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Sample records for liquids condensed disordered

  1. Spin-liquid condensate of spinful bosons.

    PubMed

    Lian, Biao; Zhang, Shoucheng

    2014-08-22

    We introduce the concept of a bosonic spin liquid condensate (SLC), where spinful bosons in a lattice form a zero-temperature spin disordered charge condensate that preserves the spin rotation symmetry, but breaks the U(1) symmetry due to a spinless order parameter with charge one. It has an energy gap to all the spin excitations. We show that such SLC states can be realized in a system of spin S ≥ 2 bosons. In particular, we analyze the SLC phase diagram in the spin 2 case using a mean-field variational wave function method. We show there is a direct analogy between the SLC and the resonating-valence-bond state. PMID:25192078

  2. Vapor condensation on a turbulent liquid interface

    NASA Technical Reports Server (NTRS)

    Helmick, M. R.; Khoo, B. C.; Sonin, A. A.

    1987-01-01

    An experimental investigation which seeks the fundamental relationship between the interfacial condensation rate and the parameters which control it when the liquid side is turbulent is discussed. The scaling laws for free-surface condensation are discussed for this case. It is argued that the condensation of cryogenic liquids can, in principle, be simulated in experiments using steam and water. Data are presented for the condensation rate in terms of the dimensionless scaling parameters which involve the fluid properties and the liquid-side turbulence velocity and length scales.

  3. Quasihole condensates in quantum Hall liquids

    SciTech Connect

    Suorsa, J.; Viefers, S.; Hansson, T. H.

    2011-06-15

    We develop a formalism to describe quasihole condensates in quantum Hall liquids and thereby extend the conformal field theory approach to the full hierarchy of spin-polarized Abelian states and to several classes of non-Abelian hierarchical states. Most previously proposed spin-polarized quantum Hall wave functions appear as special cases. In this paper we explain the physical motivations for the approach, and exemplify it by explicitly constructing the level-two quasihole condensate state at filling fraction 2/3, and the two level-three states at 5/13 and 5/7 which are built from combinations of quasielectron and quasihole condensates.

  4. Bose condensation in topologically ordered quantum liquids

    NASA Astrophysics Data System (ADS)

    Neupert, Titus; He, Huan; von Keyserlingk, Curt; Sierra, German; Bernevig, Andrei

    The condensation of bosons can induce transitions between topological quantum field theories (TQFTs). This as been previously investigated through the formalism of Frobenius algebras and with the use of Vertex lifting coefficients. We discuss an alternative, algebraic approach to boson condensation in TQFTs that is physically motivated and computationally efficient. With a minimal set of assumptions, such as commutativity of the condensation with the fusion of anyons, we can prove a number of theorems linking boson condensation in TQFTs with algebra extensions in conformal field theories and with the problem of factorization of completely positive matrices over the positive integers. We propose an algorithm for obtaining a condensed theory fusion algebra and its modular matrices. For example, this formalism can be used to build multi-layer TQFTs which could be a starting point to build three-dimensional topologically ordered phases. Using this formalism, we also give examples of bosons that cannot undergo a condensation transition due to topological obstructions.

  5. Condensation of liquid metals under low pressures

    SciTech Connect

    Elafify, M.M.

    1988-01-01

    The Direct Simulation Monte Carlo (DSMC) method is used to study one-dimensional condensation phenomena for a pure vapor or vapor/gas mixture. The results are fitted to an interpolation formula describing the condensation mass flux to provide a usable engineering correlation. For pure vapor, the DSMC results are compared with the available experimental data for condensation of mercury under low pressure. Results are compared also with some of the theoretical models. The comparison shows that the DSMC method is able to detect the qualitative behavior of the condensation mass flux, although it overestimates the mass flux by 20-30%. Compared with other introduced theoretical models, the DSMC method has the most-consistent representation of the qualitative behavior of the condensation mass flux. The method was also used to represent condensation in the presence of a noncondensable gas. A formal proof for choosing collision partners was introduced and applied in the case of condensation in the presence of a noncondensable gas. The method is applied to condensation of mercury in the presence of different monatomic noncondensable gases at different partial pressures.

  6. Boson condensation in topologically ordered quantum liquids

    NASA Astrophysics Data System (ADS)

    Neupert, Titus; He, Huan; von Keyserlingk, Curt; Sierra, Germán; Bernevig, B. Andrei

    2016-03-01

    Boson condensation in topological quantum field theories (TQFT) has been previously investigated through the formalism of Frobenius algebras and the use of vertex lifting coefficients. While general, this formalism is physically opaque and computationally arduous: analyses of TQFT condensation are practically performed on a case by case basis and for very simple theories only, mostly not using the Frobenius algebra formalism. In this paper, we provide a way of treating boson condensation that is computationally efficient. With a minimal set of physical assumptions, such as commutativity of lifting and the definition of confined particles, we can prove a number of theorems linking Boson condensation in TQFT with chiral algebra extensions, and with the factorization of completely positive matrices over Z+. We present numerically efficient ways of obtaining a condensed theory fusion algebra and S matrices; and we then use our formalism to prove several theorems for the S and T matrices of simple current condensation and of theories which upon condensation result in a low number of confined particles. We also show that our formalism easily reproduces results existent in the mathematical literature such as the noncondensability of five and ten layers of the Fibonacci TQFT.

  7. Evaporation and condensation at a liquid surface. II. Methanol

    NASA Astrophysics Data System (ADS)

    Matsumoto, Mitsuhiro; Yasuoka, Kenji; Kataoka, Yosuke

    1994-11-01

    The rates of evaporation and condensation of methanol under the vapor-liquid equilibrium condition at the temperature of 300 and 350 K are investigated with a molecular dynamics computer simulation. Compared with the argon system (reported in part I), the ratio of self-reflection is similar (˜10%), but the ratio of molecule exchange is several times larger than the argon, which suggests that the conventional assumption of condensation as a unimolecular process completely fails for associating fluids. The resulting total condensation coefficient is 20%-25%, and has a quantitative agreement with a recent experiment. The temperature dependence of the evaporation-condensation behavior is not significant.

  8. Molecular dynamics study on condensation/evaporation coefficients of chain molecules at liquid-vapor interface

    NASA Astrophysics Data System (ADS)

    Nagayama, Gyoko; Takematsu, Masaki; Mizuguchi, Hirotaka; Tsuruta, Takaharu

    2015-07-01

    The structure and thermodynamic properties of the liquid-vapor interface are of fundamental interest for numerous technological implications. For simple molecules, e.g., argon and water, the molecular condensation/evaporation behavior depends strongly on their translational motion and the system temperature. Existing molecular dynamics (MD) results are consistent with the theoretical predictions based on the assumption that the liquid and vapor states in the vicinity of the liquid-vapor interface are isotropic. Additionally, similar molecular condensation/evaporation characteristics have been found for long-chain molecules, e.g., dodecane. It is unclear, however, whether the isotropic assumption is valid and whether the molecular orientation or the chain length of the molecules affects the condensation/evaporation behavior at the liquid-vapor interface. In this study, MD simulations were performed to study the molecular condensation/evaporation behavior of the straight-chain alkanes, i.e., butane, octane, and dodecane, at the liquid-vapor interface, and the effects of the molecular orientation and chain length were investigated in equilibrium systems. The results showed that the condensation/evaporation behavior of chain molecules primarily depends on the molecular translational energy and the surface temperature and is independent of the molecular chain length. Furthermore, the orientation at the liquid-vapor interface was disordered when the surface temperature was sufficiently higher than the triple point and had no significant effect on the molecular condensation/evaporation behavior. The validity of the isotropic assumption was confirmed, and we conclude that the condensation/evaporation coefficients can be predicted by the liquid-to-vapor translational length ratio, even for chain molecules.

  9. Condensation on a noncollapsing vapor bubble in a subcooled liquid

    NASA Technical Reports Server (NTRS)

    Baumeister, K. J.; Simoneau, R. J.

    1979-01-01

    An experimental procedure is presented by which an estimate can be made of the condensation coefficient on a noncollapsing stationary vapor bubble in subcooled liquid nitrogen. Film boiling from a thin wire was used to generate vapor bubbles which remain fixed to the wire at their base. A balance was established between the evaporation in the thin annular region along the wire and the condensation in the vapor bubbles.

  10. Condensation on a noncollapsing vapor bubble in a subcooled liquid

    NASA Technical Reports Server (NTRS)

    Baumeister, K. J.; Simoneau, R. J.

    1979-01-01

    An experimental procedure is presented by which an estimate can be made of the condensation coefficient on a noncollapsing stationary vapor bubble in subcooled liquid nitrogen. The present experimental study utilizes film boiling from a thin wire to generate vapor bubbles which remain fixed to the wire at their base. A balance was established between the evaporation in the thin annular region along the wire and the condensation in the vapor bubbles.

  11. Boundary conditions on the vapor liquid interface at strong condensation

    NASA Astrophysics Data System (ADS)

    Kryukov, A. P.; Levashov, V. Yu.

    2016-07-01

    The problem of the formulation of boundary conditions on the vapor-liquid interface is considered. The different approaches to this problem and their difficulties are discussed. Usually, a quasi-equilibrium scheme is used. At sufficiently large deviations from thermodynamic equilibrium, a molecular kinetics approach should be used for the description of the vapor flow at condensation. The formulation of the boundary conditions at the vapor liquid interface to solve the Boltzmann kinetic equation for the distribution of molecules by velocity is a sophisticated problem. It appears that molecular dynamics simulation (MDS) can be used to provide this solution at the interface. The specific problems occur in the realization of MDS on large time and space scales. Some of these problems, and a hierarchy of continuum, kinetic and molecular dynamic time scales, are discussed in the paper. A description of strong condensation at the kinetic level is presented for the steady one-dimensional problem. A formula is provided for the calculation of the limiting condensation coefficient. It is shown that as the condensation coefficient approaches the limiting value, the vapor pressure rises significantly. The results of the corresponding calculations for the Mach number and temperature at different vapor flows are demonstrated. As a result of the application of the molecular kinetics method and molecular dynamics simulation to the problem of the determination of argon condensation coefficients in the range of temperatures of vapor and liquid ratio 1.0-4.0, it is concluded that the condensation coefficient is close to unity.

  12. Evaporation and condensation at a liquid surface. I. Argon

    NASA Astrophysics Data System (ADS)

    Yasuoka, Kenji; Matsumoto, Mitsuhiro; Kataoka, Yosuke

    1994-11-01

    Molecular dynamics computer simulations were carried out to investigate the dynamics of evaporation and condensation for argon at the temperature of 80 and 100 K. From the decrease of the survival probability of vapor molecules, the ratio of self reflection to collision is estimated to be 12%-15%, only weakly dependent on the temperature. This suggests that argon vapor molecules are in the condition of almost complete capture, and the condensation is considered to be a barrierless process. The total ratio of reflection which is evaluated with the flux correlation of condensation and evaporation is 20% at both temperature. The difference between these two ratios of reflection is ascribed to a phenomenon that vapor molecules colliding with the surface drive out other liquid molecules. This molecule exchange at the surface is as important as the self-reflection, and the conventional picture of condensation as a unimolecular chemical reaction is not appropriate.

  13. Condensation temperature of interacting Bose gases with and without disorder

    SciTech Connect

    Zobay, O.

    2006-02-15

    The momentum-shell renormalization group (RG) is used to study the condensation of interacting Bose gases without and with disorder. First of all, for the homogeneous disorder-free Bose gas the interaction-induced shifts in the critical temperature and chemical potential are determined up to second order in the scattering length. The approach does not make use of dimensional reduction and is thus independent of previous derivations. Secondly, the RG is used together with the replica method to study the interacting Bose gas with delta-correlated disorder. The flow equations are derived and found to reduce, in the high-temperature limit, to the RG equations of the classical Landau-Ginzburg model with random-exchange defects. The random fixed point is used to calculate the condensation temperature under the combined influence of particle interactions and disorder.

  14. Condensation of acetol and acetic acid vapor with sprayed liquid

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A cellulose-derived fraction of biomass pyrolysis vapor was simulated by evaporating acetol and acetic acid (AA) from flasks on a hot plate. The liquid in the flasks was infused with heated nitrogen. The vapor/nitrogen stream was superheated in a tube oven and condensed by contact with a cloud of ...

  15. Bose-Einstein condensation in liquid 4He under pressure

    SciTech Connect

    Glyde, Henry R; Omar Diallo, Souleymane; Azuah, Richard T; Kirichek, Oleg; Taylor, Jon W.

    2011-01-01

    We present neutron scattering measurements of Bose-Einstein condensation, the atomic momen- tum distribution and Final State effects in liquid 4He under pressure. The condensate fraction at low temperature is found to decrease from n0 = 7.25 0.75% at SVP (p 0) to n0 = 3.2 0.75% at pressure p = 24 bar. This indicates an n0 = 3.0% in the liquid at the liquid/solid co-existence line (p = 25.3 bar). The atomic momentum distribution n(k) has high occupation of low k states and differs significantly from a Gaussian (e.g. a classical n(k)). Both n(k) and the Final state function broaden with increasing pressure, reflecting the increased localization of the 4He in space under increased pressure.

  16. Mixing and transient interface condensation of a liquid hydrogen tank

    NASA Technical Reports Server (NTRS)

    Lin, C. S.; Hasan, M. M.; Nyland, T. W.

    1993-01-01

    Experiments were conducted to investigate the effect of axial jet-induced mixing on the pressure reduction of a thermally stratified liquid hydrogen tank. The tank was nearly cylindrical, having a volume of about 0.144 cu m with 0.559 m in diameter and 0.711 m length. A mixer/pump unit, which had a jet nozzle outlet of 0.0221 m in diameter was located 0.178 m from the tank bottom and was installed inside the tank to generate the axial jet mixing and tank fluid circulation. Mixing tests began with the tank pressures at which the thermal stratification results in 4.9-6.2 K liquid subcooling. The mixing time and transient vapor condensation rate at the liquid-vapor interface are determined. Two mixing time correlations, based on the thermal equilibrium and pressure equilibrium, are developed and expressed as functions of system and buoyancy parameters. The limited liquid hydrogen data of the present study shows that the modified steady state condensation rate correlation may be used to predict the transient condensation rate in a mixing process if the instantaneous values of jet sub cooling and turbulence intensity at the interface are employed.

  17. Mixing and transient interface condensation of a liquid hydrogen tank

    NASA Technical Reports Server (NTRS)

    Lin, C. S.; Hasan, M. M.; Nyland, T. W.

    1993-01-01

    Experiments were conducted to investigate the effect of axial jet-induced mixing on the pressure reduction of a thermally stratified liquid hydrogen tank. The tank was nearly cylindrical, having a volume of about 0.144 cu m with 0.559 m in diameter and 0.711 m long. A mixer/pump unit, which had a jet nozzle outlet of 0.0221 m in diameter was located 0.178 m from the tank bottom and was installed inside the tank to generate the axial jet mixing and tank fluid circulation. The liquid fill and jet flow rate ranged from 42 to 85 percent (by volume) and 0.409 to 2.43 cu m/hr, respectively. Mixing tests began with the tank pressure ranging from 187.5 to 238.5 kPa at which the thermal stratification results in 4.9 to 6.2 K liquid sub cooling. The mixing time and transient vapor condensation rate at the liquid-vapor interface are determined. Two mixing time correlations, based on the thermal equilibrium and pressure equilibrium, are developed. Both mixing time correlations are expressed as functions of system and buoyancy parameters and compared well with other experimental data. The steady state condensation rate correlation of Sonin et al. based on steam-water data is modified and expressed as a function of jet subcooling. The limited liquid hydrogen data of the present study shows that the modified steady state condensation rate correlation may be used to predict the transient condensation rate in a mixing process if the instantaneous values of jet sub cooling and turbulence intensity at the interface are employed.

  18. Spatial Coherence and Stability in a Disordered Organic Polariton Condensate

    NASA Astrophysics Data System (ADS)

    Daskalakis, K. S.; Maier, S. A.; Kéna-Cohen, S.

    2015-07-01

    Although only a handful of organic materials have shown polariton condensation, their study is rapidly becoming more accessible. The spontaneous appearance of long-range spatial coherence is often recognized as a defining feature of such condensates. In this Letter, we study the emergence of spatial coherence in an organic microcavity and demonstrate a number of unique features stemming from the peculiarities of this material set. Despite its disordered nature, we find that correlations extend over the entire spot size, and we measure g(1 )(r ,r') values of nearly unity at short distances and of 50% for points separated by nearly 10 μ m . We show that for large spots, strong shot-to-shot fluctuations emerge as varying phase gradients and defects, including the spontaneous formation of vortices. These are consistent with the presence of modulation instabilities. Furthermore, we find that measurements with flat-top spots are significantly influenced by disorder and can, in some cases, lead to the formation of mutually incoherent localized condensates.

  19. Spatial Coherence and Stability in a Disordered Organic Polariton Condensate.

    PubMed

    Daskalakis, K S; Maier, S A; Kéna-Cohen, S

    2015-07-17

    Although only a handful of organic materials have shown polariton condensation, their study is rapidly becoming more accessible. The spontaneous appearance of long-range spatial coherence is often recognized as a defining feature of such condensates. In this Letter, we study the emergence of spatial coherence in an organic microcavity and demonstrate a number of unique features stemming from the peculiarities of this material set. Despite its disordered nature, we find that correlations extend over the entire spot size, and we measure g(1)(r,r') values of nearly unity at short distances and of 50% for points separated by nearly 10  μm . We show that for large spots, strong shot-to-shot fluctuations emerge as varying phase gradients and defects, including the spontaneous formation of vortices. These are consistent with the presence of modulation instabilities. Furthermore, we find that measurements with flat-top spots are significantly influenced by disorder and can, in some cases, lead to the formation of mutually incoherent localized condensates. PMID:26230799

  20. Vapor condensation onto a non-volatile liquid drop

    SciTech Connect

    Inci, Levent; Bowles, Richard K.

    2013-12-07

    Molecular dynamics simulations of miscible and partially miscible binary Lennard–Jones mixtures are used to study the dynamics and thermodynamics of vapor condensation onto a non-volatile liquid drop in the canonical ensemble. When the system volume is large, the driving force for condensation is low and only a submonolayer of the solvent is adsorbed onto the liquid drop. A small degree of mixing of the solvent phase into the core of the particles occurs for the miscible system. At smaller volumes, complete film formation is observed and the dynamics of film growth are dominated by cluster-cluster coalescence. Mixing into the core of the droplet is also observed for partially miscible systems below an onset volume suggesting the presence of a solubility transition. We also develop a non-volatile liquid drop model, based on the capillarity approximations, that exhibits a solubility transition between small and large drops for partially miscible mixtures and has a hysteresis loop similar to the one observed in the deliquescence of small soluble salt particles. The properties of the model are compared to our simulation results and the model is used to study the formulation of classical nucleation theory for systems with low free energy barriers.

  1. The Influence of Disorder on Thermotropic Nematic Liquid Crystals Phase Behavior

    PubMed Central

    Popa-Nita, Vlad; Gerlič, Ivan; Kralj, Samo

    2009-01-01

    We review the theoretical research on the influence of disorder on structure and phase behavior of condensed matter system exhibiting continuous symmetry breaking focusing on liquid crystal phase transitions. We discuss the main properties of liquid crystals as adequate systems in which several open questions with respect to the impact of disorder on universal phase and structural behavior could be explored. Main advantages of liquid crystalline materials and different experimental realizations of random field-type disorder imposed on liquid crystal phases are described. PMID:19865529

  2. Kaon condensation in baryonic Fermi liquid at high density

    NASA Astrophysics Data System (ADS)

    Paeng, Won-Gi; Rho, Mannque

    2015-01-01

    We formulate kaon condensation in dense baryonic matter with antikaons fluctuating from the Fermi-liquid fixed point. This entails that in the Wilsonian renormalization group (RG) approach, the decimation is effectuated in the baryonic sector to the Fermi surface while in the meson sector to the origin. In writing the kaon-baryon (KN) coupling, we take a generalized hidden local symmetry Lagrangian for the meson sector endowed with a "mended symmetry" that has the unbroken symmetry limit at high density in which the Goldstone π , scalar s , and vectors ρ (and ω ) and a1 become massless. The vector mesons ρ (and ω ) and a1 can be identified as emergent (hidden) local gauge fields and the scalar s as the dilaton field of the spontaneously broken scale invariance at chiral restoration. In matter-free space, when the vector mesons and the scalar meson—whose masses are much greater than that of the pion—are integrated out, then the resulting KN coupling Lagrangian consists of the leading chiral order [O (p1) ] Weinberg-Tomozawa term and the next chiral order [O (p2) ] ΣKN term. In addressing kaon condensation in dense nuclear matter in chiral perturbation theory, one makes an expansion in the "small" Fermi momentum kF. We argue that in the Wilsonian RG formalism with the Fermi-liquid fixed point, the expansion is on the contrary in 1 /kF with the "large" Fermi momentum kF. The kaon-quasinucleon interaction resulting from integrating out the massive mesons consists of a "relevant" term from the scalar exchange (analog to the ΣKN term) and an "irrelevant" term from the vector-meson exchange (analog to the Weinberg-Tomozawa term). It is found that the critical density predicted by the latter approach, controlled by the relevant term with the irrelevant term suppressed, is three times less than that predicted by chiral perturbation theory. This would make kaon condensation take place at a much lower density than previously estimated in chiral perturbation theory.

  3. Condensation coefficient of methanol vapor near vapor-liquid equilibrium states

    NASA Astrophysics Data System (ADS)

    Fujikawa, S.; Yano, T.; Ichijo, M.; Iwanami, K.

    This paper is concerned with the nonequilibrium condensation from a vapor to a liquid phase on the plate endwall of a shock tube behind a reflected shock wave. The growth of a liquid film on the endwall is measured by an optical interferometer using a laser beam. The experiment is carefully conducted on the precisely designed apparatus, and thereby the condensation coefficient of methanol vapor is determined in a wide range of vapor-liquid conditions from near to far from equilibrium states. The result shows that the condensation coefficient increases with the increase of the ratio of number densities of vapor and saturated vapor at the interface.

  4. Buoyancy effects on the vapor condensation rate on a horizontal liquid surface

    NASA Technical Reports Server (NTRS)

    Hasan, Mohammad M.; Lin, Chin-Shun

    1990-01-01

    The results are presented of a numerical study of the effects of buoyancy on the direct condensation of saturated or nearly saturated vapor on a horizontal liquid surface in a cylindrical tank. The liquid motion beneath the liquid-vapor interface is induced by an axisymmetric laminar jet of subcooled liquid. Analysis and numerical results show that the dominant parameter which determines the influence of buoyancy on the condensation rate is the Richardson number. However, the effect of buoyancy on the condensation rate cannot be quantified in terms of the Richardson number alone. The critical value of the Richardson number below which the condensation rate is not significantly reduced depends on the Reynolds number as well as the Prandtl number.

  5. Buoyancy effects on the vapor condensation rate on a horizontal liquid surface

    NASA Technical Reports Server (NTRS)

    Hasan, Mohammad M.; Lin, Chin-Shun

    1989-01-01

    The results are presented of a numerical study of the effects of buoyancy on the direct condensation of saturated or nearly saturated vapor on a horizontal liquid surface in a cylindrical tank. The liquid motion beneath the liquid-vapor interface is induced by an axisymmetric laminar jet of subcooled liquid. Analysis and numerical results show that the dominant parameter which determines the influence of buoyancy on the condensation rate is the Richardson number. However, the effect of buoyancy on the condensation rate cannot be quantified in terms of the Richardson number alone. The critical value of the Richardson number below which the condensation rate is not significantly reduced depends on the Reynolds number as well as the Prandtl number.

  6. Non-equilibrium disordered Bose gases: condensation, superfluidity and dynamical Bose glass

    NASA Astrophysics Data System (ADS)

    Chen, Lei; Liang, Zhaoxin; Hu, Ying; Zhang, Zhidong

    2016-01-01

    In an equilibrium three-dimensional (3D) disordered condensate, it is well established that disorder can generate an amount of normal fluid ρ n equaling to 4/3 of ρ ex , where ρ ex is a sum of interaction-induced quantum depletion and disorder-induced condensate deformation. The concept that the superfluid is more volatile to the existence of disorder than the condensate is crucial to the understanding of the Bose glass phase. In this work, we show that, by bringing a weakly disordered 3D condensate to non-equilibrium regime via a quantum quench in the interaction, disorder can destroy superfluid significantly more, leading to a steady state of Hamiltonian H f in which the ρ n far exceeds 4/3 of the ρ ex . This suggests the possibility of engineering Bose glass in the dynamic regime. Here, we refer to the dynamical Bose glass as the case where in the steady state of quenched condensate, the superfluid density goes to zero while the condensate density remains finite. As both the ρ n and ρ ex are measurable quantities, our results allow an experimental demonstration of the dramatized interplay between the disorder and interaction in the non-equilibrium scenario.

  7. Rate correlation for condensation of pure vapor on turbulent, subcooled liquid

    NASA Technical Reports Server (NTRS)

    Brown, J. Steven; Khoo, Boo Cheong; Sonin, Ain A.

    1990-01-01

    An empirical correlation is presented for the condensation of pure vapor on a subcooled, turbulent liquid with a shear-free interface. The correlation expresses the dependence of the condensation rate on fluid properties, on the liquid-side turbulence (which is imposed from below), and on the effects of buoyancy in the interfacial thermal layer. The correlation is derived from experiments with steam and water, but under conditions which simulate typical cryogenic fluids.

  8. Capillary Condensation of Liquid 4He in Aerogel on Cooling Through {lambda} Point

    SciTech Connect

    Miyashita, W.; Yoneyama, K.; Kato, H.; Nomura, R.; Okuda, Y.

    2006-09-07

    Capillary condensation of liquid 4He in silica aerogel with a 90% porosity was investigated visually. The initial condition of the experiment was such that liquid 4He was present in the sample cell but not in the aerogel. This situation was realized by introducing the liquid into the cell at a fast rate to avoid liquefaction in the aerogel. The free surface of the liquid rose up in the cell with filling and eventually reached the bottom of the aerogel. Then, the aerogel absorbed the liquid by capillary condensation. The height of the liquid in the aerogel rose with time t roughly as t1/2 in the normal fluid phase. This behavior was consistent with the Washburn model. When the system was cooled through the {lambda} point during the condensation, the liquid height started to rise faster in the superfluid phase with a constant velocity of about 0.3 mm/sec. The dynamics of capillary condensation was strongly dependent on whether the liquid 4He was in the normal or the superfluid phase.

  9. Self-Transport of Condensed Liquid in Micro Cooling Device Using Distributed Meniscus Pumping.

    PubMed

    So, Hongyun; Pisano, Albert P

    2015-06-16

    This paper reports a reliable passive micro pump system combining the physical properties of a tapered microchannel and sharp microstructures. This tailored microchannel with triple-spike microstructures was created to transport condensed liquid into the reservoir chamber in a micro cooling device and in the case of chip off-mode prepare the next cooling cycle before chip on-mode, allowing the reliable and continuous circulation of coolant without liquid being trapped in the vapor channel causing dryout limitation. At the tapered channel end, the pinned liquid meniscus was distributed by a middle spike and then continued to overflow into the condenser chamber due to extended capillary action. PMID:26010771

  10. Vapor condensation rate at a turbulent liquid interface, for application to cryogenic hydrogen

    NASA Technical Reports Server (NTRS)

    Helmick, M. R.; Khoo, B. C.; Brown, J. S.; Sonin, A. A.

    1988-01-01

    The condensation of hydrogen vapor onto turbulent liquid hydrogen is simulated experimentally using steam and water at elevated pressure, where water has a Prandtl number comparable to that of liquid hydrogen. A correlation is presented for the condensation rate in terms of the intensity and macroscale of the turbulence on the liquid side. The rate correlation should be applicable to low-gravity conditions at the higher turbulence intensities; at the lower turbulence intensities, however, the data are affected by thermal stratification resulting from buoyancy effects.

  11. Mobile and static molecular disorder in liquids

    NASA Astrophysics Data System (ADS)

    Huyskens, Pierre L.

    1992-11-01

    The fraction of time during which a molecule of a pure alcohol does not undergo H-bonding, estimated from the vapor pressure, is two orders of magnitude larger than the fraction of molecules that at a given time are not bound by an H-bond to their neighbors, as deduced from IR spectroscopic data. This obviously "anti-ergodic" statement renders questionable all the thermodynamic treatments of H-bonding in liquids, which are based on the usual Boltzmann expression. This expression equates the thermodynamic probability of a system with the static probability of distribution of the various states and, as outlined by Einstein, does not hold for non-ergodic systems. As pointed out by Pais (A. Pais, Subtle is the Lord. The Science and the Life of Albert Einstein, Oxford University Press, 1982), another Boltzmann relation relates the thermodynamic probability of a state to the fraction of time during which the system is found in that state. The latter definition was used by Einstein in his treatment of the ergodic problem. Similarly, the theory of the thermodynamics of mobile order in H-bonded liquids, of Huyskens and Siegel (P.L. Huyskens and G.G. Siegel, Bull. Soc. Chim. Belg., 97 (1988) 821), considers not the static configurations of the liquid, but the fraction of time during which an OH proton follows the oxygen atom of one or another neighboring molecules in its motion through the liquid. This coordination lowers the entropy and this reduction can be evaluated quantitatively. The present paper establishes a distinction between the static disorder, which is due to the possibility of exchange between the positions of the molecules and exists in mixed crystals, and the mobile disorder, which is due to the enlargement of the domain available for the motions of a given molecule, provoked by the mixing of two real gases. The mixing of two liquids allows an exchange in the positions, but also an expansion of the individual domains available for the motions. Thus, the

  12. Excitations and Bose-Einstein condensation in liquid 4He

    NASA Astrophysics Data System (ADS)

    Sakhel, A. R.; Glyde, H. R.

    2004-10-01

    We present a model of the dynamic structure factor S(Q,ω) of He4 that reproduces the basic features of the temperature dependence of S(Q,ω) as observed in inelastic-neutron scattering measurements. Wave vectors Q beyond the roton ( Q>2.0Å-1 ) are considered. The model is able to reproduce the decrease in the intensity of the single excitation (phonon-roton) peak in S(Q,ω) with an increase of temperature (T) in the range 0.6⩽T⩽2.1K . All vertices and interactions are assumed temperature independent, and only the condensate fraction n0(T) changes with T . Also, it reproduces a second peak observed at higher energy ( ω ) which represents the single excitation intensity lying in the two excitation band. The model is based on the formulation of S(Q,ω) of Gavoret and Nozières. In this formulation, the dynamic susceptibility, χ , is separated into a singular part involving the condensate and a regular part involving states above the condensate χ=χS+χR' . The weight of the phonon-roton peak in χS is proportional to n0(T) and the phonon-roton peak disappears completely from χ in the normal phase where n0(T)=0 . Using sum rule arguments, the condensate fraction can be estimated from the data giving values in good agreement with accurate measurements at SVP and with Monte Carlo calculations.

  13. Superhydrophobic coated apparatus for liquid purification by evaporative condensation

    DOEpatents

    Simpson, John T; McNeany, Steve R; Dinsmore, Thomas V; Hunter, Scott R; Ivanov, Ilia N

    2014-03-11

    Disclosed are examples of apparatuses for evaporative purification of a contaminated liquid. In each example, there is a first vessel for storing the contaminated fluid. The first vessel includes a surface coated with a layer of superhydrophobic material and the surface is at least partially in contact with the contaminated liquid. The contaminants do not adhere to the surface as the purified liquid evaporates, thus simplifying maintenance of the apparatus.

  14. Routes Towards Anderson-Like Localization of Bose-Einstein Condensates in Disordered Optical Lattices

    NASA Astrophysics Data System (ADS)

    Schulte, T.; Drenkelforth, S.; Kruse, J.; Ertmer, W.; Arlt, J.; Sacha, K.; Zakrzewski, J.; Lewenstein, M.

    2005-10-01

    We investigate, both experimentally and theoretically, possible routes towards Anderson-like localization of Bose-Einstein condensates in disordered potentials. The dependence of this quantum interference effect on the nonlinear interactions and the shape of the disorder potential is investigated. Experiments with an optical lattice and a superimposed disordered potential reveal the lack of Anderson localization. A theoretical analysis shows that this absence is due to the large length scale of the disorder potential as well as its screening by the nonlinear interactions. Further analysis shows that incommensurable superlattices should allow for the observation of the crossover from the nonlinear screening regime to the Anderson localized case within realistic experimental parameters.

  15. Routes Towards Anderson-Like Localization of Bose-Einstein Condensates in Disordered Optical Lattices

    SciTech Connect

    Schulte, T.; Drenkelforth, S.; Kruse, J.; Ertmer, W.; Arlt, J.; Sacha, K.; Zakrzewski, J.; Lewenstein, M.

    2005-10-21

    We investigate, both experimentally and theoretically, possible routes towards Anderson-like localization of Bose-Einstein condensates in disordered potentials. The dependence of this quantum interference effect on the nonlinear interactions and the shape of the disorder potential is investigated. Experiments with an optical lattice and a superimposed disordered potential reveal the lack of Anderson localization. A theoretical analysis shows that this absence is due to the large length scale of the disorder potential as well as its screening by the nonlinear interactions. Further analysis shows that incommensurable superlattices should allow for the observation of the crossover from the nonlinear screening regime to the Anderson localized case within realistic experimental parameters.

  16. Method for analyzing the chemical composition of liquid effluent from a direct contact condenser

    DOEpatents

    Bharathan, Desikan; Parent, Yves; Hassani, A. Vahab

    2001-01-01

    A computational modeling method for predicting the chemical, physical, and thermodynamic performance of a condenser using calculations based on equations of physics for heat, momentum and mass transfer and equations of equilibrium thermodynamics to determine steady state profiles of parameters throughout the condenser. The method includes providing a set of input values relating to a condenser including liquid loading, vapor loading, and geometric characteristics of the contact medium in the condenser. The geometric and packing characteristics of the contact medium include the dimensions and orientation of a channel in the contact medium. The method further includes simulating performance of the condenser using the set of input values to determine a related set of output values such as outlet liquid temperature, outlet flow rates, pressures, and the concentration(s) of one or more dissolved noncondensable gas species in the outlet liquid. The method may also include iteratively performing the above computation steps using a plurality of sets of input values and then determining whether each of the resulting output values and performance profiles satisfies acceptance criteria.

  17. Ultrafast optical pulse interactions in active disordered condensed matter

    NASA Astrophysics Data System (ADS)

    Siddique, Masood

    2005-07-01

    The goal of this research is to better understand the basic physics that governs the behavior of short-pulsed light propagating in scattering media where either the host medium or the scattering particles exhibit emission or absorption interact with the incident light in form of absorption or stimulated emission. The temporal and spectral dynamics from the interactions of optically active disordered-media with ultrashort optical pulses is the focus of the research performed in this thesis. The interaction processes studied are optical gain, spectral narrowing, fluorescence and pulse lifetime reduction and transport of ultrashort optical pulses in disordered media containing optically active discrete scattering particles. Linear and nonlinear effects are presented where the propagation of picosecond and femtosecond laser pulses in active disordered media is measured experimentally and compared with the theories of Boltzmann radiative transport and diffusive propagation of radiation in disordered media. Active media can be involved in optical processes in disordered media where either the propagation of optical radiation can result in gain or absorption upon optical excitation. A study of optical scattering in non-discrete media such as the biological heterogeneously-continuous scattering tissues is carried out as well. Lasing in random media is one of the outcomes of these results. The optical gain of optically excited active media is divided into clear subdivisions of Amplified Spontaneous Emission, Stimulated Emission and Laser Emission by characterizing them by their temporal and spectral emission.

  18. Birefringence and DNA Condensation of Liquid Crystalline Chromosomes ▿

    PubMed Central

    Chow, Man H.; Yan, Kosmo T. H.; Bennett, Michael J.; Wong, Joseph T. Y.

    2010-01-01

    DNA can self-assemble in vitro into several liquid crystalline phases at high concentrations. The largest known genomes are encoded by the cholesteric liquid crystalline chromosomes (LCCs) of the dinoflagellates, a diverse group of protists related to the malarial parasites. Very little is known about how the liquid crystalline packaging strategy is employed to organize these genomes, the largest among living eukaryotes—up to 80 times the size of the human genome. Comparative measurements using a semiautomatic polarizing microscope demonstrated that there is a large variation in the birefringence, an optical property of anisotropic materials, of the chromosomes from different dinoflagellate species, despite their apparently similar ultrastructural patterns of bands and arches. There is a large variation in the chromosomal arrangements in the nuclei and individual karyotypes. Our data suggest that both macroscopic and ultrastructural arrangements affect the apparent birefringence of the liquid crystalline chromosomes. Positive correlations are demonstrated for the first time between the level of absolute retardance and both the DNA content and the observed helical pitch measured from transmission electron microscopy (TEM) photomicrographs. Experiments that induced disassembly of the chromosomes revealed multiple orders of organization in the dinoflagellate chromosomes. With the low protein-to-DNA ratio, we propose that a highly regulated use of entropy-driven force must be involved in the assembly of these LCCs. Knowledge of the mechanism of packaging and arranging these largest known DNAs into different shapes and different formats in the nuclei would be of great value in the use of DNA as nanostructural material. PMID:20400466

  19. Collective oscillations in trapped Bose-Einstein-condensed gases in the presence of weak disorder

    SciTech Connect

    Falco, G. M.; Pelster, A.; Graham, R.

    2007-07-15

    The influence of a weak random potential on the collective modes of a trapped interacting Bose-Einstein condensate at zero temperature is calculated in the limit when the correlation length of the disorder is smaller than the healing length of the superfluid. The problem is solved in the Thomas-Fermi limit by generalizing the superfluid hydrodynamic equations to allow for the presence of weak disorder. We find that the disorder-induced frequency shifts of the low-energy excitations can be of the same order of magnitude as the beyond mean-field corrections in the normal interaction recently observed experimentally.

  20. Bosonic Condensation and Disorder-Induced Localization in a Flat Band

    NASA Astrophysics Data System (ADS)

    Baboux, F.; Ge, L.; Jacqmin, T.; Biondi, M.; Galopin, E.; Lemaître, A.; Le Gratiet, L.; Sagnes, I.; Schmidt, S.; Türeci, H. E.; Amo, A.; Bloch, J.

    2016-02-01

    We report on the engineering of a nondispersive (flat) energy band in a geometrically frustrated lattice of micropillar optical cavities. By taking advantage of the non-Hermitian nature of our system, we achieve bosonic condensation of exciton polaritons into the flat band. Because of the infinite effective mass in such a band, the condensate is highly sensitive to disorder and fragments into localized modes reflecting the elementary eigenstates produced by geometric frustration. This realization offers a novel approach to studying coherent phases of light and matter under the controlled interplay of frustration, interactions, and dissipation.

  1. Disorder-Induced Order in Two-Component Bose-Einstein Condensates

    SciTech Connect

    Niederberger, A.; Schulte, T.; Wehr, J.; Lewenstein, M.; Sanchez-Palencia, L.; Sacha, K.

    2008-01-25

    We propose and analyze a general mechanism of disorder-induced order in two-component Bose-Einstein condensates, analogous to corresponding effects established for XY spin models. We show that a random Raman coupling induces a relative phase of {pi}/2 between the two BECs and that the effect is robust. We demonstrate it in one, two, and three dimensions at T=0 and present evidence that it persists at small T>0. Applications to phase control in ultracold spinor condensates are discussed.

  2. The Stationary Condensation and Radial Outflow of a Liquid Film on a Horizontal Disk

    NASA Technical Reports Server (NTRS)

    Bolshinskiy, Leonid; Frenkel, Alexander

    2008-01-01

    The application of capillary screen liquid acquisition devices to space-based cryogenic propulsion systems is expected to necessitate thermodynamic conditioning in order to stabilize surface tension retention characteristics. The present results have been obtained in the framework of the research of low gravity condensation-flow processes for conditioning cryogenic liquid acquisition devices. The following system is studied: On the top of a subcooled horizontal disk, a liquid film condenses from the ambient saturated vapor. The liquid is forcedly removed at the disk edge, and there is an outward radial flow of the film. Stationary regimes of the flow are uncovered such that (i) the gravity is negligible, being eclipsed by the capillary forces; (ii) the film thickness is everywhere much smaller than the disk radius; and (iii) the slow-flow lubrication approximation is valid. A nonlinear differential equation for the film thickness as a function of the radial coordinate is obtained. The (two-dimensional) fields of velocities, temperature and pressure in the film are explicitly determined by the radial profile of its thickness. The equilibrium is controlled by two parameters: (i) the vapor-disk difference of temperatures and (ii) the liquid exhaust rate. For the flow regimes with a nearly uniform film thickness, the governing equation linearizes, and the film interface is analytically predicted to have a concave-up quartic parabola profile. Thus, perhaps counter-intuitively, the liquid film is thicker at the edge and thinner at the center of the disk.

  3. Molecular evaporation and condensation of liquid [ital n]-alkane films

    SciTech Connect

    Xia, T.K.; Landman, U. )

    1994-08-01

    Energetic, structural, and dynamical properties of solid-to-liquid and liquid-to-vapor interfaces and molecular evaporation and condensation processes from high-temperature liquid [ital n]-C[sub 6]H[sub 14] and [ital n]-C[sub 16]H[sub 34] films were investigated with molecular dynamics simulations. For hexadecane all evaporation events occurred via monomers while for hexane, evaporation of monomers as well as dimers were observed. For both alkane liquids the molecular evaporation mechanism is found to be sequential in nature, starting with an end segment of a molecule leaving the surface and subsequently the evaporation of the molecule occurs via sequential dragging'' of the rest of the molecule. The condensation coefficients of vapor molecules onto the liquid surface are estimated as [similar to]0.9 for hexane and [similar to]1 for hexadecane. Evaporation is accompanied by significant molecular conformational changes. In hot liquid [ital n]-C[sub 16]H[sub 34] the [ital trans] ([ital t]) and [ital gauch] ([ital g][sub +] and [ital g][sub [minus

  4. Reduction in the Vapor Pressure in Condensation on Cold Droplets of a Liquid

    NASA Astrophysics Data System (ADS)

    Bochkareva, E. M.; Nemtsev, V. A.; Sorokin, V. V.; Terekhov, V. V.; Terekhov, V. I.

    2016-06-01

    A physicomathematical model of the process of depressurization in a pure saturated and superheated vapor due to the injection of monodisperse cold droplets of a liquid has been developed. A cellular model has been developed that is based on solving the equation of heat conduction in a liquid phase and on the integral method for a gas phase in a spherically symmetric one-dimensional formulation. Numerical investigation has been carried out of the influence of the size and concentration of the droplets and of the initial parameters of the steam on the dynamics of depressurization during the vapor condensation on the droplets.

  5. Reduction in the Vapor Pressure in Condensation on Cold Droplets of a Liquid

    NASA Astrophysics Data System (ADS)

    Bochkareva, E. M.; Nemtsev, V. A.; Sorokin, V. V.; Terekhov, V. V.; Terekhov, V. I.

    2016-05-01

    A physicomathematical model of the process of depressurization in a pure saturated and superheated vapor due to the injection of monodisperse cold droplets of a liquid has been developed. A cellular model has been developed that is based on solving the equation of heat conduction in a liquid phase and on the integral method for a gas phase in a spherically symmetric one-dimensional formulation. Numerical investigation has been carried out of the influence of the size and concentration of the droplets and of the initial parameters of the steam on the dynamics of depressurization during the vapor condensation on the droplets.

  6. Rapid and Efficient Functionalized Ionic Liquid-Catalyzed Aldol Condensation Reactions Associated with Microwave Irradiation

    PubMed Central

    Wang, Chang; Liu, Jing; Leng, Wenguang; Gao, Yanan

    2014-01-01

    Five quaternary ammonium ionic liquid (IL) and two tetrabutylphosphonium ILs were prepared and characterized. An environmentally benign and convenient functionalized ionic liquid catalytic system was thus explored in the aldol condensation reactions of aromatic aldehydes with acetone. The aldol reactions proceeded more efficiently through microwave-assisted heating than through conventional thermal heating. The yield of products obtained under microwave heating for 30 min was approximately 90%, and the ILs can be recovered and reused at least five times without apparent loss of activity. In addition, this catalytic system can be successfully extended to the Henry reactions. PMID:24445262

  7. Bose Einstein condensation: Its role in the excitations of liquid helium and in trapped Bose gases

    NASA Astrophysics Data System (ADS)

    Sakhel, Asaad R.

    The role of Bose-Einstein condensation (BEC) in determining the properties of Bose systems at ultracold temperatures is investigated. First, we present a model of the dynamic structure factor S(Q,o) of liquid 4He as observed in inelastic neutron scattering measurements beyond the roton (Q ≳ 2.0 A-1). We separate the dynamic susceptibility into chi = chiS + chi'R. chi S involves states in the condensate and chi' R states above the condensate only. We find that the weight of chiS scales with the condensate fraction n0(T) and vanishes at Tlambda. chi' R is broad and largely temperature independent and a low energy intensity broadening arises from the thermal broadening of the phonon-roton (p-r) modes. Secondly, we investigate ultracold Bose gases with repulsive and attractive interactions confined in a spherical harmonic trap over a broad range of densities using model potentials and variational Monte Carlo (VMC) at T = 0 K. In the case of repulsive interactions, the Bosons are represented by hard spheres (HS)s interacting by a HS potential. We change the densities of the Bosons by increasing the s-wave scattering length a. We find that the VMC total and VMC condensate density distributions are similar in shape, they are flat nearly at the higher densities. Further the Thomas-Fermi approximation becomes invalid and the condensate is substantially depleted at the higher densities. In the case of attractive interactions, we model the interactions by a hard core square well (HCSW). We change the densities of these systems by keeping the hard core diameter, a c, fixed and increasing the potential depth V 0 or by increasing both of them simultaneously while keeping a fixed. We find that a Bose gas with attractive interactions undergoes a first order phase transition from the gas to the liquid state at a value of N|a| ≈ 0.574 in agreement with the value predicted by Gross-Pitaevskii (GP) theory. The condensate depletion is mainly driven by the HC diameter in the

  8. The origin of non-porphyritic pyroxene chondrules in UOCs: Liquid solar nebula condensates?

    NASA Astrophysics Data System (ADS)

    Engler, Almut; Varela, Maria Eugenia; Kurat, Gero; Ebel, Denton; Sylvester, Paul

    2007-12-01

    A total of 56 non-porphyritic pyroxene and pyroxene/olivine micro-objects from different unequilibrated ordinary chondrites were selected for detailed studies to test the existing formation models. Our studies imply that the non-porphyritic objects represent quickly quenched liquids with each object reflecting a very complex and unique evolutionary history. Bulk major element analyses, obtained with EMPA and ASEM, as well as bulk lithophile trace element analyses, determined by LA-ICP-MS, resulted in unfractionated (solar-like) ratios of CaO/Al 2O 3, Yb/Ce as well as Sc/Yb in many of the studied objects and mostly unfractionated refractory lithophile trace element (RLTE) abundance patterns. These features support an origin by direct condensation from a gas of solar nebula composition. Full equilibrium condensation calculations show that it is theoretically possible that pyroxene-dominated non-porphyritic chondrules with flat REE patterns could have been formed as droplet liquid condensates directly from a nebular gas strongly depleted in olivine. Thus, it is possible to have enstatite as the stable liquidus phase in a 800 × Cl dust-enriched nebular gas at a p of 10 -3 atm, if about 72% of the original Mg is removed (as forsterite?) from the system. Condensation of liquids from vapor (primary liquid condensation) could be considered as a possible formation process of the pyroxene-dominated non-porphyritic objects. This process can produce a large spectrum of chemical compositions, which always have unfractionated RLTE abundances. Late stage and subsolidus metasomatic events appear to have furthered the compositional diversity of chondrules and related objects by addition of moderately volatile and volatile elements to these objects by exchange reactions with the chondritic reservoir (e.g., V, Cr, Mn, FeO as well as K and Na). The strong fractionation displayed by the volatile lithophile elements could be indicative of a variable efficiency of metasomatic processes

  9. WARM-LIQUID DEFROST FOR COMMERCIAL FOOD DISPLAY CASES: EXPERIMENTAL INVESTIGATION AT 32.2 DEGREES C CONDENSING

    EPA Science Inventory

    The paper gives results of an experimental investigation at 32.2 C condensing of warm-liquid defrost for commercial food display cases. A refrigeration test rig with two open cases and two reach-in cases was tested using warm-liquid defrost (WLD) at -34.4 C evaporating, 32.2 C co...

  10. Disoriented chiral condensates, pion probability distributions, and parallels with disordered systems

    SciTech Connect

    Mekjian, A. Z.

    1999-12-01

    A general expression is discussed for pion probability distributions coming from relativistic heavy ion collisions. The general expression contains as limits (1) the disoriented chiral condensate (DCC), (2) the negative binomial distribution and Pearson type-III distribution, (3) a binomial or Gaussian result, and (4) a Poisson distribution. This general expression approximates other distributions such as a signal-to-noise laser distribution. Similarities and differences of the DCC distribution with these other distributions are studied. A connection with the theory of disordered systems will be discussed which includes spin glasses, randomly broken objects, and random and chaotic maps. (c) 1999 The American Physical Society.

  11. Investigations on the liquid crystalline phases of cation-induced condensed DNA

    NASA Astrophysics Data System (ADS)

    Pillai, C. K. S.; Sundaresan, Neethu; Radhakrishnan Pillai, M.; Thomas, T.; Thomas, T. J.

    2005-10-01

    Viral and nonviral condensing agents are used in gene therapy to compact oligonucleotides and plasmid DNA into nanostructures for their efficient transport through the cell membranes. Whereas viral vectors are best by the toxic effects on the immune system, most of the nonviral delivery vehicles are not effective for use in clinical system. Recent investigations indicate that the supramolecular organization of DNA in the condensed state is liquid crystalline. The present level of understanding of the liquid crystalline phase of DNA is inadequate and a thorough investigation is required to understand the nature, stability, texture and the influence of various environmental conditions on the structure of the phase. The present study is mainly concerned with the physico-chemical investigations on the liquid crystalline transitions during compaction of DNA by cationic species such as polyamines and metallic cations. As a preliminary to the above investigation, studies were conducted on the evolution of mesophase transitions of DNA with various cationic counterion species using polarized light microscopy. These studies indicated significant variations in the phase behaviour of DNA in the presence of Li and other ions. Apart from the neutralization of the charges on the DNA molecule, these ions are found to influence selectively the hydration sphere of DNA that in turn influences the induction and stabilization of the LC phases. The higher stability observed with the liquid crystalline phases of Li--DNA system could be useful in the production of nanostructured DNA. In the case of the polyamine, a structural specificity effect depending on the nature, charge and structure of the polyamine used has been found to be favoured in the crystallization of DNA.

  12. Linear Spatial Evolution Formulation of Two-Dimensional Waves on Liquid Films Under Evaporating/Isothermal/Condensing Conditions

    SciTech Connect

    Xuemin Ye; Chunxi Li; Weiping Yan

    2002-07-01

    The linear spatial evolution formulation of the two-dimensional waves of the evaporating or isothermal or condensing liquid films falling down an inclined wall is established for the film thickness with the collocation method based on the boundary layer theory and complete boundary conditions. The evolution equation indicates that there are two different modes of waves in spatial evolution. And the flow stability is highly dependent on the evaporation or condensation, thermo-capillarity, surface tension, inclination angle and Reynolds number. (authors)

  13. Phase diagram of a spinor exciton-polariton condensate in a disordered microcavity in the presence of a magnetic field

    SciTech Connect

    Solnyshkov, D. D.; Malpuech, G.; Shelykh, I. A.

    2009-10-15

    We establish a phase diagram of a spinor exciton-polariton condensate in a disordered microcavity in the presence of an external magnetic field. We find that the combination of the full paramagnetic screening and Anderson localization leads to the formation of a condensed phase having both localized and superfluid components. This is reflected by different dispersions of elementary excitations for the two polarization components.

  14. Structural disorder in metallic glass-forming liquids

    NASA Astrophysics Data System (ADS)

    Pan, Shao-Peng; Feng, Shi-Dong; Wang, Li-Min; Qiao, Jun-Wei; Niu, Xiao-Feng; Dong, Bang-Shao; Wang, Wei-Min; Qin, Jing-Yu

    2016-06-01

    We investigated structural disorder by a new structural parameter, quasi-nearest atom (QNA), in atomistic configurations of eight metallic glass-forming systems generated through molecular dynamics simulations at various temperatures. Structural analysis reveals that the scaled distribution of the number of QNA appears to be an universal property of metallic liquids and the spatial distribution of the number of QNA displays to be clearly heterogeneous. Furthermore, the new parameter can be directly correlated with potential energy and structural relaxation at the atomic level. Some straightforward relationships between QNA and other properties (per-atom potential energy and α-relaxation time) are introduced to reflect structure-property relationship in metallic liquids. We believe that the new structural parameter can well reflect structure disorder in metallic liquids and play an important role in understanding various properties in metallic liquids.

  15. Structural disorder in metallic glass-forming liquids

    PubMed Central

    Pan, Shao-Peng; Feng, Shi-Dong; Wang, Li-Min; Qiao, Jun-Wei; Niu, Xiao-Feng; Dong, Bang-Shao; Wang, Wei-Min; Qin, Jing-Yu

    2016-01-01

    We investigated structural disorder by a new structural parameter, quasi-nearest atom (QNA), in atomistic configurations of eight metallic glass-forming systems generated through molecular dynamics simulations at various temperatures. Structural analysis reveals that the scaled distribution of the number of QNA appears to be an universal property of metallic liquids and the spatial distribution of the number of QNA displays to be clearly heterogeneous. Furthermore, the new parameter can be directly correlated with potential energy and structural relaxation at the atomic level. Some straightforward relationships between QNA and other properties (per-atom potential energy and α-relaxation time) are introduced to reflect structure-property relationship in metallic liquids. We believe that the new structural parameter can well reflect structure disorder in metallic liquids and play an important role in understanding various properties in metallic liquids. PMID:27278113

  16. Structural disorder in metallic glass-forming liquids.

    PubMed

    Pan, Shao-Peng; Feng, Shi-Dong; Wang, Li-Min; Qiao, Jun-Wei; Niu, Xiao-Feng; Dong, Bang-Shao; Wang, Wei-Min; Qin, Jing-Yu

    2016-01-01

    We investigated structural disorder by a new structural parameter, quasi-nearest atom (QNA), in atomistic configurations of eight metallic glass-forming systems generated through molecular dynamics simulations at various temperatures. Structural analysis reveals that the scaled distribution of the number of QNA appears to be an universal property of metallic liquids and the spatial distribution of the number of QNA displays to be clearly heterogeneous. Furthermore, the new parameter can be directly correlated with potential energy and structural relaxation at the atomic level. Some straightforward relationships between QNA and other properties (per-atom potential energy and α-relaxation time) are introduced to reflect structure-property relationship in metallic liquids. We believe that the new structural parameter can well reflect structure disorder in metallic liquids and play an important role in understanding various properties in metallic liquids. PMID:27278113

  17. Melting of Vortex Lattice in Bose-Einstein Condensate in Presence of Disorder

    NASA Astrophysics Data System (ADS)

    Dey, Bishwajyoti

    We study the vortex lattice dynamics in Bose-Einstein condensate (BEC) in presence of single impurity as well as random impurities or disorder. The single impurity is modeled by a Gaussian function while disorder is introduced in the system by a uniform random potential. Such potentials can be created experimentally by lasers. We solve the time-dependent Gross-Pitaevskii equation in two-dimensions using split-step Crank-Nicolson method. We first show that a single vortex can be pinned by an impurity. We then show that even a single impurity can distort the vortex lattice. For sufficiently strong impurity potential, the vortex lattice gets pinned to the impurity. We also show that a new type of giant hole with hidden vortices inside it can be created in the vortex lattice by a cluster of impurities. In presence of random impurity potential or disorder, the vortices get pinned at random positions leading to melting of the vortex lattice. We further show that the vortex lattice melting can also be induced by the pseudorandom potential generated by the superposition of two optical lattices. The absence of long-range order in the melted vortex lattice is demonstrated from the structure factor profile and the histogram of the distance between each pair of vortices. I would like to thank DST, India and BCUD SPPU, for financial assisance through research grants.

  18. Self-assembly, Condensation, and Order in Aqueous Lyotropic Chromonic Liquid Crystals Crowded with Additives

    SciTech Connect

    Tortora, L.; Park, H; Kang, S; Savaryn, V; Hong, S; Kaznatcheev, K; Finotello, D; Sprunt, S; Kumar, S; Lavrentovich, O

    2010-01-01

    Dense multicomponent systems with macromolecules and small solutes attract a broad research interest as they mimic the molecularly crowded cellular interiors. The additives can condense and align the macromolecules, but they do not change the degree of covalent polymerization. We chose a lyotropic chromonic liquid crystal with reversibly and non-covalently assembled aggregates as a much softer system, reminiscent of 'living polymers', to demonstrate that small neutral and charged additives cause condensation of aggregates with ensuing orientational and positional ordering and nontrivial morphologies of phase separation, such as tactoids and toroids of the nematic and hexagonal columnar phase coexisting with the isotropic melt. Scanning transmission X-ray microscopy (STXM) with near edge X-ray absorption fine structure (NEXAFS) analysis as well as fluorescent microscopy demonstrates segregation of the components. The observations suggest that self-assembly of chromonic aggregates in the presence of additives is controlled by both entropy effects and by specific molecular interactions and provide a new route to the regulated reversible assembly of soft materials formed by low-molecular weight components.

  19. Self-assembly, condensation, and order in aqueous lyotropic chromonic liquid crystals crowded with additives

    SciTech Connect

    Tortora, Luana; Park, Heung-Shik; Kang, Shin-Woong; Savaryn, Victoria; Hong, Seung-Ho; Kaznatcheev, Konstantine; Finotello, Daniele; Sprunt, Samuel; Kumar, Satyendra; Lavrentovich, Oleg D.

    2012-09-06

    Dense multicomponent systems with macromolecules and small solutes attract a broad research interest as they mimic the molecularly crowded cellular interiors. The additives can condense and align the macromolecules, but they do not change the degree of covalent polymerization. We chose a lyotropic chromonic liquid crystal with reversibly and non-covalently assembled aggregates as a much softer system, reminiscent of 'living polymers', to demonstrate that small neutral and charged additives cause condensation of aggregates with ensuing orientational and positional ordering and nontrivial morphologies of phase separation, such as tactoids and toroids of the nematic and hexagonal columnar phase coexisting with the isotropic melt. Scanning transmission X-ray microscopy (STXM) with near edge X-ray absorption fine structure (NEXAFS) analysis as well as fluorescent microscopy demonstrates segregation of the components. The observations suggest that self-assembly of chromonic aggregates in the presence of additives is controlled by both entropy effects and by specific molecular interactions and provide a new route to the regulated reversible assembly of soft materials formed by low-molecular weight components.

  20. Controlling Gaussian and mean curvatures at microscale by sublimation and condensation of smectic liquid crystals

    NASA Astrophysics Data System (ADS)

    Kim, Dae Seok; Cha, Yun Jeong; Kim, Mun Ho; Lavrentovich, Oleg D.; Yoon, Dong Ki

    2016-01-01

    Soft materials with layered structure such as membranes, block copolymers and smectics exhibit intriguing morphologies with nontrivial curvatures. Here, we report restructuring the Gaussian and mean curvatures of smectic A films with free surface in the process of sintering, that is, reshaping at elevated temperatures. The pattern of alternating patches of negative, zero and positive mean curvature of the air-smectic interface has a profound effect on the rate of sublimation. As a result of sublimation, condensation and restructuring, initially equilibrium smectic films with negative and zero Gaussian curvature are transformed into structures with pronounced positive Gaussian curvature of layers packing, which are rare in the samples obtained by cooling from the isotropic melt. The observed relationship between the curvatures, bulk elastic behaviour and interfacial geometries in sintering of smectic liquid crystals might pave the way for new approaches to control soft morphologies at micron and submicron scales.

  1. Controlling Gaussian and mean curvatures at microscale by sublimation and condensation of smectic liquid crystals

    PubMed Central

    Kim, Dae Seok; Cha, Yun Jeong; Kim, Mun Ho; Lavrentovich, Oleg D.; Yoon, Dong Ki

    2016-01-01

    Soft materials with layered structure such as membranes, block copolymers and smectics exhibit intriguing morphologies with nontrivial curvatures. Here, we report restructuring the Gaussian and mean curvatures of smectic A films with free surface in the process of sintering, that is, reshaping at elevated temperatures. The pattern of alternating patches of negative, zero and positive mean curvature of the air–smectic interface has a profound effect on the rate of sublimation. As a result of sublimation, condensation and restructuring, initially equilibrium smectic films with negative and zero Gaussian curvature are transformed into structures with pronounced positive Gaussian curvature of layers packing, which are rare in the samples obtained by cooling from the isotropic melt. The observed relationship between the curvatures, bulk elastic behaviour and interfacial geometries in sintering of smectic liquid crystals might pave the way for new approaches to control soft morphologies at micron and submicron scales. PMID:26725975

  2. An order-by-disorder process in the cyclic phase of spin-2 condensate with a weak magnetic field

    SciTech Connect

    Zheng, Gong-Ping; Xu, Lei-Kuan; Qin, Shuai-Feng; Jian, Wen-Tian; Liang, J.-Q.

    2013-07-15

    We present in this paper a model study on the “order-by-disorder” process in the cyclic phase of spin-2 condensate, which forms a family of incommensurable, spiral degenerate ground states. On the basis of the ordering mechanism of entropic splitting, it is demonstrated that the energy corrections resulting from quantum fluctuations of disorder lift the accidental degeneracy of the cyclic configurations and thus lead to an eventual spiral order called the cyclic order. The order-by-disorder phenomenon is then realized even if the magnetic field exists. Finally, we show that our theoretic observations can be verified experimentally by direct detection of the cyclic order in the {sup 87}Rb condensate of a spin-2 manifold with a weak magnetic field. -- Highlights: •A model for the order-by-disorder process in the cyclic phase of spin-2 condensate is presented. •The second-order quantum fluctuations of the mean-field states are studied. •The energy corrections lift the accidental degeneracy of the cyclic configurations. •The order-by-disorder phenomenon is realized even if a magnetic field exists. •The theoretic observations can be verified experimentally for {sup 87}Rb condensate.

  3. Reversible Carbene Formation in the Ionic Liquid 1-Ethyl-3-Methylimidazolium Acetate by Vaporization and Condensation.

    PubMed

    Kar, Bishnu Prasad; Sander, Wolfram

    2015-12-01

    The role of N-heterocyclic carbenes in the chemistry of ionic liquids based on imidazolium salts has long been discussed. Here, we present experimental evidence that 1-ethyl-3-methylimidazolium-2-ylidene (EMIm) can coexist with its protonated imidazolium cation (EMImH(+) ) at low temperatures. If the vapor of the ionic liquid [EMImH(+) ][AcO(-) ] is trapped in solid argon or nitrogen at 9 K, only acetic acid (AcOH) and the carbene, but no ionic species, are found by IR spectroscopy. This indicates that during the evaporation of [EMImH(+) ][AcO(-) ] proton transfer occurs to form the neutral species. If the vapor of [EMImH(+) ][AcO(-) ] is trapped at 9 K as film in the absence of a host matrix, a solid consisting of EMImH(+) , EMIm, AcO(-) , and AcOH is formed. During warming to room temperature the proton transfer in the solid to form back the IL [EMImH(+) ][AcO(-) ] can be monitored by IR spectroscopy. This clearly demonstrates that evaporation and condensation of the IL [EMImH(+) ][AcO(-) ] results in a double proton transfer, and the carbene EMIm is only metastable even at low temperatures. PMID:26376583

  4. Interfacial instability of a condensing vapor bubble in a subcooled liquid

    NASA Astrophysics Data System (ADS)

    Ueno, I.; Ando, J.; Koiwa, Y.; Saiki, T.; Kaneko, T.

    2015-03-01

    A special attention is paid to the condensing and collapsing processes of vapor bubble injected into a subcooled pool. We try to extract the vapor-liquid interaction by employing a vapor generator that supplies vapor to the subcooled pool through an orifice instead of using a immersed heating surface to realize vapor bubbles by boiling phenomenon. This system enables ones to detect a spatio-temporal behavior of a single bubble of superheated vapor exposed to a subcooled liquid. In the present study, vapor of water is injected through an orifice at constant flow rate to the subcooled pool of water at the designated degree of subcooling under the atmospheric pressure. The degree of subcooling of the pool is ranged from 0 K to 70 K, and the vapor temperature is kept constant at 101 ∘C. The behaviors of the injected vapor are captured by high-speed camera at frame rate up to 0.3 million frame per second (fps) to track the temporal variation of the vapor bubble shape. It is found that the abrupt collapse of the vapor bubble exposed to the subcooled pool takes place under the condition that the degree of subcooling is greater than around 30 K, and that the abrupt collapse always takes place accompanying the fine disturbances or instability emerged on the free surface. We then evaluate a temporal variation of the apparent `volume' of the bubble V under the assumption of the axisymmetric shape of the vapor bubble. It is also found that the instability emerges slightly after the volume of the vapor bubble reaches the maximum value. It is evaluated that the second derivative of the corresponding `radius' R of the vapor bubble is negative when the instability appears on the bubble surface, where R = 3√ 3V/4π. We also illustrate that the wave number of the instability on the liquid-vapor interface increases as the degree of subcooling.

  5. Orientational Phase Ordering in Disordered Liquid Crystalline Heteropolymers

    NASA Astrophysics Data System (ADS)

    Gutman, Lorin; Shakhnovich, Eugene I.

    2000-03-01

    Liquid-crystalline disordered heteropolymers (DLCPs) are studied by a novel creation-annihilation method and replica field theory. The 0 disorder limit of theory is the non-perturbative (A. M. Gupta and S. F. Edwards J. Chem. Phys., 98, 1588, (1993)) result for long homopolymer chains. Sequence disorder, alignment propensity, stiffness and lyotropic effects on orientational phase ordering and coexistence width are studied numerically by unconstrained iteration of principal axis of segment orientational tensors; It is shown that sequence heterogeneity impacts strongly the density order/disorder threshold and the Maxwell construction shows a three fold increase in coexistence width compared with the homopolymer analogue. The non-equilibrium meta-stable domain scale, obtained by calculation of Doring free energy from field theory and nucleation theory is of the order of μ m, in agreement with recent experiments on DLCPs.

  6. Orientational and Domain Ordering in Disordered Liquid Crystalline Heteropolymers

    NASA Astrophysics Data System (ADS)

    Gutman, Lorin; Shakhnovich, Eugene

    2001-03-01

    Liquid-crystalline disordered heteropolymers (DLCPs) are studied by a novel creation-annihilation method and replica field theory. The 0 disorder limit of theory is the non-perturbative (A. M. Gupta and S. F. Edwards J. Chem. Phys., 98, 1588, (1993)) result for long homopolymer chains. Sequence disorder, alignment propensity, stiffness and lyotropic effects on orientational phase ordering and coexistence width are studied numerically by unconstrained iteration of principal axis of segment orientational tensors; It is shown that sequence heterogeneity impacts strongly the density order/disorder threshold and the Maxwell construction shows a three fold increase in coexistence width compared with the homopolymer analogue. The non-equilibrium meta-stable domain scale, obtained by calculation of Doring free energy from field theory and nucleation theory is of the order of μ m, in agreement with recent experiments on DLCPs.

  7. An order-by-disorder process in the cyclic phase of spin-2 condensate with a weak magnetic field

    NASA Astrophysics Data System (ADS)

    Zheng, Gong-Ping; Xu, Lei-Kuan; Qin, Shuai-Feng; Jian, Wen-Tian; Liang, J.-Q.

    2013-07-01

    We present in this paper a model study on the "order-by-disorder" process in the cyclic phase of spin-2 condensate, which forms a family of incommensurable, spiral degenerate ground states. On the basis of the ordering mechanism of entropic splitting, it is demonstrated that the energy corrections resulting from quantum fluctuations of disorder lift the accidental degeneracy of the cyclic configurations and thus lead to an eventual spiral order called the cyclic order. The order-by-disorder phenomenon is then realized even if the magnetic field exists. Finally, we show that our theoretic observations can be verified experimentally by direct detection of the cyclic order in the 87Rb condensate of a spin-2 manifold with a weak magnetic field.

  8. Numerical analysis of kinetic boundary conditions at net evaporation/condensation interfaces in various liquid temperatures based on mean-field kinetic theory

    NASA Astrophysics Data System (ADS)

    Kon, Misaki; Kobayashi, Kazumichi; Watanabe, Masao

    2014-12-01

    This study aims to investigate the liquid temperature dependency of the kinetic boundary condition at a vapor-liquid interface in net evaporation/condensation. The numerical simulations based on the mean-field kinetic theory and the molecular gas dynamics in the cases of various liquid temperatures were carried out. We focused on two important issues for the kinetic boundary condition; one is to investigate the applicable limit of the kinetic boundary condition which is assumed to be the isotropic velocity distribution at the liquid temperature and the other is to estimate the value of the condensation coefficient included in the kinetic boundary condition. The simulation results showed that the applicable limit of the isotropic velocity distribution in net evaporation/condensation practically independent from the liquid temperature. Furthermore, the condensation coefficients in net evaporation/condensation depend significantly on the liquid temperature; the condensation coefficient is constant and equal to the evaporation coefficient in net evaporation, while, in net condensation, the condensation coefficient increases with the increase of the degree of nonequilibrium.

  9. Short-pulse laser interactions with disordered materials and liquids

    SciTech Connect

    Phinney, L.M.; Goldman, C.H.; Longtin, J.P.; Tien, C.L.

    1995-12-31

    High-power, short-pulse lasers in the picosecond and subpicosecond range are utilized in an increasing number of technologies, including materials processing and diagnostics, micro-electronics and devices, and medicine. In these applications, the short-pulse radiation interacts with a wide range of media encompassing disordered materials and liquids. Examples of disordered materials include porous media, polymers, organic tissues, and amorphous forms of silicon, silicon nitride, and silicon dioxide. In order to accurately model, efficiently control, and optimize short-pulse, laser-material interactions, a thorough understanding of the energy transport mechanisms is necessary. Thus, fractals and percolation theory are used to analyze the anomalous diffusion regime in random media. In liquids, the thermal aspects of saturable and multiphoton absorption are examined. Finally, a novel application of short-pulse laser radiation to reduce surface adhesion forces in microstructures through short-pulse laser-induced water desorption is presented.

  10. Topological defects as relics of emergent continuous symmetry and Higgs condensation of disorder in ferroelectrics

    NASA Astrophysics Data System (ADS)

    Lin, Shi-Zeng; Wang, Xueyun; Kamiya, Yoshitomo; Chern, Gia-Wei; Fan, Fei; Fan, David; Casas, Brian; Liu, Yue; Kiryukhin, Valery; Zurek, Wojciech H.; Batista, Cristian D.; Cheong, Sang-Wook

    2014-12-01

    Lars Onsager and Richard Feynman envisaged that the three-dimensional (3D) superfluid-to-normal λ transition in 4He occurs through the proliferation of vortices. This process should hold for every phase transition in the same universality class. The role of topological defects in symmetry-breaking phase transitions has become a prime topic in cosmology and high-temperature superconductivity, even though direct imaging of these defects is challenging. Here we show that the U(1) continuous symmetry that emerges at the ferroelectric critical point of multiferroic hexagonal manganites leads to a similar proliferation of vortices. Moreover, the disorder field (vortices) is coupled to an emergent U(1) gauge field, which becomes massive by means of the Higgs mechanism when vortices condense (span the whole system) on heating above the ferroelectric transition temperature. Direct imaging of the vortex network in hexagonal manganites offers unique experimental access to this dual description of the ferroelectric transition, while enabling tests of the Kibble-Zurek mechanism.

  11. Condensed-matter ab initio approach for strongly correlated electrons: Application to a quantum spin liquid candidate

    SciTech Connect

    Yamaji, Youhei

    2015-12-31

    Recently, condensed-matter ab initio approaches to strongly correlated electrons confined in crystalline solids have been developed and applied to transition-metal oxides and molecular conductors. In this paper, an ab initio scheme based on constrained random phase approximations and localized Wannier orbitals is applied to a spin liquid candidate Na{sub 2}IrO{sub 3} and is shown to reproduce experimentally observed specific heat.

  12. End-to-end stacking and liquid crystal condensation of 6- to 20-base pair DNA duplexes.

    SciTech Connect

    Nakata, M.; Zanchetta, G.; Chapman, B.D.; Christopher, D.; Jones, D.; Cross, J.O.; Pindak, R.; Bellini, T.; Noel, N.; X-Ray Science Division; Univ. of Colorado; Univ. di Milano; BNL

    2007-11-23

    Short complementary B-form DNA oligomers, 6 to 20 base pairs in length, are found to exhibit nematic and columnar liquid crystal phases, even though such duplexes lack the shape anisotropy required for liquid crystal ordering. Structural study shows that these phases are produced by the end-to-end adhesion and consequent stacking of the duplex oligomers into polydisperse anisotropic rod-shaped aggregates, which can order into liquid crystals. Upon cooling mixed solutions of short DNA oligomers, in which only a small fraction of the DNA present is complementary, the duplex-forming oligomers phase-separate into liquid crystal droplets, leaving the unpaired single strands in isotropic solution. In a chemical environment where oligomer ligation is possible, such ordering and condensation would provide an autocatalytic link whereby complementarity promotes the extended polymerization of complementary oligomers.

  13. Theory of thermal conductivity in the disordered electron liquid

    NASA Astrophysics Data System (ADS)

    Schwiete, G.; Finkel'stein, A. M.

    2016-03-01

    We study thermal conductivity in the disordered two-dimensional electron liquid in the presence of long-range Coulomb interactions. We describe a microscopic analysis of the problem using the partition function defined on the Keldysh contour as a starting point. We extend the renormalization group (RG) analysis developed for thermal transport in the disordered Fermi liquid and include scattering processes induced by the long-range Coulomb interaction in the sub-temperature energy range. For the thermal conductivity, unlike for the electrical conductivity, these scattering processes yield a logarithmic correction that may compete with the RG corrections. The interest in this correction arises from the fact that it violates the Wiedemann-Franz law. We checked that the sub-temperature correction to the thermal conductivity is not modified either by the inclusion of Fermi liquid interaction amplitudes or as a result of the RG flow. We therefore expect that the answer obtained for this correction is final. We use the theory to describe thermal transport on the metallic side of the metal-insulator transition in Si MOSFETs.

  14. Occurrence and solid-liquid partition of sulfonated naphthalene-formaldehyde condensates in the aquatic environment.

    PubMed

    Lange, Frank T; Merklinger, Michael; Wenz, Michael; Brauch, Heinz-J; Lehmann, Markus; Pinter, Istvan

    2005-03-15

    Sulfonated naphthalene-formaldehyde condensates (SNFC) are high production volume chemicals used in a variety of applications, for example, as concrete plasticizers, tanning agents, or dye dispersants. They enter the aquatic environment primarily by the wastewater path. The occurrence and fate of the monomers, which are different isomers of mono- and disulfonated naphthalene, was intensively investigated in previous studies. However, the environmental fate of the persistent higher molecular SNFC is so far widely unknown. This paper describes an ultrasonic extraction under alkaline conditions, followed by ion-pair HPLC with fluorescence detection for the analysis of SNFC oligomers from solid environmental matrixes such as sewage sludge, suspended solids, and river sediments. Limits of quantification of about 0.1 mg kg-1 d.m. were well below the measured concentrations in environmental samples. SNFC were adsorbed to suspended solids and river sediments in three major German rivers (Rhine, Neckar, and Danube) in concentrations typically up to several mg kg(-1) d.m. A total content of about 4 g kg(-1) d.m. was measured in a sewage sludge of a municipal wastewater treatment plant, which receives wastewater from a textile dyeing plant. Furthermore, the first quantitative field data on the partition of SNFC and their monomers between the aqueous phase and solid environmental compartments are presented. Solid-liquid partition coefficients (Kd) of oligomers with a chain-length ranging from three to six naphthalenesulfonate units were derived from the analysis of corresponding wastewater and sewage sludge samples and from suspended solids and river water samples, respectively. Determined Kd values were in the range from 10(2) to 10(4) L kg(-1). PMID:15819205

  15. Superfluidity, Bose condensation and neutron scattering in liquid {sup 4}He

    SciTech Connect

    Silver, R.N.

    1997-04-01

    The relation between superfluidity and Bose condensation in {sup 4}He provides lessons that may be valuable in understanding the strongly correlated electron system of high {Tc} superconductivity. Direct observation of a Bose condensate in the superfluid by deep inelastic neutron scattering measurements has been attempted over many years. But the impulse approximation, which relates momentum distributions to neutron scattering structure functions, is broadened by final state effects. Nevertheless, the excellent quantitative agreement between ab initio quantum many body theory and high precision neutron experiments provides confidence in the connection between superfluidity and Bose condensation.

  16. Theory of fermion condensation as an analog of the liquid-drop theory of atomic nuclei

    SciTech Connect

    Khodel, V. A.

    2015-01-15

    We discuss problems of theory of systems with a fermion condensate or, in different words, systems with flat bands pinned to the Fermi surface, employing the duality of the momentum distribution n(p) and the density distribution ρ(r). We propose that the Lifshitz topological phase transition associated with the formation of additional pockets of the Fermi surface is the precursor of fermion condensation.

  17. Gramicidin Alters the Lipid Compositions of Liquid-Ordered and Liquid-Disordered Membrane Domains

    NASA Astrophysics Data System (ADS)

    Hassan-Zadeh, Ebrahim; Huang, Juyang

    2012-10-01

    The effects of adding 1 mol % of gramicidin A to the well-known DOPC/DSPC/cholesterol lipid mixtures were investigated. 4-component giant unilamellar vesicles (GUV) were prepared using our recently developed Wet-Film method. The phase boundary of liquid-ordered and liquid-disordered (Lo-Ld) coexisting region was determined using video fluorescence microscopy. We found that if cares were not taken, light-induced domain artifacts could significantly distort the measured phase boundary. After testing several fluorescence dyes, we found that the emission spectrum of Nile Red is quite sensitive to membrane composition. By fitting the Nile Red emission spectra at the phase boundary to the spectra in the Lo-Ld coexisting region, the thermodynamic tie-lines were determined. As an active component of lipid membranes, gramicidin not only partitions favorably into the liquid-disordered (Ld) phase, it also alters the phase boundary and thermodynamic tie-lines. Even at as low as 1 mol %, gramicidin decreases the cholesterol mole fraction of Ld phase and increases the area of Lo phase.

  18. Effects of Evaporation/Condensation on Spreading and Contact Angle of a Volatile Liquid Drop

    NASA Technical Reports Server (NTRS)

    Zhang, Nengli; Chao, David F.; Singh, Bhim S. (Technical Monitor)

    2000-01-01

    Effects of evaporation/condensation on spreading and contact angle were experimentally studied. A sessile drop of R-113 was tested at different vapor environments to determine the effects of evaporation/condensation on the evolution of contact diameter and contact angle of the drop. Condensation on the drop surface occurs at both the saturated and a nonsaturated vapor environments and promotes the spreading. When the drop is placed in the saturated vapor environment it tends to completely wetting and spreads rapidly. In a nonsaturated vapor environment, the evolution of the sessile drop is divided three stages: condensation-spreading stage, evaporation-retracting stage and rapid contracting stage. In the first stage the drop behaves as in the saturated environment. In the evaporation -retracting stage, the competition between spreading and evaporation of the drop determines the evolution characteristics of the contact diameter and the contact angle. A lower evaporation rate struggles against the spreading power to turn the drop from spreading to retracting with a continuous increase of the contact angle. The drop placed in open air has a much higher evaporation rate. The strong evaporation suppresses the spreading and accelerates the retraction of the drop with a linear decrease of the contact diameter. The contraction of the evaporating drops is gradually accelerated when the contact diameter decreases to 3 min and less till drying up, though the evaporation rate is gradually slowing down.

  19. Successive disorder to disorder phase transitions in ionic liquid [HMIM][BF4] under high pressure

    NASA Astrophysics Data System (ADS)

    Zhu, Xiang; Yuan, Chaosheng; Li, Haining; Zhu, Pinwen; Su, Lei; Yang, Kun; Wu, Jie; Yang, Guoqiang; Liu, Jing

    2016-02-01

    In situ high-pressure Raman spectroscopy and synchrotron X-ray diffraction have been employed to investigate the phase behavior of ionic liquid, 1-hexyl-3-methylimidazolium tetrafluoroborate ([HMIM][BF4]) under high pressure up to 20 GPa at room temperature. With increasing pressure, some characteristic bands of [HMIM][BF4] disappear, and some characteristic bands of [HMIM][BF4] display non-monotonic pressure-induced frequency shift and non-monotonic variation of full width at half-maximum. Two successive phase transitions at ∼1.7 GPa and 7.3 GPa have been corroborated by the results above. The glass transition pressure (Pg) of [HMIM][BF4] at ∼7.3 GPa has been obtained by ruby R1 line broadening measurements and analysis of synchrotron X-ray diffraction patterns, and its glass transition mechanism is also analyzed in detail. These facts are suggestive of two successive disorder to disorder phase transitions induced by compression, that is, [HMIM][BF4] serves as a superpressurized glass under the pressure above 7.3 GPa, which is similar to the glassy state at low temperature, and a compression-induced liquid to liquid phase transition in [HMIM][BF4] occurs at ∼1.7 GPa. Besides, the conformational equilibrium of the GAAA conformer and AAAA conformer was converted easily in liquid [HMIM][BF4], while it was difficult to be influenced in glassy state.

  20. Experimental investigation of evaporation and condensation in the contact line region of a thin liquid film experiencing small thermal perturbations.

    PubMed

    Argade, Rajendra; Ghosh, Sombuddha; De, Sirshendu; DasGupta, Sunando

    2007-01-30

    Image-analyzing interferometry technique is successfully used to study microscale transport processes related to a curved microfilm on a solid substrate. Digital image processing is used to analyze the images of interference fringes, leading to the evaluation of liquid (heptane) film thickness and curvature profiles at different inclinations on a high refractive index glass surface. The curvature profiles obtained at different inclinations clearly demonstrate that there is a maximum in curvature near the junction of the adsorbed film (of uniform thickness) and the curved film, and then it becomes constant in the thicker portions of the film. The adsorbed film thickness is measured for horizontal as well as inclined positions. Experimentally obtained values of the dispersion constants are compared to those predicted from the Dzyaloshinskii-Lifshitz-Pitaevskii (DLP) theory, and reasonable agreements were obtained. A parameter alpha is defined and experimentally evaluated to quantify the closeness of the system to equilibrium. The nonequilibrium behavior of this parameter alpha is also observed with certain heat input at a particular inclination. A small thermal perturbation is used to force the liquid meniscus to undergo a cycle of alternating condensation and evaporation. High-speed video-microscopy and subsequent image analysis are used for data analysis. The numerical solution of a model that takes into account the balance between the suction and the capillary force is compared with the data to elicit new insights into the evaporation/condensation phenomena and to estimate the interfacial temperature differences for near-equilibrium situations. PMID:17241038

  1. Thermocapillary flow with evaporation and condensation and its effect on liquid retention in low-G fluid acquisition devices

    NASA Technical Reports Server (NTRS)

    Schmidt, George R.

    1994-01-01

    The steady motion, thermal and free surface behavior of a volatile, wetting liquid in microgravity are studied using scaling and numerical techniques. The objective is to determine whether the thermocapillary and two-phase convection arising from thermodynamic nonequilibrium along the porous surfaces of spacecraft liquid acquisition devices could cause the retention failures observed with liquid hydrogen and heated vapor pressurant. Why these devices seem immune to retention loss when pressurized with heated helium or heated directly through the porous structure was also examined. Results show that highly wetting fluids exhibit large negative and positive dynamic pressure gradients towards the meniscus interline when superheated and subcooled, respectively. With superheating, the pressure variation and recoil force arising from liquid/vapor phase change exert the same influence on surface morphology and promote retention. With subcooling, however, the pressure distribution produces a suction that degrades mechanical equilibrium of the surface. This result indicates that thermocapillary-induced deformation arising from subcooling and condensation is the likely cause for retention loss. In addition, increasing the level of nonequilibrium by reducing accommodation coefficient suppresses deformation and explains why this failure mode does not occur in instances of direct screen heating or pressurization with a heated inert gas.

  2. Condensation enhancement on a pool surface caused by a submerged liquid jet

    SciTech Connect

    Shumway, R.W.

    1997-05-01

    One advanced nuclear reactor design has a residual heat removal (RHR) pipe connected to the bottom of a steam generator outlet plenum. The water in the plenum can become thermally stratified during postulated loss of coolant accidents. Cold water injected through the RHR pipe has the potential effect of increasing the steam condensation on the pool surface due to the stirring action of the jet. The amount of increase depends on a number of factors, including the jet velocity and the pool height above the jet injection point. Prediction of steam condensation rates, before and after the jet breaks the pool surface, is the topic of this paper. Data and correlations exist for pre surface breakthrough and a method has been developed for post breakthrough. The models have been incorporated into the reactor safety analysis computer software known as RELAP5. Comparisons of predictions against data are presented.

  3. Simulation of water vapor condensation on LOX droplet surface using liquid nitrogen

    NASA Technical Reports Server (NTRS)

    Powell, Eugene A.

    1988-01-01

    The formation of ice or water layers on liquid oxygen (LOX) droplets in the Space Shuttle Main Engine (SSME) environment was investigated. Formulation of such ice/water layers is indicated by phase-equilibrium considerations under conditions of high partial pressure of water vapor (steam) and low LOX droplet temperature prevailing in the SSME preburner or main chamber. An experimental investigation was begun using liquid nitrogen as a LOX simulant. A monodisperse liquid nitrogen droplet generator was developed which uses an acoustic driver to force the stream of liquid emerging from a capillary tube to break up into a stream of regularly space uniformly sized spherical droplets. The atmospheric pressure liquid nitrogen in the droplet generator reservoir was cooled below its boiling point to prevent two phase flow from occurring in the capillary tube. An existing steam chamber was modified for injection of liquid nitrogen droplets into atmospheric pressure superheated steam. The droplets were imaged using a stroboscopic video system and a laser shadowgraphy system. Several tests were conducted in which liquid nitrogen droplets were injected into the steam chamber. Under conditions of periodic droplet formation, images of 600 micron diameter liquid nitrogen droplets were obtained with the stroboscopic video systems.

  4. Mass and thermal accommodation during gas-liquid condensation of water.

    PubMed

    Winkler, Paul M; Vrtala, Aron; Wagner, Paul E; Kulmala, Markku; Lehtinen, Kari E J; Vesala, Timo

    2004-08-13

    In this Letter we report, for the first time, direct and simultaneous determinations of mass and thermal accommodation coefficients for water vapor condensation in air, based on the observation of droplet growth kinetics in an expansion cloud chamber. Our experiments exclude values below 0.85 for the thermal and below 0.4 for the mass accommodation coefficients at temperatures ranging from 250 to 290 K. Both coefficients are likely to be 1 for all studied conditions. Previously available experimental data on the mass accommodation coefficient for water span about 3 orders of magnitude. Our results provide new and firm insight to cloud microphysics and consequently to the global radiative balance. PMID:15324249

  5. Benzoin Condensation: Monitoring a Chemical Reaction by High-Pressure Liquid Chromatography

    ERIC Educational Resources Information Center

    Bhattacharya, Apurba; Purohit, Vikram C.; Bellar, Nicholas R.

    2004-01-01

    High-pressure liquid chromatography (HPLC) is the preferred method of separating a variety of materials in complex mixtures such as pharmaceuticals, polymers, soils, food products and biological fluids and is also considered to be a powerful analytical tool in both academia and industry. The use of HPLC analysis as a means of monitoring and…

  6. Orientational order in liquids upon condensation in nanochannels: An optical birefringence study on rodlike and disclike molecules in monolithic mesoporous silica

    NASA Astrophysics Data System (ADS)

    Wolff, Matthias; Knorr, Klaus; Huber, Patrick; Kityk, Andriy V.

    2010-12-01

    We present high-resolution optical birefringence measurements upon sequential filling of an array of parallel-aligned nanochannels (14 nm mean diameter) with rodlike (acetonitrile) and disclike (hexafluorobenzene) molecules. We will demonstrate that such birefringence isotherms, when performed simultaneously with optically isotropic and index-matched counterparts (neopentane and hexafluoromethane), allow one to characterize the orientational state of the confined liquids with a high accuracy as a function of pore filling. The pore condensates are almost bulklike, optically isotropic liquids. For both anisotropic species we find, however, a weak orientational order (of a few percent at maximum) upon film condensation in the monolithic mesoporous membrane. It occurs upon formation of the second and third adsorbed layer, only, and vanishes gradually upon onset of capillary condensation. Presumably, it originates in the breaking of the full rotational symmetry of the interaction potential at the cylindrical, free liquid-vapor interface in the film-condensed state rather than at the silica-liquid interface. This conclusion is corroborated by comparisons of our experimental results with molecular-dynamics simulations reported in the literature.

  7. Direct Observation of Capillary Condensation of a Solid

    NASA Astrophysics Data System (ADS)

    Qiao, Ying; Christenson, Hugo K.

    2001-04-01

    We describe the direct condensation of a solid from vapor in an annular mica wedge. Neo-pentanol initially condenses as a liquid from 8 to 57 °C (the melting point Tm), followed by nucleation of a solid from vapor for T<45 °C. Menthol \\(Tm = 42 °C\\) gives only liquid condensates down to 12 °C. The adsorbed films of neo-pentanol, which unlike those of menthol show layering transitions, and the disordered crystalline phase of bulk neo-pentanol appear to facilitate condensation of the solid phase. There is evidence for a change in the nature of the solid neo-pentanol condensate with T.

  8. Formation of cluster systems in condensed matters and IR spectra of liquids

    NASA Astrophysics Data System (ADS)

    Melnikov, G.; Ignatenko, N.; Krasnych, P.; Melnikov, V.; Cherkasov, E.

    2016-02-01

    Modern approaches to the interpretation of IR spectra of polyatomic liquids are based on cluster models of the structure of matter. First of all it concerns the far infrared region of the spectrum (20-300 cm-1) where rotationally libration motions in the structure of clusters are found. This work is a continuation of research conducted by the authors earlier [G. Melnikov at al. 2015 IOP Conf. Ser Mater. Sci. Eng. 81 p 012032]. The authors have adopted a model in which the appearance of spectral bands is explained by to libration oscillations vibrations of dimers with different configurations in the structure of clusters.

  9. Effects of disorder on quantum fluctuations and superfluid density of a Bose-Einstein condensate in a two-dimensional optical lattice

    SciTech Connect

    Hu Ying; Liang Zhaoxin; Hu Bambi

    2009-10-15

    We investigate a Bose-Einstein condensate (BEC) trapped in a two-dimensional optical lattice in the presence of weak disorder within the framework of the Bogoliubov theory. In particular, we analyze the combined effects of disorder and an optical lattice on quantum fluctuations and superfluid density of the BEC system. Accordingly, the analytical expressions of the ground-state energy and quantum depletion of the system are obtained. Our results show that the lattice still induces a characteristic three-dimensional (3D) to one-dimensional crossover in the behavior of quantum fluctuations, despite the presence of weak disorder. Furthermore, we use the linear response theory to calculate the normal fluid density of the condensate induced by disorder. Our results in the 3D regime show that the combined presence of disorder and lattice induce a normal fluid density that asymptotically approaches 4/3 of the corresponding condensate depletion. Conditions for possible experimental realization of our scenario are also proposed.

  10. Studies of liquid adsorption, condensation and surface conductivity in porous media

    NASA Astrophysics Data System (ADS)

    Qi, Hao

    In the petroleum industry, accurate estimates of hydrocarbon reserve and its producibility are without a doubt among the most important issues. Quantitative estimates require the knowledge of three basic parameters of the rock formation: the porosity φ, the water saturation S w and the permeability k. Electrical conductivity is one of the most commonly made measurements used to deduce these quantities. Some empirical relationships used to make such estimates are quite well established and understood, however, many still lack a sound scientific foundation. Systematic laboratory investigation and theoretical understanding of the underlying petrophysics are much needed. This dissertation consists of three projects aimed at understanding both the surface conductivity observed in shaly sandstone, and the related phenomena of molecular adsorption on heterogeneous surfaces. In the first project, we carried out nitrogen adsorption experiments on three shale samples whose fractal dimensions had been previously characterized by small angle scattering (SANS). We found that analyzing the adsorption isotherm data according to the available theoretical predictions always resulted in D values that are lower than those obtained by SANS. The second project, a numerical simulation of adsorption on fractal surfaces, was designed to understand the origin of discrepancies revealed in the first project. We found that the interplay between van der Waals adsorption and capillary condensation always leads to a crossover between the two theoretical limits. The simulated isotherms exhibit the same general features we observed in our experimental data. The third project was aimed at understanding the surface conduction in porous media. We isolated the surface conductivity by growing water layers on the surface with water adsorption isotherm technique. Some of our results indicate that AC impedance measurement could let us determine the surface conductivity and separate it from that of the

  11. Dimensional phase transition from an array of 1D Luttinger liquids to a 3D Bose-Einstein condensate.

    PubMed

    Vogler, Andreas; Labouvie, Ralf; Barontini, Giovanni; Eggert, Sebastian; Guarrera, Vera; Ott, Herwig

    2014-11-21

    We study the thermodynamic properties of a 2D array of coupled one-dimensional Bose gases. The system is realized with ultracold bosonic atoms loaded in the potential tubes of a two-dimensional optical lattice. For negligible coupling strength, each tube is an independent weakly interacting 1D Bose gas featuring Tomonaga Luttinger liquid behavior. By decreasing the lattice depth, we increase the coupling strength between the 1D gases and allow for the phase transition into a 3D condensate. We extract the phase diagram for such a system and compare our results with theoretical predictions. Because of the high effective mass across the periodic potential and the increased 1D interaction strength, the phase transition is shifted to large positive values of the chemical potential. Our results are prototypical to a variety of low-dimensional systems, where the coupling between the subsystems is realized in a higher spatial dimension such as coupled spin chains in magnetic insulators. PMID:25479499

  12. Computational Studies of Condensed Matter Systems: Manganese Vanadium Oxide and 2D attractive Hubbard model with spin-dependent disorder

    NASA Astrophysics Data System (ADS)

    Nanguneri, Ravindra

    In this dissertation, we describe two projects, organized into two chapters, which comprise the study of condensed matter systems using self-consistent mean-field theories. In the first chapter, we study the exchange constants of MnV2O 4 using linear response, based on the magnetic force theorem (MFT), and the LSDA+U approximation of DFT in the LMTO basis. We obtain the exchanges for three different orbital orderings of the Vanadium atoms of the spinel. We then map the exchange constants to a Heisenberg model with single-ion anisotropy and solve for the spin-wave excitations in the non-collinear, low temperature phase of the spinel. The single-ion anisotropy parameters are obtained from an atomic multiplet exact-diagonalization program, taking into effect the crystal-field (CF) splitting and the spin-orbit coupling (SOC). We find good agreement between the spin-waves of one of our orbital ordered setups with previously reported experimental spin-waves as determined by neutron-scattering. We can therefore determine the correct orbital order (OO) from various proposals. In the second chapter, we show that the presence of a spin-dependent random potential in a superconductor or a superfluid atomic gas leads to distinct transitions at which the energy gap and average order parameter vanish, generating an intermediate gapless superfluid phase, in marked contrast to the case of spin-symmetric randomness where no such gapless superfluid phase is seen. By allowing the pairing amplitude to become inhomogeneous, the gapless superconducting phase persists to considerably higher disorder compared to the much earlier prediction of Abrikosov-Gor'kov. The low-lying excited states are located predominantly in regions where the pairing amplitude vanishes and coexist with the superfluid regions with a finite pairing. Our results are based on inhomogeneous Bogoliubov-de Gennes (BdG) mean field theory for a two dimensional attractive Hubbard model with spin

  13. Duality methods in networks, computer science models, and disordered condensed matter systems

    NASA Astrophysics Data System (ADS)

    Mitchell, Joseph Dan

    In this thesis, I explore lattice independent duality and systems to which it can be applied. I first demonstrate classical duality on models in an external field, including the Ising, Potts, and x -- y models, showing in particular how this modifies duality to be lattice independent and applicable to networks. I then present a novel application of duality on the boolean satsifiability problem, one of the most important problems in computational complexity, through mapping to a low temperature Ising model. This establishes the equivalence between boolean satisfiability and a problem of enumerating the positive solutions to a Diophantine system of equations. I continue by combining duality with a prominent tool for models on networks, belief propagation, deriving a new message passing procedure, dual belief propagation. In the final part of my thesis, I shift to propose and examine a semiclassical model, the two-component Coulomb glass model, which can explain the giant magnetoresistance peak present in disordered films near a superconductor-insulator transition as the effect of competition between single particle and localized pair transport. I numerically analyze the density of states and transport properties of this model.

  14. Theoretical and Computational Studies of Condensed-Phase Phenomena: The Origin of Biological Homochirality, and the Liquid-Liquid Phase Transition in Network-Forming Fluids

    NASA Astrophysics Data System (ADS)

    Ricci, Francesco

    This dissertation describes theoretical and computational studies of the origin of biological homochirality, and the existence of a liquid-liquid phase transition in pure-component network-forming fluids. A common theme throughout these studies is the use of sophisticated computer simulation and statistical mechanics techniques to study complex condensed-phase phenomena. In the first part of this dissertation, we use an elementary lattice model with molecular degrees of freedom, and satisfying microscopic reversibility, to investigate the effect of reaction reversibility on the evolution of stochastic symmetry breaking via autocatalysis and mutual inhibition in a closed system. We identify conditions under which the system's evolution towards racemic equilibrium becomes extremely slow, allowing for long-time persistence of a symmetry-broken state. We also identify a "monomer purification" mechanism, due to which a nearly homochiral state can persist for long times, even in the presence of significant reverse reaction rates. Order of magnitude estimates show that with reasonable physical parameters a symmetry broken state could persist over geologically-relevant time scales. In the second part of this dissertation, we study a chiral-symmetry breaking mechanism known as Viedma ripening. We develop a Monte Carlo model to gain further insights into the mechanisms capable of reproducing key experimental signatures associated with this phenomenon. We also provide a comprehensive investigation of how the model parameters impact the system's overall behavior. It is shown that size-dependent crystal solubility alone is insufficient to reproduce most experimental signatures, and that some form of a solid-phase chiral feedback mechanism (e.g., agglomeration) must be invoked in our model. In the third part of this dissertation, we perform rigorous free energy calculations to investigate the possibility of a liquid-liquid phase transition (LLPT) in the Stillinger-Weber (SW

  15. Condensate Mixtures and Tunneling

    SciTech Connect

    Timmermans, E.

    1998-09-14

    The experimental study of condensate mixtures is a particularly exciting application of the recently developed atomic-trap Bose-Einstein condensate (BEC) technology: such multiple condensates represent the first laboratory systems of distinguishable boson superfluid mixtures. In addition, as the authors point out in this paper, the possibility of inter-condensate tunneling greatly enhances the richness of the condensate mixture physics. Not only does tunneling give rise to the oscillating particle currents between condensates of different chemical potentials, such as those studied extensively in the condensed matter Josephson junction experiments, it also affects the near-equilibrium dynamics and stability of the condensate mixtures. In particular, the stabilizing influence of tunneling with respect to spatial separation (phase separation) could be of considerable practical importance to the atomic trap systems. Furthermore, the creation of mixtures of atomic and molecular condensates could introduce a novel type of tunneling process, involving the conversion of a pair of atomic condensate bosons into a single molecular condensate boson. The static description of condensate mixtures with such type of pair tunneling suggests the possibility of observing dilute condensates with the liquid-like property of a self-determined density.

  16. Collective excitations of a trapped Bose-Einstein condensate in the presence of weak disorder and a two-dimensional optical lattice

    SciTech Connect

    Hu Ying; Liang Zhaoxin; Hu Bambi

    2010-05-15

    We investigate the combined effects of weak disorder and a two-dimensional (2D) optical lattice on the collective excitations of a harmonically trapped Bose-Einstein condensate (BEC) at zero temperature. Accordingly, we generalize the hydrodynamic equations of superfluid for a weakly interacting Bose gas in a 2D optical lattice to include the effects of weak disorder. Our analytical results for the collective frequencies beyond the mean-field approximation reveal the peculiar role of disorder, interplaying with the 2D optical lattice and interatomic interaction, on elementary excitations along the 3D to 1D crossover. In particular, consequences of disorder on the phonon propagation and surface modes are analyzed in detail. The experimental scenario is also proposed.

  17. Liquid demixing of intrinsically disordered proteins is seeded by poly(ADP-ribose)

    PubMed Central

    Altmeyer, Matthias; Neelsen, Kai J.; Teloni, Federico; Pozdnyakova, Irina; Pellegrino, Stefania; Grøfte, Merete; Rask, Maj-Britt Druedahl; Streicher, Werner; Jungmichel, Stephanie; Nielsen, Michael Lund; Lukas, Jiri

    2015-01-01

    Intrinsically disordered proteins can phase separate from the soluble intracellular space, and tend to aggregate under pathological conditions. The physiological functions and molecular triggers of liquid demixing by phase separation are not well understood. Here we show in vitro and in vivo that the nucleic acid-mimicking biopolymer poly(ADP-ribose) (PAR) nucleates intracellular liquid demixing. PAR levels are markedly induced at sites of DNA damage, and we provide evidence that PAR-seeded liquid demixing results in rapid, yet transient and fully reversible assembly of various intrinsically disordered proteins at DNA break sites. Demixing, which relies on electrostatic interactions between positively charged RGG repeats and negatively charged PAR, is amplified by aggregation-prone prion-like domains, and orchestrates the earliest cellular responses to DNA breakage. We propose that PAR-seeded liquid demixing is a general mechanism to dynamically reorganize the soluble nuclear space with implications for pathological protein aggregation caused by derailed phase separation. PMID:26286827

  18. Pair interactions among ternary DPPC/POPC/cholesterol mixtures in liquid-ordered and liquid-disordered phases.

    PubMed

    Yang, Jing; Martí, Jordi; Calero, Carles

    2016-05-18

    Saturated phospholipids, unsaturated phospholipids, and cholesterol are essential components of cell membranes, making the understanding of their mutual interactions of great significance. We have performed microsecond molecular dynamics simulations on the ternary mixtures of DPPC/POPC/cholesterol to systematically examine lipid-lipid and cholesterol-lipid interactions in the liquid-ordered and the liquid-disordered phases. The results show that there exists a competition between the tighter packing of cholesterol-lipid and the looser packing of lipid-lipid as the membrane changes from the liquid-disordered phase to the liquid-ordered phase. Depending on the lipid saturation, the favor of lipid-lipid interactions is in the order of saturated-saturated > monounsaturated-monounsaturated > saturated-monounsaturated. Cholesterol-saturated lipid interactions are more favorable than cholesterol-monounsaturated lipid ones. The results are consistent with the push-pull forces derived from experiments and give general insights into the interactions among membrane components. PMID:27103534

  19. Tongue displacement and durational characteristics of normal and disordered Brazilian Portuguese liquids.

    PubMed

    Berti, Larissa; Boer, Gillian De; Bressmann, Tim

    2016-01-01

    The goal of the present study was to characterize normal and disordered Brazilian Portuguese liquids. The research hypotheses were that disordered liquid sounds would be characterized by (1) longer syllable and segment durations, (2) larger and more undifferentiated displacement of the tongue and (3) that the speech errors would show sub-phonemic differences depending on the target sound. The participants of this study were 11 children with phonological disorders and 9 control participants matched for age and educational background. The children's tongue movement in the sagittal plane was recorded with ultrasound. The speech stimuli consisted of 3 repetitions of 5 words representing the four Brazilian Portuguese liquids /l/, /ʎ/, /ɾ/ and /ʀ/ in the context of the vowel /a/. A panel of four listeners transcribed each of the productions and classified them as correct or incorrect. The outcome measures were based on duration (syllable duration, ratio L/V) and tongue displacement (percentage average displacement, anterior displacement, posterior displacement). Based on mixed model analyses of variance, the first research hypothesis was confirmed for the /l/ and /ɾ/ targets, but not for the /ʀ/ and /ʎ/ targets. The second hypothesis was partially confirmed. The third hypothesis was confirmed. The research serves to illustrate the effects of phonological disorder on the phonetic realisation of Brazilian Portuguese liquid sounds. PMID:26853548

  20. Ordered and disordered colloidal particle monolayers at liquid crystal interfaces

    NASA Astrophysics Data System (ADS)

    Wei, Wei-Shao; Lohr, Matthew; Gharbi, Mohamed Amine; Stebe, Kathleen; Yodh, A. G.

    2014-03-01

    In this work, we investigate ordered colloidal particle monolayers at the air/liquid-crystal (LC) interface. Specifically, silica microparticles are treated with DMOAP to create homeotropic anchoring of LC mesogens at their surfaces. These particles are then spread on an air-exposed interface of the LC 5CB. Macroscopic ordered patterns of these microparticles form due to long-range interactions between particles that are mediated by elastic deformations of the underlying LC. Different confinement conditions lead to various self-assembled patterns ranging from hexagonal lattices to chain-like dipole formations. Using dark-field video microscopy, we track and analyze the dynamics of the colloidal particles in the hexagonal crystal packing, deriving mean squared displacements, phonon modes and density of states, etc., under several conditions. Further, heating of the nematic LC into its isotropic phase enables us to observe melting dynamics of this unusual quasi-2D crystal. The investigations provide insight into crystalline packings controlled by liquid-crystal mediated colloidal interactions. This work is funded by NSF Grant DMR12-05463, PENN MRSEC Grant DMR11-20901, and NASA Grant NNX08AO0G.

  1. Interleaflet mixing and coupling in liquid-disordered phospholipid bilayers.

    PubMed

    Capponi, Sara; Freites, J Alfredo; Tobias, Douglas J; White, Stephen H

    2016-02-01

    Organized as bilayers, phospholipids are the fundamental building blocks of cellular membranes and determine many of their biological functions. Interactions between the two leaflets of the bilayer (interleaflet coupling) have been implicated in the passage of information through membranes. However, physically, the meaning of interleaflet coupling is ill defined and lacks a structural basis. Using all-atom molecular dynamics simulations of fluid phospholipid bilayers of five different lipids with differing degrees of acyl-chain asymmetry, we have examined interleaflet mixing to gain insights into coupling. Reasoning that the transbilayer distribution of terminal methyl groups is an appropriate measure of interleaflet mixing, we calculated the transbilayer distributions of the acyl chain terminal methyl groups for five lipids: dioleoylphosphatidylcholine (DOPC), palmitoyloleoylphosphatidylcholine (POPC), stearoyloleoylphosphatidylcholine (SOPC), oleoylmyristoylphosphatidylcholine (OMPC), and dimyristoylphosphatidylcholine (DMPC). We observed in all cases very strong mixing across the bilayer midplane that diminished somewhat with increasing acyl-chain ordering defined by methylene order parameters. A hallmark of the interleaflet coupling idea is complementarity, which postulates that lipids with short alkyl chains in one leaflet will preferentially associate with lipids with long alkyl chains in the other leaflet. Our results suggest a much more complicated picture for thermally disordered bilayers that we call distributed complementarity, as measured by the difference in the peak positions of the sn-1 and sn-2 methyl distributions in the same leaflet. PMID:26657692

  2. Annealing, lattice disorder, and non-Fermi-liquid behavior in UCu4Pd

    NASA Astrophysics Data System (ADS)

    Booth, C. H.; Scheidt, E.-W.; Killer, U.; Weber, A.; Kehrein, S.

    2002-10-01

    The magnetic and electronic properties of non-Fermi-liquid UCu4Pd depend on annealing conditions. Local structural changes due to this annealing are reported from U LIII- and Pd K-edge x-ray-absorption fine-structure measurements. In particular, annealing decreases the fraction of Pd atoms on nominally Cu 16e sites and the U-Cu pair-distance distribution width. This study provides quantitative information on the amount of disorder in UCu4Pd and allows an assessment of its possible importance to the observed non-Fermi-liquid behavior.

  3. Annealing, lattice disorder and non-Fermi liquid behavior in UCu4Pd

    SciTech Connect

    Booth, C.H.; Scheidt, E.-W.; Killer, U.; Weber, A.; Kehrein, S.

    2002-07-30

    The magnetic and electronic properties of non-Fermi liquid UCu{sub 4Pd} depend on annealing conditions. Local structural changes due to this annealing are reported from UL{sub III}- and Pd K-edge x-ray absorption fine-structure measurements. In particular, annealing decreases the fraction of Pd atoms on nominally Cu 16e sites and the U-Cu pair-distance distribution width. This study provides quantitative information on the amount of disorder in UCu{sub 4Pd} and allows an assessment of its possible importance to the observed non-Fermi liquid behavior.

  4. Partitioning of liquid-ordered/liquid-disordered membrane microdomains induced by the fluidifying effect of 2-hydroxylated fatty acid derivatives.

    PubMed

    Ibarguren, Maitane; López, David J; Encinar, José A; González-Ros, José M; Busquets, Xavier; Escribá, Pablo V

    2013-11-01

    Cellular functions are usually associated with the activity of proteins and nucleic acids. Recent studies have shown that lipids modulate the localization and activity of key membrane-associated signal transduction proteins, thus regulating the cell's physiology. Membrane Lipid Therapy aims to reverse cell dysfunctions (i.e., diseases) by modulating the activity of membrane signaling proteins through regulation of the lipid bilayer structure. The present work shows the ability of a series of 2-hydroxyfatty acid (2OHFA) derivatives, varying in the acyl chain length and degree of unsaturation, to regulate the membrane lipid structure. These molecules have shown greater therapeutic potential than their natural non-hydroxylated counterparts. We demonstrated that both 2OHFA and natural FAs induced reorganization of lipid domains in model membranes of POPC:SM:PE:Cho, modulating the liquid-ordered/liquid-disordered structures ratio and the microdomain lipid composition. Fluorescence spectroscopy, confocal microscopy, Fourier transform infrared spectroscopy and differential detergent solubilization experiments showed a destabilization of the membranes upon addition of the 2OHFAs and FAs which correlated with the observed disordering effect. The changes produced by these synthetic fatty acids on the lipid structure may constitute part of their mechanism of action, leading to changes in the localization/activity of membrane proteins involved in signaling cascades, and therefore modulating cell responses. PMID:23792066

  5. Analysis of the Pressure Rise in a Partially Filled Liquid Tank in Microgravity with Low Wall Heat Flux and Simultaneous Boiling and Condensation

    NASA Technical Reports Server (NTRS)

    Hasan, Mohammad M.; Balasubramaniam, R.

    2012-01-01

    Experiments performed with Freon 113 in the space shuttle have shown that in a pro- cess of very slow heating, high liquid superheats can be sustained for a long period in microgravity. In a closed system explosive vaporization of superheated liquid resulted in pressure spikes of varying magnitudes. In this paper, we analyze the pressure rise in a partially lled closed tank in which a large vapor bubble (i.e., ullage) is initially present, and the liquid is subjected to a low wall heat ux. The liquid layer adjacent to the wall becomes superheated until the temperature for nucleation of the bubbles (or the incipience of boiling) is achieved. In the absence of the gravity-induced convection large quantities of superheated liquid can accumulate over time near the heated surface. Once the incipience temperature is attained, explosive boiling occurs and the vapor bubbles that are produced on the heater surface tend to quickly raise the tank pressure. The liquid-vapor saturation temperature increases as well. These two e ects tend to induce condensation of the large ullage bubble that is initially present, and tends to mitigate the tank pressure rise. As a result, the tank pressure is predicted to rise sharply, attain a maximum, and subsequently decay slowly. The predicted pressure rise is compared with experimental results obtained in the microgravity environments of the space shuttle for Freon 113. The analysis is appli- cable, in general to heating of liquid in closed containers in microgravity and to cryogenic fuel tanks, in particular where small heat leaks into the tank are unavoidable.

  6. Heat diffusion in the disordered Fermi and electron liquids: the role of inelastic processes

    NASA Astrophysics Data System (ADS)

    Schwiete, Georg; Finkel'Stein, Alexander

    2015-03-01

    We study thermal transport in the disordered Fermi and electron liquids at low temperatures. Gravitational potentials are used as sources for finding the heat density and its correlation function. For a comprehensive study, we extend the renormalization group (RG) analysis developed for electric transport by including the gravitational potentials into the RG scheme. The analysis reveals that for the disordered Fermi liquid the Wiedemann-Franz law remains valid even in the presence of quantum corrections caused by the interplay of diffusion modes and the electron-electron interaction. In the present scheme this fundamental relation is closely connected with a fixed point in the multi-parametric RG flow of the gravitational potentials. For the disordered electron liquid we additionally analyze inelastic processes induced by the Coulomb interaction at sub-temperature energies. While the general form of the correlation function has to be compatible with energy conservation, these inelastic processes are at the origin of logarithmic corrections violating the Wiedemann-Franz law. The interplay of various terms in the heat density-heat density correlation function therefore differs from that for densities of other conserved quantities, such as total number of particles or spin. A. F. and G. S. acknowledge support by the Alexander von Humboldt foundation. A.F. is supported by the National Science Foundation Grant NSF-DMR-1006752.

  7. Quantitative prediction of physical properties of imidazolium based room temperature ionic liquids through determination of condensed phase site charges: a refined force field.

    PubMed

    Mondal, Anirban; Balasubramanian, Sundaram

    2014-03-27

    Quantitative prediction of physical properties of room temperature ionic liquids through nonpolarizable force field based molecular dynamics simulations is a challenging task. The challenge lies in the fact that mean ion charges in the condensed phase can be less than unity due to polarization and charge transfer effects whose magnitude cannot be fully captured through quantum chemical calculations conducted in the gas phase. The present work employed the density-derived electrostatic and chemical (DDEC/c3) charge partitioning method to calculate site charges of ions using electronic charge densities obtained from periodic density functional theory (DFT) calculations of their crystalline phases. The total ion charges obtained thus range between -0.6e for chloride and -0.8e for the PF6 ion. The mean value of the ion charges obtained from DFT calculations of an ionic liquid closely matches that obtained from the corresponding crystal thus confirming the suitability of using crystal site charges in simulations of liquids. These partial charges were deployed within the well-established force field developed by Lopes et al., and consequently, parameters of its nonbonded and torsional interactions were refined to ensure that they reproduced quantum potential energy scans for ion pairs in the gas phase. The refined force field was employed in simulations of seven ionic liquids with six different anions. Nearly quantitative agreement with experimental measurements was obtained for the density, surface tension, enthalpy of vaporization, and ion diffusion coefficients. PMID:24605817

  8. States of a dispersed nonwetting liquid in a disordered nanoporous medium

    NASA Astrophysics Data System (ADS)

    Borman, Vladimir D.; Belogorlov, Anton A.; Grekhov, Alexey M.; Tronin, Vladimir N.

    2015-04-01

    Three different states of a dispersed nonwetting liquid (water) in the Fluka 100 C8 and Fluka 100 C18 disordered porous media, as well as transitions between these states under variation of the temperature and the degree of filling, have been revealed. It has been shown that the appearance of such states is due to the broadening of the pore size distribution function f(R), fluctuations of configurations of neighbors in the system of pores and fluctuations in the configuration of a pore and its environment consisting of filled and empty pores in the percolation cluster. These states and transitions are caused by the competition between the effective repulsion of the nonwetting liquid from the wall of the pore, which is responsible for the "extrusion" of the liquid from the pore, and the effective collective "multiparticle" attraction of the liquid cluster in the pore to clusters in the neighboring connected pores. The observed difference in the behavior of the Fluka 100 C8/water and Fluka 100 C18/water systems and the previously studied Libersorb-23 (L23)/water system indicates a significant dependence of the state of these systems on the type of disorder in them.

  9. Competition between local disordering and global ordering fields in nematic liquid crystals

    PubMed Central

    Ambrožič, Milan; Kralj, Samo

    2010-01-01

    Summary We study the influence of external electric or magnetic field B on orientational ordering of nematic liquid crystals or of other rod-like objects (e.g. nanotubes immersed in a liquid) in the presence of random anisotropy field type of disorder. The Lebwohl–Lasher lattice type of semi-microscopic approach is used at zero temperature. Therefore, results are valid well below the transition into the isotropic phase. We calculate the correlation function of systems as a function of B, concentration p of impurities imposing random anisotropy field disorder, the disorder strength W and system dimensionality (2D and 3D systems). In order to probe memory effects we calculate correlation length ξ for random and homogeneous initial configurations. We determine the crossover fields B c(p) separating roughly the ordered and disordered regime. Memory effects are apparent only in the latter case, i.e. for B < B c. PACS numbers: 47.51.+a, 47.54.-r, 07.05.Tp, 61.30.-v PMID:20502609

  10. Approaching many-body localization from disordered Luttinger liquids via the functional renormalization group

    NASA Astrophysics Data System (ADS)

    Karrasch, C.; Moore, J. E.

    2015-09-01

    We study the interplay of interactions and disorder in a one-dimensional fermion lattice coupled adiabatically to infinite reservoirs. We employ both the functional renormalization group (FRG) as well as matrix product state techniques, which serve as an accurate benchmark for small systems. Using the FRG, we compute the length- and temperature-dependence of the conductance averaged over 104 samples for lattices as large as 105 sites. We identify regimes in which non-Ohmic power law behavior can be observed and demonstrate that the corresponding exponents can be understood by adapting earlier predictions obtained perturbatively for disordered Luttinger liquids. In the presence of both disorder and isolated impurities, the conductance has a universal single-parameter scaling form. This lays the groundwork for an application of the functional renormalization group to the realm of many-body localization.

  11. Evidence of anisotropic quenched disorder effects on a smectic liquid crystal confined in porous silicon

    SciTech Connect

    Guegan, Regis; Morineau, Denis; Loverdo, Claude; Beziel, Wilfried; Guendouz, Mohammed

    2006-01-15

    We present a neutron scattering analysis of the structure of the smectic liquid crystal octylcyanobiphenyl (8CB) confined in one-dimensional nanopores of porous silicon films (PS). The smectic transition is completely suppressed, leading to the extension of a short-range ordered smectic phase aligned along the pore axis. It evolves reversibly over an extended temperature range, down to 50 K below the N-SmA transition in pure 8CB. This behavior strongly differs from previous observations of smectics in different one-dimensional porous materials. A coherent picture of this striking behavior requires that quenched disorder effects are invoked. The strongly disordered nature of the inner surface of PS acts as random fields coupling to the smectic order. The one-dimensionality of PS nanochannels offers perspectives on quenched disorder effects, of which observation has been restricted to homogeneous random porous materials so far.

  12. Freeze-Tolerant Condensers

    NASA Technical Reports Server (NTRS)

    Crowley, Christopher J.; Elkouhk, Nabil

    2004-01-01

    Two condensers designed for use in dissipating heat carried by working fluids feature two-phase, self-adjusting configurations such that their working lengths automatically vary to suit their input power levels and/or heat-sink temperatures. A key advantage of these condensers is that they can function even if the temperatures of their heat sinks fall below the freezing temperatures of their working fluids and the fluids freeze. The condensers can even be restarted from the frozen condition. The top part of the figure depicts the layout of the first condenser. A two-phase (liquid and vapor) condenser/vapor tube is thermally connected to a heat sink typically, a radiatively or convectively cooled metal panel. A single-phase (liquid) condensate-return tube (return artery) is also thermally connected to the heat sink. At intervals along their lengths, the condenser/vapor tube and the return artery are interconnected through porous plugs. This condenser configuration affords tolerance of freezing, variable effective thermal conductance (such that the return temperature remains nearly constant, independently of the ultimate sink temperature), and overall pressure drop smaller than it would be without the porous interconnections. An additional benefit of this configuration is that the condenser can be made to recover from the completely frozen condition either without using heaters, or else with the help of heaters much smaller than would otherwise be needed. The second condenser affords the same advantages and is based on a similar principle, but it has a different configuration that affords improved flow of working fluid, simplified construction, reduced weight, and faster recovery from a frozen condition.

  13. Diagnosis of phase transitions in disordered fractional quantum Hall liquids using quantum entanglement

    NASA Astrophysics Data System (ADS)

    Liu, Zhao; Bhatt, R. N.

    The conventional method to study phase transitions from fractional quantum Hall (FQH) liquids to a localized phase induced by disorder has relied on the collapse of the mobility gap and Hall conductance. Here, we scrutinize this issue from the perspective of quantum entanglement. We consider electrons in the disordered lowest Landau level at Laughlin filling fractions ν = 1 / m with either Haldane's pseudopotentials or Coulomb interaction. We find that the derivative of the orbital-cut von-Neumann entropy with respect to the disorder strength has a sharp peak, which diverges with system size, providing a clear fingerprint of the transition from FQH liquids to a localized phase. Further, the fluctuation of the entropy with different cut boundaries is utilized to examine whether the ground states are localized in some region. We also investigate the level statistics of the entanglement spectrum, as well as the low-lying spectrum of the Hamiltonian to extract more information about the phase transition. Our method can be applied to study many-body localization in other topological systems. This work was supported by US Department of Energy, Office of Basic Energy Sciences, through Grant No. DE-SC0002140.

  14. [Basic peptides from bee venom, IV. Synthesis of the mast cell-degranulating peptide by liquid-phase fragment condensation (author's transl)].

    PubMed

    Hartter, P

    1980-04-01

    The synthesis of the mast cell-degranulating peptide by liquid-phase fragment condensation is described. After the carboxyterminal of the peptide is condensated with polyethylene-glycol (Mr 10000) the following fragments are coupled stepwise on the polymer, a soluble carrier in dichloromethane by the dicyclohexylcarbodiimide/hydroxybenzotriazole-method. Pos. 17-21 Boc-Lys(Z)-Ile-Cys(SiPr)-Gly-Lys(Z) (I) Pos. 12-16 Boc-Pro-His(Trt)-Ile-Cys(Trt)-Arg(Tos) (II) Pos. 8-11 Boc-His(Trt)-Val-Ile-Lys(Z) (III) Pos. 5-7 Boc-Cys(SiPr)-Lys(Z)-Arg(Tos) (IV) Pos. 1-4 Boc-Ile-Lys(Z)-Cys(Trt)-Asn(Mbh) (V) It is practical to crystallize the polyethyleneglycol peptide-coupling products from ethanol after each step. Most of the protecting groups can be removed by treatment of the complete polyethylene-glycol-peptide in trifluoroacetic acid/HBr. In methanol, saturated with ammonia, the peptide is removed in the amid-form from the carrier. The guanidyl-blocking group disappears by solving the peptide in liquid HF. The crude peptide is converted into the tetra-S-sulfonate derivate by oxidative sulfitolysis and purified by ion-exchange and gel chromatography. After reduction by mercaptoethanol a cautious air-reoxidation of the SH- to the SS-peptide followed. Rechromatography on ion-exchange and dextran gels yields a peptide with good biological activity in rat cell histamin-liberation and inflammation inhibition compared with the natural recombinated product. PMID:7380391

  15. Theoretical study of ionic liquids based on the cholinium cation. Ab initio simulations of their condensed phases.

    PubMed

    Campetella, Marco; Bodo, Enrico; Montagna, Maria; De Santis, Serena; Gontrani, Lorenzo

    2016-03-14

    We have explored by means of ab initio molecular dynamics the homologue series of 11 different ionic liquids based on the combination of the cholinium cation with deprotonated amino acid anions. We present a structural analysis of the liquid states of these compounds as revealed by accurate ab initio computations of the forces. We highlight the persistent structural motifs that see the ionic couple as the basic building block of the liquid whereby a strong hydrogen bonding network substantially determines the short range structural behavior of the bulk state. Other minor docking features of the interaction network are also discovered and described. Special cases along the series such as Cysteine and Phenylalanine are discussed in the view of their peculiar properties due to zwitterion formation and additional long-range structural organization. PMID:26979694

  16. Theoretical study of ionic liquids based on the cholinium cation. Ab initio simulations of their condensed phases

    NASA Astrophysics Data System (ADS)

    Campetella, Marco; Bodo, Enrico; Montagna, Maria; De Santis, Serena; Gontrani, Lorenzo

    2016-03-01

    We have explored by means of ab initio molecular dynamics the homologue series of 11 different ionic liquids based on the combination of the cholinium cation with deprotonated amino acid anions. We present a structural analysis of the liquid states of these compounds as revealed by accurate ab initio computations of the forces. We highlight the persistent structural motifs that see the ionic couple as the basic building block of the liquid whereby a strong hydrogen bonding network substantially determines the short range structural behavior of the bulk state. Other minor docking features of the interaction network are also discovered and described. Special cases along the series such as Cysteine and Phenylalanine are discussed in the view of their peculiar properties due to zwitterion formation and additional long-range structural organization.

  17. Multiplicity of metastable nonergodic states of a dispersed nonwetting liquid in a disordered nanoporous medium

    NASA Astrophysics Data System (ADS)

    Borman, Vladimir D.; Belogorlov, Anton A.; Grekhov, Alexey M.; Tronin, Vladimir N.

    2014-10-01

    Three different metastable nonergodic states of a dispersed nonwetting liquid (water) in the Fluka 100 C8 and Fluka 100 C18 disordered porous media, as well as transitions between these states under variation of the temperature and the degree of filling, have been qualitatively described. It has been shown that the appearance of such states is due to spatial variations of the number of the nearest neighbors because of the broadening of the pore size distribution function f( R), fluctuations of various local configurations of neighbors in the system of pores, and fluctuations of a configuration of a pore and its environment consisting of filled and empty pores on a percolation cluster. These states and transitions are caused by the competition between the effective repulsion of the nonwetting liquid from the wall of the pore, which is responsible for the "extrusion" of the liquid from the pore, and the effective collective multiparticle attraction of the liquid cluster in the pore to clusters in the neighboring connected pores. The theoretical dependences obtained make it possible to qualitatively describe experimental data.

  18. Fast and slow dynamics in a discotic liquid crystal with regions of columnar order and disorder.

    PubMed

    Hansen, M R; Feng, X; Macho, V; Müllen, K; Spiess, H W; Floudas, G

    2011-12-16

    Aromatic disk-shaped molecules tend to self-organize into a herringbone packing where the disks are inclined at angles ±θ with respect to the axis of the column. In discotic liquid crystals this can introduce defects between stacks of limited length. In a C(3)-symmetric hexa-peri-hexabenzocoronene, solid-state NMR, x-ray scattering, and rheology identifies such a packing with θ=43° and stacks of about seven disks. Disordered regions containing defects fill the space in between the ordered stacks. Biaxial intra- and intercolumnar dynamics differing by eight decades are identified. PMID:22243114

  19. Anomalously slow relaxation of a nonwetting liquid in the disordered confinement of a nanoporous medium

    SciTech Connect

    Borman, V. D.; Belogorlov, A. A.; Zhuromskii, V. M.; Tronin, V. N.

    2015-12-15

    The time evolution of the water–disordered nanoporous medium Libersorb 23 (L23) system has been studied after complete filling at elevated pressure followed by full release of overpressure. It is established that relaxation of the L23 rapidly flows out during the overpressure relief time, following the variation in pressure. At a temperature below that of the dispersion transition (T < T{sub d} = 284 K), e.g., at T = 277 K, the degree of filling θ decreases from 1 to 0.8 within 10 s. The degree of filling varies with time according to the power law θ ∼ t{sup –α} with the exponent α < 0.1 over a period of t ∼ 10{sup 5} s. This process corresponds to slow relaxation of a metastable state of a nonwetting liquid in a porous medium. At times t > 10{sup 5} s, the metastable state exhibits decay, manifested as the transition to a power dependence of θ(t) with a larger exponent. The relaxation of the metastable state of nonwetting liquid in a disordered porous medium is described in the mean field approximation as a continuous sequence of metastable states with a barrier decreasing upon a decrease in the degree of filling. Using this approach, it is possible to qualitatively explain the observed relaxation process and crossover transition to the stage described by θ(t) with a larger exponent.

  20. Solidification fronts in supercooled liquids: how rapid fronts can lead to disordered glassy solids.

    PubMed

    Archer, A J; Robbins, M J; Thiele, U; Knobloch, E

    2012-09-01

    We determine the speed of a crystallization (or, more generally, a solidification) front as it advances into the uniform liquid phase after the system has been quenched into the crystalline region of the phase diagram. We calculate the front speed by assuming a dynamical density functional theory (DDFT) model for the system and applying a marginal stability criterion. Our results also apply to phase field crystal (PFC) models of solidification. As the solidification front advances into the unstable liquid phase, the density profile behind the advancing front develops density modulations and the wavelength of these modulations is a dynamically chosen quantity. For shallow quenches, the selected wavelength is precisely that of the crystalline phase and so well-ordered crystalline states are formed. However, when the system is deeply quenched, we find that this wavelength can be quite different from that of the crystal, so the solidification front naturally generates disorder in the system. Significant rearrangement and aging must subsequently occur for the system to form the regular well-ordered crystal that corresponds to the free energy minimum. Additional disorder is introduced whenever a front develops from random initial conditions. We illustrate these findings with simulation results obtained using the PFC model. PMID:23030925

  1. CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES: Electron Dispersion in Liquid Alkali and Their Alloys

    NASA Astrophysics Data System (ADS)

    Vora, Aditya M.

    2010-07-01

    Ashcroft's local empty core (EMC) model pseudopotential in the second-order perturbation theory is used to study the electron dispersion relation, the Fermi energy, and deviation in the Fermi energy from free electron value for the liquid alkali metals and their equiatomic binary alloys for the first time. In the present computation, the use of pseudo-alloy-atom model (PAA) is proposed and found successful. The influence of the six different forms of the local field correction functions proposed by Hartree (H), Vashishta-Singwi (VS), Taylor (T), Ichimaru-Utsumi (IU), Farid et al. (F), and Sarkar et al. (S) on the aforesaid electronic properties is examined explicitly, which reflects the varying effects of screening. The depth of the negative hump in the electron dispersion of liquid alkalis decreases in the order Li → K, except for Rb and Cs, it increases. The results of alloys are in predictive nature.

  2. Flow Boiling and Condensation Experiment

    NASA Video Gallery

    The Flow Boiling and Condensation Experiment is another investigation that examines the flow of a mixture of liquids and the vapors they produce when in contact with hot space system equipment. Coo...

  3. Steam condensation and liquid hold-up in steam generator U-tubes during oscillatory natural circulation

    SciTech Connect

    De Santi, G.F.; Mayinger, F.

    1990-01-01

    In many accident scenarios, natural circulation is an important heat transport mechanism for long-term cooling of light water reactors. In the event of a small pipe break, with subsequent loss of primary cooling fluid loss-of-coolant accident (LOCA), or under abnormal operating conditions, early tripping of the main coolant pumps can be actuated. Primary fluid flow will then progress from forced to natural convection. Understanding of the flow regimes and heat-removal mechanisms in the steam generators during the entire transient is of primary importance to safety analysis. Flow oscillations during two-phase natural circulation experiments for pressurized water reactors (PWRs) with inverted U-tube steam generators occur at high pressure and at a primary inventory range between two-phase circulation and reflex heat removal. This paper deals with the oscillatory flow behavior that was observed in the LOBI-MOD2 facility during the transition period between two-phase natural circulation and reflex condensation.

  4. Renormalization group analysis of thermal transport in the disordered Fermi liquid

    NASA Astrophysics Data System (ADS)

    Schwiete, G.; Finkel'stein, A. M.

    2014-10-01

    We present a detailed study of thermal transport in the disordered Fermi liquid with short-range interactions. At temperatures smaller than the impurity scattering rate, i.e., in the diffusive regime, thermal conductivity acquires nonanalytic quantum corrections. When these quantum corrections become large at low temperatures, the calculation of thermal conductivity demands a theoretical approach that treats disorder and interactions on an equal footing. In this paper, we develop such an approach by merging Luttinger's idea of using gravitational potentials for the analysis of thermal phenomena with a renormalization group calculation based on the Keldysh nonlinear sigma model. The gravitational potentials are introduced in the action as auxiliary sources that couple to the heat density. These sources are a convenient tool for generating expressions for the heat density and its correlation function from the partition function. Already in the absence of the gravitational potentials, the nonlinear sigma model contains several temperature-dependent renormalization group charges. When the gravitational potentials are introduced into the model, they acquire an independent renormalization group flow. We show that this flow preserves the phenomenological form of the correlation function, reflecting its relation to the specific heat and the constraints imposed by energy conservation. The main result of our analysis is that the Wiedemann-Franz law holds down to the lowest temperatures even in the presence of disorder and interactions and despite the quantum corrections that arise for both the electric and thermal conductivities.

  5. Condensation of Self-Assembled Lyotropic Chromonic Liquid Crystal Sunset Yellow in Aqueous Solutions Crowded with Polyethylene Glycol and Doped with Salt

    SciTech Connect

    Park, Heung-Shik; Kang, Shin-Woong; Tortora, Luana; Kumar, Satyendra; Lavrentovich, Oleg D.

    2012-10-10

    We use optical and fluorescence microscopy, densitometry, cryo-transmission electron microscopy (cryo-TEM), spectroscopy, and synchrotron X-ray scattering to study the phase behavior of the reversible self-assembled chromonic aggregates of an anionic dye Sunset Yellow (SSY) in aqueous solutions crowded with an electrically neutral polymer polyethylene glycol (PEG) and doped with the salt NaCl. PEG causes the isotropic SSY solutions to condense into a liquid-crystalline region with a high concentration of SSY aggregates, coexisting with a PEG-rich isotropic (I) region. PEG added to the homogeneous nematic (N) phase causes separation into the coexisting N and I domains; the SSY concentration in the N domains is higher than the original concentration of PEG-free N phase. Finally, addition of PEG to the highly concentrated homogeneous N phase causes separation into the coexisting columnar hexagonal (C) phase and I phase. This behavior can be qualitatively explained by the depletion (excluded volume) effects that act at two different levels: at the level of aggregate assembly from monomers and short aggregates and at the level of interaggregate packing. We also show a strong effect of a monovalent salt NaCl on phase diagrams that is different for high and low concentrations of SSY. Upon the addition of salt, dilute I solutions of SSY show appearance of the condensed N domains, but the highly concentrated C phase transforms into a coexisting I and N domains. We suggest that the salt-induced screening of electric charges at the surface of chromonic aggregates leads to two different effects: (a) increase of the scission energy and the contour length of aggregates and (b) decrease of the persistence length of SSY aggregates.

  6. CONDENSATION CAN

    DOEpatents

    Booth, E.T. Jr.; Pontius, R.B.; Jacobsohn, B.A.; Slade, C.B.

    1962-03-01

    An apparatus is designed for condensing a vapor to a solid at relatively low back pressures. The apparatus comprises a closed condensing chamber, a vapor inlet tube extending to the central region of the chamber, a co-axial tubular shield surrounding the inlet tube, means for heating the inlet tube at a point outside the condensing chamber, and means for refrigeratirg the said chamber. (AEC)

  7. Relationship between lattice disorder and non-Fermi liquid properties in annealed UCu_4Pd

    NASA Astrophysics Data System (ADS)

    Booth, C. H.; Scheidt, E.-W.; Weber, A.; Maurer, D.; Kehrein, S.

    2002-03-01

    The heat capacity, electrical resistivity and lattice parameter of the lattice-disordered, non-Fermi liquid (NFL) material UCu_4Pd have been shown to be sensitive to annealing time.(A. Weber et al.), Phys. Rev. B 63, 205116 (2001). We present x-ray absorption fine-structure (XAFS) measurements from the Pd K and U L_III edges that show the percentage of Pd atoms on nominally Cu 16e sites within the C15b crystal structure decreases from about 27% to 19% upon the first day of annealing, and does not change measurably with further annealing. Moreover, the U-Cu bond length distribution width, σ, narrows monotonically, with Δ σ^2 = -0.00035(3) Åafter 14 days of annealing. These changes in the local lattice properties will be related to the measured changes in the NFL properties.

  8. Golden rule kinetics of transfer reactions in condensed phase: The microscopic model of electron transfer reactions in disordered solid matrices

    SciTech Connect

    Basilevsky, M. V.; Mitina, E. A.; Odinokov, A. V.; National Research Nuclear University “MEPhI,” 31, Kashirskoye shosse, Moscow ; Titov, S. V.

    2013-12-21

    kinetic regimes, which are usually postulated in the existing theories of the ET. Our alternative dynamic ET model for local modes immersed in the continuum harmonic medium is formulated for both classical and quantum regimes, and accounts explicitly for the mode/medium interaction. The kinetics of the energy exchange between the local ET subsystem and the surrounding environment essentially determine the total ET rate. The efficient computer code for rate computations is elaborated on. The computations are available for a wide range of system parameters, such as the temperature, external field, local mode frequency, and characteristics of mode/medium interaction. The relation of the present approach to the Marcus ET theory and to the quantum-statistical reaction rate theory [V. G. Levich and R. R. Dogonadze, Dokl. Akad. Nauk SSSR, Ser. Fiz. Khim. 124, 213 (1959); J. Ulstrup, Charge Transfer in Condensed Media (Springer, Berlin, 1979); M. Bixon and J. Jortner, Adv. Chem. Phys. 106, 35 (1999)] underlying it is discussed and illustrated by the results of computations for practically important target systems.

  9. Bio-oil fractionation and condensation

    DOEpatents

    Brown, Robert C; Jones, Samuel T; Pollard, Anthony

    2013-07-02

    A method of fractionating bio-oil vapors which involves providing bio-oil vapors comprising bio-oil constituents is described. The bio-oil vapors are cooled in a first stage which comprises a condenser having passages for the bio-oil separated by a heat conducting wall from passages for a coolant. The coolant in the condenser of the first stage is maintained at a substantially constant temperature, set at a temperature in the range of 75 to 100.degree. C., to condense a first liquid fraction of liquefied bio-oil constituents in the condenser of the first stage. The first liquid fraction of liquified bio-oil constituents from the condenser in the first stage is collected. Also described are steps for subsequently recovering further liquid fractions of liquefied bio-oil constituents. Particular compositions of bio-oil condensation products are also described.

  10. Light-scattering measurement of the nematic correlation length in a liquid crystal with quenched disorder

    NASA Astrophysics Data System (ADS)

    Bellini, Tommaso; Clark, Noel A.; Degiorgio, Vittorio; Mantegazza, Francesco; Natale, Giorgio

    1998-03-01

    We have studied a composite system formed by a nematic thermotropic liquid crystal in which small silica particles have been dispersed. The colloids are aggregated and exert a randomizing effect on the nematic structure. The distorted pattern of the optical axis gives rise to a strong optical turbidity τ. We have measured τ as a function of the silica concentration Φ and of the temperature T in both the isotropic and nematic phase. We have found that, at fixed T, τ has a maximum as a function of Φ, and that, upon changing Φ, the whole shape of τ(T) drastically transforms. We have devised a model to describe the scattering of light from a distorted uniaxial system. The model has been developed both in the Born approximation and in the anomalous diffraction approximation, the two regimes which cover the broad range of experimental conditions. The family of τ(T) curves experimentally obtained at different Φ's is remarkably well described by the theoretical model, using as the only fitting parameter the correlation length ζ. We have found that, upon decreasing Φ, the nematic correlation length diverges as a power law of Φ. We compare the exponent of the power law with the prediction of the Imry-Ma theory of phase behavior in disordered systems, and we discuss the connection between ζ and the fractal correlation length of the silica aggregates.

  11. APPARATUS FOR CONDENSATION AND SUBLIMATION

    DOEpatents

    Schmidt, R.J.; Fuis, F. Jr.

    1958-10-01

    An apparatus is presented for the sublimation and condensation of uranium compounds in order to obtain an improved crystalline structure of this material. The apparatus comprises a vaporizing chamber and condensing structure connected thereto. There condenser is fitted with a removable liner having a demountable baffle attached to the liner by means of brackets and a removable pin. The baffle is of spiral cross-section and is provided with cooling coils disposed between the surfaces of the baffle for circulation of a temperature controlling liquid within the baffle. The cooling coll provides for controlllng the temperature of the baffle to insure formatlon of a satisfactory condensate, and the removable liner facilitates the removal of condensate formed during tbe sublimation process.

  12. Condensation polyimides

    NASA Technical Reports Server (NTRS)

    Hergenrother, P. M.

    1989-01-01

    Polyimides belong to a class of polymers known as polyheterocyclics. Unlike most other high temperature polymers, polyimides can be prepared from a variety of inexpensive monomers by several synthetic routes. The glass transition and crystalline melt temperature, thermooxidative stability, toughness, dielectric constant, coefficient of thermal expansion, chemical stability, mechanical performance, etc. of polyimides can be controlled within certain boundaries. This versatility has permitted the development of various forms of polyimides. These include adhesives, composite matrices, coatings, films, moldings, fibers, foams and membranes. Polyimides are synthesized through both condensation (step-polymerization) and addition (chain growth polymerization) routes. The precursor materials used in addition polyimides or imide oligomers are prepared by condensation method. High molecular weight polyimide made via polycondensation or step-growth polymerization is studied. The various synthetic routes to condensation polyimides, structure/property relationships of condensation polyimides and composite properties of condensation polyimides are all studied. The focus is on the synthesis and chemical structure/property relationships of polyimides with particular emphasis on materials for composite application.

  13. A Monte Carlo study of absorbed dose distributions in both the vapor and liquid phases of water by intermediate energy electrons based on different condensed-history transport schemes.

    PubMed

    Bousis, C; Emfietzoglou, D; Hadjidoukas, P; Nikjoo, H

    2008-07-21

    Monte Carlo transport calculations of dose point kernels (DPKs) and depth dose profiles (DDPs) in both the vapor and liquid phases of water are presented for electrons with initial energy between 10 keV and 1 MeV. The results are obtained by the MC4 code using three different implementations of the condensed-history technique for inelastic collisions, namely the continuous slowing down approximation, the mixed-simulation with delta-ray transport and the addition of straggling distributions for soft collisions derived from accurate relativistic Born cross sections. In all schemes, elastic collisions are simulated individually based on single-scattering cross sections. Electron transport below 10 keV is performed in an event-by-event mode. Differences on inelastic interactions between the vapor and liquid phase are treated explicitly using our recently developed dielectric response function which is supplemented by relativistic corrections and the transverse contribution. On the whole, the interaction coefficients used agree to better than approximately 5% with NIST/ICRU values. It is shown that condensed phase effects in both DPKs and DDPs practically vanish above 100 keV. The effect of delta-rays, although decreases with energy, is sizeable leading to more diffused distributions, especially for DPKs. The addition of straggling for soft collisions is practically inconsequential above a few hundred keV. An extensive benchmarking with other condensed-history codes is provided. PMID:18574312

  14. Condensed Matter Theories - Volume 22

    NASA Astrophysics Data System (ADS)

    Reinholz, Heidi; Röpke, Gerd; de Llano, Manuel

    2007-09-01

    pt. A. Fermi liquids. Pressure comparison between the spherical cellular model and the Thomas-Fermi model / G.A. Baker, Jr. Pair excitations and vertex corrections in Fermi fluids and the dynamic structure function of two-dimension 3He / H.M. Böhm, H. Godfrin, E. Krotscheck, H.J. Lauter, M. Meschke and M. Panholzer. Condensation of helium in wedges / E.S. Hernádez ... [et al.]. Non-Fermi liquid behavior from the Fermi-liquid approach / V.A. Khodel ... [et al.]. Theory of third sound and stability of thin 3He-4He superfluid films / E. Krotscheck and M.D. Miller. Pairing in asymmetrical Fermi systems / K.F. Quader and R. Liao. Ground-state properties of small 3He drops from quantum Monte Carlo simulations / E. Sola, J. Casulleras and J. Boronat. Ground-state energy and compressibility of a disordered two-dimensional electron gas / Tanatar ... [et al.]. Quasiexcitons in photoluminescence of incompressible quantum liquids / A. Wójs, A.G ladysiewicz and J.J. Quinn -- pt. B. Bose liquids. Quantum Boltzmann liquids / K.A. Gernoth, M L. Ristig and T. Lindenau. Condensate fraction in the dynamic structure function of Bose fluids / M. Saarela, F. Mazzanti and V. Apaja -- pt. C. Strongly-correlated electronic systems. Electron gas in high-field nanoscopic transport: metallic carbon nanotubes / F. Green and D. Neilson. Evolution and destruction of the Kondo effect in a capacitively coupled double dot system / D.E. Logan and M.R. Galpin. The method of increments-a wavefunction-based Ab-Initio correlation method for solids / B. Paulus. Fractionally charged excitations on frustrated lattices / E. Runge, F. Pollmann and P. Fulde. 5f Electrons in actinides: dual nature and photoemission spectra / G. Zwicknagl -- pt. D. Magnetism. Magnetism in disordered two-dimensional Kondo-Necklace / W. Brenig. On the de Haas-can Alphen oscillation in 2D / S. Fujita and D.L. Morabito. Dynamics in one-dimensional spin systems-density matrix reformalization group study / S. Nishimoto and M

  15. Autism Spectrum Disorder

    MedlinePlus

    ... Awards Enhancing Diversity Find People About NINDS NINDS Autism Spectrum Disorder Information Page Condensed from Autism Spectrum ... en Español Additional resources from MedlinePlus What is Autism Spectrum Disorder? Autistic disorder (sometimes called autism or ...

  16. Amino acid digestibility of corn distillers dried grains with solubles, liquid condensed solubles, pulse dried thin stillage, and syrup balls fed to growing pigs.

    PubMed

    Soares, J A; Stein, H H; Singh, V; Shurson, G S; Pettigrew, J E

    2012-04-01

    Distillers dried grains with solubles (DDGS) has low and variable AA digestibility. The variability is often attributed to damage during the heating process, and it has been suggested that the damage happens to the soluble components of DDGS such as reducing sugars. Combining solubles and grains sometimes produces syrup balls (SB); their digestibility is unknown. The objective of this experiment was to identify potential sources of poor and variable AA digestibility in DDGS. Specifically, our objective was to determine whether the problems are associated with the solubles component or with SB. The ingredients evaluated were DDGS, intact SB, ground SB, liquid condensed solubles (LCS), and pulse dried thin stillage (PDTS) obtained from the same ethanol plant. The LCS is produced by evaporation of thin stillage. Each ingredient was used as the only source of AA in an experimental diet. In a duplicate 6 × 6 Latin square design with 7-d adaptation and collection periods, the 6 treatments consisted of an N-free diet and the 5 test ingredients. Pigs had 5 d of adaptation to each diet, and on d 6 and 7 ileal digesta were collected from an ileal cannula for 8 h each day. Both SB treatments had apparent ileal digestibility (AID) and standardized ileal digestibility (SID) of AA that were similar or greater (P < 0.05) than those of DDGS. The AID and SID values of Lys and a few other AA were similar in LCS (SID Lys: 63.1%) and DDGS (SID Lys: 61.5%), but the digestibility values of most AA in LCS were less than in DDGS (P < 0.05). The low digestibility of AA in LCS was most pronounced for Met (SID: LCS, 41.9% vs. DDGS, 82.8%). The LCS had less (P < 0.05) AID and SID of CP (SID: 67.8%) than intact SB (SID: 85.2%) and ground SB (SID: 85.9%) as well as all AA. The PDTS generally had the least AID and SID and had less (P < 0.05) CP (SID: 55.3%) and several AA, including Lys, compared with LCS. In conclusion, the presence of SB does not decrease AA digestibility of DDGS, and the LCS

  17. Evaluation of Efficacy of Herbal Intrauterine Infusion Uterofix Liquid in Treatment of Various Reproductive Disorders in Cows: A Field Study

    PubMed Central

    Verma, Satinder; Choudhary, Adarsh; Maini, Shivi; Ravikanth, K.

    2016-01-01

    Objective: To evaluate the efficacy of herbal intrauterine infusion Uterofix liquid in the treatment of various reproductive disorders in cows. Materials and Methods: Based on symptoms of endometritis, anestrous, metritis, and repeat breeders, 28 cows were selected to study the efficacy of herbal intrauterine infusion Uterofix liquid (M/S Ayurvet Limited) in uterine infections study. Group T0 (n = 8) cows served as control group, no treatment was given to this group, Group T1 (n = 5) repeat breeder cows, Group T2 (n = 5) endometritis effected cows, Group T3 (n = 5) anoestrus cows, and Group T4 (n = 5) metritis suffered cows were treated with Uterofix liquid (25 ml as intrauterine infusion once a day for 3–5 days). Total observational period was 60 days. Number of treatments needed, nature of discharge in first posttreatment estrus (physical examination), after treatment number of animal showing heat/estrus out of total treated, and posttreatment conception rate were used as criteria to judge the success or failure of treatment. Results: Results revealed that 18 out of 20 animals (90%) showed signs of heat with clear discharge, recovered completely without causing any irritation, or severe irritation/sloughing of genital mucous membrane after Uterofix liquid treatment. Conclusion: Herbal intrauterine infusion Uterofix liquid significantly treated the uterine infections in cows. SUMMARY Uterine infection is a major problem in reproductive management. A wide variety of genital tract diseases of female domestic animals are known to produce significant losses and responsible for poor fertility. Amongst these highly prevalent are metritis and repeat breeding in high-producing dairy cows which if remains untreated are associated with low conception rate per artificial insemination (AI), extended interval to pregnancy, increased culling, and economic losses. As herbal remedy the Uterofix liquid (Ayurvet Limited, India) was highly efficacious as an intrauterine infusion

  18. Direct condensation refrigerant recovery and restoration system

    SciTech Connect

    Grant, D.C.H.

    1992-03-10

    This patent describes a refrigerant recovery and purification system for removing gaseous refrigerant from a disabled refrigeration unit, cleaning the refrigerant of contaminants, and converting the gaseous refrigerant to a liquid state for storage. It comprises a low pressure inlet section; a high pressure storage section; the low pressure inlet section comprising: an oil and refrigerant gas separator, including a separated oil removal means, first conduit means for connecting an inlet of the separator to the disabled refrigerant unit, a slack-sided accumulator, second conduit means connecting the separator to the slack-sided accumulator, a reclaim condenser, third conduit means connecting the separator and the reclaim condenser in series, an evaporator coil in the reclaim condenser connectable to a conventional operating refrigeration system for receiving a liquid refrigerant under pressure for expansion therein, the evaporator coil forming a condensing surface for condensing the refrigerant gas at near atmospheric pressure in the condenser, a liquid receiver, a reclaimed refrigerant storage tank, fourth conduit means further connecting the liquid receiver in series with the reclaim condenser, downstream thereof, means between the reclaim condenser and the liquid receiver.

  19. Anomalously slow relaxation of the system of strongly interacting liquid clusters in a disordered nanoporous medium: Self-organized criticality

    NASA Astrophysics Data System (ADS)

    Borman, V. D.; Tronin, V. N.

    2016-09-01

    It has been shown that changes in the energy of a system of nonwetting liquid clusters confined in a random nanoporous medium in the process of relaxation can be written in the quasiparticle approximation in the form of the sum of the energies of local (metastable) configurations of liquid clusters interacting with clusters in the connected nearest pores. The energy spectrum and density of states of the local configuration have been calculated. It has been shown that the relaxation of the state of the system occurs through the scenario of self-organized criticality (SOC). The process is characterized by the expectation of a fluctuation necessary for overcoming a local energy barrier of the metastable state with the subsequent rapid hydrodynamic extrusion of the liquid under the action of the surface buoyancy forces of the nonwetting framework. In this case, the dependence of the interaction between local configurations on the number of filled pores belonging to the infinite percolation cluster of filled pores serves as an internal feedback initiating the SOC process. The calculations give a power-law time dependence of the relative volume of the confined liquid θ ∼t-α(α ∼ 0.1) . The developed model of the relaxation of the porous medium with the nonwetting liquid demonstrates possible mechanisms and scenarios of SOC for disordered atomic systems.

  20. Film condensation in a horizontal rectangular duct

    NASA Technical Reports Server (NTRS)

    Lu, Qing; Suryanarayana, N. V.

    1992-01-01

    Condensation heat transfer in an annular flow regime with and without interfacial waves was experimentally investigated. The study included measurements of heat transfer rate with condensation of vapor flowing inside a horizontal rectangular duct and experiments on the initiation of interfacial waves in condensation, and adiabatic air-liquid flow. An analytical model for the condensation was developed to predict condensate film thickness and heat transfer coefficients. Some conclusions drawn from the study are that the condensate film thickness was very thin (less than 0.6 mm). The average heat transfer coefficient increased with increasing the inlet vapor velocity. The local heat transfer coefficient decreased with the axial distance of the condensing surface, with the largest change at the leading edge of the test section. The interfacial shear stress, which consisted of the momentum shear stress and the adiabatic shear stress, appeared to have a significant effect on the heat transfer coefficients. In the experiment, the condensate flow along the condensing surface experienced a smooth flow, a two-dimensional wavy flow, and a three-dimensional wavy flow. In the condensation experiment, the local wave length decreased with the axial distance of the condensing surface and the average wave length decreased with increasing inlet vapor velocity, while the wave speed increased with increasing vapor velocity. The heat transfer measurements are reliable. And, the ultrasonic technique was effective for measuring the condensate film thickness when the surface was smooth or had waves of small amplitude.

  1. Condensation in Nanoporous Packed Beds.

    PubMed

    Ally, Javed; Molla, Shahnawaz; Mostowfi, Farshid

    2016-05-10

    In materials with tiny, nanometer-scale pores, liquid condensation is shifted from the bulk saturation pressure observed at larger scales. This effect is called capillary condensation and can block pores, which has major consequences in hydrocarbon production, as well as in fuel cells, catalysis, and powder adhesion. In this study, high pressure nanofluidic condensation studies are performed using propane and carbon dioxide in a colloidal crystal packed bed. Direct visualization allows the extent of condensation to be observed, as well as inference of the pore geometry from Bragg diffraction. We show experimentally that capillary condensation depends on pore geometry and wettability because these factors determine the shape of the menisci that coalesce when pore filling occurs, contrary to the typical assumption that all pore structures can be modeled as cylindrical and perfectly wetting. We also observe capillary condensation at higher pressures than has been done previously, which is important because many applications involving this phenomenon occur well above atmospheric pressure, and there is little, if any, experimental validation of capillary condensation at such pressures, particularly with direct visualization. PMID:27115446

  2. Dielectric strength of sulfur hexafluoride upon condensation

    SciTech Connect

    Antonov, A.V.; Lyapin, A.G.; Popkov, V.I.

    1983-01-01

    The behavior of sulfur hexafluoride in a sealed high-voltage device has been modeled for cooling to the condensation point of the insulating medium. The temperature dependences of the breakdown voltages of sulfur hexafluoride have been investigated for several interelectrode separations. The dielectric strength has been shown to decrease upon condensation with formation of a bridge of boiling liquid phase between the electrodes.

  3. Cooling-Trough Condenser for Sublimation Tubes

    NASA Astrophysics Data System (ADS)

    Eisenbraun, E. J.; Lucas, J. M.

    1995-11-01

    A wrap-around, trough condenser for use with large diameter (2.5") sublimation tubes is described. The design permits attachment of the condenser to the sublimation tube without removing the tube from the heater. It also permits the use of a variety of liquid (tap water, Dry Ice, and alcohol or acetone) or solid (ice or Dry Ice) coolants.

  4. Pade spectroscopy of structural correlation functions: Application to liquid gallium

    NASA Astrophysics Data System (ADS)

    Chtchelkatchev, N. M.; Klumov, B. A.; Ryltsev, R. E.; Khusnutdinoff, R. M.; Mokshin, A. V.

    2016-03-01

    We propose the new method of fluid structure investigation based on numerical analytic continuation of structural correlation functions with Pade approximants. The method particularly allows extracting hidden structural features of disordered condensed matter systems from experimental diffraction data. The method has been applied to investigate the local order of liquid gallium, which has a non-trivial structure in both the liquid and solid states. Processing the correlation functions obtained from molecular dynamic simulations, we show the method proposed reveals non-trivial structural features of liquid gallium such as the spectrum of length-scales and the existence of different types of local clusters in the liquid.

  5. Condensed Plasmas under Microgravity

    NASA Technical Reports Server (NTRS)

    Morfill, G. E.; Thomas, H. M.; Konopka, U.; Rothermel, H.; Zuzic, M.; Ivlev, A.; Goree, J.; Rogers, Rick (Technical Monitor)

    1999-01-01

    Experiments under microgravity conditions were carried out to study 'condensed' (liquid and crystalline) states of a colloidal plasma (ions, electrons, and charged microspheres). Systems with approximately 10(exp 6) microspheres were produced. The observed systems represent new forms of matter--quasineutral, self-organized plasmas--the properties of which are largely unexplored. In contrast to laboratory measurements, the systems under microgravity are clearly three dimensional (as expected); they exhibit stable vortex flows, sometimes adjacent to crystalline regions, and a central 'void,' free of microspheres.

  6. Condensation of Chondrules: Conditions for "Fiery Rain"

    NASA Astrophysics Data System (ADS)

    Grossman, L.; Fedkin, A. V.

    2012-09-01

    Equilibrium calculations at total pressures ≥1 bar in systems with CI dust enrichments of 1000 relative to solar composition, yield condensate assemblages whose olivine and coexisting silicate liquid have compositions found in primitive chondrules.

  7. Investigation into the determination of trimethylarsine in natural gas and its partitioning into gas and condensate phases using (cryotrapping)/gas chromatography coupled to inductively coupled plasma mass spectrometry and liquid/solid sorption techniques

    NASA Astrophysics Data System (ADS)

    Krupp, E. M.; Johnson, C.; Rechsteiner, C.; Moir, M.; Leong, D.; Feldmann, J.

    2007-09-01

    Speciation of trialkylated arsenic compunds in natural gas, pressurized and stable condensate samples from the same gas well was performed using (Cryotrapping) Gas Chromatography-Inductively Coupled Plasma Mass Spectrometry. The major species in all phases investigated was found to be trimethylarsine with a highest concentration of 17.8 ng/L (As) in the gas phase and 33.2 μg/L (As) in the stable condensate phase. The highest amount of trimethylarsine (121 μg/L (As)) was found in the pressurized condensate, along with trace amounts of non-identified higher alkylated arsines. Volatile arsenic species in natural gas and its related products cause concern with regards to environment, safety, occupational health and gas processing. Therefore, interest lies in a fast and simple field method for the determination of volatile arsenicals. Here, we use simple liquid and solid sorption techniques, namely absorption in silver nitrate solution and adsorption on silver nitrate impregnated silica gel tubes followed by total arsenic determination as a promising tool for field monitoring of volatile arsenicals in natural gas and gas condensates. Preliminary results obtained for the sorption-based methods show that around 70% of the arsenic is determined with these methods in comparison to volatile arsenic determination using GC-ICP-MS. Furthermore, an inter-laboratory- and inter-method comparison was performed using silver nitrate impregnated silica tubes on 14 different gas samples with concentrations varying from below 1 to 1000 μg As/m 3 natural gas. The results obtained from the two laboratories differ in a range of 10 to 60%, but agree within the order of magnitude, which is satisfactory for our purposes.

  8. Treatment of evaporator condensates by pervaporation

    DOEpatents

    Blume, Ingo; Baker, Richard W.

    1990-01-01

    A pervaporation process for separating organic contaminants from evaporator condensate streams is disclosed. The process employs a permselective membrane that is selectively permeable to an organic component of the condensate. The process involves contacting the feed side of the membrane with a liquid condensate stream, and withdrawing from the permeate side a vapor enriched in the organic component. The driving force for the process is the in vapor pressure across the membrane. This difference may be provided for instance by maintaining a vacuum on the permeate side, or by condensing the permeate. The process offers a simple, economic alternative to other separation techniques.

  9. Polarization (ellipsometric) measurements of liquid condensate deposition and evaporation rates and dew points in flowing salt/ash-containing combustion gases

    NASA Technical Reports Server (NTRS)

    Seshadri, K.; Rosner, D. E.

    1985-01-01

    An application of an optical polarization technique in a combustion environment is demonstrated by following, in real-time, growth rates of boric oxide condensate on heated platinum ribbons exposed to seeded propane-air combustion gases. The results obtained agree with the results of earlier interference measurements and also with theoretical chemical vapor deposition predictions. In comparison with the interference method, the polarization technique places less stringent requirements on surface quality, which may justify the added optical components needed for such measurements.

  10. Dynamical thermalization and vortex formation in stirred two-dimensional Bose-Einstein condensates

    NASA Astrophysics Data System (ADS)

    Wright, T. M.; Ballagh, R. J.; Bradley, A. S.; Blakie, P. B.; Gardiner, C. W.

    2008-12-01

    We present a quantum-mechanical treatment of the mechanical stirring of Bose-Einstein condensates using classical field techniques. In our approach the condensate and excited modes are described using a Hamiltonian classical field method in which the atom number and (rotating frame) energy are strictly conserved. We simulate a T=0 quasi-two-dimensional condensate perturbed by a rotating anisotropic trapping potential. Vacuum fluctuations in the initial state provide an irreducible mechanism for breaking the initial symmetries of the condensate and seeding the subsequent dynamical instability. Highly turbulent motion develops and we quantify the emergence of a rotating thermal component that provides the dissipation necessary for the nucleation and motional damping of vortices in the condensate. Vortex lattice formation is not observed, rather the vortices assemble into a spatially disordered vortex liquid state. We discuss methods we have developed to identify the condensate in the presence of an irregular distribution of vortices, determine the thermodynamic parameters of the thermal component, and extract damping rates from the classical field trajectories.

  11. Phospholipase A2-Induced Remodeling Processes on Liquid-Ordered/Liquid-Disordered Membranes Containing Docosahexaenoic or Oleic Acid: A Comparison Study.

    PubMed

    Georgieva, Rayna; Mircheva, Kristina; Vitkova, Victoria; Balashev, Konstantin; Ivanova, Tzvetanka; Tessier, Cedric; Koumanov, Kamen; Nuss, Philippe; Momchilova, Albena; Staneva, Galya

    2016-02-23

    Vesicle cycling, which is an important biological event, involves the interplay between membrane lipids and proteins, among which the enzyme phospholipase A2 (PLA2) plays a critical role. The capacity of PLA2 to trigger the budding and fission of liquid-ordered (L(o)) domains has been examined in palmitoyl-docosahexaenoylphosphatidylcholine (PDPC) and palmitoyl-oleoylphosphatidylcholine (POPC)/sphingomyelin/cholesterol membranes. They both exhibited a L(o)/liquid-disordered (L(d)) phase separation. We demonstrated that PLA2 was able to trigger budding in PDPC-containing vesicles but not POPC ones. The enzymatic activity, line tension, and elasticity of the membrane surrounding the L(o) domains are critical for budding. The higher line tension of Lo domains in PDPC mixtures was assigned to the greater difference in order parameters of the coexisting phases. The higher amount of lysophosphatidylcholine generated by PLA2 in the PDPC-containing mixtures led to a less-rigid membrane, compared to POPC. The more elastic L(d) membranes in PDPC mixtures exert a lower counteracting force against the L(o) domain bending. PMID:26794691

  12. The effect of dependence between vapor heat capacity, specific heat of evaporation-condensation of irrigating liquid and temperature on thermodynamic parameters of processes gases

    NASA Astrophysics Data System (ADS)

    Khromova, Helen; Oparina, Irene

    2014-08-01

    The results of parameters calculations of the vapor-gas flow and droplets of irrigating liquid in application to the conditions of flue gas cooling in the reactors of the soda ash workshop at "Azot" limited company, Kemerovo, are compared.

  13. Molecular dynamics study on condensation/evaporation coefficients of chain molecules at liquid–vapor interface

    SciTech Connect

    Nagayama, Gyoko Takematsu, Masaki; Mizuguchi, Hirotaka; Tsuruta, Takaharu

    2015-07-07

    The structure and thermodynamic properties of the liquid–vapor interface are of fundamental interest for numerous technological implications. For simple molecules, e.g., argon and water, the molecular condensation/evaporation behavior depends strongly on their translational motion and the system temperature. Existing molecular dynamics (MD) results are consistent with the theoretical predictions based on the assumption that the liquid and vapor states in the vicinity of the liquid–vapor interface are isotropic. Additionally, similar molecular condensation/evaporation characteristics have been found for long-chain molecules, e.g., dodecane. It is unclear, however, whether the isotropic assumption is valid and whether the molecular orientation or the chain length of the molecules affects the condensation/evaporation behavior at the liquid–vapor interface. In this study, MD simulations were performed to study the molecular condensation/evaporation behavior of the straight-chain alkanes, i.e., butane, octane, and dodecane, at the liquid–vapor interface, and the effects of the molecular orientation and chain length were investigated in equilibrium systems. The results showed that the condensation/evaporation behavior of chain molecules primarily depends on the molecular translational energy and the surface temperature and is independent of the molecular chain length. Furthermore, the orientation at the liquid–vapor interface was disordered when the surface temperature was sufficiently higher than the triple point and had no significant effect on the molecular condensation/evaporation behavior. The validity of the isotropic assumption was confirmed, and we conclude that the condensation/evaporation coefficients can be predicted by the liquid-to-vapor translational length ratio, even for chain molecules.

  14. Liquid crystal quenched orientational disorder at an AFM-scribed alignment surface.

    PubMed

    Pendery, J S; Atherton, T J; Nobili, M; Petschek, R G; Lacaze, E; Rosenblatt, C

    2015-03-21

    A polyimide substrate was scribed using the stylus of an atomic force microscope, then covered with a nematic liquid crystal. The fiber from a near field scanning optical microscope was immersed into the liquid crystal and rastered approximately 80 nm above the surface, thereby obviating smearing effects that occur in thicker samples. By appropriate averaging of multiple data sets, a histogram of the "frozen-in" director deviation Δφ from the average easy axis was obtained, having a full-width-half-maximum of ∼0.02 rad. Additionally, the spatial autocorrelation function of Δφ was extracted, where the primary correlation length was found to be comparable to, but larger than, the liquid crystal's extrapolation length. A secondary characteristic length scale of a few μm was observed, and is thought to be an artifact due to material ejection during the scribing process. Our results demonstrate the utility of nanoscale imaging of the interface behavior inside the liquid crystal. PMID:25643289

  15. Computer simulations and liquid state theoretical studies of disorder in complex fluids

    NASA Astrophysics Data System (ADS)

    Sung, Bong June

    Disorder in complex fluids is an issue of great importance because disorder can change fluid properties significantly and one can design a new material with desired properties. Disorder in complex fluids is also of academic interest since disorder makes computer simulations and theories challenging. This thesis focuses on two types of disorders, architectural disorder in random copolymers and spatial disorder in porous media. A random copolymer consists of two or more kinds of monomers. The sequence of monomers is random and quenched by chemical bonds. The polymer reference interaction site model (PRISM) integral equation theory is extended to random copolymers and used to calculate static correlations and spinodal lines. The effect of monomer correlation strength on phase separations is investigated using several closure approximations. Inter- and intra-molecular correlation functions are estimated in a self-consistent way by combining PRISM theory with field theoretic methods to consider the conformational change. Randomly coupled multi-block copolymers that consist of random sequences of monomer blocks are also investigated. In porous media, medium particles are quenched in space. Fluid is not spatially homogeneous and one has to doubly-average properties over both medium and fluid configurations. Polymer configurations in porous media are investigated using Monte Carlo simulations and integral equation theories. The polymer size is a non-monotonic function of a media concentration. An algorithm based on Voronoi tessellation and percolation theory is developed to map pores of plasma membranes onto a lattice. The plasma membrane is modeled as a 2 dimensional porous media with immobile integral proteins as static obstacles. The pore percolation threshold is estimated and the pore connectivity is strongly correlated even for randomly distributed obstacles. The effect of media structure on pore percolation in 2 dimensional polymeric media is investigated. The pore

  16. Disorder in a quantum spin liquid: flux binding and local moment formation.

    PubMed

    Willans, A J; Chalker, J T; Moessner, R

    2010-06-11

    We study the consequences of disorder in the Kitaev honeycomb model, considering both site dilution and exchange randomness. We show that a single vacancy binds a flux and induces a local moment. This moment is polarized by an applied field h: in the gapless phase, for small h the local susceptibility diverges as χ(h)∼ln(1/h); for a pair of nearby vacancies on the same sublattice, this even increases to χ(h)∼1/(h[ln(1/h)](3/2)). By contrast, weak exchange randomness does not qualitatively alter the susceptibility but has its signature in the heat capacity, which in the gapless phase is power law in temperature with an exponent dependent on disorder strength. PMID:20867265

  17. 10% liquid human immunoglobulin (KIOVIG(®)) for immunomodulation in autoimmune disorders.

    PubMed

    Nikolov, Nikolai; Reisinger, Jürgen; Schwarz, Hans P

    2016-07-01

    Intravenous immunoglobulins have been used to treat autoimmune disorders (ADs) for over 50 years. The etiologies of various ADs are not fully understood and although intravenous immunoglobulin treatment has proved its immunomodulatory properties, the roles of proposed mechanisms of action also remain a matter of speculation. A systemic search of the literature regarding KIOVIG(®) (Baxalta US, Inc., MA, USA) use in clinical trials on patients with ADs and a detailed review of retrieved articles revealed eight relevant publications. These articles reported KIOVIG use in multifocal motor neuropathy, chronic inflammatory demyelinating polyneuropathy, idiopathic thrombocytopenic purpura, Kawasaki disease, Guillain-Barré syndrome and other autoimmune and neurologic disorders and showed that KIOVIG is an effective, safe and well-tolerated treatment in the studied populations. Nevertheless, further studies on larger patient cohorts are needed. PMID:27126341

  18. Condensation model for the ESBWR passive condensers

    SciTech Connect

    Revankar, S. T.; Zhou, W.; Wolf, B.; Oh, S.

    2012-07-01

    In the General Electric's Economic simplified boiling water reactor (GE-ESBWR) the passive containment cooling system (PCCS) plays a major role in containment pressure control in case of an loss of coolant accident. The PCCS condenser must be able to remove sufficient energy from the reactor containment to prevent containment from exceeding its design pressure following a design basis accident. There are three PCCS condensation modes depending on the containment pressurization due to coolant discharge; complete condensation, cyclic venting and flow through mode. The present work reviews the models and presents model predictive capability along with comparison with existing data from separate effects test. The condensation models in thermal hydraulics code RELAP5 are also assessed to examine its application to various flow modes of condensation. The default model in the code predicts complete condensation well, and basically is Nusselt solution. The UCB model predicts through flow well. None of condensation model in RELAP5 predict complete condensation, cyclic venting, and through flow condensation consistently. New condensation correlations are given that accurately predict all three modes of PCCS condensation. (authors)

  19. The amorphous silica-liquid water interface studied by ab initio molecular dynamics (AIMD): local organization in global disorder.

    PubMed

    Cimas, Álvaro; Tielens, Frederik; Sulpizi, Marialore; Gaigeot, Marie-Pierre; Costa, Dominique

    2014-06-18

    The structural organization of water at a model of amorphous silica-liquid water interface is investigated by ab initio molecular dynamics (AIMD) simulations at room temperature. The amorphous surface is constructed with isolated, H-bonded vicinal and geminal silanols. In the absence of water, the silanols have orientations that depend on the local surface topology (i.e. presence of concave and convex zones). However, in the presence of liquid water, only the strong inter-silanol H-bonds are maintained, whereas the weaker ones are replaced by H-bonds formed with interfacial water molecules. All silanols are found to act as H-bond donors to water. The vicinal silanols are simultaneously found to be H-bond acceptors from water. The geminal pairs are also characterized by the formation of water H-bonded rings, which could provide special pathways for proton transfer(s) at the interface. The first water layer above the surface is overall rather disordered, with three main domains of orientations of the water molecules. We discuss the similarities and differences in the structural organization of the interfacial water layer at the surface of the amorphous silica and at the surface of the crystalline (0 0 0 1) quartz surface. PMID:24863440

  20. Effect of Column Disorder on Carrier Transport in Columnar Discotic Liquid Crystal Evaluated by Applying Precisely Controlled Shear Stress

    NASA Astrophysics Data System (ADS)

    Kim, Jaeki; Yamasaki, Naoyuki; Hayashi, Takeshi; Katayama, Mitsuyoshi; Yoshida, Hiroyuki; Moritake, Hiroshi; Fujii, Akihiko; Ozaki, Masanori

    2013-10-01

    The effect of column disorder on carrier drift mobility in columnar discotic liquid crystals has been investigated by applying a precisely controlled oscillating shear stress. Drift mobilities on the order of 10-1 cm2.V-1.s-1 were confirmed for positive and negative carriers in the columnar phase of 1,4,8,11,15,18,22,25-octahexylphthalocyanine in a well-aligned homeotropic geometry, in which the columnar axis was perfectly perpendicular to substrates with an electrode. A slight tilt of the columnar axis upon applying shear stress led to a marked decrease in electronic carrier mobility from 10-1 to less than 10-6 cm2.V-1.s-1, and transport was only confirmed for positive ion carriers. This result indicates that a uniform shear stress blocks the carrier transport path in the entire area of the electrode, and one-dimensional carrier transport path along the columns is easily hindered in columnar discotic liquid crystals.

  1. Kondo spin liquid in the Kondo necklace model: Classical disordered phase versus symmetry-protected topological state

    NASA Astrophysics Data System (ADS)

    Zhong, Yin; Wang, Yu-Feng; Lu, Han-Tao; Luo, Hong-Gang

    2014-08-01

    We have studied Kondo spin liquid phase of Kondo necklace models from the perspective of quantum O(N) non-linear sigma model (NLSM) field theory, particularly we focus on its possible topologically nontrivial phases. In the one-dimensional case, the Kondo spin liquid phase is a usual quantum disordered phase in contrast to the well-known topologically nontrivial Haldane phase due to destructive interference effect of topological θ term. In the two-dimensional case, the system can be mapped onto an O(4)-like NLSM with some O(3) anisotropy. Interestingly, if hedgehog-like point defects are included together with the restoration of the full O(4) symmetry, our model is identical to a kind of SU(2) symmetry-protected topological (SPT) state, which highlights a possible link between the extended Kondo necklace models and the desirable SPT states. Additionally, if the system has the expanded O(5) symmetry instead, the effective NLSM with the Wess-Zumino-Witten term is just a description of the surface modes of a three-dimensional SPT state. The deviations from fully symmetrical cases are discussed. We expect that the results might provide useful threads to identify certain microscopic bilayer antiferromagnet models (and related materials), which can support the SPT states.

  2. Spin liquid state in the disordered triangular lattice Sc2Ga2CuO7 revealed by NMR

    DOE PAGESBeta

    Khuntia, P.; Kumar, R.; Mahajan, A. V.; Baenitz, M.; Furukawa, Y.

    2016-04-18

    We present microscopic magnetic properties of a two-dimensional triangular lattice Sc2Ga2CuO7, consisting of single and double triangular Cu planes. An antiferromagnetic (AFM) exchange interaction J/kB ≈ 35 K between Cu2+ (S = 1/2) spins in the triangular biplane is obtained from the analysis of intrinsic magnetic susceptibility data. The intrinsic magnetic susceptibility, extracted from 71Ga NMR shift data, displays the presence of AFM short range spin correlations and remains finite down to 50 mK, suggesting a nonsinglet ground state. The nuclear spin-lattice relaxation rate (1/T1) reveals a slowing down of Cu2+ spin fluctuations with decreasing T down to 100 mK.more » Magnetic specific heat (Cm) and 1/T1 exhibit power law behavior at low temperatures, implying the gapless nature of the spin excitation spectrum. The absence of long range magnetic ordering down to ~J/700, nonzero spin susceptibility at low T, and the power law behavior of Cm and 1/T1 suggest a gapless quantum spin liquid (QSL) state. Our results demonstrate that persistent spin dynamics induced by frustration maintain a quantum-disordered state at T → 0 in this triangular lattice antiferromagnet. Furthermore, this suggests that the low energy modes are dominated by spinon excitations in the QSL state due to randomness engendered by disorder and frustration.« less

  3. Spin liquid state in the disordered triangular lattice Sc2Ga2CuO7 revealed by NMR

    NASA Astrophysics Data System (ADS)

    Khuntia, P.; Kumar, R.; Mahajan, A. V.; Baenitz, M.; Furukawa, Y.

    2016-04-01

    We present microscopic magnetic properties of a two-dimensional triangular lattice Sc2Ga2CuO7 , consisting of single and double triangular Cu planes. An antiferromagnetic (AFM) exchange interaction J /kB≈35 K between Cu2 + (S =1 /2 ) spins in the triangular biplane is obtained from the analysis of intrinsic magnetic susceptibility data. The intrinsic magnetic susceptibility, extracted from 71Ga NMR shift data, displays the presence of AFM short range spin correlations and remains finite down to 50 mK, suggesting a nonsinglet ground state. The nuclear spin-lattice relaxation rate (1 /T1 ) reveals a slowing down of Cu2 + spin fluctuations with decreasing T down to 100 mK. Magnetic specific heat (Cm) and 1 /T1 exhibit power law behavior at low temperatures, implying the gapless nature of the spin excitation spectrum. The absence of long range magnetic ordering down to ˜J /700 , nonzero spin susceptibility at low T , and the power law behavior of Cm and 1 /T1 suggest a gapless quantum spin liquid (QSL) state. Our results demonstrate that persistent spin dynamics induced by frustration maintain a quantum-disordered state at T →0 in this triangular lattice antiferromagnet. This suggests that the low energy modes are dominated by spinon excitations in the QSL state due to randomness engendered by disorder and frustration.

  4. Liquid polymorphism, order-disorder transitions and anomalous behavior: A Monte Carlo study of the Bell-Lavis model for water

    NASA Astrophysics Data System (ADS)

    Fiore, Carlos E.; Szortyka, Marcia M.; Barbosa, Marcia C.; Henriques, Vera B.

    2009-10-01

    The Bell-Lavis model for liquid water is investigated through numerical simulations. The lattice-gas model on a triangular lattice presents orientational states and is known to present a highly bonded low density phase and a loosely bonded high density phase. We show that the model liquid-liquid transition is continuous, in contradiction with mean-field results on the Husimi cactus and from the cluster variational method. We define an order parameter which allows interpretation of the transition as an order-disorder transition of the bond network. Our results indicate that the order-disorder transition is in the Ising universality class. Previous proposal of an Ehrenfest second order transition is discarded. A detailed investigation of anomalous properties has also been undertaken. The line of density maxima in the HDL phase is stabilized by fluctuations, absent in the mean-field solution.

  5. Film condensation in a horizontal rectangular duct

    NASA Technical Reports Server (NTRS)

    Lu, Qing; Suryanarayana, N. V.

    1993-01-01

    Condensation heat transfer in a horizontal rectangular duct was experimentally and analytically investigated. To prevent the dripping of condensate on the film, the experiment was conducted inside a horizontal rectangular duct with vapor condensing only on the bottom cooled plate of the duct. R-113 and FC-72 (Fluorinert Electronic Fluid developed by the 3M Company) were used as the condensing fluids. The experimental program included measurements of film thickness, local and average heat transfer coefficients, wave length, wave speed, and a study of wave initiation. The measured film thickness was used to obtain the local heat transfer coefficient. The wave initiation was studied both with condensation and with an adiabatic air-liquid flow. The test sections used in both experiments were identical.

  6. Method and apparatus for high-efficiency direct contact condensation

    DOEpatents

    Bharathan, Desikan; Parent, Yves; Hassani, A. Vahab

    1999-01-01

    A direct contact condenser having a downward vapor flow chamber and an upward vapor flow chamber, wherein each of the vapor flow chambers includes a plurality of cooling liquid supplying pipes and a vapor-liquid contact medium disposed thereunder to facilitate contact and direct heat exchange between the vapor and cooling liquid. The contact medium includes a plurality of sheets arranged to form vertical interleaved channels or passageways for the vapor and cooling liquid streams. The upward vapor flow chamber also includes a second set of cooling liquid supplying pipes disposed beneath the vapor-liquid contact medium which operate intermittently in response to a pressure differential within the upward vapor flow chamber. The condenser further includes separate wells for collecting condensate and cooling liquid from each of the vapor flow chambers. In alternate embodiments, the condenser includes a cross-current flow chamber and an upward flow chamber, a plurality of upward flow chambers, or a single upward flow chamber. The method of use of the direct contact condenser of this invention includes passing a vapor stream sequentially through the downward and upward vapor flow chambers, where the vapor is condensed as a result of heat exchange with the cooling liquid in the contact medium. The concentration of noncondensable gases in the resulting condensate-liquid mixtures can be minimized by controlling the partial pressure of the vapor, which depends in part upon the geometry of the vapor-liquid contact medium. In another aspect of this invention, the physical and chemical performance of a direct contact condenser can be predicted based on the vapor and coolant compositions, the condensation conditions. and the geometric properties of the contact medium.

  7. Method and apparatus for high-efficiency direct contact condensation

    DOEpatents

    Bharathan, D.; Parent, Y.; Hassani, A.V.

    1999-07-20

    A direct contact condenser having a downward vapor flow chamber and an upward vapor flow chamber, wherein each of the vapor flow chambers includes a plurality of cooling liquid supplying pipes and a vapor-liquid contact medium disposed thereunder to facilitate contact and direct heat exchange between the vapor and cooling liquid. The contact medium includes a plurality of sheets arranged to form vertical interleaved channels or passageways for the vapor and cooling liquid streams. The upward vapor flow chamber also includes a second set of cooling liquid supplying pipes disposed beneath the vapor-liquid contact medium which operate intermittently in response to a pressure differential within the upward vapor flow chamber. The condenser further includes separate wells for collecting condensate and cooling liquid from each of the vapor flow chambers. In alternate embodiments, the condenser includes a cross-current flow chamber and an upward flow chamber, a plurality of upward flow chambers, or a single upward flow chamber. The method of use of the direct contact condenser of this invention includes passing a vapor stream sequentially through the downward and upward vapor flow chambers, where the vapor is condensed as a result of heat exchange with the cooling liquid in the contact medium. The concentration of noncondensable gases in the resulting condensate-liquid mixtures can be minimized by controlling the partial pressure of the vapor, which depends in part upon the geometry of the vapor-liquid contact medium. In another aspect of this invention, the physical and chemical performance of a direct contact condenser can be predicted based on the vapor and coolant compositions, the condensation conditions, and the geometric properties of the contact medium. 39 figs.

  8. Optimizing process vacuum condensers

    SciTech Connect

    Lines, J.R.; Tice, D.W.

    1997-09-01

    Vacuum condensers play a critical role in supporting vacuum processing operations. Although they may appear similar to atmospheric units, vacuum condensers have their own special designs, considerations and installation needs. By adding vacuum condensers, precondensers and intercondensers, system cost efficiency can be optimized. Vacuum-condensing systems permit reclamation of high-value product by use of a precondenser, or reduce operating costs with intercondensers. A precondenser placed between the vacuum vessel and ejector system will recover valuable process vapors and reduce vapor load to an ejector system--minimizing the system`s capital and operating costs. Similarly, an intercondenser positioned between ejector stages can condense motive steam and process vapors and reduce vapor load to downstream ejectors as well as lower capital and operating costs. The paper describes vacuum condenser systems, types of vacuum condensers, shellside condensing, tubeside condensing, noncondensable gases, precondenser pressure drop, system interdependency, equipment installation, and equipment layout.

  9. CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES: Study of Thermodynamics of Liquid Noble-Metals Alloys Through a Pseudopotential Theory

    NASA Astrophysics Data System (ADS)

    Vora, Aditya M.

    2010-09-01

    The Gibbs-Bogoliubov (GB) inequality is applied to investigate the thermodynamic properties of some equiatomic noble metal alloys in liquid phase such as Au-Cu, Ag-Cu, and Ag-Au using well recognized pseudopotential formalism. For description of the structure, well known Percus-Yevick (PY) hard sphere model is used as a reference system. By applying a variation method the best hard core diameters have been found which correspond to minimum free energy. With this procedure the thermodynamic properties such as entropy and heat of mixing have been computed. The influence of local field correction function viz; Hartree (H), Taylor (T), Ichimaru-Utsumi (IU), Farid et al. (F), and Sarkar et al. (S) is also investigated. The computed results of the excess entropy compares favourably in the case of liquid alloys while the agreement with experiment is poor in the case of heats of mixing. This may be due to the sensitivity of the heats of mixing with the potential parameters and the dielectric function.

  10. Anomalously slow relaxation of the system of liquid clusters in a disordered nanoporous medium according to the self-organized criticality scenario

    NASA Astrophysics Data System (ADS)

    Borman, V. D.; Tronin, V. N.; Byrkin, V. A.

    2016-04-01

    We propose a physical model of a relaxation of states of clusters of nonwetting liquid confined in a random nanoporous medium. The relaxation is occurred by the self-organized criticality (SOC) scenario. Process is characterized by waiting for fluctuation necessary for overcoming of a local energy barrier with the subsequent avalanche hydrodynamic extrusion of the liquid by surface forces of the nonwetting frame. The dependence of the interaction between local configurations on the number of filled pores belonging to the infinite percolation cluster of filled pores serves as an internal feedback initiating the SOC process. The calculations give a power-law time dependence of the relative volume θ of the confined liquid θ ∼t-ν (ν ∼ 0.2) as in the picture of relaxation in the mean field approximation. The model of the relaxation of the porous medium with the nonwetting liquid demonstrates possible mechanisms and scenarios of SOC for relaxation of other disordered systems.

  11. PERVAPORATION SEPARATION IMPROVEMENTS VIA FRACTIONAL CONDENSATION (DEPHLEGMATION): IMPACT OF DEPHLEGMATOR DESIGN ON PERFORMANCE

    EPA Science Inventory

    Traditionally, pervaporation systems have been operated using a total condenser to deliver the final permeate liquid product. Over the past two years, we have investigated the use of a condensation process called "dephlegmation" to enhance the separation performance of pervapora...

  12. Experimental evidence supporting the insensitivity of cloud droplet formation to the mass accommodation coefficient for condensation of water vapor to liquid water

    NASA Astrophysics Data System (ADS)

    Langridge, Justin M.; Richardson, Mathews S.; Lack, Daniel A.; Murphy, Daniel M.

    2016-06-01

    The mass accommodation coefficient for uptake of water vapor to liquid water, αM, has been constrained using photoacoustic measurements of aqueous absorbing aerosol. Measurements performed over a range of relative humidities and pressures were compared to detailed model calculations treating coupled heat and mass transfer occurring during photoacoustic laser heating cycles. The strengths and weaknesses of this technique are very different to those for droplet growth/evaporation experiments that have typically been applied to these measurements, making this a useful complement to existing studies. Our measurements provide robust evidence that αM is greater than 0.1 for all humidities tested and greater than 0.3 for data obtained at relative humidities greater than 88% where the aerosol surface was most like pure water. These values of αM are above the threshold at which kinetic limitations are expected to impact the activation and growth of aerosol particles in warm cloud formation.

  13. Condensed Matter Nuclear Science

    NASA Astrophysics Data System (ADS)

    Biberian, Jean-Paul

    2006-02-01

    into characteristics of X-ray emission laser beams from solidstate cathode medium of high-current glow discharge / A. B. Karabut. Charged particles from Ti and Pd foils / L. Kowalski ... [et al.]. Cr-39 track detectors in cold fusion experiments: review and perspectives / A. S. Roussetski. Energetic particle shower in the vapor from electrolysis / R. A. Oriani and J. C. Fisher. Nuclear reactions produced in an operating electrolysis cell / R. A. Oriani and J. C. Fisher. Evidence of microscopic ball lightning in cold fusion experiments / E. H. Lewis. Neutron emission from D[symbol] gas in magnetic fields under low temperature / T. Mizuno ... [et al.]. Energetic charged particle emission from hydrogen-loaded Pd and Ti cathodes and its enhancement by He-4 implantation / A. G. Lipson ... [et al.]. H-D permeation. Observation of nuclear transmutation reactions induced by D[symbol] gas permeation through Pd complexes / Y. Iwamura ... [et al.]. Deuterium (hydrogen) flux permeating through palladium and condensed matter nuclear science / Q. M. Wei ... [et al.]. Triggering. Precursors and the fusion reactions in polarized Pd/D-D[symbol]O system: effect of an external electric field / S. Szpak, P. A. Mosier-Boss, and F. E. Gordon. Calorimetric and neutron diagnostics of liquids during laser irradiation / Yu. N. Bazhutov ... [et al.]. Anomalous neutron capture and plastic deformation of Cu and Pd cathodes during electrolysis in a weak thermalized neutron field: evidence of nuclei-lattice exchange / A. G. Lipson and G. H. Miley. H-D loading. An overview of experimental studies on H/Pd over-loading with thin Pd wires and different electrolytic solutions / A. Spallone ... [et al.] -- 3. Transmutations. Photon and particle emission, heat production, and surface transformation in Ni-H system / E. Campari ... [et al.]. Surface analysis of hydrogen-loaded nickel alloys / E. Campari ... [et al.]. Low-energy nuclear reactions and the leptonic monopole / G. Lochak and L. Urutskoev. Results

  14. Condensates in Jovian Atmospheres

    NASA Technical Reports Server (NTRS)

    West, R.

    1999-01-01

    Thermochemical equilibrium theory which starts with temperature/pressure profiles, compositional information and thermodynamic data for condensable species in the jovian planet atmospheres predicts layers of condensate clouds in the upper troposphere.

  15. Classification of congenital disorders of glycosylation based on analysis of transferrin glycopeptides by capillary liquid chromatography-mass spectrometry.

    PubMed

    Barroso, Albert; Giménez, Estela; Benavente, Fernando; Barbosa, José; Sanz-Nebot, Victoria

    2016-11-01

    In this work, we describe a multivariate data analysis approach for data exploration and classification of the complex and large data sets generated to study the alteration of human transferrin (Tf) N-glycopeptides in patients with congenital disorders of glycosylation (CDG). Tf from healthy individuals and two types of CDG patients (CDG-I and CDG-II) is purified by immunoextraction from serum samples before trypsin digestion and separation by capillary liquid chromatography mass spectrometry (CapLC-MS). Following a targeted data analysis approach, partial least squares discriminant analysis (PLS-DA) is applied to the relative abundance of Tf glycopeptide glycoforms obtained after integration of the extracted ion chromatograms of the different samples. The performance of PLS-DA for classification of the different samples and for providing a novel insight into Tf glycopeptide glycoforms alteration in CDGs is demonstrated. Only six out of fourteen of the detected glycoforms are enough for an accurate classification. This small glycoform set may be considered a sensitive and specific novel biomarker panel for CDGs. PMID:27591658

  16. Discovery and validation of plasma biomarkers for major depressive disorder classification based on liquid chromatography-mass spectrometry.

    PubMed

    Liu, Xinyu; Zheng, Peng; Zhao, Xinjie; Zhang, Yuqing; Hu, Chunxiu; Li, Jia; Zhao, Jieyu; Zhou, Jingjing; Xie, Peng; Xu, Guowang

    2015-05-01

    Major depressive disorder (MDD) is a debilitating mental disease with a pronounced impact on the quality of life of many people; however, it is still difficult to diagnose MDD accurately. In this study, a nontargeted metabolomics approach based on ultra-high-performance liquid chromatography equipped with quadrupole time-of-flight mass spectrometry (UPLC-Q-TOF/MS) was used to find the differential metabolites in plasma samples from patients with MDD and healthy controls. Furthermore, a validation analysis focusing on the differential metabolites was performed in another batch of samples using a targeted approach based on the dynamic multiple reactions monitoring method. Levels of acyl carnitines, ether lipids, and tryptophan pronouncedly decreased, whereas LPCs, LPEs, and PEs markedly increased in MDD subjects as compared with the healthy controls. Disturbed pathways, mainly located in acyl carnitine metabolism, lipid metabolism, and tryptophan metabolism, were clearly brought to light in MDD subjects. The binary logistic regression result showed that carnitine C10:1, PE-O 36:5, LPE 18:1 sn-2, and tryptophan can be used as a combinational biomarker to distinguish not only moderate but also severe MDD from healthy control with good sensitivity and specificity. Our findings, on one hand, provide critical insight into the pathological mechanism of MDD and, on the other hand, supply a combinational biomarker to aid the diagnosis of MDD in clinical usage. PMID:25784130

  17. Disorder-Driven Spin-Orbital Liquid Behavior in the Ba3X Sb2O9 Materials

    NASA Astrophysics Data System (ADS)

    Smerald, Andrew; Mila, Frédéric

    2015-10-01

    Recent experiments on the Ba3X Sb2O9 family have revealed materials that potentially realize spin- and spin-orbital liquid physics. However, the lattice structure of these materials is complicated due to the presence of charged X2 +-Sb5 + dumbbells, with two possible orientations. To model the lattice structure, we consider a frustrated model of charged dumbbells on the triangular lattice, with long-range Coulomb interactions. We study this model using Monte Carlo simulation, and find a freezing temperature, Tfrz , at which the simulated structure factor matches well to low-temperature x-ray diffraction data for Ba3 CuSb2 O9 . At T =Tfrz we find a complicated "branching" structure of superexchange-linked X2 + clusters, which form a fractal pattern with fractal dimension df=1.90 . We show that this gives a natural explanation for the presence of orphan spins. Finally we provide a plausible mechanism by which such dumbbell disorder can promote a spin-orbital resonant state with delocalized orphan spins.

  18. Condensed matter analogues of cosmology

    NASA Astrophysics Data System (ADS)

    Kibble, Tom; Srivastava, Ajit

    2013-10-01

    It is always exciting when developments in one branch of physics turn out to have relevance in a quite different branch. It would be hard to find two branches farther apart in terms of energy scales than early-universe cosmology and low-temperature condensed matter physics. Nevertheless ideas about the formation of topological defects during rapid phase transitions that originated in the context of the very early universe have proved remarkably fruitful when applied to a variety of condensed matter systems. The mathematical frameworks for describing these systems can be very similar. This interconnection has led to a deeper understanding of the phenomena in condensed matter systems utilizing ideas from cosmology. At the same time, one can view these condensed matter analogues as providing, at least in a limited sense, experimental access to the phenomena of the early universe for which no direct probe is possible. As this special issue well illustrates, this remains a dynamic and exciting field. The basic idea is that when a system goes through a rapid symmetry-breaking phase transition from a symmetric phase into one with spontaneously broken symmetry, the order parameter may make different choices in different regions, creating domains that when they meet can trap defects. The scale of those domains, and hence the density of defects, is constrained by the rate at which the system goes through the transition and the speed with which order parameter information propagates. This is what has come to be known as the Kibble-Zurek mechanism. The resultant scaling laws have now been tested in a considerable variety of different systems. The earliest experiments illustrating the analogy between cosmology and condensed matter were in liquid crystals, in particular on the isotropic-to-nematic transition, primarily because it is very easy to induce the phase transition (typically at room temperature) and to image precisely what is going on. This field remains one of the

  19. CFD simulation of water vapour condensation in the presence of non-condensable gas in vertical cylindrical condensers.

    PubMed

    Li, Jun-De

    2013-02-01

    This paper presents the simulation of the condensation of water vapour in the presence of non-condensable gas using computational fluid dynamics (CFD) for turbulent flows in a vertical cylindrical condenser tube. The simulation accounts for the turbulent flow of the gas mixture, the condenser wall and the turbulent flow of the coolant in the annular channel with no assumptions of constant wall temperature or heat flux. The condensate film is assumed to occupy a negligible volume and its effect on the condensation of the water vapour has been taken into account by imposing a set of boundary conditions. A new strategy is used to overcome the limitation of the currently available commercial CFD package to solve the simultaneous simulation of flows involving multispecies and fluids of gas and liquid in separate channels. The results from the CFD simulations are compared with the experimental results from the literature for the condensation of water vapour with air as the non-condensable gas and for inlet mass fraction of the water vapour from 0.66 to 0.98. The CFD simulation results in general agree well with the directly measured quantities and it is found that the variation of heat flux in the condenser tube is more complex than a simple polynomial curve fit. The CFD results also show that, at least for flows involving high water vapour content, the axial velocity of the gas mixture at the interface between the gas mixture and the condensate film is in general not small and cannot be neglected. PMID:24850953

  20. CFD simulation of water vapour condensation in the presence of non-condensable gas in vertical cylindrical condensers

    PubMed Central

    Li, Jun-De

    2013-01-01

    This paper presents the simulation of the condensation of water vapour in the presence of non-condensable gas using computational fluid dynamics (CFD) for turbulent flows in a vertical cylindrical condenser tube. The simulation accounts for the turbulent flow of the gas mixture, the condenser wall and the turbulent flow of the coolant in the annular channel with no assumptions of constant wall temperature or heat flux. The condensate film is assumed to occupy a negligible volume and its effect on the condensation of the water vapour has been taken into account by imposing a set of boundary conditions. A new strategy is used to overcome the limitation of the currently available commercial CFD package to solve the simultaneous simulation of flows involving multispecies and fluids of gas and liquid in separate channels. The results from the CFD simulations are compared with the experimental results from the literature for the condensation of water vapour with air as the non-condensable gas and for inlet mass fraction of the water vapour from 0.66 to 0.98. The CFD simulation results in general agree well with the directly measured quantities and it is found that the variation of heat flux in the condenser tube is more complex than a simple polynomial curve fit. The CFD results also show that, at least for flows involving high water vapour content, the axial velocity of the gas mixture at the interface between the gas mixture and the condensate film is in general not small and cannot be neglected. PMID:24850953

  1. Anderson and Condensed Matter Physics

    NASA Astrophysics Data System (ADS)

    Ramakrishnan, T. V.

    The legacy of P. W. Anderson, perhaps the most fertile and influential condensed matter physicist of the second half of the twentieth century, is briefly mentioned here. I note three pervasive values. They are: emergence with its constant tendency to surprise us and to stretch our imagination, the Baconian emphasis on the experimental moorings of modern science, and mechanism as the explanatory core. Out of his work, which is spread over more than six decades and in many ways has charted modern condensed matter physics, nearly a dozen seminal contributions, chosen idiosyncratically, are mentioned at the risk of leaving out many which may also have started subfields. Some of these are: antiferromagnestism and broken symmetry, superexchange and strong electron correlations, localization in disordered systems, gauge invariance and mass, and the resonating valence bond in magnetic systems as well as in high-temperature superconductivity...

  2. Detection and Quantification of Benzothiazoles in Exhaled Breath and Exhaled Breath Condensate by Real-Time Secondary Electrospray Ionization-High-Resolution Mass Spectrometry and Ultra-High Performance Liquid Chromatography.

    PubMed

    García-Gómez, Diego; Bregy, Lukas; Nussbaumer-Ochsner, Yvonne; Gaisl, Thomas; Kohler, Malcolm; Zenobi, Renato

    2015-10-20

    2-Subtituted benzothiazoles are widely used industrial chemicals whose occurrence in environmental samples has been shown to be ubiquitous. However, knowledge about human exposure to these compounds and their excretion route is still scarce. Here, we demonstrate for the first time the detection of benzothiazole derivatives in exhaled breath. Real-time analysis of breath was carried out by means of secondary electrospray ionization coupled to high-resolution mass spectrometry. This coupling allowed not only the detection of these compounds in breath with a sensitivity in the pptv range but also their robust identification by comparing tandem high-resolution mass spectra from breath and standards. For further confirmation, benzothiazoles were also determined in exhaled breath condensate samples by means of ultra high-performance liquid chromatography. This approach strengthened the identification as a result of excellent matches in retention times and also allowed quantification. An estimated total daily exhalation of ca. 20 μg day(-1) was calculated for the six benzothiazole derivatives found in breath. PMID:26390299

  3. Predictive thermodynamics for condensed phases.

    PubMed

    Glasser, Leslie; Jenkins, H Donald Brooke

    2005-10-01

    Thermodynamic information is central to assessment of the stability and reactivity of materials. However, because of both the demanding nature of experimental thermodynamics and the virtually unlimited number of conceivable compounds, experimental data is often unavailable or, for hypothetical materials, necessarily impossible to obtain. We describe simple procedures for thermodynamic prediction for condensed phases, both ionic and organic covalent, principally via formula unit volumes (or density); our volume-based approach (VBT) provides a new thermodynamic tool for such assessment. These methods, being independent of detailed knowledge of crystal structures, are applicable to liquids and amorphous materials as well as to crystalline solids. Examples of their use are provided. PMID:16172676

  4. Vortices in Spontaneous Bose-Einstein Condensates of Exciton-Polaritons

    NASA Astrophysics Data System (ADS)

    Deveaud-Plédran, Benoit; Lagoudakis, Konstantinos G.

    One of the most striking quantum effects in an interacting Bose gas at low temperature is superfluidity. First observed in liquid 4He, this phenomenon has been intensively studied in a variety of systems for its remarkable features such as the persistence of superflows and the proliferation of quantized vortices. The achievement of Bose-Einstein condensation in dilute atomic gases provided the opportunity to observe and study superfluidity in an extremely clean and well-controlled environment. In the solid state, Bose-Einstein condensation of exciton polaritons now allows to plan for the observation of similar phenomenology. Polaritons are interacting light-matter quasiparticles that occur naturally in semiconductor microcavities in the strong coupling regime and constitute an interesting example of composite bosons. Here, we report the observation of spontaneous formation of pinned quantized vortices in the Bose-condensed phase of a polariton fluid. Theoretical insight into the possible origin of such vortices is presented in terms of a generalized Gross-Pitaevskii equation. In the second part of the chapter, we provide the clear observation of half vortices, special to spinor condensates. We then go no, in the last part of this chapter, to study the dynamics of spontaneously created vortices. We show that their path is determined by the disorder landscape towards their final stable position.

  5. BES-HEP Connections: Common Problems in Condensed Matter and High Energy Physics, Round Table Discussion

    SciTech Connect

    Fradkin, Eduardo; Maldacena, Juan; Chatterjee, Lali; Davenport, James W

    2015-02-02

    On February 2, 2015 the Offices of High Energy Physics (HEP) and Basic Energy Sciences (BES) convened a Round Table discussion among a group of physicists on ‘Common Problems in Condensed Matter and High Energy Physics’. This was motivated by the realization that both fields deal with quantum many body problems, share many of the same challenges, use quantum field theoretical approaches and have productively interacted in the past. The meeting brought together physicists with intersecting interests to explore recent developments and identify possible areas of collaboration.... Several topics were identified as offering great opportunity for discovery and advancement in both condensed matter physics and particle physics research. These included topological phases of matter, the use of entanglement as a tool to study nontrivial quantum systems in condensed matter and gravity, the gauge-gravity duality, non-Fermi liquids, the interplay of transport and anomalies, and strongly interacting disordered systems. Many of the condensed matter problems are realizable in laboratory experiments, where new methods beyond the usual quasi-particle approximation are needed to explain the observed exotic and anomalous results. Tools and techniques such as lattice gauge theories, numerical simulations of many-body systems, and tensor networks are seen as valuable to both communities and will likely benefit from collaborative development.

  6. Models for water steam condensing flows

    NASA Astrophysics Data System (ADS)

    Wróblewski, Włodzimierz; Dykas, Sławomir; Chmielniak, Tadeusz

    2012-08-01

    The paper presents a description of selected models dedicated to steam condensing flow modelling. The models are implemented into an in-house computational fluid dynamics code that has been successfully applied to wet steam flow calculation for many years now. All models use the same condensation model that has been validated against the majority of available experimental data. The state equations for vapour and liquid water, the physical model as well as the numerical techniques of solution to flow governing equations have been presented. For the single-fluid model, the Reynolds-averaged Navier-Stokes equations for vapour/liquid mixture are solved, whereas the two-fluid model solves separate flow governing equations for the compressible, viscous and turbulent vapour phase and for the compressible and inviscid liquid phase. All described models have been compared with relation to the flow through the Laval nozzle.

  7. Condensation in a two-phase pool

    SciTech Connect

    Duffey, R.B.; Hughes, E.D.

    1991-12-31

    We consider the case of vapor condensation in a liquid pool, when the heat transfer is controlled by heat losses through the walls. The analysis is based on drift flux theory for phase separation in the pool, and determines the two-phase mixture height for the pool. To our knowledge this is the first analytical treatment of this classic problem that gives an explicit result, previous work having established the result for the evaporative case. From conservation of mass and energy in a one-dimensional steady flow, together with a void relation between the liquid and vapor fluxes, we determine the increase in the mixture level from the base level of the pool. It can be seen that the thermal and hydrodynamic influences are separable. Thus, the thermal influence of the wall heat transfer appears through its effect on the condensing length L*, so that at high condensation rates the pool is all liquid, and at low rates overflows (the level swell or foaming effect). Similarly, the phase separation effect hydrodynamically determines the height via the relative velocity of the mixture to the entering flux. We examine some practical applications of this result to level swell in condensing flows, and also examine some limits in ideal cases.

  8. Condensation in a two-phase pool

    SciTech Connect

    Duffey, R.B. ); Hughes, E.D. )

    1991-01-01

    We consider the case of vapor condensation in a liquid pool, when the heat transfer is controlled by heat losses through the walls. The analysis is based on drift flux theory for phase separation in the pool, and determines the two-phase mixture height for the pool. To our knowledge this is the first analytical treatment of this classic problem that gives an explicit result, previous work having established the result for the evaporative case. From conservation of mass and energy in a one-dimensional steady flow, together with a void relation between the liquid and vapor fluxes, we determine the increase in the mixture level from the base level of the pool. It can be seen that the thermal and hydrodynamic influences are separable. Thus, the thermal influence of the wall heat transfer appears through its effect on the condensing length L*, so that at high condensation rates the pool is all liquid, and at low rates overflows (the level swell or foaming effect). Similarly, the phase separation effect hydrodynamically determines the height via the relative velocity of the mixture to the entering flux. We examine some practical applications of this result to level swell in condensing flows, and also examine some limits in ideal cases.

  9. Cavity Exciton-Polaritons, Bose Einstein Condensation and Spin Dynamics

    SciTech Connect

    Malpuech, Guillaume; Solnyshkov, Dmitry; Shelykh, Ivan

    2009-10-07

    An introduction giving elementary properties of cavity exciton-polariton will be given. The condition of occurrence of the polariton lasing effect and of the polariton Bose Eintein condensation will be discussed. The impact of the structural disorder on the superfluid behavior of polariton condensates will be analysed. The spin properties of polariton condensates will be discussed. I will show how the anisotropy of the polariton-polariton interaction leads to the suppression of zeeman splitting for polariton condensates (spin Meissner effects). I will show how the combined impact of disorder and spin Meissner effect can lead to the formation of a new condense phase. I will show how these phenomena can allow for the realization of a polaritonic Datta Das spin transistor.

  10. Dissipative transport of a Bose-Einstein condensate

    SciTech Connect

    Dries, D.; Pollack, S. E.; Hitchcock, J. M.; Hulet, R. G.

    2010-09-15

    We investigate the effects of impurities, either correlated disorder or a single Gaussian defect, on the collective dipole motion of a Bose-Einstein condensate of {sup 7}Li in an optical trap. We find that this motion is damped at a rate dependent on the impurity strength, condensate center-of-mass velocity, and interatomic interactions. Damping in the Thomas-Fermi regime depends universally on the disordered potential strength scaled to the condensate chemical potential and the condensate velocity scaled to the speed of sound. The damping rate is comparatively small in the weakly interacting regime, and, in this case, is accompanied by strong condensate fragmentation. In situ and time-of-flight images of the atomic cloud provide evidence that this fragmentation is driven by dark soliton formation.

  11. Analytical Treatment of Normal Condensation Shock

    NASA Technical Reports Server (NTRS)

    Heybey

    1947-01-01

    The condensation of water vapor in an air consequences: acquisition of heat (liberated heat vaporization; loss of mass on the part of the flowing gas (water vapor is converted to liquid); change in the specific gas constants and of the ratio k of the specific heats (caused by change of gas composition). A discontinuous change of state is therefore connected with the condensation; schlieren photographs of supersonic flows in two-dimensional Laval nozzles show two intersecting oblique shock fronts that in the case of high humidities may merge near the point of intersection into one normal shock front.

  12. Measure Guideline: Evaporative Condensers

    SciTech Connect

    German, A; Dakin, B.; Hoeschele, M.

    2012-03-01

    This measure guideline on evaporative condensers provides information on properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices.

  13. Geothermal steam condensate reinjection

    NASA Technical Reports Server (NTRS)

    Chasteen, A. J.

    1974-01-01

    Geothermal electric generating plants which use condensing turbines and generate and excess of condensed steam which must be disposed of are discussed. At the Geysers, California, the largest geothermal development in the world, this steam condensate has been reinjected into the steam reservoir since 1968. A total of 3,150,000,000 gallons of steam condensate has been reinjected since that time with no noticeable effect on the adjacent producing wells. Currently, 3,700,000 gallons/day from 412 MW of installed capacity are being injected into 5 wells. Reinjection has also proven to be a satisfactory method of disposing of geothermal condensate a Imperial Valley, California, and at the Valles Caldera, New Mexico.

  14. Clustering effects of GM1 and formation mechanisms of interdigitated liquid disordered domains in GM1/SM/CHOL-supported planar bilayers on mica surfaces

    NASA Astrophysics Data System (ADS)

    Shang, Zhiguo; Mao, Yanli; Tero, Ryugo; Liu, Xinli; Hoshino, Tyuji; Tanaka, Motohiko; Urisu, Tsuneo

    2010-09-01

    We have observed by atomic force microscopy that an interdigitated liquid disordered domain (ILDD) is formed in the ganglioside (GM1)/sphingomyelin (SM)/cholesterol (CHOL) bilayers on a mica surface and accelerates the formation of fibriller Aβ agglomerates. By studies of the mechanisms using molecular dynamics simulations, we conclude that the ILDD structure is formed as a result of the phase separation to SM- and GM1-rich domains on the mica surface induced by the effects of GM1 clustering and the interaction between the GM1 head group and the water layer adsorbed in the ditrigonal cavity on the mica surface.

  15. Alpha Condensates in Atomic Nuclei

    SciTech Connect

    Suzuki, Y.; Matsumura, H.

    2005-11-21

    Recent issues on Bose-Einstein condensation (BEC) of {alpha}-particles in nuclei are reviewed. A candidate of condensates is discussed for some states in 12C and 16O by defining the amount of {alpha} condensation.

  16. High gliding fluid power generation system with fluid component separation and multiple condensers

    SciTech Connect

    Mahmoud, Ahmad M; Lee, Jaeseon; Radcliff, Thomas D

    2014-10-14

    An example power generation system includes a vapor generator, a turbine, a separator and a pump. In the separator, the multiple components of the working fluid are separated from each other and sent to separate condensers. Each of the separate condensers is configured for condensing a single component of the working fluid. Once each of the components condense back into a liquid form they are recombined and exhausted to a pump that in turn drives the working fluid back to the vapor generator.

  17. Sedimentary condensation and authigenesis

    NASA Astrophysics Data System (ADS)

    Föllmi, Karl

    2016-04-01

    Most marine authigenic minerals form in sediments, which are subjected to condensation. Condensation processes lead to the formation of well individualized, extremely thin (< 1m) beds, which were accumulated during extremely long time periods (> 100ky), and which experienced authigenesis and the precipitation of glaucony, verdine, phosphate, iron and manganese oxyhydroxides, iron sulfide, carbonate and/or silica. They usually show complex internal stratigraphies, which result from an interplay of sediment accumulation, halts in sedimentation, sediment winnowing, erosion, reworking and bypass. They may include amalgamated faunas of different origin and age. Hardgrounds may be part of condensed beds and may embody strongly condensed beds by themselves. Sedimentary condensation is the result of a hydrodynamically active depositional regime, in which sediment accumulation, winnowing, erosion, reworking and bypass are processes, which alternate as a function of changes in the location and intensity of currents, and/or as the result of episodic high-energy events engendered by storms and gravity flow. Sedimentary condensation has been and still is a widespread phenomenon in past and present-day oceans. The present-day distribution of glaucony and verdine-rich sediments on shelves and upper slopes, phosphate-rich sediments and phosphorite on outer shelves and upper slopes, ferromanganese crusts on slopes, seamounts and submarine plateaus, and ferromanganese nodules on abyssal seafloors is a good indication of the importance of condensation processes today. In the past, we may add the occurrence of oolitic ironstone, carbonate hardgrounds, and eventually also silica layers in banded iron formations as indicators of the importance of condensation processes. Besides their economic value, condensed sediments are useful both as a carrier of geochemical proxies of paleoceanographic and paleoenvironmental change, as well as the product of episodes of paleoceanographic and

  18. DROPWISE CONDENSATION ON MICRO- AND NANOSTRUCTURED SURFACES

    SciTech Connect

    Enright, R; Miljkovic, N; Alvarado, JL; Kim, K; Rose, JW

    2014-07-23

    In this review we cover recent developments in the area of surface-enhanced dropwise condensation against the background of earlier work. The development of fabrication techniques to create surface structures at the micro-and nanoscale using both bottom-up and top-down approaches has led to increased study of complex interfacial phenomena. In the heat transfer community, researchers have been extensively exploring the use of advanced surface structuring techniques to enhance phase-change heat transfer processes. In particular, the field of vapor-to-liquid condensation and especially that of water condensation has experienced a renaissance due to the promise of further optimizing this process at the micro-and nanoscale by exploiting advances in surface engineering developed over the last several decades.

  19. Electrolyte vapor condenser

    DOEpatents

    Sederquist, Richard A.; Szydlowski, Donald F.; Sawyer, Richard D.

    1983-01-01

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

  20. Electrolyte vapor condenser

    DOEpatents

    Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

    1983-02-08

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

  1. Topological framework for local structure analysis in condensed matter

    PubMed Central

    Lazar, Emanuel A.; Han, Jian; Srolovitz, David J.

    2015-01-01

    Physical systems are frequently modeled as sets of points in space, each representing the position of an atom, molecule, or mesoscale particle. As many properties of such systems depend on the underlying ordering of their constituent particles, understanding that structure is a primary objective of condensed matter research. Although perfect crystals are fully described by a set of translation and basis vectors, real-world materials are never perfect, as thermal vibrations and defects introduce significant deviation from ideal order. Meanwhile, liquids and glasses present yet more complexity. A complete understanding of structure thus remains a central, open problem. Here we propose a unified mathematical framework, based on the topology of the Voronoi cell of a particle, for classifying local structure in ordered and disordered systems that is powerful and practical. We explain the underlying reason why this topological description of local structure is better suited for structural analysis than continuous descriptions. We demonstrate the connection of this approach to the behavior of physical systems and explore how crystalline structure is compromised at elevated temperatures. We also illustrate potential applications to identifying defects in plastically deformed polycrystals at high temperatures, automating analysis of complex structures, and characterizing general disordered systems. PMID:26460045

  2. Topological framework for local structure analysis in condensed matter.

    PubMed

    Lazar, Emanuel A; Han, Jian; Srolovitz, David J

    2015-10-27

    Physical systems are frequently modeled as sets of points in space, each representing the position of an atom, molecule, or mesoscale particle. As many properties of such systems depend on the underlying ordering of their constituent particles, understanding that structure is a primary objective of condensed matter research. Although perfect crystals are fully described by a set of translation and basis vectors, real-world materials are never perfect, as thermal vibrations and defects introduce significant deviation from ideal order. Meanwhile, liquids and glasses present yet more complexity. A complete understanding of structure thus remains a central, open problem. Here we propose a unified mathematical framework, based on the topology of the Voronoi cell of a particle, for classifying local structure in ordered and disordered systems that is powerful and practical. We explain the underlying reason why this topological description of local structure is better suited for structural analysis than continuous descriptions. We demonstrate the connection of this approach to the behavior of physical systems and explore how crystalline structure is compromised at elevated temperatures. We also illustrate potential applications to identifying defects in plastically deformed polycrystals at high temperatures, automating analysis of complex structures, and characterizing general disordered systems. PMID:26460045

  3. Condensed Matter Nuclear Science

    NASA Astrophysics Data System (ADS)

    Biberian, Jean-Paul

    2006-02-01

    into characteristics of X-ray emission laser beams from solidstate cathode medium of high-current glow discharge / A. B. Karabut. Charged particles from Ti and Pd foils / L. Kowalski ... [et al.]. Cr-39 track detectors in cold fusion experiments: review and perspectives / A. S. Roussetski. Energetic particle shower in the vapor from electrolysis / R. A. Oriani and J. C. Fisher. Nuclear reactions produced in an operating electrolysis cell / R. A. Oriani and J. C. Fisher. Evidence of microscopic ball lightning in cold fusion experiments / E. H. Lewis. Neutron emission from D[symbol] gas in magnetic fields under low temperature / T. Mizuno ... [et al.]. Energetic charged particle emission from hydrogen-loaded Pd and Ti cathodes and its enhancement by He-4 implantation / A. G. Lipson ... [et al.]. H-D permeation. Observation of nuclear transmutation reactions induced by D[symbol] gas permeation through Pd complexes / Y. Iwamura ... [et al.]. Deuterium (hydrogen) flux permeating through palladium and condensed matter nuclear science / Q. M. Wei ... [et al.]. Triggering. Precursors and the fusion reactions in polarized Pd/D-D[symbol]O system: effect of an external electric field / S. Szpak, P. A. Mosier-Boss, and F. E. Gordon. Calorimetric and neutron diagnostics of liquids during laser irradiation / Yu. N. Bazhutov ... [et al.]. Anomalous neutron capture and plastic deformation of Cu and Pd cathodes during electrolysis in a weak thermalized neutron field: evidence of nuclei-lattice exchange / A. G. Lipson and G. H. Miley. H-D loading. An overview of experimental studies on H/Pd over-loading with thin Pd wires and different electrolytic solutions / A. Spallone ... [et al.] -- 3. Transmutations. Photon and particle emission, heat production, and surface transformation in Ni-H system / E. Campari ... [et al.]. Surface analysis of hydrogen-loaded nickel alloys / E. Campari ... [et al.]. Low-energy nuclear reactions and the leptonic monopole / G. Lochak and L. Urutskoev. Results

  4. BOOK REVIEW: Soft Condensed Matter

    NASA Astrophysics Data System (ADS)

    Jones, Richard A. L.

    2002-11-01

    phenomenologically and formulated through the current percolation model and the Flory-Stockmayer model. The next two chapters consider the molecular order in soft condensed matter. The rich complexity of liquid crystals is emphasized and the Frederiks transition is described in relation to liquid crystal displays. The crystallinity in polymers is discussed and its usual semi-crystallinity presented as a consequence of entanglement and timescales. The next chapter describes the self-assembly of phases and the great importance of the self-assembly phenomenon in solutions of amphiphilic molecules is largely discussed in several specific phenomena. The book ends with a chapter devoted to the description of soft matter realizations in nature. Special attention is paid to the components and structure of life: nucleic acids, proteins, polysaccharides and membranes. There are two appendixes recalling the basic concepts of thermodynamics and statistical mechanics. In each chapter, several problems are included, and solutions to a selection of them are given. The bibliography proposed is pertinent and each chapter gives details of further reading, mostly addressed to known books on the topic. iii) The presentation of the book is good. Throughout the book, the relevant, basic or new concepts of each topic are typed in bold characters and succinctly defined. The figures are abundant and adequately illustrate the text either by plots of experimental data or by computed predictions from models. Many schematic representations of structures, molecular distributions or arrangements are also included. In summary, the author has succeeded in producing a scientifically rigorous book of affordable size (around 200 pages) that is well illustrated (about 120 figures) and written in a fluent style that describes the many different physical phenomena involved in soft condensed matter. N Clavaguera

  5. Sequential phase transformation of propeller-like C3-symmetric liquid crystals from a helical to ordered to disordered hexagonal columnar structure.

    PubMed

    Park, Soyoung; Cho, Byoung-Ki

    2015-01-01

    In this paper, we report thermally induced intercolumnar phase transitions of C3-symmetric liquid crystals (LCs) bearing a triazole-based propeller-like aromatic mesogen. Since the constituting aromatic rings are conjugated through rotatable single bonds, the mesogenic shape is tuneable depending on the degree of conformational motion. Molecule 1 with ninefold octyl peripheries shows a hexagonal columnar liquid crystalline phase transition from ordered mesogenic stacking to disordered mesogenic stacking upon heating. On the other hand, molecule 2 with sixfold octyl peripheries displays a helical hexagonal columnar phase with the P6/mmm space group at ambient temperature as well as the ordered and disordered hexagonal columnar phases at higher temperatures. The intracolumnar helical order can be understood by an interdigitated stacking of the propeller-like mesogens along the columnar axis and the optimized space-filling. Notably, all the intercolumnar phase transformations in this study are revealed as second-order transitions. The thermodynamic nature agrees well with the fact that the conformational motions of the C3-symmetric aromatic mesogen change abruptly with each columnar transition. PMID:25370808

  6. Ghost condensate busting

    SciTech Connect

    Bilic, Neven; Tupper, Gary B; Viollier, Raoul D E-mail: gary.tupper@uct.ac.za

    2008-09-15

    Applying the Thomas-Fermi approximation to renormalizable field theories, we construct ghost condensation models that are free of the instabilities associated with violations of the null-energy condition.

  7. Measure Guideline: Evaporative Condensers

    SciTech Connect

    German, A.; Dakin, B.; Hoeschele, M.

    2012-03-01

    The purpose of this measure guideline on evaporative condensers is to provide information on a cost-effective solution for energy and demand savings in homes with cooling loads. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices. This document has been prepared to provide a process for properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs.

  8. Condensate dark matter stars

    SciTech Connect

    Li, X.Y.; Harko, T.; Cheng, K.S. E-mail: harko@hkucc.hku.hk

    2012-06-01

    We investigate the structure and stability properties of compact astrophysical objects that may be formed from the Bose-Einstein condensation of dark matter. Once the critical temperature of a boson gas is less than the critical temperature, a Bose-Einstein Condensation process can always take place during the cosmic history of the universe. Therefore we model the dark matter inside the star as a Bose-Einstein condensate. In the condensate dark matter star model, the dark matter equation of state can be described by a polytropic equation of state, with polytropic index equal to one. We derive the basic general relativistic equations describing the equilibrium structure of the condensate dark matter star with spherically symmetric static geometry. The structure equations of the condensate dark matter stars are studied numerically. The critical mass and radius of the dark matter star are given by M{sub crit} ≈ 2(l{sub a}/1fm){sup 1/2}(m{sub χ}/1 GeV){sup −3/2}M{sub s}un and R{sub crit} ≈ 1.1 × 10{sup 6}(l{sub a}/1 fm){sup 1/2}(m{sub χ}/1 GeV){sup −3/2} cm respectively, where l{sub a} and m{sub χ} are the scattering length and the mass of dark matter particle, respectively.

  9. The NSF Condensed Matter Physics Program

    NASA Astrophysics Data System (ADS)

    Sokol, Paul

    The Condensed Matter Physics (CMP) program in the NSF Division of Materials Research (DMR) supports experimental, as well as combined experiment and theory projects investigating the fundamental physics behind phenomena exhibited by condensed matter systems. CMP is the largest Individual Investigator Award program in DMR and supports a broad portfolio of research spanning both hard and soft condensed matter. Representative research areas include: 1) phenomena at the nano- to macro-scale including: transport, magnetic, and optical phenomena; classical and quantum phase transitions; localization; electronic, magnetic, and lattice structure or excitations; superconductivity; topological insulators; and nonlinear dynamics. 2) low-temperature physics: quantum fluids and solids; 1D & 2D electron systems. 3) soft condensed matter: partially ordered fluids, granular and colloid physics, liquid crystals, and 4) understanding the fundamental physics of new states of matter as well as the physical behavior of condensed matter under extreme conditions e.g., low temperatures, high pressures, and high magnetic fields. In this talk I will review the current CMP portfolio and discuss future funding trends for the program. I will also describe recent activities in the program aimed at addressing the challenges facing current and future principal investigators.

  10. Simulation Prediction of Transient Dropwise Condensation

    NASA Astrophysics Data System (ADS)

    Macner, Ashley; Daniel, Susan; Steen, Paul

    2014-11-01

    In order to design effective surfaces for large-scale dropwise condensation, an understanding of how surface functionalization affects drop growth and coalescence is needed. The long term technological goal is a set of design conditions to help NASA achieve maximum heat transfer rates of waste heat generated from electronics and habitable environments under microgravity conditions. Prediction of condenser surface heat transfer performance requires accurate simulation and modeling of the evolution of populations of drops in time. At shorter times, drops are primarily isolated and grow mainly by condensation onto the liquid-gas interface. At longer times, drops grow mainly by coalescence with neighbors. Simulation of dropwise condensation on a neutrally wetting surface and comparison with our previous experimental results is reported. A steady-state single drop conduction model is empirically fitted to determine a temperature profile that captures the drop size evolution. The simulation accurately predicts the continuous time evolution of number-density of drops, drop-size distributions, total condensate volume, fractional coverage, and median drop-size for both transient and steady states, all with no free parameters. This work was supported by a NASA Office of the Chief Technologist's Space Technology Research Fellowship.

  11. Nematic order-disorder state transition in a liquid crystal analogue formed by oriented and migrating amoeboid cells

    NASA Astrophysics Data System (ADS)

    Kemkemer, R.; Teichgräber, V.; Schrank-Kaufmann, S.; Kaufmann, D.; Gruler, H.

    2000-10-01

    In cell culture, liquid crystal analogues are formed by elongated, migrating, and interacting amoeboid cells. An apolar nematic liquid crystal analogue is formed by different cell types like human melanocytes (=pigment cells of the skin), human fibroblasts (=connective tissue cells), human osteoblasts (=bone cells), human adipocytes (=fat cells), etc. The nematic analogue is quite well described by i) a stochastic machine equation responsible for cell orientation and ii) a self-organized extracellular guiding signal, E_2, which is proportional to the orientational order parameter as well as to the cell density. The investigations were mainly made with melanocytes. The transition to an isotropic state analogue can be accomplished either by changing the strength of interaction (e.g. variation of the cell density) or by influencing the cellular machinery by an externally applied signal: i) An isotropic gaseous state analogue is observed at low cell density (ρ < 110melanocytes/mm^2) and a nematic liquid crystal state analogue at higher cell density. ii) The nematic state analogue disappears if the bipolar shaped melanocytes are forced to become a star-like shape (induced by colchicine or staurosporine). The analogy between nematic liquid crystal state analogue formed by elongated, migrating and interacting cells and the nematic liquid crystal phase formed by interacting elongated molecules is discussed.

  12. Diffusion in Condensed Matter: Methods, Materials, Models

    NASA Astrophysics Data System (ADS)

    Heitjans, Paul; Kärger, Jög

    This comprehensive, handbook-style survey of diffusion in condensed matter gives detailed insight into diffusion as the process of particle transport due to stochastic movement. It is understood and presented as a phenomenon of crucial relevance for a large variety of processes and materials. In this book, all aspects of the theoretical fundamentals, experimental techniques, highlights of current developments and results for solids, liquids and interfaces are presented.

  13. 'Crystal Genes' in Metallic Liquids and Glasses.

    PubMed

    Sun, Yang; Zhang, Feng; Ye, Zhuo; Zhang, Yue; Fang, Xiaowei; Ding, Zejun; Wang, Cai-Zhuang; Mendelev, Mikhail I; Ott, Ryan T; Kramer, Matthew J; Ho, Kai-Ming

    2016-01-01

    We analyze the underlying structural order that transcends liquid, glass and crystalline states in metallic systems. A genetic algorithm is applied to search for the most common energetically favorable packing motifs in crystalline structures. These motifs are in turn compared to the observed packing motifs in the actual liquid or glass structures using a cluster-alignment method. Using this method, we have revealed the nature of the short-range order in Cu64Zr36 glasses. More importantly, we identified a novel structural order in the Al90Sm10 system. In addition, our approach brings new insight into understanding the origin of vitrification and describing mesoscopic order-disorder transitions in condensed matter systems. PMID:27030071

  14. Collecting and recirculating condensate in a nuclear reactor containment

    DOEpatents

    Schultz, T.L.

    1993-10-19

    An arrangement passively cools a nuclear reactor in the event of an emergency, condensing and recycling vaporized cooling water. The reactor is surrounded by a containment structure and has a storage tank for cooling liquid, such as water, vented to the containment structure by a port. The storage tank preferably is located inside the containment structure and is thermally coupleable to the reactor, e.g. by a heat exchanger, such that water in the storage tank is boiled off to carry away heat energy. The water is released as a vapor (steam) and condenses on the cooler interior surfaces of the containment structure. The condensed water flows downwardly due to gravity and is collected and routed back to the storage tank. One or more gutters are disposed along the interior wall of the containment structure for collecting the condensate from the wall. Piping is provided for communicating the condensate from the gutters to the storage tank. 3 figures.

  15. Spark gap switch system with condensable dielectric gas

    DOEpatents

    Thayer, III, William J.

    1991-01-01

    A spark gap switch system is disclosed which is capable of operating at a high pulse rate comprising an insulated switch housing having a purging gas entrance port and a gas exit port, a pair of spaced apart electrodes each having one end thereof within the housing and defining a spark gap therebetween, an easily condensable and preferably low molecular weight insulating gas flowing through the switch housing from the housing, a heat exchanger/condenser for condensing the insulating gas after it exits from the housing, a pump for recirculating the condensed insulating gas as a liquid back to the housing, and a heater exchanger/evaporator to vaporize at least a portion of the condensed insulating gas back into a vapor prior to flowing the insulating gas back into the housing.

  16. Collecting and recirculating condensate in a nuclear reactor containment

    DOEpatents

    Schultz, Terry L.

    1993-01-01

    An arrangement passively cools a nuclear reactor in the event of an emergency, condensing and recycling vaporized cooling water. The reactor is surrounded by a containment structure and has a storage tank for cooling liquid, such as water, vented to the containment structure by a port. The storage tank preferably is located inside the containment structure and is thermally coupleable to the reactor, e.g. by a heat exchanger, such that water in the storage tank is boiled off to carry away heat energy. The water is released as a vapor (steam) and condenses on the cooler interior surfaces of the containment structure. The condensed water flows downwardly due to gravity and is collected and routed back to the storage tank. One or more gutters are disposed along the interior wall of the containment structure for collecting the condensate from the wall. Piping is provided for communicating the condensate from the gutters to the storage tank.

  17. Enhanced condensation heat transfer

    NASA Astrophysics Data System (ADS)

    Michel, J. W.; Murphy, R. W.

    1980-07-01

    Work has centered on optimizing the design variables associated with fluted surfaces on vertical tubes and comparing the tube performance with available enhanced tubes either for vertical or horizontal operation. Data with seven fluids including a hydrocarbon, fluorocarbons, and ammonia condensing on up to 30 different tubes were obtained. Data for tubes of different effective lengths (1/2 to 4 ft) and inclination were also obtained. The primary conclusion is that the best fluted tubes can provide an enhancement in condensation coefficient by a factor of approximately 6 over smooth vertical tube performance and a factor of approximately 2 over the best enhanced commercial tubes either operating vertically or horizontally. These data, together with field test data, have formed the basis for designing two prototype condensers, one for the 60 kWe Raft River, Idaho, pilot plant and one for the 500 kWe East Mesa, California, direct contact demonstration plant.

  18. Capillary Condensation in Polymer Blends: an Analysis of Phase Transitions

    NASA Astrophysics Data System (ADS)

    Ilie, Carolina C.; Jira, Nicholas C.; Evans, Ian R.; Cohen, Matthew; D'Rozario, Julia R.; Romano, Marie T.; Sabirianov, Ildar

    We explore herein the capillary condensation for various geometries. Capillary condensation is studied in the presence of van der Waals forces. We derive the grand free energy, and we analyze the phase transitions, the absorption isotherms and the triple point. Phase transitions between full, empty and two films are investigated and the shape of the liquid is calculated. We also analyze an important application of wetting phenomena and capillary condensation in binary polymer blends and investigate the type of wetting transitions presented and the phase diagram. SUNY Oswego SCAC Grant, NSF Noyce Grant.

  19. Extraction of condensed tannins from Mexican plant sources.

    PubMed

    Garcíaa, Ramiro; Aguilera, Antonio; Contreras-Esquivel, Juan C; Rodríguez, Raúl; Aguilar, Cristóbal N

    2008-01-01

    Contents of total polyphenols, condensed tannins and proanthocyanidins, and their stability to various pH values and temperatures were studied in Mexican blueberry, cuautecomate fruit, garambullo fruit, aubergine, coffee pulp and residues of black grapes. Several aqueous extracts, obtained through a one-pass-extraction process, were analyzed using liquid chromatography in order to quantify the condensed tannin (proanthocyanidin) content responsible for their antioxidant activity and colour. All tested samples included high proanthocyanidin contents demonstrating that these Mexican fruits and vegetables are good sources of natural antioxidants, and they all could be considered as excellent functional foods due to their bioactivity measured as the condensed tannin level. PMID:18386482

  20. Physics through the 1990s: Condensed-matter physics

    NASA Technical Reports Server (NTRS)

    1986-01-01

    The volume presents the current status of condensed-matter physics from developments since the 1970s to opportunities in the 1990s. Topics include electronic structure, vibrational properties, critical phenomena and phase transitions, magnetism, semiconductors, defects and diffusion, surfaces and interfaces, low-temperature physics, liquid-state physics, polymers, nonlinear dynamics, instabilities, and chaos. Appendices cover the connections between condensed-matter physics and applications of national interest, new experimental techniques and materials, laser spectroscopy, and national facilities for condensed-matter physics research. The needs of the research community regarding support for individual researchers and for national facilities are presented, as are recommendations for improved government-academic-industrial relations.

  1. Condensation and Evaporation of Solar System Materials

    NASA Astrophysics Data System (ADS)

    Davis, A. M.; Richter, F. M.

    2003-12-01

    It is widely believed that the materials making up the solar system were derived from a nebular gas and dust cloud that went through an early high-temperature stage during which virtually all of the material was in the gas phase. At one time, it was thought that the entire inner solar nebula was hot, but it is now believed that most material was processed through regions where high temperatures were achieved. Certainly some material, such as presolar grains (cf., Mendybaev et al., 2002a), has never been exposed to high temperatures. As the system cooled, solids and perhaps liquids began to condense, but at some point the partially condensed materials became isolated from the remaining gas. Various lines of evidence support this view. At the largest scale, there is the observation that the Earth, Moon, Mars, and all chondritic meteorites except for the CI chondrites are depleted to varying degrees in the abundances of moderately volatile elements relative to bulk solar system composition. The CI chondrites reflect the bulk composition of the solar system for all but hydrogen, carbon, nitrogen, oxygen, and the rare gases, the most volatile elements (see Chapter 1.03; Palme et al., 1988; McDonough and Sun, 1995; Humayun and Cassen, 2000). The depletions in moderately volatile elements are, to a significant degree, correlated with condensation temperature, suggesting progressive removal of gas as condensation proceeded ( Cassen, 1996). Additional observations that can be explained by partial condensation are that various particularly primitive components of meteorites (e.g., calcium-, aluminum-rich refractory inclusions, and certain metal grains) have mineralogy and/or details of their chemical composition that are remarkably similar to what is calculated for equilibrium condensates from a solar composition gas. For example, the calcium-, aluminum-rich inclusions (CAIs) in chondritic meteorites have compositions very similar to that calculated for the first 5% of total

  2. Keeping condensers clean

    SciTech Connect

    Wicker, K.

    2006-04-15

    The humble condenser is among the biggest contributors to a steam power plant's efficiency. But although a clean condenser can provide great economic benefit, a dirty one can raise plant heat rate, resulting in large losses of generation revenue and/or unnecessarily high fuel bills. Conventional methods for cleaning fouled tubes range form chemicals to scrapers to brushes and hydro-blasters. This article compares the available options and describes how one power station, Omaha Public Power District's 600 MW North Omaha coal-fired power station, cleaned up its act. The makeup and cooling water of all its five units comes from the Missouri River. 6 figs.

  3. Emergence of non-Fermi liquid behaviors in 5d perovskite SrIrO3 thin films: Interplay between correlation, disorder, and spin-orbit coupling

    NASA Astrophysics Data System (ADS)

    Biswas, Abhijit; Kim, Ki-Seok; Jeong, Yoon H.

    2016-02-01

    We investigate the effects of compressive strain on the electrical resistivity of 5d iridium based perovskite SrIrO3 by depositing epitaxial films of thickness 35 nm on various substrates such as GdScO3 (110), DyScO3 (110), and SrTiO3 (001). Surprisingly, we find anomalous transport behaviors as expressed by ρ∝Tε in the temperature dependent resistivity, where the temperature exponent ε evolves continuously from 4/5 to 1 and to 3/2 with an increase of compressive strain. Furthermore, magnetoresistance always remains positive irrespective of resistivity upturns at low temperatures. These observations imply that the delicate interplay between correlation and disorder in the presence of strong spin-orbit coupling is responsible for the emergence of the non-Fermi liquid behaviors in 5d perovskite SrIrO3 thin films. We offer a theoretical framework for the interpretation of the experimental results.

  4. Condensation of lattice defects and melting transitions in quantum Hall phases

    NASA Astrophysics Data System (ADS)

    Cho, Gil Young; Parrikar, Onkar; You, Yizhi; Leigh, Robert G.; Hughes, Taylor L.

    2015-01-01

    Motivated by recent progress in understanding the interplay between lattice and electronic topological phases, we consider quantum-melting transitions of weak quantum liquid crystals, a crystal and a nematic phase, in which electrons form a quantum Hall state. In certain classes of Chern band insulators and quantum Hall phases, it has been previously demonstrated that there are topological Chern-Simons terms such as a Hall viscosity term and a gravitational Chern-Simons term for local lattice deformations. The Chern-Simons terms can induce anyonic statistics for the topological lattice defects and, furthermore, dress the defects with certain symmetry quantum numbers. On the other hand, the melting transitions of such liquid-crystalline orders are driven by the condensation of lattice defects. Based on these observations, we show how the topological terms can change the nature of the proximate disordered phases of the quantum liquid-crystalline phases. We derive and study the effective dual field theories for the liquid-crystalline phases with the geometric Chern-Simons terms, and carefully examine the symmetry quantum numbers and statistics of defects. We show that a crystal may go through a continuous phase transition into another crystal with the different discrete translational symmetries because the dislocation, the topological defect in the crystal, carries nonzero crystal momentum due to the Hall viscosity term. For the nematic phase, the disclination will condense at the phase transition to the isotropic phase, and we show that the isotropic phase may support a deconfined fractionally charged excitation due to the Wen-Zee term, and thus the isotropic phase and the nematic phase have different electromagnetic Hall responses.

  5. Condensed Matter Nuclear Science

    NASA Astrophysics Data System (ADS)

    Takahashi, Akito; Ota, Ken-Ichiro; Iwamura, Yashuhiro

    Preface -- 1. General. Progress in condensed matter nuclear science / A. Takahashi. Summary of ICCF-12 / X. Z. Li. Overview of light water/hydrogen-based low-energy nuclear reactions / G. H. Miley and P. J. Shrestha -- 2. Excess heat and He detection. Development of "DS-reactor" as the practical reactor of "cold fusion" based on the "DS-cell" with "DS-cathode" / Y. Arata and Y.-C. Zhang. Progress in excess of power experiments with electrochemical loading of deuterium in palladium / V. Violante ... [et al.]. Anomalous energy generation during conventional electrolysis / T. Mizuno and Y. Toriyabe. "Excess heat" induced by deuterium flux in palladium film / B. Liu ... [et al.]. Abnormal excess heat observed during Mizuno-type experiments / J.-F. Fauvarque, P. P. Clauzon and G. J.-M. Lallevé. Seebeck envelope calorimetry with a Pd|D[symbol]O + H[symbol]SO[symbol] electrolytic cell / W.-S. Zhang, J. Dash and Q. Wang. Observation and investigation of nuclear fusion and self-induced electric discharges in liquids / A. I. Koldamasov ... [et al.]. Description of a sensitive seebeck calorimeter used for cold fusion studies / E. Storms. Some recent results at ENEA / M. Apicella ... [et al.]. Heat measurement during plasma electrolysis / K. Iizumi ... [et al.]. Effect of an additive on thermal output during electrolysis of heavy water with a palladium cathode / Q. Wang and J. Dash. Thermal analysis of calorimetric systems / L. D'Aulerio ... [et al.]. Surface plasmons and low-energy nuclear reactions triggering / E. Castagna ... [et al.]. Production method for violent TCB jet plasma from cavity / F. Amini. New results and an ongoing excess heat controversy / L. Kowalski ... [et al.] -- 3. Transmutation. Observation of surface distribution of products by X-ray fluorescence spectrometry during D[symbol] gas permeation through Pd Complexes / Y. Iwamura ... [et al.]. Discharge experiment using Pd/CaO/Pd multi-layered cathode / S. Narita ... [et al.]. Producing transmutation

  6. Simple Simulations of DNA Condensation

    SciTech Connect

    STEVENS,MARK J.

    2000-07-12

    Molecular dynamics simulations of a simple, bead-spring model of semiflexible polyelectrolytes such as DNA are performed. All charges are explicitly treated. Starting from extended, noncondensed conformations, condensed structures form in the simulations with tetravalent or trivalent counterions. No condensates form or are stable for divalent counterions. The mechanism by which condensates form is described. Briefly, condensation occurs because electrostatic interactions dominate entropy, and the favored Coulombic structure is a charge ordered state. Condensation is a generic phenomena and occurs for a variety of polyelectrolyte parameters. Toroids and rods are the condensate structures. Toroids form preferentially when the molecular stiffness is sufficiently strong.

  7. Modeling of rapid direct-contact condensation. Report on phase 1 (Final)

    SciTech Connect

    Wallis, G.B.; Richter, H.J.; Valenzuela, J.A.; Rothe, P.H.

    1985-08-01

    The focus of the study is on rapid direct-contact condensation phenomena, that is, direct-contact condensation situations characterized by extremely high condensation rates and violent mixing at the liquid-vapor interface. Rapid condensation phenomena arise in many industrial processes, but general methods do not presently exist to design effective components or to avoid system-flow instability. A conceptual model and preliminary analysis of rapid condensation are presented, and preliminary, proof-of-concept experiments are described. Some background information and a brief survey of previous work in the area are also provided.

  8. Condensed Matter Nuclear Science

    NASA Astrophysics Data System (ADS)

    Takahashi, Akito; Ota, Ken-Ichiro; Iwamura, Yashuhiro

    Preface -- 1. General. Progress in condensed matter nuclear science / A. Takahashi. Summary of ICCF-12 / X. Z. Li. Overview of light water/hydrogen-based low-energy nuclear reactions / G. H. Miley and P. J. Shrestha -- 2. Excess heat and He detection. Development of "DS-reactor" as the practical reactor of "cold fusion" based on the "DS-cell" with "DS-cathode" / Y. Arata and Y.-C. Zhang. Progress in excess of power experiments with electrochemical loading of deuterium in palladium / V. Violante ... [et al.]. Anomalous energy generation during conventional electrolysis / T. Mizuno and Y. Toriyabe. "Excess heat" induced by deuterium flux in palladium film / B. Liu ... [et al.]. Abnormal excess heat observed during Mizuno-type experiments / J.-F. Fauvarque, P. P. Clauzon and G. J.-M. Lallevé. Seebeck envelope calorimetry with a Pd|D[symbol]O + H[symbol]SO[symbol] electrolytic cell / W.-S. Zhang, J. Dash and Q. Wang. Observation and investigation of nuclear fusion and self-induced electric discharges in liquids / A. I. Koldamasov ... [et al.]. Description of a sensitive seebeck calorimeter used for cold fusion studies / E. Storms. Some recent results at ENEA / M. Apicella ... [et al.]. Heat measurement during plasma electrolysis / K. Iizumi ... [et al.]. Effect of an additive on thermal output during electrolysis of heavy water with a palladium cathode / Q. Wang and J. Dash. Thermal analysis of calorimetric systems / L. D'Aulerio ... [et al.]. Surface plasmons and low-energy nuclear reactions triggering / E. Castagna ... [et al.]. Production method for violent TCB jet plasma from cavity / F. Amini. New results and an ongoing excess heat controversy / L. Kowalski ... [et al.] -- 3. Transmutation. Observation of surface distribution of products by X-ray fluorescence spectrometry during D[symbol] gas permeation through Pd Complexes / Y. Iwamura ... [et al.]. Discharge experiment using Pd/CaO/Pd multi-layered cathode / S. Narita ... [et al.]. Producing transmutation

  9. Detail of Bright Angel stone vault, containing condenser, Hoffman condensation ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Detail of Bright Angel stone vault, containing condenser, Hoffman condensation pump, Jennings vacuum heating pump, and misc. pipes and valves. - Grand Canyon Village Utilities, Grand Canyon National Park, Grand Canyon Village, Coconino County, AZ

  10. Effects of hypothermic liquid storage and cryopreservation on basal and induced plasma membrane phospholipid disorder and acrosome exocytosis in boar spermatozoa.

    PubMed

    Guthrie, H D; Welch, G R

    2005-01-01

    Flow cytometry was utilised to determine whether short-term (Day 1) or long-term hypothermic liquid storage (Day 5), or cryopreservation of boar spermatozoa (1) caused changes in plasma membrane phospholipid disorder (MPLD) and acrosome exocytosis (AE), indicative of an advanced stage of capacitation or acrosome status, and (2) facilitated or inhibited the induction of capacitation and the acrosome reaction. Merocyanine with Yo-Pro-1 and peanut agglutinin-fluorescein isothiocyanate with propidium iodide were used to identify MPLD and AE, respectively, in viable spermatozoa. The incidence of basal sperm MPLD and AE in fresh semen was very low (1.1 and 2.2%, respectively) and was increased (P < 0.05) only a small amount in Day 5 and cryopreserved semen (3-8%). Compared to no bicarbonate, incubation with bicarbonate increased MPLD, but the response was greatest (P < 0.05) in fresh sperm (52.3%) compared with Day 1 (36.6%), Day 5 (13.9%) and cryopreserved sperm (13.6%). Incubation with calcium ionophore A23187 increased AE in spermatozoa, but the response was less (P < 0.05) for fresh (34%) and cryopreserved (27%) semen than for Day 1 (45%) and Day 5 (57%) semen. In summary, hypothermic liquid storage and cryopreservation of boar spermatozoa did not advance capacitation or acrosome status in viable spermatozoa, but did alter their responses to induction of capacitation and the acrosome reaction. PMID:15899159

  11. Inflation from gravitino condensates

    NASA Astrophysics Data System (ADS)

    Mavromatos, Nick E.

    2015-07-01

    We review work on the formation of gravitino condensates via the super-Higgs effect in the early Universe. This is a scenario for both inflating the early universe and breaking local supersymmetry(supergravity), entirely independent of any coupling to external matter. The goldstino mode associated with the breaking of (global) supersymmetry is “eaten” by the gravitino field, which becomes massive (via its own vacuum condensation) and breaks supergravity dynamically. The most natural association of gravitino condensates with inflation proceeds in an indirect way, via a Starobinsky-type inflation, in the massive gravitino phase. This inflationary phase is associated with scalar modes hidden in the higher order curvature corrections of the effective action arising from integrating out massive gravitino degrees of freedom. The scenario is in agreement with Planck data phenomenology in a natural and phenomenologically-relevant range of parameters, namely Grand-Unified-Theory values for the supersymmetry breaking energy scale and dynamically-induced gravitino mass. A hill-top inflation, on the other hand, which could also occur in the model, whereby the role of the inflaton field is played by the gravitino condensate itself, would require significant fine tuning in the inflaton's wave function renormalisation and thus may be discarded on naturalness grounds.

  12. Condensate removal device

    DOEpatents

    Maddox, James W.; Berger, David D.

    1984-01-01

    A condensate removal device is disclosed which incorporates a strainer in unit with an orifice. The strainer is cylindrical with its longitudinal axis transverse to that of the vapor conduit in which it is mounted. The orifice is positioned inside the strainer proximate the end which is remoter from the vapor conduit.

  13. Condensation of Forced Convection Two-Phase Flow in a Miniature Tube

    NASA Technical Reports Server (NTRS)

    Begg, E.; Faghri, A.; Krustalev, D.

    1999-01-01

    A physical/mathematical model of annular film condensation at the inlet of a miniature tube has been developed. In the model, the liquid flow is coupled with the vapor flow along the liquid-vapor interface through the interfacial temperature, heat flux, shear stress, and pressure jump conditions due to surface tension effects. The model predicts the shape of the liquid-vapor interface along the condenser and leads to the conclusion that there is complete condensation at a certain distance from the condenser inlet. The numerical results show that complete condensation of the incoming vapor is possible at comparatively low heat loads and that this is a special case of a more general condensation regime with two-phase bubbly flow downstream of the initial annular film condensation region. Observations from the flow visualization experiment confirm the existence and qualitative features of annular film condensation leading to the complete condensation phenomenon in a small diameter (3.25 mm) circular tube condenser.

  14. Tunable Vapor-Condensed Nanolenses

    PubMed Central

    2015-01-01

    Nanostructured optical components, such as nanolenses, direct light at subwavelength scales to enable, among others, high-resolution lithography, miniaturization of photonic circuits, and nanoscopic imaging of biostructures. A major challenge in fabricating nanolenses is the appropriate positioning of the lens with respect to the sample while simultaneously ensuring it adopts the optimal size and shape for the intended use. One application of particular interest is the enhancement of contrast and signal-to-noise ratio in the imaging of nanoscale objects, especially over wide fields-of-view (FOVs), which typically come with limited resolution and sensitivity for imaging nano-objects. Here we present a self-assembly method for fabricating time- and temperature-tunable nanolenses based on the condensation of a polymeric liquid around a nanoparticle, which we apply to the high-throughput on-chip detection of spheroids smaller than 40 nm, rod-shaped particles with diameter smaller than 20 nm, and biofunctionalized nanoparticles, all across an ultralarge FOV of >20 mm2. Previous nanoparticle imaging efforts across similar FOVs have detected spheroids no smaller than 100 nm, and therefore our results demonstrate the detection of particles >15-fold smaller in volume, which in free space have >240 times weaker Rayleigh scattering compared to the particle sizes detected in earlier wide-field imaging work. This entire platform, with its tunable nanolens condensation and wide-field imaging functions, is also miniaturized into a cost-effective and portable device, which might be especially important for field use, mobile sensing, and diagnostics applications, including, for example, the measurement of viral load in bodily fluids. PMID:24979060

  15. A Local Condensation Analysis Representing Two-phase Annular Flow in Condenser/radiator Capillary Tubes

    NASA Technical Reports Server (NTRS)

    Karimi, Amir

    1991-01-01

    NASA's effort for the thermal environmental control of the Space Station Freedom is directed towards the design, analysis, and development of an Active Thermal Control System (ATCS). A two phase, flow through condenser/radiator concept was baselined, as a part of the ATCS, for the radiation of space station thermal load into space. The proposed condenser rejects heat through direct condensation of ATCS working fluid (ammonia) in the small diameter radiator tubes. Analysis of the condensation process and design of condenser tubes are based on the available two phase flow models for the prediction of flow regimes, heat transfer, and pressure drops. The prediction formulas use the existing empirical relationships of friction factor at gas-liquid interface. An attempt is made to study the stability of interfacial waves in two phase annular flow. The formulation is presented of a stability problem in cylindrical coordinates. The contribution of fluid viscosity, surface tension, and transverse radius of curvature to the interfacial surface is included. A solution is obtained for Kelvin-Helmholtz instability problem which can be used to determine the critical and most dangerous wavelengths for interfacial waves.

  16. Condensation induced water hammer driven sterilization

    DOEpatents

    Kullberg, Craig M.

    2004-05-11

    A method and apparatus (10) for treating a fluid or materials therein with acoustic energy has a vessel (14) for receiving the fluid with inner walls shaped to focus acoustic energy to a target zone within the vessel. One or more nozzles (26) are directed into the vessel (14) for injecting a condensable vapor, such as steam, into the vessel (14). The system may include a steam source (18) for providing steam as the condensable vapor from an industrial waste heat source. Steam drums (88) are disposed between the steam source (18) and nozzles (26) to equalize and distribute the vapor pressure. A cooling source (30) provides a secondary fluid for maintaining the liquid in the vessel (14) in subcooled conditions. A heating jacket (32) surrounds the vessel (14) to heat the walls of the vessel (14) and prevent biological growth thereon. A pressurizer (33) may operate the system at elevated pressures.

  17. Multilayer graphene condenser microphone

    NASA Astrophysics Data System (ADS)

    Todorović, Dejan; Matković, Aleksandar; Milićević, Marijana; Jovanović, Djordje; Gajić, Radoš; Salom, Iva; Spasenović, Marko

    2015-12-01

    Vibrating membranes are the cornerstone of acoustic technology, forming the backbone of modern loudspeakers and microphones. Acoustic performance of a condenser microphone is derived mainly from the membrane’s size, surface mass and achievable static tension. The widely studied and available nickel has been a dominant membrane material for professional microphones for several decades. In this paper we introduce multilayer graphene as a membrane material for condenser microphones. The graphene device outperforms a high end commercial nickel-based microphone over a significant part of the audio spectrum, with a larger than 10 dB enhancement of sensitivity. Our experimental results are supported with numerical simulations, which also show that a 300 layer thick graphene membrane under maximum tension would offer excellent extension of the frequency range, up to 1 MHz.

  18. Gravitational vacuum condensate stars

    PubMed Central

    Mazur, Pawel O.; Mottola, Emil

    2004-01-01

    A new final state of gravitational collapse is proposed. By extending the concept of Bose–Einstein condensation to gravitational systems, a cold, dark, compact object with an interior de Sitter condensate pv = -ρv and an exterior Schwarzschild geometry of arbitrary total mass M is constructed. These regions are separated by a shell with a small but finite proper thickness ℓ of fluid with equation of state p = +ρ, replacing both the Schwarzschild and de Sitter classical horizons. The new solution has no singularities, no event horizons, and a global time. Its entropy is maximized under small fluctuations and is given by the standard hydrodynamic entropy of the thin shell, which is of the order kBℓMc/, instead of the Bekenstein–Hawking entropy formula, SBH = 4πkBGM2/c. Hence, unlike black holes, the new solution is thermodynamically stable and has no information paradox. PMID:15210982

  19. CW laser light condensation.

    PubMed

    Zhurahov, Michael; Bekker, Alexander; Levit, Boris; Weill, Rafi; Fischer, Baruch

    2016-03-21

    We present a first experimental demonstration of classical CW laser light condensation (LC) in the frequency (mode) domain that verifies its prediction (Fischer and Weill, Opt. Express20, 26704 (2012)). LC is based on weighting the modes in a noisy environment in a loss-gain measure compared to an energy (frequency) scale in Bose-Einstein condensation (BEC). It is characterized by a sharp transition from multi- to single-mode oscillation, occurring when the spectral-filtering (loss-trap) has near the lowest-loss mode ("ground-state") a power-law dependence with an exponent smaller than 1. An important meaning of the many-mode LC system stems from its relation to lasing and photon-BEC. PMID:27136845

  20. Bose-Einstein Condensation

    SciTech Connect

    El-Sherbini, Th.M.

    2005-03-17

    This article gives a brief review of Bose-Einstein condensation. It is an exotic quantum phenomenon that was observed in dilute atomic gases for the first time in 1995. It exhibits a new state of matter in which a group of atoms behaves as a single particle. Experiments on this form of matter are relevant to many different areas of physics- from atomic clocks and quantum computing to super fluidity, superconductivity and quantum phase transition.

  1. Capillary condenser/evaporator

    NASA Technical Reports Server (NTRS)

    Valenzuela, Javier A. (Inventor)

    2010-01-01

    A heat transfer device is disclosed for transferring heat to or from a fluid that is undergoing a phase change. The heat transfer device includes a liquid-vapor manifold in fluid communication with a capillary structure thermally connected to a heat transfer interface, all of which are disposed in a housing to contain the vapor. The liquid-vapor manifold transports liquid in a first direction and conducts vapor in a second, opposite direction. The manifold provides a distributed supply of fluid (vapor or liquid) over the surface of the capillary structure. In one embodiment, the manifold has a fractal structure including one or more layers, each layer having one or more conduits for transporting liquid and one or more openings for conducting vapor. Adjacent layers have an increasing number of openings with decreasing area, and an increasing number of conduits with decreasing cross-sectional area, moving in a direction toward the capillary structure.

  2. Asymmetric condensed dark matter

    NASA Astrophysics Data System (ADS)

    Aguirre, Anthony; Diez-Tejedor, Alberto

    2016-04-01

    We explore the viability of a boson dark matter candidate with an asymmetry between the number densities of particles and antiparticles. A simple thermal field theory analysis confirms that, under certain general conditions, this component would develop a Bose-Einstein condensate in the early universe that, for appropriate model parameters, could survive the ensuing cosmological evolution until now. The condensation of a dark matter component in equilibrium with the thermal plasma is a relativistic process, hence the amount of matter dictated by the charge asymmetry is complemented by a hot relic density frozen out at the time of decoupling. Contrary to the case of ordinary WIMPs, dark matter particles in a condensate must be lighter than a few tens of eV so that the density from thermal relics is not too large. Big-Bang nucleosynthesis constrains the temperature of decoupling to the scale of the QCD phase transition or above. This requires large dark matter-to-photon ratios and very weak interactions with standard model particles.

  3. Condensation of sodium on a micromachined surface for AMTEC

    SciTech Connect

    Crowley, C.J.; Izenson, M.G. )

    1993-01-15

    A novel condenser component is being developed to enable Alkali Metal Thermal to Electric Conversion (AMTEC) technology to achieve two critical goals: (1) optimization of conversion efficiency and (2) microgravity fluid management. The first goal is achieved by minimizing parasitic radiation heat transfer losses for condensers with a large view factor to the high-temperature [beta][double prime]-alumina surface. The condenser geometry includes a specially designed, micromachined surface where large capillary forces are used to manage the fluid distribution to accomplish the second goal. We present and discuss the results of separate effects experiments investigating the wetting and condensation behavior of sodium on this capillary surface. Test results show that the micromachined surface maintains a smooth, high reflective film of liquid sodium on the surface, which implies reduced parasitic losses and increased conversion efficiencies in AMTEC cells. Accomplishing this in an adverse gravity gradient demonstrates the potential for management of the fluid even under spacecraft acceleration conditions.

  4. Evidence of Bose-Einstein Condensation in solid helium

    NASA Astrophysics Data System (ADS)

    Chan, Moses H. W.

    2005-03-01

    The onset of superfluidity in liquid He-4 below 2.176K is associated with Bose-Einstein condensation where He-4 atoms condensed into a single momentum state and acquire quantum mechanical coherence over macroscopic length scales. Bose- Einstein condensation of alkali atoms in the vapor phase was achieved in 1995 and there is strong evidence for superfluidity in these systems. Perhaps counter to intuition, superfluid-like behavior is thought possible even in solid helium. Recent high Q torsional oscillator measurements found evidence of superflow in solid helium confined in porous media (1) and in bulk solid helium (2), indicating Bose-Einstein condensation very likely occurs in all three phases of matter. (1) E. Kim and M. H. W. Chan, Nature 427, 225 (2004) (2) E. Kim and M. H. W. Chan, Science 305, 1941 (2004).

  5. PREFACE: Topics in the application of scattering methods to investigate the structure and dynamics of soft condensed matter

    NASA Astrophysics Data System (ADS)

    Chen, Sow-Hsin; Baglioni, Piero

    2006-09-01

    This special issue of Journal of Physics: Condensed Matter gathers together a series of contributions presented at the workshop entitled `Topics in the Application of Scattering Methods to Investigate the Structure and Dynamics of Soft Condensed Matter' held at Pensione Bencista, Fiesole, Italy, a wonderful Italian jewel tucked high in the hills above Florence. This immaculate 14th century villa is a feast for the eyes with antiques and original artwork everywhere you turn, and a stunning view of Florence, overlooking numerous villas and groves of olive trees. The meeting consisted of about 40 invited talks delivered by a selected group of prominent physicists and chemists from the USA, Mexico, Europe and Asia working in the fields of complex and glassy liquids. The topics covered by the talks included: simulations on the liquid-liquid transition phenomenon dynamic crossover in deeply supercooled confined water thermodynamics and dynamics of complex fluids dynamics of interfacial water structural arrest transitions in colloidal systems structure and dynamics in complex systems structure of supramolecular assemblies The choice of topics is obviously heavily biased toward the current interests of the two organizers of the workshop, in view of the fact that one of the incentives for organizing the meeting was to celebrate Sow-Hsin Chen’s life-long scientific activities on the occasion of his 70th birthday. The 21 articles presented in this issue are a state-of-the-art description of the different aspects reported at the workshop from all points of view---experimental, theoretical and numerical. The interdisciplinary nature of the talks should make this special issue of interest to a broad community of scientists involved in the study of the properties of complex fluids, soft condensed matter and disordered glassy systems. We are grateful to the Consorzio per lo Sviluppo dei Sistemi a Grande Interfase (CSGI), Florence, Italy and to the Materials Science Program of

  6. Quenched crystal-field disorder and magnetic liquid ground states in Tb2Sn2 -xTixO7

    NASA Astrophysics Data System (ADS)

    Gaulin, B. D.; Kermarrec, E.; Dahlberg, M. L.; Matthews, M. J.; Bert, F.; Zhang, J.; Mendels, P.; Fritsch, K.; Granroth, G. E.; Jiramongkolchai, P.; Amato, A.; Baines, C.; Cava, R. J.; Schiffer, P.

    2015-06-01

    Solid solutions of the "soft" quantum spin ice pyrochlore magnets Tb2B2O7 with B = Ti and Sn display a novel magnetic ground state in the presence of strong B-site disorder, characterized by a low susceptibility and strong spin fluctuations to temperatures below 0.1 K. These materials have been studied using ac susceptibility and μ SR techniques to very low temperatures, and time-of-flight inelastic neutron scattering techniques to 1.5 K. Remarkably, neutron spectroscopy of the Tb3 + crystal-field levels appropriate to high B-site mixing (0.5

  7. Appetitive and consummative responding for liquid sucrose in the spontaneously hypertensive rat model of attention deficit hyperactivity disorder.

    PubMed

    Dommett, Eleanor J; Rostron, Claire L

    2013-02-01

    The spontaneously hypertensive rat (SHR) is one proposed animal model of attention deficit hyperactivity disorder (ADHD) argued to show strong face validity on the basis of behavioural characteristics. However, SHR may have fundamental alterations to the sensitivity of fluid reward due to altered renal function that has the potential to affect performance in complex reinforced behavioural tests. This could particularly confound determination of operant motivational alterations in the SHR. We assessed baseline bodyweight, home cage lab chow and water intake in the SHR and their typical control strains: Wistar and Wistar Kyoto. We also assessed sucrose preference, and appetitive and consummative positive and negative contrast for sucrose (4% versus 20%) on a motivational runway. As expected, SHR showed enhanced water intake compared to Wistar and Wistar Kyotos but comparable lab chow intake at baseline. SHR exhibited sucrose preference for 4% and 20%, as did both control strains, but the preference for 4% was enhanced in the SHR. SHR showed significant negative and positive contrast in sucrose consumption on the runway, as did Wistar Kyotos. Wistars exhibited neither. Appetitive contrast was not measurable in the SHR due to a robust locomotor velocity increase at the age of testing. The enhanced fluid intake found in the SHR argues against using fluid reinforcers in behavioural tests. We suggest the presence of both forms of contrast in the SHR is unusual for rats tested in ad lib. food conditions while the contrast pattern in Wistars indicate abnormalities in reward sensitivity in this control strain. PMID:23117093

  8. The influence of the liquid-to-solid transitions on the changes of macromolecules from disorder to order

    SciTech Connect

    Wunderlich, Bernhard {nmn}

    2010-01-01

    When crystallizing macromolecules, one needs to recognize that they are sufficiently long to connect neighboring phases. This coupling between the phases is the reason that on ordering, practically all polymers develop a globally metastable, semicrystalline structure, consisting of multiple phases with different degrees of mobility. The ordered and amorphous phases are separated by nanophases of strained segments of molecule of nanometer dimensions, consisting of rigid-amorphous fractions, RAFs, which soften, above, within, or below the often very broad melting range of the ordered phases. Thus, ordering of a melt of macromolecules causes significant changes in the remaining amorphous phases. A summary of the various phases is given in terms of their structures, molecular vibrations, and large-amplitude motion as they influence the glass and order-disorder transitions. This is followed by a description of the limits of the classical nucleation theory of crystals when applied to macromolecules. Discussed in detail are the problems in primary and secondary nucleation which arise from the presence of RAFs. Special macromolecular nucleation processes that needed to be considered are the self-nucleation on cooling from above the melting temperature or on heating from above the glass transition temperature, and the molecular nucleation causing molar mass segregation on ordering. Finally, the glass transitions of the phases of various sizes and degree of order are discussed on hand of selected, pertinent examples.

  9. Quenched crystal-field disorder and magnetic liquid ground states in Tb₂Sn2-xTixO₇

    DOE PAGESBeta

    Gaulin, B. D.; Kermarrec, E.; Dahlberg, M. L.; Matthews, M. J.; Bert, F.; Zhang, J.; Mendels, P.; Fritsch, K.; Granroth, G. E.; Jiramongkolchai, P.; et al

    2015-06-18

    Solid solutions of the “soft” quantum spin ice pyrochlore magnets Tb₂B₂O₇ with B = Ti and Sn display a novel magnetic ground state in the presence of strong B-site disorder, characterized by a low susceptibility and strong spin fluctuations to temperatures below 0.1 K. These materials have been studied using ac susceptibility and μSR techniques to very low temperatures, and time-of-flight inelastic neutron scattering techniques to 1.5 K. Remarkably, neutron spectroscopy of the Tb³⁺ crystal-field levels appropriate to high B-site mixing (0.5 < x < 1.5 in Tb₂Sn2-xTixO₇) reveal that the doublet ground and first excited states present as continuamore » in energy, while transitions to singlet excited states at higher energies simply interpolate between those of the end members of the solid solution. The resulting ground state suggests an extreme version of a random-anisotropy magnet, with many local moments and anisotropies, depending on the precise local configuration of the six B sites neighboring each magnetic Tb³⁺ ion.« less

  10. Immersion Condensation on Oil-Infused Heterogeneous Surfaces for Enhanced Heat Transfer

    PubMed Central

    Xiao, Rong; Miljkovic, Nenad; Enright, Ryan; Wang, Evelyn N.

    2013-01-01

    Enhancing condensation heat transfer is important for broad applications from power generation to water harvesting systems. Significant efforts have focused on easy removal of the condensate, yet the other desired properties of low contact angles and high nucleation densities for high heat transfer performance have been typically neglected. In this work, we demonstrate immersion condensation on oil-infused micro and nanostructured surfaces with heterogeneous coatings, where water droplets nucleate immersed within the oil. The combination of surface energy heterogeneity, reduced oil-water interfacial energy, and surface structuring enabled drastically increased nucleation densities while maintaining easy condensate removal and low contact angles. Accordingly, on oil-infused heterogeneous nanostructured copper oxide surfaces, we demonstrated approximately 100% increase in heat transfer coefficient compared to state-of-the-art dropwise condensation surfaces in the presence of non-condensable gases. This work offers a distinct approach utilizing surface chemistry and structuring together with liquid-infusion for enhanced condensation heat transfer. PMID:23759735

  11. Dropwise Condensation of Low Surface Tension Fluids on Omniphobic Surfaces

    NASA Astrophysics Data System (ADS)

    Rykaczewski, Konrad; Paxson, Adam T.; Staymates, Matthew; Walker, Marlon L.; Sun, Xiaoda; Anand, Sushant; Srinivasan, Siddarth; McKinley, Gareth H.; Chinn, Jeff; Scott, John Henry J.; Varanasi, Kripa K.

    2014-03-01

    Compared to the significant body of work devoted to surface engineering for promoting dropwise condensation heat transfer of steam, much less attention has been dedicated to fluids with lower interfacial tension. A vast array of low-surface tension fluids such as hydrocarbons, cryogens, and fluorinated refrigerants are used in a number of industrial applications, and the development of passive means for increasing their condensation heat transfer coefficients has potential for significant efficiency enhancements. Here we investigate condensation behavior of a variety of liquids with surface tensions in the range of 12 to 28 mN/m on three types of omniphobic surfaces: smooth oleophobic, re-entrant superomniphobic, and lubricant-impregnated surfaces. We demonstrate that although smooth oleophobic and lubricant-impregnated surfaces can promote dropwise condensation of the majority of these fluids, re-entrant omniphobic surfaces became flooded and reverted to filmwise condensation. We also demonstrate that on the lubricant-impregnated surfaces, the choice of lubricant and underlying surface texture play a crucial role in stabilizing the lubricant and reducing pinning of the condensate. With properly engineered surfaces to promote dropwise condensation of low-surface tension fluids, we demonstrate a four to eight-fold improvement in the heat transfer coefficient.

  12. Dropwise condensation of low surface tension fluids on omniphobic surfaces.

    PubMed

    Rykaczewski, Konrad; Paxson, Adam T; Staymates, Matthew; Walker, Marlon L; Sun, Xiaoda; Anand, Sushant; Srinivasan, Siddarth; McKinley, Gareth H; Chinn, Jeff; Scott, John Henry J; Varanasi, Kripa K

    2014-01-01

    Compared to the significant body of work devoted to surface engineering for promoting dropwise condensation heat transfer of steam, much less attention has been dedicated to fluids with lower interfacial tension. A vast array of low-surface tension fluids such as hydrocarbons, cryogens, and fluorinated refrigerants are used in a number of industrial applications, and the development of passive means for increasing their condensation heat transfer coefficients has potential for significant efficiency enhancements. Here we investigate condensation behavior of a variety of liquids with surface tensions in the range of 12 to 28 mN/m on three types of omniphobic surfaces: smooth oleophobic, re-entrant superomniphobic, and lubricant-impregnated surfaces. We demonstrate that although smooth oleophobic and lubricant-impregnated surfaces can promote dropwise condensation of the majority of these fluids, re-entrant omniphobic surfaces became flooded and reverted to filmwise condensation. We also demonstrate that on the lubricant-impregnated surfaces, the choice of lubricant and underlying surface texture play a crucial role in stabilizing the lubricant and reducing pinning of the condensate. With properly engineered surfaces to promote dropwise condensation of low-surface tension fluids, we demonstrate a four to eight-fold improvement in the heat transfer coefficient. PMID:24595171

  13. Dropwise Condensation of Low Surface Tension Fluids on Omniphobic Surfaces

    PubMed Central

    Rykaczewski, Konrad; Paxson, Adam T.; Staymates, Matthew; Walker, Marlon L.; Sun, Xiaoda; Anand, Sushant; Srinivasan, Siddarth; McKinley, Gareth H.; Chinn, Jeff; Scott, John Henry J.; Varanasi, Kripa K.

    2014-01-01

    Compared to the significant body of work devoted to surface engineering for promoting dropwise condensation heat transfer of steam, much less attention has been dedicated to fluids with lower interfacial tension. A vast array of low-surface tension fluids such as hydrocarbons, cryogens, and fluorinated refrigerants are used in a number of industrial applications, and the development of passive means for increasing their condensation heat transfer coefficients has potential for significant efficiency enhancements. Here we investigate condensation behavior of a variety of liquids with surface tensions in the range of 12 to 28 mN/m on three types of omniphobic surfaces: smooth oleophobic, re-entrant superomniphobic, and lubricant-impregnated surfaces. We demonstrate that although smooth oleophobic and lubricant-impregnated surfaces can promote dropwise condensation of the majority of these fluids, re-entrant omniphobic surfaces became flooded and reverted to filmwise condensation. We also demonstrate that on the lubricant-impregnated surfaces, the choice of lubricant and underlying surface texture play a crucial role in stabilizing the lubricant and reducing pinning of the condensate. With properly engineered surfaces to promote dropwise condensation of low-surface tension fluids, we demonstrate a four to eight-fold improvement in the heat transfer coefficient. PMID:24595171

  14. 'Liquid litmus': chemosensory pH-responsive photonic ionic liquids.

    PubMed

    Yung, Ka Yi; Schadock-Hewitt, Abby J; Hunter, Neil P; Bright, Frank V; Baker, Gary A

    2011-04-28

    We report on the founding member of a unique class of luminescent ionic liquids integrating a photoacidic anion that responds to the presence of both condensed- and gas-phase basicity; the analytical response is ratiometric in nature, visible to the naked eye, and offers fascinating prospects in smart photofluids, liquid logic gates, electronic noses, and sensory inks. PMID:21399813

  15. Enhanced Condensation of Vapor Bubbles by Acoustic Actuation

    NASA Astrophysics Data System (ADS)

    Boziuk, Thomas; Smith, Marc; Glezer, Ari

    2014-11-01

    The effects of acoustic actuation on enhancement of the condensation rate of vapor bubbles in a liquid pool are investigated experimentally. Vapor bubbles are formed by direct injection into quiescent liquid in a sealed tank under controlled ambient pressure that varies from atmospheric to partial vacuum. The bubbles are injected vertically from a pressurized steam reservoir through nozzles of varying characteristic diameters, and the actuation is applied during different stages of the bubbles formation and advection. It is shown that kHz range acoustic actuation leads to excitation of high-amplitude surface capillary (Faraday) waves at the vapor-liquid interface that significantly increases the condensation rate. The concomitant controlled changes in bubble volume and in the structure of the vapor interface strongly affect bubble advection in the liquid pool. The increase in condensation rate is affected by the surface waves that increase the mixing in the thermal boundary layer surrounding the bubble, and on the advection of the bubble within the pool. High-speed image processing is used to quantitatively measure the scale of the capillary waves and their effect on vapor bubble dynamics at several ambient pressures that affect the global condensation rate.

  16. Can the ordinary chondrites have condensed from a gas phase

    NASA Technical Reports Server (NTRS)

    Herndon, J. M.; Suess, H. E.

    1977-01-01

    The conditions under which ordinary chondrites containing iron in three different chemical states can form in thermodynamic equilibrium with a gas phase are calculated. Hydrogen depletion factors of 100-1000 are obtained and the formation of liquid condensates from residual gases occurs at pressures (prior to hydrogen depletion) of roughly equal to or greater than 1 atm.

  17. Heat exchanger with intermediate evaporating and condensing fluid

    DOEpatents

    Fraas, Arthur P.

    1978-01-01

    A shell and tube-type heat exchanger, such as a liquid sodium-operated steam generator for use in nuclear reactors, comprises a shell containing a primary fluid tube bundle, a secondary fluid tube bundle at higher elevation, and an intermediate fluid vaporizing at the surface of the primary fluid tubes and condensing at the surface of the secondary fluid tubes.

  18. W-007H B Plant Process Condensate Treatment Facility. Revision 3

    SciTech Connect

    Rippy, G.L.

    1995-01-20

    B Plant Process Condensate (BCP) liquid effluent stream is the condensed vapors originating from the operation of the B Plant low-level liquid waste concentration system. In the past, the BCP stream was discharged into the soil column under a compliance plan which expired January 1, 1987. Currently, the BCP stream is inactive, awaiting restart of the E-23-3 Concentrator. B Plant Steam Condensate (BCS) liquid effluent stream is the spent steam condensate used to supply heat to the E-23-3 Concentrator. The tube bundles in the E-23-3 Concentrator discharge to the BCS. In the past, the BCS stream was discharged into the soil column. Currently, the BCS stream is inactive. This project shall provide liquid effluent systems (BCP/BCS/BCE) capable of operating for a minimum of 20 years, which does not include the anticipated decontamination and decommissioning (D and D) period.

  19. Effect of spontaneous condensation on condensation heat transfer in the presence of non-condensable gases

    SciTech Connect

    Karl, J.; Hein, D.

    1999-07-01

    The presence of non condensable gases like nitrogen or air reduces the condensation heat transfer during condensation of binary steam mixtures. The non condensable gas accumulates in the vapor phase boundary layer and causes a high heat transfer resistance. Especially with high pressures and low water temperatures spontaneous condensation reduces heat transfer additionally. Fog forms within the steam-nitrogen boundary layer and the steam condenses on the water droplets of the fog layer. The convective mass transfer to the cooling water interface diminishes. Raman spectroscopy and film theory are used to quantify this effect locally. The calculation of overall condensation rates in large steam nitrogen systems requires to use three dimensional CFD codes. The paper presents equations to predict fog formation in the boundary layer which can be implemented in CFD codes.

  20. Macromolecular liquids

    SciTech Connect

    Safinya, C.R.; Safran, S.A. ); Pincus, P.A. )

    1990-01-01

    Liquids include a broad range of material systems which are of high scientific and technological interest. Generally speaking, these are partially ordered or disordered phases where the individual molecular species have organized themselves on length scales which are larger than simple fluids, typically between 10 Angstroms and several microns. The specific systems reported on in this book include membranes, microemulsions, micelles, liquid crystals, colloidal suspensions, and polymers. They have a major impact on a broad spectrum of technological industries such as displays, plastics, soap and detergents, chemicals and petroleum, and pharmaceuticals.

  1. Gravitational Condensate Stars

    NASA Astrophysics Data System (ADS)

    Mazur, P.; Mottola, E.

    The issue of the final state of the gravitational collapse will be addressed. Ishall present physical arguments to the effect that the remnant of the gravitationalcollapse of super-massive stars is a cold and dark super-dense object which isthermodynamically and dynamically stable: a Gravitational Condensate Star orQuasi Black Hole (QBH). A QBH is characterized by a huge, but not an infinite,surface redshift. This surface redshift depends universally on the total mass of aQBH and the proper thickness of a thin shell of an exotic matter described bythe Zel'dovich equation of state p = c2 . The velocity of sound in a thin shell isequal to the velocity of light. Hence, this thin shell replaces the event horizon of amathematical black hole ( = 0). Inside a thin shell the zero entropy gravitationalcondensate characterized by the cosmological equation of state p = -c2 resides.A QBH is described by a new static and spherically symmetric solution of Ein-stein's equations supplemented with the proper boundary conditions based on mi-crophysics considerations. The new solution has no singularities and no eventhorizons. Its entropy is maximized under small fluctuations and is given by thestandard hydrodynamic entropy of the thin shell which is proportional to the to-tal mass instead of the Bekenstein-Hawking entropy which is proportional to thesquare of the total mass. This resolves the paradox of an excessively high en-tropy of black holes as compared to their progenitors. The formation of such acold gravitational condensate stellar remnant very likely would require a violentcollapse process with an explosive output of energy. Some observational conse-quences of the formation of gravitational condensate stars will be described.

  2. Expansion in condensates

    SciTech Connect

    Chakrabarti, J.; Sajjad Zahir, M.

    1985-03-01

    We show that the product of local current operators in quantum chromodynamics (QCD), when expanded in terms of condensates, such as psi-barpsi, G/sup a//sub munu/ G/sup a//sub munu/, psi-barGAMMA psipsi-barGAMMApsi, f/sub a/bcG/sup a//sub munu/G/sup b//sub nualpha/ x G/sup c//sub alphamu/, etc., yields a series in Planck's constant. This, however, provides no hint that the higher terms in such an expansion may be less significant.

  3. Confinement Contains Condensates

    SciTech Connect

    Brodsky, Stanley J.; Roberts, Craig D.; Shrock, Robert; Tandy, Peter C.

    2012-03-12

    Dynamical chiral symmetry breaking and its connection to the generation of hadron masses has historically been viewed as a vacuum phenomenon. We argue that confinement makes such a position untenable. If quark-hadron duality is a reality in QCD, then condensates, those quantities that have commonly been viewed as constant empirical mass-scales that fill all spacetime, are instead wholly contained within hadrons; i.e., they are a property of hadrons themselves and expressed, e.g., in their Bethe-Salpeter or light-front wave functions. We explain that this paradigm is consistent with empirical evidence, and incidentally expose misconceptions in a recent Comment.

  4. Liquid-Vapor Coexistence in the Screened Coulomb (Yukawa) Hard Sphere Binary Mixture in Disordered Porous Media: The Mean Spherical Approximation.

    PubMed

    Trokhymchuk; Orozco; Pizio; Vlachy

    1998-11-15

    The thermodynamics of a two-component fluid with a hard core interaction and screened Coulomb (Yukawa) interaction between particles, similar to the primitive model of an electrolyte solution, adsorbed in a disordered matrix of hard spheres, is studied by using replica Ornstein-Zernike integral equations and the mean spherical approximation (MSA). The gas-liquid transition is localized. The coexistence curve is investigated dependent on the range of interaction between fluid species, on matrix density, and on fluid-matrix attraction. We have observed shrinking of the coexistence envelope with increasing matrix density. The critical temperature of adsorbed mixture decreases with increasing matrix density. The critical density is less affected; however, it also decreases slightly. The critical temperature is sensitive to the fluid species-matrix attraction and depends nonmonotonously on their strength. For a given matrix microporosity, it increases slightly and then decreases with augmenting strength of fluid-matrix attraction. The critical density is less affected by this attraction. However, it decreases for the model with a sufficiently long-range tail of fluid-matrix attraction. Copyright 1998 Academic Press. PMID:9792783

  5. Cooling balloons with liquid nitrogen

    NASA Astrophysics Data System (ADS)

    Moreno, A. J.; Ferrari, H.; Bekeris, V.

    2010-12-01

    We present an undergraduate level experiment in which the radius of a rubber balloon is measured as it is cooled with liquid nitrogen. For balloons filled with simple gases that condense at liquid nitrogen temperatures, we found that the volume decreases linearly with time. We compared our measurements with a simplified model based on elementary kinetic theory and thermodynamics that explains this behavior. Students are encouraged to test the validity of the model by repeating the experiment using gas mixtures and gases that do not condense at liquid nitrogen temperatures.

  6. Condensed matter physics and chemistry

    SciTech Connect

    Nellis, W.J.

    1995-10-01

    The proposed Los Alamos Neutron Science Center (LANSCE) upgrade is ideally suited for science-based stockpile stewardship (SBSS) because LANSCE is a highly-intensity pulsed neutron source located at a nuclear weapons design laboratory. The attributes of a high-intensity pulsed source are essential for performing experiments on Pu and other materials important for SBSS. Neutrons can accurately probe thick bulk specimens, probe thin layers both freestanding and embedded in thicker specimens, and provide time-resolution for some phenomena. Both ordered structures and disorder in solids, liquids, and amorphous materials can be characterized, as well as phase transition. Because LANSCE is at a nuclear design laboratory, specimens important for SBSS issues are available. Los Alamos National Laboratory is an appropriate place to develop the requisite hardware to accommodate SBSS specimens, such as Pu.

  7. Semiconductor nanorod liquid crystals

    SciTech Connect

    Li, Liang-shi; Walda, Joost; Manna, Liberato; Alivisatos, A. Paul

    2002-01-28

    Rodlike molecules form liquid crystalline phases with orientational order and positional disorder. The great majority of materials in which liquid crystalline phases have been observed are comprised of organic molecules or polymers, even though there has been continuing and growing interest in inorganic liquid crystals. Recent advances in the control of the sizes and shapes of inorganic nanocrystals allow for the formation of a broad class of new inorganic liquid crystals. Here we show the formation of liquid crystalline phases of CdSe semiconductor nanorods. These new liquid crystalline phases may have great importance for both application and fundamental study.

  8. Modeling of Bulk Evaporation and Condensation

    NASA Technical Reports Server (NTRS)

    Anghaie, S.; Ding, Z.

    1996-01-01

    This report describes the modeling and mathematical formulation of the bulk evaporation and condensation involved in liquid-vapor phase change processes. An internal energy formulation, for these phase change processes that occur under the constraint of constant volume, was studied. Compared to the enthalpy formulation, the internal energy formulation has a more concise and compact form. The velocity and time scales of the interface movement were obtained through scaling analysis and verified by performing detailed numerical experiments. The convection effect induced by the density change was analyzed and found to be negligible compared to the conduction effect. Two iterative methods for updating the value of the vapor phase fraction, the energy based (E-based) and temperature based (T-based) methods, were investigated. Numerical experiments revealed that for the evaporation and condensation problems the E-based method is superior to the T-based method in terms of computational efficiency. The internal energy formulation and the E-based method were used to compute the bulk evaporation and condensation processes under different conditions. The evolution of the phase change processes was investigated. This work provided a basis for the modeling of thermal performance of multi-phase nuclear fuel elements under variable gravity conditions, in which the buoyancy convection due to gravity effects and internal heating are involved.

  9. A 'dry' condensation origin for circumstellar carbonates.

    PubMed

    Toppani, Alice; Robert, François; Libourel, Guy; de Donato, Philippe; Barres, Odile; d'Hendecourt, Louis; Ghanbaja, Jaafar

    2005-10-20

    The signature of carbonate minerals has long been suspected in the mid-infrared spectra of various astrophysical environments such as protostars. Abiogenic carbonates are considered as indicators of aqueous mineral alteration in the presence of CO2-rich liquid water. The recent claimed detection of calcite associated with amorphous silicates in two planetary nebulae and protostars devoid of planetary bodies questions the relevance of this indicator; but in the absence of an alternative mode of formation under circumstellar conditions, this detection remains controversial. The main dust component observed in circumstellar envelopes is amorphous silicates, which are thought to have formed by non-equilibrium condensation. Here we report experiments demonstrating that carbonates can be formed with amorphous silicates during the non-equilibrium condensation of a silicate gas in a H2O-CO2-rich vapour. We propose that the observed astrophysical carbonates have condensed in H2O(g)-CO2(g)-rich, high-temperature and high-density regions such as evolved stellar winds, or those induced by grain sputtering upon shocks in protostellar outflows. PMID:16237436

  10. Condensing osteitis of the clavicle in children

    PubMed Central

    Andreacchio, Antonio; Marengo, Lorenza; Canavese, Federico

    2016-01-01

    AIM To confirm the rarity of this disorder and then to evaluate the effects of antibiotic treatment alone and assess whether this could produce a complete remission of symptoms in children and adolescents. METHODS We made a retrospective review of all cases of condensing osteitis of the clavicle in children and adolescents between January 2007 and January 2016. Outpatient and inpatient medical records, with radiographs, magnetic resonance imaging, triphasic bone scan and computed tomography scans were retrospectively reviewed. All the patients underwent biopsy of the affected clavicle and were treated with intra venous (IV) antibiotics followed by oral antibiotics. RESULTS Seven cases of condensing osteitis of the clavicle were identified. All the patients presented with swelling of the medial end of the clavicle, and 5 out of 7 reported persisting pain. The patients’ mean age at presentation was 11.5 years (range 10.5-13). Biopsy confirmed the diagnosis in all cases. All the patients completed the treatment with IV and oral antibiotics. At last follow-up visit none of the patients complained of residual pain; all had a clinically evident reduction in the swelling of the medial end of the affected clavicle. The mean follow-up was 4 years (range 2-7). CONCLUSION Our findings show that condensing osteitis of the clavicle is a rare condition. Biopsy is needed to confirm diagnosis. The condition should be managed with IV and oral antibiotics. Aggressive surgery should be avoided. PMID:27622150

  11. Gravitational vacuum condensate stars.

    PubMed

    Mazur, Pawel O; Mottola, Emil

    2004-06-29

    A new final state of gravitational collapse is proposed. By extending the concept of Bose-Einstein condensation to gravitational systems, a cold, dark, compact object with an interior de Sitter condensate p(v) = -rho(v) and an exterior Schwarzschild geometry of arbitrary total mass M is constructed. These regions are separated by a shell with a small but finite proper thickness l of fluid with equation of state p = +rho, replacing both the Schwarzschild and de Sitter classical horizons. The new solution has no singularities, no event horizons, and a global time. Its entropy is maximized under small fluctuations and is given by the standard hydrodynamic entropy of the thin shell, which is of the order k(B)lMc/Planck's over 2 pi, instead of the Bekenstein-Hawking entropy formula, S(BH) = 4 pi k(B)GM(2)/Planck's over 2 pi c. Hence, unlike black holes, the new solution is thermodynamically stable and has no information paradox. PMID:15210982

  12. Cosmic curvature and condensation

    NASA Technical Reports Server (NTRS)

    Harwit, Martin

    1992-01-01

    It is shown that the universe may consist of a patchwork of domains with different Riemann curvature constants k = 0, +/-1. Features of a phase transition in which flat space breaks up in a transition 2k0 - k(-) + k(+) with initial scale factors R(-) = R(+) are postulated and explored. It is shown that such a transition is energetically permitted, has the equivalent of a Curie temperature, and can lead in a natural way to the formation of voids and galaxies. It is predicted that, if the ambient universe on average is well fitted by a purely k(-) space, with only occasional domains of k(+) containing galaxies, a density parameter of (A(z sub c + 1)) super -1 should be expected, where z sub c represents the redshift of the earliest objects to have condensed, and A takes on values ranging from about 5 to 3. Present observations of quasars would suggest a density of about 0.03 or 0.05, respectively, but it could be lower if earlier condensation took place.

  13. Pion condensation in holographic QCD

    SciTech Connect

    Albrecht, Dylan; Erlich, Joshua

    2010-11-01

    We study pion condensation at zero temperature in a hard-wall holographic model of hadrons with isospin chemical potential. We find that the transition from the hadronic phase to the pion condensate phase is first order except in a certain limit of model parameters. Our analysis suggests that immediately across the phase boundary the condensate acts as a stiff medium approaching the Zel'dovich limit of equal energy density and pressure.

  14. ‘Crystal Genes’ in Metallic Liquids and Glasses

    NASA Astrophysics Data System (ADS)

    Sun, Yang; Zhang, Feng; Ye, Zhuo; Zhang, Yue; Fang, Xiaowei; Ding, Zejun; Wang, Cai-Zhuang; Mendelev, Mikhail I.; Ott, Ryan T.; Kramer, Matthew J.; Ho, Kai-Ming

    2016-03-01

    We analyze the underlying structural order that transcends liquid, glass and crystalline states in metallic systems. A genetic algorithm is applied to search for the most common energetically favorable packing motifs in crystalline structures. These motifs are in turn compared to the observed packing motifs in the actual liquid or glass structures using a cluster-alignment method. Using this method, we have revealed the nature of the short-range order in Cu64Zr36 glasses. More importantly, we identified a novel structural order in the Al90Sm10 system. In addition, our approach brings new insight into understanding the origin of vitrification and describing mesoscopic order-disorder transitions in condensed matter systems.

  15. ‘Crystal Genes’ in Metallic Liquids and Glasses

    PubMed Central

    Sun, Yang; Zhang, Feng; Ye, Zhuo; Zhang, Yue; Fang, Xiaowei; Ding, Zejun; Wang, Cai-Zhuang; Mendelev, Mikhail I.; Ott, Ryan T.; Kramer, Matthew J.; Ho, Kai-Ming

    2016-01-01

    We analyze the underlying structural order that transcends liquid, glass and crystalline states in metallic systems. A genetic algorithm is applied to search for the most common energetically favorable packing motifs in crystalline structures. These motifs are in turn compared to the observed packing motifs in the actual liquid or glass structures using a cluster-alignment method. Using this method, we have revealed the nature of the short-range order in Cu64Zr36 glasses. More importantly, we identified a novel structural order in the Al90Sm10 system. In addition, our approach brings new insight into understanding the origin of vitrification and describing mesoscopic order-disorder transitions in condensed matter systems. PMID:27030071

  16. Biomimetic super-hydrophobic surfaces for use in enhanced dropwise condensation

    NASA Astrophysics Data System (ADS)

    Cheng, Kuok; Zhang, Bong June; Lee, Chi Young; Kennedy, Mike; Kim, Sunwoo; Yoon, Hyungkee; Kim, Kwang J.; Liu, Jiong; Skandan, Ganesh

    2011-04-01

    There have been many attempts to enhance heat transfer during the condensation (vapor to liquid) process since condensation is a critical heat transfer mechanism in many industrial processes. One conventional method of enhancing condensation heat transfer is to specially treat the condensing heat exchanger surface to adequately promote so-called "dropwise" condensation. Biomimetically constructed coating with hydrophobic materials is often employed for surface treatment. This coating on the condensing heat transfer surface effectively shifts the condensation mode from filmwise (the conventional heat transfer mode) to dropwise (similar to lotus leaves?), resulting in much higher condensation heat transfer. In this method the thickness of coatings is a key parameter governing the heat transfer rate. Thin coating benefits the heat transfer but can lead to weakening hydrophobicity and failure to have an acceptable life span. However, thick coating reduces or eliminates the merit of the dropwise condensation phenomenon because the coating introduces additional thermal resistance. Herein, we report an innovative biomimetic concept in connection with a surface treatment that potentially solves the aforementioned issues. Instead of using conventional dense coatings on the condensing surface, the concept of randomly arranged or structurally oriented nano or submicro-scale fins and/or porous surfaces similar to nature-invented hydrophobic surfaces allowing molecular clustering for effective steam condensation, is presented and experimentally verified.

  17. Experimental investigation of CO2 condensation process using cryogen

    NASA Astrophysics Data System (ADS)

    Lee, Cheonkyu; Yoo, Junghyun; Lee, Jisung; Park, Hana; Jeong, Sangkwon

    2014-01-01

    Carbon dioxide (CO2) is one of the dominant gas molecules that causes greenhouse effect, i.e. global warming. Numerous studies have been carried out to regulate the emission of CO2 to reduce greenhouse gas. The liquid CO2 is a convenient form of transportation compared to high-pressurized gaseous CO2. Therefore, the direct liquefaction mechanism of CO2 at low temperature draws technical attention recently. In particular, cold thermal energy of Liquefied Natural Gas (LNG) could be a candidate to condense gaseous CO2, especially in the LNG powered ship. In this paper, the detailed direct condensation process of CO2 using LN2 with intermittent solidification is investigated. Pressurized CO2 at 600 kPa is directly liquefied in a vessel by liquid nitrogen which is supplied into the coiled tube heat exchanger inside the CO2 vessel. The heat exchanger temperature is controlled from 130 K to 205 K to regulate the solidification and sublimation of CO2 by duty control with cryogenic solenoid valve. The characteristics of CO2 condensation process with cryogen are analyzed from the measurement results. The results show that the solidification causes the significant degradation of CO2 condensation heat transfer. Finally, the condensation rate with and without solidification is compared.

  18. Calorimetry of a Bose-Einstein-condensed photon gas.

    PubMed

    Damm, Tobias; Schmitt, Julian; Liang, Qi; Dung, David; Vewinger, Frank; Weitz, Martin; Klaers, Jan

    2016-01-01

    Phase transitions, as the condensation of a gas to a liquid, are often revealed by a discontinuous behaviour of thermodynamic quantities. For liquid helium, for example, a divergence of the specific heat signals the transition from the normal fluid to the superfluid state. Apart from liquid helium, determining the specific heat of a Bose gas has proven to be a challenging task, for example, for ultracold atomic Bose gases. Here we examine the thermodynamic behaviour of a trapped two-dimensional photon gas, a system that allows us to spectroscopically determine the specific heat and the entropy of a nearly ideal Bose gas from the classical high temperature to the Bose-condensed quantum regime. The critical behaviour at the phase transition is clearly revealed by a cusp singularity of the specific heat. Regarded as a test of quantum statistical mechanics, our results demonstrate a quantitative agreement with its predictions at the microscopic level. PMID:27090978

  19. Calorimetry of a Bose-Einstein-condensed photon gas

    NASA Astrophysics Data System (ADS)

    Damm, Tobias; Schmitt, Julian; Liang, Qi; Dung, David; Vewinger, Frank; Weitz, Martin; Klaers, Jan

    2016-04-01

    Phase transitions, as the condensation of a gas to a liquid, are often revealed by a discontinuous behaviour of thermodynamic quantities. For liquid helium, for example, a divergence of the specific heat signals the transition from the normal fluid to the superfluid state. Apart from liquid helium, determining the specific heat of a Bose gas has proven to be a challenging task, for example, for ultracold atomic Bose gases. Here we examine the thermodynamic behaviour of a trapped two-dimensional photon gas, a system that allows us to spectroscopically determine the specific heat and the entropy of a nearly ideal Bose gas from the classical high temperature to the Bose-condensed quantum regime. The critical behaviour at the phase transition is clearly revealed by a cusp singularity of the specific heat. Regarded as a test of quantum statistical mechanics, our results demonstrate a quantitative agreement with its predictions at the microscopic level.

  20. Calorimetry of a Bose–Einstein-condensed photon gas

    PubMed Central

    Damm, Tobias; Schmitt, Julian; Liang, Qi; Dung, David; Vewinger, Frank; Weitz, Martin; Klaers, Jan

    2016-01-01

    Phase transitions, as the condensation of a gas to a liquid, are often revealed by a discontinuous behaviour of thermodynamic quantities. For liquid helium, for example, a divergence of the specific heat signals the transition from the normal fluid to the superfluid state. Apart from liquid helium, determining the specific heat of a Bose gas has proven to be a challenging task, for example, for ultracold atomic Bose gases. Here we examine the thermodynamic behaviour of a trapped two-dimensional photon gas, a system that allows us to spectroscopically determine the specific heat and the entropy of a nearly ideal Bose gas from the classical high temperature to the Bose-condensed quantum regime. The critical behaviour at the phase transition is clearly revealed by a cusp singularity of the specific heat. Regarded as a test of quantum statistical mechanics, our results demonstrate a quantitative agreement with its predictions at the microscopic level. PMID:27090978

  1. Density functional study of condensation in capped capillaries.

    PubMed

    Yatsyshin, P; Savva, N; Kalliadasis, S

    2015-07-15

    We study liquid adsorption in narrow rectangular capped capillaries formed by capping two parallel planar walls (a slit pore) with a third wall orthogonal to the two planar walls. The most important transition in confined fluids is arguably condensation, where the pore becomes filled with the liquid phase which is metastable in the bulk. Depending on the temperature T, the condensation in capped capillaries can be first-order (at T≤Tcw) or continuous (at T>Tcw), where Tcw is the capillary wetting temperature. At T>Tcw, the capping wall can adsorb mesoscopic amounts of metastable under-condensed liquid. The onset of condensation is then manifested by the continuous unbinding of the interface between the liquid adsorbed on the capping wall and the gas filling the rest of the capillary volume. In wide capped capillaries there may be a remnant of wedge filling transition, which is manifested by the adsorption of liquid drops in the corners. Our classical statistical mechanical treatment predicts a possibility of three-phase coexistence between gas, corner drops and liquid slabs adsorbed on the capping wall. In sufficiently wide capillaries we find that thick prewetting films of finite length may be nucleated at the capping wall below the boundary of the prewetting transition. Prewetting then proceeds in a continuous manner manifested by the unbinding interface between the thick and thin films adsorbed on the side walls. Our analysis is based on a detailed numerical investigation of the density functional theory for the fluid equilibria for a number of illustrative case studies. PMID:26086161

  2. Density functional study of condensation in capped capillaries

    NASA Astrophysics Data System (ADS)

    Yatsyshin, P.; Savva, N.; Kalliadasis, S.

    2015-07-01

    We study liquid adsorption in narrow rectangular capped capillaries formed by capping two parallel planar walls (a slit pore) with a third wall orthogonal to the two planar walls. The most important transition in confined fluids is arguably condensation, where the pore becomes filled with the liquid phase which is metastable in the bulk. Depending on the temperature T, the condensation in capped capillaries can be first-order (at T≤slant {{T}\\text{cw}} ) or continuous (at T\\gt {{T}\\text{cw}} ), where {{T}\\text{cw}} is the capillary wetting temperature. At T \\gt {{T}\\text{cw}} , the capping wall can adsorb mesoscopic amounts of metastable under-condensed liquid. The onset of condensation is then manifested by the continuous unbinding of the interface between the liquid adsorbed on the capping wall and the gas filling the rest of the capillary volume. In wide capped capillaries there may be a remnant of wedge filling transition, which is manifested by the adsorption of liquid drops in the corners. Our classical statistical mechanical treatment predicts a possibility of three-phase coexistence between gas, corner drops and liquid slabs adsorbed on the capping wall. In sufficiently wide capillaries we find that thick prewetting films of finite length may be nucleated at the capping wall below the boundary of the prewetting transition. Prewetting then proceeds in a continuous manner manifested by the unbinding interface between the thick and thin films adsorbed on the side walls. Our analysis is based on a detailed numerical investigation of the density functional theory for the fluid equilibria for a number of illustrative case studies.

  3. Correlations predict gas-condensate flow through chokes

    SciTech Connect

    Osman, M.E.; Dokla, M.E. )

    1992-03-16

    Empirical correlations have developed to describe the behavior of gas-condensate flow through surface chokes. The field data were obtained from a Middle East gas-condensate reservoir and cover a wide range of flow rates and choke sizes. Correlations for gas-condensate systems have not been previously available. These new correlations will help the production engineer to size chokes for controlling production of gas-condensate wells and predicting the performance of flowing wells under various conditions. Four forms of the correlation were developed and checked against data. One form correlates choke upstream pressure with liquid production rate, gas/liquid ratio, and choke size. The second form uses gas production rate instead of the liquid rate. The other two forms use the pressure drop across the choke instead of upstream pressure. All four of the correlations are presented in this paper as nomograms. Accuracy of the different forms was checked with five error parameters: root-mean-square error, mean-absolute error, simple-mean error, mean-percent-age-absolute error, and mean-percentage error. The correlation was found to be the most accurate when pressure-drop data are used instead of choke upstream pressure.

  4. Black Hole Bose Condensation

    NASA Astrophysics Data System (ADS)

    Vaz, Cenalo; Wijewardhana, L. C. R.

    2013-12-01

    General consensus on the nature of the degrees of freedom responsible for the black hole entropy remains elusive despite decades of effort dedicated to the problem. Different approaches to quantum gravity disagree in their description of the microstates and, more significantly, in the statistics used to count them. In some approaches (string theory, AdS/CFT) the elementary degrees of freedom are indistinguishable, whereas they must be treated as distinguishable in other approaches to quantum gravity (eg., LQG) in order to recover the Bekenstein-Hawking area-entropy law. However, different statistics will imply different behaviors of the black hole outside the thermodynamic limit. We illustrate this point by quantizing the Bañados-Teitelboim-Zanelli (BTZ) black hole, for which we argue that Bose condensation will occur leading to a "cold", stable remnant.

  5. Microgravity condensing heat exchanger

    NASA Technical Reports Server (NTRS)

    Thomas, Christopher M. (Inventor); Ma, Yonghui (Inventor); North, Andrew (Inventor); Weislogel, Mark M. (Inventor)

    2011-01-01

    A heat exchanger having a plurality of heat exchanging aluminum fins with hydrophilic condensing surfaces which are stacked and clamped between two cold plates. The cold plates are aligned radially along a plane extending through the axis of a cylindrical duct and hold the stacked and clamped portions of the heat exchanging fins along the axis of the cylindrical duct. The fins extend outwardly from the clamped portions along approximately radial planes. The spacing between fins is symmetric about the cold plates, and are somewhat more closely spaced as the angle they make with the cold plates approaches 90.degree.. Passageways extend through the fins between vertex spaces which provide capillary storage and communicate with passageways formed in the stacked and clamped portions of the fins, which communicate with water drains connected to a pump externally to the duct. Water with no entrained air is drawn from the capillary spaces.

  6. Numerical simulation on inertia controlled steam bubble condensation using MPS

    NASA Astrophysics Data System (ADS)

    Chong, Daotong; Ishiwatari, Yuki; Oka, Yoshiaki; Yan, Junjie; Liu, Jiping

    2013-07-01

    Bubble dynamics is quite complicated in the field of two-phase hydrodynamics because the interfacial heat and mass transfer is comprehensively affected by various influencing factors. Bubble condensation can be either thermally controlled or inertia controlled. Inertia controlled bubble condensation indicates that considerable pressure difference exists between the steam bubble and ambient liquid. In this paper, the inertia controlled steam bubble condensation was simulated using moving particle semi-implicit (MPS) method. The spherical bubble is located in the center of the cylindrical pool which makes the possibility of 2-D axisymmetric computation. The lateral and bottom wall are set to be rigid insulated boundaries and the top is free surface boundary. The pool volume must be large enough to eliminate the effects by pool wall. The initial bubble pressure ranges from 0.48 MPa to 3.98 MPa, and the initial bubble diameter ranges from 2 mm to 5 mm, and the ambient water pressure and temperature is 0.1 MPa and 70 °C, respectively. The bubble dynamics during condensation was investigated and the influences of initial bubble pressure and diameter were obtained. The bubble deformation during condensation is shown in figure 1, and the variations of bubble diameters and pressures during condensation are shown in figures 2 and 3, respectively.

  7. The partitioning of hydrogen sulfide in the condensers of Geysers Unit 15

    NASA Astrophysics Data System (ADS)

    Weres, O.

    1982-09-01

    Geysers Unit 15 was the first of the geothermal units equipped with surface condensers to go on line at The Geysers power plant of the Pacific Gas and Electric Company. Units 1 through 12 have contact condensers. The switch to surface condensers was motivated by considerations of hydrogen sulfide mission abatement. In the contact condensers, there is a large liquid-to-vapor ratio, and about 75% of the hydrogen sulfide that is present in the geothermal steam supply ends up dissolved in the cooling water. Once in the cooling water, it is emitted to the atmosphere from the cooling towers unless further, tertiary abatement is employed. It was reasoned that, because the liquid-to-vapor ratio in a surface condenser would be smaller by a factor of about twenty-five than in a contact condenser, most of the hydrogen sulfide would remain in the vapor phase and leave with the gas vented from the condenser rather than by dissolving in the condensate. Unit 15 is equipped with a Stretford Unit, which removes the hydrogen sulfide from the vent gas and converts it to elemental sulfur by reaction with air. Therefore, the fraction of the hydrogen sulfide that leaves the condenser with the vent gas is not emitted to the atmosphere.

  8. Impurities in Bose-Einstein Condensates: From Polaron to Soliton.

    PubMed

    Shadkhoo, Shahriar; Bruinsma, Robijn

    2015-09-25

    We propose that impurities in a Bose-Einstein condensate which is coupled to a transversely laser-pumped multimode cavity form an experimentally accessible and analytically tractable model system for the study of impurities solvated in correlated liquids and the breakdown of linear-response theory [corrected]. As the strength of the coupling constant between the impurity and the Bose-Einstein condensate is increased, which is possible through Feshbach resonance methods, the impurity passes from a large to a small polaron state, and then to an impurity-soliton state. This last transition marks the breakdown of linear-response theory. PMID:26451565

  9. 1 and 2 Dimensional Bose Einstein Condensates

    NASA Astrophysics Data System (ADS)

    Vogels, Johnny; Gorlitz, Axel; Raman, Chandra; Gustavson, Todd; Drndic, Marija; Leanhardt, Aaron; Abo-Shaeer, Jamil; Loew, Robert; Ketterle, Wolfgang

    2001-05-01

    We have created condensates in which the zero point motion exceeds the mean field enegy in either 2 (1D-condensate) or 1 dimension (2D-condensate). We describe the optical traps and magnetic traps being used, their limitations, and the regimes that are accessible. Some of our 1D condensates should have limited coherence properties (quasi-condensates).

  10. Amine catalyzed condensation of tetraethylorthosilicate

    NASA Technical Reports Server (NTRS)

    Jones, S.

    2001-01-01

    The catalysis of the condensation of hydrolyzed metal alkoxides by amines has been mentioned in the literature, but there has been no systematic study of their influence on the rate of the condensation reaction of the alkoxide and the microstructure of the resultant gel.

  11. An ultra-high-performance liquid chromatography-tandem mass spectrometric method for the determination of hederacoside C, a drug candidate for respiratory disorder, in rat plasma.

    PubMed

    Rehman, Shaheed Ur; Choi, Min Sun; Kim, In Sook; Kim, Seung Hyun; Yoo, Hye Hyun

    2016-09-10

    Hederacoside C is a principal bioactive pharmaceutical ingredient of Hedera helix leaf extracts. H. helix extracts have long been used in folk medicine for the treatment of respiratory disorders. Currently, hederacoside C is investigated as a promising candidate for the treatment of respiratory diseases. In this study, an accurate, sensitive, rapid, and reliable bioanalytical method was developed for the determination of hederacoside C in rat plasma using ultra high-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). For sample preparation, plasma proteins were precipitated with 0.1% acetic acid in acetonitrile. Waters UPLC BEH C18 (2.1mm I.D.×100mm, 1.7μm) column was used for chromatographic separation. A gradient elution of mobile phases consisting of 0.02% acetic acid in distilled water (solvent A) and 0.02% acetic acid in acetonitrile (solvent B) was used at a flow rate of 0.3mL/min. The multiple reaction monitoring (MRM) mode was used for mass spectrometric detection; the MRM transitions were m/z 1219.7→m/z 469.2 for hederacoside C and m/z 1108.3→m/z 221.2 for ginsenoside Rb1 (internal standard) in the negative ionization mode. A calibration curve was constructed in the range of 10-1000ng/mL. The intra- and inter-day precision and accuracy were within 5%. The developed UPLC-MS/MS method was successfully applied in a pharmacokinetic study of hederacoside C in rats. Hederacoside C was quickly but inadequately absorbed from the gastrointestinal tract of rats resulting in extremely low bioavailability and relatively slow clearance. PMID:27411171

  12. Excitonic condensation in bilayer systems

    NASA Astrophysics Data System (ADS)

    Su, Jung-Jung

    Among the many examples of Bose condensation considered in physics, electron-hole-pair (exciton) condensation has maintained special interest because it has been difficult to realize experimentally, and because of controversy about condensate properties. In this thesis, we studied the various aspects of spontaneous symmetry broken state of exciton in bilayer using mean field theory. We calculated the photoluminescence of excitonic condensation created by laser. We developed a one-dimensional toy model of excitonic supercurrent using mean field theory plus non-equilibrium Green's function (NEGF) which give qualitatively consistent results with experiments. We proposed graphene bilayer as a novel system for excitonic condensation to occur and estimate it to exist even at temperature as high as room temperature.

  13. Polariton condensation in a strain-compensated planar microcavity with InGaAs quantum wells

    SciTech Connect

    Cilibrizzi, Pasquale; Askitopoulos, Alexis Silva, Matteo; Lagoudakis, Pavlos G.; Bastiman, Faebian; Clarke, Edmund; Zajac, Joanna M.; Langbein, Wolfgang

    2014-11-10

    The investigation of intrinsic interactions in polariton condensates is currently limited by the photonic disorder of semiconductor microcavity structures. Here, we use a strain compensated planar GaAs/AlAs{sub 0.98}P{sub 0.02} microcavity with embedded InGaAs quantum wells having a reduced cross-hatch disorder to overcome this issue. Using real and reciprocal space spectroscopic imaging under non-resonant optical excitation, we observe polariton condensation and a second threshold marking the onset of photon lasing, i.e., the transition from the strong to the weak-coupling regime. Condensation in a structure with suppressed photonic disorder is a necessary step towards the implementation of periodic lattices of interacting condensates, providing a platform for on chip quantum simulations.

  14. Description of Liquid Nitrogen Experimental Test Facility

    NASA Technical Reports Server (NTRS)

    Jurns, John M.; Jacobs, Richard E.; Saiyed, Naseem H.

    1991-01-01

    The Liquid Nitrogen Test Facility is a unique test facility for ground-based liquid nitrogen experimentation. The test rig consists of an insulated tank of approximately 12.5 cubic ft in volume, which is supplied with liquid nitrogen from a 300 gal dewar via a vacuum jacketed piping system. The test tank is fitted with pressure and temperature measuring instrumentation, and with two view ports which allow visual observation of test conditions. To demonstrate the capabilities of the facility, the initial test program is briefly described. The objective of the test program is to measure the condensation rate by injecting liquid nitrogen as a subcooled spray into the ullage of a tank 50 percent full of liquid nitrogen at saturated conditions. The condensation rate of the nitrogen vapor on the subcooled spray can be analytically modeled, and results validated and corrected by experimentally measuring the vapor condensation on liquid sprays.

  15. Description of liquid nitrogen experimental test facility

    NASA Technical Reports Server (NTRS)

    Jurns, J. M.; Jacobs, R. E.; Saiyed, N. H.

    1992-01-01

    The Liquid Nitrogen Test Facility is a unique test facility for ground-based liquid nitrogen experimentation. The test rig consists of an insulated tank of approximately 12.5 cubic ft in volume, which is supplied with liquid nitrogen from a 300 gal dewar via a vacuum jacketed piping system. The test tank is fitted with pressure and temperature measuring instrumentation, and with two view ports which allow visual observation of test conditions. To demonstrate the capabilities of the facility, the initial test program is briefly described. The objective of the test program is to measure the condensation rate by injecting liquid nitrogen as a subcooled spray into the ullage of a tank 50 percent full of liquid nitrogen at saturated conditions. The condensation rate of the nitrogen vapor on the subcooled spray can be analytically modeled, and results validated and corrected by experimentally measuring the vapor condensation on liquid sprays.

  16. Convergent strand array liquid pumping system

    NASA Technical Reports Server (NTRS)

    Collins, Earl R., Jr. (Inventor)

    1989-01-01

    A surface-tension liquid pumping system is provided by one or more arrays of converging solid monofilament fibers or metal wires (strands) spaced apart at an input end to gather liquid, and gathered close together at the opposite end where menisci forms between wetted strands to force liquid in the direction of convergence of the strands. The liquid pumping system is independent of gravity. It is illustrated as being used in a heat pump having a heating box to vaporize the liquid and a condensing chamber. Condensed liquid is returned by the pumping system to the heating box where it is again vaporized. A vapor tube carries the vapor to the condensing chamber. In that way, a closed system pumps heat from the heating box to the evaporating chamber and from there radiated to the atmosphere.

  17. Dynamics of Spin-Orbit Coupled Bose-Einstein Condensates in a Random Potential

    NASA Astrophysics Data System (ADS)

    Mardonov, Sh.; Modugno, M.; Sherman, E. Ya.

    2015-10-01

    Disorder plays a crucial role in spin dynamics in solids and condensed matter systems. We demonstrate that for a spin-orbit coupled Bose-Einstein condensate in a random potential two mechanisms of spin evolution that can be characterized as "precessional" and "anomalous" are at work simultaneously. The precessional mechanism, typical for solids, is due to the condensate displacement. The unconventional anomalous mechanism is due to the spin-dependent velocity producing the distribution of the condensate spin polarization. The condensate expansion is accompanied by a random displacement and fragmentation, where it becomes sparse, as clearly revealed in the spin dynamics. Thus, different stages of the evolution can be characterized by looking at the condensate spin.

  18. Dynamics of Spin-Orbit Coupled Bose-Einstein Condensates in a Random Potential.

    PubMed

    Mardonov, Sh; Modugno, M; Sherman, E Ya

    2015-10-30

    Disorder plays a crucial role in spin dynamics in solids and condensed matter systems. We demonstrate that for a spin-orbit coupled Bose-Einstein condensate in a random potential two mechanisms of spin evolution that can be characterized as "precessional" and "anomalous" are at work simultaneously. The precessional mechanism, typical for solids, is due to the condensate displacement. The unconventional anomalous mechanism is due to the spin-dependent velocity producing the distribution of the condensate spin polarization. The condensate expansion is accompanied by a random displacement and fragmentation, where it becomes sparse, as clearly revealed in the spin dynamics. Thus, different stages of the evolution can be characterized by looking at the condensate spin. PMID:26565441

  19. 40 CFR 258.28 - Liquids restrictions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 1 CFR part 51. This material is incorporated as it exists on the date of approval and a notice of.../code_of_federal_regulations/ibr_locations.html. (2) Gas condensate means the liquid generated as...

  20. Holographic p-wave superconductor with disorder

    NASA Astrophysics Data System (ADS)

    Areán, D.; Farahi, A.; Pando Zayas, L. A.; Salazar Landea, I.; Scardicchio, A.

    2015-07-01

    We implement the effects of disorder on a holographic p-wave superconductor by introducing a random chemical potential which defines the local energy of the charge carriers. Since there are various possibilities for the orientation of the vector order parameter, we explore the behavior of the condensate in the parallel and perpendicular directions to the introduced disorder. We clarify the nature of various branches representing competing solutions and construct the disordered phase diagram. We find that moderate disorder enhances superconductivity as determined by the value of the condensate. Though we mostly focus on uncorrelated noise, we also consider a disorder characterized by its spectral properties and study in detail its influence on the spectral properties of the condensate and charge density. We find fairly universal responses of the resulting power spectra characterized by linear functions of the disorder power spectrum.

  1. Infrared spectroscopy of homogeneously nucleated hydrazine aerosols - Disordered and crystalline phases. [in planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Dunder, T.; Clapp, M. L.; Miller, R. E.

    1993-01-01

    It is shown that aerosols generated at low temperatures and high condensation rate spontaneously form in a highly crystalline state. The resonant absorption bands in the IR spectra of these highly crystalline particles are much sharper than any reported previously in the bulk, and reveal details in the N-H vibrational bands that have not been previously observed. A disordered phase is also observed at somewhat higher temperatures. These results are consistent with this being a supercooled liquid. The fact that the spectra associated with these two aerosol phases are quite different is important to any future attempts at detecting hydrazine aerosols in planetary atmospheres by remote sensing techniques.

  2. Characterization of spacecraft humidity condensate

    NASA Technical Reports Server (NTRS)

    Muckle, Susan; Schultz, John R.; Sauer, Richard L.

    1994-01-01

    When construction of Space Station Freedom reaches the Permanent Manned Capability (PMC) stage, the Water Recovery and Management Subsystem will be fully operational such that (distilled) urine, spent hygiene water, and humidity condensate will be reclaimed to provide water of potable quality. The reclamation technologies currently baselined to process these waste waters include adsorption, ion exchange, catalytic oxidation, and disinfection. To ensure that the baseline technologies will be able to effectively remove those compounds presenting a health risk to the crew, the National Research Council has recommended that additional information be gathered on specific contaminants in waste waters representative of those to be encountered on the Space Station. With the application of new analytical methods and the analysis of waste water samples more representative of the Space Station environment, advances in the identification of the specific contaminants continue to be made. Efforts by the Water and Food Analytical Laboratory at JSC were successful in enlarging the database of contaminants in humidity condensate. These efforts have not only included the chemical characterization of condensate generated during ground-based studies, but most significantly the characterization of cabin and Spacelab condensate generated during Shuttle missions. The analytical results presented in this paper will be used to show how the composition of condensate varies amongst enclosed environments and thus the importance of collecting condensate from an environment close to that of the proposed Space Station. Although advances were made in the characterization of space condensate, complete characterization, particularly of the organics, requires further development of analytical methods.

  3. Water condensation: a multiscale phenomenon.

    PubMed

    Jensen, Kasper Risgaard; Fojan, Peter; Jensen, Rasmus Lund; Gurevich, Leonid

    2014-02-01

    The condensation of water is a phenomenon occurring in multiple situations in everyday life, e.g., when fog is formed or when dew forms on the grass or on windows. This means that this phenomenon plays an important role within the different fields of science including meteorology, building physics, and chemistry. In this review we address condensation models and simulations with the main focus on heterogeneous condensation of water. The condensation process is, at first, described from a thermodynamic viewpoint where the nucleation step is described by the classical nucleation theory. Further, we address the shortcomings of the thermodynamic theory in describing the nucleation and emphasize the importance of nanoscale effects. This leads to the description of condensation from a molecular viewpoint. Also presented is how the nucleation can be simulated by use of molecular models, and how the condensation process is simulated on the macroscale using computational fluid dynamics. Finally, examples of hybrid models combining molecular and macroscale models for the simulation of condensation on a surface are presented. PMID:24749461

  4. SEPARATION OF VAPOR-PHASE ALCOHOL/WATER MIXTURES VIA FRACTIONAL CONDENSATION USING A PILOT-SCALE DEPHLEGMATOR: ENHANCEMENT OF THE PREVAPORATION PROCESS SEPARATION FACTOR

    EPA Science Inventory

    In prevaporation, a liquid mixture contacts a membrane surface that preferentially permeates one of the liquid components as a vapor. Our approach to improving pervaporation performance is to replace the one-stage condenser traditionally used to condense the permeate with a frac...

  5. Controlling condensation and frost growth with chemical micropatterns

    DOE PAGESBeta

    Boreyko, Jonathan B.; Hansen, Ryan R.; Murphy, Kevin R.; Nath, Saurabh; Retterer, Scott T.; Collier, C. Patrick

    2016-01-22

    Frost growth on chilled hydrophobic surfaces is an inter-droplet phenomenon, where frozen droplets harvest water from supercooled liquid droplets to grow ice bridges that propagate across the surface in a chain reaction. To date, no surface has been able to passively prevent the in-plane growth of frost across the population of supercooled condensate. Here, we demonstrate that when the nucleation sites for supercooled condensate are properly controlled with chemical micropatterns, the speed of frost growth can be slowed and even halted entirely. This stoppage of frost growth is attributed to the large interdroplet separation between condensate upon the onset ofmore » freezing, which was controlled by the pitch of the chemical patterns and by deliberately triggering an early freezing event. Lastly, these findings reveal that frost growth can be passively suppressed by designing surfaces to spatially control nucleation sites and/or temporally control the onset of freezing events.« less

  6. Controlling condensation and frost growth with chemical micropatterns

    PubMed Central

    Boreyko, Jonathan B.; Hansen, Ryan R.; Murphy, Kevin R.; Nath, Saurabh; Retterer, Scott T.; Collier, C. Patrick

    2016-01-01

    In-plane frost growth on chilled hydrophobic surfaces is an inter-droplet phenomenon, where frozen droplets harvest water from neighboring supercooled liquid droplets to grow ice bridges that propagate across the surface in a chain reaction. To date, no surface has been able to passively prevent the in-plane growth of ice bridges across the population of supercooled condensate. Here, we demonstrate that when the separation between adjacent nucleation sites for supercooled condensate is properly controlled with chemical micropatterns prior to freezing, inter-droplet ice bridging can be slowed and even halted entirely. Since the edge-to-edge separation between adjacent supercooled droplets decreases with growth time, deliberately triggering an early freezing event to minimize the size of nascent condensation was also necessary. These findings reveal that inter-droplet frost growth can be passively suppressed by designing surfaces to spatially control nucleation sites and by temporally controlling the onset of freezing events. PMID:26796663

  7. Controlling condensation and frost growth with chemical micropatterns

    NASA Astrophysics Data System (ADS)

    Boreyko, Jonathan B.; Hansen, Ryan R.; Murphy, Kevin R.; Nath, Saurabh; Retterer, Scott T.; Collier, C. Patrick

    2016-01-01

    In-plane frost growth on chilled hydrophobic surfaces is an inter-droplet phenomenon, where frozen droplets harvest water from neighboring supercooled liquid droplets to grow ice bridges that propagate across the surface in a chain reaction. To date, no surface has been able to passively prevent the in-plane growth of ice bridges across the population of supercooled condensate. Here, we demonstrate that when the separation between adjacent nucleation sites for supercooled condensate is properly controlled with chemical micropatterns prior to freezing, inter-droplet ice bridging can be slowed and even halted entirely. Since the edge-to-edge separation between adjacent supercooled droplets decreases with growth time, deliberately triggering an early freezing event to minimize the size of nascent condensation was also necessary. These findings reveal that inter-droplet frost growth can be passively suppressed by designing surfaces to spatially control nucleation sites and by temporally controlling the onset of freezing events.

  8. Steam generators, turbines, and condensers. Volume six

    SciTech Connect

    Not Available

    1986-01-01

    Volume six covers steam generators (How steam is generated, steam generation in a PWR, vertical U-tube steam generators, once-through steam generators, how much steam do steam generators make.), turbines (basic turbine principles, impulse turbines, reaction turbines, turbine stages, turbine arrangements, turbine steam flow, steam admission to turbines, turbine seals and supports, turbine oil system, generators), and condensers (need for condensers, basic condenser principles, condenser arrangements, heat transfer in condensers, air removal from condensers, circulating water system, heat loss to the circulating water system, factors affecting condenser performance, condenser auxiliaries).

  9. Liquid-vapor critical behavior in silica aerogel

    NASA Astrophysics Data System (ADS)

    Herman, Tobias Kent

    Fluids in porous media provide a testing ground for the effects of disorder and confinement on phase transitions and critical phenomena. Specifically, highly porous silica aerogel with its tenuous solid structure has allowed low temperature physicists to probe the effect of dilute fixed impurities on both the 4He superfluid transition and the 3He superfluid transition. Both systems have yielded exciting results and work is ongoing, especially on 3He in aerogel. This thesis explores the effect of aerogel on another transition---the liquid-vapor transition near the liquid-vapor critical point. In dense porous media, the liquid-vapor transition is usually described as capillary condensation---a process which assigns surface tension a primary role in determining the thermodynamic state of the system. However, aerogels are often so diffuse (less than 5% silica by volume---the rest is open space) that it becomes difficult to speak of pore size and meniscus shape as one would in a denser porous medium. As one approaches the liquid-vapor critical point, thermal fluctuations within the fluid grow until they exceed the scale of the aerogel strands and pores themselves. In this regime one cannot expect surface tension to control the thermodynamics of the system---it is instead in a regime where thermal fluctuations may govern its behavior. In the past there were even suggestions that the addition of aerogel might shift the character of the transition into another universality class. The following chapters present data collected on helium and neon in aerogel near their respective liquid-vapor critical points. While the behavior of the fluid at low temperatures is consistent with the pictures provided by capillary condensation, closer to the critical point they are incompatible and remain somewhat unexplained. Evidence for a shift in universality class was not found---in fact there was very little evidence for a macroscopic equilibrium transition of any type.

  10. Coulomb interactions and fermion condensation

    SciTech Connect

    Capstick, S.; Cutkosky, R.E.; Joensen, M.A. ); Wang, K.C. )

    1990-08-15

    The influence of the Coulomb interaction in states containing massless and flavorless fermion-antifermion pairs is studied, using a continuum formulation within the finite volume {ital S}{sup 3}. Several different forms for the Coulomb interaction are examined, including confining potentials as well as nonconfining potentials. The calculations show that if the interaction is strong enough, the Coulomb interaction leads to condensation of pairs, and that this condensation has a chiral character. The condensation does not depend on whether the interaction is confining. It is found that simplified variational approximations are not accurate enough for an adequate description of the states.

  11. Liquid methane gelled with methanol and water reduces rate of nitrogen absorption

    NASA Technical Reports Server (NTRS)

    Vanderwall, E. M.

    1972-01-01

    Dilution of gelant vapor with inert carrier gas accomplishes gelation. Mixture is injected through heated tube and orifice into liquid methane for immediate condensation within bulk of liquid. Direct dispersion of particles in liquid avoids condensation on walls of vessel and eliminates additional mixing.

  12. Using condenser performance measurements to optimize condenser cleaning

    SciTech Connect

    Wolff, P.J.; March, A.; Pearson, H.S.

    1996-05-01

    Because plant personnel perform condenser monitoring primarily to determine cleaning schedules, the accuracy and repeatability of a technique should be viewed within the context of a condenser cleaning schedule. Lower accuracy is acceptable if the cleaning schedule arising from that system is identical to a cleaning schedule arising from a technique with higher accuracy. Three condenser performance monitors were implemented and compared within the context of a condenser cleaning schedule to determine the relative advantages of different condenser monitoring techniques. These systems include a novel on-line system that consists of an electromagnetic flowmeter and an RTD mounted in a compact waterproof cylinder, an overall on-line system, and routine plant tests. The fouling measurements from each system are used in an optimization program which automatically computes a cleaning schedule that minitrack the combined cost of cleaning and the cost of increased fuel consumption caused by condenser fouling. The cleaning schedules resulting from each system`s measurements are compared. The optimization routine is also used to evaluate the sensitivity of optimal cleaning schedules to fouling rate and of the cost in dollars for non-optimal cleaning.

  13. Is natrocarbonatite a cognate fluid condensate?

    NASA Astrophysics Data System (ADS)

    Nielsen, Troels; Veksler, Ilya

    2001-10-01

    Natrocarbonatite flows in the crater of the volcano Oldoinyo Lengai (Tanzania) are the only carbonatite magmas observed to erupt and have provided strong arguments in favor of a magmatic origin for carbonatite. The currently favored explanation for the genesis of these carbonatites by liquid immiscibility between a silicate and a carbonatite melt is questioned based on the extremely low eruption temperatures of 544-593 °C and compositional and mineralogical characteristics not in agreement with experimental constraints. Experimental investigations of the relationship between Oldoinyo Lengai natrocarbonatite and related silicate rock compositions do indicate that alkali-bearing peralkaline carbonatite with liquidus calcite can form by liquid immiscibility. At the same time, these experiments result in evidence which speaks against a liquid immiscibility origin for the highly alkaline and peralkaline Oldoinyo Lengai natrocarbonatite. On the carbonatite side of the miscibility gap, fractional crystallization cannot account for a liquid evolution from alkali-bearing peralkaline carbonatite to highly alkaline natrocarbonatite. Such an evolution does not seem to be compatible with the liquidus mineral assemblages and the chemistry of Oldoinyo Lengai natrocarbonatite. No natural silicate magma is known to produce natrocarbonatite compositions by liquid immiscibility. The best interpretation of the Oldoinyo Lengai natrocarbonatite flows involves expulsion of a cognate, mobile, alkaline, and CO2-rich fluid condensate. This conclusion is supported by recent studies of silicate and carbonatite melt inclusions in minerals of ultramafic alkaline complexes, trace element partitioning, isotopic constraints, and by experimental data on major element partitioning between coexisting H2O-CO2-rich fluid and carbonatitic melt. In contrast to all other suggested modes of formation, an origin of Oldoinyo Lengai natrocarbonatite from cognate fluid appears best to be in agreement with the

  14. Is natrocarbonatite a cognate fluid condensate?

    NASA Astrophysics Data System (ADS)

    Nielsen, Troels; Veksler, Ilya

    Natrocarbonatite flows in the crater of the volcano Oldoinyo Lengai (Tanzania) are the only carbonatite magmas observed to erupt and have provided strong arguments in favor of a magmatic origin for carbonatite. The currently favored explanation for the genesis of these carbonatites by liquid immiscibility between a silicate and a carbonatite melt is questioned based on the extremely low eruption temperatures of 544-593 °C and compositional and mineralogical characteristics not in agreement with experimental constraints. Experimental investigations of the relationship between Oldoinyo Lengai natrocarbonatite and related silicate rock compositions do indicate that alkali-bearing peralkaline carbonatite with liquidus calcite can form by liquid immiscibility. At the same time, these experiments result in evidence which speaks against a liquid immiscibility origin for the highly alkaline and peralkaline Oldoinyo Lengai natrocarbonatite. On the carbonatite side of the miscibility gap, fractional crystallization cannot account for a liquid evolution from alkali-bearing peralkaline carbonatite to highly alkaline natrocarbonatite. Such an evolution does not seem to be compatible with the liquidus mineral assemblages and the chemistry of Oldoinyo Lengai natrocarbonatite. No natural silicate magma is known to produce natrocarbonatite compositions by liquid immiscibility. The best interpretation of the Oldoinyo Lengai natrocarbonatite flows involves expulsion of a cognate, mobile, alkaline, and CO2-rich fluid condensate. This conclusion is supported by recent studies of silicate and carbonatite melt inclusions in minerals of ultramafic alkaline complexes, trace element partitioning, isotopic constraints, and by experimental data on major element partitioning between coexisting H2O-CO2-rich fluid and carbonatitic melt. In contrast to all other suggested modes of formation, an origin of Oldoinyo Lengai natrocarbonatite from cognate fluid appears best to be in agreement with the

  15. Quantum entanglement in condensed matter systems

    NASA Astrophysics Data System (ADS)

    Laflorencie, Nicolas

    2016-08-01

    This review focuses on the field of quantum entanglement applied to condensed matter physics systems with strong correlations, a domain which has rapidly grown over the last decade. By tracing out part of the degrees of freedom of correlated quantum systems, useful and non-trivial information can be obtained through the study of the reduced density matrix, whose eigenvalue spectrum (the entanglement spectrum) and the associated Rényi entropies are now well recognized to contain key features. In particular, the celebrated area law for the entanglement entropy of ground-states will be discussed from the perspective of its subleading corrections which encode universal details of various quantum states of matter, e.g. symmetry breaking states or topological order. Going beyond entropies, the study of the low-lying part of the entanglement spectrum also allows to diagnose topological properties or give a direct access to the excitation spectrum of the edges, and may also raise significant questions about the underlying entanglement Hamiltonian. All these powerful tools can be further applied to shed some light on disordered quantum systems where impurity/disorder can conspire with quantum fluctuations to induce non-trivial effects. Disordered quantum spin systems, the Kondo effect, or the many-body localization problem, which have all been successfully (re)visited through the prism of quantum entanglement, will be discussed in detail. Finally, the issue of experimental access to entanglement measurement will be addressed, together with its most recent developments.

  16. Hierarchical condensation near phase equilibrium

    NASA Astrophysics Data System (ADS)

    Olemskoi, A. I.; Yushchenko, O. V.; Borisyuk, V. N.; Zhilenko, T. I.; Kosminska, Yu. O.; Perekrestov, V. I.

    2012-06-01

    A novel mechanism of new phase formation is studied both experimentally and theoretically in the example of quasi-equilibrium stationary condensation in an ion-plasma sputterer. Copper condensates are obtained to demonstrate that a specific network structure is formed as a result of self-assembly in the course of deposition. The fractal pattern related is inherent in the phenomena of diffusion limited aggregation. Condensate nuclei are shown to form statistical ensemble of hierarchically subordinated objects distributed in ultrametric space. The Langevin equation and the Fokker-Planck equation related are found to describe stationary distribution of thermodynamic potential variations at condensation. Time dependence of the formation probability of branching structures is found to clarify the experimental situation.

  17. Optical Imaging of Water Condensation on Lubricant Impregnated Micropillar Arrays

    NASA Astrophysics Data System (ADS)

    Kajiya, Tadashi; Schellenberger, Frank; Papadopoulos, Periklis; Vollmer, Doris; Butt, Hans-Jürgen

    2015-11-01

    We explored the condensation of water drops on a lubricant-impregnated surface, i.e., a micropillar patterned surface impregnated with a ionic liquid. Growing drops were imaged in 3D using a laser scanning confocal microscope equipped with a temperature and humidity control. On a lubricant-impregnated hydrophobic micropillar array, different stages of condensation can be discriminated: - Nucleation on a lubricant surface. - Regular alignement between micropillars and formation of a three-phase contact line on a bottom of the substrate. - Deformation and bridging by coalescence, leading to a detachment of the drops from the bottom substrate to pillars'top faces. However, on a lubricant-impregnated hydrophilic micropillar array, the condensed water covers the micropillars by dewetting the lubricant. As a result, the surface loses its slippery property. Our results provide fundamental concepts how these solid/liquid hybrid surfaces can be applied for facile removal of condensed water, as well as necessity of the appropriate surface treatment. Financial support from ERC for the advanced grant 340391-SUPRO is gratefully acknowledged.

  18. Condensation phase diagrams for lipid-coated perfluorobutane microbubbles.

    PubMed

    Mountford, Paul A; Sirsi, Shashank R; Borden, Mark A

    2014-06-01

    The goal of this study was to explore the thermodynamic conditions necessary to condense aqueous suspensions of lipid-coated gas-filled microbubbles into metastable liquid-filled nanodrops as well as the physicochemical mechanisms involved with this process. Individual perfluorobutane microbubbles and their lipid shells were observed as they were pressurized at 34.5 kPa s(-1) in a microscopic viewing chamber maintained at temperatures ranging from 5 to 75 °C. The microbubbles contracted under pressure, ultimately leading to either full dissolution or microbubble-to-nanodrop condensation. Temperature-pressure phase diagrams conveying condensation and stability transitions were constructed for microbubbles coated with saturated diacylphosphatidylcholine lipids of varying acyl chain length (C16 to C24). The onset of full dissolution was shifted to higher temperatures with the use of longer acyl chain lipids or supersaturated media. Longer chain lipid shells resisted both dissolution of the gas core and mechanical compression through a pronounced wrinkle-to-fold collapse transition. Interestingly, the lipid shell also provided a mechanical resistance to condensation, shifting the vapor-to-liquid transition to higher pressures than for bulk perfluorobutane. This result indicated that the lipid shell can provide a negative apparent surface tension under compression. Overall, the results of this study will aid in the design and formulation of vaporizable fluorocarbon nanodrops for various applications, such as diagnostic ultrasound imaging, targeted drug delivery, and thermal ablation. PMID:24824162

  19. Condensing the Moon from a MAD Earth

    NASA Astrophysics Data System (ADS)

    Lock, S. J.; Stewart, S. T.; Petaev, M. I.; Leinhardt, Z. M.; Mace, M.; Jacobsen, S. B.; Cuk, M.

    2015-12-01

    The favored theory for lunar origin is the giant impact hypothesis, where a protoplanet collides with the growing Earth and creates an orbiting disk of material that forms the Moon. However, the astonishing isotopic similarity between the Earth and Moon cannot be explained by current giant impact models without appealing to highly specific circumstances. Here, we demonstrate that a condensation model for lunar origin, achieved via a previously unrecognized class of post-impact states, produces the Moon's major characteristics. The required class of post-impact states is defined by (i) a high degree of vaporization and (ii) rapid rotation. When these two criteria are met, the mantle, atmosphere and disk (MAD) form a dynamically and thermodynamically continuous structure that quickly mixes, thereby diluting initial compositional heterogeneities. Then, partial condensation from the pressure-supported mass beyond the Roche limit produces a Moon that is isotopically similar to the bulk silicate Earth and depleted in volatile and moderately volatile elements. Initially, the condensed liquid is composed of silicates. As the structure cools, metal exsolves in the accreting Moon and moonlets. We calculate ~2wt% metal is exsolved from a bulk silicate Earth composition, which is consistent with estimates of the mass of the lunar core. Thus, similar tungsten isotopes are established in the Earth and Moon as metal is exsolved in both bodies after mixing. In our model, the criterion for lunar origin shifts, away from specific impact parameters that inject terrestrial material into orbit, to any collision that transforms the Earth into a rapidly rotating and substantially vaporized MAD planet. Impacts that can transform the Earth are common during the end stages of planet formation. Therefore, the characteristics of our Moon are a natural consequence of forming the Earth.

  20. Refrigerant pressurization system with a two-phase condensing ejector

    DOEpatents

    Bergander, Mark

    2009-07-14

    A refrigerant pressurization system including an ejector having a first conduit for flowing a liquid refrigerant therethrough and a nozzle for accelerating a vapor refrigerant therethrough. The first conduit is positioned such that the liquid refrigerant is discharged from the first conduit into the nozzle. The ejector includes a mixing chamber for condensing the vapor refrigerant. The mixing chamber comprises at least a portion of the nozzle and transitions into a second conduit having a substantially constant cross sectional area. The condensation of the vapor refrigerant in the mixing chamber causes the refrigerant mixture in at least a portion of the mixing chamber to be at a pressure greater than that of the refrigerant entering the nozzle and greater than that entering the first conduit.

  1. Intermediate reboiler and condenser arrangement for binary distillation columns

    SciTech Connect

    Agrawal, R.; Herron, D.M.

    1998-06-01

    The most thermodynamically efficient configuration for adding or removing heat from an intermediate location of an ideal binary distillation column distilling pure products is derived. The optimal policy requires that preconditioning of the feed be part of the overall decision-making process. The optimal configuration can be determined through the use of two parameters, {alpha}{sub IR} and {alpha}{sub IC}, that are solely functions of feed composition. Simple and readily usable heuristics using these parameters are developed that help instantly identify the most efficient selection among (1) totally vaporizing and returning a side-draw liquid stream from an intermediate location of the distillation column, (2) partially or totally vaporizing a portion of the given saturated liquid feed, (3) partially or totally condensing a portion of the given saturated vapor feed, and (4) totally condensing and returning a side-draw vapor stream from an intermediate location of the distillation column.

  2. Utilization of Porous Media for Condensing Heat Exchangers

    NASA Technical Reports Server (NTRS)

    Tuan, George C.

    2006-01-01

    The use of porous media as a mean of separating liquid condensate from the air stream in condensing heat exchangers has been explored in the past inside small plant growth chambers and in the Apollo Command Module. Both applications used a cooled porous media made of sintered stainless steel to cool and separate condensation from the air stream. However, the main issues with the utilization of porous media in the past have been the deterioration of the porous media over long duration, such as clogging and changes in surface wetting characteristics. In addition, for long duration usage, biofilm growth from microorganisms on the porous medial would also be an issue. In developing Porous Media Condensing Heat Exchangers (PMCHX) for future space applications, different porous materials and microbial growth control methods will need to be explored. This paper explores the work performed at JSC and GRC to evaluate different porous materials and microbial control methods to support the development of a Porous Media Condensing Heat Exchanger. It outlines the basic principles for designing a PMCHX and issues that were encountered and ways to resolve those issues. The PMCHX has potential of mass, volume, and power savings over current CHX and water separator technology and would be beneficial for long duration space missions.

  3. The order of condensation in capillary grooves.

    PubMed

    Rascón, Carlos; Parry, Andrew O; Nürnberg, Robert; Pozzato, Alessandro; Tormen, Massimo; Bruschi, Lorenzo; Mistura, Giampaolo

    2013-05-15

    We consider capillary condensation in a deep groove of width L. The transition occurs at a pressure p(co)(L) described, for large widths, by the Kelvin equation p(sat) - p(co)(L) = 2σ cosθ/L, where θ is the contact angle at the side walls and σ is the surface tension. The order of the transition is determined by the contact angle of the capped end θcap; it is continuous if the liquid completely wets the cap, and first-order otherwise. When the transition is first-order, corner menisci at the bottom of the capillary lead to a pronounced metastability, determined by a complementary Kelvin equation Δp(L) = 2σ sinθcap/L. On approaching the wetting temperature of the capillary cap, the corner menisci merge and a single meniscus unbinds from the bottom of the groove. Finite-size scaling shifts, crossover behaviour and critical singularities are determined at mean-field level and beyond. Numerical and experimental results showing the continuous nature of condensation for θcap = 0 and the influence of corner menisci on adsorption isotherms are presented. PMID:23611878

  4. Vapor Condensed and Supercooled Glassy Nanoclusters.

    PubMed

    Qi, Weikai; Bowles, Richard K

    2016-03-22

    We use molecular simulation to study the structural and dynamic properties of glassy nanoclusters formed both through the direct condensation of the vapor below the glass transition temperature, without the presence of a substrate, and via the slow supercooling of unsupported liquid nanodroplets. An analysis of local structure using Voronoi polyhedra shows that the energetic stability of the clusters is characterized by a large, increasing fraction of bicapped square antiprism motifs. We also show that nanoclusters with similar inherent structure energies are structurally similar, independent of their history, which suggests the supercooled clusters access the same low energy regions of the potential energy landscape as the vapor condensed clusters despite their different methods of formation. By measuring the intermediate scattering function at different radii from the cluster center, we find that the relaxation dynamics of the clusters are inhomogeneous, with the core becoming glassy above the glass transition temperature while the surface remains mobile at low temperatures. This helps the clusters sample the highly stable, low energy structures on the potential energy surface. Our work suggests the nanocluster systems are structurally more stable than the ultrastable glassy thin films, formed through vapor deposition onto a cold substrate, but the nanoclusters do not exhibit the superheating effects characteristic of the ultrastable glass states. PMID:26866858

  5. Open problems in condensed matter physics, 1987

    SciTech Connect

    Falicov, L.M.

    1988-08-01

    The 1970's and 1980's can be considered the third stage in the explosive development of condensed matter physics. After the very intensive research of the 1930's and 1940's, which followed the formulation of quantum mechanics, and the path-breaking activity of the 1950's and 1960's, the problems being faced now are much more complex and not always susceptible to simple modelling. The (subjectively) open problems discussed here are: high temperature superconductivity, its properties and the possible new mechanisms which lead to it; the integral and fractional quantum Hall effects; new forms of order in condensed-matter systems; the physics of disorder, especially the problem of spin glasses; the physics of complex anisotropic systems; the theoretical prediction of stable and metastable states of matter; the physics of highly correlated states (heavy fermions); the physics of artificially made structures, in particular heterostructures and highly metastable states of matter; the determination of the microscopic structure of surfaces; and chaos and highly nonlinear phnomena. 82 refs.

  6. Charged condensate and helium dwarf stars

    SciTech Connect

    Gabadadze, Gregory; Rosen, Rachel A E-mail: rar339@nyu.edu

    2008-10-15

    White dwarf stars composed of carbon, oxygen and heavier elements are expected to crystallize as they cool down below certain temperatures. Yet, simple arguments suggest that the helium white dwarf cores may not solidify, mostly because of zero-point oscillations of the helium ions that would dissolve the crystalline structure. We argue that the interior of the helium dwarfs may instead form a macroscopic quantum state in which the charged helium-4 nuclei are in a Bose-Einstein condensate, while the relativistic electrons form a neutralizing degenerate Fermi liquid. We discuss the electric charge screening, and the spectrum of this substance, showing that the bosonic long-wavelength fluctuations exhibit a mass gap. Hence, there is a suppression at low temperatures of the boson contribution to the specific heat-the latter being dominated by the specific heat of the electrons near the Fermi surface. This state of matter may have observational signatures.

  7. Statistical Mechanics and Applications in Condensed Matter

    NASA Astrophysics Data System (ADS)

    Di Castro, Carlo; Raimondi, Roberto

    2015-08-01

    Preface; 1. Thermodynamics: a brief overview; 2. Kinetics; 3. From Boltzmann to Gibbs; 4. More ensembles; 5. The thermodynamic limit and its thermodynamic stability; 6. Density matrix and quantum statistical mechanics; 7. The quantum gases; 8. Mean-field theories and critical phenomena; 9. Second quantization and Hartree-Fock approximation; 10. Linear response and fluctuation-dissipation theorem in quantum systems: equilibrium and small deviations; 11. Brownian motion and transport in disordered systems; 12. Fermi liquids; 13. The Landau theory of the second order phase transitions; 14. The Landau-Wilson model for critical phenomena; 15. Superfluidity and superconductivity; 16. The scaling theory; 17. The renormalization group approach; 18. Thermal Green functions; 19. The microscopic foundations of Fermi liquids; 20. The Luttinger liquid; 21. Quantum interference effects in disordered electron systems; Appendix A. The central limit theorem; Appendix B. Some useful properties of the Euler Gamma function; Appendix C. Proof of the second theorem of Yang and Lee; Appendix D. The most probable distribution for the quantum gases; Appendix E. Fermi-Dirac and Bose-Einstein integrals; Appendix F. The Fermi gas in a uniform magnetic field: Landau diamagnetism; Appendix G. Ising and gas-lattice models; Appendix H. Sum over discrete Matsubara frequencies; Appendix I. Hydrodynamics of the two-fluid model of superfluidity; Appendix J. The Cooper problem in the theory of superconductivity; Appendix K. Superconductive fluctuations phenomena; Appendix L. Diagrammatic aspects of the exact solution of the Tomonaga Luttinger model; Appendix M. Details on the theory of the disordered Fermi liquid; References; Author index; Index.

  8. Frustration in Condensed Matter and Protein Folding

    NASA Astrophysics Data System (ADS)

    Li, Z.; Tanner, S.; Conroy, B.; Owens, F.; Tran, M. M.; Boekema, C.

    2014-03-01

    By means of computer modeling, we are studying frustration in condensed matter and protein folding, including the influence of temperature and Thomson-figure formation. Frustration is due to competing interactions in a disordered state. The key issue is how the particles interact to reach the lowest frustration. The relaxation for frustration is mostly a power function (randomly assigned pattern) or an exponential function (regular patterns like Thomson figures). For the atomic Thomson model, frustration is predicted to decrease with the formation of Thomson figures at zero kelvin. We attempt to apply our frustration modeling to protein folding and dynamics. We investigate the homogeneous protein frustration that would cause the speed of the protein folding to increase. Increase of protein frustration (where frustration and hydrophobicity interplay with protein folding) may lead to a protein mutation. Research is supported by WiSE@SJSU and AFC San Jose.

  9. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  10. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 3 2014-01-01 2014-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  11. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 3 2011-01-01 2011-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  12. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 3 2012-01-01 2012-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  13. 7 CFR 58.925 - Sweetened condensed.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 3 2013-01-01 2013-01-01 false Sweetened condensed. 58.925 Section 58.925 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... Procedures § 58.925 Sweetened condensed. After condensing, the sweetened condensed product should be...

  14. Continuous Droplet Removal upon Dropwise Condensation of Humid Air on a Hydrophobic Micropatterned Surface

    PubMed Central

    2015-01-01

    Combination of two physical phenomena, capillary pressure gradient and wettability gradient, allows a simple two-step fabrication process that yields a reliable hydrophobic self-cleaning condenser surface. The surface is fabricated with specific microscopic topography and further treatment with a chemically inert low-surface-energy material. This process does not require growth of nanofeatures (nanotubes) or hydrophilic–hydrophobic patterning of the surface. Trapezoidal geometry of the microfeatures facilitates droplet transfer from the Wenzel to the Cassie state and reduces droplet critical diameter. The geometry of the micropatterns enhances local coalescence and directional movement for droplets with diameter much smaller than the radial length of the micropatterns. The hydrophobic self-cleaning micropatterned condenser surface prevents liquid film formation and promotes continuous dropwise condensation cycle. Upon dropwise condensation, droplets follow a designed wettability gradient created with micropatterns from the most hydrophobic to the least hydrophobic end of the surface. The surface has higher condensation efficiency, due to its directional self-cleaning property, than a plain hydrophobic surface. We explain the self-actuated droplet collection mechanism on the condenser surface and demonstrate experimentally the creation of an effective wettability gradient over a 6 mm radial distance. In spite of its fabrication simplicity, the fabricated surface demonstrates self-cleaning property, enhanced condensation performance, and reliability over time. Our work enables creation of a hydrophobic condenser surface with the directional self-cleaning property that can be used for collection of biological (chemical, environmental) aerosol samples or for condensation enhancement. PMID:25073014

  15. Condensed Tannins from Ficus virens as Tyrosinase Inhibitors: Structure, Inhibitory Activity and Molecular Mechanism

    PubMed Central

    Chai, Wei-Ming; Feng, Hui-Ling; Zhuang, Jiang-Xing; Chen, Qing-Xi

    2014-01-01

    Condensed tannins from Ficus virens leaves, fruit, and stem bark were isolated and their structures characterized by 13C nuclear magnetic resonance spectrometry, high performance liquid chromatography electrospray ionization mass spectrometry, and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. The results showed that the leaves, fruit, and stem bark condensed tannins were complex mixtures of homo- and heteropolymers of B-type procyanidins and prodelphinidins with degrees of polymerization up to hexamer, dodecamer, and pentadecamer, respectively. Antityrosinase activities of the condensed tannins were studied. The results indicated that the condensed tannins were potent tyrosinase inhibitors. The concentrations for the leaves, fruit, and stem bark condensed tannins leading to 50% enzyme activity were determined to be 131.67, 99.89, and 106.22 μg/ml on monophenolase activity, and 128.42, 43.07, and 74.27 μg/ml on diphenolase activity. The inhibition mechanism, type, and constants of the condensed tannins on the diphenolase activity were further investigated. The results indicated that the condensed tannins were reversible and mixed type inhibitors. Fluorescence quenching, copper interacting, and molecular docking techniques were utilized to unravel the molecular mechanisms of the inhibition. The results showed that the hydroxyl group on the B ring of the condensed tannins could chelate the dicopper irons of the enzyme. Moreover, the condensed tannins could reduce the enzyme product o-quinones into colourless compounds. These results would contribute to the development and design of antityrosinase agents. PMID:24637701

  16. Continuous droplet removal upon dropwise condensation of humid air on a hydrophobic micropatterned surface.

    PubMed

    Zamuruyev, Konstantin O; Bardaweel, Hamzeh K; Carron, Christopher J; Kenyon, Nicholas J; Brand, Oliver; Delplanque, Jean-Pierre; Davis, Cristina E

    2014-08-26

    Combination of two physical phenomena, capillary pressure gradient and wettability gradient, allows a simple two-step fabrication process that yields a reliable hydrophobic self-cleaning condenser surface. The surface is fabricated with specific microscopic topography and further treatment with a chemically inert low-surface-energy material. This process does not require growth of nanofeatures (nanotubes) or hydrophilic-hydrophobic patterning of the surface. Trapezoidal geometry of the microfeatures facilitates droplet transfer from the Wenzel to the Cassie state and reduces droplet critical diameter. The geometry of the micropatterns enhances local coalescence and directional movement for droplets with diameter much smaller than the radial length of the micropatterns. The hydrophobic self-cleaning micropatterned condenser surface prevents liquid film formation and promotes continuous dropwise condensation cycle. Upon dropwise condensation, droplets follow a designed wettability gradient created with micropatterns from the most hydrophobic to the least hydrophobic end of the surface. The surface has higher condensation efficiency, due to its directional self-cleaning property, than a plain hydrophobic surface. We explain the self-actuated droplet collection mechanism on the condenser surface and demonstrate experimentally the creation of an effective wettability gradient over a 6 mm radial distance. In spite of its fabrication simplicity, the fabricated surface demonstrates self-cleaning property, enhanced condensation performance, and reliability over time. Our work enables creation of a hydrophobic condenser surface with the directional self-cleaning property that can be used for collection of biological (chemical, environmental) aerosol samples or for condensation enhancement. PMID:25073014

  17. Generalized Bose-Einstein Condensation

    NASA Astrophysics Data System (ADS)

    Mullin, William J.; Sakhel, Asaad R.

    2012-02-01

    Generalized Bose-Einstein condensation (GBEC) involves condensates appearing simultaneously in multiple states. We review examples of the three types in an ideal Bose gas with different geometries. In Type I there is a discrete number of quantum states each having macroscopic occupation; Type II has condensation into a continuous band of states, with each state having macroscopic occupation; in Type III each state is microscopically occupied while the entire condensate band is macroscopically occupied. We begin by discussing Type I or "normal" BEC into a single state for an isotropic harmonic oscillator potential. Other geometries and external potentials are then considered: the "channel" potential (harmonic in one dimension and hard-wall in the other), which displays Type II, the "cigar trap" (anisotropic harmonic potential), and the "Casimir prism" (an elongated box), the latter two having Type III condensations. General box geometries are considered in an appendix. We particularly focus on the cigar trap, which Van Druten and Ketterle first showed had a two-step condensation: a GBEC into a band of states at a temperature T c and another "one-dimensional" transition at a lower temperature T 1 into the ground state. In a thermodynamic limit in which the ratio of the dimensions of the anisotropic harmonic trap is kept fixed, T 1 merges with the upper transition, which then becomes a normal BEC. However, in the thermodynamic limit of Beau and Zagrebnov, in which the ratio of the boundary lengths increases exponentially, T 1 becomes fixed at the temperature of a true Type I phase transition. The effects of interactions on GBEC are discussed and we show that there is evidence that Type III condensation may have been observed in the cigar trap.

  18. Aerodynamically-driven condensate layer thickness distributions on isothermal cylindrical surfaces

    NASA Technical Reports Server (NTRS)

    Rosner, D. E.; Gunes, D.; Nazih-Anous, N.

    1983-01-01

    A simple yet rather general mathematical model is presented for predicting the distribution of condensate layer thickness when aerodynamic shear is the dominant mechanism of liquid flow along the surface. The Newtonian condensate film is treated using well-known thin-layer (lubrication theory) approximations, and condensate supply is taken to be the result of either convective diffusion or inertial impaction. Illustrative calculations for a circular cylinder in a crossflow at Re = 100,000 reveal the consequences of alternate condensate arrival mechanisms and the existence of thicker reverse-flow films behind the position of gas boundary-layer separation. The present formulation is readily generalized to include transient liquid layer flows on noncircular objects of variable surface temperature, as encountered in turbine-blade materials testing or operation.

  19. Wettability modified nanoporous ceramic membrane for simultaneous residual heat and condensate recovery.

    PubMed

    Hu, H W; Tang, G H; Niu, D

    2016-01-01

    Recovery of both latent heat and condensate from boiler flue gas is significant for improving boiler efficiency and water conservation. The condensation experiments are carried out to investigate the simultaneous heat and mass transfer across the nanoporous ceramic membranes (NPCMs) which are treated to be hydrophilic and hydrophobic surfaces using the semicontinuous supercritical reactions. The effects of typical parameters including coolant flow rate, vapor/nitrogen gas mixture temperature, water vapor volume fraction and transmembrane pressure on heat and mass transfer performance are studied. The experimental results show that the hydrophilic NPCM exhibits higher performances of condensation heat transfer and condensate recovery. However, the hydrophobic modification results in remarkable degradation of heat and condensate recovery from the mixture. Molecular dynamics simulations are conducted to establish a hydrophilic/hydrophobic nanopore/water liquid system, and the infiltration characteristics of the single hydrophilic/hydrophobic nanopore is revealed. PMID:27270997

  20. N-soliton statistics and condensate formation in dense quantum gases

    NASA Astrophysics Data System (ADS)

    Mirza, Babur M.

    2014-09-01

    Statistics of N quantum density soliton waves [B. M. Mirza, Mod. Phys. Lett. B28 (2014) 1450148] is extended here to the case of systems with symmetric wave function. Since many such systems exhibit condensation phenomena, application is made of the soliton wave statistics to investigate condensation and phase transition in quantum gases such as 4He and also dense systems such as the alkali atoms. Specific heat discontinuities are used to determine the condensation temperature for dense quantum gases and liquids. For the model case of helium the statistical theory is shown to predict not only the observed superfluid condensation temperature (2.17 ± 0.01 K) correctly but also the normal condensation temperature (4.21 ± 0.02 K), as well as the exact specific heat λ-profile.

  1. Wettability modified nanoporous ceramic membrane for simultaneous residual heat and condensate recovery

    PubMed Central

    Hu, H. W.; Tang, G. H.; Niu, D.

    2016-01-01

    Recovery of both latent heat and condensate from boiler flue gas is significant for improving boiler efficiency and water conservation. The condensation experiments are carried out to investigate the simultaneous heat and mass transfer across the nanoporous ceramic membranes (NPCMs) which are treated to be hydrophilic and hydrophobic surfaces using the semicontinuous supercritical reactions. The effects of typical parameters including coolant flow rate, vapor/nitrogen gas mixture temperature, water vapor volume fraction and transmembrane pressure on heat and mass transfer performance are studied. The experimental results show that the hydrophilic NPCM exhibits higher performances of condensation heat transfer and condensate recovery. However, the hydrophobic modification results in remarkable degradation of heat and condensate recovery from the mixture. Molecular dynamics simulations are conducted to establish a hydrophilic/hydrophobic nanopore/water liquid system, and the infiltration characteristics of the single hydrophilic/hydrophobic nanopore is revealed. PMID:27270997

  2. Wettability modified nanoporous ceramic membrane for simultaneous residual heat and condensate recovery

    NASA Astrophysics Data System (ADS)

    Hu, H. W.; Tang, G. H.; Niu, D.

    2016-06-01

    Recovery of both latent heat and condensate from boiler flue gas is significant for improving boiler efficiency and water conservation. The condensation experiments are carried out to investigate the simultaneous heat and mass transfer across the nanoporous ceramic membranes (NPCMs) which are treated to be hydrophilic and hydrophobic surfaces using the semicontinuous supercritical reactions. The effects of typical parameters including coolant flow rate, vapor/nitrogen gas mixture temperature, water vapor volume fraction and transmembrane pressure on heat and mass transfer performance are studied. The experimental results show that the hydrophilic NPCM exhibits higher performances of condensation heat transfer and condensate recovery. However, the hydrophobic modification results in remarkable degradation of heat and condensate recovery from the mixture. Molecular dynamics simulations are conducted to establish a hydrophilic/hydrophobic nanopore/water liquid system, and the infiltration characteristics of the single hydrophilic/hydrophobic nanopore is revealed.

  3. Experimental study of steam condensation on water in countercurrent flow in presence of inert gases

    NASA Astrophysics Data System (ADS)

    Bharathan, D.; Althof, J.

    1984-08-01

    Experimental results of investigating steam condensation on water in the presence of (noncondensable) inert gases at low temperatures and pressures relevant to open-cycle ocean thermal energy conversion (OTEC) systems are reported. Seven different condenser configurations were tested. The experimental data are correlated using a liquid flow fraction and a vent fraction to yield simple relationships of condenser performance over a wide range of test conditions. Performance maps and envelopes are provided for evaluating the relative merits of tested configurations. The height of transfer unit (HTU) for condensation ranges from 0.2 to 0.3 m among the various condenser geometries. Also reported are the pressure-loss coefficients for all the tested geometries.

  4. Condenser on-line leak-detection system development

    SciTech Connect

    Not Available

    1991-11-01

    Condenser tube leaks have been the number one source of impurities in most utility steam cycles. The impurities lead to corrosion of feedwater systems, boilers, and turbines. EPRI recommends sodium in the condensate be less than 3 ppb, which means less than one gallon leakage per day in some cases. The location of leaks requires isolation of the condenser water box and is costly because of power reduction. On-line detection using tracer can cut down the isolation time and, therefore, offers cost advantages to utilities. The on-line leak detection technique utilizes the concepts developed by EPRI for targeted chlorination''. Sulfur hexafluoride (SF{sub 6}), helium gases, and perfluorocarbon liquid were considered as tracers. Laboratory studies were conducted to evaluate the practicability of injecting water with dissolved SF{sub 6} gas, SF{sub 6} bubbles, and dissolved SF{sub 6} gas in perfluorocarbon liquid. Both static and dynamic tests were conducted in a condenser model. It was determined that water entrained with SF{sub 6} bubbles offered the most practical method of injection, followed by dissolved SF{sub 6} gas in perfluorocarbon. A conceptual design was developed that utilizes a water lance, a swivel arrangement in the waterbox manhole cover, a tracer targeting and mixing system, and a tracer gas detection system at the air ejector exhaust. A successful demonstration of targeted leak detection using a waterjet lance with SF{sub 6} was conducted at Carolina Power Light Company's Asheville Steam Electric Station Unit 1. A measurable artificially created leak was detected and located using this system with the condenser on-line. 2 refs., 39 figs., 6 tabs.

  5. Spacecraft Crew Cabin Condensation Control

    NASA Technical Reports Server (NTRS)

    Carrillo, Laurie Y.; Rickman, Steven L.; Ungar, Eugene K.

    2013-01-01

    A report discusses a new technique to prevent condensation on the cabin walls of manned spacecraft exposed to the cold environment of space, as such condensation could lead to free water in the cabin. This could facilitate the growth of mold and bacteria, and could lead to oxidation and weakening of the cabin wall. This condensation control technique employs a passive method that uses spacecraft waste heat as the primary wallheating mechanism. A network of heat pipes is bonded to the crew cabin pressure vessel, as well as the pipes to each other, in order to provide for efficient heat transfer to the cabin walls and from one heat pipe to another. When properly sized, the heat-pipe network can maintain the crew cabin walls at a nearly uniform temperature. It can also accept and distribute spacecraft waste heat to maintain the pressure vessel above dew point.

  6. Holes in the ghost condensate

    SciTech Connect

    Krotov, D.; Rebbi, C.; Rubakov, V.; Zakharov, V.

    2005-02-15

    In a recently proposed model of 'ghost condensation', spatially homogeneous states may mix, via tunneling, with inhomogeneous states which are somewhat similar to bubbles in the theory of false vacuum decay, the corresponding bubble nucleation rate being exponentially sensitive to the ultraviolet completion of the model. The conservation of energy and charge requires that the energy density is negative and the field is strongly unstable in a part of the nucleated bubble. Unlike in the theory of false vacuum decay, this region does not expand during subsequent real-time evolution. In the outer part, positive energy outgoing waves develop, which eventually form shocks. Behind the outgoing waves and away from the bubble center, the background settles down to its original value. The outcome of the entire process is thus a microscopic region of negative energy and strong field - 'hole in the ghost condensate' - plus a collection of outgoing waves (particles of the ghost condensate field) carrying away finite energy.

  7. Condensed Astatine: Monatomic and Metallic

    NASA Astrophysics Data System (ADS)

    Hermann, Andreas; Hoffmann, Roald; Ashcroft, N. W.

    2013-09-01

    The condensed matter properties of the nominal terminating element of the halogen group with atomic number 85, astatine, are as yet unknown. In the intervening more than 70 years since its discovery significant advances have been made in substrate cooling and the other techniques necessary for the production of the element to the point where we might now enquire about the key properties astatine might have if it attained a condensed phase. This subject is addressed here using density functional theory and structural selection methods, with an accounting for relativistic physics that is essential. Condensed astatine is predicted to be quite different in fascinating ways from iodine, being already at 1 atm a metal, and monatomic at that, and possibly a superconductor (as is dense iodine).

  8. Condensed astatine: monatomic and metallic.

    PubMed

    Hermann, Andreas; Hoffmann, Roald; Ashcroft, N W

    2013-09-13

    The condensed matter properties of the nominal terminating element of the halogen group with atomic number 85, astatine, are as yet unknown. In the intervening more than 70 years since its discovery significant advances have been made in substrate cooling and the other techniques necessary for the production of the element to the point where we might now enquire about the key properties astatine might have if it attained a condensed phase. This subject is addressed here using density functional theory and structural selection methods, with an accounting for relativistic physics that is essential. Condensed astatine is predicted to be quite different in fascinating ways from iodine, being already at 1 atm a metal, and monatomic at that, and possibly a superconductor (as is dense iodine). PMID:24074111

  9. The effect of surface wettability on water vapor condensation in nanoscale

    PubMed Central

    Niu, D.; Tang, G. H.

    2016-01-01

    The effect of surface wettability on condensation heat transfer in a nanochannel is studied with the molecular dynamics simulations. Different from the conventional size, the results show that the filmwise mode leads to more efficient heat transfer than the dropwise mode, which is attributed to a lower interfacial thermal resistance between the hydrophilic surface and the condensed water compared with the hydrophobic case. The observed temperature jump at the solid-liquid surface confirms that the hydrophilic properties of the solid surface can suppress the interfacial thermal resistance and improve the condensation heat transfer performance effectively. PMID:26754316

  10. Producing Liquid Oxygen in the Classroom

    ERIC Educational Resources Information Center

    Williams, David; Warden, Nicole; Wharton, Barry

    2016-01-01

    A number of organisations have provided instructions on how to produce small quantities of liquid oxygen in the classroom using liquid nitrogen and a copper condensation coil (Lister 1995 "Classic Chemistry Demonstrations" (London: Royal Society of Chemistry) pp 61-2, French and Hibbert 2010 "Phys. Educ." 45 221-2). The method…

  11. Role of Nanostructure Coating Quality in Delay of Surface Flooding during Jumping Droplet Condensation

    NASA Astrophysics Data System (ADS)

    Preston, Daniel J.; Antao, Dion; Miljkovic, Nenad; Barabadi, Banafsheh; Queeney, John; Wang, Evelyn

    Vapor condensation is commonly observed in everyday life and routinely used in industry as an effective means of transferring heat. In industrial systems, condensed vapor typically forms a thin liquid film which is not desired due to the large thermal resistance to heat transfer; however, if the condensing surface is functionalized with a hydrophobic coating, the condensate forms discrete liquid droplets which shed at sizes approaching the capillary length and refresh the surface for re-nucleation, resulting in a 5-7x heat transfer improvement. Furthermore, when a micro- or nanostructured surface is functionalized, a superhydrophobic surface can be created on which small (~10-100 µm) droplets coalesce and can spontaneously jump away from the surface due to release of excess surface energy; this jumping droplet mode of condensation has been shown to increase heat transfer by an additional 30 - 40%. However, at elevated supersaturations, nanostructured superhydrophobic surfaces can become flooded with condensate and form pinned droplets which cannot jump, thereby eliminating the desired heat transfer improvement. In this work, we experimentally demonstrated a delay in the supersaturation at which surface flooding occurs by reducing the hydrophobic coating defect density. This resulted in a lower proportion of structure unit cells occupied by condensate, which allowed higher droplet mobility and jumping at elevated supersaturation.

  12. Numerical investigation of nitrogen spontaneous condensation flow in cryogenic nozzles using varying nucleation theories

    NASA Astrophysics Data System (ADS)

    Sun, Wan; Niu, Lu; Chen, Shuangtao; Sun, Xiaodong; Hou, Yu

    2015-06-01

    The thermodynamic irreversible loss by condensation can have an important influence on the flow characteristics and thermal efficiency in air or nitrogen cryogenic turbo-expander involving spontaneous condensation flow. However, the design of wet type turbo-expander for cryogenic liquid plants has been constrained due to the complexity of nucleation theory and the difficulty of data measurement in cryogenic environments. This paper presents numerical simulations for prediction of nitrogen spontaneous condensation flow in cryogenic nozzles. The non-equilibrium simulations were performed using three nucleation theories with the help of ANSYS CFX solver. The standard Redlich-Kwong gas state equation and Eulerian-Eulerian governing equations were used in simulations. Comparison with the equilibrium condensation model the non-equilibrium condensation model achieves a better prediction of the flow characteristics for spontaneous condensation flow in cryogenic environments. The nucleation theory which is based on classical nucleation theory (CNT) and improved by Kantrowitz for non-isothermal effects shows a better prediction of pressure drop, location of condensation onset and supercooling compared with experimental data. The influence of varying nucleation theories on the calculation of nucleation rate, the supercooling distribution and the liquid mass fraction distribution were also analyzed.

  13. On the onset of surface condensation: formation and transition mechanisms of condensation mode

    NASA Astrophysics Data System (ADS)

    Sheng, Qiang; Sun, Jie; Wang, Qian; Wang, Wen; Wang, Hua Sheng

    2016-08-01

    Molecular dynamics simulations have been carried out to investigate the onset of surface condensation. On surfaces with different wettability, we snapshot different condensation modes (no-condensation, dropwise condensation and filmwise condensation) and quantitatively analyze their characteristics by temporal profiles of surface clusters. Two different types of formation of nanoscale droplets are identified, i.e. the formations with and without film-like condensate. We exhibit the effect of surface tensions on the formations of nanoscale droplets and film. We reveal the formation mechanisms of different condensation modes at nanoscale based on our simulation results and classical nucleation theory, which supplements the ‘classical hypotheses’ of the onset of dropwise condensation. We also reveal the transition mechanism between different condensation modes based on the competition between surface tensions and reveal that dropwise condensation represents the transition states from no-condensation to filmwise condensation.

  14. On the onset of surface condensation: formation and transition mechanisms of condensation mode

    PubMed Central

    Sheng, Qiang; Sun, Jie; Wang, Qian; Wang, Wen; Wang, Hua Sheng

    2016-01-01

    Molecular dynamics simulations have been carried out to investigate the onset of surface condensation. On surfaces with different wettability, we snapshot different condensation modes (no-condensation, dropwise condensation and filmwise condensation) and quantitatively analyze their characteristics by temporal profiles of surface clusters. Two different types of formation of nanoscale droplets are identified, i.e. the formations with and without film-like condensate. We exhibit the effect of surface tensions on the formations of nanoscale droplets and film. We reveal the formation mechanisms of different condensation modes at nanoscale based on our simulation results and classical nucleation theory, which supplements the ‘classical hypotheses’ of the onset of dropwise condensation. We also reveal the transition mechanism between different condensation modes based on the competition between surface tensions and reveal that dropwise condensation represents the transition states from no-condensation to filmwise condensation. PMID:27481071

  15. On the onset of surface condensation: formation and transition mechanisms of condensation mode.

    PubMed

    Sheng, Qiang; Sun, Jie; Wang, Qian; Wang, Wen; Wang, Hua Sheng

    2016-01-01

    Molecular dynamics simulations have been carried out to investigate the onset of surface condensation. On surfaces with different wettability, we snapshot different condensation modes (no-condensation, dropwise condensation and filmwise condensation) and quantitatively analyze their characteristics by temporal profiles of surface clusters. Two different types of formation of nanoscale droplets are identified, i.e. the formations with and without film-like condensate. We exhibit the effect of surface tensions on the formations of nanoscale droplets and film. We reveal the formation mechanisms of different condensation modes at nanoscale based on our simulation results and classical nucleation theory, which supplements the 'classical hypotheses' of the onset of dropwise condensation. We also reveal the transition mechanism between different condensation modes based on the competition between surface tensions and reveal that dropwise condensation represents the transition states from no-condensation to filmwise condensation. PMID:27481071

  16. Elementary Excitations in Quantum Liquids.

    ERIC Educational Resources Information Center

    Pines, David

    1981-01-01

    Discusses elementary excitations and their role in condensed matter physics, focusing on quantum plasma, helium liquids, and superconductors. Considers research primarily conducted in the 1950s and concludes with a brief survey of some closely related further developments. (Author/JN)

  17. Condensation in Titan's lower atmosphere

    NASA Astrophysics Data System (ADS)

    Lavvas, P.; Griffith, C. A.; Yelle, R. V.

    2011-10-01

    We present a self-consistent description of Titan's aerosols-clouds-gases system and compare our results with the optical properties retrieved from measurements made by the Descent Imager / Spectral Radiometer (DISR) experiment on the Huygens probe [4]. Our calculations include the condensation of methane, ethane and hydrogen cyanide on photochemical aerosols produced in the thermosphere. Our results suggest that the two distinct extinction layers observed by DISR below 80 km are produced by HCN and methane condensation, respectively, while for the Huygens' equatorial conditions simulated here, the contribution of ethane clouds to the total opacity is negligible

  18. Gravity Effects in Condensing and Evaporating Films

    NASA Technical Reports Server (NTRS)

    Hermanson, J. C.; Som, S. M.; Allen, J. S.; Pedersen, P. C.

    2004-01-01

    A general overview of gravity effects in condensing and evaporating films is presented. The topics include: 1) Research Overview; 2) NASA Recognizes Critical Need for Condensation & Evaporation Research to Enable Human Exploration of Space; 3) Condensation and Evaporation Research in Reduced Gravity is Enabling for AHST Technology Needs; 4) Differing Role of Surface Tension on Condensing/Evaporating Film Stability; 5) Fluid Mechanisms in Condensing and Evaporating Films in Reduced Gravity; 6) Research Plan; 7) Experimental Configurations for Condensing Films; 8) Laboratory Condensation Test Cell; 9) Aircraft Experiment; 10) Condensation Study Current Test Conditions; 11) Diagnostics; 12) Shadowgraph Images of Condensing n- pentane Film in Unstable (-1g) Configuration; 13) Condensing n-Pentane Film in Normal Gravity (-1g) at Constant Pressure; 14) Condensing n-Pentane Film in Normal Gravity (-1g) with Cyclic Pressure; 15) Non-condensing Pumped Film in Normal Gravity (-1g); 16) Heat Transfer Coefficient in Developing, Unstable Condensing Film in Normal Gravity; 17) Heat Transfer for Unsteady Condensing Film (-1g); 18) Ultrasound Measurement of Film Thickness N-pentane Film, Stable (+1g) Configuration; and 19) Ultrasound Measurement of Film Thickness N-pentane Film, Unstable (-1g) Configuration.

  19. Gas-Liquid Processing in Microchannels

    SciTech Connect

    TeGrotenhuis, Ward E.; Stenkamp, Victoria S.; Twitchell, Alvin

    2005-09-01

    Processing gases and liquids together in microchannels having at least one dimension <1 mm has unique advantages for rapid heat and mass transfer. One approach for managing the two phases is to use porous structures as wicks within microchannels to segregate the liquid phase from the gas phase. Gas-liquid processing is accomplished by providing a gas flow path and inducing flow of the liquid phase through or along the wick under an induced pressure gradient. A variety of unit operations are enabled, including phase separation, partial condensation, absorption, desorption, and distillation. Results are reported of an investigation of microchannel phase separation in a transparent, single-channel device. Next, heat exchange is integrated with the microchannel wick approach to create a partial condenser that also separates the condensate. Finally, the scale-up to a multi-channel phase separator is described.

  20. Experimental study on the condensation of a thermosyphon by electrical capacitance tomography

    NASA Astrophysics Data System (ADS)

    Han, Zhenxing; Mu, Huaiping; Lei, Jing; Zhang, Jingyin; Li, Zhihong; Liu, Shi

    2016-04-01

    The study on the condensation and the two-phase flow pattern in the condensation section is important to understand the operating mechanisms in a thermosyphon. In this paper, a new electric capacitance tomography (ECT) sensor was designed for the visualization measurement in a liquid by removing the shielding case and sealing with insulating hydrophobic material. It was successfully used to measure the condensation process in a thermosyphon under different operating temperatures. The thermosyphon was made of silica glass, and alcohol was used as a working fluid. The alcohol vapor was cooled to condense through the heat convection with the cooling water. The operating temperature was controlled by a heater with different power outputs. The experimental results show that the alcohol vapor condensed in stripes and unevenly on the wall surface at a low operating temperature. The liquid bridge will be formed periodically at the operating temperature of 90°C, and the time interval between two liquid bridges will be shorter with the increase of the operating temperature. At 117°C or even higher operating temperatures, the complete liquid bridge cannot be formed sometimes due to the difference of the growth rate of the surface wave around the circumference.

  1. Conceptual Design of a Condensing Heat Exchanger for Space Systems Using Porous Media

    NASA Technical Reports Server (NTRS)

    Hasan, Mohammad M.; Khan, Lutful I.; Nayagam, Vedha; Balasubramaniam, Ramaswamy

    2006-01-01

    Condensing heat exchangers are used in many space applications in the thermal and humidity control systems. In the International Space Station (ISS), humidity control is achieved by using a water cooled fin surface over which the moist air condenses, followed by "slurper bars" that take in both the condensate and air into a rotary separator and separates the water from air. The use of a cooled porous substrate as the condensing surface provides and attractive alternative that combines both heat removal as well as liquid/gas separation into a single unit. By selecting the pore sizes of the porous substrate a gravity independent operation may also be possible with this concept. Condensation of vapor into and on the porous surface from the flowing air and the removal of condensate from the porous substrate are the critical processes involved in the proposed concept. This paper describes some preliminary results of the proposed condensate withdrawal process and discusses the on-going design and development work of a porous media based condensing heat exchanger at the NASA Glenn Research Center in collaboration with NASA Johnson Space Center.

  2. Approaching Bose-Einstein Condensation

    ERIC Educational Resources Information Center

    Ferrari, Loris

    2011-01-01

    Bose-Einstein condensation (BEC) is discussed at the level of an advanced course of statistical thermodynamics, clarifying some formal and physical aspects that are usually not covered by the standard pedagogical literature. The non-conventional approach adopted starts by showing that the continuum limit, in certain cases, cancels out the crucial…

  3. Theoretical response of condenser microphones

    NASA Technical Reports Server (NTRS)

    Zuckerwar, A. J.

    1978-01-01

    Modifications to prior theory yield expressions for the frequency response and equivalent lumped elements of a condenser microphone in terms of its fundamental geometrical and material properties. Results of the analysis show excellent agreement with experimental data taken on B&K pressure microphone types 4134 and 4146.

  4. Condensing Algebra for Technical Mathematics.

    ERIC Educational Resources Information Center

    Greenfield, Donald R.

    Twenty Algebra-Packets (A-PAKS) were developed by the investigator for technical education students at the community college level. Each packet contained a statement of rationale, learning objectives, performance activities, performance test, and performance test answer key. The A-PAKS condensed the usual sixteen weeks of algebra into a six-week…

  5. Counterion condensation and ionic conductivity

    NASA Astrophysics Data System (ADS)

    Penafiel, L. Miguel; Litovitz, Theodore A.

    1992-02-01

    The occurrence of counterion condensation is demonstrated through measurements of the incremental ionic conductivity of pH buffered Na polyacrylate solutions. pH values were selected to allow variation of the charge density parameter ξ in the range between 0.4 and 2.8, that is, across ξ=1, the theoretical critical level for counterion condensation. The results show two regions where the incremental conductivity, ΔσP, varies differently with ξ. For ξ<1.3, ΔσP remains relatively constant. A sharp drop in ΔσP is observed between ξ=1.3 and ξ=1.7 corresponding to the onset of counterion condensation. It is suggested that this discontinuity reflects a drastic change in the polyion mobility caused by a structural rearrangement of the macromolecule. For ξ≳1.7, ΔσP decreases with approximately constant slope. This latter behavior agrees qualitatively but not quantitatively with the prediction of the counterion condensation model.

  6. Experimental studies of the vapor phase nucleation of refractory compounds. VI. The condensation of sodium.

    PubMed

    Martínez, Daniel M; Ferguson, Frank T; Heist, Richard H; Nuth, Joseph A

    2005-08-01

    In this paper we discuss the condensation of sodium vapor and the formation of a sodium aerosol as it occurs in a gas evaporation condensation chamber. A one-dimensional model describing the vapor transport to the vapor/aerosol interface was employed to determine the onset supersaturation, in which we assume the observed location of the interface is coincident with a nucleation rate maximum. We then present and discuss the resulting nucleation onset supersaturation data within the context of nucleation theory based on the liquid droplet model. Nucleation results appear to be consistent with a cesium vapor-to-liquid nucleation study performed in a thermal diffusion cloud chamber. PMID:16108655

  7. Drying of pulverized material with heated condensible vapor

    DOEpatents

    Carlson, Larry W.

    1986-01-01

    Apparatus for drying pulverized material utilizes a high enthalpy condensable vapor such as steam for removing moisture from the individual particles of the pulverized material. The initially wet particulate material is tangentially delivered by a carrier vapor flow to an upper portion of a generally vertical cylindrical separation drum. The lateral wall of the separation drum is provided with a plurality of flow guides for directing the vapor tangentially therein in the direction of particulate material flow. Positioned concentrically within the separation drum and along the longitudinal axis thereof is a water-cooled condensation cylinder which is provided with a plurality of collection plates, or fins, on the outer lateral surface thereof. The cooled collection fins are aligned counter to the flow of the pulverized material and high enthalpy vapor mixture to maximize water vapor condensation thereon. The condensed liquid which includes moisture removed from the pulverized material then flows downward along the outer surface of the coolant cylinder and is collected and removed. The particles travel in a shallow helix due to respective centrifugal and vertical acceleration forces applied thereto. The individual particles of the pulverized material are directed outwardly by the vortex flow where they contact the inner cylindrical surface of the separation drum and are then deposited at the bottom thereof for easy collection and removal. The pulverized material drying apparatus is particularly adapted for drying coal fines and facilitates the recovery of the pulverized coal.

  8. Functional Implications of Plasma Membrane Condensation for T Cell Activation

    PubMed Central

    Quinn, Carmel M.; Engelhardt, Karin; Williamson, David; Grewal, Thomas; Jessup, Wendy; Harder, Thomas; Gaus, Katharina

    2008-01-01

    The T lymphocyte plasma membrane condenses at the site of activation but the functional significance of this receptor-mediated membrane reorganization is not yet known. Here we demonstrate that membrane condensation at the T cell activation sites can be inhibited by incorporation of the oxysterol 7-ketocholesterol (7KC), which is known to prevent the formation of raft-like liquid-ordered domains in model membranes. We enriched T cells with 7KC, or cholesterol as control, to assess the importance of membrane condensation for T cell activation. Upon 7KC treatment, T cell antigen receptor (TCR) triggered calcium fluxes and early tyrosine phosphorylation events appear unaltered. However, signaling complexes form less efficiently on the cell surface, fewer phosphorylated signaling proteins are retained in the plasma membrane and actin restructuring at activation sites is impaired in 7KC-enriched cells resulting in compromised downstream activation responses. Our data emphasizes lipids as an important medium for the organization at T cell activation sites and strongly indicates that membrane condensation is an important element of the T cell activation process. PMID:18509459

  9. Drying of pulverized material with heated condensible vapor

    DOEpatents

    Carlson, L.W.

    1984-08-16

    Apparatus for drying pulverized material utilizes a high enthalpy condensable vapor such as steam for removing moisture from the individual particles of the pulverized material. The initially wet particulate material is tangentially delivered by a carrier vapor flow to an upper portion of a generally vertical cylindrical separation drum. The lateral wall of the separation drum is provided with a plurality of flow guides for directing the vapor tangentially therein in the direction of particulate material flow. Positioned concentrically within the separation drum and along the longitudinal axis thereof is a water-cooled condensation cylinder which is provided with a plurality of collection plates, or fines, on the outer lateral surface thereof. The cooled collection fines are aligned counter to the flow of the pulverized material and high enthalpy vapor mixture to maximize water vapor condensation thereon. The condensed liquid which includes moisture removed from the pulverized materials then flows downward along the outer surface of the coolant cylinder and is collected and removed. The particles travel in a shallow helix due to respective centrifugal and vertical acceleration forces applied thereto. The individual particles of the pulverized material are directed outwardly by the vortex flow where they contact the inner cylindrical surface of the separation drum and are then deposited at the bottom thereof for easy collection and removal. The pulverized material drying apparatus is particularly adapted for drying coal fines and facilitates the recovery of the pulverized coal. 2 figs.

  10. Electrical conductivity of condensed molecular hydrogen in the giant planets

    NASA Technical Reports Server (NTRS)

    Smoluchowski, R.

    1972-01-01

    Theoretical interpretation of several phenomena concerning Jupiter and Saturn depends upon the electrical conductivity of molecular hydrogen which, according to present models, forms the outermost layer of both planets. The layer starts at the transition pressure between the metallic and the molecular form of hydrogen, that is around 1 Mbar, and extends to the outside limits of the atmosphere. Whether at the highest pressures (and temperatures) this layer is a solid or a dense fluid is not certain. In any case, the fluid is in supercritical condition so that there is only a gradual transition from dense liquid to a gaseous form. The two theories which require specific values of the conductivity of the condensed molecular hydrogen are those pertaining to the generation of a magnetic field in the liquid hydrogen rather than in the deep metallic interior (HIDE, 1967), and those concerned with the electromagnetic coupling and exchange of angular momentum between the liquid core and the solid molecular hydrogen mantle.

  11. Internally drained condenser for spacecraft thermal management

    NASA Technical Reports Server (NTRS)

    Valenzuela, Javier A.; Drew, Brian C.

    1989-01-01

    This paper presents the results obtained to date in a program to develop a high heat flux condenser for use in two-phase spacecraft thermal management loops. The objective is to obtain a several fold increase in condensation heat transfer coefficient over those which can be achieved with shear-controlled or capillary-wick condensers. The internally drained condenser relies on shaped fins to develop a capillary pressure gradient over the surface of the fins and drive the condensate toward narrow drainage grooves separating the fins. The condensate then flows through a drainage network embedded in the condenser walls. Heat transfer coefficients of up to 8 W/sq cm C were measured in steam, providing a heat transfer enhancement ratio greater than a factor of 8. In the paper the proof-of-concept experiments are described and simplified models to predict the performance of the internally drained condenser are presented.

  12. Polariton Condensation in Dynamic Acoustic Lattices

    NASA Astrophysics Data System (ADS)

    Cerda-Méndez, E. A.; Krizhanovskii, D. N.; Wouters, M.; Bradley, R.; Biermann, K.; Guda, K.; Hey, R.; Santos, P. V.; Sarkar, D.; Skolnick, M. S.

    2010-09-01

    We demonstrate that the tunable potential introduced by a surface acoustic wave on a homogeneous polariton condensate leads to fragmentation of the condensate into an array of wires which move with the acoustic velocity. Reduction of the spatial coherence of the condensate emission along the surface acoustic wave direction is attributed to the suppression of coupling between the spatially modulated condensates. Interparticle interactions observed at high polariton densities screen the acoustic potential, partially reversing its effect on spatial coherence.

  13. Bose-Einstein condensation at constant temperature

    NASA Astrophysics Data System (ADS)

    Erhard, M.; Schmaljohann, H.; Kronjäger, J.; Bongs, K.; Sengstock, K.

    2004-09-01

    We present an experimental approach to Bose-Einstein condensation by increasing the particle number of the system at almost constant temperature. In particular, the emergence of a new condensate is observed in multicomponent F=1 spinor condensates of Rb87 . Furthermore, we develop a simple rate-equation model for multicomponent Bose-Einstein condensate thermodynamics at finite temperature which well reproduces the measured effects.

  14. Bipolar disorder

    MedlinePlus

    Manic depression; Bipolar affective disorder; Mood disorder - bipolar; Manic depressive disorder ... happiness and high activity or energy (mania) or depression and low activity or energy (depression). The following ...

  15. Plagioclase-rich inclusions in carbonaceous chondrite meteorites - Liquid condensates?

    NASA Technical Reports Server (NTRS)

    Wark, D. A.

    1987-01-01

    The characteristics and formation of coarse-grained, plagioclase-rich inclusions are investigated. The textures, mineralogical compositions, and initial Al-26/Al-27 ratios for the plagioclase-rich inclusions are described. It is observed that plagioclase-rich inclusions in carbonaceous chondrites are either Ca-Al-rich inclusions (CAIs) composed of 30-60 vol pct anorthite, and less than 35 vol pct Ti-Al-pyroxene and melilite, or CA chondrites composed of plagioclase, pyroxene, olivine, spinel, and melilite. It is observed that CA chondrules are chemically and mineralogically the most similar components shared by carbonaceous and ordinary chondrites. The textural changes observed in the inclusions are examined. The data reveal that the CAIs have three textural groups: coarse anorthite laths, equigranular anorthite and Ti-Al-pyroxene, and lacy Ti-Al-pyroxene and fine-grained anorthite.

  16. Plagioclase-rich inclusions in carbonaceous chondrite meteorites - Liquid condensates?

    NASA Astrophysics Data System (ADS)

    Wark, D. A.

    1987-02-01

    The characteristics and formation of coarse-grained, plagioclase-rich inclusions are investigated. The textures, mineralogical compositions, and initial Al-26/Al-27 ratios for the plagioclase-rich inclusions are described. It is observed that plagioclase-rich inclusions in carbonaceous chondrites are either Ca-Al-rich inclusions (CAIs) composed of 30-60 vol pct anorthite, and less than 35 vol pct Ti-Al-pyroxene and melilite, or CA chondrites composed of plagioclase, pyroxene, olivine, spinel, and melilite. It is observed that CA chondrules are chemically and mineralogically the most similar components shared by carbonaceous and ordinary chondrites. The textural changes observed in the inclusions are examined. The data reveal that the CAIs have three textural groups: coarse anorthite laths, equigranular anorthite and Ti-Al-pyroxene, and lacy Ti-Al-pyroxene and fine-grained anorthite.

  17. Well test analysis for gas-condensate reservoirs

    SciTech Connect

    Vo, D.T.

    1989-01-01

    This dissertation provides a detailed description of the performance of gas condensate producing wells and proposes well test analysis procedures for such systems as well as far volatile oil and black-oil reservoirs. Synthetic well test data generated from a compositional simulator are used in the analysis of drawdown and buildup tests. For wells producing at constant rate during the transient flow period, the use of the pseudopressure approach is reviewed. Several existing analysis methods are compared. These include the single-phase gas pseudopressure, the steady-state analogue, the pressure-squared function, and the GOR method. A new method, based on pressure derivatives, for computing the appropriate pseudopressure function is introduced. For wells producing multiple phases at constant pressure during the transient flow period, a new method for approximating the pseudopressure is introduced. The advantage of this approach is that relative permeability data are not required. The method allows for approximate procedures to calculate sandface effective permeability and skin factor from either the semilog method or the use of constant pressure type curves. For multiphase flow during the boundary-dominated flow period, the procedure of plotting p/Z versus cumulative production is extended for a wide range of fluid systems. Appropriate pseudopressure and pseudotimes are introduced to correlate the responses of gas condensate producing wells to the constant rate liquid solution for the depletion period. Analysis of the isochronal testing for gas condensate producing wells is briefly examined. The effects of liquid condensation, rate sequence, rock and fluid properties, and near-well skin damage on the slope of the back-pressure curves and AOF estimate are investigated.

  18. Wealth condensation in pareto macroeconomies

    NASA Astrophysics Data System (ADS)

    Burda, Z.; Johnston, D.; Jurkiewicz, J.; Kamiński, M.; Nowak, M. A.; Papp, G.; Zahed, I.

    2002-02-01

    We discuss a Pareto macroeconomy (a) in a closed system with fixed total wealth and (b) in an open system with average mean wealth, and compare our results to a similar analysis in a super-open system (c) with unbounded wealth [J.-P. Bouchaud and M. Mézard, Physica A 282, 536 (2000)]. Wealth condensation takes place in the social phase for closed and open economies, while it occurs in the liberal phase for super-open economies. In the first two cases, the condensation is related to a mechanism known from the balls-in-boxes model, while in the last case, to the nonintegrable tails of the Pareto distribution. For a closed macroeconomy in the social phase, we point to the emergence of a ``corruption'' phenomenon: a sizeable fraction of the total wealth is always amassed by a single individual.

  19. Innovative use of membrane contactor as condenser for heat recovery in carbon capture.

    PubMed

    Yan, Shuiping; Zhao, Shuaifei; Wardhaugh, Leigh; Feron, Paul H M

    2015-02-17

    The gas-liquid membrane contactor generally used as a nonselective gas absorption enhancement device is innovatively proposed as a condenser for heat recovery in liquid-absorbent-based carbon capture. The membrane condenser is used as a heat exchanger to recover the latent heat of the exiting vapor from the desorber, and it can help achieve significant energy savings when proper membranes with high heat-transfer coefficients are used. Theoretical thermodynamic analysis of mass and heat transfer in the membrane condensation system shows that heat recovery increases dramatically as inlet gas temperature rises and outlet gas temperature falls. The optimal split mass flow rate is determined by the inlet gas temperature and the overall heat-transfer coefficient in the condensation system. The required membrane area is also strongly dependent on the overall heat-transfer coefficient, particularly at higher inlet gas temperatures. Mass transfer across the membrane has an insignificant effect on heat transfer and heat recovery, suggesting that membrane wetting may not be an issue when a membrane condenser is used for heat recovery. Our analysis provides important insights into the energy recovery performance of the membrane condensation system as well as selection of operational parameters, such as split mass flow rate and membrane area, thickness, and thermal conductivity. PMID:25590169

  20. Efficient use of an intermediate reboiler or condenser in a binary distillation

    SciTech Connect

    Agrawal, R.; Herron, D.M.

    1998-06-01

    The impact of an intermediate reboiler or condenser on the distillation of ideal binary mixtures into pure product streams is studied using a simplified model. The advantage of heuristics derived from this study is that they can quickly tell a process engineer if an intermediate reboiler or condenser is going to be effective in improving the efficiency and, of the two options, which one would be more effective. The heuristics simply states that if the actual fraction of liquid in a given feed is less than that with the maximum thermodynamic efficiency for distillation with no intermediate reboiler or condenser, then an intermediate condenser not only substantially improves the thermodynamic efficiency but is also more effective than an intermediate reboiler. An analogous heuristics exists for the intermediate reboiler when the fraction of liquid in the feed is greater than the optimum. Quick identification of cases that can achieve a substantial improvement in efficiency provides an incentive to search for the proper utilities needed for the intermediate reboiler or condenser. When relatively pure feed streams (concentration of either component greater than 90%) are distilled, the extremely low efficiencies of distillation can be remarkably improved by using an intermediate reboiler or condenser.

  1. Condensation of trace species to form ice layers in Titan's stratosphere

    NASA Astrophysics Data System (ADS)

    Barth, Erika L.

    2015-11-01

    In addition to the organic haze particles produced photochemically in Titan's upper atmosphere, a number of trace gases are also created. These hydrocarbon and nitrile species include C2H6, C2H2, C4H10, HCN, HC3N, C2H5CN and many more. While both Voyager and Cassini observations have found evidence for ices (e.g. C4N2, HCN) in the atmosphere above Titan's poles, these species are also likely to condense at other latitudes forming optically thin ice layers in the stratosphere. A series of simulations have been conducted using Titan CARMA, a 1-D microphysics and radiative transfer model, to explore cloud particle formation with ~20 of Titan's trace hydrocarbon and nitrile gases. These species reach their condensation temperatures between 60 and 110 km. Most condense solely as ices, however, C3H8 will condense first near 70 km as a liquid and then freeze as the droplets descend toward the surface. C3H8 and C2H6 join CH4 as a liquid at Titan's surface. Many ices have long condensation timescales resulting in particle radii ~1 μm or less. Several (including HCN, C3H8, C2H2) will grow 10-50 times larger. Expected condensation altitudes and particle sizes will be presented, as well as the implications for the optical properties of Titan's stratospheric aerosol particles.This work was supported by the NASA Outer Planets Research program.

  2. Atomistic modeling of dropwise condensation

    NASA Astrophysics Data System (ADS)

    Sikarwar, B. S.; Singh, P. L.; Muralidhar, K.; Khandekar, S.

    2016-05-01

    The basic aim of the atomistic modeling of condensation of water is to determine the size of the stable cluster and connect phenomena occurring at atomic scale to the macroscale. In this paper, a population balance model is described in terms of the rate equations to obtain the number density distribution of the resulting clusters. The residence time is taken to be large enough so that sufficient time is available for all the adatoms existing in vapor-phase to loose their latent heat and get condensed. The simulation assumes clusters of a given size to be formed from clusters of smaller sizes, but not by the disintegration of the larger clusters. The largest stable cluster size in the number density distribution is taken to be representative of the minimum drop radius formed in a dropwise condensation process. A numerical confirmation of this result against predictions based on a thermodynamic model has been obtained. Results show that the number density distribution is sensitive to the surface diffusion coefficient and the rate of vapor flux impinging on the substrate. The minimum drop radius increases with the diffusion coefficient and the impinging vapor flux; however, the dependence is weak. The minimum drop radius predicted from thermodynamic considerations matches the prediction of the cluster model, though the former does not take into account the effect of the surface properties on the nucleation phenomena. For a chemically passive surface, the diffusion coefficient and the residence time are dependent on the surface texture via the coefficient of friction. Thus, physical texturing provides a means of changing, within limits, the minimum drop radius. The study reveals that surface texturing at the scale of the minimum drop radius does not provide controllability of the macro-scale dropwise condensation at large timescales when a dynamic steady-state is reached.

  3. Confinement from constant field condensates

    NASA Astrophysics Data System (ADS)

    Gaete, Patricio; Guendelman, Eduardo; Spallucci, Euro

    2007-01-01

    For (2 + 1)- and (3 + 1)-dimensional reformulated SU (2) Yang-Mills theory, we compute the interaction potential within the framework of the gauge-invariant but path-dependent variables formalism. This reformulation is due to the presence of a constant gauge field condensate. Our results show that the interaction energy contains a linear term leading to the confinement of static probe charges. This result is equivalent to that of the massive Schwinger model.

  4. Condensation on Slippery Asymmetric Bumps

    NASA Astrophysics Data System (ADS)

    Park, Kyoo-Chul; Kim, Philseok; Aizenberg, Joanna

    Controlling dropwise condensation by designing surfaces that enable droplets to grow rapidly and be shed as quickly as possible is fundamental to water harvesting systems, thermal power generation, distillation towers, etc. However, cutting-edge approaches based on micro/nanoscale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach based on principles derived from Namib desert beetles, cacti, and pitcher plants that synergistically couples both aspects of condensation and outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle's bump geometry in promoting condensation, we show how to maximize vapor diffusion flux at the apex of convex millimetric bumps by optimizing curvature and shape. Integrating this apex geometry with a widening slope analogous to cactus spines couples rapid drop growth with fast directional transport, by creating a free energy profile that drives the drop down the slope. This coupling is further enhanced by a slippery, pitcher plant-inspired coating that facilitates feedback between coalescence-driven growth and capillary-driven motion. We further observe an unprecedented six-fold higher exponent in growth rate and much faster shedding time compared to other surfaces. We envision that our fundamental understanding and rational design strategy can be applied to a wide range of phase change applications.

  5. Extreme-UV lithography condenser

    DOEpatents

    Sweatt, William C.; Sweeney, Donald W.; Shafer, David; McGuire, James

    2001-01-01

    Condenser system for use with a ringfield camera in projection lithography where the condenser includes a series of segments of a parent aspheric mirror having one foci at a quasi-point source of radiation and the other foci at the radius of a ringfield have all but one or all of their beams translated and rotated by sets of mirrors such that all of the beams pass through the real entrance pupil of a ringfield camera about one of the beams and fall onto the ringfield radius as a coincident image as an arc of the ringfield. The condenser has a set of correcting mirrors with one of the correcting mirrors of each set, or a mirror that is common to said sets of mirrors, from which the radiation emanates, is a concave mirror that is positioned to shape a beam segment having a chord angle of about 25 to 85 degrees into a second beam segment having a chord angle of about 0 to 60 degrees.

  6. Hydrophobic liquid/gas separator for heat pipes

    NASA Technical Reports Server (NTRS)

    Marcus, B. D.

    1972-01-01

    Perforated nonwetting plug of material such as polytetrafluoroethylene is mounted in gas reservoir feed tube, preferably at end which extends into heat pipe condenser section, to prevent liquid from entering gas reservoir of passively controlled heat pipe.

  7. Microscopic droplet formation and energy transport analysis of condensation on scalable superhydrophobic nanostructured copper oxide surfaces.

    PubMed

    Li, GuanQiu; Alhosani, Mohamed H; Yuan, ShaoJun; Liu, HaoRan; Ghaferi, Amal Al; Zhang, TieJun

    2014-12-01

    Utilization of nanotechnologies in condensation has been recognized as one opportunity to improve the efficiency of large-scale thermal power and desalination systems. High-performance and stable dropwise condensation in widely-used copper heat exchangers is appealing for energy and water industries. In this work, a scalable and low-cost nanofabrication approach was developed to fabricate superhydrophobic copper oxide (CuO) nanoneedle surfaces to promote dropwise condensation and even jumping-droplet condensation. By conducting systematic surface characterization and in situ environmental scanning electron microscope (ESEM) condensation experiments, we were able to probe the microscopic formation physics of droplets on irregular nanostructured surfaces. At the early stages of condensation process, the interfacial surface tensions at the edge of CuO nanoneedles were found to influence both the local energy barriers for microdroplet growth and the advancing contact angles when droplets undergo depinning. Local surface roughness also has a significant impact on the volume of the condensate within the nanostructures and overall heat transfer from the vapor to substrate. Both our theoretical analysis and in situ ESEM experiments have revealed that the liquid condensate within the nanostructures determines the amount of the work of adhesion and kinetic energy associated with droplet coalescence and jumping. Local and global droplet growth models were also proposed to predict how the microdroplet morphology within nanostructures affects the heat transfer performance of early-stage condensation. Our quantitative analysis of microdroplet formation and growth within irregular nanostructures provides the insight to guide the anodization-based nanofabrication for enhancing dropwise and jumping-droplet condensation performance. PMID:25419845

  8. Design and Fabrication of a Hybrid Superhydrophobic-Hydrophilic Surface That Exhibits Stable Dropwise Condensation.

    PubMed

    Mondal, Bikash; Mac Giolla Eain, Marc; Xu, QianFeng; Egan, Vanessa M; Punch, Jeff; Lyons, Alan M

    2015-10-28

    Condensation of water vapor is an essential process in power generation, water collection, and thermal management. Dropwise condensation, where condensed droplets are removed from the surface before coalescing into a film, has been shown to increase the heat transfer efficiency and water collection ability of many surfaces. Numerous efforts have been made to create surfaces which can promote dropwise condensation, including superhydrophobic surfaces on which water droplets are highly mobile. However, the challenge with using such surfaces in condensing environments is that hydrophobic coatings can degrade and/or water droplets on superhydrophobic surfaces transition from the mobile Cassie to the wetted Wenzel state over time and condensation shifts to a less-effective filmwise mechanism. To meet the need for a heat-transfer surface that can maintain stable dropwise condensation, we designed and fabricated a hybrid superhydrophobic-hydrophilic surface. An array of hydrophilic needles, thermally connected to a heat sink, was forced through a robust superhydrophobic polymer film. Condensation occurs preferentially on the needle surface due to differences in wettability and temperature. As the droplet grows, the liquid drop on the needle remains in the Cassie state and does not wet the underlying superhydrophobic surface. The water collection rate on this surface was studied using different surface tilt angles, needle array pitch values, and needle heights. Water condensation rates on the hybrid surface were shown to be 4 times greater than for a planar copper surface and twice as large for silanized silicon or superhydrophobic surfaces without hydrophilic features. A convection-conduction heat transfer model was developed; predicted water condensation rates were in good agreement with experimental observations. This type of hybrid superhydrophobic-hydrophilic surface with a larger array of needles is low-cost, robust, and scalable and so could be used for heat

  9. Quark and gluon condensates in isospin matter

    SciTech Connect

    He Lianyi; Jiang Yin; Zhuang Pengfei

    2009-04-15

    By applying the Hellmann-Feynman theorem to a charged pion gas, the quark and gluon condensates at low isospin density are determined by precise pion properties. At intermediate density around f{sub {pi}}{sup 2}m{sub {pi}}, from both the estimation for the dilute pion gas and the calculation with the Nambu-Jona-Lasinio model, the quark condensate is strongly and monotonously suppressed, while the gluon condensate is enhanced and can be larger than its vacuum value. This unusual behavior of the gluon condensate is universal for Bose condensed matter of mesons. Our results can be tested by lattice calculations at finite isospin density.

  10. Superfluidity, BEC, and dimensions of liquid 4He in nanopores

    NASA Astrophysics Data System (ADS)

    Markić, L. Vranješ; Glyde, H. R.

    2015-08-01

    We present path integral Monte Carlo (PIMC) calculations of the superfluid fraction, ρS/ρ , and the one-body density matrix (OBDM) [Bose-Einstein condensation (BEC)] of liquid 4He confined in nanopores. Liquid 4He in nanopores represents a dense Bose liquid at reduced dimension and in disorder. The goal is to determine the effective dimensions of the liquid in the pores. It is to test whether observed properties, such as a very low onset temperature for superflow, Tc, can be predicted by a standard, static PIMC ρS/ρ . We simulate a cylinder of liquid of diameter dL surrounded by 5 Å of inert solid 4He in a nanopore of diameter d ; d =dL+10 Å . We find a PIMC ρS(T ) /ρ and OBDM that scales as a 1D fluid Luttinger liquid at extremely small liquid pore diameters only, dL=6 Å . At this dL, the liquid fills the pore in a 1D line at the center of the pore and there is no PIMC superflow. In the range 8 ≤dL≤22 Å the PIMC ρS(T ) /ρ scales as a 2D liquid. In this dL range the liquid fills the pores in 2D-like cylindrical layers. The crossover from no superflow at d =16 Å to superflow at d ≥18 Å agrees with experiment. There is a crossover to 3D scaling at larger dL≃22 Å . In the range 8 ≤dL≤22 Å , the Tc predicted using the Kosterlitz-Thouless 2D scaling criterion of the OBDM agrees well with that obtained from ρS(T ) /ρ . These results suggest that the superflow observed in small pore media is standard static superflow with the low Tc arising from its 2D character. An operational onset temperature, TBEC, for BEC can be defined as the temperature at which there is a crossover from exponential to algebraic decay in the OBDM. This definition leads to a TBEC≥Tc as observed in larger pore media.

  11. Bipolar disorder

    MedlinePlus

    Manic depression; Bipolar affective disorder; Mood disorder - bipolar; Manic depressive disorder ... Bipolar disorder affects men and women equally. It most often starts between ages 15 and 25. The exact ...

  12. Cyclothymic disorder

    MedlinePlus

    ... mental disorder. It is a mild form of bipolar disorder (manic depressive illness), in which a person has ... causes of cyclothymic disorder are unknown. Major depression, bipolar disorder, and cyclothymia often occur together in families. This ...

  13. [Determination of proteomic and metabolic composition of exhaled breath condensate of newborns].

    PubMed

    Kononikhin, A S; Chagovets, V V; Starodubtseva, N L; Ryndin, A Y; Bugrova, A E; Kostyukevich, Y I; Popov, I A; Frankevich, V E; Ionov, O V; Sukhikh, G T; Nikolaev, E N

    2016-01-01

    Here, the possibility of proteomic and metabolomic analysis of the composition of exhaled breath condensate of neonates with respiratory support. The developed method allows non-invasive collecting sufficient amount of the material for identification of disease-specific biomarkers. Samples were collected by using a condensing device that was incorporated into the ventilation system. The collected condensate was analyzed by liquid chromatography coupled with high resolution mass spectrometry and tandem mass spectrometry. The isolated substances were identified with a use of databases for proteins and metabolites. As a result, a number of compounds that compose the exhaled breath condensate was determined and can be considered as possible biomarkers of newborn diseases or stage of development. PMID:27414793

  14. Self-cleaning of superhydrophobic surfaces by self-propelled jumping condensate

    PubMed Central

    Wisdom, Katrina M.; Qu, Xiaopeng; Liu, Fangjie; Watson, Gregory S.; Chen, Chuan-Hua

    2013-01-01

    The self-cleaning function of superhydrophobic surfaces is conventionally attributed to the removal of contaminating particles by impacting or rolling water droplets, which implies the action of external forces such as gravity. Here, we demonstrate a unique self-cleaning mechanism whereby the contaminated superhydrophobic surface is exposed to condensing water vapor, and the contaminants are autonomously removed by the self-propelled jumping motion of the resulting liquid condensate, which partially covers or fully encloses the contaminating particles. The jumping motion off the superhydrophobic surface is powered by the surface energy released upon coalescence of the condensed water phase around the contaminants. The jumping-condensate mechanism is shown to spontaneously clean superhydrophobic cicada wings, where the contaminating particles cannot be removed by gravity, wing vibration, or wind flow. Our findings offer insights for the development of self-cleaning materials. PMID:23630277

  15. Direct evaporative cooling of 39K atoms to Bose-Einstein condensation

    NASA Astrophysics Data System (ADS)

    Landini, M.; Roy, S.; Roati, G.; Simoni, A.; Inguscio, M.; Modugno, G.; Fattori, M.

    2012-09-01

    We report the realization of a Bose-Einstein condensate of 39K atoms without the aid of an additional atomic coolant. Our route to Bose-Einstein condensation comprises sub-Doppler laser cooling of large atomic clouds with more than 1010 atoms and evaporative cooling in an optical dipole trap where the collisional cross section can be increased using magnetic Feshbach resonances. Large condensates with almost 106 atoms can be produced in less than 15 s. Our achievements eliminate the need for sympathetic cooling with Rb atoms, which was the usual route implemented until now due to the unfavorable collisional property of 39K. Our findings simplify the experimental setup for producing Bose-Einstein condensates of 39K atoms with tunable interactions, which have a wide variety of promising applications, including atom interferometry to studies on the interplay of disorder and interactions in quantum gases.

  16. Deterioration of Heat Transfer Performance in Condensation of Binary Vapor Mixtures

    NASA Astrophysics Data System (ADS)

    Fujii, Tetsu

    It is explained using theoretical results for laminar film condensation that the deterioration of heat transfer performance in the case of condensation of binary vapor mixtures is caused by the temperature drop in the vapor boundary layer due to the increase of the concentration of the volatile component at the vapor-liquid interface. As for free convection condensation the agreement between theory and experiment is satisfactory in the case where the condensate film is smooth, while the heat transfer coefficient becomes larger than the theoretical result in the case where drops and/or streaks appear in the film. It is also explained using some examples of experimental results that the heat transferred from a bulk vapor to a cooling surface can be evaluated by simultaneously solving the equations with respect to the heat transfer coefficient for condensation of pure vapors, the mass transfer coefficient in the vapor phase, and the phase equilibrium in the cases where binary vapor mixtures of water, Frons, alcohols and other organic vapors condense in a vertical tube, a plate-fin condenser, a horizontal tube and a horizontal tube bundle. Then, future problems are pointed out.

  17. Spinel-bearing spherules condensed from the Chicxulub impact-vapor plume

    NASA Astrophysics Data System (ADS)

    Ebel, Denton S.; Grossman, Lawrence

    2005-04-01

    Formation of the giant Chicxulub crater off Mexico's Yucatan Peninsula coincided with deposition of the global Ir-rich Cretaceous-Tertiary (K-T) stratigraphic boundary layer ca. 65 Ma. The boundary is marked most sharply by abundant spherules containing unaltered grains of magnesioferrite spinel. Here we predict for the first time the sequential condensation of solids and liquids from the plume of vaporized rock expected from oblique K-T impacts. We predict highly oxidizing plumes that condense silicate liquid droplets bearing spinel grains whose compositions closely match those marking the actual boundary. Systematic global variations in spinel composition are consistent with higher condensation temperatures for spinels found at Atlantic and European sites than for those in the Pacific.

  18. The Liquid Argon Purity Demonstrator

    SciTech Connect

    Adamowski, M.; Carls, B.; Dvorak, E.; Hahn, A.; Jaskierny, W.; Johnson, C.; Jostlein, H.; Kendziora, C.; Lockwitz, S.; Pahlka, B.; Plunkett, R.; Pordes, S.; Rebel, B.; Schmitt, R.; Stancari, M.; Tope, T.; Voirin, E.; Yang, T.

    2014-07-01

    The Liquid Argon Purity Demonstrator was an R&D test stand designed to determine if electron drift lifetimes adequate for large neutrino detectors could be achieved without first evacuating the cryostat. We describe here the cryogenic system, its operations, and the apparatus used to determine the contaminant levels in the argon and to measure the electron drift lifetime. The liquid purity obtained by this system was facilitated by a gaseous argon purge. Additionally, gaseous impurities from the ullage were prevented from entering the liquid at the gas-liquid interface by condensing the gas and filtering the resulting liquid before returning to the cryostat. The measured electron drift lifetime in this test was greater than 6 ms, sustained over several periods of many weeks. Measurements of the temperature profile in the argon, to assess convective flow and boiling, were also made and are compared to simulation.

  19. Bose-Einstein condensation in traps: A quantum Monte Carlo study

    NASA Astrophysics Data System (ADS)

    Dubois, Jonathan L.

    We evaluate the zero temperature properties and Bose-Einstein condensation (BEC) of hard sphere bosons in a harmonic trap using Quantum Monte Carlo methods. The chief purpose of this work is to go beyond the dilute limit, to test the limits of the Gross-Pitaevskii (GP) equation and related mean field approximations and to explore the role of interactions in determining the zero temperature properties of the trapped Bose gas. The density is increased by adjusting both the number of trapped bosons, N, and the s-wave scattering length, a, to study systems from the highly dilute region corresponding to early experiments in trapped BEC [5, 6] up to liquid 4He densities and beyond. Rather than relying on the perturbative Bogoliubov approximation (which assumes a large condensate fraction) to describe the condensate, we use the one-body density matrix (OBDM) formulation of BEC so that the properties of the condensate for systems with arbitrarily large interactions may be studied. In this formulation of BEC, condensate properties are obtained by diagonalizing the OBDM and obtaining the corresponding single particle "natural orbitals" and their occupation numbers for the system. The condensate wave function and condensate fraction are then obtained from the single particle orbital(s) with macroscopic occupation ( N0 >> 1). Within this framework, we calculate the effects of interactions and increased density on the ground state energy, the density profile, the momentum distribution, the condensate fraction and condensate "wave-function" and several other properties. We find that at low Boson density, na3 < 10-5 , where n = N/V and a is the hard core diameter, the GP theory of the condensate describes the whole system within 1%. At na3 ≈ 10-3 corrections are 3% to the GP energy but 30% to the Bogoliubov prediction of the condensate depletion. Mean field theory fails at na3 ≳ 10-2. At high density, na 3 ≳ 0.1, the condensate is localized at the edges of the trap and, in

  20. Cloud Condensation Nuclei in FIRE III

    NASA Technical Reports Server (NTRS)

    Hudson, James G.; Delnore, Victor E. (Technical Monitor)

    2002-01-01

    Yum and Hudson showed that the springtime Arctic aerosol is probably a result of long-range transport at high altitudes. Scavenging of particles by clouds reduces the low level concentrations by a factor of 3. This produces a vertical gradient in particle concentrations when low-level clouds are present. Concentrations are uniform with height when clouds are not present. Low-level CCN (cloud condensation nuclei) spectra are similar to those in other maritime areas as found by previous projects including FIRE 1 and ASTEX, which were also supported on earlier NASA-FIRE grants. Wylie and Hudson carried this work much further by comparing the CCN spectra observed during ACE with back trajectories of air masses and satellite photographs. This showed that cloud scavenging reduces CCN concentrations at all altitudes over the springtime Arctic, with liquid clouds being more efficient scavengers than frozen clouds. The small size of the Arctic Ocean seems to make it more susceptible to continental and thus anthropogenic aerosol influences than any of the other larger oceans.

  1. Molecular madeling of amorphous polymers in the condensed phase

    SciTech Connect

    Curro, J.G.

    1997-12-31

    We have developed a tractable computational approach, PRISM theory (polymer Reference Interaction Site Model), for modeling structure and thermodynamics of polymer liquids and alloys. PRISM theory allows one to predict the effect of polymer architecture and monomer structure on the intermolecular packing in the condensed phase. Three applications of this method are discussed: phase behavior of polymer blends, solubility of gases in polymers, and structure of polymers near walls and interfaces. In these applications, nonrandom mixing effects (not included in previous theories) play an important role in the macroscopic properties of importance to the materials scientist.

  2. Device for rapid transfer of condensable gases into a capillary

    NASA Astrophysics Data System (ADS)

    Halas, S.; Krouse, H. R.

    1984-07-01

    An inverted bellows-sealed vacuum valve was modified by replacing the Teflon pad on its stem by a stainless-steel dish with a knife-edge circumference and a capillary attached through its center. A Teflon cup for containing liquid air was threaded on top into the valve outlet. With the dish down, condensable gases could be frozen on a small surface area on the bottom of the cup. By pushing the dish upwards so the knife edge pushed into the Teflon, the gas was quantitatively transferred into the capillary upon warming.

  3. ENHANCED PERVAPORATION SEPARATION EFFICIENCY VIA STAGED FRACTIONAL CONDENSATION (DEPHLEGMATION) OF PERMEATE VAPOR

    EPA Science Inventory

    In traditional pervaporation systems, the permeate vapor is completely condensed to obtain a liquid permeate stream. For example, in the recovery of ethanol from a 5-wt% aqueous stream (such as a biomass fermentation broth), the permeate from a silicone rubber pervaporation membr...

  4. Liquid over-feeding air conditioning system and method

    DOEpatents

    Mei, V.C.; Chen, F.C.

    1993-09-21

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant. 1 figure.

  5. Liquid over-feeding air conditioning system and method

    DOEpatents

    Mei, Viung C.; Chen, Fang C.

    1993-01-01

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant.

  6. CDW-Exciton Condensate Competition and a Condensate Driven Force

    NASA Astrophysics Data System (ADS)

    Özgün, Ege; Hakioğlu, Tuğrul

    2016-08-01

    We examine the competition between the charge-density wave (CDW) instability and the excitonic condensate (EC) in spatially separated layers of electrons and holes. The CDW and the EC order parameters (OPs), described by two different mechanisms and hence two different transition temperatures TcCDW and TcEC, are self-consistently coupled by a microscopic mean field theory. We discuss the results in our model specifically focusing on the transition-metal dichalcogenides which are considered as the most typical examples of strongly coupled CDW/EC systems with atomic layer separations where the electronic energy scales are large with the critical temperatures in the range TcEC ˜ TcCDW ˜ 100-200 K. An important consequence of this is that the excitonic energy gap, hence the condensed free energy, vary with the layer separation resulting in a new type of force FEC. We discuss the possibility of this force as the possible driver of the structural lattice deformation observed in some TMDCs with a particular attention on the 1T-TiSe2 below 200 K.

  7. Condensing efficiency of the truncated cone condenser and its comparison with the Winston cone condenser in terahertz region

    NASA Astrophysics Data System (ADS)

    Aoki, Makoto; Hiromoto, Norihisa

    2015-01-01

    The angle-dependent condensing efficiency of a truncated cone condenser (TCC) in the terahertz (THz) region has been examined by 2D ray tracing and 3D electromagnetic simulation. The condensing efficiency in the THz region is transferred to that in the optical region by theoretical dispersive reflection from a rough surface, and it is confirmed that the latter is consistent with the measured condensing efficiency in the optical region. Although the TCC has a gradual field of view (FOV) compared with the Winston cone condenser (WCC), we improved the steepness of the FOV by adding a baffle before the input aperture of the TCC. We also proved that the TCC has a high condensing efficiency at around normal incidence in comparison with the WCC in the THz region.

  8. The analysis of diagnostic markers of genetic disorders in human blood and urine using tandem mass spectrometry with liquid secondary ion mass spectrometry

    NASA Astrophysics Data System (ADS)

    Millington, David S.; Kodo, Naoki; Terada, Naoto; Roe, Diane; Chace, Donald H.

    1991-12-01

    A method has been developed for the rapid diagnosis of metabolic diseases based on the analysis of characteristic metabolites in body fluids by fast atom bombardment or liquid secondary ion tandem mass spectrometry (FAB-MS--MS or LSIMS--MS). Acylcarnitine profiles were obtained from 100 [mu]l urine. 200 [mu]l plasma or 25 [mu]l whole blood spotted onto filter paper by simple solvent extraction, esterification and analysis using a precursor ion scan function on a triple quadrupole mass spectrometer. Specificity and sensitivity were improved by adding a small percentage of sodium octyl sulfate to the liquid matrix, which forms ion pairs with acylcarnitine esters. Acylglycines in urine were specifically detected as a group using a different precursor ion scan function. By forming methyl esters, metabolic profiles of both acylcarnitines and acylglycines were achieved in the same sample loading by application of alternating scan functions. Quantitative analysis of selected metabolites was achieved by use of stable isotope-labeled internal standards. Amino acid profiles were obtained from 100 [mu]l plasma and 25 [mu]l whole blood spots using butyl esters and a neutral loss scan function. The quantitative analysis of phenylalanine and tyrosine was achieved in these samples using stable isotope dilution. This capability will facilitate the diagnosis of phenylketonuria and other amino acidemias. These new methods have the requirements of speed, accuracy and capability for automation necessary for large-scale neonatal screening of inborn errors of matabolism.

  9. Condensation on slippery asymmetric bumps

    NASA Astrophysics Data System (ADS)

    Park, Kyoo-Chul; Kim, Philseok; Grinthal, Alison; He, Neil; Fox, David; Weaver, James C.; Aizenberg, Joanna

    2016-03-01

    Controlling dropwise condensation is fundamental to water-harvesting systems, desalination, thermal power generation, air conditioning, distillation towers, and numerous other applications. For any of these, it is essential to design surfaces that enable droplets to grow rapidly and to be shed as quickly as possible. However, approaches based on microscale, nanoscale or molecular-scale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach—based on principles derived from Namib desert beetles, cacti, and pitcher plants—that synergistically combines these aspects of condensation and substantially outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle’s bumpy surface geometry in promoting condensation, and using theoretical modelling, we show how to maximize vapour diffusion fluxat the apex of convex millimetric bumps by optimizing the radius of curvature and cross-sectional shape. Integrating this apex geometry with a widening slope, analogous to cactus spines, directly couples facilitated droplet growth with fast directional transport, by creating a free-energy profile that drives the droplet down the slope before its growth rate can decrease. This coupling is further enhanced by a slippery, pitcher-plant-inspired nanocoating that facilitates feedback between coalescence-driven growth and capillary-driven motion on the way down. Bumps that are rationally designed to integrate these mechanisms are able to grow and transport large droplets even against gravity and overcome the effect of an unfavourable temperature gradient. We further observe an unprecedented sixfold-higher exponent of growth rate, faster onset, higher steady-state turnover rate, and a greater volume of water collected compared to other surfaces. We envision that this fundamental understanding and rational design strategy can be

  10. Condensation on slippery asymmetric bumps.

    PubMed

    Park, Kyoo-Chul; Kim, Philseok; Grinthal, Alison; He, Neil; Fox, David; Weaver, James C; Aizenberg, Joanna

    2016-03-01

    Controlling dropwise condensation is fundamental to water-harvesting systems, desalination, thermal power generation, air conditioning, distillation towers, and numerous other applications. For any of these, it is essential to design surfaces that enable droplets to grow rapidly and to be shed as quickly as possible. However, approaches based on microscale, nanoscale or molecular-scale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach--based on principles derived from Namib desert beetles, cacti, and pitcher plants--that synergistically combines these aspects of condensation and substantially outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle's bumpy surface geometry in promoting condensation, and using theoretical modelling, we show how to maximize vapour diffusion fluxat the apex of convex millimetric bumps by optimizing the radius of curvature and cross-sectional shape. Integrating this apex geometry with a widening slope, analogous to cactus spines, directly couples facilitated droplet growth with fast directional transport, by creating a free-energy profile that drives the droplet down the slope before its growth rate can decrease. This coupling is further enhanced by a slippery, pitcher-plant-inspired nanocoating that facilitates feedback between coalescence-driven growth and capillary-driven motion on the way down. Bumps that are rationally designed to integrate these mechanisms are able to grow and transport large droplets even against gravity and overcome the effect of an unfavourable temperature gradient. We further observe an unprecedented sixfold-higher exponent of growth rate, faster onset, higher steady-state turnover rate, and a greater volume of water collected compared to other surfaces. We envision that this fundamental understanding and rational design strategy can be

  11. Condensing osteitis in oral region.

    PubMed

    Holly, D; Jurkovic, R; Mracna, J

    2009-01-01

    Condensing osteitis is defined as pathologic growth of maxillomandibular bones characterized by mild clinical symptoms. The bone thickening reflects the impaired bone rearrangement in response to mild infection of dental pulp. This clinical study describes case reports of patients sent to us with radiological findings and clinical examination that failed to lead to definitive diagnosis. On differential diagnosis, all bone tissue tumors were considered. Based on clinical and radiological findings (bone density and trabeculation of the bone) we settled on the diagnosis of osteitis condensans, which allowed us to remain in conservative therapy in terms of observing the patient (Fig. 3, Ref. 26). Full Text (Free, PDF) www.bmj.sk. PMID:20120441

  12. Turbulent Distortion of Condensate Accretion

    NASA Technical Reports Server (NTRS)

    Hazoume, R.; Orou Chabi, J.; Johnson, J. A., III

    1997-01-01

    When a simple model for the relationship between the density-temperature fluctuation correlation and mean values is used, we determine that the rate of change of turbulent intensity can influence directly the accretion rate of droplets. Considerable interest exists in the accretion rate for condensates in nonequilibrium flow with icing and the potential role which reactant accretion can play in nonequilibrium exothermic reactant processes. Turbulence is thought to play an important role in such flows. It has already been experimentally determined that turbulence influences the sizes of droplets in the heterogeneous nucleation of supersaturated vapors. This paper addresses the issue of the possible influence of turbulence on the accretion rate of droplets.

  13. Condensing Non-Abelian Quasiparticles

    SciTech Connect

    Hermanns, M.

    2010-02-05

    A most interesting feature of certain fractional quantum Hall states is that their quasiparticles obey non-Abelian fractional statistics. So far, candidate non-Abelian wave functions have been constructed from conformal blocks in cleverly chosen conformal field theories. In this work we present a hierarchy scheme by which we can construct daughter states by condensing non-Abelian quasiparticles (as opposed to quasiholes) in a parent state, and show that the daughters have a non-Abelian statistics that differs from the parent. In particular, we discuss the daughter of the bosonic, spin-polarized Moore-Read state at nu=4/3 as an explicit example.

  14. Velocity Condensation for Magnetotactic Bacteria.

    PubMed

    Rupprecht, Jean-François; Waisbord, Nicolas; Ybert, Christophe; Cottin-Bizonne, Cécile; Bocquet, Lydéric

    2016-04-22

    Magnetotactic swimmers tend to align along magnetic field lines against stochastic reorientations. We show that the swimming strategy, e.g., active Brownian motion versus run-and-tumble dynamics, strongly affects the orientation statistics. The latter can exhibit a velocity condensation whereby the alignment probability density diverges. As a consequence, we find that the swimming strategy affects the nature of the phase transition to collective motion, indicating that Lévy run-and-tumble walks can outperform active Brownian processes as strategies to trigger collective behavior. PMID:27152825

  15. Velocity Condensation for Magnetotactic Bacteria

    NASA Astrophysics Data System (ADS)

    Rupprecht, Jean-François; Waisbord, Nicolas; Ybert, Christophe; Cottin-Bizonne, Cécile; Bocquet, Lydéric

    2016-04-01

    Magnetotactic swimmers tend to align along magnetic field lines against stochastic reorientations. We show that the swimming strategy, e.g., active Brownian motion versus run-and-tumble dynamics, strongly affects the orientation statistics. The latter can exhibit a velocity condensation whereby the alignment probability density diverges. As a consequence, we find that the swimming strategy affects the nature of the phase transition to collective motion, indicating that Lévy run-and-tumble walks can outperform active Brownian processes as strategies to trigger collective behavior.

  16. Autism spectrum disorder

    MedlinePlus

    Autism; Autistic disorder; Asperger syndrome; Childhood disintegrative disorder; Pervasive developmental disorder ... to be regarded as separate disorders: Autistic disorder Asperger syndrome Childhood disintegrative disorder Pervasive developmental disorder

  17. Methods of forming and using porous structures for energy efficient separation of light gases by capillary condensation

    DOEpatents

    Calamur, Narasimhan; Carrera, Martin E.; Devlin, David J.; Archuleta, Tom

    2000-01-01

    The present invention relates to an improved method and apparatus for separating one or more condensable compounds from a mixture of two or more gases of differing volatilities by capillary fractionation in a membrane-type apparatus, and a method of forming porous structures therefor. More particularly, the invention includes methods of forming and using an apparatus consisting, at least in part, of a porous structure having capillary-type passages extending between a plurality of small openings on the first side and larger openings on a second side of the structure, the passages being adapted to permit a condensed liquid to flow therethrough substantially by capillary forces, whereby vapors from the mixture are condensed, at least in part, and substantially in and adjacent to the openings on the first side, and are caused to flow in a condensed liquid state, substantially in the absence of vapor, from the openings on the first side to the openings on the second side.

  18. A new experiment for investigating evaporation and condensation of cryogenic propellants

    NASA Astrophysics Data System (ADS)

    Bellur, K.; Médici, E. F.; Kulshreshtha, M.; Konduru, V.; Tyrewala, D.; Tamilarasan, A.; McQuillen, J.; Leão, J. B.; Hussey, D. S.; Jacobson, D. L.; Scherschligt, J.; Hermanson, J. C.; Choi, C. K.; Allen, J. S.

    2016-03-01

    Passive and active technologies have been used to control propellant boil-off, but the current state of understanding of cryogenic evaporation and condensation in microgravity is insufficient for designing large cryogenic depots critical to the long-term space exploration missions. One of the key factors limiting the ability to design such systems is the uncertainty in the accommodation coefficients (evaporation and condensation), which are inputs for kinetic modeling of phase change. A novel, combined experimental and computational approach is being used to determine the accommodation coefficients for liquid hydrogen and liquid methane. The experimental effort utilizes the Neutron Imaging Facility located at the National Institute of Standards and Technology (NIST) in Gaithersburg, Maryland to image evaporation and condensation of hydrogenated propellants inside of metallic containers. The computational effort includes numerical solution of a model for phase change in the contact line and thin film regions as well as an CFD effort for determining the appropriate thermal boundary conditions for the numerical solution of the evaporating and condensing liquid. Using all three methods, there is the possibility of extracting the accommodation coefficients from the experimental observations. The experiments are the first known observation of a liquid hydrogen menisci condensing and evaporating inside aluminum and stainless steel cylinders. The experimental technique, complimentary computational thermal model and meniscus shape determination are reported. The computational thermal model has been shown to accurately track the transient thermal response of the test cells. The meniscus shape determination suggests the presence of a finite contact angle, albeit very small, between liquid hydrogen and aluminum oxide.

  19. Fluorescent and Electroactive Low-Viscosity Tetrazine-Based Organic Liquids.

    PubMed

    Allain, Clémence; Piard, Jonathan; Brosseau, Arnaud; Han, Madeleine; Paquier, Julien; Marchandier, Thomas; Lequeux, Médéric; Boissière, Cédric; Audebert, Pierre

    2016-08-10

    New fluorescent molecular liquids with a tetrazine core have been prepared. These compounds remain liquid at least down to -60 °C and display very low viscosities (28 mPa.s for liquid 1, 58 mPa.s for liquid 2). Both compounds remain fluorescent in the condensed phase. For liquid 1, intermolecular quenching is observed to a certain extent, whereas liquid 2 displays similar photophysical properties in dilute solution and in neat film. PMID:27434378

  20. Investigation of Condensing Ice Heat Exchangers for MTSA Technology Development

    NASA Technical Reports Server (NTRS)

    Padilla, Sebastian; Powers, Aaron; Ball, Tyler; Lacomini, Christie; Paul, Heather L.

    2009-01-01

    Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is being developed for thermal, carbon dioxide (CO2) and humidity control for a Portable Life Support Subsystem (PLSS). Metabolically-produced CO2 present in the ventilation gas of a PLSS is collected using a CO2-selective adsorbent via temperature swing adsorption. The temperature swing is initiated through cooling to well below metabolic temperatures. Cooling is achieved with a sublimation heat exchanger using water or liquid carbon dioxide (L CO2) expanded below sublimation temperature when exposed to low pressure or vacuum. Subsequent super heated vapor, as well as additional coolant, is used to further cool the astronaut. The temperature swing on the adsorbent is then completed by warming the adsorbent with a separate condensing ice heat exchanger (CIHX) using metabolic heat from moist ventilation gas. The condensed humidity in the ventilation gas is recycled at the habitat. The water condensation from the ventilation gas represents a significant source of potential energy for the warming of the adsorbent bed as it represents as much as half of the energy potential in the moist ventilation gas. Designing a heat exchanger to efficiently transfer this energy to the adsorbent bed and allow the collection of the water is a challenge since the CIHX will operate in a temperature range from 210K to 280K. The ventilation gas moisture will first freeze and then thaw, sometimes existing in three phases simultaneously.

  1. Aldol Condensation of Volatile Carbonyl Compounds in Acidic Aerosols

    NASA Astrophysics Data System (ADS)

    Noziere, B.; Esteve, W.

    2003-12-01

    Reactions of volatile organic compounds in acidic aerosols have been shown recently to be potentially important for organic aerosol formation and growth. Aldol condensation, the acid-catalyzed polymerization of carbonyl compounds, is a likely candidate to enhance the flux of organic matter from the gas phase to the condensed phase in the atmosphere. Until now these reactions have only been characterized for conditions relevant to synthesis (high acidities and liquid phase systems) and remote from atmospheric ones. In this work, the uptake of gas-phase acetone and 2,4\\-pentanedione by sulfuric acid solutions has been measured at room temperature using a Rotated Wetted Wall Reactor coupled to a Mass Spectrometer. The aldol condensation rate constants for 2,4\\-pentanedione measured so far for sulfuric acid solutions between 96 and 70 % wt. display a variation with acidity in agreement with what predicted in the organic chemical literature. The values of these constants, however, are much lower than expected for this compound, and comparable to the ones of acetone. Experiments are underway to complete this study to lower acidities and understand the discrepancies with the predicted reactivity.

  2. Extension of JAGUAR Procedures for New Gaseous and Condensed Species

    NASA Astrophysics Data System (ADS)

    Stiel, Leonard; Baker, Ernest; Murphy, Daniel

    2011-06-01

    JAGUAR is a highly efficient and accurate thermochemical equilibrium program for the detonation properties of explosives. In previous studies equation of state EXP-6 parameters for H-CN-O gaseous explosives product species have been optimized with available individual species Hugoniot data. The Jaguar library also includes solid and liquid properties for carbon and aluminum, silicon, and boron compounds. In this study the Jaguar property library has been expanded to include additional gaseous, liquid, and solid detonation products. New EXP-6 parameters for gaseous fluorine and chlorine compounds have been established through theoretical procedures, and by analyses of Hugoniot data for the actual species or for reactants which decompose into these compounds. Properties for additional condensed species have also been analyzed and added to the library. Extensive tests have beeb performed to determine the accuracy of calculated detonation properties in comparison to experimental data. The authors gratefully acknowledge the support of the Institute for Multi Scale Reactive Modeling.

  3. Grand-canonical simulation of DNA condensation with two salts, effect of divalent counterion size

    NASA Astrophysics Data System (ADS)

    Nguyen, Toan T.

    2016-02-01

    The problem of DNA- DNA interaction mediated by divalent counterions is studied using a generalized grand-canonical Monte-Carlo simulation for a system of two salts. The effect of the divalent counterion size on the condensation behavior of the DNA bundle is investigated. Experimentally, it is known that multivalent counterions have strong effect on the DNA condensation phenomenon. While tri- and tetra-valent counterions are shown to easily condense free DNA molecules in solution into toroidal bundles, the situation with divalent counterions is not as clear cut. Some divalent counterions like Mg+2 are not able to condense free DNA molecules in solution, while some like Mn+2 can condense them into disorder bundles. In restricted environment such as in two dimensional system or inside viral capsid, Mg+2 can have strong effect and able to condense them, but the condensation varies qualitatively with different system, different coions. It has been suggested that divalent counterions can induce attraction between DNA molecules but the strength of the attraction is not strong enough to condense free DNA in solution. However, if the configuration entropy of DNA is restricted, these attractions are enough to cause appreciable effects. The variations among different divalent salts might be due to the hydration effect of the divalent counterions. In this paper, we try to understand this variation using a very simple parameter, the size of the divalent counterions. We investigate how divalent counterions with different sizes can lead to varying qualitative behavior of DNA condensation in restricted environments. Additionally, a grand canonical Monte-Carlo method for simulation of systems with two different salts is presented in detail.

  4. Grand-canonical simulation of DNA condensation with two salts, effect of divalent counterion size.

    PubMed

    Nguyen, Toan T

    2016-02-14

    The problem of DNA- DNA interaction mediated by divalent counterions is studied using a generalized grand-canonical Monte-Carlo simulation for a system of two salts. The effect of the divalent counterion size on the condensation behavior of the DNA bundle is investigated. Experimentally, it is known that multivalent counterions have strong effect on the DNA condensation phenomenon. While tri- and tetra-valent counterions are shown to easily condense free DNA molecules in solution into toroidal bundles, the situation with divalent counterions is not as clear cut. Some divalent counterions like Mg(+2) are not able to condense free DNA molecules in solution, while some like Mn(+2) can condense them into disorder bundles. In restricted environment such as in two dimensional system or inside viral capsid, Mg(+2) can have strong effect and able to condense them, but the condensation varies qualitatively with different system, different coions. It has been suggested that divalent counterions can induce attraction between DNA molecules but the strength of the attraction is not strong enough to condense free DNA in solution. However, if the configuration entropy of DNA is restricted, these attractions are enough to cause appreciable effects. The variations among different divalent salts might be due to the hydration effect of the divalent counterions. In this paper, we try to understand this variation using a very simple parameter, the size of the divalent counterions. We investigate how divalent counterions with different sizes can lead to varying qualitative behavior of DNA condensation in restricted environments. Additionally, a grand canonical Monte-Carlo method for simulation of systems with two different salts is presented in detail. PMID:26874503

  5. Axions: Bose Einstein condensate or classical field?

    NASA Astrophysics Data System (ADS)

    Davidson, Sacha

    2015-05-01

    The axion is a motivated dark matter candidate, so it would be interesting to find features in Large Scale Structures specific to axion dark matter. Such features were proposed for a Bose Einstein condensate of axions, leading to confusion in the literature (to which I contributed) about whether axions condense due to their gravitational interactions. This note argues that the Bose Einstein condensation of axions is a red herring: the axion dark matter produced by the misalignment mechanism is already a classical field, which has the distinctive features attributed to the axion condensate (BE condensates are described as classical fields). This note also estimates that the rate at which axion particles condense to the field, or the field evaporates to particles, is negligible.

  6. Violation of the spin-statistics theorem and the bose-einstein condensation of particles with half-integer spin.

    PubMed

    Scammell, H D; Sushkov, O P

    2015-02-01

    We consider the Bose condensation of bosonic particles with spin 1/2. The condensation is driven by an external magnetic field. Our work is motivated by ideas of quantum critical deconfinement and bosonic spinons in spin liquid states. We show that both the nature of the novel Bose condensate and the excitation spectrum are fundamentally different from that in the usual integer spin case. We predict two massive ("Higgs") excitations and two massless Goldstone excitations. One of the Goldstone excitations has a linear excitation spectrum and another has a quadratic spectrum. This implies that the Bose condensate does not support superfluidity, the Landau criterion is essentially violated. We formulate a "smoking gun" criterion for searches of the novel Bose condensation. PMID:25699457

  7. Development of a liquid jet model for implementation in a 3-dimensional Eularian analysis tool

    NASA Astrophysics Data System (ADS)

    Buschman, Francis X., III

    The ability to model the thermal behavior of a nuclear reactor is of utmost importance to the reactor designer. Condensation is an important phenomenon when modeling a reactor system's response to a Loss Of Coolant Accident (LOCA). Condensation is even more important with the use of passive safety systems which rely on condensation heat transfer for long term cooling. The increasing use of condensation heat transfer, including condensation on jets of water, in safety systems puts added pressure to correctly model this phenomenon with thermal-hydraulic system and sub-channel analysis codes. In this work, a stand alone module with which to simulate condensation on a liquid jet was developed and then implemented within a reactor vessel analysis code to improve that code's handling of jet condensation. It is shown that the developed liquid jet model vastly improves the ability of COBRA-TF to model condensation on turbulent liquid jets. The stand alone jet model and the coupled liquid jet COBRA-TF have been compared to experimental data. Jet condensation heat transfer experiments by Celata et al. with a variety of jet diameters, velocities, and subcooling were utilized to evaluate the models. A sensitivity study on the effects of noncondensables on jet condensation was also carried out using the stand alone jet model.

  8. The condensate from torus knots

    NASA Astrophysics Data System (ADS)

    Gorsky, A.; Milekhin, A.; Sopenko, N.

    2015-09-01

    We discuss recently formulated instanton-torus knot duality in Ω-deformed 5D SQED on {{R}}^4× {S}^1 focusing at the microscopic aspects of the condensate formation in the instanton ensemble. Using the chain of dualities and geometric transitions we embed the SQED with a surface defect into the SU(2) SQCD with N f = 4 and identify the numbers ( n, m) of the torus T n, m knot as instanton charge and electric charge. The HOMFLY torus knot invariants in the fundamental representation provide entropic factor in the condensate of the massless flavor counting the degeneracy of the instanton-W-boson web with instanton and electric numbers ( n, m) but different spin and flavor content. Using the inverse geometrical transition we explain how our approach is related to the evaluation of the HOMFLY invariants in terms of Wilson loop in 3d CS theory. The reduction to 4D theory is briefly considered and some analogy with baryon vertex is conjectured.

  9. Condensation induced water hammer safety

    SciTech Connect

    Gintner, M.A.

    1997-03-10

    Condensation induced water hammer events in piping systems can cause catastrophic steam system failures which can result in equipment damage, personal injury, and even death. As an industry, we have learned to become accustomed to the ''banging'' that we often hear in our steam piping systems, and complacent in our actions to prevent it. It is unfortunate that lives are lost needlessly, as this type of water hammer event is preventable if one only applies some basic principles when operating and maintaining their steam systems. At the U. S. Department of Energy's Hanford Site where I work, there was one such accident that occurred in 1993 which took the life of a former co-worker and friend of mine. Hanford was established as part of the Manhattan Project during World War II. it is a 560 square mile complex located along the banks of the Columbia River in Southeastern Washington State. For almost 45 years, hanford's mission was to produce weapons grade plutonium for our nations defense programs. Today, Hanford no longer produces plutonium, but is focused on site clean-up and economic diversification. Hanford still uses steam for heating and processing activities, utilizing over 20 miles of piping distribution systems similar to those found in industry. Although these aging systems are still sound, they cannot stand up to the extreme pressure pulses developed by a condensation induced water hammer.

  10. Quantum chemical approach for condensed-phase thermochemistry: Proposal of a harmonic solvation model

    NASA Astrophysics Data System (ADS)

    Nakai, Hiromi; Ishikawa, Atsushi

    2014-11-01

    We propose a novel quantum chemical method, called the harmonic solvation model (HSM), for calculating thermochemical parameters in the condensed phase, particularly in the liquid phase. The HSM represents translational and rotational motions of a solute as vibrations interacting with a cavity wall of solvent molecules. As examples, the HSM and the ideal-gas model (IGM) were used for the standard formation reaction of liquid water, combustion reactions of liquid formic acid, methanol, and ethanol, vapor-liquid equilibration of water and ethanol, and dissolution of gaseous CO2 in water. The numerical results confirmed the reliability and applicability of the HSM. In particular, the temperature dependence of the Gibbs energy of liquid molecules was accurately reproduced by the HSM; for example, the boiling point of water was reasonably determined using the HSM, whereas the conventional IGM treatment failed to obtain a crossing of the two Gibbs energy curves for gaseous and liquid water.

  11. Quantum chemical approach for condensed-phase thermochemistry: Proposal of a harmonic solvation model

    SciTech Connect

    Nakai, Hiromi; Ishikawa, Atsushi

    2014-11-07

    We propose a novel quantum chemical method, called the harmonic solvation model (HSM), for calculating thermochemical parameters in the condensed phase, particularly in the liquid phase. The HSM represents translational and rotational motions of a solute as vibrations interacting with a cavity wall of solvent molecules. As examples, the HSM and the ideal-gas model (IGM) were used for the standard formation reaction of liquid water, combustion reactions of liquid formic acid, methanol, and ethanol, vapor–liquid equilibration of water and ethanol, and dissolution of gaseous CO{sub 2} in water. The numerical results confirmed the reliability and applicability of the HSM. In particular, the temperature dependence of the Gibbs energy of liquid molecules was accurately reproduced by the HSM; for example, the boiling point of water was reasonably determined using the HSM, whereas the conventional IGM treatment failed to obtain a crossing of the two Gibbs energy curves for gaseous and liquid water.

  12. Neutron scattering from amorphous, disordered and nanocrystalline materials

    SciTech Connect

    Price, D.L.

    1994-10-01

    The author has described the power of neutron diffraction and inelastic scattering techniques for determining the structure and dynamics of disordered systems, using the archetypal glass SiO{sub 2} as a detailed example. Of course the field of amorphous and disordered systems contains a much greater variety of types of materials exhibiting a wide range of possible types of disorder. The author gives a brief review of the varieties of order and disorder exhibited by condensed matter.

  13. High-temperature condensates in carbonaceous chondrites

    NASA Technical Reports Server (NTRS)

    Grossman, L.

    1977-01-01

    Equilibrium thermodynamic calculations of the sequence of condensation of minerals from a cooling gas of solar composition play an important role in explaining the mineralogy and trace element content of different types of inclusions in carbonaceous chondrites. Group IV B iron meteorites and enstatite chondrites may also be direct condensates from the solar nebula. Condensation theory provides a framework within which chemical fractionations between different classes of chondrites may be understood.

  14. Bose-Einstein condensation of 84Sr.

    PubMed

    Martinez de Escobar, Y N; Mickelson, P G; Yan, M; DeSalvo, B J; Nagel, S B; Killian, T C

    2009-11-13

    We report Bose-Einstein condensation of (84)Sr in an optical dipole trap. Efficient laser cooling on the narrow intercombination line and an ideal s-wave scattering length allow the creation of large condensates (N(0) approximately 3 x 10(5)) even though the natural abundance of this isotope is only 0.6%. Condensation is heralded by the emergence of a low-velocity component in time-of-flight images. PMID:20365965

  15. Increased Availability From Improved Condenser Design

    SciTech Connect

    Harpster, Joseph W.

    2002-07-01

    Performance parameters and flow characteristics on the shell side of surface condensers are becoming better understood. Contributing to this knowledge base is the recent ability to measure the physical properties as well as the quantity of gases being removed from the condenser by air removal equipment. Reviewed here are the commonality of these data from many operating condensers obtained over the past six years and other known condenser measurements, theory and laboratory experiments. These are combined to formulate global theoretical description of condenser dynamics describing the mechanism responsible for aeration and de-aeration, excess back pressure buildup due to air ingress or generation of other noncondensable gases, and the dissolubility of corrosive gases in condensate. The theoretical description supports a dynamic model useful for deciding condenser configuration design and design improvements. Features of design found in many operating condensers that promote aeration and resulting corrosion are presented. The benefits of the model and engineering design modifications to plant life cycle management, improved condenser performance, outage reduction and reliability improvements, lost load recovery and fuel savings are discussed. (author)

  16. Enhanced condensation heat transfer with wettability patterning

    NASA Astrophysics Data System (ADS)

    Sinha Mahapatra, Pallab; Ghosh, Aritra; Ganguly, Ranjan; Megaridis, Constantine

    2015-11-01

    Condensation of water vapor on metal surfaces is useful for many engineering applications. A facile and scalable method is proposed for removing condensate from a vertical plate during dropwise condensation (DWC) in the presence of non-condensable gases (NCG). We use wettability-patterned superhydrophilic tracks (filmwise condensing domains) on a mirror-finish (hydrophilic) aluminum surface that promotes DWC. Tapered, horizontal ``collection'' tracks are laid to create a Laplace pressure driven flow, which collects condensate from the mirror-finish domains and sends it to vertical ``drainage tracks'' for gravity-induced shedding. An optimal design is achieved by changing the fractional area of superhydrophilic tracks with respect to the overall plate surface, and augmenting capillary-driven condensate-drainage by adjusting the track spatial layout. The design facilitates pump-less condensate drainage and enhances DWC heat transfer on the mirror-finish regions. The study highlights the relative influences of the promoting and retarding effects of dropwise and filmwise condensation zones on the overall heat transfer improvement on the substrate. The study demonstrated ~ 34% heat transfer improvement on Aluminum surface for the optimized design.

  17. Advances in modelling of condensation phenomena

    SciTech Connect

    Liu, W.S.; Zaltsgendler, E.; Hanna, B.

    1997-07-01

    The physical parameters in the modelling of condensation phenomena in the CANDU reactor system codes are discussed. The experimental programs used for thermal-hydraulic code validation in the Canadian nuclear industry are briefly described. The modelling of vapour generation and in particular condensation plays a key role in modelling of postulated reactor transients. The condensation models adopted in the current state-of-the-art two-fluid CANDU reactor thermal-hydraulic system codes (CATHENA and TUF) are described. As examples of the modelling challenges faced, the simulation of a cold water injection experiment by CATHENA and the simulation of a condensation induced water hammer experiment by TUF are described.

  18. Bipolar Disorder

    MedlinePlus

    ... How Can I Help a Friend Who Cuts? Bipolar Disorder KidsHealth > For Teens > Bipolar Disorder Print A A ... Bipolar Disorder en español Trastorno bipolar What Is Bipolar Disorder? Bipolar disorders are one of several medical conditions ...

  19. Spin Dimers: from BEC to Luttinger liquids

    NASA Astrophysics Data System (ADS)

    Giamarchi, Thierry

    2011-03-01

    Localized spin systems, and in particular dimer systems, provide a fantastic laboratory to study the interplay between quantum effects and the interaction between excitations. Magnetic field and temperature allow an excellent control on the density of excitations and various very efficient probes such as neutrons and NMR are available. They can thus be used as ``quantum simulators'' to tackle with great success questions that one would normally search in itinerant interacting quantum systems. In particular they have provided excellent realizations of Bose-Einstein condensates [1,2]. This allowed not only to probe the properties of interacting bosons in a variety of dimensions but also to study in a controlled way additional effects such as disorder. If the dimensionality is reduced they also allow to test in a quantitative way Luttinger liquid physics [3,4,5]. I will discuss these various cases, and show that we have now good theoretical tools to make quantitative comparisons with the experiments. Finally, how to go from this low dimensional case where the spins behave essentially as fermions, to the higher dimensional case where they behave as (essentially free) bosons, is a very challenging, and experimentally relevant issue. This work was supported in part by the Swiss SNF under MaNEP and division II.

  20. ENVIRONMENTAL TECHNOLOGY VERIFICATION REPORT: NEW CONDENSATOR, INC.--THE CONDENSATOR DIESEL ENGINE RETROFIT CRANKCASE VENTILATION SYSTEM

    EPA Science Inventory

    EPA's Environmental Technology Verification Program has tested New Condensator Inc.'s Condensator Diesel Engine Retrofit Crankcase Ventilation System. Brake specific fuel consumption (BSFC), the ratio of engine fuel consumption to the engine power output, was evaluated for engine...

  1. Experimental investigation of CO{sub 2} condensation process using cryogen

    SciTech Connect

    Lee, Cheonkyu; Yoo, Junghyun; Lee, Jisung; Park, Hana; Jeong, Sangkwon

    2014-01-29

    Carbon dioxide (CO{sub 2}) is one of the dominant gas molecules that causes greenhouse effect, i.e. global warming. Numerous studies have been carried out to regulate the emission of CO{sub 2} to reduce greenhouse gas. The liquid CO{sub 2} is a convenient form of transportation compared to high-pressurized gaseous CO{sub 2}. Therefore, the direct liquefaction mechanism of CO{sub 2} at low temperature draws technical attention recently. In particular, cold thermal energy of Liquefied Natural Gas (LNG) could be a candidate to condense gaseous CO{sub 2}, especially in the LNG powered ship. In this paper, the detailed direct condensation process of CO{sub 2} using LN{sub 2} with intermittent solidification is investigated. Pressurized CO{sub 2} at 600 kPa is directly liquefied in a vessel by liquid nitrogen which is supplied into the coiled tube heat exchanger inside the CO{sub 2} vessel. The heat exchanger temperature is controlled from 130 K to 205 K to regulate the solidification and sublimation of CO{sub 2} by duty control with cryogenic solenoid valve. The characteristics of CO{sub 2} condensation process with cryogen are analyzed from the measurement results. The results show that the solidification causes the significant degradation of CO{sub 2} condensation heat transfer. Finally, the condensation rate with and without solidification is compared.

  2. Quenched crystal-field disorder and magnetic liquid ground states in Tb2Sn2-xTixO7 [Crystal field disorder in the quantum spin ice ground state of Tb2Sn2-xTixO7

    DOE PAGESBeta

    Gaulin, B. D.; Kermarrec, E.; Dahlberg, M. L.; Matthews, M. J.; Bert, F.; Zhang, J.; Mendels, P.; Fritsch, K.; Granroth, G. E.; Jiramongkolchai, P.; et al

    2015-06-01

    Solid-solutions of the "soft" quantum spin ice pyrochlore magnets Tb2B2O7 with B=Ti and Sn display a novel magnetic ground state in the presence of strong B-site disorder, characterized by a low susceptibility and strong spin fluctuations to temperatures below 0.1 K. These materials have been studied using ac-susceptibility and muSR techniques to very low temperatures, and time-of-flight inelastic neutron scattering techniques to 1.5 K. Remarkably, neutron spectroscopy of the Tb3+ crystal field levels appropriate to at high B-site mixing (0.5 < x < 1.5 in Tb2Sn2-xTixO7) reveal that the doublet ground and first excited states present as continua in energy,more » while transitions to singlet excited states at higher energies simply interpolate between those of the end members of the solid solution. The resulting ground state suggests an extreme version of a random-anisotropy magnet, with many local moments and anisotropies, depending on the precise local configuration of the six B sites neighboring each magnetic Tb3+ ion.« less

  3. Concentrations of arsenic, antimony, and boron in steam and steam condensate at The Geysers, California

    USGS Publications Warehouse

    Smith, C.L.; Ficklin, W.H.; Thompson, J.M.

    1987-01-01

    Studies at The Geysers Geothermal Field, California indicate that under some circumstances elements that are transported in the vapor phase can become enriched in the liquid phase. Waters from two condensate traps (steam traps) on steam lines at The Geysers are enriched with arsenic, antimony, and boron compared to the concentrations of these elements in coexisting steam. Concentrations of boron in condensate-trap waters were as high as 160 mg/L, arsenic as high as 35 mg/L, and antimony as high as 200 ??g/L. Enrichment of arsenic, antimony, and boron is at least partially controlled by the partitioning of these elements into the liquid phase, according to their vapor-liquid distribution coefficients, after they are transported in steam. Several of the elements that are most soluble in steam, including arsenic and antimony, are part of the trace-element suite that characterizes precious-metal epithermal ore deposits. ?? 1987.

  4. Varying duty operation of air-cooled condenser units

    NASA Astrophysics Data System (ADS)

    Milman, O. O.; Kondratev, A. V.; Ptakhin, A. V.; Dunaev, S. N.; Kirjukhin, A. V.

    2016-05-01

    Results of experimental investigations of operation modes of air-cooled condensers (ACC) under design and varying duty conditions are presented. ACCs with varying cooling airflow rates under constant heat load and with constant cooling airflow under varying heat load are examined. Diagrams of heat transfer coefficients and condensation pressures on the heat load and cooling airflow are obtained. It is found that, if the relative heat load is in the range from 0.6 to 1.0 of the nominal value, the ACC heat transfer coefficient varies insignificantly, unlike that of the water-cooled surface condensers. The results of the determination of "zero points" are given, i.e., the attainable pressure in air-cooled condensing units (ACCU), if there is no heat load for several values of working water temperature at the input of water-jet ejectors and liquid ring vacuum pump. The results of the experimental determination of atmospheric air suction into the ACC vacuum system. The effect of additional air suctions in the steam pipe on ACCU characteristics is analyzed. The thermal mapping of ACC heat exchange surfaces from the cooling air inlet is carried out. The dependence of the inefficient heat exchange zone on the additional air suction into the ACC vacuum system is given. It is shown that, if there is no additional air suction into the ACC vacuum system, the inefficient heat exchange zone is not located at the bottom of the first pass tubes, and their portion adjacent to the bottom steam pipe works efficiently. Design procedures for the ACC varying duty of capacitors are presented, and their adequacy for the ACCU varying duty estimation is analyzed.

  5. On Localized Vapor Pressure Gradients Governing Condensation and Frost Phenomena.

    PubMed

    Nath, Saurabh; Boreyko, Jonathan B

    2016-08-23

    Interdroplet vapor pressure gradients are the driving mechanism for several phase-change phenomena such as condensation dry zones, interdroplet ice bridging, dry zones around ice, and frost halos. Despite the fundamental nature of the underlying pressure gradients, the majority of studies on these emerging phenomena have been primarily empirical. Using classical nucleation theory and Becker-Döring embryo formation kinetics, here we calculate the pressure field for all possible modes of condensation and desublimation in order to gain fundamental insight into how pressure gradients govern the behavior of dry zones, condensation frosting, and frost halos. Our findings reveal that in a variety of phase-change systems the thermodynamically favorable mode of nucleation can switch between condensation and desublimation depending upon the temperature and wettability of the surface. The calculated pressure field is used to model the length of a dry zone around liquid or ice droplets over a broad parameter space. The long-standing question of whether the vapor pressure at the interface of growing frost is saturated or supersaturated is resolved by considering the kinetics of interdroplet ice bridging. Finally, on the basis of theoretical calculations, we propose that there exists a new mode of frost halo that is yet to be experimentally observed; a bimodal phase map is developed, demonstrating its dependence on the temperature and wettability of the underlying substrate. We hope that the model and predictions contained herein will assist future efforts to exploit localized vapor pressure gradients for the design of spatially controlled or antifrosting phase-change systems. PMID:27463696

  6. Convection, evaporation, and condensation of binary fluids in confined geometries

    NASA Astrophysics Data System (ADS)

    Grigoriev, Roman; Qin, Tongran; Li, Yaofa; Chan, Benjamin; Yoda, Minami

    2011-11-01

    Phase change has a major effect on convection in liquid layers with a free surface. Significant latent heat generated at the free surface as a result of phase change can dramatically alter the interfacial temperature, inducing thermocapillary stresses. For binary fluids, differential evaporation leads to a variation in the concentration, and hence, induces solutocapillary stresses. This talk describes numerical and experimental studies of convection in alcohol-water mixtures due to a horizontal temperature gradient in the presence of phase change. Evaporation and condensation is known to be a notoriously difficult problem to model due to a poorly defined vapor transport problem which is strongly influenced by the presence/absence and flows of non-condensable gases (e.g., air). This issue is addressed by using a sealed cuvette heated at one end and cooled at the other. Both numerics and experiments show that, by adding or removing air from the cuvette, the direction of flow in a liquid layer covering the bottom of the cell can be reversed by emphasizing either thermocapillary or solutocapillary stresses. Supported by ONR.

  7. Condensation of helium in aerogel and athermal dynamics of the random-field Ising model.

    PubMed

    Aubry, Geoffroy J; Bonnet, Fabien; Melich, Mathieu; Guyon, Laurent; Spathis, Panayotis; Despetis, Florence; Wolf, Pierre-Etienne

    2014-08-22

    High resolution measurements reveal that condensation isotherms of (4)He in high porosity silica aerogel become discontinuous below a critical temperature. We show that this behavior does not correspond to an equilibrium phase transition modified by the disorder induced by the aerogel structure, but to the disorder-driven critical point predicted for the athermal out-of-equilibrium dynamics of the random-field Ising model. Our results evidence the key role of nonequilibrium effects in the phase transitions of disordered systems. PMID:25192103

  8. Inhibition of Condensation Frosting by Arrays of Hygroscopic Antifreeze Drops.

    PubMed

    Sun, Xiaoda; Damle, Viraj G; Uppal, Aastha; Linder, Rubin; Chandrashekar, Sriram; Mohan, Ajay R; Rykaczewski, Konrad

    2015-12-29

    The formation of frost and ice can have negative impacts on travel and a variety of industrial processes and is typically addressed by dispensing antifreeze substances such as salts and glycols. Despite the popularity of this anti-icing approach, some of the intricate underlying physical mechanisms are just being unraveled. For example, recent studies have shown that in addition to suppressing ice formation within its own volume, an individual salt saturated water microdroplet forms a region of inhibited condensation and condensation frosting (RIC) in its surrounding area. This occurs because salt saturated water, like most antifreeze substances, is hygroscopic and has water vapor pressure at its surface lower than water saturation pressure at the substrate. Here, we demonstrate that for macroscopic drops of propylene glycol and salt saturated water, the absolute RIC size can remain essentially unchanged for several hours. Utilizing this observation, we demonstrate that frost formation can be completely inhibited in-between microscopic and macroscopic arrays of propylene glycol and salt saturated water drops with spacing (S) smaller than twice the radius of the RIC (δ). Furthermore, by characterizing condensation frosting dynamics around various hygroscopic drop arrays, we demonstrate that they can delay complete frosting over of the samples 1.6 to 10 times longer than films of the liquids with equivalent volume. The significant delay in onset of ice nucleation achieved by dispensing propylene glycol in drops rather than in films is likely due to uniform dilution of the drops driven by thermocapillary flow. This transport mode is absent in the films, leading to faster dilution, and with that facilitated homogeneous nucleation, near the liquid-air interface. PMID:26651017

  9. New strategy for the screening of lysosomal storage disorders: the use of the online trapping-and-cleanup liquid chromatography/mass spectrometry.

    PubMed

    la Marca, Giancarlo; Casetta, Bruno; Malvagia, Sabrina; Guerrini, Renzo; Zammarchi, Enrico

    2009-08-01

    The aim of this study was to set up a robust method suitable for large-scale studies (screening) with a minimized preparation process and with reduced running costs, for measuring five enzyme activities on dried blood spots by a new and simplified tandem mass spectrometry-based method. After incubation, all 5 reaction mixtures, carried out separately, were stopped, combined together, and centrifuged. The cleaning-up of the injected mixture was performed through a fast online trapping step preceding a liquid chromatography/tandem mass-spectrometry measurement. This method takes only 4 min as analysis run time and without any purification following the enzymatic reaction. We assessed the effectiveness of this approach in assaying the enzymatic activities on dried blood spots from 10 patients affected by "Pompe", 6 by "Gaucher", 12 by "Fabry", 3 by "Niemann-Pick" A/B, and 2 by "Krabbe" diseases. Reference values were established on 5000 healthy newborns and 300 healthy adults. All affected patients showed enzymatic activities below the normal range. In heterozygous carriers (18 for Fabry, 10 for Pompe, and 4 for Gaucher disease) the activities were slightly lower than in control subjects. The results show that the method set out in its simplicity, low costs, and low processes preparations can be fully applicable to a mass screening. PMID:19555116

  10. Cyclothymic disorder

    MedlinePlus

    ... It is a mild form of bipolar disorder (manic depressive illness), in which a person has mood swings over ... causes of cyclothymic disorder are unknown. Major depression, bipolar disorder, and cyclothymia often occur together in families. This ...

  11. TMJ Disorders

    MedlinePlus

    ... referred Sally and her parents to a local dentist who specialized in jaw disorders. After examining Sally ... having symptoms of a TMJ disorder, let your dentist know. The earlier a TMJ disorder is diagnosed ...

  12. Mental Disorders

    MedlinePlus

    ... disorders Psychotic disorders, including schizophrenia There are many causes of mental disorders. Your genes and family history ... Biological factors can also be part of the cause. A traumatic brain injury can lead to a ...

  13. Eating Disorders

    MedlinePlus

    ... Treatments and Therapies Join a Study Learn More Eating Disorders Definition There is a commonly held view that ... can lead to stroke or heart attack Binge-eating disorder People with binge-eating disorder lose control over ...

  14. Cerebellar Disorders

    MedlinePlus

    ... Problems with the cerebellum include Cancer Genetic disorders Ataxias - failure of muscle control in the arms and legs that result in movement disorders Degeneration - disorders caused by brain cells decreasing in ...

  15. Genetic Disorders

    MedlinePlus

    ... This can cause a medical condition called a genetic disorder. You can inherit a gene mutation from ... during your lifetime. There are three types of genetic disorders: Single-gene disorders, where a mutation affects ...

  16. Quenched crystal-field disorder and magnetic liquid ground states in Tb₂Sn2-xTixO₇

    SciTech Connect

    Gaulin, B. D.; Kermarrec, E.; Dahlberg, M. L.; Matthews, M. J.; Bert, F.; Zhang, J.; Mendels, P.; Fritsch, K.; Granroth, G. E.; Jiramongkolchai, P.; Amato, A.; Baines, C.; Cava, R. J.; Schiffer, P.

    2015-06-18

    Solid solutions of the “soft” quantum spin ice pyrochlore magnets Tb₂B₂O₇ with B = Ti and Sn display a novel magnetic ground state in the presence of strong B-site disorder, characterized by a low susceptibility and strong spin fluctuations to temperatures below 0.1 K. These materials have been studied using ac susceptibility and μSR techniques to very low temperatures, and time-of-flight inelastic neutron scattering techniques to 1.5 K. Remarkably, neutron spectroscopy of the Tb³⁺ crystal-field levels appropriate to high B-site mixing (0.5 < x < 1.5 in Tb₂Sn2-xTixO₇) reveal that the doublet ground and first excited states present as continua in energy, while transitions to singlet excited states at higher energies simply interpolate between those of the end members of the solid solution. The resulting ground state suggests an extreme version of a random-anisotropy magnet, with many local moments and anisotropies, depending on the precise local configuration of the six B sites neighboring each magnetic Tb³⁺ ion.

  17. Out-of-equilibrium processes in suspensions of oppositely charged colloids: liquid-to-crystal nucleation and gel formation

    NASA Astrophysics Data System (ADS)

    Sanz, Eduardo

    2009-03-01

    We study the kinetics of the liquid-to-crystal transformation and of gel formation in colloidal suspensions of oppositely charged particles. We analyse, by means of both computer simulations and experiments, the evolution of a fluid quenched to a state point of the phase diagram where the most stable state is either a homogeneous crystalline solid or a solid phase in contact with a dilute gas. On the one hand, at high temperatures and high packing fractions, close to an ordered-solid/disordered-solid coexistence line, we find that the fluid-to-crystal pathway does not follow the minimum free energy route. On the other hand, a quench to a state point far from the ordered-crystal/disordered-crystal coexistence border is followed by a fluid-to-solid transition through the minimum free energy pathway. At low temperatures and packing fractions we observe that the system undergoes a gas-liquid spinodal decomposition that, at some point, arrests giving rise to a gel-like structure. Both our simulations and experiments suggest that increasing the interaction range favors crystallization over vitrification in gel-like structures. [4pt] In collaboration with Chantal Valeriani, Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 5, 3584 CC Utrecht, The Netherlands and SUPA, School of Physics, University of Edinburgh, JCMB King's Buildings, Mayfield Road, Edinburgh EH9 3JZ, UK; Teun Vissers, Andrea Fortini, Mirjam E. Leunissen, and Alfons van Blaaderen, Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University; Daan Frenke, FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands and Department of Chemistry, University of Cambridge, Lensfield Road, CB2 1EW, Cambridge, UK; and Marjolein Dijkstra, Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University.

  18. Liquid Hydrogen Absorber for MICE

    SciTech Connect

    Ishimoto, S.; Suzuki, S.; Yoshida, M.; Green, Michael A.; Kuno, Y.; Lau, Wing

    2010-05-30

    Liquid hydrogen absorbers for the Muon Ionization Cooling Experiment (MICE) have been developed, and the first absorber has been tested at KEK. In the preliminary test at KEK we have successfully filled the absorber with {approx}2 liters of liquid hydrogen. The measured hydrogen condensation speed was 2.5 liters/day at 1.0 bar. No hydrogen leakage to vacuum was found between 300 K and 20 K. The MICE experiment includes three AFC (absorber focusing coil) modules, each containing a 21 liter liquid hydrogen absorber made of aluminum. The AFC module has safety windows to separate its vacuum from that of neighboring modules. Liquid hydrogen is supplied from a cryocooler with cooling power 1.5 W at 4.2 K. The first absorber will be assembled in the AFC module and installed in MICE at RAL.

  19. Gravitino condensation in fivebrane backgrounds

    NASA Astrophysics Data System (ADS)

    Kitazawa, Noriaki

    2002-04-01

    We calculate the tension of the D3-brane in the fivebrane background which is described by the exactly solvable SU(2)k×U(1) world-sheet conformal field theory with large Kač-Moody level k. The D3-brane tension is extracted from the amplitude of one closed string exchange between two parallel D3-branes, and the amplitude is calculated by utilizing the open-closed string duality. The tension of the D3-brane in the background does not coincide with the one in the flat space-time even in the flat space-time limit: k-->∞. The finite curvature effect should vanish in the flat space-time limit and only the topological effect can remain. Therefore, the deviation suggests the condensation of the gravitino and/or dilatino which has been expected in the fivebrane background as a gravitational instanton.

  20. Prebiotic condensation reactions using cyanamide

    NASA Technical Reports Server (NTRS)

    Sherwood, E.; Nooner, D. W.; Eichberg, J.; Epps, D. E.; Oro, J.

    1978-01-01

    Condensation reactions in cyanamide, 4-amino-5-imidazole-carboxamide and cyanamide, imidazole systems under dehydrating conditions at moderate temperatures (60 to 100 deg C) were investigated. The cyanamide, imidazole system was used for synthesis of palmitoylglycerols from ammonium palmitate and glycerol. With the addition of deoxythymidine to the former system, P1, P2-dideoxythymidine 5 prime-phosphate was obtained; the same cyanamide, 4-amino-5-imidazole-carboxamide system was used to synthesize deoxythymidine oligonucleotides using deoxythymidine 5 prime-phosphate and deoxythymidine 5 prime-triphosphate, and peptides using glycine, phenylalanine or isoleucine with adenosine 5 prime-triphosphate. The pH requirements for these reactions make their prebiotic significance questionable; however, it is conceivable that they could occur in stable pockets of low interlayer acidity in a clay such as montmorillonite.

  1. Transient nucleation in condensed systems

    NASA Technical Reports Server (NTRS)

    Kelton, K. F.; Greer, A. L.; Thompson, C. V.

    1983-01-01

    Using classical nucleation theory we consider transient nucleation occurring in a one-component, condensed system under isothermal conditions. We obtain an exact closed-form expression for the time dependent cluster populations. In addition, a more versatile approach is developed: a numerical simulation technique which models directly the reactions by which clusters are produced. This simulation demonstrates the evolution of cluster populations and nucleation rate in the transient regime. Results from the simulation are verified by comparison with exact analytical solutions for the steady state. Experimental methods for measuring transient nucleation are assessed, and it is demonstrated that the observed behavior depends on the method used. The effect of preexisting cluster distributions is studied. Previous analytical and numerical treatments of transient nucleation are compared to the solutions obtained from the simulation. The simple expressions of Kashchiev are shown to give good descriptions of the nucleation behavior.

  2. Magnetic levitation of condensed hydrogen

    NASA Technical Reports Server (NTRS)

    Paine, C. G.; Seidel, G. M.

    1991-01-01

    Liquid and solid molecular hydrogen has been levitated using a pair of small superconducting solenoids. The hydrogen samples, up to 3 mm in dimension, were trapped in a magnetic potential having either a discrete minimum or a minimum in the form of a ring 1 cm in diameter. The hydrogen could be moved about in the magnetic trap by applying an electric field.

  3. Competing interactions in population-imbalanced two-component Bose-Einstein condensates

    NASA Astrophysics Data System (ADS)

    Galteland, Peder Notto; Sudbø, Asle

    2016-08-01

    We consider a two-component Bose-Einstein condensate with and without synthetic "spin-orbit" interactions in two dimensions. Density and phase fluctuations of the condensate are included, allowing us to study the impact of thermal fluctuations and density-density interactions on the physics originating with spin-orbit interactions. In the absence of spin-orbit interactions, we find that intercomponent density interactions deplete the minority condensate. The thermally driven phase transition is driven by coupled density and phase-fluctuations, but is nevertheless shown to be a phase-transition in the Kosterlitz-Thouless universality class with close to universal amplitude ratios irrespective of whether both the minority- and majority condensates exist in the ground state, or only one condensate exists. In the presence of spin-orbit interactions we observe three separate phases, depending on the strength of the spin-orbit coupling and intercomponent density-density interactions: a phase-modulated phase with uniform amplitudes for small intercomponent interactions, a completely imbalanced, effectively single-component condensate for intermediate spin-orbit coupling strength and sufficiently large intercomponent interactions, and a phase-modulated and amplitude-modulated phase for sufficiently large values of both the spin-orbit coupling and the intercomponent density-density interactions. The phase that is modulated by a single q -vector only is observed to transition into an isotropic liquid through a strong depinning transition with periodic boundary conditions, which weakens with open boundaries.

  4. Radiative dark-bright instability and the critical Casimir effect in DQW exciton condensates

    NASA Astrophysics Data System (ADS)

    Hakioğlu, T.; Özgün, Ege

    2011-07-01

    It is already well known that radiative interband interaction in the excitonic normal liquid in semiconducting double quantum wells is responsible for a negligible splitting between the energies of the dark and bright excitons enabling us to consider a four fold spin degeneracy. This has also lead many workers to naively consider the same degeneracy in studying the condensate. On the other hand, the non-perturbative aspects of this interaction in the condensed phase, e.g. its consequences on the order parameter and the dark-bright mixture in the ground state have not been explored. In this work, we demonstrate that the ground state concentrations of the dark and the bright exciton condensates are dramatically different beyond a sharp interband coupling threshold where the contribution of the bright component in the ground state vanishes. This shows that the effect of the radiative interband interaction on the condensate is nonperturbative. We also observe in the free energy a discontinuous derivative with respect to the layer separation at the entrance to the condensed phase, indicating a strong critical Casimir force. An estimate of its strength shows that it is measurable. Measuring the Casimir force is challenging, but at the same time it has a conclusive power about the presence of the long sought for condensed phase.

  5. Molecular attraction of condensed bodies

    NASA Astrophysics Data System (ADS)

    Derjaguin, B. V.; Abrikosova, I. I.; Lifshitz, E. M.

    2015-09-01

    From the Editorial Board. As a contribution to commemorating the 100th anniversary of the birth of Evgenii Mikhailovich Lifshitz, it was found appropriate by the Editorial Board of Uspekhi Fizicheskikh Nauk (UFN) [Physics-Uspekhi] journal that the materials of the jubilee-associated Scientific Session of the Physical Sciences Division of the Russian Academy of Sciences published in this issue (pp. 877-905) be augmented by the review paper "Molecular attraction of condensed bodies" reproduced from a 1958 UFN issue. Included in this review, in addition to an account by Evgenii Mikhailovich Lifshitz of his theory of molecular attractive forces between condensed bodies (first published in Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki (ZhETF) in 1955 and in its English translation Journal of Experimental and Theoretical Physics (JETP) in 1956), is a summary of a series of experimental studies beginning in 1949 by Irina Igorevna Abrikosova at the Institute of Physical Chemistry of the Academy of Sciences of the USSR in a laboratory led by Boris Vladimirovich Derjaguin (1902-1994), a Corresponding Member of the USSR Academy of Sciences. In 1958, however, UFN was not yet available in English translation, so the material of the review is insufficiently accessible to the present-day English-speaking reader. This is the reason why the UFN Editorial Board decided to contribute to celebrating the 100th anniversary of E M Lifshitz's birthday by reproducing on the journal's pages a 1958 review paper which contains both E M Lifshitz's theory itself and the experimental data that underpinned it (for an account of how Evgenii Mikhailovich Lifshitz was enlisted to explain the experimental results of I I Abrikosova and B V Derjaguin, see the letter to the editors N P Danilova on page 925 of this jubilee collection of publications).

  6. Slowing dynamics in supercooled liquids and other soft materials

    NASA Astrophysics Data System (ADS)

    Yardimci, Hasan

    The slow structural dynamics displayed by supercooled liquids and the transition to an out-of-equilibrium glass state that they engender are among the most challenging issues in condensed matter physics. This thesis reports experimental studies designed to elucidate central aspects of these slow dynamics and the nature of the glass state. The subjects of these studies include glass forming molecular liquids and other soft materials that have been advanced as model glassy systems such as clay suspensions and block copolymer micelle solutions. The main experimental techniques employed in these investigations have been dielectric susceptibility and neutron scattering. In the first half of this thesis, we report frequency-dependent dielectric susceptibility measurements characterizing the evolution in the dynamical properties, or aging, of two supercooled liquids, sorbitol and xylitol, quenched below their calorimetric glass transition temperatures, Tg. In addition to the alpha relaxation that tracks the structural dynamics, the susceptibilities of both liquids possess a secondary Johari-Goldstein relaxation at higher frequencies. Following a quench below Tg, the susceptibility slowly approaches equilibrium behavior. For both liquids features of the Johari-Goldstein relaxation display a dependence on the time since the quench, or aging time, that is very similar to the age dependence of the alpha peak. Implications of these findings for aging in glasses and the nature of Johari-Goldstein relaxation are discussed. Further investigation of the aging in sorbitol reveals that it displays memory strikingly similar to that of a variety of glassy materials, particularly spin glasses. During a temporary stop in cooling, the susceptibility changes with time due to aging. The memory is revealed upon reheating as the susceptibility retraces these changes. To investigate the out-of-equilibrium state of the liquid as it displays this memory, we have employed a set of intricate

  7. Can hydrodynamic contact line paradox be solved by evaporation-condensation?

    PubMed

    Janeček, V; Doumenc, F; Guerrier, B; Nikolayev, V S

    2015-12-15

    We investigate a possibility to regularize the hydrodynamic contact line singularity in the configuration of partial wetting (liquid wedge on a solid substrate) via evaporation-condensation, when an inert gas is present in the atmosphere above the liquid. The no-slip condition is imposed at the solid-liquid interface and the system is assumed to be isothermal. The mass exchange dynamics is controlled by vapor diffusion in the inert gas and interfacial kinetic resistance. The coupling between the liquid meniscus curvature and mass exchange is provided by the Kelvin effect. The atmosphere is saturated and the substrate moves at a steady velocity with respect to the liquid wedge. A multi-scale analysis is performed. The liquid dynamics description in the phase-change-controlled microregion and visco-capillary intermediate region is based on the lubrication equations. The vapor diffusion is considered in the gas phase. It is shown that from the mathematical point of view, the phase exchange relieves the contact line singularity. The liquid mass is conserved: evaporation existing on a part of the meniscus and condensation occurring over another part compensate exactly each other. However, numerical estimations carried out for three common fluids (ethanol, water and glycerol) at the ambient conditions show that the characteristic length scales are tiny. PMID:26348659

  8. Phonological disorder

    MedlinePlus

    Articulation disorder; Developmental articulation disorder; Speech distortion; Sound distortion ... unknown. Close relatives may have had speech and language problems. ... sounds. These changes may include cleft palate and problems ...

  9. Tongue Disorders

    MedlinePlus

    ... more, written in everyday language. Home Mouth and Dental Disorders Lip and Tongue Disorders Burning Mouth Syndrome Causes Symptoms Diagnosis Treatment Lip Changes and Discoloration Lip Inflammation Lip ...

  10. Panic disorder

    MedlinePlus

    ... Anxiety disorder - panic attacks References American Psychiatric Association. Diagnostic and statistical manual of mental disorders . 5th ed. Arlington, VA: American Psychiatric Publishing. 2013. ...

  11. Some effects of non-condensible gas in geothermal reservoirs with steam-water counterflow

    SciTech Connect

    McKibbin, R.; Pruess, K.

    1988-01-01

    A mathematical model is developed for fluid and heat flow in two-phase geothermal reservoirs containing non-condensible gas (CO{sub 2}). Vertical profiles of temperature, pressures and phase saturations in steady-state conditions are obtained by numerically integrating the coupled ordinary differential equations describing conservation of water, CO{sub 2}, and energy. Solutions including binary diffusion effects in the gas phase are generated for cases with net mass throughflow as well as for balanced liquid-vapor counterflow. Calculated examples illustrate some fundamental characteristics of two-phase heat transmission systems with non-condensible gas. 14 refs., 3 figs.

  12. Some effects of non-condensible gas in geothermal reservoirs with steam-water counterflow

    SciTech Connect

    McKibbin, Robert; Pruess, Karsten

    1988-01-01

    A mathematical model is developed for fluid and heat flow in two-phase geothermal reservoirs containing non-condensible gas (CO{sub 2}). Vertical profiles of temperature, pressures and phase saturations in steady-state conditions are obtained by numerically integrating the coupled ordinary differential equations describing conservation of water, CO{sub 2}, and energy. Solutions including binary diffusion effects in the gas phase are generated for cases with net mass throughflow as well as for balanced liquid-vapor counterflow. Calculated examples illustrate some fundamental characteristics of two-phase heat transmission systems with non-condensible gas.

  13. Bose-Einstein-condensate heating by atomic losses

    SciTech Connect

    Dziarmaga, Jacek; Sacha, Krzysztof

    2003-10-01

    Atomic Bose-Einstein condensate is heated by atomic losses. The losses act as a heat reservoir for the condensate. The condensate is approaching a state of thermal equilibrium with a thermal depletion ranging from 1% for a uniform three-dimensional (3D) condensate to around 13% for a quasi-1D condensate in a harmonic trap.

  14. Asymmetric avalanches in the condensate of a Zeeman-limited superconductor

    NASA Astrophysics Data System (ADS)

    Prestigiacomo, J. C.; Liu, T. J.; Adams, P. W.

    2014-11-01

    We report the nonequilibrium behavior of disordered superconducting Al films in high Zeeman fields. We have measured the tunneling density of states of the films through the first-order Zeeman critical field transition. We find that films with sheet resistances of a few hundred ohms exhibit large avalanchelike collapses of the condensate on the superheating branch of the critical field hysteresis loop. In contrast, the transition back into the superconducting phase (i.e., along the supercooling branch) is always continuous. The fact that the condensate follows an unstable trajectory to the normal state suggests that the order parameter in the hysteretic regime is not homogeneous.

  15. Quantum metrology with Bose-Einstein condensates

    SciTech Connect

    Boixo, Sergio; Datta, Animesh; Davis, Matthew J.; Flammia, Steven T.; Shaji, Anil; Tacla, Alexandre B.; Caves, Carlton M.

    2009-04-13

    We show how a generalized quantum metrology protocol can be implemented in a two-mode Bose-Einstein condensate of n atoms, achieving a sensitivity that scales better than 1/n and approaches 1/n{sup 3/2} for appropriate design of the condensate.

  16. Alignment and tolerancing of a cardioid condenser

    NASA Astrophysics Data System (ADS)

    Prince, S. M.; McGuigan, W. G.

    2007-09-01

    Design details of a cardioid dark field condenser are shown ranging from the theoretical performance of a cardioid to the best-fit spherical surface. The manufacturing tolerances, fabrication techniques and debug methods are discussed for this condenser. The primary tolerances to be achieved are center thickness of the cardioid element and maintenance of its center of curvature relative to the focal plane.

  17. Fragmentation of Bose-Einstein condensates

    NASA Astrophysics Data System (ADS)

    Mueller, Erich J.; Ho, Tin-Lun; Ueda, Masahito; Baym, Gordon

    2006-09-01

    We present the theory of bosonic systems with multiple condensates, providing a unified description of various model systems that are found in the literature. We discuss how degeneracies, interactions, and symmetries conspire to give rise to this unusual behavior. We show that as degeneracies multiply, so do the varieties of fragmentation, eventually leading to strongly correlated states with no trace of condensation.

  18. Hydrophilic structures for condensation management in appliances

    DOEpatents

    Kuehl, Steven John; Vonderhaar, John J.; Wu, Guolian; Wu, Mianxue

    2016-02-02

    An appliance that includes a cabinet having an exterior surface; a refrigeration compartment located within the cabinet; and a hydrophilic structure disposed on the exterior surface. The hydrophilic structure is configured to spread condensation. The appliance further includes a wicking structure located in proximity to the hydrophilic structure, and the wicking structure is configured to receive the condensation.

  19. Soliton resonance in bose-einstein condensate

    NASA Technical Reports Server (NTRS)

    Zak, Michail; Kulikov, I.

    2002-01-01

    A new phenomenon in nonlinear dispersive systems, including a Bose-Einstein Condensate (BEC), has been described. It is based upon a resonance between an externally induced soliton and 'eigen-solitons' of the homogeneous cubic Schrodinger equation. There have been shown that a moving source of positive /negative potential induces bright /dark solitons in an attractive / repulsive Bose condensate.

  20. Collision of Bose Condensate Dark Matter structures

    SciTech Connect

    Guzman, F. S.

    2008-12-04

    The status of the scalar field or Bose condensate dark matter model is presented. Results about the solitonic behavior in collision of structures is presented as a possible explanation to the recent-possibly-solitonic behavior in the bullet cluster merger. Some estimates about the possibility to simulate the bullet cluster under the Bose Condensate dark matter model are indicated.

  1. Dual condensate and QCD phase transition

    SciTech Connect

    Zhang Bo; Bruckmann, Falk; Fodor, Zoltan; Szabo, Kalman K.; Gattringer, Christof

    2011-05-23

    The dual condensate is a new QCD phase transition order parameter, which connnects confinement and chiral symmetry breaking as different mass limits. We discuss the relation between the fermion spectrum at general boundary conditions and the dual condensate and show numerical results for the latter from unquenched SU(3) lattice configurations.

  2. Estimates of abundance of vapor condensate from the impacts of asteroids and comets on the Moon

    NASA Astrophysics Data System (ADS)

    Svetsov, Vladimir; Shuvalov, Valery

    The hypervelocity impacts of asteroids and comets on the Moon and planets can vaporize a substantial mass of target rock comparable with the mass of a projectile. The vapor expands, forming a vapor plume, and, when it cools and reaches the liquid-vapor coexistence curve, molten spherules can condense from the vapor. Ejecta layers bearing condensate spherules have been found on the Earth along with melt droplet spherules, however, the impact-vapor condensate is extremely rare among the lunar samples. The current average impact velocities on the Moon and Earth differ only slightly, and the main distinction is probably that the vapor plume expands to the atmosphere on the Earth and into vacuum on the Moon. Using available ANEOS equations of states for quartz and dunite we have determined parameters behind shock waves for impact velocities from 9 to 30 km/s and calculated release adiabats from various points on the Hugoniot curves to very low pressures. For impacts of quartz projectiles on quartz targets at velocities 9-16 km/s the release adiabats come to the liquid branch of the two-phase curve and, during the following expansion of two-phase mixture, the shock-compressed material vaporizes and does not condense. The condensate can appear during the plume expansion only at higher impact velocities. Using our hydrocode SOVA, we have made numerical simulations of the impacts of quartz and dunite spherical projectiles on the targets from the same materials. Along with the masses of condensates we calculated the masses of melted material. The calculated ratio of vaporized mass to the melted mass proved to be of the order of 0.1. However, we obtained that at velocities below 20 km/s the condensate mass is only a small fraction of vapor and melt masses and, consequently, the major part of vapor disperses in vacuum in the form of separate molecules. At impact velocity 15 km/s the relative abundance of silicate condensates is 0.001 - 0.0001 in accordance with the studies of

  3. Silicate impact-vapor condensate on the Moon: Theoretical estimates versus geochemical data

    NASA Astrophysics Data System (ADS)

    Svetsov, Vladimir V.; Shuvalov, Valery V.

    2016-01-01

    We numerically simulated the impacts of asteroids and comets on the Moon in order to calculate the amount of condensate that can be formed after the impacts and compare the results with data for lunar samples. Using available equations of state for quartz and dunite, we have determined pressure and density behind shock waves in these materials for particle velocities from 4 to 20 km/s and obtained release adiabats from various points on the Hugoniot curves to very low pressures. For shock waves with particle velocities behind the front below 8 km/s the release adiabats intersect the liquid branch of the two-phase curve and, during the following expansion, the liquid material vaporizes and does not condense, forming a two-phase mixture of melt and vapor. The condensate can appear during expansion of material compressed by a shock with higher (>8 km/s) velocities. Using our hydrocode SOVA, we have conducted numerical simulations of the impacts of spherical quartz, dunite, and water-ice projectiles into targets of the same materials. Impact velocities were 15-25 km/s for stony projectiles and 20-70 km/s for icy impactors, and impact angles were 45°and 90° to the target surface. Along with the masses of condensates we calculated the masses of vaporized and melted material. Upon the impact of a projectile consisting of dunite into a target of quartz at a speed of 20 km/s at an angle of 45°, vaporized and melted masses of the target are equal to 1.6 and 11 in units of projectile mass, respectively, and the mass of condensate is 0.19. Vaporized and condensed masses of the projectile are 0.16 and 0.02, more than 80% of the projectile mass is melted. The calculated ratio of vaporized to melted mass proved to be on the order of 0.1. However, we calculated that, at impact velocities below 20 km/s, the condensate mass is only a small fraction of the vaporized and melted masses and, consequently, the major part of vapor disperses in vacuum in the form of separate molecules

  4. Preliminary design of condenser cleansing schedule

    SciTech Connect

    Warberg, J.; Foraker, E.K.; Civera, A.G.; Daley, M.L.

    1995-04-01

    Analysis of the operations of a fossil power plant for a 5-year period revealed a year-round trend of operating inefficiently due to elevated condenser back pressure, particularly during the summer months. A further 5-month longitudinal study between May and September of an individual condenser unit revealed a positive correlation between increasing inlet-circulating water temperature and above-design condenser back pressure. Moreover, condenser cleansing resulted in a return to approximately the design operating condition. A physical analysis of increased heat-rate and lost power generation from inefficient condenser back pressure was accomplished. Based on these observations and economic analysis, a preliminary cleansing schedule for periods of increasing circulating water temperature was derived. Further studies are planned to validate the proposed cleansing schedule.

  5. Panic Disorder among Adults

    MedlinePlus

    ... Hyperactivity Disorder Among Children Autism Spectrum Disorder (ASD) Eating Disorders Among Adults - Anorexia Nervosa Eating Disorders Among Adults - Binge Eating Disorder Eating Disorders Among ...

  6. Any Personality Disorder

    MedlinePlus

    ... Hyperactivity Disorder Among Children Autism Spectrum Disorder (ASD) Eating Disorders Among Adults - Anorexia Nervosa Eating Disorders Among Adults - Binge Eating Disorder Eating Disorders Among ...

  7. Antisocial Personality Disorder

    MedlinePlus

    ... Hyperactivity Disorder Among Children Autism Spectrum Disorder (ASD) Eating Disorders Among Adults - Anorexia Nervosa Eating Disorders Among Adults - Binge Eating Disorder Eating Disorders Among ...

  8. Bipolar Disorder Among Adults

    MedlinePlus

    ... Hyperactivity Disorder Among Children Autism Spectrum Disorder (ASD) Eating Disorders Among Adults - Anorexia Nervosa Eating Disorders Among Adults - Binge Eating Disorder Eating Disorders Among ...

  9. Borderline Personality Disorder

    MedlinePlus

    ... Hyperactivity Disorder Among Children Autism Spectrum Disorder (ASD) Eating Disorders Among Adults - Anorexia Nervosa Eating Disorders Among Adults - Binge Eating Disorder Eating Disorders Among ...

  10. Unexpected manifestation of quark condensation

    SciTech Connect

    Zinovjev, G. M.; Molodtsov, S. V.

    2015-05-15

    A comparative analysis of some quark ensembles governed by a four-fermion interaction is performed. Arguments in support of the statement that the presence of a gas-liquid phase transition is a feature peculiar to them are adduced. The instability of small quark droplets is discussed and is attributed to the formation of a chiral soliton. The stability of baryon matter is due to a mixed phase of the vacuum and baryon matter.

  11. Atomic partial charges in condensed phase from an exact sum rule for infrared absorption

    NASA Astrophysics Data System (ADS)

    Vuilleumier, Rodolphe

    2014-05-01

    A general sum rule for infrared intensities provides a definition of effective partial charges which can be experimentally obtained using isotopic substitutions and is valid in both gas and condensed phases. Of particular interest is the case of molecular liquids. We have, therefore, determined the hydrogen partial charges in liquid methanol and liquid water from the available literature. The resulting charges are 0.63 e and 0.14 e for hydrogen atoms bounded to the methanol oxygen and carbon atoms, respectively, and 0.55 e for hydrogen atoms in liquid water. The effective partial charges in liquid water were also computed from density functional based ab initio molecular dynamics simulations and found in good agreement with experiment.

  12. Personality Disorders

    MedlinePlus

    ... this page You are here Home » Personality Disorder Personality Disorder What is “Personality?” Personality refers to a distinctive set of traits, ... family, friends, and co-workers. What is a Personality Disorder? Those who struggle with a personality disorder ...

  13. 26. DETAIL VIEW OF MARISCAL WORKS CONDENSER STACK, THE END ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    26. DETAIL VIEW OF MARISCAL WORKS CONDENSER STACK, THE END OF THE CONDENSING SYSTEM, REUSED BY VIVIANNA WORKS AS THE END OF THEIR CONDENSING SYSTEM, LOOKING SOUTHWEST. - Mariscal Quicksilver Mine & Reduction Works, Terlingua, Brewster County, TX

  14. DETAIL VIEW OF MARISCAL WORKS CONDENSER STACK, THE END OF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    DETAIL VIEW OF MARISCAL WORKS CONDENSER STACK, THE END OF THE CONDENSING SYSTEM, REUSED BY VIVIANNA WORKS AS THE END OF THEIR CONDENSING SYSTEM, LOOKING SOUTHWEST. - Mariscal Quicksilver Mine & Reduction Works, Terlingua, Brewster County, TX

  15. Floating Loop System For Cooling Integrated Motors And Inverters Using Hot Liquid Refrigerant

    DOEpatents

    Hsu, John S [Oak Ridge, TN; Ayers, Curtis W [Kingston, TN; Coomer, Chester [Knoxville, TN; Marlino, Laura D [Oak Ridge, TN

    2006-02-07

    A floating loop vehicle component cooling and air-conditioning system having at least one compressor for compressing cool vapor refrigerant into hot vapor refrigerant; at least one condenser for condensing the hot vapor refrigerant into hot liquid refrigerant by exchanging heat with outdoor air; at least one floating loop component cooling device for evaporating the hot liquid refrigerant into hot vapor refrigerant; at least one expansion device for expanding the hot liquid refrigerant into cool liquid refrigerant; at least one air conditioning evaporator for evaporating the cool liquid refrigerant into cool vapor refrigerant by exchanging heat with indoor air; and piping for interconnecting components of the cooling and air conditioning system.

  16. Black holes in the ghost condensate

    SciTech Connect

    Mukohyama, Shinji

    2005-05-15

    We investigate how the ghost condensate reacts to black holes immersed in it. A ghost condensate defines a hypersurface-orthogonal congruence of timelike curves, each of which has the tangent vector u{sup {mu}}=-g{sup {mu}}{sup {nu}}{partial_derivative}{sub {nu}}{phi}. It is argued that the ghost condensate in this picture approximately corresponds to a congruence of geodesics. In other words, the ghost condensate accretes into a black hole just like a pressureless dust. Correspondingly, if the energy density of the ghost condensate at large distance is set to an extremely small value by cosmic expansion then the late-time accretion rate of the ghost condensate should be negligible. The accretion rate remains very small even if effects of higher derivative terms are taken into account, provided that the black hole is sufficiently large. It is also discussed how to reconcile the black-hole accretion with the possibility that the ghost condensate might behave like dark matter.

  17. Critical condensate saturation in porous media

    SciTech Connect

    Wang, X.; Mohanty, K.K.

    1999-06-15

    The understanding of gas and condensate flow in porous media is critical to the optimum exploitation of gas-condensate reservoirs. Critical condensate saturation and relative permeabilities are the key parameters for the evaluation of possible recovery strategies. This work is aimed at developing a mechanistic network model for the critical condensate saturation in which phase trapping and connectivity in the pore corners are critically examined. Porous media are modeled by networks of pore bodies interconnected by pore throats. Bodies and throats are characterized by their connectivity, shapes, and radii distributions. Pore-level laws are identified from micromodel experiments with near-critical fluids. A nonzero critical condensate saturation can be obtained in the absence of contact angle hysteresis due to the converging-diverging nature of the throats. The critical saturation at which the condensate flows is found to be a function of pore geometry, water saturation, and interfacial tension (or the Bond number). The modified sphere-pack model underpredicts the critical condensate saturation of typical sandstones. The cubic model adequately predicts the critical saturation and its experimentally observed trends.

  18. Condenser on-line fouling monitor

    SciTech Connect

    Tsou, J.L.; Garey, J.F.; Wiebe, D.H.

    1994-12-31

    Biological and/or chemical fouling in utility condensers is a major cause of reduced efficiency and substantially affects availability and increases operational costs. Performance losses due to water side fouling are difficult to measure and, usually, quantitative assessment of the economic impact of condenser fouling is impossible. Plant operators typically examine steam backpressure and perform complex calculations for condenser cleanliness. These direct estimates are often imprecise due to inadequate instrumentation. In addition, these data provide information on overall condenser performance which may be influenced by a number of parameters which are independent of water side fouling. Indirect (side-stream) methods are also used to isolate/measure biological or chemical fouling in condensers. This approach is extremely useful to document site/seasonal fouling rates, and for the simultaneous evaluation of treatment options. In collaboration with the Electric Power Research Institute, instrumentation has been developed which meets requirements for the direct, on-line measurement of condenser fouling. This monitor may be installed in any location within the condenser, does not interfere with routine plant operations, including on-line mechanical and chemical treatment methods, and provides continuous, real-time readings of the heat transfer efficiency of the instrumented tube. Three prototype assemblies were installed at the New England Power Company, Brayton Point Generating Station in 1993. This paper discusses the design, construction, preliminary test results, and subsequent data collected in 1994 with a redesigned system.

  19. Diquark Bose-Einstein condensation

    SciTech Connect

    Nawa, K.; Nakano, E.; Yabu, H.

    2006-08-01

    Bose-Einstein condensation of composite diquarks in quark matter (the color superconductor phase) is discussed using the quasichemical equilibrium theory at a relatively low-density region near the deconfinement phase transition, where dynamical quark-pair fluctuations are assumed to be described as bosonic degrees of freedom (diquarks). A general formulation is given for the diquark formation and particle-antiparticle pair-creation processes in the relativistic framework, and some interesting properties are shown, which are characteristic for the relativistic many-body system. Behaviors of transition temperature and phase diagram of the quark-diquark matter are generally presented in model parameter space, and their asymptotic behaviors are also discussed. As an application to the color superconductivity, the transition temperatures and the quark and diquark density profiles are calculated in case with constituent/current quarks, where the diquark is in the bound/resonant state. We obtained T{sub C}{approx}60-80 MeV for constituent quarks and T{sub C}{approx}130 MeV for current quarks at a moderate density ({rho}{sub b}{approx}3{rho}{sub 0}). The method is also developed to include interdiquark interactions into the quasichemical equilibrium theory within a mean-field approximation, and it is found that a possible repulsive diquark-diquark interaction lowers the transition temperature by {approx}50%.

  20. Condensation Processes in Astrophysical Environments

    NASA Technical Reports Server (NTRS)

    Nuth, Joseph A., III; Rietmeijer, Frans J. M.; Hill, Hugh G. M.

    2002-01-01

    Astrophysical systems present an intriguing set of challenges for laboratory chemists. Chemistry occurs in regions considered an excellent vacuum by laboratory standards and at temperatures that would vaporize laboratory equipment. Outflows around Asymptotic Giant Branch (AGB) stars have timescales ranging from seconds to weeks depending on the distance of the region of interest from the star and, on the way significant changes in the state variables are defined. The atmospheres in normal stars may only change significantly on several billion-year timescales. Most laboratory experiments carried out to understand astrophysical processes are not done at conditions that perfectly match the natural suite of state variables or timescales appropriate for natural conditions. Experimenters must make use of simple analog experiments that place limits on the behavior of natural systems, often extrapolating to lower-pressure and/or higher-temperature environments. Nevertheless, we argue that well-conceived experiments will often provide insights into astrophysical processes that are impossible to obtain through models or observations. This is especially true for complex chemical phenomena such as the formation and metamorphism of refractory grains under a range of astrophysical conditions. Data obtained in our laboratory has been surprising in numerous ways, ranging from the composition of the condensates to the thermal evolution of their spectral properties. None of this information could have been predicted from first principals and would not have been credible even if it had.