deconvolution (CGCD) methods. The fading characteristics of glow curves were also recorded up to 6 months.

  16. Environmental dosimeter of the thermoluminescent type

    DOEpatents

    Eichner, F.N.; Kocher, L.F.

    1974-01-29

    A dosimeter for accurately monitoring normally low-energy radiation including a thermoluminescent CaF phosphor enclosed within a tantalum capsule is described. The tantalum acts as a filter to weaken the measured dose due to photons having energies below about 0.2 MeV. Tantalum end caps are maintained on the capsule body by a polyolefin sheath formed from heat-contractable tubing. After exposing the dosimeter to environmental radiation, it is placed in a shielded chamber for about 24 h and subsequently annealed at about 80 deg C to release radiation energy accumulated in low-temperature traps. The dosimeter is then disassembled and the phosphors photometrically read at temperatures about 50 deg C to determine the absorbed radiation dose. (Official Gazette)

  17. Diamond thermoluminescence properties of different chondrites

    NASA Technical Reports Server (NTRS)

    Fisenko, A. V.; Kashkarov, L. L.; Semjonova, L. F.; Pillinger, C. T.

    1993-01-01

    It was found that thermoluminescence (TL) glows of diamonds depend on the origin of diamonds and the chondrite metamorphism degree. The investigation of TL of diamonds was continued and the results for diamonds from Murchison CM2, Krymka LL3.0, Kainsaz CO3, and Abee E4 were considered. The diamonds synthesized by CVD-process (samples 133, 159) and by detonation from soot (DDS-B14-89) were also analyzed for comparison. Before the TL measuring samples were annealed at approximately 350 C for a few seconds and then irradiated by gamma-rays of Cs-137 up to dose approximately 200 krad. TL-measurements were performed in the air atmosphere on the standard equipment. TL data for samples are shown. TL glow for some diamonds are also presented.

  18. The thermoluminescence carrier in the Dhajala chondrite

    NASA Technical Reports Server (NTRS)

    Sparks, M. H.; Mckimmey, P. M.; Sears, D. W. G.

    1983-01-01

    It is pointed out that the type 3 (unequilibrated) ordinary chondrites provide a major source of information on the early solar system. However, the interpretation of the data is difficult because all but a few display signs of metamorphic alteration. The present investigation is concerned with the thermoluminescence (TL) sensitivity measurements on 58 chondrules separated from the Dhajala meteorites. The data were discussed briefly by Sparks and Sears (1982). In the current investigation particular attention is given to the constraints placed by these data on the mechanism by which metamorphism is related to TL sensitivity. Dhajala-normalized TL sensitivity of the separated chondrules is plotted against chondrule mass, and a histogram of the CaO contents of 15 chondrules is presented. Histograms showing the TL sensitivity of chondrules separated from the Dhajala meteorite are also provided.

  19. Thermoluminescence of meteorites and their terrestrial ages

    NASA Astrophysics Data System (ADS)

    Melcher, C. L.

    1981-05-01

    A technique for determining chondritic meteorite terrestrial ages based on the measurement of a normalized thermoluminescence (TL) is presented and applied to samples of 11 recently discovered Antarctic meteorites. Measurements of TL levels normalized to individual meteorite TL sensitivities are presented for 45 chondrites of known terrestrial ages and shown to increase with decreasing terrestrial age. Differences in TL levels in meteorites of the same terrestrial ages are attributed to differences in orbital temperatures. TL levels determined in initial rise experiments for the Antarctic meteorites are found to indicate ages which show a rough correlation with those deduced from C-14, Al-26 and Cl-36 studies. Due to the rapidity and low material requirements of TL measurements, it is proposed that TL determinations be used as screening process to select the most interesting samples for further study by other, more exact, techniques.

  20. Thermoluminescence sensitivity of ulexite after UV irradiation

    NASA Astrophysics Data System (ADS)

    Topaksu, M.; Correcher, V.; Garcia-Guinea, J.

    2015-04-01

    The effects of UV radiation on the thermoluminescence (TL) properties of natural materials, in contrast to synthetic materials, have been scarcely studied. We report on the UV-induced thermoluminescence emission of a Turkish ulexite (NaCaB5O6(OH)6·5H2O) that displays very complex TL glow curves, with at least three groups of components peaked at 130-140 °C, 240 °C and, 340 °C, wherein the last group is weaker. Such emission could be associated with structural changes in the lattice as well as alkali self-diffusion processes. The UV exposure performed at controlled temperatures (at room temperature (RT), 50 °C and 100 °C) produced a (i) different evolutions of the intensities of each maximum, which are directly related to the controlled thermal treatment; (ii) different intensity ratios among the groups of components; (iii) different activation energies (Ea) (1.13 eV for RT, 0.99 eV for 50 °C and 0.49 eV for 100 °C) calculated using the initial rise method; and (iv) similar scattering values (12.4%, 8.2% and 12.8%), which were not a function of the controlled temperature. The thermal stability tests conducted on this borate at different temperatures, based on the Tstop protocol, confirm the presence of a continuum in the distribution of the trap system with progressively increasing Ea (from 0.60 to 0.90 eV).

  1. Prepare, Do, Review: A Skills-Based Approach for Laboratory Practical Classes in Biochemistry and Molecular Biology

    ERIC Educational Resources Information Center

    Arthur, Peter; Ludwig, Martha; Castelli, Joane; Kirkwood, Paul; Attwood, Paul

    2016-01-01

    A new laboratory practical system is described which is comprised of a number of laboratory practical modules, each based around a particular technique or set of techniques, related to the theory part of the course but not designed to be dependent on it. Each module comprises an online recorded pre-lab lecture, the laboratory practical itself and…

  2. Interpretation of thermoluminescence patterns around a Wyoming roll-type uranium deposit

    USGS Publications Warehouse

    Spirakis, Charles S.

    1979-01-01

    Thermoluminescence from quartz and feldspar grains in samples collected from the vicinity of a Wyoming roll-type uranium deposit show an increase in the importance of high-temperature thermoluminescence relative to low-temperature thermoluminescence of samples which are believed to be former positions of the migrating mineralized front. This effect is believed to be due to the increased radiation in the ore coupled with the faster rate of fading of low-temperature thermoluminescence compared to high-temperature thermoluminescence. Both the ratios of thermoluminescent responses from any of a variety of temperature ranges and glow curves (plots of intensity of thermoluminescence versus temperature) can be used to detect the increased importance of high-temperature thermoluminescence relative to low-temperature thermoluminescence of previously mineralized samples. Both ratios and glow curves present a systematic pattern around this deposit; these patterns may have application in uranium prospecting.

  3. Brief review of thermoluminescence studies in lunar samples.

    NASA Technical Reports Server (NTRS)

    Hoyt, H. P., Jr.; Walker, R. M.; Miyajima, M.

    1971-01-01

    A weak thermoluminescence, due primarily to plagioclase feldspar, is found to exist in Apollo 11 and 12 lunar rock and topsoil samples. This effect increases with depth to about 10 cm below the surface and becomes relatively even in greater depth. The penetration of the diurnal temperature wave is traced to the rock thermoluminescence. Evidence is also found for the thermal draining of the surface rock.

  4. Solving the AI Planning Plus Scheduling Problem Using Model Checking via Automatic Translation from the Abstract Plan Preparation Language (APPL) to the Symbolic Analysis Laboratory (SAL)

    NASA Technical Reports Server (NTRS)

    Butler, Ricky W.; Munoz, Cesar A.; Siminiceanu, Radu I.

    2007-01-01

    This paper describes a translator from a new planning language named the Abstract Plan Preparation Language (APPL) to the Symbolic Analysis Laboratory (SAL) model checker. This translator has been developed in support of the Spacecraft Autonomy for Vehicles and Habitats (SAVH) project sponsored by the Exploration Technology Development Program, which is seeking to mature autonomy technology for the vehicles and operations centers of Project Constellation.

  5. Pre-Service Chemistry Teachers' Competencies in the Laboratory: A Cross-Grade Study in Solution Preparation

    ERIC Educational Resources Information Center

    Karatas, F. O.

    2016-01-01

    One of the prerequisites for chemistry teacher candidates is to demonstrate certain laboratory skills. This article aims to determine and discuss the competencies of pre-service chemistry teachers in a chemistry laboratory context working with solution chemistry content. The participants in this study consisted of a group of pre-service chemistry…

  6. Thermoluminescence of shock-loaded amethyst quartz

    NASA Astrophysics Data System (ADS)

    Plath, I.; Lehmann, G.

    1987-05-01

    In natural amethyst samples subjected to shock pressures between 10 and 50 GPa (1 GPa=109 Pa), thermoluminescence (TL) was observed after subsequent X-ray irradiation, in some cases even without high energy irradiation. The glow curves could be decomposed into at most five components of Gaussian shape, but no reliable activation energies could be determined from them, perhaps due to a wide distribution of trap depths. With increasing shock pressures traps of higher thermal stability were favored. Emission bands with maxima near 14000 cm-1 were observed independent of shock pressure. They appear to be characteristic of defects created during the shock events, but it is uncertain whether the observed TL is connected with the iron impurities characteristic for amethyst. In natural amethyst samples of the same origin no TL could be observed, even after additional X-ray irradiation. It is concluded that TL in amethysts reported in the literature was actually caused by defects associated with aluminium impurities, not by destruction of Fe4+.

  7. Charge recombination and thermoluminescence in photosystem II.

    PubMed

    Rappaport, Fabrice; Cuni, Aude; Xiong, Ling; Sayre, Richard; Lavergne, Jérôme

    2005-03-01

    In the recombination process of Photosystem II (S(2)Q(A)(-)-->S(1)Q(A)) the limiting step is the electron transfer from the reduced primary acceptor pheophytin Ph(-) to the oxidized primary donor P(+) and the rate depends on the equilibrium constant between states S(2)PPhQ(A)(-) and S(1)P(+)Ph(-)Q(A). Accordingly, mutations that affect the midpoint potential of Ph or of P result in a modified recombination rate. A strong correlation is observed between the effects on the recombination rate and on thermoluminescence (TL, the light emission from S(2)Q(A)(-) during a warming ramp): a slower recombination corresponds to a large enhancement and higher temperature of the TL peak. The current theory of TL does not account for these effects, because it is based on the assumption that the rate-limiting step coincides with the radiative process. When implementing the known fact that the radiative pathway represents a minor leak, the modified TL theory readily accounts qualitatively for the observed behavior. However, the peak temperature is still lower than predicted from the temperature-dependence of recombination. We argue that this reflects the heterogeneity of the recombination process combined with the enhanced sensitivity of TL to slower components. The recombination kinetics are accurately fitted as a sum of two exponentials and we show that this is not due to a progressive stabilization of the charge-separated state, but to a pre-existing conformational heterogeneity. PMID:15653722

  8. Apparatuses and methods for laser reading of thermoluminescent phosphors

    DOEpatents

    Braunlich, Peter F.; Tetzlaff, Wolfgang

    1989-01-01

    Apparatuses and methods for rapidly reading thermoluminescent phosphors to determine the amount of luminescent energy stored therein. The stored luminescent energy is interpreted as a measure of the total exposure of the thermoluminescent phosphor to ionizing radiation. The thermoluminescent phosphor reading apparatus uses a laser to generate a laser beam. The laser beam power level is monitored by a laser power detector and controlled to maintain the power level at a desired value or values which can vary with time. A shutter or other laser beam interrupting means is used to control exposure of the thermoluminescent phosphor to the laser beam. The laser beam can be equalized using an opitcal equalizer so that the laser beam has an approximately uniform power density across the beam. The heated thermoluminescent phosphor emits a visible or otherwise detectable luminescent emission which is measured as an indication of the radiation exposure of the thermoluminscent phosphors. Also disclosed are preferred signal processing and control circuits including one system using a digital computer. Also disclosed are time-profiled laser power cycles for pre-anneal, read and post-anneal treatment of phosphors.

  9. Depth-dependent temperature effects on thermoluminescence in multilayers

    NASA Astrophysics Data System (ADS)

    Kim, Sangho S.; Armstrong, Philip R.; Mah, Merlin L.; Talghader, Joseph J.

    2013-08-01

    It is well known that thermal gradients penetrating deep into a material can preserve a memory of the temperature history of the surface. To date, this concept has been largely applied in the earth sciences, but there are many applications where a memory of rapid thermal events would be useful. For example, multiple layers of thermoluminescent films could serve as temperature sensors that indicate temperature versus depth in a microfabricated structure. As an advance toward this goal, this paper examines the effect of nonuniform temperature profiles on the thermoluminescence of heterogeneous multilayers. A Nd:YAG laser is used to create a known thermal event and apply pulses of heat energy of varying duration to a metalized thermoluminescent multilayer composed of LiF:Mg,Ti and CaF2:Dy. The thermoluminescence of the system is measured before and after the applied laser pulse. To model the process, a finite-difference time-domain method is used to calculate the dynamic heat transfer, and the temperature distribution is plugged into a first order kinetics model of the thermoluminescence of each film to get a final luminescent intensity. A thermal contact conductance between the critical layers is also introduced. Dynamic temperatures in durations of hundreds of milliseconds are resolved with the technique, and simulation curves match experimental measurements to within 6% at 250 ms.

  10. Thermoluminescence and optical characteristics of ZrO2 powder as a TL dosimeter

    NASA Astrophysics Data System (ADS)

    Montalvo, T. R.; Tenorio, L. O.; Nieto, J. A.; Celis, A. C.; Ordonez, C. V.; Fonseca, R. S.

    2004-11-01

    A description of the preparation of zirconium oxide (ZrO2) polycrystalline powder by the sol-gel method is presented. To prepare ZrO2 powder to be used as a thermoluminescent (TL) phosphor in dosimetric application, it is necessary to analyze some structural properties before, such as it's crystallinity. In this work, the property was verified using X-ray diffraction. ZrO2 polycrystalline powder obtained was subjected to thermal treatment by heating up to 1000 degrees C. Both the absorption spectrum and the emission spectrum were also studied. The TL glow curve of ZrO2 powder exhibited a peak when it was exposed to a radiation field. Results of analyzing optical properties and the preliminary results of studying the TL in ZrO2, indicate that the latter is a good candidate to be used as a TL dosimeter in radiation ionizing and UV-radiation fields.

  11. Quality control program for the Hanford External Dosimetry thermoluminescent processing system

    SciTech Connect

    Baumgartner, W.V.; Endres, A.W.; Reese, S.R.

    1992-09-01

    The Hanford External Dosimetry Program is operated by Pacific Northwest Laboratory for the US Department of Energy (DOE). The program records official external occupational radiation doses for all Hanford Site employees and visitors in compliance with DOE Order requirements. This report documents the quality control (QC) program for External Dosimetry's thermoluminescent dosimeter (TLD) processing system. The focus of the External Dosimetry Program has been (1) to accurately calculate personnel radiation doses, and (2) to document the methods used to report doses in order, to meet DOE Laboratory Accreditation Program (DOELAP) criteria. The purpose of this report is to describe the QC procedures used for dosimeters and processing equipment. Use of QC procedures allows for the prompt correction of unusual data before it is reported.

  12. Quality control program for the Hanford External Dosimetry thermoluminescent processing system

    SciTech Connect

    Baumgartner, W.V.; Endres, A.W.; Reese, S.R.

    1992-09-01

    The Hanford External Dosimetry Program is operated by Pacific Northwest Laboratory for the US Department of Energy (DOE). The program records official external occupational radiation doses for all Hanford Site employees and visitors in compliance with DOE Order requirements. This report documents the quality control (QC) program for External Dosimetry`s thermoluminescent dosimeter (TLD) processing system. The focus of the External Dosimetry Program has been (1) to accurately calculate personnel radiation doses, and (2) to document the methods used to report doses in order, to meet DOE Laboratory Accreditation Program (DOELAP) criteria. The purpose of this report is to describe the QC procedures used for dosimeters and processing equipment. Use of QC procedures allows for the prompt correction of unusual data before it is reported.

  13. Prepare, Do, Review: A skills-based approach for laboratory practical classes in biochemistry and molecular biology.

    PubMed

    Arthur, Peter; Ludwig, Martha; Castelli, Joane; Kirkwood, Paul; Attwood, Paul

    2016-05-01

    A new laboratory practical system is described which is comprised of a number of laboratory practical modules, each based around a particular technique or set of techniques, related to the theory part of the course but not designed to be dependent on it. Each module comprises an online recorded pre-lab lecture, the laboratory practical itself and a post-lab session in which students make oral presentations on different aspects of the practical. Each part of the module is assessed with the aim of providing rapid feedback to staff and students. Each laboratory practical is the responsibility of a single staff member and through this "ownership," continual review and updating is promoted. Examples of changes made by staff to modules as a result of student feedback are detailed. A survey of students who had experienced both the old-style laboratory course and the new one provided evidence of increased satisfaction with the new program. The assessment of acquired shills in the new program showed that it was much more effective than the old course. © 2016 by The International Union of Biochemistry and Molecular Biology, 44:276-287, 2016. PMID:27161811

  14. Controlled/Living Radical Polymerization in the Undergraduate Laboratories. 1. Using ATRP to Prepare Block and Statistical Copolymers of n-Butyl Acrylate and Styrene

    NASA Astrophysics Data System (ADS)

    Beers, Kathryn L.; Woodworth, Brian; Matyjaszewski, Krzysztof

    2001-04-01

    A simple method of preparing well-defined (co)polymers has been developed for application in an advanced undergraduate laboratory. The method utilizes atom transfer radical polymerization (ATRP), a controlled/living radical polymerization, to prepare difunctional poly(n-butyl acrylate) with bromine end groups, which is chain-extended with styrene to yield an ABA triblock copolymer. Simultaneously, a statistical copolymer of the two monomers is prepared for comparison. The two copolymers are isolated and compositions and molecular weights are determined using 1H NMR and SEC, respectively. Optional additions to the experiment include performing a kinetic analysis of the homopolymerization using GC and SEC, and possibly comparing the results to those expected for conventional radical polymerization. Material differences in the copolymers can be observed qualitatively or measured using thermal or mechanical analysis. The lab is designed in such a way that several parts of the whole can be used to emphasize different areas of polymer science. A more synthetic course such as the organic synthesis lab can opt to investigate only the kinetic and composition analyses, whereas an engineering or materials science course may pursue more rigorous analysis of the materials' properties. Results included here are intended for application in an organic synthesis laboratory course.

  15. Preparation for high altitude expedition and changes in cardiopulmonary and biochemical laboratory parameters with ascent to high altitude in transplant patients and live donors.

    PubMed

    Suh, Kyung-Suk; Kim, Taehoon; Yi, Nam-Joon; Hong, Geun

    2015-11-01

    High-altitude climbing has many risks, and transplant recipients should discuss the associated risks and means of preparation with their physicians. This study aimed to help prepare athletic transplant donors and recipients for mountain climbing and was designed to evaluate physical performance and changes in cardiopulmonary and biochemical laboratory parameters of transplant recipients and donors in extreme conditions of high altitude. Ten subjects-six liver transplant recipients, two liver donors, and one kidney transplant recipient and his donor-were selected for this expedition to Island Peak, Himalayas, Nepal. Six healthy subjects joined the group for comparison. Blood samplings, vital signs, and oxygen saturation were evaluated, as was the Lake Louise acute mountain sickness score. All transplant subjects and donors reached the base camp (5150 m), and two liver transplant recipients and a liver donor reached the summit (6189 m). The blood levels of immunosuppressants were well maintained. The serum erythropoietin level was significantly higher in transplant recipients taking tacrolimus. With proper preparation, certain liver transplant patients and donors can tolerate strenuous physical activity and can tolerate high altitude similarly to normal healthy control subjects without significant biochemical laboratory changes in liver and renal function. PMID:26331794

  16. Thermoluminescence and lattice defects in LiF

    NASA Technical Reports Server (NTRS)

    Stoebe, T. G.; Watanabe, S.

    1975-01-01

    The principal effect of thermal and optical treatments in an ionic solid is to alter the lattice defect equilibrium, including the concentration and arrangement of ion vacancies, impurities, impurity-vacancy associates, and assorted electrons and holes which may be associated with such defects. This paper examines the relationship between these defects and thermoluminescence in the case of lithium fluoride at and above room temperature. The discussion focuses on lattice defect equilibrium, thermoluminescent trapping centers, the relationship between recombination and luminescence, the supralinearity and sensitization of the dosimetry grade of LiF and activation energy parameters.

  17. Thermoluminescence properties of lithium magnesium borate glasses system doped with dysprosium oxide.

    PubMed

    Mhareb, M H A; Hashim, S; Ghoshal, S K; Alajerami, Y S M; Saleh, M A; Razak, N A B; Azizan, S A B

    2015-12-01

    We report the impact of dysprosium (Dy(3+)) dopant and magnesium oxide (MgO) modifier on the thermoluminescent properties of lithium borate (LB) glass via two procedures. The thermoluminescence (TL) glow curves reveal a single prominent peak at 190 °C for 0.5 mol% of Dy(3+). An increase in MgO contents by 10 mol% enhances the TL intensity by a factor of 1.5 times without causing any shift in the maximum temperature. This enhancement is attributed to the occurrence of extra electron traps created via magnesium and the energy transfer to trivalent Dy(3+) ions. Good linearity in the range of 0.01-4 Gy with a linear correlation coefficient of 0.998, fading as low as 21% over a period of 3 months, excellent reproducibility without oven annealing and tissue equivalent effective atomic numbers ~8.71 are achieved. The trap parameters, including geometric factor (μg), activation energy (E) and frequency factor (s) associated with LMB:Dy are also determined. These favorable TL characteristics of prepared glasses may contribute towards the development of Li2O-MgO-B2O3 radiation dosimeters. PMID:25828828

  18. Thermoluminescence of kunzite: A study of kinetic processes and dosimetry characteristics

    NASA Astrophysics Data System (ADS)

    Ogundare, F. O.; Alatishe, M. A.; Chithambo, M. L.; Costin, G.

    2016-04-01

    Since the use of natural minerals for dating and dose reconstruction using luminescence techniques is well-established and always of interest, we present thermoluminescence characteristics of kunzite, a gem variety of spodumene. The chemical composition of the sample was determined using an Electron Probe MicroAnalyzer to be (Li0.996Na0.009Mn0.006)∑ = 1.016(Al0.981Cr0.003Fe2+0.001)∑ = 0.995[(Si1.993Al0.008)∑ = 2.000O6]. Thermoluminescence glow curves measured at 0.5 K/s after laboratory irradiation consist of three prominent peaks at 338 K (labelled as peak I), 454 K (peak II) and 681 K (peak III). The dose response of these three peaks is linear in the range 20-308 Gy studied. The position of each of the peaks is independent of dose, an archetypical feature of first order behaviour. However, detailed kinetic analyses showed that in fact, the peaks are not subject to first order kinetics. Each of the three peaks is affected by thermal quenching with an associated activation energy of thermal quenching estimated to be 0.70, 1.35 and 0.54 eV for peaks I, II and III respectively. In terms of dosimetry use, only peak III was found to be reliable for possible use in luminescence dating and dose reconstruction.

  19. A Guide for Planning Facilities for Occupational Preparation Programs in Laboratory Animal Science Technology. Interim Report. Research 27.

    ERIC Educational Resources Information Center

    Colling, Walter E.; Farnsworth, Wilbur M.

    The major purpose of this guide is to elicit the necessary information for the writing of educational specifications for facilities to house career programs in laboratory animal science technology. The guide is also designed to: (1) assist planners in formation of creative solutions to the housing of desired educational programs, (2) prevent…

  20. Preparation and Viscosity of Biodiesel from New and Used Vegetable Oil: An Inquiry-Based Environmental Chemistry Laboratory

    ERIC Educational Resources Information Center

    Clarke, Nathan R.; Casey, John Patrick; Brown, Earlene D.; Oneyma, Ezenwa; Donaghy, Kelley J.

    2006-01-01

    A synthesis is developed to make biodiesel from vegetable oils such as soybean, sunflower, and corn oil, as an exercise in the laboratory. Viscosity measurements were used to gain an understanding of an intermolecular property of the biodiesel and that has limited the implementation of biodiesel on a wide scale basis, solidification at low…

  1. Acid-Catalyzed Preparation of Biodiesel from Waste Vegetable Oil: An Experiment for the Undergraduate Organic Chemistry Laboratory

    ERIC Educational Resources Information Center

    Bladt, Don; Murray, Steve; Gitch, Brittany; Trout, Haylee; Liberko, Charles

    2011-01-01

    This undergraduate organic laboratory exercise involves the sulfuric acid-catalyzed conversion of waste vegetable oil into biodiesel. The acid-catalyzed method, although inherently slower than the base-catalyzed methods, does not suffer from the loss of product or the creation of emulsion producing soap that plagues the base-catalyzed methods when…

  2. RESIDENTIAL SOIL SAMPLING PLAN: COMPARISON OF LABORATORY AND FIELD X-RAY FLUORESCENCE (XRF) ANALYSIS AND SAMPLE PREPARATION.

    EPA Science Inventory

    In the past, Region 10 has relied exclusively on fixed-site laboratory analyses of soil samples for Remedial Investigation/Feasibility Studies and Risk Assessments. The objectives of this sampling effort included soil analyses for removal and remedial actions as well as collecti...

  3. Evaluation of new and conventional thermoluminescent phosphors for environmental monitoring using automated thermoluminescent dosimeter readers

    SciTech Connect

    Rathbone, B.A.; Endres, A.W.; Antonio, E.J.

    1994-10-01

    In recent years, there has been considerable interest in a new generation of super-sensitive thermoluminescent (TL) phosphors for potential use in routine personnel and environmental monitoring. Two of these phosphors, {alpha}-Al{sub 2}O{sub 3}:C and LiF:Mg,Cu,P, are evaluated in this paper for selected characteristics relevant to environmental monitoring, along with two conventional phosphors widely used in environmental monitoring, LiF:Mg,Ti and CaF{sub 2}:Dy. The characteristics evaluated are light-induced fading, light-induced background, linearity and variability at low dose, and the minimum measurable dose. These characteristics were determined using an automated commercial dosimetry system (Harshaw System 8800) and routine processing protocols. Annealing and readout protocols for each phosphor were optimized for use in a large-scale environmental monitoring program.

  4. [Gdansk combined crown with occlusal rest. 1. Clinical and laboratory preparation of combined crown with occlusal rest on the basis of cast crown].

    PubMed

    Tejchman, H; Czerwińska, W

    1990-01-01

    The combined crown used since many years in the Prosthetic Laboratory, Institute of Stomatology, Medical Academy in Gdańsk contains an occlusal rest basis of a cast crown (the metal part is of a gold alloy or chromium-nickel steel, with veneer of acrylateor Colorstat) provides, owing to a special preparation of the abutment tooth and laboratory procedure, full stabilization of the crown, protection of parodontium and good maintenance of the veneer which plays a cosmetic role in this type of crown. The combined crowns with occlusal rest are particularly suitable for supporting bridgeworks. They may be applied onto devitalized or live teeth since they require less extensive grinding of teeth. PMID:2103019

  5. Preparation and Certification of Two New Bulk Welding Fume Reference Materials for Use in Laboratories Undertaking Analysis of Occupational Hygiene Samples

    PubMed Central

    Butler, Owen; Musgrove, Darren; Stacey, Peter

    2014-01-01

    Workers can be exposed to fume, arising from welding activities, which contain toxic metals and metalloids. Occupational hygienists need to assess and ultimately minimize such exposure risks. The monitoring of the concentration of particles in workplace air is one assessment approach whereby fume, from representative welding activities, is sampled onto a filter and returned to a laboratory for analysis. Inductively coupled plasma-atomic emission spectrometry and inductively coupled plasma-mass spectrometry are generally employed as instrumental techniques of choice for the analysis of such filter samples. An inherent difficulty, however, with inductively coupled plasma-based analytical techniques is that they typically require a sample to be presented for analysis in the form of a solution. The efficiency of the required dissolution step relies heavily upon the skill and experience of the analyst involved. A useful tool in assessing the efficacy of this dissolution step would be the availability and subsequent analysis of welding fume reference materials with stated elemental concentrations and matrices that match as closely as possible the matrix composition of welding fume samples submitted to laboratories for analysis. This article describes work undertaken at the Health and Safety Laboratory to prepare and certify two new bulk welding fume reference materials that can be routinely used by analysts to assess the performance of the digestion procedures they employ in their laboratories. PMID:24499055

  6. A Microfluidic Device for Preparing Next Generation DNA Sequencing Libraries and for Automating Other Laboratory Protocols That Require One or More Column Chromatography Steps

    PubMed Central

    Tan, Swee Jin; Phan, Huan; Gerry, Benjamin Michael; Kuhn, Alexandre; Hong, Lewis Zuocheng; Min Ong, Yao; Poon, Polly Suk Yean; Unger, Marc Alexander; Jones, Robert C.; Quake, Stephen R.; Burkholder, William F.

    2013-01-01

    Library preparation for next-generation DNA sequencing (NGS) remains a key bottleneck in the sequencing process which can be relieved through improved automation and miniaturization. We describe a microfluidic device for automating laboratory protocols that require one or more column chromatography steps and demonstrate its utility for preparing Next Generation sequencing libraries for the Illumina and Ion Torrent platforms. Sixteen different libraries can be generated simultaneously with significantly reduced reagent cost and hands-on time compared to manual library preparation. Using an appropriate column matrix and buffers, size selection can be performed on-chip following end-repair, dA tailing, and linker ligation, so that the libraries eluted from the chip are ready for sequencing. The core architecture of the device ensures uniform, reproducible column packing without user supervision and accommodates multiple routine protocol steps in any sequence, such as reagent mixing and incubation; column packing, loading, washing, elution, and regeneration; capture of eluted material for use as a substrate in a later step of the protocol; and removal of one column matrix so that two or more column matrices with different functional properties can be used in the same protocol. The microfluidic device is mounted on a plastic carrier so that reagents and products can be aliquoted and recovered using standard pipettors and liquid handling robots. The carrier-mounted device is operated using a benchtop controller that seals and operates the device with programmable temperature control, eliminating any requirement for the user to manually attach tubing or connectors. In addition to NGS library preparation, the device and controller are suitable for automating other time-consuming and error-prone laboratory protocols requiring column chromatography steps, such as chromatin immunoprecipitation. PMID:23894273

  7. Topics in Chemical Instrumentation: Cl. Thermoluminescence, Part I: Principles.

    ERIC Educational Resources Information Center

    Manche, Emanuel P.

    1979-01-01

    Following a delineation of thermoluminescence from a historical perspective and a qualitative description of the process, a treatment of the kinetic process based on a simple model is presented. This treatment model is adequate for the purpose of identifying the essential requirements in instrument design. (BT)

  8. Induced thermoluminescence study of experimentally shock-loaded oligoclase

    NASA Technical Reports Server (NTRS)

    Ivliev, A. I.; Kashkarov, L. L.; Badjukov, D. D.

    1993-01-01

    Artificially induced thermoluminescence (TL) in oligoclase samples which were shock-loaded up to 27 GPa was measured. The essential increase of the TL sensitivity in relation to the total gamma-ray irradiation dose was observed only in samples at the 27 GPa pressure. This result can be explained by the initiation of additional radiation damages in the shocked oligoclace crystal lattice.

  9. Spatial distribution read-out system for thermoluminescence sheets

    NASA Technical Reports Server (NTRS)

    Yamamoto, I.; Tomiyama, T.; Imaeda, K.; Ninagawa, K.; Wada, T.; Yamashita, Y.; Misaki, A.

    1985-01-01

    A spatial distribution read-out system of thermoluminescence (TL) sheets is developed. This system consists of high gain image intensifier, a CCD-TV camera, a video image processor and a host computer. This system has been applied to artificial TL sheets (BaSO4:Eu doped) for detecting high energy electromagnetic shower and heavy nuclei tracks.

  10. Metamorphism of eucrite meteorites studied quantitatively using induced thermoluminescence

    NASA Technical Reports Server (NTRS)

    Batchelor, J. David; Sears, Derek W. G.

    1991-01-01

    Induced thermoluminescence studies provide a new and quantitative means of determining relative metamorphic intensities for eucrite meteorites, the simplest and most ancient products of basaltic volcanism. Using this technique, it is shown that the eucrites constitute a continuous metamorphic series and not, as commonly assumed, two groups of metamorphosed and nonmetamorphosed meteorites. It is suggested that the method may have applications to other basalts.

  11. High-sensitive CaSO4:Dy thermoluminescent phosphor synthesis by co-precipitation technique.

    PubMed

    Lakshmanan, A R; Jose, M T; Annalakshmi, O

    2008-01-01

    This paper describes the successful development of the co-precipitation technique for the preparation of a high-sensitive dysprosium-doped calcium sulphate (CaSO(4):Dy) thermoluminescent dosimetry (TLD) phosphor with dosimetric glow peak at approximately 230 degrees C which is a desired development in the field of radiation protection dosimetry. The main advantages of this co-precipitation technique over the conventional recrystallisation technique of phosphor preparation are: (i) preparation time is very less; (ii) quantity of sulphuric acid evaporated is insignificant; (iii) higher TL sensitivity -20% more than the present material; (iv) better glow curve structure; (v) lesser glow peak shift and better linearity to gamma and (vi) uniform crystal morphology and lower grain size-all grains are mostly cuboidal in shape, quite uniform and small (average size about 25 microm), suitable for manufacturing teflon discs in as-prepared form. Optimum values of various parameters in the method of preparation for a batch of 20 g CaSO(4):Dy phosphors to obtain maximum TL sensitivity, with favourable glow curves are studied. PMID:18716066

  12. Preparation of ultra-pure water and acids and investigation of background of an ICP-MS laboratory.

    PubMed

    Yuan, H; Hu, S; Tong, J; Zhao, L; Lin, S; Gao, S

    2000-09-01

    Ultra-pure water is prepared by distillation, and followed by ion exchange and passing through an E-PURE water purifier. The resulting ultra-pure water has an electrical conductivity of 18 MOmega. Ultra-pure nitric, hydrochloric, hydrofluoric and perchloric acids are prepared by sub-boiling distillation. Spectra for mass range 3-240 amu are scanned by inductively coupled plasma mass spectrometry for tap, distilled, deionized and ultra-pure waters, and extra- and ultra-pure acids. The results show that the sub-boiling distillation greatly improves the quality of all the four acids under investigation. Metal impurities such as 75, 93, 121, 123, 134-138, 181 and 206-209 amu were remarkably reduced (sub-ppb level) after sub-boiling distillation. Configuration of peaks due to the formation of polyatomic ions was similar to the literature values reported elsewhere (S.H. Tan, G. Horlick, Appl. Spectrosc. 40 (4) (1986) 445). PMID:18968057

  13. Effect of adsorbed iron on thermoluminescence and electron spin resonance spectra of Ca-Fe-exchanged montmorillonite

    NASA Technical Reports Server (NTRS)

    Coyne, Lelia M.; Banin, Amos

    1986-01-01

    The ESR spectra and the natural and gamma-induced thermoluminescence (TL) glow curves of a series of variably cation-exchanged Fe-Ca-clays prepared from SWy-1 montmorillonite were examined. The ESR signal intensity associated with surface Fe increased linearly with surface Fe content up to a nominal concentration of 50 percent exchangeable Fe. At above 50 percent exchangeable Fe, no appreciable increase in the signal was noted. The TL intensity decreased linearly with increasing surface Fe up to 50 percent nominal exchangeable Fe. At above 50 percent, the signal was not appreciably further diminished. Possible effects of Fe on quenching of TL are considered.

  14. Determination of Radiation Energy Response for Thermoluminescent Dosimeter TLD-100: Determination of Organ Dose in Diagnostic Radiology

    SciTech Connect

    Deda, Antoneta; Telhaj, Ervis

    2009-04-19

    TLD-100 (thermoluminescent dosimeter) cards (chips) were calibrated using X-rays with energies of 25-250 kV produced by a Cs-137 source. The energy responses of lithium fluoride crystals for different energies of X-rays were studied. QA/QC was then performed in the Albanian Ionizing Radiation Metrology Laboratory. Based on the QA/QC results, the chips were used to study the doses to different organs in diagnostic radiology. Organ dose was evaluated after calculation of e dose in air (Kair), using an ionizing chamber.

  15. Determination of Radiation Energy Response for Thermoluminescent Dosimeter TLD-100: Determination of Organ Dose in Diagnostic Radiology (abstract)

    NASA Astrophysics Data System (ADS)

    Deda, Antoneta; Telhaj, Ervis

    2009-04-01

    TLD-100 (thermoluminescent dosimeter) cards (chips) were calibrated using X-rays with energies of 25-250 kV produced by a Cs-137 source. The energy responses of lithium fluoride crystals for different energies of X-rays were studied. QA/QC was then performed in the Albanian Ionizing Radiation Metrology Laboratory. Based on the QA/QC results, the chips were used to study the doses to different organs in diagnostic radiology. Organ dose was evaluated after calculation of e dose in air (Kair), using an ionizing chamber.

  16. Thermoluminescence and optically stimulated luminescence in various phases of doped Na2SO4

    NASA Astrophysics Data System (ADS)

    Gaikwad, S. U.; Patil, R. R.; Kulkarni, M. S.; Bhatt, B. C.; Moharil, S. V.

    2016-02-01

    The dependence of optically stimulated luminescence (OSL) and thermoluminescence (TL) response due to crystal phase in Cu and Cu,Mg-doped Na2SO4 was studied. Study shows that the slowly cooled samples which crystallize in phase V show good OSL sensitivity whereas the quenched samples of Na2SO4 which crystallize in phase III irrespective of doping show no OSL sensitivity. However, during storage when phase III samples get converted to phase V, samples show OSL sensitivity comparable to freshly prepared samples in phase V. Hence, it is observed that TL-OSL properties of doped Na2SO4 are phase dependent .This study will be helpful in developing OSL phosphors in which phase plays an important role in deciding the desired properties.

  17. Thermoluminescence mechanism in rare-earth-doped magnesium tetra borate phosphors

    NASA Astrophysics Data System (ADS)

    Annalakshmi, O.; Jose, M. T.; Madhusoodanan, U.; Sridevi, J.; Venkatraman, B.; Amarendra, G.; Mandal, A. B.

    2014-07-01

    Magnesium tetra borate (MTB) doped with rare earths (REs) was prepared by the solid state sintering technique. Among the different RE dopants studied in this phosphor, gadolinium-doped phosphors resulted in a dosimetric peak at a relatively higher temperature. The thermoluminescence (TL) emission spectra of RE-doped MTB showed characteristic RE 3+ emissions. Electron paramagnetic resonance measurements were carried out in these phosphors to identify the defect centers formed during gamma irradiation and to establish a mechanism for the TL process. Signals corresponding to (BO 3)2-, O v- were seen upon irradiation which vanished on annealing at 250 °C, showing the role of these centers in the TL process. The thermal activation energies calculated based on the decay of these signals matched well with those calculated on the basis of the usual conventional method showing the validity of the mechanism of TL.

  18. Investigation of thermoluminescence properties of mobile phone screen displays as dosimeters for accidental dosimetry

    NASA Astrophysics Data System (ADS)

    Mrozik, Anna; Marczewska, B.; Bilski, P.; Kłosowski, M.

    2014-11-01

    The rapid assessment of the radiation dose after unexpected exposure is a task of accidental dosimetry. In case of a radiological accident glasses originating from mobile phone screens, placed usually near the human body, could be used as emergency thermoluminescent (TL) personal dosimeters. The time between irradiation and TL readout is crucial and therefore preparation of the mobile phone screens and their readout conditions should be optimized. The influence of the samples etching, bleaching and selection of the optical filters based on measurement of the emission spectrum of irradiated glass samples during heating for different types of mobile phones were the subjects of our investigation. Obtained results showed that glasses extracted from different brands of mobile phones have different dosimetric properties but all of them give a luminescent signal which can be used to calculate the dose.

  19. Sensitivity of a mixed field dosimetry algorithm to uncertainties in thermoluminescent element readings

    SciTech Connect

    Kearfott, K.J.; Samei, E.; Han, S.

    1995-03-01

    An error analysis of the effects of the algorithms used to resolve the deep and shallow dose components for mixed fields from multi-element thermoluminescent (TLD) badge systems was undertaken for a commonly used system. Errors were introduced independently into each of the four element readings for a badge, and the effects on the calculated dose equivalents were observed. A normal random number generator was then utilized to introduce simultaneous variations in the element readings for different uncertainties. The Department of Energy Laboratory Accrediatation Program radiation fields were investigated. Problems arising from the discontinuous nature of the algorithm were encountered for a number of radiation sources for which the algorithm misidentified the radiation field. Mixed fields of low energy photons and betas were found to present particular difficulties for the algorithm. The study demonstrates the importance of small fluctuations in the TLD element`s response in a multi-element approach. 24 refs., 5 figs., 7 tabs.

  20. Application of laboratory prepared and commercially available biochars to adsorption of cadmium, copper and zinc ions from water.

    PubMed

    Bogusz, Aleksandra; Oleszczuk, Patryk; Dobrowolski, Ryszard

    2015-11-01

    The goal of the presented work was the evaluation and comparison of two biochars (produced from Sida hermaphrodita - BCSH/laboratory produced and from wheatstraw - BCS/commercial available) to adsorb heavy metal ions (Cd(II), Cu(II) and Zn(II)) from water. Kinetics of the sorption as well as sorption isotherms, the influence of solution pH and interfering ions were investigated. Different physico-chemical properties of biochars had the great influence on adsorption capacity. The greater adsorption efficiency was observed for BCSH than for BCS in the case of all investigated metals. The adsorption efficiency of BCSH was correlated with higher content of carbon and oxygen, what is equal with higher content of polar-groups on the BCSH surface e.g., -COOH. Furthermore, the molar ratio of O/C as well as polarity index (which was higher for BCSH) was also important parameters. PMID:26295440

  1. Homogeneity and stability studies during the preparation of a laboratory reference material of soy leaves for the determination of metals.

    PubMed

    dos Santos, Ana M P; Lima, Daniel C; de Jesus, Robson M; Ferreira, Sergio L C

    2011-01-01

    The homogeneity and stability of metals were tested in a candidate laboratory reference material of soy leaves. Inductively coupled plasma-optical emission spectrometry was used to quantify calcium, magnesium, manganese, iron, zinc, copper, and vanadium. A 6 kg amount of the material, which was dried, ground, and classified as mesh 60, was distributed among 100 bottles. The between-bottle homogeneity test was established by analyzing two subsamples from nine bottles. For the within-bottle test, five determinations of each element of a single bottle were performed. The stability test was performed at temperatures of -10, +27, and +40 degrees C, and after storage times of 4, 12, 24, and 52 weeks. The obtained results indicated that the material was homogeneous and stable under the conditions studied. PMID:22320099

  2. Report on Department of Homeland Security Sponsored Research Project at Lawrence Livermore National Laboratory on Preparation for an Improvised Nuclear Device Event

    SciTech Connect

    A., B

    2008-07-31

    Following the events of September 11th, a litany of imaginable horribles was trotted out before an anxious and concerned public. To date, government agencies and academics are still grappling with how to best respond to such catastrophes, and as Senator Lieberman's quote says above, now is the time to plan and prepare for such events. One of the nation's worst fears is that terrorists might detonate an improvised nuclear device (IND) in an American city. With 9/11 serving as the catalyst, the government and many NGOs have invested money into research and development of response capabilities throughout the country. Yet, there is still much to learn about how to best respond to an IND event. My summer 2008 internship at Lawrence Livermore National Laboratory afforded me the opportunity to look in depth at the preparedness process and the research that has been conducted on this issue. While at the laboratory I was tasked to collect, combine, and process research on how cities and the federal government can best prepare for the horrific prospect of an IND event. Specific projects that I was involved with were meeting reports, research reviews, and a full project report. Working directly with Brooke Buddemeier and his support team at the National Atmospheric Release Advisory Center, I was able to witness first hand, preparation for meetings with response planners to inform them of the challenges that an IND event would pose to the affected communities. In addition, I supported the Homeland Security Institute team (HSI), which was looking at IND preparation and preparing a Congressional report. I participated in meetings at which local responders expressed their concerns and contributed valuable information to the response plan. I specialized in the psycho-social aspects of an IND event and served as a technical advisor to some of the research groups. Alongside attending and supporting these meetings, I worked on an independent research project which collected

  3. Virtual Simulations as Preparation for Lab Exercises: Assessing Learning of Key Laboratory Skills in Microbiology and Improvement of Essential Non-Cognitive Skills

    PubMed Central

    Makransky, Guido; Thisgaard, Malene Warming; Gadegaard, Helen

    2016-01-01

    Objective To investigate if a virtual laboratory simulation (vLAB) could be used to replace a face to face tutorial (demonstration) to prepare students for a laboratory exercise in microbiology. Methods A total of 189 students who were participating in an undergraduate biology course were randomly selected into a vLAB or demonstration condition. In the vLAB condition students could use a vLAB at home to ‘practice’ streaking out bacteria on agar plates in a virtual environment. In the demonstration condition students were given a live demonstration from a lab tutor showing them how to streak out bacteria on agar plates. All students were blindly assessed on their ability to perform the streaking technique in the physical lab, and were administered a pre and post-test to determine their knowledge of microbiology, intrinsic motivation to study microbiology, and self-efficacy in the field of microbiology prior to, and after the experiment. Results The results showed that there were no significant differences between the two groups on their lab scores, and both groups had similar increases in knowledge of microbiology, intrinsic motivation to study microbiology, as well as self-efficacy in the field of microbiology. Conclusion Our data show that vLABs function just as well as face to face tutorials in preparing students for a physical lab activity in microbiology. The results imply that vLABs could be used instead of face to face tutorials, and a combination of virtual and physical lab exercises could be the future of science education. PMID:27253395

  4. Thermoluminescent properties of ZnS:Mn nanocrystalline powders.

    PubMed

    Ortiz-Hernández, Arturo Agustín; Méndez García, Víctor Hugo; Pérez Arrieta, María Leticia; Ortega Sígala, José Juan; Araiza Ibarra, José de Jesús; Vega-Carrillo, Héctor Rene; Falcony Guajardo, Ciro

    2015-05-01

    Thermoluminescent ZnS nanocrystals doped with Mn(2+) ions were synthesized by chemical co-precipitation method. From X-ray diffraction studies it was observed that the synthesized nanoparticles have cubic zinc blende structure with average sizes of about 40-50nm. Morphology was analyzed by TEM. Photoluminescence studies showed two transitions, one of them close to 396nm and other close to 598nm, which is enhanced with increasing dopant concentration, this behavior was also observed in the cathodoluminescence spectrum. The thermoluminescence gamma dose-response has linear behavior over dose range 5-100mGy, the glow curve structure shows two glow peaks at 436K and at 518K that were taken into account to calculate the kinetic parameters using the Computerized Glow Curve Deconvolution procedure. PMID:25746918

  5. Thermoluminescence properties of gamma-irradiated nano-structure hydroxyapatite.

    PubMed

    Shafaei, M; Ziaie, F; Sardari, D; Larijani, M M

    2016-02-01

    The suitability of nano-structured hydroxyapatite (HAP) for use as a thermoluminescence dosimeter was investigated. HAP samples were synthesized using a hydrolysis method. The formation of nanoparticles was confirmed by X-ray diffraction and average particle size was estimated to be ~30 nm. The glow curve exhibited a peak centered at around 200 °C. The additive dose method was applied and this showed that the thermoluminescence (TL) glow curves follow first-order kinetics due to the non-shifting nature of Tm after different doses. The numbers of overlapping peaks and related kinetic parameters were identified from Tm -Tstop through computerized glow curve deconvolution methods. The dependence of the TL responses on radiation dose was studied and a linear dose response up to 1000 Gy was observed for the samples. PMID:26015169

  6. Thermoluminescence dosimetric properties and effective atomic numbers of window glass

    NASA Astrophysics Data System (ADS)

    Bootjomchai, Cherdsak; Laopaiboon, Raewat

    2014-03-01

    This work presents the main thermoluminescence (TL) dosimetric characteristics of commercial Thai transparent window glass. The amorphous structure of window glass was investigated by XRD. The glow curve revealed a peak (Tm) at 235 °C. The thermoluminescence response of window glass was studied after irradiation with photons in the absorb dose range of 0-14.05 mGy, which is of interest for the personal protection level of dosimetry. A linear response was obtained after both the first irradiation and the second irradiation. The minimum detectable dose of window glass was 0.15 mGy. The effective atomic number of window glass as a function of photon energy was calculated. The obtained results for the effective atomic number showed that it is very close to that of human biological tissues (Zeff = 6.7-8.4 at studied energy).

  7. YAlO3:Ce3+ powders: Synthesis, characterization, thermoluminescence and optical studies

    NASA Astrophysics Data System (ADS)

    Parganiha, Yogita; Kaur, Jagjeet; Dubey, Vikas; Shrivastava, Ravi

    2015-09-01

    Yttrium aluminum perovskite (YAP) is a promising high temperature ceramic material, known for its mechanical, structural and optical properties. YAP's also known as an ideal host material for solid-state lasers and phosphors. In this work, Ce3+ doped YAlO3 phosphors were synthesized by solid state reaction method, which is very suitable technique for large scale production. A prepared phosphor was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Photoluminescence spectra and Thermoluminescence (TL) glow curve study. The starting reagents used for sample preparation are Y2O3, Al2O3 and CeO2, boric acid used as a flux. Ratio of Y:Al was 1:1 which shows perovskite structure confirmed by the X-ray diffraction (XRD) study. The entire prepared sample was studied by PL excitation and emission spectra. Prominent peak at 446 nm (blue emission) which shows broad emission spectra of photoluminescence. It proves that prepared phosphor can act as a single host for blue emission of light and can be used for display applications. Commission Internationale de I'Eclairage (CIE) techniques proves the blue emission of light (x = .148, y = .117). TL glow curve analysis of prepared phosphor shows the prominent peak at 189 °C for the variable UV exposure time and high temperature peak shows the more stability and less fading in the prepared phosphor. Kinetic data of prepared phosphor were evaluated by peak shape method for variable UV exposure time (5-25 min).

  8. Thermoluminescence at a heating rate threshold in stressed fused silica.

    PubMed

    Bouchut, Philippe; Milesi, Frédéric; Da Maren, Céline

    2011-12-19

    The emissive properties of proton implanted fused silica surfaces have been studied by laser beam annealing. When submitted to a high thermal step from a focused CO2 laser, an intense near infra-red transient incandescence (TI) peak rises from stressed silica. The TI presents the characteristics of a thermoluminescent (TL) emission that occurs above a thermal rate threshold. We show that TI rises at the stress relaxation. PMID:22274172

  9. Methods and means of checking thermoluminescent and radiophotoluminescent dosimeters

    SciTech Connect

    Fominykh, V.I.; Oborin, A.V.; Sebekin, A.P.; Uryaev, I.A.

    1987-06-01

    The authors discuss methods of checking thermoluminescent and radiophotoluminescent dosimeters which are used often in monitoring radiation safety in various areas including nuclear power stations. When the dosimeters are checked in the fields of standard beta-ray sources, it is recommended that the standard absorbed-dose or equivalent-dose measures for beta radiation should be sources of /sup 90/Sr + /sup 90/Y, /sup 204/Tl, and /sup 147/Pm. Various safety guidelines are discussed.

  10. Thermoluminescence and dielectric response of gamma irradiated muscovite mica

    SciTech Connect

    Kaur, Sukhnandan Singh, Surinder Singh, Lakhwant; Lochab, S. P.

    2014-04-24

    The effect of gamma radiation dose on the thermoluminescence (TL) and dielectric properties of muscovite mica was studied. TL glow curves exhibited a single peak around 141 {sup 0}C and its activation energy was estimated to be about 0.89 eV. Different dielectric parameters like dielectric constant, dielectric loss and ac conductivity have been calculated in both pristine and gamma irradiated samples. These dielectric parameters have been studied as a function of irradiation dose.

  11. Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory; preparation procedure for aquatic biological material determined for trace metals

    USGS Publications Warehouse

    Hoffman, Gerald L.

    1996-01-01

    A method for the chemical preparation of tissue samples that are subsequently analyzed for 22 trace metals is described. The tissue-preparation procedure was tested with three National Institute of Standards and Technology biological standard reference materials and two National Water Quality Laboratory homogenized biological materials. A low-temperature (85 degrees Celsius) nitric acid digestion followed by the careful addition of hydrogen peroxide (30-percent solution) is used to decompose the biological material. The solutions are evaporated to incipient dryness, reconstituted with 5 percent nitric acid, and filtered. After filtration the solutions were diluted to a known volume and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS), inductively coupled plasma-atomic emission spectrometry (ICP-AES), and cold vapor-atomic absorption spectrophotometry (CV-AAS). Many of the metals were determined by both ICP-MS and ICP-AES. This report does not provide a detailed description of the instrumental procedures and conditions used with the three types of instrumentation for the quantitation of trace metals determined in this study. Statistical data regarding recovery, accuracy, and precision for individual trace metals determined in the biological material tested are summarized.

  12. Thin thermoluminescent dosimeter and method of making same

    DOEpatents

    Simons, Gale G.; DeBey, Timothy M.

    1987-01-01

    An improved thermoluminescent ionizing radiation dosimeter of solid, extremely thin construction for more accurate low energy beta dosimetry is provided, along with a method of fabricating the dosimeter. In preferred forms, the dosimeter is a composite including a backing support (which may be tissue equivalent) and a self-sustaining body of solid thermoluminescent material such as LiF having a thickness of less than about 0.25 millimeters and a volume of at least about 0.0125 mm.sup.3. In preferred fabrication procedures, an initially thick (e.g., 0.89 millimeters) TLD body is wet sanded using 600 grit or less sandpaper to a thickness of less than about 0.25 millimeters, followed by adhesively attaching the sanded body to an appropriate backing. The sanding procedure permits routine production of extremely thin (about 0.05 millimeters) TLD bodies, and moreover serves to significantly reduce non-radiation-induced thermoluminescence. The composite dosimeters are rugged in use and can be subjected to annealing temperatures for increased accuracy.

  13. Thermoluminescence kinetics of pyrite (FeS sub 2 )

    SciTech Connect

    Silverman, A.N; Levy, P.W.; Kierstead, J.A.

    1990-01-01

    Thermoluminescence of pyrite (FeS{sub 2}) has been investigated to study the kinetics of single peak glow curves. The material used normally exhibits one large and four small peaks. However a glow curve can be obtained with only the large single peak that is suitable for testing thermoluminescence kinetics. Glow curves from aliquots of a single natural pyrite crystal studied in detail contain two low intensity thermoluminescence (TL) peaks at {approx}90{degree} and {approx}250{degree}C, and two chemiluminescence (CL) peaks at {approx}350{degree} and {approx}430{degree}C. The CL peaks are largely removable by initially heating the sample chamber under vacuum, pumping through liquid nitrogen traps, and recording glow curves immediately after helium is introduced, procedures which reduce system contaminants that react with pyrite. The shape, the variation of the temperature of the peak maximum (T{sub max}) with dose, and the retrapping to recombination cross section ratio {sigma} of the large 250{degree}C peak are better described by the general one trap (GOT) kinetic equation, the basic equation from which the 1st and 2nd order kinetic equations are obtained as special cases (see text), than by the 1st and 2nd order equations. 12 refs., 7 figs.

  14. Organic Laboratory Experiments.

    ERIC Educational Resources Information Center

    Smith, Sherrel

    1990-01-01

    Detailed is a method in which short pieces of teflon tubing may be used for collection tubes for collecting preparative fractions from gas chromatographs. Material preparation, laboratory procedures, and results of this method are discussed. (CW)

  15. Thermoluminescence in β-irradiated SrZnF4:Dy TLD phosphor

    NASA Astrophysics Data System (ADS)

    Shelke, Tushar R.; Dhoble, S. J.; Nanoti, V. M.

    2014-02-01

    SrZnF4:Dy phosphor was prepared by the wet chemical synthesis and characterized for its X-ray diffraction, thermoluminescence (TL) and photoluminescence (PL) properties. The PL emission spectra for SrZnF4:Dy3+ phosphor at 351 nm excitation give emission at 481 nm (blue) and 575 nm (yellow). The TL properties of SrZnF4:Dy were studied using β-irradiation. The response curve of the prepared phosphor with high-dose β-ray exposure is linear as compared with well-known CaSO4:Dy phosphor. The TL glow curves of SrZnF4:Dy sample showed two well-defined peaks at 143°C (peak-1) and 231°C (peak-2) indicating that two sets of traps are being activated within the particular temperature range and the trapping parameter associated with the prominent glow peaks of SrZnF4:Dy is calculated by using Chen's method.

  16. Thermoluminescence characterization of Dy(3+) -activated Mg₅ (BO₃ )₃ F low Z(eff) phosphor.

    PubMed

    Wani, Javaid A; Dhoble, N S; Dhoble, S J

    2013-01-01

    Thermoluminescence characteristics of Dy(3+) -activated Mg₅ (BO₃ )₃ F low Z(eff) phosphor are described. The Mg₅ (BO₃ )₃ F phosphor doped with Dy(3+) as activator was prepared by the modified solid-state reaction. Formation of the compound was confirmed by use of X-ray powder diffraction. The X-ray powder diffraction pattern of the as-prepared compound shows a good match with the available JCPDS data. The γ-irradiated Mg₅ (BO₃ )₃ F:Dy(3+) phosphor shows a simple glow curve peaking at about 148°C indicating that only one type of trap is being activated within a particular temperature range. The kinetic parameters, including activation energy and frequency factor were determined using Chen's method. The activation energy and frequency factors were 0.75 eV and 4.508 × 10(9) /s respectively. The Z(eff) ofMg₅ (BO₃ )₃ F:Dy(3+) phosphor was 9.84. PMID:23055350

  17. Thermoluminescence characteristics of Israeli household salts for retrospective dosimetry in radiological events

    NASA Astrophysics Data System (ADS)

    Druzhyna, S.; Datz, H.; Horowitz, Y. S.; Oster, L.; Orion, I.

    2016-06-01

    Following a nuclear accident or terror attack involving the dispersal of radioactive substances, radiation dose assessment to first responders and the members of the public is essential. The need for a retrospective assessment of the radiation dose to those possibly affected is, therefore, obligatory. The present study examines the potential use of Israeli household salt as a retrospective dosimeter (RD). The experiments were carried out on Israeli salt samples (NaCl) following a Nielsen market track survey based on scanning data representing the barcoded market, including organized and independent retail chains and a sample of private minimarkets and supermarkets. The technique used was thermoluminescence (TL) dosimetry. Salt samples were exposed to levels of dose from 0.5 mGy to 300 Gy at the Israeli Secondary Standard Dosimetry Laboratory of the Soreq Nuclear Research Center using a calibrated 137Cs source. Our emphasis has been on a detailed investigation of the basic dosimetric characteristics of the salts including: (i) glow curve analysis (ii) individual glow peak dose response (iii) reproducibility (iv) estimation of minimal measurable dose (v) effect of nitrogen readout, (vi) influence of humidity during pre-irradiation storage and (vii) light induced fading. The results are sufficiently favorable to lead to the conclusion that the Israeli household salts can serve as a pragmatic potential candidate for RD under certain restricted conditions. Occasional pre-calibration of the major salt brands in a dedicated laboratory may be essential depending on the required accuracy in the estimation of dose and consequent clinical evaluation.

  18. Heating rate controller for thermally stimulated conductivity and thermoluminescence measurements.

    NASA Technical Reports Server (NTRS)

    Manning, E. G.; Littlejohn, M. A.; Oakley, E. M.; Hutchby , J. A.

    1972-01-01

    A temperature controller is described which enables the temperature of a sample mounted on a cold finger to be varied linearly with time. Heating rates between 0.5 and 10 K/min can be achieved for temperatures between 90 and 300 K. Provision for terminating the sample heating at any temperature between these extremes is available. The temperature can be held at the terminating temperature or be reduced to the starting temperature in a matter of minutes. The controller has been used for thermally stimulated conductivity measurements and should be useful for thermoluminescence measurements as well.

  19. Method of improving BeO as a thermoluminescent detector

    DOEpatents

    Gammage, Richard B.; Thorngate, John H.; Christian, Danny J.

    1980-01-01

    Measurements of radiation exposure below 1 mR are possible with a BeO ceramic thermoluminescent detector (TLD) by treating the TL signal in a manner that discriminates against an interferring pyroelectric incandescence (PI). This is accomplished by differentiating the signals electronically to cause the composite signal to cross the baseline. A zero-crossing detector then senses and clips the negative-going portion of the signal. The resultant signal is integrated, producing a result wherein the true TL signal is substantially greater than the PI signal.

  20. A thermoluminescence dosimetry system for personal monitoring in Ireland.

    PubMed

    Currivan, L; Spain, D; Donnelly, H; Colgan, P A

    2001-01-01

    In 1993 the decision was taken to replace film badges with thermoluminescence dosemeters (TLDs) as the main form of dosemeter for both whole-body and extremity monitoring at the Dosimetry Service of the Radiological Protection Institute of Ireland (RPII) in Dublin. A review of commercially available automatic TLD systems was carried out to identify the system which best met the RPII's requirements. This paper describes the dosimetry system used, and, in addition, discusses the problems encountered and how these were addressed. PMID:11586731

  1. Synthesis and thermoluminescence characterizations of Sr2B5O9Cl:Dy3+ phosphor for TL dosimetry.

    PubMed

    Oza, Abha H; Dhoble, N S; Park, K; Dhoble, S J

    2015-09-01

    The photoluminescence (PL) and thermoluminescence (TL) displayed by Dy-activated strontium haloborate (Sr2 B5 O9 Cl) were studied. A modified solid-state reaction was employed for the preparation of the phosphor. Photoluminescence spectra showed blue (484 nm) and yellow (575 nm) emissions due to incorporation of Dy(3+) into host matrix. The Dy-doped (0.5 mol%) Sr2 B5 O9 Cl was studied after exposure to γ-irradiation and revealed a prominent glow curve at 261°C with a small hump around 143°C indicating that two types of traps were generated. The glow peak at the higher temperature side (261°C) was more stable than the lower temperature glow peak. The TL intensity was 1.17 times less than that of the standard CaSO4 :Dy thermoluminescence dosimetry (TLD) phosphor, the phosphor showed a linear dose-response curve for different γ-ray irradiation doses (0.002-1.25 Gy) and fading of 5-7% was observed for higher temperature peaks upon storage. Trapping parameters and their estimated error values have been calculated by Chen's peak shape method and by the initial rise method. Values of activation energies estimated by both these techniques were comparable. The slight difference in activation energy values calculated by Chen's peak shape method indicated the formation of two kinds of traps Furthermore, slight differences in frequency values are due to various escaping and retrapping probabilities. PMID:25428207

  2. Validity of repeated initial rise thermoluminescence kinetic parameter determinations

    SciTech Connect

    Kierstead, J.A.; Levy, P.W.

    1990-01-01

    The validity of thermoluminescence (TL) analysis by repeated initial rise measurements has been studied by computer simulation. Thermoluminescence described by 1st Order, 2nd Order, General One Trap and Interactive TL Kinetics was investigated. In the simulation each of the repeated temperature increase and decrease cycles contains a linear temperature increase followed by a decrease appropriate for radiative cooling, i.e. the latter is approximated by a decreasing exponential. The activation energies computed from the simulated emission are readily compared with those used to compute the TL emission. In all cases studied, the repeated initial rise technique provides reliable results only for single peak glow curves or for glow curves containing peaks that do not overlap and, if sufficiently separated, the lowest temperature peak in multipeak curves. Also the temperatures, or temperature cycles corresponding to correct activation energies occur on the low temperature side of the normal glow curve, often well below the peak temperature. A variety of misleading and/or incorrect results an be obtained when the repeated initial rise technique is applied to TL systems that produce overlapping peaks in the usual glow curve. 6 refs., 10 figs.

  3. Synthesis, characterization, thermoluminescence and optical studies of Eu3+ doped Y2SiO5 phosphor

    NASA Astrophysics Data System (ADS)

    Parganiha, Yogita; Kaur, Jagjeet; Dubey, Vikas; Chandrakar, Deepika

    2015-01-01

    The present paper reports thermoluminescence (TL) glow curves and photoluminescence (PL) studies of europium doped yttrium silicate (Y2SiO5:Eu3+). The samples were prepared by the modified Solid state method which is the most suited method for large scale production. Starting material used for sample preparation was Y2O3, SiO2 and Eu2O3 with variable concentration of europium. A prepared sample was characterized by XRD (X-ray diffraction) and crystallite size found 20-50 nm in size. The PL excitation spectra was found at 265 and 395 nm while the emission spectra was found at 580, 588, 595, 598, 612, 615, 623 and 626 nm, the emission peak at 612 nm was most intense peak for all Eu3+ concentration. The effect of Eu3+ concentration on PL intensity was studied and found that intensity increases with increasing concentration up to 2.5 mol% of Eu3+. Commission Internationale de l'Eclairage co-ordinate (CIE) of this phosphor is (0.65, 0.31) in the red region. TL glow curves were recorded for different doses of UV exposure at a heating rate of 6.7 °C s-1. The kinetic parameters as activation energy 'E', the order of kinetics 'b', and the frequency factor 's' of Y2SiO5:Eu3+ have been calculated by using peak shape method. The sample shows general order kinetics. The effect of Eu3+ concentration on TL intensity was also studied and found that the intensity increases linearly up to 1 mol% and then decreases with increasing concentration of Eu3+. The present phosphor acts as a single host for red emission display devices and light emitting diode (LED) as well as may be used for thermoluminescence dosimetric material under UV exposure.

  4. Thermoluminescence and the origin of the dark matrix of Fayetteville and similar meteorites

    NASA Technical Reports Server (NTRS)

    Haq, Munir; Hasan, Fouad A.; Sears, Derek W. G.; Moore, Carleton B.; Lewis, Charles F.

    1989-01-01

    The paper presents measurements of the induced thermoluminescence properties and carbon contents of the dark matrix and light clasts of six regolith breccias. For all of the meteorites, the dark matrix has a lower mean thermoluminescence sensitivity than the light clasts; the extent of the difference depends on the meteorite. The data suggest the formation of the dark matrix by comminution of the light clasts with the addition of a component, perhaps CM-like chondrites, with thermoluminescence properties distinct from those of ordinary chondrites.

  5. Pooling of cultured samples and comparison of multistate laboratory workflows with the MagMAX sample preparation system and VetMAX quantitative polymerase chain reaction reagents for detection of Tritrichomonas foetus-colonized bulls.

    PubMed

    Effinger, Lee; Peddireddi, Lalitha; Simunich, Marilyn; Oberst, Richard; O'Connell, Catherine; Leyva-Baca, Ivan

    2014-01-01

    The objectives of the current study were 1) to compare sample preparation workflows and quantitative real-time polymerase chain reaction assays (qPCR) as currently used in veterinary diagnostic laboratories with a study protocol utilizing commercially available reagents for individual Tritrichomonas foetus testing, 2) to assess the accuracy of pooling cultured smegma samples followed by extraction and qPCR testing as used in the study laboratory, and 3) to assess the specificity of the currently used primers and probes by sequencing all positive and presumptive positive samples identified in the study laboratory in an attempt to capture any nucleotide variability between T. foetus isolates and to rule out false-positive results possibly due to Simplicimonas moskowitzi. Eight hundred three cultured smegma samples were collected from different regions of the United States with the collaboration of 5 veterinary testing laboratories. The samples were processed individually by the respective laboratories, and then sent to the study laboratory and retested using the study protocol. Comparison testing showed an overall agreement of 95.89% between the veterinary testing laboratories and the study laboratory. One hundred seventy-six positive or presumptive positive samples plus 625 negative qPCR samples were combined and retested using a pooling protocol. Pools consisted of 1 positive sample and 4 negative samples (1/5). These pools were processed using the same study laboratory protocols, and 96% of the positive samples were detected in these pools. Nested PCR followed by sequencing confirmed 175 of the 178 samples classified as positive or presumptive positive in the study laboratory as containing T. foetus-specific DNA. PMID:24343558

  6. Effect of thermal annealing on the thermoluminescent properties of nano-calcium fluoride and its dose-response characteristics.

    PubMed

    Mundupuzhakal, J K; Biswas, R H; Chauhan, S; Varma, V; Acharya, Y B; Chakrabarty, B S

    2015-12-01

    Nano-CaF2, prepared by the co-precipitation method, was annealed under different annealing conditions to improve its thermoluminescence (TL) characteristics. Different annealing parameters, such as temperature (400-700°C), duration (1-4 h) and environment (vacuum and air), were explored. The effect on TL sensitivity, peak position (Tm) and full-width at half-maximum (FWHM) with respect to the different annealing conditions are discussed as they are the measure of crystallinity of the material. Annealing temperature of 500°C with annealing duration of two and a half hours in vacuum provided the highest luminescence response (i.e. maximum sensitivity, minimum peak temperature and FWHM). Wide detectable dose range (5 mGy to 2 kGy), absence of thermal quenching and sufficient activation energy (1.04 eV) of this phosphor make it suitable for dosimetric applications. PMID:25398396

  7. Thermoluminescence dosimetry properties and kinetic parameters of lithium potassium borate glass co-doped with titanium and magnesium oxides.

    PubMed

    Hashim, S; Alajerami, Y S M; Ramli, A T; Ghoshal, S K; Saleh, M A; Abdul Kadir, A B; Saripan, M I; Alzimami, K; Bradley, D A; Mhareb, M H A

    2014-09-01

    Lithium potassium borate (LKB) glasses co-doped with TiO2 and MgO were prepared using the melt quenching technique. The glasses were cut into transparent chips and exposed to gamma rays of (60)Co to study their thermoluminescence (TL) properties. The TL glow curve of the Ti-doped material featured a single prominent peak at 230 °C. Additional incorporation of MgO as a co-activator enhanced the TL intensity threefold. LKB:Ti,Mg is a low-Z material (Z(eff)=8.89) with slow signal fading. Its radiation sensitivity is 12 times lower that the sensitivity of TLD-100. The dose response is linear at doses up to 10(3) Gy. The trap parameters, such as the kinetics order, activation energy, and frequency factor, which are related to the glow peak, were determined using TolAnal software. PMID:24929526

  8. Thermoluminescence dating analysis at the site of an ancient brick structure at Pengkalan Bujang, Malaysia.

    PubMed

    Sabtu, Siti Norbaini; Mahat, Rosli Hj; Amin, Yusoff Mohd; Price, David M; Bradley, D A; Maah, Mohd Jamil

    2015-11-01

    Bujang Valley is a well-known historical complex found in the north-west of peninsular Malaysia; more than 50 ancient monuments and hundreds of artefacts have been discovered throughout the area. The discovery of these suggests Bujang Valley to have been an important South East Asian trading centre over the period from the 10th to 14th centuries. Present work concerns thermoluminescence (TL) dating analysis of shards collected from a historic monument located at Pengkalan Bujang in Bujang Valley. All the shards were prepared using the fine grain technique and the additive dose method was applied in determining the paleodose of each shard. The annual dose rate was obtained by measuring the concentration of naturally occurring radionuclides (U, Th and K) in the samples and their surroundings. The TL ages of the shards were found to range between 330±21 years and 920±69 years, indicative of the last firing of the bricks and tiles from which the shards originated, some dating back to the period during which the historical complex remained active. PMID:26319091

  9. Photoluminescence and thermoluminescence characteristics of Sr3 B2 O6 :Eu(2+) yellow phosphor.

    PubMed

    Ho Van, Tuyen; Nguyen Manh, Son; Vu Xuan, Quang; Bounyavong, Sengthong

    2016-08-01

    Sr3 B2 O6 :Eu(2+) yellow phosphor was prepared by the combustion method. The crystalline structure, photoluminescence and thermoluminescence properties of Sr3 B2 O6 :Eu(2+) were investigated extensively. The X-ray diffraction result indicates that the Sr3 B2 O6 :Eu(2+) phosphor exhibited a rhombohedral crystal structure. The emission spectra under a 435 nm excited wavelength showed an intense broad band peaking at 574 nm, which corresponds to the 4f(6) 5d(1) → 4f(7) transition of Eu(2+) ion. There were two different sites of Sr replaced by Eu in host lattice. The concentration quenching process between Eu(2+) ions is determined and the corresponding concentration quenching mechanism was verified as dipole-quadrupole interaction. The glow curve under 3 Gy β- ray irradiation had the glow peak at 160°C and the average activation energy was defined as about 0.98 eV. Copyright © 2015 John Wiley & Sons, Ltd. PMID:26669720

  10. Synthesis, characterization and thermoluminescence studies of Mn-doped ZnS nanoparticles.

    PubMed

    Chandrakar, Raju Kumar; Baghel, R N; Chandra, B P

    2016-03-01

    ZnS:Mn nanoparticles were prepared by a chemical precipitation method and characterized by X-ray diffraction (XRD), field emission gun scanning electron microscope (FEGSEM), and high resolution transmission electron microscopy (HRTEM). Capping agent (mercaptoethanol) concentrations used were 0 M, 0.005 M, 0.01 M, 0.015 M, 0.025 M, 0.040 M, and 0.060 M, and resulted in nanoparticles sizes of 2.98 nm, 2.9 nm, 2.8 nm, 2.7 nm, 2.61 nm, 2.2 nm and 2.1 nm, respectively. The thermoluminescence (TL) glow curve was recorded by heating the sample exposed to UV-radiation, at a fixed heating rate 1°C sec(-1). The TL intensity initially increased with temperature, attained a peak value Im for a particular temperature, and then decreased with further increase in temperature. The peak TL intensity increased with decreasing nanoparticle size, whereas the temperature corresponding to the peak TL intensity decreased slightly with reducing nanocrystal size. As a consequence of increase in surface-to-volume ratio and increased carrier recombination rates, the TL intensity increased with decreasing nanoparticle size. It was found that, whereas activation energy slightly decreased with decreasing nanoparticle size, the frequency factor decreased significantly with reduction in nanoparticle size. PMID:26105811

  11. Synthesis and characterisation of BaSo4:Eu thermoluminescence phosphor.

    PubMed

    Annalakshmi, O; Jose, M T; Madhusoodanan, U

    2012-06-01

    Polycrystalline powder samples of BaSO(4) doped with Eu(2+) were prepared by solid-state reaction in different reducing atmospheres. Photoluminescence (PL), thermoluminescence (TL), TL kinetic and dosimetric studies have been carried out in this phosphor. The TL glow curve of BaSO(4):Eu(2+) showed only a single peak at 513 K unlike other phosphors and the TL intensity is about three to four times higher than that of CaSO(4):Dy, which is currently used as the radiation dosemeter for personnel monitoring in India. The TL dose response of the phosphor was found to be linear up to the dose range of 10(3) Gy beyond which saturation sets in. PL and TL spectra showed the characteristic emission of Eu(2+) ion. The TL parameters such as trap depth (E) or the energy required to release the electron or hole from the trap, frequency factor (s) and the order of kinetics (b) are determined by different methods such as isothermal decay, initial rise and variable heating rate. PMID:22223718

  12. Synthesis, photoluminescence, thermoluminescence and dosimetry properties of novel phosphor Zn(BO2)2:Tb

    NASA Astrophysics Data System (ADS)

    Li, J.; Zhang, C. X.; Tang, Q.; Zhang, Y. L.; Hao, J. Q.; Su, Q.; Wang, S. B.

    2007-02-01

    Polycrystalline powder samples of terbium doped Zn(BO2)2 phosphors were prepared by solid state reaction in the thermal carbon reducing atmosphere at high temperature. The photoluminescence (PL), three-dimensional (3D) TL emission spectrum and dosimetric characteristics following 60Co gamma-rays irradiation were studied. Characteristic emission bands of Tb3+ at about 490, 543, 584 and 620 nm, attributed to the 5D4→7FJ (J=3, 4, 5, 6) transitions of Tb3+ ions, were observed in the TL and PL emission spectrum. No emission from Tb4+ ions was observed in the TL emission spectrum. The TL-dose response of the powder samples Zn(BO2)2:Tb to 60Co gamma-rays radiation in the dose range from 1 to 100 Gy for clinical dose levels was almost linear. The experiment results showed that Zn(BO2)2:Tb has potential use as the materials of gamma-rays thermoluminescence dosimeter (TLD) for clinical dosimetry.

  13. Thermoluminescence constraints on the metamorphic, shock, and brecciation history of basaltic meteorites

    NASA Technical Reports Server (NTRS)

    Batchelor, J. D.; Sears, Derek W. G.

    1991-01-01

    The metamorphic, shock, and brecciation history of 18 eucrites, 13 howardites, 6 diogenites, and 15 mesosiderites is investigated via induced thermoluminescence measurements performed on them. The eucrites show a 15-fold range of TL sensitivities, which correlate with petrographic indicators of metamorphic intensity. The temperature of the dominant TL peak observed for basaltic meteorites, and experiments in which four eucrites with diverse petrographic properties were annealed at various temperatures in the laboratory, suggests that the metamorphic equilibration temperatures for most basaltic meteorites were not more than 800 C. Assuming this temperature was typical of conditions during metamorphism, then burial depths for type-above-5 eucrites were greater than 350 m and less than 50 m for type-2 eucrites. Since TL peak temperatures are related to the degree of disorder in the Al, Si chain in feldspar, the present data provide independent evidence for very slow cooling rates for mesosiderites and for the slower cooling rates for some cumulate eucrites relative to equilibrated noncumulate eucrites.

  14. Evaluation of discrepancies between thermoluminescent dosimeter and direct-reading dosimeter results

    SciTech Connect

    Shaw, K.R.

    1993-07-01

    Currently at Oak Ridge National Laboratory (ORNL), the responses of thermoluminescent dosimeters (TLDs) and direct-reading dosimeters (DRDs) are not officially compared or the discrepancies investigated. However, both may soon be required due to the new US Department of Energy (DOE) Radiological Control Manual. In the past, unofficial comparisons of the two dosimeters have led to discrepancies of up to 200%. This work was conducted to determine the reasons behind such discrepancies. For tests conducted with the TLDs, the reported dose was most often lower than the delivered dose, while DRDs most often responded higher than the delivered dose. Trends were identified in personnel DRD readings, and ft was concluded that more training and more control of the DRDs could improve their response. TLD responses have already begun to be improved; a new background subtraction method was implemented in April 1993, and a new dose algorithm is being considered. It was concluded that the DOE Radiological Control Manual requirements are reasonable for identifying discrepancies between dosimeter types, and more stringent administrative limits might even be considered.

  15. Characterization of amorphous thermoluminescence dosimeters for patient dose measurement in X-ray diagnostic procedures

    NASA Astrophysics Data System (ADS)

    Ramli, N. N. H.; Salleh, H.; Mahdiraji, G. A.; Zulkifli, M. I.; Hashim, S.; Bradley, D. A.; M. Noor, N.

    2015-11-01

    We investigate the use of novel Ge-doped amorphous silica flat fibers as thermoluminescence dosimeters (TLDs) in verifying patient entrance surface-dose (ESD) in diagnostic examinations. Selected fibers with established dosimetric characteristics (including energy dependence, linearity, reproducibility, and fading) were loaded into plastic capsules in groups of six. The fibers have been calibrated against a parallel plate ionization chamber, use being made of x-rays generated at 70 kVp, accessing a Secondary Standards Dosimetry Laboratory (SSDL) facility. The fiber characterization measurements were made using a Toshiba X-ray machine operating within the nominal energies range 40 kVp to 150 kVp, for doses in the range 0.02 mGy up to 3 mGy. For doses from 2 mGy up to 150 mGy, the flat fibers exhibit linearity between TL yield and dose, reproducible to better than 3% standard deviation following repeat measurements (n=3). A marked energy-dependent response is observed for photons generated at potentials from 40 kVp to 150 kVp. From present results, it is concluded that Ge-doped fibers represent a viable system for use in diagnostic dosimetry, corrections being made for the various factors influencing TL yield.

  16. Thermoluminescence dating of sediments: a re-extension of age range for loess

    SciTech Connect

    Johnson, R.J.; Stipp, J.J.; Wintle, A.G.; Tamers, M.A.

    1985-01-01

    Thermoluminescence (TL) dating of wind blown minerals provides a technique whereby non-carbonaceous sediments could be dated to several hundred thousand years. Two recent reports, however, indicate age underestimates on feldspar in some European loesses older than 50 ka, the effect increasing in severity with age. Suggested causes include decay of luminescence centers, or does dependent sensitivity changes. Data presented in this paper do not support these limitations or explanations. TL provides 3 separate techniques of dating sediments, which, when used together, prove to be efficient internal cross checks for mineralogical anomalies or inconsistencies created by any of the individual methods. In the authors studies each sample was dated by all 3 methods whereas the Europeans analyses employed only the Regeneration technique. This work presents results from loess sections in Mississippi, Illinois and Alaska. These show excellent internal consistency, and consistency with both independent dating methods and stratigraphy, with 2 exceptions. Both exceptions were by the Regen technique giving age underestimates up to 30%. The underestimates were found to be caused by a change in mineral sensitivity resulting from the Regen requirements of strong laboratory light-bleaching followed by irradiations. A simple method to test and correct for this condition is presented. TL thus appears to remain a powerful and increasingly flexible method of sediment dating.

  17. Thermoluminescence emission spectra for the LiF:Mg,Cu,Na,Si thermoluminescent materials with various concentrations of the dopants (3-D measurement).

    PubMed

    Lee, J I; Lee, D; Kim, J L; Chang, S Y

    2006-01-01

    The thermoluminescence (TL) emission spectra from LiF TL materials, called KLT-300 (LiF:Mg,Cu,Na,Si) with various dopant concentrations are measured and analysed. These KLT-300 materials were developed by the Korea Atomic Energy Research Institute (KAERI) to achieve an enhancement of the thermal stability in TL readings. Six types of samples are prepared with different dopant concentrations in the following ranges; Mg (0-0.20 mol%), Cu (0-0.05 mol%), Na and Si (0-0.9 mol%). The spectra measurements are carried out for the six types of samples using a TL emission spectra measurement device. The spectra measurement device consists of a monochromator, photomultiplier tube and temperature control unit to thermally stimulate the samples. The measured data shows the light emission during heating of the sample as a function of temperature and wavelength (three-dimensional TL spectra). The spectra were analysed using a method of deconvolution based on gaussian curve. The wavelength of a main peak of the emission spectra changes depending on the existence of the Cu dopant, while intensity of the spectra rapidly changes with the Cu dopant concentrations. The 385 nm emission is mainly observed in all the spectra from the samples with the Cu dopant, but in those from the samples without the Cu dopant a very weak 401 nm emission is mainly observed. However, any change in the wavelength at a main peak of the TL emission spectra from the sample materials with Na and Si dopants is not observed but that in the intensity at a peak of the spectra is observed. PMID:16644972

  18. Structural characterization, thermoluminescence and EPR studies of Nd{sub 2}O{sub 3}:Co{sup 2+} nanophosphors

    SciTech Connect

    Umesh, B.; Eraiah, B.; Nagabhushana, H.; Sharma, S.C.; Sunitha, D.V.; Nagabhushana, B.M.; Rao, J.L.; Shivakumara, C.; Chakradhar, R.P.S.

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ► Nd{sub 2}O{sub 3}:Co{sup 2+} (1–4 mol%) nanophosphors have been prepared at much lower temperatures. ► Phosphors are well characterized by PXRD, SEM, TEM, FTIR, Raman, UV–vis spectroscopy. ► EPR and thermoluminescence properties were also reported. ► TL intensity increases linearly with γ dose suggesting usage in radiation dosimetry. -- Abstract: Nd{sub 2}O{sub 3}:Co{sup 2+} (1–4 mol%) nanophosphors (15–25 nm) have been prepared via low temperature solution combustion method. Scanning electron micrograph (SEM) shows that the product is highly porous in nature. The stokes line in the Raman spectrum at ∼2000 cm{sup −1} is assigned to F{sub g} mode and the anti-stokes lines are assigned to a combination of A{sub g} + E{sub g} modes. With increase of Co{sup 2+} concentration, the intensity of F{sub g} mode decreases, whereas the combination of A{sub g} + F{sub g} modes completely disappears. Electron paramagnetic resonance (EPR) spectrum exhibits two resonance signals with effective g values at g = 2.25 and g = 2.03. Thermoluminescence (TL) response of Nd{sub 2}O{sub 3}:Co{sup 2+} nanopowders with γ dose 0.23–2.05 kGy was studied. The activation energy (E) and frequency factor (s) are estimated using Chen's glow peak shape method and obtained to be in the range 0.45–1.67 eV and 1.8 × 10{sup 4} to 4.0 × 10{sup 12} s{sup −1}, respectively. It is observed that the TL glow peak intensity at 430 K increases linearly with γ dose which is suitable for radiation dosimetry.

  19. Improving thermoluminescence response through the fabrication of novel microstructured fibers

    NASA Astrophysics Data System (ADS)

    Dermosesian, E.; Amouzad Mahdiraji, G.; Mahamd Adikan, F. R.; Bradley, D. A.

    2015-11-01

    We present a novel technique aimed at improving upon the thermoluminescence (TL) response of optical fibers. The technique, based on the stack-and-draw method, is more conventionally used for microstructured optical fiber (MOF) fabrication. Utilizing the approach, the TL response of a single microstructured fiber can be shown to substantially improve upon that of a single capillary fiber, approaching a 30 fold increase in sensitivity. Present results provide strong support for the idea that by collapsing and fusing the surface walls of stacked fibers, strain-related defects are created, increasing the TL yield many times over. The substantial increase in sensitivity of these glass-based systems point to more extensive applications, the production of such detectors allowing versatile use, down to much lower doses than currently available using single capillary fibers.

  20. Stereotactic radiosurgery dosimetry using thermoluminescent dosimeters and radiochromic films

    NASA Astrophysics Data System (ADS)

    Ávila-Rodríguez, Miguel A.; Rodríguez-Villafuerte, Mercedes; Perches, Rodolfo Díaz

    2000-10-01

    In this work we present a protocol to measure absorbed dose distributions in stereotactic radiosurgery treatments with a linear accelerator (Linac) using thermoluminescent dosimeters (TLD) and radiochromic dye films. A Linac Philips SL-15 (6 MV X-rays), a ZD2 stereoactic system for localizing the target via computed tomography (CT), and Leibinger radiosurgery accessories will be used. A versatile spherical acrylic phantom of 16 cm diameter to measure the dose distributions has been designed. The phantom is composed of two hemispheres. On one flat side of the hemispheres an array of Harshaw/Bicron TLD-100 or a sheet of GafChromic MD-55 film will be placed. The phantom will be irradiated in three different orientations to obtain spatial dose distributions in the coronal, sagital and transverse planes. The experimental measurement will be compared with the results provided by a commercial treatment-planning system.

  1. Fossil track and thermoluminescence studies of Luna 20 material.

    NASA Technical Reports Server (NTRS)

    Crozaz, G.; Walker, R.; Zimmerman, D.

    1973-01-01

    Track densities in 85 feldspar crystals from L-2009 range from 2,500,000 per sq cm to greater than one billion per sq cm. This track distribution represents an intermediate case between what have been previously defined as lightly and heavily irradiated soils and suggests that the Luna 20 sample consists of a mixture of a mature, heavily irradiated component with another, lightly irradiated component. Using a two-component mixing model, the age of the lightly irradiated component is about 270,000,000 yr. It is possible, but by no means certain, that this is associated with the formation of the crater Apollonius C. At about 200 C the ratio of natural thermoluminescence to that induced by a standard irradiation is similar to that in Apollo 12 and 14 cores below about 7 cm. This confirms that most of the Luna 20 sample represents subsurface material.

  2. Hydrothermally synthesized barium fluoride nanocubes for thermoluminescence dosimetry

    NASA Astrophysics Data System (ADS)

    Bhadane, Mahesh S.; Dahiwale, S. S.; Bhoraskar, V. N.; Dhole, S. D.

    2016-05-01

    In this work, we report a hydrothermally synthesized Dy doped BaF2 (BaF2:Dy) nanocubes and its Thermoluminescence studies. The synthesized BaF2:Dy samples was found to posses FCC structure and having average size ~ 60-70 nm, as revealed through X-Ray Diffraction. Cubical morphology having size ~90 nm was observed from TEM analysis. The 60Co γ- ray irradiated BaF2:Dy TL dosimetric experiments shows a pre-dominant single glow peak at 153 °C, indicating a single level trap present as a metastable state. Furthermore, BaF2:Dy nanophosphor shows a sharp linear response from 10 Gy to 3 kGy, thus it can be applicable as a gamma dosimeter.

  3. Natural thermoluminescence profiles in lunar cores and implications for meteorites

    NASA Technical Reports Server (NTRS)

    Benoit, P. H.; Sears, D. W. G.

    1993-01-01

    Meteorites and lunar samples have been irradiated by high energy cosmic rays, typically for millions of years. In addition to producing isotopic changes, the irradiation creates ionization which may be recorded in the form of stored thermoluminescence (TL) in certain minerals, the most important of which is feldspar. One aspect of interpreting the TL of these samples is the effect of 'shielding' or depth control, which is particularly important for meteorites, since they have lost an unknown amount of mass during atmospheric entry. Here we report theoretical calculations which we compare with samples from lunar cores for which we have excellent stratigraphic control. We then discuss the implications for these results for the TL of meteorites, which have a different irradiation geometry. We find that, in general, calculated profiles are similar to those observed in lunar samples and meteorites. Additional effects, such as orbital (thermal) history and terrestrial age must also be considered in the case of meteorites.

  4. The natural thermoluminescence of meteorites. III - Lunar and basaltic meteorites

    NASA Technical Reports Server (NTRS)

    Sears, Derek W. G.; Benoit, Paul H.; Sears, Hazel; Batchelor, J. D.; Symes, Steve

    1991-01-01

    Natural thermoluminescence (TL) data were obtained to investigate recent thermal and radiation histories of the lunar meteorite MacAlpine Hills 88104/5 and 65 eucrites, howardites, diogenites, and mesosiderites. All these meteorites have low levels of natural TL compared to chondrites, which is primarily because they display anomalous fading. Some meteorites have especially low natural TL which must reflect heating within the last 100,000-1,000,000 y. The parameters for TL decay were determined assuming plausible values for cosmic ray dose rate and that the natural TL of MAC88104/5 was totally drained by ejection from the moon. The obtained parameters for TL decay suggest that the moon-earth transit times for MAC88104 and MAC88105 were 2,000 and 1,800 y, respectively, compared with 19,000 and 2,500 y for Y791197 and ALHA81005, respectively.

  5. Synthesis and thermoluminescence of boron-doped germanium nanowires

    NASA Astrophysics Data System (ADS)

    Zahedifar, M.; Hosseinmardi, F.; Eshraghi, L.; Ganjipour, B.

    2011-03-01

    Boron doped germanium nanowires were synthesized using chemical vapor deposition (CVD) with Au nanoparticles as nucleating centers, germanium tetrachloride as the source of germanium and B 2H 6 gas as source of boron impurity. Au nanoparticles were deposited on Si using 3-aminopropyltriethylsilane (APTES). The single crystal Ge nanowires with diameters ranging from 19 to 200 nm were grown in a controllable manner. Effects of Au nanoparticle size, argon gas flow, temperature and duration of growth on diameter and length of nanowires were investigated. This is the first report on thermoluminescence (TL) properties of boron doped germanium nanowires. Glow curves were fitted using computerized glow curve deconvolution program and seven overlapped peaks were obtained. Further the response of synthesized nanowires to different dose levels of UV was studied and linear response regime was determined.

  6. Thermoluminescent dosimeter measurements and analysis for LDEF experiment M0006

    NASA Technical Reports Server (NTRS)

    Stauber, Michael C.; Chang, J.; Kantorcik, T.

    1991-01-01

    Glow curve measurements are reported up to 600 C of (Thermoluminescent Dosimeter Measurement) TLD-100 (LiF) samples deployed on Long Duration Exposure Facility (LDEF) and retained as ground control. Lab exposure simulations are also reported with Co-60 radiation, low energy light ions and high energy protons in an effort to replicate the glow curves, especially the high temperature peaks observed in the LDEF TLD specimens. The evidence to date clearly shows the effect of inflight anneal on the low temperature part of the glow curve. It also shows that the high temperature part of the glow curve appears due to ion dose deposition. Initial correlations between high temperature glow peaks and effective LET of the registered dose is given.

  7. Evaluation of two thermoluminescent detection systems for medical imaging environments.

    PubMed

    Kearfott, K J; Nabelssi, B K; Rucker, R H; Klingler, G W

    1990-12-01

    Thermoluminescent detectors (TLDs) can provide accurate and precise measurements for both patient and personnel dosimetry in the medical imaging environment. They have the advantages of tissue equivalency, an excellent dynamic range, and dose rate independence. In the work reported here, experiments with planar x-ray, fluoroscopy, and a 57Co source were conducted to test the repeatability and energy dependence of an LiF TL ribbon/automatic reader system and a four-element CaSO2 and Li2B4O7 badge/automatic reader system for diagnostic radiology and nuclear medicine dosimetry. The results indicate the usefulness and appropriateness of the TLD systems tested for both personnel and patient dosimetry in the medical diagnostic environment. PMID:2228610

  8. Evaluation of two thermoluminescent detection systems for medical imaging environments

    SciTech Connect

    Kearfott, K.J.; Nabelssi, B.K.; Rucker, R.H.; Klingler, G.W. )

    1990-12-01

    Thermoluminescent detectors (TLDs) can provide accurate and precise measurements for both patient and personnel dosimetry in the medical imaging environment. They have the advantages of tissue equivalency, an excellent dynamic range, and dose rate independence. In the work reported here, experiments with planar x-ray, fluoroscopy, and a 57Co source were conducted to test the repeatability and energy dependence of an LiF TL ribbon/automatic reader system and a four-element CaSO2 and Li2B4O7 badge/automatic reader system for diagnostic radiology and nuclear medicine dosimetry. The results indicate the usefulness and appropriateness of the TLD systems tested for both personnel and patient dosimetry in the medical diagnostic environment.

  9. Thermoluminescence dating of calcite shells in the pectinidae family

    NASA Astrophysics Data System (ADS)

    Ninagawa, Kiyotaka; Adachi, Kenji; Uchimura, Noboru; Yamamoto, Isao; Wada, Tomonori; Yamashita, Yoshihiko; Takashima, Isao; Sekimoto, Katsuhisa; Hasegawa, Hiroichi

    Previously we investigated the thermoluminescence (TL) of a calcite shell, Pectinidae Pecten (Notovola) albicans (Schröter) (abbreviated to albicans), and we found that TL dating was possible for fossil calcite shells of albicans from 5 × 10 5 years ago to the present. In the present work, we investigate the TL emission spectra and the first glow-growth of 5 other species in the Pectinidae family, and it is found that the TL characteristics of these species are the same as those of the albicans. This means that the application of TL dating can be extended to these species. Furthermore, we tried to date fossil calcite shells older than 5 × 10 5 years ago, and we found that the upper limit for TL dating of fossil calcite shells is about 6 × 10 5 years.

  10. Comparison on characteristics of radiophotoluminescent glass dosemeters and thermoluminescent dosemeters.

    PubMed

    Hsu, Shih-Ming; Yeh, Shann-Horng; Lin, Meei-Shiow; Chen, Wei-Li

    2006-01-01

    The radiophotoluminescent glass dosemeter (RPLGD) system is applicable for measurement of radiation dose of X rays and gamma rays by using radiophotoluminescent glass (silver-activated phosphate glass). When the radiophotoluminescent glass is exposed to ionizing radiation, stable luminescent centres are created. During pulsed ultraviolet laser excitation (337.1 nm) in the reader, the centres emit a radiation induced orange fluorescent light (600-700 nm). This phenomenon is called radiophotoluminescence. This study compared the RPLGD system with lithium fluoride (LiF) thermoluminescence dosimetry system and the results of the study revealed that the RPLGD had not only good basic characteristics for reproducibility of readout value, dose linearity, energy dependence and fading, but also infinite repeatable measurements and could be one of the most important radiation dose measurement instruments. PMID:16709718

  11. Dating loess up to 800 ka by thermoluminescence

    SciTech Connect

    Berger, G.W. ); Pillans, B.J. ); Palmer, A.S. )

    1992-05-01

    Thermoluminescence (TL) ages agreeing with expected ages have been obtained for 13 loess samples spanning the age range from 20 to 800 ka. The authors samples are from Alaska and North Island, New Zealand, and are unusual in TL dating studies of loess older than 80-100 ka by having independent age assignments that are generally well constrained, from ages of associated tephra beds. With the polymineral fine-silt-sized (4-11 {mu}m) grains the partial-bleach TL technique yielded expected ages up to about 350 ka, whereas the total-bleach method gave accurate ages in the range 100 to 800 ka. Thus, the much disputed upper age limit of 100-150 ka for the TL dating of loess now appears to be sample and worker dependent, rather than a global property of the TL signals in the TL-dominant feldspars.

  12. Thermoluminescence and optically stimulated luminescence properties of natural barytes.

    PubMed

    Kitis, G; Kiyak, N G; Polymeris, G S

    2010-12-01

    Heavy, baryte-loaded, concrete is commonly used as radiation shielding material around high energy particle accelerators. Concrete samples received from a shielding block located at CERN cite contain many crystalline inclusions which were identified as barytes by X-ray diffraction analysis and separated by their color, classified as white, orange and green. Basic properties of thermoluminescence (TL) and optically stimulated luminescence (OSL) signals of these barytes samples such as thermal and optical stability, repeatability and mainly the linearity of both their luminescence responses were investigated as a function of beta dose. These results are also discussed regarding detailed investigation on the correlation between TL and OSL signals and their implications for retrospective dosimetry. PMID:20620071

  13. Positional glow curve simulation for thermoluminescent detector (TLD) system design

    NASA Astrophysics Data System (ADS)

    Branch, C. J.; Kearfott, K. J.

    1999-02-01

    Multi- and thin element dosimeters, variable heating rate schemes, and glow-curve analysis have been employed to improve environmental and personnel dosimetry using thermoluminescent detectors (TLDs). Detailed analysis of the effects of errors and optimization of techniques would be highly desirable. However, an understanding of the relationship between TL light production, light attenuation, and precise heating schemes is made difficult because of experimental challenges involved in measuring positional TL light production and temperature variations as a function of time. This work reports the development of a general-purpose computer code, thermoluminescent detector simulator, TLD-SIM, to simulate the heating of any TLD type using a variety of conventional and experimental heating methods including pulsed focused or unfocused lasers with Gaussian or uniform cross sections, planchet, hot gas, hot finger, optical, infrared, or electrical heating. TLD-SIM has been used to study the impact on the TL light production of varying the input parameters which include: detector composition, heat capacity, heat conductivity, physical size, and density; trapped electron density, the frequency factor of oscillation of electrons in the traps, and trap-conduction band potential energy difference; heating scheme source terms and heat transfer boundary conditions; and TL light scatter and attenuation coefficients. Temperature profiles and glow curves as a function of position time, as well as the corresponding temporally and/or spatially integrated glow values, may be plotted while varying any of the input parameters. Examples illustrating TLD system functions, including glow curve variability, will be presented. The flexible capabilities of TLD-SIM promises to enable improved TLD system design.

  14. From films to thermoluminescence dosemeters: the Greek Atomic Energy Commission experience.

    PubMed

    Carinou, E; Drikos, G; Hourdakis, C; Hyvönen, H; Kamenopoulou, V

    2001-01-01

    The personnel dosimetry department of the Greek Atomic Energy Commission (GAEC) assures the individual monitoring of almost 8000 occupationally exposed workers. Thermoluminescence dosimetry systems will replace the existing photographic dosimetry system for the individual monitoring with the joint support of IAEA and GAEC. The thermoluminescence dosimetry system consists of two automated readers, one automated irradiator and about 20,000 dosemeters purchased from the Rados Co. The properties of two thermoluminescent materials have been compared: LiF has been chosen for the whole-body dosemeter configuration and Li2B4O7 for the extremities. The technical evaluation of the system has been performed according to the European and IEC standards. The overall uncertainty has been calculated. The existing database system, and the accounting and dispatching procedures have been adapted to the new demands. The system became operational on March 2000, and the official distribution of thermoluminescence dosemeters has begun. PMID:11586730

  15. Topics in Chemical Instrumentation: Cl. Thermoluminescence. Part III. Application to Archeological Dating.

    ERIC Educational Resources Information Center

    Manche, Emanuel P.; Ewing, Galen W., Ed.

    1979-01-01

    Thermoluminescence and its application to archeological dating are considered in this article. Descriptions are given of the method, the required doses, absolute and relative dating, complications, and the relation of this type of dating to other methods. (SA)

  16. The Interpretation of Natural Thermoluminescence Data for Meteorites: Theoretical Basis and Practical Application

    NASA Technical Reports Server (NTRS)

    Benoit, P. H.; Sears, D. W. G.

    2000-01-01

    Natural thermoluminescence (TL) of ordinary chondrites reflects their irradiation and thermal history. We discuss the quantitative aspects of TL interpretation, with an emphasis on the terrestrial history of Antarctic meteorites and the orbital history of modern falls.

  17. Thermoluminescence Sensitivity and Thermal History of Unequilibrated Ordinary Chondrites: Review and Update

    NASA Technical Reports Server (NTRS)

    Benoit, P. H.; Ninagawa, K.; Sears, D. W. G.

    2000-01-01

    We report on the induced thermoluminescence (TL) data for 102 unequilibrated ordinary chondrites. We discuss these data in terms of pairing, weathering, and parent body thermal history. We identify ten possible meteorites of petrologic types 3.0-3.1.

  18. DOSSIER SUR "LA FORMATION PROFESSIONNELLE DES DIRECTEURS DE LABORATOIRE DE LANGUES" (PROPOSED COURSE OF STUDY FOR THE PROFESSIONAL PREPARATION OF LANGUAGE LABORATORY DIRECTORS).

    ERIC Educational Resources Information Center

    PLASTRE, GUY

    THE NEED FOR LANGUAGE LABORATORY SPECIALISTS TO MEET THE CHANGES IN MODERN LANGUAGE PEDAGOGY IS EMPHASIZED BY THE AUTHOR IN THIS REPORT. SUGGESTIONS ARE GIVEN FOR SPECIALIZED COURSES OF STUDY TOWARD A MASTER'S DEGREE FOR LANGUAGE LABORATORY DIRECTORS. SELECTIONS SHOULD BE MADE FROM BLOCKS OF COURSES IN (1) LINGUISTICS, MODERN LANGUAGES,…

  19. Evaluation of tooth preparations for Class II cavities using magnification loupes among dental interns and final year BDS students in preclinical laboratory

    PubMed Central

    Narula, Khyati; Kundabala, Mala; Shetty, Neetha; Shenoy, Ramya

    2015-01-01

    Background: With the advances in optical technology, dentistry has been benefitted in varied ways over the ages. Aim: The aim of this study was to assess the effect of dental magnification loupes on psychomotor skill acquisition during preclinical operative exercise. Methods: 40 Typhodont teeth tooth no. 36 and 46 (Frasaco - U.S.A.) were mounted on the acrylic lower jaw base of Phantom Head. Teeth are prepared for class II (MO) cavity with conservative design using micromotor, mouth mirror and probe. Tooth no.36 was prepared using magnifying loupes while tooth no.46 was prepared without the loupes. Data collected was statistically analyzed using Chi square test. Results: The results revealed that tooth preparations were better under magnifying loupes as compared to those without it with statistically significant difference with Kappa value 0.64 for samples with loupes and 0.76 for without loupes. Moreover, the study samples expressed their difficulty for using the magnifying loupes during the tooth preparation since they were using it for the first time. Conclusions: Magnifying loupes help the dental students to have better vision, thus improved dexterity with hands while preparing the tooth for restoration. However, dental students have to get adapted to the loupes for the ease of using loupes. Using loupes frequently may help them to get adapted to the loupes. PMID:26180411

  20. Spectral investigation of the thermoluminescence of heated flint (silex)

    NASA Astrophysics Data System (ADS)

    Richter, D.; Krbetschek, M. R.; Rieser, U.; Trautmann, T.; Wagner, G. A.

    1999-02-01

    Test measurements to determine the sufficient heating of silex (flint) artifacts from prehistoric sites for TL dating revealed a large variation of TL-characteristics. To determine TL-emission wavelengths suitable for dating, the spectra of several samples from different geological origin were measured. A dominant emission in the orange band was found, consisting of three peaks centred around 90-130°C, 190 and 270°C or only a broad single peak at around 250°C. Two UV peaks appear at 100-190°C and around 360°C. At the latter temperature a blue emission occurs as well. Simulation experiments of prehistoric fires for various temperatures were performed. In contrast to the blue emission the UV emission around 360°C shows slight fading and/or bleaching. The blue band also requires slightly lower temperatures for complete resetting than the UV-TL. Furthermore, this blue-TL emission is less light sensitive, especially for red laboratory light, making sample preparation much more convenient. Sufficiently heated silex samples can easily be detected by the position of the high temperature TL-peak at about 360°C and a Gaussian-like shape of the blue peak, and of course by the plateau test. The observed TL-variation of heated archaeological silex might be due to the different genesis of the material, but it can also be attributed to different degrees of ancient heating.

  1. Influence of γ-dose, dopant/codopant and heating rate on thermoluminescence properties of CaWO{sub 4} phosphors

    SciTech Connect

    Ambast, A. K. Sharma, S. K.

    2015-08-28

    A series of Ca{sub 1-2x}K{sub x}Dy{sub x}WO{sub 4} (x = 0.02, 0.03, 0.04) phosphors were prepared by solid state reaction method and their thermoluminescence properties were investigated. Before thermoluminescence measurements, the sample was heated to 300°C for 1hour and then quenched to room temperature to erase out all the previous radiation memory. The prepared phosphors were irradiated by γ-ray in the dose range 1KGy–5KGy and their glow curves were recorded at an uniform rate of 5°C/s. In order to see the effect of heating rate as well as concentration of dopant/codopant, TL glow curves were also recorded by heating the samples at the rate of 3°C/s and 7°C/s as well as by varying the concentration x = 0.02, 0.03, 0.04.

  2. Dose distribution around a needle-like anode X-ray tube: dye-film vs. planar thermoluminescent detectors.

    PubMed

    Budzanowski, M; Olko, P; Marczewska, B; Czopyk, L; Slapa, M; Stras, W; Traczyk, M; Talejko, M

    2006-01-01

    The dosimetry around the X-ray tube with a needle-like anode (NAXT), developed at the Institute of Nuclear Studies, for interstitial brachytherapy has been performed using (1) dye films (Gafchromic XR-T), (2) large-area thermoluminescent (TL) detectors--prepared either by gluing TL powder onto thin Al foil (so-called planar detectors with spatial resolution of 0.1 mm) and (3) miniature (2 mm diameter and 0.5 mm thick) TL detectors. The measurements were performed in following geometries. (1) Needle inside a PMMA cylinder--the planar TL detector mounted on the surface of the cylinder. (2) Needle inside a thick block of PMMA and TL detector mounted vertically 7 mm from needle axis. TL detectors were read with the planar (2D) thermoluminescence reader, developed at IFJ, with a sensitive CCD (charge couple device) camera. Gafchromic films were evaluated with a system based on Agfa Arcus 1200 scanner and calibrated with X rays (35 kV) filtered with 0.03 mm Mo and with Co-60 photons. The intensity distribution of TL light on the planar detector was calibrated in terms of absorbed dose to water, using (137)Cs gamma-rays. TL planar detectors seem to be a promising tool for 2D dosimetry of miniature X-ray sources. Obtained results for TLDs and Gafchromic films seem to be comparable but differences have been found. Both methods are useful for measurements of dose distribution around the NAXT X-rays source. PMID:16614087

  3. Neutron Activation and Thermoluminescent Detector Responses to a Bare Pulse of the CEA Valduc SILENE Critical Assembly

    SciTech Connect

    Miller, Thomas Martin; Celik, Cihangir; McMahan, Kimberly L.; Lee, Yi-kang; Gagnier, Emmanuel; Authier, Nicolas; Piot, Jerome; Jacquet, Xavier; Rousseau, Guillaume; Reynolds, Kevin H.

    2015-09-01

    This benchmark experiment was conducted as a joint venture between the US Department of Energy (DOE) and the French Commissariat à l'Energie Atomique (CEA). Staff at the Oak Ridge National Laboratory (ORNL) in the US and the Centre de Valduc in France planned this experiment. The experiment was conducted on October 11, 2010 in the SILENE critical assembly facility at Valduc. Several other organizations contributed to this experiment and the subsequent evaluation, including CEA Saclay, Lawrence Livermore National Laboratory (LLNL), the Y-12 National Security Complex (NSC), Babcock International Group in the United Kingdom, and Los Alamos National Laboratory (LANL). The goal of this experiment was to measure neutron activation and thermoluminescent dosimeter (TLD) doses from a source similar to a fissile solution critical excursion. The resulting benchmark can be used for validation of computer codes and nuclear data libraries as required when performing analysis of criticality accident alarm systems (CAASs). A secondary goal of this experiment was to qualitatively test performance of two CAAS detectors similar to those currently and formerly in use in some US DOE facilities. The detectors tested were the CIDAS MkX and the Rocky Flats NCD-91. These detectors were being evaluated to determine whether they would alarm, so they were not expected to generate benchmark quality data.

  4. Laboratory investigations

    NASA Technical Reports Server (NTRS)

    Russell, Ray W.

    1988-01-01

    Laboratory studies related to cometary grains and the nuclei of comets can be broken down into three areas which relate to understanding the spectral properties, the formation mechanisms, and the evolution of grains and nuclei: (1) Spectral studies to be used in the interpretation of cometary spectra; (2) Sample preparation experiments which may shed light on the physical nature and history of cometary grains and nuclei by exploring the effects on grain emissivities resulting from the ways in which the samples are created; and (3) Grain processing experiments which should provide insight on the interaction of cometary grains with the environment in the immediate vicinity of the cometary nucleus as the comet travels from the Oort cloud through perihelion, and perhaps even suggestions regarding the relationship between interstellar grains and cometary matter. A summary is presented with a different view of lab experiments than is found in the literature, concentrating on measurement techniques and sample preparations especially relevant to cometary dust.

  5. Percentage depth dose evaluation in heterogeneous media using thermoluminescent dosimetry.

    PubMed

    da Rosa, L A R; Cardoso, S C; Campos, L T; Alves, V G L; Batista, D V S; Facure, A

    2010-01-01

    The purpose of this study is to investigate the influence of lung heterogeneity inside a soft tissue phantom on percentage depth dose (PDD). PDD curves were obtained experimentally using LiF:Mg,Ti (TLD-100) thermoluminescent detectors and applying Eclipse treatment planning system algorithms Batho, modified Batho (M-Batho or BMod), equivalent TAR (E-TAR or EQTAR), and anisotropic analytical algorithm (AAA) for a 15 MV photon beam and field sizes of 1 x 1, 2 x 2, 5 x 5, and 10 x 10 cm 2 . Monte Carlo simulations were performed using the DOSRZnrc user code of EGSnrc. The experimental results agree with Monte Carlo simulations for all irradiation field sizes. Comparisons with Monte Carlo calculations show that the AAA algorithm provides the best simulations of PDD curves for all field sizes investigated. However, even this algorithm cannot accurately predict PDD values in the lung for field sizes of 1 x 1 and 2 x 2 cm 2 . An overdosage in the lung of about 40% and 20% is calculated by the AAA algorithm close to the interface soft tissue/lung for 1 x 1 and 2 x 2 cm 2 field sizes, respectively. It was demonstrated that differences of 100% between Monte Carlo results and the algorithms Batho, modified Batho, and equivalent TAR responses may exist inside the lung region for the 1 x 1 cm 2 field. PMID:20160687

  6. Thermoluminescence in gallium sulfide crystals: an unusual heating rate dependence

    NASA Astrophysics Data System (ADS)

    Delice, S.; Bulur, E.; Gasanly, N. M.

    2015-03-01

    Trap centres in gallium sulfide single crystals have been investigated by thermoluminescence measurements in the temperature range of 10-230 K. A curve-fitting method was utilized to evaluate the activation energies (52, 200 and 304 meV) of the revealed three trap centres. The heating rate dependence and trap distribution of the peaks have been studied using experimental techniques based on various heating rates and various illumination temperatures, respectively. An anomalous heating rate dependence of the high-temperature peak was found by carrying out TL measurements with various heating rates between 0.2 and 1.0 K/s. This behaviour was explained on the basis of a semi-localized transition model. Whereas normal heating rate dependence was established for low-temperature peak, that is, the TL intensity of the glow curve decreases and the peak maximum temperature shifts to higher values with increasing the heating rate. Moreover, a quasi-continuous trap distribution with the increase of activation energies from 52 to 90 meV, from 200 to 268 meV and from 304 to 469 meV for the observed three different traps was established employing the various illumination temperatures method.

  7. Dose measurements in intraoral radiography using thermoluminescent dosimeters

    NASA Astrophysics Data System (ADS)

    Azorín, C.; Azorín, J.; Aguirre, F.; Rivera, T.

    2015-01-01

    The use of X-ray in medicine demands to expose the patient and the professional to the lowest radiation doses available in agreement with ALARA philosophy. The reference level for intraoral dental radiography is 7 mGy and, in Mexico, a number of examinations of this type are performed annually. It is considered that approximately 25% of all the X-rays examinations carried out in our country correspond to intraoral radiographies. In other hand, most of the intraoral X-ray equipment correspond to conventional radiological systems using film, which are developed as much manual as automatically. In this work the results of determining the doses received by the patients in intraoral radiological examinations made with different radiological systems using LiF:Mg,Cu,P+PTFE thermoluminescent dosimeters are presented. In some conventional radiological systems using film, when films are developed manual or automatically, incident kerma up to 10.61 ± 0.74 mGv were determined. These values exceed that reference level suggested by the IAEA and in the Mexican standards for intraoral examinations.

  8. Thermoluminescence response of natural white quartz collected from Gelephu, Bhutan

    NASA Astrophysics Data System (ADS)

    Kalita, J. M.; Wary, G.

    2016-09-01

    TL properties of natural quartz mineral collected from Gelephu, (Bhutan) were studied. With the help of various characterization techniques the quality of the sample was tested. The thermoluminescence (TL) analysis was carried out under X-ray irradiation. The un-irradiated sample showed no TL signal; however, after X-ray irradiation, a composite glow curve was observed. The kinetic analysis of the glow curve was carried out and it was observed that there was five trapping sites at depths ∼0.68, 0.90, 0.97, 1.06 and 1.10 eV responsible for five closely spaced glow peaks at ∼341, 362, 383, 397 and 426 K respectively. The dosimetric features of the mineral were studied. The response when studied from the whole glow curve was non-linear. However, the dose response studied from the 426 K peak was found to be linear from 10 mGy to 10 Gy. The fading of the TL signal of this 426 K peak was ∼12% within 5 days after irradiation and onward it was ∼4% up to 30 days. The reproducibility of the results was also good.

  9. Analysis of thermoluminescent glow peaks of zoisite under beta irradiations

    SciTech Connect

    Ccallata, Henry Javier; Watanabe, Shigueo

    2010-08-04

    In this study, the thermoluminescence (TL) properties of natural crystal of zoisite were investigated after beta ({sup 90}Sr) irradiation at room temperature (RT). Zoisite, of chemical formula Ca{sub 2}Al{sub 3}(SiO{sub 4})(Si{sub 2}O{sub 7})O(OH), is found in Minas Gerais State, Brazil as natural mineral of silicate, member of the epidote group. The glow curve of a natural sample submitted to a heat treatment at 600 deg. C is composed of two broad peaks, centered at about 110-130 deg. C and another one at about 205-210 deg. C. A heating rate of 4 deg. C s{sup -1} was used in the temperature range from RT to 300 deg. C. The additive dose, T{sub m}-T{sub STOP} thermal cleaning, initial rise, variable heating rate and computerized glow curve deconvolution methods have shown that the glow curve is a superposition of six peaks at 100, 130, 155, 175, 200 and 230 deg. C. The trapping parameters for the individual peaks have been calculated. The TL dose response of 130 and 200 deg. C peaks has a linear response. Zoisite is a candidate for a TL dosimeter because of its high sensitivity.

  10. Thermoluminescence dosimetry measurements of brachytherapy sources in liquid water

    SciTech Connect

    Tailor, Ramesh; Tolani, Naresh; Ibbott, Geoffrey S.

    2008-09-15

    Radiation therapy dose measurements are customarily performed in liquid water. The characterization of brachytherapy sources is, however, generally based on measurements made with thermoluminescence dosimeters (TLDs), for which contact with water may lead to erroneous readings. Consequently, most dosimetry parameters reported in the literature have been based on measurements in water-equivalent plastics, such as Solid Water. These previous reports employed a correction factor to transfer the dose measurements from a plastic phantom to liquid water. The correction factor most often was based on Monte Carlo calculations. The process of measuring in a water-equivalent plastic phantom whose exact composition may be different from published specifications, then correcting the results to a water medium leads to increased uncertainty in the results. A system has been designed to enable measurements with TLDs in liquid water. This system, which includes jigs to support water-tight capsules of lithium fluoride in configurations suitable for measuring several dosimetric parameters, was used to determine the correction factor from water-equivalent plastic to water. Measurements of several {sup 125}I and {sup 131}Cs prostate brachytherapy sources in liquid water and in a Solid Water phantom demonstrated a correction factor of 1.039{+-}0.005 at 1 cm distance. These measurements are in good agreement with a published value of this correction factor for an {sup 125}I source.