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Sample records for lng vapor dispersion

  1. A dispersion safety factor for LNG vapor clouds.

    PubMed

    Vílchez, Juan A; Villafañe, Diana; Casal, Joaquim

    2013-02-15

    The growing importance of liquefied natural gas (LNG) to global energy demand has increased interest in the possible hazards associated with its storage and transportation. Concerning the event of an LNG spill, a study was performed on the relationship between the distance at which the lower flammability limit (LFL) concentration occurs and that corresponding to the visible contour of LNG vapor clouds. A parameter called the dispersion safety factor (DSF) has been defined as the ratio between these two lengths, and two expressions are proposed to estimate it. During an emergency, the DSF can be a helpful parameter to indicate the danger of cloud ignition and flash fire. PMID:23305750

  2. CFD Modeling of LNG Spill: Humidity Effect on Vapor Dispersion

    NASA Astrophysics Data System (ADS)

    Giannissi, S. G.; Venetsanos, A. G.; Markatos, N.

    2015-09-01

    The risks entailed by an accidental spill of Liquefied Natural Gas (LNG) should be indentified and evaluated, in order to design measures for prevention and mitigation in LNG terminals. For this purpose, simulations are considered a useful tool to study LNG spills and to understand the mechanisms that influence the vapor dispersion. In the present study, the ADREA-HF CFD code is employed to simulate the TEEX1 experiment. The experiment was carried out at the Brayton Fire Training Field, which is affiliated with the Texas A&M University system and involves LNG release and dispersion over water surface in open- obstructed environment. In the simulation the source was modeled as a two-phase jet enabling the prediction of both the vapor dispersion and the liquid pool spreading. The conservation equations for the mixture are solved along with the mass fraction for natural gas. Due to the low prevailing temperatures during the spill ambient humidity condenses and this might affect the vapor dispersion. This effect was examined in this work by solving an additional conservation equation for the water mass fraction. Two different models were tested: the hydrodynamic equilibrium model which assumes kinetic equilibrium between the phases and the non hydrodynamic equilibrium model, in order to assess the effect of slip velocity on the prediction. The slip velocity is defined as the difference between the liquid phase and the vapor phase and is calculated using the algebraic slip model. Constant droplet diameter of three different sizes and a lognormal distribution of the droplet diameter were applied and the results are discussed and compared with the measurements.

  3. LNG fire and vapor control system technologies

    SciTech Connect

    Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

    1982-06-01

    This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

  4. FEM3A simulations of selected LNG vapor barrier verification field tests

    SciTech Connect

    Chan, S.T.

    1990-10-01

    In order to evaluate and eventually predict the possible mitigating effects of vapor fences on the dispersion of the vapor cloud resulting from an accidental liquefied natural gas (LNG) spill in storage areas, a research program was initiated to evaluate methods for predicting LNG dispersion distances for realistic facility configurations. As part of the program, Lawrence Livermore National Laboratory (LLNL) conducted a series of large-scale field experiments called the LNG Vapor Barrier Verification Field Trials (also referred to as the Falcon Series) at the Liquefied Gaseous Fuels Spill Test Facility (LGFSTF), Nevada. Objectives were (1) to provide a data base on LNG vapor dispersion from spill involving complex field obstacles to assist in validation of wind tunnel and mathematical models, and (2) to assess the effectiveness of vapor fences for mitigating LNG vapor dispersion hazards in the events of an accidental spill. Five spill experiments were conducted on water in order to generate vapor at rates equivalent to the liquid spill rates. In this study, the FEM3A model was applied to simulate four of the Falcon experiments. The objectives of this study were, through numerical modeling and a detailed model-data comparison: (1) to improve our understanding of LNG vapor dispersion involving vapor barriers, (2) to assess FEM3A in modeling such complex vapor dispersion scenarios, and (3) to complement the results of field and wind tunnel tests, such as providing plausible explanations for unexpected results and filling in data gaps due to instrument failure or limited array size. Toward these goals, the relevant field measurements were analyzed and several series of 2-D and 3-D simulations were carried out. 11 refs., 93 figs., 11 tabs.

  5. Coyote series data report LLNL/NWC 1981 LNG spill tests dispersion, vapor burn, and rapid-phase-transition. Volume 1. [7 experiments with liquefied natural gas, 2 with liquid methane, and one with liquid nitrogen

    SciTech Connect

    Goldwire, H.C. Jr.; Rodean, H.C.; Cederwall, R.T.; Kansa, E.J.; Koopman, R.P.; McClure, J.W.; McRae, T.G.; Morris, L.K.; Kamppinen, L.; Kiefer, R.D.

    1983-10-01

    The Coyote series of liquefied natural gas (LNG) spill experiments was performed at the Naval Weapons Center (NWC), China Lake, California, during the summer and fall of 1981. These tests were a joint effort of the Lawrence Livermore National Laboratory (LLNL) and the NWC and were sponsored by the US Department of Energy (DOE) and the Gas Research Institute. There were ten Coyote experiments, five primarily for the study of vapor dispersion and burning vapor clouds, and five for investigating the occurrence of rapid-phase-transition (RPT) explosions. Each of the last four of the five RPT tests consisted of a series of three spills. Seven experiments were with LNG, two were with liquid methane (LCH/sub 4/), and one was with liquid nitrogen (LN/sub 2/). Three arrays of instrumentation were deployed. An array of RPT diagnostic instruments was concentrated at the spill pond and was operated during all of the tests, vapor burn as well as RPT. The wind-field array was operated during the last nine experiments to define the wind direction and speed in the area upwind and downwind of the spill pond. The gas-dispersion array was deployed mostly downwind of the spill pond to measure gas concentration, humidity, temperature, ground heat flux, infrared (IR) radiation, and flame-front passage during three of the vapor dispersion and burn experiments (Coyotes 3, 5, and 6). High-speed color motion pictures were taken during every test, and IR imagery (side and overhead) was obtained during some vapor-burn experiments. Data was obtained by radiometers during Coyotes 3, 6, and 7. This report presents a comprehensive selection of the data obtained. It does not include any data analysis except that required to determine the test conditions and the reliability of the data. Data analysis is to be reported in other publications. 19 references, 76 figures, 13 tables.

  6. Thermoelectric Power Conversion System Combined with LNG Vaporizer

    NASA Astrophysics Data System (ADS)

    Kambe, Mitsuru; Morita, Ryo; Omoto, Kazuyuki; Koji, Yasuhiro; Yoshida, Tatsuo; Noishiki, Koji

    A conceptual design of the thermoelectric power conversion system combined with open rack type LNG (liquefied natural gas) vaporizer to make use of cold heat of LNG is presented. The system performance analysis has been made based on the thermoelectric module performance data obtained at the cryogenic thermoelectric (CTE) test rig which could realize temperature and fluid dynamic condition of the open rack type LNG vaporizer. Conventional bismuth-telluride thermoelectric modules were tested, however, each module is encapsulated in the stainless steel container to achieve water proof. Electricity production cost evaluation of the system is also discussed.

  7. Four band differential radiometer for monitoring LNG vapors

    NASA Astrophysics Data System (ADS)

    Simmonds, J. J.

    1981-06-01

    The development by JPL of a four band differential radiometer (FBDR) which is capable of providing a fast rate of response, accurate measurements of methane, ethane, and propane concentrations on the periphery of a dispersing LNG cloud. The FBDR is a small, low power, lightweight, portable instrument system that uses differential absorption of near infrared radiation by the LNG cloud as a technique for the determination of concentration of the three gases as the LNG cloud passes the instrument position. Instrument design and data analysis approaches are described. The data obtained from the FBDR prototype instrument system deployed in an instrument array during two 40 cubic meter spill tests are discussed.

  8. Four band differential radiometer for monitoring LNG vapors

    NASA Technical Reports Server (NTRS)

    Simmonds, J. J.

    1981-01-01

    The development by JPL of a four band differential radiometer (FBDR) which is capable of providing a fast rate of response, accurate measurements of methane, ethane, and propane concentrations on the periphery of a dispersing LNG cloud. The FBDR is a small, low power, lightweight, portable instrument system that uses differential absorption of near infrared radiation by the LNG cloud as a technique for the determination of concentration of the three gases as the LNG cloud passes the instrument position. Instrument design and data analysis approaches are described. The data obtained from the FBDR prototype instrument system deployed in an instrument array during two 40 cubic meter spill tests are discussed.

  9. The theoretical analysis of the Fog removal in the LNG Ambient Vaporizer

    NASA Astrophysics Data System (ADS)

    Lee, T.; Lee, D.; Jeong, H.; Chung, H.

    2015-09-01

    The fog removal process is one of the important process in LNG Ambient Vaporizer. In this study we carried out theoretical study of the fog removal process in LNG Ambient Vaporizer. The LNG Ambient Vaporizer in Incheon area was used in our study. The fog temperature and the required energy produced from air fan to remove fog in LNG Ambient Vaporizer were calculated using average temperature of Incheon area in 2012 by Psychometruc Chart method. As a result we can be remove fog in LNG Ambient Vaporizer using Enthalpy[kW] energy in summer season and Enthalpy[kW] in winter season respectively.

  10. Atmospheric Dispersion about a Heavy Gas Vapor Detention System.

    NASA Astrophysics Data System (ADS)

    Shin, Seong-Hee

    Dispersion of liquefied natural gas (LNG) in the event of an accidental spill is a major concern in LNG storage and transport safety planning, hazard response, and facility siting. Falcon Series large scale LNG spill experiments were planned by Lawrence Livermore National Laboratory (LLNL) for the Department of Transportation (DOT) and the Gas Research Institute (GRI) as part of a joint government/industry study in 1987 to evaluate the effectiveness of vapor fences as a mitigating technique for accidental release of LNG and to assist in validating wind tunnel and numerical methods for vapor dispersion simulation. Post-field-spill wind-tunnel experiments were performed in Environmental Wind Tunnel (EWT) (1988, 1989) to augment the LNG Vapor Fence Program data obtained during the Falcon Test Series. The program included four different model length scales and two different simulant gases. The purpose of this program is to provide a basis for the analysis of the simulation of physical modeling tests using proper physical modeling techniques and to assist in the development and verification of analytical models. Field data and model data were compared and analyzed by surface pattern comparisons and statistical methods. A layer-averaged slab model developed by Meroney et al. (1988) (FENC23) was expanded to evaluate an enhanced entrainment model proposed for dense gas dispersion including the effect of vapor barriers, and the numerical model was simulated for Falcon tests without the fence and with the vapor fence to examine the effectiveness of vapor detention system on heavy gas dispersion. Model data and the field data were compared with the numerical model data, and degree of similarity between data were assessed.

  11. Vapor burn analysis for the Coyote series LNG spill experiments

    SciTech Connect

    Rodean, H.C.; Hogan, W.J.; Urtiew, P.A.; Goldwire, H.C. Jr.; McRae, T.G.; Morgan, D.L. Jr.

    1984-04-01

    A major purpose of the Coyote series of field experiments at China Lake, California, in 1981 was to study the burning of vapor clouds from spills of liquefied natural gas (LNG) on water. Extensive arrays of instrumentation were deployed to obtain micrometeorological, gas concentration, and fire-related data. The instrumentation included in situ sensors of various types, high-speed motion picture cameras, and infrared (IR) imagers. Five of the total of ten Coyote spill experiments investigated vapor burns. The first vapor-burn experiment, Coyote 2, was done with a small spill of LNG to assess instrument capability and survivability in vapor cloud fires. The emphasis in this report is on the other four vapor-burn experiments: Coyotes 3, 5, 6, and 7. The data are analyzed to determine fire spread, flame propagation, and heat flux - quantities that are related to the determination of the damage zone for vapor burns. The results of the analyses are given here. 20 references, 57 figures, 7 tables.

  12. Numerical simulation of the mitigating effects of an LNG vapor fence

    SciTech Connect

    Chan, S.T.

    1990-05-01

    FEM3A, a fully three-dimensional numerical model for simulating the atmospheric dispersion of heavy gases involving complex geometry, has been used to investigate the mitigating effects of a vapor fence for LNG storage areas. In this paper, a brief description of the numerical model used to perform such calculations is given, the problem being simulated is described, and an intercomparison among the results from numerical simulations (with and without the vapor fence) and field data (with vapor fence) is made. The numerical results indicate that, with the present fence configuration, the maximum concentration on the cloud centerline was reduced by a factor of two or more within 250 m behind the fence, and the downwind distance to the 2.5% concentration was reduced from 365 m to 230 m. However, a vapor fence could also cause the vapor cloud to linger considerably longer in the source area, thus increasing the potential for ignition and combustion within the vapor fence and the area nearby over time. 8 refs., 10 figs.

  13. Cost-benefit analysis of alternative LNG vapor-mitigation measures. Topical report, September 14, 1987-January 15, 1991

    SciTech Connect

    Atallah, S.

    1992-06-25

    A generalized methodology is presented for comparing the costs and safety benefits of alternative hazard mitigation measures for a large LNG vapor release. The procedure involves the quantification of the risk to the public before and after the application of LNG vapor mitigation measures. In the study, risk was defined as the product of the annual accident frequency, estimated from a fault tree analysis, and the severity of the accident. Severity was measured in terms of the number of people who may be exposed to 2.5% or higher concentration. The ratios of the annual costs of the various mitigation measures to their safety benefits (as determined by the differences between the risk before and after mitigation measure implementation), were then used to identify the most cost-effective approaches to vapor cloud mitigation.

  14. Falcon series data report: 1987 LNG vapor barrier verification field trials

    SciTech Connect

    Brown, T.C.; Cederwall, R.T.; Chan, S.T.; Ermak, D.L.; Koopman, R.P.; Lamson, K.C.; McClure, J.W.; Morris, L.K.

    1990-06-01

    A series of five Liquefied Natural Gas Spills up to 66 m{sup 3} in volume were performed on water within a vapor barrier structure at Frenchman Flat on the Nevada Test Site as a part of a joint government/industry study. This data report presents a description of the tests, the test apparatus, the instrumentation, the meteorological conditions, and the data from the tests. 16 refs., 27 figs., 8 tabs.

  15. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Dispersion Model.” Alternatively, in order to account for additional cloud dilution which may be caused by... if it can be shown that the terrain both upwind and downwind of the vapor cloud has dense vegetation and that the vapor cloud height is more than ten times the height of the obstacles encountered by...

  16. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Dispersion Model.” Alternatively, in order to account for additional cloud dilution which may be caused by... if it can be shown that the terrain both upwind and downwind of the vapor cloud has dense vegetation and that the vapor cloud height is more than ten times the height of the obstacles encountered by...

  17. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Dispersion Model.” Alternatively, in order to account for additional cloud dilution which may be caused by... if it can be shown that the terrain both upwind and downwind of the vapor cloud has dense vegetation and that the vapor cloud height is more than ten times the height of the obstacles encountered by...

  18. LNG SAFETY RESEARCH: FEM3A MODEL DEVELOPMENT

    SciTech Connect

    Jerry Havens; Iraj A. Salehi

    2005-05-10

    The objective of this report is to develop the FEM3A model for application to general scenarios involving dispersion problems with obstacles and terrain features of realistic complexity, and for very low wind speed, stable weather conditions as required for LNG vapor dispersion application specified in 49 CFR 193. The dispersion model DEGADIS specified in 49 CFR 193 is limited to application for dispersion over smooth, level terrain free of obstacles (such as buildings, tanks, or dikes). There is a need for a dispersion model that allows consideration of the effects of terrain features and obstacles on the dispersion of LNG vapor clouds. Project milestones are: (1) Simulation of Low-Wind-Speed Stable Atmospheric Milestones Conditions; (2) Verification for Dispersion over Rough Surfaces, With And Without Obstacles; and (3) Adapting the FEM3A Model for General Application. Results for this quarter are work continues to underway to address numerical problems during simulation of low-wind-speed, stable, atmospheric conditions with FEM3A. Steps 1 and 2 in the plan outlined in the first Quarterly report are complete and steps 3 and 4 are in progress. During this quarter, we have been investigating the effect upon numerical stability of the heat transfer model used to predict the surface-to-cloud heat transfer, which can be important for LNG vapor dispersion. Previously, no consideration has been given to ground cooling as a result of heat transfer to the colder gas cloud in FEM3A. The present effort is directed to describing the ground surface temperature decrease as a function of time.

  19. Lessons learned from LNG safety research.

    PubMed

    Koopman, Ronald P; Ermak, Donald L

    2007-02-20

    During the period from 1977 to 1989, the Lawrence Livermore National Laboratory (LLNL) conducted a liquefied gaseous fuels spill effects program under the sponsorship of the US Department of Energy, Department of Transportation, Gas Research Institute and others. The goal of this program was to develop and validate tools that could be used to predict the effects of a large liquefied gas spill through the execution of large scale field experiments and the development of computer models to make predictions for conditions under which tests could not be performed. Over the course of the program, three series of LNG spill experiments were performed to study cloud formation, dispersion, combustion and rapid phase transition (RPT) explosions. The purpose of this paper is to provide an overview of this program, the lessons learned from 12 years of research as well as some recommendations for the future. The general conclusion from this program is that cold, dense gas related phenomena can dominate the dispersion of a large volume, high release rate spill of LNG especially under low ambient wind speed and stable atmospheric conditions, and therefore, it is necessary to include a detailed and validated description of these phenomena in computer models to adequately predict the consequences of a release. Specific conclusions include: * LNG vapor clouds are lower and wider than trace gas clouds and tend to follow the downhill slope of terrain due to dampened vertical turbulence and gravity flow within the cloud. Under low wind speed, stable atmospheric conditions, a bifurcated, two lobed structure develops. * Navier-Stokes models provide the most complete description of LNG dispersion, while more highly parameterized Lagrangian models were found to be well suited to emergency response applications. * The measured heat flux from LNG vapor cloud burns exceeded levels necessary for third degree burns and were large enough to ignite most flammable materials. * RPTs are of two

  20. Electrodeless-discharge-vapor-lamp-based Faraday anomalous-dispersion optical filter.

    PubMed

    Sun, Qinqing; Zhuang, Wei; Liu, Zhiwen; Chen, Jingbiao

    2011-12-01

    We report an excited-state Faraday anomalous-dispersion optical filter operating on the rubidium 5P(3/2)-5D(5/2) transition (775.9 nm in vacuum) without the use of a pump laser. An electrodeless discharge vapor lamp is employed to replace the Rb vapor cell in a traditional Faraday anomalous-dispersion optical filter system. Atoms can be excited by power rather than a complex frequency-locked pump laser. A proof-of-concept experimental demonstration with a maximum transmission of 1.9% and a filter bandwidth of 650 MHz is presented. PMID:22139259

  1. Cost estimate for a proposed GDF Suez LNG testing program

    SciTech Connect

    Blanchat, Thomas K.; Brady, Patrick Dennis; Jernigan, Dann A.; Luketa, Anay Josephine; Nissen, Mark R.; Lopez, Carlos; Vermillion, Nancy; Hightower, Marion Michael

    2014-02-01

    At the request of GDF Suez, a Rough Order of Magnitude (ROM) cost estimate was prepared for the design, construction, testing, and data analysis for an experimental series of large-scale (Liquefied Natural Gas) LNG spills on land and water that would result in the largest pool fires and vapor dispersion events ever conducted. Due to the expected cost of this large, multi-year program, the authors utilized Sandia's structured cost estimating methodology. This methodology insures that the efforts identified can be performed for the cost proposed at a plus or minus 30 percent confidence. The scale of the LNG spill, fire, and vapor dispersion tests proposed by GDF could produce hazard distances and testing safety issues that need to be fully explored. Based on our evaluations, Sandia can utilize much of our existing fire testing infrastructure for the large fire tests and some small dispersion tests (with some modifications) in Albuquerque, but we propose to develop a new dispersion testing site at our remote test area in Nevada because of the large hazard distances. While this might impact some testing logistics, the safety aspects warrant this approach. In addition, we have included a proposal to study cryogenic liquid spills on water and subsequent vaporization in the presence of waves. Sandia is working with DOE on applications that provide infrastructure pertinent to wave production. We present an approach to conduct repeatable wave/spill interaction testing that could utilize such infrastructure.

  2. 46 CFR 154.1854 - Methane (LNG) as fuel.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Methane (LNG) as fuel. 154.1854 Section 154.1854... STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1854 Methane (LNG) as fuel. (a) If methane (LNG) vapors are used as fuel in the main propulsion system of a vessel,...

  3. 46 CFR 154.1854 - Methane (LNG) as fuel.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Methane (LNG) as fuel. 154.1854 Section 154.1854... STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1854 Methane (LNG) as fuel. (a) If methane (LNG) vapors are used as fuel in the main propulsion system of a vessel,...

  4. 46 CFR 154.1854 - Methane (LNG) as fuel.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Methane (LNG) as fuel. 154.1854 Section 154.1854... STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1854 Methane (LNG) as fuel. (a) If methane (LNG) vapors are used as fuel in the main propulsion system of a vessel,...

  5. 46 CFR 154.1854 - Methane (LNG) as fuel.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Methane (LNG) as fuel. 154.1854 Section 154.1854... STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1854 Methane (LNG) as fuel. (a) If methane (LNG) vapors are used as fuel in the main propulsion system of a vessel,...

  6. 46 CFR 154.1854 - Methane (LNG) as fuel.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Methane (LNG) as fuel. 154.1854 Section 154.1854... STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Operations § 154.1854 Methane (LNG) as fuel. (a) If methane (LNG) vapors are used as fuel in the main propulsion system of a vessel,...

  7. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Flammable vapor-gas dispersion protection. 193.2059 Section 193.2059 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY LIQUEFIED NATURAL GAS FACILITIES:...

  8. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Flammable vapor-gas dispersion protection. 193.2059 Section 193.2059 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY LIQUEFIED NATURAL GAS FACILITIES:...

  9. LNG SAFETY RESEARCH: FEM3A MODEL DEVELOPMENT

    SciTech Connect

    Jerry Havens; Iraj A. Salehi

    2005-02-21

    This quarterly report for DE-FG26-04NT42030 covers a period from October 1, 2004 to December 31, 2004. On December 9, 2004 a meeting was held in Morgantown to rescope the LNG safety modeling project such that the work would complement the DOE's efforts relative to the development of the intended LNG-Fluent model. It was noted and discussed at the December 9th meeting that the fundamental research being performed on surface to cloud heat transfer and low wind speed issues will be relevant to the development of the DOE LNG/Fluent Model. In general, it was decided that all research to be performed from December 9th through the remainder of the contract is to be focused on the development of the DOE LNG/Fluent model. In addition, all GTI activities for dissemination and transfer of FEM3A will cease and dissemination activities will focus on the new DOE LNG/Fluent model. The proposed new scope of work is presented in section 4 of this report. The work reported in the present document relates to the original scope of work which was in effect during the reporting period. The future work will be re-scoped to meet the requirements of the new scope of work. During the report period work was underway to address numerical problems present during simulation of low-wind-speed, stable, atmospheric conditions with FEM3A. Steps 1 and 2 in the plan outlined in the first Quarterly report are complete and steps 3 and 4 are in progress. During this quarter, the University of Arkansas has been investigating the effect upon numerical stability of the heat transfer model used to predict the surface-to-cloud heat transfer, which can be important for LNG vapor dispersion. Previously, no consideration has been given to ground cooling as a result of heat transfer to the colder gas cloud in FEM3A.

  10. Vaporization, dispersion, and radiant fluxes from LPG spills. Final technical report

    SciTech Connect

    Not Available

    1982-05-01

    Both burning and non-burning spills of LPG (primarily propane) were studied. Vaporization rates for propane spills on soil, concrete, insulating concrete, asphalt, sod, wood, and polymer foams were measured. Thermal conductivity, heat transfer coefficients, and steady state vaporization rates were determined. Vapor concentrations were measured downwind of open propane pools and a Gaussian dispersion model modified for area sources provided a good correlation of measured concentrations. Emitted and incident radiant fluxes from propane fires were measured. Simplified flame radiation models were adequate for predicting radiant fluxes. Tests in which propane was sprayed into the air showed that at moderately high spray rates all the propane flashed to vapor or atomized; no liquid collected on the ground.

  11. Dispersion of flammable vapor clouds resulting from large spills of liquid hydrogen

    NASA Technical Reports Server (NTRS)

    Witcofski, R. D.

    1981-01-01

    The purpose of this paper is to report the preliminary findings of hydrogen vapor cloud dispersion experiments conducted by NASA. The experiments were performed to obtain basic information regarding the physical phenomena governing the dispersion of flammable clouds formed as the result of spills of large quantities of liquid hydrogen. The experiments consisted of ground spills of up to 5.7 cubic meters (1500 gal) of liquid hydrogen, with spill durations of approximately 35 seconds. Instrumented towers, located downwind of the spill site, gather data on the temperature, hydrogen concentration, and turbulence levels as the hydrogen vapor cloud drifted downwind. Visual phenomena were recorded by motion picture and still cameras. Preliminary results of the experiments indicate that, for rapid spills, thermal and momentum induced turbulences cause the cloud to disperse to safe concentration levels and become positively buoyant long before mixing due to normal atmospheric turbulence becomes a major factor.

  12. Vapor Liquid Equilibria of Hydrofluorocarbons Using Dispersion-Corrected and Nonlocal Density Functionals.

    PubMed

    Goel, Himanshu; Butler, Charles L; Windom, Zachary W; Rai, Neeraj

    2016-07-12

    Recent developments in dispersion corrected and nonlocal density functionals are aimed at accurately capturing dispersion interactions, a key shortcoming of local and semilocal approximations of density functional theory. These functionals have shown significant promise for dimers and small clusters of molecules as well as crystalline materials. However, their efficacy for predicting vapor liquid equilibria is largely unexplored. In this work, we examine the accuracy of dispersion-corrected and nonlocal van der Waals functionals by computing the vapor liquid coexistence curves (VLCCs) of hydrofluoromethanes. Our results indicate that the PBE-D3 functional performs significantly better in predicting saturated liquid densities than the rVV10 functional. With the PBE-D3 functional, we also find that as the number of fluorine atoms increase in the molecule, the accuracy of saturated liquid density prediction improves as well. All the functionals significantly underpredict the saturated vapor densities, which also result in an underprediction of saturated vapor pressure of all compounds. Despite the differences in the bulk liquid densities, the local microstructures of the liquid CFH3 and CF2H2 are relatively insensitive to the density functional employed. For CF3H, however, rVV10 predicts slightly more structured liquid than the PBE-D3 functional. PMID:27295451

  13. Dispersion studies of the 22 GHz water vapor line shape. II - Instrumental correction.

    NASA Technical Reports Server (NTRS)

    Dillon, T. A.; Liebe, H. J.

    1971-01-01

    Anomalies in the resonance dispersion of the pressure-broadened water vapor line at a frequency of 22.235 GHz are resolved. The pressure-scanning differential-refraction spectrometer gives rise to a signal enhancement as the line center moves within the width of the dispersion discriminator. Resonance absorption prevents the frequency of peak transmitted power from coinciding with the resonance condition of zero phase. The results reported for the 23.6 GHz rotational line of ethylene oxide show a Lorentzian molecular line shape.

  14. Endosulfan transport: II. Modeling airborne dispersal and deposition by spray and vapor.

    PubMed

    Raupach, M R; Briggs, P R; Ahmad, N; Edge, V E

    2001-01-01

    Endosulfan (C9H6O3Cl6S; 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepin 3-oxide) and other agricultural chemicals can be transported from farms to rivers by several airborne pathways including spray drift and vapor transport. This paper describes a modeling framework for quantifying both of these airborne pathways, consisting of components describing the source, dispersion, and deposition phases of each pathway. Throughout, the framework uses economical descriptions consistent with the need to capture the major physical processes. The dispersion of spray and vapor is described by similarity and mass-conservation principles approximated by Gaussian solutions. Deposition of particles to vegetation is described by a single-layer model incorporating contributions from settling, impaction, and Brownian diffusion. Vapor deposition to water surfaces is described by a simple kinetic formulation dependent on an exchange velocity. All model components are tested against available field and laboratory data. The models, and the measurements used for comparisons, both demonstrate that spray drift and vapor transport are significant pathways. The broader context, described in another paper, is an integrative assessment of all transport pathways (both airborne and waterborne) contributing to endosulfan transport from farms to rivers. PMID:11401262

  15. Curves to determine the relative importance of advection and dispersion for solute and vapor transport

    USGS Publications Warehouse

    Garges, J.A.; Baehr, A.L.

    1998-01-01

    The relative importance of advection and dispersion for both solute and vapor transport can be determined from type curves or concentration, flux, or cumulative flux. The dimensionless form of the type curves provides a means to directly evaluate the importance of mass transport by advection relative to that of mass transport by diffusion and dispersion. Type curves based on an analytical solution to the advection-dispersion equation are plotted in terms of dimensionless time and Peclet number. Flux and cumulative flux type curves provide additional rationale for transport regime determination in addition to the traditional concentration type curves. The extension of type curves to include vapor transport with phase partitioning in the unsaturated zone is a new development. Type curves for negative Peclet numbers also are presented. A negative Peclet number characterizes a problem in which one direction of flow is toward the contamination source, and thereby diffusion and advection can act in opposite directions. Examples are the diffusion of solutes away from the downgradient edge of a pump-and-treat capture zone, the upward diffusion of vapors through the unsaturated zone with recharge, and the diffusion of solutes through a low hydraulic conductivity cutoff wall with an inward advective gradient.

  16. Research on energy efficiency design index for sea-going LNG carriers

    NASA Astrophysics Data System (ADS)

    Lin, Yan; Yu, Yanyun; Guan, Guan

    2014-12-01

    This paper describes the characteristics of liquefied natural gas (LNG) carriers briefly. The LNG carrier includes power plant selection, vapor treatment, liquid cargo tank type, etc. Two parameters—fuel substitution rate and recovery of boil of gas (BOG) volume to energy efficiency design index (EEDI) formula are added, and EEDI formula of LNG carriers is established based on ship EEDI formula. Then, based on steam turbine propulsion device of LNG carriers, mathematical models of LNG carriers' reference line value are established in this paper. By verification, the EEDI formula of LNG carriers described in this paper can provide a reference for LNG carrier EEDI calculation and green shipbuilding.

  17. Determination of the dispersion constant in a constrained vapor bubble thermosyphon

    NASA Technical Reports Server (NTRS)

    Dasgupta, Sunando; Plawsky, Joel L.; Wayner, Peter C., Jr.

    1995-01-01

    The isothermal profiles of the extended meniscus in a quartz cuvette were measured in a gravitational field using an image analyzing interferometer which is based on computer enhanced video microscopy of the naturally occurring interference fringes. The experimental results for heptane and pentane menisci were analyzed using the extended Young Laplace Equation. These isothermal results characterized the interfacial force field in-siru at the start of the heat transfer experiments by quantifying the dispersion constant, which is a function of the liquid-solid system and cleaning procedures. The experimentally obtained values of the disjoining pressure and the dispersion constants were compared to that predicted from the DLP theory and good agreements were obtained. The measurements are critical to the subsequent non-isothermal experiments because one of the major variables in the heat sink capability of the Constrained Vapor Bubble Thermosyphon, CVBT, is the dispersion constant. In all previous studies of micro heat pipes the value of the dispersion constant has been 'estimated'. One of the major advantages of the current glass cell is the ability to view the extended meniscus at all times. Experimentally, we find that the extended Young-Laplace Equation is an excellent model for the force field at the solid-liquid-vapor interfaces.

  18. Pressure drop in fully developed, duct flow of dispersed liquid-vapor mixture at zero gravity

    NASA Technical Reports Server (NTRS)

    Sridhar, K. R.; Chao, B. T.; Soo, S. L.

    1990-01-01

    The dynamics of steady, fully developed dispersed liquid-vapor flow in a straight duct at 0-g is simulated by flowing water containing n-butyl benzoate droplets. Water and benzoate are immiscible and have identical density at room temperature. The theoretical basis of the simulation is given. Experiments showed that, for a fixed combined flow rate of water and benzoate, the frictional pressure drop is unaffected by large changes in the volume fraction of benzoate drops and their size distribution. Measured power spectra of the static wall pressure fluctuations induced by the turbulent water-benzoate flow also revealed that their dynamics is essentially unaltered by the presence of the droplets. These experimental findings, together with the theoretical analysis, led to the conclusion that the pressure drop in fully developed, dispersed liquid-vapor flow in straight ducts of constant cross section at 0-g is identical to that due to liquid flowing alone at the same total volumetric flow rate of the liquid-vapor mixture and, therefore, can be readily determined.

  19. Determination of the dispersion constant in a constrained vapor bubble thermosyphon

    NASA Technical Reports Server (NTRS)

    Dasgupta, SUNANDO.; Plawsky, Joel L.; Wayner, Peter C., Jr.

    1993-01-01

    The isothermal profiles of the extended meniscus in a quartz cuvette were measured in a gravitational field using an image analyzing interferometer which is based on computer enhanced video microscopy of the naturally occurring interference fringes. The experimental results for heptane and pentane menisci were analyzed using the extended Young-Laplace equation. These isothermal results characterized the interfacial force field in-situ at the start of the heat transfer experiments by quantifying the dispersion constant, which is a function of the liquid-solid system and cleaning procedures. The experimentally obtained values of the disjoining pressure and the dispersion constants were compared to that predicted from the DLP theory and good agreements were obtained. The measurements are critical to the subsequent non-isothermal experiments because one of the major variables in the heat sink capability of the CVBT is the dispersion constant. In all previous studies of micro heat pipes the value of the dispersion constant has been 'guesstimated'. One of the major advantages of the current glass cell is the ability to view the extended meniscus at all times. Experimentally. we find that the extended Young-Laplace equation is an excellent model for the force field at the solid-liquid-vapor interfaces.

  20. Heavy Gas Dispersion Incompressible Flow

    Energy Science and Technology Software Center (ESTSC)

    1992-01-27

    FEM3 is a numerical model developed primarily to simulate heavy gas dispersion in the atmosphere, such as the gravitational spread and vapor dispersion that result from an accidental spill of liquefied natural gas (LNG). FEM3 solves both two and three-dimensional problems and, in addition to the generalized anelastic formulation, includes options to use either the Boussinesq approximation or an isothermal assumption, when appropriate. The FEM3 model is composed of three parts: a preprocessor PREFEM3, themore » main code FEM3, and two postprocessors TESSERA and THPLOTX.« less

  1. Exergy of LNG regasification - possible utilization method. Case study of LNG - ANG coupling

    NASA Astrophysics Data System (ADS)

    Roszak, E. A.; Chorowski, M.

    2014-01-01

    This article gives an overview on new exergy recovery methods for LNG. The concept is based on coupling the LNG regasification unit with the filling process of Adsorbed Natural Gas (ANG) tanks. The latent heat of the LNG vaporization is directly used for precooling the ANG adsorption bed. This reduces the back pressure from filling ANG tanks due to strong adsorption temperature dependency. This improves the economic attractiveness of ANG storage (no need for compressors, longer lifetime cycle of adsorbent). This case study presents the concept of LNG - ANG coupling. Presented results are based on experimental adsorption data. A brief exergy analysis of the process shows an advantage of this method over others. This LNG-ANG method is worth consideration as a cost optimizing solution, especially for periodically working regasification stations.

  2. Dispersion of seed vapor and gas ionization in an MHD second stage combustor and channel

    SciTech Connect

    Chang, S.L.; Lottes, S.A.; Bouillard, J.X.

    1992-07-01

    An approach is introduced for the simulation of a magnetohydrodynamic system consisting of a second stage combustor, a convergent nozzle, and a channel. The simulation uses an Argonne integral combustion flow computer code and another Argonne channel computer code to predict flow, thermal and electric properties in the seed particle laden reacting flow in the system. The combustion code is a general hydrodynamics computer code for two-phase, two-dimensional, turbulent, and reacting flows, based on mass, momentum, and energy conservation laws for gaseous and condensed phases. The channel code is a multigrid three-dimensional computer code for compressible flow subject to magnetic and electric interactions. Results of this study suggests that (1) the processes of seed particle evaporation, seed vapor dispersion, and gas ionization in the reacting flow are critical to the evaluation of the downstream channel performance and (2) particle size, loading, and inlet profile have strong effects on wall deposition and plasma temperature development.

  3. Dispersion of seed vapor and gas ionization in an MHD second stage combustor and channel

    SciTech Connect

    Chang, S.L.; Lottes, S.A.; Bouillard, J.X.

    1992-01-01

    An approach is introduced for the simulation of a magnetohydrodynamic system consisting of a second stage combustor, a convergent nozzle, and a channel. The simulation uses an Argonne integral combustion flow computer code and another Argonne channel computer code to predict flow, thermal and electric properties in the seed particle laden reacting flow in the system. The combustion code is a general hydrodynamics computer code for two-phase, two-dimensional, turbulent, and reacting flows, based on mass, momentum, and energy conservation laws for gaseous and condensed phases. The channel code is a multigrid three-dimensional computer code for compressible flow subject to magnetic and electric interactions. Results of this study suggests that (1) the processes of seed particle evaporation, seed vapor dispersion, and gas ionization in the reacting flow are critical to the evaluation of the downstream channel performance and (2) particle size, loading, and inlet profile have strong effects on wall deposition and plasma temperature development.

  4. Highly Dispersed Gold Nanoparticles Supported on SBA-15 for Vapor Phase Aerobic Oxidation of Benzyl Alcohol.

    PubMed

    Kumar, Ashish; Sreedhar, Bojja; Chary, Komandur V R

    2015-02-01

    Gold nanoparticles supported on SBA-15 are prepared by homogenous deposition-precipitation method (HDP) using urea as the precipitating agent. The structural features of the synthesized catalysts were characterized by various techniques such as X-ray diffraction (XRD), transmission electron microscopy (TEM), nitrogen adsorption-desorption (BET), pore size distribution (PSD), CO chemisorption and X-ray photoelectron spectroscopy (XPS). The catalytic activity and stability of the Au/SBA-15 catalysts are investigated during the vapor phase aerobic oxidation of benzyl alcohol. The BJH pore size distribution results of SBA-15 support and Au/SBA-15 catalysts reveals that the formation of mesoporous structure in all the samples. TEM results suggest that Au nanoparticles are highly dispersed over SBA-15 and long range order of hexagonal mesopores of SBA-15 is well retained even after the deposition of Au metallic nanoparticles. XPS study reveals the formation of Au (0) after chemical reduction by NaBH4. The particle size measured from CO-chemisorption and TEM analysis are well correlated with the TOF values of the reaction. Au/SBA-1 5 catalysts are found to show higher activity compare to Au/TiO2 and Au/MgO catalysts during the vapor phase oxidation of benzyl alcohol. The catalytic functionality are well substantiated with particle size measured from TEM. The crystallite size of Au in both fresh and spent catalysts were measured from X-ray diffraction. PMID:26353720

  5. Two-way shift of wavelength in holographic sensing of organic vapor in nanozeolites dispersed acrylamide photopolymer.

    PubMed

    Mao, Dongyao; Geng, Yaohui; Liu, Hongpeng; Zhou, Ke; Xian, Lihong; Yu, Dan

    2016-08-10

    Holographic sensing of alcohol organic vapor is characterized in detail at transmission and reflection geometries in Y nanozeolites dispersed acrylamide photopolymer. The two-way shift of the diffraction spectrum and its temporal evolution with various vapor concentrations are measured. Obvious blueshifts of diffraction spectrum peaks are observed and analyzed in two recording geometries. The competition mechanism between decreasing the average refractive index and swelling the grating fringe space is proposed for exploring the wavelength shift mechanism. In the reflection grating, as organic vapor increases, the redshift after the blueshift of the wavelength peaks are observed clearly. We further demonstrate the significance of this competition mechanism. In the low concentration region, at transmission <700  ppm and reflection <400  ppm in nanozeolites dispersed polymer, the blueshift of the wavelength is a significant factor in identifying an organic vapor with a low refractive index. These experimental results provide a probability for improving the applicability of a holographic sensor. This work can accelerate the development of the holographic sensing strategy and provide a novel identification method for organic vapor. PMID:27534461

  6. Comparative safety analysis of LNG storage tanks

    SciTech Connect

    Fecht, B.A.; Gates, T.E.; Nelson, K.O.; Marr, G.D.

    1982-07-01

    LNG storage tank design and response to selected release scenarios were reviewed. The selection of the scenarios was based on an investigation of potential hazards as cited in the literature. A review of the structure of specific LNG storage facilities is given. Scenarios initially addressed included those that most likely emerge from the tank facility itself: conditions of overfill and overflow as related to liquid LNG content levels; over/underpressurization at respective tank vapor pressure boundaries; subsidence of bearing soil below tank foundations; and crack propagation in tank walls due to possible exposure of structural material to cryogenic temperatures. Additional scenarios addressed include those that result from external events: tornado induced winds and pressure drops; exterior tank missile impact with tornado winds and rotating machinery being the investigated mode of generation; thermal response due to adjacent fire conditions; and tank response due to intense seismic activity. Applicability of each scenario depended heavily on the specific tank configurations and material types selected. (PSB)

  7. Vapor spill pipe monitor

    NASA Astrophysics Data System (ADS)

    Bianchini, G. M.; McRae, T. G.

    1983-06-01

    The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote IR gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote IR sensor which measures the gas composition.

  8. Vapor spill pipe monitor

    DOEpatents

    Bianchini, G.M.; McRae, T.G.

    1983-06-23

    The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

  9. LNG systems for natural gas propelled ships

    NASA Astrophysics Data System (ADS)

    Chorowski, M.; Duda, P.; Polinski, J.; Skrzypacz, J.

    2015-12-01

    In order to reduce the atmospheric pollution generated by ships, the International Marine Organization has established Emission Controlled Areas. In these areas, nitrogen oxides, sulphur oxides and particulates emission is strongly controlled. From the beginning of 2015, the ECA covers waters 200 nautical miles from the coast of the US and Canada, the US Caribbean Sea area, the Baltic Sea, the North Sea and the English Channel. From the beginning of 2020, strong emission restrictions will also be in force outside the ECA. This requires newly constructed ships to be either equipped with exhaust gas cleaning devices or propelled with emission free fuels. In comparison to low sulphur Marine Diesel and Marine Gas Oil, LNG is a competitive fuel, both from a technical and economical point of view. LNG can be stored in vacuum insulated tanks fulfilling the difficult requirements of marine regulations. LNG must be vaporized and pressurized to the pressure which is compatible with the engine requirements (usually a few bar). The boil-off must be controlled to avoid the occasional gas release to the atmosphere. This paper presents an LNG system designed and commissioned for a Baltic Sea ferry. The specific technical features and exploitation parameters of the system will be presented. The impact of strict marine regulations on the system's thermo-mechanical construction and its performance will be discussed. The review of possible flow-schemes of LNG marine systems will be presented with respect to the system's cost, maintenance, and reliability.

  10. Temporal compression of cw diode-laser output into short pulses with cesium-vapor group-velocity dispersion.

    PubMed

    Choi, K; Menders, J; Ross, D; Korevaar, E

    1993-11-15

    Using a technique similar to chirped pulse compression, we have compressed the 50-mW cw output of a diode laser into pulses of greater than 500-mW peak power and less than 400-ps duration. By applying a small current modulation to the diode, we induced a small wavelength modulation in the vicinity of the 6s(1/2)-to-6p(3/2) cesium resonance transition at 852 nm. Group-velocity dispersion on propagation through a cesium vapor cell then led to pulse compression. We developed a simple model to make predictions of output pulse shapes by using different modulation waveforms. PMID:19829441

  11. High efficiency Brayton cycles using LNG

    DOEpatents

    Morrow, Charles W.

    2006-04-18

    A modified, closed-loop Brayton cycle power conversion system that uses liquefied natural gas as the cold heat sink media. When combined with a helium gas cooled nuclear reactor, achievable efficiency can approach 68 76% (as compared to 35% for conventional steam cycle power cooled by air or water). A superheater heat exchanger can be used to exchange heat from a side-stream of hot helium gas split-off from the primary helium coolant loop to post-heat vaporized natural gas exiting from low and high-pressure coolers. The superheater raises the exit temperature of the natural gas to close to room temperature, which makes the gas more attractive to sell on the open market. An additional benefit is significantly reduced costs of a LNG revaporization plant, since the nuclear reactor provides the heat for vaporization instead of burning a portion of the LNG to provide the heat.

  12. Dispersive radio frequency electrometry using Rydberg atoms in a prism-shaped atomic vapor cell

    NASA Astrophysics Data System (ADS)

    Fan, H. Q.; Kumar, S.; Kübler, H.; Shaffer, J. P.

    2016-05-01

    We introduce a method to measure radio frequency (RF) electric fields (E-fields) using atoms contained in a prism-shaped vapor cell. The method utilizes the concept of electromagnetically induced transparency with Rydberg atoms. The RF E-field induces changes in the index of refraction of the vapor resulting in deflection of the probe laser beam as it passes through the prism-shaped vapor cell. We measured a minimum RF E-field of 8.25 μ {{Vcm}}-1 with a sensitivity of ∼ 46.5 μ {{Vcm}}-1 {{Hz}}-1/2. The experimental results agree with a numerical model that includes dephasing effects. We discuss possible improvements to obtain higher sensitivity for RF E-field measurements.

  13. 75 FR 53371 - Liquefied Natural Gas Facilities: Obtaining Approval of Alternative Vapor-Gas Dispersion Models

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-31

    ... model that accounts for additional cloud dilution which may be caused by the complex flow patterns... not to influence the flow field of the vapor cloud) and/or through a sensitivity analysis of the... data that produced the maximum arc wise concentration relative to the cloud centerline. The...

  14. Heavy Gas Dispersion Incompressible Flow

    Energy Science and Technology Software Center (ESTSC)

    1992-02-03

    FEM3 is a numerical model developed primarily to simulate heavy gas dispersion in the atmosphere, such as the gravitational spread and vapor dispersion that result from an accidental spill of liquefied natural gas (LNG). FEM3 solves both two and three-dimensional problems and, in addition to the generalized anelastic formulation, includes options to use either the Boussinesq approximation or an isothermal assumption, when appropriate. The FEM3 model is composed of three parts: a preprocessor PREFEM3, themore » main code FEM3, and two postprocessors TESSERA and THPLOTX. The DEC VAX11 version contains an auxiliary program, POLYREAD, which reads the polyplot file created by FEM3.« less

  15. Temperature Sensitivity of an Atomic Vapor Cell-Based Dispersion-Enhanced Optical Cavity

    NASA Technical Reports Server (NTRS)

    Myneni, K.; Smith, D. D.; Chang, H.; Luckay, H. A.

    2015-01-01

    Enhancement of the response of an optical cavity to a change in optical path length, through the use of an intracavity fast-light medium, has previously been demonstrated experimentally and described theoretically for an atomic vapor cell as the intracavity resonant absorber. This phenomenon may be used to enhance both the scale factor and sensitivity of an optical cavity mode to the change in path length, e.g. in gyroscopic applications. We study the temperature sensitivity of the on-resonant scale factor enhancement, S(sub o), due to the thermal sensitivity of the lower-level atom density in an atomic vapor cell, specifically for the case of the Rb-87 D(sub 2) transition. A semi-empirical model of the temperature-dependence of the absorption profile, characterized by two parameters, a(sub o)(T) and gamma(sub a)(T) allows the temperature-dependence of the cavity response, S(sub o)(T) and dS(sub o)/dT to be predicted over a range of temperature. We compare the predictions to experiment. Our model will be useful in determining the useful range for S(sub o), given the practical constraints on temperature stability for an atomic vapor cell.

  16. Homogeneous Dispersion of Carbon Nanotubes on Surface-Modified Bulk Titanium Substrates by Thermal Chemical Vapor Deposition.

    PubMed

    Kim, Hogyu; Kwak, Seoung Yeol; Park, Ju Hyuk; Suk, Myung Jin; Oh, Sung Tag; Kim, Young Do

    2016-01-01

    Catalytic syntheses of CNTs on the pristine Ti mesh, the pristine Ti plate and the etched Ti plate have been conducted using thermal chemical vapor deposition (CVD) with Fe catalysts. Surface of the pristine Ti plate was etched in a sulfuric acid (H₂SO₄) solution to facilitate the uniform dispersion of Fe catalysts. The surface of Ti substrates, the distribution and the composition of catalysts, and the structure and dispersion of the CNTs were examined using Scanning electron microscope (SEM), transmission electron microscope (TEM), atomic force microscope (AFM), electron probe micro-analysis (EPMA) and Micro-Raman spectroscopy. Fe catalysts were dispersed uniformly on the surface of the etched Ti plate indicating that Surface modification by etching was effective. CNTs on the pristine Ti mesh and the etched Ti plate are more densely populated and have smaller diameters than CNTs on the pristine Ti plate. These results can be attributed to smaller Fe catalysts more homogeneously distributed on the pristine Ti mesh and the etched Ti plate. The calculated I(G)/I(D) ratios of 1.02 and 0.97 for CNTs on the pristine Ti mesh and the etched Ti plate, respectively, indicate a high degree of structural disorders on CNTs. PMID:27398544

  17. Insulating LNG (liquified natural gas) storage tank containment dikes with a lightweight polymer concrete

    SciTech Connect

    Fontana, J.J.

    1987-08-01

    The natural gas industry has always been concerned ith accidental spills of liquified natural gas (LNG) from storage tanks into surrounding containment dikes. The LNG that is leaked to the dike area boils off and the vapors mix with the atmosphere forming a hazardous explsoive mixture within the dike walls. These hazardous mixtures can travel long distances into industrial or residential areas surroungind LNG storage facilities. Studies by the natural gas industry indicate that the hazards associated with accidental spills of LNG from storage tanks can be makedly reduced by insulating the diked areas surrounding these tanks. In this manner, the heat transfer from the dike surface to the LNG is reduced. The insulating composite is used to construct a thermal barrier between the walls and floor of the dike an the spilled LNG. The thermal conductivity, porosity, and compression strength of a concrete, polymer composite insulating material is discussed. 6 refs., 8 figs., 5 tbs.

  18. PRELIMINARY INVESTIGATION OF UNCOMBUSTED AUTO FUEL VAPOR DISPERSION WITHIN A RESIDENTIAL GARAGE MICROENVIRONMENT

    EPA Science Inventory

    Evaporative emissions from vehicles in an attached garage may represent a significant source of indoor pollution and human exposure. ilot field study was undertaken to investigate potential in-house dispersion of evaporative emissions of uncombusted fuels from a vehicle parked in...

  19. An LNG release, transport, and fate model system for marine spills.

    PubMed

    Spaulding, Malcolm L; Swanson, J Craig; Jayko, Kathy; Whittier, Nicole

    2007-02-20

    LNGMAP, a fully integrated, geographic information based modular system, has been developed to predict the fate and transport of marine spills of LNG. The model is organized as a discrete set of linked algorithms that represent the processes (time dependent release rate, spreading, transport on the water surface, evaporation from the water surface, transport and dispersion in the atmosphere, and, if ignited, burning and associated radiated heat fields) affecting LNG once it is released into the environment. A particle-based approach is employed in which discrete masses of LNG released from the source are modeled as individual masses of LNG or spillets. The model is designed to predict the gas mass balance as a function of time and to display the spatial and temporal evolution of the gas (and radiated energy field). LNGMAP has been validated by comparisons to predictions of models developed by ABS Consulting and Sandia for time dependent point releases from a draining tank, with and without burning. Simulations were in excellent agreement with those performed by ABS Consulting and consistent with Sandia's steady state results. To illustrate the model predictive capability for realistic emergency scenarios, simulations were performed for a tanker entering Block Island Sound. Three hypothetical cases were studied: the first assumes the vessel continues on course after the spill starts, the second that the vessel stops as soon as practical after the release begins (3 min), and the third that the vessel grounds at the closest site practical. The model shows that the areas of the surface pool and the incident thermal radiation field (with burning) are minimized and dispersed vapor cloud area (without burning) maximized if the vessel continues on course. For this case the surface pool area, with burning, is substantially smaller than for the without burning case because of the higher mass loss rate from the surface pool due to burning. Since the vessel speed substantially

  20. Dispersibility of vapor phase oxygen and nitrogen functionalized multi-walled carbon nanotubes in various organic solvents

    PubMed Central

    Khazaee, Maryam; Xia, Wei; Lackner, Gerhard; Mendes, Rafael G.; Rümmeli, Mark; Muhler, Martin; Lupascu, Doru C.

    2016-01-01

    The synthesis and characterization of gas phase oxygen- and nitrogen-functionalized multi-walled carbon nanotubes (OMWCNTs and NMWCNTs) and the dispersibility of these tubes in organic solvents were investigated. Recently, carbon nanotubes have shown supreme capacity to effectively enhance the efficiency of organic solar cells (OSCs). A critical challenge is to individualize tubes from their bundles in order to provide homogenous nano-domains in the active layer of OSCs. OMWCNTs and NMWCNTs were synthesized via HNO3 vapor and NH3 treatments, respectively. Surface functional groups and the structure of the tubes were analyzed by temperature-programmed desorption, Fourier transform infrared spectroscopy, transmission electron microscopy, and Raman spectroscopy which confirmed the formation of functional groups on the tube surface and the enhancement of surface defects. Elemental analysis demonstrated that the oxygen and nitrogen content increased with increasing treatment time of the multi-walled carbon nanotube (MWCNT) in HNO3 vapor. According to ultra-violet visible spectroscopy, modification of the MWCNT increased the extinction coefficients of the tubes owing to enhanced compatibility of the functionalized tubes with organic matrices. PMID:27188622

  1. Dispersibility of vapor phase oxygen and nitrogen functionalized multi-walled carbon nanotubes in various organic solvents

    NASA Astrophysics Data System (ADS)

    Khazaee, Maryam; Xia, Wei; Lackner, Gerhard; Mendes, Rafael G.; Rümmeli, Mark; Muhler, Martin; Lupascu, Doru C.

    2016-05-01

    The synthesis and characterization of gas phase oxygen- and nitrogen-functionalized multi-walled carbon nanotubes (OMWCNTs and NMWCNTs) and the dispersibility of these tubes in organic solvents were investigated. Recently, carbon nanotubes have shown supreme capacity to effectively enhance the efficiency of organic solar cells (OSCs). A critical challenge is to individualize tubes from their bundles in order to provide homogenous nano-domains in the active layer of OSCs. OMWCNTs and NMWCNTs were synthesized via HNO3 vapor and NH3 treatments, respectively. Surface functional groups and the structure of the tubes were analyzed by temperature-programmed desorption, Fourier transform infrared spectroscopy, transmission electron microscopy, and Raman spectroscopy which confirmed the formation of functional groups on the tube surface and the enhancement of surface defects. Elemental analysis demonstrated that the oxygen and nitrogen content increased with increasing treatment time of the multi-walled carbon nanotube (MWCNT) in HNO3 vapor. According to ultra-violet visible spectroscopy, modification of the MWCNT increased the extinction coefficients of the tubes owing to enhanced compatibility of the functionalized tubes with organic matrices.

  2. Dispersibility of vapor phase oxygen and nitrogen functionalized multi-walled carbon nanotubes in various organic solvents.

    PubMed

    Khazaee, Maryam; Xia, Wei; Lackner, Gerhard; Mendes, Rafael G; Rümmeli, Mark; Muhler, Martin; Lupascu, Doru C

    2016-01-01

    The synthesis and characterization of gas phase oxygen- and nitrogen-functionalized multi-walled carbon nanotubes (OMWCNTs and NMWCNTs) and the dispersibility of these tubes in organic solvents were investigated. Recently, carbon nanotubes have shown supreme capacity to effectively enhance the efficiency of organic solar cells (OSCs). A critical challenge is to individualize tubes from their bundles in order to provide homogenous nano-domains in the active layer of OSCs. OMWCNTs and NMWCNTs were synthesized via HNO3 vapor and NH3 treatments, respectively. Surface functional groups and the structure of the tubes were analyzed by temperature-programmed desorption, Fourier transform infrared spectroscopy, transmission electron microscopy, and Raman spectroscopy which confirmed the formation of functional groups on the tube surface and the enhancement of surface defects. Elemental analysis demonstrated that the oxygen and nitrogen content increased with increasing treatment time of the multi-walled carbon nanotube (MWCNT) in HNO3 vapor. According to ultra-violet visible spectroscopy, modification of the MWCNT increased the extinction coefficients of the tubes owing to enhanced compatibility of the functionalized tubes with organic matrices. PMID:27188622

  3. Introduction to LNG vehicle safety

    NASA Astrophysics Data System (ADS)

    Bratvold, Delma; Friedman, David; Chernoff, Harry; Farkhondehpay, Dariush; Comay, Claudia

    1994-03-01

    Basic information on the characteristics of liquefied natural gas (LNG) is assembled to provide an overview of safety issues and practices for the use of LNG vehicles. This document is intended for those planning or considering the use of LNG vehicles, including vehicle fleet owners and operators, public transit officials and boards, local fire and safety officials, manufacturers and distributors, and gas industry officials. Safety issues and mitigation measures that should be considered for candidate LNG vehicle projects are addressed.

  4. Dispersal

    USGS Publications Warehouse

    2001-01-01

    The ability of species to migrate and disperse is a trait that has interested ecologists for many years. Now that so many species and ecosystems face major environmental threats from habitat fragmentation and global climate change, the ability of species to adapt to these changes by dispersing, migrating, or moving between patches of habitat can be crucial to ensuring their survival. This book provides a timely and wide-ranging overview of the study of dispersal and incorporates much of the latest research. The causes, mechanisms, and consequences of dispersal at the individual, population, species and community levels are considered. The potential of new techniques and models for studying dispersal, drawn from molecular biology and demography, is also explored. Perspectives and insights are offered from the fields of evolution, conservation biology and genetics. Throughout the book, theoretical approaches are combined with empirical data, and care has been taken to include examples from as wide a range of species as possible.

  5. LNG risk management

    NASA Astrophysics Data System (ADS)

    Martino, P.

    1980-12-01

    A general methodology is presented for conducting an analysis of the various aspects of the hazards associated with the storage and transportation of liquefied natural gas (LNG) which should be considered during the planning stages of a typical LNG ship terminal. The procedure includes the performance of a hazards and system analysis of the proposed site, a probability analysis of accident scenarios and safety impacts, an analysis of the consequences of credible accidents such as tanker accidents, spills and fires, the assessment of risks and the design and evaluation of risk mitigation measures.

  6. 77 FR 73627 - 2012 LNG Export Study

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-11

    ... Charles Exports, LLC, FE Docket No. 11-59-LNG, 76 FR 34212 (June 13, 2011); Dominion Cove Point LNG, LP, FE Docket No. 11-128-LNG, 76 FR 76698 (December 8, 2011); Carib Energy (USA) LLC, FE Docket No. 11-141-LNG, 76 FR 80913 (December 12, 2011); Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC,...

  7. LNG annotated bibliography

    SciTech Connect

    Bomelburg, H.J.; Counts, C.A.; Cowan, C.E.; Davis, W.E.; DeSteese, J.G.; Pelto, P.J.

    1982-09-01

    This document updates the bibliography published in Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: third status report (PNL-4172) and is a complete listing of literature reviewed and reported under the LNG Technical Surveillance Task. The bibliography is organized alphabetically by author.

  8. Steady-state and dynamic simulation study on boil-off gas minimization and recovery strategies at LNG exporting terminals

    NASA Astrophysics Data System (ADS)

    Kurle, Yogesh

    Liquefied natural gas (LNG) is becoming one of the prominent clean energy sources with its abundance, high calorific value, low emission, and price. Vapors generated from LNG due to heat leak are called boil-off gas (BOG). As world-wide LNG productions are increasing fast, BOG generation and handling problems are becoming more critical. Also, due to stringent environmental regulations, flaring of BOG is not a viable option. In this study, typical Propane-and-Mixed-Refrigerant (C3-MR) process, storage facilities, and loading facilities are modeled and simulated to study BOG generation at LNG exporting terminals, including LNG processing, storage, and berth loading areas. Factors causing BOG are presented, and quantities of BOG generated due to each factor at each location are calculated under different LNG temperatures. Various strategies to minimize, recover, and reuse BOG are also studied for their feasibility and energy requirements. Rate of BOG generation during LNG loading---Jetty BOG (JBOG)---changes significantly with loading time. In this study, LNG vessel loading is simulated using dynamic process simulation software to obtain JBOG generation profile and to study JBOG recovery strategies. Also, fuel requirements for LNG plant to run steam-turbine driven compressors and gas-turbine driven compressors are calculated. Handling of JBOG generated from multiple loadings is also considered. The study would help proper handling of BOG problems in terms of minimizing flaring at LNG exporting terminals, and thus reducing waste, saving energy, and protecting surrounding environments.

  9. Effect of Mo Dispersion Size and Water Vapor on Oxidation of Two-Phase Directionally Solidified NiAl-9Mo In-Situ Composites

    SciTech Connect

    Brady, Michael P; Bei, Hongbin; Meisner, Roberta Ann; Lance, Michael J; Tortorelli, Peter F

    2014-01-01

    Oxidation of two-phase NiAl-9Mo eutectics with 3 different growth rates/2nd phase Mo dispersion sizes were investigated at 900 C in air and air with 10% water vapor. Good oxidation resistance via alumina formation was observed in dry air, with Mo volatilization loss minimized by fine submicron Mo dispersions. However, extensive Mo volatilization and in-place internal oxidation of prior Mo phase regions was observed in wet air oxidation. Ramifications of this phenomenon for the development of multi-phase high-temperature alloys are discussed

  10. LNG pool fire spectral data and calculation of emissive power.

    PubMed

    Raj, Phani K

    2007-04-11

    Spectral description of thermal emission from fires provides a fundamental basis on which the fire thermal radiation hazard assessment models can be developed. Several field experiments were conducted during the 1970s and 1980s to measure the thermal radiation field surrounding LNG fires. Most of these tests involved the measurement of fire thermal radiation to objects outside the fire envelope using either narrow-angle or wide-angle radiometers. Extrapolating the wide-angle radiometer data without understanding the nature of fire emission is prone to errors. Spectral emissions from LNG fires have been recorded in four test series conducted with LNG fires on different substrates and of different diameters. These include the AGA test series of LNG fires on land of diameters 1.8 and 6m, 35 m diameter fire on an insulated concrete dike in the Montoir tests conducted by Gaz de France, a 1976 test with 13 m diameter and the 1980 tests with 10 m diameter LNG fire on water carried out at China Lake, CA. The spectral data from the Montoir test series have not been published in technical journals; only recently has some data from this series have become available. This paper presents the details of the LNG fire spectral data from, primarily, the China Lake test series, their analysis and results. Available data from other test series are also discussed. China Lake data indicate that the thermal radiation emission from 13 m diameter LNG fire is made up of band emissions of about 50% of energy by water vapor (band emission), about 25% by carbon dioxide and the remainder constituting the continuum emission by luminous soot. The emissions from the H2O and CO2 bands are completely absorbed by the intervening atmosphere in less than about 200 m from the fire, even in the relatively dry desert air. The effective soot radiation constitutes only about 23% during the burning period of methane and increases slightly when other higher hydrocarbon species (ethane, propane, etc.) are

  11. Blanketing effect of expansion foam on liquefied natural gas (LNG) spillage pool.

    PubMed

    Zhang, Bin; Liu, Yi; Olewski, Tomasz; Vechot, Luc; Mannan, M Sam

    2014-09-15

    With increasing consumption of natural gas, the safety of liquefied natural gas (LNG) utilization has become an issue that requires a comprehensive study on the risk of LNG spillage in facilities with mitigation measures. The immediate hazard associated with an LNG spill is the vapor hazard, i.e., a flammable vapor cloud at the ground level, due to rapid vaporization and dense gas behavior. It was believed that high expansion foam mitigated LNG vapor hazard through warming effect (raising vapor buoyancy), but the boil-off effect increased vaporization rate due to the heat from water drainage of foam. This work reveals the existence of blocking effect (blocking convection and radiation to the pool) to reduce vaporization rate. The blanketing effect on source term (vaporization rate) is a combination of boil-off and blocking effect, which was quantitatively studied through seven tests conducted in a wind tunnel with liquid nitrogen. Since the blocking effect reduces more heat to the pool than the boil-off effect adds, the blanketing effect contributes to the net reduction of heat convection and radiation to the pool by 70%. Water drainage rate of high expansion foam is essential to determine the effectiveness of blanketing effect, since water provides the boil-off effect. PMID:25194555

  12. LNG Vehicle High-Pressure Fuel System and ''Cold Energy'' Utilization

    SciTech Connect

    powers,Charles A.; Derbidge, T. Craig

    2001-03-27

    A high-pressure fuel system for LNG vehicles with direct-injection natural gas engines has been developed and demonstrated on a heavy-duty truck. A new concept for utilizing the ''cold energy'' associated with LNG vehicles to generate mechanical power to drive auxiliary equipment (such as high-pressure fuel pumps) has also been developed and demonstrated in the laboratory. The high-pressure LNG fuel system development included the design and testing of a new type of cryogenic pump utilizes multiple chambers and other features to condense moderate quantities of sucked vapor and discharge supercritical LNG at 3,000 to 4,000 psi. The pump was demonstrated on a Class 8 truck with a Westport high-pressure direct-injection Cummins ISX engine. A concept that utilizes LNG's ''cold energy'' to drive a high-pressure fuel pump without engine attachments or power consumption was developed. Ethylene is boiled and superheated by the engine coolant, and it is cooled and condensed by rejecting h eat to the LNG. Power is extracted in a full-admission blowdown process, and part of this power is applied to pump the ethylene liquid to the boiler pressure. Tests demonstrated a net power output of 1.1. hp at 1.9 Lbm/min of LNG flow, which is adequate to isentropically pump the LNG to approximately 3,400 psi..

  13. Liquefied Natural Gas (LNG) dispenser verification device

    NASA Astrophysics Data System (ADS)

    Xiong, Maotao; Yang, Jie-bin; Zhao, Pu-jun; Yu, Bo; Deng, Wan-quan

    2013-01-01

    The composition of working principle and calibration status of LNG (Liquefied Natural Gas) dispenser in China are introduced. According to the defect of weighing method in the calibration of LNG dispenser, LNG dispenser verification device has been researched. The verification device bases on the master meter method to verify LNG dispenser in the field. The experimental results of the device indicate it has steady performance, high accuracy level and flexible construction, and it reaches the international advanced level. Then LNG dispenser verification device will promote the development of LNG dispenser industry in China and to improve the technical level of LNG dispenser manufacture.

  14. LNG Observer: Second Qatargas train goes onstream

    SciTech Connect

    1997-01-01

    The January-February, 1997 issue of the LNG Observer is presented. The following topics are discussed: second Qatargas train goes onstream; financing for the eighth Indonesian liquefaction train; Koreans take stakes in Oman LNG; US imports and exports of LNG in 1996; A 60% increase in proved reserves on the North West Shelf; proposals for Indian LNG terminal CEDIGAZ forecasts world LNG trade by 2010; growth for North African gas production and exports; and new forecast sees strong growth for Asian gas.

  15. Use of TX100-dangled epoxy as a reactive noncovalent dispersant of vapor-grown carbon nanofibers in an aqueous solution.

    PubMed

    Dong, Yubing; Wang, Rui; Li, Shan; Yang, Hongbing; Du, Mingliang; Fu, Yaqin

    2013-02-01

    The dispersion of carbon nanotubes (CNTs) into individual particles or small bundles has remained a vexing problem that limits the use of the excellent properties of CNTs in composite applications. Noncovalent functionalization is an attractive option for changing the interfacial properties of nanotubes because it does not destroy the nanotube grapheme structure. In this study, a new reactive copolymer, epoxy-toluene diisocyanate-Triton X-100 (EP-TDI-TX100) was successfully synthesized, which is shown to be highly effective in dispersing vapor-grown carbon nanofibers (VGCNFs) into individual or small bundles, as evidenced by transmission electron microscopy (TEM) and UV-vis absorption spectra. The strong π-π interaction between VGCNFs and EP-TDI-TX100 was revealed by Raman spectra and the covalent reaction between curing agent was confirmed via Fourier transform infrared spectroscopy. For an effective dispersion, the optimum weight ratio of EP-TDI-TX100 to VGCNFs is 2:1. The maximum VGCNF concentration that can be homogeneously dispersed in an aqueous solution is approximately 0.64 mg/mL. The EP-TDI-TX100 molecules are adsorbed on the VGCNF surface and prevent reaggregation of VGCNFs, so that a colloidal stability of VGCNF dispersion can be maintained for 6 months. PMID:23116860

  16. Thermodynamic and heat transfer analysis of LNG energy recovery for power production

    NASA Astrophysics Data System (ADS)

    Franco, A.; Casarosa, C.

    2014-11-01

    An important option to transport the gas is to convert it into liquid natural gas (LNG) and convey it using insulated LNG tankers. At receiving terminals, the LNG is offloaded into storage tanks and then pumped at the required pressure and vaporized for final transmission to the pipeline. The LNG production process consumes a considerable amount of energy, while the cold availability, as also known as cold energy, has been stored in LNG. At a receiving terminal, LNG needs to be evaporated into gas at environmental temperature before fed into the gas distribution system. Seawater is commonly used for the regasification process of the LNG. In the present paper, after a general analysis of the perspectives of the various thermodynamic schemes proposed for power production from the regasification, a detailed analysis of enhanced direct expansion system is carried out in order to identify the upper level of the energy that can be recovered. The analysis outlines that power production typical of optimized ORC plant configurations (120 kJ/kg) can be obtained with direct expansion solutions.

  17. North American LNG Project Sourcebook

    SciTech Connect

    2007-06-15

    The report provides a status of the development of LNG Import Terminal projects in North America, and includes 1-2 page profiles of 63 LNG projects in North America which are either in operation, under construction, or under development. For each project, the sourcebook provides information on the following elements: project description, project ownership, project status, projected operation date, storage capacity, sendout capacity, and pipeline interconnection.

  18. Investigation of low-cost LNG vehicle fuel tank concepts. Final report

    SciTech Connect

    O`Brien, J.E.; Siahpush, A.

    1998-02-01

    The objective of this study was to investigate development of a low-cost liquid natural gas (LNG) vehicle fuel storage tank with low fuel boil-off, low tank pressure, and high safety margin. One of the largest contributors to the cost of converting a vehicle to LNG is the cost of the LNG fuel tank. To minimize heat leak from the surroundings into the low-temperature fuel, these tanks are designed as cryogenic dewars with double walls separated by an evacuated insulation space containing multi-layer insulation. The cost of these fuel tanks is driven by this double-walled construction, both in terms of materials and labor. The primary focus of the analysis was to try to devise a fuel tank concept that would allow for the elimination of the double-wall requirement. Results of this study have validated the benefit of vacuum/MLI insulation for LNG fuel tanks and the difficulty in identifying viable alternatives. The thickness of a non-vacuum insulation layer would have to be unreasonably large to achieve an acceptable non-venting hold time. Reasonable hold times could be achieved by using an auxiliary tank to accept boil-off vapor from a non-vacuum insulated primary tank, if the vapor in the auxiliary tank can be stored at high pressure. The primary focus of the analysis was to try to devise a fuel tank concept that allowed for the elimination of the double-wall requirement. Thermodynamic relations were developed for analyzing the fuel tank transient response to heat transfer, venting of vapor, and out-flow of either vapor or liquid. One of the major costs associated with conversion of a vehicle to LNG fuel is the cost of the LNG fuel tank. The cost of these tanks is driven by the cryogenic nature of the fuel and by the fundamental design requirements of long non-venting hold times and low storage pressure.

  19. On the application of computational fluid dynamics codes for liquefied natural gas dispersion.

    SciTech Connect

    Luketa-Hanlin, Anay Josephine; Koopman, Ronald P.; Ermak, Donald

    2006-02-01

    Computational fluid dynamics (CFD) codes are increasingly being used in the liquefied natural gas (LNG) industry to predict natural gas dispersion distances. This paper addresses several issues regarding the use of CFD for LNG dispersion such as specification of the domain, grid, boundary and initial conditions. A description of the k-{var_epsilon} model is presented, along with modifications required for atmospheric flows. Validation issues pertaining to the experimental data from the Burro, Coyote, and Falcon series of LNG dispersion experiments are also discussed. A description of the atmosphere is provided as well as discussion on the inclusion of the Coriolis force to model very large LNG spills.

  20. Recommended research on LNG safety

    SciTech Connect

    Carpenter, H.J.; Gilmore, F.R.

    1981-03-01

    The US Department of Energy (DOE) is conducting research on the safety and other environmental aspects of liquefied energy gases including liquefied natural gas (LNG). The effort reported here was conducted as part of the planning for further research into the safety aspects of transporting and storing LNG, with primary emphasis on public safety. Although the modern LNG industry has enjoyed excellent success in providing for safe operations, significant questions remain on the part of many, the expressions of which were intensified with the addition of marine-based LNG import terminals. Public safety with regard to large-scale importation of this fuel has received widespread attention in the US Congress, state legislatures, county and city governments, and from various individuals and public groups, with coverage in all the news media, including books published on the subject. The safety concerns have centered around the consequences to the public of a large spill of the cryogenic liquid from an ocean tanker or a larger storage tank, either of which might hold as much as 125,000 m/sup 3/ of LNG.

  1. LNG to CNG refueling stations

    SciTech Connect

    Branson, J.D.

    1995-12-31

    While the fleet operator is concerned about the environment, he or she is going to make the choice based primarily on economics. Which fuel provides the lowest total operating cost? The calculation of this costing must include the price-per-gallon of the fuel delivered, as well as the tangible and intangible components of fuel delivery, such as downtime for vehicles during the refueling process, idle time for drivers during refueling, emissions costings resulting from compressor oil blow-by, inclusion of non-combustible constituents in the CNG, and energy consumption during the refueling process. Also, the upfront capital requirement of similar delivery capabilities must be compared. The use of LNG as the base resource for the delivered CNG, in conjunction with the utilization of a fully temperature-compressed LNG/CNG refueling system, eliminates many of the perceived shortfalls of CNG. An LNG/CNG refueling center designed to match the capabilities of the compressor-based station will have approximately the same initial capital requirement. However, because it derives its CNG sales product from the {minus}260 F LNG base product, thus availing itself of the natural physical properties of the cryogenic product, all other economic elements of the system favor the LNG/CNG product.

  2. Numerical investigation of supercritical LNG convective heat transfer in a horizontal serpentine tube

    NASA Astrophysics Data System (ADS)

    Han, Chang-Liang; Ren, Jing-Jie; Dong, Wen-Ping; Bi, Ming-Shu

    2016-09-01

    The submerged combustion vaporizer (SCV) is indispensable general equipment for liquefied natural gas (LNG) receiving terminals. In this paper, numerical simulation was conducted to get insight into the flow and heat transfer characteristics of supercritical LNG on the tube-side of SCV. The SST model with enhanced wall treatment method was utilized to handle the coupled wall-to-LNG heat transfer. The thermal-physical properties of LNG under supercritical pressure were used for this study. After the validation of model and method, the effects of mass flux, outer wall temperature and inlet pressure on the heat transfer behaviors were discussed in detail. Then the non-uniformity heat transfer mechanism of supercritical LNG and effect of natural convection due to buoyancy change in the tube was discussed based on the numerical results. Moreover, different flow and heat transfer characteristics inside the bend tube sections were also analyzed. The obtained numerical results showed that the local surface heat transfer coefficient attained its peak value when the bulk LNG temperature approached the so-called pseudo-critical temperature. Higher mass flux could eliminate the heat transfer deteriorations due to the increase of turbulent diffusion. An increase of outer wall temperature had a significant influence on diminishing heat transfer ability of LNG. The maximum surface heat transfer coefficient strongly depended on inlet pressure. Bend tube sections could enhance the heat transfer due to secondary flow phenomenon. Furthermore, based on the current simulation results, a new dimensionless, semi-theoretical empirical correlation was developed for supercritical LNG convective heat transfer in a horizontal serpentine tube. The paper provided the mechanism of heat transfer for the design of high-efficiency SCV.

  3. Re-Examining the Properties of the Aqueous Vapor-Liquid Interface Using Dispersion Corrected Density Functional Theory

    SciTech Connect

    Baer, Marcel D.; Mundy, Christopher J.; McGrath, Matthew J.; Kuo, I-F W.; Siepmann, Joern I.; Tobias, Douglas J.

    2011-09-28

    First-principles molecular dynamics simulations, in which the forces are computed from electronic structure calculations, have great potential to provide unique insight into structure, dynamics, electronic properties, and chemistry at aqueous interfaces that is not available from empirical force fields. The majority of current first-principles simulations are driven by forces derived from density functional theory with generalized gradient approximations to the exchange-correlation energy, which do not capture dispersion interactions. We have carried out first-principles molecular dynamics simulations of air-water interfaces employing a particular generalized gradient approximation to the exchange-correlation functional (BLYP), with and without empirical dispersion corrections. We assess the utility of the dispersion corrections by comparison of a variety of structural, dynamic, and thermodynamic properties of bulk and interfacial water with experimental data, as well as other first-principles and force field-based simulations. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  4. Characterization of the Near-Field Transport and Dispersion of Vapors Released from the Headspaces of Hanford Site Underground Storage Tanks

    SciTech Connect

    Droppo, James G.

    2004-07-30

    A parametric air dispersion analysis has been conducted to define the range of tank vapor concentrations from the Hanford Site underground tanks that can potentially occur in the worker breathing zones from active and passive releases from the waste tanks. The potential influences of tank farm specific release characteristics, ambient meteorological conditions, local farm surface roughness, and topographical influences are considered. The parametric approach allows consideration of the full range venting configurations and potential vapor concentration over the range of meteorological conditions at the Hanford Site. The results indicate that occasional short duration exposures of up to several seconds to relatively undiluted headspace air can be expected in the immediate vicinity of the tank vents. Average concentrations which represent diffusion, as well as spatial averaging, fall off rapidly with distance for the passive vents and to a lesser extent for the forced-air stacks. The addition of the influence of the surface roughness elements on the tank farms will result in a faster decrease of concentrations with downwind distance.

  5. Dispersion of UO{sub 2}F{sub 2} aerosol and HF vapor in the operating floor during winter ventilation at the Paducah Gaseous Diffusion Plant

    SciTech Connect

    Kim, S.H.; Chen, N.C.J.; Taleyarkhan, R.P.; Keith, K.D.; Schmidt, R.W.; Carter, J.C.

    1996-12-30

    The gaseous diffusion process is currently employed at two plants in the US: the Paducah Gaseous Diffusion Plant and the Portsmouth Gaseous Diffusion Plant. As part of a facility-wide safety evaluation, a postulated design basis accident involving large line-rupture induced releases of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant (GDP) is evaluated. When UF{sub 6} is released into the atmosphere, it undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form vaporized hydrogen fluoride (HF) and aerosolized uranyl fluoride (UO{sub 2}F{sub 2}). These reactants disperse in the process building and transport through the building ventilation system. The ventilation system draws outside air into the process building, distributes it evenly throughout the building, and discharges it to the atmosphere at an elevated temperature. Since air is recirculated from the cell floor area to the operating floor, issues concerning in-building worker safety and evacuation need to be addressed. Therefore, the objective of this study is to evaluate the transport of HF vapor and UO{sub 2}F{sub 2} aerosols throughout the operating floor area following B-line break accident in the cell floor area.

  6. LNG vehicle technology, economics, and safety assessment

    NASA Astrophysics Data System (ADS)

    Powars, Charles A.; Moyer, Carl B.; Lowell, Douglas D.

    1994-02-01

    Liquid natural gas (LNG) is an attractive transportation fuel because of its high heating value and energy density (i.e., Btu/lb. and Btu/gal.), clean burning characteristics, relatively low cost ($/Btu), and domestic availability. This research evaluated LNG vehicle and refueling system technology, economics, and safety. Prior and current LNG vehicle projects were studied to identify needed technology improvements. Life-cycle cost analyses considered various LNG vehicle and fuel supply options. Safety records, standards, and analysis methods were reviewed. The LNG market niche is centrally fueled heavy-duty fleet vehicles with high fuel consumption. For these applications, fuel cost savings can amortize equipment capital costs.

  7. A Study on the Air flow outside Ambient Vaporizer Fin

    NASA Astrophysics Data System (ADS)

    Oh, G.; Lee, T.; Jeong, H.; Chung, H.

    2015-09-01

    In this study, we interpreted Fog's Fluid that appear in the Ambient Vaporizer and predict the point of change Air to Fog. We interpreted using Analysis working fluid was applied to LNG and Air. We predict air flow when there is chill of LNG in the air Temperature and that makes fog. Also, we interpreted based on Summer and Winter criteria in the air temperature respectively. Finally, we can check the speed of the fog when fog excreted.

  8. Simultaneous speciation of inorganic arsenic, selenium and tellurium in environmental water samples by dispersive liquid liquid microextraction combined with electrothermal vaporization inductively coupled plasma mass spectrometry.

    PubMed

    Liu, Ying; He, Man; Chen, Beibei; Hu, Bin

    2015-09-01

    A new method based on dispersive liquid liquid microextraction (DLLME) combined with electrothermal vaporization inductively coupled plasma mass spectrometry (ETV-ICP-MS) was developed for the simultaneous speciation of inorganic arsenic (As), selenium (Se) and tellurium (Te) with sodium diethyldithiocarbamate (DDTC) as both chelating reagent and chemical modifier. As(III), Se(IV) and Te(IV) were transformed into DDTC-chelates at pH 7 and extracted into the fine droplets formed by injecting the binary solution of bromobenzene (extraction solvent) and methanol (dispersive solvent) into the sample solution. After phase separation by centrifugation, As(III), Se(IV) and Te(IV) preconcentrated in the organic phase were determined by ETV-ICP-MS. Total inorganic As, Se and Te were obtained by reducing As(V), Se(VI) and Te(VI) to As(III), Se(IV) and Te(IV) with L-cysteine, which were then subjected to the same DLLME-ETV-ICP-MS process. The concentration of As(V), Se(VI), Te(VI) were calculated by subtracting the concentration of As(III), Se(IV) and Te(IV) from the total inorganic As, Se and Te, respectively. The main factors affecting the microextraction efficiency and the vaporization behavior of target species were investigated in detail. Under the optimal conditions, the limits of detection were 2.5, 8.6 and 0.56 ng L(-1) for As(III), Se(IV) and Te(IV), respectively, with the relative standard deviations (n=7) of 8.5-9.7%. The developed method was applied to the speciation of inorganic As, Se and Te in Certified Reference Materials of GSBZ50004-88, GBW(E)080395 and GBW(E)080548 environmental waters, and the determined values are in good agreement with the certified values. The method was also successfully applied to the simultaneous speciation of inorganic As, Se and Te in different environmental water samples with the recoveries in the range of 86.3-107% for the spiked samples. PMID:26003714

  9. Feasibility of methods and systems for reducng LNG tanker fire hazards

    SciTech Connect

    Not Available

    1980-08-01

    In this program concepts for reducing fire hazards that may result from LNG tanker collisions are identified and their technical feasibility evaluated. Concepts considered include modifications to the shipborne LNG containers so that in the event of a container rupture less of the contents would spill and/or the contents would spill at a reduced rate. Changes in the cargo itself, including making the LNG into a gel, solidifying it, converting it to methanol, and adding flame suppressants are also evaluated. The relative effectiveness and the costs of implementing these methods in terms of increased cost of gas at the receiving terminal, are explained. The vulnerability of an LNG tanker and its crew to the thermal effects of a large pool fire caused by a collision spill is estimated and methods of protecting the crew are considered. It is shown that the protection of ship and crew so that further deterioration of a damaged ship might be ameliorated, would require the design and installation of extraordinary insulation systems and life support assistance for the crew. Methods of salvaging or disposing of cargo from a damaged and disabled ship are evaluated, and it is concluded that if the cargo cannot be transferred to another (empty) LNG tanker because of lack of availability, then the burning of the cargo at a location somewhat distant from the disabled tanker appears to be a promising approach. Finally, the likelihood of the vapors from a spill being ignited due to the frictional impact of the colliding ships was examined. It is found that the heating of metal sufficient to ignite flammable vapors would occur during a collision, but it is questionable whether flammable vapor and air will, in fact, come in contact with the hot metal surfaces.

  10. LNG Safety Assessment Evaluation Methods

    SciTech Connect

    Muna, Alice Baca; LaFleur, Angela Christine

    2015-05-01

    Sandia National Laboratories evaluated published safety assessment methods across a variety of industries including Liquefied Natural Gas (LNG), hydrogen, land and marine transportation, as well as the US Department of Defense (DOD). All the methods were evaluated for their potential applicability for use in the LNG railroad application. After reviewing the documents included in this report, as well as others not included because of repetition, the Department of Energy (DOE) Hydrogen Safety Plan Checklist is most suitable to be adapted to the LNG railroad application. This report was developed to survey industries related to rail transportation for methodologies and tools that can be used by the FRA to review and evaluate safety assessments submitted by the railroad industry as a part of their implementation plans for liquefied or compressed natural gas storage ( on-board or tender) and engine fueling delivery systems. The main sections of this report provide an overview of various methods found during this survey. In most cases, the reference document is quoted directly. The final section provides discussion and a recommendation for the most appropriate methodology that will allow efficient and consistent evaluations to be made. The DOE Hydrogen Safety Plan Checklist was then revised to adapt it as a methodology for the Federal Railroad Administration’s use in evaluating safety plans submitted by the railroad industry.

  11. 40 CFR Table W - 6 of Subpart W-Default Methane Emission Factors for LNG Import and Export Equipment

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Petroleum and Natural Gas Systems Definitions. Pt. 98, Subpt. W, Table W-6 Table W-6 of Subpart W—Default Methane... Connector 0.34 Other 1 1.77 Population Emission Factors—LNG Terminals Compressor, Gas Service Vapor...

  12. Strategic evaluation central to LNG project formation

    SciTech Connect

    Nissen, D.; DiNapoli, R.N.; Yost, C.C.

    1995-07-03

    An efficient-scale, grassroots LNG facility of about 6 million metric tons/year capacity requires a prestart-up outlay of $5 billion or more for the supply facilities--production, feedgas pipeline, liquefaction, and shipping. The demand side of the LNG chain requires a similar outlay, counting the import-regasification terminal and a combination of 5 gigawatts or more of electric power generation or the equivalent in city gas and industrial gas-using facilities. There exist no well-developed commodity markets for free-on-board (fob) or delivered LNG. A new LNG supply project is dedicated to its buyers. Indeed, the buyers` revenue commitment is the project`s only bankable asset. For the buyer to make this commitment, the supply venture`s capability and commitment must be credible: to complete the project and to deliver the LNG reliably over the 20+ years required to recover capital committed on both sides. This requirement has technical, economic, and business dimensions. In this article the authors describe a LNG project evaluation system and show its application to typical tasks: project cost of service and participant shares; LNG project competition; alternative project structures; and market competition for LNG-supplied electric power generation.

  13. 33 CFR 127.321 - Release of LNG.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Release of LNG. 127.321 Section... Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.321 Release of LNG. (a) The operator of the waterfront facility handling LNG shall ensure that— (1) No person releases LNG into the...

  14. 49 CFR 193.2181 - Impoundment capacity: LNG storage tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Impoundment capacity: LNG storage tanks. 193.2181... Impoundment capacity: LNG storage tanks. Each impounding system serving an LNG storage tank must have a minimum volumetric liquid impoundment capacity of: (a) 110 percent of the LNG tank's maximum...

  15. 49 CFR 193.2181 - Impoundment capacity: LNG storage tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Impoundment capacity: LNG storage tanks. 193.2181... Impoundment capacity: LNG storage tanks. Each impounding system serving an LNG storage tank must have a minimum volumetric liquid impoundment capacity of: (a) 110 percent of the LNG tank's maximum...

  16. 33 CFR 127.321 - Release of LNG.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Release of LNG. 127.321 Section... Waterfront Facilities Handling Liquefied Natural Gas Operations § 127.321 Release of LNG. (a) The operator of the waterfront facility handling LNG shall ensure that— (1) No person releases LNG into the...

  17. Ultra-trace determination of gold nanoparticles in environmental water by surfactant assisted dispersive liquid liquid microextraction coupled with electrothermal vaporization-inductively coupled plasma-mass spectrometry

    NASA Astrophysics Data System (ADS)

    Liu, Ying; He, Man; Chen, Beibei; Hu, Bin

    2016-08-01

    A new method by coupling surfactant assisted dispersive liquid liquid microextraction (SA-DLLME) with electrothermal vaporization inductively coupled plasma mass spectrometry (ETV-ICP-MS) was proposed for the analysis of gold nanoparticles (AuNPs) in environmental water samples. Effective separation of AuNPs from ionic gold species was achieved by using sodium thiosulphate as a complexing agent. Various experimental parameters affecting SA-DLLME of AuNPs, such as the organic solvent, organic solvent volume, pH of the sample, the kind of surfactant, surfactant concentration, vortex time, speed of centrifugation, centrifugation time, and different coating as well as sizes of AuNPs were investigated carefully. Furthermore, the interference of coexisting ions, dissolved organic matter (DOM) and other metal nanoparticles (NPs) were studied. Under the optimal conditions, a detection limit of 2.2 ng L- 1 and an enrichment factor of 152-fold was achieved for AuNPs, and the original morphology of the AuNPs could be maintained during the extraction process. The developed method was successfully applied for the analysis of AuNPs in environmental water samples, including tap water, the East Lake water, and the Yangtze River water, with recoveries in the range of 89.6-102%. Compared with the established methods for metal NPs analysis, the proposed method has the merits of simple and fast operation, low detection limit, high selectivity, good tolerance to the sample matrix and no digestion or dilution required. It provides an efficient quantification methodology for monitoring AuNPs' pollution in the environmental water and evaluating its toxicity.

  18. How Gaz de France optimizes LNG regasification

    SciTech Connect

    Colonna, J.L.; Lecomte, B.; Caudron, S.

    1986-05-05

    A regasification optimization program was implemented at Montoir-de-Bretagne in 1984, and rapidly accepted by the operators. It has been an important tool for decision-making in the optimizing operation of this liquefied natural gas (LNG) storage and regasification terminal. The models used are regularly and easily updated on the basis of equipment behavior: aging or fouling. The Montoir-de-Bretagne LNG terminal is in the port area of Nates-Saint Nazaire on the Atlantic coast. It was commissioned in 1982 by Gaz de France. This terminal is used for receiving, storing, and regasifying the Algerian LNG received under a contract between Gaz de France and Sonatrach, as well as the LNG imported by Belgium and temporarily routed through France. It is designed to receive 25,000 to 200,000 cu m LNG carriers and has three 120,000 cm m LNG storage tanks. The daily sendout ranges between 6.7 million cu m and 36 million cu m. Monitor terminal supplies mainly Brittany and the Paris area. Two identifical berths allow the simultaneous reception of two LNG carriers. LNG is carried to the storage tanks in 32-in. lines at a rate of 12,000 cu m/hr. Each storage tank is equipped with three submerged 450 cu m/hr pumps with which the LNG is sent from the tanks to the secondary pumps at 8 bar. The nine high-pressure (HP) secondary pumps, with a capacity of either 450 cu m/hr or 180 cu m/hr, raise the LNG pressure to a level at least equal to pipeline pressure prior to revaporization.

  19. 76 FR 2677 - Southern LNG Company, LLC; Notice of Public Scoping Meeting for the Proposed LNG Truck Loading...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-14

    ... Energy Regulatory Commission Southern LNG Company, LLC; Notice of Public Scoping Meeting for the Proposed LNG Truck Loading Project January 7, 2011. On February 2, 2011, the Office of Energy Projects staff... Southern LNG Company, LLC's (Southern) LNG Truck Loading Project. We scheduled this meeting to...

  20. LNG -- A paradox of propulsion potential

    SciTech Connect

    McKay, D.J.

    1995-12-31

    Liquefied natural gas (LNG) has been demonstrating its viability as a clean-burning alternative fuel for buses and medium- and heavy-duty trucks for the past 30 years. The first known LNG vehicle project began in San Diego in 1965, When San Diego Gas and Electric converted 22 utility trucks and three passenger vehicles to dedicated LNG. A surge in LNG vehicle project activity over the past five years has led to a fairly robust variety of vehicles testing the fuel, from Class 8 tractors, refuse haulers and transit buses to railroad locomotives and ferry boats. Recent technology improvements in engine design, cryogenic tanks, fuel nozzles and other related equipment have made LNG more practical to use than in the 1960s. LNG delivers more than twice the driving range from the same-sized fuel tank as a vehicle powered by compressed natural gas (CNG). Although technical and economic hurdles must be overcome before this fuel can achieve widespread use, various ongoing demonstration projects are showing LNG`s practicality, while serving the vital role of pinpointing those areas of performance that are the prime candidates for improvement.

  1. Raley's LNG Truck Site Final Data Report

    SciTech Connect

    Battelle

    1999-07-01

    Raley's is a 120-store grocery chain with headquarters in Sacramento, California, that has been operating eight heavy-duty LNG trucks (Kenworth T800 trucks with Cummins L10-300G engines) and two LNG yard tractors (Ottawa trucks with Cummins B5.9G engines) since April 1997. This report describes the results of data collection and evaluation of the eight heavy-duty LNG trucks compared to similar heavy-duty diesel trucks operating at Raley's. The data collection and evaluation are a part of the U.S. Department of Energy (DOE)/National Renewable Energy Laboratory (NREL) Alternative Fuel Truck Evaluation Project.

  2. Research of design challenges and new technologies for floating LNG

    NASA Astrophysics Data System (ADS)

    Lee, Dong-Hyun; Ha, Mun-Keun; Kim, Soo-Young; Shin, Sung-Chul

    2014-06-01

    With the rate of worldwide LNG demand expected to grow faster than that of gas demand, most major oil companies are currently investing their resources to develop floating LNG-FLNG (i.e. LNG FSRU and LNG FPSO). The global Floating LNG (FLNG) market trend will be reviewed based on demand and supply chain relationships. Typical technical issues associated with FLNG design are categorized in terms of global performance evaluation. Although many proven technologies developed through LNG carrier and oil FPSO projects are available for FLNG design, we are still faced with several technical challenges to clear for successful FLNG projects. In this study, some of the challenges encountered during development of the floating LNG facility (i.e. LNG FPSO and FSRU) will be reviewed together with their investigated solution. At the same time, research of new LNG-related technologies such as combined containment system will be presented.

  3. Gas treating alternatives for LNG plants

    SciTech Connect

    Clarke, D.S.; Sibal, P.W.

    1998-12-31

    This paper covers the various gas treating processes available for treating sour natural gas to specifications required for LNG production. The LNG product specification requires that the total sulfur level be less than 30--40 ppmv, the CO{sub 2} level be less than 50 ppmv and the water level be less than 100 ppmv to prevent freezing problems in the LNG cryogenic column. A wide variety of natural gas compositions are encountered in the various fields and the gas treating process selection is dependent on the type of impurities present in the gas, namely, levels of H{sub 2}S, CO{sub 2}, mercaptans and other organic sulfur compounds. This paper discusses the implications various components in the feed to the LNG plant can have on process selection, and the various treating processes that are available to condition the gas. Process selection criteria, design and operating philosophies are discussed. An economic comparison for two treating schemes is provided.

  4. Norcal Prototype LNG Truck Fleet: Final Results

    SciTech Connect

    Not Available

    2004-07-01

    U.S. DOE and National Renewable Energy Laboratory evaluated Norcal Waste Systems liquefied natural gas (LNG) waste transfer trucks. Trucks had prototype Cummins Westport ISXG engines. Report gives final evaluation results.

  5. LNG carrier using membrane tank system delivered

    SciTech Connect

    Not Available

    1993-12-06

    The world's first LNG carrier that incorporates the Technigaz Mark 3 membrane tank system was delivered in October to its owner, Asia LNG Transport Sdn. Bhd., a joint venture between Nippon Yusen K.K. and Perbadanan Nasional Shipping Line Berhad of Malaysia. NKK built the 18,800 cu m, fully double-hull carrier Aman Bintulu at its Tsu works. Construction was completed in September with more than 2 months of sea trials and gas tests using [minus]190 C. Liquid nitrogen and final gas trails with LNG. The orthogonally corrugated stainless membrane primary barrier and the triplex (aluminum foil/fiber glass cloth) composite-material secondary barrier prevent LNG from leaking in the event of an accident.

  6. Effects of lng Mutations on LngA Expression, Processing, and CS21 Assembly in Enterotoxigenic Escherichia coli E9034A.

    PubMed

    Saldaña-Ahuactzi, Zeus; Rodea, Gerardo E; Cruz-Córdova, Ariadnna; Rodríguez-Ramírez, Viridiana; Espinosa-Mazariego, Karina; González-Montalvo, Martín A; Ochoa, Sara A; González-Pedrajo, Bertha; Eslava-Campos, Carlos A; López-Villegas, Edgar O; Hernández-Castro, Rigoberto; Arellano-Galindo, José; Patiño-López, Genaro; Xicohtencatl-Cortes, Juan

    2016-01-01

    Enterotoxigenic Escherichia coli (ETEC) is a major cause of morbidity in children under 5 years of age in low- and middle-income countries and a leading cause of traveler's diarrhea worldwide. The ability of ETEC to colonize the intestinal epithelium is mediated by fimbrial adhesins, such as CS21 (Longus). This adhesin is a type IVb pilus involved in adherence to intestinal cells in vitro and bacterial self-aggregation. Fourteen open reading frames have been proposed to be involved in CS21 assembly, hitherto only the lngA and lngB genes, coding for the major (LngA) and minor (LngB) structural subunit, have been characterized. In this study, we investigated the role of the LngA, LngB, LngC, LngD, LngH, and LngP proteins in the assembly of CS21 in ETEC strain E9034A. The deletion of the lngA, lngB, lngC, lngD, lngH, or lngP genes, abolished CS21 assembly in ETEC strain E9034A and the adherence to HT-29 cells was reduced 90%, compared to wild-type strain. Subcellular localization prediction of CS21 proteins was similar to other well-known type IV pili homologs. We showed that LngP is the prepilin peptidase of LngA, and that ETEC strain E9034A has another peptidase capable of processing LngA, although with less efficiency. Additionally, we present immuno-electron microscopy images to show that the LngB protein could be localized at the tip of CS21. In conclusion, our results demonstrate that the LngA, LngB, LngC, LngD, LngH, and LngP proteins are essential for CS21 assembly, as well as for bacterial aggregation and adherence to HT-29 cells. PMID:27536289

  7. Effects of lng Mutations on LngA Expression, Processing, and CS21 Assembly in Enterotoxigenic Escherichia coli E9034A

    PubMed Central

    Saldaña-Ahuactzi, Zeus; Rodea, Gerardo E.; Cruz-Córdova, Ariadnna; Rodríguez-Ramírez, Viridiana; Espinosa-Mazariego, Karina; González-Montalvo, Martín A.; Ochoa, Sara A.; González-Pedrajo, Bertha; Eslava-Campos, Carlos A.; López-Villegas, Edgar O.; Hernández-Castro, Rigoberto; Arellano-Galindo, José; Patiño-López, Genaro; Xicohtencatl-Cortes, Juan

    2016-01-01

    Enterotoxigenic Escherichia coli (ETEC) is a major cause of morbidity in children under 5 years of age in low- and middle-income countries and a leading cause of traveler's diarrhea worldwide. The ability of ETEC to colonize the intestinal epithelium is mediated by fimbrial adhesins, such as CS21 (Longus). This adhesin is a type IVb pilus involved in adherence to intestinal cells in vitro and bacterial self-aggregation. Fourteen open reading frames have been proposed to be involved in CS21 assembly, hitherto only the lngA and lngB genes, coding for the major (LngA) and minor (LngB) structural subunit, have been characterized. In this study, we investigated the role of the LngA, LngB, LngC, LngD, LngH, and LngP proteins in the assembly of CS21 in ETEC strain E9034A. The deletion of the lngA, lngB, lngC, lngD, lngH, or lngP genes, abolished CS21 assembly in ETEC strain E9034A and the adherence to HT-29 cells was reduced 90%, compared to wild-type strain. Subcellular localization prediction of CS21 proteins was similar to other well-known type IV pili homologs. We showed that LngP is the prepilin peptidase of LngA, and that ETEC strain E9034A has another peptidase capable of processing LngA, although with less efficiency. Additionally, we present immuno-electron microscopy images to show that the LngB protein could be localized at the tip of CS21. In conclusion, our results demonstrate that the LngA, LngB, LngC, LngD, LngH, and LngP proteins are essential for CS21 assembly, as well as for bacterial aggregation and adherence to HT-29 cells. PMID:27536289

  8. Keys to modeling LNG spills on water.

    PubMed

    Hissong, D W

    2007-02-20

    Although no LNG ship has experienced a loss of containment in over 40 years of shipping, it is important for risk management planning to understand the predicted consequences of a spill. A key parameter in assessing the impact of an LNG spill is the pool size. LNG spills onto water generally result in larger pools than land spills because they are unconfined. Modeling of LNG spills onto water is much more difficult than for land spills because the phenomena are more complex and the experimental basis is more limited. The most prevalent practice in predicting pool sizes is to treat the release as instantaneous or constant-rate, and to calculate the pool size using an empirical evaporation or burn rate. The evaporation or burn rate is particularly difficult to estimate for LNG spills on water, because the available data are so limited, scattered, and difficult to extrapolate to the large releases of interest. A more effective modeling of possible spills of LNG onto water calculates, rather than estimating, the evaporation or burn rate. The keys to this approach are to: * Use rigorous multicomponent physical properties. * Use a time-varying analysis of spill and evaporation. * Use a material and energy balance approach. * Estimate the heat transfer from water to LNG in a way that reflects the turbulence. These keys are explained and demonstrated by predictions of a model that incorporates these features. The major challenges are describing the effects of the LNG-water turbulence and the heat transfer from the pool fire to the underlying LNG pool. The model includes a fundamentally based framework for these terms, and the current formulation is based on some of the largest tests to-date. The heat transfer coefficient between the water and LNG is obtained by applying a "turbulence factor" to the value from correlations for quiescent film and transition boiling. The turbulence factor is based on two of the largest unignited tests on water to-date. The heat transfer from

  9. 76 FR 73609 - Cameron LNG, LLC; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-29

    ... operate a boil-off gas (BOG) liquefaction system at its LNG import terminal in Cameron Parish, Louisiana... terminal to liquefy BOG and return such gas in the form of LNG to its storage tanks. Cameron states...

  10. 49 CFR 193.2019 - Mobile and temporary LNG facilities.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS General § 193.2019 Mobile and temporary LNG facilities. (a) Mobile and temporary LNG facilities for peakshaving application, for service maintenance... 49 Transportation 3 2014-10-01 2014-10-01 false Mobile and temporary LNG facilities....

  11. 49 CFR 193.2019 - Mobile and temporary LNG facilities.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS General § 193.2019 Mobile and temporary LNG facilities. (a) Mobile and temporary LNG facilities for peakshaving application, for service maintenance... 49 Transportation 3 2012-10-01 2012-10-01 false Mobile and temporary LNG facilities....

  12. 49 CFR 193.2019 - Mobile and temporary LNG facilities.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS General § 193.2019 Mobile and temporary LNG facilities. (a) Mobile and temporary LNG facilities for peakshaving application, for service maintenance... 49 Transportation 3 2013-10-01 2013-10-01 false Mobile and temporary LNG facilities....

  13. 49 CFR 193.2019 - Mobile and temporary LNG facilities.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS General § 193.2019 Mobile and temporary LNG facilities. (a) Mobile and temporary LNG facilities for peakshaving application, for service maintenance... 49 Transportation 3 2011-10-01 2011-10-01 false Mobile and temporary LNG facilities....

  14. 49 CFR 193.2019 - Mobile and temporary LNG facilities.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS General § 193.2019 Mobile and temporary LNG facilities. (a) Mobile and temporary LNG facilities for peakshaving application, for service maintenance... 49 Transportation 3 2010-10-01 2010-10-01 false Mobile and temporary LNG facilities....

  15. 78 FR 41047 - UGI LNG, Inc.; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-09

    ... Energy Regulatory Commission UGI LNG, Inc.; Notice of Application On June 17, 2013, UGI LNG, Inc. (UGI... Ontelaunee Township, Berks County, Pennsylvania. As more fully described in the application, the new.... Questions regarding this application may be directed to Frank H. Markle, Counsel for UGI LNG, by calling...

  16. 75 FR 26744 - Cameron LNG, LLC; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-12

    ... Energy Regulatory Commission Cameron LNG, LLC; Notice of Application May 5, 2010. On April 22, 2010, Cameron LNG, LLC filed with the Federal Energy Regulatory Commission (Commission) an application under... this application may be directed to William D. Rapp, Senior Regulatory Counsel at Cameron LNG, LLC,...

  17. Safety implications of a large LNG tanker spill over water.

    SciTech Connect

    Hightower, Marion Michael; Gritzo, Louis Alan; Luketa-Hanlin, Anay Josephine

    2005-04-01

    The increasing demand for natural gas in the United States could significantly increase the number and frequency of marine LNG (liquefied natural gas) imports. Although many studies have been conducted to assess the consequences and risks of potential LNG spills, the increasing importance of LNG imports suggests that consistent methods and approaches be identified and implemented to help ensure protection of public safety and property from a potential LNG spill. For that reason the U.S. Department of Energy (DOE), Office of Fossil Energy, requested that Sandia National Laboratories (Sandia) develop guidance on a risk-based analysis approach to assess and quantify potential threats to an LNG ship, the potential hazards and consequences of a large spill from an LNG ship, and review prevention and mitigation strategies that could be implemented to reduce both the potential and the risks of an LNG spill over water. Specifically, DOE requested: (1) An in-depth literature search of the experimental and technical studies associated with evaluating the safety and hazards of an LNG spill from an LNG ship; (2) A detailed review of four recent spill modeling studies related to the safety implications of a large-scale LNG spill over water; (3) Evaluation of the potential for breaching an LNG ship cargo tank, both accidentally and intentionally, identification of the potential for such breaches and the potential size of an LNG spill for each breach scenario, and an assessment of the potential range of hazards involved in an LNG spill; (4) Development of guidance on the use of modern, performance-based, risk management approaches to analyze and manage the threats, hazards, and consequences of an LNG spill over water to reduce the overall risks of an LNG spill to levels that are protective of public safety and property.

  18. 46 CFR 154.703 - Methane (LNG).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Methane (LNG). 154.703 Section 154.703 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR... system that meets § 154.702; (b) A waste heat or catalytic furnace that burns boil-off gas, and:...

  19. 46 CFR 154.703 - Methane (LNG).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Methane (LNG). 154.703 Section 154.703 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Cargo Pressure and Temperature Control § 154.703 Methane...

  20. U.S. LNG Imports - The Next Wave

    EIA Publications

    2007-01-01

    U.S. LNG imports - The Next Wave, is now available as a special supplement to the January 2007 issue of the Short-Term Energy Outlook (STEO). Although liquefied natural gas (LNG) imports still account for less than 3% of total U.S. natural gas supplies, the global market is growing and the Energy Information Administration (EIA) foresees another wave of U.S. LNG import growth over the next two years. The supplement focuses on recent trends in global and U.S. LNG trade, and presents factors expected to influence LNG imports through 2008. EIA expects year-over-year increases in LNG imports of 34.5% and 38.5% in 2007 and 2008, respectively.

  1. Beauty of Simplicity: Phillips Optimized Cascade LNG Liquefaction Process

    NASA Astrophysics Data System (ADS)

    Andress, D. L.; Watkins, R. J.

    2004-06-01

    Paper describes how use of single component refrigerants yields an LNG liquefaction process that is safe, simple to operate, easy to understand, and robust in reliability. The 34-year operating history of Kenai LNG has proven the inherent advantages of the Phillips Optimized Cascade LNG Process. The paper is written from an operational point of view, and describes basic design parameters and operation of the processes.

  2. Candidate Water Vapor Lines to Locate the H2O Snowline through High-dispersion Spectroscopic Observations. I. The Case of a T Tauri Star

    NASA Astrophysics Data System (ADS)

    Notsu, Shota; Nomura, Hideko; Ishimoto, Daiki; Walsh, Catherine; Honda, Mitsuhiko; Hirota, Tomoya; Millar, T. J.

    2016-08-01

    Inside the H2O snowline of protoplanetary disks, water evaporates from the dust-grain surface into the gas phase, whereas it is frozen out onto the dust in the cold region beyond the snowline. H2O ice enhances the solid material in the cold outer part of a disk, which promotes the formation of gas-giant planet cores. We can regard the H2O snowline as the surface that divides the regions between rocky and gaseous giant planet formation. Thus observationally measuring the location of the H2O snowline is crucial for understanding the planetesimal and planet formation processes, and the origin of water on Earth. In this paper, we find candidate water lines to locate the H2O snowline through future high-dispersion spectroscopic observations. First, we calculate the chemical composition of the disk and investigate the abundance distributions of H2O gas and ice, and the position of the H2O snowline. We confirm that the abundance of H2O gas is high not only in the hot midplane region inside the H2O snowline but also in the hot surface layer of the outer disk. Second, we calculate the H2O line profiles and identify those H2O lines that are promising for locating the H2O snowline: the identified lines are those that have small Einstein A coefficients and high upper state energies. The wavelengths of the candidate H2O lines range from mid-infrared to sub-millimeter, and they overlap with the regions accessible to the Atacama Large Millimeter/sub-millimeter Array and future mid-infrared high-dispersion spectrographs (e.g., TMT/MICHI, SPICA).

  3. Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report

    SciTech Connect

    1980-10-01

    Volume 2 consists of 19 reports describing technical effort performed by Government Contractors in the area of LNG Safety and Environmental Control. Report topics are: simulation of LNG vapor spread and dispersion by finite element methods; modeling of negatively buoyant vapor cloud dispersion; effect of humidity on the energy budget of a liquefied natural gas (LNG) vapor cloud; LNG fire and explosion phenomena research evaluation; modeling of laminar flames in mixtures of vaporized liquefied natural gas (LNG) and air; chemical kinetics in LNG detonations; effects of cellular structure on the behavior of gaseous detonation waves under transient conditions; computer simulation of combustion and fluid dynamics in two and three dimensions; LNG release prevention and control; the feasibility of methods and systems for reducing LNG tanker fire hazards; safety assessment of gelled LNG; and a four band differential radiometer for monitoring LNG vapors.

  4. 49 CFR 193.2623 - Inspecting LNG storage tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Inspecting LNG storage tanks. 193.2623 Section 193.2623 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS... GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2623 Inspecting LNG storage tanks. Each...

  5. 49 CFR 193.2623 - Inspecting LNG storage tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Inspecting LNG storage tanks. 193.2623 Section 193.2623 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS... GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2623 Inspecting LNG storage tanks. Each...

  6. 78 FR 20312 - Downeast LNG, Inc., Downeast Pipeline, LLC.; Notice of Availability of the Supplemental Draft...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-04

    ... Energy Regulatory Commission Downeast LNG, Inc., Downeast Pipeline, LLC.; Notice of Availability of the Supplemental Draft Environmental Impact Statement for the Proposed Downeast LNG Project The staff of the... Impact Statement (EIS) for the Downeast LNG Project, proposed by Downeast LNG, Inc. and Downeast...

  7. 75 FR 51989 - Southern LNG Company, L.L.C.; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-24

    ... Energy Regulatory Commission Southern LNG Company, L.L.C.; Notice of Application August 16, 2010. Take notice that on August 4, 2010, Southern LNG Company, L.L.C. (Southern LNG), Post Office Box 2563... Regulatory, Southern LNG Company, L.L.C., 569 Brookwood Village, Suite 501, Birmingham, Alabama 35209 at...

  8. Submarine LNG tanker concept for the Arctic

    SciTech Connect

    Veliotis, P.T.; Reitz, S.

    1981-01-01

    If LNG tankers could travel underwater, they could transport natural gas from Arctic regions year-round. General Dynamics has designed just such a tanker - a 140,000-m/sup 3/ submarine with a methane-fired steam-propulsion system that uses recirculated exhaust gas injected with oxygen to sustain combustion. (Nuclear power would be cheaper but might not be practical if new regulations are imposed.) Developed from parametric variations in cargo capacity, hull material, and ballasting, the design identifies such ship characteristics as length, beam, depth, cargo-system arrangement, speed, and ship control. An economic analysis indicates the concept's competitiveness with both pipelines and icebreaking tankers.

  9. Get accurate LNG densities with COSTALD

    SciTech Connect

    Hankinson, R.W.; Coker, T.A.; Thomson, G.H.

    1982-04-01

    A fine-tuned version of the COSTALD correlation predicts the densities for 40 LNG-type mixtures at an average absolute error of 0.078%. When tested against 285 points of low-temperature data collected by the US National Bureau of Standards, the average error was 0.199%, compared with a 0.227% error obtained with the NBS's McCarty-Klosek-McKinley technique. The COSTALD correlation relates the saturated molar volume of a liquid to a characteristic volume, the reduced temperature, and, a modified acentric factor for each stream component. The fine-tuning involved adding several interaction parameters dervied from binary density data.

  10. Leak response gelling of liquefied natural gas (LNG). Final report Jan-Oct 81

    SciTech Connect

    Tarpley, W.B. Jr; Twesme, E.N.; Zatko, J.R.

    1981-03-01

    Techniques for thixotropic gelling of liquefied natural gas (LNG) in response to leak or rupture in an LNG container were examined, and the hazard-reducing potential of the technique was demonstrated by limiting mobility and reducing evaporation and burning rate. Of 30 candidate gelants for liquefied methane evaluated, gels of highest yield stress and lowest evaporation rate were obtained with carbon blacks and pyrogenic silica, and means were investigated for reducing the volume requirements of these low bulk-density materials; these included the addition of a surfactant, gelant concentration in a liquid carrier at least partially soluble in methane, and pelletization. All of these techniques showed promise, and pelletization of the low-density gelants reduced required gelant volume to 11 percent of the undensified volume. High-shear mixing of the densified gelants as well as of high-density gelants such as bentonite clay into a methane homolog at room temperature improved the speed of gelation. Other dispersion techniques were investigated. It is recommended that future research optimize gelling and dispersion techniques for industry use and develop hardware designs for long-term gelant storage and rapid introduction in the event of spillage.

  11. Particle- and Gaseous Emissions from an LNG Powered Ship.

    PubMed

    Anderson, Maria; Salo, Kent; Fridell, Erik

    2015-10-20

    Measurements of particle number and mass concentrations and number size distribution of particles from a ship running on liquefied natural gas (LNG) were made on-board a ship with dual-fuel engines installed. Today there is a large interest in LNG as a marine fuel, as a means to comply with sulfur and NOX regulations. Particles were studied in a wide size range together with measurements of other exhaust gases under different engine loads and different mixtures of LNG and marine gas oil. Results from these measurements show that emissions of particles, NOX, and CO2 are considerably lower for LNG compared to present marine fuel oils. Emitted particles were mainly of volatile character and mainly had diameters below 50 nm. Number size distribution for LNG showed a distinct peak at 9-10 nm and a part of a peak at diameter 6 nm and below. Emissions of total hydrocarbons and carbon monoxide are higher for LNG compared to present marine fuel oils, which points to the importance of considering the methane slip from combustion of LNG. PMID:26422536

  12. Adapting British gas LNG facilities to varying gas compositions: The SELEXOL {reg_sign} process and cryogenic separation

    SciTech Connect

    Dewing, R.A.; Waring, S.; Burns, D.

    1996-12-31

    The original design of the UK National Transmission System (NTS) included five peak shave LNG storage sites strategically located around the country. They now form part of the Storage business that offers gas services to gas transportation companies-these include non British Gas companies as well as other parts of British Gas itself. At these sites, natural gas can be taken from the NTS at the request of the gas transportation companies, treated to cryogenic specifications, and liquefied for storage. LNG can then be re-vaporized and re-injected into the NTS or local mains as required. In this way the whole NTS does not have to be sized for peak rates and increases in demand can be met very quickly. Each peak-shave site was originally designed to handle natural gas with CO{sub 2} levels of up to 1 mol% and with ethane and higher hydrocarbon (C{sub 2}+) levels that needed only limited reduction. However, as different natural gas reservoirs came on stream in the early 1990`s the level of CO{sub 2} and C{sub 2}+ in the NTS network began to rise, and significant modifications were required at four of the five LNG sites. 3 refs., 2 figs., 2 tabs.

  13. Vapor-phase photo-oxidation of methanol over nano-size titanium dioxide clusters dispersed in MCM-41 host material part 2: catalytic properties and surface transient species.

    PubMed

    Bhattacharyya, K; Varma, S; Kumar, D; Tripathi, A K; Gupta, N M

    2005-05-01

    We report in this paper on the ultraviolet-assisted vapor-phase oxidation of methanol at room temperature, with the help of nano-size clusters of titanium dioxide dispersed in an MCM-41 silicate matrix. The surface species formed during the adsorption/oxidation of methanol and the transformation that they undergo as a result of ultraviolet irradiation were monitored using in-situ Fourier transform infrared and thermal desorption spectroscopy techniques. Parallel experiments conducted on TiO2/MCM, bulk titania, and pristine MCM-41 samples helped in identifying the individual role of titanium dioxide and host matrix in these processes. The photo-catalytic oxidation of methanol, at concentrations of 0.1 to 1.1 mol% in air, gave rise to formation of CO2 and H2O as products, for both the TiO2/MCM and bulk TiO2 samples. No such reaction occurred on titania-free MCM. Furthermore, the rate of reaction depended upon the TiO2 content of a sample and also on the concentration of methanol in reaction mixture. Thus, the rate of conversion increased progressively with the increase in TiO2 loading from 5 to 21 wt% in TiO2/MCM samples, particularly for the experiments with high concentration of methanol. For low methanol concentration (0.1 mol%) in air, the effect of titania content in MCM was very small. The specific activity (per g of titania) of a sample, on the other hand, showed an inverse relationship with the loading of titanium dioxide in a sample. Infrared and temperature-programmed desorption results revealed that the mode of CH3OH adsorption and the reactivity of the transient species formed during the oxidation process were independent of the size of dispersed titania particles. Thus, the particles of approximately 2-6 nm size, present in TiO2/MCM, exhibited a chemisorption behavior similar to that of the bulk titania. The results of the present study provide strong evidence that the hydroxyl groups, both on the host matrix and at the titania sites, participate

  14. Topsides equipment, operating flexibility key floating LNG design

    SciTech Connect

    Yost, K.; Lopez, R.; Mok, J.

    1998-03-09

    Use of a large-scale floating liquefied natural gas (LNG) plant is an economical alternative to an onshore plant for producing from an offshore field. Mobil Technology Co., Dallas, has advanced a design for such a plant that is technically feasible, economical, safe, and reliable. Presented were descriptions of the general design basis, hull modeling and testing, topsides and storage layouts, and LNG offloading. But such a design also presents challenges for designing topsides equipment in an offshore environment and for including flexibility and safety. These are covered in this second article. Mobil`s floating LNG plant design calls for a square concrete barge with a moon-pool in the center. It is designed to produce 6 million tons/year of LNG with up to 55,000 b/d of condensate from 1 bcfd of raw feed gas.

  15. The Phoenix series large scale LNG pool fire experiments.

    SciTech Connect

    Simpson, Richard B.; Jensen, Richard Pearson; Demosthenous, Byron; Luketa, Anay Josephine; Ricks, Allen Joseph; Hightower, Marion Michael; Blanchat, Thomas K.; Helmick, Paul H.; Tieszen, Sheldon Robert; Deola, Regina Anne; Mercier, Jeffrey Alan; Suo-Anttila, Jill Marie; Miller, Timothy J.

    2010-12-01

    The increasing demand for natural gas could increase the number and frequency of Liquefied Natural Gas (LNG) tanker deliveries to ports across the United States. Because of the increasing number of shipments and the number of possible new facilities, concerns about the potential safety of the public and property from an accidental, and even more importantly intentional spills, have increased. While improvements have been made over the past decade in assessing hazards from LNG spills, the existing experimental data is much smaller in size and scale than many postulated large accidental and intentional spills. Since the physics and hazards from a fire change with fire size, there are concerns about the adequacy of current hazard prediction techniques for large LNG spills and fires. To address these concerns, Congress funded the Department of Energy (DOE) in 2008 to conduct a series of laboratory and large-scale LNG pool fire experiments at Sandia National Laboratories (Sandia) in Albuquerque, New Mexico. This report presents the test data and results of both sets of fire experiments. A series of five reduced-scale (gas burner) tests (yielding 27 sets of data) were conducted in 2007 and 2008 at Sandia's Thermal Test Complex (TTC) to assess flame height to fire diameter ratios as a function of nondimensional heat release rates for extrapolation to large-scale LNG fires. The large-scale LNG pool fire experiments were conducted in a 120 m diameter pond specially designed and constructed in Sandia's Area III large-scale test complex. Two fire tests of LNG spills of 21 and 81 m in diameter were conducted in 2009 to improve the understanding of flame height, smoke production, and burn rate and therefore the physics and hazards of large LNG spills and fires.

  16. Vaporizer performance

    NASA Astrophysics Data System (ADS)

    Liu, C. H.; Perez-Ortiz, B. M.; Whitelaw, J. H.

    This paper examines the nature of the flow leaving a vaporizer, its dependence on the flowrates of air and kerosene fuel, the inlet air temperature, and the possible consequences for the performance of a combustor fueled by the vaporizer. A phase Doppler velocimeter was used to examine the distribution of droplet diameters, velocities of the droplets, and the liquid-fuel flux at the exit. Measurements are also reported which show the nature of the two-phase flow away from the vaporizer exits and in important regions within a combustor corresponding to a one-sixth annular sector of a reverse-flow arrangement. The distribution of droplets within the combustor was observed and photographs of the combusting flow are presented.

  17. Vapor fragrancer

    NASA Astrophysics Data System (ADS)

    Sang, Q. Tran; Bryant, Timothy D.

    1987-05-01

    This invention relates to a vapor fragrancer for continuously, uniformly, and economically odorizing or deodorizing an environment. Homes, offices, automobiles, and space stations require either odorizing or deodorizing of the atmosphere to create pleasant conditions for work or leisure. A vapor fragrancer is provided to accomplish these goals. A supplier continuously supplies a predetermined amount of desired liquid fragrance from a container to a retaining material, which is positioned in the circulation path of the atmosphere. The supplier is either a low powered pump or a gravity dispenser. The atmosphere flowing in a circulation path passes over the retaining material containing the liquid fragrance and lifts a fragrant vapor from the retaining material. The atmosphere is thereby continuously and uniformly fragranced.

  18. The Asia Pacific LNG trade: Status and technology development

    SciTech Connect

    Hovdestad, W.R.

    1995-10-01

    The Asia Pacific Region is experiencing a period of sustained economic expansion. Economic growth has led to an increasing demand for energy that has spurred a rapid expansion of baseload liquefied natural gas (LNG) facilities in this region. This is illustrated by the fact that seven of the ten baseload facilities in existence provide LNG for markets in the Asia Pacific region. With the three exceptions having been initially commissioned in 1972 and earlier, it is fair to observed that most advances in LNG technology have been developed and applied for this market. The paper presents the current status and identified future trends for the Asia Pacific LNG trade. Technology development in terms of application to onstream production, processing and transportation facilities, including LNG tankers, is presented. The potential of future advances to applied technology and operational practices to improve the cost-effectiveness of new and existing facilities is discussed. Current design data and methods as actually used are examined in terms of identifying where fundamental research and basic physical data are insufficient for optimization purposes. These findings are then summarized and presented in terms of the likely evolution of future and existing LNG projects in the Asia Pacific region.

  19. LNG Safety Research: FEM3A Model Development

    SciTech Connect

    2006-09-30

    The initial scope of work for this project included: 1) Improving the FEM3A advanced turbulence closure module, 2) Adaptation of FEM3A for more general applications, and 3) Verification of dispersion over rough surfaces, with and without obstacle using the advanced turbulence closure module. These work elements were to be performed by Chemical Hazards Research Center (CHRC), Department of Chemical Engineering, University of Arkansas as a subcontractor to Gas Technology Institute (GTI). The tasks for GTI included establishment of the scientific support base for standardization of the FEM3A model, project management, technology transfer, and project administration. Later in the course of the project, the scope of work was modified by the National Energy Technology Laboratories (NETL) to remove the emphasis on FEM3A model and instead, develop data in support of NETL’s FLUENT modeling. With this change, GTI was also instructed to cease activities relative to FEM3A model. GTI’s technical activities through this project included the initial verification of FEM3A model, provision of technical inputs to CHRC researchers regarding the structure of the final product, and participation in technical discussion sessions with CHRC and NETL technical staff. GTI also began the development of a Windows-based front end for the model but the work was stopped due to the change in scope of work. In the meantime, GTI organized a workshop on LNG safety in Houston, Texas. The workshop was very successful and 75 people from various industries participated. All technical objectives were met satisfactorily by Dr. Jerry Havens and Dr. Tom Spicer of CHRC and results are presented in a stand-alone report included as Appendix A to this report.

  20. LNG Safety Research: FEM3A Model Development

    SciTech Connect

    Iraj A. Salehi; Jerry Havens; Tom Spicer

    2006-09-30

    The initial scope of work for this project included: (1) Improving the FEM3A advanced turbulence closure module, (2) Adaptation of FEM3A for more general applications, and (3) Verification of dispersion over rough surfaces, with and without obstacle using the advanced turbulence closure module. These work elements were to be performed by Chemical Hazards Research Center (CHRC), Department of Chemical Engineering, University of Arkansas as a subcontractor to Gas Technology Institute (GTI). The tasks for GTI included establishment of the scientific support base for standardization of the FEM3A model, project management, technology transfer, and project administration. Later in the course of the project, the scope of work was modified by the National Energy Technology Laboratories (NETL) to remove the emphasis on FEM3A model and instead, develop data in support of NETL's FLUENT modeling. With this change, GTI was also instructed to cease activities relative to FEM3A model. GTI's technical activities through this project included the initial verification of FEM3A model, provision of technical inputs to CHRC researchers regarding the structure of the final product, and participation in technical discussion sessions with CHRC and NETL technical staff. GTI also began the development of a Windows-based front end for the model but the work was stopped due to the change in scope of work. In the meantime, GTI organized a workshop on LNG safety in Houston, Texas. The workshop was very successful and 75 people from various industries participated. All technical objectives were met satisfactorily by Dr. Jerry Havens and Dr. Tom Spicer of CHRC and results are presented in a stand-alone report included as Appendix A to this report.

  1. LNG cascading damage study. Volume I, fracture testing report.

    SciTech Connect

    Petti, Jason P.; Kalan, Robert J.

    2011-12-01

    As part of the liquefied natural gas (LNG) Cascading Damage Study, a series of structural tests were conducted to investigate the thermal induced fracture of steel plate structures. The thermal stresses were achieved by applying liquid nitrogen (LN{sub 2}) onto sections of each steel plate. In addition to inducing large thermal stresses, the lowering of the steel temperature simultaneously reduced the fracture toughness. Liquid nitrogen was used as a surrogate for LNG due to safety concerns and since the temperature of LN{sub 2} is similar (-190 C) to LNG (-161 C). The use of LN{sub 2} ensured that the tests could achieve cryogenic temperatures in the range an actual vessel would encounter during a LNG spill. There were four phases to this test series. Phase I was the initial exploratory stage, which was used to develop the testing process. In the Phase II series of tests, larger plates were used and tested until fracture. The plate sizes ranged from 4 ft square pieces to 6 ft square sections with thicknesses from 1/4 inches to 3/4 inches. This phase investigated the cooling rates on larger plates and the effect of different notch geometries (stress concentrations used to initiate brittle fracture). Phase II was divided into two sections, Phase II-A and Phase II-B. Phase II-A used standard A36 steel, while Phase II-B used marine grade steels. In Phase III, the test structures were significantly larger, in the range of 12 ft by 12 ft by 3 ft high. These structures were designed with more complex geometries to include features similar to those on LNG vessels. The final test phase, Phase IV, investigated differences in the heat transfer (cooling rates) between LNG and LN{sub 2}. All of the tests conducted in this study are used in subsequent parts of the LNG Cascading Damage Study, specifically the computational analyses.

  2. 33 CFR 127.105 - Layout and spacing of marine transfer area for LNG.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... spacing of marine transfer area for LNG. (a) LNG impounding spaces must be located so that the heat flux... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Layout and spacing of marine transfer area for LNG. 127.105 Section 127.105 Navigation and Navigable Waters COAST GUARD, DEPARTMENT...

  3. 33 CFR 127.105 - Layout and spacing of marine transfer area for LNG.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... spacing of marine transfer area for LNG. (a) LNG impounding spaces must be located so that the heat flux... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Layout and spacing of marine transfer area for LNG. 127.105 Section 127.105 Navigation and Navigable Waters COAST GUARD, DEPARTMENT...

  4. 33 CFR 127.105 - Layout and spacing of marine transfer area for LNG.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... spacing of marine transfer area for LNG. (a) LNG impounding spaces must be located so that the heat flux... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Layout and spacing of marine transfer area for LNG. 127.105 Section 127.105 Navigation and Navigable Waters COAST GUARD, DEPARTMENT...

  5. 75 FR 2126 - Calais Pipeline Company, LLC; Calais LNG Project Company, LLC; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-14

    ... Energy Regulatory Commission Calais Pipeline Company, LLC; Calais LNG Project Company, LLC; Notice of Application January 6, 2010. Take notice that on December 18, 2009, Calais LNG Project Company, LLC (Calais LNG) and Calais Pipeline Company, LLC (Calais Pipeline) 142 ] Main Street, P.O. Box 133, Calais,...

  6. 33 CFR 127.703 - Access to the marine transfer area for LNG.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... area for LNG. 127.703 Section 127.703 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF... Access to the marine transfer area for LNG. The operator shall ensure that— (a) Access to the marine transfer area for LNG from the shoreside and the waterside is limited to— (1) Personnel who work at...

  7. 33 CFR 127.703 - Access to the marine transfer area for LNG.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... area for LNG. 127.703 Section 127.703 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF... Access to the marine transfer area for LNG. The operator shall ensure that— (a) Access to the marine transfer area for LNG from the shoreside and the waterside is limited to— (1) Personnel who work at...

  8. 75 FR 54025 - Revision of LNG and LHG Waterfront Facility General Requirements

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-03

    ... final rule entitled ``Revision of LNG and LHG Waterfront Facility General Requirements'' (75 FR 29420... SECURITY Coast Guard 33 CFR Part 127 RIN 1625-AB13 Revision of LNG and LHG Waterfront Facility General... (WSA) requirements for liquefied natural gas (LNG) and liquefied hazardous gas (LHG) facilities....

  9. 76 FR 81925 - Freeport LNG Development, L.P.; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-29

    ... Energy Regulatory Commission Freeport LNG Development, L.P.; Notice of Application Take notice that on December 9, 2011, Freeport LNG Development, L.P. (Freeport LNG), filed an application pursuant to Section 3..., Fulbright & Jaworski L.L.P., 666 Fifth Avenue, New York, New York 10103. Telephone (212) 318-3009, fax...

  10. 75 FR 74029 - Sabine Pass LNG, L.P.; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-30

    ... Energy Regulatory Commission Sabine Pass LNG, L.P.; Notice of Application November 22, 2010. Take notice that on November 12, 2010, Sabine Pass LNG, L.P. (Sabine Pass), 700 Milam Street, Suite 800, Houston... directed to Patricia Outtrim, Sabine Pass LNG, L.P., 700 Milam Street, Suite 800, Houston, Texas 77002,...

  11. 75 FR 53688 - Southern LNG Company, L.L.C.; Notice of Technical Conference

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-01

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Southern LNG Company, L.L.C.; Notice of Technical Conference August 25, 2010..., Southern LNG Company, L.L.C. (Southern LNG) filed a tariff sheet to revise its tariff with respect to...

  12. 77 FR 788 - Southern LNG Company, L.L.C.; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-01-06

    ... Energy Regulatory Commission Southern LNG Company, L.L.C.; Notice of Application Take notice that on December 15, 2011, Southern LNG Company, L.L.C. (SLNG), 569 Brookwood Village, Suite 501, Birmingham... should be directed to Glenn A. Sheffield, Director, Rates & Regulatory Affairs, Southern LNG Company,...

  13. Floating LNG plant will stress reliability and safety

    SciTech Connect

    Kinney, C.D.; Schulz, H.R.; Spring, W.

    1997-07-01

    Mobil has developed a unique floating LNG plant design after extensive studies that set safety as the highest priority. The result is a production, storage and offloading platform designed to produce 6 million tons per year of LNG and up to 55,000 bpd of condensate from 1 Bcfd of feed gas. All production and off-loading equipment is supported by a square donut-shaped concrete hull, which is spread-moored. The hull contains storage tanks for 250,000 m{sup 3} of LNG, 6540,000 bbl of condensate and ballast water. Both LNG and condensate can be directly offloaded to shuttle tankers. Since the plant may be moved to produce from several different gas fields during its life, the plant and barge were designed to be generic. It can be used at any location in the Pacific Rim, with up to 15% CO{sub 2}, 100 ppm H{sub 2}S, 55 bbl/MMcf condensate and 650 ft water depth. It can be modified to handle other water depths, depending upon the environment. In addition, it is much more economical than an onshore grassroots LNG plant, with potential capital savings of 25% or more. The paper describes the machinery, meteorology and oceanography, and safety engineering.

  14. Insulating polymer concrete for LNG impounding dikes. [Polymer concretes

    SciTech Connect

    Fontana, J.J.; Steinberg, M.

    1986-03-01

    An insulating polymer concrete (IPC) composite has been developed under contract to the Gas Research Institute for possible use as a dike insulation material at Liquid Natural Gas (LNG) storage facilities. In the advent of an LNG spill into the impounding dike area, the boiloff rate of the LNG can be substantially reduced if the surfaces of the dike are insulated. This increased safety at the LNG facility will tend to reduce the hazardous explosive mixture with atmospheric air in the surrounding region. The dike insulation material must have a low thermal conductivity and be unaffected by environmental conditions. The IPC composites developed consist of perlite or glass nodule aggregates bound together as a closed cell structure with a polyester resin. In addition to low thermal conductivity and porosity, these composites have correspondingly high strengths and, therefore, can carry transient loads of workmen and maintenance equipment. Prefabricated IPC panels have been installed experimentally and at least one utility is currently considering a complete installation at its LNG facility. 5 refs., 5 tabs.

  15. Overview study of LNG release prevention and control systems

    SciTech Connect

    Pelto, P.J.; Baker, E.G.; Holter, G.M.; Powers, T.B.

    1982-03-01

    The liquefied natural gas (LNG) industry employs a variety of release prevention and control techniques to reduce the likelihood and the consequences of accidental LNG releases. A study of the effectiveness of these release prevention and control systems is being performed. Reference descriptions for the basic types of LNG facilities were developed. Then an overview study was performed to identify areas that merit subsequent and more detailed analyses. The specific objectives were to characterize the LNG facilities of interest and their release prevention and control systems, identify possible weak links and research needs, and provide an analytical framework for subsequent detailed analyses. The LNG facilities analyzed include a reference export terminal, marine vessel, import terminal, peakshaving facility, truck tanker, and satellite facility. A reference description for these facilities, a preliminary hazards analysis (PHA), and a list of representative release scenarios are included. The reference facility descriptions outline basic process flows, plant layouts, and safety features. The PHA identifies the important release prevention operations. Representative release scenarios provide a format for discussing potential initiating events, effects of the release prevention and control systems, information needs, and potential design changes. These scenarios range from relatively frequent but low consequence releases to unlikely but large releases and are the principal basis for the next stage of analysis.

  16. Oil dispersants

    SciTech Connect

    Flaherty, L.M.

    1989-01-01

    This book contains papers presented at a symposium of the American Society for Testing and Materials. The topics covered include: The effect of elastomers on the efficiency of oil spill dispersants; planning for dispersant use; field experience with dispersants for oil spills on land; and measurements on natural dispersion.

  17. Impact Vaporization of Planetesimal Cores

    NASA Astrophysics Data System (ADS)

    Kraus, R. G.; Root, S.; Lemke, R. W.; Stewart, S. T.; Jacobsen, S. B.; Mattsson, T. R.

    2013-12-01

    The degree of mixing and chemical equilibration between the iron cores of planetesimals and the mantle of the growing Earth has important consequences for understanding the end stages of Earth's formation and planet formation in general. At the Sandia Z machine, we developed a new shock-and-release technique to determine the density on the liquid-vapor dome of iron, the entropy on the iron shock Hugoniot, and the criteria for shock-induced vaporization of iron. We find that the critical shock pressure to vaporize iron is 507(+65,-85) GPa and show that decompression from a 15 km/s impact will initiate vaporization of iron cores, which is a velocity that is readily achieved at the end stages of planet formation. Vaporization of the iron cores increases dispersal of planetesimal cores, enables more complete chemical equilibration of the planetesimal cores with Earth's mantle, and reduces the highly siderophile element abundance on the Moon relative to Earth due to the expanding iron vapor exceeding the Moon's escape velocity. Sandia National Laboratories is a multiprogram laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Securities Administration under Contract No. DE-AC04-94AL85000.

  18. 75 FR 20591 - AES Sparrows Point LNG, LLC and Mid-Atlantic Express, LLC; Notice of Final General Conformity...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-04-20

    ... General Conformity Determination for Pennsylvania for the Proposed Sparrows Point LNG Terminal and... liquefied natural gas (LNG) import terminal and natural gas pipeline proposed by AES Sparrows Point LNG, LLC... quality impacts from the construction and operation of the following LNG terminal and natural gas...

  19. Hawaii energy strategy project 2: Fossil energy review. Task 3 -- Greenfield options: Prospects for LNG use

    SciTech Connect

    Breazeale, K.; Fesharaki, F.; Fridley, D.; Pezeshki, S.; Wu, K.

    1993-12-01

    This paper begins with an overview of the Asia-Pacific LNG market, its major players, and the likely availability of LNG supplies in the region. The discussion then examines the possibilities for the economic supply of LNG to Hawaii, the potential Hawaiian market, and the viability of an LNG project on Oahu. This survey is far from a complete technical assessment or an actual engineering/feasibility study. The economics alone cannot justify LNG`s introduction. The debate may continue as to whether fuel diversification and environmental reasons can outweigh the higher costs. Several points are made. LNG is not a spot commodity. Switching to LNG in Hawaii would require a massive, long-term commitment and substantial investments. LNG supplies are growing very tight in the Asia-Pacific region. Some of the environmental benefits of LNG are not entirely relevant in Hawaii because Hawaii`s air quality is generally excellent. Any air quality benefits may be more than counterbalanced by the environmental hazards connected with large-scale coastal zone construction, and by the safety hazards of LNG carriers, pipelines, etc. Lastly, LNG is not suitable for all energy uses, and is likely to be entirely unsuitable for neighbor island energy needs.

  20. Comparison of CNG and LNG technologies for transportation applications

    SciTech Connect

    Sinor, J.E. Consultants, Inc., Niwot, CO )

    1992-01-01

    This report provides a head-to-head comparison of compressed natural gas (CNG) and liquefied natural gas (LNG) supplied to heavy-duty vehicles. The comparison includes an assessment of the overall efficiency of the fuel delivery system, the cost of the fuel supply system, the efficiency of use in heavy-duty vehicles, and the environmental impact of each technology. The report concludes that there are applications in which CNG will have the advantage, and applications in which LNG will be preferred.

  1. Monitoring, safety systems for LNG and LPG operators

    SciTech Connect

    True, W.R.

    1998-11-16

    Operators in Korea and Australia have chosen monitoring and control systems in recent contracts for LNG and LPG storage. Korea Gas Corp. (Kogas) has hired Whessoe Varec, Calais, to provide monitoring systems for four LNG storage tanks being built at Kogas` Inchon terminal. For Elgas Ltd., Port Botany, Australia, Whessoe Varec has already shipped a safety valve-shutdown system to a new LPG cavern-storage facility under construction. The paper describes the systems, terminal monitoring, dynamic approach to tank management, and meeting the growing demand for LPG.

  2. Analysis of LNG peakshaving-facility release-prevention systems

    SciTech Connect

    Pelto, P.J.; Baker, E.G.; Powers, T.B.; Schreiber, A.M.; Hobbs, J.M.; Daling, P.M.

    1982-05-01

    The purpose of this study is to provide an analysis of release prevention systems for a reference LNG peakshaving facility. An overview assessment of the reference peakshaving facility, which preceeded this effort, identified 14 release scenarios which are typical of the potential hazards involved in the operation of LNG peakshaving facilities. These scenarios formed the basis for this more detailed study. Failure modes and effects analysis and fault tree analysis were used to estimate the expected frequency of each release scenario for the reference peakshaving facility. In addition, the effectiveness of release prevention, release detection, and release control systems were evaluated.

  3. Pressure Build-Up in LNG and LH2 Vehicular Cryogenic Storage Tanks

    NASA Astrophysics Data System (ADS)

    Barclay, J. A.; Rowe, A. M.; Barclay, M. A.

    2004-06-01

    The use of LNG and LH2 as fuels in heavy duty vehicles is increasing steadily because cryogenic liquids provides superior volumetric and gravimetric energy densities compared to other means of on-board storage. Although several sizes and types of tanks exist, a typical vehicular storage tank has a volume of ˜400 liters (˜100 gallons). The pressure in the ullage space of a tank freshly filled is usually ˜0.25 MPa but may vary during use from ˜0.25 MPa (˜20 psig) to ˜0.92 MPa (˜120 psig). Cryogenic vehicular tanks are typically dual-walled, stainless steel vessels with vacuum and superinsulation isolation between the inner and outer vessel walls. The heat leaks into such tanks are measured as a percentage boil-off per day. For a storage tank of vehicular size range, the boil-off may be ˜ 1 % day, depending upon the cryogen and the quality of the tank. The corresponding heat leak into the cryogenic liquid vaporizes a certain amount of liquid that in turn increases the pressure in the tank which in turn significantly influences the properties of the cryogens. We have used a novel approach to calculate the increase in pressure of LNG and LH2 in a closed cryogenic vessel with a fixed heat leak as a function of time using real equations of state for the properties of the cryogens. The method and results for the time it takes for a freshly filled tank to increase in pressure from the filling pressure of ˜0.25 MPa to a venting pressure of ˜1.73 MPa are presented.

  4. A review of recent field tests and mathematical modelling of atmospheric dispersion of large spills of Denser-than-air gases

    NASA Astrophysics Data System (ADS)

    Koopman, Ronald P.; Ermak, Donald L.; Chan, Stevens T.

    Large-scale spills of hazardous materials often produce gas clouds which are denser than air. The dominant physical processes which occur during dense-gas dispersion are very different from those recognized for trace gas releases in the atmosphere. Most important among these processes are stable stratification and gravity flow. Dense-gas flows displace the ambient atmospheric flow and modify ambient turbulent mixing. Thermodynamic and chemical reactions can also contribute to dense-gas effects. Some materials flash to aerosol and vapor when released and the aerosol can remain airborne, evaporating as it moves downwind, causing the cloud to remain cold and dense for long distances downwind. Dense-gas dispersion models, which include phase change and terrain effects have been developed and are capable of simulating many possible accidental releases. A number of large-scale field tests with hazardous materials such as liquefied natural gas (LNG), ammonia (NH 3), hydrofluoric acid(HF) and nitrogen tetroxide(N 2O 4) have been performed and used to evaluate models. The tests have shown that gas concentrations up to ten times higher than those predicted by trace gas models can occur due to aerosols and other dense-gas effects. A methodology for model evaluation has been developed which is based on the important physical characteristics of dense-gas releases.

  5. 76 FR 53425 - Pivotal LNG, Inc.; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-26

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Pivotal LNG, Inc.; Notice of Application Take notice that on August 8, 2011... Federal Energy Regulatory Commission (Commission) an application under section 7(c) of the Natural Gas...

  6. 49 CFR 193.2181 - Impoundment capacity: LNG storage tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Design Impoundment Design and Capacity § 193.2181... minimum volumetric liquid impoundment capacity of: (a) 110 percent of the LNG tank's maximum liquid... largest tank's maximum liquid capacity, whichever is greater, for the impoundment serving more than...

  7. 49 CFR 193.2181 - Impoundment capacity: LNG storage tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Design Impoundment Design and Capacity § 193.2181... minimum volumetric liquid impoundment capacity of: (a) 110 percent of the LNG tank's maximum liquid... largest tank's maximum liquid capacity, whichever is greater, for the impoundment serving more than...

  8. 49 CFR 193.2181 - Impoundment capacity: LNG storage tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Design Impoundment Design and Capacity § 193.2181... minimum volumetric liquid impoundment capacity of: (a) 110 percent of the LNG tank's maximum liquid... largest tank's maximum liquid capacity, whichever is greater, for the impoundment serving more than...

  9. Fire performance of LNG carriers insulated with polystyrene foam.

    PubMed

    Havens, Jerry; Venart, James

    2008-10-30

    Analysis of the response of a liquid-full Moss Sphere LNG tank insulated with polystyrene foam to an engulfing LNG fire indicates that current regulatory requirements for pressure relief capacity sufficient to prevent tank rupture are inadequate. The inadequacy of the current requirements stems primarily from two factors. Firstly, the area of the Moss Sphere protruding above what would be the nominal deck on a conventional carrier, which is protected only by a steel weather cover from exposure to heat from a tank-engulfing fire, is being underestimated. Secondly, aluminum foil-covered polystyrene foam insulation applied to the exterior of the LNG tank is protected above the deck only by the steel weather cover under which the insulation could begin to melt in as little as 1-3 min, and could completely liquefy in as few as 10 min. U.S. and International Regulations require that the insulations on the above-deck portion of tanks have approved fire proofing and stability under fire exposure. Polystyrene foam, as currently installed on LNG carriers, does not appear to meet these criteria. As a result of these findings, but giving no consideration to the significant potential for further damage if the polystyrene should burn, the boil-off rate is predicted to be an order-of-magnitude higher than provided for by current PRV sizing requirements. PMID:18372107

  10. Solar vapor generation enabled by nanoparticles.

    PubMed

    Neumann, Oara; Urban, Alexander S; Day, Jared; Lal, Surbhi; Nordlander, Peter; Halas, Naomi J

    2013-01-22

    Solar illumination of broadly absorbing metal or carbon nanoparticles dispersed in a liquid produces vapor without the requirement of heating the fluid volume. When particles are dispersed in water at ambient temperature, energy is directed primarily to vaporization of water into steam, with a much smaller fraction resulting in heating of the fluid. Sunlight-illuminated particles can also drive H(2)O-ethanol distillation, yielding fractions significantly richer in ethanol content than simple thermal distillation. These phenomena can also enable important compact solar applications such as sterilization of waste and surgical instruments in resource-poor locations. PMID:23157159

  11. Field experiments on high expansion (HEX) foam application for controlling LNG pool fire.

    PubMed

    Suardin, Jaffee A; Wang, Yanjun; Willson, Mike; Mannan, M Sam

    2009-06-15

    Previous research suggests that high expansion foam with an expansion ratio of 500 to 1 is one of the best options for controlling liquefied natural gas (LNG) pool fire on land. However, its effectiveness heavily depends on the foam application rate, foam generator location, and the design of LNG spill containment dike. Examination of these factors is necessary to achieve the maximum benefit for applying HEX on LNG pool fires. While theoretical study of the effects of foam on LNG fires is important, the complicated phenomena involved in LNG pool fire and foam application increase the need for LNG field experimentation. Therefore, five LNG experiments were conducted at Texas A&M University's Brayton Fire Training Field. ANGUS FIRE provided Expandol solution to form 500 to 1 high expansion foam (HEX) and its latest LNG Turbex Fixed High Expansion Foam Generators. In this paper, data collected during five experiments are presented and analyzed. The effectiveness of high expansion foam for controlling LNG pool fires with various application rates at two different types of containment pits is discussed. LNG fire behaviors and the effects of dike wall height are also presented and discussed. PMID:19056175

  12. Investigation of propulsion system for large LNG ships

    NASA Astrophysics Data System (ADS)

    Sinha, R. P.; Nik, Wan Mohd Norsani Wan

    2012-09-01

    Requirements to move away from coal for power generation has made LNG as the most sought after fuel source, raising steep demands on its supply and production. Added to this scenario is the gradual depletion of the offshore oil and gas fields which is pushing future explorations and production activities far away into the hostile environment of deep sea. Production of gas in such environment has great technical and commercial impacts on gas business. For instance, laying gas pipes from deep sea to distant receiving terminals will be technically and economically challenging. Alternative to laying gas pipes will require installing re-liquefaction unit on board FPSOs to convert gas into liquid for transportation by sea. But, then because of increased distance between gas source and receiving terminals the current medium size LNG ships will no longer remain economical to operate. Recognizing this business scenario shipowners are making huge investments in the acquisition of large LNG ships. As power need of large LNG ships is very different from the current small ones, a variety of propulsion derivatives such as UST, DFDE, 2-Stroke DRL and Combined cycle GT have been proposed by leading engine manufacturers. Since, propulsion system constitutes major element of the ship's capital and life cycle cost, which of these options is most suited for large LNG ships is currently a major concern of the shipping industry and must be thoroughly assessed. In this paper the authors investigate relative merits of these propulsion options against the benchmark performance criteria of BOG disposal, fuel consumption, gas emissions, plant availability and overall life cycle cost.

  13. Analysis of LNG import terminal release prevention systems

    SciTech Connect

    Baker, E G

    1982-04-01

    The release prevention systems of liquefied natural gas (LNG) import terminal were analyzed. A series of potential release scenarios were analyzed to determine the frequency of the release events, the probability these releases are not stopped or isolated by emergency shutdown systems, the estimated release quantities, and the critical components of the system. The two plant areas identified as being most significant with respect to safety are the unloading system and the storage system. Rupture of the main transfer line and gross failure of the storage tanks are the two release scenarios of primary safety interest. Reducing the rate of failure by improved design, better maintenance and testing, or adding redundancy of the critical system components for these plant areas and release scenarios will result in improved safety. Several design alternatives which have the potential to significantly reduce the probability of a large release of LNG occurring at an import terminal are identified. These design alternatives would reduce the probability of a large release of LNG by reducing the expected number of failures which could cause a release or by reducing the magnitude of releases that do occur. All of these alternatives are technically feasible and have been used or considered for use in at least one LNG facility. A more rigorous analysis of the absolute risk of LNG import terminal operation is necessary before the benefits of these design alternatives can be determined. In addition, an economic evaluation of these alternatives must be made so the costs and benefits can be compared. It is concludd that for remotely located facilities many of these alternatives are probably not justified; however, for facilities located in highly populated areas, these alternatives deserve serious consideration.

  14. Development of a simple 5-15 litre per hour LNG refueling system

    SciTech Connect

    Corless, A.J.; Sarangi, S.; Hall, J.L.; Barclay, J.A.

    1994-12-31

    A variable capacity, small-scale liquefied natural gas (LNG) refueling system has been designed, built, and tested at the Cryofuel Systems` Laboratory, University of Victoria, Canada. The system, designed to continuously liquefy between 5 and 15 litres of NG, utilizes liquid nitrogen (LN{sub 2}) as its cold source and contains most of the components found in a typical commercial refueling system; i.e. purification system, liquefier, LNG storage, automatic control and monitoring system. This paper describes the design of the system as well as the results of a set of LNG production trials. The performance of the system exceeded expected LNG production rates, but at levels of efficiency somewhat less than predicted. Cryofuel Systems expects to use this system to implement an LNG vehicle demonstration program and to gain experience in the integration of LNG refueling systems which exploit advanced liquefaction technology such as magnetic refrigeration.

  15. Qualitative Risk Assessment for an LNG Refueling Station and Review of Relevant Safety Issues

    SciTech Connect

    Siu, N.; Herring, J.S.; Cadwallader, L.; Reece, W.; Byers, J.

    1998-02-01

    This report is a qualitative assessment of the public and worker risk involved with the operation of a liquefied natural gas (LNG) vehicle refueling facility. This study includes facility maintenance and operations, tank truck deliveries, and end-use vehicle fueling; it does not treat the risks of LNG vehicles on roadways. Accident initiating events are identified by using a Master Logic Diagram, a Failure Modes and Effects Analysis, and historical operating experiences. The event trees were drawn to depict possible sequences of mitigating events following the initiating events. The phenomenology of LNG and other vehicle fuels is discussed to characterize the hazard posed by LNG usage. Based on the risk modeling and analysis, recommendations are given to improve the safety of LNG refueling stations in the areas of procedures and training, station design, and the dissemination of ``best practice`` information throughout the LNG community.

  16. Interim qualitative risk assessment for an LNG refueling station and review of relevant safety issues

    SciTech Connect

    Siu, N.; Herring, S.; Cadwallader, L.; Reece, W.; Byers, J.

    1997-07-01

    This report is a qualitative assessment of the public and worker risk involved with the operation of a liquefied natural (LNG) vehicle refueling facility. This study includes facility maintenance and operations, tanker truck delivers and end-use vehicle fueling; it does not treat the risks of LNG vehicles on roadways. Accident initiating events are identified by using a Master Logic Diagram, a Failure Modes and Effects analysis and historical operating experiences. The event trees were drawn to depict possible sequences of mitigating events following the initiating events. The phenomenology of LNG and other vehicle fuels is discussed to characterize the hazard posed by LNG usage. Based on the risk modeling and analysis, recommendations are given to improve the safety of LNG refueling stations in the areas of procedures and training, station design, and the dissemination of best practice information throughout the LNG community.

  17. Two-phase heat transfer and pressure drop of LNG during saturated flow boiling in a horizontal tube

    NASA Astrophysics Data System (ADS)

    Chen, Dongsheng; Shi, Yumei

    2013-12-01

    Two-phase heat transfer and pressure drop of LNG (liquefied natural gas) have been measured in a horizontal smooth tube with an inner diameter of 8 mm. The experiments were conducted at inlet pressures from 0.3 to 0.7 MPa with a heat flux of 8-36 kW m-2, and mass flux of 49.2-201.8 kg m-2 s-1. The effect of vapor quality, inlet pressure, heat flux and mass flux on the heat transfer characteristic are discussed. The comparisons of the experimental data with the predicted value by existing correlations are analyzed. Zou et al. (2010) correlation shows the best accuracy with 24.1% RMS deviation among them. Moreover four frictional pressure drop methods are also chosen to compare with the experimental database.

  18. Flare system for safe disposal of LNG from a disabled tanker

    SciTech Connect

    Not Available

    1982-12-01

    The feasibility of a flare system for the rapid and safe incineration of the cargo of a disabled LNG tanker is evaluated. The project developed design parameters and proof-of-principle investigations of a system for off-loading and flaring LNG from a disabled LNG tanker. The system described offers enough promise to warrant additional investigation, if cargo burning is desired as a way of reducing other possible hazards.

  19. Ocular dispersion

    NASA Astrophysics Data System (ADS)

    Hammer, Daniel X.; Noojin, Gary D.; Thomas, Robert J.; Stolarski, David J.; Rockwell, Benjamin A.; Welch, Ashley J.

    1999-06-01

    Spectrally resolved white-light interferometry (SRWLI) was used to measure the wavelength dependence of refractive index (i.e., dispersion) for various ocular components. The accuracy of the technique was assessed by measurement of fused silica and water, the refractive indices of which have been measured at several different wavelengths. The dispersion of bovine and rabbit aqueous and vitreous humor was measured from 400 to 1100 nm. Also, the dispersion was measured from 400 to 700 nm for aqueous and vitreous humor extracted from goat and rhesus monkey eyes. For the humors, the dispersion did not deviate significantly from water. In an additional experiment, the dispersion of aqueous and vitreous humor that had aged up to a month was compared to freshly harvested material. No difference was found between the fresh and aged media. An unsuccessful attempt was also made to use the technique for dispersion measurement of bovine cornea and lens. Future refinement may allow measurement of the dispersion of cornea and lens across the entire visible and near-infrared wavelength band. The principles of white- light interferometry including image analysis, measurement accuracy, and limitations of the technique, are discussed. In addition, alternate techniques and previous measurements of ocular dispersion are reviewed.

  20. Calibrated vapor generator source

    DOEpatents

    Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

    1995-09-26

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

  1. Calibrated vapor generator source

    DOEpatents

    Davies, John P.; Larson, Ronald A.; Goodrich, Lorenzo D.; Hall, Harold J.; Stoddard, Billy D.; Davis, Sean G.; Kaser, Timothy G.; Conrad, Frank J.

    1995-01-01

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet.

  2. US North Slope gas and Asian LNG markets

    USGS Publications Warehouse

    Attanasi, E.D.

    1994-01-01

    Prospects for export of liquified natural gas (LNG) from Alaska's North Slope are assessed. Projected market conditions to 2010 show that new LNG capacity beyond announced expansions will be needed to meet regional demand and that supplies will probably come from outside the region. The estimated delivered costs of likely suppliers show that Alaska North Slope gas will not be competitive. The alternative North Slope gas development strategies of transport and sale to the lower 48 states and use on the North Slope for either enhanced oil recovery or conversion to liquids are examined. The alternative options require delaying development until US gas prices increase, exhaustion of certain North Slope oil fields, or advances occur in gas to liquid fuels conversion technology. ?? 1995.

  3. Kalimantan field development hikes gas supply for LNG export

    SciTech Connect

    Suharmoko, G.R. )

    1991-10-14

    This paper reports on the development of Tambora and Tunu gas fields in Kalimantan that have increased available gas supply for the export of liquefied natural gas (LNG) from Indonesia. The demand for LNG is increasing in the energy thirsty Far East market. And Indonesia, the world's largest exporter, is keeping pace by expanding the Bontang liquefaction plant in East Kalimantan. A fifth train, with a capacity of around 2.5 million tons/year, began operating in January 1990. Start-up of a sixth train, of identical capacity, is planned for January 1994. The Bontang plant is operated by PT Badak on behalf of Pertamina, the Indonesian state oil and gas mining company. The feed to the fifth train comes primarily from the first-phase development of Total Indonesie's two gas fields, Tambora and Tunu. The sixth train will be fed by a second-phase development of the Tunu field.

  4. LNG (liquefied natural gas) in the Asia-Pacific region: Twenty years of trade and outlook for the future

    SciTech Connect

    Kiani, B.

    1990-01-01

    This report discusses the following topics: the current status of LNG trade in the Asia-Pacific region; present structure and projected demand in the Asia-Pacific region; prospective and tentative projects; and LNG contracts: stability versus flexibility.

  5. Coupling dynamic blow down and pool evaporation model for LNG.

    PubMed

    Woodward, John L

    2007-02-20

    Treating the dynamic effects of accidental discharges of liquefied natural gas (LNG) is important for realistic predictions of pool radius. Two phenomena have important influence on pool spread dynamics, time-varying discharge (blow down) and pool ignition. Time-varying discharge occurs because a punctured LNG tanker or storage tank drains with a decreasing liquid head and decreasing head-space pressure. Pool ignition increases the evaporation rate of a pool and consequently decreases the ultimate pool area. This paper describes an approach to treat these phenomena in a dynamic pool evaporation model. The pool evaporation model developed here has two separate regimes. Early in the spill, momentum forces dominate and the pool spreads independently of pool evaporation rate and the corresponding heat transfer rate. After the average pool depth drops below a minimum value, momentum forces are largely dissipated and the thin edges of the pool completely evaporate, so pool area is established by the heat transfer rate. The maximum extent of a burning pool is predicted to be significantly less than that of an unignited pool because the duration of the first regime is reduced by higher heat transfer rates. The maximum extent of an LNG pool is predicted to be larger upon accounting for blow down compared with using a constant average discharge rate. However, the maximum pool extent occurs only momentarily before retreating. PMID:17184912

  6. Design advanced for large-scale, economic, floating LNG plant

    SciTech Connect

    Naklie, M.M.

    1997-06-30

    A floating LNG plant design has been developed which is technically feasible, economical, safe, and reliable. This technology will allow monetization of small marginal fields and improve the economics of large fields. Mobil`s world-scale plant design has a capacity of 6 million tons/year of LNG and up to 55,000 b/d condensate produced from 1 bcfd of feed gas. The plant would be located on a large, secure, concrete barge with a central moonpool. LNG storage is provided for 250,000 cu m and condensate storage for 650,000 bbl. And both products are off-loaded from the barge. Model tests have verified the stability of the barge structure: barge motions are low enough to permit the plant to continue operation in a 100-year storm in the Pacific Rim. Moreover, the barge is spread-moored, eliminating the need for a turret and swivel. Because the design is generic, the plant can process a wide variety of feed gases and operate in different environments, should the plant be relocated. This capability potentially gives the plant investment a much longer project life because its use is not limited to the life of only one producing area.

  7. Analysis of temperature and pressure changes in liquefied natural gas (LNG) cryogenic tanks

    NASA Astrophysics Data System (ADS)

    Chen, Q.-S.; Wegrzyn, J.; Prasad, V.

    2004-10-01

    Liquefied natural gas (LNG) is being developed as a transportation fuel for heavy vehicles such as trucks and transit buses, to lessen the dependency on oil and to reduce greenhouse gas emissions. The LNG stations are properly designed to prevent the venting of natural gas (NG) from LNG tanks, which can cause evaporative greenhouse gas emissions and result in fluctuations of fuel flow and changes of fuel composition. Boil-off is caused by the heat added into the LNG fuel during the storage and fueling. Heat can leak into the LNG fuel through the shell of tank during the storage and through hoses and dispensers during the fueling. Gas from tanks onboard vehicles, when returned to LNG tanks, can add additional heat into the LNG fuel. A thermodynamic and heat transfer model has been developed to analyze different mechanisms of heat leak into the LNG fuel. The evolving of properties and compositions of LNG fuel inside LNG tanks is simulated. The effect of a number of buses fueled each day on the possible total fuel loss rate has been analyzed. It is found that by increasing the number of buses, fueled each day, the total fuel loss rate can be reduced significantly. It is proposed that an electric generator be used to consume the boil-off gas or a liquefier be used to re-liquefy the boil-off gas to reduce the tank pressure and eliminate fuel losses. These approaches can prevent boil-off of natural gas emissions, and reduce the costs of LNG as transportation fuel.

  8. HANFORD CHEMICAL VAPORS WORKER CONCERNS & EXPOSURE EVALUATION

    SciTech Connect

    ANDERSON, T.J.

    2006-12-20

    Chemical vapor emissions from underground hazardous waste storage tanks on the Hanford site in eastern Washington State are a potential concern because workers enter the tank farms on a regular basis for waste retrievals, equipment maintenance, and surveillance. Tank farm contractors are in the process of retrieving all remaining waste from aging single-shell tanks, some of which date to World War II, and transferring it to newer double-shell tanks. During the waste retrieval process, tank farm workers are potentially exposed to fugitive chemical vapors that can escape from tank headspaces and other emission points. The tanks are known to hold more than 1,500 different species of chemicals, in addition to radionuclides. Exposure assessments have fully characterized the hazards from chemical vapors in half of the tank farms. Extensive sampling and analysis has been done to characterize the chemical properties of hazardous waste and to evaluate potential health hazards of vapors at the ground surface, where workers perform maintenance and waste transfer activities. Worker concerns. risk communication, and exposure assessment are discussed, including evaluation of the potential hazards of complex mixtures of chemical vapors. Concentrations of vapors above occupational exposure limits-(OEL) were detected only at exhaust stacks and passive breather filter outlets. Beyond five feet from the sources, vapors disperse rapidly. No vapors have been measured above 50% of their OELs more than five feet from the source. Vapor controls are focused on limited hazard zones around sources. Further evaluations of vapors include analysis of routes of exposure and thorough analysis of nuisance odors.

  9. 33 CFR 165.1709 - Security Zones: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG Pier, Cook Inlet, AK. (a... navigable waters within a 1000-yard radius of the Liquefied Natural Gas (LNG) tankers during their inbound... Natural Gas tankers while they are moored at Phillips Petroleum LNG Pier, 60°40′43″ N and 151°24′10″ W....

  10. 33 CFR 165.1709 - Security Zones: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG Pier, Cook Inlet, AK. (a... navigable waters within a 1000-yard radius of the Liquefied Natural Gas (LNG) tankers during their inbound... Natural Gas tankers while they are moored at Phillips Petroleum LNG Pier, 60°40′43″ N and 151°24′10″ W....

  11. 40 CFR Table W - 5 of Subpart W-Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Emission Factors for Liquefied Natural Gas (LNG) Storage W Table W Protection of Environment ENVIRONMENTAL... Natural Gas Systems Definitions. Pt. 98, Subpt. W, Table W-5 Table W-5 of Subpart W—Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage LNG storage Emission factor...

  12. 33 CFR 165.1709 - Security Zones: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG Pier, Cook Inlet, AK. (a... navigable waters within a 1000-yard radius of the Liquefied Natural Gas (LNG) tankers during their inbound... Natural Gas tankers while they are moored at Phillips Petroleum LNG Pier, 60°40′43″ N and 151°24′10″ W....

  13. 33 CFR 165.1709 - Security Zones: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG Pier, Cook Inlet, AK. (a... navigable waters within a 1000-yard radius of the Liquefied Natural Gas (LNG) tankers during their inbound... Natural Gas tankers while they are moored at Phillips Petroleum LNG Pier, 60°40′43″ N and 151°24′10″ W....

  14. 33 CFR 165.1709 - Security Zones: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...: Liquefied Natural Gas Tanker Transits and Operations at Phillips Petroleum LNG Pier, Cook Inlet, AK. (a... navigable waters within a 1000-yard radius of the Liquefied Natural Gas (LNG) tankers during their inbound... Natural Gas tankers while they are moored at Phillips Petroleum LNG Pier, 60°40′43″ N and 151°24′10″ W....

  15. 75 FR 11169 - AES Sparrows Point LNG, LLC; Mid-Atlantic Express, LLC; Notice of Availability of the Revised...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-10

    ... Sparrows Point LNG Terminal and Pipeline Project March 1, 2010. The staff of the Federal Energy Regulatory... operation of a liquefied natural gas (LNG) import terminal and natural gas pipeline proposed by AES Sparrows... LNG terminal and natural gas pipeline facilities: A ship unloading facility, with two berths,...

  16. 75 FR 353 - AES Sparrows Point LNG, LLC and Mid-Atlantic Express, LLC; Notice of Availability of the Final...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-05

    ... Terminal and Pipeline Project December 29, 2009. The staff of the Federal Energy Regulatory Commission... natural gas (LNG) import terminal and natural gas pipeline proposed by AES Sparrows Point LNG, LLC and Mid... operation of the following LNG terminal and natural gas pipeline facilities: A ship unloading facility,...

  17. LNG as a fuel for railroads: Assessment of technology status and economics. Topical report, June-September 1992

    SciTech Connect

    Pera, C.J.; Moyer, C.B.

    1993-01-06

    The objective of the research was to investigate the feasibility of liquefied natural gas (LNG) as a fuel for railroads. The investigation included assessment of the status of relevant technologies (i.e., LNG-fueled locomotive engines, tender cars, refueling equipment), a review of current demonstration projects, and an analytical evaluation of LNG railroad economics.

  18. 78 FR 42587 - Deepwater Port License: Amendment of the Neptune LNG LLC Deepwater Port License and Temporary...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-16

    ... Maritime Administration Deepwater Port License: Amendment of the Neptune LNG LLC Deepwater Port License and Temporary Suspension of Operations at the Neptune LNG Deepwater Port AGENCY: Maritime Administration... Administration (MarAd) provides public notice of its decision to approve the request of Neptune LNG LLC...

  19. 75 FR 29420 - Revision of LNG and LHG Waterfront Facility General Requirements

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-26

    ... proposed rulemaking entitled ``Revision of LNG and LHG Waterfront Facility General Requirements'' (74 FR... easily be obtained from the facility-design specifications'' (60 FR ] 39788). Every LOI provided by an... Regulatory Commission FR Federal Register LHG Liquefied hazardous gas LNG Liquefied natural gas LOI Letter...

  20. 77 FR 66830 - LNG Development Company, LLC and Oregon Pipeline Company; Northwest Pipeline GP; Notice of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-11-07

    ... Energy Regulatory Commission LNG Development Company, LLC and Oregon Pipeline Company; Northwest Pipeline GP; Notice of Extension of Comment Period for the Oregon LNG Export and Washington Expansion Projects This notice announces the extension of the public scoping process and comment period for the Oregon...

  1. 76 FR 40723 - Dominion Cove Point LNG, LP; Notice of Technical Conference

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-11

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Dominion Cove Point LNG, LP; Notice of Technical Conference On May 27, 2011, pursuant to section 4 of the Natural Gas Act (NGA), Dominion Cove Point LNG, LP (Cove Point) filed...

  2. 77 FR 10732 - Cameron LNG, LLC; Application for Long-Term Authorization To Export Domestically Produced...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-23

    ...The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an application (Application), filed on December 21, 2011, by Cameron LNG, LLC (Cameron), requesting long-term, multi-contract authorization to export up to 12 million metric tons per annum (mtpa) of domestically produced liquefied natural gas (LNG) (equivalent to approximately 620 billion cubic feet......

  3. The potential for LNG as a railroad fuel in the U.S.

    SciTech Connect

    Fritz, S.G.

    2000-01-01

    Freight railroad operations in the US represent a substantial opportunity for liquefied natural gas (LNG) to displace diesel fuel. With the promise of achieving an overwhelming economic advantage over diesel fuel, this paper presents some discussion to the question, ``Why is the application of LNG for railroad use in the US moving so slowly?'' A brief overview of the freight railroad operations in the US is given, along with a summary of several railroad LNG demonstration projects. US Environmental Protection Agency and California Air Resources Board exhaust emission regulations may cause the railroad industry to move from small-scale LNG demonstration projects to using LNG as a primary freight railroad transportation fuel in selected regions or route-specific applications.

  4. D-optimal experimental design coupled with parallel factor analysis 2 decomposition a useful tool in the determination of triazines in oranges by programmed temperature vaporization-gas chromatography-mass spectrometry when using dispersive-solid phase extraction.

    PubMed

    Herrero, A; Ortiz, M C; Sarabia, L A

    2013-05-01

    The determination of triazines in oranges using a GC-MS system coupled to a programmed temperature vaporizer (PTV) inlet in the context of legislation is performed. Both pretreatment (using a Quick Easy Cheap Effective Rugged and Safe (QuEChERS) procedure) and injection steps are optimized using D-optimal experimental designs for reducing the experimental effort. The relative dirty extracts obtained and the elution time shifts make it necessary to use a PARAFAC2 decomposition to solve these two usual problems in the chromatographic determinations. The "second-order advantage" of the PARAFAC2 decomposition allows unequivocal identification according to document SANCO/12495/2011 (taking into account the tolerances for relative retention time and the relative abundance for the diagnostic ions), avoiding false negatives even in the presence of unknown co-eluents. The detection limits (CCα) found, from 0.51 to 1.05μgkg(-1), are far below the maximum residue levels (MRLs) established by the European Union for simazine, atrazine, terbuthylazine, ametryn, simetryn, prometryn and terbutryn in oranges. No MRL violations were found in the commercial oranges analyzed. PMID:23522618

  5. Vapor phase pyrolysis

    NASA Technical Reports Server (NTRS)

    Steurer, Wolfgang

    1992-01-01

    The vapor phase pyrolysis process is designed exclusively for the lunar production of oxygen. In this concept, granulated raw material (soil) that consists almost entirely of metal oxides is vaporized and the vapor is raised to a temperature where it dissociates into suboxides and free oxygen. Rapid cooling of the dissociated vapor to a discrete temperature causes condensation of the suboxides, while the oxygen remains essentially intact and can be collected downstream. The gas flow path and flow rate are maintained at an optimum level by control of the pressure differential between the vaporization region and the oxygen collection system with the aid of the environmental vacuum.

  6. Dispersion Modeling.

    ERIC Educational Resources Information Center

    Budiansky, Stephen

    1980-01-01

    This article discusses the need for more accurate and complete input data and field verification of the various models of air pollutant dispension. Consideration should be given to changing the form of air quality standards based on enhanced dispersion modeling techniques. (Author/RE)

  7. LNG projects make progress in Oman and Yemen

    SciTech Connect

    1997-02-24

    Two LNG projects in the Middle East, one in Oman and the other in Yemen, are due on stream at the turn of the century--each the largest single project ever put together in its country. Officials described their projects at a yearend 1996 conference in Paris by Institut Francais du Petrole and Petrostrategies. The Oman project develops gas reserves, does gas processing, and transports the gas 360 km to a liquefaction plant to be built on the coast. The Yemen project involves a liquefaction plant and an export terminal.

  8. Comparison of hypothetical LNG and fuel oil fires on water.

    PubMed

    Lehr, William; Simecek-Beatty, Debra

    2004-02-27

    Large spills of refined petroleum products have been an occasional occurrence over the past few decades. This has not been true for large spills of liquefied natural gas (LNG). This paper compares the likely similarities and differences between accidental releases from a ship of sizable quantities of these different hydrocarbon fuels, their subsequent spreading, and possible pool-fire behavior. Quantitative estimates are made of the spread rate and maximum slick size, burn rate, and duration; effective thermal radiation; and subsequent soot generation. PMID:15036638

  9. Cryogenic flexible pipes for offshore LNG-LPG production

    SciTech Connect

    Dumay, J.M.

    1981-01-01

    Available in long, flexible pieces (up to several miles), the high-performance Coflexip pipe comprises four basic layers: (1) an interlocked, spiraled-steel carcass to resist crushing and prevent deformation, (2) an inner thermoplastic sheath to render the line internally leakproof, (3) two cross-laid steel-wire armors to oppose the stresses induced by internal pressure, and (4) an external thermoplastic sheath to ensure water-tightness and resist corrosion. Coflexip pipe is particularly suitable for transporting cryogenic liquids such as LNG from, for example, an offshore liquefaction plant.

  10. Chrysler to race hybrid electric-LNG car

    SciTech Connect

    1994-03-07

    Chrysler Corp. hopes to race a hybrid electric-liquefied natural gas car in the Le Mans in 1995. Preparing for a racing program will speed technological advances that could take years under a regular development program. The car converts LNG to electricity with a two-turbine alternator that powers an electric traction motor. Power not used immediately is placed in reserve in an ultra-high-speed carbon-fiber flywheel, which also captures kinetic energy at braking. Even with the accelerated race program, Chrysler says it will likely be the next century before hybrid technology will make it into production cars.

  11. The effects of refueling system operating pressure on LNG and CNG economics

    SciTech Connect

    Corless, A.J.; Barclay, J.A.

    1996-12-31

    Natural gas (NG) liquefaction and compression are energy intensive processes which make up a significant portion of the overall delivered price of liquefied NG (LNG) and compressed NG (CNG). Increases in system efficiency and/or process changes which reduce the required amount of work will improve the overall economics of NG as a vehicle fuel. This paper describes a method of reducing the delivered cost of LNG by liquefying the gas above ambient pressures. Higher pressure LNG is desirable because OEM NG engine manufacturers would like NG delivered to the engine intake manifold at elevated pressures to avoid compromising engine performance. Producing LNG at higher pressures reduces the amount of work required for liquefaction but it is only practical when the LNG is liquefied on-site. Using a thermo-economic approach, it is shown that NG fuel costs can be reduced by as much as 10% when producing LNG at higher pressures. A reduction in the delivered cost is also demonstrated for CNG produced on-site from high pressure LNG.

  12. White paper: Preliminary assessment of LNG vehicle technology, economics, and safety issues, revision 1

    NASA Astrophysics Data System (ADS)

    Powars, Charles; Lucher, Dan; Moyer, Carl; Browning, Lou

    1992-01-01

    The objective of the study is to evaluate the potential of liquified natural gas (LNG) as a vehicle fuel, to determine market inches, and to identify needed technology improvements. The white paper is being issued when the work is approximately 30 percent complete to preview the study direction, draw preliminary conclusions, and make initial recommendations. Interim findings relative to LNG vehicle technology, economics, and safety are presented. It is important to decide if heavier hydrocarbons should be allowed in LNG vehicle fuel. Development of suitable refueling couplings and vehicle fuel supply pressure systems are recommended. Initial economics analyses considered transit buses and pickup and delivery trucks fueled via onsite liquefiers and imported LNG. Net user costs were more than (but in some cases close to) those for diesel fuel and gasoline. Lowering the cost of small-scale liquefiers would significantly improve the economics of LNG vehicles. New emissions regulations may introduce considerations beyond simple cost comparisons. LNG vehicle safety and available accident data are reviewed. Consistent codes for LNG vehicles and refueling facilities are needed.

  13. Fog dispersion

    NASA Technical Reports Server (NTRS)

    Frost, W.; Christensen, L. S.; Collins, F. G.; Camp, D. W.

    1980-01-01

    A study of economically viable techniques for dispersing warm fog at commercial airports is presented. Five fog dispersion techniques are examined: evaporation suppression, downwash, mixing, seeding with hygroscopic material, thermal techniques, and charged particle techniques. Thermal techniques, although effective, were found to be too expensive for routine airport operations, and detrimental to the environment. Seeding or helicopter downwash are practical for small-scale or temporary fog clearing, but are probably not useful for airport operations on a routine basis. Considerable disagreement exists on the capability of charged particle techniques, which stems from the fact that different assumptions and parameter values are used in the analytical models. Recommendations resulting from the review of this technique are listed, and include: experimental measurements of the parameters in question; a study to ascertain possible safety hazards, such as increased electrical activity or fuel ignition during refueling operations which could render charged particle techniques impractical; and a study of a single charged particle generator.

  14. Enabling a viable technique for the optimization of LNG carrier cargo operations

    NASA Astrophysics Data System (ADS)

    Alaba, Onakoya Rasheed; Nwaoha, T. C.; Okwu, M. O.

    2016-07-01

    In this study, we optimize the loading and discharging operations of the Liquefied Natural Gas (LNG) carrier. First, we identify the required precautions for LNG carrier cargo operations. Next, we prioritize these precautions using the analytic hierarchy process (AHP) and experts' judgments, in order to optimize the operational loading and discharging exercises of the LNG carrier, prevent system failure and human error, and reduce the risk of marine accidents. Thus, the objective of our study is to increase the level of safety during cargo operations.

  15. Vaporization of droplets in premixing chambers

    NASA Technical Reports Server (NTRS)

    Yule, A. J.; Chigier, N. A.

    1980-01-01

    Detailed measurements were made of the structures of turbulent fuel sprays vaporizing in heated airstreams. The measurements show the size dependent vaporization and dispersion of the droplets and the important influence of the large eddies in the turbulence. The measurements form a data base for the development of models of fuel spray vaporization. Two laser techniques were specially developed for the investigation. A laser tomography technique converts line-of-sight light scattering measurements into time averaged 'point' measurements of droplet size distribution and volume concentration. A laser anemometer particle sizing technique was further developed to permit accurate measurements of individual particle sizes and velocities, with backscatter collection of light. The experiments are combined with heat transfer models to analyze the performance of miniature thermocouples in liquid sprays.

  16. Vapor spill monitoring method

    DOEpatents

    Bianchini, Gregory M.; McRae, Thomas G.

    1985-01-01

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  17. Supplemental fuel vapor system

    SciTech Connect

    Foster, P.M.

    1991-01-08

    This patent describes a supplemental fuel system utilizing fuel vapor. It comprises: an internal combustion engine including a carburetor and an intake manifold; a fuel tank provided with air vents; a fuel conduit having a first end connected to the fuel tank and in communication with liquid fuel in the tank and a second end connected to the carburetor; the fuel conduit delivering the liquid fuel to the carburetor from the fuel tank; a fuel vapor conduit having a first end connected to the fuel tank at a location displaced from contact with the liquid fuel and a second end connected to a carbon canister; a PCV conduit having a first end connected to a pollution control valve and a second end connected to the intake manifold; and, an intermediate fuel vapor conduit having a first end connected to the fuel vapor conduit and a second end connected to the PCV conduit; wherein the air vents continuously provide air to the tank to mix with the liquid fuel and form fuel vapor. The fuel vapor drawn from the fuel tank by vacuum developed in the intake manifold and flows through the fuel vapor conduit. The intermediate fuel vapor conduit and the intake manifold to combustion chambers of the internal combustion engine so as to supplement fuel delivered to the engine by the fuel conduit. The liquid fuel and the fuel vapor constantly delivered to the engine during normal operation.

  18. Three-dimensional model for simulating atmospheric dispersion of heavy-gases over complex terrain

    SciTech Connect

    Chan, S.T.

    1997-09-01

    To help understand heavy gas releases and simulate the resultant dispersion, we have developed a three-dimensional finite element model called FEM3 and an improved version names FEM3A for solving the time dependent conservation equations based on generalized anelastic approximation. Recent enhancements to the model to include the treatment of dispersion scenarios involving density variations much larger than the liquefied natural gas range and an advanced turbulence submodel based on the buoyancy-extended transport equations. This paper presents the main features of the present model FEM3C and numerical results from the simulations of a field-scale LNG spill experiment.

  19. Hydrogen production by steam reforming of liquefied natural gas (LNG) over nickel catalysts supported on cationic surfactant-templated mesoporous aluminas

    NASA Astrophysics Data System (ADS)

    Seo, Jeong Gil; Youn, Min Hye; Park, Sunyoung; Jung, Ji Chul; Kim, Pil; Chung, Jin Suk; Song, In Kyu

    Two types of mesoporous γ-aluminas (denoted as A-A and A-S) are prepared by a hydrothermal method under different basic conditions using cationic surfactant (cetyltrimethylammonium bromide, CTAB) as a templating agent. A-A and A-S are synthesized in a medium of ammonia solution and sodium hydroxide solution, respectively. Ni/γ-Al 2O 3 catalysts (Ni/A-A and Ni/A-S) are then prepared by an impregnation method, and are applied to hydrogen production by steam reforming of liquefied natural gas (LNG). The effect of a mesoporous γ-Al 2O 3 support on the catalytic performance of Ni/γ-Al 2O 3 is investigated. The identity of basic solution strongly affects the physical properties of the A-A and A-S supports. The high surface-area of the mesoporous γ-aluminas and the strong metal-support interaction of supported catalysts greatly enhance the dispersion of nickel species on the catalyst surface. The well-developed mesopores of the Ni/A-A and Ni/A-S catalysts prohibit the polymerization of carbon species on the catalyst surface during the reaction. In the steam reforming of LNG, both Ni/A-A and Ni/A-S catalysts give better catalytic performance than the nickel catalyst supported on commercial γ-Al 2O 3 (Ni/A-C). In addition, the Ni/A-A catalyst is superior to the Ni/A-S catalyst. The relatively strong metal-support interaction of Ni/A-A catalyst effectively suppresses the sintering of metallic nickel and the carbon deposition in the steam reforming of LNG. The large pores of the Ni/A-A catalyst also play an important role in enhancing internal mass transfer during the reaction.

  20. Petroleum Vapor - Field Technical

    EPA Science Inventory

    The screening approach being developed by EPA OUST to evaluate petroleum vapor intrusion (PVI) requires information that has not be routinely collected in the past at vapor intrusion sites. What is the best way to collect this data? What are the relevant data quality issues and ...

  1. Water vapor pressure calculation.

    PubMed

    Hall, J R; Brouillard, R G

    1985-06-01

    Accurate calculation of water vapor pressure for systems saturated with water vapor can be performed using the Goff-Gratch equation. A form of the equation that can be adapted for computer programming and for use in electronic databases is provided. PMID:4008425

  2. Stratospheric water vapor feedback

    PubMed Central

    Dessler, A. E.; Schoeberl, M. R.; Wang, T.; Davis, S. M.; Rosenlof, K. H.

    2013-01-01

    We show here that stratospheric water vapor variations play an important role in the evolution of our climate. This comes from analysis of observations showing that stratospheric water vapor increases with tropospheric temperature, implying the existence of a stratospheric water vapor feedback. We estimate the strength of this feedback in a chemistry–climate model to be +0.3 W/(m2⋅K), which would be a significant contributor to the overall climate sensitivity. One-third of this feedback comes from increases in water vapor entering the stratosphere through the tropical tropopause layer, with the rest coming from increases in water vapor entering through the extratropical tropopause. PMID:24082126

  3. Stratospheric water vapor feedback.

    PubMed

    Dessler, A E; Schoeberl, M R; Wang, T; Davis, S M; Rosenlof, K H

    2013-11-01

    We show here that stratospheric water vapor variations play an important role in the evolution of our climate. This comes from analysis of observations showing that stratospheric water vapor increases with tropospheric temperature, implying the existence of a stratospheric water vapor feedback. We estimate the strength of this feedback in a chemistry-climate model to be +0.3 W/(m(2)⋅K), which would be a significant contributor to the overall climate sensitivity. One-third of this feedback comes from increases in water vapor entering the stratosphere through the tropical tropopause layer, with the rest coming from increases in water vapor entering through the extratropical tropopause. PMID:24082126

  4. Vapor core turbulence in annular two-phase flow

    SciTech Connect

    Trabold, T.A.; Kumar, R.

    1998-06-01

    This paper reports a new technique to measure vapor turbulence in two-phase flows using hot-film anemometry. Continuous vapor turbulence measurements along with local void fraction, droplet frequency, droplet velocity and droplet diameter were measured in a thin, vertical duct. By first eliminating the portion of the output voltage signal resulting from the interaction of dispersed liquid droplets with the HFA sensor, the discrete voltage samples associated with the vapor phase were separately analyzed. The data revealed that, over the range of liquid droplet sizes and concentrations encountered, the presence of the droplet field acts to enhance vapor turbulence. In addition, there is evidence that vapor turbulence is significantly influenced by the wall-bounded liquid film. The present results are qualitatively consistent with the limited data available in the open literature.

  5. Numerical simulation of water injection into vapor-dominated reservoirs

    SciTech Connect

    Pruess, K.

    1995-01-01

    Water injection into vapor-dominated reservoirs is a means of condensate disposal, as well as a reservoir management tool for enhancing energy recovery and reservoir life. We review different approaches to modeling the complex fluid and heat flow processes during injection into vapor-dominated systems. Vapor pressure lowering, grid orientation effects, and physical dispersion of injection plumes from reservoir heterogeneity are important considerations for a realistic modeling of injection effects. An example of detailed three-dimensional modeling of injection experiments at The Geysers is given.

  6. Accelerated dilution of liquefied natural gas plumes with fences and vortex generators

    SciTech Connect

    Kothari, K.M.; Meroney, R.N.

    1982-05-01

    Wind-tunnel tests confirmed that a passive fence or vortex generator can help dilute a hazardous LNG vapor cloud, leading to a quicker dispersal of the plume. Supplying a large database on the interaction of LNG plumes with such devices, the tests determined the effects of boiloff rate, wind speed, and fence configuration on cloud dispersion.

  7. Thermodynamic Processes Involving Liquefied Natural Gas at the LNG Receiving Terminals / Procesy termodynamiczne z wykorzystaniem skroplonego gazu ziemnego w terminalach odbiorczych LNG

    NASA Astrophysics Data System (ADS)

    Łaciak, Mariusz

    2013-06-01

    The increase in demand for natural gas in the world, cause that the production of liquefied natural gas (LNG) and in consequences its regasification becoming more common process related to its transportation. Liquefied gas is transported in the tanks at a temperature of about 111K at atmospheric pressure. The process required to convert LNG from a liquid to a gas phase for further pipeline transport, allows the use of exergy of LNG to various applications, including for electricity generation. Exergy analysis is a well known technique for analyzing irreversible losses in a separate process. It allows to specify the distribution, the source and size of the irreversible losses in energy systems, and thus provide guidelines for energy efficiency. Because both the LNG regasification and liquefaction of natural gas are energy intensive, exergy analysis process is essential for designing highly efficient cryogenic installations. Wzrost zapotrzebowania na gaz ziemny na świecie powoduje, że produkcja skroplonego gazu ziemnego (LNG), a w konsekwencji jego regazyfikacja, staje się coraz bardziej powszechnym procesem związanym z jego transportem. Skroplony gaz transportowany jest w zbiornikach w temperaturze około 111K pod ciśnieniem atmosferycznym. Przebieg procesu regazyfikacji niezbędny do zamiany LNG z fazy ciekłej w gazową dla dalszego transportu w sieci, umożliwia wykorzystanie egzergii LNG do różnych zastosowań, między innymi do produkcji energii elektrycznej. Analiza egzergii jest znaną techniką analizowania nieodwracalnych strat w wydzielonym procesie. Pozwala na określenie dystrybucji, źródła i wielkości nieodwracalnych strat w systemach energetycznych, a więc ustalić wytyczne dotyczące efektywnego zużycia energii. Ponieważ zarówno regazyfikacja LNG jak i skraplanie gazu ziemnego są energochłonne, proces analizy egzergii jest niezbędny do projektowania wysoce wydajnych instalacji kriogenicznych.

  8. Vacuum vapor deposition

    NASA Technical Reports Server (NTRS)

    Poorman, Richard M. (Inventor); Weeks, Jack L. (Inventor)

    1995-01-01

    A method and apparatus is described for vapor deposition of a thin metallic film utilizing an ionized gas arc directed onto a source material spaced from a substrate to be coated in a substantial vacuum while providing a pressure differential between the source and the substrate so that, as a portion of the source is vaporized, the vapors are carried to the substrate. The apparatus includes a modified tungsten arc welding torch having a hollow electrode through which a gas, preferably inert, flows and an arc is struck between the electrode and the source. The torch, source, and substrate are confined within a chamber within which a vacuum is drawn. When the arc is struck, a portion of the source is vaporized and the vapors flow rapidly toward the substrate. A reflecting shield is positioned about the torch above the electrode and the source to ensure that the arc is struck between the electrode and the source at startup. The electrode and the source may be confined within a vapor guide housing having a duct opening toward the substrate for directing the vapors onto the substrate.

  9. Vapor resistant arteries

    NASA Technical Reports Server (NTRS)

    Shaubach, Robert M. (Inventor); Dussinger, Peter M. (Inventor); Buchko, Matthew T. (Inventor)

    1989-01-01

    A vapor block resistant liquid artery structure for heat pipes. A solid tube artery with openings is encased in the sintered material of a heat pipe wick. The openings are limited to that side of the artery which is most remote from the heat source. The liquid in the artery can thus exit the artery through the openings and wet the sintered sheath, but vapor generated at the heat source is unlikely to move around the solid wall of the artery and reverse its direction in order to penetrate the artery through the openings. An alternate embodiment uses finer pore size wick material to resist vapor entry.

  10. AMTEC vapor-vapor series connected cells

    NASA Technical Reports Server (NTRS)

    Underwood, Mark L. (Inventor); Williams, Roger M. (Inventor); Ryan, Margaret A. (Inventor); Nakamura, Barbara J. (Inventor); Oconnor, Dennis E. (Inventor)

    1995-01-01

    An alkali metal thermoelectric converter (AMTEC) having a plurality of cells structurally connected in series to form a septum dividing a plenum into two chambers, and electrically connected in series, is provided with porous metal anodes and porous metal cathodes in the cells. The cells may be planar or annular, and in either case a metal alkali vapor at a high temperature is provided to the plenum through one chamber on one side of the wall and returned to a vapor boiler after condensation at a chamber on the other side of the wall in the plenum. If the cells are annular, a heating core may be placed along the axis of the stacked cells. This arrangement of series-connected cells allows efficient generation of power at high voltage and low current.

  11. Colloidal Dispersions

    NASA Astrophysics Data System (ADS)

    Russel, W. B.; Saville, D. A.; Schowalter, W. R.

    1992-03-01

    The book covers the physical side of colloid science from the individual forces acting between submicron particles suspended in a liquid through the resulting equilibrium and dynamic properties. The relevant forces include Brownian motion, electrostatic repulsion, dispersion attraction, both attraction and repulsion due to soluble polymer, and viscous forces due to relative motion between the particles and the liquid. The balance among Brownian motion and the interparticle forces decides the questions of stability and phase behavior. Imposition of external fields produces complex effects, i.e. electrokinetic phenomena (electric field), sedimentation (gravitational field), diffusion (concentration/chemical potential gradient), and non-Newtonian rheology (shear field). The treatment aims to impart a sound, quantitative understanding based on fundamental theory and experiments with well-characterized model systems. This broad grasp of the fundamentals lends insight and helps to develop the intuitive sense needed to isolate essential features of technological problems and design critical experiments. Some exposure to fluid mechanics, statistical mechanics, and electricity and magnetism is assumed, but each subject is reintroduced in a self-contained manner.

  12. Second Vapor-Level Sensor For Vapor Degreaser

    NASA Technical Reports Server (NTRS)

    Painter, Nance M.; Burley, Richard K.

    1990-01-01

    Second vapor-level sensor installed at lower level in vapor degreaser makes possible to maintain top of vapor at that lower level. Evaporation reduced during idle periods. Provides substantial benefit, without major capital cost of building new vapor degreaser with greater freeboard height.

  13. Gasoline Vapor Recovery

    NASA Technical Reports Server (NTRS)

    1979-01-01

    Gasoline is volatile and some of it evaporates during storage, giving off hydrocarbon vapor. Formerly, the vapor was vented into the atmosphere but anti-pollution regulations have precluded that practice in many localities, so oil companies and storage terminals are installing systems to recover hydrocarbon vapor. Recovery provides an energy conservation bonus in that most of the vapor can be reconverted to gasoline. Two such recovery systems are shown in the accompanying photographs (mid-photo at right and in the foreground below). They are actually two models of the same system, although.configured differently because they are customized to users' needs. They were developed and are being manufactured by Edwards Engineering Corporation, Pompton Plains, New Jersey. NASA technological information proved useful in development of the equipment.

  14. Optimization and testing of the Beck Engineering free-piston cryogenic pump for LNG systems on heavy vehicles. Final technical report

    SciTech Connect

    Beck, Douglas S.

    2003-01-10

    Task 7 was completed by reaching Milestone 7: Test free piston cryogenic pump (FPCP) in Integrated LNG System. Task 4: Alternative Pump Design was also completed. The type of performance of the prototype LNG system is consistent with requirements of fuel systems for heavy vehicles; however, the maximum flow capacity of the prototype LNG system is significantly less than the total flow requirement. The flow capacity of the prototype LNG system is determined by a cavitation limit for the FPCP.

  15. Light-Drag Enhancement by a Highly Dispersive Rubidium Vapor.

    PubMed

    Safari, Akbar; De Leon, Israel; Mirhosseini, Mohammad; Magaña-Loaiza, Omar S; Boyd, Robert W

    2016-01-01

    The change in the speed of light as it propagates through a moving material has been a subject of study for almost two centuries. This phenomenon, known as the Fresnel light-drag effect, is quite small and usually requires a large interaction path length and/or a large velocity of the moving medium to be observed. Here, we show experimentally that the observed drag effect can be enhanced by over 2 orders of magnitude when the light beam propagates through a moving slow-light medium. Our results are in good agreement with the theoretical prediction, which indicates that, in the limit of large group indices, the strength of the light-drag effect is proportional to the group index of the moving medium. PMID:26799017

  16. Scale effects in liquefied-fuel-gas vapor dispersion

    NASA Astrophysics Data System (ADS)

    Fay, J. A.; Ranck, D.

    1981-09-01

    A generalized framework for comparing experimental observations of dense cloud behavior and, ultimately, for comparing the predictions of mathematical models with the experimental data is proposed. The dual bases of this framework are the definition of dimensionless variables and the use of a simple entrainment model to depict the expected relationships among the dimensionless variables. To test the usefulness of this methodology, all the available data from wind tunnel and field tests were correlated in accordance with the proposed scheme.

  17. Process simulation for a new conceptual design of LNG terminal coupling NGL recovery and LNG re-gasification for maximum energy savings

    NASA Astrophysics Data System (ADS)

    Muqeet, Mohammed A.

    With the high demands of shale gas and promising development of LNG terminals, a lot of research has focused towards the process development for effective recovery of C2+ hydrocarbons (NGL). Shale gas requires a large amount of cold energy to cool down and recover the NGL; and the LNG re-gasification process requires a lot of heat energy to evaporate for NGL recovery. Thus, coupling the shale gas NGL recovery process and LNG re-gasification process, for utilizing the cold energy from LNG re-gasification process to assist NGL recovery from shale gas has significant economic benefits on both energy saving and high value product recovery. Wang et al. developed new conceptual design of such coupled process in 2013 and later Wang and Xu developed an optimal design considering uncertainties in 2014. This work deals with process simulation of both these designs and the feasibility of the process is verified. A steady state model is developed based on the plant design proposed by Wang et al. using Aspen plusRTM and then a dynamic model of the process is developed using Aspen dynamicsRTM. An effective control strategy is developed and the flexibility of the dynamic model is examined by giving disturbances in the shale gas feed. A comparison is made between the two proposed design and the prospects of the design for real plant scenario is discussed.

  18. 40 CFR Table W - 5 of Subpart W of Part 98-Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Methane Emission Factors for Liquefied Natural Gas (LNG) Storage W Table W Protection of Environment... Petroleum and Natural Gas Systems Definitions. Pt. 98, Subpt. W, Table W-5 Table W-5 of Subpart W of Part 98—Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage LNG storage Emission factor...

  19. 40 CFR Table W - 5 of Subpart W of Part 98-Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Methane Emission Factors for Liquefied Natural Gas (LNG) Storage W Table W Protection of Environment... Petroleum and Natural Gas Systems Definitions. Pt. 98, Subpt. W, Table W-5 Table W-5 of Subpart W of Part 98—Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage LNG storage Emission factor...

  20. 77 FR 58118 - Freeport LNG Development, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC, FLNG...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-09-19

    ... Energy Regulatory Commission Freeport LNG Development, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC, FLNG Liquefaction 3, LLC; Notice of Application Take notice that on August 31, 2012, Freeport LNG Development, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC, and FLNG Liquefaction 3,...

  1. 77 FR 65546 - Sabine Pass Liquefaction, LLC; Sabine Pass LNG, L.P.; Notice of Petition To Amend Authorizations...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-29

    ... Energy Regulatory Commission Sabine Pass Liquefaction, LLC; Sabine Pass LNG, L.P.; Notice of Petition To... Pass Liquefaction, LLC and Sabine Pass LNG, L.P. (collectively, Sabine Pass), 700 Milam Street, Suite... authorizations granted on April 16, 2012 in Docket No. CP11-72-000 (Liquefaction Project) in order to...

  2. 78 FR 66909 - Sabine Pass Liquefaction, LLC; Sabine Pass LNG, L.P.; Notice of Application to Amend...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-07

    ... Energy Regulatory Commission Sabine Pass Liquefaction, LLC; Sabine Pass LNG, L.P.; Notice of Application... Sabine Pass Liquefaction, LLC and Sabine Pass LNG, L.P. (collectively, Sabine Pass), 700 Milam Street... authorizations granted on April 16, 2012 in Docket No. CP11-72-000 (Liquefaction Project), as amended in...

  3. 76 FR 9573 - Sabine Pass Liquefaction, LLC and Sabine Pass LNG, L.P.; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-02-18

    ... Energy Regulatory Commission Sabine Pass Liquefaction, LLC and Sabine Pass LNG, L.P.; Notice of Application Take notice that on January 31, 2011, Sabine Pass Liquefaction, LLC and Sabine Pass LNG, L.P... the Commission's Regulations, to site, construct, and operate liquefaction and export...

  4. 75 FR 61475 - Cameron LNG, LLC; Notice of Intent To Prepare an Environmental Assessment for the Proposed...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-05

    ... Energy Regulatory Commission Cameron LNG, LLC; Notice of Intent To Prepare an Environmental Assessment for the Proposed Cameron LNG Export Project and Request for Comments on Environmental Issues September... important environmental issues. By this notice, the Commission requests public comments on the scope of...

  5. 77 FR 48145 - Cameron Interstate Pipeline, LLC, Cameron LNG, LLC; Notice of Intent To Prepare an Environmental...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-13

    ... Project in the first quarter of 2015 and complete construction during the second quarter of 2016. The... for commissioning of the initial liquefaction train at the LNG terminal in the fourth quarter of 2016... quarter of 2016. Operations would commence after the commissioning of the first LNG liquefaction...

  6. Natural gas and CO2 price variation: impact on the relative cost-efficiency of LNG and pipelines

    PubMed Central

    Ulvestad, Marte; Overland, Indra

    2012-01-01

    This article develops a formal model for comparing the cost structure of the two main transport options for natural gas: liquefied natural gas (LNG) and pipelines. In particular, it evaluates how variations in the prices of natural gas and greenhouse gas emissions affect the relative cost-efficiency of these two options. Natural gas is often promoted as the most environmentally friendly of all fossil fuels, and LNG as a modern and efficient way of transporting it. Some research has been carried out into the local environmental impact of LNG facilities, but almost none into aspects related to climate change. This paper concludes that at current price levels for natural gas and CO2 emissions the distance from field to consumer and the volume of natural gas transported are the main determinants of transport costs. The pricing of natural gas and greenhouse emissions influence the relative cost-efficiency of LNG and pipeline transport, but only to a limited degree at current price levels. Because more energy is required for the LNG process (especially for fuelling the liquefaction process) than for pipelines at distances below 9100 km, LNG is more exposed to variability in the price of natural gas and greenhouse gas emissions up to this distance. If the prices of natural gas and/or greenhouse gas emission rise dramatically in the future, this will affect the choice between pipelines and LNG. Such a price increase will be favourable for pipelines relative to LNG. PMID:24683269

  7. 78 FR 75339 - Barca LNG LLC; Application for Long-Term Authorization To Export Liquefied Natural Gas Produced...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-11

    ... LNG LLC; Application for Long-Term Authorization To Export Liquefied Natural Gas Produced From Domestic Natural Gas Resources to Non-Free Trade Agreement Countries for a 25-Year Period AGENCY: Office of...) of natural gas, or 1.6 Bcf per day (Bcf/d). Barca seeks authorization to export the LNG for a...

  8. Seismic analysis of a LNG storage tank isolated by a multiple friction pendulum system

    NASA Astrophysics Data System (ADS)

    Zhang, Ruifu; Weng, Dagen; Ren, Xiaosong

    2011-06-01

    The seismic response of an isolated vertical, cylindrical, extra-large liquefied natural gas (LNG) tank by a multiple friction pendulum system (MFPS) is analyzed. Most of the extra-large LNG tanks have a fundamental frequency which involves a range of resonance of most earthquake ground motions. It is an effective way to decrease the response of an isolation system used for extra-large LNG storage tanks under a strong earthquake. However, it is difficult to implement in practice with common isolation bearings due to issues such as low temperature, soft site and other severe environment factors. The extra-large LNG tank isolated by a MFPS is presented in this study to address these problems. A MFPS is appropriate for large displacements induced by earthquakes with long predominant periods. A simplified finite element model by Malhotra and Dunkerley is used to determine the usefulness of the isolation system. Data reported and statistically sorted include pile shear, wave height, impulsive acceleration, convective acceleration and outer tank acceleration. The results show that the isolation system has excellent adaptability for different liquid levels and is very effective in controlling the seismic response of extra-large LNG tanks.

  9. [The preparation, characterization and ultraviolet photodegradation of LNG-HP-beta-CD].

    PubMed

    Wang, Da-wei; Liu, Qi; Liu, Ming; Liu, Xiao-hui

    2011-03-01

    The characteristics of levonorgestrel (LNG), low solubility and the quick degradation under ultraviolet, limited its study and application in rodent contraception. The inclusion complex of hydroxypropyl-beta-cyclodextrin (HP-beta-CD) with LNG was investigated in present study. The inclusion complex was prepared by solution method and characterized by ultraviolet absorption spectrum and infrared spectrum spectra. And the stability was evaluated by being exposed to ultraviolet. The authors' results showed that the accurate and simple method of quantitative determination for LNG was established by ultraviolet spectrum, the molar ratio of the complex was 1:1 calculated from the phase solubility diagram, the stability constant was 187.3 L x mol(-1) at 25 degrees C, and the formation of the inclusion complex was validated by UV-Vis and Fourier transform infrared spectroscopy. Moreover, the degradation rate of the inclusion complex was less than 5%, which was slower than the LNG monomer. The present study indicated that HP-beta-CD could be formed inclusion complexes with LNG and the solubility, and stability were obviously enhanced. PMID:21595245

  10. Results of the evaluation and preliminary validation of a primary LNG mass flow standard

    NASA Astrophysics Data System (ADS)

    van der Beek, Mijndert; Lucas, Peter; Kerkhof, Oswin; Mirzaei, Maria; Blom, Gerard

    2014-10-01

    LNG custody transfer measurements at large terminals have been based on ship tank level gauging for more than 50 years. Flow meter application has mainly been limited to process control in spite of the promise of simplified operations, potentially smaller uncertainties and better control over the measurements for buyers. The reason for this has been the lack of LNG flow calibration standards as well as written standards. In the framework of the EMRP1 ‘Metrology for LNG’ project, Van Swinden Laboratory (VSL) has developed a primary LNG mass flow standard. This standard is so far the only one in the world except for a liquid nitrogen flow standard at the National Institute of Standards and Technology (NIST). The VSL standard is based on weighing and holds a Calibration and Measurement Capability (CMC) of 0.12% to 0.15%. This paper discusses the measurement principle, results of the uncertainty validation with LNG and the differences between water and LNG calibration results of four Coriolis mass flow meters. Most of the calibrated meters do not comply with their respective accuracy claims. Recommendations for further improvement of the measurement uncertainty will also be discussed.