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Sample records for long-range chemical gradients

  1. Rapid generation of biologically relevant hydrogels containing long-range chemical gradients **

    PubMed Central

    He, Jiankang; Du, Yanan; Villa-Uribe, Jose L; Hwang, Changmo; Li, Dichen

    2010-01-01

    Many biological processes are regulated by gradients of bioactive chemicals. Thus, the generation of materials with embedded chemical gradients may be beneficial for understanding biological phenomena and generating tissue-mimetic constructs. Here we describe a simple and versatile method to rapidly generate materials containing centimeter-long gradients of chemical properties in a microfluidic channel. The formation of chemical gradient was initiated by a passive-pump-induced forward flow and further developed during an evaporation-induced backward flow. The gradient was spatially controlled by the backward flow time and the hydrogel material containing the gradient was synthesized via photopolymerization. Gradients of a cell-adhesion ligand, Arg-Gly-Asp-Ser (RGDS), was incorporated in the poly(ethylene glycol)-diacrylate (PEG-DA) hydrogels to test the response of endothelial cells. The cells attached and spread along the hydrogel material in a manner consistent with the RGDS gradient profile. A hydrogel containing PEG-DA concentration gradient and constant RGDS concentration was also generated. The morphology of cells cultured on such hydrogel changed from round in the lower PEG-DA concentration regions to well-spread in the higher PEG-DA concentration regions. This approach is expected to be a valuable tool to investigate the cell-material interactions in a simple and high-throughput manner and to design graded biomimetic materials for tissue engineering applications. PMID:20216924

  2. A diffusion based long-range and steady chemical gradient generator on a microfluidic device for studying bacterial chemotaxis

    NASA Astrophysics Data System (ADS)

    Murugesan, Nithya; Singha, Siddhartha; Panda, Tapobrata; Das, Sarit K.

    2016-03-01

    Studies on chemotaxis in microfluidics device have become a major area of research to generate physiologically similar environment in vitro. In this work, a novel micro-fluidic device has been developed to study chemo-taxis of cells in near physiological condition which can create controllable, steady and long-range chemical gradients using various chemo-effectors in a micro-channel. Hydrogels like agarose, collagen, etc, can be used in the device to maintain exclusive diffusive flux of various chemical species into the micro-channel under study. Variations of concentrations and flow rates of Texas Red dextran in the device revealed that an increase in the concentration of the dye in the feed from 6 to 18 μg ml-1, causes a steeper chemical gradient in the device, whereas the flow rate of the dye has practically no effect on the chemical gradient in the device. This observation confirms that a diffusion controlled chemical gradient is generated in the micro-channel. Chemo-taxis of E. coli cells were studied under the steady gradient of a chemo-attractant and a chemo-repellent separately in the same chemical gradient generator. For sorbitol and NiSO4·6H2O, the bacterial cells exhibit a steady distribution in the micro channel after 1 h and 30 min, respectively. From the distribution of bacterial population chemo-tactic strength of the chemo-effectors was estimated for E. coli. In a long microfluidic channel, migration behavior of bacterial cells under diffusion controlled chemical gradient showed chemotaxis, random movement, aggregation, and concentration dependent reverse chemotaxis.

  3. Convection driven generation of long-range material gradients

    PubMed Central

    Du, Yanan; Hancock, Matthew J.; He, Jiankang; Villa-Uribe, Jose; Wang, Ben; Cropek, Donald M.; Khademhosseini, Ali

    2009-01-01

    Natural materials exhibit anisotropy with variations in soluble factors, cell distribution, and matrix properties. The ability to recreate the heterogeneity of the natural materials is a major challenge for investigating cell-material interactions and for developing biomimetic materials. Here we present a generic fluidic approach using convection and alternating flow to rapidly generate multi-centimeter gradients of biomolecules, polymers, beads and cells and cross-gradients of two species in a microchannel. Accompanying theoretical estimates and simulations of gradient growth provide design criteria over a range of material properties. A poly(ethyleneglycol) hydrogel gradient, a porous collagen gradient and a composite material with a hyaluronic acid/gelatin cross-gradient were generated with continuous variations in material properties and in their ability to regulate cellular response. This simple yet generic fluidic platform should prove useful for creating anisotropic biomimetic materials and high-throughput platforms for investigating cell-microenvironment interaction. PMID:20035990

  4. Long-range order and dynamic structure factor of a nematic under a thermal gradient

    NASA Astrophysics Data System (ADS)

    Rodríguez, R. F.; Híjar, H.

    2006-03-01

    We use a fluctuating hydrodynamic approach to calculate the orientation fluctuations correlation functions of a thermotropic nematic liquid crystal in a nonequilibrium state induced by a stationary heat flux. Since in this nonequilibrium stationary state the hydrodynamic fluctuations evolve on three widely separated times scales, we use a time-scale perturbation procedure in order to partially diagonalize the hydrodynamic matrix. The wave number and frequency dependence of these orientation correlation functions is evaluated and their explicit functional form on position is also calculated analytically in and out of equilibrium. We show that for both states these correlations are long-ranged. This result shows that indeed, even in equilibrium there is long-range orientational order in the nematic, consistently with the well known properties of these systems.We also calculate the dynamic structure of the fluid in both states for a geometry consistent with light scattering experiments. We find that as with isotropic simple fluids, the external temperature gradient introduces an asymmetry in the spectrum shifting its maximum by an amount proportional to the magnitude of the gradient. This effect may be of the order of 7 per cent. Also, the width at half height may decrease by a factor of about 10 per cent. Since to our knowledge there are no experimental results available in the literature to compare with, the predictions of our model calculation remains to be assessed.

  5. Long-range electron transport in Geobacter sulfurreducens biofilms is redox gradient-driven

    PubMed Central

    Snider, Rachel M.; Strycharz-Glaven, Sarah M.; Tsoi, Stanislav D.; Erickson, Jeffrey S.; Tender, Leonard M.

    2012-01-01

    Geobacter spp. can acquire energy by coupling intracellular oxidation of organic matter with extracellular electron transfer to an anode (an electrode poised at a metabolically oxidizing potential), forming a biofilm extending many cell lengths away from the anode surface. It has been proposed that long-range electron transport in such biofilms occurs through a network of bound redox cofactors, thought to involve extracellular matrix c-type cytochromes, as occurs for polymers containing discrete redox moieties. Here, we report measurements of electron transport in actively respiring Geobacter sulfurreducens wild type biofilms using interdigitated microelectrode arrays. Measurements when one electrode is used as an anode and the other electrode is used to monitor redox status of the biofilm 15 μm away indicate the presence of an intrabiofilm redox gradient, in which the concentration of electrons residing within the proposed redox cofactor network is higher farther from the anode surface. The magnitude of the redox gradient seems to correlate with current, which is consistent with electron transport from cells in the biofilm to the anode, where electrons effectively diffuse from areas of high to low concentration, hopping between redox cofactors. Comparison with gate measurements, when one electrode is used as an electron source and the other electrode is used as an electron drain, suggests that there are multiple types of redox cofactors in Geobacter biofilms spanning a range in oxidation potential that can engage in electron transport. The majority of these redox cofactors, however, seem to have oxidation potentials too negative to be involved in electron transport when acetate is the electron source. PMID:22955881

  6. Long-range transport of Saharan dust and chemical transformations over the Eastern Mediterranean

    NASA Astrophysics Data System (ADS)

    Athanasopoulou, E.; Protonotariou, A.; Papangelis, G.; Tombrou, M.; Mihalopoulos, N.; Gerasopoulos, E.

    2016-09-01

    Three recent Saharan dust outbreaks during different seasons (4-6 days in winter of 2009, late autumn of 2010 and summer of 2011) are selected in order to study the chemical footprint and aging processes of dust intrusions over the Eastern Mediterranean (EM). The applied model system (PMCAMx, WRF and GEOS-CHEM) and methodology are found competent to reproduce dust production, long-range transport and chemical transformations over the EM, with the synergistic use of synoptic patterns analysis, optical depth retrievals, back-trajectories, surface and satellite aerosol measurements. The dust loads were high during the cold period events and much lighter during summertime, when transport was mainly in the free troposphere. In all cases, dust originated from the northwest and/or west Saharan desert and reached the EM from the west/southwest. Sensitivity runs underlie the effect of dust transport on the chemical constituents of aerosols over the EM and show a large impact on calcium (70-90% of maximum daily values 2-5 μg m-3), with its gradient at surface level being around -10% per 100 km along the dust pathway. For the cold period cases, this value can also be considered analogous to the dust dissipation ratio, because the plume is vertically extended down to the surface layers. Interestingly, the surface particulate nitrate concentrations over the EM are reversely affected by the approaching dust loads, exhibiting the highest values (up to 6 μg m-3) and the largest dust fraction (ca. 70%) during summertime. This is attributed to the enhanced nitric acid formation under high atmospheric temperature and insolation, its uptake onto the carbonate dust particles, and their effective accumulation, due to low deposition rates over the sea and scarce precipitation. Sulfate formation onto dust particles is found insignificant (rapid reaction with ammonia and/or sea-salt), while the influence of dust and sea-salt on sodium, when spatio-temporal averages are calculated, is

  7. Cellular interpretation of the long-range gradient of Four-jointed activity in the Drosophila wing

    PubMed Central

    Hale, Rosalind; Brittle, Amy L; Fisher, Katherine H; Monk, Nicholas A M; Strutt, David

    2015-01-01

    To understand how long-range patterning gradients are interpreted at the cellular level, we investigate how a gradient of expression of the Four-jointed kinase specifies planar polarised distributions of the cadherins Fat and Dachsous in the Drosophila wing. We use computational modelling to test different scenarios for how Four-jointed might act and test the model predictions by employing fluorescence recovery after photobleaching as an in vivo assay to measure the influence of Four-jointed on Fat-Dachsous binding. We demonstrate that in vivo, Four-jointed acts both on Fat to promote its binding to Dachsous and on Dachsous to inhibit its binding to Fat, with a bias towards a stronger effect on Fat. Overall, we show that opposing gradients of Fat and Dachsous phosphorylation are sufficient to explain the observed pattern of Fat–Dachsous binding and planar polarisation across the wing, and thus demonstrate the mechanism by which a long-range gradient is interpreted. DOI: http://dx.doi.org/10.7554/eLife.05789.001 PMID:25707557

  8. Atmospheric emissions and long-range transport of persistent organic chemicals

    NASA Astrophysics Data System (ADS)

    Scheringer, M.

    2010-12-01

    Persistent organic chemicals include several groups of halogenated compounds, such as polychlorinated biphenyls (PCBs), polybrominated diphenylethers (PBDEs), and polyfluorinated carboxylic acids (PFCAs). These chemicals remain for long times (years to decades) in the environment and cycle between different media (air, water, sediment, soil, vegetation, etc.). The environmental distribution of this type of chemicals can conveniently be analyzed by multimedia models. Multimedia models consist of a set of coupled mass balance equations for the environmental media considered; they can be set up at various scales from local to global. Two applications of multimedia models to airborne chemicals are discussed in detail: the day-night cycle of PCBs measured in air near the surface, and the atmospheric long-range transport of volatile precursors of PFCAs, formation of PFCAs by oxidation of these precursors, and subsequent deposition of PFCAs to the surface in remote regions such as the Arctic.

  9. Chemical and Aerosol Signatures of Biomass Burning via Long Range Transport observed at Storm Peak Laboratory

    NASA Astrophysics Data System (ADS)

    Hallar, A. G.; Obrist, D.; McCubbin, I. B.; Fain, X.; Rahn, T.

    2008-12-01

    The Desert Research Institute operates a high elevation facility, Storm Peak Laboratory (SPL), located on the Steamboat Springs Ski Resort in Colorado at an elevation 3.2 km. During the spring of 2008, two field projects were conducted at SPL; Storm Peak Cloud and Aerosol Characterization (SPACC) and a State of Colorado Mercury Monitoring project. Measurements of gaseous elemental mercury (GEM), along with CO, ozone and aerosol concentrations and aerosol size distributions will be presented from April 28 to July 1st 2008. This work focuses on specific case studies pertaining to long range transport events. Specifically, high levels of GEM and CO will be presented from May 15, 2008. This data will be coupled with HYSPLIT backtrajectories, chemical modeling via MOZART, and satellite imagery (MODIS) to present evidence that Siberian wildfires impacted the air quality at Storm Peak Laboratory.

  10. Network of long-range concerted chemical shift displacements upon ligand binding to human angiogenin

    PubMed Central

    Gagné, Donald; Narayanan, Chitra; Doucet, Nicolas

    2015-01-01

    Molecular recognition models of both induced fit and conformational selection rely on coupled networks of flexible residues and/or structural rearrangements to promote protein function. While the atomic details of these motional events still remain elusive, members of the pancreatic ribonuclease superfamily were previously shown to depend on subtle conformational heterogeneity for optimal catalytic function. Human angiogenin, a structural homologue of bovine pancreatic RNase A, induces blood vessel formation and relies on a weak yet functionally mandatory ribonucleolytic activity to promote neovascularization. Here, we use the NMR chemical shift projection analysis (CHESPA) to clarify the mechanism of ligand binding in human angiogenin, further providing information on long-range intramolecular residue networks potentially involved in the function of this enzyme. We identify two main clusters of residue networks displaying correlated linear chemical shift trajectories upon binding of substrate fragments to the purine- and pyrimidine-specific subsites of the catalytic cleft. A large correlated residue network clusters in the region corresponding to the V1 domain, a site generally associated with the angiogenic response and structural stability of the enzyme. Another correlated network (residues 40–42) negatively affects the catalytic activity but also increases the angiogenic activity. 15N-CPMG relaxation dispersion experiments could not reveal the existence of millisecond timescale conformational exchange in this enzyme, a lack of flexibility supported by the very low-binding affinities and catalytic activity of angiogenin. Altogether, the current report potentially highlights the existence of long-range dynamic reorganization of the structure upon distinct subsite binding events in human angiogenin. PMID:25450558

  11. On chemical distances and shape theorems in percolation models with long-range correlations

    SciTech Connect

    Drewitz, Alexander; Ráth, Balázs; Sapozhnikov, Artëm

    2014-08-01

    In this paper, we provide general conditions on a one parameter family of random infinite subsets of Z{sup d} to contain a unique infinite connected component for which the chemical distances are comparable to the Euclidean distance. In addition, we show that these conditions also imply a shape theorem for the corresponding infinite connected component. By verifying these conditions for specific models, we obtain novel results about the structure of the infinite connected component of the vacant set of random interlacements and the level sets of the Gaussian free field. As a byproduct, we obtain alternative proofs to the corresponding results for random interlacements in the work of Cerný and Popov [“On the internal distance in the interlacement set,” Electron. J. Probab. 17(29), 1–25 (2012)], and while our main interest is in percolation models with long-range correlations, we also recover results in the spirit of the work of Antal and Pisztora [“On the chemical distance for supercritical Bernoulli percolation,” Ann Probab. 24(2), 1036–1048 (1996)] for Bernoulli percolation. Finally, as a corollary, we derive new results about the (chemical) diameter of the largest connected component in the complement of the trace of the random walk on the torus.

  12. On chemical distances and shape theorems in percolation models with long-range correlations

    NASA Astrophysics Data System (ADS)

    Drewitz, Alexander; Ráth, Balázs; Sapozhnikov, Artëm

    2014-08-01

    In this paper, we provide general conditions on a one parameter family of random infinite subsets of {{Z}}^d to contain a unique infinite connected component for which the chemical distances are comparable to the Euclidean distance. In addition, we show that these conditions also imply a shape theorem for the corresponding infinite connected component. By verifying these conditions for specific models, we obtain novel results about the structure of the infinite connected component of the vacant set of random interlacements and the level sets of the Gaussian free field. As a byproduct, we obtain alternative proofs to the corresponding results for random interlacements in the work of Černý and Popov ["On the internal distance in the interlacement set," Electron. J. Probab. 17(29), 1-25 (2012)], and while our main interest is in percolation models with long-range correlations, we also recover results in the spirit of the work of Antal and Pisztora ["On the chemical distance for supercritical Bernoulli percolation," Ann Probab. 24(2), 1036-1048 (1996)] for Bernoulli percolation. Finally, as a corollary, we derive new results about the (chemical) diameter of the largest connected component in the complement of the trace of the random walk on the torus.

  13. Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons--a review.

    PubMed

    Keyte, Ian J; Harrison, Roy M; Lammel, Gerhard

    2013-12-21

    Polycyclic aromatic hydrocarbons (PAHs) are of considerable concern due to their well-recognised toxicity and especially due to the carcinogenic hazard which they present. PAHs are semi-volatile and therefore partition between vapour and condensed phases in the atmosphere and both the vapour and particulate forms undergo chemical reactions. This article briefly reviews the current understanding of vapour-particle partitioning of PAHs and the PAH deposition processes, and in greater detail, their chemical reactions. PAHs are reactive towards a number of atmospheric oxidants, most notably the hydroxyl radical, ozone, the nitrate radical (NO3) and nitrogen dioxide. Rate coefficient data are reviewed for reactions of lower molecular weight PAH vapour with these species as well as for heterogeneous reactions of higher molecular weight compounds. Whereas the data for reactions of the 2-3-ring PAH vapour are quite extensive and generally consistent, such data are mostly lacking for the 4-ring PAHs and the heterogeneous rate data (5 and more rings), which are dependent on the substrate type and reaction conditions, are less comprehensive. The atmospheric reactions of PAH lead to the formation of oxy and nitro derivatives, reviewed here, too. Finally, the capacity of PAHs for long range transport and the results of numerical model studies are described. Research needs are identified. PMID:24077263

  14. Chemical characteristics of Northeast Asian fly ash particles: Implications for their long-range transportation

    NASA Astrophysics Data System (ADS)

    Inoue, Jun; Momose, Azusa; Okudaira, Takamoto; Murakami-Kitase, Akiko; Yamazaki, Hideo; Yoshikawa, Shusaku

    2014-10-01

    The chemical compositions of fly ash particles emitted in Northeast Asia were studied to better understand the long-range transportation of atmospheric pollutants. We examined the compositions of spheroidal carbonaceous particles (SCPs), a type of fly ash from several to ˜20 μm in diameter found in surface sediments in or near the main industrial cities of Japan, China, South Korea, and Taiwan. SCPs from different countries were found to vary; SCPs from Japan and South Korea were characterized by low Ti/Si and high S/Si ratios, whereas SCPs in China exhibited high Ti/Si and low S/Si ratios and particles from Taiwan showed high Ti/Si and S/Si ratios. We also examined the SCPs found in remote islands in the Sea of Japan, at least 100 km from any industrial city. On the basis of their chemical compositions, these SCPs were classified as Japan and Korea, China, and Taiwan types using discriminant analysis. The results indicated that 30-50% of the particles found in these islands were assigned to the China type, suggesting that most of these SCPs were probably transported from Chinese industrial regions to these islands. It implies that even large particulate pollutants of ˜10 μm, such as SCPs, could be transported long distances of ˜1000 km.

  15. Fabrication of long-range surface plasmon polaritons waveguide by wet chemical etching

    NASA Astrophysics Data System (ADS)

    Xie, Ying; Liu, Tong; Zhao, Xuliang; Zhang, Meiling; Chen, Changming; Wang, Fei; Sun, Xiaoqiang; Zhang, Daming

    2014-06-01

    The fabrication of long-range surface plasmon polaritons (LRSPPs) waveguides based on a thin Au stripe embedded in poly(methyl-methacrylate-glycidly-methacrylate) polymers was investigated. By patterning the photoresist, a wet chemical etching technique was used to avoid sharp pin-like and shark-fin-like structures on the edges of the Au stripe. The surface morphology of the Au film and polymer cladding were studied by atomic force microscopy (AFM), as well as by using the waveguide configuration of the Au stripe. AFM images proved the elimination of parasitic structures. A 2 cm long, 4 μm wide, and 25 nm thick Au stripe waveguide exhibited a propagation loss of approximately 4.3 dB cm-1 measured by the cut-back method and end-fire excitation of LRSPP mode guiding at 1550 nm. The demonstration of optical signal transmission indicates that the LRSPP waveguide fabricated by wet chemical etching is a potential solution to on-chip optical interconnections.

  16. Long-range standoff detection of chemical, biological, and explosive hazards on surfaces

    NASA Astrophysics Data System (ADS)

    Fountain, Augustus Way, III; Guicheteau, Jason A.; Pearman, William F.; Chyba, Thomas H.; Christesen, Steven D.

    2010-04-01

    Fielded surface detection systems rely on contact with either the liquid contamination itself or the associated chemical vapor above the contaminated surface and do not provide a standoff or remote detection capability. Conversely, standoff chemical vapor sensing techniques have not shown efficacy in detecting those contaminants as liquids or solids on surfaces. There are a number of optical or spectroscopic techniques that could be applied to this problem of standoff chemical detection on surfaces. The three techniques that have received the most interest and development are laser induced breakdown spectroscopy (LIBS), fluorescence, and Raman spectroscopy. Details will be presented on the development of these techniques and their applicability to detecting CBRNE contamination on surfaces.

  17. Long range standoff detection of chemical and explosive hazards on surfaces

    NASA Astrophysics Data System (ADS)

    Fountain, Augustus Way, III; Christesen, Steven D.; Guicheteau, Jason A.; Pearman, William F.; Chyba, Tom

    2009-09-01

    Fielded surface detection systems rely on contact with either the liquid contamination itself or the associated chemical vapor above the contaminated surface and do not provide a standoff or remote detection capability. Conversely, standoff chemical vapor sensing techniques have not shown efficacy in detecting those contaminants as liquids or solids on surfaces. There are a number of optical or spectroscopic techniques that could be applied to this problem of standoff chemical detection on surfaces. The three techniques that have received the most interest and development are laser induced breakdown spectroscopy (LIBS), fluorescence, and Raman spectroscopy. Details will be presented on the development of these techniques and their applicability to detecting CBRNE contamination on surfaces.

  18. Long-range chemical orders in Au-Pd nanoparticles revealed by aberration-corrected electron microscopy.

    PubMed

    Nelayah, Jaysen; Nguyen, Nhat Tai; Alloyeau, Damien; Wang, Guillaume Yangshu; Ricolleau, Christian

    2014-09-01

    Despite the importance of gold-palladium nanoalloys in heterogeneous catalysis, the phase stability of Au-Pd alloys still remains unclear. We report here on the alloying and chemical ordering in epitaxially-grown and post-annealed gold-palladium nanoparticles (NPs) using aberration-corrected transmission electron microscopy. Au-Pd NPs with a controlled size, composition and structure were grown by pulsed laser deposition on freshly-cleaved NaCl(001) single crystals heated at 300 °C. After transfer to an amorphous carbon support, the NPs were annealed in vacuum at elevated temperatures above 400 °C for a few hours (6-10 hours) to promote chemical ordering. The as-grown NPs were mostly monocrystalline with a chemically-disordered face-centered cubic structure. Upon high-temperature annealing, a high degree of chemical ordering was observed in nanometer-sized NPs. Electron microscopy measurements showed that both L10 and L12 orders are stabilized in the Au-rich region of the Au-Pd phase diagram. These ordered phases exist at temperatures as high as 600 °C. Moreover, compositional analysis of single annealed particles revealed that the observed chemical ordering occurs in parallel to a two-tiered Ostwald ripening process. Due to this ripening process, a clear dependence between chemical composition and particle size is established during annealing with an enrichment in Pd as the NPs grow in size. Our results, besides clarifying some controversial aspects about long-range order in Au-Pd alloys, shed light on the structural stability of Au-Pd nanoalloys at elevated temperatures. PMID:25079393

  19. Implications of the chemical transformation of Asian outflow aerosols for the long-range transport of inorganic nitrogen species

    NASA Astrophysics Data System (ADS)

    Chou, Charles C.-K.; Lee, C. T.; Yuan, C. S.; Hsu, W. C.; Lin, C.-Y.; Hsu, S.-C.; Liu, S. C.

    To improve our understanding of the chemical characteristics of aerosols transported from the Asian continent to the western North Pacific, an aerosol observation network has been established in Taiwan. From the measurements made during 2003-2005, it was found that the aerosol concentrations in the continental outflows were much higher than those of remote areas, evidently due to the long-range transport of air pollutants and dust from the Asian continent. Analysis on the chemical compositions of aerosols revealed that the Asian outflow aerosols underwent chemical transformation and, consequently, became more abundant in ammonium and nitrate when they mixed with air pollutants originating from Taiwan. The NH 4+/SO 42- ratio in fine aerosols (PM2.5) increased from 1.55 at the Cape Fuguei, the northern tip of Taiwan, to 2.30 at Penghu, in the middle of the Taiwan Strait. The increased NH 4+/SO 42- ratio implied that the acidity of the sulfate aerosols in Asian outflows was totally neutralized by ammonia as the aerosols traveled through the North Taiwan and its vicinity. In addition, the analysis indicated that the chlorine deficiency of sea salt aerosols was higher at the southern stations than at the Cape Fuguei. The chlorine deficiency was attributed to the heterogeneous reaction of NaCl and HNO 3(g), which means that the oxidation of SO 2 in sea spray droplets was inhibited. Moreover, uptake of secondary acids by the dust particles was observed. The results of this study suggested that the Asian outflow aerosols are important carriers of gaseous inorganic nitrogen species, particularly nitric acid and ammonia, in this region. Hence the atmospheric deposition of soluble inorganic nitrogen could become enhanced in the northern South China Sea, which is downwind of Taiwan during the periods of Asian winter monsoons.

  20. Thermo-chemical structure of the lithospheric mantle underneath the Siberian craton inferred from long-range seismic profiles

    NASA Astrophysics Data System (ADS)

    Kuskov, O. L.; Kronrod, V. A.; Prokofyev, A. A.; Pavlenkova, N. I.

    2014-03-01

    Based on a self-consistent thermodynamic-geophysical approach and xenolith-based constraints, we map the 2-D seismic, thermal and density structure of the mantle beneath the Siberian craton along the long-range profiles (Craton, Kimberlite, Rift and Meteorite) carried out in Russia with peaceful nuclear explosions. Structural peculiarities of the cratonic mantle are manifested by changes in seismic velocities, the degree and nature of layering and the relief of seismic boundaries. The results predict appreciable lateral temperature variations within the root to a depth of about 200 km, which are the main cause of seismic velocity variations. We find that the cratonic mantle is 300-400 °C colder than the tectonically younger surrounding mantle in this depth range. At greater depths, lateral changes in temperatures have little effect implying that thermal heterogeneity rapidly decreases. The present-day geotherms pass close to the 32.5-35 mW m- 2 conductive models and suggest low mantle heat flow. Within the model resolution, the thickness of the thermal boundary layer, TBL (defined as the depth of the 1300 °C adiabat) beneath Siberia does not depend significantly on the composition and can be estimated as 300 ± 30 km; temperature at the base of the TBL is close to the 1450 ± 100 °C isotherm. Changes in the composition from depleted to fertile material reveal a negligible effect on seismic velocities, which are practically unresolved by seismic methods, but remain the most important factor for the density increase of the cratonic root. Density variations in the lower part of the root due to the chemical composition are greater than those caused by temperature. We find that both compositional and thermal anomalies are required to explain the Siberian mantle by a keel model consisting of depleted garnet peridotite at depths of 100 to 180 km and more fertile material at greater depths.

  1. Long Range Technology Planning.

    ERIC Educational Resources Information Center

    Ambron, Sueann, Ed.

    1986-01-01

    This summary of a meeting of the Apple Education Advisory Council, on long range technology plans at the state, county, district, and school levels, includes highlights from group discussions on future planning, staff development, and curriculum. Three long range technology plans at the state level are provided: Long Range Educational Technology…

  2. Development of frequency-agile high-repetition-rate CO{sub 2} DIAL systems for long range chemical remote sensing

    SciTech Connect

    Quick, C.R. Jr.; Fite, C.B.; Foy, B.R.; Jolin, J.; Mietz, D.E.

    1997-11-01

    Issues related to the development of direct detection, long-range CO{sub 2} DIAL systems for chemical detection and identification are presented and discussed including: data handling and display techniques for large, multi-{lambda} data sets, turbulence effects, slant path propagation, and speckle averaging. Data examples from various field campaigns and CO{sub 2} lidar platforms are used to illustrate the issues.

  3. Long-Range Chemical Sensitivity in the Sulfur K-Edge X-ray Absorption Spectra of Substituted Thiophenes

    PubMed Central

    2015-01-01

    Thiophenes are the simplest aromatic sulfur-containing compounds and are stable and widespread in fossil fuels. Regulation of sulfur levels in fuels and emissions has become and continues to be ever more stringent as part of governments’ efforts to address negative environmental impacts of sulfur dioxide. In turn, more effective removal methods are continually being sought. In a chemical sense, thiophenes are somewhat obdurate and hence their removal from fossil fuels poses problems for the industrial chemist. Sulfur K-edge X-ray absorption spectroscopy provides key information on thiophenic components in fuels. Here we present a systematic study of the spectroscopic sensitivity to chemical modifications of the thiophene system. We conclude that while the utility of sulfur K-edge X-ray absorption spectra in understanding the chemical composition of sulfur-containing fossil fuels has already been demonstrated, care must be exercised in interpreting these spectra because the assumption of an invariant spectrum for thiophenic forms may not always be valid. PMID:25116792

  4. Investigating long-range transport of pollution to the Arctic troposphere using aircraft observations and a global chemical transport model

    NASA Astrophysics Data System (ADS)

    Monks, S.; Arnold, S.; Chipperfield, M.; Turquety, S.; Ancellet, G.; Law, K.; Schlager, H.

    2009-04-01

    Surface temperatures in the Arctic have increased more than in any other region over the past few decades. A better understanding of the processes governing this warming, including the role of short-lived greenhouse gases, is therefore urgently required. During summer 2008, the POLARCAT campaign aimed to collect an extensive gas-phase and aerosol dataset within the Arctic troposphere, which will aid the evaluation of our understanding of oxidant photochemistry and aerosol processing in the region. Previous comparisons of global chemical transport models have shown that they exhibit large variability in their Arctic chemical budgets, indicating that the processes controlling Arctic tropospheric composition are not well understood or represented within models. Here, we will use new trace-gas observations from the French ATR and German DLR Falcon aircraft during the POLARCAT experiment to evaluate the ability of a global chemical transport model (TOMCAT) to simulate the summertime transport of pollutants to the Arctic, and their impact on oxidant budgets. In particular, we aim to quantify the impact of anthropogenic and biomass burning sources on the Arctic tropospheric ozone budget. Initial results show that the model underestimates observed concentrations of CO which has led to a re-evaluation of the different sources of CO to the region. Model performance in the Arctic is highly sensitive to the treatment of boreal biomass burning emissions. Boreal biomass burning plumes were sampled frequently over the course of the campaign therefore accurate representation of emission injection heights and fire locations is essential. Model CO is improved with real-time satellite derived daily biomass burning emissions, however large uncertainties in these emissions result in large variability in the Arctic CO budget. We will also present results on the ability of the model to capture pollution transport pathways to the Arctic and contributions to the oxidant and NOy budgets

  5. A new multimedia contaminant fate model for China: how important are environmental parameters in influencing chemical persistence and long-range transport potential?

    PubMed

    Zhu, Ying; Price, Oliver R; Tao, Shu; Jones, Kevin C; Sweetman, Andy J

    2014-08-01

    We present a new multimedia chemical fate model (SESAMe) which was developed to assess chemical fate and behaviour across China. We apply the model to quantify the influence of environmental parameters on chemical overall persistence (POV) and long-range transport potential (LRTP) in China, which has extreme diversity in environmental conditions. Sobol sensitivity analysis was used to identify the relative importance of input parameters. Physicochemical properties were identified as more influential than environmental parameters on model output. Interactive effects of environmental parameters on POV and LRTP occur mainly in combination with chemical properties. Hypothetical chemicals and emission data were used to model POV and LRTP for neutral and acidic chemicals with different KOW/DOW, vapour pressure and pKa under different precipitation, wind speed, temperature and soil organic carbon contents (fOC). Generally for POV, precipitation was more influential than the other environmental parameters, whilst temperature and wind speed did not contribute significantly to POV variation; for LRTP, wind speed was more influential than the other environmental parameters, whilst the effects of other environmental parameters relied on specific chemical properties. fOC had a slight effect on POV and LRTP, and higher fOC always increased POV and decreased LRTP. Example case studies were performed on real test chemicals using SESAMe to explore the spatial variability of model output and how environmental properties affect POV and LRTP. Dibenzofuran released to multiple media had higher POV in northwest of Xinjiang, part of Gansu, northeast of Inner Mongolia, Heilongjiang and Jilin. Benzo[a]pyrene released to the air had higher LRTP in south Xinjiang and west Inner Mongolia, whilst acenaphthene had higher LRTP in Tibet and west Inner Mongolia. TCS released into water had higher LRTP in Yellow River and Yangtze River catchments. The initial case studies demonstrated that SESAMe

  6. Observation of chemical modification of Asian Dust particles during long-range transport by the combined use of quantitative ED-EPMA and ATR-FT-IR imaging

    NASA Astrophysics Data System (ADS)

    Song, Young-Chul; Eom, Hyo-Jin; Jung, Hae-Jin; Malek, Md Abdul; Kim, HyeKyeong; Ro, Chul-Un

    2012-10-01

    In our previous works, it was demonstrated that the combined use of quantitative energy-dispersive electron probe X-ray microanalysis (ED-EPMA), which is also known as low-Z particle EPMA, and attenuated total reflectance FT-IR (ATR-FT-IR) imaging has great potential for a detailed characterization of individual aerosol particles. In this study, individual Asian Dust particles collected during an Asian Dust storm event on 11 November 2011 in Korea were characterized by the combined use of low-Z particle EPMA and ATR-FT-IR imaging. The combined use of the two single-particle analytical techniques on the same individual particles showed that Asian Dust particles had experienced extensive chemical modification during long-range transport. Overall, 109 individual particles were classified into four particle types based on their morphology, elemental concentrations, and molecular species and/or functional groups of individual particles available from the two analytical techniques: Ca-containing (38%); NaNO3-containing (30%); silicate (22%); and miscellaneous particles (10%). Among the 41 Ca-containing particles, 10, 8, and 14 particles contained nitrate, sulfate, and both, respectively, whereas only two particles contained unreacted CaCO3. Airborne amorphous calcium carbonate (ACC) particles were observed in this Asian Dust sample for the first time, where their IR peaks for the insufficient symmetric environment of CO32- ions of ACC were clearly differentiated from those of crystalline CaCO3. This paper also reports the field observations of CaCl2 particles converted from CaCO3 for the Asian Dust sample collected in the planetary boundary layer. Thirty three particles contained NaNO3, which are the reaction products of sea-salt and NOx/HNO3, whereas no genuine sea-salt particles were encountered, indicating that sea-salt particles are more reactive than CaCO3 particles. Some silicate particles were observed to contain nitrate, sulfate, and water. Among 24 silicate

  7. Results of joint processing of data on nuclear and chemical explosions recorded on the long-range Quartz profile (Murmansk-Kyzyl)

    NASA Astrophysics Data System (ADS)

    Pavlenkova, G. A.; Pavlenkova, N. I.

    2008-04-01

    The long-range seismic profile Quartz, measured by the GEON Center (Ministry of Geology of the USSR), crosses a few large geostructures: the East European platform, Timan-Pechora plate, Northern Urals, West Siberian plate (WSP), and Altai. Observations of nuclear and chemical explosions were conducted on the profile. Joint processing of records from sources of both types provided detailed structures of the crust and upper mantle. They have confirmed the known patterns in the structure of these shells of the Earth and revealed new ones. Mountain roots are observed beneath the Urals and Altai, and areas of a higher heat flow are matched by lower velocity zones in the upper mantle. Moreover, it is shown that the Timan-Pechora plate is characterized by a two-layer crust untypical of other young plates of central Eurasia and the upper mantle has the same velocities beneath the ancient East European platform and the young Altai orogen. It is also shown that the vast region including the Timan-Pechora plate, Urals, and WSP is bounded on both sides by deep faults in the upper mantle dipping toward the center of Western Siberia. A few nearly continuous reflectors traceable in the upper mantle are represented by thin-layered heterogeneous beds. The largest horizontal heterogeneity is observed in the upper 100-km layer, often underlain by a lower velocity zone. The asthenosphere, as a layer of lower seismic velocities at the depth of a possible solidus (200 250 km), has not been revealed. The latter is evidently a feature specific to inner parts of the Eurasian continent; in marginal regions, e.g., in Western Europe, the asthenospheric layer is identified almost ubiquitously.

  8. Institutional Long-Range Planning.

    ERIC Educational Resources Information Center

    Bolin, John G.

    This booklet presents a general outline for conducting a long-range planning study that can be adapted for use by any institution of higher education. The basic components of an effective long-range plan should include: (1) purposes of the plan, which define the scope of the study and provide the setting in which it will be initiated; (2) a set of…

  9. Density Gradient Columns for Chemical Displays.

    ERIC Educational Resources Information Center

    Guenther, William B.

    1986-01-01

    Procedures for preparing density gradient columns for chemical displays are presented. They include displays illustrating acid-base reactions, metal ion equilibria, and liquid density. The lifetime of these metastable displays is surprising, some lasting for months in display cabinets. (JN)

  10. Ratchetaxis: Long-Range Directed Cell Migration by Local Cues.

    PubMed

    Caballero, David; Comelles, Jordi; Piel, Matthieu; Voituriez, Raphaël; Riveline, Daniel

    2015-12-01

    Directed cell migration is usually thought to depend on the presence of long-range gradients of either chemoattractants or physical properties such as stiffness or adhesion. However, in vivo, chemical or mechanical gradients have not systematically been observed. Here we review recent in vitro experiments, which show that other types of spatial guidance cues can bias cell motility. Introducing local geometrical or mechanical anisotropy in the cell environment, such as adhesive/topographical microratchets or tilted micropillars, show that local and periodic external cues can direct cell motion. Together with modeling, these experiments suggest that cell motility can be viewed as a stochastic phenomenon, which can be biased by various types of local cues, leading to directional migration. PMID:26615123

  11. Long-range electron transfer

    PubMed Central

    Gray, Harry B.; Winkler, Jay R.

    2005-01-01

    Recent investigations have shed much light on the nuclear and electronic factors that control the rates of long-range electron tunneling through molecules in aqueous and organic glasses as well as through bonds in donor–bridge–acceptor complexes. Couplings through covalent and hydrogen bonds are much stronger than those across van der Waals gaps, and these differences in coupling between bonded and nonbonded atoms account for the dependence of tunneling rates on the structure of the media between redox sites in Ru-modified proteins and protein–protein complexes. PMID:15738403

  12. Long-range atmospheric predictability

    NASA Astrophysics Data System (ADS)

    Reichler, Thomas Josef

    This study investigated the prospects and limits of global atmospheric predictability on the long range (beyond 2 weeks). Forecasting the atmosphere at this range is very challenging since elements of both weather and climate prediction enter the problem. The basic questions were: (1) how large is long-range predictability with perfect model and data; (2) how sensitive is such predictability to uncertainties in model and data; (3) which atmospheric processes are related to this predictability? These questions were answered through numerical experiments with an atmospheric general circulation model which is forced with different combinations of initial and boundary conditions. In particular, four tasks were accomplished: First, temporal variations of predictability and its relationship to initial and boundary conditions were examined. On average, initial conditions dominated predictability for the first 4 weeks, improved predictability for 6 weeks, and influenced predictability for 8 weeks. These time scales varied with season, region, and strength of the external forcing. Second, the global 3-dimensional structure of predictability was examined. Boundary forcing dominated over the tropics, and over the two main teleconnection regions in the North and South Pacific. Initial conditions influenced predictability almost everywhere, in particular when the external forcing was weak. This was mostly related to atmospheric persistence, which in turn was linked to low-frequency variability of major atmospheric modes. Third, predictability in the tropics was investigated for monthly means. Boundary forcing is generally dominating for this time scale, and its quality is crucial. The atmospheric response was strongly asymmetric to SST forcing, which suggests that tropical convection has a positive self-amplifying feedback. Initial conditions were also important, in particular over the Eastern Hemisphere. This was related to strong persistence of the divergent circulation and

  13. Space - The long range future

    NASA Technical Reports Server (NTRS)

    Von Puttkamer, J.

    1985-01-01

    Space exploration goals for NASA in the year 2000 time frame are examined. A lunar base would offer the opportunity for continuous earth viewing, further cosmogeochemical exploration and rudimentary steps at self-sufficiency in space. The latter two factors are also compelling reasons to plan a manned Mars base. Furthermore, competition and cooperation in a Mars mission and further interplanetary exploration is an attractive substitute for war. The hardware requirements for various configurations of Mars missions are briefly addressed, along with other, unmanned missions to the asteroid belt, Mercury, Venus, Jupiter and the moons of Jupiter and Saturn. Finally, long-range technological requirements for providing adequate living/working facilities for larger human populations in Space Station environments are summarized.

  14. Long range fast tool servo

    NASA Astrophysics Data System (ADS)

    Moorefield, G. M., II; Dow, Thomas A.; Falter, Karl J.; Ro, Paul I.

    1993-05-01

    The PEC's MAC 100 Fast Tool Servo (FTS) System has demonstrated the efficacy of fabricating off-axis parabolic segments on axis by utilizing a fast tool motion to machine non-rotationally symmetric surfaces. The key to this technique was a servo for the tool motion that had a high-bandwidth coupled with a small range of motion. The Keck telescope, with its thirty-six (36) 1-meter diameter segments, would have been an excellent application for this technology. Since this technology was not available at the time of construction, each mirror segment was fabricated to its desired shape by loading it to a specified deformed shape and polishing it to a spherical contour, then removing the bending loads to allow the segment to relax to the desired asymmetric shape. If the segments of this optic had been constructed on axis with an FTS, the fabrication of the most extreme segment would have required only about 200 micrometers of non-rotational symmetry. However, the demand for larger displacement actuators is being driven by new applications with nonrotationally symmetric components in the millimeter range. This report describes the search for a suitable actuator for a long range fast tool servo system that would allow the fabrication of non-rotationally symmetric optical surfaces with a 1 mm range of servo motion. To allow cost-effective machining of these surfaces, the actuator must also possess a 50 Hz bandwidth (minimum) and 25 nanometer resolution.

  15. A Cellular System for Spatial Signal Decoding in Chemical Gradients.

    PubMed

    Hegemann, Björn; Unger, Michael; Lee, Sung Sik; Stoffel-Studer, Ingrid; van den Heuvel, Jasmin; Pelet, Serge; Koeppl, Heinz; Peter, Matthias

    2015-11-23

    Directional cell growth requires that cells read and interpret shallow chemical gradients, but how the gradient directional information is identified remains elusive. We use single-cell analysis and mathematical modeling to define the cellular gradient decoding network in yeast. Our results demonstrate that the spatial information of the gradient signal is read locally within the polarity site complex using double-positive feedback between the GTPase Cdc42 and trafficking of the receptor Ste2. Spatial decoding critically depends on low Cdc42 activity, which is maintained by the MAPK Fus3 through sequestration of the Cdc42 activator Cdc24. Deregulated Cdc42 or Ste2 trafficking prevents gradient decoding and leads to mis-oriented growth. Our work discovers how a conserved set of components assembles a network integrating signal intensity and directionality to decode the spatial information contained in chemical gradients. PMID:26585298

  16. Long-range neural synchrony in behavior.

    PubMed

    Harris, Alexander Z; Gordon, Joshua A

    2015-07-01

    Long-range synchrony between distant brain regions accompanies multiple forms of behavior. This review compares and contrasts the methods by which long-range synchrony is evaluated in both humans and model animals. Three examples of behaviorally relevant long-range synchrony are discussed in detail: gamma-frequency synchrony during visual perception, hippocampal-prefrontal synchrony during working memory, and prefrontal-amygdala synchrony during anxiety. Implications for circuit mechanism, translation, and clinical relevance are discussed. PMID:25897876

  17. Long-range neural synchrony in behavior

    PubMed Central

    Harris, Alexander Z.; Gordon, Joshua A.

    2015-01-01

    Long-range synchrony between distant brain regions accompanies multiple forms of behavior. This review compares and contrasts the methods by which long-range synchrony is evaluated in both humans and model animals. Three examples of behaviorally-relevant long-range synchrony are discussed in detail: gamma-frequency synchrony during visual perception; hippocampal-prefrontal synchrony during working memory; and prefrontal-amygdala synchrony during anxiety. Implications for circuit mechanism, translation, and clinical relevance are discussed. PMID:25897876

  18. 1995-1998 Long Range Plan.

    ERIC Educational Resources Information Center

    Pennsylvania Coll. of Technology, Williamsport.

    At Pennsylvania College of Technology (PCT), in Williamsport, long range planning is used to define institutional philosophy and mission and determine strategies to make the best use of available resources and implement actions to fulfill institutional mission. This document presents PCT's long-range plan for 1995-98 in three parts. Following an…

  19. Long Range Plan: 1992-1995.

    ERIC Educational Resources Information Center

    Pennsylvania Coll. of Technology, Williamsport.

    Intended to enhance strategic planning and enable staff to work as a team toward a shared vision and common goals, this report presents the 1992-95 long-range plan of the Pennsylvania College of Technology (PCT). Part I defines long-range planning; describes the structure and use of the plan at PCT; presents PCT's philosophy, mission, and vision…

  20. Long Range Plan, 1991-1994.

    ERIC Educational Resources Information Center

    Pennsylvania Coll. of Technology, Williamsport.

    This long-range plan for the Pennsylvania College of Technology (PCT) is divided into three main sections. Part I provides an overview of planning at PCT, including a definition of long-range planning, the college philosophy, mission, and vision statements, major institutional initiatives for 1991-92, and accreditation agency recommendations…

  1. Long Range Plan, 1997-2000.

    ERIC Educational Resources Information Center

    Pennsylvania Coll. of Technology, Williamsport. Office of Strategic Planning and Research.

    At Pennsylvania College of Technology (PCT), long range planning is used to define institutional philosophy and mission and determine strategies to make the best use of available resources and implement actions to fulfill institutional mission. This document presents PCT's long-range plan for 1997-2000 in three parts. The first part describes long…

  2. Assessment of a long-range corrected hybrid functional

    SciTech Connect

    Vydrov, Oleg A.; Scuseria, Gustavo E.

    2006-12-21

    Common approximate exchange-correlation functionals suffer from self-interaction error, and as a result, their corresponding potentials have incorrect asymptotic behavior. The exact asymptote can be imposed by introducing range separation into the exchange component and replacing the long-range portion of the approximate exchange by the Hartree-Fock counterpart. The authors show that this long-range correction works particularly well in combination with the short-range variant of the Perdew-Burke-Ernzerhof (PBE) exchange functional. This long-range-corrected hybrid, here denoted LC-{omega}PBE, is remarkably accurate for a broad range of molecular properties, such as thermochemistry, barrier heights of chemical reactions, bond lengths, and most notably, description of processes involving long-range charge transfer.

  3. Chemical Abundance Gradients in the Star-forming Ring Galaxies

    NASA Astrophysics Data System (ADS)

    Korchagin, Vladimir; Vorobyov, Eduard; Mayya, Y. D.

    1999-09-01

    Ring waves of star formation, propagating outward in the galactic disks, leave chemical abundance gradients in their wakes. We show that the relative [Fe/O] abundance gradients in ring galaxies can be used as a tool for determining the role of the SN Ia explosions in their chemical enrichment. We consider two mechanisms--a self-induced wave and a density wave--that can create outwardly propagating star-forming rings in a purely gaseous disk and demonstrate that the radial distribution of the relative [Fe/O] abundance gradients depends neither on the particular mechanism of the wave formation anor on the parameters of the star-forming process. We show that the [Fe/O] profile is determined by the velocity of the wave, the initial mass function, and the initial chemical composition of the star-forming gas. If the role of SN Ia explosions is negligible in the chemical enrichment, the ratio [Fe/O] remains constant throughout the galactic disk with a steep gradient at the wave front. If SN Ia stars are important in the production of cosmic iron, the [Fe/O] ratio has a gradient in the wake of the star-forming wave with the value depending on the frequency of SN Ia explosions.

  4. Topological defects with long-range interactions

    NASA Astrophysics Data System (ADS)

    Mello, B. A.; González, J. A.; Guerrero, L. E.; López-Atencio, E.

    1998-07-01

    We investigate a modified sine-Gordon equation which possesses soliton solutions with long-range interaction. We introduce a generalized version of the Ginzburg-Landau equation which supports long-range topological defects in D = 1 and D > 1. The interaction force between the defects decays so slowly that it is possible to enter the non-extensivity regime. These results can be applied to non-equilibrium systems, pattern formation and growth models.

  5. Passive long range acousto-optic sensor

    NASA Astrophysics Data System (ADS)

    Slater, Dan

    2006-08-01

    Alexander Graham Bell's photophone of 1880 was a simple free space optical communication device that used the sun to illuminate a reflective acoustic diaphragm. A selenium photocell located 213 m (700 ft) away converted the acoustically modulated light beam back into sound. A variation of the photophone is presented here that uses naturally formed free space acousto-optic communications links to provide passive multichannel long range acoustic sensing. This system, called RAS (remote acoustic sensor), functions as a long range microphone with a demonstrated range in excess of 40 km (25 miles).

  6. Photon assisted long-range tunneling

    SciTech Connect

    Gallego-Marcos, Fernando; Sánchez, Rafael; Platero, Gloria

    2015-03-21

    We analyze long-range transport through an ac driven triple quantum dot with a single electron. Resonant transitions between separated and detuned dots are mediated by the exchange of n photons with the time-dependent field. An effective model is proposed in terms of second order (cotunneling) processes which dominate the long-range transport between the edge quantum dots. The ac field renormalizes the inter dot hopping, modifying the level hybridization. It results in a non-trivial behavior of the current with the frequency and amplitude of the external ac field.

  7. Photon assisted long-range tunneling

    NASA Astrophysics Data System (ADS)

    Gallego-Marcos, Fernando; Sánchez, Rafael; Platero, Gloria

    2015-03-01

    We analyze long-range transport through an ac driven triple quantum dot with a single electron. Resonant transitions between separated and detuned dots are mediated by the exchange of n photons with the time-dependent field. An effective model is proposed in terms of second order (cotunneling) processes which dominate the long-range transport between the edge quantum dots. The ac field renormalizes the inter dot hopping, modifying the level hybridization. It results in a non-trivial behavior of the current with the frequency and amplitude of the external ac field.

  8. Swarming behavior of gradient-responsive colloids with chemical signaling.

    PubMed

    Grančič, Peter; Štěpánek, František

    2013-07-01

    The article describes swarm dynamics of a system composed of colloidal particles that release chemical signals to navigate their peers toward the location of a static point target in two dimensions. The time evolution of the system is calculated by employing a combination of Brownian dynamics method for the particle motion and the diffusion problem for spatial transport of chemical signals, coupled via diffusiophoresis. A parametric study is performed with respect to crucial model parameters that control the diffusivity of the particles and the chemical signals. This includes the initial concentration of chemical signals carried by the particles, the chemical signal release rate, the diffusion coefficient of the chemical signals, the diffusiophoretic mobility of the particles, and the topological complexity of the surrounding environment. Three measures are used to evaluate the performance of the system: the target arrival time, the target localization success rate, and the target residence time. Since the particle motion is determined by the local concentration gradients of the chemical signals, parameter values that result in steep and durable concentration gradients lead to the best performance in navigating a swarm of colloidal particles toward the target. However, the results show that a trade-off principle exists, as it is not always possible to improve all the performance criteria simultaneously. For a topologically complex environment, the particles often become trapped in areas where the chemical signals accumulate, leading to a significant decrease in the localization success rate. PMID:23734621

  9. College and University Long-Range Planning.

    ERIC Educational Resources Information Center

    Haas, Raymond M.

    The system for long-range planning at West Virginia University is described, with emphasis on how it relates to short-range planning and how it is carried out operationally. Planning tools used include (1) an inventory of the past and present of the institution, (2) a statement of the division of labor within the institution and the objectives of…

  10. Long-Range Plan, 1978-83.

    ERIC Educational Resources Information Center

    Jonas, Stephen

    This nine-part, long-range plan discusses the internal and external factors that will affect Lorain County Community College's (LCCC's) development from 1978 to 1983 and presents a forecast of LCCC's future needs. Part I traces the history of LCCC, provides a conceptual framework for college planning, and discusses the plan development process…

  11. Discussion of long-range weather prediction

    SciTech Connect

    Canavan, G.H.

    1998-09-10

    A group of scientists at Los Alamos have held a series of discussions of the issues in and prospects for improvements in Long-range Weather Predictions Enabled by Proving of the Atmosphere at High Space-Time Resolution. The group contained the requisite skills for a full evaluation, although this report presents only an informal discussion of the main technical issues. The group discussed all aspects of the proposal, which are grouped below into the headings: (1) predictability; (2) sensors and satellites, (3) DIAL and atmospheric sensing; (4) localized transponders; and (5) summary and integration. Briefly, the group agreed that the relative paucity of observations of the state of the atmosphere severely inhibits the accuracy of weather forecasts, and any program that leads to a more dense and uniform observational network is welcome. As shown in Long-range Weather more dense and uniform observational network is welcome. As shown in Long-range Weather Predictions, the pay-back of accurate long-range forecasts should more than justify the expenditure associated with improved observations and forecast models required. The essential step is to show that the needed technologies are available for field test and space qualification.

  12. Look Ahead: Long-Range Learning Plans

    ERIC Educational Resources Information Center

    Weinstein, Margery

    2010-01-01

    Faced with an unsteady economy and fluctuating learning needs, planning a learning strategy designed to last longer than the next six months can be a tall order. But a long-range learning plan can provide a road map for success. In this article, four companies (KPMG LLP, CarMax, DPR Construction, and EMC Corp.) describe their learning plans, and…

  13. Resources and Long-Range Forecasts

    ERIC Educational Resources Information Center

    Smith, Waldo E.

    1973-01-01

    The author argues that forecasts of quick depletion of resources in the environment as a result of overpopulation and increased usage may not be free from error. Ignorance still exists in understanding the recovery mechanisms of nature. Long-range forecasts are likely to be wrong in such situations. (PS)

  14. Chemical gradients and progressive veining in a partly serpentinized harzburgite

    NASA Astrophysics Data System (ADS)

    Schwarzenbach, Esther; Caddick, Mark; Beard, James; Bodnar, Robert

    2016-04-01

    Serpentinized ultramafic rocks constitute a major part of the oceanic lithosphere. They form when water interacts with olivine and pyroxene to produce a dense network of veins comprised of secondary minerals: Serpentine + brucite ± magnetite veins occur in olivine, Al-rich serpentine + talc veins occur in orthopyroxene, and Al-rich serpentine ± talc ± brucite veins occur at the boundary between orthopyroxene and olivine. Here, we present a detailed study on a harzburgite from the Santa Elena Ophiolite in Costa Rica that is ~30% serpentinized in order to provide new constraints on the effect of variable water (H2O) and silica (SiO2) activities on vein formation in peridotites. The studied sample records 1) mineralogical and chemical zonations in olivine-hosted veins that show a distinct pattern with increasing width of the veins (consumption of olivine), 2) varying brucite composition depending on whether or not it is associated with magnetite, and 3) chemical gradients in Si, Al, Cr, and Ca at the boundary between orthopyroxene- and olivine-hosted veins. These observed chemical variations suggest fluid mediated mass transport within and between orthopyroxene- and olivine-hosted veins. We use thermodynamic models to show that an increase in vein width and progressive evolution of olivine-hosted veins is accompanied by an increase in water-rock ratios. This is associated with the development of chemical gradients (e.g. gradients in water and silica activity) between the fluid-rich center of serpentine veins and the olivine grain boundaries as typically expressed by the abundance of brucite in the vein center and a dominance of serpentine at the boundary with olivine. The increase in water-rock ratios within the vein center also leads to the formation of magnetite from Fe-rich brucite ± Fe-rich serpentine. Mass transfer between vein core and vein rim may exist on the submicron-scale along grain boundaries of the finely intergrown serpentine-brucite mixture. We

  15. Critical Hamiltonians with long range hopping

    NASA Astrophysics Data System (ADS)

    Levitov, L. S.

    1999-11-01

    Critical states are studied by a real space RG in the problem with strong diagonal disorder and long range power law hopping. The RG ow of the distribution of coupling parameters is characterized by a family of non-trivial fix points. We consider the RG flow of the distribution of participation ratios of eigenstates. Scaling of participation ratios is sensitive to the nature of the RG fix point. For some fix points, scaling of participation ratios is characterized by a distribution of exponents, rather than by a single exponent.The RG method can be generalized to treat certain fermionic Hamiltonians with disorder and long range hopping. We derive the RG for a model of interacting two-level systems. Besides couplings, in this problem the RG includes the density of states. The density of states is renormalized so that it develops a singularity near zero energy.

  16. Long-range correlations in nucleotide sequences

    NASA Astrophysics Data System (ADS)

    Peng, C.-K.; Buldyrev, S. V.; Goldberger, A. L.; Havlin, S.; Sciortino, F.; Simons, M.; Stanley, H. E.

    1992-03-01

    DNA SEQUENCES have been analysed using models, such as an it-step Markov chain, that incorporate the possibility of short-range nucleotide correlations1. We propose here a method for studying the stochastic properties of nucleotide sequences by constructing a 1:1 map of the nucleotide sequence onto a walk, which we term a 'DNA walk'. We then use the mapping to provide a quantitative measure of the correlation between nucleotides over long distances along the DNA chain. Thus we uncover in the nucleotide sequence a remarkably long-range power law correlation that implies a new scale-invariant property of DNA. We find such long-range correlations in intron-containing genes and in nontranscribed regulatory DNA sequences, but not in complementary DNA sequences or intron-less genes.

  17. Gemini: A long-range cargo transport

    NASA Technical Reports Server (NTRS)

    1994-01-01

    The proposed Gemini, a long-range cargo transport, is designed as a high capacity, dedicated cargo transporter of 8'x8'x20' inter-modal containers, and long-range design. These requirements will result in a design that is larger than any existing aircraft. Due to the size, a conventional configuration would result in an aircraft unable to operate economically at existing airports. It is necessary to design for a minimum possible empty weight, wingspan, and landing gear track. After considering both a single fuselage biplane and a double fuselage biplane configuration, the design team choose the double fuselage biplane configuration. Both of these configuration choices result in a reduced wing root bending moment and subsequently in substantial savings in the wing weight. An overall decrease in the weight of the airplane, its systems, and fuel will be a direct result of the wing weight savings.

  18. Holographic thermalization with initial long range correlation

    NASA Astrophysics Data System (ADS)

    Lin, Shu

    2016-01-01

    We studied the evolution of the Wightman correlator in a thermalizing state modeled by AdS3 -Vaidya background. We gave a prescription for calculating the Wightman correlator in coordinate space without using any approximation. For equal-time correlator ⟨ O (v ,x )O (v ,0 )⟩ , we obtained an enhancement factor v2 due to long range correlation present in the initial state. This was missed by previous studies based on geodesic approximation. We found that the long range correlation in initial state does not lead to significant modification to thermalization time as compared to known results with generic initial state. We also studied the spatially integrated Wightman correlator and showed evidence on the distinction between long distance and small momentum physics for an out-of-equilibrium state. We also calculated the radiation spectrum of particles weakly coupled to O and found that lower frequency mode approaches thermal spectrum faster than high frequency mode.

  19. Holographic thermalization with initial long range correlation

    DOE PAGESBeta

    Lin, Shu

    2016-01-19

    Here, we studied the evolution of the Wightman correlator in a thermalizing state modeled by AdS3-Vaidya background. A prescription was given for calculating the Wightman correlator in coordinate space without using any approximation. For equal-time correlator , we obtained an enhancement factor v2 due to long range correlation present in the initial state. This was missed by previous studies based on geodesic approximation. Moreover, we found that the long range correlation in initial state does not lead to significant modification to thermalization time as compared to known results with generic initial state. We also studied the spatially integrated Wightman correlatormore » and showed evidence on the distinction between long distance and small momentum physics for an out-of-equilibrium state. We also calculated the radiation spectrum of particles weakly coupled to O and found that lower frequency mode approaches thermal spectrum faster than high frequency mode.« less

  20. Long-range charge transfer in biopolymers

    NASA Astrophysics Data System (ADS)

    Astakhova, T. Yu; Likhachev, V. N.; Vinogradov, G. A.

    2012-11-01

    The results of theoretical and experimental studies on the charge transfer in biopolymers, namely, DNA and peptides, are presented. Conditions that ensure the efficient long-range charge transport (by several tens of nanometres) are considered. The known theoretical models of charge transfer mechanisms are discussed and the scopes of their application are analyzed. Attention is focused on the charge transport by the polaron mechanism. The bibliography includes 262 references.

  1. Long-range hybrid wedge plasmonic waveguide.

    PubMed

    Zhang, Zhonglai; Wang, Jian

    2014-01-01

    We design a novel long-range hybrid wedge plasmonic (LRHWP) waveguide composed of two identical dielectric nanowires symmetrically placed on two opposed wedges of a diamond shaped metal wire. With strong coupling between the dielectric nanowire mode and long-range surface plasmon polariton (SPP) mode, both deep subwavelength mode confinement and low propagation loss are achieved. On one hand, when compared to the previous long-range hybrid SPP waveguide, LRHWP waveguide can achieve smaller mode size with similar propagation length; on the other hand, when compared to the previous hybrid wedge SPP waveguide, LRHWP waveguide can provide an order of magnitude longer propagation length with similar level of mode confinement. The designed LRHWP waveguide also features an overall advantage of one-order improvement of Figure of Merit. We further evaluate in detail the impacts of possible practical fabrication imperfections on the mode properties. The obtained results of mode properties show that the proposed LRHWP waveguide with an optimized wedge tip angle of 140 degree is fairly tolerant to practical fabrication errors in geometry parameters such as misalignment in the horizontal direction, asymmetry in the vertical direction, variation of wedge tip angle, tilt or rotation of metal wire, and variation of wedge tip curvature radius. PMID:25362900

  2. Long-range hybrid wedge plasmonic waveguide

    PubMed Central

    Zhang, Zhonglai; Wang, Jian

    2014-01-01

    We design a novel long-range hybrid wedge plasmonic (LRHWP) waveguide composed of two identical dielectric nanowires symmetrically placed on two opposed wedges of a diamond shaped metal wire. With strong coupling between the dielectric nanowire mode and long-range surface plasmon polariton (SPP) mode, both deep subwavelength mode confinement and low propagation loss are achieved. On one hand, when compared to the previous long-range hybrid SPP waveguide, LRHWP waveguide can achieve smaller mode size with similar propagation length; on the other hand, when compared to the previous hybrid wedge SPP waveguide, LRHWP waveguide can provide an order of magnitude longer propagation length with similar level of mode confinement. The designed LRHWP waveguide also features an overall advantage of one-order improvement of Figure of Merit. We further evaluate in detail the impacts of possible practical fabrication imperfections on the mode properties. The obtained results of mode properties show that the proposed LRHWP waveguide with an optimized wedge tip angle of 140 degree is fairly tolerant to practical fabrication errors in geometry parameters such as misalignment in the horizontal direction, asymmetry in the vertical direction, variation of wedge tip angle, tilt or rotation of metal wire, and variation of wedge tip curvature radius. PMID:25362900

  3. Fabricating nanoscale chemical gradients with ThermoChemical NanoLithography.

    PubMed

    Carroll, Keith M; Giordano, Anthony J; Wang, Debin; Kodali, Vamsi K; Scrimgeour, Jan; King, William P; Marder, Seth R; Riedo, Elisa; Curtis, Jennifer E

    2013-07-01

    Production of chemical concentration gradients on the submicrometer scale remains a formidable challenge, despite the broad range of potential applications and their ubiquity throughout nature. We present a strategy to quantitatively prescribe spatial variations in functional group concentration using ThermoChemical NanoLithography (TCNL). The approach uses a heated cantilever to drive a localized nanoscale chemical reaction at an interface, where a reactant is transformed into a product. We show using friction force microscopy that localized gradients in the product concentration have a spatial resolution of ~20 nm where the entire concentration profile is confined to sub-180 nm. To gain quantitative control over the concentration, we introduce a chemical kinetics model of the thermally driven nanoreaction that shows excellent agreement with experiments. The comparison provides a calibration of the nonlinear dependence of product concentration versus temperature, which we use to design two-dimensional temperature maps encoding the prescription for linear and nonlinear gradients. The resultant chemical nanopatterns show high fidelity to the user-defined patterns, including the ability to realize complex chemical patterns with arbitrary variations in peak concentration with a spatial resolution of 180 nm or better. While this work focuses on producing chemical gradients of amine groups, other functionalities are a straightforward modification. We envision that using the basic scheme introduced here, quantitative TCNL will be capable of patterning gradients of other exploitable physical or chemical properties such as fluorescence in conjugated polymers and conductivity in graphene. The access to submicrometer chemical concentration and gradient patterning provides a new dimension of control for nanolithography. PMID:23751047

  4. Fan-less long range alpha detector

    DOEpatents

    MacArthur, Duncan W.; Bounds, John A.

    1994-01-01

    A fan-less long range alpha detector which operates by using an electrical field between a signal plane and the surface or substance to be monitored for air ions created by collisions with alpha radiation. Without a fan, the detector can operate without the possibility of spreading dust and potential contamination into the atmosphere. A guard plane between the signal plane and the electrically conductive enclosure and maintained at the same voltage as the signal plane, reduces leakage currents. The detector can easily monitor soil, or other solid or liquid surfaces.

  5. Fan-less long range alpha detector

    DOEpatents

    MacArthur, D.W.; Bounds, J.A.

    1994-05-10

    A fan-less long range alpha detector is disclosed which operates by using an electrical field between a signal plane and the surface or substance to be monitored for air ions created by collisions with alpha radiation. Without a fan, the detector can operate without the possibility of spreading dust and potential contamination into the atmosphere. A guard plane between the signal plane and the electrically conductive enclosure and maintained at the same voltage as the signal plane, reduces leakage currents. The detector can easily monitor soil, or other solid or liquid surfaces. 2 figures.

  6. A criterion autoscheduler for long range planning

    NASA Technical Reports Server (NTRS)

    Sponsler, Jeffrey L.

    1994-01-01

    A constraint-based scheduling system called SPIKE is used to create long-term schedules for the Hubble Space Telescope. A meta-level scheduler called the Criterion Autoscheduler for Long range planning (CASL) was created to guide SPIKE's schedule generation according to the agenda of the planning scientists. It is proposed that sufficient flexibility exists in a schedule to allow high level planning heuristics to be applied without adversely affected crucial constraints such as spacecraft efficiency. This hypothesis is supported by test data which is described.

  7. NASA's Long-range Technology Goals

    NASA Technical Reports Server (NTRS)

    1990-01-01

    This document is part of the Final Report performed under contract NASW-3864, titled "NASA's Long-Range Technology Goals". The objectives of the effort were: To identify technologies whose development falls within NASA's capability and purview, and which have high potential for leapfrog advances in the national industrial posture in the 2005-2010 era. To define which of these technologies can also enable quantum jumps in the national space program. To assess mechanisms of interaction between NASA and industry constituencies for realizing the leapfrog technologies. This Volume details the findings pertaining to the advanced space-enabling technologies.

  8. Long-range imaging ladar flight test

    NASA Astrophysics Data System (ADS)

    Brandt, James; Steiner, Todd D.; Mandeville, William J.; Dinndorf, Kenneth M.; Krasutsky, Nick J.; Minor, John L.

    1995-06-01

    Wright Laboratory and Loral Vought Systems (LVS) have been involved for the last nine years in the research and development of high power diode pumped solid state lasers for medium to long range laser radar (LADAR) seekers for tactical air-to-ground munitions. LVS provided the lead in three key LADAR programs at Wright Lab; the Submunition Guidance Program (Subguide), the Low Cost Anti-Armor Submunition Program (LOCAAS) and the Diode Laser and Detector Array Development Program (3-D). This paper discusses recent advances through the 3-D program that provide the opportunity to obtain three dimensional laser radar imagery in captive flight at a range of 5 km.

  9. Long-range interaction of anisotropic systems

    NASA Astrophysics Data System (ADS)

    Zhang, J.-Y.; Schwingenschlögl, U.

    2015-02-01

    The first-order electrostatic interaction energy between two far-apart anisotropic atoms depends not only on the distance between them but also on their relative orientation, according to Rayleigh-Schrödinger perturbation theory. Using the first-order interaction energy and the continuum model, we study the long-range interaction between a pair of parallel pristine graphene sheets at zero temperature. The asymptotic form of the obtained potential density, \\varepsilon(D) \\propto -D-3-O(D-4) , is consistent with the random phase approximation and Lifshitz theory. Accordingly, neglectance of the anisotropy, especially the nonzero first-order interaction energy, is the reason why the widely used Lennard-Jones potential approach and dispersion corrections in density functional theory give a wrong asymptotic form \\varepsilon(D) \\propto -D-4 .

  10. Long-range polarimetric imaging through fog.

    PubMed

    Fade, Julien; Panigrahi, Swapnesh; Carré, Anthony; Frein, Ludovic; Hamel, Cyril; Bretenaker, Fabien; Ramachandran, Hema; Alouini, Mehdi

    2014-06-20

    We report an experimental implementation of long-range polarimetric imaging through fog over kilometric distance in real field atmospheric conditions. An incoherent polarized light source settled on a telecommunication tower is imaged at a distance of 1.3 km with a snapshot polarimetric camera including a birefringent Wollaston prism, allowing simultaneous acquisition of two images along orthogonal polarization directions. From a large number of acquisitions datasets and under various environmental conditions (clear sky/fog/haze, day/night), we compare the efficiency of using polarized light for source contrast increase with different signal representations (intensity, polarimetric difference, polarimetric contrast, etc.). With the limited-dynamics detector used, a maximum fourfold increase in contrast was demonstrated under bright background illumination using polarimetric difference image. PMID:24979415

  11. Fe-based long range ordered alloys

    DOEpatents

    Liu, C.T.

    Malleable long range ordered alloys with high critical ordering temperatures exist in the V(Co,Fe)/sub 3/ and V(Co,Fe,Ni)/sub 3/ system. The composition comprising by weight 22 to 23% V, 35 to 50% Fe, 0 to 22% Co and 19 to 40% Ni with an electron density no greater than 8.00. Excellent high temperature properties occur in alloys having compositions comprising by weight 22 to 23% V, 35 to 45% Fe, 0 to 10% Co, 25 to 35% Ni; 22 to 23% V, 28 to 33% Ni and the remainder Fe; and 22 to 23% V, 19 to 22% Co and the remainder Fe. The alloys are fabricable by casting, deforming and annealing for sufficient time to provide ordered structure.

  12. Fe-based long range ordered alloys

    DOEpatents

    Liu, Chain T; Inouye, Henry; Schaffhauser, Anthony C.

    1980-01-01

    Malleable long range ordered alloys having high critical ordering temperatures exist in the V(Co,Fe).sub.3 and V(Co,Fe,Ni).sub.3 system having the composition comprising by weight 22-23% V, 35-50% Fe, 0-22% Co and 19-40% Ni with an electron density no greater than 8.00. Excellent high temperature properties occur in alloys having compositions comprising by weight 22-23% V, 35-45% Fe, 0-10% Co, 25-35% Ni; 22-23% V, 28-33% Ni and the remainder Fe; and 22-23% V, 19-22% Ni, 19-22% Co and the remainder Fe. The alloys are fabricable by casting, deforming and annealing for sufficient time to provide ordered structure.

  13. A Long-Range Video Observation Post

    SciTech Connect

    Arlowe, D.

    1995-07-01

    The Long Range Video Observation Post (LRVOP) Project is a cooperative effort between the US and a Middle Eastern country to develop an improved version of their current video observation post. This project is part of a larger effort to cooperatively develop anti-terrorist technology. This particular equipment is required to facilitate the recording and identification of humans at a range of 1000 meters in day-light and 500 meters at night. The project objective was to take advantage of recent advances in camera technology, recorders, and image processing to provide an significant increase in performance with only a minimum increase in size, weight, and cost. The goal of the project was to convert the users general needs and desires into specific requirements that could be bid on by several companies. This paper covers the specific performance requirements, generally describe the components that might be used, and concentrate on describing the more difficult issues and technical challenges.

  14. Long range inductive power transfer system

    NASA Astrophysics Data System (ADS)

    Lawson, James; Pinuela, Manuel; Yates, David C.; Lucyszyn, Stepan; Mitcheson, Paul D.

    2013-12-01

    We report upon a recently developed long range inductive power transfer system (IPT) designed to power remote sensors with mW level power consumption at distances up to 7 m. In this paper an inductive link is established between a large planar (1 × 1 m) transmit coil (Tx) and a small planer (170 × 170 mm) receiver coil (Rx), demonstrating the viability of highly asymmetrical coil configurations that real-world applications such as sensor networks impose. High Q factor Tx and Rx coils required for viable power transfer efficiencies over such distances are measured using a resonant method. The applicability of the Class-E amplifier in very low magnetic coupling scenarios and at the high frequencies of operation required for high Q operation is demonstrated by its usage as the Tx coil driver.

  15. Long range position and Orientation Tracking System

    SciTech Connect

    Armstrong, G.A.; Jansen, J.F.; Burks, B.L.

    1996-02-01

    The long range Position and Orientation Tracking System is an active triangulation-based system that is being developed to track a target to a resolution of 6.35 mm (0.25 in.) and 0.009{degrees}(32.4 arcseconds) over a range of 13.72 m (45 ft.). The system update rate is currently set at 20 Hz but can be increased to 100 Hz or more. The tracking is accomplished by sweeping two pairs of orthogonal line lasers over infrared (IR) sensors spaced with known geometry with respect to one another on the target (the target being a rigid body attached to either a remote vehicle or a remote manipulator arm). The synchronization and data acquisition electronics correlates the time that an IR sensor has been hit by one of the four lasers and the angle of the respective mirror at the time of the hit. This information is combined with the known geometry of the IR sensors on the target to determine position and orientation of the target. This method has the advantage of allowing the target to be momentarily lost due to occlusions and then reacquired without having to return the target to a known reference point. The system also contains a camera with operator controlled lighting in each pod that allows the target to be continuously viewed from either pod, assuming their are no occlusions.

  16. A long-range laser velocimeter

    NASA Technical Reports Server (NTRS)

    Reinath, Michael S.

    1991-01-01

    A long-range laser velocimeter (LV) developed for remote operation from within the flow fields of large wind tunnels is described. Emphasis is placed on recent improvements in optical hardware as well as recent additions to data acquisition and processing techniques. The method used for data reduction of photon resolved signals is outlined in detail, and measurement accuracy is discussed. To study the performance of the LV and verify the measurement accuracy, laboratory measurements were made in the flow field of a 10-cm-diameter, 30-m/s axisymetric jet. The measured velocity and turbulence intensity surveys are compared with measurements made with a hot-wire anemometer. Additionally, the LV was used during the flow calibration of the 80-ft x 120-ft wind tunnel to measure the test-section boundary-layer thickness at the maximum wind tunnel speed of 51.5 m/s. The requirements and techniques used to seed the flow are discussed, and boundary-layer surveys of mean velocity and turbulence intensity of the streamwise component and the component normal to the surface are presented. The streamwise component of mean velocity is compared with data obtained with a total pressure rake.

  17. Long range position and orientation tracking system

    SciTech Connect

    Armstrong, G.A.; Jansen, J.F.; Burks, B.L.; Bernacki, B.E.; Nypaver, D.J.

    1995-12-31

    The long range position and orientation tracking system (LRPOTS) will consist of two measurement pods, a VME-based computer system, and a detector array. The system is used to measure the position and orientation of a target that may be attached to a robotic arm, teleoperated manipulator, or autonomous vehicle. The pods have been designed to be mounted in the man-ways of the domes of the Fernald K-65 waste silos. Each pod has two laser scanner subsystems as well as lights and camera systems. One of the laser scanners will be oriented to scan in the pan direction, the other in the tilt direction. As the lasers scan across the detector array, the angles of incidence with each detector are recorded. Combining measurements from each of the four lasers yields sufficient data for a closed-form solution of the transform describing the location and orientation of the Content Mobilization System (CMS). Redundant detectors will be placed on the CMS to accommodate occlusions, to provide improved measurement accuracy, and to determine the CMS orientation.

  18. Long-range forecasting of intermittent streamflow

    NASA Astrophysics Data System (ADS)

    van Ogtrop, F. F.; Vervoort, R. W.; Heller, G. Z.; Stasinopoulos, D. M.; Rigby, R. A.

    2011-01-01

    Long-range forecasting of intermittent streamflow in semi-arid Australia poses a number of major challenges. One of the challenges relates to modelling zero, skewed, non-stationary, and non-linear data. To address this, a probabilistic statistical model to forecast streamflow 12 months ahead is applied to five semi-arid catchments in South Western Queensland. The model uses logistic regression through Generalised Additive Models for Location, Scale and Shape (GAMLSS) to determine the probability of flow occurring in any of the systems. We then use the same regression framework in combination with a right-skewed distribution, the Box-Cox t distribution, to model the intensity (depth) of the non-zero streamflows. Time, seasonality and climate indices, describing the Pacific and Indian Ocean sea surface temperatures, are tested as covariates in the GAMLSS model to make probabilistic 12-month forecasts of the occurrence and intensity of streamflow. The output reveals that in the study region the occurrence and variability of flow is driven by sea surface temperatures and therefore forecasts can be made with some skill.

  19. Long-range forecasting of intermittent streamflow

    NASA Astrophysics Data System (ADS)

    van Ogtrop, F. F.; Vervoort, R. W.; Heller, G. Z.; Stasinopoulos, D. M.; Rigby, R. A.

    2011-11-01

    Long-range forecasting of intermittent streamflow in semi-arid Australia poses a number of major challenges. One of the challenges relates to modelling zero, skewed, non-stationary, and non-linear data. To address this, a statistical model to forecast streamflow up to 12 months ahead is applied to five semi-arid catchments in South Western Queensland. The model uses logistic regression through Generalised Additive Models for Location, Scale and Shape (GAMLSS) to determine the probability of flow occurring in any of the systems. We then use the same regression framework in combination with a right-skewed distribution, the Box-Cox t distribution, to model the intensity (depth) of the non-zero streamflows. Time, seasonality and climate indices, describing the Pacific and Indian Ocean sea surface temperatures, are tested as covariates in the GAMLSS model to make probabilistic 6 and 12-month forecasts of the occurrence and intensity of streamflow. The output reveals that in the study region the occurrence and variability of flow is driven by sea surface temperatures and therefore forecasts can be made with some skill.

  20. Dynamic designing of microstructures by chemical gradient-mediated growth

    PubMed Central

    Shim, Tae Soup; Yang, Seung-Man; Kim, Shin-Hyun

    2015-01-01

    Shape is one of the most important determinants of the properties of microstructures. Despite of a recent progress on microfabrication techniques, production of three-dimensional micro-objects are yet to be fully achieved. Nature uses reaction–diffusion process during bottom-up self-assembly to create functional shapes and patterns with high complexity. Here we report a method to produce polymeric microstructures by using a dynamic reaction–diffusion process during top-down photolithography, providing unprecedented control over shape and composition. In radical polymerization, oxygen inhibits reaction, and therefore diffusion of oxygen significantly alters spatial distribution of growth rate. Therefore, growth pathways of the microstructures can be controlled by engineering a concentration gradient of oxygen. Moreover, stepwise control of chemical gradients enables the creation of highly complex microstructures. The ease of use and high controllability of this technology provide new opportunities for microfabrication and for fundamental studies on the relationships between shape and function for the materials. PMID:25766762

  1. Accurate ab initio energy gradients in chemical compound space.

    PubMed

    Anatole von Lilienfeld, O

    2009-10-28

    Analytical potential energy derivatives, based on the Hellmann-Feynman theorem, are presented for any pair of isoelectronic compounds. Since energies are not necessarily monotonic functions between compounds, these derivatives can fail to predict the right trends of the effect of alchemical mutation. However, quantitative estimates without additional self-consistency calculations can be made when the Hellmann-Feynman derivative is multiplied with a linearization coefficient that is obtained from a reference pair of compounds. These results suggest that accurate predictions can be made regarding any molecule's energetic properties as long as energies and gradients of three other molecules have been provided. The linearization coefficent can be interpreted as a quantitative measure of chemical similarity. Presented numerical evidence includes predictions of electronic eigenvalues of saturated and aromatic molecular hydrocarbons. PMID:19894922

  2. First hyperpolarizability of polymethineimine with long-range corrected functionals

    NASA Astrophysics Data System (ADS)

    Jacquemin, Denis; Perpète, Eric A.; Medved', Miroslav; Scalmani, Giovanni; Frisch, Michael J.; Kobayashi, Rika; Adamo, Carlo

    2007-05-01

    Using the long-range corrected (LC) density functional theory (DFT) scheme introduced by Iikura et al. [J. Chem. Phys. 115, 3540 (2001)] and the Coulomb-attenuating model (CAM-B3LYP) of Yanai et al. [Chem. Phys. Lett. 393, 51 (2004)], we have calculated the longitudinal dipole moments and static electronic first hyperpolarizabilities of increasingly long polymehtineimine oligomers. For comparison purposes Hartree-Fock (HF), Møller-Plesset perturbation theory (MP2), and conventional pure and hybrid functionals have been considered as well. HF, generalized gradient approximation (GGA), and conventional hybrids provide too large dipole moments for long oligomers, while LC-DFT allows to reduce the discrepancy with respect to MP2 by a factor of 3. For the first hyperpolarizability, the incorrect evolution with the chain length predicted by HF is strongly worsened by BLYP, Perdew-Burke-Ernzerhof (PBE), and also by B3LYP and PBE0. On the reverse, LC-BLYP and LC-PBE hyperpolarizabilities are correctly predicted to be positive (but for the two smallest chains). Indeed, for medium and long oligomers LC hyperpolarizabilities are slightly smaller than MP2 hyperpolarizabilities, as it should be. CAM-B3LYP also strongly improves the B3LYP results, though a bit less impressively for small chain lengths. The present study demonstrates the efficiency of long-range DFT, even in very pathological cases.

  3. Long-range dismount activity classification: LODAC

    NASA Astrophysics Data System (ADS)

    Garagic, Denis; Peskoe, Jacob; Liu, Fang; Cuevas, Manuel; Freeman, Andrew M.; Rhodes, Bradley J.

    2014-06-01

    Continuous classification of dismount types (including gender, age, ethnicity) and their activities (such as walking, running) evolving over space and time is challenging. Limited sensor resolution (often exacerbated as a function of platform standoff distance) and clutter from shadows in dense target environments, unfavorable environmental conditions, and the normal properties of real data all contribute to the challenge. The unique and innovative aspect of our approach is a synthesis of multimodal signal processing with incremental non-parametric, hierarchical Bayesian machine learning methods to create a new kind of target classification architecture. This architecture is designed from the ground up to optimally exploit correlations among the multiple sensing modalities (multimodal data fusion) and rapidly and continuously learns (online self-tuning) patterns of distinct classes of dismounts given little a priori information. This increases classification performance in the presence of challenges posed by anti-access/area denial (A2/AD) sensing. To fuse multimodal features, Long-range Dismount Activity Classification (LODAC) develops a novel statistical information theoretic approach for multimodal data fusion that jointly models multimodal data (i.e., a probabilistic model for cross-modal signal generation) and discovers the critical cross-modal correlations by identifying components (features) with maximal mutual information (MI) which is efficiently estimated using non-parametric entropy models. LODAC develops a generic probabilistic pattern learning and classification framework based on a new class of hierarchical Bayesian learning algorithms for efficiently discovering recurring patterns (classes of dismounts) in multiple simultaneous time series (sensor modalities) at multiple levels of feature granularity.

  4. Mechanism of long-range proton translocation along biological membranes

    PubMed Central

    Medvedev, Emile S.; Stuchebrukhov, Alexei A.

    2014-01-01

    Recent experiments suggest that protons can travel along biological membranes up to tens of micrometers, but the mechanism of transport is unknown. To explain such a long-range proton translocation we describe a model that takes into account the coupled bulk diffusion that accompanies the migration of protons on the surface. We show that protons diffusing at or near the surface before equilibrating with the bulk desorb and re-adsorb at the surface thousands of times, giving rise to a power-law desorption kinetics. As a result, the decay of the surface protons occurs very slowly, allowing for establishing local gradient and local exchange, as was envisioned in the early local models of biological energy transduction. PMID:23268201

  5. Long range migration of aphids into Sweden

    NASA Astrophysics Data System (ADS)

    Wiktelius, Staffan

    1984-09-01

    A five year study of migration of aphids across the southern part of the Baltic Sea is reported. The aphids were caught in a suction trap placed on a lighthouse 50 m from the shoreline. Large sections of the results are presented as case studies i.e. catches of aphids from periods containing at least three consecutive days with a southerly gradient wind. Some periods contained large and diverse catches and it is assumed that aphids regularly cross the Baltic Sea. The catches was largest on days when a cold front passed the trapping site within a period. More Myzus persicae were caught on days when the wind was southerly than on days with a northerly wind direction.

  6. Functional Sites Induce Long-Range Evolutionary Constraints in Enzymes

    PubMed Central

    Jack, Benjamin R.; Meyer, Austin G.; Echave, Julian; Wilke, Claus O.

    2016-01-01

    Functional residues in proteins tend to be highly conserved over evolutionary time. However, to what extent functional sites impose evolutionary constraints on nearby or even more distant residues is not known. Here, we report pervasive conservation gradients toward catalytic residues in a dataset of 524 distinct enzymes: evolutionary conservation decreases approximately linearly with increasing distance to the nearest catalytic residue in the protein structure. This trend encompasses, on average, 80% of the residues in any enzyme, and it is independent of known structural constraints on protein evolution such as residue packing or solvent accessibility. Further, the trend exists in both monomeric and multimeric enzymes and irrespective of enzyme size and/or location of the active site in the enzyme structure. By contrast, sites in protein–protein interfaces, unlike catalytic residues, are only weakly conserved and induce only minor rate gradients. In aggregate, these observations show that functional sites, and in particular catalytic residues, induce long-range evolutionary constraints in enzymes. PMID:27138088

  7. Nonlinear Behaviour in Long Range Integrable Models with Spin

    NASA Astrophysics Data System (ADS)

    Kulkarni, Manas; Franchini, Fabio; Abanov, Alexander

    2010-03-01

    We study nonlinear aspects of long range integrable models with spin by going beyond the Luttinger Liquid theory. We present here [1], the fully nonlinear dynamics of spin and charge in spin-Calogero model (sCM), an integrable 1D model of quantum spin-1/2 particles interacting through inverse square interaction and exchange. Hydrodynamic equations of motion are written for this model in the regime where gradient corrections to the exact theory may be neglected. In this approximation, variables separate in terms of dressed Fermi momenta of the model. Hydrodynamic equations reduce to a set of decoupled Riemann-Hopf equations for the dressed Fermi momenta. We study the dynamics of some non-equilibrium spin-charge configurations for times smaller than the time-scale of gradient catastrophe. We then show [2] how this field theory allows to calculate correlation functions that cannot be considered with conventional bosonization. We also highlight the connections between sCM, Haldane-Shastry model and λ=2 spin-less Calogero model. [1] M. Kulkarni, F. Franchini, A. G. Abanov, Phys. Rev. B 80, 165105 (2009) [2] F. Franchini, M. Kulkarni, Nucl. Phys. B, 825, 320 (2010)

  8. A natural orbital analysis of the long range behavior of chemical bonding and van der Waals interaction in singlet H2: the issue of zero natural orbital occupation numbers.

    PubMed

    Sheng, X W; Mentel, Ł M; Gritsenko, O V; Baerends, E J

    2013-04-28

    This paper gives a natural orbital (NO) based analysis of the van der Waals interaction in (singlet) H2 at long distance. The van der Waals interaction, even if not leading to a distinct van der Waals well, affects the shape of the interaction potential in the van der Waals distance range of 5-9 bohrs and can be clearly distinguished from chemical bonding effects. In the NO basis the van der Waals interaction can be quantitatively covered with, apart from the ground state configurations (1σ(g))(2) and (1σ(u))(2), just the 4 configurations (2σ(g))(2) and (2σ(u))(2), and (1π(u))(2) and (1π(g))(2). The physics of the dispersion interaction requires and explains the peculiar relatively large positive CI coefficients of the doubly excited electron configurations (2σ(u))(2) and (1π(g))(2) (the occupancy amplitudes of the 2σ(u) and 1π(gx, y) NOs) in the distance range 5-9 bohrs, which have been observed before by Cioslowski and Pernal [Chem. Phys. Lett. 430, 188 (2006)]. We show that such positive occupancy amplitudes do not necessarily lead to the existence of zero occupation numbers at some H-H distances. PMID:23635109

  9. Modeling of forced flow/thermal gradient chemical vapor infiltration

    SciTech Connect

    Starr, T.L.; Smith, A.W.

    1992-09-01

    The forced flow/thermal gradient chemical vapor infiltration process (FCVI) has proven to be a successful technique for fabrication of ceramic matrix composites. It is particularly attractive for thick components which cannot be fabricated using the conventional, isothermal method (ICVI). Although it offers processing times that are at least an order of magnitude shorter than ICVI, FCVI has not been used to fabricate parts of complex geometry and is perceived by some to be unsuitable for such components. The major concern Is that selection and control of the flow pattern and thermal profile for optimum infiltration can be a difficult and costly exercise. In order to reduce this effort, we are developing a computer model for FCVI that simulates the densification process for given component geometry, reactor configuration and operating parameters. Used by a process engineer, this model can dramatically reduce the experimental effort needed to obtain uniform densification. A one-dimensional process model, described in a previous interim report, has demonstrated good agreement with experimental results in predicting overall densification time and density uniformity during processing and the effect of various fiber architectures and operating parameters on these process issues. This model is fundamentally unsuitable for more complex geometries, however, and extension to two- and three-dimensions is necessary. This interim report summarizes our progress since the previous interim report toward development of a ``finite volume`` model for FCVI.

  10. Modeling of forced flow/thermal gradient chemical vapor infiltration

    SciTech Connect

    Starr, T.L.; Smith, A.W. )

    1992-09-01

    The forced flow/thermal gradient chemical vapor infiltration process (FCVI) has proven to be a successful technique for fabrication of ceramic matrix composites. It is particularly attractive for thick components which cannot be fabricated using the conventional, isothermal method (ICVI). Although it offers processing times that are at least an order of magnitude shorter than ICVI, FCVI has not been used to fabricate parts of complex geometry and is perceived by some to be unsuitable for such components. The major concern Is that selection and control of the flow pattern and thermal profile for optimum infiltration can be a difficult and costly exercise. In order to reduce this effort, we are developing a computer model for FCVI that simulates the densification process for given component geometry, reactor configuration and operating parameters. Used by a process engineer, this model can dramatically reduce the experimental effort needed to obtain uniform densification. A one-dimensional process model, described in a previous interim report, has demonstrated good agreement with experimental results in predicting overall densification time and density uniformity during processing and the effect of various fiber architectures and operating parameters on these process issues. This model is fundamentally unsuitable for more complex geometries, however, and extension to two- and three-dimensions is necessary. This interim report summarizes our progress since the previous interim report toward development of a finite volume'' model for FCVI.

  11. Emergent long-range magnetic ordering in manganite superlattices

    NASA Astrophysics Data System (ADS)

    Burganov, Bulat; Macke, Sebastian; Monkman, Eric; Adamo, Carolina; Shai, Daniel; Schlom, Darrell; Sawatzky, George; Shen, Kyle

    2015-03-01

    Complex oxides composed into atomically precise heterostructures host a plethora of new phenomena driven by interface effects, dimensionality, correlations and strain. An example is emergent ferromagnetism in the superlattices (SL) of LaMnO3/SrMnO3 and the dimensionality-driven metal insulator transition, still not well understood theoretically. We use soft x-ray scattering combined with SQUID magnetometry to determine the magnetic and orbital ordering in the (LaMnO3)2n /(SrMnO3)n SL for n =1,2,3,4. By composition this system is close to colossal-magnetoresistive La2/3Sr1/3MnO3, an FM metal below 400K. The system undergoes a metal-insulator transition with higher n and is believed to have a complex magnetic ordering. We observe an unexpected long-range order in the n =4 sample where the magnetic period is equal to two chemical periods. The observed half-order Bragg peaks show strong linear and no circular dichroism. The temperature and polarization dependence of reflectometry points towards alignment between A-type AFM orders in the neighboring LaMnO3 layers, which is very unusual and indicates a long range interaction acting across the thick SrMnO3 layers with nominally G-type spin configuration. We simulate the reflectometry data for several model spin configurations to further elucidate the nature of this ordering.

  12. DNA Structural Correlation in Short and Long Ranges.

    PubMed

    Gu, Chan; Zhang, Jun; Yang, Y Isaac; Chen, Xi; Ge, Hao; Sun, Yujie; Su, Xiaodong; Yang, Lijiang; Xie, Sunney; Gao, Yi Qin

    2015-11-01

    Recent single-molecule measurements have revealed the DNA allostery in protein/DNA binding. MD simulations showed that this allosteric effect is associated with the deformation properties of DNA. In this study, we used MD simulations to further investigate the mechanism of DNA structural correlation, its dependence on DNA sequence, and the chemical modification of the bases. Besides a random sequence, poly d(AT) and poly d(GC) are also used as simpler model systems, which show the different bending and twisting flexibilities. The base-stacking interactions and the methyl group on the 5-carbon site of thymine causes local structures and flexibility to be very different for the two model systems, which further lead to obviously different tendencies of the conformational deformations, including the long-range allosteric effects. PMID:26439165

  13. Theory of Long-Range Ultracold Atom-Molecule Photoassociation

    NASA Astrophysics Data System (ADS)

    Pérez-Ríos, Jesús; Lepers, Maxence; Dulieu, Olivier

    2015-08-01

    The creation of ultracold molecules is currently limited to diatomic species. In this Letter, we present a theoretical description of the photoassociation of ultracold atoms and molecules to create ultracold excited triatomic molecules, thus being a novel example of a light-assisted ultracold chemical reaction. The calculation of the photoassociation rate of an ultracold Cs2 molecule in its rovibrational ground state with an ultracold Cs atom at frequencies close to its resonant excitation is reported, based on the solution of the quantum dynamics involving the atom-molecule long-range interactions and assuming a model potential for the short-range physics. The rate for the formation of excited Cs3 molecules is predicted to be comparable with currently observed atom-atom photoassociation rates. We formulate an experimental proposal to observe this process relying on the available techniques of optical lattices and standard photoassociation spectroscopy.

  14. Fieldwide Chemical and Isotopic Gradients in Steam from the Geysers

    SciTech Connect

    Truesdell, A.H.; Haizlip, J.R.; Box, W.T. Jr.; D'Amore, F.

    1987-01-20

    Strong fieldwide gradients from southeast to northwest in gas/steam and {delta}{sup 18}O have been found in steam produced from wells at The Geysers. These gradients result from recharge from the southeast that has increased liquid saturation in the southern part of the reservoir and flushed gases and high {delta}{sup 18}O connate waters to the north and out of the system through surface vents. Variations in the steepness of the gradients are probably related to major venting in the Big Geysers area. Although lateral steam flow and condensation subsequent to flushing explain some local gradients in the southern area, these processes cannot explain the fieldwide variations. 1 tab., 24 refs., 5 figs.

  15. A spatiotemporally controllable chemical gradient generator via acoustically oscillating sharp-edge structures.

    PubMed

    Huang, Po-Hsun; Chan, Chung Yu; Li, Peng; Nama, Nitesh; Xie, Yuliang; Wei, Cheng-Hsin; Chen, Yuchao; Ahmed, Daniel; Huang, Tony Jun

    2015-11-01

    The ability to generate stable, spatiotemporally controllable concentration gradients is critical for resolving the dynamics of cellular response to a chemical microenvironment. Here we demonstrate an acoustofluidic gradient generator based on acoustically oscillating sharp-edge structures, which facilitates in a step-wise fashion the rapid mixing of fluids to generate tunable, dynamic chemical gradients. By controlling the driving voltage of a piezoelectric transducer, we demonstrated that the chemical gradient profiles can be conveniently altered (spatially controllable). By adjusting the actuation time of the piezoelectric transducer, moreover, we generated pulsatile chemical gradients (temporally controllable). With these two characteristics combined, we have developed a spatiotemporally controllable gradient generator. The applicability and biocompatibility of our acoustofluidic gradient generator are validated by demonstrating the migration of human dermal microvascular endothelial cells (HMVEC-d) in response to a generated vascular endothelial growth factor (VEGF) gradient, and by preserving the viability of HMVEC-d cells after long-term exposure to an acoustic field. Our device features advantages such as simple fabrication and operation, compact and biocompatible device, and generation of spatiotemporally tunable gradients. PMID:26338516

  16. Chemical Gradient-mediated Melting Curve Analysis for Genotyping of Single Nucleotide Polymorphisms

    PubMed Central

    Russom, Aman; Irimia, Daniel; Toner, Mehmet

    2009-01-01

    This report describes a microfluidic solid-phase Chemical Gradient-mediated Melting Curve Analysis (CGMCA) method for single nucleotide polymorphism (SNP) analysis. The method is based on allele-specific denaturation to discriminate mismatched (MM) from perfectly matched (PM) DNA duplexes upon exposure to linear chemical gradient. PM and MM DNA duplexes conjugated on beads are captured in a microfluidic gradient generator device designed with dams, keeping the beads trapped perpendicular to a gradient generating channel. Two denaturants, formamide and urea, were tested for their ability to destabilize the DNA duplex by competing with Watson-Crick pairing. Upon exposure to the chemical gradient, rapid denaturing profile was monitored in real time using fluorescence microscopy. The results show that the two duplexes exhibit different kinetics of denaturation profiles, enabling discrimination of MM from PM DNA duplexes to score SNP. PMID:19593749

  17. Long Range Plan, 1993-1996. Pennsylvania College of Technology.

    ERIC Educational Resources Information Center

    Slotnick, Sandra; And Others

    At Pennsylvania College of Technology (PCT), in Williamsport, long range planning is used to define institutional philosophy and mission and determine strategies to make the best use of available resources and implement actions to fulfill institutional mission. This document presents PCT's long-range plan for 1993-96 in three parts. Following an…

  18. 77 FR 13683 - Alaska Federal Lands Long Range Transportation Plan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-07

    ... Federal Highway Administration Alaska Federal Lands Long Range Transportation Plan AGENCY: Federal Highway..., announced the availability of the draft Alaska Federal Lands Long Range Transportation Plans (LRTP) for..., 2011, at 76 FR 77300, the FHWA published a notice in the Federal Register inviting comments to...

  19. 76 FR 77300 - Alaska Federal Lands Long Range Transportation Plan

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-12

    ... Federal Highway Administration Alaska Federal Lands Long Range Transportation Plan AGENCY: Federal Highway... Lands Long Range Transportation Plans (LRTP) for public review and comment. The draft plans outline a... United States Code Section 204 requires all Federal land management agencies to conduct long...

  20. Long-Range Planning and the Enrollment Decline.

    ERIC Educational Resources Information Center

    Fredrickson, John H.

    The current period of enrollment decline offers school districts an ideal opportunity for program and facility reevaluation and long-range planning. Any long-range plan should evaluate current programs in light of statutory and educational trends, estimate existing facilities' ability to accommodate change, determine the community's potential…

  1. A Model for Long Range Planning for Seminole Community College.

    ERIC Educational Resources Information Center

    Miner, Norris

    A model for long-range planning designed to maximize involvement of college personnel, to improve communication among various areas of the college, to provide a process for evaluation of long-range plans and the planning process, to adjust to changing conditions, to utilize data developed at a level useful for actual operations, and to have…

  2. Report of the Long-Range Planning Committee

    SciTech Connect

    Not Available

    1984-07-01

    This is the final report of the Long-Range Planning Committee of the Lawrence Livermore National Laboratory. It describes the make-up, purpose, working assumptions, and activities of the Committee and discusses the work done by the Committee on defense matters, energy, a number of additional topics, and future long-range planning activities.

  3. Quench dynamics in long-range interacting quantum systems

    NASA Astrophysics Data System (ADS)

    Gong, Zhexuan

    2016-05-01

    A distinctive feature of atomic, molecular, and optical systems is that interactions between particles are often long-ranged. Control techniques from quantum optics often allow one to tune the pattern of these long-range interactions, creating an entirely new degree of freedom, absent in typical condensed matter systems. These tunable long-range interactions can result in very different far-from-equilibrium dynamics compared to systems with only short-range interactions. In the first half of the talk, I will describe how very general types of long-range interactions can qualitatively change the entanglement and correlation growth shortly after a quantum quench. In the second half of the talk I will show that, at longer times, long-range interactions can lead to exotic quasi-stationary states and dynamical phase transitions. These theoretical ideas have been explored in recent trapped-ion experiments, and connections to these experiments will be emphasized in both parts of the talk.

  4. Truncated Long-Range Percolation on Oriented Graphs

    NASA Astrophysics Data System (ADS)

    van Enter, A. C. D.; de Lima, B. N. B.; Valesin, D.

    2016-07-01

    We consider different problems within the general theme of long-range percolation on oriented graphs. Our aim is to settle the so-called truncation question, described as follows. We are given probabilities that certain long-range oriented bonds are open; assuming that the sum of these probabilities is infinite, we ask if the probability of percolation is positive when we truncate the graph, disallowing bonds of range above a possibly large but finite threshold. We give some conditions in which the answer is affirmative. We also translate some of our results on oriented percolation to the context of a long-range contact process.

  5. Hyperfine-structure-induced purely long-range molecules.

    PubMed

    Enomoto, Katsunari; Kitagawa, Masaaki; Tojo, Satoshi; Takahashi, Yoshiro

    2008-03-28

    We have experimentally observed and theoretically identified a novel class of purely long-range molecules. This novel purely long-range state is formed due to a very weak hyperfine interaction that is usually treated only as a small perturbation in molecular spectra. Photoassociation spectroscopy of ultracold ytterbium (171Yb) atoms with the 1S0-3P1 intercombination transition presents clear identification of molecular states and the shallowest molecular potential depth of about 750 MHz among the purely long-range molecules ever observed. PMID:18517858

  6. Orthogonal, three-component, alkanethiol-based surface-chemical gradients on gold.

    PubMed

    Beurer, Eva; Venkataraman, Nagaiyanallur V; Rossi, Antonella; Bachmann, Florian; Engeli, Roman; Spencer, Nicholas D

    2010-06-01

    An orthogonal surface-chemical gradient composed of self-assembled monolayers on gold has been prepared by successive, controlled immersions in orthogonal directions into dilute solutions of dodecanethiol and perfluorododecanethiol. The resulting two-component orthogonal gradient in surface coverage was backfilled with 11-mercaptoundecanol, leading to a two-directional, three-component surface-chemical gradient. Water and hexadecane show distinctly different wetting behaviors on the gradient surface because of the differences in the hydrophobic and oleophobic natures of the three different constituents. These results are correlated with the chemical composition maps of the surface obtained by X-ray photoelectron spectroscopy. The homogeneity and the ordering of the self-assembled monolayer were investigated by dynamic water contact angle measurements and polarization-modulation infrared reflection-absorption spectroscopy. PMID:20166727

  7. Long-range eye tracking: A feasibility study

    SciTech Connect

    Jayaweera, S.K.; Lu, Shin-yee

    1994-08-24

    The design considerations for a long-range Purkinje effects based video tracking system using current technology is presented. Past work, current experiments, and future directions are thoroughly discussed, with an emphasis on digital signal processing techniques and obstacles. It has been determined that while a robust, efficient, long-range, and non-invasive eye tracking system will be difficult to develop, such as a project is indeed feasible.

  8. Communication: Control of chemical reactions using electric field gradients

    NASA Astrophysics Data System (ADS)

    Deshmukh, Shivaraj D.; Tsori, Yoav

    2016-05-01

    We examine theoretically a new idea for spatial and temporal control of chemical reactions. When chemical reactions take place in a mixture of solvents, an external electric field can alter the local mixture composition, thereby accelerating or decelerating the rate of reaction. The spatial distribution of electric field strength can be non-trivial and depends on the arrangement of the electrodes producing it. In the absence of electric field, the mixture is homogeneous and the reaction takes place uniformly in the reactor volume. When an electric field is applied, the solvents separate and the reactants are concentrated in the same phase or separate to different phases, depending on their relative miscibility in the solvents, and this can have a large effect on the kinetics of the reaction. This method could provide an alternative way to control runaway reactions and to increase the reaction rate without using catalysts.

  9. Communication: Control of chemical reactions using electric field gradients.

    PubMed

    Deshmukh, Shivaraj D; Tsori, Yoav

    2016-05-21

    We examine theoretically a new idea for spatial and temporal control of chemical reactions. When chemical reactions take place in a mixture of solvents, an external electric field can alter the local mixture composition, thereby accelerating or decelerating the rate of reaction. The spatial distribution of electric field strength can be non-trivial and depends on the arrangement of the electrodes producing it. In the absence of electric field, the mixture is homogeneous and the reaction takes place uniformly in the reactor volume. When an electric field is applied, the solvents separate and the reactants are concentrated in the same phase or separate to different phases, depending on their relative miscibility in the solvents, and this can have a large effect on the kinetics of the reaction. This method could provide an alternative way to control runaway reactions and to increase the reaction rate without using catalysts. PMID:27208928

  10. Biofilm responses to smooth flow fields and chemical gradients in novel microfluidic flow cells.

    PubMed

    Song, Jisun L; Au, Kelly H; Huynh, Kimberly T; Packman, Aaron I

    2014-03-01

    We present two novel microfluidic flow cells developed to provide reliable control of flow distributions and chemical gradients in biofilm studies. We developed a single-inlet microfluidic flow cell to support biofilm growth under a uniform velocity field, and a double-inlet flow cell to provide a very smooth transverse concentration gradient. Both flow cells consist of a layer of polydimethylsiloxane (PDMS) bonded to glass cover slips and were fabricated using the replica molding technique. We demonstrate the capabilities of the flow cells by quantifying flow patterns before and after growth of Pseudomonas aeruginosa biofilms through particle imaging velocimetry, and by evaluating concentration gradients within the double-inlet microfluidic flow cell. Biofilm growth substantially increased flow complexity by diverting flow around biomass, creating high- and low-velocity regions and surface friction. Under a glucose gradient in the double-inlet flow cell, P. aeruginosa biofilms grew in proportion to the local glucose concentration, producing distinct spatial patterns in biofilm biomass relative to the imposed glucose gradient. When biofilms were subjected to a ciprofloxacin gradient, spatial patterns of fractions of dead cells were also in proportion to the local antibiotic concentration. These results demonstrate that the microfluidic flow cells are suitable for quantifying flow complexities resulting from flow-biofilm interactions and investigating spatial patterns of biofilm growth under chemical gradients. These novel microfluidic flow cells will facilitate biofilm research that requires flow control and in situ imaging, particularly investigations of biofilm-environment interactions. PMID:24038055

  11. Biofilm responses to smooth flow fields and chemical gradients in novel microfluidic flow cells

    PubMed Central

    Song, Jisun L.; Au, Kelly H.; Huynh, Kimberly T.

    2013-01-01

    We present two novel microfluidic flow cells developed to provide reliable control of flow distributions and chemical gradients in biofilm studies. We developed a single-inlet microfluidic flow cell to support biofilm growth under a uniform velocity field, and a double-inlet flow cell to provide a very smooth transverse concentration gradient. Both flow cells consist of a layer of polydimethylsiloxane (PDMS) bonded to glass cover slips and were fabricated using the replica molding technique. We demonstrate the capabilities of the flow cells by quantifying flow patterns before and after growth of Pseudomonas aeruginosa biofilms through particle imaging velocimetry, and by evaluating concentration gradients within the double-inlet microfluidic flow cell. Biofilm growth substantially increased flow complexity by diverting flow around biomass, creating high- and low-velocity regions and surface friction. Under a glucose gradient in the double-inlet flow cell, P. aeruginosa biofilms grew in proportion to the local glucose concentration, producing distinct spatial patterns in biofilm biomass relative to the imposed glucose gradient. When biofilms were subjected to a ciprofloxacin gradient, spatial patterns of fractions of dead cells were also in proportion to the local antibiotic concentration. These results demonstrate that the microfluidic flow cells are suitable for quantifying flow complexities resulting from flow-biofilm interactions and investigating spatial patterns of biofilm growth under chemical gradients. These novel microfluidic flow cells will facilitate biofilm research that requires flow control and in situ imaging, particularly investigations of biofilm-environment interactions. PMID:24038055

  12. Application of advanced technology to future long-range aircraft

    NASA Technical Reports Server (NTRS)

    Schrader, O. E.

    1976-01-01

    The objective of this paper is to provide an overview assessment of three separate programs at Langley Research Center that have incorporated advanced technology into the design of long-range passenger and cargo aircraft. The first technology centers around the use of an span-loaded cargo aircraft with the payload distributed along the wing. This concept has the potential for reduced structural weights. The second technology is the application of laminar flow control (LFC) to the aircraft to reduce the aerodynamic drag. The use of LFC can reduce the fuel requirements during long-range cruise. The last program evaluates the production of alternate aircraft fuels from coal and the use of liquid hydrogen as an aircraft fuel. Coal-derived hydrogen as an aircraft fuel offers both the prospect for reduced dependence on petroleum fuels and improved performance for long-range aircraft.

  13. Fourth International Symposium on Long-Range Sound Propagation

    NASA Technical Reports Server (NTRS)

    Willshire, William L., Jr. (Compiler)

    1990-01-01

    Long range sound propagation is an aspect of many acoustical problems ranging from en route aircraft noise to the acoustic detection of aircraft. Over the past decade, the University of Mississippi and the Open University of England, together with a third institution, have held a symposium approx. every 2 years so that experts in the field of long range propagation could exchange information on current research, identify areas needing additional work, and coordinate activities as much as possible. The Fourth International Symposium on Long Range Sound Propagation was jointly sponsored by the University of Mississippi, the Open University of England, and NASA. Papers were given in the following areas: ground effects on propagation; infrasound propagation; and meteorological effects on sound propagation. A compilation of the presentations made at the symposium is presented along with a list of attendees, and the agenda.

  14. Long-Range Interactions Restrict Water Transport in Pyrophyllite Interlayers.

    PubMed

    Zarzycki, Piotr; Gilbert, Benjamin

    2016-01-01

    Water diffusion within smectite clay interlayers is reduced by confinement and hence is highly determined by the interlayer spacings that are adopted during swelling. However, a molecular understanding of the short- and long-range forces governing interlayer water structure and dynamics is lacking. Using molecular dynamics simulations of water intercalated between pyrophyllite (smectite prototype) layers we provide a detailed picture of the variation of interlayered water mobility accompanying smectite expansion. Subtle changes in hydrogen bond network structure cause significant changes in water mobility that is greater for stable hydration states and reduced for intermediate separations. By studying pyrophyllite with and without external water we reveal that long-range electrostatic forces apply a restraining effect upon interlayer water mobility. Our findings are relevant for broad range of confining nanostructures with walls thin enough to permit long-range interactions that could affect the mobility of confined solvent molecules and solute species. PMID:27118164

  15. Entanglement area law for long-range interacting systems

    NASA Astrophysics Data System (ADS)

    Gong, Zhexuan; Foss-Feig, Michael; Brandao, Fernando G. S. L.; Gorshkov, Alexey V.

    Area laws for entanglement provide crucial insight into the low-energy behavior of many-body systems and are intimately connected to the efficiency of classical computational methods. For 1D systems, an area law was rigorously proven for ground states of gapped Hamiltonians with local interactions and for states with exponentially decaying correlations. In the presence of long-range interactions, the proof of an area law for gapped ground states becomes much more challenging because long-range interactions can change the effective dimensionality of the system and introduce correlations decaying slower than an exponential. Based on recent theoretical advances that reveal strong remnants of locality in quenched systems with power-law decaying interactions, we prove an area law for a large class of gapped Hamiltonians with long-range interactions. As an intermediate step, we prove tight bounds on the decay of ground-state correlations.

  16. Long-Range Interactions Restrict Water Transport in Pyrophyllite Interlayers

    PubMed Central

    Zarzycki, Piotr; Gilbert, Benjamin

    2016-01-01

    Water diffusion within smectite clay interlayers is reduced by confinement and hence is highly determined by the interlayer spacings that are adopted during swelling. However, a molecular understanding of the short- and long-range forces governing interlayer water structure and dynamics is lacking. Using molecular dynamics simulations of water intercalated between pyrophyllite (smectite prototype) layers we provide a detailed picture of the variation of interlayered water mobility accompanying smectite expansion. Subtle changes in hydrogen bond network structure cause significant changes in water mobility that is greater for stable hydration states and reduced for intermediate separations. By studying pyrophyllite with and without external water we reveal that long-range electrostatic forces apply a restraining effect upon interlayer water mobility. Our findings are relevant for broad range of confining nanostructures with walls thin enough to permit long-range interactions that could affect the mobility of confined solvent molecules and solute species. PMID:27118164

  17. Long-range interactions in lattice field theory

    SciTech Connect

    Rabin, J.M.

    1981-06-01

    Lattice quantum field theories containing fermions can be formulated in a chirally invariant way provided long-range interactions are introduced. It is established that in weak-coupling perturbation theory such a lattice theory is renormalizable when the corresponding continuum theory is, and that the continuum theory is indeed recovered in the perturbative continuum limit. In the strong-coupling limit of these theories one is led to study an effective Hamiltonian describing a Heisenberg antiferromagnet with long-range interactions. Block-spin renormalization group methods are used to find a critical rate of falloff of the interactions, approximately as inverse distance squared, which separates a nearest-neighbor-antiferromagnetic phase from a phase displaying identifiable long-range effects. A duality-type symmetry is present in some block-spin calculations.

  18. Long-range oil and gas forecasting methodologies: literature survey

    SciTech Connect

    Cherniavsky, E.A.

    1980-08-01

    Performance of long-range energy system analyses requires the capability to project conventional domestic oil and gas supplies in the long term. The objective of the Long-range Forecasting Methodology project is to formulate an approach to this problem which will be compatible with the principal tool employed by the Energy Information Administration of the Department of Energy for long-range energy system analyses, the Long-term Energy Analysis Package (LEAP). This paper reports on projection methodologies that have appeared in the literature, evaluates them in terms of their applicability to the LEAP framework, and discusses the principal determinants of conventional domestic oil and gas supply in the long run.

  19. Memory and long-range correlations in chess games

    NASA Astrophysics Data System (ADS)

    Schaigorodsky, Ana L.; Perotti, Juan I.; Billoni, Orlando V.

    2014-01-01

    In this paper we report the existence of long-range memory in the opening moves of a chronologically ordered set of chess games using an extensive chess database. We used two mapping rules to build discrete time series and analyzed them using two methods for detecting long-range correlations; rescaled range analysis and detrended fluctuation analysis. We found that long-range memory is related to the level of the players. When the database is filtered according to player levels we found differences in the persistence of the different subsets. For high level players, correlations are stronger at long time scales; whereas in intermediate and low level players they reach the maximum value at shorter time scales. This can be interpreted as a signature of the different strategies used by players with different levels of expertise. These results are robust against the assignation rules and the method employed in the analysis of the time series.

  20. Long-Range Beam-Beam Compensation Using Wires

    NASA Astrophysics Data System (ADS)

    Zimmermann, F.; Schmickler, H.

    At the LHC, the effect of unavoidable long-range beam-beam collisions reduces the dynamic aperture, calling for a minimum crossing angle. A wire compensator partially cancels the effect of the long-range collisions, and may allow operation with reduced crossing angle or decreased beta function at the interaction point, thereby increasing the (virtual) peak luminosity. In this chapter, we describe the proposed compensation scheme, previous validation experiments with a single beam and multiple wires at the SPS, simulations for the LHC high-luminosity upgrade, a demonstrator project with real long-range encounters foreseen in the LHC proper, and the possible use of a low-energy electron beam as a future ultimate "wire".

  1. Long-range corrected density functional theory with linearly-scaled HF exchange

    NASA Astrophysics Data System (ADS)

    Song, Jong-Won; Hirao, Kimihiko

    2015-12-01

    Long-range corrected density functional theory (LC-DFT) attracts many chemists' attentions as a quantum chemical method to be applied to large molecular system and its property calculations. However, the expensive time cost to evaluate the long-range HF exchange is a big obstacle to be overcome to be applied to the large molecular systems and the solid state materials. Upon this problem, we propose a linear-scaling method of the HF exchange integration, in particular, for the LC-DFT hybrid functional.

  2. Long-range corrected density functional theory with linearly-scaled HF exchange

    SciTech Connect

    Song, Jong-Won; Hirao, Kimihiko

    2015-12-31

    Long-range corrected density functional theory (LC-DFT) attracts many chemists’ attentions as a quantum chemical method to be applied to large molecular system and its property calculations. However, the expensive time cost to evaluate the long-range HF exchange is a big obstacle to be overcome to be applied to the large molecular systems and the solid state materials. Upon this problem, we propose a linear-scaling method of the HF exchange integration, in particular, for the LC-DFT hybrid functional.

  3. Coding constraints modulate chemically spontaneous mutational replication gradients in mitochondrial genomes.

    PubMed

    Seligmann, Hervé

    2012-03-01

    Distances from heavy and light strand replication origins determine duration mitochondrial DNA remains singlestranded during replication. Hydrolytic deaminations from A->G and C->T occur more on single- than doublestranded DNA. Corresponding replicational nucleotide gradients exist across mitochondrial genomes, most at 3rd, least 2(nd) codon positions. DNA singlestrandedness during RNA transcription causes gradients mainly in long-lived species with relatively slow metabolism (high transcription/replication ratios). Third codon nucleotide contents, evolutionary results of mutation cumulation, follow replicational, not transcriptional gradients in Homo; observed human mutations follow transcriptional gradients. Synonymous third codon position transitions potentially alter adaptive off frame information. No mutational gradients occur at synonymous positions forming off frame stops (these adaptively stop early accidental frameshifted protein synthesis), nor in regions coding for putative overlapping genes according to an overlapping genetic code reassigning stop codons to amino acids. Deviation of 3rd codon nucleotide contents from deamination gradients increases with coding importance of main frame 3rd codon positions in overlapping genes (greatest if these are 2(nd) position in overlapping genes). Third codon position deamination gradients calculated separately for each codon family are strongest where synonymous transitions are rarely pathogenic; weakest where transitions are frequently pathogenic. Synonymous mutations affect translational accuracy, such as error compensation of misloaded tRNAs by codon-anticodon mismatches (prevents amino acid misinsertion despite tRNA misacylation), a potential cause of pathogenic mutations at synonymous codon positions. Indeed, codon-family-specific gradients are inversely proportional to error compensation associated with gradient-promoted transitions. Deamination gradients reflect spontaneous chemical reactions in

  4. Long-range correction for dipolar fluids at planar interfaces

    NASA Astrophysics Data System (ADS)

    Werth, Stephan; Horsch, Martin; Hasse, Hans

    2015-12-01

    A slab-based long-range correction for dipolar interactions in molecular dynamics simulation of systems with a planar geometry is presented and applied to simulate vapour-liquid interfaces. The present approach is validated with respect to the saturated liquid density and the surface tension of the Stockmayer fluid and a molecular model for ethylene oxide. The simulation results exhibit no dependence on the cut-off radius for radii down to 1 nm, proving that the long-range correction accurately captures the influence of the dipole moment on the intermolecular interaction energies and forces as well as the virial and the surface tension.

  5. Long-range dependence in interest rates and monetary policy

    NASA Astrophysics Data System (ADS)

    Cajueiro, Daniel O.; Tabak, Benjamin M.

    2008-01-01

    This Letter studies the dynamics of Brazilian interest rates for short-term maturities. The Letter employs developed techniques in the econophysics literature and tests for long-range dependence in the term structure of these interest rates for the last decade. Empirical results suggest that the degree of long-range dependence has changed over time due to changes in monetary policy, specially in the short-end of the term structure of interest rates. Therefore, we show that it is possible to identify monetary arrangements using these techniques from econophysics.

  6. Long-Range Beam-Beam Compensation in RHIC

    SciTech Connect

    Kim, Hyung Jin; Sen, Tanaji; Fischer, Wolfram; /Brookhaven

    2010-05-01

    In order to avoid the effects of long-range beam-beam interactions which produce beam blow-up and deteriorate beam life time, a compensation scheme with current carrying wires has been proposed. Two long-range beam-beam compensators were installed in RHIC rings in 2006. The effects of the compensators have been experimentally investigated. An indication was observed that the compensators are beneficial to beam life time in measurements performed in RHIC during 2009. In this paper, we report the effects of wire compensator on beam loss and emittance for proton-proton beams at collision energy.

  7. Small long-range alpha detector (LRAD) with computer readout

    SciTech Connect

    MacArthur, D.W.; Allander, K.S.; Bounds, J.A.; Butterfield, K.B.

    1991-10-01

    The small long-range alpha detector developed by N-2 was described in detail in the Los Alamos publication LA-12073-MS, Long-Range Alpha Detector,'' published in 1991. Since publication of that report, a computerized data acquisition system has been added to the LRAD detector. In addition to detailing the new data acquisition system, we discuss new data generated with the enhanced system, including measurements of (1) ultimate sensitivity; (2) detector linearity; (3) ion lifetime; and (4) characteristics. Furthermore, we have expanded our understanding of ion recombination and statistical noise effects in the LRAD and have addressed them here as well as several proposed applications. 6 refs., 30 figs.

  8. Design of a high capacity long range cargo aircraft

    NASA Technical Reports Server (NTRS)

    Weisshaar, Terrence A.

    1994-01-01

    This report examines the design of a long range cargo transport to attempt to reduce ton-mile shipping costs and to stimulate the air cargo market. This design effort involves the usual issues but must also include consideration of: airport terminal facilities; cargo loading and unloading; and defeating the 'square-cube' law to design large structures. This report reviews the long range transport design problem and several solutions developed by senior student design teams at Purdue University. The results show that it will be difficult to build large transports unless the infrastructure is changed and unless the basic form of the airplane changes so that aerodynamic and structural efficiencies are employed.

  9. Long-range correlation in cosmic microwave background radiation.

    PubMed

    Movahed, M Sadegh; Ghasemi, F; Rahvar, Sohrab; Tabar, M Reza Rahimi

    2011-08-01

    We investigate the statistical anisotropy and gaussianity of temperature fluctuations of Cosmic Microwave Background (CMB) radiation data from the Wilkinson Microwave Anisotropy Probe survey, using the Multifractal Detrended Fluctuation Analysis, Rescaled Range, and Scaled Windowed Variance methods. Multifractal Detrended Fluctuation Analysis shows that CMB fluctuations has a long-range correlation function with a multifractal behavior. By comparing the shuffled and surrogate series of CMB data, we conclude that the multifractality nature of the temperature fluctuation of CMB radiation is mainly due to the long-range correlations, and the map is consistent with a gaussian distribution. PMID:21928945

  10. RESIDENCE TIME OF ATMOSPHERIC POLLUTANTS AND LONG-RANGE TRANSPORT

    EPA Science Inventory

    The Lagrangian trajectory model which is suitable for the study of long-range transport of pollutants, is developed. The computer program is capable of calculating trajectories over the region of the U.S. using routine sounding data. The output consists of tables of locations of ...

  11. Long-range correlation analysis of economic news flow intensity

    NASA Astrophysics Data System (ADS)

    Sidorov, S. P.; Faizliev, A. R.; Balash, V. A.; Korobov, E. A.

    2016-02-01

    The goal of the paper is to examine the auto-correlation properties for time series of the news flow intensity using different methods, such as the fluctuation analysis, the detrended fluctuation analysis and the detrending moving average analysis. Empirical findings for news analytics data show the presence of long-range correlations for the time series of news intensity data.

  12. LONG RANGE DEVELOPMENT PLAN FOR HONOLULU COMMUNITY COLLEGE.

    ERIC Educational Resources Information Center

    KILIAN, OTTO H.

    THE LONG RANGE DEVELOPMENT PLAN FOR HONOLULU COMMUNITY COLLEGE DESCRIBES VERY BRIEFLY A WIDE RANGE OF TOPICS AS FOLLOWS--(1) SITE CONDITIONS--VICINITY MAP, PHYSICAL CHARACTERISTICS, ZONING AND LAND USE, ASSESSED VALUATIONS, TRAFFIC ANALYSIS, (2) EXISTING CAMPUS--TYPE, AGE AND CONDITION OF NEIGHBORHOOD AND CAMPUS STRUCTURES, CAMPUS PLAN, CAMPUS…

  13. "MAPseq"-uencing Long-Range Neuronal Projections.

    PubMed

    Yonehara, Keisuke; Roska, Botond

    2016-09-01

    Kebschull et al. (2016a) describe "MAPseq," which tags individual neurons from a specific brain region with individual mRNA barcodes and sequences these barcodes in other brain regions. This allows the simultaneous mapping of long-range neuronal projections at single-cell resolution. PMID:27608754

  14. New Long-Range Interaction between Dipolar Chains

    NASA Astrophysics Data System (ADS)

    Gross, Mark; Kiskamp, Stephen

    1997-09-01

    The interaction between two finite chains of dipoles is treated in a systematic fashion by considering perturbations from the idealized case of two infinite, uniform, parallel chains. A long-range attractive interaction is obtained which survives the zero-temperature limit. Thermal effects increase the range of attraction. Applications to magnetorheological fluids are discussed.

  15. Long-Range Strategic Planning: The Rochester Experience.

    ERIC Educational Resources Information Center

    Schultz, John M.; Anthony, Deborah L.

    The administration of Rochester Community Schools (Michigan) initiated a process for long-range strategic planning in 1984, described in this synopsis. Strategic planning is an ongoing, evolutionary process of defining the business one is in or should be in; establishing organizational goals and objectives; and developing and implementing…

  16. Long Range Development Plan, University of California, Riverside.

    ERIC Educational Resources Information Center

    Russell (George Vernon) and Associates, Architects and Planners.

    A long range development plan, conceived as a general guide to final objectives, uses many diagrams and maps to illustrate the text. The plan is predicated on the assumption that orderly and efficient development of site possibilities is subject to ever-changing influences. The following areas are examined--(1) campus environment, (2) academic…

  17. Microcanonical Analysis on a System with Long-Range Interactions

    NASA Astrophysics Data System (ADS)

    Hou, Ji-Xuan; Yu, Xu-Chen; Hou, Jing-Min

    2016-09-01

    We study a long-range interacting spin chain placed in a staggered magnetic field using microcanonical approach and obtain the global phase diagram. We find that this model exhibits both first order phase transition and second order phase transition separated by a tricritical point, and temperature jump can be observed in the first order phase transition.

  18. Strategic Long Range Planning for Universities. AIR Forum 1980 Paper.

    ERIC Educational Resources Information Center

    Baker, Michael E.

    The use of strategic long-range planning at Carnegie-Mellon University (CMU) is discussed. A structure for strategic planning analysis that integrates existing techniques is presented, and examples of planning activities at CMU are included. The key concept in strategic planning is competitive advantage: if a university has a competitive…

  19. Long-range contributions to double beta decay revisited

    NASA Astrophysics Data System (ADS)

    Helo, J. C.; Hirsch, M.; Ota, T.

    2016-06-01

    We discuss the systematic decomposition of all dimension-7 ( d = 7) lepton number violating operators. These d = 7 operators produce momentum enhanced contributions to the long-range part of the 0νββ decay amplitude and thus are severely constrained by existing half-live limits. In our list of possible models one can find contributions to the long-range amplitude discussed previously in the literature, such as the left-right symmetric model or scalar leptoquarks, as well as some new models not considered before. The d = 7 operators generate Majorana neutrino mass terms either at tree-level, 1-loop or 2-loop level. We systematically compare constraints derived from the mass mechanism to those derived from the long-range 0 νββ decay amplitude and classify our list of models accordingly. We also study one particular example decomposition, which produces neutrino masses at 2-loop level, can fit oscillation data and yields a large contribution to the long-range 0 νββ decay amplitude, in some detail.

  20. Causality and quantum criticality in long-range lattice models

    NASA Astrophysics Data System (ADS)

    Maghrebi, Mohammad F.; Gong, Zhe-Xuan; Foss-Feig, Michael; Gorshkov, Alexey V.

    2016-03-01

    Long-range quantum lattice systems often exhibit drastically different behavior than their short-range counterparts. In particular, because they do not satisfy the conditions for the Lieb-Robinson theorem, they need not have an emergent relativistic structure in the form of a light cone. Adopting a field-theoretic approach, we study the one-dimensional transverse-field Ising model with long-range interactions, and a fermionic model with long-range hopping and pairing terms, explore their critical and near-critical behavior, and characterize their response to local perturbations. We deduce the dynamic critical exponent, up to the two-loop order within the renormalization group theory, which we then use to characterize the emergent causal behavior. We show that beyond a critical value of the power-law exponent of the long-range couplings, the dynamics effectively becomes relativistic. Various other critical exponents describing correlations in the ground state, as well as deviations from a linear causal cone, are deduced for a wide range of the power-law exponent.

  1. DEMONSTRATION OF A LONG RANGE TRACER SYSTEM USING PERFLUOROCARBONS

    EPA Science Inventory

    Regional-scale tracer experiments are needed to validate atmospheric dispersion aspects of air pollution models. The capability of a new system, using perfluorocarbon tracers (PFTs), for long-range dispersion experiments at reasonable cost, was demonstrated in two experiments. Tw...

  2. The long-range interaction landscape of gene promoters.

    PubMed

    Sanyal, Amartya; Lajoie, Bryan R; Jain, Gaurav; Dekker, Job

    2012-09-01

    The vast non-coding portion of the human genome is full of functional elements and disease-causing regulatory variants. The principles defining the relationships between these elements and distal target genes remain unknown. Promoters and distal elements can engage in looping interactions that have been implicated in gene regulation. Here we have applied chromosome conformation capture carbon copy (5C) to interrogate comprehensively interactions between transcription start sites (TSSs) and distal elements in 1% of the human genome representing the ENCODE pilot project regions. 5C maps were generated for GM12878, K562 and HeLa-S3 cells and results were integrated with data from the ENCODE consortium. In each cell line we discovered >1,000 long-range interactions between promoters and distal sites that include elements resembling enhancers, promoters and CTCF-bound sites. We observed significant correlations between gene expression, promoter-enhancer interactions and the presence of enhancer RNAs. Long-range interactions show marked asymmetry with a bias for interactions with elements located ∼120 kilobases upstream of the TSS. Long-range interactions are often not blocked by sites bound by CTCF and cohesin, indicating that many of these sites do not demarcate physically insulated gene domains. Furthermore, only ∼7% of looping interactions are with the nearest gene, indicating that genomic proximity is not a simple predictor for long-range interactions. Finally, promoters and distal elements are engaged in multiple long-range interactions to form complex networks. Our results start to place genes and regulatory elements in three-dimensional context, revealing their functional relationships. PMID:22955621

  3. Strategies and Applications for Incorporating Physical and Chemical Signal Gradients in Tissue Engineering

    PubMed Central

    Singh, Milind; Berkland, Cory

    2008-01-01

    From embryonic development to wound repair, concentration gradients of bioactive signaling molecules guide tissue formation and regeneration. Moreover, gradients in cellular and extracellular architecture as well as in mechanical properties are readily apparent in native tissues. Perhaps tissue engineers can take a cue from nature in attempting to regenerate tissues by incorporating gradients into engineering design strategies. Indeed, gradient-based approaches are an emerging trend in tissue engineering, standing in contrast to traditional approaches of homogeneous delivery of cells and/or growth factors using isotropic scaffolds. Gradients in tissue engineering lie at the intersection of three major paradigms in the field—biomimetic, interfacial, and functional tissue engineering—by combining physical (via biomaterial design) and chemical (with growth/differentiation factors and cell adhesion molecules) signal delivery to achieve a continuous transition in both structure and function. This review consolidates several key methodologies to generate gradients, some of which have never been employed in a tissue engineering application, and discusses strategies for incorporating these methods into tissue engineering and implant design. A key finding of this review was that two-dimensional physicochemical gradient substrates, which serve as excellent high-throughput screening tools for optimizing desired biomaterial properties, can be enhanced in the future by transitioning from two dimensions to three dimensions, which would enable studies of cell–protein–biomaterial interactions in a more native tissue–like environment. In addition, biomimetic tissue regeneration via combined delivery of graded physical and chemical signals appears to be a promising strategy for the regeneration of heterogeneous tissues and tissue interfaces. In the future, in vivo applications will shed more light on the performance of gradient-based mechanical integrity and signal

  4. Shear-induced quench of long-range correlations in a liquid mixture.

    PubMed

    Wada, Hirofumi

    2004-03-01

    A static correlation function of concentration fluctuations in a (dilute) binary liquid mixture subjected to both a concentration gradient and uniform shear flow is investigated within the framework of fluctuating hydrodynamics. It is shown that a well-known |c|(2)/k(4) long-range correlation at large wave numbers k crosses over to a weaker divergent one at wave numbers satisfying k<(gamma;/D)(1/2), while an asymptotic shear-controlled power-law dependence is found at much smaller wave numbers given by k<(gamma;/nu)(1/2), where c, gamma;, D, and nu are the mass concentration, the rate of the shear, the mass diffusivity, and the kinematic viscosity of the mixture, respectively. The result will provide the possibility to observe the shear-induced suppression of a long-range correlation experimentally by using, for example, a low-angle light scattering technique. PMID:15089275

  5. Mechanobiological induction of long-range contractility by diffusing biomolecules and size scaling in cell assemblies

    PubMed Central

    Dasbiswas, K.; Alster, E.; Safran, S. A.

    2016-01-01

    Mechanobiological studies of cell assemblies have generally focused on cells that are, in principle, identical. Here we predict theoretically the effect on cells in culture of locally introduced biochemical signals that diffuse and locally induce cytoskeletal contractility which is initially small. In steady-state, both the concentration profile of the signaling molecule as well as the contractility profile of the cell assembly are inhomogeneous, with a characteristic length that can be of the order of the system size. The long-range nature of this state originates in the elastic interactions of contractile cells (similar to long-range “macroscopic modes” in non-living elastic inclusions) and the non-linear diffusion of the signaling molecules, here termed mechanogens. We suggest model experiments on cell assemblies on substrates that can test the theory as a prelude to its applicability in embryo development where spatial gradients of morphogens initiate cellular development. PMID:27283037

  6. Mechanobiological induction of long-range contractility by diffusing biomolecules and size scaling in cell assemblies

    NASA Astrophysics Data System (ADS)

    Dasbiswas, K.; Alster, E.; Safran, S. A.

    2016-06-01

    Mechanobiological studies of cell assemblies have generally focused on cells that are, in principle, identical. Here we predict theoretically the effect on cells in culture of locally introduced biochemical signals that diffuse and locally induce cytoskeletal contractility which is initially small. In steady-state, both the concentration profile of the signaling molecule as well as the contractility profile of the cell assembly are inhomogeneous, with a characteristic length that can be of the order of the system size. The long-range nature of this state originates in the elastic interactions of contractile cells (similar to long-range “macroscopic modes” in non-living elastic inclusions) and the non-linear diffusion of the signaling molecules, here termed mechanogens. We suggest model experiments on cell assemblies on substrates that can test the theory as a prelude to its applicability in embryo development where spatial gradients of morphogens initiate cellular development.

  7. Mechanobiological induction of long-range contractility by diffusing biomolecules and size scaling in cell assemblies.

    PubMed

    Dasbiswas, K; Alster, E; Safran, S A

    2016-01-01

    Mechanobiological studies of cell assemblies have generally focused on cells that are, in principle, identical. Here we predict theoretically the effect on cells in culture of locally introduced biochemical signals that diffuse and locally induce cytoskeletal contractility which is initially small. In steady-state, both the concentration profile of the signaling molecule as well as the contractility profile of the cell assembly are inhomogeneous, with a characteristic length that can be of the order of the system size. The long-range nature of this state originates in the elastic interactions of contractile cells (similar to long-range "macroscopic modes" in non-living elastic inclusions) and the non-linear diffusion of the signaling molecules, here termed mechanogens. We suggest model experiments on cell assemblies on substrates that can test the theory as a prelude to its applicability in embryo development where spatial gradients of morphogens initiate cellular development. PMID:27283037

  8. Microfluidic device with chemical gradient for single-cell cytotoxicity assays.

    PubMed

    Hosokawa, Masahito; Hayashi, Takuma; Mori, Tetsushi; Yoshino, Tomoko; Nakasono, Satoshi; Matsunaga, Tadashi

    2011-05-15

    Here, we report the fabrication of a chemical gradient microfluidic device for single-cell cytotoxicity assays. This device consists of a microfluidic chemical gradient generator and a microcavity array that enables entrapment of cells with high efficiency at 88 ± 6% of the loaded cells. A 2-fold logarithmic chemical gradient generator that is capable of generating a serial 2-fold gradient was designed and then integrated with the microcavity array. High density single-cell entrapment was demonstrated in the device without cell damage, which was performed in 30 s. Finally, we validated the feasibility of this device to perform cytotoxicity assays by exposing cells to potassium cyanide (0-100 μM KCN). The device captured images of 4000 single cells affected by 6 concentrations of KCN and determined cell viability by counting the effected cells. Image scanning of the microcavity array was completed within 10 min using a 10× objective lens and a motorized stage. Aligning cells on the microcavity array eases cell counting, observation, imaging, and evaluation of singular cells. Thus, this platform was able to determine the cytotoxicity of chemicals at a single-cell level, as well as trace the cytotoxicity over time. This device and method will be useful for cytotoxicity analysis and basic biomedical research. PMID:21526753

  9. The impact of long-range transport on secondary aerosol in Northeast Asia

    NASA Astrophysics Data System (ADS)

    Kim, Y.; Carmichael, G. R.; Woo, J.; Zhang, Q.

    2013-12-01

    Long-range transport air pollution is an important issue in Northeast Asia. Large amounts of anthropogenic emissions of SO2 and NOx aggravate air pollution in the region. Most of the emissions come from the industrialized regions along the East China coast. China and Korea are changing their air quality standards for particle pollutant from PM10 to PM2.5 in 2012 and 2015, respectively. According to many previous studies, the long-rang transport of particle matter contributes to Korean air pollution problems, but there are many uncertainties regarding the impact of long range transport. Secondary inorganic aerosols (sulfate, nitrate and ammonium) are dominant ionic contributors to PM2.5. Especially high relative contributions of secondary aerosol appear under westerly wind cases at Korea. The secondary aerosols are produced by converting from SO2 and NOx during the long-range transport, but the contribution varies dramatically depending on season and wind pattern. So far, sulfate is the primary contributor to PM2.5, but nitrate levels are increasing because that NOx emissions in China are increasing dramatically since 2000 due to the growth in power, industry, and transport, while SO2 emissions are trending downward since 2005. We will present chemical characteristics of PM2.5 by westerly long-range transport focused on secondary aerosol, tracking their transport pattern, and production pathway in order to better understand regional air quality modeling of the long-range transport. This study will be performed based on the international study, MICS-Asia phase III, initiated with many researchers. Results using CMAQ with the modeling domain covering Northeast and Southeast China, Korea, and Japan with 15km resolution will be discussed.

  10. The design of a long-range megatransport aircraft

    NASA Technical Reports Server (NTRS)

    Weisshaar, Terrence A.; Allen, Carl L.

    1992-01-01

    Aircraft manufacturers are examining the market and feasibility of long-range passenger aircraft carrying more than 600 passengers. These aircraft would carry travelers at reduced cost and, at the same time, reduce congestion around major airports. The design of a large, long-range transport involves broad issues such as: the integration of airport terminal facilities; passenger loading and unloading; trade-offs between aircraft size and the cost to reconfigure these existing facilities; and, defeating the 'square-cube' law. Thirteen Purdue design teams generated RFP's that defined passenger capability and range, based upon team perception of market needs and infrastructure constraints. Turbofan engines were designed by each group to power these aircraft. The design problem and the variety of solutions developed are reviewed.

  11. Travel: a long-range goal of retired women.

    PubMed

    Staats, Sara; Pierfelice, Loretta

    2003-09-01

    The authors surveyed retired persons (predominately women) with regard to their immediate, intermediate, and long-range activities following retirement. As predicted, leisure travel emerged as a frequent long-range goal for persons retired more than 5 years. The travel activity preferences of long-retired older women present challenges and opportunities to both researchers and marketers. Length of trips and frequency of trips have been predicted from regression models, with trip length in particular being well predicted by the problem of daily life hassles. A theoretical model of continued post-retirement travel is presented as a variant of Solomon's opponent process theory of affect (R. L. Solomon, 1980). The authors suggest that to the degree that places traveled to are varied and different, older people may remain stimulated and continue to enjoy retirement. PMID:14629078

  12. Long-range correlation analysis of urban traffic data

    NASA Astrophysics Data System (ADS)

    Sheng, Peng; Wang, Jun-Feng; Tang, Tie-Qiao; Zhao, Shu-Long

    2010-08-01

    This paper investigates urban traffic data by analysing the long-range correlation with detrended fluctuation analysis. Through a large number of real data collected by the travel time detection system in Beijing, the variation of flow in different time periods and intersections is studied. According to the long-range correlation in different time scales, it mainly discusses the effect of intersection location in road net, people activity customs and special traffic controls on urban traffic flow. As demonstrated by the obtained results, the urban traffic flow represents three-phase characters similar to highway traffic. Moreover, compared by the two groups of data obtained before and after the special traffic restrictions (vehicles with special numbered plates only run in a special workday) enforcement, it indicates that the rules not only reduce the flow but also avoid irregular fluctuation.

  13. Periodic discrete energy for long-range potentials

    NASA Astrophysics Data System (ADS)

    Hardin, D. P.; Saff, E. B.; Simanek, B.

    2014-12-01

    We consider periodic energy problems in Euclidean space with a special emphasis on long-range potentials that cannot be defined through the usual infinite sum. One of our main results builds on more recent developments of Ewald summation to define the periodic energy corresponding to a large class of long-range potentials. Two particularly interesting examples are the logarithmic potential and the Riesz potential when the Riesz parameter is smaller than the dimension of the space. For these examples, we use analytic continuation methods to provide concise formulas for the periodic kernel in terms of the Epstein Hurwitz Zeta function. We apply our energy definition to deduce several properties of the minimal energy including the asymptotic order of growth and the distribution of points in energy minimizing configurations as the number of points becomes large. We conclude with some detailed calculations in the case of one dimension, which shows the utility of this approach.

  14. Temperature inversion in long-range interacting systems

    NASA Astrophysics Data System (ADS)

    Teles, Tarcísio N.; Gupta, Shamik; Di Cintio, Pierfrancesco; Casetti, Lapo

    2015-08-01

    Temperature inversions occur in nature, e.g., in the solar corona and in interstellar molecular clouds: Somewhat counterintuitively, denser parts of the system are colder than dilute ones. We propose a simple and appealing way to spontaneously generate temperature inversions in systems with long-range interactions, by preparing them in inhomogeneous thermal equilibrium states and then applying an impulsive perturbation. In similar situations, short-range systems would typically relax to another thermal equilibrium, with a uniform temperature profile. By contrast, in long-range systems, the interplay between wave-particle interaction and spatial inhomogeneity drives the system to nonequilibrium stationary states that generically exhibit temperature inversion. We demonstrate this mechanism in a simple mean-field model and in a two-dimensional self-gravitating system. Our work underlines the crucial role the range of interparticle interaction plays in determining the nature of steady states out of thermal equilibrium.

  15. Sirius: a long-range infrared search and track system

    NASA Astrophysics Data System (ADS)

    Knepper, R.

    1997-08-01

    Sirius is a long range infra red search and track system (LR- IRST) and intended to be used in an anti air warfare (AAW) multisensor suite on board of modern frigates. This Dutch/Canadian development program started 1/1/95 and includes also the evaluation of the system in warm and cold water scenarios. The operational requirements were drafted by both the national navies. The primary task is automatic detection, tracking and reporting of seaskimming missiles at long range. The design is based on recent experiences with IRSTs and the latest technological achievements in the areas of processing capabilities and IR-detectors. In this presentation design drivers and main technical choices are discussed.

  16. Preservation of long range temporal correlations under extreme random dilution

    NASA Astrophysics Data System (ADS)

    Mirzayof, Dror; Ashkenazy, Yosef

    2010-12-01

    Many natural time series exhibit long range temporal correlations that may be characterized by power-law scaling exponents. However, in many cases, the time series have uneven time intervals due to, for example, missing data points, noisy data, and outliers. Here we study the effect of randomly missing data points on the power-law scaling exponents of time series that are long range temporally correlated. The Fourier transform and detrended fluctuation analysis (DFA) techniques are used for scaling exponent estimation. We find that even under extreme dilution of more than 50%, the value of the scaling exponent remains almost unaffected. Random dilution is also applied on heart interbeat interval time series. It is found that dilution of 70%-80% of the data points leads to a reduction of only 8% in the scaling exponent; it is also found that it is possible to discriminate between healthy and heart failure subjects even under extreme dilution of more than 90%.

  17. Quantum Defect Theory for Long-range Anisotropic Interactions

    NASA Astrophysics Data System (ADS)

    Ruzic, Brandon P.; Bohn, John L.; Greene, Chris H.

    2014-05-01

    Quantum Defect Theory (QDT) is a numerically efficient and accurate tool for studying a wide variety of ultracold atomic collisions, where the asymptotic behavior of the atoms is well described by a set of simple parameters. However, analytic formulas for these parameters only exist for the pure - 1 /R6 potential. The long-range parameters are given by simple power law equations in the collision energy, and the bound state energies of different partial waves are simply related. We extend these formulas to encompass all potentials of the form - 1 /Rn , where n > 2 . Moreover, the accuracy of QDT is limited by long-range anisotropic interactions, which, for example, play an important role in collisions of dysprosium or erbium atoms. We present our recent developments on numerically treating this type of interaction within perturbation theory. This work is supported by the US Department of Energy.

  18. Long-range nuclear cruise missiles and stability

    SciTech Connect

    Lewis, G.N.; Postol, T.A. )

    1992-01-01

    Long-range nuclear-armed cruise missiles are highly accurate and are capable of reaching most targets within the United States and the Commonwealth of Independent States (CIS) from launch points beyond their borders. Neither the United States nor the CIS has air surveillance systems capable of providing reliable warning against cruise missiles. Thus it is possible that a small-scale cruise missile attack could go entirely undetected until the nuclear weapons arrived over their targets. Such an attack could destroy the other country's entire strategic bomber force on the ground and severely damage its strategic command and control system, perhaps to the point of endangering the ability of its ICBM force to be launched on warning. This capability makes long-range nuclear cruise missiles potentially one of the most destabilizing of all nuclear weapons.

  19. Long-range mutual information and topological uncertainty principle

    NASA Astrophysics Data System (ADS)

    Jian, Chao-Ming; Kim, Isaac; Qi, Xiao-Liang

    Ordered phases in Landau paradigm can be diagnosed by a local order parameter, whereas topologically ordered phases cannot be detected in such a way. In this paper, we propose long-range mutual information (LRMI) as a unified diagnostic for both conventional long-range order and topological order. Using the LRMI, we characterize orders in n +1D gapped systems as m-membrane condensates with 0 <= m <= n-1. The familiar conventional order and 2 +1D topological orders are respectively identified as 0-membrane and 1-membrane condensates. We propose and study the topological uncertainty principle, which describes the non-commuting nature of non-local order parameters in topological orders.

  20. Information propagation and equilibration in long-range Kitaev chains

    NASA Astrophysics Data System (ADS)

    Van Regemortel, Mathias; Sels, Dries; Wouters, Michiel

    2016-03-01

    We study the propagation of information through a Kitaev chain with long-range pairing interactions. Although the Lieb-Robinson bound is violated in the strict sense for long-range interacting systems, we illustrate that a major amount of information in this model still propagates ballistically on a light cone. We find a pronounced effect of the interaction range on the decay of the mutual information between spatially disconnected subsystems. A significant amount of information is shared at timelike separations. This regime is accompanied by very slow equilibration of local observables. As the Kitaev model is quasifree, we illustrate how the distribution of quasiparticle group velocities explains the physics of this system qualitatively.

  1. Long-range Coulomb interaction in nodal-ring semimetals

    NASA Astrophysics Data System (ADS)

    Huh, Yejin; Moon, Eun-Gook; Kim, Yong Baek

    2016-01-01

    Recently there have been several proposals of materials predicted to be nodal-ring semimetals, where zero energy excitations are characterized by a nodal ring in the momentum space. This class of materials falls between the Dirac-like semimetals and the more conventional Fermi-surface systems. As a step towards understanding this unconventional system, we explore the effects of the long-range Coulomb interaction. Due to the vanishing density of states at the Fermi level, Coulomb interaction is only partially screened and remains long-ranged. Through renormalization group and large-Nf computations, we have identified a nontrivial interacting fixed point. The screened Coulomb interaction at the interacting fixed point is an irrelevant perturbation, allowing controlled perturbative evaluations of physical properties of quasiparticles. We discuss unique experimental consequences of such quasiparticles: acoustic wave propagation, anisotropic dc conductivity, and renormalized phonon dispersion as well as energy dependence of quasiparticle lifetime.

  2. Reaching for the Horizon: The 2015 NSAC Long Range Plan

    NASA Astrophysics Data System (ADS)

    Geesaman, Donald

    2015-10-01

    In April 2014, the Nuclear Science Advisory Committee was charged to conduct a new study of the opportunities and priorities for United States nuclear physics research and to recommend a long range plan for the coordinated advancement of the Nation's nuclear science program over the next decade. The entire community actively contributed to developing this plan. Ideas and goals, new and old, were examined and community priorities were established. The Long Range Plan Working Group gathered at Kitty Hawk, NC to converge on the recommendations. In this talk I will discuss the vision for the future that has emerged from this process. The new plan, ``Reaching for the Horizon,'' offers the promise of great leaps forward in our understanding of nuclear science and new opportunities for nuclear science to serve society. This work was supported by the U. S. Department of Energy, Office of Science, Office of Nuclear Physics, under Contract No. DE-AC02-06CH11357.

  3. The design of a long range megatransport aircraft

    NASA Technical Reports Server (NTRS)

    Weisshaar, Terrence A.; Allen, Carl L.

    1992-01-01

    During the period from August 1991 - June 1992 two design classes at Purdue University participated in the design of a long range, high capacity transport aircraft, dubbed the megatransport. Thirteen Purdue design teams generated RFP's that defined passenger capability and range, based upon team perception of market needs and infrastructure constraints. Turbofan engines were designed by each group to power these aircraft. The design problem and the variety of solutions developed are described in an attached paper.

  4. Long Range Interactions With Laser Cooled Neutral Atoms

    SciTech Connect

    Gattobigio, Giovanni Luca; Michaud, Franck; Labeyrie, Guillaume; Kaiser, Robin; Loureiro, Jorge; Mendonca, Jose Tito; Tercas, Hugo; Pohl, Thomas

    2008-09-07

    Multiple scattering of light in a trap of laser cooled neutral atoms leads to repulsion forces between the atoms. The corresponding interactions have long range behavior in 1/r{sup 2} and are thus similar to Coulomb interaction in an one component confined plasma. Consequences of these interactions will be described in this paper, including the limitation of the spatial density one can obtain in such systems and self-sustained oscillations of the cloud.

  5. Emergent long-range couplings in arrays of fluid cells

    SciTech Connect

    Abraham, Douglas Bruce

    2014-08-07

    We present a system exhibiting extraordinarily long-range cooperative effects, on a length scale far exceeding the bulk correlation length. We give a theoretical explanation of these phenomena based on the mesoscopic picture of phase coexistence in finite systems, which is confirmedly Monte Carlo (MC) simulation studies. Our work demonstrates that such action-at-a-distance can occur in classical systems involving simple or complex fluids, such as colloid-polymer mixtures, or ferromagnets.

  6. Long-range substantially nonradiative metallo-dielectric waveguide.

    PubMed

    Buckley, Robin; Berini, Pierre

    2009-01-15

    A waveguide structure capable of aggressive bends (r(0)-->0) and long-range propagation (approximately 1.2 dB/mm) is described here. The structure uses a step-index slab to create the vertical confinement and a pair of metallic parallel plates on either side of the core for lateral confinement. The parallel plates are dimensioned to ensure that all modes that would cause radiation loss in a bend are cut off. PMID:19148262

  7. Long-range quantum entanglement in noisy cluster states

    SciTech Connect

    Raussendorf, Robert; Bravyi, Sergey; Harrington, Jim

    2005-06-15

    We describe a phase transition for long-range entanglement in a three-dimensional cluster state affected by noise. The partially decohered state is modeled by the thermal state of a short-range translation-invariant Hamiltonian. We find that the temperature at which the entanglement length changes from infinite to finite is nonzero. We give an upper and lower bound to this transition temperature.

  8. Long range Ising model for credit risk modeling

    NASA Astrophysics Data System (ADS)

    Molins, Jordi; Vives, Eduard

    2005-07-01

    Within the framework of maximum entropy principle we show that the finite-size long-range Ising model is the adequate model for the description of homogeneous credit portfolios and the computation of credit risk when default correlations between the borrowers are included. The exact analysis of the model suggest that when the correlation increases a first-order-like transition may occur inducing a sudden risk increase.

  9. Long range science scheduling for the Hubble Space Telescope

    NASA Technical Reports Server (NTRS)

    Miller, Glenn; Johnston, Mark

    1991-01-01

    Observations with NASA's Hubble Space Telescope (HST) are scheduled with the assistance of a long-range scheduling system (SPIKE) that was developed using artificial intelligence techniques. In earlier papers, the system architecture and the constraint representation and propagation mechanisms were described. The development of high-level automated scheduling tools, including tools based on constraint satisfaction techniques and neural networks is described. The performance of these tools in scheduling HST observations is discussed.

  10. Long-range electrostatic screening in ionic liquids.

    PubMed

    Gebbie, Matthew A; Dobbs, Howard A; Valtiner, Markus; Israelachvili, Jacob N

    2015-06-16

    Electrolyte solutions with high concentrations of ions are prevalent in biological systems and energy storage technologies. Nevertheless, the high interaction free energy and long-range nature of electrostatic interactions makes the development of a general conceptual picture of concentrated electrolytes a significant challenge. In this work, we study ionic liquids, single-component liquids composed solely of ions, in an attempt to provide a novel perspective on electrostatic screening in very high concentration (nonideal) electrolytes. We use temperature-dependent surface force measurements to demonstrate that the long-range, exponentially decaying diffuse double-layer forces observed across ionic liquids exhibit a pronounced temperature dependence: Increasing the temperature decreases the measured exponential (Debye) decay length, implying an increase in the thermally driven effective free-ion concentration in the bulk ionic liquids. We use our quantitative results to propose a general model of long-range electrostatic screening in ionic liquids, where thermally activated charge fluctuations, either free ions or correlated domains (quasiparticles), take on the role of ions in traditional dilute electrolyte solutions. This picture represents a crucial step toward resolving several inconsistencies surrounding electrostatic screening and charge transport in ionic liquids that have impeded progress within the interdisciplinary ionic liquids community. More broadly, our work provides a previously unidentified way of envisioning highly concentrated electrolytes, with implications for diverse areas of inquiry, ranging from designing electrochemical devices to rationalizing electrostatic interactions in biological systems. PMID:26040001

  11. Long-range infrasound monitoring of eruptive volcanoes.

    NASA Astrophysics Data System (ADS)

    Marchetti, Emanuele; Innocenti, Lorenzo; Ulivieri, Giacomo; Lacanna, Giorgio; Ripepe, Maurizio

    2016-04-01

    The efficient long-range propagation in the atmosphere makes infrasound of active volcanoes extremely promising and opens new perspectives for volcano monitoring at large scale. In favourable propagation conditions, long-range infrasound observations can be used to track the occurrence and the duration of volcanic eruptions also at remote non-monitored volcanoes, but its potential to infer volcanic eruptive source term is still debated. We present results of comparing five years of infrasound of eruptive activity at Mt.Etna volcano (Italy) recorded both at local (~5 km) and at regional distances (~600 km) from the source. Infrasound of lava fountains at Etna volcano, occurring in between 2010 and 2015, are analysed in terms of the local and regional wavefield record, and by comparing to all available volcanic source terms (i.e. plume height and mass eruption rates). Besides, the potential of near real-time notification of ongoing volcanic activity at Etna volcano at a regional scale is investigated. In particular we show how long range infrasound, in the case of Etna volcano, can be used to promptly deliver eruption notification and reliability is constrained by the results of the local array. This work is performed in the framework of the H2020 ARISE2 project funded by the EU in the period 2015-2018.

  12. Long-range electrostatic screening in ionic liquids

    PubMed Central

    Gebbie, Matthew A.; Dobbs, Howard A.; Valtiner, Markus; Israelachvili, Jacob N.

    2015-01-01

    Electrolyte solutions with high concentrations of ions are prevalent in biological systems and energy storage technologies. Nevertheless, the high interaction free energy and long-range nature of electrostatic interactions makes the development of a general conceptual picture of concentrated electrolytes a significant challenge. In this work, we study ionic liquids, single-component liquids composed solely of ions, in an attempt to provide a novel perspective on electrostatic screening in very high concentration (nonideal) electrolytes. We use temperature-dependent surface force measurements to demonstrate that the long-range, exponentially decaying diffuse double-layer forces observed across ionic liquids exhibit a pronounced temperature dependence: Increasing the temperature decreases the measured exponential (Debye) decay length, implying an increase in the thermally driven effective free-ion concentration in the bulk ionic liquids. We use our quantitative results to propose a general model of long-range electrostatic screening in ionic liquids, where thermally activated charge fluctuations, either free ions or correlated domains (quasiparticles), take on the role of ions in traditional dilute electrolyte solutions. This picture represents a crucial step toward resolving several inconsistencies surrounding electrostatic screening and charge transport in ionic liquids that have impeded progress within the interdisciplinary ionic liquids community. More broadly, our work provides a previously unidentified way of envisioning highly concentrated electrolytes, with implications for diverse areas of inquiry, ranging from designing electrochemical devices to rationalizing electrostatic interactions in biological systems. PMID:26040001

  13. Long-range intercellular Ca2+ wave patterns

    NASA Astrophysics Data System (ADS)

    Tabi, C. B.; Maïna, I.; Mohamadou, A.; Ekobena, H. P. F.; Kofané, T. C.

    2015-10-01

    Modulational instability is utilized to investigate intercellular Ca2+ wave propagation in an array of diffusively coupled cells. Cells are supposed to be connected via paracrine signaling, where long-range effects, due to the presence of extracellular messengers, are included. The multiple-scale expansion is used to show that the whole dynamics of Ca2+ waves, from the endoplasmic reticulum to the cytosol, can be reduced to a single differential-difference nonlinear equation whose solutions are assumed to be plane waves. Their linear stability analysis is studied, with emphasis on the impact of long-range coupling, via the range parameter s. It is shown that s, as well as the number of interacting cells, importantly modifies the features of modulational instability, as small values of s imply a strong coupling, and increasing its value rather reduces the problem to a first-neighbor one. Our theoretical findings are numerically tested, as the generic equations are fully integrated, leading to the emergence of nonlinear patterns of Ca2+ waves. Strong long-range coupling is pictured by extended trains of breather-like structures whose frequency decreases with increasing s. We also show numerically that the number of interacting cells plays on the spatio-temporal formation of Ca2+ patterns, whilst the quasi-perfect intercellular communication depends on the paracrine coupling parameter.

  14. Segmentation of time series with long-range fractal correlations

    PubMed Central

    Bernaola-Galván, P.; Oliver, J.L.; Hackenberg, M.; Coronado, A.V.; Ivanov, P.Ch.; Carpena, P.

    2012-01-01

    Segmentation is a standard method of data analysis to identify change-points dividing a nonstationary time series into homogeneous segments. However, for long-range fractal correlated series, most of the segmentation techniques detect spurious change-points which are simply due to the heterogeneities induced by the correlations and not to real nonstationarities. To avoid this oversegmentation, we present a segmentation algorithm which takes as a reference for homogeneity, instead of a random i.i.d. series, a correlated series modeled by a fractional noise with the same degree of correlations as the series to be segmented. We apply our algorithm to artificial series with long-range correlations and show that it systematically detects only the change-points produced by real nonstationarities and not those created by the correlations of the signal. Further, we apply the method to the sequence of the long arm of human chromosome 21, which is known to have long-range fractal correlations. We obtain only three segments that clearly correspond to the three regions of different G + C composition revealed by means of a multi-scale wavelet plot. Similar results have been obtained when segmenting all human chromosome sequences, showing the existence of previously unknown huge compositional superstructures in the human genome. PMID:23645997

  15. Acidic loadings in South Korean ecosystems by long-range transport and local emissions

    NASA Astrophysics Data System (ADS)

    Shim, Jae-Myun; Park, Soon-Ung

    2004-10-01

    Exceedances of sulfur and nitrogen critical loads in South Korean ecosystems caused by long-range transport and local emissions of sulfur and nitrogen have been estimated using the maximum critical load of sulfur and the critical load of nutrient nitrogen. The long-term-averaged deposition of sulfur and nitrogen is estimated with a simplified chemical model and the K-mean clustering technique. The three consecutive days of gridded daily mean National Center for Environmental Protection (NCEP) reanalyzed 850 hPa geopotential height fields with and without precipitation on the last day over South Korea are used for clustering of synoptic patterns for the period of 1994-1998. Two emission conditions are simulated for each cluster to estimate long-term averaged depositions of sulfur and nitrogen by long-range transport and local emissions over South Korea. One condition takes all emissions within the simulated domain into account as a base case and the other condition excludes all South Korean emissions but includes all of the other emissions, as a control case. The results of the present study indicate that the contribution of long-range transport to the annual total deposition over South Korea is found to be about 40% (530 eqha-1yr-1) for sulfur and 49% (650 eqha-1yr-1) for nitrogen, of which 55% for sulfur and 58% for nitrogen are contributed by wet deposition. This suggests the importance of wet deposition through the transformed acidic precursors for long-range transport to South Korea's total deposition of sulfur and nitrogen. The estimated exceedance for South Korean ecosystems indicates that the current estimate of total sulfur deposition affects about 42% of the South Korean ecosystems adversely, of which 14% is attributed to South Korean source only and the rest 28% is attributed to long-range transport together with South Korean source. Long-range transport of sulfur itself does not exceed the maximum critical load of sulfur. On the other hand, the current

  16. Long-Range Weather Forecasting In The Ukraine

    NASA Astrophysics Data System (ADS)

    Martazinova, V. F.; Ivanova, E. K.

    2004-12-01

    The operational system for long range weather forecasting (LRF) was developed by Ukrainian Hydrometeorological Institute (UHMI) in the result of studies of general circulation and on the long-range weather forecasting which were began in 1975 by research group leaded by Prof. V. Martazinova. Three key approaches are used in the operational system LRF of UHMI: (1) Floating analog method (FAM); (2) Two-month quasi-periodicity of atmospheric processes in the troposphere of the Northern Hemisphere; (3)Ethalon-field approach. The based on the pattern recognition technique FAM is the continuation of the ideas of former Soviet Union school of long-range forecasting. The traditional method of analog was generalized and advanced as the method of "floating analog" (Martazinova and Sologub, 1986; Martazinova, 1989; 2001). FAM requires only geometrical similarity of the planetary high-level frontal zone and surface pressure on the Northern Hemisphere. The limiting conditions of the coincidence in time and space are lifted. The use of FAM made it possible to reveal the two-month quasi-periodicity of synoptic situation in the Northern Hemisphere. The strong changes of weather within month are predicted using statistical "ethalon field" approach that was developed for classification of meteorological fields in the climate research and the long-range forecasting (Martazinova and Prokhorenko, 1991). The meteorological information for the forecast is used only for the last two months before the target month. The fields of geopotential and pressure are recognized by the "ethalon-field-analog" which corresponds to two-month quasi-periodicity of the ethalon-fields. The forecast for days the strong changes of weather over the territory of Ukraine in next two months. Recognition of daily synoptic situations of last two months by the synoptic situation of two-month quasi-periodicity of atmospheric processes for ethalons when there are waves of cold and heat, strong precipitation, strong

  17. The Characteristics of Long-range Transboundary Inorganic Secondary Aerosols in Northeast Asia

    NASA Astrophysics Data System (ADS)

    Kim, Y. J.; Carmichael, G. R.; Woo, J. H.; Qiang, Z.

    2014-12-01

    Recurrent particle matter episodes greatly influence air quality in Northeast Asia. According to many studies, a major reason is long-range transport of air pollutant. Large amount of emission of chemical compounds aggravate air pollution in the region. Emitted air pollutants mainly come from industrialized regions along the East China coast. It can be transported over downwind region by the prevailing westerlies. The long-rang transported fine particle certainly attributes to air quality in downwind region, but there are many unknowns on the quantity, transport pattern, and secondary aerosol production mechanism despite the fact with many studies have been performed. Major contributors of PM2.5 are inorganic secondary aerosols, sulfate, nitrate and ammonium, in Korea. Especially high relative contributions of inorganic secondary aerosols appear for westerly wind cases. The main pathway of production of inorganic secondary aerosols is produced by converting from SO2 and NOx during the long-range transport but the contribution varies dramatically depending on season and wind pattern. Sulfate is consistently the primary contributor of PM2.5 still now but we should more concern nitrate because that NOx emissions of China is increasing steeply since 2000 by leading powerplant, industry, and transport, despite downward trend of SO2. In order to better understand regional air quality modeling of the long-range transport, international study, MICS-Asia phase III, has been initiated with many researchers. We will present chemical characteristics of PM2.5 long-range transport during westerly wind cases focused on secondary aerosol, tracking their transport pattern, and production pathway. Results using CMAQ with the modeling domain covering Northeast and Southeast China, Korea, and Japan with 15km resolution will be discussed.

  18. The Origin of Long-Range Attraction between Hydrophobes in Water

    PubMed Central

    Despa, Florin; Berry, R. Stephen

    2007-01-01

    When water-coated hydrophobic surfaces meet, direct contacts form between the surfaces, driving water out. However, long-range attractive forces first bring those surfaces close. This analysis reveals the source and strength of the long-range attraction between water-coated hydrophobic surfaces. The origin is in the polarization field produced by the strong correlation and coupling of the dipoles of the water molecules at the surfaces. We show that this polarization field gives rise to dipoles on the surface of the hydrophobic solutes that generate long-range hydrophobic attractions. Thus, hydrophobic aggregation begins with a step in which water-coated nonpolar solutes approach one another due to long-range electrostatic forces. This precursor regime occurs before the entropy increase of releasing the water layers and the short-range van der Waals attraction provide the driving force to “dry out” the contact surface. The effective force of attraction is derived from basic molecular principles, without assumptions of the structure of the hydrophobe-water interaction. The strength of this force can be measured directly from atomic force microscopy images of a hydrophobic molecule tethered to a surface but extending into water, and another hydrophobe attached to an atomic force probe. The phenomenon can be observed in the transverse relaxation rates in water proton magnetic resonance as well. The results shed light on the way water mediates chemical and biological self-assembly, a long outstanding problem. PMID:16997876

  19. Effects of reversible chemical reaction on Li diffusion and stresses in spherical composition-gradient electrodes

    SciTech Connect

    Li, Yong; Zhang, Kai; Zheng, Bailin Zhang, Xiaoqian; Wang, Qi

    2015-06-28

    Composition-gradient electrode materials have been proven to be one of the most promising materials in lithium-ion battery. To study the mechanism of mechanical degradation in spherical composition-gradient electrodes, the finite deformation theory and reversible chemical theory are adopted. In homogeneous electrodes, reversible electrochemical reaction may increase the magnitudes of stresses. However, reversible electrochemical reaction has different influences on stresses in composition-gradient electrodes, resulting from three main inhomogeneous factors—forward reaction rate, backward reaction rate, and reaction partial molar volume. The decreasing transition form of forward reaction rate, increasing transition form of backward reaction rate, and increasing transition form of reaction partial molar volume can reduce the magnitudes of stresses. As a result, capacity fading and mechanical degradation are reduced by taking advantage of the effects of inhomogeneous factors.

  20. Preparation and analysis of chemically gradient functional bioceramic coating formed by pulsed laser deposition.

    PubMed

    Rajesh, P; Muraleedharan, C V; Sureshbabu, S; Komath, Manoj; Varma, Harikrishna

    2012-02-01

    Bioactive ceramic coatings based on calcium phosphates yield better functionality in the human body for a variety of metallic implant devices including orthopaedic and dental prostheses. In the present study chemically and hence functionally gradient bioceramic coating was obtained by pulsed laser deposition method. Calcium phosphate bioactive ceramic coatings based on hydroxyapatite (HA) and tricalcium phosphate (TCP) were deposited over titanium substrate to produce gradation in physico-chemical characteristics and in vitro dissolution behaviour. Sintered targets of HA and α-TCP were deposited in a multi target laser deposition system. The obtained deposits were characterized by X-ray diffraction, fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray analysis. Inductively coupled plasma spectroscopy was used to estimate the in vitro dissolution behaviour of coatings. The variation in mechanical property of the gradient layer was evaluated through scratch test and micro-indentation hardness. The bioactivity was examined in vitro with respect to the ability of HA layer to form on the surface as a result of contact with simulated body fluid. It could be inferred that chemically gradient functional bioceramic coating can be produced by laser deposition of multiple sintered targets with variable chemical composition. PMID:22105226

  1. Chemical gradients in the Milky Way from the RAVE data. I. Dwarf stars

    NASA Astrophysics Data System (ADS)

    Boeche, C.; Siebert, A.; Piffl, T.; Just, A.; Steinmetz, M.; Sharma, S.; Kordopatis, G.; Gilmore, G.; Chiappini, C.; Williams, M.; Grebel, E. K.; Bland-Hawthorn, J.; Gibson, B. K.; Munari, U.; Siviero, A.; Bienaymé, O.; Navarro, J. F.; Parker, Q. A.; Reid, W.; Seabroke, G. M.; Watson, F. G.; Wyse, R. F. G.; Zwitter, T.

    2013-11-01

    Aims: We aim at measuring the chemical gradients of the elements Mg, Al, Si, and Fe along the Galactic radius to provide new constraints on the chemical evolution models of the Galaxy and Galaxy models such as the Besançon model. Thanks to the large number of stars of our RAVE sample we can study how the gradients vary as function of the distance from the Galactic plane. Methods: We analysed three different samples selected from three independent datasets: a sample of 19 962 dwarf stars selected from the RAVE database, a sample of 10 616 dwarf stars selected from the Geneva-Copenhagen Survey (GCS) dataset, and a mock sample (equivalent to the RAVE sample) created by using the GALAXIA code, which is based on the Besançon model. The three samples were analysed by using the very same method for comparison purposes. We integrated the Galactic orbits and obtained the guiding radii (Rg) and the maximum distances from the Galactic plane reached by the stars along their orbits (Zmax). We measured the chemical gradients as functions of Rg at different Zmax. Results: We found that the chemical gradients of the RAVE and GCS samples are negative and show consistent trends, although they are not equal: at Zmax< 0.4 kpc and 4.5 gradient for the RAVE sample is d [Fe/H] /dRg = -0.065 dex kpc-1, whereas for the GCS sample it is d [Fe/H] /dRg = -0.043 dex kpc-1 with internal errors of ±0.002 and ±0.004 dex kpc-1, respectively. The gradients of the RAVE and GCS samples become flatter at larger Zmax. Conversely, the mock sample has a positive iron gradient of d [Fe/H] /dRg = +0.053 ± 0.003 dex kpc-1 at Zmax< 0.4 kpc and remains positive at any Zmax. These positive and unrealistic values originate from the lack of correlation between metallicity and tangential velocity in the Besançon model. In addition, the low metallicity and asymmetric drift of the thick disc causes a shift of the stars towards lower Rg and metallicity which, together with the thin

  2. Acceleration of evolutionary spread by long-range dispersal.

    PubMed

    Hallatschek, Oskar; Fisher, Daniel S

    2014-11-18

    The spreading of evolutionary novelties across populations is the central element of adaptation. Unless populations are well mixed (like bacteria in a shaken test tube), the spreading dynamics depend not only on fitness differences but also on the dispersal behavior of the species. Spreading at a constant speed is generally predicted when dispersal is sufficiently short ranged, specifically when the dispersal kernel falls off exponentially or faster. However, the case of long-range dispersal is unresolved: Although it is clear that even rare long-range jumps can lead to a drastic speedup--as air-traffic-mediated epidemics show--it has been difficult to quantify the ensuing stochastic dynamical process. However, such knowledge is indispensable for a predictive understanding of many spreading processes in natural populations. We present a simple iterative scaling approximation supported by simulations and rigorous bounds that accurately predicts evolutionary spread, which is determined by a trade-off between frequency and potential effectiveness of long-distance jumps. In contrast to the exponential laws predicted by deterministic "mean-field" approximations, we show that the asymptotic spatial growth is according to either a power law or a stretched exponential, depending on the tails of the dispersal kernel. More importantly, we provide a full time-dependent description of the convergence to the asymptotic behavior, which can be anomalously slow and is relevant even for long times. Our results also apply to spreading dynamics on networks with a spectrum of long-range links under certain conditions on the probabilities of long-distance travel: These are relevant for the spread of epidemics. PMID:25368183

  3. Acceleration of evolutionary spread by long-range dispersal

    PubMed Central

    Hallatschek, Oskar; Fisher, Daniel S.

    2014-01-01

    The spreading of evolutionary novelties across populations is the central element of adaptation. Unless populations are well mixed (like bacteria in a shaken test tube), the spreading dynamics depend not only on fitness differences but also on the dispersal behavior of the species. Spreading at a constant speed is generally predicted when dispersal is sufficiently short ranged, specifically when the dispersal kernel falls off exponentially or faster. However, the case of long-range dispersal is unresolved: Although it is clear that even rare long-range jumps can lead to a drastic speedup—as air-traffic–mediated epidemics show—it has been difficult to quantify the ensuing stochastic dynamical process. However, such knowledge is indispensable for a predictive understanding of many spreading processes in natural populations. We present a simple iterative scaling approximation supported by simulations and rigorous bounds that accurately predicts evolutionary spread, which is determined by a trade-off between frequency and potential effectiveness of long-distance jumps. In contrast to the exponential laws predicted by deterministic “mean-field” approximations, we show that the asymptotic spatial growth is according to either a power law or a stretched exponential, depending on the tails of the dispersal kernel. More importantly, we provide a full time-dependent description of the convergence to the asymptotic behavior, which can be anomalously slow and is relevant even for long times. Our results also apply to spreading dynamics on networks with a spectrum of long-range links under certain conditions on the probabilities of long-distance travel: These are relevant for the spread of epidemics. PMID:25368183

  4. Long-range attraction of particles adhered to lipid vesicles

    NASA Astrophysics Data System (ADS)

    Sarfati, Raphael; Dufresne, Eric R.

    2016-07-01

    Many biological systems fold thin sheets of lipid membrane into complex three-dimensional structures. This microscopic origami is often mediated by the adsorption and self-assembly of proteins on a membrane. As a model system to study adsorption-mediated interactions, we study the collective behavior of micrometric particles adhered to a lipid vesicle. We estimate the colloidal interactions using a maximum likelihood analysis of particle trajectories. When the particles are highly wrapped by a tense membrane, we observe strong long-range attractions with a typical binding energy of 150 kBT and significant forces extending a few microns.

  5. DIII-D tokamak long range plan. Revision 3

    SciTech Connect

    1992-08-01

    The DIII-D Tokamak Long Range Plan for controlled thermonuclear magnetic fusion research will be carried out with broad national and international participation. The plan covers: (1) operation of the DIII-D tokamak to conduct research experiments to address needs of the US Magnetic Fusion Program; (2) facility modifications to allow these new experiments to be conducted; and (3) collaborations with other laboratories to integrate DIII-D research into the national and international fusion programs. The period covered by this plan is 1 November 19983 through 31 October 1998.

  6. A Long Range Science Rover For Future Mars Missions

    NASA Technical Reports Server (NTRS)

    Hayati, Samad

    1997-01-01

    This paper describes the design and implementation currently underway at the Jet Propulsion Laboratory of a long range science rover for future missions to Mars. The small rover prototype, called Rocky 7, is capable of long traverse. autonomous navigation. and science instrument control, carries three science instruments, and can be commanded from any computer platform and any location using the World Wide Web. In this paper we describe the mobility system, the sampling system, the sensor suite, navigation and control, onboard science instruments. and the ground command and control system.

  7. Application of advanced technology to future long-range aircraft

    NASA Technical Reports Server (NTRS)

    Schrader, O. E.

    1976-01-01

    An assessment is presented of three separate programs that have incorporated advanced technology into the design of long-range passenger and cargo aircraft. The first technology centers around the use of a span-loaded cargo aircraft with the payload distributed along the wing. The second technology is the application of laminar flow control to the aircraft to reduce the aerodynamic drag. The last program evaluates the production of alternate aircraft fuels from coal and the use of liquid hydrogen as an aircraft fuel.

  8. Impact of atmospheric aerosols on long range image quality

    NASA Astrophysics Data System (ADS)

    LeMaster, Daniel A.; Eismann, Michael T.

    2012-06-01

    Image quality in high altitude long range imaging systems can be severely limited by atmospheric absorption, scattering, and turbulence. Atmospheric aerosols contribute to this problem by scattering target signal out of the optical path and by scattering in unwanted light from the surroundings. Target signal scattering may also lead to image blurring though, in conventional modeling, this effect is ignored. The validity of this choice is tested in this paper by developing an aerosol modulation transfer function (MTF) model for an inhomogeneous atmosphere and then applying it to real-world scenarios using MODTRAN derived scattering parameters. The resulting calculations show that aerosol blurring can be effectively ignored.

  9. Reconfigurable long-range phonon dynamics in optomechanical arrays.

    PubMed

    Xuereb, André; Genes, Claudiu; Pupillo, Guido; Paternostro, Mauro; Dantan, Aurélien

    2014-04-01

    We investigate periodic optomechanical arrays as reconfigurable platforms for engineering the coupling between multiple mechanical and electromagnetic modes and for exploring many-body phonon dynamics. Exploiting structural resonances in the coupling between light fields and collective motional modes of the array, we show that tunable effective long-range interactions between mechanical modes can be achieved. This paves the way towards the implementation of controlled phononic walks and heat transfer on densely connected graphs as well as the coherent transfer of excitations between distant elements of optomechanical arrays. PMID:24745417

  10. INEL D&D Long-Range Plan

    SciTech Connect

    Buckland, R.J.; Kenoyer, D.J.; Preussner, D.H.

    1993-10-01

    This Long-Range Plan presents the Decontamination and Decommissioning (D&D) Program planning status for facilities at the Idaho National Engineering Laboratory (INEL). The plan provides a general description of the D&D Program objectives, management criteria, and philosophy; discusses current activities; and documents the INEL D&D Program cost and schedule estimate projections for the next 15 years. appendices are included that provide INEL D&D project historical information and a comprehensive descriptive summary of each current surplus facility.

  11. Comment on "Temperature inversion in long-range interacting systems".

    PubMed

    Dumin, Yurii V

    2016-06-01

    In the recent paper by Teles et al. [Phys. Rev. E 92, 020101 (2015)]PRESCM1539-375510.1103/PhysRevE.92.020101, it was suggested that the inversed temperature profiles in various astrophysical objects-ranging from the solar corona to the interstellar molecular clouds-can be explained by the specific features of relaxation in the long-range interacting systems. Here, we show that this mechanism can really work in the self-gravitating interstellar gaseous clouds; but it is irrelevant in the solar (and stellar) coronas where stratification of density is produced by the external gravitational field. PMID:27415395

  12. INEL D&D long-range plan

    SciTech Connect

    Buckland, R.J.; Kenoyer, D.J.; LaBuy, S.A.

    1995-09-01

    This Long-Range Plan presents the Decontamination and Dismantlement (D&D) Program planning status for facilities at the Idaho National Engineering Laboratory (INEL). The plan provides a general description of the D&D Program objectives, management criteria, and policy; discusses current activities; and documents the INEL D&D Program cost and schedule estimate projections for the next 15 years. Appendices are included that provide INEL D&D project historical information, a comprehensive descriptive summary of each current D&D surplus facility, and a summary database of all INEL contaminated facilities awaiting or undergoing the facility transition process.

  13. The design of a long range megatransport aircraft

    NASA Technical Reports Server (NTRS)

    Weisshaar, T. A.; Layton, J. B.; Allen, C. L.

    1993-01-01

    Megatransport objectives and constraints are briefly reviewed, and certain solutions developed by student design teams at Perdue University are summarized. Particular attention is given to the market needs and the economic risks involved in such a project; and the different approaches taken to solve the problem and difficulties faced by the design teams. A long range megatransport aircraft is aimed at carrying more than 600 passengers at reduced cost, and at the same time, reducing airport and airway congestion. The design effort must take into account airport terminal facilities; passenger loading and unloading; and defeating the 'square-cube' law to design large structures.

  14. Comment on "Temperature inversion in long-range interacting systems"

    NASA Astrophysics Data System (ADS)

    Dumin, Yurii V.

    2016-06-01

    In the recent paper by Teles et al. [Phys. Rev. E 92, 020101 (2015)], 10.1103/PhysRevE.92.020101, it was suggested that the inversed temperature profiles in various astrophysical objects—ranging from the solar corona to the interstellar molecular clouds—can be explained by the specific features of relaxation in the long-range interacting systems. Here, we show that this mechanism can really work in the self-gravitating interstellar gaseous clouds; but it is irrelevant in the solar (and stellar) coronas where stratification of density is produced by the external gravitational field.

  15. Political Mechanisms for Long-Range Survival and Development

    NASA Astrophysics Data System (ADS)

    Marshall, W.

    As the first species aware of extinction and capable of proactively ensuring our long-term survival and development, it is striking that we do not do so with the rigor, formality, and foresight it requires. Only from a reactive posture have we responded to the challenges of global warfare, human rights, environmental concerns, and sustainable development. Despite our awareness of the possibility for extinction and apocalyptic set-backs to our evolution, and despite the existence of long-range studies-which must still be dramatically increased-proactive global policy implementation regarding our long-term survival and development is arguably non-existent. This lack of long-term policy making can be attributed in part to the lack of formal political mechanisms to facilitate longer-range policy making that extends 30 years or more into the future. Political mechanisms for infusing long-range thinking, research, and strategic planning into the policy-making process can help correct this shortcoming and provide the motivation needed to adequately address long-term challenges with the political rigor required to effectively establish and implement long-term policies. There are some efforts that attempt to address longer-range issues, but those efforts often do not connect to the political process, do not extend 30 or more years into the future, are not well-funded, and are not sufficiently systemic. Political mechanisms for long-range survival and prosperity could correct these inadequacies by raising awareness, providing funding, and most importantly, leveraging political rigor to establish and enforce long-range strategic planning and policies. The feasibility of such mechanisms should first be rigorously studied and assessed in a feasibility study, which could then inform implementation. This paper will present the case for such a study and suggest some possible political mechanisms that should be investigated further in the proposed study. This work is being further

  16. Immiscible Lattice Gas with Long-Range Interaction

    NASA Astrophysics Data System (ADS)

    Tsumaya, Akira; Ohashi, Hirotada

    We developed a new LGA model which has the applicability for simulation of immiscible two phases with wide difference in density. We introduced long-range interparticle forces into the Rothman and Keller's ILG model to represent density difference between phases. We attempted some simulations of phase separation using our new model. Two-phase interfaces are stably made with density distribution coinciding with particle color distribution. Furthermore, the two-phase interface is clearer than that obtained by the Appert and Zaleski's LG model.

  17. Fabrication and characterization of a microfluidic module for chemical gradient generation utilizing passive pumping.

    PubMed

    Kuo, Jonathan T W; Li, Connie; Meng, Ellis

    2014-01-01

    We introduce a micro-biochemical administration module (μBAM) for generating chemical gradients for use in axonal guidance studies. The device is designed to be simple to use, require minimal packaging, and be operated using only a pipette. A passive pumping mechanism is utilized to pump liquid through a SU-8 microchannel and then the micropore on the Parylene cap of the microchannel. The achievable flow rate delivery through the micropore was characterized and manipulated by varying the drop volumes used to passively drive fluid flow into the device. Biochemicals controllably delivered using this module can be combined with neuronal cell cultures to form chemical gradients for axonal guidance studies. PMID:25570971

  18. Surface tension and long range corrections of cylindrical interfaces

    SciTech Connect

    Bourasseau, E.; Ghoufi, A.

    2015-12-21

    The calculation of the surface tension of curved interfaces has been deeply investigated from molecular simulation during this last past decade. Recently, the thermodynamic Test-Area (TA) approach has been extended to the calculation of surface tension of curved interfaces. In the case of the cylindrical vapour-liquid interfaces of water and Lennard-Jones fluids, it was shown that the surface tension was independent of the curvature of the interface. In addition, the surface tension of the cylindrical interface is higher than that of the planar interface. Molecular simulations of cylindrical interfaces have been so far performed (i) by using a shifted potential, (ii) by means of large cutoff without periodic boundary conditions, or (iii) by ignoring the long range corrections to the surface tension due to the difficulty to estimate them. Indeed, unlike the planar interfaces there are no available operational expressions to consider the tail corrections to the surface tension of cylindrical interfaces. We propose here to develop the long range corrections of the surface tension for cylindrical interfaces by using the non-exponential TA (TA2) method. We also extend the formulation of the Mecke-Winkelmann corrections initially developed for planar surfaces to cylindrical interfaces. We complete this study by the calculation of the surface tension of cylindrical surfaces of liquid tin and copper using the embedded atom model potentials.

  19. Long-range response in ac electricity grids.

    PubMed

    Jung, Daniel; Kettemann, Stefan

    2016-07-01

    Local changes in the topology of electricity grids can cause overloads far away from the disturbance [D. Witthaut and M. Timme, Eur. Phys. J. B 86, 377 (2013)EPJBFY1434-602810.1140/epjb/e2013-40469-4], making the prediction of the robustness against changes in the topology-for example, caused by power outages or grid extensions-a challenging task. The impact of single-line additions on the long-range response of dc electricity grids has recently been studied [D. Labavić, R. Suciu, H. Meyer-Ortmanns, and S. Kettemann, Eur. Phys. J.: Spec. Top. 223, 2517 (2014)1951-635510.1140/epjst/e2014-02273-0]. By solving the real part of the static ac load flow equations, we conduct a similar investigation for ac grids. In a regular two-dimensional grid graph with cyclic boundary conditions, we find a power law decay for the change of power flow as a function of distance to the disturbance over a wide range of distances. The power exponent increases and saturates for large system sizes. By applying the same analysis to the German transmission grid topology, we show that also in real-world topologies a long-ranged response can be found. PMID:27575148

  20. Slow and long-ranged dynamical heterogeneities in dissipative fluids.

    PubMed

    Avila, Karina E; Castillo, Horacio E; Vollmayr-Lee, Katharina; Zippelius, Annette

    2016-06-28

    A two-dimensional bidisperse granular fluid is shown to exhibit pronounced long-ranged dynamical heterogeneities as dynamical arrest is approached. Here we focus on the most direct approach to study these heterogeneities: we identify clusters of slow particles and determine their size, Nc, and their radius of gyration, RG. We show that , providing direct evidence that the most immobile particles arrange in fractal objects with a fractal dimension, df, that is observed to increase with packing fraction ϕ. The cluster size distribution obeys scaling, approaching an algebraic decay in the limit of structural arrest, i.e., ϕ→ϕc. Alternatively, dynamical heterogeneities are analyzed via the four-point structure factor S4(q,t) and the dynamical susceptibility χ4(t). S4(q,t) is shown to obey scaling in the full range of packing fractions, 0.6 ≤ϕ≤ 0.805, and to become increasingly long-ranged as ϕ→ϕc. Finite size scaling of χ4(t) provides a consistency check for the previously analyzed divergences of χ4(t) ∝ (ϕ-ϕc)(-γχ) and the correlation length ξ∝ (ϕ-ϕc)(-γξ). We check the robustness of our results with respect to our definition of mobility. The divergences and the scaling for ϕ→ϕc suggest a non-equilibrium glass transition which seems qualitatively independent of the coefficient of restitution. PMID:27230572

  1. Helioseismology with long-range dark matter-baryon interactions

    SciTech Connect

    Lopes, Ilídio; Panci, Paolo; Silk, Joseph E-mail: panci@iap.fr

    2014-11-10

    Assuming the existence of a primordial asymmetry in the dark sector, we study how long-range dark matter (DM)-baryon interactions, induced by the kinetic mixing of a new U(1) gauge boson and a photon, affect the evolution of the Sun and, in turn, the sound speed the profile obtained from helioseismology. Thanks to the explicit dependence on the exchanged momenta in the differential cross section (Rutherford-like scattering), we find that DM particles with a mass of ∼10 GeV, kinetic mixing parameter of the order of 10{sup –9}, and a mediator with a mass smaller than a few MeV improve the agreement between the best solar model and the helioseismic data without being excluded by direct detection experiments. In particular, the LUX detector will soon be able to either constrain or confirm our best-fit solar model in the presence of a dark sector with long-range interactions that reconcile helioseismology with thermal neutrino results.

  2. Dolphin "packet" use during long-range echolocation tasks.

    PubMed

    Finneran, James J

    2013-03-01

    When echolocating, dolphins typically emit a single broadband "click," then wait to receive the echo before emitting another click. However, previous studies have shown that during long-range echolocation tasks, they may instead emit a burst, or "packet," of several clicks, then wait for the packet of echoes to return before emitting another packet of clicks. The reasons for the use of packets are unknown. In this study, packet use was examined by having trained bottlenose dolphins perform long-range echolocation tasks. The tasks featured "phantom" echoes produced by capturing the dolphin's outgoing echolocation clicks, convolving the clicks with an impulse response to create an echo waveform, and then broadcasting the delayed, scaled echo to the dolphin. Dolphins were trained to report the presence of phantom echoes or a change in phantom echoes. Target range varied from 25 to 800 m. At ranges below 75 m, the dolphins rarely used packets. As the range increased beyond 75 m, two of the three dolphins increasingly produced packets, while the third dolphin instead utilized very high click repetition rates. The use of click packets appeared to be governed more by echo delay (target range) than echo amplitude. PMID:23464048

  3. Long-range response in ac electricity grids

    NASA Astrophysics Data System (ADS)

    Jung, Daniel; Kettemann, Stefan

    2016-07-01

    Local changes in the topology of electricity grids can cause overloads far away from the disturbance [D. Witthaut and M. Timme, Eur. Phys. J. B 86, 377 (2013), 10.1140/epjb/e2013-40469-4], making the prediction of the robustness against changes in the topology—for example, caused by power outages or grid extensions—a challenging task. The impact of single-line additions on the long-range response of dc electricity grids has recently been studied [D. Labavić, R. Suciu, H. Meyer-Ortmanns, and S. Kettemann, Eur. Phys. J.: Spec. Top. 223, 2517 (2014), 10.1140/epjst/e2014-02273-0]. By solving the real part of the static ac load flow equations, we conduct a similar investigation for ac grids. In a regular two-dimensional grid graph with cyclic boundary conditions, we find a power law decay for the change of power flow as a function of distance to the disturbance over a wide range of distances. The power exponent increases and saturates for large system sizes. By applying the same analysis to the German transmission grid topology, we show that also in real-world topologies a long-ranged response can be found.

  4. Helioseismology with Long-range Dark Matter-Baryon Interactions

    NASA Astrophysics Data System (ADS)

    Lopes, Ilídio; Panci, Paolo; Silk, Joseph

    2014-11-01

    Assuming the existence of a primordial asymmetry in the dark sector, we study how long-range dark matter (DM)-baryon interactions, induced by the kinetic mixing of a new U(1) gauge boson and a photon, affect the evolution of the Sun and, in turn, the sound speed the profile obtained from helioseismology. Thanks to the explicit dependence on the exchanged momenta in the differential cross section (Rutherford-like scattering), we find that DM particles with a mass of ~10 GeV, kinetic mixing parameter of the order of 10-9, and a mediator with a mass smaller than a few MeV improve the agreement between the best solar model and the helioseismic data without being excluded by direct detection experiments. In particular, the LUX detector will soon be able to either constrain or confirm our best-fit solar model in the presence of a dark sector with long-range interactions that reconcile helioseismology with thermal neutrino results.

  5. The ORNL Surplus Facilities Management Program Long Range Plan

    SciTech Connect

    Myrick, T.E.

    1984-09-01

    The Surplus Facilities Management Program (SFMP) at Oak Ridge National Laboratory (ORNL) is part of the Department of Energy`s (DOE) National SFMP, administered by the Richland Operations Office. This program was established to provide for the management of DOE surplus radioactively contaminated facilities from the end of their operating life until final facility disposition is completed. As part of this program, the ORNL SFMP oversees some 76 individual surplus facilities, ranging in complexity from abandoned waste storage tanks to large experimental reactors. The ORNL SFMP has prepared this Long Range Plan to outline the long-term management strategy for those facilities included in the program. The primary objective of this plan are to: (1) develop a base of information for each ORNL SFMP facility, (2) conduct preliminary decommissioning analyses to identify feasible alternatives, (3) assess the current and future risk of each facility, (4) establish a priority list for the decommissioning projects, and (5) integrate the individual project costs and schedules into an overall program schedule and cost estimate for the ORNL site. The Long Range Plan also provides an overview of the ORNL SFMP management structure, specifies the decommissioning criteria to be employed, and identifies special technical problems, research and development needs, and special facilities and equipment that may be required for decommissioning operations.

  6. Advanced 3D imaging lidar concepts for long range sensing

    NASA Astrophysics Data System (ADS)

    Gordon, K. J.; Hiskett, P. A.; Lamb, R. A.

    2014-06-01

    Recent developments in 3D imaging lidar are presented. Long range 3D imaging using photon counting is now a possibility, offering a low-cost approach to integrated remote sensing with step changing advantages in size, weight and power compared to conventional analogue active imaging technology. We report results using a Geiger-mode array for time-of-flight, single photon counting lidar for depth profiling and determination of the shape and size of tree canopies and distributed surface reflections at a range of 9km, with 4μJ pulses with a frame rate of 100kHz using a low-cost fibre laser operating at a wavelength of λ=1.5 μm. The range resolution is less than 4cm providing very high depth resolution for target identification. This specification opens up several additional functionalities for advanced lidar, for example: absolute rangefinding and depth profiling for long range identification, optical communications, turbulence sensing and time-of-flight spectroscopy. Future concepts for 3D time-of-flight polarimetric and multispectral imaging lidar, with optical communications in a single integrated system are also proposed.

  7. Long Range Memory and Trends in Model Data

    NASA Astrophysics Data System (ADS)

    Oestvand, L.; Nilsen, T.; Rypdal, K.; Rypdal, M.

    2013-12-01

    Local and global observed temperature records have previously been found to have the property of long range memory (LRM). Some model data sets have also been analyzed, with various results. In this work, new model data for the Northern Hemisphere are analyzed with the wavelet variance analysis (WVA) and maximum likelihood estimation (MLE) method to look for long range memory. The data have a monthly resolution over approximately the last 2000 years. Reconstructed temperature records for the same time period seem to have an oscillation, but it is not yet decided if this oscillation is a significant trend or a natural part of an LRM record. In some of the model data used here, an oscillatory trend seems to be present, and the significance of the amplitude is tested against a null hypothesis that the data are an LRM stochastic process with no trend. In the cases where the trends are significant, the data are detrended by subtracting the estimated trend. The detrended data are then analyzed with WVA and MLE to test for LRM. The method is applied to temperature reconstructions by Mann and Moberg, for comparing the results of the model data to those of the reconstructions.

  8. Importance of closely spaced vertical sampling in delineating chemical and microbiological gradients in groundwater studies

    USGS Publications Warehouse

    Smith, R.L.; Harvey, R.W.; LeBlanc, D.R.

    1991-01-01

    Vertical gradients of selected chemical constituents, bacterial populations, bacterial activity and electron acceptors were investigated for an unconfined aquifer contaminated with nitrate and organic compounds on Cape Cod, Massachusetts, U.S.A. Fifteen-port multilevel sampling devices (MLS's) were installed within the contaminant plume at the source of the contamination, and at 250 and 2100 m downgradient from the source. Depth profiles of specific conductance and dissolved oxygen at the downgradient sites exhibited vertical gradients that were both steep and inversely related. Narrow zones (2-4 m thick) of high N2O and NH4+ concentrations were also detected within the contaminant plume. A 27-fold change in bacterial abundance; a 35-fold change in frequency of dividing cells (FDC), an indicator of bacterial growth; a 23-fold change in 3H-glucose uptake, a measure of heterotrophic activity; and substantial changes in overall cell morphology were evident within a 9-m vertical interval at 250 m downgradient. The existence of these gradients argues for the need for closely spaced vertical sampling in groundwater studies because small differences in the vertical placement of a well screen can lead to incorrect conclusions about the chemical and microbiological processes within an aquifer.Vertical gradients of selected chemical constituents, bacterial populations, bacterial activity and electron acceptors were investigated for an unconfined aquifer contaminated with nitrate and organic compounds on Cape Cod, Massachusetts, USA. Fifteen-port multilevel sampling devices (MLS's) were installed within the contaminant plume at the source of the contamination, and at 250 and 2100 m downgradient from the source. Depth profiles of specific conductance and dissolved oxygen at the downgradient sites exhibited vertical gradients that were both steep and inversely related. Narrow zones (2-4 m thick) of high N2O and NH4+ concentrations were also detected within the contaminant plume

  9. Long-Range Lepton Flavor Interactions and Neutrino Oscillations

    SciTech Connect

    Davoudiasl, H.; Lee, H-S; Marciano, W.

    2011-03-31

    Recent results from the MINOS accelerator neutrino experiment suggest a possible difference between {nu}{sub {mu}} and {bar {nu}}{sub {mu}} disappearance oscillation parameters, which one may ascribe to a new long distance potential acting on neutrinos. As a specific example, we consider a model with gauged B - L{sub e} - 2L{sub {tau}} number which contains an extremely light new vector boson, m{sub Z}, < 10{sup -18} eV and extraordinarily weak coupling {alpha}{prime} {approx}< 10{sup -52}. In that case, differences between {nu}{sub {mu}} {yields} {nu}{sub {tau}} and {bar {nu}}{sub {mu}} {yields} {bar {nu}}{sub {tau}} oscillations can result from a long-range potential due to neutrons in the Earth and the Sun that distinguishes {nu}{sub {mu}} and {nu}{sub {tau}} on Earth, with a potential difference of {approx} 6 x 10{sup -14} eV, and changes sign for anti-neutrinos. We show that existing solar, reactor, accelerator, and atmospheric neutrino oscillation constraints can be largely accommodated for values of parameters that help explain the possible MINOS anomaly by this new physics, although there is some tension with atmospheric constraints. A long-range interaction, consistent with current bounds, could have very pronounced effects on atmospheric neutrino disappearance in the 20-50 GeV range that will be studied with the IceCube DeepCore array, currently in operation, and can have a significant effect on future high-precision long-baseline oscillation experiments which aim for {+-}1% sensitivity, in {nu}{sub {mu}} and {bar {nu}}{sub {mu}} disappearance, separately. Together, these experiments can extend the reach for new long-distance effects well beyond current bounds and test their relevance to the aforementioned MINOS anomaly. We also point out that long-range potentials originating from the Sun could lead to annual modulations of neutrino data at the percent level, due to the variation of the Earth-Sun distance. A similar phenomenology is shown to apply to

  10. Reservoir shore development in long range terrestrial laser scanning monitoring.

    NASA Astrophysics Data System (ADS)

    Kaczmarek, Halina

    2016-04-01

    Shore zones of reservoirs are in most cases very active, getting transformed as a result of coastal processes and mass movements initiated on the slopes surrounding the reservoir. From the point of view of the users of water reservoirs shore recession strongly undesirable as it causes destruction to infrastructure and buildings located in the immediate vicinity of the reservoir. For this reason, reservoir shores require continuous geodetic monitoring. Fast and accurate geodetic measurements covering shore sections several kilometers long, often in poorly accessible areas, are available using long range terrestrial laser scanning (TLS). The possibilities of using long range terrestrial laser scanning are shown on the example of the reservoir Jeziorsko on the Warta River (Central Poland). This reservoir, created in the years 1986-1992, is a typical retention reservoir, the annual fluctuations of which reach 5 m. Depending on the water level its surface area ranges from 42.3 to 19.6 km2. The width of the reservoir is 2.5 km. The total shore length of the reservoir, developed in Quaternary till and sand-till sediments, is 44.3 km, including 30.1 km of the unreinforced shore. Out of the unreinforced shore 27% is subject to coastal erosion. The cliff heights vary from a few cm to 12.5 meters, and the current rate of the cliff recession ranges from 0 to 1.12 m/y. The study used a terrestrial long range laser scanner Riegl VZ-4000 of a range of up to 4000 m. It enabled conducting the measurements of the cliff recession from the opposite shore of the reservoir, with an angular resolution of 0.002°, which gives about 50 measurement points per 1 m2. The measurements were carried out in the years 2014-2015, twice a year, in early spring before high water level, and in late autumn at a dropping water level. This allowed the separation of the impact of coastal processes and frost weathering on the cliff recession and their quantitative determination. The size and nature of

  11. Atmosphere-surface exchange and long-range transport of persistent organic pollutants

    SciTech Connect

    Pul, W.A.J. van; Jaarsveld, J.A. van; Jacobs, C.M.J.

    1996-12-31

    Persistent Organic Pollutants (POPs) are compounds that are resistant to photolytic, biological and chemical degradation. Many POPs are semi-volatile at atmospheric conditions. Because of these characteristics POPs have a atmospheric lifetime of weeks or more and are subject to long-range atmospheric transport. During this transport POPs can be deposited as well as be re-emitted from soil and water bodies. In this study a model for the exchange of POP at the soil and sea surface is presented as well as its application in a long-range atmospheric transport model. The main goal of this study is to simulate the spatial distribution of POP deposition (accumulation) over Europe.

  12. A long-range polarization-controlled optical tractor beam

    NASA Astrophysics Data System (ADS)

    Shvedov, Vladlen; Davoyan, Arthur R.; Hnatovsky, Cyril; Engheta, Nader; Krolikowski, Wieslaw

    2014-11-01

    The laser beam has become an indispensable tool for the controllable manipulation and transport of microscopic objects in biology, physical chemistry and condensed matter physics. In particular, ‘tractor’ laser beams can draw matter towards a laser source and perform, for instance, all-optical remote sampling. Recent advances in lightwave technology have already led to small-scale experimental demonstrations of tractor beams. However, the realization of long-range tractor beams has not gone beyond the realm of theoretical investigations. Here, we demonstrate the stable transfer of gold-coated hollow glass spheres against the power flow of a single inhomogeneously polarized laser beam over tens of centimetres. Additionally, by varying the polarization state of the beam we can stop the spheres or reverse the direction of their motion at will.

  13. Long-range properties of 1 S bottomonium states

    NASA Astrophysics Data System (ADS)

    Brambilla, Nora; Krein, Gastão; Tarrús Castellà, Jaume; Vairo, Antonio

    2016-03-01

    In the framework of weakly coupled potential nonrelativistic QCD, we derive, first, an analytical expression for the chromopolarizability of 1 S bottomonium states in agreement with previous determinations. Then we use the QCD trace anomaly to obtain the two-pion production amplitude for the chromopolarizability operator and match the result to a chiral effective field theory with 1 S bottomonium states and pions as degrees of freedom. In this chiral effective field theory we compute some long-range properties of the 1 S bottomonium generated by the pion coupling such as the leading chiral logarithm to the 1 S bottomonium mass and the van der Waals potential between two 1 S bottomonium states. Both results improve on previously known expressions.

  14. Sparse Labeling of Proteins: Structural Characterization from Long Range Constraints

    PubMed Central

    Prestegard, James H.; Agard, David A.; Moremen, Kelley W.; Lavery, Laura A.; Morris, Laura C.; Pederson, Kari

    2014-01-01

    Structural characterization of biologically important proteins faces many challenges associated with degradation of resolution as molecular size increases and loss of resolution improving tools such as perdeuteration when non-bacterial hosts must be used for expression. In these cases, sparse isotopic labeling (single or small subsets of amino acids) combined with long range paramagnetic constraints and improved computational modeling offer an alternative. This perspective provides a brief overview of this approach and two discussions of potential applications; one involving a very large system (an Hsp90 homolog) in which perdeuteration is possible and methyl-TROSY sequences can potentially be used to improve resolution, and one involving ligand placement in a glycosylated protein where resolution is achieved by single amino acid labeling (the sialyltransferase, ST6Gal1). This is not intended as a comprehensive review, but as a discussion of future prospects that promise impact on important questions in the structural biology area. PMID:24656078

  15. Sparse labeling of proteins: Structural characterization from long range constraints

    NASA Astrophysics Data System (ADS)

    Prestegard, James H.; Agard, David A.; Moremen, Kelley W.; Lavery, Laura A.; Morris, Laura C.; Pederson, Kari

    2014-04-01

    Structural characterization of biologically important proteins faces many challenges associated with degradation of resolution as molecular size increases and loss of resolution improving tools such as perdeuteration when non-bacterial hosts must be used for expression. In these cases, sparse isotopic labeling (single or small subsets of amino acids) combined with long range paramagnetic constraints and improved computational modeling offer an alternative. This perspective provides a brief overview of this approach and two discussions of potential applications; one involving a very large system (an Hsp90 homolog) in which perdeuteration is possible and methyl-TROSY sequences can potentially be used to improve resolution, and one involving ligand placement in a glycosylated protein where resolution is achieved by single amino acid labeling (the sialyltransferase, ST6Gal1). This is not intended as a comprehensive review, but as a discussion of future prospects that promise impact on important questions in the structural biology area.

  16. Superconductivity from a Long-Range Repulsive Interaction

    NASA Astrophysics Data System (ADS)

    Onari, S.; Arita, R.; Kuroki, K.; Aoki, H.

    2006-09-01

    The lattice model with short-range interactions (exemplified by the Hubbard model) is known to exhibit quite different features from those in the electron gas with the long-range Coulomb interaction. In order to explore how they cross over to each other, we have studied an extended Hubbard model which includes repulsions up to the 12th neighbors with the simplified fluctuation exchange (FLEX) approximation for the square lattice. We have found that (i) in the most dilute density region, spin and charge fluctuations become comparable, and s- and p-waves superconductivity become dominant, in agreement with the result for the electron gas by Takada, while (ii) the dominant spin fluctuation and its reflection on dx2-y2 and dxy pairing, both the effect of lattice structure, persists well away (n ≳ 0.2) from the half filling. 2006 American Institute of Physics

  17. Phantom energy mediates a long-range repulsive force.

    PubMed

    Amendola, Luca

    2004-10-29

    Scalar field models with nonstandard kinetic terms have been proposed in the context of k inflation, of Born-Infeld Lagrangians, of phantom energy and, more in general, of low-energy string theory. In general, scalar fields are expected to couple to matter inducing a new interaction. In this Letter I derive the cosmological perturbation equations and the Yukawa correction to gravity for such general models. I find three interesting results: first, when the field behaves as phantom energy (equation of state less than -1), then the coupling strength is negative, inducing a long-range repulsive force; second, the dark-energy field might cluster on astrophysical scales; third, applying the formalism to a Brans-Dicke theory with a general kinetic term it is shown that its Newtonian effects depend on a single parameter that generalizes the Brans-Dicke constant. PMID:15525149

  18. Disrupting long-range polar order with an electric field

    NASA Astrophysics Data System (ADS)

    Guo, Hanzheng; Liu, Xiaoming; Xue, Fei; Chen, Long-Qing; Hong, Wei; Tan, Xiaoli

    2016-05-01

    Electric fields are known to favor long-range polar order through the aligning of electric dipoles in relation to Coulomb's force. Therefore, it would be surprising to observe a disordered polar state induced from an ordered state by electric fields. Here we show such an unusual phenomenon in a polycrystalline oxide where electric fields induce a ferroelectric-to-relaxor phase transition. The nonergodic relaxor phase with disordered dipoles appears as an intermediate state under electric fields during polarization reversal of the ferroelectric phase. Using the phenomenological theory, the underlying mechanism for this unexpected behavior can be attributed to the slow kinetics of the ferroelectric-to-relaxor phase transition, as well as its competition against domain switching during electric reversal. The demonstrated material could also serve as a model system to study the transient stages in first-order phase transitions; the slow kinetics does not require the use of sophisticated ultrafast tools.

  19. Fractional dynamics of coupled oscillators with long-range interaction

    SciTech Connect

    Tarasov, Vasily E.; Zaslavsky, George M.

    2006-06-15

    We consider a one-dimensional chain of coupled linear and nonlinear oscillators with long-range powerwise interaction. The corresponding term in dynamical equations is proportional to 1/|n-m|{sup {alpha}}{sup +1}. It is shown that the equation of motion in the infrared limit can be transformed into the medium equation with the Riesz fractional derivative of order {alpha}, when 0<{alpha}<2. We consider a few models of coupled oscillators and show how their synchronization can appear as a result of bifurcation, and how the corresponding solutions depend on {alpha}. The presence of a fractional derivative also leads to the occurrence of localized structures. Particular solutions for fractional time-dependent complex Ginzburg-Landau (or nonlinear Schroedinger) equation are derived. These solutions are interpreted as synchronized states and localized structures of the oscillatory medium.

  20. Modeling of long range frequency sweeping for energetic particle modes

    SciTech Connect

    Nyqvist, R. M.; Breizman, B. N.

    2013-04-15

    Long range frequency sweeping events are simulated numerically within a one-dimensional, electrostatic bump-on-tail model with fast particle sources and collisions. The numerical solution accounts for fast particle trapping and detrapping in an evolving wave field with a fixed wavelength, and it includes three distinct collisions operators: Drag (dynamical friction on the background electrons), Krook-type collisions, and velocity space diffusion. The effects of particle trapping and diffusion on the evolution of holes and clumps are investigated, and the occurrence of non-monotonic (hooked) frequency sweeping and asymptotically steady holes is discussed. The presented solution constitutes a step towards predictive modeling of frequency sweeping events in more realistic geometries.

  1. Chromatin and epigenetic features of long-range gene regulation

    PubMed Central

    Harmston, Nathan; Lenhard, Boris

    2013-01-01

    The precise regulation of gene transcription during metazoan development is controlled by a complex system of interactions between transcription factors, histone modifications and modifying enzymes and chromatin conformation. Developments in chromosome conformation capture technologies have revealed that interactions between regions of chromatin are pervasive and highly cell-type specific. The movement of enhancers and promoters in and out of higher-order chromatin structures within the nucleus are associated with changes in expression and histone modifications. However, the factors responsible for mediating these changes and determining enhancer:promoter specificity are still not completely known. In this review, we summarize what is known about the patterns of epigenetic and chromatin features characteristic of elements involved in long-range interactions. In addition, we review the insights into both local and global patterns of chromatin interactions that have been revealed by the latest experimental and computational methods. PMID:23766291

  2. Transuranic waste projections at SRS for long range planning

    SciTech Connect

    Hootman, H.E.; Cook, J.R.

    1994-05-01

    This report predicts 30 year receipts of solid transuranic (TRU) wastes from eventual plutonium facility deactivation and cleanup, and combines them with the existing TRU waste holdings to provide a technical and quantitative basis for interim and long range TRU waste management planning. The current TRU waste holdings have been characterized based on data from the Computerized Radioactive Waste Burial Records Analysis (COBRA) system. Six TRU waste disposition categories have been identified for existing TRU waste as shown in Table 1. An additional category has been quantified that includes projected waste volumes from the Decontamination and Decommissioning (D&D) of TRU waste generating facilities. These projections are based on COBRA data from D&D of the original plutonium finishing facilities in F and H Areas that were replaced in the 1970`s and 80`s.

  3. Parallelized Stochastic Cutoff Method for Long-Range Interacting Systems

    NASA Astrophysics Data System (ADS)

    Endo, Eishin; Toga, Yuta; Sasaki, Munetaka

    2015-07-01

    We present a method of parallelizing the stochastic cutoff (SCO) method, which is a Monte-Carlo method for long-range interacting systems. After interactions are eliminated by the SCO method, we subdivide a lattice into noninteracting interpenetrating sublattices. This subdivision enables us to parallelize the Monte-Carlo calculation in the SCO method. Such subdivision is found by numerically solving the vertex coloring of a graph created by the SCO method. We use an algorithm proposed by Kuhn and Wattenhofer to solve the vertex coloring by parallel computation. This method was applied to a two-dimensional magnetic dipolar system on an L × L square lattice to examine its parallelization efficiency. The result showed that, in the case of L = 2304, the speed of computation increased about 102 times by parallel computation with 288 processors.

  4. Position-insensitive long range inductive power transfer

    NASA Astrophysics Data System (ADS)

    Kwan, Christopher H.; Lawson, James; Yates, David C.; Mitcheson, Paul D.

    2014-11-01

    This paper presents results of an improved inductive wireless power transfer system for reliable long range powering of sensors with milliwatt-level consumption. An ultra-low power flyback impedance emulator operating in open loop is used to present the optimal load to the receiver's resonant tank. Transmitter power modulation is implemented in order to maintain constant receiver power and to prevent damage to the receiver electronics caused by excessive received voltage. Received power is steady up to 3 m at around 30 mW. The receiver electronics and feedback system consumes 3.1 mW and so with a transmitter input power of 163.3 W the receiver becomes power neutral at 4.75 m. Such an IPT system can provide a reliable alternative to energy harvesters for supplying power concurrently to multiple remote sensors.

  5. Protein lethality investigated in terms of long range dynamical interactions.

    PubMed

    Rodrigues, Francisco A; Costa, Luciano da Fontoura

    2009-04-01

    The relationship between network structure/dynamics and biological function constitutes a fundamental issue in systems biology. However, despite many related investigations, the correspondence between structure and biological functions is not yet fully understood. A related subject that has deserved particular attention recently concerns how essentiality is related to the structure and dynamics of protein interactions. In the current work, protein essentiality is investigated in terms of long range influences in protein-protein interaction networks by considering simulated dynamical aspects. This analysis is performed with respect to outward activations, an approach which models the propagation of interactions between proteins by considering self-avoiding random walks. The obtained results are compared to protein local connectivity. Both the connectivity and the outward activations were found to be strongly related to protein essentiality. PMID:19396375

  6. Long-Range Spin Transfer in Triple Quantum Dots

    NASA Astrophysics Data System (ADS)

    Sánchez, R.; Granger, G.; Gaudreau, L.; Kam, A.; Pioro-Ladrière, M.; Studenikin, S. A.; Zawadzki, P.; Sachrajda, A. S.; Platero, G.

    2014-05-01

    Tunneling in a quantum coherent structure is not restricted to only nearest neighbors. Hopping between distant sites is possible via the virtual occupation of otherwise avoided intermediate states. Here we report the observation of long-range transitions in the transport through three quantum dots coupled in series. A single electron is delocalized between the left and right quantum dots, while the center one remains always empty. Superpositions are formed, and both charge and spin are exchanged between the outermost dots. The delocalized electron acts as a quantum bus transferring the spin state from one end to the other. Spin selection is enabled by spin correlations. The process is detected via the observation of narrow resonances which are insensitive to Pauli spin blockade.

  7. Long-range spin transfer in triple quantum dots.

    PubMed

    Sánchez, R; Granger, G; Gaudreau, L; Kam, A; Pioro-Ladrière, M; Studenikin, S A; Zawadzki, P; Sachrajda, A S; Platero, G

    2014-05-01

    Tunneling in a quantum coherent structure is not restricted to only nearest neighbors. Hopping between distant sites is possible via the virtual occupation of otherwise avoided intermediate states. Here we report the observation of long-range transitions in the transport through three quantum dots coupled in series. A single electron is delocalized between the left and right quantum dots, while the center one remains always empty. Superpositions are formed, and both charge and spin are exchanged between the outermost dots. The delocalized electron acts as a quantum bus transferring the spin state from one end to the other. Spin selection is enabled by spin correlations. The process is detected via the observation of narrow resonances which are insensitive to Pauli spin blockade. PMID:24836266

  8. Long-Range Correlations of Global Sea Surface Temperature.

    PubMed

    Jiang, Lei; Zhao, Xia; Wang, Lu

    2016-01-01

    Scaling behaviors of the global monthly sea surface temperature (SST) derived from 1870-2009 average monthly data sets of Hadley Centre Sea Ice and SST (HadISST) are investigated employing detrended fluctuation analysis (DFA). The global SST fluctuations are found to be strong positively long-range correlated at all pertinent time-intervals. The value of scaling exponent is larger in the tropics than those in the intermediate latitudes of the northern and southern hemispheres. DFA leads to the scaling exponent α = 0.87 over the globe (60°S~60°N), northern hemisphere (0°N~60°N), and southern hemisphere (0°S~60°S), α = 0.84 over the intermediate latitude of southern hemisphere (30°S~60°S), α = 0.81 over the intermediate latitude of northern hemisphere (30°N~60°N) and α = 0.90 over the tropics 30°S~30°N [fluctuation F(s) ~ sα], which the fluctuations of monthly SST anomaly display long-term correlated behaviors. Furthermore, the larger the standard deviation is, the smaller long-range correlations (LRCs) of SST in the corresponding regions, especially in three distinct upwelling areas. After the standard deviation is taken into account, an index χ = α * σ is introduced to obtain the spatial distributions of χ. There exists an obvious change of global SST in central east and northern Pacific and the northwest Atlantic. This may be as a clue on predictability of climate and ocean variabilities. PMID:27100397

  9. Long-range energy transport in photosystem II

    NASA Astrophysics Data System (ADS)

    Roden, Jan J. J.; Bennett, Doran I. G.; Whaley, K. Birgitta

    2016-06-01

    We simulate the long-range inter-complex electronic energy transfer in photosystem II - from the antenna complex, via a core complex, to the reaction center - using a non-Markovian (ZOFE) quantum master equation description that allows the electronic coherence involved in the energy transfer to be explicitly included at all length scales. This allows us to identify all locations where coherence is manifested and to further identify the pathways of the energy transfer in the full network of coupled chromophores using a description based on excitation probability currents. We investigate how the energy transfer depends on the initial excitation - localized, coherent initial excitation versus delocalized, incoherent initial excitation - and find that the overall energy transfer is remarkably robust with respect to such strong variations of the initial condition. To explore the importance of vibrationally enhanced transfer and to address the question of optimization in the system parameters, we systematically vary the strength of the coupling between the electronic and the vibrational degrees of freedom. We find that the natural parameters lie in a (broad) region that enables optimal transfer efficiency and that the overall long-range energy transfer on a ns time scale appears to be very robust with respect to variations in the vibronic coupling of up to an order of magnitude. Nevertheless, vibrationally enhanced transfer appears to be crucial to obtain a high transfer efficiency, with the latter falling sharply for couplings outside the optimal range. Comparison of our full quantum simulations to results obtained with a "classical" rate equation based on a modified-Redfield/generalized-Förster description previously used to simulate energy transfer dynamics in the entire photosystem II complex shows good agreement for the overall time scales of excitation energy transport.

  10. Photoassociation of long-range nD Rydberg molecules

    NASA Astrophysics Data System (ADS)

    Raithel, Georg

    2015-05-01

    Cold atomic systems have opened new frontiers at the interface of atomic and molecular physics. Of particular interest are a recently discovered class of long-range, homonuclear Rydberg molecules first predicted in and observed in. In rubidium, these molecules are formed via low-energy electron scattering of the Rydberg electron from a 5S1/2 ground-state atom that is present within the Rydberg atom's volume. The binding mostly arises from S-wave and P-wave triplet scattering. In recent work, we have observed long-range homonuclear diatomic nD Rydberg molecules photoassociated out of an ultracold gas of 87Rb atoms for principal quantum numbers 34 <= n <= 40. Related results have also been reported in. The measured ground-state binding energies of 87Rb(nD + 5S1 / 2) molecular states are larger than those of their 87Rb(nS + 5S1 / 2) counterparts, showing the dependence of the molecular bond on the angular momentum of the Rydberg atom. We have exhibited the transition of 87Rb(nD + 5S1 / 2) molecules from a molecular-binding-dominant regime at low n to a fine-structure-dominant regime at high n [akin to Hund's cases (a) and (c), respectively]. In our analysis, we use a Fermi model that includes S-wave and P-wave singlet and triplet scattering, the fine structure coupling of the Rydberg atom and the hyperfine structure coupling of the 5S1/2 atom. The hyperfine structure is important because it gives rise to mixed singlet-triplet potentials. This work was supported by the AFOSR (FA9550-10-1-0453) and the NSF (PHY-1205559).

  11. Long-Range Correlations of Global Sea Surface Temperature

    PubMed Central

    Jiang, Lei; Zhao, Xia; Wang, Lu

    2016-01-01

    Scaling behaviors of the global monthly sea surface temperature (SST) derived from 1870–2009 average monthly data sets of Hadley Centre Sea Ice and SST (HadISST) are investigated employing detrended fluctuation analysis (DFA). The global SST fluctuations are found to be strong positively long-range correlated at all pertinent time-intervals. The value of scaling exponent is larger in the tropics than those in the intermediate latitudes of the northern and southern hemispheres. DFA leads to the scaling exponent α = 0.87 over the globe (60°S~60°N), northern hemisphere (0°N~60°N), and southern hemisphere (0°S~60°S), α = 0.84 over the intermediate latitude of southern hemisphere (30°S~60°S), α = 0.81 over the intermediate latitude of northern hemisphere (30°N~60°N) and α = 0.90 over the tropics 30°S~30°N [fluctuation F(s) ~ sα], which the fluctuations of monthly SST anomaly display long-term correlated behaviors. Furthermore, the larger the standard deviation is, the smaller long-range correlations (LRCs) of SST in the corresponding regions, especially in three distinct upwelling areas. After the standard deviation is taken into account, an index χ = α * σ is introduced to obtain the spatial distributions of χ. There exists an obvious change of global SST in central east and northern Pacific and the northwest Atlantic. This may be as a clue on predictability of climate and ocean variabilities. PMID:27100397

  12. Bacteria are not too small for spatial sensing of chemical gradients: An experimental evidence

    PubMed Central

    Thar, Roland; Kühl, Michael

    2003-01-01

    By analyzing the chemotactic behavior of a recently described marine bacterial species, we provide experimental evidence that bacteria are not too small for sensing chemical gradients spatially. The bipolar flagellated vibrioid bacteria (typical size 2 × 6 μm) exhibit a unique motility pattern as they translate along as well as rotate around their short axis, i.e., the pathways of the cell poles describe a double helix. The natural habitat of the bacteria is characterized by steep oxygen gradients where they accumulate in a band at their preferred oxygen concentration of ≈2 μM. Single cells leaving the band toward the oxic region typically return to the band within 16 s following a U-shaped track. A detailed analysis of the tracks reveals that the cells must be able to sense the oxygen gradient perpendicular to their swimming direction. Thus, they can detect oxygen gradients along a distance of ≈5 μm corresponding to the extension of their long axis. The observed behavior can be explained by the presence of two independent sensor regions at either cell pole that modulate the rotation speed of the polar flagellar bundles, i.e., the flagellar bundle at the cell pole exposed to higher oxygen concentration is rotating faster than the other bundle. A mathematical model based on these assumptions reproduces the observed swimming behavior of the bacteria. PMID:12719518

  13. Meteorological effects on long-range outdoor sound propagation

    NASA Technical Reports Server (NTRS)

    Klug, Helmut

    1990-01-01

    Measurements of sound propagation over distances up to 1000 m were carried out with an impulse sound source offering reproducible, short time signals. Temperature and wind speed at several heights were monitored simultaneously; the meteorological data are used to determine the sound speed gradients according to the Monin-Obukhov similarity theory. The sound speed profile is compared to a corresponding prediction, gained through the measured travel time difference between direct and ground reflected pulse (which depends on the sound speed gradient). Positive sound speed gradients cause bending of the sound rays towards the ground yielding enhanced sound pressure levels. The measured meteorological effects on sound propagation are discussed and illustrated by ray tracing methods.

  14. Multicomponent diffusion under general chemical potential gradients. Final report, July 1, 1981-June 30, 1984

    SciTech Connect

    Sato, H.; Kikuchi, R.

    1984-06-01

    Theoretical basis for identifying the origin of deterioration of high temperature materials by diffusion has been sought. The need for an appropriate form of irreversible statistical mechanics, rather than commonly utilized irreversible thermodynamics, to this problem was identified. The Path Probability method of irreversible statistical mechanics was thus adapted to diffusion problems and necessary modifications of the method suitable for transport problems in multicomponent systems were made. Thermal diffusion (diffusion which occurs under temperature gradient) was then formulated by the Path Probability method for the first time, and so far elusive concepts such as the heat of transport were thus microscopically identified. An example of demixing of originally homogeneous solid solutions under general chemical potential gradients was thus worked out.

  15. In-flight sleep, pilot fatigue and Psychomotor Vigilance Task performance on ultra-long range versus long range flights.

    PubMed

    Gander, Philippa H; Signal, T Leigh; van den Berg, Margo J; Mulrine, Hannah M; Jay, Sarah M; Jim Mangie, Captain

    2013-12-01

    This study evaluated whether pilot fatigue was greater on ultra-long range (ULR) trips (flights >16 h on 10% of trips in a 90-day period) than on long range (LR) trips. The within-subjects design controlled for crew complement, pattern of in-flight breaks, flight direction and departure time. Thirty male Captains (mean age = 54.5 years) and 40 male First officers (mean age = 48.0 years) were monitored on commercial passenger flights (Boeing 777 aircraft). Sleep was monitored (actigraphy, duty/sleep diaries) from 3 days before the first study trip to 3 days after the second study trip. Karolinska Sleepiness Scale, Samn-Perelli fatigue ratings and a 5-min Psychomotor Vigilance Task were completed before, during and after every flight. Total sleep in the 24 h before outbound flights and before inbound flights after 2-day layovers was comparable for ULR and LR flights. All pilots slept on all flights. For each additional hour of flight time, they obtained an estimated additional 12.3 min of sleep. Estimated mean total sleep was longer on ULR flights (3 h 53 min) than LR flights (3 h 15 min; P(F) = 0.0004). Sleepiness ratings were lower and mean reaction speed was faster at the end of ULR flights. Findings suggest that additional in-flight sleep mitigated fatigue effectively on longer flights. Further research is needed to clarify the contributions to fatigue of in-flight sleep versus time awake at top of descent. The study design was limited to eastward outbound flights with two Captains and two First Officers. Caution must be exercised when extrapolating to different operations. PMID:23889686

  16. Describing long-range charge-separation processes with subsystem density-functional theory

    SciTech Connect

    Solovyeva, Alisa; Neugebauer, Johannes; Pavanello, Michele

    2014-04-28

    Long-range charge-transfer processes in extended systems are difficult to describe with quantum chemical methods. In particular, cost-effective (non-hybrid) approximations within time-dependent density functional theory (DFT) are not applicable unless special precautions are taken. Here, we show that the efficient subsystem DFT can be employed as a constrained DFT variant to describe the energetics of long-range charge-separation processes. A formal analysis of the energy components in subsystem DFT for such excitation energies is presented, which demonstrates that both the distance dependence and the long-range limit are correctly described. In addition, electronic couplings for these processes as needed for rate constants in Marcus theory can be obtained from this method. It is shown that the electronic structure of charge-separated states constructed by a positively charged subsystem interacting with a negatively charged one is difficult to converge — charge leaking from the negative subsystem to the positive one can occur. This problem is related to the delocalization error in DFT and can be overcome with asymptotically correct exchange–correlation (XC) potentials or XC potentials including a sufficiently large amount of exact exchange. We also outline an approximate way to obtain charge-transfer couplings between locally excited and charge-separated states.

  17. Neural network analysis of long-range precipitation forecasts

    NASA Astrophysics Data System (ADS)

    Silverman, David I.

    The object of this research is to show that long range forecasts of precipitation for California is possible using large-scale climatological indexes and that artificial neural networks (ANNs) are a viable tool for modeling and data extraction. For each of California's seven climate zones, ANNs were trained using a calendar year's input of parameters to predict the coming water year's total precipitation and to predict the following water year's. Activity by the El Niño-Southern Oscillation (ENSO) in the east Pacific and the 700 mb height anomaly over the northern hemisphere is known to be related to various phenomena in specific regions of California. These large-scale climatological parameters represent the global atmospheric circulation that, in a sense, bring the weather to a region. By determining how these parameters interact over time, we can determine the general weather conditions that will arrive in a region. Because of the large amount of data, the short time period the data covers, the unknown type of relationships involved, and the possibly extraneous data, common statistical methods are not easily applied. Artificial neural networks (ANNs) are powerful and useful tools, especially in cases where the complex relationship between the inputs and outputs cannot easily be determined by common modeling methods. 0It was found that the pattern of rainfall predicted by the ANN model matched closely the observed rainfall with the nine month time lag for most California climate zones and for most years. This portion of the research shows the possibility of making long range forecasts using ANNs and large scale climatological parameters. These artificial ``brains'' were then analyzed by two different methods to reveal their methods of forecasting. One method produced for each climate zone a reduced set of important global parameters that were used in a simple linear regression model with good results. The second method gave information about how the individual

  18. Long Range Chiral Imprinting of Cu(110) by Tartaric Acid

    SciTech Connect

    Lawton, T J; Pushkarev, V; Wei, D; Lucci, F R; Sholl, D S; Gellman, A J; Sykes, E C. H.

    2013-10-31

    Restructuring of metals by chiral molecules represents an important route to inducing and controlling enantioselective surface chemistry. Tartaric acid adsorption on Cu(110) has served as a useful system for understanding many aspects of chiral molecule adsorption and ordering on a metal surface, and a number of chiral and achiral unit cells have been reported. Herein, we show that given the appropriate annealing treatment, singly deprotonated tartaric acid monolayers can restructure the Cu metal itself, and that the resulting structure is both highly ordered and chiral. Molecular resolution scanning tunneling microscopy reveals that singly deprotonated tartaric acid extracts Cu atoms from the Cu(110) surface layer and incorporates them into highly ordered, chiral adatom arrays capped by a continuous molecular layer. Further evidence for surface restructuring comes from images of atom-deep trenches formed in the Cu(110) surface during the process. These trenches also run in low symmetry directions and are themselves chiral. Simulated scanning tunneling microscopy images are consistent with the appearance of the added atom rows and etched trenches. The chiral imprinting results in a long-range, highly ordered unit cell covering the whole surface as confirmed by low energy electron diffraction. Details of the restructuring mechanism were further investigated via time-lapse imaging at elevated temperature. This work reveals the stages of nanoscale surface restructuring and offers an interesting method for chiral modification of an achiral metal surface.

  19. Ultracold Long-Range Rydberg Molecules with Complex Multichannel Spectra

    NASA Astrophysics Data System (ADS)

    Eiles, Matthew; Greene, Chris

    2016-05-01

    A generalized class of exotic long-range Rydberg molecules consisting of a multichannel Rydberg atom bound to a distant ground state atom by the Rydberg electron is predicted. These molecules are characterized by the rich physics provided by the strongly perturbed multichannel Rydberg spectra of divalent atoms, in contrast to the regular Rydberg series of the alkali atoms used to form Rydberg molecules to date. These multichannel Rydberg molecules exhibit favorable properties for laser excitation, because states exist where the quantum defect varies strongly with the principal quantum number n. In particular, the nd Rydberg state of calcium becomes nearly degenerate with states of high orbital angular momentum over the range 17 < n < 22 , promoting its admixture into the high l deeply bound ``trilobite'' molecule states and thereby circumventing the usual difficulty posed by electric dipole selection rules. Further novel molecular states are predicted to occur in the low- J states of silicon, which are strongly perturbed due to channel interactions between Rydberg series leading to the spin-orbit split ionization thresholds. These interactions manifest themselves in potential curves exhibiting two distinct length scales, providing novel opportunities for quantum manipulation. Supported in part by the National Science Foundation under Grant No. PHY-1306905.

  20. Metrological capabilities of Scanning Long Range Doppler Lidars

    NASA Astrophysics Data System (ADS)

    Loaec, Sophie; Boquet, Matthieu; Cariou, Jean-Pierre

    2013-04-01

    Many application areas are interested in getting wind measurements within the Planetary Boundary Layer (PBL) height, and with a relatively high accuracy. These applications include meteorology like PBL studies, air traffic safety like aircraft induced wake vortices and wind shears detection or wind farming like wind resources assessment. In order to answer these demands there are recent developments and deployments of long-range vertical profiler or fully hemispherical scanning wind lidars. To validate the measurements provided by such a system, it is possible to make inter-comparisons with a met mast at short distance and with wind profilers radar or sodar at longer distance. But, there are difficulties that may arise from the implementation of this kind of methodology because of the uncertainty related to the campaign set-up and the instruments used as reference. In that perspective Leosphere is developing a method to assess the accuracy of the Leosphere's lidars. In this presentation, we will give a detail description of the method and its results.

  1. Long-range forecasts of UK winter hydrology

    NASA Astrophysics Data System (ADS)

    Svensson, C.; Brookshaw, A.; Scaife, A. A.; Bell, V. A.; Mackay, J. D.; Jackson, C. R.; Hannaford, J.; Davies, H. N.; Arribas, A.; Stanley, S.

    2015-06-01

    Seasonal river flow forecasts are beneficial for planning agricultural activities, river navigation, and for management of reservoirs for public water supply and hydropower generation. In the United Kingdom (UK), skilful seasonal river flow predictions have previously been limited to catchments in lowland (southern and eastern) regions. Here we show that skilful long-range forecasts of winter flows can now be achieved across the whole of the UK. This is due to a remarkable geographical complementarity between the regional geological and meteorological sources of predictability for river flows. Forecast skill derives from the hydrogeological memory of antecedent conditions in southern and eastern parts of the UK and from meteorological predictability in northern and western areas. Specifically, it is the predictions of the atmospheric circulation over the North Atlantic that provides the skill at the seasonal timescale. In addition, significant levels of skill in predicting the frequency of winter high flow events is demonstrated, which has the potential to allow flood adaptation measures to be put in place.

  2. Long range metrological atomic force microscope with versatile measuring head

    NASA Astrophysics Data System (ADS)

    Lu, Mingzhen; Gao, Sitian; Li, Qi; Li, Wei; Shi, Yushu; Tao, Xingfu

    2013-01-01

    A long range metrological atomic force microscope (AFM) has been developed at NIM. It aims to realize a maximum measurement volume of 50mm×50mm×2mm with an uncertainty of a few tens of nanometers in the whole range. In compliance with Abbe Principle, the instrument is designed as a sample-scanning type. The sample is moved by a 6-DOF piezostage in combination with a hybrid slide-air bearing stage for long scanning range. Homodyne interferometers with four passes attached to a metrological frame measure relative displacement between the probe and sample thus the instrument is directly traceable to the SI. An AFM head is developed as the measuring head for the instrument. Considering accuracy and dynamic performance of the instrument, it is designed to be capable of scanning perpendicularly in a range of 5μm×5μm×5μm with a 3-DOF piezostage. Optical beam deflection method is used and a minimum of components are mounted on the moving part. A novel design is devised so that the photodetector is only sensitive to the deflection of cantilever, but not the displacement of the head. Moving manner of the head varies with scanning range and mode of the instrument. Results of different measurements are demonstrated, showing the excellent performance of the instrument.

  3. Stochastic Kinetic Monte Carlo algorithms for long-range Hamiltonians

    SciTech Connect

    Mason, D R; Rudd, R E; Sutton, A P

    2003-10-13

    We present a higher order kinetic Monte Carlo methodology suitable to model the evolution of systems in which the transition rates are non- trivial to calculate or in which Monte Carlo moves are likely to be non- productive flicker events. The second order residence time algorithm first introduced by Athenes et al.[1] is rederived from the n-fold way algorithm of Bortz et al.[2] as a fully stochastic algorithm. The second order algorithm can be dynamically called when necessary to eliminate unproductive flickering between a metastable state and its neighbors. An algorithm combining elements of the first order and second order methods is shown to be more efficient, in terms of the number of rate calculations, than the first order or second order methods alone while remaining statistically identical. This efficiency is of prime importance when dealing with computationally expensive rate functions such as those arising from long- range Hamiltonians. Our algorithm has been developed for use when considering simulations of vacancy diffusion under the influence of elastic stress fields. We demonstrate the improved efficiency of the method over that of the n-fold way in simulations of vacancy diffusion in alloys. Our algorithm is seen to be an order of magnitude more efficient than the n-fold way in these simulations. We show that when magnesium is added to an Al-2at.%Cu alloy, this has the effect of trapping vacancies. When trapping occurs, we see that our algorithm performs thousands of events for each rate calculation performed.

  4. Long-range magnetic coupling across a polar insulating layer.

    PubMed

    Lü, W M; Saha, Surajit; Wang, X Renshaw; Liu, Z Q; Gopinadhan, K; Annadi, A; Zeng, S W; Huang, Z; Bao, B C; Cong, C X; Venkatesan, M; Yu, T; Coey, J M D; Ariando; Venkatesan, T

    2016-01-01

    Magnetic interactions in solids are normally mediated by short-range exchange or weak dipole fields. Here we report a magnetic interaction that can propagate over long distances (∼10 nm) across a polar insulating oxide spacer. Evidence includes oscillations of magnetization, coercivity and field-cooled loop shift with the thickness of LaAlO3 in La0.67Sr0.33MnO3/LaAlO3/SrTiO3 heterostructures. Similar modifications of the hysteresis loop appear when two coupled films of La0.67Sr0.33MnO3 are separated by LaAlO3, or another polar insulator, but they are absent when the oxide spacer layer is nonpolar. The loop shift is attributed to strong spin-orbit coupling and Dzyaloshinskii-Moriya interaction at the interfaces. There is evidence from inelastic light scattering that the polar spacer mediates long-range transmission of orbital magnetization. This coupling mechanism is expected to apply for any conducting ferromagnetic oxide with mixed valence; in view of electron hopping frequency involved, it raises the prospect of terahertz tunability of magnetic coupling. PMID:26980456

  5. On long-range forces of repulsion between biological cells

    NASA Astrophysics Data System (ADS)

    Derjaguin, B. V.; Golovanov, M. V.

    1992-05-01

    We have established experimentally that when biological cells, for example, blood, are suspended in concentrated solutions of inorganic electrolytes (for instance, in a 15% solution of sodium chloride) then around some cells (leucocytes, especially tumour cells) there form haloes, i.e., circular spaces free from background cells (erythrocytes, yeast cells, colloidal particles of Indian ink). In the medium made up of erythrocytes the haloes form during 5-10 min as a result of the background cells drawing apart from the central halo-forming cell (HFC) at a distance of 10-100 μm and more. In the medium made of the Indian ink particles, the haloes form during 2-4 s and attain a thickness of about 10-20 μm. The erythrocytes and the haloes forming in their medium can be preserved for about three to five days at room temperature. It has been established that, when tumour HFCs are present at sufficient concentrations, they form hexagonal periodic structures having a mean spacing between cells of up to 60 μm. The authors put forward as one probable suggestion that the formation of haloes is largely determined by long-range repulsive forces arising from the phenomenon of diffusiophoresis generated by the diffusion currents that emerge from the surface of halo-forming cells.

  6. ORNL long-range environmental and waste management plan

    SciTech Connect

    Baldwin, J.S.; Bates, L.D.; Brown, C.H.; Easterday, C.A.; Hill, L.G.; Kendrick, C.M.; McNeese, L.E.; Myrick, T.E.; Payne, T.L.; Pepper, C.E.; Robinson, S.M.; Rohwer, P.S.; Scanlan, T.F.; Smith, M.A.; Stratton, L.E.; Trabalka, J.R.

    1989-09-01

    This report, the ORNL Long-Range Environmental and Waste Management Plan, is the annual update in a series begun in fiscal year 1985. Its primary purpose is to provide a thorough and systematic planning document to reflect the continuing process of site assessment, strategy development, and planning for the current and long-term control of environmental issues, waste management practices, and remedial action requirements. The document also provides an estimate of the resources required to implement the current plan. This document is not intended to be a budget document; it is, however, intended to provide guidance to both Martin Marietta Energy Systems, Inc., and the US Department of Energy (DOE) management as to the near order of magnitude of the resources (primarily funding requirements) and the time frame required to execute the strategy in the present revision of the plan. As with any document of this nature, the near-term (one to three years) part of the plan is a pragmatic assessment of the current program and ongoing capital projects and reflects the efforts perceived to be necessary to comply with all current state and federal regulations and DOE orders. It also should be in general agreement with current budget (funding) requests and obligations for these immediate years. 55 figs., 72 tabs.

  7. Long-range magnetic coupling across a polar insulating layer

    PubMed Central

    Lü, W. M.; Saha, Surajit; Wang, X. Renshaw; Liu, Z. Q.; Gopinadhan, K.; Annadi, A.; Zeng, S. W.; Huang, Z.; Bao, B. C.; Cong, C. X.; Venkatesan, M.; Yu, T.; Coey, J. M. D.; Ariando; Venkatesan, T.

    2016-01-01

    Magnetic interactions in solids are normally mediated by short-range exchange or weak dipole fields. Here we report a magnetic interaction that can propagate over long distances (∼10 nm) across a polar insulating oxide spacer. Evidence includes oscillations of magnetization, coercivity and field-cooled loop shift with the thickness of LaAlO3 in La0.67Sr0.33MnO3/LaAlO3/SrTiO3 heterostructures. Similar modifications of the hysteresis loop appear when two coupled films of La0.67Sr0.33MnO3 are separated by LaAlO3, or another polar insulator, but they are absent when the oxide spacer layer is nonpolar. The loop shift is attributed to strong spin–orbit coupling and Dzyaloshinskii–Moriya interaction at the interfaces. There is evidence from inelastic light scattering that the polar spacer mediates long-range transmission of orbital magnetization. This coupling mechanism is expected to apply for any conducting ferromagnetic oxide with mixed valence; in view of electron hopping frequency involved, it raises the prospect of terahertz tunability of magnetic coupling. PMID:26980456

  8. Two general models that generate long range correlation

    NASA Astrophysics Data System (ADS)

    Gan, Xiaocong; Han, Zhangang

    2012-06-01

    In this paper we study two models that generate sequences with LRC (long range correlation). For the IFT (inverse Fourier transform) model, our conclusion is the low frequency part leads to LRC, while the high frequency part tends to eliminate it. Therefore, a typical method to generate a sequence with LRC is multiplying the spectrum of a white noise sequence by a decaying function. A special case is analyzed: the linear combination of a smooth curve and a white noise sequence, in which the DFA plot consists of two line segments. For the patch model, our conclusion is long subsequences leads to LRC, while short subsequences tend to eliminate it. Therefore, we can generate a sequence with LRC by using a fat-tailed PDF (probability distribution function) of the length of the subsequences. A special case is also analyzed: if a patch model with long subsequences is mixed with a white noise sequence, the DFA plot will consist of two line segments. We have checked known models and actual data, and found they are all consistent with this study.

  9. Long range transport of colloids in aqueous solutions

    NASA Astrophysics Data System (ADS)

    Florea, Daniel; Musa, Sami; Huyghe, Jacques M. R. J.; Wyss, Hans M.

    2013-03-01

    Colloids in aqueous suspensions can experience strong, extremely long range repulsive forces near interfaces such as biological tissues, gels, ion exchange resins or metals. As a result exclusion zones extending over several millimeters can be formed. While this phenomenon has been previously described, a physical understanding of this process is still lacking. This exclusion zone formation is puzzling because the typical forces acting on colloidal particles are limited to much shorter distances and external fields that could drive the particles are absent. Here we study the exclusion zone formation in detail by following the time and distance-dependent forces acting on the particles. We present a simple model that accounts for our experimental data and directly links the exclusion zone formation to an already known physical transport phenomenon. We show that the effect can be tuned by changing the zeta potential of the particles or by varying the species present in the aqueous solution. We thus provide a direct physical explanation for the intriguing exclusion zone formation and we illustrate how this effect can be exploited in a range of industrial applications.

  10. Long-range position and orientation tracking system

    SciTech Connect

    Armstrong, G.A.; Jansen, J.F.; Burks, B.L.

    1995-12-31

    The long-range position and orientation tracking system will consist of two measurement pods, a VME-based computer system, and a detector array. The system is used to measure the position and orientation of a target that may be attached to a robotic arm, teleoperated manipulator, or autonomous vehicle. The pods have been designed to be mounted in the manways of the domes of the Fernald K-65 waste silos. Each pod has two laser scanner subsystems as well as lights and camera systems. One of the laser scanners will be oriented to scan in the pan direction, the other in the tilt direction. As the lasers scan across the detector array, the angles of incidence with each detector are recorded. Combining measurements from each of the four lasers yields sufficient data for a closed-form solution of the transform describing the location and orientation of the content mobilization system (CMS). Redundant detectors will be placed on the CMS to accommodate occlusions, to provide improved measurement accuracy, and to determine the CMS orientation.

  11. Measured long-range repulsive Casimir–Lifshitz forces

    PubMed Central

    Munday, J. N.; Capasso, Federico; Parsegian, V. Adrian

    2014-01-01

    Quantum fluctuations create intermolecular forces that pervade macroscopic bodies1–3. At molecular separations of a few nanometres or less, these interactions are the familiar van der Waals forces4. However, as recognized in the theories of Casimir, Polder and Lifshitz5–7, at larger distances and between macroscopic condensed media they reveal retardation effects associated with the finite speed of light. Although these long-range forces exist within all matter, only attractive interactions have so far been measured between material bodies8–11. Here we show experimentally that, in accord with theoretical prediction12, the sign of the force can be changed from attractive to repulsive by suitable choice of interacting materials immersed in a fluid. The measured repulsive interaction is found to be weaker than the attractive. However, in both cases the magnitude of the force increases with decreasing surface separation. Repulsive Casimir–Lifshitz forces could allow quantum levitation of objects in a fluid and lead to a new class of switchable nanoscale devices with ultra-low static friction13–15. PMID:19129843

  12. Using light to shape chemical gradients for parallel and automated analysis of chemotaxis

    PubMed Central

    Collins, Sean R; Yang, Hee Won; Bonger, Kimberly M; Guignet, Emmanuel G; Wandless, Thomas J; Meyer, Tobias

    2015-01-01

    Numerous molecular components have been identified that regulate the directed migration of eukaryotic cells toward sources of chemoattractant. However, how the components of this system are wired together to coordinate multiple aspects of the response, such as directionality, speed, and sensitivity to stimulus, remains poorly understood. Here we developed a method to shape chemoattractant gradients optically and analyze cellular chemotaxis responses of hundreds of living cells per well in 96-well format by measuring speed changes and directional accuracy. We then systematically characterized migration and chemotaxis phenotypes for 285 siRNA perturbations. A key finding was that the G-protein Giα subunit selectively controls the direction of migration while the receptor and Gβ subunit proportionally control both speed and direction. Furthermore, we demonstrate that neutrophils chemotax persistently in response to gradients of fMLF but only transiently in response to gradients of ATP. The method we introduce is applicable for diverse chemical cues and systematic perturbations, can be used to measure multiple cell migration and signaling parameters, and is compatible with low- and high-resolution fluorescence microscopy. PMID:25908733

  13. Vortex flows with suspended separation regions and long-range untwisted central jets

    SciTech Connect

    Abramovich, G.N.; Trofimov, R.S.

    1988-05-01

    A study is made of possible physicoaerodynamic configurations of vortical flow with suspended separation regions and untwisted central jets. Such flows are encountered in power plants (heat exchangers, combustion chambers, and chemical reactors) and in nature (tornadoes). The basic configurations of several flows of this type are described, including the structure of a flow formed by coaxial cocurrent twisted jets, the flow in a conical swirl chamber with the formation of an untwisted long-range axial jet, the flow pattern in a gas turbine engine chamber, and some considerations regarding the aerodynamics of a tornado.

  14. Long range laser propagation: power scaling and beam quality issues

    NASA Astrophysics Data System (ADS)

    Bohn, Willy L.

    2010-09-01

    This paper will address long range laser propagation applications where power and, in particular beam quality issues play a major role. Hereby the power level is defined by the specific mission under consideration. I restrict myself to the following application areas: (1)Remote sensing/Space based LIDAR, (2) Space debris removal (3)Energy transmission, and (4)Directed energy weapons Typical examples for space based LIDARs are the ADM Aeolus ESA mission using the ALADIN Nd:YAG laser with its third harmonic at 355 nm and the NASA 2 μm Tm:Ho:LuLiF convectively cooled solid state laser. Space debris removal has attracted more attention in the last years due to the dangerous accumulation of debris in orbit which become a threat to the satellites and the ISS space station. High power high brightness lasers may contribute to this problem by partially ablating the debris material and hence generating an impulse which will eventually de-orbit the debris with their subsequent disintegration in the lower atmosphere. Energy transmission via laser beam from space to earth has long been discussed as a novel long term approach to solve the energy problem on earth. In addition orbital transfer and stationkeeping are among the more mid-term applications of high power laser beams. Finally, directed energy weapons are becoming closer to reality as corresponding laser sources have matured due to recent efforts in the JHPSSL program. All of this can only be realized if he laser sources fulfill the necessary power requirements while keeping the beam quality as close as possible to the diffraction limited value. And this is the rationale and motivation of this paper.

  15. Epidemic spreading in networks with nonrandom long-range interactions

    NASA Astrophysics Data System (ADS)

    Estrada, Ernesto; Kalala-Mutombo, Franck; Valverde-Colmeiro, Alba

    2011-09-01

    An “infection,” understood here in a very broad sense, can be propagated through the network of social contacts among individuals. These social contacts include both “close” contacts and “casual” encounters among individuals in transport, leisure, shopping, etc. Knowing the first through the study of the social networks is not a difficult task, but having a clear picture of the network of casual contacts is a very hard problem in a society of increasing mobility. Here we assume, on the basis of several pieces of empirical evidence, that the casual contacts between two individuals are a function of their social distance in the network of close contacts. Then, we assume that we know the network of close contacts and infer the casual encounters by means of nonrandom long-range (LR) interactions determined by the social proximity of the two individuals. This approach is then implemented in a susceptible-infected-susceptible (SIS) model accounting for the spread of infections in complex networks. A parameter called “conductance” controls the feasibility of those casual encounters. In a zero conductance network only contagion through close contacts is allowed. As the conductance increases the probability of having casual encounters also increases. We show here that as the conductance parameter increases, the rate of propagation increases dramatically and the infection is less likely to die out. This increment is particularly marked in networks with scale-free degree distributions, where infections easily become epidemics. Our model provides a general framework for studying epidemic spreading in networks with arbitrary topology with and without casual contacts accounted for by means of LR interactions.

  16. Long-range Plans for the NASA Infrared Telescope Facility

    NASA Astrophysics Data System (ADS)

    Tokunaga, A. T.; Bus, S. J.; Rayner, J.; Tollestrup, E. V.

    2004-11-01

    The NASA Infrared Telescope Facility (IRTF) is a 3-meter optical/IR telescope dedicated to NASA-related programs of mission support and basic solar system research. All of the funding for IRTF operations comes from the Planetary Astronomy Program. The IRTF is unique in providing NASA with a dedicated telescope for mission support. Its aperture is sufficient for many kinds of solar system observations. While large telescopes like the Keck allow astronomers to push the limits of sensitivity, the IRTF provides the ability to carry out complementary studies on brighter objects. In addition, the IRTF provides the planetary community with access to one of the world's best observing sites, the summit of Mauna Kea. The user base of the telescope has been expanding in recent years due to new instrumentation, visible imaging capability, and remote observing. The IRTF also provides opportunities for instrument development and training of students and post-docs, thus helping ensure a solid foundation for the next generation of planetary scientists. A long-range plan is being developed that will position the IRTF to be a powerful facility for mission support well beyond the Cassini mission. A refurbished IRTF would have: (1) Optimized instruments for planetary science that provide high-spectral resolution, wide wavelength coverage, and diffraction-limited imaging capabilities. (2) An adaptive optics system that produces extremely high Strehl ratio images, and includes an extended object wave-front sensor. (3) Focused programs on mission support, NEOs, asteroids, and comets. (4) Remote observing. (5) Rapid response to needs of the planetary community. (6) Flexible scheduling. (7) Daytime observing close to the Sun. We acknowledge the support of NASA Cooperative Agreement no. NCC 5-538 with the National Aeronautics and Space Administration, Planetary Astronomy Program.

  17. ADRPM-VII applied to the long-range acoustic detection problem

    NASA Technical Reports Server (NTRS)

    Shalis, Edward; Koenig, Gerald

    1990-01-01

    An acoustic detection range prediction model (ADRPM-VII) has been written for IBM PC/AT machines running on the MS-DOS operating system. The software allows the user to predict detection distances of ground combat vehicles and their associated targets when they are involved in quasi-military settings. The program can also calculate individual attenuation losses due to spherical spreading, atmospheric absorption, ground reflection and atmospheric refraction due to temperature and wind gradients while varying parameters effecting the source-receiver problem. The purpose here is to examine the strengths and limitations of ADRPM-VII by modeling the losses due to atmospheric refraction and ground absorption, commonly known as excess attenuation, when applied to the long range detection problem for distances greater than 3 kilometers.

  18. Long-range sound propagation: A review of some experimental data

    NASA Technical Reports Server (NTRS)

    Sutherland, Louis C.

    1990-01-01

    Three experimental studies of long range sound propagation carried out or sponsored in the past by NASA are briefly reviewed to provide a partial prospective for some of the analytical studies presented in this symposium. The three studies reviewed cover (1) a unique test of two large rocket engines conducted in such a way as to provide an indication of possible atmospheric scattering loss from a large low-frequency directive sound source, (2) a year-long measurement of low frequency sound propagation which clearly demonstrated the dominant influence of the vertical gradient in the vector sound velocity towards the receiver in defining excess sound attenuation due to refraction, and (3), a series of excess ground attenuation measurements over grass and asphalt surfaces replicated several times under very similar inversion weather conditions.

  19. Long-range magnetic order and spin-lattice coupling in delafossite CuFeO2

    NASA Astrophysics Data System (ADS)

    Eyert, Volker; Frésard, Raymond; Maignan, Antoine

    2008-08-01

    The electronic and magnetic properties of the delafossite CuFeO2 are investigated by means of electronic structure calculations. They are performed using density functional theory in the generalized gradient approximation, as well as the new full-potential augmented spherical wave method. The calculations reveal three different spin states at the iron sites. Using for the first time the experimentally determined low-temperature crystal structure, we find long-range antiferromagnetic ordering in agreement with experiment. In addition, our calculations show that nonlocal interactions as covered by the generalized gradient approximation lead to a semiconducting ground state.

  20. Multifractal Geophysical Extremes: Nonstationarity and Long Range Correlations

    NASA Astrophysics Data System (ADS)

    Tchiguirinskaia, I.; Schertzer, D.; Lovejoy, S.

    2012-04-01

    Throughout the world, extremes in environmental sciences are of prime importance. They are key variables not only for risk assessments and engineering designs (e.g. of dams and bridges), but also for resource management (e.g. water and energy) and for land use. A better understanding of them is more and more indispensable in settling the debate on their possible climatological evolution. Whereas it took decades before a uniform technique for estimating flow frequencies within a stationary framework, it is often claimed that « stationarity is dead ! ». The fact that geophysical and environmental fields are variable over a wider range of scales than previously thought require to go beyond the limits of the (classical) Extreme Value Theory (EVT). Indeed, long-range correlations are beyond the scope of the classical EVT theory. We show that multifractal concepts and techniques are particularly appealing because they can effectively deal with a cascade of interactions concentrating for instance energy, liquid water, etc. into smaller and smaller space-time domains. Furthermore, a general outcome of these cascade processes -which surprisingly was realized only rather recently- is that rather independently of their details they yield probability distributions with power-law fall-offs, often called (asymptotic) Pareto or Zipf laws. We discuss the corresponding probability distributions of their maxima and its relationship with the Frechet law. We use these multifractal techniques to investigate the possibility of using very short or incomplete data records for reliable statistical predictions of the extremes. In particular we assess the multifractal parameter uncertainty with the help of long synthetic multifractal series and their sub-samples, in particular to obtain an approximation of confidence intervals that would be particularly important for the predictions of multifractal extremes. We finally illustrate the efficiency of this approach with its application to

  1. Long-range transport of air pollution into the Arctic

    NASA Astrophysics Data System (ADS)

    Stohl, A.; Berg, T.; Breivik, K.; Burkhart, J. F.; Eckhardt, S.; Fjæraa, A.; Forster, C.; Herber, A.; Lunder, C.; McMillan, W. W.; None, N.; Manø, S.; Oltmans, S.; Shiobara, M.; Stebel, K.; Hirdman, D.; Stroem, J.; Tørseth, K.; Treffeisen, R.; Virkkunen, K.; Yttri, K. E.; Andrews, E.; Kowal, D.; Mefford, T.; Ogren, J. A.; Sharma, S.; Spichtinger, N.; Stone, R.; Hoch, S.; Wehrli, C.

    2007-12-01

    This paper presents an overview of air pollution transport into the Arctic. The major transport processes will be highlighted, as well as their seasonal, interannual, and spatial variability. The source regions of Arctic air pollution will be discussed, with a focus on black carbon (BC) sources, as BC can produce significant radiative forcing in the Arctic. It is found that Europe is the main source region for BC in winter, whereas boreal forest fires are the strongest source in summer, especially in years of strong burning. Two case studies of recent extreme Arctic air pollution events will be presented. In summer 2004, boreal forest fires in Alaska and Canada caused pan-Arctic enhancements of black carbon. The BC concentrations measured at Barrow (Alaska), Alert (Canada), Summit (Greenland) and Zeppelin (Spitsbergen) were all episodically elevated, as a result of the long-range transport of the biomass burning emissions. Aerosol optical depth was also episodically elevated at these stations, with an almost continuous elevation over more than a month at Summit. During the second episode in spring 2006, new records were set for all measured air pollutant species at the Zeppelin station (Spitsbergen) as well as for ozone in Iceland. At Zeppelin, BC, AOD, aerosol mass, ozone, carbon monoxide and other compounds all reached new record levels, compared to the long-term monitoring record. The episode was caused by transport of polluted air masses from Eastern Europe deep into the Arctic, a consequence of the unusual warmth in the European Arctic during the episode. While fossil fuel combustion sources certainly contributed to this episode, smoke from agricultural fires in Eastern Europe was the dominant pollution component. We also suggest a new revolatilization mechanism for persistent organic pollutants (POPs) stored in soils and vegetation by fires, as POPs were strongly elevated during both episodes. All this suggests a considerable influence of biomass burning on

  2. An elevational gradient in snowpack chemical loading at Glacier National Park, Montana: implications for ecosystem processes

    USGS Publications Warehouse

    Fagre, Daniel; Tonnessen, Kathy; Morris, Kristi; Ingersoll, George; McKeon, Lisa; Holzer, Karen

    2000-01-01

    The accumulation and melting of mountain snowpacks are major drivers of ecosystem processes in the Rocky Mountains. These include the influence of snow water equivalent (SWE) timing and amount of release on soil moisture for annual tree growth, and alpine stream discharge and temperature that control aquatic biota life histories. Snowfall also brings with it atmospheric deposition. Snowpacks will hold as much as 8 months of atmospheric deposition for release into mountain ecosystems during the spring melt. These pulses of chemicals influence soil microbiota and biogeochemical processes affecting mountain vegetation growth. Increased atmospheric nitrogen inputs recently have been documented in remote parts of Colorado's mountain systems but no baseline data exist for the Northern Rockies. We examined patterns of SWE and snow chemistry in an elevational gradient stretching from west to east over the continental divide in Glacier National Park in March 1999 and 2000. Sites ranged from 1080m to 2192m at Swiftcurrent Pass. At each site, two vertically-integrated columns of snow were sampled from snowpits up to 600cm deep and analyzed for major cations and anions. Minor differences in snow chemistry, on a volumetric basis, existed over the elvational gradient. Snowpack chemical loading estimates were calculated for NH4, SO4 and NO3 and closely followed elevational increases in SWE. NO3 (in microequivalents/square meter) ranged from 1,000 ueq/m2 at low elevation sites to 8,000+ ueq/m2 for high elevation sites. Western slopes received greater amounts of SWE and chemical loads for all tested compounds.

  3. Comparison of two operational long-range transport air pollution forecast models

    NASA Astrophysics Data System (ADS)

    Brandt, J.; Geels, C.; Christensen, J. C.; Frohn, L. M.; Hansen, K. M.; Skjøth, C. A.; Hertel, O.

    2003-04-01

    An operational air pollution forecast system, THOR, covering scales from regional over urban background to urban street scales has been developed. The long-range transport model, The Danish Eulerian Operational Model (DEOM) is presently used in the system to calculate the long-range transported air pollution from European sources to the areas of interest. DEOM is an Eulerian model covering Europe and includes 35 chemical compounds. In order to carry out fast computations in operational mode, the model is applied with three vertical layers (bottom layer representing the mixing height, second layer representing the old advected mixing height from the day before and finally a reservoir top layer). In the last years, computer power has increased to a level where real 3-D calculations are possible for forecasting. Therefore a new comprehensive 3-D model, The Danish Eulerian Hemispheric Model (DEHM), including 62 chemical species and 18 vertical layers has been developed. Both models operate on the same polar stereographic projection with a 50 km x 50 km horizontal resolution and uses the same meteorological data from the Eta model as input. The models have been run for the year of 1999, and comparisons of model results with measurements from the European Monitoring and Evaluation Programme (EMEP) will be shown. The differences in the model characteristics will be described together with an intercomparison of the models, using different statistical tests.

  4. 2006 Long Range Development Plan Final Environmental ImpactReport

    SciTech Connect

    Philliber, Jeff

    2007-01-22

    This environmental impact report (EIR) has been prepared pursuant to the applicable provisions of the California Environmental Quality Act (CEQA) and its implementing guidelines (CEQA Guidelines), and the Amended University of California Procedures for Implementation of the California Environmental Quality Act (UC CEQA Procedures). The University of California (UC or the University) is the lead agency for this EIR, which examines the overall effects of implementation of the proposed 2006 Long Range Development Plan (LRDP; also referred to herein as the 'project' for purposes of CEQA) for Lawrence Berkeley National Laboratory (LBNL; also referred to as 'Berkeley Lab,' 'the Laboratory,' or 'the Lab' in this document). An LRDP is a land use plan that guides overall development of a site. The Lab serves as a special research campus operated by the University employees, but it is owned and financed by the federal government and as such it is distinct from the UC-owned Berkeley Campus. As a campus operated by the University of California, the Laboratory is required to prepare an EIR for an LRDP when one is prepared or updated pursuant to Public Resources Code Section 21080.09. The adoption of an LRDP does not constitute a commitment to, or final decision to implement, any specific project, construction schedule, or funding priority. Rather, the proposed 2006 LRDP describes an entire development program of approximately 980,000 gross square feet of new research and support space construction and 320,000 gross square feet of demolition of existing facilities, for a total of approximately 660,000 gross square feet of net new occupiable space for the site through 2025. Specific projects will undergo CEQA review at the time proposed to determine what, if any, additional review is necessary prior to approval. As described in Section 1.4.2, below, and in Chapter 3 of this EIR (the Project Description), the size of the project has been reduced since the Notice of Preparation for

  5. Chemical composition of vegetation along urbanisation gradients in two European cities.

    PubMed

    Sæbø, A; Hanslin, H M; Torp, T; Lierhagen, S; Gawronska, H; Dzierzanowski, K; Gawronski, S

    2015-03-01

    Accumulation of particulate matter (PM) and metals on leaves of three deciduous woody species was studied along urbanisation gradients in Stavanger and Warsaw. Differences between rural and urban sites explained most of the observed variation in leaf chemistry, followed by differences between regions. Highest leaf accumulation of elements was found in Warsaw, but also composition of elements differed between the cities. Overall, species showed similar patterns of element accumulation, but differed in accumulation of specific elements. These differences could in part be explained by differences in epicuticular waxes and PM accumulation. Expected source of elements and their chemical characteristics did not explain the observed accumulation patterns. A better differentiation between elements taken up from soil and air would be required for his. Species specific accumulation of elements has to be taken into consideration using leaf samples for biomonitoring. PMID:25590129

  6. Finite volume model for forced flow/thermal gradient chemical vapor infiltration

    SciTech Connect

    Starr, T.L.; Smith, A.W.

    1991-03-01

    The forced flow/thermal gradient chemical vapor infiltration process (FCVI) has proven to be a successfully technique for fabrication of ceramic matrix composites. It is particularly attractive for thick components which cannot be fabricated using the conventional, isothermal method (ICVI). Although it offers processing times that are at least an order of magnitude shorter than ICVI, FCVI has not been used to fabricate parts of complex geometry and is perceived by many to be unsuitable for such components. The major concern is that selection and control of the flow pattern and thermal profile for optimum infiltration can be a difficult and costly exercise. In order to reduce this effort, we are developing a computer model for FCVI that simulates the densification process for given component geometry, reactor configuration and operating parameters. Used by a process engineer, this model can dramatically reduce the experimental effort needed to obtain uniform densification.

  7. Does the long-range transport of African mineral dust across the Atlantic enhance their hygroscopicity?

    NASA Astrophysics Data System (ADS)

    Denjean, Cyrielle; Caquineau, Sandrine; Desboeufs, Karine; Laurent, Benoit; Quiñones Rosado, Mariana; Vallejo, Pamela; Mayol-Bracero, Olga; Formenti, Paola

    2015-04-01

    Influence of mineral dust on radiation balance is largely dependent on their ability to interact with water. While fresh mineral dusts are highly hydrophobic, various transformation processes (coagulation, heterogeneous chemical reaction) can modify the dust physical and chemical properties during long-range transport, which, in turn, can change the dust hygroscopic properties. The model predictions of the radiative effect by mineral dust still suffer of the lack of certainty of dust hygroscopic properties, and their temporal evolution during long-range transport. We present the first direct surface measurements of the hygroscopicity of Saharan dust after long-range transport over the Atlantic Ocean, their relationship with chemical composition, their influence on particle size and shape and implications for optical properties. Particles were collected during the DUST Aging and TransporT from Africa to the Caribbean (Dust-AttaCk) campaign at the Cape San Juan Puerto Rico station in June-July 2012. Environmental scanning electron microscopy (ESEM) was used to analyze the size, shape, chemical composition and hygroscopic properties of individual particles. At different levels of concentrations in summertime, the coarse mode of atmospheric aerosols in Puerto Rico is dominated by Saharan mineral dust. Most of aged dust particles survived atmospheric transport intact with no observed internal mixture with other species and did not show hygroscopic growth up to 94% relative humidity. This is certainly due to the fact that in summertime dust is mostly transported above the marine boundary layer. A minor portion of mineral dust (approximately 19-28% by number) were involved in atmospheric heterogeneous reactions with acidic gases (likely SO2 and HCl) and sea salt aggregation. While sulfate- and chloride-coated dust remained extremely hydrophobic, dust particles in internal mixing with NaCl underwent profound changes in their hygroscopicity, therefore in size and shape. We

  8. Surface Chemical Gradient Affects the Differentiation of Human Adipose-Derived Stem Cells via ERK1/2 Signaling Pathway.

    PubMed

    Liu, Xujie; Shi, Shengjun; Feng, Qingling; Bachhuka, Akash; He, Wei; Huang, Qianli; Zhang, Ranran; Yang, Xing; Vasilev, Krasimir

    2015-08-26

    To understand the role of surface chemistry on cell behavior and the associated molecular mechanisms, we developed and utilized a surface chemical gradient of amine functional groups by carefully adjusting the gas composition of 1,7-octadiene (OD) and allylamine (AA) of the plasma phase above a moving substrate. The chemical gradient surface used in the present work shows an increasing N/C ratio and wettability from the OD side toward the AA side with no change in surface topography. Under standard culture conditions (with serum), human adipose-derived stem cells (hASCs) adhesion and spreading area increased toward the AA side of the gradient. However, there were no differences in cell behavior in the absence of serum. These results, supported by the trends in proteins adsorption on the gradient surface, demonstrated that surface chemistry affects the response of hASCs through cell-adhesive serum proteins, rather than interacting directly with the cells. The expression of p-ERK and the osteogenic differentiation increased toward the AA side of the gradient, while adipogenic differentiation decreased in the same direction; however, when the activation of ERK1/2 was blocked by PD98059, the levels of osteogenic or adipogenic differentiation on different regions of the chemical gradient were the same. This indicates that ERK1/2 may be an important downstream signaling pathway of surface chemistry directed stem cell fate. PMID:26237746

  9. Exclusion of cosmic rays in protoplanetary disks. II. Chemical gradients and observational signatures

    SciTech Connect

    Cleeves, L. Ilsedore; Bergin, Edwin A.; Adams, Fred C.

    2014-10-20

    The chemical properties of protoplanetary disks are especially sensitive to their ionization environment. Sources of molecular gas ionization include cosmic rays (CRs), stellar X-rays, and short-lived radionuclides, each of which varies with location in the disk. This behavior leads to a significant amount of chemical structure, especially in molecular ion abundances, which is imprinted in their submillimeter rotational line emission. Using an observationally motivated disk model, we make predictions for the dependence of chemical abundances on the assumed properties of the ionizing field. We calculate the emergent line intensity for abundant molecular ions and simulate sensitive observations with the Atacama Large Millimeter/Sub-millimeter Array (ALMA) for a disk at D = 100 pc. The models readily distinguish between high ionization rates (ζ ≳ 10{sup –17} s{sup –1} per H{sub 2}) and below, but it becomes difficult to distinguish between low ionization models when ζ ≲ 10{sup –19} s{sup –1}. We find that H{sub 2}D{sup +} emission is not detectable for sub-interstellar CR rates with ALMA (6h integration), and that N{sub 2}D{sup +} emission may be a more sensitive tracer of midplane ionization. HCO{sup +} traces X-rays and high CR rates (ζ{sub CR} ≳ 10{sup –17} s{sup –1}), and provides a handle on the warm molecular ionization properties where CO is present in the gas. Furthermore, species like HCO{sup +}, which emits from a wide radial region and samples a large gradient in temperature, can exhibit ring-like emission as a consequence of low-lying rotational level de-excitation near the star. This finding highlights a scenario where rings are not necessarily structural or chemical in nature, but simply a result of the underlying line excitation properties.

  10. THE RADIAL METALLICITY GRADIENTS IN THE MILKY WAY THICK DISK AS FOSSIL SIGNATURES OF A PRIMORDIAL CHEMICAL DISTRIBUTION

    SciTech Connect

    Curir, A.; Serra, A. L.; Spagna, A.; Lattanzi, M. G.; Re Fiorentin, P.; Diaferio, A.

    2014-04-01

    In this Letter we examine the evolution of the radial metallicity gradient induced by secular processes, in the disk of an N-body Milky Way-like galaxy. We assign a [Fe/H] value to each particle of the simulation according to an initial, cosmologically motivated, radial chemical distribution and let the disk dynamically evolve for ∼6 Gyr. This direct approach allows us to take into account only the effects of dynamical evolution and to gauge how and to what extent they affect the initial chemical conditions. The initial [Fe/H] distribution increases with R in the inner disk up to R ≈ 10 kpc and decreases for larger R. We find that the initial chemical profile does not undergo major transformations after ∼6 Gyr of dynamical evolution. The final radial chemical gradients predicted by the model in the solar neighborhood are positive and of the same order as those recently observed in the Milky Way thick disk. We conclude that (1) the spatial chemical imprint at the time of disk formation is not washed out by secular dynamical processes and (2) the observed radial gradient may be the dynamical relic of a thick disk originated from a stellar population showing a positive chemical radial gradient in the inner regions.

  11. Long-range structural correlations in amorphous ternary In-based oxides

    NASA Astrophysics Data System (ADS)

    Khanal, Rabi; Medvedeva, Julia

    2015-03-01

    In recent years, there is an increasing shift towards the use of oxide semiconductor materials in their amorphous form owing to several technological advantages and the fact that amorphous oxides exhibit similar or even superior properties than their crystalline counterparts. In this work we have systemically investigated the effect of chemical composition and oxygen stoichiometry on the local and long-range structure of ternary amorphous oxides, namely In-X-O with X =Sn, Zn, Ga, Cd, Ge, Sc, Y, or La, by means of ab-initio molecular dynamics. The results reveal that the local MO structure remains nearly intact upon amorphization and exhibit weak dependence on the composition. In marked contrast, the structural characteristics of the metal-metal shell, namely, the M-M distances and M-O-M angles that determine how MO polyhedra are connected into a network, are affected by the presence of X. Complex interplay between several factors such as the cation ionic size, metal-oxygen bond strength, as well as the natural preference for edge, corner, or face-sharing between the MO polyhedra, leads to a correlated behavior in the long-range structure. These findings highlight the mechanisms of the amorphous structure formation as well as the species of the carrier transport in these oxides.

  12. Long-range atmospheric transport and the distribution of polycyclic aromatic hydrocarbons in Changbai Mountain.

    PubMed

    Zhao, Xiangai; Kim, Seung-Kyu; Zhu, Weihong; Kannan, Narayanan; Li, Donghao

    2015-01-01

    The Changbai (also known as "Baekdu") Mountain, on the border between China and North Korea, is the highest mountain (2750 m) in northeastern China. Recently, this mountain region has experienced a dramatic increase in air pollution, not only because of increasing volumes of tourism-derived traffic but also because of the long-range transport of polluted westerly winds passing through major industrial and urban cities in the eastern region of China. To assess the relative importance of the two sources of pollution, 16 polycyclic aromatic hydrocarbons (PAHs) as model substances were determined in the mountain soil. A total of 32 soil samples were collected from different sides of the mountain at different latitudes between July and August of 2009. The ∑PAH concentrations were within the range 38.5-190.1 ng g(-1) on the northern side, 117.7-443.6 ng g(-1) on the southern side, and 75.3-437.3 ng g(-1) on the western side. A progressive increase in the level of ∑PAHs with latitude was observed on the southern and western sides that face the westerly wind with abundant precipitation. However, a similar concentration gradient was not observed on the northern side that receives less rain and is on the leeward direction of the wind. The high-molecular-weight PAH compounds were predominant in the soils on the southern and western sides, while low-molecular-weight PAHs dominated the northern side soils. These findings show that the distribution of PAHs in the mountain soil is strongly influenced by the atmospheric long-range transport and cold trapping. PMID:25036943

  13. Long-range signaling in growing neurons after local elevation of cyclic AMP-dependent activity

    PubMed Central

    1994-01-01

    Cyclic AMP-dependent activity at the growth cone or the soma of cultured Xenopus spinal neurons was elevated by local extracellular perfusion of the neuron with culture medium containing 8-bromoadenosine 3',5'-cyclic monophosphate (8-br-cAMP) or forskolin. During local perfusion of one of the growth cones of multipolar neurons with these drugs, the perfused growth cone showed further extension, while the distant, unperfused growth cones were inhibited in their growth. Local perfusion of the growth cone with culture medium or local perfusion with 8-br-cAMP at a cell-free region 100 microns away from the growth cone did not produce any effect on the extension of the growth cone. Reduced extension of all growth cones was observed when the perfusion with 8-br-cAMP was restricted to the soma. The distant inhibitory effect does not depend on the growth of the perfused growth cone since local coperfusion of the growth cone with 8-br-cAMP and colchicine inhibited growth on both perfused and unperfused growth cones, while local perfusion with colchicine alone inhibited only the perfused growth cone. The distant inhibitory effect was abolished when the perfusion of 8-br-cAMP was carried out together with kinase inhibitor H- 8, suggesting the involvement of cAMP-dependent protein kinase and/or its downstream factors in the long-range inhibitory signaling. Uniform exposure of the entire neuron to bath-applied 8-br-cAMP, however, led to enhanced growth activity at all growth cones. Thus, local elevation of cAMP-dependent activity produces long-range and opposite effects on distant parts of the neuron, and a cytosolic gradient of second messengers may produce effects distinctly different from those following uniform global elevation of the messenger, leading to differential growth regulation at different regions of the same neuron. PMID:7798321

  14. Chemical and morphological gradient scaffolds to mimic hierarchically complex tissues: From theoretical modeling to their fabrication.

    PubMed

    Marrella, Alessandra; Aiello, Maurizio; Quarto, Rodolfo; Scaglione, Silvia

    2016-10-01

    Porous multiphase scaffolds have been proposed in different tissue engineering applications because of their potential to artificially recreate the heterogeneous structure of hierarchically complex tissues. Recently, graded scaffolds have been also realized, offering a continuum at the interface among different phases for an enhanced structural stability of the scaffold. However, their internal architecture is often obtained empirically and the architectural parameters rarely predetermined. The aim of this work is to offer a theoretical model as tool for the design and fabrication of functional and structural complex graded scaffolds with predicted morphological and chemical features, to overcome the time-consuming trial and error experimental method. This developed mathematical model uses laws of motions, Stokes equations, and viscosity laws to describe the dependence between centrifugation speed and fiber/particles sedimentation velocity over time, which finally affects the fiber packing, and thus the total porosity of the 3D scaffolds. The efficacy of the theoretical model was tested by realizing engineered graded grafts for osteochondral tissue engineering applications. The procedure, based on combined centrifugation and freeze-drying technique, was applied on both polycaprolactone (PCL) and collagen-type-I (COL) to test the versatility of the entire process. A functional gradient was combined to the morphological one by adding hydroxyapatite (HA) powders, to mimic the bone mineral phase. Results show that 3D bioactive morphologically and chemically graded grafts can be properly designed and realized in agreement with the theoretical model. Biotechnol. Bioeng. 2016;113: 2286-2297. © 2016 Wiley Periodicals, Inc. PMID:27093435

  15. Physico-chemical gradients within the hydrothermal chimney Roane define sharp boundaries for microbial community ecology

    NASA Astrophysics Data System (ADS)

    Frank, K. L.; Kelley, D. S.; Girguis, P. R.

    2011-12-01

    The unique physico-chemical gradients characteristic of hydrothermal vents provide diverse niches for prokaryotic communities. To date, our knowledge of environmental constraints on microbial colonization and metabolic activity within active sulfide structures has been limited by the lack of co-registered in situ chemistry and appropriate, taxonomic and metabolic genetic markers. Here we characterize de novo endolithic microbial colonization using a sulfide microbial incubator within the hydrothermal vent Roane during a one-year deployment, with co-registered temperature, fluid chemistry and mineralogy. Taxanomic assessment of phylogenetic diversity via 16S rDNA extracted from the outer (40-70°C) and middle (150-240°C) chambers of the incubator revealed patterns of distribution comparable to previously published observations. However, quantitative and statistical analyses of 16S rDNA sequences from two chambers revealed very distinct communities, with less than 5% of the identified operational taxonomic units common to both chambers. Analyses of metagenomic data suggest an elevated potential for motility and select biosynthetic pathways in the outer chamber community. In contrast, the middle chamber community exhibits a greater potential for quorum sensing, biofilm formation and archaeal lipid biosynthesis. Striking differences in metabolic potential were also apparent. These data suggest that the distribution, abundance and physiological capacity of these communities is strongly governed by chemical and physical variability of the environment.

  16. Gel for Simultaneous Chemical Imaging of Anionic and Cationic Solutes Using Diffusive Gradients in Thin Films

    PubMed Central

    2013-01-01

    We report on a novel gel based on diffusive gradients in thin films (DGT) for the simultaneous measurement of cations and anions and its suitability for high resolution chemical imaging by using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). The new high resolution mixed binding gel (HR-MBG) is based on zirconium-hydroxide and suspended particulate reagent-iminodiacetate (SPR-IDA) as resin materials which are embedded in an ether-based urethane polymer hydrogel. The use of this polymer hydrogel material allows the production of ultrathin, highly stable and tear-proof resin gel layers with superior handling properties compared to existing ultrathin polyacrylamide gels. The gel was characterized regarding its uptake kinetics, the anion and cation capacities, and the effects of pH, ionic strength, and aging on the performance of the HR-MBG. Our results demonstrate the capability of this novel gel for concomitant sampling of anions and cations. The suitability of this new gel type for DGT chemical imaging at submm spatial resolution in soils using LA-ICPMS is shown. 2D images of P, As, Co, Cu, Mn, and Zn distributions around roots of Zea mays L. demonstrate the new opportunities offered by the HR-MBG for high-resolution mapping of solute dynamics in soil and sediment hotspots, such as the rhizosphere, by simultaneous observation of anionic and cationic solute species. PMID:24256092

  17. Gel for simultaneous chemical imaging of anionic and cationic solutes using diffusive gradients in thin films.

    PubMed

    Kreuzeder, Andreas; Santner, Jakob; Prohaska, Thomas; Wenzel, Walter W

    2013-12-17

    We report on a novel gel based on diffusive gradients in thin films (DGT) for the simultaneous measurement of cations and anions and its suitability for high resolution chemical imaging by using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). The new high resolution mixed binding gel (HR-MBG) is based on zirconium-hydroxide and suspended particulate reagent-iminodiacetate (SPR-IDA) as resin materials which are embedded in an ether-based urethane polymer hydrogel. The use of this polymer hydrogel material allows the production of ultrathin, highly stable and tear-proof resin gel layers with superior handling properties compared to existing ultrathin polyacrylamide gels. The gel was characterized regarding its uptake kinetics, the anion and cation capacities, and the effects of pH, ionic strength, and aging on the performance of the HR-MBG. Our results demonstrate the capability of this novel gel for concomitant sampling of anions and cations. The suitability of this new gel type for DGT chemical imaging at submm spatial resolution in soils using LA-ICPMS is shown. 2D images of P, As, Co, Cu, Mn, and Zn distributions around roots of Zea mays L. demonstrate the new opportunities offered by the HR-MBG for high-resolution mapping of solute dynamics in soil and sediment hotspots, such as the rhizosphere, by simultaneous observation of anionic and cationic solute species. PMID:24256092

  18. Swelling of chemical and physical planar brushes of gradient copolymers in a selective solvent.

    PubMed

    Venev, Sergey V; Potemkin, Igor I

    2014-09-14

    We propose a mean-field theory of chemical and physical planar brushes of linear gradient copolymers swollen in a selective solvent. The polymer chains are grafted to the substrate by the ends with the excess of insoluble monomer units, and the majority of the soluble units are located near the free ends of the chains. The grafting points are considered to be immobile (chemical brush) and mobile in-plane (physical brush). In the latter case the grafting density is determined from the equilibrium conditions (minimum of the free energy). A common peculiarity of the brushes of both types is that the polymer concentration gradually changes from a relatively high value near the substrate (collapsed region of the brush) to a small value near the free surface (swollen region of the brush). In the case of the chemical brush, a polymer depletion zone can appear in the middle of the brush if incompatibility between insoluble and soluble (A and B) units is high enough. Here the polymer density is even lower than near the free surface of the brush. The grafting density of the physical brush is inversely proportional to the chain length and increases with the decrease of the solvent quality for the insoluble (A) units. The latter can be accompanied by shrinkage of the brush thickness due to broad distribution of the insoluble units through the chain: a minor fraction of insoluble units near the free ends can aggregate with a major fraction of them near the substrate. As a result, the concentration of the soluble (B) units can have a maximum in the middle of the brush rather than near the free surface. PMID:25058377

  19. Facile and rapid generation of 3D chemical gradients within hydrogels for high-throughput drug screening applications.

    PubMed

    Ahadian, Samad; Ramón-Azcón, Javier; Estili, Mehdi; Obregón, Raquel; Shiku, Hitoshi; Matsue, Tomokazu

    2014-09-15

    We propose a novel application of dielectrophoresis (DEP) to make three-dimensional (3D) methacrylated gelatin (GelMA) hydrogels with gradients of micro- and nanoparticles. DEP forces were able to manipulate micro- and nanoparticles of different sizes and materials (i.e., C2C12 myoblasts, polystyrene beads, gold microparticles, and carbon nanotubes) within GelMA hydrogels in a rapid and facile way and create 3D gradients of these particles in a microchamber. Immobilization of drugs, such as fluorescein isothiocyanate-dextran (FITC-dextran) and 6-hydroxydopamine (6-OHDA), on gold microparticles allowed us to investigate the high-throughput release of these drugs from GelMA-gold microparticle gradient systems. The latter gradient constructs were incubated with C2C12 myoblasts for 24h to examine the cell viability through the release of 6-OHDA. The drug was released from the microparticles in a gradient manner, inducing a cell viability gradient. This novel approach to create 3D chemical gradients within hydrogels is scalable to any arbitrary length scale. It is useful for making anisotropic biomimetic materials and high-throughput platforms to investigate cell-microenvironment interactions in a rapid, simple, cost-effective, and reproducible manner. PMID:24727602

  20. Cyanobacterial distributions along a physico-chemical gradient in the Northeastern Pacific Ocean.

    PubMed

    Sudek, Sebastian; Everroad, R Craig; Gehman, Alyssa-Lois M; Smith, Jason M; Poirier, Camille L; Chavez, Francisco P; Worden, Alexandra Z

    2015-10-01

    The cyanobacteria Prochlorococcus and Synechococcus are important marine primary producers. We explored their distributions and covariance along a physico-chemical gradient from coastal to open ocean waters in the Northeastern Pacific Ocean. An inter-annual pattern was delineated in the dynamic transition zone where upwelled and eastern boundary current waters mix, and two new Synechococcus clades, Eastern Pacific Clade (EPC) 1 and EPC2, were identified. By applying state-of-the-art phylogenetic analysis tools to bar-coded 16S amplicon datasets, we observed higher abundance of Prochlorococcus high-light I (HLI) and low-light I (LLI) in years when more oligotrophic water intruded farther inshore, while under stronger upwelling Synechococcus I and IV dominated. However, contributions of some cyanobacterial clades were proportionally relatively constant, e.g. Synechococcus EPC2. In addition to supporting observations that Prochlorococcus LLI thrive at higher irradiances than other LL taxa, the results suggest LLI tolerate lower temperatures than previously reported. The phylogenetic precision of our 16S rRNA gene analytical approach and depth of bar-coded sequencing also facilitated detection of clades at low abundance in unexpected places. These include Prochlorococcus at the coast and Cyanobium-related sequences offshore, although it remains unclear whether these came from resident or potentially advected cells. Our study enhances understanding of cyanobacterial distributions in an ecologically important eastern boundary system. PMID:25522910

  1. Creating 3D chemical gradients with self-folding microfluidic networks

    NASA Astrophysics Data System (ADS)

    Jamal, Mustapha; Kalinin, Yevgeniy; Zarafshar, Aasiyeh; Gracias, David

    2012-02-01

    We describe the reversible self-folding of polymeric films into intricate three-dimensional (3D) microfluidic networks and investigate their utility as bio-inspired synthetic vasculature for in vitro tissue culture models. Our fabrication methodology relies on patterning of channels inside the films at the planar microfabrication stage followed by programmable self-folding of the two-dimensional patterned structures. Here self-folding action is enabled by stress gradients which develop in the films due to differential ultraviolet cross-linking and subsequent solvent conditioning. We achieved wafer-scale assembly of micropatterned geometries including helices, polyhedra and corrugated sheets. To demonstrate utility of such self-folded microfluidic devices we present localized chemical delivery of biochemicals in 3D to discrete regions of cells cultured on the curved self-assembled surfaces and in a thick, surrounding hydrogel. We believe that the devices can be used to mimic such natural self-assembled systems as leaves and tissues. Reference: M. Jamal et al., Nature Communications (2011; in press).

  2. Long-range and rapid transport of individual nano-objects by a hybrid electrothermoplasmonic nanotweezer.

    PubMed

    Ndukaife, Justus C; Kildishev, Alexander V; Nnanna, Agbai George Agwu; Shalaev, Vladimir M; Wereley, Steven T; Boltasseva, Alexandra

    2016-01-01

    Plasmon-enhanced optical trapping is being actively studied to provide efficient manipulation of nanometre-sized objects. However, a long-standing issue with previously proposed solutions is how to controllably load the trap on-demand without relying on Brownian diffusion. Here, we show that the photo-induced heating of a nanoantenna in conjunction with an applied a.c. electric field can initiate rapid microscale fluid motion and particle transport with a velocity exceeding 10 μm s(-1), which is over two orders of magnitude faster than previously predicted. Our electrothermoplasmonic device enables on-demand long-range and rapid delivery of single nano-objects to specific plasmonic nanoantennas, where they can be trapped and even locked in place. We also present a physical model that elucidates the role of both heat-induced fluidic motion and plasmonic field enhancement in the plasmon-assisted optical trapping process. Finally, by applying a d.c. field or low-frequency a.c. field (below 10 Hz) while the particle is held in the trap by the gradient force, the trapped nano-objects can be immobilized into plasmonic hotspots, thereby providing the potential for effective low-power nanomanufacturing on-chip. PMID:26524398

  3. Long-range and rapid transport of individual nano-objects by a hybrid electrothermoplasmonic nanotweezer

    NASA Astrophysics Data System (ADS)

    Ndukaife, Justus C.; Kildishev, Alexander V.; Nnanna, Agbai George Agwu; Shalaev, Vladimir M.; Wereley, Steven T.; Boltasseva, Alexandra

    2016-01-01

    Plasmon-enhanced optical trapping is being actively studied to provide efficient manipulation of nanometre-sized objects. However, a long-standing issue with previously proposed solutions is how to controllably load the trap on-demand without relying on Brownian diffusion. Here, we show that the photo-induced heating of a nanoantenna in conjunction with an applied a.c. electric field can initiate rapid microscale fluid motion and particle transport with a velocity exceeding 10 μm s-1, which is over two orders of magnitude faster than previously predicted. Our electrothermoplasmonic device enables on-demand long-range and rapid delivery of single nano-objects to specific plasmonic nanoantennas, where they can be trapped and even locked in place. We also present a physical model that elucidates the role of both heat-induced fluidic motion and plasmonic field enhancement in the plasmon-assisted optical trapping process. Finally, by applying a d.c. field or low-frequency a.c. field (below 10 Hz) while the particle is held in the trap by the gradient force, the trapped nano-objects can be immobilized into plasmonic hotspots, thereby providing the potential for effective low-power nanomanufacturing on-chip.

  4. Flying the fly: long-range flight behavior of Drosophila melanogaster to attractive odors.

    PubMed

    Becher, Paul G; Bengtsson, Marie; Hansson, Bill S; Witzgall, Peter

    2010-06-01

    The fruit fly, Drosophila melanogaster Meigen (Diptera: Drosophilidae), is a model for how animals sense, discriminate, and respond to chemical signals. However, with D. melanogaster our knowledge of the behavioral activity of olfactory receptor ligands has relied largely on close-range attraction, rather than on long-range orientation behavior. We developed a flight assay to relate chemosensory perception to behavior. Headspace volatiles from vinegar attracted 62% of assayed flies during a 15-min experimental period. Flies responded irrespective of age, sex, and mating state, provided they had been starved. To identify behaviorally relevant chemicals from vinegar, we compared the responses to vinegar and synthetic chemicals. Stimuli were applied by a piezoelectric sprayer at known and constant release rates. Re-vaporized methanol extracts of Super Q-trapped vinegar volatiles attracted as many flies as vinegar. The main volatile component of vinegar, acetic acid, elicited significant attraction as a single compound. Two other vinegar volatiles, 2-phenyl ethanol and acetoin, produced a synergistic effect when added to acetic acid. Geosmin, a microbiological off-flavor, diminished attraction to vinegar. This wind tunnel assay based on a conspicuous and unambiguous behavioral response provides the necessary resolution for the investigation of physiologically and ecologically relevant odors and will become an essential tool for the functional analysis of the D. melanogaster olfactory system. PMID:20437263

  5. Light-Activated Amino Acid Transport Systems in Halobacterium halobium Envelope Vesicles: Role of Chemical and Electrical Gradients

    NASA Technical Reports Server (NTRS)

    MacDonald, Russell E.; Greene, Richard V.; Lanyi, Janos K.

    1977-01-01

    The accumulation of 20 commonly occurring L-amino acids by cell envelope vesicles of Halobacterium halobium, in response to light-induced membrane potential and an artificially created sodium gradient, has been studied. Nineteen of these amino acids are actively accumulated under either or both of these conditions. Glutamate is unique in that its uptake is driven only by a chemical gradient for sodium. Amino acid concentrations at half-maximal uptake rates (Km) and maximal transport rates (V(sub max) have been determined for the uptake of all 19 amino acids. The transport systems have been partially characterized with respect to groups of amino acids transported by common carriers, cation effects, and relative response to the electrical and chemical components of the sodium gradient, the driving forces for uptake. The data presented clearly show that the carrier systems, which are responsible for uptake of individual amino acids, are as variable in their properties as those found in other organisms, i. e., some are highly specific for individual amino acids, some transport several amino acids competitively, some are activated by a chemical gradient of sodium only, and some function also in the complete absence of such a gradient. For all amino acids, Na(+) and K(+) are both required for maximal rate of uptake. The carriers for L-leucine and L-histidine are symmetrical in that these amino acids are transported in both directions across the vesicle membrane. It is suggested that coupling of substrate transport to metabolic energy via transient ionic gradients may be a general phenomenon in procaryotes.

  6. Contribution of long range transport to local fine particulate matter concerns

    NASA Astrophysics Data System (ADS)

    Wagstrom, K. M.; Pandis, S. N.

    2011-05-01

    We have utilized the Particulate Matter Source Apportionment Technology (PSAT) in PMCAMx (a regional chemical transport model) to quantify the contributions from local emissions and short range (under 100 km), mid range (100-550 km) and long range (over 550 km) pollutant transport to both primary and secondary particulate matter concentrations using the Eastern United States as a test case. We have studied these contributions for two urban (Pittsburgh, Pennsylvania and Atlanta, Georgia) and one rural area (Great Smoky Mountains National Park) during all seasons. The local emissions impacts to elemental carbon (EC) in major urban areas were found to be substantial with approximately 50% of the EC coming from local sources and 80% emitted within 200 km of the receptor. The local sources are even more important during the night contributing around 60% of the EC and then dropping to around 40% during the early afternoon. The EC in the rural Great Smoky Mountains was mainly the result of sources 100-550 km away. The seasonal variation of the EC source area contributions is small. There was also little difference between high and low EC concentration days. The contributions to secondary aerosol species were found to be more regional with more than 50% of the sulfate and secondary organic aerosol (SOA) originating from SO 2 and VOC sources that were more than 200 km away from the receptor. The importance of sources further away increased during the winter because of the lower photochemical activity. While mid range transport dominated in the summer the sulfate and SOA levels in all areas, long range transport became the most important sulfate and SOA source during the winter in the colder Northeastern US and of sulfate in the warmer South.

  7. Long-range transport of Asian outflow to the equatorial Pacific

    NASA Astrophysics Data System (ADS)

    Martin, Brian D.; Fuelberg, Henry E.; Blake, Nicola J.; Crawford, James H.; Logan, Jennifer A.; Blake, Donald R.; Sachse, Glen W.

    2002-01-01

    The second Pacific Exploratory Mission to the Tropics (PEM T-B) was conducted as part of NASA's Global Tropospheric Experiment (GTE) from 25 February through 19 April 1999. Long-range pollution signatures are examined during four PEM T-B flights that ranged as far northeast as California and as far southwest as coastal New Guinea. The signatures are studied to determine their ages and chemical evolution during transport. The chemical species examined include nonmethane hydrocarbons, halocarbons, and carbon monoxide. Wind data from the European Centre for Medium Range Weather Forecasts (ECMWF) are used to calculate backward trajectories along the four flight tracks. Results show that some pollutants originating from the Asian continent, and even farther west, are transported across the Pacific by the middle latitude westerly winds and reach the subtropical Pacific anticyclone where they subside and turn southwestward under the influence of the low level trade winds. The parcels ultimately reach the western Pacific near coastal New Guinea after 20-25 days of transit.

  8. Long-range transport of Asian outflow to the equatorial Pacific

    NASA Astrophysics Data System (ADS)

    Martin, Brian D.; Fuelberg, Henry E.; Blake, Nicola J.; Crawford, James H.; Logan, Jennifer A.; Blake, Donald R.; Sachse, Glen W.

    2003-01-01

    The second Pacific Exploratory Mission to the Tropics (PEM T-B) was conducted as part of NASA's Global Tropospheric Experiment (GTE) from 25 February through 19 April 1999. Long-range pollution signatures are examined during four PEM T-B flights that ranged as far northeast as California and as far southwest as coastal New Guinea. The signatures are studied to determine their ages and chemical evolution during transport. The chemical species examined include nonmethane hydrocarbons, halocarbons, and carbon monoxide. Wind data from the European Centre for Medium Range Weather Forecasts (ECMWF) are used to calculate backward trajectories along the four flight tracks. Results show that some pollutants originating from the Asian continent, and even farther west, are transported across the Pacific by the middle latitude westerly winds and reach the subtropical Pacific anticyclone where they subside and turn southwestward under the influence of the low level trade winds. The parcels ultimately reach the western Pacific near coastal New Guinea after 20-25 days of transit.

  9. THE OPEN CLUSTER CHEMICAL ANALYSIS AND MAPPING SURVEY: LOCAL GALACTIC METALLICITY GRADIENT WITH APOGEE USING SDSS DR10

    SciTech Connect

    Frinchaboy, Peter M.; Thompson, Benjamin; Jackson, Kelly M. E-mail: b.a.thompson1@tcu.edu; and others

    2013-11-01

    The Open Cluster Chemical Analysis and Mapping (OCCAM) survey aims to produce a comprehensive, uniform, infrared-based data set for hundreds of open clusters, and constrain key Galactic dynamical and chemical parameters from this sample. This first contribution from the OCCAM survey presents analysis of 141 members stars in 28 open clusters with high-resolution metallicities derived from a large uniform sample collected as part of the Sloan Digital Sky Survey III/Apache Point Observatory Galactic Evolution Experiment. This sample includes the first high-resolution metallicity measurements for 22 open clusters. With this largest ever uniformly observed sample of open cluster stars we investigate the Galactic disk gradients of both [M/H] and [α/M]. We find basically no gradient in [α/M] across 7.9 kpc ≤ R {sub GC} ≤ 14.5 kpc, but [M/H] does show a gradient for R {sub GC} < 10 kpc and a significant flattening beyond R {sub GC} = 10 kpc. In particular, whereas fitting a single linear trend yields an [M/H] gradient of –0.09 ± 0.03 dex kpc{sup –1}—similar to previously measure gradients inside 13 kpc—by independently fitting inside and outside 10 kpc separately we find a significantly steeper gradient near the Sun (7.9 ≤ R {sub GC} ≤ 10) than previously found (–0.20 ± 0.08 dex kpc{sup –1}) and a nearly flat trend beyond 10 kpc (–0.02 ± 0.09 dex kpc{sup –1})

  10. Molecular simulations of the n -alkane liquid-vapor interface: interfacial properties and their long range corrections.

    PubMed

    Ibergay, C; Ghoufi, A; Goujon, F; Ungerer, P; Boutin, A; Rousseau, B; Malfreyt, P

    2007-05-01

    Monte Carlo simulations have been performed to study the interfacial properties of the liquid-vapor interface of alkanes. We highlight the chemical equilibrium of the liquid-vapor interface by calculating a local chemical potential including the appropriate long-range corrections profiles. We extend the "test-area" (TA) technique developed by Gloor [J. Chem. Phys. 123, 134703 (2005)] on Lennard-Jones and square-well fluids to molecular systems. We establish both operational expressions of the TA approach for the calculation of the surface tension profile and the corresponding long-range corrections by underlining the approximations used. We compare the results between the different operational expressions of the surface tension and focus on the truncation procedures to explain the difference between the different techniques using either the potential or force equations. We make the results of surface tension identical between the different methods by using consistent potential and force equations. In the case of a relatively small cutoff, we propose to show that the Irving-Kirkwood definition and TA methods lead to the same value of the surface tension under condition that appropriate long-range corrections be included in the calculation. We end this paper by calculation of the entropy change profile and a comparison with experiments. PMID:17677073

  11. Commercial scale fabrication method for fabricating a gradient refractive-index rod: Overcoming volume shrinkage and chemical restrictions.

    PubMed

    Cho, Hansol; Son, Young Mok; Kim, Mu Gyeom; Ra, Byoung Joo; Park, Joon-Yong; Lee, Seung Hui; Choi, Jin Sung; Song, Min Young; Park, O Ok; Kim, Youn Cheol; Hwang, Jin Taek

    2006-10-01

    We report a fabrication method for a gradient refractive-index polymeric object from a binary comonomer system, regardless of the monomers' reactivity ratio and the molar volume criteria of gradient refractive-index development. To fabricate a large gradient refractive-index rod consisting of a methyl methacrylate and 2,2,3,3-tetrafluoropropyl methacrylate comonomer pair that has not been used for fabrication of a copolymer gradient refractive-index rod by previous conventional methods because of chemical restrictions in molar volume and reactivity ratio difference, we use the so-called successive UV polymerization in a controlled radial volume in conjunction with an automatic refill reactor. Simultaneously and automatically, the volume shrinkage problem, an inevitable shortcoming for the fabrication of a large polymeric object in a commercial production scale, is overcome and exploited. The theoretical features of the refractive-index profile generation of this method are also compared with those of conventional methods for which the chemical restrictions of monomers are crucial for the shape of a refractive-index profile. PMID:16983409

  12. 75 FR 1799 - Terminate Long Range Aids to Navigation (Loran-C) Signal

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-13

    ... Register of January 7, 2010 (75 FR 998). The document announced termination of the Long Range Aids to... January 7, 2010, in ] FR Doc. 2010-83, on page 998 in the second column under DATES, correct... SECURITY Coast Guard Terminate Long Range Aids to Navigation (Loran-C) Signal AGENCY: U.S. Coast Guard,...

  13. Long Range Plan for Information Systems from the State Board of Education.

    ERIC Educational Resources Information Center

    Texas Education Agency, Austin.

    The Information Systems Long Range Plan specifically addresses Goal four of the Texas State Board of Education's (SBOE's) "Long-Range Plan for Public School Education" dealing with efficient management and organization of the educational system. To facilitate this goal, the SBOE in 1986 approved and directed the Texas Education Agency to implement…

  14. 48 CFR 5.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 48 Federal Acquisition Regulations System 1 2011-10-01 2011-10-01 false Release of long-range... REGULATION ACQUISITION PLANNING PUBLICIZING CONTRACT ACTIONS Release of Information 5.404 Release of long... may be desirable to publicize estimates of unclassified long-range acquisition requirements....

  15. 48 CFR 405.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 48 Federal Acquisition Regulations System 4 2013-10-01 2013-10-01 false Release of long-range acquisition estimates. 405.404 Section 405.404 Federal Acquisition Regulations System DEPARTMENT OF... Release of long-range acquisition estimates....

  16. 48 CFR 405.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 48 Federal Acquisition Regulations System 4 2012-10-01 2012-10-01 false Release of long-range acquisition estimates. 405.404 Section 405.404 Federal Acquisition Regulations System DEPARTMENT OF... Release of long-range acquisition estimates....

  17. 48 CFR 605.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 48 Federal Acquisition Regulations System 4 2011-10-01 2011-10-01 false Release of long-range acquisition estimates. 605.404 Section 605.404 Federal Acquisition Regulations System DEPARTMENT OF STATE... long-range acquisition estimates....

  18. 48 CFR 5.404-2 - Announcements of long-range acquisition estimates.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 48 Federal Acquisition Regulations System 1 2011-10-01 2011-10-01 false Announcements of long... Announcements of long-range acquisition estimates. Further publicizing, consistent with the needs of the individual case, may be accomplished by announcing through the GPE that long-range acquisition estimates...

  19. 48 CFR 405.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 48 Federal Acquisition Regulations System 4 2011-10-01 2011-10-01 false Release of long-range acquisition estimates. 405.404 Section 405.404 Federal Acquisition Regulations System DEPARTMENT OF... Release of long-range acquisition estimates....

  20. 48 CFR 605.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 4 2014-10-01 2014-10-01 false Release of long-range acquisition estimates. 605.404 Section 605.404 Federal Acquisition Regulations System DEPARTMENT OF STATE... long-range acquisition estimates....

  1. 48 CFR 5.404-2 - Announcements of long-range acquisition estimates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 1 2014-10-01 2014-10-01 false Announcements of long... Announcements of long-range acquisition estimates. Further publicizing, consistent with the needs of the individual case, may be accomplished by announcing through the GPE that long-range acquisition estimates...

  2. 48 CFR 5.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 1 2014-10-01 2014-10-01 false Release of long-range... REGULATION ACQUISITION PLANNING PUBLICIZING CONTRACT ACTIONS Release of Information 5.404 Release of long... may be desirable to publicize estimates of unclassified long-range acquisition requirements....

  3. 48 CFR 605.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 48 Federal Acquisition Regulations System 4 2012-10-01 2012-10-01 false Release of long-range acquisition estimates. 605.404 Section 605.404 Federal Acquisition Regulations System DEPARTMENT OF STATE... long-range acquisition estimates....

  4. 48 CFR 1405.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 48 Federal Acquisition Regulations System 5 2012-10-01 2012-10-01 false Release of long-range acquisition estimates. 1405.404 Section 1405.404 Federal Acquisition Regulations System DEPARTMENT OF THE... Release of long-range acquisition estimates....

  5. 14 CFR 125.267 - Flight navigator and long-range navigation equipment.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 3 2011-01-01 2011-01-01 false Flight navigator and long-range navigation... Requirements § 125.267 Flight navigator and long-range navigation equipment. (a) No certificate holder may... current flight navigator certificate; or (2) Two independent, properly functioning, and approved...

  6. 48 CFR 1305.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 5 2014-10-01 2014-10-01 false Release of long-range acquisition estimates. 1305.404 Section 1305.404 Federal Acquisition Regulations System DEPARTMENT OF COMMERCE... long-range acquisition estimates....

  7. 14 CFR 125.267 - Flight navigator and long-range navigation equipment.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Flight navigator and long-range navigation... Requirements § 125.267 Flight navigator and long-range navigation equipment. (a) No certificate holder may... current flight navigator certificate; or (2) Two independent, properly functioning, and approved...

  8. 14 CFR 125.267 - Flight navigator and long-range navigation equipment.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 3 2013-01-01 2013-01-01 false Flight navigator and long-range navigation... Requirements § 125.267 Flight navigator and long-range navigation equipment. (a) No certificate holder may... current flight navigator certificate; or (2) Two independent, properly functioning, and approved...

  9. 14 CFR 125.267 - Flight navigator and long-range navigation equipment.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 3 2014-01-01 2014-01-01 false Flight navigator and long-range navigation... Requirements § 125.267 Flight navigator and long-range navigation equipment. (a) No certificate holder may... current flight navigator certificate; or (2) Two independent, properly functioning, and approved...

  10. 48 CFR 405.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 4 2014-10-01 2014-10-01 false Release of long-range acquisition estimates. 405.404 Section 405.404 Federal Acquisition Regulations System DEPARTMENT OF... Release of long-range acquisition estimates....

  11. 48 CFR 605.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 48 Federal Acquisition Regulations System 4 2013-10-01 2013-10-01 false Release of long-range acquisition estimates. 605.404 Section 605.404 Federal Acquisition Regulations System DEPARTMENT OF STATE... long-range acquisition estimates....

  12. 48 CFR 1405.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 5 2014-10-01 2014-10-01 false Release of long-range acquisition estimates. 1405.404 Section 1405.404 Federal Acquisition Regulations System DEPARTMENT OF THE... Release of long-range acquisition estimates....

  13. 48 CFR 5.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Release of long-range... REGULATION ACQUISITION PLANNING PUBLICIZING CONTRACT ACTIONS Release of Information 5.404 Release of long... may be desirable to publicize estimates of unclassified long-range acquisition requirements....

  14. 48 CFR 5.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 48 Federal Acquisition Regulations System 1 2013-10-01 2013-10-01 false Release of long-range... REGULATION ACQUISITION PLANNING PUBLICIZING CONTRACT ACTIONS Release of Information 5.404 Release of long... may be desirable to publicize estimates of unclassified long-range acquisition requirements....

  15. 48 CFR 5.404-2 - Announcements of long-range acquisition estimates.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 48 Federal Acquisition Regulations System 1 2013-10-01 2013-10-01 false Announcements of long... Announcements of long-range acquisition estimates. Further publicizing, consistent with the needs of the individual case, may be accomplished by announcing through the GPE that long-range acquisition estimates...

  16. 48 CFR 5.404-2 - Announcements of long-range acquisition estimates.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Announcements of long... Announcements of long-range acquisition estimates. Further publicizing, consistent with the needs of the individual case, may be accomplished by announcing through the GPE that long-range acquisition estimates...

  17. 48 CFR 1305.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 48 Federal Acquisition Regulations System 5 2012-10-01 2012-10-01 false Release of long-range acquisition estimates. 1305.404 Section 1305.404 Federal Acquisition Regulations System DEPARTMENT OF COMMERCE... long-range acquisition estimates....

  18. 14 CFR 125.267 - Flight navigator and long-range navigation equipment.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 3 2012-01-01 2012-01-01 false Flight navigator and long-range navigation... Requirements § 125.267 Flight navigator and long-range navigation equipment. (a) No certificate holder may...-range means of navigation which enable a reliable determination to be made of the position of...

  19. 23 CFR 450.214 - Development and content of the long-range statewide transportation plan.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false Development and content of the long-range statewide transportation plan. 450.214 Section 450.214 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF... Programming § 450.214 Development and content of the long-range statewide transportation plan. (a) The...

  20. North Idaho College Long-Range Plan and Statement of Institutional Mission and Purpose.

    ERIC Educational Resources Information Center

    Cargol, Owen F.

    Based upon a planning project initiated at North Idaho College (NIC) in 1981 and approved by the Board of Trustees in 1982, this long-range plan states the mission of NIC and specifies goals and objectives to be attained in the next 3 years. First, introductory sections consider the qualities of a good long-range plan, address the responsibilities…

  1. 7 CFR 1717.604 - Long-range engineering plans and construction work plans.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... construction work plans (CWPs) in form and substance as set forth in 7 CFR part 1710, subpart F. (b... 7 Agriculture 11 2010-01-01 2010-01-01 false Long-range engineering plans and construction work... AND GUARANTEED ELECTRIC LOANS Operational Controls § 1717.604 Long-range engineering plans...

  2. 48 CFR 1405.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false Release of long-range acquisition estimates. 1405.404 Section 1405.404 Federal Acquisition Regulations System DEPARTMENT OF THE... Release of long-range acquisition estimates....

  3. 48 CFR 1305.404 - Release of long-range acquisition estimates.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false Release of long-range acquisition estimates. 1305.404 Section 1305.404 Federal Acquisition Regulations System DEPARTMENT OF COMMERCE... long-range acquisition estimates....

  4. 7 CFR 1717.604 - Long-range engineering plans and construction work plans.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... construction work plans (CWPs) in form and substance as set forth in 7 CFR part 1710, subpart F. (b... 7 Agriculture 11 2011-01-01 2011-01-01 false Long-range engineering plans and construction work... AND GUARANTEED ELECTRIC LOANS Operational Controls § 1717.604 Long-range engineering plans...

  5. 7 CFR 1717.604 - Long-range engineering plans and construction work plans.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... construction work plans (CWPs) in form and substance as set forth in 7 CFR part 1710, subpart F. (b... 7 Agriculture 11 2013-01-01 2013-01-01 false Long-range engineering plans and construction work... AND GUARANTEED ELECTRIC LOANS Operational Controls § 1717.604 Long-range engineering plans...

  6. 7 CFR 1717.604 - Long-range engineering plans and construction work plans.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... construction work plans (CWPs) in form and substance as set forth in 7 CFR part 1710, subpart F. (b... 7 Agriculture 11 2014-01-01 2014-01-01 false Long-range engineering plans and construction work... AND GUARANTEED ELECTRIC LOANS Operational Controls § 1717.604 Long-range engineering plans...

  7. 7 CFR 1717.604 - Long-range engineering plans and construction work plans.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... construction work plans (CWPs) in form and substance as set forth in 7 CFR part 1710, subpart F. (b... 7 Agriculture 11 2012-01-01 2012-01-01 false Long-range engineering plans and construction work... AND GUARANTEED ELECTRIC LOANS Operational Controls § 1717.604 Long-range engineering plans...

  8. Radial metallicity gradients in spiral galaxies from H II regions and planetary nebulae: probing galactic chemical evolution

    NASA Astrophysics Data System (ADS)

    Stanghellini, Letizia

    2015-08-01

    Radial metallicity gradients, typically observed in spiral galaxies, are excellent constraints for chemical evolution models. The contemporary studies of the two stellar populations, whose progenitors have formed at different times, yield to the chemical and time constraining of the models. In this context, planetary nebula and HII region analysis proved to be ideal two-epochs test populations. We present an assortment of galaxies whose oxygen abundances have been determined both with weak- and strong-line methods, and whose radial metallicity gradients and their evolution in time have disclosed very interesting correlations with the galaxy characteristics. New results from our Gemini/GMOS observations, and a review of the best literature data, set the stage for a better understanding of spiral galaxy evolution.

  9. QUANTIFYING UNCERTAINTY IN LONG RANGE TRANSPORT MODELS: WORKSHOP REPORT ON SOURCES AND EVALUATION OF UNCERTAINTY IN LONG-RANGE TRANSPORT MODELS

    EPA Science Inventory

    The quantification of uncertainty in long-range transport model predictions and the implications of these uncertainties on formulations of control policy have been the subject of investigations by both the United States and Canada. To more fully address these topics, the American...

  10. Synthesis and Characterization of Biomimetic Hydroxyapatite Nanoconstruct Using Chemical Gradient across Lipid Bilayer.

    PubMed

    Koirala, Mukund Bahadur; Nguyen, Tuyen Duong Thanh; Pitchaimani, Arunkumar; Choi, Seong-O; Aryal, Santosh

    2015-12-16

    In this study, we synthesized biomimetic hydroxyapatite nanoconstruct (nanosized hydroxyapatite, NHAp) using a double emulsion technique combined with a chemical gradient across a lipid bilayer for surface modification of a titanium (Ti) implant. The synthesized NHAp was characterized by dynamic light scattering, X-ray diffraction, transmission electron microscopy, and Fourier transform infrared (FTIR) spectroscopy, and it was further tested for its biocompatibility and in vitro proliferation efficacy using normal human osteoblasts (NHOst). The results showed that the synthesized NHAp had a hydrodynamic diameter of ∼200 nm with high aqueous stability. The chemistry of the NHAp was confirmed by FTIR spectroscopic analysis. Typical FTIR vibrational bands corresponding to the phosphate group (PO4(3-)) present in hydroxyapatite (HAp) were observed at 670, 960, and 1000 cm(-1). A broad band at 3500 cm(-1) confirmed the presence of a structural -OH group in the NHAp. Powder X-ray crystallographic diffraction further confirmed the formation of NHAp with characteristic reflections in (002), (211), (130), and (213) planes at respective 2θ degrees. These reflection planes are similar to those of typical HAp crystallized toward (002) and (211) crystallographic planes. The mechanism of the formation of NHAp was studied using the fluorescence resonance energy transfer (FRET) technique. The FRET study showed the fluorescent recovery of a donor fluorophore and the mechanism of the insertion of lipids into nanodroplets obtained from the first water-in-oil (w/o) emulsion during the formation of the second oil-in-water (o/w) emulsion. With these confirmations, we further studied NHOst cell proliferation on a Ti surface. When NHOst were cultured on the Ti surface coated with the NHAp, a distinct proliferation pattern and cell-cell communication via cytoplasmic extension on the substrate surface were observed. In contrast, a bare Ti surface showed diminished cell size with minimal

  11. Assessment of the efficiency of long-range corrected functionals for some properties of large compounds

    NASA Astrophysics Data System (ADS)

    Jacquemin, Denis; Perpète, Eric A.; Scalmani, Giovanni; Frisch, Michael J.; Kobayashi, Rika; Adamo, Carlo

    2007-04-01

    Using the long-range correction (LC) density functional theory (DFT) scheme introduced by Iikura et al. [J. Chem. Phys. 115, 3540 (2001)] and the Coulomb-attenuating model (CAM-B3LYP) of Yanai et al. [Chem. Phys. Lett. 393, 51 (2004)], we have calculated a series of properties that are known to be poorly reproduced by standard functionals: Bond length alternation of π-conjugated polymers, polarizabilities of delocalized chains, and electronic spectra of extended dyes. For each of these properties, we present cases in which traditional hybrid functionals do provide accurate results and cases in which they fail to reproduce the correct trends. The quality of the results is assessed with regard to experimental values and/or data arising from electron-correlated wave function approaches. It turns out that (i) both LC-DFT and CAM-B3LYP provide an accurate bond length alternation for polyacetylene and polymethineimine, although for the latter they decrease slightly too rapidly with chain length. (ii) The LC generalized gradient approximation and MP2 polarizabilities of long polyphosphazene and polymethineimine oligomers agree almost perfectly. In the same way, CAM-B3LYP corrects the major part of the B3LYP faults. (iii) LC and CAM techniques do not help in correcting the nonrealistic evolution with chain length of the absorption wavelengths of cyanine derivatives. In addition, though both schemes significantly overestimate the ground to excited state transition energy of substituted anthraquinone dyes, they provide a more consistent picture once a statistical treatment is performed than do traditional hybrid functionals.

  12. Critical behavior of su(1|1) supersymmetric spin chains with long-range interactions

    NASA Astrophysics Data System (ADS)

    Carrasco, José A.; Finkel, Federico; González-López, Artemio; Rodríguez, Miguel A.; Tempesta, Piergiulio

    2016-06-01

    We introduce a general class of su (1 |1 ) supersymmetric spin chains with long-range interactions which includes as particular cases the su (1 |1 ) Inozemtsev (elliptic) and Haldane-Shastry chains, as well as the XX model. We show that this class of models can be fermionized with the help of the algebraic properties of the su (1 |1 ) permutation operator and take advantage of this fact to analyze their quantum criticality when a chemical potential term is present in the Hamiltonian. We first study the low-energy excitations and the low-temperature behavior of the free energy, which coincides with that of a (1 +1 ) -dimensional conformal field theory (CFT) with central charge c =1 when the chemical potential lies in the critical interval ( 0 ,E (π )) , E (p ) being the dispersion relation. We also analyze the von Neumann and Rényi ground state entanglement entropies, showing that they exhibit the logarithmic scaling with the size of the block of spins characteristic of a one-boson (1 +1 ) -dimensional CFT. Our results thus show that the models under study are quantum critical when the chemical potential belongs to the critical interval, with central charge c =1 . From the analysis of the fermion density at zero temperature, we also conclude that there is a quantum phase transition at both ends of the critical interval. This is further confirmed by the behavior of the fermion density at finite temperature, which is studied analytically (at low temperature), as well as numerically for the su (1 |1 ) elliptic chain.

  13. Critical behavior of su(1|1) supersymmetric spin chains with long-range interactions.

    PubMed

    Carrasco, José A; Finkel, Federico; González-López, Artemio; Rodríguez, Miguel A; Tempesta, Piergiulio

    2016-06-01

    We introduce a general class of su(1|1) supersymmetric spin chains with long-range interactions which includes as particular cases the su(1|1) Inozemtsev (elliptic) and Haldane-Shastry chains, as well as the XX model. We show that this class of models can be fermionized with the help of the algebraic properties of the su(1|1) permutation operator and take advantage of this fact to analyze their quantum criticality when a chemical potential term is present in the Hamiltonian. We first study the low-energy excitations and the low-temperature behavior of the free energy, which coincides with that of a (1+1)-dimensional conformal field theory (CFT) with central charge c=1 when the chemical potential lies in the critical interval (0,E(π)), E(p) being the dispersion relation. We also analyze the von Neumann and Rényi ground state entanglement entropies, showing that they exhibit the logarithmic scaling with the size of the block of spins characteristic of a one-boson (1+1)-dimensional CFT. Our results thus show that the models under study are quantum critical when the chemical potential belongs to the critical interval, with central charge c=1. From the analysis of the fermion density at zero temperature, we also conclude that there is a quantum phase transition at both ends of the critical interval. This is further confirmed by the behavior of the fermion density at finite temperature, which is studied analytically (at low temperature), as well as numerically for the su(1|1) elliptic chain. PMID:27415204

  14. Dielectrophoretic characterization of cells in a stationary nanoliter droplet array with generated chemical gradients.

    PubMed

    Ben-Arye, Tom; Park, Sinwook; Shemesh, Jonathan; Peer, Dan; Levenberg, Shulamit; Yossifon, Gilad

    2015-10-01

    A novel design of reusable microfluidic platform that generates a stationary nanoliter droplet array (SNDA) for cell incubation and analysis, equipped with a complementary array of individually addressable electrodes for each microwell is studied. Various solute concentration gradients were generated between the wells where dielectrophoresis (DEP) was used to characterize the effect of the gradients on the cell's response. The feasibility of generating concentration gradients and observation of DEP responses was demonstrated using a gradient of salts in combination with microparticles and viable cells. L1210 Lymphoma cells were used as the model cells in these experiments. Lymphoma cells' cross-over frequency (COF) decreased with increasing stress conditions. Specifically, a linear decrease in the cell COF was measured as a function of solution tonicity and blebbistatin dose. Lymphoma cells were incubated under a gradient of the chemotherapeutic agent doxorubicin (DOX), which led to saturation in the cell-COF response at 30 nM DOX, demonstrating the potential of the platform in screening of label-free drugs. PMID:26286862

  15. Role of Long-Range Protein Dynamics in Different Thymidylate Synthase Catalyzed Reactions

    PubMed Central

    Abeysinghe, Thelma; Kohen, Amnon

    2015-01-01

    Recent studies of Escherichia coli thymidylate synthase (ecTSase) showed that a highly conserved residue, Y209, that is located 8 Å away from the reaction site, plays a key role in the protein’s dynamics. Those crystallographic studies indicated that Y209W mutant is a structurally identical but dynamically altered relative to the wild type (WT) enzyme, and that its turnover catalytic rate governed by a slow hydride-transfer has been affected. The most challenging test of an examination of a fast chemical conversion that precedes the rate-limiting step has been achieved here. The physical nature of both fast and slow C-H bond activations have been compared between the WT and mutant by means of observed and intrinsic kinetic isotope effects (KIEs) and their temperature dependence. The findings indicate that the proton abstraction step has not been altered as much as the hydride transfer step. Additionally, the comparison indicated that other kinetic steps in the TSase catalyzed reaction were substantially affected, including the order of the substrate binding. Enigmatically, although Y209 is H-bonded to 3'-OH of 2'-deoxyuridine-5'-mono­phosphate (dUMP), its altered dynamics is more pronounced on the binding of the remote cofactor, (6R)-N5,N10-methylene-5,6,7,8-tetrahydrofolate (CH2H4folate), revealing the importance of long-range dynamics of the enzymatic complex and its catalytic function. PMID:25837629

  16. Long-range interactions between polar bialkali ground-state molecules in arbitrary vibrational levels

    NASA Astrophysics Data System (ADS)

    Vexiau, R.; Lepers, M.; Aymar, M.; Bouloufa-Maafa, N.; Dulieu, O.

    2015-06-01

    We have calculated the isotropic C6 coefficients characterizing the long-range van der Waals interaction between two identical heteronuclear alkali-metal diatomic molecules in the same arbitrary vibrational level of their ground electronic state X1Σ+. We consider the ten species made up of 7Li, 23Na, 39K, 87Rb, and 133Cs. Following our previous work [Lepers et al., Phys. Rev. A 88, 032709 (2013)], we use the sum-over-state formula inherent to the second-order perturbation theory, composed of the contributions from the transitions within the ground state levels, from the transition between ground-state and excited state levels, and from a crossed term. These calculations involve a combination of experimental and quantum-chemical data for potential energy curves and transition dipole moments. We also investigate the case where the two molecules are in different vibrational levels and we show that the Moelwyn-Hughes approximation is valid provided that it is applied for each of the three contributions to the sum-over-state formula. Our results are particularly relevant in the context of inelastic and reactive collisions between ultracold bialkali molecules in deeply bound or in Feshbach levels.

  17. Emergent ultra–long-range interactions between active particles in hybrid active–inactive systems

    NASA Astrophysics Data System (ADS)

    Steimel, Joshua P.; Aragones, Juan L.; Hu, Helen; Qureshi, Naser

    2016-04-01

    Particle–particle interactions determine the state of a system. Control over the range of such interactions as well as their magnitude has been an active area of research for decades due to the fundamental challenges it poses in science and technology. Very recently, effective interactions between active particles have gathered much attention as they can lead to out-of-equilibrium cooperative states such as flocking. Inspired by nature, where active living cells coexist with lifeless objects and structures, here we study the effective interactions that appear in systems composed of active and passive mixtures of colloids. Our systems are 2D colloidal monolayers composed primarily of passive (inactive) colloids, and a very small fraction of active (spinning) ferromagnetic colloids. We find an emergent ultra–long-range attractive interaction induced by the activity of the spinning particles and mediated by the elasticity of the passive medium. Interestingly, the appearance of such interaction depends on the spinning protocol and has a minimum actuation timescale below which no attraction is observed. Overall, these results clearly show that, in the presence of elastic components, active particles can interact across very long distances without any chemical modification of the environment. Such a mechanism might potentially be important for some biological systems and can be harnessed for newer developments in synthetic active soft materials.

  18. Long-range wetting transparency on top of layered metal-dielectric substrates

    PubMed Central

    Noginov, M. A.; Barnakov, Yuri A.; Liberman, Vladimir; Prayakarao, Srujana; Bonner, Carl E.; Narimanov, Evgenii E.

    2016-01-01

    It has been recently shown that scores of physical and chemical phenomena (including spontaneous emission, scattering and Förster energy transfer) can be controlled by nonlocal dielectric environments provided by metamaterials with hyperbolic dispersion and simpler metal/dielectric structures. At this time, we have researched van der Waals interactions and experimentally studied wetting of several metallic, dielectric and composite multilayered substrates. We have found that the wetting angle of water on top of MgF2 is highly sensitive to the thickness of the MgF2 layer and the nature of the underlying substrate that could be positioned as far as ~100 nm beneath the water/MgF2 interface. We refer to this phenomenon as long range wetting transparency. The latter effect cannot be described in terms of the most basic model of dispersion van der Waals-London forces based on pair-wise summation of dipole-dipole interactions across an interface or a gap separating the two media. We infer that the experimentally observed gradual change of the wetting angle with increase of the thickness of the MgF2 layer can possibly be explained by the distance dependence of the Hamaker function (describing the strength of interaction), which originates from retardation of electromagnetic waves at the distances comparable to a wavelength. PMID:27324650

  19. Unmanned platform for long-range remote analysis of volatile compounds in air samples.

    PubMed

    da Costa, Eric T; Neves, Carlos A; Hotta, Guilherme M; Vidal, Denis T R; Barros, Marcelo F; Ayon, Arturo A; Garcia, Carlos D; do Lago, Claudimir Lucio

    2012-09-01

    This paper describes a long-range remotely controlled CE system built on an all-terrain vehicle. A four-stroke engine and a set of 12-V batteries were used to provide power to a series of subsystems that include drivers, communication, computers, and a capillary electrophoresis module. This dedicated instrument allows air sampling using a polypropylene porous tube, coupled to a flow system that transports the sample to the inlet of a fused-silica capillary. A hybrid approach was used for the construction of the analytical subsystem combining a conventional fused-silica capillary (used for separation) and a laser machined microfluidic block, made of PMMA. A solid-state cooling approach was also integrated in the CE module to enable controlling the temperature and therefore increasing the useful range of the robot. Although ultimately intended for detection of chemical warfare agents, the proposed system was used to analyze a series of volatile organic acids. As such, the system allowed the separation and detection of formic, acetic, and propionic acids with signal-to-noise ratios of 414, 150, and 115, respectively, after sampling by only 30 s and performing an electrokinetic injection during 2.0 s at 1.0 kV. PMID:22965708

  20. Emergent Ultra-Long-Range Interactions Between Active Particles in Hybrid Active-Inactive Systems

    NASA Astrophysics Data System (ADS)

    Steimel, Joshua; Aragones, Juan; Hu, Helen; Qureshi, Naser; Alexander-Katz, Alfredo

    Particle-particle interactions determine the state of a system. Control over the range and magnitude of such interactions has been an active area of research for decades due to the fundamental challenges it poses in science and technology. Effective interactions between active particles have gathered much attention as they can lead to out-of-equilibrium cooperative states such as flocking. Inspired by nature, where active living cells coexist with lifeless, immobile objects and structures, here we study the effective interactions that appear in systems composed of active and passive mixtures of colloids. Our system is a two dimensional colloidal monolayer composed primarily of passive (inactive) colloids and a very small fraction of active (sinning) ferromagnetic colloids. We find an emergent ultra-long-range attractive interaction between active particles induced by the activity of the spinning particles and mediated by the elasticity of the passive medium. Interestingly, the appearance of such interaction depends on the spinning protocol and has a minimum actuation time scale below which no attraction is observed. Overall, these results clearly show that in the presence of elastic components, active particles can interact across very long distances without any chemical modification of the environment. Such a mechanism might potentially be important for some biological systems and can be harnessed for newer developments in synthetic active soft materials.

  1. Long-range wetting transparency on top of layered metal-dielectric substrates

    NASA Astrophysics Data System (ADS)

    Noginov, M. A.; Barnakov, Yuri A.; Liberman, Vladimir; Prayakarao, Srujana; Bonner, Carl E.; Narimanov, Evgenii E.

    2016-06-01

    It has been recently shown that scores of physical and chemical phenomena (including spontaneous emission, scattering and Förster energy transfer) can be controlled by nonlocal dielectric environments provided by metamaterials with hyperbolic dispersion and simpler metal/dielectric structures. At this time, we have researched van der Waals interactions and experimentally studied wetting of several metallic, dielectric and composite multilayered substrates. We have found that the wetting angle of water on top of MgF2 is highly sensitive to the thickness of the MgF2 layer and the nature of the underlying substrate that could be positioned as far as ~100 nm beneath the water/MgF2 interface. We refer to this phenomenon as long range wetting transparency. The latter effect cannot be described in terms of the most basic model of dispersion van der Waals-London forces based on pair-wise summation of dipole-dipole interactions across an interface or a gap separating the two media. We infer that the experimentally observed gradual change of the wetting angle with increase of the thickness of the MgF2 layer can possibly be explained by the distance dependence of the Hamaker function (describing the strength of interaction), which originates from retardation of electromagnetic waves at the distances comparable to a wavelength.

  2. Role of long-range protein dynamics in different thymidylate synthase catalyzed reactions.

    PubMed

    Abeysinghe, Thelma; Kohen, Amnon

    2015-01-01

    Recent studies of Escherichia coli thymidylate synthase (ecTSase) showed that a highly conserved residue, Y209, that is located 8 Å away from the reaction site, plays a key role in the protein's dynamics. Those crystallographic studies indicated that Y209W mutant is a structurally identical but dynamically altered relative to the wild type (WT) enzyme, and that its turnover catalytic rate governed by a slow hydride-transfer has been affected. The most challenging test of an examination of a fast chemical conversion that precedes the rate-limiting step has been achieved here. The physical nature of both fast and slow C-H bond activations have been compared between the WT and mutant by means of observed and intrinsic kinetic isotope effects (KIEs) and their temperature dependence. The findings indicate that the proton abstraction step has not been altered as much as the hydride transfer step. Additionally, the comparison indicated that other kinetic steps in the TSase catalyzed reaction were substantially affected, including the order of the substrate binding. Enigmatically, although Y209 is H-bonded to 3'-OH of 2'-deoxyuridine-5'-mono-phosphate (dUMP), its altered dynamics is more pronounced on the binding of the remote cofactor, (6R)-N5,N10-methylene-5,6,7,8-tetrahydrofolate (CH2H4folate), revealing the importance of long-range dynamics of the enzymatic complex and its catalytic function. PMID:25837629

  3. Long-range wetting transparency on top of layered metal-dielectric substrates.

    PubMed

    Noginov, M A; Barnakov, Yuri A; Liberman, Vladimir; Prayakarao, Srujana; Bonner, Carl E; Narimanov, Evgenii E

    2016-01-01

    It has been recently shown that scores of physical and chemical phenomena (including spontaneous emission, scattering and Förster energy transfer) can be controlled by nonlocal dielectric environments provided by metamaterials with hyperbolic dispersion and simpler metal/dielectric structures. At this time, we have researched van der Waals interactions and experimentally studied wetting of several metallic, dielectric and composite multilayered substrates. We have found that the wetting angle of water on top of MgF2 is highly sensitive to the thickness of the MgF2 layer and the nature of the underlying substrate that could be positioned as far as ~100 nm beneath the water/MgF2 interface. We refer to this phenomenon as long range wetting transparency. The latter effect cannot be described in terms of the most basic model of dispersion van der Waals-London forces based on pair-wise summation of dipole-dipole interactions across an interface or a gap separating the two media. We infer that the experimentally observed gradual change of the wetting angle with increase of the thickness of the MgF2 layer can possibly be explained by the distance dependence of the Hamaker function (describing the strength of interaction), which originates from retardation of electromagnetic waves at the distances comparable to a wavelength. PMID:27324650

  4. Emergent ultra-long-range interactions between active particles in hybrid active-inactive systems.

    PubMed

    Steimel, Joshua P; Aragones, Juan L; Hu, Helen; Qureshi, Naser; Alexander-Katz, Alfredo

    2016-04-26

    Particle-particle interactions determine the state of a system. Control over the range of such interactions as well as their magnitude has been an active area of research for decades due to the fundamental challenges it poses in science and technology. Very recently, effective interactions between active particles have gathered much attention as they can lead to out-of-equilibrium cooperative states such as flocking. Inspired by nature, where active living cells coexist with lifeless objects and structures, here we study the effective interactions that appear in systems composed of active and passive mixtures of colloids. Our systems are 2D colloidal monolayers composed primarily of passive (inactive) colloids, and a very small fraction of active (spinning) ferromagnetic colloids. We find an emergent ultra-long-range attractive interaction induced by the activity of the spinning particles and mediated by the elasticity of the passive medium. Interestingly, the appearance of such interaction depends on the spinning protocol and has a minimum actuation timescale below which no attraction is observed. Overall, these results clearly show that, in the presence of elastic components, active particles can interact across very long distances without any chemical modification of the environment. Such a mechanism might potentially be important for some biological systems and can be harnessed for newer developments in synthetic active soft materials. PMID:27071096

  5. Long-range interactions between polar bialkali ground-state molecules in arbitrary vibrational levels

    SciTech Connect

    Vexiau, R.; Lepers, M. Aymar, M.; Bouloufa-Maafa, N.; Dulieu, O.

    2015-06-07

    We have calculated the isotropic C{sub 6} coefficients characterizing the long-range van der Waals interaction between two identical heteronuclear alkali-metal diatomic molecules in the same arbitrary vibrational level of their ground electronic state X{sup 1}Σ{sup +}. We consider the ten species made up of {sup 7}Li, {sup 23}Na, {sup 39}K, {sup 87}Rb, and {sup 133}Cs. Following our previous work [Lepers et al., Phys. Rev. A 88, 032709 (2013)], we use the sum-over-state formula inherent to the second-order perturbation theory, composed of the contributions from the transitions within the ground state levels, from the transition between ground-state and excited state levels, and from a crossed term. These calculations involve a combination of experimental and quantum-chemical data for potential energy curves and transition dipole moments. We also investigate the case where the two molecules are in different vibrational levels and we show that the Moelwyn-Hughes approximation is valid provided that it is applied for each of the three contributions to the sum-over-state formula. Our results are particularly relevant in the context of inelastic and reactive collisions between ultracold bialkali molecules in deeply bound or in Feshbach levels.

  6. Long Range Correlation of Hydrophilicity and Flexibility Along the Hemoglobin Chain

    SciTech Connect

    Craciun, D.; Isvoran, A.; Avram, N. M.

    2010-08-04

    Within this study, we reveal the long range correlation concerning hydrophilicity and flexibility along sequences of hemoglobins belonging to different organisms and we compare them with the long range correlations properties obtained for other protein families. For all hemoglobins considered, we investigate two discrete spatial series: the hydrophilicity and flexibility respectively. We apply the nonlinear analysis methods to analyze the two spatial series by calculating the spectral coefficient {beta}, the scaling exponent {alpha} and Hurst exponent H. The obtained values for the mentioned coefficients suggest long range correlation within the analyzed sequences of hemoglobins in good agreement with those obtained for the calcium binding proteins and hydrolases.

  7. Long-range dependence and multifractality in the term structure of LIBOR interest rates

    NASA Astrophysics Data System (ADS)

    Cajueiro, Daniel O.; Tabak, Benjamin M.

    2007-01-01

    In this paper we present evidence of long-range dependence in LIBOR interest rates. We study a data set from 2000 to 2005, for six different currencies and various maturities. Empirical results suggest that the degree of long-range dependence decreases with maturity, with the exception of interest rates on Japanese Yen and on Indonesian Rupiah. Furthermore, interest rates have a multifractal nature and the degree of multifractality is much stronger for Indonesia (emerging market). These findings suggest that interest rates derivatives should take these features into account. Furthermore, fixed income risk and portfolio management should incorporate long-range dependence in the modeling of interest rates.

  8. Ising-model description of long-range correlations in DNA sequences

    NASA Astrophysics Data System (ADS)

    Colliva, A.; Pellegrini, R.; Testori, A.; Caselle, M.

    2015-05-01

    We model long-range correlations of nucleotides in the human DNA sequence using the long-range one-dimensional (1D) Ising model. We show that, for distances between 103 and 106 bp, the correlations show a universal behavior and may be described by the non-mean-field limit of the long-range 1D Ising model. This allows us to make some testable hypothesis on the nature of the interaction between distant portions of the DNA chain which led to the DNA structure that we observe today in higher eukaryotes.

  9. Photon Devil's staircase: photon long-range repulsive interaction in lattices of coupled resonators with Rydberg atoms.

    PubMed

    Zhang, Yuanwei; Fan, Jingtao; Liang, J-Q; Ma, Jie; Chen, Gang; Jia, Suotang; Nori, Franco

    2015-01-01

    The realization of strong coherent interactions between individual photons is a long-standing goal in science and engineering. In this report, based on recent experimental setups, we derive a strong photon long-range repulsive interaction, by controlling the van der Waals repulsive force between Cesium Rydberg atoms located inside different cavities in extended Jaynes-Cummings-Hubbard lattices. We also find novel quantum phases induced by this photon long-range repulsive interaction. For example, without photon hopping, a photon Devil's staircase, induced by the breaking of long-range translation symmetry, can emerge. If photon hopping occurs, we predict a photon-floating solid phase, due to the motion of particle- and hole-like defects. More importantly, for a large chemical potential in the resonant case, the photon hopping can be frozen even if the hopping term exists. We call this new phase the photon-frozen solid phase. In experiments, these predicted phases could be detected by measuring the number of polaritons via resonance fluorescence. PMID:26108705

  10. Photon Devil’s staircase: photon long-range repulsive interaction in lattices of coupled resonators with Rydberg atoms

    NASA Astrophysics Data System (ADS)

    Zhang, Yuanwei; Fan, Jingtao; Liang, J.-Q.; Ma, Jie; Chen, Gang; Jia, Suotang; Nori, Franco

    2015-06-01

    The realization of strong coherent interactions between individual photons is a long-standing goal in science and engineering. In this report, based on recent experimental setups, we derive a strong photon long-range repulsive interaction, by controlling the van der Waals repulsive force between Cesium Rydberg atoms located inside different cavities in extended Jaynes-Cummings-Hubbard lattices. We also find novel quantum phases induced by this photon long-range repulsive interaction. For example, without photon hopping, a photon Devil’s staircase, induced by the breaking of long-range translation symmetry, can emerge. If photon hopping occurs, we predict a photon-floating solid phase, due to the motion of particle- and hole-like defects. More importantly, for a large chemical potential in the resonant case, the photon hopping can be frozen even if the hopping term exists. We call this new phase the photon-frozen solid phase. In experiments, these predicted phases could be detected by measuring the number of polaritons via resonance fluorescence.

  11. Photon Devil’s staircase: photon long-range repulsive interaction in lattices of coupled resonators with Rydberg atoms

    PubMed Central

    Zhang, Yuanwei; Fan, Jingtao; Liang, J.-Q.; Ma, Jie; Chen, Gang; Jia, Suotang; Nori, Franco

    2015-01-01

    The realization of strong coherent interactions between individual photons is a long-standing goal in science and engineering. In this report, based on recent experimental setups, we derive a strong photon long-range repulsive interaction, by controlling the van der Waals repulsive force between Cesium Rydberg atoms located inside different cavities in extended Jaynes-Cummings-Hubbard lattices. We also find novel quantum phases induced by this photon long-range repulsive interaction. For example, without photon hopping, a photon Devil’s staircase, induced by the breaking of long-range translation symmetry, can emerge. If photon hopping occurs, we predict a photon-floating solid phase, due to the motion of particle- and hole-like defects. More importantly, for a large chemical potential in the resonant case, the photon hopping can be frozen even if the hopping term exists. We call this new phase the photon-frozen solid phase. In experiments, these predicted phases could be detected by measuring the number of polaritons via resonance fluorescence. PMID:26108705

  12. Bacterial Fe(II) oxidation distinguished by long-range correlation in redox potential

    NASA Astrophysics Data System (ADS)

    Enright, Allison M. L.; Ferris, F. Grant

    2016-05-01

    The kinetics of bacterial Fe(II) oxidation was investigated 297 m underground at the Äspö Hard Rock Laboratory (near Oskarshamn, Sweden) under steady state groundwater flow conditions in a flow-through cell containing well-developed flocculent mats of bacteriogenic iron oxides (BIOS). Pseudo first-order rate constants of 0.004 min-1 and 0.009 min-1 were obtained for chemical and bacterial Fe(II) oxidation, respectively, based on the 104 min retention time of groundwater in the flow cell, inlet Fe(II) concentration of 21.0 ± 0.5 µm, outlet Fe(II) concentration of 8.5 ± 0.7 µm, as well as constant pH = - log H+ of 7.42 ± 0.01, dissolved O2 concentration of 0.11 ± 0.01 mg/L, and groundwater temperature of 12.4 ± 0.1°C. Redox potential was lower at the BIOS-free inlet (-135.4 ± 1.16 mV) compared to inside BIOS within the flow cell (-112.6 ± 1.91 mV), consistent with the Nernst relationship and oxidation of Fe(II) to Fe(III). Further evaluation of the redox potential time series data using detrended fluctuation analysis (DFA) revealed power law scaling in the amplitude of fluctuations over increasing intervals of time with significantly different (p < 0.01) DFA α scaling exponents of 1.89 ± 0.03 for BIOS and 1.67 ± 0.06 at the inlet. These α values not only signal the presence of long-range correlation in the redox potential time series measurements but also distinguish between the slower rate of chemical Fe(II) oxidation at the inlet and faster rate accelerated by FeOB in BIOS.

  13. Inter- and intraspecific variations of the chemical properties of high-Arctic mosses along water-regime gradients

    NASA Astrophysics Data System (ADS)

    Ueno, Takeshi; Osono, Takashi; Kanda, Hiroshi

    We examined and compared the contents of organic chemical components (lignin-like compounds, total carbohydrates and extractives), carbon and nutrients (nitrogen, phosphorus, potassium, calcium, magnesium) among the mosses Calliergon giganteum, Hylocomium splendens, Racomitrium lanuginosum, and among three populations of H. splendens collected from habitats in contrasting water regimes in the Canadian high-arctic tundra. C:N:P ratios were analyzed among and within moss species. Mosses from hydric habitats had lower total carbohydrate and higher nutrients contents than did mosses from drier habitats; however, we found no intraspecific variations in nitrogen and calcium contents in the different populations of H. splendens along water-regime gradients. The contents in lignin-like compounds, extractives and carbon showed no clear trends along water-regime gradients. Mosses from hydric habitats had lower C:N, C:P and N:P ratios than mosses from drier habitats, although we found no intraspecific variations in C:N ratios in H. splendens along water-regime gradients. These results suggest that chemical properties of mosses, especially nutrient contents, are strongly correlated with water availability in high-Arctic tundra.

  14. van der Waals forces in density functional theory: Perturbational long-range electron-interaction corrections

    SciTech Connect

    Angyan, Janos G.; Gerber, Iann C.; Savin, Andreas; Toulouse, Julien

    2005-07-15

    Long-range exchange and correlation effects, responsible for the failure of currently used approximate density functionals in describing van der Waals forces, are taken into account explicitly after a separation of the electron-electron interaction in the Hamiltonian into short- and long-range components. We propose a 'range-separated hybrid' functional based on a local density approximation for the short-range exchange-correlation energy, combined with a long-range exact exchange energy. Long-range correlation effects are added by a second-order perturbational treatment. The resulting scheme is general and is particularly well adapted to describe van der Waals complexes, such as rare gas dimers.

  15. Relationships Between Long-Range Lightning Networks and TRMM/LIS Observations

    NASA Technical Reports Server (NTRS)

    Rudlosky, Scott D.; Holzworth, Robert H.; Carey, Lawrence D.; Schultz, Chris J.; Bateman, Monte; Cummins, Kenneth L.; Cummins, Kenneth L.; Blakeslee, Richard J.; Goodman, Steven J.

    2012-01-01

    Recent advances in long-range lightning detection technologies have improved our understanding of thunderstorm evolution in the data sparse oceanic regions. Although the expansion and improvement of long-range lightning datasets have increased their applicability, these applications (e.g., data assimilation, atmospheric chemistry, and aviation weather hazards) require knowledge of the network detection capabilities. The present study intercompares long-range lightning data with observations from the Lightning Imaging Sensor (LIS) aboard the Tropical Rainfall Measurement Mission (TRMM) satellite. The study examines network detection efficiency and location accuracy relative to LIS observations, describes spatial variability in these performance metrics, and documents the characteristics of LIS flashes that are detected by the long-range networks. Improved knowledge of relationships between these datasets will allow researchers, algorithm developers, and operational users to better prepare for the spatial and temporal coverage of the upcoming GOES-R Geostationary Lightning Mapper (GLM).

  16. Possible causes of long-range dependence in the Brazilian stock market

    NASA Astrophysics Data System (ADS)

    Cajueiro, Daniel O.; Tabak, Benjamin M.

    2005-01-01

    While the presence of long-range dependence in the asset returns seems to be a stylized fact, the issue of arguing the possible causes of this phenomena is totally obscure. Trying to shed light in this problem, we investigate the possible sources of the long-range dependence phenomena in the Brazilian Stock Market. For this purpose, we employ a sample which comprises stocks traded in the Brazilian financial market (BOVESPA Index). The Hurst exponent here is considered as our measure of long-range dependence and it is evaluated by six different methods. We have found evidence of statistically significant rank correlation between specific variables of the Brazilian firms which subscribe stocks and the long-range dependence phenomena present in these stocks.

  17. Modeling of Long-Range Atmospheric Lasercom Links Between Static and Mobile Platforms

    SciTech Connect

    Scharlemann, E T; Breitfeller, E F; Henderson, J R; Kallman, J S; Morris, J R; Ruggiero, A J

    2003-07-29

    We describe modeling and simulation of long-range terrestrial laser communications links between static and mobile platforms. Atmospheric turbulence modeling, along with pointing, tracking and acquisition models are combined to provide an overall capability to estimate communications link performance.

  18. Motion planning in unstructured road for intelligent vehicle with long-range perception

    NASA Astrophysics Data System (ADS)

    Shi, Chaoxia; Wang, Yanqing; Yang, Jingyu; Liu, Hanxiang

    2011-10-01

    We present a novel motion planning method for intelligent vehicle with long-range perception under the uncertain constraints of unstructured road boundary on the basis of obstacle roadside fusion strategy and beam curvature method . Not only does this method inherit the advantages of reliability, smoothness and speediness from LCM, but also it can produce more reasonable path than traditional LCM does by virtue of the global information acquired by long-range sensors.

  19. High energy factorization in nucleus-nucleus collisions III. Long range rapidity correlations

    SciTech Connect

    Venugopalan, R.; Gelis, F., Lappi, T.

    2009-10-27

    We obtain a novel result in QCD for long range rapidity correlations between gluons produced in the collision of saturated high energy hadrons or nuclei. This result, obtained in a high energy factorization framework, provides strong justification for the Glasma flux tube picture of coherent strong color fields. Our formalism can be applied to 'near side ridge' events at the Relativistic Heavy Ion Collider and in future studies of long range rapidity correlations at the LHC.

  20. High energy factorization in nucleus-nucleus collisions. III. Long range rapidity correlations

    SciTech Connect

    Gelis, Francois

    2009-05-01

    We obtain a novel result in QCD for long range rapidity correlations between gluons produced in the collision of saturated high energy hadrons or nuclei. This result, obtained in a high energy factorization framework, provides strong justification for the Glasma flux tube picture of coherent strong color fields. Our formalism can be applied to 'near side ridge' events at the Relativistic Heavy Ion Collider and in future studies of long range rapidity correlations at the LHC.

  1. Long-range interactions and wave patterns in a DNA model.

    PubMed

    Tabi, C B; Mohamadou, A; Kofané, T C

    2010-07-01

    We propose a spin-like model of DNA nonlinear dynamics with long-range interactions between adjacent base pairs. We show that the model equation is a modified sine-Gordon equation. We perform the linear stability analysis of a plane wave, which predicts high-amplitude and extended oscillating waves for high values of the long-range parameter. This is confirmed numerically and biological implications of the obtained patterns are suggested. PMID:20676723

  2. Long-Range Correlations in Stride Intervals May Emerge from Non-Chaotic Walking Dynamics

    PubMed Central

    Ahn, Jooeun; Hogan, Neville

    2013-01-01

    Stride intervals of normal human walking exhibit long-range temporal correlations. Similar to the fractal-like behaviors observed in brain and heart activity, long-range correlations in walking have commonly been interpreted to result from chaotic dynamics and be a signature of health. Several mathematical models have reproduced this behavior by assuming a dominant role of neural central pattern generators (CPGs) and/or nonlinear biomechanics to evoke chaos. In this study, we show that a simple walking model without a CPG or biomechanics capable of chaos can reproduce long-range correlations. Stride intervals of the model revealed long-range correlations observed in human walking when the model had moderate orbital stability, which enabled the current stride to affect a future stride even after many steps. This provides a clear counterexample to the common hypothesis that a CPG and/or chaotic dynamics is required to explain the long-range correlations in healthy human walking. Instead, our results suggest that the long-range correlation may result from a combination of noise that is ubiquitous in biological systems and orbital stability that is essential in general rhythmic movements. PMID:24086274

  3. Statistical mechanics in biology: how ubiquitous are long-range correlations?

    NASA Technical Reports Server (NTRS)

    Stanley, H. E.; Buldyrev, S. V.; Goldberger, A. L.; Goldberger, Z. D.; Havlin, S.; Mantegna, R. N.; Ossadnik, S. M.; Peng, C. K.; Simons, M.

    1994-01-01

    The purpose of this opening talk is to describe examples of recent progress in applying statistical mechanics to biological systems. We first briefly review several biological systems, and then focus on the fractal features characterized by the long-range correlations found recently in DNA sequences containing non-coding material. We discuss the evidence supporting the finding that for sequences containing only coding regions, there are no long-range correlations. We also discuss the recent finding that the exponent alpha characterizing the long-range correlations increases with evolution, and we discuss two related models, the insertion model and the insertion-deletion model, that may account for the presence of long-range correlations. Finally, we summarize the analysis of long-term data on human heartbeats (up to 10(4) heart beats) that supports the possibility that the successive increments in the cardiac beat-to-beat intervals of healthy subjects display scale-invariant, long-range "anti-correlations" (a tendency to beat faster is balanced by a tendency to beat slower later on). In contrast, for a group of subjects with severe heart disease, long-range correlations vanish. This finding suggests that the classical theory of homeostasis, according to which stable physiological processes seek to maintain "constancy," should be extended to account for this type of dynamical, far from equilibrium, behavior.

  4. Implementation and benchmark of a long-range corrected functional in the density functional based tight-binding method.

    PubMed

    Lutsker, V; Aradi, B; Niehaus, T A

    2015-11-14

    Bridging the gap between first principles methods and empirical schemes, the density functional based tight-binding method (DFTB) has become a versatile tool in predictive atomistic simulations over the past years. One of the major restrictions of this method is the limitation to local or gradient corrected exchange-correlation functionals. This excludes the important class of hybrid or long-range corrected functionals, which are advantageous in thermochemistry, as well as in the computation of vibrational, photoelectron, and optical spectra. The present work provides a detailed account of the implementation of DFTB for a long-range corrected functional in generalized Kohn-Sham theory. We apply the method to a set of organic molecules and compare ionization potentials and electron affinities with the original DFTB method and higher level theory. The new scheme cures the significant overpolarization in electric fields found for local DFTB, which parallels the functional dependence in first principles density functional theory (DFT). At the same time, the computational savings with respect to full DFT calculations are not compromised as evidenced by numerical benchmark data. PMID:26567646

  5. Implementation and benchmark of a long-range corrected functional in the density functional based tight-binding method

    SciTech Connect

    Lutsker, V.; Niehaus, T. A.; Aradi, B.

    2015-11-14

    Bridging the gap between first principles methods and empirical schemes, the density functional based tight-binding method (DFTB) has become a versatile tool in predictive atomistic simulations over the past years. One of the major restrictions of this method is the limitation to local or gradient corrected exchange-correlation functionals. This excludes the important class of hybrid or long-range corrected functionals, which are advantageous in thermochemistry, as well as in the computation of vibrational, photoelectron, and optical spectra. The present work provides a detailed account of the implementation of DFTB for a long-range corrected functional in generalized Kohn-Sham theory. We apply the method to a set of organic molecules and compare ionization potentials and electron affinities with the original DFTB method and higher level theory. The new scheme cures the significant overpolarization in electric fields found for local DFTB, which parallels the functional dependence in first principles density functional theory (DFT). At the same time, the computational savings with respect to full DFT calculations are not compromised as evidenced by numerical benchmark data.

  6. Implementation and benchmark of a long-range corrected functional in the density functional based tight-binding method

    NASA Astrophysics Data System (ADS)

    Lutsker, V.; Aradi, B.; Niehaus, T. A.

    2015-11-01

    Bridging the gap between first principles methods and empirical schemes, the density functional based tight-binding method (DFTB) has become a versatile tool in predictive atomistic simulations over the past years. One of the major restrictions of this method is the limitation to local or gradient corrected exchange-correlation functionals. This excludes the important class of hybrid or long-range corrected functionals, which are advantageous in thermochemistry, as well as in the computation of vibrational, photoelectron, and optical spectra. The present work provides a detailed account of the implementation of DFTB for a long-range corrected functional in generalized Kohn-Sham theory. We apply the method to a set of organic molecules and compare ionization potentials and electron affinities with the original DFTB method and higher level theory. The new scheme cures the significant overpolarization in electric fields found for local DFTB, which parallels the functional dependence in first principles density functional theory (DFT). At the same time, the computational savings with respect to full DFT calculations are not compromised as evidenced by numerical benchmark data.

  7. Application of a salt gradient solar pond to a chemical process industry

    SciTech Connect

    Ochs, T.L.; Johnson, S.C.; Sadan, A.

    1981-01-01

    A method is described for establishing a salinity gradient for a solar pond for the purpose of increasing the magnesium yield of an electrolysis plant on the Great Salt Lake. The method is to start with the filled pond, layer on an incremental thickness of fresh water, and allow surface wave action to mix this layer with the dense brine below. This is to be repeated until a sufficient gradient zone is produced. A rubber sheet is floated on the pond surface and water is allowed to flow slowly and continuously onto the sheet, thus avoiding turbulance and mixing at the injection site. Temperature and specific gravity profiles are given for the pond. (LEW)

  8. Variability in chemical defense across a shallow to mesophotic depth gradient in the Caribbean sponge Plakortis angulospiculatus

    NASA Astrophysics Data System (ADS)

    Slattery, Marc; Gochfeld, Deborah J.; Diaz, M. Cristina; Thacker, Robert W.; Lesser, Michael P.

    2016-03-01

    The transition between shallow and mesophotic coral reef communities in the tropics is characterized by a significant gradient in abiotic and biotic conditions that could result in potential trade-offs in energy allocation. The mesophotic reefs in the Bahamas and the Cayman Islands have a rich sponge fauna with significantly greater percent cover of sponges than in their respective shallow reef communities, but relatively low numbers of spongivores. Plakortis angulospiculatus, a common sponge species that spans the depth gradient from shallow to mesophotic reefs in the Caribbean, regenerates faster following predation and invests more energy in protein synthesis at mesophotic depths compared to shallow reef conspecifics. However, since P. angulospiculatus from mesophotic reefs typically contain lower concentrations of chemical feeding deterrents, they are not able to defend new tissue from predation as efficiently as conspecifics from shallow reefs. Nonetheless, following exposure to predators on shallow reefs, transplanted P. angulospiculatus from mesophotic depths developed chemical deterrence to predatory fishes. A survey of bioactive extracts indicated that a specific defensive metabolite, plakortide F, varied in concentration with depth, producing altered deterrence between shallow and mesophotic reef P. angulospiculatus. Different selective pressures in shallow and mesophotic habitats have resulted in phenotypic plasticity within this sponge species that is manifested in variable chemical defense and tissue regeneration at wound sites.

  9. Noggin4 is a long-range inhibitor of Wnt8 signalling that regulates head development in Xenopus laevis

    PubMed Central

    Eroshkin, Fedor M.; Nesterenko, Alexey M.; Borodulin, Alexander V.; Martynova, Natalia Yu.; Ermakova, Galina V.; Gyoeva, Fatima K.; Orlov, Eugeny E.; Belogurov, Alexey A.; Lukyanov, Konstantin A.; Bayramov, Andrey V.; Zaraisky, Andrey G.

    2016-01-01

    Noggin4 is a Noggin family secreted protein whose molecular and physiological functions remain unknown. In this study, we demonstrate that in contrast to other Noggins, Xenopus laevis Noggin4 cannot antagonise BMP signalling; instead, it specifically binds to Wnt8 and inhibits the Wnt/β -catenin pathway. Live imaging demonstrated that Noggin4 diffusivity in embryonic tissues significantly exceeded that of other Noggins. Using the Fluorescence Recovery After Photobleaching (FRAP) assay and mathematical modelling, we directly estimated the affinity of Noggin4 for Wnt8 in living embryos and determined that Noggin4 fine-tune the Wnt8 posterior-to-anterior gradient. Our results suggest a role for Noggin4 as a unique, freely diffusing, long-range inhibitor of canonical Wnt signalling, thus explaining its ability to promote head development. PMID:26973133

  10. {sup 63}Cu and {sup 197}Au nuclear quadrupole moments from four-component relativistic density-functional calculations using correct long-range exchange

    SciTech Connect

    Thierfelder, Christian; Schwerdtfeger, Peter; Saue, Trond

    2007-09-15

    The electric field gradient in late transition metal compounds is incorrectly determined by most density functionals. We show that the coupling of short-range density functional based with long-range wave function based methods using a reparametrization of the Coulomb-attenuated Becke three-parameter Lee-Yang-Parr approximation gives reliable results for the electric field gradients of copper and gold for a series of compounds. This results in nuclear quadrupole moments of -0.208 b for {sup 63}Cu and +0.526 b for {sup 197}Au in good agreement with experimental values of -0.220(15) and +0.547(16)b, respectively.

  11. The long-range transport of southern African aerosols to the tropical South Atlantic

    NASA Astrophysics Data System (ADS)

    Swap, R.; Garstang, M.; Macko, S. A.; Tyson, P. D.; Maenhaut, W.; Artaxo, P.; KâLlberg, P.; Talbot, R.

    1996-10-01

    Two episodes of long-range aerosol transport (4000 km) from southern Africa into the central tropical South Atlantic are documented. Stable nitrogen isotope analysis, multielemental analysis, and meteorological observations on local and regional scales are used to describe the observed surface aerosol chemistry during these transport episodes. The chemical, kinematic, and thermodynamic analyses suggest that for the central tropical South Atlantic, west Africa between 0° and 10°S is the primary air mass source region (over 50%) during austral spring. Over 70% of all air arriving in the lower and middle troposphere in the central tropical South Atlantic comes from a broad latitudinal band extending from 20°S to 10°N. Air coming from the east subsides and is trapped below the midlevel and trade wind inversion layers. Air from the west originates at higher levels (500 hPa) and contributes less than 30% of the air masses arriving in the central tropical South Atlantic. The source types of aerosols and precursor trace gases extend over a broad range of biomes from desert and savanna to the rain forest. During austral spring, over this broad region, processes include production from vegetation, soils, and biomass burning. The aerosol composition of air masses over and the atmospheric chemistry of the central South Atlantic is a function of the supply of biogenic, biomass burning, and aeolian emissions from tropical Africa. Rainfall is a common controlling factor for all three sources. Rain, in turn, is governed by the large-scale circulations which show pronounced interannual variability. The field measurements were taken in an extremely dry year and reflect the circulation and transport fields typical of these conditions.

  12. Assessing very long-range impacts from a rapid climate change

    SciTech Connect

    Markley, O.W.; Hall, P.R.

    1982-01-01

    A variety of anthropogenic, or human-generated forces are gradually changing global climate. These include effects due to slash and burn agriculture, industrial particulates, waste heat and gasses such as chlorofluoromethanes, nitrous oxide, and carbon dioxide. Although the short-range effects of these forces may seem to be relatively minor from a long-range perspective, climatologists warn that the long-range effects - especially of increases in atmospheric carbon dioxide resulting from widespread fossil fuel use - will be great, bringing significant alterations in atmospheric temperature, wind and ocean currents, precipitation patterns, and other ecological phenomena. From a geological time perspective, the resulting climate changes will occur quite rapidly, and will affect human concerns in a number of ways. Besides being important for long-range social planning, these effects are of intrinsic interest to futures research and impact assessment methodologists. Although many uncertainties exist in long-range climate forecasting, climate change comprises one of the very few classes of phenomena where the nature of very long-range (i.e., 30 to 3000 years) impact-producing changes are feasible to forecast in reasonably rigorous, quantitative terms.

  13. Hierarchical organization of long-range circuits in the olfactory cortices

    PubMed Central

    Yang, Weiguo; Sun, Qian-Quan

    2015-01-01

    How sensory information is processed within olfactory cortices is unclear. Here, we examined long-range circuit wiring between different olfactory cortical regions of acute mouse brain slices using a channelrhodopsin-2 (ChR2)-based neuronal targeting approach. Our results provide detailed information regarding the synaptic properties of the reciprocal long-range monosynaptic glutamatergic projections (LRMGP) between and within anterior piriform cortex (aPC), posterior piriform cortex (pPC), and lateral entorhinal cortex (LEC), thereby creating a long-range inter- and intracortical circuit diagrams at the level of synapses and single cortical neurons. Our results reveal the following information regarding hierarchical intra- and intercortical organizations: (i) there is massive bottom-up (i.e., rostral–caudal) excitation within the LRMGP accompanied with strong feedforward (FF) inhibition; (ii) there are convergent FF connections onto LEC from both aPC and pPC; (iii) feedback (FB) intercortical connections are weak with a significant fraction of presumptive silent synapses; and (iv) intra and intercortical long-range connections lack layer specificity and their innervation of interneurons are stronger than neighboring pyramidal neurons. The elucidation of the distinct hierarchical organization of long-range olfactory cortical circuits paves the way for further understanding of higher order cortical processing within the olfactory system. PMID:26416972

  14. Aberrant long-range functional connectivity density in generalized tonic-clonic seizures.

    PubMed

    Zhu, Ling; Li, Yibo; Wang, Yifeng; Li, Rong; Zhang, Zhiqiang; Lu, Guangming; Chen, Huafu

    2016-06-01

    Studies in generalized tonic-clonic seizures (GTCS) have reported both structural and functional alterations in the brain. However, changes in spontaneous neuronal functional organization in GTCS remain largely unknown.In this study, 70 patients with idiopathic generalized epilepsy characterized by tonic-clonic seizures and 70 age- and sex-matched healthy controls were recruited. Here, functional connectivity density (FCD) mapping, an ultrafast data-driven method based on functional magnetic resonance imaging (fMRI), was applied for the first time to investigate the changes of spontaneous functional brain activity caused by epilepsy.The results showed significantly decreased long-range FCD in the middle and inferior temporal, prefrontal, and inferior parietal cortices as well as increased long-range FCD in the cerebellum anterior lobe and sensorimotor areas. Negative correlation between duration of disease and reduced long-range FCD was found. In addition, most regions with reduced long-range FCD showed decreased resting-state functional connectivity (rsFC) within default mode network.Negative correlation between duration of disease and long-range FCD may reflect an adverse consequence eventually from original. Furthermore, the observed FCD and rsFC alterations have been speculated to be associated with the social-cognitive impairments as well as motor control. Our study provided novel evidences to look into neuro-pathophysiological mechanisms underlying GTCS. PMID:27310985

  15. Long-range ordered vorticity patterns in living tissue induced by cell division

    PubMed Central

    Rossen, Ninna S.; Tarp, Jens M.; Mathiesen, Joachim; Jensen, Mogens H.; Oddershede, Lene B.

    2014-01-01

    In healthy blood vessels with a laminar blood flow, the endothelial cell division rate is low, only sufficient to replace apoptotic cells. The division rate significantly increases during embryonic development and under halted or turbulent flow. Cells in barrier tissue are connected and their motility is highly correlated. Here we investigate the long-range dynamics induced by cell division in an endothelial monolayer under non-flow conditions, mimicking the conditions during vessel formation or around blood clots. Cell divisions induce long-range, well-ordered vortex patterns extending several cell diameters away from the division site, in spite of the system’s low Reynolds number. Our experimental results are reproduced by a hydrodynamic continuum model simulating division as a local pressure increase corresponding to a local tension decrease. Such long-range physical communication may be crucial for embryonic development and for healing tissue, for instance around blood clots. PMID:25483750

  16. Emergent long-range synchronization of oscillating ecological populations without external forcing described by Ising universality

    PubMed Central

    Noble, Andrew E.; Machta, Jonathan; Hastings, Alan

    2015-01-01

    Understanding the synchronization of oscillations across space is fundamentally important to many scientific disciplines. In ecology, long-range synchronization of oscillations in spatial populations may elevate extinction risk and signal an impending catastrophe. The prevailing assumption is that synchronization on distances longer than the dispersal scale can only be due to environmental correlation (the Moran effect). In contrast, we show how long-range synchronization can emerge over distances much longer than the length scales of either dispersal or environmental correlation. In particular, we demonstrate that the transition from incoherence to long-range synchronization of two-cycle oscillations in noisy spatial population models is described by the Ising universality class of statistical physics. This result shows, in contrast to all previous work, how the Ising critical transition can emerge directly from the dynamics of ecological populations. PMID:25851364

  17. Density of states and magnetotransport in Weyl semimetals with long-range disorder

    NASA Astrophysics Data System (ADS)

    Pesin, D. A.; Mishchenko, E. G.; Levchenko, A.

    2015-11-01

    We study the density of states and magnetotransport properties of disordered Weyl semimetals, focusing on the case of a strong long-range disorder. To calculate the disorder-averaged density of states close to nodal points, we treat exactly the long-range random potential fluctuations produced by charged impurities, while the short-range component of disorder potential is included systematically and controllably with the help of a diagram technique. We find that, for energies close to the degeneracy point, long-range potential fluctuations lead to a finite density of states. In the context of transport, we discuss that a self-consistent theory of screening in magnetic field may conceivably lead to nonmonotonic low-field magnetoresistance.

  18. UTag: Long-range Ultra-wideband Passive Radio Frequency Tags

    SciTech Connect

    Dowla, F

    2007-03-14

    Long-range, ultra-wideband (UWB), passive radio frequency (RF) tags are key components in Radio Frequency IDentification (RFID) system that will revolutionize inventory control and tracking applications. Unlike conventional, battery-operated (active) RFID tags, LLNL's small UWB tags, called 'UTag', operate at long range (up to 20 meters) in harsh, cluttered environments. Because they are battery-less (that is, passive), they have practically infinite lifetimes without human intervention, and they are lower in cost to manufacture and maintain than active RFID tags. These robust, energy-efficient passive tags are remotely powered by UWB radio signals, which are much more difficult to detect, intercept, and jam than conventional narrowband frequencies. The features of long range, battery-less, and low cost give UTag significant advantage over other existing RFID tags.

  19. Exact Diagonalization of a Quantum XXZ Model with Long-Range Interactions

    NASA Astrophysics Data System (ADS)

    Williams, Justin A.; Smith, David A.; Wang, C. C.-Joseph; Varney, Christopher N.

    In recent years, rapid advancement has been made in using ultra-cold gases as quantum spin simulators, with two dimensional lattices becoming a rich target for exploring the exotic states and excitations of spin-1/2 systems on frustrated lattices. When the interaction in the system becomes long-ranged, the spins are frustrated by the long-range interaction. Consequently, the competition between the geometric frustration and the long-range interaction results in the the underlying orders present in the ground state being unclear. Here, we investigate the quantum dipolar XXZ model with exact diagonalization to characterize and contrast the ground state and excitations on square and triangular lattices to provide a baseline for comparison with experiments. University of West Florida Summer Undergraduate Research Program, University of West Florida Quality Enhancement Plan Award.

  20. Spreading of Perturbations in Long-Range Interacting Classical Lattice Models

    NASA Astrophysics Data System (ADS)

    Métivier, David; Bachelard, Romain; Kastner, Michael

    2014-05-01

    Lieb-Robinson-type bounds are reported for a large class of classical Hamiltonian lattice models. By a suitable rescaling of energy or time, such bounds can be constructed for interactions of arbitrarily long range. The bound quantifies the dependence of the system's dynamics on a perturbation of the initial state. The effect of the perturbation is found to be effectively restricted to the interior of a causal region of logarithmic shape, with only small, algebraically decaying effects in the exterior. A refined bound, sharper than conventional Lieb-Robinson bounds, is required to correctly capture the shape of the causal region, as confirmed by numerical results for classical long-range XY chains. We discuss the relevance of our findings for the relaxation to equilibrium of long-range interacting lattice models.

  1. Cross-Sensor Calibration of the GAI Long Range Detection Network

    NASA Technical Reports Server (NTRS)

    Boccippio, Dennis J.; Boeck, William; Goodman, Steven J.; Cummins, K.; Cramer, J.

    1999-01-01

    The long range component of the North American Lightning Detection Network has been providing experimental data products since July 1996, offering cloud-to-ground lightning coverage throughout the Atlantic and Western Pacific oceans, as well as south to the Intertropical Convergence Zone. The network experiences a strong decrease in detection efficiency with range, which is also significantly modulated by differential propagation under day, night and terminator-crossing conditions. A climatological comparison of total lightning data observed by the Optical Transient Detector (OTD) and CG lightning observed by the long range network is conducted, with strict quality control and allowance for differential network performance before and after the activation of the Canadian Lightning Detection Network. This yields a first-order geographic estimate of long range network detection efficiency and its spatial variability. Intercomparisons are also performed over the continental US, allowing large scale estimates of the midlatitude climatological IC:CG ratio and its possible dependence on latitude.

  2. Long-Range Coulomb Effect in Intense Laser-Driven Photoelectron Dynamics

    NASA Astrophysics Data System (ADS)

    Quan, Wei; Hao, Xiaolei; Chen, Yongju; Yu, Shaogang; Xu, Songpo; Wang, Yanlan; Sun, Renping; Lai, Xuanyang; Wu, Chengyin; Gong, Qihuang; He, Xiantu; Liu, Xiaojun; Chen, Jing

    2016-06-01

    In strong field atomic physics community, long-range Coulomb interaction has for a long time been overlooked and its significant role in intense laser-driven photoelectron dynamics eluded experimental observations. Here we report an experimental investigation of the effect of long-range Coulomb potential on the dynamics of near-zero-momentum photoelectrons produced in photo-ionization process of noble gas atoms in intense midinfrared laser pulses. By exploring the dependence of photoelectron distributions near zero momentum on laser intensity and wavelength, we unambiguously demonstrate that the long-range tail of the Coulomb potential (i.e., up to several hundreds atomic units) plays an important role in determining the photoelectron dynamics after the pulse ends.

  3. Long-Range Coulomb Effect in Intense Laser-Driven Photoelectron Dynamics

    PubMed Central

    Quan, Wei; Hao, XiaoLei; Chen, YongJu; Yu, ShaoGang; Xu, SongPo; Wang, YanLan; Sun, RenPing; Lai, XuanYang; Wu, ChengYin; Gong, QiHuang; He, XianTu; Liu, XiaoJun; Chen, Jing

    2016-01-01

    In strong field atomic physics community, long-range Coulomb interaction has for a long time been overlooked and its significant role in intense laser-driven photoelectron dynamics eluded experimental observations. Here we report an experimental investigation of the effect of long-range Coulomb potential on the dynamics of near-zero-momentum photoelectrons produced in photo-ionization process of noble gas atoms in intense midinfrared laser pulses. By exploring the dependence of photoelectron distributions near zero momentum on laser intensity and wavelength, we unambiguously demonstrate that the long-range tail of the Coulomb potential (i.e., up to several hundreds atomic units) plays an important role in determining the photoelectron dynamics after the pulse ends. PMID:27256904

  4. Long-Range Coulomb Effect in Intense Laser-Driven Photoelectron Dynamics.

    PubMed

    Quan, Wei; Hao, XiaoLei; Chen, YongJu; Yu, ShaoGang; Xu, SongPo; Wang, YanLan; Sun, RenPing; Lai, XuanYang; Wu, ChengYin; Gong, QiHuang; He, XianTu; Liu, XiaoJun; Chen, Jing

    2016-01-01

    In strong field atomic physics community, long-range Coulomb interaction has for a long time been overlooked and its significant role in intense laser-driven photoelectron dynamics eluded experimental observations. Here we report an experimental investigation of the effect of long-range Coulomb potential on the dynamics of near-zero-momentum photoelectrons produced in photo-ionization process of noble gas atoms in intense midinfrared laser pulses. By exploring the dependence of photoelectron distributions near zero momentum on laser intensity and wavelength, we unambiguously demonstrate that the long-range tail of the Coulomb potential (i.e., up to several hundreds atomic units) plays an important role in determining the photoelectron dynamics after the pulse ends. PMID:27256904

  5. Long-range ordered vorticity patterns in living tissue induced by cell division

    NASA Astrophysics Data System (ADS)

    Rossen, Ninna S.; Tarp, Jens M.; Mathiesen, Joachim; Jensen, Mogens H.; Oddershede, Lene B.

    2014-12-01

    In healthy blood vessels with a laminar blood flow, the endothelial cell division rate is low, only sufficient to replace apoptotic cells. The division rate significantly increases during embryonic development and under halted or turbulent flow. Cells in barrier tissue are connected and their motility is highly correlated. Here we investigate the long-range dynamics induced by cell division in an endothelial monolayer under non-flow conditions, mimicking the conditions during vessel formation or around blood clots. Cell divisions induce long-range, well-ordered vortex patterns extending several cell diameters away from the division site, in spite of the system’s low Reynolds number. Our experimental results are reproduced by a hydrodynamic continuum model simulating division as a local pressure increase corresponding to a local tension decrease. Such long-range physical communication may be crucial for embryonic development and for healing tissue, for instance around blood clots.

  6. Nucleation in the presence of long-range interactions. [performed on ferroelectric barium titanate

    NASA Technical Reports Server (NTRS)

    Chandra, P.

    1989-01-01

    Unlike droplet nucleation near a liquid-gas critical point, the decay of metastable phases in crystalline materials is strongly affected by the presence of long-range forces. Field quench experiments performed on the ferroelectric barium titanate indicate that nucleation in this material is markedly different from that observed in liquids. In this paper, a theory for nucleation at a first-order phase transition in which the mediating forces are long range is presented. It is found that the long-range force induces cooperative nucleation and growth processes, and that this feedback mechanism produces a well-defined delay time with a sharp onset in the transformation to the stable phase. Closed-form expressions for the characteristic onset time and width of the transition are developed, in good agreement with numerical and experimental results.

  7. Fractality Evidence and Long-Range Dependence on Capital Markets: a Hurst Exponent Evaluation

    NASA Astrophysics Data System (ADS)

    Oprean, Camelia; Tănăsescu, Cristina

    2014-07-01

    Since the existence of market memory could implicate the rejection of the efficient market hypothesis, the aim of this paper is to find any evidence that selected emergent capital markets (eight European and BRIC markets, namely Hungary, Romania, Estonia, Czech Republic, Brazil, Russia, India and China) evince long-range dependence or the random walk hypothesis. In this paper, the Hurst exponent as calculated by R/S fractal analysis and Detrended Fluctuation Analysis is our measure of long-range dependence in the series. The results reinforce our previous findings and suggest that if stock returns present long-range dependence, the random walk hypothesis is not valid anymore and neither is the market efficiency hypothesis.

  8. Effect of disorder with long-range correlation on transport in graphene nanoribbon

    SciTech Connect

    Zhang, GP; Gao, M.; Zhang, Y.Y.; Liu, N.; Qin, Z.J.; Shanqqan, M.H.

    2012-06-13

    Transport in disordered armchair graphene nanoribbons (AGR) with long-range correlation between quantum wire contacts is investigated by a transfer matrix combined with Landauer's formula. The metal-insulator transition is induced by disorder in neutral AGR. Therein, the conductance is one conductance quantum for the metallic phase and exponentially decays otherwise, when the length of AGR approaches infinity and far longer than its width. Similar to the case of long-range disorder, the conductance of neutral AGR first increases and then decreases while the conductance of doped AGR monotonically decreases, as the disorder strength increases. In the presence of strong disorder, the conductivity depends monotonically and non-monotonically on the aspect ratio for heavily doped and slightly doped AGR, respectively. For edge disordered graphene nanoribbon, the conductance increases with the disorder strength of long-range correlated disordered while no delocalization exists, since the edge disorder induces localization.

  9. Effects of long-range hopping and interactions on quantum walks in ordered and disordered lattices

    NASA Astrophysics Data System (ADS)

    Chattaraj, T.; Krems, R. V.

    2016-08-01

    We study the effects of long-range hopping and long-range interparticle interactions on the quantum walk of hard-core bosons in ideal and disordered one-dimensional lattices. We find that the range of hopping has a much more significant effect on the particle correlation dynamics than the range of interactions. We illustrate that long-range hopping makes the correlation diagrams asymmetric with respect to the sign of the interaction. We examine the relative role of repulsive and attractive interactions on the dynamics of scattering by isolated impurities and Anderson localization in disordered lattices. We show that weakly repulsive interactions increase the probability of tunneling through isolated impurities and decrease the localization.

  10. Long-range magnetic response of the XY spin chain under far-from-equilibrium conditions

    NASA Astrophysics Data System (ADS)

    Gorczyca–Goraj, Anna; Mierzejewski, Marcin; Prosen, Tomaž

    2010-05-01

    Within the formalism of the Keldysh Green’s functions we investigate long-range response of an anisotropic XY chain to the local magnetic field. This field couples to a single spin on a selected lattice site. The system is driven out of equilibrium by a coupling to two semi-infinite XX spin chains. We demonstrate that the long-range response becomes enhanced by a few orders of magnitude upon application of nonequilibrium conditions. This enhancement does not occur in the isotropic XX chain. Our results agree with the recently predicted nonequilibrium-driven long-range magnetic correlations [T. Prosen and I. Pižorn, Phys. Rev. Lett. 101, 105701 (2008)]. We argue that this effect may be observed in quasi-one-dimensional triplet superconductors.

  11. Effective Long-Range Attraction between Protein Molecules in Solutions Studied by Small Angle Neutron Scattering

    SciTech Connect

    Liu Yun; Chen, W.-R.; Chen, S.-H.; Fratini, Emiliano; Baglioni, Piero

    2005-09-09

    Small angle neutron scattering intensity distributions taken from cytochrome C and lysozyme protein solutions show a rising intensity at a very small wave vector Q, which can be interpreted in terms of the presence of a weak long-range attraction between protein molecules. This interaction has a range several times that of the diameter of the protein molecule, much greater than the range of the screened electrostatic repulsion. We show evidence that this long-range attraction is closely related to the type of anion present and ion concentration in the solution.

  12. Monitoring aerosol elemental composition in particle size fractions of long-range transport

    NASA Astrophysics Data System (ADS)

    Metternich, P.; Georgii, H.-W.; Groeneveld, K. O.

    1983-04-01

    Collection of atmospheric samples was performed at Malta, a semi-remote environment in the Mediterranean, in case of long-range transport studies of pollutants and natural substances. Using PIXE as a non-destructive trace-element analytical tool, the elemental composition of these samples was determined. Atmospheric concentrations obtained in this study were of one magnitude higher than those observed over the open North Alantic in purely marine air. For most of the anomalously enriched elements in the Mediterranean aerosol, the high concentrations can be explained by long-range transport.

  13. Experimental comparison between conventional and hybrid long-range surface plasmon waveguide bends

    SciTech Connect

    Degiron, Aloyse; Cho, Sang-Yeon; Harrison, Cameron; Jokerst, Nan Marie; Smith, David R.; Dellagiacoma, Claudio; Martin, Olivier J. F.

    2008-02-15

    We report on the characterization of long-range surface plasmon waveguide bends at telecom wavelengths ({lambda}=1550 nm). The structures consist of a thin Au stripe embedded in a transparent polymer film. When the polymer thickness is larger than the lateral extension of the plasmon, the stripe sustains a conventional long-range mode; in the opposite case, the mode is hybrid because its field distribution is confined by total internal reflection in the dielectric cladding. This hybridization increases the damping by absorption but dramatically reduces the radiation loss that occurs for curved geometries, such as bends. Our results are supported quantitatively by full-wave finite-element simulations.

  14. Long-range airplane study: The consumer looks at SST travel

    NASA Technical Reports Server (NTRS)

    Landes, K. H.; Matter, J. A.

    1980-01-01

    The attitudes of long-range air travelers toward several basic air travel decisions, were surveyed. Of interest were tradeoffs involving time versus comfort and time versus cost as they pertain to supersonic versus conventional wide-body aircraft on overseas routes. The market focused upon was the segment of air travelers most likely to make that type of tradeoff decision: those having flown overseas routes for business or personal reasons in the recent past. The information generated is intended to provide quantifiable insight into consumer demand for supersonic as compared to wide-body aircraft alternatives for long-range overseas air travel.

  15. Long range forecasts of the Northern Hemisphere anomalies with antecedent sea surface temperature patterns

    NASA Technical Reports Server (NTRS)

    Kung, Ernest C.

    1994-01-01

    The contract research has been conducted in the following three major areas: analysis of numerical simulations and parallel observations of atmospheric blocking, diagnosis of the lower boundary heating and the response of the atmospheric circulation, and comprehensive assessment of long-range forecasting with numerical and regression methods. The essential scientific and developmental purpose of this contract research is to extend our capability of numerical weather forecasting by the comprehensive general circulation model. The systematic work as listed above is thus geared to developing a technological basis for future NASA long-range forecasting.

  16. Effect of long-range interactions on ion equilibria in liquid-liquid extraction

    NASA Astrophysics Data System (ADS)

    Dufrêche, J.-F.; Zemb, Th.

    2015-02-01

    We demonstrate here that equilibria of electrolytes between a water phase and an (organic) solvent phase containing amphiphilic extractants depend not only on complexation toward nearest neighbors but also on long range supramolecular interactions (LRI). Taking into account bulk, polarization and chain reorganization terms, we show that the net free energy difference associated with one metal ion transfer from water results from a strong inhibition (>25 kBT/ metal ion) due to colloidal long range interactions competing with differences in complexation considered in surpramolecular chemistry (≈-30 kBT/ metal ion). LRI also influence selectivity.

  17. Long-range anticorrelations and non-Gaussian behavior of the heartbeat

    NASA Technical Reports Server (NTRS)

    Peng, C.-K.; Mietus, J.; Hausdorff, J. M.; Havlin, S.; Stanley, H. E.; Goldberger, A. L.

    1993-01-01

    We find that the successive increments in the cardiac beat-to-beat intervals of healthy subjects display scale-invariant, long-range anticorrelations (up to 10 exp 4 heart beats). Furthermore, we find that the histogram for the heartbeat intervals increments is well described by a Levy (1991) stable distribution. For a group of subjects with severe heart disease, we find that the distribution is unchanged, but the long-range correlations vanish. Therefore, the different scaling behavior in health and disease must relate to the underlying dynamics of the heartbeat.

  18. Do chemical gradients within soil aggregates reflect plant/soil interactions?

    NASA Astrophysics Data System (ADS)

    Krüger, Jaane; Hallas, Till; Kinsch, Lena; Stahr, Simon; Prietzel, Jörg; Lang, Friederike

    2016-04-01

    As roots and hyphae often accumulate at the surface of soil aggregates, their formation and turnover might be related to the bioavailability especially of immobile nutrients like phosphorus. Several methods have been developed to obtain specific samples from aggregate surfaces and aggregate cores and thus to investigate differences between aggregate shell and core. However, these methods are often complex and time-consuming; therefore most common methods of soil analysis neglect the distribution of nutrients within aggregates and yield bulk soil concentrations. We developed a new sequential aggregate peeling method to analyze the distribution of different nutrients within soil aggregates (4-20 mm) from four forest sites (Germany) differing in concentrations of easily available mineral P. Aggregates from three soil depths (Ah, BwAh, Bw) were isolated, air-dried, and peeled with a sieving machine performing four sieving levels with increasing sieving intensity. This procedure was repeated in quadruplicate, and fractions of the same sample and sieving level were pooled. Carbon and N concentration, citric acid-extractable PO4 and P, as well as total element concentrations (P, K, Mg, Ca, Al, Fe) were analyzed. Additionally, synchrotron-based P K-edge XANES spectroscopy was applied on selected samples to detect P speciation changes within the aggregates. The results reveal for most samples a significantly higher C and N concentration at the surface compared to the interior of the aggregates. Carbon and N gradients get more pronounced with increasing soil depth and decreasing P status of study sites. This might be explained by lower aggregate turnover rates of subsoil horizons and intense bioturbation on P-rich sites. This assumption is also confirmed by concentrations of citric acid-extractable PO4 and P: gradients within aggregates are getting more pronounced with increasing soil depth and decreasing P status. However, the direction of these gradients is site

  19. Transport of a liquid water and methanol mixture through carbon nanotubes under a chemical potential gradient

    NASA Astrophysics Data System (ADS)

    Zheng, Jie; Lennon, Erin M.; Tsao, Heng-Kwong; Sheng, Yu-Jane; Jiang, Shaoyi

    2005-06-01

    In this work, we report a dual-control-volume grand canonical molecular dynamics simulation study of the transport of a water and methanol mixture under a fixed concentration gradient through nanotubes of various diameters and surface chemistries. Methanol and water are selected as fluid molecules since water represents a strongly polar molecule while methanol is intermediate between nonpolar and strongly polar molecules. Carboxyl acid (-COOH) groups are anchored onto the inner wall of a carbon nanotube to alter the hydrophobic surface into a hydrophilic one. Results show that the transport of the mixture through hydrophilic tubes is faster than through hydrophobic nanotubes although the diffusion of the mixture is slower inside hydrophilic than hydrophobic pores due to a hydrogen network. Thus, the transport of the liquid mixture through the nanotubes is controlled by the pore entrance effect for which hydrogen bonding plays an important role.

  20. Long-range transport across the Atlantic in summertime does not enhance the hygroscopicity of African mineral dust

    NASA Astrophysics Data System (ADS)

    Denjean, C.; Caquineau, S.; Desboeufs, K.; Laurent, B.; Maille, M.; Quiñones Rosado, M.; Vallejo, P.; Mayol-Bracero, O. L.; Formenti, P.

    2015-09-01

    We present the first direct evidence that the hygroscopic properties of super micron (>1 µm) African dust particles did not change despite undergoing long-range transport across the Atlantic toward the Caribbean. Concurrent measurements of chemical composition show that most of mineral dust was chemically unprocessed and externally mixed. A minor portion of mineral dust was internally mixed with sulfate and chloride (~13-24% by number) or aggregated with sea-salt particles (~3-6%). Only dust particles aggregated with sea salt showed significant hygroscopic growth above 75% relative humidity (RH), resulting in a decrease in extinction mass efficiency by up to a factor 2.2. All other dust particles did not take up significant amounts of water when exposed to up to 94% RH. These results demonstrate that the direct radiative effect of African dust in this region remained independent of RH and an external mixing state could be considered for evaluating the climate effects of dust.

  1. Geochemistry and Chemical Weathering in Soils along an Earthworm Invasion Gradient

    NASA Astrophysics Data System (ADS)

    Resner, K.; Yoo, K.; Aufdenkampe, A. K.; Hale, C.; Sebestyen, S. D.

    2010-12-01

    One of the central tenets in geomorphology is that a chemical denudation rate is limited by the total denudation rate, which controls how fast minerals are exposed to reactive environments of the earth’s surface. Though the mineral supply rate has been routinely tied to tectonic uplifts, in soil mantled landscapes, organisms such as earthworms may also significantly contribute to exposing minerals to varying geochemical environments and thus altering chemical denudation rates of the landscapes they inhabit through mineral translocation. In glaciated parts of North America, many forests evolved without native earthworms, since the last glacial retreat, until they were invaded by exotic earthworm species that arrived with agriculture, recreational fishing, and logging. Therefore, an earthworm invasion chronosequence in northern Minnesota--the focus of this ongoing study--provides an ideal natural laboratory to quantitatively study how burrowing organisms, by mixing soils, contribute to chemically denuding the landscapes. We are currently determining the inorganic chemistry of soils along a ~200 meter long transect that includes pre earthworm invasion soils as well as soils populated with several earthworm species with different burrowing habits. Additionally, six soils pits along the transect are densely installed with lysimeters, piezometers, and gas sampling tubes. The soils’ elemental chemistry profiles show that earthworms have significantly relocated minerals vertically, which is consistent with the 210Pb activity profiles determined with gamma spectroscopy. Major elements, depending on their solubility, biological demands, and susceptibility to be complexed with organic matter, respond to the enhanced mixing rates in different ways. To constrain the impacts of earthworm burrowing on chemical denudation, we are also measuring cations, anions, and alkalinity in the water samples collected with the lysimeters and piezometers. Ultimately, the soil and water

  2. 75 FR 998 - Terminate Long Range Aids to Navigation (Loran-C) Signal

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-07

    ... FR 4047), the U.S. Coast Guard began a public review process for its Draft Programmatic Environmental... SECURITY Coast Guard Terminate Long Range Aids to Navigation (Loran-C) Signal AGENCY: U.S. Coast Guard, DHS..., the Department of Transportation has determined that sufficient alternative navigation aids...

  3. South Dakota Arts Council Long Range Plan FY 2006-2008

    ERIC Educational Resources Information Center

    South Dakota Arts Council, 2006

    2006-01-01

    This report presents South Dakota Arts Council Long Range Plan for Fiscal Years 2006-2008 in terms of how it intends to achieve six goals. These goals are: (1) Enhance quality of life and economic development through the arts; (2) Promote public awareness and support of the arts; (3) Advance the arts as essential to education and life-long…

  4. Managing Strategic and Long-Range Planning via a Proactive, User-Friendly Planning Document.

    ERIC Educational Resources Information Center

    Dailey, Anne Louise; And Others

    1991-01-01

    A computerized method for managing institutional information to use in creating college planning documents is described. Development of the database, manipulation of the data for reporting, uses in strategic and long-range planning, and the model's implications for improvement of planning processes are discussed. (MSE)

  5. The Long Range Plan for Statewide Library Development in Texas, 1989-1991.

    ERIC Educational Resources Information Center

    Texas State Library, Austin. Dept. of Library Development.

    This long-range plan was prepared to satisfy the requirements of the Library Services and Construction Act (LSCA; Public Law 98-480) and to guide the Texas State Library and Archives Commission in the fulfillment of its statutory mission. The plan provides a framework for the establishment or expansion of programs to carry out the purposes…

  6. Long-Range Plan for Library Services in Wisconsin, 1991-1996. Bulletin No. 92157.

    ERIC Educational Resources Information Center

    Wisconsin State Dept. of Public Instruction, Madison. Div. of Library Services.

    This report addresses the status of library development in Wisconsin, the needs and problems of libraries, and possible ways of meeting these needs over the next 5 years. These long-range plans developed by the staff of the Division for Library Services (DLS) reflect reports submitted to the DLS, surveys, consultations with librarians and…

  7. Idaho State Library Long Range Plan for Implementation of LSCA Priorities, 1989-1991.

    ERIC Educational Resources Information Center

    Joslin, Ann

    Based largely on recommendations from a 1986 strategy study, this long range plan for the improvement of library services in Idaho addresses goals and activities for the years 1989-1991. It is intended to support the direction of library development begun in 1984 to improve services to the user and to meet Library Services and Construction Act…

  8. The Long Range Plan for Statewide Library Development in Texas, 1990-1993. Revised.

    ERIC Educational Resources Information Center

    Texas State Library, Austin. Dept. of Library Development.

    The Long Range Plan was prepared to satisfy requirements of the Library Services Construction Act (LSCA) and to guide the Texas State Library and Archives Commission in the fulfillment of its statutory mission. The plan provides a framework for the establishment or expansion of programs to carry out the purposes mandated by the state and federal…

  9. Long Range Plan for Statewide Library Development in Texas: 1996 to 1999.

    ERIC Educational Resources Information Center

    Texas State Library, Austin. Dept. of Library Development.

    Texas State Library's 1996 to 1999 long range plan for library development provides for the establishment and expansion of programs needed to carry out the objectives of the Library Services and Construction Act (LSCA) and the Library Systems Act (LSA). The first three chapters give an overview of the Statewide Library Development Program of the…

  10. LONG-RANGE TRANSPORT AND TRANSFORMATION OF SO2 AND SULFATE

    EPA Science Inventory

    Technical descriptions and computer programs are presented for two models that calculate long-range transport, diffusion, transformation of SO2 to sulfate, and dry and precipitation deposition of initially emitted SO2. One model treats the mixing layer height as constant; the oth...

  11. FINE-PARTICLE SODIUM TRACER FOR LONG-RANGE TRANSPORT OF THE KUWAITI OIL FIRE PLUME

    EPA Science Inventory

    Evidence for long-range transport of the Kuwaiti oil-fire smoke during the months following the Persian Gulf War has been more or less indirect. or example, high concentrations of aerosols containing soot and oil-combustion tracers such as vanadium observed at great distances fro...

  12. Long range correlations in high multiplicity hadron collisions: Building bridges with ridges

    SciTech Connect

    Venugopalan, Raju

    2015-01-15

    We discuss the physics of the ridge–azimuthally collimated long range rapidity correlations–in high multiplicity proton–proton and proton–nucleus collisions. We outline some of the theoretical discussions in the literature that address the systematics of these ridge correlations.

  13. Attractor nonequilibrium stationary states in perturbed long-range interacting systems

    NASA Astrophysics Data System (ADS)

    Joyce, Michael; Morand, Jules; Viot, Pascal

    2016-05-01

    Isolated long-range interacting particle systems appear generically to relax to nonequilibrium states ("quasistationary states" or QSSs) which are stationary in the thermodynamic limit. A fundamental open question concerns the "robustness" of these states when the system is not isolated. In this paper we explore, using both analytical and numerical approaches to a paradigmatic one-dimensional model, the effect of a simple class of perturbations. We call them "internal local perturbations" in that the particle energies are perturbed at collisions in a way which depends only on the local properties. Our central finding is that the effect of the perturbations is to drive all the very different QSSs we consider towards a unique QSS. The latter is thus independent of the initial conditions of the system, but determined instead by both the long-range forces and the details of the perturbations applied. Thus in the presence of such a perturbation the long-range system evolves to a unique nonequilibrium stationary state, completely different from its state in absence of the perturbation, and it remains in this state when the perturbation is removed. We argue that this result may be generic for long-range interacting systems subject to perturbations which are dependent on the local properties (e.g., spatial density or velocity distribution) of the system itself.

  14. The pluripotent regulatory circuitry connecting promoters to their long-range interacting elements.

    PubMed

    Schoenfelder, Stefan; Furlan-Magaril, Mayra; Mifsud, Borbala; Tavares-Cadete, Filipe; Sugar, Robert; Javierre, Biola-Maria; Nagano, Takashi; Katsman, Yulia; Sakthidevi, Moorthy; Wingett, Steven W; Dimitrova, Emilia; Dimond, Andrew; Edelman, Lucas B; Elderkin, Sarah; Tabbada, Kristina; Darbo, Elodie; Andrews, Simon; Herman, Bram; Higgs, Andy; LeProust, Emily; Osborne, Cameron S; Mitchell, Jennifer A; Luscombe, Nicholas M; Fraser, Peter

    2015-04-01

    The mammalian genome harbors up to one million regulatory elements often located at great distances from their target genes. Long-range elements control genes through physical contact with promoters and can be recognized by the presence of specific histone modifications and transcription factor binding. Linking regulatory elements to specific promoters genome-wide is currently impeded by the limited resolution of high-throughput chromatin interaction assays. Here we apply a sequence capture approach to enrich Hi-C libraries for >22,000 annotated mouse promoters to identify statistically significant, long-range interactions at restriction fragment resolution, assigning long-range interacting elements to their target genes genome-wide in embryonic stem cells and fetal liver cells. The distal sites contacting active genes are enriched in active histone modifications and transcription factor occupancy, whereas inactive genes contact distal sites with repressive histone marks, demonstrating the regulatory potential of the distal elements identified. Furthermore, we find that coregulated genes cluster nonrandomly in spatial interaction networks correlated with their biological function and expression level. Interestingly, we find the strongest gene clustering in ES cells between transcription factor genes that control key developmental processes in embryogenesis. The results provide the first genome-wide catalog linking gene promoters to their long-range interacting elements and highlight the complex spatial regulatory circuitry controlling mammalian gene expression. PMID:25752748

  15. A Long-Range, Comprehensive Plan for Early Childhood Education in Alaska.

    ERIC Educational Resources Information Center

    Rath, Robert R.

    This long-range, comprehensive plan for early childhood education in Alaska focuses on providing environmental surroundings conducive to learning for children aged 3, 4 and 5. Topics covered are: (1) needs, objectives and activities--projected numbers of students (age and grade distribution, school distribution), early childhood education…

  16. Quantum transport with long-range steps on Watts-Strogatz networks

    NASA Astrophysics Data System (ADS)

    Wang, Yan; Xu, Xin-Jian

    2016-07-01

    We study transport dynamics of quantum systems with long-range steps on the Watts-Strogatz network (WSN) which is generated by rewiring links of the regular ring. First, we probe physical systems modeled by the discrete nonlinear schrödinger (DNLS) equation. Using the localized initial condition, we compute the time-averaged occupation probability of the initial site, which is related to the nonlinearity, the long-range steps and rewiring links. Self-trapping transitions occur at large (small) nonlinear parameters for coupling ɛ=-1 (1), as long-range interactions are intensified. The structure disorder induced by random rewiring, however, has dual effects for ɛ=-1 and inhibits the self-trapping behavior for ɛ=1. Second, we investigate continuous-time quantum walks (CTQW) on the regular ring ruled by the discrete linear schrödinger (DLS) equation. It is found that only the presence of the long-range steps does not affect the efficiency of the coherent exciton transport, while only the allowance of random rewiring enhances the partial localization. If both factors are considered simultaneously, localization is greatly strengthened, and the transport becomes worse.

  17. Kaleidoscope of quantum phases in a long-range interacting spin-1 chain

    NASA Astrophysics Data System (ADS)

    Gong, Z.-X.; Maghrebi, M. Â. F.; Hu, A.; Foss-Feig, M.; Richerme, P.; Monroe, C.; Gorshkov, A. Â. V.

    2016-05-01

    Motivated directly by recent trapped-ion quantum simulation experiments, we carry out a comprehensive study of the phase diagram of a spin-1 chain with XXZ-type interactions that decay as 1 /rα , using a combination of finite and infinite-size DMRG calculations, spin-wave analysis, and field theory. In the absence of long-range interactions, varying the spin-coupling anisotropy leads to four distinct and well-studied phases: a ferromagnetic Ising phase, a disordered XY phase, a topological Haldane phase, and an antiferromagnetic Ising phase. If long-range interactions are antiferromagnetic and thus frustrated, we find primarily a quantitative change of the phase boundaries. On the other hand, ferromagnetic (nonfrustrated) long-range interactions qualitatively impact the entire phase diagram. Importantly, for α ≲3 , long-range interactions destroy the Haldane phase, break the conformal symmetry of the XY phase, give rise to a new phase that spontaneously breaks a U (1 ) continuous symmetry, and introduce a possibly exotic tricritical point with no direct parallel in short-range interacting spin chains. Importantly, we show that the main signatures of all five phases found could be observed experimentally in the near future.

  18. Application of powered-lift concepts for improved cruise efficiency of long-range aircraft

    NASA Technical Reports Server (NTRS)

    Coe, P. L., Jr.; Fournier, P. G.

    1976-01-01

    Results of studies conducted to explore the use of powered lift concepts for improved low speed performance of long range subsonic and supersonic cruise vehicles are summarized. It is indicated that powered lift can provide significant improvements in low speed performance, as well as substantial increases in cruise efficiency and range for both subsonic and supersonic cruise configurations.

  19. 25 CFR 170.410 - What is the purpose of tribal long-range transportation planning?

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false What is the purpose of tribal long-range transportation planning? 170.410 Section 170.410 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR LAND AND WATER INDIAN RESERVATION ROADS PROGRAM Planning, Design, and Construction of Indian Reservation...

  20. The pluripotent regulatory circuitry connecting promoters to their long-range interacting elements

    PubMed Central

    Schoenfelder, Stefan; Furlan-Magaril, Mayra; Mifsud, Borbala; Tavares-Cadete, Filipe; Sugar, Robert; Javierre, Biola-Maria; Nagano, Takashi; Katsman, Yulia; Sakthidevi, Moorthy; Wingett, Steven W.; Dimitrova, Emilia; Dimond, Andrew; Edelman, Lucas B.; Elderkin, Sarah; Tabbada, Kristina; Darbo, Elodie; Andrews, Simon; Herman, Bram; Higgs, Andy; LeProust, Emily; Osborne, Cameron S.; Mitchell, Jennifer A.

    2015-01-01

    The mammalian genome harbors up to one million regulatory elements often located at great distances from their target genes. Long-range elements control genes through physical contact with promoters and can be recognized by the presence of specific histone modifications and transcription factor binding. Linking regulatory elements to specific promoters genome-wide is currently impeded by the limited resolution of high-throughput chromatin interaction assays. Here we apply a sequence capture approach to enrich Hi-C libraries for >22,000 annotated mouse promoters to identify statistically significant, long-range interactions at restriction fragment resolution, assigning long-range interacting elements to their target genes genome-wide in embryonic stem cells and fetal liver cells. The distal sites contacting active genes are enriched in active histone modifications and transcription factor occupancy, whereas inactive genes contact distal sites with repressive histone marks, demonstrating the regulatory potential of the distal elements identified. Furthermore, we find that coregulated genes cluster nonrandomly in spatial interaction networks correlated with their biological function and expression level. Interestingly, we find the strongest gene clustering in ES cells between transcription factor genes that control key developmental processes in embryogenesis. The results provide the first genome-wide catalog linking gene promoters to their long-range interacting elements and highlight the complex spatial regulatory circuitry controlling mammalian gene expression. PMID:25752748

  1. SOURCES AND EVALUATION OF UNCERTAINTY IN LONG-RANGE TRANSPORT MODELS

    EPA Science Inventory

    The American Meteorological Society, under joint sponsorship from the U.S. Environmental Protection Agency, the Atmospheric Environment Service, Canada and the Ontario Ministry of the Environment, Canada, convened a workshop in September 1984 to address an aspect of long-range tr...

  2. Calculation of long range forces and their applications in determining gaseous properties

    NASA Technical Reports Server (NTRS)

    Singh, J. J.

    1979-01-01

    A discussion of various theoretical and experimental techniques for the calculation of long range interaction between two atomic systems at moderate separation is presented. Some applications of these techniques for obtaining gaseous properties are described. The forces between neutral molecules and metallic surfaces are also discussed and numerical values of heats of adsorption for a number of systems are calculated.

  3. Towards theoretical analysis of long-range proton transfer kinetics in biomolecular pumps

    PubMed Central

    König, P. H.; Ghosh, N.; Hoffmann, M.; Elstner, M.; Tajkhorshid, E.; Frauenheim, Th.; Cui, Q.

    2008-01-01

    Motivated by the long-term goal of theoretically analyzing long-range proton transfer (PT) kinetics in biomolecular pumps, a number of technical developments were made in the framework of QM/MM simulations. A set of collective reaction co-ordinates is proposed for characterizing the progress of long-range proton transfers; unlike previous suggestions, the new coordinates can describe PT along highly non-linear three-dimensional pathways. Calculations using a realistic model of carbonic anhydrase demonstrated that adiabatic mapping using these collective coordinates gives reliable energetics and critical geometrical parameters as compared to minimum energy path calculations, which suggests that the new coordinates can be effectively used as reaction coordinate in potential of mean force calculations for long-range PT in complex systems. In addition, the generalized solvent boundary potential was implemented in the QM/MM framework for rectangular geometries, which is useful for studying reactions in membrane systems. The resulting protocol was found to produce water structure in the interior of aquaporin consistent with previous studies including much larger number of explicit solvent and lipid molecules. The effect of electrostatics for PT through membrane protein was also illustrated with a simple model channel embedded in different dielectric continuum environments. The encouraging results observed so far suggest that robust theoretical analysis of long-range PT kinetics in biomolecular pumps can soon be realized in a QM/MM framework. PMID:16405327

  4. Global and Regional Modeling of Long-Range Transport and Intercontinental Source-Receptor Linkages (presentation)

    EPA Science Inventory

    Because long-range transport has been shown to affect air quality in downwind continents, there is a growing realization that these effects may need to be considered in air quality management efforts by distinguishing between the contributions of local and regional emission sourc...

  5. Policy Directions for U. S. Agriculture; Long-Range Choices in Farming and Rural Living.

    ERIC Educational Resources Information Center

    Clawson, Marion

    A comprehensive view of agriculture is presented in this volume written to aid critical re-examination of long-range agricultural policy. Farm people, rural institutions and services, rural towns, the spatial organization of agriculture, and its capital structure, in addition to the usual subjects of agricultural output, demand, trade, price, and…

  6. INVESTIGATING THE INFLUENCE OF LONG RANGE TRANSPORT ON MERCURY DEPOSITION IN SOUTH FLORIDA

    EPA Science Inventory

    In 1999, the US EPA National Exposure Research Laboratory (NERL) through a Regional Applied Research Effort initiated a study to evaluate the magnitude of long-range transport of mercury through the marine free troposphere to South Florida via aircraft measurements (200 to 11,5...

  7. Long-range dispersion interactions. III: Method for two homonuclear atoms

    SciTech Connect

    Mitroy, J.; Zhang, J.-Y.

    2007-12-15

    A procedure for systematically evaluating the long-range dispersion interaction between two homonuclear atoms in arbitrary LS coupled states is outlined. The method is then used to generate dispersion coefficients for a number of the low-lying states of the Na and Mg dimers.

  8. Futures Research and the Strategic Planning Process: Implications for Long-Range Planning in Higher Education.

    ERIC Educational Resources Information Center

    Morrison, James L.; Renfro, William L.

    The concepts of long-range planning and strategic planning are explained, and a planning model is proposed. Attention is directed to an environmental scanning model that is congruent with the concept of strategic planning and that emerges from one portion of the futures research community, issues management. A third planning model, the strategic…

  9. Sterling landing fuel tanks site environmental baseline survey: Tatalina Long Range Radar Station, Alaska. Final report

    SciTech Connect

    1997-03-01

    The purpose of the environmental baselines survey (EBS) was to document the existence of petroleum hydrocarbon contamination and to identify potential environmental liabilities to the US. Air Force (USAF) associated with the fuel storage tanks at Sterling Landing on the Tatalina Long Range Radar Station (LRRS).

  10. Attenuated MP2 with a Long-Range Dispersion Correction for Treating Nonbonded Interactions.

    PubMed

    Goldey, Matthew B; Belzunces, Bastien; Head-Gordon, Martin

    2015-09-01

    Attenuated second order Møller-Plesset theory (MP2) captures intermolecular binding energies at equilibrium geometries with high fidelity with respect to reference methods, yet must fail to reproduce dispersion energies at stretched geometries due to the removal of fully long-range dispersion. For this problem to be ameliorated, long-range correction using the VV10 van der Waals density functional is added to attenuated MP2, capturing short-range correlation with attenuated MP2 and long-range dispersion with VV10. Attenuated MP2 with long-range VV10 dispersion in the aug-cc-pVTZ (aTZ) basis set, MP2-V(terfc, aTZ), is parametrized for noncovalent interactions using the S66 database and tested on a variety of noncovalent databases, describing potential energy surfaces and equilibrium binding energies equally well. Further, a spin-component scaled (SCS) version, SCS-MP2-V(2terfc, aTZ), is produced using the W4-11 database as a supplemental thermochemistry training set, and the resulting method reproduces the quality of MP2-V(terfc, aTZ) for noncovalent interactions and exceeds the performance of SCS-MP2/aTZ for thermochemistry. PMID:26575911

  11. Imputation of Missing Genotypes From Sparse to High Density Using Long-Range Phasing

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Related individuals in a population share long chromosome segments which trace to a common ancestor. We describe a long-range phasing algorithm that makes use of this property to phase whole chromosomes and simultaneously impute a large number of missing markers. We test our method by imputing marke...

  12. Superharmonic long-range triplet current in a diffusive Josephson junction.

    PubMed

    Richard, Caroline; Houzet, Manuel; Meyer, Julia S

    2013-05-24

    We study the Josephson current through a long ferromagnetic bilayer in the diffusive regime. For noncollinear magnetizations, we find that the current-phase relation is dominated by its second harmonic, which corresponds to the long-range coherent propagation of two triplet pairs of electrons. PMID:23745915

  13. Long-Range Statewide Enrollment and WSCH Forecast, California Community Colleges.

    ERIC Educational Resources Information Center

    McIntyre, Chuck; Chan, Chuen-Rong

    This report summarizes the most recent (December 1998) long-range statewide forecast of fall enrollment and average annual weekly student contact hours (WSCH) in California Community Colleges. The annual fall survey of college registrars shows that fall 1998 enrollment is up 1.8 percent over fall 1997. The office forecasting model projects an…

  14. Long-Range Strategic Planning for the Alamo Community College District. Position Papers.

    ERIC Educational Resources Information Center

    McClenney, Byron N.; Moore, Kay M.

    Prepared for use in long-range planning in the Alamo Community College District (ACCD), this report presents an overview of the District and position papers containing data and interpretive discussion on five planning concerns. Following an overview of ACCD enrollments, personnel, and finances, the first position paper outlines population…

  15. NIDRR Long-Range Plan for Fiscal Years 2005-09. Executive Summary

    ERIC Educational Resources Information Center

    US Department of Education, 2007

    2007-01-01

    The National Institute on Disability and Rehabilitation Research (NIDRR) "Long-Range Plan for Fiscal Years 2005-09" (the "Plan") provides an agenda for achieving advancements in applied rehabilitation research that will benefit people with disabilities in the United States. This executive summary describes the purposes and scope of the "Plan,"…

  16. 25 CFR 170.411 - What may a long-range transportation plan include?

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 25 Indians 1 2011-04-01 2011-04-01 false What may a long-range transportation plan include? 170.411 Section 170.411 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR LAND AND WATER INDIAN RESERVATION ROADS PROGRAM Planning, Design, and Construction of Indian Reservation Roads Program...

  17. 25 CFR 170.411 - What may a long-range transportation plan include?

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false What may a long-range transportation plan include? 170.411 Section 170.411 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR LAND AND WATER INDIAN RESERVATION ROADS PROGRAM Planning, Design, and Construction of Indian Reservation Roads Program...

  18. Long range ordered alloys modified by addition of niobium and cerium

    DOEpatents

    Liu, Chain T.

    1987-01-01

    Long range ordered alloys are described having the nominal composition (Fe,Ni,Co).sub.3 (V,M) where M is a ductility enhancing metal selected from the group Ti, Zr, Hf with additions of small amounts of cerium and niobium to drammatically enhance the creep properties of the resulting alloys.

  19. Long range ordered alloys modified by addition of niobium and cerium

    DOEpatents

    Liu, C.T.

    1984-08-22

    Long range ordered alloys are described having the nominal composition (Fe,Ni,Co)/sub 3/ (V,M) where M is a ductility enhancing metal selected from the group Ti, Zr, Hf with additions of small amounts of cerium and niobium to dramatically enhance the creep properties of the resulting alloys.

  20. A long range transmission system communication plan for ComEd of Chicago 1995 to 2000

    SciTech Connect

    Casanova, R.; Gerleve, F.J.

    1995-10-01

    The design of a telecommunication fiber optical network serving ComEd`s commercial centers and generation stations is described. A long range communication plan is presented describing a migration of transmission substation protection, monitoring and control from an analog system over power line carrier, microwave, and leased phone lines to a digital system using an optimum mix of communication channels including fiber.

  1. Robustness of Estimators of Long-Range Dependence and Self-Similarity under non-Gaussianity

    NASA Astrophysics Data System (ADS)

    Franzke, C.; Watkins, N. W.; Graves, T.; Gramacy, R.; Hughes, C.

    2011-12-01

    Long-range dependence and non-Gaussianity are ubiquitous in many natural systems like ecosystems, biological systems and climate. However, it is not always appreciated that both phenomena may occur together in natural systems and that self-similarity in a system can be a superposition of both phenomena. These features, which are common in complex systems, impact the attribution of trends and the occurrence and clustering of extremes. The risk assessment of systems with these properties will lead to different outcomes (e.g. return periods) than the more common assumption of independence of extremes. Two paradigmatic models are discussed which can simultaneously account for long-range dependence and non-Gaussianity: Autoregressive Fractional Integrated Moving Average (ARFIMA) and Linear Fractional Stable Motion (LFSM). Statistical properties of estimators for long-range dependence and self-similarity are critically assessed. It is found that the most popular estimators can be biased in the presence of important features of many natural systems like trends and multiplicative noise. Also the long-range dependence and non-Gaussianity of two typical natural time series are discussed.

  2. Long-range spin coupling: a tetraphosphine-bridged palladium dimer.

    PubMed

    Arumugam, Kuppuswamy; Shaw, Mohammed C; Mague, Joel T; Bill, Eckhard; Sproules, Stephen; Donahue, James P

    2011-04-01

    The dipalladium compound [{(adt)Pd}(2)(μ-tpbz)] (1) (adt = bis(p-anisyl)-1,2-ethylenedithiolate, tpbz = 1,2,4,5-tetrakis(diphenylphosphino)benzene) has been synthesized from [{Cl(2)Pd}(2)(μ-tpbz)] by transmetalation employing (adt)SnMe(2). The cyclic voltammogram (CV) of 1 reveals reversible oxidation waves at 0.00 V and +0.50 V (vs [Fc](+)/Fc) with current amplitude twice that for identical processes in the monopalladium compound [(adt)Pd(dppb)] (2) (dppb = 1,2-bis(diphenylphosphino)benzene), an observation indicating each wave involves simultaneous one-electron oxidations at each metallodithiolene fragment. This assignment is affirmed by density functional theory (DFT) calculations that show the redox-active molecular orbital (MO) is principally composed of the dithiolene S(2)C(2) π-system, and by spectroelectrochemical UV-vis of [1](2+), which displays hallmark low energy charge transfer (CT) bands. Dication [1](2+) is a diradical with a near degenerate singlet-triplet ground state; fluid solution electron paramagnetic resonance (EPR) spectra validate the DFT-derived isotropic exchange coupling, J' = -6.3 cm(-1). The frozen solution X-band EPR spectrum of [1](2+) is consistent with a spin-triplet bearing a very faint half-field ("ΔM(S) = 2") signal. It is successfully simulated with an amazingly small zero field splitting, D = -15 × 10(-4) cm(-1) and negligible rhombicity (E/D = 0.008). These zero-field splitting parameters, which stem from the long-range dipolar spin coupling, are very accurately reproduced using a multipoint dipole model with an optimized interspin distance of 12.434 Å. With the framework reported herein for understanding how the weak interaction of two spins is mediated by tpbz, this bridging ligand can now be incorporated into extended systems with tailored chemical and physical properties for use in a variety of molecular-based electronic and magnetic devices. PMID:21381668

  3. [Simulation of long-range transport potential of POPs in Poyang Lake].

    PubMed

    Gong, Xiao-Feng; Xiang, Hong-Rui; Chen, Chun-Li; Zhou, Wen-Bin; Wang, Jia-Jia; Liu, Chun-Ying; Zeng, Yan

    2014-06-01

    The long-range transport potential (LRTP) and overall persistence (Pov) of 5 typical persisitent organic pollutants (POPs) through air and water in Poyang Lake were estimated by the TaPL3 model. The characteristic travel distance (CTD) and Pov of different POPs were compared. In addition, the key parameters were examined by the sensitivity analysis method using p, p'-DDT as an example. The results showed that the CTD(Air) of p, p'-DDT, gamma-HCH, HCB, PCP and 2, 3, 7, 8-TCDD ranged from 432 km (2, 3, 7, 8-TCDD) to 86 479 km (HCB), and the value of Pov(Air) ranged from 85.6 d (PCP) to 2 231 d (HCB), when POPs were emitted to the atmosphere. Soil phase was the main fate of these typical POPs, and it was about 72.0% percent of the total phase. Meanwhile, the CTD(Water) was from 4 207 km (PCP) to 1.19 x 10(5) km (gamma-HCH), and Pov(Water) was from 103 d (PCP) to 2 890 d (HCB), when POPs were emitted to the water. Sediment phase was the main fate of these typical POPs, and it was about 52.5% percent of the total phase. Half-life in the environment and octanol-water partition coefficient logarithm of POPs were the two main physical-chemical parameters that affected CTD and Pov. When compared with other similar studies in China, the CTD(Air) of related POPs in Poyang Lake is in the middle level. While the CTD(Water) was a little higher than other areas, which was due to the higher water depth and water flow velocity of Poyang Lake. Therefore, the higher water depth and water flow velocity were two significantly-affected parameters of CTD(Water). The results could provide a scientific basis to studies of environmental process and risks of POPs in Poyang Lake. PMID:25158504

  4. Chemical bond as a test of density-gradient expansions for kinetic and exchange energies

    NASA Astrophysics Data System (ADS)

    Perdew, John P.; Levy, Mel; Painter, G. S.; Wei, Siqing; Lagowski, Jolanta B.

    1988-01-01

    Errors in kinetic and exchange contributions to the molecular bonding energy are assessed for approximate density functionals by reference to near-exact Hartree-Fock values. From the molecular calculations of Allan et al.and of Lee and Ghosh, it is demonstrated that the density-gradient expansion does not accurately describe the noninteracting kinetic contribution to the bonding energy, even when this expansion is carried to fourth order and applied in its spin-density-functional form to accurate Hartree-Fock densities. In a related study, it is demonstrated that the overbinding of molecules such as N2 and F2, which occurs in the local-spin-density (LSD) approximation for the exchange-correlation energy, is not attributable to errors in the self-consistent LSD densities. Contrary to expectations based upon the Gunnarsson-Jones nodality argument, it is found that the LSD approximation for the exchange energy can seriously overbind a molecule even when bonding does not create additional nodes in the occupied valence orbitals. LSD and exact values for the exchange contribution to the bonding energy are displayed and discussed for several molecules.

  5. Chemical reactions accompanying fluid flow through granite held in a temperature gradient

    USGS Publications Warehouse

    Moore, Diane E.; Morrow, C.A.; Byerlee, J.D.

    1983-01-01

    Distilled water was passed at a low rate down a temperature gradient through cylinders of Barre and Westerly Granite. Temperatures ranged from 80-100??C at the outer edges of the cylinders to 250-300??C in central, drilled holes which housed the heating coils. The measured permeabilities of the granite cylinders decreased by as much as two orders of magnitude in experiments of 1-3 weeks' duration. The amount of permeability decrease varied directly with temperature and inversely with the rate of fluid flow. The compositions of the fluids discharged from the granites were functions of temperature and flow rate as well as mineral composition, with dissolved silica concentrations showing trends different from those of the other analyzed species. Fluids from experiments run at higher temperatures but at much lower initial rates of fluid flow had higher concentrations of most ions but substantially lower dissolved silica contents. In contrast, an increase in temperature at similar rates of fluid flow resulted in higher silica concentrations. In the experiments, the distilled water acquired enough dissolved materials at high temperatures to become supersaturated with respect to several minerals at the low-temperature edges of the cylinders. Some of this material, particularly silica, was deposited along grain boundaries and microfractures, causing the observed permeability decreases. The very low rates of fluid flow in some high-temperature experiments significantly increased the rates of SiO2 precipitation and reduced dissolved silica concentrations relative to other species in the discharged fluids. ?? 1983.

  6. Chemical bond as a test of density-gradient expansions for kinetic and exchange energies

    SciTech Connect

    Perdew, J.P.; Levy, M.; Painter, G.S.; Wei, S.; Lagowski, J.B.

    1988-01-15

    Errors in kinetic and exchange contributions to the molecular bonding energy are assessed for approximate density functionals by reference to near-exact Hartree-Fock values. From the molecular calculations of Allan et al. and of Lee and Ghosh, it is demonstrated that the density-gradient expansion does not accurately describe the noninteracting kinetic contribution to the bonding energy, even when this expansion is carried to fourth order and applied in its spin-density-functional form to accurate Hartree-Fock densities. In a related study, it is demonstrated that the overbinding of molecules such as N/sub 2/ and F/sub 2/, which occurs in the local-spin-density (LSD) approximation for the exchange-correlation energy, is not attributable to errors in the self-consistent LSD densities. Contrary to expectations based upon the Gunnarsson-Jones nodality argument, it is found that the LSD approximation for the exchange energy can seriously overbind a molecule even when bonding does not create additional nodes in the occupied valence orbitals. LSD and exact values for the exchange contribution to the bonding energy are displayed and discussed for several molecules.

  7. Assessment of long-range correlation in time series: how to avoid pitfalls.

    PubMed

    Gao, Jianbo; Hu, Jing; Tung, Wen-Wen; Cao, Yinhe; Sarshar, N; Roychowdhury, Vwani P

    2006-01-01

    Due to the ubiquity of time series with long-range correlation in many areas of science and engineering, analysis and modeling of such data is an important problem. While the field seems to be mature, three major issues have not been satisfactorily resolved. (i) Many methods have been proposed to assess long-range correlation in time series. Under what circumstances do they yield consistent results? (ii) The mathematical theory of long-range correlation concerns the behavior of the correlation of the time series for very large times. A measured time series is finite, however. How can we relate the fractal scaling break at a specific time scale to important parameters of the data? (iii) An important technique in assessing long-range correlation in a time series is to construct a random walk process from the data, under the assumption that the data are like a stationary noise process. Due to the difficulty in determining whether a time series is stationary or not, however, one cannot be 100% sure whether the data should be treated as a noise or a random walk process. Is there any penalty if the data are interpreted as a noise process while in fact they are a random walk process, and vice versa? In this paper, we seek to gain important insights into these issues by examining three model systems, the autoregressive process of order 1, on-off intermittency, and Lévy motions, and considering an important engineering problem, target detection within sea-clutter radar returns. We also provide a few rules of thumb to safeguard against misinterpretations of long-range correlation in a time series, and discuss relevance of this study to pattern recognition. PMID:16486226

  8. Spatial and temporal changes in microbial community structure associated with recharge-influenced chemical gradients in a contaminated aquifer

    USGS Publications Warehouse

    Haack, S.K.; Fogarty, L.R.; West, T.G.; Alm, E.W.; McGuire, J.T.; Long, D.T.; Hyndman, D.W.; Forney, L.J.

    2004-01-01

    In a contaminated water-table aquifer, we related microbial community structure on aquifer sediments to gradients in 24 geochemical and contaminant variables at five depths, under three recharge conditions. Community amplified ribsosomal DNA restriction analysis (ARDRA) using universal 16S rDNA primers and denaturing gradient gel electrophoresis (DGGE) using bacterial 16S rDNA primers indicated: (i) communities in the anoxic, contaminated central zone were similar regardless of recharge; (ii) after recharge, communities at greatest depth were similar to those in uncontaminated zones; and (iii) after extended lack of recharge, communities at upper and lower aquifer margins differed from communities at the same depths on other dates. General aquifer geochemistry was as important as contaminant or terminal electron accepting process (TEAP) chemistry in discriminant analysis of community groups. The Shannon index of diversity (H) and the evenness index (E), based on DGGE operational taxonomic units (OTUs), were statistically different across community groups and aquifer depths. Archaea or sulphate-reducing bacteria 16S rRNA abundance was not clearly correlated with TEAP chemistry indicative of methanogenesis or sulphate reduction. Eukarya rRNA abundance varied by depth and date from 0 to 13% of the microbial community. This contaminated aquifer is a dynamic ecosystem, with complex interactions between physical, chemical and biotic components, which should be considered in the interpretation of aquifer geochemistry and in the development of conceptual or predictive models for natural attenuation or remediation.

  9. Tailored Height Gradients in Vertical Nanowire Arrays via Mechanical and Electronic Modulation of Metal-Assisted Chemical Etching.

    PubMed

    Otte, M A; Solis-Tinoco, V; Prieto, P; Borrisé, X; Lechuga, L M; González, M U; Sepulveda, B

    2015-09-01

    In current top-down nanofabrication methodologies the design freedom is generally constrained to the two lateral dimensions, and is only limited by the resolution of the employed nanolithographic technique. However, nanostructure height, which relies on certain mask-dependent material deposition or etching techniques, is usually uniform, and on-chip variation of this parameter is difficult and generally limited to very simple patterns. Herein, a novel nanofabrication methodology is presented, which enables the generation of high aspect-ratio nanostructure arrays with height gradients in arbitrary directions by a single and fast etching process. Based on metal-assisted chemical etching using a catalytic gold layer perforated with nanoholes, it is demonstrated how nanostructure arrays with directional height gradients can be accurately tailored by: (i) the control of the mass transport through the nanohole array, (ii) the mechanical properties of the perforated metal layer, and (iii) the conductive coupling to the surrounding gold film to accelerate the local electrochemical etching process. The proposed technique, enabling 20-fold on-chip variation of nanostructure height in a spatial range of a few micrometers, offers a new tool for the creation of novel types of nano-assemblies and metamaterials with interesting technological applications in fields such as nanophotonics, nanophononics, microfluidics or biomechanics. PMID:26033973

  10. Uranium geochemistry on the Amazon shelf: Chemical phase partitioning and cycling across a salinity gradient

    NASA Astrophysics Data System (ADS)

    Swarzenski, P. W.; McKee, B. A.; Booth, J. G.

    1995-01-01

    The size distribution of U was examined in surface waters of the Amazon shelf. Water samples were collected during a low discharge river stage across a broad salinity gradient (0.3-35.4%) and fractionated by planar filtration and tangential-flow ultrafiltration into (1) solution (Us, <10,000 MW; ˜1-10 nm), (2) colloidal (Uc 10,000 MW-0.4 μm), (3) dissolved (Ud, <0.4 μm), and (4) particulate (Up, >0.4 μm) phases. Concentrations of colloidal U comprise up to 92% of the dissolved U fraction at the river mouth and attain highest values (˜0.45 μg/L) in the productive, biogenic region of the Amazon shelf (salinities above ˜20%). Ud and Uc distributions are highly nonconservative relative to ideal dilution of river water and seawater, indicating extensive removal at salinities below ˜10%. The distribution of Us also shows some nonconservative behavior, yet removal, if any, is minimal. Saltwater-induced precipitation and aggregation of riverine colloidal material is most likely the dominant mechanism of U removal in the low salinity, terrigenous region of the Amazon shelf. There is evidence of a substantial colloidal U input (˜245% of the riverine Uc flux into surface waters above 5%. Such Uc enrichment most likely is the result of colloidal U-rich porewater diffusion/advection from the seabed and fluid muds or shelf-wide particle-colloid disaggregation. Removal of solution and dissolved phase U via a colloidal intermediate and Uc aggregation was examined in terms of coagulation theory. The highly reactive nature of all U phases on the Amazon shelf suggests that remobilization and fractionation of U may also occur in other river-influenced coastal environments.

  11. Measurement of Neutral Winds and Gradients in the Lower Thermosphere with Multi-Point, Chemical-Release Sounding Rocket Payloads.

    NASA Astrophysics Data System (ADS)

    Andersen, C.

    2014-12-01

    Sounding rocket payloads capable of deploying multi-point chemical releases provide a unique tool for investigating the properties of the lower thermosphere. This type of payload consists of a collection of sub-payloads that are propelled laterally out of the rocket during flight. Each contains a canister of liquid tracer (such as tri-methyl aluminum) which, after separating from the main rocket, is dispersed by explosive detonation. The result is a luminous "puff" that can be tracked by triangulation using images taken from several ground stations, producing wind vector velocities with typical uncertainties of just 1-2 m/s. A deployment of puffs throughout a 3-dimensional volume spanning approximately 100x100 km horizontally and from 100 to 180 km altitude, vertically, makes it possible to measure the height profiles of all nine first-order spatial gradients of the neutral wind vector in the lower thermosphere.

  12. Rapid processing of carbon-carbon composites by forced flow-thermal gradient chemical vapor infiltration (FCVI)

    SciTech Connect

    Vaidyaraman, S.; Lackey, W.J.; Agrawal, P.K.; Freeman, G.B.; Langman, M.D.

    1995-10-01

    Carbon fiber-carbon matrix composites were fabricated using the forced flow-thermal gradient chemical vapor infiltration (FCVI) process. Preforms were prepared by stacking 40 layers of plain weave carbon cloth in a graphite holder. The preforms were infiltrated using propylene, propane, and methane. The present work showed that the FCVI process is well suited for fabricating carbon-carbon composites; without optimization of the process, the authors have achieved uniform and thorough densification. Composites with porosities as low as 7% were fabricated in 8--12 h. The highest deposition rate obtained in the present study was {approximately}3 {micro}m/h which is more than an order of magnitude faster than the typical value of 0.1--0.25 {micro}m/h for the isothermal process. It was also found that the use of propylene and propane as reagents resulted in faster infiltration compared to methane.

  13. Characterization and chemical surface texturization of bulk ZnTe crystals grown by temperature gradient solution growth

    NASA Astrophysics Data System (ADS)

    Yang, Rui; Jie, Wan-qi; Liu, Hang

    2015-07-01

    Using tellurium as a solvent, we grew ZnTe ingots of 30 mm in diameter and 70 mm in length by a temperature gradient solution growth method. Hall tests conducted at 300 K indicated that the as-grown ZnTe exhibits p-type conductivity, with a carrier concentration of approximately 1014 cm-3, a mobility of approximately 300 cm2·V-1·s-1, and a resistivity of approximately 102 Ω·cm. A simple and effective method was proposed for chemical surface texturization of ZnTe using an HF:H2O2:H2O etchant. Textures with the sizes of approximately 1 µm were produced on {100}, {110}, and {111}Zn surfaces after etching. The etchant is also very promising in crystal characterization because of its strong anisotropic character and Te-phase selectivity.

  14. Controlling the long-range corrections in atomistic Monte Carlo simulations of two-phase systems.

    PubMed

    Goujon, Florent; Ghoufi, Aziz; Malfreyt, Patrice; Tildesley, Dominic J

    2015-10-13

    The long-range correction to the surface tension can amount to up to 55% of the calculated value of the surface tension for cutoffs in the range of 2.1-6.4 σ. The calculation of the long-range corrections to the surface tension and to the configurational energy in two-phase systems remains an active area of research. In this work, we compare the long-range corrections methods proposed by Guo and Lu ( J. Chem. Phys. 1997 , 106 , 3688 - 3695 ) and Janeček ( J. Phys. Chem. B 2006 , 110 , 6264 - 6269 ) for the calculation of the surface tension and of the coexisting densities in Monte Carlo simulations of the truncated Lennard-Jones potential and the truncated and shifted Lennard-Jones potential models. These methods require an estimate of the long-range correction at each step in the Monte Carlo simulation. We apply the full version of the Guo and Lu method, which involves the calculation of a double integral that contains a series of density differences, and we compare these results with the simplified version of the method which is routinely used in two-phase simulations. We conclude that the cutoff dependencies of the surface tension and coexisting densities are identical for the full versions of Guo and Lu and Janeček methods. We show that it is possible to avoid applying the long-range correction at every step by using the truncated Lennard-Jones potential with a cutoff rc ≥ 5 σ. The long-range correction can then be applied at the end of the simulation. The limiting factor in the accurate calculation of this final correction is an accurate estimate of the coexisting densities. Link-cell simulations performed using a cutoff rc = 5.5 σ require twice as much computing time as those with a more typical cutoff of rc = 3.0 σ. The application of the Janeček correction increases the running time of the simulation by less than 10%, and it can be profitably applied with the shorter cutoff. PMID:26574249

  15. Uranium geochemistry on the Amazon shelf: Chemical phase partitioning and cycling across a salinity gradient

    SciTech Connect

    Swarzenski, P.W.; McKee, B.A.; Booth, J.G.

    1995-01-01

    The size distribution of U was examined in surface waters of the Amazon shelf. Water samples were collected during a low discharge river stage across a broad salinity gradient (0.3-35.4%) and fractionated by planar filtration and tangential-flow ultrafiltration into (1) solution (U{sub s}, <10,000 MW; {approximately}1-10 nm), (2) colloidal (U{sub c}, 10,000 MW-0.4 {mu}m), (3) dissolved (U{sub d} <0.4 {mu}m), and (4) particulate (U{sub p} >0.4 {mu}m) phases. Concentrations of colloidal U comprise up to 92% of the dissolved U fraction at the river mouth and attain highest values ({approximately}0.45 {mu}g/L) in the productive, biogenic region of the Amazon shelf (salinities above {approximately}20%). U{sub d} and U{sub c} distributions are highly nonconservative relative to ideal dilution of river water and seawater, indicating extensive removal at salinities below {approximately}10%. The distribution of U{sub s} also shows some nonconservative behavior, yet removal, if any, is minimal. Saltwater-induced precipitation and aggregation of riverine colloidal material is most likely the dominant mechanism of U removal in the low salinity, terrigenous region of the Amazon shelf. There is evident of a substantial colloidal U input ({approximately}245% of the riverine U{sub c} flux) into surface waters above 5%. Such U{sub c} enrichment most likely is the result of colloidal U-rich porewater diffusion/advection from the seabed and fluid muds or shelf-wide particle-colloid disaggregation. Removal of solution and dissolved phase U via a colloidal intermediate and U{sub c} aggregation in terms of coagulation phase U via a colloidal intermediate and U{sub c} aggregation was examined in terms of coagulation theory. The high reactive nature of all U phases on the Amazon shelf suggests that remobilization and fractionation of U may also occur in other river-influenced coastal environments.

  16. PBDEs as indicator chemicals of urbanization along an urban/rural gradient in South China.

    PubMed

    Sun, Jian-Lin; Chen, Zheng-Xia; Ni, Hong-Gang; Zeng, Hui

    2013-07-01

    Fourteen polybrominated diphenyl ethers (PBDEs) were measured in surface sediments collected from an urban watershed in a rapidly urbanizing region, Shenzhen, China. BDE209 was the predominant congener of PBDEs detected in surface sediments, which was consistent with the fact that technical deca-BDE mixtures are the dominant PBDE formulation used in China, especially the Pearl River Delta. A positive association between sediment PBDEs and catchment degree of urbanization suggested that the rapid urbanization process may be affecting the PBDEs levels in surface sediments. Similar to the "urban heat island effect", an "urban pollution island effect" was observed in the present study. These results indicated that PBDEs can be used as potential indicator chemicals of catchment's urbanization process in the present region. PMID:23415307

  17. Adiabatic potential-energy curves of long-range Rydberg molecules: Two-electron R -matrix approach

    NASA Astrophysics Data System (ADS)

    Tarana, Michal; Čurík, Roman

    2016-01-01

    We introduce a computational method developed for study of long-range molecular Rydberg states of such systems that can be approximated by two electrons in a model potential of the atomic cores. Only diatomic molecules are considered. The method is based on a two-electron R -matrix approach inside a sphere centered on one of the atoms. The wave function is then connected to a Coulomb region outside the sphere via a multichannel version of the Coulomb Green's function. This approach is put into a test by its application to a study of Rydberg states of the hydrogen molecule for internuclear distances R from 20 to 400 bohrs and energies corresponding to n from 3 to 22. The results are compared with previous quantum chemical calculations (lower quantum numbers n ) and computations based on contact-potential models (higher quantum numbers n ).

  18. Low-frequency source for very long-range underwater communication.

    PubMed

    Mosca, Frédéric; Matte, Guillaume; Shimura, Takuya

    2013-01-01

    Very long-range underwater acoustic communication (UAC) is crucial for long cruising (>1000 km) autonomous underwater vehicles (AUVs). Very long-range UAC source for AUV must exhibit high electro-acoustic efficiency (>60%) and compactness. This paper describes the Janus-Hammer Bell (JHB) transducer that has been designed for this purpose and meets those requirements. The transducer works on the 450-550 Hz bandwidth and reaches source level above 200 dB (ref. 1 μPa at 1 m) with 1 kW excitation and full immersion capability. JHB source has been used for communication experiments by the Japanese institute for marine technology (Japan Agency for Marine-Earth Science and Technology) achieving a baud rate of 100 bits/s at 1000 km. PMID:23298019

  19. Long-range spoof surface plasmons on the doubly corrugated metal surfaces

    NASA Astrophysics Data System (ADS)

    Liu, Yong-Qiang; Kong, Ling-Bao; Liu, Pu-Kun

    2016-07-01

    In this paper, symmetric spoof surface plasmon (SSP) mode on the doubly corrugated metal surfaces is indentified as long-range spoof surface plasmon (LRSSP) because of its extreme low propagation loss and symmetric dominant field profile so as short-range SSP (SRSSP) for anti-symmetric mode. Based on theoretical calculation and numerical simulation of finite integration method, symmetric and anti-symmetric SSP modes with various gap sizes between these two identical corrugated metal surfaces are investigated in terahertz (THz) regime and good agreement is realized. Besides, the low loss superiority of LRSSP diminishes along with the increased gap size. This work opens up new avenues to utilize this long-range surface mode in far-infrared, THz or lower frequency band and can find many potential applications such as low-loss waveguide, filters and novel electronic sources.

  20. Electrically tunable birefringence of a polymer composite with long-range orientational ordering of liquid crystals.

    PubMed

    Choi, Byeongdae; Song, Seongkyu; Jeong, Soon Moon; Chung, Seok-Hwan; Glushchenko, Anatoliy

    2014-07-28

    We report an optical film with electrically tunable birefringence in which the liquid crystals (LCs), mixed with the host polymer, form long-range ordering. The film was prepared through polymerization without phase separation between the LCs and polymers. Driving voltage below 30 V for full switching of birefringence is achieved in a 6 μm-thick film. Electro-optical investigations for the film suggest that the long-range ordering of the LCs mixed in the film caused by polymerization lead to rotations of the LCs as well as optical anisotropy in the film. These films with electrically tunable birefringence could have applications as flexible light modulators and phase retardation films for 2D-3D image switching. PMID:25089422

  1. Impact of Local Pollution Versus Long Range Transported Aerosols on Clouds and Precipitation over California

    NASA Astrophysics Data System (ADS)

    Prather, K. A.

    2015-12-01

    Aerosols form cloud droplets and ice crystals in clouds and can profoundly impact precipitation processes. In-situ aircraft measurements of the composition of individual cloud residuals have been used to study the impact of different aerosol sources including sea spray, dust, soot, and biomass burning on cloud microphysics and precipitation processes. Aircraft studies in 2011 as part of the CalWater project showed that long range transport of dust aerosols from as far away as Africa and biological particles can lead to an increase in the amount of snowfall over California. This presentation will describe results from CalWater-2015 involving aircraft and ground-based measurements at a coastal site. A discussion of the aerosol sources measured in clouds will be presented detailing the relative impacts of local versus long range transported pollution aerosols over California.

  2. Spin Superfluidity and Long-Range Transport in Thin-Film Ferromagnets.

    PubMed

    Skarsvåg, Hans; Holmqvist, Cecilia; Brataas, Arne

    2015-12-01

    In ferromagnets, magnons may condense into a single quantum state. Analogous to superconductors, this quantum state may support transport without dissipation. Recent works suggest that longitudinal spin transport through a thin-film ferromagnet is an example of spin superfluidity. Although intriguing, this tantalizing picture ignores long-range dipole interactions; here, we demonstrate that such interactions dramatically affect spin transport. In single-film ferromagnets, "spin superfluidity" only exists at length scales (a few hundred nanometers in yttrium iron garnet) somewhat larger than the exchange length. Over longer distances, dipolar interactions destroy spin superfluidity. Nevertheless, we predict the reemergence of spin superfluidity in trilayer ferromagnet-normal metal-ferromagnet films that are ∼1  μm in size. Such systems also exhibit other types of long-range spin transport in samples that are several micrometers in size. PMID:26684138

  3. Spontaneous emission noise in long-range surface plasmon polariton waveguide based optical gyroscope

    PubMed Central

    Wang, Yang-Yang; Zhang, Tong

    2014-01-01

    Spontaneous emission noise is an important limit to the performance of active plasmonic devices. Here, we investigate the spontaneous emission noise in the long-range surface plasmon-polariton waveguide based optical gyroscope. A theoretical model of the sensitivity is established to study the incoherent multi-beam interference of spontaneous emission in the gyroscope. Numerical results show that spontaneous emission produces a drift in the transmittance spectra and lowers the signal-to-noise-ratio of the gyroscope. It also strengthens the shot noise to be the main limit to the sensitivity of the gyroscope for high propagation loss. To reduce the negative effects of the spontaneous emission noise on the gyroscope, an external feedback loop is suggested to estimate the drift in the transmittance spectra and therefor enhance the sensitivity. Our work lays a foundation for the improvement of long-range surface plasmon-polariton gyroscope and paves the way to its practical application. PMID:25234712

  4. Against the long-range spectral leakage of the cosine window family

    NASA Astrophysics Data System (ADS)

    Chen, Kui Fu; Jiang, Jing Tao; Crowsen, Stephen

    2009-06-01

    Suppressing spectral leakage in the fast Fourier transform (FFT) has been investigated for over 30 years. Regarding the frequently used cosine window family, it is observed that the long-range leakage sampled by FFT spectral lines follow a flat trajectory. Consequently, the long-range leakage is approximated by polynomials in this paper. In light of this parametric model, the interpolating formula is presented with up to nine-point for a cosine window with maximum side lobe decaying. Its expression is general in the window order and number of interpolating points. Some well-known formulas of the modulus-based interpolated FFT are parallel to special cases of the new formula, but the former are susceptible to significant bias at coherent sampling conditions. The new formula was tested with real-valued signals containing a single tone and then duel tones. It is demonstrated the new formula is easy to implement and is free of the significant bias aforementioned.

  5. Entropy and long-range memory in random symbolic additive Markov chains

    NASA Astrophysics Data System (ADS)

    Melnik, S. S.; Usatenko, O. V.

    2016-06-01

    The goal of this paper is to develop an estimate for the entropy of random symbolic sequences with elements belonging to a finite alphabet. As a plausible model, we use the high-order additive stationary ergodic Markov chain with long-range memory. Supposing that the correlations between random elements of the chain are weak, we express the conditional entropy of the sequence by means of the symbolic pair correlation function. We also examine an algorithm for estimating the conditional entropy of finite symbolic sequences. We show that the entropy contains two contributions, i.e., the correlation and the fluctuation. The obtained analytical results are used for numerical evaluation of the entropy of written English texts and DNA nucleotide sequences. The developed theory opens the way for constructing a more consistent and sophisticated approach to describe the systems with strong short-range and weak long-range memory.

  6. Fractal mechanisms and heart rate dynamics. Long-range correlations and their breakdown with disease

    NASA Technical Reports Server (NTRS)

    Peng, C. K.; Havlin, S.; Hausdorff, J. M.; Mietus, J. E.; Stanley, H. E.; Goldberger, A. L.

    1995-01-01

    Under healthy conditions, the normal cardiac (sinus) interbeat interval fluctuates in a complex manner. Quantitative analysis using techniques adapted from statistical physics reveals the presence of long-range power-law correlations extending over thousands of heartbeats. This scale-invariant (fractal) behavior suggests that the regulatory system generating these fluctuations is operating far from equilibrium. In contrast, it is found that for subjects at high risk of sudden death (e.g., congestive heart failure patients), these long-range correlations break down. Application of fractal scaling analysis and related techniques provides new approaches to assessing cardiac risk and forecasting sudden cardiac death, as well as motivating development of novel physiologic models of systems that appear to be heterodynamic rather than homeostatic.

  7. Excitation of Ultracold Molecules to ``TRILOBITE-LIKE" Long-Range Molecular Rydberg States

    NASA Astrophysics Data System (ADS)

    Bellos, M. A.; Carollo, R.; Banerjee, J.; Eyler, E. E.; Gould, P. L.; Stwalley, W. C.

    2013-06-01

    A class of long-range Rydberg molecules, sometimes called ``trilobite states", occurs when a ground-state atom is embedded in the electronic cloud of a Rydberg atom. The bond between the Rydberg atom and the ground-state atom originates from the low-energy scattering of the Rydberg electron from the ground-state atom. We produce trilobite-like states of ultracold Rb_2 at low principal quantum numbers and at internuclear separations less than 40 bohr. We populate these states through single-photon ultraviolet transitions starting from molecules in high-lying vibrational levels of the lowest triplet state. This demonstrates that long-range Rydberg molecules can also be excited through bound-bound transitions, in addition to previous studies that used free-bound transitions. We also discuss the advantages of a bound-bound pathway. C. H. Greene, A. S. Dickinson, and H. R. Sadeghpour, Phys. Rev. Lett. 85, 2458 (2000).

  8. Fractional quantum mechanics on networks: Long-range dynamics and quantum transport.

    PubMed

    Riascos, A P; Mateos, José L

    2015-11-01

    In this paper we study the quantum transport on networks with a temporal evolution governed by the fractional Schrödinger equation. We generalize the dynamics based on continuous-time quantum walks, with transitions to nearest neighbors on the network, to the fractional case that allows long-range displacements. By using the fractional Laplacian matrix of a network, we establish a formalism that combines a long-range dynamics with the quantum superposition of states; this general approach applies to any type of connected undirected networks, including regular, random, and complex networks, and can be implemented from the spectral properties of the Laplacian matrix. We study the fractional dynamics and its capacity to explore the network by means of the transition probability, the average probability of return, and global quantities that characterize the efficiency of this quantum process. As a particular case, we explore analytically these quantities for circulant networks such as rings, interacting cycles, and complete graphs. PMID:26651751

  9. On the Continuum Limit for Discrete NLS with Long-Range Lattice Interactions

    NASA Astrophysics Data System (ADS)

    Kirkpatrick, Kay; Lenzmann, Enno; Staffilani, Gigliola

    2013-02-01

    We consider a general class of discrete nonlinear Schrödinger equations (DNLS) on the lattice {h{Z}} with mesh size h > 0. In the continuum limit when h → 0, we prove that the limiting dynamics are given by a nonlinear Schrödinger equation (NLS) on {{R}} with the fractional Laplacian (-Δ) α as dispersive symbol. In particular, we obtain that fractional powers {1/2 < α < 1} arise from long-range lattice interactions when passing to the continuum limit, whereas the NLS with the usual Laplacian -Δ describes the dispersion in the continuum limit for short-range or quick-decaying interactions (e. g., nearest-neighbor interactions). Our results rigorously justify certain NLS model equations with fractional Laplacians proposed in the physics literature. Moreover, the arguments given in our paper can be also applied to discuss the continuum limit for other lattice systems with long-range interactions.

  10. Fluorescence quenching of quantum dots by gold nanoparticles: a potential long range spectroscopic ruler.

    PubMed

    Samanta, Anirban; Zhou, Yadong; Zou, Shengli; Yan, Hao; Liu, Yan

    2014-09-10

    The dependence of quantum dot (QD) fluorescence emission on the proximity of 30 nm gold nanoparticles (AuNPs) was studied with controlled interparticle distances ranging from 15 to 70 nm. This was achieved by coassembling DNA-conjugated QDs and AuNPs in a 1:1 ratio at precise positions on a triangular-shaped DNA origami platform. A profound, long-range quenching of the photoluminescence intensity of the QDs was observed. A combination of static and time-resolved fluorescence measurements suggests that the quenching is due to an increase in the nonradiative decay rate of QD emission. Unlike FRET, the energy transfer is inversely proportional to the 2.7th power of the distance between nanoparticles with half quenching at ∼28 nm. This long-range quenching phenomena may be useful for developing extended spectroscopic rulers in the future. PMID:25084363

  11. Photoassociation of a cold-atom-molecule pair: Long-range quadrupole-quadrupole interactions

    SciTech Connect

    Lepers, M.; Dulieu, O.; Kokoouline, V.

    2010-10-15

    The general formalism of the multipolar expansion of electrostatic interactions is applied to the calculation of the potential energy between an excited atom (without fine structure) and a ground-state diatomic molecule at large mutual separations. Both partners exhibit a permanent quadrupole moment so that their mutual long-range interaction is dominated by a quadrupole-quadrupole term, which is attractive enough to bind trimers. Numerical results are given for an excited Cs(6{sup 2}P) atom and a ground-state Cs{sub 2} molecule. The prospects for achieving photoassociation of a cold-atom-dimer pair are thus discussed and found promising. The formalism can be generalized to the long-range interaction between molecules to investigate the formation of cold tetramers.

  12. Stable distribution and long-range correlation of Brent crude oil market

    NASA Astrophysics Data System (ADS)

    Yuan, Ying; Zhuang, Xin-tian; Jin, Xiu; Huang, Wei-qiang

    2014-11-01

    An empirical study of stable distribution and long-range correlation in Brent crude oil market was presented. First, it is found that the empirical distribution of Brent crude oil returns can be fitted well by a stable distribution, which is significantly different from a normal distribution. Second, the detrended fluctuation analysis for the Brent crude oil returns shows that there are long-range correlation in returns. It implies that there are patterns or trends in returns that persist over time. Third, the detrended fluctuation analysis for the Brent crude oil returns shows that after the financial crisis 2008, the Brent crude oil market becomes more persistence. It implies that the financial crisis 2008 could increase the frequency and strength of the interdependence and correlations between the financial time series. All of these findings may be used to improve the current fractal theories.

  13. Quantum spin models with long-range interactions and tunnelings: a quantum Monte Carlo study

    NASA Astrophysics Data System (ADS)

    Maik, Michał; Hauke, Philipp; Dutta, Omjyoti; Zakrzewski, Jakub; Lewenstein, Maciej

    2012-11-01

    We use a quantum Monte Carlo method to investigate various classes of two-dimensional spin models with long-range interactions at low temperatures. In particular, we study a dipolar XXZ model with U(1) symmetry that appears as a hard-core boson limit of an extended Hubbard model describing polarized dipolar atoms or molecules in an optical lattice. Tunneling, in such a model, is short-range, whereas density-density couplings decay with distance following a cubic power law. We also investigate an XXZ model with long-range couplings of all three spin components—such a model describes a system of ultracold ions in a lattice of microtraps. We describe an approximate phase diagram for such systems at zero and at finite temperature, and compare their properties. In particular, we compare the extent of crystalline, superfluid and supersolid phases. Our predictions apply directly to current experiments with mesoscopic numbers of polar molecules and trapped ions.

  14. Organic thin films. Rational synthesis of organic thin films with exceptional long-range structural integrity.

    PubMed

    Seiki, Noriya; Shoji, Yoshiaki; Kajitani, Takashi; Ishiwari, Fumitaka; Kosaka, Atsuko; Hikima, Takaaki; Takata, Masaki; Someya, Takao; Fukushima, Takanori

    2015-06-01

    Highly oriented, domain-boundary-free organic thin films could find use in various high-performance organic materials and devices. However, even with state-of-the-art supramolecular chemistry, it is difficult to construct organic thin films with structural integrity in a size regime beyond the micrometer length scale. We show that a space-filling design, relying on the two-dimensional (2D) nested hexagonal packing of a particular type of triptycene, enables the formation of large-area molecular films with long-range 2D structural integrity up to the centimeter length scale by vacuum evaporation, spin-coating, and cooling from the isotropic liquid of the triptycene. X-ray diffraction analysis and microscopic observations reveal that triptycene molecules form a completely oriented 2D (hexagonal triptycene array) + 1D (layer stacking) structure, which is key for the long-range propagation of structural order. PMID:26045433

  15. Dark matter, long-range forces, and large-scale structure

    NASA Technical Reports Server (NTRS)

    Gradwohl, Ben-Ami; Frieman, Joshua A.

    1992-01-01

    If the dark matter in galaxies and clusters is nonbaryonic, it can interact with additional long-range fields that are invisible to experimental tests of the equivalence principle. We discuss the astrophysical and cosmological implications of a long-range force coupled only to the dark matter and find rather tight constraints on its strength. If the force is repulsive (attractive), the masses of galaxy groups and clusters (and the mean density of the universe inferred from them) have been systematically underestimated (overestimated). We explore the consequent effects on the two-point correlation function, large-scale velocity flows, and microwave background anisotropies, for models with initial scale-invariant adiabatic perturbations and cold dark matter.

  16. Collective modes in charge-density waves and long-range Coulomb interactions

    NASA Astrophysics Data System (ADS)

    Virosztek, Attila; Maki, Kazumi

    1993-07-01

    We study theoretically the collective modes in charge-density waves in the presence of long-range Coulomb interaction. We find that earlier works by Takada and his collaborators are inadequate since they introduced inconsistent approximations in evaluating a variety of correlation functions. The amplitude mode is unaffected by the Coulomb interaction, while the phase mode splits into the phason with linear dispersion (i.e., acoustic mode) and the optical mode with an energy gap in the presence of the Coulomb interaction. In particular, we establish the temperature dependence of the phason velocity vφ. A comparison with recent neutron-scattering data on the phason velocity in the charge-density wave of a single crystal of blue bronze K0.3MoO3 indicates that mean-field theory which includes the long-range Coulomb interaction gives an excellent description of the observed phason velocity.

  17. Short-range/Long-range Integrated Target (SLIT) for Video Guidance Sensor Rendezvous and Docking

    NASA Technical Reports Server (NTRS)

    Roe, Fred D. (Inventor); Bryan, Thomas C. (Inventor)

    2009-01-01

    A laser target reflector assembly for mounting upon spacecraft having a long-range reflector array formed from a plurality of unfiltered light reflectors embedded in an array pattern upon a hemispherical reflector disposed upon a mounting plate. The reflector assembly also includes a short-range reflector array positioned upon the mounting body proximate to the long-range reflector array. The short-range reflector array includes three filtered light reflectors positioned upon extensions from the mounting body. The three filtered light reflectors retro-reflect substantially all incident light rays that are transmissive by their monochromatic filters and received by the three filtered light reflectors. In one embodiment the short-range reflector array is embedded within the hemispherical reflector,

  18. Evaluation of Long-Range Lightning Detection Networks Using TRMM/LIS Observations

    NASA Technical Reports Server (NTRS)

    Rudlosky, Scott D.; Holzworth, Robert H.; Carey, Lawrence D.; Schultz, Chris J.; Bateman, Monte; Cecil, Daniel J.; Cummins, Kenneth L.; Petersen, Walter A.; Blakeslee, Richard J.; Goodman, Steven J.

    2011-01-01

    Recent advances in long-range lightning detection technologies have improved our understanding of thunderstorm evolution in the data sparse oceanic regions. Although the expansion and improvement of long-range lightning datasets have increased their applicability, these applications (e.g., data assimilation, atmospheric chemistry, and aviation weather hazards) require knowledge of the network detection capabilities. Toward this end, the present study evaluates data from the World Wide Lightning Location Network (WWLLN) using observations from the Lightning Imaging Sensor (LIS) aboard the Tropical Rainfall Measurement Mission (TRMM) satellite. The study documents the WWLLN detection efficiency and location accuracy relative to LIS observations, describes the spatial variability in these performance metrics, and documents the characteristics of LIS flashes that are detected by WWLLN. Improved knowledge of the WWLLN detection capabilities will allow researchers, algorithm developers, and operational users to better prepare for the spatial and temporal coverage of the upcoming GOES-R Geostationary Lightning Mapper (GLM).

  19. Pairing in high-density neutron matter including short- and long-range correlations

    NASA Astrophysics Data System (ADS)

    Ding, Dong; Rios, Arnau; Dussan, Helber; Dickhoff, Willem; Witte, Sam; Polls, Artur

    2016-03-01

    To address open questions in neutron star phenomenology, pairing gaps of 1S0 and 3P2 -3F2 channels in a wide range of densities has been calculated using three different interactions (AV18 CDbonn N3LO). Traditionally, the Bardeen-Cooper-Schrieffer(BCS) approach has been used to compute gaps from bare nucleon-nucleon interactions. Here, we incorporate the influence of short- and long-range correlations in the pairing gaps. Short-range correlations (SRC) are treated including the appropriate fragmentation of single-particle states, and they suppress the gaps substantially. Long-range correlations(LRC) dress the pairing interaction via density and spin modes, and provide a relatively small correction. Results are relevant and parametrized in a user friendly way for neutron-star cooling scenarios, in particular in view of the recent observational data on Cassiopeia A.

  20. FY 1991--FY 1995 Information Technology Resources Long-Range Plan

    SciTech Connect

    Not Available

    1989-12-01

    The Department of Energy has consolidated its plans for Information Systems, Computing Resources, and Telecommunications into a single document, the Information Technology Resources Long-Range Plan. The consolidation was done as a joint effort by the Office of ADP Management and the Office of Computer Services and Telecommunications Management under the Deputy Assistant Secretary for Administration, Information, and Facilities Management. This Plan is the product of a long-range planning process used to project both future information technology requirements and the resources necessary to meet those requirements. It encompasses the plans of the various organizational components within the Department and its management and operating contractors over the next 5 fiscal years, 1991 through 1995.

  1. ATCOM: accelerated image processing for terrestrial long-range imaging through atmospheric effects

    NASA Astrophysics Data System (ADS)

    Curt, Petersen F.; Paolini, Aaron

    2013-05-01

    Long-range video surveillance performance is often severely diminished due to atmospheric turbulence. The larger apertures typically used for video-rate operation at long-range are particularly susceptible to scintillation and blurring effects that limit the overall diffraction efficiency and resolution. In this paper, we present research progress made toward a digital signal processing technique which aims to mitigate the effects of turbulence in real-time. Our previous work in this area focused on an embedded implementation for portable applications. Our more recent research has focused on functional enhancements to the same algorithm using general-purpose hardware. We present some techniques that were successfully employed to accelerate processing of high-definition color video streams and study performance under nonideal conditions involving moving objects and panning cameras. Finally, we compare the real-time performance of two implementations using a CPU and a GPU.

  2. Reinvestigation of long-range magnetic ordering in icosahedral Tb-Mg-Zn

    NASA Astrophysics Data System (ADS)

    Islam, Z.; Fisher, I. R.; Zarestky, J.; Canfield, P. C.; Stassis, C.; Goldman, A. I.

    1998-05-01

    We present results of a study of possible magnetic ordering in the icosahedral phase of Tb-Mg-Zn probed by bulk magnetization measurements and neutron diffraction. Measurements on both crushed single grains and cast polycrystalline samples of Tb-Mg-Zn were performed. Magnetization measurements on both samples reveal only a spin-glass-like transition at approximately 5.8 K. Neutron diffraction from the crushed single grains reveals only short-range magnetic ordering at low temperatures, with no evidence of the long-range magnetic ordering reported previously [Charrier, Ouladdiaf, and Schmitt, Phys. Rev. Lett. 78, 4637 (1997)]. Likewise, the cast polycrystalline samples exhibit primarily diffuse magnetic scattering at low temperature, but at least one relatively sharp diffraction peak was observed. Our results indicate that for single grain samples there is no long-range magnetic ordering and that, at best, the magnetic ordering in these quasicrystalline alloys is not very robust.

  3. Pairing in high-density neutron matter including short- and long-range correlations

    NASA Astrophysics Data System (ADS)

    Ding, D.; Rios, A.; Dussan, H.; Dickhoff, W. H.; Witte, S. J.; Carbone, A.; Polls, A.

    2016-08-01

    Pairing gaps in neutron matter need to be computed in a wide range of densities to address open questions in neutron-star phenomenology. Traditionally, the Bardeen-Cooper-Schrieffer approach has been used to compute gaps from bare nucleon-nucleon interactions. Here we incorporate the influence of short- and long-range correlations in the pairing gaps. Short-range correlations are treated, including the appropriate fragmentation of single-particle states, and substantially suppress the gaps. Long-range correlations dress the pairing interaction via density and spin modes and provide a relatively small correction. We use different interactions, some with three-body forces, as a starting point to control for any systematic effects. Results are relevant for neutron-star cooling scenarios, in particular in view of the recent observational data on Cassiopeia A.

  4. Instabilities and relaxation to equilibrium in long-range oscillator chains

    NASA Astrophysics Data System (ADS)

    Miloshevich, George; Nguenang, Jean-Pierre; Dauxois, Thierry; Khomeriki, Ramaz; Ruffo, Stefano

    2015-03-01

    We study instabilities and relaxation to equilibrium in a long-range extension of the Fermi-Pasta-Ulam-Tsingou (FPU) oscillator chain by exciting initially the lowest Fourier mode. Localization in mode space is stronger for the long-range FPU model. This allows us to uncover the sporadic nature of instabilities, i.e., by varying initially the excitation amplitude of the lowest mode, which is the control parameter, instabilities occur in narrow amplitude intervals. Only for sufficiently large values of the amplitude, the system enters a permanently unstable regime. These findings also clarify the long-standing problem of the relaxation to equilibrium in the short-range FPU model. Because of the weaker localization in mode space of this latter model, the transfer of energy is retarded and relaxation occurs on a much longer timescale.

  5. Long-range repulsion of colloids driven by ion exchange and diffusiophoresis

    PubMed Central

    Florea, Daniel; Musa, Sami; Huyghe, Jacques M. R.; Wyss, Hans M.

    2014-01-01

    Interactions between surfaces and particles in aqueous suspension are usually limited to distances smaller than 1 μm. However, in a range of studies from different disciplines, repulsion of particles has been observed over distances of up to hundreds of micrometers, in the absence of any additional external fields. Although a range of hypotheses have been suggested to account for such behavior, the physical mechanisms responsible for the phenomenon still remain unclear. To identify and isolate these mechanisms, we perform detailed experiments on a well-defined experimental system, using a setup that minimizes the effects of gravity and convection. Our experiments clearly indicate that the observed long-range repulsion is driven by a combination of ion exchange, ion diffusion, and diffusiophoresis. We develop a simple model that accounts for our data; this description is expected to be directly applicable to a wide range of systems exhibiting similar long-range forces. PMID:24748113

  6. Long range correlations in tree ring chronologies of the USA: Variation within and across species

    NASA Astrophysics Data System (ADS)

    Bowers, M. C.; Gao, J. B.; Tung, W. W.

    2013-02-01

    Abstract Tree ring width data are among the best proxies for reconstructing past temperature and precipitation records. The discovery of fractal scaling and long-memory in meteorological and hydrological signals motivates us to investigate such properties in tree ring chronologies. Detrended fluctuation analysis and adaptive fractal analysis are utilized to estimate the Hurst parameter values of 697 tree ring chronologies from the continental United States. We find significant differences in the Hurst parameter values across the 10 species studied in the work. The <span class="hlt">long-range</span> scaling relations found here suggest that the behavior of tree ring growth observed in a short calibration period may be similar to the general behavior of tree ring growth in a much longer period, and therefore, the limited calibration period may be more useful than originally thought. The variations of the <span class="hlt">long-range</span> correlations within and across species may be further explored in future to better reconstruct paleoclimatic records.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://www.osti.gov/scitech/servlets/purl/10159129','SCIGOV-STC'); return false;" href="http://www.osti.gov/scitech/servlets/purl/10159129"><span id="translatedtitle">Information resources management <span class="hlt">long-range</span> plan, FY1994--1998</span></a></p> <p><a target="_blank" href="http://www.osti.gov/scitech">SciTech Connect</a></p> <p>Not Available</p> <p>1993-04-01</p> <p>This document describes IRM activities and the information technology resources and capabilities of the Department, the future requirements, and the strategies and plans to satisfy the identified requirements. The <span class="hlt">long-range</span> planning process provides the systematic means to meet this objective and assists the Department in assuring that information technology (IT) support is provided in an efficient, effective, and timely manner so that its programmatic missions can be accomplished. Another important objective of the Plan is to promote better understanding, both within and external to the Department, of its IT environment, requirements, issues, and recommended solutions. This DOE IRM Plan takes into consideration the IRM requirements of approximately 50 different sites. The annual <span class="hlt">long-range</span> planning cycle for supporting this Plan was initiated by a Call in August 1991 for site plans to be submitted in February 1992 by those Departmental components and contractors with major IRM requirements.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://www.osti.gov/scitech/biblio/6731272','SCIGOV-STC'); return false;" href="http://www.osti.gov/scitech/biblio/6731272"><span id="translatedtitle">ESR study of 2-substituted 2-adamantyl radicals. Configuration and <span class="hlt">long-range</span> hyperfine interaction</span></a></p> <p><a target="_blank" href="http://www.osti.gov/scitech">SciTech Connect</a></p> <p>Kira, Mitsuo; Akiyama, Mieko; Ichinose, Michiko; Sakurai, Hideki )</p> <p>1989-10-11</p> <p>Structure and <span class="hlt">long-range</span> hyperfine interaction in 2-adamantyl, 5,7-dimethyl-2-adamantyl, and the various 2-substituted radicals (substituent = CH{sub 3}, CH{sub 2}SiMe{sub 3}, OSiMe{sub 3}, SSiMe{sub 3}, CH{sub 2}GeMe{sub 3}, etc.) were studied by ESR. The origin of the <span class="hlt">long-range</span> hyperfine interaction is discussed on the basis of the comparison between experimental and theoretical hfs values. The analyses of hfs values for persistent 2-bis(trimethylsilyl)methyl-2-adamantyl radical and the 5,7-dimethyl derivative were made by the assistance of the ENDOR spectrum.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://www.ncbi.nlm.nih.gov/pubmed/20588373','PUBMED'); return false;" href="http://www.ncbi.nlm.nih.gov/pubmed/20588373"><span id="translatedtitle"><span class="hlt">Long-range</span> surface magnetoplasmon on thin plasmon films in the Voigt configuration.</span></a></p> <p><a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Lan, Yung-Chiang; Chen, Chih-Min</p> <p>2010-06-01</p> <p>This study elucidates the characteristics of a <span class="hlt">long-range</span> surface magnetoplasmon (LRSMP) that propagates on a plasmon film with the Voigt configuration. Particle-in-cell (PIC) simulations and theoretical analyses are performed. Simulation results indicate that LRSMP has non-symmetrical fields. The proposed scheme also verifies the non-reciprocal properties of LRSMP as the direction of an applied external magnetic field is reversed. When surface waves propagate on a plasmon film across an interface on one side of which <span class="hlt">long-range</span> surface plasmon (LRSP) is allowed while on the other side of which LRSMP is allowed, the interface behaves similar to a defect and transforms the surface waves into radiation modes owing to the mismatch between the field patterns of LRSP and LRSMP. Furthermore, PIC simulation results confirm the presence of a new high-frequency LRSMP whose frequency exceeds the plasma frequency and lacks a LRSP counterpart. PMID:20588373</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006EL.....74..547M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006EL.....74..547M"><span id="translatedtitle"><span class="hlt">Long-range</span> transport and universality classes in in vitro viral infection spread</span></a></p> <p><a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Manrubia, S. C.; García-Arriaza, J.; Domingo, E.; Escarmís, C.</p> <p>2006-05-01</p> <p>Dispersal mechanisms play a main role in the dynamics of infection spread. Recent experimental results with in vitro infections of foot-and-mouth disease virus reveal that the time needed for the virus to kill a cellular monolayer depends qualitatively on the number of viral particles required to initiate infection in a susceptible cell. A two-dimensional susceptible-infected-removed (SIR) model based on the experimental setting agrees with the observations only when viral particles are subject to <span class="hlt">long-range</span> transport. Numerical and analytical results show that this <span class="hlt">long-range</span> transport plays a role when a single particle causes infection, while it is inefficient when complementation between two or more particles is necessary.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://www.ncbi.nlm.nih.gov/pubmed/27415245','PUBMED'); return false;" href="http://www.ncbi.nlm.nih.gov/pubmed/27415245"><span id="translatedtitle">Entropy and <span class="hlt">long-range</span> memory in random symbolic additive Markov chains.</span></a></p> <p><a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Melnik, S S; Usatenko, O V</p> <p>2016-06-01</p> <p>The goal of this paper is to develop an estimate for the entropy of random symbolic sequences with elements belonging to a finite alphabet. As a plausible model, we use the high-order additive stationary ergodic Markov chain with <span class="hlt">long-range</span> memory. Supposing that the correlations between random elements of the chain are weak, we express the conditional entropy of the sequence by means of the symbolic pair correlation function. We also examine an algorithm for estimating the conditional entropy of finite symbolic sequences. We show that the entropy contains two contributions, i.e., the correlation and the fluctuation. The obtained analytical results are used for numerical evaluation of the entropy of written English texts and DNA nucleotide sequences. The developed theory opens the way for constructing a more consistent and sophisticated approach to describe the systems with strong short-range and weak <span class="hlt">long-range</span> memory. PMID:27415245</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://www.ncbi.nlm.nih.gov/pubmed/26450319','PUBMED'); return false;" href="http://www.ncbi.nlm.nih.gov/pubmed/26450319"><span id="translatedtitle"><span class="hlt">Long-range</span> orientation correlation in dipolar liquids probed by hyper-Rayleigh scattering.</span></a></p> <p><a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Shelton, David P</p> <p>2015-10-01</p> <p>Hyper-Rayleigh scattering (HRS) is sensitive to <span class="hlt">long-range</span> molecular orientation correlation in isotropic liquids composed of dipolar molecules. The correlation functions that appear in the calculation of HRS mediated by the vector part of the first hyperpolarizability β are the same as the correlation functions for the homogeneous isotropic random vector fields that appear in the description of fluid turbulence. Recent experiments measuring the angle and polarization dependence of HRS from water find a dominant transverse mode contribution with amplitude independent of the scattering wavevector, and this observation of transverse mode HRS strongly constrains the form of the orientation correlation function. Analysis of these HRS results for water determines that the <span class="hlt">long-range</span> molecular orientation correlation function varies as r(-3±ε) with |ε| < 0.03 on spatial scales up to 2000 nm. PMID:26450319</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016APS..DMP.T9005Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016APS..DMP.T9005Y"><span id="translatedtitle">Cesium Ultra-<span class="hlt">Long-Range</span> Rydberg Molecules and Many-Body Physics</span></a></p> <p><a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Yang, Jin; Jahangiri, Akbar; Rittenhouse, Seth; Reschke, Margarita; Booth, Donald; Sadeghpour, Hossein; Shaffer, James</p> <p>2016-05-01</p> <p>Ultra-<span class="hlt">long-range</span> Rydberg molecules have received increasing interest recently because of their novel properties such as the ability to serve as an electron trap, the potential to possess kilo-Debye dipole moments, and their unique binding mechanism. Recently, experiments focusing on Rydberg P-state and D-state molecules have revealed interesting new features of these novel molecules, like coupling between singlet and triplet scattering channels, p-wave scattering dominated states and their behavior in magnetic fields. In this presentation, we report our recent observation of Cesium D-state ultra-<span class="hlt">long-range</span> Rydberg molecules and compare our observations to theoretical calculations. We also report our preliminary data on ``polymer'' molecules, which are formed by one Cs Rydberg atom but more than one Cs ground state atom. The transition from a few-body system to a many-body system can provide insight into many-body physics. We acknowledge funding from the NSF.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://www.ncbi.nlm.nih.gov/pubmed/22181921','PUBMED'); return false;" href="http://www.ncbi.nlm.nih.gov/pubmed/22181921"><span id="translatedtitle"><span class="hlt">Long-range</span> crystalline nature of the Skyrmion lattice in MnSi.</span></a></p> <p><a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a></p> <p>Adams, T; Mühlbauer, S; Pfleiderer, C; Jonietz, F; Bauer, A; Neubauer, A; Georgii, R; Böni, P; Keiderling, U; Everschor, K; Garst, M; Rosch, A</p> <p>2011-11-18</p> <p>We report small angle neutron scattering of the Skyrmion lattice in MnSi using an experimental setup that minimizes the effects of demagnetizing fields and double scattering. Under these conditions, the Skyrmion lattice displays resolution-limited Gaussian rocking peaks that correspond to a magnetic correlation length in excess of several hundred micrometers. This is consistent with exceptionally well-defined <span class="hlt">long-range</span> order. We further establish the existence of higher-order scattering, discriminating parasitic double scattering with Renninger scans. The field and temperature dependence of the higher-order scattering arises from an interference effect. It is characteristic for the <span class="hlt">long-range</span> crystalline nature of the Skyrmion lattice as shown by simple mean-field calculations. PMID:22181921</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015PhRvB..92v4504C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015PhRvB..92v4504C"><span id="translatedtitle"><span class="hlt">Long-range</span> order and pinning of charge-density waves in competition with superconductivity</span></a></p> <p><a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Caplan, Yosef; Wachtel, Gideon; Orgad, Dror</p> <p>2015-12-01</p> <p>Recent experiments show that charge-density-wave correlations are prevalent in underdoped cuprate superconductors. The correlations are short ranged at weak magnetic fields but their intensity and spatial extent increase rapidly at low temperatures beyond a crossover field. Here we consider the possibility of <span class="hlt">long-range</span> charge-density-wave order in a model of a layered system where such order competes with superconductivity. We show that in the clean limit, low-temperature <span class="hlt">long-range</span> order is stabilized by arbitrarily weak magnetic fields. This apparent discrepancy with the experiments is resolved by the presence of disorder. Like the field, disorder nucleates halos of charge-density wave, but unlike the former it also disrupts interhalo coherence, leading to a correlation length that is always finite. Our results are compatible with various experimental trends, including the onset of longer range correlations induced by interlayer coupling above a characteristic field scale.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://www.osti.gov/scitech/biblio/486560','SCIGOV-STC'); return false;" href="http://www.osti.gov/scitech/biblio/486560"><span id="translatedtitle">Integrabilities of the <span class="hlt">long-range</span> t-J models with twisted boundary conditions</span></a></p> <p><a target="_blank" href="http://www.osti.gov/scitech">SciTech Connect</a></p> <p>Liu, J.T.; Wang, D.F.</p> <p>1997-02-01</p> <p>The integrability of the one-dimensional <span class="hlt">long-range</span> supersymmetric t-J model has previously been established for both open systems and those closed by periodic boundary conditions through explicit construction of its integrals of motion. Recently the system has been extended to include the effect of magnetic flux, which gives rise to a closed chain with twisted boundary conditions. While the t-J model with twisted boundary conditions has been solved for the ground state and full energy spectrum, proof of its integrability has so far been lacking. In this paper we extend the proof of integrability of the <span class="hlt">long-range</span> supersymmetric t-J model and its SU(m{vert_bar}n) generalization to include the case of twisted boundary conditions. {copyright} {ital 1997} {ital The American Physical Society}</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015PhRvE..92e2814R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015PhRvE..92e2814R"><span id="translatedtitle">Fractional quantum mechanics on networks: <span class="hlt">Long-range</span> dynamics and quantum transport</span></a></p> <p><a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Riascos, A. P.; Mateos, José L.</p> <p>2015-11-01</p> <p>In this paper we study the quantum transport on networks with a temporal evolution governed by the fractional Schrödinger equation. We generalize the dynamics based on continuous-time quantum walks, with transitions to nearest neighbors on the network, to the fractional case that allows <span class="hlt">long-range</span> displacements. By using the fractional Laplacian matrix of a network, we establish a formalism that combines a <span class="hlt">long-range</span> dynamics with the quantum superposition of states; this general approach applies to any type of connected undirected networks, including regular, random, and complex networks, and can be implemented from the spectral properties of the Laplacian matrix. We study the fractional dynamics and its capacity to explore the network by means of the transition probability, the average probability of return, and global quantities that characterize the efficiency of this quantum process. As a particular case, we explore analytically these quantities for circulant networks such as rings, interacting cycles, and complete graphs.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013JMMM..327..110C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013JMMM..327..110C"><span id="translatedtitle">Entanglement and quantum-classical crossover in the extended XX model with <span class="hlt">long-range</span> interactions</span></a></p> <p><a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Campelo, M. W. V.; de Lima, J. P.; Gonçalves, L. L.</p> <p>2013-02-01</p> <p>In this work we considered the one-dimensional extended isotropic XY model (s=1/2) in a transverse field with uniform <span class="hlt">long-range</span> interactions among the z components of the spins. We studied the classical critical behaviour of the model through the behaviour of the magnetization, isothermal susceptibility, internal energy and specific heat. We have obtained exact expressions for these functions and evaluated the critical exponents. The phase diagrams for the classical critical behaviour were built for three cases of the multiplicity p of the multiple spin interaction, namely p=2, p=3 and p→∞. We have also shown that the quantum phase transitions can also be characterized through two quantifiers of entanglement, namely, the concurrence and the von Neumann entropy. We have also verified through the von Neumann entropy how the central charge of the model is affected by the multiplicity p, the coupling exchange J2 and the uniform <span class="hlt">long-range</span> interaction I.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012PhRvE..86b2102R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012PhRvE..86b2102R"><span id="translatedtitle">Anomalous diffusion and <span class="hlt">long-range</span> correlations in the score evolution of the game of cricket</span></a></p> <p><a target="_blank" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a></p> <p>Ribeiro, Haroldo V.; Mukherjee, Satyam; Zeng, Xiao Han T.</p> <p>2012-08-01</p> <p>We investigate the time evolution of the scores of the second most popular sport in the world: the game of cricket. By analyzing, event by event, the scores of more than 2000 matches, we point out that the score dynamics is an anomalous diffusive process. Our analysis reveals that the variance of the process is described by a power-law dependence with a superdiffusive exponent, that the scores are statistically self-similar following a universal Gaussian distribution, and that there are <span class="hlt">long-range</span> correlations in the score evolution. We employ a generalized Langevin equation with a power-law correlated noise that describes all the empirical findings very well. These observations suggest that competition among agents may be a mechanism leading to anomalous diffusion and <span class="hlt">long-range</span> correlation.</p> </li> <li> <p><a target="_blank" onclick="trackOutboundLink('http://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4685257','PMC'); return false;" href="http://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4685257"><span id="translatedtitle">Enzymatic cellulose oxidation is linked to lignin by <span class="hlt">long-range</span> electron transfer</span></a></p> <p><a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a></p> <p>Westereng, Bjørge; Cannella, David; Wittrup Agger, Jane; Jørgensen, Henning; Larsen Andersen, Mogens; Eijsink, Vincent G.H.; Felby, Claus</p> <p>2015-01-01</p> <p>Enzymatic oxidation of cell wall polysaccharides by lytic polysaccharide monooxygenases (LPMOs) plays a pivotal role in the degradation of plant biomass. While experiments have shown that LPMOs are copper dependent enzymes requiring an electron donor, the mechanism and origin of the electron supply in biological systems are only partly understood. We show here that insoluble high molecular weight lignin functions as a reservoir of electrons facilitating LPMO activity. The electrons are donated to the enzyme by <span class="hlt">long-range</span> electron transfer involving soluble low molecular weight lignins present in plant cell walls. Electron transfer was confirmed by electron paramagnetic resonance spectroscopy showing that LPMO activity on cellulose changes the level of unpaired electrons in the lignin. The discovery of a <span class="hlt">long-range</span> electron transfer mechanism links the biodegradation of cellulose and lignin and sheds new light on how oxidative enzymes present in plant degraders may act in concert. 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