Mass transfer effects in a gasification riser
Breault, Ronald W; Li, Tingwen; Nicoletti, Phillip
2013-01-01
In the development of multiphase reacting computational fluid dynamics (CFD) codes, a number of simplifications were incorporated into the codes and models. One of these simplifications was the use of a simplistic mass transfer correlation for the faster reactions and omission of mass transfer effects completely on the moderate speed and slow speed reactions such as those in a fluidized bed gasifier. Another problem that has propagated is that the mass transfer correlation used in the codes is not universal and is being used far from its developed bubbling fluidized bed regime when applied to circulating fluidized bed (CFB) riser reactors. These problems are true for the major CFD codes. To alleviate this problem, a mechanistic based mass transfer coefficient algorithm has been developed based upon an earlier work by Breault et al. This fundamental approach uses the local hydrodynamics to predict a local, time varying mass transfer coefficient. The predicted mass transfer coefficients and the corresponding Sherwood numbers agree well with literature data and are typically about an order of magnitude lower than the correlation noted above. The incorporation of the new mass transfer model gives the expected behavior for all the gasification reactions evaluated in the paper. At the expected and typical design values for the solid flow rate in a CFB riser gasifier an ANOVA analysis has shown the predictions from the new code to be significantly different from the original code predictions. The new algorithm should be used such that the conversions are not over predicted. Additionally, its behaviors with changes in solid flow rate are consistent with the changes in the hydrodynamics.
Taylor, R.; Krishna, R.
1993-01-01
This is an important book on multicomponent mass transfer, meant for readers already acquainted with the theory of mass transfer and the fundamentals of transport phenomena. Part 1, entitled Molecular Diffusion, contains the following chapters: Preliminary Concepts; The Maxwell-Stefan Relations; Fick's Law; Estimation of Diffusion Coefficients; Solution of multicomponent Diffusion Problems: The Linearized Theory; and Solution of Multicomponent Diffusion Problems: Effective Diffusivity Methods. Part 2, entitled Interphase Transfer, contains the following chapters: Mass-Transfer Coefficients; Film Theory; Unsteady-State Mass-Transfer Models; Mass Transfer in Turbulent Flow; and Simultaneous Mass and Energy Transfer. Part 3, entitled Design, contains the following chapters: Multicomponent Distillation: Mass-Transfer Models; Multicomponent Distillation: Efficiency Models; Multicomponent Distillation: A Nonequilibrium Stage Model; and Condensation of Vapor Mixtures. Appendices are provided on matrix algebra, equation-solving and estimation of a thermodynamic derivative matrix. A computer diskette is provided with the book; the examples in Chapters 1--13 are solvable using this diskette and the commercial package Mathcad which the user must obtain. A separate software package, Chemsep, is needed for some of the exercises in Chapter 14.
Effects of mass transfer between Martian satellites on surface geology
NASA Astrophysics Data System (ADS)
Nayak, Michael; Nimmo, Francis; Udrea, Bogdan
2016-03-01
Impacts on planetary bodies can lead to both prompt secondary craters and projectiles that reimpact the target body or nearby companions after an extended period, producing so-called "sesquinary" craters. Here we examine sesquinary cratering on the moons of Mars. We model the impact that formed Voltaire, the largest crater on the surface of Deimos, and explore the orbital evolution of resulting high-velocity ejecta across 500 years using four-body physics and particle tracking. The bulk of mass transfer to Phobos occurs in the first 102 years after impact, while reaccretion of ejecta to Deimos is predicted to continue out to a 104 year timescale (cf. Soter, S. [1971]. Studies of the Terrestrial Planets. Cornell University). Relative orbital geometry between Phobos and Deimos plays a significant role; depending on the relative true longitude, mass transfer between the moons can change by a factor of five. Of the ejecta with a velocity range capable of reaching Phobos, 25-42% by mass reaccretes to Deimos and 12-21% impacts Phobos. Ejecta mass transferred to Mars is <10%. We find that the characteristic impact velocity of sesquinaries on Deimos is an order of magnitude smaller than those of background (heliocentric) hypervelocity impactors and will likely result in different crater morphologies. The time-averaged flux of Deimos material to Phobos can be as high as 11% of the background (heliocentric) direct-to-Phobos impactor flux. This relatively minor contribution suggests that spectrally red terrain on Phobos (Murchie, S., Erard, S. [1996]. Icarus 123, 63-86) is not caused by Deimos material. However the high-velocity ejecta mass reaccreted to Deimos from a Voltaire-sized impact is comparable to the expected background mass accumulated on Deimos between Voltaire-size events. Considering that the high-velocity ejecta contains only 0.5% of the total mass sent into orbit, sesquinary ejecta from a Voltaire-sized impact could feasibly resurface large parts of the Moon
Effect of electric fields on mass transfer to droplets. Final report
Carleson, T.E.; Budwig, R.
1994-02-01
During the six year funding period, the effects of a direct and alternating field upon single drop hydrodynamics and mass transfer were evaluated both experimentally and theoretically. Direct current field effects upon drop size, velocity and mass transfer rates were also observed for multiple drops formed in a three stage sieve tray column. Drop size, velocity, and mass transfer rates were measured experimentally and compared to simple models for direct current electric fields. Agreement between theory and experiment was found for drop charge, size, and velocity. Drop mass transfer coefficients were substantially larger than theoretical predictions while extraction efficiencies were moderately higher. Drop distortion and oscillation were observed and are thought to result in the experimentally observed higher values. For alternating current fields, drop flow streamlines and oscillations were measured and found to compare well with predictions from a solved mathematical model. In addition, equipment was constructed to determine mass transfer rates to oscillating drops. Concentration profiles in still and oscillating drops were measured and qualitatively compared to theoretical predictions.
Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes
Not Available
1990-08-22
While developing dry sorbent duct injection flue gas desulfurization processes may offer significant improvement in capital cost and process simplicity compared to wet scrubbing systems, the economics of this technology can be improved significantly by an improvement in sorbent utilization. While a general understanding of the mechanism by which the sorbents operate is known, a much more detailed knowledge of reaction rate-controlling phenomena, the role of inherent reactivity, and mass transfer effects and their interaction in needed. Objectives of this project are threefold: 1. Mass transfer investigation--determine the controlling physical and chemical processes that limit sorbent utilization. In particular, determine whether mass transfer is a controlling factor in in-duct flue gas desulfurization and establish the relative contributions of gas- and liquid-phase mass transfer and inherent sorbent reactivity. 2. Field test support--evaluate various sorbents, operating conditions and process schemes to support large-scale field testings at Meredosia and Beverly. 3. Mass transfer enhancement--examine various techniques that will enable sorbent utilization rates of at least 75 percent to be achieved. Sorbents investigated were Ca(OH){sub 2}, Mississippi hydrate and Mississippi slaked lime. Epsom Salt was investigated as an additive. Agglomeration of Ca(OH){sub 2} solids was also investigated. 3 refs., 92 figs., 23 tabs.
Wojtusik, Mateusz; Zurita, Mauricio; Villar, Juan C; Ladero, Miguel; Garcia-Ochoa, Felix
2016-09-01
The effect of fluid dynamic conditions on enzymatic hydrolysis of acid pretreated corn stover (PCS) has been assessed. Runs were performed in stirred tanks at several stirrer speed values, under typical conditions of temperature (50°C), pH (4.8) and solid charge (20% w/w). A complex mixture of cellulases, xylanases and mannanases was employed for PCS saccharification. At low stirring speeds (<150rpm), estimated mass transfer coefficients and rates, when compared to chemical hydrolysis rates, lead to results that clearly show low mass transfer rates, being this phenomenon the controlling step of the overall process rate. However, for stirrer speed from 300rpm upwards, the overall process rate is controlled by hydrolysis reactions. The ratio between mass transfer and overall chemical reaction rates changes with time depending on the conditions of each run. PMID:27233094
Dumitrescu, Ioana; Crooks, Richard M.
2012-01-01
Here we report on the effect of the mass transfer rate (kt) on the oxygen reduction reaction (ORR) catalyzed by Pt dendrimer-encapsulated nanoparticles (DENs) comprised of 147 and 55 atoms (Pt147 and Pt55). The experiments were carried out using a dual-electrode microelectrochemical device, which enables the study of the ORR under high kt conditions with simultaneous detection of H2O2. At low kt (0.02 to 0.12 cm s-1) the effective number of electrons involved in ORR, neff, is 3.7 for Pt147 and 3.4 for Pt55. As kt is increased, the mass-transfer-limited current for the ORR becomes significantly lower than the value predicted by the Levich equation for a 4-electron process regardless of catalyst size. However, the percentage of H2O2 detected remains constant, such that neff barely changes over the entire kt range explored (0.02 cm s-1). This suggests that mass transfer does not affect neff, which has implications for the mechanism of the ORR on Pt nanoparticles. Interestingly, there is a significant difference in neff for the two sizes of Pt DENs (neff = 3.7 and 3.5 for Pt147 and Pt55, respectively) that cannot be assigned to mass transfer effects and that we therefore attribute to a particle size effect. PMID:22665772
Leung, Juliana Y; Srinivasan, Sanjay
2016-09-01
Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It
NASA Astrophysics Data System (ADS)
Leung, Juliana Y.; Srinivasan, Sanjay
2016-09-01
Modeling transport process at large scale requires proper scale-up of subsurface heterogeneity and an understanding of its interaction with the underlying transport mechanisms. A technique based on volume averaging is applied to quantitatively assess the scaling characteristics of effective mass transfer coefficient in heterogeneous reservoir models. The effective mass transfer coefficient represents the combined contribution from diffusion and dispersion to the transport of non-reactive solute particles within a fluid phase. Although treatment of transport problems with the volume averaging technique has been published in the past, application to geological systems exhibiting realistic spatial variability remains a challenge. Previously, the authors developed a new procedure where results from a fine-scale numerical flow simulation reflecting the full physics of the transport process albeit over a sub-volume of the reservoir are integrated with the volume averaging technique to provide effective description of transport properties. The procedure is extended such that spatial averaging is performed at the local-heterogeneity scale. In this paper, the transport of a passive (non-reactive) solute is simulated on multiple reservoir models exhibiting different patterns of heterogeneities, and the scaling behavior of effective mass transfer coefficient (Keff) is examined and compared. One such set of models exhibit power-law (fractal) characteristics, and the variability of dispersion and Keff with scale is in good agreement with analytical expressions described in the literature. This work offers an insight into the impacts of heterogeneity on the scaling of effective transport parameters. A key finding is that spatial heterogeneity models with similar univariate and bivariate statistics may exhibit different scaling characteristics because of the influence of higher order statistics. More mixing is observed in the channelized models with higher-order continuity. It
Bai, Dongsheng; Zhang, Diwei; Zhang, Xianren; Chen, Guangjin
2015-01-01
Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our simulations suggest a coupling between the mass transfer resistance and heat transfer resistance as the driving mechanism for self-preservation effect. We found that the hydrate is initially melted from the interface, and then a solid-like water layer with temperature-dependent structures is formed next to the hydrate interface that exhibits fractal feature, followed by an increase of mass transfer resistance for the diffusion of methane from hydrate region. Furthermore, our results indicate that heat transfer resistance is a more fundamental factor, since it facilitates the formation of the solid-like layer and hence inhibits the further dissociation of the hydrates. The self-preservation effect is found to be enhanced with the increase of pressure and particularly the decrease of temperature. Kinetic equations based on heat balance calculations is also developed to describe the self-preservation effect, which reproduces our simulation results well and provides an association between microscopic and macroscopic properties. PMID:26423519
Bai, Dongsheng; Zhang, Diwei; Zhang, Xianren; Chen, Guangjin
2015-01-01
Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance. Our simulations suggest a coupling between the mass transfer resistance and heat transfer resistance as the driving mechanism for self-preservation effect. We found that the hydrate is initially melted from the interface, and then a solid-like water layer with temperature-dependent structures is formed next to the hydrate interface that exhibits fractal feature, followed by an increase of mass transfer resistance for the diffusion of methane from hydrate region. Furthermore, our results indicate that heat transfer resistance is a more fundamental factor, since it facilitates the formation of the solid-like layer and hence inhibits the further dissociation of the hydrates. The self-preservation effect is found to be enhanced with the increase of pressure and particularly the decrease of temperature. Kinetic equations based on heat balance calculations is also developed to describe the self-preservation effect, which reproduces our simulation results well and provides an association between microscopic and macroscopic properties. PMID:26423519
Ison, A P; Macrae, A R; Smith, C G; Bosley, J
1994-01-20
The use of solvent-free systems in the oil and fats industry is commonplace. Initial studies on interesterification were carried out in solvent systems because the lipase was immobilized solely by adsorption onto particles of diatomaceous earth. In this study, the mass transfer characteristics associated with the continuous interesterification of olive oil in a solvent-free system have been examined, for lipase immobilized on the three ion-exchange materials: Duolite ES562, Duolite ES568, and Spheroil DEA. The process of immobilization is influenced by the internal structure of the material and this in turn influences the interesterification activity of the catalyst. Individually prepared catalysts for the three support materials have shown that external mass transfer limitations are unlikely even at low flowrates.In the case of Spherosil DEA, with a mean pore diameter of 1480 A, the wide pores would be expected to reduce internal mass transfer limitations; however, it is more likely that the reduction in activity with increased catalyst loading is due to the lipase molecules being immobilized in a tightly packed monolayer. In such a situation, some active sites of the lipase molecules would become inaccessible to substrate molecules leading to an observed reduction in activity. For Duolite ES568, the observed results are very similar to those seen for Spherosil DEA, however, the pore structure of this support material indicate that some internal mass transfer limitations may also be occurring. Yet the contribution of the individual effects cannot be determined. The results observed for the support Duolite ES562 are different than those observed for the other materials and reflect the heterogeneity of Duolite ES562. The large proportion of narrow pores in the support mean that, for the catalysts examined, immobilization is most likely to have occurred in the external pores of the particles, and as such no internal mass transfer limitation is observed.It is clear
Effect of acoustic streaming on the mass transfer from a sublimating sphere
NASA Astrophysics Data System (ADS)
Kawahara, N.; Yarin, A. L.; Brenn, G.; Kastner, O.; Durst, F.
2000-04-01
The effect of the acoustic streaming on the mass transfer from the surface of a sphere positioned in an ultrasonic acoustic levitator is studied both experimentally and theoretically. Acoustic levitation using standing ultrasonic waves is an experimental tool for studying the heat and mass transfer from small solid or liquid samples, because it allows an almost steady positioning of a sample at a fixed location in space. However, the levitator introduces some difficulties. One of the main problems with acoustic levitation is that an acoustic streaming is induced near the sample surface, which affects the heat and mass transfer rates, as characterized by increased Nusselt and Sherwood numbers. The transfer rates are not uniform along the sample surface, and the aim of the present study is to quantify the spatial Sherwood number distribution over the surface of a sphere. The experiments are based on the measurement of the surface shape of a sphere layered with a solid substance as a function of time using a charge-coupled device (CCD) camera with backlighting. The sphere used in this research is a glass sphere layered with a volatile solid substance (naphthalene or camphor). The local mass transfer from the surface both with and without an ultrasonic acoustic field is investigated in order to evaluate the effect of the acoustic streaming. The experimental results are compared with predictions following from the theory outlined [A. L. Yarin, M. Pfaffenlehner, and C. Tropea, J. Fluid Mech. 356, 65 (1998); A. L. Yarin, G. Brenn, O. Kastner, D. Rensink, and C. Tropea, ibid. 399, 151 (1999)] which describes the acoustic field and the resulting acoustic streaming, and the mass transfer at the surface of particles and droplets located in an acoustic levitator. The results are also compared with the experimental data and with the theoretical predictions of Burdukov and Nakoryakov [J. Appl. Mech. Tech. Phys. 6, 51 (1965)], which are valid only in the case of spherical
The effects of recirculation flows on mass transfer from the arterial wall to flowing blood.
Zhang, Zhiguo; Deng, Xiaoyan; Fan, Yubo; Guidoin, Robert
2008-01-01
Using a sudden tubular expansion as a model of an arterial stenosis, the effect of disturbed flow on mass transfer from the arterial wall to flowing blood was studied theoretically and tested experimentally by measuring the dissolution rate of benzoic acid disks forming the outer tube of a sudden tubular expansion. The study revealed that mass transfer from vessel wall to flowing fluid in regions of disturbed flow is independent of wall shear rates. The rate of mass transfer is significantly higher in regions of disturbed flow with a local maximum around the reattachment point where the wall shear rate is zero. The experimental study also revealed that the rate of mass transfer from the vessel wall to a flowing fluid is much higher in the presence of microspheres (as models of blood cells) in the flowing fluid and under the condition of pulsatile flow than in steady flow. These results imply that flow disturbance may enhance the transport of biochemicals and macromolecules, such as plasma proteins and lipoproteins synthesized within the blood vessel wall, from the blood vessel wall to flowing blood. PMID:18204314
Analysis of Effect of Gas-Liquid Interfacial Disturbance on Mass Transfer Performance
NASA Astrophysics Data System (ADS)
Wu, Honda; Chung, Tsair-Wang
In order to study the mass transfer phenomena for water vapor absorbed by triethylene glycol (TEG) solution and to elucidate effect of interfacial disturbance on absorption performance, the interfacial phenomena for water drop instilling on the surface of TEG solution and mass transfer process were observed and operated in this study. Besides liquid and gas flow rates, the interfacial disturbance can also affect the mass transfer performance in the absorption system with continuous liquid phase, and the advanced mass transfer phenomena must be discussed from the interface of matter. Therefore, the surface tensions of desiccant solutions were measured to analyze the disturbed phenomena of water drop instilling on the surface of TEG solution. Since the Marangoni-Index (MI) means the maximum surface tension difference on the surface of liquid layer, the values of MI were calculated and compared with the mass transfer performance of packed-bed absorber. Generally speaking, the interfacial disturbance, resulted from the surface tension difference, would promote the contacting area of gas and liquid phases. The observation of water drop instilling on surface of TEG solution found that the interfacial disturbance existed between water drop and TEG solution, and the interfacial instability was found in the peripheral region of the water drop. On the other hand, the values of MI were increased by the increased TEG concentrations, and it can be deduced that the surface tension effect should be significant in the higher concentration of TEG solution and the interfacial disturbance would be heavier above 95 wt.% TEG solutions. Finally, the absorption performance for 95 and 96 wt.% TEG solutions were much larger than that of 90 and 88.6 wt.% TEG solutions in the operation of packed-bed absorber.
Effect of radiator position and mass flux on the dryer room heat transfer rate
NASA Astrophysics Data System (ADS)
Mirmanto, M.; Sulistyowati, E. D.; Okariawan, I. D. K.
A room radiator as usually used in cold countries, is actually able to be used as a heat source to dry goods, especially in the rainy season where the sun seldom shines due to much rain and cloud. Experiments to investigate effects of radiator position and mass flux on heat transfer rate were performed. This study is to determine the best position of the radiator and the optimum mass flux. The radiator used was a finned radiator made of copper pipes and aluminum fins with an overall dimension of 220 mm × 50 mm × 310 mm. The prototype room was constructed using plywood and wood frame with an overall size of 1000 mm × 1000 mm × 1000 mm. The working fluid was heated water flowing inside the radiator and air circulating naturally inside the prototype room. The nominal mass fluxes employed were 800, 900 and 1000 kg/m2 s. The water was kept at 80 °C at the radiator entrance, while the initial air temperature inside the prototype room was 30 °C. Three positions of the radiator were examined. The results show that the effect of the mass flux on the forced and free convection heat transfer rate is insignificant but the radiator position strongly affects the heat transfer rate for both forced and free convection.
NASA Astrophysics Data System (ADS)
Khan, Ilyas; Ali, Farhad; Shafie, Sharidan; Mustapha, Norzieha
2011-06-01
The combined effects of Hall current and mass transfer on the unsteady magnetohydrodynamic (MHD) flow of a viscous fluid passing through a porous channel have been investigated. The flow in the fluid has been induced due to external pressure gradient. The closed form analytical solutions have been obtained for the velocity, temperature and concentration fields. The analytical expressions for non-dimensional Skin-friction, Nusselt number and Sherwood number have been computed. The influence of various embedded flow parameters have been analyzed through graphs. The solutions obtained show that the influence of Hall parameter and mass transfer phenomenon give some interesting results. It is found that the Hall parameter have an increasing effect on the fluid velocity and approaches to the steady state as the time parameter is increased. The fluid concentration is increased for larger values of Peclet and Schmidt numbers whereas decreased with increase in Soret number and time parameter.
Dumitrescu, Ioana; Crooks, Richard M
2012-07-17
Here we report on the effect of the mass transfer rate (k(t)) on the oxygen reduction reaction (ORR) catalyzed by Pt dendrimer-encapsulated nanoparticles (DENs) comprised of 147 and 55 atoms (Pt(147) and Pt(55)). The experiments were carried out using a dual-electrode microelectrochemical device, which enables the study of the ORR under high k(t) conditions with simultaneous detection of H(2)O(2). At low k(t) (0.02 to 0.12 cm s(-1)) the effective number of electrons involved in ORR, n(eff), is 3.7 for Pt(147) and 3.4 for Pt(55). As k(t) is increased, the mass-transfer-limited current for the ORR becomes significantly lower than the value predicted by the Levich equation for a 4-electron process regardless of catalyst size. However, the percentage of H(2)O(2) detected remains constant, such that n(eff) barely changes over the entire k(t) range explored (0.02 cm s(-1)). This suggests that mass transfer does not affect n(eff), which has implications for the mechanism of the ORR on Pt nanoparticles. Interestingly, there is a significant difference in n(eff) for the two sizes of Pt DENs (n(eff) = 3.7 and 3.5 for Pt(147) and Pt(55), respectively) that cannot be assigned to mass transfer effects and that we therefore attribute to a particle size effect. PMID:22665772
Mass transfer from a circular cylinder: Effects of flow unsteadiness and slight nonuniformities
NASA Technical Reports Server (NTRS)
Marziale, M. L.; Mayle, R. E.
1984-01-01
Experiments were performed to determine the effect of periodic variations in the angle of the flow incident to a turbine blade on its leading edge heat load. To model this situation, measurements were made on a circular cylinder oscillating rotationally in a uniform steady flow. A naphthalene mass transfer technique was developed and used in the experiments and heat transfer rates are inferred from the results. The investigation consisted of two parts. In the first, a stationary cylinder was used and the transfer rate was measured for Re = 75,000 to 110,000 and turbulence levels from .34 percent to 4.9 percent. Comparisons with both theory and the results of others demonstrate that the accuracy and repeatability of the developed mass transfer technique is about + or - 2 percent, a large improvement over similar methods. In the second part identical flow conditions were used but the cylinder was oscillated. A Strouhal number range from .0071 to .1406 was covered. Comparisons of the unsteady and steady results indicate that the magnitude of the effect of oscillation is small and dependent on the incident turbulence conditions.
Soret and dufour effects on MHD mixed convection heat and mass transfer in a micropolar fluid
NASA Astrophysics Data System (ADS)
Srinivasacharya, Darbhasayanam; Upendar, Mendu
2013-12-01
This paper analyzes the flow, heat and mass transfer characteristics of the mixed convection on a vertical plate in a micropolar fluid in the presence of Soret and Dufour effects. A uniform magnetic field of magnitude is applied normal to the plate. The governing nonlinear partial differential equations are transformed into a system of coupled nonlinear ordinary differential equations using similarity transformations and then solved numerically using the Keller-box method. The numerical results are compared and found to be in good agreement with previously published results as special cases of the present investigation. The rate of heat and mass transfer at the plate are presented graphically for various values of coupling number, magnetic parameter, Prandtl number, Schmidt number, Dufour and Soret numbers. In addition, the skin-friction coefficient, the wall couple stress are shown in a tabular form.
Geochemical Speciation Mass Transfer
1985-12-01
PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineral phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.
Geochemical Speciation Mass Transfer
Energy Science and Technology Software Center (ESTSC)
1985-12-01
PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineralmore » phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.« less
Mass Transfer with Chemical Reaction.
ERIC Educational Resources Information Center
DeCoursey, W. J.
1987-01-01
Describes the organization of a graduate course dealing with mass transfer, particularly as it relates to chemical reactions. Discusses the course outline, including mathematics models of mass transfer, enhancement of mass transfer rates by homogeneous chemical reaction, and gas-liquid systems with chemical reaction. (TW)
Barton, J.W.; Zhang, X.S.; Klasson, K.T.; Davison, B.H.
1998-03-01
Mathematical models of varying complexity have been proposed in the open literature for describing uptake of volatile organics in trickling bed biofilters. Many simpler descriptions yield relatively accurate solutions, but are limited as predictive tools by numerous assumptions which decrease the utility of the model. Trickle bed operation on the boundary between mass transfer and kinetic limitation regimes serves as one example in which these models may be insufficient. One-dimensional models may also fail to consider important effects/relationships in multiple directions, limiting their usefulness. This paper discusses the use of a predictive, two-dimensional mathematical model to describe microbial uptake, diffusion through a biofilm, and mass transfer of VOCs from gas to liquid. The model is validated by experimental data collected from operating trickle-bed bioreactors designed for removing sparingly soluble gaseous contaminants. Axial and radial (biofilm) concentration profiles are presented, along with validation results. Operation in regimes in which both mass transfer and kinetic factors play significant roles are discussed, along with predictive modeling implications.
Effects of Rate-Limited Mass Transfer on Modeling Vapor Intrusion with Aerobic Biodegradation.
Chen, Yiming; Hou, Deyi; Lu, Chunhui; Spain, Jim C; Luo, Jian
2016-09-01
Most of the models for simulating vapor intrusion accept the local equilibrium assumption for multiphase concentration distributions, that is, concentrations in solid, liquid and vapor phases are in equilibrium. For simulating vapor transport with aerobic biodegradation controlled by counter-diffusion processes, the local equilibrium assumption combined with dual-Monod kinetics and biomass decay may yield near-instantaneous behavior at steady state. The present research investigates how predicted concentration profiles and fluxes change as interphase mass transfer resistances are increased for vapor intrusion with aerobic biodegradation. Our modeling results indicate that the attenuation coefficients for cases with and without mass transfer limitations can be significantly different by orders of magnitude. Rate-limited mass transfer may lead to larger overlaps of contaminant vapor and oxygen concentrations, which cannot be simulated by instantaneous reaction models with local equilibrium mass transfer. In addition, the contaminant flux with rate-limited mass transfer is much smaller than that with local equilibrium mass transfer, indicating that local equilibrium mass transfer assumption may significantly overestimate the biodegradation rate and capacity for mitigating vapor intrusion through the unsaturated zone. Our results indicate a strong research need for field tests to examine the validity of local equilibrium mass transfer, a widely accepted assumption in modeling vapor intrusion. PMID:27486832
Investigation on the effective mass of Ge1-xSnx alloys and the transferred-electron effect
NASA Astrophysics Data System (ADS)
Liu, Lei; Liang, Renrong; Wang, Jing; Xu, Jun
2015-03-01
The electron band structures of Ge1-xSnx alloys were calculated using the nonlocal empirical pseudopotential method. The electron and hole effective masses were extracted, and the mobility enhancement over Ge was comprehensively analyzed. For the direct gap Ge1-xSnx with high Sn compositions, only a small fraction of electrons occupy the Γ valley with high mobility at room temperature. Hence, the negative differential mobility resulting from the transferred-electron effect may not be observed, and the electron mobility enhancement over Ge is only two-fold. Low temperature conditions may lead to the transferred-electron effect and a significantly enhanced electron mobility.
NASA Astrophysics Data System (ADS)
Zhang, Qi; Gui, Keting; Wang, Xiaobo
2016-02-01
The effects of magnetic fields on improving the mass transfer in flue gas desulfurization using a fluidized bed are investigated in the paper. In this research, the magnetically fluidized bed (MFB) is used as the reactor in which ferromagnetic particles are fluidized with simulated flue gas under the influence of an external magnetic field. Lime slurry is continuously sprayed into the reactor. As a consequence, the desulfurization reaction and the slurry drying process take place simultaneously in the MFB. In this paper, the effects of ferromagnetic particles and external magnetic fields on the desulphurization efficiency are studied and compared with that of quartz particles as the fluidized particles. Experimental results show that the ferromagnetic particles not only act as a platform for lime slurry to precipitate on like quartz particles, but also take part in the desulfurization reaction. The results also show that the specific surface area of ferromagnetic particles after reaction is enlarged as the magnetic intensity increases, and the external magnetic field promotes the oxidation of S(IV), improving the mass transfer between sulphur and its sorbent. Hence, the efficiency of desulphurization under the effects of external magnetic fields is higher than that in general fluidized beds.
Leith, S.D.; Reddy, M.M.; Irez, W.F.; Heymans, M.J.
1996-01-01
The pore structure of Salem limestone is investigated, and conclusions regarding the effect of the pore geometry on modeling moisture and contaminant transport are discussed based on thin section petrography, scanning electron microscopy, mercury intrusion porosimetry, and nitrogen adsorption analyses. These investigations are compared to and shown to compliment permeability and capillary pressure measurements for this common building stone. Salem limestone exhibits a bimodal pore size distribution in which the larger pores provide routes for convective mass transfer of contaminants into the material and the smaller pores lead to high surface area adsorption and reaction sites. Relative permeability and capillary pressure measurements of the air/water system indicate that Salem limestone exhibits high capillarity end low effective permeability to water. Based on stone characterization, aqueous diffusion and convection are believed to be the primary transport mechanisms for pollutants in this stone. The extent of contaminant accumulation in the stone depends on the mechanism of partitioning between the aqueous and solid phases. The described characterization techniques and modeling approach can be applied to many systems of interest such as acidic damage to limestone, mass transfer of contaminants in concrete and other porous building materials, and modeling pollutant transport in subsurface moisture zones.
NASA Astrophysics Data System (ADS)
Cvetkovic, Vladimir; Fiori, Aldo; Dagan, Gedeon
2016-04-01
The driving mechanism of contaminant transport in aquifers is groundwater flow, which is controlled by boundary conditions and heterogeneity of hydraulic properties. In this work we show how hydrodynamics and mass transfer can be combined in a general analytical manner to derive a physically-based (or process-based) residence time distribution for a given integral scale of the hydraulic conductivity; the result can be applied for a broad class of linear mass transfer processes. The derived tracer residence time distribution is a transfer function with parameters to be inferred from combined field and laboratory measurements. It is scalable relative to the correlation length and applicable for an arbitrary statistical distribution of the hydraulic conductivity. Based on the derived residence time distribution, the coefficient of variation and skewness of contaminant residence time are illustrated assuming a log-normal hydraulic conductivity distribution and first-order mass transfer. We show that for a low Damkohler number the coefficient of variation is more strongly influenced by mass transfer than by heterogeneity, whereas skewness is more strongly influenced by heterogeneity. The derived physically-based residence time distribution for solute transport in heterogeneous aquifers is particularly useful for studying natural attenuation of contaminants. We illustrate the relative impacts of high heterogeneity and a generalised (non-Fickian) multi-rate mass transfer on natural attenuation defined as contaminant mass loss from injection to a downstream compliance boundary.
Mass transfer effect of the stalk contraction-relaxation cycle of Vorticella convallaria
NASA Astrophysics Data System (ADS)
Zhou, Jiazhong; Admiraal, David; Ryu, Sangjin
2014-11-01
Vorticella convallaria is a genus of protozoa living in freshwater. Its stalk contracts and coil pulling the cell body towards the substrate at a remarkable speed, and then relaxes to its extended state much more slowly than the contraction. However, the reason for Vorticella's stalk contraction is still unknown. It is presumed that water flow induced by the stalk contraction-relaxation cycle may augment mass transfer near the substrate. We investigated this hypothesis using an experimental model with particle tracking velocimetry and a computational fluid dynamics model. In both approaches, Vorticella was modeled as a solid sphere translating perpendicular to a solid surface in water. After having been validated by the experimental model and verified by grid convergence index test, the computational model simulated water flow during the cycle based on the measured time course of stalk length changes of Vorticella. Based on the simulated flow field, we calculated trajectories of particles near the model Vorticella, and then evaluated the mass transfer effect of Vorticella's stalk contraction based on the particles' motion. We acknowlege support from Laymann Seed Grant of the University of Nebraska-Lincoln.
Effect of NAPL Source Morphology on Mass Transfer in the Vadose Zone.
Petri, Benjamin G; Fučík, Radek; Illangasekare, Tissa H; Smits, Kathleen M; Christ, John A; Sakaki, Toshihiro; Sauck, Carolyn C
2015-01-01
The generation of vapor-phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non-aqueous-phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two-dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water-wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water-saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective-dispersive-diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed. PMID:25535651
Effect of impeller geometry on gas-liquid mass transfer coefficients in filamentous suspensions.
Dronawat, S N; Svihla, C K; Hanley, T R
1997-01-01
Volumetric gas-liquid mass transfer coefficients were measured in suspensions of cellulose fibers with concentrations ranging from 0 to 20 g/L. The mass transfer coefficients were measured using the dynamic method. Results are presented for three different combinations of impellers at a variety of gassing rates and agitation speeds. Rheological properties of the cellulose fibers were also measured using the impeller viscometer method. Tests were conducted in a 20 L stirred-tank fermentor and in 65 L tank with a height to diameter ratio of 3:1. Power consumption was measured in both vessels. At low agitation rates, two Rushton turbines gave 20% better performance than the Rushton and hydrofoil combination and 40% better performance than the Rushton and propeller combination for oxygen transfer. At higher agitation rates, the Rushton and hydrofoil combination gave 14 and 25% better performance for oxygen transfer than two Rushton turbines and the Rushton and hydrofoil combination, respectively. PMID:18576095
NASA Astrophysics Data System (ADS)
Davidson, Stuart
2010-08-01
This paper reports work undertaken to assess the change in the mass values of stainless steel and platinum-iridium weights transferred between air and vacuum and to determine the repeatability of this change. Sets of kilogram transfer standards, manufactured from stainless steel and platinum-iridium and with different surface areas, were used to determine the effect of transfer between air and vacuum on the values of the mass standards. The SI unit of mass is the only unit of the seven base SI quantities which is still defined in terms of an artefact rather than by relation to a fundamental physical constant. Work is underway to identify a means of deriving the SI unit of mass from fundamental constants and at present the two principal approaches are the International Avogadro Coordination and the watt balance projects. Both of these approaches involve realizing a kilogram in vacuum and therefore the traceability from a kilogram realized in vacuum to mass standards in air is crucial to the effective dissemination of the mass scale. The work reported here characterizes the changes in mass values of standards on transfer between air and vacuum and thus will enable traceability to be established for an in-air mass scale based on a definition of the unit in vacuum.
Effect of laminar and turbulent fluid flow on mass transfer in some electrochemical systems
NASA Astrophysics Data System (ADS)
Chen, Qian
2000-10-01
The influence of fluid flow on electrode-shape change that results from electrodeposition in the presence of a model leveling agent is simulated and discussed. The treatment is more rigorous than past studies in that flow and concentration fields are recalculated as the electrode shape changes. It is shown that uncertainties due to approximate treatments of fluid flow may be as significant as existing discrepancies between experiment and theory. The mass transfer characteristics of a turbulent slot jet impinging normally on a target wall are examined using numerical simulations. Fluid flow is modeled using the k-turbulence model of Wilcox [1]. The computations are validated against existing experimental fluid flow, heat transfer and mass transfer data. The range of Reynolds numbers examined is from 450 to 20,000 with Prandtl or Schmidt numbers from 1 to 2,400. The distance of the target plate from the slot jet varies between 2 to 8 times the slot jet width. The study reveals computational aspects that are unique to the solution of flow and mass transfer problems with the combination of high Schmidt numbers and turbulent flows. A low order "coherent structure" near-wall flow model first proposed by Chapman and Kuhn [2] is used to obtain the near-wall fluid flow field. This flow field is then used to compute high Schmidt number mass transfer for a turbulent boundary layer flow. It is shown that useful insight can be obtained into high Schmidt number mass transfer for a turbulent fluid flow using this model. The boundary conditions for this near-wall field for more complicated flow or geometries may be obtained either from experimental turbulent velocity and frequency data or from a k-o type of turbulence model.
Light-Time Effect and Mass Transfer in the Triple Star SW Lyncis
NASA Astrophysics Data System (ADS)
Kim, Chun-Hwey
1999-06-01
In this paper all the photoelectric times of minimum for the triple star SW Lyn have been analyzed in terms of light-time e ect due to the third-body and secular period decreases induced by mass transfer process. The light-time orbit determined recently by Ogloza et al.(1998) were modi ed and improved. And it is found that the orbital period of SW Lyn have been decreasing secularly. The third-body revolves around the mass center of triple stars every 5y.77 in a highly eccentric elliptical orbit(e=0.61). The third-body with a minimum mass of 1.13M may be a binary or a white dwarf. The rate of secular period-decrease were obtained as ¡âP/P = -12.45 x 10-11, implying the mass-transfer from the massive primary star to the secondary. The mass losing rate from the primary were calculated as about 1.24 x 10-8M /y. It is noticed that the mass-transfer in SW Lyn system is opposite in direction to that deduced from it's Roche geometry by previous investigators.
NASA Astrophysics Data System (ADS)
Ogorzalek Loo, Rachel R.; Mitchell, Charles; Stevenson, Tracy I.; Loo, Joseph A.; Andrews, Philip C.
1997-12-01
Diffusive transfer was examined as a blotting method to transfer proteins from polyacrylamide gels to membranes for ultraviolet matrix-assisted laser desorption ionization (MALDI) mass spectrometry. The method is well-suited for transfers from isoelectric focusing (IEF) gels. Spectra have been obtained for 11 pmol of 66 kDa albumin loaded onto an IEF gel and subsequently blotted to polyethylene. Similarly, masses of intact carbonic anhydrase and hemoglobin were obtained from 14 and 20 pmol loadings. This methodology is also compatible with blotting high molecular weight proteins, as seen for 6 pmol of the 150 kDa monoclonal antibody anti-[beta]-galactosidase transferred to Goretex. Polypropylene, Teflon, Nafion and polyvinylidene difluoride (PVDF) also produced good spectra following diffusive transfer. Only analysis from PVDF required that the membrane be kept wet prior to application of matrix. Considerations in mass accuracy for analysis from large-area membranes with continuous extraction and delayed extraction were explored, as were remedies for surface charging. Vapor phase CNBr cleavage was applied to membrane-bound samples for peptide mapping.
Demonstrating the Effect of Interphase Mass Transfer in a Transparent Fluidized Bed Reactor
ERIC Educational Resources Information Center
Saayman, Jean; Nicol, Willie
2011-01-01
A demonstration experiment is described that employs the ozone decomposition reaction at ambient conditions on Fe2O3 impregnated Fluidized Catalytic Cracking (FCC) catalyst. Using a two-dimensional see-through column the importance of interphase mass transfer is clearly illustrated by the significant difference in ozone conversion between the…
Effect of laminar unsteady fluid flows on mass transfer in electrochemical systems
NASA Astrophysics Data System (ADS)
Shehata, Ahmed Kamal
1999-11-01
A numerical study of mass transfer in steady as well as unsteady two-dimensional laminar channel flows is investigated. When a circular cylinder is suspended in a steady flow stream, the flow becomes unsteady and oscillates periodically for Reynolds numbers, Re, between 200 and 800 (where Re is based on the channel height) due to the formation of the Karman vortex street. This well- characterized unsteady periodic flow is utilized to study mass transfer rates at different positions downstream of the blocking cylinder. The study consisted of mass transfer to a channel wall and mass transfer to the bottom surface of rectangular cavities, of different depth/width ratios. All investigated positions, including cavity position, are located downstream of the blocking cylinder. The study also included the mass transfer to a channel wall in a steady fully-developed flow when a hemi-cylindrical bump is located at the lower wall. The results of the numerical simulations are then compared to the experimental data. The numerical and experimental results are found to be generally in good agreement. Structured multi-block grids are utilized for the fluid flow simulations. It is shown that grids can be created differently with different block topologies. Solution accuracy is shown to be strongly affected by the shape as well as the densities of the resulting grids. The finite element method is used to simulate the fluid flow while for the concentration field a procedure based on the finite volume method is used. The strength of the flow at the cavity mouth was found to scale linearly with wall shear in the absence of the cavity for steady channel flow. The flow at the cavity mouth was also found to be independent of the cavity depth for both steady and unsteady flows. Based on these observations it is possible to predict cavity flows and cavity mass transfer without computing the flow in the entire channel plus cavity domain when studying different cavity aspect ratios. A
NASA Astrophysics Data System (ADS)
Veera Krishna, M.; Swarnalathamma, B. V.
2016-05-01
In this paper, we discussed the peristaltic MHD flow of an incompressible and electrically conducting Williamson fluid in a symmetric planar channel with heat and mass transfer under the effect of inclined magnetic field. Viscous dissipation and Joule heating are also taken into consideration. Mathematical model is presented by using the long wavelength and low Reynolds number approximations. The differential equations governing the flow are highly nonlinear and thus perturbation solution for small Weissenberg number (We < 1) is presented. Effects of the heat and mass transfer on the longitudinal velocity, temperature and concentration are studied in detail. Main observations are presented in the concluding section. The streamlines pattern is also given due attention.
Effect of protein molecular weight on the mass transfer in protein mixing
NASA Astrophysics Data System (ADS)
Asad, Ahmed; Chai, Chuan; Wu, JiangTao
2012-03-01
The mixing of protein solutions with that of precipitating agents is very important in protein crystallization experiments. In this work, the interferometry images were recorded during the mixing of two proteins with different molecular weights: lysozyme of ˜14.6 kDa, trypsin of ˜23.3 kDa and pepsin of ˜34.8 kDa were placed in a Mach-Zehnder interferometer. The protein molecular weight dependence on the competition of the transport process and kinetics at the interface was studied. The concentration profiles of protein solutions were calculated to analyze the mass transfer during the mixing process. It was observed that the mass transfer process is more efficient during the mixing of proteins with higher molecular weights. In addition, the more rapid concentration changes above the interface suggest that convection may dominate the diffusion. The phenomenon of convection is higher in the protein solutions with higher molecular weight.
Evaluation of the mass transfer effect of the stalk contraction cycle of Vorticella
NASA Astrophysics Data System (ADS)
Zhou, Jiazhong; Admiraal, David; Ryu, Sangjin
2014-03-01
Vorticella is a protozoan with a contractile stalk that can contract pulling the cell body toward the substrate in less than 10 ms and return to the extended state in a few seconds. Although this stalk contraction is one of the fastest cellular motions, it is unknown why Vorticella contracts. Because the flow field induced by Vorticella shows different characteristics between contraction and relaxation, it has been suggested that Vorticella augments mass transfer near the substrate based on its stalk contraction-relaxation. We investigate this hypothesis using computational fluid dynamics (CFD) simulations and particle image velocimetry (PIV) experiments. In both approaches, Vorticella is modelled as a solid sphere that translates perpendicular to a solid surface in liquid based on the measured stalk length changes of Vorticella. Based on the computationally and experimentally simulated flow, we evaluate the mass transfer capability of Vorticella, for a possible application of the stalk contraction of Vorticella as a biomimetic model system for microfluidic mixers.
Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes
Jozewicz, W. . Environmental Systems Div.); Rochelle, G.T. . Dept. of Chemical Engineering)
1992-01-29
Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide (Ca(OH){sub 2}) slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)
Yao, Kangning; Chi, Yong; Wang, Fei; Yan, Jianhua; Ni, Mingjiang; Cen, Kefa
2016-01-01
A commonly used aeration device at present has the disadvantages of low mass transfer rate because the generated bubbles are several millimeters in diameter which are much bigger than microbubbles. Therefore, the effect of a microbubble on gas-liquid mass transfer and wastewater treatment process was investigated. To evaluate the effect of each bubble type, the volumetric mass transfer coefficients for microbubbles and conventional bubbles were determined. The volumetric mass transfer coefficient was 0.02905 s(-1) and 0.02191 s(-1) at a gas flow rate of 0.67 L min(-1) in tap water for microbubbles and conventional bubbles, respectively. The degradation rate of simulated municipal wastewater was also investigated, using aerobic activated sludge and ozone. Compared with the conventional bubble generator, the chemical oxygen demand (COD) removal rate was 2.04, 5.9, 3.26 times higher than those of the conventional bubble contactor at the same initial COD concentration of COD 200 mg L(-1), 400 mg L(-1), and 600 mg L(-1), while aerobic activated sludge was used. For the ozonation process, the rate of COD removal using microbubble generator was 2.38, 2.51, 2.89 times of those of the conventional bubble generator. Based on the results, the effect of initial COD concentration on the specific COD degradation rate were discussed in different systems. Thus, the results revealed that microbubbles could enhance mass transfer in wastewater treatment and be an effective method to improve the degradation of wastewater. PMID:27120652
Effects of microscale inertia on heat or mass transfer from a drop
NASA Astrophysics Data System (ADS)
Krishnamurthy, Deepak; Subramanian, Ganesh
2012-11-01
Heat or mass transport from suspensions of solid particles or drops is ubiquitous in many industrial processes. In the zero inertia limit the transport is diffusion limited owing to the presence of closed streamlines around each particle. A small but finite amount of inertia though, results in a vastly different picture, greatly enhancing transport by destroying the closed streamline configuration. We develop a theoretical formulation to study the effects of weak inertia on transport from a density-matched drop in a 2D linear flow. It is shown that, unlike a solid particle, the near-surface streamlines are closed only when the viscosity ratio (λ) exceeds a critical value λc = 2 α / (1- α) , where α is the linear flow parameter measuring relative magnitudes of extension and vorticity. The velocity field on the drop surface can be characterized using a complex-valued analogue of the (C, τ) coordinate system used to describe Jeffrey orbits of an axisymmetric particle. In the open-streamline case (λ < λ c) , convective transport occurs even with zero inertia, and for large Peclet number (Pe) (the relative magnitude of convective to diffusive transport), the Nusselt number (dimensionless rate of heat transfer) is expected to scale as F(α, λ) Pe1/2 and is determined via a boundary layer analysis in the (C, τ) coordinate system. In the closed streamline case (λ > λ c) , similar to the solid particle, inertia plays a crucial role, and the Nusselt number must scale as G(α, λ)Re1/2Pe1/2. A methodology is developed to analyze the convection along spiraling streamlines using a physically motivated choice of coordinate system on the drop surface.
Gas mass transfer for stratified flows
Duffey, R.B.; Hughes, E.D.
1995-07-01
We analyzed gas absorption and release in water bodies using existing surface renewal theory. We show a new relation between turbulent momentum and mass transfer from gas to water, including the effects of waves and wave roughness, by evaluating the equilibrum integral turbulent dissipation due to energy transfer to the water from the wind. Using Kolmogoroff turbulence arguments the gas transfer velocity, or mass transfer coefficient, is then naturally and straightforwardly obtained as a non-linear function of the wind speed drag coefficient and the square root of the molecular diffusion coefficient. In dimensionless form, the theory predicts the turbulent Sherwood number to be Sh{sub t} = (2/{radical}{pi}) Sc{sup 1/2}, where Sh{sub t} is based on an integral dissipation length scale in the air. The theory confirms the observed nonlinear variation of the mass transfer coefficient as a function of the wind speed; gives the correct transition with turbulence-centered models for smooth surfaces at low speeds; and predicts experimental data from both laboratory and environmental measurements within the data scatter. The differences between the available laboratory and field data measurements are due to the large differences in the drag coefficient between wind tunnels and oceans. The results also imply that the effect of direct aeration due to bubble entrainment at wave breaking is no more than a 20% increase in the mass transfer for the highest speeds. The theory has importance to mass transfer in both the geophysical and chemical engineering literature.
Gas mass transfer for stratified flows
Duffey, R.B.; Hughes, E.D.
1995-06-01
We analyzed gas absorption and release in water bodies using existing surface renewal theory. We show a new relation between turbulent momentum and mass transfer from gas to water, including the effects of waves and wave roughness, by evaluating the equilibrium integral turbulent dissipation due to energy transfer to the water from the wind. Using Kolmogoroff turbulence arguments the gas transfer velocity, or mass transfer coefficient, is then naturally and straightforwardly obtained as a non-linear function of the wind speed drag coefficient and the square root of the molecular diffusion coefficient. In dimensionless form, the theory predicts the turbulent Sherwood number to be Sh{sub t} = (2/{radical}{pi})Sc{sup 1/2}, where Sh{sub t} is based on an integral dissipation length scale in the air. The theory confirms the observed nonlinear variation of the mass transfer coefficient as a function of the wind speed; gives the correct transition with turbulence-centered models for smooth surfaces at low speeds; and predicts experimental data from both laboratory and environmental measurements within the data scatter. The differences between the available laboratory and field data measurements are due to the large differences in the drag coefficient between wind tunnels and oceans. The results also imply that the effect of direct aeration due to bubble entrainment at wave breaking is no more than a 20% increase in the mass transfer for the highest speeds. The theory has importance to mass transfer in both the geo-physical and chemical engineering literature.
Goldstein, R.J.; Cho, H.H.; Jabbari, M.Y.
1997-10-01
Convective heat/mass transfer near and within the entrance region of film cooling holes supplied with air from an internal duct (plenum) behind the cooling holes has been measured using a naphthalene sublimation technique. The experiments are conducted for duct Reynolds number, based on the duct inlet flow condition, of 1,800 to 13,500, which results in a range of hole Reynolds numbers of 8000 to 30,000, close to actual engine operating conditions. The flow entering the hole can be considered a combination of flow along a 90 deg tube bend and a sudden contraction duct flow. The flow separates at the inner corner and a secondary flow is induced by the centrifugal force associated with the streamline curvature. The mass transfer coefficient for the duct wall (surface of film-cooled plate) with a cooling hole is three to five times higher than for a fully developed duct flow. With a smaller duct, the overall transfer coefficient on the hole entrance surface increases due to the higher duct Reynolds numbers, but the flow has less secondary flow effects within the smaller space. Generally, transfer coefficients on the hole entrance surface are largely unaffected by the duct end presence, but the transfer coefficient is larger downstream for a short distance from the center of the last hole to the duct end. In tests with multiple film cooling holes, the flow at the first hole is more of a curved duct flow (strong secondary flow) and the flow at the last hole is more of a sink-like flow. At the middle hole, the flow is a combination of both flows. The mass transfer rates on the inner hole surfaces are found to be the same for holes with corresponding positions relative to the duct end, although the total number of open holes is different.
Njau, K N; Gastory, L; Eshton, B; Katima, J H Y; Minja, R J A; Kimwaga, R; Shaaban, M
2011-01-01
The effect of mass transfer on the removal rate constants of BOD5, NH3, NO3 and TKN has been investigated in a Horizontal Subsurface Flow Constructed Wetland (HSSFCW) planted with Phragmites mauritianus. The plug flow model was assumed and the inlet and outlet concentrations were used to determine the observed removal rate constants. Mass transfer effects were studied by assessing the influence of interstitial velocity on pollutant removal rates in CW cells of different widths. The flow velocities varied between 3-46 m/d. Results indicate that the observed removal rate constants are highly influenced by the flow velocity. Correlation of dimensionless groups namely Reynolds Number (Re), Sherwood Number (Sh) and Schmidt Number (Sc) were applied and log-log plots of rate constants against velocity yielded straight lines with values beta = 0.87 for BOD5, 1.88 for NH3, 1.20 for NO3 and 0.94 for TKN. The correlation matched the expected for packed beds although the constant beta was higher than expected for low Reynolds numbers. These results indicate that the design values of rate constants used to size wetlands are influenced by flow velocity. This paper suggests the incorporation of mass transfer into CW design procedures in order to improve the performance of CW systems and reduce land requirements. PMID:22049736
Rehman, Fahad; Medley, Gareth J D; Bandulasena, Hemaka; Zimmerman, William B J
2015-02-01
Aeration is one of the most energy intensive processes in the waste water treatment plants and any improvement in it is likely to enhance the overall efficiency of the overall process. In the current study, a fluidic oscillator has been used to produce microbubbles in the order of 100 μm in diameter by oscillating the inlet gas stream to a pair of membrane diffusers. Volumetric mass transfer coefficient was measured for steady state flow and oscillatory flow in the range of 40-100l/min. The highest improvement of 55% was observed at the flow rates of 60, 90 and 100l/min respectively. Standard oxygen transfer rate and efficiency were also calculated. Both standard oxygen transfer rate and efficiency were found to be considerably higher under oscillatory air flow conditions compared to steady state airflow. The bubble size distributions and bubble densities were measured using an acoustic bubble spectrometer and confirmed production of monodisperse bubbles with approximately 100 μm diameters with fluidic oscillation. The higher number density of microbubbles under oscillatory flow indicated the effect of the fluidic oscillation in microbubble production. Visual observations and dissolved oxygen measurements suggested that the bubble cloud generated by the fluidic oscillator was sufficient enough to provide good mixing and to maintain uniform aerobic conditions. Overall, improved mass transfer coefficients, mixing efficiency and energy efficiency of the novel microbubble generation method could offer significant savings to the water treatment plants as well as reduction in the carbon footprint. PMID:25483415
Hayat, T; Saeed, Yusra; Alsaedi, A; Asad, Sadia
2015-01-01
The aim here is to investigate the effects of convective heat and mass transfer in the flow of Eyring-Powell fluid past an inclined exponential stretching surface. Mathematical formulation and analysis have been performed in the presence of Soret, Dufour and thermal radiation effects. The governing partial differential equations corresponding to the momentum, energy and concentration are reduced to a set of non-linear ordinary differential equations. Resulting nonlinear system is computed for the series solutions. Interval of convergence is determined. Physical interpretation is seen for the embedded parameters of interest. Skin friction coefficient, local Nusselt number and local Sherwood number are numerically computed and examined. PMID:26327398
NASA Astrophysics Data System (ADS)
Hayat, Tasawar; Qasim, Muhammad
2010-11-01
An analysis has been carried out to study the combined effects of heat and mass transfer on the unsteady flow of a micropolar fluid over a stretching sheet. The thermal radiation effects are presented. The arising nonlinear partial differential equations are first reduced to a set of nonlinear ordinary differential equations and then solved by the homotopy analysis method (HAM). Plots for various interesting parameters are presented and discussed. Numerical data for surface shear stress, Nusselt number, and Sherwood number in steady case are also tabulated. Comparison between the present and previous limiting results is given.
Hayat, T.; Saeed, Yusra; Alsaedi, A.; Asad, Sadia
2015-01-01
The aim here is to investigate the effects of convective heat and mass transfer in the flow of Eyring-Powell fluid past an inclined exponential stretching surface. Mathematical formulation and analysis have been performed in the presence of Soret, Dufour and thermal radiation effects. The governing partial differential equations corresponding to the momentum, energy and concentration are reduced to a set of non-linear ordinary differential equations. Resulting nonlinear system is computed for the series solutions. Interval of convergence is determined. Physical interpretation is seen for the embedded parameters of interest. Skin friction coefficient, local Nusselt number and local Sherwood number are numerically computed and examined. PMID:26327398
Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes
Jozewicz, W. . Environmental Systems Div.); Rochelle, G.T. . Dept. of Chemical Engineering)
1992-01-29
This report presents the results of fundamental mass transfer testing for in-duct removal of SO{sub 2}. Following this initial part of an experimental program, it became clear that the amount of initial moisture on the sorbent strongly affected the extent of Ca(OH){sub 2} conversion. Novel techniques aimed at increasing sorbent utilization were investigated and are described. Major novel technique investigated and reported on here was the reaction with SO{sub 2} of sorbents with initial free moisture (damp sorbents). The duct injection process using damp solids has the following steps: preparation of sorbent as a slurry, blending of the slurry with dry recycle materials to create damp solids, injection of the solids into the duct, reaction and drying of the solids with flue gas in the duct, collection in particulate control equipment, and finally recycle of dry solids with some bleed to disposal. The moisture content of the solids at each step affects system performance. Various factors favor high moisture whereas others favor low moisture. (VC)
Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes
Not Available
1990-04-25
During this reporting period, bench- and pilot-scale experiments have been concluded to measure mass transfer and kinetic rates at simulated duct injection conditions. Section 2 describes the tank reactor test results. Present work is focused on running the slurry absorption model for solution compositions which are representative of the tests performed in the stirred tank reactor. The slurry absorption model has been run successfully to simulate most of the clear solution experiments. Section 3 presents the results of a special study investigating the use of Epsom Salt (magnesium sulfate heptahydrate, MgSO{sub 4}{center dot}7H{sub 2}O) as an additive for in-duct dry injection to reduce the amount of water needed for humidification. Industrial grade Epsom Salt was injected into a 50-cfm pilot plant at {approximately}3.4 lb/h. Section 4 summarizes the status of slaking modification tests. The present study focuses on an evaluation of techniques for the production of a fine particulate Ca(OH){sub 2} during slaking. Section 5 reports on differential reactor (Task 4) tests. The reactor has been modified to allow contact of solids containing varying amounts of surface water with humidified flue gas for 10--120 s. Preliminary gas and wet solids experiments have been performed using lime/flyash mixtures containing 5--40 percent initial free moisture. 3 refs., 14 figs., 10 tabs.
PHREEQC. Geochemical Speciation Mass Transfer
Parkhurst, D.L.
1995-01-01
PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineral phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.
NASA Technical Reports Server (NTRS)
Weidner, John W.; Fedkiw, Peter S.
1991-01-01
A means is presented to account for the effect of ohmic, mass-transfer, and kinetic resistances on linear-sweep voltammograms by modeling a pore in a porous matrix as a cylindrical-pore electrode, and solving the mass and charge conservation equations in the context of this geometry for the simply redox reaction O + ne(-) yield R where both O and R are soluble species. Both analytical and numerical techniques are used to solve the governing equations. The calculated peak currents and potentials are correlated by empirical formulas to the measurable parameters: sweep rate, concentration of the redox species, diffusion coefficient, conductivity of the electrolyte, and pore dimensions. Using the correlations, a methodology is established for determining if the redox reaction kinetics are irreversible or reversible (Nernstian). If the reaction is irreversible, it is shown how the standard rate constant and the transfer coefficient may be extracted from linear-sweep voltammetry data, or, if the reaction is reversible, how the number of electrons transferred may be deduced.
MHD heat and mass transfer flow over a permeable stretching/shrinking sheet with radiation effect
NASA Astrophysics Data System (ADS)
Mat Yasin, Mohd Hafizi; Ishak, Anuar; Pop, Ioan
2016-06-01
The steady two-dimensional magnetohydrodynamic (MHD) flow past a permeable stretching/shrinking sheet with radiation effects is investigated. The similarity transformation is introduced to transform the governing partial differential equations into a system of ordinary differential equations before being solved numerically using a shooting method. The results are obtained for the skin friction coefficient, the local Nusselt number and the local Sherwood number as well as the velocity, temperature and the concentration profiles for some values of the governing parameters, namely, suction/injection parameter S, stretching/shrinking parameter λ, magnetic parameter M, radiation parameter R, heat source/sink Q and chemical rate parameter K. For the shrinking case, there exist two solutions for a certain range of parameters, but the solution is unique for the stretching case. The stability analysis verified that the upper branch solution is linearly stable and physically reliable while the lower branch solution is not. For the reliable solution, the skin friction coefficient increases in the present of magnetic field. The heat transfer rate at the surface decreases in the present of radiation.
Tsuchiya, Katsumi; Haryono, M.H.; Tomida, Tahei; Hatano, Hiroyuki; Oaki, Hiroshi
1996-02-01
Gas-dispersive capability of a hollow-fiber membrane, manufactured specifically for the use in fine bubbles generation, is tested for attaining high gas-liquid mass transfer rate under low-gas-throughput, shallow-sparging (at depths < 0.7 m) conditions. The hollow fiber is wound in a plane spiral form, each of which can be piled in a cylindrical module. A bubble column is used in the presence as well as absence of a draft tube, which the module can fit to and serve as part of. To enhance the effectiveness in the module`s generating fine bubbles, electrolytes are added to the liquid phase, water. Over a superficial gas velocity range of 0.1--2 mm/s, the hollow-fiber module (in comparison to conventional perforated-plate distributors) demonstrates, even with moderate gas-supply pressures (< 0.3 MPa), as high as 3-fold and 20-fold increases in the volumetric mass transfer coefficient in the absence and presence of the electrolytes, respectively. The former has been attained with a negligible increase in the gas holdup; the latter has accompanied a large ({approximately} 20-fold) increase in the gas holdup. While in the latter case the bubbles are very finely dispersed, the draft-tube model of operation secures still reasonable liquid circulation with nonclustering, spherical bubbles uniformly dispersed in each of the core and annular regions of the bubble column.
NASA Astrophysics Data System (ADS)
Reddy, M. Gnaneswara
2013-03-01
The problem of unsteady two-dimensional laminar flow of a viscous incompressible micropolar fluid past a vertical porous plate in the presence of a transverse magnetic field and thermal radiation with variable heat and mass fluxes is considered. The free stream velocity is subjected to exponentially increasing or decreasing small perturbations. A uniform magnetic field acts perpendicularly to a porous surface where a micropolar fluid is absorbed with a suction velocity varying with time. The Rosseland approximation is used to describe radiative heat transfer in the limit of optically thick fluids. The effects of the flow parameters and thermophysical properties on the velocity and temperature fields across the boundary layer are investigated. The effects of various parameters on the velocity, microrotation velocity, temperature, and concentration profiles are given graphically, and the values of the skin friction and couple stress coefficients are presented.
Enhancement of heat and mass transfer by cavitation
NASA Astrophysics Data System (ADS)
Zhang, Y. N.; Zhang, Y. N.; Du, X. Z.; Xian, H. Z.
2015-01-01
In this paper, a brief summary of effects of cavitation on the heat and mass transfer are given. The fundamental studies of cavitation bubbles, including its nonlinearity, rectified heat and mass diffusion, are initially introduced. Then selected topics of cavitation enhanced heat and mass transfer were discussed in details including whales stranding caused by active sonar activity, pool boiling heat transfer, oscillating heat pipe and high intensity focused ultrasound treatment.
Guerrero, H; Mark Fowley, M; Charles Crawford, C; Michael Restivo, M; Robert Leishear, R
2007-12-24
Gas holdup tests performed in a small-scale mechanically-agitated mixing system at the Savannah River National Laboratory (SRNL) were reported in 2006. The tests were for a simulant of waste from the Hanford Tank 241-AZ-101 and featured additions of DOW Corning Q2-3183A Antifoam agent. Results indicated that this antifoam agent (AFA) increased gas holdup in the waste simulant by about a factor of four and, counter intuitively, that the holdup increased as the simulant shear strength decreased (apparent viscosity decreased). These results raised questions about how the AFA might affect gas holdup in Hanford Waste Treatment and Immobilization Plant (WTP) vessels mixed by air sparging and pulse-jet mixers (PJMs). And whether the WTP air supply system being designed would have the capacity to handle a demand for increased airflow to operate the sparger-PJM mixing systems should the AFA increase retention of the radiochemically generated flammable gases in the waste by making the gas bubbles smaller and less mobile, or decrease the size of sparger bubbles making them mix less effectively for a given airflow rate. A new testing program was developed to assess the potential effects of adding the DOW Corning Q2-3183A AFA to WTP waste streams by first confirming the results of the work reported in 2006 by Stewart et al. and then determining if the AFA in fact causes such increased gas holdup in a prototypic sparger-PJM mixing system, or if the increased holdup is just a feature of the small-scale agitation system. Other elements of the new program include evaluating effects other variables could have on gas holdup in systems with AFA additions such as catalysis from trace noble metals in the waste, determining mass transfer coefficients for the AZ-101 waste simulant, and determining whether other AFA compositions such as Dow Corning 1520-US could also increase gas holdup in Hanford waste. This new testing program was split into two investigations, prototypic sparger
Yih, K.A.
1997-03-01
Effect of transpiration velocity on the heat and mass transfer characteristics of mixed convection about a permeable vertical plate embedded in a saturated porous medium under the coupled effects of thermal and mass diffusion is numerically analyzed. The plate is maintained at a uniform temperature and species concentration with constant transpiration velocity. The transformed governing equations are solved by Keller box method. Numerical results for the local Nusselt number and local Sherwood number are presented. In general, it has been found for thermally assisted flow that the local surface heat and mass transfer rates increase owing to suction of fluid. This trend reversed for blowing of fluid. It is apparent that the Lewis number has a pronounced effect on the local Sherwood number than it does on the local Nusselt number. Increasing the Lewis number decreases (increases) the local heat (mass) transfer rate.
Calculation of mass transfer in multiphase flow
Wang, L.; Gopal, M.
1998-12-31
This paper summarizes the results of mass transfer mechanisms under disturbed liquid-gas flow in 10 cm diameter pipe using electrochemical limiting current density and potentiostatic noise technique. The solution used is potassium ferro/ferricyanide dissolve in 1.3 N sodium hydroxide system. Mass transfer coefficients in full pipe flow and slug flow are obtained. The relationship between mass transfer coefficient with full pipe flow velocities and with slug flow Froude numbers are studied. The impact of bubbles in slugs on the mass transfer coefficient is revealed, The impact of flow disturbance, including weld beads and pits, are discussed for both full pipe flow and slug flow.
NASA Astrophysics Data System (ADS)
Van Camp, M.; Viron, O.; Avouac, J. P.
2016-05-01
We estimate the signature of the climate-induced mass transfers in repeated absolute gravity measurements based on satellite gravimetric measurements from the Gravity Recovery and Climate Experiment (GRACE) mission. We show results at the globe scale and compare them with repeated absolute gravity (AG) time behavior in three zones where AG surveys have been published: Northwestern Europe, Canada, and Tibet. For 10 yearly campaigns, the uncertainties affecting the determination of a linear gravity rate of change range 3-4 nm/s2/a in most cases, in the absence of instrumental artifacts. The results are consistent with what is observed for long-term repeated campaigns. We also discuss the possible artifact that can result from using short AG survey to determine the tectonic effects in a zone of high hydrological variability. We call into question the tectonic interpretation of several gravity changes reported from stations in Tibet, in particular the variation observed prior to the 2015 Gorkha earthquake.
Non-conservative mass transfers in Algols
NASA Astrophysics Data System (ADS)
Erdem, A.; Öztürk, O.
2014-06-01
We applied a revised model for non-conservative mass transfer in semi-detached binaries to 18 Algol-type binaries showing orbital period increase or decrease in their parabolic O-C diagrams. The combined effect of mass transfer and magnetic braking due to stellar wind was considered when interpreting the orbital period changes of these 18 Algols. Mass transfer was found to be the dominant mechanism for the increase in orbital period of 10 Algols (AM Aur, RX Cas, DK Peg, RV Per, WX Sgr, RZ Sct, BS Sct, W Ser, BD Vir, XZ Vul) while magnetic braking appears to be the responsible mechanism for the decrease in that of 8 Algols (FK Aql, S Cnc, RU Cnc, TU Cnc, SX Cas, TW Cas, V548 Cyg, RY Gem). The peculiar behaviour of orbital period changes in three W Ser-type binary systems (W Ser, itself a prototype, RX Cas and SX Cas) is discussed. The empirical linear relation between orbital period (P) and its rate of change (dP/dt) was also revised.
How We Make Mass Transfer Seem Difficult.
ERIC Educational Resources Information Center
Cussler, E. L.
1984-01-01
Indicates that teaching of mass transfer can be improved by: (1) using a single, simple definition of mass transfer coefficients; (2) altering use of analogies; and (3) repeatedly stressing differences between mathematical models used for chemical reactions and the actual chemistry of these reactions. Examples for undergraduate/graduate courses…
Heat and mass transfer in materials processing
NASA Astrophysics Data System (ADS)
Tanasawa, Ichiro; Lior, Noam
Various papers on heat and mass transfer in materials processing are presented. The topics addressed include: heat transfer in plasma spraying, structure of ultrashort pulse plasma for CVD processing, heat flow and thermal contraction during plasma spray deposition, metal melting process by laser heating, improved electron beam weld design and control with beam current profile measurements, transport phenomena in laser materials processing, perspectives on integrated modeling of transport processes in semiconductor crystal growth, numerical simulation of natural convection in crystal growth in space and on the earth, conjugate heat transfer in crystal growth, effects of convection on the solidification of binary mixtures. Also discussed are: heat transfer in in-rotating-liquid-spinning process, thermal oscillations in materials processing, modeling and simulation of manufacturing processes of advanced composite materials, reaction engineering principles of combustion synthesis of advanced materials, numerical evaluation of the physical properties of magnetic fluids suitable for heat transfer control, and measurement techniques of thermophysical properties of high temperature melts. (For individual items see A93-10827 to A93-10843)
Mass transfer and temperature effects on substrate utilization in brewery granules
Wu, M.M.; Criddle, C.S.; Hickey, R.F. |
1995-06-05
Liquid film and diffusional resistance of brewery granules during acetate, propionate, and ethanol utilization were investigated. Substrate utilization rate increased with decreased granule size. Effectiveness factors for acetate, propionate, and ethanol were calculated by comparing the maximum rates of substrate utilization of whole granules (1.8 to 3.0 mm) and fine flocs (20 to 75 {mu}m) derived by disrupting whole granules. For acetate, propionate, and ethanol, maximum specific substrate utilization rates (k{sub m}, g/g VS{center_dot}d) for the flocs, were 5.11, 6.25, and 5.49, respectively, and half-velocity coefficients (K{sub s}, mM) were 0.45, 0.40, and 3.37, respectively. Calculated effectiveness factors were 0.32, 0.41, and 0.75 for acetate, propionate, and ethanol, respectively. The effect of temperature on substrate utilization was examined at 26 C, 31 C, and 37 C using acetate as sole carbon source. Utilization rates increased with temperature. Flocs were most sensitive to temperature, and whole granules were least affected. The behavior of flocs was well described by the Van`t Hoff-Arrhenius equation. Effectiveness factors for acetate utilization by the granules were 0.36, 0.35, and 0.32 at 26 C, 31 C, and 37 C, respectively, indicating little effect of temperature. Based on these results, the authors conclude that both liquid film and diffusional resistances influenced the rate of substrate utilization in a UASB reactor with granular sludge. Temperature effects were much less important than diffusional limitations within the granules.
Technology Transfer Automated Retrieval System (TEKTRAN)
The diffusion coefficients of water and solutes are important parameters in the analysis, design and optimization of any infusion processes. Concentration and temperature of infusion solution have great influence on the rate of solid gain and water loss during an infusion processing. The effects o...
Espinal-Ruiz, Mauricio; Restrepo-Sánchez, Luz-Patricia; Narváez-Cuenca, Carlos-Eduardo
2016-10-15
The effect of high (HMP) and low (LMP) methoxylated pectins (2%w/w) on the rate and extent of the mass transfer of monosaccharides, amino acids, and a corn oil-in-water emulsion across a cellulose membrane was evaluated. A sigmoidal response kinetic analysis was used to calculate both the diffusion coefficients (rate) and the amount of nutrients transferred through the membrane (extent). In all cases, except for lysine, HMP was more effective than LMP in inhibiting both the rate and extent of the mass transfer of nutrients through the membrane. LMP and HMP, e.g., reduced 1.3 and 3.0times, respectively, the mass transfer rate of glucose, as compared to control (containing no pectin), and 1.3 and 1.5times, respectively, the amount of glucose transferred through the membrane. Viscosity, molecular interactions, and flocculation were the most important parameters controlling the mass transfer of electrically neutral nutrients, electrically charged nutrients, and emulsified lipids, respectively. PMID:27173546
Theoretical approach for enhanced mass transfer effects in duct flue gas desulfurization processes
Jozewicz, Wojciech . Environmental Systems Div.); Rochelle, G.T. . Dept. of Chemical Engineering)
1991-09-17
Novel techniques designed for the enhancement of Ca(OH){sub 2} utilization in dry-sorbent injection (DSI) and duct-spray drying (DSD) were investigated in the Long Time Differential Reactor (LTDR), Short Time Differential Reactor (STDR), and 50-cfm pilot plant. At 2000-ppm SO{sub 2} and 60 percent relative humidity, the presence of up to 30-percent initial free moisture significantly increased sorbent reactivity with SO{sub 2}, compared to sorbent with equilibrium amount of moisture. The conversion decreased when the initial free moisture increased beyond 30--50 percent. The initial free moisture content and corresponding level of maximum sorbent conversion with SO{sub 2} varied with the surface area of the sorbent. Sorbent moisture capacity tests indicated that agglomeration of damp calcium silicate sorbent was a function of sorbent pore volume. Critical moisture content was increasing with specific surface area. Very little improvement in SO{sub 2} removal was obtained by DSI recycle operation downstream of humidification. Significant enhancement was achieved by DSI recycle upstream of humidification. Grinding of DSI solids with and without fly ash resulted in significant increase of surface area and pore volume and resulting reactivity with SO{sub 2}. Organic buffer additives were tested as potential enhancement of Ca(OH){sub 2} utilization during the DSD process. Bench-scale results suggested that organic acids should be effective additives to enhance SO{sub 2} in slurry if SO{sub 2} absorption was controlled significantly by liquid film resistance. Pilot-plant tests did not demonstrate significant enhancement of Ca(OH){sub 2} conversion during spray drying as a result of buffer additives. Grinding of simulated DSD solids resulted in significant enhancement of Ca(OH){sub 2} reactivity with SO{sub 2}.
NASA Astrophysics Data System (ADS)
Zapata-Rios, Xavier; Brooks, Paul D.; Troch, Peter A.; McIntosh, Jennifer; Rasmussen, Craig
2016-03-01
The critical zone (CZ) is the heterogeneous, near-surface layer of the planet that regulates life-sustaining resources. Previous research has demonstrated that a quantification of the influxes of effective energy and mass transfer (EEMT) to the CZ can predict its structure and function. In this study, we quantify how climate variability in the last 3 decades (1984-2012) has affected water availability and the temporal trends in EEMT. This study takes place in the 1200 km2 upper Jemez River basin in northern New Mexico. The analysis of climate, water availability, and EEMT was based on records from two high-elevation SNOTEL stations, PRISM data, catchment-scale discharge, and satellite-derived net primary productivity (MODIS). Results from this study indicated a decreasing trend in water availability, a reduction in forest productivity (4 g C m-2 per 10 mm of reduction in precipitation), and decreasing EEMT (1.2-1.3 MJ m2 decade-1). Although we do not know the timescales of CZ change, these results suggest an upward migration of CZ/ecosystem structure on the order of 100 m decade-1, and that decadal-scale differences in EEMT are similar to the differences between convergent/hydrologically subsidized and planar/divergent landscapes, which have been shown to be very different in vegetation and CZ structure.
Ozone mass transfer and kinetics experiments
Bollyky, L.J.; Beary, M.M.
1981-12-01
Experiments were conducted at the Hanford Site to determine the most efficient pH and temperature levels for the destruction of complexants in Hanford high-level defense waste. These complexants enhance migration of radionuclides in the soil and inhibit the growth of crystals in the evaporator-crystallizer. Ozone mass transfer and kinetics tests have been outlined for the determination of critical mass transfer and kinetics parameters of the ozone-complexant reaction.
Secular dynamics in hierarchical three-body systems with mass loss and mass transfer
Michaely, Erez; Perets, Hagai B.
2014-10-20
Recent studies have shown that secular evolution of triple systems can play a major role in the evolution and interaction of their inner binaries. Very few studies explored the stellar evolution of triple systems, and in particular the mass-loss phase of the evolving stellar components. Here we study the dynamical secular evolution of hierarchical triple systems undergoing mass loss. We use the secular evolution equations and include the effects of mass loss and mass transfer, as well as general relativistic effects. We present various evolutionary channels taking place in such evolving triples, and discuss both the effects of mass loss and mass transfer in the inner binary system, as well as the effects of mass loss/transfer from an outer third companion. We discuss several distinct types/regimes of triple secular evolution, where the specific behavior of a triple system can sensitively depend on its hierarchy and the relative importance of classical and general relativistic effects. We show that the orbital changes due to mass-loss and/or mass-transfer processes can effectively transfer a triple system from one dynamical regime to another. In particular, mass loss/transfer can both induce and quench high-amplitude (Lidov-Kozai) variations in the eccentricity and inclination of the inner binaries of evolving triples. They can also change the system dynamics from an orderly periodic behavior to a chaotic one, and vice versa.
Mass transfer cycles in cataclysmic variables
NASA Technical Reports Server (NTRS)
King, A. R.; Frank, J.; Kolb, U.; Ritter, H.
1995-01-01
It is well known that in cataclysmic variables the mass transfer rate must fluctuate about the evolutionary mean on timescales too long to be directly observable. We show that limit-cycle behavior can occur if the radius change of the secondary star is sensitive to the instantaneous mass transfer rate. The only reasonable way in which such a dependence can arise is through irradiation of this star by the accreting component. The system oscillates between high states, in which irradiation causes slow expansion of the secondary and drives an elevated transfer rate, and low states, in which this star contracts.
Mass transfer from bypassed zones during gas injection
Burger, J.E.; Mohanty, K.K.
1995-12-31
Gasflooding in oil reservoirs leads to bypassing of the oil due to gravitational, viscous and/or heterogeneity effects. The bypassed oil can be recovered by the flowing solvent by pressure-driven, gravity-driven, dispersion/diffusion-driven and capillarity-driven crossflow/mass transfer. It is difficult to represent all of these mechanisms explicitly in large-scale simulations. In this work, we have studied the effect of the orientation of the bypassed region and the enrichment of the solvent on the mass transfer. Laboratory-scale mass transfer and coreflood experiments were conducted. Numerical simulation was used to identify the role of the different mechanisms. Results indicate that the mass transfer is the least for the vertical orientation, intermediate for the inverted orientation and the highest for the horizontal orientation. The mass transfer increases with enrichment for all orientations. Liquid phase diffusion controls vertical orientation mass transfer for the fluids studied. Phase behavior determines the liquid phase saturation. Capillary pumping does not contribute to the mass transfer of oil because the interfacial tension decreases towards the flowing region. Gravity-driven flow contributes the most to the mass transfer in the horizontal and the inverted orientations. The gravity-driven flow, however, is impeded by the capillarity whose magnitude decreases with solvent enrichment. Oil recovery in the horizontal gasfloods is nonmonotonic with enrichment for this fluid system in an almost homogeneous Berea core. Multiphase flow in the near-miscible floods leads to less gravity override compared to the FCM floods. In the heterogeneous core studied, the heterogeneity is very strong and the capillary forces do not prevent bypassing. The capillary forces, in fact, reduce oil recovery by diminishing mass transfer from the bypassed regions.
Mass Transfer Enhancement in Moving Biofilm Structures
Taherzadeh, Danial; Picioreanu, Cristian; Horn, Harald
2012-01-01
Biofilms are layers of microbial cells growing on an interface and they can form highly complex structures adapted to a wide variety of environmental conditions. Biofilm streamers have a small immobile base attached to the support and a flexible tail elongated in the flow direction, which can vibrate in fast flows. Herein we report numerical results for the role of the periodical movement of biofilm streamers on the nutrient uptake and in general on the solute mass transfer enhancement due to flow-induced oscillations. We developed what to our knowledge is a novel two-dimensional fluid-structure interaction model coupled to unsteady solute mass transport and solved the model using the finite element method with a moving mesh. Results demonstrate that the oscillatory movement of the biofilm tail significantly increases the substrate uptake. The mass transfer coefficient is the highest in regions close to the streamer tip. The reason for substrate transfer enhancement is the increase in speed of tip movement relative to the surrounding liquid, thereby reducing the thickness of the mass transfer boundary layer. In addition, we show that the relative mass transfer enhancement in unsteady conditions compared with the rigid static structure is larger at higher flow velocities, and this relative increase favors a more flexible structure. PMID:22500748
NASA Technical Reports Server (NTRS)
Walker, R. D., Jr.
1973-01-01
Developments in the following areas are reported: surface area and pore size distribution in electrolyte matrices, electron microscopy of electrolyte matrices, surface tension of KOH solutions, water transport in fuel cells, and effectiveness factors for fuel cell components.
Mass transfer in composite catalytic membranes
Langhendries, G.; Claessens, R.; Baron, G.V.
1996-12-31
The partial oxidation of cyclohexane was studied in a composite polymer-zeolite catalytic membrane reactor. In a first step the equilibrium and mass transfer properties (swelling, diffusion and sorption) of dense composite membranes were examined. The swelling behavior of the crosslinked poly(dimethylsiloxane) network was determined for several solvents and related to the differences between the Hildebrand solubility parameters of solvent and polymer. Time lag experiments, which enable us to measure simultaneously diffusion and partition coefficients, were carried out on a dense poly(dimethylsiloxane) membrane. A mathematical model describing the mass transfer behavior of these catalytic membranes was derived and validated with experimental data. Mass transfer through composite catalytic membranes can be predicted using the properties of pure catalyst and polymer material, and a single tortuosity factor. 9 refs., 5 figs., 4 tabs.
Roha, D.J.
1981-06-01
Limiting currents for the reduction of ferric cyanide at a rotating disk were determined in the presence of 0 to 40 percent by volume of spherical glass beads. Experiments were conducted with six different particle diameters, and with rotation speeds in the range of 387 to 270 rpm, usong both a 0.56 cm and a 1.41 cm radius disk electrode. It was established that at a given rpm upon addition of glass beads in the limiting current, i/sub L/, may increase to more than three times its value without solids. This increase in limiting current density is greater at high rotation speeds and with the larger disk electrode. i/sub L/ as a function of particle diameter yields at maximum at approx. 10 ..mu..m. Two mass transfer models are offered to explain this behavior, both of which assume that the beads are in contact with the disk electrode and moving parallel to its surface. In the surface renewal model it is assumed that complete mixing takes place with the passage of each bead and the boundary layer is replaced with fresh bulk solution. While with the particle film model it is assumed the bead and a clinging film of fluid rotate together. The film promotes mass transfer by alternately absorbing and desorbing the diffusing species. The particle film model best explains the observed behavior of the limiting current density. Calculations of stirring power required verses i/sub L/ observed, show that adding beads to increase i/sub L/ consumes less additional power than simply increasing the rotation speed alone and even permits a decrease in the amount of stirring energy required per unit reactant consumed, at limiting current conditions.
Local Mass and Heat Transfer on a Turbine Blade Tip
Jin, P.; Goldstein, R. J.
2003-01-01
Locmore » al mass and heat transfer measurements on a simulated high-pressure turbine blade-tip surface are conducted in a linear cascade with a nonmoving tip endwall, using a naphthalene sublimation technique. The effects of tip clearance (0.86–6.90% of chord) are investigated at various exit Reynolds numbers (4–7 × 10 5 ) and turbulence intensities (0.2 and 12.0%). The mass transfer on the tip surface is significant along its pressure edge at the smallest tip clearance. At the two largest tip clearances, the separation bubble on the tip surface can cover the whole width of the tip on the second half of the tip surface. The average mass-transfer rate is highest at a tip clearance of 1.72% of chord. The average mass-transfer rate on the tip surface is four and six times as high as on the suction and the pressure surface, respectively. A high mainstream turbulence level of 12.0% reduces average mass-transfer rates on the tip surface, while the higher mainstream Reynolds number generates higher local and average mass-transfer rates on the tip surface.« less
NASA Astrophysics Data System (ADS)
Mabood, F.; Shateyi, S.; Khan, W. A.
2015-09-01
This paper deals with a theoretical investigation of flow and heat transfer of a Casson fluid from a horizontal circular cylinder in a non-Darcy porous medium under the action of slips and thermal radiation parameters. A model of Casson fluid flow for a circular cylinder has been developed to simulate the transport phenomena. The numerical solution has been obtained for the dimensionless velocity and temperature of the Casson fluid. The effects of various important parameters on the dimensionless velocity, temperature as well as on the skin friction and the dimensionless heat transfer rates are investigated and presented graphically. A comparison with previous published data has been done and we found a good agreement with them.
NASA Astrophysics Data System (ADS)
Pedacchia, Augusta; Adrover, Alessandra
2012-11-01
We provide an analytical solution for the combined diffusive and convective 2-d mass transport from a surface film (of arbitrary shape at a given uniform concentration) to a pure solvent flowing in creeping flow conditions into a microchannel, delimited by a flat no-slip surface and by the releasing film itself. Such a problem arises in the study of swelling and dissolution of polimeric thin films under the action of a solvent tangential flow simulating the oral thin film dissolution for drug relase towards the buccal mucosa or oral cavity. We present a similarity solution for laminar forced convection mass (or heat) transfer that generalizes the classical boundary layer solution of the Graetz-Nusselt problem (valid for straight channels or pipes) to a solvent flowing in creeping flow conditions into a 2-d channel with cross-section continuously varying along the axial coordinate x. Close to the releasing boundary, parametrized by a curvilinear abscissa s, both tangential and normal velocity components play a role and their scaling behavior, as a function of wall distance r, should be taken into account in order to have an accurate description of the concentration profile in the boundary layer and of the dependence of the Sherwood number on the curvilinear abscissa s.
Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters
Day-Lewis, Frederick David; Singha, Kamini; Johnson, Timothy C.; Haggerty, Roy; Binley, Andrew; Lane, John W.
2014-11-25
Mass transfer affects contaminant transport and is thought to control the efficiency of aquifer remediation at a number of sites within the Department of Energy (DOE) complex. An improved understanding of mass transfer is critical to meeting the enormous scientific and engineering challenges currently facing DOE. Informed design of site remedies and long-term stewardship of radionuclide-contaminated sites will require new cost-effective laboratory and field techniques to measure the parameters controlling mass transfer spatially and across a range of scales. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Including the NMR component, our revised study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3
NASA Astrophysics Data System (ADS)
Prabhakar Reddy, B.
2016-02-01
In this paper, a numerical solution of mass transfer effects on an unsteady free convection flow of an incompressible electrically conducting viscous dissipative fluid past an infinite vertical porous plate under the influence of a uniform magnetic field considered normal to the plate has been obtained. The non-dimensional governing equations for this investigation are solved numerically by using the Ritz finite element method. The effects of flow parameters on the velocity, temperature and concentration fields are presented through the graphs and numerical data for the skin-friction, Nusselt and Sherwood numbers are presented in tables and then discussed.
Monolithic supports with unique geometries and enhanced mass transfer.
Stuecker, John Nicholas; Ferrizz, Robert Matthew; Cesarano, Joseph, III; Miller, James Edward
2004-01-01
The catalytic combustion of natural gas has been the topic of much research over the past decade. Interest in this technology results from a desire to decrease or eliminate the emissions of harmful nitrogen oxides (NOX) from gas turbine power plants. A low-pressure drop catalyst support, such as a ceramic monolith, is ideal for this high-temperature, high-flow application. A drawback to the traditional honeycomb monoliths under these operating conditions is poor mass transfer to the catalyst surface in the straight-through channels. 'Robocasting' is a unique process developed at Sandia National Laboratories that can be used to manufacture ceramic monoliths with alternative 3-dimensional geometries, providing tortuous pathways to increase mass transfer while maintaining low pressure drops. This report details the mass transfer effects for novel 3-dimensional robocast monoliths, traditional honeycomb-type monoliths, and ceramic foams. The mass transfer limit is experimentally determined using the probe reaction of CO oxidation over a Pt / {gamma}-Al{sub 2}O{sub 3} catalyst, and the pressure drop is measured for each monolith sample. Conversion versus temperature data is analyzed quantitatively using well-known dimensionless mass transfer parameters. The results show that, relative to the honeycomb monolith support, considerable improvement in mass transfer efficiency is observed for robocast samples synthesized using an FCC-like geometry of alternating rods. Also, there is clearly a trade-off between enhanced mass transfer and increased pressure drop, which can be optimized depending on the particular demands of a given application.
Proton Transfer Reaction Ion Trap Mass Spectrometer
Prazeller, Peter; Palmer, Peter T.; Boscaini, Elena; Jobson, B Tom T.; Alexander, M. Lizabeth
2003-06-11
Proton transfer reaction mass spectrometry is a relatively new field that has attracted a great deal of interest in the last few years. This technique uses H₃Oþ as a chemical ionization (CI) reagent to measure volatile organic compounds (VOCs) in the parts per billion by volume (ppbv) to parts per trillion by volume (pptv) range. Mass spectra acquired with a proton transfer reaction mass spectrometer (PTR-MS) are simple because proton transfer chemical ionization is ‘soft’ and results in little or no fragmentation. Unfortunately, peak identification can still be difficult due to isobaric interferences. A possible solution to this problem is to couple the PTR drift tube to an ion trap mass spectrometer (ITMS). The use of an ITMS is appealing because of its ability to perform MS/MS and possibly distinguish between isomers and other isobars. Additionally, the ITMS duty cycle is much higher than that of a linear quadrupole so faster data acquisition rates are possible that will allow for detection of multiple compounds. Here we present the first results from a proton transfer reaction ion trap mass spectrometer (PTR-ITMS). The aim of this study was to investigate ion injection and storage efficiency of a simple prototype instrument in order to estimate possible detection limits of a second-generation instrument. Using this prototype a detection limit of 100 ppbv was demonstrated. Modifications are suggested that will enable further reduction in detection limits to the low-ppbv to high-pptv range. Furthermore, the applicability of MS/MS in differentiating between isobaric species was determined. MS/MS spectra of the isobaric compounds methyl vinyl ketone (MVK) and methacrolein (MACR) are presented and show fragments of different mass making differentiation possible, even when a mixture of both species is present in the same sample. However, MS/MS spectra of acetone and propanal produce fragments with the same molecular masses but with different intensity ratios
Jian, Guoqiang; Zhou, Lei; Piekiel, Nicholas W; Zachariah, Michael R
2014-06-01
Oxygen release from metal oxides at high temperatures is relevant to many thermally activated chemical processes, including chemical-looping combustion, solar thermochemical cycles and energetic thermite reactions. In this study, we evaluated the thermal decomposition of nanosized metal oxides under rapid heating (~10(5) K s(-1)) with time-resolved mass spectrometry. We found that the effective activation-energy values that were obtained using the Flynn-Wall-Ozawa isoconversional method are much lower than the values found at low heating rates, indicating that oxygen transport might be rate-determining at a high heating rate. PMID:24619858
Yasin, Muhammad; Park, Shinyoung; Jeong, Yeseul; Lee, Eun Yeol; Lee, Jinwon; Chang, In Seop
2014-10-01
This study proposed a submerged hollow fibre membrane bioreactor (HFMBR) system capable of achieving high carbon monoxide (CO) mass transfer for applications in microbial synthesis gas conversion systems. Hydrophobic polyvinylidene fluoride (PVDF) membrane fibres were used to fabricate a membrane module, which was used for pressurising CO in water phase. Pressure through the hollow fibre lumen (P) and membrane surface area per unit working volume of the liquid (A(S)/V(L)) were used as controllable parameters to determine gas-liquid volumetric mass transfer coefficient (k(L)a) values. We found a k(L)a of 135.72 h(-1) when P was 93.76 kPa and AS/VL was fixed at 27.5m(-1). A higher k(L)a of 155.16 h(-1) was achieved by increasing AS/VL to 62.5m(-1) at a lower P of 37.23 kPa. Practicality of HFMBR to support microbial growth and organic product formation was assessed by CO/CO2 fermentation using Eubacterium limosum KIST612. PMID:25105269
Heat and mass transfer considerations in advanced heat pump systems
Panchal, C.B.; Bell, K.J.
1992-01-01
Advanced heat-pump cycles are being investigated for various applications. However, the working media and associated thermal design aspects require new concepts for maintaining high thermal effectiveness and phase equilibrium for achieving maximum possible thermodynamic advantages. In the present study, the heat- and mass-transfer processes in two heat-pump systems -- those based on absorption processes, and those using refrigerant mixtures -- are analyzed. The major technical barriers for achieving the ideal performance predicted by thermodynamic analysis are identified. The analysis provides general guidelines for the development of heat- and mass-transfer equipment for advanced heat-pump systems.
Heat and mass transfer considerations in advanced heat pump systems
Panchal, C.B.; Bell, K.J.
1992-08-01
Advanced heat-pump cycles are being investigated for various applications. However, the working media and associated thermal design aspects require new concepts for maintaining high thermal effectiveness and phase equilibrium for achieving maximum possible thermodynamic advantages. In the present study, the heat- and mass-transfer processes in two heat-pump systems -- those based on absorption processes, and those using refrigerant mixtures -- are analyzed. The major technical barriers for achieving the ideal performance predicted by thermodynamic analysis are identified. The analysis provides general guidelines for the development of heat- and mass-transfer equipment for advanced heat-pump systems.
Zhang, Chuan; Zhang, Huan; Zhang, Zhiping; Jiao, Youzhou; Zhang, Quanguo
2014-02-01
In this work, effects of mass transfer and light intensity on performance of substrate biodegradation by cell-immobilized photosynthetic bacteria were investigated within an annular fiber-illuminating bioreactor (AFIBR). In AFIBR, stable biofilm of photosynthetic bacteria was generated on the surface of side-glowing optical fiber to provide sufficient light supply and uniform light distribution in cell-immobilized zone for continuous substrate biodegradation during hydrogen production process. To optimize operation parameters for substrate degradation, a two-dimensional mass transfer model based on experimental data to describe coupled processes of substrate transfer and biodegradation in biofilm with substrate diffusion and convection in bulk flow region was proposed. Investigations on influences of substrate concentration, flow rate and light intensity were carried out. It was showed that the optimum operational parameters for the substrate degradation in the AFIBR are: 10g/l substrate concentration, 100ml/h flow rate and 3.1W/m(2) light intensity. PMID:24531266
Agitating mass transfer with a warped disc's shadow
NASA Astrophysics Data System (ADS)
Cambier, H.
2015-10-01
For compact objects fed by Roche lobe overflow, accretion-generated X-rays irradiating the donor star can alter gas flow towards the Lagrange point thus varying mass transfer. The latest work specific to this topic consists of simple yet insightful two-dimensional hydrodynamics simulations stressing the role of global flow. To explore how a time-varying disc shadow affects mass transfer, I generalize the geometry, employ a robust hydrodynamics solver, and use phase space analysis near the nozzle to include coriolis lift there. Without even exposing the nozzle, a warped disc's shadow can drive mass transfer cycles by shifting the equatorial edges of the irradiation patches in turns: drawing in denser ambient gas before sweeping it into the nozzle. Other important effects remain missing in two-dimensional models, which I discuss along with prospects for more detailed yet efficient models.
NASA Astrophysics Data System (ADS)
Zhao, Weiguo; Han, Xiangdong; Liu, Ming; Zheng, Yingjie
2016-05-01
The paper analyzed the effects of sand grain diameters and volume fractions on the mass transferring from the water-liquid to the water-vapor in a two-dimensional nozzle. Based on the mixture model, k–ɛ turbulence model and Schnerr-Sauer cavitation model, the solid-liquid-vapor three phases’ cavitation flows were simulated. When the grain mean diameters were defined as constants, volume fractions were changed to investigate the effects of them. The grain mean diameters were 0.013mm, 0.025mm and 0.05mm. Volume fractions were 0.02, 0.04, 0.05, 0.07 and 0.10. Results indicated that cavitation occurred at the beginning spots of the narrow part of the nozzle, low pressure regions. With the different grain mean diameters and volume fractions, effects of the sand on the mass transferring from the water-liquid to the water-vapor were diverse, proved by the curves of the cavitation numbers with the volume fractions of the sand and the curves of the volume fractions of the water-vapor with the volume fractions of the sand, reflecting the distinctions of interactions between the bubbles and the sand grains.
Konti, Aikaterini; Mamma, Diomi; Hatzinikolaou, Dimitios G; Kekos, Dimitris
2016-10-01
3-Chloro-1,2-propanediol (3-CPD) biodegradation by Ca-alginate immobilized Pseudomonas putida cells was performed in batch system, continuous stirred tank reactor (CSTR), and packed-bed reactor (PBR). Batch system exhibited higher biodegradation rates and 3-CPD uptakes compared to CSTR and PBR. The two continuous systems (CSTR and PBR) when compared at 200 mg/L 3-CPD in the inlet exhibited the same removal of 3-CPD at steady state. External mass-transfer limitations are found negligible at all systems examined, since the observable modulus for external mass transfer Ω ≪ 1 and the Biot number Bi > 1. Intra-particle diffusion resistance had a significant effect on 3-CPD biodegradation in all systems studied, but to a different extent. Thiele modulus was in the range of 2.5 in batch system, but it was increased at 11 when increasing cell loading in the beads, thus lowering significantly the respective effectiveness factor. Comparing the systems at the same cell loading in the beads PBR was less affected by internal diffusional limitations compared to CSTR and batch system, and, as a result, exhibited the highest overall effectiveness factor. PMID:27262716
Proton Transfer Reaction Ion Trap Mass Spectrometer
Prazeller, Peter; Palmer, Peter T.; Boscaini, Elena; Jobson, B Tom; Alexander, M. Lizabeth
2003-07-07
Proton Transfer Reaction Mass Spectrometry (PTR-MS) is a relatively new field that has attracted a great deal of interest in the last several years. This technique uses H3O+ as a chemical ionization (CI) agent for measuring volatile organic compounds (VOCs) in the parts per billion by volume (ppbv) - parts per trillion by volume (pptv) range. PTR-MS mass spectra are simple because the ionization method of proton transfer is “soft”, resulting in little or no fragmentation. Unfortunately, the simplicity of the mass spectra can cause problems in peak identification due to isobaric interferences. A possible solution to this problem is to couple the PTR drift tube to an ion trap mass spectrometer (ITMS). ITMS is appealing because of the ability to perform MS/MS and possibly distinguish between isomers and other isobars. Additionally, the ITMS duty cycle is much higher than that of a linear quadrupole so faster data acquisition rates can be realized for detection of multiple compounds. We present here the first results from a Proton Transfer Reaction Ion Trap Mass Spectrometer (PTR-ITMS). The aim of this study was to investigate ion injection and storage efficiency of a simple prototype interface in order to estimate possible detection limits of a second generation instrument. Using this prototype a detection limit of 100 ppbv was demonstrated for the PTR-ITMS. Modifications are suggested that will enable further reduction in detection limits to the low ppbv to pptv range. Furthermore the applicability of MS/MS to differentiate between isobaric species was determined. MS/MS spectra of the isobaric compounds methyl vinyl ketone (MVK) and methacrolein (MACR) are presented and show fragments of different mass making a differentiation possible even when a mixture of both species is present in the same sample. MS/MS spectra of acetone and propanal produce fragments with the same molecular weight but different ratios, allowing quantitative distinction only if one species
43 CFR 3106.4-3 - Mass transfers.
Code of Federal Regulations, 2011 CFR
2011-10-01
... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the...
43 CFR 3106.4-3 - Mass transfers.
Code of Federal Regulations, 2013 CFR
2013-10-01
... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the...
43 CFR 3106.4-3 - Mass transfers.
Code of Federal Regulations, 2012 CFR
2012-10-01
... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the...
43 CFR 3106.4-3 - Mass transfers.
Code of Federal Regulations, 2014 CFR
2014-10-01
... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Mass transfers. 3106.4-3 Section 3106.4-3... or Otherwise § 3106.4-3 Mass transfers. (a) A mass transfer may be utilized in lieu of the provisions... large number of Federal leases to the same transferee. (b) Three originally executed copies of the...
Simultaneous removal of SO2 and trace SeO2 from flue gas: effect of product layer on mass transfer.
Li, Yuzhong; Tong, Huiling; Zhuo, Yuqun; Chen, Changhe; Xu, Xuchang
2006-07-01
Sulfur dioxide (SO2) and trace elements are all pollutants derived from coal combustion. This study relates to the simultaneous removal of sulfur and trace selenium dioxide (SeO2) by calcium oxide (CaO) adsorption in the medium temperature range, especially the mass transfer effect of sulfate product layer on trace elements. Through experiments on CaO adsorbing different concentrations of SO2 gases, conclusions can be drawn that although the product layer introduces extra mass transfer resistance into the sorbent-gas reaction process, the extent of CaO adsorption ability loss due to this factor decreases with decreasing SO2 concentration. When the gas concentration is at trace level, the loss of CaO adsorption ability can be neglected. Subsequent experiments on CaO adsorbing trace SeO2 gas suggest that the sulfate product layer, whether it is thick or thin, has no obvious effect on the CaO ability to adsorb trace SeO2 gas. PMID:16856751
Chaktranond, Chainarong; Rattanadecho, Phadungsak
2010-11-15
This research experimentally investigates the influences of electrical voltage, particle sizes and layer arrangement on the heat and mass transfer in porous packed bed subjected to electrohydrodynamic drying. The packed bed consists of a single and double layers of glass beads, water and air. Sizes of glass beads are 0.125 and 0.38 mm in diameter. Electric fields are applied in the range of 0-15 kV. Average velocity and temperature of hot airflow are controlled at 0.33 m/s and 60 C, respectively. The results show that the convective heat transfer coefficient and drying rate are enhanced considerably with a Corona wind. In the single-layered case, due to effects of porosity, the packed bed containing small beads has capillary pressure higher than that with big beads, resulting in higher removal rate of water and higher rate of heat transfer. Considering the effect of capillary pressure difference, temperature distribution and removal rate of moisture in the double-layered case appear to be different than those observed in the single-layered case. Moreover, in the double-layered case, the fine-coarse packed bed gives drying rate higher than that given by the coarse-fine packed bed. (author)
Multidimensional mechanistic modeling of interfacial heat and mass transfer
Shaver, D. R.; Antal, S. P.; Podowski, M. Z.
2012-07-01
A combined theoretical and computational study in modeling multidimensional, diabatic vapor/liquid flows is presented. Models have been developed governing kinematic aspects of multiphase flow as well as interfacial mass and heat transfer for flows of condensable gas (vapor) and liquids. The modeling formulation is based on the Reynolds averaged Navier-Stokes (RANS) type multi-field approach which utilizes a complete set of conservation equations for each fluid component 1. The modeled interfacial interactions include energy, mass, and momentum transfer. Emphasis in the model development work has been placed on the mechanisms governing coupled interfacial heat and mass transfer between the liquid and vapor fields (condensation and/or boiling). A method for tracking changes in bubble size is presented and tested. Locally based models of multidimensional effects have been analyzed, including distributions of fluid temperatures and volume fractions. The overall model accounts for both kinematic and thermodynamic nonequilibrium between the component fluids including superheated vapor. The model has been implemented in the NPHASE-CMFD computer code. Results from the kinematic model are compared to experimental data and good agreement is demonstrated. The heat and mass transfer model is parametrically tested to show the multidimensional effects on the rate of heat and mass transfer. These effects are explained in terms of local characteristics of the two-phase flow. The model is applied to a scenario of saturated vapor injected into a subcooled flow through a heated, porous wall. This provides a reasonable approximation to subcooled boiling. The results are found to be dependent on the partitioning of the wall heat flux between direct liquid heating and vapor generation. However, the observed dependencies are explained and the modeling is considered consistent. (authors)
NASA Astrophysics Data System (ADS)
Egorov, Alexander V.; Nigmatulin, Robert I.; Rozhkov, Aleksey N.
2016-06-01
The present paper focuses on heat and mass exchange processes in methane hydrate fragments during in situ displacement from the gas hydrate stability zone (GHSZ) to the water surface of Lake Baikal. After being extracted from the methane hydrate deposit at the lakebed, hydrate fragments were placed into a container with transparent walls and a bottom grid. There were no changes in the hydrate fragments during ascent within the GHSZ. The water temperature in the container remained the same as that of the ambient water (~3.5 °C). However, as soon as the container crossed the upper border of the GHSZ, first signs of hydrate decomposition and transformation into free methane gas were observed. The gas filled the container and displaced water from it. At 300 m depth, the upper and lower thermometers in the container simultaneously recorded noticeable decreases of temperature. The temperature in the upper part of the container decreased to -0.25 °C at about 200 m depth, after which the temperature remained constant until the water surface was reached. The temperature at the bottom of the container reached -0.25 °C at about 100 m depth, after which it did not vary during further ascent. These observed effects could be explained by the formation of a gas phase in the container and an ice layer on the hydrate surface caused by heat consumption during hydrate decomposition (self-preservation effect). However, steady-state simulations suggest that the forming ice layer is too thin to sustain the hydrate internal pressure required to protect the hydrate from decomposition. Thus, the mechanism of self-preservation remains unclear.
Interrupted Binary Mass Transfer in Star Clusters
NASA Astrophysics Data System (ADS)
Leigh, Nathan W. C.; Geller, Aaron M.; Toonen, Silvia
2016-02-01
Binary mass transfer (MT) is at the forefront of some of the most exciting puzzles of modern astrophysics, including SNe Ia, gamma-ray bursts, and the formation of most observed exotic stellar populations. Typically, the evolution is assumed to proceed in isolation, even in dense stellar environments such as star clusters. In this paper, we test the validity of this assumption via the analysis of a large grid of binary evolution models simulated with the SeBa code. For every binary, we calculate analytically the mean time until another single or binary star comes within the mean separation of the mass-transferring binary, and compare this timescale to the mean time for stable MT to occur. We then derive the probability for each respective binary to experience a direct dynamical interruption. The resulting probability distribution can be integrated to give an estimate for the fraction of binaries undergoing MT that are expected to be disrupted as a function of the host cluster properties. We find that for lower-mass clusters (≲ {10}4 {M}⊙ ), on the order of a few to a few tens of percent of binaries undergoing MT are expected to be interrupted by an interloping single, or more often binary, star, over the course of the cluster lifetime, whereas in more massive globular clusters we expect \\ll 1% to be interrupted. Furthermore, using numerical scattering experiments performed with the FEWBODY code, we show that the probability of interruption increases if perturbative fly-bys are considered as well, by a factor ˜2.
LUT observations of the mass-transferring binary AI Dra
NASA Astrophysics Data System (ADS)
Liao, Wenping; Qian, Shengbang; Li, Linjia; Zhou, Xiao; Zhao, Ergang; Liu, Nianping
2016-06-01
Complete UV band light curve of the eclipsing binary AI Dra was observed with the Lunar-based Ultraviolet Telescope (LUT) in October 2014. It is very useful to adopt this continuous and uninterrupted light curve to determine physical and orbital parameters of the binary system. Photometric solutions of the spot model are obtained by using the W-D (Wilson and Devinney) method. It is confirmed that AI Dra is a semi-detached binary with secondary component filling its critical Roche lobe, which indicates that a mass transfer from the secondary component to the primary one should happen. Orbital period analysis based on all available eclipse times suggests a secular period increase and two cyclic variations. The secular period increase was interpreted by mass transfer from the secondary component to the primary one at a rate of 4.12 ×10^{-8}M_{⊙}/yr, which is in agreement with the photometric solutions. Two cyclic oscillations were due to light travel-time effect (LTTE) via the presence of two cool stellar companions in a near 2:1 mean-motion resonance. Both photometric solutions and orbital period analysis confirm that AI Dra is a mass-transferring binary, the massive primary is filling 69 % of its critical Roche lobe. After the primary evolves to fill the critical Roche lobe, the mass transfer will be reversed and the binary will evolve into a contact configuration.
Mass transfer experiments on single irregular-shaped particles
Ramezan, M. ); Kale, S.R. ); Anderson, R.J. )
1991-01-01
Mass transfer from irregular-shaped naphthalene particles (100-200 {mu}m in size) was studied in an electrodynamic balance. Charged particles were suspended in an electrostatic field directly in line with a calibrated air jet. Mass and size change histories were obtained under ambient conditions, and under steady- and pulsed-flow conditions. For natural convection, the time-averaged Sherwood number was similar to that for spheres. Forced-convection Sherwood number under steady-flow conditions was strongly dependent on particle shape and particle Reynolds number, and was consistently higher than values predicted for spheres at comparable Reynolds numbers. This paper validates the technique and indicates the shape effect on mass transfer from single particles.
Heat and mass transfer in flames
NASA Technical Reports Server (NTRS)
Faeth, G. M.
1986-01-01
Heat- and mass-transfer processes in turbulent diffusion flames are discussed, considering turbulent mixing and the structure of single-phase flames, drop processes in spray flames, and nonluminous and luminous flame radiation. Interactions between turbulence and other phenomena are emphasized, concentrating on past work of the author and his associates. The conserved-scalar formalism, along with the laminar-flamelet approximation, is shown to provide reasonable estimates of the structure of gas flames, with modest levels of empiricism. Extending this approach to spray flames has highlighted the importance of drop/turbulence interactions; e.g., turbulent dispersion of drops, modification of turbulence by drops, etc. Stochastic methods being developed to treat these phenomena are yielding encouraging results.
USINT. Heat and Mass Transfer In Concrete
Eyberger, L.R.
1989-12-01
USINT was developed to model the thermal response of concrete to very high heating rates such as might occur from sodium spills on concrete surfaces in a breeder reactor. The major phenomena treated are conductive energy transport; chemical decomposition of concrete; and two-phase, three-component heat and mass transfer of the decomposition products: steam, liquid water, and carbon dioxide. The USINT model provides for porosity to increase as water and carbon-dioxide are formed from the concrete. The concrete is treated generally as divided into two basic regions, wet and dry. In the wet region, steam, carbon-dioxide, and liquid water may co-exist, but in the dry region, there is no liquid water. There is also the possibility of a third region in which there is only liquid water and no gases.
USINT. Heat and Mass Transfer in Concrete
Beck, J.V.; Knight, R.L.
1989-12-01
USINT was developed to model the thermal response of concrete to very high heating rates such as might occur from sodium spills on concrete surfaces in a breeder reactor. The major phenomena treated are conductive energy transport; chemical decomposition of concrete; and two-phase, three-component heat and mass transfer of the decomposition products: steam, liquid water, and carbon dioxide. The USINT model provides for porosity to increase as water and carbon-dioxide are formed from the concrete. The concrete is treated generally as divided into two basic regions, wet and dry. In the wet region, steam, carbon-dioxide, and liquid water may co-exist, but in the dry region, there is no liquid water. There is also the possibility of a third region in which there is only liquid water and no gases.
Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters
Day-Lewis, Frederick; Singha, Kamini; Haggerty, Roy; Johnson, Tim; Binley, Andrew; Lane, John
2014-01-16
Mass transfer affects contaminant transport and is thought to control the efficiency of aquifer remediation at a number of sites within the Department of Energy (DOE) complex. An improved understanding of mass transfer is critical to meeting the enormous scientific and engineering challenges currently facing DOE. Informed design of site remedies and long-term stewardship of radionuclide-contaminated sites will require new cost-effective laboratory and field techniques to measure the parameters controlling mass transfer spatially and across a range of scales. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Including the NMR component, our revised study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3
Mixing and mass transfer considerations in highly viscous fermentations
Applegate, M.A.; Flatt, J.H.
1995-12-01
Highly viscous microbial fermentations pose difficult scale-up challenges for the industrial biochemical engineer. Incomplete bulk mixing and poor oxygen mass transfer often limit fermentor titers and productivities. Lower heat transfer coefficients coupled with higher rates of heat generation through viscous dissipation further confound operational difficulties. Practical approaches to alleviating these factors will be discussed using examples from viscoelastic gellan, welan, and xanthan gum fermentations. In addition, a summary of the effects of power input, aeration, media manipulation, and genetic modifications will be discussed.
Fundamental mass transfer models for indoor air pollution sources
Tichenor, B.A.; Guo, Z.; Sparks, L.E.
1993-01-01
The paper discusses a simple, fundamental mass transfer model, based on Fick's Law of Diffusion, for indoor air pollution wet sorbent-based sources. (Note: Models are needed to predict emissions from indoor sources. While empirical approaches based on dynamic chamber data are useful, a more fundamental approach is needed to fully elucidate the relevant mass transfer processes). In the model, the mass transfer rate is assumed to be gas-phase limited and controlled by the boundary layer mass transfer coefficient, the saturation vapor pressure of the material being emitted, and the mass of volatile material remaining. Results of static and dynamic chamber tests, as well as test house studies, are presented.
NASA Astrophysics Data System (ADS)
Thamizhsudar, M.; Pandurangan, J.; Muthucumaraswamy, R.
2015-08-01
A theoretical solution of flow past an exponentially accelerated vertical plate in the presence of Hall current and MHD relative to a rotating fluid with uniform temperature and mass diffusion is presented. The dimensionless equations are solved using the Laplace method. The axial and transverse velocity, temperature and concentration fields are studied for different parameters such as the Hall parameter (m), Hartmann number (M), Rotation parameter (Ω), Schmidt number, Prandtl number, thermal Grashof number (Gr) and mass Grashof number (Gc). It has been observed that the temperature of the plate decreases with increasing values of the Prandtl number and the concentration near the plate increases with decreasing values of Schmidt number. It is also observed that both axial and transverse velocities increase with decreasing values of the magnetic field parameter or rotation parameter, but the trend gets reversed with respect to the Hall parameter. The effects of parameters m, M, Ω, Gr and Gc on the axial and transverse velocity profiles are shown graphically.
Uwanta, Ime Jimmy; Usman, Halima
2014-01-01
The present paper investigates the combined effects of Soret and Dufour on free convective heat and mass transfer on the unsteady one-dimensional boundary layer flow over a vertical channel in the presence of viscous dissipation and constant suction. The governing partial differential equations are solved numerically using the implicit Crank-Nicolson method. The velocity, temperature, and concentration distributions are discussed numerically and presented through graphs. Numerical values of the skin-friction coefficient, Nusselt number, and Sherwood number at the plate are discussed numerically for various values of physical parameters and are presented through tables. It has been observed that the velocity and temperature increase with the increase in the viscous dissipation parameter and Dufour number, while an increase in Soret number causes a reduction in temperature and a rise in the velocity and concentration. PMID:27419208
NASA Technical Reports Server (NTRS)
Gokoglu, S. A.; Rosner, D. E.
1984-01-01
A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.
Conjugate mixed convection heat and mass transfer in brick drying
NASA Astrophysics Data System (ADS)
Suresh, H. N.; Aswatha Narayana, P. A.; Seetharamu, K. N.
In this study, a numerical methodology for the solution of conjugate heat and mass transfer problem is presented. Fluid flow, heat and mass transfer over a rectangular brick due to transient laminar mixed convection has been numerically simulated. The coupled non-linear partial differential equations, for both gas phase and solid are solved using finite element procedure. Flow is assumed to be incompressible, two-dimensional, laminar. Analysis has been carried out at a Reynolds number of 200 with Pr=0.71. The effect of buoyancy on the brick drying has been investigated. Velocity vectors, streamlines in the flow field and temperature and moisture contours and temperature distribution along the solid surface are presented. It is observed that there is considerable effect of buoyancy during drying. The results indicate a non-uniform drying of the brick with the leading edge drying faster than the rest of the brick.
Nonlinear analysis of capillary instability with heat and mass transfer
NASA Astrophysics Data System (ADS)
Awasthi, Mukesh Kumar; Agrawal, G. S.
2012-06-01
The nonlinear capillary instability of the cylindrical interface between the vapor and liquid phases of a fluid is studied when there is heat and mass transfer across the interface, using viscous potential flow theory. The fluids are considered to be viscous and incompressible with different kinematic viscosities. Both asymmetric and axisymmetric disturbances are considered. The analysis is based on the method of multiple scale perturbation and the nonlinear stability is governed by first-order nonlinear partial differential equation. The stability conditions are obtained and discussed theoretically as well as numerically. Regions of stability and instability have been shown graphically indicating the effect of various parameters. It has been observed that the heat and mass transfer has stabilizing effect on the stability of the system in the nonlinear analysis for both axisymmetric as well as asymmetric disturbances.
The impact of separated flow on heat and mass transfer
Goldstein, R.J.; Jabbari, M.Y.
1990-01-01
An investigation of the effect of flow separation on heat (or mass) transfer is underway. This research, sponsored by the Department of Energy (Contract No. FG02-87ER13800), is planned to enhance our understanding of the fundamental mechanisms governing the process. This report summarizes previous accomplishments and briefly describes works done during period May 1, 1989 through April 30, 1990. Future plans and studies under preparation are also mentioned. 8 refs., 7 figs.
Mass transfer at gas-evolving surfaces in electrolysis
Dees, D.W.; Tobias, C.W.
1983-09-01
A novel micro-mosaic electrode was developed to resolve time-dependent, mass-transfer distribution in the close vicinity of bubble phenomena. The electrode, prepared on a silicon wafer using integrated circuit manufacturing technology, consists of a 10 by 10 matrix of coplanar, electrically isolated, square platinum segments on 100 micron centers, surrounded by a relatively large buffer segment. A computer-actuated data acquisition and control system was assembled and the software developed to monitor the current to each of the segments and control the potential of selected segments. The utility of the electrode to examine interfacial mass transport phenomena which have characteristic lengths as small as 100 microns has been clearly demonstrated. The effect of a single hydrogen bubble disengagement and of the coalescence of two bubbles, on the limiting current of the reduction of ferric to ferrous ion was measured using the micro-mosaic electrode in a horizontal: facing-up orientation. In the absence of gas evolution, large regular fluctuations in the limiting current to the segments with a period of 29 sec were observed. This periodic behavior is attributed to free convection: a cellular fluid motion moving across the electrode with a velocity of 40 microns/second. It was found that the mass-transfer enhancement due to bubble disengagement is small when compared to that due to coalescence. Increases in the mass-transfer rate of more than an order of magnitude over the free convection limiting current were observed for the coalescence phenomena. Two theoretical models were developed to account for the observed effect of a bubble disengagement on the mass transfer-rate to the surface.
The impact of separated flow on heat and mass transfer. Final report
Goldstein, R.J.
1998-08-01
An investigation of the effect of flow separation on heat and mass transfer has been completed. This research provided enhanced understanding of fundamental mechanisms governing important heat and mass transfer flow processes. This report summarizes the work conducted under the project. This research has provided considerable new knowledge on flow and heat transfer situations of great interest in a number of energy conversion devices, including heat exchangers, gas turbines, solar energy systems and general heat transfer systems.
Behavior of the mass transfer zone in a biosorption column.
Naja, Ghinwa; Volesky, Bohumil
2006-06-15
Modeling of the mass transfer zone behavior under variable conditions in a flow-through fixed-bed sorption column enabled the prediction of breakthrough curves for Cu2+ and Ca-preloaded Sargassum fluitans biomass. The mass transfer resistance, particle diffusion, and the axial dispersion were incorporated in the model. The dynamics of the mass transfer zone was described under variable sorption column operating conditions including different column lengths and fluid flow rates. Accurate estimation of the behavior of the mass transfer zone as it progressed through the column, reflected eventually in the breakthrough curve, assisted in its relevant interpretations. Furthermore, the proposed mathematical model of the biosorption process was capable of demonstrating the expanding and broadening of the mass transfer zone linked to the equilibrium sorption isotherm. The fundamental understanding of the mass transfer zone dynamics is particularly important for process scale-up where maintaining the process efficiency is critical. PMID:16830573
Mass-transfer in close binary and their companions
NASA Astrophysics Data System (ADS)
Liao, Wenping; Qian, Shengbang; Zhu, Liying; Li, Linjia
2016-07-01
Secular and/or cyclical orbital period variations of close binaries can be derived by analyzing the (O-C) diagram. The secular variations are usually explained as mass transfer between components, while the most plausible explanation of the cyclic period changes is the light-travel time effect (LTTE) through the presence of a third body. Mass transfer and additional companions in close binary systems are important for understanding the formation and evolution of the systems. Here, UV light curves of several close binaries based on the Lunar-based Ultraviolet Telescope (LUT) observations are presented and analyzed with the Wilson-Devinney (W-D) method. Then, based on those light-curve solutions and new analysis of the orbital period variations, the multiplicity, geometrical structure and evolution state of targets are discussed.
Modelling mass transfer and agitator performance in multiturbine fermentors.
Bader, F G
1987-07-01
A methodology for mathematically analyzing agitator performance and mass transfer in large multiturbine production fermentors is presented. The application of this approach provides a method for determining axial dissolved oxygen profiles under conditions of known mass transfer rates as a function of agitation-aeration characteristics. A stagewise approach is used which divides the fermentor into a series of mixing cells. This allows for each turbine and mixing cell to be individually optimized. The model also permits the determination of the mass transfer coefficient for each turbine based upon limited dissolved oxygen data. The primary limitation of this approach rests in the limited data and correlations available for multiturbine systems. The structure of the modelling approach can serve as a basis for testing single turbine correlations and adapting them to multiturbine systems. The step-by-step details of the mathematical analysis are presented and interpreted. A series of computer simulations demonstrate the effect of typical fermentor operating variables on the axial dissolved oxygen profile. Further simulations demonstrate the effect of modifying agitator blade numbers on the dissolved oxygen profile and agitator power requirement. PMID:18576581
Restrained Ion Population Transfer: A Novel Ion Transfer Method for Mass Spectrometry.
Kaiser, Nathan K.; Skulason, Gunnar; Weisbrod, Chad R.; Wu, Si; Zhang, Kai; Prior, David C.; Buschbach, Michael A.; Anderson, Gordon A.; Bruce, James E.
2008-06-30
With modern Fourier transform ion cyclotron resonance (ICR) mass spectrometers, ions are created and accumulated exterior to the mass analyzer. The ion accumulation event takes place in a region of higher pressure which allows ions to be thermally cooled before being given kinetic energy and accelerated toward the ICR cell where they are to be decelerated and re-trapped. When gated trapping is used to collect ions in the ICR cell for analysis, mass discrimination can occur due to time-of-flight effects. Also, trapping ions with large axial kinetic energy can decrease the performance of the ICR instrument when compared to the analysis of thermally-cooled ions located at the trap center. Therefore, it is desirable to limit the energy imparted in the ions within the ICR cell as well as minimize time-of-flight effects. The approach presented here for ion transfer called restrained ion population transfer or RIPT provides complete axial control of an ion population throughout the entire transfer sequence from the accumulation region to the ICR cell. This is accomplished by utilization of a number of quadrupole segments arranged in series with independent control of the dc bias voltage applied to each segment of the quadrupole ion guide. This approach circumvents problems associated with time-of-flight effects and minimizes the energy imparted to the ions allowing transfer of the cooled ion packet from the ion accumulation region to the ICR cell. Initial data are presented to illustrate feasibility of restrained ion population transfer. RIPT was also modeled with SIMION 7.0 and simulation results that support our feasibility studies of the ions transfer process are presented.
Convective heat and mass transfer during the evaporation of a liquid into a gas flow
NASA Astrophysics Data System (ADS)
Boiarshinov, B. F.; Volchkov, E. P.; Terekhov, V. I.
1985-10-01
Heat and mass transfer processes associated with liquid evaporation are analyzed for adiabatic and nonadiabatic conditions. Experimental data are then presented on heat and mass transfer during the evaporation of water and ethyl alcohol from a porous surface. It is shown that heat and mass transfer under conditions of evaporation can be described by using expressions for flow past a 'dry' wall. A diagram is presented for determining the magnitudes of additional heat sources in the case of nonadiabatic evaporation. Finally, the effect of various factors, such as temperature, flow humidity, and liquid type, on heat and mass transfer during evaporation is analyzed for laminar and turbulent flows.
NASA Astrophysics Data System (ADS)
Chen, X.; Le, T.; Ewing, D.; Ching, C. Y.
2016-02-01
The mass transfer to turbulent flow through back-to-back pipe bends arranged in a 180° configuration with different lengths of pipe between the bends was measured using a dissolving gypsum test section in water. The measurements were performed for bends with a radius of curvature of 1.5 times the pipe diameter (D) at a Reynolds numbers of 70,000 and Schmidt number of 1280. The maximum mass transfer in the bends decreased from approximately 1.8 times the mass transfer in the upstream pipe when there was no separation distance between the bends to 1.7 times when there was a 1D or 5D length of pipe between the bends. The location of the maximum mass transfer was on the inner sidewall downstream of the second bend when there was no separation distance between the bends. This location changed to the inner wall at the beginning of the second bend when there was a 1D long pipe between the bends, and to the inner sidewall at the end of the first bend when there was a 5D long pipe between the bends.
Michelan, Rogério; Zimmer, Thiago R; Rodrigues, José A D; Ratusznei, Suzana M; de Moraes, Deovaldo; Zaiat, Marcelo; Foresti, Eugenio
2009-03-01
The effect of flow type and rotor speed was investigated in a round-bottom reactor with 5 L useful volume containing 2.0 L of granular biomass. The reactor treated 2.0 L of synthetic wastewater with a concentration of 800 mgCOD/L in 8-h cycles at 30 degrees C. Five impellers, commonly used in biological processes, have been employed to this end, namely: a turbine and a paddle impeller with six-vertical-flat-blades, a turbine and a paddle impeller with six-45 degrees -inclined-flat-blades and a three-blade-helix impeller. Results showed that altering impeller type and rotor speed did not significantly affect system stability and performance. Average organic matter removal efficiency was about 84% for filtered samples, total volatile acids concentration was below 20 mgHAc/L and bicarbonate alkalinity a little less than 400 mgCaCO3/L for most of the investigated conditions. However, analysis of the first-order kinetic model constants showed that alteration in rotor speed resulted in an increase in the values of the kinetic constants (for instance, from 0.57 h(-1) at 50 rpm to 0.84 h(-1) at 75 rpm when the paddle impeller with six-45 degrees -inclined-flat-blades was used) and that axial flow in mechanically stirred reactors is preferable over radial-flow when the vertical-flat-blade impeller is compared to the inclined-flat-blade impeller (for instance at 75 rpm, from 0.52 h(-1) with the six-flat-blade-paddle impeller to 0.84 h(-1) with the six-45 degrees -inclined-flat-blade-paddle impeller), demonstrating that there is a rotor speed and an impeller type that maximize solid-liquid mass transfer in the reaction medium. Furthermore, power consumption studies in this reduced reactor volume showed that no high power transfer is required to improve mass transfer (less than 0.6 kW/10(3)m3). PMID:18814952
Mass transfer ways of ultraviolet printing ink ingredients into foodstuffs.
Jung, T; Simat, T J; Altkofer, W
2010-07-01
The case of isopropylthioxanthone (ITX) showed conclusively that the ingredients of ultraviolet printing inks may migrate into packaged foodstuffs. For multilayered materials like beverage cartons, the only way that mass transfer can occur is by the so-called set-off effect. In contrast, in the case of rigid plastics like yoghurt cups, two other methods of mass transfer, permeation and gas phase, have to be considered. In cooperation with producers of ink, plastic cups and yoghurt, a project was conducted in order to elucidate the mass transfer of ink ingredients. In addition, the influence of storage time and the age of ultraviolet lamps on the migration level was examined. The suitability of 50% ethanol as a simulant for yoghurt was also tested. ITX was chosen as a model migrant, as it is easily detectable. Furthermore, the migration of two other substances, the photo-initiator 2-methyl-4'-(methylthio)-2-morpholinopropiophenone (MTMP) and the amine synergist ethyl-4-(dimethylamino)benzoate (EDAB), which may be used in combination with ITX, was studied. Before being filled with yoghurt or 50% ethanol, the printed cups were stored under different contact conditions, with and without contact between the inner layer and the printed surfaces, in order to distinguish between the possible mass transfer ways. All analyses were performed by means of high performance liquid chromatography with diode array and fluorescence detection (HPLC-DAD/FLD). It was shown that contamination with ITX and EDAB occurs via set-off and that the degree of migration increases with lamp age and storage time of the unfilled cups. Migration of MTMP was not detectable. The results show that besides the careful selection of the appropriate raw materials for printing ink, a close monitoring of the process also plays a major role in migration control. In addition, the results proved that 50% ethanol is a suitable simulant for yoghurt. PMID:20432097
NASA Astrophysics Data System (ADS)
Postelnicu, Adrian
2010-10-01
Dufour and Soret effects on flow at a stagnation point in a fluid-saturated porous medium are studied in this paper. A two dimensional stagnation-point flow with suction/injection of a Darcian fluid is considered. By using an appropriate similarity transformation, the boundary layer equations of momentum, energy and concentration are reduced to a set of ordinary differential equations, which are solved numerically using the Keller-box method, which is a very efficient finite differences technique. Nusselt and Sherwood numbers are obtained, together with the velocity, temperature and concentration profiles in the boundary layer. For the large suction case, asymptotic analytical solutions of the problem are obtained, which compare favourably with the numerical solutions. A critical view of the problem is presented finally.
NASA Astrophysics Data System (ADS)
Prasad, V. Ramachandra; Vasu, B.; Bég, O. Anwar; Parshad, Rana D.
2012-02-01
A mathematical model is presented for multiphysical transport of an optically-dense, electrically-conducting fluid along a permeable isothermal sphere embedded in a variable-porosity medium. A constant, static, magnetic field is applied transverse to the cylinder surface. The non-Darcy effects are simulated via second order Forchheimer drag force term in the momentum boundary layer equation. The surface of the sphere is maintained at a constant temperature and concentration and is permeable, i.e. transpiration into and from the boundary layer regime is possible. The boundary layer conservation equations, which are parabolic in nature, are normalized into non-similar form and then solved numerically with the well-tested, efficient, implicit, stable Keller-box finite difference scheme. Increasing porosity ( ɛ) is found to elevate velocities, i.e. accelerate the flow but decrease temperatures, i.e. cool the boundary layer regime. Increasing Forchheimer inertial drag parameter ( Λ) retards the flow considerably but enhances temperatures. Increasing Darcy number accelerates the flow due to a corresponding rise in permeability of the regime and concomitant decrease in Darcian impedance. Thermal radiation is seen to reduce both velocity and temperature in the boundary layer. Local Nusselt number is also found to be enhanced with increasing both porosity and radiation parameters.
NASA Astrophysics Data System (ADS)
Gavrilov, A. V.; Kritskii, V. G.; Rodionov, Yu. A.; Berezina, I. G.
2013-07-01
Certain features of the effect of boric acid in the reactor coolant of nuclear power installations equipped with a VVER-440 reactor on mass transfer in the reactor core are considered. It is determined that formation of boric acid polyborate complexes begins under field conditions at a temperature of 300°C when the boric acid concentration is equal to around 0.065 mol/L (4 g/L). Operations for decontaminating the reactor coolant system entail a growth of corrosion product concentration in the coolant, which gives rise to formation of iron borates in the zones where subcooled boiling of coolant takes place and to the effect of axial offset anomalies. A model for simulating variation of pressure drop in a VVER-440 reactor's core that has invariable parameters during the entire fuel campaign is developed by additionally taking into account the concentrations of boric acid polyborate complexes and the quantity of corrosion products (Fe, Ni) represented by the ratio of their solubilities.
Jozewicz, Wojciech; Rochelle, G.T.
1991-09-17
Novel techniques designed for the enhancement of Ca(OH){sub 2} utilization in dry-sorbent injection (DSI) and duct-spray drying (DSD) were investigated in the Long Time Differential Reactor (LTDR), Short Time Differential Reactor (STDR), and 50-cfm pilot plant. At 2000-ppm SO{sub 2} and 60 percent relative humidity, the presence of up to 30-percent initial free moisture significantly increased sorbent reactivity with SO{sub 2}, compared to sorbent with equilibrium amount of moisture. The conversion decreased when the initial free moisture increased beyond 30--50 percent. The initial free moisture content and corresponding level of maximum sorbent conversion with SO{sub 2} varied with the surface area of the sorbent. Sorbent moisture capacity tests indicated that agglomeration of damp calcium silicate sorbent was a function of sorbent pore volume. Critical moisture content was increasing with specific surface area. Very little improvement in SO{sub 2} removal was obtained by DSI recycle operation downstream of humidification. Significant enhancement was achieved by DSI recycle upstream of humidification. Grinding of DSI solids with and without fly ash resulted in significant increase of surface area and pore volume and resulting reactivity with SO{sub 2}. Organic buffer additives were tested as potential enhancement of Ca(OH){sub 2} utilization during the DSD process. Bench-scale results suggested that organic acids should be effective additives to enhance SO{sub 2} in slurry if SO{sub 2} absorption was controlled significantly by liquid film resistance. Pilot-plant tests did not demonstrate significant enhancement of Ca(OH){sub 2} conversion during spray drying as a result of buffer additives. Grinding of simulated DSD solids resulted in significant enhancement of Ca(OH){sub 2} reactivity with SO{sub 2}.
Solon, Kimberly; Flores-Alsina, Xavier; Gernaey, Krist V; Jeppsson, Ulf
2015-01-01
This paper examines the importance of influent fractionation, kinetic, stoichiometric and mass transfer parameter uncertainties when modeling biogas production in wastewater treatment plants. The anaerobic digestion model no. 1 implemented in the plant-wide context provided by the benchmark simulation model no. 2 is used to quantify the generation of CH₄, H₂and CO₂. A comprehensive global sensitivity analysis based on (i) standardized regression coefficients (SRC) and (ii) Morris' screening's (MS's) elementary effects reveals the set of parameters that influence the biogas production uncertainty the most. This analysis is repeated for (i) different temperature regimes and (ii) different solids retention times (SRTs) in the anaerobic digester. Results show that both SRC and MS are good measures of sensitivity unless the anaerobic digester is operating at low SRT and mesophilic conditions. In the latter situation, and due to the intrinsic nonlinearities of the system, SRC fails in decomposing the variance of the model predictions (R² < 0.7) making MS a more reliable method. At high SRT, influent fractionations are the most influential parameters for predictions of CH₄and CO₂emissions. Nevertheless, when the anaerobic digester volume is decreased (for the same load), the role of acetate degraders gains more importance under mesophilic conditions, while lipids and fatty acid metabolism is more influential under thermophilic conditions. The paper ends with a critical discussion of the results and their implications during model calibration and validation exercises. PMID:25812096
Mounsef, Jihane Rahbani; Salameh, Dominique; Louka, Nicolas; Brandam, Cedric; Lteif, Roger
2015-09-20
The aeration is a key factor for Bacillus thuringiensis growth, sporulation and δ-endotoxins production. The objective of our work was to study the effect of aeration on the fermentation kinetics of Bacillus thuringiensis kurstaki (Btk), cultivated in a cereal milling byproduct (CMB) mono-component medium, in order to improve the δ-endotoxins productivity. Aeration conditions were systematically characterized by the volumetric mass transfer coefficient KLa. In the 6% CMB culture medium, different values of the maximal specific oxygen uptake rate were obtained at different values of KLa. For KLa of 7.2 h(-1), the growth was inhibited and the sporulation was defective. There was a linear increase of the average specific growth rate and faster sporulation and liberation of spores and δ-endotoxins crystals when KLa was increased between 13.3 h(-1) and 65.5 h(-1). Similar kinetic was observed in cultures performed at KLa equal to 65.5 h(-1) and 106.2 h(-1). The highest toxins productivity of 96.1 mg L(-1) (h)-1 was obtained in the 9% CMB culture medium for KLa of 102 h(-1). It was possible to track the evolution of the bacterial cells between vegetative growth, sporulation and liberation of mature spores by following the variation of the CO2 percent in the effluent gas. PMID:26091772
Electron Transfer Dissociation Mass Spectrometry of Hemoglobin on Clinical Samples
NASA Astrophysics Data System (ADS)
Coelho Graça, Didia; Lescuyer, Pierre; Clerici, Lorella; Tsybin, Yury O.; Hartmer, Ralf; Meyer, Markus; Samii, Kaveh; Hochstrasser, Denis F.; Scherl, Alexander
2012-10-01
A mass spectrometry-based assay combining the specificity of selected reaction monitoring and the protein ion activation capabilities of electron transfer dissociation was developed and employed for the rapid identification of hemoglobin variants from whole blood without previous proteolytic cleavage. The analysis was performed in a robust ion trap mass spectrometer operating at nominal mass accuracy and resolution. Subtle differences in globin sequences, resulting with mass shifts of about one Da, can be unambiguously identified. These results suggest that mass spectrometry analysis of entire proteins using electron transfer dissociation can be employed on clinical samples in a workflow compatible with diagnostic applications.
Jozewicz, W.; Rochelle, G.T.
1992-01-29
Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide [Ca(OH){sub 2}] slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)
Modeling heat and mass transfer in catalytic wood gasification
Brown, M.D.; Robertus, R.J.; Baker, E.G.; Mudge, L.K.
1986-03-01
Current research in the gasification of biomass materials includes production of a methanol synthesis gas catalytically. Previous experiments have indicated early deactivation of catalysts due primarily to carbon deposition. This study presents the results of efforts to model the heat and mass transfer within a spherical catalyst pellet using orthogonal collocation. Solutions are presented which predict temperature and concentration distributions and pellet effectiveness factors. These solutions are compared to a thermodynamic equilibrium model to predict regimes of carbon deposition and subsequent deactivation. Experimental data are presented which support conclusions drawn above. 11 refs., 3 figs., 1 tab.
A mass transfer model for VOC emission from silage
NASA Astrophysics Data System (ADS)
Hafner, Sasha D.; Montes, Felipe; Rotz, C. Alan
2012-07-01
Silage has been shown to be an important source of emissions of volatile organic compounds (VOCs), which contribute to the formation of ground-level ozone. Measurements have shown that environmental conditions and silage properties strongly influence emission rates, making it difficult to assess the contribution of silage in VOC emission inventories. In this work, we present an analytical convection-diffusion-dispersion model for predicting emission of VOCs from silage. It was necessary to incorporate empirical relationships from wind tunnel trials for the response of mass transfer parameters to surface air velocity and silage porosity. The resulting model was able to accurately predict the effect of temperature on ethanol emission in wind tunnel trials, but it over-predicted alcohol and aldehyde emission measured using a mass balance approach from corn silage samples outdoors and within barns. Mass balance results confirmed that emission is related to gas-phase porosity, but the response to air speed was not clear, which was contrary to wind tunnel results. Mass balance results indicate that alcohol emission from loose silage on farms may approach 50% of the initial mass over six hours, while relative losses of acetaldehyde will be greater.
The effect of pH on coupled mass transfer and sol-gel reaction in a two-phase system.
Castelijns, H J; Huinink, H P; Pel, L; Zitha, P L J
2007-11-01
The coupled mass transfer and chemical reactions of a gel-forming compound in a two-phase system were recently analyzed in detail [Castelijns et al. J. Appl. Phys. 2006, 100, 024916]. In this successive work, the gel-forming chemical tetramethylorthosilicate (TMOS) was dissolved in a mineral oil and placed together with heavy water (D2O) in small cylinders. The transfer of TMOS from the oleic phase to the aqueous phase was monitored through nuclear magnetic resonance (NMR) relaxation time measurements of hydrogen in the oleic phase. The rate of gelation was measured through NMR relaxation time measurements of deuterium in the aqueous phase. The temperature, the initial concentration of TMOS, and the type of buffer in the aqueous phase were varied in the experiments. The mass transfer is driven by the rate of hydrolysis, which increases with temperature. The hydrolysis rate is the lowest at a neutral pH and is the highest at a low pH. In the aqueous phase, a sharp decrease in the transverse relaxation time (T2) of 2H is observed, which is attributed to the gel reaction. The plateau in T2 indicates the gel transition point. The gel rates increase with increasing temperature and increasing concentration, and are the highest at a neutral pH. PMID:17927235
Probing the Mass-Transfer Stability Limit in Close Binaries
NASA Astrophysics Data System (ADS)
D'Souza, M. C. R.; Motl, P. M.; Tohline, J. E.; Frank, J.
2004-12-01
We present results from numerical simulations that follow the nonlinear development of mass-transfer instabilities in close binary star systems. A self-consistent-field (SCF) technique is used to construct initial equilibrium models, which are synchronously rotating, semi-detached, polytropic stars on circular orbits. These models are evolved with an Eulerian, finite-difference hydrodynamics code in a fully self-consistent manner. Results are presented for binary systems having a wide range of initial conditions; emphasis is placed on systems in which the mass-transfer stream directly impacts the surface of the accreting star. Some systems are dynamically unstable and result in a merger; others approach a long-term, stable phase of mass transfer. The time-evolutionary behavior of the binary separation, mass transfer rate, spin angular momentum of the accretor, and gravitational wave strain are presented.
Impact of kinetic mass transfer on free convection in a porous medium
NASA Astrophysics Data System (ADS)
Lu, Chunhui; Shi, Liangsheng; Chen, Yiming; Xie, Yueqing; Simmons, Craig T.
2016-05-01
We investigate kinetic mass transfer effects on unstable density-driven flow and transport processes by numerical simulations of a modified Elder problem. The first-order dual-domain mass transfer model coupled with a variable-density-flow model is employed to describe transport behavior in porous media. Results show that in comparison to the no-mass-transfer case, a higher degree of instability and more unstable system is developed in the mass transfer case due to the reduced effective porosity and correspondingly a larger Rayleigh number (assuming permeability is independent on the mobile porosity). Given a constant total porosity, the magnitude of capacity ratio (i.e., immobile porosity/mobile porosity) controls the macroscopic plume profile in the mobile domain, while the magnitude of mass transfer timescale (i.e., the reciprocal of the mass transfer rate coefficient) dominates its evolution rate. The magnitude of capacity ratio plays an important role on the mechanism driving the mass flux into the aquifer system. Specifically, for a small capacity ratio, solute loading is dominated by the density-driven transport, while with increasing capacity ratio local mass transfer dominated solute loading may occur at later times. At significantly large times, however, both mechanisms contribute comparably to solute loading. Sherwood Number could be a nonmonotonic function of mass transfer timescale due to complicated interactions of solute between source zone, mobile zone and immobile zone in the top boundary layer, resulting in accordingly a similar behavior of the total mass. The initial assessment provides important insights into unstable density-driven flow and transport in the presence of kinetic mass transfer.
NASA Astrophysics Data System (ADS)
Li, Like; AuYeung, Nick; Mei, Renwei; Klausner, James F.
2016-08-01
We present a systematic study on the effects of tangential-type boundary condition discontinuities on the accuracy of the lattice Boltzmann equation (LBE) method for Dirichlet and Neumann problems in heat and mass transfer modeling. The second-order accurate boundary condition treatments for continuous Dirichlet and Neumann problems are directly implemented for the corresponding discontinuous boundary conditions. Results from three numerical tests, including both straight and curved boundaries, are presented to show the accuracy and order of convergence of the LBE computations. Detailed error assessments are conducted for the interior temperature or concentration (denoted as a scalar ϕ) and the interior derivatives of ϕ for both types of boundary conditions, for the boundary flux in the Dirichlet problem and for the boundary ϕ values in the Neumann problem. When the discontinuity point on the straight boundary is placed at the center of the unit lattice in the Dirichlet problem, it yields only first-order accuracy for the interior distribution of ϕ, first-order accuracy for the boundary flux, and zeroth-order accuracy for the interior derivatives compared with the second-order accuracy of all quantities of interest for continuous boundary conditions. On the lattice scale, the LBE solution for the interior derivatives near the singularity is largely independent of the resolution and correspondingly the local distribution of the absolute errors is almost invariant with the changing resolution. For Neumann problems, when the discontinuity is placed at the lattice center, second-order accuracy is preserved for the interior distribution of ϕ; and a "superlinear" convergence order of 1.5 for the boundary ϕ values and first-order accuracy for the interior derivatives are obtained. For straight boundaries with the discontinuity point arbitrarily placed within the lattice and curved boundaries, the boundary flux becomes zeroth-order accurate for Dirichlet problems
Nonstationary Mass Transfer Near the Surface of a Cylindrical Body
NASA Astrophysics Data System (ADS)
Rudobashta, S. P.; Kosheleva, M. K.; Kartashov, É. M.
2015-11-01
The problem of nonstationary diffusion of the target component to a phase that is external relative to the surface of a cylindrical body has been formulated and solved analytically. From the found solution the dependences have been obtained for calculating the instantaneous mass transfer coefficient and the phase-contact-time mean mass transfer coefficient, on the basis of which the process of extraction of technological pollutants from fibrous materials has been analyzed.
Heat and mass transfer in materials processing
Tanasawa, I. . Inst. of Industrial Science); Lior, N. . Dept. of Mechanical Engineering and Applied Mechanics)
1992-01-01
This book contains forty papers presented at the seminar. The papers are representative of the seminar's scope, and include plasma spraying, laser and electron beam processing, crystal growth, solidification, steel processing, casting and molding, and papermaking, as well as fundamental heat transfer issues and physical properties underlying all of the above. The seminar emphasized thorough discussion of the presentations and of the subfields. Brief summaries of the discussions are presented in the rapporteurs' reports.
Romanini, C E B; Exadaktylos, V; Hong, S W; Tong, Q; McGonnell, I; Demmers, T G M; Bergoug, H; Guinebretière, M; Eterradossi, N; Roulston, N; Verhelst, R; Bahr, C; Berckmans, D
2015-02-01
Thermodynamic study of incubated eggs is an important component in the optimisation of incubation processes. However, research on the interaction of heat and moisture transfer mechanisms in eggs is rather limited and does not focus on the hatching stage of incubation. During hatch, both the recently hatched chick and the broken eggshell add extra heat and moisture contents to the hatcher environment. In this study, we have proposed a novel way to estimate thermodynamically the amount of water evaporated from a broken eggshell during hatch. The hypothesis of this study considers that previously reported drops in eggshell temperature during hatching of chicks is the result remaining water content evaporating from the eggshell, released on the inner membrane by the recently hatched wet chick, just before hatch. To reproduce this process, water was sprayed on eggshells to mimic the water-fluid from the wet body of a chick. For each sample of eggshell, the shell geometry and weight, surface area and eggshell temperature were measured. Water evaporation losses and convection coefficient were calculated using a novel model approach considering the simultaneous heat and mass transfer profiles in an eggshell. The calculated average convective coefficient was 23.9 ± 7.5 W/m(2) °C, similar to previously reported coefficients in literature as a function of 0.5-1m/s air speed range. Comparison between measured and calculated values for the water evaporation showed 68% probability accuracy, associated to the use of an experimentally derived single heat transfer coefficient. The results support our proposed modelling approach of heat and mass transfer mechanisms. Furthermore, by estimating the amount of evaporated water in an eggshell post-hatch, air humidity levels inside the hatcher can be optimised to ensure wet chicks dry properly while not dehydrating early hatching chicks. PMID:25660633
Oscillatory flow through submerged canopies: 2. Canopy mass transfer
NASA Astrophysics Data System (ADS)
Lowe, Ryan J.; Koseff, Jeffrey R.; Monismith, Stephen G.; Falter, James L.
2005-10-01
Mass transfer rates from submerged canopies constructed from arrays of vertical cylinders were investigated for a range of different cylinder spacings under both unidirectional and oscillatory flow. Individual canopy elements made from gypsum were dissolved in fresh water to simulate the mass transfer of dissolved metabolites to and from canopies of living benthic organisms. Mass transfer rates under oscillatory flow were up to three times higher than values measured for a comparable unidirectional current. This enhancement was shown to be a strong function of the canopy element spacing. A model was developed to predict canopy mass transfer rates on the basis of the in-canopy flow speed and was generalized to incorporate either unidirectional or oscillatory flow. Agreement between the modeled and experimentally measured mass transfer rates indicate that enhanced mass transfer to/from living benthic canopies under oscillatory flow is driven primarily by the higher in-canopy water motion generated by the oscillatory flow, as detailed in the companion paper (Lowe et al., 2005).
Mass transfer and transport in a geologic environment
Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.; Ahn, J.; Kajiwara, S.; Kim, C.L.; Kimura, H.; Lung, H.; Williams, W.J.; Zavoshy, S.J.
1985-04-01
This report is in a continuing series of reports that present analytic solutions for the dissolution and hydrogeologic transport of radionuclides from geologic repositories of nuclear waste. Previous reports have dealt mainly with radionuclide transport in the far-field, away from the effects of the repository. In the present report, the emphasis is on near-field processes, the transfer and transport of radionuclides in the vicinity of the waste packages. The primary tool used in these analyses is mass transfer theory from chemical engineering. The thrust of our work is to develop methods for predicting the performance of geologic repositories. The subjects treated in the present report are: radionuclide transport from a spherical-equivalent waste form through a backfill; analysis of radionuclide transport through a backfill using a non-linear sorption isotherm; radionuclide transport from a prolate spheroid-equivalent waste form with a backfill; radionuclide transport from a spherical-equivalent waste form through a backfill, where the solubility, diffusivity and retardation coefficients are temperature dependent; a coupled near-field, far-field analysis where dissolution and migration rates are temperature dependent; transport of radionuclides from a point source in a three-dimensional flow field; and a general solution for the transport of radioactive chains in geologic media. There are several important results from the numerical evaluations. First, radioactive decay, higher sorption in the rock and the backfill steepens the gradient for mass transfer, and lead to higher dissolution rates. This is contrary to what was expected by some other workers, but is shown clearly in the analytical solutions. Second, the backfill serves to provide sorption sites so that there is a delay in the arrival of radionuclides in the rock, although this effect is not so important for the steady-state transport of long-lived radionuclides.
Acoustic Streaming and Heat and Mass Transfer Enhancement
NASA Technical Reports Server (NTRS)
Trinh, E. H.; Gopinath, A.
1996-01-01
A second order effect associated with high intensity sound field, acoustic streaming has been historically investigated to gain a fundamental understanding of its controlling mechanisms and to apply it to practical aspects of heat and mass transfer enhancement. The objectives of this new research project are to utilize a unique experimental technique implementing ultrasonic standing waves in closed cavities to study the details of the generation of the steady-state convective streaming flows and of their interaction with the boundary of ultrasonically levitated near-spherical solid objects. The goals are to further extend the existing theoretical studies of streaming flows and sample interactions to higher streaming Reynolds number values, for larger sample size relative to the wavelength, and for a Prandtl and Nusselt numbers parameter range characteristic of both gaseous and liquid host media. Experimental studies will be conducted in support to the theoretical developments, and the crucial impact of microgravity will be to allow the neglect of natural thermal buoyancy. The direct application to heat and mass transfer in the absence of gravity will be emphasized in order to investigate a space-based experiment, but both existing and novel ground-based scientific and technological relevance will also be pursued.
Pattern formation and mass transfer under stationary solutal Marangoni instability.
Schwarzenberger, Karin; Köllner, Thomas; Linde, Hartmut; Boeck, Thomas; Odenbach, Stefan; Eckert, Kerstin
2014-04-01
According to the seminal theory by Sternling and Scriven, solutal Marangoni convection during mass transfer of surface-active solutes may occur as either oscillatory or stationary instability. With strong support of Manuel G. Velarde, a combined initiative of experimental works, in particular to mention those of Linde, Wierschem and coworkers, and theory has enabled a classification of dominant wave types of the oscillatory mode and their interactions. In this way a rather comprehensive understanding of the nonlinear evolution of the oscillatory instability could be achieved. A comparably advanced state-of-the-art with respect to the stationary counterpart seemed to be out of reach a short time ago. Recent developments on both the numerical and experimental side, in combination with assessing an extensive number of older experiments, now allow one to draw a more unified picture. By reviewing these works, we show that three main building blocks exist during the nonlinear evolution: roll cells, relaxation oscillations and relaxation oscillations waves. What is frequently called interfacial turbulence results from the interaction between these partly coexisting basic patterns which may additionally occur in different hierarchy levels. The second focus of this review lies on the practical importance of such convection patterns concerning their influence on mass transfer characteristics. Particular attention is paid here to the interaction between Marangoni and buoyancy effects which frequently complicates the pattern formation even more. To shed more light on these dependencies, new simulations regarding the limiting case of stabilizing density stratification and vanishing buoyancy are incorporated. PMID:24456800
Mass transfer between debris discs during close stellar encounters
NASA Astrophysics Data System (ADS)
Jílková, Lucie; Hamers, Adrian S.; Hammer, Michael; Portegies Zwart, Simon
2016-04-01
We study mass transfers between debris discs during stellar encounters. We carried out numerical simulations of close flybys of two stars, one of which has a disc of planetesimals represented by test particles. We explored the parameter space of the encounters, varying the mass ratio of the two stars, their pericentre and eccentricity of the encounter, and its geometry. We find that particles are transferred to the other star from a restricted radial range in the disc and the limiting radii of this transfer region depend on the parameters of the encounter. We derive an approximate analytic description of the inner radius of the region. The efficiency of the mass transfer generally decreases with increasing encounter pericentre and increasing mass of the star initially possessing the disc. Depending on the parameters of the encounter, the transfer particles have a specific distribution in the space of orbital elements (semimajor axis, eccentricity, inclination, and argument of pericentre) around their new host star. The population of the transferred particles can be used to constrain the encounter through which it was delivered. We expect that many stars experienced transfer among their debris discs and planetary systems in their birth environment. This mechanism presents a formation channel for objects on wide orbits of arbitrary inclinations, typically having high eccentricity but possibly also close to circular (eccentricities of about 0.1). Depending on the geometry, such orbital elements can be distinct from those of the objects formed around the star.
Overall Heat and Mass Transfer Coefficient of Water Vapor Adsorption
NASA Astrophysics Data System (ADS)
Hamamoto, Yoshinori; Mori, Hideo; Godo, Masazumi; Miura, Kunio; Watanabe, Yutaka; Ishizawa, Toshihiko; Takatsuka, Takeshi
A fundamental investigation was performed to develop a compact and simple desiccant ventilation unit which is one of the main components of a novel energy saving air-conditioning system. Water vapor in the air is adsorbed and/or desorbed to be controlled the humidity of supply air through a unit of an adsorbent packed bed. A numerical simulation helps to understand the phenomena of heat and mass transfer in the bed. Overall transfer coefficients of them as properties for the simulation were estimated by performing both experiment and calculation. It was clarified that the transient overall equivalent heat and mass transfer does not strongly depend on the air flow rate through the packed bed, the averaged equivalent mass transfer is governed by surface and pore diffusion in a particle of adsorbent at low flow rate. Moreover, the coefficient during the adsorption process is slightly larger than desorption. An equation of the overall mass transfer coefficient is derived. It shows five times as large as the value estimated by experiment. Therefore, the correlation and fitting parameters are presented for prediction of the overall heat and mass transfer coefficients. The estimation accuracy was improved.
NASA Astrophysics Data System (ADS)
Othmani, Hammouda; Hassini, Lamine; Lamloumi, Raja; El Cafsi, Mohamed Afif
2016-02-01
A comprehensive internal heat and water transfer model including the gas pressure effect has been proposed in order to improve the industrial high-temperature air drying of inserts made of agglomerated sand. In this model, the internal gas phase pressure effect was made perfectly explicit, by considering the liquid and vapour transfer by filtration and the liquid expulsion at the surface. Wet sand enclosed in a tight cylindrical glass bottle dried convectively at a high temperature was chosen as an application case. The model was validated on the basis of the experimental average water content and core temperature curves for drying trials at different operating conditions. The simulations of the spatio-temporal distribution of internal gas pressure were performed and interpreted in terms of product potential damage. Based on a compromise between the drying time and the pressure increase, a simple drying cycle was implemented in order to optimize the drying process.
Zhao, C.; Muehlaus, H.B.; Hobbs, B.E.
1998-03-01
A parametric study is carried out to investigate how geological inhomogeneity affects the pore-fluid convective flow field, the temperature distribution, and the mass concentration distribution in a fluid-saturated porous medium. The related numerical results have demonstrated that (1) the effects of both medium permeability inhomogeneity and medium thermal conductivity inhomogeneity are significant on the pore-fluid convective flow and the species concentration distribution in the porous medium; (2) the effect of medium thermal conductivity inhomogeneity is dramatic on the temperature distribution in the porous medium, but the effect of medium permeability inhomogeneity on the temperature distribution may be considerable, depending on the Rayleigh number involved in the analysis; (3) if the coupling effect between pore-fluid flow and mass transport is weak, the effect of the Lewis number is negligible on the pore-fluid convective flow and temperature distribution, but it is significant on the species concentration distribution in the medium.
Calculation of Post-Closure Natural Convection Heat and Mass Transfer in Yucca Mountain Drifts
S. Webb; M. Itamura
2004-03-16
Natural convection heat and mass transfer under post-closure conditions has been calculated for Yucca Mountain drifts using the computational fluid dynamics (CFD) code FLUENT. Calculations have been performed for 300, 1000, 3000, and 10,000 years after repository closure. Effective dispersion coefficients that can be used to calculate mass transfer in the drift have been evaluated as a function of time and boundary temperature tilt.
Bell, J H; Hand, L A
2005-04-21
The growth rate of a crystal in a supersaturated solution is limited by both reaction kinetics and the local concentration of solute. If the local mass transfer coefficient is too low, concentration of solute at the crystal-solution interface will drop below saturation, leading to a defect in the growing crystal. Here, mass transfer coefficients are calculated for a rotating crystal growing in a supersaturated solution of potassium diphosphate (KDP) in water. Since mass transfer is difficult to measure directly, the heat transfer coefficient of a scale model crystal in water is measured using temperature-sensitive paint (TSP). To the authors' knowledge this is the first use of TSP to measure temperatures in water. The corresponding mass transfer coefficient is then calculated using the Chilton- Colburn analogy. Measurements were made for three crystal sizes at two running conditions each. Running conditions include periodic reversals of rotation direction. Heat transfer coefficients were found to vary significantly both across the crystal faces and over the course of a rotation cycle, but not from one face to another. Mean heat transfer coefficients increased with both crystal size and rotation rate. Computed mass transfer coefficients were broadly in line with expectations from the full-scale crystal growth experiments. Additional experiments show that continuous rotation of the crystal results in about a 30% lower heat transfer compared to rotation with periodic reversals. The continuous rotation case also shows a periodic variation in heat transfer coefficient of about 15%, with a period about 1/20th of the rotation rate.
Heat and mass transfer over slippery, superhydrophobic surfaces
NASA Astrophysics Data System (ADS)
Haase, A. Sander; Lammertink, Rob G. H.
2016-04-01
The classical Graetz-Nusselt problem is extended to describe heat and mass transfer over heterogeneously slippery, superhydrophobic surfaces. The cylindrical wall consists of segments with a constant temperature/concentration and areas that are insulating/impermeable. Only in the case of mass transport do the locations of hydrodynamic slip and mass exchange coincide. This makes advection near the mass exchanging wall segments larger than near the heat exchanging regions. Also the direction of radial fluid flow is reversed for heat and mass transport, which has an influence on the location where the concentration or temperature boundary layer is compressed or extended. As a result, mass transport is more efficient than heat transfer. Also the influence of axial diffusion on the Nusselt and Sherwood numbers is investigated for various Péclet numbers Pe. When Pe < 102, which is characteristic for heat transfer over superhydrophobic surfaces, axial conduction should be taken into account. For Pe ≥ 102, which are typical numbers for mass transport in microfluidic systems, axial diffusion can be neglected.
Mass transfer apparatus and method for separation of gases
Blount, Gerald C.
2015-10-13
A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.
A multiscale modeling study for the convective mass transfer in a subsurface aquifer
NASA Astrophysics Data System (ADS)
Alam, Jahrul M.
2015-09-01
Quantitative and realistic computer simulations of mass transfer associated with disposal in subsurface aquifers is a challenging endeavor. This article has proposed a novel and efficient multiscale modeling framework, and has examined its potential to study the penetrative mass transfer in a plume that migrates in an aquifer. Numerical simulations indicate that the migration of the injected enhances the vorticity generation, and the dissolution of has a strong effect on the natural convection mass transfer. The vorticity decays with the increase of the porosity. The time scale of the vertical migration of a plume is strongly dependent on the rate of dissolution. Comparisons confirm the near optimal performance of the proposed multiscale model. These primary results with an idealized computational model of the migration in an aquifer brings the potential of the proposed multiscale model to the field of heat and mass transfer in the geoscience.
Finite Element Heat & Mass Transfer Code
Energy Science and Technology Software Center (ESTSC)
1996-10-10
FEHM is a numerical simulation code for subsurface transport processes. It models 3-D, time-dependent, multiphase, multicomponent, non-isothermal, reactive flow through porous and fractured media. It can accurately represent complex 3-D geologic media and structures and their effects on subsurface flow and transport. Its capabilities include flow of gas, water, and heat; flow of air, water, and heat; multiple chemically reactive and sorbing tracers; finite element/finite volume formulation; coupled stress module; saturated and unsaturated media; andmore » double porosity and double porosity/double permeability capabilities.« less
Simultaneous heat and mass transfer from a two-dimensional, partially liquid-covered surface
Tao, Y.X.; Kaviany, M. )
1991-11-01
Simultaneous heat and mass transfer from partially liquid-covered surfaces is examined experimentally using a surface made of cylinders with the voids filled with liquid. The steady-state evaporation rate, surface temperature of the liquid and exposed solid, and location of meniscus are measured for various ambient air velocities and temperatures. Using these, the authors examine the effect of the extent to which the liquid covers the surface on the evaporation mass transfer rate resulting from the convective heat transfer from the ambient gas to this surface. The results show strong Bond and Reynolds number effects. For small Bond and Reynolds numbers, the presence of dry (exposed solid) surface does not influence the mass transfer rate. As the Bond or Reynolds number increases, a critical liquid coverage is found below which the mass transfer begins to decrease. Heat transfer from the exposed solid to the liquid is also examined using the measured surface temperature, a conduction model, and an estimate of the liquid and solid surface areas (using a static formation for the liquid meniscus). The results show that at the liquid surface an analogy between heat and mass transfer does not exist.
Combined heat and mass transfer in absorption processes
Grossman, G.
1982-01-01
The approach to theoretical analysis of the combined heat and mass transfer process taking place in absorption systems is described. The two tranfer phenomena are strongly coupled here. The purpose of the analysis is to relate, quantitatively, the heat and mass transfer coefficients to the physical properties of the working fluids and to the geometry of the system. The preferred configuration is that of a falling film of liquid on a metallic surface which serves to transfer heat from the absorbent in contact with the vapor of the absorbate. The model developed may be solved for laminar, turbulent, or transition flow regimes. The results of the solution describe the development of the thermal and concentration boundary layers and the variation of the temperatures, concentrations, and heat and mass fluxes. These quantities in their normalized, dimensionless form depend on two characteristic parameters of the system: the Lewis number Le and the dimensionless heat of absorption lambda. The length in the direction of flow is normalized with respect to the Peclet number and the film thickness. Heat and mass transfer coefficients for the system were calculated. The Sherwood number for mass transfer from the vapor-liquid interface to the bulk of the film reaches a constant value of 3.63 with fully developed boundary layers for both the adiabatic and constant temperature wall. The Nusselt number for heat transfer from the interface to the bulk reaches under the same conditions values of 3.63 and 2.67 for the adiabatic and constant temperature wall, respectively. The Nusselt number for heat tranfer from the bulk to the wall reaches 1.60.
TWIN BINARIES: STUDIES OF STABILITY, MASS TRANSFER, AND COALESCENCE
Lombardi, J. C.; Holtzman, W.; Gearity, K.; Dooley, K. L.; Kalogera, V.; Rasio, F. A.
2011-08-20
Motivated by suggestions that binaries with almost equal-mass components ('twins') play an important role in the formation of double neutron stars and may be rather abundant among binaries, we study the stability of synchronized close and contact binaries with identical components in circular orbits. In particular, we investigate the dependency of the innermost stable circular orbit on the core mass, and we study the coalescence of the binary that occurs at smaller separations. For twin binaries composed of convective main-sequence stars, subgiants, or giants with low-mass cores (M{sub c} {approx}< 0.15M, where M is the mass of a component), a secular instability is reached during the contact phase, accompanied by a dynamical mass transfer instability at the same or at a slightly smaller orbital separation. Binaries that come inside this instability limit transfer mass gradually from one component to the other and then coalesce quickly as mass is lost through the outer Lagrangian points. For twin giant binaries with moderate to massive cores (M{sub c} {approx}> 0.15M), we find that stable contact configurations exist at all separations down to the Roche limit, when mass shedding through the outer Lagrangian points triggers a coalescence of the envelopes and leaves the cores orbiting in a central tight binary. In addition to the formation of binary neutron stars, we also discuss the implications of our results for the production of planetary nebulae with double degenerate central binaries.
Chemical mass transfer in magmatic processes
NASA Astrophysics Data System (ADS)
Ghiorso, Mark S.
1987-07-01
Lasaga's (1982) Master Equation for crystal growth is solved for multicomponent systems in situations which allow for coupled diffusion of melt species. The structure of the solution is explored in some detail for the case of a constant diffusion coefficient matrix. Incorporating these results, the growth of plagioclase is modeled in undercooled tholeiitic melts by approximating interface growth rates with (1) a reduced growth rate function and with (2) calculated solid-liquid solution properties obtained from the silicate liquid solution model of Ghiorso et al. (1983; appendix of Ghiorso 1985). For this purpose algorithms are provided for estimating the liquidus temperature or the chemical affinity of a multicomponent solid solution precipitating from a complex melt of specified bulk composition. Compositional trends in initial solids produced by successive degrees of undercooling are opposite to those predicted in the binary system NaAlSi3O8-CaAl2Si2O8. Calculations suggest that the solid phase and interface melt compositions rapidly approach a “steady state” for a given degree of undercooling. Consequently, the overall isothermal growth rate of plagioclase forming from tholeiitic melts appears to be entirely diffusion controlled. In magmatic systems the multicomponent growth equations allow for the formation of oscillatory zoned crystals as a consequence of the “couplingr” between interface reaction kinetics and melt diffusion. The magnitude of this effect is largely dependent upon the asymmetry of the diffusion coefficient matrix. Methods are described to facilitate the calibration of diffusion matrices from experimental data on multicomponent penetration curves. Experimental results (Lesher and Walker 1986) on steady state Soret concentration profiles resulting from thermal diffusion in MORB and andesitic liquids are analyzed using the theory of multicomponent linear irreversible thermodynamics. Under conditions where the entropy production is
Ali, Farhad; Khan, Ilyas; Samiulhaq; Shafie, Sharidan
2013-01-01
The aim of this study is to present an exact analysis of combined effects of radiation and chemical reaction on the magnetohydrodynamic (MHD) free convection flow of an electrically conducting incompressible viscous fluid over an inclined plate embedded in a porous medium. The impulsively started plate with variable temperature and mass diffusion is considered. The dimensionless momentum equation coupled with the energy and mass diffusion equations are analytically solved using the Laplace transform method. Expressions for velocity, temperature and concentration fields are obtained. They satisfy all imposed initial and boundary conditions and can be reduced, as special cases, to some known solutions from the literature. Expressions for skin friction, Nusselt number and Sherwood number are also obtained. Finally, the effects of pertinent parameters on velocity, temperature and concentration profiles are graphically displayed whereas the variations in skin friction, Nusselt number and Sherwood number are shown through tables. PMID:23840321
Numerical Simulation of Heat and Mass Transfer in an Ejection Apparatus
NASA Astrophysics Data System (ADS)
Kologrivov, M. M.; Buzovskii, V. P.
2016-01-01
The results of numerical simulation of heat and mass transfer in an ejection apparatus during condensation of vapor-gas mixture components on cold brine droplets are presented. The local parameters of working flows were determined by solving a system of differential heat transfer equations with account for the hydrodynamic pattern. Calculations were carried out on the assumption that the liquid spray is directed horizontally. The Stefan formula has been derived with reference to a spherical coordinate system. The results of calculation of heat and mass transfer rates with and without regard for steam condensation jointly with hydrocarbon vapors are compared and analyzed. Estimation of the effect exerted by the apparatus and drip pan walls on the general process of heat and mass transfer was carried out. The results of simulation made it possible to quantitatively estimate the influence of the adopted thickness of the diffusional boundary layer on the vapor-air mixture cooling effect.
Stability of coaxial jets confined in a tube with heat and mass transfer
NASA Astrophysics Data System (ADS)
Mohanta, Lokanath; Cheung, Fan-Bill; Bajorek, Stephen M.
2016-02-01
A linear temporal stability of coaxial confined jets in a vertical tube involving heat and mass transfer at the interface is presented in this paper. A potential flow analysis that includes the effect of viscosity at the interface is performed in analyzing the stability of the system. Film boiling in a vertical tube gives rise to the flow configuration explored in this work. The effects of various non-dimensional parameters on the growth rate and the neutral curve are discussed. The heat transfer at the interface has been characterized by introducing a heat flux ratio between the conduction heat flux and the evaporation heat flux. Viscous forces and the heat and mass transfer at the interface are found to stabilize the flow both in the capillary instability region and Kelvin-Helmholtz instability region. Increasing heat and mass transfer at the interface stabilizes the flow to small as well as very large wave numbers.
Twisted mass finite volume effects
Colangelo, Gilberto; Wenger, Urs; Wu, Jackson M. S.
2010-08-01
We calculate finite-volume effects on the pion masses and decay constant in twisted mass lattice QCD at finite lattice spacing. We show that the lighter neutral pion in twisted mass lattice QCD gives rise to finite-volume effects that are exponentially enhanced when compared to those arising from the heavier charged pions. We demonstrate that the recent two flavor twisted mass lattice data can be better fitted when twisted mass effects in finite-volume corrections are taken into account.
Evaporation from flowing channels ( mass-transfer formulas).
Fulford, J.M.; Sturm, T.W.
1984-01-01
Stability-dependent and Dalton-type mass transfer formulas are determined from experimental evaporation data in ambient and heated channels and are shown to have similar performance in prediction of evaporation. The formulas developed are compared with those proposed by other investigators for lakes and flowing channels. -from ASCE Publications Information
Analysis of Heat and Mass Transfer in a Desiccant Rotor
NASA Astrophysics Data System (ADS)
Hamamoto, Yoshinori; Murase, Sousuke; Akisawa, Atsushi; Kashiwagi, Takao; Okajima, Jirou; Matsuoka, Fumio
The study aims at clarifying the local heat and mass transfer in the desiccant rotor, and at obtaining the design aspects of high efficient desiccant rotor and operation method. In the paper, theoretical analysis is performed for rotary dehumidifier. Both surface diffusion and mass transfer coefficient are considered in the model. It is examined that the results of calculation agree well with the experimental data. The local temperature, humidity and the amount of adsorbed water vapor are calculated. It is clarified that temperature and humidity of air in the rotor change clockwise between each inlet air condition on the psychrometric chart. The outlet temperature and humidity distribution of the rotor is clarified in the system showing the optimum rotor speed. Furthermore, it is clarified that local desorption rate is higher than adsorption rate. It is attributed to the increase of mass transfer coefficient and surface diffusivity of the rotor during desorption process. And, it is clarified that the influence of surface diffusion on amount of adsorbed water vapor is much larger than that of mass transfer coefficient.
Dissociation and Mass Transfer Coefficients for Ammonia Volatilization Models
Technology Transfer Automated Retrieval System (TEKTRAN)
Process-based models are being used to predict ammonia emissions from manure sources, but their accuracy has not been fully evaluated for cattle manure. Laboratory trials were conducted to measure the dissociation and mass transfer coefficients for ammonia volatilization from media of buffered ammon...
FUNDAMENTAL MASS TRANSFER MODELS FOR INDOOR AIR POLLUTION SOURCES
The paper discusses a simple, fundamental mass transfer model, based on Fick's Law of Diffusion, for indoor air pollution wet sorbent-based sources. (Note: Models are needed to predict emissions from indoor sources. hile empirical approaches based on dynamic chamber data are usef...
Interphase mass transfer between fluids in subsurface formations: A review
NASA Astrophysics Data System (ADS)
Agaoglu, Berken; Copty, Nadim K.; Scheytt, Traugott; Hinkelmann, Reinhard
2015-05-01
This paper presents a review of the state-of-the-art on interphase mass transfer between immiscible fluids in porous media with focus on the factors that have significant influence on this process. In total close to 300 papers were reviewed focusing to a large extent on the literature relating to NAPL contamination of the subsurface. The large body of work available on this topic was organized according to the length scale of the conducted studies, namely the pore, meso and field scales. The interrelation of interphase mass transfer at these different scales is highlighted. To gain further insight into interphase mass transfer, published studies were discussed and evaluated in terms of the governing flow configurations defined in terms of the wettability and mobility of the different phases. Such organization of the existing literature enables the identification of the interfacial domains that would have significant impact on interphase mass transfer. Available modeling approaches at the various length scales are discussed with regard to current knowledge on the physics of this process. Future research directions are also suggested.
A Course in Advanced Topics in Heat and Mass Transfer.
ERIC Educational Resources Information Center
Shaeiwitz, Joseph A.
1983-01-01
A three or four semester-hour graduate course was designed to provide basic instruction in heat/mass transfer topics relevant to chemical engineering problems and to train students to develop mathematical descriptions for new situations encountered in problem-solving. Course outline and list of references used in the course are provided. (JM)
NASA Astrophysics Data System (ADS)
Boroumand, Ali; Abriola, Linda M.
2015-02-01
Analysis of partitioning tracer tests conducted in dense nonaqueous phase liquid (DNAPL) source zones relies on conceptual models that describe mass exchange between the DNAPL and aqueous phases. Such analysis, however, is complicated by the complex distribution of entrapped DNAPL mass and formation heterogeneity. Due to parameter uncertainty in heterogeneous regions and the desire to reduce model complexity, the effect of mass transfer limitations is often neglected, and an equilibrium-based model is typically used to interpret test results. This work explores the consequences of that simplifying assumption on test data interpretation and develops an alternative upscaled modeling approach to quantify effective mass transfer rates. To this end, a series of partitioning tracer tests is numerically simulated in heterogeneous two-dimensional PCE-DNAPL source zones, representative of a range of hydraulic conductivity and DNAPL mass distribution characteristics. The effective mass transfer coefficient corresponding to each test is determined by fitting an upscaled model to the simulated data, and regression analysis is performed to explore the correlation between various source zone metrics and the effective mass transfer coefficient. Results suggest that vertical DNAPL spreading, Reynolds number, pool fraction, and the effective organic phase saturation are the most significant parameters controlling tracer partitioning rates. Finally, a correlation for prediction of the effective (upscaled) mass transfer coefficient is proposed and verified using existing experimental data. The developed upscaled model incorporates the influence of physical heterogeneity on the rate of tracer partitioning and, thus, can be used for the estimation of source zone mass distribution characteristics from tracer test results.
NASA Astrophysics Data System (ADS)
Hayat, T.; Farooq, S.; Alsaedi, A.; Ahmad, B.
2016-08-01
The purpose of present investigation is to study the Hall and MHD effects on peristaltic flow of Carreau-Yasuda fluid in a convectively curved configuration. Thermal radiation, Soret and Dufour effects are also accounted. The channel walls comprised the no slip and compliant properties. Constitutive equations for mass, momentum, energy and concentration are first modeled in view of considered assumptions and then simplified under long wavelength and low Reynolds number approximation. Solution of the resulting system of equations is carried out via a regular perturbation technique. Physical behaviors of velocity, temperature, concentration and streamlines are discussed with the help of graphical representation.
Mass and heat transfer model of Tubular Solar Still
Ahsan, Amimul; Fukuhara, Teruyuki
2010-07-15
In this paper, a new mass and heat transfer model of a Tubular Solar Still (TSS) was proposed incorporating various mass and heat transfer coefficients taking account of the humid air properties inside the still. The heat balance of the humid air and the mass balance of the water vapor in the humid air were formulized for the first time. As a result, the proposed model enabled to calculate the diurnal variations of the temperature, water vapor density and relative humidity of the humid air, and to predict the hourly condensation flux besides the temperatures of the water, cover and trough, and the hourly evaporation flux. The validity of the proposed model was verified using the field experimental results carried out in Fukui, Japan and Muscat, Oman in 2008. The diurnal variations of the calculated temperatures and water vapor densities had a good agreement with the observed ones. Furthermore, the proposed model can predict the daily and hourly production flux precisely. (author)
Jozewicz, W.; Rochelle, G.T.
1992-01-29
This report presents the results of fundamental mass transfer testing for in-duct removal of SO{sub 2}. Following this initial part of an experimental program, it became clear that the amount of initial moisture on the sorbent strongly affected the extent of Ca(OH){sub 2} conversion. Novel techniques aimed at increasing sorbent utilization were investigated and are described. Major novel technique investigated and reported on here was the reaction with SO{sub 2} of sorbents with initial free moisture (damp sorbents). The duct injection process using damp solids has the following steps: preparation of sorbent as a slurry, blending of the slurry with dry recycle materials to create damp solids, injection of the solids into the duct, reaction and drying of the solids with flue gas in the duct, collection in particulate control equipment, and finally recycle of dry solids with some bleed to disposal. The moisture content of the solids at each step affects system performance. Various factors favor high moisture whereas others favor low moisture. (VC)
Mass transfer kinetics during osmotic dehydration of pomegranate arils.
Mundada, Manoj; Hathan, Bahadur Singh; Maske, Swati
2011-01-01
The mass transfer kinetics during osmotic dehydration of pomegranate arils in osmotic solution of sucrose was studied to increase palatability and shelf life of arils. The freezing of the whole pomegranate at -18 °C was carried out prior to osmotic dehydration to increase the permeability of the outer cellular layer of the arils. The osmotic solution concentrations used were 40, 50, 60°Bx, osmotic solution temperatures were 35, 45, 55 °C. The fruit to solution ratio was kept 1:4 (w/w) during all the experiments and the process duration varied from 0 to 240 min. Azuara model and Peleg model were the best fitted as compared to other models for water loss and solute gain of pomegranate arils, respectively. Generalized Exponential Model had an excellent fit for water loss ratio and solute gain ratio of pomegranate arils. Effective moisture diffusivity of water as well as solute was estimated using the analytical solution of Fick's law of diffusion. For above conditions of osmotic dehydration, average effective diffusivity of water loss and solute gain varied from 2.718 × 10(-10) to 5.124 × 10(-10) m(2)/s and 1.471 × 10(-10) to 5.147 × 10(-10) m(2)/s, respectively. The final product was successfully utilized in some nutritional formulations such as ice cream and bakery products. PMID:21535673
Overall Heat and Mass Transfer Coefficient of Water Vapor Adsorption
NASA Astrophysics Data System (ADS)
Hamamoto, Yoshinori; Mori, Hideo; Godo, Masazumi; Miura, Kunio; Watanabe, Yutaka; Ishizawa, Toshihiko; Takatsuka, Takeshi
A fundamental investigation was performed to develop a compact and simple desiccant ventilation unit which is one of the main components of a novel energy saving air-conditioning system. Water vapor in the air is adsorbed and/or desorbed to be controlled the humidity of supply air through a unit of an adsorbent rotor. A numerical simulation helps to understand the phenomena of heat and mass transfer in the rotor block. Overall transfer coefficients were estimated by performing both experiment and calculation. It was examined that the transient overall equivalent heat and mass transfer coefficient was not constant. It seems that both film fluid and diffusion resistance govern the coefficients in the block, and the influence of air flow on the time averaged coefficients is estimated by a considering the laminar forced convection from a flat plate. There is little difference of the coefficient between adsorption and desorption process. The correlation and fitting parameters are presented for prediction of the overall heat and mass transfer coefficients. The estimation accuracy was improved.
Simplified Simulation of Mass Transfer in Double White Dwarf Systems
NASA Astrophysics Data System (ADS)
Vannah, Sara; Frank, Juhan
2016-01-01
The behavior both stable and unstable mass transfer in semi-detached double white dwarfs triggers a cornucopia of astrophysical phenomena including Type Ia supernovae and AM CVn stars. Current 3D hydrodynamic simulations of the evolution these systems following the mass transfer, binary orbital parameters, and the self-consistent gravitational field over several tens of orbital periods have produced a wealth of data. However, these simulations can take weeks to months in high-performance computing platforms to execute. To help with the interpretation of results of such large scale simulations, and to enable a quick exploration of binary parameter space, we have developed a Mathematica code that integrates forward in time a system of 5 ODEs describing the orbit-averaged evolution of the binary separation as well as the radius, mass, and spin angular momentum of both components of the binary. By adjusting a few parameters describing the mass transfer as a function of the Roche-lobe overflow and the strength of the tidal coupling between the orbit and component spins we are able to obtain approximate fits to previously run hydrodynamic simulations. This simplified simulation is able to run simulations similar to the hydrodynamic versions in a matter of seconds on a dual-core PC or Mac computer.
Evaporative Mass Transfer Behavior of a Complex Immiscible Liquid
McColl, Colleen M.; Johnson, Gwynn R.; Brusseau, Mark L.
2010-01-01
A series of laboratory experiments was conducted with a multiple-component immiscible liquid, collected from the Picillo Farm Superfund Site in Rhode Island, to examine liquid-vapor mass-transfer behavior. The immiscible liquid, which comprises solvents, oils, pesticides, PCBs, paint sludges, explosives, and other compounds, was characterized using gas chromatography and gas chromatography/mass spectrometry to determine mole fractions of selected constituents. Batch experiments were conducted to evaluate equilibrium phase-partitioning behavior. Two sets of air-stripping column studies were conducted to examine the mass-transfer dynamics of five selected target compounds present in the immiscible-liquid mixture. One set of column experiments was designed to represent a system with free-phase immiscible liquid present; the other was designed to represent a system with a residual phase of immiscible liquid. Initial elution behavior of all target components generally appeared to be ideal for both systems, as the initial vapor-phase concentrations were similar to vapor-phase concentrations measured for the batch experiment and those estimated using Raoult’s law (incorporating the immiscible-liquid composition data). Later-stage removal of 1,2-dichlorobenzene appeared to be rate limited for the columns containing free-phase immiscible liquid and no porous medium. Conversely, evaporative mass transfer appeared to be ideal throughout the experiment conducted with immiscible liquid distributed relatively uniformly as a residual phase within a sandy porous medium. PMID:18614196
Heat and mass transfer in multi-porous cavity
Saghir, M.Z.
1998-10-01
The study of heat and mass transfer in porous media has a large number of applications in the areas of environmental geothermal and petroleum engineering. Problems such as the disposal of waste material and groundwater contamination are only few applications of the present work. When heat and species transfer takes place within a fluid layer, the temperature and concentration gradients create a convection mode. This phenomenon is called double-diffusive convection. In this paper, two-dimensional non-linear double diffusive convection in a multiporous cavity is considered. The Darcy equation, including Brinkman term to account for the viscous effects, is used as the momentum equation. The model consists of two rectangular cavities filled with glass beads having a diameter d{sub 1} of either 5.25 mm (Case 1) or 3.25 mm (Case 2). The smaller cavity is located at the top left corner of the larger one. The larger cavity is filled initially with hot salty fluid while the smaller one contains initially cold fresh fluid. At the initial time, the obstacle between the two cavities was released and the double diffusive phenomena were studied in details. The momentum, solutal, energy and continuity equations are solved numerically using the finite element technique. This transient problem is solved for two different Darcy numbers. For each Darcy number, the influence of the solutal Rayleigh number on double diffusive convection was studied in details. The permeability in the horizontal and vertical direction was assumed identical. A comparison of the intruding force between this case and the open flow case studied by Saghir et al. showed that it is inversely proportional to the Darcy number. Finite element modeling results indicate that salinity induces stronger convection than the thermal ones.
Mass Transfer Limited Enhanced Bioremediation at Dnapl Source Zones: a Numerical Study
NASA Astrophysics Data System (ADS)
Kokkinaki, A.; Sleep, B. E.
2011-12-01
The success of enhanced bioremediation of dense non-aqueous phase liquids (DNAPLs) relies on accelerating contaminant mass transfer from the organic to the aqueous phase, thus enhancing the depletion of DNAPL source zones compared to natural dissolution. This is achieved by promoting biological activity that reduces the contaminant's aqueous phase concentration. Although laboratory studies have demonstrated that high reaction rates are attainable by specialized microbial cultures in DNAPL source zones, field applications of the technology report lower reaction rates and prolonged remediation times. One possible explanation for this phenomenon is that the reaction rates are limited by the rate at which the contaminant partitions from the DNAPL to the aqueous phase. In such cases, slow mass transfer to the aqueous phase reduces the bioavailability of the contaminant and consequently decreases the potential source zone depletion enhancement. In this work, the effect of rate limited mass transfer on bio-enhanced dissolution of DNAPL chlorinated ethenes is investigated through a numerical study. A multi-phase, multi-component groundwater transport model is employed to simulate DNAPL mass depletion for a range of source zone scenarios. Rate limited mass transfer is modeled by a linear driving force model, employing a thermodynamic approach for the calculation of the DNAPL - water interfacial area. Metabolic reductive dechlorination is modeled by Monod kinetics, considering microbial growth and self-inhibition. The model was utilized to identify conditions in which mass transfer, rather than reaction, is the limiting process, as indicated by the bioavailability number. In such cases, reaction is slower than expected, and further increase in the reaction rate does not enhance mass depletion. Mass transfer rate limitations were shown to affect both dechlorination and microbial growth kinetics. The complex dynamics between mass transfer, DNAPL transport and distribution, and
Fundamental mass transfer model for indoor air emissions from surface coatings
Tichenor, B.A.; Guo, Z.; Sparks, L.E.
1994-01-01
The paper discusses the work of researchers at the U.S. EPA's Air and Energy Engineering Research Laboratory (Indoor Air Branch) who are evaluating mass transfer models based on fundamental principles to determine their effectiveness in predicting emissions from indoor architectural coatings. As a first step, a simple model based on Fick's Law of Diffusion has been developed. In the model, the mass transfer rate is assumed to be controlled by the boundary layer mass transfer coefficient, the saturation vapor pressure of the material being emitted, and the mass of volatile material remaining in the source at any point in time. Both static and dynamic chamber tests were conducted to obtain model validation data. Further validation experiments were conducted in a test house. Results of these tests are presented.
NASA Technical Reports Server (NTRS)
Deissler, Robert G
1955-01-01
The expression for eddy diffusivity from a previous analysis was modified in order to account for the effect of kinematic viscosity on the turbulence in the region close to a wall. By using the modified expression, good agreement was obtained between predicted and experimental results for heat and mass transfer at Prandtl and Schmidt numbers between 0.5 and 3000. The effects of length-to-diameter ratio and of variable viscosity were also investigated for a wide range of Prandtl numbers.
Mass transfer and magnetic braking in Sco X-1
NASA Astrophysics Data System (ADS)
Pavlovskii, K.; Ivanova, N.
2016-02-01
Sco X-1 is a low-mass X-ray binary (LMXB) that has one of the most precisely determined set of binary parameters such as the mass accretion rate, companions mass ratio and the orbital period. For this system, as well as for a large fraction of other well-studied LMXBs, the observationally-inferred mass accretion rate is known to strongly exceed the theoretically expected mass transfer (MT) rate. We suggest that this discrepancy can be solved by applying a modified magnetic braking prescription, which accounts for increased wind mass-loss in evolved stars compared to main sequence stars. Using our MT framework based on MESA, we explore a large range of binaries at the onset of the MT. We identify the subset of binaries for which the MT tracks cross the Sco X-1 values for the mass ratio and the orbital period. We confirm that no solution can be found for which the standard magnetic braking can provide the observed accretion rates, while wind-boosted magnetic braking can provide the observed accretion rates for many progenitor binaries that evolve to the observed orbital period and mass ratio.
Final Report: Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters
Haggerty, Roy; Day-Lewis, Fred; Singha, Kamini; Johnson, Timothy; Binley, Andrew; Lane, John
2014-03-20
Mass transfer affects contaminant transport and is thought to control the efficiency of aquifer remediation at a number of sites within the Department of Energy (DOE) complex. An improved understanding of mass transfer is critical to meeting the enormous scientific and engineering challenges currently facing DOE. Informed design of site remedies and long-term stewardship of radionuclide-contaminated sites will require new cost-effective laboratory and field techniques to measure the parameters controlling mass transfer spatially and across a range of scales. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Including the NMR component, our revised study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3
Heat and mass transfer in unsaturated porous media. Final report
Childs, S.W.; Malstaff, G.
1982-02-01
A preliminary study of heat and water transport in unsaturated porous media is reported. The project provides background information regarding the feasibility of seasonal thermal energy storage in unconfined aquifers. A parametric analysis of the factors of importance, and an annotated bibliography of research findings pertinent to unconfined aquifer thermal energy storage (ATES) are presented. This analysis shows that heat and mass transfer of water vapor assume dominant importance in unsaturated porous media at elevated temperature. Although water vapor fluxes are seldom as large as saturated medium liquid water fluxes, they are important under unsaturated conditions. The major heat transport mechanism for unsaturated porous media at temperatures from 50 to 90/sup 0/C is latent heat flux. The mechanism is nonexistent under saturated conditions but may well control design of unconfined aquifer storage systems. The parametric analysis treats detailed physical phenomena which occur in the flow systems study and demonstrates the temperature and moisture dependence of the transport coefficients of importance. The question of design of an unconfined ATES site is also addressed by considering the effects of aquifer temperature, depth to water table, porous medium flow properties, and surface boundary conditions. Recommendations are made for continuation of this project in its second phase. Both scientific and engineering goals are considered and alternatives are presented.
Chemical separations by bubble-assisted interphase mass-transfer.
Boyd, David A; Adleman, James R; Goodwin, David G; Psaltis, Demetri
2008-04-01
We show that when a small amount of heat is added close to a liquid-vapor interface of a captive gas bubble in a microchannel, interphase mass-transfer through the bubble can occur in a controlled manner with only a slight change in the temperature of the fluid. We demonstrate that this method, which we refer to as bubble-assisted interphase mass-transfer (BAIM), can be applied to interphase chemical separations, e.g., simple distillation, without the need for high temperatures, vacuum, or active cooling. Although any source of localized heating could be used, we illustrate BAIM with an all-optical technique that makes use of the plasmon resonance in an array of nanoscale metal structures that are incorporated into the channel to produce localized heating of the fluid when illuminated by a stationary low-power laser. PMID:18321130
Heat and Mass Transfer in a Freezing Unsaturated Porous Medium
NASA Astrophysics Data System (ADS)
Jame, Yih-Wu; Norum, Donald I.
1980-08-01
A numerical simulation of a laboratory experiment involving coupled heat and mass transfer in a horizontal porous medium column with one end subjected to a temperature below 0°C has been carried out. The model is essentially that of Harlan (1973) and is solved numerically by the finite difference method using the Crank-Nicholson scheme. The solution yields temperature, liquid water content, and ice content profiles along the column as a function of time. Comparison of the experimental results and the simulation analysis results shows that Harlan's model, with some modification in the hydraulic conductivity of the frozen medium, can be used successfully to simulate numerically the coupled heat and mass transfer processes when ice lensing does not occur.
Geoelectrical inference of mass transfer parameters using temporal moments
Day-Lewis, F. D.; Singha, K.
2008-01-01
We present an approach to infer mass transfer parameters based on (1) an analytical model that relates the temporal moments of mobile and bulk concentration and (2) a bicontinuum modification to Archie's law. Whereas conventional geochemical measurements preferentially sample from the mobile domain, electrical resistivity tomography (ERT) is sensitive to bulk electrical conductivity and, thus, electrolytic solute in both the mobile and immobile domains. We demonstrate the new approach, in which temporal moments of collocated mobile domain conductivity (i.e., conventional sampling) and ERT-estimated bulk conductivity are used to calculate heterogeneous mass transfer rate and immobile porosity fractions in a series of numerical column experiments. Copyright 2008 by the American Geophysical Union.
Combined heat and mass transfer device for improving separation process
Tran, Thanh Nhon
1999-01-01
A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area.
Combined heat and mass transfer device for improving separation process
Tran, T.N.
1999-08-24
A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area. 12 figs.
A Comparison of Stellar Mass-Transfer & Merger Simulations
NASA Astrophysics Data System (ADS)
Tohline, Joel E.; Motl, P.; Diehl, S.; Even, W.; Clayton, G.; Fryer, C.
2011-01-01
We present detailed comparisons of 3D stellar mass-transfer and merger simulations that have been carried out using two very different numerical hydrodynamic algorithms -- a finite-volume "grid" code (typically using 4M cylindrical grid cells) and a smoothed-particle hydrodynamics (SPH) code (typically using 1M particles). In all cases the initial binary models contain synchronously rotating, n = 3/2 polytropic stars of a specified mass ratio (q = Mdonor/Maccretor) that are in circular orbit with one star (the donor) marginally filling its Roche lobe. In our "base" set of 8 comparison simulations, we have followed the evolution of binaries having four different initial mass ratios (q0 = 1.3, 0.7, 0.5, 0.4) and each is evolved using two different equations of state: polytropic (P) and ideal-gas (I). In addition, some evolutions are repeated using a different numerical resolution and/or a different initial episode of "driving" to initiate mass-transfer. In the case of the binary systems with q0 = 1.3 and q0 = 0.7, the codes show a remarkable level of quantitative agreement; in the former case, the two stars merge and, in the latter case, the donor gets tidally disrupted. Binary systems with q0 = 0.5 or 0.4 enter a long phase (> 10-20 orbits) of stable mass-transfer during which the binary separation steadily increases; tidal disruption of the donor may ultimately occur if sufficiently deep contact is made between the Roche lobe and the donor during an initial episode of "driving." This work has been supported by grants AST-0708551 and DGE-0504507 from the U.S. National Science Foundation; by grants NNX07AG84G and NNX10AC72G from NASA's ATP program; and by grants of high-performance computing time on the TeraGrid, at LSU and across LONI (Louisiana Optical Network Initiative).
2D and 3D Mass Transfer Simulations in β Lyrae System
NASA Astrophysics Data System (ADS)
Nazarenko, V. V.; Glazunova, L. V.; Karetnikov, V. G.
2001-12-01
2D and 3D mass transfer simulations of the mass transfer in β Lyrae binary system. We have received that from a point L3 40 per cent of mass transfer from L1-point is lost.The structure of a gas envelope, around system is calculated.3-D mass transfer simulations has shown presence the spiral shock in the disk around primary star's and a jet-like structures (a mass flow in vertical direction) over a stream.
Mass transfer of VOCs in laboratory-scale air sparging tank.
Chao, Keh-Ping; Ong, Say Kee; Huang, Mei-Chuan
2008-04-15
Volatilization of VOCs was investigated using a 55-gal laboratory-scale model in which air sparging experiments were conducted with a vertical air injection well. In addition, X-ray imaging of an air sparging sand box showed air flows were in the form of air bubbles or channels depending on the size of the porous media. Air-water mass transfer was quantified using the air-water mass transfer coefficient which was determined by fitting the experimental data to a two-zone model. The two-zone model is a one-dimensional lumped model that accounts for the effects of air flow type and diffusion of VOCs in the aqueous phase. The experimental air-water mass transfer coefficients, KGa, obtained from this study ranged from 10(-2) to 10(-3)1/min. From a correlation analysis, the air-water mass transfer coefficient was found to be directly proportional to the air flow rate and the mean particle size of soil but inversely proportional to Henry's constant. The correlation results implied that the air-water mass transfer coefficient was strongly affected by the size of porous media and the air flow rates. PMID:17804158
Mathematical modeling heat and mass transfer processes in porous media
NASA Astrophysics Data System (ADS)
Akhmed-Zaki, Darkhan
2013-11-01
On late development stages of oil-fields appears a complex problem of oil-recovery reduction. One of solution approaches is injecting of surfactant together with water in the form of active impurities into the productive layer - for decreasing oil viscosity and capillary forces between ``oil-water'' phases system. In fluids flow the surfactant can be in three states: dissolved in water, dissolved in oil and adsorbed on pore channels' walls. The surfactant's invasion into the reservoir is tracked by its diffusion with reservoir liquid and mass-exchange with two phase (liquid and solid) components of porous structure. Additionally, in this case heat exchange between fluids (injected, residual) and framework of porous medium has practical importance for evaluating of temperature influences on enhancing oil recovery. Now, the problem of designing an adequate mathematical model for describing a simultaneous flowing heat and mass transfer processes in anisotropic heterogeneous porous medium -surfactant injection during at various temperature regimes has not been fully researched. In this work is presents a 2D mathematical model of surfactant injections into the oil reservoir. Description of heat- and mass transfer processes in a porous media is done through differential and kinetic equations. For designing a computational algorithm is used modify version of IMPES method. The sequential and parallel computational algorithms are developed using an adaptive curvilinear meshes which into account heterogeneous porous structures. In this case we can evaluate the boundaries of our process flows - fronts (``invasion'', ``heat'' and ``mass'' transfers), according to the pressure, temperature, and concentration gradient changes.
The model of heat and mass transfer in rough and irrigated ducts
NASA Astrophysics Data System (ADS)
Laptev, A. G.; Lapteva, E. A.
2015-07-01
To determine the coefficients of the heat and mass transfer in the ducts with rough and irrigated walls the development of the classical hydrodynamic analogy of the momentum, mass, and energy transfer has been continued. The conservation properties of the skin-friction laws with respect to various disturbances are used for this purpose, and the "effective velocity" is found the value of which enables us to correct the hydrodynamic analogy. The examples of computations of the Nusselt, Sherwood, and Stanton numbers are shown for rough ducts, cooler, and film flow in the counter-flow. A comparison with the results of other researchers is given.
NASA Technical Reports Server (NTRS)
Rosner, D. E.
1985-01-01
The effects of Soret diffusion (for vapors) and thermophoresis (for particles) are illustrated using recent optical experiments and boundary layer computations. Mass transfer rate augmentations of up to a factor of 1000 were observed and predicted for submicron-particle capture by cooled solid surfaces, while mass transfer suppressions of more than 10 to the -10th-fold were predicted for 'overheated' surfaces. It is noted that the results obtained are of interest in connection with such technological applications as fly-ash capture in power generation equipment and glass droplet deposition in optical-waveguide manufacture.
Stagnation Point Flow and Mass Transfer with Chemical Reaction past a Stretching/Shrinking Cylinder
Najib, Najwa; Bachok, Norfifah; Arifin, Norihan Md.; Ishak, Anuar
2014-01-01
This paper is about the stagnation point flow and mass transfer with chemical reaction past a stretching/shrinking cylinder. The governing partial differential equations in cylindrical form are transformed into ordinary differential equations by a similarity transformation. The transformed equations are solved numerically using a shooting method. Results for the skin friction coefficient, Schmidt number, velocity profiles as well as concentration profiles are presented for different values of the governing parameters. Effects of the curvature parameter, stretching/shrinking parameter and Schmidt number on the flow and mass transfer characteristics are examined. The study indicates that dual solutions exist for the shrinking cylinder but for the stretching cylinder, the solution is unique. It is observed that the surface shear stress and the mass transfer rate at the surface increase as the curvature parameter increases. PMID:24569547
Influence of drying air parameters on mass transfer characteristics of apple slices
NASA Astrophysics Data System (ADS)
Beigi, Mohsen
2015-12-01
To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.
Influence of mass transfer on bubble plume hydrodynamics.
Lima Neto, Iran E; Parente, Priscila A B
2016-03-01
This paper presents an integral model to evaluate the impact of gas transfer on the hydrodynamics of bubble plumes. The model is based on the Gaussian type self-similarity and functional relationships for the entrainment coefficient and factor of momentum amplification due to turbulence. The impact of mass transfer on bubble plume hydrodynamics is investigated considering different bubble sizes, gas flow rates and water depths. The results revealed a relevant impact when fine bubbles are considered, even for moderate water depths. Additionally, model simulations indicate that for weak bubble plumes (i.e., with relatively low flow rates and large depths and slip velocities), both dissolution and turbulence can affect plume hydrodynamics, which demonstrates the importance of taking the momentum amplification factor relationship into account. For deeper water conditions, simulations of bubble dissolution/decompression using the present model and classical models available in the literature resulted in a very good agreement for both aeration and oxygenation processes. Sensitivity analysis showed that the water depth, followed by the bubble size and the flow rate are the most important parameters that affect plume hydrodynamics. Lastly, dimensionless correlations are proposed to assess the impact of mass transfer on plume hydrodynamics, including both the aeration and oxygenation modes. PMID:26840001
FUNDAMENTAL MASS TRANSFER MODEL FOR INDOOR AIR EMISSION FROM SURFACE COATINGS
The paper, discusses the work of researchers at the U.S. EPA's Air and Energy Engineering Research Laboratory (Indoor Air Branch) who are evaluating mass transfer models based on fundamental principles to determine their effectiveness in predicting emissions from indoor architect...
Coarsening of sand ripples in mass transfer models.
Hellén, E K O; Krug, J
2002-07-01
Coarsening of sand ripples is studied in a one-dimensional stochastic model, where neighboring ripples exchange mass with algebraic rates, Gamma(m) approximately m(gamma), and ripples of zero mass are removed from the system. For gamma<0, ripples vanish through rare fluctuations and the average ripple mass grows as
Sales Training: Effects of Spaced Practice on Training Transfer
ERIC Educational Resources Information Center
Kauffeld, Simone; Lehmann-Willenbrock, Nale
2010-01-01
Purpose: The benefits of spaced training over massed training practice are well established in the laboratory setting. In a field study design with sales trainings, the purpose of this paper is to investigate the effects of spaced compared with massed practice on transfer quantity and quality, sales competence, and key figures.…
Direct geoelectrical evidence of mass transfer at the laboratory scale
NASA Astrophysics Data System (ADS)
Swanson, Ryan D.; Singha, Kamini; Day-Lewis, Frederick D.; Binley, Andrew; Keating, Kristina; Haggerty, Roy
2012-10-01
Previous field-scale experimental data and numerical modeling suggest that the dual-domain mass transfer (DDMT) of electrolytic tracers has an observable geoelectrical signature. Here we present controlled laboratory experiments confirming the electrical signature of DDMT and demonstrate the use of time-lapse electrical measurements in conjunction with concentration measurements to estimate the parameters controlling DDMT, i.e., the mobile and immobile porosity and rate at which solute exchanges between mobile and immobile domains. We conducted column tracer tests on unconsolidated quartz sand and a material with a high secondary porosity: the zeolite clinoptilolite. During NaCl tracer tests we collected nearly colocated bulk direct-current electrical conductivity (σb) and fluid conductivity (σf) measurements. Our results for the zeolite show (1) extensive tailing and (2) a hysteretic relation between σf and σb, thus providing evidence of mass transfer not observed within the quartz sand. To identify best-fit parameters and evaluate parameter sensitivity, we performed over 2700 simulations of σf, varying the immobile and mobile domain and mass transfer rate. We emphasized the fit to late-time tailing by minimizing the Box-Cox power transformed root-mean square error between the observed and simulated σf. Low-field proton nuclear magnetic resonance (NMR) measurements provide an independent quantification of the volumes of the mobile and immobile domains. The best-fit parameters based on σf match the NMR measurements of the immobile and mobile domain porosities and provide the first direct electrical evidence for DDMT. Our results underscore the potential of using electrical measurements for DDMT parameter inference.
Characterizing Mass Transfer at the Hanford 300 Area
NASA Astrophysics Data System (ADS)
Hall, L. H.
2012-12-01
Aquifer remediation efforts in the Hanford 300 Area in Washington have presented substantial challenges for the Department of Energy. Since the early 1940s, this site has been a receptacle for radiological and chemical wastes from nuclear weapons production, including high concentrations of uranium. Employing techniques to estimate and measure mass transfer in-situ will improve understanding of contaminant fate and transport at this site, and perhaps others. A field experiment was conducted with a combination of electrical resistivity tomography (ERT) and ionic tracer tests through a double-ring infiltrometer to quantify multirate mass-transfer and other transport parameters in the 300 Area. The tests included a series of injections into an infiltrating column of water. After saturating the column with fresh water at a constant head, bromide tracer solution with initial known concentration was injected for a specified amount of hours. This was followed by a continual fresh water injection during which time fluid samples were taken at varying depths along the probe to observe the tailing of the breakthrough curve during this purge. Throughout the experiment, ERT data collected along the column as well as along a transect perpendicular to the vertical sampling ports. These experiments will result in a model of the local vadose zone which will be calibrated using field data and modeled using HYDRUS 2D and its sequential inverse modeling feature. This program numerically solves the Richards equation for variably saturated water flow and advection-dispersion (AD) type equations for solute transport. It also considers dual-porosity type flow in the mobile and immobile domain. Additionally, mass transfer parameters will be modeled using a code which utilizes the AD equation and numerically solves for concentrations using Laplace Transforms. Analysis on governing processes and calibration of this code using field data will be used for additional verification on
Direct geoelectrical evidence of mass transfer at the laboratory scale
Swanson, Ryan D.; Singha, Kamini; Day-Lewis, Frederick D.; Binley, Andrew; Keating, Kristina; Haggerty, Roy
2012-01-01
Previous field-scale experimental data and numerical modeling suggest that the dual-domain mass transfer (DDMT) of electrolytic tracers has an observable geoelectrical signature. Here we present controlled laboratory experiments confirming the electrical signature of DDMT and demonstrate the use of time-lapse electrical measurements in conjunction with concentration measurements to estimate the parameters controlling DDMT, i.e., the mobile and immobile porosity and rate at which solute exchanges between mobile and immobile domains. We conducted column tracer tests on unconsolidated quartz sand and a material with a high secondary porosity: the zeolite clinoptilolite. During NaCl tracer tests we collected nearly colocated bulk direct-current electrical conductivity (σb) and fluid conductivity (σf) measurements. Our results for the zeolite show (1) extensive tailing and (2) a hysteretic relation between σf and σb, thus providing evidence of mass transfer not observed within the quartz sand. To identify best-fit parameters and evaluate parameter sensitivity, we performed over 2700 simulations of σf, varying the immobile and mobile domain and mass transfer rate. We emphasized the fit to late-time tailing by minimizing the Box-Cox power transformed root-mean square error between the observed and simulated σf. Low-field proton nuclear magnetic resonance (NMR) measurements provide an independent quantification of the volumes of the mobile and immobile domains. The best-fit parameters based on σf match the NMR measurements of the immobile and mobile domain porosities and provide the first direct electrical evidence for DDMT. Our results underscore the potential of using electrical measurements for DDMT parameter inference.
Heat and mass transfer intensification in coaxial reactor
NASA Astrophysics Data System (ADS)
Ananyev, D. V.; Halitova, G. R.
2014-04-01
The work considers heat and mass transfer in the homophasic polymerization reactor. The reactor is a coaxial channel with internal tube in the form of a channel of confusor-diffuser type. The authors compared the degree of polymer transformation in the intensified coaxial reactor with internal tube of confusor-diffuser type and the reactor with constant rectilinear longitudinal section. It was found that in coaxial channels with internal tube of confusor-diffuser type, it is possible to reach high values of the transformation degree and to improve the quality of the obtained polymer.
Increasing peritoneal contact area during dialysis improves mass transfer.
Flessner, M F; Lofthouse, J; Williams, A
2001-10-01
Previous studies in mice demonstrated that relatively large volumes in the peritoneal cavity made contact with only 40% of the anatomic peritoneum and that this contact area (A(contact)) could be increased with use of a surfactant, dioctyl sodium sulfosuccinate (DSS). To investigate the hypothesis that mass transfer rates during peritoneal dialysis are dependent on the area of peritoneum in contact with the dialysis solution, rats were dialyzed for 2 h with a solution that contained (14)C-mannitol, with or without 0.02% DSS. The mass transfer-area coefficients (MTAC) were determined to be (mean +/- SEM, ml/min): no DSS, 0.163 +/- 0.008; with DSS, 0.247 +/- 0.006 (P < 0.002). DSS also caused an increase in total protein loss over 2 h (mean +/- SEM, mg): no DSS, 83.8 +/- 15.8; DSS, 159.5 +/- 6.3 (P < 0.001). In a separate set of animals, the ratio (R) of A(contact) to anatomic area in each plane was measured as in the previous study R(mean) (mean +/- SEM) and equaled 0.466 +/- 0.075, no DSS; 0.837 +/- 0.074, with DSS. The ratio of MTAC (1.52) and protein loss (1.90) approximate the ratio of R(mean(S)) (1.78). Because MTAC = mass transfer coefficient (MTC) x A(contact), small peritoneal transport chambers were used to determine MTC for (14)C-mannitol and fluorescein isothiocyanate-albumin. MTC(mannitol) did not change significantly with the addition of DSS. MTC(albumin) (cm/min x 10(4), mean +/- SEM) equaled 1.47 +/- 0.45 without DSS and 1.78 +/- 0.52 with DSS (P < 0.04). It was concluded that DSS increases the mass transfer rates of mannitol and protein by increasing A(contact), whereas protein transport is further augmented by an apparent increase in the barrier permeability to protein. PMID:11562413
Solid lubricant mass contact transfer technology usage for vacuum ball bearings longevity increasing
NASA Astrophysics Data System (ADS)
Arzymatov, B.; Deulin, E.
2016-07-01
A contact mass transfer technological method of solid lubricant deposition on components of vacuum ball bearings is presented. Physics-mathematical model of process contact mass transfer is being considered. The experimental results of ball bearings covered with solid lubricant longevity in vacuum are presented. It is shown that solid lubricant of contact mass transfer method deposition is prospective for ball bearing longevity increasing.
Mass transfer studies of Geobacter sulfurreducens biofilms on rotating disk electrodes.
Babauta, Jerome T; Beyenal, Haluk
2014-02-01
Electrochemical impedance spectroscopy has received significant attention recently as a method to measure electrochemical parameters of Geobacter sulfurreducens biofilms. Here, we use electrochemical impedance spectroscopy to demonstrate the effect of mass transfer processes on electron transfer by G. sulfurreducens biofilms grown in situ on an electrode that was subsequently rotated. By rotating the biofilms up to 530 rpm, we could control the microscale gradients formed inside G. sulfurreducens biofilms. A 24% increase above a baseline of 82 µA could be achieved with a rotation rate of 530 rpm. By comparison, we observed a 340% increase using a soluble redox mediator (ferrocyanide) limited by mass transfer. Control of mass transfer processes was also used to quantify the change in biofilm impedance during the transition from turnover to non-turnover. We found that only one element of the biofilm impedance, the interfacial resistance, changed significantly from 900 to 4,200 Ω under turnover and non-turnover conditions, respectively. We ascribed this change to the electron transfer resistance overcome by the biofilm metabolism and estimate this value as 3,300 Ω. Additionally, under non-turnover, the biofilm impedance developed pseudocapacitive behavior indicative of bound redox mediators. Pseudocapacitance of the biofilm was estimated at 740 µF and was unresponsive to rotation of the electrode. The increase in electron transfer resistance and pseudocapacitive behavior under non-turnover could be used as indicators of acetate limitations inside G. sulfurreducens biofilms. PMID:23996084
Mass Transfer Studies of Geobacter sulfurreducens Biofilms on Rotating Disk Electrodes
Babuta, Jerome T.; Beyenal, Haluk
2014-01-01
Electrochemical impedance spectroscopy has received significant attention recently as a method to measure electrochemical parameters of Geobacter sulfurreducens bio-films. Here, we use electrochemical impedance spectroscopy to demonstrate the effect of mass transfer processes on electron transfer by G.sulfurreducens biofilms grown in situ on an electrode that was subsequently rotated. By rotating the biofilms up to 530 rpm, we could control the microscale gradients formed inside G.sulfurreducens biofilms. A 24% increase above a baseline of 82 μA could be achieved with a rotation rate of 530 rpm. By comparison, we observed a 340% increase using a soluble redox mediator (ferrocyanide) limited by mass transfer. Control of mass transfer processes was also used to quantify the change in biofilm impedance during the transition from turnover to non-turnover. We found that only one element of the biofilm impedance, the interfacial resistance, changed significantly from 900 to 4,200 Ω under turnover and non-turnover conditions, respectively. We ascribed this change to the electron transfer resistance overcome by the biofilm metabolism and estimate this value as 3,300 Ω. Additionally, under non-turnover, the biofilm impedance developed pseudocapacitive behavior indicative of bound redox mediators. Pseudocapacitance of the biofilm was estimated at 740 μF and was unresponsive to rotation of the electrode. The increase in electron transfer resistance and pseudocapacitive behavior under non-turnover could be used as indicators of acetate limitations inside G.sulfurreducens biofilms. PMID:23996084
Volatile organic compound emission rates from mechanical surface aerators: Mass-transfer modeling
Chern, J.M.; Chou, S.R.
1999-08-01
In wastewater treatment plants, many operation units such as equalization and aeration involve oxygen transfer between wastewater and air. While oxygen is transferred from air to wastewater, volatile organic compounds (VOCs) are stripped from wastewater to air. Because of increasingly stringent environmental regulations, wastewater treatment operators have to do VOC inventory of their facilities. A new mass-transfer model has been developed to predict the VOC emission rates from batch and continuous aeration tanks with mechanical surface aerators. The model takes into consideration that the VOC mass transfer occurs in two separate mass-transfer zones instead of lumping the overall VOC transfer in the whole aeration tank as is done in the conventional ASCE-based model. The predictive capabilities of the two-zone and the ASCE-based models were examined by calculating the emission rates of 10 priority pollutants from aeration tanks. The effects of the hydraulic retention time, the Henry`s law constant, gas-phase resistance, and the water and air environmental conditions on the VOC emission rates were predicted by the two models.
NASA Astrophysics Data System (ADS)
Zapata-Rios, X.; Brooks, P. D.; Troch, P. A.; McIntosh, J.; Rasmussen, C.
2015-08-01
The Critical Zone (CZ) is the heterogeneous, near-surface layer of the planet that regulates life-sustaining resources. Previous research has demonstrated that a quantification of the influxes of effective energy and mass (EEMT) to the CZ can predict its structure and function. In this study, we quantify how climate variability in the last three decades (1984-2012) has affected water availability and the temporal trends in EEMT. This study takes place in the 1200 km2 upper Jemez River Basin in northern New Mexico. The analysis of climate, water availability, and EEMT was based on records from two high elevation SNOTEL stations, PRISM data, catchment scale discharge, and satellite derived net primary productivity (MODIS). Records from the two SNOTEL stations showed clear increasing trends in winter and annual temperatures (+1.0-1.3 °C decade-1; +1.2-1.4 °C decade-1, respectively), decreasing trends in winter and annual precipitation (-41.6-51.4 mm decade-1; -69.8-73.2 mm decade-1, respectively) and maximum Snow Water Equivalent (SWE; -33.1-34.7 mm decade-1). The water partitioning fluxes at the basin scale showed statistically significant decreasing trends in precipitation (-61.7 mm decade-1), discharge (-17.6 mm decade-1) and vaporization (-45.7 mm decade-1). Similarly Q50, an indicator of snowmelt timing, is occurring 4.3 days decade-1 earlier. Results from this study indicated a decreasing trend in water availability, a reduction in forest productivity (4 g C m-2 per 10 mm of reduction in Precipitation) and EEMT (1.2-1.3 MJ m2 decade-1). These changes in EEMT point towards a hotter, drier and less productive ecosystem which may alter critical zone processes in high elevation semi-arid systems.
Mixed convection heat and mass transfer in radially rotating rectangular ducts
Lee, K.T.; Yan, W.M.
1998-11-27
Heat transfer in rotating ducts is encountered in many engineering applications, such as cooling of turbomachinery, gas turbines, and other rotating systems. The present work investigates mixed convection heat and mass transfer in the entrance region of radially rotating rectangular ducts with water film evaporation along the porous duct walls. Mechanisms of secondary vortex development in the ducts under various conditions are examined by a vorticity-velocity numerical method. Emphasis is placed on the rotation effects, including both Coriolis and centrifugal buoyancy forces, and the mass diffusion effect on the flow structure and heat transfer characteristics. Results are presented in particular for an air-water vapor system under various conditions. Predicted results show that the effects of liquid film evaporation along the porous duct walls on the mixed convection heat transfer are rather substantial. The magnitude of the evaporative latent heat transfer may be 10 times greater than that of sensible heat transfer. The predictions also demonstrate that the distributions of Nu, Sh{sub z}, and fRe are closely related to the emergence, disappearance, growth, and decay of the rotating-induced secondary vortices. Additionally, a higher Nu{sub z} is found for a rectangular duct with a larger aspect ratio ({gamma} = 2) due to the relatively stronger secondary flows.
Collisional processes and transfer of mass among the planetary satellites
NASA Astrophysics Data System (ADS)
Marchi, S.; Dell'Oro, A.; Paolicchi, P.; Barbieri, C.
2001-08-01
Several pairs of planetary satellites may have been involved, during the history of the Solar System, in mutual mass transfer processes. Such processes can be triggered by catastrophic collisions of a satellite (parent body) with a third object. As a consequence, the collision fragments are injected into independent orbits that can cross the trajectory of the another satellite (target). These swarms of secondary impacts may be of some importance influencing the properties of the target body. Even the formation of the atmosphere around some giant satellites may have been triggered by the gas released after the impacts of fragments onto the target's surface. Moreover, the different albedos and the different surface density of impact craters within the same satellite system may be connected to peculiar collisional phenomena, such as those we are dealing with. A quantitative modelling of the role of mass transfer processes obviously requires an estimate of how much material the parent bodies are able to supply, and under what circumstances the process may take place. A general analysis of the various pairs throughout the major satellite systems present in the Solar System has been performed in the present paper. Our analysis uses a statistical algorithm, computing, as a function of the initial properties of the fragments (masses and ejection velocities from their parent body), the mean intrinsic probability of impact, and then the mean lifetime of a fragment before impacting the target, as well as the distribution of the relative velocity. For an order-of-magnitude estimate of the available amount of mass, some simple analytical equations have been derived to evaluate the fraction of fragments from the parent body that can reach the target. These formulae allow a preliminary discrimination of the interesting cases. The pair Hyperion-Titan and the Uranus system have been analyzed in detail.
The effect of the coating layer thickness on VOC extraction performance of a ceramic polymer composite membrane has been investigated. It was found, under experimental condiitons representing typical field operation, the overall mass transfer rates of feed components were control...
Goemans, M.G.E.; Gloyna, E.F.
1996-10-01
The potential of sub- and supercritical water as extraction solvents has been demonstrated for the (reactive) extraction of coals, used car tires, organic species from residual aqueous solutions, and class selective extraction of organic pollutants with different polarities from solids. In addition, the potential of extraction of coal with supercritical aqueous solutions has been studied. However, physical transport in water at elevated temperature and pressures- and their impact on heterogenous reactions and (reactive) extraction -are not adequately understood. This situation is largely due to the limited data that is available for diffusion in high temperature, high pressure water mixture. Only the molecular diffusion of Iodine ions and hydroquinone in near-critical subcritical water and the self diffusion of coefficient of compressed supercritical water have been reported. In this paper, we present molecular diffusion coefficients of benzophenone, acetone, naphthalene, and anthracene in water at infinite dilution. Pressures ranged from 250 to 500 bar at temperatures ranging from 50{degrees}C to 500{degrees}C resulting in water densities ranging from 1000 to 150 kg/m{sup 3}. Diffusion coefficients were determined by the Taylor-Aris dispersion technique. The effects of increased diffusion on the mass transfer coefficients for emulsions and packed beds were quantified. Molecular division coefficients were 10 to 20 times faster in supercritical water than in water at ambient conditions. Experimental results were correlated with hydrodynamic and kinetic theory. This study and results to be published elsewhere show that diffusion-limited conditions are much more likely to be encountered in supercritical water than is commonly acknowledged.
NASA Astrophysics Data System (ADS)
Pal, Dulal; Chatterjee, Sewli
2011-03-01
A numerical model is developed to examine the combined effects of Soret and Dufour on mixed convection magnetohydrodynamic heat and mass transfer in micropolar fluid-saturated Darcian porous medium in the presence of thermal radiation, non-uniform heat source/sink and Ohmic dissipation. The governing boundary layer equations for momentum, angular momentum (microrotation), energy and species transfer are transformed to a set of non-linear ordinary differential equations by using similarity solutions which are then solved numerically based on shooting algorithm with Runge-Kutta-Fehlberg integration scheme over the entire range of physical parameters with appropriate boundary conditions. The influence of Darcy number, Prandtl number, Schmidt number, Soret number and Dufour number, magnetic parameter, local thermal Grashof number and local solutal Grashof number on velocity, temperature and concentration fields are studied graphically. Finally, the effects of related physical parameters on local Skin-friction, local Nusselt number and local Sherwood number are also studied. Results showed that the fields were influenced appreciably by the Soret and Dufour effects, thermal radiation and magnetic field, etc.
NASA Astrophysics Data System (ADS)
Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi
2016-05-01
An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.
3D modelling of coupled mass and heat transfer of a convection-oven roasting process.
Feyissa, Aberham Hailu; Gernaey, Krist V; Adler-Nissen, Jens
2013-04-01
A 3D mathematical model of coupled heat and mass transfer describing oven roasting of meat has been developed from first principles. The proposed mechanism for the mass transfer of water is modified and based on a critical literature review of the effect of heat on meat. The model equations are based on a conservation of mass and energy, coupled through Darcy's equations of porous media - the water flow is mainly pressure-driven. The developed model together with theoretical and experimental assessments were used to explain the heat and water transport and the effect of the change in microstructure (permeability, water binding capacity and elastic modulus) that occur during the meat roasting process. The developed coupled partial differential equations were solved by using COMSOL Multiphysics®3.5 and state variables are predicted as functions of both position and time. The proposed mechanism was partially validated by experiments in a convection oven where temperatures were measured online. PMID:23305831
Hornblendite delineates zones of mass transfer through the lower crust
Daczko, Nathan R.; Piazolo, Sandra; Meek, Uvana; Stuart, Catherine A.; Elliott, Victoria
2016-01-01
Geochemical signatures throughout the layered Earth require significant mass transfer through the lower crust, yet geological pathways are under-recognized. Elongate bodies of basic to ultrabasic rocks are ubiquitous in exposures of the lower crust. Ultrabasic hornblendite bodies hosted within granulite facies gabbroic gneiss of the Pembroke Valley, Fiordland, New Zealand, are typical occurrences usually reported as igneous cumulate hornblendite. Their igneous features contrast with the metamorphic character of their host gabbroic gneiss. Both rock types have a common parent; field relationships are consistent with modification of host gabbroic gneiss into hornblendite. This precludes any interpretation involving cumulate processes in forming the hornblendite; these bodies are imposter cumulates. Instead, replacement of the host gabbroic gneiss formed hornblendite as a result of channeled high melt flux through the lower crust. High melt/rock ratios and disequilibrium between the migrating magma (granodiorite) and its host gabbroic gneiss induced dissolution (grain-scale magmatic assimilation) of gneiss and crystallization of mainly hornblende from the migrating magma. The extent of this reaction-replacement mechanism indicates that such hornblendite bodies delineate significant melt conduits. Accordingly, many of the ubiquitous basic to ultrabasic elongate bodies of the lower crust likely map the ‘missing’ mass transfer zones. PMID:27546342
Hornblendite delineates zones of mass transfer through the lower crust.
Daczko, Nathan R; Piazolo, Sandra; Meek, Uvana; Stuart, Catherine A; Elliott, Victoria
2016-01-01
Geochemical signatures throughout the layered Earth require significant mass transfer through the lower crust, yet geological pathways are under-recognized. Elongate bodies of basic to ultrabasic rocks are ubiquitous in exposures of the lower crust. Ultrabasic hornblendite bodies hosted within granulite facies gabbroic gneiss of the Pembroke Valley, Fiordland, New Zealand, are typical occurrences usually reported as igneous cumulate hornblendite. Their igneous features contrast with the metamorphic character of their host gabbroic gneiss. Both rock types have a common parent; field relationships are consistent with modification of host gabbroic gneiss into hornblendite. This precludes any interpretation involving cumulate processes in forming the hornblendite; these bodies are imposter cumulates. Instead, replacement of the host gabbroic gneiss formed hornblendite as a result of channeled high melt flux through the lower crust. High melt/rock ratios and disequilibrium between the migrating magma (granodiorite) and its host gabbroic gneiss induced dissolution (grain-scale magmatic assimilation) of gneiss and crystallization of mainly hornblende from the migrating magma. The extent of this reaction-replacement mechanism indicates that such hornblendite bodies delineate significant melt conduits. Accordingly, many of the ubiquitous basic to ultrabasic elongate bodies of the lower crust likely map the 'missing' mass transfer zones. PMID:27546342
Gas Blowing: Mass Transfer in Gas and Melt
NASA Astrophysics Data System (ADS)
Sortland, Øyvind Sunde; Tangstad, Merete
2014-09-01
Metallurgical routes for solar grade silicon production are being developed as alternatives to chemical processes for their potential to achieve cost reductions, increased production volume, and reduced environmental and safety concerns. An important challenge in the development of metallurgical routes relates to the higher impurity concentrations in the silicon product, particularly for boron and other elements that are not efficiently segregated in solidification techniques. The reactive gas refining process is studied for its potential to remove boron below the solar grade silicon target concentration in a single step by blowing steam and hydrogen gas jets onto the melt surface. Boron in a silicon melt is extracted to HBO gas in parallel to active oxidation of silicon. The literature is not unified regarding the rate determining step in this process. Relevant theories and equations for gas blowing in induction furnaces are combined and used to explain mass transfer in experiments. Mass transfer in the melt and gas is investigated by comparing resistance and induction heating of the melt, and varying gas flow rate, crucible diameter, diameter of the gas lance, and the position of the gas lance above the melt surface. The rate of boron removal is found to increase with increasing gas flow rate and crucible diameter. A relatively high fraction of the reactive gas is utilized in the process, and supply of steam in the bulk gas is the only identified rate determining step.
NASA Astrophysics Data System (ADS)
Luo, Benyi; Lu, Yigang
2008-10-01
Based on several hypotheses about the process of supercritical carbon dioxide extraction, the onflow around the solute granule is figured out by the Navier-Stocks equation. In combination with the Higbie’s solute infiltration model, the link between the mass-transfer coefficient and the velocity of flow is found. The mass-transfer coefficient with the ultrasonical effect is compared with that without the ultrasonical effect, and then a new parameter named the ultrasonic-enhanced factor of mass-transfer coefficient is brought forward, which describes the mathematical model of the supercritical carbon dioxide extraction process enhanced by ultrasonic. The model gives out the relationships among the ultrasonical power, the ultrasonical frequency, the radius of solute granule and the ultrasonic-enhanced factor of mass-transfer coefficient. The results calculated by this model fit well with the experimental data, including the extraction of Coix Lacryma-jobi Seed Oil (CLSO) and Coix Lacryma-jobi Seed Ester (CLSE) from coix seeds and the extraction of Eicosapentaenoic Acid (EPA) and Docosahexaenoic Acid (DHA) from the alga by means of the ultrasonic-enhanced supercritical carbon dioxide extraction (USFE) and the supercritical carbon dioxide extraction (SFE) respectively. This proves the rationality of the ultrasonic-enhanced factor model. The model provides a theoretical basis for the application of ultrasonic-enhanced supercritical fluid extraction technique.
Hydrodynamic characteristics and gas-liquid mass transfer in a biofilm airlift suspension reactor.
Nicolella, C; van Loosdrecht, M C; van der Lans, R G; Heijnen, J J
1998-12-01
The hydrodynamics and mass transfer, specifically the effects of gas velocity and the presence and type of solids on the gas hold-up and volumetric mass transfer coefficient, were studied on a lab-scale airlift reactor with internal draft tube. Basalt particles and biofilm-coated particles were used as solid phase. Three distinct flow regimes were observed with increasing gas flow rate. The influence of the solid phase on the hydrodynamics was a peculiar characteristic of the regimes. The volumetric mass transfer coefficient was found to decrease with increasing solid loading and particle size. This could be predominantly related to the influence that the solid has on gas hold-up. The ratio between gas hold-up and volumetric mass transfer coefficient was found to be independent of solid loading, size, or density, and it was proven that the presence of solids in airlift reactors lowers the number of gas bubbles without changing their size. To evaluate scale effects, experimental results were compared with theoretical and empirical models proposed for similar systems. PMID:10099471
Mass-independent isotope effects.
Buchachenko, Anatoly L
2013-02-28
Three fundamental properties of atomic nuclei-mass, spin (and related magnetic moment), and volume-are the source of isotope effects. The mostly deserved and popular, with almost hundred-year history, is the mass-dependent isotope effect. The first mass-independent isotope effect which chemically discriminates isotopes by their nuclear spins and nuclear magnetic moments rather than by their masses was detected in 1976. It was named as the magnetic isotope effect because it is controlled by magnetic interaction, i.e., electron-nuclear hyperfine coupling in the paramagnetic species, the reaction intermediates. The effect follows from the universal physical property of chemical reactions to conserve angular momentum (spin) of electrons and nuclei. It is now detected for oxygen, silicon, sulfur, germanium, tin, mercury, magnesium, calcium, zinc, and uranium in a great variety of chemical and biochemical reactions including those of medical and ecological importance. Another mass-independent isotope effect was detected in 1983 as a deviation of isotopic distribution in reaction products from that which would be expected from the mass-dependent isotope effect. On the physical basis, it is in fact a mass-dependent effect, but it surprisingly results in isotope fractionation which is incompatible with that predicted by traditional mass-dependent effects. It is supposed to be a function of dynamic parameters of reaction and energy relaxation in excited states of products. The third, nuclear volume mass-independent isotope effect is detected in the high-resolution atomic and molecular spectra and in the extraction processes, but there are no unambiguous indications of its importance as an isotope fractionation factor in chemical reactions. PMID:23301791
Chen, J.J.; Lin, J.D.
1998-06-01
Drying is one of the essential steps in a number of industrial applications, such as the preserving of food and the drying of paint, pulp, and paper. The quality of paper tubes is significantly affected by the heat and mass transfer process. The drying of polymer solution plays a crucial role in the manufacturer of photographic film, synthetic fibers, adhesives, and a variety of other polymeric products. During drying of wet materials, simultaneous heat and mass transfer occurs both inside the medium and in the boundary layer of the drying agent. Drying is one of the most energy-consuming processes in the industrial sector and can also be very time consuming as, for example, in conventional convective drying by hot air, while minimum cost and energy consumption and maximum product quality are among the main concerns in industry today. Here, a theoretical study is performed that describes heat transfer and moisture variation while a polymer solution is exposed to high-intensity infrared radiation flux and/or an airflow. While the intermittent heating is considered, the authors investigate the influences of various radiation and convection parameters on the transfer of heat and moisture variation of coated layers on an optically thick substrate. During the tempering stage in the intermittent heating process, the convective mass transfer is included to simulate the ambient air in reality. The effects of radiation and convection parameters on the transfer processes are presented in terms of the rate of water content removal, heat transfer, and moisture distributions. Numerical results show that the rate of water removal from the polymer solution is dominated by both the adsorbed radiative heat energy and the distributions of water mass fraction in the polymer solution.
Local endwall heat/mass-transfer distributions in pin fin channels
NASA Astrophysics Data System (ADS)
Lau, S. C.; Kim, Y. S.; Han, J. C.
1987-10-01
Naphthalene sublimination experiments were conducted to study the effects of the pin configuration, the pin length-to-diameter ratio, and the entrance length on local endwall heat/mass transfer in a channel with short pin fins (pin length-to-diameter ratios of 0.5 and 1.0). The detailed distributions of the local endwall heat/mass-transfer coefficient were obtained for staggered and aligned arrays of pin fins, for the spanwise pin spacing-to-diameter ratio of 2.5, and for streamwise pin spacing-to-diameter ratios of 1.25 and 2.5. The Reynolds numbers were kept at about 33,000. Overall- and row-averaged Nusselt numbers compared very well with those from previous heat-transfer studies.
NASA Astrophysics Data System (ADS)
Sotehi, Nassima; Chaker, Abla
A numerical study was carried out in order to investigate the behaviour of building envelopes made of lightweight concretes. In this work, we are particularly interested to the building envelopes which are consist of cement paste with incorporation of cork aggregates in order to obtain small thermal conductivity and low-density materials. The mathematical formulation of coupled heat and mass transfer in wet porous materials has been made using Luikov's model, the system describing temperature and moisture transfer processes within building walls is solved numerically with the finite elements method. The obtained results illustrate the temporal evolutions of the temperature and the moisture content, and the distributions of the temperature and moisture content inside the wall for several periods of time. They allow us to specify the effect of the nature and dosage of fibre on the heat and mass transfer.
NASA Astrophysics Data System (ADS)
Bakr, A. A.
2011-02-01
This paper concerns with studying the steady and unsteady MHD micropolar flow and mass transfers flow with constant heat source in a rotating frame of reference in the presence chemical reaction of the first-order, taking an oscillatory plate velocity and a constant suction velocity at the plate. The plate velocity is assumed to oscillate in time with a constant frequency; it is thus assumed that the solutions of the boundary layer are the same oscillatory type. The governing dimensionless equations are solved analytically after using small perturbation approximation. The effects of the various flow parameters and thermophysical properties on the velocity and temperature fields across the boundary layer are investigated. Numerical results of velocity profiles of micropolar fluids are compared with the corresponding flow problems for a Newtonian fluid. The results show that there exists completely oscillating behavior in the velocity distribution.
NASA Technical Reports Server (NTRS)
Clark, R. K.
1972-01-01
The differential equations governing the transient response of a one-dimensional ablative thermal protection system undergoing stagnation ablation are derived. These equations are for thermal nonequilibrium effects between the pyrolysis gases and the char layer and kinetically controlled chemical reactions and mass transfer between the pyrolysis gases and the char layer. The boundary conditions are written for the particular case of stagnation heating with surface removal by oxidation or sublimation and pyrolysis of the uncharred layer occurring in a plane. The governing equations and boundary conditions are solved numerically using the modified implicit method (Crank-Nicolson method). Numerical results are compared with exact solutions for a number of simplified cases. The comparison is favorable in each instance.
NASA Astrophysics Data System (ADS)
Sundqvist, J. O.; Puls, J.; Owocki, S. P.
2014-08-01
Aims: We provide a fast and easy-to-use formalism for treating the reduction in effective opacity associated with optically thick clumps in an accelerating two-component medium. Methods: We develop and benchmark effective-opacity laws for continuum and line radiative transfer that bridge the limits of optically thin and thick clumps. We then use this formalism to i) design a simple method for modeling and analyzing UV wind resonance lines in hot, massive stars, and ii) derive simple correction factors to the line force driving the outflows of such stars. Results: Using a vorosity-modified Sobolev with exact integration (vmSEI) method, we show that, for a given ionization factor, UV resonance doublets may be used to analytically predict the upward corrections in empirically inferred mass-loss rates associated with porosity in velocity space (a.k.a. velocity-porosity, or vorosity). However, we also show the presence of a solution degeneracy: in a two-component clumped wind with given inter-clump medium density, there are always two different solutions producing the same synthetic doublet profile. We demonstrate this by application to SiIV and PV in B and O supergiants and derive, for an inter-clump density set to 1% of the mean density, upward empirical mass-loss corrections of typically factors of either ~5 or ~50, depending on which of the two solutions is chosen. Overall, our results indicate that this solution dichotomy severely limits the use of UV resonance lines as direct mass-loss indicators in current diagnostic models of clumped hot stellar winds. We next apply the effective line-opacity formalism to the standard CAK theory of line-driven winds. A simple vorosity correction factor to the CAK line force is derived, which for normalized velocity filling factor fvel simply scales as fvelα, where α is the slope of the CAK line-strength distribution function. By analytic and numerical hydrodynamics calculations, we further show that in cases where vorosity is
Gwo, Jin-Ping; Jardine, Philip M; Sanford, William E
2005-03-01
Multiple factors may affect the scale-up of laboratory multi-tracer injection into structured porous media to the field. Under transient flow conditions and with multiscale heterogeneities in the field, previous attempts to scale-up laboratory experiments have not answered definitely the questions about the governing mechanisms and the spatial extent of the influence of small-scale mass transfer processes such as matrix diffusion. The objective of this research is to investigate the effects of multiscale heterogeneity, mechanistic and site model conceptualization, and source term density effect on elucidating and interpreting tracer movement in the field. Tracer release and monitoring information previously obtained in a field campaign of multiple, conservative tracer injection under natural hydraulic gradients at a low-level waste disposal site in eastern Tennessee, United States, is used for the research. A suite of two-pore-domain, or fracture-matrix, groundwater flow and transport models are calibrated and used to conduct model parameter and prediction uncertainty analyses. These efforts are facilitated by a novel nested Latin-hypercube sampling technique. Our results verify, at field scale, a multiple-pore-domain, multiscale mechanistic conceptual model that was used previously to interpret only laboratory observations. The results also suggest that, integrated over the entire field site, mass flux rates attributable to small-scale mass transfer are comparable to that of field-scale solute transport. The uncertainty analyses show that fracture spacing is the most important model parameter and model prediction uncertainty is relatively higher at the interface between the preferred flow path and its parent bedrock. The comparisons of site conceptual models indicate that the effect of matrix diffusion may be confined to the immediate neighborhood of the preferential flow path. Finally, because the relatively large amount of tracer needed for field studies, it is
Monodisperse droplet generation for microscale mass transfer studies
NASA Astrophysics Data System (ADS)
Roberts, Christine; Rao, Rekha; Grillet, Anne; Jove-Colon, Carlos; Brooks, Carlton; Nemer, Martin
2011-11-01
Understanding interfacial mass transport on a droplet scale is essential for modeling liquid-liquid extraction processes. A thin flow-focusing microfluidic channel is evaluated for generating monodisperse liquid droplets for microscale mass transport studies. Surface treatment of the microfluidic device allows creation of both oil in water and water in oil emulsions, facilitating a large parameter study of viscosity and flow rate ratios. The unusually thin channel height promotes a flow regime where no droplets form. Through confocal microscopy, this regime is shown to be highly influenced by the contact angle of the liquids with the channel. Drop sizes are found to scale with a modified capillary number. Liquid streamlines within the droplets are inferred by high speed imagery of microparticles dispersed in the droplet phase. Finally, species mass transfer to the droplet fluid is quantitatively measured using high speed imaging. Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85.
On Computations for Thermal Radiation in MHD Channel Flow with Heat and Mass Transfer
Hayat, T.; Awais, M.; Alsaedi, A.; Safdar, Ambreen
2014-01-01
This study examines the simultaneous effects of heat and mass transfer on the three-dimensional boundary layer flow of viscous fluid between two infinite parallel plates. Magnetohydrodynamic (MHD) and thermal radiation effects are present. The governing problems are first modeled and then solved by homotopy analysis method (HAM). Influence of several embedded parameters on the velocity, concentration and temperature fields are described. PMID:24497968
NASA Astrophysics Data System (ADS)
Laptev, A. G.; Lapteva, E. A.
2015-07-01
The efficiency of heat and mass transfer in the bubbling bed on the plate has been investigated with the use of the method of combined physical and mathematical modeling based on the representation of the physical process in the form of a combination of elementary phenomena having a hierarchy of scales that permits realizing a scale transition in designing a contact device. The mathematical modeling of the heat and mass transfer in the above bed is based on the idea that the structure of this bed is invariant with its size and the interaction of the phases in it. A parametric investigation of the interaction of various effects in the process of heat and mass transfer in the bubbling bed on the plate and their conjugation has been carried out on the basis of the variational formulation of the conservation laws. Examples of calculating the efficiencies of the heat and mass transfer processes on bubbling plates are given. The results of calculations were compared with the corresponding experimental data.
Mass transfer coefficients developed from the air gasification of wood pellets
Botts, J.W.
1998-07-01
A convertible updraft/downdraft, fixed-bed gasifier was used in the gasification of 3/8-inch diameter wood pellets. The test data was used to develop mass transfer coefficients and describe the gasification process for each gasifier configuration. The results show that the production of the principal combustion gases, i.e., hydrogen (H{sub c}), carbon monozide (CO), and methane (CH{sub 4}), varies directly as to their mass transfer coefficient: H{sub 2}, CO, and CH{sub 4} = k h{sub DA}. Factoring the Reynolds (Re{sub d}) and Schmidt (Sc) numbers with the influence of the noncombustible gases, i.e., nitrogen (N{sub 2}), oxygen (O{sub 2}), and carbon dioxide (CO{sub 2}), is used to define the mass transfer coefficients. The general form describing this joint variation is: H{sub 2}, CO, and CH{sub 4} = kx (the effect of the noncombustible gases) x Re x Sc where Re = Reynolds number and Sc = Schmidt number. The developments of these mass transfer coefficients are shown for updraft and downdraft gasification.
Mass Transfer Testing of a 12.5-cm Rotor Centrifugal Contactor
D. H. Meikrantz; T. G. Garn; J. D. Law; N. R. Mann; T. A. Todd
2008-09-01
TRUEX mass transfer tests were performed using a single stage commercially available 12.5 cm centrifugal contactor and stable cerium (Ce) and europium (Eu). Test conditions included throughputs ranging from 2.5 to 15 Lpm and rotor speeds of 1750 and 2250 rpm. Ce and Eu extraction forward distribution coefficients ranged from 13 to 19. The first and second stage strip back distributions were 0.5 to 1.4 and .002 to .004, respectively, throughout the dynamic test conditions studied. Visual carryover of aqueous entrainment in all organic phase samples was estimated at < 0.1 % and organic carryover into all aqueous phase samples was about ten times less. Mass transfer efficiencies of = 98 % for both Ce and Eu in the extraction section were obtained over the entire range of test conditions. The first strip stage mass transfer efficiencies ranged from 75 to 93% trending higher with increasing throughput. Second stage mass transfer was greater than 99% in all cases. Increasing the rotor speed from 1750 to 2250 rpm had no significant effect on efficiency for all throughputs tested.
Drop oscillation and mass transfer in alternating electric fields
Carleson, T.E.
1992-06-24
In certain cases droplet direct contact heat transfer rates can be significantly enhanced by the application of an alternating electric field. This field can produce shape oscillations in a droplet which will enhance mixing. The theoretical evaluation of the effect of the interaction of the field with drop charge on the hydrodynamics has been completed for small amplitude oscillations. Previous work with a zero order perturbation method was followed up with a first order perturbation method to evaluate the effect of drop distortion on drop charge and field distribution. The first order perturbation results show secondary drop oscillations of four modes and two frequencies in each mode. The most significant secondary oscillation has the same mode and frequency as the second mode oscillation predicted from the first order perturbation work. The resonant frequency of all oscillations decrease with increasing electric field strength and drop charge. Work is currently underway to evaluate the heat transfer enhancement from an applied alternating electric field.
Ahn, Sungwoo; Werner, David; Luthy, Richard G
2008-06-01
A three-compartment kinetic partitioning model was employed to assess contaminant mass transfer and intraparticle diffusion in systems comprising dense slurries of polluted soil or aquifer sediment with or without sorbent amendments to sequester polycyclic aromatic hydrocarbons (PAHs). The model was applied to simulate temporal changes in aqueous and particle-bound PAH concentrations comparing different pollution sources (heavy oil or tar sludge) and various sorbent amendments (polyoxymethylene (POM), coke breeze, and activated carbon). For the model evaluation, all the parameters needed were directly measured from a series of experiments, allowing full calibration and verification of model predictions without parameter fitting. The numerical model reproduced two separate laboratory-scale experiments reasonably: PAH uptake in POM beads and PAH uptake by semipermeable membrane devices. PAH mass transfer was then simulated for various scenarios, considering different sorbent doses and mass transfer rates as well as biodegradation. Such model predictions provide a quick assessment tool for identifying mass transfer limitations during washing, stabilization, or bioslurry treatments of polluted soil or sediment in mixed systems. It appears that PAHs would be readily released from materials contaminated by small oil droplets, but not tar decanter sludge. Released PAHs would be sequestered rapidly by activated carbon amendment but to a much lesser extent by coke breeze. If sorbing black carbon is present in the slurries, POM pellets would not be effective as a sequestration amendment. High first-order biodegradation rates in the free aqueous phase, e.g., in the order of 0.001 s(-1) for phenanthrene, would be required to compete effectively with adsorption and mass transfer for strong sorbents. PMID:18456306
Heat and mass transfer performances on plate fin and tube heat exchangers with dehumidification
Seshimo, Y.; Ogawa, K.; Marumoto, K.; Fujii, M. )
1990-09-01
The authors discuss how they conducted an experimental study on the air side performance of a single-row plate fin and tube heat exchanger in moist air where mass transfer exist under a relatively low driving potential. The results are as follows: The heat transfer with dehumidification is about 20% greater than that with only sensible heat transfer. Also the air side pressure drop is about 30-40% greater. The reason, as clarified by visual observations, comes from the condensate effect. To study how the condensate film affects performance, the presence of the stagnant condensate in the heat exchanger was modeled as an apparent change of the heat exchanger geometry, and the equivalent thickness of the condensate film was calculated from the increase in the air side pressure drop. As a result, if the presence of condensate in the heat exchanger is considered, then the heat transfer with dehumidification can be treated in the same way as with only sensible heat transfer. The analogy between heat and mass transfer does not strictly hold, the experimental results being closed to the Lewis Law.
31 CFR 544.202 - Effect of transfers violating the provisions of this part.
Code of Federal Regulations, 2012 CFR
2012-07-01
... and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WEAPONS OF MASS DESTRUCTION PROLIFERATORS SANCTIONS REGULATIONS Prohibitions § 544.202 Effect of transfers violating...
31 CFR 544.202 - Effect of transfers violating the provisions of this part.
Code of Federal Regulations, 2010 CFR
2010-07-01
... and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WEAPONS OF MASS DESTRUCTION PROLIFERATORS SANCTIONS REGULATIONS Prohibitions § 544.202 Effect of transfers violating...
31 CFR 544.202 - Effect of transfers violating the provisions of this part.
Code of Federal Regulations, 2014 CFR
2014-07-01
... and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WEAPONS OF MASS DESTRUCTION PROLIFERATORS SANCTIONS REGULATIONS Prohibitions § 544.202 Effect of transfers violating...
31 CFR 544.202 - Effect of transfers violating the provisions of this part.
Code of Federal Regulations, 2011 CFR
2011-07-01
... and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WEAPONS OF MASS DESTRUCTION PROLIFERATORS SANCTIONS REGULATIONS Prohibitions § 544.202 Effect of transfers violating...
31 CFR 544.202 - Effect of transfers violating the provisions of this part.
Code of Federal Regulations, 2013 CFR
2013-07-01
... and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WEAPONS OF MASS DESTRUCTION PROLIFERATORS SANCTIONS REGULATIONS Prohibitions § 544.202 Effect of transfers violating...
Modeling of Heat and Mass Transfer in Fusion Welding
Zhang, Wei
2011-01-01
In fusion welding, parts are joined together by melting and subsequent solidification. Although this principle is simple, complex transport phenomena take place during fusion welding, and they determine the final weld quality and performance. The heat and mass transfer in the weld pool directly affect the size and shape of the pool, the solidification microstructure, the formation of weld defects such as porosity and humping, and the temperature distribution in the fusion zone and heat-affected zone (HAZ). Furthermore, the temperature evolution affects the kinetics and extent of various solid-state phase transformations, which in turn determine the final weld microstructure and mechanical properties. The formation of residual stresses and distortion originates from the thermal expansion and contraction during welding heating and cooling, respectively.
Code System to Calculate Heat and Mass Transfer In Concrete
Energy Science and Technology Software Center (ESTSC)
1999-05-26
Version 00 This version is designated USINTC and was developed to model the thermal response of concrete to very high heating rates such as might occur from sodium spills on concrete surfaces in a breeder reactor. The major phenomena treated are conductive energy transport; chemical decomposition of concrete; and two-phase, three-component heat and mass transfer of the decomposition products: steam, liquid water, and carbon dioxide. The USINT model provides for porosity to increase as watermore » and carbon-dioxide are formed from the concrete. The concrete is treated generally as divided into two basic regions, wet and dry. In the wet region, steam, carbon-dioxide, and liquid water may co-exist, but in the dry region, there is no liquid water. There is also the possibility of a third region in which there is only liquid water and no gases.« less
Mass transfer of electron acceptor aross the capillary fringe
NASA Astrophysics Data System (ADS)
Liu, S.; Piepenbrink, M.; Grathwohl, P.
2005-12-01
Transverse dispersion has been identified as a potentially limiting parameter controlling the mixing of electron donors and electron acceptors for natural attenuation of plumes originating from continuously emitting sources, however determining reactive transverse dispersion coefficients is not a simple task. The objective of this work is to elaborate the mass transfer of electron acceptor across the capillary fringe. A two-dimensional numerical reactive transport model and a fully controlled tank experiment are set up to investigate the mass transfer across the capillary and reactive fringe, where the oxygen supply is the limiting factor. The tank (77.9 times 14 times 0.8 cm) is made from acrylic-glass and filled with glass beads (0.5-0.75mm). Sodium dithionite, an easily oxidizable compound, is used as a surrogate for contaminants and is continuously injected from the inlets of the tank and reaches a steady state flow. Air circulates on the top of the glass beads. The oxygen concentrations as well as the reactive products (sulfate) are measured at the outlets of the tank with an oxygen sensor and via IC. In addition to that, resazurine, a redox indicator, is added to visualize the redox zones. These two-dimensional experimental results show quantitatively and qualitatively how the oxygen concentrations decrease at the plume fringe. Two dimensional numerical simulations with Min3P predicted oxygen distributions are compared with the experimental results. Acknowledgements: This work was funded by Helmholtz Association and Helmholtz Research Center UFZ; Project: `Virtual Institute for isotope biogeochemistry-biologically mediated processes at geochemical gradients and interfaces in soil - aquifer systems', Contract VH-VI-155.
Devices with extended area structures for mass transfer processing of fluids
TeGrotenhuis, Ward E.; Wegeng, Robert S.; Whyatt, Greg A.; King, David L.; Brooks, Kriston P.; Stenkamp, Victoria S.
2009-04-21
A microchannel device includes several mass transfer microchannels to receive a fluid media for processing at least one heat transfer microchannel in fluid communication with a heat transfer fluid defined by a thermally conductive wall, and at several thermally conductive fins each connected to the wall and extending therefrom to separate the mass transfer microchannels from one another. In one form, the device may optionally include another heat transfer microchannel and corresponding wall that is positioned opposite the first wall and has the fins and the mass transfer microchannels extending therebetween.
NASA Astrophysics Data System (ADS)
Day-Lewis, F. D.; Haggerty, R.; Singha, K.; Binley, A.; Swanson, R. D.; Clifford, J.; Lane, J. W.; Ward, A. L.; Johnson, T. J.
2011-12-01
In both field and laboratory settings, time-lapse electrical measurements have indicated rate-limited mass transfer of ionic tracer between mobile and immobile (or less mobile) domains in porous media over a range of flow rates and time scales. In previous work, a simple bicontinuum extension of Archie's Law was used to relate direct-current bulk conductivity and fluid conductivity assuming that the mobile and immobile domains contribute as conductors in parallel with weights given by porosity fraction; however, other petrophysical models may account for the effect of internal connectivity of each domain on its relative contribution to bulk conductivity. Additional work is required to (1) evaluate the bicontinuum Archie formulation relative to these other models for bulk conductivity of multiphase (i.e., multidomain) media with application to mass-transfer problems, and (2) characterize the geoelectrical signature of mass transfer for porous media with different pore geometries and electrical properties. To address this long standing problem, we developed a coupled fluid flow, electrical conduction, and solute transport simulator for two-dimensional pore networks. The pore space is modeled as a pipe lattice where pipes are square in cross section with widths drawn from random distributions. Pipe conductances for the fluid flow problem are assigned according to Hagen-Pouseuille flow, and the conservation problem is solved. Alternative to computationally intensive simulation of transient advective-dispersive transport, we adopt a more efficient but approximate two-step approach. First, we find the zeroth and first temporal moments throughout the network by solving sequentially two steady-state transport problems; from these results we calculate mean arrival time for each node in the network. Second, we convert the calculated mean arrival times to mass-transfer rates for input to a semi-analytical multi-rate mass transfer model to simulate gross transport through a
About Mass Transfer in Capillaries of Biological Systems under Influence of Vibrations
NASA Astrophysics Data System (ADS)
Prisniakov, K.
Vibrations accompany the flight of the manned spacecraft both at a stage of a orbital injection to an orbit, and during long flights (as noise), rendering undesirable physiological influence on crew, reducing serviceability and creating constant discomfort. The report represents attempt to predict a state of the cosmonaut in conditions of influence of vibrations for the period of start and stay in Space, being based on researches of mass transfer processes in capillary systems. For this purpose the original researches on heat and mass transfer processes with evaporation of liquids in capillary - porous structures in conditions of vibration actions and changes of a direction of action of gravitation are generalized. Report demonstrates the existence of modes at which increased or lowered mass transfer is achieved on border of separation "liquid - gas". The possible mechanism of influence of vibrations on evaporation of a liquid in capillaries is examined. The magnitudes of frequencies and amplitudes are submitted at which minimax characteristics are observed. The opportunity of application of the developed mathematical model of heat and mass transfer in capillary - porous structures to forecasting influence of vibrations for biological processes in capillaries of alive essences is analyzed. Such approach is justified on the mechanical nature of harmful influence of vibrations on an organism of the person. In addition the range of vibration frequencies which arise during space flights, corresponds to own resonant frequencies of a human body and his separate organs. Comparison of these resonant frequencies of a body of the person (5-80 Hertz) with vibration frequencies of optimum modes of heat and mass transfer in capillary - porous structures (20-40 Hertz) is shown their ranges of coverage. It gives the basis to assume existence of similar effects in capillaries of human body. It is supposed, that the difficulty of breath, change of a rhythm of breath, the subsequent
Vadose Zone VOC Mass Transfer Testing At The SRS Miscellaneous Chemical Basin
Riha, B
2005-10-30
Active remedial activities have been ongoing since 1996 to address low levels of solvent contamination at the Miscellaneous Chemical Basin at SRS. Contaminant levels in the subsurface may be approaching levels where mass transfer limitations are impacting the efficiency of the remedial action. Rate limited mass transfer effects have been observed at other sites in the vadose zone at the SRS, however, detailed measurements and evaluation has not been undertaken. Anecdotal evidence suggests that the mass transfer rates are very slow from the fine grain sediments. This conclusion is based on the observation that measured soil gas concentrations tend to be low in permeable zones relative to the higher concentrations found in fine grain zones. Decreasing soil gas concentration with depth below the ''upland unit'' at several areas at SRS is also evidence of slow diffusion rates. In addition, due to the length of time since disposal ceased at the MCB, we hypothesize that mobile solvents have migrated downward, and the solvent remaining in the upper fine grain zone (''upland unit'') are trapped in fine grain material and are primarily released by gas diffusion (Riha and Rossabi 2004). Natural weathering and other chemical solutions disposed with the solvents can further enhance this effect by increasing the micro-porosity in the clays (kaolinite). This microporosity can result in increased entrapment of water and solvents by capillary forces (Powers, et. al., 2003). Also supporting this conclusion is the observation that active SVE has proven ineffective on VOC removal from the fine grain zones at the SRS. Adsorption and the very slow release phenomenon have been documented similarly in the literature especially for old solvent spills such as at the SRS (Pavlostathis and Mathavan 1992; Oostrom and Lenhard 2003). Mass transfer relationships need to be developed in order to optimize remediation activities and to determine actual loading rates to groundwater. These metrics
Mass balance model parameter transferability on a tropical glacier
NASA Astrophysics Data System (ADS)
Gurgiser, Wolfgang; Mölg, Thomas; Nicholson, Lindsey; Kaser, Georg
2013-04-01
The mass balance and melt water production of glaciers is of particular interest in the Peruvian Andes where glacier melt water has markedly increased water supply during the pronounced dry seasons in recent decades. However, the melt water contribution from glaciers is projected to decrease with appreciable negative impacts on the local society within the coming decades. Understanding mass balance processes on tropical glaciers is a prerequisite for modeling present and future glacier runoff. As a first step towards this aim we applied a process-based surface mass balance model in order to calculate observed ablation at two stakes in the ablation zone of Shallap Glacier (4800 m a.s.l., 9°S) in the Cordillera Blanca, Peru. Under the tropical climate, the snow line migrates very frequently across most of the ablation zone all year round causing large temporal and spatial variations of glacier surface conditions and related ablation. Consequently, pronounced differences between the two chosen stakes and the two years were observed. Hourly records of temperature, humidity, wind speed, short wave incoming radiation, and precipitation are available from an automatic weather station (AWS) on the moraine near the glacier for the hydrological years 2006/07 and 2007/08 while stake readings are available at intervals of between 14 to 64 days. To optimize model parameters, we used 1000 model simulations in which the most sensitive model parameters were varied randomly within their physically meaningful ranges. The modeled surface height change was evaluated against the two stake locations in the lower ablation zone (SH11, 4760m) and in the upper ablation zone (SH22, 4816m), respectively. The optimal parameter set for each point achieved good model skill but if we transfer the best parameter combination from one stake site to the other stake site model errors increases significantly. The same happens if we optimize the model parameters for each year individually and transfer
Study on magnetohydrodynamic Kelvin-Helmholtz instability with mass transfer through porous media
NASA Astrophysics Data System (ADS)
Kumar Awasthi, Mukesh
2013-09-01
We study the linear analysis of Kelvin-Helmholtz instability of the interface between two viscous and magnetic fluids in a fully saturated porous medium using viscous potential flow theory, when the fluids are subjected to a constant tangential magnetic field, and when there is heat and mass transfer across the interface. The Darcy-Brinkman model has been used for the investigation. A dispersion relation has been derived and stability is discussed theoretically as well as numerically. The stability criterion is given in terms of a critical value of relative velocity as well as the critical value of applied magnetic field. It has been observed that both tangential magnetic field and vapor fraction have stabilizing effect on the stability of the system while heat and mass transfer destabilizes the interface. Porosity stabilizes the interface while the porous medium has destabilizing effect.
HRD Effectiveness and Transfer of Learning. Symposium.
ERIC Educational Resources Information Center
2002
This document contains three papers from a symposium on human resource development (HRD) effectiveness and transfer of learning. "Factors Affecting Transfer of Training in Thailand" (Siriporn Yamnill, Gary N. McLean) discusses how the Learning Transfer System Inventory was validated in Thailand by administering it to 1,029 employers and analyzing…
Wind mass transfer in S-type symbiotic binaries. II. Indication of wind focusing
NASA Astrophysics Data System (ADS)
Shagatova, N.; Skopal, A.; Cariková, Z.
2016-04-01
Context. The wind mass transfer from a giant to its white dwarf companion in symbiotic binaries is not well understood. For example, the efficiency of wind mass transfer of the canonical Bondi-Hoyle accretion mechanism is too low to power the typical luminosities of the accretors. However, recent observations and modelling indicate a considerably more efficient mass transfer in symbiotic binaries. Aims: We determine the velocity profile of the wind from the giant at the near-orbital-plane region of eclipsing S-type symbiotic binaries EG And and SY Mus, and derive the corresponding spherical equivalent of the mass-loss rate. With this approach, we indicate the high mass transfer ratio. Methods: We achieved this aim by modelling the observed column densities taking into account ionization of the wind of the giant, whose velocity profile is derived using the inversion of Abel's integral operator for the hydrogen column density function. Results: Our analysis revealed the spherical equivalent of the mass-loss rate from the giant to be a few times 10-6 M⊙ yr-1, which is a factor of ≳10 higher than rates determined by methods that do not depend on the line of sight. This discrepancy rules out the usual assumption that the wind is spherically symmetric. As our values were derived from near-orbital-plane column densities, these values can be a result of focusing the wind from the giant towards the orbital plane. Conclusions: Our findings suggests that the wind from giants in S-type symbiotic stars is not spherically symmetric, since it is enhanced at the orbital plane and, thus, is accreted more effectively onto the hot component.
Numerical simulations of heat and mass transfer at ablating surface in hypersonic flow
NASA Astrophysics Data System (ADS)
Bocharov, A. N.; Golovin, N. N.; Petrovskiy, V. P.; Teplyakov, I. O.
2015-11-01
The numerical technique was developed to solve heat and mass transfer problem in 3D hypersonic flow taking into account destruction of thermal protection system. Described technique was applied for calculation of heat and mass transfer in sphere-cone shaped body. The data on temperature, heat flux and mass flux were obtained.
Study on Electrohydrodynamic Rayleigh-Taylor Instability with Heat and Mass Transfer
Awasthi, Mukesh Kumar; Srivastava, Vineet K.
2014-01-01
The linear analysis of Rayleigh-Taylor instability of the interface between two viscous and dielectric fluids in the presence of a tangential electric field has been carried out when there is heat and mass transfer across the interface. In our earlier work, the viscous potential flow analysis of Rayleigh-Taylor instability in presence of tangential electric field was studied. Here, we use another irrotational theory in which the discontinuities in the irrotational tangential velocity and shear stress are eliminated in the global energy balance. Stability criterion is given by critical value of applied electric field as well as critical wave number. Various graphs have been drawn to show the effect of various physical parameters such as electric field, heat transfer coefficient, and vapour fraction on the stability of the system. It has been observed that heat transfer and electric field both have stabilizing effect on the stability of the system. PMID:24526897
Study on electrohydrodynamic Rayleigh-Taylor instability with heat and mass transfer.
Awasthi, Mukesh Kumar; Srivastava, Vineet K
2014-01-01
The linear analysis of Rayleigh-Taylor instability of the interface between two viscous and dielectric fluids in the presence of a tangential electric field has been carried out when there is heat and mass transfer across the interface. In our earlier work, the viscous potential flow analysis of Rayleigh-Taylor instability in presence of tangential electric field was studied. Here, we use another irrotational theory in which the discontinuities in the irrotational tangential velocity and shear stress are eliminated in the global energy balance. Stability criterion is given by critical value of applied electric field as well as critical wave number. Various graphs have been drawn to show the effect of various physical parameters such as electric field, heat transfer coefficient, and vapour fraction on the stability of the system. It has been observed that heat transfer and electric field both have stabilizing effect on the stability of the system. PMID:24526897
Proton transfer reaction-mass spectrometry applications in medical research.
Herbig, Jens; Amann, Anton
2009-06-01
Gathering information about a subject's physiological and pathophysiological condition from the `smell' of breath is an idea that dates back to antiquity. This intriguing concept of non-invasive diagnosis has been revitalized by `exhaled breath analysis' in recent decades. A main driving force was the development of sensitive and versatile gas-chromatographic and mass-spectrometric instruments for trace gas analysis. Ironically, only non-smelling constituents of breath, such as O(2), CO(2), H(2), and NO have so far been included in routine clinical breath analysis. The `smell' of human breath, on the other hand, arises through a combination of volatile organic compounds (VOCs) of which several hundred have been identified to date. Most of these volatiles are systemic and are released in the gas-exchange between blood and air in the alveoli. The concentration of these compounds in the alveolar breath is related to the respective concentrations in blood. Measuring VOCs in exhaled breath allows for screening of disease markers, studying the uptake and effect of medication (pharmacokinetics), or monitoring physiological processes. There is a range of requirements for instruments for the analysis of a complex matrix, such as human breath. Mass-spectrometric techniques are particularly well suited for this task since they offer the possibility of detecting a large variety of interesting compounds. A further requirement is the ability to measure accurately in the concentration range of breath VOCs, i.e. between parts-per-trillion (pptv) and parts-per-million (ppmv) range. In the mid 1990's proton transfer reaction-mass spectrometry (PTR-MS) was developed as a powerful and promising tool for the analysis of VOCs in gaseous media. Soon thereafter these instruments became commercially available to a still growing user community and have now become standard equipment in many fields including environmental research, food and flavour science, as well as life sciences. Their
Karimi, Ali; Golbabaei, Farideh; Mehrnia, Momammad Reza; Neghab, Masoud; Mohammad, Kazem; Nikpey, Ahmad; Pourmand, Mohammad Reza
2013-01-01
In this study, a miniature stirred tank bioreactor was designed for treatment of waste gas containing benzene, toluene and xylene. Oxygen mass transfer characteristics for various twin and single-impeller systems were investigated for 6 configurations in a vessel with 10 cm of inner diameter and working volume of 1.77L. Three types of impellers, namely, Rushton turbine, Pitched 4blades and Pitched 2blades impellers with downward pumping have been used. Deionized water was used as a liquid phase. With respect to other independent variables such as agitation speed, aeration rate, type of sparger, number of impellers, the relative performance of these impellers was assessed by comparing the values of (KLa) as a key parameter. Based on the experimental data, empirical correlations as a function of the operational conditions have been proposed, to study the oxygen transfer rates from air bubbles generated in the bioreactor. It was shown that twin Rushton turbine configuration demonstrates superior performance (23% to 77% enhancement in KLa) compared with other impeller compositions and that sparger type has negligible effect on oxygen mass transfer rate. Agitation speeds of 400 to 800 rpm were the most efficient speeds for oxygen mass transfer in the stirred bioreactor. PMID:23369581
2013-01-01
In this study, a miniature stirred tank bioreactor was designed for treatment of waste gas containing benzene, toluene and xylene. Oxygen mass transfer characteristics for various twin and single-impeller systems were investigated for 6 configurations in a vessel with 10 cm of inner diameter and working volume of 1.77L. Three types of impellers, namely, Rushton turbine, Pitched 4blades and Pitched 2blades impellers with downward pumping have been used. Deionized water was used as a liquid phase. With respect to other independent variables such as agitation speed, aeration rate, type of sparger, number of impellers, the relative performance of these impellers was assessed by comparing the values of (KLa) as a key parameter. Based on the experimental data, empirical correlations as a function of the operational conditions have been proposed, to study the oxygen transfer rates from air bubbles generated in the bioreactor. It was shown that twin Rushton turbine configuration demonstrates superior performance (23% to 77% enhancement in KLa) compared with other impeller compositions and that sparger type has negligible effect on oxygen mass transfer rate. Agitation speeds of 400 to 800 rpm were the most efficient speeds for oxygen mass transfer in the stirred bioreactor. PMID:23369581
Mass Transfer of Phosphorus in Silicon Melts Under Vacuum Induction Refining
NASA Astrophysics Data System (ADS)
Zheng, Song-Sheng; Chen, Wen-Hui; Cai, Jing; Li, Jin-Tang; Chen, Chao; Luo, Xue-Tao
2010-12-01
An experimental investigation into the mass transfer of phosphorus in molten silicon under vacuum induction refining has been carried out. In a pilot-scale experiment, in the temperature range 1773 K (1500 °C) to 1873 K (1600 °C) and a vacuum of 0.1 to 0.035 Pa smelting for 7200 seconds (2 hours), phosphorus is decreased from 15 ppmw to 0.08 ppmw, which achieved the target for solar-grade silicon of less than 0.1 ppmw. Lab-scale experiments are used to determine the effects of vacuum, refining time, and temperature on the rate of mass transfer of phosphorus during vacuum refining. Hardly any phosphorus was removed when the vacuum pressure is greater than 100 Pa. Mass-transfer coefficients are nearly independent of pressure at 1783 K (1510 °C) when pressures are below 0.1 Pa and are highly correlated with vacuum pressures above 0.1 Pa. A model of vacuum refining of inductively stirred silicon melts is discussed to explain the transfer path of phosphorus out of the melt.
Estimation of mass transfer and kinetics in operating biofilters for removal of VOCs
Barton, J.W.; Davison, B.H.; Gable, C.C.
1997-11-18
Long-term, stable operation of trickle-bed bioreactors remains desirable, but is difficult to achieve for industrial processes, which generate continuous streams of dilute gaseous hydrocarbons. Mass transfer and kinetic parameters are difficult to measure, complicating predictive estimates. Two methods are presented which were used to predict the importance of mass transfer versus kinetics limitations in operating trickle-bed biofilters. Both methods altered the overall kinetic activity of the biofilter and estimated the effective mass transfer coefficient (K{sub 1}a) by varying the VOC (volatile organic contaminant) loading rate and concentration. The first method, used with developing biofilters possessing low biomass, involved addition of cultured biomass to the recirculating liquid to effect an overall change in VOC removal capacity. The second method altered the total bed temperature of a well-established biofilter to effect a change. Results and modeling from these experiments are presented for a mixed culture biofilter which is capable of consuming sparingly soluble alkanes, such as pentane and isobutane. Methods to control overgrowth are discussed which were used to operate one reactor continuously for over 24 months with sustained degradation of VOC alkanes with a rate of 50 g/h/m{sup 3}.
Numerical Simulations of the Onset and Stability of Dynamical Mass Transfer in Binaries
NASA Astrophysics Data System (ADS)
D'Souza, Mario C. R.; Motl, Patrick M.; Tohline, Joel E.; Frank, Juhan
2006-05-01
Hydrodynamical simulations of semidetached, polytropic binary stars are presented in an effort to study the onset and stability of dynamical mass transfer events. Initial, synchronously rotating equilibrium models are constructed using a self-consistent field technique and then evolved with an Eulerian hydrodynamics code in a fully self-consistent manner. We describe code improvements introduced over the past few years that permit us to follow dynamical mass transfer events through more than 30 orbits. Mass transfer evolutions are presented for two different initial configurations: a dynamically unstable binary with initial mass ratio (donor/accretor) q0=1.3 that leads to a complete merger in ~10 orbits, and a double-degenerate binary with initial mass ratio q0=0.5 that, after some initial unstable growth of mass transfer, tends to separate as the mass transfer rate levels off.
Direct Geoelectrical Evidence of Mass Transfer at the Lab scale
NASA Astrophysics Data System (ADS)
Swanson, R. D.; Singha, K.; Day-Lewis, F. D.; Keating, K.; Binley, A.; Clifford, J.; Haggerty, R.
2011-12-01
At many field sites, anomalous tailing behavior-- a long, slow decrease of solute concentration in time-- is observed yet cannot be explained with the advection-dispersion model. One explanation for this commonly observed behavior is the exchange of solute between mobile and immobile domains; however, direct experimental observations of this controlling process remain elusive. Circumstantial evidence for a less-mobile phase is typically inferred from tailing behavior observed in fluid samples of the mobile phase. Electrical methods provide a measure of the total solutes in both the immobile and mobile domain and therefore have been hypothesized to provide, in combination with fluid sampling, direct experimental evidence for a less-mobile and mobile model, yet experimental evidence is needed to support this claim. Here, we conduct column solute tracer tests and measure both electrical resistivity and fluid conductivity on unconsolidated, well-sorted sand in addition to fine and coarse fractions of the porous zeolite clinoptilolite. We examine nearly co-located time-lapse standard fluid conductivity and bulk apparent resistivity measurements to identify solute exchange between multiple domains at the lab scale. Our results show extensive tailing behavior in both fluid and bulk electrical conductivity measurements in the zeolite but not in sand, providing evidence for a mobile-immobile framework. Transport parameters are estimated by minimizing the root-mean-square error between the observed and simulated fluid conductivity in COMSOL Multiphysics. These best-fit parameters support our claims of mass transfer occurring in the zeolite columns and provide the first direct electrical evidence of dual-domain mass transport at the lab scale.
Micro-scale mass-transfer variations during electrodeposition
Sutija, D.P.
1991-08-01
Results of two studies on micro-scale mass-transfer enhancement are reported: (1) Profiled cross-sections of striated zinc surfaces deposited in laminar channel flow were analyzed with fast-fourier transforms (FFT) to determine preferred striation wavelengths. Striation frequency increases with current density until a minimum separation between striae of 150 {mu}m is reached. Beyond this point, independent of substrate used, striae meld together and form a relatively smooth, nodular deposit. Substrates equipped with artificial micron-sized protrusions result in significantly different macro-morphology in zinc deposits. Micro-patterned electrodes (MPE) with hemispherical protrusions 5 {mu}m in diameter yield thin zinc striae at current densities that ordinarily produce random nodular deposits. MPEs with artificial hemi-cylinders, 2.5 {mu}m in height and spaced 250 {mu}m apart, form striae with a period which matches the spacing of micron-sized ridges. (2) A novel, corrosion-resistant micromosaic electrode was fabricated on a silicon wafer. Measurements of mass-transport enhancement to a vertical micromosaic electrode caused by parallel bubble streams rising inside of the diffusion boundary-layer demonstrated the presence of two co-temporal enhancement mechanisms: surface-renewal increases the limiting current within five bubble diameters of the rising column, while bubble-induced laminar flows cause weaker enhancement over a much broader swath. The enhancement caused by bubble curtains is predicted accurately by linear superposition of single-column enhancements. Two columns of smaller H{sub 2} bubbles generated at the same volumetric rate as a single column of larger bubbles cause higher peak and far-field enhancements. 168 refs., 96 figs., 6 tabs.
Chen, Dong-Zhi; Fang, Jun-Yi; Shao, Qian; Ye, Jie-Xu; Ouyang, Du-Juan; Chen, Jian-Meng
2013-07-01
A novel entrapment matrix, calcium alginate (CA) coupled with activated carbon fiber (ACF), was prepared to immobilize Pseudomonas oleovorans DT4 for degrading tetrahydrofuran (THF). The addition of 1.5% ACF increased the adsorption capacity of the immobilized bead, thus resulting in an enhanced average removal rate of 30.3mg/(Lh). The synergism between adsorption and biodegradation was observed in the hybrid CA-ACF beads instead of in the system comprising CA beads and freely suspended ACF. The effective diffusion coefficient of the CA-ACF bead was not significantly affected by bead size, but the bead's value of 1.14×10(-6)cm(2)/s (for the bead diameter of 0.4 cm) was larger than that of the CA bead by almost one order of magnitude based on the intraparticle diffusion-reaction kinetics analysis. Continuous treatment of the THF-containing wastewater was succeeded by CA-ACF immobilized cells in a packed-bed reactor for 54 d with a >90% removal efficiency. PMID:23644074
Heat and mass transfer at adiabatic evaporation of binary zeotropic solutions
NASA Astrophysics Data System (ADS)
Makarov, M. S.; Makarova, S. N.
2016-01-01
Results of numerical simulation of heat and mass transfer in a laminar flow of three-component gas at adiabatic evaporation of binary solutions from a flat plate are presented. The studies were carried out for the perfect solution of ethanol/methanol and zeotrope solutions of water/acetone, benzene/acetone, and ethanol/acetone. The liquid-vapor equilibrium is described by the Raoult law for the ideal solution and Carlson-Colburn model for real solutions. The effect of gas temperature and liquid composition on the heat and diffusion flows, and temperature of vapor-gas mixture at the interface is analyzed. The formula for calculating the temperature of the evaporation surface for the binary liquid mixtures using the similarity of heat and mass transfer was proposed. Data of numerical simulations are in a good agreement with the results of calculations based on the proposed dependence for all examined liquid mixtures in the considered range of temperatures and pressures.
Busigin, A.
2015-03-15
Liquid Phase Catalytic Exchange (LPCE) is a key technology used in water detritiation systems. Rigorous simulation of LPCE is complicated when a column may have both hydrogen and deuterium present in significant concentrations in different sections of the column. This paper presents a general mass transfer model for a homogenous packed bed LPCE column as a set of differential equations describing composition change, and equilibrium equations to define the mass transfer driving force within the column. The model is used to show the effect of deuterium buildup in the bottom of an LPCE column from non-negligible D atom fraction in the bottom feed gas to the column. These types of calculations are important in the design of CECE (Combined Electrolysis and Catalytic Exchange) water detritiation systems.
Bioremediation of solid TNT particles in a soil slurry reactor: Mass transfer considerations
Gilcrease, P.C.; Murphy, V.G.; Reardon, K.F.
1996-12-31
The bioreduction of solid TNT by a Pseudomonas fluorescens strain was investigated in a stirred tank reactor. Experiments in which TNT beads were the only solids present indicated that the biodegradation mechanism is dissolution followed by degradation in bulk solution. Dissolution may limit the overall rate, in which case degradation can be enhanced through increased agitation. Since soil slurries may contain high concentrations of solids other than TNT, Teflon chips were added to investigate two separate effects on TNT dissolution in slurries. First, Teflon solids increase the viscosity of the slurry, resulting in lower solid-liquid mass transfer coefficients. Second, the agitated Teflon slurry can grind or comminute TNT particles, creating additional surface area for mass transfer. Enhanced dissolution rates were observed for TNT beads in a Teflon slurry at higher agitator speeds. This suggests that the biodegradation of solid TNT nuggets in a soil slurry bioreactor may be enhanced under conditions that promote particle attrition.
NASA Astrophysics Data System (ADS)
Ganapathirao, M.; Ravindran, R.; Momoniat, E.
2015-02-01
The purpose of this work is to study the effects of chemical reaction, heat and mass transfer on an unsteady mixed convection boundary layer flow over a vertical wedge with heat generation/absorption in the presence of uniform suction or injection. The fluid is assumed to be viscous and incompressible. The unsteadiness is caused by the time dependent free stream velocity varying arbitrarily with time. Both accelerating and decelerating free stream flows are considered. Non-similar solutions are obtained numerically by using an implicit finite difference scheme in combination with the quasi-linearization technique. Numerical computations are carried out for different values of dimensionless parameters on velocity, temperature and concentration profiles graphically reported in the present study. Also, numerical results are presented for the local skin friction coefficient, the local Nusselt number and the local Sherwood number. Results indicate that the time effect is crucial on velocity, temperature and concentration profiles, and on the local skin friction coefficient, the local Nusselt and Sherwood numbers. The buoyancy assisting force causes overshoot in the velocity profile for lower Prandtl number fluids. Results are compared with previously published work and are found to be in an excellent agreement.
Biological conversion of synthesis gas. Mass transfer/kinetic studies
Klasson, K.T.; Basu, R.; Johnson, E.R.; Clausen, E.C.; Gaddy, J.L.
1992-03-01
Mass transfer and kinetic studies were carried out for the Rhodospirillum rubrum and Chlorobium thiosulfatophilum bacterial systems. R. rubrum is a photosynthetic anaerobic bacterium which catalyzes the biological water gas shift reaction: CO + H{sub 2}0 {yields} CO{sub 2} + H{sub 2}. C. thiosulfatophilum is also a H{sub 2}S and COS to elemental sulfur. The growth of R. rubrum may be satisfactorily carried out at 25{degree} and 30{degree}C, while CO uptake and thus the conversion of CO best occurs at temperatures of either 30{degree}, 32{degree} or 34{degree}C. The rate of conversion of COs and H{sub 2}O to CO{sub 2} and H{sub 2}S may be modeled by a first order rate expression. The rate constant at 30{degree}C was found to be 0.243 h{sup {minus}1}. The growth of C. thiosulfatophilum may be modeled in terms of incoming light intensity using a Monod equation: {mu} = {sub 351} + I{sub o}/{sup 0.152}I{sub o}. Comparisons of the growth of R. rubrum and C. thiosulfatophilum shows that the specific growth rate of C. thiosulfatophilum is much higher at a given light intensity.
Improved oxygen mass transfer modeling for diffused or subsurface aeration systems
McWhirter, J.R.; Hutter, J.C. . Dept. of Chemical Engineering)
1988-01-01
The mass transfer analysis of the oxygen transfer performance of diffused air or subsurface mechanical aeration systems has progressed very little over the past twenty years. The ASCE Standard Method for determination of the oxygen mass transfer performance as applied to a diffused or subsurface aeration systems is based on a greatly over-simplified mass transfer model. Although the ASCE Standard can be used to empirically evaluate point performance conditions, it is not suitable for prediction of the performance of diffused aeration systems under changing operating or environmental conditions. A new oxygen mass transfer model has been developed which is a fundamentally more rigorous description of the actual mass transfer process in diffused aeration systems. This model can be confidently used to predict aerator performance under changing operation and environmental conditions and is easily adapted to numerical solution on a computer for routing aeration system performance evaluation as well as process design. The model is presented in this book.
Close binary systems before and after mass transfer. III - Spectroscopic binaries
NASA Astrophysics Data System (ADS)
Vansina, F.; De Greve, J. P.
1982-10-01
A method is presented, for the computation of absolute dimensions from spectroscopic data on binary systems, which has been adapted for use with the 7th Catalogue of Batten et al. (1978) and takes into account several results of close binary evolution, with emphasis on the phase of slow mass transfer during a case B mass transfer. Among the unevolved systems, the mass transfer case B is found to be the most abundant type of interaction. In the set of evolving systems, a subset of 18 interacting systems was found with mass ratio near unity, the first star being the mass loser as well as the brightest.
Modelling mass and heat transfer in nano-based cancer hyperthermia
Nabil, M.; Decuzzi, P.; Zunino, P.
2015-01-01
We derive a sophisticated mathematical model for coupled heat and mass transport in the tumour microenvironment and we apply it to study nanoparticle delivery and hyperthermic treatment of cancer. The model has the unique ability of combining the following features: (i) realistic vasculature; (ii) coupled capillary and interstitial flow; (iii) coupled capillary and interstitial mass transfer applied to nanoparticles; and (iv) coupled capillary and interstitial heat transfer, which are the fundamental mechanisms governing nano-based hyperthermic treatment. This is an improvement with respect to previous modelling approaches, where the effect of blood perfusion on heat transfer is modelled in a spatially averaged form. We analyse the time evolution and the spatial distribution of particles and temperature in a tumour mass treated with superparamagnetic nanoparticles excited by an alternating magnetic field. By means of numerical experiments, we synthesize scaling laws that illustrate how nano-based hyperthermia depends on tumour size and vascularity. In particular, we identify two distinct mechanisms that regulate the distribution of particle and temperature, which are characterized by perfusion and diffusion, respectively. PMID:26587251
Yao, Ye
2016-07-01
The physical mechanisms of heat and mass transfer enhancement by ultrasound have been identified by people. Basically, the effect of 'cavitation' induced by ultrasound is the main reason for the enhancement of heat and mass transfer in a liquid environment, and the acoustic streaming and vibration are the main reasons for that in a gaseous environment. The adsorbent regeneration and food drying/dehydration are typical heat and mass transfer process, and the intensification of the two processes by ultrasound is of complete feasibility. This paper makes an overview on recent studies regarding applications of power ultrasound to adsorbent regeneration and food drying/dehydration. The concerned adsorbents include desiccant materials (typically like silica gel) for air dehumidification and other ones (typically active carbon and polymeric resin) for water treatment. The applications of ultrasound in the regeneration of these adsorbents have been proved to be energy saving. The concerned foods are mostly fruits and vegetables. Although the ultrasonic treatment may cause food degradation or nutrient loss, it can greatly reduce the food processing time and decrease drying temperature. From the literature, it can be seen that the ultrasonic conditions (i.e., acoustic frequency and power levels) are always focused on during the study of ultrasonic applications. The increasing number of relevant studies argues that ultrasound is a very promising technology applied to the adsorbent regeneration and food drying/dehydration. PMID:26964979
Application and limitations of a mass transfer VOC emission model for a dry building material
NASA Astrophysics Data System (ADS)
Crawford, S.; Lungu, C. T.
2013-12-01
Volatile organic compound (VOC) emission from building materials into air has been quantified, characterized and modeled. Internal diffusion of VOC through a material based on Fick's law of diffusion is the basis for mass transfer modeling of diffusive emission used to estimate VOC concentrations in air over time. Current mass transfer models have been shown to appropriately estimate air VOC concentrations at approximate room temperature, while other research has shown that temperature has a profound effect on the diffusion coefficient, D, of VOC in a material. Here, a mass transfer model is operated at 23 °C and 40 °C using input parameters applicable for each temperature. The model estimates are validated against environmental test chamber data for styrene emission from a vinyl ester resin thermoset composite material. The model correlates well with the 23 °C chamber data, but underestimates chamber data by as much as 10-4 at 264 h for the 40 °C modeling. This suggests that the model requires adjustment for predicting VOC air concentrations at temperatures other than 23 °C.
Modelling mass and heat transfer in nano-based cancer hyperthermia.
Nabil, M; Decuzzi, P; Zunino, P
2015-10-01
We derive a sophisticated mathematical model for coupled heat and mass transport in the tumour microenvironment and we apply it to study nanoparticle delivery and hyperthermic treatment of cancer. The model has the unique ability of combining the following features: (i) realistic vasculature; (ii) coupled capillary and interstitial flow; (iii) coupled capillary and interstitial mass transfer applied to nanoparticles; and (iv) coupled capillary and interstitial heat transfer, which are the fundamental mechanisms governing nano-based hyperthermic treatment. This is an improvement with respect to previous modelling approaches, where the effect of blood perfusion on heat transfer is modelled in a spatially averaged form. We analyse the time evolution and the spatial distribution of particles and temperature in a tumour mass treated with superparamagnetic nanoparticles excited by an alternating magnetic field. By means of numerical experiments, we synthesize scaling laws that illustrate how nano-based hyperthermia depends on tumour size and vascularity. In particular, we identify two distinct mechanisms that regulate the distribution of particle and temperature, which are characterized by perfusion and diffusion, respectively. PMID:26587251
Miano, Alberto Claudio; Ibarz, Albert; Augusto, Pedro Esteves Duarte
2016-03-01
The aim of this work was to demonstrate how ultrasound mechanisms (direct and indirect effects) improve the mass transfer phenomena in food processing, and which part of the process they are more effective in. Two model cases were evaluated: the hydration of sorghum grain (with two water activities) and the influx of a pigment into melon cylinders. Different treatments enabled us to evaluate and discriminate both direct (inertial flow and "sponge effect") and indirect effects (micro channel formation), alternating pre-treatments and treatments using an ultrasonic bath (20 kHz of frequency and 28 W/L of volumetric power) and a traditional water-bath. It was demonstrated that both the effects of ultrasound technology are more effective in food with higher water activity, the micro channels only forming in moist food. Moreover, micro channel formation could also be observed using agar gel cylinders, verifying the random formation of these due to cavitation. The direct effects were shown to be important in mass transfer enhancement not only in moist food, but also in dry food, this being improved by the micro channels formed and the porosity of the food. In conclusion, the improvement in mass transfer due to direct and indirect effects was firstly discriminated and described. It was proven that both phenomena are important for mass transfer in moist foods, while only the direct effects are important for dry foods. Based on these results, better processing using ultrasound technology can be obtained. PMID:26585022
Effective Masses of Vector Polarons
NASA Astrophysics Data System (ADS)
Foell, Charles; Clougherty, Dennis
2006-03-01
We consider the vector polarons of a one-dimensional model of an electron in a doubly (or nearly) degenerate band that couples to two elastic distortions, as described previously by Clougherty and Foell [1]. A variational approach is used to analytically and numerically calculate effective masses of the three types of vector polarons. [1] D. P. Clougherty and C. A. Foell, Phys. Rev. B 70, 052301 (2004).
Miller, W.A.
1999-03-24
Experiments were conducted in a laboratory to investigate the absorption of water vapor into a falling-film of aqueous lithium bromide (LiBr). A mini-absorber test stand was used to test smooth tubes and a variety of advanced tube surfaces placed horizontally in a single-row bundle. The bundle had six copper tubes; each tube had an outside diameter of 15.9-mm and a length of 0.32-m. A unique feature of the stand is its ability to operate continuously and support testing of LiBr brine at mass fractions {ge} 0.62. The test stand can also support testing to study the effect of the failing film mass flow rate, the coolant mass flow rate, the coolant temperature, the absorber pressure and the tube spacing. Manufacturers of absorption chillers add small quantities of a heat and mass transfer additive to improve the performance of the absorbers. The additive causes surface stirring which enhances the transport of absorbate into the bulk of the film. Absorption may also be enhanced with advanced tube surfaces that mechanically induce secondary flows in the falling film without increasing the thickness of the film. Several tube geometry's were identified and tested with the intent of mixing the film and renewing the interface with fresh solution from the tube wall. Testing was completed on a smooth tube and several different externally enhanced tube surfaces. Experiments were conducted over the operating conditions of 6.5 mm Hg absorber pressure, coolant temperatures ranging from 20 to 35 C and LiBr mass fractions ranging from 0.60 through 0.62. Initially the effect of tube spacing was investigated for the smooth tube surface, tested with no heat and mass transfer additive. Test results showed the absorber load and the mass absorbed increased as the tube spacing increased because of the improved wetting of the tube bundle. However, tube spacing was not a critical factor if heat and mass transfer additive was active in the mini-absorber. The additive dramatically affected
Guo, Xin; Yao, Lishan; Huang, Qingshan
2015-08-01
Effects of superficial gas velocity and top clearance on gas holdup, liquid circulation velocity, mixing time, and mass transfer coefficient are investigated in a new airlift loop photobioreactor (PBR), and empirical models for its rational control and scale-up are proposed. In addition, the impact of top clearance on hydrodynamics, especially on the gas holdup in the internal airlift loop reactor, is clarified; a novel volume expansion technique is developed to determine the low gas holdup in the PBR. Moreover, a model strain of Chlorella vulgaris is cultivated in the PBR and the volumetric power is analyzed with a classic model, and then the aeration is optimized. It shows that the designed PBR, a cost-effective reactor, is promising for the mass cultivation of microalgae. PMID:25958141
Model of neutrino effective masses
Dinh Nguyen Dinh; Nguyen Thi Hong Van; Nguyen Anh Ky; Phi Quang Van
2006-10-01
It is shown that an effective (nonrenormalizable) coupling of lepton multiplets to scalar triplets in the 331 model with sterile/exotic neutrinos, can be a good way for generating neutrino masses of different types. The method is simple and avoids radiative/loop calculations which, sometimes, are long and complicated. Basing on some astrophysical arguments it is also stated that the scale of SU(3){sub L} symmetry breaking is at TeV scale, in agreement with earlier investigations. Or equivalently, starting from this symmetry breaking scale we could have sterile/exotic neutrinos with mass of a few keV's which could be used to explain several astrophysical and cosmological puzzles, such as the dark matter, the fast motion of the observed pulsars, the re-ionization of the Universe, etc.
Simultaneous Heat and Mass Transfer Model for Convective Drying of Building Material
NASA Astrophysics Data System (ADS)
Upadhyay, Ashwani; Chandramohan, V. P.
2016-06-01
A mathematical model of simultaneous heat and moisture transfer is developed for convective drying of building material. A rectangular brick is considered for sample object. Finite-difference method with semi-implicit scheme is used for solving the transient governing heat and mass transfer equation. Convective boundary condition is used, as the product is exposed in hot air. The heat and mass transfer equations are coupled through diffusion coefficient which is assumed as the function of temperature of the product. Set of algebraic equations are generated through space and time discretization. The discretized algebraic equations are solved by Gauss-Siedel method via iteration. Grid and time independent studies are performed for finding the optimum number of nodal points and time steps respectively. A MATLAB computer code is developed to solve the heat and mass transfer equations simultaneously. Transient heat and mass transfer simulations are performed to find the temperature and moisture distribution inside the brick.
Mass Transfer from Gas Bubbles to Impinging Flow of Biological Fluids with Chemical Reaction
Yang, Wen-Jei; Echigo, R.; Wotton, D. R.; Ou, J. W.; Hwang, J. B.
1972-01-01
The rates of mass transfer from a gas bubble to an impinging flow of a biological fluid such as whole blood and plasma are investigated analytically and experimentally. Gases commonly found dissolved in body fluids are included. Consideration is given to the effects of the chemical reaction between the dissolved gas and the liquid on the rate of mass transfer. Through the application of boundary layer theory the over-all transfer is found to be Sh/(Re)1/2 = 0.845 Sc1/3 in the absence of chemical reaction, and Sh/(Re) 1/2 = F′ (0) in the presence of chemical reaction, where Sh, Re, and Sc are the Sherwood, Reynolds, and Schmidt numbers, respectively, and F′ (0) is a function of Sc and the dimensionless reaction rate constant. Analytical results are also obtained for the bubble lifetime and the bubble radius-time history. These results, which are not incompatible with experimental results, can be applied to predict the dissolution of the entrapped gas emboli in the circulatory system of the human body. PMID:4642218
Ungerman, Andrew J; Heindel, Theodore J
2007-01-01
This study compares the power demand and gas-liquid volumetric mass transfer coefficient, kLa, in a stirred tank reactor (STR) (T = 0.211 m) using different impeller designs and schemes in a carbon monoxide-water system, which is applicable to synthesis gas (syngas) fermentation. Eleven different impeller schemes were tested over a range of operating conditions typically associated with the "after large cavity" region (ALC) of a Rushton-type turbine (D/T = 0.35). It is found that the dual Rushton-type impeller scheme exhibits the highest volumetric mass transfer rates for all operating conditions; however, it also displays the lowest mass transfer performance (defined as the volumetric mass transfer coefficient per unit power input) for all conditions due to its high power consumption. Dual impeller schemes with an axial flow impeller as the top impeller show improved mass transfer rates without dramatic increases in power draw. At high gas flow rates, dual impeller schemes with a lower concave impeller have kLa values similar to those of the Rushton-type dual impeller schemes but show improved mass transfer performance. It is believed that the mass transfer performance can be further enhanced for the bottom concave impeller schemes by operating at conditions beyond the ALC region defined for Rushton-type impellers because the concave impeller can handle higher gas flow rates prior to flooding. PMID:17326659
Gritti, Fabrice; Guiochon, Georges A
2010-01-01
Band broadening in chromatography results from the combination of the dispersive effects that are associated with the different steps involved in the migration of compound bands along the column. These steps include longitudinal diffusion, trans-particle mass transfer, external film mass transfer, overall eddy diffusion, including trans-column, short-range inter-channel, trans-channel eddy diffusion, and the possible, additional mass transfer contributions arising from heat friction and the thermal heterogeneity of the column. We describe a series of experiments that provide the data needed to determine the coefficients of the contributions to band broadening of each one of these individual mass transfer steps. This specifically designed protocol can provide key information regarding the kinetic performance of columns used in liquid chromatography and explain why different columns behave so differently. The limitations, accuracy and precision of these methods are discussed. Further avenues of research that could improve the characterization of the mass transfer mechanisms in chromatographic columns, possibly contributing to the development of better columns, are suggested.
Physical modeling of liquid/liquid mass transfer in gas stirred ladles
NASA Astrophysics Data System (ADS)
Kim, Seon-Hyo; Fruehan, R. J.
1987-06-01
Several of the metallurgical reactions occurring in gas stirred steel ladles are controlled by liquid phase mass transfer between the metal and slag. In order to calculate the rate of these reactions, information about the two phase mass transfer parameter is necessary. The mass transfer between two immiscible liquids, oil and water simulating slag and steel, respectively, was measured in a scale model of a ladle. The mass transferred species was thymol which has an equilibrium partition ratio between oil and water similar to that for sulfur between slag and metal. The mass transfer rate was measured as a function of gas flow rate, tuyere position and size, method of injection, oil viscosity, and oil/water volume ratio. In addition, mixing times in the presence of the oil layer and mass transfer coefficient for the dissolution of solid benzoic acid rods were measured. The results show that there are three gas flow rate regimes in which the dependence of mass transfer on gas flow rate is different. At a critical gas flow rate, the oil layer breaks into droplets which are entrained into the water, resulting in an increase in the two phase interfacial area. This critical gas flow rate was found to be a function of tuyere position, oil volume, densities of two phases, and interfacial tension. Two phase mass transfer for a lance and a tuyere was found to be the same for the same stirring energy in low energy regions regardless of lance depth. Mass transfer is faster for a center tuyere as compared to an offcenter tuyere, but mixing times are smaller for the offcenter tuyere. From the results obtained, the optimum stirring conditions for metallurgical reactions are qualitatively discussed.
Herek L. Clack
2006-06-01
Electrostatic precipitation is the dominant method of particulate control used for coal combustion, and varying degrees of mercury capture and transformation have been reported across ESPs. Nevertheless, the fate of gas-phase mercury within an ESP remains poorly understood. The present analysis focuses on the gas-particle mass transfer that occurs within a charged aerosol in an ESP. As a necessary step in gas-phase mercury adsorption or transformation, gas-particle mass transfer - particularly in configurations other than fixed beds - has received far less attention than studies of adsorption kinetics. Our previous analysis showed that only a small fraction of gas-phase mercury entering an ESP is likely to be adsorbed by collected particulate matter on the plate electrodes. The present simplified analysis provides insight into gas-particle mass transfer within an ESP under two limiting conditions: laminar and turbulent fluid flows. The analysis reveals that during the process of particulate collection, gas-particle mass transfer can be quite high, easily exceeding the mass transfer to ESP plate electrodes in most cases. Decreasing particle size, increasing particle mass loading, and increasing temperature all result in increased gas-particle mass transfer. The analysis predicts significantly greater gas-particle mass transfer in the laminar limit than in the turbulent limit; however, the differences become negligible under conditions where other factors, such as total mass of suspended particulates, are the controlling mass transfer parameters. Results are compared to selected pilot- and full-scale sorbent injection data. 41 refs., 5 figs.
LY Aurigua: A mass-transferring O-type contact binary with a tertiary stellar companion
NASA Astrophysics Data System (ADS)
Zhao, Ergang; Qian, Shengbang; Li, Linjia; He, Jiajia; Liu, Liang; Wang, Jingjing; Zhang, Jia
2014-01-01
LY Aur is a contact massive close binary with a period of a little more than four days. The first O-C analysis of this early-type binary presented in this paper suggests that the period of the system is increasing continuously at a rate of dP/dt=+7.2×10-7 days/year, while a cyclic oscillation with the period of 12.5 years is obvious. The long-term increasing can be explained by mass transfer from the less massive companion to the more one on the nuclear time-scale of less massive body, which suggests that the contact configuration will be broken and this binary will evolve into a semi-detached system. The periodic oscillation may be the consequence of the light-travel time effect of the third body, whose mass is no less than 3.4 M⊙. It is expected that the third body may play an important role for the origin and evolution of the system by removing angular momentum from the central system, making the eclipsing pairs to have a low angular momentum, while initially it may have had a longer orbital period, with larger angular momentum. The original system may have evolved into the present contact configuration via a case A mass transfer.
NASA Astrophysics Data System (ADS)
Zubair Akbar, Muhammad; Ashraf, Muhammad; Farooq Iqbal, Muhammad; Ali, Kashif
2016-04-01
The paper presents the numerical study of heat and mass transfer analysis in a viscous unsteady MHD nanofluid flow through a channel with porous walls and medium in the presence of metallic nanoparticles. The two cases for effective thermal conductivity are discussed in the analysis through H-C model. The impacts of the governing parameters on the flow, heat and mass transfer aspects of the issue are talked about. Under the patronage of small values of permeable Reynolds number and relaxation/contraction parameter, we locate that, when wall contraction is together with suction, flow turning is encouraged close to the wall where the boundary layer is shaped. On the other hand, when the wall relaxation is coupled with injection, the flow adjacent to the porous walls decreased. The outcome of the exploration may be beneficial for applications of biotechnology. Numerical solutions for the velocity, heat and mass transfer rate at the boundary are obtained and analyzed.
MASS TRANSFER VARIATIONS IN UX MONOCEROTIS: EIGHT YEARS OF AUTOMATED PHOTOMETRIC MONITORING
Olson, Edward C.; Henry, Gregory W.; ETZEL, PAUL B. E-mail: henry@schwab.tsuniv.edu
2009-11-15
We analyze eight years (1999-2007) of automated photometric observations of the active Algol binary UX Monocerotis to search for mass transfer bursts similar to those seen in U Cephei. The largest photometric anomaly is the mean gainer luminosity difference between the stream-impact hemisphere and the opposite hemisphere. We find an updated Wilson-Devinney solution for earlier six-color observations. The UX Mon donor star fills its Roche lobe and the gainer nearly fills its rotational lobe. Instead of isolated bursts of the U Cep type, we found nearly continuous brightness fluctuations likely produced by variable mass transfer. We discuss implications for mass transfer.
Late Diagenesis and Mass Transfer in Sandstone Shale Sequences
NASA Astrophysics Data System (ADS)
Milliken, K. L.
2003-12-01
, involving only compaction and dewatering of sedimentary materials. Detrital phases that survived weathering were seen as essentially inert to subsequent reaction during burial and prior to the onset of metamorphism. Metamorphism itself was viewed as isochemical and accomplished principally through solid-state reactions (see a brief summary in Ague, 1991). Notable exceptions to these views constitute the foundations of existing theory regarding the nature of late diagenesis. "Intrastratal solution" of chemically unstable detrital minerals (e.g., Pettijohn, 1941), apparent potassium metasomatism of shales (e.g., Weaver and Beck, 1971), and massive mineralogical changes during progressive burial (e.g., Coombs et al., 1959) are observations that established the directions of modern research in late diagenesis. Advances in petrographic imaging techniques (e.g., backscattered electron- and cathodoluminescence-imaging) and integration of petrographic observations with both bulk and spatially resolved chemical analyses have greatly accelerated the evolution of concepts about late diagenesis and early metamorphism.Today, basin-scale mass transfer of some materials (e.g., helium, water, and petroleum) is unquestioned (e.g., Hunt, 1996). Other materials (e.g., titanium and the REEs) are sufficiently mobile to appear within authigenic precipitates, but are likely to be "immobile" on the scale of a hand specimen. Mobilities of the major elements that make up sandstones and shales (silicon, aluminum, calcium, sodium, potassium) remain controversial. Conflicting notions about processes in rock suites across the wide range of burial conditions and alteration show that fundamental questions remain unanswered about the nature of the volumetrically significant processes within a major segment of the rock cycle. It is very likely that something is wrong, or at least inadequate, with the present concepts and/or data pertaining to the evolution of permeability, transport mechanisms, and timing
NASA Astrophysics Data System (ADS)
Harikrishnan, L.; Maiya, M. P.; Tiwari, S.; Wohlfeil, A.; Ziegler, F.
2009-10-01
In this paper the heat and mass transfer characteristics of a horizontal tube absorber for the mixture R134a/DMAC in terms of experimentally gained heat and mass transfer coefficients are presented. The heat transfer coefficient is mainly dependent on the solution’s mass flow rate. The mass transfer coefficient is strongly related to the subcooling of the solution. The data are compared to experimental absorption characteristics of water into aqueous lithium bromide in an absorption chiller. The mass transfer coefficients are of similar size whereas the heat transfer coefficients are about one order of magnitude smaller for R134a-DMAC.
Mass Transfer in a Rigid Tube With Pulsatile Flow and Constant Wall Concentration
Moschandreou, T. E.; Ellis, C. G.; Goldman, D.
2011-01-01
An approximate-analytical solution method is presented for the problem of mass transfer in a rigid tube with pulsatile flow. For the case of constant wall concentration, it is shown that the generalized integral transform (GIT) method can be used to obtain a solution in terms of a perturbation expansion, where the coefficients of each term are given by a system of coupled ordinary differential equations. Truncating the system at some large value of the parameter N, an approximate solution for the system is obtained for the first term in the perturbation expansion, and the GIT-based solution is verified by comparison to a numerical solution. The GIT approximate-analytical solution indicates that for small to moderate nondimensional frequencies for any distance from the inlet of the tube, there is a positive peak in the bulk concentration C1b due to pulsation, thereby, producing a higher mass transfer mixing efficiency in the tube. As we further increase the frequency, the positive peak is followed by a negative peak in the time-averaged bulk concentration and then the bulk concentration C1b oscillates and dampens to zero. Initially, for small frequencies the relative Sherwood number is negative indicating that the effect of pulsation tends to reduce mass transfer. There is a band of frequencies, where the relative Sherwood number is positive indicating that the effect of pulsation tends to increase mass transfer. The positive peak in bulk concentration corresponds to a matching of the phase of the pulsatile velocity and the concentration, respectively, where the unique maximum of both occur for certain time in the cycle. The oscillatory component of concentration is also determined radially in the tube where the concentration develops first near the wall of the tube, and the lobes of the concentration curves increase with increasing distance downstream until the concentration becomes fully developed. The GIT method proves to be a working approach to solve the first
NASA Astrophysics Data System (ADS)
Keshavarz Moraveji, Mostafa; Ebrahimi Fakhari, Mona; Mohsenzadeh, Elmira; Davarnejad, Reza
2013-01-01
In this article, the influences of alcohols on the hydrodynamics and oxygen mass transfer characteristics in an airlift reactor equipped with packing were investigated. The hydrodynamic parameters and mass transfer coefficient in 1 % (v/v) aqueous solutions of four aliphatic alcohols were tested. It was concluded that alcohols addition increased gas holdup and gas-liquid mass transfer coefficient. The packing installation increased mass transfer coefficient, gas holdup and liquid circulation velocity, as well.
Leading edge film cooling effects on turbine blade heat transfer
NASA Technical Reports Server (NTRS)
Garg, Vijay K.; Gaugler, Raymond E.
1995-01-01
An existing three dimensional Navier-Stokes code, modified to include film cooling considerations, has been used to study the effect of spanwise pitch of shower-head holes and coolant to mainstream mass flow ratio on the adiabatic effectiveness and heat transfer coefficient on a film-cooled turbine vane. The mainstream is akin to that under real engine conditions with stagnation temperature = 1900 K and stagnation pressure = 3 MPa. It is found that with the coolant to mainstream mass flow ratio fixed, reducing P, the spanwise pitch for shower-head holes, from 7.5 d to 3.0 d, where d is the hole diameter, increases the average effectiveness considerably over the blade surface. However, when P/d= 7.5, increasing the coolant mass flow increases the effectiveness on the pressure surface but reduces it on the suction surface due to coolant jet lift-off. For P/d = 4.5 or 3.0, such an anomaly does not occur within the range of coolant to mainstream mass flow ratios analyzed. In all cases, adiabatic effectiveness and heat transfer coefficient are highly three-dimensional.
Heat and Mass Transfer Measurements for Tray-Fermented Fungal Products
NASA Astrophysics Data System (ADS)
Jou, R.-Y.; Lo, C.-T.
2011-01-01
In this study, heat and mass transfer in static tray fermentation, which is widely used in solid-state fermentation (SSF) to produce fungal products, such as enzymes or koji, is investigated. Specifically, kinetic models of transport phenomena in the whole-tray chamber are emphasized. The effects of temperature, moisture, and humidity on microbial growth in large-scale static tray fermentation are essential to scale-up SSF and achieve uniform fermentation. In addition, heat and mass transfer of static tray fermentation of Trichoderma fungi with two tray setups—traditional linen coverings and stacks in a temperature-humidity chamber is examined. In both these setups, the following factors of fermentation were measured: air velocity, air temperature, illumination, pH, carbon dioxide (CO2) concentration, and substrate temperature, and the effects of bed height, moisture of substrate, and relative humidity of air are studied. A thin (1 cm) bed at 28 °C and 95 % relative humidity is found to be optimum. Furthermore, mixing was essential for achieving uniform fermentation of Trichoderma fungi. This study has important applications in large-scale static tray fermentation of fungi.
A mass transfer origin for blue stragglers in NGC 188 as revealed by half-solar-mass companions.
Geller, Aaron M; Mathieu, Robert D
2011-10-20
In open star clusters, where all members formed at about the same time, blue straggler stars are typically observed to be brighter and bluer than hydrogen-burning main-sequence stars, and therefore should already have evolved into giant stars and stellar remnants. Correlations between blue straggler frequency and cluster binary star fraction, core mass and radial position suggest that mass transfer or mergers in binary stars dominates the production of blue stragglers in open clusters. Analytic models, detailed observations and sophisticated N-body simulations, however, argue in favour of stellar collisions. Here we report that the blue stragglers in long-period binaries in the old (7 × 10(9)-year) open cluster NGC 188 have companions with masses of about half a solar mass, with a surprisingly narrow mass distribution. This conclusively rules out a collisional origin, as the collision hypothesis predicts a companion mass distribution with significantly higher masses. Mergers in hierarchical triple stars are marginally permitted by the data, but the observations do not favour this hypothesis. The data are highly consistent with a mass transfer origin for the long-period blue straggler binaries in NGC 188, in which the companions would be white dwarfs of about half a solar mass. PMID:22012393
Mathematical model of quasistationary conditions of mass transfer in an electrodialysis cell
NASA Astrophysics Data System (ADS)
Khanmamedov, M. N.
2000-07-01
The author suggests a quasistationary mathematical model of the mass-transfer conditions in an electrodialysis cell in which the main operating parameters of the electrodialysis apparatus are expressed as a function of the dimensionless diluate concentration.
Simoes, P.C.; Matos, H.A.; Carmelo, P.J.; Gomes de Azevedo, E.; Nunes da Ponte, M. . Faculdade de Ciencias e Tecnologia)
1995-02-01
Supercritical fluid extraction (SFE) is an alternative separation method to more conventional processes such as liquid extraction and distillation. However, up to now, few works have been devoted to the investigation of the efficiency of countercurrent packed columns under supercritical conditions from a mass transfer point of view. Mass transfer in a countercurrent column, filled with structured gauze packing, was measured for the separation of a mixture of terpenes (d-limonene/1,8-cineole) by supercritical carbon dioxide, at 313 and 318 K and pressures up to 9 MPa. The extraction efficiency was determined in terms of the overall mass transfer coefficient. Operating lines for this process had an appreciable curvature due to a high miscibility of the two contacting phases. The real slope of these lines had to be estimated. Available mass transfer models for packed columns predicted efficiencies diverging to a great extent from the experimental results.
Fluid-dynamic and mass-transfer behavior of static mixers and regular packings
Cavatorta, O.N.; Boehm, U.; Chiappori de del Giorgio, A.M.
1999-05-01
The fluid dynamics and liquid-to-wall mass transfer for spaced and stacked regular packings were studied for forced convection and fluidized beds. The behavior of these configurations in bubble columns and under natural convection conditions is also presented. Flow parameters characterizing structured packings, presented in the literature, were used in the evaluation of results. General equations to predict pressure drop and mass transfer are discussed, as well as the relationship between energy dissipation and mass transfer. In the presence of fluidized particles, single-phase flow or natural convection conditions, the mass-transfer behavior of a packing element stacked between other packs or separated from the neighboring elements by liquid layers is almost the same, but differs in bubble columns.
Tabares Velasco, P. C.
2011-04-01
This presentation discusses estimating heat and mass transfer processes in green roof systems: current modeling capabilities and limitations. Green roofs are 'specialized roofing systems that support vegetation growth on rooftops.'
Small chamber tests were conducted to experimentally determine the overall mass transfer coefficient for pollutant emissions from still water under simulated indoor-residential or occupational-environmental conditions. Fourteen tests were conducted in small environmental chambers...
The mechanism of thermal-gradient mass transfer in the sodium hydroxide-nickel system
NASA Technical Reports Server (NTRS)
May, Charles E
1958-01-01
"Thermal-gradient mass transfer" was investigated in the molten sodium hydroxide-nickel system. Possible mechanisms (physical, electrochemical, and chemical) are discussed in terms of experimental and theoretical evidence. Experimental details are included in appendixes.
NASA Astrophysics Data System (ADS)
Mannella, G. A.; La Carrubba, V.; Brucato, V.
2012-06-01
Vapor mass transfer phenomena in four different membrane distillation (MD) configurations were examined through a self-built laboratory scale experimental apparatus: Air Gap MD, Sweeping Gas MD, Vacuum Sweeping Gas MD and Vacuum MD. Vapor fluxes were measured and compared with those predicted by various models, showing that MD performance under usual processing conditions is severely controlled by the permeate side resistance to mass transfer.
Nogueira, Bruno L; Pérez, Julio; van Loosdrecht, Mark C M; Secchi, Argimiro R; Dezotti, Márcia; Biscaia, Evaristo C
2015-09-01
In moving bed biofilm reactors (MBBR), the removal of pollutants from wastewater is due to the substrate consumption by bacteria attached on suspended carriers. As a biofilm process, the substrates are transported from the bulk phase to the biofilm passing through a mass transfer resistance layer. This study proposes a methodology to determine the external mass transfer coefficient and identify the influence of the mixing intensity on the conversion process in-situ in MBBR systems. The method allows the determination of the external mass transfer coefficient in the reactor, which is a major advantage when compared to the previous methods that require mimicking hydrodynamics of the reactor in a flow chamber or in a separate vessel. The proposed methodology was evaluated in an aerobic lab-scale system operating with COD removal and nitrification. The impact of the mixing intensity on the conversion rates for ammonium and COD was tested individually. When comparing the effect of mixing intensity on the removal rates of COD and ammonium, a higher apparent external mass transfer resistance was found for ammonium. For the used aeration intensities, the external mass transfer coefficient for ammonium oxidation was ranging from 0.68 to 13.50 m d(-1) and for COD removal 2.9 to 22.4 m d(-1). The lower coefficient range for ammonium oxidation is likely related to the location of nitrifiers deeper in the biofilm. The measurement of external mass transfer rates in MBBR will help in better design and evaluation of MBBR system-based technologies. PMID:25996756
Some Biological Hints on the Control of Heat and Mass Transfer
NASA Astrophysics Data System (ADS)
Hagiwara, Yoshimichi
This review paper explores the possibilities of the control of heat and mass transfer associated with drought tolerance and freeze tolerance. The accumulation of some metabolites, such as proline and trehalose, are effective for drought tolerance. The special microstructures on the surfaces of some plants and insects in deserts are effective for collecting moisture in the air. Methods of preserving crops will be improved by the mimetic of the drought tolerance. Calcium ions and a protein are effective for the retrieval of damaged cell membrane due to ice formation. Ice crystal growth is inhibited by some substances such as antifreeze proteins. The cryopreservation of foods and organs will be improved by the mimetic of the freeze tolerance.
Mass transfer of a neutral solute in porous microchannel under streaming potential.
Mondal, Sourav; De, Sirshendu
2014-03-01
The mass transport of a neutral solute in a porous wall, under the influence of streaming field, has been analyzed in this study. The effect of the induced streaming field on the electroviscous effect of the fluid for different flow geometries has been suitably quantified. The overall electroosmotic velocity profile and expression for streaming field have been obtained analytically using the Debye-Huckel approximation, and subsequently used in the analysis for the mass transport. The analysis shows that as the solution Debye length increases, the strength of the streaming field and, consequently, the electroviscous effect diminishes. The species transport equation has been coupled with Darcy's law for quantification of the permeation rate across the porous wall. The concentration profile inside the mass transfer boundary layer has been solved using the similarity transformation, and the Sherwood number has been calculated from the definition. In this study, the variation of the permeation rate and solute permeate concentration has been with the surface potential, wall retention factor and osmotic pressure coefficient has been demonstrated for both the circular as well as rectangular channel cross-section. PMID:24339025
Mass and Energy Transfer Between the Solar Photosphere and Corona
NASA Astrophysics Data System (ADS)
Peter, H.
2015-12-01
The problem of chromospheric and coronal heating is also a problem of mass supply to the corona. On average we see redshifts at transition region temperatures of the order of 10 km/s. If interpreted as downflows, this would quickly empty the corona, and fresh material has to be transported into the corona. Several models have been proposed to understand this mass cycle between the different atmospheric layers. However, as of yet all these proposals have serious shortcomings. On the observational side open questions remain, too. With the new IRIS mission we can observe the transition region at unprecedented spatial and spectral resolution, but the observational results are still puzzling. In particular the finding that the spatial distribution of line widths and Doppler shifts do not change with increasing resolution is against physical intuition. This shows that even with IRIS we still have significant velocity gradients along the line-of-sight, indicating that shocks might play a significant role. Likewise the temporal evolution might be a key for our understanding of the mass cycle. It might well be that the filling and draining of hot plasma occurs on significantly different time scales, which might be part of the difficulty to arrive at a conclusive observational picture. Considering the progress made for the quiet Sun, it seems clear that the processes responsible for the mass exchange are not resolved (yet). Therefore one might wonder to what extent one could use larger and resolved individual events in more active parts of the Sun to understand the details of the mass transport. In particular a common understanding of reconnection events such as Ellerman bombs in the photosphere, explosive events in the transition region and the recently discovered IRIS bombs in-between might provide the key to better understand the mass cycle throughout the atmospheric layers from the photosphere to the corona.
Fluid flow and mass transfer over circular strands using the lattice Boltzmann method
NASA Astrophysics Data System (ADS)
Hossain, Md. Shakhawath; Chen, X. B.; Bergstrom, D. J.
2015-10-01
Knowledge of the fluid flow and mass transfer over circular strands is fundamental to the cell culture of tissue scaffolds in bio-reactors. This paper presents a study on the simulation of fluid flow and mass transfer over the circular strands of a tissue scaffold by using the multiple relaxation time lattice Boltzmann method for the low Reynolds number regime, with Re D = 0.01 and 0.1, respectively. The mass transfer problem approximates the transport of a scalar nutrient from the bulk fluid to the strand surface, such as is encountered in the flow through tissue scaffolds placed in bio-reactors. The circular geometry of the scaffold strand is treated and implemented by means of the interpolated bounce-back boundary condition formulation. Our simulation illustrates that the flow accelerates around the strand, resulting in the maximum shear stress at the shoulder of the strand and that diffusion mass transfer plays the dominant role in the scalar transport. The local Sherwood number varies significantly over the surface of the strand, with a peak value located on the upstream surface. Increasing the Schmidt number of the scalar and decreasing the blockage ratio results in higher mass transfer rates on the surface of the stand. Overall, the simulation results provide one with the insight into the fluid flow and mass transfer over the circular strands of a tissue scaffold in a bio-reactor, which would be impractical to obtain by experiments.
Orbital Evolution of Mass-transferring Eccentric Binary Systems. II. Secular Evolution
NASA Astrophysics Data System (ADS)
Dosopoulou, Fani; Kalogera, Vicky
2016-07-01
Finite eccentricities in mass-transferring eccentric binary systems can be explained by taking into account the mass loss and mass transfer processes that often occur in these systems. These processes can be treated as perturbations of the general two-body problem. The time-evolution equations for the semimajor axis and the eccentricity derived from perturbative methods are generally phase-dependent. The osculating semimajor axis and eccentricity change over the orbital timescale and are not easy to implement in binary evolution codes like MESA. However, the secular orbital element evolution equations can be simplified by averaging over the rapidly varying true anomalies. In this paper, we derive the secular time-evolution equations for the semimajor axis and the eccentricity for various mass loss/transfer processes using either the adiabatic approximation or the assumption of delta-function mass loss/transfer at periastron. We begin with the cases of isotropic and anisotropic wind mass loss. We continue with conservative and non-conservative non-isotropic mass ejection/accretion (including Roche-Lobe-Overflow) for both point-masses and extended bodies. We conclude with the case of phase-dependent mass accretion. Comparison of the derived equations with similar work in the literature is included and an explanation of the existing discrepancies is provided.
Virtual mass effect in dynamic micromechanical mass sensing in liquids
NASA Astrophysics Data System (ADS)
Peiker, P.; Oesterschulze, E.
2016-06-01
Weighing individual micro- or nanoscale particles in solution using dynamic micromechanical sensors is quite challenging: viscous losses dramatically degrade the sensor's performance by both broadening the resonance peak and increasing the effective total mass of the resonator by the dragged liquid. While the virtual mass of the resonator was discussed frequently, little attention has been paid to the virtual mass of particles attached to the resonator's surface and its impact on the accuracy of mass sensing. By means of the in situ detection of a polystyrene microbead in water using a bridge-based microresonator, we demonstrate that the virtual mass of the bead significantly affects the observed frequency shift. In fact, 55 % of the frequency shift was caused by the virtual mass of the adsorbed bead, predicted by Stoke's theory. Based on the observed shift in the resonator's quality factor during particle adsorption, we confirm this significant effect of the virtual mass. Thus, a quantitative analysis of the mass of a single adsorbed particle is strongly diminished if dynamic micromechanical sensors are operated in a liquid environment.
Dan, Marius; Rosswog, Stephan; Guillochon, James; Ramirez-Ruiz, Enrico E-mail: rosswog@jacobs-university.de E-mail: enrico@ucolick.org
2011-08-20
calculating the gravitational wave foreground (although expected to be below Laser Interferometer Space Antenna's sensitivity at these high frequencies). We also show that the inclusion of the entropy increase associated with shock heating of the accreted material reduces the number of orbits a binary survives given the same initial conditions, although the effect is not as pronounced when using the appropriate initial conditions. The use of accurate initial conditions and a correct treatment of shock heating allows for a reliable time evolution of the temperature, density, and angular momentum, which are important when considering thermonuclear events that may occur during the mass transfer phase and/or after merger. Our treatment allows us to accurately identify when surface detonations may occur in the lead-up to the merger, as well as the properties of final merger products.
An overview of challenges in modeling heat and mass transfer for living on Mars.
Yamashita, Masamichi; Ishikawa, Yoji; Kitaya, Yoshiaki; Goto, Eiji; Arai, Mayumi; Hashimoto, Hirofumi; Tomita-Yokotani, Kaori; Hirafuji, Masayuki; Omori, Katsunori; Shiraishi, Atsushi; Tani, Akira; Toki, Kyoichiro; Yokota, Hiroki; Fujita, Osamu
2006-09-01
Engineering a life-support system for living on Mars requires the modeling of heat and mass transfer. This report describes the analysis of heat and mass transfer phenomena in a greenhouse dome, which is being designed as a pressurized life-support system for agricultural production on Mars. In this Martian greenhouse, solar energy will be converted into chemical energy in plant biomass. Agricultural products will be harvested for food and plant cultivation, and waste materials will be processed in a composting microbial ecosystem. Transpired water from plants will be condensed and recycled. In our thermal design and analysis for the Martian greenhouse, we addressed the question of whether temperature and pressure would be maintained in the appropriate range for humans as well as plants. Energy flow and material circulation should be controlled to provide an artificial ecological system on Mars. In our analysis, we assumed that the greenhouse would be maintained at a subatmospheric pressure under 1/3-G gravitational force with 1/2 solar light intensity on Earth. Convection of atmospheric gases will be induced inside the greenhouse, primarily by heating from sunlight. Microclimate (thermal and gas species structure) could be generated locally around plant bodies, which would affect gas transport. Potential effects of those environmental factors are discussed on the phenomena including plant growth and plant physiology and focusing on transport processes. Fire safety is a crucial issue and we evaluate its impact on the total gas pressure in the greenhouse dome. PMID:17124127
NASA Technical Reports Server (NTRS)
Bugbee, B.; Monje, O.; Tanner, B.
1996-01-01
Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.
Experimental Investigations of Heat and Mass Transfer in Microchannel Heat-Transfer Elements
NASA Astrophysics Data System (ADS)
Konovalov, D. A.
2016-06-01
The present work seeks to develop and investigate experimentally microchannel heat-exchange apparatuses of two designs: with porous elements manufactured from titanium and copper, and also based on the matrix of filamentary silicon single crystals under operating conditions with high heat loads, unsteadiness, and nonlinear flow of the coolant. For experimental investigations, the authors have developed and manufactured a unique test bench allowing tests of the developed heat-transfer elements in unsteady operating regimes. The performed experimental investigations have made it possible to obtain criterial dependences of the heat-transfer coefficient on the Reynolds and Prandtl numbers and to refine the values of viscous and inertial coefficients. It has been established that microchannel heat-transfer elements based on silicon single crystals, which make it possible to remove a heat flux above 100 W/cm2, are the most efficient. For porous heat-transfer elements, the best result was attained for wedge-shaped copper samples. According to investigation results, the authors have considered the issues of optimization of thermal and hydraulic characteristics of the heat-transfer elements under study. In the work, the authors have given examples of practical use of the developed heat-transfer elements for cooling systems of radioelectronic equipment.
Experimental Investigations of Heat and Mass Transfer in Microchannel Heat-Transfer Elements
NASA Astrophysics Data System (ADS)
Konovalov, D. A.
2016-05-01
The present work seeks to develop and investigate experimentally microchannel heat-exchange apparatuses of two designs: with porous elements manufactured from titanium and copper, and also based on the matrix of filamentary silicon single crystals under operating conditions with high heat loads, unsteadiness, and nonlinear flow of the coolant. For experimental investigations, the authors have developed and manufactured a unique test bench allowing tests of the developed heat-transfer elements in unsteady operating regimes. The performed experimental investigations have made it possible to obtain criterial dependences of the heat-transfer coefficient on the Reynolds and Prandtl numbers and to refine the values of viscous and inertial coefficients. It has been established that microchannel heat-transfer elements based on silicon single crystals, which make it possible to remove a heat flux above 100 W/cm2, are the most efficient. For porous heat-transfer elements, the best result was attained for wedge-shaped copper samples. According to investigation results, the authors have considered the issues of optimization of thermal and hydraulic characteristics of the heat-transfer elements under study. In the work, the authors have given examples of practical use of the developed heat-transfer elements for cooling systems of radioelectronic equipment.
Ramus, Ksenia; Kopinke, Frank-Dieter; Georgi, Anett
2012-01-01
The effect of dissolved humic substances (DHS) on the rate of water-gas exchange of two volatile organic compounds was studied under various conditions of agitation intensity, solution pH and ionic strength. Mass-transfer coefficients were determined from the rate of depletion of model compounds from an apparatus containing a stirred aqueous solution with continuous purging of the headspace above the solution (dynamic system). Under these conditions, the overall transfer rate is controlled by the mass-transfer resistance on the water side of the water-gas interface. The experimental results show that the presence of DHS hinders the transport of the organic molecules from the water into the gas phase under all investigated conditions. Mass-transfer coefficients were significantly reduced even by low, environmentally relevant concentrations of DHS. The retardation effect increased with increasing DHS concentration. The magnitude of the retardation effect on water-gas exchange was compared for Suwannee River fulvic and humic acids, a commercially available leonardite humic acid and two synthetic surfactants. The observed results are in accordance with the concept of hydrodynamic effects. Surface pressure forces due to surface film formation change the hydrodynamic characteristics of water motion at the water-air interface and thus impede surface renewal. PMID:22051345
Mathematical equivalence between time-dependent single-rate and multirate mass transfer models
NASA Astrophysics Data System (ADS)
Fernández-Garcia, D.; Sanchez-Vila, X.
2015-05-01
The often observed tailing of tracer breakthrough curves is caused by a multitude of mass transfer processes taking place over multiple scales. Yet, in some cases, it is convenient to fit a transport model with a single-rate mass transfer coefficient that lumps all the non-Fickian observed behavior. Since mass transfer processes take place at all characteristic times, the single-rate mass transfer coefficient derived from measurements in the laboratory or in the field vary with time ω>(t>). The literature review and tracer experiments compiled by Haggerty et al. (2004) from a number of sites worldwide suggest that the characteristic mass transfer time, which is proportional to ω>(t>)-1, scales as a power law of the advective and experiment duration. This paper studies the mathematical equivalence between the multirate mass transfer model (MRMT) and a time-dependent single-rate mass transfer model (t-SRMT). In doing this, we provide new insights into the previously observed scale-dependence of mass transfer coefficients. The memory function, g(t), which is the most salient feature of the MRMT model, determines the influence of the past values of concentrations on its present state. We found that the t-SRMT model can also be expressed by means of a memory function φ>(t,τ>). In this case, though the memory function is nonstationary, meaning that in general it cannot be written as φ>(t-τ>). Nevertheless, the full behavior of the concentrations using a single time-dependent rate ω>(t>) is approximately analogous to that of the MRMT model provided that the equality ω>(t>)=-dlng>(t>)/dt holds and the field capacity is properly chosen. This relationship suggests that when the memory function is a power law, g>(t>)˜t1-k, the equivalent mass transfer coefficient scales as ω>(t>)˜t-1, nicely fitting without calibration the estimated mass transfer coefficients compiled by Haggerty et al. (2004).
Macro- to Nanoscale Heat and Mass Transfer: The Lagging Behavior
NASA Astrophysics Data System (ADS)
Ghazanfarian, Jafar; Shomali, Zahra; Abbassi, Abbas
2015-07-01
The classical model of the Fourier's law is known as the most common constitutive relation for thermal transport in various engineering materials. Although the Fourier's law has been widely used in a variety of engineering application areas, there are many exceptional applications in which the Fourier's law is questionable. This paper gathers together such applications. Accordingly, the paper is divided into two parts. The first part reviews the papers pertaining to the fundamental theory of the phase-lagging models and the analytical and numerical solution approaches. The second part wrap ups the various applications of the phase-lagging models including the biological materials, ultra-high-speed laser heating, the problems involving moving media, micro/nanoscale heat transfer, multi-layered materials, the theory of thermoelasticity, heat transfer in the material defects, the diffusion problems we call as the non-Fick models, and some other applications. It is predicted that the interest in the field of phase-lagging heat transport has grown incredibly in recent years because they show good agreement with the experiments across a wide range of length and time scales.
NASA Astrophysics Data System (ADS)
Qasim, M.; Khan, Z. H.; Lopez, R. J.; Khan, W. A.
2016-01-01
The heat and mass transport of a nanofluid thin film over an unsteady stretching sheet has been investigated. This is the first paper on nanofluid thin film flow caused by unsteady stretching sheet using Buongiorno's model. The model used for the nanofluid film incorporates the effects of Brownian motion and thermophoresis. The self-similar non-linear ordinary differential equations are solved using Maple's built-in BVP solver. The results for pure fluid are found to be in good agreement with the literature. Present analysis shows that free surface temperature and nanoparticle volume fraction increase with both unsteadiness and magnetic parameters. The results reveal that effect of both nanofluid parameters and viscous dissipation is to reduce the heat transfer rate.
Methods to control phase inversions and enhance mass transfer in liquid-liquid dispersions
Tsouris, Constantinos; Dong, Junhang
2002-01-01
The present invention is directed to the effects of applied electric fields on liquid-liquid dispersions. In general, the present invention is directed to the control of phase inversions in liquid-liquid dispersions. Because of polarization and deformation effects, coalescence of aqueous drops is facilitated by the application of electric fields. As a result, with an increase in the applied voltage, the ambivalence region is narrowed and shifted toward higher volume fractions of the dispersed phase. This permits the invention to be used to ensure that the aqueous phase remains continuous, even at a high volume fraction of the organic phase. Additionally, the volume fraction of the organic phase may be increased without causing phase inversion, and may be used to correct a phase inversion which has already occurred. Finally, the invention may be used to enhance mass transfer rates from one phase to another through the use of phase inversions.
Gas-liquid mass transfer in filamentous slurries in airlift bioreactors
Chisti, M.Y.; Moo-Young, M. )
1988-01-01
Biotechnology production processes are often critically dependent on oxygen transfer in gas-liquid-solid multiphase systems. Some of these biofluid slurries are composed of fibrous or filamentous, mycelial, solids suspended in a water-like medium. Examples are the broths of Aspergilli, Penicillia, Neurospora and Streptomyces, all of which are of commercial importance. This paper reports of the gas-liquid mass transfer behaviour of aqueous slurries of cellulose fibre solids (1-3 wt./vol. % solids in 0.15 kmol m/sup -3/ NaCl) which simulate the filamentous fermentation broths of interest. Fundamental investigations into the relationship between the mass transfer coefficient (k/sub L/) and bubble diameter (d/sub B/) are undertaken. The observations can be usefully employed for scale-up of bioreactors for gas-liquid mass transfer as demonstrated in the paper.
Rotating machinery heat and mass transfer research in the People's Republic of China
NASA Astrophysics Data System (ADS)
Wu, C.-H.; Ko, S.-Y.; Liu, D.; Shen, J.; Xu, J.-Z.
A survey of research on rotating machinery heat and mass transfer in the People's Republic of China has been made. Since the later part of 1950's, considerable research and development work has been conducted in this field in China in order to improve the performance and prolong the life of rotating machinery. The emphasis of gas turbine heat transfer has been made in this survey. The water cooling of generator and the heat transfer of rotary piston engine are also included. Researches on the measuring technique of rotating machinery such as the temperature measurement, heat flux gauge, turbulence measurement, optical measurement and flow field visualization are discussed. The following topics of gas turbine heat and mass transfer are included: numerical analysis of air cooling of turbine blades, internal cooling passage heat transfer, impingment cooling, film cooling, transpiration cooling of turbine blades, cooling of blade root tenon, cooling of rotor disc, film cooling of flame tube and cooling of afterburner.
Mass savings domain of plasma propulsion for LEO to GEO transfer
Choueiri, E.Y.; Kelly, A.J.; Jahn, R.G. )
1993-01-20
A parametric model is used to study the mass savings of plasma propulsion over advanced chemical propulsion for lower earth orbit (LEO) to geosynchronous orbit (GEO) transfer. Such savings are characterized by stringent requirements of massive payloads (O(10) metric tons) and high power levels (O(100) kW). Mass savings on the order of the payload mass are possible but at the expense of longer transfer times (8--20 months). Typical of the savings domain is the case of a self-field magnetoplasmadynamic (MPD) thruster running quasi-steadily, at an [ital I][sub [ital s
A Convergence Study of Mass Transfer in a Simulated Double White Binary
NASA Astrophysics Data System (ADS)
Motl, Patrick M.; Tohline, J. E.; Frank, J.
2011-01-01
We present evolutions of a model double white dwarf binary with a low initial mass ratio (q = 0.4). We vary both the initial depth of contact (and hence the initial mass transfer rate) as well as the numerical resolution in our Eulerian hydrodynamics code. At the highest resolution of about 47 million grid cells we find that the binary has an initially growing mass transfer rate that then declines as the binary separates through the 50 orbital periods of the simulation. The lower resolution run (evolved with about 3 million cells) of the same binary also shows evidence for stable mass transfer though the mass transfer rate is significantly higher - emphasizing the importance of numerical resolution in these simulations. In this presentation we quantify the convergence of mass transfer between donor and accretor and measure the exchange of angular momentum through orbit-averaged equations. This work has been supported in part by NASA Astrophysics Theory Program grant number NNX10AC72G. The computations were performed on Teragrid and LONI facilities.
A generalized mass transfer law unifying various particle transport mechanisms in dilute dispersions
NASA Astrophysics Data System (ADS)
Guha, Abhijit
2008-09-01
A generalized mass transfer law for dilute dispersion of particles (or droplets) of any sizes suspended in a fluid has been described, which can be applied to turbulent or laminar flow. The generalized law reduces to the Fick’s law of diffusion in the limit of very small particles. Thus the study shows how the well-known and much-used Fick’s law of diffusion fits into the broader context of particle transport. The general expression for particle flux comprises a diffusive flux due to Brownian motion and turbulent fluctuation, a diffusive flux due to temperature gradient (thermophoresis plus stressphoresis) and a convective flux that arises primarily due to the interaction of particle inertia and the inhomogeneity of the fluid turbulence field (turbophoresis). Shear-induced lift force, electrical force, gravity, etc. also contribute to the convective flux. The present study includes the effects of surface roughness, and the calculations show that the presence of small surface roughness even in the hydraulically smooth regime significantly enhances deposition especially of small particles. Thermophoresis can have equally strong effects, even with a modest temperature difference between the wall and the bulk fluid. For particles of the intermediate size range, turbophoresis, thermophoresis and roughness are all important contributors to the overall deposition rate. The paper includes a parametric study of the effects of electrostatic forces due to mirror charging. The present work provides a unified framework to determine the combined effect of various particle transport mechanisms on mass transfer rate and the inclusion of other mechanisms not considered in this paper is possible.
Heat and mass transfer of submerged helium injection in liquid oxygen vessel
NASA Astrophysics Data System (ADS)
Jung, Youngsuk; Cho, Namkyung; Baek, Seungwhan; Jeong, Sangkwon
2014-11-01
The submerged helium injection process results in the heat and mass transfer between the helium bubble and the cryogenic liquid. The objective of this paper is to analyze the dynamics of the heat and mass transfer process. It is observed that during the helium injection process the dynamics of mass transfer is dominant and the transient heat transfer is negligible. The helium bubble shape and rising patterns are observed with a visualization device that helps to discern the dominant process between heat transfer and mass transfer. The clustering patterns such as coalescence of helium bubbles are observed with the visualization device. The visualization results indicate that, it is very difficult to determine the representative size of bubbles due to the irregular shape of the helium bubbles. The shape and size of the helium bubbles are important parameters for evaluating the overall mass transfer coefficient (kGA) which is the essential parameter for calculating the evaporation rate of the bulk liquid into the helium bubbles. In this paper, the simplified lumped model is considered to fairly approximate the evaporation rate of the cryogenic liquid into the bubbles and the cooling rate of helium injection. The empirical correlation for the average concentration (C‾A) of evaporated cryogenic liquid into the helium bubbles is presented and the overall mass transfer coefficients (kGA) are calculated as the result of the lumped model. The proposed model and empirical correlations are compared with the experimental results, and the comparison result shows good agreement with differences that are less than ±0.4 K.
Heat and mass transfer in a steam-generating tube
Doroshchuk, V.Y.
1990-01-01
Reliable data on the distribution of phases of steam-water flow in a channel cross-section, on steam and water velocities, and on void fractions are almost non-existent. This paper reports that by assuming that u{sub 1}/u{sub 3} = square root {rho}{prime}/{rho}{prime}{prime} (where u{sub 1} and u{sub 3} are the velocities of steam in the flow core and of a liquid film near a wall, {rho}{prime}{prime} and {rho}{prime} are the densities of corresponding phases) and by using the limiting void fractions x{sup o}{sub lim}, the above-mentioned flow parameters can be determined analytically for the instant of onset of a heat transfer crisis of the second kind.
Fuel cell collector plates with improved mass transfer channels
Gurau, Vladimir; Barbir, Frano; Neutzler, Jay K.
2003-04-22
A fuel cell collector plate can be provided with one or more various channel constructions for the transport of reactants to the gas diffusion layer and the removal of water therefrom. The outlet channel can be arranged to have a reduced volume compared to the inlet channel, in both interdigitated and discontinuous spiral applications. The land width between an inlet channel and outlet channel can be reduced to improved mass flow rate in regions of deleted reactant concentrations. Additionally or alternatively, the depth of the inlet channel can be reduced in the direction of flow to reduce the diffusion path as the concentration of reactant is reduced.
Esperança, M N; Cunha, F M; Cerri, M O; Zangirolami, T C; Farinas, C S; Badino, A C
2014-05-01
Sugarcane bagasse is a low-cost and abundant by-product generated by the bioethanol industry, and is a potential substrate for cellulolytic enzyme production. The aim of this work was to evaluate the effects of air flow rate (QAIR), solids loading (%S), sugarcane bagasse type, and particle size on the gas hold-up (εG) and volumetric oxygen transfer coefficient (kLa) in three different pneumatic bioreactors, using response surface methodology. Concentric tube airlift (CTA), split-cylinder airlift (SCA), and bubble column (BC) bioreactor types were tested. QAIR and %S affected oxygen mass transfer positively and negatively, respectively, while sugarcane bagasse type and particle size (within the range studied) did not influence kLa. Using large particles of untreated sugarcane bagasse, the loop-type bioreactors (CTA and SCA) exhibited higher mass transfer, compared to the BC reactor. At higher %S, SCA presented a higher kLa value (0.0448 s−1) than CTA, and the best operational conditions in terms of oxygen mass transfer were achieved for %S < 10.0 g L−1 and QAIR > 27.0 L min−1. These results demonstrated that pneumatic bioreactors can provide elevated oxygen transfer in the presence of vegetal biomass, making them an excellent option for use in three-phase systems for cellulolytic enzyme production by filamentous fungi. PMID:24078146
Prediction of Heat and Mass Transfer in a Rotating Ribbed Coolant Passage With a 180 Degree Turn
NASA Technical Reports Server (NTRS)
Rigby, David L.
1999-01-01
Numerical results are presented for flow in a rotating internal passage with a 180 degree turn and ribbed walls. Reynolds numbers ranging from 5200 to 7900, and Rotation numbers of 0.0 and 0.24 were considered. The straight sections of the channel have a square cross section, with square ribs spaced one hydraulic diameter (D) apart on two opposite sides. The ribs have a height of 0.1D and are not staggered from one side to the other. The full three dimensional Reynolds Averaged Navier-Stokes equations are solved combined with the Wilcox k-omega turbulence model. By solving an additional equation for mass transfer, it is possible to isolate the effect of buoyancy in the presence of rotation. That is, heat transfer induced buoyancy effects can be eliminated as in naphthalene sublimation experiments. Heat transfer, mass transfer and flow field results are presented with favorable agreement with available experimental data. It is shown that numerically predicting the reattachment between ribs is essential to achieving an accurate prediction of heat/mass transfer. For the low Reynolds numbers considered, the standard turbulence model did not produce reattachment between ribs. By modifying the wall boundary condition on omega, the turbulent specific dissipation rate, much better agreement with the flow structure and heat/ mass transfer was achieved. It is beyond the scope of the present work to make a general recommendation on the omega wall boundary condition. However, the present results suggest that the omega boundary condition should take into account the proximity to abrupt changes in geometry.
NASA Astrophysics Data System (ADS)
Papa, Marco
The effect of secondary flows on mass transfer from a simulated gas turbine blade and hubwall is investigated. Measurements performed using naphthalene sublimation provide non-dimensional mass transfer coefficients, in the form of Sherwood numbers, that can be converted to heat transfer coefficients through the use of an analogy. Tests are conducted in a linear cascade composed of five blades having the profile of a first stage rotor blade of a high-pressure turbine aircraft engine. Detailed mass transfer maps on the airfoil and endwall surfaces allow the identification of significant flow features that are in good agreement with existing secondary flow models. These results are well-suited for validation of numerical codes, as they are obtained with an accurate technique that does not suffer from conduction or radiation errors and allows the imposition of precise boundary conditions. The performance of a RANS (Reynolds Averaged Navier-Stokes) numerical code that simulates the flow and heat/mass transfer in the cascade using the SST (Shear Stress Transport) k-o model is evaluated through a comparison with the experimental results. Tests performed with a modified blade leading edge show that the introduction of a fillet at the junction with the endwall reduces the effects of the horseshoe vortex in the first part of the passage, while no measurable changes in mass transfer are observed further downstream. Air injected through a slot located upstream of the cascade simulates the engine wheelspace coolant injection between the stator and the rotor. Local mass transfer data obtained injecting naphthalene-free and naphthalene-saturated air are reduced to derive maps of cooling effectiveness on the blade and endwall. Oil dot tests show the surface flow on the endwall. The surface downstream of the gap is coplanar to the upstream surface in the baseline configuration and is shifted to form a forward and backward facing step to investigate the effects of component
Orbital Evolution of Mass-transferring Eccentric Binary Systems. I. Phase-dependent Evolution
NASA Astrophysics Data System (ADS)
Dosopoulou, Fani; Kalogera, Vicky
2016-07-01
Observations reveal that mass-transferring binary systems may have non-zero orbital eccentricities. The time evolution of the orbital semimajor axis and eccentricity of mass-transferring eccentric binary systems is an important part of binary evolution theory and has been widely studied. However, various different approaches to and assumptions on the subject have made the literature difficult to comprehend and comparisons between different orbital element time evolution equations not easy to make. Consequently, no self-consistent treatment of this phase has ever been included in binary population synthesis codes. In this paper, we present a general formalism to derive the time evolution equations of the binary orbital elements, treating mass loss and mass transfer as perturbations of the general two-body problem. We present the self-consistent form of the perturbing acceleration and phase-dependent time evolution equations for the orbital elements under different mass loss/transfer processes. First, we study the cases of isotropic and anisotropic wind mass loss. Then, we proceed with non-isotropic ejection and accretion in a conservative as well as a non-conservative manner for both point masses and extended bodies. We compare the derived equations with similar work in the literature and explain the existing discrepancies.
Disentangling oil weathering using GC x GC. 2. Mass transfer calculations.
Arey, J Samuel; Nelson, Robert K; Plata, Desiree L; Reddy, Christopher M
2007-08-15
Hydrocarbon mass transfers to the atmosphere and water column drive the early weathering of oil spills and also control the chemical exposures of many coastal wildlife species. However, in the field, mass transfer rates of individual hydrocarbons to air and water are often uncertain. In the Part 1 companion to this paper, we used comprehensive two-dimensional gas chromatography (GC x GC) to identify distinct signatures of evaporation and dissolution encoded in the compositional evolution of weathered oils. In Part 2, we further investigate patterns of mass removal in GC x GC chromatograms using a mass transfer model. The model was tailored to conditions at a contaminated beach on Buzzards Bay, MA, after the 2003 Bouchard 120 oil spill. The model was applied to all resolved hydrocarbon compounds in the C11-C24 boiling range, based on their GC x GC-estimated vapor pressures and aqueous solubilities. With no fitted parameters, the model successfully predicted GC x GC chromatogram patterns of mass removal associated with evaporation, water-washing, and diffusion-limited transport. This enabled a critical field evaluation of the mass transfer model and also allowed mass apportionment estimates of hundreds of individual hydrocarbon compounds to air and water. Ultimately, this method should improve assessments of wildlife exposures to oil spill hydrocarbons. PMID:17874782
Quark mass effect on axial charge dynamics
NASA Astrophysics Data System (ADS)
Guo, Er-dong; Lin, Shu
2016-05-01
We studied the effect of finite quark mass on the dynamics of the axial charge using the D3/D7 model in holography. The mass term in the axial anomaly equation affects both the fluctuation (generation) and dissipation of the axial charge. We studied the dependence of the effect on quark mass and an external magnetic field. For axial charge generation, we calculated the mass diffusion rate, which characterizes the helicity flipping rate. The rate is a nonmonotonous function of mass and can be significantly enhanced by the magnetic field. The diffusive behavior is also related to a divergent susceptibility of the axial charge. For axial charge dissipation, we found that in the long time limit, the mass term dissipates all the charge effectively generated by parallel electric and magnetic fields. The result is consistent with a relaxation time approximation. The rate of dissipation through mass term is a monotonous increasing function of both quark mass and a magnetic field.
Briggs, Martin A.; Day-Lewis, Frederick D.; Ong, John B.; Curtis, Gary P.; Lane, Jr., John W.
2013-01-01
Anomalous solute transport, modeled as rate-limited mass transfer, has an observable geoelectrical signature that can be exploited to infer the controlling parameters. Previous experiments indicate the combination of time-lapse geoelectrical and fluid conductivity measurements collected during ionic tracer experiments provides valuable insight into the exchange of solute between mobile and immobile porosity. Here, we use geoelectrical measurements to monitor tracer experiments at a former uranium mill tailings site in Naturita, Colorado. We use nonlinear regression to calibrate dual-domain mass transfer solute-transport models to field data. This method differs from previous approaches by calibrating the model simultaneously to observed fluid conductivity and geoelectrical tracer signals using two parameter scales: effective parameters for the flow path upgradient of the monitoring point and the parameters local to the monitoring point. We use regression statistics to rigorously evaluate the information content and sensitivity of fluid conductivity and geophysical data, demonstrating multiple scales of mass transfer parameters can simultaneously be estimated. Our results show, for the first time, field-scale spatial variability of mass transfer parameters (i.e., exchange-rate coefficient, porosity) between local and upgradient effective parameters; hence our approach provides insight into spatial variability and scaling behavior. Additional synthetic modeling is used to evaluate the scope of applicability of our approach, indicating greater range than earlier work using temporal moments and a Lagrangian-based Damköhler number. The introduced Eulerian-based Damköhler is useful for estimating tracer injection duration needed to evaluate mass transfer exchange rates that range over several orders of magnitude.
NASA Astrophysics Data System (ADS)
Briggs, Martin A.; Day-Lewis, Frederick D.; Ong, John B. T.; Curtis, Gary P.; Lane, John W.
2013-09-01
Anomalous solute transport, modeled as rate-limited mass transfer, has an observable geoelectrical signature that can be exploited to infer the controlling parameters. Previous experiments indicate the combination of time-lapse geoelectrical and fluid conductivity measurements collected during ionic tracer experiments provides valuable insight into the exchange of solute between mobile and immobile porosity. Here, we use geoelectrical measurements to monitor tracer experiments at a former uranium mill tailings site in Naturita, Colorado. We use nonlinear regression to calibrate dual-domain mass transfer solute-transport models to field data. This method differs from previous approaches by calibrating the model simultaneously to observed fluid conductivity and geoelectrical tracer signals using two parameter scales: effective parameters for the flow path upgradient of the monitoring point and the parameters local to the monitoring point. We use regression statistics to rigorously evaluate the information content and sensitivity of fluid conductivity and geophysical data, demonstrating multiple scales of mass transfer parameters can simultaneously be estimated. Our results show, for the first time, field-scale spatial variability of mass transfer parameters (i.e., exchange-rate coefficient, porosity) between local and upgradient effective parameters; hence our approach provides insight into spatial variability and scaling behavior. Additional synthetic modeling is used to evaluate the scope of applicability of our approach, indicating greater range than earlier work using temporal moments and a Lagrangian-based Damköhler number. The introduced Eulerian-based Damköhler is useful for estimating tracer injection duration needed to evaluate mass transfer exchange rates that range over several orders of magnitude.
Upscaling transport with mass transfer models: Mean behavior and propagation of uncertainty
NASA Astrophysics Data System (ADS)
Fernã Ndez-Garcia, D.; Llerar-Meza, G.; Gómez-HernáNdez, J. Jaime
2009-10-01
The choice of an adequate large-scale conceptual transport model constitutes a major challenge associated with the upscaling of solute transport. Among the different alternatives to the classical advection-dispersion model, the (multirate) mass transfer model has been proposed as a valuable and convenient alternative to model the large-scale behavior of solute transport. This paper evaluates the use of mass transfer models as a constitutive equation for upscaling solute transport. To achieve this, we compare Monte Carlo simulations of solute transport at two different support scales. Transport simulations performed at the smallest scale represent a set of reference transport solutions described at a high resolution, which are contrasted against transport simulations obtained using an upscaled model (low resolution). Several formulations of the multirate mass transfer model, which differ in the type of memory function (single rate, double rate, and truncated power law), are used as a constitutive transport equation. The large-scale scenario represents a simplified model obtained by partially homogenizing the reference solution. Results show that the double-rate and the truncated power law mass transfer models are capable of properly describing the ensemble average behavior of the main features associated with the integrated breakthrough curves. However, the uncertainty associated with the upscaled mass transfer models was substantially smaller than that attributed to the reference solution. Importantly, the cumulative distribution function of concentrations associated with the upscaled model follows a distribution similar to the reference solution but with smaller statistical dispersion. The reason is that while appropriate memory functions can be used to preserve the residence time distribution of mass particles during upscaling, the lack of memory in space prevents the model from reproducing mass fluxes in all directions. Specifically, the reproduction of mass
Bridge Frost Prediction by Heat and Mass Transfer Methods
NASA Astrophysics Data System (ADS)
Greenfield, Tina M.; Takle, Eugene S.
2006-03-01
Frost on roadways and bridges can present hazardous conditions to motorists, particularly when it occurs in patches or on bridges when adjacent roadways are clear of frost. To minimize materials costs, vehicle corrosion, and negative environmental impacts, frost-suppression chemicals should be applied only when, where, and in the appropriate amounts needed to maintain roadways in a safe condition for motorists. Accurate forecasts of frost onset times, frost intensity, and frost disappearance (e.g., melting or sublimation) are needed to help roadway maintenance personnel decide when, where, and how much frost-suppression chemical to use. A finite-difference algorithm (BridgeT) has been developed that simulates vertical heat transfer in a bridge based on evolving meteorological conditions at its top and bottom as supplied by a weather forecast model. BridgeT simulates bridge temperatures at numerous points within the bridge (including its upper and lower surface) at each time step of the weather forecast model and calculates volume per unit area (i.e., depth) of deposited, melted, or sublimed frost. This model produces forecasts of bridge surface temperature, frost depth, and bridge condition (i.e., dry, wet, icy/snowy). Bridge frost predictions and bridge surface temperature are compared with observed and measured values to assess BridgeT's skill in forecasting bridge frost and associated conditions.
Volatile organic compound emission rate from diffused aeration systems. 1: Mass transfer modeling
Chern, J.M.; Yu, C.F.
1995-08-01
The activated sludge process is one of the most commonly used biochemical oxidation process for the secondary treatment of municipal and industrial wastewaters. The release of volatile organic compounds (VOCs) from wastewater treatment plants has recently caused great concern. In wastewater treatment plants, many operation units such s equalization and aeration involve oxygen transfer between wastewater and air. While oxygen is transferred from air to wastewater, VOCs are stripped from wastewater to air. Due to increasingly stringent environmental regulations, wastewater treatment operators have to do VOC inventory of their facilities. A mass transfer model for VOCs is therefore called for to assess VOC emission rates from wastewater treatment processes. Almost all existing methods adopt an oxygen mass transfer model standardized by the American Society of Civil Engineers (ASCE) to evaluate VOC emission rates. A new and more fundamental oxygen mass transfer model for diffused aeration systems was developed to assess the VOC emission rates. The new model provides better insight of the VOC mass transfer process and requires only aeration performance data to predict the VOC emission rates. The results and implications of both models were discussed and compared.
Baker, Jordan J; Crivellari, Francesca; Gagnon, Zachary; Betenbaugh, Michael J
2016-09-01
A microfluidic device (channels <70 μm) was utilized to create micro-scale bubbles to significantly increase mass transfer efficiency at low flow rates. The convergence of one gas and two liquid channels at a Y-junction generates bubbles via cyclic changes in pressure. At low flow rates, the bubbles had an average diameter of 110 μm, corresponding to a volumetric mass transfer KL a of 1.43 h(-1) . Values of KL a normalized per flow rate showed that the microbubbler had a 100-fold increased transfer efficiency compared to four other commonly used bubblers. The calculated percentage of oxygen transferred was approximately 90%, which was consistent with a separate off-gas analysis. The improved mass transfer was also tested in an algae bioreactor in which the microbubbler absorbed approximately 90% of the CO2 feed compared to 2% in the culture with an alternative needle bubbling method. The microbubbler yielded a cell density 82% of the cell density for the alternative needle tip with an 800-fold lower flow rate (0.5 mL/min versus 400 mL/min) and a 700-fold higher ratio of biomass to fed carbon dioxide. The application of microfluidics may transform interfacial processing in order to increase mass transfer efficiencies, minimize gas feeding, and provide for more sustainable multiphase processes. Biotechnol. Bioeng. 2016;113: 1924-1933. © 2016 Wiley Periodicals, Inc. PMID:26928403
NASA Astrophysics Data System (ADS)
Sheremet, M. A.; Shishkin, N. I.
2012-07-01
Mathematical simulation of the nonstationary regimes of heat-and-mass transfer in a ventilated rectangular cavity with heat-conducting walls of finite thickness in the presence of a heat-generating element of constant temperature has been carried out with account for the radiative heat transfer in the Rosseland approximation. As mechanisms of energy transfer in this cavity, the combined convection and the thermal radiation in the gas space of the cavity and the heat conduction in the elements of its fencing solid shell were considered. The mathematical model formulated in the dimensionless stream function-vorticity vector-temperature-concentration variables was realized numerically with the use of the finite-difference method. The streamline, temperature-field, and concentration distributions reflecting the influence of the Rayleigh number (Ra = 104, 105, 106), the nonstationarity (0 < τ ≤ 1000), and the optical thickness of the medium (τλ = 50, 100, 200) on the regimes of the gas flow and the heat-and-mass transfer in the cavity have been obtained.
Mass transfer and interfacial properties in two-phase microchannel flows
NASA Astrophysics Data System (ADS)
Martin, Jeffrey D.; Hudson, Steven D.
2009-11-01
Drop-based microfluidic devices are becoming more common, and molecular mass transfer and drop circulation are issues that often affect the performance of such devices. Moreover, interfacial properties and surfactant mass transfer rates govern emulsion behavior. Since these phenomena depend strongly on drop size, measurement methods using small drops and flow typical of applications are desired. Using mineral oil as a continuous phase, water droplets and an alcohol surfactant, we demonstrate here a microfluidic approach to measure the interrelated phenomena of dynamic interfacial tension, surfactant mass transfer and interfacial retardation that employs droplet flows in a microchannel with constrictions/expansions. Interfacial flow is influenced markedly by adsorption of surfactant: severe interfacial retardation (by a factor of 30) is observed at low surfactant concentrations and interface remobilization is observed at higher surfactant concentrations. The interfacial tension is described by Langmuir kinetics and the parameters for interfaces with mineral oil (studied here) compare closely with those previously found at air interfaces. For the conditions explored, the surfactant mass transfer is described well by a mixed kinetic-diffusion limited model, and the desorption rate coefficients are measured to be both approximately 70 s-1. The transition from a diffusion-controlled to mixed diffusion-kinetic mass transfer mechanism predicted with reducing drop size is verified. This experimental approach (i.e. adjustable geometry and drop size and height) can therefore probe interfacial dynamics in simple and complex flow.
Heat/Mass Transfer Measurement on The Tip Surface Of Rotor Blade With Squlear Rim
NASA Astrophysics Data System (ADS)
Park, Jun Su; Lee, Dong Hyun; Lee, Woo Jin; Cho, Hyung Hee; Rhee, Dong-Ho; Kang, Shin-Hyung
2010-06-01
The present study investigates local heat/mass transfer characteristics on blade tip surface with squealer rim. A linear cascade experimental setup consists of three large scale airfoils was used. The axial chord length and turning angle of test blade are 237 mm and 126°, respectively. Heat/mass transfer coefficients were measured with three different rim heights (3%, 6% and 9% of axial chord length) and fixed tip clearance (2% of axial chord length). Main flow Reynolds number based on axial chord length is 1.5×105. Naphthalene sublimation method is used to measure the detailed mass transfer coefficient on the blade tip surface. The heat/mass transfer results show that as the rim height increases, the peak values on the upstream region of the tip surface decreases and moves to the suction side rim. At the downstream region of the tip surface, the pitch-wise averaged heat/mass transfer coefficients increases as the rim height increases.
Calculation of the mass transfer coefficient for the combustion of a carbon particle
Scala, Fabrizio
2010-01-15
In this paper we address the calculation of the mass transfer coefficient around a burning carbon particle in an atmosphere of O{sub 2}, N{sub 2}, CO{sub 2}, CO, and H{sub 2}O. The complete set of Stefan-Maxwell equations is analytically solved under the assumption of no homogeneous reaction in the boundary layer. An expression linking the oxygen concentration and the oxygen flux at the particle surface (as a function of the bulk gas composition) is derived which can be used to calculate the mass transfer coefficient. A very simple approximate explicit expression is also given for the mass transfer coefficient, that is shown to be valid in the low oxygen flux limit or when the primary combustion product is CO{sub 2}. The results are given in terms of a correction factor to the equimolar counter-diffusion mass transfer coefficient, which is typically available in the literature for specific geometries and/or fluid-dynamic conditions. The significance of the correction factor and the accuracy of the different available expressions is illustrated for several cases of practical interest. Results show that under typical combustion conditions the use of the equimolar counter-diffusion mass transfer coefficient can lead to errors up to 10%. Larger errors are possible in oxygen-enriched conditions, while the error is generally low in oxy-combustion. (author)
Zhang, Y; Xiong, J; Mo, J; Gong, M; Cao, J
2016-02-01
Mass transfer is key to understanding and controlling indoor airborne organic chemical contaminants (e.g., VVOCs, VOCs, and SVOCs). In this study, we first introduce the fundamentals of mass transfer and then present a series of representative works from the past two decades, focusing on the most recent years. These works cover: (i) predicting and controlling emissions from indoor sources, (ii) determining concentrations of indoor air pollutants, (iii) estimating dermal exposure for some indoor gas-phase SVOCs, and (iv) optimizing air-purifying approaches. The mass transfer analysis spans the micro-, meso-, and macroscales and includes normal mass transfer modeling, inverse problem solving, and dimensionless analysis. These representative works have reported some novel approaches to mass transfer. Additionally, new dimensionless parameters such as the Little number and the normalized volume of clean air being completely cleaned in a given time period were proposed to better describe the general process characteristics in emissions and control of airborne organic compounds in the indoor environment. Finally, important problems that need further study are presented, reflecting the authors' perspective on the research opportunities in this area. PMID:25740682
Heat and mass transfer analysis for paraffin/nitrous oxide burning rate in hybrid propulsion
NASA Astrophysics Data System (ADS)
Ben-Basat (Sisi), Shani; Gany, Alon
2016-03-01
This research presents a physical-mathematical model for the combustion of liquefying fuels in hybrid combustors, accounting for blowing effect on the heat transfer. A particular attention is given to a paraffin/nitrous oxide hybrid system. The use of a paraffin fuel in hybrid propulsion has been considered because of its much higher regression rate enabling significantly higher thrust compared to that of common polymeric fuels. The model predicts the overall regression rate (melting rate) of the fuel and the different mechanisms involved, including evaporation, entrainment of droplets of molten material, and mass loss due to melt flow on the condensed fuel surface. Prediction of the thickness and velocity of the liquid (melt) layer formed at the surface during combustion was done as well. Applying the model for an oxidizer mass flux of 45 kg/(s m2) as an example representing experimental range, it was found that 21% of the molten liquid undergoes evaporation, 30% enters the gas flow by the entrainment mechanism, and 49% reaches the end of the combustion chamber as a flowing liquid layer. When increasing the oxidizer mass flux in the port, the effect of entrainment increases while that of the flowing liquid layer along the surface shows a relatively lower contribution. Yet, the latter is predicted to have a significant contribution to the overall mass loss. In practical applications it may cause reduced combustion efficiency and should be taken into account in the motor design, e.g., by reinforcing the paraffin fuel with different additives. The model predictions have been compared to experimental results revealing good agreement.
Quantification of colloidal and aqueous element transfer in soils: The dual-phase mass balance model
Bern, Carleton R.; Thompson, Aaron; Chadwick, Oliver A.
2015-01-01
Mass balance models have become standard tools for characterizing element gains and losses and volumetric change during weathering and soil development. However, they rely on the assumption of complete immobility for an index element such as Ti or Zr. Here we describe a dual-phase mass balance model that eliminates the need for an assumption of immobility and in the process quantifies the contribution of aqueous versus colloidal element transfer. In the model, the high field strength elements Ti and Zr are assumed to be mobile only as suspended solids (colloids) and can therefore be used to distinguish elemental redistribution via colloids from redistribution via dissolved aqueous solutes. Calculations are based upon element concentrations in soil, parent material, and colloids dispersed from soil in the laboratory. We illustrate the utility of this model using a catena in South Africa. Traditional mass balance models systematically distort elemental gains and losses and changes in soil volume in this catena due to significant redistribution of Zr-bearing colloids. Applying the dual-phase model accounts for this colloidal redistribution and we find that the process accounts for a substantial portion of the major element (e.g., Al, Fe and Si) loss from eluvial soil. In addition, we find that in illuvial soils along this catena, gains of colloidal material significantly offset aqueous elemental loss. In other settings, processes such as accumulation of exogenous dust can mimic the geochemical effects of colloid redistribution and we suggest strategies for distinguishing between the two. The movement of clays and colloidal material is a major process in weathering and pedogenesis; the mass balance model presented here is a tool for quantifying effects of that process over time scales of soil development.
Processes of heat and mass transfer in straw bales using flue gasses as a drying medium
NASA Astrophysics Data System (ADS)
Goryl, Wojciech; Szubel, Mateusz; Filipowicz, Mariusz
2016-03-01
Moisture content is a main problem of using straw in form of bales for energy production. The paper presents possibility of straw drying in dedicated, innovative and patented in Poland straw dryers which using flue gasses as a drying medium. Paper presents an improved way of drying which proved to be very sufficient. Temperature and humidity of straw during the process of drying were measured. The measurements helped understand and perform numerical model of heat and mass transfer inside the straw bale. By using CFD codes it was possible to perform analysis of phenomenon occurring inside the dried straw bale. Based on the CFD model, proposals of the optimization and improvement process of drying have been discussed. Experimental and computational data have been compared in terms of convergence. A satisfying degree of agreement has been achieved. Applying improved drying method, homogenous field of moisture content and temperature in the straw bale is achieved in a very cost effective way.
A NUMERICAL METHOD FOR STUDYING SUPER-EDDINGTON MASS TRANSFER IN DOUBLE WHITE DWARF BINARIES
Marcello, Dominic C.; Tohline, Joel E. E-mail: tohline@phys.lsu.edu
2012-04-01
We present a numerical method for the study of double white dwarf (DWD) binary systems at the onset of super-Eddington mass transfer. We incorporate the physics of ideal inviscid hydrodynamical flow, Newtonian self-gravity, and radiation transport on a three-dimensional uniformly rotating cylindrical Eulerian grid. Care has been taken to conserve the key physical quantities such as angular momentum and energy. Our new method conserves total energy to a higher degree of accuracy than other codes that are presently being used to model mass transfer in DWD systems. We present the results of verification tests and simulate the first 20 + orbits of a binary system of mass ratio q 0.7 at the onset of dynamically unstable direct impact mass transfer. The mass transfer rate quickly exceeds the critical Eddington limit by many orders of magnitude, and thus we are unable to model a trans-Eddington phase. It appears that radiation pressure does not significantly affect the accretion flow in the highly super-Eddington regime. An optically thick common envelope forms around the binary within a few orbits. Although this envelope quickly exceeds the spatial domain of the computational grid, the fraction of the common envelope that exceeds zero gravitational binding energy is extremely small, suggesting that radiation-driven mass loss is insignificant in this regime. It remains to be seen whether simulations that capture the trans-Eddington phase of such flows will lead to the same conclusion or show that substantial material gets expelled.
Quantitative spatially resolved measurements of mass transfer through laryngeal cartilage.
Macpherson, J V; O'Hare, D; Unwin, P R; Winlove, C P
1997-11-01
The scanning electrochemical microscope (SECM) is a scanned probe microscope that uses the response of a mobile ultramicroelectrode (UME) tip to determine the reactivity, topography, and mass transport characteristics of interfaces with high spatial resolution. SECM strategies for measuring the rates of solute diffusion and convection through samples of cartilage, using amperometric UMEs, are outlined. The methods are used to determine the diffusion coefficients of oxygen and ruthenium(III) hexamine [Ru(NH3)6(3+)] in laryngeal cartilage. The diffusion coefficient of oxygen in cartilage is found to be approximately 50% of that in aqueous electrolyte solution, assuming a partition coefficient of unity for oxygen between cartilage and aqueous solution. In contrast, diffusion of Ru(NH3)6(3+) within the cartilage sample cannot be detected on the SECM timescale, suggesting a diffusion coefficient at least two orders of magnitude lower than that in solution, given a measured partition coefficient for Ru(NH3)6(3+) between cartilage and aqueous solution, Kp = [Ru(NH3)6(3+)]cartilage/[RU(NH3)6(3+)]solution = 3.4 +/- 0.1. Rates of Ru(NH3)6(3+) osmotically driven convective transport across cartilage samples are imaged at high spatial resolution by monitoring the current response of a scanning UME, with an osmotic pressure of approximately 0.75 atm across the slice. A model is outlined that enables the current response to be related to the local flux. By determining the topography of the sample from the current response with no applied osmotic pressure, local transport rates can be correlated with topographical features of the sample surface, at much higher spatial resolution than has previously been achieved. PMID:9370471
Quantitative spatially resolved measurements of mass transfer through laryngeal cartilage.
Macpherson, J V; O'Hare, D; Unwin, P R; Winlove, C P
1997-01-01
The scanning electrochemical microscope (SECM) is a scanned probe microscope that uses the response of a mobile ultramicroelectrode (UME) tip to determine the reactivity, topography, and mass transport characteristics of interfaces with high spatial resolution. SECM strategies for measuring the rates of solute diffusion and convection through samples of cartilage, using amperometric UMEs, are outlined. The methods are used to determine the diffusion coefficients of oxygen and ruthenium(III) hexamine [Ru(NH3)6(3+)] in laryngeal cartilage. The diffusion coefficient of oxygen in cartilage is found to be approximately 50% of that in aqueous electrolyte solution, assuming a partition coefficient of unity for oxygen between cartilage and aqueous solution. In contrast, diffusion of Ru(NH3)6(3+) within the cartilage sample cannot be detected on the SECM timescale, suggesting a diffusion coefficient at least two orders of magnitude lower than that in solution, given a measured partition coefficient for Ru(NH3)6(3+) between cartilage and aqueous solution, Kp = [Ru(NH3)6(3+)]cartilage/[RU(NH3)6(3+)]solution = 3.4 +/- 0.1. Rates of Ru(NH3)6(3+) osmotically driven convective transport across cartilage samples are imaged at high spatial resolution by monitoring the current response of a scanning UME, with an osmotic pressure of approximately 0.75 atm across the slice. A model is outlined that enables the current response to be related to the local flux. By determining the topography of the sample from the current response with no applied osmotic pressure, local transport rates can be correlated with topographical features of the sample surface, at much higher spatial resolution than has previously been achieved. Images FIGURE 6 FIGURE 7 FIGURE 8 PMID:9370471
A holographic interferometric method to study combined heat and mass transfer in film sorption
NASA Astrophysics Data System (ADS)
Zheng, G.; Worek, W. M.
1992-08-01
Sorption by a liquid desiccant is a key process in open-cycle, liquid desiccant cooling systems. In order to study the absorption rates in a liquid desiccant, a fiber-optic, double-wavelength holographic interferometric method was developed and used to measure the combined heat and mass transfer processes that occurred during a regeneration process. In the experiment, the heat and mass transfer processes that occur at the interface between a dry air stream and either a liquid desiccant or a film of water are investigated. The temperature and concentration distribution were calculated and the results were used to determine the Lewis number Le and the local heat and mass transfer coefficients.
Thermodynamics and mass transfer kinetics of phenol in reversed phase liquid chromatography
Kaczmarski, Krzysztof; Gritti, Fabrice; Guiochon, Georges A
2006-05-01
The thermodynamics and the mass transfer kinetics of the chromatographic system made of phenol, in a water-acetonitrile mobile phase, on a C18 RPLC column, were studied in the temperature range from 21 to 77 C and the interstitial velocity range of 0.021 to 1.27 cm/s. The equilibrium isotherm was accurately approximated by a multilayer model assuming lateral interactions between adsorbed molecules. The parameters of the kinetics of the phenol mass transfer in this column were measured by the method of moments. These data were analyzed using the available models and correlations. It was proven that the parameters of the mass transfer kinetics measured under linear conditions could be successfully used for the prediction of the concentration profiles obtained under overloaded conditions.
A Novel Model for the Mass Transfer of Articular Cartilage: Rolling Depression Load Device
NASA Astrophysics Data System (ADS)
Fan, Zhenmin; Zhang, Chunqiu; Liu, Haiying; Xu, Baoshan; Li, Jiang; Gao, Lilan
The mass transfer is one of important aspects to maintain the physiological activity proper of tissue, specially, cartilage cannot run without mechanical environment. The mechanical condition drives nutrition in and waste out in the cartilage tissue, the change of this process plays a key role for biological activity. Researchers used to adopt compression to study the mass transfer in cartilage, here we firstly establish a new rolling depression load (RDL) device, and also put this device into practice. The device divided into rolling control system and the compression adjusting mechanism. The rolling control system makes sure the pure rolling and uniform speed of roller applying towards cultured tissue. The compression adjusting mechanism can realize different compressive magnitudes and uniform compression. Preliminary test showed that rolling depression load indeed enhances the process of mass transfer articular cartilage.
Permanently reconfigured metamaterials due to terahertz induced mass transfer of gold.
Strikwerda, Andrew C; Zalkovskij, Maksim; Iwaszczuk, Krzysztof; Lorenzen, Dennis Lund; Jepsen, Peter Uhd
2015-05-01
We present a new technique for permanent metamaterial reconfiguration via optically induced mass transfer of gold. This mass transfer, which can be explained by field-emission induced electromigration, causes a geometric change in the metamaterial sample. Since a metamaterial's electromagnetic response is dictated by its geometry, this structural change massively alters the metamaterial's behavior. We show this by optically forming a conducting pathway between two closely spaced dipole antennas, thereby changing the resonance frequency by a factor of two. After discussing the physics of the process, we conclude by presenting an optical fuse that can be used as a sacrificial element to protect sensitive components, demonstrating the applicability of optically induced mass transfer for device design. PMID:25969252
Cheung, M C; Wolfbauer, G; Albers, J J
1996-09-27
Human plasma phospholipid transfer protein (PLTP) has been shown to facilitate the transfer of phospholipid from liposomes or isolated very low and low density lipoproteins to high density lipoproteins. Its activity in plasma and its physiological function are presently unknown. To elucidate the role of PLTP in lipoprotein metabolism and to delineate factors that may affect the rate of phospholipid transfer between lipoproteins, we determined the plasma phospholipid mass transfer rate (PLTR) in 16 healthy adult volunteers and assessed its relationship to plasma lipid levels, and to phospholipid transfer activity (PLTA) and cholesteryl ester transfer activity (CETA) measured by radioassays. The plasma PLTR in these subjects was 27.2 +/- 11.8 nmol/ml per h at 37 degrees C (mean +/- S.D.), and their PLTA and CETA were 13.0 +/- 1.7 mumol/ml per h and 72.8 +/- 15.7 nmol/ml per h, respectively. Plasma PLTR was correlated directly with total, non-HDL, and HDL triglyceride (rs = 0.76, P < 0.001), total and non-HDL phospholipid (rs > 0.53, P < 0.05), and inversely with HDL free cholesterol (rs = -0.54, P < 0.05), but not with plasma PLTA and CETA. When 85% to 96% of the PLTA in plasma was removed by polyclonal antibodies against recombinant human PLTP, phospholipid mass transfer from VLDL and LDL to HDL was reduced by 50% to 72%, but 80% to 100% of CETA could still be detected. These studies demonstrate that PLTP plays a major role in facilitating the transfer of phospholipid between lipoproteins, and suggest that triglyceride is a significant modulator of intravascular phospholipid transport. Furthermore, most of the PLTP and CETP in human plasma is associated with different particles. Plasma PLTA and CETA were also measured in mouse, rat, hamster, guinea pig, rabbit, dog, pig, and monkey. Compared to human, PLTA in rat and mouse was significantly higher and in rabbit and guinea pig was significantly lower while the remaining animal species had PLTA similar to humans. No
Surface term effects on mass estimators
NASA Astrophysics Data System (ADS)
Membrado, M.; Pacheco, A. F.
2016-05-01
Context. We propose a way of estimating the mass contained in the volume occupied by a sample of galaxies in a virialized system. Aims: We analyze the influence of surface effects and the contribution of the cosmological constant terms on our mass estimations of galaxy systems. Methods: We propose two equations that contain surface terms to estimate galaxy sample masses. When the surface terms are neglected, these equations provide the so-called virial and projected masses. Both equations lead to a single equation that allows sample masses to be estimated without the need for calculating surface terms. Sample masses for some nearest galaxy groups are estimated and compared with virialized masses determined from turn-around radii and results of a spherical infall model. Results: Surface effects have a considerable effect on the mass estimations of the studied galaxy groups. According to our results, they lead sample masses of some groups to being less than half the virial mass estimations and even less than 10% of projected mass estimations. However, the contributions of cosmological constant terms to mass estimations are smaller than 2% for the majority of the virialized groups studied. Our estimations are in agreement with virialized masses calculated from turn-around radii. Virialized masses for complexes were found to be: (8.9 ± 2.8) × 1011 M⊙ for the Milky Way - M 31; (12.5 ± 2.5) × 1011 M⊙ for M 81 - NGC 2403; (21.5 ± 7.7) × 1011 M⊙. for Cantaurs A - M 83; and (7.9 ± 2.6) × 1011 M⊙. for IC 324 - Maffei. Conclusions: The nearest galaxy groups located inside a sphere of 5 Mpc have been addressed to explore the performance of our mass estimator. We have seen that surface effects make mass estimations of galaxy groups rather smaller than both virial and projected masses. In mass calculations, cosmological constant terms can be neglected; nevertheless, the collapse of cold dark matter leading to virialized structures is strongly affected by the
Cheng, K H; Cheng, Y S; Yeh, H C; Swift, D L
1997-11-01
This paper presents measurements of the geometric shape, perimeter, and cross-sectional area of the human oral passage (from oral entrance to midtrachea) and relates them through dimensionless parameters to the depositional mass transfer of ultrafine particles. Studies were performed in two identical replicate oral passage models, one of which was cut orthogonal to the airflow direction into 3 mm elements for measurement, the other used intact for experimental measurements of ultrafine aerosol deposition. Dimensional data were combined with deposition measurements in two sections of the oral passage (the horizontal oral cavity and the vertical laryngeal-tracheal airway) to calculate the dimensionless mass transfer Sherwood number (Sh). Mass transfer theory suggests that Sh should be expressible as a function of the Reynolds number (Re) and the Schmidt number (Sc). For inhalation and exhalation through the oral cavity (O-C), an empirical relationship was obtained for flow rates from 7.5-30.0 1 min-1: Sh = 15.3 Re0.812 Sc-0.986 An empirical relationship was likewise obtained for the laryngeal-tracheal (L-T) region over the same range of flow rates: Sh = 25.9 Re0.861 Sc-1.37 These relationships were compared to heat transfer in the human upper airways through the well-known analogy between heat and mass transfer. The Reynolds number dependence for both the O-C and L-T relationships was in good agreement with that for heat transfer. The mass transfer coefficients were compared to extrathoracic uptake of gases and vapors and showed similar flow rate dependence. For gases and vapors that conform to the zero concentration boundary condition, the empirical relationships are applicable when diffusion coefficients are taken into consideration. PMID:9407288
NASA Astrophysics Data System (ADS)
Mansour, M. A.; El-Hakiem, M. A.; El Kabeir, S. M.
2000-10-01
Steady laminar boundary layer analysis of heat and mass transfer characteristics in magnetohydrodynamic (MHD) flow of a micropolar fluid on a circular cylinder maintained at uniform heat and mass flux has been conducted. The solution of the energy equation inside the boundary layer is obtained as a power series of the distance measured along the surface from the front stagnation point of the cylinder. The results of dimensionless temperature, Nusselt number, wall shear stress, wall couple stress and Sherwood number have been presented graphically for various values of the material parameters. The results indicate that the micropolar fluids display a reduction in drag as well as heat transfer rate when compared with Newtonian fluids.
Mass Fractionation Laws, Mass-Independent Effects, and Isotopic Anomalies
NASA Astrophysics Data System (ADS)
Dauphas, Nicolas; Schauble, Edwin A.
2016-06-01
Isotopic variations usually follow mass-dependent fractionation, meaning that the relative variations in isotopic ratios scale with the difference in mass of the isotopes involved (e.g., δ17O ≈ 0.5×δ18O). In detail, however, the mass dependence of isotopic variations is not always the same, and different natural processes can define distinct slopes in three-isotope diagrams. These variations are subtle, but improvements in analytical capabilities now allow precise measurement of these effects and make it possible to draw inferences about the natural processes that caused them (e.g., reaction kinetics versus equilibrium isotope exchange). Some elements, in some sample types, do not conform to the regularities of mass-dependent fractionation. Oxygen and sulfur display a rich phenomenology of mass-independent fractionation, documented in the laboratory, in the rock record, and in the modern atmosphere. Oxygen in meteorites shows isotopic variations that follow a slope-one line (δ17O ≈ δ18O) whose origin may be associated with CO photodissociation. Sulfur mass-independent fractionation in ancient sediments provides the tightest constraint on the oxygen partial pressure in the Archean and the timing of Earth's surface oxygenation. Heavier elements also show departures from mass fractionation that can be ascribed to exotic effects associated with chemical reactions such as magnetic effects (e.g., Hg) or the nuclear field shift effect (e.g., U or Tl). Some isotopic variations in meteorites and their constituents cannot be related to the terrestrial composition by any known process, including radiogenic, nucleogenic, and cosmogenic effects. Those variations have a nucleosynthetic origin, reflecting the fact that the products of stellar nucleosynthesis were not fully homogenized when the Solar System formed. Those anomalies are found at all scales, from nanometer-sized presolar grains to bulk terrestrial planets. They can be used to learn about stellar
Tribological behavior of a friction couple functioning with selective mass transfer
NASA Astrophysics Data System (ADS)
Ilie, Filip
2016-06-01
Experimental researches on different lubricated friction couples, have confirmed that it is useful to investigate thermodynamic processes which are unstable in lubricant and on the friction couples surfaces in the first stage of the friction process. This presupposes that, in operating conditions, physical-chemical processes which are favourable to friction, such as: polymerization, formation of colloids, formation of other active substances at the contact surfaces and of other compounds with low resistance to shear take place. Friction in such conditions takes place with selective mass transfer, and it is used there where the friction of the mixed and adherence layers is not safe enough, or the durability of the friction couples is not assured. The selective mass transfer allows the transfer of some elements of the materials in contact from one surface to the other, covering them with a thin, superficial layer, with superior properties at minimal friction and wear. The aim of this paper is to analyse the physical-chemical factors and the proper processes for achieving the selective mass transfer for the couple steel/bronze, which in optimal conditions, forms a thin layer of copper on the contact surfaces areas. Also, it presents some studies and researches concerning the tribological behaviour of the surfaces of a friction couple with linear contact (roll/roll) which operates with selective mass transfer, tested on Amsler tribometer.
NASA Astrophysics Data System (ADS)
Solis, Kyle J.; Martin, James E.
2012-11-01
Isothermal magnetic advection (IMA) is a recently discovered method of inducing highly organized, non-contact flow lattices in suspensions of magnetic particles, using only uniform ac magnetic fields of modest strength. The initiation of these vigorous flows requires neither a thermal gradient nor a gravitational field, and so can be used to transfer heat and mass in circumstances where natural convection does not occur. These advection lattices are comprised of a square lattice of antiparallel flow columns. If the column spacing is sufficiently large compared to the column length and the flow rate within the columns is sufficiently large, then one would expect efficient transfer of both heat and mass. Otherwise, the flow lattice could act as a countercurrent heat exchanger and only mass will be efficiently transferred. Although this latter case might be useful for feeding a reaction front without extracting heat, it is likely that most interest will be focused on using IMA for heat transfer. In this paper, we explore the various experimental parameters of IMA to determine which of these can be used to control the column spacing. These parameters include the field frequency, strength, and phase relation between the two field components, the liquid viscosity, and particle volume fraction. We find that the column spacing can easily be tuned over a wide range to enable the careful control of heat and mass transfer.
Gondrexon, N; Cheze, L; Jin, Y; Legay, M; Tissot, Q; Hengl, N; Baup, S; Boldo, P; Pignon, F; Talansier, E
2015-07-01
This paper aims to illustrate the interest of ultrasound technology as an efficient technique for both heat and mass transfer intensification. It is demonstrated that the use of ultrasound results in an increase of heat exchanger performances and in a possible fouling monitoring in heat exchangers. Mass transfer intensification was observed in the case of cross-flow ultrafiltration. It is shown that the enhancement of the membrane separation process strongly depends on the physico-chemical properties of the filtered suspensions. PMID:25216897
Influence of Mass Transfer on Bioavailability and Kinetic Rate of Uranium(VI) Biotransformation
Chongxuan Liu; Zheming Wang; John M. Zachara; James K. Fredrickson
2006-06-01
This research is investigating the influence of mass transfer process on the rate and extent of microbial reduction of U(VI) associated with intragrain domains in the Hanford subsurface sediments. The project will develop instrumental techniques to characterize microscopic mass transfer process at the sediment grain scale and to develop kinetic data and process models that describe microbial reduction of intragrain U(VI). Scientific knowledge and process models developed from this research will enhance our understanding on the future behavior of in-ground U(VI) at Hanford and other DOE sites where sediments contain U(VI) in intragrain domains or fracture-matrix systems.
Mathematical Modeling of Mass Transfer in Laminar Motion of a Droplet in a Liquid Medium
NASA Astrophysics Data System (ADS)
Elizarov, D. V.; Elizarov, V. V.; Kamaliev, T. S.; D‧yakonov, S. G.
2016-03-01
Consideration is given to mathematical modeling of the process of nonstationary liquid-liquid extraction in apparatuses with free motion of a dispersed phase. Solutions of nonstationary equations of transfer of momentum and mass in the boundary layer on the droplet and inside the droplet near the phase boundary are given. Equations for calculation of the coefficients of mass transfer and concentration of the extracted component are obtained. A comparison is made of the calculated data and experimental results in extracting various liquid mixtures.
43 CFR 3106.7-5 - Effect of transfer.
Code of Federal Regulations, 2011 CFR
2011-10-01
... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Effect of transfer. 3106.7-5 Section 3106... MANAGEMENT, DEPARTMENT OF THE INTERIOR MINERALS MANAGEMENT (3000) OIL AND GAS LEASING Transfers by Assignment, Sublease or Otherwise § 3106.7-5 Effect of transfer. A transfer of record title to 100 percent of a...
Effects of nonlocality on transfer reactions
NASA Astrophysics Data System (ADS)
Titus, Luke
Nuclear reactions play a key role in the study of nuclei away from stability. Single-nucleon transfer reactions involving deuterons provide an exceptional tool to study the single-particle structure of nuclei. Theoretically, these reactions are attractive as they can be cast into a three-body problem composed of a neutron, proton, and the target nucleus. Optical potentials are a common ingredient in reactions studies. Traditionally, nucleon-nucleus optical potentials are made local for convenience. The effects of nonlocal potentials have historically been included approximately by applying a correction factor to the solution of the corresponding equation for the local equivalent interaction. This is usually referred to as the Perey correction factor. In this thesis, we have systematically investigated the effects of nonlocality on (p,d) and (d,p) transfer reactions, and the validity of the Perey correction factor. We implemented a method to solve the single channel nonlocal equation for both bound and scattering states. We also developed an improved formalism for nonlocal interactions that includes deuteron breakup in transfer reactions. This new formalism, the nonlocal adiabatic distorted wave approximation, was used to study the effects of including nonlocality consistently in ( d,p) transfer reactions. For the (p,d) transfer reactions, we solved the nonlocal scattering and bound state equations using the Perey-Buck type interaction, and compared to local equivalent calculations. Using the distorted wave Born approximation we construct the T-matrix for (p,d) transfer on 17O, 41Ca, 49Ca, 127 Sn, 133Sn, and 209Pb at 20 and 50 MeV. Additionally we studied (p,d) reactions on 40Ca using the the nonlocal dispersive optical model. We have also included nonlocality consistently into the adiabatic distorted wave approximation and have investigated the effects of nonlocality on on (d,p) transfer reactions for deuterons impinged on 16O, 40Ca, 48Ca, 126Sn, 132Sn, 208Pb at 10
NASA Astrophysics Data System (ADS)
Volchkov, E. P.; Boyarshinov, B. F.; Titkov, V. I.
2002-07-01
Uncertainty of evaluation of each factor (separation laminar-turbulent transition combustion and turbulization) hinders mathematical simulation of the joint effect on gas dynamic and thermal characteristics of the boundary layer. The characteristics may be most reliably determined experimentally. The work objective is the experimental study of the boundary layer structure comparison of the fields of temperature velocity and its pulsation with data on heat and mass transfer.
LUT Reveals a New Mass-transferring Semi-detached Binary
NASA Astrophysics Data System (ADS)
Qian, S.-B.; Zhou, X.; Zhu, L.-Y.; Zejda, M.; Soonthornthum, B.; Zhao, E.-G.; Zhang, J.; Zhang, B.; Liao, W.-P.
2015-12-01
GQ Dra is a short-period eclipsing binary in a double stellar system that was discovered by Hipparcos. Complete light curves in the UV band were obtained with the Lunar-based Ultraviolet Telescope in 2014 November and December. Photometric solutions are determined using the W-D (Wilson and Devinney) method. It is discovered that GQ Dra is a classical Algol-type semi-detached binary where the secondary component is filling the critical Roche lobe. An analysis of all available times of minimum light suggests that the orbital period is increasing continuously at a rate of \\dot{P}=+3.48(+/- 0.23)× {10}-7 days yr-1. This could be explained by mass transfer from the secondary to the primary, which is in agreement with the semi-detached configuration with a lobe-filling secondary. By assuming a conservation of mass and angular momentum, the mass transfer rate is estimated as \\dot{m}=9.57(+/- 0.63)× {10}-8 {M}⊙ {{yr}}-1. All of these results reveal that GQ Dra is a mass-transferring semi-detached binary in a double system that was formed from an initially detached binary star. After the massive primary evolves to fill the critical Roche lobe, the mass transfer will be reversed and the binary will evolve into a contact configuration with two sub-giant or giant component stars.
Heat/mass transfer and flow characteristics of pin fin cooling channels in turbine blades
NASA Astrophysics Data System (ADS)
Lau, S. C.; Saxena, A.
Experiments studied the local heat/mass transfer distributions and pressure drops in pin fin channels that modeled internal cooling passages in gas turbine blades. Heat/mass transfer distributions were determined for a straight flow through a pin fin channel (H/D = 1.0, X/D = S/D = 2.5) and a flow through the pin fin channel with trailing edge flow ejection. The overall friction factor and local pressure drop results were obtained for various configurations and lengths of the trailing edge ejection holes. The results show that, when there is trailing edge flow ejection, the main flow stream turns toward the trailing edge ejection holes. The wake regions downstream of the pins and the regions affected by secondary flow shift toward the ejection holes. The local channel wall heat/mass transfer is generally high immediately upstream of a pin, in the wake region downstream of a pin, and in the regions affected by secondary flow. In the case with trailing edge flow ejection, the heat/mass transfer generally decreases in the radial direction as a result of the reducing radial mass flow rate. The overall friction is higher when the trailing edge ejection holes are longer and when they are configured such that more flow is forced further downstream in the pin fin channel before exiting through the ejection holes.
NASA Astrophysics Data System (ADS)
Mobile, Michael; Widdowson, Mark; Stewart, Lloyd; Nyman, Jennifer; Deeb, Rula; Kavanaugh, Michael; Mercer, James; Gallagher, Daniel
2016-04-01
Better estimates of non-aqueous phase liquid (NAPL) mass, its persistence into the future, and the potential impact of source reduction are critical needs for determining the optimal path to clean up sites impacted by NAPLs. One impediment to constraining time estimates of source depletion is the uncertainty in the rate of mass transfer between NAPLs and groundwater. In this study, an innovative field test is demonstrated for the purpose of quantifying field-scale NAPL mass transfer coefficients (klN) within a source zone of a fuel-contaminated site. Initial evaluation of the test concept using a numerical model revealed that the aqueous phase concentration response to the injection of clean groundwater within a source zone was a function of NAPL mass transfer. Under rate limited conditions, NAPL dissolution together with the injection flow rate and the radial distance to monitoring points directly controlled time of travel. Concentration responses observed in the field test were consistent with the hypothetical model results allowing field-scale NAPL mass transfer coefficients to be quantified. Site models for groundwater flow and solute transport were systematically calibrated and utilized for data analysis. Results show klN for benzene varied from 0.022 to 0.60 d- 1. Variability in results was attributed to a highly heterogeneous horizon consisting of layered media of varying physical properties.
Mobile, Michael; Widdowson, Mark; Stewart, Lloyd; Nyman, Jennifer; Deeb, Rula; Kavanaugh, Michael; Mercer, James; Gallagher, Daniel
2016-04-01
Better estimates of non-aqueous phase liquid (NAPL) mass, its persistence into the future, and the potential impact of source reduction are critical needs for determining the optimal path to clean up sites impacted by NAPLs. One impediment to constraining time estimates of source depletion is the uncertainty in the rate of mass transfer between NAPLs and groundwater. In this study, an innovative field test is demonstrated for the purpose of quantifying field-scale NAPL mass transfer coefficients (kl(N)) within a source zone of a fuel-contaminated site. Initial evaluation of the test concept using a numerical model revealed that the aqueous phase concentration response to the injection of clean groundwater within a source zone was a function of NAPL mass transfer. Under rate limited conditions, NAPL dissolution together with the injection flow rate and the radial distance to monitoring points directly controlled time of travel. Concentration responses observed in the field test were consistent with the hypothetical model results allowing field-scale NAPL mass transfer coefficients to be quantified. Site models for groundwater flow and solute transport were systematically calibrated and utilized for data analysis. Results show kl(N) for benzene varied from 0.022 to 0.60d(-1). Variability in results was attributed to a highly heterogeneous horizon consisting of layered media of varying physical properties. PMID:26855386
Plasma effects in high frequency radiative transfer
Alonso, C.T.
1981-02-08
This paper is intended as a survey of collective plasma processes which can affect the transfer of high frequency radiation in a hot dense plasma. We are rapidly approaching an era when this subject will become important in the laboratory. For pedagogical reasons we have chosen to examine plasma processes by relating them to a particular reference plasma which will consist of fully ionized carbon at a temperature kT=1 KeV (10/sup 70/K) and an electron density N = 3 x 10/sup 23/cm/sup -3/, (which corresponds to a mass density rho = 1 gm/cm/sup 3/ and an ion density N/sub i/ = 5 x 10/sup 22/ cm/sup -3/). We will consider the transport in such a plasma of photons ranging from 1 eV to 1 KeV in energy. Such photons will probably be frequently used as diagnostic probes of hot dense laboratory plasmas.
AW Ursae Majoris: a semidetached mass-transferring system indeed?
NASA Astrophysics Data System (ADS)
Eaton, Joel A.
2016-03-01
I have reinterpreted Rucinski's line profiles (broadening functions) for the hot A-type W Ursae Majoris binary AW UMa in terms of various contact models, finding that the detached/semidetached geometry he postulates does not fit the system's light variation or its line profiles. The highly overcontact geometry that actually fits the system's ellipsoidal light variation reproduce the total breadth of the lines but give profiles too broad to fit their shapes. The best solution to this dilemma is differential rotation of both stars in which the mid-latitudes are rotating 20-30 per cent slower than synchronously. This approach preserves the traditional light-curve solution and explains the drift of ripples seen in the line profiles. In addition, there are obviously other flows superimposed on the rotation which make the profiles asymmetrical. Fitting the line profiles is complicated by uncertainties in how the equivalent widths of the lines change with effective temperature and how much they are limb darkened. The contribution of any point on the stellar surface to the equivalent width depends only very weakly on local temperature throughout the range of W UMa binaries. The limb darkening of the lines is probably small, although the effect remains unexplored. I also speculate about the nature of hypothetical star-spots in this system.
Estimation of cauliflower mass transfer parameters during convective drying
NASA Astrophysics Data System (ADS)
Sahin, Medine; Doymaz, İbrahim
2016-05-01
The study was conducted to evaluate the effect of pre-treatments such as citric acid and hot water blanching and air temperature on drying and rehydration characteristics of cauliflower slices. Experiments were carried out at four different drying air temperatures of 50, 60, 70 and 80 °C with the air velocity of 2.0 m/s. It was observed that drying and rehydration characteristics of cauliflower slices were greatly influenced by air temperature and pre-treatment. Six commonly used mathematical models were evaluated to predict the drying kinetics of cauliflower slices. The Midilli et al. model described the drying behaviour of cauliflower slices at all temperatures better than other models. The values of effective moisture diffusivities (D eff ) were determined using Fick's law of diffusion and were between 4.09 × 10-9 and 1.88 × 10-8 m2/s. Activation energy was estimated by an Arrhenius type equation and was 23.40, 29.09 and 26.39 kJ/mol for citric acid, blanch and control samples, respectively.
Fundamental mass transfer modeling of emission of volatile organic compounds from building materials
NASA Astrophysics Data System (ADS)
Bodalal, Awad Saad
In this study, a mass transfer theory based model is presented for characterizing the VOC emissions from building materials. A 3-D diffusion model is developed to describe the emissions of volatile organic compounds (VOCs) from individual sources. Then the formulation is extended to include the emissions from composite sources (system comprising an assemblage of individual sources). The key parameters for the model (The diffusion coefficient of the VOC in the source material D, and the equilibrium partition coefficient k e) were determined independently (model parameters are determined without the use of chamber emission data). This procedure eliminated to a large extent the need for emission testing using environmental chambers, which is costly, time consuming, and may be subject to confounding sink effects. An experimental method is developed and implemented to measure directly the internal diffusion (D) and partition coefficients ( ke). The use of the method is illustrated for three types of VOC's: (i) Aliphatic Hydrocarbons, (ii) Aromatic Hydrocarbons and ( iii) Aldehydes, through typical dry building materials (carpet, plywood, particleboard, vinyl floor tile, gypsum board, sub-floor tile and OSB). Then correlations for predicting D and ke based solely on commonly available properties such as molecular weight and vapour pressure were proposed for each product and type of VOC. These correlations can be used to estimate the D and ke when direct measurement data are not available, and thus facilitate the prediction of VOC emissions from the building materials using mass transfer theory. The VOC emissions from a sub-floor material (made of the recycled automobile tires), and a particleboard are measured and predicted. Finally, a mathematical model to predict the diffusion coefficient through complex sources (floor adhesive) as a function of time was developed. Then this model (for diffusion coefficient in complex sources) was used to predict the emission rate from
Experimental and theoretical investigation of heat and mass transfer processes during wood pyrolysis
Park, Won Chan; Atreya, Arvind; Baum, Howard R.
2010-03-15
Thermal decomposition of 25.4 mm diameter dry wood spheres is studied both experimentally and theoretically. Wood spheres were pyrolyzed in a vertical tube furnace at temperatures ranging from 638 K to 879 K. Mass loss and temperatures of the sample were measured during pyrolysis. Center temperature measurements showed two distinct thermal events consisting of sequential endothermic and exothermic reactions. A numerical investigation of these endo/exothermic reactions using various pyrolysis kinetics models was conducted to determine the pyrolysis mechanism and the heats of the pyrolysis reactions. A comparison of the experimental and numerical results showed that (i) Contrary to the suggestions in the literature, the contributions of the secondary tar decomposition and lignin decomposition to the center temperature exothermic peak are small. (ii) Exothermic decomposition of the intermediate solid is responsible for the center temperature peak. (iii) The center temperature plateau is caused by the endothermic decomposition of cellulose. (iv) Internal pressure generation was found to be quite important because it controls the pyrolyzate mass transfer and thus affects both the heat transfer and the residence time of the pyrolysis gases for secondary decomposition. Based on the experimental and numerical results, a new wood pyrolysis model is proposed. The model consists of three endothermic parallel reactions producing tar, gas and intermediate solid and subsequent exothermic decomposition of the intermediate solid to char and exothermic decomposition of tar to char and gas. The proposed pyrolysis model shows good agreement with the experiments. Pressure calculations based on the new pyrolysis model revealed that high pressure is generated inside the biomass particle during pyrolysis and sample splitting was observed during the experiments. The splitting is due to both weakening of the structure and internal pressure generation during pyrolysis. At low heating rates
Mass transfer of large molecules through collagen and collagen-silica hybrid membranes
NASA Astrophysics Data System (ADS)
Jofre-Lora, Pedro
Diabetes is a growing concern in the United States and around the world that must be addressed through new treatment options. Current standard treatment options of diabetes are limiting and have tremendous impacts on patient's lives. Emerging therapies, such as the implantation of encapsulated islets, are promising treatment options, but have not yet materialized due to unsolved problems with material properties. Hybrid silica-collagen membranes address some of these unsolved problems and are a promising material for cell encapsulation. However, the mass transfer properties of large molecules, such as insulin, TNF-alpha, IL1beta, and other important proteins in the etiology of diabetes, through these hybrid membranes are poorly characterized. In order to begin characterizing these properties, a device was constructed to accurately and efficiently measure the mass transfer of other similar large molecules, fluorescein isothiocyanate dextrans (FITC-dextran), through collagen-silica hybrid membranes. The device was used to measure diffusion coefficients of 4, 20, 40, and 150 kDa FITC-dextrans through non-silicified and silicified samples of 200 and 1000 Pa porcine skin collagen. Diffusion coefficients were found to be in the 10-7-10-6 cm2s -1 range, which is in agreement with previously published data for similar molecules through similar hydrogels. The effects of collagen stiffness, FITC-dextran molecular weight, and silicification treatment on diffusion were investigated. It was found that collagen stiffness and FITC-dextran molecular weight had a negative correlation with diffusion, whereas silicification treatment had no global impact on diffusion. The device created, and the results of this preliminary investigation, can be used to develop collagen-silica hybrid membranes as an alternative material for cell encapsulation in a forward-design manner.
Effective Mass of an Oscillating Spring
ERIC Educational Resources Information Center
Rodriguez, Eduardo E.; Gesnouin, Gabriel A.
2007-01-01
We present an experimental method to obtain the effective mass of an unloaded oscillating spring. We measure the period "T"("n") of the partial springs that result when hanging "n" of the total "N" coils of a given spring. Data are correlated with the expectation of a simple model for "T"("n") that takes into account the effective mass of the…
Rauf, A. Meraj, M. A.; Ashraf, M.; Batool, K.; Hussain, M.
2015-07-15
This article studies the simultaneous impacts of heat and mass transfer of an incompressible electrically conducting micropolar fluid generated by the stretchable disk in presence of porous medium. The thermal radiation effect is accounted via Rosseland’s approximation. The governing boundary layer equations are reduced into dimensionless form by employing the suitable similarity transformations. A finite difference base algorithm is utilized to obtain the solution expressions. The impacts of physical parameters on dimensionless axial velocity, radial velocity, micro-rotation, temperature and concentrations profiles are presented and examined carefully. Numerical computation is performed to compute shear stress, couple stress, heat and mass rate at the disk.
NASA Astrophysics Data System (ADS)
Rauf, A.; Ashraf, M.; Batool, K.; Hussain, M.; Meraj, M. A.
2015-07-01
This article studies the simultaneous impacts of heat and mass transfer of an incompressible electrically conducting micropolar fluid generated by the stretchable disk in presence of porous medium. The thermal radiation effect is accounted via Rosseland's approximation. The governing boundary layer equations are reduced into dimensionless form by employing the suitable similarity transformations. A finite difference base algorithm is utilized to obtain the solution expressions. The impacts of physical parameters on dimensionless axial velocity, radial velocity, micro-rotation, temperature and concentrations profiles are presented and examined carefully. Numerical computation is performed to compute shear stress, couple stress, heat and mass rate at the disk.
Xiu, G H; Jiang, L; Li, P
2001-07-01
A mathematical model has been developed for immobilized enzyme-catalyzed kinetic resolution of racemate in a fixed-bed reactor in which the enzyme-catalyzed reaction (the irreversible uni-uni competitive Michaelis-Menten kinetics is chosen as an example) was coupled with intraparticle diffusion, external mass transfer, and axial dispersion. The effects of mass-transfer limitations, competitive inhibition of substrates, deactivation on the enzyme effective enantioselectivity, and the optical purity and yield of the desired product are examined quantitatively over a wide range of parameters using the orthogonal collocation method. For a first-order reaction, an analytical solution is derived from the mathematical model for slab-, cylindrical-, and spherical-enzyme supports. Based on the analytical solution for the steady-state resolution process, a new concise formulation is presented to predict quantitatively the mass-transfer limitations on enzyme effective enantioselectivity and optical purity and yield of the desired product for a continuous steady-state kinetic resolution process in a fixed-bed reactor. PMID:11353408
NASA Technical Reports Server (NTRS)
Curry, D. M.; Cox, J. E.
1972-01-01
Coupled nonlinear partial differential equations describing heat and mass transfer in a porous matrix are solved in finite difference form with the aid of a new iterative technique (the strongly implicit procedure). Example numerical results demonstrate the characteristics of heat and mass transport in a porous matrix such as a charring ablator. It is emphasized that multidimensional flow must be considered when predicting the thermal response of a porous material subjected to nonuniform boundary conditions.
On the stream-accretion disk interaction - Response to increased mass transfer rate
NASA Technical Reports Server (NTRS)
Dgani, Ruth; Livio, Mario; Soker, Noam
1989-01-01
The time-dependent interaction between the stream of mass from the inner Lagrangian point and the accretion disk, resulting from an increasing mass transfer rate is calculated. The calculation is fully three-dimensional, using a pseudoparticle description of the hydrodynamics. It is demonstrated that the results of such calculations, when combined with specific observations, have the potential of both determining essential parameters, such as the viscosity parameter alpha, and can distinguish between different models of dwarf nova eruptions.
What is the role of wind pumping on heat and mass transfer rates at the air-snow interface?
NASA Astrophysics Data System (ADS)
Helgason, W.; Pomeroy, J. W.
2010-12-01
Accurate prediction of the turbulent exchange of sensible heat and water vapour between the atmosphere and snowpack remains a challenging task under all but the most ideal conditions. Heat and mass transfer coefficients that recognize the unique properties of the snow surface are warranted. A particular area requiring improvement concerns the role of the porous nature of snow which provides a large surface area for heat and mass exchange with the atmosphere. Wind-pumping has long been considered as a viable mechanism for incorporating aerosols into snowpacks; however these processes are not considered in parameterization schemes for heat and mass transfer near the surface. This study attempts to determine the degree to which wind pumping can increase the rates of heat and mass transfer to snow, and to ascertain which structural properties of the snowpack are needed for inclusion in heat and mass transfer coefficients that reflect wind pumping processes. Based upon a review of recent geophysical and engineering literature where porous surfaces are exploited for their ability to augment heat and mass transfer rates, a technical analysis was conducted. Numerous conceptual mechanisms of wind pumping were considered: topographically-induced flow; barometric pressure changes; high frequency pressure fluctuations at the surface; and steady flow in the interfacial region. A sensitivity analysis was performed, subjecting each conceptual model to varying thermal and hydraulic conditions at the air-snow interface, as well as variable micro-structural properties of snow. It is shown that the rate of heat and mass exchange is most sensitive to the interfacial thermal conditions and factors controlling the energy balance of the uppermost snow grains. The effect upon the thermal regime of the snowpack was found to be most significant for mechanisms of wind pumping that result in shorter flow paths near the surface, rather than those caused by low frequency pressure changes. In
NASA Astrophysics Data System (ADS)
Nagel, Florian P.; Schildhauer, Tilman J.; Biollaz, Serge M. A.; Stucki, Samuel
The interaction between charge, heat and mass transfer occurring in SOFCs is investigated applying a finite-volume-based SOFC model. The strong interactions are the consequence of the high degree of integration of different processes (chemical/electrochemical reactions, diffusion, heat and mass transfer) within SOFCs. The understanding of these interactions is a key for the future development and application of SOFCs. The investigation was conducted by means of a sensitivity analysis for two different fuel gases, where one gas features a considerable amount of methane inducing steam reforming reactions as additional disturbance factor in the energy and mass balance system of SOFCs. In order to isolate the impact of the varied model parameters and the according changes in the interactions of charge, mass and heat transfer from side effects, the sensitivity analysis was conducted at constant fuel utilization. It was found that the impact of different fuel gases on the operational conditions of SOFCs dominates geometrical and material-induced phenomena. The power output was most affected by the fuel, followed by the values for the activation polarization activation energy that reflects the employed electrode catalysts activity.
Heat And Mass Transfer Analysis of a Film Evaporative MEMS Tunable Array
NASA Astrophysics Data System (ADS)
O'Neill, William J.
This thesis details the heat and mass transfer analysis of a MEMs microthruster designed to provide propulsive, attitude control and thermal control capabilities to a cubesat. This thruster is designed to function by retaining water as a propellant and applying resistive heating in order to increase the temperature of the liquid-vapor interface to either increase evaporation or induce boiling to regulate mass flow. The resulting vapor is then expanded out of a diverging nozzle to produce thrust. Because of the low operating pressure and small length scale of this thruster, unique forms of mass transfer analysis such as non-continuum gas flow were modeled using the Direct Simulation Monte Carlo method. Continuum fluid/thermal simulations using COMSOL Multiphysics have been applied to model heat and mass transfer in the solid and liquid portions of the thruster. The two methods were coupled through variables at the liquid-vapor interface and solved iteratively by the bisection method. The simulations presented in this thesis confirm the thermal valving concept. It is shown that when power is applied to the thruster there is a nearly linear increase in mass flow and thrust. Thus, mass flow can be regulated by regulating the applied power. This concept can also be used as a thermal control device for spacecraft.
On the performance of proton-transfer-reaction mass spectrometry for breath-relevant gas matrices
NASA Astrophysics Data System (ADS)
Beauchamp, J.; Herbig, J.; Dunkl, J.; Singer, W.; Hansel, A.
2013-12-01
The accuracy of quantitative volatile organic compound (VOC) detection by proton-transfer-reaction mass spectrometry (PTR-MS) is substantially enhanced if the instrument is calibrated. Although quantification of a compound is in principle possible by mathematical methods based on kinetic theory, the underlying picture can become complicated depending on the gas matrix, leading to error. A simple, reliable method to overcome this is to calibrate the instrument using standard gas mixtures containing VOCs at known concentrations, which enables the compound-dependent sensitivity of the instrument to be determined. A dynamic gas calibration unit was developed to generate variable but known quantities of selected standard compounds in a carrier gas of variable relative humidity (RH; up to 100% at 37 °C) and CO2 content (≤10%v) to reflect the changing conditions of a breath-gas sample matrix. Besides individual compound sensitivities, calibration also yields the limits of detection and quantification of the experimental method. Extensive calibrations of PTR-MS with several breath-relevant compounds were made at varying RH and CO2. Gas matrix effects of several compounds were negligible when appropriate mass-dependent transmission correction and normalization to the primary ions (m/z 21 and m/z 37) were applied. Two compounds are discussed in particular, namely acetaldehyde, which interferes with a CO2-related background, and formaldehyde, which shows a nonlinear dependence on sample gas humidity.
Mass and isotopic effects in the Li-Li+ collision
NASA Astrophysics Data System (ADS)
Bouledroua, Moncef; Bouchelaghem, Fouzia
2011-10-01
We suggest in this work to deal with the ion-atom collision. More precisely, the transport coefficients, the temperature-dependant mobilities, and the charge-transfer phenomena are examined quatum-mechanically. Also is examined the mass and isotopic effects and their behaviour with temperature. To do so, the interatomic potentials are constructed and then injected in the radial wave equation to determine the phase shifts.
NASA Astrophysics Data System (ADS)
Illangasekare, T. H.; Frippiat, C. C.; Zyvoloski, G. A.
2007-12-01
A significant body of knowledge exists on separates processes of thermal and mass transport in granular and fractured subsurface formations. However, the need to simulate these processes in a fully coupled way has become necessary to deal with problems associated with long-term-storage of nuclear waste, and the development of new technologies for subsurface remediation. Another emerging area for research is associated with the development of technologies for in situ extraction of underground resources. Numerical models that couple thermal and mass transport processes will play a crucial role in understanding the fundamental processes associated with these new technologies, as well as in making predictions on how complex subsurface systems are expected to behave. It is our hypothesis that heat transport will have a significant impact on distributions of solute concentration, through temperature-dependent dissolution and precipitation, and temperature-dependent rate-limited diffusive transfer of solutes in fractured or highly heterogeneous media. A number of issues related to the validity of existing numerical tools that capture these processes, and their application to field systems through up-scaling need to be investigated. With this overall goal in mind, in this preliminary study, we explore the effect of the variability of subsurface properties on heat and mass transport using simulations conducted using an existing multiphase model. The finite-element code FEHM (Finite-Element Heat and Mass transport code) used in this study was developed at Los Alamos National Laboratory. This code allows for the coupled simulation of flow, heat and mass transport, accounting for density effects and dissolution and/or precipitation reactions. Our analysis is based on two- and three-dimensional simulations using synthetic data sets. Heterogeneous facies distributions are generated according to Markov Chain transition probability models. A distributed source of constant
Analysis of coupled mass transfer and sol-gel reaction in a two-phase system
NASA Astrophysics Data System (ADS)
Castelijns, H. J.; Huinink, H. P.; Pel, L.; Zitha, P. L. J.
2006-07-01
The coupled mass transfer and chemical reactions of a gel-forming compound in a two-phase system were studied in detail. Tetra-methyl-ortho-silicate (TMOS) is often used as a precursor in sol-gel chemistry to produce silica gels in aqueous systems. TMOS can also be mixed with many hydrocarbons without chemical reaction, which allows for various applications in multiphase systems. In this study, TMOS was mixed with n-hexadecane and placed together with water in small cylinders. Upon contact of the mixture with the water, TMOS transfers completely to the aqueous phase where it forms a gel through a heterogeneous reaction. Nuclear magnetic resonance imaging and relaxation time measurements were employed to monitor the mass transfer of TMOS from the oleic to the aqueous phase. The longitudinal relaxation time (T1) was calibrated and used to determine the concentration of TMOS in n-hexadecane during the transfer. The mass transfer rate was obtained at various temperatures (25-45°C) and for several initial concentrations of TMOS. In the aqueous phase a sharp decrease in the transversal relaxation time (T2) is observed which is attributed to the gel reaction, in particular the formation of methanol in the initial stage. The minimum in T2 indicates the gelation point, and was found to be strongly dependent on temperature and concentration.
Radiative transfer effects in primordial hydrogen recombination
Ali-Haiemoud, Yacine; Hirata, Christopher M.; Grin, Daniel
2010-12-15
The calculation of a highly accurate cosmological recombination history has been the object of particular attention recently, as it constitutes the major theoretical uncertainty when predicting the angular power spectrum of cosmic microwave background anisotropies. Lyman transitions, in particular the Lyman-{alpha} line, have long been recognized as one of the bottlenecks of recombination, due to their very low escape probabilities. The Sobolev approximation does not describe radiative transfer in the vicinity of Lyman lines to a sufficient degree of accuracy, and several corrections have already been computed in other works. In this paper, we compute the impact of some radiative transfer effects that were previously ignored, or for which previous treatments were incomplete. First, the effect of Thomson scattering in the vicinity of the Lyman-{alpha} line is evaluated, using a full redistribution kernel incorporated into a radiative transfer code. The effect of feedback of distortions generated by the optically thick deuterium Lyman-{alpha} line blueward of the hydrogen line is investigated with an analytic approximation. It is shown that both effects are negligible during cosmological hydrogen recombination. Second, the importance of high-lying, nonoverlapping Lyman transitions is assessed. It is shown that escape from lines above Ly{gamma} and frequency diffusion in Ly{beta} and higher lines can be neglected without loss of accuracy. Third, a formalism generalizing the Sobolev approximation is developed to account for the overlap of the high-lying Lyman lines, which is shown to lead to negligible changes to the recombination history. Finally, the possibility of a cosmological hydrogen recombination maser is investigated. It is shown that there is no such maser in the purely radiative treatment presented here.
NASA Astrophysics Data System (ADS)
Nait Alla, Abderrahman; Feddaoui, M'barek; Meftah, Hicham
2015-12-01
The interactive effects of heat and mass transfer in the evaporation of ethylene and propylene glycol flowing as falling films on vertical channel was investigated. The liquid film falls along a left plate which is externally subjected to a uniform heat flux while the right plate is the dry wall and is kept thermally insulated. The model solves the coupled governing equations in both phases together with the boundary and interfacial conditions. The systems of equations obtained by using an implicit finite difference method are solved by Tridiagonal Matrix Algorithm. The influence of the inlet liquid flow, Reynolds number in the gas flow and the wall heat flux on the intensity of heat and mass transfers are examined. A comparison between the results obtained for studied glycols and water in the same conditions is made. The results indicate that water evaporates in more intense way in comparison to glycols and the increase of gas flow rate tends to improve slightly the evaporation.
NASA Astrophysics Data System (ADS)
Diaz, Gerardo
2010-12-01
Liquid desiccant systems have received significant attention as a way to reduce latent loads. Tests of liquid desiccant systems in humid climates have shown significant reductions in energy consumption. As moisture in the air is absorbed at the dehumidifier, the temperature of the liquid desiccant increases due to the addition of heat from the enthalpy of condensation of the water vapor. Thus, the coupled effects of heat and mass transfer are relevant for these applications. A two-dimensional mathematical model of the transient heat and mass transfer for an absorber where a thin film of liquid desiccant flows down its walls and dehumidifies the air in parallel-flow configuration is developed and the dynamics of the modeled system are analyzed.
Ali, Kashif; Iqbal, Muhammad Farooq; Ashraf, Muhammad; Akbar, Muhammad Zubair
2014-10-15
The paper deals with the study of heat and mass transfer in an unsteady viscous incompressible water-based nanofluid (containing Titanium dioxide nanoparticles) between two orthogonally moving porous coaxial disks with suction. A combination of iterative (successive over relaxation) and a direct method is employed for solving the sparse systems of linear algebraic equations arising from the FD discretization of the linearized self similar ODEs. It has been noticed that the rate of mass transfer at the disks decreases with the permeability Reynolds number whether the disks are approaching or receding. The findings of the present investigation may be beneficial for the electronic industry in maintaining the electronic components under effective and safe operational conditions.
Mass Transfer Study of Chlorine Dioxide Gas Through Polymeric Packaging Materials
Technology Transfer Automated Retrieval System (TEKTRAN)
A continuous system for measuring the mass transfer of gaseous chlorine dioxide (ClO2), a strong oxidizing agent and used in food and pharmaceutical packaging, through 10 different types of polymeric packaging material was developed utilizing electrochemical sensor as a detector. Permeability, diff...
A mass transfer model of ethanol emission from thin layers of corn silage
Technology Transfer Automated Retrieval System (TEKTRAN)
A mass transfer model of ethanol emission from thin layers of corn silage was developed and validated. The model was developed based on data from wind tunnel experiments conducted at different temperatures and air velocities. Multiple regression analysis was used to derive an equation that related t...
A Laboratory Experiment for Measuring Solid-Liquid Mass Transfer Parameters
ERIC Educational Resources Information Center
Dapia, Sonia; Vila, Carlos; Dominguez, Herminia; Parajo, Juan Carlos
2004-01-01
The lab experiment described starts from the principles developed by Sensel and Myers, but the experimental procedure are modified to provide a more reliable experiment assessment. The mass transfer equation is solved and all the involved parameters are calculated by a simple, numerical method.
Dissociation and ammonia mass transfer from ammonium solution and dairy cattle manure
Technology Transfer Automated Retrieval System (TEKTRAN)
Process-based models are being used to predict ammonia (NH**3) emissions from manure sources, but their accuracy has not been fully evaluated for cattle manure. Laboratory trials were conducted to measure the dissociation and mass transfer coefficient for NH**3 volatilization from media of buffered ...
Mass transfer coefficient in ginger oil extraction by microwave hydrotropic solution
NASA Astrophysics Data System (ADS)
Handayani, Dwi; Ikhsan, Diyono; Yulianto, Mohamad Endy; Dwisukma, Mandy Ayulia
2015-12-01
This research aims to obtain mass transfer coefficient data on the extraction of ginger oil using microwave hydrotropic solvent as an alternative to increase zingiberene. The innovation of this study is extraction with microwave heater and hydrotropic solvent,which able to shift the phase equilibrium, and the increasing rate of the extraction process and to improve the content of ginger oil zingiberene. The experiment was conducted at the Laboratory of Separation Techniques at Chemical Engineering Department of Diponegoro University. The research activities carried out in two stages, namely experimental and modeling work. Preparation of the model postulated, then lowered to obtain equations that were tested and validated using data obtained from experimental. Measurement of experimental data was performed using microwave power (300 W), extraction temperature of 90 ° C and the independent variable, i.e.: type of hydrotropic, the volume of solvent and concentration in order, to obtain zingiberen levels as a function of time. Measured data was used as a tool to validate the postulation, in order to obtain validation of models and empirical equations. The results showed that the mass transfer coefficient (Kla) on zingiberene mass transfer models ginger oil extraction at various hydrotropic solution attained more 14 ± 2 Kla value than its reported on the extraction with electric heating. The larger value of Kla, the faster rate of mass transfer on the extraction process. To obtain the same yields, the microwave-assisted extraction required one twelfth time shorter.
Numerical Problems and Agent-Based Models for a Mass Transfer Course
ERIC Educational Resources Information Center
Murthi, Manohar; Shea, Lonnie D.; Snurr, Randall Q.
2009-01-01
Problems requiring numerical solutions of differential equations or the use of agent-based modeling are presented for use in a course on mass transfer. These problems were solved using the popular technical computing language MATLABTM. Students were introduced to MATLAB via a problem with an analytical solution. A more complex problem to which no…
Technology Transfer Automated Retrieval System (TEKTRAN)
An empirical correlation of volumetric mass transfer coefficient was developed for a pilot scale internal-loop rectangular airlift bioreactor that was designed for biotechnology. The empirical correlation combines classic turbulence theory, Kolmogorov’s isotropic turbulence theory with Higbie’s pen...
Mayer, A.S.; Zhong, L.; Pope, G.A.
1999-09-01
Surfactant-enhanced solubilization of residual, non-aqueous-phase liquid (NAPL) contaminants is an emerging, subsurface remediation technology. The potential for nonequilibrium conditions is investigated for surfactant-enhanced solubilization of a NAPL, trichlorethylene (TCE), in a model porous medium. The surfactant formulation consists of an anionic surfactant, sodium dihexyl sulfosuccinate, an alcohol, and an electrolyte in aqueous solution. Batch solubilization experiments are conducted to assess the significant of chemical rate limitations. Surfactant flood experiments are conducted in packed columns with residual TCE. Mass-transfer rate coefficients are determined as a function of aqueous-phase pore velocity, NAPL volumetric fraction, and surfactant concentration. A correlation for predicting mass-transfer rate coefficients as a function of system properties is developed. The mass-transfer rate coefficients and correlation are obtained by fitting a transport simulator to the column effluent concentration results. Significant differences are found between the correlation developed here and correlations developed for other NAPL--surfactant systems. The correlation predicts near-linear dependences of mass-transfer rates on the NAPL volumetric fraction and pore velocity. Using the Damkohler number, the degree of nonequilibrium behavior in surfactant-enhanced NAPL solubilization is analyzed for a range of conditions. Nonequilibrium conditions are found to be significant at relatively low NAPL volumetric fractions.
MASS TRANSFER IN BINARY STARS USING SMOOTHED PARTICLE HYDRODYNAMICS. II. ECCENTRIC BINARIES
Lajoie, Charles-Philippe; Sills, Alison E-mail: asills@mcmaster.ca
2011-01-10
Despite numerous efforts to better understand binary star evolution, some aspects of it remain poorly constrained. In particular, the evolution of eccentric binaries has remained elusive mainly because the Roche lobe formalism derived for circular binaries does not apply. Here we report the results of our smoothed particle hydrodynamic simulations of mass transfer in eccentric binaries using an alternate method in which we model only the outermost layers of the stars with appropriate boundary conditions. Using this technique, along with properly relaxed model stars, we characterize the mass transfer episodes of binaries with various orbital parameters. In particular, we show that these episodes can be described by Gaussians with an FWHM of {approx}0.12P{sub orb} and that the peak rates occur after periastron, at an orbital phase of {approx}0.58, independently of the eccentricity and mass of the stars. The accreted material is observed to form a rather sparse envelope around either or both stars. Although the fate of this envelope is not modeled in our simulations, we show that a constant fraction ({approx}5%) of the material transferred is ejected from the systems. We discuss this result in terms of the non-conservative mass transfer scenario. We suggest that our results could be incorporated in analytical and binary population synthesis studies to help better understand the evolution of eccentric binaries and the formation of exotic stellar populations.
Patel, Sajal M; Pikal, Michael J
2010-07-01
This study is aimed at characterizing and understanding different modes of heat and mass transfer in glass syringes to develop a robust freeze-drying process. Two different holder systems were used to freeze-dry in syringes: an aluminum (Al) block and a plexiglass holder. The syringe heat transfer coefficient was characterized by a sublimation test using pure water. Mannitol and sucrose (5% w/v) were also freeze-dried, as model systems, in both the assemblies. Dry layer resistance was determined from manometric temperature measurement (MTM) and product temperature was measured using thermocouples, and was also determined from MTM. Further, freeze-drying process was also designed using Smart freeze-dryer to assess its application for freeze-drying in novel container systems. Heat and mass transfer in syringes were compared against the traditional container system (i.e., glass tubing vial). In the Al block, the heat transfer was via three modes: contact conduction, gas conduction, and radiation with gas conduction being the dominant mode of heat transfer. In the plexiglass holder, the heat transfer was mostly via radiation; convection was not involved. Also, MTM/Smart freeze-drying did work reasonably well for freeze-drying in syringes. When compared to tubing vials, product temperature decreases and hence drying time increases in syringes. PMID:20166199
NASA Astrophysics Data System (ADS)
Briggs, M. A.; Day-Lewis, F. D.; Ong, J. B.; Lane, J. W.; Curtis, G. P.
2012-12-01
In the presence of rate-limited mass transfer (RLMT), conventional chemical sampling of the subsurface preferentially pulls pore water from the mobile domain. Therefore, the characteristics of the immobile domain must be inferred from the mobile tracer signal, which is modified with transport and immobile exchange over a representative length. Because conventional chemical data are not directly sensitive to the immobile zone, this representative length must be sufficient to allow enough exchange between the two domains to inform immobile parameter estimation (e.g., optimal Damkohler range). Flowpath "averaged" RLMT parameters may not well describe the true field variability in the immobile domain size and exchange coefficient, parameters which control the retention and subsequent long-term release of contaminants. In contrast, bulk electrical conductivity is sensitive to the volume-weighted ionic tracer concentration in both the mobile and immobile domains. When co-located bulk conductivity and fluid conductivity are analyzed concurrently, estimates can be obtained for (1) effective RLMT parameters averaged along the upgradient flowpath and (2) local-scale RLMT parameters for the volume from which chemical samples and electrical measurements are taken. Here, we use electrical resistivity tomography (ERT), for the first time, to discriminate and identify effective flowpath and local-scale RLMT parameters, informing the true spatial variability in mass transfer. We apply this technique at the field scale at a uranium contamination site in Naturita, Colorado, USA. Inverse modeling was used to optimize parameter estimates to best simulate both the observed bulk and fluid conductivity, and objectively determine parameter sensitivity, correlation, and confidence. Local RLMT parameters were found to be most sensitive to changes in bulk conductivity, while effective flowpath parameters were most sensitive to changes in fluid conductivity. Observed non-linear hysteresis
Experimental study of surfactant effects on pool boiling heat transfer
Ying Liang Tzan; Yu Min Yang )
1990-02-01
In the first part of this work, nucleate boiling of aqueous solutions of sodium lauryl sulfate (SLS) over relatively wide ranges of concentration and heat flux was carried out in a pool boiling apparatus. The experimental results show that a small amount of surface active additive makes the nucleate boiling heat transfer coefficient h considerably higher, and that there is an optimum additive concentration for higher heat fluxes. Beyond this optimum point, further increase in additive concentration makes h lower. In the second part of this work, nucleate boiling heat transfer rate for n-propanol-water binary mixtures with various amounts of sodium lauryl sulfate were measured in the same pool boiling apparatus. The importance of the mass diffusion effect, which is caused by preferential evaporation of the more volatile component at the vapor-liquid interface on the boiling of the binary mixture, has been confirmed. However, it is shown that the effect exerted by the addition of a surfactant dominates over the mass diffusion effect in dilute binary mixtures.
NASA Astrophysics Data System (ADS)
Aroudam, El. H.
In this paper, we present a modelling of the performance of a reactor of a solar cooling machine based carbon-ammonia activated bed. Hence, for a solar radiation, measured in the Energetic Laboratory of the Faculty of Sciences in Tetouan (northern Morocco), the proposed model computes the temperature distribution, the pressure and the ammonia concentration within the activated carbon bed. The Dubinin-Radushkevich formula is used to compute the ammonia concentration distribution and the daily cycled mass necessary to produce a cooling effect for an ideal machine. The reactor is heated at a maximum temperature during the day and cool at the night. A numerical simulation is carried out employing the recorded solar radiation data measured locally and the daily ambient temperature for the typical clear days. Initially the reactor is at ambient temperature, evaporating pressure; Pev=Pst(Tev=0 ∘C) and maintained at uniform concentration. It is heated successively until the threshold temperature corresponding to the condensing pressure; Pcond=Pst(Tam) (saturation pressure at ambient temperature; in the condenser) and until a maximum temperature at a constant pressure; Pcond. The cooling of the reactor is characterised by a fall of temperature to the minimal values at night corresponding to the end of a daily cycle. We use the mass balance equations as well as energy equation to describe heat and mass transfer inside the medium of three phases. A numerical solution of the obtained non linear equations system based on the implicit finite difference method allows to know all parameters characteristic of the thermodynamic cycle and consider principally the daily evolution of temperature, ammonia concentration for divers positions inside the reactor. The tube diameter of the reactor shows the dependence of the optimum value on meteorological parameters for 1 m2 of collector surface.
Hussain, Amir; Kangwa, Martin; Yumnam, Nivedita; Fernandez-Lahore, Marcelo
2015-12-01
The influence of internal mass transfer on productivity as well as the performance of packed bed bioreactor was determined by varying a number of parameters; chitosan coating, flow rate, glucose concentration and particle size. Saccharomyces cerevisiae cells were immobilized in chitosan and non-chitosan coated alginate beads to demonstrate the effect on particle side mass transfer on substrate consumption time, lag phase and ethanol production. The results indicate that chitosan coating, beads size, glucose concentration and flow rate have a significant effect on lag phase duration. The duration of lag phase for different size of beads (0.8, 2 and 4 mm) decreases by increasing flow rate and by decreasing the size of beads. Moreover, longer lag phase were found at higher glucose medium concentration and also with chitosan coated beads. It was observed that by increasing flow rates; lag phase and glucose consumption time decreased. The reason is due to the reduction of external (fluid side) mass transfer as a result of increase in flow rate as glucose is easily transported to the surface of the beads. Varying the size of beads is an additional factor: as it reduces the internal (particle side) mass transfer by reducing the size of beads. The reason behind this is the distance for reactants to reach active site of catalyst (cells) and the thickness of fluid created layer around alginate beads is reduced. The optimum combination of parameters consisting of smaller beads size (0.8 mm), higher flow rate of 90 ml/min and glucose concentration of 10 g/l were found to be the maximum condition for ethanol production. PMID:26272478
Mass transfer and hydrocarbon biodegradation of aged soil in slurry phase.
García-Rivero, M; Saucedo-Castañeda, G; Flores De Hoyos, S; Gutiérrez-Rojas, M
2002-01-01
Addition of toluene into slurry phase laboratory microcosm is proposed in order to increase desorption rate of hydrocarbons and as an alternative to improve bioavailability of hydrocarbon in aged soils. Our studies showed that toluene has a positive effect on desorption of total petroleum hydrocarbons (TPH). Addition of 14,000 mg toluene/kg of soil, in highly polluted soil, increased the consumption rate of hydrocarbons three times in comparison to control without solvent. In 30 days the initial TPH concentration in soil, 292,000 mg/kg, diminished 45%. Although toluene was able to dissolve complex organic compounds such as asphaltene fraction, it probably yielded a highly toxic toluene-hydrocarbons phase. The inhibitory effect of toluene-TPH was also studied. A substrate inhibition model was used: the k(m) and k(i) constants were 57 and 490 mg TPH/L liquid phase, respectively. Experimental data were well described when the proposed model included sequential desorption and biodegradation phenomena. Damköhler number evaluation showed that rate of mass transfer was the limiting step in overall biodegradation in nonsolvent control. When high concentration of toluene was added, then bioreaction was the limiting step, but inhibitory effect should be considered. However, toluene addition at low concentrations facilitates the biodegradation of aromatic compounds. PMID:12153305
Exploring Differential Effects of Supervisor Support on Transfer of Training
ERIC Educational Resources Information Center
Nijman, Derk-Jan J. M.; Nijhof, Wim J.; Wognum, A. A. M.; Veldkamp, Bernard P.
2006-01-01
Purpose: The purpose of this article is to provide further insight into the relationship between supervisor support and transfer of training, by taking into account the effects of other transfer-influencing factors in a systemic approach of the transfer process. Design/methodology/approach: A review of studies on factors affecting transfer of…
Bibliography on augmentation of convective heat and mass transfer-II
Bergles, A.E.; Nirmalan, V.; Junkhan, G.H.; Webb, R.L.
1983-12-01
Heat transfer augmentation has developed into a major specialty area in heat transfer research and development. This report presents and updated bibliography of world literature on augmentation. The literature is classified into passive augmentation techniques, which require no external power, and active techniques, which do require external power. The fifteen techniques are grouped in terms of their applications to the various modes of heat transfer. Mass transfer is included for completeness. Key words are included with each citation for technique/mode identification. The total number of publications cited is 3045, including 135 surveys of various techniques and 86 papers on performance evaluation of passive techniques. Patents are not included, as they are the subject of a separate bibliographic report.
NASA Astrophysics Data System (ADS)
Vandadi, Vahid; Jafari Kang, Saeed; Masoud, Hassan
2016-06-01
In the study of convective heat and mass transfer from a particle, key quantities of interest are usually the average rate of transfer and the mean distribution of the scalar (i.e., temperature or concentration) at the particle surface. Calculating these quantities using conventional equations requires detailed knowledge of the scalar field, which is available predominantly for problems involving uniform scalar and flux boundary conditions. Here we derive a reciprocal relation between two diffusing scalars that are advected by oppositely driven Stokes or potential flows whose streamline configurations are identical. This relation leads to alternative expressions for the aforementioned average quantities based on the solution of the scalar field for uniform surface conditions. We exemplify our results via two applications: (i) heat transfer from a sphere with nonuniform boundary conditions in Stokes flow at small Péclet numbers and (ii) extension of Brenner's theorem for the invariance of heat transfer rate to flow reversal.
Numerical study on heat and mass transfer in hygroscopic rotor during sorption process
NASA Astrophysics Data System (ADS)
Shin, Hyun-Geun; Park, Il Seouk
2016-06-01
Recently, interest in hygroscopic dehumidifiers has rapidly increased in the indoor environment industry because of their potential contribution to the development of hybrid (refrigerating + hygroscopic) dehumidifiers. Heat and mass transport phenomena such as adsorption and desorption, and their complex interactions occur in a desiccant rotor, which comprises many small hygroscopic channels. This study numerically investigated the conjugated heat and mass transfers in a channel modeled with the flow and porous desiccant regions, where only ordinary and surface diffusions (excluding Knudsen diffusion) during the sorption processes were considered. The change in the dehumidification performance depending on operating conditions such as the rotor's rotating speed, air flow rate, and adsorption-desorption ratio, was examined under various working environments. The temporal and spatial variations in the temperature, vapor mass fraction, and liquid water mass fraction in the channel were considered in detail. The closely linked heat and mass transports were clarified for a better understanding of the sorption processes in the desiccant rotor.
Effects of the Mass Media of Communication.
ERIC Educational Resources Information Center
Weiss, Walter
The mass media are considered to be television, radio, movies, and newspapers. They may generate changes in cognition and comprehension. They do effect emotional arousal, sex and behavior identification, and changes in allocation of time, consumer purchase, and voting behavior. The only data which show a clear relationship between the mass media…
Is effective mass in combat sports punching above its weight?
Lenetsky, Seth; Nates, Roy J; Brughelli, Matt; Harris, Nigel K
2015-04-01
The segmental and muscular complexity of the human body can result in challenges when examining the kinetics of impacts. To better understand this complexity, combat sports literature has selected effective mass as a measure of an athlete's inertial contribution to the momentum transfer during the impact of strikes. This measure helps to clarify the analysis of striking kinetics in combat sports. This paper will review: (1) effective mass as a concept and its usage as a measure of impact intensity in combat sports, (2) the neuromuscular pattern known as "double peak muscle activation" which has been theorized to help enhance initial hand velocity upon impact and joint stiffening during impact, (3) the methods and equations used to calculate effective mass, and (4) practitioner recommendations based on the literature. We will argue in this manuscript that the act of punching presents unique challenges to the current understanding of effective mass due to additional force application during impact. This review will improve the understanding of effective mass and its roles in effective striking serving to underpin future research into performance enhancement in striking based combat sports. PMID:25544341
Martens, Jonathan; Berden, Giel; Oomens, Jos
2016-06-21
Ion/ion reactions have in recent years seen widespread use in ion activation methods such as electron transfer dissociation (ETD) tandem mass spectrometry (MS/MS) as well as in charge manipulation of highly charged peptides/proteins and their fragments by proton transfer reaction (PTR). These techniques have, in combination, enabled top-down proteomics on limited-resolution benchtop mass spectrometry platforms such as quadrupole ion traps. Anions generated by chemical ionization of fluoranthene are often used for both ETD and PTR reactions; the radical anion of fluoranthene (m/z 202) for ETD and the closed-shell anion resulting from H atom attachment to the radical anion (m/z 203) for PTR. Here we use infrared ion spectroscopy in combination with density functional theory calculations to identify the structures of these reagent anions. We establish that the m/z 203 PTR reagent anion possesses a structure that deviates from what has been suggested previously and provides some insight into the reaction mechanism involved in PTR. PMID:27228406
Characterization of gas-liquid mass transfer phenomena in microtiter plates.
Hermann, Robert; Lehmann, Mathias; Büchs, Jochen
2003-01-20
Gas-liquid mass transfer properties of shaken 96-well microtiter plates were characterized using a recently described method. The maximum oxygen transfer capacity (OTR(max)), the specific mass transfer area (a), and the mass transfer coefficient (k(L)) in a single well were determined at different shaking intensities (different shaking frequencies and shaking diameters at constant filling volume) and different filling volumes by means of sulfite oxidation as a chemical model system. The shape (round and square cross-sections) and the size (up to 2 mL maximum filling volume) of a microtiter plate well were also considered as influencing parameters. To get an indication of the hydrodynamic behavior of the liquid phase in a well, images were taken during shaking and the liquid height derived as a characteristic parameter. The investigations revealed that the OTR(max) is predominantly dependent on the specific mass transfer area (a) for the considered conditions in round-shaped wells. The mass transfer coefficient (k(L)) in round-shaped wells remains at a nearly constant value of about 0.2 m/h for all shaking intensities, thus within the range reported in the literature for surface-aerated bioreactors. The OTR(max) in round-shaped wells is strongly influenced by the interfacial tension, determined by the surface tension of the medium used and the surface properties of the well material. Up to a specific shaking intensity the liquid surface in the wells remains horizontal and no liquid movement can be observed. This critical shaking intensity must be exceeded to overcome the surface tension and, thus, to increase the liquid height and enlarge the specific mass transfer area. This behavior is solely specific to microtiter plates and has not yet been observed for larger shaking bioreactors such as shaking flasks. In square-shaped microtiter plate wells the corners act as baffles and cause a significant increase of OTR(max), a, and k(L). An OTR(max) of up to 0.15 mol
Modelling heat and mass transfer in a membrane-based air-to-air enthalpy exchanger
NASA Astrophysics Data System (ADS)
Dugaria, S.; Moro, L.; Del, D., Col
2015-11-01
The diffusion of total energy recovery systems could lead to a significant reduction in the energy demand for building air-conditioning. With these devices, sensible heat and humidity can be recovered in winter from the exhaust airstream, while, in summer, the incoming air stream can be cooled and dehumidified by transferring the excess heat and moisture to the exhaust air stream. Membrane based enthalpy exchangers are composed by different channels separated by semi-permeable membranes. The membrane allows moisture transfer under vapour pressure difference, or water concentration difference, between the two sides and, at the same time, it is ideally impermeable to air and other contaminants present in exhaust air. Heat transfer between the airstreams occurs through the membrane due to the temperature gradient. The aim of this work is to develop a detailed model of the coupled heat and mass transfer mechanisms through the membrane between the two airstreams. After a review of the most relevant models published in the scientific literature, the governing equations are presented and some simplifying assumptions are analysed and discussed. As a result, a steady-state, two-dimensional finite difference numerical model is setup. The developed model is able to predict temperature and humidity evolution inside the channels. Sensible and latent heat transfer rate, as well as moisture transfer rate, are determined. A sensitive analysis is conducted in order to determine the more influential parameters on the thermal and vapour transfer.
Mass transfer during osmotic dehydration of celery stalks in a batch osmo-reactor
NASA Astrophysics Data System (ADS)
Sareban, M.; Abbasi Souraki, B.
2016-07-01
In this study, dehydration behavior of bulk of celery stalks, during osmotic drying in a limited volume of salt solution, was investigated. Experiments were carried out in the three initial solution concentrations of 10, 18 and 25 % (w/w) and at the three temperatures of 35, 45 and 55 °C. The volume ratio of the fruit to the solution was considered 1:3. A two-parameter model was used for prediction of kinetics of mass transfer and values of equilibrium moisture loss and solid gain. Moisture and salt effective diffusivities in celery stalks were estimated by fitting the experimental data of moisture loss and solute gain to the analytical solution of Fick's second law of diffusion. The analytical model was solved by defining a partition factor, K, assuming that the concentration of solute just within the surface of the material is K times that in the solution. Results showed that moisture and salt effective diffusivities and equilibrium values of moisture loss and solute gain increased with increasing the temperature and solution concentration. Results showed a good agreement between the two parameter model (with mean relative error of 4.016 % for moisture loss and 5.977 % for solid gain), analytical solution of Fick's second law (with mean relative error of 8.924 % for moisture loss and 9.164 % for solid gain) and experimental data.
NASA Astrophysics Data System (ADS)
Aprea, Eugenio; Biasioli, Franco; Carlin, Silvia; Märk, Tilmann D.; Gasperi, Flavia
2008-08-01
The presence of benzene in food and in particular in soft drinks has been reported in several studies and should be considered in fundamental investigations about formation of this carcinogen compound as well as in quality control. Proton transfer reaction-mass spectrometry (PTR-MS) has been used here for rapid, direct quantification of benzene and to monitor its formation in model systems related to the use of benzoate, a common preservative, in presence of ascorbic acid: a widespread situation that yields benzene in, e.g., soft drinks and fruit juices. Firstly, we demonstrate here that PTR-MS allows a rapid determination of benzene that is in quantitative agreement with independent solid phase micro-extraction/gas chromatography (SPME/GC) analysis. Secondly, as a case study, the effect of different sugars (sucrose, fructose and glucose) on benzene formation is investigated indicating that they inhibit its formation and that this effect is enhanced for reducing sugars. The sugar-induced inhibition of benzene formation depends on several parameters (type and concentration of sugar, temperature, time) but can be more than 80% in situations that can be expected in the storage of commercial soft drinks. This is consistent with the reported observations of higher benzene concentrations in sugar-free soft drinks.
Buffiere, P.; Steyer, J.P.; Moletta, R.; Fonade, C.
1995-12-20
Anaerobic digestion--a process where organic matter is degraded into a gas mixture of methane and carbon dioxide--is particularly adapted for food industry wastewater treatment because it reduces the chemical oxygen demand (COD) of the influent and produces valuable energy (methane). A cognitive model for anaerobic digestion in fluidized bed reactors is developed. The general pathway of the process is divided into five main reactions performed by different bacterial groups. Molecular diffusion of each substrate involved in the reaction scheme is described. Effectiveness factor calculations are performed in steady state for each bacterial group taken into account in the process. The case of a single substrate removal is discussed, and optimal biofilm sizes are found. Sequential substrate removal is investigated, and different kinetic regimes are characterized. The influence of biofilm size and primary substrate removal is discussed in the case of standard concentrations in the liquid phase. This study shows that, according to the theoretical model the limiting step of the process may be different and depends in a large way on mass transfer effects. Finally, importance of biofilm size is compared for acidogenic and methanogenic steps: each reaction is found to be optimized for different biofilm thicknesses. This result may be of interest for design purposes and further dynamic modeling. Concluding remarks concerning the validation of the model are made, and a comparison to experimental data from the literature is presented.
NASA Astrophysics Data System (ADS)
Tecklenburg, Jan; Neuweiler, Insa; Carrera, Jesus; Dentz, Marco
2016-05-01
We study modeling of two-phase flow in highly heterogeneous fractured and porous media. The flow behaviour is strongly influenced by mass transfer between a highly permeable (mobile) fracture domain and less permeable (immobile) matrix blocks. We quantify the effective two-phase flow behavior using a multirate rate mass transfer (MRMT) approach. We discuss the range of applicability of the MRMT approach in terms of the pertinent viscous and capillary diffusion time scales. We scrutinize the linearization of capillary diffusion in the immobile regions, which allows for the formulation of MRMT in the form of a non-local single equation model. The global memory function, which encodes mass transfer between the mobile and the immobile regions, is at the center of this method. We propose two methods to estimate the global memory function for a fracture network with given fracture and matrix geometry. Both employ a scaling approach based on the known local memory function for a given immobile region. With the first method, the local memory function is calculated numerically, while the second one employs a parametric memory function in form of truncated power-law. The developed concepts are applied and tested for fracture networks of different complexity. We find that both physically based parameter estimation methods for the global memory function provide predictive MRMT approaches for the description of multiphase flow in highly heterogeneous porous media.
de Godos, I; Mendoza, J L; Acién, F G; Molina, E; Banks, C J; Heaven, S; Rogalla, F
2014-02-01
Mass transfer of CO2 from flue gas was quantified in a 100m(2) raceway. The carbonation sump was operated with and without a baffle at different liquid/gas ratios, with the latter having the greatest influence on CO2 recovery from the flue gas. A rate of mass transfer sufficient to meet the demands of an actively growing algal culture was best achieved by maintaining pH at ∼8. Full optimisation of the process required both pH control and selection of the best liquid/gas flow ratio. A carbon transfer rate of 10gCmin(-1) supporting an algal productivity of 17gm(-2)day(-1) was achieved with only 4% direct loss of CO2 in the sump. 66% of the carbon was incorporated into biomass, while 6% was lost by outgassing and the remainder as dissolved carbon in the liquid phase. Use of a sump baffle required additional power without significantly improving carbon mass transfer. PMID:24374031
Upward and downward heat and mass transfer with miniature periodically operating loop thermosyphons
NASA Astrophysics Data System (ADS)
Fantozzi, Fabio; Filippeschi, Sauro; Latrofa, Enrico Maria
2004-03-01
Upward and downward two-phase heat and mass transfer has been considered in the present paper. The heat and mass transfer with the condenser located below the evaporator has been obtained by inserting an accumulator tank in the liquid line of a loop thermosyphon and enforcing a pressure pulsation. In previous papers these heat transfer devices have been called pulsated two phase thermosyphons (PTPT). A mini PTPT has been experimentally investigated. It has shown a stable periodic heat transfer regime weakly influenced by the position of the condenser with respect to the evaporator. In contrast a classical loop mini thermosyphon (diameter of connecting pipes 4 mm) did not achieve a stable functioning for the investigated level differences between evaporator and condenser lower than 0.37 m. The present study shows that the functioning of a PTPT device does not directly depend on the level difference or the presence of noncondensable gas. In order to obtain a natural circulation in mini or micro loops, a periodically operating heat transfer regime should therefore be considered.
The calculational modeling of impurity mass transfer in NPP circuits with liquid metal coolant
NASA Astrophysics Data System (ADS)
Alexeev, V.; Kozlov, F.; Kumaev, V.; Orlova, E.; Klimanova, Yu; Torbenkova, I.
2008-02-01
The authors create three levels of models (one-dimensional, two-dimensional and three-dimensional) for estimation of impurity mass transfer in sodium circuits units as well as applicable computational programs. In the one-dimensional model the flow path elements are simulated by annular channels. The Lagrange coordinate system is used in the mathematical description of processes in channels. The two-dimensional model is based on the porous body approximation and enables one to simulate global spatial distributions of coolant flow velocity fields, coolant and fuel rods temperatures, and concentration distribution of transferred substances. The mathematical description of passive multicomponent impurity transfer is carried out using the system of the differential equations with sources and impurity diffusion, written for each component. The equations are solved by the finite-difference method. The developed version of the three-dimensional code is based on a general approach of the spatial three-dimensional description of thermal-hydraulic and mass-transfer processes in fuel rod bundles. The determining system of finite-difference equations of hydrodynamics and heat exchange is obtained using the control volume approach. As a result of the performed calculations, valuable data on corrosion products transfer in the primary circuit of the BN-600 reactor are obtained.
Differential effects of adult court transfer on juvenile offender recidivism.
Loughran, Thomas A; Mulvey, Edward P; Schubert, Carol A; Chassin, Laurie A; Steinberg, Laurence; Piquero, Alex R; Fagan, Jeffrey; Cota-Robles, Sonia; Cauffman, Elizabeth; Losoya, Sandy
2010-12-01
Prior research indicates that adolescent offenders transferred to adult court are more likely to recidivate than those retained in the juvenile system. The studies supporting this conclusion, however, are limited in addressing the issue of heterogeneity among transferred adolescents. This study estimates the effect of transfer on later crime using a sample of 654 serious juvenile offenders, 29% of whom were transferred. We use propensity score matching to reduce potential selection bias, and we partition the sample on legal characteristics to examine subgroup effects. We find an overall null effect of transfer on re-arrest, but evidence of differential effects of transfer for adolescents with different offending histories. These results suggest that evaluating the effects of transfer for all transferred adolescents together may lead to misguided policy conclusions. PMID:20195895
Differential Effects of Adult Court Transfer on Juvenile Offender Recidivism
Loughran, Thomas A.; Schubert, Carol A.; Chassin, Laurie A.; Steinberg, Laurence; Piquero, Alex R.; Fagan, Jeffrey; Cota-Robles, Sonia; Cauffman, Elizabeth; Losoya, Sandy
2010-01-01
Prior research indicates that adolescent offenders transferred to adult court are more likely to recidivate than those retained in the juvenile system. The studies supporting this conclusion, however, are limited in addressing the issue of heterogeneity among transferred adolescents. This study estimates the effect of transfer on later crime using a sample of 654 serious juvenile offenders, 29% of whom were transferred. We use propensity score matching to reduce potential selection bias, and we partition the sample on legal characteristics to examine subgroup effects. We find an overall null effect of transfer on re-arrest, but evidence of differential effects of transfer for adolescents with different offending histories. These results suggest that evaluating the effects of transfer for all transferred adolescents together may lead to misguided policy conclusions. PMID:20195895
Mass transfer in electromembrane extraction--The link between theory and experiments.
Huang, Chuixiu; Jensen, Henrik; Seip, Knut Fredrik; Gjelstad, Astrid; Pedersen-Bjergaard, Stig
2016-01-01
Electromembrane extraction was introduced in 2006 as a totally new sample preparation concept for the extraction of charged analytes present in aqueous samples. Electromembrane extraction is based on electrokinetic migration of the analytes through a supported liquid membrane and into a μL-volume of acceptor solution under the influence of an external electrical field. To date, electromembrane extraction has mostly been used for the extraction of drug substances, amino acids, and peptides from biological fluids, and for organic micropollutants from environmental samples. Electromembrane extraction has typically been combined with chromatography, mass spectrometry, and electrophoresis for analyte separation and detection. At the moment, close to 125 research papers have been published with focus on electromembrane extraction. Electromembrane extraction is a hybrid technique between electrophoresis and liquid-liquid extraction, and the fundamental principles for mass transfer have only partly been investigated. Thus, although there is great interest in electromembrane extraction, the fundamental principle for mass transfer has to be described in more detail for the scientific acceptance of the concept. This review summarizes recent efforts to describe the fundamentals of mass transfer in electromembrane extraction, and aim to give an up-to-date understanding of the processes involved. PMID:26420509
Magnetohydrodynamic free convection and mass transfer flow in micropolar fluid with constant suction
NASA Astrophysics Data System (ADS)
El-Amin, M. F.
2001-09-01
An analysis is presented for the problem of free convection with mass transfer flow for a micropolar fluid bounded by a vertical infinite surface under the action of a transverse magnetic field. Approximate solutions of the coupled nonlinear governing equations are obtained for different values of the microrotation- and the magnetic-parameters. Numerical calculations are carried out for the various parameters entering into the problem. Velocity, angular velocity, temperature and concentration profiles are shown graphically. The numerical values of the skin friction, the wall couple stress, the rate of heat transfer and the concentration gradient at the wall are entered in tables.
Heat/Mass Transfer Coefficients of an Absorber in Absorption Refrigeration System
NASA Astrophysics Data System (ADS)
Fujita, Isamu; Hihara, Eiji
This paper presents a new method to calculate heat and mass transfer coefficients applicable to the vertical tube or plate type absorber of absorption refrigeration system. Conventional method for calculating the coefficients using logarithmic mean temperature/ concentration differences is criticized for its lacking in the theoretical rationality and usually giving untrue values except some limited situations such that temperature of the solution can be assumed to change linearly along the heat transfer surface. The newly introduced method, which is intended to overcome this difficulty, is verified by numerical simulation and is accompanied by an example applied to the experimental results.
Probing the hydrophobic effect of noncovalent complexes by mass spectrometry.
Bich, Claudia; Baer, Samuel; Jecklin, Matthias C; Zenobi, Renato
2010-02-01
The study of noncovalent interactions by mass spectrometry has become an active field of research in recent years. The role of the different noncovalent intermolecular forces is not yet fully understood since they tend to be modulated upon transfer into the gas phase. The hydrophobic effect, which plays a major role in protein folding, adhesion of lipid bilayers, etc., is absent in the gas phase. Here, noncovalent complexes with different types of interaction forces were investigated by mass spectrometry and compared with the complex present in solution. Creatine kinase (CK), glutathione S-transferase (GST), ribonuclease S (RNase S), and leucine zipper (LZ), which have dissociation constants in the nM range, were studied by native nanoelectrospray mass spectrometry (nanoESI-MS) and matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) combined with chemical cross-linking (XL). Complexes interacting with hydrogen bonds survived the transfer into gas phase intact and were observed by nanoESI-MS. Complexes that are bound largely by the hydrophobic effect in solution were not detected or only at very low intensity. Complexes with mixed polar and hydrophobic interactions were detected by nanoESI-MS, most likely due to the contribution from polar interactions. All noncovalent complexes could easily be studied by XL MALDI-MS, which demonstrates that the noncovalently bound complexes are conserved, and a real "snap-shot" of the situation in solution can be obtained. PMID:19931466
NASA Astrophysics Data System (ADS)
Katz, Brian G.; Plummer, L. Niel; Busenberg, Eurybiades; Revesz, Kinga M.; Jones, Blair F.; Lee, Terrie M.
1995-06-01
Chemical patterns along evolutionary groundwater flow paths in silicate and carbonate aquifers were interpreted using solute tracers, carbon and sulfur isotopes, and mass balance reaction modeling for a complex hydrologic system involving groundwater inflow to and outflow from a sinkhole lake in northern Florida. Rates of dominant reactions along defined flow paths were estimated from modeled mass transfer and ages obtained from CFC-modeled recharge dates. Groundwater upgradient from Lake Barco remains oxic as it moves downward, reacting with silicate minerals in a system open to carbon dioxide (CO2), producing only small increases in dissolved species. Beneath and downgradient of Lake Barco the oxic groundwater mixes with lake water leakage in a highly reducing, silicate-carbonate mineral environment. A mixing model, developed for anoxic groundwater downgradient from the lake, accounted for the observed chemical and isotopic composition by combining different proportions of lake water leakage and infiltrating meteoric water. The evolution of major ion chemistry and the 13C isotopic composition of dissolved carbon species in groundwater downgradient from the lake can be explained by the aerobic oxidation of organic matter in the lake, anaerobic microbial oxidation of organic carbon, and incongruent dissolution of smectite minerals to kaolinite. The dominant process for the generation of methane was by the CO2 reduction pathway based on the isotopic composition of hydrogen (δ2H(CH4) = -186 to -234‰) and carbon (δ13C(CH4) = -65.7 to -72.3‰). Rates of microbial metabolism of organic matter, estimated from the mass transfer reaction models, ranged from 0.0047 to 0.039 mmol L-1 yr-1 for groundwater downgradient from the lake.
43 CFR 3106.7-5 - Effect of transfer.
Code of Federal Regulations, 2012 CFR
2012-10-01
... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Effect of transfer. 3106.7-5 Section 3106.7-5 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND..., Sublease or Otherwise § 3106.7-5 Effect of transfer. A transfer of record title to 100 percent of a...
NASA Astrophysics Data System (ADS)
Salem, A. M.; Ismail, Galal; Fathy, Rania
2015-06-01
The unsteady boundary layer stagnation point flow of heat and mass transfer in a nanofluid with magnetic field and thermal radiation is theoretically investigated. The resulting governing equations are nondimensionalized and are transformed using a similarity transformation and then solved numerically by the shooting method. Comparison with the previously published work is presented and the results are found to be in good agreement. The effects of unsteadiness parameter A , solid volume fraction , magnetic field M, radiation parameter R, Schmidit number Sc and suction parameter w on the fluid flow, heat and mass transfer characteristic are discussed. Dual similarity solutions for the velocity, temperature and concentration profiles are obtained for some negative values of the unsteadiness parameter. It is found that the critical values of A for which the dual solution exists depend on the values of solid volume fraction parameter in the presence of the Schmidit number. Also, the magnetic field parameter as well as the mass fluid suction widen the range of A for which the solution exists. The results also indicate that momentum, thermal and concentration boundary layer thickness for the first solution are thinner than that of the second solution.
Solute mass transfer from near field to far field in a HLWR experiment at real scale.
NASA Astrophysics Data System (ADS)
Buil, B.; Peña, J.; Gómez, P.; Garralón, A.; Turrero, M. J.; Sánchez, L.; Durán, J. M.
2009-04-01
The FEBEX experiment located in Grimsel (Switzerland) is a 1:1 simulation of a high level waste disposal facility in crystalline rock according to the Spanish concept: two electrical heaters of dimension and weight equivalent to those of the real canisters were installed concentrically with the drift and simulated the thermal effect of the wastes and surrounded by a clay barrier constructed from highly-compacted bentonite blocks. This experiment started in 1996 and the external rim of bentonite is saturated with the granitic water. The difference between the chemical gradients generated by the bentonite porewater and the granitic water made possible the movement of solute into the geosphere. The experiment reproduces in the most realistic conditions, all the processes affecting the radionuclide migration in a HLWR. Two boreholes parallel to the axis of the FEBEX drift were drilled in granite relatively close to the bentonite surface (20 and 60cm) in order to highlight the solute migration mechanisms in crystalline host rock, influenced by the presence of the bentonite buffer and by the geochemical gradients generated at the bentonite/granite interface. After three years of periodic water sampling campaigns in those boreholes, the chemical composition of waters reveal that there is an appreciable increase of Na and Cl concentration in time in the waters sampled from the borehole located at 20cm from the bentonite surface. On the other hand, the Na/Cl ratio in waters is similar to the Na/Cl ratio in the bentonite porewater. For this reason Cl and Na are considered as the main natural tracers indicating the mass transfer process between the bentonite porewater and the granite. A diffusion transport modelling (PHREEQC) was used to describe the mass transfer process. The results show that the Cl and Na concentration in the granitic waters is the result of a diffusive transport from the bentonite to the granite, with a calculated De≈ 5,0E-11 m2/s. These results could
De Mink, S. E.; Langer, N.; Izzard, R. G.; Sana, H.; De Koter, A.
2013-02-20
Rotation is thought to be a major factor in the evolution of massive stars-especially at low metallicity-with consequences for their chemical yields, ionizing flux, and final fate. Deriving the birth spin distribution is of high priority given its importance as a constraint on theories of massive star formation and as input for models of stellar populations in the local universe and at high redshift. Recently, it has become clear that the majority of massive stars interact with a binary companion before they die. We investigate how this affects the distribution of rotation rates, through stellar winds, expansion, tides, mass transfer, and mergers. For this purpose, we simulate a massive binary-star population typical for our Galaxy assuming continuous star formation. We find that, because of binary interaction, 20{sup +5} {sub -10}% of all massive main-sequence stars have projected rotational velocities in excess of 200 km s{sup -1}. We evaluate the effect of uncertain input distributions and physical processes and conclude that the main uncertainties are the mass transfer efficiency and the possible effect of magnetic braking, especially if magnetic fields are generated or amplified during mass accretion and stellar mergers. The fraction of rapid rotators we derive is similar to that observed. If indeed mass transfer and mergers are the main cause for rapid rotation in massive stars, little room remains for rapidly rotating stars that are born single. This implies that spin-down during star formation is even more efficient than previously thought. In addition, this raises questions about the interpretation of the surface abundances of rapidly rotating stars as evidence for rotational mixing. Furthermore, our results allow for the possibility that all early-type Be stars result from binary interactions and suggest that evidence for rotation in explosions, such as long gamma-ray bursts, points to a binary origin.
Mass transfer from a sphere in an oscillating flow with zero mean velocity
NASA Technical Reports Server (NTRS)
Drummond, Colin K.; Lyman, Frederic A.
1990-01-01
A pseudospectral numerical method is used for the solution of the Navier-Stokes and mass transport equations for a sphere in a sinusoidally oscillating flow with zero mean velocity. The flow is assumed laminar and axisymmetric about the sphere's polar axis. Oscillating flow results were obtained for Reynolds numbers (based on the free-stream oscillatory flow amplitude) between 1 and 150, and Strouhal numbers between 1 and 1000. Sherwood numbers were computed and their dependency on the flow frequency and amplitude discussed. An assessment of the validity of the quasi-steady assumption for mass transfer is based on these results.
Heat and mass transfer in combustion - Fundamental concepts and analytical techniques
NASA Technical Reports Server (NTRS)
Law, C. K.
1984-01-01
Fundamental combustion phenomena and the associated flame structures in laminar gaseous flows are discussed on physical bases within the framework of the three nondimensional parameters of interest to heat and mass transfer in chemically-reacting flows, namely the Damkoehler number, the Lewis number, and the Arrhenius number which is the ratio of the reaction activation energy to the characteristic thermal energy. The model problems selected for illustration are droplet combustion, boundary layer combustion, and the propagation, flammability, and stability of premixed flames. Fundamental concepts discussed include the flame structures for large activation energy reactions, S-curve interpretation of the ignition and extinctin states, reaction-induced local-similarity and non-similarity in boundary layer flows, the origin and removal of the cold boundary difficulty in modeling flame propagation, and effects of flame stretch and preferential diffusion on flame extinction and stability. Analytical techniques introduced include the Shvab-Zeldovich formulation, the local Shvab-Zeldovich formulation, flame-sheet approximation and the associated jump formulation, and large activation energy matched asymptotic analysis. Potentially promising research areas are suggested.
Mass transfer enhancement in supercritical fluids extraction by means of power ultrasound.
Riera, E; Golás, Y; Blanco, A; Gallego, J A; Blasco, M; Mulet, A
2004-05-01
The use of high-intensity ultrasound represents an efficient manner of producing small scale agitation, enhancing mass transfer on supercritical fluids (SF) extraction processes. In this way, a supercritical CO(2) extraction of oil from particulate almonds using power ultrasound was studied. To examine the effect of the acoustic waves all experiments were performed with and without ultrasound. A power ultrasonic transducer for a working frequency of about 20 kHz was constructed and installed inside a high-pressure 5 l SF extractor. The experimental tests were carried out with CO(2) at 280 bar and 55 degrees C. Grounded almonds with an oil content of about 55%, in an amount of 1500 g were deposited inside the SF reactor where the solvent was introduced at a flow rate of 20 kg/h. The results show that the kinetics and the extraction yield of the oil were enhanced by 30% and 20% respectively, when a power of about 50 W was applied to the transducer. The average time of each extraction process was of about 8 h and 30 min. In addition, the transducer was also used as a sensitive probe capable to detect the phase behavior of supercritical fluids when it was driven with low power signals. PMID:15081988
Counter-extrapolation method for conjugate interfaces in computational heat and mass transfer.
Le, Guigao; Oulaid, Othmane; Zhang, Junfeng
2015-03-01
In this paper a conjugate interface method is developed by performing extrapolations along the normal direction. Compared to other existing conjugate models, our method has several technical advantages, including the simple and straightforward algorithm, accurate representation of the interface geometry, applicability to any interface-lattice relative orientation, and availability of the normal gradient. The model is validated by simulating the steady and unsteady convection-diffusion system with a flat interface and the steady diffusion system with a circular interface, and good agreement is observed when comparing the lattice Boltzmann results with respective analytical solutions. A more general system with unsteady convection-diffusion process and a curved interface, i.e., the cooling process of a hot cylinder in a cold flow, is also simulated as an example to illustrate the practical usefulness of our model, and the effects of the cylinder heat capacity and thermal diffusivity on the cooling process are examined. Results show that the cylinder with a larger heat capacity can release more heat energy into the fluid and the cylinder temperature cools down slower, while the enhanced heat conduction inside the cylinder can facilitate the cooling process of the system. Although these findings appear obvious from physical principles, the confirming results demonstrates the application potential of our method in more complex systems. In addition, the basic idea and algorithm of the counter-extrapolation procedure presented here can be readily extended to other lattice Boltzmann models and even other computational technologies for heat and mass transfer systems. PMID:25871245
Natural convection mass transfer on a vertical steel structure submerged in a molten aluminum pool
Cheung, F.B.; Yang, B.C.; Shiah, S.W.; Cho, D.H.; Tan, M.J.
1995-02-01
The process of dissolution mass transport along a vertical steel structure submerged in a large molten aluminum pool is studied theoretically. A mathematical model is developed from the conservation laws and thermodynamic principles, taking full account of the density variation in the dissolution boundary layer due to concentration differences. Also accounted for are the influence of the solubility of the wall material on species transfer and the motion of the solid/liquid interface at the dissolution front. The governing equations are solved by a combined analytical-numerical technique to determine the characteristics of the dissolution boundary layer and the rate of natural convection mass transfer. Based upon the numerical results, a correlation for the average Sherwood number is obtained. It is found that the Sherwood number depends strongly on the saturated concentration of the substrate at the moving dissolution front but is almost independent of the freestream velocity.
Dong, Zhengya; Yao, Chaoqun; Zhang, Xiaoli; Xu, Jie; Chen, Guangwen; Zhao, Yuchao; Yuan, Quan
2015-02-21
The combination of ultrasound and microreactor is an emerging and promising area, but the report of designing high-power ultrasonic microreactor (USMR) is still limited. This work presents a robust, high-power and highly efficient USMR by directly coupling a microreactor plate with a Langevin-type transducer. The USMR is designed as a longitudinal half wavelength resonator, for which the antinode plane of the highest sound intensity is located at the microreactor. According to one dimension design theory, numerical simulation and impedance analysis, a USMR with a maximum power of 100 W and a resonance frequency of 20 kHz was built. The strong and uniform sound field in the USMR was then applied to intensify gas-liquid mass transfer of slug flow in a microfluidic channel. Non-inertial cavitation with multiple surface wave oscillation was excited on the slug bubbles, enhancing the overall mass transfer coefficient by 3.3-5.7 times. PMID:25537767
Microscale resolution of interfacial mass-transfer rates in electrode processes
Whitney, G.M.; Tobias, C.W.
1987-06-01
Results of four interrelated studies concerning the nature of electrolytic gas evolution are reported: (1) configurations of axisymmetric bubbles formed on curved surfaces are evaluated; (2) mass-transfer enhancement by a stream of bubbles rising near a mass-transfer surface is resolved spatially and temporally using a micro-mosaic electrode; (3) the onset of buoyancy-induced convection is investigated for a case in which the density profile develops in a semi-infinite fluid, due to a step change in surface concentration at a rigid, conducting boundary; (4) observations of galvanostatic growth and disengagement of hydrogen bubbles at a 127-..mu..m-diameter micro-electrode embedded in a large, coplanar, horizontal electrode in 1.0-M sulfuric acid are reported.
Microbial synthesis gas utilization and ways to resolve kinetic and mass-transfer limitations.
Yasin, Muhammad; Jeong, Yeseul; Park, Shinyoung; Jeong, Jiyeong; Lee, Eun Yeol; Lovitt, Robert W; Kim, Byung Hong; Lee, Jinwon; Chang, In Seop
2015-02-01
Microbial conversion of syngas to energy-dense biofuels and valuable chemicals is a potential technology for the efficient utilization of fossils (e.g., coal) and renewable resources (e.g., lignocellulosic biomass) in an environmentally friendly manner. However, gas-liquid mass transfer and kinetic limitations are still major constraints that limit the widespread adoption and successful commercialization of the technology. This review paper provides rationales for syngas bioconversion and summarizes the reaction limited conditions along with the possible strategies to overcome these challenges. Mass transfer and economic performances of various reactor configurations are compared, and an ideal case for optimum bioreactor operation is presented. Overall, the challenges with the bioprocessing steps are highlighted, and potential solutions are suggested. Future research directions are provided and a conceptual design for a membrane-based syngas biorefinery is proposed. PMID:25443672
Thermal treatments of foods: a predictive general-purpose code for heat and mass transfer
NASA Astrophysics Data System (ADS)
Barba, Anna Angela
2005-05-01
Thermal treatments of foods required accurate processing protocols. In this context, mathematical modeling of heat and mass transfer can play an important role in the control and definition of the process parameters as well as to design processing systems. In this work a code able to simulate heat and mass transfer phenomena within solid bodies has been developed. The code has been written with the ability of describing different geometries and it can account for any kind of different initial/boundary conditions. Transport phenomena within multi-layer bodies can be described, and time/position dependent material parameters can be implemented. Finally, the code has been validated by comparison with a problem for which the analytical solution is known, and by comparison with a differential scanning calorimetry signal that described the heating treatment of a raw potato (Solanum tuberosum).
Bhargava, Swapnil; Wenger, Kevin S; Marten, Mark R
2003-01-01
Productivity in many fungal fermentations is detrimentally affected by high broth viscosity and consequent reduced oxygen mass transfer capacity. The goal here was to determine whether pulsed feeding of limiting carbon in a fungal fermentation could lead to reduced viscosity and improved oxygen mass transfer. As a model, an industrially relevant recombinant strain of Aspergillus oryzae was grown in carbon-limited, fed-batch mode. Maltodextrin was used as a carbon source and was added either continuously or in 1.5-min pulses, 3.5 min apart. In both feeding modes the same total amount of carbon was added, and carbon feed rate was at sufficiently low levels to ensure cultures were always carbon-limited. Compared to continuous feeding, pulsed addition of substrate led to smaller fungal elements, which resulted in a significant reduction in broth viscosity. This in turn led to higher dissolved oxygen concentrations and increased oxygen uptake rates during pulsed feeding. PMID:12790687
Mass partitioning effects in diffusion transport.
Kojic, Milos; Milosevic, Miljan; Wu, Suhong; Blanco, Elvin; Ferrari, Mauro; Ziemys, Arturas
2015-08-28
Frequent mass exchange takes place in a heterogeneous environment among several phases, where mass partitioning may occur at the interface of phases. Analytical and computational methods for diffusion do not usually incorporate molecule partitioning masking the true picture of mass transport. Here we present a computational finite element methodology to calculate diffusion mass transport with a partitioning phenomenon included and the analysis of the effects of partitioning. Our numerical results showed that partitioning controls equilibrated mass distribution as expected from analytical solutions. The experimental validation of mass release from drug-loaded nanoparticles showed that partitioning might even dominate in some cases with respect to diffusion itself. The analysis of diffusion kinetics in the parameter space of partitioning and diffusivity showed that partitioning is an extremely important parameter in systems, where mass diffusivity is fast and that the concentration of nanoparticles can control payload retention inside nanoparticles. The computational and experimental results suggest that partitioning and physiochemical properties of phases play an important, if not crucial, role in diffusion transport and should be included in the studies of mass transport processes. PMID:26204522
Local immobilization of particles in mass transfer described by a Jeffreys-type equation
NASA Astrophysics Data System (ADS)
Rukolaine, S. A.; Samsonov, A. M.
2013-12-01
We consider the Jeffreys-type equation as the foundation in three different models of mass transfer, namely, the Jeffreys-type and two-phase models and the D1 approximation to the linear Boltzmann equation. We study two classic (1+1)-dimensional problems in the framework of each model. The first problem is the transfer of a substance initially confined at a point. The second problem is the transfer of a substance from a stationary point source. We calculate the mean-square displacement (MSD) for the solutions of the first problem. The temporal behavior of the MSD in the framework of the first and third models is found to be the same as that in the Brownian motion described by the standard Langevin equation. In addition, we find a remarkable phenomenon when a portion of the substance does not move.
NASA Astrophysics Data System (ADS)
Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza
2015-08-01
To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.
Energy (mass) transfer processes in low-temperature plasma as applied to forming ordered structures
NASA Astrophysics Data System (ADS)
Abramenko, T. N.; Laktyushina, T. V.; Laktyushin, A. N.
2000-03-01
The methods of irreversible thermodynamics are adopted to analyze the energy (mass) transfer in gases (their mixtures) over a wide temperature range up to 20000 K. An energy transfer process is considered as a path in the state space, and a concept of non-Euclidean state space is postulated. Experimental data on the gas thermal conductivity over a wide temperature range is generalized by the methods of thermodynamic similarity theory. Thermal conductivities of CH4-O2 and CH4-H2O mixtures are calculated for technological applications. The process of forming a space-time structure is analyzed by using the experimental data on the gas thermal conductivity over a wide temperature range. An attempt is made to interpret the mechanism of the thermal diffusion in gases due to the forming of ordered structures. A contribution of the diffusional thermoeffect to the energy transfer processes in a three-component nitrogen plasma is calculated.
Analysis of mass transfer in dissipative nonideal systems: Experiments on dusty plasmas
Vaulina, O. S.; Adamovich, K. G. Petrov, O. F.; Fortov, V. E.
2008-08-15
Results of an experimental study of mass transfer are presented for extended systems of dust particles observed in capacitively coupled RF discharge plasmas. The Green-Kubo relation and the Langevin equation are validated as applied to dust grain dynamics in laboratory plasmas. A procedure is proposed for evaluating the temperature, friction coefficient, and characteristic oscillation frequency for dust grains. Measured characteristics of the dust subsystem (diffusion coefficient, pair correlation function, and friction coefficient) are compared with available theoretical and numerical results.
Mass transfer kinetics on heterogeneous binding sites of molecularly imprinted polymers
Kim, Hyunjung; Kaczmarski, Krzysztof; Guiochon, Georges A
2005-07-01
The mass transfer kinetics of the L- and D-Fmoc-Tryptophan (Fmoc-Trp) enantiomers on Fmoc-L-Trp imprinted polymer (MIP) and on its reference polymer (NIP), were measured using their elution peak profiles and the breakthrough curves recorded in frontal analysis for the determination of their equilibrium isotherms, at temperatures of 40, 50, 60, and 70 C. At all temperatures, the isotherm data of the Fmoc-Trp enantiomers on the MIP were best accounted for by the Tri-Langmuir isotherm model, while the isotherm data of Fmoc-Trp on the NIP were best accounted for by the Bi-Langmuir isotherm model. The profiles of the elution bands of various amounts of each enantiomer were acquired in the concentration range from 0.1 to 40 mM. These experimental profiles were compared with those calculated using the best values estimated for the isotherm parameters and the lumped pore diffusion model (POR), which made possible to calculate the intraparticle diffusion coefficients for each system. The results show that surface diffusion contributes predominantly to the overall mass transfer kinetics on both the MIP and the NIP, compared to external mass transfer and pore diffusion. The surface diffusion coefficients (D{sub s}) of Fmoc-L-Trp on the NIP does not depend on the amount bound (q) while the values of D{sub s} for the two Fmoc-Trp enantiomers on the MIP increase with increasing q at all temperatures. These positive dependencies of D{sub s} on q for Fmoc-Trp on the MIP were fairly well modeled by indirectly incorporating surface heterogeneity into the surface diffusion coefficient. The results obtained show that the mass transfer kinetics of the enantiomers on the imprinted polymers depend strongly on the surface heterogeneity.
Multi-scale heat and mass transfer modelling of cell and tissue cryopreservation
Xu, Feng; Moon, Sangjun; Zhang, Xiaohui; Shao, Lei; Song, Young Seok; Demirci, Utkan
2010-01-01
Cells and tissues undergo complex physical processes during cryopreservation. Understanding the underlying physical phenomena is critical to improve current cryopreservation methods and to develop new techniques. Here, we describe multi-scale approaches for modelling cell and tissue cryopreservation including heat transfer at macroscale level, crystallization, cell volume change and mass transport across cell membranes at microscale level. These multi-scale approaches allow us to study cell and tissue cryopreservation. PMID:20047939
Microscale Enhancement of Heat and Mass Transfer for Hydrogen Energy Storage
Drost, Kevin; Jovanovic, Goran; Paul, Brian
2015-09-30
The document summarized the technical progress associated with OSU’s involvement in the Hydrogen Storage Engineering Center of Excellence. OSU focused on the development of microscale enhancement technologies for improving heat and mass transfer in automotive hydrogen storage systems. OSU’s key contributions included the development of an extremely compact microchannel combustion system for discharging hydrogen storage systems and a thermal management system for adsorption based hydrogen storage using microchannel cooling (the Modular Adsorption Tank Insert or MATI).
Modeling of the mass transfer rates of metal ions across supported liquid membranes. 1: Theory
Elhassadi, A.A.; Do, D.D.
1999-01-01
This paper deals with the modeling of the transport and separation of metal ions across supported liquid membranes. The mass transfer resistance at the liquid-membrane interfaces and the interfacial chemical reactions at both the extracting side and the stripping side are taken into account in the model equations. Simple analysis of the time scale of the system shows the influence of various important parameters and their interactions on the overall transport rate. Parametric studies are also dealt with in this paper.
Modulated mass-transfer model for superhumps in SU Ursae Majoris stars
NASA Technical Reports Server (NTRS)
Mineshige, Shin
1988-01-01
The response of a circular accretion disk to rapid modulation of the mass-transfer rate into the disk is explored in order to model superhumps in SU UMa stars. It is proposed that periodically enhanced flow may disrupt or heat up the outer disk and produce the dips noted just before the superhump peaks. The elliptical accretion-disk model with extended vertical disk structure can account for the observed characteristics of superhumps in these stars.
Kinetics of mass transfer during deep fat frying of yellow fleshed cassava root slices
NASA Astrophysics Data System (ADS)
Oyedeji, A. B.; Sobukola, O. P.; Henshaw, F. O.; Adegunwa, M. O.; Sanni, L. O.; Tomlins, K. I.
2016-05-01
Kinetics of mass transfer [moisture content, oil uptake, total carotenoid (TC) and shrinkage] during frying of yellow fleshed cassava roots (TMS 01/1371) was investigated. Slices were divided into (i) fresh and (ii) pre-dried to 75 % moisture content before atmospheric frying and (iii) vacuum fried. Percentage TC and activation energies of vacuum, fresh and pre-dried fried samples were 76, 63 and 61 %; and 82, 469.7, 213.7 kJ/mol, respectively.
NASA Astrophysics Data System (ADS)
Sharifi Haddad, Amin
Fractured porous media are important structures in petroleum engineering and geohydrology. The accelerating global demand for energy has turned the focus to fractured formations. The fractured porous media are also found in conventional naturally fractured reservoirs and the water supply from karst (carbonate) aquifers. Studying mass transfer processes allows us to explore the complexities and uncertainties encountered with fractured rocks. This dissertation is developing an analytical methodology for the study of mass transfer in fractured reservoirs. The dissertation begins with two cases that demonstrate the importance of the rock matrix block size distribution and dispersivity through a transient mass exchange mechanism between rock matrix blocks and fractures. The first case assumes a medium with no surface adsorption, and the second case includes the surface adsorption variable. One of the main focuses of this work is the characterization of the rock matrix block size distribution in fractured porous media. Seismic surveying, well test analysis, well logging, and geomechanical tools are currently used to characterize this property, based on measurements of different variables. This study explores an innovative method of using solute transport to determine the fracture intensity. This methodology is applied to slab-shaped rock matrix blocks and can easily be extended to other geometries. Another focus of this dissertation is the characterization of dispersivity in field scale studies. Improving our knowledge of dispersivity will enable more accurate mass transfer predictions and advance the study of transport processes. Field tracer tests demonstrated that dispersivity is scale-dependent. Proposed functions for the increasing trend of dispersivity include linear and asymptotic scale-dependence. This study investigated the linear dispersivity trend around the injection wellbore. An analysis of the tracer concentration in a monitoring well was used to
Mass and charge transfer in the heavy ion reactions 208Ni and 208Ni
NASA Astrophysics Data System (ADS)
Sapotta, K.; Bass, R.; Hartmann, V.; Noll, H.; Renfordt, R. E.; Stelzer, K.
1985-04-01
Target-like reaction products corresponding to the transfer of one or several nucleons have been measured as a function of the total kinetic energy loss in the reactions 208Ni (1215 MeV) and 208Ni (1107 MeV) with a focusing time-of-flight spectrometer which provided a unique mass and charge separation and good energy resolution. The analysis of the experimental data covered the range from elastic scattering to deep-inelastic collisions. In the quasielastic region, neutron transfer dominates. The transfer probabilities as a function of the distance of closest approach can be described by a semiclassical theory of tunneling. Quasielastic transfer from the Ni targets to the 208Pb projectile is strongly inhibited by the reaction Q values. For the intermediate and deep-inelastic collisions, the mean values and variances of the mass and charge distributions as a function of the dissipated energy, as well as the correlations between neutron and proton transport, are discussed in a statistical diffusion theory. The important influence of the static potential energy surface on nucleon transport in the deep-inelastic region is demonstrated. Deviations from the simple diffusion model, observed at small to medium energy losses, are discussed.
NASA Astrophysics Data System (ADS)
Tobajas, M.; García-Calvo, E.
Mass transfer in bioreactors has been examined. In the present work, dynamic methods are used for the determination of KLa values for water, model media and a fermentation broth (Candida utilis) in an airlift reactor. The conventional dynamic method is applied at the end of the microbial process in order to avoid an alteration in the metabolism of the microorganisms. New dynamic methods are used to determine KLa in an airlift reactor during the microbial growth of Candida utilis on glucose. One of the methods is based on the continuous measurement of carbon dioxide production while the other method is based on the relationship between the oxygen transfer and biomass growth rates. These methods of determining KLa does not interfere with the microorganisms action. A theoretical mass transfer model has been used for KLa estimation for the systems described above. Some differences between calculated and measured values are found for fermentation processes due to the model is developed for two-phase air-water systems. Nevertheless, the average deviation between the predicted values and those obtained from the relationship between oxygen transfer and biomass production rates are lower than 25% in any case.
Calibration of mass transfer-based models to predict reference crop evapotranspiration
NASA Astrophysics Data System (ADS)
Valipour, Mohammad
2015-03-01
The present study aims to compare mass transfer-based models to determine the best model under different weather conditions. The results showed that the Penman model estimates reference crop evapotranspiration better than other models in most provinces of Iran (15 provinces). However, the values of R 2 were less than 0.90 for 24 provinces of Iran. Therefore, the models were calibrated, and precision of estimation was increased (the values of R 2 were less than 0.90 for only ten provinces in the modified models). The mass transfer-based models estimated reference crop evapotranspiration in the northern (near the Caspian Sea) and southern (near the Persian Gulf) Iran (annual relative humidity more than 65 %) better than other provinces. The best values of R 2 were 0.96 and 0.98 for the Trabert and Rohwer models in Ardabil (AR) and Mazandaran (MZ) provinces before and after calibration, respectively. Finally, a list of the best performances of each model was presented to use other regions and next studies according to values of mean, maximum, and minimum temperature, relative humidity, and wind speed. The best weather conditions to use mass transfer-based equations are 8-18 °C (with the exception of Ivanov), <25.5 °C, <15 °C, >55 % for mean, maximum, and minimum temperature, and relative humidity, respectively.
Mass transfer from nonaqueous phase organic liquids in water-saturated porous media
Geller, J.T. ); Hunt, J.R. )
1993-04-01
The widespread production and use of industrial solvents and liquid petroleum products have provided ample opportunity for subsurface contamination from leaking underground storage tanks and pipelines, hazardous waste sites, and surface spills. The aqueous solubility of these organic liquid contaminants is low enough for them to exist in the subsurface as nonaqueous phase liquids (NAPLs) but large enough to seriously degrade water quality. In this paper, results from measuring the complete dissolution of trapped NAPLs and developing a model are discussed. The NAPL saturation is modeled as discrete spheres that are initially uniform in size. From the experimental data, ganglia size and the cross-sectional area of the NAPL region are obtained by fitting the model to the data and assuming a fixed initial NAPL saturation. This two-parameter model, when combined with known magnitudes of residual saturation and relative permeability functions represented experimental observations of (1) increasing aqueous concentration during initial water flooding as the mass transfer zone is established, (2) a quasi-steady effluent concentration as the mass transfer zone propagates downstream, and (3) the decline in effluent concentration as the NAPL-containing region shrinks to less than the length of the mass transfer zone. The experimental data and modeling effort illustrate mechanisms that limit the remediation of NAPL-contaminated aquifers. There is a complex dependency of groundwater contaminant concentration on flow velocity.
Li, Chunqing; Tie, Xiaobo; Liang, Kai; Ji, Chanjuan
2016-01-01
After conducting the intensive research on the distribution of fluid's velocity and biochemical reactions in the membrane bioreactor (MBR), this paper introduces the use of the mass-transfer differential equation to simulate the distribution of the chemical oxygen demand (COD) concentration in MBR membrane pool. The solutions are as follows: first, use computational fluid dynamics to establish a flow control equation model of the fluid in MBR membrane pool; second, calculate this model by adopting direct numerical simulation to get the velocity field of the fluid in membrane pool; third, combine the data of velocity field to establish mass-transfer differential equation model for the concentration field in MBR membrane pool, and use Seidel iteration method to solve the equation model; last but not least, substitute the real factory data into the velocity and concentration field model to calculate simulation results, and use visualization software Tecplot to display the results. Finally by analyzing the nephogram of COD concentration distribution, it can be found that the simulation result conforms the distribution rule of the COD's concentration in real membrane pool, and the mass-transfer phenomenon can be affected by the velocity field of the fluid in membrane pool. The simulation results of this paper have certain reference value for the design optimization of the real MBR system. PMID:27375999
Passive control of wall shear stress and mass transfer generated by submerged lobed impinging jet
NASA Astrophysics Data System (ADS)
Sodjavi, Kodjovi; Montagné, Brice; Meslem, Amina; Byrne, Paul; Serres, Laurent; Sobolik, Vaclav
2016-05-01
Particle image velocimetry was used to investigate the flow field in an impinging lobed daisy hemispherical nozzle jet in comparison to its counterpart round jet, at a Reynolds number of 5620 based on the exit velocity and the equivalent diameter D e of the nozzle. The limitations of the PIV technique in the vicinity of the target wall due to the laser scattering were addressed by using the electrodiffusion (ED) technique to determine the wall shear rate distribution. The distribution of the mass transfer coefficient is also obtained using the ED technique. The target wall is placed at a distance H = 2 D e from the plane tangent to the nozzle, at the center of the orifice. The entrainment of ambient fluid in the free jet region, which is larger in the lobed jet compared to the round jet, feeds in turn the wall jet region. The maximum wall shear rate was found significantly higher in the daisy jet, with an excess of 93 % compared to the reference round jet. The maximum mass transfer is 35 % higher in the former compared to the latter. Therefore, the hemispherical daisy nozzle is an excellent candidate in passive strategies to enhance local skin-friction and the subsequent local mass transfer at a constant exit Reynolds number.
Mass transfer in a flow past a non-porous catalyst sphere
NASA Astrophysics Data System (ADS)
Sun, Bo; Tenneti, Sudheer; Subramaniam, Shankar
2015-11-01
Mass transfer in a flow past a particle with a surface chemical reaction occurs in applications involving catalytic reaction. This type of the mass transfer problem has been analyzed by solving the convection-diffusion equation for Stokes flow (Acrivos et al., 1962) or flow at low Reynolds number (Taylor 1963, Gupalo et al., 1972). The objective of this study is to extend our understanding of this mass transfer problem to higher Reynolds number (up to 100) and assemblies of several particles by using particle-resolved direct numerical simulation (PR-DNS) of gas-solid flow. A uniform flow past a non-porous spherical particle with a first-order surface reaction is simulated. The non-dimensional reaction rate constant is the important parameter in the single particle case. The PR-DNS results at low Reynolds number for a single particle are first compared with 2D analytical solutions for concentration fields and the Sherwood number. Finally, the dependence of the concentration field on the non-dimensional reaction rate constant, and comparison of PR-DNS results with other Sherwood number correlations that use the Reynolds analogy to adapt Nusselt number correlations (which do not explicitly account for surface reactions) are explored at high Reynolds number. CBET 1034307, CBET 1336941.
Simultaneous heat and mass transfer in absorption of gases in laminar liquid films
Grossman, G
1982-09-01
A theoretical analysis of the combined heat and mass transfer process taking place in the absorption of a gas or vapor into a laminar liquid film is described. This type of process, which occurs in many gas-liquid systems, often releases only a small amount of heat, making the process almost isothermal. In some cases, however, the heat of absorption is significant and temperature variations cannot be ignored. One example, from which the present study originated, is in absorption heat pumps where mass transfer is produced specifically to generate a temperature change. The model analyzed describes a liquid film that flows over an inclined plane and has its free surface in contact with stagnant vapor. The absorption process at the surface creates nonuniform temperature and concentration profiles in the film, which develop until equilibrium between the liquid and vapor is achieved. The energy and diffusion equations are solved simultaneously to give the temperature and concentration variations at the interface and the wall. Two cases of interest are considered: constant-temperature and adiabatic walls. The Nusselt and Sherwood numbers are expressed in terms of the operating parameters, from which heat and mass transfer coefficients can be determined. The Nusselt and Sherwood numbers are found to depend on the Peclet and Lewis numbers as well as on the equilibrium characteristics of the working materials.
Method and system for simulating heat and mass transfer in cooling towers
Bharathan, Desikan; Hassani, A. Vahab
1997-01-01
The present invention is a system and method for simulating the performance of a cooling tower. More precisely, the simulator of the present invention predicts values related to the heat and mass transfer from a liquid (e.g., water) to a gas (e.g., air) when provided with input data related to a cooling tower design. In particular, the simulator accepts input data regarding: (a) cooling tower site environmental characteristics; (b) cooling tower operational characteristics; and (c) geometric characteristics of the packing used to increase the surface area within the cooling tower upon which the heat and mass transfer interactions occur. In providing such performance predictions, the simulator performs computations related to the physics of heat and mass transfer within the packing. Thus, instead of relying solely on trial and error wherein various packing geometries are tested during construction of the cooling tower, the packing geometries for a proposed cooling tower can be simulated for use in selecting a desired packing geometry for the cooling tower.
Janecky, D.R.
1988-09-21
A computational modeling code (EQPSreverse arrowS) has been developed to examine sulfur isotopic distribution pathways coupled with calculations of chemical mass transfer pathways. A post processor approach to EQ6 calculations was chosen so that a variety of isotopic pathways could be examined for each reaction pathway. Two types of major bounding conditions were implemented: (1) equilibrium isotopic exchange between sulfate and sulfide species or exchange only accompanying chemical reduction and oxidation events, and (2) existence or lack of isotopic exchange between solution species and precipitated minerals, parallel to the open and closed chemical system formulations of chemical mass transfer modeling codes. All of the chemical data necessary to explicitly calculate isotopic distribution pathways is generated by most mass transfer modeling codes and can be input to the EQPS code. Routines are built in to directly handle EQ6 tabular files. Chemical reaction models of seafloor hydrothermal vent processes and accompanying sulfur isotopic distribution pathways illustrate the capabilities of coupling EQPSreverse arrowS with EQ6 calculations, including the extent of differences that can exist due to the isotopic bounding condition assumptions described above. 11 refs., 2 figs.
Modeling CO2 mass transfer in amine mixtures: PZ-AMP and PZ-MDEA.
Puxty, Graeme; Rowland, Robert
2011-03-15
The most common method of carbon dioxide (CO(2)) capture is the absorption of CO(2) into a falling thin film of an aqueous amine solution. Modeling of mass transfer during CO(2) absorption is an important way to gain insight and understanding about the underlying processes that are occurring. In this work a new software tool has been used to model CO(2) absorption into aqueous piperazine (PZ) and binary mixtures of PZ with 2-amino-2-methyl-1-propanol (AMP) or methyldiethanolamine (MDEA). The tool solves partial differential and simultaneous equations describing diffusion and chemical reaction automatically derived from reactions written using chemical notation. It has been demonstrated that by using reactions that are chemically plausible the mass transfer in binary mixtures can be fully described by combining the chemical reactions and their associated parameters determined for single amines. The observed enhanced mass transfer in binary mixtures can be explained through chemical interactions occurring in the mixture without need to resort to using additional reactions or unusual transport phenomena such as the "shuttle mechanism". PMID:21329341
Drop mass transfer in a microfluidic chip compared to a centrifugal contactor
Nemer, Martin B.; Roberts, Christine C.; Hughes, Lindsey G.; Wyatt, Nicholas B.; Brooks, Carlton F.; Rao, Rekha
2014-06-13
A model system was developed for enabling a multiscale understanding of centrifugal-contactor liquid–liquid extraction.The system consisted of Nd(III) + xylenol orange in the aqueous phase buffered to pH =5.5 by KHP, and dodecane + thenoyltrifluroroacetone (HTTA) + tributyphosphate (TBP) in the organic phase. Diffusion constants were measured for neodymium in both the organic and aqueous phases, and the Nd(III) partition coefficients were measured at various HTTA and TBP concentrations. A microfluidic channel was used as a high-shear model environment to observe mass-transfer on a droplet scale with xylenol orange as the aqueous-phase metal indicator; mass-transfer rates were measured quantitatively inmore » both diffusion and reaction limited regimes on the droplet scale. Lastly, the microfluidic results were comparable to observations made for the same system in a laboratory scale liquid–liquid centrifugal contactor, indicating that single drop microfluidic experiments can provide information on mass transfer in complicated flows and geometries.« less
Drop mass transfer in a microfluidic chip compared to a centrifugal contactor
Nemer, Martin B.; Roberts, Christine C.; Hughes, Lindsey G.; Wyatt, Nicholas B.; Brooks, Carlton F.; Rao, Rekha
2014-06-13
A model system was developed for enabling a multiscale understanding of centrifugal-contactor liquid–liquid extraction.The system consisted of Nd(III) + xylenol orange in the aqueous phase buffered to pH =5.5 by KHP, and dodecane + thenoyltrifluroroacetone (HTTA) + tributyphosphate (TBP) in the organic phase. Diffusion constants were measured for neodymium in both the organic and aqueous phases, and the Nd(III) partition coefficients were measured at various HTTA and TBP concentrations. A microfluidic channel was used as a high-shear model environment to observe mass-transfer on a droplet scale with xylenol orange as the aqueous-phase metal indicator; mass-transfer rates were measured quantitatively in both diffusion and reaction limited regimes on the droplet scale. Lastly, the microfluidic results were comparable to observations made for the same system in a laboratory scale liquid–liquid centrifugal contactor, indicating that single drop microfluidic experiments can provide information on mass transfer in complicated flows and geometries.
NASA Astrophysics Data System (ADS)
Tecklenburg, Jan; Neuweiler, Insa; Dentz, Marco; Carrera, Jesus; Geiger, Sebastian
2013-04-01
Flow processes in geotechnical applications do often take place in highly heterogeneous porous media, such as fractured rock. Since, in this type of media, classical modelling approaches are problematic, flow and transport is often modelled using multi-continua approaches. From such approaches, multirate mass transfer models (mrmt) can be derived to describe the flow and transport in the "fast" or mobile zone of the medium. The porous media is then modeled with one mobile zone and multiple immobile zones, where the immobile zones are connected to the mobile zone by single rate mass transfer. We proceed from a mrmt model for immiscible displacement of two fluids, where the Buckley-Leverett equation is expanded by a sink-source-term which is nonlocal in time. This sink-source-term models exchange with an immobile zone with mass transfer driven by capillary diffusion. This nonlinear diffusive mass transfer can be approximated for particular imbibition or drainage cases by a linear process. We present a numerical scheme for this model together with simulation results for a single fracture test case. We solve the mrmt model with the finite volume method and explicit time integration. The sink-source-term is transformed to multiple single rate mass transfer processes, as shown by Carrera et. al. (1998), to make it local in time. With numerical simulations we studied immiscible displacement in a single fracture test case. To do this we calculated the flow parameters using information about the geometry and the integral solution for two phase flow by McWorther and Sunnada (1990). Comparision to the results of the full two dimensional two phase flow model by Flemisch et. al. (2011) show good similarities of the saturation breakthrough curves. Carrera, J., Sanchez-Vila, X., Benet, I., Medina, A., Galarza, G., and Guimera, J.: On matrix diffusion: formulations, solution methods and qualitative effects, Hydrogeology Journal, 6, 178-190, 1998. Flemisch, B., Darcis, M
Gonçalves, L R; Suzuki, G S; Giordano, R C; Giordano, R L
2001-01-01
Kinetic and mass transport parameters were estimated for maltotriose hydrolysis using glucoamylase immobilized on macroporous silica and wrapped in pectin gel at 30 degrees C. Free enzyme assays were used to obtain the intrinsic kinetic parameters of a Michaelis-Menten equation, with product inhibition by glucose. The uptake method, based on transient experimental data, was employed in the estimation of mass transfer parameters. Effective diffusivities of maltotriose in pectin gel were estimated by fitting a classical diffusion model to experimental data of maltotriose diffusion into particles of pectin gel in the absence of silica. The effective diffusivities of maltotriose in silica were obtained after fitting a bidisperse model to experimental data of maltotriose hydrolysis using glucoamylase immobilized in silica and wrapped in pectin gel. PMID:11963897
The Effect of Increasing Mass upon Locomotion
NASA Technical Reports Server (NTRS)
DeWitt, John; Hagan, Donald
2007-01-01
The purpose of this investigation was to determine if increasing body mass while maintaining bodyweight would affect ground reaction forces and joint kinetics during walking and running. It was hypothesized that performing gait with increased mass while maintaining body weight would result in greater ground reaction forces, and would affect the net joint torques and work at the ankle, knee and hip when compared to gait with normal mass and bodyweight. Vertical ground reaction force was measured for ten subjects (5M/5F) during walking (1.34 m/s) and running (3.13 m/s) on a treadmill. Subjects completed one minute of locomotion at normal mass and bodyweight and at four added mass (AM) conditions (10%, 20%, 30% and 40% of body mass) in random order. Three-dimensional joint position data were collected via videography. Walking and running were analyzed separately. The addition of mass resulted in several effects. Peak impact forces and loading rates increased during walking, but decreased during running. Peak propulsive forces decreased during walking and did not change during running. Stride time increased and hip extensor angular impulse and positive work increased as mass was added for both styles of locomotion. Work increased at a greater rate during running than walking. The adaptations to additional mass that occur during walking are different than during running. Increasing mass during exercise in microgravity may be beneficial to increasing ground reaction forces during walking and strengthening hip musculature during both walking and running. Future study in true microgravity is required to determine if the adaptations found would be similar in a weightless environment.
The dielectric friction effect under electrolyte transfer in an aquatic environment
NASA Astrophysics Data System (ADS)
Rozental, O. M.; Podkin, Yu. G.
2015-06-01
Natural and industrial waters commonly contain admixtures of electrolytes distributed irregularly in the system. It is shown that the resulting inner mass transfer within the volume or liquid layers is accompanied with the increment of the veritable part of the short-wave permittivity. The microsecond electric oscillators likely causing this effect belong to ion-molecular complexes destroyed under the attenuation of mass transfer but capable of occurring for a long time in a thixotropic medium. The discovered effect denoted as dielectric friction allows one to control the degree of completeness of the processes of mixing of electrolyte solutions at the sites of wastewater discharge, in riverine deltas, in mixing chambers, etc.
User`s manual for the FEHM application -- A finite-element heat- and mass-transfer code
Zyvoloski, G.A.; Robinson, B.A.; Dash, Z.V.; Trease, L.L.
1997-07-01
The use of this code is applicable to natural-state studies of geothermal systems and groundwater flow. A primary use of the FEHM application will be to assist in the understanding of flow fields and mass transport in the saturated and unsaturated zones below the proposed Yucca Mountain nuclear waste repository in Nevada. The equations of heat and mass transfer for multiphase flow in porous and permeable media are solved in the FEHM application by using the finite-element method. The permeability and porosity of the medium are allowed to depend on pressure and temperature. The code also has provisions for movable air and water phases and noncoupled tracers; that is, tracer solutions that do not affect the heat- and mass-transfer solutions. The tracers can be passive or reactive. The code can simulate two-dimensional, two-dimensional radial, or three-dimensional geometries. In fact, FEHM is capable of describing flow that is dominated in many areas by fracture and fault flow, including the inherently three-dimensional flow that results from permeation to and from faults and fractures. The code can handle coupled heat and mass-transfer effects, such as boiling, dryout, and condensation that can occur in the near-field region surrounding the potential repository and the natural convection that occurs through Yucca Mountain due to seasonal temperature changes. This report outlines the uses and capabilities of the FEHM application, initialization of code variables, restart procedures, and error processing. The report describes all the data files, the input data, including individual input records or parameters, and the various output files. The system interface is described, including the software environment and installation instructions.
Tauris; van Den Heuvel EP; Savonije
2000-02-20
We have performed detailed numerical calculations of the nonconservative evolution of close X-ray binary systems with intermediate-mass (2.0-6.0 M middle dot in circle) donor stars and a 1.3 M middle dot in circle accreting neutron star. We calculated the thermal response of the donor star to mass loss in order to determine its stability and follow the evolution of the mass transfer. Under the assumption of the "isotropic reemission model," we demonstrate that in many cases it is possible for the binary to prevent a spiral-in and survive a highly super-Eddington mass transfer phase (1
FEHMN 1.0: Finite element heat and mass transfer code; Revision 1
Zyvoloski, G.; Dash, Z.; Kelkar, S.
1992-05-01
A computer code is described which can simulate non-isothermal multi-phase multicomponent flow in porous media. It is applicable to natural-state studies of geothermal systems and groundwater flow. The equations of heat and mass transfer for multiphase flow in porous and permeable media are solved sing the finite element method. The permeability and porosity of the medium are allowed to depend on pressure and temperature. The code also has provisions for movable air and water phases and noncoupled tracers; that is, tracer solutions that do not affect the heat and mass transfer solutions. The tracers can be passive or reactive. The code can simulate two-dimensional, two-dimensional radial, or three-dimensional geometries. A summary of the equations in the model and the numerical solution procedure are provided in this report. A user`s guide and sample problems are also included. The FEHMN (Finite Element Heat and Mass Nuclear) code, described in this report, is a version of FEHM (Finite Element Heat and Mass, Zyvoloski et al., 1988) developed for the Yucca Mountain Site Characterization Project (YMP). The main use of FEHMN will be to assist in the understanding of flow fields in the saturated zone below the potential Yucca Mountain repository.
A Quantitative Study of S Cancri: An Algol Binary at the Terminal State of Mass Transfer
NASA Astrophysics Data System (ADS)
Polidan, Ronald S.
The Algol binary S Cnc is a 9.5 day totally eclipsing system with a very low mass (0.23M(sun)) K0III-IV secondary star. The system has an extensive archive of optical data, the analysis of which argues that this system has ceased mass transfer and that the secondary is now detached from its critical Roche lobe and has an "extended atmosphere" between its photosphere and Roche lobe. Existing low S/N IUE eclipse spectra show strong emission in C IV, Si IV, Mg II and other lines. The derived luminosities in these UV lines are an order of magnitude greater than the luminosities for the most chromospherically active single or binary stars. We propose to use low and high resolution IUE spectra to investigate S Cnc in order to derive a better understanding of the origins of the UV emission lines seen during eclipse and to define the geometrical properties and physical conditions in the gas giving rise to the extended atmosphere detected near eclipse in optical spectra. These new data will advance our understanding of the mass-transfer process in the late stages of close binary-star evolution and provide the first measures of the level of chromospheric activity in the low mass, Roche-lobe-filling secondary in this system.
Dynamical equation of the effective gluon mass
Aguilar, A. C.; Binosi, D.; Papavassiliou, J.
2011-10-15
In this article, we derive the integral equation that controls the momentum dependence of the effective gluon mass in the Landau gauge. This is accomplished by means of a well-defined separation of the corresponding ''one-loop dressed'' Schwinger-Dyson equation into two distinct contributions, one associated with the mass and one with the standard kinetic part of the gluon. The entire construction relies on the existence of a longitudinally coupled vertex of nonperturbative origin, which enforces gauge invariance in the presence of a dynamical mass. The specific structure of the resulting mass equation, supplemented by the additional requirement of a positive-definite gluon mass, imposes a rather stringent constraint on the derivative of the gluonic dressing function, which is comfortably satisfied by the large-volume lattice data for the gluon propagator, both for SU(2) and SU(3). The numerical treatment of the mass equation, under some simplifying assumptions, is presented for the aforementioned gauge groups, giving rise to a gluon mass that is a nonmonotonic function of the momentum. Various theoretical improvements and possible future directions are briefly discussed.
Vasudevan, M; Nambi, Indumathi M; Suresh Kumar, G
2016-06-15
Knowledge about distribution of dissolved plumes and their influencing factors is essential for risk assessment and remediation of light non-aqueous phase liquid contamination in groundwater. Present study deals with the applicability of numerical model for simulating various hydro-geological scenarios considering non-uniform source distribution at a petroleum contaminated site in Chennai, India. The complexity associated with the hydrogeology of the site has limited scope for on-site quantification of petroleum pipeline spillage. The change in fuel composition under mass-transfer limited conditions was predicted by simultaneously comparing deviations in aqueous concentrations and activity coefficients (between Raoult's law and analytical approaches). The effects of source migration and weathering on the dissolution of major soluble fractions of petroleum fuel were also studied in relation to the apparent change in their activity coefficients and molar fractions. The model results were compared with field observations and found that field conditions were favourable for biodegradation, especially for the aromatic fraction (benzene and toluene (nearly 95% removal), polycyclic aromatic hydrocarbons (up to 65% removal) and xylene (nearly 45% removal). The results help to differentiate the effect of compositional non-ideality from rate-limited dissolution towards tailing of less soluble compounds (alkanes and trimethylbenzene). Although the effect of non-ideality decreased with distance from the source, the assumption of spatially varying residual saturation could effectively illustrate post-spill scenario by estimating the consequent decrease in mass transfer rate. PMID:27017268
The Effect of Conceptual and Contextual Familiarity on Transfer Performance
ERIC Educational Resources Information Center
Kulasegaram, Kulamakan; Min, Cynthia; Ames, Kimberly; Howey, Elizabeth; Neville, Alan; Norman, Geoffrey
2012-01-01
Applying a previously learned concept to a novel problem is an important but difficult process called transfer. It is suggested that a commonsense analogy aids in transfer by linking novel concepts to familiar ones. How the context of practice affects transfer when learning using analogies is still unclear. This study investigated the effect of a…
NASA Technical Reports Server (NTRS)
Yuan, S. W. K.; Frederking, T. H. K.
1986-01-01
Newtonian fluid motion, coupled to heat transfer via latent heat of phase transition, is well known from numerous studies of condensation and boiling. Considerably less knowledge is available for vapor-liquid phase separation in the absence of gravity effect on the transport phenomena. The present studies are focused on heat and mass transfer associated with vapor-liquid phase separation required for long-term storage of the cryogen liquid He II in space vessels. Though space conditions are the dominant mode of interest in advanced equipment, e.g. IR telescopes, the systems may be operated in principle during terrestrial conditions. The latter are considered in the present work. It emphasizes the linear regime including an extrapolation based on variable thermophysical properties. Data taken with a phase separation approach show departures from the linear regime prediction. They agree with a transport equation proposed for the nonlinear, turbulent regime.
Fornstedt, T.; Zhong, G.; Bensetiti, Z.; Guiochon, G. |
1996-07-15
The thermodynamics and mass transfer kinetics of the retention of the R and S enantiomers of propranolol were investigated on a system comprising an acetic acid buffer solution as mobile phase and the protein cellobiohydrolase I immobilized on silica as the stationary phase. The bi-Langmuir isotherm model fitted best to each set of single-component isotherm data. The monolayer capacity of the nonchiral type of adsorption sites was 22.9 mM. For the chiral type of sites, it was 0.24 mM for the R enantiomer and 0.64 nM for the S enantiomer. Peak tailing was observed, even at very low concentrations allowing operation of the low-capacity chiral sites under linear conditions. This tailing can be explained on the basis of heterogeneous mass transfer kinetics. At higher concentrations, which are often used in analytical applications, the isotherms on the chiral sites no longer have a linear behavior, and peak tailing is consequently more pronounced. Under those conditions, peak tailing originates from the combined effect of heterogeneous thermodynamics and heterogeneous mass transfer kinetics. These complex phenomena are explained and modeled using the transport-dispersive model with a solid film linear driving force model modified to account for heterogeneous mass transfer kinetics. The rate coefficient of the mass transfer kinetics was found to be concentration dependent. 36 refs., 5 figs., 1 tab.
Conjugate heat and mass transfer in the lattice Boltzmann equation method
Li, LK; Chen, C; Mei, RW; Klausner, JF
2014-04-22
An interface treatment for conjugate heat and mass transfer in the lattice Boltzmann equation method is proposed based on our previously proposed second-order accurate Dirichlet and Neumann boundary schemes. The continuity of temperature (concentration) and its flux at the interface for heat (mass) transfer is intrinsically satisfied without iterative computations, and the interfacial temperature (concentration) and their fluxes are conveniently obtained from the microscopic distribution functions without finite-difference calculations. The present treatment takes into account the local geometry of the interface so that it can be directly applied to curved interface problems such as conjugate heat and mass transfer in porous media. For straight interfaces or curved interfaces with no tangential gradient, the coupling between the interfacial fluxes along the discrete lattice velocity directions is eliminated and thus the proposed interface schemes can be greatly simplified. Several numerical tests are conducted to verify the applicability and accuracy of the proposed conjugate interface treatment, including (i) steady convection-diffusion in a channel containing two different fluids, (ii) unsteady convection-diffusion in the channel, (iii) steady heat conduction inside a circular domain with two different solid materials, and (iv) unsteady mass transfer from a spherical droplet in an extensional creeping flow. The accuracy and order of convergence of the simulated interior temperature (concentration) field, the interfacial temperature (concentration), and heat (mass) flux are examined in detail and compared with those obtained from the "half-lattice division" treatment in the literature. The present analysis and numerical results show that the half-lattice division scheme is second-order accurate only when the interface is fixed at the center of the lattice links, while the present treatment preserves second-order accuracy for arbitrary link fractions. For curved
Ringer, Joachim M
2013-01-01
The chemical warfare agents (CWA) Sarin, Soman, Cyclosarin and Tabun were characterised by proton transfer mass spectrometry (PTRMS). It was found that PTRMS is a suitable technique to detect nerve agents highly sensitively, highly selectively and in near real-time. Methods were found to suppress molecule fragmentation which is significant under PTRMS hollow cathode ionisation conditions. In this context, the drift voltage (as one of the most important system parameters) was varied and ammonia was introduced as an additional chemical reagent gas. Auxiliary chemicals such as ammonia affect ionisation processes and are quite common in context with detectors for CWAs based on ion mobility spectrometry (IMS). With both, variation of drift voltage and ammonia as the reagent gas, fragmentation can be suppressed effectively. Suppression of fragmentation is crucial particularly concerning the implementation of an algorithm for automated agent identification in field applications. On the other hand, appearance of particular fragments might deliver additional information. Degradation and rearrangement products of nerve agents are not distinctive for the particular agent but for the chemical class they belong to. It was found that switching between ammonia doped and ordinary water ionisation chemistry can easily be performed within a few seconds. Making use of this effect it is possible to switch between fragment and molecular ion peak spectra. Thus, targeted fragmentation can be used to confirm identification based only on single peak detection. PTRMS turned out to be a promising technique for future CWA detectors. In terms of sensitivity, response time and selectivity (or confidence of identification, respectively) PTRMS performs as a bridging technique between IMS and GC-MS. PMID:24308198
IS WX CEN A POSSIBLE TYPE Ia SUPERNOVA PROGENITOR WITH WIND-DRIVEN MASS TRANSFER?
Qian, S.-B.; Shi, G.; Zhu, L.-Y.; Liu, L.; Zhao, E.-G.; Li, L.-J.; Fernandez Lajus, E.; Di Sisto, R. P.
2013-08-01
WX Cen is one of a few compact binary supersoft X-ray sources (CBSS) in the Galaxy that is a possible Type Ia supernova (SN Ia) progenitor. The supersoft X-ray radiation is explained as hydrostatic nuclear burning on the surface of the white dwarf component that is accreting hydrogen from a stellar companion at a high rate. If the mass donor in this system has a low mass, as has been suggested in the literature, one would expect a high wind-driven mass transfer rate. In that case, the orbital period of the system should increase. To test this theoretical prediction, we have monitored the system photometrically since 2010. By using four newly determined eclipse timings together with those collected from the literature, we discovered that the orbital period is decreasing at a rate of dP/dt = -5.15 Multiplication-Sign 10{sup -7} days yr{sup -1}. The long-term decrease in the orbital period is contrary to the prediction that the system is powered by wind-driven accretion. It therefore seems plausible that the mass donor could be more massive than the white dwarf, and that the mass transfer is driven by the thermal instability of the donor star. This finding suggests that WX Cen is a key object to check the physical mechanisms of mass accretion in CBSS. The corresponding timescale of the period change is about P/P-dot {approx} 0.81 x 10{sup 6} yr, indicating that WX Cen may evolve into an SNe Ia within one million years in the Galaxy.
Numerical simulation of mass transfer in the liquid phase of the bubble layer of a thermal deaerator
NASA Astrophysics Data System (ADS)
Laptev, A. G.; Misbakhov, R. Sh.; Lapteva, E. A.
2015-12-01
On the basis of one-dimensional diffusion model of the flow structure and boundary layer theory, a method for calculating the mass transfer of dissolved oxygen in the liquid phase of the bubble layer of a thermal deaerator is developed. Mass transfer with the bulk source of mass has been considered, wherein the basic parameter is mass-transfer coefficient. A model of pseudo laminar boundary layer on the bubble surface is proposed, and the possibility of calculating of mass-transfer coefficient from bubbles in the mass source of diffusion model is shown, taking into account the gas content and external turbulence. A comparison of the calculation results of mass-transfer coefficient is given from the bubbles with known experimental data. It is shown that taking into account gas content results in an increase of the mass-transfer coefficient by 2-4 times. Expressions for calculations of gas content, dynamic speed, and inverse stirring coefficient in the liquid phase of the bubble layer are presented. In the special case, transition from the diffusion model of the flow structure to cell model is made, and comparison of the calculation results on the concentration of oxygen in water at the output of DSA-300 bubbling thermal deaerator with experimental data is performed. The developed mathematical model and calculation algorithm can be used in the design, diagnosis, and modernization of thermal deaerators.
Local Mass Transfer Coefficient for Idealized 2D Urban Street Canyon Models
NASA Astrophysics Data System (ADS)
Leung, Ka Kit; Liu, Chun-Ho
2011-09-01
Human activities in urban areas is one of the major sources of anthropogenic releases in the atmospheric boundary layer (ABL). The mechanism of urban morphology for the heat and mass transfer in built environment is thus an attractive topic in the research community. In this paper, a series of laboratory measurements is conducted to elucidate the mass transfer from hypothetical urban roughness constructed by idealized 2D street canyons. The experiments are carried out in the wind tunnel in the University of Hong Kong. The urban ABL structure inside the wind tunnel is controlled by placing small cubic Styrofoam blocks upstream of the test section. The street canyons are fabricated by movable rectangular acrylic blocks so that different building height to street width (aspect) ratios are examined. The height of building blocks is kept minimum to make sure that the urban ABL over the street canyons is high enough for fully developed turbulent flows. The prevailing wind is normal to the street axis, demonstrating the scenario of least pollutant removal from the street canyons to the urban ABL. The sample street canyon is covered by soaked filter papers to represent uniform mass concentrations on the building facades and ground surface. The wet bulb temperature of the filter papers is continuously monitored to ensure saturated conditions. Their weight before and after an experiment is used to measure the amount of water evaporated. Preliminary results illustrate the local mass transfer coefficient distribution for aspect ratios 1/4, 1/2, 1, and 2, which are comparable with those available in literuatre.
NASA Astrophysics Data System (ADS)
Dervisoglu, Ahmet; Pavlovski, Kresimir; Kolbas, Vladimir; Southworth, John
2016-07-01
In the course of evolution of stars in close binary systems, mass transfer could happen due to limited space allowed for the expansion. An Algol type binary system would eventually be formed. As the consequence of the mass transfer, the layers which were originally deep in the star and have been altered by thermonuclear fusion during the star's main sequence evolution, are now exposed at the surfaces of the components. Thus, photospheric abundances give a precious way of diagnosing the nucleosynthesis processes that occurred deep in the stars. In this study, we present our previous results for u Her and ongoing analysis of δ Lib. A new set of high-resolution echelle spectra of u Her and δ Lib were obtained at CAHA, Spain. Spectral disentangling allows us to isolate the individual spectrum of the components for both systems. For both u Her and δ Lib systems, the detailed spectroscopic analysis of the primary component indicates a clear abundance pattern expected from the CNO process. Evolutionary scenario of the stars based on CAMBRIDGE version of STARS code in this systems and the effects of thermohaline mixing in the envelope of mass gainer stars will be discussed in the framework of this finding.
NASA Technical Reports Server (NTRS)
Mosher, Don R; Lad, Robert A
1954-01-01
An investigation was conducted using static capsules fabricated from "L" nickel tubing to determine the effect of temperature level, temperature gradient, and test duration on corrosion and mass transfer by molten sodium hydroxide under free-convection conditions. A base temperature range from 1000 degrees to 1600 degrees F with temperature differences to 500 degrees was studied. The rate of mass transfer was found to be strongly dependent on both temperature level and gradient. The rate shows little tendency to decrease for test durations up to 200 hours, although the concentration of nickel in the melt approaches a limited value after 100 hours.