Science.gov

Sample records for light oil production

  1. Implications of Increasing Light Tight Oil Production for U.S. Refining

    EIA Publications

    2015-01-01

    EIA retained Turner, Mason & Company to provide analysis of the implications of increasing domestic light tight oil production for U.S. refining, focusing on regional crude supply/demand balances, refinery crude slates, operations, capital investment, product yields, crude oil exports/imports, petroleum product exports, infrastructure constraints and expansions, and crude oil price relationships.

  2. Production of light oil by injection of hot inert gas

    NASA Astrophysics Data System (ADS)

    Ruidas, Bidhan C.; Ganguly, Somenath

    2016-05-01

    Hot inert gas, when injected into an oil reservoir is capable of generating a vaporization-condensation drive and as a consequence, a preferential movement of the lighter components to the production well. This form of displacement is an important unit mechanism in hot flue-gas injection, or in thermal recovery from a watered-out oil reservoir. This article presents the movement of heat front vis-à-vis the changes in the saturation profile, and the gas-phase composition. The plateau in the temperature profile due to the exchange of latent heat, and the formation of water bank at the downstream are elaborated. The broadening of the vaporization-condensation zone with continued progression is discussed. The effect of inert gas temperature on the cumulative production of oil is reviewed. The results provide insight to the vaporization-condensation drive as a stand-alone mechanism. The paper underscores the relative importance of this mechanism, when operated in tandem with other processes in improved oil recovery and CO2 sequestration.

  3. Production of alkyl-aromatics from light oxygenates over zeolite catalysts for bio-oil refining

    NASA Astrophysics Data System (ADS)

    Hoang, Trung Q.

    in aromatic yield. Further improvement of aromatization and catalyst lifetime was also found with ZnHZSM-5 wherein the Zn evidently modifies the acidity. These model compound results show that the optimized use of zeolites for production of alkyl aromatics from light oxygenates at mild conditions may be effective for bio-oil refining.

  4. Oil Production

    Energy Science and Technology Software Center (ESTSC)

    1989-07-01

    A horizontal and slanted well model was developed and incorporated into BOAST, a black oil simulator, to predict the potential production rates for such wells. The HORIZONTAL/SLANTED WELL MODEL can be used to calculate the productivity index, based on the length and location of the wellbore within the block, for each reservoir grid block penetrated by the horizontal/slanted wellbore. The well model can be run under either pressure or rate constraints in which wellbore pressuresmore » can be calculated as an option of infinite-conductivity. The model can simulate the performance of multiple horizontal/slanted wells in any geometric combination within reservoirs.« less

  5. Water issues associated with heavy oil production.

    SciTech Connect

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  6. 40 CFR 61.133 - Standard: Light-oil sumps.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... detectable emissions, using Method 21 (40 CFR part 60, appendix A) and the procedures specified in § 61.245(c... 40 Protection of Environment 9 2012-07-01 2012-07-01 false Standard: Light-oil sumps. 61.133... Emissions from Coke By-Product Recovery Plants § 61.133 Standard: Light-oil sumps. (a) Each owner...

  7. 40 CFR 61.133 - Standard: Light-oil sumps.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... detectable emissions, using Method 21 (40 CFR part 60, appendix A) and the procedures specified in § 61.245(c... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Standard: Light-oil sumps. 61.133... Emissions from Coke By-Product Recovery Plants § 61.133 Standard: Light-oil sumps. (a) Each owner...

  8. 40 CFR 61.133 - Standard: Light-oil sumps.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... detectable emissions, using Method 21 (40 CFR part 60, appendix A) and the procedures specified in § 61.245(c... 40 Protection of Environment 9 2013-07-01 2013-07-01 false Standard: Light-oil sumps. 61.133... Emissions from Coke By-Product Recovery Plants § 61.133 Standard: Light-oil sumps. (a) Each owner...

  9. Light metal production

    DOEpatents

    Fan, Qinbai

    2016-04-19

    An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

  10. Effect of wettability on light oil steamflooding

    SciTech Connect

    Olsen, D.K.

    1991-12-01

    This report summarizes NIPER's research on four interrelated topics for Light Oil Steamflooding. Four interrelated topics are described: The methodology for measuring capillary pressure and wettability at elevated temperature, the use of silylating agents to convert water-wet Berea sandstones or unconsolidated quartz sands to oil-wetted surfaces, the evaluation of the thermal hydrolytic stability of these oil-wet surfaces for possible use in laboratory studies using steam and hot water to recover oil, and the effect of porous media of different wettabilities on oil recovery where the porous media is first waterflooded and then steamflooded.

  11. Effect of wettability on light oil steamflooding

    SciTech Connect

    Olsen, D.K.

    1991-12-01

    This report summarizes NIPER`s research on four interrelated topics for Light Oil Steamflooding. Four interrelated topics are described: The methodology for measuring capillary pressure and wettability at elevated temperature, the use of silylating agents to convert water-wet Berea sandstones or unconsolidated quartz sands to oil-wetted surfaces, the evaluation of the thermal hydrolytic stability of these oil-wet surfaces for possible use in laboratory studies using steam and hot water to recover oil, and the effect of porous media of different wettabilities on oil recovery where the porous media is first waterflooded and then steamflooded.

  12. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  13. Light cone matrix product

    SciTech Connect

    Hastings, Matthew B

    2009-01-01

    We show how to combine the light-cone and matrix product algorithms to simulate quantum systems far from equilibrium for long times. For the case of the XXZ spin chain at {Delta} = 0.5, we simulate to a time of {approx} 22.5. While part of the long simulation time is due to the use of the light-cone method, we also describe a modification of the infinite time-evolving bond decimation algorithm with improved numerical stability, and we describe how to incorporate symmetry into this algorithm. While statistical sampling error means that we are not yet able to make a definite statement, the behavior of the simulation at long times indicates the appearance of either 'revivals' in the order parameter as predicted by Hastings and Levitov (e-print arXiv:0806.4283) or of a distinct shoulder in the decay of the order parameter.

  14. Products from vegetable oils

    SciTech Connect

    Bagby, M.O.

    1995-12-01

    Vegetable oils serve various industrial applications such as plasticizers, emulsifiers, surfactants, plastics and resins. Research and development approaches may take advantage of natural properties of the oils. More often it is advantageous to modify those properties for specific applications. One example is the preparation of ink vehicles using vegetable oils in the absence of petroleum. They are cost competitive with petroleum-based inks with similar quality factors. Vegetable oils have potential as renewable sources of fuels for the diesel engine. However, several characteristics can restrict their use. These include poor cold-engine startup, misfire and for selected fuels, high pour point and cloud point temperatures. Other characteristics include incomplete combustion causing carbon buildup, lube oil dilution and degradation, and elevated NO{sub x} emissions. Precombustion and fuel quality data are presented as a tool for understanding and solving these operational and durability problems.

  15. 40 CFR 61.133 - Standard: Light-oil sumps.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... detectable emissions, using Method 21 (40 CFR part 60, appendix A) and the procedures specified in § 61.245(c... Emissions from Coke By-Product Recovery Plants § 61.133 Standard: Light-oil sumps. (a) Each owner...

  16. Oil prices in a new light

    SciTech Connect

    Fesharaki, F. )

    1994-05-01

    For a clear picture of how oil prices develop, the author steps away from the price levels to which the world is accustomed, and evaluates scientifically. What makes prices jump from one notch to another The move results from a political or economic shock or the perception of a particular position by the futures market and the media. The shock could range from a war or an assassination to a promise of cooperation among OPEC members (when believed by the market) or to speculation about another failure at an OPEC meeting. In the oil market, only a couple of factual figures can provide a floor to the price of oil. The cost of production of oil in the Gulf is around $2 to $3/bbl, and the cost of production of oil (capital and operating costs) in key non-OPEC areas is well under $10/bbl. With some adjustments for transport and quality, a price range of $13/bbl to $16/bbl would correspond to a reasonable sustainable floor price. The reason for prices above the floor price has been a continuous fear of oil supply interruptions. That fear kept prices above the floor price for many years. The fear factor has now almost fully disappeared. The market has gone through the drama of the Iranian Revolution, the Iran-Iraq war, the tanker war, the invasion of Kuwait, and the expulsions of the Iraqis. And still the oil flowed -- all the time. It has become abundantly clear that fears above the oil market were unjustified. Everyone needs to export oil, and oil will flow under the worst circumstances. The demise of the fear factor means that oil prices tend toward the floor price for a prolonged period.

  17. 2. Oil house, fog signal house and light tower, view ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Oil house, fog signal house and light tower, view southwest, east and north sides - Great Duck Island Light Station, At southern tip of Great Duck Island southeast of Bass Harbor & northeast of Frenchboro, Frenchboro, Hancock County, ME

  18. 5. Shed, keeper's house, boathouse, light tower and oil house, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. Shed, keeper's house, boathouse, light tower and oil house, view southeast, northwest and southwest sides - Goat Island Light Station, Goat Island, next to entrance to Cape Porpoise Harbor, just south of Trott Island, Cape Porpoise, York County, ME

  19. 1. Light tower, oil house close by, boathouse and keeper's ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Light tower, oil house close by, boathouse and keeper's house, view northwest, south or southeast sides - Goat Island Light Station, Goat Island, next to entrance to Cape Porpoise Harbor, just south of Trott Island, Cape Porpoise, York County, ME

  20. 4. Storage building, outhouse, oil house, keeper's house and light ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. Storage building, outhouse, oil house, keeper's house and light tower, view southwest, northeast sides (southeast and northeast sides of keeper's house) - Petit Manan Light Station, 2.5 miles south of Petit Manan Point, Milbridge, Washington County, ME

  1. Catalytic conversion of olefinic fischer tropsch light oil to heavier hydrocarbons

    SciTech Connect

    Owen, H.; Tabak, S. A.; Wright, B. S.

    1985-05-28

    A process for converting synthol light oil product of Fischer-Tropsch synthesis to heavy distillate comprising the steps of contacting the light oil at elevated temperature and pressure with acid zeolite conversion catalyst to oligomerize olefins and convert oxygenated hydrocarbons contained in the light oil thereby providing an effluent containing light heavy distillate range hydrocarbon, hydrocarbon vapor and byproduct water; flashing and separating the effluent to recover a heavy distillate-rich liquid phase and a light hydrocarbon-rich vapor phase containing byproduct water; condensing the vapor phase to provide a liquid hydrocarbon recycle stream; removing byproduct water from the recycle stream; combining the light oil with the pressurized recycle stream as heat sink to prevent excessive reaction temperature during catalytic conversion.

  2. 2. Light tower and oil house, view west, southeast and ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Light tower and oil house, view west, southeast and northeast sides of tower and south side of oil house - Goat Island Light Station, Goat Island, next to entrance to Cape Porpoise Harbor, just south of Trott Island, Cape Porpoise, York County, ME

  3. 2. Keeper's house, light tower and oil house, view north, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Keeper's house, light tower and oil house, view north, south and east sides of keeper's house, south side of tower and oil house - Owl's Head Light Station, Off State Highway 73 just east of Rockland on Owl's Head Bay, Owls Head, Knox County, ME

  4. HP-41C helps predict oil production

    SciTech Connect

    Bixler, B.

    1982-04-01

    A new program for the HP-41C hand-held programable computer predicts yearly oil production and water-oil ratios (WOR) given the following: (1) barrels original oil-in-place; (2) barrels cumulative oil production at start of the flood or at the beginning of the study if the flood is in progress; (3) percent of original oil-in-place ultimately recovered; (4) WOR at the beginning of the study; (5) WOR at abandonment; and (6) barrels total fluid produced per day. This method assumes that the plot of log WOR vs. CUM oil (cumulative oil to the end of the given year) is linear and that the combined production (withdrawal) rate of oil and water is constant for the life of the flood. Details of the program are given, along with a program listing, an example problem, and a bar code listing.

  5. Problems Associated with Declining National Oil Production

    NASA Astrophysics Data System (ADS)

    Jackson, J. S.

    2009-12-01

    Forecasts of peak oil production have focussed on the global impacts of declining production. Meanwhile, national oil production has declined in 20 countries, leading to local problems that receive little comment outside of the effected regions. Two problems deserve wider recognition: declining state revenues and fuel substitution. Most oil producing countries with large reserves adopted licensing practices that provide significant revenues to the host governments such that oil revenues generate from 40 to 80 percent of total government funds. Typically these governments allocate a fraction of this revenue to their state oil companies, utilizing the remainder for other activities. As oil revenues decline with falling production, host governments face a dilemma: either to increase state oil company budgets in order to stem the decline, or to starve the state oil company while maintaining other government programs. The declining oil revenues in these states can significantly reduce the government's ability to address important national issues. Mexico, Indonesia, and Yemen illustrate this situation in its early phases. Fuel substitution occurs whenever one fuel proves less expensive than another. The substitution of coal for wood in the eighteenth century and oil for coal in the twentieth century are classic examples. China and India appear to be at peak oil production, while their economies generate increasing demand for energy. Both countries are substituting coal and natural gas for oil with attendant environmental impacts. Coal-to-liquids projects are proposed in in both China, which will require significant water resources if they are executed. These examples suggest that forecasting the impact of peak oil at a regional level requires more than an assessment of proven-probable-possible reserves and a forecast of supply-demand scenarios. A range of government responses to declining oil income scenarios must also be considered, together with scenarios describing

  6. Selective conversion of bio-oil to light olefins: controlling catalytic cracking for maximum olefins.

    PubMed

    Gong, Feiyan; Yang, Zhi; Hong, Chenggui; Huang, Weiwei; Ning, Shen; Zhang, Zhaoxia; Xu, Yong; Li, Quanxin

    2011-10-01

    Light olefins are the basic building blocks for the petrochemical industry. In this work, selective production of light olefins from catalytic cracking of bio-oil was performed by using the La/HZSM-5 catalyst. With a nearly complete conversion of bio-oil, the maximum yield reached 0.28±0.02 kg olefins/(kg bio-oil), which was close to that from methanol. Addition of La into zeolite efficiently changed the total acid amount of HZSM-5, especially the acid distribution among the strong, medium and weak acid sites. A moderate increase of the number of the medium acid sites effectively enhanced the olefins selectivity and improved the catalyst stability. The comparison between the catalytic cracking and pyrolysis of bio-oil was studied. The mechanism of the conversion of bio-oil to light olefins was also discussed. PMID:21807503

  7. Enhanced oil spill detection sensors in low-light environments

    NASA Astrophysics Data System (ADS)

    Allik, Toomas H.; Ramboyong, Len; Roberts, Mark; Walters, Mark; Soyka, Thomas J.; Dixon, Roberta; Cho, Jay

    2016-05-01

    Although advances have been made in oil spill remote detection, many electro-optic sensors do not provide real-time images, do not work well under degraded visual environments, nor provide a measure of extreme oil thickness in marine environments. A joint program now exists between BSEE and NVESD that addresses these capability gaps in remote sensing of oil spills. Laboratory experiments, calibration techniques, and field tests were performed at Fort Belvoir, Virginia; Santa Barbara, California; and the Ohmsett Test Facility in Leonardo, New Jersey. Weathered crude oils were studied spectroscopically and characterized with LWIR, and low-light-level visible/NIR, and SWIR cameras. We designed and fabricated an oil emulsion thickness calibration cell for spectroscopic analysis and ground truth, field measurements. Digital night vision cameras provided real-time, wide-dynamic-range imagery, and were able to detect and recognize oil from full sun to partial moon light. The LWIR camera provided quantitative oil analysis (identification) for >1 mm thick crude oils both day and night. Two filtered, co-registered, SWIR cameras were used to determine whether oil thickness could be measured in real time. Spectroscopic results revealed that oil emulsions vary with location and weathered state and some oils (e.g., ANS and Santa Barbara seeps) do not show the spectral rich features from archived Deep Water Horizon hyperspectral data. Multi-sensor imagery collected during the 2015 USCG Airborne Oil Spill Remote Sensing and Reporting Exercise and the design of a compact, multiband imager are discussed.

  8. 1. Oil house, keeper's house, Southern Light Tower and Northern ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Oil house, keeper's house, Southern Light Tower and Northern Light Tower, view northwest, south and east sides - Kennebec River Light Station, South side of Doubling Point Road, off State Highway 127, 1.8 miles south of U.S. Route 1, Arrowsic, Sagadahoc County, ME

  9. Soviet oil production begins to falter

    SciTech Connect

    Fueg, J.C

    1989-08-01

    Soviet industry managers are warning that a new oil production slump may be on the way, especially in the crucial West Siberian industry. The USSR's global energy balance will depend on accelerating natural gas development. In the rest of Eastern Europe, Albania, Poland, Romania and Yugoslavia all showed significant declines in oil production.

  10. Improved Light Utilization in Camelina: Center for Enhanced Camelina Oil (CECO)

    SciTech Connect

    2012-01-01

    PETRO Project: The Danforth Center will optimize light utilization in Camelina, a drought-resistant, cold-tolerant oilseed crop. The team is modifying how Camelina collects sunlight, engineering its topmost leaves to be lighter in color so sunlight can more easily reflect onto lower parts of the plant. A more uniform distribution of light would improve the efficiency of photosynthesis. Combined with other strategies to produce more oil in the seed, Camelina would yield more oil per plant. The team is also working to allow Camelina to absorb carbon dioxide (CO2) more efficiently, providing more carbon input for oil production. The goal is to improve light utilization and oil production to the point where Camelina produces enough fuel precursors per acre to compete with other fuels.

  11. Upgrading and Refining of Crude Oils and Petroleum Products by Ionizing Irradiation.

    PubMed

    Zaikin, Yuriy A; Zaikina, Raissa F

    2016-06-01

    A general trend in the oil industry is a decrease in the proven reserves of light crude oils so that any increase in future oil exploration is associated with high-viscous sulfuric oils and bitumen. Although the world reserves of heavy oil are much greater than those of sweet light oils, their exploration at present is less than 12 % of the total oil recovery. One of the main constraints is very high expenses for the existing technologies of heavy oil recovery, upgrading, transportation, and refining. Heavy oil processing by conventional methods is difficult and requires high power inputs and capital investments. Effective and economic processing of high viscous oil and oil residues needs not only improvements of the existing methods, such as thermal, catalytic and hydro-cracking, but the development of new technological approaches for upgrading and refining of any type of problem oil feedstock. One of the perspective approaches to this problem is the application of ionizing irradiation for high-viscous oil processing. Radiation methods for upgrading and refining high-viscous crude oils and petroleum products in a wide temperature range, oil desulfurization, radiation technology for refining used oil products, and a perspective method for gasoline radiation isomerization are discussed in this paper. The advantages of radiation technology are simple configuration of radiation facilities, low capital and operational costs, processing at lowered temperatures and nearly atmospheric pressure without the use of any catalysts, high production rates, relatively low energy consumption, and flexibility to the type of oil feedstock. PMID:27573274

  12. 17 CFR 229.1204 - (Item 1204) Oil and gas production, production prices and production costs.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... production, by final product sold, of oil, gas, and other products. Disclosure shall be made by geographical... conversion to synthetic oil or gas, the product's production, transfer prices, and production costs should be... expressed in common units of production with oil, gas, and other products converted to a common unit...

  13. 17 CFR 229.1204 - (Item 1204) Oil and gas production, production prices and production costs.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... production, by final product sold, of oil, gas, and other products. Disclosure shall be made by geographical... conversion to synthetic oil or gas, the product's production, transfer prices, and production costs should be... expressed in common units of production with oil, gas, and other products converted to a common unit...

  14. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    SciTech Connect

    Anthony R. Kovscek

    2002-07-01

    This technical progress report describes work performed from April 1 through June 30, 2002, for the project ''Heavy and Thermal Oil Recovery Production Mechanisms.'' We investigate a broad spectrum of topics related to thermal and heavy-oil recovery. Significant results were obtained in the areas of multiphase flow and rock properties, hot-fluid injection, improved primary heavy oil recovery, and reservoir definition. The research tools and techniques used are varied and span from pore-level imaging of multiphase fluid flow to definition of reservoir-scale features through streamline-based history-matching techniques. Briefly, experiments were conducted to image at the pore level matrix-to-fracture production of oil from a fractured porous medium. This project is ongoing. A simulation studied was completed in the area of recovery processes during steam injection into fractured porous media. We continued to study experimentally heavy-oil production mechanisms from relatively low permeability rocks under conditions of high pressure and high temperature. High temperature significantly increased oil recovery rate and decreased residual oil saturation. Also in the area of imaging production processes in laboratory-scale cores, we use CT to study the process of gas-phase formation during solution gas drive in viscous oils. Results from recent experiments are reported here. Finally, a project was completed that uses the producing water-oil ratio to define reservoir heterogeneity and integrate production history into a reservoir model using streamline properties.

  15. Transgenic oil palm: production and projection.

    PubMed

    Parveez, G K; Masri, M M; Zainal, A; Majid, N A; Yunus, A M; Fadilah, H H; Rasid, O; Cheah, S C

    2000-12-01

    Oil palm is an important economic crop for Malaysia. Genetic engineering could be applied to produce transgenic oil palms with high value-added fatty acids and novel products to ensure the sustainability of the palm oil industry. Establishment of a reliable transformation and regeneration system is essential for genetic engineering. Biolistic was initially chosen as the method for oil palm transformation as it has been the most successful method for monocotyledons to date. Optimization of physical and biological parameters, including testing of promoters and selective agents, was carried out as a prerequisite for stable transformation. This has resulted in the successful transfer of reporter genes into oil palm and the regeneration of transgenic oil palm, thus making it possible to improve the oil palm through genetic engineering. Besides application of the Biolistics method, studies on transformation mediated by Agrobacterium and utilization of the green fluorescent protein gene as a selectable marker gene have been initiated. Upon the development of a reliable transformation system, a number of useful targets are being projected for oil palm improvement. Among these targets are high-oleate and high-stearate oils, and the production of industrial feedstock such as biodegradable plastics. The efforts in oil palm genetic engineering are thus not targeted as commodity palm oil. Due to the long life cycle of the palm and the time taken to regenerate plants in tissue culture, it is envisaged that commercial planting of transgenic palms will not occur any earlier than the year 2020. PMID:11171275

  16. Light-cone matrix product

    SciTech Connect

    Hastings, M. B.

    2009-09-15

    We show how to combine the light-cone and matrix product algorithms to simulate quantum systems far from equilibrium for long times. For the case of the XXZ spin chain at {delta}=0.5, we simulate to a time of {approx_equal}22.5. While part of the long simulation time is due to the use of the light-cone method, we also describe a modification of the infinite time-evolving bond decimation algorithm with improved numerical stability, and we describe how to incorporate symmetry into this algorithm. While statistical sampling error means that we are not yet able to make a definite statement, the behavior of the simulation at long times indicates the appearance of either 'revivals' in the order parameter as predicted by Hastings and Levitov (e-print arXiv:0806.4283) or of a distinct shoulder in the decay of the order parameter.

  17. Oil Production, The Price Crash and Uncertainty in Climate Change

    NASA Astrophysics Data System (ADS)

    Murray, J. W.

    2015-12-01

    World oil production increased to about 74 million barrels per day by January 2005, and was fairly constant until 2011 when it started to increase to 77.8 mb/d in 2014. This spectacular increase of 4 mb/d was almost entirely due to a sharp increase in production in the US from shale formations, called light tight oil (LTO). World oil production minus this increase in US LTO Production has been flat since 2005 at about 74 mb/d. When US production starts to decline, world oil production likely will as well. That surge is forecast to end soon because LTO is expensive to produce, the first year decline rates are extremely high requiring many new wells each year to maintain or increase production and the most productive locations have already been drilled. It is unprofitable for the Exploration and Production (E&P) companies. Full-year free cash flow has been negative for most tight oil E&P companies since 2009. The total negative cash flow for the 19 largest E&P companies totaled 10.5B in 2014. The surge in US LTO production created an imbalance in global supply and demand and resulted in a 50% decrease in the price of oil. The tight-oil producers who were are financially marginal at an oil price greater than 90 per barrel are even more so at the lower price. As a result the surge in US production of LTO is declining, making it unlikely that world oil production will exceed the present value of about 28 Gb/yr (equivalent to 75 mb/d) (175 EJ/yr). Many of the SRES (IPCC Special Report on Emission Scenarios) and RCP (IPCC Representative Concentration Pathways) projections (especially RCP 8.5 and 6) require CO2 emissions due to oil consumption in the range of 32 Gb/yr to 57 Gb/yr (200 to 350 EJ/yr). The higher values would require a doubling of world oil production. It is highly uncertain whether the higher CO2 scenarios will be reached. This is an element of uncertainty missing from most considerations of future climate change.

  18. Opportunities to improve oil productivity in unstructured deltaic reservoirs

    SciTech Connect

    Not Available

    1991-01-01

    This report contains presentations presented at a technical symposium on oil production. Chapter 1 contains summaries of the presentations given at the Department of Energy (DOE)-sponsored symposium and key points of the discussions that followed. Chapter 2 characterizes the light oil resource from fluvial-dominated deltaic reservoirs in the Tertiary Oil Recovery Information System (TORIS). An analysis of enhanced oil recovery (EOR) and advanced secondary recovery (ASR) potential for fluvial-dominated deltaic reservoirs based on recovery performance and economic modeling as well as the potential resource loss due to well abandonments is presented. Chapter 3 provides a summary of the general reservoir characteristics and properties within deltaic deposits. It is not exhaustive treatise, rather it is intended to provide some basic information about geologic, reservoir, and production characteristics of deltaic reservoirs, and the resulting recovery problems.

  19. 17 CFR 229.1204 - (Item 1204) Oil and gas production, production prices and production costs.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... production, by final product sold, of oil, gas, and other products. Disclosure shall be made by geographical... conversion to synthetic oil or gas, the product's production, transfer prices, and production costs should be... (Extractive Activities—Oil and Gas Topic). Instruction 5 to Item 1204: The average production cost,...

  20. 17 CFR 229.1204 - (Item 1204) Oil and gas production, production prices and production costs.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... production, by final product sold, of oil, gas, and other products. Disclosure shall be made by geographical... conversion to synthetic oil or gas, the product's production, transfer prices, and production costs should be... (Extractive Activities—Oil and Gas Topic). Instruction 5 to Item 1204: The average production cost,...

  1. New production techniques for alberta oil sands.

    PubMed

    Carrigy, M A

    1986-12-19

    Low world oil prices represent a serious threat to expanded commercial development of the Canadian oil sands in the near term, as they do to all of the higher cost alternatives to crude oil such as oil shales and coal liquefaction. Nonetheless, research and field testing of new technology for production of oil from oil sands are being pursued by industry and government in Alberta. New production technology is being developed in Canada to produce synthetic oil from the vast resources of bitumen trapped in the oil sands and bituminous carbonates of northern Alberta. This technology includes improved methods of mining, extraction, and upgrading of bitumen from near-surface deposits as well as new drilling and production techniques for thermal production of bitumen from the more deeply buried reservoirs. Of particular interest are the cluster drilling methods designed to reduce surface disturbance and the techniques for horizontal drilling of wells from underground tunnels to increase the contact of injection fluids with the reservoir. PMID:17816505

  2. Oil industry waste: a potential feedstock for biodiesel production.

    PubMed

    Abbas, Javeria; Hussain, Sabir; Iqbal, Muhammad Javid; Nadeem, Habibullah; Qasim, Muhammad; Hina, Saadia; Hafeez, Farhan

    2016-08-01

    The worldwide rising energy demands and the concerns about the sustainability of fossil fuels have led to the search for some low-cost renewable fuels. In this scenario, the production of biodiesel from various vegetable and animal sources has attracted worldwide attention. The present study was conducted to evaluate the production of biodiesel from the oil industry waste following base-catalysed transesterification. The transesterification reaction gave a yield of 83.7% by 6:1 methanol/oil molar ratio, at 60°C over 80 min of reaction time in the presence of NaOH. The gas chromatographic analysis of the product showed the presence of 16 fatty acid methyl esters with linoleic and oleic acid as principal components representing about 31% and 20.7% of the total methyl esters, respectively. The fourier transform infrared spectroscopy spectrum of oil industry waste and transesterified product further confirmed the formation of methyl esters. Furthermore, the fuel properties of oil industry waste methyl esters, such as kinematic viscosity, cetane number, cloud point, pour point, flash point, acid value, sulphur content, cold filter plugging point, copper strip corrosion, density, oxidative stability, higher heating values, ash content, water content, methanol content and total glycerol content, were determined and discussed in the light of ASTM D6751 and EN 14214 biodiesel standards. Overall, this study presents the production of biodiesel from the oil industry waste as an approach of recycling this waste into value-added products. PMID:26776601

  3. Spectral signatures of fluorescence and light absorption to identify crude oils found in the marine environment

    NASA Astrophysics Data System (ADS)

    Baszanowska, E.; Otremba, Z.

    2014-08-01

    To protect the natural marine ecosystem, it is necessary to continuously enhance knowledge of environmental contamination, including oil pollution. Therefore, to properly track the qualitative and quantitative changes in the natural components of seawater, a description of the essential spectral features describing petroleum products is necessary. This study characterises two optically-different types of crude oils (Petrobaltic and Romashkino) - substances belonging to multi-fluorophoric systems. To obtain the spectral features of crude oils, the excitation-emission spectroscopy technique was applied. The fluorescence and light absorption properties for various concentrations of oils at a stabilised temperature are described. Both excitation-emission spectra (EEMs) and absorption spectra of crude oils are discussed. Based on the EEM spectra, both excitation end emission peaks for the wavelengthindependent fluorescence maximum (Exmax/ Emmax) - characteristic points for each type of oil - were identified and compared with the literature data concerning typical marine chemical structures.

  4. Studies on water-in-oil products from crude oils and petroleum products.

    PubMed

    Fingas, Merv; Fieldhouse, Ben

    2012-02-01

    Water-in-oil mixtures such as emulsions, often form and complicate oil spill countermeasures. The formation of water-in-oil mixtures was studied using more than 300 crude oils and petroleum products. Water-in-oil types were characterized by resolution of water at 1 and 7 days, and some after 1 year. Rheology measurements were carried out at the same intervals. The objective of this laboratory study was to characterize the formed water-in-oil products and relate these properties to starting oil properties. Analysis of the starting oil properties of these water-in-oil types shows that the existence of each type relates to the starting oil viscosity and its asphaltene and resin contents. This confirms that water-in-oil emulsification is a result of physical stabilization by oil viscosity and chemical stabilization by asphaltenes and resins. This stabilization is illustrated using simple graphical techniques. Four water-in-oil types exist: stable, unstable, meso-stable and entrained. Each of these has distinct physical properties. PMID:22183525

  5. Products Derived From Lesquerella Oil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Lesquerella fendleri is a member of the Brassicaceae (mustard) family. Lesquerella is a winter annual seed oil crop native to the desert southwestern United States, and is currently undergoing an intensive research effort for its successful introduction into agriculture. Lesquerella produces a...

  6. Biotechnology for Castor oil Production

    Technology Transfer Automated Retrieval System (TEKTRAN)

    We conducted a series of seed development studies in castor and L. fendleri, including seed morphogenesis, oil and storage protein accumulation and lipid gene expression. In castor, the entire course of seed development can be divided into eight stages and each stage can be distinguished by seed co...

  7. Kuwait pressing toward preinvasion oil production capacity

    SciTech Connect

    Tippee, B.

    1993-03-15

    Oil field reconstruction is shifting focus in Kuwait as the country races toward prewar production capacity of 2 million b/d. Oil flow last month reached 1.7 million b/d, thanks largely to a massive workover program that has accomplished about as much as it can. By midyear, most of the 19 rigs in Kuwait will be drilling rather than working over wells vandalized by retreating Iraqi troops in February 1991. Seventeen gathering centers are at work, with capacities totaling 2.4 million b/d, according to state-owned Kuwait Oil Co. (KOC). This article describes current work, the production infrastructure, facilities strategy, oil recovery, well repairs, a horizontal pilot project, the drilling program, the constant reminders of war, and heightened tensions.

  8. Alcorn wells bolster Philippines oil production

    SciTech Connect

    Not Available

    1992-09-21

    This paper reports that Alcorn International Inc., Houston, is producing about 16,500 b/d of oil from West Linapacan A field in the South China Sea off the Philippines. The field's current production alone is more than fivefold the Philippines' total average oil flow of 3,000 b/d in 1991. It's part of a string of oil and gas strikes off Palawan Island that has made the region one of the hottest exploration/development plays in the Asia-Pacific theater.

  9. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    SciTech Connect

    Anthony R. Kovscek

    2003-04-01

    This technical progress report describes work performed from January 1 through March 31, 2003 for the project ''Heavy and Thermal Oil Recovery Production Mechanisms,'' DE-FC26-00BC15311. In this project, a broad spectrum of research is undertaken related to thermal and heavy-oil recovery. The research tools and techniques span from pore-level imaging of multiphase fluid flow to definition of reservoir-scale features through streamline-based history matching techniques. During this period, previous analysis of experimental data regarding multidimensional imbibition to obtain shape factors appropriate for dual-porosity simulation was verified by comparison among analytic, dual-porosity simulation, and fine-grid simulation. We continued to study the mechanisms by which oil is produced from fractured porous media at high pressure and high temperature. Temperature has a beneficial effect on recovery and reduces residual oil saturation. A new experiment was conducted on diatomite core. Significantly, we show that elevated temperature induces fines release in sandstone cores and this behavior may be linked to wettability. Our work in the area of primary production of heavy oil continues with field cores and crude oil. On the topic of reservoir definition, work continued on developing techniques that integrate production history into reservoir models using streamline-based properties.

  10. A model of peak production in oil fields

    NASA Astrophysics Data System (ADS)

    Abrams, Daniel M.; Wiener, Richard J.

    2010-01-01

    We developed a model for oil production on the basis of simple physical considerations. The model provides a basic understanding of Hubbert's empirical observation that the production rate for an oil-producing region reaches its maximum when approximately half the recoverable oil has been produced. According to the model, the oil production rate at a large field must peak before drilling peaks. We use the model to investigate the effects of several drilling strategies on oil production. Despite the model's simplicity, predictions for the timing and magnitude of peak production match data on oil production from major oil fields throughout the world.

  11. Bailey's industrial oil and fat products

    SciTech Connect

    Swern, D.

    1982-01-01

    The material in this book is divided into 7 chapters and is not solely an updating of subjects from earlier editions. Information on hydrogenation (chapter 1) is an update of the process in oil and fat technology. Chapter 2, entitled Fat Splitting, Esterification, and Interesterification, described the techniques used to obtain some of the most important chemical raw materials derived from oils and fats. The widely diverse natural sources of and the processing of oils and fats to render them suitable for the many industrial and edible applications are addressed in chapter 3, Extraction of Fats and Oils, and in chapter 4, Refining and Bleaching. Selected important commercial uses for oils and fats in edible products that show improved demand are discussed in chapter 5, and predominately industrial uses of oils and fats form the basis of material in chapter 6. The discussion of analytical methods for oils and fats covered in chapter 7 is entirely new material as is that covering environmental aspects presented in chapter 8. (BLM)

  12. Biodiesel production using waste frying oil

    SciTech Connect

    Charpe, Trupti W.; Rathod, Virendra K.

    2011-01-15

    Research highlights: {yields} Waste sunflower frying oil is successfully converted to biodiesel using lipase as catalyst. {yields} Various process parameters that affects the conversion of transesterification reaction such as temperature, enzyme concentration, methanol: oil ratio and solvent are optimized. {yields} Inhibitory effect of methanol on lipase is reduced by adding methanol in three stages. {yields} Polar solvents like n-hexane and n-heptane increases the conversion of tranesterification reaction. - Abstract: Waste sunflower frying oil is used in biodiesel production by transesterification using an enzyme as a catalyst in a batch reactor. Various microbial lipases have been used in transesterification reaction to select an optimum lipase. The effects of various parameters such as temperature, methanol:oil ratio, enzyme concentration and solvent on the conversion of methyl ester have been studied. The Pseudomonas fluorescens enzyme yielded the highest conversion. Using the P. fluorescens enzyme, the optimum conditions included a temperature of 45 deg. C, an enzyme concentration of 5% and a methanol:oil molar ratio 3:1. To avoid an inhibitory effect, the addition of methanol was performed in three stages. The conversion obtained after 24 h of reaction increased from 55.8% to 63.84% because of the stage-wise addition of methanol. The addition of a non-polar solvent result in a higher conversion compared to polar solvents. Transesterification of waste sunflower frying oil under the optimum conditions and single-stage methanol addition was compared to the refined sunflower oil.

  13. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    SciTech Connect

    Anthony R. Kovscek; Louis M. Castanier

    2004-03-01

    This technical progress report describes work performed from July 1 through September, 2003 for the project ''Heavy and Thermal Oil Recovery Production Mechanisms,'' DE-FC26-00BC15311. In this project, a broad spectrum of research is undertaken related to thermal and heavy-oil recovery. The research tools and techniques span from pore-level imaging of multiphase fluid flow to definition of reservoir-scale features through streamline-based history-matching techniques. During this period, work focused on completing project tasks in the area of multiphase flow and rock properties. The area of interest is the production mechanisms of oil from porous media at high temperature. Temperature has a beneficial effect on oil recovery and reduces residual oil saturation. Work continued to delineate how the wettability of reservoir rock shifts from mixed and intermediate wet conditions to more water-wet conditions as temperature increases. One mechanism for the shift toward water-wet conditions is the release of fines coated with oil-wet material from pore walls. New experiments and theory illustrate the role of temperature on fines release.

  14. Optimization of biodiesel production from castor oil.

    PubMed

    da Silva, Nivea de Lima; Maciel, Maria Regina Wolf; Batistella, César Benedito; Maciel Filho, Rubens

    2006-01-01

    The transesterification of castor oil with ethanol in the presence of sodium ethoxide as catalyst is an exceptional option for the Brazilian biodiesel production, because the castor nut is quite available in the country. Chemically, its oil contains about 90% of ricinoleic acid that gives to the oil some beneficial characteristics such as its alcohol solubility at 30 degrees C. The transesterification variables studied in this work were reaction temperature, catalyst concentration and alcohol oil molar ratio. Through a star configuration experimental design with central points, this study shows that it is possible to achieve the same conversion of esters carrying out the transesterification reaction with a smaller alcohol quantity, and a new methodology was developed to obtain high purity biodiesel. PMID:16915657

  15. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    SciTech Connect

    Anthony R. Kovscek

    2003-01-01

    This technical progress report describes work performed from October 1 through December 31, 2002 , for the project ''Heavy and Thermal Oil Recovery Production Mechanisms.'' In this project, a broad spectrum of research is undertaken related to thermal and heavy-oil recovery. The research tools and techniques used are varied and span from pore-level imaging of multiphase fluid flow to definition of reservoir-scale features through streamline-based history-matching techniques. During this period, experimental data regarding multidimensional imbibition was analyzed to obtain shape factors appropriate for dual-porosity simulation. It is shown that the usual assumption of constant, time-independent shape factors is incorrect. In other work, we continued to study the mechanisms by which oil is produced from fractured media at high pressure and high temperature. High temperature significantly increased the apparent wettability and affected water relative permeability of cores used in previous experiments. A phenomenological and mechanistic cause for this behavior is sought. Our work in the area of primary production of heavy oil continues with field cores and crude oil. On the topic of reservoir definition, work continued on developing techniques that integrate production history into reservoir models using streamline-based properties.

  16. Oil as a Product of the Mantle

    NASA Astrophysics Data System (ADS)

    Ivanov, Kirill; Fedorov, Yuri; Erokhin, Yuri; Petrov, Lev; Pogromskaja, Olga; Shishmakov, A.; Biglov, Kamil

    2010-05-01

    Thermodynamic calculations and experiments showed that methane can not polymerize into heavier hydrocarbons at pressures lower than 5 kbar, while for a synthesis of hydrocarbon systems similar on composition to nature oils it is necessary 700-1800° and 15-80 kbar [1, 2]. If oil had been formed in mantle, composed mainly of ultrabasic rocks, then it is logically to suppose that oil and ultramaphite interrelation should be reflected upon its microelement composition. The West Siberia and Tatarstan oil geochemical study (by ICP-MS method; Element 2, analytics Yu.L. Ronkin et al., lab. of physical-chemical methods of researches, IGG, UB RAS) shows [3] that oils possess an extremely specific microelement composition. The main geochemical oil features are limitedly low contents of the majority of microelements and a brightly expressed positive europium anomaly, characteristic for deep formations. At the diagram of the normalized REE contents a noted feature of their distribution in oils is the prevalence of light lanthanoids over middle and heavy ones (La/Yb=16-19). Ni, Co, Cr, V, Cs, Sr, Zr and PGE in oils are quite comparable with their concentrations in ultrabasites. A series of experiments on the mass transport of the organic compounds from the bituminous argillites samples (of the Bazhenov suite of the North-Pokachev, South-Yagun and Tevlin-Russkin West-Siberian oil deposits) into synthesided hydrocarbons and mineralized thermal waters has been made. It was shown that biomarker presence in natural oils is not a proof of the oil organic origin, but may be quite gained by the hydrocarbons in the process of migration through sedimentary rocks, containing the organic substance. One of the main tasks should be the development of new methods of hydrocarbon deposit prospecting. Thus, proceeding from the deep oil genesis quite an important thing is the mapping of the basement faults. The ideas being developed by us [3] give all grounds for refusing from such quite recently

  17. Microbial screening and analytical methods for the production of polyol oils from soybean oil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The objective of this study is to develop a new useful method including microbial screening and product identification for a bioprocess to produce polyol oils from soybean oil. Methods for separating of product polyol oils from soybean oil substrate and free fatty acid byproducts using HPLC and TLC...

  18. [Spontaneous superweak light of oils by their antioxidant potentional defination].

    PubMed

    Zhuravlev, A I; Zakoteev, Iu A

    2008-01-01

    It was show that by autooxidation of the oleic asid there is as spontaneous superweak light (SSL)--chemiluminescence by forming some unstable peroxides and their decomposition with synthesis of EES--and accumulation of the more stable and chemically titrated peroxides. During a chemically inductive period by native vegetable oils containing bioantioxidants the accumulation of chemically titrated peroxides is depressed completely, but SSL can be fixed and measured, it means there is degrading and forming unstable peroxides with synthesis of EES. As concerns the extent of suppression of SSL and accumulation of some titrated peroxides in the oleic acid by adding native oils the antioxidative activity (AO) of these oils was thoroughly estimated. AO of sunflower oil grown in northern lands is higher than AO of refined oils which have been refined from bioantioxidants. It is revealed that a detailed estimation of an autooxidation process is possible with studying SSL only. We offer here an oleic chemiluminescence-chemical model for a complex AO estimation of examined materials. PMID:18368855

  19. Power generation for offshore oil production

    SciTech Connect

    Chellini, R.

    1997-01-01

    French industry has played a major role in supplying surface equipment for the exploitation of the N`Kossa oil field, located in deep waters (150-300 m) some 60 km offshore the Congo Coast. This immense reservoir (7 km long, 4 km wide, 3000 m under the seabed) was discovered in 1984, and production of oil and LPG started recently. Production of crude oil, which will peak 5 million tons in 1998, and LPG, reaching 300000 tons in 1999, is expected to continue for a period of 30 years. The NKP floating barge used for production is considered a world first in many aspects. It was designed by CTIP Geoproduction (TPG) for the operator, ELF Congo, and was constructed in Marseilles. The barge, which features a prestressed concrete hull, has a bearing capacity of 330000 tons. It is 220 long and 46 m wide, providing a deck area of one hectare. All production facilities as well as living quarters for 160 people are housed on the barge which, for construction purposes, was subdivided into six modules. This paper describes the design of the power generation module. 3 figs.

  20. OIL CONTENT IN PRODUCED BRINE ON TEN LOUISIANA PRODUCTION PLATFORMS

    EPA Science Inventory

    A survey of the oil content of brine effluents from offshore crude oil production platforms was conducted for the Oil and Hazardous Spills Branch of the Environmental Protection Agency. The objectives were to determine the amount of oil in the brine, and to determine the factors ...

  1. Upgrading of light Fischer-Tropsch products

    SciTech Connect

    Shah, P.P.

    1990-11-30

    The upgrading of Fischer-Tropsch (F-T) light ends was studied at UOP in a program sponsored by the Pittsburgh Energy Technology Center of the US Department of Energy. The goal of the program was to increase the overall yield of marketable transportation fuels from the F-T upgrading complex by focusing on liquefied petroleum gas (LPG) and naphtha. An overview of the entire light-ends program is presented in this paper. Although this contract is specifically concerned with light products (C{sub 3}-C{sub 11}), a separate DOE-sponsored program at UOP investigated the characterization and upgrading of the heavy end of the F-T product spectrum: F-T wax. An economic analysis of the light and heavy ends upgrading was performed to evaluate the conversion of F-T products to marketable transportation fuels. 9 refs., 7 figs., 9 tabs.

  2. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    SciTech Connect

    Anthony R. Kovscek; Louis M. Castanier

    2002-09-30

    The Stanford University Petroleum Research Institute (SUPRI-A) conducts a broad spectrum of research intended to help improve the recovery efficiency from difficult to produce reservoirs including heavy oil and fractured low permeability systems. Our scope of work is relevant across near-, mid-, and long-term time frames. The primary functions of the group are to conduct direction-setting research, transfer research results to industry, and educate and train students for careers in industry. Presently, research in SUPRI-A is divided into 5 main project areas. These projects and their goals include: (1) Multiphase flow and rock properties--to develop better understanding of the physics of displacement in porous media through experiment and theory. This category includes work on imbibition, flow in fractured media, and the effect of temperature on relative permeability and capillary pressure. (2) Hot fluid injection--to improve the application of nonconventional wells for enhanced oil recovery and elucidate the mechanisms of steamdrive in low permeability, fractured porous media. (3) Mechanisms of primary heavy oil recovery--to develop a mechanistic understanding of so-called ''foamy oil'' and its associated physical chemistry. (4) In-situ combustion--to evaluate the effect of different reservoir parameters on the insitu combustion process. (5) Reservoir definition--to develop and improve techniques for evaluating formation properties from production information. What follows is a report on activities for the past year. Significant progress was made in all areas.

  3. Effect of oil and oil products on lipase activity in gray forest soil

    NASA Astrophysics Data System (ADS)

    Kireeva, N. A.; Tarasenko, E. M.; Shamaeva, A. A.; Novoselova, E. I.

    2006-08-01

    The effect of different rates of oil and oil products on the lipase activity in gray forest soil was studied under field and laboratory conditions. It was found that hydrocarbons activate the lipolytic activity of the soil. Along with the activation of lipolysis, an increase in the number of hydrocarbon-oxidizing microorganisms and a decrease in the content of oil products were observed.

  4. Production of polyol oils from soybean oil by Pseudomonas aeruginosa E03-12.

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Soy-polyols are important starting materials for the manufacture of polymers such as polyurethane. We have been trying to develop a bioprocess for the production of polyol oils directly from soybean oil. We reported earlier the polyol products produced from soybean oil by Acinetobacter haemolyticus ...

  5. Production of polyol oils from soybean oil by bioprocess and Philippines edible medicinal wild mushrooms

    Technology Transfer Automated Retrieval System (TEKTRAN)

    We have been trying to develop a bioprocess for the production of polyol oils directly from soybean oil. We reported earlier the polyol products produced from soybean oil by Acinetobacter haemolyticus A01-35 (NRRL B-59985) (Hou and Lin, 2013). The objective of this study is to identify the chemical ...

  6. Regulation of lipid production by light-emitting diodes in human sebocytes.

    PubMed

    Jung, Yu Ra; Kim, Sue Jeong; Sohn, Kyung Cheol; Lee, Young; Seo, Young Joon; Lee, Young Ho; Whang, Kyu Uang; Kim, Chang Deok; Lee, Jeung Hoon; Im, Myung

    2015-04-01

    Light-emitting diodes (LED) have been used to treat acne vulgaris. However, the efficacy of LED on sebaceous lipid production in vitro has not been examined. This study investigated the efficacy of 415 nm blue light and 630 nm red light on lipid production in human sebocytes. When applied to human primary sebocytes, 415 nm blue light suppressed cell proliferation. Based on a lipogenesis study using Oil Red O, Nile red staining, and thin-layered chromatography, 630 nm red light strongly downregulated lipid production in sebocytes. These results suggest that 415 nm blue light and 630 nm red light influence lipid production in human sebocytes and have beneficial effects on acne by suppressing sebum production. PMID:25690162

  7. Green processing for commercial production of feruloylated vegetable oils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Covalent incorporation of ferulic acid into vegetable oils produces a desirable product for cosmetic applications. Current practice involves the biocatalytic transesterification of ethyl ferulate with soybean oil, followed by a molecular distillation step to remove unconsumed ethyl ferulate and the...

  8. Dispersion Of Crude Oil And Petroleum Products In Freshwater

    EPA Science Inventory

    The objective of this research was to investigate the relationship between dispersion effectiveness in freshwater and the surfactant composition for fresh and weathered crude oil. Although limited research on the chemical dispersion of crude oil and petroleum products in freshwat...

  9. Catalyst life and product color prediction for gas oil HDS

    SciTech Connect

    Ushio, M.; Hatayama, M.; Waku, T.

    1995-12-31

    Gas oil hydrodesulfurization was investigated. The sulfur content was reduced by increasing the reaction temperature. However, the severe temperatures made the product oil colored. The kinetic parameters of decoloring reaction at lower tempeatures were calculated.

  10. [Pollution hazard for water bodies at oil production].

    PubMed

    Zholdakova, Z I; Beliaeva, N I

    2015-01-01

    In the paper there have been summarizes the concepts of the danger of the pollution ofwater bodies in oil production (the most dangerous are reagents used in the drilling, drilling waste, oil and petrochemicals, oil biodestructors. There was shown the danger of the spread of oil pollution. New indices, presenting a hazard during drilling and oil production have been substantiated The tasks aimed to the improvement of the standards and methods of the control of the water pollution by oil, as well as of the documents regulating the conditions of environmental protection during the drilling have been conceived. PMID:26031037

  11. Bio Gas Oil Production from Waste Lard

    PubMed Central

    Hancsók, Jenő; Baladincz, Péter; Kasza, Tamás; Kovács, Sándor; Tóth, Csaba; Varga, Zoltán

    2011-01-01

    Besides the second generations bio fuels, one of the most promising products is the bio gas oil, which is a high iso-paraffin containing fuel, which could be produced by the catalytic hydrogenation of different triglycerides. To broaden the feedstock of the bio gas oil the catalytic hydrogenation of waste lard over sulphided NiMo/Al2O3 catalyst, and as the second step, the isomerization of the produced normal paraffin rich mixture (intermediate product) over Pt/SAPO-11 catalyst was investigated. It was found that both the hydrogenation and the decarboxylation/decarbonylation oxygen removing reactions took place but their ratio depended on the process parameters (T = 280–380°C, P = 20–80 bar, LHSV = 0.75–3.0 h−1 and H2/lard ratio: 600 Nm3/m3). In case of the isomerization at the favourable process parameters (T = 360–370°C, P = 40 –50 bar, LHSV = 1.0 h−1 and H2/hydrocarbon ratio: 400 Nm3/m3) mainly mono-branching isoparaffins were obtained. The obtained products are excellent Diesel fuel blending components, which are practically free of heteroatoms. PMID:21403875

  12. The NKOSSA concrete oil production barge

    SciTech Connect

    Valenchon, C.; Nagel, R.; Viallon, J.P.; Belbeoc`h, H.; Rouillon, J.

    1995-12-31

    This paper gives a presentation of the NKOSSA Production Barge. Most attention is, however, paid to the concrete hull. As part of the development of the NKOSSA hydrocarbon field located off the Congolese coast, West Africa, ELF CONGO will use a prestressed concrete barge as the main production facility to carry the equipment for oil and gas treatment. Once operational at the KNOSSA field, the barge and its 30,000 tons of equipment will house 160 people, serve as control center for the other field installations and provide oil treatment, LPG production, gas reinjection and water injection functions together with all utilities. The hull of the barge is of rectangular shape, 220 m long, 46 m wide and 16 m high. The bottom is 45 cm thick, the sides 50 cm and the deck 40 cm thick. High performance concrete, with a 70 MPa compressive cylinder strength is used for the construction of the hull, for both strength and durability purposes. The barge will be permanently anchored in 170 m water depth by twelve 4.5 inch chains in group of three at each corner of the vessel.

  13. Cultivation of yeast on light-oil fractions of hard-coal tar

    SciTech Connect

    Kucher, R.V.; Dzumeozei, N.V.; Pavlyuk, M.I.; Tyrovskii, A.A.

    1982-01-01

    The results are given of experiments on the cultivation of the yeast Candida tropicalis on light-oil fractions of coal-tar. It has been shown that a light fraction can serve as the sole source of carbon and energy. Surface active agents stimulate the growth of the yeast on the light-oil fractions of hard-coal tar.

  14. Microbially Enhanced Oil Recovery by Sequential Injection of Light Hydrocarbon and Nitrate in Low- And High-Pressure Bioreactors.

    PubMed

    Gassara, Fatma; Suri, Navreet; Stanislav, Paul; Voordouw, Gerrit

    2015-10-20

    Microbially enhanced oil recovery (MEOR) often involves injection of aqueous molasses and nitrate to stimulate resident or introduced bacteria. Use of light oil components like toluene, as electron donor for nitrate-reducing bacteria (NRB), offers advantages but at 1-2 mM toluene is limiting in many heavy oils. Because addition of toluene to the oil increased reduction of nitrate by NRB, we propose an MEOR technology, in which water amended with light hydrocarbon below the solubility limit (5.6 mM for toluene) is injected to improve the nitrate reduction capacity of the oil along the water flow path, followed by injection of nitrate, other nutrients (e.g., phosphate) and a consortium of NRB, if necessary. Hydrocarbon- and nitrate-mediated MEOR was tested in low- and high-pressure, water-wet sandpack bioreactors with 0.5 pore volumes of residual oil in place (ROIP). Compared to control bioreactors, those with 11-12 mM of toluene in the oil (gained by direct addition or by aqueous injection) and 80 mM of nitrate in the aqueous phase produced 16.5 ± 4.4% of additional ROIP (N = 10). Because toluene is a cheap commodity chemical, HN-MEOR has the potential to be a cost-effective method for additional oil production even in the current low oil price environment. PMID:26406569

  15. Discovery of oil reserves through production geology

    SciTech Connect

    Harker, S.D.

    1988-01-01

    Production geology, effectively integrated with other disciplines, resulted in an increase in main area Claymore reserves of 29 million standard bbl to date. From mid-1983 to mid-1987, daily oil production increased from 43,000 to 55,000 standard bbl. The Claymore field is located in the North Sea, 110 mi northeast of Aberdeen, Scotland. It was discovered in 1974 and brought on stream in 1977. In 1978, main area Claymore peak daily production was 62,000 standard bbl. Production is from Late Jurassic sandstones in a truncated, tilted fault block on the southwest margin of the Witch Ground graben. The Sgiath and Piper formations of the lower reservoir are overlain by the Claymore Sandstone Member of the Kimmeridge Clay Formation. The Claymore consists of up to 1,630 ft of thinly bedded, fine-grained turbidite sandstones and contained 95% of the main area Claymore original oil in place. The Claymore Sandstone Member is divided into two informal units: low gamma-ray sands and high gamma-ray sands. Areal sweep and water injection effectiveness are evaluated by the use of well logs, flowmeter surveys, and RFT pressures. New well locations are selected only after very detailed sedimentology and structural geology appraisal. True vertical thickness logs are used for stratigraphic correlation. Together with core studies, high-resolution dipmeter is used for bed definition as well as structural interpretation. Three-dimensional seismic coverage is fully integrated with the use of many true-scale structural cross sections. The integration of all available geological, geophysical, and engineering data is crucial to the continuing success of main area Claymore reservoir management.

  16. Method and apparatus for improving oil production in oil wells

    SciTech Connect

    Vogen, W.V.

    1987-06-23

    This patent describes a method for improving the production of oil from appropriate wells, comprising: attaching the lower end of an elastic steel column to the upper end of a liner; the upper end of the column extending to the top of the well and above; attaching the upper end of the column to a reaction mass vertically above through vertically mounted compression spring means and, in parallel with a vertically mounted servo-controlled hydraulic cylinder-piston assembly; applying a substantially constant upward load to the reactions mass; reciprocating the piston of the hydraulic cylinder under servo control to apply vertical vibration to the upper end of the column with resultant vertical displacement of the upper end of the column; developing a displacement signal while developing an electrical, pressure-differential signal corresponding to the pressure across the cylinder-piston assembly; adjusting the vertical vibration through the servo control in accordance with the displacement signal and the pressure differential signal: to seek and find an appropriate resonant frequency for the column in the range of 5 Hz to 25 Hz; and maintaining the frequency at resonance.

  17. Market analysis of shale oil co-products. Appendices

    SciTech Connect

    Not Available

    1980-12-01

    Data are presented in these appendices on the marketing and economic potential for soda ash, aluminia, and nahcolite as by-products of shale oil production. Appendices 1 and 2 contain data on the estimated capital and operating cost of an oil shales/mineral co-products recovery facility. Appendix 3 contains the marketing research data.

  18. Screening of microbes for the production of polyol oils from soybean oil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Introduction. More than 30.6 million tons of soybean oil were produced worldwide annually and the major use of this oil is for food products. Triacylglycerols (TAG) containing hydroxy fatty acids (FA), e.g., castor oil, have many industrial uses such as the manufacture of aviation lubricant, plasti...

  19. Combined effect of oil, oil products and dispersants on the blue-green algae Synechocystis aquatilis and Anabaena variabilis

    SciTech Connect

    Gapochka, L.D.; Brodskii, L.I.; Kravchenko, M.E.; Fedorov, V.D.

    1980-01-01

    The study of the combined effect of oil, oil products and dispersants on the growth of the blue-green algae Synechocystis aquatilis and Anabaena variabilis has shown that out of 12 studied oil-dispersant pairs 6 revealed a positive relationship, which provides evidence for a decrease in oil and oil products toxic effect in the presence of a dispersant. The positive interaction between oil and oil products was found. The negative oil and oil products effect on all studied indices of A. variabilis culture increases with time.

  20. Oil from hydrocracking as a raw material for the production of white oils

    SciTech Connect

    Potanina, V.A.; Dremova, T.I.; Ponomareva, T.P.; Zlotnikov, V.Z.

    1984-01-01

    This article investigates the feasibility of using distillate oil from hydrocracking for white oil production. A process technology has been developed in the USSR for the manufacture of high-quality oils by hydrocracking a heavy distillate feed in high-pressure equipment. The neutral and hydrocracked oil sample and a blend of these stocks were subjected to treatment with oleum, neutralization with 65% ethyl alcohol, and contact finishing to obtain white oils. The physicochemical properties of the white oils are given. It is determined that the hydrocracked oil can be used as the raw material in manufacturing perfume oil meeting the standard GOST 4225-76, and that the blends can be used to obtain pharmaceutical white oil meeting the standard GOST 3164-78.

  1. Life Cycle Assessment for the Production of Oil Palm Seeds

    PubMed Central

    Muhamad, Halimah; Ai, Tan Yew; Khairuddin, Nik Sasha Khatrina; Amiruddin, Mohd Din; May, Choo Yuen

    2014-01-01

    The oil palm seed production unit that generates germinated oil palm seeds is the first link in the palm oil supply chain, followed by the nursery to produce seedling, the plantation to produce fresh fruit bunches (FFB), the mill to produce crude palm oil (CPO) and palm kernel, the kernel crushers to produce crude palm kernel oil (CPKO), the refinery to produce refined palm oil (RPO) and finally the palm biodiesel plant to produce palm biodiesel. This assessment aims to investigate the life cycle assessment (LCA) of germinated oil palm seeds and the use of LCA to identify the stage/s in the production of germinated oil palm seeds that could contribute to the environmental load. The method for the life cycle impact assessment (LCIA) is modelled using SimaPro version 7, (System for Integrated environMental Assessment of PROducts), an internationally established tool used by LCA practitioners. This software contains European and US databases on a number of materials in addition to a variety of European- and US-developed impact assessment methodologies. LCA was successfully conducted for five seed production units and it was found that the environmental impact for the production of germinated oil palm was not significant. The characterised results of the LCIA for the production of 1000 germinated oil palm seeds showed that fossil fuel was the major impact category followed by respiratory inorganics and climate change. PMID:27073598

  2. Life Cycle Assessment for the Production of Oil Palm Seeds.

    PubMed

    Muhamad, Halimah; Ai, Tan Yew; Khairuddin, Nik Sasha Khatrina; Amiruddin, Mohd Din; May, Choo Yuen

    2014-12-01

    The oil palm seed production unit that generates germinated oil palm seeds is the first link in the palm oil supply chain, followed by the nursery to produce seedling, the plantation to produce fresh fruit bunches (FFB), the mill to produce crude palm oil (CPO) and palm kernel, the kernel crushers to produce crude palm kernel oil (CPKO), the refinery to produce refined palm oil (RPO) and finally the palm biodiesel plant to produce palm biodiesel. This assessment aims to investigate the life cycle assessment (LCA) of germinated oil palm seeds and the use of LCA to identify the stage/s in the production of germinated oil palm seeds that could contribute to the environmental load. The method for the life cycle impact assessment (LCIA) is modelled using SimaPro version 7, (System for Integrated environMental Assessment of PROducts), an internationally established tool used by LCA practitioners. This software contains European and US databases on a number of materials in addition to a variety of European- and US-developed impact assessment methodologies. LCA was successfully conducted for five seed production units and it was found that the environmental impact for the production of germinated oil palm was not significant. The characterised results of the LCIA for the production of 1000 germinated oil palm seeds showed that fossil fuel was the major impact category followed by respiratory inorganics and climate change. PMID:27073598

  3. Sophorolipids Production by Candida bombicola ATCC 22214 and its Potential Application in Microbial Enhanced Oil Recovery

    PubMed Central

    Elshafie, Abdulkadir E.; Joshi, Sanket J.; Al-Wahaibi, Yahya M.; Al-Bemani, Ali S.; Al-Bahry, Saif N.; Al-Maqbali, Dua’a; Banat, Ibrahim M.

    2015-01-01

    Biosurfactant production using Candida bombicola ATCC 22214, its characterization and potential applications in enhancing oil recovery were studied at laboratory scale. The seed media and the production media were standardized for optimal growth and biosurfactant production. The production media were tested with different carbon sources: glucose (2%w/v) and corn oil (10%v/v) added separately or concurrently. The samples were collected at 24 h interval up to 120 h and checked for growth (OD660), and biosurfactant production [surface tension (ST) and interfacial tension (IFT)]. The medium with both glucose and corn oil gave better biosurfactant production and reduced both ST and IFT to 28.56 + 0.42mN/m and 2.13 + 0.09mN/m, respectively within 72 h. The produced biosurfactant was quite stable at 13–15% salinity, pH range of 2–12, and at temperature up to 100°C. It also produced stable emulsions (%E24) with different hydrocarbons (pentane, hexane, heptane, tridecane, tetradecane, hexadecane, 1-methylnaphthalene, 2,2,4,4,6,8-heptamethylnonane, light and heavy crude oil). The produced biosurfactant was extracted using ethyl acetate and characterized as a mixture of sophorolipids (SPLs). The potential of SPLs in enhancing oil recovery was tested using core-flooding experiments under reservoir conditions, where additional 27.27% of residual oil (Sor) was recovered. This confirmed the potential of SPLs for applications in microbial enhanced oil recovery. PMID:26635782

  4. Life-Cycle Assessment of Pyrolysis Bio-Oil Production*

    SciTech Connect

    Steele, Philip; Puettmann, Maureen E.; Penmetsa, Venkata Kanthi; Cooper, Jerome E.

    2012-07-01

    As part ofthe Consortium for Research on Renewable Industrial Materials' Phase I life-cycle assessments ofbiofuels, lifecycle inventory burdens from the production of bio-oil were developed and compared with measures for residual fuel oil. Bio-oil feedstock was produced using whole southern pine (Pinus taeda) trees, chipped, and converted into bio-oil by fast pyrolysis. Input parameters and mass and energy balances were derived with Aspen. Mass and energy balances were input to SimaPro to determine the environmental performance of bio-oil compared with residual fuel oil as a heating fuel. Equivalent functional units of 1 MJ were used for demonstrating environmental preference in impact categories, such as fossil fuel use and global warming potential. Results showed near carbon neutrality of the bio-oil. Substituting bio-oil for residual fuel oil, based on the relative carbon emissions of the two fuels, estimated a reduction in CO2 emissions by 0.075 kg CO2 per MJ of fuel combustion or a 70 percent reduction in emission over residual fuel oil. The bio-oil production life-cycle stage consumed 92 percent of the total cradle-to-grave energy requirements, while feedstock collection, preparation, and transportation consumed 4 percent each. This model provides a framework to better understand the major factors affecting greenhouse gas emissions related to bio-oil production and conversion to boiler fuel during fast pyrolysis.

  5. Saturating Light Induces Sustained Accumulation of Oil in Plastidal Lipid Droplets in Chlamydomonas reinhardtii.

    PubMed

    Goold, Hugh Douglas; Cuiné, Stéphan; Légeret, Bertrand; Liang, Yuanxue; Brugière, Sabine; Auroy, Pascaline; Javot, Hélène; Tardif, Marianne; Jones, Brian; Beisson, Fred; Peltier, Gilles; Li-Beisson, Yonghua

    2016-08-01

    Enriching algal biomass in energy density is an important goal in algal biotechnology. Nitrogen (N) starvation is considered the most potent trigger of oil accumulation in microalgae and has been thoroughly investigated. However, N starvation causes the slow down and eventually the arrest of biomass growth. In this study, we show that exposing a Chlamydomonas reinhardtii culture to saturating light (SL) under a nonlimiting CO2 concentration in turbidostatic photobioreactors induces a sustained accumulation of lipid droplets (LDs) without compromising growth, which results in much higher oil productivity than N starvation. We also show that the polar membrane lipid fraction of SL-induced LDs is rich in plastidial lipids (approximately 70%), in contrast to N starvation-induced LDs, which contain approximately 60% lipids of endoplasmic reticulum origin. Proteomic analysis of LDs isolated from SL-exposed cells identified more than 200 proteins, including known proteins of lipid metabolism, as well as 74 proteins uniquely present in SL-induced LDs. LDs induced by SL and N depletion thus differ in protein and lipid contents. Taken together, lipidomic and proteomic data thus show that a large part of the sustained oil accumulation occurring under SL is likely due to the formation of plastidial LDs. We discuss our data in relation to the different metabolic routes used by microalgae to accumulate oil reserves depending on cultivation conditions. Finally, we propose a model in which oil accumulation is governed by an imbalance between photosynthesis and growth, which can be achieved by impairing growth or by boosting photosynthetic carbon fixation, with the latter resulting in higher oil productivity. PMID:27297678

  6. Screening and characterization of oleaginous Chlorella strains and exploration of photoautotrophic Chlorella protothecoides for oil production.

    PubMed

    Sun, Zheng; Zhou, Zhi-gang; Gerken, Henri; Chen, Feng; Liu, Jin

    2015-05-01

    The growth and oil production of nine Chlorella strains were comparatively assessed and Chlorellaprotothecoides CS-41 demonstrated the greatest lipid production potential. The effects of different nitrogen forms and concentrations, phosphorus concentrations and light intensities on growth and oil production were studied in laboratory columns. C. protothecoides CS-41 accumulated lipids up to 55% of dry weight, with triacylglycerol and oleic acid being 71% of total lipids and 59% of total fatty acids, respectively. High biomass and lipid productivities were achieved in outdoor panel PBRs, up to 1.25 and 0.59 g L(-1) day(-1), or 44. 1 and 16.1 g m(-2) day(-1), respectively. A two-stage cultivation strategy was proposed to enhance the algal biomass and lipid production. This is the first comprehensive investigation of both indoor and outdoor photoautotrophic C. protothecoides cultures for oil production, and C. protothecoides CS-41 represents a promising biofuel feedstock worthy of further exploration. PMID:25266686

  7. Light scattering measurement of sodium polyacrylate products

    NASA Astrophysics Data System (ADS)

    Lama, Nisha; Norwood, David; Boone, Steven; Massie-Boyer, Valerie

    2015-03-01

    In the presentation, we will describe the use of a multi-detector HPLC incorporating the DAWN EOS multi-angle laser light scattering (MALLS) detector to measure the properties such as molecular weight, RMS radius, contour and persistence length and polydispersity of sodium polyacrylate products. The samples of sodium polyacrylate are used in various industries as thickening agents, coating dispersants, artificial snow, laundry detergent and disposable diapers. Data and results obtained from the experiment will be presented.

  8. 40 CFR 112.9 - Spill Prevention, Control, and Countermeasure Plan Requirements for onshore oil production...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... PROGRAMS OIL POLLUTION PREVENTION Requirements for Petroleum Oils and Non-Petroleum Oils, Except Animal Fats and Oils and Greases, and Fish and Marine Mammal Oils; and Vegetable Oils (Including Oils from... Countermeasure Plan Requirements for onshore oil production facilities (excluding drilling and...

  9. 40 CFR 112.9 - Spill Prevention, Control, and Countermeasure Plan Requirements for onshore oil production...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... PROGRAMS OIL POLLUTION PREVENTION Requirements for Petroleum Oils and Non-Petroleum Oils, Except Animal Fats and Oils and Greases, and Fish and Marine Mammal Oils; and Vegetable Oils (Including Oils from... Countermeasure Plan Requirements for onshore oil production facilities (excluding drilling and...

  10. 40 CFR 112.9 - Spill Prevention, Control, and Countermeasure Plan Requirements for onshore oil production...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... PROGRAMS OIL POLLUTION PREVENTION Requirements for Petroleum Oils and Non-Petroleum Oils, Except Animal Fats and Oils and Greases, and Fish and Marine Mammal Oils; and Vegetable Oils (Including Oils from... Countermeasure Plan Requirements for onshore oil production facilities (excluding drilling and...

  11. Chemical composition of fat and oil products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Fats and oils are an important dietary component, and contribute to the nutritional and sensory quality of foods. This chapter focuses on the chemical composition of fats and oils, and how these compositions affect the functional properties of fats and oils in foods. The focus will remain on the mos...

  12. Enzymatic Products from Modified Soybean Oil Containing Hydrazinoester

    Technology Transfer Automated Retrieval System (TEKTRAN)

    We use soybean oil to produce new, non-petroleum based products. The starting material is the ene reaction product of soybean oil and diethyl azodicarboxylate (DEAD), which can then be hydrolyzed chemically and enzymatically. Chemical hydrolysis gives hydrazino-fatty acids, whereas enzymatic hydro...

  13. Potential Large-Scale Production of Conjugated Soybean Oil Catalyzed by Photolyzed Iodine in Hexanes

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A laboratory apparatus is described for the production of conjugated soybean oil (SBO) in pound quantities via irradiation with visible-light. Under our reaction conditions, quantitative conversions (determined by NMR spectroscopy) of SBO to conjugated SBO, in hexanes at reflux temperatures, were a...

  14. Production of polyol oils from soybean oil through bioprocess

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Soy-polyol oils (oxygenated acylglycerols) are important starting materials for the manufacture of polymers such as polyurethane. Currently, they are produced by a two-step chemical process involving epoxidation and then the subsequent opening of the oxirane ring. The objective of this study is to d...

  15. Estimates of future regional heavy oil production at three production rates--background information for assessing effects in the US refining industry

    SciTech Connect

    Olsen, D.K.

    1993-07-01

    This report is one of a series of publications from a project considering the feasibility of increasing domestic heavy oil (10{degree} to 20{degree} API gravity inclusive) production being conducted for the US Department of Energy. The report includes projections of future heavy oil production at three production levels: 900,000; 500,000; and 300,000 BOPD above the current 1992 heavy oil production level of 750,000 BOPD. These free market scenario projections include time frames and locations. Production projections through a second scenario were developed to examine which heavy oil areas would be developed if significant changes in the US petroleum industry occurred. The production data helps to define the possible constraints (impact) of increased heavy oil production on the US refining industry (the subject of a future report). Constraints include a low oil price and low rate of return. Heavy oil has high production, transportation, and refining cost per barrel as compared to light oil. The resource is known, but the right mix of technology and investment is required to bring about significant expansion of heavy oil production in the US.

  16. [Bio-oil production from biomass pyrolysis in molten salt].

    PubMed

    Ji, Dengxiang; Cai, Tengyue; Ai, Ning; Yu, Fengwen; Jiang, Hongtao; Ji, Jianbing

    2011-03-01

    In order to investigate the effects of pyrolysis conditions on bio-oil production from biomass in molten salt, experiments of biomass pyrolysis were carried out in a self-designed reactor in which the molten salt ZnCl2-KCl (with mole ratio 7/6) was selected as heat carrier, catalyst and dispersion agent. The effects of metal salt added into ZnCl2-KCl and biomass material on biomass pyrolysis were discussed, and the main compositions of bio-oil were determined by GC-MS. Metal salt added into molten salt could affect pyrolysis production yields remarkably. Lanthanon salt could enhance bio-oil yield and decrease water content in bio-oil, when mole fraction of 5.0% LaCl3 was added, bio-oil yield could reach up to 32.0%, and water content of bio-oil could reduce to 61.5%. The bio-oil and char yields were higher when rice straw was pyrolysed, while gas yield was higher when rice husk was used. Metal salts showed great selectivity on compositions of bio-oil. LiCl and FeCl2 promoted biomass to pyrolyse into smaller molecular weight compounds. CrCl3, CaCl2 and LaCl3 could restrain second pyrolysis of bio-oil. The research provided a scientific reference for production of bio-oil from biomass pyrolysis in molten salt. PMID:21650030

  17. Biological cleaning of soil and reservoirs from oil products

    SciTech Connect

    Zinberg, M.B.; Ivanovskaya, I.B.; Gafarov, N.A.

    1996-12-31

    The production of oil and gas condensate invariably involves environmental hazards: water and soil contamination due to miscellaneous breakdowns of technological equipment and pipeline damage. Among many existing contamination methods biological cleaning has become more popular lately. It took us some years to make investigations and to carry out a number of field tests in order to develop biological methods of cleaning soil and reservoirs from oil and gas condensate products. Our method is based on the use of special biological agents containing various active hydrocarbon oxidizing bacteria. It has been experimentally proved that biological agents of {open_quotes}Devouroil{close_quotes} possess the greatest oxidizing properties. {open_quotes}Devouroil{close_quotes} contains five kinds of hydrocarbon oxidizing bacteria of Pseudomonas, Rodococcus, Candida genera. These bacteria are extracted from natural ecosystems: underground waters, soils, reservoirs. As the agents are grown on oil distillate, they are very destructive to different oil products. We also proved the described microorganisms ability to oxidize sulfate oil and hydrocarbon condensate, which are the most toxic components. For four years our colleagues have been cleaning soil and reservoirs contaminated with oil, black oil, gas condensate and other products of hydrocarbon origin. This method was used to treat different kinds of soil and ground (grass and arable land, swamp and forest) in actual hazardous situations involving oil and gas condensate spills. Besides it was successfully applied to clean sludge storage which had been filled with oil process sewage for several years.

  18. Detection of argan oil adulteration with vegetable oils by high-performance liquid chromatography-evaporative light scattering detection.

    PubMed

    Salghi, Rachid; Armbruster, Wolfgang; Schwack, Wolfgang

    2014-06-15

    Triacylglycerol profiles were selected as indicator of adulteration of argan oils to carry out a rapid screening of samples for the evaluation of authenticity. Triacylglycerols were separated by high-performance liquid chromatography-evaporative light scattering detection. Different peak area ratios were defined to sensitively detect adulteration of argan oil with vegetable oils such as sunflower, soy bean, and olive oil up to the level of 5%. Based on four reference argan oils, mean limits of detection and quantitation were calculated to approximately 0.4% and 1.3%, respectively. Additionally, 19 more argan oil reference samples were analysed by high-performance liquid chromatography-refractive index detection, resulting in highly comparative results. The overall strategy demonstrated a good applicability in practise, and hence a high potential to be transferred to routine laboratories. PMID:24491744

  19. Genetic discovery for oil production and quality in sesame

    PubMed Central

    Wei, Xin; Liu, Kunyan; Zhang, Yanxin; Feng, Qi; Wang, Linhai; Zhao, Yan; Li, Donghua; Zhao, Qiang; Zhu, Xiaodong; Zhu, Xiaofeng; Li, Wenjun; Fan, Danlin; Gao, Yuan; Lu, Yiqi; Zhang, Xianmei; Tang, Xiumei; Zhou, Congcong; Zhu, Chuanrang; Liu, Lifeng; Zhong, Ruichun; Tian, Qilin; Wen, Ziruo; Weng, Qijun; Han, Bin; Huang, Xuehui; Zhang, Xiurong

    2015-01-01

    Oilseed crops are used to produce vegetable oil. Sesame (Sesamum indicum), an oilseed crop grown worldwide, has high oil content and a small diploid genome, but the genetic basis of oil production and quality is unclear. Here we sequence 705 diverse sesame varieties to construct a haplotype map of the sesame genome and de novo assemble two representative varieties to identify sequence variations. We investigate 56 agronomic traits in four environments and identify 549 associated loci. Examination of the major loci identifies 46 candidate causative genes, including genes related to oil content, fatty acid biosynthesis and yield. Several of the candidate genes for oil content encode enzymes involved in oil metabolism. Two major genes associated with lignification and black pigmentation in the seed coat are also associated with large variation in oil content. These findings may inform breeding and improvement strategies for a broad range of oilseed crops. PMID:26477832

  20. Genetic discovery for oil production and quality in sesame.

    PubMed

    Wei, Xin; Liu, Kunyan; Zhang, Yanxin; Feng, Qi; Wang, Linhai; Zhao, Yan; Li, Donghua; Zhao, Qiang; Zhu, Xiaodong; Zhu, Xiaofeng; Li, Wenjun; Fan, Danlin; Gao, Yuan; Lu, Yiqi; Zhang, Xianmei; Tang, Xiumei; Zhou, Congcong; Zhu, Chuanrang; Liu, Lifeng; Zhong, Ruichun; Tian, Qilin; Wen, Ziruo; Weng, Qijun; Han, Bin; Huang, Xuehui; Zhang, Xiurong

    2015-01-01

    Oilseed crops are used to produce vegetable oil. Sesame (Sesamum indicum), an oilseed crop grown worldwide, has high oil content and a small diploid genome, but the genetic basis of oil production and quality is unclear. Here we sequence 705 diverse sesame varieties to construct a haplotype map of the sesame genome and de novo assemble two representative varieties to identify sequence variations. We investigate 56 agronomic traits in four environments and identify 549 associated loci. Examination of the major loci identifies 46 candidate causative genes, including genes related to oil content, fatty acid biosynthesis and yield. Several of the candidate genes for oil content encode enzymes involved in oil metabolism. Two major genes associated with lignification and black pigmentation in the seed coat are also associated with large variation in oil content. These findings may inform breeding and improvement strategies for a broad range of oilseed crops. PMID:26477832

  1. Medicinal and cosmetics soap production from Jatropha oil.

    PubMed

    Shahinuzzaman, M; Yaakob, Zahira; Moniruzzaman, M

    2016-06-01

    Soap is the most useful things which we use our everyday life in various cleansing and cosmetics purposes. Jatropha oil is nonedible oil which has more benefits to soap making. It has also cosmetics and medicinal properties. But the presence of toxic Phorbol esters in Jatropha oil is the main constrains to use it. So it is necessary to search a more suitable method for detoxifying the Jatropha oil before the use as the main ingredient of soap production. This review implies a more suitable method for removing phorbol esters from Jatropha oil. Several parameters such as the % yield of pure Jatropha oil soap, TFM value of soap, total alkali content, free caustic alkalinity content, pH, the antimicrobial activity, and CMC value of general soap should be taken into consideration for soap from detoxified Jatropha oil. PMID:26777540

  2. Quantifying Light, Medium, and Heavy Crude Oil Distribution in Homogeneous Porous Media

    NASA Astrophysics Data System (ADS)

    Ghosh, J.; Tick, G. R.

    2008-12-01

    Crude oil recovery is highly dependent upon the physical heterogeneity of media and resulting distribution of the oil-phase within the pore spaces. Factors such as capillary force, the geometry of the pore spaces, and interfacial tension between the oil blobs and water-wet porous media will ultimately control the recovery process. Pore scale studies were conducted to study the distribution and the morphology of various fractions of crude oil in increasingly heterogeneous porous media. In addition, experiments were also carried out to characterize the temporal changes in distribution and morphology of the oil phase after a series of surfactant flooding events. Specifically, columns were packed with three different porous media with increasing heterogeneity and distributed with three different fractions (light, medium, and heavy) of crude oil. The columns were imaged using synchrotron X-ray microtomography before and after a series of surfactant floods to quantify the resulting crude oil distributions over time. Preliminary results show that the light crude oil was more heterogeneously distributed than the medium fraction crude oil within the same porous media type both before and throughout the series of surfactant floods. It was also observed that approximately 95% of the medium fraction crude oil blob-size distribution was smaller (<0.0008 cu mm) than that of the light crude oil, encompassing a significant number of blob singlets. The lighter crude oil fraction has the median blob diameter approximately 20 times greater than that of the medium crude oil fraction. These results further reveal that that oil extraction and recovery is highly dependent upon the oil fraction, the presence of small- sized blob singlets, and the resulting distributions present within porous media before and during surfactant flooding. This research will not only be helpful in understanding the factors controlling crude oil mobilization at the pore scale but also test the utility of

  3. Control system for an n-methyl-2-pyrrolidone refining unit receiving light sweet charge oil

    SciTech Connect

    Barger, F.L.; Sequeira, A.J.

    1980-11-04

    A refining unit treats light sweet charge oil with an n-methyl-2-pyrrolidone solvent, hereafter referred to as mp, in a refining tower to yield raffinate and extract mix. The mp is recovered from the raffinate and from the extract mix and returned to the refining tower. A system controlling the refining unit includes a gravity analyzer, a sulfur analyzer, and viscosity analyzers; all analyzing the light sweet charge oil and providing corresponding signals, sensors sense the flow rates of the charge oil and the mp flowing into the refining tower and the temperature of the extract mix and provide corresponding signals. One of the flow rates of the light sweet charge oil and the mp flow rates is controlled in accordance with the signals from all the analyzers and all the sensors, while the other flow rate of the light sweet charge oil and the mp flow rates is constant.

  4. Non-OPEC oil production: The key to the future

    SciTech Connect

    Borg, I.Y.

    1990-05-11

    The dramatic increase in non-OPEC oil production that has occurred since the fuel crises of the seventies was accelerated by the subsequent increases in oil prices on world markets. Current moderate world prices are attributable to increased supply in the last decade from these countries. Among those nations whose production has more than doubled since 1973 are China, Mexico, the UK, Norway, Egypt, India, Oman, Brazil, Colombia, Angola, and Syria. In this context, non-OPEC nations include the Communist oil-producing countries, since their ability to meet their own domestic demand has forestalled the day when they will compete for supplies on world markets. The prospect for continued growth in non-OPEC oil production is good. Prospects for additions to reserves continue to be bright in virgin exploration areas and semimature oil-producing provinces. Non-OPEC oil production may reach peak levels in the 1995--2000 time frame. However, production will be increasingly countered by growing demand, especially in South and Central America and Asia. It is almost certain that by the mid-nineties, competition for oil supplies in world markets will elevate the price of oil available from the well endowed OPEC nations. Supply disruptions as well may be in the offing by the turn of the century as surpluses on world markets disappear. 92 refs., 20 figs., 5 tabs.

  5. Estimating primary productivity of tropical oil palm in Malaysia using remote sensing technique and ancillary data

    NASA Astrophysics Data System (ADS)

    Kanniah, K. D.; Tan, K. P.; Cracknell, A. P.

    2014-10-01

    The amount of carbon sequestration by vegetation can be estimated using vegetation productivity. At present, there is a knowledge gap in oil palm net primary productivity (NPP) at a regional scale. Therefore, in this study NPP of oil palm trees in Peninsular Malaysia was estimated using remote sensing based light use efficiency (LUE) model with inputs from local meteorological data, upscaled leaf area index/fractional photosynthetically active radiation (LAI/fPAR) derived using UK-DMC 2 satellite data and a constant maximum LUE value from the literature. NPP values estimated from the model was then compared and validated with NPP estimated using allometric equations developed by Corley and Tinker (2003), Henson (2003) and Syahrinudin (2005) with diameter at breast height, age and the height of the oil palm trees collected from three estates in Peninsular Malaysia. Results of this study show that oil palm NPP derived using a light use efficiency model increases with respect to the age of oil palm trees, and it stabilises after ten years old. The mean value of oil palm NPP at 118 plots as derived using the LUE model is 968.72 g C m-2 year-1 and this is 188% - 273% higher than the NPP derived from the allometric equations. The estimated oil palm NPP of young oil palm trees is lower compared to mature oil palm trees (<10 years old), as young oil palm trees contribute to lower oil palm LAI and therefore fPAR, which is an important variable in the LUE model. In contrast, it is noted that oil palm NPP decreases with respect to the age of oil palm trees as estimated using the allomeric equations. It was found in this study that LUE models could not capture NPP variation of oil palm trees if LAI/fPAR is used. On the other hand, tree height and DBH are found to be important variables that can capture changes in oil palm NPP as a function of age.

  6. Production and Characterization of Biodiesel from Tung Oil

    NASA Astrophysics Data System (ADS)

    Park, Ji-Yeon; Kim, Deog-Keun; Wang, Zhong-Ming; Lu, Pengmei; Park, Soon-Chul; Lee, Jin-Suk

    The feasibility of biodiesel production from tung oil was investigated. The esterification reaction of the free fatty acids of rung oil was performed using Amberlyst-15. Optimal molar ratio of methanol to oil was determined to be 7.5:1, and Amberlyst-15 was 20.8wt% of oil by response surface methodology. Under these reaction conditions, the acid value of rung oil was reduced to 0.72mg KOH/g. In the range of the molar equivalents of methanol to oil under 5, the esterification was strongly affected by the amount of methanol but not the catalyst. When the molar ratio of methanol to oil was 4.1:1 and Amberlyst-15 was 29.8wt% of the oil, the acid value decreased to 0.85mg KOH/g. After the transesterification reaction of pretreated rung oil, the purity of rung biodiesel was 90.2wt%. The high viscosity of crude rung oil decreased to 9.8mm2/s at 40 °C. Because of the presence of eleostearic acid, which is a main component of tung oil, the oxidation stability as determined by the Rancimat method was very low, 0.5h, but the cold filter plugging point, -11 °C, was good. The distillation process did not improve the fatty acid methyl ester content and the viscosity.

  7. Investigation of the two- and three-phase relative permeability relation in carbon dioxide-oil-water systems for light and heavy oil reservoirs

    NASA Astrophysics Data System (ADS)

    Zarivnyy, Ostap

    CO2 flooding has gained increased interest in regard to both light and heavy oil reservoirs, as a means of combining improved oil recovery and geological storage of CO2 in partially depleted oil reservoirs. Distribution and movement of CO2 in oil reservoirs is a function of the relative permeability of three phases of water, oil, and CO2 in oil reservoirs. In general, three-phase relative permeability relations are required with respect to the design of CO2 field projects for accurate predictions via numerical reservoir simulation of CO 2 flood performance and to model production and injection problems. However, a two-phase relative permeability relation is used to generate the three-phase relative permeability relation for use in reservoir simulations. An overview of the available literature indicates few attempts have been made to experimentally determine the three-phase relative permeability relation for CO2-oil-water systems under practical reservoir conditions. This research attempts to investigate the two- and three-phase relative permeability relation of CO2-oil-water systems through a series of carefully designed laboratory experiments. Fourteen experiments in two-phase systems, and four experiments in three-phase systems with heavy and light oils, were conducted in order to study the effect of pressure, temperature, viscosity, and flow rate on the relative permeability relation. It was shown that relative permeability is temperature dependent and increases with an increase in temperature. Pressure and oil viscosity had similar effects, although higher pressure caused a decrease in relative permeability to water in water-oil and water-oil-gas systems. Investigating the effect of flow rate it was found that higher injection flow rate caused increase in relative permeability values. The effect of the injection flow rate on relative permeability behaviour can be explained by the formation of emulsion during the displacement process. A set of new correlations

  8. Biofuel production from catalytic cracking of woody oils.

    PubMed

    Xu, Junming; Jiang, Jianchun; Chen, Jie; Sun, Yunjuan

    2010-07-01

    The catalytic cracking reactions of several kinds of woody oils have been studied. The products were analyzed by GC-MS and FTIR and show the formation of olefins, paraffins and carboxylic acids. Several kinds of catalysts were compared. It was found that the fraction distribution of product was modified by using base catalysts such as CaO. The products from woody oils showed good cold flow properties compared with diesel used in China. The results presented in this work have shown that the catalytic cracking of woody oils generates fuels that have physical and chemical properties comparable to those specified for petroleum based fuels. PMID:20206508

  9. Market analysis of shale oil co-products. Summary report

    SciTech Connect

    Not Available

    1980-12-01

    This study examines the potential for separating, upgrading and marketing sodium mineral co-products together with shale oil production. The co-products investigated are soda ash and alumina which are derived from the minerals nahcolite and dawsonite. Five cases were selected to reflect the variance in mineral and shale oil content in the identified resource. In the five cases examined, oil content of the shale was varied from 20 to 30 gallons per ton. Two sizes of facilities were analyzed for each resource case to determine economies of scale between a 15,000 barrel per day demonstration unit and a 50,000 barrel per day full sized plant. Three separate pieces of analysis were conducted in this study: analysis of manufacturing costs for shale oil and co-products; projection of potential world markets for alumina, soda ash, and nahcolite; and determination of economic viability and market potential for shale co-products.

  10. Enhanced Microbial Pathways for Methane Production from Oil Shale

    SciTech Connect

    Paul Fallgren

    2009-02-15

    Methane from oil shale can potentially provide a significant contribution to natural gas industry, and it may be possible to increase and continue methane production by artificially enhancing methanogenic activity through the addition of various substrate and nutrient treatments. Western Research Institute in conjunction with Pick & Shovel Inc. and the U.S. Department of Energy conducted microcosm and scaled-up reactor studies to investigate the feasibility and optimization of biogenic methane production from oil shale. The microcosm study involving crushed oil shale showed the highest yield of methane was produced from oil shale pretreated with a basic solution and treated with nutrients. Incubation at 30 C, which is the estimated temperature in the subsurface where the oil shale originated, caused and increase in methane production. The methane production eventually decreased when pH of the system was above 9.00. In the scaled-up reactor study, pretreatment of the oil shale with a basic solution, nutrient enhancements, incubation at 30 C, and maintaining pH at circumneutral levels yielded the highest rate of biogenic methane production. From this study, the annual biogenic methane production rate was determined to be as high as 6042 cu. ft/ton oil shale.

  11. Factors influencing the design and construction of oil production platforms

    SciTech Connect

    Wells, K.J.; Tilston, C.G.

    1980-01-01

    A brief account is given of the requirements that are imposed in the drilling, production, processing and export of oil, and the consequential demands made on platforms that support these operations. The way in which current platform designs meet these demands is discussed. Particular reference is made to the Thistle and Beatrice fields, operated by The British National Oil Corp.

  12. Oil Biotechnology: Value-Added Products and Bioactive Fatty Acids

    Technology Transfer Automated Retrieval System (TEKTRAN)

    During my 40+ years research career, I have been working on "biocatalysis" of hydrophobic organic compounds, both petroleum oil and vegetable oil, to convert them to value-added products. "Biocatalysis" is defined as the use of a biocatalyst such as whole microbial cells or enzymes, in an aqueous o...

  13. By-products: oil sorbents as a potential energy source.

    PubMed

    Karakasi, Olga K; Moutsatsou, Angeliki

    2013-04-01

    The present study investigated the utilization of an industrial by-product, lignite fly ash, in oil pollution treatment, with the further potential profit of energy production. The properties of lignite fly ash, such as fine particle size, porosity, hydrophobic character, combined with the properties, such as high porosity and low specific gravity, of an agricultural by-product, namely sawdust, resulted in an effective oil-sorbent material. The materials were mixed either in the dry state or in aqueous solution. The oil sorption behaviour of the fly ash-sawdust mixtures was investigated in both marine and dry environments. Mixtures containing fly ash and 15-25% w/w sawdust performed better than each material alone when added to oil spills in a marine environment, as they formed a cohesive semi-solid phase, adsorbing almost no water, floating on the water surface and allowing total oil removal. For the clean-up of an oil spill 0.5 mm thick with surface area 1000 m(2), 225-255 kg of lignite fly ash can be utilized with the addition of 15-25% w/w sawdust. Fly ash-sawdust mixtures have also proved efficient for oil spill clean-up on land, since their oil sorption capacity in dry conditions was at least 0.6-1.4 g oil g(-1) mixture. The higher calorific value of the resultant oil-fly ash-sawdust mixtures increased up to that of bituminous coal and oil and exceeded that of lignite, thereby encouraging their utilization as alternative fuels especially in the cement industry, suggesting that the remaining ash can contribute in clinker production. PMID:23179513

  14. Allocating petroleum products during oil supply disruptions.

    PubMed

    Bezdek, R H; Taylor, W B

    1981-06-19

    Four options for allocating a long-term, severe shortfall of petroleum imports are analyzed: oil price and allocation controls, coupon gasoline rationing, variable gasoline tax and rebate, and no oil price controls with partial rebates. Each of these options is evaluated in terms of four criteria: microeconomic effects, macroeconomic effects, equity, and practical problems. The implications of this analysis for energy contingency planning are discussed. PMID:17746245

  15. Pyrolysis oil-based lipid production as biodiesel feedstock by Rhodococcus opacus.

    PubMed

    Wei, Zhen; Zeng, Guangming; Kosa, Matyas; Huang, Danlian; Ragauskas, Arthur J

    2015-01-01

    Light oil from pyrolysis, which accounts for ∼10 % carbon yield of the starting biomass, is a complex aqueous product that is difficult to utilize and usually discarded. This work presents the feasibility of light oil as a sole carbon source to support the growth of Rhodococcus opacus (R. opacus) that in turn accumulate triacylglycerols as biodiesel feedstock. Two types of bacteria (R. opacus PD630 and DSM 1069) were selected in this study. Research results showed that after short adaption periods both strains can grow well on this complex carbon source, as proved by the consumption of oligomers and monomers in light oil. Lipid content by R. opacus PD630 and DSM 1069 was observed up to 25.8 % and 22.0 % of cell dry weight, respectively. Palmitic and stearic acids were found to be the predominant fatty acids in these bacterial cells. In addition, the light oil-based lipid production can be enhanced by reducing the pH value from 7 to 4, especially in case of DSM 1069. PMID:25377250

  16. Light irradiance and spectral distribution effects on cyanobacterial hydrogen production

    NASA Astrophysics Data System (ADS)

    Fatihah Salleh, Siti; Kamaruddin, Azlina; Hekarl Uzir, Mohamad; Rahman Mohamed, Abdul; Halim Shamsuddin, Abdul

    2016-03-01

    Light is an essential energy source for photosynthetic cyanobacteria. Changes in both light irradiance and spectral distribution will affect their photosynthetic productivity. Compared to the light irradiance, little investigations have been carried out on the effect of light spectra towards cyanobacterial hydrogen production. Hence, this work aims to investigate the effects of both light quantity and quality on biohydrogen productivity of heterocystous cyanobacterium, A.variabilis. Under white light condition, the highest hydrogen production rate of 31 µmol H2 mg chl a -1 h-1 was achieved at 70 µE m-2 s-1. When the experiment was repeated at the same light irradiance but different light spectra of blue, red and green, the accumulations of hydrogen were significantly lower than the white light except for blue light. As the light irradiance was increased to 350 µE m-2 s-1, the accumulated hydrogen under the blue light doubled that of the white light. Besides that, an unusual prolongation of the hydrogen production up to 120 h was observed. The results obtained suggest that blue light could be the most desirable light spectrum for cyanobacterial hydrogen production.

  17. Outer Continental Shelf Oil and Gas Leasing/Production Program

    SciTech Connect

    Not Available

    1988-01-01

    This annual report on the Outer Continental Shelf (OCS) Oil and Gas Leasing and Production program summarizes receipts and expenditures, and includes information on OCS safety violations as reported by the US Coast Guard. 3 figs., 12 tabs.

  18. Heavy and Thermal Oil Recovery Production Mechanisms, SUPRI TR-127

    SciTech Connect

    Kovscek, Anthony R.; Brigham, William E.; Castanier, Louis M.

    2001-09-07

    The program spans a spectrum of topics and is divided into five categories: (i) multiphase flow and rock properties, (ii) hot fluid injection, (iii) primary heavy-oil production, (iv) reservoir definition, and (v) in-situ combustion.

  19. AIR POLLUTION CONTROL ALTERNATIVES FOR SHALE OIL PRODUCTION OPERATIONS

    EPA Science Inventory

    The report consolidates, evaluates, and presents available air pollution emission data and air pollution control technology relevant to oil shale production, for use by project developers in preparing environmental impact statements and permit applications under Clean Air Act and...

  20. Parameterization for light ion production from electromagnetic dissociation

    NASA Astrophysics Data System (ADS)

    Norbury, John

    2014-09-01

    Light ion (hydrogen and helium isotopes) production from relativistic nucleus-nucleus collisions is important in space radiation protection problems, when galactic cosmic rays interact with spacecraft. In fact, for thick spacecraft shields, such as the International Space Station, light ion and neutron production can dominate the contribution to dose equivalent. Both strong and electromagnetic interactions can contribute to light ion production. The present work extends a previous parameterization of electromagnetically produced light ions, so that particle branching ratios are described more realistically.

  1. Biomass fast pyrolysis for bio-oil production in a fluidized bed reactor under hot flue atmosphere.

    PubMed

    Li, Ning; Wang, Xiang; Bai, Xueyuan; Li, Zhihe; Zhang, Ying

    2015-10-01

    Fast pyrolysis experiments of corn stalk were performed to investigate the optimal pyrolysis conditions of temperature and bed material for maximum bio-oil production under flue gas atmosphere. Under the optimized pyrolysis conditions, furfural residue, xylose residue and kelp seaweed were pyrolyzed to examine their yield distributions of products, and the physical characteristics of bio-oil were studied. The best flow rate of the flue gas at selected temperature is obtained, and the pyrolysis temperature at 500 degrees C and dolomite as bed material could give a maximum bio-oil yield. The highest bio-oil yield of 43.3% (W/W) was achieved from corn stalk under the optimal conditions. Two main fractions were recovered from the stratified bio-oils: light oils and heavy oils. The physical properties of heavy oils from all feedstocks varied little. The calorific values of heavy oils were much higher than that of light oils. The pyrolysis gas could be used as a gaseous fuel due to a relatively high calorific value of 6.5-8.5 MJ/m3. PMID:26964339

  2. Order has been restored to world oil production

    SciTech Connect

    Not Available

    1990-02-01

    This paper reports on the activities of OPEC during the past few years and on world oil production. The cartel has shown an increasing willingness to discipline itself and foster cooperation. Meanwhile, growth in world oil output during 1989 was much more in line with increases in global demand. World production averaged 59.62 MMbopd, a 2.2% gain over 1988's level.

  3. Mitigating Accidents In Oil And Gas Production Facilities

    NASA Astrophysics Data System (ADS)

    Johnsen, Stig

    Integrated operations are increasingly used in oil and gas production facilities to improve yields, reduce costs and maximize profits. They leverage information and communications technology (ICT) to facilitate collaboration between experts at widely dispersed locations. This paper discusses the safety and security consequences of implementing integrated operations for oil and gas production. It examines the increased accident risk arising from the tight coupling of complex ICT and SCADA systems, and proposes technological, organizational and human factors based strategies for mitigating the risk.

  4. Vegetable Oil from Leaves and Stems: Vegetative Production of Oil in a C4 Crop

    SciTech Connect

    2012-01-01

    PETRO Project: Arcadia Biosciences, in collaboration with the University of California-Davis, is developing plants that produce vegetable oil in their leaves and stems. Ordinarily, these oils are produced in seeds, but Arcadia Biosciences is turning parts of the plant that are not usually harvested into a source of concentrated energy. Vegetable oil is a concentrated source of energy that plants naturally produce and is easily separated after harvest. Arcadia Biosciences will isolate traits that control oil production in seeds and transfer them into leaves and stems so that all parts of the plants are oil-rich at harvest time. After demonstrating these traits in a fast-growing model plant, Arcadia Biosciences will incorporate them into a variety of dedicated biofuel crops that can be grown on land not typically suited for food production

  5. Bioprospecting for oil producing microalgal strains: evaluation of oil and biomass production for ten microalgal strains.

    PubMed

    Araujo, Glacio S; Matos, Leonardo J B L; Gonçalves, Luciana R B; Fernandes, Fabiano A N; Farias, Wladimir R L

    2011-04-01

    Microalgae have the ability to grow rapidly, synthesize and accumulate large amounts (approximately 20-50% of dry weight) of lipids. A successful and economically viable algae based oil industry depends on the selection of appropriate algal strains. In this study ten species of microalgae were prospected to determine their suitability for oil production: Chaetoceros gracilis, Chaetoceros mulleri, Chlorella vulgaris, Dunaliella sp., Isochrysis sp., Nannochloropsis oculata, Tetraselmis sp., Tetraselmis chui, Tetraselmis tetrathele and Thalassiosira weissflogii. The study was carried out in 3 L glass flasks subjected to constant aeration and controlled artificial illumination and temperature at two different salinities. After harvesting, the extraction of oil was carried out using the Bligh and Dyer method assisted by ultrasound. Results showed that C. gracilis presented the highest oil content and that C. vulgaris presented the highest oil production. PMID:21353534

  6. Method for controlling boiling point distribution of coal liquefaction oil product

    DOEpatents

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships. 3 figs.

  7. Method for controlling boiling point distribution of coal liquefaction oil product

    DOEpatents

    Anderson, Raymond P.; Schmalzer, David K.; Wright, Charles H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships.

  8. Lidar technologies application to leakage detection in oil product pipelines

    NASA Astrophysics Data System (ADS)

    Petoukhov, Valery M.; Petoukhova, Zaytuna K.; Akhtiamov, Rishad A.; Il'in, German I.; Morozov, Oleg G.; Pol'ski, Yuri E.

    1999-02-01

    Most of oil product pipelines have a design life from 20 till 25 years. The first attributes of their destruction are leakage of oil products. In our paper we try to discuss advantages and disadvantages of one of the main nondestructive techniques to oil product pipelines testing-- lidar technologies and its application to leakage detection. We consider applications of two basical lidars--IR-cw--LFM lidar (DIAL-system) for methane determining and pulsed lidar based on YAG:Nd3+ laser for registration of liquid oil products fluoristation. Set-ups for both lidars were made in Tupolev Kazan State Technical University and were used on the area of Sredne-Volgsk TransNefteProduct oil company for pipelines testing. Theoretical considerations and experimental results are presented. Some technical problems of specified lidars and their decisions are discussed. Particularly we present two frequency technique for He-Ne-DIAL-system and peculiarities of pumping source with high repetition range for pulsed laser. Its allow to improve characteristics of lidars. Possibilities of computerized leak detection system based on two specified lidars are discussed. It is shown that system can analyze leakage of different oil products, can determine leakage location (the second function of lidars-laser locator), can evaluate degree of damages. The structure of system and its peculiarities are shown.

  9. Production and pipeline transport of oil-water dispersions

    SciTech Connect

    Carniani, E.; Celsi, A.; Ercolani, D.

    1997-07-01

    Oil-water dispersions are becoming increasingly important for their potential application in the economical exploitation of heavy-oil fields and as novel fuels to be utilized for gasification in industrial power plants and in small heating systems. Snamprogetti in co-operation with Agip and Eniricerche is involved in a research project, partially supported by the Holding Company ENI and Europen Union (Thermie project), for the developing of a new integrated process to produce heavy crude oil from the marginal fields located in the Adriatic Sea as oil-water dispersions. The process scheme provides the multiphase pipeline transportation of the oil in reservoir water dispersion (primary dispersion) from the platform to the onshore processing Oil Centre for oil production and for the preparation of a very stable dispersion of oil in fresh water (secondary dispersion) to be utilized for direct burning. To obtain the necessary information for the design of the production, transportation and processing systems Snamprogetti has equipped a pilot plant to perform dispersion preparations and characterizations, single phase and multiphase transportation tests. The present work provides experimental data relevant to pumping tests of primary and secondary dispersions showing a stable flow configuration for the secondary and a tendency to stratification for the primary in certain flow conditions. During multiphase pumping tests of primary dispersions a markedly non-newtonian behavior has been observed when strong segregation phenomena occur. A comparison with results obtained by one-phase and multiphase flow programs is also presented.

  10. Rhagoletis cerasi: Oviposition Reduction Effects of Oil Products

    PubMed Central

    Daniel, Claudia

    2014-01-01

    The European cherry fruit fly, Rhagoletis cerasi (L.) (Diptera: Tephritidae), is a highly destructive pest. Methods to control it are limited and alternatives are needed. Observations of cherry fruit flies suggest that females exert much effort to penetrate cherries at color change stage (from green to yellow) for oviposition. Therefore, the question arose as to whether a physical barrier on the fruit surface could reduce oviposition. The effects of different commercial horticultural oil products on R. cerasi oviposition were evaluated in a series of laboratory, semi-field and field experiments. In the laboratory experiments, the rate of successful oviposition on fruits treated with 0.25% v/v of the rapeseed oil product Telmion was significantly reduced by 90% compared to the untreated control. In semi-field experiments, deposits of 1% of rapeseed, mineral and paraffinic oil significantly reduced oviposition for up to 3 days. Semi-field experiments indicated that the oil products lose efficacy within 3 to 6 days after application due to degradation. Although treatments with the rapeseed oil product Telmion reduced infestation rates in an on-farm field experiment, the infested fruit clearly exceeded the level of market tolerance of 2%. Further research is needed to assess whether combinations of oil products, higher application rates and different formulations might improve field efficacy. PMID:26462686

  11. The effect of alkaline additives on the performance of surfactant systems designed to recover light oils

    SciTech Connect

    French, T.R.; Josephson, C.B.; Evans, D.B.

    1991-02-01

    Surfactant flooding is flexible because of the ability to optimize formulations for a wide range of reservoir conditions and crude oil types. The objective for this work was to determine if the addition of alkaline additives will allow the design of surfactant formulations that are effective for the recovery of crude oil, while, at the same time, maintaining the surfactant concentration at a much lower level than has previously been used for micellar flooding. Specifically, the focus of the work was on light, midcontinent crudes that typically have very low acid contents. These oils are typical of much of the midcontinent resource. The positive effect of alkaline additives on the phase behavior of the surfactant formulations and acidic crude oils is well known. The extension to nonacidic and slightly acidic oils is not obvious. Three crude oils, a variety of commercial surfactants, and several alkaline additives were tested. The oils had acid numbers that ranged from 0.13, which is quite low, to less than 0.01 mg KOH/g of oil. Alkaline additives were found to be very effective in recovering Delaware-Childers (OK) oil at elevated temperatures, but much less effective at reservoir temperatures. Alkaline additives were very effective with Teapot Dome (WY) oil. With Teapot Dome oil, surfactant/alkali systems produced ultralow IFT values and recovered 60% of the residual oil that remained after waterflooding. The effect of alkaline additives on recovering Hepler (KS) oil was minimal. The results of this work indicate that alkaline additives do have merit for use in surfactant flooding of low acid crude oils; however, no universal statement about applicability can be made. Each oil behaves differently, with this treatment, and the effect of alkaline additives must be determined (at reservoir conditions) for each oil. 23 refs., 13 figs., 3 tabs.

  12. IR detector for hydrocarbons concentration measurement in emissions during petroleum and oil products storage and transportation

    NASA Astrophysics Data System (ADS)

    Vasilyev, Andrey O.; Shemanin, Valeriy G.; Chartiy, Pavel V.

    2011-10-01

    A double beam IR detector is developed for light hydrocarbons concentration measurement in emissions from storage vessels during oil and oil products storage and transportation. It was concluded on the basis of chromatogram that main crude losses from evaporation are the share of hydrocarbons light ends from methane to decane. Detector operation is based on spectral transparency measurement in the infrared spectra absorption range. Operational wavelength of infrared radiation makes 3.4 μm. measurement principle is based on concentration calculation proceed from molecule absorption cross-section, optical path length between light emitted diode and reference and signal photodiodes as well as from value of measured signal transmitted through gaging volume. The novel of offering device is an actual paraffin hydrocarbons concentration measurement in emissions and continuous and automatic environment quality control.

  13. Light quality and efficiency of consumer grade solid state lighting products

    NASA Astrophysics Data System (ADS)

    Dam-Hansen, Carsten; Corell, Dennis Dan; Thorseth, Anders; Poulsen, Peter Behrensdorff

    2013-03-01

    The rapid development in flux and efficiency of Light Emitting Diodes (LED) has resulted in a flooding of the lighting market with Solid State Lighting (SSL) products. Many traditional light sources can advantageously be replaced by SSL products. There are, however, large variations in the quality of these products, and some are not better than the ones they are supposed to replace. A lack of quality demands and standards makes it difficult for consumers to get an overview of the SSL products. Here the results of a two year study investigating SSL products on the Danish market are presented. Focus has been on SSL products for replacement of incandescent lamps and halogen spotlights. The warm white light and good color rendering properties of these traditional light sources are a must for lighting in Denmark and the Nordic countries. 266 SSL replacement lamps have been tested for efficiency and light quality with respect to correlated color temperature and color rendering properties. This shows a trade-off between high color rendering warm white light and energy efficiency. The lumen and color maintenance over time has been investigated and results for products running over 11000 h will be presented. A new internet based SSL product selection tool will be shown. Here the products can be compared on efficiency, light quality parameters, thus providing a better basis for the selection of SSL products for consumers.

  14. Analysis of vegetable oil production in central Iowa

    SciTech Connect

    Claar, P.W. II.; Colvin, T.S.; Marley, S.J.

    1982-01-01

    Vegetable oil can be used as an emergency substitute for diesel fuel for farming applications. This paper is an economic and energy analysis for vegetable oil production on a 180-ha (450-acre) central Iowa farm. The following data are presented as the basis for the economic analysis: (1) the yields of four varieties of sunflowers at three planting dates; (2) the measured sunflower harvesting losses-preharvest, header, threshing, and separating and cleaning for each variety and date of planting; and (3) the quantities of sunflower oil yielded from the pressing operation. Based on the data presented, it was concluded that even though a farmer could satisfatorily produce sunflowers, the on-farm processed sunflower oil does not compete with current diesel fuel prices. On-farm processed soybean oil has more potential as a substitute fuel from an economic standpoint in central Iowa. 8 tables.

  15. Peaking of world oil production: Impacts, mitigation, & risk management

    SciTech Connect

    Hirsch, R.L.; Bezdek, Roger; Wendling, Robert

    2005-02-01

    The peaking of world oil production presents the U.S. and the world with an unprecedented risk management problem. As peaking is approached, liquid fuel prices and price volatility will increase dramatically, and, without timely mitigation, the economic, social, and political costs will be unprecedented. Viable mitigation options exist on both the supply and demand sides, but to have substantial impact, they must be initiated more than a decade in advance of peaking.... The purpose of this analysis was to identify the critical issues surrounding the occurrence and mitigation of world oil production peaking. We simplified many of the complexities in an effort to provide a transparent analysis. Nevertheless, our study is neither simple nor brief. We recognize that when oil prices escalate dramatically, there will be demand and economic impacts that will alter our simplified assumptions. Consideration of those feedbacks will be a daunting task but one that should be undertaken. Our aim in this study is to-- • Summarize the difficulties of oil production forecasting; • Identify the fundamentals that show why world oil production peaking is such a unique challenge; • Show why mitigation will take a decade or more of intense effort; • Examine the potential economic effects of oil peaking; • Describe what might be accomplished under three example mitigation scenarios. • Stimulate serious discussion of the problem, suggest more definitive studies, and engender interest in timely action to mitigate its impacts.

  16. Biotechnological processes for biodiesel production using alternative oils.

    PubMed

    Azócar, Laura; Ciudad, Gustavo; Heipieper, Hermann J; Navia, Rodrigo

    2010-10-01

    As biodiesel (fatty acid methyl ester (FAME)) is mainly produced from edible vegetable oils, crop soils are used for its production, increasing deforestation and producing a fuel more expensive than diesel. The use of waste lipids such as waste frying oils, waste fats, and soapstock has been proposed as low-cost alternative feedstocks. Non-edible oils such as jatropha, pongamia, and rubber seed oil are also economically attractive. In addition, microalgae, bacteria, yeast, and fungi with 20% or higher lipid content are oleaginous microorganisms known as single cell oil and have been proposed as feedstocks for FAME production. Alternative feedstocks are characterized by their elevated acid value due to the high level of free fatty acid (FFA) content, causing undesirable saponification reactions when an alkaline catalyst is used in the transesterification reaction. The production of soap consumes the conventional catalyst, diminishing FAME production yield and simultaneously preventing the effective separation of the produced FAME from the glycerin phase. These problems could be solved using biological catalysts, such as lipases or whole-cell catalysts, avoiding soap production as the FFAs are esterified to FAME. In addition, by-product glycerol can be easily recovered, and the purification of FAME is simplified using biological catalysts. PMID:20697706

  17. CO2 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

    SciTech Connect

    Boomer, R.J.; Cole, R.; Kovar, M.; Prieditis, J.; Vogt, J.; Wehner, S.

    1999-02-24

    The application cyclic CO2, often referred to as the CO2 Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO2 Huff-n-Puff process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in capital-intensive miscible projects. Texaco Exploration and Production Inc. and the US Department of Energy have teamed up in a attempt to develop the CO2 Huff-n-Puff process in the Grayburg and San Andres formations which are light oil, shallow shelf carbonate reservoirs that exist throughout the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir.

  18. Method for creating high carbon content products from biomass oil

    DOEpatents

    Parker, Reginald; Seames, Wayne

    2012-12-18

    In a method for producing high carbon content products from biomass, a biomass oil is added to a cracking reactor vessel. The biomass oil is heated to a temperature ranging from about 100.degree. C. to about 800.degree. C. at a pressure ranging from about vacuum conditions to about 20,700 kPa for a time sufficient to crack the biomass oil. Tar is separated from the cracked biomass oil. The tar is heated to a temperature ranging from about 200.degree. C. to about 1500.degree. C. at a pressure ranging from about vacuum conditions to about 20,700 kPa for a time sufficient to reduce the tar to a high carbon content product containing at least about 50% carbon by weight.

  19. Effect of Light Crude Oil-Contaminated Soil on Growth and Germination of Festuca arundinacea

    NASA Astrophysics Data System (ADS)

    Minai-Tehrani, Dariush; Shahriari, Malek-Hossein; Savaghebi-Firoozabadi, Gholamreza

    In this study the effect of different concentrations of light crude oil (up to 10%) on the growth and germination of Festuca arundinacea (Tall fescue) was studied. Present results showed that the germination number and dry biomass of the plant decreased by increasing light crude oil concentration in the soil. The biomass was higher in 1% crude oil sample while it was lower in 10% crude oil sample. The length of leaves reduced in higher crude oil concentration in comparison with the control. Total and oil-degrading colony count of soil showed that the microbial population in 7 and 10% samples was higher than the control and low concentrations of crude oil (1 and 3% samples). The crude oil reduction in the vegetated and the non-vegetated samples was higher in 1% sample. All vegetated samples had higher crude oil reduction than non-vegetated samples. The higher reduction was occurred at 1% sample, while the lower reduction was seen at 10% sample.

  20. Deoxygenation of waste cooking oil and non-edible oil for the production of liquid hydrocarbon biofuels.

    PubMed

    Romero, M J A; Pizzi, A; Toscano, G; Busca, G; Bosio, B; Arato, E

    2016-01-01

    Deoxygenation of waste cooking vegetable oil and Jatropha curcas oil under nitrogen atmosphere was performed in batch and semi-batch experiments using CaO and treated hydrotalcite (MG70) as catalysts at 400 °C. In batch conditions a single liquid fraction (with yields greater than 80 wt.%) was produced containing a high proportion of hydrocarbons (83%). In semi-batch conditions two liquid fractions (separated by a distillation step) were obtained: a light fraction and an intermediate fraction containing amounts of hydrocarbons between 72-80% and 85-88% respectively. In order to assess the possible use of the liquid products as alternative fuels a complete chemical characterization and measurement of their properties were carried out. PMID:25869843

  1. Changes in the chemical components of light crude oil during simulated short term weathering

    NASA Astrophysics Data System (ADS)

    Ma, Qimin; Luo, Xia; Yu, Zhigang

    2007-07-01

    To unambiguously identify spilled oils and to link them to the known sources are extremely important in settling questions of environmental impact and legal liability. The fate and behavior of spilled oils in the environment depend on a number of physicochemical and biological factors. This paper presents the results regarding changes in chemical composition of light crude oil during simulated short-term weathering based on natural environmental conditions. The results show that the saturated hydrocarbons of the light crude oil mainly distribute between n-C8 and n-C23 and the most abundant n-alkanes are found in the n-C10 to n-C16. The main chemical components of the light crude oil are n-alkanes and isoprenoids. The aromatic compounds are subordinate chemical components. Under the conditions of the weathering simulation experiment, n-alkanes less than n-C12, toluene and 1,3-dimethyl benzene are lost after 1 d weathering, the n-C13, n-C14, naphthalene and 2-methyl-naphthalene are lost on the fifth day of weathering, and n-C15 alkane components show certain weatherproof capability. The ratios n-C17/pristane and n-C18/phytane are unaltered and can be used to identify the source of the light crude oil during the first 8 d of weathering. After 21 d, the ratio pristine/phytane can not provide much information on the source of the spilled light crude oil. Triterpanes (m/z 191) as biomarker compounds of light crude oil are more valuable.

  2. Conversion of crude oil to methane by a microbial consortium enriched from oil reservoir production waters

    PubMed Central

    Berdugo-Clavijo, Carolina; Gieg, Lisa M.

    2014-01-01

    The methanogenic biodegradation of crude oil is an important process occurring in petroleum reservoirs and other oil-containing environments such as contaminated aquifers. In this process, syntrophic bacteria degrade hydrocarbon substrates to products such as acetate, and/or H2 and CO2 that are then used by methanogens to produce methane in a thermodynamically dependent manner. We enriched a methanogenic crude oil-degrading consortium from production waters sampled from a low temperature heavy oil reservoir. Alkylsuccinates indicative of fumarate addition to C5 and C6 n-alkanes were identified in the culture (above levels found in controls), corresponding to the detection of an alkyl succinate synthase encoding gene (assA/masA) in the culture. In addition, the enrichment culture was tested for its ability to produce methane from residual oil in a sandstone-packed column system simulating a mature field. Methane production rates of up to 5.8 μmol CH4/g of oil/day were measured in the column system. Amounts of produced methane were in relatively good agreement with hydrocarbon loss showing depletion of more than 50% of saturate and aromatic hydrocarbons. Microbial community analysis revealed that the enrichment culture was dominated by members of the genus Smithella, Methanosaeta, and Methanoculleus. However, a shift in microbial community occurred following incubation of the enrichment in the sandstone columns. Here, Methanobacterium sp. were most abundant, as were bacterial members of the genus Pseudomonas and other known biofilm forming organisms. Our findings show that microorganisms enriched from petroleum reservoir waters can bioconvert crude oil components to methane both planktonically and in sandstone-packed columns as test systems. Further, the results suggest that different organisms may contribute to oil biodegradation within different phases (e.g., planktonic vs. sessile) within a subsurface crude oil reservoir. PMID:24829563

  3. NEXT GENERATION ENERGY EFFICIENT FLUORESCENT LIGHTING PRODUCT

    SciTech Connect

    Alok Srivastava; Anant Setlur

    2003-04-01

    This is the Final Report of the Next-Generation Energy Efficient Fluorescent Lighting Products program, Department of Energy (DOE). The overall goal of this three-year program was to develop novel phosphors to improve the color rendition and efficiency of compact and linear fluorescent lamps. The prime technical approach was the development of quantum-splitting phosphor (QSP) to further increase the efficiency of conventional linear fluorescent lamps and the development of new high color rendering phosphor blends for compact fluorescent lamps (CFLs) as potential replacements for the energy-hungry and short-lived incandescent lamps in market segments that demand high color rendering light sources. We determined early in the project that the previously developed oxide QSP, SrAl{sub 12}O{sub 19}:Pr{sup 3+}, did not exhibit an quantum efficiency higher than unity under excitation by 185 nm radiation, and we therefore worked to determine the physical reasons for this observation. From our investigations we concluded that the achievement of quantum efficiency exceeding unity in SrAl{sub 12}O{sub 19}:Pr{sup 3+} was not possible due to interaction of the Pr{sup 3+} 5d level with the conduction band of the solid. The interaction which gives rise to an additional nonradiative decay path for the excitation energy is responsible for the low quantum efficiency of the phosphor. Our work has led to the development of a novel spectroscopic method for determining photoionzation threshold of luminescent centers in solids. This has resulted in further quantification of the requirements for host phosphor lattice materials to optimize quantum efficiency. Because of the low quantum efficiency of the QSP, we were unable to demonstrate a linear fluorescent lamp with overall performance exceeding that of existing mercury-based fluorescent lamps. Our work on the high color rendering CFLs has been very successful. We have demonstrated CFLs that satisfies the EnergyStar requirement with color

  4. Utilization of papaya waste and oil production by Chlorella protothecoides

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Algae derived oils have outstanding potential for use in biodiesel production. Chlorella protothecoides has been shown to accumulate lipid up to 60% of its cellular dry weight with glucose supplementation under heterotrophic growth conditions. To reduce production costs, alternative carbon feedstock...

  5. Oil production by Candida curvata and extraction, composition and properties of the oil

    SciTech Connect

    Hammond, E.G.; Glatz, B.A.; Choi, Y.; Teasdale, M.T.

    1981-01-01

    A strain of the yeast C. curvata was grown in cheese whey permeate under conditions that allowed for oil production. The N-C ratio of the fermentation medium influenced the amount of oil produced. Concentrated permeate could be used as a substrate, but the efficiency of conversion to oil was reduced. The yeast grew well and produced oil in several different types of whey and milk permeates and also in nonsterile systems. The lipid of C. curvata amounted to approximately 50% of its dry weight and could be extracted by sequential treatment with ethanol, hexane, and benzene. The extraction with benzene was necessary for good yields even though nearly all the material extracted with benzene was soluble in hexane. The lipid was 80-90% triglyceride, contained little free fatty acid, and could be degummed by traditional methods. The triglyceride was 30.4% palmitic, 0.84% palmitoleic acid, 11.4% stearic, 51.0% oleic, 6.2% linoleic, and 0.4% linolenic acid. The saturated acyl groups were almost completely on the sn-1 and 3 positions of the glycerol. The oil melting point was -10 to 22 degrees. No tocopherol was detected and the oil oxidized at a rate similar to that for soybean oil at 55 degrees. The oil contained a variety of linear hydrocarbons and 4 sterols. The polar lipids include phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, and phosphatidic acid.

  6. Past, Present, and Future Production of Bio-oil

    SciTech Connect

    Steele, Philip; Yu, Fei; Gajjela, Sanjeev

    2009-04-01

    Bio-oil is a liquid product produced by fast pyrol-ysis of biomass. The fast pyrolysis is performed by heating the biomass rapidly (2 sec) at temperatures ranging from 350 to 650 oC. The vapors produced by this rapid heating are then condensed to produce a dark brown water-based emulsion composed of frag-ments of the original hemicellulose, cellulose and lignin molecules contained in the biomass. Yields range from 60 to 75% based on the feedstock type and the pyrolysis reactor employed. The bio-oil pro-duced by this process has a number of negative prop-erties that are produced mainly by the high oxygen content (40 to 50%) contributed by that contained in water (25 to 30% of total mass) and oxygenated compounds. Each bio-oil contains hundreds of chemi-cal compounds. The chemical composition of bio-oil renders it a very recalcitrant chemical compound. To date, the difficulties in utilizing bio-oil have limited its commercial development to the production of liq-uid smoke as food flavoring. Practitioners have at-tempted to utilize raw bio-oil as a fuel; they have also applied many techniques to upgrade bio-oil to a fuel. Attempts to utilize raw bio-oil as a combustion engine fuel have resulted in engine or turbine dam-age; however, Stirling engines have been shown to successfully combust raw bio-oil without damage. Utilization of raw bio-oil as a boiler fuel has met with more success and an ASTM standard has recently been released describing bio-oil characteristics in relation to assigned fuel grades. However, commercialization has been slow to follow and no reports of distribution of these bio-oil boiler fuels have been reported. Co-feeding raw bio-oil with coal has been successfully performed but no current power generation facilities are following this practice. Upgrading of bio-oils to hydrocarbons via hydroprocessing is being performed by several organizations. Currently, limited catalyst life is the obstacle to commercialization of this tech-nology. Researchers

  7. Integrated Use of Fluidized Bed Technology for Oil Production from Oil Shale

    NASA Astrophysics Data System (ADS)

    Siirde, Andres; Martins, Ants

    The plant unit which consists of a fluidized bed retort and CFB furnace for burning the by-products of retorting (semicoke and semicoke gas) is presented in this paper. The oil shale retort consists of a fast fluidized bed shaft, coarse semicoke bit, semicoke separation chamber and cyclone for the separation of fine semicoke particles. The crashed oil shale and hot ash from the CFB ash separator are fed concurrently into the fast fluidized bed shaft. For fluidizing the mixture of oil shale and hot ash particles, the recycle semicoke gas is used. The pyrolysis of oil shale begins in fluidized bed and is completed in the semicoke separation chamber. The coarse semicoke particles are separated from fluidized bed directly while the medium size particles are separated from the gases in the semicoke separation chamber and the finest semicoke particles in the cyclone. All the fractions of semicoke from the fluidized bed retort and semicoke gas from the oil fractionator are burnt in the CFB furnace. The semicoke ash is separated from flue gases in the CFB ash separator. A part of separated hot ash is fed into the fluidized bed retort as a solid heat carrier material and the rest into the furnace through the ash cooler or separated from the process. The retention of sulphur dioxide formed during the semicoke and semicoke gas combustion, is guaranteed for about 99 % due to the high CaO content in the semicoke ash and convenient temperature (about 850°C) in the CFB furnace. The described plant unit is useful for retorting oil shale and other solid hydrocarbon-containing fuels. The advantages of the present retorting process and system are: improved oil yield, greater throughput, lower retorting time, avoidance of moving parts in the retorting zones, reduced downtime, etc. A new plant unit for oil shale oil production has been elaborated and defended by the Estonian Utility Model EE 200700671 UI.

  8. Environmental effects of offshore oil production

    SciTech Connect

    Middletich, B.S.

    1981-01-01

    The papers deal with two major categories of oil field impacts: hydrocarbon and sulfur discharges from producing platforms; and the effects of the structures themselves in the marine environment. The studies can also be broken down into those that deal with the fate of the polluting discharges (dispersion, degradation, consumption); and those that deal with the affected organisms themselves. Some studies used control sites to compare effects near the platforms. Others analyzed composition, density, and quality of organisms throughout the field, offering comparisons between control sites and oil field sites. The presence of pollutants in particulates was studied and measured. Effectiveness of degradation of petro pollutants by bacteria is also examined. Biocides used in the working stream to control sulfur oxidizing bacteria were treated briefly. Effects of the structures and potential pollution was also described for the fouling community, i.e., barnacles, etc. Effects of the presence of the structures on migratory and resident birds are examined for hundreds of species constantly using the area as a fly-way or habitat.

  9. Light Penetration in Seawater Polluted by Dispersed Oil: Results of Radiative Transfer Modelling

    NASA Astrophysics Data System (ADS)

    Haule, K.; Darecki, M.; Toczek, H.

    2015-11-01

    The downwelling light in seawater is shaped by natural seawater constituents as well as by some external substances which can occur locally and temporally. In this study we focused on dispersed oil droplets which can be found in seawater after an oil spill or in the consequence of intensive shipping, oil extraction and transportation. We applied our modified radiative transfer model based on Monte Carlo code to evaluate the magnitude of potential influence of dispersed oil droplets on the downwelling irradiance and the depth of the euphotic zone. Our model was validated on the basis of in situ measurements for natural (unpolluted) seawater in the Southern Baltic Sea, resulting in less than 5% uncertainty. The optical properties of dispersed Petrobaltic crude oil were calculated on the basis of Mie theory and involved into radiative transfer model. We found that the changes in downwelling light caused by dispersed oil depend on several factors such as oil droplet concentration, size distribution, and the penetration depth (i.e. vertical range of oil droplets occurrence below sea surface). Petrobaltic oil droplets of submicron sizes and penetration depth of 5 m showed a potentially detectable reduction in the depth of the euphotic zone of 5.5% at the concentration of only 10 ppb. Micrometer-sized droplets needed 10 times higher concentration to give a similar effect. Our radiative transfer model provided data to analyse and discuss the influence of each factor separately. This study contributes to the understanding of the change in visible light penetration in seawater affected by dispersed oil.

  10. The carcinogenic initiating and promoting properties of a lightly refined paraffinic oil.

    PubMed

    McKee, R H; Plutnick, R T; Przygoda, R T

    1989-05-01

    The dermal carcinogenic potential of some petroleum-derived liquids is related to the polycyclic aromatic hydrocarbon (PAH) content. However, repeated application of middle distillates (MDs), e.g., kerosene, diesel fuel, and heating oil, produced tumors in mouse skin. This result was unexpected since the MDs typically contain very low levels of biologically active PAHs. The present study examined the tumorigenic mechanism of a lightly refined paraffinic oil (LRPO), an MD shown to be active in mouse skin. The LRPO was separated into saturated and aromatic fractions. Whole LRPO and various fractions were tested for mutagenic activity in the Salmonella assay and for carcinogenic initiating and promoting activity. There was no evidence that any of the samples examined were mutagenic in bacteria or carcinogenic initiating agents in mouse skin. Thus no support was provided for the hypothesis that the complete tumorigenic activity of LRPO was in any way related to the presence of low levels of PAHs or to an interaction between initiating and promoting constituents. There was evidence that LRPO was a weak promoter of dimethylbenzanthracene (DMBA)-initiated mouse skin. It was also found that repeated application of LRPO produced chronic irritation and hyperplasia, and this may have been responsible for the promotional effects. Based on these data, it seemed likely that the complete carcinogenic activity of this class of products is also the result of an epigenetic process related to skin irritation. PMID:2663578

  11. Recent Trends in Water Use and Production for California Oil Production.

    PubMed

    Tiedeman, Kate; Yeh, Sonia; Scanlon, Bridget R; Teter, Jacob; Mishra, Gouri Shankar

    2016-07-19

    Recent droughts and concerns about water use for petroleum extraction renew the need to inventory water use for oil production. We quantified water volumes used and produced by conventional oil production and hydraulic fracturing (HF) in California. Despite a 25% decrease in conventional oil production from 1999 to 2012, total water use increased by 30% though much of that increase was derived from reuse of produced water. Produced water volumes increased by 50%, with increasing amounts disposed in unlined evaporation ponds or released to surface water. Overall freshwater use (constituting 1.2% of the state's nonagricultural water consumption) increased by 46% during this period due to increased freshwater-intensive tertiary oil production. HF has been practiced in California for more than 30 years, accounting for 1% of total oil production in 2012 from mostly directional and vertical wells. Water use intensity for HF wells in California averaged at 3.5 vol water/vol oil production in 2012 and 2.4 vol/vol in 2013, higher than the range from literature estimates and net water use intensity of conventional production (1.2 vol/vol in 2012). Increasing water use and disposal for oil production have important implications for water management and have potentially adverse health, environmental, and ecological impacts. PMID:27175896

  12. Consumption of tomato products with olive oil but not sunflower oil increases the antioxidant activity of plasma.

    PubMed

    Lee, A; Thurnham, D I; Chopra, M

    2000-11-15

    Health benefits of lycopene from tomato products have been suggested to be related to its antioxidant activity. Dietary fat may influence the absorption and hence the plasma levels and antioxidant activity of lycopene. In the present study, we have compared the effect of consumption of tomato products with extra-virgin olive oil vs. tomato products plus sunflower oil on plasma lycopene and antioxidant levels. Results show that the oil composition does not affect the absorption of lycopene from tomato products because similar levels of plasma lycopene (mean +/- SD) were obtained on feeding tomatoes (providing approximately 46 mg lycopene/d) for 7 d with either olive oil (0.66 +/- 0.26 vs 1.20 +/- 0.20 micromol/l, p <.002) or sunflower oil (0.67 +/- 0.27 vs. 1.14 micromol/l, p <.001). However, consumption of tomato products with olive oil significantly raised the plasma antioxidant activity (FRAP) from 930 +/- 150 to 1118 +/- 184 micromol/l, p <.01) but no effect was observed when the sunflower oil was used. The change (supplementation minus start values) in FRAP following the consumption of tomato products with oil was significantly higher for olive oil (190 +/- 101) than for sunflower oil (-9.6 +/- 99, p <. 005). In conclusion, the results of the study show that consumption of tomato products with olive oil but not with sunflower oil improves the antioxidant activity of the plasma. PMID:11084294

  13. Scenedesmus dimorphus biofilm: Photoefficiency and biomass production under intermittent lighting

    PubMed Central

    Toninelli, Andrea Efrem; Wang, Junfeng; Liu, Mingshen; Wu, Hong; Liu, Tianzhong

    2016-01-01

    This study investigated the effect of intermittent lighting on the growth performances of a Scenedesmus dimorphus biofilm. Flashing light effect (FLE) is common in traditional suspended cultures of microalgae; yet, publications about this phenomenon, in the context of biofilm cultivation, are scarce. In this work we demonstrate that, thanks to intermittent illumination, it is possible for attached cultivations to fulfill FLE, improve photoefficiency and productivity as well as providing protection from photoinhibition using much lower flashing light frequencies than those usually required with suspended cultures. Medium frequency intermittent lighting (0.1 Hz) guaranteed excellent light integration resulting in 9.13 g m−2 d−1 biomass productivity, which was 8.9% higher than with continuous lighting. Results showed that a light fraction value of 0.5 always improved photoefficiency values as related to continuous light with a 118.8% maximum increase. PMID:27561323

  14. Scenedesmus dimorphus biofilm: Photoefficiency and biomass production under intermittent lighting.

    PubMed

    Toninelli, Andrea Efrem; Wang, Junfeng; Liu, Mingshen; Wu, Hong; Liu, Tianzhong

    2016-01-01

    This study investigated the effect of intermittent lighting on the growth performances of a Scenedesmus dimorphus biofilm. Flashing light effect (FLE) is common in traditional suspended cultures of microalgae; yet, publications about this phenomenon, in the context of biofilm cultivation, are scarce. In this work we demonstrate that, thanks to intermittent illumination, it is possible for attached cultivations to fulfill FLE, improve photoefficiency and productivity as well as providing protection from photoinhibition using much lower flashing light frequencies than those usually required with suspended cultures. Medium frequency intermittent lighting (0.1 Hz) guaranteed excellent light integration resulting in 9.13 g m(-2) d(-1) biomass productivity, which was 8.9% higher than with continuous lighting. Results showed that a light fraction value of 0.5 always improved photoefficiency values as related to continuous light with a 118.8% maximum increase. PMID:27561323

  15. Studies of Terminalia catappa L. oil: characterization and biodiesel production.

    PubMed

    Dos Santos, I C F; de Carvalho, S H V; Solleti, J I; Ferreira de La Salles, W; Teixeira da Silva de La Salles, K; Meneghetti, S M P

    2008-09-01

    Since the biodiesel program has been started in Brazil, the investigation of alternative sources of triacylglycerides from species adapted at semi-arid lands became a very important task for Brazilian researchers. Thus we initiated studies with the fruits of the Terminalia catappa L (TC), popularly known in Brazil as "castanhola", evaluating selected properties and chemical composition of the oil, as well any potential application in biodiesel production. The oil was obtained from the kernels of the fruit, with yields around 49% (% mass). Also, its fatty acid composition was quite similar to that of conventional oils. The crude oil of the TC was transesterified, using a conventional catalyst and methanol to form biodiesel. The studied physicochemical properties of the TC biodiesel are in acceptable range for use as biodiesel in diesel engines. PMID:18178081

  16. Environmental Compliance for Oil and Gas Exploration and Production

    SciTech Connect

    Hansen, Christine

    1999-10-26

    The Appalachian/Illinois Basin Directors is a group devoted to increasing communication among the state oil and gas regulatory agencies within the Appalachian and Illinois Basin producing region. The group is comprised of representatives from the oil and gas regulatory agencies from states in the basin (Attachment A). The directors met to discuss regulatory issues common to the area, organize workshops and seminars to meet the training needs of agencies dealing with the uniqueness of their producing region and perform other business pertinent to this area of oil and gas producing states. The emphasis of the coordinated work was a wide range of topics related to environmental compliance for natural gas and oil exploration and production.

  17. [Determination of aromatics in light petroleum products by comprehensive two-dimensional gas chromatography].

    PubMed

    Li, Yanyan

    2006-07-01

    In recent years, comprehensive two-dimensional gas chromatography (GC x GC) have been used widely, and the applications of this technique to many fields have already been reported. In the standard method of oil analysis, the concentrations of aromatics and naphthalene hydrocarbons in light petroleum products must be detected by more than two methods. Mono-aromatics, di-aromatics etc. in light petroleum products were detected only by comprehensive two-dimensional gas chromatography. After the proper selection of column system and optimization of chromatographic conditions, the method can achieve the group separations of paraffins, olefins, naphthenes, aromatics with 1 to 2 rings and some target components in light petroleum products with good reproducibility and good precision. The recoveries of standard compounds were 89.5% - 106.1%, and the relative standard deviations of repeatedly detecting the components were all lower than 5.8%. It took only 30 min to finish a determination. PMID:17017165

  18. Optimization of alkaline transesterification of soybean oil and castor oil for biodiesel production.

    PubMed

    de Oliveira, Débora; Di Luccio, Marco; Faccio, Carina; Dalla Rosa, Clarissa; Bender, João Paulo; Lipke, Nádia; Amroginski, Cristiana; Dariva, Cláudio; de Oliveira, José Vladimir

    2005-01-01

    This article reports experimental data on the production of fatty acid ethyl esters from refined and degummed soybean oil and castor oil using NaOH as catalyst. The variables investigated were temperature (30-70 degrees C), reaction time (1-3 h), catalyst concentration (0.5-1.5 w/wt%), and oil-to-ethanol molar ratio (1:3-1:9). The effects of process variables on the reaction conversion as well as the optimum experimental conditions are presented. The results show that conversions >95% were achieved for all systems investigated. In general, an increase in reaction temperature, reaction time, and in oil-to-ethanol molar ratio led to an enhancement in reaction conversion, whereas an opposite trend was verified with respect to catalyst concentration. PMID:15920262

  19. Carbonyl Emissions From Oil and Gas Production Facilities

    NASA Astrophysics Data System (ADS)

    Lyman, S. N.; O'Neil, T.; Tran, T.

    2015-12-01

    A number of recent studies have targeted emissions of methane and other hydrocarbons from oil and gas exploration and production activity. These measurements are greatly increasing understanding of the atmospheric impacts of oil and gas development. Very few measurements exist, however, of emissions of formaldehyde and other carbonyls from oil and gas equipment. Carbonyls are toxic and serve as important ozone precursors, especially during winter ozone episodes in places like Utah's Uintah Basin. Current air quality models are only able to reproduce observed high wintertime ozone if they incorporate emissions inventories with very high carbonyl emissions. We measured carbonyl emissions from oil and gas equipment and facilities—including glycol dehydrators, liquid storage tanks, raw gas leaks, raw gas-burning engines, and produced water surface impoundments—in Rocky Mountain oil and gas fields. Carbonyl emissions from raw gas were below detection, but emissions of formaldehyde, acetaldehyde, and other carbonyls were detected from liquid storage tanks, glycol dehydrators, and other oil and gas equipment. In some cases, carbonyls may be formed from the degradation of methanol and other chemicals used in oil and gas production, but the collected data provide evidence for other non-combustion formation pathways. Raw gas-burning engines also emitted carbonyls. Emissions from all measured sources were a small fraction of total volatile organic compound emissions. We incorporated our measurements into an emissions inventory, used that inventory in an air quality model (WRF-SMOKE-CAMx), and were unable to reproduce observed high wintertime ozone. This could be because (1) emission sources we have not yet measured, including compressors, gas processing plants, and others, are large; (2) non-carbonyl emissions, especially those that quickly degrade into carbonyls during photochemical processing, are underestimated in the inventory; or (3) the air quality model is unable

  20. Relating productivity to visibility and lighting

    SciTech Connect

    Clear, R.; Berman, S.

    1982-01-01

    The problem of determining the appropriate light levels for visual tasks is a cost-benefit problem. Existing light level recommendations seriously underweight the importance of economic factors. Furthermore, the relative importance of the visibility factors in determining the optimal light levels appears inconsistent with the importance of these factors in determining visibility and visual performance. It is shown that calculations based on acuities give a lower limit of 100 to 200 lux for cost-effective light levels for office tasks. Upper limits are calculated from correlations of task performance to visibility levels. Visibility levels become progressively insensitive to luminance as luminance increases. Average power densities above 100 watts/m/sup 2/ are cost-effective only when visibility is very low. However, there is a 3-to-10 times larger increase in benefits from improving contrast or contrast sensitivity than from using more than 10 watts/m/sup 2/. Contrast or contrast sensitivity can be improved by using forms with larger print, using xerographic copy instead of carbon or mimeo, making sure office workers have the right eyeglasses, or even by transferring workers with visual problems to less visually demanding tasks. Once these changes are made it is no longer cost-effective to use more than 10 watts/m/sup 2/. This conclusion raises serious questions about recommendations that lead to greater than about 10 watts/m/sup 2/ of installed lighting for general office work.

  1. Lipase production by Penicillium restrictum using solid waste of industrial babassu oil production as substrate.

    PubMed

    Palma, M B; Pinto, A L; Gombert, A K; Seitz, K H; Kivatinitz, S C; Castilho, L R; Freire, D M

    2000-01-01

    Lipase, protease, and amylase production by Penicillium restrictum in solid-state fermentation was investigated. The basal medium was an industrial waste of babassu oil (Orbignya oleifera) production. It was enriched with peptone, olive oil, and Tween-80. The supplementation positively influenced both enzyme production and fungal growth. Media enriched with Tween-80 provided the highest protease activity (8.6 U/g), whereas those enriched with peptone and olive oil led to the highest lipase (27.8 U/g) and amylase (31.8 U/g) activities, respectively. PMID:10849864

  2. Catalytic applications in the production of biodiesel from vegetable oils.

    PubMed

    Sivasamy, Arumugam; Cheah, Kien Yoo; Fornasiero, Paolo; Kemausuor, Francis; Zinoviev, Sergey; Miertus, Stanislav

    2009-01-01

    The predicted shortage of fossil fuels and related environmental concerns have recently attracted significant attention to scientific and technological issues concerning the conversion of biomass into fuels. First-generation biodiesel, obtained from vegetable oils and animal fats by transesterification, relies on commercial technology and rich scientific background, though continuous progress in this field offers opportunities for improvement. This review focuses on new catalytic systems for the transesterification of oils to the corresponding ethyl/methyl esters of fatty acids. It also addresses some innovative/emerging technologies for the production of biodiesel, such as the catalytic hydrocracking of vegetable oils to hydrocarbons. The special role of the catalyst as a key to efficient technology is outlined, together with the other important factors that affect the yield and quality of the product, including feedstock-related properties and various system conditions. PMID:19360707

  3. Biodiesel fuel production by transesterification of oils.

    PubMed

    Fukuda, H; Kondo, A; Noda, H

    2001-01-01

    Biodiesel (fatty acid methyl esters), which is derived from triglycerides by transesterification with methanol, has attracted considerable attention during the past decade as a renewable, biodegradable, and nontoxic fuel. Several processes for biodiesel fuel production have been developed, among which transesterification using alkali-catalysis gives high levels of conversion of triglycerides to their corresponding methyl esters in short reaction times. This process has therefore been widely utilized for biodiesel fuel production in a number of countries. Recently, enzymatic transesterification using lipase has become more attractive for biodiesel fuel production, since the glycerol produced as a by-product can easily be recovered and the purification of fatty methyl esters is simple to accomplish. The main hurdle to the commercialization of this system is the cost of lipase production. As a means of reducing the cost, the use of whole cell biocatalysts immobilized within biomass support particles is significantly advantageous since immobilization can be achieved spontaneously during batch cultivation, and in addition, no purification is necessary. The lipase production cost can be further lowered using genetic engineering technology, such as by developing lipases with high levels of expression and/or stability towards methanol. Hence, whole cell biocatalysts appear to have great potential for industrial application. PMID:16233120

  4. Scaling properties of light-cluster production

    NASA Astrophysics Data System (ADS)

    Chajecki, Zbigniew; Youngs, Michael; Coupland, Daniel D.; Lynch, William; Tsang, Betty; Chbihi, Abdelouahad; Danielewicz, Pawel; Desouza, Romualdo; Famiano, Michael; Ghosh, Tilak; Giacherio, B.; Henzl, Vlad; Henzlova, Daniela; Hudan, Sylvie; Kilburn, Micha; Lee, Jenny; Lu, Fei; Rogers, Andrew; Russotto, Paulo; Verde, Giuseppe; Sanetullaev, Alisher; Showalter, Rachel; Sobotka, Lee; Wallace, Mark; Winkelbauer, Jack

    2014-09-01

    We show, using the experimental data from Ca+Ca and Sn+Sn collisions, that ratios of light-particle energy spectra display scaling properties that can be accurately described by effective local chemical potentials. This demonstrates the equivalence of t/3He and n/p spectral ratios and provides an essential test of theoretical predictions of isotopically resolved light-particle spectra. In addition, this approach allows direct comparisons of many theoretical n/p spectral ratios to experiments where charged-particle spectra but not neutron spectra are accurately measured. Such experiments may provide much more quantitative constraints on the density and momentum dependence of the symmetry energy.

  5. Evaluating oil quality and monitoring production from heavy oil reservoirs using geochemical methods: Application to the Boscan Field, Venezuela

    SciTech Connect

    Kaufman, R.L.; Noguera, V.H.; Bantz, D.M.; Rodriguez, R.

    1996-08-01

    Many oil fields worldwide contain heavy oil in one or more reservoir units. The low gravity of these oils is most frequently due to biodegradation and/or low maturity. The challenge is to find ways to economically recover this oil. Methods which reduce the operating costs of producing heavy oil add significant value to such projects. Geochemical techniques which use the composition of the reservoir fluids as natural tracers offer cost effective methods to assist with reservoir management. The low viscosity and gravity of heavy oil, combined with frequent high water cuts, low flow rates, and the presence of downhole artificial lift equipment, make many conventional production logging methods difficult to apply. Therefore, monitoring production, especially if the produced oil is commingled from multiple reservoirs, can be difficult. Geochemical methods can be used to identify oil/water contacts, tubing string leaks and to allocate production to individual zones from commingled production. An example of a giant heavy oil field where geochemical methods may be applicable is the Boscan Field in Venezuela. Low maturity oil, averaging 10{degrees} API gravity, is produced from the Eocene Upper and Lower Boscan (Miosa) Sands. Geochemical, stratigraphic and engineering data have helped to better define the controls on oil quality within the field, identified new reservoir compartments and defined unique characteristics of the Upper and Lower Boscan oils. This information can be used to identify existing wells in need of workovers due to mechanical problems and to monitor production from new infill wells.

  6. Low-rank coal oil agglomeration product and process

    DOEpatents

    Knudson, C.L.; Timpe, R.C.; Potas, T.A.; DeWall, R.A.; Musich, M.A.

    1992-11-10

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-degradable, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  7. Low-rank coal oil agglomeration product and process

    DOEpatents

    Knudson, Curtis L.; Timpe, Ronald C.; Potas, Todd A.; DeWall, Raymond A.; Musich, Mark A.

    1992-01-01

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-decrepitating, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  8. Production of crude oils in Pakistan: Outlook for the future

    SciTech Connect

    Ahmad, S.

    1995-12-31

    Pakistan`s sedimentary basins cover an area of 827,000 km{sub 2} that stretches from the Karakurum Mountains in the north to the Arabian Sea in the south. The first exploration well in the region was drilled near Kundal in 1866, just seven years after the Drake well in Pennsylvania. To date, 384 exploration wells have been drilled in Pakistan resulting in 45 oil and 55 gas discoveries, thus generating a highly favourable success ratio of 1:4. The drilling density in Pakistan is one well/1000 square kilometers. Pakistan has proven oil reserves of around 500 million barrels of oil, whereas proven gas reserves are about 31 trillion cubic feet. However, Pakistan`s resource potential is estimated to be 40 billion barrels of oil and 200 TCF of gas. The purpose of this paper is to describe: (i) habitat and production of crude oil in Pakistan, (ii) Pakistan`s current energy needs and future outlook, and (iii) steps being taken by the Government of Pakistan to promote exploration for oil and gas.

  9. Development and field testing of a Light Aircraft Oil Surveillance System (LAOSS)

    NASA Technical Reports Server (NTRS)

    Burns, W.; Herz, M. J.

    1976-01-01

    An experimental device consisting of a conventional TV camera with a low light level photo image tube and motor driven polarized filter arrangement was constructed to provide a remote means of discriminating the presence of oil on water surfaces. This polarized light filtering system permitted a series of successive, rapid changes between the vertical and horizontal components of reflected polarized skylight and caused the oil based substances to be more easily observed and identified as a flashing image against a relatively static water surface background. This instrument was flight tested, and the results, with targets of opportunity and more systematic test site data, indicate the potential usefulness of this airborne remote sensing instrument.

  10. Integrating Sunflower Oil Seed Crops into Florida Horticultural Production Systems

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Locally produced biodiesel feedstock plant oil creates a unique possibility to integrate multiple-goal oriented cover crops into Florida horticultural production systems. Typically, cover crops are planted to improve soil fertility and the natural suppression of soilborne pests at times when fields...

  11. A Computer-Assisted Oil Exploration and Production Game.

    ERIC Educational Resources Information Center

    Nichols, Gary John

    1987-01-01

    Describes a computer-assisted oil exploration and production game for students involved in a short course in petroleum geology. Outlines the game and its procedures, and provides sample structure maps generated by the computer in the course of playing the game. (TW)

  12. Production and properties of biodiesel from algal oils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biodiesel is an alternative to petroleum-based conventional diesel fuel (petrodiesel). A major issue facing biodiesel is sufficient supply of feedstock to replace significant amounts of petrodiesel. This issue has caused a search for sources of triacylglycerol-based oils with high production poten...

  13. ASSESSMENT OF OIL PRODUCTION VOLATILE ORGANIC COMPOUND SOURCES

    EPA Science Inventory

    An extensive description of oil and gas exploration and production drilling technology is presented. Emphasis has been placed on the makeup, use, and disposal of drilling fluids. A simple model for assessment of VOC emissions accompanying drilling is presented, along with an esti...

  14. Develop a New Lesquerella fendleri Crop for Castor Oil Production

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Seed oil of Lesquerella fendleri contains a valuable hydroxy fatty acid (HFA), lesquerolic acid (20:1OH). The conventional source of HFA is ricinoleic acid (18:1OH) from castor seeds. Ricinoleic acid and its derivatives are used as raw materials for numerous industrial products, such as lubricants, ...

  15. Enzymatic hydrolysis of fractionated products from oil thermally oxidated

    SciTech Connect

    Yashida, H.; Alexander, J.C.

    1983-01-01

    Enzymatic hydrolysis of the acylglycerol products obtained from thermally oxidized vegetable oils was studied. Corn, sunflower and soybean oils were heated in the laboratory at 180/sup 0/C for 50, 70 and 100 hr with aeration and directly fractionated by silicic acid column chromatography. By successive elution with 20%, then 60% isopropyl ether in n-hexane, and diethyl ether, the thermally oxidized oils were separated into three fractions: the nonpolar fraction (monomeric compounds), slightly polar fraction (dimeric compounds), and polar fraction comprising oligomeric compounds. Enzymatic hydrolysis with pancreatic lipase showed that the monomers were hydrolyzed as rapidly as the corresponding unheated oils, the dimers much more slowly, and the oligomeric compounds barely at all. Overall, the hydrolysis of the dimers was less than 23% of that for the monomers, with small differences among the oils. Longer heating periods resulted in greater reductions in hydrolysis of the dimeric compounds. These results suggest that the degree of enzymatic hydrolysis of the fractionated acylglycerol compounds is related to differences in the thermal oxidative deterioration, and amounts of polar compounds in the products. (33 Refs.)

  16. Development of hydrate risk quantification in oil and gas production

    NASA Astrophysics Data System (ADS)

    Chaudhari, Piyush N.

    Subsea flowlines that transport hydrocarbons from wellhead to the processing facility face issues from solid deposits such as hydrates, waxes, asphaltenes, etc. The solid deposits not only affect the production but also pose a safety concern; thus, flow assurance is significantly important in designing and operating subsea oil and gas production. In most subsea oil and gas operations, gas hydrates form at high pressure and low temperature conditions, causing the risk of plugging flowlines, with a undesirable impact on production. Over the years, the oil and gas industry has shifted their perspective from hydrate avoidance to hydrate management given several parameters such as production facility, production chemistry, economic and environmental concerns. Thus, understanding the level of hydrate risk associated with subsea flowlines is an important in developing efficient hydrate management techniques. In the past, hydrate formation models were developed for various flow-systems (e.g., oil dominated, water dominated, and gas dominated) present in the oil and gas production. The objective of this research is to extend the application of the present hydrate prediction models for assessing the hydrate risk associated with subsea flowlines that are prone to hydrate formation. It involves a novel approach for developing quantitative hydrate risk models based on the conceptual models built from the qualitative knowledge obtained from experimental studies. A comprehensive hydrate risk model, that ranks the hydrate risk associated with the subsea production system as a function of time, hydrates, and several other parameters, which account for inertial, viscous, interfacial forces acting on the flow-system, is developed for oil dominated and condensate systems. The hydrate plugging risk for water dominated systems is successfully modeled using The Colorado School of Mines Hydrate Flow Assurance Tool (CSMHyFAST). It is found that CSMHyFAST can be used as a screening tool in

  17. CHARACTERISTICS OF SPILLED OILS, FUELS, AND PETROLEUM PRODUCTS: 1. COMPOSITION AND PROPERTIES OF SELECTED OILS

    EPA Science Inventory

    Multicomponent composition and corresponding physical properties data of crude oils and petroleum products are needed as input to environmental fate simulations. Complete sets of such data, however, are not available in the literature due to the complexity and expense of making t...

  18. Liquid fuels from coal: analysis of a partial transition from oil to coal; light liquids in Zimbabwe's liquid fuels base

    SciTech Connect

    Maya, R.S.

    1986-01-01

    This study assesses the feasibility of a coal based light liquids program as a way to localize forces that determine the flow of oil into the Zimbabwean economy. Methods in End-use Energy Analysis and Econometrics in which the utilization of petroleum energy is related to economic and industrial activity are used to gain insight into the structure and behavior of petroleum utilization in that country and to forecast future requirements of this resource. The feasibility of coal liquefaction as a substitute for imported oil is assessed by the use of engineering economics in which the technical economics of competing oil supply technologies are analyzed and the best option is selected. Coal conversion technologies are numerous but all except the Fischer-Trosch indirect coal liquefaction technology are deficient in reliability as commercial ventures. The Fischer-Tropsch process by coincidence better matches Zimbabwe's product configuration than the less commercially advanced technologies. Using present value analysis to compare the coal liquefaction and the import option indicates that it is better to continue importing oil than to resort to a coal base for a portion of the oil supplies. An extended analysis taking special consideration of the risk and uncertainty factors characteristic of Zimbabwe's oil supply system indicates that the coal option is better than the import option. The relative infancy of the coal liquefaction industry and the possibility that activities responsible for the risk and uncertainty in the oil supply system will be removed in the future, however, make the adoption of the coal option an unusually risky undertaking.

  19. Production of polyol oils from soybean oil by bioprocess: results of microbial screening and identification of positive cultures

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Recently we reported methods for microbial screening and production of polyol oils from soybean oil through bioprocessing (Hou and Lin, 2013). Soy-polyol oils (oxygenated acylglycerols) are important starting materials for the manufacture of polymers such as polyurethane. Currently, they are produce...

  20. Some modern notions on oil and gas reservoir production regulation

    SciTech Connect

    Lohrenz, J.; Monash, E.A.

    1980-05-21

    The historic rhetoric of oil and gas reservoir production regulations has been burdened with misconceptions. One was that most reservoirs are rate insensitive. Another was that a reservoir's decline is primarily a function of reservoir mechaism rather than a choice unconstrained by the laws of physics. Relieved of old notions like these, we introduce some modern notions, the most basic being that production regulation should have the purpose of obtaining the highest value from production per irreversible diminution of thermodynamically available energy. The laws of thermodynamics determine the available energy. What then is value. Value may include contributions other than production per se and purely monetary economic outcomes.

  1. Electro-Production of Light Lambda Hypernuclei

    SciTech Connect

    Nakamura, Satoshi N.

    2013-02-01

    Through the study of light hypernuclei, we can learn about hyperon nucleon interaction. The hypernuclear spectroscopy with electron beams is one of most powerful methods to study detailed structure of light hypernuclei thanks to its high energy resolution. With a decade of efforts at Jefferson Lab, the spectroscopy of Λ hypernuclei with an electron beam is now established. Observation of {sup 7}{sub Λ}He which gave the last missing binding energy of the A = 7, T = 1 iso-triplet hypernuclei provides an important experimental input for the charge symmetry breaking (CSB) effect of the ΛN interaction. Further study about A = 4 hypernuclear iso-doublet, {sup 4}{sub Λ}H and {sup 4}{sub Λ}He , is necessary and such experiments are now planned.

  2. Mineral oil extraction of light filth from rubbed sage: collaborative study.

    PubMed

    Holtgreve, N D

    1978-07-01

    An improved method has been developed for extracting light filth in rubbed sage. The method is similar to 44.A04 and 44.A05, except the light filth is isolated by using 20% isopropanol with mineral oil. Collaborative results show that the proposed method yielded better recoveries than the present official first action method. The method has been adopted as official first action. PMID:681262

  3. Olive Oil Based Emulsions in Frozen Puff Pastry Production

    NASA Astrophysics Data System (ADS)

    Gabriele, D.; Migliori, M.; Lupi, F. R.; de Cindio, B.

    2008-07-01

    Puff pastry is an interesting food product having different industrial applications. It is obtained by laminating layers of dough and fats, mainly shortenings or margarine, having specific properties which provides required spreading characteristic and able to retain moisture into dough. To obtain these characteristics, pastry shortenings are usually saturated fats, however the current trend in food industry is mainly oriented towards unsatured fats such as olive oil, which are thought to be safer for human health. In the present work, a new product, based on olive oil, was studied as shortening replacer in puff pastry production. To ensure the desired consistency, for the rheological matching between fat and dough, a water-in-oil emulsion was produced based on olive oil, emulsifier and a hydrophilic thickener agent able to increase material structure. Obtained materials were characterized by rheological dynamic tests in linear viscoelastic conditions, aiming to setup process and material consistency, and rheological data were analyzed by using the weak gel model. Results obtained for tested emulsions were compared to theological properties of a commercial margarine, adopted as reference value for texture and stability. Obtained emulsions are characterized by interesting rheological properties strongly dependent on emulsifier characteristics and water phase composition. However a change in process temperature during fat extrusion and dough lamination seems to be necessary to match properly typical dough rheological properties.

  4. NLO Vector Boson Production With Light Jets

    SciTech Connect

    Bern, Z.; Diana, G.; Dixon, L.J.; Febres Cordero, F.; Forde, D.; Gleisberg, T.; Hoeche, S.; Ita, H.; Kosower, D.A.; Maitre, D.; Ozeren, K.

    2012-02-15

    In this contribution we present recent progress in the computation of next-to-leading order (NLO) QCD corrections for the production of an electroweak vector boson in association with jets at hadron colliders. We focus on results obtained using the virtual matrix element library BlackHat in conjunction with SHERPA, focusing on results relevant to understanding the background to top production. The production of a vector boson in association with several jets at the Large Hadron Collider (LHC) is an important background for other Standard Model processes as well as new physics signals. In particular, the production of a W boson in association with many jets is an important background for processes involving one or more top quarks. Precise predictions for the backgrounds are crucial to measurement of top-quark processes. Vector boson production in association with multiple jets is also a very important background for many SUSY searches, as it mimics the signatures of many typical decay chains. Here we will discuss how polarization information can be used as an additional handle to differentiate top pair production from 'prompt' W-boson production. More generally, ratios of observables, for example for events containing a W boson versus those containing a Z boson, are expected to be better-behaved as many uncertainties cancel in such ratios. Precise calculation of ratios, along with measurement of one of the two processes in the ratio, can be used in data-driven techniques for estimating backgrounds.

  5. Biosurfactants production by Pseudomonas aeruginosa FR using palm oil.

    PubMed

    Oliveira, Fernando J S; Vazquez, Leonardo; De Campos, Norberto P; de França, Francisca P

    2006-03-01

    Biosurfactants production by a strain of Pseudomonas aeruginosa using palm oil as a sole carbon source was investigated. The experiments were carried out in 500-mL conical flasks containing 100 mL of mineral media supplemented with palm oil as the sole carbon source. The P. aeruginosa FR strain was able to reduce surface tension of three tested inorganic media. Rotation velocities from 100 to 150 rpm provided free-cell fermented media with the lowest surface tension of approx 33 mN/m. Emulsification index results of even 100% were achieved when diesel was used as oil phase. Eight surface-active compounds produced by the bacterium were identified by mass spectrometry. PMID:18563649

  6. Characterizing risk factors for pediatric lamp oil product exposures

    PubMed Central

    SHEIKH, S.; CHANG, A.; KIESZAK, S.; LAW, R.; BENNETT, H. K. W.; ERNST, E.; BOND, G. R.; SPILLER, H. A.; SCHURZ-ROGERS, H.; CHU, A.; BRONSTEIN, A. C.; SCHIER, J. G.

    2015-01-01

    Poisonings from lamp oil ingestion continue to occur worldwide among the pediatric population despite preventive measures such as restricted sale of colored and scented lamp oils. This suggests that optimal prevention practices for unintentional pediatric exposures to lamp oil have yet to be identified and/or properly implemented. Objective To characterize demographic, health data, and potential risk factors associated with reported exposures to lamp oil by callers to poison centers (PCs) in the US and discuss their public health implications. Study design . This was a two part study in which the first part included characterizing all exposures to a lamp oil product reported to the National Poison Data System (NPDS) with regard to demographics, exposure, health, and outcome data from 1/1/2000 to 12/31/2010. Regional penetrance was calculated using NPDS data by grouping states into four regions and dividing the number of exposure calls by pediatric population per region (from the 2000 US census). Temporal analyses were performed on NPDS data by comparing number of exposures by season and around the July 4th holiday. Poisson regression was used to model the count of exposures for these analyses. In the second part of this project, in order to identify risk factors we conducted a telephone-based survey to the parents of children from five PCs in five different states. The 10 most recent lamp oil product exposure calls for each poison center were systematically selected for inclusion. Calls in which a parent or guardian witnessed a pediatric lamp oil product ingestion were eligible for inclusion. Data on demographics, exposure information, behavioral traits, and health were collected. A descriptive analysis was performed and Fisher’s exact test was used to evaluate associations between variables. All analyses were conducted using SAS v9.3. Results Among NPDS data, 2 years was the most common patient age reported and states in the Midwestern region had the highest

  7. EVALUATION OF COMMERCIAL, MICROBIAL-BASED PRODUCTS TO TREAT PARAFFIN DEPOSITION IN TANK BOTTOMS AND OIL PRODUCTION EQUIPMENT

    EPA Science Inventory

    Introduction:

    Paraffins are naturally-occurring components of crude oils, but often form solids within oil reservoirs and on oil production equipment when oil is harvested from hot subsurface temperatures to the cooler surface environments. Microbial t...

  8. 75 FR 36773 - Pipeline Safety: Updating Facility Response Plans in Light of the Deepwater Horizon Oil Spill

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-28

    ... Act of 1990, 33 U.S.C. 1321, and Executive Order 12777, 56 FR 54757, Oct. 18, 1991, PHMSA has issued... Light of the Deepwater Horizon Oil Spill AGENCY: Pipeline and Hazardous Materials Safety Administration... response plan under 49 CFR part 194. In light of the Deepwater Horizon oil spill in the Gulf of...

  9. Contribution of Lubricating Oil to Particulate Matter Emissions from Light-duty Gasoline Vehicles in Kansas City

    EPA Science Inventory

    The contribution of lubricating oil to particulate matter (PM) emissions representative of the in-use 2004 light-duty gasoline vehicles fleet is estimated from the Kansas City Light-Duty Vehicle Emissions Study (KCVES). PM emissions are apportioned to lubricating oil and gasoline...

  10. Contribution of Lubricating Oil to Particulate Matter Emissions from Light-Duty Gasoline Vehicles in Kansas City

    EPA Science Inventory

    The contribution of lubricating oil to particulate matter (PM) emissions representative of the in-use 2004 light-duty gasoline vehicles fleet is estimated from the Kansas City Light-Duty Vehicle Emissions Study (KCVES). PM emissions are apportioned to lubricating oil and gasoline...

  11. Visualization by light transmission of oil and water contents in transient two-phase flow fields

    NASA Astrophysics Data System (ADS)

    Darnault, Christophe J. G.; Throop, James A.; DiCarlo, David A.; Rimmer, Alon; Steenhuis, Tammo S.; Parlange, J.-Yves

    1998-06-01

    The difficulty of determining transient fluid contents in a soil-oil-water system is hampering an understanding of the system's flow characteristics. In this paper, we describe a light transmission method (LTM) which can rapidly obtain oil and water contents throughout a large two-dimensional flow field of silica sand. By appropriately coloring the water with 0.005% FD&C blue #1, the hue of the transmitted light is found to be directly related to the water content within the porous media. The hue provides a high resolution measurement of the water and oil contents in transient flow fields (such as unstable flow). Evaluation of the reliability of LTM was assessed by checking the mass balance for a known water injection and its utility in visualizing a whole flow field was exemplified for unstable fingered flow by comparing fluid contents to those obtained with synchrotron X-ray radiation.

  12. Nigeria`s oil production behavior: Tests of alternative hypotheses

    SciTech Connect

    Awokuse, T.O.; Jones, C.T.

    1994-12-31

    The sudden quadrupling of world oil prices in 1973-1974 marked the beginning of several formal inquiries by economists into the production behavior of members of the Organization of the Petroleum Exporting Countries (OPEC). Interest in the organization was further heightened in 1979 when nominal oil prices further doubled. However, oil market analysts have differed in their evaluation of OPEC`s role in the determination of world oil prices. Most energy economists have modeled OPEC as a cartel. Morris Adelman has suggested that OPEC`s true nature lies somewhere between two polar cases of a dominant-firm industry and an imperfect, market-sharing cartel. In the former case, one large, dominant firm (i.e., Saudi Arabia) serves as the {open_quotes}swing producer,{close_quotes} allowing other cartel members and non-OPEC oil producers to produce whatever they wished, controlling the market price by itself through its own output adjustments. The latter case of an imperfect market-sharing cartel is a loose collusive arrangement in which all members agree on an acceptable price level and individual output shares for each producer. Adelman believes that OPEC wobbles between these two cases, depending upon market conditions.

  13. Water footprints of products of oil palm plantations and palm oil mills in Thailand.

    PubMed

    Suttayakul, Phetrada; H-Kittikun, Aran; Suksaroj, Chaisri; Mungkalasiri, Jitti; Wisansuwannakorn, Ruthairat; Musikavong, Charongpun

    2016-01-15

    The water footprint (WF) of fresh fruit bunches (FFBs) from oil palm plantations and crude palm oil (CPO) from palm oil mills in southern and eastern Thailand were determined over 25 years. Climatic conditions, soil characteristics, and the characteristics of oil palm growth were considered. The WF of FFBs was 1063 m(3)/ton (t) on average. Green, blue, and grey waters comprised of 68, 18, and 14% of total WF, respectively. The oil palm plantations in Thailand required smaller amounts of indirect blue water. The average WF for producing a ton of CPO of seven mills was 5083 m(3). Most of the waters used in the mills originated from indirect green, blue and grey waters from the plantations. The direct blue water used in the mills had less impact on the total WF, lower than 1% of the total WF. Average percentages of green, blue, and grey waters of 69, 16, and 15% of total WF were determined for the mills, respectively. The water deprivation of the FFBs and CPO ranged from 0.73-12.9 and 3.44-58.3 m(3)H2Oeq/t, respectively. In 2013, the CPO production in Thailand including green, blue, and grey waters from plantation and blue water from mills required 11,343 million m(3) water. If the oil palm variety Suratthani 7 is used in the plantation, it would increase the yield from 15.2 to 22.8 t FFBs/ha-year and decrease the WF to 888 m(3)/t FFBs. The average value of the oil extraction rate (OER) of mills was 18.1%. With an increase in the OER of 1%, a reduction of the WF of 250 m(3)/t CPO or 5.1% of total WF could be obtained. PMID:26520275

  14. Utilization of palm oil sludge through pyrolysis for bio-oil and bio-char production.

    PubMed

    Thangalazhy-Gopakumar, Suchithra; Al-Nadheri, Wail Mohammed Ahmed; Jegarajan, Dinesh; Sahu, J N; Mubarak, N M; Nizamuddin, S

    2015-02-01

    In this study, pyrolysis technique was utilized for converting palm oil sludge to value added materials: bio-oil (liquid fuel) and bio-char (soil amendment). The bio-oil yield obtained was 27.4±1.7 wt.% having a heating value of 22.2±3.7 MJ/kg and a negligible ash content of 0.23±0.01 wt.%. The pH of bio-oil was in alkaline region. The bio-char yielded 49.9±0.3 wt.%, which was further investigated for sorption efficiency by adsorbing metal (Cd(2+) ions) from water. The removal efficiency of Cd(2+) was 89.4±2%, which was almost similar to the removal efficiency of a commercial activated carbon. The adsorption isotherm was well described by Langmuir model. Therefore, pyrolysis is proved as an efficient tool for palm oil sludge management, where the waste was converted into valuable products. PMID:25278112

  15. Light nuclei production in fusion of heavy ions

    SciTech Connect

    Antonenko, N.V.; Ivanova, S.P.; Jolos, R.V.; Scheid, W. Joint Institute for Nuclear Research, 141980 Dubna )

    1994-10-01

    A possible mechanism of the production of light nuclei in fusion reactions is considered. It is shown that the decay of the dinuclear system during its evolution to a compound nucleus yields a substantial rate for the production of light nuclei. The cross section of this process is calculated for the reaction [sup 58]Ni+[sup 58]Ni. The coupling of other modes of motion causes an increase of the asymmetric decay of the dinuclear system.

  16. Collaborative study of a mineral oil method for the extraction of light filth from ground paprika.

    PubMed

    Thrasher, J J; Gentry, R

    1977-01-01

    An official first action method for the extraction of light filth from spices, 44.A03--44.A05, was modified for the analyses of ground paprika. The sample is extracted with isopropanol and light filth is isolated from 40% isopropanol with mineral oil. Eight collaborators analyzed 4 paprika samples, 2 by the official method and 2 by the proposed method. Average recoveries of added elytral squares were 97 and 66%, respectively, for the proposed and official methods. Recoveries of added rodent hairs were 94 and 61%, respectively. The method has been adopted as official first action for the extraction of light filth from ground paprika. PMID:833083

  17. Influence of paternal exposure to oil and oil products on time to pregnancy and spontaneous abortions.

    PubMed

    Bull, N; Riise, T; Moen, B E

    1999-08-01

    The objective of this study was to evaluate the influence of exposure to oil and oil products among men on the time taken for their wives to conceive and on the incidence of spontaneous abortion among them. A cross-sectional study was performed by posting questionnaires to 1,269 men employed as offshore mechanics, offshore operators, offshore drilling personnel, car mechanics (the 'exposed' occupations) and carpenters ('unexposed'). The married men were asked to give a separate questionnaire to their wives for details about their pregnancies. The time elapsed between the beginning of coitus without contraception and the wife becoming pregnant (time to pregnancy) was analyzed with Cox regression analysis by calculating fecundability ratios for the pregnancies for the men exposed to oil and oil products as compared with the men who were not exposed. Spontaneous abortions were analyzed with logistic regression by calculating odds ratios for the pregnancies in which the men were exposed vs. not exposed. A total of 741 (58%) men returned the questionnaires. A total of 301 pregnancies were analyzed for time taken to conceive and 580 for spontaneous abortion. The results were adjusted for variables that could significantly influence conception time (previous infections of the reproductive system and coffee drinking) or the incidence of spontaneous abortion (mother's age, parity and smoking). The outcomes between the exposed and unexposed pregnancies showed no significant differences. Car mechanics had a lower fecundability ratio before 1992 than after 1992. Paternal exposure to hydrocarbons in the occupations studied did not seem to have had a major influence on time to conception or the incidence of spontaneous abortion among the wives of the men exposed to oil products. PMID:10628044

  18. 40 CFR 112.9 - Spill Prevention, Control, and Countermeasure Plan Requirements for onshore oil production...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Countermeasure Plan Requirements for onshore oil production facilities (excluding drilling and workover... Requirements for onshore oil production facilities (excluding drilling and workover facilities). If you are the owner or operator of an onshore oil production facility (excluding a drilling or workover facility),...

  19. 78 FR 59632 - Oil and Gas and Sulphur Operations on the Outer Continental Shelf-Oil and Gas Production Safety...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-27

    ... proposed rulemaking on production safety systems on August 22, 2013 (78 FR 52240). The proposed rule would... Bureau of Safety and Environmental Enforcement 30 CFR Part 250 RIN 1014-AA10 Oil and Gas and Sulphur Operations on the Outer Continental Shelf--Oil and Gas Production Safety Systems AGENCY: Bureau of Safety...

  20. Oil biodegradation by Bacillus strains isolated from the rock of an oil reservoir located in a deep-water production basin in Brazil.

    PubMed

    da Cunha, Claudia Duarte; Rosado, Alexandre S; Sebastián, Gina V; Seldin, Lucy; von der Weid, Irene

    2006-12-01

    Sixteen spore forming Gram-positive bacteria were isolated from the rock of an oil reservoir located in a deep-water production basin in Brazil. These strains were identified as belonging to the genus Bacillus using classical biochemical techniques and API 50CH kits, and their identity was confirmed by sequencing of part of the 16S rRNA gene. All strains were tested for oil degradation ability in microplates using Arabian Light and Marlin oils and only seven strains showed positive results in both kinds of oils. They were also able to grow in the presence of carbazole, n-hexadecane and polyalphaolefin (PAO), but not in toluene, as the only carbon sources. The production of key enzymes involved with aromatic hydrocarbons biodegradation process by Bacillus strains (catechol 1,2-dioxygenase and catechol 2,3-dioxygenase) was verified spectrophotometrically by detection of cis,cis-muconic acid and 2-hydroxymuconic semialdehyde, and results indicated that the ortho ring cleavage pathway is preferential. Furthermore, polymerase chain reaction (PCR) products were obtained when the DNA of seven Bacillus strains were screened for the presence of catabolic genes encoding alkane monooxygenase, catechol 1,2-dioxygenase, and/or catechol 2,3-dioxygenase. This is the first study on Bacillus strains isolated from an oil reservoir in Brazil. PMID:16896598

  1. Production of valuable hydrocarbons by flash pyrolysis of oil shale

    DOEpatents

    Steinberg, M.; Fallon, P.T.

    1985-04-01

    A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

  2. Hydrodesulphurization of Light Gas Oil using hydrogen from the Water Gas Shift Reaction

    NASA Astrophysics Data System (ADS)

    Alghamdi, Abdulaziz

    2009-12-01

    The production of clean fuel faces the challenges of high production cost and complying with stricter environmental regulations. In this research, the ability of using a novel technology of upgrading heavy oil to treat Light Gas Oil (LGO) will be investigated. The target of this project is to produce cleaner transportation fuel with much lower cost of production. Recently, a novel process for upgrading of heavy oil has been developed at University of Waterloo. It is combining the two essential processes in bitumen upgrading; emulsion breaking and hydroprocessing into one process. The water in the emulsion is used to generate in situ hydrogen from the Water Gas Shift Reaction (WGSR). This hydrogen can be used for the hydrogenation and hydrotreating reaction which includes sulfur removal instead of the expensive molecular hydrogen. This process can be carried out for the upgrading of the bitumen emulsion which would improve its quality. In this study, the hydrodesulphurization (HDS) of LGO was conducted using in situ hydrogen produced via the Water Gas Shift Reaction (WGSR). The main objective of this experimental study is to evaluate the possibility of producing clean LGO over dispersed molybdenum sulphide catalyst and to evaluate the effect of different promoters and syn-gas on the activity of the dispersed Mo catalyst. Experiments were carried out in a 300 ml Autoclave batch reactor under 600 psi (initially) at 391°C for 1 to 3 hours and different amounts of water. After the hydrotreating reaction, the gas samples were collected and the conversion of carbon monoxide to hydrogen via WGSR was determined using a refinery gas analyzer. The sulphur content in liquid sample was analyzed via X-Ray Fluorescence. Experimental results showed that using more water will enhance WGSR but at the same time inhibits the HDS reaction. It was also shown that the amount of sulfur removed depends on the reaction time. The plan is to investigate the effect of synthesis gas (syngas

  3. Electromagnetic production of very light gluinos

    SciTech Connect

    Carlson, C.E.; Sher, M.; Weinstein, L.

    1994-04-01

    Current experiments allow the possibility of gluino masses below about 600 MeV if the lifetime of the gluino is longer than 100 picoseconds. If the mass and lifetime are in this window, then electromagnetic production of pairs of gluino-gluon bound states can provide a means to observe them. The cross section is large enough that the window can be fully explored, up to lifetimes exceeding a microsecond, at high luminosity electron accelerators. A discussion of signatures and a table of event rates for various possibilities at CEBAF is given.

  4. Organic Substances from Unconventional Oil and Gas Production in Shale

    NASA Astrophysics Data System (ADS)

    Orem, W. H.; Varonka, M.; Crosby, L.; Schell, T.; Bates, A.; Engle, M.

    2014-12-01

    Unconventional oil and gas (UOG) production has emerged as an important element in the US and world energy mix. Technological innovations in the oil and gas industry, especially horizontal drilling and hydraulic fracturing, allow for the enhanced release of oil and natural gas from shale compared to conventional oil and gas production. This has made commercial exploitation possible on a large scale. Although UOG is enormously successful, there is surprisingly little known about the effects of this technology on the targeted shale formation and on environmental impacts of oil and gas production at the surface. We examined water samples from both conventional and UOG shale wells to determine the composition, source and fate of organic substances present. Extraction of hydrocarbon from shale plays involves the creation and expansion of fractures through the hydraulic fracturing process. This process involves the injection of large volumes of a water-sand mix treated with organic and inorganic chemicals to assist the process and prop open the fractures created. Formation water from a well in the New Albany Shale that was not hydraulically fractured (no injected chemicals) had total organic carbon (TOC) levels that averaged 8 mg/L, and organic substances that included: long-chain fatty acids, alkanes, polycyclic aromatic hydrocarbons, heterocyclic compounds, alkyl benzenes, and alkyl phenols. In contrast, water from UOG production in the Marcellus Shale had TOC levels as high as 5,500 mg/L, and contained a range of organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at thousands of μg/L for individual compounds. These chemicals and TOC decreased rapidly over the first 20 days of water recovery as injected fluids were recovered, but residual organic compounds (some naturally-occurring) remained up to 250 days after the start of water recovery (TOC 10-30 mg/L). Results show how hydraulic fracturing changes the organic

  5. Hydrocracking of used cooking oil for biofuels production.

    PubMed

    Bezergianni, Stella; Kalogianni, Aggeliki

    2009-09-01

    Hydrocracking of used cooking oil is studied as a potential process for biofuels production. In this work several parameters are considered for evaluating the effectiveness of this technology, including hydrocracking temperature, liquid hourly space velocity (LHSV) and days on stream (DOS). Conversion and total biofuels production is favored by increasing temperature and decreasing LHSV. However moderate reaction temperatures and LHSVs are more attractive for diesel production, whereas higher temperatures and smaller LHSVs are more suitable for gasoline production. Furthermore heteroatom (S, N and O) removal increases as hydrocracking temperature increases, with de-oxygenation being particularly favorable. Saturation, however, is not favored with temperature indicating the necessity of a pre-treatment step prior to hydrocracking to enable saturation of the double bonds and heteroatom removal. Finally the impact of extended operation (catalyst life) on product yields and qualities indicates that all reactions are affected yet at different rates. PMID:19369071

  6. Maximizing Light Utilization Efficiency and Hydrogen Production in Microalgal Cultures

    SciTech Connect

    Melis, Anastasios

    2014-12-31

    The project addressed the following technical barrier from the Biological Hydrogen Production section of the Fuel Cell Technologies Program Multi-Year Research, Development and Demonstration Plan: Low Sunlight Utilization Efficiency in Photobiological Hydrogen Production is due to a Large Photosystem Chlorophyll Antenna Size in Photosynthetic Microorganisms (Barrier AN: Light Utilization Efficiency).

  7. Polycyclic aromatic hydrocarbons in Italian preserved food products in oil.

    PubMed

    Sannino, Anna

    2016-06-01

    A method based on gas chromatography/ tandem mass spectrometry was used to assess levels of 16 EU priority polycyclic aromatic hydrocarbons (PAHs) in 48 preserved food products in oil including foods such as vegetables in oil, fish in oil and oil-based sauces obtained from the Italian market. The benzo[a]pyrene concentrations ranged from <0.04 to 0.40 µg kg(-1), and 72.9% of the samples showed detectable levels of this compound. The highest contamination level was observed for chrysene with three additional PAHs (benzo[a]anthracene, benzo[b]fluoranthene and benzo[c]fluorene) giving mean values higher than the mean value for benzo[a]pyrene. Chrysene was detected in all the samples at concentrations ranging from 0.07 to 1.80 µg kg(-1) (median 0.31 µg kg(-1)). The contamination expressed as PAH4 (sum of benzo(a)pyrene, chrysene, benzo(a)anthracene and benzo(b)fluoranthene), for which the maximum tolerable limit has been set by Commission Regulation (EU) No. 835/2011, varied between 0.10 and 2.94 µg kg(-1). PMID:26886159

  8. Plans for first oil production revived in two Sudanese fields

    SciTech Connect

    Not Available

    1993-05-03

    A Vancouver, British Columbia, independent and its Sudanese partner have filed a development plan with the government of Sudan to produce an initial 40,000 b/d from Heglig and Unity oil fields in Sudan. Arakis Energy Corp., and the private Sudanese company State Petroleum Corp. (SPC) want to begin the first commercial hydrocarbon production in the destitute, war torn country. They are picking up where Chevron Corp. left off after years of grappling with an ambitious, costly - and ultimately futile - effort to export crude-oil from Sudan. After finding almost 300 million bbl of oil in Sudan during the early 1980s, Chevron scuttled a $2 billion project to export 50,000 b/d of Sudanese crude in 1986. It drilled 90 wells and sank more than $1 billion into the project. But it dropped the plan, citing the 1986 collapse of oil prices and concerns over security after repeated guerrilla attacks delayed work. The paper details the project.

  9. Life cycle inventory for the production of germinated oil palm seeds at a selected seed production unit in Malaysia

    NASA Astrophysics Data System (ADS)

    Khairuddin, Nik Sasha Khatrina; Ismail, B. S.; Muhamad, Halimah; May, Choo Yuen

    2013-11-01

    The increasing global demand for edible oil has encouraged Malaysia to increase the areas under oil palm cultivation. The total demand for germinated oil palm seeds in the years 2009, 2010, 2011 and 2012 were 86.4, 76.5, 72.6 and 75.2 million, respectively. Production of germinated oil palm seeds is the first link in the palm oil supply chain. Therefore, good management practices at seed production stage is required to ensure only high quality germinated oil palm seeds are produced before sale to customers. Life cycle assessment (LCA) has been used as a tool to assess environmental impact of the processes throughout a product's lifespan and this approach is an important tool for assessing green house gas (GHG) emission. For this study, a gate-to-gate life cycle inventory (LCI) of a single germinated oil palm seed production unit was carried out. The functional unit used for this LCI was one germinated oil palm seed. To determine the environmental impact for the production of germinated oil palm seeds, information on the inputs were obtained. The inputs for the production of germinated oil palm seeds involved materials such as polyethylene bags, electricity, water, chemicals and fungicides. For this study, the system boundary involved seed germination process and management of germinated oil palm seeds. It was found that the amount of input such as materials and energy used in the production of germinated oil palm seeds was very minimal.

  10. Engineered microbes and methods for microbial oil production

    DOEpatents

    Stephanopoulos, Gregory; Tai, Mitchell; Chakraborty, Sagar

    2015-02-10

    Some aspects of this invention provide engineered microbes for oil production. Methods for microbe engineering and for use of engineered microbes are also provided herein. In some embodiments, microbes are provided that are engineered to modulate a combination of rate-controlling steps of lipid synthesis, for example, a combination of a step generating metabolites, acetyl-CoA, ATP or NADPH for lipid synthesis (a push step), and a step sequestering a product or an intermediate of a lipid synthesis pathway that mediates feedback inhibition of lipid synthesis (a pull step). Such push-and-pull engineered microbes exhibit greatly enhanced conversion yields and TAG synthesis and storage properties.

  11. CO2 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

    SciTech Connect

    Kovar, Mark; Wehner, Scott

    1998-01-13

    The application of cyclic CO2, often referred to as the CO2 Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO2 Huff-n-Puff process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital-intensive miscible projects. Texaco Exploration & Production Inc. and the U. S. Department of Energy have teamed up in an attempt to develop the CO2 Huff-n-Puff process in the Grayburg and San Andres formations which are light oil, shallow shelf carbonate reservoirs that exist throughout the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected sites for this demonstration project are the Central Vacuum Unit waterflood in Lea County, New Mexico and the Sundown Slaughter Field in Hockley County, Texas. Miscible CO2 flooding is the process of choice for enhancing recovery of light oils and already accounts for over 12% of the Permian Basin's daily production. There are significant probable reserves associated with future miscible CO2 projects. However, many are marginally economic at current market conditions due to large up-front capital commitments for a peak response, which may be several years in the future. The resulting negative cash-flow is sometimes too much for an operator to absorb. The CO2 Huff-n-Puff process is being investigated as a near

  12. Floating oil production unit slated in small field off Gabon

    SciTech Connect

    Not Available

    1991-10-14

    This paper reports on the first U.S. tanker converted to a floating production, storage, and offloading (FPSO) unit which takes up station in Gombe-Beta field off Gabon by Dec. 1. FPSO Ocean Producer will work under a 3 year, day rate contract let late in 1990 by Amoco-Gabon Bombe Marin co., a unit of Amoco Production Co. (OGJ, Dec. 24, 1990, p. 27). Gombe-Beta field is in the Atlantic Ocean about 70 miles south of Port Gentil, Gabon. Ocean Producer will be moored in 50 ft of water 3.7 miles off Gabon, with Bombe-Beta's unmanned production platform about 820 ft astern. The vessel will be held in position by a disconnectable, asymmetric, six point, spread mooring system, It is owned and operated by Oceaneering International Services Ltd. (OISL). Affiliate Oceaneering Production Systems (OPS) converted the 78,061 dwt oil tanker MT Baltimore Sea at a capital cost of $25 million at Gulf Copper Manufacturing Corp.'s Port Arthur, Tex., shipyard. Both companies are units of Oceaneering International Inc., Houston. OPS the Ocean Producer's use in Gombe-Beta field is the shallowest water FPSO application in the world. Amoco-Gabon chose an FPSO production system for Gombe-Beta because it expects the remote field to have a short economic life, and the oil requires extensive processing.

  13. Design of governmental policies for oil production rates and oil income spending; a long-term perspective

    SciTech Connect

    Moxnes, E.

    1983-01-01

    Norway is a small country with large oil reserves. In 1980, oil production amounted to 1 million barrels per day. Taxes and royalties to the government from this production provided 9% of the GNP. With current estimates of recoverable reserves, the 1980 production rate would last for 100 years. Because potential income is so large, decisions about oil production rates and oil income spending have tremendous impacts on society. The current debate provides a wide variety of policy suggestions. Attempts to design an appropriate oil policy are complicated by much uncertainty about total reserves, future oil prices, and complex economic responses to production and income. This report provides an integrating framework to aid government officials in their evaluation of policy options. A system dynamics model of the Norwegian national economy is developed for the analysis. The model determines endogenously the spending of oil income, GNP, consumption and investments, imports and exports, unemployment, and labor migration from exporting industries to service industries; all variables result from exogenous decisions about oil production.

  14. Simulating Oil Production from Fractured/Faulted Basement Reservoirs

    NASA Astrophysics Data System (ADS)

    Wang, H.; Forster, C.; Fu, Y.; Huang, C.; Yang, Y.; Deo, M.

    2006-12-01

    A fully-implicit, three-dimensional (3D), three-phase, discrete fault/fracture, black oil simulator provides new insight and understanding of oil production from reservoirs in fractured, low-permeability basement rocks. Results obtained with a controlled volume finite element (CVFE) method compare favorably to those obtained using both single- and dual-porosity finite difference methods (e.g., ECLIPSE). A regularized network of 30 orthogonal faults within a 1000 by 1000 by 200 feet model domain is used to compare the simulator results and to explore the implications of grid sensitivity. In this simple reservoir, cumulative oil recoveries over 900 days of production are similar for CVFE, single-porosity and dual-porosity approaches. CVFE is used to simulate a complex network of intersecting faults that mimic a more realistic basement reservoir with the same fault surface area and fault volume as the regularized network. Cumulative oil production at 900 days is about 3% lower than for the regularized network. The CVFE method provides a much improved ability to represent complex fracture/fault geometries and spatial variations in the internal properties of faults. CVFE simulations of the realistic network illustrate the possible consequences of uncertainty in knowing fracture/fault properties (e.g., porosity, permeability, thickness, dip orientation, connectivity and flow transmissibility). For example, introducing spatial variability in permeability within the fault planes (using spatially randomized patterns of 10, 100 and 1000 md), while retaining a constant geometric mean permeability of 100 md, yields enhanced oil production due to the high-permeability pathways. A 50:50 mix of 10 and 1000 md elements yields 36%OOIP while a 33:33:33 mix of 10, 100 and 1000 md yields 24%OOIP. These results are 26% and 14% greater, respectively, than that obtained for the uniform 100 md case (11%OOIP). This inherent variability, combined with uncertainty in knowing the detailed

  15. Indonesia palm oil production without deforestation and peat conversion by 2050.

    PubMed

    Afriyanti, Dian; Kroeze, Carolien; Saad, Asmadi

    2016-07-01

    Palm oil is a promising source of cooking oil and biodiesel. The demand for palm oil has been increasing worldwide. However, concerns exist surrounding the environmental and socio-economic sustainability of palm oil production. Indonesia is a major palm oil producing country. We explored scenarios for palm oil production in Indonesia until 2050, focusing on Sumatra, Kalimantan and Papua. Our scenarios describe possible trends in crude palm oil production in Indonesia, while considering the demand for cooking oil and biodiesel, the available land for plantations, production capacity (for crude palm oil and fresh fruit bunches) and environmentally restricting conditions. We first assessed past developments in palm oil production. Next, we analysed scenarios for the future. In the past 20years, 95% of the Indonesian oil palm production area was in Sumatra and Kalimantan and was increasingly cultivated in peatlands. Our scenarios for the future indicate that Indonesia can meet a considerable part of the global and Asian demand for palm oil, while avoiding further cultivation of peatlands and forest. By 2050, 264-447Mt crude palm oil may be needed for cooking oil and biodiesel worldwide. In Indonesia, the area that is potentially suitable for oil palm is 17 to 26Mha with a potential production rate of 27-38t fresh fruit bunches/ha, yielding 130-176Mt crude palm oil. Thus Indonesia can meet 39-60% of the international demand. In our scenarios this would be produced in Sumatra (21-26%), Kalimantan (12-16%), and Papua (2%). The potential areas include the current oil palm plantation in mineral lands, but exclude the current oil palm plantations in peatlands. PMID:27037877

  16. Surfactant-enhanced alkaline flooding for light oil recovery. Annual report, 1992--1993

    SciTech Connect

    Wasan, D.T.

    1994-08-01

    In this report, the authors present the results of experimental and theoretical studies in surfactant-enhanced alkaline flooding for light oil recovery. The overall objective of this work is to develop a very cost-effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12.0) for ultimate spontaneous emulsification and ultralow interfacial tension. In addition, the authors have (1) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, (2) investigated the mechanisms for spontaneous emulsification, (3) developed a technique to monitor low water content in oil, and (4) developed a technique to study water-in-oil emulsion film properties.

  17. Commercial production of the oil absorbent Sea Sweep

    SciTech Connect

    Reed, T.B.; Mobeck, W.L.

    1993-12-31

    A new absorbent has been developed for oil spills. It attracts oil and chemicals and floats on water indefinitely. It is mpm-leaching and can save land and beaches from environmental disasters and can be disposed of in an environmentally acceptable manner or recycled. The new absorbent is called {open_quotes}Sea Sweep{close_quotes}; extensive research has been done on it under an EPA Small Business Innovation Research grant, Phase I and Phase II. Sea Sweep has been tested for toxicity to the environment. Less than 2 mg/l total organic carbon was found in water in contact with oil saturated Sea Sweep after 30 minutes. No toxicity was measured to any of the marine or freshwater tested species at any test concentrations. Sea Sweep is made from {open_quotes}pin chips,{close_quotes} a waste wood product, using a patented thermolytic process in which the wood is heated to about 300{degrees}C. It is a coarse, free-flowing granular material absorbing from 2.6 to 6.6 g/g of oils and chemicals. While originally designed for marine oil spills, it is also very effective for oil and chemical spills on land or water. Sea Sweep has now reached the stage of limited commercialization. A small (5 tons/day) plant has been built in northern Colorado at a wood recycling plant and it has been operated since January 1993. The plant features an afterburner that destroys the blue haze resulting from pyrolysis of the sawdust so that production is environmentally acceptable. Sea Sweep is marketed in 5, 10 and 25 lb plastic bags and 500 lb drop bags. It is also sold in socks, booms pillows and bilge rats. The company will recycle non-toxic materials for the customer using methods developed under the SBIR grant. Sea Sweep has been features in a number of articles, on television, and in national and international trade shows. The international marketing of Sea Sweep is administered from the corporate offices in Denver. Domestic marketing is administered from the regional office in Chicago.

  18. Halogens in oil and gas production-associated wastewater.

    NASA Astrophysics Data System (ADS)

    Harkness, J.; Warner, N. R.; Dwyer, G. S.; Mitch, W.; Vengosh, A.

    2014-12-01

    Elevated chloride and bromide in oil and gas wastewaters that are released to the environment are one of the major environmental risks in areas impacted by shale gas development [Olmstead et al.,2013]. In addition to direct contamination of streams, the potential for formation of highly toxic disinfection by-products (DBPs) in drinking water in utilities located downstream from disposal sites poses a serious risk to human health. Here we report on the occurrence of iodide in oil and gas wastewater. We conducted systematic measurements of chloride, bromide, and iodide in (1) produced waters from conventional oil and gas wells from the Appalachian Basin; (2) hydraulic fracturing flowback fluids from unconventional Marcellus and Fayetteville shale gas, (3) effluents from a shale gas spill site in West Virginia; (4) effluents of oil and gas wastewater disposed to surface water from three brine treatment facilities in western Pennsylvania; and (5) surface waters downstream from the brine treatment facilities. Iodide concentration was measured by isotope dilution-inductively coupled plasma-mass spectrometry, which allowed for a more accurate measurement of iodide in a salt-rich matrix. Iodide in both conventional and unconventional oil and gas produced and flowback waters varied from 1 mg/L to 55 mg/L, with no systematic enrichment in hydraulic fracturing fluids. The similarity in iodide content between the unconventional Marcellus flowback waters and the conventional Appalachian produced waters clearly indicate that the hydraulic fracturing process does not induce additional iodide and the iodide content is related to natural variations in the host formations. Our data show that effluents from the brine treatment facilities have elevated iodide (mean = 20.9±1 mg/L) compared to local surface waters (0.03± 0.1 mg/L). These results indicate that iodide, in addition to chloride and bromide in wastewater from oil and gas production, poses an additional risk to downstream

  19. 40 CFR 721.10210 - Soybean oil, epoxidized, reaction products with diethanolamine.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Significant New Uses for Specific Chemical Substances § 721.10210 Soybean oil, epoxidized, reaction products... chemical substance identified as soybean oil, epoxidized, reaction products with diethanolamine (PMN P-09... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Soybean oil, epoxidized,...

  20. 40 CFR 721.10210 - Soybean oil, epoxidized, reaction products with diethanolamine.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Significant New Uses for Specific Chemical Substances § 721.10210 Soybean oil, epoxidized, reaction products... chemical substance identified as soybean oil, epoxidized, reaction products with diethanolamine (PMN P-09... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Soybean oil, epoxidized,...

  1. 40 CFR 721.10210 - Soybean oil, epoxidized, reaction products with diethanolamine.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Significant New Uses for Specific Chemical Substances § 721.10210 Soybean oil, epoxidized, reaction products... chemical substance identified as soybean oil, epoxidized, reaction products with diethanolamine (PMN P-09... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Soybean oil, epoxidized,...

  2. 40 CFR 721.10210 - Soybean oil, epoxidized, reaction products with diethanolamine.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Significant New Uses for Specific Chemical Substances § 721.10210 Soybean oil, epoxidized, reaction products... chemical substance identified as soybean oil, epoxidized, reaction products with diethanolamine (PMN P-09... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Soybean oil, epoxidized,...

  3. 15 CFR 754.3 - Petroleum products not including crude oil.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... SUPPLY CONTROLS § 754.3 Petroleum products not including crude oil. (a) License requirement. As indicated... required to all destinations, including Canada, for the export of petroleum products, excluding crude oil..., other than crude oil, will be denied, unless the President makes a finding required by the...

  4. Investigation of oil recovery improvement by coupling an interfacial tension agent and a mobility control agent in light oil reservoirs. Final report

    SciTech Connect

    Pitts, M.

    1995-12-01

    This research studied the oil recovery potential of flooding light oil reservoirs by combining interfacial tension reducing agent(s) with a mobility control agent. The specific objectives were: To define the mechanisms and limitations of co-injecting interfacial tension reduction agent(s) and a mobility control agent to recover incremental oil. Specifically, the study focused on the fluid-fluid and fluid-rock interactions. To evaluate the economics of the combination technology and investigate methods to make the process more profitable. Specific areas of study were to evaluate different chemical concentration tapers and the volume of chemical injection required to give optimal oil recovery.

  5. Production of single cell oil from Lipomyces starkeyi ATCC 56304 using biorefinery by-products.

    PubMed

    Probst, Kyle V; Vadlani, Praveen V

    2015-12-01

    Single cell oil (SCO) is a valuable noncrop-based renewable oil source. Hemicellulose derived sugars can be utilized to produce SCO using the oleaginous yeast Lipomyces starkeyi ATCC 56304. Bran by-products were tested as hemicellulose-rich feedstocks for the production of SCO. Whole and destarched corn and wheat bran hydrolysates were produced using hydrothermal and dilute sulfuric acid (0%, 0.5%, 1.0%, v/v) pretreatment along with enzymatic hydrolysis. Whole bran hydrolysates produced from hydrothermal pretreatment generated the highest average oil yields of 126.7 and 124.3 mg oil/g sugar for both wheat and corn bran, respectively. 1.0% acid pretreatment was effective for the destarched bran generating a hemicellulose hydrolysis efficiency of 94% and 84% for wheat and corn bran, respectively, resulting in the highest oil yield of 70.7 mg oil/g sugar. The results indicate pretreated corn and wheat bran hydrolysates can serve as viable feedstocks for oleaginous yeast SCO bioconversion. PMID:26402869

  6. Surfactant-enhanced alkaline flooding for light oil recovery. Quarterly report, January 1--March 31, 1994

    SciTech Connect

    Wasan, D.T.

    1994-06-01

    The overall objective of this project is to develop a very cost-effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12.0) for ultimate spontaneous emulsification and ultra-low tension. In addition, the novel concept of pH gradient design to optimize flood water conditions will be tested. Last quarter we investigated the phase behavior and the regions where in the middle phase occurs. The optimum phase was found to go through a maximum with pH, sodium concentration and surfactant concentration. The optimum pH is about 12.0 to 13.5, the optimum sodium concentration is about 0.513 mol/liter, and the optimum surfactant concentration is about 0.2%. The effect of surfactant type was also investigated. Petrostep B-105 was found to give the most middle phase production. This quarter, we investigated the contact angle of Long Beach oil, Adena oil, and a model oil on a solid glass surface in contact with an aqueous alkaline solution both with and without added preformed surfactant. The contact angle with Long Beach and Adena oils showed oil-wet conditions, whereas the model oil showed both oil-wet and water-wet conditions depending on the pH of the aqueous phase. The addition of surfactant to the alkaline solution resulted in making the system less oil-wet. Spreading of the oil on the glass surface was observed in all three systems investigated.

  7. Product Quality Assurance for Off-Grid Lighting in Africa

    SciTech Connect

    World Bank; Mills, Evan; Mills, Evan

    2008-07-13

    Although the emergence of markets for high efficiency off-grid lighting technologies holds promise, realizing the potential of this opportunity on a long-term, sustainable basis requires careful attention to issues of product quality, consumer protection, and the potential for significant 'market spoiling', in anticipation of increases of sales of low cost, low performance off-grid lighting products. The goal of the Lighting Africa quality assurance workshop was to articulate strategies to mitigate the dangers of market spoiling and to explore ways to protect consumers from misleading advertising for sales of inferior, off-grid lighting products in the context of Lighting Africa's overarching objective to support the industry in developing a robust off-grid lighting market in Africa. The workshop resulted in the identification of two strategic approaches for meeting Lighting Africa quality assurance programmatic needs. The first strategy is intended to meet a short-term programmatic need for quality associated with requests for lighting products by bulk procurement agents, such as in a World Bank-financed project. The development of procurement specifications and test procedures that could be used in a quality/usability screening method in order to provide guidance for forthcoming large volume purchases emerged as the best solution to meet this need. Such approaches are used in World Bank-financed solar home systems (SHSs) projects in Bangladesh, Sri Lanka, and China, among others. However, unlike the SHSs which have multiple balance-of-system (BOS) components warranting the need for an array of specifications for individual components, stand alone lighting systems require specifications that are amenable to individual light points. To test this approach, Lighting Africa elected to use the technical specifications issued by the Photovoltaic Global Approval Program for solar lanterns that use CFL bulbs (PVRS11A) as the basis of qualifying such products. A contract

  8. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    SciTech Connect

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. It was hoped that the successful application of these technologies would result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs.

  9. Characteristics of biomarkers from light oils and their source rocks in the northern continental shelf of the South China Sea

    NASA Astrophysics Data System (ADS)

    An Qiao, Wang; Bao Ming, Zheng

    Light oil occurs in oil-bearing basins at the northern continental shelf of the South China Sea. They are of three types (A-C), based on their biomarker characteristics. The light oil of type A exhibits abundant C 30-4-methyl sterane, and a minority of tricyclic terpanes. It therefore has an affinity to Eocene lacustrine source rock with a richness of algae and pinus pollen. However, the light oil of type B is charaterized by a pronounced peak of C 19-tricyclic terpane. It also contains extremely abundant Tm. The oil of this type has characteristics identical to that of Oligocene coal and paludal mudstone. The light oil of type C shows the relatively high peak of γ-lupane and Ts as its characterization. Therefore, this type of oil is correlated to Oligocene lacustrine source rock which contains comparatively rich angiosperm pollen. The conclusion made is that light oil (including condensate), and natural gas, can originate from source rocks at different maturities in different sedimentary facies.

  10. Method for the flotation oil extraction of light filth from ground capsicums.

    PubMed

    Thrasher, J J; Colliflower, E J

    1977-05-01

    The present official first action method for ground capsicums, 44.123, was adopted in 1945 and there have been great changes in processing and examination of spices since that time. The proposed method involves isopropanol pretreatment, followed by wet sieving and extraction of the light filth from 60% ethanol with flotation oil. The filter papers were clean and recoveries were good (95%) for 5 different lots of capsicums and annato spiked with insect fragments and rodent hairs. PMID:870482

  11. Photoenhanced Toxicity of Oil to Larval Fish

    EPA Science Inventory

    Photoenhanced toxicity is the increase in the toxicity of a chemical in the presence of ultraviolet light (UV), compared to toxicity elicited under conditions of minimal UV. Oil products, weathered oils, combusted oil products, and specific polycyclic aromatic compounds in oil ha...

  12. Proteomic analysis of the oil palm fruit mesocarp reveals elevated oxidative phosphorylation activity is critical for increased storage oil production.

    PubMed

    Loei, Hendrick; Lim, Justin; Tan, Melvin; Lim, Teck Kwang; Lin, Qing Song; Chew, Fook Tim; Kulaveerasingam, Harikrishna; Chung, Maxey C M

    2013-11-01

    Palm oil is a highly versatile commodity with wide applications in the food, cosmetics, and biofuel industries. Storage oil in the oil palm mesocarp can make up a remarkable 80% of its dry mass, making it the oil crop with the richest oil content in the world. As such, there has been an ongoing interest in understanding the mechanism of oil production in oil palm fruits. To identify the proteome changes during oil palm fruit maturation and factors affecting oil yield in oil palm fruits, we examined the proteomic profiles of oil palm mesocarps at four developing stages--12, 16, 18, and 22 weeks after pollination--by 8-plex iTRAQ labeling coupled to 2D-LC and MALDI-TOF/TOF MS. It was found that proteins from several important metabolic processes, including starch and sucrose metabolism, glycolysis, pentose phosphate shunt, fatty acid biosynthesis, and oxidative phosphorylation, were differentially expressed in a concerted manner. These increases led to an increase in carbon flux and a diversion of resources such as ATP and NADH that are required for lipid biosynthesis. The temporal proteome profiles between the high-oil-yielding (HY) and low-oil-yielding (LY) fruits also showed significant differences in the levels of proteins involved in the regulation of the TCA cycle and oxidative phosphorylation. In particular, the expression level of the β subunit of the ATP synthase complex (complex IV of the electron transport chain) was found to be increased during fruit maturation in HY but decreased in the LY during the fruit maturation. These results suggested that increased energy supply is necessary for augmented oil yield in the HY oil palm trees. PMID:24083564

  13. Lipid Production by Dunaliella salina in Batch Culture: Effects of Nitrogen Limitation and Light Intensity

    SciTech Connect

    Weldy, Chad S.; Huesemann, Michael H.

    2007-01-01

    Atmospheric carbon dioxide (CO2) concentrations are increasing and will cause unknown deleterious environmental effects if left unchecked. The Intergovernmental Panel on Climate Change (IPCC) has predicted in its latest report a 2ºC to 4ºC increase in global temperatures even with the strictest CO2 mitigation practices. Global warming can be attributed to in large part to the burning of carbon-based fossil fuels, as the concentration of atmospheric CO2 is directly related to the burning of fossil fuels. Biofuels which do not add CO2 to the atmosphere are presently generated primarily from terrestrial plants, i.e., ethanol from corn grain and biodiesel from soybean oil. The production of biofuels from terrestrial plants is severely limited by the availability of fertile land. Lipid production from microalgae and its corresponding biodiesel production have been studied since the late 1970’s but large scale production was determined to be economically unfeasible due to the large costs of sterile growing conditions required for many algal species. This study focuses on the potential to use the halophilic microalgae species Dunaliella salina as a source of lipids and subsequently for biodiesel production. The lipid production rates were compared for D. salina cultured in replicate photobioreactors under high light and low light as well as nitrogen sufficient and nitrogen deficient culture conditions. The results show (a) cellular lipid content ranging from 16 to 44% (wt), (b) a maximum culture lipid concentration of 450 mg lipid/L, and (c) a maximum integrated lipid production rate of 46 mg lipid/L culture*day. The high amount of lipids produced suggests that D. salina, which can be mass-cultured in non-sterile outdoor ponds, has a strong potential to be an economically valuable source for renewable oil and biodiesel production.

  14. LIPID PRODUCTION BY DUNALIELLA SALINA IN BATCH CULTURE: EFFECTS OF NITROGEN LIMITATION AND LIGHT INTENSITY

    SciTech Connect

    Weldy, C.S.; Huesemann, M.

    2007-01-01

    Atmospheric carbon dioxide (CO2) concentrations are increasing and may cause unknown deleterious environmental effects if left unchecked. The Intergovernmental Panel on Climate Change (IPCC) has predicted in its latest report a 2°C to 4°C increase in global temperatures even with the strictest CO2 mitigation practices. Global warming can be attributed in large part to the burning of carbon-based fossil fuels, as the concentration of atmospheric CO2 is directly related to the burning of fossil fuels. Biofuels which do not add CO2 to the atmosphere are presently generated primarily from terrestrial plants, i.e., ethanol from corn grain and biodiesel from soybean oil. The production of biofuels from terrestrial plants is severely limited by the availability of fertile land. Lipid production from microalgae and its corresponding biodiesel production have been studied since the late 1970s but large scale production has remained economically infeasible due to the large costs of sterile growing conditions required for many algal species. This study focuses on the potential of the halophilic microalgae species Dunaliella salina as a source of lipids and subsequent biodiesel production. The lipid production rates under high light and low light as well as nitrogen suffi cient and nitrogen defi cient culture conditions were compared for D. salina cultured in replicate photobioreactors. The results show (a) cellular lipid content ranging from 16 to 44% (wt), (b) a maximum culture lipid concentration of 450mg lipid/L, and (c) a maximum integrated lipid production rate of 46mg lipid/L culture*day. The high amount of lipids produced suggests that D. salina, which can be mass-cultured in non-sterile outdoor ponds, has strong potential to be an economically valuable source for renewable oil and biodiesel production.

  15. 78 FR 54417 - Oil and Gas and Sulphur Operations on the Outer Continental Shelf-Oil and Gas Production Safety...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-04

    ... Operations on the Outer Continental Shelf--Oil and Gas Production Safety Systems Correction In proposed rule....802 Design, installation, Sec. 250.819 Specification and operation of surface production- for surface... features. Sec. 250.803 Additional production Sec. 250.850 Production system requirements....

  16. Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil

    SciTech Connect

    Elliott, Douglas C.; Wang, Huamin; French, Richard; Deutch, Steve; Iisa, Kristiina

    2014-08-14

    Hot-vapor filtered bio-oils were produced from two different biomass feedstocks, oak and switchgrass, and the oils were evaluated in hydroprocessing tests for production of liquid hydrocarbon products. Hot-vapor filtering reduced bio-oil yields and increased gas yields. The yields of fuel carbon as bio-oil were reduced by ten percentage points by hot-vapor filtering for both feedstocks. The unfiltered bio-oils were evaluated alongside the filtered bio-oils using a fixed bed catalytic hydrotreating test. These tests showed good processing results using a two-stage catalytic hydroprocessing strategy. Equal-sized catalyst beds, a sulfided Ru on carbon catalyst bed operated at 220°C and a sulfided CoMo on alumina catalyst bed operated at 400°C were used with the entire reactor at 100 atm operating pressure. The products from the four tests were similar. The light oil phase product was fully hydrotreated so that nitrogen and sulfur were below the level of detection, while the residual oxygen ranged from 0.3 to 2.0%. The density of the products varied from 0.80 g/ml up to 0.86 g/ml over the period of the test with a correlated change of the hydrogen to carbon atomic ratio from 1.79 down to 1.57, suggesting some loss of catalyst activity through the test. These tests provided the data needed to assess the suite of liquid fuel products from the process and the activity of the catalyst in relationship to the existing catalyst lifetime barrier for the technology.

  17. Linkages between the markets for crude oil and the markets for refined products

    SciTech Connect

    Didziulis, V.S.

    1990-01-01

    To understand the crude oil price determination process it is necessary to extend the analysis beyond the markets for petroleum. Crude oil prices are determined in two closely related markets: the markets for crude oil and the markets for refined products. An econometric-linear programming model was developed to capture the linkages between the markets for crude oil and refined products. In the LP refiners maximize profits given crude oil supplies, refining capacities, and prices of refined products. The objective function is profit maximization net of crude oil prices. The shadow price on crude oil gives the netback price. Refined product prices are obtained from the econometric models. The model covers the free world divided in five regions. The model is used to analyze the impacts on the markets of policies that affect crude oil supplies, the demands for refined products, and the refining industry. For each scenario analyzed the demand for crude oil is derived from the equilibrium conditions in the markets for products. The demand curve is confronted with a supply curve which maximizes revenues providing an equilibrium solution for both crude oil and product markets. The model also captures crude oil price differentials by quality. The results show that the demands for crude oil are different across regions due to the structure of the refining industries and the characteristics of the demands for refined products. Changes in the demands for products have a larger impact on the markets than changes in the refining industry. Since markets for refined products and crude oil are interrelated they can't be analyzed individually if an accurate and complete assessment of a policy is to be made. Changes in only one product market in one region affect the other product markets and the prices of crude oil.

  18. Optimization of light use efficiency for biofuel production in algae.

    PubMed

    Simionato, Diana; Basso, Stefania; Giacometti, Giorgio M; Morosinotto, Tomas

    2013-12-01

    A major challenge for next decades is development of competitive renewable energy sources, highly needed to compensate fossil fuels reserves and reduce greenhouse gas emissions. Among different possibilities, which are currently under investigation, there is the exploitation of unicellular algae for production of biofuels and biodiesel in particular. Some algae species have the ability of accumulating large amount of lipids within their cells which can be exploited as feedstock for the production of biodiesel. Strong research efforts are however still needed to fulfill this potential and optimize cultivation systems and biomass harvesting. Light provides the energy supporting algae growth and available radiation must be exploited with the highest possible efficiency to optimize productivity and make microalgae large scale cultivation energetically and economically sustainable. Investigation of the molecular bases influencing light use efficiency is thus seminal for the success of this biotechnology. In this work factors influencing light use efficiency in algal biomass production are reviewed, focusing on how algae genetic engineering and control of light environment within photobioreactors can improve the productivity of large scale cultivation systems. PMID:23876487

  19. Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery

    SciTech Connect

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Wagirin Ruiz Paidin; Thaer N. N. Mahmoud; Daryl S. Sequeira; Amit P. Sharma

    2006-09-30

    This is the final report describing the evolution of the project ''Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' from its conceptual stage in 2002 to the field implementation of the developed technology in 2006. This comprehensive report includes all the experimental research, models developments, analyses of results, salient conclusions and the technology transfer efforts. As planned in the original proposal, the project has been conducted in three separate and concurrent tasks: Task 1 involved a physical model study of the new GAGD process, Task 2 was aimed at further developing the vanishing interfacial tension (VIT) technique for gas-oil miscibility determination, and Task 3 was directed at determining multiphase gas-oil drainage and displacement characteristics in reservoir rocks at realistic pressures and temperatures. The project started with the task of recruiting well-qualified graduate research assistants. After collecting and reviewing the literature on different aspects of the project such gas injection EOR, gravity drainage, miscibility characterization, and gas-oil displacement characteristics in porous media, research plans were developed for the experimental work to be conducted under each of the three tasks. Based on the literature review and dimensional analysis, preliminary criteria were developed for the design of the partially-scaled physical model. Additionally, the need for a separate transparent model for visual observation and verification of the displacement and drainage behavior under gas-assisted gravity drainage was identified. Various materials and methods (ceramic porous material, Stucco, Portland cement, sintered glass beads) were attempted in order to fabricate a satisfactory visual model. In addition to proving the effectiveness of the GAGD process (through measured oil recoveries in the range of 65 to 87% IOIP), the visual models demonstrated three possible

  20. Method of processing thermal cracked by-product oil

    SciTech Connect

    Matsuzaka, E.; Sato, A.; Shimizu, I.

    1980-06-17

    This invention provides a method of processing thermal cracked by-product oil which comprises reacting a distillate from a thermal cracked by-product oil principally containing components of a boiling range between 75/sup 0/ C and 198/sup 0/C said distillate being one of the distillates from the cracking of petroleum hydrocarbons at a cracking temperature of 700/sup 0/C or higher, and containing a ratio of 5-100 molar percent aromatic olefins to non -olefinic aromatic hydrocarbons, in liquid phase in the presence of an acid catalyst under such conditions that the reaction temperature is 0/sup 0/C -200/sup 0/ C., the liquid residence time is 0.1 hour-5 hours and wherein the content of aromatic olefins in the reaction system are 5% by weight or less at the end of the reaction, to yield a processed distillate containing noncondensed di- and tricyclic aromatic compounds which are reaction products of aromatic olefins with other aromatic hydrocarbons but no substantial amount of unsaturated components.

  1. Biodiesel production from waste frying oils and its quality control.

    PubMed

    Sabudak, T; Yildiz, M

    2010-05-01

    The use of biodiesel as fuel from alternative sources has increased considerably over recent years, affording numerous environmental benefits. Biodiesel an alternative fuel for diesel engines is produced from renewable sources such as vegetable oils or animal fats. However, the high costs implicated in marketing biodiesel constitute a major obstacle. To this regard therefore, the use of waste frying oils (WFO) should produce a marked reduction in the cost of biodiesel due to the ready availability of WFO at a relatively low price. In the present study waste frying oils collected from several McDonald's restaurants in Istanbul, were used to produce biodiesel. Biodiesel from WFO was prepared by means of three different transesterification processes: a one-step base-catalyzed, a two-step base-catalyzed and a two-step acid-catalyzed transesterification followed by base transesterification. No detailed previous studies providing information for a two-step acid-catalyzed transesterification followed by a base (CH(3)ONa) transesterification are present in literature. Each reaction was allowed to take place with and without tetrahydrofuran added as a co-solvent. Following production, three different procedures; washing with distilled water, dry wash with magnesol and using ion-exchange resin were applied to purify biodiesel and the best outcome determined. The biodiesel obtained to verify compliance with the European Standard 14214 (EN 14214), which also corresponds to Turkish Biodiesel Standards. PMID:20100653

  2. Atmospheric fate of oil matter adsorbed on sea salt particles under UV light

    NASA Astrophysics Data System (ADS)

    Vaitilingom, M.; Avij, P.; Huang, H.; Valsaraj, K. T.

    2014-12-01

    The presence of liquid petroleum hydrocarbons at the sea water surface is an important source of marine pollution. An oil spill in sea-water will most likely occur due to an involuntary accident from tankers, offshore platforms, etc. However, a large amount of oil is also deliberately spilled in sea-water during the clean-out process of tank vessels (e.g. for the Mediterranean Sea, 490,000 tons/yr). Moreover, the pollution caused by an oil spill does not only affect the aquatic environment but also is of concern for the atmospheric environment. A portion of the oil matter present at the sea-water surface is transported into the atmosphere viaevaporation and adsorption at the surface of sea spray particles. Few studies are related to the presence of oil matter in airborne particles resulting from their adsorption on sea salt aerosols. We observed that the non-volatile oil matter was adsorbed at the surface of sea-salt crystals (av. size of 1.1 μm). Due to their small size, these particles can have a significant residence time in the atmosphere. The hydrocarbon matter adsorbed at the surface of these particles can also be transformed by catalyzers present in the atmosphere (i.e. UV, OH, O3, ...). In this work, we focused on the photo-oxidation rates of the C16 to C30alkanes present in these particles. We utilized a bubble column reactor, which produced an abundance of small sized bubbles. These bubbles generated droplets upon bursting at the air-salt water interface. These droplets were then further dried up and lifted to the top of the column where they were collected as particles. These particles were incubated in a controlled reactor in either dark conditions or under UV-visible light. The difference of alkane content analyzed by GC-MS between the particles exposed to UV or the particles not exposed to UV indicated that up to 20% in mass was lost after 20 min of light exposure. The degradation kinetics varied for each range of alkanes (C16-20, C21-25, C26

  3. Catalytic processes towards the production of biofuels in a palm oil and oil palm biomass-based biorefinery.

    PubMed

    Chew, Thiam Leng; Bhatia, Subhash

    2008-11-01

    In Malaysia, there has been interest in the utilization of palm oil and oil palm biomass for the production of environmental friendly biofuels. A biorefinery based on palm oil and oil palm biomass for the production of biofuels has been proposed. The catalytic technology plays major role in the different processing stages in a biorefinery for the production of liquid as well as gaseous biofuels. There are number of challenges to find suitable catalytic technology to be used in a typical biorefinery. These challenges include (1) economic barriers, (2) catalysts that facilitate highly selective conversion of substrate to desired products and (3) the issues related to design, operation and control of catalytic reactor. Therefore, the catalytic technology is one of the critical factors that control the successful operation of biorefinery. There are number of catalytic processes in a biorefinery which convert the renewable feedstocks into the desired biofuels. These include biodiesel production from palm oil, catalytic cracking of palm oil for the production of biofuels, the production of hydrogen as well as syngas from biomass gasification, Fischer-Tropsch synthesis (FTS) for the conversion of syngas into liquid fuels and upgrading of liquid/gas fuels obtained from liquefaction/pyrolysis of biomass. The selection of catalysts for these processes is essential in determining the product distribution (olefins, paraffins and oxygenated products). The integration of catalytic technology with compatible separation processes is a key challenge for biorefinery operation from the economic point of view. This paper focuses on different types of catalysts and their role in the catalytic processes for the production of biofuels in a typical palm oil and oil palm biomass-based biorefinery. PMID:18434141

  4. Natural Oil Production from Microorganisms: Bioprocess and Microbe Engineering for Total Carbon Utilization in Biofuel Production

    SciTech Connect

    2010-07-15

    Electrofuels Project: MIT is using carbon dioxide (CO2) and hydrogen generated from electricity to produce natural oils that can be upgraded to hydrocarbon fuels. MIT has designed a 2-stage biofuel production system. In the first stage, hydrogen and CO2 are fed to a microorganism capable of converting these feedstocks to a 2-carbon compound called acetate. In the second stage, acetate is delivered to a different microorganism that can use the acetate to grow and produce oil. The oil can be removed from the reactor tank and chemically converted to various hydrocarbons. The electricity for the process could be supplied from novel means currently in development, or more proven methods such as the combustion of municipal waste, which would also generate the required CO2 and enhance the overall efficiency of MIT’s biofuel-production system.

  5. Hadron production in light and heavy, quark and antiquark jets

    SciTech Connect

    Baird, K.G.; SLD Collaboration

    1996-08-01

    The authors review four hadronization studies performed by the SLD experiment at SLAC, involving separation of light (Z{sup 0} {r_arrow} u{anti u}, d{anti d}, s{anti s}), c, and b flavors using precision vertexing, and separation of q- and {anti q}-jets using the highly polarized SLC electron beam. They measured the differences between the average charged multiplicities in Z{sup 0} {r_arrow} light, {r_arrow} c{anti c}, and {r_arrow}b{anti b} events, and found that the results were consistent with predictions of perturbative QCD. Next, they measured {pi}/{Kappa}/p/{Kappa}{sup 0}/{Lambda}{sup 0} production in light events for the first time, and compared with production in c- and b-flavor events. They then examined particle production differences in light quark and antiquark hemispheres, and observed more high momentum baryons and K{sup {minus}}`s than antibaryons and K{sup +}`s in quark hemispheres, consistent with the leading particle hypothesis. Lastly, they performed a search for jet handedness in light q- and {anti q}-jets. Assuming Standard Model values of quark polarization in Z{sup 0} decays, they have set an improved upper limit on the analyzing power of the handedness method.

  6. Diffuse-light absorption spectroscopy by fiber optics for detecting and quantifying the adulteration of extra virgin olive oil

    NASA Astrophysics Data System (ADS)

    Mignani, A. G.; Ciaccheri, L.; Ottevaere, H.; Thienpont, H.; Conte, L.; Marega, M.; Cichelli, A.; Attilio, C.; Cimato, A.

    2010-09-01

    A fiber optic setup for diffuse-light absorption spectroscopy in the wide 400-1700 nm spectral range is experimented for detecting and quantifying the adulteration of extra virgin olive oil caused by lower-grade olive oils. Absorption measurements provide spectral fingerprints of authentic and adulterated oils. A multivariate processing of spectroscopic data is applied for discriminating the type of adulterant and for predicting its fraction.

  7. Lighting Up Enzymes for Solar Hydrogen Production (Fact Sheet)

    SciTech Connect

    Not Available

    2011-02-01

    Scientists at the National Renewable Energy Laboratory (NREL) have combined quantum dots, which are spherical nanoparticles that possess unique size-tunable photophysical properties, with the high substrate selectivity and fast turnover of hydrogenase enzymes to achieve light-driven hydrogen (H2) production. They found that quantum dots of cadmium telluride coated in carboxylic acids easily formed highly stable complexes with the hydrogenase and that these hybrid assemblies functioned to catalyze H2 production using the energy of sunlight.

  8. Laboratory simulation of the successive aerobic and anaerobic degradation of oil products in oil-contaminated high-moor peat

    NASA Astrophysics Data System (ADS)

    Tolpeshta, I. I.; Trofimov, S. Ya.; Erkenova, M. I.; Sokolova, T. A.; Stepanov, A. L.; Lysak, L. V.; Lobanenkov, A. M.

    2015-03-01

    A model experiment has been performed on the successive aerobic and anaerobic degradation of oil products in samples of oil-contaminated peat sampled from a pine-subshrub-sphagnum bog near the Sutormin oilfield pipeline in the Yamal-Nenets autonomous district. During the incubation of oil-contaminated peat with lime and mineral fertilizers under complete flooding, favorable conditions are created for the aerobic oxidation of oil products at the beginning of the experiment and, as the redox potential decreases, for the anaerobic degradation of oil products conjugated with the reduction of N5+ and S+6 and methanogenesis. From the experimental data on the dynamics of the pH; Eh; and the NO{3/-}, NO{2/-}, and SO{4/2-} concentrations in the liquid phase of the samples, it has been found that denitrifiers significantly contributed to the biodegradation of oil products under the experimental conditions. After the end of the experiment, the content of oil products in the contaminated samples decreased by 21-26%.

  9. Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

    DOEpatents

    Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

    2014-12-02

    The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

  10. Technical options for processing additional light tight oil volumes within the United States

    EIA Publications

    2015-01-01

    This report examines technical options for processing additional LTO volumes within the United States. Domestic processing of additional LTO would enable an increase in petroleum product exports from the United States, already the world’s largest net exporter of petroleum products. Unlike crude oil, products are not subject to export limitations or licensing requirements. While this is one possible approach to absorbing higher domestic LTO production in the absence of a relaxation of current limitations on crude exports, domestic LTO would have to be priced at a level required to encourage additional LTO runs at existing refinery units, debottlenecking, or possible additions of processing capacity.

  11. Life cycle assessment of a palm oil system with simultaneous production of biodiesel and cooking oil in Cameroon.

    PubMed

    Achten, Wouter M J; Vandenbempt, Pieter; Almeida, Joana; Mathijs, Erik; Muys, Bart

    2010-06-15

    The use of palm oil as a biofuel has been heavily debated for its land-use conflict with nature and its competition with food production, being the number one cooking oil worldwide. In that context, we present a life cycle assessment of a palm oil production process yielding both biodiesel and cooking oil, incorporating the land-use impact and evaluating the effect of treating the palm oil mill effluent (POME) prior to disposal. The results show that the nonrenewable energy requirement, global warming potential (GWP; exclusive land-use change), and acidification potential are lower than those of the fossil alternative. However, the system triggers an increase in eutrophication potential (EP) compared to the fossil fuel reference. This system shows less energy requirement, global warming and acidification reduction, and less eutrophication increase compared to the reference than the same system converting all palm oil into biodiesel (no cooking oil production). The land occupation of palm oil triggers ecosystem quality (EQ) loss of 30-45% compared to the potential natural vegetation. Furthermore, such land-use change triggers a carbon debt neutralizing the GWP reduction for 45-53 years. The POME treatment scenarios reveal a trade-off between GWP and EP. PMID:20496929

  12. Gamma-linolenic acid egg production enriched with hemp seed oil and evening primrose oil in diet of laying hens.

    PubMed

    Park, Sang-Oh; Hwangbo, Jong; Yuh, In-Suh; Park, Byung-Sung

    2014-07-01

    This study was carried out to find out the effect of supplying gamma linolenic acid (GLA) on laying performance and egg quality. A hundred twenty of 30 weeks old hyline brown laying hens with 98% of egg production were completely randomized to 4 different treatment groups by 30 hens (the control group fed with the diet containing beef tallow, 3 treatment groups fed with the diet containing corn oil, the diet containing hemp seed oil and the diet containing evening primrose oil, respectively), and their laying performance and egg production were investigated for 5 weeks. Intake of hemp seed oil or evening primrose helped to increase the retention rate of GLA, which was transmigrated into eggs from blood. GLA was not detected in the blood samples of control group and treatment group fed diet containing corn oil, while it was significantly increased in the blood samples of the treatment groups fed with diet containing hemp seed oil and diet containing evening primrose oil, respectively. GLA retention was not observed in the eggs produced respectively by control group and treatment group fed with diet containing corn oil, whereas it was significantly increased in the eggs produced by the treatment group fed with diet containing hemp seed oil by 1.09% and the treatment group fed with diet containing evening primrose oil by 4.87%. This result suggests that GLA-reinforced functional eggs can be produced by adding hemp seed oil and evening primrose oil to the feed for laying hens and feeding them with it. It is thought that further researches and clinical trials on biochemical mechanism related to atopic dermatitis should be conducted in future. PMID:25004746

  13. World oil and gas resources-future production realities

    SciTech Connect

    Masters, C.D.; Root, D.H.; Attanasi, E.D. )

    1990-01-01

    Welcome to uncertainty was the phrase Jack Schanz used to introduce both layman and professionals to the maze of petroleum energy data that must be comprehended to achieve understanding of this critical commodity. Schanz was referring to the variables as he and his colleagues with Resources for the Future saw them in those years soon after the energy-awakening oil embargo of 1973. In some respects, the authors have made progress in removing uncertainty from energy data, but in general, we simply must accept that there are many points of view and many ways for the blindman to describe the elephant. There can be definitive listing of all uncertainties, but for this paper the authors try to underscore those traits of petroleum occurrence and supply that the author's believe bear most heavily on the understanding of production and resource availability. Because oil and gas exist in nature under such variable conditions and because the products themselves are variable in their properties, the authors must first recognize classification divisions of the resource substances, so that the reader might always have a clear perception of just what we are talking about and how it relates to other components of the commodity in question.

  14. Production of haploids and doubled haploids in oil palm

    PubMed Central

    2010-01-01

    Background Oil palm is the world's most productive oil-food crop despite yielding well below its theoretical maximum. This maximum could be approached with the introduction of elite F1 varieties. The development of such elite lines has thus far been prevented by difficulties in generating homozygous parental types for F1 generation. Results Here we present the first high-throughput screen to identify spontaneously-formed haploid (H) and doubled haploid (DH) palms. We secured over 1,000 Hs and one DH from genetically diverse material and derived further DH/mixoploid palms from Hs using colchicine. We demonstrated viability of pollen from H plants and expect to generate 100% homogeneous F1 seed from intercrosses between DH/mixoploids once they develop female inflorescences. Conclusions This study has generated genetically diverse H/DH palms from which parental clones can be selected in sufficient numbers to enable the commercial-scale breeding of F1 varieties. The anticipated step increase in productivity may help to relieve pressure to extend palm cultivation, and limit further expansion into biodiverse rainforest. PMID:20929530

  15. Extraction of light filth from oriental fish products containing spice: collaborative study.

    PubMed

    Glaze, L E

    1993-01-01

    A collaborative study was conducted to validate a new method for the extraction of light filth from oriental fish products containing spice. A 100 g test portion is digested by boiling in a mixture of HCl, Igepal DM-710, and CO-730. Light filth is isolated by wet-sieving on a No. 230 plain-weave sieve with Tergitol, deaeration boiling in 40% isopropanol, and extracting with mineral oil-heptane (85 + 15) and 40% isopropanol in a Wildman trap flask. Three spiking levels for rat hairs and insect fragments were used in the study. For rat hairs, recoveries at the low, medium, and high levels averaged 80.0, 71.6, and 88.0%, respectively. Recoveries of insect fragments for low, medium, and high levels averaged 87.8, 83.7, and 89.4%, respectively. The method was adopted first action by AOAC International. PMID:8448443

  16. Biodiesel production from Jatropha oil by catalytic and non-catalytic approaches: an overview.

    PubMed

    Juan, Joon Ching; Kartika, Damayani Agung; Wu, Ta Yeong; Hin, Taufiq-Yap Yun

    2011-01-01

    Biodiesel (fatty acids alkyl esters) is a promising alternative fuel to replace petroleum-based diesel that is obtained from renewable sources such as vegetable oil, animal fat and waste cooking oil. Vegetable oils are more suitable source for biodiesel production compared to animal fats and waste cooking since they are renewable in nature. However, there is a concern that biodiesel production from vegetable oil would disturb the food market. Oil from Jatropha curcas is an acceptable choice for biodiesel production because it is non-edible and can be easily grown in a harsh environment. Moreover, alkyl esters of jatropha oil meet the standard of biodiesel in many countries. Thus, the present paper provides a review on the transesterification methods for biodiesel production using jatropha oil as feedstock. PMID:21094045

  17. Surfactant-enhanced alkaline flooding for light oil recovery. Final report

    SciTech Connect

    Wasan, D.T.

    1996-05-01

    In this report, we present the results of our experimental and theoretical studies in surfactant-enhanced alkaline flooding for light oil recovery. The overall objective of this work is to develop a very cost-effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12. 0) for ultimate spontaneous emulsification and ultralow interfacial tension. In addition, we have (1) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, (2) investigated the mechanisms for spontaneous emulsification, (3) developed a technique to monitor low water content in oil and (4) developed a technique to study water-in-oil emulsion film properties, (5) investigated the effect of surfactant on the equilibrium and transient interfacial tension, (6) investigated the kinetics of oil removal from a silica surface, and (7) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, accounting for added surfactant. The results of the studies conducted during the course of this project are discussed.

  18. Surfactant-enhanced alkaline flooding for light oil recovery. Final report 1994--1995

    SciTech Connect

    Wasan, D.T.

    1995-12-01

    In this report, the authors present the results of their experimental and theoretical studies in surfactant-enhanced alkaline flooding for light oil recovery. The overall objective of this work is to develop a very cost-effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12.0) for ultimate spontaneous emulsification and ultralow interfacial tension. In addition, the authors have (1) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, (2) investigated the mechanisms for spontaneous emulsification, (3) developed a technique to monitor low water content in oil, and (4) developed a technique to study water-in-oil emulsion film properties, (5) investigated the effect of surfactant on the equilibrium and transient interfacial tension, (6) investigated the kinetics of oil removal from a silica surface, and (7) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, accounting for added surfactant. The results of the studies conducted during the course of this project are summarized.

  19. A CO{sub 2}-based analysis of a light-oil steamflood at NPR-1, Elk Hills, CA

    SciTech Connect

    Shotts, D.R.; Senum, G.I.

    1992-12-01

    A steamdrive pilot was run on a light-oil reservoir at the Naval Petroleum Reserve No 1 (NPR1) in the Elk Hills oil field, Kern County, CA. The goal of this work was to establish a correlation between a documented growth in CO{sub 2} concentrations found in producing wells in the pilot area to the light-oil steamflood (LOSF); then to use a thermodynamic analysis of the expended energy to come up with an energy efficiency of the steamdrive.

  20. 76 FR 67201 - Information Collection Activities: Oil and Gas Production Safety Systems; Submitted for Office of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-31

    ... Production Safety Systems; Submitted for Office of Management and Budget (OMB) Review; Comment Request ACTION... the paperwork requirements in the regulations under Subpart H, ``Oil and Gas Production Safety Systems... H, Oil and Gas Production Safety Systems. Abstract: The Outer Continental Shelf (OCS) Lands Act,...

  1. Non-Edible Plant Oils as New Sources for Biodiesel Production

    PubMed Central

    Chhetri, Arjun B.; Tango, Martin S.; Budge, Suzanne M.; Watts, K. Chris; Islam, M. Rafiqul

    2008-01-01

    Due to the concern on the availability of recoverable fossil fuel reserves and the environmental problems caused by the use those fossil fuels, considerable attention has been given to biodiesel production as an alternative to petrodiesel. However, as the biodiesel is produced from vegetable oils and animal fats, there are concerns that biodiesel feedstock may compete with food supply in the long-term. Hence, the recent focus is to find oil bearing plants that produce non-edible oils as the feedstock for biodiesel production. In this paper, two plant species, soapnut (Sapindus mukorossi) and jatropha (jatropha curcas, L.) are discussed as newer sources of oil for biodiesel production. Experimental analysis showed that both oils have great potential to be used as feedstock for biodiesel production. Fatty acid methyl ester (FAME) from cold pressed soapnut seed oil was envisaged as biodiesel source for the first time. Soapnut oil was found to have average of 9.1% free FA, 84.43% triglycerides, 4.88% sterol and 1.59% others. Jatropha oil contains approximately 14% free FA, approximately 5% higher than soapnut oil. Soapnut oil biodiesel contains approximately 85% unsaturated FA while jatropha oil biodiesel was found to have approximately 80% unsaturated FA. Oleic acid was found to be the dominant FA in both soapnut and jatropha biodiesel. Over 97% conversion to FAME was achieved for both soapnut and jatropha oil. PMID:19325741

  2. Searching for a Safe Source of Castor Oil Production through Metabolic Engineering

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Castor oil contains 90% ricinoleate (12-hydroxy-oleate) which has numerous industrial uses. The production of castor oil is hampered by the presence of the toxin ricin and hyper-allergenic 2S albumins in its seed. We are developing a safe source of castor oil by two approaches: blocking gene expres...

  3. Non-edible plant oils as new sources for biodiesel production.

    PubMed

    Chhetri, Arjun B; Tango, Martin S; Budge, Suzanne M; Watts, K C; Islam, M R

    2008-02-01

    Due to the concern on the availability of recoverable fossil fuel reserves and the environmental problems caused by the use those fossil fuels, considerable attention has been given to biodiesel production as an alternative to petrodiesel. However, as the biodiesel is produced from vegetable oils and animal fats, there are concerns that biodiesel feedstock may compete with food supply in the long-term. Hence, the recent focus is to find oil bearing plants that produce non-edible oils as the feedstock for biodiesel production. In this paper, two plant species, soapnut (Sapindus mukorossi) and jatropha (jatropha curcas, L.) are discussed as newer sources of oil for biodiesel production. Experimental analysis showed that both oils have great potential to be used as feedstock for biodiesel production. Fatty acid methyl ester (FAME) from cold pressed soapnut seed oil was envisaged as biodiesel source for the first time. Soapnut oil was found to have average of 9.1% free FA, 84.43% triglycerides, 4.88% sterol and 1.59% others. Jatropha oil contains approximately 14% free FA, approximately 5% higher than soapnut oil. Soapnut oil biodiesel contains approximately 85% unsaturated FA while jatropha oil biodiesel was found to have approximately 80% unsaturated FA. Oleic acid was found to be the dominant FA in both soapnut and jatropha biodiesel. Over 97% conversion to FAME was achieved for both soapnut and jatropha oil. PMID:19325741

  4. 40 CFR 721.9460 - Tall oil fatty acids, reaction products with polyamines, alkyl substituted.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.9460 Tall oil fatty acids, reaction... reporting. (1) The chemical substance identified generically as tall oil fatty acids, reaction products with... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Tall oil fatty acids,...

  5. 40 CFR 721.9460 - Tall oil fatty acids, reaction products with polyamines, alkyl substituted.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.9460 Tall oil fatty acids, reaction... reporting. (1) The chemical substance identified generically as tall oil fatty acids, reaction products with... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Tall oil fatty acids,...

  6. 40 CFR 721.9460 - Tall oil fatty acids, reaction products with polyamines, alkyl substituted.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.9460 Tall oil fatty acids, reaction... reporting. (1) The chemical substance identified generically as tall oil fatty acids, reaction products with... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Tall oil fatty acids,...

  7. 40 CFR 721.9460 - Tall oil fatty acids, reaction products with polyamines, alkyl substituted.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.9460 Tall oil fatty acids, reaction... reporting. (1) The chemical substance identified generically as tall oil fatty acids, reaction products with... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Tall oil fatty acids,...

  8. 40 CFR 721.9460 - Tall oil fatty acids, reaction products with polyamines, alkyl substituted.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.9460 Tall oil fatty acids, reaction... reporting. (1) The chemical substance identified generically as tall oil fatty acids, reaction products with... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Tall oil fatty acids,...

  9. Biodiesel Production from Chlorella protothecoides Oil by Microwave-Assisted Transesterification

    PubMed Central

    Gülyurt, Mustafa Ömer; Özçimen, Didem; İnan, Benan

    2016-01-01

    In this study, biodiesel production from microalgal oil by microwave-assisted transesterification was carried out to investigate its efficiency. Transesterification reactions were performed by using Chlorella protothecoides oil as feedstock, methanol, and potassium hydroxide as the catalyst. Methanol:oil ratio, reaction time and catalyst:oil ratio were investigated as process parameters affected methyl ester yield. 9:1 methanol/oil molar ratio, 1.5% KOH catalyst/oil ratio and 10 min were optimum values for the highest fatty acid methyl ester yield. PMID:27110772

  10. Biodiesel Production from Chlorella protothecoides Oil by Microwave-Assisted Transesterification.

    PubMed

    Gülyurt, Mustafa Ömer; Özçimen, Didem; İnan, Benan

    2016-01-01

    In this study, biodiesel production from microalgal oil by microwave-assisted transesterification was carried out to investigate its efficiency. Transesterification reactions were performed by using Chlorella protothecoides oil as feedstock, methanol, and potassium hydroxide as the catalyst. Methanol:oil ratio, reaction time and catalyst:oil ratio were investigated as process parameters affected methyl ester yield. 9:1 methanol/oil molar ratio, 1.5% KOH catalyst/oil ratio and 10 min were optimum values for the highest fatty acid methyl ester yield. PMID:27110772

  11. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    DOE PAGESBeta

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen rangedmore » from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.« less

  12. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    SciTech Connect

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen ranged from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.

  13. Surfactant-enhanced alkaline flooding for light oil recovery. [Annual report], 1993--1994

    SciTech Connect

    Wasan, D.T.

    1995-03-01

    In this report, we present the results of our experimental and theoretical studies in surfactant-enhanced alkaline flooding for light oil recovery. The overall objective of this work is to develop a very cost-effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12.0) for ultimate spontaneous emulsification and ultralow interfacial tension. In addition, we have (1) investigated the effect of surfactant on the equilibrium and transient interfacial tension, (2) investigated the kinetics of oil removal from a silica surface, and (3) developed a theoretical interfacial activity model for determining equilibrium interfacial tension. The results of the studies conducted during the course of this project are presented.

  14. Microbial production of polyhydroxyalkanoates by bacteria isolated from oil wastes.

    PubMed

    Wong, A L; Chua, H; Yu, P H

    2000-01-01

    A Gram-positive coccus-shaped bacterium capable of synthesizing higher relative molecular weight (M(r)) poly-hydroxybutyrate (PHB) was isolated from sesame oil and identified as Staphylococcus epidermidis (by Microbial ID, Inc., Newark, NJ). The experiment was conducted by shake flask fermentation culture using media containing fructose. Cell growth up to a dry mass of 2.5 g/L and PHB accumulation up to 15.02% of cell dry wt was observed. Apart from using single carbohydrate as a sole carbon source, various industrial food wastes including sesame oil, ice cream, malt, and soya wastes were investigated as nutrients for S. epidermidis to reduce the cost of the carbon source. As a result, we found that by using malt wastes as nutrient for cell growth, PHB accumulation of S. epidermidis was much better than using other wastes as nutrient source. The final dried cell mass and PHB production using malt wastes were 1.76 g/L and 6.93% polymer/cells (grams/gram), and 3.5 g/L and 3.31% polymer/cells (grams/gram) in shake flask culture and in fermentor culture, respectively. The bacterial polymer was characterized by 1H-nuclear magnetic resonance (NMR), 13C-NMR, Fourier transform infrared, and differential scanning calorimetry. The results show that with different industrial food wastes as carbon and energy sources, the same biopolymer (PHB) was obtained. However, the use of sesame oil as the carbon source resulted in the accumulation of PHB with a higher melting point than that produced from other food wastes as carbon sources by this organism under similar experimental conditions. PMID:10849842

  15. CO2 Enhanced Oil Recovery from the Residual Zone - A Sustainable Vision for North Sea Oil Production

    NASA Astrophysics Data System (ADS)

    Stewart, Jamie; Haszeldine, Stuart; Wilkinson, Mark; Johnson, Gareth

    2014-05-01

    This paper presents a 'new vision for North Sea oil production' where previously unattainable residual oil can be produced with the injection of CO2 that has been captured at power stations or other large industrial emitters. Not only could this process produce incremental oil from a maturing basin, reducing imports, it also has the capability to store large volumes of CO2 which can offset the emissions of additional carbon produced. Around the world oil production from mature basins is in decline and production from UK oil fields peaked in 1998. Other basins around the world have a similar story. Although in the UK a number of tax regimes, such as 'brown field allowances' and 'new field allowances' have been put in place to re-encourage investment, it is recognised that the majority of large discoveries have already been made. However, as a nation our demand for oil remains high and in the last decade imports of crude oil have been steadily increasing. The UK is dependent on crude oil for transport and feedstock for chemical and plastics production. Combined with the necessity to provide energy security, there is a demand to re-assess the potential for CO2 Enhanced Oil Recovery (CO2-EOR) in the UK offshore. Residual oil zones (ROZ) exist where one of a number of natural conditions beyond normal capillary forces have caused the geometry of a field's oil column to be altered after filling [1]. When this re-structuring happens the primary interest to the hydrocarbon industry has in the past been in where the mobile oil has migrated to. However it is now considered that significant oil resource may exist in the residual zone play where the main oil column has been displaced. Saturations within this play are predominantly close to residual saturation (Sr) and would be similar to that of a water-flooded field [2]. Evidence from a number of hydrocarbon fairways shows that, under certain circumstances, these residual zones in US fields are comparable in thickness to the

  16. Thin Film Packaging Solutions for High Efficiency OLED Lighting Products

    SciTech Connect

    2008-06-30

    The objective of the 'Thin Film Packaging Solutions for High Efficiency OLED Lighting Products' project is to demonstrate thin film packaging solutions based on SiC hermetic coatings that, when applied to glass and plastic substrates, support OLED lighting devices by providing longer life with greater efficiency at lower cost than is currently available. Phase I Objective: Demonstrate thin film encapsulated working phosphorescent OLED devices on optical glass with lifetime of 1,000 hour life, CRI greater than 75, and 15 lm/W. Phase II Objective: Demonstrate thin film encapsulated working phosphorescent OLED devices on plastic or glass composite with 25 lm/W, 5,000 hours life, and CRI greater than 80. Phase III Objective: Demonstrate 2 x 2 ft{sup 2} thin film encapsulated working phosphorescent OLED with 40 lm/W, 10,000 hour life, and CRI greater than 85. This report details the efforts of Phase III (Budget Period Three), a fourteen month collaborative effort that focused on optimization of high-efficiency phosphorescent OLED devices and thin-film encapsulation of said devices. The report further details the conclusions and recommendations of the project team that have foundation in all three budget periods for the program. During the conduct of the Thin Film Packaging Solutions for High Efficiency OLED Lighting Products program, including budget period three, the project team completed and delivered the following achievements: (1) a three-year marketing effort that characterized the near-term and longer-term OLED market, identified customer and consumer lighting needs, and suggested prototype product concepts and niche OLED applications lighting that will give rise to broader market acceptance as a source for wide area illumination and energy conservation; (2) a thin film encapsulation technology with a lifetime of nearly 15,000 hours, tested by calcium coupons, while stored at 16 C and 40% relative humidity ('RH'). This encapsulation technology was characterized

  17. The implications of the declining energy return on investment of oil production.

    PubMed

    Murphy, David J

    2014-01-13

    Declining production from conventional oil resources has initiated a global transition to unconventional oil, such as tar sands. Unconventional oil is generally harder to extract than conventional oil and is expected to have a (much) lower energy return on (energy) investment (EROI). Recently, there has been a surge in publications estimating the EROI of a number of different sources of oil, and others relating EROI to long-term economic growth, profitability and oil prices. The following points seem clear from a review of the literature: (i) the EROI of global oil production is roughly 17 and declining, while that for the USA is 11 and declining; (ii) the EROI of ultra-deep-water oil and oil sands is below 10; (iii) the relation between the EROI and the price of oil is inverse and exponential; (iv) as EROI declines below 10, a point is reached when the relation between EROI and price becomes highly nonlinear; and (v) the minimum oil price needed to increase the oil supply in the near term is at levels consistent with levels that have induced past economic recessions. From these points, I conclude that, as the EROI of the average barrel of oil declines, long-term economic growth will become harder to achieve and come at an increasingly higher financial, energetic and environmental cost. PMID:24298084

  18. Oil flotation extraction of light filth from ground capsicums excluding paprika: collaborative study.

    PubMed

    Thrasher, J J; Colliflower, E J

    1978-07-01

    A collaborative study has been completed on an improved method for the isolation of light filth from ground capsicums other than paprika. The proposed method involves isopropanol pretreatment, wet-sieving, and extraction from cooled 60% ethanol with a mineral oil-heptane mixture. The collaborative tests by the proposed method showed an approximate 2-fold increase in recoveries of insect fragments and rodent hairs with acceptable coefficients of variation and clean filter papers. The proposed method has been adopted as official first action to replace 44.123. PMID:681260

  19. On-farm production of soybean oil and its properties as a fuel

    SciTech Connect

    Suh, S.R.

    1983-01-01

    This study presents the design of a system for on-farm production of soybean oil for use as a fuel in compression ignition engines. The soybean oil production system consists of a heat exchanger to heat the beans with the exhaust gas of an engine, a screw press and a system for water degumming and drying the expressed crude oil. Optimum parameters of the oil production system were found. The rheological properties of soybean oil, ester of soybean oil and blends of the above with diesel fuel and diesel fuel additives are given. Data on soybean temperature, outlet gas temperature and thermal efficiency were obtained from a developed mathematical model of the heat exchanger. Chemical analyses show that crude oil from the press is similar to that of commercially degummed oil. The degumming process is not needed for the crude oil to be used as a fuel in compression ignition engines. Rheological properties of the soybean oil and soybean oil diesel fuel mixture show that the fluids have viscosities of time independent characteristics and are Newtonian fluids. Diesel fuel additives having low viscosities can be used to lower the viscosity of soybean oil and blends with diesel fuel but the effect is insignificant.

  20. National voluntary laboratory accreditation program: Energy efficient lighting products. Handbook

    SciTech Connect

    Galowin, L.S.; Hall, W.; Rossiter, W.J.

    1994-07-01

    The purpose of this handbook is to set out procedures and technical requirements for the National Voluntary Laboratory Accreditation Program (NVLAP) accreditation of laboratories which perform test methods covered by the Energy Efficient Lighting (EEL) Products program. It complements and supplements the NVLAP programmatic procedures and general requirements found in NIST Handbook 150 (PB94-178225). The interpretive comments and additional requirements contained in this handbook make the general NVLAP criteria specifically applicable to the EEL program.

  1. Financial incentives for marginal oil and gas production

    SciTech Connect

    Terzian, G.A.; Enright, J.M.; Brashear, J.P.

    1995-12-31

    Congress and the Administration are considering Federal tax incentives to improve the economics of marginal oil and gas wells. The effectiveness of these will depend on the specific provisions of the incentive, primarily whether they can be used by the large percentage of marginal well operators in AMT or without taxable income. Comprehensive assessment of Federal marginal well incentives requires a methodology that accounts for the diversity of marginal production operations. This paper presents a marginal well database, model, and methodology designed specifically to assess the costs and benefits of Federal tax incentives for marginal wells. Selected results are presented, along with general conclusions about Federal marginal well tax incentives based on numerous analyses.

  2. Ultrasound-assisted biodiesel production from Camelina sativa oil.

    PubMed

    Sáez-Bastante, J; Ortega-Román, C; Pinzi, S; Lara-Raya, F R; Leiva-Candia, D E; Dorado, M P

    2015-06-01

    The main drawbacks of biodiesel production are high reaction temperatures, stirring and time. These could be alleviated by aiding transesterification with alternative energy sources, i.e. ultrasound (US). In this study, biodiesel was obtained from Camelina sativa oil, aided with an ultrasonic probe (20kHz, 70% duty cycle, 50% amplitude). Design of experiments included the combination of sonication and agitation cycles, w/wo heating (50°C). To gain knowledge about the implications of the proposed methodology, conventional transesterification was optimized, resulting in higher needs on catalyst concentration and reaction time, compared to the proposed reaction. Although FAME content met EN 14103 standard, FAME yields were lower than those provided by US-assisted transesterification. Energy consumption measurements showed that ultrasound assisted transesterification required lower energy, temperature, catalyst and reaction time. PMID:25768413

  3. Effects of Cymbopogon citratus L. essential oil on the growth, morphogenesis and aflatoxin production of Aspergillus flavus ML2-strain.

    PubMed

    Helal, G A; Sarhan, M M; Abu Shahla, A N K; Abou El-Khair, E K

    2007-02-01

    The mycelial growth of Aspergillus flavus Link was completely inhibited using 1.5 (microl/ml or 2.0 (microl/ml of Cymbopogon citratus essential oil applied by fumigation or contact method in Czapek's liquid medium, respectively. This oil was found also to be fungicidal at the same concentrations. The sublethal doses 1.0 and 1.5 (microl/ml inhibited about 65% of fungal growth after five days of incubation and delayed conidiation as compared with the control. Microscopic observations using Light Microscope (LM), Scanning Electron Microscope (SEM) and Transmission Electron Microscope (TEM) were carried out to determine the ultra structural modifications of A. flavus hyphae after treatment with C. citratus essential oil. The hyphal diameter decreased and hyphal wall appeared as precipitates and disappeared in some regions. This oil also caused plasma membrane disruption and mitochondrial structure disorganization. Moreover, Ca(+2), K(+) and Mg(+2) leakages increased from the fumigated mycelium and its total lipid content decreased, while the saturated and unsaturated fatty acids increased. One of the most important results obtained during this study was the ability of C. citratus essential oil at its sublethal dose to completely inhibit aflatoxin B(1) production from A. flavus. These findings increase the possibility of exploiting C. citratus essential oil as an effective inhibitor of biodegradation and storage contaminating fungi and also in fruit juice preservation. PMID:17304618

  4. Development of oil product toxicity benchmarks using SSDs

    EPA Science Inventory

    Determining the sensitivity of a diversity of species to spilled oil and chemically dispersed oil continues to be a significant challenge in spill response and impact assessment. We developed species sensitivity distributions (SSDs) of acute toxicity values using standardized te...

  5. Production and characterization of pyrolytic oils by pyrolysis of waste machinery oil.

    PubMed

    Sinağ, Ali; Gülbay, Selen; Uskan, Burçin; Uçar, Suat; Ozgürler, Sara Bilge

    2010-01-15

    The main objective of this work is to propose an alternative method for evaluation of the waste machinery oil which is an environmental problem in Turkey. For this purpose, pyrolysis of waste machinery oil was conducted in a tubular reactor. Effect of the experimental conditions (various temperatures, catalyst type) on the formation of pyrolytic oil, gas, and char was investigated. Nickel supported on silica and zeolite (HZSM-5) were used as catalysts. Properties of the pyrolytic oils were characterized by gas chromatograph equipped with a mass selective detector (GC-MS), gas chromatography with flame ionization detector (GC-FID for boiling point range distribution), nuclear magnetic resonance ((1)H NMR) spectroscopy, higher heating value measurement, and elemental analysis. The behavior of the metals in the waste machinery oil and the pyrolytic oil samples was also quantitatively detected by inductively coupled plasma (ICP) analysis. As, Cd and Cr contents of the all pyrolytic oils were found as <0.05 ppm, while Cu content of the pyrolytic oils varied between 0.3 ppm and 0.61 ppm. Only Vanadium contents of the pyrolytic oils obtained at 800 degrees C (0.342 ppm) and in the presence of HZSM5 (0.57 ppm) increased compared to that obtained by waste machinery oil (0.1 ppm). Lower metal contents of the pyrolytic oils reveal that pyrolysis of the waste machinery oils leads to the formation of environmental friendly pyrolytic oils with higher heating values. PMID:19744779

  6. Mineral oil extraction of light filth from rubbed sage: collaborative study.

    PubMed

    Colliflower, E J; Thrasher, J J

    1979-05-01

    The official methods for extracting light filth from rubbed sage, 44.D08--44.D10, specifies a hot isopropanol pretreatment and flotation from cooled dilute isopropanol with mineral oil to extract light filth. The method gives good recoveries, but occasionally excessive interfering plant material is extracted along with the filth elements. A new method has been developed in which chloroform is used for pretreatment instead of isopropanol, and Tween 80-EDTA is added twice rather than once. This method has given consistently cleaner filter papers and better recoveries for rodent hairs, 85 vs. 79%, and for elytral squares, 95 vs. 84%. The new method has been adopted as official first action. PMID:479084

  7. Studies on the lipophilicity of vehicles (or co-vehicles) and botanical oils used in cosmetic products.

    PubMed

    Mbah, C J

    2007-05-01

    The lipophilic character of five vehicles (or co-vehicles): diethylhexylmaleate, dimethicone, light mineral oil, octyldodecanol and oleyl alcohol and eight botanical oils: Aloe vera oil, coconut oil, extra virgin olive oil, grape leaf oil, grape seed oil, hazelnut oil, jojoba oil and safflower oil was determined by partitioning esters of p-hydroxybenzoic acid (parabens) between them and phosphate buffer (pH 7.4). The results were compared to those obtained with 1-octanol. The most lipophilic effects were observed with octyldodecanol and oleyl alcohol for the vehicles (or co-vehicles), coconut oil, jojoba oil and safflower oil for botanical oils. Light mineral oil showed the least lipophilic effect. With butylparaben, it was observed that oleyl alcohol, octyldodecanol, coconut oil and jojoba oil were 0.94, 0.91, 0.74 and 0.68 times as lipophilic as 1-octanol respectively. The study indicates that octyldodecanol and oleyl alcohol could be good substitutes for 1-octanol in partition coefficient determination. The estimated permeability coefficients of the parabens suggest that octyldodecanol, oleyl alcohol, coconut oil and jojoba oil could be potential dermal permeation enhancers. PMID:17557742

  8. An evaluation of oil spill responses for offshore oil production projects in Newfoundland and Labrador, Canada: Implications for seabird conservation.

    PubMed

    Fraser, Gail S; Racine, Vincent

    2016-06-15

    Seabirds are vulnerable to oil pollution, particularly in cold-water regions. We investigated the response of small spills (<7.95m(3)) at offshore production platforms in Newfoundland, a region recognized for seabird diversity and abundance. In three environmental assessments for oil production operations Environment Canada requested monitoring and mitigation of small spills potentially impacting seabird populations; suggestions supported by two independent reviews. An industry spill response plan states that operators would collect systematic observations on spills and deploy countermeasures where possible. Operators' spill reports were obtained under an Access to Information request. There were 220 daytime spills with sheens (out of 381 spills; 1997-2010). Of these, six reported time to oil dispersion and eleven the presence or absence of seabirds. Industry self-reporting has not permitted an evaluation of the impact of chronic oil spills on seabirds. We recommend that independent observers be placed on platforms to systematically collect data on spills and seabirds. PMID:27131965

  9. Processing use, and characterization of shale oil products

    PubMed Central

    Decora, Andrew W.; Kerr, Robert D.

    1979-01-01

    Oil shale is a potential source of oil that will supplement conventional sources for oil as our needs for fossil fuels begin to exceed our supplies. The resource may be mined and processed on the surface or it may be processed in situ. An overview of the potential technologies and environmental issues is presented. PMID:446454

  10. Production of Lipase and Oxygenated Fatty Acids from Vegetable Oils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Vegetable oils such as soybean oil and corn oil are cheap raw materials. Various value-added oxygenated fatty acids have been produced from unsaturated fatty acids such as oleic and linoleic acid by biotransformation. Lipase from the non-pathogenic yeast Candida cylindracea is another important va...

  11. The social and environmental context of argan oil production.

    PubMed

    de Waroux, Yann le Polain

    2013-01-01

    In recent decades, argan oil has become one of the most expensive cosmetic oils on world markets. This review outlines the social and environmental context of the argan boom, highlighting its consequences on local livelihoods and conservation. It examines the claims that the argan oil boom has benefited the local population and that it encourages the conservation of argan woodlands. PMID:23472447

  12. A test for evaluating the toxicity of oils, dispersants, and oil biodegradation products to embryos of grass shrimp (Palaemonetes pugio)

    SciTech Connect

    Foss, S.S.; Fisher, W.S.; Chapman, P.J.; Shelton, M.

    1994-12-31

    A test has been developed to determine the toxicity of oil, commercial oil dispersants, and oil biodegradation products to embryos of the grass shrimp, Palaemonetes pugio. The system has several advantages over traditional toxicity tests: Embryos are exposed separately in glass tubes eliminating interaction between individuals, they do not require feeding, are easily examined, and require low volumes of test toxicant. Additionally, tests can be performed using artificial sea salts and adult P. pugio can be maintained and cultured year round in the laboratory. Toxicity tests demonstrated that oil dispersants increased the toxicity of the water-soluble fraction of No. 2 Fuel Oil with estimated LC50 values approximating those obtained with the 7d chronic tests using Mysidopsis bahia. Embryos exposed to neutral fractions derived by microbial degradation of weathered Prudhoe Bay crude oil showed toxicity of metabolic products at relatively low concentrations and cause virtually 100% mortality within a narrow time interval. P. pugio embryos were especially responsive to oil metabolites, exhibiting high sensitivity and low variability. All tests showed a consistently high survival (90--100%) of control embryos to hatch under a variety of temperatures and salinities; embryos at any given test condition usually hatched within 24h of one another.

  13. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    SciTech Connect

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies would result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs.

  14. Nigerian bonny light crude oil induces endocrine disruption in male rats.

    PubMed

    Adedara, Isaac A; Ebokaiwe, Azubike P; Mathur, Premendu P; Farombi, Ebenezer O

    2014-04-01

    Exposure to Nigerian bonny light crude oil (BLCO) in the southern part of Nigeria has been reported to be associated with reproductive toxicity, but there is paucity of information on its interference with steroidogenesis. This study investigated the influence of BLCO on testicular steroidogenesis and plasma levels of hormones from the pituitary and thyroid components of the brain-pituitary-testicular axis. Adult male Wistar rats were orally treated with BLCO dissolved in corn oil at 0, 200 and 800 mg/kg for 7 days. Immunoblot analysis revealed that BLCO exposure suppressed steroid acute regulatory protein and androgen-binding protein expression with concomitant decrease in 3β-hydroxysteroid dehydrogenase (HSD) and 17β-hydroxysteroid dehydrogenase activities. BLCO exposure significantly decreased plasma concentrations of follicle-stimulating hormone, luteinizing hormone, prolactin and intratesticular testosterone, but elevated thyrotropin, triiodothyronine and thyroxine above the control values. The data presented herein indicate that undue exposure to BLCO has an inhibitory effect on testicular steroidogenesis. The underlying mechanisms for BLCO-induced testicular dysfunction may involve its disruptive effect on the brain-pituitary-testicular axis. These observations highlight the potential risk to public health for a population where, unfortunately, oil spillages occur frequently. PMID:24171665

  15. 78 FR 52239 - Oil and Gas and Sulphur Operations on the Outer Continental Shelf-Oil and Gas Production Safety...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-22

    ... current regulations were originally published on April 1, 1988 (53 FR 10690). Since that time, various..., well completions associated with offshore production platforms are characterized as either dry tree... a well casinghead used to control the production and flow of oil or gas. Dry tree completions...

  16. From heavy oils to marketable products: IFP proposes new schemes for maximum conversion

    SciTech Connect

    Peries, J.P.; Billon, A.; Hennico, A.

    1995-12-31

    The conversion of atmospheric or vacuum residues into light distillates (naphtha, diesel oil) is the solution to eliminate the increasing excess of high sulfur heavy fuels. Two general families of processes are used: (1) Processes that utilize thermal cracking, such as visbreaking (VB) or coking (CK), to convert mainly vacuum residues into lighter products. (2) Catalytic cracking processes, such as fluid catalytic cracking (FCC) without hydrogen or hydrocracking (HDC) in the presence of hydrogen, to convert essentially vacuum gas-oils (VGO) into lighter, more valuable materials. Fluid catalytic cracking and hydrocracking processes use catalysts with an acid carrier. Consequently, these catalysts can easily be poisoned through excessive coking or metal deposition. Asphaltenes in feed to FCC or HDC processes polymerize and deposit on the catalyst as coke, inhibiting the catalyst activity. Metals (primarily Ni or V) deposit in the catalyst pore volume, resulting in less surface area available on the catalyst, causing increased catalyst usage and deteriorating product selectivity. To remove the asphaltenes and metals, two feed pretreatment processes can be considered. Solvent deasphalting removes most of the metals and asphaltenes. IFP`s Solvahl process will be described in this paper for solvent deasphalting of residues. Alternatively, IFP`s fixed bed demetallization catalysts used in conjunction with the Hyvahl process can improve feed quality for residue FCC.

  17. A multi-criteria analysis approach for ranking and selection of microorganisms for the production of oils for biodiesel production.

    PubMed

    Ahmad, Farah B; Zhang, Zhanying; Doherty, William O S; O'Hara, Ian M

    2015-08-01

    Oleaginous microorganisms have potential to be used to produce oils as alternative feedstock for biodiesel production. Microalgae (Chlorella protothecoides and Chlorella zofingiensis), yeasts (Cryptococcus albidus and Rhodotorula mucilaginosa), and fungi (Aspergillus oryzae and Mucor plumbeus) were investigated for their ability to produce oil from glucose, xylose and glycerol. Multi-criteria analysis (MCA) using analytic hierarchy process (AHP) and preference ranking organization method for the enrichment of evaluations (PROMETHEE) with graphical analysis for interactive aid (GAIA), was used to rank and select the preferred microorganisms for oil production for biodiesel application. This was based on a number of criteria viz., oil concentration, content, production rate and yield, substrate consumption rate, fatty acids composition, biomass harvesting and nutrient costs. PROMETHEE selected A. oryzae, M. plumbeus and R. mucilaginosa as the most prospective species for oil production. However, further analysis by GAIA Webs identified A. oryzae and M. plumbeus as the best performing microorganisms. PMID:25958151

  18. Contaminants, water quality, and wildlife mortality on oil production sites in western South Dakota. Interim report

    SciTech Connect

    Henry, C.J.; Ruelle, R.

    1993-04-01

    The objectives of the study were to evaluate oil pits and other hazards at oil production sites to (1) document the magnitude of wildlife mortality due to exposure to oil and other chemicals, (2) determine the physical and toxic effects of oil pit contents on wildlife, and (3) identify methods to prevent sublethal and lethal impacts to wildlife. Pits at oil production sites in Fall River and Harding Counties of western South Dakota were surveyed for wildlife carcasses by searching the shorelines and raking underwater around the pit edges in April, July, and October 1992. In July, composite water and sediment samples were collected from 26 pits, and analyzed for oil and grease. Bioassays were conducted with two life stages of Hyalella azteca and Daphnia magna to determine pit water toxicity. Seed germination tests were conducted using radish seeds exposed to pit water. Oil and poor water quality appeared to be the primary causes of pit liquid toxicity.

  19. Production of bio-oil from alfalfa stems by fluidized-bed fast pyrolysis

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This study focused on the production of bio-oil from alfalfa stem material. Two alfalfa maturity stages, harvested at early bud and full flower stages of development, were examined to evaluate the impact of variation in cell wall polysaccharide and lignin content on pyrolysis oil yields, production ...

  20. LABORATORY EVALUATION OF OIL SPILL BIOREMEDIATION PRODUCTS IN SALT AND FRESHWATER SYSTEMS

    EPA Science Inventory

    Ten oil spill bioremediation products were tested in the laboratory for their ability to enhance biodegradation of weathered Alaskan North Slope crude oil in both fresh and salt-water media. The products included: nutrients to stimulate inoculated microorganisms, nutrients plus a...

  1. 77 FR 68144 - Information Collection Activities: Oil and Gas Production Measurement, Surface Commingling, and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-11-15

    ... Production Measurement, Surface Commingling, and Security; Proposed Collection; Comment Request ACTION: 60... requirements in the regulations under Subpart L, Oil and Gas Production Measurement, Surface Commingling, and... this ICR. SUPPLEMENTARY INFORMATION: Title: 30 CFR Part 250, subpart L, Oil and Gas...

  2. 25 CFR 211.41 - Rentals and production royalty on oil and gas leases.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 25 Indians 1 2013-04-01 2013-04-01 false Rentals and production royalty on oil and gas leases. 211.41 Section 211.41 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEASING OF TRIBAL LANDS FOR MINERAL DEVELOPMENT Rents, Royalties, Cancellations and Appeals § 211.41 Rentals and production royalty on oil and...

  3. Detection and quantification of fugitive emissions from Colorado oil and gas production operations using remote monitoring

    EPA Science Inventory

    Western states contain vast amounts of oil and gas production. For example, Weld County Colorado contains approximately 25,000 active oil and gas well sites with associated production operations. There is little information on the air pollutant emission potential from this source...

  4. 25 CFR 212.41 - Rentals and production royalty on oil and gas leases.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false Rentals and production royalty on oil and gas leases. 212... Rentals and production royalty on oil and gas leases. (a) A lessee shall pay, in advance, beginning with... CFR chapter II, subchapters A and C. If the valuation provisions in the lease are inconsistent...

  5. 25 CFR 212.41 - Rentals and production royalty on oil and gas leases.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 25 Indians 1 2012-04-01 2011-04-01 true Rentals and production royalty on oil and gas leases. 212... Rentals and production royalty on oil and gas leases. (a) A lessee shall pay, in advance, beginning with... CFR chapter II, subchapters A and C. If the valuation provisions in the lease are inconsistent...

  6. 25 CFR 212.41 - Rentals and production royalty on oil and gas leases.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 25 Indians 1 2011-04-01 2011-04-01 false Rentals and production royalty on oil and gas leases. 212... Rentals and production royalty on oil and gas leases. (a) A lessee shall pay, in advance, beginning with... CFR chapter II, subchapters A and C. If the valuation provisions in the lease are inconsistent...

  7. 25 CFR 212.41 - Rentals and production royalty on oil and gas leases.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 25 Indians 1 2013-04-01 2013-04-01 false Rentals and production royalty on oil and gas leases. 212... Rentals and production royalty on oil and gas leases. (a) A lessee shall pay, in advance, beginning with... CFR chapter II, subchapters A and C. If the valuation provisions in the lease are inconsistent...

  8. Solvent fractionation of rice bran oil to produce a spreadable rice bran product

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Rice bran oil is becoming increasingly popular as a functional ingredient, due to its high stability and health benefits. We detail here a new extraction procedure for the production of a spreadable product derived from rice bran oil. Four different experimental conditions for extraction yielded f...

  9. Results on studies of soot production and fouling in oil-fired condensing systems

    SciTech Connect

    Butcher, T.; Celebi, Y.; Piraino, M.; McDonald, R.

    1986-01-01

    The development of condensing heat exchangers for oil-fired heating equipment would yield a significant improvement in thermal efficiency. Soot production by oil burners, however, could lead to fouling problems in these systems. Results are reported on tests done to evaluate the effect of operating conditions on start-up and shutdown smoke production in both noncondensing and condensing furnaces.

  10. U.S. Crude Oil Production to 2025: Updated Projection of Crude Types

    EIA Publications

    2015-01-01

    This report updates and extends a May 2014 EIA report, U.S. crude oil production forecast – analysis of crude types. It provides a projection of domestic crude oil production by crude type through 2025, supplementing the overall production projection provided in the AEO2015. Projections of production by crude type matter for several reasons. First, U.S. crude streams vary widely in quality. Second, the economics surrounding various options for the domestic use of additional domestic oil production are directly dependent on crude quality characteristics. Third, actual or potential export values also vary significantly with quality characteristics.

  11. Amphiphilic siderophore production by oil-associating microbes.

    PubMed

    Kem, Michelle P; Zane, Hannah K; Springer, Stephen D; Gauglitz, Julia M; Butler, Alison

    2014-06-01

    The Deepwater Horizon oil spill in 2010 released an unprecedented amount of oil into the ocean waters of the Gulf of Mexico. As a consequence, bioremediation by oil-degrading microbes has been a topic of increased focus. One factor limiting the rate of hydrocarbon degradation by microbial communities is the availability of necessary nutrients, including iron. The siderophores produced from two Vibrio spp. isolated from the Gulf of Mexico following the Deepwater Horizon oil spill, along with the well-studied oil-degrading microbe, Alcanivorax borkumensis SK2, are studied under iron-limiting conditions. Here we report the amphiphilic amphibactin siderophores produced by the oil-associated bacteria, Vibrio sp. S1B, Vibrio sp. S2A and Alcanivorax borkumensis SK2. These findings provide insight into oil-associating microbial iron acquisition. PMID:24663669

  12. Light flavour hadron production in the ALICE experiment at LHC

    NASA Astrophysics Data System (ADS)

    Badalà, Angela

    2016-05-01

    Unique among the LHC experiments, ALICE has excellent particle identification capabilities for the measurement of light-flavour hadrons. A large number of hadron species from pions to multi-strange baryons and light nuclei have been measured over a large transverse momentum region. The measurement of the production of these particles is a valuable tool to study the properties of the medium formed in heavy-ion collisions. In particular they give information on the collective phenomena of the fireball, on the parton energy loss in the hot QCD medium and on the hadronization mechanisms such as recombination and statistical hadronization. The measurements in pp and in p-nucleus collisions provide the necessary baseline for heavy-ion data and help to investigate the effects of the ordinary nuclear matter. In this paper some of the main ALICE results on identified light-flavour hadron production in Pb-Pb collisions at √sNN = 2.76 TeV and p-Pb collisions at √sNN = 5.02 TeV will be presented.

  13. Remote and Onsite Direct Measurement of Emissions from Oil and Natural Gas Production

    EPA Science Inventory

    Environmentally responsible oil and gas production requires accurate knowledge of emissions from long-term production operations1, which can include methane, volatile organic compounds, and hazardous air pollutants. Well pad emissions vary based on the geologically-determined com...

  14. Remote and Onsite Direct Measurements of Emissions from Oil and Natural Gas Production

    EPA Science Inventory

    Environmentally responsible oil and gas production requires accurate knowledge of emissions from long-term production operations1, which can include methane, volatile organic compounds, and hazardous air pollutants. Well pad emissions vary based on the geologically-determined com...

  15. Environmental benefits of advanced oil and gas exploration and production technology

    SciTech Connect

    1999-10-01

    THROUGHOUT THE OIL AND GAS LIFE CYCLE, THE INDUSTRY HAS APPLIED AN ARRAY OF ADVANCED TECHNOLOGIES TO IMPROVE EFFICIENCY, PRODUCTIVITY, AND ENVIRONMENTAL PERFORMANCE. THIS REPORT FOCUSES SPECIFICALLY ON ADVANCES IN EXPLORATION AND PRODUCTION (E&P) OPERATIONS.

  16. Therapeutic switching: from antidermatophytic essential oils to new leishmanicidal products

    PubMed Central

    Houël, Emeline; Gonzalez, German; Bessière, Jean-Marie; Odonne, Guillaume; Eparvier, Véronique; Deharo, Eric; Stien, Didier

    2015-01-01

    This study examined whether the antidermatophytic activity of essential oils (EOs) can be used as an indicator for the discovery of active natural products against Leishmania amazonensis. The aerial parts of seven plants were hydrodistilled. Using broth microdilution techniques, the obtained EOs were tested against three strains of dermatophytes (Trichophyton mentagrophytes, Microsporum gypseum and Microsporum canis). To compare the EOs antifungal and antiparasitic effects, the EOs activities against axenic amastigotes of L. amazonensis were concurrently evaluated. For the most promising EOs, their antileishmanial activities against parasites infecting peritoneal macrophages of BALB/c mice were measured. The most interesting antifungal candidates were the EOs from Cymbopogon citratus, Otacanthus azureus and Protium heptaphyllum, whereas O. azureus, Piper hispidum and P. heptaphyllum EOs exhibited the lowest 50% inhibitory concentration (IC50) values against axenic amastigotes, thus revealing a certain correspondence between both activities. The P. hispidum EO was identified as the most promising product in the results from the infected macrophages model (IC50: 4.7 µg/mL, safety index: 8). The most abundant compounds found in this EO were sesquiterpenes, notably curzerene and furanodiene. Eventually, the evaluation of the antidermatophytic activity of EOs appears to be an efficient method for identifying new potential drugs for the treatment of L. amazonensis. PMID:25742270

  17. Therapeutic switching: from antidermatophytic essential oils to new leishmanicidal products.

    PubMed

    Houël, Emeline; Gonzalez, German; Bessière, Jean-Marie; Odonne, Guillaume; Eparvier, Véronique; Deharo, Eric; Stien, Didier

    2015-02-01

    This study examined whether the antidermatophytic activity of essential oils (EOs) can be used as an indicator for the discovery of active natural products against Leishmania amazonensis. The aerial parts of seven plants were hydrodistilled. Using broth microdilution techniques, the obtained EOs were tested against three strains of dermatophytes (Trichophyton mentagrophytes, Microsporum gypseum and Microsporum canis). To compare the EOs antifungal and antiparasitic effects, the EOs activities against axenic amastigotes of L. amazonensis were concurrently evaluated. For the most promising EOs, their antileishmanial activities against parasites infecting peritoneal macrophages of BALB/c mice were measured. The most interesting antifungal candidates were the EOs from Cymbopogon citratus, Otacanthus azureus and Protium heptaphyllum, whereas O. azureus, Piper hispidum and P. heptaphyllum EOs exhibited the lowest 50% inhibitory concentration (IC50) values against axenic amastigotes, thus revealing a certain correspondence between both activities. The P. hispidum EO was identified as the most promising product in the results from the infected macrophages model (IC50: 4.7 µg/mL, safety index: 8). The most abundant compounds found in this EO were sesquiterpenes, notably curzerene and furanodiene. Eventually, the evaluation of the antidermatophytic activity of EOs appears to be an efficient method for identifying new potential drugs for the treatment of L. amazonensis. PMID:25742270

  18. Fiber optic penetrator for offshore oil well exploration and production

    SciTech Connect

    Collins, J.C.; Warner, C.P.; Henkener, J.A.; Glauser, R.

    1986-07-01

    A fiber optic penetrator arrangement is described for an undersea wall structure of offshore oil well production apparatus, comprising: a. a generally cylindrical housing; b. a cofferdam associated with the undersea production apparatus and defining a generally cylindrical entrance port into which the penetrator is designed to be inserted and mounted; c. a sealing means for sealing the penetrator relative to the entrance port after insertion of the penetrator therein; d. an external bulkhead; e. a second bulkhead positioned internally of the external bulkead; f. a compression spring normally retaining the second bulkhead in a sealed position with the penetrator, the compressing spring being compressed between the second bulkhead and the external bulkhead; g. a breakaway connection affixed to the external bulkhead for coupling an optical fiber transmission cable to the external bulkhead, such that if the transmission cable is snagged or pulled, the external bulkhead will sever along with the breakaway connection so that the penetrator is not pulled from the cofferdam entrance port, the second bulkhead being held in position by ambient water pressure to become the primary bulkhead after the external bulkhead is severed.

  19. Effect of commercially available plant-derived essential oil products on arthropod pests.

    PubMed

    Cloyd, Raymond A; Galle, Cindy L; Keith, Stephen R; Kalscheur, Nanette A; Kemp, Kenneth E

    2009-08-01

    Plant-derived essential oil products, in general, are considered minimum-risk pesticides and are exempt from Environmental Protection Agency registration under section 25(b) of the Federal Insecticide Fungicide and Rodenticide Act. However, many of the plant-derived essential products available to consumers (homeowners) have not been judiciously evaluated for both efficacy and plant safety. In fact, numerous plant-derived essential oil products labeled for control of arthropod pests have not been subject to rigorous evaluation, and there is minimal scientific information or supporting data associated with efficacy against arthropod pests. We conducted a series of greenhouse experiments to determine the efficacy and phytotoxicity of an array of plant-derived essential oil products available to consumers on arthropod pests including the citrus mealybug, Planococcus citri (Risso); western flower thrips, Frankliniella occidentalis (Pergande); twospotted spider mite, Tetranychus urticae Koch; sweetpotato whitefly B-biotype, Bemisia tabaci (Gennadius); and green peach aphid, Myzus persicae (Sulzer). Although the products Flower Pharm (cottonseed, cinnamon, and rosemary oil) and Indoor Pharm (soybean, rosemary, and lavender oil) provided > 90% mortality of citrus mealybug, they were also the most phytotoxic to the coleus, Solenostemon scutellarioides (L.) Codd, plants. Both GC-Mite (cottonseed, clove, and garlic oil) and Bugzyme (citric acid) were most effective against the twospotted spider mite (> or = 90% mortality). However, SMC (canola, coriander oil, and triethanolamine), neem (clarified hydrophobic extract of neem oil), and Bug Assassin (eugenol, sodium lauryl sulfate, peppermint, and citronella oil) provided > 80% mortality. Monterey Garden Insect Spray, which contained 0.5% spinosad, was most effective against western flower thrips with 100% mortality. All the other products evaluated failed to provide sufficient control of western flower thrips with < 30

  20. LED Lighting Facts® Program Supports Accuracy in SSL Product Information

    SciTech Connect

    2013-09-30

    Fact sheet that provides a summary of LED Lighting Facts, a program to assure that LED lighting is accurately represented in the marketplace, illustrated by the LED Lighting Facts label to disclose product performance data.

  1. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2001-06-27

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies will result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs.

  2. Effects of egg oiling on larid productivity and population dynamics

    USGS Publications Warehouse

    Lewis, S.J.; Malecki, R.A.

    1984-01-01

    In this study, oil was applied to naturally incubated great black-backed gull (Larus marinus) and herring gull (L. argentatus) eggs, and its effects on reproductive success were assessed. Embryo survival was inversely proportional to the quantity of petroleum applied to eggshell surfaces. Dose responses, however, were dependent on embryonic age at the time of treatment. Eggs of either species, treated with 10-20 mu l of No. 2 fuel oil 4-8 days after laying, experienced significant reductions in hatching success. Embryos oiled past the midpoint of the 28-day incubation period were insensitive to as much as 100 mu l of petroleum. Fuel oil weathered outdoors for several weeks was as toxic as fresh oil to larid embryos. Only under severe conditions (e.g., large doses of petroleum contaminating young embryos) could egg oiling have a significant impact upon populations of the herring gull and species with similar life-history characteristics.

  3. Enhanced di-Higgs production through light colored scalars

    NASA Astrophysics Data System (ADS)

    Kribs, Graham D.; Martin, Adam

    2012-11-01

    We demonstrate enhanced di-Higgs production at the LHC in the presence of modifications of the effective couplings of Higgs to gluons from new, light, colored scalars. While our results apply to an arbitrary set of colored scalars, we illustrate the effects with a real color octet scalar—a simple, experimentally viable model involving a light (≃125-300GeV) colored scalar. Given the recent LHC results, we consider two distinct scenarios: First, if the Higgs is indeed near 125 GeV, we show that the di-Higgs cross section could be up to nearly 103 times the Standard Model rate for particular octet couplings and masses. This is potentially observable in single Higgs production modes, such as pp→hh→γγbb¯ as well as pp→hh→τ+τ-bb¯ where a small fraction of the γγ or τ+τ- events near the putative Higgs invariant mass peak contain also a bb¯ resonance consistent with the Higgs mass. Second, if the Higgs is not at 125 GeV (and what the LHC has observed is an impostor), we show that the same parameter region where singly-produced Higgs production can be suppressed below current LHC limits, for a heavier Higgs mass, also simultaneously predicts substantially enhanced di-Higgs production. We point out several characteristic signals of di-Higgs production with a heavier Higgs boson, such as pp→hh→W+W-W+W-, which could use same-sign dileptons or trileptons plus missing energy to uncover evidence.

  4. Air quality concerns of unconventional oil and natural gas production.

    PubMed

    Field, R A; Soltis, J; Murphy, S

    2014-05-01

    Increased use of hydraulic fracturing ("fracking") in unconventional oil and natural gas (O & NG) development from coal, sandstone, and shale deposits in the United States (US) has created environmental concerns over water and air quality impacts. In this perspective we focus on how the production of unconventional O & NG affects air quality. We pay particular attention to shale gas as this type of development has transformed natural gas production in the US and is set to become important in the rest of the world. A variety of potential emission sources can be spread over tens of thousands of acres of a production area and this complicates assessment of local and regional air quality impacts. We outline upstream activities including drilling, completion and production. After contrasting the context for development activities in the US and Europe we explore the use of inventories for determining air emissions. Location and scale of analysis is important, as O & NG production emissions in some US basins account for nearly 100% of the pollution burden, whereas in other basins these activities make up less than 10% of total air emissions. While emission inventories are beneficial to quantifying air emissions from a particular source category, they do have limitations when determining air quality impacts from a large area. Air monitoring is essential, not only to validate inventories, but also to measure impacts. We describe the use of measurements, including ground-based mobile monitoring, network stations, airborne, and satellite platforms for measuring air quality impacts. We identify nitrogen oxides, volatile organic compounds (VOC), ozone, hazardous air pollutants (HAP), and methane as pollutants of concern related to O & NG activities. These pollutants can contribute to air quality concerns and they may be regulated in ambient air, due to human health or climate forcing concerns. Close to well pads, emissions are concentrated and exposure to a wide range of

  5. Prorationing and reserves constraints for Texas oil production, 1945-1995

    NASA Astrophysics Data System (ADS)

    Blackburne, Edward Francis, III

    Texas relies on the oil industry for direct tax revenues and jobs. The importance of oil to the state is not subject to debate. This dissertation models this all important supply of Texas onshore oil. Throughout this dissertation, the prorationing constraint and the cost constraint of reserves were explored. Two classes of models were estimated: (i) geophysical specifications, in the spirit of Hubbert Curves, and (ii) econometric models of partial adjustment. The econometric models were applied to both state aggregate data and a panel data set of the twelve Texas Railroad Commission districts. Various panel data techniques were explored. The marginal effect of prorationing on oil production was a strong limiting factor to oil producers until 1973. The stock of oil in the ground represents a cost constraint to producers. It is these two constraints, not prices, that dictate our state oil supply.

  6. An overview of regulations for offshore oil and gas exploration and production in China

    SciTech Connect

    Yang, M.

    1994-12-31

    Many American oil companies have participated in Chinese offshore oil and gas development in recent years and will continue to do so. Very often American oil companies that pursue joint development programs with the Chinese oil firms are responsible for engineering and construction execution and facility operation. To fulfill the responsibilities, the American oil companies need to design, construct, install and operate an offshore facility in compliance with relevant Chinese offshore oil and gas development regulations. This article provides an overview of current Chinese regulations for offshore oil and gas exploration and production as well as highlights on some specific requirements imposed by the Chinese regulations, especially in environmental protection and safety areas. This article also discusses permitting requirements and mandatory approvals by the Chinese government. Other discussions include how to achieve compliance through sound strategy, thorough understanding and good planning.

  7. Integrated utilization of red radish seeds for the efficient production of seed oil and sulforaphene.

    PubMed

    Zhang, Jie; Zhou, Xing; Fu, Min

    2016-02-01

    Supercritical CO2 was used to obtain seed oil from red radish seeds. The influence of pressure, temperature, CO2 flow rate and time on extraction yield of oil were investigated in detail. The maximum extraction yield of oil was 92.07 ± 0.76% at the optimal extraction conditions. The physicochemical properties and fatty acid composition of oil indicated that the seed oil can be used as a dietary oil. Meanwhile, the high purity sulforaphene (96.84 ± 0.17%) was separated by solvent extraction coupled with preparative high performance liquid chromatography from red radish seed meal. The initial pH, R, extraction temperature and extraction time for each cycle had a considerable influence both on the extraction yield and purity of sulforaphene of crude product. The extraction of oil was directly responsible for an increase of 18.32% in the yield of sulforaphene. PMID:26304382

  8. Process integration possibilities for biodiesel production from palm oil using ethanol obtained from lignocellulosic residues of oil palm industry.

    PubMed

    Gutiérrez, Luis F; Sánchez, Oscar J; Cardona, Carlos A

    2009-02-01

    In this paper, integration possibilities for production of biodiesel and bioethanol using a single source of biomass as a feedstock (oil palm) were explored through process simulation. The oil extracted from Fresh Fruit Bunches was considered as the feedstock for biodiesel production. An extractive reaction process is proposed for transesterification reaction using in situ produced ethanol, which is obtained from two types of lignocellulosic residues of palm industry (Empty Fruit Bunches and Palm Press Fiber). Several ways of integration were analyzed. The integration of material flows between ethanol and biodiesel production lines allowed a reduction in unit energy costs down to 3.4%, whereas the material and energy integration leaded to 39.8% decrease of those costs. The proposed integrated configuration is an important option when the technology for ethanol production from biomass reaches such a degree of maturity that its production costs be comparable with those of grain or cane ethanol. PMID:18930392

  9. 17 CFR 229.1204 - (Item 1204) Oil and gas production, production prices and production costs.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 17 Commodity and Securities Exchanges 3 2014-04-01 2014-04-01 false (Item 1204) Oil and gas... Exchanges SECURITIES AND EXCHANGE COMMISSION STANDARD INSTRUCTIONS FOR FILING FORMS UNDER SECURITIES ACT OF 1933, SECURITIES EXCHANGE ACT OF 1934 AND ENERGY POLICY AND CONSERVATION ACT OF 1975-REGULATION...

  10. Mathematical analysis of intermittent gas injection model in oil production

    NASA Astrophysics Data System (ADS)

    Tasmi, Silvya, D. R.; Pudjo, S.; Leksono, M.; Edy, S.

    2016-02-01

    Intermittent gas injection is a method to help oil production process. Gas is injected through choke in surface and then gas into tubing. Gas forms three areas in tubing: gas column area, film area and slug area. Gas column is used to propel slug area until surface. A mathematical model of intermittent gas injection is developed in gas column area, film area and slug area. Model is expanding based on mass and momentum conservation. Using assume film thickness constant in tubing, model has been developed by Tasmi et. al. [14]. Model consists of 10 ordinary differential equations. In this paper, assumption of pressure in gas column is uniform. Model consist of 9 ordinary differential equations. Connection of several variables can be obtained from this model. Therefore, dynamics of all variables that affect to intermittent gas lift process can be seen from four equations. To study the behavior of variables can be analyzed numerically and mathematically. In this paper, simple mathematically analysis approach is used to study behavior of the variables. Variables that affect to intermittent gas injection are pressure in upstream valve and in gas column. Pressure in upstream valve will decrease when gas mass in valve greater than gas mass in choke. Dynamic of the pressure in the gas column will decrease and increase depending on pressure in upstream valve.

  11. Process design for the reuse of waste water for oil production

    SciTech Connect

    Card, R.; Kus, J.

    1983-01-01

    Suncor Inc. operates a heavy oil thermal pilot project located near Bonnyville, Alberta. Because of favorable economics, Suncor expanded their existing oil production from 183 cu m/day (1,150 bpd) to 800 cu m/day (5,000 bpd). The technique used is cyclic steam stimulation, where steam is injected into the oil bearing formation for a period of several days to heat and fluidize the oil. Following steaming, the well is put into production for several days. Two to 4 bbl of water (steam) are injected for each barrel of oil produced. The water (condensate) returns with the oil and, after phase separation, is known as produced water. 13 references.

  12. A nuclear wind/solar oil-shale system for variable electricity and liquid fuels production

    SciTech Connect

    Forsberg, C.

    2012-07-01

    The recoverable reserves of oil shale in the United States exceed the total quantity of oil produced to date worldwide. Oil shale contains no oil, rather it contains kerogen which when heated decomposes into oil, gases, and a carbon char. The energy required to heat the kerogen-containing rock to produce the oil is about a quarter of the energy value of the recovered products. If fossil fuels are burned to supply this energy, the greenhouse gas releases are large relative to producing gasoline and diesel from crude oil. The oil shale can be heated underground with steam from nuclear reactors leaving the carbon char underground - a form of carbon sequestration. Because the thermal conductivity of the oil shale is low, the heating process takes months to years. This process characteristic in a system where the reactor dominates the capital costs creates the option to operate the nuclear reactor at base load while providing variable electricity to meet peak electricity demand and heat for the shale oil at times of low electricity demand. This, in turn, may enable the large scale use of renewables such as wind and solar for electricity production because the base-load nuclear plants can provide lower-cost variable backup electricity. Nuclear shale oil may reduce the greenhouse gas releases from using gasoline and diesel in half relative to gasoline and diesel produced from conventional oil. The variable electricity replaces electricity that would have been produced by fossil plants. The carbon credits from replacing fossil fuels for variable electricity production, if assigned to shale oil production, results in a carbon footprint from burning gasoline or diesel from shale oil that may half that of conventional crude oil. The U.S. imports about 10 million barrels of oil per day at a cost of a billion dollars per day. It would require about 200 GW of high-temperature nuclear heat to recover this quantity of shale oil - about two-thirds the thermal output of existing

  13. C02 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

    SciTech Connect

    Mark Kovar; Scott Wehner

    1998-01-31

    The principal objective of this CO2 Huf-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO2 H-n-P process, coupled with reservoir characterization components are to be used to determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan of increasing oil production and deferring abandonment of shallow shelf carbonate reservoirs.

  14. Production of leukotrienes by macrophage cells irradiated with ultraviolet light

    SciTech Connect

    Minoui, S.

    1986-01-01

    Mouse peritoneal macrophages were cultured, labelled with /sup 14/C-arachidonic acid, and then were irradiated with UV light (254 nm). Also, some /sup 14/C-arachidonic acid labelled macrophages were treated with Ca-ionophore (A-23187). The UV-treated macrophages produced two to three times as much arachidonic acid metabolites as did the Ca-ionophore treated cells, the UV irradiated cells produced about 20 ng of LTC/sub 4/ and 5 ng of LTB/sub 4/ per million cells, whereas the Ca-ionophore treated cells produced 10 ng LTC/sub 4/ and 1 ng LTB/sub 4/ per million cells. The irradiated cultures also exhibited a high degree of aggregation of viable macrophages around the lysed cells. There was little aggregation in the Ca-ionophore treated cultures. In phagocytosis and cell aggregation leukotrienes are produced by the viable macrophage cells. Leukotrienes are arachidonic acid oxygenation products that are thought to be mediators both in the expression of the immune-based and inflammatory responses. This study shows that macrophage cells under stressful conditions produced by a trauma-causing agent (UV light) respond by producing leukotrienes and chemotactic factors. These responses of the macrophage cells are the result of multiple biochemical events that promote the production of leukotrienes in the cultures.

  15. Environmental cleanup of oil production sites in southern Illinois

    SciTech Connect

    Vendl, K.A.; Basso, T.C.; Bengal, L.E.

    1996-12-31

    On January 2, 1988, a 4 million gallon aboveground oil storage tank collapsed in Pennsylvania, resulting in a spill of approximately 3.8 million gallons of diesel fuel. Of that amount, approximately 750,000 gallons entered the Monongahela River. On March 23, 1989, the Exxon Valdez, loaded with 1.26 million barrels (54 million gallons) of crude oil struck the rocks of Bligh Reef near Valdez, Alaska. As a result, more than 11 million gallons of crude oil was released into Prince William Sound within 5 hours of the event. The environmental damage and massive cleanup efforts were the most visible effects of these spills. However, one of the most important, but least discussed outcomes was the enactment of the Oil Pollution Act (OPA), which George Bush signed into law on August 18, 1990. The Oil Pollution Act contains many provisions; one of them is the strengthening of the national response system by providing better coordination of spill contingency planning among federal, state, and local authorities. Another provision is the increase in liability for parties responsible for costs and damages resulting from oil spills. In situations where there is no responsible party, OPA provides funding for the Oil Spill Liability Trust Fund. In this fund, there is $50 million in an emergency appropriation which can be used to contain and remove oil discharges that affect or threaten to affect the surface waters of the United States.

  16. A data mining approach to finding relationships between reservoir properties and oil production for CHOPS

    NASA Astrophysics Data System (ADS)

    Cai, Yongxiang; Wang, Xin; Hu, Kezhen; Dong, Mingzhe

    2014-12-01

    Cold heavy oil production with sand (CHOPS) is a primary oil extraction process for heavy crude oil and reservoir properties are key factors that contribute to the effectiveness of CHOPS. However, identification of the key reservoir properties and quantification of the relationships between the reservoir properties and the oil production are still challenging tasks. In this paper, we propose the use of a data mining approach for finding quantitative relationships between various reservoir properties and oil production for CHOPS. The approach includes four steps: firstly, a set of reservoir properties are identified to describe reservoir characteristics through a petrophysical analysis. In addition to common parameters, such as porosity and permeability, two new parameters - a fluid mobility factor and the maximum inscribed rectangular of net pay (MIRNP) - are proposed. Secondly, three new parameters to describe the production performance of wells are proposed: the peak value, effective life cycle and effective yield. Next, the fuzzy ranking method is used to rank the importance of the identified reservoir properties in terms of oil production. Finally, association rule mining is used to obtain quantitative relationships between reservoir property variables and the production performance of wells. The proposed methods have been applied for 118 wells in the Sparky Formation of the Lloydminster heavy oil field in Alberta. The result shows that the production performance of wells in the area could be described and predicted by using the found quantitative relations.

  17. Producing Light Oil from a Frozen Reservoir: Reservoir and Fluid Characterization of Umiat Field, National Petroleum Reserve, Alaska

    SciTech Connect

    Hanks, Catherine

    2012-12-31

    Umiat oil field is a light oil in a shallow, frozen reservoir in the Brooks Range foothills of northern Alaska with estimated oil-in-place of over 1 billion barrels. Umiat field was discovered in the 1940’s but was never considered viable because it is shallow, in the permafrost, and far from any transportation infrastructure. The advent of modern drilling and production techniques has made Umiat and similar fields in northern Alaska attractive exploration and production targets. Since 2008 UAF has been working with Renaissance Alaska Inc. and, more recently, Linc Energy, to develop a more robust reservoir model that can be combined with rock and fluid property data to simulate potential production techniques. This work will be used to by Linc Energy as they prepare to drill up to 5 horizontal wells during the 2012-2013 drilling season. This new work identified three potential reservoir horizons within the Cretaceous Nanushuk Formation: the Upper and Lower Grandstand sands, and the overlying Ninuluk sand, with the Lower Grandstand considered the primary target. Seals are provided by thick interlayered shales. Reserve estimates for the Lower Grandstand alone range from 739 million barrels to 2437 million barrels, with an average of 1527 million bbls. Reservoir simulations predict that cold gas injection from a wagon-wheel pattern of multilateral injectors and producers located on 5 drill sites on the crest of the structure will yield 12-15% recovery, with actual recovery depending upon the injection pressure used, the actual Kv/Kh encountered, and other geologic factors. Key to understanding the flow behavior of the Umiat reservoir is determining the permeability structure of the sands. Sandstones of the Cretaceous Nanushuk Formation consist of mixed shoreface and deltaic sandstones and mudstones. A core-based study of the sedimentary facies of these sands combined with outcrop observations identified six distinct facies associations with distinctive permeability

  18. The produced waters of oil deposits in Tomsk region: its use for iodine industrial production

    NASA Astrophysics Data System (ADS)

    Yankovskii, V. V.; Zippa, E. V.; Syskina, A. A.

    2016-03-01

    In world practice, groundwater is the main raw material for iodine production. In the current geopolitical conditions, a significant part of the traditional areas of iodine production is located outside the Russian Federation. As iodine is biogenic by its origin, it associates with oil and petroleum water. Therefore, the produced waters of oil deposits of Western Siberia acquire the leading role as the raw-material base for iodine production.

  19. Understanding High Wintertime Ozone Events over an Oil and Natural Gas Production Region from Air Quality Model Perspective

    NASA Astrophysics Data System (ADS)

    Ahmadov, R.; McKeen, S. A.; Trainer, M.; Banta, R. M.; Brown, S. S.; Edwards, P. M.; Frost, G. J.; Gilman, J.; Helmig, D.; Johnson, B.; Karion, A.; Koss, A.; Lerner, B. M.; Oltmans, S. J.; Roberts, J. M.; Schnell, R. C.; Veres, P. R.; Warneke, C.; Williams, E. J.; Wild, R. J.; Yuan, B.; Zamora, R. J.; Petron, G.; De Gouw, J. A.; Peischl, J.

    2014-12-01

    The huge increase in production of oil and natural gas has been associated with high wintertime ozone events over some parts of the western US. The Uinta Basin, UT, where oil and natural gas production is abundant experienced high ozone concentrations in winters of recent years, when cold stagnant weather conditions were prevalent. It has been very challenging for conventional air quality models to accurately simulate such wintertime ozone pollution cases. Here, a regional air quality model study was successfully conducted for the Uinta Basin by using the WRF-Chem model. For this purpose a new emission dataset for the region's oil/gas sector was built based on atmospheric in-situ measurements made during 2012 and 2013 field campaigns in the Uinta Basin. The WRF-Chem model demonstrates that the major factors driving high ozone in the Uinta Basin in winter are shallow boundary layers with light winds, high emissions of volatile organic compounds (VOC) compared to nitrogen oxides emissions from the oil and natural gas industry, enhancement of photolysis rates and reduction of O3 dry deposition due to snow cover. We present multiple sensitivity simulations to quantify the contribution of various factors driving high ozone over the Uinta Basin. The emission perturbation simulations show that the photochemical conditions in the Basin during winter of 2013 were VOC sensitive, which suggests that targeting VOC emissions would be most beneficial for regulatory purposes. Shortcomings of the emissions within the most recent US EPA (NEI-2011, version 1) inventory are also discussed.

  20. Contribution of lubricating oil to particulate matter emissions from light-duty gasoline vehicles in Kansas City.

    PubMed

    Sonntag, Darrell B; Bailey, Chad R; Fulper, Carl R; Baldauf, Richard W

    2012-04-01

    The contribution of lubricating oil to particulate matter (PM) emissions representative of the in-use 2004 light-duty gasoline vehicles fleet is estimated from the Kansas City Light-Duty Vehicle Emissions Study (KCVES). PM emissions are apportioned to lubricating oil and gasoline using aerosol-phase chemical markers measured in PM samples obtained from 99 vehicles tested on the California Unified Driving Cycle. The oil contribution to fleet-weighted PM emission rates is estimated to be 25% of PM emission rates. Oil contributes primarily to the organic fraction of PM, with no detectable contribution to elemental carbon emissions. Vehicles are analyzed according to pre-1991 and 1991-2004 groups due to differences in properties of the fitting species between newer and older vehicles, and to account for the sampling design of the study. Pre-1991 vehicles contribute 13.5% of the KC vehicle population, 70% of oil-derived PM for the entire fleet, and 33% of the fuel-derived PM. The uncertainty of the contributions is calculated from a survey analysis resampling method, with 95% confidence intervals for the oil-derived PM fraction ranging from 13% to 37%. The PM is not completely apportioned to the gasoline and oil due to several contributing factors, including varied chemical composition of PM among vehicles, metal emissions, and PM measurement artifacts. Additional uncertainties include potential sorption of polycyclic aromatic hydrocarbons into the oil, contributions of semivolatile organic compounds from the oil to the PM measurements, and representing the in-use fleet with a limited number of vehicles. PMID:22369074

  1. Increasing Heavy Oil Reserves in the Wilmington Oil Field through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect

    City of Long Beach; David K.Davies and Associates; Tidelands Oil Production Company; University of Southern California

    1999-06-25

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California. This is realized through the testing and application of advanced reservoir characterization and thermal production technologies. It is hoped that the successful application of these technologies will result in their implementation throughout the Wilmington Field and through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively insufficient because of several producability problems which are common in SBC reservoir; inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves.

  2. Utilization of oil extracted from spent coffee grounds for sustainable production of polyhydroxyalkanoates.

    PubMed

    Obruca, Stanislav; Petrik, Sinisa; Benesova, Pavla; Svoboda, Zdenek; Eremka, Libor; Marova, Ivana

    2014-07-01

    Spent coffee grounds (SCG), an important waste product of the coffee industry, contain approximately 15 wt% of coffee oil. The aim of this work was to investigate the utilization of oil extracted from SCG as a substrate for the production of poly(3-hydroxybutyrate) (PHB) by Cupriavidus necator H16. When compared to other waste/inexpensive oils, the utilization of coffee oil resulted in the highest biomass as well as PHB yields. Since the correlation of PHB yields and the acid value of oil indicated a positive effect of the presence of free fatty acids in oil on PHB production (correlation coefficient R (2) = 0.9058), superior properties of coffee oil can be probably attributed to the high content of free fatty acids which can be simply utilized by the bacteria culture. Employing the fed-batch mode of cultivation, the PHB yields, the PHB content in biomass, the volumetric productivity, and the Y P/S yield coefficient reached 49.4 g/l, 89.1 wt%, 1.33 g/(l h), and 0.82 g per g of oil, respectively. SCG are annually produced worldwide in extensive amounts and are disposed as solid waste. Hence, the utilization of coffee oil extracted from SCG is likely to improve significantly the economic aspects of PHB production. Moreover, since oil extraction decreased the calorific value of SCG by only about 9 % (from 19.61 to 17.86 MJ/kg), residual SCG after oil extraction can be used as fuel to at least partially cover heat and energy demands of fermentation, which should even improve the economic feasibility of the process. PMID:24652066

  3. Factors impacting the formation of monochloropropanediol (MCPD) fatty acid diesters during palm (Elaeis guineensis) oil production.

    PubMed

    Craft, Brian D; Nagy, Kornél; Sandoz, Laurence; Destaillats, Frédéric

    2012-01-01

    Recently, organic and inorganic chlorinated compounds were detected in crude and commercially refined palm oils. Further, the predominant formation mechanism of monochloropropanediol (MCPD) diesters at high temperatures (>170-180°C) was revealed. The present study involved the development and comparison of solutions to mitigate MCPD diester levels in oils from various stages of palm oil production. Partially refined palm oil samples and oil extracted from fresh palm fruits were submitted to bench-top deodorisation experiments. Application of glycerol and ethanol as refining aids during the deodorisation of refined-bleached palm oil proved to be moderately effective; about 25%-35% reduction of MCPD diester levels was achieved. Washing crude palm oil with ethanol-water (1:1) prior to deodorisation was also an effective strategy yielding an ∼30% reduction of MCPD diester contents. Washing palm fruit pulp before oil extraction, however, was most impactful, resulting in a 95% reduction of MCPD diesters when compared to the deodorised control oil. This suggests that intervention upstream in the process chain is most efficient in reducing levels of these contaminants in refined oils. Following the study, a root-cause analysis was performed in order to map the parameters potentially responsible for the occurrence of MCPD diesters in refined palm oil and related fractions. PMID:22168150

  4. Stimulation methods applicable to thickened oil section in production and injection wells of daqing oilfield

    SciTech Connect

    Yin, L.; Pei, F.

    1983-01-01

    Daqing oil field is a multi-zone sandstone oil field. Because the natural drive energy of the reservoir is small, waterflooding was adopted to maintain reservoir energy at the initial development stage. In the oil-water transition belt, block D in SB area, the northern part of the oil field, because of the poorer reservoir characteristics and the poorer physical properties of crude oil and the lower injectivity of water injection well, the effects of development were worse than that from the net oil area. A simulation experiment on cores was performed, according to the characteristics and the existing problems in the thickened oil section in the oil-water transition belt. Based on the results of the experiment, adopting the measures of injectivity improvement of solvent and selective acidizing in water injection wells of this area, water injection was increased greatly, and the oil wells were affected continuously. At the same time, oil output per well and oil productive thickness of reservoir were increased, as to improve the results of development in block D.

  5. Preliminary Economics for the Production of Pyrolysis Oil from Lignin in a Cellulosic Ethanol Biorefinery

    SciTech Connect

    Jones, Susanne B.; Zhu, Yunhua

    2009-04-01

    Cellulosic ethanol biorefinery economics can be potentially improved by converting by-product lignin into high valued products. Cellulosic biomass is composed mainly of cellulose, hemicellulose and lignin. In a cellulosic ethanol biorefinery, cellulose and hemicellullose are converted to ethanol via fermentation. The raw lignin portion is the partially dewatered stream that is separated from the product ethanol and contains lignin, unconverted feed and other by-products. It can be burned as fuel for the plant or can be diverted into higher-value products. One such higher-valued product is pyrolysis oil, a fuel that can be further upgraded into motor gasoline fuels. While pyrolysis of pure lignin is not a good source of pyrolysis liquids, raw lignin containing unconverted feed and by-products may have potential as a feedstock. This report considers only the production of the pyrolysis oil and does not estimate the cost of upgrading that oil into synthetic crude oil or finished gasoline and diesel. A techno-economic analysis for the production of pyrolysis oil from raw lignin was conducted. comparing two cellulosic ethanol fermentation based biorefineries. The base case is the NREL 2002 cellulosic ethanol design report case where 2000 MTPD of corn stover is fermented to ethanol (NREL 2002). In the base case, lignin is separated from the ethanol product, dewatered, and burned to produce steam and power. The alternate case considered in this report dries the lignin, and then uses fast pyrolysis to generate a bio-oil product. Steam and power are generated in this alternate case by burning some of the corn stover feed, rather than fermenting it. This reduces the annual ethanol production rate from 69 to 54 million gallons/year. Assuming a pyrolysis oil value similar to Btu-adjusted residual oil, the estimated ethanol selling price ranges from $1.40 to $1.48 (2007 $) depending upon the yield of pyrolysis oil. This is considerably above the target minimum ethanol selling

  6. Productivity, Oil Content, and Oil Composition of Sweet Basil as a Function of Nitrogen and Sulfur Fertilization

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Nitrogen (N) and sulfur (S) were believed to be important nutrient management tools for the production of sweet basil (Ocimum basilicum L. 'German') with desirable oil content and composition and also acceptable herbage yields. A multi-location research study was initiated to evaluate the effect of...

  7. National Assessment of Oil and Gas Project: Areas of Historical Oil and Gas Exploration and Production in the United States

    USGS Publications Warehouse

    Biewick, Laura R.H.

    2008-01-01

    This report contains maps and associated spatial data showing historical oil and gas exploration and production in the United States. Because of the proprietary nature of many oil and gas well databases, the United States was divided into cells one-quarter square mile and the production status of all wells in a given cell was aggregated. Base-map reference data are included, using the U.S. Geological Survey (USGS) National Map, the USGS and American Geological Institute (AGI) Global GIS, and a World Shaded Relief map service from the ESRI Geography Network. A hardcopy map was created to synthesize recorded exploration data from 1859, when the first oil well was drilled in the U.S., to 2005. In addition to the hardcopy map product, the data have been refined and made more accessible through the use of Geographic Information System (GIS) tools. The cell data are included in a GIS database constructed for spatial analysis via the USGS Internet Map Service or by importing the data into GIS software such as ArcGIS. The USGS internet map service provides a number of useful and sophisticated geoprocessing and cartographic functions via an internet browser. Also included is a video clip of U.S. oil and gas exploration and production through time.

  8. Production, separation and applications of phenolic-rich bio-oil--a review.

    PubMed

    Kim, Joo-Sik

    2015-02-01

    This paper provides an overview of current research trends in the production and separation of phenolic-rich bio-oils, as well as their applications. The first part of this paper highlights the strong dependency of the phenolic content of bio-oil on the kinds of biomass feedstock, reaction system, reaction conditions, and the type of catalysts used in their production. More recent separation technologies are also discussed in the second part of the paper. The final part of the paper deals with recent experimental results from applications of phenolic-rich bio-oils in the synthesis of phenolic resins. The paper suggests that the microwave-assisted pyrolysis of palm residues is a promising route for phenolic-rich bio-oil production, and that the use of supercritical CO2 and switchable hydrophilicity solvents during extraction, as well as molecular distillation techniques, can be applied to increase the recovery of phenolic compounds from bio-oils. PMID:25239785

  9. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Unknown

    2001-08-08

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California, through the testing and application of advanced reservoir characterization and thermal production technologies. The hope is that successful application of these technologies will result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs, including: (1) Development of three-dimensional (3-D) deterministic and stochastic reservoir simulation models--thermal or otherwise--to aid in reservoir management of the steamflood and post-steamflood phases and subsequent development work. (2) Development of computerized 3-D visualizations of the geologic and reservoir simulation models to aid reservoir surveillance and operations. (3) Perform detailed studies of the geochemical interactions between the steam and the formation rock and fluids. (4) Testing and proposed application of a

  10. Bio-oil upgrading strategies to improve PHA production from selected aerobic mixed cultures.

    PubMed

    Moita Fidalgo, Rita; Ortigueira, Joana; Freches, André; Pelica, João; Gonçalves, Magarida; Mendes, Benilde; Lemos, Paulo C

    2014-06-25

    Recent research on polyhydroxyalkanoates (PHAs) has focused on developing cost-effective production processes using low-value or industrial waste/surplus as substrate. One of such substrates is the liquid fraction resulting from pyrolysis processes, bio-oil. In this study, valorisation of bio-oil through PHA production was investigated. The impact of the complex bio-oil matrix on PHA production by an enriched mixed culture was examined. The performance of the direct utilization of pure bio-oil was compared with the utilization of three defined substrates contained in this bio-oil: acetate, glucose and xylose. When compared with acetate, bio-oil revealed lower capacity for polymer production as a result of a lower polymer yield on substrate and a lower PHA cell content. Two strategies for bio-oil upgrade were performed, anaerobic fermentation and vacuum distillation, and the resulting liquid streams were tested for polymer production. The first one was enriched in volatile fatty acids and the second one mainly on phenolic and long-chain fatty acids. PHA accumulation assays using the upgraded bio-oils attained polymer yields on substrate similar or higher than the one achieved with acetate, although with a lower PHA content. The capacity to use the enriched fractions for polymer production has yet to be optimized. The anaerobic digestion of bio-oil could also open-up the possibility to use the fermented bio-oil directly in the enrichment process of the mixed culture. This would increase the selective pressure toward an optimized PHA accumulating culture selection. PMID:24189432

  11. Air Pollutant Emissions from Oil and Gas Production pads (Investigating Low Cost Passive Samplers)

    EPA Science Inventory

    To help achieve the goal of sustainable, environmentally responsible development of oil and gas resources, it isnecessary to understand the potential for air pollutant emissions from various extraction and production (E&P)processes at the upstream, wellpad level. Upstream oil and...

  12. Workshop in environmental issues associated with western hemisphere oil and gas production

    SciTech Connect

    1994-12-31

    Representatives from several U.S. and Latin American oil and gas companies, and government representatives, met in Montevideo, Uruguay, on May 4-6, 1994, to discuss regulation, cooperation, and management of environmental issues associated with oil and gas production. This report presents a brief summary of the topics discussed at the meeting.

  13. Processing of coriander fruits for the production of essential oil, triglyceride, and high protein seed meal

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Coriander (Coriandrum sativum L.) is a summer annual traditionally grown for use as a fresh green herb or as a spice. The essential oil extracted from coriander fruit is also widely used as flavoring in a variety of food products. The fatty oil (triglyceride) fraction in the seed is rich in petrosel...

  14. Comparative Toxicity of Eight Oil Dispersant Products on Two Gulf of Mexico Aquatic Test Species

    EPA Science Inventory

    This report is the first of a round of toxicity testing data for eight oil dispersants that have been authorized for use on the National Contingency Plan (NCP) Product Schedule, which is a list of authorized dispersants and other chemicals that may be used to respond to oil disch...

  15. ALOX5 gene variants affect eicosanoid production and response to fish oil supplementation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The objective of this study was to determine whether 5-lipoxygenase (ALOX5) gene variants associated with cardiovascular disease affect eicosanoid production by monocytes. The study was a randomized, double-masked, parallel intervention trial with fish oil (5.0 g of fish oil daily, containing 2.0 g ...

  16. Production and Evaluation of Biodiesel from Field Pennycress (Thlaspi Arvense L.) Oil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Field pennycress (Thlaspi arvense L.) oil is evaluated for the first time as a potential feedstock for biodiesel production. Biodiesel was obtained in 82 wt % yield by a standard transesterification procedure with methanol and sodium methoxide catalyst at 60 deg C and an alcohol to oil ratio of 6:1...

  17. 40 CFR 112.9 - Spill Prevention, Control, and Countermeasure Plan Requirements for onshore oil production...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 22 2011-07-01 2011-07-01 false Spill Prevention, Control, and Countermeasure Plan Requirements for onshore oil production facilities (excluding drilling and workover facilities). 112.9 Section 112.9 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS OIL POLLUTION...

  18. Functional beverage products using caseinate–omega-3 oil-oat beta glucan emulsions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Beverages with soluble dietary fiber and Omega 3 oil are highly desired by health conscious consumers. However, Omega 3 oil is prone to oxidation and accompanying deterioration of sensory profiles; there is an issue to incorporate soluble fiber into beverage products that will not interfere with oxi...

  19. Western oil-shale development: a technology assessment. Volume 2: technology characterization and production scenarios

    SciTech Connect

    Not Available

    1982-01-01

    A technology characterization of processes that may be used in the oil shale industry is presented. The six processes investigated are TOSCO II, Paraho Direct, Union B, Superior, Occidental MIS, and Lurgi-Ruhrgas. A scanario of shale oil production to the 300,000 BPD level by 1990 is developed. (ACR)

  20. Synthesis of novel plant oil derivatives: Furan and Diels-Alder reaction products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Plant oils are useful sustainable raw materials for the development of new chemical products. In this work epoxidized soybean oil was treated with different acids, and variable amounts of furan structures were produced from the epoxidized linoleate moiety. From process studies, the highest yields of...

  1. Adaptability of irrigated spring canola oil production to the U.S. High Plains

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Canola oil is high in oleic acid which is commonly used for food and industrial purposes. To determine adaptability of spring canola (Brassica napus L.) to the High Plains for industrial oil production, 26 irrigated trials were conducted from 2005-2008. Trials were divided into five regions: (1) 36...

  2. Polymer flooding increases production in giant oil field

    SciTech Connect

    Delamaide, E.; Corlay, P. )

    1994-12-01

    Daqing field, discovered in 1959, is the largest oil field in the People's Republic of China, with original oil in place exceeding two billion tons. Reservoir heterogeneity and oil viscosity have resulted in moderate displacement efficiency and high watercut. To increase recovery, polymer injection was tested in two pilots between 1987 and 1992, after lab and reservoir studies. Both pilots proved highly successful and led to the decision to extend polymer injection to the whole field. This article presents the history of Daqing polymer flooding, from preliminary studies to full-field extension.

  3. 30 CFR 1206.112 - What adjustments and transportation allowances apply when I value oil production from my lease...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... exchange (or both transport and exchange) less than 20 percent of the crude oil produced from your lease... published in an ONRR-approved publication for the market center nearest your lease, for crude oil most... example, for light sweet crude oil produced offshore of Louisiana, use the WTI differential for...

  4. 30 CFR 206.112 - What adjustments and transportation allowances apply when I value oil production from my lease...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... exchange) less than 20 percent of the crude oil produced from your lease between the lease and a market...-approved publication for the market center nearest your lease, for crude oil most similar in quality to... crude oil produced offshore of Louisiana, use the WTI differential for Light Louisiana Sweet crude...

  5. Increased mycelial biomass production by Lentinula edodes intermittently illuminated by green light emitting diodes.

    PubMed

    Glukhova, Lubov B; Sokolyanskaya, Ludmila O; Plotnikov, Evgeny V; Gerasimchuk, Anna L; Karnachuk, Olga V; Solioz, Marc; Karnachuk, Raisa A

    2014-11-01

    Fungi possess a range of light receptors to regulate metabolism and differentiation. To study the effect of light on Lentinula edodes (the shiitake mushroom), mycelial cultures were exposed to blue, green, and red fluorescent lights and light-emitting diodes, as well as green laser light. Biomass production, morphology, and pigment production were evaluated. Exposure to green light at intervals of 1 min/d at 0.4 W/m(2) stimulated biomass production by 50-100 %, depending on the light source. Light intensities in excess of 1.8 W/m(2) or illumination longer than 30 min/d did not affect biomass production. Carotenoid production and morphology remained unaltered during increased biomass production. These observations provide a cornerstone to the study of photoreception by this important fungus. PMID:25048231

  6. Can fruit-form be a marker for argan oil production?

    PubMed

    Gharby, Saïd; Harhar, Hicham; Kartah, Badr Eddine; El Monfalouti, Hanae; Denhez, Clément; Hilali, Miloudi; Guillaume, Dom; Charrouf, Zoubida

    2013-01-01

    Deforestation is an important matter for the argan forest whose preservation necessitates planting trees. Macroscopic parameters are urgently needed to identify trees presenting good potential as oil producers. This study demonstrates that argan oil produced from kernels of apiculate fruit is richer in d-tocopherol, whereas oil produced from spherical fruit is richer in linoleic acid, and that produced from fusiform fruit is richer in oleic acid. Therefore, the use of fruit-form as a marker could permit an easy organic production of "naturally enriched" oils. PMID:23472452

  7. Production of biodiesel from winery waste: extraction, refining and transesterification of grape seed oil.

    PubMed

    Fernández, Carmen María; Ramos, María Jesús; Pérez, Angel; Rodríguez, Juan Francisco

    2010-09-01

    In regions with a large wine production the usage of their natural waste to make biodiesel can result an interesting alternative. In this work, different methods of extraction, refining and transesterification of grape seed oil were assayed. Two techniques of oil extraction were compared: solvent extraction and pressing. Two conventional transesterifications of the refined oil were carried out using methanol and bioethanol, being the methyl and ethyl ester contents higher than 97 wt.%. Finally, several in situ transesterifications were done. In situ transesterification did not reach either the oil yield extraction or the alkyl ester contents but the obtained biodiesel had better oxidation stability in comparison with the conventional process. PMID:20435475

  8. Light scalar mesons in central production at COMPASS

    NASA Astrophysics Data System (ADS)

    Austregesilo, Alexander

    2016-05-01

    COMPASS is a fixed-target experiment at the CERN SPS that studies the spectrum of light-quark hadrons. In 2009, it collected a large dataset using a 190 GeV/c positive hadron beam impinging on a liquid-hydrogen target in order to measure the central exclusive production of light scalar mesons. One of the goals is the search for so-called glueballs, which are hypothetical meson-like objects without valence-quark content. We study the decay of neutral resonances by selecting centrally produced pion pairs from the COMPASS dataset. The angular distributions of the two pseudoscalar mesons are decomposed in terms of partial waves, where particular attention is paid to the inherent mathematical ambiguities. The large dataset allows us to perform a detailed analysis in bins of the two squared four-momentum transfers carried by the exchange particles in the reaction. Possible parameterisations of the mass dependence of the partial-wave amplitudes in terms of resonances are also discussed.

  9. Increasing Heavy Oil in the Wilmington Oil Fiel Through Advanced Reservoir Characterization and Thermal Production Technologies. Annual Report, March 30, 1995--March 31, 1996

    SciTech Connect

    Allison, Edith

    1996-12-01

    The objective of this project is to increase heavy oil reserves in a portion of the Wilmington Oil Field, near Long Beach, California, by implementing advanced reservoir characterization and thermal production technologies. Based on the knowledge and experience gained with this project, these technologies are intended to be extended to other sections of the Wilmington Oil Field, and, through technology transfer, will be available to increase heavy oil reserves in other slope and basin clastic (SBC) reservoirs.

  10. Light element production by low energy nuclei from massive stars

    NASA Technical Reports Server (NTRS)

    Vangioni-Flam, E.; Casse, M.; Ramaty, R.

    1997-01-01

    The Orion complex is a source of gamma rays attributed to the de-excitation of fast carbon and oxygen nuclei excited through interactions with ambient hydrogen and helium. This has consequences for the production and evolution of light isotopes in the Galaxy, as massive stars appear as prolific sources of C-O rich low energy nuclei. The different stages of massive star evolution are considered in relation to the acceleration of nuclei to moderate energies. It is concluded that the low energy nuclear component originating from massive stars plays a larger role than the usual Galactic cosmic rays in shaping the evolution of Li-6, Be-9, B-10 and B-11, especially in the early Galactic evolution. The enhancement of the B-11/B-10 ratio observed in meteorites and in the interstellar medium is attributed to the interaction of low energy carbon nuclei with ambient H and to a lesser degree, to neutrino spallation.

  11. PROTOTYPIC CONTINUITY METHODS FOR FASTER RECOVERY OF OIL PRODUCTS SUPPLY AFTER GREAT QUAKE

    NASA Astrophysics Data System (ADS)

    Yasuno, Takato

    In the Great East Japan Earthquake, some oil product farms and tanks had a lot of damages. Then we temporally run short of oil products such as gasoline, lamp oil. The oil product is indispensable to make cargo shipment, or rescue operations, and some trouble must come for everyday shopping and movement of business. The lifeline damages come out electric power, water service, gas and communication. In addition the oil product shortage overlaps then the importance to restore was recognized. After earthquake disaster, there is a possibility to interrupt supply services such as shipping from oil tanks and sale at stations. Even if their discontinuation comes, it needs some business continuity policies in order to recover supply service at early stage. This paper grasps oil product discontinuation of supply and restoration transition and tries to get disaster lessons. This paper proposes prototypic techniques to minimize the sum of penalties to supply no service for neighbor region with capacities of critical stations. It applies to Tohoku regions and their gas stations and comments the usefulness of techniques and implication of supply service continuity policy.

  12. Comparison Between Different Flavored Olive Oil Production Techniques: Healthy Value and Process Efficiency.

    PubMed

    Clodoveo, Maria Lisa; Dipalmo, Tiziana; Crupi, Pasquale; Durante, Viviana; Pesce, Vito; Maiellaro, Isabella; Lovece, Angelo; Mercurio, Annalisa; Laghezza, Antonio; Corbo, Filomena; Franchini, Carlo

    2016-03-01

    Three different flavoring methods of olive oil were tested employing two different herbs, thyme and oregano. The traditional method consist in the infusion of herbs into the oil. A second scarcely diffused method is based on the addition of herbs to the crushed olives before the malaxation step during the extraction process. The third innovative method is the implementation of the ultrasound before the olive paste malaxation. The objective of the study is to verify the effect of the treatments on the quality of the product, assessed by means of the chemical characteristics, the phenol composition and the radical scavenging activity of the resulting oils. The less favorable method was the addition of herbs directly to the oil. A positive effect was achieved by the addition of herbs to the olive paste and other advantages were attained by the employment of ultrasound. These last two methods allow to produce oils "ready to sell", instead the infused oils need to be filtered. Moreover, the flavoring methods applied during the extraction process determine a significant increment of phenolic content and radical scavenging activity of olive oils. The increments were higher when oregano is used instead of thyme. Ultrasound inhibited the olive polyphenoloxidase, the endogenous enzyme responsible for olive oil phenol oxidation. This treatment of olive paste mixed with herbs before malaxation was revealed as the most favorable method due to the best efficiency, reduced time consumption and minor labor, enhancing the product quality of flavored olive oil. PMID:26852311

  13. CO{sub 2} huff-n-puff process in a light oil shallow carbonate reservoir. Annual report, January 1, 1996--December 31, 1996

    SciTech Connect

    Prieditis, J.; Wehner, S.

    1998-01-01

    The application of cyclic CO{sub 2}, often referred to as the CO{sub 2} Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO{sub 2} H-n-P process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital intensive miscible projects. Texaco Exploration & Production Inc. and the U.S. Department of Energy have teamed up in an attempt to develop the CO{sub 2} Huff-n-Puff process in the Grayburg and San Andres formations; a light oil, shallow shelf carbonate reservoir that exists throughout the Permian Basin. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected site for this demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico. Miscible CO{sub 2} flooding is the process of choice for enhancing recovery of light oils and already accounts for over 12% of the Permian Basin`s daily production. There are significant probable reserves associated with future miscible CO{sub 2} projects. However, many are marginally economic at current market conditions due to large up-front capital commitments for a peak response which may be several years in the future. The resulting negative cash-flow is sometimes too much for an operator to absorb. The CO{sub 2} H-n-P process is being investigated as a near-term option to mitigate the negative cash-flow situation--allowing acceleration of inventoried miscible CO{sub 2} projects when coupled together.

  14. Bio-oil based biorefinery strategy for the production of succinic acid

    PubMed Central

    2013-01-01

    Background Succinic acid is one of the key platform chemicals which can be produced via biotechnology process instead of petrochemical process. Biomass derived bio-oil have been investigated intensively as an alternative of diesel and gasoline fuels. Bio-oil could be fractionized into organic phase and aqueous phase parts. The organic phase bio-oil can be easily upgraded to transport fuel. The aqueous phase bio-oil (AP-bio-oil) is of low value. There is no report for its usage or upgrading via biological methods. In this paper, the use of AP-bio-oil for the production of succinic acid was investigated. Results The transgenic E. coli strain could grow in modified M9 medium containing 20 v/v% AP-bio-oil with an increase in OD from 0.25 to 1.09. And 0.38 g/L succinic acid was produced. With the presence of 4 g/L glucose in the medium, succinic acid concentration increased from 1.4 to 2.4 g/L by addition of 20 v/v% AP-bio-oil. When enzymatic hydrolysate of corn stover was used as carbon source, 10.3 g/L succinic acid was produced. The obtained succinic acid concentration increased to 11.5 g/L when 12.5 v/v% AP-bio-oil was added. However, it decreased to 8 g/L when 50 v/v% AP-bio-oil was added. GC-MS analysis revealed that some low molecular carbon compounds in the AP-bio-oil were utilized by E. coli. Conclusions The results indicate that AP-bio-oil can be used by E. coli for cell growth and succinic acid production. PMID:23657107

  15. 76 FR 28968 - Imperial Oil and ExxonMobil Oil Corporation, v. Enbridge Pipelines (Southern Lights) LLC; Notice...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-19

    ... Lights) LLC; Notice of Complaint Take notice that on May 11, 2011, pursuant to Rule 206 of the Rules of... Pipelines (Southern Lights) LLC (Respondent). Complainants are challenging certain rates, terms...

  16. Status of Solid State Lighting Product Development and Future Trends for General Illumination.

    PubMed

    Katona, Thomas M; Pattison, P Morgan; Paolini, Steve

    2016-06-01

    After decades of research and development on fabrication of efficient light-emitting diodes (LEDs) throughout the visible spectrum, LED-based lighting has reached unparalleled performance with respect to energy efficiency and has become the light source for virtually all new lighting products being designed today. The development of the core light sources and their subsequent integration into lighting systems continue to present unique challenges and opportunities for product designers. We review these systems and the current development status, as well as provide context for the trends in solid state lighting that are leading to the development of value-added lighting solutions that extend the domain of lighting beyond light generation, into fields as diverse as communications, healthcare, and agricultural production. PMID:27023662

  17. Stripped corn oil controls scald and maintains volatile production potential in golden supreme and delicious apples.

    PubMed

    Ju, Z; Curry, E A

    2000-06-01

    Effects of stripped (alpha-tocopherol < 5 mg L(-)(1)) corn oil on flesh firmness, skin color, acidity, soluble solids content (SSC), scald, and fruit volatiles during 6 months at 0 degrees C were studied using Golden Supreme and Delicious apples. Treatment with 10% oil emulsion reduced production of ethylene, alpha-farnesene, and major volatile esters in the first 3 months of storage, but this trend reversed after 5 months. After 6 months at 0 degrees C plus 7 days at 20 degrees C, oil-treated fruit were firmer and greener and had higher levels of titratable acidity than the controls. In addition, control fruit developed 27% and 42% scald in Golden Supreme and Delicious apples, respectively, whereas oil-treated fruit were free from scald. Soluble solids content and ethanol production were unaffected by oil treatment. PMID:10888517

  18. Use of oil bodies and oleosins in recombinant protein production and other biotechnological applications.

    PubMed

    Bhatla, S C; Kaushik, V; Yadav, M K

    2010-01-01

    Oil bodies obtained from oilseeds have been exploited for a variety of applications in biotechnology in the recent past. These applications are based on their non-coalescing nature, ease of extraction and presence of unique membrane proteins-oleosins. In suspension, oil bodies exist as separate entities and, hence, they can serve as emulsifying agent for a wide variety of products, ranging from vaccines, food, cosmetics and personal care products. Oil bodies have found significant uses in the production and purification of recombinant proteins with specific applications. The desired protein can be targeted to oil bodies in oilseeds by affinity tag or by fusing it directly to the N or C terminal of oleosins. Upon targeting, the hydrophobic domain of oleosin embeds into the TAG matrix of oil body, whereas the protein fused with N and/or C termini is exposed on the oil body surface, where it acquires correct confirmation spontaneously. Oil bodies with the attached foreign protein can be separated easily from other cellular components. They can be used directly or the protein can be cleaved from the fusion. The desired protein can be a pharmaceutically important polypeptide (e.g. hirudin, insulin and epidermal growth factor), a neutraceutical polypeptide (somatotropin), a commercially important enzyme (e.g. xylanase), a protein important for improvement of crops (e.g. chitinase) or a multimeric protein. These applications can further be widened as oil bodies can also be made artificially and oleosin gene can be expressed in bacterial systems. Thus, a protein fused to oleosin can be expressed in Escherichia coli and after cell lysis it can be incorporated into artificial oil bodies, thereby facilitating the extraction and purification of the desired protein. Artificial oil bodies can also be used for encapsulation of probiotics. The manipulation of oleosin gene for the expression of polyoleosins has further expanded the arena of the applications of oil bodies in

  19. Biodiesel Fuel Production by the Transesterification Reaction of Soybean Oil Using Immobilized Lipase

    NASA Astrophysics Data System (ADS)

    Bernardes, Otávio L.; Bevilaqua, Juliana V.; Leal, Márcia C. M. R.; Freire, Denise M. G.; Langone, Marta A. P.

    The enzymatic alcoholysis of soybean oil with methanol and ethanol was investigated using a commercial, immobilized lipase (Lipozyme RM IM). The effect of alcohol (methanol or ethanol), enzyme concentration, molar ratio of alcohol to soybean oil, solvent, and temperature on biodiesel production was determined. The best conditions were obtained in a solvent-free system with ethanol/oil molar ratio of 3.0, temperature of 50°C, and enzyme concentration of 7.0% (w/w). Three-step batch ethanolysis was most effective for the production of biodiesel. Ethyl esters yield was about 60% after 4 h of reaction.

  20. Production and characterization of refined oils obtained from Indian oil sardine (Sardinella longiceps).

    PubMed

    Chakraborty, Kajal; Joseph, Deepu

    2015-01-28

    Crude Sardinella longiceps oil was refined in different stages such as degumming, neutralization, bleaching, and deodorization. The efficiency of these processes was evaluated on the basis of free fatty acid (FFA), peroxide (PV), p-anisidine (pAV), total oxidation (TOTOX), thiobarbituric acid reactive species (TBARS) values, Lovibond CIE-L*a*b* color analyses, and (1)H NMR or GC-MS experiments. The utilities of NMR-based proton signal characteristics as new analytical tools to understand the signature peaks and relative abundance of different fatty acids and monitoring the refining process of fish oil have been demonstrated. Phosphoric acid (1%) was found to be an effective degumming reagent to obtain oil with the lowest FFA, PV, pAV, TOTOX, and TBARS values and highest color reduction. Significant reduction in the contents of hydrocarbon functionalities as shown by the decrease in proton integral in the characteristic (1)H NMR region was demonstrated by using 1% H3PO4 during the course of the degumming process. A combination (1.25:3.75%) of activated charcoal and Fuller's earth at 3% concentration for a stirring time of 40 min was found to be effective in bleaching the sardine oil. This study demonstrated that unfavorable odor-causing components, particularly low molecular weight carbonyl compounds, could successfully be removed by the refining process. The alkane-dienals/alkanes, which cause unfavorable fishy odors, were successfully removed by distillation (100 °C) under vacuum with aqueous acetic acid solution (0.25 N) to obtain greater quality of refined sardine oil, a rich source of essential fatty acids and improved oxidative stability. The present study demonstrated that the four-stage refinement process of sardine oil resulted in a significant improvement in quality characteristics and nutritional values, particularly n-3 PUFAs, with improved fish oil characteristics for use in the pharmaceutical and functional food industries. PMID:25547196

  1. Microbial Methane Production Associated with Carbon Steel Corrosion in a Nigerian Oil Field

    PubMed Central

    Mand, Jaspreet; Park, Hyung S.; Okoro, Chuma; Lomans, Bart P.; Smith, Seun; Chiejina, Leo; Voordouw, Gerrit

    2016-01-01

    Microbially influenced corrosion (MIC) in oil field pipeline systems can be attributed to many different types of hydrogenotrophic microorganisms including sulfate reducers, methanogens and acetogens. Samples from a low temperature oil reservoir in Nigeria were analyzed using DNA pyrotag sequencing. The microbial community compositions of these samples revealed an abundance of anaerobic methanogenic archaea. Activity of methanogens was demonstrated by incubating samples anaerobically in a basal salts medium, in the presence of carbon steel and carbon dioxide. Methane formation was measured in all enrichments and correlated with metal weight loss. Methanogens were prominently represented in pipeline solids samples, scraped from the inside of a pipeline, comprising over 85% of all pyrosequencing reads. Methane production was only witnessed when carbon steel beads were added to these pipeline solids samples, indicating that no methane was formed as a result of degradation of the oil organics present in these samples. These results were compared to those obtained for samples taken from a low temperature oil field in Canada, which had been incubated with oil, either in the presence or in the absence of carbon steel. Again, methanogens present in these samples catalyzed methane production only when carbon steel was present. Moreover, acetate production was also found in these enrichments only in the presence of carbon steel. From these studies it appears that carbon steel, not oil organics, was the predominant electron donor for acetate production and methane formation in these low temperature oil fields, indicating that the methanogens and acetogens found may contribute significantly to MIC. PMID:26793176

  2. Microbial Methane Production Associated with Carbon Steel Corrosion in a Nigerian Oil Field.

    PubMed

    Mand, Jaspreet; Park, Hyung S; Okoro, Chuma; Lomans, Bart P; Smith, Seun; Chiejina, Leo; Voordouw, Gerrit

    2015-01-01

    Microbially influenced corrosion (MIC) in oil field pipeline systems can be attributed to many different types of hydrogenotrophic microorganisms including sulfate reducers, methanogens and acetogens. Samples from a low temperature oil reservoir in Nigeria were analyzed using DNA pyrotag sequencing. The microbial community compositions of these samples revealed an abundance of anaerobic methanogenic archaea. Activity of methanogens was demonstrated by incubating samples anaerobically in a basal salts medium, in the presence of carbon steel and carbon dioxide. Methane formation was measured in all enrichments and correlated with metal weight loss. Methanogens were prominently represented in pipeline solids samples, scraped from the inside of a pipeline, comprising over 85% of all pyrosequencing reads. Methane production was only witnessed when carbon steel beads were added to these pipeline solids samples, indicating that no methane was formed as a result of degradation of the oil organics present in these samples. These results were compared to those obtained for samples taken from a low temperature oil field in Canada, which had been incubated with oil, either in the presence or in the absence of carbon steel. Again, methanogens present in these samples catalyzed methane production only when carbon steel was present. Moreover, acetate production was also found in these enrichments only in the presence of carbon steel. From these studies it appears that carbon steel, not oil organics, was the predominant electron donor for acetate production and methane formation in these low temperature oil fields, indicating that the methanogens and acetogens found may contribute significantly to MIC. PMID:26793176

  3. Market Trial: Selling Off-Grid Lighting Products in Rural Kenya

    SciTech Connect

    Tracy, Jennifer; Alstone, Peter; Jacobson, Arne; Mills, Evan

    2010-06-21

    In this study, we performed a market trial of off-grid LED lighting products in Maai Mahiu, arural Kenyan town. Our goals were to assess consumer demand and consumer preferences with respect to off-grid lighting systems and to gain feedback from off-grid lighting users at the point of purchase and after they have used to products for some time.

  4. Consumption and quantitation of delta9-tetrahydrocannabinol in commercially available hemp seed oil products.

    PubMed

    Bosy, T Z; Cole, K A

    2000-10-01

    There has been a recent and significant increase in the use and availability of hemp seed oil products. These products are being marketed as a healthy source of essential omega fatty acids when taken orally. Although the health aspects of these oils is open to debate, the probability that oils derived from the hemp seed will contain delta9-tetrahyrdocannabinol (THC) is noteworthy. Recent additions to the literature cite a number of studies illustrating that the ingestion of these products results in urinary levels of the THC metabolite, delta9-tetrahyrdocannabinol carboxylic acid (THCA), well above the administrative cutoff (50 ng/mL) used during random drug screens. Testing performed by our laboratory found that the concentration of THC in hemp oil products has been reduced considerably since the publication of earlier studies. The purpose of this study is to quantitate the THC levels in commercially available hemp oils and to administer those oils tested to THC-free volunteers to determine urine metabolite levels following several 15-g doses. Two extraction protocols were evaluated for removing THC from the oil matrix: a single step liquid-liquid extraction was compared to a two-phase process using both liquid-liquid and solid-phase techniques. Gas chromatography-mass spectrometry was used to determine THC levels in several products: four from Spectrum Essentials (3 bottled oils and 1-g capsules), two from Health from the Sun (1-g capsules and bottled oil) oils, and single samples of both Hempstead and Hempola hemp oils. These hemp oil products contained THC concentrations of 36.0, 36.4, 117.5, 79.5, 48.6, 45.7, 21.0, and 11.5 mg/g, respectively. The Abbott AxSYM FPIA and Roche On-Line KIMS immunoassays were used to screen the urine samples, and GC-MS was used to determine the amount of THC in each oil as well as confirm and quantitate THCA in the urine of study participants immediately before and 6 h after each dose. Peak THCA levels in the participants' urine

  5. DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

    SciTech Connect

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Amit P. Sharma

    2004-10-01

    This report describes the progress of the project ''Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' for the duration of the second project year (October 1, 2003--September 30, 2004). There are three main tasks in this research project. Task 1 is scaled physical model study of GAGD process. Task 2 is further development of vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 is determination of multiphase displacement characteristics in reservoir rocks. In Section I, preliminary design of the scaled physical model using the dimensional similarity approach has been presented. Scaled experiments on the current physical model have been designed to investigate the effect of Bond and capillary numbers on GAGD oil recovery. Experimental plan to study the effect of spreading coefficient and reservoir heterogeneity has been presented. Results from the GAGD experiments to study the effect of operating mode, Bond number and capillary number on GAGD oil recovery have been reported. These experiments suggest that the type of the gas does not affect the performance of GAGD in immiscible mode. The cumulative oil recovery has been observed to vary exponentially with Bond and capillary numbers, for the experiments presented in this report. A predictive model using the bundle of capillary tube approach has been developed to predict the performance of free gravity drainage process. In Section II, a mechanistic Parachor model has been proposed for improved prediction of IFT as well as to characterize the mass transfer effects for miscibility development in reservoir crude oil-solvent systems. Sensitivity studies on model results indicate that provision of a single IFT measurement in the proposed model is sufficient for reasonable IFT predictions. An attempt has been made to correlate the exponent (n) in the mechanistic model with normalized solute compositions present in both fluid phases

  6. DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

    SciTech Connect

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Thaer N.N. Mahmoud; Wagirin Ruiz Paidin

    2006-01-01

    This report describes the progress of the project ''Development And Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' for the duration of the thirteenth project quarter (Oct 1, 2005 to Dec 30, 2005). There are three main tasks in this research project. Task 1 is a scaled physical model study of the GAGD process. Task 2 is further development of a vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 is determination of multiphase displacement characteristics in reservoir rocks. Section I reports experimental work designed to investigate wettability effects of porous medium, on secondary and tertiary mode GAGD performance. The experiments showed a significant improvement of oil recovery in the oil-wet experiments versus the water-wet runs, both in secondary as well as tertiary mode. When comparing experiments conducted in secondary mode to those run in tertiary mode an improvement in oil recovery was also evident. Additionally, this section summarizes progress made with regard to the scaled physical model construction and experimentation. The purpose of building a scaled physical model, which attempts to include various multiphase mechanics and fluid dynamic parameters operational in the field scale, was to incorporate visual verification of the gas front for viscous instabilities, capillary fingering, and stable displacement. Preliminary experimentation suggested that construction of the 2-D model from sintered glass beads was a feasible alternative. During this reporting quarter, several sintered glass mini-models were prepared and some preliminary experiments designed to visualize gas bubble development were completed. In Section II, the gas-oil interfacial tensions measured in decane-CO{sub 2} system at 100 F and live decane consisting of 25 mole% methane, 30 mole% n-butane and 45 mole% n-decane against CO{sub 2} gas at 160 F have been modeled using the Parachor and newly proposed

  7. Hydrothermal liquefaction of oil mill wastewater for bio-oil production in subcritical conditions.

    PubMed

    Hadhoum, Loubna; Balistrou, Mourad; Burnens, Gaëtan; Loubar, Khaled; Tazerout, Mohand

    2016-10-01

    The main purpose of this study is to investigate the direct hydrothermal liquefaction of oil mill wastewater (OMWW). Experiments were carried out at different temperatures (240-300°C), water contents (58-88wt.%) and reaction times (15-45min). Results show that the highest bio-oil yield was about 58wt.%, resulting in a higher heating value of 38MJ/kg. This was conducted at the following optimal conditions: water content 88wt.%, a temperature of 280°C, and 30min as reaction time. To put bio-oil into wide application, the various physical and chemical characteristics were determined. A detailed chemical composition analysis of bio-oil was performed by gas chromatography-mass spectrometry (GC-MS) coupled with a flame ionization detector (FID). The dominant compounds were identified by using NIST library. Analyses show that the bio-oil contains mainly oleic acid, hexadecanoic acid, fatty acid methyl ester, fatty acid ethyl ester, amino acid derived compounds and phenolic compounds. PMID:27344243

  8. Universal Indicators for Oil and Gas Prospecting Based on Bacterial Communities Shaped by Light-Hydrocarbon Microseepage in China.

    PubMed

    Deng, Chunping; Yu, Xuejian; Yang, Jinshui; Li, Baozhen; Sun, Weilin; Yuan, Hongli

    2016-07-28

    Light hydrocarbons accumulated in subsurface soil by long-term microseepage could favor the anomalous growth of indigenous hydrocarbon-oxidizing microorganisms, which could be crucial indicators of underlying petroleum reservoirs. Here, Illumina MiSeq sequencing of the 16S rRNA gene was conducted to determine the bacterial community structures in soil samples collected from three typical oil and gas fields at different locations in China. Incubation with n-butane at the laboratory scale was performed to confirm the presence of "universal microbes" in light-hydrocarbon microseepage ecosystems. The results indicated significantly higher bacterial diversity in next-to-well samples compared with background samples at two of the three sites, which were notably different to oil-contaminated environments. Variation partitioning analysis showed that the bacterial community structures above the oil and gas fields at the scale of the present study were shaped mainly by environmental parameters, and geographic location was able to explain only 7.05% of the variation independently. The linear discriminant analysis effect size method revealed that the oil and gas fields significantly favored the growth of Mycobacterium, Flavobacterium, and Pseudomonas, as well as other related bacteria. The relative abundance of Mycobacterium and Pseudomonas increased notably after n-butane cultivation, which highlighted their potential as biomarkers of underlying oil deposits. This work contributes to a broader perspective on the bacterial community structures shaped by long-term light-hydrocarbon microseepage and proposes relatively universal indicators, providing an additional resource for the improvement of microbial prospecting of oil and gas. PMID:27116995

  9. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir

    SciTech Connect

    1998-06-01

    The application of cyclic CO{sub 2}, often referred to as the CO{sub 2} Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO{sub 2} H-n-P process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital intensive miscible projects. Texaco Exploration and Production Inc. and the US Department of Energy have teamed up in an attempt to develop the CO{sub 2} Huff-n-Puff process in the Grayburg and San Andres formations, a light oil, shallow shelf carbonate reservoir that exists throughout the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir. The selected site for this demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico. The goals of the project are the development of guidelines for cost-effective selection of candidate reservoirs and wells, along with estimating recovery potential. This project has two defined budget periods. The first budget period primarily involves tasks associated with reservoir analysis and characterization, characterizing existing producibility problems, and reservoir simulation of the proposed technology. The final budget period covers the actual field demonstration of the proposed technology. Technology transfer spans the entire course of the project. This report covers the concluding tasks performed under the second budget period.

  10. Oil cakes - a by-product of agriculture industry as a fortificant in bakery products.

    PubMed

    Behera, Satyabadi; Indumathi, K; Mahadevamma, S; Sudha, M L

    2013-11-01

    Groundnut cake (GNC) and soybean cake (SBC) by-product of agriculture industry had protein and protein digestibility in the range of 42.7-50.5 and 71.3-76.8%, respectively. Polyphenols present in GNC and SBC were cholorogenic acid, syringic acid and p-coumaric acid. The number of bands separated in soybean meal was greater than the bands observed in GNC flour as seen in SDS-PAGE pattern, respectively. SEM of groundnut flour showed distension of protein bodies due to roasting of the oil cakes. The water absorption of wheat flour GNC blends decreased from 59.2 to 57.3% and increased in wheat flour SBC blends from 59.2 to 68.3% with an increase in oil cake from 0 to 20%. With increase in either GNC or SBC, the biscuits became harder. Addition of glycerol monostearate and sodium stearoyl lactylate in combination with 20% blend of GNC/SBC decreased the breaking strength values and increased the sensory parameters of the biscuits. Nutritionally rich biscuits were thus prepared by incorporating GNC/SBC. PMID:23742142

  11. Development of an In Situ Biosurfactant Production Technology for Enhanced Oil Recovery

    SciTech Connect

    M.J. McInerney; R.M. Knapp; Kathleen Duncan; D.R. Simpson; N. Youssef; N. Ravi; M.J. Folmsbee; T.Fincher; S. Maudgalya; Jim Davis; Sandra Weiland

    2007-09-30

    The long-term economic potential for enhanced oil recovery (EOR) is large with more than 300 billion barrels of oil remaining in domestic reservoirs after conventional technologies reach their economic limit. Actual EOR production in the United States has never been very large, less than 10% of the total U. S. production even though a number of economic incentives have been used to stimulate the development and application of EOR processes. The U.S. DOE Reservoir Data Base contains more than 600 reservoirs with over 12 billion barrels of unrecoverable oil that are potential targets for microbially enhanced oil recovery (MEOR). If MEOR could be successfully applied to reduce the residual oil saturation by 10% in a quarter of these reservoirs, more than 300 million barrels of oil could be added to the U.S. oil reserve. This would stimulate oil production from domestic reservoirs and reduce our nation's dependence on foreign imports. Laboratory studies have shown that detergent-like molecules called biosurfactants, which are produced by microorganisms, are very effective in mobilizing entrapped oil from model test systems. The biosurfactants are effective at very low concentrations. Given the promising laboratory results, it is important to determine the efficacy of using biosurfactants in actual field applications. The goal of this project is to move biosurfactant-mediated oil recovery from laboratory investigations to actual field applications. In order to meet this goal, several important questions must be answered. First, it is critical to know whether biosurfactant-producing microbes are present in oil formations. If they are present, then it will be important to know whether a nutrient regime can be devised to stimulate their growth and activity in the reservoir. If biosurfactant producers are not present, then a suitable strain must be obtained that can be injected into oil reservoirs. We were successful in answering all three questions. The specific objectives

  12. Open-source products for a lighting experiment device.

    PubMed

    Gildea, Kevin M; Milburn, Nelda

    2014-12-01

    The capabilities of open-source software and microcontrollers were used to construct a device for controlled lighting experiments. The device was designed to ascertain whether individuals with certain color vision deficiencies were able to discriminate between the red and white lights in fielded systems on the basis of luminous intensity. The device provided the ability to control the timing and duration of light-emitting diode (LED) and incandescent light stimulus presentations, to present the experimental sequence and verbal instructions automatically, to adjust LED and incandescent luminous intensity, and to display LED and incandescent lights with various spectral emissions. The lighting device could easily be adapted for experiments involving flashing or timed presentations of colored lights, or the components could be expanded to study areas such as threshold light perception and visual alerting systems. PMID:24281687

  13. Nonlinear joint dynamics between prices of crude oil and refined products

    NASA Astrophysics Data System (ADS)

    Zhang, Tao; Ma, Guofeng; Liu, Guangsheng

    2015-02-01

    In this paper, we investigate the relationships between crude oil and refined product prices. We find that nonlinear correlations are stronger in the long-term than in the short-term. Crude oil and product prices are cointegrated and financial crisis in 2007-2008 caused a structural break of the cointegrating relationship. Moreover, different from the findings in most studies, we reveal that the relationships are almost symmetric based on a threshold error correction model. The so-called 'asymmetric relationships' are caused by some outliers and financial crisis. Most of the time, crude oil prices play the major role in the adjustment process of the long-term equilibrium. However, refined product prices dominated crude oil prices during the period of financial crisis. Important policy and risk management implications can be learned from the empirical findings.

  14. [Treatment of simulated produced wastewater from polymer flooding in oil production using dithiocarbamate-type flocculant].

    PubMed

    Gao, Yue; Jia, Yu-Yan; Gao, Bao-Yu; Cao, Bai-Chuan; Zhang, Yong-Qiang; Lu, Lei

    2010-10-01

    A dithiocarbamate flocculant, DTC (T403), was prepared by the reaction of amine-terminated polyoxypropane-ether compound known as Jeffamine-T403 and carbon disulfide in alkaline solution. The oil removal efficiency of DTC (T403) for simulated produced wastewater from polymer flooding in oil production was studied by Jar-test. The effect of the dosage of DTC (T403), hydrolyzed polyacrylamide (HPAM), Fe2+ and Fe3+ ions, and pH on the oil removal efficiency of DTC (T403) was investigated. The results showed that the chelate polymer formed by DTC (T403) and Fe2+ ion has good oil removal performance by net capturing mechanism. HPAM had a negative effect on oil removal efficiency of DTC (T403). For the treatment of the simulated wastewater containing 0-900 mg/L of HPAM and 300 mg/L of oil, the residual oil concentrations in water samples decreased below 10 mg/L when the dosage of Fe2+ and DTC (T403) was 10 mg/L and 25 mg/L, respectively. The oil removal efficiency of DTC (T403) was affected by pH and good oil removal efficiency was obtained when the pH was below 7.5. DTC (T403) is appropriate for the treatment of oily wastewater containing Fe2+ ion. PMID:21229744

  15. Activation of the biochemical processes in an oil-contaminated soil using a light-correcting film and humic acids

    NASA Astrophysics Data System (ADS)

    Filatov, D. A.; Ivanov, A. A.; Svarovskaya, L. I.; Yudina, N. V.

    2011-02-01

    It was shown that the use of a light-correcting film as a covering material for an oil-contaminated soil in combination with humic acids increased the number of the main physiological groups of the soil microorganisms responsible for the development of the soil's fertility (heterotrophic bacteria, actinomycetes, and micromycetes) by 60-100 times. The activity of the soil enzymes (catalase, dehydrogenase, polyphenoloxidase, peroxidase, and urease) increased by 3-6 times. The biochemical oxidation of oil hydrocarbons in the soil became significantly more intense.

  16. Determination of lipid oxidation products in vegetable oils and marine omega-3 supplements

    PubMed Central

    Halvorsen, Bente Lise; Blomhoff, Rune

    2011-01-01

    Background There is convincing evidence that replacing dietary saturated fats with polyunsaturated fats (PUFA) decreases risk of cardiovascular diseases. Therefore, PUFA rich foods such as vegetable oils, fatty fish, and marine omega-3 supplements are recommended. However, PUFA are easily oxidizable and there is concern about possible negative health effects from intake of oxidized lipids. Little is known about the degree of lipid oxidation in such products. Objective To assess the content of lipid oxidation products in a large selection of vegetable oils and marine omega-3 supplements available in Norway. Both fresh and heated vegetable oils were studied. Design A large selection of commercially available vegetable oils and marine omega-3 supplements was purchased from grocery stores, pharmacies, and health food stores in Norway. The content of lipid oxidation products were measured as peroxide value and alkenal concentration. Twelve different vegetable oils were heated for a temperature (225°C) and time (25 minutes) resembling conditions typically used during cooking. Results The peroxide values were in the range 1.04–10.38 meq/kg for omega-3 supplements and in the range 0.60–5.33 meq/kg for fresh vegetable oils. The concentration range of alkenals was 158.23–932.19 nmol/mL for omega-3 supplements and 33.24–119.04 nmol/mL for vegetable oils. After heating, a 2.9–11.2 fold increase in alkenal concentration was observed for vegetable oils. Conclusions The contents of hydroperoxides and alkenals in omega-3 supplements are higher than in vegetable oils. After heating vegetable oils, a large increase in alkenal concentration was observed. PMID:21691461

  17. Oil production by entrained pyrolysis of biomass and processing of oil and char

    DOEpatents

    Knight, James A.; Gorton, Charles W.

    1990-01-02

    Entrained pyrolysis of lignocellulosic material proceeds from a controlled pyrolysis-initiating temperature to completion of an oxygen free environment at atmospheric pressure and controlled residence time to provide a high yield recovery of pyrolysis oil together with char and non-condensable, combustible gases. The residence time is a function of gas flow rate and the initiating temperature is likewise a function of the gas flow rate, varying therewith. A controlled initiating temperature range of about 400.degree. C. to 550.degree. C. with corresponding gas flow rates to maximize oil yield is disclosed.

  18. Effect of plant oils upon lipase and citric acid production in Yarrowia lipolytica yeast.

    PubMed

    Darvishi, Farshad; Nahvi, Iraj; Zarkesh-Esfahani, Hamid; Momenbeik, Fariborz

    2009-01-01

    The nonconventional yeast Yarrowia lipolytica degrades very efficiently hydrophobic substrates to produce organic acids, single-cell oil, lipases, and so forth. The aim of this study was to investigate the biochemical behavior and simultaneous production of valuable metabolites such as lipase, citric acid (CA), and single-cell protein (SCP) by Yarrowia lipolytica DSM 3286 grown on various plant oils as sole carbon source. Among tested plant oils, olive oil proved to be the best medium for lipase and CA production. The Y. lipolytica DSM 3286 produced 34.6 +/- 0.1 U/mL of lipase and also CA and SCP as by-product on olive oil medium supplemented with yeast extract. Urea, as organic nitrogen, was the best nitrogen source for CA production. The results of this study suggest that the two biotechnologically valuable products, lipase and CA, could be produced simultaneously by this strain using renewable low-cost substrates such as plant oils in one procedure. PMID:19826636

  19. Effect of Plant Oils upon Lipase and Citric Acid Production in Yarrowia lipolytica Yeast

    PubMed Central

    Darvishi, Farshad; Nahvi, Iraj; Zarkesh-Esfahani, Hamid; Momenbeik, Fariborz

    2009-01-01

    The nonconventional yeast Yarrowia lipolytica degrades very efficiently hydrophobic substrates to produce organic acids, single-cell oil, lipases, and so forth. The aim of this study was to investigate the biochemical behavior and simultaneous production of valuable metabolites such as lipase, citric acid (CA), and single-cell protein (SCP) by Yarrowia lipolytica DSM 3286 grown on various plant oils as sole carbon source. Among tested plant oils, olive oil proved to be the best medium for lipase and CA production. The Y. lipolytica DSM 3286 produced 34.6 ± 0.1 U/mL of lipase and also CA and SCP as by-product on olive oil medium supplemented with yeast extract. Urea, as organic nitrogen, was the best nitrogen source for CA production. The results of this study suggest that the two biotechnologically valuable products, lipase and CA, could be produced simultaneously by this strain using renewable low-cost substrates such as plant oils in one procedure. PMID:19826636

  20. Bio-oil production via catalytic pyrolysis of Anchusa azurea: Effects of operating conditions on product yields and chromatographic characterization.

    PubMed

    Aysu, Tevfik; Durak, Halil; Güner, Serkan; Bengü, Aydın Şükrü; Esim, Nevzat

    2016-04-01

    Pyrolysis of Anchusa azurea, a lignocellulosic gramineous plant, was carried out in a tubular, fixed-bed reactor in the presence of four catalysts (Ca(OH)2, Na2CO3, ZnCl2, Al2O3). The influences of pyrolysis parameters such as catalyst and temperature on the yields of products were studied. It was found that higher temperature resulted in lower liquid (bio-oil) and solid (bio-char) yields and higher gas yields. Catalysts effected the yields of products differently and the composition of bio-oils. Liquid yields were increased in the presence of Na2CO3, ZnCl2 and Al2O3 and decreased with Ca(OH)2. The highest bio-oil yield (34.05%) by weight including aqueous phase was produced with Na2CO3 catalyst at 450°C. The yields of products (bio-char, bio-oil and gas) and the compositions of the resulting bio-oils were determined by GC-MS, FT-IR and elemental analysis. GC-MS identified 124 and 164 different compounds in the bio-oils obtained at 350 and 550°C respectively. PMID:26800388

  1. Chemical Composition and Bioactivity of Essential Oil of Atalantia guillauminii against Three Species Stored Product Insects.

    PubMed

    Yang, Kai; You, Chun-Xue; Wang, Cheng-Fang; Lei, Ning; Guo, Shan-Shan; Geng, Zhu-Feng; Du, Shu-Shan; Ma, Ping; Deng, Zhi-Wei

    2015-01-01

    The toxic and repellent activities of the essential oil extracted from the leaves of Atalantia guillauminii Swingle were evaluated against three stored product insects, red flour beetles (Tribolium castaneum), cigarette beetles (Lasioderma serricorne) and booklice (Liposcelis bostrychophila). The essential oil obtained by hydrodistillation was investigated by GC-MS. The main constituents of the essential oil were β-thujene (27.18%), elemicin (15.03%), eudesma-3, 7(11)-diene (9.64%), followed by (-)-4-terpeniol (6.70%) and spathulenol (5.25%). The crude oil showed remarkable contact toxicity against T. castaneum, L. serricorne adults and L. bostrychophila with LD50 values of 17.11, 24.07 µg/adult and 55.83 µg/cm(2) respectively and it also displayed strong fumigant toxicity against T. castaneum, L. serricorne adults with LC50 values of 17.60 and 12.06 mg/L respectively, while weak fumigant toxicity against L. bostrychophila with a LC50 value of 16.75 mg/L. Moreover, the essential oil also exhibited the same level repellency against the three stored product insects, relative to the positive control, DEET. At the same concentrations, the essential oil was more repellent to T. castaneum than to L. serricorne. Thus, the essential oil of A. guillauminii may be potential to be developed as a new natural fumigant/repellent in the control of stored product insects. PMID:26369599

  2. Citric acid production in Yarrowia lipolytica SWJ-1b yeast when grown on waste cooking oil.

    PubMed

    Liu, Xiaoyan; Lv, Jinshun; Xu, Jiaxing; Zhang, Tong; Deng, Yuanfang; He, Jianlong

    2015-03-01

    In this study, citric acid was produced from waste cooking oil by Yarrowia lipolytica SWJ-1b. To get the maximal yield of citric acid, the compositions of the medium for citric acid production were optimized, and our results showed that extra nitrogen and magnesium rather than vitamin B1 and phosphate were needed for CA accumulation when using waste cooking oil. The results also indicated that the optimal initial concentration of the waste cooking oil in the medium for citric acid production was 80.0 g/l, and the ideal inoculation size was 1 × 10(7) cells/l of medium. We also reported that during 10-l fermentation, 31.7 g/l of citric acid, 6.5 g/l of isocitric acid, 5.9 g/l of biomass, and 42.1 g/100.0 g cell dry weight of lipid were attained from 80.0 g/l of waste cooking oil within 336 h. At the end of the fermentation, 94.6 % of the waste cooking oil was utilized by the cells of Y. lipolytica SWJ-1b, and the yield of citric acid was 0.4 g/g waste cooking oil, which suggested that waste cooking oil was a suitable carbon resource for citric acid production. PMID:25488499

  3. Production of polyhydroxyalkanoates (PHAs) with canola oil as carbon source.

    PubMed

    López-Cuellar, M R; Alba-Flores, J; Rodríguez, J N Gracida; Pérez-Guevara, F

    2011-01-01

    Wautersia eutropha was able to synthesize medium chain length polyhydroxyalkanoates (PHAs) when canola oil was used as carbon source. W. eutropha was cultivated using fructose and ammonium sulphate as carbon and nitrogen sources, respectively, for growth and inoculum development. The experiments were done in a laboratory scale bioreactor in three stages. Initially, the biomass was adapted in a batch culture. Secondly, a fed-batch was used to increase the cell dry weight and PHA concentration to 4.36 g L(-1) and 0.36 g L(-1), respectively. Finally, after the addition of canola oil as carbon source a final concentration of 18.27 g L(-1) PHA was obtained after 40 h of fermentation. With canola oil as carbon source, the polymer content of the cell dry matter was 90%. The polymer was purified from dried cells and analyzed by FTIR, NMR and DSC using PHB as reference. The polymer produced by W. eutropha from canola oil had four carbon monomers in the structure of the PHA and identified by 1H and 13C NMR analysis as 3-hydroxybutyrate (3HB), 3-hydroxyvalerate (3HV), 3-hydroxyoctanoate (3HO), and 3-hydroxydodecanoate (3HDD). PMID:20933541

  4. Evaluating Sustainability: Soap versus Biodiesel Production from Plant Oils

    ERIC Educational Resources Information Center

    Pohl, Nicola L. B.; Streff, Jennifer M.; Brokman, Steve

    2012-01-01

    Herein we describe a series of experiments for the undergraduate organic laboratory curriculum in which various plant oils (soybean, rapeseed, and olive) are subjected to saponification and transesterification reactions to create a set of compounds that can function as soaps or as fuels. The experiments introduce students to and asks them to…

  5. Biobased lubricants and functional products from Cuphea oil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Cuphea (Lythraceae) is an annual plant that produces a small seed rich in saturated medium-chain triacylglycerols (TAGs). With the need for higher seed yields, oil content, and less seed shattering, Oregon State University began developing promising cuphea crosses. Cuphea PSR23 is a hybrid between C...

  6. Production and applications of ferulate-modified vegetable oil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Concerns have been raised about the potential adverse health and ecological effects of the commonly used sunscreen active ingredients. A sunscreen active ingredient can be derived from two natural plant components, ferulic acid and vegetable oil triglycerides. Transesterification of ferulic acid e...

  7. EOR initiative: A strategy for enhanced domestic oil production

    SciTech Connect

    Not Available

    1988-08-01

    The Assistant Secretary for Fossil Energy directed that a review be made to determine whether an expanded petroleum initiative could be fashioned to respond positively to the current situation. This report is the result of that review. It sets forth what might be done from a technical standpoint to help mitigate the problems being experienced in the domestic oil industry.

  8. Production and analysis of fast pyrolysis oils from proteinaceous biomass

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Fast pyrolysis of lignocellulosic biomass is a facile method for producing high yields of liquid fuel intermediates. However, because most fast pyrolysis oils are highly oxygenated, acidic and unstable identification of feedstocks that produce higher quality pyrolysis liquids is desirable. Therefor...

  9. Optimization of biodiesel production process using recycled vegetable oil

    NASA Astrophysics Data System (ADS)

    Lugo, Yarely

    Petro diesel toxic emissions and its limited resources have created an interest for the development of new energy resources, such as biodiesel. Biodiesel is traditionally produced by a transesterification reaction between vegetable oil and an alcohol in the presence of a catalyst. However, this process is slow and expensive due to the high cost of raw materials. Low costs feedstock oils such as recycled and animal fats are available but they cannot be transesterified with alkaline catalysts due to high content of free fatty acids, which can lead to undesirable reactions such as saponification. In this study, we reduce free fatty acids content by using an acid pre-treatment. We compare sulfuric acid, hydrochloric acid and ptoluenesulfonic acid (PTSA) to pre-treat recycled vegetable oil. PTSA removes water after 60 minutes of treatment at room temperature or within 15 minutes at 50°C. The pretreatment was followed by a transesterification reaction using alkaline catalyst. To minimize costs and accelerate reaction, the pretreatment and transesterification reaction of recycle vegetable oil was conducted at atmospheric pressure in a microwave oven. Biodiesel was characterized using a GC-MS method.

  10. Floating production systems (FPS): Troll Oil and Kvaerner Concrete Semis

    SciTech Connect

    Loeset, O.

    1995-10-01

    This paper describes the main features of the Troll Oil concrete semi platform and the improvements and optimization carried further by the Kvaerner Concrete Semi. Significant elements contributing to marked cost reductions are pointed out, demonstrating the competitiveness of the concrete hull semi submersible platform.

  11. Ketonization of Cuphea oil for the production of 2-undecanone

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The objective of this work was to demonstrate the viability of the cross ketonization reaction with the triacylglycerol from Cuphea sp. and acetic acid in a fixed-bed plug-flow reactor. The seed oil from Cuphea sp. contains up to 71% decanoic acid and the reaction of this fatty acid residue with ac...

  12. Comparison of the constituents of two jet engine lubricating oils and their volatile pyrolytic degradation products.

    PubMed

    van Netten, C; Leung, V

    2000-03-01

    Leaking oil seals in jet engines, at locations prior to the compressor stage, can be a cause of smoke in the cabins of BAe-146 aircraft. Compressed combustion air is bled off to pressurize the cabin and to provide a source of fresh air. Bleed air is diverted from a location just prior to the combustion chamber at a temperature around 500 degrees C. To prevent oil breakdown products from entering the cabin air, catalytic converters have been used to clean the air. During an oil seal failure this device becomes overloaded and smoke is observed in the cabin. Some aircraft companies have removed the catalytic converters and claim an improvement in air quality. During an oil seal failure, however, the flight crew is potentially exposed to the thermal breakdown products of the engine oils. Because very little is known regarding the thermal breakdown products of jet engine lubrication oils, two commercially available oils were investigated under laboratory conditions at 525 degrees C to measure the release of CO, CO2,NO2, and HCN as well as volatiles which were analyzed using GC-Mass spectrometry in an attempt to see if the neurotoxic agents tricresyl phosphates (TCPs) and trimethyl propane phosphate (TMPP) would be present or formed. TMPP was not found in these experiments. Some CO2 was generated along with CO which reached levels in excess of 100 ppm. HCN and NO2 were not detected. GC compositions of the two bulk oils and their breakdown products were almost identical. The presence of TCPs was confirmed in the bulk oils and in the volatiles. Localized condensation in the ventilation ducts and filters in the air conditioning packs are likely the reason why the presence of TCPs has not been demonstrated in cabin air. It was recommended that this needed to be verified in aircraft. PMID:10701290

  13. Inhibitory Effect of Essential Oils on Aspergillus ochraceus Growth and Ochratoxin A Production

    PubMed Central

    Selvaraj, Jonathan Nimal; Wang, Yan; Zhao, Yueju; Zhou, Lu; Liu, Xiao; Liu, Yang

    2014-01-01

    Ochratoxin A (OTA) is a mycotoxin which is a common contaminant in grains during storage. Aspergillus ochraceus is the most common producer of OTA. Essential oils play a crucial role as a biocontrol in the reduction of fungal contamination. Essential oils namely natural cinnamaldehyde, cinnamon oil, synthetic cinnamaldehyde, Litsea citrate oil, citral, eugenol, peppermint, eucalyptus, anise and camphor oils, were tested for their efficacy against A. ochraceus growth and OTA production by fumigation and contact assays. Natural cinnamaldehyde proved to be the most effective against A. ochraceus when compared to other oils. Complete fungal growth inhibition was obtained at 150–250 µL/L with fumigation and 250–500 µL/L with contact assays for cinnamon oil, natural and synthetic cinnamaldehyde, L. citrate oil and citral. Essential oils had an impact on the ergosterol biosynthesis and OTA production. Complete inhibition of ergosterol biosynthesis was observed at ≥100 µg/mL of natural cinnamaldehyde and at 200 µg/mL of citral, but total inhibition was not observed at 200 µg/mL of eugenol. But, citral and eugenol could inhibit the OTA production at ≥75 µg/mL and ≥150 µg/mL respectively, while natural cinnamaldehyde couldn’t fully inhibit OTA production at ≤200 µg/mL. The inhibition of OTA by natural cinnamaldehyde is mainly due to the reduction in fungal biomass. However, citral and eugenol could significant inhibit the OTA biosynthetic pathway. Also, we observed that cinnamaldehyde was converted to cinnamic alcohol by A. ochraceus, suggesting that the antimicrobial activity of cinnamaldehyde was mainly attributed to its carbonyl aldehyde group. The study concludes that natural cinnamaldehyde, citral and eugenol could be potential biocontrol agents against OTA contamination in storage grains. PMID:25255251

  14. Carbon isotopic comparisons of oil products used in the developmental history of Alaska

    USGS Publications Warehouse

    Kvenvolden, K.A.; Carlson, P.R.; Warden, A.; Threlkeld, C.N.

    1998-01-01

    Studies of the fate of oil released into Prince William Sound, AK, as a result of the 1989 Exxon Valdez oil spill, have led to an unexpected discovery. In addition to oil-like residues attributed to the spill, the ubiquitous presence of flattened tar balls, the carbon isotopic compositions of which fall within a surprisingly narrow range [??13C(PDB) = -23.7 ?? 0.3??? (n = 65)], were observed on the shorelines of the northern and western parts of the sound. These compositions are similar to those of some oil products [-23.7 ?? 0.7??? (n = 35)] that were shipped from California and used in Alaska for fuel, lubrication, construction, and paving before ~ 1970. These products include fuel oil, asphalt, and lubricants [-23.8 ?? 0.5??? (n = 11)], caulking, sealants, and roofing tar [-23.7 ?? 0.7??? (n = 16)], and road pavements and airport runways [-23.5 ?? 0.9??? (n = 8)]. Fuel oil and asphalt [-23.5 ?? 0.1??? (n = 3)], stored at the old Valdez town site and spilled during the 1964 Alaskan earthquake, appear to be the source of most of the beached tar balls. Oil products with lighter carbon isotopic compositions, between -25 and -30??? (n = 18), appear to have been used more recently in Alaska, that is, after ~ 1970. The source of some of the products used for modern pavement and runways [-29.3 ?? 0.2??? (n = 6)] is likely Alaskan North Slope crude oil, an example of which was spilled in the 1989 oil spill [-29.2??? (n = 1)].

  15. Inhibitory effect of essential oils on Aspergillus ochraceus growth and ochratoxin A production.

    PubMed

    Hua, Huijuan; Xing, Fuguo; Selvaraj, Jonathan Nimal; Wang, Yan; Zhao, Yueju; Zhou, Lu; Liu, Xiao; Liu, Yang

    2014-01-01

    Ochratoxin A (OTA) is a mycotoxin which is a common contaminant in grains during storage. Aspergillus ochraceus is the most common producer of OTA. Essential oils play a crucial role as a biocontrol in the reduction of fungal contamination. Essential oils namely natural cinnamaldehyde, cinnamon oil, synthetic cinnamaldehyde, Litsea citrate oil, citral, eugenol, peppermint, eucalyptus, anise and camphor oils, were tested for their efficacy against A. ochraceus growth and OTA production by fumigation and contact assays. Natural cinnamaldehyde proved to be the most effective against A. ochraceus when compared to other oils. Complete fungal growth inhibition was obtained at 150-250 µL/L with fumigation and 250-500 µL/L with contact assays for cinnamon oil, natural and synthetic cinnamaldehyde, L. citrate oil and citral. Essential oils had an impact on the ergosterol biosynthesis and OTA production. Complete inhibition of ergosterol biosynthesis was observed at ≥ 100 µg/mL of natural cinnamaldehyde and at 200 µg/mL of citral, but total inhibition was not observed at 200 µg/mL of eugenol. But, citral and eugenol could inhibit the OTA production at ≥ 75 µg/mL and ≥ 150 µg/mL respectively, while natural cinnamaldehyde couldn't fully inhibit OTA production at ≤ 200 µg/mL. The inhibition of OTA by natural cinnamaldehyde is mainly due to the reduction in fungal biomass. However, citral and eugenol could significant inhibit the OTA biosynthetic pathway. Also, we observed that cinnamaldehyde was converted to cinnamic alcohol by A. ochraceus, suggesting that the antimicrobial activity of cinnamaldehyde was mainly attributed to its carbonyl aldehyde group. The study concludes that natural cinnamaldehyde, citral and eugenol could be potential biocontrol agents against OTA contamination in storage grains. PMID:25255251

  16. An example of using oil-production induced microseismicity in characterizing a naturally fractured reservoir

    SciTech Connect

    Rutledge, J.T.; Phillips, W.S.; Schuessler, B.K.; Anderson, D.W.

    1996-06-01

    Microseismic monitoring was conducted using downhole geophone tools deployed in the Seventy-Six oil field, Clinton County, Kentucky. Over a 7-month monitoring period, 3237 microearthquakes were detected during primary oil production; no injection operations were conducted. Gross changes in production rate correlate with microearthquake event rate with event rate lagging production-rate changes by about 2 weeks. Hypocenters and first-motion data have revealed low-angle, thrust fracture zones above and below the currently drained depth interval. Production history, well logs and drill tests indicate the seismically-active fractures are previously drained intervals that have subsequently recovered to hydrostatic pressure via brine invasion. The microseismic data have revealed, for the first time, the importance of the low-angle fractures in the storage and production of oil in the study area. The seismic behavior is consistent with poroelastic models that predict slight increases in compressive stress above and below currently drained volumes.

  17. Effect of Nitrogen, Location and Harvesting Stage on Peppermint Productivity, Oil Content and Oil Composition

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Peppermint (Mentha •piperita) is currently not a common crop in the southeastern United States. Recently, there has been an interest in peppermint as an essential oil crop for this region. In 2007, a 'eld experiment was conducted in Mississippi to determine the effect of nitrogen (N) (0 and 80 kg•ha...

  18. Ozone production at the National Synchrotron Light Source

    SciTech Connect

    Weilandics, C.; Rohrig, N.; Gmur, N.F.

    1987-01-01

    Ozone production by synchrotron radiation as a function of power density in air was investigated using a white beam at the BNL National Synchrotron Light Source (NSLS) x-ray ring. Power densities were calculated from the energy spectrum at 2.52 GeV. Ozone concentrations in small beam pipes were measured for power densities between I = 10/sup 12/ and 10/sup 15/ eV . cm/sup -3/ . sec/sup -1/. The measured ozone half-life was 37 +- 2 min. The measured G-value was 2.69 +- 0.14 mol/100 eV and the ozone destruction factor k was less than 7 x 10/sup -19/ cm/sup 3/ . eV/sup -1/. The random uncertainties stated are approximately one standard error. The large departure of the values for G and k from previous values suggest that some undiscovered systematic error may exist in the experiment. Ozone concentration in excess of the 0.1 ppM ACGIH TLV can be generated in the experimental hutches but can readily be controlled. Industrial hygiene aspects of operation and possible control measures will be discussed. 19 refs., 7 figs., 3 tabs.

  19. Production of Energetic Light Fragments in Spallation Reactions

    NASA Astrophysics Data System (ADS)

    Mashnik, Stepan G.; Kerby, Leslie M.; Gudima, Konstantin K.; Sierk, Arnold J.

    2014-03-01

    Different reaction mechanisms contribute to the production of light fragments (LF) from nuclear reactions. Available models cannot accurately predict emission of LF from arbitrary reactions. However, the emission of LF is important formany applications, such as cosmic-ray-induced single event upsets, radiation protection, and cancer therapy with proton and heavy-ion beams, to name just a few. The cascade-exciton model (CEM) and the Los Alamos version of the quark-gluon string model (LAQGSM), as implemented in the CEM03.03 and LAQGSM03.03 event generators used in the Los Alamos Monte Carlo transport code MCNP6, describe quite well the spectra of fragments with sizes up to 4He across a broad range of target masses and incident energies. However, they do not predict high-energy tails for LF heavier than 4He. The standard versions of CEM and LAQGSM do not account for preequilibrium emission of LF larger than 4He. The aim of our work is to extend the preequilibrium model to include such processes. We do this by including the emission of fragments heavier than 4He at the preequilibrium stage, and using an improved version of the Fermi Break-up model, providing improved agreement with various experimental data.

  20. The physics of Cerenkov light production during proton therapy.

    PubMed

    Helo, Y; Kacperek, A; Rosenberg, I; Royle, G; Gibson, A P

    2014-12-01

    There is increasing interest in using Cerenkov emissions for quality assurance and in vivo dosimetry in photon and electron therapy. Here, we investigate the production of Cerenkov light during proton therapy and its potential applications in proton therapy. A primary proton beam does not have sufficient energy to generate Cerenkov emissions directly, but we have demonstrated two mechanisms by which such emissions may occur indirectly: (1) a fast component from fast electrons liberated by prompt gamma (99.13%) and neutron (0.87%) emission; and (2) a slow component from the decay of radioactive positron emitters. The fast component is linear with dose and doserate but carries little spatial information; the slow component is non-linear but may be localised. The properties of the two types of emission are explored using Monte Carlo modelling in GEANT4 with some experimental verification. We propose that Cerenkov emissions could contribute to the visual sensation reported by some patients undergoing proton therapy of the eye and we discuss the feasibility of some potential applications of Cerenkov imaging in proton therapy. PMID:25365447

  1. The physics of Cerenkov light production during proton therapy

    NASA Astrophysics Data System (ADS)

    Helo, Y.; Kacperek, A.; Rosenberg, I.; Royle, G.; Gibson, A. P.

    2014-12-01

    There is increasing interest in using Cerenkov emissions for quality assurance and in vivo dosimetry in photon and electron therapy. Here, we investigate the production of Cerenkov light during proton therapy and its potential applications in proton therapy. A primary proton beam does not have sufficient energy to generate Cerenkov emissions directly, but we have demonstrated two mechanisms by which such emissions may occur indirectly: (1) a fast component from fast electrons liberated by prompt gamma (99.13%) and neutron (0.87%) emission; and (2) a slow component from the decay of radioactive positron emitters. The fast component is linear with dose and doserate but carries little spatial information; the slow component is non-linear but may be localised. The properties of the two types of emission are explored using Monte Carlo modelling in GEANT4 with some experimental verification. We propose that Cerenkov emissions could contribute to the visual sensation reported by some patients undergoing proton therapy of the eye and we discuss the feasibility of some potential applications of Cerenkov imaging in proton therapy.

  2. Methyl ester of [Maclura pomifera (Rafin.) Schneider] seed oil: biodiesel production and characterization.

    PubMed

    Saloua, Fatnassi; Saber, Chatti; Hedi, Zarrouk

    2010-05-01

    Oil extracted from seeds of Maclura pomifera fruits grown in Tunisia was investigated as an alternative feedstock for the production of biodiesel fuel. Biodiesel was prepared by transesterification of the crude oil with methanol in the presence of NaOH as catalyst. Maximum oil to ester conversion was 90%. The viscosity of the biodiesel oil (4.66 cSt) is similar to that of petroleum diesel (2.5-3.5 cSt). The density (0.889 g/cm(3)), kinematic viscosity (4.66 cSt), flash point (180 degrees Celsius), iodine number (125 degrees Celsius), neutralization number (0.4), pour point (-9 degrees Celsius), cloud point (-5 degrees Celsius), cetane number (48) are very similar to the values set forth by the ASTM and EN biodiesel standards for petroleum diesel (No. 2). The comparison shows that the methyl esters of M. pomifera oil could be possible diesel fuel replacements. PMID:20060293

  3. Catalytic cracking of palm oil for the production of biofuels: optimization studies.

    PubMed

    Tamunaidu, Pramila; Bhatia, Subhash

    2007-12-01

    Oil palm is widely grown in Malaysia. Palm oil has attracted the attention of researchers to develop an 'environmentally friendly' and high quality fuel, free of nitrogen and sulfur. In the present study, the catalytic cracking of palm oil to biofuel was studied over REY catalyst in a transport riser reactor at atmospheric pressure. The effect of reaction temperature (400-500 degrees C), catalyst/palm oil ratio (5-10) and residence time (10-30s) was studied over the yield of bio-gasoline and gas as fuel. Design of experiments was used to study the effect of operating variables over conversion of palm oil and yield of hydrocarbon fuel. The response surface methodology was used to determine the optimum value of the operating variables for maximum yield of bio-gasoline fraction in the liquid product obtained. PMID:17208441

  4. Use of array of conducting polymers for differentiation of coconut oil products.

    PubMed

    Rañola, Rey Alfred G; Santiago, Karen S; Sevilla, Fortunato B

    2016-01-01

    An array of chemiresistors based on conducting polymers was assembled for the differentiation of coconut oil products. The chemiresistor sensors were fabricated through the potentiostatic electrodeposition of polyaniline (PANi), polypyrrole (PPy) and poly(3-methylthiophene) (P-3MTp) on the gap separating two planar gold electrodes set on a Teflon substrate. The change in electrical resistance of the sensors was measured and observed after exposing the array to the headspace of oil samples. The sensor response was found rapid, reversible and reproducible. Different signals were obtained for each coconut oil sample and pattern recognition techniques were employed for the analysis of the data. The developed system was able to distinguish virgin coconut oil (VCO) from refined, bleached & deodorised coconut oil (RBDCO), flavoured VCO, homemade VCO, and rancid VCO. PMID:26695237

  5. Assessment of combustion of oil shale refinery by-products in a TP-101 boiler

    NASA Astrophysics Data System (ADS)

    Sidorkin, V. T.; Tugov, A. N.; Vereshchetin, V. A.; Mel'nikov, D. A.

    2015-04-01

    The most cost-efficient method for utilization of the oil shale refinery by-products, viz., the retort gas and the shale gasoline, for power generation is combustion of these products in power-generating oil shale-fired boilers. Calculation studies carried out at the Estonian electric power plant in Narva, an enterprise of EESTI ENERGIA, have shown that recycling of the flue gases in the furnace of a TP-101 boiler enables an increase in the portion of the oil shale refinery by-products burned in the boiler from the current 7% to 40%. Recycling of the flue gases is aimed at maintaining the temperatures in the furnace at a level characteristic of combustion of oil shale and reducing the nitric oxide concentration in the retort gas burners' flame. The degree of the flue gas recycling depends on the percentage of the burnt oil shale refinery by-products in the total heat generation and increases with the increasing percentage. For the threshold value of 40% under the rated conditions, the flue gas recycling accounts for 10%. A complete changeover of the boiler to combustion of only the retort gas in place of the oil shale does not seem to be possible, since this will necessitate major modification to the TP-101 boiler heating surfaces. Considering the obtained results, as a pilot project, one boiler furnace was modified by installing six retort gas burners and a flue gas recycling system.

  6. Biomarkers in Natural Fish Populations Indicate Adverse Biological Effects of Offshore Oil Production

    PubMed Central

    Balk, Lennart; Hylland, Ketil; Hansson, Tomas; Berntssen, Marc H. G.; Beyer, Jonny; Jonsson, Grete; Melbye, Alf; Grung, Merete; Torstensen, Bente E.; Børseth, Jan Fredrik; Skarphedinsdottir, Halldora; Klungsøyr, Jarle

    2011-01-01

    Background Despite the growing awareness of the necessity of a sustainable development, the global economy continues to depend largely on the consumption of non-renewable energy resources. One such energy resource is fossil oil extracted from the seabed at offshore oil platforms. This type of oil production causes continuous environmental pollution from drilling waste, discharge of large amounts of produced water, and accidental spills. Methods and principal findings Samples from natural populations of haddock (Melanogrammus aeglefinus) and Atlantic cod (Gadus morhua) in two North Sea areas with extensive oil production were investigated. Exposure to and uptake of polycyclic aromatic hydrocarbons (PAHs) were demonstrated, and biomarker analyses revealed adverse biological effects, including induction of biotransformation enzymes, oxidative stress, altered fatty acid composition, and genotoxicity. Genotoxicity was reflected by a hepatic DNA adduct pattern typical for exposure to a mixture of PAHs. Control material was collected from a North Sea area without oil production and from remote Icelandic waters. The difference between the two control areas indicates significant background pollution in the North Sea. Conclusion It is most remarkable to obtain biomarker responses in natural fish populations in the open sea that are similar to the biomarker responses in fish from highly polluted areas close to a point source. Risk assessment of various threats to the marine fish populations in the North Sea, such as overfishing, global warming, and eutrophication, should also take into account the ecologically relevant impact of offshore oil production. PMID:21625421

  7. Lubricant oil production: The proper marriage of process and catalyst technologies

    SciTech Connect

    Everett, G.L.; Suchanek, A.

    1996-12-01

    As the industry moves into the next millennium, higher product quality demands to meet the higher performance needs of modern engine technology and rising costs of traditional good quality lube crudes are driving lubricant base oil manufacturers to select hydroprocessing options versus traditional solvent refining techniques. This paper discusses how to properly select the best economic hydroprocessing technology necessary to produce high quality lubricant base oils and waxes. The economic success of such operations depends on the proper combination of process and catalyst technologies that maximizes yields of high quality products with minimum consumption of hydrogen resources and process utilities. This is particular true on the extreme end of the quality spectrum, namely, Very High Viscosity Index (VHVI) base oils and food grade white oils and waxes where there is no room for marginal product quality. Multiplicity of operations is also becoming more important as refiners try to upgrade their facilities with as little capital expense as possible, while at the same time, broaden their high valued product slate to recoup these expenses in the shortest possible payback period. Lyondell Licensing and Criterion Catalyst have put together an effective alliance based on years of development and commercial experience in both the process and catalyst areas to assist lubricant oil manufacturers in meeting these future challenges using as much existing equipment and infrastructure as is practical. Their experience will permit the proper fitting of the chemistry of hydroprocessing to make lubricant base oils to existing or new operations.

  8. Leaf oil body functions as a subcellular factory for the production of a phytoalexin in Arabidopsis.

    PubMed

    Shimada, Takashi L; Takano, Yoshitaka; Shimada, Tomoo; Fujiwara, Masayuki; Fukao, Yoichiro; Mori, Masashi; Okazaki, Yozo; Saito, Kazuki; Sasaki, Ryosuke; Aoki, Koh; Hara-Nishimura, Ikuko

    2014-01-01

    Oil bodies are intracellular structures present in the seed and leaf cells of many land plants. Seed oil bodies are known to function as storage compartments for lipids. However, the physiological function of leaf oil bodies is unknown. Here, we show that leaf oil bodies function as subcellular factories for the production of a stable phytoalexin in response to fungal infection and senescence. Proteomic analysis of oil bodies prepared from Arabidopsis (Arabidopsis thaliana) leaves identified caleosin (CLO3) and α-dioxygenase (α-DOX1). Both CLO3 and α-DOX1 were localized on the surface of oil bodies. Infection with the pathogenic fungus Colletotrichum higginsianum promoted the formation of CLO3- and α-DOX1-positive oil bodies in perilesional areas surrounding the site of infection. α-DOX1 catalyzes the reaction from α-linolenic acid (a major fatty acid component of oil bodies) to an unstable compound, 2-hydroperoxy-octadecatrienoic acid (2-HPOT). Intriguingly, a combination of α-DOX1 and CLO3 produced a stable compound, 2-hydroxy-octadecatrienoic acid (2-HOT), from α-linolenic acid. This suggests that the colocalization of α-DOX1 and CLO3 on oil bodies might prevent the degradation of unstable 2-HPOT by efficiently converting 2-HPOT into the stable compound 2-HOT. We found that 2-HOT had antifungal activity against members of the genus Colletotrichum and that infection with C. higginsianum induced 2-HOT production. These results defined 2-HOT as an Arabidopsis phytoalexin. This study provides, to our knowledge, the first evidence that leaf oil bodies produce a phytoalexin under a pathological condition, which suggests a new mechanism of plant defense. PMID:24214535

  9. Recovery of different waste vegetable oils for biodiesel production: a pilot experience in Bahia State, Brazil.

    PubMed

    Torres, Ednildo Andrade; Cerqueira, Gilberto S; Tiago, M Ferrer; Quintella, Cristina M; Raboni, Massimo; Torretta, Vincenzo; Urbini, Giordano

    2013-12-01

    In Brazil, and mainly in the State of Bahia, crude vegetable oils are widely used in the preparation of food. Street stalls, restaurants and canteens make a great use of palm oil and soybean oil. There is also some use of castor oil, which is widely cultivated in the Sertão Region (within the State of Bahia), and widely applied in industry. This massive use in food preparation leads to a huge amount of waste oil of different types, which needs either to be properly disposed of, or recovered. At the Laboratorio Energia e Gas-LEN (Energy & Gas lab.) of the Universidade Federal da Bahia, a cycle of experiments were carried out to evaluate the recovery of waste oils for biodiesel production. The experiences were carried out on a laboratory scale and, in a semi-industrial pilot plant using waste oils of different qualities. In the transesterification process, applied waste vegetable oils were reacted with methanol with the support of a basic catalyst, such as NaOH or KOH. The conversion rate settled at between 81% and 85% (in weight). The most suitable molar ratio of waste oils to alcohol was 1:6, and the amount of catalyst required was 0.5% (of the weight of the incoming oil), in the case of NaOH, and 1%, in case of KOH. The quality of the biodiesel produced was tested to determine the final product quality. The parameters analyzed were the acid value, kinematic viscosity, monoglycerides, diglycerides, triglycerides, free glycerine, total glycerine, clearness; the conversion yield of the process was also evaluated. PMID:23993759

  10. Oil spill treatment products approval: the UK approach and potential application to the Gulf region.

    PubMed

    Kirby, Mark F; Law, Robin J

    2008-07-01

    The environmental threat from oil spills remains significant across the globe and particularly in regions of high oil production and transport such as the Gulf. The ultimate damage caused can be limited by mitigation actions that responders deploy. The responsible and appropriate use of oil spill treatment products (e.g. dispersants, sorbents etc.) can offer response options that can result in substantial net environmental benefit. However, the approval and choice of what products to use needs careful consideration. The United Kingdom has had in place a statutory approval scheme for oil spill treatment products for 30 years. It is based on measures of efficiency and environmental acceptability. Two toxicity tests form an integral part of the assessment, the Sea test and the Rocky Shore test, and work on the premise that approved products will not make the situation significantly worse when added to spilled oil. This paper outlines the UK approach and how its rationale might be applied to the approval of products specific for the Gulf region. Issues such as species choice, higher temperatures and salinity and regional environmental conditions are considered. PMID:18433797

  11. LIDAR for remote sensing of contaminations on water and earth surfaces taking place during oil-gas production

    NASA Astrophysics Data System (ADS)

    Pashayev, A.; Tagiyev, B.; Allahverdiyev, K.; Musayev, A.; Sadikhov, I.

    2015-12-01

    Remote sensing of contaminations on water and earth surfaces (oil spills, films) taking place during oil-gas extraction is an interesting and actual problem. This problem may be solved by using different methods of optical spectroscopy, including: •Raman scattering; •light induced breakdown spectroscopy (LIBS); •fluorescence spectroscopy. Fluorescence Light Detection and Ranging (LIDAR) LIDARs are successfully used for remote sensing of chemical and biological substances at atmosphere. A new laser induced fluorescence (LIF) KA-14 LIDAR system for detecting of oil spills on the sea surface was employed at the National Aviation Academy of Azerbaijan. LIDAR's parameters are as follows: •laser CFR 200- type QUANTEL, λ = 355 nm, beam Ø = 5.35 mm, f = 20 Hz, pulse duration τ = 7 ns, pulse power 60 mJ; •diameter of Newtonian- type telescope is 200 mm; •collimator expansion of the laser beam diameter- not less than 3; •angle range of telescope measurements relative to horizon: from -20 to +20 degree; •spectral range of measurements: from 380 to 750 nm, number of spectral channels- 32; •maximum range of measurements- not less than 250 m. This LIDAR is the first performing these kind of research not only on the Azerbaijan beach of Caspian sea, but also on the earth places of Absheron peninsula, where oil-gas production takes place. We hope that the performance of LIDAR will have an International recognition and will make noticeable input on the International Research of Caspian sea surfaces.

  12. Biolistic-mediated production of transgenic oil palm.

    PubMed

    Parveez, Ghulam Kadir Ahmad; Bahariah, Bohari

    2012-01-01

    The effectiveness of mannose (using phosphomannose isomerase [pmi] gene) as a positive selection agent to preferably allow the growth of transformed oil palm embryogenic calli was successfully evaluated. Using the above selection agent in combination with the previously optimized physical and biological parameters and the best constitutive promoter, oil palm embryogenic calli were transformed with pmi gene for producing transgenic plants. Bombarded embryogenic calli were exposed to embryogenic calli medium containing 30:0 g/L mannose to sucrose 3 weeks postbombardment. Selectively, proliferating embryogenic calli started to emerge around 6 months on the above selection medium. The proliferated embryogenic calli were individually isolated once they reached a specific size and regenerated to produce complete plantlets. The complete regenerated plantlets were evaluated for the presence of transgenes by PCR and Southern analyses. PMID:22351007

  13. New applications for enzymes in oil and gas production

    SciTech Connect

    Harris, R.E.; McKay, I.D.

    1999-04-01

    Enzymes have been previously used as gel breakers. In these applications, the enzyme removes a chemical which is no longer required, such as biopolymers in filter cakes after drilling or in frac gels after the frac has occurred. Enzymes are now used to produce useful oilfield chemicals in-situ for acidizing, sand consolidation and water shutoff applications. Enzyme-based processes for generating other useful oil-field chemicals, including minerals, gels and resins, are being developed, and these applications are discussed.

  14. Enzymatic pretreatment of low-grade oils for biodiesel production.

    PubMed

    Nordblad, Mathias; Pedersen, Anders K; Rancke-Madsen, Anders; Woodley, John M

    2016-04-01

    The alkaline process for making biodiesel (fatty acid methyl esters, or FAME) is highly efficient at the transesterification of glycerides. However, its performance is poor when it comes to using oil that contain significant amounts of free fatty acids (FFA). The traditional approach to such feedstocks is to employ acid catalysis, which is slow and requires a large excess of methanol, or to evaporate FFA and convert that in a separate process. An attractive option would be to convert the FFA in oil feedstocks to FAME, before introducing it into the alkaline process. The high selectivity of enzyme catalysis makes it a suitable basis for such a pretreatment process. In this work, we present a characterization of the pretreatment of high-FFA rapeseed oil using immobilized Candida antarctica lipase B (Novozym 435), focused on the impact of initial FFA and methanol concentration. Based on experimental results, we have identified limitations for the process in terms of FFA concentration in the feedstock and make suggestions for process operation. It was found that, using 5% catalyst and 4% methanol at 35°C, the FFA concentration could be reduced to 0.5% within an hour for feedstock containing up to 15% FFA. Further, the reaction was observed to be under kinetic control, in that the biocatalyst converts FFA (and FAME) at a much higher rate than glyceride substrates. There is thus, both a minimum and a maximum reaction time for the process to achieve the desired concentration of FFA. Finally, an assessment of process stability in a continuous packed bed system indicates that as much as 15 m(3) oil could potentially be pretreated by 1 kg of biocatalyst at the given process conditions. PMID:26442879

  15. Plastic plugbacks can extend oil and gas well productive life

    SciTech Connect

    Rice, R.T. )

    1991-11-01

    A high rate of successful water reduction has been documented in 21 plastic plugbacks performed on gravel-packed oil and gas well completions in the Gulf of Mexico. This electric wireline plugback method is unique because it is performed inside gravel pack assemblies, utilizing plastic instead of cement. This article presents a case study of field results from 21 jobs performed by Tenneco/Chevron.

  16. Peak Oil Production: How to Evaluate Estimates of Depleting Natural Resources?

    NASA Astrophysics Data System (ADS)

    Craver, Bruce

    2005-04-01

    We review recent data for world oil production along with forecasts that world production is at or near a maximum. Many books and articles about ``peak oil'' have appeared in the non-peer reviewed literature in the past few years; we concentrate on information available from the petroleum industry, governmental agencies and the peer-reviewed literature. A summary of possible alternatives to petroleum will be given, with emphasis given to arguments based on the concept of energy return on energy invested (EROEI). We conclude that there is at least a high probability that ``peak oil'' is close at hand, and if that is the case, the consequences will likely constitute one of the greatest challenges for the current generation of students. The topic of peak oil is one that fits naturally into classroom discussions of energy in introductory physics courses for non-majors.

  17. Tuning single-cell oil production in Ashbya gossypii by engineering the elongation and desaturation systems.

    PubMed

    Ledesma-Amaro, Rodrigo; Santos, María-Angeles; Jiménez, Alberto; Revuelta, José Luis

    2014-09-01

    Microbial oils represent a sustainable alternative to vegetable oils and animal fats as feedstock for both the chemical and biofuel industries. The applications of microbial oils depend on their fatty acid composition, which is defined by the relative amount of each fatty acid, also considering the length and unsaturations of the acyl chain. These two properties are determined by elongases and desaturases. In the present study, we characterized the elongase and desaturase systems in the filamentous fungus Ashbya gossypii, which is able to accumulate high amounts of lipids. Additionally, both the elongation and desaturation systems were engineered in order to broaden the potential applications of A. gossypii oils. Finally, the properties of the strains engineered for biodiesel production were analyzed, with the observation that A. gossypii is a good candidate for the microbial production of renewable biofuels. PMID:24668265

  18. Economics of on-farm production and use of vegetable oils for fuel

    SciTech Connect

    McIntosh, C.S.; Withers, R.V.; Smith, S.M.

    1982-01-01

    The technology of oilseed processing, on a small scale, is much simpler than that for ethanol production. This, coupled with the fact that most energy intensive farm operations use diesel powered equipment, has created substantial interest in vegetable oils as an alternative source of liquid fuel for agriculture. The purpose of this study was to estimate the impact on gross margins resulting from vegetable oil production and utilization in two case study areas, Latah and Power Counties, in Iadho. The results indicate that winter rape oil became a feasible alternative to diesel when the price of diesel reached $0.84 per liter in the Latah County model. A diesel price of $0.85 per liter was required in the Power County model before it became feasible to produce sunflower oil for fuel. 5 tables.

  19. Significance of high-wax oil variability to Pacific Rim exploration and production

    SciTech Connect

    Carlson, R.M.K.; Jacobson, S.R.

    1996-12-31

    High-Wax oils are a class of paraffinic crudes that occur widely in Pacific Rim petroleum systems. New analytical technologies, particularly High Temperature Gas Chromatography (HTGC) show unexpected variations in the molecular weight ranges and concentrations of paraffin waxes within this class of crudes. These variations are source and maturity-related, providing paleoenvironmental and generative information useful to exploration. Paleoenvironmental factors revealed by high-wax oil HTGC source signatures can also help interpret the potential for nearby reservoirs. Furthermore, variations in wax compositions affect flow and organic scale-forming properties that impact the production economics of these oils. Lacustrine-sourced high-wax oils contain broad distributions of paraffin waxes ranging from C{sub 20} to C{sub 60} or higher. Various algae appear to be the source of higher molecular weight waxes in these oils. Paleoenvironmental factors, such as water salinities and paleoclimate, affect wax compositions of resulting lacustrine high-wax oils. Other terrestrial-sourced oils generated by paralic or nearshore marine source rocks show high concentrations of C{sub 25} to C{sub 35} waxes, but much lower distributions of higher molecular weight waxes. These high-wax oils appear to. contain waxes derived principally from terrestrial, higher plant materials. Results for high-wax petroleum systems in Australia, Indonesia, the Philippines and China illustrate these conclusions with examples ranging in age from Carboniferous-Permian to late Tertiary.

  20. Significance of high-wax oil variability to Pacific Rim exploration and production

    SciTech Connect

    Carlson, R.M.K. ); Jacobson, S.R. )

    1996-01-01

    High-Wax oils are a class of paraffinic crudes that occur widely in Pacific Rim petroleum systems. New analytical technologies, particularly High Temperature Gas Chromatography (HTGC) show unexpected variations in the molecular weight ranges and concentrations of paraffin waxes within this class of crudes. These variations are source and maturity-related, providing paleoenvironmental and generative information useful to exploration. Paleoenvironmental factors revealed by high-wax oil HTGC source signatures can also help interpret the potential for nearby reservoirs. Furthermore, variations in wax compositions affect flow and organic scale-forming properties that impact the production economics of these oils. Lacustrine-sourced high-wax oils contain broad distributions of paraffin waxes ranging from C[sub 20] to C[sub 60] or higher. Various algae appear to be the source of higher molecular weight waxes in these oils. Paleoenvironmental factors, such as water salinities and paleoclimate, affect wax compositions of resulting lacustrine high-wax oils. Other terrestrial-sourced oils generated by paralic or nearshore marine source rocks show high concentrations of C[sub 25] to C[sub 35] waxes, but much lower distributions of higher molecular weight waxes. These high-wax oils appear to. contain waxes derived principally from terrestrial, higher plant materials. Results for high-wax petroleum systems in Australia, Indonesia, the Philippines and China illustrate these conclusions with examples ranging in age from Carboniferous-Permian to late Tertiary.

  1. Insecticidal Activity of the Essential Oils from Different Plants Against Three Stored-Product Insects

    PubMed Central

    Ayvaz, Abdurrahman; Sagdic, Osman; Karaborklu, Salih; Ozturk, Ismet

    2010-01-01

    This study was conducted to determine the insecticidal activity of essential oils from oregano, Origanum onites L. (Lamiales: Lamiaceae), savory, Satureja thymbra L. (Lamiales: Lamiaceae), and myrtle, Myrtus communis L. (Rosales: Myrtaceae) against three stored-product insects. Essential oils from three species of plants were obtained by Clevenger-type water distillation. The major compounds in these essential oils were identified using gas chromatography-mass spectrometry and their insecticidal activity was tested against adults of the Mediterranean flour moth Ephestia kuehniella Zeller (Lepidoptera: Pyralidae), the Indian meal moth Plodia interpunctella Hübner (Lepidoptera: Pyralidae) and the bean weevil Acanthoscelides obtectus Say (Coleoptera: Bruchidae). While the major compound found in oregano and savory was carvacrol, the main constituent of the myrtle was linalool. Among the tested insects, A. obtectus was the most tolerant species against the essential oils. However, the insecticidal activity of the myrtle oil was more pronounced than other oils tested against A. obtectus adults. The essential oils of oregano and savory were highly effective against P. interpunctella and E. kuehniella, with 100% mortality obtained after 24 h at 9 and 25 µl/l air for P. interpunctella and E. kuehniella, respectively. LC50 and LC99 values of each essential oil were estimated for each insect species. PMID:20578885

  2. Insecticidal activity of the essential oils from different plants against three stored-product insects.

    PubMed

    Ayvaz, Abdurrahman; Sagdic, Osman; Karaborklu, Salih; Ozturk, Ismet

    2010-01-01

    This study was conducted to determine the insecticidal activity of essential oils from oregano, Origanum onites L. (Lamiales: Lamiaceae), savory, Satureja thymbra L. (Lamiales: Lamiaceae), and myrtle, Myrtus communis L. (Rosales: Myrtaceae) against three stored-product insects. Essential oils from three species of plants were obtained by Clevenger-type water distillation. The major compounds in these essential oils were identified using gas chromatography-mass spectrometry and their insecticidal activity was tested against adults of the Mediterranean flour moth Ephestia kuehniella Zeller (Lepidoptera: Pyralidae), the Indian meal moth Plodia interpunctella Hübner (Lepidoptera: Pyralidae) and the bean weevil Acanthoscelides obtectus Say (Coleoptera: Bruchidae). While the major compound found in oregano and savory was carvacrol, the main constituent of the myrtle was linalool. Among the tested insects, A. obtectus was the most tolerant species against the essential oils. However, the insecticidal activity of the myrtle oil was more pronounced than other oils tested against A. obtectus adults. The essential oils of oregano and savory were highly effective against P. interpunctella and E. kuehniella, with 100% mortality obtained after 24 h at 9 and 25 microl/l air for P. interpunctella and E. kuehniella, respectively. LC(50) and LC(99) values of each essential oil were estimated for each insect species. PMID:20578885

  3. A droplet microfluidics platform for rapid microalgal growth and oil production analysis.

    PubMed

    Kim, Hyun Soo; Guzman, Adrian R; Thapa, Hem R; Devarenne, Timothy P; Han, Arum

    2016-08-01

    Microalgae have emerged as a promising source for producing future renewable biofuels. Developing better microalgal strains with faster growth and higher oil production rates is one of the major routes towards economically viable microalgal biofuel production. In this work, we present a droplet microfluidics-based microalgae analysis platform capable of measuring growth and oil content of various microalgal strains with single-cell resolution in a high-throughput manner. The platform allows for encapsulating a single microalgal cell into a water-in-oil emulsion droplet and tracking the growth and division of the encapsulated cell over time, followed by on-chip oil quantification. The key feature of the developed platform is its capability to fluorescently stain microalgae within microdroplets for oil content quantification. The performance of the developed platform was characterized using the unicellular microalga Chlamydomonas reinhardtii and the colonial microalga Botryococcus braunii. The application of the platform in quantifying growth and oil accumulation was successfully confirmed using C. reinhardtii under different culture conditions, namely nitrogen-replete and nitrogen-limited conditions. These results demonstrate the capability of this platform as a rapid screening tool that can be applied to a wide range of microalgal strains for analyzing growth and oil accumulation characteristics relevant to biofuel strain selection and development. Biotechnol. Bioeng. 2016;113: 1691-1701. © 2016 Wiley Periodicals, Inc. PMID:26724784

  4. Spectral conversion of light for enhanced microalgae growth rates and photosynthetic pigment production.

    PubMed

    Mohsenpour, Seyedeh Fatemeh; Richards, Bryce; Willoughby, Nik

    2012-12-01

    The effect of light conditions on the growth of green algae Chlorella vulgaris and cyanobacteria Gloeothece membranacea was investigated by filtering different wavelengths of visible light and comparing against a model daylight source as a control. Luminescent acrylic sheets containing violet, green, orange or red dyes illuminated by a solar simulator produced the desired wavelengths of light for this study. From the experimental results the highest specific growth rate for C. vulgaris was achieved using the orange range whereas violet light promoted the growth of G. membranacea. Red light exhibited the least efficiency in conversion of light energy into biomass in both strains of microalgae. Photosynthetic pigment formation was examined and maximum chlorophyll-a production in C. vulgaris was obtained by red light illumination. Green light yielded the best chlorophyll-a production in G. membranacea. The proposed illumination strategy offers improved microalgae growth without resorting to artificial light sources, reducing energy use and costs of cultivation. PMID:23023239

  5. Advantages of diffuse light for horticultural production and perspectives for further research

    PubMed Central

    Li, Tao; Yang, Qichang

    2015-01-01

    Plants use diffuse light more efficiently than direct light, which is well established due to diffuse light penetrates deeper into the canopy and photosynthetic rate of a single leaf shows a non-linear response to the light flux density. Diffuse light also results in a more even horizontal and temporal light distribution in the canopy, which plays substantial role for crop photosynthesis enhancement as well as production improvement. Here we show some of the recent findings about the effect of diffuse light on light distribution over the canopy and its direct and indirect effects on crop photosynthesis and plant growth, and suggest some perspectives for further research which could strengthen the scientific understanding of diffuse light modulate plant processes and its application in horticultural production. PMID:26388890

  6. Castor oil overdose

    MedlinePlus

    Castor oil comes from the seeds of the castor oil plant. It can be found in these products: Castor oil Alphamul Emulsoil Fleet Flavored Castor Oil Laxopol Unisol Other products may also contain castor oil.

  7. Economic assessment of environmental impact in the course of oil field development and production

    NASA Astrophysics Data System (ADS)

    Tsibulnikova, M. R.; Kupriyanova, O. S.; Strelnikova, A. B.

    2015-11-01

    The article considers the variety of impacts that oil exploration and production operations have on the environment at different stages of the process. To provide accurate economic assessment, an oil field development project was designed, with various development options. These options being analyzed, the strategy with the minimal environmental impact was identified. This has allowed preparation of a guideline on how to prevent deterioration of the environment and to reduce the negative environmental impact

  8. 15 CFR 754.3 - Petroleum products not including crude oil.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 15 Commerce and Foreign Trade 2 2013-01-01 2013-01-01 false Petroleum products not including crude... (Continued) BUREAU OF INDUSTRY AND SECURITY, DEPARTMENT OF COMMERCE EXPORT ADMINISTRATION REGULATIONS SHORT SUPPLY CONTROLS § 754.3 Petroleum products not including crude oil. (a) License requirement. As...

  9. 15 CFR 754.3 - Petroleum products not including crude oil.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 15 Commerce and Foreign Trade 2 2010-01-01 2010-01-01 false Petroleum products not including crude... (Continued) BUREAU OF INDUSTRY AND SECURITY, DEPARTMENT OF COMMERCE EXPORT ADMINISTRATION REGULATIONS SHORT SUPPLY CONTROLS § 754.3 Petroleum products not including crude oil. (a) License requirement. As...

  10. 15 CFR 754.3 - Petroleum products not including crude oil.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 15 Commerce and Foreign Trade 2 2012-01-01 2012-01-01 false Petroleum products not including crude... (Continued) BUREAU OF INDUSTRY AND SECURITY, DEPARTMENT OF COMMERCE EXPORT ADMINISTRATION REGULATIONS SHORT SUPPLY CONTROLS § 754.3 Petroleum products not including crude oil. (a) License requirement. As...

  11. 15 CFR 754.3 - Petroleum products not including crude oil.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 15 Commerce and Foreign Trade 2 2014-01-01 2014-01-01 false Petroleum products not including crude... (Continued) BUREAU OF INDUSTRY AND SECURITY, DEPARTMENT OF COMMERCE EXPORT ADMINISTRATION REGULATIONS SHORT SUPPLY CONTROLS § 754.3 Petroleum products not including crude oil. (a) License requirement. As...

  12. Fluid and Rock Property Controls On Production And Seismic Monitoring Alaska Heavy Oils

    SciTech Connect

    Liberatore, Matthew; Herring, Andy; Prasad, Manika; Dorgan, John; Batzle, Mike

    2012-10-30

    The goal of this project is to improve recovery of Alaskan North Slope (ANS) heavy oil resources in the Ugnu formation by improving our understanding of the formation's vertical and lateral heterogeneities via core evaluation, evaluating possible recovery processes, and employing geophysical monitoring to assess production and modify production operations.

  13. Western states enhanced oil shale recovery program: Shale oil production facilities conceptual design studies report

    SciTech Connect

    Not Available

    1989-08-01

    This report analyzes the economics of producing syncrude from oil shale combining underground and surface processing using Occidental's Modified-In-Situ (MIS) technology and Lawrence Livermore National Laboratory's (LLNL) Hot Recycled Solids (HRS) retort. These retorts form the basic technology employed for oil extraction from oil shale in this study. Results are presented for both Commercial and Pre-commercial programs. Also analyzed are Pre-commercialization cost of Demonstration and Pilot programs which will confirm the HRS and MIS concepts and their mechanical designs. These programs will provide experience with the circulating Fluidized Bed Combustor (CFBC), the MIS retort, the HRS retort and establish environmental control parameters. Four cases are considered: commercial size plant, demonstration size plant, demonstration size plant minimum CFBC, and a pilot size plant. Budget cost estimates and schedules are determined. Process flow schemes and basic heat and material balances are determined for the HRS system. Results consist of summaries of major equipment sizes, capital cost estimates, operating cost estimates and economic analyses. 35 figs., 35 tabs.

  14. Effect of photosensitizer and hydrogen peroxide on desulfurization of light oil by photochemical reaction and liquid-liquid extraction

    SciTech Connect

    Hirai, Takayuki; Shiraishi, Yasuhiro; Ogawa, Ken; Komasawa, Isao

    1997-03-01

    A desulfurization process for dibenzothiophene (DBT) by a combination of photochemical reaction and liquid-liquid extraction has been investigated. The DBT dissolved in tetradecane was photodecomposed by the use of a high-pressure mercury lamp and removed into the water phase at conditions of room temperature and atmospheric pressure. The addition of benzophenone (BZP), a triplet photosensitizer, enhanced the removal of DBT from tetradecane. This reaction, however, hardly proceeded in the presence of naphthalene (NP), probably because of triplet energy transfer from photoexcited DBT or BZP to ground-state NP. The addition of hydrogen peroxide enhanced the desulfurization of commercial light oil as well as the removal of DBT from tetradecane, since H{sub 2}O{sub 2} acted as a weak oxidizing agent for photoexcited DBT and interrupted the energy transfer from excited DBT to NP to some extent. In the case using a 30% H{sub 2}O{sub 2} solution, the desulfurization yield of commercial light oil was 75% following 24 h of photoirradiation and the sulfur content in the light oil was reduced from 0.2 wt % to less than 0.05 wt %.

  15. Simple techniques to increase the production yield and enhance the quality of organic rice bran oils.

    PubMed

    Srikaeo, Khongsak; Pradit, Maythawinee

    2011-01-01

    This study develops simple techniques for increasing production yield and refining of crude RBO (CRBO). It was found that pre-heating of rice bran by hot air oven to reach 60°C before being extracted by screw press machine increased the yield from 4.8 to 8.3%w/w. This paper suggested three simple steps for refining of organic CRBO: (1) filtering using filter papers (2) sedimentation by adding 4%w/v fuller's earth and (3) bleaching by running through a packed column of activated carbon. These steps significantly enhanced the qualities of RBO when compared to CRBO before treatment. It was found that the lightness of oil as indicated by color value (L*) increased from 22.8 to 28.7, gum and wax decreased from 3.6 to 1.3%w/w. However, the simple refining method had no effect on peroxide value and free fatty acid content. Moreover, it slightly induced the loss of oryzanol content from 2.8 to 2.2%w/w. PMID:21178310

  16. Hypertriton and light nuclei production at Lambda-production subthreshold energy in heavy-ion collisions

    SciTech Connect

    Zhang, S.; Zu, Z.; Chen, J.H., Ma, Y.G., Cai, X-Z, Ma, G.L., Zhong, C.

    2011-08-01

    High-energy heavy-ion collisions produce abundant hyperons and nucleons. A dynamical coalescence model coupled with the ART model is employed to study the production probabilities of light clusters, deuteron (d), triton (t), helion ({sup 3}He), and hypertriton ({sub {Lambda}}{sup 3}H) at subthreshold energy of Aproduction ({approx} 1 GeV per nucleon). We study the dependence on the reaction system size of the coalescence penalty factor per additional nucleon and entropy per nucleon. The Strangeness Population Factor (S{sub 3} = {sup 3}{sub {Lambda}}H/({sup 3}He x {Lambda}/p)) shows an extra suppression of hypertriton comparing to light clusters of the same mass number. This model predicts a hypertriton production cross-section of a few {mu}b in {sup 36}Ar+{sup 36}Ar, {sup 40}Ca+{sup 40}Ca and {sup 56}Ni+{sup 56}Ni in 1 A GeV reactions. The production rate is as high as a few hypertritons per million collisions, which shows that the fixed-target heavy-ion collisions at CSR (Lanzhou/China) at {Lambda} subthreshold energy are suitable for breaking new ground in hypernuclear physics.

  17. Hypertriton and light nuclei production at Λ-production subthreshold energy in heavy-ion collisions

    NASA Astrophysics Data System (ADS)

    Zhang, Song; Chen, Jin-Hui; Ma, Yu-Gang; Xu, Zhang-Bu; Cai, Xiang-Zhou; Ma, Guo-Liang; Zhong, Chen

    2011-08-01

    High-energy heavy-ion collisions produce abundant hyperons and nucleons. A dynamical coalescence model coupled with the ART model is employed to study the production probabilities of light clusters, deuteron (d), triton (t), helion (3He), and hypertriton (3ΛH) at subthreshold energy of Aproduction (≈ 1 GeV per nucleon). We study the dependence on the reaction system size of the coalescence penalty factor per additional nucleon and entropy per nucleon. The Strangeness Population Factor shows an extra suppression of hypertriton comparing to light clusters of the same mass number. This model predicts a hypertriton production cross-section of a few μb in 36Ar+36Ar, 40Ca+40Ca and 56Ni+56Ni in 1 A GeV reactions. The production rate is as high as a few hypertritons per million collisions, which shows that the fixed-target heavy-ion collisions at CSR (Lanzhou/China) at Λ subthreshold energy are suitable for breaking new ground in hypernuclear physics.

  18. Tolerance and accumulation of lead in Vetiveria zizanioides and its effect on oil production.

    PubMed

    Rotkittikhun, P; Kruatrachue, M; Pokethitiyook, P; Baker, A J M

    2010-05-01

    Experiments were conducted to evaluate lead tolerance and accumulation in vetiver grass Vetiveria zizanioides (L.), grown in hydroponics and a pot study and to examine the effect of lead on vetiver oil production. Elevated concentrations of lead decreased the length of shoots and roots of plants. However, vetiver grown in highly contaminated soils showed no apparent phytotoxicity symptoms. Lead concentrations in the shoots and roots of vetiver plants grown in hydroponics were up to 144 and 19530 mg kg(-1) and those grown in soil were 38 and 629 mg kg(-1), respectively. Lead had an effect on vetiver oil production and composition by stimulating oil yield and the number of its constituents. Oil yield ranged from 0.4-1.3%; the highest yields were found in plants grown in nutrient solution with 100 mg Pb l(-1) for 5 weeks (1.29%) and 7 weeks (1.22%). The number of total constituents of vetiver oil also varied between 47-143 compounds when lead was presentin the growth medium. The highest number (143) was found in plants grown in soil spiked with 1000 mg Pb kg(-1). The predominant compound was khusimol (10.7-18.1%) followed by (E)-isovalencenol (10.3-15.6%). Our results indicated that lead could increase the oil production of vetiver. PMID:21047007

  19. Microwave assisted esterification of acidified oil from waste cooking oil by CERP/PES catalytic membrane for biodiesel production.

    PubMed

    Zhang, Honglei; Ding, Jincheng; Zhao, Zengdian

    2012-11-01

    The traditional heating and microwave assisted method for biodiesel production using cation ion-exchange resin particles (CERP)/PES catalytic membrane were comparatively studied to achieve economic and effective method for utilization of free fatty acids (FFAs) from waste cooking oil (WCO). The optimal esterification conditions of the two methods were investigated and the experimental results showed that microwave irradiation exhibited a remarkable enhanced effect for esterification compared with that of traditional heating method. The FFAs conversion of microwave assisted esterification reached 97.4% under the optimal conditions of reaction temperature 60°C, methanol/acidified oil mass ratio 2.0:1, catalytic membrane (annealed at 120°C) loading 3g, microwave power 360W and reaction time 90min. The study results showed that it is a fast, easy and green way to produce biodiesel applying microwave irradiation. PMID:22940301

  20. The Peaking of World Oil Production: The Problem and Its Mitigation

    NASA Astrophysics Data System (ADS)

    Hirsch, Robert L.

    2006-11-01

    The peaking of world conventional oil production will be unlike any energy problem yet faced by modern industrial society. Without timely mitigation, the economic, social, and political costs will be dire and unprecedented. Viable mitigation options exist on both the supply and demand sides, but to have substantial impact, they must be initiated more than a decade in advance of peaking, because the scale of liquid fuels mitigation is inherently extremely large. When world oil peaking will occur is not known with certainty. A fundamental problem in predicting oil peaking is the poor quality of, and political biases in, world oil reserves data. Some experts believe peaking may occur soon, while some think later, but not beyond the time required for effective mitigation. The problems associated with world oil production peaking will not be temporary, and past ``energy crisis'' experience will provide relatively little guidance. Oil peaking will create a severe liquid fuels problem primarily for the transportation sector, not an ``energy crisis'' in the usual sense that term has been used. While greater end-use efficiency is essential, increased efficiency alone will be neither sufficient nor timely enough to solve the problem. Production of large amounts of substitute liquid fuels will be required. A number of commercial or near-commercial substitute fuel production technologies are currently available for deployment, so the production of vast amounts of substitute liquid fuels is feasible with existing technology. Intervention by governments will be required, because the economic and social implications of oil peaking would otherwise be chaotic. The experiences of the 1970s and 1980s offer important guides as to government actions that are desirable and those that are undesirable, but the process will not be easy.

  1. CO2 Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Annual report, January 1, 1995--December 31, 1995

    SciTech Connect

    Wehner, S.C.; Boomer, R.J.; Cole, R.; Preiditus, J.; Vogt, J.

    1996-09-01

    The application of cyclic CO{sub 2}, often referred to as the CO{sub 2} Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO{sub 2} H-n-P process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital intensive miscible projects. Texaco Exploration & Production Inc. and the U.S. Department of Energy have teamed up in an attempt to develop the CO{sub 2} Huff-n-Puff process in the Grayburg/San Andres formation; a light oil, shallow shelf carbonate reservoir within the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected site for this demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico.

  2. FT-Raman and photoacoustic infrared spectroscopy of syncrude light gas oil distillation fractions.

    PubMed

    Michaelian, Kirk H; Hall, Robert H; Bulmer, J Tim

    2003-11-01

    FT-Raman and photoacoustic (PA) infrared spectra of 12 distillation fractions derived from Syncrude light gas oil (LGO), which has a boiling range from 195 to 343 degrees C, were analyzed in detail in this study. In the fingerprint region (200-1800 cm(-1)) most of the information is obtained from the FT-Raman spectra, which display 36 bands that are assignable to various alkyl or aryl functional groups. Monocyclic, bicyclic and tricyclic aromatics in the 12 fractions were also characterized using Raman bands in this region. The corresponding section of the infrared spectra is much simpler, displaying a relatively small number of bands due to either aromatic or aliphatic CH(n) (n=1, 2 or 3) groups. The Cz.sbnd;H stretching region in both FT-Raman and PA infrared spectra of the LGO distillation fractions was curve-fitted according to procedures established in previous investigations of Syncrude samples with various boiling ranges. The PA spectra of the LGO fractions were also analyzed using an accepted integration strategy that requires no a priori assumptions with regard to the number of constituent bands or their shapes. The curve-fitting results show that the frequencies of the 11 Raman and eight infrared bands used to model the aliphatic ( approximately 2775-3000 cm(-1)) parts of the respective spectra decrease systematically as the median boiling points of the LGO fractions increase. These band positions are consistent with those determined in earlier studies of other distillation fractions. Both curve fitting and integration show that the abundance of CH(2) groups increases at the expense of CH(3) groups as the boiling points of the fractions increase within the LGO region. PMID:14583274

  3. Cell death and cytokine production induced by autoimmunogenic hydrocarbon oils.

    PubMed

    Herman, Sonja; Kny, Angelika; Schorn, Christine; Pfatschbacher, Jürgen; Niederreiter, Birgit; Herrmann, Martin; Holmdahl, Rikard; Steiner, Günter; Hoffmann, Markus H

    2012-12-01

    Hydrocarbon oils such as pristane or hexadecane induce arthritis and lupus in rodents sharing clinical and pathological features with the human diseases rheumatoid arthritis and systemic lupus erythematosus, respectively. In pristane-induced lupus in the mouse induction of apoptosis and augmentation of type-I Interferon signalling by pristane have been suggested to contribute to pathology, whereas in pristane-induced arthritis (PIA) in the rat the pathological mechanisms are still elusive. Here we show that pristane induces cell death in rat and human cells. Increased numbers of apoptotic cells were found in draining lymph nodes of pristane-injected rats and increased percentages of apoptotic and necrotic cells were observed in peripheral blood. In addition, neutrophil extracellular trap formation was triggered by pristane and hexadecane in neutrophils. Because levels of interleukin (IL)-1β were elevated in sera of pristane-injected rats, with levels mirroring the course of PIA, we examined the effect of pristane at single cell level in vitro, using rat splenocytes and the human monocytic cell line THP-1. Pristane and other hydrocarbon oils induced IL-1β secretion in THP-1 cells as well as in rat splenocytes. The potassium channel inhibitor glibenclamide partly inhibited IL-1β induction, suggesting involvement of the inflammasome. Elevated levels of IL-1α were also found in supernatants of cells treated with pristane and hexadecane. In conclusion, autoimmunogenic hydrocarbon oils induce various forms of cell death in rat and human cells. The higher serum IL-1β levels in pristane-injected animals might be caused by both inflammasome-dependent and -independent mechanisms, such as passive release from dying-cells and probably extracellular maturation of pro-IL-1β. PMID:22917079

  4. Short-Term Energy Outlook Supplement: Key drivers for EIA's short-term U.S. crude oil production outlook

    EIA Publications

    2013-01-01

    Crude oil production increased by 790,000 barrels per day (bbl/d) between 2011 and 2012, the largest increase in annual output since the beginning of U.S. commercial crude oil production in 1859. The U.S. Energy Information Administration (EIA) expects U.S. crude oil production to continue rising over the next two years represented in the Short-Term Energy Outlook (STEO).

  5. A screening method of oil-soluble synthetic dyes in chilli products based on multi-wavelength chromatographic fingerprints comparison.

    PubMed

    Zhu, Yonghong; Wu, Yanlei; Zhou, Chunjie; Zhao, Bo; Yun, Wen; Huang, Siyu; Tao, Peng; Tu, Dawei; Chen, Shiqi

    2016-02-01

    A multi-wavelength HPLC fingerprint comparison method was proposed for the screening of oil-soluble synthetic dyes in chilli products. The screening was based on the fingerprint differences of normal unadulterated chilli sample with tested chilli samples. The samples were extracted with acetone and fingerprinted by HPLC under four visible light wavelengths (450 nm, 490 nm, 520 nm, and 620 nm). It was found that the fingerprints of different chilli product samples had a relatively fixed number of peaks and stable retention time. When 16 kinds of known synthetic dyes were used as model analytes to assess the screening efficiency, 14 of them could be screened using fingerprint comparison method, with LOD of 0.40-2.41 mg/kg. The new screening method was simple and had the possibility of finding existence of the adulterated dyes which could not be identified using known standard analytes as control. PMID:26304371

  6. High severity pyrolysis of shale and petroleum gas oil mixtures

    SciTech Connect

    Leftin, H.P.; Newsome, D.S.

    1986-01-01

    Light gas oil and heavy gas oil from Paraho shale oil and their mixtures with a petroleum light gas oil were pyrolyzed in the presence of steam at 880-900/sup 0/C and contact times between 60 and 90 ms in a nonisothermal bench-scale pyrolysis reactor. Blending of petroleum LGO into the shale oil feeds provided product yields that were the weighted linear combination of the yields of the individual components of the blends. Partial denitrogenation and a pronounced decrease in the rate of coke deposition on the reactor walls were observed when petroleum gas oil was blended with the shale gas oils.

  7. Lighting.

    SciTech Connect

    United States. Bonneville Power Administration.

    1992-09-01

    Since lighting accounts for about one-third of the energy used in commercial buildings, there is opportunity to conserve. There are two ways to reduce lighting energy use: modify lighting systems so that they used less electricity and/or reduce the number of hours the lights are used. This booklet presents a number of ways to do both. Topics covered include: reassessing lighting levels, reducing lighting levels, increasing bulb & fixture efficiency, using controls to regulate lighting, and taking advantage of daylight.

  8. Levels of Vitamin E Decreases and Retinol Increases in Oil Extracts from Aged Alaska Pollock (Theragra chalcogramma) By-Products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The Alaska Pollock constitutes one of the largest commercial fish catch and generation of by-products in the world. Crude oil is one of the products generated from the by-products; however, quality loss is expected if time delay or temperature abuse is encountered before oil extraction. The objectiv...

  9. Characterization and thermal conversion of charcoal derived from fluidized-bed fast pyrolysis oil production of switchgrass

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The char coproduct of pyrolysis oil production can have many potential uses. Applications including soil amendment, use as combustion fuel, or gasifier feedstock have been proposed but not extensively studied. In this work the charcoal produced from making pyrolysis oil (bio-oil) from switchgrass in...

  10. 40 CFR 721.10189 - Fatty acids, tall-oil, reaction products with (butoxymethyl) oxirane formaldehyde-phenol polymer...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Fatty acids, tall-oil, reaction... Substances § 721.10189 Fatty acids, tall-oil, reaction products with (butoxymethyl) oxirane formaldehyde... to reporting. (1) The chemical substance identified generically as fatty acids, tall-oil,...

  11. 40 CFR 721.10189 - Fatty acids, tall-oil, reaction products with (butoxymethyl) oxirane formaldehyde-phenol polymer...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Fatty acids, tall-oil, reaction... Substances § 721.10189 Fatty acids, tall-oil, reaction products with (butoxymethyl) oxirane formaldehyde... to reporting. (1) The chemical substance identified generically as fatty acids, tall-oil,...

  12. 40 CFR 721.10189 - Fatty acids, tall-oil, reaction products with (butoxymethyl) oxirane formaldehyde-phenol polymer...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Fatty acids, tall-oil, reaction... Substances § 721.10189 Fatty acids, tall-oil, reaction products with (butoxymethyl) oxirane formaldehyde... to reporting. (1) The chemical substance identified generically as fatty acids, tall-oil,...

  13. Light olefin production, skeletal olefin isomerization and etherification for oxygenated fuel production

    SciTech Connect

    Gaffney, A.M.

    1994-12-31

    ARCO`s newly developed SUPERFLEX{sup SM} process offers opportunities to product high yields of light olefins, from a variety of readily available refinery and petrochemical feedstocks. The process is unique in that it employs a catalytic reactor system which is lower in capital and operating costs than conventional steam cracking reactors. The SUPERFLEX process is also more selective for production of propylene and butylenes (including isobutylene) than conventional steam cracking operations. The C{sub 4} product stream from the SUPERFLEX process contains about 20 to 30 percent isobutylene. The SUPERFLEX C{sub 4} product is, therefore, an excellent feedstock for producing MTBE via reaction of the contained isobutylene with methanol. After MTBE production, the isobutylene depleted C{sub 4} stream may be recycled to the SUPERFLEX process to produce additional isobutylene and propylene. This paper will focus on the chemistry and mechanism of catalytic cracking and skeletal olefin isomerization. In addition, there will be some discussion on catalyst activation, life and characterization.

  14. Method and apparatus for effectively eliminating tar-forming fractions and light oils from gases produced by coal gasification. [US patent

    SciTech Connect

    Bissett, L.A.

    1981-01-09

    The present invention is directed to a coal-gasification system in which tar-forming fractions and light oil-forming fractions in the combustible gases formed in the gasification chamber are eliminated in such a manner so that the sensible heat realized in the gasification operation can be retained for recovery. In the present system preheated air is introduced together with the tar-laden-producer gas into an afterburner chamber where partial combustion of the producer gas occurs and increases the temperature of the gases in the afterburner to a temperature sufficient to thermally decompose the tar-forming fractions to provide a tar-free product gas and soot which is easily separated from the gas stream. While the heating value of the producer gas is slightly reduced by this afterburning operation, the volume of producer gas is increased by the addition thereto of gases provided by the reduction of the light oil- and tar-forming fractions. Further, the sensible heat in the gas from the gasification operation and that provided by this additional combustion operation is easily recovered so as to provide a tar-removing system considerably more efficient than previously available.

  15. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2003-06-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  16. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2004-03-05

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  17. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect

    Scott Hara

    2003-09-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  18. Classification of energy-conserving engine oil for passenger cars, vans, sport utility vehicles, and light-duty trucks (revised May 97). (SAE standard)

    SciTech Connect

    1997-05-01

    This SAE Standard was developed cooperatively by SAE, ASTM, and API to define and identify energy conserving engine oils for passenger cars, vans, and light-duty (3856 kg (8500 lb) GVW or less) trucks.

  19. Prediction of oil palm production using the weighted average of fuzzy sets concept approach

    NASA Astrophysics Data System (ADS)

    Nugraha, R. F.; Setiyowati, Susi; Mukhaiyar, Utriweni; Yuliawati, Apriliani

    2015-12-01

    Proper planning becomes crucial for decision making in a company. For oil palm producer companies, the prediction of future products realizations is useful and considered in making company's strategies. It is mean that to do the best in predicting is absolute. Until now, to predict the next monthly oil palm productions, the company use simple mean statistics of the latest five-year observations. Lately, imprecision in estimates of oil palm production (overestimate) becomes a problem and the focus of attention in a company. Here we proposed weighted mean approach by using fuzzy concept approach to do estimation and prediction. We obtain that the prediction using fuzzy concept almost always give underestimate of realizations than the simple mean.

  20. Biodiesel production from Jatropha oil catalyzed by immobilized Burkholderia cepacia lipase on modified attapulgite.

    PubMed

    You, Qinghong; Yin, Xiulian; Zhao, Yuping; Zhang, Yan

    2013-11-01

    Lipase from Burkholderia cepacia was immobilized on modified attapulgite by cross-linking reaction for biodiesel production with jatropha oil as feedstock. Effects of various factors on biodiesel production were studied by single-factor experiment. Results indicated that the best conditions for biodiesel preparation were: 10 g jatropha oil, 2.4 g methanol (molar ratio of oil to methanol is 1:6.6) being added at 3h intervals, 7 wt% water, 10 wt% immobilized lipase, temperature 35°C, and time 24h. Under these conditions, the maximum biodiesel yield reached 94%. The immobilized lipase retained 95% of its relative activity during the ten repeated batch reactions. The half-life time of the immobilized lipase is 731 h. Kinetics was studied and the Vmax of the immobilized lipases were 6.823 mmol L(-1). This immobilized lipase catalyzed process has potential industrial use for biodiesel production to replace chemical-catalyzed method. PMID:24055964

  1. Health implications of Mediterranean diets in light of contemporary knowledge. 2. Meat, wine, fats, and oils.

    PubMed

    Kushi, L H; Lenart, E B; Willett, W C

    1995-06-01

    Consumption of beef, pork, and lamb has traditionally been low in Mediterranean countries. Regular consumption of red meat has been associated in epidemiologic studies with increased risks of coronary heart disease (CHD) and colon and other cancers; possible mechanisms may involve dietary cholesterol, saturated fat, heme iron, and the presence of carcinogens formed in cooking. Also, high consumption of red meat, the major source of animal protein in most Western diets, increases urinary calcium losses and is therefore likely to contribute to osteoporotic fractures. In Mediterranean diets the major source of dietary fat has traditionally been olive oil, which, compared with saturated and partially hydrogenated fats, reduces low-density-lipoprotein (LDL) cholesterol and, compared with carbohydrates, increases high-density-lipoprotein (HDL) cholesterol. A wealth of epidemiologic evidence supports a potent protective effect of moderate alcohol consumption against CHD, probably in part by increasing HDL concentrations. Although dietary factors alone may not fully explain the excellent health of Mediterranean populations, available evidence strongly suggests important contributions of high consumption of fruit, vegetables, and whole grains; moderate intake of alcohol; and low consumption of animal products, saturated and hydrogenated fats, and refined carbohydrates. PMID:7754997

  2. Effects of fluid and light dynamics on H2 production in a mechanically stirred photobioreactor.

    PubMed

    Zhang, T

    2013-10-01

    Hydrogen productions through biophotolysis by microalgae in photobioreactors (PBRs) were studied using a computational model integrated with fluid dynamics, particle tracking technique, light attenuation dynamics, biochemical kinetics, and mass transport. The trajectories of microalgae entrained in the flow fields within these PBRs were traced by the particle tracking technique and were used to determine the dynamics of light attenuation subjected by the cells, which were analyzed and compared with those obtained from the unstirred PBR under different incident light illuminations. The results show an improvement on the light penetration depth in the mechanically stirred cultures. The dynamics of light attenuation was incorporated into the kinetics equations for the analysis of the inhomogeneous biochemical process for hydrogen production by microalgae. Hydrogen production in the unstirred and the impeller-stirred PBRs were determined under different light illumination conditions and the results show an improvement on hydrogen production in the impeller-stirred PBRs. PMID:23911818

  3. Enhanced biomass production and lipid accumulation of Picochlorum atomus using light-emitting diodes (LEDs).

    PubMed

    Ra, Chae Hun; Kang, Chang-Han; Jung, Jang-Hyun; Jeong, Gwi-Taek; Kim, Sung-Koo

    2016-10-01

    The effects of light-emitting diode (LED) wavelength, light intensity, nitrate concentration, and time of exposure to different LED wavelength stresses in a two-phase culture on lipid production were evaluated in the microalga, Picochlorum atomus. The biomass produced by red LED light was higher than that produced by purple, blue, green, or yellow LED and fluorescent lights from first phase of two-phase culture. The highest lipid production of P. atomus was 50.3% (w/w) with green LED light at 2days of second phase as light stress. Fatty acid analysis of the microalgae showed that palmitic acid (C16:0) and linolenic acid (C18:3) accounted for 84-88% (w/w) of total fatty acids from P. atomus. The two-phase culture of P. atomus is suitable for biofuel production due to higher lipid productivity and favorable fatty acid composition. PMID:27474341

  4. Improved method for determination of light filth in chocolate products.

    PubMed

    Shostak, M T

    1978-07-01

    The recovery of rodent hairs from chocolate has been significantly improved by the introduction of an additional defatting step, substitution of 40% isopropanol for water, and substitution of mineral oil-heptane (85+15) for heptane in the trapping-off step. These changes have no adverse effect on insect fragment recovery. An average recovery of 95% was obtained for rodent hairs, coefficient of variation 7.9%. Insect fragment recoveries were 100%. PMID:681273

  5. Contact and Repellent Activities of the Essential Oil from Juniperus formosana against Two Stored Product Insects.

    PubMed

    Guo, Shanshan; Zhang, Wenjuan; Liang, Junyu; You, Chunxue; Geng, Zhufeng; Wang, Chengfang; Du, Shushan

    2016-01-01

    The chemical composition of the essential oil from Juniperus formosana leaves and its contact and repellent activities against Tribolium castaneum and Liposcelis bostrychophila adults were investigated. The essential oil of J. formosana leaves was obtained by hydrodistillation and analyzed by GC-MS. A total of 28 components were identified and the main compounds in the essential oil were α-pinene (21.66%), 4-terpineol (11.25%), limonene (11.00%) and β-phellandrene (6.63%). The constituents α-pinene, 4-terpineol and d-limonene were isolated from the essential oil. It was found that the essential oil exhibited contact activity against T. castaneum and L. bostrychophila adults (LD50 = 29.14 μg/adult and 81.50 µg/cm², respectively). The compound 4-terpineol exhibited the strongest contact activity (LD50 = 7.65 μg/adult). In addition, data showed that at 78.63 nL/cm², the essential oil and the three isolated compounds strongly repelled T. castaneum adults. The compounds α-pinene and d-limonene reached the same level (Class V) of repellency as DEET (p = 0.396 and 0.664) against L. bostrychophila at 63.17 nL/cm² after 2 h treatment. The results indicate that the essential oil and the isolated compounds have potential to be developed into natural insecticides and repellents to control insects in stored products. PMID:27092485

  6. 16 CFR 305.15 - Labeling for lighting products.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... package, as measured in degrees Kelvin and expressed as “Light Appearance” and by a number and a marker in... standards specified in 42 U.S.C. 6295 or the DOE standards at 10 CFR 430.32(n)(5) effective July 14, 2012... day and 11 cents ($0.11) per kWh. (2) Principal display panel format: The light output...

  7. 16 CFR 305.15 - Labeling for lighting products.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... package, as measured in degrees Kelvin and expressed as “Light Appearance” and by a number and a marker in... standards specified in 42 U.S.C. 6295 or the DOE standards at 10 CFR 430.32(n)(5) effective July 14, 2012... day and 11 cents ($0.11) per kWh. (2) Principal display panel format. The light output...

  8. Production of rhamnolipids and diesel oil degradation by bacteria isolated from soil contaminated by petroleum.

    PubMed

    Leite, Giuseppe G F; Figueirôa, Juciane V; Almeida, Thiago C M; Valões, Jaqueline L; Marques, Walber F; Duarte, Maria D D C; Gorlach-Lira, Krystyna

    2016-03-01

    Biosurfactants are microbial secondary metabolites. The most studied are rhamnolipids, which decrease the surface tension and have emulsifying capacity. In this study, the production of biosurfactants, with emphasis on rhamnolipids, and diesel oil degradation by 18 strains of bacteria isolated from waste landfill soil contaminated by petroleum was analyzed. Among the studied bacteria, gram-positive endospore forming rods (39%), gram positive rods without endospores (17%), and gram-negative rods (44%) were found. The following methods were used to test for biosurfactant production: oil spreading, emulsification, and hemolytic activity. All strains showed the ability to disperse the diesel oil, while 77% and 44% of the strains showed hemolysis and emulsification of diesel oil, respectively. Rhamnolipids production was observed in four strains that were classified on the basis of the 16S rRNA sequences as Pseudomonas aeruginosa. Only those strains showed the rhlAB gene involved in rhamnolipids synthesis, and antibacterial activity against Escherichia coli, P. aeruginosa, Staphylococcus aureus, Bacillus cereus, Erwinia carotovora, and Ralstonia solanacearum. The highest production of rhamnolipids was 565.7 mg/L observed in mineral medium containing olive oil (pH 8). With regard to the capacity to degrade diesel oil, it was observed that 7 strains were positive in reduction of the dye 2,6-dichlorophenolindophenol (2,6-DCPIP) while 16 had the gene alkane mono-oxygenase (alkB), and the producers of rhamnolipids were positive in both tests. Several bacterial strains have shown high potential to be explored further for bioremediation purposes due to their simultaneous ability to emulsify, disperse, and degrade diesel oil. © 2015 American Institute of Chemical Engineers Biotechnol. Prog., 32:262-270, 2016. PMID:26588432

  9. The effects of utilization of hazelnut oil, sunflower oil and their products on performance and fatty acid composition of yolk in layer hens.

    PubMed

    Cetıngul, I S; Inal, F

    2009-08-01

    This research has been performed to determine the effects of hazelnut crude oil, sunflower crude oil and its refinery by-products over the laying hens performance and the fatty acid composition of the egg's yolk. Four hundreds 36-week-old Nick Brown layer hens were allocated into five groups. Treatment groups were supplemented with 1.5% of sunflower crude oil, hazelnut crude oil, acidulated sunflower soapstock, acidulated hazelnut soapstock and acidulated hazelnut crude oil. The daily feed consumption for groups that were fed with crude oils were numerically improved as compared for those nourished with acidulated soapstocks. Although the percentages of cracked and broken eggs in acidulated hazelnut soapstock group was significantly higher than the other groups, daily feed consumption and egg production values were not different. The usage of acidulated hazelnut soapstock reduced the percentage of intact egg ratio. Egg's specific gravity and yolk color index were the highest level throughout the experiment from start to end in hazelnut crude oil group (p < 0.05). In group that was nourished by hazelnut oil, Omega 3/Omega-6 fatty acid ratios in egg yolk were higher than the groups that were fed with sunflower oil. The oleic acid content of the egg yolk was increased in the groups which were supplemented with hazelnut crude oil and acidulated hazelnut crude oil. Consequently, hazelnut crude oil and acidulated hazelnut crude oil improved the egg shell quality, yolk color index and yolk oleic acid value which would increase egg's shelf life. On the other hand acidulated hazelnut soapstock supplementation adversely affects the quality of egg shell. PMID:19142742

  10. Optimization of crude oil degradation by Dietzia cinnamea KA1, capable of biosurfactant production.

    PubMed

    Kavynifard, Amirarsalan; Ebrahimipour, Gholamhossein; Ghasempour, Alireza

    2016-05-01

    The aim of this study was isolation and characterization of a crude oil degrader and biosurfactant-producing bacterium, along with optimization of conditions for crude oil degradation. Among 11 isolates, 5 were able to emulsify crude oil in Minimal Salt Medium (MSM) among which one isolate, named KA1, showed the highest potency for growth rate and biodegradation. The isolate was identified as Dietzia cinnamea KA1 using morphological and biochemical characteristics and 16S rRNA gene sequencing. The optimal conditions were 510 mM NaCl, pH 9.0, 35 °C, and minimal requirement of 46.5 mM NH4 Cl and 2.10 mM NaH2 PO4 . Gravimetric test and Gas chromatography-Mass spectroscopy technique (GC-MS) showed that Dietzia cinnamea KA1 was able to utilize and degrade 95.7% of the crude oil after 5 days, under the optimal conditions. The isolate was able to grow and produce biosurfactant when cultured in MSM supplemented with crude oil, glycerol or whey as the sole carbon sources, but bacterial growth was occurred using molasses with no biosurfactant production. This is the first report of biosurfactant production by D. cinnamea using crude oil, glycerol and whey and the first study to report a species of Dietzia degrading a wide range of hydrocarbons in a short time. PMID:26615815

  11. Minimising hydrogen sulphide generation during steam assisted production of heavy oil

    NASA Astrophysics Data System (ADS)

    Montgomery, Wren; Sephton, Mark A.; Watson, Jonathan S.; Zeng, Huang; Rees, Andrew C.

    2015-02-01

    The majority of global petroleum is in the form of highly viscous heavy oil. Traditionally heavy oil in sands at shallow depths is accessed by large scale mining activities. Recently steam has been used to allow heavy oil extraction with greatly reduced surface disturbance. However, in situ thermal recovery processes can generate hydrogen sulphide, high levels of which are toxic to humans and corrosive to equipment. Avoiding hydrogen sulphide production is the best possible mitigation strategy. Here we use laboratory aquathermolysis to reproduce conditions that may be experienced during thermal extraction. The results indicate that hydrogen sulphide generation occurs within a specific temperature and pressure window and corresponds to chemical and physical changes in the oil. Asphaltenes are identified as the major source of sulphur. Our findings reveal that for high sulphur heavy oils, the generation of hydrogen sulphide during steam assisted thermal recovery is minimal if temperature and pressure are maintained within specific criteria. This strict pressure and temperature dependence of hydrogen sulphide release can allow access to the world's most voluminous oil deposits without generating excessive amounts of this unwanted gas product.

  12. Minimising hydrogen sulphide generation during steam assisted production of heavy oil

    PubMed Central

    Montgomery, Wren; Sephton, Mark A.; Watson, Jonathan S.; Zeng, Huang; Rees, Andrew C.

    2015-01-01

    The majority of global petroleum is in the form of highly viscous heavy oil. Traditionally heavy oil in sands at shallow depths is accessed by large scale mining activities. Recently steam has been used to allow heavy oil extraction with greatly reduced surface disturbance. However, in situ thermal recovery processes can generate hydrogen sulphide, high levels of which are toxic to humans and corrosive to equipment. Avoiding hydrogen sulphide production is the best possible mitigation strategy. Here we use laboratory aquathermolysis to reproduce conditions that may be experienced during thermal extraction. The results indicate that hydrogen sulphide generation occurs within a specific temperature and pressure window and corresponds to chemical and physical changes in the oil. Asphaltenes are identified as the major source of sulphur. Our findings reveal that for high sulphur heavy oils, the generation of hydrogen sulphide during steam assisted thermal recovery is minimal if temperature and pressure are maintained within specific criteria. This strict pressure and temperature dependence of hydrogen sulphide release can allow access to the world's most voluminous oil deposits without generating excessive amounts of this unwanted gas product. PMID:25670085

  13. Cinnamon bark oil and its components inhibit biofilm formation and toxin production.

    PubMed

    Kim, Yong-Guy; Lee, Jin-Hyung; Kim, Soon-Il; Baek, Kwang-Hyun; Lee, Jintae

    2015-02-16

    The long-term usage of antibiotics has resulted in the evolution of multidrug resistant bacteria, and pathogenic biofilms contribute to reduced susceptibility to antibiotics. In this study, 83 essential oils were initially screened for biofilm inhibition against Pseudomonas aeruginosa. Cinnamon bark oil and its main constituent cinnamaldehyde at 0.05% (v/v) markedly inhibited P. aeruginosa biofilm formation. Furthermore, cinnamon bark oil and eugenol decreased the production of pyocyanin and 2-heptyl-3-hydroxy-4(1H)-quinolone, the swarming motility, and the hemolytic activity of P. aeruginosa. Also, cinnamon bark oil, cinnamaldehyde, and eugenol at 0.01% (v/v) significantly decreased biofilm formation of enterohemorrhagic Escherichia coli O157:H7 (EHEC). Transcriptional analysis showed that cinnamon bark oil down-regulated curli genes and Shiga-like toxin gene stx2 in EHEC. In addition, biodegradable poly(lactic-co-glycolic acid) film incorporating biofilm inhibitors was fabricated and shown to provide efficient biofilm control on solid surfaces. This is the first report that cinnamon bark oil and its components, cinnamaldehyde and eugenol, reduce the production of pyocyanin and PQS, the swarming motility, and the hemolytic activity of P. aeruginosa, and inhibit EHEC biofilm formation. PMID:25500277

  14. Determining The Dispersibility Of South Louisiana Crude Oil By Eight Oil Dispersant Products Listed On The NCP Product Schedule

    EPA Science Inventory

    We recently conducted a laboratory study to measure the dispersion effectiveness of eight dispersants currently listed on the National Contingency Plan Product Schedule. Results are useful in determining how many commercial dispersant products would have been effective for use o...

  15. Exopolysaccharide production by a genetically engineered Enterobacter cloacae strain for microbial enhanced oil recovery.

    PubMed

    Sun, Shanshan; Zhang, Zhongzhi; Luo, Yijing; Zhong, Weizhang; Xiao, Meng; Yi, Wenjing; Yu, Li; Fu, Pengcheng

    2011-05-01

    Microbial enhanced oil recovery (MEOR) is a petroleum biotechnology for manipulating function and/or structure of microbial environments existing in oil reservoirs for prolonged exploitation of the largest source of energy. In this study, an Enterobacter cloacae which is capable of producing water-insoluble biopolymers at 37°C and a thermophilic Geobacillus strain were used to construct an engineered strain for exopolysaccharide production at higher temperature. The resultant transformants, GW3-3.0, could produce exopolysaccharide up to 8.83 g l(-1) in molasses medium at 54°C. This elevated temperature was within the same temperature range as that for many oil reservoirs. The transformants had stable genetic phenotype which was genetically fingerprinted by RAPD analysis. Core flooding experiments were carried out to ensure effective controlled profile for the simulation of oil recovery. The results have demonstrated that this approach has a promising application potential in MEOR. PMID:21444201

  16. Production of biodiesel from non-edible herbaceous vegetable oil: Xanthium sibiricum Patr.

    PubMed

    Chang, Fei; Hanna, Milford A; Zhang, De-Jing; Li, Hu; Zhou, Quan; Song, Bao-An; Yang, Song

    2013-07-01

    In this study, Xanthium sibiricum Patr oil, a non-edible oil, was investigated for the first time to produce biodiesel. X. sibiricum Patr has very good environmental adaptability and thus has plenty of wild resources. Its seed has a high oil content (42.34%) which gives potential annual output of 100,000 tons just in China. And the oil acid value is pretty low (1.38 mg KOH/g). Under the optimal conditions, the FAME content and yield of X. sibiricum biodiesel were 98.7 wt.% and 92.0%, respectively. The properties of the biodiesel product were tested and most properties were in accordance with EN 14214-08, ASTM D6751-10 and GB/T 20828-07 standards, except cetane number and oxidative stability. The results indicated that X. sibiricum Patr is a promising species as a biodiesel feedstock in China. PMID:23714693

  17. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect

    Scott Hara

    1998-03-03

    The project involves improving thermal recovery techniques in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. using advanced reservoir characterization and thermal production technologies. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing a 2100 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and

  18. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect

    Scott Hara

    1997-08-08

    The project involves improving thermal recovery techniques in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. using advanced reservoir characterization and thermal production technologies. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing a 2100 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and

  19. Sub/supercritical liquefaction of oil palm fruit press fiber for the production of bio-oil: effect of solvents.

    PubMed

    Mazaheri, Hossein; Lee, Keat Teong; Bhatia, Subhash; Mohamed, Abdul Rahman

    2010-10-01

    Thermal decomposition of oil palm fruit press fiber (FPF) with sub/supercritical methanol, ethanol, acetone, and 1,4-dioxane treatments were investigated using a high-pressure autoclave reactor. When FPF was decomposed with methanol, ethanol, and acetone from 483 to 603 K, the highest degree of conversion obtained were 81.5%, 77.8%, and 67.9% while the highest liquid product yield (LP) obtained were 38.0%, 36.9%, and 38.5%, respectively. For the case of 1,4-dioxane, the conversion of FPF increased from 18.30% to 80.00%, while LP yield increased dramatically from 13.30% to 50.90% (consisting of 42.3% bio-oil compounds) when the reaction temperature was increased from 483 to 563 K. However, the conversion of FPF and LP yield decreased to 69.60% and 24.10%, respectively, when the temperature was further increased to 603 K. Comparison between all the solvents, subcritical 1,4-dioxane treatment was found very effective in the degradation of FPF to produce bio-oil component. PMID:20510608

  20. Analytical expressions to estimate the free product recovery in oil-contaminated aquifers

    NASA Astrophysics Data System (ADS)

    Corapcioglu, M. Yavuz; Tuncay, Kagan; Lingarn, Rajasekhar; Kambham, Kiran K. R.

    1994-12-01

    Petroleum products, such as gasoline, leaked from an underground storage tank can be recovered successfully by two-pump operations. The success of the recovery effort depends on the accurate placement of the recovery well at the spill site. An effective recovery operation can minimize the remaining contamination mass in the subsurface. Therefore, a careful evaluation and determination has to be made as to where to locate the recovery well. The location of the well can be decided based on an estimation of the extent and thickness of free product on the water table. Such an estimation should be based on analysis of governing mechanisms. In this study we present analytical solutions to estimate the recovery of oil from an established oil lens. These solutions are obtained by applying the Laplace transformation to averaged linear partial differential equations governing the phenomenon. The governing equation for the free product thickness is derived by averaging the oil phase mass balance equation along the free product thickness and substituting the boundary conditions at the oil/water interface and oil surface. The analytical solutions estimate the temporal and spatial distribution of free product thickness on the water table for a number of recovery scenarios. Results are presented for the temporal and spatial variation of the free product thickness, temporal variation of the free product volume recovered, and recovery efficiency based on the readings at the monitoring wells. Since they can be utilized without a great deal of data, analytical solutions are quite attractive as screening tools in two-pump free product recovery operations.