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Sample records for laser-induced spark dplis

  1. Evaluation and Characterization Study of Dual Pulse Laser-Induced Spark (DPLIS) For Rocket Engine Ignition System Application

    NASA Technical Reports Server (NTRS)

    Trinh, Huu P.; Early, Jim; Osborne, Robin

    2002-01-01

    This paper addresses the progress of technology development of a laser ignition system at NASA Marshall Space Flight Center (MSFC). Initial hot-fire tests in a small-scale rocket chamber at MSFC have demonstrated the DPLIS concept having two main advantages over existing laser ignition concepts. First, the DPLIS can be potentially optimized its laser pulse format to maximize the initial plasma volume, the plasma lifetime, as well as the flame kernel growth rate. Characterization studies of the laser pulse format are now underway with experiments of igniting gaseous hydrogen/air in a Hencken burner. Once ignition is achieved, the flame is open to the atmosphere. This open environment allows easy access for diagnostics of the ignition phenomenon. The quick turn-around time of conducting experiments on this burner make it more amenable for conducting a large number of experiments for statistical analysis of the sensitivity of the test parameters. The results from these experiments will help optimize the laser format for future testing in an H2/O2 subscale rocket chamber.

  2. Evaluation and Characterization Study of Dual Pulse Laser-Induced Spark (DPLIS) for Rocket Engine Ignition System Application

    NASA Technical Reports Server (NTRS)

    Osborne, Robin; Wehrmeyer, Joseph; Trinh, Huu; Early, James

    2003-01-01

    This paper addresses the progress of technology development of a laser ignition system at NASA Marshall Space Flight Center (MSFC). Laser ignition has been used at MSFC in recent test series to successfully ignite RP1/GOX propellants in a subscale rocket chamber, and other past studies by NASA GRC have demonstrated the use of laser ignition for rocket engines. Despite the progress made in the study of this ignition method, the logistics of depositing laser sparks inside a rocket chamber have prohibited its use. However, recent advances in laser designs, the use of fiber optics, and studies of multi-pulse laser formats3 have renewed the interest of rocket designers in this state-of the-art technology which offers the potential elimination of torch igniter systems and their associated mechanical parts, as well as toxic hypergolic ignition systems. In support of this interest to develop an alternative ignition system that meets the risk-reduction demands of Next Generation Launch Technology (NGLT), characterization studies of a dual pulse laser format for laser-induced spark ignition are underway at MSFC. Results obtained at MSFC indicate that a dual pulse format can produce plasmas that absorb the laser energy as efficiently as a single pulse format, yet provide a longer plasma lifetime. In an experiments with lean H2/air propellants, the dual pulse laser format, containing the same total energy of a single laser pulse, produced a spark that was superior in its ability to provide sustained ignition of fuel-lean H2/air propellants. The results from these experiments are being used to optimize a dual pulse laser format for future subscale rocket chamber tests. Besides the ignition enhancement, the dual pulse technique provides a practical way to distribute and deliver laser light to the combustion chamber, an important consideration given the limitation of peak power that can be delivered through optical fibers. With this knowledge, scientists and engineers at Los

  3. Laser induced spark ignition of methane-oxygen mixtures

    NASA Technical Reports Server (NTRS)

    Santavicca, D. A.; Ho, C.; Reilly, B. J.; Lee, T.-W.

    1991-01-01

    Results from an experimental study of laser induced spark ignition of methane-oxygen mixtures are presented. The experiments were conducted at atmospheric pressure and 296 K under laminar pre-mixed and turbulent-incompletely mixed conditions. A pulsed, frequency doubled Nd:YAG laser was used as the ignition source. Laser sparks with energies of 10 mJ and 40 mJ were used, as well as a conventional electrode spark with an effective energy of 6 mJ. Measurements were made of the flame kernel radius as a function of time using pulsed laser shadowgraphy. The initial size of the spark ignited flame kernel was found to correlate reasonably well with breakdown energy as predicted by the Taylor spherical blast wave model. The subsequent growth rate of the flame kernel was found to increase with time from a value less than to a value greater than the adiabatic, unstretched laminar growth rate. This behavior was attributed to the combined effects of flame stretch and an apparent wrinkling of the flame surface due to the extremely rapid acceleration of the flame. The very large laminar flame speed of methane-oxygen mixtures appears to be the dominant factor affecting the growth rate of spark ignited flame kernels, with the mode of ignition having a small effect. The effect of incomplete fuel-oxidizer mixing was found to have a significant effect on the growth rate, one which was greater than could simply be accounted for by the effect of local variations in the equivalence ratio on the local flame speed.

  4. Benefits and applications of laser-induced sparks in real scale model measurements.

    PubMed

    Gómez-Bolaños, Javier; Delikaris-Manias, Symeon; Pulkki, Ville; Eskelinen, Joona; Hæggström, Edward; Jeong, Cheol-Ho

    2015-09-01

    The characteristics of using a laser-induced spark as a monopole source in scale model measurements were assessed by comparison with an electric spark and a miniature spherical loudspeaker. Room impulse responses of first order directivity sources were synthesized off-line using six spatially distributed sparks. The source steering direction was scanned across the horizontal and vertical plane to assess the origin of early reflections. The results confirm that the characteristics of the laser-induced spark outperform those of typical sources. Its monopole characteristics enable the authors to synthesize room responses of directional sources, e.g., to obtain directional information about reflections inside scale models. PMID:26428809

  5. Laser-induced spark ignition fundamental and applications

    SciTech Connect

    Tran, P.X.

    2006-05-01

    Laser ignition has become an active research topic in recent years because it has the potential to replace the conventional electric spark plugs in engines that are required to operate under much higher compression ratios, faster compression rates, and much leaner fuel-to-air ratios than gas engines today. It is anticipated that the igniter in these engines will face with pressures as high as 50MPa and temperatures as high as 4000 K. Using the conventional ignition system, the required voltage and energy must be greatly increased (voltages in excess of 40 kV) to reliably ignite the air and fuel mixture under these conditions. Increasing the voltage and energy does not always improve ignitability but it does create greater reliability problem. The objective of this paper is to review past work to identify some fundamental issues underlying the physics of the laser spark ignition process and research needs in order to bring the laser ignition concept into the realm of reality.

  6. High-speed laser-induced fluorescence and spark plug absorption sensor diagnostics for mixing and combustion studies in engines.

    PubMed

    Cundy, Michael; Schucht, Torsten; Thiele, Olaf; Sick, Volker

    2009-02-01

    Simultaneous high-speed in-cylinder measurements of laser-induced fluorescence of biacetyl as a fuel tracer and mid-infrared broadband absorption of fuel and combustion products (water and carbon dioxide) using a spark plug probe are compared in an optical engine. The study addresses uncertainties and the applicability of absorption measurements at a location slightly offset to the spark plug when information about mixing at the spark plug is desired. Absorbance profiles reflect important engine operation events, such as valve opening and closing, mixing, combustion, and outgassing from crevices. PMID:19183588

  7. Production of organic compounds in plasmas - A comparison among electric sparks, laser-induced plasmas, and UV light

    NASA Astrophysics Data System (ADS)

    Scattergood, T. W.; McKay, C. P.; Borucki, W. J.; Giver, L. P.; van Ghyseghem, H.; Parris, J. E.; Miller, S. L.

    1989-10-01

    In order to ascertain the features of organic compound-production in planetary atmospheres under the effects of plasmas and shocks, various mixtures of N2, CH4, and H2 modeling the atmosphere of Titan were subjected to discrete sparks, laser-induced plasmas, and UV radiation. The experimental results obtained suggest that UV photolysis from the plasma is an important organic compound synthesis process, as confirmed by the photolysis of gas samples that were exposed to the light but not to the shock waves emitted by the sparks. The thermodynamic equilibrium theory is therefore incomplete in the absence of photolysis.

  8. Production of organic compounds in plasmas - A comparison among electric sparks, laser-induced plasmas, and UV light

    NASA Technical Reports Server (NTRS)

    Scattergood, Thomas W.; Mckay, Christopher P.; Borucki, William J.; Giver, Lawrence P.; Van Ghyseghem, Hilde

    1989-01-01

    In order to ascertain the features of organic compound-production in planetary atmospheres under the effects of plasmas and shocks, various mixtures of N2, CH4, and H2 modeling the atmosphere of Titan were subjected to discrete sparks, laser-induced plasmas, and UV radiation. The experimental results obtained suggest that UV photolysis from the plasma is an important organic compound synthesis process, as confirmed by the photolysis of gas samples that were exposed to the light but not to the shock waves emitted by the sparks. The thermodynamic equilibrium theory is therefore incomplete in the absence of photolysis.

  9. Production of organic compounds in plasmas: a comparison among electric sparks, laser-induced plasmas, and UV light.

    PubMed

    Scattergood, T W; McKay, C P; Borucki, W J; Giver, L P; Van Ghyseghem, H; Parris, J E; Miller, S L

    1989-01-01

    The chemistry in planetary atmospheres that is induced by processes associated with high-temperature plasmas is of broad interest because such processes may explain many of the chemical species observed. There are at least two important phenomena that are known to generate plasmas (and shocks) in planetary atmospheres: lightning and meteor impacts. For both phenomena, rapid heating of atmospheric gases leads to formation of a high-temperature plasma which emits radiation and produces shock waves that propagate through the surrounding atmosphere. These processes initiate chemical reactions that can transform simple gases into more complex compounds. In order to study the production of organic compounds in plasmas (shocks), various mixtures of N2, CH4, and H2, modeling the atmosphere of Titan, were exposed to discrete sparks, laser-induced plasmas (LIP), an ultraviolet radiation. The yields of HCN and several simple hydrocarbons were measured by gas chromatography and compared to those calculated from a simple quenched thermodynamic equilibrium model. The agreement between experiment and theory was fair for HCN and C2H2. However, the agreement for C2H6 and the other hydrocarbons was poor, indicating that a more comprehensive theory is needed. Our experiments suggest that photolysis by ultraviolet light from the plasma is an important process in the synthesis. This was confirmed by the photolysis of gas samples exposed to the light but not to the shock waves emitted by the sparks. Hence, the results of these experiments demonstrate that the thermodynamic equilibrium theory does not adequately model lightning and meteor impacts and that photolysis must be included. Finally, the similarity in yields between the spark and the LIP experiments suggest that LIP provide valid and clean simulations of lightning and meteor impacts and that photolysis must be included. Finally, the similarity in yields between the spark and the LIP experiments suggests that LIP provide valid

  10. Analysis of tungsten carbide coatings by infrared laser-induced argon spark with inductively coupled plasma atomic emission spectrometry

    NASA Astrophysics Data System (ADS)

    Kanický, V.; Otruba, V.; Mermet, J.-M.

    2000-10-01

    Infrared laser ablation was studied for application to the analysis of plasma-sprayed tungsten carbide/cobalt coatings. The potential of the laser induced argon-spark (LINA-Spark™), as a sample introduction device in inductively coupled plasma atomic emission spectrometry was studied. The use of an IR laser along with defocusing led to laser-induced microplasma-based ablation. The mass ablation rate, represented by the ICP emission intensity per laser beam unit area, exhibited a flat increase in the irradiance range 2-250 GW/cm 2. A low slope (0.5) of this dependence in log-log scale gave evidence of plasma shielding. The steep increase in the measured acoustic signal when focused in front of the sample, i.e. in argon, indicated a breakdown of argon. Consequently, considerably lower ICP emissions were observed within the same range of irradiance. The cobalt/tungsten line intensity ratio in the ICP was practically constant from 1.5 up to at least 250 GW/cm 2. Acceptable precision (R.S.D.<5%) was obtained without internal standardization for irradiance between 2 and 8 GW/cm 2. Optimization of the laser pulse energy, repetition rate, beam focusing and sample displacement during interaction led to the linearization of dependences of signal vs. cobalt percentage, at least up to the highest studied value of 23% Co.

  11. Investigating the dynamics of laser induced sparks in atmospheric helium using Rayleigh and Thomson scattering

    SciTech Connect

    Nedanovska, E.; Nersisyan, G.; Lewis, C. L. S.; Riley, D.; Graham, W. G.; Morgan, T. J.; Hüwel, L.; Murakami, T.

    2015-01-07

    We have used optical Rayleigh and Thomson scattering to investigate the expansion dynamics of laser induced plasma in atmospheric helium and to map its electron parameters both in time and space. The plasma is created using 9 ns duration, 140 mJ pulses from a Nd:YAG laser operating at 1064 nm, focused with a 10 cm focal length lens, and probed with 7 ns, 80 mJ, and 532 nm Nd:YAG laser pulses. Between 0.4 μs and 22.5 μs after breakdown, the electron density decreases from 3.3 × 10{sup 17 }cm{sup −3} to 9 × 10{sup 13 }cm{sup −3}, while the temperature drops from 3.2 eV to 0.1 eV. Spatially resolved Thomson scattering data recorded up to 17.5 μs reveal that during this time the laser induced plasma expands at a rate given by R ∼ t{sup 0.4} consistent with a non-radiative spherical blast wave. This data also indicate the development of a toroidal structure in the lateral profile of both electron temperature and density. Rayleigh scattering data show that the gas density decreases in the center of the expanding plasma with a central scattering peak reemerging after about 12 μs. We have utilized a zero dimensional kinetic global model to identify the dominant particle species versus delay time and this indicates that metastable helium and the He{sub 2}{sup +} molecular ion play an important role.

  12. Investigating the dynamics of laser induced sparks in atmospheric helium using Rayleigh and Thomson scattering

    NASA Astrophysics Data System (ADS)

    Nedanovska, E.; Nersisyan, G.; Morgan, T. J.; Hüwel, L.; Murakami, T.; Lewis, C. L. S.; Riley, D.; Graham, W. G.

    2015-01-01

    We have used optical Rayleigh and Thomson scattering to investigate the expansion dynamics of laser induced plasma in atmospheric helium and to map its electron parameters both in time and space. The plasma is created using 9 ns duration, 140 mJ pulses from a Nd:YAG laser operating at 1064 nm, focused with a 10 cm focal length lens, and probed with 7 ns, 80 mJ, and 532 nm Nd:YAG laser pulses. Between 0.4 μs and 22.5 μs after breakdown, the electron density decreases from 3.3 × 1017 cm-3 to 9 × 1013 cm-3, while the temperature drops from 3.2 eV to 0.1 eV. Spatially resolved Thomson scattering data recorded up to 17.5 μs reveal that during this time the laser induced plasma expands at a rate given by R ˜ t0.4 consistent with a non-radiative spherical blast wave. This data also indicate the development of a toroidal structure in the lateral profile of both electron temperature and density. Rayleigh scattering data show that the gas density decreases in the center of the expanding plasma with a central scattering peak reemerging after about 12 μs. We have utilized a zero dimensional kinetic global model to identify the dominant particle species versus delay time and this indicates that metastable helium and the He2+ molecular ion play an important role.

  13. Production of organic compounds in plasmas: A comparison among electric sparks, laser-induced plasmas and UV light

    NASA Technical Reports Server (NTRS)

    Scattergood, T. W.; Mckay, C. P.; Borucki, W. J.; Giver, L. P.; Vanghyseghem, H.; Parris, J. E.; Miller, S. L.

    1991-01-01

    In order to study the production of organic compounds in plasmas (and shocks), various mixtures of N2, CH4, and H2, modeling the atmosphere of Titan, were exposed to discrete sparks, laser-induced plasmas (LIP) and ultraviolet light. The yields of HCN and simple hydrocarbons were measured and compared to those calculated from a simple quenched thermodynamic equilibrium model. The agreement between experiment and theory was fair for HCN and C2H2. However, the yields of C2H6 and other hydrocarbons were much higher than those predicted by the model. Our experiments suggest that photolysis by ultraviolet light from the plasma is an important process in the synthesis. This was confirmed by the photolysis of gas samples exposed to the light, but not to the plasma or shock waves. The results of these experiments demonstrate that, in addition to the well-known efficient synthesis of organic compounds in plasmas, the yields of saturated species, e.g., ethane, may be higher than predicted by theory and that LIP provide a convenient and clean way of simulating planetary lightning and impact plasmas in the laboratory.

  14. Diagnosis of caries by spectral analysis of laser-induced plasma sparks

    NASA Astrophysics Data System (ADS)

    Niemz, Markolf H.

    1994-12-01

    A picosecond Nd:YLF laser system was used to remove sound and carious enamel by the mechanism of plasma-induced ablation. The plasma spark was optically imaged onto the entrance pupil of a spectrometer. The spectra were scanned between 400 - 700 nm with a typical resolution of 0.2 nm. Calcium in neutral and singly ionized states and the sodium doublet at 589 nm were observed. The second harmonic of the laser wavelength was generated in an external BBO crystal, thereby converting about 10 (mu) J of the pulse energy to radiation at 527 nm. The amplitude of the diffuse reflected second harmonic was used as a reference signal for normalization of the spectra. Several sound and artificial caries regions of different teeth were investigated. The spectra obtained from caries always showed a strong decrease in amplitude of all mineral lines, if compared to sound enamel. These results can be explained by the demineralization process of dental decay. Thus, caries infected teeth are easily distinguished from sound probes, enabling a computer controlled caries removal in the near future. The possible setup of such an automated system is discussed.

  15. Direct solid analysis of powdered tungsten carbide hardmetal precursors by laser-induced argon spark ablation with inductively coupled plasma atomic emission spectrometry.

    PubMed

    Holá, Markéta; Kanický, Viktor; Mermet, Jean-Michel; Otruba, Vítezslav

    2003-12-01

    The potential of the laser-induced argon spark atomizer (LINA-Spark atomizer) coupled with ICP-AES as a convenient device for direct analysis of WC/Co powdered precursors of sintered hardmetals was studied. The samples were presented for the ablation as pressed pellets prepared by mixing with powdered silver binder containing GeO2 as internal standard. The pellets were ablated with the aid of a Q-switched Nd:YAG laser (1064 nm) focused 16 mm behind the target surface with a resulting estimated power density of 5 GW cm(-2). Laser ablation ICP-AES signals were studied as a function of ablation time, and the duration of time prior to measurement (pre-ablation time) which was necessary to obtain reliable results was about 40 s. Linear calibration plots were obtained up to 10% (m/m) Ti, 9% Ta and 3.5% Nb both without internal standardization and by using germanium as an added internal standard or tungsten as a contained internal standard. The relative uncertainty at the centroid of the calibration line was in the range from +/- 6% to +/- 11% for Nb, Ta and Ti both with and without internal standardisation by Ge. A higher spread of points about the regression was observed for cobalt for which the relative uncertainty at the centroid was in the range from +/- 9% to +/- 14%. Repeatability of results was improved by the use of both Ge and W internal standards. The lowest determinable quantities calculated for calibration plots were 0.060% Co, 0.010% Nb, 0.16% Ta and 0.030% Ti with internal standardization by Ge. The LA-ICP-AES analyses of real samples led to good agreement with the results obtained by solution-based ICP determination with a relative bias not exceeding 10%. The elimination of the dissolution procedure of powdered tungsten (Nb, Ta, Ti) carbide is the principal advantage of the developed LA-ICP-AES method. PMID:14564441

  16. On the study of threshold intensity dependence on the gain and loss processes in laser induced spark ignition of molecular hydrogen

    SciTech Connect

    Omar, M. M. Aboulfotouh, A. M.; Gamal, Y. E. E.

    2015-03-30

    In the present work, a numerical analysis is performed to investigate the comparative contribution of the mechanisms responsible for electron gain and losses in laser spark ignition and plasma formation of H{sub 2}. The analysis considered H{sub 2} over pressure range 150 -3000 torr irradiated by a Nd:YAG laser radiation at wavelengths 1064 and 532 nm with pulse length 5.5 ns. The study based on a modified electron cascade model by one of the authors which solves numerically the time dependent Boltzmann equation as well as a set of rate equations that describe the rate of change of the excited states population. The model includes most of the physical processes that might take place during the interaction. Computations of The threshold intensity are performed for the combined and separate contribution of each of the gain and loss processes. Reasonable agreement with the measured values over the tested pressure range is obtained only for the case of the combined contribution. Basing on the calculation of the electron energy distribution function, the determined relations of the time evolution of the electrons density for selected values of the tested gas pressure region revealed that photo-ionization of the excited states could determine the time of electron generation and hence spark ignition. Collisional ionization contributes to this phenomenon only at the high pressure regime. Loss processes due to electron diffusion, vibrational excitation are found to have significant effect over examined pressure values for the two applied laser wavelengths.

  17. Laser induced ignition

    NASA Astrophysics Data System (ADS)

    Liedl, G.; Schuöcker, D.; Geringer, B.; Graf, J.; Klawatsch, D.; Lenz, H. P.; Piock, W. F.; Jetzinger, M.; Kapus, P.

    2007-05-01

    Nowadays, combustion engines and other combustion processes play an overwhelming and important role in everyday life. As a result, ignition of combustion processes is of great importance, too. Usually, ignition of a combustible material is defined in such a way that an ignition initiates a self-sustained reaction which propagates through the inflammable material even in the case that the ignition source has been removed. In most cases, a well defined ignition location and ignition time is of crucial importance. Spark plugs are well suited for such tasks but suffer from some disadvantages, like erosion of electrodes or restricted positioning possibilities. In some cases, ignition of combustible materials by means of high power laser pulses could be beneficial. High power lasers offer several different possibilities to ignite combustible materials, like thermal ignition, resonant ignition or optical breakdown ignition. Since thermal and resonant ignitions are not well suited on the requirements mentioned previously, only optical breakdown ignition will be discussed further. Optical breakdown of a gas within the focal spot of a high power laser allows a very distinct localization of the ignition spot in a combustible material. Since pulse duration is usually in the range of several nanoseconds, requirements on the ignition time are fulfilled easily, too. Laser peak intensities required for such an optical breakdown are in the range of 10 11 W/cm2. The hot plasma which forms during this breakdown initiates the following self-propagating combustion process. It has been shown previously that laser ignition of direct injection engines improves the fuel consumption as well as the exhaust emissions of such engines significantly. The work presented here gives a brief overview on the basics of laser induced ignition. Flame propagation which follows a successful ignition event can be distinguished into two diffrent regimes. Combustion processes within an engine are usually

  18. Interaction of Laser Induced Micro-shockwaves

    NASA Astrophysics Data System (ADS)

    Leela, Ch.; Bagchi, Suman; Tewari, Surya P.; Kiran, P. Prem

    Laser induced Shock Waves (LISWs) characterized by several optical methods provide Equation of State (EOS) for a variety of materials used in high-energy density physics experiments at Mbar pressures [1, 2]. Other applications include laser spark ignition for fuel-air mixtures, internal combustion engines, pulse detonation engines, laser shock peening [3], surface cleaning [4] and biological applications (SW lithotripsy) [5] to name a few.

  19. Railgun system using a laser-induced plasma armature

    SciTech Connect

    Onozuka, M.; Oda, Y.; Azuma, K.

    1996-05-01

    Development of an electromagnetic railgun system that utilizes a laser-induced plasma armature formation has been conducted to investigate the application of the railgun system for high-speed pellet injection into fusion plasmas. Using the laser-induced plasma formation technique, the required breakdown voltage was reduced by one-tenth compared with that for the spark-discharged plasma. The railgun system successfully accelerated the laser-induced plasma armature by an electromagnetic force that accelerated the pellet. The highest velocity of the solid hydrogen pellets, obtained so far, was 2.6 km/sec using a 2m-long railgun. {copyright} {ital 1996 American Institute of Physics.}

  20. A Simple LIBS (Laser-Induced Breakdown Spectroscopy) Laboratory Experiment to Introduce Undergraduates to Calibration Functions and Atomic Spectroscopy

    ERIC Educational Resources Information Center

    Chinni, Rosemarie C.

    2012-01-01

    This laboratory experiment introduces students to a different type of atomic spectroscopy: laser-induced breakdown spectroscopy (LIBS). LIBS uses a laser-generated spark to excite the sample; once excited, the elemental emission is spectrally resolved and detected. The students use LIBS to analyze a series of standard synthetic silicate samples…

  1. Predictive spark timing method

    SciTech Connect

    Tang, D.L.; Chang, M.F.; Sultan, M.C.

    1990-01-09

    This patent describes a method of determining spark time in a spark timing system of an internal combustion engine having a plurality of cylinders and a spark period for each cylinder in which a spark occurs. It comprises: generating at least one crankshaft position reference pulse for each spark firing event, the reference pulse nearest the next spark being set to occur within a same cylinder event as the next spark; measuring at least two reference periods between recent reference pulses; calculating the spark timing synchronously with crankshaft position by performing the calculation upon receipt of the reference pulse nearest the next spark; predicting the engine speed for the next spark period from at least two reference periods including the most recent reference period; and based on the predicted speed, calculating a spark time measured from the the reference pulse nearest the next spark.

  2. Spatial and temporal dependence of interspark interactions in femtosecond-nanosecond dual-pulse laser-induced breakdown spectroscopy.

    PubMed

    Scaffidi, Jon; Pearman, William; Lawrence, Marion; Carter, J Chance; Colston, Bill W; Angel, S Michael

    2004-09-20

    A femtosecond air spark has recently been combined with a nanosecond ablative pulse in order to map the spatial and temporal interactions of the two plasmas in femtosecond-nanosecond orthogonal preablation spark dual-pulse laser-induced breakdown spectroscopy (LIBS). Good spatial and temporal correlation was found for reduced atomic emission from atmospheric species (nitrogen and oxygen) and increased atomic emission from ablated species (copper and aluminum) in the femtosecond-nanosecond plasma, suggesting a potential role for atmospheric pressure or nitrogen/oxygen concentration reduction following air spark formation in generating atomic emission enhancements in dual-pulse LIBS. PMID:15473246

  3. Spatial and Temporal Dependence of Interspark Interactions in Femtosecond-Nanosecond Dual-Pulse Laser-Induced Breakdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    Scaffidi, Jon; Pearman, William; Lawrence, Marion; Chance Carter, J.; Colston, Bill W., Jr.; Angel, S. Michael

    2004-09-01

    A femtosecond air spark has recently been combined with a nanosecond ablative pulse in order to map the spatial and temporal interactions of the two plasmas in femtosecond-nanosecond orthogonal preablation spark dual-pulse laser-induced breakdown spectroscopy (LIBS). Good spatial and temporal correlation was found for reduced atomic emission from atmospheric species (nitrogen and oxygen) and increased atomic emission from ablated species (copper and aluminum) in the femtosecond-nanosecond plasma, suggesting a potential role for atmospheric pressure or nitrogen/oxygen concentration reduction following air spark formation in generating atomic emission enhancements in dual-pulse LIBS.

  4. Laser spark distribution and ignition system

    DOEpatents

    Woodruff, Steven; McIntyre, Dustin L.

    2008-09-02

    A laser spark distribution and ignition system that reduces the high power optical requirements for use in a laser ignition and distribution system allowing for the use of optical fibers for delivering the low peak energy pumping pulses to a laser amplifier or laser oscillator. An optical distributor distributes and delivers optical pumping energy from an optical pumping source to multiple combustion chambers incorporating laser oscillators or laser amplifiers for inducing a laser spark within a combustion chamber. The optical distributor preferably includes a single rotating mirror or lens which deflects the optical pumping energy from the axis of rotation and into a plurality of distinct optical fibers each connected to a respective laser media or amplifier coupled to an associated combustion chamber. The laser spark generators preferably produce a high peak power laser spark, from a single low power pulse. The laser spark distribution and ignition system has application in natural gas fueled reciprocating engines, turbine combustors, explosives and laser induced breakdown spectroscopy diagnostic sensors.

  5. Laser-induced breakdown spectroscopy expands into industrial applications

    NASA Astrophysics Data System (ADS)

    Noll, Reinhard; Fricke-Begemann, Cord; Brunk, Markus; Connemann, Sven; Meinhardt, Christoph; Scharun, Michael; Sturm, Volker; Makowe, Joachim; Gehlen, Christoph

    This paper presents R&D activities in the field of laser-induced breakdown spectroscopy for industrial applications and shows novel LIBS systems running in routine operation for inline process control tasks. Starting with a comparison of the typical characteristics of LIBS with XRF and spark-discharge optical emission spectrometry, the principal structure of LIBS machines embedded for inline process monitoring will be presented. A systematic requirement analysis for LIBS systems following Ishikawa's scheme was worked out. Stability issues are studied for laser sources and Paschen-Runge spectrometers as key components for industrial LIBS systems. Examples of industrial applications range from handheld LIBS systems using a fiber laser source, via a set of LIBS machines for inline process control tasks, such as scrap analysis, coal analysis, liquid slag analysis and finally monitoring of drill dust.

  6. Picosecond laser-induced water condensation in a cloud chamber.

    PubMed

    Sun, Haiyi; Liu, Yonghong; Ju, Jingjing; Tian, Ye; Bai, Yafeng; Liu, Yaoxiang; Du, Shengzhe; Wang, Cheng; Wang, Tiejun; Liu, Jiansheng; Chin, See Leang; Li, Ruxin; Xu, Zhizhan

    2016-09-01

    We investigated water condensation in a laboratory cloud chamber induced by picosecond (ps) laser pulses at ~350 ps (800 nm/1-1000 Hz) with a maximum peak power of ~25 MW. The peak power was much lower than the critical power for self-focusing in air (~3-10 GW depending on the pulse duration). Sparks, airflow and snow formation were observed under different laser energies or repetition rates. It was found that weaker ps laser pulses can also induce water condensation by exploding and breaking down ice crystals and/or water droplets into tiny particles although there was no formation of laser filament. These tiny particles would grow until precipitation in a super-saturation zone due to laser-induced airflow in a cold region with a large temperature gradient. PMID:27607654

  7. Spark ultrasonic transducer

    NASA Technical Reports Server (NTRS)

    Hoop, J. M.

    1972-01-01

    Nondestructive testing by spark transducer induces ultrasonic pulses in materials without physical contact. High power pulse generator connected to step up transformer produces sparking between two tungsten rods and ultrasonic energy pulses in test samples placed between rods.

  8. Rotating arc spark plug

    DOEpatents

    Whealton, John H.; Tsai, Chin-Chi

    2003-05-27

    A spark plug device includes a structure for modification of an arc, the modification including arc rotation. The spark plug can be used in a combustion engine to reduce emissions and/or improve fuel economy. A method for operating a spark plug and a combustion engine having the spark plug device includes the step of modifying an arc, the modifying including rotating the arc.

  9. A Fundamental Study of Laser-Induced Breakdown Spectroscopy Using Fiber Optics for Remote Measurements Of Trace Metals

    SciTech Connect

    Scott Goode; S. Michael Angel

    2004-01-20

    Develop a fiber-optic imaging probe for microanalysis of solid samples; Design a time-resolved plasma imaging system to measure the development of the LIBS signal; Setup a laboratory system capable of timing two lasers independently, for optimizing and characterizing dual-pulse LIBS; Compare the development of laser-induced plasmas generated with a single laser pulse to the development of laser-induced plasmas generated with a pre-ablation spark prior to sample ablation; Examine the effect of sample matrix on the LIBS signals of elements in different sample matrices; Investigate the effect of excitation wavelength of the ablation beam in pre-ablation spark dual-pulse LIBS experiments; Determine the effect of the physical properties of the sample on the mass of materials ablated.

  10. Laser-induced fluorescence of formaldehyde in combustion using third harmonic Nd:YAG laser excitation.

    PubMed

    Brackmann, Christian; Nygren, Jenny; Bai, Xiao; Li, Zhongshan; Bladh, Henrik; Axelsson, Boman; Denbratt, Ingemar; Koopmans, Lucien; Bengtsson, Per-Erik; Aldén, Marcus

    2003-12-01

    Formaldehyde (CH2O) is an important intermediate species in combustion processes and it can through laser-induced fluorescence measurements be used for instantaneous flame front detection. The present study has focussed on the use of the third harmonic of a Nd:YAG laser at 355 nm as excitation wavelength for formaldehyde, and different dimethyl ether (C2H6O) flames were used as sources of formaldehyde in the experiments. The investigations included studies of the overlap between the laser profile and the absorption lines of formaldehyde, saturation effects and the potential occurrence of laser-induced photochemistry. The technique was applied for detection of formaldehyde in an internal combustion engine operated both as a spark ignition engine and as a homogenous charge compression ignition engine. PMID:14607232

  11. Laser-Induced Thermal Acoustics

    NASA Astrophysics Data System (ADS)

    Cummings, Eric Bryant

    1995-01-01

    Laser-induced thermal acoustics (LITA) is a new technique for remote nonintrusive measurement of thermophysical gas properties. LITA involves forming, via opto-acoustic effects, grating-shaped perturbations of gas properties by the use of intersecting beams from a short-pulse laser. A third beam scatters coherently into a signal beam off the perturbation grating via acousto-optical effects. The evolution of the gas perturbations modulates the scattered signal beam. Accurate values of the sound speed, transport properties, and composition of the gas can be extracted by analyzing the signal beam. An analytical expression for the spectrum, absolute magnitude, and time history of the LITA signal is derived. The optoacoustic effects of thermalization and electrostriction are treated. Finite beam-diameter, beam-duration, and thermalization-rate effects are included in the analysis. The expression accurately models experimental signals over a wide range of gas conditions. Experimental tests using LITA have been conducted on pure and NO_2-seeded air and helium at pressures ranging from {~ }0.1 kPa-14 MPa. Carbon dioxide has been explored near its liquid-vapor critical point. Accuracies of 0.1% in sound speed measurements have been achieved in these tests. Accuracies of {~}1% have been achieved in measurements of thermal diffusivity, although beam misalignment effects have typically degraded this accuracy by a factor of {~} 10-20. Using LITA, susceptibility spectra have been taken of approximately a femtogram of NO_2 . The effects of fluid motion and turbulence have been explored. LITA velocimetry has been demonstrated, in which the Doppler shift of light scattered from a flowing fluid is measured. LITA velocimetry requires no particle seeding, has a coherent signal beam, and can be applied to pulsed flows. LITA has also been applied to measure single-shot |chi^{(1) }|^2 or "Rayleigh scattering" spectra of a gas by the use of a technique of wavelength -division multiplexing

  12. Laser-induced thermal acoustics

    NASA Astrophysics Data System (ADS)

    Cummings, Eric B.

    Laser-induced thermal acoustics (LITA) is a new technique for remote nonintrusive measurement of thermophysical gas properties. LITA involves forming, via opto-acoustic effects, grating-shaped perturbations of gas properties using intersecting beams from a short-pulse laser. A third beam scatters coherently into a signal beam off the perturbation grating via acousto-optical effects. The evolution of the gas perturbations modulates the scattered signal beam. Accurate values of the sound speed, transport properties, and composition of the gas can be extracted by analyzing the signal beam.An analytical expression for the spectrum, absolute magnitude, and time history of the LITA signal is derived. The optoacoustic effects of thermalization and electrostriction are treated. Finite beam-diameter, beam-duration, and thermalization-rate effects are included in the analysis. The expression accurately models experimental signals over a wide range of gas conditions.Experimental tests using LITA have been conducted on pure and [...]-seeded air and helium at pressures ranging from ~0.1 kPa-14 MPa. Carbon dioxide has been explored near its liquid-vapor critical point. Accuracies of 0.1% in sound speed measurements have been achieved in these tests. Accuracies of ~1% have been achieved in measurements of thermal diffusivity, although beam misalignment effects have typically degraded this accuracy by a factor of ~10-20. Using LITA, susceptibility spectra have been taken of approximately a femtogram of [...]. The effects of fluid motion and turbulence have been explored. LITA velocimetry has been demonstrated, in which the Doppler shift of light scattered from a flowing fluid is measured. LITA velocimetry requires no particle seeding, has a coherent signal beam, and can be applied to pulsed flows. LITA has also been applied to measure single-shot [...] or "Rayleigh scattering" spectra of a gas using a technique of wavelength-division multiplexing, called multiplex LITA. The LITA

  13. Laser-induced caesium-137 decay

    SciTech Connect

    Barmina, E V; Simakin, A V; Shafeev, G A

    2014-08-31

    Experimental data are presented on the laser-induced beta decay of caesium-137. We demonstrate that the exposure of a gold target to a copper vapour laser beam (wavelengths of 510.6 and 578.2 nm, pulse duration of 15 ns) for 2 h in an aqueous solution of a caesium-137 salt reduces the caesium-137 activity by 70%, as assessed from the gamma activity of the daughter nucleus {sup 137m}Ba, and discuss potential applications of laser-induced caesium-137 decay in radioactive waste disposal. (letters)

  14. Mestastable State Population in Laser Induced Plasmas

    NASA Technical Reports Server (NTRS)

    Kwong, V. H. S.; Kyriakides, C.; Ward, W. K.

    2006-01-01

    Laser induced plasma has been used as a source of neutrals and ions in the study of astrophysical plasmas. The purity of state of this source is essential in the determination of collision parameters such as the charge transfer rate coefficients between ions and neutrals. We will show that the temperature of the laser induced plasma is a rapidly decreasing function of time. The temperature is initially high but cools off rapidly through collisions with the expanding plasma electrons as the plasma recombines and streams into the vacuum. This rapid expansion of the plasma, similar to a supersonic jet, drastically lowers the internal energy of the neutrals and ions.

  15. Characterization of the Delamination Defects in Marine Steel Using Laser-Induced Breakdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    Yang, Chun; Jia, Yunhai; Zhang, Yong; Li, Dongling; Liu, Jia; Chen, Jiwen; Chen, Yongyan; Liu, Ying

    2015-08-01

    In this paper, two types of comparison analyses, bulk analysis and defect analysis, were carried out for marine steel. The results of laser-induced breakdown spectroscopy (LIBS) were compared with those of spark optical emission spectrometry (Spark-OES) and scanning electron microscopy/energy dispersion spectroscopy (SEM/EDS) in the bulk and defect analyses. The comparison of the bulk analyses shows that the chemical contents of C, Si, Mn, P, S and Cr obtained from LIBS agree well with those determined using Spark-OES. The LIBS is slightly less precise than Spark-OES. Defects were characterized in the two-dimensional distribution analysis mode for Al, Mg, Ca, Si and other elements. Both the LIBS and SEM/EDS results show the enrichment of Al, Mg, Ca and Si at the defect position and the two methods agree well with each other. SEM/EDS cannot provide information about the difference in the chemical constituents when the differences between the defect position and the normal position are not significant. However, LIBS can provide this information, meaning that the sensitivity of LIBS is higher than that of SEM/EDS. LIBS can be used to rapidly characterize marine steel defects and provide guidance for improving metallurgical processes. supported by a Special Fund for Nationally Important Instruments of China (No. 2012YQ20018208)

  16. The sparking voltage of spark plugs

    NASA Technical Reports Server (NTRS)

    Silsbee, F B

    1925-01-01

    This report has been prepared in order to collect and correlate into convenient and useful form the available data on this subject. The importance of the subject lies in the fact that it forms the common meeting ground for studies of the performance of spark generators and spark plugs on the one hand and of the internal combustion engines on the other hand. While much of the data presented was obtained from various earlier publications, numerous places were found where necessary data were lacking, and these have been provided by experiments in gasoline engines at the Bureau of Standards.

  17. Laser-Induced Ignition Modeling and Comparison with Experiments

    NASA Astrophysics Data System (ADS)

    Dors, Ivan; Qin, W.; Chen, Y.-L.; Parigger, C.; Lewis, J. W. L.

    2000-11-01

    We have studied experimentally the ignition resulting from optical breakdowns in mixtures of oxygen and the fuel ammonia induced by a 10 nanosecond pulsewidth laser for a time of hundreds of milliseconds using laser spectroscopy. In these studies, we have for the first time characterized the laser-induced plasma, the formation of the combustion radicals, the detonation wave, the flame front and the combustion process itself. The objective of the modeling is to understand the fluid dynamic and chemical kinetic effects following the nominal 10 ns laser pulse until 1 millisecond after laser breakdown. The calculated images match the experimentally recorded data sets and show spatial details covering volumes of 1/10000 cc to 1000 cc. The code was provided by CFD Research Corporation of Huntsville, Alabama, and was appropriately augmented to compute the observed phenomena. The fully developed computational model now includes a kinetic mechanism that implements plasma equilibrium kinetics in ionized regions, and non-equilibrium, multistep, finite rate reactions in non-ionized regions. The predicted fluid phenomena agree with various flow patterns characteristic of laser spark ignition as measured in the CLA laboratories. Comparison of calculated and measured OH and NH concentration will be presented.

  18. Study Of Laser-Induced Copolymerization

    NASA Technical Reports Server (NTRS)

    Miner, Gilda A.; Meador, Willard E.; Chang, C. Ken

    1993-01-01

    Report describes experiments on photopolymerization of styrene/maleic anhydride copolymer published as part of Laser Polymerization Program at NASA Langley Research Center. Presents basic study of copolymerization of styrene and maleic anhydride under laser-induced initiation and polymerization. Helps to clarify different theories on such initiation and represents significant advances in understanding of basic processes.

  19. Nitrogen spark denoxer

    DOEpatents

    Ng, Henry K.; Novick, Vincent J.; Sekar, Ramanujam R.

    1997-01-01

    A NO.sub.X control system for an internal combustion engine includes an oxygen enrichment device that produces oxygen and nitrogen enriched air. The nitrogen enriched air contains molecular nitrogen that is provided to a spark plug that is mounted in an exhaust outlet of an internal combustion engine. As the nitrogen enriched air is expelled at the spark gap of the spark plug, the nitrogen enriched air is exposed to a pulsating spark that is generated across the spark gap of the spark plug. The spark gap is elongated so that a sufficient amount of atomic nitrogen is produced and is injected into the exhaust of the internal combustion engine. The injection of the atomic nitrogen into the exhaust of the internal combustion engine causes the oxides of nitrogen to be reduced into nitrogen and oxygen such that the emissions from the engine will have acceptable levels of NO.sub.X. The oxygen enrichment device that produces both the oxygen and nitrogen enriched air can include a selectively permeable membrane.

  20. SPARK GAP SWITCH

    DOEpatents

    Neal, R.B.

    1957-12-17

    An improved triggered spark gap switch is described, capable of precisely controllable firing time while switching very large amounts of power. The invention in general comprises three electrodes adjustably spaced and adapted to have a large potential impressed between the outer electrodes. The central electrode includes two separate elements electrically connected togetaer and spaced apart to define a pair of spark gaps between the end electrodes. Means are provided to cause the gas flow in the switch to pass towards the central electrode, through a passage in each separate element, and out an exit disposed between the two separate central electrode elements in order to withdraw ions from the spark gap.

  1. SparkJet Efficiency

    NASA Technical Reports Server (NTRS)

    Golbabaei-Asl, Mona; Knight, Doyle; Anderson, Kellie; Wilkinson, Stephen

    2013-01-01

    A novel method for determining the thermal efficiency of the SparkJet is proposed. A SparkJet is attached to the end of a pendulum. The motion of the pendulum subsequent to a single spark discharge is measured using a laser displacement sensor. The measured displacement vs time is compared with the predictions of a theoretical perfect gas model to estimate the fraction of the spark discharge energy which results in heating the gas (i.e., increasing the translational-rotational temperature). The results from multiple runs for different capacitances of c = 3, 5, 10, 20, and 40 micro-F show that the thermal efficiency decreases with higher capacitive discharges.

  2. Elemental analysis of metals under water using laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Pichahchy, A. E.; Cremers, D. A.; Ferris, M. J.

    1997-01-01

    Laser-induced breakdown spectroscopy (LIBS) has been evaluated for the detection of metals located under water. Repetitive laser sparks were formed on the metals by focused pulses from a Q-switched Nd:YAG laser (1064 nm). Using repetitive single sparks (RSS) at 10 Hz, only weak elemental emission signals were generated from even strongly emitting species at high concentrations (e.g. Al(I) from commercially pure aluminum). The spectrum in these cases was dominated by spectrally broad emissions (continuum radiation) from the plume ( T < 3000 K). The use of a repetitive spark pair (RSP), however, produced a plasma ( T ˜ 8,880 K) on the second pulse useful to monitor the elemental composition of the metals. In the RSP, a pair of pulses was focused on the metals at 10 Hz with the separation between pulses adjusted from 30 to 180 μs. The pulse pair was generated from a single laser. Only a weak dependence of the emission intensities on the separation between the pulses of the spark pair was observed although signal enhancements over two orders of magnitude were obtained compared to the RSS. Using the RSP, detection limits of 367, 520, 1200, and 1190 ppm were obtained for Cr, Cu, Mn, and Si in steel. Using time-resolved imaging of the laser plumes/plasmas formed on the metal samples under water, some characteristics of the excitation process were evaluated. It was determined that the first pulse of the RSP forms a large bubble or vapor cavity (maximum diameter ˜ 8 mm) on the metal surface which is then interrogated by the second pulse. The second pulse then forms a plasma resulting in excitation similar to that produced by a single laser spark formed on metal in air.

  3. Spectroscopy During Laser Induced Shock Wave Lithotripsy

    NASA Astrophysics Data System (ADS)

    Engelhardt, R.; Meyer, W.; Hering, P.

    1988-06-01

    In the course of laser induced shock wave lithotripsy (LISL) by means of a flashlamp pumped dye laser a plasma is formed on the stone's surface. Spectral analysis of the plasma flash leads to chemical stone analysis during the procedure. A time resolved integral analysis of scattered and laser induced fluorescence light makes stone detection possible and avoids tissue damage. We used a 200 μm fiber to transmit a 2 μs, 50 mJ pulse to the stone's surface and a second 200 μ fiber for analysis. This transmission system is small and flexible enough for controlled endoscopic use in the treatment of human ureter or common bile duct stones. Under these conditions the stone selective effect of lasertripsy leads only to minor tissue injury.

  4. Laser Induced Aluminum Surface Breakdown Model

    NASA Technical Reports Server (NTRS)

    Chen, Yen-Sen; Liu, Jiwen; Zhang, Sijun; Wnag, Ten-See (Technical Monitor)

    2001-01-01

    Laser powered propulsion systems involve complex fluid dynamics, thermodynamics and radiative transfer processes. Based on an unstructured grid., pressure-based computational aerothermodynamics, platform, several sub-nio"'dels describing such underlying physics as laser ray tracing and focusing, thermal non-equilibrium, plasma radiation and air spark ignition have been developed. This proposed work shall extend the numerical platform and existing sub-models to include the aluminum wall surface Inverse Bremsstrahlung (113) effect from which surface ablation and free-electron generation can be initiated without relying on the air spark ignition sub-model. The following tasks will be performed to accomplish the research objectives.

  5. Laser Induced Aluminum Surface Breakdown Model

    NASA Technical Reports Server (NTRS)

    Chen, Yen-Sen; Liu, Jiwen; Zhang, Sijun; Wang, Ten-See (Technical Monitor)

    2002-01-01

    Laser powered propulsion systems involve complex fluid dynamics, thermodynamics and radiative transfer processes. Based on an unstructured grid, pressure-based computational aerothermodynamics; platform, several sub-models describing such underlying physics as laser ray tracing and focusing, thermal non-equilibrium, plasma radiation and air spark ignition have been developed. This proposed work shall extend the numerical platform and existing sub-models to include the aluminum wall surface Inverse Bremsstrahlung (IB) effect from which surface ablation and free-electron generation can be initiated without relying on the air spark ignition sub-model. The following tasks will be performed to accomplish the research objectives.

  6. Mars Spark Source Prototype

    NASA Technical Reports Server (NTRS)

    Eichenberg, Dennis J.; Lindamood, Glenn R.; Weiland, Karen J.; VanderWal, Randall L.

    1999-01-01

    The Mars Spark Source Prototype (MSSP) hardware has been developed as part of a proof of concept system for the detection of trace metals such as lead, cadmium, and arsenic in Martian dusts and soils. A spark discharge produces plasma from a soil sample and detectors measure the optical emission from metals in the plasma that will allow their identification and quantification. Trace metal measurements are vital for the assessment of the potential toxicity of the Martian environment for human exploration. The current method of X-ray fluorescence can yield concentrations only of major species. Other instruments are incompatible with the volume, weight, and power constraints for a Mars mission. The instrument will be developed primarily for use in the Martian environment, but would be adaptable for terrestrial use in environmental monitoring. This paper describes the Mars Spark Source Prototype hardware, the results of the characterization tests, and future plans for hardware development.

  7. MULTIPLE SPARK GAP SWITCH

    DOEpatents

    Schofield, A.E.

    1958-07-22

    A multiple spark gap switch of unique construction is described which will permit controlled, simultaneous discharge of several capacitors into a load. The switch construction includes a disc electrode with a plurality of protuberances of generally convex shape on one surface. A firing electrode is insulatingly supponted In each of the electrode protuberances and extends substantially to the apex thereof. Individual electrodes are disposed on an insulating plate parallel with the disc electrode to form a number of spark gaps with the protuberances. These electrodes are each connected to a separate charged capacitor and when a voltage ls applied simultaneously between the trigger electrodes and the dlsc electrode, each spark gap fires to connect its capacitor to the disc electrode and a subsequent load.

  8. Spark gap electrode erosion

    NASA Astrophysics Data System (ADS)

    Krompholz, H.; Kristiansen, M.

    1984-12-01

    The results of a one-year contract on electrode erosion phenomena are summarized. The arc voltage drop in a spark gap was measured for various electrode, gas, and pressure combinations. A previously developed model of self breakdown voltage distribution was extended. A jet model for electrode erosion was proposed and an experimental arrangement for testing the model was constructed. The effects of inhomogeneities and impurities in the electrodes were investigated. Some of the work described here is scheduled for completion in 1985 under a current grant (AFOSR 84-0032). The areas of investigation described here include: (1) Self breakdown voltage distributions; (2) Electrode erosion; (3) Spark gap voltage recovery.

  9. Laser induced surface stress on water droplets.

    PubMed

    Wang, Neng; Lin, Zhifang; Ng, Jack

    2014-10-01

    Laser induced stress on spherical water droplets is studied. At mechanical equilibrium, the body stress vanishes therefore we consider only the surface stress. The surface stress on sub-wavelength droplets is slightly weaker along the light propagation direction. For larger droplets, due to their light focusing effect, the forward stress is significantly enhanced. For a particle roughly 3 micron in radius, when it is excited at whispering gallery mode with Q ∼ 10⁴ by a 1 Watt Gaussian beam, the stress can be enhanced by two orders of magnitude, and can be comparable with the Laplace pressure. PMID:25321955

  10. Kinetic Approach for Laser-Induced Plasmas

    SciTech Connect

    Omar, Banaz; Rethfeld, Baerbel

    2008-10-22

    Non-equilibrium distribution functions of electron gas and phonon gas excited with ultrashort intense laser pulses are calculated for laser-induced plasmas occurring in solids. The excitation during femtosecond irradiation and the subsequent thermalization of the free electrons, as well as the dynamics of phonons are described by kinetic equations. The microscopic collision processes, such as absorption by inverse bremsstrahlung, electron-electron collisions, and electron-phonon interactions are considered by complete Boltzmann collision integrals. We apply our kinetic approach for gold by taking s-band electron into account and compare it with the case of excitation of d-band electrons.

  11. Laser-induced electric breakdown in solids

    NASA Technical Reports Server (NTRS)

    Bloembergen, N.

    1974-01-01

    A review is given of recent experimental results on laser-induced electric breakdown in transparent optical solid materials. A fundamental breakdown threshold exists characteristic for each material. The threshold is determined by the same physical process as dc breakdown, namely, avalanche ionization. The dependence of the threshold on laser pulse duration and frequency is consistent with this process. The implication of this breakdown mechanism for laser bulk and surface damage to optical components is discussed. It also determines physical properties of self-focused filaments.

  12. Modeling of Laser-Induced Metal Combustion

    SciTech Connect

    Boley, C D; Rubenchik, A M

    2008-02-20

    Experiments involving the interaction of a high-power laser beam with metal targets demonstrate that combustion plays an important role. This process depends on reactions within an oxide layer, together with oxygenation and removal of this layer by the wind. We present an analytical model of laser-induced combustion. The model predicts the threshold for initiation of combustion, the growth of the combustion layer with time, and the threshold for self-supported combustion. Solutions are compared with detailed numerical modeling as benchmarked by laboratory experiments.

  13. Laser Induced Chemical Liquid Phase Deposition (LCLD)

    SciTech Connect

    Nanai, Laszlo; Balint, Agneta M.

    2012-08-17

    Laser induced chemical deposition (LCLD) of metals onto different substrates attracts growing attention during the last decade. Deposition of metals onto the surface of dielectrics and semiconductors with help of laser beam allows the creation of conducting metal of very complex architecture even in 3D. In the processes examined the deposition occurs from solutions containing metal ions and reducing agents. The deposition happens in the region of surface irradiated by laser beam (micro reactors). Physics -chemical reactions driven by laser beam will be discussed for different metal-substrate systems. The electrical, optical, mechanical properties of created interfaces will be demonstrated also including some practical-industrial applications.

  14. Fostering the Curiosity Spark

    ERIC Educational Resources Information Center

    Crow, Sherry R.

    2010-01-01

    Many of the children in the early grades who marveled at the plethora of beautiful resources just did not seem that interested by the time they reached upper elementary school. While some children sustained their spark of curiosity, others did not. The force that keeps children (or people of any age) excited about anything is called "intrinsic…

  15. Confocal Laser Induced Fluorescence of Argon Plasmas

    NASA Astrophysics Data System (ADS)

    Scime, Earl; Soderholm, Mark

    2015-11-01

    Laser Induced Fluorescence (LIF) provides measurements of flow speed, temperature and when absolutely calibrated, density of ions or neutrals in a plasma. Traditionally, laser induced fluorescence requires two ports on a plasma device. One port is used for laser injection and the other is used for fluorescence emission collection. Traditional LIF is tedious and time consuming to align. These difficulties motivate the development of an optical configuration that requires a single port and remains fully aligned at all times; confocal LIF. Our confocal optical design employs a single two inch diameter lens to both inject the laser light and collect the stimulated emission from an argon plasma. A pair of axicon lenses create an annular beam path for the emission collection and the pump laser light is confined inside the annulus of the collection beam. The measurement location is scanned radially by manually adjusting the final focusing lens position. Here we present optical modeling of and initial results from the axicon based confocal optical system. The confocal measurements are compared to traditional, two-port, LIF measurements over the same radial range. This work is supported by US National Science Foundation grant number PHY-1360278.

  16. Characterization of alumina-based ceramic nanocomposites by laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Ahmad, Kaleem; Al-Eshaikh, Mohammad A.; Kadachi, Ahmed N.

    2015-06-01

    Alumina-based hybrids containing different concentrations of carbon nanostructure and SiC nanoparticles were consolidated by the spark plasma sintering in order to obtain fully dense bulk ceramic nanocomposites. Laser-induced breakdown spectroscopy was employed to determine relationship between plasma temperature and surface hardness of the composites. The characteristic parameters of plasma generated by irradiation of laser Nd:YAG ( λ = 1064 nm) on different bulk nanocomposites were determined at different delay times and energies by assuming the LTE condition for optically thin plasma. The plasma temperatures were estimated through intensity of selected aluminum emission lines using the Boltzmann plot method. The electron density was determined using the Stark broadening of selected aluminum and silicon emission lines. The samples were mechanically characterized by the Vickers hardness test. It has been observed that the plasma temperature increases with the increase in hardness and shows a perfect linear relationship. The results suggest that calibration curve between hardness and the plasma temperature can be employed as an alternate method to estimate the hardness of nanocomposite with varying concentrations of nanostructures just by measuring the plasma temperature with better reproducibility and accuracy. Therefore, laser-induced break down spectroscopy (LIBS) offers potential applications in nuclear industry.

  17. Observations in collinear femtosecond-nanosecond dual-pulse laser-induced breakdown spectroscopy.

    PubMed

    Scaffidi, J; Pearman, W; Carter, J C; Angel, S M

    2006-01-01

    In the work reported herein, we have combined a short-lived femtosecond laser-induced plasma (LIP) and a longer-lived nanosecond LIP in a collinear pulse configuration to examine the source(s) of atomic emission and signal-to-noise enhancement in dual-pulse laser-induced breakdown spectroscopy (LIBS). Initial studies indicate that the primary source of dual-pulse LIBS enhancement in the collinear configuration may in large part be a matter of pulse focus; focusing on the sample surface, for example, yields atomic emission enhancements whose lifetime correlates reasonably well with the femtosecond LIP emissive lifetime, suggesting that plasma-plasma coupling may play an important role at that pulse focus. At a second "optimal" focal position above the sample surface, alternatively, atomic emission and signal-to-noise enhancements correlate quite well with the nitrogen and oxygen atomic emission reductions previously seen following use of a femtosecond air spark and a nanosecond ablative pulse in the orthogonal dual-pulse configuration, suggesting that pressure or number density reductions due to femtosecond LIP formation in air may be significant at that pulse focus. PMID:16454914

  18. Laser-induced breakdown spectroscopy for in-cylinder equivalence ratio measurements in laser-ignited natural gas engines.

    PubMed

    Joshi, Sachin; Olsen, Daniel B; Dumitrescu, Cosmin; Puzinauskas, Paulius V; Yalin, Azer P

    2009-05-01

    In this contribution we present the first demonstration of simultaneous use of laser sparks for engine ignition and laser-induced breakdown spectroscopy (LIBS) measurements of in-cylinder equivalence ratios. A 1064 nm neodynium yttrium aluminum garnet (Nd:YAG) laser beam is used with an optical spark plug to ignite a single cylinder natural gas engine. The optical emission from the combustion initiating laser spark is collected through the optical spark plug and cycle-by-cycle spectra are analyzed for H(alpha)(656 nm), O(777 nm), and N(742 nm, 744 nm, and 746 nm) neutral atomic lines. The line area ratios of H(alpha)/O(777), H(alpha)/N(746), and H(alpha)/N(tot) (where N(tot) is the sum of areas of the aforementioned N lines) are correlated with equivalence ratios measured by a wide band universal exhaust gas oxygen (UEGO) sensor. Experiments are performed for input laser energy levels of 21 mJ and 26 mJ, compression ratios of 9 and 11, and equivalence ratios between 0.6 and 0.95. The results show a linear correlation (R(2) > 0.99) of line intensity ratio with equivalence ratio, thereby suggesting an engine diagnostic method for cylinder resolved equivalence ratio measurements. PMID:19470212

  19. Digital optical spark chambers

    NASA Technical Reports Server (NTRS)

    Evenson, Paul; Tuska, Evelyn

    1989-01-01

    The authors constructed and tested a prototype digital readout system for optical spark chambers using a linear, solid-state charge-coupled-device detector array. Position resolution of 0.013 mm (sigma) over a 25-cm field of view has been demonstrated. It is concluded that this technique should permit the construction of economical, lightweight and low-power trajectory hodoscopes for use in cosmic-ray instrumentation on balloons and in spacecraft.

  20. Laser-induced fluorescence imaging of bacteria

    NASA Astrophysics Data System (ADS)

    Hilton, Peter J.

    1998-12-01

    This paper outlines a method for optically detecting bacteria on various backgrounds, such as meat, by imaging their laser induced auto-fluorescence response. This method can potentially operate in real-time, which is many times faster than current bacterial detection methods, which require culturing of bacterial samples. This paper describes the imaging technique employed whereby a laser spot is scanned across an object while capturing, filtering, and digitizing the returned light. Preliminary results of the bacterial auto-fluorescence are reported and plans for future research are discussed. The results to date are encouraging with six of the eight bacterial strains investigated exhibiting auto-fluorescence when excited at 488 nm. Discrimination of these bacterial strains against red meat is shown and techniques for reducing background fluorescence discussed.

  1. CW CO2 Laser Induced Chemical Reactions

    NASA Astrophysics Data System (ADS)

    Pola, Joseph

    1989-05-01

    CW CO2 laser driven reactions between sulfur hexafluoride and carbon oxide, carbon suboxide, carbonyl sulfide and carbon disulfide proceed at subatmospheric pressures and yield fluorinated carbon compounds and sulfur tetrafluoride. CW CO2 laser driven reactions of organic compounds in the presence of energy-conveying sulfur hexafluoride show reaction course different from that normally observed due to elimination of reactor hot surface effects. The examples concern the decomposition of polychlorohydrocarbons, 2-nitropropane, tert.-butylamine, allyl chloride, spirohexane, isobornyl acetate and the oxidation of haloolefins. CW CO2 laser induced fragmentation of 1-methyl-l-silacyclobutanes and 4-silaspiro(3.4)octane in the presence of sulfur hexafluoride is an effective way for preparation and deposition of stable organosilicon polymers.

  2. Laser induced fluorescence of dental caries

    NASA Technical Reports Server (NTRS)

    Albin, S.; Byvik, C. E.; Buoncristiani, A. M.

    1988-01-01

    Significant differences between the optical spectra taken from sound regions of teeth and carious regions have been observed. These differences appear both in absorption and in laser induced fluorescence spectra. Excitation by the 488 nm line of an argon ion laser beam showed a peak in the emission intensity around 553 nm for the sound dental material while the emission peak from the carious region was red-shifted by approximately 40 nm. The relative absorption of carious region was significantly higher at 488 nm; however its fluorescence intensity peak was lower by an order of magnitude compared to the sound tooth. Implications of these results for a safe, reliable and early detection of dental caries are discussed.

  3. Laser-Induced Spallation of Microsphere Monolayers.

    PubMed

    Hiraiwa, Morgan; Stossel, Melicent; Khanolkar, Amey; Wang, Junlan; Boechler, Nicholas

    2016-08-01

    The detachment of a semiordered monolayer of polystyrene microspheres adhered to an aluminum-coated glass substrate is studied using a laser-induced spallation technique. The microsphere-substrate adhesion force is estimated from substrate surface displacement measurements obtained using optical interferometry, and a rigid-body model that accounts for the inertia of the microspheres. The estimated adhesion force is compared with estimates obtained using an adhesive contact model together with interferometric measurements of the out-of-plane microsphere contact resonance, and with estimated work of adhesion values for the polystyrene-aluminum interface. Scanning electron microscope images of detached monolayer regions reveal a unique morphology, namely, partially detached monolayer flakes composed of single hexagonal close packed crystalline domains. This work contributes to the fields of microsphere adhesion and contact dynamics, and demonstrates a unique monolayer delamination morphology. PMID:27409715

  4. Laser-Induced Incandescence: Detection Issues

    NASA Technical Reports Server (NTRS)

    VanderWal, Randall L.

    1996-01-01

    Experimental LII (laser-induced incandescence) measurements were performed in a laminar gasjet flame to test the sensitivity of different LII signal collection strategies to particle size. To prevent introducing a particle size dependent bias in the LII signal, signal integration beginning with the excitation laser pulse is necessary . Signal integration times extending to 25 or 100 nsec after the laser pulse do not produce significant differences in radial profiles of the LII signal due to particle size effects with longer signal integration times revealing a decreased sensitivity to smaller primary particles. Long wavelength detection reduces the sensitivity of the LII signal to primary particle size. Excitation of LII using 1064 nm light is recommended to avoid creating photochemical interferences thus allowing LII signal collection to occur during the excitation pulse without spectral interferences.

  5. Laser-induced breakdown spectroscopy in China

    NASA Astrophysics Data System (ADS)

    Wang, Zhe; Yuan, Ting-Bi; Hou, Zong-Yu; Zhou, Wei-Dong; Lu, Ji-Dong; Ding, Hong-Bin; Zeng, Xiao-Yan

    2014-08-01

    Laser-induced breakdown spectroscopy (LIBS) has been regarded as a future superstar for chemical analysis for years due to its unique features such as little or no sample preparation, remote sensing, and fast and multi-element analysis. Chinese LIBS community is one of the most dynamically developing communities in the World. The aim of the work is to inspect what have been done in China for LIBS development and, based on the understanding of the overall status, to identify the challenges and opportunities for the future development. In this paper, the scientific contributions from Chinese LIBS community are reviewed for the following four aspects: fundamentals, instrumentation, data processing and modeling, and applications; and the driving force of LIBS development in China is analyzed, the critical issues for successful LIBS application are discussed, and in our opinion, the potential direction to improve the technology and to realize large scale commercialization in China is proposed.

  6. Laser-induced autofluorescence of caries

    NASA Astrophysics Data System (ADS)

    Koenig, Karsten; Hibst, Raimund; Flemming, Gabriela; Schneckenburger, Herbert

    1993-07-01

    The laser induced autofluorescence from carious regions of human teeth was studied using a krypton ion laser at 407 nm as an excitation source, a fiberoptical detection system combined with a polychromator and an optical multichannel analyzer. In addition, time-resolved and time-gated fluorescence measurements in the nanosecond range were carried out. It was found that carious regions contain different fluorophores which emit in the red spectral range. The emission spectra with maxima around 590 nm, 625 nm and 635 nm are typical for metalloporphyrins, copro- and protoporphyrin. During excitation the fluorescence was bleached. Non-carious regions showed a broad fluorescence band with a maximum in the short-wavelength spectral region with shorter fluorescence decay times than the carious regions. Therefore, caries can be detected by spectral analysis of the autofluorescence as well as by determination of the fluorescence decay times or by time-gated imaging.

  7. Direct spark ignition system

    SciTech Connect

    Gann, R.A.

    1986-12-02

    This patent describes a direct spark ignition system having a gas burner, an electrically operable valve connected to the burner to admit fuel thereto, a gated oscillator having a timing circuit for timing a trial ignition, a spark generator responsive to the oscillator for igniting fuel emanating from the burner, and a flame sensor for sustaining oscillations of the oscillator while a flame exists at the burner. The spark generator has an inverter connected to a low voltage dc source and responsive to the oscillator for converting the dc voltage to a high ac voltage, a means for rectifying the high ac voltage, a capacitor connected to the rectifying means for storing the rectified high voltage, an ignition coil in series between the storage capacitor and a switch, and a means for periodically turning on the switch to produce ignition pulses through the coil. The ignition system is powered from the dc source but controlled by the oscillator. An improvement described here is wherein the inverter is comprised of a step-up transformer having its primary winding connected in series with the dc source and a common emitter transistor having its collector connected to the primary winding. The transistor has its base connected to be controlled by the oscillator to chop the dc into ac in the primary winding, and a diode connected between the storage capacitor and the collector of the transistor, the diode being poled to couple into the capacitor back EMF energy when the transistor is turned off.

  8. Laser-induced fluorescence-cued, laser-induced breakdown spectroscopy biological-agent detection

    SciTech Connect

    Hybl, John D.; Tysk, Shane M.; Berry, Shaun R.; Jordan, Michael P

    2006-12-01

    Methods for accurately characterizing aerosols are required for detecting biological warfare agents. Currently, fluorescence-based biological agent sensors provide adequate detection sensitivity but suffer from high false-alarm rates. Combining single-particle fluorescence analysis with laser-induced breakdown spectroscopy (LIBS) provides additional discrimination and potentially reduces false-alarm rates. A transportable UV laser-induced fluorescence-cued LIBS test bed has been developed and used to evaluate the utility of LIBS for biological-agent detection. Analysis of these data indicates that LIBS adds discrimination capability to fluorescence-based biological-agent detectors.However, the data also show that LIBS signatures of biological agent simulants are affected by washing. This may limit the specificity of LIBS and narrow the scope of its applicability in biological-agent detection.

  9. Characteristics of microwave plasma induced by lasers and sparks.

    PubMed

    Ikeda, Yuji; Tsuruoka, Ryoji

    2012-03-01

    Characteristics of the plasma light source of microwave (MW) plus laser-induced breakdown spectroscopy (LIBS) or spark-induced breakdown spectroscopy (SIBS) were studied. The plasma was initially generated by laser- or spark-induced breakdown as a plasma seed. A plasma volume was then grown and sustained by MWs in air. This MW plasma had a long lifetime, large volume, strong emission intensity, and high stability with time. These characteristics are suitable for applications in the molecular analysis of gases such as OH or N(2). Because the plasma properties did not depend on laser or spark plasma seeds, the resulting plasma was easily controllable by the input power and duration of the MWs. Therefore, a significant improvement was achieved in the spectral intensity and signal-to-noise ratio. For example, the peak intensity of the Pb spectra of LIBS increased 15 times, and that of SIBS increased 880 times without increases in their background noise. A MW-enhanced plasma light source could be used to make the total system smaller and cheaper than a conventional LIBS system, which would be useful for real-time and in situ analysis of gas molecules in, for example, food processing, medical applications, chemical exposure, and gas turbine or automobile air-to-fuel ratio and exhaust gas measurement. PMID:22410918

  10. Appearance of toroidal structure in dissipating laser-generated sparks

    NASA Astrophysics Data System (ADS)

    Nassif, D.; Hüwel, L.

    2000-03-01

    We have investigated the temporal and spatial evolution of laser-induced plasmas in pure nitrogen. A 1064 nm, 20 ns pulse from a neodymium-doped yttrium-aluminum-garnet (Nd:YAG) laser with pulse energies ranging from 175 to 500 mJ is tightly focused to produce a spark at various, near-atmospheric pressures. Spatially resolved Rayleigh scattered light from a time-delayed, 355 nm Nd:YAG laser pulse traversing the spark at right angles is collected with an image intensifier gated, linear diode array. At a delay time of 30 μs, the laser plasma remnant appears as a nearly spherically symmetric region with a center temperature of about 4500 K. After around 100 μs, the hot gas starts to change into a toroidal shape expanding radially at an average speed of a few meters per second. The final torus size increases with decreasing pressure and increasing laser power. This general behavior of the plasma afterglow can be reconciled with a numerical model, where in the aftermath of the spark shock wave a pair of vortices is produced which in turn moves the residual hot gas into the observed toroidal geometry.

  11. Movable fiber probe for gas-phase laser-induced breakdown spectroscopy.

    PubMed

    Dumitrescu, Cosmin E; Puzinauskas, Paulius V; Olcmen, Semih

    2008-11-01

    A movable probe that fiber couples both the beam delivery and the signal collection functions of gas-phase laser-induced breakdown spectroscopy (LIBS) measurements was evaluated. The adjustable probe was used to investigate the effect of delivery fiber curvature on plasma characteristics and the associated effect on LIBS spectra and to further identify issues remaining to facilitate fully fiber-coupled gas-phase LIBS measurements. LIBS data were collected from lean methane-air mixtures of various equivalence ratios and spectroscopically analyzed to establish the ability to determine relative fuel-air ratio. Measurements with straight delivery fiber were compared to those with the fiber curved at specific radii. Decreasing fiber radius of curvature decreased fiber transmission efficiency and reduced the spark formation probability by almost a factor of 2. For constant fiber input energy, this decreased transmission increased the percentage of failed spark formations and influenced the LIBS elemental ratio calculations. However, minimal difference was found between LIBS measurements with straight or curved fiber as long as the output energy and a constant laser beam spot diameter were maintained on the exit beam focusing lens. A significant reduction in data scatter and improved linearity were achieved by using the Balmer series H(alpha) and H(beta) hydrogen emission line ratio as a data selection criterion. Observed linear variation of H/N elemental ratio with equivalence ratio confirmed the possibility of a flexible, light-contained, fully fiber-coupled probe for remote gas-phase LIBS analysis. PMID:19122708

  12. Flame Speed and Spark Intensity

    NASA Technical Reports Server (NTRS)

    Randolph, D W; Silsbee, F B

    1925-01-01

    This report describes a series of experiments undertaken to determine whether or not the electrical characteristics of the igniting spark have any effect on the rapidity of flame spread in the explosive gas mixtures which it ignites. The results show very clearly that no such effect exists. The flame velocity in carbon-monoxide oxygen, acetylene oxygen, and gasoline-air mixtures was found to be unaffected by changes in spark intensity from sparks which were barely able to ignite the mixture up to intense condenser discharge sparks having fifty time this energy. (author)

  13. Laser-Induced Damage of Calcium Fluoride

    SciTech Connect

    Espana, Aubrey L.; Joly, Alan G.; Hess, Wayne P.; Dickinson, J T.

    2004-12-01

    Radiation damage of materials has long been of fundamental interest, especially since the growth of laser technology. One such source of damage comes from UV laser light. Laser systems continue to move into shorter wavelength ranges, but unfortunately are limited by the damage threshold of their optical components. For example, semiconductor lithography is making its way into the 157nm range and requires a material that can not only transmit this light (air cannot), but also withstand the highly energetic photons present at this shorter wavelength. CaF2, an alkaline earth halide, is the chosen material for vacuum UV 157 nm excimer radiation. It can transmit light down to 120 nm and is relatively inexpensive. Although it is readily available through natural and synthetic sources, it is often times difficult to find in high purity. Impurities in the crystal can result in occupied states in the band gap that induce photon absorption [2] and ultimately lead to the degradation of the material. In order to predict how well CaF2 will perform under irradiation of short wavelength laser light, one must understand the mechanisms for laser-induced damage. Laser damage is often a two-step process: initial photons create new defects in the lattice and subsequent photons excite these defects. When laser light is incident on a solid surface there is an initial production of electron-hole (e-h) pairs, a heating of free electrons and a generation of local heating around optically absorbing centers [3]. Once this initial excitation converts to the driving energy for nuclear motion, the result is an ejection of atoms, ions and molecules from the surface, known as desorption or ablation [3]. Secondary processes further driving desorption are photoabsorption, successive excitations of self-trapped excitons (STE's) and defects, and ionization of neutrals by incident laser light [3]. The combination of laser-induced desorption and the alterations to the electronic and geometrical

  14. Laser-induced electron capture mass spectrometry

    PubMed

    Wang; Giese

    2000-02-15

    Two techniques are reported for detection of electrophorederivatized compounds by laser-induced electron capture time-of-flight mass spectrometry (LI-EC-TOF-MS). In both cases, a nitrogen laser is used to induce the electron capture. The analyte is deposited in a matrix consisting of a compound with a low ionization potential such as benzo[ghi]perylene in the first technique, where the electron for electron capture apparently comes from this matrix. In the second technique, the analyte is deposited on a silver surface in the absence of matrix. It seems that "monoenergetic" ions instantly desorb from the target surface in the latter case, since the peak width in the continuous extraction mode essentially matches the pulse width of the laser (4 ns). Ten picomoles of 3-O-(pentafluorobenzyl)-alpha-estradiol were detected at a S/N > or = 50, where the spot size of the laser was approximately 0.25% of the sample spot. It is attractive that simple conditions can enable sensitive detection of electrophores on routine TOF-MS equipment. The technique can be anticipated to broaden the range of analytes in both polarity and size that can be detected by EC-MS relative to the range for GC/EC-MS. PMID:10701262

  15. Laser-Induced Magnetic Dipole Spectroscopy.

    PubMed

    Hintze, Christian; Bücker, Dennis; Domingo Köhler, Silvia; Jeschke, Gunnar; Drescher, Malte

    2016-06-16

    Pulse electron paramagnetic resonance measurements of nanometer scale distance distributions have proven highly effective in structural studies. They exploit the magnetic dipole-dipole coupling between spin labels site-specifically attached to macromolecules. The most commonly applied technique is double electron-electron resonance (DEER, also called pulsed electron double resonance (PELDOR)). Here we present the new technique of laser-induced magnetic dipole (LaserIMD) spectroscopy based on optical switching of the dipole-dipole coupling. In a proof of concept experiment on a model peptide, we find, already at a low quantum yield of triplet excitation, the same sensitivity for measuring the distance between a porphyrin and a nitroxide label as in a DEER measurement between two nitroxide labels. On the heme protein cytochrome C, we demonstrate that LaserIMD allows for distance measurements between a heme prosthetic group and a nitroxide label, although the heme triplet state is not directly observable by an electron spin echo. PMID:27163749

  16. Laser Induced Birefringence in Pure Liquids

    NASA Astrophysics Data System (ADS)

    Harrison, Neil J.

    1991-01-01

    Available from UMI in association with The British Library. Laser induced birefringence or the Optical Kerr effect is a subject that has undergone much research over previous years and is an established technique for the study of many classes of materials. To date the measurements on various media have been characterized by the substantial time required to obtain results and the generally poor sensitivity of the apparatus used. This work describes the development of a new apparatus which is the first in the field to automate the signal capture and analysis utilizing a 1 Gigasample/second digitizing oscilloscope connected to a microcomputer to provide fast, accurate transient analysis. Careful design of the apparatus enabled operation at two inducing wavelengths of 532nm and 1064nm. The sensitivity and accuracy of the apparatus coupled with the rapid transient evaluation was tested on a number of well characterized samples including benzene, nitrobenzene, toluene and benzoyl chloride and was found to give excellent agreement with other workers. The apparatus was used to investigate the properties of the organic pure liquid series the n-alkanes before making the first measurements on the 1-alkenes, 1-alkynes, alcohols, carboxylic acids and three alkdienes. Results from these experiments were used to evaluate the contributions of sigma and pi bonds to the Optical Kerr effect in simple organic molecules. A review of all previously published Optical Kerr effect results for pure liquids was also carried out and the first comprehensive table of results complied.

  17. Anions in laser-induced plasmas

    NASA Astrophysics Data System (ADS)

    Shabanov, S. V.; Gornushkin, I. B.

    2016-07-01

    The equation of state for plasmas containing negative atomic and molecular ions (anions) is modeled. The model is based on the assumption that all ionization processes and chemical reactions are at local thermal equilibrium and the Coulomb interaction in the plasma is described by the Debye-Hückel theory. In particular, the equation of state is obtained for plasmas containing the elements Ca, Cl, C, Si, N, and Ar. The equilibrium reaction constants are calculated using the latest experimental and ab initio data of spectroscopic constants for the molecules CaCl_2, CaCl, Cl_2, N_2, C_2, Si_2, CN, SiN, SiC, and their positive and negative ions. The model is applied to laser-induced plasmas (LIPs) by including the equation of state into a fluid dynamic numerical model based on the Navier-Stokes equations describing an expansion of LIP plumes into an ambient gas as a reactive viscous flow with radiative losses. In particular, the formation of anions Cl-, C-, Si-, {{Cl}}2^{ - }, {{Si}}2^{ - }, {{C}}2^{ - }, CN-, SiC-, and SiN- in LIPs is investigated in detail.

  18. Medical Applications of Laser Induced Breakdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    Pathak, A. K.; Rai, N. K.; Singh, Ankita; Rai, A. K.; Rai, Pradeep K.; Rai, Pramod K.

    2014-11-01

    Sedentary lifestyle of human beings has resulted in various diseases and in turn we require a potential tool that can be used to address various issues related to human health. Laser Induced Breakdown Spectroscopy (LIBS) is one such potential optical analytical tool that has become quite popular because of its distinctive features that include applicability to any type/phase of samples with almost no sample preparation. Several reports are available that discusses the capabilities of LIBS, suitable for various applications in different branches of science which cannot be addressed by traditional analytical methods but only few reports are available for the medical applications of LIBS. In the present work, LIBS has been implemented to understand the role of various elements in the formation of gallstones (formed under the empyema and mucocele state of gallbladder) samples along with patient history that were collected from Purvancal region of Uttar Pradesh, India. The occurrence statistics of gallstones under the present study reveal higher occurrence of gallstones in female patients. The gallstone occurrence was found more prevalent for those male patients who were having the habit of either tobacco chewing, smoking or drinking alcohols. This work further reports in-situ LIBS study of deciduous tooth and in-vivo LIBS study of human nail.

  19. Laser Induced Fluorescence of the Iodine Ion

    NASA Astrophysics Data System (ADS)

    Hargus, William

    2014-10-01

    Iodine (I2) has been considered as a potential electrostatic spacecraft thruster propellant for approximately 2 decades, but has only recently been demonstrated. Energy conversion efficiency appears to be on par with xenon without thruster modification. Intriguingly, performance appears to exceed xenon at high acceleration potentials. As part of a continuing program for the development of non-intrusive plasma diagnostics for advanced plasma spacecraft propulsion, we have identified the I II 5d5D4 o state as metastable, and therefore containing a reservoir of excited state ions suitable for laser probing. The 5d5D4 o - 6p5P3 transition at 695.878 nm is convenient for diode laser excitation with the 5s5S2 o - 6p5P3 transition at 516.12 nm as an ideal candidate for non-resonant fluorescence collection. We have constructed a Penning type iodine microwave discharge lamp optimized for I II production for table-top measurements. This work demonstrates I II laser-induced fluorescence in a representative iodine discharge and will validate our previous theoretical work based on the limited available historical I II spectral data.

  20. Volume of a laser-induced microjet

    NASA Astrophysics Data System (ADS)

    Kawamoto, Sennosuke; Hayasaka, Keisuke; Noguchi, Yuto; Tagawa, Yoshiyuki

    2015-11-01

    Needle-free injection systems are of great importance for medical treatments. In spite of their great potential, these systems are not commonly used. One of the common problems is strong pain caused by diffusion shape of the jet. To solve this problem, the usage of a high-speed highly-focused microjet as needle-free injection system is expected. It is thus crucial to control important indicators such as ejected volume of the jet for its safe application. We conduct experiments to reveal which parameter influences mostly the ejected volume. In the experiments, we use a glass tube of an inner diameter of 500 micro-meter, which is filled with the liquid. One end is connected to a syringe and the other end is opened. Radiating the pulse laser instantaneously vapors the liquid, followed by the generation of a shockwave. We find that the maximum volume of a laser-induced bubble is approximately proportional to the ejected volume. It is also found that the occurrence of cavitation does not affect the ejected volume while it changes the jet velocity.

  1. Laser-induced lipolysis on adipose cells

    NASA Astrophysics Data System (ADS)

    Solarte, Efrain; Gutierrez, O.; Neira, Rodrigo; Arroyave, J.; Isaza, Carolina; Ramirez, Hugo; Rebolledo, Aldo F.; Criollo, Willian; Ortiz, C.

    2004-10-01

    Recently, a new liposuction technique, using a low-level laser (LLL) device and Ultrawet solution prior to the procedure, demonstrated the movement of fat from the inside to the outside of the adipocyte (Neira et al., 2002). To determine the mechanisms involved, we have performed Scanning and Transmission Electron Microscopy studies; Light transmittance measurements on adipocyte dilutions; and a study of laser light propagation in adipose tissue. This studies show: 1. Cellular membrane alterations. 2. LLL is capable to reach the deep adipose tissue layer, and 3. The tumescence solution enhances the light propagation by clearing the tissue. MRI studies demonstrated the appearance of fat on laser treated abdominal tissue. Besides, adipocytes were cultivated and irradiated to observe the effects on isolated cells. These last studies show: 1. 635 nm-laser alone is capable of mobilizing cholesterol from the cell membrane; this action is enhanced by the presence of adrenaline and lidocaine. 2. Intracellular fat is released from adipocytes by co joint action of adrenaline, aminophyline and 635 nm-laser. Results are consistent with a laser induced cellular process, which causes fat release from the adipocytes into the intercellular space, besides the modification of the cellular membranes.

  2. Laser-induced fluorescence in medical diagnostics

    NASA Astrophysics Data System (ADS)

    Andersson-Engels, Stefan; Johansson, Jonas; Svanberg, Katarina; Svanberg, Sune

    1990-07-01

    We have performed extensive investigations using laser-induced fluorescence in animal as well as human tissue in order to localize diseased tissue and thus discriminate such tissue from normal surrounding areas. In characterizing different tissue types the endogenous fluorescence (autofluorescence) as well as specific fluorescence from different photosensitising substances was utilized. We have investigated different experimental and human malignant tumors in vivo and in vitro as well as atherosclerotic lesions in vitro. A fiber-optic fluorosensor was constructed and used in the experiments and in the clinical examination of patients. Dimensionless spectroscopic functions were formed to ensure that the signals were independent of clinically uncontrollable variables such as distance variations, tissue topography, light source fluctuations and variations in detection efficiency. A multi-color two-dimensional imaging system was constructed for real-time imaging. The system was tested peroperatively and during standard examination patient procedures. Besides utilizing the time-integrated fluorescence signal we have also investigated the possibility of incorporating time-resolved fluorescence characterization.

  3. Laser Induced Fluorescence on Molecular Discharges

    NASA Astrophysics Data System (ADS)

    Mulders, Hjalmar; Rijke, Arij; Girault, Vincent; Stoffels, Winfred

    2008-10-01

    In the last half century, mercury has been used widely as the radiating species in many low pressure fluorescent lamps. Mercury primarily radiates at 254 nm and 185 nm. These photons excite a phosphor that fluoresces back to the ground state producing visible photons. This process reduces the efficiency because much of the energy of the UV photons has to be discarded. Using a species that emits light closer to or even in the visible range reduces these losses. Ideally the species (or a mixture of several species) should build up the whole visible spectrum, much like in HID lamps. InBr seems to be a good candidate for such a lamp, because it is an efficient radiator that emits most of its light around 370 nm; much closer to the visible part of the spectrum. In order to get insight in the energy transfer processes going on in these molecules we have conducted a laser induced fluorescence (LIF) experiment on InBr vapour and on a plasma. We have measured the decay times of different rovibrational levels of the InBr-molecule as well as the spectral distribution of the fluorescence from these levels. From the former we calculated the rotational temperature of the plasma and from the latter we calculated the Franck-Condon factors for the A-state as well as the vibrational temperature.

  4. Laser-induced hydrocarbon contamination in vacuum

    NASA Astrophysics Data System (ADS)

    Riede, Wolfgang; Allenspacher, Paul; Schröder, Helmut; Wernham, Denny; Lien, Yngve

    2005-12-01

    We investigated laser-induced deposition processes on BK7 substrates under the influence of pulsed Q-switched Nd:YAG laser radiation, starting from small toluene partial pressures in a background vacuum environment. The composition and structure of the deposit was analyzed using microscopic methods like Nomarski DIC, dark-field and white-light interference microscopy, TEM, EDX and XPS. We found a distinct threshold for deposition built-up dependant on the partial pressure of toluene (0.2 J/cm2 at 0.1 mbar, 0.8 J/cm2 at 0.01 mbar toluene). The deposits strictly followed the spherical geometry of the laser spot. No deposit accumulated on MgF2 AR coated BK7 samples even at high toluene partial pressures. The onset of deposit was accompanied by periodic surface ripples formation. EDX and XPS analysis showed a carbon-like layer which strongly absorbed the 1 μm laser radiation. The typical number of shots applied was 50 000. In addition, long term lifetime tests of more than 5 Mio. shots per site were run.

  5. Tool grinding and spark testing

    NASA Technical Reports Server (NTRS)

    Widener, Edward L.

    1993-01-01

    The objectives were the following: (1) to revive the neglected art of metal-sparking; (2) to promote quality-assurance in the workplace; (3) to avoid spark-ignited explosions of dusts or volatiles; (4) to facilitate the salvage of scrap metals; and (5) to summarize important references.

  6. Classical cutoffs for laser-induced nonsequential double ionization

    SciTech Connect

    Milosevic, D.B.; Becker, W.

    2003-12-01

    Classical cutoffs for the momenta of electrons ejected in laser-induced nonsequential double ionization are derived for the recollision-impact-ionization scenario. Such simple cutoff laws can aid in the interpretation of the observed electron spectra.

  7. Vacuum ultraviolet laser induced fluorescence on a Si atomic beam

    NASA Technical Reports Server (NTRS)

    O'Brian, T. R.; Lawler, J. E.

    1991-01-01

    A broadly applicable vacuum ultraviolet experiment is described for measuring radiative lifetimes of neutral and singly-ionized atoms in a beam environment to 5-percent accuracy using laser induced fluorescence. First results for neutral Si are reported.

  8. Improved Imaging With Laser-Induced Eddy Currents

    NASA Technical Reports Server (NTRS)

    Chern, Engmin J.

    1993-01-01

    System tests specimen of material nondestructively by laser-induced eddy-current imaging improved by changing method of processing of eddy-current signal. Changes in impedance of eddy-current coil measured in absolute instead of relative units.

  9. Comparision of laser-induced and classical ultasound

    NASA Astrophysics Data System (ADS)

    Niederhauser, Joel J.; Jaeger, Michael; Frenz, Martin

    2003-06-01

    A classical medical ultrasound system was combined with a pulsed laser source to allow laser-induced ultrasound imaging (optoacoustics). Classical ultrasound is based on reflection and scattering of an incident acoustic pulse at internal tissue structures. Laser-induced ultrasound is generated in situ by heating optical absorbing structures, such as blood vessels, with a 5 ns laser pulse (few degrees or fraction of degree), which generates pressure transients. Laser-induced ultrasound probes optical properties and therefore provides much higher contrast and complementary information compared to classical ultrasound. An ultrasound array transducer in combination with a commercial medical imaging system was used to record acoustic transients of both methods. Veins and arteries in a human forearm were identified in vivo using classical color doppler and oxygenation dependent optical absorption at 660 nm and 1064 nm laser wavelength. Safety limits of both methods were explored. Laser-induced ultrasound seems well suited to improve classical ultrasound imaging of subcutaneous regions.

  10. Development of microwave-enhanced spark-induced breakdown spectroscopy

    SciTech Connect

    Ikeda, Yuji; Moon, Ahsa; Kaneko, Masashi

    2010-05-01

    We propose microwave-enhanced spark-induced breakdown spectroscopy with the same measurement and analysis processes as in laser-induced breakdown spectroscopy, but with a different plasma generation mechanism. The size and lifetime of the plasma generated can contribute to increased measurement accuracy and expand its applicability to industrial measurement, such as an exhaust gas analyzer for automobile engine development and its regulation, which has been hard to operate by laser at an engineering evaluation site. The use of microwaves in this application helps lower the cost, reduce the system size, and increase the ease of operation to make it commercially viable. A microwave frequency of 2.45 GHz was used to enhance the volume and lifetime of the plasma at atmospheric condition even at elevated pressure.

  11. Metal surface nitriding by laser induced plasma

    NASA Astrophysics Data System (ADS)

    Thomann, A. L.; Boulmer-Leborgne, C.; Andreazza-Vignolle, C.; Andreazza, P.; Hermann, J.; Blondiaux, G.

    1996-10-01

    We study a nitriding technique of metals by means of laser induced plasma. The synthesized layers are composed of a nitrogen concentration gradient over several μm depth, and are expected to be useful for tribological applications with no adhesion problem. The nitriding method is tested on the synthesis of titanium nitride which is a well-known compound, obtained at present by many deposition and diffusion techniques. In the method of interest, a laser beam is focused on a titanium target in a nitrogen atmosphere, leading to the creation of a plasma over the metal surface. In order to understand the layer formation, it is necessary to characterize the plasma as well as the surface that it has been in contact with. Progressive nitrogen incorporation in the titanium lattice and TiN synthesis are studied by characterizing samples prepared with increasing laser shot number (100-4000). The role of the laser wavelength is also inspected by comparing layers obtained with two kinds of pulsed lasers: a transversal-excited-atmospheric-pressure-CO2 laser (λ=10.6 μm) and a XeCl excimer laser (λ=308 nm). Simulations of the target temperature rise under laser irradiation are performed, which evidence differences in the initial laser/material interaction (material heated thickness, heating time duration, etc.) depending on the laser features (wavelength and pulse time duration). Results from plasma characterization also point out that the plasma composition and propagation mode depend on the laser wavelength. Correlation of these results with those obtained from layer analyses shows at first the important role played by the plasma in the nitrogen incorporation. Its presence is necessary and allows N2 dissociation and a better energy coupling with the target. Second, it appears that the nitrogen diffusion governs the nitriding process. The study of the metal nitriding efficiency, depending on the laser used, allows us to explain the differences observed in the layer features

  12. Laser-induced gas-surface interactions

    NASA Astrophysics Data System (ADS)

    Chuang, T. J.

    Chemical reactions in homogeneous systems activated by laser radiation have been extensively investigated for more than a decade. The applications of lasers to promote gas-surface interactions have just been realized in recent years. The purpose of this paper is to examine the fundamental processes involved in laser-induced gas-surface chemical interactions. Specifically, the photon-enhanced adsorption, adsorbate-adsorbate and adsorbate-solid reactions, product formation and desorption processes are discussed in detail. The dynamic processes involved in photoexcitation of the electronic and vibrational states, the energy transfer and relaxation in competition with chemical interactions are considered. These include both single and multiple photon adsorption, and fundamental and overtone transitions in the excitation process, and inter- and intra-molecular energy transfer, and coupling with phonons, electron-hole pairs and surface plasmons in the energy relaxation process. Many current experimental and theoretical studies on the subject are reviewed and discussed with the goal of clarifying the relative importance of the surface interaction steps and relating the resulting concepts to the experimentally observed phenomena. Among the many gas-solid systems that have been investigated, there has been more extensive use of CO adsorbed on metals, and SF 6 and XeF 2 interactions with silicon as examples to illustrate the many facets of the electronically and vibrationally activated surface processes. Results on IR laser stimulated desorption of C 5H 5N and C 5D 5N molecules from various solid surfaces are also presented. It is clearly shown that rapid intermolecular energy exchange and molecule to surface energy transfer can have important effects on photodesorption cross sections and isotope selectivities. It is concluded that utilization of lasers in gas-surface studies not only can provide fundamental insight into the mechanism and dynamics involved in heterogeneous

  13. Spark ignition of flowing gases

    NASA Technical Reports Server (NTRS)

    Swett, Clyde C , Jr

    1956-01-01

    Research conducted at the NACA Lewis Laboratory on ignition of flowing gases by means of long-duration discharges is summarized and analyzed. Data showing the effect of a flowing combustible mixture on the physical and electrical characteristics of spark discharges and data showing the effects of variables on the spark energy required for ignition that has been developed to predict the effect of many of the gas-stream and spark variables is described and applied to a limited amount of experimental data.

  14. Laser-induced thermal acoustic velocimetry

    NASA Astrophysics Data System (ADS)

    Schlamp, Stefan

    2000-11-01

    Laser-Induced Thermal Acoustics (LITA) is a non- intrusive, remote, four-wave mixing laser diagnostic technique for measurements of the speed of sound and of the thermal diffusivity in gases. If the gas composition is known, then its temperature and density can be inferred. Beam misalignments and bulk fluid velocities can influence the time history and intensity of LITA signals. A closed-form analytic expression for LITA signals incorporating these effects is derived. The magnitude of beam misalignment and the flow velocity can be inferred from the signal shape using a least-squares fit of this model to the experimental data. High-speed velocimetry using homodyne detection is demonstrated with NO2-seeded air in a supersonic blow-down nozzle. The measured speed of sound deviates less than 2% from the theoretical value assuming isentropic quasi-1D flow. Boundary layer effects degrade the velocity measurements to errors of 20%. Heterodyne detection is used for low-speed velocimetry up to Mach number M = 0.1. The uncertainty of the velocity measurements was ~0.2 m/s. The sound speed measurements were repeatable to 0.5%. The agreement between theory and experiments is very good. A one-hidden-layer feed-forward neural network is trained using back-propagation learning and a steepest descent learning rule to extract the speed of sound and flow velocity from a heterodyne LITA signal. The effect of the network size on the performance is demonstrated. The accuracy is determined with a second set of LITA signals that were not used during the training phase. The accuracy is found to be better than that of a conventional frequency decomposition technique while being computationally as efficient. This data analysis method is robust with respect to noise, numerically stable, and fast enough for real-time data analysis. The accuracy and uncertainty of non-resonant LITA measurements is investigated. The error in measurements of the speed of sound and of the thermal diffusivity

  15. Laser-Induced-Fluorescence Photogrammetry and Videogrammetry

    NASA Technical Reports Server (NTRS)

    Danehy, Paul; Jones, Tom; Connell, John; Belvin, Keith; Watson, Kent

    2004-01-01

    surface of the target. The improved method is denoted laser-induced-fluorescence photogrammetry.

  16. Laser-Induced Damage of Calcium Fluoride

    SciTech Connect

    Espana, A.; Joly, A.G.; Hess, W.P.; Dickinson, J.T.

    2004-01-01

    As advances continue to be made in laser technology there is an increasing demand for materials that have high thresholds for laser-induced damage. Laser damage occurs when light is absorbed, creating defects in the crystal lattice. These defects can lead to the emission of atoms, ions and molecules from the sample. One specific field where laser damage is of serious concern is semiconductor lithography, which is beginning to use light at a wavelength of 157 nm. CaF2 is a candidate material for use in this new generation of lithography. In order to prevent unnecessary damage of optical components, it is necessary to understand the mechanisms for laser damage and the factors that serve to enhance it. In this research, we study various aspects of laser interactions with CaF2, including impurity absorbance and various forms of damage caused by incident laser light. Ultraviolet (UV) laser light at 266 nm with both femtosecond (fs) and nanosecond (ns) pulse widths is used to induce ion and neutral particle emission from cleaved samples of CaF2. The resulting mass spectra show significant differences suggesting that different mechanisms for desorption occur following excitation using the different pulse durations. Following irradiation by ns pulses at 266 nm, multiple single-photon absorption from defect states is likely responsible for ion emission whereas the fs case is driven by a multi-photon absorption process. This idea is further supported by the measurements made of the transmission and reflection of fs laser pulses at 266 nm, the results of which reveal a non-linear absorption process in effect at high incident intensities. In addition, the kinetic energy profiles of desorbed Ca and K contaminant atoms are different indicating that a different mechanism is responsible for their emission as well. Overall, these results show that purity plays a key role in the desorption of atoms from CaF2 when using ns pulses. On the other hand, once the irradiance reaches high

  17. Laser induced incandescence and laser induced breakdown spectroscopy based sensor development

    NASA Astrophysics Data System (ADS)

    Eseller, Kemal Efe

    In this doctoral dissertation, two laser-based sensors were evaluated for different applications. Laser Induced Incandescence (LII) is a technique which can provide non-intrusive quantitative measurement of soot and it provides a unique diagnostic tool to characterize engine performance. Since LII is linearly proportional to the soot volume fraction, it can provide in situ, real time measurement of soot volume fraction with high temporal and spatial resolution. LII has the capability to characterize soot formation during combustion. The soot volume fraction from both flames and a soot generator was investigated with LII. The effects of experimental parameters, such as laser fluence, gate delay, gate width and various laser beam focusing, on LII signal was studied. Laser Induced Breakdown Spectroscopy (LIBS), a diagnostic tool for in situ elemental analysis, has been evaluated for on-line, simultaneous, multi-species impurity monitoring in hydrogen. LIBS spectra with different impurity levels of nitrogen, argon, and oxygen were recorded and the intensity of the spectral lines of Ar, O, N, and H observed were used to form calibration plots for impurities in hydrogen measurements. An ungated detection method for LIBS has been developed and applied to equivalence ratio measurements of CH4/air and biofuel/air. LIBS has also been used to quantitatively analyze the composition of a slurry sample. The quenching effect of water in slurry samples causes low LIBS signal quality with poor sensitivity. Univariate and multivariate calibration was performed on LIBS spectra of dried slurry samples for elemental analysis of Mg, Si and Fe. Calibration results show that the dried slurry samples give good correlation between spectral intensity and elemental concentration.

  18. Spark Plug Defects and Tests

    NASA Technical Reports Server (NTRS)

    Silsbee, F B; Loeb, L B; Sawyer, L G; Fonseca, E L; Dickinson, H C; Agnew, P G

    1920-01-01

    The successful operation of the spark plug depends to a large extent on the gas tightness of the plug. Part 1 of this report describes the method used for measuring the gas tightness of aviation spark plugs. Part 2 describes the methods used in testing the electrical conductivity of the insulation material when hot. Part 3 describes the testing of the cold dielectric strength of the insulation material, the resistance to mechanical shock, and the final engine test.

  19. Large laser sparks for laboratory simulation of high-energy-density events in planetary atmospheres

    NASA Astrophysics Data System (ADS)

    Babankova, Dagmar; Juha, Libor; Civias, Svatopluk; Bittner, Michal; Cihelka, Jaroslav; Bartnik, Andrzej; Fiedorowicz, Henryk; Mikolajczyk, Janusz; Ryc, Leszek; Pfeifer, Miroslav; Skala, Jiri; Ullschmied, Jiri

    2005-09-01

    Single ≤1 kJ pulses from a high-power laser are focused into molecular gases to create large laser sparks. This provides a unique way to mimic the chemical effects of high-energy-density events in planetary atmospheres (cometary impact, lightning) matching the natural energy-density, its spatio-temporal evolution and plasma-volume scaling of such events in a fully-controlled laboratory environment. Some chemical reactions initiated by laser-induced dielectric breakdown (LIDB) in both pure molecular gases and mixtures related to the chemical evolution of the Earth's early atmosphere were studied. Most of the experiments were carried out in a static gas cell. However, an initial series of experiments was also performed with a gas-puff target placed within a vacuum interaction chamber. Under these dynamic conditions the hot core of a laser spark can be directly investigated.

  20. Time-resolved aluminium laser-induced plasma temperature measurements

    NASA Astrophysics Data System (ADS)

    Surmick, D. M.; Parigger, C. G.

    2014-11-01

    We seek to characterize the temperature decay of laser-induced plasma near the surface of an aluminium target from laser-induced breakdown spectroscopy measurements of aluminium alloy sample. Laser-induced plasma are initiated by tightly focussing 1064 nm, nanosecond pulsed Nd:YAG laser radiation. Temperatures are inferred from aluminium monoxide spectra viewed at systematically varied time delays by comparing experimental spectra to theoretical calculations with a Nelder Mead algorithm. The temperatures are found to decay from 5173 ± 270 to 3862 ± 46 Kelvin from 10 to 100 μs time delays following optical breakdown. The temperature profile along the plasma height is also inferred from spatially resolved spectral measurements and the electron number density is inferred from Stark broadened Hβ spectra.

  1. Laser-induced fluorescence of space-exposed polyurethane

    NASA Technical Reports Server (NTRS)

    Hill, Ralph H., Jr.

    1993-01-01

    The object of this work was to utilize laser-induced fluorescence technique to characterize several samples of space-exposed polyurethane. These samples were flown on the Long Duration Exposure Facility (LDEF), which was in a shuttle-like orbit for nearly 6 years. Because of our present work to develop laser-induced-fluorescence inspection techniques for polymers, space-exposed samples and controls were lent to us for evaluation. These samples had been attached to the outer surface of LDEF; therefore, they were subjected to thermal cycling, solar ultraviolet radiation, vacuum, and atomic oxygen. It is well documented that atomic oxygen and ultraviolet exposure have detrimental effects on many polymers. This was a unique opportunity to make measurements on material that had been naturally degraded by an unusual environment. During our past work, data have come from artificially degraded samples and generally have demonstrated a correlation between laser-induced fluorescence and tensile strength or elasticity.

  2. Laser-induced differential normalized fluorescence method for cancer diagnosis

    DOEpatents

    Vo-Dinh, T.; Panjehpour, M.; Overholt, B.F.

    1996-12-03

    An apparatus and method for cancer diagnosis are disclosed. The diagnostic method includes the steps of irradiating a tissue sample with monochromatic excitation light, producing a laser-induced fluorescence spectrum from emission radiation generated by interaction of the excitation light with the tissue sample, and dividing the intensity at each wavelength of the laser-induced fluorescence spectrum by the integrated area under the laser-induced fluorescence spectrum to produce a normalized spectrum. A mathematical difference between the normalized spectrum and an average value of a reference set of normalized spectra which correspond to normal tissues is calculated, which provides for amplifying small changes in weak signals from malignant tissues for improved analysis. The calculated differential normalized spectrum is correlated to a specific condition of a tissue sample. 5 figs.

  3. Laser-induced differential normalized fluorescence method for cancer diagnosis

    DOEpatents

    Vo-Dinh, Tuan; Panjehpour, Masoud; Overholt, Bergein F.

    1996-01-01

    An apparatus and method for cancer diagnosis are disclosed. The diagnostic method includes the steps of irradiating a tissue sample with monochromatic excitation light, producing a laser-induced fluorescence spectrum from emission radiation generated by interaction of the excitation light with the tissue sample, and dividing the intensity at each wavelength of the laser-induced fluorescence spectrum by the integrated area under the laser-induced fluorescence spectrum to produce a normalized spectrum. A mathematical difference between the normalized spectrum and an average value of a reference set of normalized spectra which correspond to normal tissues is calculated, which provides for amplifying small changes in weak signals from malignant tissues for improved analysis. The calculated differential normalized spectrum is correlated to a specific condition of a tissue sample.

  4. Crystal structure of laser-induced subsurface modifications in Si

    DOE PAGESBeta

    Verburg, P. C.; Smillie, L. A.; Römer, G. R. B. E.; Haberl, B.; Bradby, J. E.; Williams, J. S.; Huis in ’t Veld, A. J.

    2015-06-04

    Laser-induced subsurface modification of dielectric materials is a well-known technology. Applications include the production of optical components and selective etching. In addition to dielectric materials, the subsurface modification technology can be applied to silicon, by employing near to mid-infrared radiation. An application of subsurface modifications in silicon is laser-induced subsurface separation, which is a method to separate wafers into individual dies. Other applications for which proofs of concept exist are the formation of waveguides and resistivity tuning. However, limited knowledge is available about the crystal structure of subsurface modifications in silicon. In this paper, we investigate the geometry and crystalmore » structure of laser-induced subsurface modifications in monocrystalline silicon wafers. Finally, in addition to the generation of lattice defects, we found that transformations to amorphous silicon and Si-iii/Si-xii occur as a result of the laser irradiation.« less

  5. Crystal structure of laser-induced subsurface modifications in Si

    SciTech Connect

    Verburg, P. C.; Smillie, L. A.; Römer, G. R. B. E.; Haberl, B.; Bradby, J. E.; Williams, J. S.; Huis in ’t Veld, A. J.

    2015-06-04

    Laser-induced subsurface modification of dielectric materials is a well-known technology. Applications include the production of optical components and selective etching. In addition to dielectric materials, the subsurface modification technology can be applied to silicon, by employing near to mid-infrared radiation. An application of subsurface modifications in silicon is laser-induced subsurface separation, which is a method to separate wafers into individual dies. Other applications for which proofs of concept exist are the formation of waveguides and resistivity tuning. However, limited knowledge is available about the crystal structure of subsurface modifications in silicon. In this paper, we investigate the geometry and crystal structure of laser-induced subsurface modifications in monocrystalline silicon wafers. Finally, in addition to the generation of lattice defects, we found that transformations to amorphous silicon and Si-iii/Si-xii occur as a result of the laser irradiation.

  6. Laser induced breakdown spectroscopy inside liquids: Processes and analytical aspects

    NASA Astrophysics Data System (ADS)

    Lazic, V.; Jovićević, S.

    2014-11-01

    This paper provides an overview of the laser induced breakdown spectroscopy (LIBS) inside liquids, applied for detection of the elements present in the media itself or in the submerged samples. The processes inherent to the laser induced plasma formation and evolution inside liquids are discussed, including shockwave generation, vapor cavitation, and ablation of solids. Types of the laser excitation considered here are single pulse, dual pulse and multi-pulse. The literature relative to the LIBS measurements and applications inside liquids is reviewed and the most relevant results are summarized. Finally, we discuss the analytical aspects and release some suggestions for improving the LIBS sensitivity and accuracy in liquid environment.

  7. Evolution of laser-induced plasma in solvent aerosols

    NASA Astrophysics Data System (ADS)

    Hening, Alexandru; Wroblewski, Ronald; George, Robert; McGirr, Scott

    2014-10-01

    This paper describes a novel technique for the detection of contaminants in air using the process of laser-induced filamentation. This work is focused primarily on the visible and infrared spectrum. Characterization of the temporal and spatial evolution of laser-generated plasma in solvent aerosols is necessary for the development of potential applications. Atmospheric aerosols impact capabilities of applications such as range from laser-induced ionized micro channels and filaments able to transfer high electric pulses over a few hundreds of meters, to the generation of plasma artifacts in air, far away from the laser source.

  8. Ultrafast molecular imaging by laser-induced electron diffraction

    SciTech Connect

    Peters, M.; Nguyen-Dang, T. T.; Cornaggia, C.; Saugout, S.; Charron, E.; Keller, A.; Atabek, O.

    2011-05-15

    We address the feasibility of imaging geometric and orbital structures of a polyatomic molecule on an attosecond time scale using the laser-induced electron diffraction (LIED) technique. We present numerical results for the highest molecular orbitals of the CO{sub 2} molecule excited by a near-infrared few-cycle laser pulse. The molecular geometry (bond lengths) is determined within 3% of accuracy from a diffraction pattern which also reflects the nodal properties of the initial molecular orbital. Robustness of the structure determination is discussed with respect to vibrational and rotational motions with a complete interpretation of the laser-induced mechanisms.

  9. Laser-induced breakdown spectroscopy for on-line engine equivalence ratio measurements.

    PubMed

    Ferioli, Francesco; Puzinauskas, Paulius V; Buckley, Steven G

    2003-09-01

    Laser-induced breakdown spectroscopy (LIBS) has been used to measure the equivalence ratio of a spark-ignited engine in a laboratory setting. Spectral features of C (711.3 nm), O (776.6 nm), N (746.3 and 743.8 nm), and CN (broad emission 707-734 nm) were used to quantify the equivalence ratio over a range from phi = 0.8 to phi = 1.2. The C/N and C/O peak ratios were found to be successful measurement metrics, compared with a standard exhaust gas oxygen analyzer, for averaged measurements. Some variation in the measurements was observed as a function of engine load. Single-shot data based on a CN/air peak ratio were evaluated using a separate calibration from averaged measurements, and the average of the single-shot data was found to agree well with the exhaust gas oxygen analyzer. The scatter in the single-shot data was substantially higher at lower equivalence ratios. The measurements including the CN peak were slightly sensitive to load, possibly due to pressure changes in the sample as the load increases, or possibly due to changes in the particle size distribution in the gas stream. PMID:14611051

  10. Laser-Induced Breakdown Spectroscopy of Trace Metals

    NASA Technical Reports Server (NTRS)

    Simons, Stephen (Technical Monitor); VanderWal, Randall L.; Ticich, Thomas M.; West, Joseph R., Jr.

    2004-01-01

    An alternative approach for laser-induced breakdown spectroscopy (LIBS) determination of trace metal determination in liquids is demonstrated. The limits of detection (LOD) for the technique ranged from 10 ppb to 10 ppm for 15 metals metals (Mg, Al, Si, Ca, Ti, Cr, Fe, Co, Ni, Cu, Zn, As, Cd, Hg, Pb) tested.

  11. Plasma erosion rate diagnostics using laser-induced fluorescence

    NASA Technical Reports Server (NTRS)

    Gaeta, C. J.; Turley, R. S.; Matossian, J. N.; Beattie, J. R.; Williamson, W. S.

    1992-01-01

    An optical technique for measuring the sputtering rate of a molybdenum surface immersed in a xenon plasma has been developed and demonstrated. This approach, which may be useful in real-time wear diagnostics for ion thrusters, relies on laser-induced fluorescence to determine the density of sputtered molybdenum atoms.

  12. Using Laser-Induced Incandescence To Measure Soot in Exhaust

    NASA Technical Reports Server (NTRS)

    Bachalo, William D.; Sankar, Subramanian V.

    2005-01-01

    An instrumentation system exploits laser-induced incandescence (LII) to measure the concentration of soot particles in an exhaust stream from an engine, furnace, or industrial process that burns hydrocarbon fuel. In comparison with LII soot-concentration-measuring systems, this system is more complex and more capable.

  13. Laser-induced copper deposition with weak reducing agents

    NASA Astrophysics Data System (ADS)

    Kochemirovsky, V. A.; Fateev, S. A.; Logunov, L. S.; Tumkin, I. I.; Safonov, S. V.; Khairullina, E. M.

    2013-11-01

    The study showed that organic alcohols with 1,2,3,5,6 hydroxyl groups can be used as reducing agents for laser-induced copper deposition from solutions (LCLD).Multiatomic alcohols, sorbitol, xylitol, and glycerol, are shown to be effective reducing agents for performing LCLD at glass-ceramic surfaces. High-conductivity copper tracks with good topology were synthesized.

  14. Efficiency of SparkJet

    NASA Technical Reports Server (NTRS)

    Golbabaei-Asl, M.; Knight, D.; Wilkinson, S.

    2013-01-01

    The thermal efficiency of a SparkJet is evaluated by measuring the impulse response of a pendulum subject to a single spark discharge. The SparkJet is attached to the end of a pendulum. A laser displacement sensor is used to measure the displacement of the pendulum upon discharge. The pendulum motion is a function of the fraction of the discharge energy that is channeled into the heating of the gas (i.e., increasing the translational-rotational temperature). A theoretical perfect gas model is used to estimate the portion of the energy from the heated gas that results in equivalent pendulum displacement as in the experiment. The earlier results from multiple runs for different capacitances of C = 3, 5, 10, 20, and 40(micro)F demonstrate that the thermal efficiency decreases with higher capacitive discharges.1 In the current paper, results from additional run cases have been included and confirm the previous results

  15. Are Crab nanoshots Schwinger sparks?

    SciTech Connect

    Stebbins, Albert; Yoo, Hojin

    2015-05-21

    The highest brightness temperature ever observed are from "nanoshots" from the Crab pulsar which we argue could be the signature of bursts of vacuum e± pair production. If so this would be the first time the astronomical Schwinger effect has been observed. These "Schwinger sparks" would be an intermittent but extremely powerful, ~103 L, 10 PeV e± accelerator in the heart of the Crab. These nanosecond duration sparks are generated in a volume less than 1 m3 and the existence of such sparks has implications for the small scale structure of the magnetic field of young pulsars such as the Crab. As a result, this mechanism may also play a role in producing other enigmatic bright short radio transients such as fast radio bursts.

  16. Bright Sparks of Our Future!

    NASA Astrophysics Data System (ADS)

    Riordan, Naoimh

    2016-04-01

    My name is Naoimh Riordan and I am the Vice Principal of Rockboro Primary School in Cork City, South of Ireland. I am a full time class primary teacher and I teach 4th class, my students are aged between 9-10 years. My passion for education has developed over the years and grown towards STEM (Science, Technology, Engineering and Mathematics) subjects. I believe these subjects are the way forward for our future. My passion and beliefs are driven by the unique after school programme that I have developed. It is titled "Sparks" coming from the term Bright Sparks. "Sparks" is an after school programme with a difference where the STEM subjects are concentrated on through lessons such as Science, Veterinary Science Computer Animation /Coding, Eco engineering, Robotics, Magical Maths, Chess and Creative Writing. All these subjects are taught through activity based learning and are one-hour long each week for a ten-week term. "Sparks" is fully inclusive and non-selective which gives all students of any level of ability an opportunity to engage into these subjects. "Sparks" is open to all primary students in County Cork. The "Sparks" after school programme is taught by tutors from the different Universities and Colleges in Cork City. It works very well because the tutor brings their knowledge, skills and specialised equipment from their respective universities and in turn the tutor gains invaluable teaching practise, can trial a pilot programme in a chosen STEM subject and gain an insight into what works in the physical classroom.

  17. IKK2 Inhibition Attenuates Laser-Induced Choroidal Neovascularization

    PubMed Central

    Lu, Huayi; Lu, Qingxian; Gaddipati, Subhash; Kasetti, Ramesh Babu; Wang, Wei; Pasparakis, Manolis; Kaplan, Henry J.; Li, Qiutang

    2014-01-01

    Choroidal neovascularization (CNV) is aberrant angiogenesis associated with exudative age-related macular degeneration (AMD), a leading cause of blindness in the elderly. Inflammation has been suggested as a risk factor for AMD. The IKK2/NF-κB pathway plays a key role in the inflammatory response through regulation of the transcription of cytokines, chemokines, growth factors and angiogenic factors. We investigated the functional role of IKK2 in development of the laser-induced CNV using either Ikk2 conditional knockout mice or an IKK2 inhibitor. The retinal neuronal tissue and RPE deletion of IKK2 was generated by breeding Ikk2−/flox mice with Nestin-Cre mice. Deletion of Ikk2 in the retina caused no obvious defect in retinal development or function, but resulted in a significant reduction in laser-induced CNV. In addition, intravitreal or retrobulbar injection of an IKK2 specific chemical inhibitor, TPCA-1, also showed similar inhibition of CNV. Furthermore, in vitro inhibition of IKK2 in ARPE-19 cells significantly reduced heat shock-induced expression of NFKBIA, IL1B, CCL2, VEGFA, PDGFA, HIF1A, and MMP-2, suggesting that IKK2 may regulate multiple molecular pathways involved in laser-induced CNV. The in vivo laser-induced expression of VEGFA, and HIF1A in RPE and choroidal tissue was also blocked by TPCA-1 treatment. Thus, IKK2/NF-κB signaling appears responsible for production of pro-inflammatory and pro-angiogenic factors in laser-induced CNV, suggesting that this intracellular pathway may serve as an important therapeutic target for aberrant angiogenesis in exudative AMD. PMID:24489934

  18. Fiber laser coupled optical spark delivery system

    DOEpatents

    Yalin, Azer; Willson, Bryan; Defoort, Morgan; Joshi, Sachin; Reynolds, Adam

    2008-03-04

    A spark delivery system for generating a spark using a laser beam is provided, and includes a laser light source and a laser delivery assembly. The laser delivery assembly includes a hollow fiber and a launch assembly comprising launch focusing optics to input the laser beam in the hollow fiber. The laser delivery assembly further includes exit focusing optics that demagnify an exit beam of laser light from the hollow fiber, thereby increasing the intensity of the laser beam and creating a spark. Other embodiments use a fiber laser to generate a spark. Embodiments of the present invention may be used to create a spark in an engine. Yet other embodiments include collecting light from the spark or a flame resulting from the spark and conveying the light for diagnostics. Methods of using the spark delivery systems and diagnostic systems are provided.

  19. Spark gap with low breakdown voltage jitter

    DOEpatents

    Rohwein, G.J.; Roose, L.D.

    1996-04-23

    Novel spark gap devices and electrodes are disclosed. The novel spark gap devices and electrodes are suitable for use in a variety of spark gap device applications. The shape of the electrodes gives rise to local field enhancements and reduces breakdown voltage jitter. Breakdown voltage jitter of approximately 5% has been measured in spark gaps according the invention. Novel electrode geometries and materials are disclosed. 13 figs.

  20. Spark gap with low breakdown voltage jitter

    DOEpatents

    Rohwein, Gerald J.; Roose, Lars D.

    1996-01-01

    Novel spark gap devices and electrodes are disclosed. The novel spark gap devices and electrodes are suitable for use in a variety of spark gap device applications. The shape of the electrodes gives rise to local field enhancements and reduces breakdown voltage jitter. Breakdown voltage jitter of approximately 5% has been measured in spark gaps according the invention. Novel electrode geometries and materials are disclosed.

  1. Effect of temperature and CO 2 concentration on laser-induced breakdown spectroscopy measurements of alkali fume

    NASA Astrophysics Data System (ADS)

    Molina, Alejandro; Shaddix, Christopher R.; Sickafoose, Shane M.; Walsh, Peter M.; Blevins, Linda G.

    2005-08-01

    Laser-induced breakdown spectroscopy (LIBS) was used in the evaluation of aerosol concentration in the exhaust of an oxygen/natural-gas glass furnace. Experiments showed that for a delay time of 10 μs and a gate width of 50 μs, the presence of CO 2 and changes in gas temperature affect the intensity of both continuum emission and the Na D lines. The intensity increased for the neutral Ca and Mg lines in the presence of 21% CO 2 when compared to 100% N 2, whereas the intensity of the Mg and Ca ionic lines decreased. An increase in temperature from 300 to 730 K produced an increase in both continuum emission and Na signal. These laboratory measurements were consistent with measurements in the glass furnace exhaust. Time-resolved analysis of the spark radiation suggested that differences in continuum radiation resulting from changes in bath composition are only apparent at long delay times. The changes in the intensity of ionic and neutral lines in the presence of CO 2 are believed to result from higher free electron number density caused by lower ionization energies of species formed during the spark decay process in the presence of CO 2. For the high Na concentration observed in the glass furnace exhaust, self-absorption of the spark radiation occurred. Power law regression was used to fit laboratory Na LIBS calibration data for sodium loadings, gas temperatures, and a CO 2 content representative of the furnace exhaust. Improvement of the LIBS measurement in this environment may be possible by evaluation of Na lines with weaker emission and through the use of shorter gate delay times.

  2. Analysis of organic vapors with laser induced breakdown spectroscopy

    SciTech Connect

    Nozari, Hadi; Tavassoli, Seyed Hassan; Rezaei, Fatemeh

    2015-09-15

    In this paper, laser induced breakdown spectroscopy (LIBS) is utilized in the study of acetone, ethanol, methanol, cyclohexane, and nonane vapors. Carbon, hydrogen, oxygen, and nitrogen atomic emission spectra have been recorded following laser-induced breakdown of the organic vapors that are mixed with air inside a quartz chamber at atmospheric pressure. The plasma is generated with focused, Q-switched Nd:YAG radiation at the wavelength of 1064 nm. The effects of ignition and vapor pressure are discussed in view of the appearance of the emission spectra. The recorded spectra are proportional to the vapor pressure in air. The hydrogen and oxygen contributions diminish gradually with consecutive laser-plasma events without gas flow. The results show that LIBS can be used to characterize organic vapor.

  3. Supersonic laser-induced jetting of aluminum micro-droplets

    SciTech Connect

    Zenou, M.; Sa'ar, A.; Kotler, Z.

    2015-05-04

    The droplet velocity and the incubation time of pure aluminum micro-droplets, printed using the method of sub-nanosecond laser induced forward transfer, have been measured indicating the formation of supersonic laser-induced jetting. The incubation time and the droplet velocity were extracted by measuring a transient electrical signal associated with droplet landing on the surface of the acceptor substrate. This technique has been exploited for studying small volume droplets, in the range of 10–100 femto-litters for which supersonic velocities were measured. The results suggest elastic propagation of the droplets across the donor-to-acceptor gap, a nonlinear deposition dynamics on the surface of the acceptor and overall efficient energy transfer from the laser beam to the droplets.

  4. Laser induced melting and crystallization of boron doped amorphous silicon

    SciTech Connect

    Nebel, C.E.; Schoeniger, S.; Dahlheimer, B.; Stutzmann, M.

    1997-07-01

    Transient reflectivity experiments have been performed to measure the dynamics of laser-induced melting of amorphous silicon (a-Si) and the crystallization to {micro}c-Si of films with different thicknesses on Corning 7059 glass. The laser-induced melting takes place with a velocity of 13 to 24 m/s, while the solidification is about a factor 10 slower. The crystallization starts at the Si/glass interface and at the surface. In the center of the films Si remains liquid for an extended period of time. The crystallization dynamics point towards an heterogeneous morphology of laser-crystallized Si, where the surface and the interface layers are composed of small grains and the bulk of larger grains.

  5. Estimating explosive performance from laser-induced shock waves

    NASA Astrophysics Data System (ADS)

    Gottfried, Jennifer

    2015-06-01

    A laboratory-scale method for predicting explosive performance (e.g., detonation velocity and pressure) based on milligram quantities of material is currently being developed. This technique is based on schlieren imaging of the shock wave generated in air by the formation of a laser-induced plasma on the surface of an energetic material. A large suite of pure and composite conventional energetic materials has been tested. Based on the observed linear correlation between the laser-induced shock velocity and the measured performance from full-scale detonation testing, this method is a potential screening tool for the development of new energetic materials and formulations prior to detonation testing. Recent results on the extension of this method to metal-containing energetic materials will be presented.

  6. Applications of laser-induced gratings to spectroscopy and dynamics

    SciTech Connect

    Rohlfing, E.A.

    1993-12-01

    This program has traditionally emphasized two principal areas of research. The first is the spectroscopic characterization of large-amplitude motion on the ground-state potential surface of small, transient molecules. The second is the reactivity of carbonaceous clusters and its relevance to soot and fullerene formation in combustion. Motivated initially by the desire to find improved methods of obtaining stimulated emission pumping (SEP) spectra of transients, most of our recent work has centered on the use of laser-induced gratings or resonant four-wave mixing in free-jet expansions. These techniques show great promise for several chemical applications, including molecular spectroscopy and photodissociation dynamics. The author describes recent applications of two-color laser-induced grating spectroscopy (LIGS) to obtain background-free SEP spectra of transients and double resonance spectra of nonfluorescing species, and the use of photofragment transient gratings to probe photodissociation dynamics.

  7. Laser-induced macular holes demonstrate impaired choroidal perfusion

    NASA Astrophysics Data System (ADS)

    Brown, Jeremiah, Jr.; Allen, Ronald D.; Zwick, Harry; Schuschereba, Steven T.; Lund, David J.; Stuck, Bruce E.

    2003-06-01

    Choroidal perfusion was evaluated following the creation of a laser induced macular hole in a nonhuman primate model. Two Rhesus monkeys underwent macular exposures delivered by a Q-switched Nd:YAG laser. The lesions were evaluated with fluorescein angiography and indocyanine green (ICG) angiography . Each lesion produced vitreous hemorrhage and progressed to a full thickness macular hole. ICG angiography revealed no perfusion of the choriocapillaris beneath the lesion centers. Histopathologic evaluation showed replacement of the choriocapillaris with fibroblasts and connective tissue. Nd:YAG, laser-induced macular holes result in long term impairment of choroidal perfusion at the base of the hole due to choroidal scarring and obliteration of the choriocapillaris.

  8. Analysis of organic vapors with laser induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Nozari, Hadi; Rezaei, Fatemeh; Tavassoli, Seyed Hassan

    2015-09-01

    In this paper, laser induced breakdown spectroscopy (LIBS) is utilized in the study of acetone, ethanol, methanol, cyclohexane, and nonane vapors. Carbon, hydrogen, oxygen, and nitrogen atomic emission spectra have been recorded following laser-induced breakdown of the organic vapors that are mixed with air inside a quartz chamber at atmospheric pressure. The plasma is generated with focused, Q-switched Nd:YAG radiation at the wavelength of 1064 nm. The effects of ignition and vapor pressure are discussed in view of the appearance of the emission spectra. The recorded spectra are proportional to the vapor pressure in air. The hydrogen and oxygen contributions diminish gradually with consecutive laser-plasma events without gas flow. The results show that LIBS can be used to characterize organic vapor.

  9. Supersonic laser-induced jetting of aluminum micro-droplets

    NASA Astrophysics Data System (ADS)

    Zenou, M.; Sa'ar, A.; Kotler, Z.

    2015-05-01

    The droplet velocity and the incubation time of pure aluminum micro-droplets, printed using the method of sub-nanosecond laser induced forward transfer, have been measured indicating the formation of supersonic laser-induced jetting. The incubation time and the droplet velocity were extracted by measuring a transient electrical signal associated with droplet landing on the surface of the acceptor substrate. This technique has been exploited for studying small volume droplets, in the range of 10-100 femto-litters for which supersonic velocities were measured. The results suggest elastic propagation of the droplets across the donor-to-acceptor gap, a nonlinear deposition dynamics on the surface of the acceptor and overall efficient energy transfer from the laser beam to the droplets.

  10. Laser-induced periodic surface structuring of biopolymers

    NASA Astrophysics Data System (ADS)

    Pérez, Susana; Rebollar, Esther; Oujja, Mohamed; Martín, Margarita; Castillejo, Marta

    2013-03-01

    We report here on a systematic study about the formation of laser-induced periodic surface structures (LIPSS) on biopolymers. Self-standing films of the biopolymers chitosan, starch and the blend of chitosan with the synthetic polymer poly (vinyl pyrrolidone), PVP, were irradiated in air with linearly polarized laser beams at 193, 213 and 266 nm, with pulse durations in the range of 6-17 ns. The laser-induced periodic surface structures were topographically characterized by atomic force microscopy and the chemical modifications induced by laser irradiation were inspected via Raman spectroscopy. Formation of LIPSS parallel to the laser polarization direction, with periods similar to the laser wavelength, was observed at efficiently absorbed wavelengths in the case of the amorphous biopolymer chitosan and its blend with PVP, while formation of LIPSS is prevented in the crystalline starch biopolymer.

  11. Fiber coupled optical spark delivery system

    DOEpatents

    Yalin, Azer; Willson, Bryan; Defoort, Morgan

    2008-08-12

    A spark delivery system for generating a spark using a laser beam is provided, the spark delivery system including a laser light source and a laser delivery assembly. The laser delivery assembly includes a hollow fiber and a launch assembly comprising launch focusing optics to input the laser beam in the hollow fiber. In addition, the laser delivery assembly includes exit focusing optics that demagnify an exit beam of laser light from the hollow fiber, thereby increasing the intensity of the laser beam and creating a spark. In accordance with embodiments of the present invention, the assembly may be used to create a spark in a combustion engine. In accordance with other embodiments of the present invention, a method of using the spark delivery system is provided. In addition, a method of choosing an appropriate fiber for creating a spark using a laser beam is also presented.

  12. Laser-induced incandescence applied to droplet combustion

    NASA Astrophysics Data System (ADS)

    Wal, Randall L. Vander; Dietrich, Daniel L.

    1995-02-01

    Laser-induced incandescence (LII) is ideally suited for obtaining high temporally and spatially resolved measurements of soot volume fraction in transient combustion phenomena. We demonstrate qualitative two-dimensional nonintrusive optical measurements of the soot evolution versus time from single fiber-supported burning fuel droplets of heptane and decane. Quantitative measurement of the soot volume fraction is also demonstrated through calibration of the LII signal against a small coflow ethylene diffusion flame.

  13. Post-acceleration of laser-induced ion beams

    NASA Astrophysics Data System (ADS)

    Nassisi, V.; Delle Side, D.

    2015-04-01

    A complete review of the essential and recent developments in the field of post-acceleration of laser-induced ion beams is presented. After a brief introduction to the physics of low-intensity nanosecond laser-matter interaction, the details of ions extraction and acceleration are critically analyzed and the key parameters to obtain good-quality ion beams are illustrated. A description of the most common ion beam diagnosis system is given, together with the associated analytical techniques.

  14. Lowering evaluation uncertainties in laser-induced damage testing

    NASA Astrophysics Data System (ADS)

    Jensen, Lars O.; Mrohs, Marius; Gyamfi, Mark; Mädebach, Heinrich; Ristau, Detlev

    2015-11-01

    As a consequence of the statistical nature of laser-induced damage threshold measurements in the nanosecond regime, the evaluation method plays a vital role. Within the test procedure outlined in the corresponding ISO standard, several steps of data reduction are required, and the resulting damage probability distribution as a function of laser fluence needs to be fitted either based on an empirical regression function or described by models for the respective damage mechanism.

  15. Laser-induced breakdown spectroscopy for specimen analysis

    DOEpatents

    Kumar, Akshaya; Yu-Yueh, Fang; Burgess, Shane C.; Singh, Jagdish P.

    2006-08-15

    The present invention is directed to an apparatus, a system and a method for detecting the presence or absence of trace elements in a biological sample using Laser-Induced Breakdown Spectroscopy. The trace elements are used to develop a signature profile which is analyzed directly or compared with the known profile of a standard. In one aspect of the invention, the apparatus, system and method are used to detect malignant cancer cells in vivo.

  16. Ultratrace analysis of transuranic actinides by laser-induced fluorescence

    DOEpatents

    Miller, S.M.

    1983-10-31

    Ultratrace quantities of transuranic actinides are detected indirectly by their effect on the fluorescent emissions of a preselected fluorescent species. Transuranic actinides in a sample are coprecipitated with a host lattice material containing at least one preselected fluorescent species. The actinide either quenches or enhances the laser-induced fluorescence of the preselected fluorescent species. The degree of enhancement or quenching is quantitatively related to the concentration of actinide in the sample.

  17. Lasing effects in a laser-induced plasma plume

    NASA Astrophysics Data System (ADS)

    Nagli, Lev; Gaft, Michael

    2015-11-01

    We have studied coherent emission from optically pumped preliminarily created laser induced plasma and demonstrate the possibility to create laser sources based on laser plasma as an active medium. The effect was studied in detail with Al plasma, and preliminary but promising results were also obtained with other atoms from the 13th and 14th groups of the periodic table. These lasers may be used as coherent light sources in a variety of optical applications.

  18. Coherent microwave radiation from a laser induced plasma

    SciTech Connect

    Shneider, M. N.; Miles, R. B.

    2012-12-24

    We propose a method for generation of coherent monochromatic microwave/terahertz radiation from a laser-induced plasma. It is shown that small-scale plasma, located in the interaction region of two co-propagating plane-polarized laser beams, can be a source of the dipole radiation at a frequency equal to the difference between the frequencies of the lasers. This radiation is coherent and appears as a result of the so-called optical mixing in plasma.

  19. Photodiagnostics of turbulent flows using laser-induced fluorescence

    NASA Technical Reports Server (NTRS)

    Bershader, D.; Gross, K. P.

    1983-01-01

    An optical probe technique that will allow remote measurements of temperature (and density), along with their time dependent fluctuations, to be made in a supersonic turbulent wind tunnel flow was developed. Laser-induced fluorescence from nitric oxide which was seeded into the flowing gas medium (nitrogen) at low concentrations was used. The fluorescence emission intensity following laser excitation of the nitric oxide (NO) ground state rotational levels is then related to thermodynamic quantities of the bulk fluid.

  20. Ultratrace analysis of transuranic actinides by laser-induced fluorescence

    DOEpatents

    Miller, Steven M.

    1988-01-01

    Ultratrace quantities of transuranic actinides are detected indirectly by their effect on the fluorescent emissions of a preselected fluorescent species. Transuranic actinides in a sample are coprecipitated with a host lattice material containing at least one preselected fluorescent species. The actinide either quenches or enhances the laser-induced fluorescence of the preselected fluorescent species. The degree of enhancement or quenching is quantitatively related to the concentration of actinide in the sample.

  1. Laser-induced transient grating setup with continuously tunable period

    SciTech Connect

    Vega-Flick, A.; Eliason, J. K.; Maznev, A. A.; Nelson, K. A.; Khanolkar, A.; Abi Ghanem, M.; Boechler, N.; Alvarado-Gil, J. J.

    2015-12-15

    We present a modification of the laser-induced transient grating setup enabling continuous tuning of the transient grating period. The fine control of the period is accomplished by varying the angle of the diffraction grating used to split excitation and probe beams. The setup has been tested by measuring dispersion of bulk and surface acoustic waves in both transmission and reflection geometries. The presented modification is fully compatible with optical heterodyne detection and can be easily implemented in any transient grating setup.

  2. Laser-Induced Fluorescence Helps Diagnose Plasma Processes

    NASA Technical Reports Server (NTRS)

    Beattie, J. R.; Mattosian, J. N.; Gaeta, C. J.; Turley, R. S.; Williams, J. D.; Williamson, W. S.

    1994-01-01

    Technique developed to provide in situ monitoring of rates of ion sputter erosion of accelerator electrodes in ion thrusters also used for ground-based applications to monitor, calibrate, and otherwise diagnose plasma processes in fabrication of electronic and optical devices. Involves use of laser-induced-fluorescence measurements, which provide information on rates of ion etching, inferred rates of sputter deposition, and concentrations of contaminants.

  3. Laser Induced Breakdown Spectroscopy:. AN Application on Multilayered Archeological Ceramics

    NASA Astrophysics Data System (ADS)

    Ponterio, R.; Trusso, S.; Vasi, C.; Aragona, S.; Mavilia, L.

    2004-10-01

    In this work we show an example of application of Laser Induced Breakdown Spectroscopy (LIBS) in combination with another laser-based technique: Raman micro-spectroscopy for the identification of pigments and glaze on pottery found archaeological excavations in Amendolea castle site (south of Italy in Calabrian peninsula); the objects belong to medieval period. The spectral data indicates the qualitative elemental composition of the examined materials and, in addition, give us useful information on the stratigraphy of the paint layers.

  4. Biomedical application of laser-induced tissue oxygenation

    NASA Astrophysics Data System (ADS)

    Asimov, M. M.

    2007-03-01

    Concentration of oxygen in tissue plays an important role in enhancing in vivo wide variety of biochemical reactions including cell metabolism. Aerobic cell metabolism is primary mechanism in energy production in tissue. Controlling this mechanism gives unique possibility of biological stimulation to reach therapeutic effect. This goal could be reached by laser-induced photodissociation of oxyhemoglobin in cutaneous blood vessels. This phenomenon is considered as a main mechanism of biostimulating and therapeutic effect of low energy laser radiation. Laser-induced photodissociation of oxyhemoglobin in vivo manifests itself through the changes of the value of arterial blood saturation before and during the laser irradiation. High sensitive pulse oxymeter could be used for the measurements of the level of arterial blood saturation. Unique possibility is reached in local increase the concentration of oxygen by additional releasing it into tissue. Laser-induced enrichment of tissue oxygenation stimulates of cell metabolism and allows develop new effective methods for laser therapy as well as phototherapy of pathologies where elimination of local tissue hypoxia is critical.

  5. Determination of cobalt in low-alloy steels using laser-induced breakdown spectroscopy combined with laser-induced fluorescence.

    PubMed

    Li, Jiaming; Guo, Lianbo; Zhao, Nan; Yang, Xinyan; Yi, Rongxing; Li, Kuohu; Zeng, Qingdong; Li, Xiangyou; Zeng, Xiaoyan; Lu, Yongfeng

    2016-05-01

    Cobalt element plays an important role for the properties of magnetism and thermology in steels. In this work, laser-induced breakdown spectroscopy combined with laser-induced fluorescence (LIBS-LIF) was studied to selectively enhance the intensities of Co lines. Two states of Co atoms were resonantly excited by a wavelength-tunable laser. LIBS-LIF with ground-state atom excitation (LIBS-LIFG) and LIBS-LIF with excited-state atom excitation (LIBS-LIFE) were compared. The results show that LIBS-LIFG has analytical performance with LoD of 0.82μg/g, R(2) of 0.982, RMSECV of 86μg/g, and RE of 9.27%, which are much better than conventional LIBS and LIBS-LIFE. This work provided LIBS-LIFG as a capable approach for determining trace Co element in the steel industry. PMID:26946032

  6. Lifecycle of laser-produced air sparks

    NASA Astrophysics Data System (ADS)

    Harilal, S. S.; Brumfield, B. E.; Phillips, M. C.

    2015-06-01

    We investigated the lifecycle of laser-generated air sparks or plasmas using multiple plasma diagnostic tools. The sparks were generated by focusing the fundamental radiation from an Nd:YAG laser in air, and studies included early and late time spark dynamics, decoupling of the shock wave from the plasma core, emission from the spark kernel, cold gas excitation by UV radiation, shock waves produced by the air spark, and the spark's final decay and turbulence formation. The shadowgraphic and self-emission images showed similar spark morphology at earlier and late times of its lifecycle; however, significant differences are seen in the midlife images. Spectroscopic studies in the visible region showed intense blackbody-type radiation at early times followed by clearly resolved ionic, atomic, and molecular emission. The detected spectrum at late times clearly contained emission from both CN and N2+. Additional spectral features have been identified at late times due to emission from O and N atoms, indicating some degree of molecular dissociation and excitation. Detailed spatially and temporally resolved emission analysis provides insight about various physical mechanisms leading to molecular and atomic emission by air sparks, including spark plasma excitation, heating of cold air by UV radiation emitted by the spark, and shock-heating.

  7. Lifecycle of laser-produced air sparks

    SciTech Connect

    Harilal, S. S. Brumfield, B. E.; Phillips, M. C.

    2015-06-15

    We investigated the lifecycle of laser-generated air sparks or plasmas using multiple plasma diagnostic tools. The sparks were generated by focusing the fundamental radiation from an Nd:YAG laser in air, and studies included early and late time spark dynamics, decoupling of the shock wave from the plasma core, emission from the spark kernel, cold gas excitation by UV radiation, shock waves produced by the air spark, and the spark's final decay and turbulence formation. The shadowgraphic and self-emission images showed similar spark morphology at earlier and late times of its lifecycle; however, significant differences are seen in the midlife images. Spectroscopic studies in the visible region showed intense blackbody-type radiation at early times followed by clearly resolved ionic, atomic, and molecular emission. The detected spectrum at late times clearly contained emission from both CN and N{sub 2}{sup +}. Additional spectral features have been identified at late times due to emission from O and N atoms, indicating some degree of molecular dissociation and excitation. Detailed spatially and temporally resolved emission analysis provides insight about various physical mechanisms leading to molecular and atomic emission by air sparks, including spark plasma excitation, heating of cold air by UV radiation emitted by the spark, and shock-heating.

  8. Mars Spark Source Prototype Developed

    NASA Technical Reports Server (NTRS)

    Eichenberg, Dennis J.; Lindamood, Glenn R.; VanderWal, Randall L.; Weiland, Karen J.

    2000-01-01

    The Mars Spark Source Prototype (MSSP) hardware was developed as part of a proof of concept system for the detection of trace metals such as lead, cadmium, and arsenic in Martian dusts and soils. A spark discharge produces plasma from a soil sample, and detectors measure the optical emission from metals in the plasma to identify and quantify them. Trace metal measurements are vital in assessing whether or not the Martian environment will be toxic to human explorers. The current method of x-ray fluorescence can yield concentrations of major species only. Other instruments are incompatible with the volume, weight, and power constraints for a Mars mission. The new instrument will be developed primarily for use in the Martian environment, but it would be adaptable for terrestrial use in environmental monitoring. The NASA Glenn Research Center at Lewis Field initiated the development of the MSSP as part of Glenn's Director's Discretionary Fund project for the Spark Analysis Detection of Trace Metal Species in Martian Dusts and Soils. The objective of this project is to develop and demonstrate a compact, sensitive optical instrument for the detection of trace hazardous metals in Martian dusts and soils.

  9. Multi-point laser spark generation for internal combustion engines using a spatial light modulator

    NASA Astrophysics Data System (ADS)

    Lyon, Elliott; Kuang, Zheng; Cheng, Hua; Page, Vincent; Shenton, Tom; Dearden, Geoff

    2014-11-01

    This paper reports on a technique demonstrating for the first time successful multi-point laser-induced spark generation, which is variable in three dimensions and derived from a single laser beam. Previous work on laser ignition of internal combustion engines found that simultaneously igniting in more than one location resulted in more stable and faster combustion - a key potential advantage over conventional spark ignition. However, previous approaches could only generate secondary foci at fixed locations. The work reported here is an experimental technique for multi-point laser ignition, in which several sparks with arbitrary spatial location in three dimensions are created by variable diffraction of a pulsed single laser beam source and transmission through an optical plug. The diffractive multi-beam arrays and patterns are generated using a spatial light modulator on which computer generated holograms are displayed. A gratings and lenses algorithm is used to accurately modulate the phase of the input laser beam and create multi-beam output. The underpinning theory, experimental arrangement and results obtained are presented and discussed.

  10. High temperature fiber optic laser-induced breakdown spectroscopy sensor for analysis of molten alloy constituents

    NASA Astrophysics Data System (ADS)

    Rai, Awadhesh K.; Yueh, Fang Y.; Singh, Jagdish P.; Zhang, Hansheng

    2002-10-01

    A fiber optic (FO) laser-induced breakdown spectroscopy (LIBS) sensor that measures the on-line, in situ elemental composition of a molten alloy inside the melt in a furnace is described. This sensor has applications as a process monitor and control tool for glass, aluminum, and steel melters. The sensor is based on the transmission of laser energy through a multimode optical fiber. The laser radiation from the fiber is collimated and finally focused inside the aluminum melt in the furnace by a specially designed stainless steel holder that holds the collimating and focusing lens. Atomic emission from sparks from the laser plasma is collected by the same stainless steel lens holder and transmitted back through the optical fiber and finally fed into the entrance slit of the spectrograph. The present design of the stainless steel holder is useful for obtaining a collimated LIBS signal over a long distance (the distance between the focusing and collimated lenses is more than 200 cm). Parametric studies such as sample-to-lens distance and the effect of the angle of incidence of the laser beam on the sample surface were performed. Calibration curves for minor elements were obtained for solid Al alloys as well as for a molten Al alloy in the laboratory furnace by inserting the FO LIBS probe inside the molten material. The performance of the probe was also tested by inserting the stainless steel holder into the melt at a 45° angle, which is necessary for collecting LIBS data in an industrial furnace. LIBS spectra in different spectral regions were recorded in the pilot furnace during different tests where known amounts of minor elements were added to the melt. The results obtained from this sensor for different Al alloys demonstrate the usefulness of this sensor to monitor the concentration of different constituents of the molten Al alloy in an industrial furnace.

  11. Q-Switched Alexandrite Laser-induced Chrysiasis

    PubMed Central

    Victor Ross, E.

    2015-01-01

    Background: Chyriasis is an uncommon side effect that occurs in patients who are receiving prolonged treatment with either intravenous or intramuscular gold as a distinctive blue-gray pigmentation of light-exposed skin. Laser-induced chrysiasis is a rarely described phenomenon in individuals who have received systemic gold and are subsequently treated with a Q-switched laser. Purpose: To describe the characteristics of patients with laser-induced chrysiasis. Methods: The authors describe a 60-year-old woman who developed chrysiasis at Q-switched alexandrite laser treatment sites. They also reviewed the medical literature using PubMed, searching the terms chrysiasis, gold, and laser-induced. Patient reports and previous reviews of these subjects were critically assessed and the salient features are presented. Results: Including the authors’ patient, laser-induced chrysiasis has been described in five Caucasian arthritis patients (4 women and 1 man); most of the patients had received more than 8g of systemic gold therapy during a period of 3 to 13 years. Gold therapy was still occurring or had been discontinued as long as 26 years prior to laser treatment. All of the patients immediately developed blue macules at the Q-switched laser treatment site. Resolution of the dyschromia occurred in a 70-year-old woman after two treatment sessions with a long-pulsed ruby laser and the authors’ patient after a sequential series of laser sessions using a long-pulsed alexandrite laser, followed by a nonablative fractional laser and an ablative carbon dioxide laser. Conclusion: Laser-induced chrysiasis has been observed following treatment with Q-switched lasers in patients who are receiving or have previously been treated with systemic gold. It can occur decades after treatment with gold has been discontinued. Therefore, inquiry regarding a prior history of treatment with gold—particularly in older patients with arthritis—should be considered prior to treatment with a Q

  12. Laser-induced breakdown spectroscopy with high detection sensitivity

    NASA Astrophysics Data System (ADS)

    Shen, X. K.; Ling, H.; Lu, Y. F.

    2009-02-01

    Laser-induced breakdown spectroscopy (LIBS) with spatial confinement and LIBS combined with laser-induced fluorescence (LIF) have been investigated to improve the detection sensitivity and selectivity of LIBS. An obvious enhancement in the emission intensity of Al atomic lines was observed when a cylindrical wall was placed to spatially confine the plasma plumes. The maximum enhancement factor for the emission intensity of Al atomic lines was measured to be around 10. Assuming local thermodynamic equilibrium conditions, the plasma temperatures are estimated to be in the range from 4000 to 5800 K. It shows that the plasma temperature increased by around 1000 K when the cylindrical confinement was applied. Fast imaging of the laser-induced Al plasmas shows that the plasmas were compressed into a smaller volume with a pipe presented. LIBS-LIF has been investigated to overcome the matrix effects in LIBS for the detection of trace uranium in solids. A wavelength-tunable laser with an optical parametric oscillator was used to resonantly excite the uranium atoms and ions within the plasma plumes generated by a Q-switched Nd:YAG laser. Both atomic and ionic lines can be selected to detect their fluorescence lines. A uranium concentration of 462 ppm in a glass sample can be detected using this technique at an excitation wavelength of 385.96 nm for resonant excitation of U II and a fluorescence line wavelength of 409.01 nm from U II. The mechanism of spatial confinement effects and the influence of relevant operational parameters of LIBS-LIF are discussed.

  13. H sup minus beam characterization using laser-induced neutralization

    SciTech Connect

    Yuan, V.W.; Garcia, R.; Johnson, K.F.; Saadatmand, K.; Sander, O.R.; Sandoval, D.; Shinas, M.

    1991-01-01

    The Laser-induced neutralization techniques, LINDA, is important as a noninterceptive diagnostic for quantitatively measuring beam emittance values. It is also valuable for its capability to characterize, both quantitatively and qualitatively, the performance and match of linac components. In this paper we present LINDA experimental results that show how the output beam of a radio-frequency quadrupole (RFQ) and drift-tube linac (DTL) combination changes with the variation of RFQ-DTL relative phase and of DTL cavity power. We also present results showing the effect of a longitudinal buncher on beam emissions. 2 refs., 4 figs.

  14. Remote sensing of phytoplankton using laser-induced fluorescence

    SciTech Connect

    Babichenko, S.; Poryvkina, L.; Arikese, V. ); Kaitala, S. ); Kuosa, H. )

    1993-06-01

    The results of remote laser sensing of brackish-water phytoplankton on board a research vessel are presented. Field data of laser-induced fluorescence of phytoplankton obtained during the several cruises in the mouth of tile Gulf of Finland are compared with the results of standard chlorophyll a analysis of water samples and phytoplankton species determination by microscopy. The approach of fluorescence excitation by tunable laser radiation is applied to study the spatial distribution of a natural phytoplankton community. The remote analysis of the pigment composition of a phytoplankton community using the method of selective pigment excitation is described. The possibility of elaborating methods of quantitative laser remote biomonitoring is discussed.

  15. Laser-induced backward transfer of nanoimprinted polymer elements

    NASA Astrophysics Data System (ADS)

    Feinaeugle, Matthias; Heath, Daniel J.; Mills, Benjamin; Grant-Jacob, James A.; Mashanovich, Goran Z.; Eason, Robert W.

    2016-04-01

    Femtosecond laser-induced backward transfer of transparent photopolymers is demonstrated in the solid state, assisted by a digital micromirror spatial light modulator for producing shaped deposits. Through use of an absorbing silicon carrier substrate, we have been able to successfully transfer solid-phase material, with lateral dimensions as small as ~6 µm. In addition, a carrier of silicon incorporating a photonic waveguide relief structure enables the transfer of imprinted deposits that have been accomplished with surface features exactly complementing those present on the substrate, with an observed minimum feature size of 140 nm.

  16. Laser-Induced Breakdown Spectroscopy (LIBS): specific applications

    NASA Astrophysics Data System (ADS)

    Trtica, M. S.; Savovic, J.; Stoiljkovic, M.; Kuzmanovic, M.; Momcilovic, M.; Ciganovic, J.; Zivkovic, S.

    2015-12-01

    A short overview of Laser Induced Breakdown Spectroscopy (LIBS) with emphasis on the new trends is presented. Nowadays, due to unique features of this technique, LIBS has found applications in a great variety of fields. Achievements in the application of LIBS in nuclear area, for hazardous materials detection and in geology were considered. Also, some results recently obtained at VINCA Institute, with LIBS system based on transversely excited atmospheric (TEA) CO2 laser, are presented. Future investigations of LIBS will be oriented toward further improvement of the analytical performance of this technique, as well as on finding new application fields.

  17. Infrared laser-induced breakdown spectroscopy emissions from energetic materials

    NASA Astrophysics Data System (ADS)

    Yang, Clayton S.; Brown, E.; Hommerich, Uwe; Trivedi, Sudhir B.; Samuels, Alan C.; Snyder, A. Peter

    2011-05-01

    Laser-induced breakdown spectroscopy (LIBS) has shown great promise for applications in chemical, biological, and explosives (CBE) sensing and has significant potential for real time standoff detection and analysis. We have studied LIBS emissions in the mid-infrared (MIR) spectral region for potential applications in CBE sensing. Detailed MIR-LIBS studies were performed for several energetic materials for the first time. In this study, the IR signature spectral region between 4 - 12 um was mined for the appearance of MIR-LIBS emissions that are directly indicative of oxygenated breakdown products as well as partially dissociated and recombination molecular species.

  18. Femtosecond laser-induced electronic plasma at metal surface

    SciTech Connect

    Chen Zhaoyang; Mao, Samuel S.

    2008-08-04

    We develop a theoretical analysis to model plasma initiation at the early stage of femtosecond laser irradiation of metal surfaces. The calculation reveals that there is a threshold intensity for the formation of a microscale electronic plasma at the laser-irradidated metal surface. As the full width at half maximum of a laser pulse increases from 15 to 200 fs, the plasma formation threshold decreases by merely about 20%. The dependence of the threshold intensity on laser pulse width can be attributed to laser-induced surface electron emission, in particular due to the effect of photoelectric effect.

  19. Laser-induced thermal-acoustic velocimetry with heterodyne detection

    SciTech Connect

    Schlamp, Stefan; Cummings, Eric B.; Sobota, Thomas H.

    2000-02-15

    Laser-induced thermal acoustics (LITA) was used with heterodyne detection to measure simultaneously and in a single laser pulse the sound speed and flow velocity of NO{sub 2} -seeded air in a low-speed wind tunnel up to Mach number M=0.1 . The uncertainties of the velocity and the sound speed measurements were {approx}0.2 m/s and 0.5%, respectively. Measurements were obtained through a nonlinear least-squares fit to a general, analytic closed-form solution for heterodyne-detected LITA signals from thermal gratings. Agreement between theory and experiment is exceptionally good. (c) 2000 Optical Society of America.

  20. Nonresonant Referenced Laser-Induced Thermal Acoustics Thermometry in Air

    NASA Astrophysics Data System (ADS)

    Hart, Roger C.; Balla, R. Jeffrey; Herring, Gregory C.

    1999-01-01

    We report a detailed investigation of nonresonant laser-induced thermal acoustics (LITA) for the single-shot measurement of the speed of sound ( v S ) in an oven containing room air. A model for the speed of sound that includes important acoustic relaxation effects is used to convert the speed of sound into temperature. A reference LITA channel is used to reduce uncertainties in v S . Comparing thermocouple temperatures with temperatures deduced from our v S measurements and model, we find the mean temperature difference from 300 to 650 K to be 1% ( 2 ). The advantages of using a reference LITA channel are discussed.

  1. Laser-Induced Underwater Plasma And Its Spectroscopic Applications

    SciTech Connect

    Lazic, Violeta

    2008-09-23

    Applications of Laser Induced Breakdown Spectroscopy (LIBS) for analysis of immersed solid and soft materials, and for liquid impurities are described. A method for improving the LIBS signal underwater and for obtaining quantitative analyses in presence of strong shot-to-shot variations of the plasma properties is proposed. Dynamic of the gas bubble formed by the laser pulse is also discussed, together with its importance in Double-Pulse (DP) laser excitation. Results of the studies relative to an application of multi-pulse sequence and its effects on the plasma and gas bubble formation are also presented.

  2. Interaction between jets during laser-induced forward transfer

    SciTech Connect

    Patrascioiu, A.; Florian, C.; Fernández-Pradas, J. M.; Morenza, J. L.; Serra, P.; Hennig, G.; Delaporte, P.

    2014-07-07

    Simultaneous two-beam laser-induced forward transfer (LIFT) was carried out for various inter-beam separations, analyzing both the resulting printing outcomes and the corresponding liquid transfer dynamics. In a first experiment, droplets of an aqueous solution were printed onto a substrate at different inter-beam distances, which proved that a significant departure from the single-beam LIFT dynamics takes places at specific separations. In the second experiment, time-resolved imaging analysis revealed the existence of significant jet-jet interactions at those separations; such interactions proceed through a dynamics that results in remarkable jet deflection for which a possible onset mechanism is proposed.

  3. Laser-induced fluorescence measurement of combustion chemistry intermediates

    NASA Technical Reports Server (NTRS)

    Crosley, David R.

    1986-01-01

    Laser-induced fluorescence (LIF) can measure the trace (often free radical) species encountered as intermediates in combustion chemistry; OH, CS, NH, NS, and NCO are typical of the species detected in flames by LIF. Attention is given to illustrative experiments designed to accumulate a quantitative data base for LIF detection in low pressure flow systems and flames, as well as to flame measurements conducted with a view to the detection of new chemical intermediaries that may deepen insight into the chemistry of combustion.

  4. Trace metal mapping by laser-induced breakdown spectroscopy

    SciTech Connect

    Kaiser, Jozef; Novotny, Dr. Karel; Hrdlicka, A; Malina, R; Hartl, M; Kizek, R; Adam, V

    2012-01-01

    Abstract: Laser-Induced Breakdown Spectroscopy (LIBS) is a sensitive optical technique capable of fast multi-elemental analysis of solid, gaseous and liquid samples. The potential applications of lasers for spectrochemical analysis were developed shortly after its invention; however the massive development of LIBS is connected with the availability of powerful pulsed laser sources. Since the late 80s of 20th century LIBS dominated the analytical atomic spectroscopy scene and its application are developed continuously. Here we review the utilization of LIBS for trace elements mapping in different matrices. The main emphasis is on trace metal mapping in biological samples.

  5. Colloid formation and laser-induced bleaching in fluorite

    SciTech Connect

    LeBret, Joel B.; Cramer, Loren P.; Norton, M. Grant; Dickinson, J. T.

    2004-11-08

    Colloid formation and subsequent laser-induced bleaching in fluorite has been studied by transmission electron microscopy and electron diffraction. At high incident electron-beam (e-beam) energies, Ca colloids with diameter {approx}10 nm form a simple cubic superlattice with lattice parameter a{approx}18 nm. The colloids themselves are topotactic with the fluorite matrix forming low-energy interfaces close to a {sigma}=21 special grain boundary in cubic materials. Laser irradiation using {lambda}=532 nm has been shown to effectively bleach the e-beam-irradiated samples returning the fluorite to its monocrystalline state. The bleached samples appear more resistant to further colloid formation.

  6. Laser-induced fluorescence spectroscopy of the secondary cataract

    NASA Astrophysics Data System (ADS)

    Maslov, N. A.; Larionov, P. M.; Rozhin, I. A.; Druzhinin, I. B.; Chernykh, V. V.

    2016-06-01

    Excitation-emission matrices of laser-induced fluorescence of lens capsule epithelium, the lens nucleus, and the lens capsule are investigated. A solid-state laser in combination with an optical parametric generator tunable in the range from 210 to 350 nm was used for excitation of fluorescence. The spectra of fluorescence of all three types of tissues exhibit typical features that are specific to them and drastically differ from one another. This effect can be used for intrasurgical control of presence of residual lens capsule epithelium cells in the capsular bag after surgical treatment of a cataract.

  7. Laser-induced reaction alumina coating on ceramic composite

    NASA Astrophysics Data System (ADS)

    Xiao, Chenghe

    Silicon carbide ceramics are susceptible to corrosion by certain industrial furnace environments. It is also true for a new class of silicon carbide-particulate reinforced alumina-matrix composite (SiCsb(P)Alsb2Osb3) since it contains more than 55% of SiC particulate within the composite. This behavior would limit the use of SiCsb(P)Alsb2Osb3 composites in ceramic heat exchangers. Because oxide ceramics corrode substantially less in the same environments, a laser-induced reaction alumina coating technique has been developed for improving corrosion resistance of the SiCsb(P)Alsb2Osb3 composite. Specimens with and without the laser-induced reaction alumina coating were subjected to corrosion testing at 1200sp°C in an air atmosphere containing Nasb2COsb3 for 50 ˜ 200 hours. Corroded specimens were characterized via x-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectrometer (EDS). The uncoated SiCsbP/Alsb2Osb3 composite samples experienced an initial increase in weight during the exposure to Nasb2COsb3 at 1200sp°C due to the oxidation of residual aluminum metal in the composite. There was no significant weight change difference experienced during exposure times between 50 and 200 hours. The oxidation layer formed on the as-received composite surface consisted of Si and Alsb2Osb3 (after washing with a HF solution). The oxidation layer grew outward and inward from the original surface of the composite. The growth rate in the outward direction was faster than in the inward direction. The formation of the Si/Alsb2Osb3 oxidation layer on the as-received composite was nonuniform, and localized corrosion was observed. The coated samples experienced very little mass increase. The laser-induced reaction alumina coating effectively provided protection for the SiCsbP/Alsb2Osb3 composite by keeping the corrodents from contacting the composite and by the formation of some refractory compounds such as Nasb2OAlsb2Osb3SiOsb2 and Nasb2Alsb{22}Osb

  8. Spatial confinement effects in laser-induced breakdown spectroscopy

    SciTech Connect

    Shen, X. K.; Sun, J.; Ling, H.; Lu, Y. F.

    2007-08-20

    The spatial confinement effects in laser-induced breakdown of aluminum (Al) targets in air have been investigated both by optical emission spectroscopy and fast photography. A KrF excimer laser was used to produce plasmas from Al targets in air. Al atomic emission lines show an obvious enhancement in the emission intensity when a pair of Al-plate walls were placed to spatially confine the plasma plumes. Images of the Al plasma plumes showed that the plasma plumes evolved into a torus shape and were compressed in the Al walls. The mechanism for the confinement effects was discussed using shock wave theory.

  9. Search for laser-induced formation of antihydrogen atoms.

    PubMed

    Amoretti, M; Amsler, C; Bonomi, G; Bowe, P D; Canali, C; Carraro, C; Cesar, C L; Charlton, M; Ejsing, A M; Fontana, A; Fujiwara, M C; Funakoshi, R; Genova, P; Hangst, J S; Hayano, R S; Jørgensen, L V; Kellerbauer, A; Lagomarsino, V; Lodi Rizzini, E; Macrì, M; Madsen, N; Manuzio, G; Mitchard, D; Montagna, P; Posada, L G C; Pruys, H; Regenfus, C; Rotondi, A; Telle, H H; Testera, G; Van der Werf, D P; Variola, A; Venturelli, L; Yamazaki, Y; Zurlo, N

    2006-11-24

    Antihydrogen can be synthesized by mixing antiprotons and positrons in a Penning trap environment. Here an experiment to stimulate the formation of antihydrogen in the n = 11 quantum state by the introduction of light from a CO2 continuous wave laser is described. An overall upper limit of 0.8% with 90% C.L. on the laser-induced enhancement of the recombination has been found. This result strongly suggests that radiative recombination contributes negligibly to the antihydrogen formed in the experimental conditions used by the ATHENA Collaboration. PMID:17155742

  10. Progress in fieldable laser-induced breakdown spectroscopy (LIBS)

    NASA Astrophysics Data System (ADS)

    Miziolek, Andrzej W.

    2012-06-01

    In recent years there has been great progress in the Laser Induced Breakdown Spectroscopy (LIBS) technology field. Significant advances have been made both in fundamental and applied research as well as in data processing/chemometrics. Improvements in components, most notably lasers/optics and spectrometers are enabling the development of new devices that are suitable for field use. These new commercial devices recently released to the marketplace, as well as ones currently under development, are bringing the potential of LIBS for CBRNE threat analysis into real-world applications.

  11. Storytelling through animation: Oxford Sparks

    NASA Astrophysics Data System (ADS)

    Pyle, D. M.; Cook, A.

    2013-12-01

    Oxford Sparks is a portal that launched in 2012, with the aim of bringing together resources that have been created across the University of Oxford and elsewhere for the purpose of wider engagement with science. To bring attention to this site, Oxford Sparks developed a set of high-quality short animations, each designed to tell a story relating to a current area of science. These animations have been launched on YouTube, and will shortly be available on iTunesU, and have covered broad areas of science from subduction zones (';Underwater Volcano Disaster'), through the early history of the solar system (';Rogue Planet') to the workings of the Large Hadron Collider (';A quick look around the LHC'). The animations have each been developed in close collaboration with researchers, created by a team with experience of education, engagement and outreach. The two minute scripts are intended to be both widely accessible and viewable as ';stand alone' stories. To this end, the scripts are humorous; while the animations are delightfully quirky, and created by professional animator with a degree-level science background. The animations are also intended to be used as ';lesson starters' in school, and educational activities graded for different age groups are being developed in parallel with the animations. They have been used, successfully, on pre-university summer schools, and in university classes. We are gathering both quantitative (analytics) and qualitative (school teacher and student focus group) feedback to monitor the success of the project, and to understand the strengths and weaknesses of the approach. In the first year since launch, Oxford Sparks animations were viewed over 80,000 times on YouTube, in part due to the surge of interest in the Large Hadron Collider animation after the discovery of the Higgs Boson.

  12. Cosmic sparks from superconducting strings.

    PubMed

    Vachaspati, Tanmay

    2008-10-01

    We investigate cosmic sparks from cusps on superconducting cosmic strings in light of the recently discovered millisecond radio burst by Lorimer et al.. We find that the observed duration, fluence, spectrum, and event rate can be reasonably explained by grand unification scale superconducting cosmic strings that carry currents approximately 10{5} GeV. The superconducting string model predicts an event rate that falls off only as S{-1/2}, where S is the energy flux, and hence predicts a population of very bright bursts. Other surveys, with different observational parameters, are shown to impose tight constraints on the superconducting string model. PMID:18851517

  13. Cosmic Sparks from Superconducting Strings

    SciTech Connect

    Vachaspati, Tanmay

    2008-10-03

    We investigate cosmic sparks from cusps on superconducting cosmic strings in light of the recently discovered millisecond radio burst by Lorimer et al.. We find that the observed duration, fluence, spectrum, and event rate can be reasonably explained by grand unification scale superconducting cosmic strings that carry currents {approx}10{sup 5} GeV. The superconducting string model predicts an event rate that falls off only as S{sup -1/2}, where S is the energy flux, and hence predicts a population of very bright bursts. Other surveys, with different observational parameters, are shown to impose tight constraints on the superconducting string model.

  14. Power Measurements of Spark Discharge Experiments

    NASA Astrophysics Data System (ADS)

    Navarro-González, Rafael; Romero, Alfredo; Honda, Yasuhiro

    1998-04-01

    An accurate and precise knowledge of the amount of energy introduced into prebiotic discharge experiments is important to understand the relative roles of different energy sources in the synthesis of organic compounds in the primitive Earth's atmosphere and other planetary atmospheres. Two methods widely used to determine the power of spark discharges were evaluated, namely calorimetric and oscilloscopic, using a chemically inert gas. The power dissipated by the spark in argon at 500 Torr was determined to be 2.4 (^+12%/_-17%) J s^-1 by calorimetry and 5.3 +/- 15%) J s^-1 by the oscilloscope. The difference between the two methods was attributed to (1) an incomplete conversion of the electric energy into heat, and (2) heat loss from the spark channel to the connecting cables through the electrodes. The latter contribution leads to an unwanted effect in the spark channel by lowering the spark product yields as the spark channel cools by mixing with surrounding air and by losing heat to the electrodes. Once the concentrations of the spark products have frozen at the freeze-out temperature, any additional loss of heat from the spark channel to the electrodes has no consequence in product yields. Therefore, neither methods accurately determines the net energy transferred to the system. With a lack of a quantitative knowledge of the amount of heat loss from the spark channel during the interval from ignition of the spark to when the freeze-out temperature is reached, it is recommended to derive the energy yields of the spark products from the mean value of the two methods with the uncertainty being their standard deviation. For the case of argon at 500 Torr, this would be 3.8 (+/-50%) J s^-1.

  15. [Identification of invoice based on laser-induced photoluminescence spectrum].

    PubMed

    Yang, Qin; Yang, Yong; Tian, Yong-hong

    2011-12-01

    The rapid identification of invoice authenticity was studied based on laser-induced photoluminescence spectrum. First, the spectral curves of eighty invoice samples were obtained by laser-induced photoluminescence detection system, and genetic algorithm (GA) was applied to fit and separate overlapped spectral region between 566 and 669 nm by three Gaussian peaks. Spectral feature parameters extracted by GA were employed as the inputs of BP neural networks, and then an identification model was built. One hundred and four data were converted to 13 Gaussian parameters, and for authentic and false invoices the coefficients of determination (R2) were 0.99789 and 0.99683 and the relative standard deviations (RSD) were 0.017052 and 0.022362, respectively. It was showed that Gaussian fitting algorithm could not only simplify the parameters of models, but also improve the explanation of analysis models. Through comparison analysis of the results, it was found that the model, whose thirteen feature parameters and two evaluated parameters were all applied as BP inputs, was the best, and the corrected identification rates of sixty calibration samples and twenty validation samples were both 100%. So the identification method studied in the present research played a good role in the classification and identification, and offered a new approach to the rapid identification of invoice authenticity. PMID:22295788

  16. A model for traumatic brain injury using laser induced shockwaves

    NASA Astrophysics Data System (ADS)

    Selfridge, A.; Preece, D.; Gomez, V.; Shi, L. Z.; Berns, M. W.

    2015-08-01

    Traumatic brain injury (TBI) represents a major treatment challenge in both civilian and military medicine; on the cellular level, its mechanisms are poorly understood. As a method to study the dysfunctional repair mechanisms following injury, laser induced shock waves (LIS) are a useful way to create highly precise, well characterized mechanical forces. We present a simple model for TBI using laser induced shock waves as a model for damage. Our objective is to develop an understanding of the processes responsible for neuronal death, the ways in which we can manipulate these processes to improve cell survival and repair, and the importance of these processes at different levels of biological organization. The physics of shock wave creation has been modeled and can be used to calculate forces acting on individual neurons. By ensuring that the impulse is in the same regime as that occurring in practical TBI, the LIS model can ensure that in vitro conditions and damage are similar to those experienced in TBI. This model will allow for the study of the biochemical response of neurons to mechanical stresses, and can be combined with microfluidic systems for cell growth in order to better isolate areas of damage.

  17. Nanorod Surface Plasmon Enhancement of Laser-Induced Ultrafast Demagnetization

    PubMed Central

    Xu, Haitian; Hajisalem, Ghazal; Steeves, Geoffrey M.; Gordon, Reuven; Choi, Byoung C.

    2015-01-01

    Ultrafast laser-induced magnetization dynamics in ferromagnetic thin films were measured using a femtosecond Ti:sapphire laser in a pump-probe magneto-optic Kerr effect setup. The effect of plasmon resonance on the transient magnetization was investigated by drop-coating the ferromagnetic films with dimensionally-tuned gold nanorods supporting longitudinal surface plasmon resonance near the central wavelength of the pump laser. With ~4% nanorod areal coverage, we observe a >50% increase in demagnetization signal in nanorod-coated samples at pump fluences on the order of 0.1 mJ/cm2 due to surface plasmon-mediated localized electric-field enhancement, an effect which becomes more significant at higher laser fluences. We were able to qualitatively reproduce the experimental observations using finite-difference time-domain simulations and mean-field theory. This dramatic enhancement of ultrafast laser-induced demagnetization points to possible applications of nanorod-coated thin films in heat-assisted magnetic recording. PMID:26515296

  18. Kr II laser-induced fluorescence for measuring plasma acceleration.

    PubMed

    Hargus, W A; Azarnia, G M; Nakles, M R

    2012-10-01

    We present the application of laser-induced fluorescence of singly ionized krypton as a diagnostic technique for quantifying the electrostatic acceleration within the discharge of a laboratory cross-field plasma accelerator also known as a Hall effect thruster, which has heritage as spacecraft propulsion. The 728.98 nm Kr II transition from the metastable 5d(4)D(7/2) to the 5p(4)P(5/2)(∘) state was used for the measurement of laser-induced fluorescence within the plasma discharge. From these measurements, it is possible to measure velocity as krypton ions are accelerated from near rest to approximately 21 km/s (190 eV). Ion temperature and the ion velocity distributions may also be extracted from the fluorescence data since available hyperfine splitting data allow for the Kr II 5d(4)D(7/2)-5p(4)P(5/2)(∘) transition lineshape to be modeled. From the analysis, the fluorescence lineshape appears to be a reasonable estimate for the relatively broad ion velocity distributions. However, due to an apparent overlap of the ion creation and acceleration regions within the discharge, the distributed velocity distributions increase ion temperature determination uncertainty significantly. Using the most probable ion velocity as a representative, or characteristic, measure of the ion acceleration, overall propellant energy deposition, and effective electric fields may be calculated. With this diagnostic technique, it is possible to nonintrusively characterize the ion acceleration both within the discharge and in the plume. PMID:23126755

  19. Laser induced alignment of molecules dissolved in Helium nanodroplets

    NASA Astrophysics Data System (ADS)

    Stapelfeldt, Henrik

    2013-05-01

    Laser induced alignment, the method to confine the principal axes of molecules along axes fixed in the laboratory frame, is now used in a range of applications in physics and chemistry. With a few exceptions all studies have focused on isolated molecules in the gas phase. In this talk we present experimental studies of laser induced alignment of molecules embedded in the solvent of a superfluid helium nanodroplet. Alignment is conducted in both the adiabatic and the nonadiabtic regime where the alignment pulse is much longer or shorter, respectively, than the rotational period of the molecules. In the nonadiabatic limit, induced by a few-hundred femtosecond long laser pulse, we show that methyliodide molecules reach an alignment maximum 20 ps after the alignment pulse and gradually loose the alignment completely in another 60 ps. This dynamics is completely different from that of isolated methyliodide molecules where alignment occurs in regularly spaced (by 33.3 ps), narrow time windows, termed revivals. Adiabatic alignment, induced by 10 ns laser pulses, resembles the gas phase behavior although the observed degree of alignment falls below that of isolated molecules. Work done in collaboration with Dominik Pentkehner, Department of Chemistry, Aarhus University; Jens Hedegaard Nielsen, Department of Physics, Aarhus University; Alkwin Slenczka, Department of Chemistry, Regensburg University; and Klaus Mølmer, Department of Physics, Aarhus University.

  20. Microwave assisted laser-induced breakdown spectroscopy at ambient conditions

    NASA Astrophysics Data System (ADS)

    Viljanen, Jan; Sun, Zhiwei; Alwahabi, Zeyad T.

    2016-04-01

    Signal enhancements in laser-induced breakdown spectroscopy (LIBS) using external microwave power are demonstrated in ambient air. Pulsed microwave at 2.45 GHz and of 1 millisecond duration was delivered via a simple near field applicator (NFA), with which an external electric field is generated and coupled into laser induced plasma. The external microwave power can significantly increase the signal lifetime from a few microseconds to hundreds of microseconds, resulting in a great enhancement on LIBS signals with the use of a long integration time. The dependence of signal enhancement on laser energy and microwave power is experimentally assessed. With the assistance of microwave source, a significant enhancement of ~ 100 was achieved at relatively low laser energy that is only slightly above the ablation threshold. A limit of detection (LOD) of 8.1 ppm was estimated for copper detection in Cu/Al2O3 solid samples. This LOD corresponds to a 93-fold improvement compared with conventional single-pulse LIBS. Additionally, in the microwave assisted LIBS, the self-reversal effect was greatly reduced, which is beneficial in measuring elements of high concentration. Temporal measurements have been performed and the results revealed the evolution of the emission process in microwave-enhanced LIBS. The optimal position of the NFA related to the ablation point has also been investigated.

  1. Laser-induced breakdown spectroscopy of tantalum plasma

    NASA Astrophysics Data System (ADS)

    Khan, Sidra; Bashir, Shazia; Hayat, Asma; Khaleeq-ur-Rahman, M.; Faizan-ul-Haq

    2013-07-01

    Laser Induced Breakdown spectroscopy (LIBS) of Tantalum (Ta) plasma has been investigated. For this purpose Q-switched Nd: YAG laser pulses (λ ˜ 1064 nm, τ ˜ 10 ns) of maximum pulse energy of 100 mJ have been employed as an ablation source. Ta targets were exposed under the ambient environment of various gases of Ar, mixture (CO2: N2: He), O2, N2, and He under various filling pressure. The emission spectrum of Ta is observed by using LIBS spectrometer. The emission intensity, excitation temperature, and electron number density of Ta plasma have been evaluated as a function of pressure for various gases. Our experimental results reveal that the optical emission intensity, the electron temperature and density are strongly dependent upon the nature and pressure of ambient environment. The SEM analysis of the ablated Ta target has also been carried out to explore the effect of ambient environment on the laser induced grown structures. The growth of grain like structures in case of molecular gases and cone-formation in case of inert gases is observed. The evaluated plasma parameters by LIBS analysis such as electron temperature and the electron density are well correlated with the surface modification of laser irradiated Ta revealed by SEM analysis.

  2. Detection of explosives with laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Wang, Qian-Qian; Liu, Kai; Zhao, Hua; Ge, Cong-Hui; Huang, Zhi-Wen

    2012-12-01

    Our recent work on the detection of explosives by laser-induced breakdown spectroscopy (LIBS) is reviewed in this paper. We have studied the physical mechanism of laser-induced plasma of an organic explosive, TNT. The LIBS spectra of TNT under single-photon excitation are simulated using MATLAB. The variations of the atomic emission lines intensities of carbon, hydrogen, oxygen, and nitrogen versus the plasma temperature are simulated too. We also investigate the time-resolved LIBS spectra of a common inorganic explosive, black powder, in two kinds of surrounding atmospheres, air and argon, and find that the maximum value of the O atomic emission line SBR of black powder occurs at a gate delay of 596 ns. Another focus of our work is on using chemometic methods such as principle component analysis (PCA) and partial least squares discriminant analysis (PLS-DA) to distinguish the organic explosives from organic materials such as plastics. A PLS-DA model for classification is built. TNT and seven types of plastics are chosen as samples to test the model. The experimental results demonstrate that LIBS coupled with the chemometric techniques has the capacity to discriminate organic explosive from plastics.

  3. Laser-induced grating spectroscopy of cadmium telluride

    NASA Astrophysics Data System (ADS)

    Petrovic, Mark S.; Suchocki, Andrzej; Powell, Richard C.; Cantwell, Gene; Aldridge, Jeff

    1989-08-01

    Laser-induced transient gratings produced by two-photon absorption of picosecond pulses at 1.064 μm were used to examine the room-temperature nonlinear optical responses of CdTe crystals with different types of conductivity. Pulse-probe degenerate four-wave mixing measurements of grating dynamics on subnanosecond time scales were used to measure the ambipolar diffusion coefficient (Da) of charge carriers in the crystals. The value of Da =3.0 cm2 s-1 which was obtained is in very good agreement with theoretical estimates. A long-lived contribution to the signal consistent with a trapped charge photorefractive effect was observed at large grating spacings for n-type conductivity, and is tentatively attributed to a larger trap density in this sample. Measurements of the relative scattering efficiencies of successive diffracted orders in the Raman-Nath regime allowed for calculation of the laser-induced change in the index of refraction, due to the creation of free carriers. The value of Δn=4×10-4 which was obtained is in good agreement with theoretical estimates.

  4. Analytical application of femtosecond laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Melikechi, Noureddine; Markushin, Yuri

    2015-05-01

    We report on significant advantages provided by femtosecond laser-induced breakdown spectroscopy (LIBS) for analytical applications in fields as diverse as protein characterization and material science. We compare the results of a femto- and nanosecond-laser-induced breakdown spectroscopy analysis of dual-elemental pellets in terms of the shot-to-shot variations of the neutral/ionic emission line intensities. This study is complemented by a numerical model based on two-dimensional random close packing of disks in an enclosed geometry. In addition, we show that LIBS can be used to obtain quantitative identification of the hydrogen composition of bio-macromolecules in a heavy water solution. Finally, we show that simultaneous multi-elemental particle assay analysis combined with LIBS can significantly improve macromolecule detectability up to near single molecule per particle efficiency. Research was supported by grants from the National Science Foundation Centers of Research Excellence in Science and Technology (0630388), National Aeronautics and Space Administration (NX09AU90A). Our gratitude to Dr. D. Connolly, Fox Chase Cancer Center.

  5. Nanorod Surface Plasmon Enhancement of Laser-Induced Ultrafast Demagnetization

    NASA Astrophysics Data System (ADS)

    Xu, Haitian; Hajisalem, Ghazal; Steeves, Geoffrey M.; Gordon, Reuven; Choi, Byoung C.

    2015-10-01

    Ultrafast laser-induced magnetization dynamics in ferromagnetic thin films were measured using a femtosecond Ti:sapphire laser in a pump-probe magneto-optic Kerr effect setup. The effect of plasmon resonance on the transient magnetization was investigated by drop-coating the ferromagnetic films with dimensionally-tuned gold nanorods supporting longitudinal surface plasmon resonance near the central wavelength of the pump laser. With ~4% nanorod areal coverage, we observe a >50% increase in demagnetization signal in nanorod-coated samples at pump fluences on the order of 0.1 mJ/cm2 due to surface plasmon-mediated localized electric-field enhancement, an effect which becomes more significant at higher laser fluences. We were able to qualitatively reproduce the experimental observations using finite-difference time-domain simulations and mean-field theory. This dramatic enhancement of ultrafast laser-induced demagnetization points to possible applications of nanorod-coated thin films in heat-assisted magnetic recording.

  6. Direct probing of chromatography columns by laser-induced fluorescence

    SciTech Connect

    McGuffin, V.L.

    1992-12-07

    This report summarizes the progress and accomplishments of this research project from September 1, 1989 to February 28, 1993. During this period, we have accomplished all of the primary scientific objectives of the research proposal: (1) constructed and evaluated a laser-induced fluorescence detection system that allows direct examination of the chromatographic column, (2) examined nonequilibrium processes that occur upon solute injection and elution, (3) examined solute retention in liquid chromatography as a function of temperature and pressure, (4) examined solute zone dispersion in liquid chromatography as a function of temperature and pressure, and (5) developed appropriate theoretical models to describe these phenomena. In each of these studies, substantial knowledge has been gained of the fundamental processes that are responsible for chromatographic separations. In addition to these primary research objectives, we have made significant progress in three related areas: (1) examined pyrene as a fluorescent polarity probe insupercritical fluids and liquids as a function of temperature and pressure, (2) developed methods for the class-selective identification of polynuclear aromatic hydrocarbons in coal-derived fluids by microcolumn liquid chromatography with fluorescence quenching detection, and (3) developed methods for the determination of saturated and unsaturated (including omega-3) fatty acids in fish oil extracts by microcolumn liquid chromatography with laser-induced fluorescence detection. In these studies, the advanced separation and detection techniques developed in our laboratory are applied to practical problems of environmental and biomedical significance.

  7. Laser-induced breakdown spectroscopy of tantalum plasma

    SciTech Connect

    Khan, Sidra; Bashir, Shazia; Hayat, Asma; Khaleeq-ur-Rahman, M.; Faizan–ul-Haq

    2013-07-15

    Laser Induced Breakdown spectroscopy (LIBS) of Tantalum (Ta) plasma has been investigated. For this purpose Q-switched Nd: YAG laser pulses (λ∼ 1064 nm, τ∼ 10 ns) of maximum pulse energy of 100 mJ have been employed as an ablation source. Ta targets were exposed under the ambient environment of various gases of Ar, mixture (CO{sub 2}: N{sub 2}: He), O{sub 2}, N{sub 2}, and He under various filling pressure. The emission spectrum of Ta is observed by using LIBS spectrometer. The emission intensity, excitation temperature, and electron number density of Ta plasma have been evaluated as a function of pressure for various gases. Our experimental results reveal that the optical emission intensity, the electron temperature and density are strongly dependent upon the nature and pressure of ambient environment. The SEM analysis of the ablated Ta target has also been carried out to explore the effect of ambient environment on the laser induced grown structures. The growth of grain like structures in case of molecular gases and cone-formation in case of inert gases is observed. The evaluated plasma parameters by LIBS analysis such as electron temperature and the electron density are well correlated with the surface modification of laser irradiated Ta revealed by SEM analysis.

  8. Direct probing of chromatography columns by laser-induced fluorescence

    NASA Astrophysics Data System (ADS)

    McGuffin, V. L.

    1992-12-01

    This report summarizes the progress and accomplishments of this research project from 1 Sep. 1989 to 28 Feb. 1993. During this period, we have accomplished all of the primary scientific objectives of the research proposal: (1) constructed and evaluated a laser-induced fluorescence detection system that allows direct examination of the chromatographic column, (2) examined nonequilibrium processes that occur upon solute injection and elution, (3) examined solute retention in liquid chromatography as a function of temperature and pressure, (4) examined solute zone dispersion in liquid chromatography as a function of temperature and pressure, and (5) developed appropriate theoretical models to describe these phenomena. In each of these studies, substantial knowledge has been gained of the fundamental processes that are responsible for chromatographic separations. In addition to these primary research objectives, we have made significant progress in three related areas: (1) examined pyrene as a fluorescent polarity probe in supercritical fluids and liquids as a function of temperature and pressure, (2) developed methods for the class-selective identification of polynuclear aromatic hydrocarbons in coal-derived fluids by microcolumn liquid chromatography with fluorescence quenching detection, and (3) developed methods for the determination of saturated and unsaturated (including omega-3) fatty acids in fish oil extracts by microcolumn liquid chromatography with laser-induced fluorescence detection. In these studies, the advanced separation and detection techniques developed in our laboratory are applied to practical problems of environmental and biomedical significance.

  9. Calibration analysis of zeolites by laser induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Horňáčková, M.; Grolmusová, Z.; Horňáček, M.; Rakovský, J.; Hudec, P.; Veis, P.

    2012-08-01

    Laser induced breakdown spectroscopy was used for calibration analysis of different types of microporous crystalline aluminosilicates with exactly ordered structure — zeolites. The LIBS plasma was generated using a Q-switched Nd:YAG laser operating at the wavelength of 532 nm and providing laser pulses of 4 ns duration. Plasma emission was analysed by echelle type emission spectrometer, providing wide spectral range 200-950 nm. The spectrometer was equipped with intensified CCD camera providing rapid spectral acquisition (gating time from 5 ns). The optimum experimental conditions (time delay, gate width and laser pulse energy) have been determined for reliable use of LIBS for quantitative analysis. Samples of different molar ratios of Si/Al were used to create the calibration curves. Calibration curves for different types of zeolites (mordenite, type Y and ZSM-5) were constructed. Molar ratios of Si/Al for samples used for calibration were determined by classical wet chemical analysis and were in the range 5.3-51.8 for mordenite, 2.3-12.8 for type Y and 14-600 for ZSM-5. Zeolites with these molar ratios of Si/Al are usually used as catalysts in alkylation reactions. Laser induced breakdown spectroscopy is a suitable method for analysis of molar ratio Si/Al in zeolites, because it is simple, fast, and does not require sample preparation compared with classical wet chemical analysis which are time consuming, require difficult sample preparation and manipulation with strong acids and bases.

  10. Sparks.

    ERIC Educational Resources Information Center

    Education Unlimited, 1979

    1979-01-01

    Described are: a banking token economy to increase math skills of learning-disabled and emotionally disturbed boys (11 to 14 years old); task analysis approach to individualizing instruction for mainstreamed learning-disabled students; language and reading instruction for mainstreamed deaf and hearing-impaired students; and a music program for…

  11. Gas mixtures for spark gap closing switches

    DOEpatents

    Christophorou, L.G.; McCorkle, D.L.; Hunter, S.R.

    1987-02-20

    Gas mixtures for use in spark gap closing switches comprised of fluorocarbons and low molecular weight, inert buffer gases. To this can be added a third gas having a low ionization potential relative to the buffer gas. The gas mixtures presented possess properties that optimized the efficiency spark gap closing switches. 6 figs.

  12. Gas mixtures for spark gap closing switches

    DOEpatents

    Christophorou, Loucas G.; McCorkle, Dennis L.; Hunter, Scott R.

    1988-01-01

    Gas mixtures for use in spark gap closing switches comprised of fluorocarbons and low molecular weight, inert buffer gases. To this can be added a third gas having a low ionization potential relative to the buffer gas. The gas mixtures presented possess properties that optimized the efficiency spark gap closing switches.

  13. Sparking Interest in Nature--Family Style

    ERIC Educational Resources Information Center

    Satterlee, Donna J.; Cormons, Grace D.

    2008-01-01

    This article describes SPARK (Shore People Advancing Readiness for Knowledge), a nature-based program designed to advance literacy and environmental knowledge in a rural Virginia county that has long been combating generational poverty and low literacy. SPARK engages children between the ages of 3 and 7 and their families in nature learning. The…

  14. Trisphere spark gap actuates overvoltage relay

    NASA Technical Reports Server (NTRS)

    Camacho, S. L.

    1966-01-01

    Trisphere spark gap and high voltage relay provides a positive, fast response, high current capacity device that will sense an overvoltage condition and remove power from the circuit before insulation breakdown. When an overvoltage occurs, the spark gap breaks down and conducts an actuating current to the relay which removes power from the circuit.

  15. Determination of phosphorus in steel by the combined technique of laser induced breakdown spectrometry with laser induced fluorescence spectrometry

    NASA Astrophysics Data System (ADS)

    Kondo, Hiroyuki; Hamada, Naoya; Wagatsuma, Kazuaki

    2009-09-01

    Laser induced breakdown spectrometry (LIBS) combined with laser induced fluorescence spectrometry (LIFS) has been applied for detection of trace-level phosphorus in steel. The plasma induced by irradiation of Nd:YAG laser pulse for ablation was illuminated by the 3rd harmonic of Ti:Sapphire laser tuned to one of the resonant lines for phosphorus in the wavelength region of 253-256 nm. An excitation line for phosphorus was selected to give the highest signal-to-noise ratio. Fluorescence signals, P213.62 and P214.91 nm, were observed with high selectivity at the contents as low as several tens µg g - 1 . Fluorescence intensities were in a good linear correlation with the contents. Fluorescence intensity ratio of a collisionally assisted line (213.62 nm) to a direct transition line (214.91 nm) was discussed in terms of the analytical conditions and experimental results were compared with a calculation based on rate equations. Since the fluorescence signal light in the wavelength range longer than 200 nm can be transmitted relatively easily, even through fiber optics of moderate length, LIBS/LIFS would be a versatile technique in on-site applications for the monitoring of phosphorus contents in steel.

  16. Detection of trace phosphorus in steel using laser-induced breakdown spectroscopy combined with laser-induced fluorescence.

    PubMed

    Shen, X K; Wang, H; Xie, Z Q; Gao, Y; Ling, H; Lu, Y F

    2009-05-01

    Monitoring of light-element concentration in steel is very important for quality assurance in the steel industry. In this work, detection in open air of trace phosphorus (P) in steel using laser-induced breakdown spectroscopy (LIBS) combined with laser-induced fluorescence (LIF) has been investigated. An optical parametric oscillator wavelength-tunable laser was used to resonantly excite the P atoms within plasma plumes generated by a Q-switched Nd:YAG laser. A set of steel samples with P concentrations from 3.9 to 720 parts in 10(6) (ppm) were analyzed using LIBS-LIF at wavelengths of 253.40 and 253.56 nm for resonant excitation of P atoms and fluorescence lines at wavelengths of 213.55 and 213.62 nm. The calibration curves were measured to determine the limit of detection for P in steel, which is estimated to be around 0.7 ppm. The results demonstrate the potential of LIBS-LIF to meet the requirements for on-line analyses in open air in the steel industry. PMID:19412215

  17. Neuroprotective therapy for argon-laser-induced retinal injury

    NASA Astrophysics Data System (ADS)

    Belkin, Michael; Rosner, Mordechai; Solberg, Yoram; Turetz, Yosef

    1999-06-01

    Laser photocoagulation treatment of the central retina is often complicated by an immediate side effect of visual impairment, caused by the unavoidable laser-induced destruction of the normal tissue lying adjacent to the lesion and not affected directly by the laser beam. Furthermore, accidental laser injuries are at present untreatable. A neuroprotective therapy for salvaging the normal tissue might enhance the benefit obtained from treatment and allow safe perifoveal photocoagulation. We have developed a rat model for studying the efficacy of putative neuroprotective compounds in ameliorating laser-induced retinal damage. Four compounds were evaluated: the corticosteroid methylprednisolone, the glutamate-receptor blocker MK-801, the anti-oxidant enzyme superoxide dismutase, and the calcim-overload antagonist flunarizine. The study was carried out in two steps: in the first, the histopathological development of retinal laser injuries was studied. Argon laser lesions were inflicted in the retinas of 18 pigmented rats. The animals were sacrificed after 3, 20 or 60 days and their retinal lesions were evaluated under the light microscope. The laser injury mainly involved the outer layers of the retina, where it destroyed significant numbers of photoreceptor cells. Over time, evidence of two major histopathological processes was observed: traction of adjacent nomral retinal cells into the central area of the lesion forming an internal retinal bulging, and a retinal pigmented epithelial proliferative reaction associated with subretinal neovascularization and invations of the retinal lesion site by phagocytes. The neuroprotective effects of each of the four compounds were verified in a second step of the study. For each drug tested, 12 rats were irradiated wtih argon laser inflictions: six of them received the tested agent while the other six were treated with the corresponding vehicle. Twenty days after laser expsoure, the rats were sacrificed and their lesions were

  18. Laser-Induced Fluorescence in Gaseous [I[subscript]2] Excited with a Green Laser Pointer

    ERIC Educational Resources Information Center

    Tellinghuisen, Joel

    2007-01-01

    A green laser pointer could be used in a flashy demonstration of laser-induced fluorescence in the gas phase by directing the beam of the laser through a cell containing [I[subscript]2] at its room temperature vapor pressure. The experiment could be used to provide valuable insight into the requirements for laser-induced fluorescence (LIF) and the…

  19. Laser-induced plasma generation and evolution in a transient spray.

    PubMed

    Kawahara, Nobuyuki; Tsuboi, Kazuya; Tomita, Eiji

    2014-01-13

    The behaviors of laser-induced plasma and fuel spray were investigated by visualizing images with an ultra-high-speed camera. Time-series images of laser-induced plasma in a transient spray were visualized using a high-speed color camera. The effects of a shockwave generated from the laser-induced plasma on the evaporated spray behavior were investigated. The interaction between a single droplet and the laser-induced plasma was investigated using a single droplet levitated by an ultrasonic levitator. Two main conclusions were drawn from these experiments: (1) the fuel droplets in the spray were dispersed by the shockwave generated from the laser-induced plasma; and (2) the plasma position may have shifted due to breakdown of the droplet surface and the lens effect of droplets. PMID:24921999

  20. Microwave scattering from laser spark in air

    SciTech Connect

    Sawyer, Jordan; Zhang Zhili; Shneider, Mikhail N.

    2012-09-15

    In this paper, microwave Mie scattering from a laser-induced plasma in atmospheric air is computed. It shows that the scattered microwave transitions from coherent Rayleigh scattering to Mie scattering based on the relative transparency of the laser-induced plasma at the microwave frequency. The microwave penetration in the plasma alters from total transparency to partial shielding due to the sharp increase of the electron number density within the avalanche ionization phase. The transition from Rayleigh scattering to Mie scattering is verified by both the temporal evolution of the scattered microwave and the homogeneity of polar scattering plots.

  1. Laser-induced surface modification and metallization of polymers

    NASA Astrophysics Data System (ADS)

    Frerichs, H.; Stricker, J.; Wesner, D. A.; Kreutz, E. W.

    1995-02-01

    Laser-induced surface modification of different polymers is presented as a suitable pretreatment of surfaces in a two-step metallization process. Materials such as polyamide (PA), polypropylene (PP), polystyrene (PS), polycarbonate (PC), acrylbutadienestyrene (ABS), styreneacrylnitrile (SAN), polybutadieneterephthalate (PBT), and polyoxymethylene (POM) were treated by excimer-laser radiation at 248 nm in air. The aim of this study is to investigate different processing regimes of surface modification and ablation to increase surface roughness. Therefore, the laser-processing variables fluence F, repetition rate v and pulse number N are varied and the ablation depth, optical penetration depth, absorption coefficient and ablation threshold are determined. The metallization of pretreated (laser, wet chemical and plasma etching) polymers is investigated for different surface morphologies. The used metallization processes were electroplating and physical vapour deposition (PVD). The adhesion of the deposited films is measured with scratch and tape test methods in order to determine the regimes of suitable surface modification for metallization.

  2. Laser-induced damage measurements with 266-nm pulses

    NASA Astrophysics Data System (ADS)

    Deaton, T. F.; Smith, W. L.

    1980-07-01

    Results of a survey of laser-induced damage thresholds for optical components at 266-nm are reported. The thresholds were measured at two pulse durations; 0.150 ns and 1.0 ns. The 30 samples tested include four commercial dielectric reflectors, three metallic reflectors, two anti-reflection films, a series of eight half-wave oxide and fluoride films, and twelve bare surfaces (fluoride crystals, silica, sapphire, BK-7 glass, cesium dideuterium arsenate and potassium dihydrogen phosphate). The 266-nm pulses were obtained by frequency-quadrupling a Nd:YAG, glass laser. Equivalent plane imagery and calorimetry were used to measure the peak fluence of each of the UV pulses with an accuracy of + or - of 15%; the uncertainty in the threshold determinations is typically + or - 30%.

  3. Quantitative analysis of gallstones using laser-induced breakdown spectroscopy

    SciTech Connect

    Singh, Vivek K.; Singh, Vinita; Rai, Awadhesh K.; Thakur, Surya N.; Rai, Pradeep K.; Singh, Jagdish P

    2008-11-01

    The utility of laser-induced breakdown spectroscopy (LIBS) for categorizing different types of gallbladder stone has been demonstrated by analyzing their major and minor constituents. LIBS spectra of three types of gallstone have been recorded in the 200-900 nm spectral region. Calcium is found to be the major element in all types of gallbladder stone. The spectrophotometric method has been used to classify the stones. A calibration-free LIBS method has been used for the quantitative analysis of metal elements, and the results have been compared with those obtained from inductively coupled plasma atomic emission spectroscopy (ICP-AES) measurements. The single-shot LIBS spectra from different points on the cross section (in steps of 0.5 mm from one end to the other) of gallstones have also been recorded to study the variation of constituents from the center to the surface. The presence of different metal elements and their possible role in gallstone formation is discussed.

  4. Laser induced sonofusion: A new road toward thermonuclear reactions

    NASA Astrophysics Data System (ADS)

    Sadighi-Bonabi, Rasoul; Gheshlaghi, Maryam

    2016-03-01

    The Possibility of the laser assisted sonofusion is studied via single bubble sonoluminescence (SBSL) in Deuterated acetone (C3D6O) using quasi-adiabatic and hydro-chemical simulations at the ambient temperatures of 0 and -28.5 °C. The interior temperature of the produced bubbles in Deuterated acetone is 1.6 × 106 K in hydro-chemical model and it is reached up to 1.9 × 106 K in the laser induced SBSL bubbles. Under these circumstances, temperature up to 107 K can be produced in the center of the bubble in which the thermonuclear D-D fusion reactions are promising under the controlled conditions.

  5. Hydroxylapatite nanoparticles obtained by fiber laser-induced fracture

    NASA Astrophysics Data System (ADS)

    Boutinguiza, M.; Lusquiños, F.; Riveiro, A.; Comesaña, R.; Pou, J.

    2009-03-01

    This work presents the results of laser-induced fragmentation of hydroxylapatite microparticles in water dissolution. Calcined fish bones in form of powder, which were previously milled to achieve microsized particles, were used as precursor material. Two different laser sources were employed to reduce the size of the suspended particles: a pulsed Nd:YAG laser and a Ytterbium doped fiber laser working in continuous wave mode. The morphology as well as the composition of the obtained particles was characterized by scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy and conventional and high resolution transmission electron microscopy (TEM, HRTEM). The results show that nanometric particles of hydroxylapatite and β-tricalcium phosphate as small as 10 nm diameter can be obtained.

  6. Apparatus, system, and method for laser-induced breakdown spectroscopy

    SciTech Connect

    Effenberger, Jr., Andrew J; Scott, Jill R; McJunkin, Timothy R

    2014-11-18

    In laser-induced breakdown spectroscopy (LIBS), an apparatus includes a pulsed laser configured to generate a pulsed laser signal toward a sample, a constructive interference object and an optical element, each located in a path of light from the sample. The constructive interference object is configured to generate constructive interference patterns of the light. The optical element is configured to disperse the light. A LIBS system includes a first and a second optical element, and a data acquisition module. The data acquisition module is configured to determine an isotope measurement based, at least in part, on light received by an image sensor from the first and second optical elements. A method for performing LIBS includes generating a pulsed laser on a sample to generate light from a plasma, generating constructive interference patterns of the light, and dispersing the light into a plurality of wavelengths.

  7. Laser-induced fluorescence spectroscopy in tissue local necrosis detection

    NASA Astrophysics Data System (ADS)

    Cip, Ondrej; Buchta, Zdenek; Lesundak, Adam; Randula, Antonin; Mikel, Bretislav; Lazar, Josef; Veverkova, Lenka

    2014-03-01

    The recent effort leads to reliable imaging techniques which can help to a surgeon during operations. The fluorescence spectroscopy was selected as very useful online in vivo imaging method to organics and biological materials analysis. The presented work scopes to a laser induced fluorescence spectroscopy technique to detect tissue local necrosis in small intestine surgery. In first experiments, we tested tissue auto-fluorescence technique but a signal-to-noise ratio didn't express significant results. Then we applied a contrast dye - IndoCyanine Green (ICG) which absorbs and emits wavelengths in the near IR. We arranged the pilot experimental setup based on highly coherent extended cavity diode laser (ECDL) used for stimulating of some critical areas of the small intestine tissue with injected ICG dye. We demonstrated the distribution of the ICG exciter with the first file of shots of small intestine tissue of a rabbit that was captured by high sensitivity fluorescent cam.

  8. Laser-induced stress transients: applications for molecular delivery

    NASA Astrophysics Data System (ADS)

    Flotte, Thomas J.; Lee, Shun; Zhang, Hong; McAuliffe, Daniel J.; Douki, Tina; Doukas, Apostolos G.

    1995-05-01

    Lasers can be used to enhance the delivery of a number of molecules. Other investigators have demonstrated local release of molecules from liposomes following laser irradiation, microbeam disruption of the cell membrane to increase cell transport, microbeam ablation of the zona pellucida surrounding the ovum to increase the chances of fertilization, and increased transcutaneous transport following ablation of the stratum corneum. Our experiments have shown that laser-induced stress transients can be utilized as a vector for intracellular delivery of molecules that may or may not normally cross the cell membrane. These two conditions have been tested with Photofrin and DNA. This technology may have applications in cell and molecular biology, cancer therapy, gene therapy, and others.

  9. Laser-induced single point nanowelding of silver nanowires

    NASA Astrophysics Data System (ADS)

    Dai, Shuowei; Li, Qiang; Liu, Guoping; Yang, Hangbo; Yang, Yuanqing; Zhao, Ding; Wang, Wei; Qiu, Min

    2016-03-01

    Nanowelding of nanomaterials opens up an emerging set of applications in transparent conductors, thin-film solar cells, nanocatalysis, cancer therapy, and nanoscale patterning. Single point nanowelding (SPNW) is highly demanded for building complex nanostructures. In this letter, the precise control of SPNW of silver nanowires is explored in depth, where the nanowelding is laser-induced through the plasmonic resonance enhanced photothermal effect. It is shown that the illumination position is a critical factor for the nanowelding process. As an example of performance enhancement, output at wire end can be increased by 65% after welding for a plasmonic nanocoupler. Thus, single point nanowelding technique shows great potentials for high-performance electronic and photonic devices based on nanowires, such as nanoelectronic circuits and plasmonic nanodevices.

  10. Thermal characterization of nanofluids using laser induced thermal lens technique

    NASA Astrophysics Data System (ADS)

    Kurian, Achamma; Kumar, Rajesh B.; George, Sajan D.

    2009-08-01

    A laser induced thermal lens technique has been employed to evaluate the dynamic thermal parameter, the thermal diffusivity, of gold nanofluids. Gold nanoparticles were synthesized by citrate reduction of HAuCl4 in water. The UVVIS optical absorption spectra show an absorption peak around 540 nm owing to surface Plasmon resonance band of the gold particles. The thermal diffusivity of gold nanoparticles was evaluated by knowing the time constant of transient thermal lens obtained by fitting the experimental curve to the theoretical model of the mode-matched thermal lens. Analyses of the results show that the nanofluid exhibits lower thermal diffusivity value in comparison to the host medium, water. Further investigations also reveal that the concentration of nanoparticles in the fluid have influence on the measured thermal diffusivity value. Results are interpreted in terms of interfacial thermal resistance around the nanoparticles as well as on the clustering of nanoparticles.

  11. Elemental analysis of slurry samples with laser induced breakdown spectroscopy

    SciTech Connect

    Eseller, Kemal E.; Tripathi, Markandey M.; Yueh, Fang-Yu; Singh, Jagdish P.

    2010-05-01

    Direct analysis of wet slurry samples with laser induced breakdown spectroscopy (LIBS) is challenging due to problems of sedimentation, splashing, and surface turbulence. Also, water can quench the laser plasma and suppress the LIBS signal, resulting in poor sensitivity. The effect of water on LIBS spectra from slurries was investigated. As the water content decreased, the LIBS signal was enhanced and the standard deviation was reduced. To improve LIBS slurry analysis, dried slurry samples prepared by applying slurry on PVC coated slides were evaluated. Univariate and multivariate calibration was performed on the LIBS spectra of the dried slurry samples for elemental analysis of Mg, Si, and Fe. Calibration results show that the dried slurry samples give a good correlation between spectral intensity and elemental concentration.

  12. Laser-induced modification of transparent crystals and glasses

    SciTech Connect

    Bulgakova, N M; Stoian, Razvan; Rosenfeld, A

    2010-12-29

    We analyse the processes taking place in transparent crystals and glasses irradiated by ultrashort laser pulses in the regimes typical of various applications in optoelectronics and photonics. We consider some phenomena, which have been previously described by the authors within the different model representations: charging of the dielectric surface due to electron photoemission resulting in a Coulomb explosion; crater shaping by using an adaptive control of the laser pulse shape; optimisation of the waveguide writing in materials strongly resistant to laser-induced compaction under ordinary irradiation conditions. The developed models and analysis of the processes relying on these models include the elements of the solid-state physics, plasma physics, thermodynamics, theory of elasticity and plasticity. Some important experimental observations which require explanations and adequate description are summarised. (photonics and nanotechnology)

  13. Radioactive contamination screening with laser-induced fluorescence

    SciTech Connect

    Sheely, R.; Di Benedetto, J.

    1994-06-01

    The ability to induce, detect and discriminate fluorescence of uranium oxides makes available new capabilities for screening the surface of large complex facilities for uranium. This paper will present the results of field tests evaluate laser-induced fluorescence (LIF) as a contamination screening tool and report on the progress to produce a field portable instrument for uranium surveys on exposed surfaces. The principal effect is to illuminate the surface of an object or an area with a remotely-located light source, and to evaluate the re-radiated emission energy. A gated intensified CCD camera was used with ultraviolet (UV) laser excitation to discriminate the phosphorescent (persistent) green uranium emission from the prompt background fluorescence which results from excitation of plants, concrete, soils, and other background materials.

  14. Detection of early caries by laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Sasazawa, Shuhei; Kakino, Satoko; Matsuura, Yuji

    2015-07-01

    To improve sensitivity of dental caries detection by laser-induced breakdown spectroscopy (LIBS) analysis, it is proposed to utilize emission peaks in the ultraviolet. We newly focused on zinc whose emission peaks exist in ultraviolet because zinc exists at high concentration in the outer layer of enamel. It was shown that by using ratios between heights of an emission peak of Zn and that of Ca, the detection sensitivity and stability are largely improved. It was also shown that early caries are differentiated from healthy part by properly setting a threshold in the detected ratios. The proposed caries detection system can be applied to dental laser systems such as ones based on Er:YAG-lasers. When ablating early caries part by laser light, the system notices the dentist that the ablation of caries part is finished. We also show the intensity of emission peaks of zinc decreased with ablation with Er:YAG laser light.

  15. Quantitative investigation of soot distribution by laser-induced incandescence.

    PubMed

    Bryce, D J; Ladommatos, N; Zhao, H

    2000-09-20

    Strategies employed for quantitative measurement by laser-induced incandescence are detailed. Data are obtained for several laminar diffusion flames formed from blended Diesel fuels of known composition. A tomographic procedure is developed to scale the two-dimensional data to soot volume fraction and to correct for the trapping of signal by the soot field. Scaling is achieved by use of laser extinction along the measurement plane. The findings are used in discussions of measurement issues within turbulent environments. Data are augmented with elastic scattering measurements, allowing particle-size and number-density distributions to be inferred. A degree of axial and radial similarity among various flames suggests that the processes of soot formation and oxidation occur over similar time scales for each fuel. PMID:18350100

  16. Laser-induced microbubble poration of localized single cells.

    PubMed

    Fan, Qihui; Hu, Wenqi; Ohta, Aaron T

    2014-05-01

    Laser-induced microbubbles were used to porate the cell membranes of localized single NIH/3T3 fibroblasts. Microsecond laser pulses were focused on an optically absorbent substrate, creating a vapour microbubble that oscillated in size at the laser focal point in a fluidic chamber. The shear stress accompanying the bubble size oscillation was able to porate nearby cells. Cell poration was demonstrated with the delivery of FITC-dextran dye with various molecular weights. Under optimal poration conditions, the cell poration efficiency was up to 95.2 ± 4.8%, while maintaining 97.6 ± 2.4% cell viability. The poration system is able to target a single cell without disturbing surrounding cells. PMID:24632785

  17. Uncertainty analysis of planar laser-induced fluorescence measurements

    NASA Astrophysics Data System (ADS)

    Tavoularis, Stavros; Vanderwel, Christina

    2014-11-01

    We present a thorough analysis of the uncertainty of the planar laser-induced fluorescence (PLIF) method. We consider the measurement of concentration maps in cross-sections parallel to and normal to the axis of a slender plume containing Rhodamine 6G as a passive scalar tracer and transported by a turbulent shear flow. In particular, we identify two previously unexplored sources of error contributed by non-uniformity of the concentration across the laser sheet and by secondary fluorescence. We propose new methods to evaluate and correct for these sources of error and demonstrate that the corrected concentration measurements accurately determined the injected dye mass flow rate of the plume in the far field. Supported by NSERC.

  18. Laser-induced vibration of a thin soap film.

    PubMed

    Emile, Olivier; Emile, Janine

    2014-09-21

    We report on the vibration of a thin soap film based on the optical radiation pressure force. The modulated low power laser induces a counter gravity flow in a vertical free-standing draining film. The thickness of the soap film is then higher in the upper region than in the lower region of the film. Moreover, the lifetime of the film is dramatically increased by a factor of 2. Since the laser beam only acts mechanically on the film interfaces, such a film can be employed in an optofluidic diaphragm pump, the interfaces behaving like a vibrating membrane and the liquid in-between being the fluid to be pumped. Such a pump could then be used in delicate micro-equipment, in chips where temperature variations are detrimental and even in biological systems. PMID:25017934

  19. Laser induced breakdown spectroscopy for the discrimination of Candida strains.

    PubMed

    Manzoor, S; Ugena, L; Tornero-Lopéz, J; Martín, H; Molina, M; Camacho, J J; Cáceres, J O

    2016-08-01

    The present study reports the evaluation of Laser Induced Breakdown Spectroscopy (LIBS) and Neural Networks (NN) for the discrimination of different strains of various species of Candida. This genus of yeast was selected due to its medical relevance as it is commonly found in cases of fungal infection in humans. Twenty one strains belonging to seven species of Candida were included in the study. Scanning Electron Microscopy with Energy-Dispersive X-ray Spectroscopy (SEM-EDS) was employed as a complementary technique to provide information about elemental composition of Candida cells. The use of LIBS spectra in combination with optimized NN models provided reliable discrimination among the distinct Candida strains with a high spectral correlation index for the samples analyzed, without any false positive or false negative. Therefore, this study indicates that LIBS-NN based methodology has the potential to be used as fast fungal identification or even diagnostic method. PMID:27216662

  20. Microfabrication of Fresnel zone plates by laser induced solid ablation

    NASA Astrophysics Data System (ADS)

    Rodrigues, Vanessa R. M.; Thomas, John; Santhosh, Chidangil; Ramachandran, Hema; Mathur, Deepak

    2016-07-01

    A novel and simple single-step method of inscribing optical elements on metal-coated transparent substrates is demonstrated. Laser induced solid ablation (LISA) demands very low laser energies (nJ), as can be amply provided by a femtosecond laser oscillator. Here, LISA is used to write Fresnel zone plates on indium and tungsten coated glass. With up to 100 zones, remarkable agreement is obtained between measured and expected values of the focal length. LISA has enabled attainment of focal spot sizes that are 38% smaller than what would be obtained using conventional lenses of the same numerical aperture. The simplicity with which a high degree of automation can readily be achieved using LISA makes this cost-effective method amenable to a wide variety of applications related to microfabrication of optical elements.

  1. Application of the method of laser-induced fluorescence

    NASA Astrophysics Data System (ADS)

    Fateeva, Natalia L.; Matvienko, Gennadii G.

    2004-02-01

    Great attention is now paid to ecology of the environment, in whic plants are of great importance. However the present methods of biophysical analysis of plant states are very labor-intensive and require a lot of time. The structure of protein-pigment complexes is known to break in different dissolvents that results in the shift of maxima of chlorophyll absorption and fluorescence bands. That is why development of methods for remote diagnostics of plants is of great scientific and practical interest. They would make it possible to determine species and state of plants rather quickly and accurately. We have developed a setup and methods for optical diagnostics of the physiological state of plants to investigate the dynamics of the fastest part of fluorescence of plants in vivo. The method of laser-induced fluorescence makes it possible to observe the level of vegetative development of living plants, as well as their state under the impact of some stress factors.

  2. Combined Endoscopic Optical Coherence Tomography and Laser Induced Fluorescence

    NASA Astrophysics Data System (ADS)

    Barton, Jennifer K.; Tumlinson, Alexandre R.; Utzinger, Urs

    Optical coherence tomography (OCT) and laser-induced fluorescence (LIF) are promising modalities for tissue characterization in human patients and animal models. OCT detects coherently backscattered light, whereas LIF detects fluorescence emission of endogenous biochemicals, such as reduced nicotinamide adenine dinucleotide (NADH), flavin adenine dinucleotide (FAD), collagen, and fluorescent proteins, or exogenous substances such as cyanine dyes. Given the complementary mechanisms of contrast for OCT and LIF, the combination of the two modalities could potentially provide more sensitive and specific detection of disease than either modality alone. Sample probes for both OCT and LIF can be implemented using small diameter optical fibers, suggesting a particular synergy for endoscopic applications. In this chapter, the mechanisms of contrast and diagnostic capability for both OCT and LIF are briefly examined. Evidence of complementary capability is described. Example published combined OCT-LIF systems are reviewed, one successful commercial instrument is discussed, and example applications are provided.

  3. Femtosecond laser-induced surface structures on carbon fibers.

    PubMed

    Sajzew, Roman; Schröder, Jan; Kunz, Clemens; Engel, Sebastian; Müller, Frank A; Gräf, Stephan

    2015-12-15

    The influence of different polarization states during the generation of periodic nanostructures on the surface of carbon fibers was investigated using a femtosecond laser with a pulse duration τ=300  fs, a wavelength λ=1025  nm, and a peak fluence F=4  J/cm². It was shown that linear polarization results in a well-aligned periodic pattern with different orders of magnitude concerning their period and an alignment parallel and perpendicular to fiber direction, respectively. For circular polarization, both types of uniform laser-induced periodic surface structures (LIPSS) patterns appear simultaneously with different dominance in dependence on the position at the fiber surface. Their orientation was explained by the polarization-dependent absorptivity and the geometrical anisotropy of the carbon fibers. PMID:26670499

  4. Laser-induced breakdown spectroscopy analysis of energetic materials

    NASA Astrophysics Data System (ADS)

    de Lucia, Frank C.; Harmon, Russell S.; McNesby, Kevin L.; Winkel, Raymond J.; Miziolek, Andrzej W.

    2003-10-01

    A number of energetic materials and explosives have been studied by laser-induced breakdown spectroscopy (LIBS). They include black powder, neat explosives such as TNT, PETN, HMX, and RDX (in various forms), propellants such as M43 and JA2, and military explosives such as C4 and LX-14. Each of these materials gives a unique spectrum, and generally the spectra are reproducible shot to shot. We observed that the laser-produced microplasma did not initiate any of the energetic materials studied. Extensive studies of black powder and its ingredients by use of a reference spectral library have demonstrated excellent accuracy for unknown identification. Finally, we observed that these nitrogen- and oxygen-rich materials yield LIBS spectra in air that have correspondingly different O:N peak ratios compared with air. This difference can help in the detection and identification of such energetic materials.

  5. Enhancing Laser Induced Plasma Emissions using Various Excitation Modalities

    NASA Astrophysics Data System (ADS)

    Johnson, Lewis; Akpovo, Charlemagne; Gebreegziabher, Samson; Martinez, Jorge, Jr.

    2008-11-01

    Detection of hazardous materials with Laser Induced Breakdown Spectroscopy (LIBS) requires a detailed understanding of the sample matrix as well as the surrounding environment. We report on our efforts to understand and manipulate the continuum and atmospheric levels while enhancing surface and substrate material identifications. Comparisons are made between: single pulse (SP) nanosecond (ns); SP femtosecond (fs); SP fs-self-channeled (fs-sc); Dual pulse (DP) ns; DP ns -- fs; and DP ns fs-sc; and multi--pulse Continuous Wave (CW) plasmas formed on the sample surface. Plasma emission spectra from atmospheric oxygen and nitrogen, as well as aluminum and Copper substrates, and hazardous oxygen and nitrogen rich materials residues are analyzed.

  6. Optically Probed Laser-Induced Field-Free Molecular Alignment

    NASA Astrophysics Data System (ADS)

    Faucher, O.; Lavorel, B.; Hertz, E.; Chaussard, F.

    Molecular alignment induced by laser fields has been investigated in research laboratories for over two decades. It led to a better understanding of the fundamental processes at play in the interaction of strong laser fields with molecules, and also provided significant contributions to the fields of high harmonic generation, laser spectroscopy, and laser filamentation. In this chapter, we discuss molecular alignment produced under field-free conditions, as resulting from the interaction of a laser pulse of duration shorter than the rotational period of the molecule. The experimental results presented will be confined to the optically probed alignment of linear as well as asymmetric top molecules. Special care will be taken to describe and compare various optical methods that can be employed to characterize laser-induced molecular alignment. Promising applications of optically probed molecular alignment will be also demonstrated.

  7. Development of Isotope Analysis Based on Laser Induced Fluorescence

    SciTech Connect

    Sakai, T.; Watanabe, K.; Uritani, A.; Tomita, H.; Iguchi, T.

    2009-03-17

    We have proposed Laser Induced Fluorescence analysis using Doppler Shift of laser ablated atoms for Isotope Analysis (LIF-DS-IA). This isotope analysis is expected to have a small mass discrimination effect because the detection target is fluorescence photons instead of ions, which distort the measured isotope ratio by the space charge effect. We demonstrate this technique to be feasible through the model calculations. We experimentally confirmed the fundamental behavior in LIF-DS-IA that the shift in the irradiating laser frequency corresponds to that of peak position in the time domain LIF spectra. The reason of poor mass resolution in the present system was considered to be inadequate definition in the field of view of the fluorescence detector.

  8. Laser-induced thermal acoustics (LITA) signals from finite beams

    NASA Astrophysics Data System (ADS)

    Cummings, E. B.; Leyva, I. A.; Hornung, H. G.

    1995-06-01

    Laser-induced thermal acoustics (LITA) is a four-wave mixing technique that may be employed to measure sound speeds, transport properties, velocities, and susceptibilities of fluids. It is particularly effective in high-pressure gases ( greater than 1 bar). An analytical expression for LITA signals is derived by the use of linearized equations of hydrodynamics and light scattering. This analysis, which includes full finite-beam-size effects and the optoacoustic effects of thermalization and electrostriction, predicts the amplitude and the time history of narrow-band time-resolved LITA and broadband spectrally resolved (mulitplex) LITA signals. The time behavior of the detected LITA signal depends significantly on the detection solid angle, with implications for the measurement of diffusivities by the use of LITA and the proper physical picture of LITA scattering. This and other elements of the physics of LITA that emerge from the analysis are discussed. Theoretical signals are compared with experimental LITA data.

  9. Neural network data analysis for laser-induced thermal acoustics

    NASA Astrophysics Data System (ADS)

    Schlamp, Stefan; Hornung, Hans G.; Cummings, Eric B.

    2000-06-01

    A general, analytical closed-form solution for laser-induced thermal acoustic (LITA) signals using homodyne or heterodyne detection and using electrostrictive and thermal gratings is derived. A one-hidden-layer feed-forward neural network is trained using back-propagation learning and a steepest descent learning rule to extract the speed of sound and flow velocity from a heterodyne LITA signal. The effect of the network size on the performance is demonstrated. The accuracy is determined with a second set of LITA signals that were not used during the training phase. The accuracy is found to be better than that of a conventional frequency decomposition technique while being computationally as efficient. This data analysis method is robust with respect to noise, numerically stable and fast enough for real-time data analysis.

  10. Terahertz generation in multiple laser-induced air plasmas

    SciTech Connect

    Chen, M.-K.; Kim, Jae Hun; Yang, C.-E.; Yin, Stuart Shizhuo; Hui Rongqing; Ruffin, Paul

    2008-12-08

    An investigation of the terahertz wave generation in multiple laser-induced air plasmas is presented. First, it is demonstrated that the intensity of the terahertz wave increases as the number of air plasmas increases. Second, the physical mechanism of this enhancement effect of the terahertz generation is studied by quantitatively measuring the intensity of the generated terahertz wave as a function of phase difference between adjacent air plasmas. It is found out that the superposition is the main mechanism to cause this enhancement. Thus, the results obtained in this paper not only provide a technique to generate stronger terahertz wave but also enable a better understanding of the mechanism of the terahertz generation in air plasma.

  11. Elemental Analysis of Soils by Laser Induced Breakdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    Gondal, Mohammed Ashraf; Dastageer, Mohamed A.

    The chemical and elemental composition of soil is very complex as it contains many constituents like minerals, organic matters, living organisms, fossils, air and water. Considering the diversity of soil contents, quality and usability, a systematic scientific study on the elemental and chemical composition of soil is very important. In order to study the chemical composition of soil, Laser induced breakdown spectroscopy (LIBS) has been applied recently. The important features of LIBS system and its applications for the measurement of nutrients in green house soil, on-line monitoring of remediation process of chromium polluted soil, determination of trace elements in volcanic erupted soil samples collected from ancient cenozoic lava eruption sites and detection of toxic metals in Gulf war oil spill contaminated soil using LIBS are described in this chapter.

  12. Laser-induced breakdown spectroscopy analysis of energetic materials.

    PubMed

    De Lucia, Frank C; Harmon, Russell S; McNesby, Kevin L; Winkel, Raymond J; Miziolek, Andrzej W

    2003-10-20

    A number of energetic materials and explosives have been studied by laser-induced breakdown spectroscopy (LIBS). They include black powder, neat explosives such as TNT, PETN, HMX, and RDX (in various forms), propellants such as M43 and JA2, and military explosives such as C4 and LX-14. Each of these materials gives a unique spectrum, and generally the spectra are reproducible shot to shot. We observed that the laser-produced microplasma did not initiate any of the energetic materials studied. Extensive studies of black powder and its ingredients by use of a reference spectral library have demonstrated excellent accuracy for unknown identification. Finally, we observed that these nitrogen- and oxygen-rich materials yield LIBS spectra in air that have correspondingly different O:N peak ratios compared with air. This difference can help in the detection and identification of such energetic materials. PMID:14594077

  13. Laser induced fluorescence applied to turbulent reacting flows

    NASA Technical Reports Server (NTRS)

    Daily, J. W.

    1976-01-01

    The saturated fluorescence method makes use of the great simplifications which occur when under conditions of intense radiation the excitation process becomes saturated. A description is presented of the saturated fluorescence method, taking into account rate equations and saturation, radiative transfer, the two-level system, a multilevel system, and measurements under saturation conditions. The detectability limits of the method are investigated. Fluorescence trapping is found to place an upper limit on the number density of the fluorescing species that can be measured without signal loss. Turbulence places time and spatial constraints on the measurements, but otherwise poses no difficulties. Saturated laser induced fluorescence spectroscopy appears to be a most promising method for measuring species concentrations in flames.

  14. Laser-induced jet formation in liquid films

    NASA Astrophysics Data System (ADS)

    Brasz, Frederik; Arnold, Craig

    2014-11-01

    The absorption of a focused laser pulse in a liquid film generates a cavitation bubble on which a narrow jet can form. This is the basis of laser-induced forward transfer (LIFT), a versatile printing technique that offers an alternative to inkjet printing. We study the influence of the fluid properties and laser pulse energy on jet formation using numerical simulations and time-resolved imaging. At low energies, surface tension causes the jet to retract without transferring a drop, and at high energies, the bubble breaks up into a splashing spray. We explore the parameter space of Weber number, Ohnesorge number, and ratio of film thickness to maximum bubble radius, revealing regions where uniform drops are transferred.

  15. Flexible Boron-Doped Laser-Induced Graphene Microsupercapacitors.

    PubMed

    Peng, Zhiwei; Ye, Ruquan; Mann, Jason A; Zakhidov, Dante; Li, Yilun; Smalley, Preston R; Lin, Jian; Tour, James M

    2015-06-23

    Heteroatom-doped graphene materials have been intensely studied as active electrodes in energy storage devices. Here, we demonstrate that boron-doped porous graphene can be prepared in ambient air using a facile laser induction process from boric acid containing polyimide sheets. At the same time, active electrodes can be patterned for flexible microsupercapacitors. As a result of boron doping, the highest areal capacitance of as-prepared devices reaches 16.5 mF/cm(2), 3 times higher than nondoped devices, with concomitant energy density increases of 5-10 times at various power densities. The superb cyclability and mechanical flexibility of the device are well-maintained, showing great potential for future microelectronics made from this boron-doped laser-induced graphene material. PMID:25978090

  16. Dynamic response of shear thickening fluid under laser induced shock

    SciTech Connect

    Wu, Xianqian Yin, Qiuyun; Huang, Chenguang; Zhong, Fachun

    2015-02-16

    The dynamic response of the 57 vol./vol. % dense spherical silica particle-polyethylene glycol suspension at high pressure was investigated through short pulsed laser induced shock experiments. The measured back free surface velocities by a photonic Doppler velocimetry showed that the shock and the particle velocities decreased while the shock wave transmitted in the shear thickening fluid (STF), from which an equation of state for the STF was obtained. In addition, the peak stress decreased and the absorbed energy increased rapidly with increasing the thickness for a thin layer of the STF, which should be attributed to the impact-jammed behavior through compression of particle matrix, the deformation or crack of the hard-sphere particles, and the volume compression of the particles and the polyethylene glycol.

  17. OH Planar Laser-Induced Fluorescence from Microgravity Droplet Combustion

    NASA Technical Reports Server (NTRS)

    Winter, Michael; Wegge, Jason; Kang, Kyung-Tae

    1997-01-01

    Droplet combustion under microgravity conditions has been extensively studied, but laser diagnostics have just begun to be employed in microgravity droplet experiments. This is due in part to the level of difficulty associated with laser system size, power and economic availability. Hydroxyl radical (OH) is an important product of combustion, and laser-induced fluorescence (LIF) has proved to be an adequate and sensitive tool to measure OH. In this study, a frequency doubled Nd:YAG laser and a doubled dye laser, compact and reliable enough to perform OH PLIF experiments aboard a parabolic flight-path aircraft, has been developed and successfully demonstrated in a methanol droplet flame experiment. Application to microgravity conditions is planned aboard parabolic flight-path aircraft.

  18. Analysis of fresco by laser induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Caneve, L.; Diamanti, A.; Grimaldi, F.; Palleschi, G.; Spizzichino, V.; Valentini, F.

    2010-08-01

    The laser-based techniques have been shown to be a very powerful tool for artworks characterization and are used in the field of cultural heritage for the offered advantages of minimum invasiveness, in situ applicability and high sensitivity. Laser induced breakdown spectroscopy, in particular, has been applied in this field to many different kinds of ancient materials with successful results. In this work, a fragment of a Roman wall painting from the archaeological area of Pompeii has been investigated by LIBS. The sample elemental composition resulting from LIBS measurements suggested the presence of certain pigments. The ratio of the intensities of different lines related to some characteristic elements is proposed as an indicator for pigment recognition. The depth profiling permitted to put in evidence the presence of successive paint layers with different compositions. A comparison with the results obtained by the microscopy inspection of the sample has been done.

  19. Hydrogen retention in tungsten materials studied by Laser Induced Desorption

    NASA Astrophysics Data System (ADS)

    Zlobinski, M.; Philipps, V.; Schweer, B.; Huber, A.; Reinhart, M.; Möller, S.; Sergienko, G.; Samm, U.; 't Hoen, M. H. J.; Manhard, A.; Schmid, K.; Textor Team

    2013-07-01

    Development of methods to characterise the first wall in ITER and future fusion devices without removal of wall tiles is important to support safety assessments for tritium retention and dust production and to understand plasma wall processes in general. Laser based techniques are presently under investigation to provide these requirements, among which Laser Induced Desorption Spectroscopy (LIDS) is proposed to measure the deuterium and tritium load of the plasma facing surfaces by thermal desorption and spectroscopic detection of the desorbed fuel in the edge of the fusion plasma. The method relies on its capability to desorb the hydrogen isotopes in a laser heated spot. The application of LID on bulk tungsten targets exposed to a wide range of deuterium fluxes, fluences and impact energies under different surface temperatures is investigated in this paper. The results are compared with Thermal Desorption Spectrometry (TDS), Nuclear Reaction Analysis (NRA) and a diffusion model.

  20. Infrared Signatures of Laser Induced Plasma in Air

    NASA Astrophysics Data System (ADS)

    Hening, Alexandru; Lu, Ryan; Ramirez, Ayax; Advanced Technology Team

    2014-03-01

    Characterization of the temporal and spatial evolution of laser generated plasma in air is necessary for the development of potential applications which range from laser induced ionized micro channels and filaments able to transfer high electric pulses over few hundreds of meters, to the generation of plasma artifacts in air, far away from the laser source. This work is focused mainly on the infrared spectrum. The influence of laser parameters (energy per pulse, pulse duration, repetition rate, wavelength and etc.) on the plasma formation and evolution has been investigated. Laser transmission losses through the air as well as through the breakdown plasma as well as their effect on infrared plasma signature are to be presented.

  1. Laser-induced photo-thermal magnetic imaging

    NASA Astrophysics Data System (ADS)

    Thayer, David A.; Lin, Yuting; Luk, Alex; Gulsen, Gultekin

    2012-08-01

    Due to the strong scattering nature of biological tissue, optical imaging beyond the diffusion limit suffers from low spatial resolution. In this letter, we present an imaging technique, laser-induced photo-thermal magnetic imaging (PMI), which uses laser illumination to induce temperature increase in a medium and magnetic resonance imaging to map the spatially varying temperature, which is proportional to absorbed energy. This technique can provide high-resolution images of optical absorption and can potentially be used for small animal as well as breast cancer and lymph node imaging. First, we describe the theory of PMI, including the modeling of light propagation and heat transfer in tissue. We also present experimental data with corresponding predictions from theoretical models, which show excellent agreement.

  2. Laser-Induced Acoustic Desorption of Natural and Functionalized Biochromophores

    PubMed Central

    2015-01-01

    Laser-induced acoustic desorption (LIAD) has recently been established as a tool for analytical chemistry. It is capable of launching intact, neutral, or low charged molecules into a high vacuum environment. This makes it ideally suited to mass spectrometry. LIAD can be used with fragile biomolecules and very massive compounds alike. Here, we apply LIAD time-of-flight mass spectrometry (TOF-MS) to the natural biochromophores chlorophyll, hemin, bilirubin, and biliverdin and to high mass fluoroalkyl-functionalized porphyrins. We characterize the variation in the molecular fragmentation patterns as a function of the desorption and the VUV postionization laser intensity. We find that LIAD can produce molecular beams an order of magnitude slower than matrix-assisted laser desorption (MALD), although this depends on the substrate material. Using titanium foils we observe a most probable velocity of 20 m/s for functionalized molecules with a mass m = 10 000 Da. PMID:25946522

  3. Optical properties of laser-induced heavily doped Si

    NASA Astrophysics Data System (ADS)

    Ravindra, N. M.; Mhoronge, J. F.; Jouanne, M.

    1985-09-01

    An analysis of experimental studies (Slaoui et al., 1983) of the optical properties of laser-induced heavily doped Si layers is presented. The analysis has been made on the basis of models like those of Penn (1962) and Breckenridge et al. (1974). The calculations show that, in general, the effective number of electrons contributing to optically induced electronic transitions, increases as does the imaginary part of the complex dielectric constant. This reflects an increased absorption coefficient for these As-doped samples. These studies have been carried out on samples of Si heavily doped by ion-implantation followed by a laser-annealing process. The conclusions based on these studies are seen to be in accord with those of Aspnes et al. (1984) and Vina and Cardona (1984).

  4. Titanium monoxide spectroscopy following laser-induced optical breakdown

    NASA Astrophysics Data System (ADS)

    Parigger, Christian G.; Woods, Alexander C.; Keszler, Anna; Nemes, László; Hornkohl, James O.

    2012-07-01

    This work investigates Titanium Monoxide (TiO) in ablation-plasma by employing laser-induced breakdown spectroscopy (LIBS) with 1 to 10 TW/cm2 irradiance, pulsed, 13 nanosecond, Q-switched Nd:YAG laser radiation at the fundamental wavelength of 1064 nm. The analysis of TiO is based on our first accurate determination of transition line strengths for selected TiO A-X, B-X, and E-X transitions, particularly TiO A-X γ and B-X γ' bands. Electric dipole line strengths for the A3Φ-X3δ and B3Π-X3δ bands of TiO are computed. The molecular TiO spectra are observed subsequent to laser-induced breakdown (LIB). We discuss analysis of diatomic molecular spectra that may occur simultaneously with spectra originating from atomic species. Gated detection is applied to investigate the development in time of the emission spectra following LIB. Collected emission spectra allow one to infer micro-plasma parameters such as temperature and electron density. Insight into the state of the micro-plasma is gained by comparing measurements with predictions of atomic and molecular spectra. Nonlinear fitting of recorded and computed diatomic spectra provides the basis for molecular diagnostics, while atomic species may overlap and are simultaneously identified. Molecular diagnostic approaches similar to TiO have been performed for diatomic molecules such as AlO, C2, CN, CH, N2, NH, NO and OH.

  5. Experimental Studies of Laser-Induced Breakdown in Transparent Dielectrics

    SciTech Connect

    Carr, C W

    2003-09-23

    The mechanisms by which transparent dielectrics damage when exposed to high power laser radiation has been of scientific and technological interest since the invention of the laser. In this work, a set of three experiments are presented which provide insight into the damage initiation mechanisms and the processes involved in laser-induced damage. Using an OPO (optical parametric oscillator) laser, we have measured the damage thresholds of deuterated potassium dihydrogen phosphate (DKDP) from the near ultraviolet into the visible. Distinct steps, whose width is of order K{sub b}T, are observed in the damage threshold at photon energies associated with the number of photons (3{yields}2 or 4{yields}3) needed to promote a ground state electron across the energy gap. The wavelength dependence of the damage threshold suggests that a primary mechanism for damage initiation in DKDP is a multi-photon process in which the order is reduced through excited defect state absorption. In-situ fluorescence microscopy, in conjunction with theoretical calculations by Liu et al., has been used to establish that hydrogen displacement defects are potentially responsible for the reduction in the multi-photon cross-section. During the damage process, the material absorbs energy from the laser pulse and produces an ionized region that gives rise to broadband emission. By performing a time-resolved investigation of this emission, we demonstrate both that it is blackbody in nature, and we provide the first direct measurement of the localized temperature during and following laser damage initiation for various optical materials. For excitation using nanosecond laser pulses, the plasma, when confined in the bulk, is in thermal equilibrium with the lattice. These results allow for a detailed characterization of temperature, pressure, and electron densities occurring during laser-induced damage.

  6. Kr II laser-induced fluorescence for measuring plasma acceleration

    SciTech Connect

    Hargus, W. A. Jr.

    2012-10-15

    We present the application of laser-induced fluorescence of singly ionized krypton as a diagnostic technique for quantifying the electrostatic acceleration within the discharge of a laboratory cross-field plasma accelerator also known as a Hall effect thruster, which has heritage as spacecraft propulsion. The 728.98 nm Kr II transition from the metastable 5d{sup 4}D{sub 7/2} to the 5p{sup 4}P{sub 5/2}{sup Ring-Operator} state was used for the measurement of laser-induced fluorescence within the plasma discharge. From these measurements, it is possible to measure velocity as krypton ions are accelerated from near rest to approximately 21 km/s (190 eV). Ion temperature and the ion velocity distributions may also be extracted from the fluorescence data since available hyperfine splitting data allow for the Kr II 5d{sup 4}D{sub 7/2}-5p{sup 4}P{sub 5/2}{sup Ring-Operator} transition lineshape to be modeled. From the analysis, the fluorescence lineshape appears to be a reasonable estimate for the relatively broad ion velocity distributions. However, due to an apparent overlap of the ion creation and acceleration regions within the discharge, the distributed velocity distributions increase ion temperature determination uncertainty significantly. Using the most probable ion velocity as a representative, or characteristic, measure of the ion acceleration, overall propellant energy deposition, and effective electric fields may be calculated. With this diagnostic technique, it is possible to nonintrusively characterize the ion acceleration both within the discharge and in the plume.

  7. Discriminating crude oil grades using laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    El-Hussein, A.; Marzouk, A.; Harith, M. A.

    2015-11-01

    The analysis of crude oil using laser-based analytical techniques such as laser-induced breakdown spectroscopy (LIBS) has become of great interest to various specialists in different fields such as geology, petro-chemistry and environmental science. In this work, a detailed study is presented wherein the implementation of an efficient and simple LIBS technique to identify the elemental constituents of crude oil and to distinguish between different grades of petroleum crude oil is discussed. Laser-induced plasma (LIP) technique has been used in this work for direct measurements of atomic, ionic and molecular species in dry crude oil samples with API gravities ranging between 18 and 36. The technique was implemented using the first harmonic of a pulsed Nd-YAG laser source. Atomic and molecular emission bands were observed, consisting of characteristic spectral lines of atoms and diatomic molecular bands, namely from C, H, Si, Na, Ca, Mg, AL, Fe, Ti, Mo, C2 and CN. The intensities of high-resolution spectral lines for some atoms and molecules of elements such as Ca, Na, Fe, Mo, C2 and CN were evaluated at different wavelengths along the obtained spectra. The molecular bands and the elemental spectral lines were used to assess the possibility of adopting the LIBS technique in differentiating between crude oil samples with different American Petroleum Institute (API) gravity values. The results indicate the presence of a distinct correlation between the API gravity values of the various oil samples and the spectral line intensities of the elements and some molecular radical constituents. In addition, the possibility of identifying the API gravity values of unknown oil samples is also indicated.

  8. Biological effects of laser-induced stress waves

    SciTech Connect

    Doukas, A.; Lee, S.; McAuliffe, D.

    1995-12-31

    Laser-induced stress waves can be generated by one of the following mechanisms: Optical breakdown, ablation or rapid heating of an absorbing medium. These three modes of laser interaction with matter allow the investigation of cellular and tissue responses to stress waves with different characteristics and under different conditions. The most widely studied phenomena are those of the collateral damage seen in photodisruption in the eye and in 193 run ablation of cornea and skin. On the other hand, the therapeutic application of laser-induced stress waves has been limited to the disruption of noncellular material such as renal stones, atheromatous plaque and vitreous strands. The effects of stress waves to cells and tissues can be quite disparate. Stress waves can fracture tissue, damage cells, and increase the permeability of the plasma membrane. The viability of cell cultures exposed to stress waves increases with the peak stress and the number of pulses applied. The rise time of the stress wave also influences the degree of cell injury. In fact, cell viability, as measured by thymidine incorporation, correlates better with the stress gradient than peak stress. Recent studies have also established that stress waves induce a transient increase of the permeability of the plasma membrane in vitro. In addition, if the stress gradient is below the damage threshhold, the cells remain viable. Thus, stress waves can be useful as a means of drug delivery, increasing the intracellular drug concentration and allowing the use of drugs which are impermeable to the cell membrane. The present studies show that it is important to create controllable stress waves. The wavelength tunability and the micropulse structure of the free electron laser is ideal for generating stress waves with independently adjustable parameters, such as rise time, duration and peak stress.

  9. Sparking rates measured on the CRITS RFQ

    SciTech Connect

    Balleyguier, P.

    1998-05-28

    During the test of the LEDA injector on the CRITS RFQ, an automatic data acquisition system has been implemented. The purpose was to measure the sparking rate of this CW RFQ. The RF level has some influences on vacuum, but there is no evidence of any reciprocal effect. The raw sparking rate is very difficult to interpret, since burst of sparks bias the statistics. A more convenient and useful interpretation is the number of sparking seconds. At the nominal field level (1.75 Kilp), the sparking-second rate is 0.5 per minute without beam. It strongly depends on the field, with a logarithmic law: 4.5 decade/Kilp. With beam, the sparking rate jumps to 3.0 per minute. As far as tested, it depends neither on the beam current (20 to 80 mA) nor on the field (1.5 to 1.7 Kilp tested). With sparking rates as measured here, one could not hope to build an RFQ that would be free of sparks over a several months continuous operation. Such a requirement, based on an extrapolation of the curves presented here, would lead to a maximal electric field much lower than the Kilpatrick value, an unreasonable requirement for a functional RFQ. A conclusion is that a sparkless RFQ is hopeless, even with a very carefully conditioned cavity. It will probably be necessary to deal with a few sparks per day, and the linac must be able to restart automatically after a short beam interruption.

  10. Spark ignition systems for internal combustion engines

    SciTech Connect

    Gol, G.; Hill, W.F.

    1980-08-26

    An internal combustion engine spark ignition system is provided which ensures that sparks are inhibited if the engine temperature exceeds a maximum safe level. The ignition circuit includes an input transistor which is switched on and off by an engine shaft transducer. The input transistor controls charging and discharging of a capacitor the voltage on which determines whether switching of the input transistor causes a spark to be produced via an output amplifier and ignition coil. A temperature sensing element determines both the rate at which the capacitor can charge and the final voltage to which it can be charged.

  11. Vibrator improves spark erosion cutting process

    NASA Technical Reports Server (NTRS)

    Thrall, L. R.

    1966-01-01

    Variable frequency mechanical vibrator improves spark erosion cutting process. The vibration of the cutting tip permits continual flushing away of residue around the cut area with nondestructive electric transformer oil during the cutting process.

  12. Spark discharge trace element detection system

    DOEpatents

    Adler-Golden, Steven; Bernstein, Lawrence S.; Bien, Fritz

    1988-01-01

    A spark discharge trace element detection system is provided which includes a spark chamber including a pair of electrodes for receiving a sample of gas to be analyzed at no greater than atmospheric pressure. A voltage is provided across the electrodes for generating a spark in the sample. The intensity of the emitted radiation in at least one primary selected narrow band of the radiation is detected. Each primary band corresponds to an element to be detected in the gas. The intensity of the emission in each detected primary band is integrated during the afterglow time interval of the spark emission and a signal representative of the integrated intensity of the emission in each selected primary bond is utilized to determine the concentration of the corresponding element in the gas.

  13. Spark discharge trace element detection system

    DOEpatents

    Adler-Golden, S.; Bernstein, L.S.; Bien, F.

    1988-08-23

    A spark discharge trace element detection system is provided which includes a spark chamber including a pair of electrodes for receiving a sample of gas to be analyzed at no greater than atmospheric pressure. A voltage is provided across the electrodes for generating a spark in the sample. The intensity of the emitted radiation in at least one primary selected narrow band of the radiation is detected. Each primary band corresponds to an element to be detected in the gas. The intensity of the emission in each detected primary band is integrated during the afterglow time interval of the spark emission and a signal representative of the integrated intensity of the emission in each selected primary bond is utilized to determine the concentration of the corresponding element in the gas. 12 figs.

  14. Titian: Data Provenance Support in Spark

    PubMed Central

    Interlandi, Matteo; Shah, Kshitij; Tetali, Sai Deep; Gulzar, Muhammad Ali; Yoo, Seunghyun; Kim, Miryung; Millstein, Todd; Condie, Tyson

    2015-01-01

    Debugging data processing logic in Data-Intensive Scalable Computing (DISC) systems is a difficult and time consuming effort. Today’s DISC systems offer very little tooling for debugging programs, and as a result programmers spend countless hours collecting evidence (e.g., from log files) and performing trial and error debugging. To aid this effort, we built Titian, a library that enables data provenance—tracking data through transformations—in Apache Spark. Data scientists using the Titian Spark extension will be able to quickly identify the input data at the root cause of a potential bug or outlier result. Titian is built directly into the Spark platform and offers data provenance support at interactive speeds—orders-of-magnitude faster than alternative solutions—while minimally impacting Spark job performance; observed overheads for capturing data lineage rarely exceed 30% above the baseline job execution time. PMID:26726305

  15. Laser induced damage of fused silica polished optics due to a droplet forming organic contaminant.

    PubMed

    Bien-Aimé, Karell; Néauport, Jérome; Tovena-Pecault, Isabelle; Fargin, Evelyne; Labrugère, Christine; Belin, Colette; Couzi, Michel

    2009-04-20

    We report on the effect of organic molecular contamination on single shot laser induced damage density at the wavelength of 351 nm, with a 3 ns pulse length. Specific contamination experiments were made with dioctylphthalate (DOP) in liquid or gaseous phase, on the surface of fused silica polished samples, bare or solgel coated. Systematic laser induced damage was observed only in the case of liquid phase contamination. Different chemical and morphological characterization methods were used to identify and understand the damage process. We demonstrate that the contaminant morphology, rather than its physicochemical nature, can be responsible for the decrease of laser induced damage threshold of optics. PMID:19381171

  16. Theoretical analysis for temperature dependence of laser- induced damage threshold of optical thin films

    NASA Astrophysics Data System (ADS)

    Mikami, K.; Motokoshi, S.; Somekawa, T.; Jitsuno, T.; Fujita, M.; Tanaka, KA; Azechi, H.

    2016-03-01

    The temperature dependence of the laser-induced damage threshold on optical coatings was studied in detail for laser pulses from 123 K to 473 K at different temperatures. The laser-induced damage threshold increased with decreasing temperatures when we tested long pulses (200 ps and 4 ns). The temperature dependence, however, was reversed for pulses shorter than a few picoseconds (100 fs testing). We propose a scaling model with a flowchart that includes three separate processes: free-electron generation, electron multiplication, and electron heating. Furthermore, we calculated the temperature dependence of laser-induced damage thresholds at different temperatures. Our calculation results agreed well with the experimental results.

  17. Resistance of a water spark.

    SciTech Connect

    Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Lehr, Jane Marie

    2005-11-01

    The later time phase of electrical breakdown in water is investigated for the purpose of improving understanding of the discharge characteristics. One dimensional simulations in addition to a zero dimensional lumped model are used to study the spark discharge. The goal is to provide better electrical models for water switches used in the pulse compression section of pulsed power systems. It is found that temperatures in the discharge channel under representative drive conditions, and assuming small initial radii from earlier phases of development, reach levels that are as much as an order of magnitude larger than those used to model discharges in atmospheric gases. This increased temperature coupled with a more rapidly rising conductivity with temperature than in air result in a decreased resistance characteristic compared to preceding models. A simple modification is proposed for the existing model to enable the approximate calculation of channel temperature and incorporate the resulting conductivity increase into the electrical circuit for the discharge channel. Comparisons are made between the theoretical predictions and recent experiments at Sandia. Although present and past experiments indicated that preceding late time channel models overestimated channel resistance, the calculations in this report seem to underestimate the resistance relative to recent experiments. Some possible reasons for this discrepancy are discussed.

  18. Electro-spark deposition technology

    SciTech Connect

    Johnson, R.N.

    1997-12-01

    Electro-Spark Deposition (ESD) is a micro-welding process that uses short duration, high-current electrical pulses to deposit or alloy a consumable electrode material onto a metallic substrate. The ESD process was developed to produce coatings for use in severe environments where most other coatings fail. Because of the exceptional damage resistance of these coatings, and the versatility of the process to apply a wide variety of alloys, intermetallics, and cermets to metal surfaces, the ESD process has been designated critical to the life and economy of the advanced fossil energy systems as the higher temperatures and corrosive environments exceed the limits of known structural materials to accommodate the service conditions. Developments include producing iron aluminide-based coatings with triple the corrosion resistance of the best previous Fe{sub 3}Al coatings, coatings with refractory metal diffusion barriers and multi layer coatings for achieving functionally gradient properties between the substrate and the surface. A new development is the demonstration of advanced aluminide-based ESD coatings for erosion and wear applications. One of the most significant breakthroughs to occur in the last dozen years is the discovery of a process regime that yields an order of magnitude increase in deposition rates and achievable coating thicknesses. Achieving this regime has required the development of advanced ESD electronic capabilities. Development is now focused on further improvements in deposition rates, system reliability when operating at process extremes, and economic competitiveness.

  19. Development of laser induced breakdown spectroscopy instrumentatin for safeguards applications

    SciTech Connect

    Barefield Il, James E; Clegg, Samuel M; Le, Loan A; Lopez, Leon N

    2010-01-01

    In September 2006, a Technical Meeting on Application of Laser Spectrometry Techniques in IAEA Safeguards was held at IAEA headquarters (HQ). One of the principal recommendations from this meeting was the need to 'pursue the development of novel complementary access instrumentation based on laser induced breakdown spectroscopy (LIBS) for the detection of gaseous and solid signatures and indicators of nuclear fuel cycle processes and associated materials.' Pursuant to this recommendation the Department of Safeguards (SG) under the Division of Technical Support (SGTS) convened the Experts and Users Advisory Meeting on Laser Induced Breakdown Spectroscopy (LIBS) for Safeguards Applications. This meeting was held at IAEA HQ from July 7-11,2008 and hosted by the Novel Technologies Unit (NTU). The meeting was attended by 12 LIBS experts from the Czech Republic, the European Commission, France, the Republic of Korea, the United States of America, Germany, the United Kingdom of Great Britain, Canada, and Northern Ireland. After a presentation of the needs of the IAEA inspectors, the LIBS experts were in agreement that needs as presented could be partially or fully fulfilled using LIBS instrumentation. The needs of the IAEA inspectors were grouped in the following broad categories: (1) Improvements to in-field measurements/environmental sampling; (2) Monitoring status of activity in a Hot Cell; (3) Verifying status of activity at a declared facility via process monitoring; and (4) Need for pre-screening of environmental samples before analysis. Under the Department of Energy/National Nuclear Security Administration (DOE/NNSA) Next Generation Safeguards Initiative (NGSI) Los Alamos National Laboratory is exploring three potential applications of LIBS for international safeguards. As part of this work, we are developing: (1) a user-friendly man-portable LIBS system to characterize samples across a wide range of elements in the periodic table from hydrogen up to heavy elements

  20. Laser-induced incandescence measurements of particles in aeroengine exhausts

    NASA Astrophysics Data System (ADS)

    Black, John D.

    1999-09-01

    Laser Induced Incandescence (LII) has been demonstrated as a non-intrusive technique for measurement of particle concentration in the exhausts of aero-engines on sea level test beds as part of a European Union collaborative program (AEROJET) aimed at replacing gas sampling rakes behind development engines with non-intrusive instrumentation. Currently emissions of CO, NOx, unburned hydrocarbon, and smoke from aero-engines must be shown to be less than internationally specified limits. Measurements are made on development engines on sea level test beds by applying a number of standard analytical methods to extracted exhaust gas samples. The hardware required for exhaust gas sampling is heavy and complex and is expensive to build and install. As a result, only the minimum number of emissions tests are conducted during an engine development program, and emissions data is only available to combustion engineers late in the program. Hence, there is a need for more versatile and less costly non-intrusive measurement techniques. Molecular species can be measured using Fourier Transform Infrared (FTIR) spectroscopy, while LII is a promising smoke measuring technique. The development of an LII system specifically designed for exhaust applications is described.

  1. Laser-induced surface modification and metallization of polymers

    NASA Astrophysics Data System (ADS)

    Frerichs, Hartmut; Wesner, David A.; Kreutz, Ernst-Wolfgang

    1995-04-01

    Laser-induced surface modification of various polymers is presented as a suitable pretreatment of surfaces in a two-step metallization process. Materials such as polyamide (PA), polypropylene (PP), polystyrene (PS), polycarbonate (PC), acrylbutadienestyrene (ABS), styreneacrylnitril (SAN), polybutadieneterphtalate (PBT), and polyoxymethylen (POM) were treated by excimer laser radiation ((lambda) equals 248 nm) in air. The aim of this study is to investigate different processing regimes of surface modification. Therefore the laser processing variables fluence F, repetition rate v and pulse number N are varied and the absorption coefficient, optical penetration depth, ablation depth and ablation threshold are determined. The surface morphology and surface roughness are studied by optical surface profilometry and secondary electron microscopy (SEM). The influence of laser treatment on chemical composition of modified and ablated surfaces is analyzed by X-ray photoelectron spectroscopy (XPS). Depending on the processing parameters and materials properties different microstructures and values of surface roughness are generated on the micrometer length scale. Pretreatment for the subsequent metallization is performed with laser radiation, wet chemical and plasma etching. The metallization of polymers is investigated for different surface morphologies. The used metallization processes are electroplating and physical vapor deposition (PVD). Adhesion of the deposited films, measured with scratch and tape test methods, is used as a criterion for determining regimes of suitable surface modification for subsequent metallization.

  2. Electrodes for microfluidic devices produced by laser induced forward transfer

    NASA Astrophysics Data System (ADS)

    Germain, Chris; Charron, Luc; Lilge, Lothar; Tsui, Ying Y.

    2007-07-01

    The laser induced forward transfer (LIFT) process was used to create conductive lines and pads for rapid prototyping and repairing microdevices. Single 0.1-10 μJ pulses from a 120 fs 800 nm titanium:sapphire laser were used to transfer films consisting of 40-80 nm thick gold to create the lines. Experiments were conducted in air ambient. The laser was focused using 4× and 10× microscope objectives and produced 5-20 μm diameter metal spots which were overlapped to produce conductive lines. Electrodes with widths between 10 and 50 μm have been produced and their resistances have been measured. The resistivities of these LIFT produced Au electrodes were found to be approximately (1-4) × 10 -6 Ω m. It has also been shown that the conductivity of the lines can be further improved by electrical curing. The LIFT process was used to repair heaters for microfluidic applications and preliminarily create electrodes for control of electro-osmotic flow in microfluidic devices.

  3. Laser-induced breakdown plasma-based sensors

    NASA Astrophysics Data System (ADS)

    Griffin, Steven T.

    2010-04-01

    Laser Induced Breakdown Spectroscopy (LIBS) is dependent on the interaction between the initiating Laser sequence, the sampled material and the intermediate plasma states. Pulse shaping and timing have been empirically demonstrated to have significant impact on the signal available for active/passive detection and identification. The transient nature of empirical LIBS work makes data collection for optimization an expensive process. Guidance from effective computer simulation represents an alternative. This computational method for CBRNE sensing applications models the Laser, material and plasma interaction for the purpose of performance prediction and enhancement. This paper emphasizes the aspects of light, plasma, and material interaction relevant to portable sensor development for LIBS. The modeling structure emphasizes energy balances and empirical fit descriptions with limited detailed-balance and finite element approaches where required. Dusty plasma from partially decomposed material sample interaction with pulse dynamics is considered. This heuristic is used to reduce run times and computer loads. Computer simulations and some data for validation are presented. A new University of Memphis HPC/super-computer (~15 TFLOPS) is used to enhance simulation. Results coordinated with related effort at Arkansas State University. Implications for ongoing empirical work are presented with special attention paid to the application of compressive sensing for signal processing, feature extraction, and classification.

  4. Femtosecond laser-induced periodic surface structures on silica

    SciTech Connect

    Hoehm, S.; Rosenfeld, A.; Krueger, J.; Bonse, J.

    2012-07-01

    The formation of laser-induced periodic surface structures (LIPSS) on two different silica polymorphs (single-crystalline synthetic quartz and commercial fused silica glass) upon irradiation in air with multiple linearly polarized single- and double-fs-laser pulse sequences ({tau} = 150 fs pulse duration, {lambda} = 800 nm center wavelength, temporal pulse separation {Delta}t < 40 ps) is studied experimentally and theoretically. Two distinct types of fs-LIPSS [so-called low-spatial-frequency LIPSS (LSFL) and high-spatial-frequency LIPSS (HSFL)] with different spatial periods and orientations were identified. Their appearance was characterized with respect to the experimental parameters peak laser fluence and number of laser pulses per spot. Additionally, the 'dynamics' of the LIPSS formation was addressed in complementary double-fs-pulse experiments with varying delays, revealing a characteristic change of the LSFL periods. The experimental results are interpreted on the basis of a Sipe-Drude model considering the carrier dependence of the optical properties of fs-laser excited silica. This new approach provides an explanation of the LSFL orientation parallel to the laser beam polarisation in silica - as opposed to the behaviour of most other materials.

  5. Laser-induced autofluorescence study of caries model in vitro.

    PubMed

    Borisova, Ekaterina; Uzunov, Tzonko; Avramov, Latchezar

    2006-04-01

    Laser-induced autofluorescence spectra of teeth irradiated by a 337 nm nitrogen laser were measured during in vitro caries formation through initial enamel demineralization and introducing of carious bacterial flora in the lesions developed. Spectra obtained from sound teeth consist of an intensive maximum at 480-500 nm and secondary maximum at 430-450 nm. In the process of caries formation, we observed an increase in the intensity at 430-450 nm and the appearance of two maxima in the red spectral region-at 590-650 nm. The intensity increase at 430-450 nm was related to the tooth demineralization. Bacteria presence and their metabolism products induced an increase in the absorption in the UV-blue spectral region at 350-420 nm and the appearance of a fluorescence signal in the long-wave spectral region at 590-650 nm. From the point of view of tissue optics, these results allow caries to be considered as consisting of two different phenomena-tissue destruction and bacterial flora and its metabolism products increase. The results could be used to obtain a more complete picture of caries formation on the base of its fluorescent properties. PMID:16568211

  6. Future Development for Laser-Induced Thermal Acoustics

    NASA Astrophysics Data System (ADS)

    Schlamp, Stefan

    2002-07-01

    The development of novel flow diagnostic techniques typically proceeds in certain stages from a proof of principle in a laboratory to a commercial product either for use in industry or as turn-key research tool. While the first usable versions are brought to market, further progress is made in the laboratory by improvements, refinements, and extensions of the technique. Consider Particle Image Velocimetry (PIV), which started by double-exposing a photographic film with the image of an illuminated particle-laden flow and where today turn-key, off-the-shelf CCD systems are available for purchase, which include the necessary data analysis software. At the same time, 3d PIV, dual-plane PIV, Doppler Global Velocimetry (DGV), etc. are being used in laboratories and will doubtless be available as integrated systems in the near future. In this paper, the origin, an overview over the current status and an outlook on the future potential of Laser-Induced Thermal Acoustics (LITA) will be given, where the focus will be on the possible technique extensions to other than the current applications. As such, it represents a collection of ideas and avenues for future research, which have not been applied as of yet, but are conceptually feasible.

  7. Drift mechanism of laser-induced electron acceleration in vacuum

    NASA Astrophysics Data System (ADS)

    Morgovsky, L.

    2015-12-01

    Laser-induced electron acceleration in vacuum is possible due to the ejection of electrons from the beam as a consequence of the transverse drift orthogonal to the propagation direction. The transverse drift is derived from the general solution of the equations of motion of the electrons in the field of a plane electromagnetic wave with arbitrary polarization. It is shown that the energy gain is proportional to the square of the field strength additionally modulated by the function of the injection and ejection phases. In particular, for a linearly polarized beam this function is reduced to the squared difference between the cosines of these phases. The finite laser pulse duration restricts the range of the field strength suitable for direct electron acceleration in vacuum within certain limits. It is demonstrated that the high efficiency of energy transfer from the laser wave into the kinetic energy of the accelerated electrons demands phase matching between the electron quiver phase at the exit point and the phase of the energy transfer.

  8. Construction of a Laser Induced Breakdown Spectroscopy Setup

    NASA Astrophysics Data System (ADS)

    Mays, Joseph; Palmer, Andria; Amos, James; Dynka, Tom; Ujj, Lazlo

    Laser Induced Breakdown Spectroscopy (LIBS) is a practical spectroscopy to determine the chemical and atomic composition of materials. The third harmonic output of a Nd:YAG Q-switched laser generating 5ns pulses with 10Hz repetition rate was used to ablate the sample and create a micro-plasma. The emission of the radiating plasma was focused into an optical fiber with 0.22 numerical aperture. The spectra was measured with an Ocean Optics micro spectrometer. A synchronized shutter was used to select single laser pulses. In order to reach the breakdown threshold of the sample using the available energy of the laser pulses (<5 mJ) a beam expander and a parabolic mirror was used for tight focusing. The optical and technical details including the characterization of the system will be presented. LIBS spectra taken from a variety of metal and organic samples show appropriate selectivity for quantitative and qualitative analysis for materials. UWF NIH MARC U-STAR 1T34GM110517-01, UWF Office of Undergraduate Research.

  9. Analysis of human nails by laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Hosseinimakarem, Zahra; Tavassoli, Seyed Hassan

    2011-05-01

    Laser-induced breakdown spectroscopy (LIBS) is applied to analyze human fingernails using nanosecond laser pulses. Measurements on 45 nail samples are carried out and 14 key species are identified. The elements detected with the present system are: Al, C, Ca, Fe, H, K, Mg, N, Na, O, Si, Sr, Ti as well as CN molecule. Sixty three emission lines have been identified in the spectrum that are dominated by calcium lines. A discriminant function analysis is used to discriminate among different genders and age groups. This analysis demonstrates efficient discrimination among these groups. The mean concentration of each element is compared between different groups. Correlation between concentrations of elements in fingernails is calculated. A strong correlation is found between sodium and potassium while calcium and magnesium levels are inversely correlated. A case report on high levels of sodium and potassium in patients with hyperthyroidism is presented. It is shown that LIBS could be a promising technique for the analysis of nails and therefore identification of health problems.

  10. Laser-induced incandescence applied to dusty plasmas

    NASA Astrophysics Data System (ADS)

    van de Wetering, F. M. J. H.; Oosterbeek, W.; Beckers, J.; Nijdam, S.; Kovačević, E.; Berndt, J.

    2016-07-01

    This paper reports on the laser heating of nanoparticles (diameters ≤slant 1 μm) confined in a reactive plasma by short (150 ps) and intense (∼ 63 mJ) UV (355 nm) laser pulses (laser-induced incandescence, LII). Important parameters such as the particle temperature and radius follow from analysis of the emission spectrum of the heated nanoparticles. The nanoparticles are not ideal black bodies, which is taken into account by calculating their emissivity using a light-scattering theory relevant to our conditions (Mie theory). Three sets of refractive index data from the literature serve as model input. The obtained radii range between 100 and 165 nm, depending on the choice of refractive index data set. By fitting the temperature decay of the particles to a heat exchange model, the product of their mass density and specific heat is determined as (1.3+/- 0.5) J K‑1 cm‑3, which is considerably smaller than the value for bulk graphite at the temperature our particles attain (3000 K): 4.8 J K‑1 cm‑3. The particle sizes obtained in situ with LII are compared with ex situ scanning electron microscopy analysis of collected particles. Quantitative assessment of the LII measurements is hampered by transport of particles in the plasma volume and the fact that LII probes locally, whereas the samples with collected particles have a more global character.

  11. Laser-induced fluorescence for discrimination of crops and weeds

    NASA Astrophysics Data System (ADS)

    Hilton, Peter J.

    2000-11-01

    This paper reports the use of Laser Induced Fluorescence (LIF) of plants to discriminate between crops and weeds for potential use in an intelligent crop spraying system. Past and current work in intelligent crop spraying has concentrated on using multi-spectral reflectance data in particular using near infrared (NIR) and color. Texture and shape image processing has also been used with limited success and is usually computationally expensive. Also, most of these approaches are error prone since they rely on ambient solar illumination and so are susceptible to errors caused by cloud variations, shadows and other non-uniformities. There are several commercial spraying systems available that detect presence or absence of plants using the NIR 'red-edge' effect without discrimination between species. 'Weedseeker' and 'Detectspray' are two examples of such systems, the 'Weedseeker' system being one of the few active systems, incorporating its own light source. However, both systems suffer from poor spatial resolution. The use of plant or chlorophyll fluorescence for discrimination between species is a relatively under researched area. This paper shows that LIF of several crops and weeds can be used to discriminate between species. Spectra are presented for two crop and two weed species over a range of discrete laser excitation wavelengths. The technique can be directly implemented with a laser imaging system for real-time detection and discrimination of crops and weeds.

  12. Laser-induced Forward Transfer of Ag Nanopaste

    PubMed Central

    Breckenfeld, Eric; Kim, Heungsoo; Auyeung, Raymond C. Y.; Piqué, Alberto

    2016-01-01

    Over the past decade, there has been much development of non-lithographic methods1-3 for printing metallic inks or other functional materials. Many of these processes such as inkjet3 and laser-induced forward transfer (LIFT)4 have become increasingly popular as interest in printable electronics and maskless patterning has grown. These additive manufacturing processes are inexpensive, environmentally friendly, and well suited for rapid prototyping, when compared to more traditional semiconductor processing techniques. While most direct-write processes are confined to two-dimensional structures and cannot handle materials with high viscosity (particularly inkjet), LIFT can transcend both constraints if performed properly. Congruent transfer of three dimensional pixels (called voxels), also referred to as laser decal transfer (LDT)5-9, has recently been demonstrated with the LIFT technique using highly viscous Ag nanopastes to fabricate freestanding interconnects, complex voxel shapes, and high-aspect-ratio structures. In this paper, we demonstrate a simple yet versatile process for fabricating a variety of micro- and macroscale Ag structures. Structures include simple shapes for patterning electrical contacts, bridging and cantilever structures, high-aspect-ratio structures, and single-shot, large area transfers using a commercial digital micromirror device (DMD) chip. PMID:27077645

  13. Laser-induced thermoelastic effects can evoke tactile sensations.

    PubMed

    Jun, Jae-Hoon; Park, Jong-Rak; Kim, Sung-Phil; Min Bae, Young; Park, Jang-Yeon; Kim, Hyung-Sik; Choi, Seungmoon; Jung, Sung Jun; Hwa Park, Seung; Yeom, Dong-Il; Jung, Gu-In; Kim, Ji-Sun; Chung, Soon-Cheol

    2015-01-01

    Humans process a plethora of sensory information that is provided by various entities in the surrounding environment. Among the five major senses, technology for touch, haptics, is relatively young and has relatively limited applications largely due to its need for physical contact. In this article, we suggest a new way for non-contact haptic stimulation that uses laser, which has potential advantages such as mid-air stimulation, high spatial precision, and long working distance. We demonstrate such tactile stimulation can be enabled by laser-induced thermoelastic effects by means of physical and perceptual studies, as well as simulations. In the physical study, the mechanical effect of laser on a human skin sample is detected using low-power radiation in accordance with safety guidelines. Limited increases (< ~2.5 °C) in temperature at the surface of the skin, examined by both thermal camera and the Monte Carlo simulation, indicate that laser does not evoke heat-induced nociceptive sensation. In the human EEG study, brain responses to both mechanical and laser stimulation are consistent, along with subjective reports of the non-nociceptive sensation of laser stimuli. PMID:26047142

  14. Fast analysis of wood preservers using laser induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Uhl, A.; Loebe, K.; Kreuchwig, L.

    2001-06-01

    Laser-induced breakdown spectroscopy (LIBS) is used for the investigation of wood preservers in timber and in furniture. Both experiments in laboratory and practical applications in recycling facilities and on a building site prove the new possibilities for the fast detection of harmful agents in wood. A commercial system was developed for mobile laser-plasma-analysis as well as for industrial use in sorting plants. The universal measuring principle in combination with an Echelle optics permits real simultaneous multi-element-analysis in the range of 200-780 nm with a resolution of a few picometers. It enables the user to detect main and trace elements in wood within a few seconds, nearly independent of the matrix, knowing that different kinds of wood show an equal elemental composition. Sample preparation is not required. The quantitative analysis of inorganic wood preservers (containing, e.g. Cu, Cr, B, As, Pb, Hg) has been performed exactly using carbon as reference element. It can be shown that the detection limits for heavy metals in wood are in the ppm-range. Additional information is given concerning the quantitative analysis. Statistical data, e.g. the standard deviation (S.D.), were determined and calibration curves were used for each particular element. A comparison between ICP-AES and LIBS is given using depth profile correction factors regarding the different penetration depths with respect to the different volumes in wood analyzed by both analytical methods.

  15. Laser-induced breakdown spectroscopy combined with spatial heterodyne spectroscopy.

    PubMed

    Gornushkin, Igor B; Smith, Ben W; Panne, Ulrich; Omenetto, Nicoló

    2014-01-01

    A spatial heterodyne spectrometer (SHS) is tested for the first time in combination with laser-induced breakdown spectroscopy (LIBS). The spectrometer is a modified version of the Michelson interferometer in which mirrors are replaced by diffraction gratings. The SHS contains no moving parts and the gratings are fixed at equal distances from the beam splitter. The main advantage is high throughput, about 200 times higher than that of dispersive spectrometers used in LIBS. This makes LIBS-SHS a promising technique for low-light standoff applications. The output signal of the SHS is an interferogram that is Fourier-transformed to retrieve the original plasma spectrum. In this proof-of-principle study, we investigate the potential of LIBS-SHS for material classification and quantitative analysis. Brass standards with broadly varying concentrations of Cu and Zn were tested. Classification via principal component analysis (PCA) shows distinct groupings of materials according to their origin. The quantification via partial least squares regression (PLS) shows good precision (relative standard deviation < 10%) and accuracy (within ± 5% of nominal concentrations). It is possible that LIBS-SHS can be developed into a portable, inexpensive, rugged instrument for field applications. PMID:25226262

  16. Ultraviolet Laser-induced ignition of RDX single crystal

    NASA Astrophysics Data System (ADS)

    Yan, Zhonghua; Zhang, Chuanchao; Liu, Wei; Li, Jinshan; Huang, Ming; Wang, Xuming; Zhou, Guorui; Tan, Bisheng; Yang, Zongwei; Li, Zhijie; Li, Li; Yan, Hongwei; Yuan, Xiaodong; Zu, Xiaotao

    2016-02-01

    The RDX single crystals are ignited by ultraviolet laser (355 nm, 6.4 ns) pulses. The laser-induced damage morphology consisted of two distinct regions: a core region of layered fracture and a peripheral region of stripped material surrounding the core. As laser fluence increases, the area of the whole crack region increases all the way, while both the area and depth of the core region increase firstly, and then stay stable over the laser fluence of 12 J/cm2. The experimental details indicate the dynamics during laser ignition process. Plasma fireball of high temperature and pressure occurs firstly, followed by the micro-explosions on the (210) surface, and finally shock waves propagate through the materials to further strip materials outside and yield in-depth cracks in larger surrounding region. The plasma fireball evolves from isotropic to anisotropic under higher laser fluence resulting in the damage expansion only in lateral direction while maintaining the fixed depth. The primary insights into the interaction dynamics between laser and energetic materials can help developing the superior laser ignition technique.

  17. Dust Removal on Mars Using Laser-Induced Breakdown Spectroscopy

    NASA Technical Reports Server (NTRS)

    Graff, T. G.; Morris, R. V.; Clegg, S. M.; Wiens, R. C.; Anderson, R. B.

    2011-01-01

    Dust coatings on the surface of Mars complicate and, if sufficiently thick, mask the spectral characteristics and compositional determination of underlying material from in situ and remote sensing instrumentation. The Laser-Induced Breakdown Spectroscopy (LIBS) portion of the Chemistry & Camera (ChemCam) instrument, aboard the Mars Science Laboratory (MSL) rover, will be the first active remote sensing technique deployed on Mars able to remove dust. ChemCam utilizes a 5 ns pulsed 1067 nm high-powered laser focused to less than 400 m diameter on targets at distances up to 7 m [1,2]. With multiple laser pulses, dust and weathering coatings can be remotely analyzed and potentially removed using this technique [2,3]. A typical LIBS measurement during MSL surface operations is planned to consist of 50 laser pulses at 14 mJ, with the first 5 to 10 pulses used to analyze as well as remove any surface coating. Additionally, ChemCam's Remote Micro-Imager (RMI) is capable of resolving 200 m details at a distance of 2 m, or 1 mm at 10 m [1,4]. In this study, we report on initial laboratory experiments conducted to characterize the removal of dust coatings using similar LIBS parameters as ChemCam under Mars-like conditions. These experiments serve to better understand the removal of surface dust using LIBS and to facilitate the analysis of ChemCam LIBS spectral data and RMI images.

  18. Airborne laser induced fluorescence imaging. Innovative technology summary report

    SciTech Connect

    1999-06-01

    Laser-Induced Fluorescence (LIF) was demonstration as part of the Fernald Environmental Management Project (FEMP) Plant 1 Large Scale Demonstration and Deployment Project (LSDDP) sponsored by the US Department of Energy (DOE) Office of Science and Technology, Deactivation and Decommissioning Focus Area located at the Federal Energy Technology Center (FETC) in Morgantown, West Virginia. The demonstration took place on November 19, 1996. In order to allow the contaminated buildings undergoing deactivation and decommissioning (D and D) to be opened to the atmosphere, radiological surveys of floors, walls and ceilings must take place. After successful completion of the radiological clearance survey, demolition of the building can continue. Currently, this process is performed by collecting and analyzing swipe samples for radiological analysis. Two methods are used to analyze the swipe samples: hand-held frisker and laboratory analysis. For the purpose of this demonstration, the least expensive method, swipe samples analyzed by hand-held frisker, is the baseline technology. The objective of the technology demonstration was to determine if the baseline technology could be replaced using LIF.

  19. Modeling chemical reactions in laser-induced plasmas

    NASA Astrophysics Data System (ADS)

    Shabanov, S. V.; Gornushkin, I. B.

    2015-11-01

    Under the assumption of local thermal equilibrium, a numerical algorithm is proposed to find the equation of state for laser-induced plasmas (LIPs) in which chemical reactions are permitted in addition to ionization processes. The Coulomb interaction in plasma is accounted for by the Debye-Hückel method. The algorithm is used to calculate the equation of state for LIPs containing carbon, silicon, nitrogen, and argon. The equilibrium reaction constants are calculated using the latest experimental and ab initio data of spectroscopic constants for the molecules {N}_2, {C}_2, {Si}_2, {CN}, {SiN}, {SiC} and their ions. The algorithm is incorporated into a fluid dynamic numerical model based on the Navier-Stokes equations describing an expansion of LIP plumes into an ambient gas. The dynamics of LIP plumes obtained by the ablation of SiC, solid silicon, or solid carbon in an ambient gas containing {N}_2 and Ar is simulated to study formation of molecules and molecular ions.

  20. Laser-induced Forward Transfer of Ag Nanopaste.

    PubMed

    Breckenfeld, Eric; Kim, Heungsoo; Auyeung, Raymond C Y; Piqué, Alberto

    2016-01-01

    Over the past decade, there has been much development of non-lithographic methods(1-3) for printing metallic inks or other functional materials. Many of these processes such as inkjet(3) and laser-induced forward transfer (LIFT)(4) have become increasingly popular as interest in printable electronics and maskless patterning has grown. These additive manufacturing processes are inexpensive, environmentally friendly, and well suited for rapid prototyping, when compared to more traditional semiconductor processing techniques. While most direct-write processes are confined to two-dimensional structures and cannot handle materials with high viscosity (particularly inkjet), LIFT can transcend both constraints if performed properly. Congruent transfer of three dimensional pixels (called voxels), also referred to as laser decal transfer (LDT)(5-9), has recently been demonstrated with the LIFT technique using highly viscous Ag nanopastes to fabricate freestanding interconnects, complex voxel shapes, and high-aspect-ratio structures. In this paper, we demonstrate a simple yet versatile process for fabricating a variety of micro- and macroscale Ag structures. Structures include simple shapes for patterning electrical contacts, bridging and cantilever structures, high-aspect-ratio structures, and single-shot, large area transfers using a commercial digital micromirror device (DMD) chip. PMID:27077645

  1. Laser induced alignment of state-selected CH3I.

    PubMed

    He, Lanhai; Bulthuis, Jaap; Luo, Sizuo; Wang, Jia; Lu, Chunjing; Stolte, Steven; Ding, Dajun; Roeterdink, Wim G

    2015-10-01

    Hexapole state selection is used to prepare CH3I molecules in the |JKM〉 = |1±1∓1〉 state. The molecules are aligned in a strong 800 nm laser field, which is linearly polarised perpendicular to the weak static extraction field E of the time of flight setup. The molecules are subsequently ionised by a second time delayed probe laser pulse. It will be shown that in this geometry at high enough laser intensities the Newton sphere has sufficient symmetry to apply the inverse Abel transformation to reconstruct the three dimensional distribution from the projected ion image. The laser induced controllable alignment was found to have the upper and lower extreme values of 〈P2(cos θ)〉 = 0.7 for the aligned molecule and -0.1 for the anti-aligned molecule, coupled to 〈P4(cos θ)〉 between 0.3 and 0.0. The method to extract the alignment parameters 〈P2(cos θ)〉 and 〈P4(cos θ)〉 directly from the velocity map ion images will be discussed. PMID:26314900

  2. Laser induced fluorescence measurements of the cylindrical Hall thruster plume

    SciTech Connect

    Spektor, R.; Diamant, K. D.; Beiting, E. J.; Raitses, Y.; Fisch, N. J.

    2010-09-15

    An investigation of a fully cylindrical Hall thruster was performed using laser induced fluorescence (LIF) to measure ion velocity profiles in the plume. The measurements confirm a previously reported 9% increase in the exhaust energy when the cathode keeper draws an excess current (overrun mode). Furthermore, the velocity directions in the plume remain relatively unchanged for the cusped and direct magnetic field configuration in both overrun and nonoverrun modes. Previously reported plume narrowing in the overrun mode was confirmed and found to be due to the shift of the acceleration and ionization regions toward the anode. The electric field inferred from the LIF measurements allowed calculation of the electron ExB drift. Close to the centerline of the thruster, electrons drift azimuthally with velocity decreasing away from the centerline, thus creating shear. This shear can be a source of plasma instabilities and influence electron transport. Further away from the centerline, electrons drift in the opposite direction with their velocity increasing with increasing radius. In that region, electrons rotate without shear.

  3. Laser-induced porous graphene films from commercial polymers

    PubMed Central

    Lin, Jian; Peng, Zhiwei; Liu, Yuanyue; Ruiz-Zepeda, Francisco; Ye, Ruquan; Samuel, Errol L. G.; Yacaman, Miguel Jose; Yakobson, Boris I.; Tour, James M.

    2014-01-01

    Synthesis and patterning of carbon nanomaterials cost effectively is a challenge in electronic and energy storage devices. Here report a one-step, scalable approach for producing and patterning porous graphene films with 3-dimensional networks from commercial polymer films using a CO2 infrared laser. The sp3-carbon atoms are photothermally converted to sp2-carbon atoms by pulsed laser irradiation. The resulting laser-induced graphene (LIG) exhibits high electrical conductivity. The LIG can be readily patterned to interdigitated electrodes for in-plane microsupercapacitors with specific capacitances of >4 mF·cm−2 and power densities of ~9 mW·cm−2. Theoretical calculations partially suggest that enhanced capacitance may result from LIG’s unusual ultra-polycrystalline lattice of pentagon-heptagon structures. Combined with the advantage of one-step processing of LIG in air from commercial polymer sheets, which would allow the employment of a roll-to-roll manufacturing process, this technique provides a rapid route to polymer-written electronic and energy storage devices. PMID:25493446

  4. Cavity ringdown and laser-induced incandescence measurements of soot.

    PubMed

    Vander Wal, R L; Ticich, T M

    1999-03-20

    Currently laser-induced incandescence (LII) is widely used for the measurement of soot volume fraction. A particularly important aspect of the technique that has received less attention, however, is calibration. The applicability of cavity ringdown (CRD) for measurement of soot volume fraction f(v) is assessed, and the calibration of LII by means of CRD is demonstrated. The accuracy of CRD for f(v) determination is validated by comparison with traditional light extinction and path-integrated LII. By use of CRD, the quantification of LII for parts in 10(9) (ppb) f(v) levels is demonstrated. Results are presented that demonstrate the accuracy of CRD for a single laser pulse to be better than ?5% for measurement of ppb soot volume-fraction levels over a 1-cm path length. By use of CRD, spatially resolved LII signals from soot within methane-air diffusion flames are calibrated for ppb f(v) levels, thereby avoiding the extrapolation required of less sensitive methods in current use. PMID:18305765

  5. Laser-induced breakdown spectroscopy in industrial and security applications

    SciTech Connect

    Bol'shakov, Alexander A.; Yoo, Jong H.; Liu Chunyi; Plumer, John R.; Russo, Richard E.

    2010-05-01

    Laser-induced breakdown spectroscopy (LIBS) offers rapid, localized chemical analysis of solid or liquid materials with high spatial resolution in lateral and depth profiling, without the need for sample preparation. Principal component analysis and partial least squares algorithms were applied to identify a variety of complex organic and inorganic samples. This work illustrates how LIBS analyzers can answer a multitude of real-world needs for rapid analysis, such as determination of lead in paint and children's toys, analysis of electronic and solder materials, quality control of fiberglass panels, discrimination of coffee beans from different vendors, and identification of generic versus brand-name drugs. Lateral and depth profiling was performed on children's toys and paint layers. Traditional one-element calibration or multivariate chemometric procedures were applied for elemental quantification, from single laser shot determination of metal traces at {approx}10 {mu}g/g to determination of halogens at 90 {mu}g/g using 50-shot spectral accumulation. The effectiveness of LIBS for security applications was demonstrated in the field by testing the 50-m standoff LIBS rasterizing detector.

  6. Ultraviolet Laser-induced ignition of RDX single crystal.

    PubMed

    Yan, Zhonghua; Zhang, Chuanchao; Liu, Wei; Li, Jinshan; Huang, Ming; Wang, Xuming; Zhou, Guorui; Tan, Bisheng; Yang, Zongwei; Li, Zhijie; Li, Li; Yan, Hongwei; Yuan, Xiaodong; Zu, Xiaotao

    2016-01-01

    The RDX single crystals are ignited by ultraviolet laser (355 nm, 6.4 ns) pulses. The laser-induced damage morphology consisted of two distinct regions: a core region of layered fracture and a peripheral region of stripped material surrounding the core. As laser fluence increases, the area of the whole crack region increases all the way, while both the area and depth of the core region increase firstly, and then stay stable over the laser fluence of 12 J/cm(2). The experimental details indicate the dynamics during laser ignition process. Plasma fireball of high temperature and pressure occurs firstly, followed by the micro-explosions on the (210) surface, and finally shock waves propagate through the materials to further strip materials outside and yield in-depth cracks in larger surrounding region. The plasma fireball evolves from isotropic to anisotropic under higher laser fluence resulting in the damage expansion only in lateral direction while maintaining the fixed depth. The primary insights into the interaction dynamics between laser and energetic materials can help developing the superior laser ignition technique. PMID:26847854

  7. Laser-Induced Incandescence Measurements in Low Gravity

    NASA Technical Reports Server (NTRS)

    VanderWal, R. L.

    1997-01-01

    A low-gravity environment offers advantages to investigations concerned with soot growth or flame radiation by eliminating of buoyancy-induced convection. Basic to each type of study is knowledge of spatially resolved soot volume fraction, (f(sub v). Laser-induced incandescence (LII) has emerged as a diagnostic for soot volume fraction determination because it possesses high temporal and spatial resolution, geometric versatility and high sensitivity. Implementation and system characterization of LII in a drop tower that provides 2.2 sec of low-gravity (micro)g) at the NASA Lewis Research Center are described here. Validation of LII for soot volume fraction determination in (micro)g is performed by comparison between soot volume fraction measurements obtained by light extinction [20] and LII in low-gravity for a 50/50 mixture (by volume) of 0 acetylene/nitrogen issuing into quiescent air. Quantitative soot volume fraction measurements within other laminar flames of ethane and propane and a turbulent diffusion flame in (micro)g via LII are also demonstrated. An analysis of LII images of a turbulent acetylene diffusion flame in 1-g and (micro)g is presented.

  8. Elemental analysis of cotton by laser-induced breakdown spectroscopy

    SciTech Connect

    Schenk, Emily R.; Almirall, Jose R.

    2010-05-01

    Laser-induced breakdown spectroscopy (LIBS) has been applied to the elemental characterization of unprocessed cotton. This research is important in forensic and fraud detection applications to establish an elemental fingerprint of U.S. cotton by region, which can be used to determine the source of the cotton. To the best of our knowledge, this is the first report of a LIBS method for the elemental analysis of cotton. The experimental setup consists of a Nd:YAG laser that operates at the fundamental wavelength as the LIBS excitation source and an echelle spectrometer equipped with an intensified CCD camera. The relative concentrations of elements Al, Ba, Ca, Cr, Cu, Fe, Mg, and Sr from both nutrients and environmental contributions were determined by LIBS. Principal component analysis was used to visualize the differences between cotton samples based on the elemental composition by region in the U.S. Linear discriminant analysis of the LIBS data resulted in the correct classification of >97% of the cotton samples by U.S. region and >81% correct classification by state of origin.

  9. Laser-Induced Fluorescence in plasmas at UC Irvine

    NASA Astrophysics Data System (ADS)

    McWilliams, R.

    2003-10-01

    For about 25 years laser-induced fluorescence (LIF) has been performed at UC Irvine with many people contributing over that time period. A central contributor to the work has been Raul Stern, whether directly involved with the experiments at hand or via physics advice obtained wherever he could be found worldwide spreading the joys of LIF. At Irvine LIF has been developed (1,2) and used for ion tagging (3), spatial diffusion (4,5), velocity-space diffusion (6), optical tomography (7), and plasma processing (8) among many other fascinating experimental results. This talk will review the LIF work at Irvine with special note of Stern's contributions and influence. 1.) D. Hill, S. Fornaca, M. Wickham, Rev. Sci. Instrum. 54, 309 (1983) 2.) G.D. Severn, D.A. Edrich, and R. McWilliams, Rev. Sci. Instrum. 69, 10 (1998). 3.) R. Stern, D. Hill, N. Rynn, Phys. Lett. A93, 127 (1983) 4.) M. Okubo, R. McWilliams, Phys. Fluids 30, 2849 (1987). 5.) R. McWilliams, M. K. Okubo and N. S. Wolf, Phys. Fluids B 2(3), 523 (1990). 6.) J. Bowles, R. McWilliams, N. Rynn, Phys. Plasmas 1, 3814 (1994). 7.) R. McWilliams, R. Koslover), Phys. Rev. Lett. 58, 37 (1987). 8.) R. McWilliams, D. Edrich, Thin Solid Films 435, 1 (2003).

  10. Independent component analysis classification of laser induced breakdown spectroscopy spectra

    NASA Astrophysics Data System (ADS)

    Forni, Olivier; Maurice, Sylvestre; Gasnault, Olivier; Wiens, Roger C.; Cousin, Agnès; Clegg, Samuel M.; Sirven, Jean-Baptiste; Lasue, Jérémie

    2013-08-01

    The ChemCam instrument on board Mars Science Laboratory (MSL) rover uses the laser-induced breakdown spectroscopy (LIBS) technique to remotely analyze Martian rocks. It retrieves spectra up to a distance of seven meters to quantify and to quantitatively analyze the sampled rocks. Like any field application, on-site measurements by LIBS are altered by diverse matrix effects which induce signal variations that are specific to the nature of the sample. Qualitative aspects remain to be studied, particularly LIBS sample identification to determine which samples are of interest for further analysis by ChemCam and other rover instruments. This can be performed with the help of different chemometric methods that model the spectra variance in order to identify a the rock from its spectrum. In this paper we test independent components analysis (ICA) rock classification by remote LIBS. We show that using measures of distance in ICA space, namely the Manhattan and the Mahalanobis distance, we can efficiently classify spectra of an unknown rock. The Mahalanobis distance gives overall better performances and is easier to manage than the Manhattan distance for which the determination of the cut-off distance is not easy. However these two techniques are complementary and their analytical performances will improve with time during MSL operations as the quantity of available Martian spectra will grow. The analysis accuracy and performances will benefit from a combination of the two approaches.

  11. Ultraviolet Laser-induced ignition of RDX single crystal

    PubMed Central

    Yan, Zhonghua; Zhang, Chuanchao; Liu, Wei; Li, Jinshan; Huang, Ming; Wang, Xuming; Zhou, Guorui; Tan, Bisheng; Yang, Zongwei; Li, Zhijie; Li, Li; Yan, Hongwei; Yuan, Xiaodong; Zu, Xiaotao

    2016-01-01

    The RDX single crystals are ignited by ultraviolet laser (355 nm, 6.4 ns) pulses. The laser-induced damage morphology consisted of two distinct regions: a core region of layered fracture and a peripheral region of stripped material surrounding the core. As laser fluence increases, the area of the whole crack region increases all the way, while both the area and depth of the core region increase firstly, and then stay stable over the laser fluence of 12 J/cm2. The experimental details indicate the dynamics during laser ignition process. Plasma fireball of high temperature and pressure occurs firstly, followed by the micro-explosions on the (210) surface, and finally shock waves propagate through the materials to further strip materials outside and yield in-depth cracks in larger surrounding region. The plasma fireball evolves from isotropic to anisotropic under higher laser fluence resulting in the damage expansion only in lateral direction while maintaining the fixed depth. The primary insights into the interaction dynamics between laser and energetic materials can help developing the superior laser ignition technique. PMID:26847854

  12. Seedless Laser Velocimetry Using Heterodyne Laser-Induced Thermal Acoustics

    NASA Technical Reports Server (NTRS)

    Hart, Roger C.; Balla, R. Jeffrey; Herring, G. C.; Jenkins, Luther N.; Bushnell, Dennis M. (Technical Monitor)

    2001-01-01

    A need exists for a seedless equivalent of laser Doppler velocimetry (LDV) for use in low-turbulence or supersonic flows or elsewhere where seeding is undesirable or impractical. A compact laser velocimeter using heterodyne non-resonant laser-induced thermal acoustics (LITA) to measure a single component of velocity is described. Neither molecular (e.g. NO2) nor particulate seed is added to the flow. In non-resonant LITA two beams split from a short-pulse pump laser are crossed; interference produces two counterpropagating sound waves by electrostriction. A CW probe laser incident on the sound waves at the proper angle is directed towards a detector. Measurement of the beating between the Doppler-shifted light and a highly attenuated portion of the probe beam allows determination of one component of flow velocity, speed of sound, and temperature. The sound waves essentially take the place of the particulate seed used in LDV. The velocimeter was used to study the flow behind a rearward-facing step in NASA Langley Research Center's Basic Aerodynamics Research Tunnel. Comparison is made with pitot-static probe data in the freestream over the range 0 m/s - 55 m/s. Comparison with LDV is made in the recirculation region behind the step and in a well-developed boundary layer in front of the step. Good agreement is found in all cases.

  13. Laser-induced thermoelastic effects can evoke tactile sensations

    NASA Astrophysics Data System (ADS)

    Jun, Jae-Hoon; Park, Jong-Rak; Kim, Sung-Phil; Min Bae, Young; Park, Jang-Yeon; Kim, Hyung-Sik; Choi, Seungmoon; Jung, Sung Jun; Hwa Park, Seung; Yeom, Dong-Il; Jung, Gu-In; Kim, Ji-Sun; Chung, Soon-Cheol

    2015-06-01

    Humans process a plethora of sensory information that is provided by various entities in the surrounding environment. Among the five major senses, technology for touch, haptics, is relatively young and has relatively limited applications largely due to its need for physical contact. In this article, we suggest a new way for non-contact haptic stimulation that uses laser, which has potential advantages such as mid-air stimulation, high spatial precision, and long working distance. We demonstrate such tactile stimulation can be enabled by laser-induced thermoelastic effects by means of physical and perceptual studies, as well as simulations. In the physical study, the mechanical effect of laser on a human skin sample is detected using low-power radiation in accordance with safety guidelines. Limited increases (< ~2.5 °C) in temperature at the surface of the skin, examined by both thermal camera and the Monte Carlo simulation, indicate that laser does not evoke heat-induced nociceptive sensation. In the human EEG study, brain responses to both mechanical and laser stimulation are consistent, along with subjective reports of the non-nociceptive sensation of laser stimuli.

  14. The stochastic nature of growth of laser-induced damage

    NASA Astrophysics Data System (ADS)

    Carr, C. W.; Cross, David A.; Liao, Zhi M.; Norton, Mary A.; Negres, Raluca A.

    2015-07-01

    Laser fluence and operational tempo of ICF systems operating in the UV are typically limited by the growth of laser- induced damage on their final optics (primarily silica optics). In the early 2000 time frame, studies of laser damage growth with relevant large area beams revealed that for some laser conditions damage sites located on the exit surface of a fused silica optic grew following an exponential growth rule: D(n) = D0 exp (n α(φ)), where D is final site diameter, D0 is the initial diameter of the site, φ is the laser fluence, α(φ) is the growth coefficient, and n is the number of exposures. In general α is a linear function of φ, with a threshold of φTH. In recent years, it has been found that that growth behavior is actually considerably more complex. For example, it was found that α is not a constant for a given fluence but follows a probability distribution with a mean equal to α(φ). This is complicated by observations that these distributions are actually functions of the pulse shape, damage site size, and initial morphology of damage initiation. In addition, there is not a fixed fluence threshold for damage sites growth, which is better described by a probability of growth which depends on site size, morphology and laser fluence. Here will review these findings and discuss implications for the operation of large laser systems.

  15. Laser-induced forward transfer (LIFT) of congruent voxels

    NASA Astrophysics Data System (ADS)

    Piqué, Alberto; Kim, Heungsoo; Auyeung, Raymond C. Y.; Beniam, Iyoel; Breckenfeld, Eric

    2016-06-01

    Laser-induced forward transfer (LIFT) of functional materials offers unique advantages and capabilities for the rapid prototyping of electronic, optical and sensor elements. The use of LIFT for printing high viscosity metallic nano-inks and nano-pastes can be optimized for the transfer of voxels congruent with the shape of the laser pulse, forming thin film-like structures non-lithographically. These processes are capable of printing patterns with excellent lateral resolution and thickness uniformity typically found in 3-dimensional stacked assemblies, MEMS-like structures and free-standing interconnects. However, in order to achieve congruent voxel transfer with LIFT, the particle size and viscosity of the ink or paste suspensions must be adjusted to minimize variations due to wetting and drying effects. When LIFT is carried out with high-viscosity nano-suspensions, the printed voxel size and shape become controllable parameters, allowing the printing of thin-film like structures whose shape is determined by the spatial distribution of the laser pulse. The result is a new level of parallelization beyond current serial direct-write processes whereby the geometry of each printed voxel can be optimized according to the pattern design. This work shows how LIFT of congruent voxels can be applied to the fabrication of 2D and 3D microstructures by adjusting the viscosity of the nano-suspension and laser transfer parameters.

  16. Laser induced mechanisms controlling the size distribution of metallic nanoparticles.

    PubMed

    Liu, Zeming; Vitrant, Guy; Lefkir, Yaya; Bakhti, Said; Destouches, Nathalie

    2016-09-21

    This paper describes a model to simulate changes in the size distribution of metallic nanoparticles (NPs) in TiO2 films upon continuous wave light excitation. Interrelated laser induced physical and chemical processes initiated directly by photon absorption or by plasmon induced thermal heating are considered. Namely the model takes into account the NP coalescence, Ostwald ripening, the reduction of silver ions and the oxidation of metallic NPs, competitive mechanisms that can lead to counter-intuitive behaviors depending on the exposure conditions. Theoretical predictions are compared successfully to the experimental results deduced from a thorough analysis of scanning transmission electron microscopy (STEM) pictures of Ag:TiO2 films processed with a scanning visible laser beam at different speeds. Ag:TiO2 systems are considered for many applications in solar energy conversion, photocatalysis or secured data printing. Numerical investigations of such a system provide a better understanding of light induced growth and shrinking processes and open up prospects for designing more efficient photocatalytic devices based on metal NP doped TiO2 or for improving the size homogeneity in self-organized metallic NP patterns, for instance. PMID:27539293

  17. Mid-infrared emission from laser-induced breakdown spectroscopy.

    PubMed

    Yang, Clayton S-C; Brown, Ei E; Hommerich, Uwe H; Trivedi, Sudhir B; Samuels, Alan C; Snyder, A Peter

    2007-03-01

    Laser-induced breakdown spectroscopy (LIBS) is a powerful analytical technique for detecting and identifying trace elemental contaminants by monitoring the visible atomic emission from small plasmas. However, mid-infrared (MIR), generally referring to the wavelength range between 2.5 to 25 microm, molecular vibrational and rotational emissions generated by a sample during a LIBS event has not been reported. The LIBS investigations reported in the literature largely involve spectral analysis in the ultraviolet-visible-near-infrared (UV-VIS-NIR) region (less than 1 microm) to probe elemental composition and profiles. Measurements were made to probe the MIR emission from a LIBS event between 3 and 5.75 microm. Oxidation of the sputtered carbon atoms and/or carbon-containing fragments from the sample and atmospheric oxygen produced CO(2) and CO vibrational emission features from 4.2 to 4.8 microm. The LIBS MIR emission has the potential to augment the conventional UV-VIS electronic emission information with that in the MIR region. PMID:17389073

  18. Visualization of plasma turbulence with laser-induced fluorescence (invited)

    SciTech Connect

    Levinton, Fred M.; Trintchouk, Fedor

    2001-01-01

    Turbulence is a key factor limiting the performance of fusion devices. Plasma edge turbulence determines the boundary values of the plasma density and temperature, which in turn determine the internal gradients and controls global plasma transport. In recent years, significant progress has been made in modeling turbulence behavior in plasmas and its effect on transport. Progress has also been made in diagnostics for turbulence measurement; however, there is still a large gap in our understanding of it. An approach to improve this situation is to experimentally visualize the turbulence, that is, a high resolution 2-D image of the plasma density. Visualization of turbulence can improve the connection to theory and help validate theoretical models. One method that has been successfully developed to visualize turbulence in gases and fluids is planar laser-induced fluorescence. We have recently applied this technique to visualize turbulence and structures in a plasma. This was accomplished using an Alexandrite laser that is tunable between 700 and 800 nm, and from 350 to 400 nm with second harmonic generation. The fluorescence light from an argon ion transition has been imaged onto an intensified charged coupled device camera that is gated in synchronization with the laser. Images from the plasma show a rotating structure at 30 kHz in addition to small scale turbulence.

  19. Laser induced fluorescence of argon ion in plasma presheaths

    SciTech Connect

    Atta Khedr, M.; Hala, A.M.; Oksuz, L.; Hershkowitz, N.

    1999-07-01

    A turnable diode laser system has been used to measure ion velocity distribution functions of ArII in plasma presheaths using laser-induced fluorescence (LIF). The diode laser system can examine the velocity distribution function with marginally greater resolution than the dye laser owing to their smaller line width (0.001 nm). LIF of ArII requires excitation at 668.61 nm. the diode laser is centered at that wavelength with a tuning range of 0.15 nm and the optical amplifier (MOPA) is at 10 nm. LIF measurements of presheaths as a function of pressure (0.5--3 mTorr) were made in a DC hot-filament produced multidipole plasma discharge near a negatively biased plate. The ion velocity has range of 10{sup 3}cm/s--10{sup 5} cm/s for presheaths thickness 0.5 cm--5cm. These measurements are compared with results obtained by using a double sided Langmuir probe (Mach probe) and an emissive probe.

  20. Concentration measurements with Laser-Induced Thermal Acoustics

    NASA Astrophysics Data System (ADS)

    Schlamp, Stefan; Sobota, Thomas H.

    2001-03-01

    Laser-induced thermal acoustics (LITA) is used to measure the concentration of iodine vapor (40-150 ppm) in air instantaneously (1 μs), remotely, and non-intrusively. Two focused, pulsed intersecting laser beams inscribe a density grating in the fluid. A cw interrogation beam directed at the Bragg angle on the grating is scattered into a coherent signal beam whose intensity depends on the instantaneous density grating magnitude. The signal beam is detected by a photomultiplier tube and its history recorded by a digital storage oscilloscope. The species in question (e.g., I_2) and the dilution species are excited resonantly (by thermalization) and non-resonantly (by electrostriction), respectively. The signals show oscillations at (twice) the grating's Brillouin frequency for the case of thermalization (electrostriction). The ratio of the thermalization to the electrostriction grating magnitudes is proportional to the resonant species concentration. They are extracted by a least-squares fitting scheme. For good accuracy, the ratio must be of order unity. For this case, the standard error is 5%. The speed of sound (error <1%) and flow velocity (error <1%) can be measured simultaneously.

  1. Laser induced focusing for over-dense plasma beams

    SciTech Connect

    Schmidt, Peter; Boine-Frankenheim, Oliver; Mulser, Peter

    2015-09-15

    The capability of ion acceleration with high power, pulsed lasers has become an active field of research in the past years. In this context, the radiation pressure acceleration (RPA) mechanism has been the topic of numerous theoretical and experimental publications. Within that mechanism, a high power, pulsed laser beam hits a thin film target. In contrast to the target normal sheath acceleration, the entire film target is accelerated as a bulk by the radiation pressure of the laser. Simulations predict heavy ion beams with kinetic energy up to GeV, as well as solid body densities. However, there are several effects which limit the efficiency of the RPA: On the one hand, the Rayleigh-Taylor-instability limits the predicted density. On the other hand, conventional accelerator elements, such as magnetic focusing devices are too bulky to be installed right after the target. Therefore, we present a new beam transport method, suitable for RPA-like/over-dense plasma beams: laser induced focusing.

  2. Production of biomolecule microarrays through laser induced forward transfer

    NASA Astrophysics Data System (ADS)

    Fernandez-Pradas, Juan Marcos; Serra, Pere; Colina, Monica; Morenza, Jose-Luis

    2004-10-01

    Biomolecule microarrays are a kind of biosensors that consist in patterns of different biological molecules immobilized on a solid substrate and capable to bind specifically to their complementary targets. In particular, DNA and protein microarrays have been revealed to be very efficient devices for genen and protein identification, what has converted them in powerful tools for many applications, like clinical diagnose, drug discovery analysis, genomics and proteomics. The production of these devices requires the manipulation of tiny amounts of a liquid solution containing biomolecules without damaging them. In this work laser induced forward transfer (LIFT) has been used for spotting a biomolecule in order to check the viability of this technique for the production of microarrays. A pulsed Nd:YAG laser beam (355 nm wavelength) has been used to transfer droplets of a biomolecule containing solution onto a solid slide. Optical microscopy of the transferred material has been carried out to investigate the morphological characteristics of the droplets obtained under different irradiation conditions. Afterwards, a DNA microarray has been spotted. The viability of the transference has been tested by checking the biological activity of the biomolecule in front of its specific complementary target. This has revealed that, indeed, the LIFT technique is adequate for the production of DNA microarrays.

  3. Laser-induced breakdown spectroscopy enhanced by a micro torch.

    PubMed

    Liu, L; Huang, X; Li, S; Lu, Yao; Chen, K; Jiang, L; Silvain, J F; Lu, Y F

    2015-06-01

    A commercial butane micron troch was used to enhance plasma optical emissions in laser-induced breakdown spectroscopy (LIBS). Fast imaging and spectroscopic analyses were used to observe plasma evolution in the atmospheric pressure for LIBS without and with using a micro torch. Optical emission intensities and signal-to-noise ratios (SNRs) as functions of delay time were studied. Enhanced optical emission and SNRs were obtained by using a micro torch. The effects of laser pulse energy on the emission intensities and SNRs were studied. The same spectral intensity could be obtained using micro torch with much lower laser pulse energy. The investigation of SNR evolution with delay time at different laser pulse energies showed that the SNR enhancement factor is higher for plasmas generated by lower laser pulse energies than those generated by higher laser energies. The calibration curves of emission line intensities with elemental concentrations showed that detection sensitivities of Mn I 404.136 nm and V I 437.923 nm were improved by around 3 times. The limits of detection for both Mn I 404.136 nm and V I 437.923 nm are reduced from 425 and 42 ppm to 139 and 20 ppm, respectively, after using the micro torch. The LIBS system with micro torch was demonstrated to be cost-effective, compact, and capable of sensitivity improvement, especially for LIBS system operating with low laser pulse energy. PMID:26072861

  4. Laser-induced porous graphene films from commercial polymers.

    PubMed

    Lin, Jian; Peng, Zhiwei; Liu, Yuanyue; Ruiz-Zepeda, Francisco; Ye, Ruquan; Samuel, Errol L G; Yacaman, Miguel Jose; Yakobson, Boris I; Tour, James M

    2014-01-01

    The cost effective synthesis and patterning of carbon nanomaterials is a challenge in electronic and energy storage devices. Here we report a one-step, scalable approach for producing and patterning porous graphene films with three-dimensional networks from commercial polymer films using a CO2 infrared laser. The sp(3)-carbon atoms are photothermally converted to sp(2)-carbon atoms by pulsed laser irradiation. The resulting laser-induced graphene (LIG) exhibits high electrical conductivity. The LIG can be readily patterned to interdigitated electrodes for in-plane microsupercapacitors with specific capacitances of >4 mF cm(-2) and power densities of ~9 mW cm(-2). Theoretical calculations partially suggest that enhanced capacitance may result from LIG's unusual ultra-polycrystalline lattice of pentagon-heptagon structures. Combined with the advantage of one-step processing of LIG in air from commercial polymer sheets, which would allow the employment of a roll-to-roll manufacturing process, this technique provides a rapid route to polymer-written electronic and energy storage devices. PMID:25493446

  5. Laser-induced breakdown spectroscopy analyses of tungsten surfaces

    NASA Astrophysics Data System (ADS)

    Nishijima, D.; Hollmann, E. M.; Doerner, R. P.; Rudakov, D. L.

    2016-02-01

    Tungsten (W) surfaces are analyzed with laser-induced breakdown spectroscopy (LIBS). Interactions of W with nanosecond (ns) and femtosecond (fs) laser pulses are found to be quite different in terms of the ambient Ar gas pressure dependence of the average ablation rate and W I line intensity. Collinear double-pulse LIBS (115 + 115 mJ) using two ns lasers (with interpulse separation Δt 12 = 5.32 μs) improves the signal-to-noise ratio over the whole Ar pressure range P Ar = 6.7 × 10-1 - 6.7 × 104 Pa in contrast with single-pulse LIBS (SP-LIBS) with 230 mJ, where a signal enhancement by a factor of ˜2-3 is obtained only at P Ar > 103 Pa. SP-LIBS with a ns laser has succeeded in obtaining a sharp transition between thin W layer with a thickness of ˜100 nm and the graphite substrate. A He I (587.5 nm) line has been successfully detected with SP-LIBS with a ns laser from W containing He bubbles (˜20-30 nm layers) in the near-surface region.

  6. Study of Bacterial Samples Using Laser Induced Breakdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    W, A. Farooq; M, Atif; W, Tawfik; M, S. Alsalhi; Z, A. Alahmed; M, Sarfraz; J, P. Singh

    2014-12-01

    Laser-induced breakdown spectroscopy (LIBS) technique has been applied to investigate two different types of bacteria, Escherichia coli (B1) and Micrococcus luteus (B2) deposited on glass slides using Spectrolaser 7000. LIBS spectra were analyzed using spectrolaser software. LIBS spectrum of glass substrate was compared with bacteria spectra. Ca, Mg, Na, K, P, S, Cl, Fe, Al, Mn, Cu, C, H and CN-band appeared in bacterial samples in air. Two carbon lines at 193.02 nm, 247.88 nm and one hydrogen line at 656.28 nm with intensity ratios of 1.9, 1.83 and 1.53 appeared in bacterial samples B1 and B2 respectively. Carbon and hydrogen are the important components of the bio-samples like bacteria and other cancer cells. Investigation on LIBS spectra of the samples in He and Ar atmospheres is also presented. Ni lines appeared only in B2 sample in Ar atmosphere. From the present experimental results we are able to show that LIBS technique has a potential in the identification and discrimination of different types of bacteria.

  7. Wavelet-based laser-induced ultrasonic inspection in pipes

    NASA Astrophysics Data System (ADS)

    Baltazar-López, Martín E.; Suh, Steve; Chona, Ravinder; Burger, Christian P.

    2006-02-01

    The feasibility of detecting localized defects in tubing using Wavelet based laser-induced ultrasonic-guided waves as an inspection method is examined. Ultrasonic guided waves initiated and propagating in hollow cylinders (pipes and/or tubes) are studied as an alternative, robust nondestructive in situ inspection method. Contrary to other traditional methods for pipe inspection, in which contact transducers (electromagnetic, piezoelectric) and/or coupling media (submersion liquids) are used, this method is characterized by its non-contact nature. This characteristic is particularly important in applications involving Nondestructive Evaluation (NDE) of materials because the signal being detected corresponds only to the induced wave. Cylindrical guided waves are generated using a Q-switched Nd:YAG laser and a Fiber Tip Interferometry (FTI) system is used to acquire the waves. Guided wave experimental techniques are developed for the measurement of phase velocities to determine elastic properties of the material and the location and geometry of flaws including inclusions, voids, and cracks in hollow cylinders. As compared to the traditional bulk wave methods, the use of guided waves offers several important potential advantages. Some of which includes better inspection efficiency, the applicability to in-situ tube inspection, and fewer evaluation fluctuations with increased reliability.

  8. [The Progress in Remote Laser-Induced Breakdown Spectroscopy].

    PubMed

    Zhang, Ting-ting; Wan, Xiong; Shu, Rong; Liu, Peng-xi

    2015-07-01

    As a kind of spectroscopic technique, the remote laser-induced breakdown spectroscopy (Remote LIBS) can measure elemental compositions of remote targets by using high-power lasers and focusing approaches. In this paper, three remote detection approaches (open path LIBS, fiber optic LIBS and compact probe fiber optic LIBS) and their system architectures are summarized and analyzed. Conventional open path LIBS, with high requirement of specifications of lasers, optical systems, spectrographs and detectors, has always been a research focus in remote testing field. Fiber optic LIBS has the advantages of simplification of optical focusing system and high collection efficiency of the plasma light. This paper reviews the progress in new techniques of LIBS, for instance Filament-LIBS techniques and LIBS combines with other spectral detection techniques, and emphatically analyzes their characteristics and advantages. These new techniques have greatly broadened the detection range of LIBS, enhanced material recognition ability of LIBS, and made a great contribution to expanding applications of remote LIBS. Latest development of applications of remote LIBS in fields of deep space exploration, hazardous material detection, pollution testing, metallurgical industries and heritage restoration is introduced in detail. With the development of laser techniques, spectral detection and calibration techniques, the detection range of remote LIBS has been expended, their application fields has been extended, and the detection precision and accuracy have been improved. PMID:26717768

  9. Treatment of laser-induced retinal injuries by neuroprotection

    NASA Astrophysics Data System (ADS)

    Solberg, Yoram; Rosner, Mordechai; Belkin, Michael

    1997-05-01

    Retinal laser photocoagulation treatments are often complicated with immediate side-effect of visual impairment. To determine whether glutamate-receptor blockers can serve as adjuvant neuroprotective therapy, we examined the effect of MK-801, an NMDA-receptor antagonist, on laser-induced retinal injury in a rat model. Argon laser retinal lesions were created in the retina of 36 DA rats. Treatment with intraperitoneal injections of MK-801 or saline was started immediately after the laser photocoagulation. The animals were sacrificed after 3, 20 or 60 days and the retinal lesions were evaluated histologically and morphometrically. Photoreceptor-cell loss was significantly smaller in MK-801-treated rats than controls. The proliferative membrane composed of retinal pigment epithelial cells which was seen at the base of the lesion in control retinas, was smaller in the MK-801-treated retinas. MK-801 exhibited neuroprotective and anti-proliferative properties in the retina. Glutamate-receptor blockers should be further investigated for serving as adjuvant therapy to retinal photocoagulation treatments.

  10. In vivo laser-induced breakdown in the rabbit eye

    NASA Astrophysics Data System (ADS)

    Cain, Clarence P.; DiCarlo, Cheryl D.; Kennedy, Paul K.; Noojin, Gary D.; Amnotte, Rodney E.; Roach, William P.

    1995-05-01

    Threshold measurements for femtosecond laser pulsewidths have been made for retinal minimum visible lesions (MVLs) in Dutch Belted rabbit and rhesus monkey eyes. Laser-induced breakdown (LIB) thresholds in biological materials including vitreous, normal saline, tap water, and ultrapure water have been measured and reported using an artificial eye. We have recorded on video the first LIB causing bubble formation in any eye in vivo using albino rabbit eyes (New Zealand white) with 120- femtosecond (fs) pulses and pulse energies as low as 5 microjoules ((mu) J). These bubbles were clearly formed anterior to the retina within the vitreous humor and, with 60 (mu) J of energy, they lasted for several seconds before disappearing and leaving no apparent damage to the retina. We believe this to be true LIB because of the lack of pigmentation or melanin granules within the albino rabbit eye (thus no absorptive elements) and because of the extremely high peak powers within the 5-(mu) J, 120-fs laser pulse. These high peak powers produce self-focusing of the pulse within the vitreous. The bubble formation at the breakdown site acts as a limiting mechanism for energy transmission and may explain why high-energy femotsecond pulses at energies up to 100 (mu) J sometimes do not cause severe damage in the pigmented rabbit eye. This fact may also explain why it is so difficult to produce hemorrhagic lesions in either the rabbit or primate eye with 100-fs laser pulses.

  11. Measuring turbulent fluid dispersion using laser induced phosphorescence

    NASA Astrophysics Data System (ADS)

    van der Voort, Dennis; Dam, Nico; van de Water, Willem; Kunnen, Rudie; Clercx, Herman; van Heijst, Gertjan

    2015-11-01

    Fluid dispersion due to turbulence is an important subject in both natural and engineering processes, from cloud formation to turbulent mixing and liquid spray combustion. The combination of small scales and often high velocities results in few experimental techniques that can follow the course of events. We introduce a novel technique, which measures the dispersion of ``tagged'' fluid particles by means of laser-induced phosphorescence, using a solution containing a europium-based molecular complex with a relatively long phosphorescence half-life. This technique is used to measure transport processes in both the dispersion of droplets in homogeneous isotropic turbulence and the dispersion of fluid of near-nozzle spray breakup processes. By tagging a small amount of droplets/fluid via laser excitation, the tagged droplets can be tracked in a Lagrangian way. The absolute dispersion of the droplets can be measured in a variety of turbulent flows. Using this technique it is shows that droplets around St =τp /τη ~ 1 (Stokes number) disperse faster than true fluid tracers in homogeneous isotropic turbulence, as well as differences between longitudinal and radial dispersion in turbulent sprays. This work is part of the research programme of the Foundation for Fundamental Research on Matter (FOM), which is part of the Dutch Organisation for Scientific Research (NWO).

  12. Oxide nanoparticles synthesis via laser-induced plasma in liquid

    NASA Astrophysics Data System (ADS)

    Goto, Taku; Weihs, Hansel; Honda, Mitsuhiro; Kulinich, Sergei; Shimizu, Yoshiki; Ito, Tsuyohito

    2014-10-01

    Laser ablation in fluids has recently attracted a lot of attention as one of synthetic techniques to prepare new attractive nanomaterials, with the ability to control both product chemistry and morphology in many systems. In this study, we generated laser-induced plasma in H2O - ethanol mixtures, while ablating metal targets to produce oxide nanoparticles and to study the effect of the medium on their properties. The ablated targets used in this study were Zn or Sn plates. A nanosecond Nd:YAG laser with the wavelength of 532 nm (10 Hz, 20--30 mJ/pulse) was applied to irradiate the targets. The liquid media were maintained at 0.1 to 30 MPa to study the effect of pressure. We found that the H2O/ethanol ratio (at atmospheric pressure) can control the properties of the produced ZnO nanoparticles, such as defects and oxidation degree. The properties were examined by photoluminescence (PL) spectroscopy, X-ray diffraction, electron microscopies, and so on. More details will be presented at the symposium.

  13. Femtosecond laser induced nanostructuring for surface enhanced Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Messaoudi, H.; Das, S. K.; Lange, J.; Heinrich, F.; Schrader, S.; Frohme, M.; Grunwald, R.

    2014-03-01

    The formation of periodical nanostructures with femtosecond laser pulses was used to create highly efficient substrates for surface-enhanced Raman spectroscopy (SERS). We report about the structuring of silver and copper substrates and their application to the SERS of DNA (herring sperm) and protein molecules (egg albumen). The maximum enhancement factors were found on Ag substrates processed with the second harmonic generation (SHG) of a 1-kHz Ti:sapphire laser and structure periods near the SHG wavelength. In the case of copper, however, the highest enhancement was obtained with long-period ripples induced with at fundamental wavelength. This is explained by an additional significant influence of nanoparticles on the surface. Nanostructured areas in the range of 1.25 mm2 were obtained in 10 s. The surfaces were characterized by scanning electron microscopy, Fast Fourier Transform and Raman spectroscopy. Moreover, the role of the chemical modification of the metal structures is addressed. Thin oxide layers resulting from working in atmosphere which improve the biocompatibility were indicated by vibration spectra. It is expected that the detailed study of the mechanisms of laser-induced nanostructure formation will stimulate further applications of functionalized surfaces like photocatalysis, selective chemistry and nano-biology.

  14. Hyperspectral laser-induced autofluorescence imaging of dental caries

    NASA Astrophysics Data System (ADS)

    Bürmen, Miran; Fidler, Aleš; Pernuš, Franjo; Likar, Boštjan

    2012-01-01

    Dental caries is a disease characterized by demineralization of enamel crystals leading to the penetration of bacteria into the dentine and pulp. Early detection of enamel demineralization resulting in increased enamel porosity, commonly known as white spots, is a difficult diagnostic task. Laser induced autofluorescence was shown to be a useful method for early detection of demineralization. The existing studies involved either a single point spectroscopic measurements or imaging at a single spectral band. In the case of spectroscopic measurements, very little or no spatial information is acquired and the measured autofluorescence signal strongly depends on the position and orientation of the probe. On the other hand, single-band spectral imaging can be substantially affected by local spectral artefacts. Such effects can significantly interfere with automated methods for detection of early caries lesions. In contrast, hyperspectral imaging effectively combines the spatial information of imaging methods with the spectral information of spectroscopic methods providing excellent basis for development of robust and reliable algorithms for automated classification and analysis of hard dental tissues. In this paper, we employ 405 nm laser excitation of natural caries lesions. The fluorescence signal is acquired by a state-of-the-art hyperspectral imaging system consisting of a high-resolution acousto-optic tunable filter (AOTF) and a highly sensitive Scientific CMOS camera in the spectral range from 550 nm to 800 nm. The results are compared to the contrast obtained by near-infrared hyperspectral imaging technique employed in the existing studies on early detection of dental caries.

  15. Laser-induced breakdown spectroscopy of molten aluminum alloy

    NASA Astrophysics Data System (ADS)

    Rai, Awadhesh K.; Yueh, Fang-Yu; Singh, Jagdish P.

    2003-04-01

    We have demonstrated that a fiber-optic laser-induced breakdown spectroscopy (LIBS) probe is suitable for measuring the concentration of minor constituents of a molten Al alloy in a laboratory furnace. For the first time to our knowledge we are able to record the LIBS spectra in several spectral regions of seven different molten Al alloy samples by inserting the LIBS probe inside the molten alloys, allowing us to obtain a ratio calibration curve for minor constituents (Cr, Mg, Zn, Cu, Si, etc.), using Fe as a reference element. A ratio calibration curve for Fe with a major element (Al) can also be obtained with which the concentration of Fe in the alloy can be determined. The effects of the surrounding atmosphere on the LIBS spectra of the molten alloy were investigated. Effects of focal length of the lens on the LIBS signals were also studied. LIBS spectra of a solid Al alloy recorded with the same LIBS probe were compared with the LIBS spectra of the molten alloy. Our results suggest that the LIBS probe is useful for monitoring the elemental composition of an Al melt in an industrial furnace at different depths and different positions inside the melt.

  16. Laser induced formation of micro-rough structures

    NASA Astrophysics Data System (ADS)

    Singh, Rajiv K.; Fitz-Gerald, James M.

    1997-01-01

    Laser induced micro-rough structures (LIMS) are a by-product of laser ablation process and are created during multiple pulse irradiation on the surface of the material. Although LIMS have been found to be deleterious for the thin film deposition process, these surfaces have wide variety of applications in synthesis of adherent coatings in thermal expansion mismatched systems. Earlier models, based on interference effects of the laser beam, to explain the evolution of LIMS, are not consistent with the experimental results. Experiments were conducted on a wide variety of materials (e.g. SiC, alumina, YBaCuO superconductor, etc.) to understand the mechanisms for generation of the micro-rough structures. A novel model was developed to explain the characteristics of LIMS such as (i) feature orientation (ii) evolution of surface structures as a function of pulses, (iii) formation of LIMS within a energy window near ablation threshold and (iv) periodicity which is independent of the laser wavelength and incident angle.

  17. Development and applications of laser-induced incandescence

    NASA Technical Reports Server (NTRS)

    Vanderwal, Randy L.; Dietrich, Daniel L.; Zhou, Zhiquang; Choi, Mun Y.

    1995-01-01

    Several NASA-funded investigations focus on soot processes and radiative influences of soot in diffusion flames given their simplicity, practical significance, and potential for theoretical modeling. Among the physical parameters characterizing soot, soot volume fraction, f(sub v), a function of particle size and number density, is often of chief practical interest in these investigations, as this is the geometrical property that directly impacts radiative characteristics and the temperature field of the flame and is basic to understanding soot growth and oxidation processes. Diffusion flames, however, present a number of challenges to the determination of f(sub v) via traditional extinction measurements. Laser-induced incandescence (LII) possesses several advantages compared to line-of-sight extinction techniques for determination of f(sub v). Since LII is not a line-of-sight technique, similar to fluorescence, it possesses geometric versatility allowing spatially resolved measurements of f(sub v) in real time in nonaxisymmetric systems without using deconvolution techniques. The spatial resolution of LII is determined by the detector and imaging magnification used. Neither absorption by polycyclic aromatic hydrocarbons (PAH's) nor scattering contributes to the signal. Temporal capabilities are limited only by the laser pulse and camera gate duration, with measurements having been demonstrated with 10 ns resolution. Because of these advantages, LII should be applicable to a variety of combustion processes involving both homogeneous and heterogeneous phases. Our work has focussed on characterization of the technique as well as exploration of its capabilities and is briefly described.

  18. Slag analysis with laser-induced breakdown spectrometry.

    PubMed

    Kraushaar, M; Noll, R; Schmitz, H U

    2003-10-01

    Laser-induced breakdown spectrometry (LIBS) has been applied for multi-elemental analysis of slag samples from a steel plant. In order to avoid the time-consuming step of sample preparation, the liquid slag material can be filled in special probes. After cooling of the liquid slag and solidification, the samples can be analyzed with LIBS. Chemical analysis of slag is an essential input parameter used for numerical simulations to control liquid steel processing. The relative variation range of element concentrations in slag samples from steel production can amount to up to 30%. A multivariate calibration model is used to take into account matrix effects caused by these varying concentrations. By optimizing the measuring parameters as well as the calibration models, an agreement between the standard X-ray fluorescence (XRF) analysis and LIBS analysis in terms of the coefficient of determination r2 of 0.99 for the main analytes CaO, SiO2, and Fetot of converter slag samples was achieved. The average repeatability of the LIBS measurement for these elements in terms of the relative standard deviation of the determined concentration is improved to less than 1.0%. With these results, the basis is established for future on-line applications of LIBS in the steel-making industry for slag analysis. PMID:14639759

  19. Laser-induced thermoelastic effects can evoke tactile sensations

    PubMed Central

    Jun, Jae-Hoon; Park, Jong-Rak; Kim, Sung-Phil; Min Bae, Young; Park, Jang-Yeon; Kim, Hyung-Sik; Choi, Seungmoon; Jung, Sung Jun; Hwa Park, Seung; Yeom, Dong-Il; Jung, Gu-In; Kim, Ji-Sun; Chung, Soon-Cheol

    2015-01-01

    Humans process a plethora of sensory information that is provided by various entities in the surrounding environment. Among the five major senses, technology for touch, haptics, is relatively young and has relatively limited applications largely due to its need for physical contact. In this article, we suggest a new way for non-contact haptic stimulation that uses laser, which has potential advantages such as mid-air stimulation, high spatial precision, and long working distance. We demonstrate such tactile stimulation can be enabled by laser-induced thermoelastic effects by means of physical and perceptual studies, as well as simulations. In the physical study, the mechanical effect of laser on a human skin sample is detected using low-power radiation in accordance with safety guidelines. Limited increases (< ~2.5 °C) in temperature at the surface of the skin, examined by both thermal camera and the Monte Carlo simulation, indicate that laser does not evoke heat-induced nociceptive sensation. In the human EEG study, brain responses to both mechanical and laser stimulation are consistent, along with subjective reports of the non-nociceptive sensation of laser stimuli. PMID:26047142

  20. Laser-induced forward transfer of hybrid carbon nanostructures

    NASA Astrophysics Data System (ADS)

    Palla-Papavlu, A.; Filipescu, M.; Vizireanu, S.; Vogt, L.; Antohe, S.; Dinescu, M.; Wokaun, A.; Lippert, T.

    2016-06-01

    Chemically functionalized carbon nanowalls (CNWs) are promising materials for a wide range of applications, i.e. gas sensors, membranes for fuel cells, or as supports for catalysts. However, the difficulty of manipulation of these materials hinders their integration into devices. In this manuscript a procedure for rapid prototyping of CNWs and functionalized CNWs (i.e. decorated with SnO2 nanoparticles) is described. This procedure enables the use of laser-induced forward transfer (LIFT) as a powerful technique for printing CNWs and CNW:SnO2 pixels onto rigid and flexible substrates. A morphological study shows that for a large range of laser fluences i.e. 500-700 mJ/cm2 it is possible to transfer thick (4 μm) CNW and CNW:SnO2 pixels. Micro-Raman investigation of the transferred pixels reveals that the chemical composition of the CNWs and functionalized CNWs does not change as a result of the laser transfer. Following these results one can envision that CNWs and CNW:SnO2 pixels obtained by LIFT can be ultimately applied in technological applications.

  1. Enhancing the analytical performance of laser-induced breakdown spectroscopy

    SciTech Connect

    Cremers, D.A.; Chinni, R.C.; Pichahchy, A.E.; Thornquist, H.K.

    1998-12-31

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The objective of this work is to enhance the analytical capabilities of laser-induced breakdown spectroscopy (LIBS). LIBS is a method of elemental analysis in which powerful laser pulses are focused on a sample to form a microplasma. LIBS is perhaps the most versatile elemental analysis method, applicable to a variety of different real-world analysis problems. Therefore, it is important to enhance the capabilities of the method as much as possible. Accomplishments include: (1) demonstration of signal enhancements of 5--30 times from soils and metals using a double pulse method; (2) development of a model of the observed enhancement obtained using double pulses; (3) demonstration that the analytical performance achievable using low laser-pulse energies (10 and 25 mJ) can match that achievable using an energy of 100 mJ; and (4) demonstration that time-gated detection is not necessary with LIBS.

  2. Shock wave generated by high-energy electric spark discharge

    NASA Astrophysics Data System (ADS)

    Liu, Qingming; Zhang, Yunming

    2014-10-01

    Shock wave generated by electric spark discharge was studied experimentally and the shock wave energy was evaluated in this paper. A pressure measurement system was established to study the pressure field of the electric spark discharge process. A series of electric spark discharge experiments were carried out and the energy of the electric spark used in present study was in the range of 10 J, 100 J, and 1000 J, respectively. The shock wave energy released from the electric spark discharge process was calculated by using the overpressure values at different measurement points near the electric spark discharge center. The good consistency of shock wave energies calculated by pressure histories at different measuring points in the same electric spark discharge experiment illustrates the applicability of the weak shock wave theory in calculating the energy of shock wave induced by electric spark discharge process. The result showed that shock wave formed at the initial stage of electric spark discharge process, and the shock wave energy is only a little part of electric spark energy. From the analysis of the shock wave energy and electric spark energy, a good linear relationship between shock wave energy and electric spark energy was established, which make it possible to calculate shock wave energy by measuring characteristic parameters of electric spark discharge process instead of shock wave. So, the initiation energy of direct initiation of detonation can be determined easily by measuring the parameters of electric spark discharge process.

  3. Red-shift law of intense laser-induced electro-absorption in solids

    NASA Astrophysics Data System (ADS)

    Deng, Hong-Xiang; Zu, Hao-Yue; Wu, Shao-Yi; Sun, Kai; Zu, Xiao-Tao

    2014-02-01

    A theoretical study on the red-shift of laser-induced electro-absorption is presented. It is found that laser-induced red-shift scales with the cube root of the pump laser intensity in the optical tunneling regime and has an obvious deviation from this scale in the multi-photon regime. Our results show that in the optical tunneling regime, the laser-induced red shift has the same law as that in the direct current (DC) approximation. Though the scales are the same in the optical tunneling regime, the physical pictures in the two cases are quite different. The electro-absorption in the DC case is a tunneling-assisted transition process, while the laser-induced electro-absorption is a mixed multi-photon process.

  4. APPLICATIONS OF CAPILLARY ELECTROPHORESIS/LASER-INDUCED FLUORESCENCE DETECTION TO GROUND WATER MIGRATION STUDIES

    EPA Science Inventory

    Capillary electrophoresis (CE) has been applied to the determination of groundwater migration based on laser-induced fluorescence (LIF) detection and traditional spectrofluorimetry. The detection limits of injected dye-fluorescent whitening agent (tinopal) in the low parts per tr...

  5. Mid-infrared Molecular Emission Studies from Energetic Materials using Laser-Induced Breakdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    Brown, Ei; Hommerich, Uwe; Yang, Clayton; Trivedi, Sudhir; Samuels, Alan; Snyder, Peter

    2011-10-01

    Laser-induced breakdown spectroscopy (LIBS) is a powerful diagnostic tool for detection of trace elements by monitoring the atomic and ionic emission from laser-induced plasmas. The laser-induced plasma was produced by focusing a 30 mJ pulsed Nd:YAG laser (1064 nm) to dissociate, atomize, and ionize target molecules. In this work, LIBS emissions in the mid-infrared (MIR) region were studied for potential applications in chemical, biological, and explosives (CBE) sensing. We report on the observation of MIR emissions from energetic materials (e.g. ammonium compounds) due to laser-induced breakdown processes. All samples showed LIBS-triggered oxygenated breakdown products as well as partially dissociated and recombination molecular species. More detailed results of the performed MIR LIBS studies on the energetic materials will be discussed at the conference.

  6. Penta(cyclopentadienyl)-[eta]5-cyclopentadienylmanganesetricarbonyl: Structure and laser-induced conversion to fullerenes

    SciTech Connect

    Barrow, Mark P.; Cammack, J. Kevin; Goebel, Matthias; Wasser, Ian M.; Vollhardt, K.Peter C.; Drewello, Thomas

    1998-08-28

    The title compound [Cp5CpMn(CO)3], 1, has been characterized by X-ray crystallography and shown by laser-induced desorption/ionization (LDI) to undergo coalescence to fullerene C60 and other carbon clusters.

  7. Laser-induced fluorescence detection strategies for sodium atoms and compounds in high-pressure combustors

    NASA Technical Reports Server (NTRS)

    Weiland, Karen J. R.; Wise, Michael L.; Smith, Gregory P.

    1993-01-01

    A variety of laser-induced fluorescence schemes were examined experimentally in atmospheric pressure flames to determine their use for sodium atom and salt detection in high-pressure, optically thick environments. Collisional energy transfer plays a large role in fluorescence detection. Optimum sensitivity, at the parts in 10 exp 9 level for a single laser pulse, was obtained with the excitation of the 4p-3s transition at 330 nm and the detection of the 3d-3p fluorescence at 818 nm. Fluorescence loss processes, such as ionization and amplified spontaneous emission, were examined. A new laser-induced atomization/laser-induced fluorescence detection technique was demonstrated for NaOH and NaCl. A 248-nm excimer laser photodissociates the salt molecules present in the seeded flames prior to atom detection by laser-induced fluorescence.

  8. Electro-spark deposition technology

    SciTech Connect

    Johnson, R.N.

    1996-08-01

    Electro-Spark Deposition (ESD) is a micro-welding process that uses short duration, high-current electrical pulses to deposit or alloy a consumable electrode material onto a metallic substrate. The ESD process was developed to produce coatings for use in severe environments where most other coatings fail. Because of the exceptional damage resistance of these coatings, and the versatility of the process to apply a wide variety of alloys, intermetallics, and cermets to metal surfaces, the ESD process has been designated as one of the enabling technologies for advanced energy systems. Developments include producing iron aluminide-based coatings with triple the corrosion resistance of the best previous Fe{sub 3}Al coatings, coatings with refractory metal diffusion barriers and multi layer coatings for achieving functionally gradient properties between the substrate and the surface. One of the most significant breakthroughs to occur in the last dozen years is the discovery of a process regime that promises an order of magnitude increase in deposition rates and achievable coating thicknesses. Since this regime borders on and exceeds the normal operating limits of existing ESD electronic equipment, development is in progress to produce equipment that can consistently and reliably achieve these conditions for a broad range of materials. Progress so far has resulted in a consistent 500% increase in deposition rates, and greater rates still are anticipated. Technology transfer activities are a significant portion of the ESD program effort. Notable successes now include the start-up of a new business to commercialize the ESD technology, the incorporation of the process into the operations of a major gas turbine manufacturer, major new applications in gas turbine blade and steam turbine blade protection and repair, and in military, medical, metal-working, and recreational equipment applications.

  9. Reflectance, scattering, and laser induced fluorescence for the detection of dental caries

    NASA Astrophysics Data System (ADS)

    Drakaki, Eleni; Makropoulou, Myrsini; Khabbaz, Maruan; Serafetinides, Alexandros A.

    2003-10-01

    Directional dependence of reflected laser light and of the laser induced fluorescence signals performed both on the intact hard dental tissues, such as enamel, dentine, cementum and on the tissues pathologically affected by caries (superficial, intermediate, and deep). The laser induced fluorescence spectra were collected at different angles of observation and were correlated with the different scattering and reflectance properties of the hard dental samples

  10. Laser-induced periodic annular surface structures on fused silica surface

    SciTech Connect

    Liu, Yi; Brelet, Yohann; Forestier, Benjamin; Houard, Aurelien; Yu, Linwei; Deng, Yongkai; Jiang, Hongbing

    2013-06-24

    We report on the formation of laser-induced periodic annular surface structures on fused silica irradiated with multiple femtosecond laser pulses. This surface morphology emerges after the disappearance of the conventional laser induced periodic surface structures, under successive laser pulse irradiation. It is independent of the laser polarization and universally observed for different focusing geometries. We interpret its formation in terms of the interference between the reflected laser field on the surface of the damage crater and the incident laser pulse.

  11. Spectroscopic analysis of fire suppressants and refrigerants by laser-induced breakdown spectroscopy.

    PubMed

    Lancaster, E D; McNesby, K L; Daniel, R G; Miziolek, A W

    1999-03-20

    Laser-induced breakdown spectroscopy is evaluated as a means of detecting the fire suppressants CF(3)Br, C(3)F(7)H, and CF(4) and the refrigerant C(2)F(4)H(2). The feasibility of employing laser-induced breakdown spectroscopy for time- and space-resolved measurement of these agents during use, storage, and recharge is discussed. Data are presented that demonstrate the conditions necessary for optimal detection of these chemicals. PMID:18305769

  12. Properties and Applications of Laser-Induced Gratings in Rare Earth Doped Glasses.

    NASA Astrophysics Data System (ADS)

    Behrens, Edward Grady

    Scope and method of study. Four-wave-mixing techniques were used in an attempt to create permanent laser-induced grating in Pr^{3+}-, Nd ^{3+}-, Eu^ {3+}-, and Er^{3+ }-doped glasses. The permanent laser-induced grating signal intensity and build-up and erase times were investigated as function of the write beam crossing angle, write beam power, and temperature. Thermal lensing measurements were conducted on Eu^{3+} - and Nd^{3+}-doped glasses and room temperature Raman and resonant Raman spectra were obtained for Eu^{3+}-doped glasses. The permanent laser-induced grating signal intensity was studied in Eu^{3+} -doped alkali-metal glasses as a function of the alkali -metal network modifier ion and a model was developed by treating the sample as a two-level system. Optical device applications of the permanent laser-induced gratings were studied by creating some simple devices. Findings and conclusions. Permanent laser-induced gratings were created in the Pr^{3+ }- and Eu^{3+} -doped glasses. The permanent laser-induced grating is associated with a structural phase change of the glass host. The structural change is produced by high energy phonons which are emitted by radiationless relaxation processes of the rare earth ion. Nd^{3+} and Er^{3+} relax nonradiatively by the emission of phonons of much lower energy which are unable to produce the structural phase change needed to form a permanent laser-induced grating. The difference in energy of the emitted phonons is responsible for the differing characteristics of the thermal lensing experiments. The model does a good job of predicting the experimental results for the asymmetry and other parameters of the two-level system. The application of these laser -induced gratings for optical devices demonstrates their importance to optical technology.

  13. Simultaneous measurement of Raman scattering and laser-induced OH fluorescence in nonpremixed turbulent jet flames.

    PubMed

    Barlow, R S; Dibble, R W; Lucht, R P

    1989-03-01

    Spontaneous Raman scattering and laser-induced fluorescence are combined to perform simultaneous point measurements of major species concentrations, temperature, and hydroxyl radical concentration in turbulent nonpremixed flames. The Raman-scattering data for major species concentrations and temperature characterize the instantaneous, local, collisional quenching environment of the OH molecule. Collisional quenching corrections are applied for each laser shot so that absolute hydroxyl concentrations are obtained in turbulent flames using linear laser-induced fluorescence. PMID:19749889

  14. Laser-induced pattern formation in liquid sulfur. An indication of laser-induced phase transition to ordered polymer

    NASA Astrophysics Data System (ADS)

    Sakaguchi, Y.; Tamura, K.

    2007-04-01

    Liquid sulfur is a well-known liquid which exhibits a polymerization transition at T_p=159 °C. Recently, it was found from our experiments that such a transition can be induced below Tp through laser illumination and that an iridescent pattern appears under strong illumination with a pulsed laser of more than 60 mJ/cm2 pulse. It is proposed that the visible change in iridescence is due to a macroscopic reconstruction of laser-generated polymers and that a laser-induced phase transition takes place from a freely expanded polymer phase to an ordered polymer phase when increasing the laser illumination. To further examine this possibility, the time variation of the iridescent pattern has been fully investigated using a macro lens, a polarized microscope and an optical microscope. In an analysis of the iridescent pattern, a rapid decrease in the area was observed after an initial slow decrease, suggesting a type of phase transition. Results from the observation of a quenched sulfur sample with a polarized microscope gave evidence that the iridescent region consists of polymers. Through observation of the liquid with a microscope, a striped pattern with micrometer sized spacing was noted in the iridescent pattern. A drastic color change was observed in the pattern from its generation to its disappearance. Sample thickness dependence of the pattern was also observed. These results were well explained by assuming the self-arrangement of laser-generated colloidal polymers.

  15. Comparative study of INPIStron and spark gap

    NASA Technical Reports Server (NTRS)

    Han, Kwang S.; Lee, Ja H.

    1993-01-01

    An inverse pinch plasma switch, INPIStron, was studied in comparison to a conventional spark gap. The INPIStron is under development for high power switching applications. The INPIStron has an inverse pinch dynamics, opposed to Z-pinch dynamics in the spark gap. The electrical, plasma dynamics and radiative properties of the closing plasmas have been studied. Recently the high-voltage pulse transfer capabilities or both the INPIStron and the spark gap were also compared. The INPIStron with a low impedance Z = 9 ohms transfers 87 percent of an input pulse with a halfwidth of 2 mu s. For the same input pulse the spark gap of Z = 100 ohms transfers 68 percent. Fast framing and streak photography, taken with an TRW image converter camera, was used to observe the discharge uniformity and closing plasma speed in both switches. In order to assess the effects of closing plasmas on erosion of electrode material, emission spectra of two switches were studied with a spectrometer-optical multi channel analyzer (OMA) system. The typical emission spectra of the closing plasmas in the INPIStron and the spark gap showed that there were comparatively weak carbon line emission in 658.7 nm and copper (electrode material) line emissions in the INPIStron, indicating low erosion of materials in the INPIStron.

  16. Pulsed laser-induced evaporation of liquids and its applications

    NASA Astrophysics Data System (ADS)

    Kim, Dongsik

    The interaction of laser irradiation with materials is very important in a variety of laser-based manufacturing processes and scientific studies. Particularly, the interaction of a short laser pulse with absorbing liquids or solid materials in contact with liquid is central to a number of applications, including laser cleaning of microcontaminants, pulsed laser deposition of thin film materials, laser tissue removal, and laser surface texturing. In this dissertation, experimental and theoretical works on the following topics are summarized: (1) physical mechanisms of pulsed laser induced ablation of absorbing liquids at laser fluence below the plasma ignition threshold, (2) analysis of rapid vaporization at the absorbing solid/transparent liquid interface, (3) laser cleaning of surface contaminates. Concerning the first topic, the near-threshold ablation process at low laser fluences and the high power explosive vaporization process accompanying subsequent ablation plume dynamics are elucidated. Acoustic-wave detection by a piezoelectric pressure transducer, visualization by laser flash photography, and optical reflection/transmission measurements are carried out for the in-situ diagnosis of the process. Quantification of the acoustic-field generation and detection of the bubble-nucleation dynamics in the rapid vaporization at the solid liquid interface are performed by photoacoustic beam deflection technique and optical interferometry, respectively. Finally, experiments are carried out for the development of a practical laser cleaning tool and the analysis of the contaminant-removal mechanism. The results show that the near-threshold ablation by a short laser pulse is initiated by the tensile component of the thermoelastic stress without significant increase of liquid temperature at low laser fluences. On the other hand, if the heating rate is rapid enough to achieve high degree of superheating of the liquid, explosive vaporization takes place due to the abrupt

  17. Laser induced x-ray `RADAR' particle physics model

    NASA Astrophysics Data System (ADS)

    Lockley, D.; Deas, R.; Moss, R.; Wilson, L. A.; Rusby, D.; Neely, D.

    2016-05-01

    The technique of high-power laser-induced plasma acceleration can be used to generate a variety of diverse effects including the emission of X-rays, electrons, neutrons, protons and radio-frequency radiation. A compact variable source of this nature could support a wide range of potential applications including single-sided through-barrier imaging, cargo and vehicle screening, infrastructure inspection, oncology and structural failure analysis. This paper presents a verified particle physics simulation which replicates recent results from experiments conducted at the Central Laser Facility at Rutherford Appleton Laboratory (RAL), Didcot, UK. The RAL experiment demonstrated the generation of backscattered X-rays from test objects via the bremsstrahlung of an incident electron beam, the electron beam itself being produced by Laser Wakefield Acceleration. A key initial objective of the computer simulation was to inform the experimental planning phase on the predicted magnitude of the backscattered X-rays likely from the test objects. This objective was achieved and the computer simulation was used to show the viability of the proposed concept (Laser-induced X-ray `RADAR'). At the more advanced stages of the experimental planning phase, the simulation was used to gain critical knowledge of where it would be technically feasible to locate key diagnostic equipment within the experiment. The experiment successfully demonstrated the concept of X-ray `RADAR' imaging, achieved by using the accurate timing information of the backscattered X-rays relative to the ultra-short laser pulse used to generate the electron beam. By using fast response X-ray detectors it was possible to derive range information for the test objects being scanned. An X-ray radar `image' (equivalent to a RADAR B-scan slice) was produced by combining individual X-ray temporal profiles collected at different points along a horizontal distance line scan. The same image formation process was used to generate

  18. Laser induced damage in optical materials: tenth ASTM symposium.

    PubMed

    Glass, A J; Guenther, A H

    1979-07-01

    The tenth annual Symposium on Optical Materials for High Power Lasers (Boulder Damage Symposium) was held at the National Bureau of Standards in Boulder, Colorado, 12-14 September 1978. The symposium was held under the auspices of ASTM Committee F-1, Subcommittee on Laser Standards, with the joint sponsorship of NBS, the Defense Advanced Research Project Agency, the Department of Energy, and the Office of Naval Research. About 175 scientists attended, including representatives of the United Kingdom, France, Canada, Japan, West Germany, and the Soviet Union. The symposium was divided into sessions concerning the measurement of absorption characteristics, bulk material properties, mirrors and surfaces, thin film damage, coating materials and design, and breakdown phenomena. As in previous years, the emphasis of the papers presented was directed toward new frontiers and new developments. Particular emphasis was given to materials for use from 10.6 microm to the UV region. Highlights included surface characterization, thin film-substrate boundaries, and advances in fundamental laser-matter threshold interactions and mechanisms. The scaling of damage thresholds with pulse duration, focal area, and wavelength was also discussed. In commemoration of the tenth symposium in this series, a number of comprehensive review papers were presented to assess the state of the art in various facets of laser induced damage in optical materials. Alexander J. Glass of Lawrence Livermore Laboratory and Arthur H. Guenther of the Air Force Weapons Laboratory were co-chairpersons. The eleventh annual symposium is scheduled for 30-31 October 1979 at the National Bureau of Standards, Boulder, Colorado. PMID:20212622

  19. Lanthanide-based laser-induced phosphorescence for spray diagnostics

    NASA Astrophysics Data System (ADS)

    van der Voort, D. D.; Maes, N. C. J.; Lamberts, T.; Sweep, A. M.; van de Water, W.; Kunnen, R. P. J.; Clercx, H. J. H.; van Heijst, G. J. F.; Dam, N. J.

    2016-03-01

    Laser-induced phosphorescence (LIP) is a relatively recent and versatile development for studying flow dynamics. This work investigates certain lanthanide-based molecular complexes for their use in LIP for high-speed sprays. Lanthanide complexes in solutions have been shown to possess long phosphorescence lifetimes (˜1-2 ms) and to emit light in the visible wavelength range. In particular, europium and terbium complexes are investigated using fluorescence/phosphorescence spectrometry, showing that europium-thenoyltrifluoracetone-trioctylphosphineoxide (Eu-TTA-TOPO) can be easily and efficiently excited using a standard frequency-tripled Nd:YAG laser. The emitted spectrum, with maximum intensity at a wavelength of 614 nm, is shown not to vary strongly with temperature (293-383 K). The decay constant of the phosphorescence, while independent of ambient pressure, decreases by approximately 12 μs/K between 323 and 373 K, with the base level of the decay constant dependent on the used solvent. The complex does not luminesce in the gas or solid state, meaning only the liquid phase is visualized, even in an evaporating spray. By using an internally excited spray containing the phosphorescent complex, the effect of vaporization is shown through the decrease in measured intensity over the length of the spray, together with droplet size measurements using interferometric particle imaging. This study shows that LIP, using the Eu-TTA-TOPO complex, can be used with different solvents, including diesel surrogates. Furthermore, it can be easily handled and used in sprays to investigate spray breakup and evaporation.

  20. Liquid Jet Formation in Laser-Induced Forward Transfer

    NASA Astrophysics Data System (ADS)

    Brasz, C. Frederik

    Laser-induced forward transfer (LIFT) is a direct-write technique capable of printing precise patterns of a wide variety of materials. In this process, a laser pulse is focused through a transparent support and absorbed in a thin donor film, propelling material onto an adjacent acceptor substrate. For fluid materials, this transfer occurs through the formation of a narrow liquid jet, which eventually pinches off due to surface tension. This thesis examines in detail the fluid mechanics of the jet formation process occurring in LIFT. The main focus is on a variant of LIFT known as blister-actuated LIFT (BA-LIFT), in which the laser pulse is absorbed in an ink-coated polymer layer, rapidly deforming it locally into a blister to induce liquid jet formation. The early-time response of a fluid layer to a deforming boundary is analyzed with a domain perturbation method and potential-flow simulations, revealing scalings for energy and momentum transfer to the fluid and providing physical insight on how and why a jet forms in BA-LIFT. The remaining chapters explore more complex applications and modifications of LIFT. One is the possibility of high-repetition rate printing and limits on time delay and separation between pulses imposed by a tilting effect found for adjacent jets. Another examines a focusing effect achieved by perturbing the interface with ring-shaped disturbances. The third contains an experimental study of LIFT using a silver paste as the donor material instead of a Newtonian liquid. The transfer mechanism is significantly different, although with repeated pulses at one location, a focusing effect is again observed. All three of these chapters investigate how perturbations to the interface can strongly influence the jet formation process.

  1. Infrared laser induced plasma diagnostics of silver target

    SciTech Connect

    Ahmat, L. Nadeem, Ali; Ahmed, I.

    2014-09-15

    In the present work, the optical emission spectra of silver (Ag) plasma have been recorded and analyzed using the laser induced breakdown spectroscopy technique. The emission line intensities and plasma parameters were investigated as a function of lens to sample distance, laser irradiance, and distance from the target surface. The electron number density (n{sub e}) and electron temperature (T{sub e}) were determined using the Stark broadened line profile and Boltzmann plot method, respectively. A gradual increase in the spectral line intensities and the plasma parameters, n{sub e} from 2.89 × 10{sup 17} to 3.92 × 10{sup 17 }cm{sup −3} and T{sub e} from 4662 to 8967 K, was observed as the laser irradiance was increased 2.29 × 10{sup 10}–1.06 × 10{sup 11} W cm{sup −2}. The spatial variations in n{sub e} and T{sub e} were investigated from 0 to 5.25 mm from the target surface, yielding the electron number density from 4.78 × 10{sup 17} to 1.72 × 10{sup 17 }cm{sup −3} and electron temperature as 9869–3789 K. In addition, the emission intensities and the plasma parameters of silver were investigated by varying the ambient pressure from 0.36 to 1000 mbars.

  2. Characterization Of High Explosives Detonations Via Laser-Induced Plasmas

    SciTech Connect

    Villa-Aleman, E.

    2015-10-08

    One objective of the Department of Energy’s National Security Administration is to develop technologies that can help the United States government to detect foreign nuclear weapons development activities. The realm of high explosive (HE) experiments is one of the key areas to assess the nuclear ambitions of a country. SRNL has participated in the collection of particulates from HE experiments and characterized the material with the purpose to correlate particulate matter with HE. Since these field campaigns are expensive, on-demand simulated laboratory-scale explosion experiments are needed to further our knowledge of the chemistry and particle formation in the process. Our goal is to develop an experimental test bed in the laboratory to test measurement concepts and correlate particle formation processes with the observables from the detonation fireball. The final objective is to use this knowledge to tailor our experimental setups in future field campaigns. The test bed uses pulsed laser-induced plasmas to simulate micro-explosions, with the intent to study the temporal behavior of the fireball observed in field tests. During FY15, a plan was prepared and executed which assembled two laser ablation systems, procured materials for study, and tested a Step-Scan Fourier Transform Infrared Spectrometer (SS-FTIR). Designs for a shadowgraph system for shock wave analysis, design for a micro-particulate collector from ablated pulse were accomplished. A novel spectroscopic system was conceived and a prototype system built for acquisition of spectral/temporal characterization of a high speed event such as from a high explosive detonation. Experiments and analyses will continue into FY16.

  3. Laser-induced fluorescence in diagnosis of dental caries

    NASA Astrophysics Data System (ADS)

    Drakaki, Eleni A.; Makropoulou, Mersini I.; Khabbaz, Maruan; Serafetinides, Alexandros A.

    2003-09-01

    laser induces better discrimination in deep caries diagnosis.

  4. [Laser Induced Fluorescence Spectrum Characteristics of Paddy under Nitrogen Stress].

    PubMed

    Yang, Jian; Shi, Shuo; Gong, Wei; Du, Lin; Zhu, Bo; Ma, Ying-ying; Sun, Jia

    2016-02-01

    Order to guide fertilizing andreduce waste of resources as well as enviro nmental pollution, especially eutrophication, which are caused by excessive fertilization, a system of laser-induced fluorescence(LIF) was built. The system aimed to investigate the correlation between nitrogen(N) content of paddy leaf and the fluorescence intensity. We measuredNcontent and SPAD of paddy leaf (the samples came from the second upper leaves of paddy in tillering stage and the study area was located in Jianghan plain of China) by utilizing the Plant Nutrient (Tester TYS-3N). The fluorescence spectrum was also obtained by using the systembuilt based on theLIFtechnology. Fluorescence spectra of leaf with different N-content were collected and then a fluorescence spectra database wasestablished. It is analyzed that the relationship between the parameters of fluorescence (F₇₄₀/F₆₈₅ is the ratio of fluorescence intensity of 740 nm. dividing that of 685 nm) and the N level of paddy. It is found that the effect of different N-content on the fluorescence spectrum characteristics is significant. The experiment demonstrated the positive correlation between fluorescence parameters and paddy leaf N-content. Results showed a positive linear correlation between the ratio of peak fluorescence (F₇₄₀/F₆₈₅) and N-content The correlation coefficient (r) reached 0.871 8 and the root mean square error (RMSE) was 0.076 82. The experiment demonstrated that LIF spectroscopy detection technology has the advantages of rapidand non-destructive measurement, and it also has the potential to measure plant content of nutrient elements. It will provide a more accurate remote sensing method to rapidly detect the crop nitrogen levels. PMID:27209764

  5. Laser Induced Fluorescence Diagnostic for the ASTRAL Plasma Source.

    NASA Astrophysics Data System (ADS)

    Boivin, Robert; Kamar, Ola; Munoz, Jorge

    2006-10-01

    A Laser Induced Fluorescence (LIF) diagnostic is presented in this poster. The ion temperature measurements are made in the ASTRAL (Auburn Steady sTate Research fAciLity) helicon plasma source using a diode laser based LIF diagnostic. ASTRAL produces Ar plasmas with the following parameters: ne = 10^10 to 10^13 cm-3, Te = 2 to 10 eV and Ti = 0.03 to 0.5 eV. A series of 7 large coils produce an axial magnetic field up to 1.3 kGauss. Operating pressure varies from 0.1 to 100 mTorr and any gas can be used for the discharge. A fractional helix antenna is used to introduce rf power up to 2 kWatt. A number of diagnostics are presently installed on the plasma device (Langmuir Probe, Spectrometer, LIF system). The LIF diagnostic makes use of a diode laser with the following characteristics: 1.5 MHz bandwidth, Littrow external cavity, mode-hop free tuning range up to 16 GHz, total power output of about 15 mW. The wavelength is measured by a precision wavemeter and frequent monitoring prevents wavelength drift. For Ar plasma, a new LIF scheme has been developed. The laser tuned at 686.354 nm, is used to pump the 3d^4F5/2 Ar II metastable level to the 4p^4D5/2 state. The fluorescence radiation between the 4p^4D5/2 and the 4s^4P3/2 terms (442.6 nm) is monitored by a PMT.

  6. Application of Laser Induced Breakdown Spectroscopy under Polar Conditions

    NASA Astrophysics Data System (ADS)

    Clausen, J. L.; Hark, R.; Bol'shakov, A.; Plumer, J.

    2015-12-01

    Over the past decade our research team has evaluated the use of commercial-off-the-shelf laser-induced breakdown spectroscopy (LIBS) for chemical analysis of snow and ice samples under polar conditions. One avenue of research explored LIBS suitability as a detector of paleo-climate proxy indicators (Ca, K, Mg, and Na) in ice as it relates to atmospheric circulation. LIBS results revealed detection of peaks for C and N, consistent with the presence of organic material, as well as major ions (Ca, K, Mg, and Na) and trace metals (Al, Cu, Fe, Mn, Ti). The detection of Ca, K, Mg, and Na confirmed that LIBS has sufficient sensitivity to be used as a tool for characterization of paleo-climate proxy indicators in ice-core samples. Techniques were developed for direct analysis of ice as well as indirect measurements of ice via melting and filtering. Pitfalls and issues of direct ice analysis using several cooling techniques to maintain ice integrity will be discussed. In addition, a new technique, laser ablation molecular isotopic spectroscopy (LAMIS) was applied to detection of hydrogen and oxygen isotopes in ice as isotopic analysis of ice is the main tool in paleoclimatology and glaciology studies. Our results demonstrated that spectra of hydroxyl isotopologues 16OH, 18OH, and 16OD can be recorded with a compact spectrograph to determine hydrogen and oxygen isotopes simultaneously. Quantitative isotopic calibration for ice analysis can be accomplished using multivariate chemometric regression as previously realized for water vapor. Analysis with LIBS and LAMIS required no special sample preparation and was about ten times faster than analysis using ICP-MS. Combination of the two techniques in one portable instrument for in-field analysis appears possible and would eliminate the logistical and cost issues associated with ice core management.

  7. Spectrally resolved laser-induced fluorescence for bioaerosols standoff detection

    NASA Astrophysics Data System (ADS)

    Buteau, Sylvie; Stadnyk, Laurie; Rowsell, Susan; Simard, Jean-Robert; Ho, Jim; Déry, Bernard; McFee, John

    2007-09-01

    An efficient standoff biological warfare detection capability could become an important asset for both defence and security communities based on the increasing biological threat and the limits of the presently existing protection systems. Defence R&D Canada (DRDC) has developed, by the end of the 90s, a standoff bioaerosol sensor prototype based on intensified range-gated spectrometric detection of Laser Induced Fluorescence (LIF). This LIDAR system named SINBAHD monitors the spectrally resolved LIF originating from inelastic interactions with bioaerosols present in atmospheric cells customizable in size and in range. SINBAHD has demonstrated the capability of near real-time detection and classification of bioaerosolized threats at multi-kilometre ranges. In spring 2005, DRDC has initiated the BioSense demonstration project, which combines the SINBAHD technology with a geo-referenced Near InfraRed (NIR) LIDAR cloud mapper. SINBAHD is now being used to acquire more signatures to add in the spectral library and also to optimize and test the new BioSense algorithm strategy. In September 2006, SINBAHD has participated in a two-week trial held at DRDC-Suffield where different open-air wet releases of live and killed bioagent simulants, growth media and obscurants were performed. An autoclave killing procedure was performed on two biological materials (Bacillus subtilis var globigii or BG, and Bacillus thuringiensis or Bt) before being aerosolized, disseminated and spectrally characterized with SINBAHD. The obtained results showed no significant impact of this killing process on their normalised spectral signature in comparison with their live counterparts. Correlation between the detection signals from SINBAHD, an array of slit samplers and a FLuorescent Aerosol Particle Sensor (C-FLAPS) was obtained and SINBAHD's sensitivity could then be estimated. At the 2006 trial, a detection limit of a few tens of Agent Containing Particles per Liter of Air (ACPLA) was obtained

  8. Single shot thermometry using laser induced thermal grating

    NASA Astrophysics Data System (ADS)

    Qu, Pubo; Guan, Xiaowei; Zhang, Zhenrong; Wang, Sheng; Li, Guohua; Ye, Jingfeng; Hu, Zhiyun

    2015-05-01

    With the concern of environmental protection and reducing the fossil fuel consumption, combustion processes need to be more efficient and less contaminable. Therefore, the ability to obtain important thermophysical parameters is crucial to combustion research and combustor design. Traditional surveying techniques were difficult to apply in a confined space, especially the physically intrusions of detectors can alter the combustion processes. Laser-based diagnostic techniques, like CARS, SVRS, PLIF and TDLAS, allow the in situ, non-intrusive, spatially and temporally resolved measurements of combustion parameters in hostile environments. We report here a new non-intrusive optical diagnostic technique, based on laser-induced thermal grating. Thermal gratings generated in NO2/N2 binary mixtures, arise from the nonlinear interaction between the medium and the light radiation from the interference of two pulsed, frequency-doubled Nd:YAG lasers (532 nm). This leads to the formation of a dynamic grating through the resonant absorption and the subsequent collisional relaxation. By the temporally resolved detection of a continuous wave, frequency-doubled Nd:YVO4 probe laser beam (671 nm) diffracted by LITG. The temporal behavior of the signal is a function of the local temperature and other properties of gas, various parameters of the target gas can be extracted by analyzing the signal. The accurate singleshot temperature measurements were carried out at different test conditions using a stainless steel pressurized cell, data averaged on 100 laser shots were compared with simultaneously recorded thermocouple data, and the results were consistent with each other. The LITG signal is shown to grow with increasing the gas pressure and is spatially coherent, which makes the LITG thermometry technique a promising candidate in high pressure environments.

  9. A handheld laser-induced fluorescence detector for multiple applications.

    PubMed

    Fang, Xiao-Xia; Li, Han-Yang; Fang, Pan; Pan, Jian-Zhang; Fang, Qun

    2016-04-01

    In this paper, we present a compact handheld laser-induced fluorescence (LIF) detector based on a 450 nm laser diode and quasi-confocal optical configuration with a total size of 9.1 × 6.2 × 4.1 cm(3). Since there are few reports on the use of 450 nm laser diode in LIF detection, especially in miniaturized LIF detector, we systematically investigated various optical arrangements suitable for the requirements of 450 nm laser diode and system miniaturization, including focusing lens, filter combination, and pinhole, as well as Raman effect of water at 450 nm excitation wavelength. As the result, the handheld LIF detector integrates the light source (450 nm laser diode), optical circuit module (including a 450 nm band-pass filter, a dichroic mirror, a collimating lens, a 525 nm band-pass filter, and a 1.0mm aperture), optical detector (miniaturized photomultiplier tube), as well as electronic module (including signal recording, processing and displaying units). This detector is capable of working independently with a cost of ca. $2000 for the whole instrument. The detection limit of the instrument for sodium fluorescein solution is 0.42 nM (S/N=3). The broad applicability of the present system was demonstrated in capillary electrophoresis separation of fluorescein isothiocyanate (FITC) labeled amino acids and in flow cytometry of tumor cells as an on-line LIF detector, as well as in droplet array chip analysis as a LIF scanner. We expect such a compact LIF detector could be applied in flow analysis systems as an on-line detector, and in field analysis and biosensor analysis as a portable universal LIF detector. PMID:26838391

  10. Laser-induced growth of nanocrystals embedded in porous materials

    NASA Astrophysics Data System (ADS)

    Capoen, Bruno; Chahadih, Abdallah; El Hamzaoui, Hicham; Cristini, Odile; Bouazaoui, Mohamed

    2013-06-01

    Space localization of the linear and nonlinear optical properties in a transparent medium at the submicron scale is still a challenge to yield the future generation of photonic devices. Laser irradiation techniques have always been thought to structure the matter at the nanometer scale, but combining them with doping methods made it possible to generate local growth of several types of nanocrystals in different kinds of silicate matrices. This paper summarizes the most recent works developed in our group, where the investigated nanoparticles are either made of metal (gold) or chalcogenide semiconductors (CdS, PbS), grown in precursor-impregnated porous xerogels under different laser irradiations. This review is associated to new results on silver nanocrystals in the same kind of matrices. It is shown that, depending on the employed laser, the particles can be formed near the sample surface or deep inside the silica matrix. Photothermal and/or photochemical mechanisms may be invoked to explain the nanoparticle growth, depending on the laser, precursor, and matrix. One striking result is that metal salt reduction, necessary to the production of the corresponding nanoparticles, can efficiently occur due to the thermal wrenching of electrons from the matrix itself or due to multiphoton absorption of the laser light by a reducer additive in femtosecond regime. Very localized semiconductor quantum dots could also be generated using ultrashort pulses, but while PbS nanoparticles grow faster than CdS particles due to one-photon absorption, this better efficiency is counterbalanced by a sensitivity to oxidation. In most cases where the reaction efficiency is high, particles larger than the pores have been obtained, showing that a fast diffusion of the species through the interconnected porosity can modify the matrix itself. Based on our experience in these techniques, we compare several examples of laser-induced nanocrystal growth in porous silica xerogels, which allows

  11. Characterisation of CFRP surface contamination by laser induced fluorescence

    NASA Astrophysics Data System (ADS)

    Malinowski, Pawel H.; Sawczak, Miroslaw; Wandowski, Tomasz; Ostachowicz, Wieslaw M.; Cenian, Adam

    2014-03-01

    The application of Carbon Fibre Reinforced Polymers (CFRP) in aeronautics has been increasing. The CFRP elements are joint using rivets and adhesive bonding. The reliability of the bonding limits the use of adhesive bonding for primary aircraft structures, therefore it is important to assess the bond quality. The performance of adhesive bonds depends on the physico-chemical properties of the adhered surfaces. This research is focused on characterization of surfaces before bonding. In-situ examination of large surface materials, determine the group of methods that are preferred. The analytical methods should be non-destructive, enabling large surface analysis in relatively short time. In this work a spectroscopic method was tested that can be potentially applied for surface analysis. Four cases of surface condition were investigated that can be encountered either in the manufacturing process or during aircraft service. The first case is related to contamination of CFRP surface with hydraulic fluid. This fluid reacts with water forming a phosphoric acid that can etch the CFRP. Second considered case was related to silicone-based release agent contamination. These agents are used during the moulding process of composite panels. Third case involved moisture content in CFRP. Moisture content lowers the adhesion quality and leads to reduced performance of CFRP resulting in reduced performance of the adhesive bond. The last case concentrated on heat damage of CFRP. It was shown that laser induced fluorescence method can be useful for non-destructive evaluation of CFRP surface and some of the investigated contaminants can be easily detected.

  12. Analysis of slags using laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Sanghapi, Hervé K.; Ayyalasomayajula, Krishna K.; Yueh, Fang Y.; Singh, Jagdish P.; McIntyre, Dustin L.; Jain, Jinesh C.; Nakano, Jinichiro

    2016-01-01

    The feasibility of laser-induced breakdown spectroscopy (LIBS) for the analysis of gasification slags was investigated by comparing LIBS results to the results of an ICP-OES analyzer. A small amount of slag sample was placed on a piece of double sided adhesive tape attached to a glass microscope slide and analyzed for Al, Ca, Fe, Si, and V which are major elements found in slags. The partial least squares regression (PLS-R) and univariate simple linear regression (SLR) calibration methods indicated that apart from V (accuracy up to + 20%) the accuracy of analysis varies within 0.35-6.5% for SLR and 0.06-10% for PLS-R. A paired-sample t-test within the 95% confidence level yielded p-values greater than 0.05, meaning no appreciable statistical difference was observed between the univariate SLR with internal standardization and the multivariate PLS-R for most of the analytes. From the results obtained in this work, LIBS response varies depending on the element and the technique used for quantitative analysis. Simultaneous use of the univariate calibration curves with internal standard (intensity ratio) and PLS regression in multi-elemental analysis can help reduce the matrix effect of slags associated to their high variation in concentration. Overall, these results demonstrate the capability of LIBS as an alternative technique for analyzing gasification slags. Estimated limits of detection for Al, Ca, Fe, Si and V were 0.167, 0.78, 0.171, 0.243 and 0.01 wt.%, respectively.

  13. Improved assessment of laser-induced choroidal neovascularization

    PubMed Central

    Toma, Hassanain S.; Barnett, Joshua M.; Penn, John S.; Kim, Stephen J.

    2011-01-01

    The primary objective of this study was to develop and evaluate new methods of analyzing laser-induced choroidal neovascularization (CNV), in order to make recommendations for improving the reporting of experimental CNV in the literature. Six laser burns of sufficient power to rupture Bruch's membrane were concentrically placed in each eye of 18 adult Norway rats. Eyes received intravitreal injections of either triamcinolone acetonide, ketorolac, or balanced salt solution (BSS). Fluorescein angiography (FA) was performed 2 and 3 weeks after injection, followed by choroidal flat mount preparation. Vascular leakage on FAs and vascular budding on choroidal mounts were quantified by measuring either the cross-sectional area of each CNV lesion contained within the best-fitting polygon using Adobe Photoshop (Lasso Technique or Quick Selection Technique), or the area of bright pixels within a lesion using Image-Pro Plus. On choroidal mounts, the Lasso Technique and Image-Pro Plus detected a significant difference in lesion size between either ketorolac or triamcinolone when compared to BSS, while the Quick Selection Technique did not (Lasso Technique, 0.78 and 0.64; Image-Pro Plus, 0.77 and 0.65). On FA, the Lasso Technique and Quick Selection Technique detected a significant difference in lesion size between either ketorolac or triamcinolone when compared to BSS, while Image-Pro Plus did not (Lasso Tool, 0.81 and 0.54; Quick Selection Tool, 0.76 and 0.57). Choroidal mounts and FA are both valuable for imaging experimental CNV. Adobe Photoshop and Image-Pro Plus are both able to detect subtle differences in CNV lesion size, when images are not manipulated. The combination of choroidal mounts and FA provides a more comprehensive assessment of CNV anatomy and physiology. PMID:20553963

  14. Laser-induced selective copper plating of polypropylene surface

    NASA Astrophysics Data System (ADS)

    Ratautas, K.; Gedvilas, M.; Stankevičiene, I.; JagminienÄ--, A.; Norkus, E.; Li Pira, N.; Sinopoli, S.; Emanuele, U.; Račiukaitis, G.

    2016-03-01

    Laser writing for selective plating of electro-conductive lines for electronics has several significant advantages, compared to conventional printed circuit board technology. Firstly, this method is faster and cheaper at the prototyping stage. Secondly, material consumption is reduced, because it works selectively. However, the biggest merit of this method is potentiality to produce moulded interconnect device, enabling to create electronics on complex 3D surfaces, thus saving space, materials and cost of production. There are two basic techniques of laser writing for selective plating on plastics: the laser-induced selective activation (LISA) and laser direct structuring (LDS). In the LISA method, pure plastics without any dopant (filler) can be used. In the LDS method, special fillers are mixed in the polymer matrix. These fillers are activated during laser writing process, and, in the next processing step, the laser modified area can be selectively plated with metals. In this work, both methods of the laser writing for the selective plating of polymers were investigated and compared. For LDS approach, new material: polypropylene with carbon-based additives was tested using picosecond and nanosecond laser pulses. Different laser processing parameters (laser pulse energy, scanning speed, the number of scans, pulse durations, wavelength and overlapping of scanned lines) were applied in order to find out the optimal regime of activation. Areal selectivity tests showed a high plating resolution. The narrowest width of a copper-plated line was less than 23 μm. Finally, our material was applied to the prototype of the electronic circuit board on a 2D surface.

  15. Lanthanide-based laser-induced phosphorescence for spray diagnostics.

    PubMed

    van der Voort, D D; Maes, N C J; Lamberts, T; Sweep, A M; van de Water, W; Kunnen, R P J; Clercx, H J H; van Heijst, G J F; Dam, N J

    2016-03-01

    Laser-induced phosphorescence (LIP) is a relatively recent and versatile development for studying flow dynamics. This work investigates certain lanthanide-based molecular complexes for their use in LIP for high-speed sprays. Lanthanide complexes in solutions have been shown to possess long phosphorescence lifetimes (∼1-2 ms) and to emit light in the visible wavelength range. In particular, europium and terbium complexes are investigated using fluorescence/phosphorescence spectrometry, showing that europium-thenoyltrifluoracetone-trioctylphosphineoxide (Eu-TTA-TOPO) can be easily and efficiently excited using a standard frequency-tripled Nd:YAG laser. The emitted spectrum, with maximum intensity at a wavelength of 614 nm, is shown not to vary strongly with temperature (293-383 K). The decay constant of the phosphorescence, while independent of ambient pressure, decreases by approximately 12 μs/K between 323 and 373 K, with the base level of the decay constant dependent on the used solvent. The complex does not luminesce in the gas or solid state, meaning only the liquid phase is visualized, even in an evaporating spray. By using an internally excited spray containing the phosphorescent complex, the effect of vaporization is shown through the decrease in measured intensity over the length of the spray, together with droplet size measurements using interferometric particle imaging. This study shows that LIP, using the Eu-TTA-TOPO complex, can be used with different solvents, including diesel surrogates. Furthermore, it can be easily handled and used in sprays to investigate spray breakup and evaporation. PMID:27036779

  16. Detection of uranium using laser-induced breakdown spectroscopy.

    PubMed

    Chinni, Rosemarie C; Cremers, David A; Radziemski, Leon J; Bostian, Melissa; Navarro-Northrup, Claudia

    2009-11-01

    The goal of this work is a detailed study of uranium detection by laser-induced breakdown spectroscopy (LIBS) for application to activities associated with environmental surveillance and detecting weapons of mass destruction (WMD). The study was used to assist development of LIBS instruments for standoff detection of bulk radiological and nuclear materials and these materials distributed as contaminants on surfaces. Uranium spectra were analyzed under a variety of different conditions at room pressure, reduced pressures, and in an argon atmosphere. All spectra displayed a high apparent background due to the high density of uranium lines. Time decay curves of selected uranium lines were monitored and compared to other elements in an attempt to maximize detection capabilities for each species in the complicated uranium spectrum. A survey of the LIBS uranium spectra was conducted and relative emission line strengths were determined over the range of 260 to 800 nm. These spectra provide a guide for selection of the strongest LIBS analytical lines for uranium detection in different spectral regions. A detection limit for uranium in soil of 0.26% w/w was obtained at close range and 0.5% w/w was achieved at a distance of 30 m. Surface detection limits were substrate dependent and ranged from 13 to 150 microg/cm2. Double-pulse experiments (both collinear and orthogonal arrangements) were shown to enhance the uranium signal in some cases. Based on the results of this work, a short critique is given of the applicability of LIBS for the detection of uranium residues on surfaces for environmental monitoring and WMD surveillance. PMID:19891832

  17. Laser induced vibrational energy transfer in iron pentacarbonyl

    NASA Astrophysics Data System (ADS)

    Langsam, Yedidyah; Ronn, A. M.

    1984-01-01

    The internal kinetics of Fe(CO)5 as well as the kinetics between Fe(CO)5 and other nonreactive species were studied using the technique of laser induced fluorescence. The energy transfer behavior of this large polyatomic is discussed in terms of existing V-V and V-T/R theories and collisional energy transfer. Iron pentacarbonyl's vibrational energy structure is treated by means of a simple three and four level energy transfer scheme. Subsequent to excitation of the 10 μ region by a CO2 laser, infrared fluorescence has been detected from the ˜16, ˜5, and ˜4 μ regions of Fe(CO)5. A single exponential decay rate of 13.6 ms-1 Torr-1 is observed from the ˜5 μ region, in good agreement with other decay rates established for smaller polyatomics possessing similar vibrational level structure. Under conditions of low fluence (˜30 mJ/cm2), this region is activated at a rate of 474 ms-1 Torr-1 suggesting a rapid near resonant collisional energy transfer. Under conditions of high fluence (˜5 J/cm2), the activation of the ˜5 μ region proceeds at a rate of 1250 ms-1 Torr-1 suggesting a different pathway for the determining step of the excitation process. The rare gas deactivation rates as well as those with Ni(CO)4, CO(CO)3No, and CO (as well as the reverse rate) and the crossover rate from excited Fe(CO)5 to CO in high rare gas dilution have also been determined.

  18. Laser-induced breakdown spectroscopy based deminers' probe

    NASA Astrophysics Data System (ADS)

    Hauck, James P.; Walker, Mark; Hamadani, Siavosh; Bloomhardt, Natalie; Eagan, Justin

    2009-05-01

    We report on a prototype Laser Induced Breakdown Spectroscopy (LIBS) Deminers' Probe used to identify underground objects. We have built a prototype, and are in the process of developing a more advanced LIBS based Deminer' s Probe used to prod objects underground, and then sense them by creating a micro-plasma plume of the surface material and analyzing the spectrum of the emitted light to identify the object. It is expected that the Deminer will be able to eliminate many false positives, which consume most of the Deminers' time. SARA Fiber-Optics coupled LIBS system consists in a probe that can be inserted into the ground to provide a path for both the laser beam to the target, and for the micro-plasma plume fluorescence from the target to a spectrometer or spectrometers for analysis. The probe is closely modeled after the conventional Deminers' probe, resembling a saber. We have demonstrated that this simple system is capable of producing remarkably different spectra from different materials. Our next steps are to add a number of features to the Deminers' Probe. These include: a new optical configuration to increase the irradiance and fluence created by the pulsed laser at the target, a multiple channel fluorescence reception system that can increase the amount of light delivered to the spectrometers, a fluidic system to clear the detritus away from the probe tip, and a complete operational/control and readout system for the Deminer to use. Mine-lane tests are planned to be performed in the later part of 2009, or shortly thereafter.

  19. Characterisation of estuarine intertidal macroalgae by laser-induced fluorescence

    NASA Astrophysics Data System (ADS)

    Gameiro, Carla; Utkin, Andrei B.; Cartaxana, Paulo

    2015-12-01

    The article reports the application of laser-induced fluorescence (LIF) for the assessment of macroalgae communities of estuarine intertidal areas. The method was applied for the characterisation of fifteen intertidal macroalgae species of the Tagus estuary, Portugal, and adjacent coastal area. Three bands characterised the LIF spectra of red macroalgae with emission maxima in the ranges 577-583 nm, 621-642 nm and 705-731 nm. Green and brown macroalgae showed one emission maximum in the red region (687-690 nm) and/or one in the far-red region (726-732 nm). Characteristics of LIF emission spectra were determined by differences in the main fluorescing pigments: phycoerythrin, phycocyanin and chlorophyll a (Chl a). In the green and brown macroalgae groups, the relative significance of the two emission maxima seems to be related to the thickness of the photosynthetic layer. In thick macroalgae, like Codium tomentosum or Fucus vesiculosus, the contribution of the far-red emission fluorescence peak was more significant, most probably due to re-absorption of the emitted red Chl a fluorescence within the dense photosynthetic layer. Similarly, an increase in the number of layers of the thin-blade green macroalgae Ulva rigida caused a shift to longer wavelengths of the red emission maximum and the development of a fluorescence peak at the far-red region. Water loss from Ulva's algal tissue also led to a decrease in the red/far-red Chl fluorescence ratio (F685/F735), indicating an increase in the density of chloroplasts in the shrinking macroalgal tissue during low tide exposure.

  20. Laser-induced growth of nanocrystals embedded in porous materials

    PubMed Central

    2013-01-01

    Space localization of the linear and nonlinear optical properties in a transparent medium at the submicron scale is still a challenge to yield the future generation of photonic devices. Laser irradiation techniques have always been thought to structure the matter at the nanometer scale, but combining them with doping methods made it possible to generate local growth of several types of nanocrystals in different kinds of silicate matrices. This paper summarizes the most recent works developed in our group, where the investigated nanoparticles are either made of metal (gold) or chalcogenide semiconductors (CdS, PbS), grown in precursor-impregnated porous xerogels under different laser irradiations. This review is associated to new results on silver nanocrystals in the same kind of matrices. It is shown that, depending on the employed laser, the particles can be formed near the sample surface or deep inside the silica matrix. Photothermal and/or photochemical mechanisms may be invoked to explain the nanoparticle growth, depending on the laser, precursor, and matrix. One striking result is that metal salt reduction, necessary to the production of the corresponding nanoparticles, can efficiently occur due to the thermal wrenching of electrons from the matrix itself or due to multiphoton absorption of the laser light by a reducer additive in femtosecond regime. Very localized semiconductor quantum dots could also be generated using ultrashort pulses, but while PbS nanoparticles grow faster than CdS particles due to one-photon absorption, this better efficiency is counterbalanced by a sensitivity to oxidation. In most cases where the reaction efficiency is high, particles larger than the pores have been obtained, showing that a fast diffusion of the species through the interconnected porosity can modify the matrix itself. Based on our experience in these techniques, we compare several examples of laser-induced nanocrystal growth in porous silica xerogels, which allows

  1. Using SPARK as a Solver for Modelica

    SciTech Connect

    Wetter, Michael; Wetter, Michael; Haves, Philip; Moshier, Michael A.; Sowell, Edward F.

    2008-06-30

    Modelica is an object-oriented acausal modeling language that is well positioned to become a de-facto standard for expressing models of complex physical systems. To simulate a model expressed in Modelica, it needs to be translated into executable code. For generating run-time efficient code, such a translation needs to employ algebraic formula manipulations. As the SPARK solver has been shown to be competitive for generating such code but currently cannot be used with the Modelica language, we report in this paper how SPARK's symbolic and numerical algorithms can be implemented in OpenModelica, an open-source implementation of a Modelica modeling and simulation environment. We also report benchmark results that show that for our air flow network simulation benchmark, the SPARK solver is competitive with Dymola, which is believed to provide the best solver for Modelica.

  2. Low current extended duration spark ignition system

    DOEpatents

    Waters, Stephen Howard; Chan, Anthony Kok-Fai

    2005-08-30

    A system for firing a spark plug is disclosed. The system includes a timing controller configured to send a first timing signal and a second timing signal. The system also includes an ignition transformer having a primary winding and a secondary winding and a spark-plug that is operably associated with the secondary winding. A first switching element is disposed between the timing controller and the primary winding of the ignition transformer. The first switching element controls a supply of power to the primary winding based on the first timing signal. Also, a second switching element is disposed between the timing controller and the primary winding of the ignition transformer. The second switching element controls the supply of power to the primary winding based on the second timing signal. A method for firing a spark plug is also disclosed.

  3. Heat energy of various ignition sparks

    NASA Technical Reports Server (NTRS)

    Silsbee, F B; Loeb, L B; Fonseca, E L

    1920-01-01

    This report describes a method developed at the Bureau of Standards for measuring the total energy liberated as heat in a spark gap by an ignition system. Since this heat energy is obtained from the electromagnetic energy stored in the windings of the magneto or coil, it is a measure of the effectiveness of the device as an electric generator. Part 2 gives the results of measurements in absolute units of the total heat supplied to a spark gap by ignition systems of different types operating at various speeds, under conditions substantially equivalent to those in the cylinder of a high-compression aviation engine.

  4. Optical diagnostics integrated with laser spark delivery system

    DOEpatents

    Yalin, Azer; Willson, Bryan; Defoort, Morgan; Joshi, Sachin; Reynolds, Adam

    2008-09-02

    A spark delivery system for generating a spark using a laser beam is provided, and includes a laser light source and a laser delivery assembly. The laser delivery assembly includes a hollow fiber and a launch assembly comprising launch focusing optics to input the laser beam in the hollow fiber. The laser delivery assembly further includes exit focusing optics that demagnify an exit beam of laser light from the hollow fiber, thereby increasing the intensity of the laser beam and creating a spark. Other embodiments use a fiber laser to generate a spark. Embodiments of the present invention may be used to create a spark in an engine. Yet other embodiments include collecting light from the spark or a flame resulting from the spark and conveying the light for diagnostics. Methods of using the spark delivery systems and diagnostic systems are provided.

  5. Optimization of an Image-Guided Laser-Induced Choroidal Neovascularization Model in Mice

    PubMed Central

    Sun, Ye; Fu, Zhongjie; Liu, Chi-Hsiu; Evans, Lucy; Tian, Katherine; Saba, Nicholas; Fredrick, Thomas; Morss, Peyton; Chen, Jing; Smith, Lois E. H.

    2015-01-01

    The mouse model of laser-induced choroidal neovascularization (CNV) has been used in studies of the exudative form of age-related macular degeneration using both the conventional slit lamp and a new image-guided laser system. A standardized protocol is needed for consistent results using this model, which has been lacking. We optimized details of laser-induced CNV using the image-guided laser photocoagulation system. Four lesions with similar size were consistently applied per eye at approximately double the disc diameter away from the optic nerve, using different laser power levels, and mice of various ages and genders. After 7 days, the mice were sacrificed and retinal pigment epithelium/choroid/sclera was flat-mounted, stained with Isolectin B4, and imaged. Quantification of the area of the laser-induced lesions was performed using an established and constant threshold. Exclusion criteria are described that were necessary for reliable data analysis of the laser-induced CNV lesions. The CNV lesion area was proportional to the laser power levels. Mice at 12-16 weeks of age developed more severe CNV than those at 6-8 weeks of age, and the gender difference was only significant in mice at 12-16 weeks of age, but not in those at 6-8 weeks of age. Dietary intake of omega-3 long-chain polyunsaturated fatty acid reduced laser-induced CNV in mice. Taken together, laser-induced CNV lesions can be easily and consistently applied using the image-guided laser platform. Mice at 6-8 weeks of age are ideal for the laser-induced CNV model. PMID:26161975

  6. Laser-induced breakdown emission in hydrocarbon fuel mixtures

    NASA Astrophysics Data System (ADS)

    Kobayashi, Kazunobu; Bak, Moon Soo; Tanaka, Hiroki; Carter, Campbell; Do, Hyungrok

    2016-04-01

    Time-resolved emission measurements of laser-induced breakdown plasmas have been carried out to investigate the effect that gas species might have on the kinetics, particularly in excited states, and the resulting plasma properties. For this purpose, fuel-oxygen (O2)-carbon dioxide (CO2) mixtures with either helium (He) or nitrogen (N2) balance are prepared while maintaining their atomic compositions. The fuels tested in this study are methane (CH4), ethylene (C2H4), propane (C3H8), and butane (C4H10). The breakdown is produced in the mixtures (CH4/CO2/O2/He, C2H4/O2/He, C3H8/CO2/O2/He and C4H10/CO2/O2/He or CH4/CO2/O2/N2, C2H4/O2/N2, C3H8/CO2/O2/N2 and C4H10/CO2/O2/N2) at room conditions using the second harmonic of a Q-switched Nd:YAG laser (with pulse duration of 10 ns). The temporal evolution of plasma temperature is deduced from the ratio of two oxygen lines (777 nm and 823 nm) through Boltzmann analysis, while the evolution of electron number density is estimated based on Stark broadening of the Balmer-alpha (H α ) line at 656 nm and the measured plasma temperature. From the results, the temporal evolution of emission spectra and decay rates of atomic line-intensities are found to be almost identical between the breakdown plasma in the different mixtures given balancing gases. Furthermore, the temporal evolution of plasma temperature and electron number density are also found to be independent of the species compositions. Therefore, this behavior—of the breakdown emissions and plasma properties in the different mixtures with identical atomic composition—may be because the breakdown gases reach similar thermodynamic and physiochemical states immediately after the breakdown.

  7. Morphological studies of laser-induced photoacoustic damage

    NASA Astrophysics Data System (ADS)

    Flotte, Thomas J.; Yashima, Yutaka; Watanabe, Shinichi; McAuliffe, Daniel J., Sr.; Jacques, Steven L.

    1990-06-01

    Argon-fluoride excimer laser ablation of stratum comeum causes deeper tissue damage than expected for thermal or photochemical mechanisms, suggesting thatphotoacoustic waves have arole in tissue damage. Laserirradiation (193 nm, 14 ns pulses, 1-2 Hz) attworadiantexposures, 60 and 160 mJ/cm2perpulse was usedto ablate the stratumcomeumofskin. Light and electron microscopy ofimmediate biopsies demonstrated damage to fibroblasts as deep as 88 and 220 jun, respectively, below the ablation site. Ablation throughwaterwas usedtoinertially confine the ablation zone. Partial ablationofs.c. through airproducedno damage, whereas partial ablation through water damaged skin to amean depth of 1 14.5 8.8( Full thickness ablation of s.c. through air and water produced damage zones measuring 192.2 16.2 and 293.0 71.6 rim, respectively (p <0.05). The increased depth ofdamage in the presence ofinertial confinementprovided by the layer of water strongly supports a photoacoustic mechanism ofdamage. The depths ofdamage for thelarge spot, line, and small spots were 43 1 164 urn, 269 96xni, andno damage. The spot size dependence ofthedepthofdamage is consistentwiththe geometric attenuation one would expect to be present from a pressure wave related phenomena. Sequential biopsies were taken over a 7 day period for light and transmission electron microscopy. At 24 hours, there was necrosis of the epidermis and papillary dermis subjacent to the ablation site, with neutrophils surrounding and demarcating the affected area. The necrotic zone sloughedby48 hours. Thereepithelializationwas completeby7 days. The sequenceofrepairis similartoknife wound healing which we have previously studied, and is analogous to other wound healing processes. We have used an experimental model of ArF excimer laser ablation of stratum corneum to investigate laser-induced photoacoustic damage. The evidence for the injury being due to pressure transients is indirectbutcompelling. Whether these pressuretransients are

  8. Application of femtosecond-laser induced nanostructures in optical memory.

    PubMed

    Shimotsuma, Yasuhiko; Sakakura, Masaaki; Miura, Kiyotaka; Qiu, Jiarong; Kazansky, Peter G; Fujita, Koji; Hirao, Kazuyuki

    2007-01-01

    The femtosecond laser induced micro- and nanostructures for the application to the three-dimensional optical data storage are investigated. We have observed the increase of refractive index due to local densification and atomic defect generation, and demonstrated the real time observation of photothermal effect after the femtosecond laser irradiation inside a glass by the transient lens (TrL) method. The TrL signal showed a damped oscillation with about an 800 ps period. The essential feature of the oscillation can be reproduced by the pressure wave creation and propagation to the outward direction from the irradiated region. The simulation based on elastodynamics has shown that a large thermoelastic stress is relaxed by the generation of the pressure wave. In the case of soda-lime glass, the velocity of the pressure wave is almost same as the longitudinal sound velocity at room temperature (5.8 microm/ns). We have also observed the localized photo-reduction of Sm3+ to Sm2+ inside a transparent and colorless Sm(3+)-doped borate glass. Photoluminescence spectra showed that some the Sm3+ ions in the focal spot within the glass sample were reduced to Sm2+ ions after femtosecond laser irradiation. A photo-reduction bit of 200 nm in three-dimensions can be recorded with a femtosecond laser and readout clearly by detecting the fluorescence excited by Ar+ laser (lambda = 488 nm). A photo-reduction bit can be also erased by photo-oxidation with a cw Ar+ laser (lambda = 514.5 nm). Since photo-reduction bits can be spaced 150 nm apart in a layer within glass, a memory capacity of as high as 1 Tbit can be achieved in a glass piece with dimensions of 10 mm x 10 mm x 1 mm. We have also demonstrated the first observation of the polarization-dependent periodic nanostructure formation by the interference between femtosecond laser light and electron acoustic waves. The observed nanostructures are the smallest embedded structures ever created by light. The period of self

  9. Modeling of Laser Induced Damage in NIF UV Optics

    SciTech Connect

    Feit, M D; Rubenchik, A M

    2001-02-21

    Controlling damage to nominally transparent optical elements such as lenses, windows and frequency conversion crystals on high power lasers is a continuing technical problem. Scientific understanding of the underlying mechanisms of laser energy absorption, material heating and vaporization and resultant mechanical damage is especially important for UV lasers with large apertures such as NIF. This LDRD project was a single year effort, in coordination with associated experimental projects, to initiate theoretical descriptions of several of the relevant processes. In understanding laser damage, we distinguish between damage initiation and the growth of existent damage upon subsequent laser irradiation. In general, the effect of damage could be ameliorated by either preventing its initiation or by mitigating its growth. The distinction comes about because initiation is generally due to extrinsic factors such as contaminants, which provide a means of local laser energy absorption. Thus, initiation tends to be local and stochastic in nature. On the other hand, the initial damaging event appears to modify the surrounding material in such a way that multiple pulse damage grows more or less regularly. More exactly, three ingredients are necessary for visible laser induced damage. These are adequate laser energy, a mechanism of laser energy absorption and mechanical weakness. For damage growth, the material surrounding a damage site is already mechanically weakened by cracks and probably chemically modified as well. The mechanical damage can also lead to electric field intensification due to interference effects, thus increasing the available laser energy density. In this project, we successfully accounted for the pulselength dependence of damage threshold in bulk DKDP crystals with the hypothesis of small absorbers with a distribution of sizes. We theoretically investigated expected scaling of damage initiation craters both to baseline detailed numerical simulations

  10. Talent Development in STEM Disciplines: Sparking Innovators

    ERIC Educational Resources Information Center

    Roberts, Julia Link

    2010-01-01

    What role can specialized schools with focus on mathematics, science, and technology have in sparking innovation? Such specialized schools can be and in some cases currently are leaders in promoting high-level content knowledge, creative and critical thinking, and problem solving--the basic ingredients of innovation. In this article, the author…

  11. Spark gap device for precise switching

    DOEpatents

    Boettcher, G.E.

    1984-10-02

    A spark gap device for precise switching of an energy storage capacitor into an exploding bridge wire load is disclosed. Niobium electrodes having a melting point of 2,415 degrees centigrade are spaced apart by an insulating cylinder to define a spark gap. The electrodes are supported by conductive end caps which, together with the insulating cylinder, form a hermetically sealed chamber filled with an inert, ionizable gas, such as pure xenon. A quantity of solid radioactive carbon-14 within the chamber adjacent the spark gap serves as a radiation stabilizer. The sides of the electrodes and the inner wall of the insulating cylinder are spaced apart a sufficient distance to prevent unwanted breakdown initiation. A conductive sleeve may envelop the outside of the insulating member from the midpoint of the spark gap to the cap adjacent the cathode. The outer metallic surfaces of the device may be coated with a hydrogen-impermeable coating to lengthen the shelf life and operating life of the device. The device breaks down at about 1,700 volts for input voltage rates up to 570 volts/millisecond and allows peak discharge currents of up to 3,000 amperes from a 0.3 microfarad energy storage capacitor for more than 1,000 operations. 3 figs.

  12. Spark gap device for precise switching

    DOEpatents

    Boettcher, Gordon E.

    1984-01-01

    A spark gap device for precise switching of an energy storage capacitor into an exploding bridge wire load is disclosed. Niobium electrodes having a melting point of 2,415 degrees centrigrade are spaced apart by an insulating cylinder to define a spark gap. The electrodes are supported by conductive end caps which, together with the insulating cylinder, form a hermetically sealed chamber filled with an inert, ionizable gas, such as pure xenon. A quantity of solid radioactive carbon-14 within the chamber adjacent the spark gap serves as a radiation stabilizer. The sides of the electrodes and the inner wall of the insulating cylinder are spaced apart a sufficient distance to prevent unwanted breakdown initiation. A conductive sleeve may envelop the outside of the insulating member from the midpoint of the spark gap to the cap adjacent the cathode. The outer metallic surfaces of the device may be coated with a hydrogen-impermeable coating to lengthen the shelf life and operating life of the device. The device breaks down at about 1,700 volts for input voltage rates up to 570 volts/millisecond and allows peak discharge currents of up to 3,000 amperes from a 0.3 microfarad energy storage capacitor for more than 1,000 operations.

  13. Spark decomposition studies of dielectric gas mixtures

    NASA Astrophysics Data System (ADS)

    Sauers, I.; Christophorou, L. G.

    The ultimate usefulness of a high voltage insulating gas depends not only on the ability of the gas to withstand high voltages, but also on the degradation of the gas resulting from spark discharges, corona or prolonged electrical stress and the effect(s) of the by-products on the equipment and, possibly, the environment. In view of these considerations, the study of long-range spark decomposition was undertaken in an effort to improve the decomposition characteristics of dielectric gases through proper tailoring of gas mixtures while maintaining high breakdown strengths. The data reported are on the analyses of gases sparked by capactive (0.1 micro F) discharge into a 0.5-mm gap, resulting in an energy input of approximately 5 J per spark. The nature of the decomposition products of SF6 formed by high voltage discharges observed is found to be critically dependent on impurities (particularly H2O), electrode material and insulating materials present in the system.

  14. Crevice flow and combustion visualization in a direct-injection spark-ignition engine using laser imaging techniques

    SciTech Connect

    Drake, M.C.; Fansler, T.D.; French, D.T.

    1995-12-31

    Crevice flows of hydrocarbon fuel (both liquid and vapor) have been observed directly from fuel-injector mounting and nozzle-exit crevices in an optically-accessible single-cylinder direct-injection two-stroke engine burning commercial gasoline. Fuel trapped in crevices escapes combustion during the high-pressure portions of the engine cycle, exits the crevice as the cylinder pressure decreases, partially reacts when mixed with hot combustion gases in the cylinder, and contributes to unburned hydrocarbon emissions. High-speed laser Mie-scattering imaging reveals substantial liquid crevice flow in a cold engine at light load, decreasing as the engine warms up and as load is increased. Single-shot laser induced fluorescence imaging of fuel (both vapor and liquid) shows that substantial fuel vapor emanates from fuel injector crevices during every engine cycle and for all operating conditions. Early in the crevice-flow process, some of the emerging fuel vapor (imaged by laser-induced fluorescence) burns as a rich diffusion flame (imaged by flame luminosity), but most of the crevice flow fails to burn as the cylinder pressure and temperature fall. Crevice HC`s are a significant (but not the predominant) source of hydrocarbon emissions in this two-stroke engine, since most of the crevice flow hydrocarbons are retained as residual fuel in the combustion chamber. Similar laser-imaging techniques are applicable to four-stroke spark-ignition engines, where crevice flows are believed to be the dominant hydrocarbon-emissions source.

  15. Time-Resolved Aluminum Monoxide Emission Measurements in Laser-Induced Plasma

    NASA Astrophysics Data System (ADS)

    Surmick, David; Parigger, Christian

    2014-03-01

    Laser-induced plasmas are useful for diagnostic applications in a wide variety of fields. One application is the creation of laser-induced plasmas on the surface of an aluminum sample to simulate an aluminized flame. In this study, aluminum monoxide emissions are measured to characterize the temperature along the laser-induced plasma as a function of time delay following laser-induced optical breakdown. The breakdown event is achieved by focusing 1064 nanometer laser radiation from an Nd:YAG laser onto the surface of an aluminum sample. Light from the plasma is dispersed with the use of a Czerny-Turner spectrograph, and time resolved emission spectra are recorded with an intensified, gated detector. Temperatures are inferred from the diatomic molecular emissions by fitting the experimentally collected to theoretically calculated spectra using a Nelder-Mead algorithm. For computation of synthetic spectra we utilize accurate line strengths for selected AlO molecular bands. Atomic emissions from aluminum are also investigated in our study of laser-induced plasma.

  16. Self-emission and enhancement of laser-induced emission of electrons from ferroelectrics

    NASA Astrophysics Data System (ADS)

    Geissler, K. K.; Meineke, A.; Riege, H.; Handerek, J.

    1994-02-01

    We report on laser-induced electron emission (LIEE) from ferroelectrics (FE) at 266, 355 and 532 nm wavelength. The self-emission of charges up to 20 nC/cm 2 with kinetic energies up to several keV was observed with PLZT ceramics at laser-pulse energy densities of 13 mJ/cm 2 and a pulse width of 5 ns FWHM after high-voltage-induced polarization switching. The driving electric field is generated by the laser-induced change of the spontaneous polarization in a time scale of 1 ns. The dependence of the emission on the laser-pulse energy density is shown and the relation between the enhancement of LIEE and the laser-induced self-emission is discussed.

  17. Laser-induced fluorescence of fused silica irradiated by ArF excimer laser

    SciTech Connect

    Zhang Haibo; Yuan Zhijun; Zhou Jun; Dong Jingxing; Wei Yunrong; Lou Qihong

    2011-07-01

    Laser-induced fluorescence (LIF) of high-purity fused silica irradiated by ArF excimer laser is studied experimentally. LIF bands of the fused silica centered at 281 nm, 478 nm, and 650 nm are observed simultaneously. Furthermore, the angular distribution of the three fluorescence peaks is examined. Microscopic image of the laser modified fused silica indicates that scattering of the generated fluorescence by laser-induced damage sites is the main reason for the angular distribution of LIF signals. Finally, the dependence of LIF signals intensities of the fused silica on laser power densities is presented. LIF signals show a squared power density dependence, which indicates that laser-induced defects are formed mainly via two-photon absorption processes.

  18. Laser-induced fluorescence imaging of coronary arteries for open-heart surgery applications

    NASA Astrophysics Data System (ADS)

    Taylor, Roderick S.; Gladysz, D.; Brown, Derek W.; Higginson, Lyall A. J.

    1991-07-01

    A technique utilizing laser induced fluorescence has been developed to obtain direct real-time imaging of the coronary artery network for open heart surgery applications. Both excimer pumped dye and cw argon-ion laser radiation transmitted through a fused silica fiber were used as laser sources to irradiate swine, bovine, and human cadaver hearts whose coronary arteries had been injected with strongly fluorescent dyes. The laser induces fluorescence originating from within the coronary arteries and detected by the surgeon's eye, allows the entire coronary network to be directly viewed. A comparison between laser induced fluorescence and the use of direct visual inspection of arteries following injection of the dye Cardio-Green(R) as well as conventional thermal imaging is presented. The limitations imposed on each technique by layers of fat on top of the coronary arteries are also described. The possibility of using these techniques to detect mechanical or laser beam perforations during laser endarterectomy procedures is discussed.

  19. Quantitative measurement of electron number in nanosecond and picosecond laser-induced air breakdown

    NASA Astrophysics Data System (ADS)

    Wu, Yue; Sawyer, Jordan C.; Su, Liu; Zhang, Zhili

    2016-05-01

    Here we present quantitative measurements of total electron numbers in laser-induced air breakdown at pressures ranging from atmospheric to 40 barg by 10 ns and 100 ps laser pulses. A quantifiable definition for the laser-induced breakdown threshold is identified by a sharp increase in the measurable total electron numbers via dielectric-calibrated coherent microwave scattering. For the 10 ns laser pulse, the threshold of laser-induced breakdown in atmospheric air is defined as the total electron number of ˜106. This breakdown threshold decreases with an increase of pressure and laser photon energy (shorter wavelength), which is consistent with the theory of initial multiphoton ionization and subsequent avalanche processes. For the 100 ps laser pulse cases, a clear threshold is not present and only marginal pressure effects can be observed, which is due to the short pulse duration leading to stronger multiphoton ionization and minimal collisional avalanche ionization.

  20. Standoff Detection of Volatile Organic Compounds In Air Using Laser Induced Fluorescence

    NASA Astrophysics Data System (ADS)

    Clark, Jerry; Alexander, Alonzo; Wiggins, Delonia; Williams, Sydney; Akpovo, Charlemagne; Mezonlin, Ephrem; Johnson, Joseph, III; CenterPlasma Science; Technology (CePaST) Team

    2011-10-01

    The use of laser-induced fluorescence has proven to be an excellent method of detecting important intermediates in turbulent systems. However, Acetylene detection in air at ambient temperatures has proven more challenging. Molecular spectra were collected in laser induced acetylene plasmas using a 250 mJ Nd:YAG laser and an optical parametric oscillator (OPO) to achieve the 260 nm wavelength and greater than 3 mJ energy necessary to excite acetylene molecules. The acetylene laser-induced fluorescence excitation was observed at the 228 nm wavelength. Using various concentration ratios, acetylene was mixed with air to specifically determine the capabilities of standoff acetylene detection at atmospheric pressure. These results will lead to further research and development of turbulence based battlefield ready detection devices. Research supported in part by NSF grants to FAMU.

  1. Photophysics of Laser Dye-Doped Polymer Membranes for Laser-Induced Fluorescence Photogrammetry

    NASA Technical Reports Server (NTRS)

    Dorrington, Adrian A.; Jones, Thomas W.; Danehy, Paul M.

    2004-01-01

    Laser-induced fluorescence target generation in dye-doped polymer films has recently been introduced as a promising alternative to more traditional photogrammetric targeting techniques for surface profiling of highly transparent or reflective membrane structures. We investigate the photophysics of these dye-doped polymers to help determine their long-term durability and suitability for laser-induced fluorescence photogrammetric targeting. These investigations included experimental analysis of the fluorescence emission pattern, spectral content, temporal lifetime, linearity, and half-life. Results are presented that reveal an emission pattern wider than normal Lambertian diffuse surface scatter, a fluorescence time constant of 6.6 ns, a pump saturation level of approximately 20 micro J/mm(exp 2), and a useful lifetime of more than 300,000 measurements. Furthermore, two demonstrations of photogrammetric measurements by laser-induced fluorescence targeting are presented, showing agreement between photogrammetric and physically measured dimensions within the measurement scatter of 100 micron.

  2. Sensitive Measurement of Trace Mercury Using Low Pressure Laser-Induced Plasma

    NASA Astrophysics Data System (ADS)

    Wang, Zhenzhen; Deguchi, Yoshihiro; Kuwahara, Masakazu; Zhang, Xiaobo; Yan, Junjie; Liu, Jiping

    2013-11-01

    The emission of trace heavy metals, such as mercury (Hg), from power plants and other industries is a severe environmental problem concerning the public health. The laser-induced plasma technique was employed to measure Hg under various conditions, which reveals several merits of this method at low pressure. The main interferences of laser-induced breakdown spectroscopy (LIBS), which include the black-body-like emission from plasma itself and coexisting molecular and atomic emissions, decreased significantly using low pressure laser-induced plasma. Under low pressure conditions, Hg signal was rather clear without serious influence even if there is no delay time from the laser irradiation, which means the gated detection device is not necessary. This method featured the detection limit of 0.3 ppm at pressure 700 Pa. Additionally, the feasible of this method in real applications was demonstrated by measuring Hg in combustion gas which performed preferable results.

  3. Laser-induced breakdown spectroscopy detection of heavy metal in water based on graphite conch method

    NASA Astrophysics Data System (ADS)

    Wang, Chunlong; Liu, Jianguo; Zhao, Nanjing; Shi, Huan; Liu, Lituo; Ma, Mingjun; Zhang, Wei; Chen, Dong; Liu, Jing; Zhang, Yujun; Liu, Wenqing

    2012-10-01

    The laser-induced breakdown spectroscopy emission characteristics of trace heavy metal lead in water is studied based on graphite conch method, with a 1064nm wavelength Nd: YAG laser as excitation source, the echelle spectrometer and ICCD detector are used for spectral separation and high sensitive detection with high resolution and wide spectral range. The delay time 900ns and gate time 1600ns are determined in the experiment. The calibration curve of Pb is plotted based on the different concentration measurement results, and a limit of detection of 0.0138mg / L is obtained for Pb in water. Graphite conch method effectively overcomes the current problems on laser-induced breakdown spectroscopy detection of heavy metal in water. The detection limits and stability are improved. The reference data is provided for further study on the fast measurement of trace heavy metals in water by laser induced breakdown spectroscopy technique.

  4. Analysis of plutonium oxide surrogate residue using laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Zheng, Hongbo; Yueh, Fang Yu; Miller, Tracy; Singh, Jagdish P.; Zeigler, Kristine E.; Marra, James C.

    2008-09-01

    Laser-induced breakdown spectroscopy was used to determine the elemental composition of a CeO 2 composite powder for process control verification during lanthanide borosilicate glass fabrication. Cerium oxide is used as a surrogate for plutonium oxide, which along with other canister contents will be combined with frit to make glass. Laser-induced breakdown spectroscopy data for the composition of the CeO 2 batch containing concentrations of Ce, Cr, Si, Fe, Ta, Ni, Zn, Al Mg, Gd, and W were quantitatively determined from laser-induced breakdown spectroscopy spectra of both pellet and powder samples. The results of both forms were compared and it was determined that the pellet data gave slightly better precision than the powder sample.

  5. High-voltage spark atomic emission detector for gas chromatography

    NASA Technical Reports Server (NTRS)

    Calkin, C. L.; Koeplin, S. M.; Crouch, S. R.

    1982-01-01

    A dc-powered, double-gap, miniature nanosecond spark source for emission spectrochemical analysis of gas chromatographic effluents is described. The spark is formed between two thoriated tungsten electrodes by the discharge of a coaxial capacitor. The spark detector is coupled to the gas chromatograph by a heated transfer line. The gas chromatographic effluent is introduced into the heated spark chamber where atomization and excitation of the effluent occurs upon breakdown of the analytical gap. A microcomputer-controlled data acquisition system allows the implementation of time-resolution techniques to distinguish between the analyte emission and the background continuum produced by the spark discharge. Multiple sparks are computer averaged to improve the signal-to-noise ratio. The application of the spark detector for element-selective detection of metals and nonmetals is reported.

  6. Comparisons of laser-saturated, laser-induced, and planar laser-induced fluorescence measurements of nitric oxide in a lean direct-injection spray flame.

    PubMed

    Cooper, C S; Ravikrishna, R V; Laurendeau, N M

    1998-07-20

    We report quantitative, spatially resolved laser-saturated fluorescence (LSF), linear laser-induced fluorescence (LIF), and planar laser-induced fluorescence (PLIF) measurements of nitric oxide (NO) concentration in a preheated, lean direct-injection spray flame at atmospheric pressure. The spray is produced by a hollow-cone, pressure-atomized nozzle supplied with liquid heptane, and the overall equivalence ratio is unity. NO is excited by means of the Q(2)(26.5) transition of the gamma(0, 0) band. LSF and LIF detection are performed in a 2-nm region centered on the gamma(0, 1) band. PLIF detection is performed in a broad ~70-nm region with a peak transmission at 270 nm. Quantitative radial NO profiles obtained by LSF are presented and analyzed so as to correct similar LIF and PLIF profiles. Excellent agreement is achieved among the three fluorescence methodologies. PMID:18285943

  7. Laser-induced synthesis and decay of Tritium under exposure of solid targets in heavy water

    NASA Astrophysics Data System (ADS)

    Barmina, E. V.; Timashev, S. F.; Shafeev, G. A.

    2016-03-01

    The processes of laser-assisted synthesis of Tritium nuclei and their laser-induced decay in cold plasma in the vicinity of solid targets (Au, Ti, Se, etc.) immersed into heavy water are experimentally realized at peak laser intensity of 1010-1013 W/cm2. Initial stages of Tritium synthesis and their laser-induced beta-decay are interpreted on the basis of non-elastic interaction of plasma electrons having kinetic energy of 5-10 eV with nuclei of Deuterium and Tritium, respectively.

  8. Single-Walled Carbon Nanotubes, Carbon Nanofibers and Laser-Induced Incandescence

    NASA Technical Reports Server (NTRS)

    Schubert, Kathy (Technical Monitor); VanderWal, Randy L.; Ticich, Thomas M.; Berger, Gordon M.; Patel, Premal D.

    2004-01-01

    Laser induced incandescence applied to a heterogeneous, multi-element reacting flows is characterized by a) temporally resolved emission spectra, time-resolved emission at selected detection wavelengths and fluence dependence. Laser fluences above 0.6 Joules per square centimeter at 1064 nm initiate laser-induced vaporization, yielding a lower incandescence intensity, as found through fluence dependence measurements. Spectrally derived temperatures show that values of excitation laser fluence beyond this value lead to a super-heated plasma, well above the vaporization of temperature of carbon. The temporal evolution of the emission signal at these fluences is consistent with plasma dissipation processes, not incandescence from solid-like structures.

  9. (Study of flow properties of wet solids using laser induced photochemical anemometry)

    SciTech Connect

    Falco, B.

    1990-07-23

    A new diagnostic measurement technique is being developed that will enable the investigation of the dynamics of flowing wet solids. The technique involves that use of Laser Induced Photochemical Anemometry (LIPA), enhanced to enable two photochemical species to be excited. It uses laser induced photochromic and photo luminescent molecules to separately tag the two phases for times long enough for them to distort the tagging. Recording the distortions of the tagging caused by the movement of each phase enables us to obtain local characterization of flow properties of both phases of the wet solids at many positions simultaneously across a pipe.

  10. (Study of flow properties of wet solids using laser induced photochemical anemometry)

    SciTech Connect

    Falco, B.

    1990-04-03

    A new diagnostic measurement technique is being developed that will enable the investigation of the dynamics of flowing wet solids. The technique involves the use of Laser Induced Photochemical Anemometry (LIPA), enhanced to enable two photochemical species to be excited. It uses laser induced photochromic and photo luminescent molecules to separately tag the two phases for times long enough for them to distort the tagging. Recording the distortions of the tagging caused by the movement of each phase enables us to obtain local characterization of flow properties of both phases of the wet solids at many positions simultaneously across a pipe.

  11. (Study of flow properties of wet solids using laser induced photochemical anemometry)

    SciTech Connect

    Falco, B.; Nocera, D.

    1990-01-23

    A new diagnostic measurement technique is being developed that will enable the investigation of the dynamics of flowing wet solids. The technique involves the use of Laser Induced Photochemical Anemometry (LIPA), enhanced to enable two photochemical species to be excited. It uses laser induced photochromic and photo luminescent molecules to separately tag the two phases for times long enough for them to distort the tagging. Recording the distortions of the tagging caused by the movement of each phase enables us to obtain local characterization of flow properties of both phases of the wet solids at many positions simultaneously across a pipe.

  12. (Study of flow properties of wet solids using laser induced photo chemical anemometry)

    SciTech Connect

    Falco, B.

    1992-04-09

    A new diagnostic measurement technique is being developed that will enable the investigation of the dynamics of flowing wet solids. The technique involves the use of Laser Induced Photochemical Anemometry (LIPA), enhanced to enable two photochemical species to be excited. It uses laser induced photochromic and photo luminescent molecules to separately tag the two phases for times long enough for them to distort the tagging. Recording the distortions of the tagging caused by the movement of each phase enables us to obtain local characterization of flow properties of both phases of the wet solids at many positions simultaneously across a pipe.

  13. Detection of Broadband Terahertz Waves with a Laser-Induced Plasma in Gases

    SciTech Connect

    Dai Jianming; Xie Xu; Zhang, X.-C.

    2006-09-08

    We report the experimental results and theoretical analysis of broadband detection of terahertz (THz) waves via electric-field-induced second-harmonic generation in laser-induced air plasma with ultrashort laser pulses. By introducing the second-harmonic component of the white light in the laser-induced plasma as a local oscillator, coherent detection of broadband THz waves with ambient air is demonstrated for the first time. Our results show that, depending on the probe intensity, detection of THz waves in air can be categorized as incoherent, hybrid, and coherent detection. Coherent detection is achieved only when the tunnel ionization process dominates in gases.

  14. Non-gated laser-induced breakdown spectroscopy in bulk water by position-selective detection

    SciTech Connect

    Tian, Ye; Xue, Boyang; Song, Jiaojian; Lu, Yuan; Zheng, Ronger

    2015-09-14

    Temporal and spatial evolutions of the laser-induced plasma in bulk water are investigated using fast imaging and emission spectroscopic techniques. By tightly focusing a single-pulse nanosecond Nd: YAG laser beam into the bulk water, we generate a strongly expanded plasma with high reproducibility. Such a strong expanding plasma enables us to obtain well-resolved spectral lines by means of position-selective detection; hence, the time-gated detector becomes abdicable. The present results suggest not only a possible non-gated approach for underwater laser-induced breakdown spectroscopy but also give an insight into the plasma generation and expansion in bulk water.

  15. Influence of energy and wavelength on femtosecond laser-induced nucleation of protein

    NASA Astrophysics Data System (ADS)

    Murai, Ryota; Yoshikawa, Hiroshi Y.; Hasenaka, Hitoshi; Takahashi, Yoshinori; Maruyama, Mihoko; Sugiyama, Shigeru; Adachi, Hiroaki; Takano, Kazufumi; Matsumura, Hiroyoshi; Murakami, Satoshi; Inoue, Tsuyoshi; Mori, Yusuke

    2011-06-01

    The influence of energy and wavelength on femtosecond laser-induced nucleation of protein was systematically investigated with Hen Egg White Lysozyme and Glucose Isomerase at two different wavelengths, λ = 780 nm and 260 nm. We found that the enhancement of nucleation probability at a laser wavelength of λ = 780 nm was comparable with that at λ = 260 nm, which produces more protein dimers. The nucleation was dependent on laser pulse energy and could be induced beyond the threshold energy of cavitation bubbles. These results indicate that the photophysical processes like cavitation bubbles formation are main triggers for the femtosecond laser-induced nucleation.

  16. Laser-induced wavelength-controlled self-assembly of colloidal quasi-resonant quantum dots.

    PubMed

    Tsipotan, Aleksey S; Gerasimova, Marina A; Slabko, Vitaliy V; Aleksandrovsky, Aleksandr S

    2016-05-16

    Self-assembly of colloidal semiconductor quantum dots controlled solely by laser-induced interaction is demonstrated for the first time. Pairs of CdTe nanoparticles are formed under irradiation with nanosecond pulses at wavelengths 555 or 560 nm. Formation of pairs is justified by corresponding changes of absorption spectra. Conditions of the experiment are in excellent agreement with those predicted by the theory of laser-induced dipole-dipole interaction of QDs. The fraction of QDs assembled into pairs is up to 47%. PMID:27409936

  17. Escherichia coli identification and strain discrimination using nanosecond laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Diedrich, Jonathan; Rehse, Steven J.; Palchaudhuri, Sunil

    2007-04-01

    Three strains of Escherichia coli, one strain of environmental mold, and one strain of Candida albicans yeast have been analyzed by laser-induced breakdown spectroscopy using nanosecond laser pulses. All microorganisms were analyzed while still alive and with no sample preparation. Nineteen atomic and ionic emission lines have been identified in the spectrum, which is dominated by calcium, magnesium, and sodium. A discriminant function analysis has been used to discriminate between the biotypes and E. coli strains. This analysis showed efficient discrimination between laser-induced breakdown spectroscopy spectra from different strains of a single bacteria species.

  18. Comparison of calcium phosphate coatings formed on femtosecond laser-induced and sand-blasted titanium

    NASA Astrophysics Data System (ADS)

    Liang, C. Y.; Yang, X. J.; Wei, Q.; Cui, Z. D.

    2008-11-01

    High energy femtosecond laser process was employed to create regular surface patterning on titanium while sand blasting treatment made a coarse surface. Both laser-induced titanium and blasted titanium could promote the formation of calcium phosphate compounds after the acid and alkali treatment, but little crystallized hydroxyapatite was grown on the laser-induced titanium in 1.5SBF only for 6 h, whereas Ca 4P 6O 19 was formed on the sand-blasted titanium. The femtosecond laser process together with common acid and alkali treatment might provide potential choice to enhance the biocompatibility of titanium and its alloys.

  19. Optimally enhanced optical emission in laser-induced air plasma by femtosecond double-pulse

    NASA Astrophysics Data System (ADS)

    Chen, Anmin; Li, Suyu; Li, Shuchang; Jiang, Yuanfei; Shao, Junfeng; Wang, Tingfeng; Huang, Xuri; Jin, Mingxing; Ding, Dajun

    2013-10-01

    In laser-induced breakdown spectroscopy, a femtosecond double-pulse laser was used to induce air plasma. The plasma spectroscopy was observed to lead to significant increase of the intensity and reproducibility of the optical emission signal compared to femtosecond single-pulse laser. In particular, the optical emission intensity can be optimized by adjusting the delay time of femtosecond double-pulse. An appropriate pulse-to-pulse delay was selected, that was typically about 50 ps. This effect can be especially advantageous in the context of femtosecond laser-induced breakdown spectroscopy, plasma channel, and so on.

  20. Optimally enhanced optical emission in laser-induced air plasma by femtosecond double-pulse

    SciTech Connect

    Chen, Anmin; Li, Suyu; Li, Shuchang; Jiang, Yuanfei; Ding, Dajun; Shao, Junfeng; Wang, Tingfeng; Huang, Xuri; Jin, Mingxing

    2013-10-15

    In laser-induced breakdown spectroscopy, a femtosecond double-pulse laser was used to induce air plasma. The plasma spectroscopy was observed to lead to significant increase of the intensity and reproducibility of the optical emission signal compared to femtosecond single-pulse laser. In particular, the optical emission intensity can be optimized by adjusting the delay time of femtosecond double-pulse. An appropriate pulse-to-pulse delay was selected, that was typically about 50 ps. This effect can be especially advantageous in the context of femtosecond laser-induced breakdown spectroscopy, plasma channel, and so on.

  1. MR-Guided Laser-Induced Thermotherapy of the Infratemporal Fossa and Orbit in Malignant Chondrosarcoma via a Modified Technique

    SciTech Connect

    Vogl, Thomas J.; Mack, Martin G.; Straub, Ralf; Eichler, Katrin; Zangos, Stephan

    2001-12-15

    A 76-year-old patient presented with a recurrent mass of a malignant chondrosarcoma in the right infratemporal fossa and in the left maxillary sinus with orbital invasion. The patient was treated with a palliative intention with MR-guided laser-induced thermotherapy using a modified applicator technique. Following treatment clinical symptoms improved and MRI revealed complete laser-induced tumor necrosis.

  2. Suprathermal electrons in a vacuum spark discharge

    NASA Astrophysics Data System (ADS)

    Bashutin, O. A.; Savjolov, A. S.

    2016-04-01

    Results of experiments on the detection of suprathermal electron beams in the plasma of a highcurrent low-inductance vacuum spark by means of space-resolved spectral X-ray polarimetry are presented. It is shown that the observed polarization of bremsstrahlung may be caused by an ~100-keV electron beam propagating along the discharge axis from the pinching region toward the anode. The influence of the discharge initiation conditions on the parameters of the generated electron beams is analyzed.

  3. SPARK Version 1. 1 user manual

    SciTech Connect

    Weissenburger, D.W.

    1988-01-01

    This manual describes the input required to use Version 1.1 of the SPARK computer code. SPARK 1.1 is a library of FORTRAN main programs and subprograms designed to calculate eddy currents on conducting surfaces where current flow is assumed zero in the direction normal to the surface. Surfaces are modeled with triangular and/or quadrilateral elements. Lorentz forces produced by the interaction of eddy currents with background magnetic fields can be output at element nodes in a form compatible with most structural analysis codes. In addition, magnetic fields due to eddy currents can be determined at points off the surface. Version 1.1 features eddy current streamline plotting with optional hidden-surface-removal graphics and topological enhancements that allow essentially any orientable surface to be modeled. SPARK also has extensive symmetry specification options. In order to make the manual as self-contained as possible, six appendices are included that present summaries of the symmetry options, topological options, coil options and code algorithms, with input and output examples. An edition of SPARK 1.1 is available on the Cray computers at the National Magnetic Fusion Energy Computer Center at Livermore, California. Another more generic edition is operational on the VAX computers at the Princeton Plasma Physics Laboratory and is available on magnetic tape by request. The generic edition requires either the GKS or PLOT10 graphics package and the IMSL or NAG mathematical package. Requests from outside the United States will be subject to applicable federal regulations regarding dissemination of computer programs. 22 refs.

  4. HIGH VOLTAGE, HIGH CURRENT SPARK GAP SWITCH

    DOEpatents

    Dike, R.S.; Lier, D.W.; Schofield, A.E.; Tuck, J.L.

    1962-04-17

    A high voltage and current spark gap switch comprising two main electrodes insulatingly supported in opposed spaced relationship and a middle electrode supported medially between the main electrodes and symmetrically about the median line of the main electrodes is described. The middle electrode has a perforation aligned with the median line and an irradiation electrode insulatingly supported in the body of the middle electrode normal to the median line and protruding into the perforation. (AEC)

  5. Spark gap switch with spiral gas flow

    DOEpatents

    Brucker, John P.

    1989-01-01

    A spark gap switch having a contaminate removal system using an injected gas. An annular plate concentric with an electrode of the switch defines flow paths for the injected gas which form a strong spiral flow of the gas in the housing which is effective to remove contaminates from the switch surfaces. The gas along with the contaminates is exhausted from the housing through one of the ends of the switch.

  6. High voltage spark carbon fiber detection system

    NASA Technical Reports Server (NTRS)

    Yang, L. C.

    1980-01-01

    The pulse discharge technique was used to determine the length and density of carbon fibers released from fiber composite materials during a fire or aircraft accident. Specifications are given for the system which uses the ability of a carbon fiber to initiate spark discharge across a high voltage biased grid to achieve accurate counting and sizing of fibers. The design of the system was optimized, and prototype hardware proved satisfactory in laboratory and field tests.

  7. Simultaneous imaging of fuel vapor mass fraction and gas-phase temperature inside gasoline sprays using two-line excitation tracer planar laser-induced fluorescence.

    PubMed

    Zigan, Lars; Trost, Johannes; Leipertz, Alfred

    2016-02-20

    This paper reports for the first time, to the best of our knowledge, on the simultaneous imaging of the gas-phase temperature and fuel vapor mass fraction distribution in a direct-injection spark-ignition (DISI) spray under engine-relevant conditions using tracer planar laser-induced fluorescence (TPLIF). For measurements in the spray, the fluorescence tracer 3-pentanone is added to the nonfluorescent surrogate fuel iso-octane, which is excited quasi-simultaneously by two different excimer lasers for two-line excitation LIF. The gas-phase temperature of the mixture of fuel vapor and surrounding gas and the fuel vapor mass fraction can be calculated from the two LIF signals. The measurements are conducted in a high-temperature, high-pressure injection chamber. The fluorescence calibration of the tracer was executed in a flow cell and extended significantly compared to the existing database. A detailed error analysis for both calibration and measurement is provided. Simultaneous single-shot gas-phase temperature and fuel vapor mass fraction fields are processed for the assessment of cyclic spray fluctuations. PMID:26906600

  8. Laser-induced fluorescence of ketones at elevated temperatures for pressures up to 20 bars by using a 248 nm excitation laser wavelength: experiments and model improvements.

    PubMed

    Braeuer, Andreas; Beyrau, Frank; Leipertz, Alfred

    2006-07-10

    Laser-induced fluorescence of acetone and 3-pentanone for a 248 nm excitation wavelength was investigated for conditions relevant for internal combustion engines regarding temperature, pressure, and gas composition. An optically accessible calibration chamber with continuous gas flow was operated by using CO2 and air as a bath gas. According to the varying pressure and temperature conditions during the compression stroke of a spark ignition engine, fluorescence experiments were performed under isothermal pressure variations from 1 to 20 bars for different temperatures between 293 and 700 K. The ketone fluorescence behavior predictions, based on a model previously developed by Thurber et al. [Appl. Opt. 37, 4963 (1998)], were found to overestimate the pressure-related fluorescence increase for high temperature and small wavelength excitation at 248 nm. The parameters influencing the model only in the large vibrational energy regime were newly adjusted, which resulted in an improved model with a better agreement with the experiment. The model's validity for excitation at larger wavelengths was not influenced. For the air bath gas an additional collision and vibrational energy sensitive quenching rate was implemented in the model for both tracers, acetone and 3-pentanone. PMID:16807609

  9. Laser-induced fluorescence of ketones at elevated temperatures for pressures up to 20 bars by using a 248 nm excitation laser wavelength: experiments and model improvements

    NASA Astrophysics Data System (ADS)

    Braeuer, Andreas; Beyrau, Frank; Leipertz, Alfred

    2006-07-01

    Laser-induced fluorescence of acetone and 3-pentanone for a 248 nm excitation wavelength was investigated for conditions relevant for internal combustion engines regarding temperature, pressure, and gas composition. An optically accessible calibration chamber with continuous gas flow was operated by using CO2 and air as a bath gas. According to the varying pressure and temperature conditions during the compression stroke of a spark ignition engine, fluorescence experiments were performed under isothermal pressure variations from 1 to 20 bars for different temperatures between 293 and 700 K. The ketone fluorescence behavior predictions, based on a model previously developed by Thurber et al. [Appl. Opt. 37, 4963 (1998)], were found to overestimate the pressure-related fluorescence increase for high temperature and small wavelength excitation at 248 nm. The parameters influencing the model only in the large vibrational energy regime were newly adjusted, which resulted in an improved model with a better agreement with the experiment. The model's validity for excitation at larger wavelengths was not influenced. For the air bath gas an additional collision and vibrational energy sensitive quenching rate was implemented in the model for both tracers, acetone and 3-pentanone.

  10. Relationship between Exploding Bridgewire & Spark Initiation of Low Density PETN

    NASA Astrophysics Data System (ADS)

    Lee, Elizabeth; Drake, Rod

    2015-06-01

    Recent work has shown that the energy delivered after bridgewire burst affects the function time of an EBW detonator. The spark which is formed post bridgewire burst is the means by which the remaining fireset energy is delivered into the detonator. Therefore, by studying the characteristics of spark-gap detonators insight into the contribution of spark initiation to the functioning of EBW detonators may be achieved. Spark initiation of low density explosives consists of; (i) spark formation, (ii) spark interaction with the bed, and (iii) ignition and growth of reaction. Experiments were performed in which beds of an inert simulant were used to study the formation and propagation of sparks. The effect of the spark on inert porous beds was studied over a limited delivered energy range. The disruption of the bed was found to be dependent on the particle size / pore structure of the bed. The effect of spark initiation on a low density PETN bed was then examined, the relationship between delivered energy and function time was found to be the same as for EBW detonators. This necessitated the development of electrical diagnostic techniques to measure the energy delivered to the spark.

  11. The Early Phase of Spark Ignition

    NASA Astrophysics Data System (ADS)

    Pitt, Philip Lawrence

    In this dissertation, some practical ignition techniques are presented that show how some problems of lean-burn combustion can be overcome. Then, to shed light on the effects of the ignition techniques described, the focus shifts to the more specific problem of the early phase of spark ignition. Thermal models of ignition are reviewed. These models treat the energy provided by the electrical discharge as a point source, delivered infinitely fast and creating a spherically symmetric ignition kernel. The thesis challenges the basis of these thermal models by reviewing the work of many investigators who have clearly shown that the temporal characteristics of the discharge have a profound effect upon ignition. Photographic evidence of the early phase of ignition, as well as other evidence from the literature, is also presented. The evidence clearly demonstrates that the morphology of spark kernels in the early phase of development is toroidal, not spherical as suggested by thermal models. A new perspective for ignition, a fluid dynamic point of view, is described. The common ignition devices are then classified according to fluid dynamics. A model describing the behaviour of spark kernels is presented, which extends a previously established mixing model for plasma jets, to the realm of conventional axial discharges. Comparison of the model behaviour to some limited data is made. The model is modified by including the effect of heat addition from combustion, and ignition criteria are discussed.

  12. SI Engine with repetitive NS spark plug

    NASA Astrophysics Data System (ADS)

    Pancheshniy, Sergey; Nikipelov, Andrey; Anokhin, Eugeny; Starikovskiy, Andrey; Laplase Team; Mipt Team; Pu Team

    2013-09-01

    Now de-facto the only technology for fuel-air mixtures ignition in IC engines exists. It is a spark discharge of millisecond duration in a short discharge gap. The reason for such a small variety of methods of ignition initiation is very specific conditions of the engine operation. First, it is very high-pressure of fuel-air mixture - from 5-7 atmospheres in old-type engines and up to 40-50 atmospheres on the operating mode of HCCI. Second, it is a very wide range of variation of the oxidizer/fuel ratio in the mixture - from almost stoichiometric (0.8-0.9) at full load to very lean (φ = 0.3-0.5) mixtures at idle and/or economical cruising mode. Third, the high velocity of the gas in the combustion chamber (up to 30-50 m/s) resulting in a rapid compression of swirling inlet flow. The paper presents the results of tests of distributed spark ignition system powered by repetitive pulse nanosecond discharge. Dynamic pressure measurements show the increased pressure and frequency stability for nanosecond excitation in comparison with the standard spark plug. Excitation by single nanosecond high-voltage pulse and short train of pulses was examined. In all regimes the nanosecond pulsed excitation demonstrate a better performance.

  13. Life and death of a cardiac calcium spark

    PubMed Central

    Ríos, Eduardo; Maltsev, Victor A.

    2013-01-01

    Calcium sparks in cardiac myocytes are brief, localized calcium releases from the sarcoplasmic reticulum (SR) believed to be caused by locally regenerative calcium-induced calcium release (CICR) via couplons, clusters of ryanodine receptors (RyRs). How such regeneration is terminated is uncertain. We performed numerical simulations of an idealized stochastic model of spark production, assuming a RyR gating scheme with only two states (open and closed). Local depletion of calcium in the SR was inevitable during a spark, and this could terminate sparks by interrupting CICR, with or without assumed modulation of RyR gating by SR lumenal calcium. Spark termination by local SR depletion was not robust: under some conditions, sparks could be greatly and variably prolonged, terminating by stochastic attrition–a phenomenon we dub “spark metastability.” Spark fluorescence rise time was not a good surrogate for the duration of calcium release. Using a highly simplified, deterministic model of the dynamics of a couplon, we show that spark metastability depends on the kinetic relationship of RyR gating and junctional SR refilling rates. The conditions for spark metastability resemble those produced by known mutations of RyR2 and CASQ2 that cause life-threatening triggered arrhythmias, and spark metastability may be mitigated by altering the kinetics of the RyR in a manner similar to the effects of drugs known to prevent those arrhythmias. The model was unable to explain the distributions of spark amplitudes and rise times seen in chemically skinned cat atrial myocytes, suggesting that such sparks may be more complex events involving heterogeneity of couplons or local propagation among sub-clusters of RyRs. PMID:23980195

  14. Effect of surrounding gases and water vapor on the induced electric current associated with a laser-induced plasma

    NASA Astrophysics Data System (ADS)

    Matsuta, Hideyuki

    2016-04-01

    The effect of surrounding gases and water vapor on the laser-induced electric current was investigated. Laser-induced plasma was generated on an aluminum alloy target. The laser-induced plasma was optically examined to estimate the excitation temperature and electron density in room air. There was a linear relationship between the maximum amplitude of the laser-induced current and the electron density. As the electron mean free path of the surrounding gas increased, the observed amplitude of the current increased. The amplitude of the induced current signal in dry air became maximum upon mixing with the optimum amount of water vapor. This enhancement of the induced current signal might be due to the large relative permittivity of water vapor. The laser-induced plasma as a whole seems to be a low-temperature plasma consisting of electrons, a large amount of cold surrounding gas, injected hot atoms, hot ions, and hot particles.

  15. Laser-induced fluorescence of metal-atom impurities in a neutral beam

    SciTech Connect

    Burrell, C.F.; Pyle, R.V.; Sabetimani, Z.; Schlachter, A.S.

    1984-10-01

    The need to limit impurities in fusion devices to low levels is well known. We have investigated, by the technique of laser-induced fluorescence, the concentration of heavy-metal atoms in a neutral beam caused by their evaporation from the hot filaments in a conventional high-current multifilament hydrogen-ion source.

  16. Laser-Induced Damage Threshold and Certification Procedures for Optical Materials

    NASA Technical Reports Server (NTRS)

    1997-01-01

    This document provides instructions for performing laser-induced-damage-threshold tests and pass-fail certification tests on optical materials used in pulsed-laser systems. The optical materials to which these procedures apply include coated and uncoated optical substrates, laser crystals, Q-switches, polarizers, and other optical components employed in pulsed-laser systems.

  17. Means and method for capillary zone electrophoresis with laser-induced indirect fluorescence detection

    DOEpatents

    Yeung, Edwards; Kuhr, Werner G.

    1991-04-09

    A means and method for capillary zone electrphoresis with laser-induced indirect fluorescence detection. A detector is positioned on the capillary tube of a capillary zone electrophoresis system. The detector includes a laser which generates a laser beam which is imposed upon a small portion of the capillary tube. Fluorescence of the elutant electromigrating through the capillary tube is indirectly detected and recorded.

  18. Recognition of edible oil by using BP neural network and laser induced fluorescence spectrum

    NASA Astrophysics Data System (ADS)

    Mu, Tao-tao; Chen, Si-ying; Zhang, Yin-chao; Guo, Pan; Chen, He; Zhang, Hong-yan; Liu, Xiao-hua; Wang, Yuan; Bu, Zhi-chao

    2013-09-01

    In order to accomplish recognition of the different edible oil we set up a laser induced fluorescence spectrum system in the laboratory based on Laser induced fluorescence spectrum technology, and then collect the fluorescence spectrum of different edible oil by using that system. Based on this, we set up a fluorescence spectrum database of different cooking oil. It is clear that there are three main peak position of different edible oil from fluorescence spectrum chart. Although the peak positions of all cooking oil were almost the same, the relative intensity of different edible oils was totally different. So it could easily accomplish that oil recognition could take advantage of the difference of relative intensity. Feature invariants were extracted from the spectrum data, which were chosen from the fluorescence spectrum database randomly, before distinguishing different cooking oil. Then back propagation (BP) neural network was established and trained by the chosen data from the spectrum database. On that basis real experiment data was identified by BP neural network. It was found that the overall recognition rate could reach as high as 83.2%. Experiments showed that the laser induced fluorescence spectrum of different cooking oil was very different from each other, which could be used to accomplish the oil recognition. Laser induced fluorescence spectrum technology, combined BP neural network,was fast, high sensitivity, non-contact, and high recognition rate. It could become a new technique to accomplish the edible oil recognition and quality detection.

  19. Study of mid IR fiber transmission and mode patterns under laser induced stimulated Brillouin scattering

    NASA Technical Reports Server (NTRS)

    Yu, C.; Chong, Yat C.; Zhou, Hongyi

    1990-01-01

    Mid IR fiber transmission and exit radiation mode patterns at various incident CO2 laser power levels appear to be effective diagnostic tools for monitoring laser induced stimulated Brillouin scattering in various mid IR fibers. Such processes are deemed to be essential mechanisms for fiber-optic amplifiers and switches as potential replacements of current repeaters and bistable devices.

  20. North American Symposium on Laser Induced Breakdown Spectroscopy (NASLIBS): introduction to feature issue.

    PubMed

    Singh, Jagdish P; Almirall, Jose; Sabsabi, Mohamad; Miziolek, Andrzej W

    2012-03-01

    This feature issue highlights the topics of the 2011 North American Symposium on Laser Induced Breakdown Spectroscopy (NASLIBS). These include LIBS application to Security and Forensic, Biomedical and Environmental, Liquid Analysis and Fundamentals of LIBS, Instrumentation/Commercialization, Fusion with LIBS, and New Frontiers. PMID:22410934

  1. Raman and Fluorescence Study of Erbium-Doped Laser-Induced Crystals-in-Glass

    NASA Astrophysics Data System (ADS)

    Knorr, Brian; Veenhuizen, Keith; Stone, Adam; Jain, Himanshu; Dierolf, Volkmar

    Laser induced crystallization of glasses is a spatially selective process which has the potential to produce photonic integrated circuits in a glass matrix. Low temperature Combined Excitation Emission Spectroscopy in Er:LaBGeO5 show that erbium incorporates at predominantly one majority site in both glass-ceramics and laser-induced crystals-in-glass, but that other minority sites also exist. The energy levels of the majority site were quantified. The fluorescence characteristics of the erbium ions in any site in the laser-induced crystals were found to be only weakly influenced by the irradiation conditions during growth. On the other hand, a hidden parameter, potentially boron deficiency-related defects, resulted in a significant change in the incorporation behavior of the erbium ions. Simultaneous scanning confocal Raman and fluorescence spectroscopy showed that the energies of the Raman modes are shifted, and the erbium fluorescence intensity varies, in a non-uniform manner, despite the host glass being homogeneously doped, across the cross-sections of laser-induced crystals in glass. These fluctuations within the Raman and fluorescence are spatially correlated, implying that different erbium sites form preferentially at different locations in the crystal cross-section.

  2. Use of laser induced breakdown spectroscopy for the analysis of poultry products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Laser Induced Breakdown Spectroscopy is evaluated as a potential method to characterize a wide range of poultry product quality and safety characteristics. In one part of this study, breast meat quality indices, including pH and water holding capacity, were treated as dependent variables for correla...

  3. Optimization study of the femtosecond laser-induced forward-transfer process with thin aluminum films

    NASA Astrophysics Data System (ADS)

    Bera, Sudipta; Sabbah, A. J.; Yarbrough, J. M.; Allen, C. G.; Winters, Beau; Durfee, Charles G.; Squier, Jeff A.

    2007-07-01

    The parameters for an effective laser-induced forward-transfer (LIFT) process of aluminum thin films using a femtosecond laser are studied. Deposited feature size as a function of laser fluence, donor film thickness, quality of focus, and the pulse duration are varied, providing a metric of the most desirable conditions for femtosecond LIFT with thin aluminum films.

  4. Laser-induced blood serum fluorescence and Raman spectroscopy for cancer diagnosis

    NASA Astrophysics Data System (ADS)

    Li, Xiaozhou; Wang, Qiuyu; Lin, Junxiu

    1999-09-01

    Laser induced auto-fluorescence and Raman spectra of serum from cancerous and normal people are measured and analyzed. The content of (beta) -carotene in the serum from normal man is higher than that from the cancerous one, this result agrees with other reports.

  5. Means and method for capillary zone electrophoresis with laser-induced indirect fluorescence detection

    DOEpatents

    Yeung, Edward S.; Kuhr, Werner G.

    1996-02-20

    A means and method for capillary zone electrphoresis with laser-induced indirect fluorescence detection. A detector is positioned on the capillary tube of a capillary zone electrophoresis system. The detector includes a laser which generates a laser beam which is imposed upon a small portion of the capillary tube. Fluorescence of the elutant electromigrating through the capillary tube is indirectly detected and recorded.

  6. Impulse characteristics of laser-induced blast wave in monoatomic gases

    NASA Astrophysics Data System (ADS)

    Yu, X. L.; Ohtani, T.; Sasoh, A.; Kim, S.; Urabe, N.; Jeung, I.-S.

    The paper focuses on physical gas-dynamic characteristics of impulse generation by laser Induced blast wave (LIBW) in a laser-driven in tube accelerator (LITA). Propagation, reflection of blast wave and wave structure were intensively studied by using an ICCD camera system through shadowgraph.

  7. Application of laser-induced fluorescence to neoplasm diagnosis using bis-1[alanylo-N]ethylodeuteroporphyrin

    NASA Astrophysics Data System (ADS)

    Kwasny, Miroslaw; Mierczyk, Zygmunt; Graczyk, Alfreda; Chwirot, S.; Chwirot, B. W.; Pirozynska, E.; Zuchewicz, K.

    1996-03-01

    This study presents possibilities of neoplasm localization applying the laser-induced fluorescence method using new porphyrin derivatives -- complexes of protoporphyrin and amino acids. These compounds show a strong retention in diseased tissues. Their spectral characteristics and photosensitizing properties are similar to hematoporphyrin derivatives, so they can be used both in the photodynamic therapy method and neoplasm diagnosis.

  8. [The Spectral Analysis of Laser-Induced Plasma in Laser Welding with Various Protecting Conditions].

    PubMed

    Du, Xiao; Yang, Li-jun; Liu, Tong; Jiao, Jiao; Wang, Hui-chao

    2016-01-01

    The shielding gas plays an important role in the laser welding process and the variation of the protecting conditions has an obvious effect on the welding quality. This paper studied the influence of the change of protecting conditions on the parameters of laser-induced plasma such as electron temperature and electron density during the laser welding process by designing some experiments of reducing the shielding gas flow rate step by step and simulating the adverse conditions possibly occurring in the actual Nd : YAG laser welding process. The laser-induced plasma was detected by a fiber spectrometer to get the spectral data. So the electron temperature of laser-induced plasma was calculated by using the method of relative spectral intensity and the electron density by the Stark Broadening. The results indicated that the variation of protecting conditions had an important effect on the electron temperature and the electron density in the laser welding. When the protecting conditions were changed, the average electron temperature and the average electron density of the laser-induced plasma would change, so did their fluctuation range. When the weld was in a good protecting condition, the electron temperature, the electron density and their fluctuation were all low. Otherwise, the values would be high. These characteristics would have contribution to monitoring the process of laser welding. PMID:27228732

  9. Long-distance remote laser-induced breakdown spectroscopy using filamentation in air

    NASA Astrophysics Data System (ADS)

    Stelmaszczyk, Kamil; Rohwetter, Philipp; Méjean, Guillaume; Yu, Jin; Salmon, Estelle; Kasparian, Jérôme; Ackermann, Roland; Wolf, Jean-Pierre; Wöste, Ludger

    2004-11-01

    We demonstrate remote elemental analysis at distances up to 90m, using a laser-induced breakdown spectroscopy scheme based on filamentation induced by the nonlinear propagation of unfocused ultrashort laser pulses. A detailed signal analysis suggests that this technique, remote filament-induced breakdown spectroscopy, can be extended up to the kilometer range.

  10. Prospects for single-molecule detection in liquids by laser-induced fluorescence

    SciTech Connect

    Trkula, M.; Keller, R.A.; Martin, J.C.; Jett, J.H.; Dovichi, N.J.

    1983-01-01

    A laser-induced fluoresence determination of aqueous solutions of rhodamine 6G resulted in a detection limit of 18 attograms, or 22,000 molecules, of rhodamine 6G. These results allow the projection to single-molecule detection with reasonable improvements in the experimental apparatus.

  11. Use of laser-induced ionization to detect soot inception in premixed flames

    SciTech Connect

    Manzello, Samuel L.; Lee, Eui Ju; Mulholland, George W

    2005-08-20

    Experimental measurements of laser-induced ionization were performed for ethene-air premixed flames operated near the soot inception point. Soot was ionized with a pulsed laser operated at 532 nm. The ionization signal was collected with a tungsten electrode located in the postflame region. Ionization signals were collected by use of both single-electrode and dual-electrode configurations. Earlier laser-induced- ionization studies focused on the use of a single biased electrode to generate the electric field, with the burner head serving as the path to ground. In many practical combustion systems, a path to ground is not readily available. To apply the laser-induced- ionization diagnostic to these geometries, a dual-electrode geometry must be employed. The influence of electrode configuration, flame equivalence ratio, and flame height on ionization signal detection was determined. The efficacy of the laser-induced-ionization diagnostic in detecting soot inception in the postflame region of a premixed flame by use of a dual-electrode configuration was investigated. Of the dual-electrode configurations tested, the dual-electrode geometry oriented parallel to the laser beam was observed to be most sensitive for detecting the soot inception point in a premixed flame.

  12. Gene transfer into mammalian cells by use of a nanosecond pulsed laser-induced stress wave

    NASA Astrophysics Data System (ADS)

    Terakawa, Mitsuhiro; Ogura, Makoto; Sato, Shunichi; Wakisaka, Hitoshi; Ashida, Hiroshi; Uenoyama, Maki; Masaki, Yoshinori; Obara, Minoru

    2004-06-01

    Plasmid DNA has been successfully delivered to mammalian cells by applying a nanosecond pulsed laser-induced stress wave (LISW). Cells exposed to a LISW were selectively transfected with plasmids coding for green fluorescent protein. It was also shown that transient, mild cellular heating (~43 °C) was effective in improving the transfection efficiency.

  13. MULTISPECTRAL LASER-INDUCED FLUORESCENCE IMAGING SYSTEM FOR LARGE BIOLOGICAL SAMPLES

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Presented is a detailed description of a common aperture, multispectral laser-induced fluorescence imaging system developed to allow detection of fecal matter on agricultural products. With an expanded, 355 nm, Nd:YAG laser beam as the excitation source, fluorescence emission images in the blue, gr...

  14. Laser-induced fluorescence measurement of the dynamics of a pulsed planar sheath

    SciTech Connect

    Goeckner, M.J.; Malik, S.M. ); Conrad, J.R. ); Breun, R.A. )

    1994-04-01

    Using laser-induced fluorescence (LIF) the ion density near the edge of an expanding plasma sheath has been measured. These measurements utilized a transition of N[sup +][sub 2] [the P12 component of the [ital X] [sup 2][Sigma][sup +][sub [ital g

  15. Detection of fecal residue on poultry carcasses by laser induced fluorescence imaging techniques

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The potential use of laser-induced fluorescence imaging techniques was investigated for the detection of diluted fecal matters from various parts of the digestive tract, including colon, ceca, small intestine, and duodenum, on poultry carcasses. One of the challenges for using fluorescence imaging f...

  16. Broadband field-resolved terahertz detection via laser induced air plasma with controlled optical bias.

    PubMed

    Li, Chia-Yeh; Seletskiy, Denis V; Yang, Zhou; Sheik-Bahae, Mansoor

    2015-05-01

    We report a robust method of coherent detection of broadband THz pulses using terahertz induced second-harmonic (TISH) generation in a laser induced air plasma together with a controlled second harmonic optical bias. We discuss a role of the bias field and its phase in the process of coherent detection. Phase-matching considerations subject to plasma dispersion are also examined. PMID:25969238

  17. LLNL small-scale static spark machine: static spark sensitivity test

    SciTech Connect

    Foltz, M F; Simpson, L R

    1999-08-23

    Small-scale safety testing of explosives and other energetic materials is done in order to determine their sensitivity to various stimuli, such as friction, static spark, and impact. Typically this testing is done to discover potential handling problems that may exist for either newly synthesized materials of unknown behavior, or materials that have been stored for long periods of time. This report describes the existing ''Static Spark Test Apparatus'' at Lawrence Livermore National Laboratory (LLNL), as well as the method used to evaluate the relative static spark sensitivity of energetic materials. The basic design, originally developed by the Picatinny Arsenal in New Jersey, is discussed. The accumulated data for the materials tested to date is not included here, with the exception of specific examples that have yielded interesting or unusual results during the tests.

  18. Experimental Characterization of a Laser-Triggered, Gas-Insulated, Spark-Gap Switch

    NASA Astrophysics Data System (ADS)

    Camacho, J. F.; Brown, D. J.; Domonkos, M. T.; Ruden, E. L.; Schmitt-Sody, A.; Lucero, A. P.; Canright, J. P.; Miner, R. L.

    2015-11-01

    We have developed an experimental test bed to characterize the performance of a laser-triggered spark-gap switch as it transitions from photoionization to current conduction. The discharge of current through the switch is triggered by a focused 532-nm wavelength beam from a Q-switched Nd:YAG laser with a pulse duration of about 10 ns. The trigger pulse is delivered along the longitudinal axis of the switch, and the focal spot can be placed anywhere along the axis of the 5-mm, gas-insulated gap between the switch electrodes. The test bed is designed to support a variety of working gases (e.g., Ar, N2, He, H2) over a range of pressures. Electrical and optical diagnostics are used to measure switch performance as a function of parameters such as charge voltage, trigger pulse energy, insulating gas pressure, and gas species. Data from our experiments will be used to determine the minimum conditions necessary to induce the breakdown and conduction of a gas-insulated electrode gap in the presence of laser-induced photoionization. The electromagnetic particle-in-cell code ICEPIC will be used to produce numerical simulations of the laser-initiated arc discharge, and the experimental data will be used to validate the calculations.

  19. Dual channel formation in a laser-triggered spark gap

    NASA Astrophysics Data System (ADS)

    Kushner, M. J.; Kimura, W. D.; Ford, D. H.; Byron, S. R.

    1985-12-01

    During self-break in spark-gap switches, multiple streamers can form in close proximity to one another. The rate of expansion of these streamers is sufficiently fast that they can interact during the current pulse. To help understand how these closely spaced, expanding spark columns interact, a laser-triggered spark gap has been studied in which two parallel columns (separation 1.3 mm) are simultaneously preionized, resulting in a pair of nearly identical, axisymmetric spark columns. The spark gap (electrode separation 1.2 cm) switches a 100 ns, 40-60 kV, 12-20 kA, 1.5 Ω waterline. Interferograms of the expanding arc channels are obtained with a laser interferometer having a time and spatial resolution of 5 ns and 10 μm, respectively. Voltage and current were measured with an internal capacitive-voltage divider and a current viewing resistor. The interferograms show that for initially identical axisymmetric columns, the individual channels do not merge into a single larger axisymmetric spark column. Instead, regions of high gas density remain inside the combined column long into the recovery period. The columns also do not remain axisymmetric as they grow, indicating a long-range interaction between the channels. The voltage drop and resistance of the dual channel spark gaps changes by less than 15% from that of a single spark channel. A scaling model is presented to explain the resistance measurements and to predict the change in resistance for multichannel spark gaps.

  20. Use of laser-induced spark for studying ignition stability and unburned hydrogen escaping from laminar diluted hydrogen diffusion jet flames

    NASA Astrophysics Data System (ADS)

    Phuoc, Tran X.; Chen, Ruey-Hung

    2007-08-01

    Ignition and unburned hydrogen escaping from hydrogen jet diffusion flames diluted with nitrogen up to 70% were experimentally studied. The successful ignition locations were about 2/3 of the flame length above the jet exit for undiluted flames and moved much closer to the exit for diluted flames. For higher levels of dilution or higher flow rates, there existed a region within which a diluted hydrogen diffusion flame can be ignited and burns with a stable liftoff height. This is contrary to previous findings that pure and diluted hydrogen jet diffusion cannot achieve a stable lifted flame configuration. With liftoff, the flame is noisy and short with significant amount of unburned hydrogen escaping into the product gases. If ignition is initiated below this region, the flame propagates upstream quickly and attaches to the burner rim. Results from measurements of unburned hydrogen in the combustion products showed that the amount of unburned hydrogen increased as the nitrogen dilution level was increased. Thus, hydrogen diffusion flame diluted with nitrogen cannot burn completely.

  1. Spark assisted chemical engraving (SACE) in microfactory

    NASA Astrophysics Data System (ADS)

    Wüthrich, R.; Fujisaki, K.; Couthy, Ph; Hof, L. A.; Bleuler, H.

    2005-10-01

    Spark assisted chemical engraving (SACE) is a method for 3D microstructuring of glass or other non-conductive materials with high aspect ratio and smooth surface quality. It is applicable for rapid prototyping of microfluidic devices, for MEMS interfacing and similar applications. Typical feature size is in the hundreds of micrometres, down to a few tens of micrometres. It is a table-top technology requiring no clean rooms and no masks and with very modest space usage. It is thus well suited for microfactories. This paper gives a basic introduction to SACE and some machining examples.

  2. Anticipating change, sparking innovation: framing the future.

    PubMed

    Petersen, Donna J; Finnegan, John R; Spencer, Harrison C

    2015-03-01

    As the 100th anniversary of the 1915 Welch-Rose report approaches, the Association of Schools and Programs of Public Health (ASPPH) has been pursuing two initiatives to spark innovation in academic partnerships for enhancing population health: (1) Framing the Future: The Second 100 Years of Education for Public Health and (2) Reconnecting Public Health and Care Delivery to Improve the Health of Populations. We describe how ASPPH-member schools and programs accredited by the Council on Education for Public Health, along with their extraordinarily diverse array of partners, are working to improve education that better prepares health professionals to meet 21st-century population health needs. PMID:25706017

  3. The Miller volcanic spark discharge experiment.

    PubMed

    Johnson, Adam P; Cleaves, H James; Dworkin, Jason P; Glavin, Daniel P; Lazcano, Antonio; Bada, Jeffrey L

    2008-10-17

    Miller's 1950s experiments used, besides the apparatus known in textbooks, one that generated a hot water mist in the spark flask, simulating a water vapor-rich volcanic eruption. We found the original extracts of this experiment in Miller's material and reanalyzed them. The volcanic apparatus produced a wider variety of amino acids than the classic one. Release of reduced gases in volcanic eruptions accompanied by lightning could have been common on the early Earth. Prebiotic compounds synthesized in these environments could have locally accumulated, where they could have undergone further processing. PMID:18927386

  4. Relativistic electrons from sparks in the laboratory

    NASA Astrophysics Data System (ADS)

    Østgaard, N.; Carlson, B. E.; Nisi, R. S.; Gjesteland, T.; Grøndahl, Ø.; Skeltved, A.; Lehtinen, N. G.; Mezentsev, A.; Marisaldi, M.; Kochkin, P.

    2016-03-01

    Discharge experiments were carried out at the Eindhoven University of Technology in 2013. The experimental setup was designed to search for electrons produced in meter-scale sparks using a 1 MV Marx generator. Negative voltage was applied to the high voltage (HV) electrode. Five thin (1 mm) plastic detectors (5 cm2 each) were distributed in various configurations close to the spark gap. Earlier studies have shown (for HV negative) that X-rays are produced when a cloud of streamers is developed 30-60 cm from the negative electrode. This indicates that the electrons producing the X-rays are also accelerated at this location, that could be in the strong electric field from counterstreamers of opposite polarity. Comparing our measurements with modeling results, we find that ˜300 keV electrons produced about 30-60 cm from the negative electrode are the most likely source of our measurements. A statistical analysis of expected detection of photon bursts by these fiber detectors indicates that only 20%-45% of the detected bursts could be from soft (˜10 keV) photons, which further supports that the majority of detected bursts are produced by relativistic electrons.

  5. A generalized chemistry version of SPARK

    NASA Technical Reports Server (NTRS)

    Carpenter, Mark H.

    1988-01-01

    An extension of the reacting H2-air computer code SPARK is presented, which enables the code to be used on any reacting flow problem. Routines are developed calculating in a general fashion, the reaction rates, and chemical Jacobians of any reacting system. In addition, an equilibrium routine is added so that the code will have frozen, finite rate, and equilibrium capabilities. The reaction rate for the species is determined from the law of mass action using Arrhenius expressions for the rate constants. The Jacobian routines are determined by numerically or analytically differentiating the law of mass action for each species. The equilibrium routine is based on a Gibbs free energy minimization routine. The routines are written in FORTRAN 77, with special consideration given to vectorization. Run times for the generalized routines are generally 20 percent slower than reaction specific routines. The numerical efficiency of the generalized analytical Jacobian, however, is nearly 300 percent better than the reaction specific numerical Jacobian used in SPARK.

  6. Nanosecond laser-induced ablation and laser-induced shockwave structuring of polymer foils down to sub-μm patterns

    NASA Astrophysics Data System (ADS)

    Lorenz, P.; Bayer, L.; Ehrhardt, M.; Zimmer, K.; Engisch, L.

    2015-03-01

    Micro- and nanostructures exhibit a growing commercial interest where a fast, cost-effective, and large-area production is attainable. Laser methods have a great potential for the easy fabrication of surface structures into flexible polymer foils like polyimide (PI). In this study two different concepts for the structuring of polymer foils using a KrF excimer laser were tested and compared: the laser-induced ablation and the laser-induced shock wave structuring. The direct front side laser irradiation of these polymers allows the fabrication of different surface structures. For example: The low laser fluence treatment of PI results in nano-sized cone structures where the cone density can be controlled by the laser parameters. This allows inter alia the laser fabrication of microscopic QR code and high-resolution grey-tone images. Furthermore, the laser treatment of the front side of the polymer foil allows the rear side structuring due to a laserinduced shock wave. The resultant surface structures were analysed by optical and scanning electron microscopy (SEM) as well as white light interferometry (WLI).

  7. SPARK Peer Helper Program, 1993-94. OER Report.

    ERIC Educational Resources Information Center

    Goldberg, Phyllis

    The Peer Helper Program was administered by Substance Prevention, Abuse Rehabilitation, and Knowledge (SPARK). Since its beginning in 1971, SPARK has addressed issues such as drug use, teenage pregnancy, HIV/AIDS, sexual abuse and other forms of violence. The Peer Helper Program was designed to train students in the skills required to assist peers…

  8. Dual Spark Plugs For Stratified-Charge Rotary Engine

    NASA Technical Reports Server (NTRS)

    Abraham, John; Bracco, Frediano V.

    1996-01-01

    Fuel efficiency of stratified-charge, rotary, internal-combustion engine increased by improved design featuring dual spark plugs. Second spark plug ignites fuel on upstream side of main fuel injector; enabling faster burning and more nearly complete utilization of fuel.

  9. A cosmic dust composition analyzed with a spark ion source

    NASA Technical Reports Server (NTRS)

    Auer, S.

    1974-01-01

    Simulated iron micrometeoroids were fired unto a capacitor-type micrometeoroid detector which responded to an impact with a spark. Large ion currents were extracted from the spark and analyzed in a crude ion time-of-flight mass spectrometer. The mass spectra show the elements of both detector and particle materials.

  10. Properties and preparation of ceramic insulators for spark plugs

    NASA Technical Reports Server (NTRS)

    Silsbee, F B; Honaman, R K; Fonseca, E L; Bleininger, A V; Staley, H F

    1920-01-01

    Report describes in detail the preliminary experiments which were made on the conductivity of spark-plug insulators in order to develop a satisfactory comparative method for testing various spark-plug materials. Materials tested were cements, porcelain, feldspar, and quartz.

  11. Development of a SPARK Training Dataset

    SciTech Connect

    Sayre, Amanda M.; Olson, Jarrod R.

    2015-03-01

    In its first five years, the National Nuclear Security Administration’s (NNSA) Next Generation Safeguards Initiative (NGSI) sponsored more than 400 undergraduate, graduate, and post-doctoral students in internships and research positions (Wyse 2012). In the past seven years, the NGSI program has, and continues to produce a large body of scientific, technical, and policy work in targeted core safeguards capabilities and human capital development activities. Not only does the NGSI program carry out activities across multiple disciplines, but also across all U.S. Department of Energy (DOE)/NNSA locations in the United States. However, products are not readily shared among disciplines and across locations, nor are they archived in a comprehensive library. Rather, knowledge of NGSI-produced literature is localized to the researchers, clients, and internal laboratory/facility publication systems such as the Electronic Records and Information Capture Architecture (ERICA) at the Pacific Northwest National Laboratory (PNNL). There is also no incorporated way of analyzing existing NGSI literature to determine whether the larger NGSI program is achieving its core safeguards capabilities and activities. A complete library of NGSI literature could prove beneficial to a cohesive, sustainable, and more economical NGSI program. The Safeguards Platform for Automated Retrieval of Knowledge (SPARK) has been developed to be a knowledge storage, retrieval, and analysis capability to capture safeguards knowledge to exist beyond the lifespan of NGSI. During the development process, it was necessary to build a SPARK training dataset (a corpus of documents) for initial entry into the system and for demonstration purposes. We manipulated these data to gain new information about the breadth of NGSI publications, and they evaluated the science-policy interface at PNNL as a practical demonstration of SPARK’s intended analysis capability. The analysis demonstration sought to answer the

  12. Airborne laser-spark for ambient desorption/ionisation.

    PubMed

    Bierstedt, Andreas; Riedel, Jens

    2016-01-01

    A novel direct sampling ionisation scheme for ambient mass spectrometry is presented. Desorption and ionisation are achieved by a quasi-continuous laser induced plasma in air. Since there are no solid or liquid electrodes involved the ion source does not suffer from chemical interferences or fatigue originating from erosive burning or from electrode consumption. The overall plasma maintains electro-neutrality, minimising charge effects and accompanying long term drift of the charged particles trajectories. In the airborne plasma approach the ambient air not only serves as the plasma medium but at the same time also slows down the nascent ions via collisional cooling. Ionisation of the analyte molecules does not occur in the plasma itself but is induced by interaction with nascent ionic fragments, electrons and/or far ultraviolet photons in the plasma vicinity. At each individual air-spark an audible shockwave is formed, providing new reactive species, which expands concentrically and, thus, prevents direct contact of the analyte with the hot region inside the plasma itself. As a consequence the interaction volume between plasma and analyte does not exceed the threshold temperature for thermal dissociation or fragmentation. Experimentally this indirect ionisation scheme is demonstrated to be widely unspecific to the chemical nature of the analyte and to hardly result in any fragmentation of the studied molecules. A vast ensemble of different test analytes including polar and non-polar hydrocarbons, sugars, low mass active ingredients of pharmaceuticals as well as natural biomolecules in food samples directly out of their complex matrices could be shown to yield easily accessible yet meaningful spectra. Since the plasma medium is humid air, the chemical reaction mechanism of the ionisation is likely to be similar to other ambient ionisation techniques. Wir stellen hier eine neue Ionisationsmethode für die Umgebungsionisation (ambient ionisation) vor. Sowohl die

  13. Note: A novel technique for analysis of aqueous solutions by laser-induced breakdown spectroscopy

    SciTech Connect

    Rusak, D. A.; Bell, Z. T.; Anthony, T. P.

    2015-11-15

    Surface-enhanced Raman spectroscopy (SERS) substrates typically consist of gold or silver nanoparticles deposited on a non-conductive substrate. In Raman spectroscopy, the nanoparticles produce an enhancement of the electromagnetic field which, in turn, leads to greater electronic excitation of molecules in the local environment. Here, we show that these same surfaces can be used to enhance the signal-to-noise ratio obtained in laser-induced breakdown spectroscopy of aqueous solutions. In this case, the SERS substrates not only lower breakdown thresholds and lead to more efficient plasma initiation but also provide an appropriately wettable surface for the deposition of the liquid. We refer to this technique as surface-enhanced laser-induced breakdown spectroscopy.

  14. Ultraviolet femtosecond and nanosecond laser ablation of silicon: Ablation efficiency and laser-induced plasma expansion

    SciTech Connect

    Zeng, Xianzhong; Mao, Xianglei; Greif, Ralph; Russo, Richard E.

    2004-03-23

    Femtosecond laser ablation of silicon in air was studied and compared with nanosecond laser ablation at ultraviolet wavelength (266 nm). Laser ablation efficiency was studied by measuring crater depth as a function of pulse number. For the same number of laser pulses, the fs-ablated crater was about two times deeper than the ns-crater. The temperature and electron number density of the pulsed laser-induced plasma were determined from spectroscopic measurements. The electron number density and temperature of fs-pulse plasmas decreased faster than ns-pulse plasmas due to different energy deposition mechanisms. Images of the laser-induced plasma were obtained with femtosecond time-resolved laser shadowgraph imaging. Plasma expansion in both the perpendicular and the lateral directions to the laser beam were compared for femtosecond and nanosecond laser ablation.

  15. Picosecond laser-induced breakdown at 5321 and 5347 A - Observation of frequency-dependent behavior

    NASA Technical Reports Server (NTRS)

    Smith, W. L.; Bechtel, J. H.; Bloembergen, N.

    1977-01-01

    A study is presented of picosecond laser-induced breakdown at 3547 and 5321 A of several materials. The thresholds obtained for breakdown at 5321 A are compared to previous results obtained at 1.064 microns using the same laser system. This comparison illustrates the transition of bulk laser-induced breakdown as it becomes increasingly frequency dependent. UV picosecond pulses are obtained by mixing 5321 A and 1.064 micron pulses in a KH2PO4 crystal. Upper and lower bounds on the 3547 A breakdown threshold are defined, although some effects of walk-off distortion and self-focusing are observed. The results are discussed with reference to models for the intrinsic processes involved in the breakdown, i.e., avalanche and multiphoton ionization.

  16. Hyperspectral laser-induced flourescence imaging for assessing internal quality of kiwi fruit

    NASA Astrophysics Data System (ADS)

    Liu, Muhua; Liao, Yifeng; Zhou, Xiaomei

    2008-03-01

    This paper describes an experimental study on non-destructive methods for predicting quality of kiwifruits using fluorescence imaging. The method is based on hyperspectral laser-induced fluorescence imaging in the region between 700 and 1110 nm, and estimates the kiwifruits quality in terms of internal sugar content and firmness. A station for acquiring hyperspectral laser-induced fluorescence imaging has been designed and carefully choosing each component. The fluorescence imaging acquired by the station has been pre-processed by selecting regions of interest (ROIs) of 50 100 × pixels. A line regressing prediction method estimates the quality of kiwifruit samples. The results obtained in classification show that the station and prediction model enables the correct discrimination of kiwifruits internal sugar content and firmness with a percentage of r= 98.5%, SEP=0.4 and r=99.9%, SEP=0.62.

  17. The effect of pseudo-accumulation in the measurement of fatigue laser-induced damage threshold

    NASA Astrophysics Data System (ADS)

    Melninkaitis, A.; Mirauskas, J.; Jupé, M.; Ristau, D.; Arenberg, J. W.; Sirutkaitis, V.

    2008-10-01

    Laser-induced damage threshold determination as a function of the number of incident pulses on a specific optic is a classic problem in laser damage studies. There are several models of the fundamental mechanisms explaining the fatigue laser damage behavior including temperature accumulation and changes of electronic or chemical material structure. Herewith we discuss the effects of unstable laser radiation on S-on-1 laser-induced damage probability. Numerical simulations of S-on-1 measurements for specific cases of defect densities, spot sizes and beam jitters are performed. It is demonstrated that the statistical effects of "pseudo-accumulation" reasoned by unstable laser radiation in transparent dielectrics containing nanometer sized defects leads to accumulation-like behavior. The magnitudes of the random beam walking and the energy fluctuations are directly related to the damage probability. Experimental results are also introduced to illustrate the theoretical results.

  18. Laser induced plane acoustic wave generation, propagation, and interaction with rigid structures in water

    NASA Astrophysics Data System (ADS)

    Ko, Seung H.; Ryu, Sang G.; Misra, Nipun; Pan, Heng; Grigoropoulos, Costas P.; Kladias, Nick; Panides, Elias; Domoto, Gerald A.

    2008-10-01

    Short pulsed laser induced single acoustic wave generation, propagation, interaction with rigid structures, and focusing in water are experimentally and numerically studied. A large area short duration single plane acoustic wave was generated by the thermoelastic interaction of a homogenized nanosecond pulsed laser beam with a liquid-solid interface and propagated at the speed of sound in water. Laser flash schlieren photography was used to visualize the transient interaction of the plane acoustic wave with various submerged rigid structures [(a) a single block, (b) double blocks, (c) 33° tilted single block, and (d) concave cylindrical acoustic lens configurations]. Excellent agreement between the experimental results and numerical simulation is observed. Our simulation results demonstrate that the laser induced planar acoustic wave can be focused down to several tens of micron size and several bars in pressure.

  19. Spectral analysis of Qinling Mountain rock using laser induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Luo, W. F.; Zhao, X. X.; Zhu, H. Y.; Xie, D. H.; Liu, J.; Jin, P. F.

    2013-12-01

    The composition of Qinling Mountain rock is studied using laser induced breakdown spectroscopy for the first time. Elements Ca, Mg, Cu, Fe, C, Na, Si, Al, Ti, K and Mn are identified qualitatively. Using an improved iterative Boltzmann plot method, the electron temperature of 16,825 K is inferred with Ca I lines at 422.67, 428.30, 443.49, 445.48, and 585.74 nm, while the ionic temperature of 15,587 K is obtained with Ca II lines at 393.37, 396.85, and 370.60 nm. The electron number density of 1.49 ? 10? cm? is inferred from the Stark broadened profile of Ca I 422.67 nm averaged with 10 single spectra. The laser-induced rock plasma is verified to be in local thermodynamic equilibrium and to be optically thin based on the experimental results.

  20. Laser induced damage in multilayer dielectric gratings due to ultrashort laser pulses. Revision 1

    SciTech Connect

    Shore, B.W.; Stuart, B.C.; Feit, M.D.; Rubenchik, A.M.; Perry, M.D.

    1995-07-11

    Chirped pulse amplification is increasingly used to produce intense ultrashort laser pulses. When high-efficiency gratings are the dispersive element, as in the LLNL Petawatt laser, their susceptibility to laser induced damage constitutes a limitation on the peak intensities that can be reached. To obtain robust gratings, it is necessary to understand the causes of short-pulse damage, and to recognize the range of design options for high efficiency gratings. Metal gratings owe their high efficiency to their high conductivity. To avoid the inevitable light absorption that accompanies conductivity, we have developed designs for high efficiency rejection gratings that use only transparent dielectric materials. These combine the reflectivity of a multi-layer dielectric stack with a diffraction grating. We report here our present understanding of short-pulse laser induced damage, as it applies to dielectric gratings.

  1. Laser induced damage in multilayer dielectric gratings due to ultrashort laser pulses

    SciTech Connect

    Shore, B.W.; Stuart, B.C.; Feit, M.D.; Rubenchik, A.M.; Perry, M.D.

    1995-05-26

    Chirped pulse amplification is increasingly used to produce intense ultrashort laser pulses. When high-efficiency gratings are the dispersive element, as in the LLNL Petawatt laser, their susceptibility to laser induced damage constitutes a limitation on the peak intensities that can be reached. To obtain robust gratings, it is necessary to understand the causes of short-pulse damage, and to recognize the range of design options for high efficiency gratings. Metal gratings owe their high efficiency to their high conductivity. To avoid the inevitable light absorption that accompanies conductivity, we have developed designs for high efficiency reflection gratings that use only transparent dielectric materials. These combine the reflectivity of a multilayer dielectric stack with a diffraction grating. We report here our present understanding of short-pulse laser induced damage, as it applies to dielectric gratings.

  2. Crystallo-optic diagnostics method of the soft laser-induced effects in biological fluids

    NASA Astrophysics Data System (ADS)

    Skopinov, S. A.; Yakovleva, S. V.

    1991-05-01

    Presently, it is well known that individual cells"2 and higher organisms3'4 exhibit a marked response to soft laser irradiation in certain parts of the visible and near infrared spectral ranges. Broad clinical applications of laser therapy and slow progress in understanding of the physical, chemical and biological mechanisms of this phenomenon make the task to search new methods of objectivisation of laser-induces bioeffects very insistent. In this paper we give a short review of the methods of structural-optical diagnostics of the soft laser-induced effects in biofluids (blood and its fractions, saliva, juices, mucuses, exudations, etc.) and suggest their applications in experimental and clinical studies of the soft laser bioeffects.

  3. Laser-induced damage behaviors of antireflective coatings at cryogenic condition.

    PubMed

    Wang, He; Zhang, Weili; He, Hongbo

    2012-12-20

    The laser-induced damage to antireflective coatings on Yb:YAG crystals under different temperatures was investigated. An optical profiler, field-emission scanning-electron microscopy, and a step profiler were used to determine the damage morphology, including size and depth. The results show that there is about 5 J/cm(2) decrease in the laser-induced damage threshold of cryogenic conditions compared to that of room temperature in 1-on-1 test mode, and a 3 J/cm(2) decrease in 100-on-1 mode. There is an accumulation effect in both cases. Meanwhile, the damage areas and depths are also much larger under cryogenic conditions. The precipitation of the subsurface defects in the substrate and the thermal stress in the interface between the film and the substrate under cryogenic conditions are considered to be the key factors in the unique damage behaviors. PMID:23262610

  4. Time-synchronized continuous wave laser-induced fluorescence on an oscillatory xenon discharge

    SciTech Connect

    MacDonald, N. A.; Cappelli, M. A.; Hargus, W. A. Jr.

    2012-11-15

    A novel approach to time-synchronizing laser-induced fluorescence measurements to an oscillating current in a 60 Hz xenon discharge lamp using a continuous wave laser is presented. A sample-hold circuit is implemented to separate out signals at different phases along a current cycle, and is followed by a lock-in amplifier to pull out the resulting time-synchronized fluorescence trace from the large background signal. The time evolution of lower state population is derived from the changes in intensity of the fluorescence excitation line shape resulting from laser-induced fluorescence measurements of the 6s{sup Prime }[1/2]{sub 1}{sup 0}-6p{sup Prime }[3/2]{sub 2} xenon atomic transition at {lambda}= 834.68 nm. Results show that the lower state population oscillates at twice the frequency of the discharge current, 120 Hz.

  5. Influence of external magnetic field on laser-induced gold nanoparticles fragmentation

    NASA Astrophysics Data System (ADS)

    Serkov, A. A.; Rakov, I. I.; Simakin, A. V.; Kuzmin, P. G.; Shafeev, G. A.; Mikhailova, G. N.; Antonova, L. Kh.; Troitskii, A. V.; Kuzmin, G. P.

    2016-08-01

    Laser-assisted fragmentation is an efficient method of the nanoparticles size and morphology control. However, its exact mechanisms are still under consideration. One of the remaining problems is the plasma formation, inevitably occurring upon the high intensity laser irradiation. In this Letter, the role of the laser-induced plasma is studied via introduction of high-intensity external magnetic field (up to 7.5 T). Its presence is found to cause the plasma emission to start earlier regarding to a laser pulse, also increasing the plume luminosity. Under these conditions, the acceleration of nanoparticles fragmentation down to a few nanometers is observed. Laser-induced plasma interaction with magnetic field and consequent energy transfer from plasma to nanoparticles are discussed.

  6. Qualitative and quantitative analysis of environmental samples by laser-induced breakdown spectrometry

    NASA Astrophysics Data System (ADS)

    Zorov, N. B.; Popov, A. M.; Zaytsev, S. M.; Labutin, T. A.

    2015-10-01

    The key achievements in the determination of trace amounts of components in environmental samples (soils, ores, natural waters, etc.) by laser-induced breakdown spectrometry are considered. Unique capabilities of this method make it suitable for rapid analysis of metals and alloys, glasses, polymers, objects of cultural heritage, archaeological and various environmental samples. The key advantages of the method that account for its high efficiency are demonstrated, in particular, a small amount of analyzed material, the absence of sample preparation, the possibility of local and remote analysis of either one or several elements. The use of chemometrics in laser-induced breakdown spectrometry for qualitative sample classification is described in detail. Various approaches to improving the figures of merit of quantitative analysis of environmental samples are discussed. The achieved limits of detection for most elements in geochemical samples are critically evaluated. The bibliography includes 302 references.

  7. Inkjet Printing of Viscous Monodisperse Microdroplets by Laser-Induced Flow Focusing

    NASA Astrophysics Data System (ADS)

    Delrot, Paul; Modestino, Miguel A.; Gallaire, François; Psaltis, Demetri; Moser, Christophe

    2016-08-01

    The on-demand generation of viscous microdroplets to print functional or biological materials remains challenging using conventional inkjet-printing methods, mainly due to aggregation and clogging issues. In an effort to overcome these limitations, we implement a jetting method to print viscous microdroplets by laser-induced shockwaves. We experimentally investigate the dependence of the jetting regimes and the droplet size on the laser-pulse energy and on the inks' physical properties. The range of printable liquids with our device is significantly extended compared to conventional inkjet printers's performances. In addition, the laser-induced flow-focusing phenomenon allows us to controllably generate viscous microdroplets up to 210 mPa s with a diameter smaller than the nozzle from which they originated (200 μ m ). Inks containing proteins are printed without altering their functional properties, thus demonstrating that this jetting technique is potentially suitable for bioprinting.

  8. Laser induced damage of sapphire and titanium doped sapphire crystals under femtosecond to nanosecond laser irradiation

    NASA Astrophysics Data System (ADS)

    Bussière, B.; Utéza, O.; Sanner, N.; Sentis, M.; Riboulet, G.; Vigroux, L.; Commandré, M.; Wagner, F.; Natoli, J.-Y.; Chambaret, J.-P.

    2009-10-01

    The use of large Ti:Sapphire crystals in ultra fast high peak power laser amplifiers makes crucial the problem of crystal laser induced damage. These works aim to quantify the laser induced damage threshold (LIDT) of Sapphire and Ti:Sapphire crystals under femtosecond, picosecond and nanosecond laser pulse irradiations, which are typically encountered in such laser chains. Furthermore, a study of the influence of cryogenic conditions on the LIDT of Ti:Sapphire crystals and of their anti-reflection coating has been performed. The results are important to understand the mechanisms leading to the damage, and to reveal the key parameters which will have to be optimized in future high peak power laser chains.

  9. Laser-induced plasma spectroscopy of hydrogen Balmer series in laboratory air.

    PubMed

    Swafford, Lauren D; Parigger, Christian G

    2014-01-01

    Stark-broadened emission profiles for the hydrogen alpha and beta Balmer series lines in plasma are measured to characterize electron density and temperature. Plasma is generated using a typical laser-induced breakdown spectroscopy (LIBS) arrangement that employs a focused Q-switched neodymium-doped yttrium aluminum garnet (Nd : YAG) laser, operating at the fundamental wavelength of 1064 nm. The temporal evolution of the hydrogen Balmer series lines is explored using LIBS. Spectra from the plasma are measured following laser-induced optical breakdown in laboratory air. The electron density is primarily inferred from the Stark-broadened experimental data collected at various time delays. Due to the presence of nitrogen and oxygen in air, the hydrogen alpha and beta lines become clearly discernible from background radiation for time delays of 0.4 and 1.4 μs, respectively. PMID:25226255

  10. Trace species concentration and temperature measurements at high pressure using laser-induced grating spectroscopy

    NASA Astrophysics Data System (ADS)

    Brown, Michael S.; DeBarber, Peter A.; Cummings, Eric B.; Hornung, Hans G.

    1995-09-01

    We have recorded laser-induced grating signals from mixtures of NO2 and air over a pressure range extending from less that 100 kPa (1 atm) to 10 MPa (100 atm). Signals generated from concentrations of NO2 at the part-per-million level have been successfully detected with high signal-to-noise rations. The measurements were made using the technique of laser-induced thermal acoustics (LITA). Analysis of the acquired data was made using a comprehensive theory which includes the hydrodynamic response of the fluid and finite beam-size effects. The observed pressure dependence of the peak amplitude signals is consistent with the theory. Additionally, least squares fits between the theory and the temporally resolved signal yield accurate values of the local sound speed and thermal diffusivity. Determination of the local sound speed provides a measurement of the local temperature.

  11. The effect of multiple wavelengths on Laser-induced damage in DKDP crystals

    SciTech Connect

    Carr, C W; Auerbach, J M

    2005-07-11

    Laser-induced damage is a key factor that constrains how optical materials are used in high-power laser systems. In this work the size and density of bulk laser-induced damage sites formed during frequency tripling in a DKDP crystal are studied. The characteristics of the damage sites formed during tripling, where 1053-nm, 526-nm, and 351-nm light is simultaneously present, are compared to damage sites formed by 351-nm light alone. The fluence of each wavelength is calculated as a function of depth with a full 4D(x,y,z,t) frequency conversion code and compared to measured damage density and size distributions. The density of damage is found be predominantly governed by 351-nm light with some lesser, though non-negligible contribution from 526-nm light. The morphology of the damage sites, however, is seen to be relatively insensitive to wavelength and depend only on total fluence of all wavelengths present.

  12. Absolute tracer dye concentration using airborne laser-induced water Raman backscatter

    NASA Technical Reports Server (NTRS)

    Hoge, F. E.; Swift, R. N.

    1981-01-01

    The use of simultaneous airborne-laser-induced dye fluorescence and water Raman backscatter to measure the absolute concentration of an ocean-dispersed tracer dye is discussed. Theoretical considerations of the calculation of dye concentration by the numerical comparison of airborne laser-induced fluorescence spectra with laboratory spectra for known dye concentrations using the 3400/cm OH-stretch water Raman scatter as a calibration signal are presented which show that minimum errors are obtained and no data concerning water mass transmission properties are required when the laser wavelength is chosen to yield a Raman signal near the dye emission band. Results of field experiments conducted with an airborne conical scan lidar over a site in New York Bight into which rhodamine dye had been injected in a study of oil spill dispersion are then indicated which resulted in a contour map of dye concentrations, with a minimum detectable dye concentration of approximately 2 ppb by weight.

  13. Preliminary Design of Laser - induced Breakd own Spectroscopy for Proto - MPEX

    SciTech Connect

    Shaw, Guinevere C; Biewer, T.M.; Martin, Madhavi Z; Martin, Rodger Carl

    2014-01-01

    Laser-induced breakdown spectroscopy (LIBS) is a technique for measuring surface matter composition. LIBS is performed by focusing laser radiation onto a target surface, ablating the surface, forming a plasma, and analyzing the light produced. LIBS surface analysis is a possible diagnostic for characterizing plasma-facing materials in ITER. Oak Ridge National Laboratory (ORNL) has enabled the initial installation of a laser-induced breakdown spectroscopy diagnostic on the prototype Material-Plasma Exposure eXperiment (Proto-MPEX), which strives to mimic the conditions found at the surface of the ITER divertor. This paper will discuss the LIBS implementation on Proto-MPEX, preliminary design of the fiber optic LIBS collection probe, and the expected results.

  14. Experimental investigation on dynamic characteristics and strengthening mechanism of laser-induced cavitation bubbles.

    PubMed

    Ren, X D; He, H; Tong, Y Q; Ren, Y P; Yuan, S Q; Liu, R; Zuo, C Y; Wu, K; Sui, S; Wang, D S

    2016-09-01

    The dynamic features of nanosecond laser-induced cavitation bubbles near the light alloy boundary were investigated with the high-speed photography. The shock-waves and the dynamic characteristics of the cavitation bubbles generated by the laser were detected using the hydrophone. The dynamic features and strengthening mechanism of cavitation bubbles were studied. The strengthening mechanisms of cavitation bubble were discussed when the relative distance parameter γ was within the range of 0.5-2.5. It showed that the strengthening mechanisms caused by liquid jet or shock-waves depended on γ much. The research results provided a new strengthening method based on laser-induced cavitation shotless peening (CSP). PMID:27150764

  15. Mechanisms of two-color laser-induced field-free molecular orientation.

    PubMed

    Spanner, Michael; Patchkovskii, Serguei; Frumker, Eugene; Corkum, Paul

    2012-09-14

    Two mechanisms of two-color (ω+2ω) laser-induced field-free molecular orientation, based on the hyperpolarizability and ionization depletion, are explored and compared. The CO molecule is used as a computational example. While the hyperpolarizability mechanism generates small amounts of orientation at intensities below the ionization threshold, ionization depletion quickly becomes the dominant mechanism as soon as ionizing intensities are reached. Only the ionization mechanism leads to substantial orientation (e.g., on the order of ≳0.1). For intensities typical of laser-induced molecular alignment and orientation experiments, the two mechanisms lead to robust, characteristic timings of the field-free orientation wave-packet revivals relative to the alignment revivals and the revival time. The revival timings can be used to detect the active orientation mechanism experimentally. PMID:23005623

  16. On two optomechanical effects of laser-induced electrostriction in dielectric liquids

    NASA Astrophysics Data System (ADS)

    Gojani, Ardian B.; Bejtullahu, Rasim; Obayashi, Shigeru

    2014-09-01

    This paper presents electrostriction from the phenomenological perspective, and gives details on two mechanical effects arising from laser-matter interaction. Electrostriction is the tendency of materials to compress in the presence of a varying electric field. In this paper, the investigated materials are polar and nonpolar dielectric liquids. It is stressed that the dominant factor is the time evolution of the laser pulse, which causes tensile stresses and acoustic waves. The study is supported by experimental realization of electrostriction, which can be detected only at favorable conditions (observed in water, but not in castor oil). This study will shed light in developing measurement techniques (e.g., laser-induced grating spectroscopy) and in explaining the onset of cavities and laser-induced liquid breakdown.

  17. [Effect of flat-mirror device on laser-induced plasma radiation characteristics].

    PubMed

    Chen, Jin-Zhong; Bai, Jin-Ning; Chen, Zhen-Yu; Cheng, Chen; Sun, Jiang; Wei, Yan-Hong

    2013-08-01

    To improve the quality of laser-induced breakdown spectroscopy, flat-mirror device was proposed. The effects of flat-mirror device on the radiation characteristics of laser-induced plasma were studied. The experimental results showed that when the device consisted of three flat-mirrors placed around the plasma, the spectral line intensity of Mg, Fe, Ba, Ti and Al increases by about 116.2%, 96.43%, 90.93%, 102.1% and 98.57% than that without flat-mirror device, and the signal-to-noise raises by around 39.17%, 32.48%, 38.07%, 39.95% and 21.30%,respectively. By measuring the plasma parameters, the mechanism of the radiation enhancement obtained with the device consisting of three flat-mirrors was explained. This method was an effective way to improve the detection capacity of LIBS. PMID:24159841

  18. Time-synchronized continuous wave laser-induced fluorescence on an oscillatory xenon discharge.

    PubMed

    MacDonald, N A; Cappelli, M A; Hargus, W A

    2012-11-01

    A novel approach to time-synchronizing laser-induced fluorescence measurements to an oscillating current in a 60 Hz xenon discharge lamp using a continuous wave laser is presented. A sample-hold circuit is implemented to separate out signals at different phases along a current cycle, and is followed by a lock-in amplifier to pull out the resulting time-synchronized fluorescence trace from the large background signal. The time evolution of lower state population is derived from the changes in intensity of the fluorescence excitation line shape resulting from laser-induced fluorescence measurements of the 6s(')[1/2](1)(0)-6p(')[3/2](2) xenon atomic transition at λ = 834.68 nm. Results show that the lower state population oscillates at twice the frequency of the discharge current, 120 Hz. PMID:23206061

  19. Measurements of laser-induced plasma temperature field in deep penetration laser welding

    NASA Astrophysics Data System (ADS)

    Chen, Genyu; Zhang, Mingjun; Zhao, Zhi; Zhang, Yi; Li, Shichun

    2013-02-01

    Laser-induced plasma in deep penetration laser welding is located inside or outside the keyhole, namely, keyhole plasma or plasma plume, respectively. The emergence of laser-induced plasma in laser welding reveals important information of the welding technological process. Generally, electron temperature and electron density are two important characteristic parameters of plasma. In this paper, spectroscopic measurements of electron temperature and electron density of the keyhole plasma and plasma plume in deep penetration laser welding conditions were carried out. To receive spectra from several points separately and simultaneously, an Optical Multi-channel Analyser (OMA) was developed. On the assumption that the plasma was in local thermal equilibrium, the temperature was calculated with the spectral relative intensity method. The spectra collected were processed with Abel inversion method to obtain the temperature fields of keyhole plasma and plasma plume.

  20. Investigations for the correction of presbyopia by fs-laser-induced cuts

    NASA Astrophysics Data System (ADS)

    Ripken, Tammo; Oberheide, Uwe; Heisterkamp, Alexander; Ertmer, Wolfgang; Gerten, Georg; Lubatschowski, Holger

    2004-07-01

    The most probable reason for presbyopia is an age-related loss of the elasticity of the lens. It develops through the whole life, but is first noticeable typically at the age of about 45. From that on it leads within 15 years to a total loss of the accommodation ability. However, both, the ciliary muscle and the lens capsule stay active and elastic, respectively. With respect to this, a possible treatment conception is to increase or regain the elasticity. The possibility to increase elasticity with ps-laser induced cuts inside the lens was already shown by Krueger. We made an improvement in cutting quality while using a fs laser with 5~kHz repetition rate emitting in the near infrared. Different fs-laser-induced μm smooth cuts inside fresh enucleated ex-vivo pig lenses will be presented.

  1. Planar laser-induced fluorescence measurements of high-enthalpy free jet flow with nitric oxide

    NASA Technical Reports Server (NTRS)

    Palmer, Jennifer L.; Mcmillin, Brian K.; Hanson, Ronald K.

    1992-01-01

    Planar laser-induced fluorescence (PLIF) measurements of property fields in a high-enthalpy, supersonic, underexpanded free jet generated in a reflection-type shock tunnel are reported. PLIF images showing velocity and temperature sensitivity are presented. The inferred radial velocity and relative rotational temperature fields are found to be in agreement with those predicted by a numerical simulation of the flowfield using the method of characteristics.

  2. Laser-Induced Fluorescence Analysis of Protein-Based Binding Media

    NASA Astrophysics Data System (ADS)

    Nevin, A.; Cather, S.; Anglos, D.; Fotakis, Costas

    Laser-induced fluorescence of intrinsic fluorophores of organic media found in paintings (casein, animal glue and egg proteins) provides a means of characterising general classes of media depending on the amino acid composition and presence of degradation cross-linkages. Wavelength dependence of spectra is investigated for non-destructive and non-invasive analyses of thin films of protein-based binding media.

  3. Correlation between stimulated scattering processes and laser-induced damage in crystalline quartz

    NASA Technical Reports Server (NTRS)

    Yu, C.; Haw, M. F.; Hsu, H.

    1977-01-01

    The results of a systematic series of experiments to uncover possible correlation between laser-induced stimulated-Brillouin-scattering (SBS) phonons and damage in quartz are presented. Such correlation is confirmed and the various thresholds are established. The anomalous transmission factor under phonon generation is found to decay exponentially as predicted with increasing incident laser power. The LF SBS phonon is also demonstrated to be a sensitive probe for precatastrophic damage.

  4. Radiative lifetimes in B I using ultraviolet and vacuum-ultraviolet laser-induced fluorescence

    NASA Technical Reports Server (NTRS)

    O'Brian, T. R.; Lawler, J. E.

    1992-01-01

    Radiative lifetimes of the eight lowest even parity levels in the doublet system of B I are measured using time-resolved laser-induced fluorescence in the UV and VUV on an atomic beam of boron. The accurate lifetimes provide a base for improved determination of absolute transition probabilities in B I. The techniques described are broadly applicable to measurement of lifetimes of levels with transitions in the visible, UV, and VUV in almost any element.

  5. Laser-induced chemical liquid phase deposition of copper from aqueous solutions without reducing agents

    SciTech Connect

    Kochemirovsky, V A; Tumkin, I I; Logunov, L S; Safonov, S V; Menchikov, Leonid G

    2012-08-31

    Laser-induced chemical liquid phase deposition of copper without a traditional reducing agent has been used for the first time to obtain conductive patterns on a dielectric surface having a reducing ability. It is shown that phenol-formaldehyde binder of the dielectric (glass fibre) can successfully play the role of a reducing agent in this process. The resulting copper sediments have low electrical resistance and good topology. (interaction of laser radiation with matter. laser plasmas)

  6. Development of bio-photonic sensor based on laser-induced fluorescence

    NASA Astrophysics Data System (ADS)

    Kim, Chan Kyu

    Laser-induced fluorescence (LIF) has been shown to be potentially useful for identifying microorganisms in real time. It is a selective and sensitive technique because the excitation is performed at one wavelength while the emission is monitored at longer wavelengths so that background from the excitation source can be eliminated. This specialized optical property of LIF can be applied to development of an optical sensor capable of quickly, non-invasively, and quantitatively probing complex biochemical transformations in microorganisms. Various bio-photonic optical fiber sensors based on laser-induced fluorescence (LIF) spectroscopy were developed as diagnostic tools for microorganisms. In the first phase, the enhancement of the sensitivity and selectivity of the optical sensor system focused on diagnosis of human breast cancer cell lines and Azotobacter vinelandii (an aerobic soil-dwelling organism). Auto-fluorescence spectra from human breast cancer cell lines and Azotobacter vinelandii corresponding to different growth environments were investigated. Then, the study has expanded to include the use of gold nanoparticles for specific DNA detection. The use of gold nanoparticles opens a door into construction of a compact, highly specific, inexpensive and user-friendly optical fiber senor for specific DNA detection. An optical fiber laser-induced fluorescence (LIF) sensor based has been developed to detect single-strand (ss) DNA hybridization at the femtomolar level. Effects of various experimental parameters and configuration were investigated in order to optimize sensor performance and miniaturize sensor size. Key words. Laser induced fluorescence, human breast cancer cell lines, Azotobacter vinelandii, DNA, gold nanoparticles.

  7. Performance Characteristics of Compact Mobile LIFS (Laser-Induced Fluorescence Spectrum) Lidar

    NASA Astrophysics Data System (ADS)

    Tomida, Takayuki; Nishizawa, Naoto; Sakurai, Kosuke; Suganumata, Hikaru; Tsukada, Shodai; Song, Sung-Moo; Park, Ho-Dong; Saito, Yasunori

    2016-06-01

    We developed a compact but versatile laser-induced fluorescence spectrum (LIFS) lidar that has potential use for material or aerosol identification outside experimental rooms. The compactness and mobility of the LIFS lidar means observations can be more freely conducted at any place and any time. Its performance characteristics were validated by threedimensional fluorescence imaging of targets and remote detection of quasi bio/organic aerosols.

  8. Time-resolved digital holographic microscopy of laser-induced forward transfer process

    PubMed Central

    Ma, H.; Venugopalan, V.

    2014-01-01

    We develop a method for time-resolved digital holographic microscopy to obtain time-resolved 3-D deformation measurements of laser induced forward transfer (LIFT) processes. We demonstrate nanometer axial resolution and nanosecond temporal resolution of our method which is suitable for measuring dynamic morphological changes in LIFT target materials. Such measurements provide insight into the early dynamics of the LIFT process and a means to examine the effect of laser and material parameters on LIFT process dynamics. PMID:24748724

  9. Time-resolved digital holographic microscopy of laser-induced forward transfer process.

    PubMed

    Ma, H; Venugopalan, V

    2014-03-01

    We develop a method for time-resolved digital holographic microscopy to obtain time-resolved 3-D deformation measurements of laser induced forward transfer (LIFT) processes. We demonstrate nanometer axial resolution and nanosecond temporal resolution of our method which is suitable for measuring dynamic morphological changes in LIFT target materials. Such measurements provide insight into the early dynamics of the LIFT process and a means to examine the effect of laser and material parameters on LIFT process dynamics. PMID:24748724

  10. Analysis of laser-induced fluorescence spectra of in vitro plant tissue cultures

    NASA Astrophysics Data System (ADS)

    Muñoz-Muñoz, Ana Celia; Gutiérrez-Pulido, Humberto; Rodríguez-Domínguez, José Manuel; Gutiérrez-Mora, Antonia; Rodríguez-Garay, Benjamín; Cervantes-Martínez, Jesús

    2007-04-01

    We demonstrate the effectiveness of laser-induced fluorescence (LIF) for monitoring the development and stress detection of in vitro tissue cultures in a nondestructive and noninvasive way. The changes in LIF spectra caused by the induction of organogenesis, the increase of the F690/F740 ratio as a result of the stress originated in the organogenic explants due to shoot emergence, and the relationship between fluorescence spectra and shoot development were detected by LIF through closed containers of Saintpaulia ionantha.

  11. Correlation among the laser-induced breakdown thresholds in solids, liquids, and gases.

    PubMed

    Bettis, J R

    1992-06-20

    A simple expression is developed that permits a correlation among laser-induced breakdown thresholds in solids, liquids, and gases. It is shown that the breakdown thresholds for the bulk of solid dielectrics, linear liquids, and gases all follow a linear fit to the expression N(2/3)/(n(2) - 1), where N is the atomic number density and n is the refractive index. The gas breakdown threshold versus pressure is compared with the predicted dependence. PMID:20725310

  12. Single cell transfection by laser-induced breakdown of an optically trapped gold nanoparticle

    NASA Astrophysics Data System (ADS)

    Arita, Yoshihiko; Ploschner, Martin; Antkowiak, Maciej; Gunn-Moore, Frank; Dholakia, Kishan

    2014-03-01

    Cell selective introduction of therapeutic agents remains a challenging problem. Cavitation-based therapies including ultrasound-induced sonoporation and laser-induced optoporation have led the way for novel approaches to provide the potential of sterility and cell selectivity compared with viral or biochemical counterparts. Acoustic streaming, shockwaves and liquid microjets associated with the cavitation dynamics are implicated in gene and drug delivery. These approaches, however, often lead to non-uniform and sporadic molecular uptake that lacks refined spatial control and suffers from a significant loss of cell viability. Here we demonstrate spatially controlled cavitation instigated by laser-induced breakdown of an optically trapped single gold nanoparticle. Our unique approach employs optical tweezers to trap a single nanoparticle, which when irradiated by a nanosecond laser pulse is subject to laser-induced breakdown followed by cavitation. Using this method for laser-induced cavitation, we can gain additional degrees of freedom for the cavitation process - the particle material, its size, and its position relative to cells or tissues. We show the energy breakdown threshold of gold nanoparticles of l00nm with a single nanosecond laser pulse at 532 nm is three orders of magnitude lower than that for water, which leads to gentle nanocavitation enabling single cell transfection. We optimize the shear stress to the cells from the expanding bubble to be in the range of 1-10 kPa for transfection by precisely positioning a trapped gold nanoparticle, and thus nanobubble, relative to a cell of interest. The method shows transfection of plasmid-DNA into individual mammalian cells with an efficiency of 75%.

  13. Laser-induced interstitial thermotherapy in treatment of recurrent nodular goiter and thyroid cancer

    NASA Astrophysics Data System (ADS)

    Seliverstov, Oleg V.; Privalov, Valeriy A.; Lappa, Alexander V.; Demidov, A. K.; Faizrakhmanov, Alexey B.; Yarovoy, Nicolay N.

    2001-10-01

    Laser-induced interstitial thermotherapy was performed in 29 patients with recurrent nodular and multinodular goiter, and in 3 patients with recurrent inoperable thyroid cancer. There were used transcutaneous puncture under ultrasonic control, diode lasers with wavelength 805, 980, and 1060 nm, quartz monofibers, special computerized thermometer with microthermocouples. Disappearance or significant reduction of nodes in the most goiter cases, and regress of tumor in the cancer cases were marked during observation period (0.5 - 2.5 years).

  14. Multi-target PCR analysis by capillary electrophoresis and laser-induced fluorescence

    NASA Astrophysics Data System (ADS)

    Lu, Wei; Han, Dai-Shu; Yuan, Ju; Andrieu, Jean-Marie

    1994-03-01

    Quantitative analysis of polymerase chain reaction (PCR) amplified HIV-1 DNA or cDNA fragments is attained using an automated system that combines capillary-gel electrophoresis (CGE) for high-efficiency separation and laser-induced fluorescence (LIF) for high-sensitivity detection. This system enables the detection of PCR-amplified multiple target DNA or cDNA in the same tube by a single injection with high precision.

  15. Laser-induced two-photon blackbody radiation in the vacuum ultraviolet

    NASA Technical Reports Server (NTRS)

    Zych, L. J.; Young, J. F.; Harris, S. E.; Lukasik, J.

    1978-01-01

    Experimental measurements of a new type of vacuum-ultraviolet radiation source are reported. It is shown that the maximum source brightness, within its narrow linewidth, is that of a blackbody at the temperature of a metastable storage level. The laser-induced emission at 569 A from a He glow discharge corresponded to a metastable temperature of 22,700 K and was over 100 times brighter than the 584-A He resonance line.

  16. Identification of British one pound counterfeit coins using laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Appleby, Andrew; Thevar, Thangavel

    2016-04-01

    The use of laser-induced breakdown spectroscopy (LIBS) as a low-cost, nondestructive method for detecting counterfeit coins was examined. A pulsed laser was used to evaporate a minute amount of coin surface, and the emanating plasma was interrogated with an entry-level spectrometer. The spectra produced showed evidence of lead content in six of the eight counterfeits examined. Thus, LIBS could offer a viable low-cost technique for identifying a significant number of fake coins.

  17. Simultaneous laser-induced fluorescence and Raman imaging inside a hydrogen engine.

    PubMed

    Engel, Sascha Ronald; Koch, Peter; Braeuer, Andreas; Leipertz, Alfred

    2009-12-10

    We report on the simultaneous and two-dimensional measurement of laser-induced fluorescence (LIF) and Raman scattering (Ramanography) applied inside a hydrogen internal combustion (IC) engine. Two different LIF tracer molecules, triethylamine (TEA) and trimethylamine (TMA), were used for the LIF experiments. The LIF and Raman results were found to be in very good agreement. The simultaneous application of Ramanography and LIF imaging indicated that TMA is the more suitable LIF tracer molecule, compared to TEA. PMID:20011004

  18. Detection of human colonic adenoma by laser-induced autofluorescence integrated with diffuse reflectance spectroscopy

    NASA Astrophysics Data System (ADS)

    Tang, Guilin; Lu, Haibao; Zhang, Yangde; Yan, Shuhua; Chen, Zhifeng

    2000-10-01

    A combined in vivo measurement system integrating laser- induced autofluorescence (LIAF) and diffuse reflectance spectroscopy (DRS) measurement was developed and investigated for detecting colonic adenoma. The system could work with regular endoscopy examination. A three- layer backpropagating neural network (BNN) was built to differentiate the two tissue classes. The preliminary results gave the mean predictive accuracy, sensitivity and specificity better than either of the two methods used alone.

  19. A time-gating scintillation detector for the measurement of laser-induced fast neutrons

    SciTech Connect

    Lee, Sungman; Park, Sangsoon; Yea, Kwon-hae; Cha, Hyungki

    2009-06-15

    A time-gating scintillation detector, in which a fast high voltage switch is used for gating a channel photomultiplier, was developed for a measurement of laser-induced fast neutrons. The x rays generated from the intense femtosecond laser and the solid target interactions were suppressed selectively and a time-of-flight signal of a laser-generated fast neutron was measured effectively. The detector was used successfully to measure the neutron yield of a femtosecond, deuterated, polystyrene plasma.

  20. A time-gating scintillation detector for the measurement of laser-induced fast neutrons.

    PubMed

    Lee, Sungman; Park, Sangsoon; Yea, Kwon-hae; Cha, Hyungki

    2009-06-01

    A time-gating scintillation detector, in which a fast high voltage switch is used for gating a channel photomultiplier, was developed for a measurement of laser-induced fast neutrons. The x rays generated from the intense femtosecond laser and the solid target interactions were suppressed selectively and a time-of-flight signal of a laser-generated fast neutron was measured effectively. The detector was used successfully to measure the neutron yield of a femtosecond, deuterated, polystyrene plasma. PMID:19566199