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Sample records for mode iii effects

  1. Effects of friction and high torque on fatigue crack propagation in Mode III

    NASA Astrophysics Data System (ADS)

    Nayeb-Hashemi, H.; McClintock, F. A.; Ritchie, R. O.

    1982-12-01

    Turbo-generator and automotive shafts are often subjected to complex histories of high torques. To provide a basis for fatigue life estimation in such components, a study of fatigue crack propagation in Mode III (anti-plane shear) for a mill-annealed AISI 4140 steel (RB88, 590 MN/m2 tensile strength) has been undertaken, using torsionally-loaded, circumferentially-notched cylindrical specimens. As demonstrated previously for higher strength AISI 4340 steel, Mode III cyclic crack growth rates (dc/dN) IIIcan be related to the alternating stress intensity factor ΔKIII for conditions of small-scale yielding. However, to describe crack propagation behavior over an extended range of crack growth rates (˜10-6 to 10-2 mm per cycle), where crack growth proceeds under elastic-plastic and full plastic conditions, no correlation between (dc/dN) III and ΔKIII is possible. Accordingly, a new parameter for torsional crack growth, termed the plastic strain intensity Γ III, is introduced and is shown to provide a unique description of Mode III crack growth behavior for a wide range of testing conditions, provided a mean load reduces friction, abrasion, and interlocking between mating fracture surfaces. The latter effect is found to be dependent upon the mode of applied loading (i.e., the presence of superimposed axial loads) and the crack length and torque level. Mechanistically, high-torque surfaces were transverse, macroscopically flat, and smeared. Lower torques showed additional axial cracks (longitudinal shear cracking) perpendicular to the main transverse surface. A micro-mechanical model for the main radi l Mode III growth, based on the premise that crack advance results from Mode II coalescence of microcracks initiated at inclusions ahead of the main crack front, is extended to high nominal stress levels, and predicts that Mode III fatigue crack propagation rates should be proportional to the range of plastic strain intensity (ΔΓIII if local Mode II growth rates are

  2. Complexation of uranium(VI) and samarium(III) with oxydiacetic acid: temperature effect and coordination modes.

    PubMed

    Rao, Linfeng; Garnov, Alexander Yu; Jiang, Jun; Di Bernardo, Plinio; Zanonato, PierLuigi; Bismondo, Arturo

    2003-06-01

    The complexation of uranium(VI) and samarium(III) with oxydiacetate (ODA) in 1.05 mol kg(-1) NaClO(4) is studied at variable temperatures (25-70 degrees C). Three U(VI)/ODA complexes (UO(2)L, UO(2)L(2)(2-), and UO(2)HL(2)(-)) and three Sm(III)/ODA complexes (SmL(j)((3-2)(j)+) with j = 1, 2, 3) are identified in this temperature range. The formation constants and the molar enthalpies of complexation are determined by potentiometry and calorimetry. The complexation of uranium(VI) and samarium(III) with oxydiacetate becomes more endothermic at higher temperatures. However, the complexes become stronger due to increasingly more positive entropy of complexation at higher temperatures that exceeds the increase in the enthalpy of complexation. The values of the heat capacity of complexation (Delta C(p) degrees in J K(-1) mol(-1)) are 95 +/- 6, 297 +/- 14, and 162 +/- 19 for UO(2)L, UO(2)L(2)(2-), and UO(2)HL(2)(-), and 142 +/- 6, 198 +/- 14, and 157 +/- 19 for SmL(+), SmL(2)(-), and SmL(3)(3-), respectively. The thermodynamic parameters, in conjunction with the structural information from spectroscopy, help to identify the coordination modes in the uranium oxydiacetate complexes. The effect of temperature on the thermodynamics of the complexation is discussed in terms of the electrostatic model and the change in the solvent structure. PMID:12767209

  3. Mode III cleavage of a coin-shaped titanium implant in bone: effect of friction and crack propagation.

    PubMed

    Mathieu, Vincent; Vayron, Romain; Barthel, Etienne; Dalmas, Davy; Soffer, Emmanuel; Anagnostou, Fani; Haiat, Guillaume

    2012-04-01

    Endosseous cementless implants are widely used in orthopaedic, maxillofacial and oral surgery. However, failures are still observed and remain difficult to anticipate as remodelling phenomena at the bone-implant interface are poorly understood. The assessment of the biomechanical strength of the bone-implant interface may improve the understanding of the osseointegration process. An experimental approach based on a mode III cleavage mechanical device aims at understanding the behaviour of a planar bone-implant interface submitted to torsional loading. To do so, coin-shaped titanium implants were inserted on the tibiae of a New Zealand white rabbit for seven weeks. After the sacrifice, mode III cleavage experiments were performed on bone samples. An analytical model was developed to understand the debonding process of the bone-implant interface. The model allowed to assess the values of different parameters related to bone tissue at the vicinity of the implant with the additional assumption that bone adhesion occurs over around 70% of the implant surface, which is confirmed by microscopy images. The approach allows to estimate different quantities related to the bone-implant interface such as: torsional stiffness (around 20.5 N m rad(-1)), shear modulus (around 240 MPa), maximal torsional loading (around 0.056 N.m), mode III fracture energy (around 77.5 N m(-1)) and stress intensity factor (0.27 MPa m(1/2)). This study paves the way for the use of mode III cleavage testing for the investigation of torsional loading strength of the bone-implant interface, which might help for the development and optimization of implant biomaterial, surface treatment and medical treatment investigations. PMID:22402166

  4. Effects of mixed mode I/II loading and grain orientation on crack initiation and stable tearing in 2024-T3 aluminum

    SciTech Connect

    Amstutz, B.E.; Sutton, M.A.; Boone, M.L.; Dawicke, D.S.

    1997-12-01

    The effects of material grain orientation and mixed mode I/II loading on crack initiation and stable tearing in 2.3-mm-thick, unclad 2024-T3 aluminum is experimentally investigated. Mode I experiments were performed on center-cracked specimens with the crack being oriented at various angles relative to the rolling direction. Defining {theta} to be the angle between the normal to the initial crack plane and the loading direction, Mode I/II experiments were performed using an Arcan test fixture for 0{degree} {le} {theta} {le} 90{degree} [corresponding to 90{degree} {ge} {beta} {ge} 0{degree}, where {beta} = atan (K{sub II}/K{sub I})] with the crack oriented either along the rolling direction (T-L) or perpendicular to the rolling direction (L-T). Results indicate that: 1. The Mode I crack tip opening displacement (CTOD) is a strong function of the orientation of the crack relative to the rolling direction; CTOD for a T-L specimen is 0.84 mm, increasing linearly with orientation angle to 1.05 mm for an L-T case. 2. The Mode I/II CTOD increases rapidly during initial increments of crack growth and then decreases towards a constant value as crack growth continues. 3. For {theta} < 68{degree} ({beta} > 29{degree}), all cracks kinked and the Mode I/II plastic zones are similar to rotated Mode I plastic zones throughout the crack growth process. 4. J{sub II} = 0 reasonably predicts the direction of tension-dominated crack growth, but does not predict the transition to shear crack growth which occurs for {theta} {ge} 75{degree}. 5. K{sub II} {ge} K{sub I} for {theta} {approx} 58{degree} ({beta} = 45{degree}) does not quantitatively predict the transition to shear crack growth for {theta} {ge} 75{degree} ({beta} {le} 22{degree}), but does provide an indication of changing conditions in the crack tip region.

  5. Modeling Quantum and Coulomb Effects in Nanoscale Enhancement-Mode Tri-Gate III-V MOSFETs

    NASA Astrophysics Data System (ADS)

    Al-Sibiani, Sameer; Khair, Khadija; Ahmed, Shaikh

    2014-03-01

    Because of limited benefits of strain engineering in extremely scaled silicon devices and lack of demonstration of a performance gain at the product level with nanowires, nanotubes, graphene, and other exotic channel materials, there is a strong motivation to continue device scaling using high-transport III-V (such as InGaAs and InAsSb) channel materials beyond the year 2020. However, there are several challenges with III-V MOSFETs prohibiting their use in high-performance and low-power logic applications. In this work, we investigate the performance of the tri-gate III-V FETs as compared to the planar counterpart, and show how quantum size quantization and random dopant fluctuations (RDF) affect the tri-gate FET characteristics and how to curb these issues. A 3-D fully atomistic quantum-corrected Monte Carlo device simulator has been used in this work. Space-quantization effects have been accounted for via a parameter-free effective potential scheme (and benchmarked against the NEGF approach in the ballistic limit). To treat full Coulomb (electron-ion and electron-electron) interactions, the simulator implements a real-space corrected Coulomb electron dynamics (ED) scheme. Also, the essential bandstructure parameters (bandgap, effective masses, and the density-of-states) have been computed using a 20-band nearest-neighbour sp3d5s* tight-binding scheme.

  6. Adiabatic Survey of Subdwarf B Star Oscillations. III. Effects of Extreme Horizontal Branch Stellar Evolution on Pulsation Modes

    NASA Astrophysics Data System (ADS)

    Charpinet, S.; Fontaine, G.; Brassard, P.; Dorman, Ben

    2002-06-01

    We present the final results of a large, systematic survey of the adiabatic oscillation properties of models of subdwarf B (sdB) stars. This survey is aimed at providing the minimal theoretical background with which to understand the asteroseismological characteristics of the recently discovered class of pulsating sdB stars (the EC 14026 objects). In this paper, the last of a series of three, we consider the effects of stellar evolution on the pulsation eigenmodes of sdB star models. We specifically analyze the adiabatic properties of 149 equilibrium models culled from seven distinct extreme horizontal branch evolutionary sequences. Those have been chosen in order to span fully the region of parameter space where real sdB stars are found. We primarily focus on the evolution of the pulsation periods (P) and the rates of period change (dP/dt), which are both a priori observable quantities. Both the acoustic and gravity branches of stellar oscillations are considered. In light of the results derived in the first two papers of this series, we discuss how the values of P and dP/dt relate to the various structural adjustments that sdB stars undergo during evolution. We find that the acoustic modes react primarily to the secular variations of the surface gravity. In contrast, we identify three main factors that regulate the period evolution of gravity modes: these are the variations brought about by evolution in both the surface gravity and the effective temperature, as well as the onset and growth of a chemical discontinuity between the C-O-enriched nucleus and the helium-rich mantle. We also find, as expected from our previous results, that the period evolution of the pulsation modes in sdB stars is further complicated by trapping effects (microtrapping in the case of p-modes) and by avoided crossings between modes. The latter occur preferentially in certain regions of parameter space. We provide our final results in the form of extensive tabular data in the appendices

  7. Comparison of fatigue crack propagation in Modes I and III

    SciTech Connect

    Ritchie, R.O.

    1985-06-01

    The propagation behavior of fatigue cracks in Mode III (anti-plane shear), measured under cyclic torsion, is described and compared with more commonly encountered behavior under Mode I (tensile opening) loads. It is shown that a unique, global characterization of Mode III growth rates, akin to the Paris ''law'' in Mode I, is only possible if characterizating parameters appropriate to large-scale yielding are employed and allowance is made for crack tip shielding from sliding crack surface interference (i.e., friction and abrasion) between mating fracture surfaces. Based on the crack tip stress and deformation fields for Mode III stationary cracks, the cyclic crack tip displacement, (..delta..CTD/sub III/, and plastic strain intensity range ..delta..GAMMA/sub III/, have been proposed and are found to provide an adequate description of behavior in a range of steels, provided crack surface interference is minimized. The magnitude of this interference, which is somewhat analogous to crack closure in Mode I, is further examined in the light of the complex fractography of torsional fatigue failures and the question of a ''fatigue threshold'' for Mode III crack growth. Finally, micro-mechanical models for cyclic crack extension in anti-plane shear are briefly described, and the contrasting behavior between Mode III and Mode I cracks subjected to simple variable amplitude spectra is examined in terms of the differing role of crack tip blunting and closure in influencing shear, as opposed to tensile opening, modes of crack growth.

  8. Mode III fatigue crack propagation in low alloy steel

    NASA Astrophysics Data System (ADS)

    Ritchie, R. O.; McClintock, F. A.; Nayeb-Hashemi, H.; Ritter, M. A.

    1982-01-01

    To provide a basis for estimating fatigue life in large rotating generator shafts subjected to transient oscillations, a study is made of fatigue crack propagation in Mode III (anti-plane shear) in torsionally-loaded spheroidized AISI4340 steel, and results compared to analogous behavior in Mode I. Torsional S/N curves, determined on smooth bars containing surface defects, showed results surprisingly close to expected unnotched Mode I data, with lifetime increasing from 104 cycles at nominal yield to 106 cycles at half yield. Fatigue crack growth rates in Mode III, measured on circumferentially-notched samples, were found to be slower than in Mode I, although still power-law related to the alternating stress intensity (△K III) for small-scale yielding. Mode III growth rates were only a small fraction (0.002 to 0.0005) of cyclic crack tip displacements (△CTD III) per cycle, in contrast to Mode I where the fraction was much larger (0.1 to 0.01). A micromechanical model for Mode III growth is proposed, where crack advance is considered to take place by a Mode II coalescence of cracks, initiated at inclusions ahead of the main crack front. This mechanism is consistent with the crack increment being a small fraction of △CTDIII per cycle.

  9. Combined mode I-mode III fracture toughness of a particulate reinforced metal-matrix composite

    NASA Technical Reports Server (NTRS)

    Manoharan, M.; Lewandowski, J. J.

    1991-01-01

    The aim of this investigation was to determine the fracture behavior of a particulate reinfored aluminum alloy composite under combined mode I-mode III loading conditions. A modified three-point bend specimen was used to carry out these tests. It was found that the mode I loading condition was energetically most favorable. Addition of mode III components to the system seems to increase the amount of redundant work during fracture without affecting the critical fracture criterion.

  10. Mode III fatigue crack propagation in low alloy steel

    SciTech Connect

    Ritchie, R.O.; McClintock, F.A.; Nayeb-Hashemi, H.; Ritter, M.A.

    1982-01-01

    To provide a basis for estimating fatigue life in large rotating generator shafts subjected to transient oscillations, a study is made of fatigue crack propagation in Mode III (anti-plane shear) in torsionally-loaded spheroidized AISI 4340 steel. Results are compared to analogous behavior in Mode I. The approach investigated the feasibility of using continuum fracture mechanics and preliminary mechanistic modeling to serve as a basis for defect-tolerant life estimation procedures. 38 refs.

  11. Complexation of Curium(III) with DTPA at 10–70 °C: Comparison with Eu(III)–DTPA in Thermodynamics, Luminescence, and Coordination Modes

    SciTech Connect

    Tian, Guoxin; Zhang, Zhiyong; Martin, Leigh R.; Rao, Linfeng

    2015-02-16

    Separation of trivalent actinides (An(III)) from trivalent lanthanides (Ln(III)) is a challenging task because of their nearly identical chemical properties. Diethylenetriaminepentaacetate (DTPA), a key reagent used in the TALSPEAK process that effectively separates An(III) from Ln(III), is believed to play a critical role in the An(III)/Ln(III) separation. However, the underlying principles for the separation based on the difference in the complexation of DTPA with An(III) and Ln(III) remain unclear. In this work, the complexation of DTPA with Cm(III) at 10-70 ºC was investigated by spectrophotometry, luminescence spectroscopy, and microcalorimetry, in conjunction with computational methods. The binding strength, the enthalpy of complexation, the coordination modes, and the luminescence properties are compared between the Cm(III)-DTPA and Eu(III)-DTPA systems. The experimental and computational data have demonstrated that the difference between Cm(III) and Eu(III) in the binding strength with DTPA can be attributed to the stronger covalence bonding between Cm(III) and the nitrogen donors of DTPA.

  12. Is the Pharmacological Mode of Action of Chromium(III) as a Second Messenger?

    PubMed

    Vincent, John B

    2015-07-01

    Although recent studies have shown that chromium (as the trivalent ion) is not an essential trace element, it has been demonstrated to generate beneficial effects at pharmacologically relevant doses on insulin sensitivity and cholesterol levels of rodent models of insulin insensitivity, including models of type 2 diabetes. The mode of action of Cr(III) at a molecular level is still an area of active debate; however, the movement of Cr(III) in the body, particularly in response to changes in insulin concentration, suggests that Cr(III) could act as a second messenger, amplifying insulin signaling. The evidence for the pharmacological mechanism of Cr(III)'s ability to increase insulin sensitivity by acting as a second messenger is reviewed, and proposals for testing this hypothesis are described. PMID:25595680

  13. III-nitride tunable cup-cavities supporting quasi whispering gallery modes from ultraviolet to infrared

    NASA Astrophysics Data System (ADS)

    Shubina, T. V.; Pozina, G.; Jmerik, V. N.; Davydov, V. Yu.; Hemmingsson, C.; Andrianov, A. V.; Kazanov, D. R.; Ivanov, S. V.

    2015-12-01

    Rapidly developing nanophotonics needs microresonators for different spectral ranges, formed by chip-compatible technologies. In addition, the tunable ones are much in demand. Here, we present site-controlled III-nitride monocrystal cup-cavities grown by molecular beam epitaxy. The cup-cavities can operate from ultraviolet to near-infrared, supporting quasi whispering gallery modes up to room temperature. Besides, their energies are identical in large ’ripened’ crystals. In these cavities, the refractive index variation near an absorption edge causes the remarkable effect of mode switching, which is accompanied by the spatial redistribution of electric field intensity with concentration of light into a subwavelength volume. Our results shed light on the mode behavior in semiconductor cavities and open the way for single-growth-run manufacturing the devices comprising an active region and a cavity with tunable mode frequencies.

  14. III-nitride tunable cup-cavities supporting quasi whispering gallery modes from ultraviolet to infrared

    PubMed Central

    Shubina, T. V.; Pozina, G.; Jmerik, V. N.; Davydov, V. Yu.; Hemmingsson, C.; Andrianov, A. V.; Kazanov, D. R.; Ivanov, S. V.

    2015-01-01

    Rapidly developing nanophotonics needs microresonators for different spectral ranges, formed by chip-compatible technologies. In addition, the tunable ones are much in demand. Here, we present site-controlled III-nitride monocrystal cup-cavities grown by molecular beam epitaxy. The cup-cavities can operate from ultraviolet to near-infrared, supporting quasi whispering gallery modes up to room temperature. Besides, their energies are identical in large ’ripened’ crystals. In these cavities, the refractive index variation near an absorption edge causes the remarkable effect of mode switching, which is accompanied by the spatial redistribution of electric field intensity with concentration of light into a subwavelength volume. Our results shed light on the mode behavior in semiconductor cavities and open the way for single-growth-run manufacturing the devices comprising an active region and a cavity with tunable mode frequencies. PMID:26656267

  15. Analysis of mode III crack perpendicular to the interface between two dissimilar strips

    NASA Astrophysics Data System (ADS)

    Matbuly, M. S.

    2008-08-01

    The present work is concerned with the problem of mode III crack perpendicular to the interface of a bi-strip composite. One of these strips is made of a functionally graded material and the other of an isotropic material, which contains an edge crack perpendicular to and terminating at the interface. Fourier transforms and asymptotic analysis are employed to reduce the problem to a singular integral equation which is numerically solved using Gauss-Chebyshev quadrature formulae. Furthermore, a parametric study is carried out to investigate the effects of elastic and geometric characteristics of the composite on the values of stress intensity factor.

  16. III-V-on-silicon anti-colliding pulse-type mode-locked laser.

    PubMed

    Keyvaninia, S; Uvin, S; Tassaert, M; Wang, Z; Fu, X; Latkowski, S; Marien, J; Thomassen, L; Lelarge, F; Duan, G; Lepage, G; Verheyen, P; Van Campenhout, J; Bente, E; Roelkens, G

    2015-07-01

    An anti-colliding pulse-type III-V-on-silicon passively mode-locked laser is presented for the first time based on a III-V-on-silicon distributed Bragg reflector as outcoupling mirror implemented partially underneath the III-V saturable absorber. Passive mode-locking at 4.83 GHz repetition rate generating 3 ps pulses is demonstrated. The generated fundamental RF tone shows a 1.7 kHz 3 dB linewidth. Over 9 mW waveguide coupled output power is demonstrated. PMID:26125366

  17. Subcritical crack growth under mode I, II, and III loading for Coconino sandstone

    NASA Astrophysics Data System (ADS)

    Ko, Tae Young

    In systems subjected to long-term loading, subcritical crack growth is the principal mechanism causing the time-dependent deformation and failure of rocks. Subcritical crack growth is environmentally-assisted crack growth, which can allow cracks to grow over a long period of time at stresses far smaller than their failure strength and at tectonic strain rates. The characteristics of subcritical crack growth can be described by a relationship between the stress intensity factor and the crack velocity. This study presents the results of studies conducted to validate the constant stress-rate test for determining subcritical crack growth parameters in Coconino sandstone, compared with the conventional testing method, the double torsion test. The results of the constant stress-rate test are in good agreement with the results of double torsion test. More importantly, the stress-rate tests can determine the parameter A with a much smaller standard deviation than the double torsion test. Thus the constant stress-rate test seems to be both a valid and preferred test method for determining the subcritical crack growth parameters in rocks. We investigated statistical aspects of the constant stress-rate test. The effects of the number of tests conducted on the subcritical crack growth parameters were examined and minimum specimen numbers were determined. The mean and standard deviation of the subcritical crack growth parameters were obtained by randomly selecting subsets from the original strength data. In addition, the distribution form of the subcritical crack growth parameters and the relation between the parameter n and A were determined. We extended the constant stress-rate test technique to modes II and III subcritical crack growth in rocks. The experimental results of the modes I, II and III tests show that the values of the subcritical crack growth parameters are similar to each other. The subcritical crack growth parameter n value for Coconino sandstone has the range

  18. Helicon modes in uniform plasmas. III. Angular momentum

    SciTech Connect

    Stenzel, R. L.; Urrutia, J. M.

    2015-09-15

    Helicons are electromagnetic waves with helical phase fronts propagating in the whistler mode in magnetized plasmas and solids. They have similar properties to electromagnetic waves with angular momentum in free space. Helicons are circularly polarized waves carrying spin angular momentum and orbital angular momentum due to their propagation around the ambient magnetic field B{sub 0}. These properties have not been considered in the community of researchers working on helicon plasma sources, but are the topic of the present work. The present work focuses on the field topology of helicons in unbounded plasmas, not on helicon source physics. Helicons are excited in a large uniform laboratory plasma with a magnetic loop antenna whose dipole axis is aligned along or across B{sub 0}. The wave fields are measured in orthogonal planes and extended to three dimensions (3D) by interpolation. Since density and B{sub 0} are uniform, small amplitude waves from loops at different locations can be superimposed to generate complex antenna patterns. With a circular array of phase shifted loops, whistler modes with angular and axial wave propagation, i.e., helicons, are generated. Without boundaries radial propagation also arises. The azimuthal mode number m can be positive or negative while the field polarization remains right-hand circular. The conservation of energy and momentum implies that these field quantities are transferred to matter which causes damping or reflection. Wave-particle interactions with fast electrons are possible by Doppler shifted resonances. The transverse Doppler shift is demonstrated. Wave-wave interactions are also shown by showing collisions between different helicons. Whistler turbulence does not always have to be created by nonlinear wave-interactions but can also be a linear superposition of waves from random sources. In helicon collisions, the linear and/or orbital angular momenta can be canceled, which results in a great variety of field

  19. Helicon modes in uniform plasmas. III. Angular momentum

    NASA Astrophysics Data System (ADS)

    Stenzel, R. L.; Urrutia, J. M.

    2015-09-01

    Helicons are electromagnetic waves with helical phase fronts propagating in the whistler mode in magnetized plasmas and solids. They have similar properties to electromagnetic waves with angular momentum in free space. Helicons are circularly polarized waves carrying spin angular momentum and orbital angular momentum due to their propagation around the ambient magnetic field B0. These properties have not been considered in the community of researchers working on helicon plasma sources, but are the topic of the present work. The present work focuses on the field topology of helicons in unbounded plasmas, not on helicon source physics. Helicons are excited in a large uniform laboratory plasma with a magnetic loop antenna whose dipole axis is aligned along or across B0. The wave fields are measured in orthogonal planes and extended to three dimensions (3D) by interpolation. Since density and B0 are uniform, small amplitude waves from loops at different locations can be superimposed to generate complex antenna patterns. With a circular array of phase shifted loops, whistler modes with angular and axial wave propagation, i.e., helicons, are generated. Without boundaries radial propagation also arises. The azimuthal mode number m can be positive or negative while the field polarization remains right-hand circular. The conservation of energy and momentum implies that these field quantities are transferred to matter which causes damping or reflection. Wave-particle interactions with fast electrons are possible by Doppler shifted resonances. The transverse Doppler shift is demonstrated. Wave-wave interactions are also shown by showing collisions between different helicons. Whistler turbulence does not always have to be created by nonlinear wave-interactions but can also be a linear superposition of waves from random sources. In helicon collisions, the linear and/or orbital angular momenta can be canceled, which results in a great variety of field topologies. The work will

  20. Comparison of Mode II and III Monotonic and Fatigue Delamination Onset Behavior for Carbon/Toughened Epoxy Composites

    NASA Technical Reports Server (NTRS)

    Li, Jian; OBrien, T. Kevin; Lee, Shaw Ming

    1997-01-01

    Monotonic and fatigue tests were performed to compare the Mode II and III interlaminar fracture toughness and fatigue delamination onset for Tenax-HTA/R6376 carbon/toughened epoxy composites. The Mode II interlaminar fracture toughness and fatigue delamination onset were characterized using the end-notched flexure (ENF) test while the Mode III interlaminar fracture toughness and fatigue delamination onset were characterized by using the edge crack torsion (ECT) test. Monotonic tests show that the Mode III fracture toughness is higher than the Mode II fracture toughness. Both Mode II and III cyclic loading greatly increases the tendency for a delamination to grow relative to a single monotonically increasing load. Under fatigue loading, the Mode III specimen also has a longer life than the Mode II specimen.

  1. Out-of-plane deviation of a mode I+III crack encountering a tougher obstacle

    NASA Astrophysics Data System (ADS)

    Leblond, Jean-Baptiste; Ponson, Laurent

    2016-07-01

    One possible explanation of out-of-plane deviations of cracks loaded in mode I+III was suggested by Gao and Rice in 1986. These authors noted that small in-plane undulations of the crack front, arising from fluctuations of the fracture toughness, should generate a small local mode-II component, causing the crack to depart from planarity. Their analysis is completed here by explicitly calculating the evolution in time of the out-of-plane deviation of a mode-I+III crack encountering a tougher obstacle. The calculation is based on (i) first-order formulae for the stress intensity factors of a crack slightly perturbed within and out of its plane; and (ii) a "double" propagation criterion combining a Griffith condition on the local energy-release rate and a Goldstein-Salganik condition on the local stress intensity factor of mode II. It is predicted that the crack must evolve toward a stationary state, wherein the orthogonal distance from the average fracture plane to the perturbed crack front is constant outside the obstacle and varies linearly across it. We hope that this theoretical prediction will encourage comparison with experiments, and propose a fracture test involving propagation of a mode-I+III crack through a 3D-printed specimen containing some designed obstacle. xml:lang="fr"

  2. The effective degeneracy of protein normal modes

    NASA Astrophysics Data System (ADS)

    Na, Hyuntae; Song, Guang

    2016-06-01

    Normal modes are frequently computed and used to portray protein dynamics and interpret protein conformational changes. In this work, we investigate the nature of normal modes and find that the normal modes of proteins, especially those at the low frequency range (0–600 cm‑1), are highly susceptible to degeneracy. Two or more modes are degenerate if they have the same frequency and consequently any orthogonal transformation of them also is a valid representation of the mode subspace. Thus, degenerate modes can no longer characterize unique directions of motions as regular modes do. Though the normal modes of proteins are usually of different frequencies, the difference in frequency between neighboring modes is so small that, under even slight structural uncertainty that unavoidably exists in structure determination, it can easily vanish and as a result, a mode becomes effectively degenerate with its neighboring modes. This can be easily observed in that some modes seem to disappear and their matching modes cannot be found when the structure used to compute the modes is modified only slightly. We term this degeneracy the effective degeneracy of normal modes. This work is built upon our recent discovery that the vibrational spectrum of globular proteins is universal. The high density of modes observed in the vibrational frequency spectra of proteins renders their normal modes highly susceptible to degeneracy, under even the smallest structural uncertainty. Indeed, we find the degree of degeneracy of modes is proportional to the density of modes in the vibrational spectrum. This means that for modes at the same frequency, degeneracy is more severe for larger proteins. Degeneracy exists also in the modes of coarse-grained models, but to a much lesser extent than those of all-atom models. In closing, we discuss the implications of the effective degeneracy of normal modes: how it may significantly affect the ways in which normal modes are used in various normal modes

  3. The effective degeneracy of protein normal modes.

    PubMed

    Na, Hyuntae; Song, Guang

    2016-01-01

    Normal modes are frequently computed and used to portray protein dynamics and interpret protein conformational changes. In this work, we investigate the nature of normal modes and find that the normal modes of proteins, especially those at the low frequency range (0-600 cm(-1)), are highly susceptible to degeneracy. Two or more modes are degenerate if they have the same frequency and consequently any orthogonal transformation of them also is a valid representation of the mode subspace. Thus, degenerate modes can no longer characterize unique directions of motions as regular modes do. Though the normal modes of proteins are usually of different frequencies, the difference in frequency between neighboring modes is so small that, under even slight structural uncertainty that unavoidably exists in structure determination, it can easily vanish and as a result, a mode becomes effectively degenerate with its neighboring modes. This can be easily observed in that some modes seem to disappear and their matching modes cannot be found when the structure used to compute the modes is modified only slightly. We term this degeneracy the effective degeneracy of normal modes. This work is built upon our recent discovery that the vibrational spectrum of globular proteins is universal. The high density of modes observed in the vibrational frequency spectra of proteins renders their normal modes highly susceptible to degeneracy, under even the smallest structural uncertainty. Indeed, we find the degree of degeneracy of modes is proportional to the density of modes in the vibrational spectrum. This means that for modes at the same frequency, degeneracy is more severe for larger proteins. Degeneracy exists also in the modes of coarse-grained models, but to a much lesser extent than those of all-atom models. In closing, we discuss the implications of the effective degeneracy of normal modes: how it may significantly affect the ways in which normal modes are used in various normal modes

  4. Mixed mode stress field effect in adhesive fracture

    NASA Technical Reports Server (NTRS)

    Anderson, G. P.; Devries, K. L.; Williams, M. L.

    1974-01-01

    Numerical or analytical analyses were performed on seven different test specimens including blister test, 90-degree peel test, torsion test, and various cone tests. These specimens are in general subjected to complex stress fields having various amounts of Mode I, Mode II, and Mode III loads. The specimens were then constructed using polymethyl methacrylate for the adherends and a transparent polyurethane elastomer (Solithane 113) for the adhesive. This combination permitted direct observation of the bondline as load was applied. Although initial debonds as well as bond end termination singularities were present in all specimens, in some cases the debond did not initiate at the singularity points as would normally have been expected. An explanation for this behavior is presented, as well as a comparison of loading mode effect on those specimens for which the debond did propagate from a bond terminus singular point.

  5. Multiple nucleic acid cleavage modes in divergent type III CRISPR systems

    PubMed Central

    Zhang, Jing; Graham, Shirley; Tello, Agnes; Liu, Huanting; White, Malcolm F.

    2016-01-01

    CRISPR-Cas is an RNA-guided adaptive immune system that protects bacteria and archaea from invading nucleic acids. Type III systems (Cmr, Csm) have been shown to cleave RNA targets in vitro and some are capable of transcription-dependent DNA targeting. The crenarchaeon Sulfolobus solfataricus has two divergent subtypes of the type III system (Sso-IIID and a Cmr7-containing variant of Sso-IIIB). Here, we report that both the Sso-IIID and Sso-IIIB complexes cleave cognate RNA targets with a ruler mechanism and 6 or 12 nt spacing that relates to the organization of the Cas7 backbone. This backbone-mediated cleavage activity thus appears universal for the type III systems. The Sso-IIIB complex is also known to possess a distinct ‘UA’ cleavage mode. The predominant activity observed in vitro depends on the relative molar concentration of protein and target RNA. The Sso-IIID complex can cleave plasmid DNA targets in vitro, generating linear DNA products with an activity that is dependent on both the cyclase and HD nuclease domains of the Cas10 subunit, suggesting a role for both nuclease active sites in the degradation of double-stranded DNA targets. PMID:26801642

  6. Cryogenic Interlaminar Fracture Properties of Woven Glass/Epoxy Composite Laminates Under Mixed-Mode I/III Loading Conditions

    NASA Astrophysics Data System (ADS)

    Miura, Masaya; Shindo, Yasuhide; Takeda, Tomo; Narita, Fumio

    2013-08-01

    We characterize the combined Mode I and Mode III delamination fracture behavior of woven glass fiber reinforced polymer (GFRP) composite laminates at cryogenic temperatures. The eight-point bending plate (8PBP) tests were conducted at room temperature, liquid nitrogen temperature (77 K) and liquid helium temperature (4 K) using a new test fixture. A three-dimensional finite element analysis was also performed to calculate the energy release rate distribution along the delamination front, and the delamination fracture toughnesses were evaluated for various mixed-mode I/III ratios. Furthermore, the microscopic examinations of the fracture surfaces were carried out with scanning electron microscopy (SEM), and the mixed-mode I/III delamination fracture mechanisms in the woven GFRP laminates at cryogenic temperatures were assessed. The fracture properties were then correlated with the observed characteristics.

  7. Characterization of the Edge Crack Torsion (ECT) Test for Mode III Fracture Toughness Measurement of Laminated Composites

    NASA Technical Reports Server (NTRS)

    Ratcliffe, James G.

    2004-01-01

    The edge crack torsion (ECT) test is designed to initiate mode III delamination growth in composite laminates. An ECT specimen is a rectangular laminate, containing an edge delamination at the laminate mid-plane. Torsion load is applied to the specimens, resulting in relative transverse shear sliding of the delaminated faces. The test data reduction schemes are intended to yield initiation values of critical mode III strain energy release rate, G(sub IIIc), that are constant with delamination length. The test has undergone several design changes during its development. The objective of this paper was to determine the suitability of the current ECT test design as a mode III fracture test. To this end, ECT tests were conducted on specimens manufactured from IM7/8552 and specimens made from S2/8552 tape laminates. Several specimens, each with different delamination lengths are tested. Detailed, three-dimensional finite element analyses of the specimens were performed. The analysis results were used to calculate the distribution of mode I, mode II, and mode III strain energy release rate along the delamination front. The results indicated that mode III-dominated delamination growth would be initiated from the specimen center. However, in specimens of both material types, the measured values of G(sub IIIc) exhibited significant dependence on delamination length. Furthermore, there was a large amount of scatter in the data. Load-displacement response of the specimens exhibited significant deviation from linearity before specimen failure. X-radiographs of a sample of specimens revealed that damage was initiated in the specimens prior to failure. Further inspection of the failure surfaces is required to identify the damage and determine that mode III delamination is initiated in the specimens.

  8. Dependence of mode I and mixed mode I/III fracture toughness on temperature for a ferritic/martensitic stainless steel

    SciTech Connect

    Li, H.; Jones, R.H.; Gelles, D.S.

    1995-04-01

    The objective is to investigate the dependence of mode I and mixed mode I/III fracture toughness on temperature in the range of {minus}95{degrees}C to 25{degrees}C for a low activation ferritic/martensitic stainless steel (F82-H). Mode I and mixed Mode I/III fracture toughnesses were investigated in the range of {minus}95 to 25{degree}C for a F82-H steel heat-treated in the following way; 1000{degree}C/20 h/air-cooled (AC), 1100{degree}C/7 min/AC, and 700{degree}C/2 h/AC. The results indicate that crack tip plasticity was increased by mixed mode loading, and suggest that at low temperature, mode I fracture toughness is the critical design parameter, but at temperatures above room temperature, expecially concerning fatigure and creep-fatigue crack growth rate, a mixed mode loading may be more harmful than a mode I loading for this steel because a mixed mode loading results in lower fracture toughness and higher crack tip plasticity (or dislocation activity).

  9. Characterization of the Edge Crack Torsion (ECT) Test for Mode III Fracture Toughness Measurement of Laminated Composites

    NASA Technical Reports Server (NTRS)

    Ratcliffe, James G.

    2004-01-01

    The edge crack torsion (ECT) test is designed to initiate mode III delamination growth in composite laminates. The test has undergone several design changes during its development. The objective of this paper was to determine the suitability of the current ECT test design a mode III fracture test. To this end, ECT tests were conducted on specimens manufactured from IM7/8552 and S2/8552 tape laminates. Three-dimensional finite element analyses were performed. The analysis results were used to calculate the distribution of mode I, mode II, and mode III strain energy release rate along the delamination front. The results indicated that mode IIIdominated delamination growth would be initiated from the specimen center. However, in specimens of both material types, the measured values of GIIIc exhibited significant dependence on delamination length. Load-displacement response of the specimens exhibited significant deviation from linearity before specimen failure. X-radiographs of a sample of specimens revealed that damage was initiated in the specimens prior to failure. Further inspection of the failure surfaces is required to identify the damage and determine that mode III delamination is initiated in the specimens.

  10. A comparison of pure mode I and mixed mode I-III cracking of an adhesive containing an open knit cloth carrier

    NASA Technical Reports Server (NTRS)

    Ripling, E. J.; Crosley, P. B.; Johnson, W. S.

    1988-01-01

    Static and fatigue tests were carried out on two commercial modified epoxy film adhesives with a wide open knit polyester carrier in order to compare crack resistance in mode I and mixed mode I-III loading. The carrier cloth is found to have a significant influence on the cracking behavior of the adhesives. The open air net carrier used in this study separates from the adhesive in mode I cracking but shreds during mixed-mode crack extension. This decreases the opening mode toughness but increases the mixed-mode toughness as compared with results obtained earlier using a heavier knit carrier. The results suggest that the type of carrier may have a far larger influence on crack resistance than is generally recognized.

  11. Collisionless microinstabilities in stellarators. III. The ion-temperature-gradient mode

    SciTech Connect

    Plunk, G. G. Helander, P.; Xanthopoulos, P.

    2014-03-15

    We investigate the linear theory of the ion-temperature-gradient (ITG) mode, with the goal of developing a general understanding that may be applied to stellarators. We highlight the Wendelstein 7X (W7-X) device. Simple fluid and kinetic models that follow closely from existing literature are reviewed and two new first-principle models are presented and compared with results from direct numerical simulation. One model investigates the effect of regions of strong localized shear, which are generic to stellarator equilibria. These “shear spikes” are found to have a potentially significant stabilizing affect on the mode; however, the effect is strongest at short wavelengths perpendicular to the magnetic field, and it is found to be significant only for the fastest growing modes in W7-X. A second model investigates the long-wavelength limit for the case of negligible global magnetic shear. The analytic calculation reveals that the effect of the curvature drive enters at second order in the drift frequency, confirming conventional wisdom that the ITG mode is slab-like at long wavelengths. Using flux tube simulations of a zero-shear W7-X configuration, we observe a close relationship to an axisymmetric configuration at a similar parameter point. It is concluded that scale lengths of the equilibrium gradients constitute a good parameter space to characterize the ITG mode. Thus, to optimize the magnetic geometry for ITG mode stability, it may be fruitful to focus on local parameters, such as the magnitude of bad curvature, connection length, and local shear at locations of bad curvature (where the ITG mode amplitude peaks)

  12. Hybrid H-mode scenario with nitrogen seeding and type III ELMs in JET

    NASA Astrophysics Data System (ADS)

    Corre, Y.; Joffrin, E.; Monier-Garbet, P.; Andrew, Y.; Arnoux, G.; Beurskens, M.; Brezinsek, S.; Brix, M.; Buttery, R.; Coffey, I.; Crombe, K.; de La Luna, E.; Felton, R.; Giroud, C.; Hacquin, S.; Hobirk, J.; Huber, A.; Imbeaux, F.; Jachmich, S.; Kempenaars, M.; Litaudon, X.; Leggate, H.; Loarer, T.; Maddison, G.; Rachlew, E.; Rapp, J.; Sauter, O.; Savchkov, A.; Telesca, G.; Widdowson, A.; Zastrow, K. D.; Zimmermann, O.; collaborators, JET-EFDA

    2008-11-01

    The performance of the 'hybrid' H-mode regime (long pulse operation with high neutron fluency) has been extensively investigated in JET during the 2005-2007 experimental campaign up to normalized pressure βN = 3, toroidal magnetic field Bt = 1.7 T, with type I ELMs plasma edge conditions. The optimized external current drive sources, self-generated non-inductive bootstrap current and plasma core stability properties provide a good prospect of achieving a high fusion gain at reduced plasma current for long durations in ITER. One of the remaining issues is the erosion of the divertor target plates associated with the type I ELM regime. A possible solution could be to operate with a plasma edge in the type III ELM regime (reduced transient and stationary heat loads) obtained with impurity seeding. An integrated hybrid type III ELM regime with a normalized pressure βN = 2.6 (PNBI ~ 20-22 MW) and a thermal confinement factor of H_{98}^\\ast (y,2)\\sim 0.83 has been recently successfully developed on JET with nitrogen seeding. This scenario shows good plasma edge condition (compatible with the future ITER-like wall on JET) and moderate MHD activity. In this paper, we report on the experimental development of the scenario (with plasma current Ip = 1.7 MA and magnetic field Bt = 1.7 T) and the trade-off between heat load reduction at the target plates and global confinement due to nitrogen seeding and type III ELM working conditions.

  13. Mode Transitions in Hall Effect Thrusters

    NASA Technical Reports Server (NTRS)

    Sekerak, Michael J.; Longmier, Benjamin W.; Gallimore, Alec D.; Brown, Daniel L.; Hofer, Richard R.; Polk, James E.

    2013-01-01

    Mode transitions have been commonly observed in Hall Effect Thruster (HET) operation where a small change in a thruster operating parameter such as discharge voltage, magnetic field or mass flow rate causes the thruster discharge current mean value and oscillation amplitude to increase significantly. Mode transitions in a 6-kW-class HET called the H6 are induced by varying the magnetic field intensity while holding all other operating parameters constant and measurements are acquired with ion saturation probes and ultra-fast imaging. Global and local oscillation modes are identified. In the global mode, the entire discharge channel oscillates in unison and azimuthal perturbations (spokes) are either absent or negligible. Downstream azimuthally spaced probes show no signal delay between each other and are very well correlated to the discharge current signal. In the local mode, signals from the azimuthally spaced probes exhibit a clear delay indicating the passage of "spokes" and are not well correlated to the discharge current. These spokes are localized oscillations propagating in the ExB direction that are typically 10-20% of the mean value. In contrast, the oscillations in the global mode can be 100% of the mean value. The transition between global and local modes occurs at higher relative magnetic field strengths for higher mass flow rates or higher discharge voltages. The thrust is constant through mode transition but the thrust-to-power decreased by 25% due to increasing discharge current. The plume shows significant differences between modes with the global mode significantly brighter in the channel and the near-field plasma plume as well as exhibiting a luminous spike on thruster centerline. Mode transitions provide valuable insight to thruster operation and suggest improved methods for thruster performance characterization.

  14. Energetic particle effects on global MHD modes

    SciTech Connect

    Cheng, C.Z.

    1990-01-01

    The effects of energetic particles on MHD type modes are studied by analytical theories and the nonvariational kinetic-MHD stability code (NOVA-K). In particular we address the problems of (1) the stabilization of ideal MHD internal kink modes and the excitation of resonant fishbone'' internal modes and (2) the alpha particle destabilization of toroidicity-induced Alfven eigenmodes (TAE) via transit resonances. Analytical theories are presented to help explain the NOVA-K results. For energetic trapped particles generated by neutral-beam injection (NBI) or ion cyclotron resonant heating (ICRH), a stability window for the n=1 internal kink mode in the hot particle beat space exists even in the absence of core ion finite Larmor radius effect (finite {omega}{sub *i}). On the other hand, the trapped alpha particles are found to resonantly excite instability of the n=1 internal mode and can lower the critical beta threshold. The circulating alpha particles can strongly destabilize TAE modes via inverse Landau damping associated with the spatial gradient of the alpha particle pressure. 23 refs., 5 figs.

  15. A Mixed-Mode (I-II) Fracture Criterion for AS4/8552 Carbon/Epoxy Composite Laminate

    NASA Astrophysics Data System (ADS)

    Karnati, Sidharth Reddy

    A majority of aerospace structures are subjected to bending and stretching loads that introduce peel and shear stresses between the plies of a composite laminate. These two stress components cause a combination of mode I and II fracture modes in the matrix layer of the composite laminate. The most common failure mode in laminated composites is delamination that affects the structural integrity of composite structures. Damage tolerant designs of structures require two types of materials data: mixed-mode (I-II) delamination fracture toughness that predicts failure and delamination growth rate that predicts the life of the structural component. This research focuses determining mixed-mode (I-II) fracture toughness under a combination of mode I and mode II stress states and then a fracture criterion for AS4/8552 composite laminate, which is widely used in general aviation. The AS4/8552 prepreg was supplied by Hexcel Corporation and autoclave fabricated into a 20-ply unidirectional laminate with an artificial delamination by a Fluorinated Ethylene Propylene (FEP) film at the mid-plane. Standard split beam specimens were prepared and tested in double cantilever beam (DCB) and end notched flexure modes to determine mode I (GIC) and II (GIIC) fracture toughnesses, respectively. The DCB specimens were also tested in a modified mixed-mode bending apparatus at GIIm /GT ratios of 0.18, 0.37, 0.57 and 0.78, where GT is total and GIIm is the mode II component of energy release rates. The measured fracture toughness, GC, was found to follow the locus a power law equation. The equation was validated for the present and literature experimental data.

  16. A plane stress finite element model for elastic-plastic mode I/II crack growth

    NASA Astrophysics Data System (ADS)

    James, Mark Anthony

    A finite element program has been developed to perform quasi-static, elastic-plastic crack growth simulations. The model provides a general framework for mixed-mode I/II elastic-plastic fracture analysis using small strain assumptions and plane stress, plane strain, and axisymmetric finite elements. Cracks are modeled explicitly in the mesh. As the cracks propagate, automatic remeshing algorithms delete the mesh local to the crack tip, extend the crack, and build a new mesh around the new tip. State variable mapping algorithms transfer stresses and displacements from the old mesh to the new mesh. The von Mises material model is implemented in the context of a non-linear Newton solution scheme. The fracture criterion is the critical crack tip opening displacement, and crack direction is predicted by the maximum tensile stress criterion at the crack tip. The implementation can accommodate multiple curving and interacting cracks. An additional fracture algorithm based on nodal release can be used to simulate fracture along a horizontal plane of symmetry. A core of plane strain elements can be used with the nodal release algorithm to simulate the triaxial state of stress near the crack tip. Verification and validation studies compare analysis results with experimental data and published three-dimensional analysis results. Fracture predictions using nodal release for compact tension, middle-crack tension, and multi-site damage test specimens produced accurate results for residual strength and link-up loads. Curving crack predictions using remeshing/mapping were compared with experimental data for an Arcan mixed-mode specimen. Loading angles from 0 degrees to 90 degrees were analyzed. The maximum tensile stress criterion was able to predict the crack direction and path for all loading angles in which the material failed in tension. Residual strength was also accurately predicted for these cases.

  17. Electrically driven hybrid Si/III-V Fabry-Pérot lasers based on adiabatic mode transformers.

    PubMed

    Ben Bakir, B; Descos, A; Olivier, N; Bordel, D; Grosse, P; Augendre, E; Fulbert, L; Fedeli, J M

    2011-05-23

    We report the first demonstration of an electrically driven hybrid silicon/III-V laser based on adiabatic mode transformers. The hybrid structure is formed by two vertically superimposed waveguides separated by a 100-nm-thick SiO2 layer. The top waveguide, fabricated in an InP/InGaAsP-based heterostructure, serves to provide optical gain. The bottom Si-waveguides system, which supports all optical functions, is constituted by two tapered rib-waveguides (mode transformers), two distributed Bragg reflectors (DBRs) and a surface-grating coupler. The supermodes of this hybrid structure are controlled by an appropriate design of the tapers located at the edges of the gain region. In the middle part of the device almost all the field resides in the III-V waveguide so that the optical mode experiences maximal gain, while in regions near the III-V facets, mode transformers ensure an efficient transfer of the power flow towards Si-waveguides. The investigated device operates under quasi-continuous wave regime. The room temperature threshold current is 100 mA, the side-mode suppression ratio is as high as 20 dB, and the fiber-coupled output power is ~7 mW. PMID:21643289

  18. Electromagnetic effects on geodesic acoustic modes

    SciTech Connect

    Bashir, M. F.; Smolyakov, A. I.; Elfimov, A. G.; Melnikov, A. V.; Murtaza, G.

    2014-08-15

    By using the full electromagnetic drift kinetic equations for electrons and ions, the general dispersion relation for geodesic acoustic modes (GAMs) is derived incorporating the electromagnetic effects. It is shown that m = 1 harmonic of the GAM mode has a finite electromagnetic component. The electromagnetic corrections appear for finite values of the radial wave numbers and modify the GAM frequency. The effects of plasma pressure β{sub e}, the safety factor q, and the temperature ratio τ on GAM dispersion are analyzed.

  19. The equilibrium concentration of hydrogen atoms ahead of a mixed mode I-mode III crack tip in single crystal iron

    SciTech Connect

    Zhang, T.Y.; Hack, J.E.

    1999-01-01

    Calculations of the equilibrium hydrogen concentration profiles about a mixed ode I-mode III crack in single crystal iron were performed. Both material anisotropy and the tetragonal nature of the distortion induced in the iron crystal structure by interstitial hydrogen were incorporated. Results show that, unlike the case of a spherical distortion, a strong coupling exists between the strain field of the interstitial hydrogen and the stress field of the crack for orientations of the crack plane that are not coincident with the cube axes of the lattice. As a result, the predicated enhancement of hydrogen in the crack tip region increases with increasing levels of mode III loading for those orientations. The results may help reconcile conflicting observations concerning the potential role of shear stresses in hydrogen embrittlement and preferential cracking of grains ahead of loaded crack tips in sustained load cracking experiments.

  20. A streamlined failure mode and effects analysis

    SciTech Connect

    Ford, Eric C. Smith, Koren; Terezakis, Stephanie; Croog, Victoria; Gollamudi, Smitha; Gage, Irene; Keck, Jordie; DeWeese, Theodore; Sibley, Greg

    2014-06-15

    Purpose: Explore the feasibility and impact of a streamlined failure mode and effects analysis (FMEA) using a structured process that is designed to minimize staff effort. Methods: FMEA for the external beam process was conducted at an affiliate radiation oncology center that treats approximately 60 patients per day. A structured FMEA process was developed which included clearly defined roles and goals for each phase. A core group of seven people was identified and a facilitator was chosen to lead the effort. Failure modes were identified and scored according to the FMEA formalism. A risk priority number,RPN, was calculated and used to rank failure modes. Failure modes with RPN > 150 received safety improvement interventions. Staff effort was carefully tracked throughout the project. Results: Fifty-two failure modes were identified, 22 collected during meetings, and 30 from take-home worksheets. The four top-ranked failure modes were: delay in film check, missing pacemaker protocol/consent, critical structures not contoured, and pregnant patient simulated without the team's knowledge of the pregnancy. These four failure modes hadRPN > 150 and received safety interventions. The FMEA was completed in one month in four 1-h meetings. A total of 55 staff hours were required and, additionally, 20 h by the facilitator. Conclusions: Streamlined FMEA provides a means of accomplishing a relatively large-scale analysis with modest effort. One potential value of FMEA is that it potentially provides a means of measuring the impact of quality improvement efforts through a reduction in risk scores. Future study of this possibility is needed.

  1. An assessment of BWR (boiling water reactor) Mark III containment challenges, failure modes, and potential improvements in performance

    SciTech Connect

    Schroeder, J.A.; Pafford, D.J.; Kelly, D.L.; Jones, K.R.; Dallman, F.J. )

    1991-01-01

    This report describes risk-significant challenges posed to Mark III containment systems by severe accidents as identified for Grand Gulf. Design similarities and differences between the Mark III plants that are important to containment performance are summarized. The accident sequences responsible for the challenges and the postulated containment failure modes associated with each challenge are identified and described. Improvements are discussed that have the potential either to prevent or delay containment failure, or to mitigate the offsite consequences of a fission product release. For each of these potential improvements, a qualitative analysis is provided. A limited quantitative risk analysis is provided for selected potential improvements. 21 refs., 5 figs., 46 tabs.

  2. Mode I and mixed I/III crack initiation and propagation behavior of V-4Cr-4Ti alloy at 25{degrees}C

    SciTech Connect

    Li, H.X.; Kurtz, R.J.; Jones, R.H.

    1997-04-01

    The mode I and mixed-mode I/III fracture behavior of the production-scale heat (No. 832665) of V-4Cr-4Ti has been investigated at 25{degrees}C using compact tension (CT) specimens for a mode I crack and modified CT specimens for a mixed-mode I/III crack. The mode III to mode I load ratio was 0.47. Test specimens were vacuum annealed at 1000{degrees}C for 1 h after final machining. Both mode I and mixed-mode I/III specimens were fatigue cracked prior to J-integral testing. It was noticed that the mixed-mode I/III crack angle decreased from an initial 25 degrees to approximately 23 degrees due to crack plane rotation during fatigue cracking. No crack plane rotation occurred in the mode I specimen. The crack initiation and propagation behavior was evaluated by generating J-R curves. Due to the high ductility of this alloy and the limited specimen thickness (6.35 mm), plane strain requirements were not met so valid critical J-integral values were not obtained. However, it was found that the crack initiation and propagation behavior was significantly different between the mode I and the mixed-mode I/III specimens. In the mode I specimen crack initiation did not occur, only extensive crack tip blunting due to plastic deformation. During J-integral testing the mixed-mode crack rotated to an increased crack angle (in contrast to fatigue precracking) by crack blunting. When the crack initiated, the crack angle was about 30 degrees. After crack initiation the crack plane remained at 30 degrees until the test was completed. Mixed-mode crack initiation was difficult, but propagation was easy. The fracture surface of the mixed-mode specimen was characterized by microvoid coalescence.

  3. Electroelastic effect of thickness mode langasite resonators.

    PubMed

    Zhang, Haifeng; Turner, Joseph A; Yang, Jiashi; Kosinski, John A

    2007-10-01

    Langasite is a very promising material for resonators due to its good temperature behavior and high piezoelectric coupling, low acoustic loss, and high Q factor. The biasing effect for langasite resonators is crucial for resonator design. In this article, the resonant frequency shift of a thickness-mode langasite resonator is analyzed with respect to a direct current (DC) electric field applied in the thickness direction. The vibration modes of a thin langasite plate fully coated with an electrode are analyzed. The analysis is based on the theory for small fields superposed on a bias in electroelastic bodies and the first-order perturbation integral theory. The electroelastic effect of the resonator is analyzed by both analytical and finite-element methods. The complete set of nonlinear elastic, piezoelectric, dielectric permeability, and electrostrictive constants of langasite is used in the theoretical and numerical analysis. The sensitivity of electroelastic effect to nonlinear material constants is analyzed. PMID:18019250

  4. Effective plasmonic mode-size converter.

    PubMed

    Park, Hae-Ryeong; Park, Jong-Moon; Kim, Min-su; Ju, Jung Jin; Son, Jung-Han; Lee, Myung-Hyun

    2011-10-24

    Plasmonic mode-size converters (PMSCs) for long-range surface plasmon polaritons (LR-SPPs) at the wavelength of 1.55 μm are presented. The PMSC is composed of an insulator-metal-insulator waveguide (IMI-W), a laterally tapered insulator-metal-insulator-metal-insulator waveguide (LT-IMIMI-W), and an IMIMI-W in series. The mode-intensity sizes of the LR-SPPs for the IMI-W and the IMIMI-W were not only calculated using a finite element method but were also experimentally measured. The propagation losses of the IMI-W and the IMIMI-W as well as the coupling losses between them were analyzed by the cut-back method to investigate the effect of LT-IMIMI-Ws. By using the PMSC with a ~27 ° angled LT-IMIMI-W, the coupling loss between a polarization-maintaining fiber and a 3 μm-wide IMIMI-W was reduced by ~3.4 dB. Moreover, the resulting mode-intensity in the output of the PMSC was squeezed to ~35% of the mode-intensity in the input IMI-W. The PMSC may be potentially useful for bridging micro- to nano-plasmonic integrated circuits. PMID:22109009

  5. Characterization of the apoLp-III/LPS complex: insight in the mode of binding interaction

    PubMed Central

    Oztug, Merve; Martinon, Daisy; Weers, Paul M.M.

    2012-01-01

    Apolipoproteins are able to associate with lipopolysaccharides (LPS), potentially providing protection against septic shock. To gain insight in the molecular details of this binding interaction, apolipophorin III (apoLp-III) from Galleria mellonella was used as a model. The binding of apoLp-III to LPS was optimal around 37–40 °C, close to the LPS phase transition temperature. ApoLp-III formed complexes with LPS from E. coli (serotype O55:B5) with a diameter of 24 nm, a molecular weight of ~390 kDa, containing four molecules of apoLp-III and 24 molecules of LPS. The LPS-bound form of the protein was substantially more resistant to guanidine-induced denaturation compared to unbound protein. The denaturation profile displayed a multiphase character with a steep drop in secondary structure between 0–1 M guanidine, and a slower decrease above 1 M guanidine HCl. In contrast, apoLp-III bound to detoxified LPS was only slightly more resistant to guanidine HCl induced denaturation compared to unbound protein. Analysis of size-exclusion FPLC elution profiles of mixtures of apoLp-III with LPS or detoxified LPS indicated a much weaker binding interaction with detoxified LPS compared to intact LPS. These results indicate that apoLp-III initially interacts with exposed carbohydrate regions, but that the lipid A region is required for a more stable LPS binding interaction. PMID:22779761

  6. Period-Luminosity relations derived from the OGLE-III first-overtone mode Cepheids in the Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Bhardwaj, Anupam; Ngeow, Chow-Choong; Kanbur, Shashi M.; Singh, Harinder P.

    2016-06-01

    We present multiband Period-Luminosity (PL) relations for first-overtone mode Cepheids in the Small Magellanic Cloud (SMC). We derive optical band PL relations and the Wesenheit function using VI mean magnitudes from the Optical Gravitational Lensing Experiment (OGLE-III) survey. We cross-match OGLE-III first-overtone mode Cepheids to the 2MASS and SAGE-SMC catalogues to derive PL relations at near-infrared (JHKs) and mid-infrared (3.6 and 4.5 μm) wavelengths. We test for possible non-linearities in these PL relations using robust statistical tests and find a significant break only in the optical band PL relations at 2.5 d for first-overtone mode Cepheids. We do not find statistical evidence for a non-linearity in these PL relations at 1 d. The multiband PL relations for fundamental-mode Cepheids in the SMC also exhibit a break at 2.5 d. We suggest that the period break around 2.5 d is related to sharp changes in the light-curve parameters for SMC Cepheids. We also derive new optical and mid-infrared band PL relations for first-overtone mode Cepheids in the Large Magellanic Cloud (LMC). We compare multiband PL relations for first-overtone mode Cepheids in the Magellanic Clouds and find a significant difference in the slope of the V-band PL relations but not for I-band PL relations. The slope of PL relations are found to be consistent in most of the infrared bands. A relative distance modulus of Δμ = 0.49 ± 0.02 mag between the two clouds is estimated using multiband PL relations for the first-overtone mode Cepheids in the SMC and LMC.

  7. Failure modes and effects analysis automation

    NASA Technical Reports Server (NTRS)

    Kamhieh, Cynthia H.; Cutts, Dannie E.; Purves, R. Byron

    1988-01-01

    A failure modes and effects analysis (FMEA) assistant was implemented as a knowledge based system and will be used during design of the Space Station to aid engineers in performing the complex task of tracking failures throughout the entire design effort. The three major directions in which automation was pursued were the clerical components of the FMEA process, the knowledge acquisition aspects of FMEA, and the failure propagation/analysis portions of the FMEA task. The system is accessible to design, safety, and reliability engineers at single user workstations and, although not designed to replace conventional FMEA, it is expected to decrease by many man years the time required to perform the analysis.

  8. Blockade of HERG channels by the class III antiarrhythmic azimilide: mode of action

    PubMed Central

    Busch, A E; Eigenberger, B; Jurkiewicz, N K; Salata, J J; Pica, A; Suessbrich, H; Lang, F

    1998-01-01

    The class III antiarrhythmic azimilide has previously been shown to inhibit IKs and IKr in guinea-pig cardiac myocytes and IKs (minK) channels expressed in Xenopus oocytes. Because HERG channels underly the conductance IKr in human heart, the effects of azimilide on HERG channels expressed in Xenopus oocytes were the focus of the present study.In contrast to other well characterized HERG channel blockers, azimilide blockade was reverse use-dependent, i.e., the relative block and apparent affinity of azimilide decreased with an increase in channel activation frequency. Azimilide blocked HERG channels at 0.1 and 1 Hz with IC50 s of 1.4 μM and 5.2  μM respectively.In an envelope of tail test, HERG channel blockade increased with increasing channel activation, indicating binding of azimilide to open channels.Azimilide blockade of HERG channels expressed in Xenopus oocytes and IKr in mouse AT-1 cells was decreased under conditions of high [K+]e, whereas block of slowly activating IKs channels was not affected by changes in [K+]e.In summary, azimilide is a blocker of cardiac delayed rectifier channels, IKs and HERG. Because of the distinct effects of stimulation frequency and [K+]e on azimilide block of IKr and IKs channels, we conclude that the relative contribution of block of each of these cardiac delayed rectifier channels depends on heart frequency. [K+]e and regulatory status of the respective channels. PMID:9484850

  9. Failure-Modes-And-Effects Analysis Of Software Logic

    NASA Technical Reports Server (NTRS)

    Garcia, Danny; Hartline, Thomas; Minor, Terry; Statum, David; Vice, David

    1996-01-01

    Rigorous analysis applied early in design effort. Method of identifying potential inadequacies and modes and effects of failures caused by inadequacies (failure-modes-and-effects analysis or "FMEA" for short) devised for application to software logic.

  10. Evaluation of the split cantilever beam for mode III delamination testing

    NASA Technical Reports Server (NTRS)

    Martin, Roderick, H.

    1991-01-01

    A test rig for testing a thick split cantilever beam for scissoring delamination (mode 3) fracture toughness was developed. A 3-D finite element analysis was conducted on the test specimen to determine the strain energy release rate, G, distribution along the delamination front. The virtual crack closure technique was used to calculate the G components resulting from interlaminar tension, GI, interlaminar sliding shear, GII, and interlaminar tearing shear, GIII. The finite element analysis showed that at the delamination front no GI component existed, but a GII component was present in addition to a GIII component. Furthermore, near the free edges, the GII component was significantly higher than the GIII component. The GII/GIII ratio was found to increase with delamination length but was insensitive to the beam depth. The presence of GII at the delamination front was verified experimentally by examination of the failure surfaces. At the center of the beam, where the failure was in mode 3, there was significant fiber bridging. However, at the edges of the beam where the failure was in mode 3, there was no fiber bridging and mode 2 shear hackles were observed. Therefore, it was concluded that the split cantilever beam configuration does not represent a pure mode 3 test. The experimental work showed that the mode 2 fracture toughness, GIIc, must be less than the mode 3 fracture toughness, GIIIc. Therefore, a conservative approach to characterizing mode 3 delamination is to equate GIIIc to GIIc.

  11. A Mixed-Mode I/II Fracture Criterion and Its Application in Crack Growth Predictions

    NASA Technical Reports Server (NTRS)

    Sutton, Michael A.; Deng, Xiaomin; Ma, Fashang; Newman, James S., Jr.

    1999-01-01

    A crack tip opening displacement (CTOD)-based, mixed mode fracture criterion is developed for predicting the onset and direction of crack growth. The criterion postulates that crack growth occurs in either the Mode I or Mode II direction, depending on whether the maximum in either the opening or the shear component of CTOD, measured at a specified distance behind the crack tip, attains a critical value. For crack growth direction prediction, the proposed CTOD criterion is shown to be equivalent to seven commonly used crack growth criteria under linearly elastic and asymptotic conditions. Under elastic-plastic conditions the CTOD criterion's prediction of the dependence of the crack growth direction on the crack-up mode mixity is in excellent agreement with the Arcan test results. Furthermore, the CTOD criterion correctly predicts the existence of a crack growth transition from mode I to mode II as the mode mixity approaches the mode II loading condition. The proposed CTOD criterion has been implemented in finite element crack growth simulation codes Z1P2DL and FRANC2DL to predict the crack growth paths in (a) a modified Arcan test specimen and fixture made of AL 2024-T34 and (b) a double cantilever beam (DCB) specimen made of AL 7050. A series of crack growth simulations have been carried out for the crack growth tests in the Arcan and DCB specimens and the results further demonstrate the applicability of the mixed mode CTOD fracture criterion crack growth predictions and residual strength analyses for airframe materials.

  12. The Fundamental Solutions for the Stress Intensity Factors of Modes I, II And III. The Axially Symmetric Problem

    NASA Astrophysics Data System (ADS)

    Rogowski, B.

    2015-05-01

    The subject of the paper are Green's functions for the stress intensity factors of modes I, II and III. Green's functions are defined as a solution to the problem of an elastic, transversely isotropic solid with a penny-shaped or an external crack under general axisymmetric loadings acting along a circumference on the plane parallel to the crack plane. Exact solutions are presented in a closed form for the stress intensity factors under each type of axisymmetric ring forces as fundamental solutions. Numerical examples are employed and conclusions which can be utilized in engineering practice are formulated.

  13. (-)-Carvone: antispasmodic effect and mode of action.

    PubMed

    Souza, Fábia Valéria M; da Rocha, Marcelly Barbosa; de Souza, Damião P; Marçal, Rosilene Moretti

    2013-03-01

    (-)-Carvone is a monoterpene ketone found in spearmint (Mentha spicata var. crispa) essential oil that is widely used as an odor and flavor additive. An intestinal antispasmodic effect was recently reported for (-)-carvone, and it has been shown to be more potent than its (+)-antipode. The mechanism of (-)-carvone action in the intestines has not been investigated. To gain a better understanding of the (-)-carvone antispasmodic effect, we investigated its pharmacological effects in the guinea pig ileum. Terminal portions of the ileum were mounted for isotonic contraction recordings. The effect of (-)-carvone was compared with that of the classical calcium channel blocker (CCB) verapamil. In isolated ileal smooth muscle, (-)-carvone did not produce direct contractile or relaxation responses and did not modify electrically elicited contractions or low K(+)-evoked contractions. The submaximal contractions induced by histamine (p<0.001), BaCl2 (p<0.05), and carbachol (p<0.01) were significantly reduced by (-)-carvone. The contractile response elicited by high concentrations of carbachol was reduced but not abolished by (-)-carvone. No additive action was detected with co-incubation of (-)-carvone and verapamil on carbachol-induced contraction. (-)-Carvone reduced the contraction induced by high K(+) and was almost 100 times more potent than verapamil. Thus, (-)-carvone showed a typical and potent CCB-like action. Many effects described for both (-)-carvone and spearmint oil can be explained as a CCB-like mode of action. PMID:23103297

  14. Drift effects on electromagnetic geodesic acoustic modes

    SciTech Connect

    Sgalla, R. J. F.

    2015-02-15

    A two fluid model with parallel viscosity is employed to derive the dispersion relation for electromagnetic geodesic acoustic modes (GAMs) in the presence of drift (diamagnetic) effects. Concerning the influence of the electron dynamics on the high frequency GAM, it is shown that the frequency of the electromagnetic GAM is independent of the equilibrium parallel current but, in contrast with purely electrostatic GAMs, significantly depends on the electron temperature gradient. The electromagnetic GAM may explain the discrepancy between the f ∼ 40 kHz oscillation observed in tokamak TCABR [Yu. K. Kuznetsov et al., Nucl. Fusion 52, 063044 (2012)] and the former prediction for the electrostatic GAM frequency. The radial wave length associated with this oscillation, estimated presently from this analytical model, is λ{sub r} ∼ 25 cm, i.e., an order of magnitude higher than the usual value for zonal flows (ZFs)

  15. Drift effects on electromagnetic geodesic acoustic modes

    NASA Astrophysics Data System (ADS)

    Sgalla, R. J. F.

    2015-02-01

    A two fluid model with parallel viscosity is employed to derive the dispersion relation for electromagnetic geodesic acoustic modes (GAMs) in the presence of drift (diamagnetic) effects. Concerning the influence of the electron dynamics on the high frequency GAM, it is shown that the frequency of the electromagnetic GAM is independent of the equilibrium parallel current but, in contrast with purely electrostatic GAMs, significantly depends on the electron temperature gradient. The electromagnetic GAM may explain the discrepancy between the f ˜ 40 kHz oscillation observed in tokamak TCABR [Yu. K. Kuznetsov et al., Nucl. Fusion 52, 063044 (2012)] and the former prediction for the electrostatic GAM frequency. The radial wave length associated with this oscillation, estimated presently from this analytical model, is λr ˜ 25 cm, i.e., an order of magnitude higher than the usual value for zonal flows (ZFs).

  16. Fatigue delamination growth in woven glass/epoxy composite laminates under mixed-mode II/III loading conditions at cryogenic temperatures

    NASA Astrophysics Data System (ADS)

    Takeda, Tomo; Miura, Masaya; Shindo, Yasuhide; Narita, Fumio

    2013-12-01

    We investigate the cryogenic delamination growth behavior in woven glass fiber reinforced polymer (GFRP) composite laminates under mixed-mode II/III fatigue loading. Fatigue delamination tests were conducted with six-point bending plate (6PBP) specimens at room temperature, liquid nitrogen temperature (77 K) and liquid helium temperature (4 K), and the delamination growth rate data for various mixed-mode ratios of Modes II and III were obtained. The energy release rate was evaluated using the three-dimensional finite element method. In addition, the fatigue delamination growth mechanisms were characterized by scanning electron microscopic observations of the specimen fracture surfaces.

  17. 25 CFR 291.15 - How long do Class III gaming procedures remain in effect?

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false How long do Class III gaming procedures remain in effect... ENTERPRISES CLASS III GAMING PROCEDURES § 291.15 How long do Class III gaming procedures remain in effect? Class III gaming procedures remain in effect for the duration specified in the procedures or...

  18. Effects of Jigsaw III Technique on Achievement in Written Expression

    ERIC Educational Resources Information Center

    Sahin, Abdullah

    2011-01-01

    The objective of this paper is to compare the Jigsaw III technique (of cooperative learning) with the instructional teacher-centered teaching method in six graders in terms of the effect of written expression on their academic success. The universe of the study consists of 71 sixth-grade students studying during 2009-2010 academic term in a…

  19. Electron cyclotron maser emission mode coupling to the z-mode on a longitudinal density gradient in the context of solar type III bursts

    SciTech Connect

    Pechhacker, R.; Tsiklauri, D.

    2012-11-15

    A beam of super-thermal, hot electrons was injected into maxwellian plasma with a density gradient along a magnetic field line. 1.5D particle-in-cell simulations were carried out which established that the EM emission is produced by the perpendicular component of the beam injection momentum. The beam has a positive slope in the distribution function in perpendicular momentum phase space, which is the characteristic feature of a cyclotron maser. The cyclotron maser in the overdense plasma generates emission at the electron cyclotron frequency. The frequencies of generated waves were too low to propagate away from the injection region, hence the wavelet transform shows a pulsating wave generation and decay process. The intensity pulsation frequency is twice the relativistic cyclotron frequency. Eventually, a stable wave packet formed and could mode couple on the density gradient to reach frequencies of the order of the plasma frequency that allowed for propagation. The emitted wave is likely to be a z-mode wave. The total electromagnetic energy generated is of the order of 0.1% of the initial beam kinetic energy. The proposed mechanism is of relevance to solar type III radio bursts, as well as other situations, when the injected electron beam has a non-zero perpendicular momentum, e.g., magnetron.

  20. Mode Contributions to the Casimir Effect

    NASA Astrophysics Data System (ADS)

    Intravaia, F.; Henkel, C.

    2010-04-01

    Applying a sum-over-modes approach to the Casimir interaction between two plates with finite conductivity, we isolate and study the contributions of surface plasmons and Foucault (eddy current) modes. We show in particular that for the TE-polarization eddy currents provide a repulsive force that cancels, at high temperatures, the Casimir free energy calculated with the plasma model.

  1. Achirality in the low temperature structure and lattice modes of tris(acetylacetonate)iron(iii).

    PubMed

    Ellis, Thomas K; Kearley, Gordon J; Piltz, Ross O; Jayasooriya, Upali A; Stride, John A

    2016-05-10

    Tris(acetylacteonate) iron(iii) is a relatively ubiquitous mononuclear inorganic coordination complex. The bidentate nature of the three acetylacteonate ligands coordinating around a single centre inevitably leads to structural isomeric forms, however whether or not this relates to chirality in the solid state has been questioned in the literature. Variable temperature neutron diffraction data down to T = 3 K, highlights the dynamic nature of the ligand environment, including the motions of the hydrogen atoms. The Fourier transform of the molecular dynamics simulation based on the experimentally determined structure was shown to closely reproduce the low temperature vibrational density of states obtained using inelastic neutron scattering. PMID:27109447

  2. Optical modes in slab waveguides with magnetoelectric effect

    NASA Astrophysics Data System (ADS)

    Talebi, Nahid

    2016-05-01

    Optical modes in anisotropic slab waveguides with topological and chiral magnetoelectric effects are investigated analytically, by deriving the closed-form characteristic equations of the modes and hence computing the dispersion-diagrams. In order to compute the characteristic equations, a vector-potential approach is introduced by incorporating a generalized Lorentz gauge, and the Helmholtz equations are derived correspondingly. It will be shown that the formation of the complex modes and hybridization of the optical modes in such slab waveguides is inevitable. Moreover, when the tensorial form of the permittivity in the waveguide allows for a hyperbolic dispersion, complex transition from the photonic kinds of modes to the plasmonic modes is expected.

  3. Optical phonon modes of III-V nanoparticles and indium phosphide/II-VI core-shell nanoparticles: A Raman and infrared study

    NASA Astrophysics Data System (ADS)

    Manciu, Felicia Speranta

    The prospects for realizing efficient nanoparticle light emitters in the visible/near IR for communications and bio-medical applications have benefited from progress in chemical fabrication of nanoparticles. III-V semiconductor nanopaticles such as GaP and InP are promising materials for the development of "blue" and "green" emitters, respectively, due to their large effective bandgaps. Enhanced emission efficiency has been achieved for core-shell nanoparticles, since inorganic shell materials increase electronic tunability and may decrease surface defects that often occur for nanoparticles capped with organic molecules. Also, the emission wavelength of InP nanoparticle cores can be tuned from green to red by changing the shell material in InP/II-VI core-shell nanoparticles. Investigations of phonon modes in nanocrystals are of both fundamental and applied interest. In the former case the optical phonon modes, such as surface/interface modes, are dependent on the nanoparticle dimensions, and also can provide information about dynamical properties of the nanoparticles and test the validity of various theoretical approaches. In the latter case the vibronic properties of nanoparticle emitters are controlled by confined phonons and modifications of the electron-phonon interaction by the confinement. Thus, the objective of the present thesis is the detailed study of the phonon modes of III-V nanoparticles (GaP and InP) and InP/II-VI core-shell nanoparticles by IR absorption and Raman scattering spectroscopies, and an elucidation of their complex vibrational properties. With the exception of three samples (two GaP and one InP), all samples were synthesized by a novel colloidal chemistry method, which does not requires added surfactant, but rather treatment of the corresponding precursors in octadecene noncoordinative solvent. Sample quality was characterized by ED, TEM and X-ray diffraction. Based on a comparison with a dielectric continuum model, the observed features

  4. Different functional modes of p300 in activation of RNA polymerase III transcription from chromatin templates.

    PubMed

    Mertens, Claudia; Roeder, Robert G

    2008-09-01

    Transcriptional coactivators that regulate the activity of human RNA polymerase III (Pol III) in the context of chromatin have not been reported. Here, we describe a completely defined in vitro system for transcription of a human tRNA gene assembled into a chromatin template. Transcriptional activation and histone acetylation in this system depend on recruitment of p300 by general initiation factor TFIIIC, thus providing a new paradigm for recruitment of histone-modifying coactivators. Beyond its role as a chromatin-modifying factor, p300 displays an acetyltransferase-independent function at the level of preinitiation complex assembly. Thus, direct interaction of p300 with TFIIIC stabilizes binding of TFIIIC to core promoter elements and results in enhanced transcriptional activity on histone-free templates. Additional studies show that p300 is recruited to the promoters of actively transcribed tRNA and U6 snRNA genes in vivo. These studies identify TFIIIC as a recruitment factor for p300 and thus may have important implications for the emerging concept that tRNA genes or TFIIIC binding sites act as chromatin barriers to prohibit spreading of silenced heterochromatin domains. PMID:18644873

  5. Different Functional Modes of p300 in Activation of RNA Polymerase III Transcription from Chromatin Templates▿

    PubMed Central

    Mertens, Claudia; Roeder, Robert G.

    2008-01-01

    Transcriptional coactivators that regulate the activity of human RNA polymerase III (Pol III) in the context of chromatin have not been reported. Here, we describe a completely defined in vitro system for transcription of a human tRNA gene assembled into a chromatin template. Transcriptional activation and histone acetylation in this system depend on recruitment of p300 by general initiation factor TFIIIC, thus providing a new paradigm for recruitment of histone-modifying coactivators. Beyond its role as a chromatin-modifying factor, p300 displays an acetyltransferase-independent function at the level of preinitiation complex assembly. Thus, direct interaction of p300 with TFIIIC stabilizes binding of TFIIIC to core promoter elements and results in enhanced transcriptional activity on histone-free templates. Additional studies show that p300 is recruited to the promoters of actively transcribed tRNA and U6 snRNA genes in vivo. These studies identify TFIIIC as a recruitment factor for p300 and thus may have important implications for the emerging concept that tRNA genes or TFIIIC binding sites act as chromatin barriers to prohibit spreading of silenced heterochromatin domains. PMID:18644873

  6. Effects of Therapist Response Modes in Brief Psychotherapy.

    ERIC Educational Resources Information Center

    Hill, Clara E.; And Others

    1988-01-01

    Examined therapist response modes in 127 sessions of eight cases of brief psychotherapy with experienced therapists and anxious-depressed clients. Response modes had significant effect on immediate outcome, with self-disclosure, interpretation, approval, and paraphrase being the most helpful response modes. Found large individual differences in…

  7. Alpha particle effects on the internal kink modes

    SciTech Connect

    Wu, Yanlin; Cheng, C.Z.

    1994-08-01

    The {alpha}-particle effects on the internal kink mode stability are studied. Finite Grad-Shafranov Shift, plasma {beta}, and plasma shape can significantly enhance the trapped particle drift reversal domain in pitch angle space and reduce average magnetic drift frequency. The drift reversal effect on the ideal kink mode is small, but the {beta}{sub {alpha}} threshold for the fishbone mode can be much lower than previously predicted. In addition, the ion diamagnetic drift has a stronger destabilizing effect.

  8. Effect of thickness and loading mode on the fracture properties of V 4Cr 4Ti at room temperature

    NASA Astrophysics Data System (ADS)

    Li, H.; Kurtz, R. J.; Jones, R. H.

    1998-10-01

    The effect of thickness on the room temperature (RT) mode I fracture behavior of V-4Cr-4Ti has been investigated. Mode I fracture properties were measured from J-integral tests of compact tension (CT) specimens ranging in thickness from 6.4 to 25.4 mm. All specimens were machined in the T-L orientation and vacuum annealed following final machining. Two heats of V-4Cr-4Ti were tested. Specimens 6.4 and 12.7 mm thick were taken from Wah Chang Heat No. 832665. The 25.4 mm thick specimens were obtained from Wah Chang Heat No. 832864. The effect of loading mode on fracture of V-4Cr-4Ti at RT was also studied using material from Heat No. 832665. Mode I fracture behavior was compared to mixed-mode (I/III) fracture properties obtained from modified CT specimens. Crack angles of 0° and 25° were used to vary the ratio of mode III to mode I loading. J- R curves were generated as the basis for determining the affect of loading mode. The specimen loaded in mixed-mode exhibited lower resistance to crack initiation and propagation than pure mode I specimens.

  9. Transfer-printing-based integration of single-mode waveguide-coupled III-V-on-silicon broadband light emitters.

    PubMed

    De Groote, Andreas; Cardile, Paolo; Subramanian, Ananth Z; Fecioru, Alin M; Bower, Christopher; Delbeke, Danae; Baets, Roel; Roelkens, Günther

    2016-06-27

    We present the first III-V opto-electronic components transfer printed on and coupled to a silicon photonic integrated circuit. Thin InP-based membranes are transferred to an SOI waveguide circuit, after which a single-spatial-mode broadband light source is fabricated. The process flow to create transfer print-ready coupons is discussed. Aqueous FeCl3 at 5°C was found to be the best release agent in combination with the photoresist anchoring structures that were used. A thin DVS-BCB layer provides a strong bond, accommodating the post-processing of the membranes. The resulting optically pumped LED has a 3 dB bandwidth of 130 nm, comparable to devices realized using a traditional die-to-wafer bonding method. PMID:27410539

  10. Characteristics of Low-Frequency Molecular Phonon Modes Studied by THz Spectroscopy and Solid-State ab Initio Theory: Polymorphs I and III of Diflunisal.

    PubMed

    Zhang, Feng; Wang, Houng-Wei; Tominaga, Keisuke; Hayashi, Michitoshi

    2016-03-01

    THz absorption spectra of two polymorphs of diflunisal, form I and form III, exhibit distinct features due to the influence of packing conformations on the frequency distributions and IR activities of gamma point phonon modes within the 100 cm(-1) region. In order to understand the origins of these THz modes, we perform a detailed mode analysis. The result shows that although the spectral features are different, these low-frequency phonon modes of the two molecular polymorphs have similar vibrational characteristics in terms of harmonic couplings of intermolecular and intramolecular vibrations. PMID:26808927

  11. The mode III crack problem in bonded materials with a nonhomogeneous interfacial zone

    NASA Technical Reports Server (NTRS)

    Erdogan, F.; Joseph, P. F.; Kaya, A. C.

    1991-01-01

    The mode 3 crack problem for two bonded homogeneous half planes was considered. The interfacial zone was modelled by a nonhomogeneous strip in such a way that the shear modulus is a continuous function throughout the composite medium and has discontinuous derivatives along the boundaries of the interfacial zone. The problem was formulated for cracks perpendicular to the nominal interface and was solved for various crack locations in and around the interfacial region. The asymptotic stress field near the tip of a crack terminating at an interface was examined and it was shown that, unlike the corresponding stress field in piecewise homogeneous materials, in this case the stresses have the standard square root singularity and their angular variation was identical to that of a crack in a homogeneous medium. With application to the subcritical crack growth process in mind, the results given include mostly the stress intensity factors for some typical crack geometries and various material combinations.

  12. Analysis of the Effects of Three Modes of Head Start Delivery. Head Start Delivery Modes Project: Final Report.

    ERIC Educational Resources Information Center

    Peters, Donald L.; And Others

    This study analyzed the critical features of three delivery modes for Head Start services in order to: (1) compare the effects of different delivery modes on the immediate outcomes for children and parents; and (2) explore the pattern of effects both within and across modes to ascertain how the process works. The first mode represented the most…

  13. Plasmon modes of metallic nanowires including quantum nonlocal effects

    SciTech Connect

    Moradi, Afshin

    2015-03-15

    The properties of electrostatic surface and bulk plasmon modes of cylindrical metallic nanowires are investigated, using the quantum hydrodynamic theory of plasmon excitation which allows an analytical study of quantum tunneling effects through the Bohm potential term. New dispersion relations are obtained for each type of mode and their differences with previous treatments based on the standard hydrodynamic model are analyzed in detail. Numerical results show by considering the quantum effects, as the value of wave number increases, the surface modes are slightly red-shifted first and then blue-shifted while the bulk modes are blue-shifted.

  14. Mod 1 wind turbine generator failure modes and effects analysis

    NASA Technical Reports Server (NTRS)

    1979-01-01

    A failure modes and effects analysis (FMEA) was directed primarily at identifying those critical failure modes that would be hazardous to life or would result in major damage to the system. Each subsystem was approached from the top down, and broken down to successive lower levels where it appeared that the criticality of the failure mode warranted more detail analysis. The results were reviewed by specialists from outside the Mod 1 program, and corrective action taken wherever recommended.

  15. a Mossbauer Effect Study of Iron(iii) Dithiocarbamates.

    NASA Astrophysics Data System (ADS)

    Fiddy, Judith Mary

    Available from UMI in association with The British Library. Ever since the pioneering work of Cambi iron(III) trisdithiocarbamates, which have the formula Fe(R _2NCS_2]_3 where R is an alkyl or an aryl group, have formed the basis for understanding spin-state equilibria in iron(III) complexes. Magnetic and infrared studies clearly indicate equilibrium between the high-spin and low-spin states. The Mossbauer spectra, however, show only a single component, indicating rapid relaxation between the two spin states on the Mossbauer timescale. It has been assumed that the spectral parameters are therefore a function of the relative spin-state populations. In this thesis, the results of Mossbauer experiments carried out on a series of iron(III) trisdithiocarbamates with various organic substituents, known to give a range of high-spin and low-spin state populations at room temperature, are presented. An iron(III) bisdithiocarbamate complex, Fe^{57} ((C_5 H_{10})_2NCS _2]_2NCS, was also investigated. The samples were studied at temperatures from 1.3K to 295K, and at pressures between atmospheric pressure and 80kbar at room temperature only. It was found that, in fact, the spin-equilibrium plays only a minor role in determining the Mossbauer spectra of the trisdithiocarbamate compounds. The effects of spin -state relaxation on the temperature dependence of the spectra are, in general, masked by those of slow paramagnetic relaxation which, in contrast to the effects of the spin-equilibrium, are marked and different for each compound. By fitting the spectra to models of paramagnetic relaxation the temperature dependence of the relaxation rates and possible directions of the magnetic hyperfine field relative to the major axis of the electric field gradient were found. The pressure dependence of the spectra was found to be rather similar for all the compounds, the main differences being in the widths and in the asymmetry of the areas of the spectral lines. Both these effects can

  16. Period-Luminosity Relations Derived from the OGLE-III Fundamental Mode Cepheids. II. The Small Magellanic Cloud Cepheids

    NASA Astrophysics Data System (ADS)

    Ngeow, Chow-Choong; Kanbur, Shashi M.; Bhardwaj, Anupam; Singh, Harinder P.

    2015-07-01

    In this paper we present multi-band period-luminosity (P-L) relations for fundamental mode Cepheids in the SMC. The optical VI-band mean magnitudes for these SMC Cepheids were taken from the third phase of the Optical Gravitational Lensing Experiment (OGLE-III) catalog. We also matched the OGLE-III SMC Cepheids to 2MASS and SAGE-SMC catalog to derive mean magnitudes in the JHK-bands and the four Spitzer IRAC bands, respectively. All photometry was corrected for extinction by adopting Zaritsky’s extinction map. Cepheids with periods smaller than ˜2.5 days were removed from the sample. In addition to the extinction corrected P-L relations in nine filters from optical to infrared, we also derived the extinction-free Wesenheit function for these Cepheids. We tested the nonlinearity of these SMC P-L relations (except the 8.0 μ {{m}}-band P-L relation) at 10 days: none of the P-L relations show statistically significant evidence of nonlinearity. When compared to the P-L relations in the LMC, the t-test results revealed that there is a difference between the SMC/LMC P-L slopes only in the V- and J-band. Further, we found excellent agreement between the SMC/LMC Wesenheit P-L slope. The difference in LMC and SMC Period-Wesenheit relation LMC and SMC zero points was found to be {{Δ }}μ =0.483+/- 0.015 mag. This amounts to a difference in distance modulus between the LMC and SMC.

  17. Technology-Enhanced Courses and a Mode III Organization of Instructional Work

    ERIC Educational Resources Information Center

    Rhoades, Gary

    2007-01-01

    Although information technology is increasingly used to deliver distance and conventional courses, there have been few studies of the effect of technology-enhanced education on the organization and purposes of academics' instructional work. I explore this issue in undergraduate and masters level education through the vehicle of case analyses of…

  18. Adamantyl-group containing mixed-mode acrylamide-based continuous beds for capillary electrochromatography. Part III. Optimization of the chromatographic efficiency.

    PubMed

    Al-Massaedh, Ayat Allah; Pyell, Ute

    2014-01-17

    In a previous article we described the synthesis of amphiphilic monolithic stationary phases by in situ free radical copolymerization of cyclodextrin-solubilized N-adamantyl acrylamide, piperazinediacrylamide, methacrylamide and vinylsulfonic acid in aqueous medium in pre-treated fused silica capillaries of 100μ.m I.D. In this work, a series of N-adamantyl-group containing acrylamide-based continuous beds is synthesized under variation of different synthesis parameters. The studied synthesis parameters are (i) concentration of the lyotropic salt ammonium sulfate, (ii) concentration of the initiator ammonium persulfate, and (iii) concentration of the negatively charged monomer vinylsulfonic acid in the polymerization mixture. The influence of the synthesis parameters on the chromatographic efficiency is studied under isocratic conditions for a homologues series of alkylphenones in the reversed-phase mode at constant composition of the mobile phase via capillary electrochromatography with varied electric field strength. With varied concentration of the lyotropic salt ammonium sulfate or varied concentration of the initiator ammonium persulfate in the polymerization mixture, a strong impact on the chromatographic efficiency is observed, while there is only a minor influence when varying the molar fraction of the charged monomer VSA. The absence of a significant influence of extra-column band broadening effects on the determined efficiency is confirmed. There is a good repeatability (with respect to capillary-to-capillary variation and run-to-run variation) reached for the theoretical plate heights obtained for DMF and selected alkylphenones in the reversed-phase mode. PMID:24296296

  19. The Effects of Different Delivery Modes in Survey Administration

    ERIC Educational Resources Information Center

    Goho, James

    2003-01-01

    A perennial problem for survey research is achieving adequate response rates. One method for improving rates is to offer multiple modes for response. An associated issue is the effect of differing modes. This research examined both matters using a survey of community college graduates. Fielding consisted of two phases. Phase One offered three…

  20. Letter report seismic shutdown system failure mode and effect analysis

    SciTech Connect

    KECK, R.D.

    1999-09-01

    The Supply Ventilation System Seismic Shutdown ensures that the 234-52 building supply fans, the dry air process fans and vertical development calciner are shutdown following a seismic event. This evaluates the failure modes and determines the effects of the failure modes.

  1. Effective As(III) Removal by A Multi-Charged Hydroacid Complex Draw Solute Facilitated Forward Osmosis-Membrane Distillation (FO-MD) Processes.

    PubMed

    Ge, Qingchun; Han, Gang; Chung, Tai-Shung

    2016-03-01

    Effective removal of As(III) from water by an oxalic acid complex with the formula of Na3[Cr(C2O4)3] (Na-Cr-OA) is demonstrated via an forward osmosis-membrane distillation (FO-MD) hybrid system in this study. Na-Cr-OA first proved its superiority as a draw solute with high water fluxes and negligible reverse fluxes in FO, then a systematic investigation of the Na-Cr-OA promoted FO process was conducted to ascertain the factors in As(III) removal. Relatively high water fluxes of 28 LMH under the FO mode and 74 LMH under the pressure retarded osmosis (PRO) mode were achieved when using a 1000 ppm As(III) solution as the feed and 1.0 M Na-Cr-OA as the draw solution at 60 °C. As(III) removal with a water recovery up to 21.6% (FO mode) and 48.3% (PRO mode) were also achieved in 2 h. An outstanding As(III) rejection with 30-3000 μg/L As(III) in the permeate was accomplished when As(III) feed solutions varied from 5 × 10(4) to 1 × 10(6) μg/L, superior to the best FO performance reported for As(III) removal. Incorporating MD into FO not only makes As(III) removal sustainable by reconcentrating the Na-Cr-OA solution simultaneously, but also reduces the As(III) concentration below 10 μg/L in the product water, meeting the WHO standard. PMID:26822310

  2. III-V nanowire growth mechanism: V/III ratio and temperature effects.

    PubMed

    Dayeh, Shadi A; Yu, Edward T; Wang, Deli

    2007-08-01

    We have studied the dependence of Au-assisted InAs nanowire (NW) growth on InAs(111)B substrates as a function of substrate temperature and input V/III precursor ratio using organometallic vapor-phase epitaxy. Temperature-dependent growth was observed within certain temperature windows that are highly dependent on input V/III ratios. This dependence was found to be a direct consequence of the drop in NW nucleation and growth rate with increasing V/III ratio at a constant growth temperature due to depletion of indium at the NW growth sites. The growth rate was found to be determined by the local V/III ratio, which is dependent on the input precursor flow rates, growth temperature, and substrate decomposition. These studies advance understanding of the key processes involved in III-V NW growth, support the general validity of the vapor-liquid-solid growth mechanism for III-V NWs, and improve rational control over their growth morphology. PMID:17608541

  3. Pulse-mode quantum projection synthesis: Effects of mode mismatch on optical state truncation and preparation

    SciTech Connect

    Oezdemir, Sahin Kaya; Koashi, Masato; Miranowicz, Adam; Imoto, Nobuyuki

    2002-11-01

    Quantum projection synthesis can be used for phase-probability-distribution measurement and optical-state truncation and preparation. The method relies on interfering optical light beams, which is a major challenge in experiments performed by pulsed light sources. In the pulsed regime, the time frequency overlap of the interfering light beams has a major impact on the efficiency of the method. In this paper, the pulse-mode projection-synthesis approach is developed, the mode structures of interfering light beams are characterized, and the effect of this overlap on the fidelity of optical-state truncation and preparation is investigated. By introducing the positive-operator-valued measure for the detection events in the scheme, the effect of mode mismatch between the photon-counting detectors and the incident light beams is also presented.

  4. Geometric Effects on the Amplification of First Mode Instability Waves

    NASA Technical Reports Server (NTRS)

    Kirk, Lindsay C.; Candler, Graham V.

    2013-01-01

    The effects of geometric changes on the amplification of first mode instability waves in an external supersonic boundary layer were investigated using numerical techniques. Boundary layer stability was analyzed at Mach 6 conditions similar to freestream conditions obtained in quiet ground test facilities so that results obtained in this study may be applied to future test article design to measure first mode instability waves. The DAKOTA optimization software package was used to optimize an axisymmetric geometry to maximize the amplification of the waves at first mode frequencies as computed by the 2D STABL hypersonic boundary layer stability analysis tool. First, geometric parameters such as nose radius, cone half angle, vehicle length, and surface curvature were examined separately to determine the individual effects on the first mode amplification. Finally, all geometric parameters were allowed to vary to produce a shape optimized to maximize the amplification of first mode instability waves while minimizing the amplification of second mode instability waves. Since first mode waves are known to be most unstable in the form of oblique wave, the geometries were optimized using a broad range of wave frequencies as well as a wide range of oblique wave angles to determine the geometry that most amplifies the first mode waves. Since first mode waves are seen most often in flows with low Mach numbers at the edge of the boundary layer, the edge Mach number for each geometry was recorded to determine any relationship between edge Mach number and the stability of first mode waves. Results indicate that an axisymmetric cone with a sharp nose and a slight flare at the aft end under the Mach 6 freestream conditions used here will lower the Mach number at the edge of the boundary layer to less than 4, and the corresponding stability analysis showed maximum first mode N factors of 3.

  5. Failure Modes and Effects Analysis (FMEA) Assistant Tool Feasibility Study

    NASA Technical Reports Server (NTRS)

    Flores, Melissa; Malin, Jane T.

    2013-01-01

    An effort to determine the feasibility of a software tool to assist in Failure Modes and Effects Analysis (FMEA) has been completed. This new and unique approach to FMEA uses model based systems engineering concepts to recommend failure modes, causes, and effects to the user after they have made several selections from pick lists about a component s functions and inputs/outputs. Recommendations are made based on a library using common failure modes identified over the course of several major human spaceflight programs. However, the tool could be adapted for use in a wide range of applications from NASA to the energy industry.

  6. Kinetic effect of toroidal rotation on the geodesic acoustic mode

    SciTech Connect

    Guo, W. Ye, L.; Zhou, D.; Xiao, X.; Wang, S.

    2015-01-15

    Kinetic effects of the toroidal rotation on the geodesic acoustic mode are theoretically investigated. It is found that when the toroidal rotation increases, the damping rate increases in the weak rotation regime due to the rotation enhancement of wave-particle interaction, and it decreases in the strong rotation regime due to the reduction of the number of resonant particles. Theoretical results are consistent with the behaviors of the geodesic acoustic mode recently observed in DIII-D and ASDEX-Upgrade. The kinetic damping effect of the rotation on the geodesic acoustic mode may shed light on the regulation of turbulence through the controlling the toroidal rotation.

  7. Effective field theory from modified gravity with massive modes

    NASA Astrophysics Data System (ADS)

    Capozziello, Salvatore; de Laurentis, Mariafelicia; Paolella, Mariacristina; Ricciardi, Giulia

    2015-10-01

    Massive gravitational modes in effective field theories can be recovered by extending General Relativity and taking into account generic functions of the curvature invariants, not necessarily linear in the Ricci scalar R. In particular, adopting the minimal extension of f(R) gravity, an effective field theory with massive modes is straightforwardly recovered. This approach allows to evade shortcomings like ghosts and discontinuities if a suitable choice of expansion parameters is performed.

  8. Complexation of Nd(III) with tetraborate ion and its effect on actinide (III) solubility in WIPP brine

    SciTech Connect

    Borkowski, Marian; Richmann, Michael K; Reed, Donald T; Yongliang, Xiong

    2010-01-01

    The potential importance of tetraborate complexation on lanthanide(III) and actinide(III) solubility is recognized in the literature but a systematic study of f-element complexation has not been performed. In neodymium solubility studies in WIPP brines, the carbonate complexation effect is not observed since tetraborate ions form a moderately strong complex with neodymium(III). The existence of these tetraborate complexes was established for low and high ionic strength solutions. Changes in neodymium(III) concentrations in undersaturation experiments were used to determine the neodymium with tetraborate stability constants as a function of NaCl ionic strength. As very low Nd(III) concentrations have to be measured, it was necessary to use an extraction pre-concentration step combined with ICP-MS analysis to extend the detection limit by a factor of 50. The determined Nd(III) with borate stability constants at infinite dilution and 25 C are equal to log {beta}{sub 1} = 4.55 {+-} 0.06 using the SIT approach, equal to log {beta}{sub 1} = 4.99 {+-} 0.30 using the Pitzer approach, with an apparent log {beta}{sub 1} = 4.06 {+-} 0.15 (in molal units) at I = 5.6 m NaCl. Pitzer ion-interaction parameters for neodymium with tetraborate and SIT interaction coefficients were also determined and reported.

  9. Effective transition probability for the Faraday effect of lanthanide(III) ion solutions.

    PubMed

    Miyamoto, Kayoko; Isai, Kento; Suwa, Masayori; Watarai, Hitoshi

    2009-05-13

    The Faraday effects of 14 lanthanide(III) ion solutions were systematically analyzed on the basis of the Faraday C term. The effective transition probability, K, which measures the magneto-optical contribution of the 4f(n) --> 4f(n-1)5d transition to the molar Verdet constant, was determined. Linear correlations between K and the square root of the molar magnetic susceptibility of the lanthanide(III) ions, chi(m)(1/2), were obtained. From the observed new regularity, K for promethium(III) was estimated. PMID:19378955

  10. Heterogeneously integrated III-V/Si single mode lasers based on a MMI-ring configuration and triplet-ring reflectors

    NASA Astrophysics Data System (ADS)

    Keyvaninia, S.; Verstuyft, S.; Lelarge, F.; Duan, G.-H.; Messaoudene, S.; Fédéli, J. M.; Geluk, E. J.; De Vries, T.; Smalbrugge, B.; Bolk, J.; Smit, M.; Van Thourhout, D.; Roelkens, G.

    2013-05-01

    In this paper we show that using a DVS-BCB adhesive bonding process compact heterogeneously integrated III-V/silicon single mode lasers can be realized. Two new designs were implemented: in a first design a multimode interferometer coupler (MMI) - ring resonator combination is used to provide a comb-like reflection spectrum, while in a second design a triplet-ring reflector design is used to obtain the same. A broadband silicon Bragg grating reflector is implemented on the other side of the cavity. The III-V optical amplifier is heterogeneously integrated on the 400nm thick silicon waveguide layer, which is compatible with high-performance modulator designs and allows for efficient coupling to a standard 220nm high index contrast silicon waveguide layer. In order to make the optical coupling efficient, both the III-V waveguide and the silicon waveguide are tapered, with a tip width of the III-V waveguide of around 500nm. The III-V thin film optical amplifier is implemented as a 3μm wide mesa etched through to the n-type InP contact layer. In this particular device implementation the amplifier section was 500μm long. mW-level waveguide coupled output power at 20°C and a side mode suppression ratio of more than 40dB is obtained.

  11. Interactions of bis(2,4,4-trimethylpentyl)dithiophosphinate with Nd(III) and Cm(III) in a homogeneous medium: a comparative study of thermodynamics and coordination modes.

    PubMed

    Xu, Chao; Rao, Linfeng

    2014-11-01

    Complexation of Nd(III) and Cm(III) with purified Cyanex301 (ammonium bis(2,4,4-trimethylpentyl)dithiophosphinate, denoted as HL) was studied in 1 % v/v water/ethanol under identical conditions by spectrophotometry and microcalorimetry. For Nd(III) , three successive complexes, NdL(2+) , NdL2 (+) , and NdL3 , formed in the solution. In contrast, four complexes, CmL(2+) , CmL2 (+) , CmL3 , and CmL4 (-) formed during the titration with Cm. Fluorescence lifetime measurements provided additional insight into the complexation of Cm(III) with Cyanex301. The stepwise stability constants for the CmLj ((3-j)+) (j=1-3) complexes are about one order of magnitude higher than the corresponding NdLj ((3-j)+) complexes. The enthalpies of complexation are endothermic for both Nd(III) and Cm(III) , suggesting that the energy required for desolvation exceeds the energy gained from the cation/ligand combination. Specifically, the enthalpy of complexation for CmL(2+) is 3.5 kJ mol(-1) less endothermic than that of NdL(2+) , implying stronger covalent interaction in CmL(2+) than NdL(2+) . However, the enthalpies of complexation for CmL2 (+) and NdL2 (+) are nearly identical, and the enthalpy of complexation for CmL3 (aq) becomes more endothermic than that for NdL3 (aq). The observations suggest that, in the ethanol/water media, the overall energetics of the Cm(III) /Nd(III) complexation with Cyanex301 could depend on a number of factors, including the extent of covalency, the degree of desolvation, and the coordination modes. PMID:25213623

  12. Arc fusion splicing effects in large-mode-area single-mode ytterbium-doped fibers.

    PubMed

    Feng, Ting; Jenkins, Micah H; Yan, Fengping; Gaylord, Thomas K

    2013-11-10

    For the first time the effects of arc fusion splicing on the residual stress and refractive index of large-mode-area single-mode ytterbium-doped fibers (YDFs) are investigated using a state-of-the-art three-dimensional concurrent stress-index measurement method. The results, based on a commercially available fiber, describe a host of perturbations that decrease the core/cladding refractive index difference by as much as 1.74 × 10(-3) over an axial length of many hundreds of wavelengths. Simulations indicate that these perturbations result in an expansion of the mode-field-diameter by 39.6% and, based on the measured sample, result in an extra splice loss of 20.8%. The results of this investigation will be useful in the design and optimization of high-power all-fiber YDF lasers and amplifiers. PMID:24216728

  13. Neoclassical viscosity effects on resistive magnetohydrodynamic modes in toroidal geometry

    SciTech Connect

    Yang, J.G.; Oh, Y.H.; Choi, D.I. ); Kim, J.Y.; Horton, W. )

    1992-03-01

    The flux-surface-averaged linearized resistive magnetohydrodynamic (MHD) boundary-layer equations including the compressibility, diamagnetic drift, and neoclassical viscosity terms are derived in toroidal geometry. These equations describe the resistive layer dynamics of resistive MHD modes over the collisionality regime between the banana plateau and the Pfirsch--Schlueter. From the resulting equations, the effects of neoclassical viscosity on the stability of the tearing and resistive ballooning modes are investigated numerically. Also, a study is given for the problem of how the neoclassical resistive MHD mode is generated as the collisionality is reduced. It is shown that the neoclassical viscosity terms give a significant destabilizing effect for the tearing and resistive ballooning modes. This destabilization comes mainly from the reduction of the stabilizing effect of the parallel ion sound compression by the ion neoclassical viscosity. In the banana-plateau collisionality limit, where the compressibility is negligible, the dispersion relations of the tearing and resistive ballooning modes reduce to the same form, with the threshold value of the driving force given by {Delta}{sub {ital c}}=0. On the other hand, with the finite neoclassical effect it is found that the neoclassical resistive MHD instability is generated in agreement with previous results. Furthermore, it is shown that this later instability can be generated in a wide range of the collisionality including near the Pfirsch--Schlueter regime as well as the banana-plateau regime, suggesting that this mode is a probable cause of anomalous transport.

  14. Aggregated enhanced Raman scattering in Fe(III)PPIX solutions: the effects of concentration and chloroquine on excitonic interactions.

    PubMed

    Webster, Grant T; McNaughton, Don; Wood, Bayden R

    2009-05-14

    Resonance Raman spectra of hematin and hemin solutions are reported for 413 and 514 nm excitation wavelengths. Enhancement of A1g modes (1569 and 1370 cm(-1)) and B1g modes (1124 and 755 cm(-1)) as a function of increased concentration are observed when irradiating with 514 nm laser excitation but not 413 nm. This can be rationalized by considering an excitonic coupling mechanism. As the concentration of hematin increases there is an increased probability of supramolecular interactions between iron(III) protoporphyrin IX (Fe(III)PPIX) units occurring. The Fe(III)PPIX concentration reaches a saturation point in solution and excitonic coupling reaches a maximum causing the enhancement profile to plateau when applying 514 nm excitation. In contrast, when using 413 nm excitation there were no changes in band intensity with increased concentration showing that excitonic coupling through supramolecular interactions for aggregated solutions is wavelength dependent. Electronic absorption spectra show that as the concentration of Fe(III)PPIX increases in solution the Soret band is slightly blue shifted and the Q-band significantly broadens supporting the excitonic hypothesis. Understanding the mechanism that accounts for the Raman photophysical behavior of hemes at high concentrations provided an indirect method to monitor antimalarial drug interactions. A second aim was to investigate chloroquine binding to Fe(III)PPIX-OH/H2O monomers, pi-pi dimers and micro-oxo dimers formed in highly concentrated solutions approaching those of the digestive vacuole of the P. falciparum malaria parasite using excitonic Raman enhancement. It was hypothesized that the Raman excitonic enhancement mechanism could be impeded in heme aggregated solutions by the addition of chloroquine. This would result in a reduction in heme bands associated with the A1g modes including nu4. Resonance Raman spectra recorded using 514 nm excitation show that chloroquine (CQ) acts as a molecular spacer and binds

  15. Survey mode effects on valuation of environmental goods.

    PubMed

    Bell, Jason; Huber, Joel; Viscusi, W Kip

    2011-04-01

    This article evaluates the effect of the choice of survey recruitment mode on the value of water quality in lakes, rivers, and streams. Four different modes are compared: bringing respondents to one central location after phone recruitment, mall intercepts in two states, national phone-mail survey, and an Internet survey with a national, probability-based panel. The modes differ in terms of the representativeness of the samples, non-response rates, sample selection effects, and consistency of responses. The article also shows that the estimated value of water quality can differ substantially depending on the survey mode. The national Internet panel has the most desirable properties with respect to performance on the four important survey dimensions of interest. PMID:21695037

  16. Plasma Oscillations and Operational Modes in Hall Effect Thrusters

    NASA Astrophysics Data System (ADS)

    Sekerak, Michael J.

    Mode transitions have been commonly observed in Hall effect thruster (HET) operation where a small change in a thruster operating parameter such as discharge voltage, magnetic field or mass flow rate causes the thruster discharge current mean value and oscillation amplitude to increase significantly. In this study, mode transitions in HETs are induced by varying the magnetic field intensity while holding all other operating parameters constant and measurements are acquired with high-speed probes and ultra-fast imaging. Two primary oscillatory modes were identified and extensively characterized called global oscillation mode and local oscillation mode. In the global mode, the entire discharge channel oscillates in unison and azimuthal perturbations (spokes) are either absent or negligible. Downstream azimuthally spaced probes show no signal delay between each other and are very well correlated to the discharge current signal. In the local mode, signals from the azimuthally spaced probes exhibit a clear delay indicating the passage of spokes. These spokes are localized oscillations in discharge current density propagating in the E x B direction that are typically 10-20% of the mean value. In contrast, the oscillations in the global mode can be 100% of the mean discharge current density value. The spoke velocity is determined from high-speed image analysis using three methods yielding values between 1500 and 2200 m/s across a range of magnetic field settings. The transition between global and local modes occurs at higher relative magnetic field strengths for higher mass flow rates or higher discharge voltages. It is proposed that mode transitions represent de-stabilization of the ionization front similar to excitation of the well-studied Hall thruster breathing mode, which is supported by time-resolved simulations of the discharge channel plasma. The thrust is approximately constant in both modes, but the thrust-to-power and anode efficiency decrease in global mode

  17. Effects of voids on delamination behavior under static and fatigue mode I and mode II

    NASA Astrophysics Data System (ADS)

    Abdelal, Nisrin Rizek

    Composite materials have become materials of choice for wind turbine blade manufacturing due to their high specific stiffness, strength and fatigue life. Glass fiber composites are used extensively in light-weight structural components for wind turbines, aircrafts, marine craft and high performance automobile because glass fiber is inexpensive and usually provides high strength to weight ratio and good in-plane mechanical properties. The high cycle fatigue resistance of composite materials used in wind turbine blades has been recognized as a major uncertainty in predicting the reliability of wind turbines over their design lifetime. Blades are expected to experience 108 to 109 fatigue cycles over a 20 to 30 year lifetime. Delamination or interlaminar failure is a serious failure mode observed in composite structures. Even partial delamination will lead to a loss of local stiffness, which can preclude buckling failure. Manufacturing process defects such as voids and fiber waviness degrade the fatigue life and delamination resistance of the blade's composite. This research describes the effect of voids on static and fatigue interlaminar fracture behavior under mode I and mode II loading of wind turbine glass fiber composites. Samples with different void volume fractions in the 0.5%-7% range were successfully obtained by varying the vacuum in the hand layup vacuum bagging manufacturing process. Void content was characterized using four different methods; ultrasonic scanning, epoxy burn off, serial sectioning and X-Ray computed tomography. The effect of voids on both mode I and mode II interlaminar fracture toughness under static and fatigue loading was investigated. Finally, fractographic analysis (using optical and scanning electron microscopy) was conducted. The results showed that voids leads to slight reduction in static modes I and II interlaminar fracture toughness. In addition, voids lead to a decrease in modes I and II maximum cyclic strain energy release

  18. Development of fracture facets from a crack loaded in mode I+III: Solution and application of a model 2D problem

    NASA Astrophysics Data System (ADS)

    Leblond, Jean-Baptiste; Frelat, Joël

    2014-03-01

    It is experimentally well-known that a crack loaded in mode I+III propagates through formation of discrete fracture facets inclined at a certain tilt angle on the original crack plane, depending on the ratio of the mode III to mode I initial stress intensity factors. Pollard et al. (1982) have proposed to calculate this angle by considering the tractions on all possible future infinitesimal facets and assuming shear tractions to be zero on that which will actually develop. In this paper we consider the opposite case of well-developed facets; the stress field near the lateral fronts of such facets becomes independent of the initial crack and essentially 2D in a plane perpendicular to the main direction of crack propagation. To determine this stress field, we solve the model 2D problem of an infinite plate containing an infinite periodic array of cracks inclined at some angle on a straight line, and loaded through uniform stresses at infinity. This is done first analytically, for small values of this angle, by combining Muskhelishvili's (1953) formalism and a first-order perturbation procedure. The formulae found for the 2D stress intensity factors are then extended in an approximate way to larger angles by using another reference solution, and finally assessed through comparison with some finite element results. To finally illustrate the possible future application of these formulae to the prediction of the stationary tilt angle, we introduce the tentative assumption that the 2D mode II stress intensity factor is zero on the lateral fronts of the facets. An approximate formula providing the tilt angle as a function of the ratio of the mode III to mode I stress intensity factors of the initial crack is deduced from there. This formula, which slightly depends on the type of loading imposed, predicts somewhat smaller angles than that of Pollard et al. (1982).

  19. Effects of Ca2+ on refolding of the recombinant hemolytic lectin CEL-III.

    PubMed

    Hisamatsu, Keigo; Unno, Hideaki; Goda, Shuichiro; Hatakeyama, Tomomitsu

    2009-05-01

    CEL-III is a hemolytic lectin isolated from Cucumaria echinata. Although recombinant CEL-III (rCEL-III) expressed in Escherichia coli showed very weak hemolytic activity compared with native protein, it was considerably enhanced by refolding in the presence of Ca(2+). This suggests that Ca(2+) supported correct folding of the carbohydrate-binding domains of rCEL-III, leading to effective binding to the cell surface and subsequent self-oligomerization. PMID:19420692

  20. Experimental and simulation predicted crack paths for al-2024-t351 under mixed-mode i/ii fatigue loading using an arcan fixture

    NASA Astrophysics Data System (ADS)

    Miller, Eileen

    Mixed mode I/II fatigue experiments and simulations are performed for an Arcan fixture and a 6.35mm thick Al-2024-T351 specimen. Experiments were performed for Arcan loading angles that gave rise to a range of Mode I/II crack tip conditions from 0 ¡U ¦¤KII/¦¤KI ¡U ¡TH. Measurements include the crack paths, loading cycles and maximum and minimum loads for each loading angle. Simulations were performed using three-dimensional finite element analysis (3D-FEA) with 10-noded tetrahedral elements via CRACK3D. While modeling the entire fixture-specimen geometry, a modified version of VCCT with automatic crack tip re-meshing and a maximum normal stress criterion were used to predict the direction of crack growth. Results indicate excellent agreement between experiments and simulations for the measured crack paths during the first several millimeters of crack extension.

  1. Complex modes and effective refractive index in 3D periodic arrays of plasmonic nanospheres.

    PubMed

    Campione, Salvatore; Steshenko, Sergiy; Albani, Matteo; Capolino, Filippo

    2011-12-19

    We characterize the modes with complex wavenumber for both longitudinal and transverse polarization states (with respect to the mode traveling direction) in three dimensional (3D) periodic arrays of plasmonic nanospheres, including metal losses. The Ewald representation of the required dyadic periodic Green's function to represent the field in 3D periodic arrays is derived from the scalar case, which can be analytically continued into the complex wavenumber space. We observe the presence of one longitudinal mode and two transverse modes, one forward and one backward. Despite the presence of two modes for transverse polarization, we notice that the forward one is "dominant" (i.e., it contributes most to the field in the array). Therefore, in case of transverse polarization, we describe the composite material in terms of a homogenized effective refractive index, comparing results from (i) modal analysis, (ii) Maxwell Garnett theory, (iii) Nicolson-Ross-Weir retrieval method from scattering parameters for finite thickness structures (considering different thicknesses, showing consistency of results), and (iv) the fitting of the fields obtained through HFSS simulations. The agreement among the different methods justifies the performed homogenization procedure in case of transverse polarization. PMID:22274192

  2. Possible confirmation of the existence of the ergoregion by the Kerr quasinormal mode in gravitational waves from a Population III massive black hole binary

    NASA Astrophysics Data System (ADS)

    Kinugawa, Tomoya; Nakano, Hiroyuki; Nakamura, Takashi

    2016-03-01

    The existence of the ergoregion of the Kerr space-time has not yet been confirmed observationally. We show that the confirmation would be possible by observing the quasinormal mode in gravitational waves. As an example, using the recent population synthesis results of Population III (Pop III) binary black holes, we find that the peak of the final merger mass (M_f) is about 50 M_{⊙}, while the fraction of the final spin q_f = a_f/M_f > 0.7 needed for the confirmation of a part of the ergoregion is {˜ }77%. To confirm the frequency of the quasinormal mode, SNR > 35 is needed. The standard model of Pop III population synthesis tells us that the event rate for the confirmation of more than 50% of the ergoregion by second generation gravitational wave detectors is {˜ }2.3 events yr^{-1 (SFR_p/(10^{-2.5} M_⊙ yr^{-1} Mpc^{-3}))} \\cdot ([f_b/(1+f_b)]/0.33), where SFR_p and f_b are the peak value of the Pop III star formation rate and the fraction of binaries, respectively.

  3. Effects of mode-mode and isospin-isospin correlations on domain formation of disoriented chiral condensates

    SciTech Connect

    Ikezi, N.; Asakawa, M.; Tsue, Y.

    2006-04-15

    The effects of mode-mode and isospin-isospin correlations on nonequilibrium chiral dynamics are investigated by using the method of the time-dependent variational approach with squeezed states as trial states. Our numerical simulations show that large domains of the disoriented chiral condensate (DCC) are formed because of the combined effect of the mode-mode and isospin-isospin correlations. Moreover, it is found that, when the mode-mode correlation is included, the DCC domain formation is accompanied by the amplification of the quantum fluctuation, which implies the squeezing of the state. However, neither the DCC domain formation nor the amplification of the quantum fluctuation is observed if only the isospin-isospin correlation is included. This suggests that the mode-mode coupling plays a key role in the DCC domain formation.

  4. Polarization Effects in Group III-Nitride Materials and Devices

    NASA Astrophysics Data System (ADS)

    Wei, Qiyuan

    Group III-nitride semiconductors have wide application in optoelectronic devices. Spontaneous and piezoelectric polarization effects have been found to be critical for electric and optical properties of group III-nitrides. In this dissertation, firstly, the crystal orientation dependence of the polarization is calculated and in-plane polarization is revealed. The in-plane polarization is sensitive to the lateral characteristic dimension determined by the microstructure. Specific semi-polar plane growth is suggested for reducing quantum-confined Stark effect. The macroscopic electrostatic field from the polarization discontinuity in the heterostructures is discussed, b ased on that, the band diagram of InGaN/GaN quantum well/barrier and AlGaN/GaN heterojunction is obtained from the self-consistent solution of Schrodinger and Poisson equations. New device design such as triangular quantum well with the quenched polarization field is proposed. Electron holography in the transmission electron microscopy is used to examine the electrostatic potential under polarization effects. The measured potential energy profiles of heterostructure are compared with the band simulation, and evidences of two-dimensional hole gas (2DHG) in a wurtzite AlGaN/ AlN/ GaN superlattice, as well as quasi two-dimensional electron gas (2DEG) in a zinc-blende AlGaN/GaN are found. The large polarization discontinuity of AlN/GaN is the main source of the 2DHG of wurtzite nitrides, while the impurity introduced during the growth of AlGaN layer provides the donor states that to a great extent balance the free electrons in zinc-blende nitrides. It is also found that the quasi-2DEG concentration in zinc-blende AlGaN/GaN is about one order of magnitude lower than the wurtzite AlGaN/GaN, due to the absence of polarization. Finally, the InAlN/GaN lattice-matched epitaxy, which ideally has a zero piezoelectric polarization and strong spontaneous polarization, is experimentally studied. The breakdown in

  5. Langmuir mixing effects on global climate: WAVEWATCH III in CESM

    NASA Astrophysics Data System (ADS)

    Li, Qing; Webb, Adrean; Fox-Kemper, Baylor; Craig, Anthony; Danabasoglu, Gokhan; Large, William G.; Vertenstein, Mariana

    2016-07-01

    Large-Eddy Simulations (LES) have shown the effects of ocean surface gravity waves in enhancing the ocean boundary layer mixing through Langmuir turbulence. Neglecting this Langmuir mixing process may contribute to the common shallow bias in mixed layer depth in regions of the Southern Ocean and the Northern Atlantic in most state-of-the-art climate models. In this study, a third generation wave model, WAVEWATCH III, has been incorporated as a component of the Community Earth System Model, version 1.2 (CESM1.2). In particular, the wave model is now coupled with the ocean model through a modified version of the K-Profile Parameterization (KPP) to approximate the influence of Langmuir mixing. Unlike past studies, the wind-wave misalignment and the effects of Stokes drift penetration depth are considered through empirical scalings based on the rate of mixing in LES. Wave-Ocean only experiments show substantial improvements in the shallow biases of mixed layer depth in the Southern Ocean. Ventilation is enhanced and low concentration biases of pCFC-11 are reduced in the Southern Hemisphere. A majority of the improvements persist in the presence of other climate feedbacks in the fully coupled experiments. In addition, warming of the subsurface water over the majority of global ocean is observed in the fully coupled experiments with waves, and the cold subsurface ocean temperature biases are reduced.

  6. Nonlinear simulations of particle source effects on edge localized mode

    SciTech Connect

    Huang, J.; Tang, C. J.; Chen, S. Y.; Wang, Z. H.

    2015-12-15

    The effects of particle source (PS) with different intensities and located positions on Edge Localized Mode (ELM) are systematically studied with BOUT++ code. The results show the ELM size strongly decreases with increasing the PS intensity once the PS is located in the middle or bottom of the pedestal. The effects of PS on ELM depend on the located position of PS. When it is located at the top of the pedestal, peeling-ballooning (P-B) modes can extract more free energy from the pressure gradient and grow up to be a large filament at the initial crash phase and the broadening of mode spectrum can be suppressed by PS, which leads to more energy loss. When it is located in the middle or bottom of the pedestal, the extraction of free energy by P-B modes can be suppressed, and a small filament is generated. During the turbulence transport phase, the broader mode spectrum suppresses the turbulence transport when PS is located in the middle, while the zonal flow plays an important role in damping the turbulence transport when PS is located at the bottom.

  7. The congruency sequence effect transfers across different response modes.

    PubMed

    Weissman, Daniel H; Colter, Katelyn; Drake, Brittany; Morgan, Christina

    2015-10-01

    The congruency effect observed in distracter interference tasks is usually smaller after incongruent relative to congruent trials. However, the nature of control processes underlying this congruency sequence effect (CSE) remains a topic of active debate. For example, while some researchers have suggested that these processes are recruited only when participants utilize the same response mode (e.g., the same hand) to respond in consecutive trials, others have argued that these processes can operate independently of response mode. To distinguish between these views, we investigated whether changes of response mode across consecutive trials influence the CSE in a prime-probe task (Experiment 1) or a flanker task (Experiment 2). Such changes did not influence the CSE in either task. Further, the CSE was significant even when participants utilized different response modes (i.e., different hands) to respond in consecutive trials. These findings indicate that control processes underlying the CSE can operate independently of response mode and thereby clarify the nature of control processes that minimize distraction from irrelevant stimuli. PMID:26343331

  8. Nonlinear simulations of particle source effects on edge localized mode

    NASA Astrophysics Data System (ADS)

    Huang, J.; Chen, S. Y.; Wang, Z. H.; Tang, C. J.

    2015-12-01

    The effects of particle source (PS) with different intensities and located positions on Edge Localized Mode (ELM) are systematically studied with BOUT++ code. The results show the ELM size strongly decreases with increasing the PS intensity once the PS is located in the middle or bottom of the pedestal. The effects of PS on ELM depend on the located position of PS. When it is located at the top of the pedestal, peeling-ballooning (P-B) modes can extract more free energy from the pressure gradient and grow up to be a large filament at the initial crash phase and the broadening of mode spectrum can be suppressed by PS, which leads to more energy loss. When it is located in the middle or bottom of the pedestal, the extraction of free energy by P-B modes can be suppressed, and a small filament is generated. During the turbulence transport phase, the broader mode spectrum suppresses the turbulence transport when PS is located in the middle, while the zonal flow plays an important role in damping the turbulence transport when PS is located at the bottom.

  9. Enhancing Effective Chemistry Learning through Hypermedia Instructional Mode of Delivery

    ERIC Educational Resources Information Center

    Abanikannda, Mutahir Oluwafemi

    2016-01-01

    This study provides a framework for the production of Hypermedia Instructional package. It also assessed the effectiveness of hypermedia instructional mode of delivery on students? performance in Chemistry. This is with a view of improving the learning of Chemistry which may eventually help to improve students? performance. The developmental study…

  10. Verification of gyrokinetic particle simulation of current-driven instability in fusion plasmas. III. Collisionless tearing mode

    NASA Astrophysics Data System (ADS)

    Liu, Dongjian; Bao, Jian; Han, Tao; Wang, Jiaqi; Lin, Zhihong

    2016-02-01

    A finite-mass electron fluid model for low frequency electromagnetic fluctuations, particularly the collisionless tearing mode, has been implemented in the gyrokinetic toroidal code. Using this fluid model, linear properties of the collisionless tearing mode have been verified. Simulations verify that the linear growth rate of the single collisionless tearing mode is proportional to De2, where De is the electron skin depth. On the other hand, the growth rate of a double tearing mode is proportional to De in the parameter regime of fusion plasmas.

  11. Radiation effects on III-V heterostructure devices

    NASA Astrophysics Data System (ADS)

    Jun, Bongim

    The neutron and electron radiation effects in III-V compound semiconductor heterostructure devices are studied in this thesis. Three types of devices investigated are AlGaAs/GaAs high electron mobility transistors (HEMTs), AlGaAs/InGaAs/GaAs heterostructure insulated gate field effect transistors (HIGFETs), and InP/InGaAs/InGaAs single heterojunction bipolar transistors (SHBTs). HEMTs and HIGFETs are primarily investigated for neutron irradiation effects. Detailed optimized processing of HEMT devices is introduced. Numerical as well as analytical models that incorporate radiation-induced degradation effects in HEMTs and HIGFETs are developed. The most prominent radiation effects appearing on both HEMT and HIGFET devices are increase of threshold voltage (VT) and decrease of transconductance (gm) as radiation dose increases. These effects are responsible for drain current degradation under given bias conditions after irradiation. From our experimental neutron irradiation study and our theoretical models, we concluded that threshold voltage increase is due to the radiation-induced acceptor-like (negatively charged) traps in the GaAs channel region removing carriers. The mobility degradation in the channel is responsible for gm decrease. Series resistance increase is also related to carrier removal and mobility degradation. Traps introduced in the GaAs region affect the device performance more than the traps in the AlGaAs doped region. V T and gm of HIGFET devices are less affected by neutron radiation than they are in HEMTs. This difference is attributed to different shapes of the quantum well in the two devices. The main effects of electron and neutron irradiation of SHBTs are decrease of collector current (IC), decrease of common-emitter DC gain, increase of the collector output conductance (DeltaI C/DeltaVCE), and increase of collector-collector offset voltage. The decrease of breakdown voltage of reverse biased base-emitter junction diode is responsible for

  12. Failure Modes and Effects Analysis (FMEA): A Bibliography

    NASA Technical Reports Server (NTRS)

    2000-01-01

    Failure modes and effects analysis (FMEA) is a bottom-up analytical process that identifies process hazards, which helps managers understand vulnerabilities of systems, as well as assess and mitigate risk. It is one of several engineering tools and techniques available to program and project managers aimed at increasing the likelihood of safe and successful NASA programs and missions. This bibliography references 465 documents in the NASA STI Database that contain the major concepts, failure modes or failure analysis, in either the basic index of the major subject terms.

  13. Effect of Population III Multiplicity on Dark Star Formation

    NASA Technical Reports Server (NTRS)

    Stacy, Athena; Pawlik, Andreas H.; Bromm, Volker; Loeb, Abraham

    2012-01-01

    We numerically study the mutual interaction between dark matter (DM) and Population III (Pop III) stellar systems in order to explore the possibility of Pop III dark stars within this physical scenario. We perform a cosmological simulation, initialized at z approx. 100, which follows the evolution of gas and DM. We analyze the formation of the first mini halo at z approx. 20 and the subsequent collapse of the gas to densities of 10(exp 12)/cu cm. We then use this simulation to initialize a set of smaller-scale 'cut-out' simulations in which we further refine the DM to have spatial resolution similar to that of the gas. We test multiple DM density profiles, and we employ the sink particle method to represent the accreting star-forming region. We find that, for a range of DM configurations, the motion of the Pop III star-disk system serves to separate the positions of the protostars with respect to the DM density peak, such that there is insufficient DM to influence the formation and evolution of the protostars for more than approx. 5000 years. In addition, the star-disk system causes gravitational scattering of the central DM to lower densities, further decreasing the influence of DM over time. Any DM-powered phase of Pop III stars will thus be very short-lived for the typical multiple system, and DM will not serve to significantly prolong the life of Pop III stars.

  14. Stabilization effect of Weibel modes in relativistic laser fusion plasma

    NASA Astrophysics Data System (ADS)

    Belghit, Slimen; Sid, Abdelaziz

    2016-06-01

    In this work, the Weibel instability (WI) due to inverse bremsstrahlung (IB) absorption in a laser fusion plasma has been investigated. The stabilization effect due to the coupling of the self-generated magnetic field by WI with the laser wave field is explicitly shown. In this study, the relativistic effects are taken into account. Here, the basic equation is the relativistic Fokker-Planck (F-P) equation. The main obtained result is that the coupling of self-generated magnetic field with the laser wave causes a stabilizing effect of excited Weibel modes. We found a decrease in the spectral range of Weibel unstable modes. This decreasing is accompanied by a reduction of two orders in the growth rate of instable Weibel modes or even stabilization of these modes. It has been shown that the previous analysis of the Weibel instability due to IB has overestimated the values of the generated magnetic fields. Therefore, the generation of magnetic fields by the WI due to IB should not affect the experiences of an inertial confinement fusion.

  15. The effect of mixed mode precracking on the mode 1 fracture toughness of composite laminates

    NASA Technical Reports Server (NTRS)

    Shankar, Prashanth; Bascom, Williard D.; Nairn, John A.

    1993-01-01

    We subjected double cantilever beam specimens from four different composite materials to mixed-mode precracking. Three different precracking mode 1 to mode 2 ratios were used--1 to 4, 1 to 1, and 4 to 1. Following precracking the specimens were tested for mode I fracture toughness. The mixed-mode precracking often influenced the mode 1 toughness and its influence persisted for as much as 60 mm of mode 1 crack growth. We tested composites with untoughened matrices, composites with rubber-toughened matrices, and composites with interlayer toughening. Depending on material type and precracking mode ratio, the precracking could cause either a significant increase or a significant decrease in the mode 1 fracture toughness.

  16. Failure mode and effect analysis-based quality assurance for dynamic MLC tracking systems

    SciTech Connect

    Sawant, Amit; Dieterich, Sonja; Svatos, Michelle; Keall, Paul

    2010-12-15

    Purpose: To develop and implement a failure mode and effect analysis (FMEA)-based commissioning and quality assurance framework for dynamic multileaf collimator (DMLC) tumor tracking systems. Methods: A systematic failure mode and effect analysis was performed for a prototype real-time tumor tracking system that uses implanted electromagnetic transponders for tumor position monitoring and a DMLC for real-time beam adaptation. A detailed process tree of DMLC tracking delivery was created and potential tracking-specific failure modes were identified. For each failure mode, a risk probability number (RPN) was calculated from the product of the probability of occurrence, the severity of effect, and the detectibility of the failure. Based on the insights obtained from the FMEA, commissioning and QA procedures were developed to check (i) the accuracy of coordinate system transformation, (ii) system latency, (iii) spatial and dosimetric delivery accuracy, (iv) delivery efficiency, and (v) accuracy and consistency of system response to error conditions. The frequency of testing for each failure mode was determined from the RPN value. Results: Failures modes with RPN{>=}125 were recommended to be tested monthly. Failure modes with RPN<125 were assigned to be tested during comprehensive evaluations, e.g., during commissioning, annual quality assurance, and after major software/hardware upgrades. System latency was determined to be {approx}193 ms. The system showed consistent and accurate response to erroneous conditions. Tracking accuracy was within 3%-3 mm gamma (100% pass rate) for sinusoidal as well as a wide variety of patient-derived respiratory motions. The total time taken for monthly QA was {approx}35 min, while that taken for comprehensive testing was {approx}3.5 h. Conclusions: FMEA proved to be a powerful and flexible tool to develop and implement a quality management (QM) framework for DMLC tracking. The authors conclude that the use of FMEA-based QM ensures

  17. Asymmetric large-mode-area photonic crystal fiber structure with effective single-mode operation: design and analysis.

    PubMed

    Saini, Than Singh; Kumar, Ajeet; Sinha, Ravindra Kumar

    2016-03-20

    The asymmetrical structure of photonic crystal fiber has been reported for a large mode area with the single-mode operation. The design works on the principle of bend-induced mode filtering. The proposed structure can be designed (i) by introducing down-doped material rods in place of nine air holes of the inner ring near the core of the structure and (ii) by increasing the diameter of the rest of the three air holes of the same ring in the direction of bending. These three air holes together with nine down-doped material rods control the mode field inside the core region and hence the bending losses of the modes. The single-mode operation is ensured by introducing high bend loss for the first higher order mode and very low bend loss for the fundamental mode. The finite-element-method-based anisotropic perfectly matched layer boundary condition has been applied for accurate analysis of bend loss of the structure. Numerical results show that effective single-mode operation can be ensured with a mode area as large as 1530  μm2 at bend state with a bend radius of 30 cm. The proposed photonic crystal optical fiber with such a large mode area can have potential applications in compact high-power delivery devices such as high-power fiber lasers and amplifiers. PMID:27140567

  18. Mode splitting effect in FEMs with oversized Bragg resonators

    NASA Astrophysics Data System (ADS)

    Peskov, N. Yu.; Kaminsky, A. K.; Kuzikov, S. V.; Perelstein, E. A.; Sedykh, S. N.; Sergeev, A. S.

    2016-07-01

    Splitting of the fundamental mode in an oversized Bragg resonator with a step of the corrugation phase, which operates over the feedback loop involving the waveguide waves of different transverse structures, was found to be the result of mutual influence of the neighboring zones of the Bragg scattering. Theoretical description of this effect was developed within the framework of the advanced (four-wave) coupled-wave approach. It is shown that mode splitting reduces the selective properties, restricts the output power, and decreases the stability of the narrow-band operating regime in the free-electron maser (FEM) oscillators based on such resonators. The results of the theoretical analysis were confirmed by 3D simulations and "cold" microwave tests. Experimental data on Bragg resonators with different parameters in a 30-GHz FEM are presented. The possibility of reducing the mode splitting by profiling the corrugation parameters is shown. The use of the mode splitting effect for the output power enhancement by passive compression of the double-frequency pulse generated in the FEM with such a resonator is discussed.

  19. Effects of magnetosonic perturbations on electron temperature gradient driven modes and the stability of skin depth sized electron ballooning modes

    SciTech Connect

    Joiner, N.; Hirose, A.

    2007-11-15

    The effect of the magnetosonic perturbation {delta}B{sub parallel} on the growth of electron temperature gradient driven (ETG) modes and electron temperature gradient driven ballooning modes [Hirose, Plasma Phys. Control. Fusion 49, 145 (2007)] is investigated using local gyrokinetic analysis and numerical solution, with supporting simulations from the initial value code GS2 [Kotschenreuther, et al., Comp. Phys. Commun. 88, 128 (1996)]. The effect of {delta}B{sub parallel} on the ETG mode is found to depend on the competition between two physical processes related to magnetosonic compression. Local analysis of the ballooning mode appears to significantly overestimate growth rates of this instability. The electron temperature gradient driven ballooning mode has been observed in GS2 simulations. However, this work supports the conclusion that this instability will be subdominant to the ETG mode in normal tokamak regimes.

  20. The effect of the edge current density on confinement and kink mode stability in H-mode and VH-mode discharges

    SciTech Connect

    Ferron, J.R.; Lao, L.L.; Osborne, T.H.; Strait, E.J.; Taylor, T.S.; Thompson, S.J.; Turnbull, A.D.; Sauter, O.

    1994-07-01

    The effect of the local current density in the outer portion of a tokamak discharge [J({rho} {approximately} a)] is discussed in three situations. In a H-mode discharge, a strong reduction of J({rho} {approximately} a) results in the loss of the H-mode pressure pedestal. A smaller reduction in J({rho} {approximately} a) can prevent the transition from H-mode to VH-mode. Finally, a sufficiently large value of J({rho} {approximately} a) accompanied by a sufficiently large value of the pressure gradient in the same region of the discharge, can destabilize low-n (e.g., n = 1 to 5) kink-type modes in a VH-mode discharge. Conference Information: European conference on controlled fusion and plasma physics, Montpellier (France), 26 Jun - 1 Jul 1994

  1. Application of failure mode and effects analysis to treatment planning in scanned proton beam radiotherapy

    PubMed Central

    2013-01-01

    Background A multidisciplinary and multi-institutional working group applied the Failure Mode and Effects Analysis (FMEA) approach to the actively scanned proton beam radiotherapy process implemented at CNAO (Centro Nazionale di Adroterapia Oncologica), aiming at preventing accidental exposures to the patient. Methods FMEA was applied to the treatment planning stage and consisted of three steps: i) identification of the involved sub-processes; ii) identification and ranking of the potential failure modes, together with their causes and effects, using the risk probability number (RPN) scoring system, iii) identification of additional safety measures to be proposed for process quality and safety improvement. RPN upper threshold for little concern of risk was set at 125. Results Thirty-four sub-processes were identified, twenty-two of them were judged to be potentially prone to one or more failure modes. A total of forty-four failure modes were recognized, 52% of them characterized by an RPN score equal to 80 or higher. The threshold of 125 for RPN was exceeded in five cases only. The most critical sub-process appeared related to the delineation and correction of artefacts in planning CT data. Failures associated to that sub-process were inaccurate delineation of the artefacts and incorrect proton stopping power assignment to body regions. Other significant failure modes consisted of an outdated representation of the patient anatomy, an improper selection of beam direction and of the physical beam model or dose calculation grid. The main effects of these failures were represented by wrong dose distribution (i.e. deviating from the planned one) delivered to the patient. Additional strategies for risk mitigation, easily and immediately applicable, consisted of a systematic information collection about any known implanted prosthesis directly from each patient and enforcing a short interval time between CT scan and treatment start. Moreover, (i) the investigation of

  2. EFFECTS OF ASYMMETRIC FLOWS IN SOLAR CONVECTION ON OSCILLATION MODES

    SciTech Connect

    Baldner, Charles S.; Schou, Jesper

    2012-11-20

    Many helioseismic measurements suffer from substantial systematic errors. A particularly frustrating one is that time-distance measurements suffer from a large center to limb effect which looks very similar to the finite light travel time, except that the magnitude depends on the observable used and can have the opposite sign. This has frustrated attempts to determine the deep meridional flow in the solar convection zone, with Zhao et al. applying an ad hoc correction with little physical basis to correct the data. In this Letter, we propose that part of this effect can be explained by the highly asymmetrical nature of the solar granulation which results in what appears to the oscillation modes as a net radial flow, thereby imparting a phase shift on the modes as a function of observing height and thus heliocentric angle.

  3. Failure Mode Effects Analysis for an Accelerator Control System

    SciTech Connect

    Hartman, Steven M

    2009-01-01

    Failure mode effects analysis (FMEA) has been used in industry for design, manufacturing and assembly process quality control. It describes a formal approach for categorizing how a process may fail and for prioritizing failures based on their severity, frequency and likelihood of detection. Experience conducting a partial FMEA of an accelerator subsystem and its related control system will be reviewed. The applicability of the FMEA process to an operational accelerator control system will be discussed.

  4. Effects of difructose anhydride III (DFA III) administration on bile acids and growth of DFA III-assimilating bacterium Ruminococcus productus on rat intestine.

    PubMed

    Minamida, Kimiko; Kaneko, Maki; Ohashi, Midori; Sujaya, I Nengah; Sone, Teruo; Wada, Masaru; Yokota, Atsushi; Hara, Hiroshi; Asano, Kozo; Tomita, Fusao

    2005-06-01

    The growth of DFA III-assimilating bacteria in the intestines of rats fed 3% DFA III for 2 weeks was examined. Sixty-four percent of the DFA III intake had been assimilated on day 3 of ingestion, and almost all of the DFA III was assimilated at the end of the experiment. The DFA III-assimilating bacterium, Ruminococcus productus, in DFA III-fed rats was in the stationary state of 10(8)-10(9) cells/g dry feces within a week from 10(6) cells/g dry feces on day 1 of DFA III ingestion. The number of R. productus cells was associated with the amount of DFA III excreted in the feces. The acetic acid produced from DFA III by R. productus lowered the cecal pH to 5.8. In control-fed rats and DFA III-fed rats, 94% of secondary bile acids and 94% of primary bile acids, respectively, were accounted for in the total bile acids analyzed. DFA III ingestion increased the ratio of primary bile acids and changed the composition of fecal bile acids. In conclusion, R. productus assimilated DFA III, produced short chain fatty acids, and the cecal pH was lowered. The acidification of rat intestine perhaps inhibited secondary bile acid formation and decreased the ratio of secondary bile acids. Therefore, it is expected that DFA III may prevent colorectal cancer and be a new prebiotic candidate. PMID:16233830

  5. The Effect of Administration Mode on Test Performance and Score Precision, and Some Factors Contributing to Mode Differences.

    ERIC Educational Resources Information Center

    Pommerich, Mary

    This paper considers differences in modes of test administration, addressing three questions: (1) Do examinees respond to items in the same way across administration modes and computer interface variations? (2) What are some of the factors that can contribute to modal effects? and (3) Can item parameters calibrated from paper and pencil…

  6. 25 CFR 291.13 - When do Class III gaming procedures for an Indian tribe become effective?

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false When do Class III gaming procedures for an Indian tribe... ECONOMIC ENTERPRISES CLASS III GAMING PROCEDURES § 291.13 When do Class III gaming procedures for an Indian tribe become effective? Upon approval of Class III gaming procedures for the Indian tribe under...

  7. Microstructural effects on fracture toughness of polycrystalline ceramics in combined mode I and mode II loading

    NASA Technical Reports Server (NTRS)

    Singh, D.; Shetty, D. K.

    1988-01-01

    Fracture toughness of polycrystalline alumina and ceria partially-stabilized tetragonal zirconia (CeO2-TZP) ceramics were assessed in combined mode I and mode II loading using precracked disk specimens in diametral compression. Stress states ranging from pure mode I, combined mode I and mode II, and pure mode II were obtained by aligning the center crack at specific angles relative to the loading diameter. The resulting mixed-mode fracture toughness envelope showed significant deviation to higher fracture toughness in mode II relative to the predictions of the linear elastic fracture mechanics theory. Critical comparison with corresponding results on soda-lime glass and fracture surface observations showed that crack surface resistance arising from grain interlocking and abrasion was the main source of the increased fracture toughness in mode II loading of the polycrystalline ceramics. The normalized fracture toughness for pure mode II loading, (KII/KIc), increased with increasing grain size for the CeO2-TZP ceramics. Quantitative fractography confirmed an increased percentage of transgranular fracture of the grains in mode II loading.

  8. Acoustic attenuation, phase and group velocities in liquid-filled pipes III: nonaxisymmetric propagation and circumferential modes in lossless conditions.

    PubMed

    Baik, Kyungmin; Jiang, Jian; Leighton, Timothy G

    2013-03-01

    Equations for the nonaxisymmetric modes that are axially and circumferentially propagating in a liquid-filled tube with elastic walls surrounded by air/vacuum are presented using exact elasticity theory. Dispersion curves for the axially propagating modes are obtained and verified through comparison with measurements. The resulting theory is applied to the circumferential modes, and the pressures and the stresses in the liquid-filled pipe are calculated under external forced oscillation by an acoustic source. This provides the theoretical foundation for the narrow band acoustic bubble detector that was subsequently deployed at the Target Test Facility (TTF) of the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL), TN. PMID:23463995

  9. Linear canonical transformations of coherent and squeezed states in the Wigner phase space. III - Two-mode states

    NASA Technical Reports Server (NTRS)

    Han, D.; Kim, Y. S.; Noz, Marilyn E.

    1990-01-01

    It is shown that the basic symmetry of two-mode squeezed states is governed by the group SP(4) in the Wigner phase space which is locally isomorphic to the (3 + 2)-dimensional Lorentz group. This symmetry, in the Schroedinger picture, appears as Dirac's two-oscillator representation of O(3,2). It is shown that the SU(2) and SU(1,1) interferometers exhibit the symmetry of this higher-dimensional Lorentz group. The mathematics of two-mode squeezed states is shown to be applicable to other branches of physics including thermally excited states in statistical mechanics and relativistic extended hadrons in the quark model.

  10. Magnetospheric filter effect for Pc 3 Alfven mode waves

    NASA Technical Reports Server (NTRS)

    Zhang, X.; Comfort, R. H.; Gallagher, D. L.; Green, J. L.; Musielak, Z. E.; Moore, T. E.

    1995-01-01

    We present a ray-tracing study of the propagation of Pc 3 Alfven mode waves originating at the dayside magnetopause. This study reveals interesting features of magnetospheric filter effect for these waves. Pc 3 Alfven mode waves cannot penetrate to low Earth altitudes unless the wave frequency is below approximately 30 mHz. Configurations of the dispersion curves and the refractive index show that the gyroresonance and pseudo-cutoff introduced by the heavy ion O(+) block the waves. When the O(+) concentration is removed from the plasma composition, the barriers caused by the O(+) no longer exist, and waves with much higher frequencies than 30 mHz can penetrate to low altitudes. The result that the 30 mHz or lower frequency Alfven waves can be guided to low altitudes agrees with ground-based power spectrum observation at high altitudes.

  11. Magnetospheric filter effect for Pc 3 Alfven mode waves

    NASA Technical Reports Server (NTRS)

    Zhang, X.; Comfort, R. H.; Gallagher, D. L.; Green, J. L.; Musielak, Z. E.; Moore, T. E.

    1994-01-01

    We present a ray-tracing study of the propagation of Pc 3 Alfven mode waves originating at the dayside magnetopause. This study reveals interesting features of a magnetospheric filter effect for these waves. Pc 3 Alfven mode waves cannot penetrate to low Earth altitudes unless the wave frequency is below approximately 30 mHz. Configurations of the dispersion curves and the refractive index show that the gyroresonance and pseudo-cutoff introduced by the heavy ion O(+) block the waves. When the O(+) concentration is removed from the plasma composition, the barriers caused by the O(+) no longer exist, and waves with much higher frequencies than 30 mHz can penetrate to low altitudes. The result that the 30 mHz or lower frequency Alfven waves can be guided to low altitudes agrees with ground-based power spectrum observations at high latitudes.

  12. Atomic physics effects on tokamak edge drift-tearing modes

    SciTech Connect

    Hahm, T.S.

    1993-03-01

    The effects of ionization and charge exchange on the linear stability of drift-tearing modes are analytically investigated. In particular, the linear instability threshold {Delta}{sup Th}, produced by ion sound wave coupling is modified. In the strongly collisional regime, the ionization breaks up the near cancellation of the perturbed electric field and the pressure gradient along the magnetic field, and increases the threshold. In the semi-collisional regime, both ionization and charge exchange act as drag on the ion parallel velocity, and consequently decrease the threshold by reducing the effectiveness of ion sound wave propagation.

  13. Atomic physics effects on tokamak edge drift-tearing modes

    SciTech Connect

    Hahm, T.S.

    1993-03-01

    The effects of ionization and charge exchange on the linear stability of drift-tearing modes are analytically investigated. In particular, the linear instability threshold [Delta][sup Th], produced by ion sound wave coupling is modified. In the strongly collisional regime, the ionization breaks up the near cancellation of the perturbed electric field and the pressure gradient along the magnetic field, and increases the threshold. In the semi-collisional regime, both ionization and charge exchange act as drag on the ion parallel velocity, and consequently decrease the threshold by reducing the effectiveness of ion sound wave propagation.

  14. Proton irradiation effects on advanced digital and microwave III-V components

    SciTech Connect

    Hash, G.L.; Schwank, J.R.; Shaneyfelt, M.R.; Sandoval, C.E.; Connors, M.P.; Sheridan, T.J.; Sexton, F.W.; Slayton, E.M.; Heise, J.A.; Foster, C.

    1994-09-01

    A wide range of advanced III-V components suitable for use in high-speed satellite communication systems were evaluated for displacement damage and single-event effects in high-energy, high-fluence proton environments. Transistors and integrated circuits (both digital and MMIC) were irradiated with protons at energies from 41 to 197 MeV and at fluences from 10{sup 10} to 2 {times} 10{sup 14} protons/cm{sup 2}. Large soft-error rates were measured for digital GaAs MESFET (3 {times} 10{sup {minus}5} errors/bit-day) and heterojunction bipolar circuits (10{sup {minus}5} errors/bit-day). No transient signals were detected from MMIC circuits. The largest degradation in transistor response caused by displacement damage was observed for 1.0-{mu}m depletion- and enhancement-mode MESFET transistors. Shorter gate length MESFET transistors and HEMT transistors exhibited less displacement-induced damage. These results show that memory-intensive GaAs digital circuits may result in significant system degradation due to single-event upset in natural and man-made space environments. However, displacement damage effects should not be a limiting factor for fluence levels up to 10{sup 14} protons/cm{sup 2} [equivalent to total doses in excess of 10 Mrad(GaAs)].

  15. Fiber pressure sensors based on periodical mode coupling effects

    NASA Astrophysics Data System (ADS)

    Lotem, Haim; Wang, Wen C.; Wang, Michael; Schaafsma, David; Skolnick, Bob; Grebel, Haim

    2005-05-01

    Fiber optic sensor technology offers the possibility of implementing low weight, high performance and cost effective health and damage assessment for infrastructure elements. Common fiber sensors are based on the effect of external action on the spectral response of a Fabry-Perot or a Bragg grating section, or on the modal dynamics in multimode (MM) fiber. In the latter case, the fiber itself acts as the sensor, giving it the potential for large range coverage. We were interested in this type of sensor because of its cost advantage in monitoring structural health. In the course of the research, a new type of a rugged modal filter device, based on off-center splicing, was developed. This device, in combination with a MM fiber, was found to be a potential single point-pressure sensing device. Additionally, by translating the pressing point along a MM sensing fiber with a constant load and speed, a sinusoidal intensity modulation was observed. This harmonic behavior, during load translation, is explained by the theory of mode coupling and dispersion. The oscillation period, L~0.43. mm, obtained at 980 nm in a Corning SMF-28 fiber, corresponds to the wavevector difference, Db, between the two-coupled modes, by L = 2p/Db. An additional outcome of the present research is the observation that the response of the loaded MM fiber is strongly dependent on the polarization state of the light traveling along the MM fiber due to different response of the modes to polarization active elements. Our main conclusions are that in MM fiber optic sensor design, special cautions need to be taken in order to stabilize the system, and that the sensitivity along a MM fiber sensor is periodic with a period of ~ 0.4 - 0.5 mm, depending on various fiber parameters and excited modes.

  16. Hydrodynamic effects of the tip movement on surface nanobubbles: a combined tapping mode, lift mode and force volume mode AFM study.

    PubMed

    Walczyk, Wiktoria; Hain, Nicole; Schönherr, Holger

    2014-08-28

    We report on an Atomic Force Microscopy (AFM) study of AFM tip-nanobubble interactions in experiments conducted on argon surface nanobubbles on HOPG (highly oriented pyrolytic graphite) in water in tapping mode, lift mode and Force Volume (FV) mode AFM. By subsequent data acquisition on the same nanobubbles in these three different AFM modes, we could directly compare the effect of different tip-sample interactions. The tip-bubble interaction strength was found to depend on the vertical and horizontal position of the tip on the bubble with respect to the bubble center. The interaction forces measured experimentally were in good agreement with the forces calculated using the dynamic interaction model. The strength of the hydrodynamic effect was also found to depend on the direction of the tip movement. It was more pronounced in the FV mode, in which the tip approaches the bubble from the top, than in the lift mode, in which the tip approaches the bubble from the side. This result suggests that the direction of tip movement influences the bubble deformation. The effect should be taken into account when nanobubbles are analysed by AFM in various scanning modes. PMID:24988375

  17. Impurity effects on trapped electron mode in tokamak plasmas

    NASA Astrophysics Data System (ADS)

    Du, Huarong; Wang, Zheng-Xiong; Dong, J. Q.

    2016-07-01

    The effects of impurity ions on the trapped electron mode (TEM) in tokamak plasmas are numerically investigated with the gyrokinetic integral eigenmode equation. It is shown that in the case of large electron temperature gradient ( η e ), the impurity ions have stabilizing effects on the TEM, regardless of peaking directions of their density profiles for all normalized electron density gradient R / L n e . Here, R is the major radius and L n e is the electron density gradient scale length. In the case of intermediate and/or small η e , the light impurity ions with conventional inwardly (outwardly) peaked density profiles have stabilizing effects on the TEM for large (small) R / L n e , while the light impurity ions with steep inwardly (outwardly) peaked density profiles can destabilize the TEM for small (large) R / L n e . Besides, the TEM driven by density gradient is stabilized (destabilized) by the light carbon or oxygen ions with inwardly (outwardly) peaked density profiles. In particular, for flat and/or moderate R / L n e , two independent unstable modes, corresponding respectively to the TEM and impurity mode, are found to coexist in plasmas with impurity ions of outwardly peaked density profiles. The high Z tungsten impurity ions play a stronger stabilizing role in the TEM than the low Z impurity ions (such as carbon and oxygen) do. In addition, the effects of magnetic shear and collision on the TEM instability are analyzed. It is shown that the collisionality considered in this work weakens the trapped electron response, leading to a more stable TEM instability, and that the stabilizing effects of the negative magnetic shear on the TEM are more significant when the impurity ions with outwardly peaked density profile are taken into account.

  18. Development and Application of Benchmark Examples for Mixed-Mode I/II Quasi-Static Delamination Propagation Predictions

    NASA Technical Reports Server (NTRS)

    Krueger, Ronald

    2012-01-01

    The development of benchmark examples for quasi-static delamination propagation prediction is presented and demonstrated for a commercial code. The examples are based on finite element models of the Mixed-Mode Bending (MMB) specimen. The examples are independent of the analysis software used and allow the assessment of the automated delamination propagation prediction capability in commercial finite element codes based on the virtual crack closure technique (VCCT). First, quasi-static benchmark examples were created for the specimen. Second, starting from an initially straight front, the delamination was allowed to propagate under quasi-static loading. Third, the load-displacement relationship from a propagation analysis and the benchmark results were compared, and good agreement could be achieved by selecting the appropriate input parameters. Good agreement between the results obtained from the automated propagation analysis and the benchmark results could be achieved by selecting input parameters that had previously been determined during analyses of mode I Double Cantilever Beam and mode II End Notched Flexure specimens. The benchmarking procedure proved valuable by highlighting the issues associated with choosing the input parameters of the particular implementation. Overall the results are encouraging, but further assessment for mixed-mode delamination fatigue onset and growth is required.

  19. The Emotional Child Witness Effect Survives Presentation Mode.

    PubMed

    Melinder, Annika; Burrell, Lisa; Eriksen, Maria Olaussen; Magnussen, Svein; Wessel, Ellen

    2016-01-01

    The emotional witness effect - the phenomenon whereby people are affected by the emotional manner in which a witness presents testimony - constitutes a possible source of wrongful decisions in legal contexts. One stereotypical view of abused children is that they should be sad when talking about their experiences of maltreatment, whereas children may in fact express a variety of emotional expressions when talking about abusive events. This raises the question as to whether there is an optimal mode in which to present child victim testimony that could reduce the possible influence of displayed emotions. In the present study, mock police interviews were carried out with female child actors, role-playing the victims of physical abuse by their stepfather, telling the same story with four emotional expressions (neutral, sad, angry, or positive). Laypersons (N = 465) were presented with the interviews as transcripts with the emotional reactions of the child witness noted, audio recordings, or videotaped recordings. Participants then rated the credibility of the victim witness. Replicating previous results, the "sad" expression elicited the highest credibility ratings across all modes of presentations. Presentation mode affected ratings of credibility, with the transcript versions resulting in the highest ratings. Copyright © 2016 John Wiley & Sons, Ltd. PMID:26990221

  20. Estimation of the isotope effect on the lattice thermal conductivity of group IV and group III-V semiconductors

    NASA Astrophysics Data System (ADS)

    Morelli, D. T.; Heremans, J. P.; Slack, G. A.

    2002-11-01

    The isotope effect on the lattice thermal conductivity for group IV and group III-V semiconductors is calculated using the Debye-Callaway model modified to include both transverse and longitudinal phonon modes explicitly. The frequency and temperature dependences of the normal and umklapp phonon-scattering rates are kept the same for all compounds. The model requires as adjustable parameters only the longitudinal and transverse phonon Grüneisen constants and the effective sample diameter. The model can quantitatively account for the observed isotope effect in diamond and germanium but not in silicon. The magnitude of the isotope effect is predicted for silicon carbide, boron nitride, and gallium nitride. In the case of boron nitride the predicted increase in the room-temperature thermal conductivity with isotopic enrichment is in excess of 100%. Finally, a more general method of estimating normal phonon-scattering rate coefficients for other types of solids is presented.

  1. Effects of Humidity on Non-Hermetically Packaged III-V Structures and Devices

    NASA Technical Reports Server (NTRS)

    Leon, R.; Martin, S.; Lee, T.; Okuno, J.; Ruiz, R.; Gauldin, R.; Gaidis, M.; Smith, R.

    1999-01-01

    High humidity and temperature test (known as 85/85 tests) were performed on various III-V devices and structures to determine environmental effects in non-hermetically packaged GaAs membrane mixer diodes.

  2. Kinetic description of collective oscillations in a system of parametric spin waves. III. Long-wave collective modes

    SciTech Connect

    Morozov, V.G.; Mukhai, A.N.

    1988-10-01

    Long-wave collective oscillations in a system of parametric spin waves of a ferromagnet are studied on the basis of the kinetic equations for the Wigner distribution functions of the magnons. A study is made of the linear response of the magnetization m to a change in the internal field h (in the case of deviation of a packet of parametric waves from a stationary state), and boundary-value problem for finding the eigenfrequencies of the collective modes in a sample of finite volume is formulated. It is shown that allowance for the influence of the boundary conditions leads to discreteness of the frequency spectrum of the collective modes in the region of wave numbers q of the order of the reciprocal sample dimension L/sup /minus/1/. For a spherical sample, expressions are obtained for the discrete frequencies of long-wave collective modes corresponding to oscillations with longitudinal component h/sub z/ of the internal field that does not depend on the coordinate z. Criteria for stability of stationary states of the ferromagnet with respect to the excitation of auto-oscillations are obtained.

  3. Development and Application of Benchmark Examples for Mixed-Mode I/II Quasi-Static Delamination Propagation Predictions

    NASA Technical Reports Server (NTRS)

    Krueger, Ronald

    2012-01-01

    The development of benchmark examples for quasi-static delamination propagation prediction is presented. The example is based on a finite element model of the Mixed-Mode Bending (MMB) specimen for 50% mode II. The benchmarking is demonstrated for Abaqus/Standard, however, the example is independent of the analysis software used and allows the assessment of the automated delamination propagation prediction capability in commercial finite element codes based on the virtual crack closure technique (VCCT). First, a quasi-static benchmark example was created for the specimen. Second, starting from an initially straight front, the delamination was allowed to propagate under quasi-static loading. Third, the load-displacement as well as delamination length versus applied load/displacement relationships from a propagation analysis and the benchmark results were compared, and good agreement could be achieved by selecting the appropriate input parameters. The benchmarking procedure proved valuable by highlighting the issues associated with choosing the input parameters of the particular implementation. Overall, the results are encouraging, but further assessment for mixed-mode delamination fatigue onset and growth is required.

  4. Effects of damping on mode shapes, volume 1

    NASA Technical Reports Server (NTRS)

    Gates, R. M.

    1977-01-01

    Displacement, velocity, and acceleration admittances were calculated for a realistic NASTRAN structural model of space shuttle for three conditions: liftoff, maximum dynamic pressure and end of solid rocket booster burn. The realistic model of the orbiter, external tank, and solid rocket motors included the representation of structural joint transmissibilities by finite stiffness and damping elements. Methods developed to incorporate structural joints and their damping characteristics into a finite element model of the space shuttle, to determine the point damping parameters required to produce realistic damping in the primary modes, and to calculate the effect of distributed damping on structural resonances through the calculation of admittances.

  5. Failure modes and effects analysis in clinical engineering.

    PubMed

    Willis, G

    1992-01-01

    Failure modes and effects analysis (FMEA) is a proactive quality assurance procedure that has been commonly used to address potential design flaws and product misuses during the design stage of a product's life. FMEA is becoming commonplace among manufacturing companies but is relatively unknown outside of manufacturing circles. One potential new application of FMEA is by medical device end-users who could address design or functional concerns specific to their situation. The continued increase in the amount and complexity of medical instrumentation necessitates an aggressive stance towards safety in each hospital, such as is recommended in this paper. PMID:10117004

  6. Effects of mean flow on duct mode optimum suppression rates

    NASA Technical Reports Server (NTRS)

    Kraft, R. E.; Wells, W. R.

    1976-01-01

    The nature of the solution to the convected acoustic wave equation and associated boundary conditions for rectangular ducts containing uniform mean flow is examined in terms of the complex mapping between the wall admittance and characteristic mode eigenvalues. It is shown that the Cremer optimum suppression criteria must be modified to account for the effects of flow below certain critical values of the nondimensional frequency parameter of duct height divided by sound wavelength. The implications of these results on the design of low frequency suppressors are considered.

  7. Reflective liquid crystal light valve with hybrid field effect mode

    NASA Technical Reports Server (NTRS)

    Boswell, Donald D. (Inventor); Grinberg, Jan (Inventor); Jacobson, Alexander D. (Inventor); Myer, Gary D. (Inventor)

    1977-01-01

    There is disclosed a high performance reflective mode liquid crystal light valve suitable for general image processing and projection and particularly suited for application to real-time coherent optical data processing. A preferred example of the device uses a CdS photoconductor, a CdTe light absorbing layer, a dielectric mirror, and a liquid crystal layer sandwiched between indium-tin-oxide transparent electrodes deposited on optical quality glass flats. The non-coherent light image is directed onto the photoconductor; this reduces the impedance of the photoconductor, thereby switching the AC voltage that is impressed across the electrodes onto the liquid crystal to activate the device. The liquid crystal is operated in a hybrid field effect mode. It utilizes the twisted nematic effect to create a dark off-state (voltage off the liquid crystal) and the optical birefringence effect to create the bright on-state. The liquid crystal thus modulates the polarization of the coherent read-out or projection light responsively to the non-coherent image. An analyzer is used to create an intensity modulated output beam.

  8. Effects of H content on the tensile properties and fracture behavior of SA508-III steel

    NASA Astrophysics Data System (ADS)

    Liu, Jia-hua; Wang, Lei; Liu, Yang; Song, Xiu; Luo, Jiong; Yuan, Dan

    2015-08-01

    SA508-III steel was charged with different hydrogen (H) contents using a high-pressure thermal charging method to study the effects of H content on the tensile properties and evaluate the H embrittlement behavior of the steel. The results indicate that the ultimate tensile strength remains nearly unchanged with the addition of H. In contrast, the yielding strength slightly increases, and the elongation significantly decreases with increasing H content, especially at concentrations exceeding 5.6 × 10-6. On the basis of fractographic analysis, it is clear that the addition of H changes the fracture mode from microvoid coalescence to a mixture of river patterns and dimples. Carbides are strong traps for H; thus, the H atoms easily migrate in the form of Cottrell atmosphere toward the carbides following moving dislocations during tensile deformation. In addition, stress-induced H atoms accumulate at the interface between carbides and the matrix after necking under three-dimensional stress, which weakens the interfacial bonding force. Consequently, when the local H concentration reaches a critical value, microcracks occur at the interface, resulting in fracture.

  9. Effects of ionic strength and fulvic acid on adsorption of Tb(III) and Eu(III) onto clay.

    PubMed

    Poetsch, Maria; Lippold, Holger

    2016-09-01

    High salinity and natural organic matter are both known to facilitate migration of toxic or radioactive metals in geochemical systems, but little is known on their combined effect. We investigated complexation of Tb(III) and Eu(III) (as analogues for trivalent actinides) with fulvic acid and their adsorption onto a natural clay in the presence of NaCl, MgCl2 and CaCl2 up to very high ionic strengths. (160)Tb, (152)Eu and (14)C-labelled fulvic acid were employed as radiotracers, allowing investigations at very low concentrations according to probable conditions in far-field scenarios of nuclear waste repositories. A combined Kd approach (Linear Additive Model) was tested for suitability in predicting solid-liquid distribution of metals in the presence of organic matter based on the interactions in the constituent subsystems. In this analysis, it could be shown that high ionic strength does not further enhance the mobilizing potential of humic matter. A quantitative reproduction of the influence of fulvic acid failed for most systems under study. Assumptions and limitations of the model are discussed. PMID:27454893

  10. Effects of ionic strength and fulvic acid on adsorption of Tb(III) and Eu(III) onto clay

    NASA Astrophysics Data System (ADS)

    Poetsch, Maria; Lippold, Holger

    2016-09-01

    High salinity and natural organic matter are both known to facilitate migration of toxic or radioactive metals in geochemical systems, but little is known on their combined effect. We investigated complexation of Tb(III) and Eu(III) (as analogues for trivalent actinides) with fulvic acid and their adsorption onto a natural clay in the presence of NaCl, MgCl2 and CaCl2 up to very high ionic strengths. 160Tb, 152Eu and 14C-labelled fulvic acid were employed as radiotracers, allowing investigations at very low concentrations according to probable conditions in far-field scenarios of nuclear waste repositories. A combined Kd approach (Linear Additive Model) was tested for suitability in predicting solid-liquid distribution of metals in the presence of organic matter based on the interactions in the constituent subsystems. In this analysis, it could be shown that high ionic strength does not further enhance the mobilizing potential of humic matter. A quantitative reproduction of the influence of fulvic acid failed for most systems under study. Assumptions and limitations of the model are discussed.

  11. Failure mode and effects analysis application to critical care medicine.

    PubMed

    Duwe, Beau; Fuchs, Barry D; Hansen-Flaschen, John

    2005-01-01

    In July 2001, the United States Joint Commission on Accreditation of Health care Organizations adopted a new leadership standard that requires department heads in health care organizations to perform at least one Failure Mode and Effects Analysis (FMEA) every year. This proactive approach to error prevention has proven to be highly effective in other industries, notably aerospace, but remains untested in acute care hospitals. For several reasons, the intensive care unit (ICU) potentially is an attractive setting for early adoption of FMEA; however, successful implementation of FMEA in ICUs is likely to require strong, effective leadership and a sustained commitment to prevent errors that may have occurred rarely or never before in the local setting. This article describes FMEA in relation to critical care medicine and reviews some of the attractive features together with several potential pitfalls that are associated with this approach to error prevention in ICUs. PMID:15579350

  12. Effect of multiperforated plates on the acoustic modes in combustors

    NASA Astrophysics Data System (ADS)

    Gullaud, Elsa; Mendez, Simon; Sensiau, Claude; Nicoud, Franck; Poinsot, Thierry

    2009-06-01

    The analytical model derived by Howe assessing the acoustic effect of perforated plates has been implemented in a 3D Helmholtz solver. This solver allows one to compute the acoustic modes of industrial chambers taking into account the multiperforated plates present for the cooling of the walls. An academic test case consisting of two coaxial cylinders, with the inner one being perforated is used to validate the implementation in the general purpose AVSP code. This case is also used to show the effects of the presence of the plates. In particular, the sensitivity of the acoustic damping to the bias flow speed will be studied. A maximum absorption speed is shown, and the behaviour towards an infinite speed will be illustrated by the academic case. Computations are also conducted in the case of an industrial helicopter chamber. The value of the maximum absorption speed is discussed to explain why the modes are in fact not much absorbed by the perforated plates, and that the frequencies are the same as for walls. To cite this article: E. Gullaud et al., C. R. Mecanique 337 (2009).

  13. Gravitational Effects on Collective Modes of Superfluid Shells

    NASA Astrophysics Data System (ADS)

    Padavić, Karmela; Sun, Kuei; Lannert, Courtney; Vishveshwara, Smitha

    We study the effects of gravity on collective excitations of shell-shaped Bose-Einstein condensates (BECs). Superfluid shells are of general interest as examples of hollow geometries that can be produced in ultracold atoms in bubble-trap potentials or optical lattices. Our approach to analyzing superfluid shells is based on a Gross-Pitaevskii mean field theory and hydrodynamic equations derived from it. Considering a spherically symmetric BEC in general, there are distinct collective excitation spectra for the cases of a fully filled sphere and a very thin shell. Furthermore, an adiabatic change in the potential producing a slow transition from one geometry to the other shows a characteristic evolution. Given that in most realistic experimental conditions gravity cannot be neglected we investigate its effects on the equilibrium profile and the collective modes in the very thin shell limit. We analytically obtain the full excitation spectrum for the thin shell geometry and account for gravity perturbatively at length and energy scales that describe a stable matter-wave bubble. We find that gravity breaks spherical symmetry of the equilibrium density profile and affects the collective excitations by coupling adjacent modes in the angular direction.

  14. Scaling of divertor power footprint width in RF-heated type-III ELMy H-mode on the EAST superconducting tokamak

    NASA Astrophysics Data System (ADS)

    Wang, L.; Guo, H. Y.; Xu, G. S.; Liu, S. C.; Gan, K. F.; Wang, H. Q.; Gong, X. Z.; Liang, Y.; Zou, X. L.; Hu, J. S.; Chen, L.; Xu, J. C.; Liu, J. B.; Yan, N.; Zhang, W.; Chen, R.; Shao, L. M.; Ding, S.; Hu, G. H.; Feng, W.; Zhao, N.; Xiang, L. Y.; Liu, Y. L.; Li, Y. L.; Sang, C. F.; Sun, J. Z.; Wang, D. Z.; Ding, H. B.; Luo, G. N.; Chen, J. L.; Gao, X.; Hu, L. Q.; Wan, B. N.; Li, J.; the EAST Team

    2014-11-01

    Dedicated experiments for the scaling of divertor power footprint width have been performed in the ITER-relevant radio-frequency (RF)-heated H-mode scheme under the lower single null, double null and upper single null divertor configurations in the Experimental Advanced Superconducting Tokamak (EAST) under lithium wall coating conditioning. A strong inverse scaling of the edge localized mode (ELM)-averaged power fall-off width with the plasma current (equivalently the poloidal field) has been demonstrated for the attached type-III ELMy H-mode as λq \\propto Ip-1.05 by various heat flux diagnostics including the divertor Langmuir probes (LPs), infra-red (IR) thermograph and reciprocating LPs on the low-field side. The IR camera and divertor LP measurements show that λq,IR ≈ {λq,div{-LPs}}/{1.3}=1.15Bp,omp-1.25 , in good agreement with the multi-machine scaling trend during the inter-ELM phase between type-I ELMs or ELM-free enhanced Dα (EDA). H-mode. However, the magnitude is nearly doubled, which may be attributed to the different operation scenarios or heating schemes in EAST, i.e., dominated by electron heating. It is also shown that the type-III ELMs only broaden the power fall-off width slightly, and the ELM-averaged width is representative for the inter-ELM period. Furthermore, the inverse Ip (Bp) scaling appears to be independent of the divertor configurations in EAST. The divertor power footprint integral width, fall-off width and dissipation width derived from EAST IR camera measurements follow the relation, λint ≅ λq + 1.64S, yielding λ_intEAST =(1.39+/- 0.03)λqEAST +(0.97+/- 0.35) mm . Detailed analysis of these three characteristic widths was carried out to shed more light on their extrapolation to ITER.

  15. Retrieval Mode Distinguishes the Testing Effect from the Generation Effect

    ERIC Educational Resources Information Center

    Karpicke, Jeffrey D.; Zaromb, Franklin M.

    2010-01-01

    A series of four experiments examined the effects of generation vs. retrieval practice on subsequent retention. Subjects were first exposed to a list of target words. Then the subjects were shown the targets again intact for Read trials or they were shown fragments of the targets. Subjects in Generate conditions were told to complete the fragments…

  16. Mode Transitions in Magnetically Shielded Hall Effect Thrusters

    NASA Technical Reports Server (NTRS)

    Sekerak, Michael J.; Longmier, Benjamin W.; Gallimore, Alec D.; Huang, Wensheng; Kamhawi, Hani; Hofer, Richard R.; Jorns, Benjamin A.; Polk, James E.

    2014-01-01

    A mode transition study is conducted in magnetically shielded thrusters where the magnetic field magnitude is varied to induce mode transitions. Three different oscillatory modes are identified with the 20-kW NASA-300MS-2 and the 6-kW H6MS: Mode 1) global mode similar to unshielded thrusters at low magnetic fields, Mode 2) cathode oscillations at nominal magnetic fields, and Mode 3) combined spoke, cathode and breathing mode oscillations at high magnetic fields. Mode 1 exhibits large amplitude, low frequency (1-10 kHz), breathing mode type oscillations where discharge current mean value and oscillation amplitude peak. The mean discharge current is minimized while thrust-to-power and anode efficiency are maximized in Mode 2, where higher frequency (50-90 kHz), low amplitude, cathode oscillations dominate. Thrust is maximized in Mode 3 and decreases by 5-6% with decreasing magnetic field strength. The presence or absence of spokes and strong cathode oscillations do not affect each other or discharge current. Similar to unshielded thrusters, mode transitions and plasma oscillations affect magnetically shielded thruster performance and should be characterized during system development.

  17. [Failure mode and effect analysis: application in chemotherapy].

    PubMed

    Chuang, Ching-Hui; Chuang, Sheu-Wen

    2009-08-01

    Medical institutions are increasingly concerned about ensuring the safety of patients under their care. Failure mode and effect analysis (FMEA) is a qualitative approach based on a proactive process. Strongly promoted by the Joint Commission Accredited of Health Organization (JCAHO) since 2002, FMEA has since been adopted and widely practiced in healthcare organizations to assess and analyze clinical error events. FMEA has proven to be an effective method of minimizing errors in both manufacturing and healthcare industries. It predicts failure points in systems and allows an organization to address proactively the causes of problems and prioritize improvement strategies. The application of FMEA in chemotherapy at our department identified three main failure points: (1) inappropriate chemotherapy standard operating procedures (SOPs), (2) communication barriers, and (3) insufficient training of nurses. The application of FMEA in chemotherapy is expected to enhance the sensitivity and proactive abilities of healthcare practitioners during potentially risky situations as well as to improve levels of patient care safety. PMID:19634100

  18. Failure modes and effects analysis (RADL Item 2-23)

    SciTech Connect

    1980-04-01

    The Pilot Plant is a central receiver design concept. It is comprised of five major subsystems as shown schematically, plus a set of equipment (Plant Support Subsystem) used to support total plant operation. The failure modes and effects analysis (FMEA) is a bottom-up analysis used to identify the failure characteristics of the system (total equipment used to produce electrical power), that is, the failure of a single component is assumed and the effect of that failure upon the system is determined. The FMEA is concerned with the plant from an operational standpoint (i.e., the production of electrical power). This analysis was performed to the component level. This was interpreted as a valve, computer, measurement sensor and its associated signal conditioning, an electronic black box, etc.

  19. Application of failure mode and effects analysis (FMEA) to pretreatment phases in tomotherapy.

    PubMed

    Broggi, Sara; Cantone, Marie Claire; Chiara, Anna; Di Muzio, Nadia; Longobardi, Barbara; Mangili, Paola; Veronese, Ivan

    2013-01-01

    The aim of this paper was the application of the failure mode and effects analysis (FMEA) approach to assess the risks for patients undergoing radiotherapy treatments performed by means of a helical tomotherapy unit. FMEA was applied to the preplanning imaging, volume determination, and treatment planning stages of the tomotherapy process and consisted of three steps: 1) identification of the involved subprocesses; 2) identification and ranking of the potential failure modes, together with their causes and effects, using the risk probability number (RPN) scoring system; and 3) identification of additional safety measures to be proposed for process quality and safety improvement. RPN upper threshold for little concern of risk was set at 125. A total of 74 failure modes were identified: 38 in the stage of preplanning imaging and volume determination, and 36 in the stage of planning. The threshold of 125 for RPN was exceeded in four cases: one case only in the phase of preplanning imaging and volume determination, and three cases in the stage of planning. The most critical failures appeared related to (i) the wrong or missing definition and contouring of the overlapping regions, (ii) the wrong assignment of the overlap priority to each anatomical structure, (iii) the wrong choice of the computed tomography calibration curve for dose calculation, and (iv) the wrong (or not performed) choice of the number of fractions in the planning station. On the basis of these findings, in addition to the safety strategies already adopted in the clinical practice, novel solutions have been proposed for mitigating the risk of these failures and to increase patient safety. PMID:24036868

  20. Adsorption of fluoride on synthetic iron (III), zirconium(IV) and binary iron(III)-zirconium (IV) oxides: comparative assessment on pH effect and isotherm.

    PubMed

    Biswas, Krishna; Bandhopadhyay, Durjoy; Ghosh, Uday Chand

    2008-04-01

    Fluoride is an accumulative poison at high dose of intake for humans and animals. In the present study, the sorption of fluoride from aqueous solution has been investigated on synthetic hydrous ferric oxide (HFO), hydrous zirconium oxide (HZO) and hydrous zirconium(IV)-iron(III) oxide (HZFO) by batch mode experiments. Both HFO and HZFO were crystalline and HZO was amorphous in nature. The parametes studied were the effect of pH and sorption equilibriums. The results showed increase in fluoride-sorption with increasing pH from nearly 2.0 to 5.0, 4.6 and 6.8 for HFO, HZO and HZFO, respectively. Analysis of temperature dependent sorption data obtained at equilibrium solution pH 6.8 (+/- 0.2) has been described by the Langmuir, Freundlich, Temkin and Redlich-Peterson isotherm model equations. The present sorption data fit, in general, found very well with the Langmuir and Redlich-Peterson models; and the data fit for HZFO and HFO found to increase, but for HZO the data found to decrease with increasing temperature. The computed thermodynamic parameters such as deltaG0, delltaH0 and deltaS0 from the Langmuir equilibrium constant (b, L/Umg) values show that the fluoride-sorption on HZFO was more spontaneous and endothermic process compared to HFO. The deltaH0 value obtained for fluoride adsorption on HZO indicates exothermic nature. PMID:19295101

  1. Resistivity and sheared rotation effects on the toroidal external kink mode

    NASA Astrophysics Data System (ADS)

    Cole, A. J.; Brennan, D. P.; Finn, J. M.

    2014-10-01

    We present PEST-III analysis of the toroidal external kink with plasma resistivity and sheared rotation for a range of equilibria varying elongation, driven unstable by increasing β. The results show that the typical ordering for marginally stable β values is βrp,rw <βrp,iw <βip,rw <βip,iw , where rp,ip signify resistive or ideal plasma, and iw,rw indicate ideal wall or resistive wall (no-wall). The two resistive plasma β limits are significantly lower than the two ideal plasma values. We vary aspects of the tearing layer physics by means of a variational principle with Padé approximants, and compare with a general computational solution for the layers to gain insight. We also include pressure gradient and local velocity shear within the layers. Global rotation shear Ω' is included in the form of a relative rotation of the q = 2 , 3 , ... surfaces and we investigate the resultant effect on the poloidal mode number spectrum. We then present a model for active feedback control, which is the toroidal generalization building on recent results in cylindrical mode control theory [D. P. Brennan and J. M. Finn, submitted to Phys. Plasmas (2014)].

  2. Iron (III) Matrix Effects on Mineralization and Immobilization of Actinides

    SciTech Connect

    Cynthia-May S. Gong; Tyler A. Sullens; Kenneth R. Czerwinski

    2006-01-01

    Abstract - A number of models for the Yucca Mountain Project nuclear waste repository use studies of actinide sorption onto well-defined iron hydroxide materials. In the case of a waste containment leak, however, a complex interaction between dissolved waste forms and failed containment vessel components can lead to immediate precipitation of migratory iron and uranyl in the silicate rich near-field environment. Use of the Fe(III) and UO22+ complexing agent acetohydroxamic acid (AHA) as a colorimetric agent for visible spectrophotometry is well-known. Using the second derivative of these spectra a distinct shift in iron complexation in the presence of silicate is seen that is not seen with uranyl or alone. Silica also decreases the ability of uranyl and ferric solutions to absorb hydroxide, hastening precipitation. These ferric silicate precipitates are highly amorphous and soluble. Precipitates formed in the presence of uranyl below ~1 mol% exhibit lower solubility than precipitates from up to 50 mol % and of uranyl silicates alone.

  3. Radiology failure mode and effect analysis: what is it?

    PubMed

    Abujudeh, Hani H; Kaewlai, Rathachai

    2009-08-01

    Proactive prevention of medical errors is critical in medical practice. Root cause analysis (RCA) is a conventional method used to deal with errors that result in an adverse event. However, RCA has several limitations. An analytic method for health care risk management, health care failure mode and effect analysis (FMEA), has been introduced relatively recently. Health care FMEA combines several existing analytic approaches into one simple tool with which to analyze a particular health care process, determine the risks associated with it, and develop corrective actions and outcome measures. The authors provide a brief history of health care FMEA, describe its validation process, and relate their experience with its use in a radiology department. PMID:19703888

  4. An effective model for microscopic intrinsic localized modes.

    SciTech Connect

    Kalosakas, G.; Bishop, A. R.

    2001-01-01

    We present a system of coupled degrees of freedom that can effectively describe the localization of intra-molecular excitations in the charge transfer solid PtCl. These excitations correspond to the Raman active motion of chlorines (symmetric Pt - Cl stretching). By fitting two parameters of the model we obtain an accurate description of the strong red-shifts that appear in the overtone Raman spectra of the isotopically pure material. The resulting intrinsic localized modes extend on length scales of the order of nanometers. With the same set of parameters the model can reproduce the specific structure of the Raman spectra of naturally abundant PtCl, which contains a random distribution of chloride isotopes.

  5. Diamagnetic drift effects on the low-n magnetohydrodynamic modes at the high mode pedestal with plasma rotation

    NASA Astrophysics Data System (ADS)

    Zheng, L. J.; Kotschenreuther, M. T.; Valanju, P.

    2014-06-01

    The diamagnetic drift effects on the low-n magnetohydrodynamic instabilities at the high-mode (H-mode) pedestal are investigated in this paper with the inclusion of bootstrap current for equilibrium and rotation effects for stability, where n is the toroidal mode number. The AEGIS (Adaptive EiGenfunction Independent Solutions) code [L. J. Zheng and M. T. Kotschenreuther, J. Comp. Phys. 211 (2006)] is extended to include the diamagnetic drift effects. This can be viewed as the lowest order approximation of the finite Larmor radius effects in consideration of the pressure gradient steepness at the pedestal. The H-mode discharges at Jointed European Torus is reconstructed numerically using the VMEC code [P. Hirshman and J. C. Whitson, Phys. Fluids 26, 3553 (1983)], with bootstrap current taken into account. Generally speaking, the diamagnetic drift effects are stabilizing. Our results show that the effectiveness of diamagnetic stabilization depends sensitively on the safe factor value (qs) at the safety-factor reversal or plateau region. The diamagnetic stabilization are weaker, when qs is larger than an integer; while stronger, when qs is smaller or less larger than an integer. We also find that the diamagnetic drift effects also depend sensitively on the rotation direction. The diamagnetic stabilization in the co-rotation case is stronger than in the counter rotation case with respect to the ion diamagnetic drift direction.

  6. Failure mode and weakening effect of water on sandstone

    NASA Astrophysics Data System (ADS)

    Baud, Patrick; Zhu, Wenlu; Wong, Teng-Fong

    2000-07-01

    Previous studies have shown that brittle strength of a rock is generally reduced in the presence of water. However, for siliciclastic rocks, there is a paucity of data on the waterweakening behavior in the cataclastic flow regime. To compare the weakening effect of water in the brittle faulting and cataclastic flow regime, triaxial compression experiments were conducted on the Berea, Boise, Darley Dale, and Gosford sandstones (with nominal porosities ranging from 11% to 35%) under nominally dry and saturated conditions at room temperature. Inelastic behavior and failure mode of the nominal dry samples were qualitatively similar to those of water-saturated samples. At elevated pressures, shear localization was inhibited, and all the samples failed by strain hardening. The compactive yield strengths (associated with the onset of shear-enhanced compaction) in the saturated samples were lower than those in the dry samples deformed under comparable pressure conditions by 20% to 70%. The reductions of brittle strength in the presence of water ranged from 5% to 17%. The water-weakening effects were most and least significant in the Gosford and Berea sandstones, respectively. The relation between water weakening and failure mode is consistently explained by micromechanical models formulated on the basis that the specific surface energy in the presence of water is lowered than that in vacuum by the ratio λ. In accordance with the Hertzian fracture model the initial yield stress in the compactive cataclastic flow regime scales with the grain-crushing pressure, which is proportional to λ3/2. In the brittle faulting regime, damage mechanics models predict that the uniaxial compressive strength scales with λ1/2. In the presence of water the confined brittle strength is lower due to reductions of both the specific surface energy and friction coefficient.

  7. Can dispersal mode predict corridor effects on plant parasites?

    SciTech Connect

    Sullivan, Lauren, L.; Johnson, Brenda, L.; Brudvig, Lars, A.; Haddad, Nick, M.

    2011-08-01

    Habitat corridors, a common management strategy for increasing connectivity in fragmented landscapes, have experimentally validated positive influences on species movement and diversity. However, long-standing concerns that corridors could negatively impact native species by spreading antagonists, such as disease, remain largely untested. Using a large-scale, replicated experiment, we evaluated whether corridors increase the incidence of plant parasites. We found that corridor impacts varied with parasite dispersal mode. Connectivity provided by corridors increased incidence of biotically dispersed parasites (galls on Solidago odora) but not of abiotically dispersed parasites (foliar fungi on S. odora and three Lespedeza spp.). Both biotically and abiotically dispersed parasites responded to edge effects, but the direction of responses varied across species. Although our results require additional tests for generality to other species and landscapes, they suggest that, when establishing conservation corridors, managers should focus on mitigating two potential negative effects: the indirect effects of narrow corridors in creating edges and direct effects of corridors in enhancing connectivity of biotically dispersed parasites.

  8. Investigation of ELM [edge localized mode] Dynamics with the Resonant Magnetic Perturbation Effects

    SciTech Connect

    Pankin, Alexei Y.; Kritz, Arnold H.

    2011-07-19

    Topics covered are: anomalous transport and E x B flow shear effects in the H-mode pedestal; RMP (resonant magnetic perturbation) effects in NSTX discharges; development of a scaling of H-mode pedestal in tokamak plasmas with type I ELMs (edge localized modes); and divertor heat load studies.

  9. The Games Children Play III: More Comments on Effective Teaching

    ERIC Educational Resources Information Center

    Humphries, Charlotte A.; Ashy, Madge

    2013-01-01

    In the years since the authors published two articles with tips for effective teaching, they have acquired and developed more advice and impressions on teaching. This article presents ideas that can help physical educators become increasingly effective in their teaching.

  10. The effect of ligand dynamics on heme electronic transition band III in myoglobin.

    PubMed

    Nienhaus, Karin; Lamb, Don C; Deng, Pengchi; Nienhaus, G Ulrich

    2002-02-01

    Band III is a near-infrared electronic transition at ~13,000 cm(-1) in heme proteins that has been studied extensively as a marker of protein conformational relaxation after photodissociation of the heme-bound ligand. To examine the influence of the heme pocket structure and ligand dynamics on band III, we have studied carbon monoxide recombination in a variety of myoglobin mutants after photolysis at 3 K using Fourier transform infrared temperature-derivative spectroscopy with monitoring in three spectral ranges, (1) band III, the mid-infrared region of (2) the heme-bound CO, and (3) the photodissociated CO. Here we present data on mutant myoglobins V68F and L29W, which both exhibit pronounced ligand movements at low temperature. From spectral and kinetic analyses in the mid-infrared, a small number of photoproduct populations can be distinguished, differing in their distal heme pocket conformations and/or CO locations. We have decomposed band III into its individual photoproduct contributions. Each photoproduct state exhibits a different "kinetic hole-burning" (KHB) effect, a coupling of the activation enthalpy for rebinding to the position of band III. The analysis reveals that the heme pocket structure and the photodissociated CO markedly affect the band III transition. A strong kinetic hole-burning effect results only when the CO ligand resides in the docking site on top of the heme group. Migration of CO away from the heme group leads to an overall blue shift of band III. Consequently, band III can be used as a sensitive tool to study ligand dynamics after photodissociation in heme proteins. PMID:11806945

  11. Twist effect and sensing of few mode polymer fibre Bragg gratings

    NASA Astrophysics Data System (ADS)

    Yan, Binbin; Luo, Yanhua; Bhowmik, Kishore; Rajan, Ginu; Ji, Minning; Wen, Jianxiang; Peng, Gang-Ding

    2016-01-01

    For the development of the twist sensor based on few mode polymer optical fibre (POF) gratings, we investigated the twist effect of few mode (FM) POF Bragg gratings with large twist, and found the twist effect on reflection is highly mode dependent-insignificant on the fundamental mode and considerable on higher order modes, which seems closely related to the symmetry of modal field. In addition, Bragg wavelengths of both the fundamental mode and higher modes red-shift with the twisting and blue-shift with the twist releasing, and they almost display the similar response trend without any mode dependence. Further analysis found that the red-shift of the Bragg wavelength should be attributed to the redistribution of the pre-strain applied upon the POF, activated by twist. Finally, based on the reflection response to the twist, one kind of twist sensing scheme with few mode POF gratings has been demonstrated, showing great potential as a twist sensor.

  12. Mode competition effects in free electron lasers and gyrotrons

    SciTech Connect

    Levush, B.; Antonsen, T.M.

    1990-01-01

    In many cases in high frequency, high power coherent radiation generators (such as free electron laser and gyrotrons) the linear gain is positive for many modes and therefore these modes will grow and compete for the beam energy. The questions related to mode competition, coherency of the radiation and maximization of the interaction efficiency are of great importance. To address these issues simple multi-mode models have been formulated. This paper is a short review of the recent results from both simulation and analyses of these models. 3 figs.

  13. The effect of initial conditions on the electromagnetic radiation generation in type III solar radio bursts

    SciTech Connect

    Schmitz, H.; Tsiklauri, D.

    2013-06-15

    Extensive particle-in-cell simulations of fast electron beams injected in a background magnetised plasma with a decreasing density profile were carried out. These simulations were intended to further shed light on a newly proposed mechanism for the generation of electromagnetic waves in type III solar radio bursts [D. Tsiklauri, Phys. Plasmas, 18, 052903 (2011)]. The numerical simulations were carried out using different density profiles and fast electron distribution functions. It is shown that electromagnetic L and R modes are excited by the transverse current, initially imposed on the system. In the course of the simulations, no further interaction of the electron beam with the background plasma could be observed.

  14. OCEAN OUTFALLS. III: EFFECT OF DIFFUSER DESIGN ON SUBMERGED WASTEFIELD

    EPA Science Inventory

    The effects of spacing and jet momentum flux on the characteristics of submerged wastefields produced by multi-port ocean outfalls in linearly stratified currents were investigated experimentally. Within the range studied the primary effect of these variables is on the rise heigh...

  15. Dislocation effects in FinFETs for different III-V compound semiconductors

    NASA Astrophysics Data System (ADS)

    Hur, Ji-Hyun; Jeon, Sanghun

    2016-04-01

    While Si-based devices are facing the limits of scaling, III-V materials, having high mobility, have attracted more and more attention. However, their advantages are obtained by ignoring the drawbacks of inevitably present dislocations. In this paper, we present a theoretical model that describes the degradation in carrier mobility caused by these inevitable charged dislocations in nanometer-sized, quantum-confined III-V compound semiconductor fin-shaped field effect transistors. We conclude that the Fermi-level pinning effect needs to be resolved to give carriers high enough energy (Fermi energy in the channel) to effectively ignore Coulomb scattering of charges at dislocations in a channel made by III-V compound semiconductors.

  16. Effects of Al(III) and nano-Al13 species on malate dehydrogenase activity.

    PubMed

    Yang, Xiaodi; Cai, Ling; Peng, Yu; Li, Huihui; Chen, Rong Fu; Shen, Ren Fang

    2011-01-01

    The effects of different aluminum species on malate dehydrogenase (MDH) activity were investigated by monitoring amperometric i-t curves for the oxidation of NADH at low overpotential using a functionalized multi-wall nanotube (MWNT) modified glass carbon electrode (GCE). The results showed that Al(III) and Al(13) can activate the enzymatic activity of MDH, and the activation reaches maximum levels as the Al(III) and Al(13) concentration increase. Our study also found that the effects of Al(III) and Al(13) on the activity of MDH depended on the pH value and aluminum speciation. Electrochemical and circular dichroism spectra methods were applied to study the effects of nano-sized aluminum compounds on biomolecules. PMID:22163924

  17. Effects of subchronic exposure to Caramel Colour III on the immune system in mice.

    PubMed

    Thuvander, A; Oskarsson, A

    1994-01-01

    Administration of Caramel Colour III is associated with lymphopenia in laboratory animals, especially if the animals are fed a vitamin B6-deficient diet. Recently, functional immunological alterations in rats exposed to Caramel Colour III have been reported. The component of Caramel Colour III that is responsible for the immunological effects has been shown to be 2-acetyl-4-tetrahydroxybutyl imidazole (THI). In the present study, female Balb/c mice fed a diet with a relatively high vitamin B6 content were exposed to 2 or 10% of a commercial Caramel Colour III preparation with a low THI content (less than 25 ppm) in the drinking water for 9 wk. Although this treatment did not induce a lymphopenia in the exposed mice, flow cytometric analysis of lymphocyte subpopulations demonstrated reductions in the CD4+ and CD8+ cell populations. In addition, the proliferative response of spleen cells to B and T cell mitogens was significantly reduced in the mice exposed to 2% Caramel Colour III. No changes were observed in natural killer cell activity or in the humoral antibody response to a viral antigen. The results indicate that Caramel Colour III that meets the specified limit of less than 25 mg THI/kg may, nevertheless, interfere with the lymphoid system in mice with an adequate vitamin B6 status. PMID:8132168

  18. Effects of reactive Mn(III)-oxalate complexes on structurally intact plant cell walls

    NASA Astrophysics Data System (ADS)

    Summering, J. A.; Keiluweit, M.; Goni, M. A.; Nico, P. S.; Kleber, M.

    2011-12-01

    Lignin components in the in plant litter are commonly assumed to have longer residence times in soil than many other compounds, which are supposedly, more easily degradable. The supposed resistance of lignin compounds to decomposition is generally attributed to the complex chain of biochemical steps required to create footholds in the non-porous structure of ligno-cellulose in cell walls. Interestingly, Mn(III) complexes have shown the ability to degrade ligno-cellulose. Mn(III) chelated by ligands such as oxalate are soluble oxidizers with a high affinity for lignin structures. Here we determined (i) the formation and decay kinetics of the Mn(III)-oxalate complexes in aqueous solution and (ii) the effects that these complexes have on intact ligno-cellulose. UV/vis spectroscopy and iodometric titrations confirmed the transient nature of Mn(III)-oxalate complexes with decay rates being in the order of hours. Zinnia elegans tracheary elements - a model ligno-cellulose substrate - were treated with Mn(III)-oxalate complexes in a newly developed flow-through reactor. Soluble decomposition products released during the treatment were analyzed by GC/MS and the degree of cell integrity was measured by cell counts, pre- and post-treatment counts indicate a decrease in intact Zinnia elegans as a result of Mn(III)-treatment. GC/MS results showed the release of a multitude of solubilized lignin breakdown products from plant cell walls. We conclude that Mn(III)-oxalate complexes have the ability to lyse intact plant cells and solubilize lignin. Lignin decomposition may thus be seen as resource dependent, with Mn(III) a powerful resource that should be abundant in terrestrial characterized by frequent redox fluctuations.

  19. Effectiveness of Urban Shelter-in-Place. III: Commercial Districts

    SciTech Connect

    Chan, Wanyu R.; Chan, Wanyu R.; Nazaroff, William W.; Price, Phillip N.; Gadgil, Ashok J.

    2007-12-28

    In the event of a toxic chemical release to the atmosphere, shelter-in-place (SIP) is an emergency response option available to protect public health. This paper is the last in a three-part series that examines the effectiveness of SIP at reducing adverse health effects in communities. We model a hypothetical chemical release in an urban area, and consider SIP effectiveness in protecting occupants of commercial buildings. Building air infiltration rates are predicted from empirical data using an existing model. We consider the distribution of building air infiltration rates both with mechanical ventilation systems turned off and with the systems operating. We also consider the effects of chemical sorption to indoor surfaces and nonlinear chemical dose-response relationships. We find that commercial buildings provide effective shelter when ventilation systems are off, but that any delay in turning off ventilation systems can greatly reduce SIP effectiveness. Using a two-zone model, we find that there can be substantial benefit by taking shelter in the inner parts of a building that do not experience direct air exchange with the outdoors. Air infiltration rates vary substantially among buildings and this variation is important in quantifying effectiveness for emergency response. Community-wide health metrics, introduced in the previous papers in this series, can be applied in pre-event planning and to guide real-time emergency response.

  20. Failure mode and effects analysis: too little for too much?

    PubMed

    Dean Franklin, Bryony; Shebl, Nada Atef; Barber, Nick

    2012-07-01

    Failure mode and effects analysis (FMEA) is a structured prospective risk assessment method that is widely used within healthcare. FMEA involves a multidisciplinary team mapping out a high-risk process of care, identifying the failures that can occur, and then characterising each of these in terms of probability of occurrence, severity of effects and detectability, to give a risk priority number used to identify failures most in need of attention. One might assume that such a widely used tool would have an established evidence base. This paper considers whether or not this is the case, examining the evidence for the reliability and validity of its outputs, the mathematical principles behind the calculation of a risk prioirty number, and variation in how it is used in practice. We also consider the likely advantages of this approach, together with the disadvantages in terms of the healthcare professionals' time involved. We conclude that although FMEA is popular and many published studies have reported its use within healthcare, there is little evidence to support its use for the quantitative prioritisation of process failures. It lacks both reliability and validity, and is very time consuming. We would not recommend its use as a quantitative technique to prioritise, promote or study patient safety interventions. However, the stage of FMEA involving multidisciplinary mapping process seems valuable and work is now needed to identify the best way of converting this into plans for action. PMID:22447819

  1. Antidiabetic Effect and Mode of Action of Cytopiloyne

    PubMed Central

    Chang, Cicero Lee-Tian; Liu, Hsien-Yueh; Kuo, Tien-Fen; Hsu, Yi-Jou; Shen, Ming-Yi; Pan, Chien-Yuan

    2013-01-01

    Cytopiloyne was identified as a novel polyacetylenic compound. However, its antidiabetic properties are poorly understood. The aim of the present study was to investigate the anti-diabetic effect and mode of action of cytopiloyne on type 2 diabetes (T2D). We first evaluated the therapeutic effect of cytopiloyne on T2D in db/db mice. We found that one dose of cytopiloyne reduced postprandial glucose levels while increasing blood insulin levels. Accordingly, long-term treatment with cytopiloyne reduced postprandial blood glucose levels, increased blood insulin, improved glucose tolerance, suppressed the level of glycosylated hemoglobin A1c (HbA1c), and protected pancreatic islets in db/db mice. Next, we studied the anti-diabetic mechanism of action of cytopiloyne. We showed that cytopiloyne failed to decrease blood glucose in streptozocin- (STZ-)treated mice whose β cells were already destroyed. Additionally, cytopiloyne dose dependently increased insulin secretion and expression in β cells. The increase of insulin secretion/expression of cytopiloyne was regulated by protein kinase Cα (PKCα) and its activators, calcium, and diacylglycerol (DAG). Overall, our data suggest that cytopiloyne treats T2D via regulation of insulin production involving the calcium/DAG/PKCα cascade in β cells. These data thus identify the molecular mechanism of action of cytopiloyne and prove its therapeutic potential in T2D. PMID:23573144

  2. Finite Larmor radius effects on the coupled trapped electron and ion temperature gradient modes

    SciTech Connect

    Sandberg, I.; Isliker, H.; Pavlenko, V. P.

    2007-09-15

    The properties of the coupled trapped electron and toroidal ion temperature gradient modes are investigated using the standard reactive fluid model and taking rigorously into account the effects attributed to the ion polarization drift and to the drifts associated with the lowest-order finite ion Larmor radius effects. In the flat density regime, where the coupling between the modes is relatively weak, the properties of the unstable modes are slightly modified through these effects. For the peak density regions, where the coupling of the modes is rather strong, these second-order drifts determine the spectra of the unstable modes near the marginal conditions.

  3. Flare loop radiative hydrodynamics. III - Nonlocal radiative transfer effects

    NASA Technical Reports Server (NTRS)

    Canfield, R. C.; Fisher, G. H.; Mcclymont, A. N.

    1983-01-01

    The study has three goals. The first is to demonstrate that processes exist whose intrinsic nonlocal nature cannot be represented by local approximations. The second is to elucidate the physical nature and origins of these nonlocal processes. The third is to suggest that the methods and results described here may prove useful in constructing semiempirical models of the chromosphere by means more efficient than trial and error. Matrices are computed that describe the effect of a temperature perturbation at an arbitrary point in the loop on density, hydrogen ionized fraction, total radiative loss rate, and radiative loss rate of selected hydrogen lines and continua at all other points. It is found that the dominant nonlocal radiative transfer effects can be separated into flux divergence coefficient effects and upper level population effects. The former are most important when the perturbation takes place in a region of significant opacity. Upper level population effects arise in both optically thick and thin regions in response to nonlocal density, ionization, and interlocking effects.

  4. Mixed Mode Effects in a Community College Graduate Survey.

    ERIC Educational Resources Information Center

    Goho, James

    This paper describes the results of research evaluating the use of mixed-mode surveys in institutional research. Surveys were administered to 1999-2000 graduates at Red River Community College in 2 phases. Phase 1 offered three modes of response: mail, Web-based, and touch-tone data entry (TDE). Phase 2 (administered to non-respondents of Phase 1)…

  5. Pulsatile Support Mode of BJUT-II Ventricular Assist Device (VAD) has Better Hemodynamic Effects on the Aorta than Constant Speed Mode: A Primary Numerical Study

    PubMed Central

    Gu, Kaiyun; Gao, Bin; Chang, Yu; Zeng, Yi

    2016-01-01

    Background BJUT-II VAD is a novel left ventricular assist device (LVADs), directly implanted into the ascending aorta. The pulsatile support mode is proposed to achieve better unloading performance than constant speed mode. However, the hemodynamic effects of this support mode on the aorta are still unclear. The aim of this study was to clarify the hemodynamic effects BJUT-II VAD under pulsatile support mode on the aorta. Material/Methods Computational fluid dynamics (CFD) studies, based on a patient-specific aortic geometric model, were conducted. Wall shear stress (WSS), averaged WSS (avWSS), oscillatory shear index (OSI), and averaged helicity density (Ha) were calculated to compare the differences in hemodynamic effects between pulsatile support mode and constant speed mode. Results The results show that avWSS under pulsatile support mode is significantly higher than that under constant speed mode (0.955Pa vs. 0.675Pa). Similarly, the OSI value under pulsatile mode is higher than that under constant speed mode (0.104 vs. 0.057). In addition, Ha under pulsatile mode for all selected cross-sections is larger than that under constant mode. Conclusions BJUT-II VAD, under pulsatile control mode, may prevent atherosclerosis lesions and aortic remodeling. The precise effects of pulsatile support mode on atherosclerosis and aortic remodeling need to be further studied in animal experiments. PMID:27363758

  6. Pulsatile Support Mode of BJUT-II Ventricular Assist Device (VAD) has Better Hemodynamic Effects on the Aorta than Constant Speed Mode: A Primary Numerical Study.

    PubMed

    Gu, Kaiyun; Gao, Bin; Chang, Yu; Zeng, Yi

    2016-01-01

    BACKGROUND BJUT-II VAD is a novel left ventricular assist device (LVADs), directly implanted into the ascending aorta. The pulsatile support mode is proposed to achieve better unloading performance than constant speed mode. However, the hemodynamic effects of this support mode on the aorta are still unclear. The aim of this study was to clarify the hemodynamic effects BJUT-II VAD under pulsatile support mode on the aorta. MATERIAL AND METHODS Computational fluid dynamics (CFD) studies, based on a patient-specific aortic geometric model, were conducted. Wall shear stress (WSS), averaged WSS (avWSS), oscillatory shear index (OSI), and averaged helicity density (Ha) were calculated to compare the differences in hemodynamic effects between pulsatile support mode and constant speed mode. RESULTS The results show that avWSS under pulsatile support mode is significantly higher than that under constant speed mode (0.955Pa vs. 0.675Pa). Similarly, the OSI value under pulsatile mode is higher than that under constant speed mode (0.104 vs. 0.057). In addition, Ha under pulsatile mode for all selected cross-sections is larger than that under constant mode. CONCLUSIONS BJUT-II VAD, under pulsatile control mode, may prevent atherosclerosis lesions and aortic remodeling. The precise effects of pulsatile support mode on atherosclerosis and aortic remodeling need to be further studied in animal experiments. PMID:27363758

  7. Constructing an effective prevention mechanism for MSW lifecycle using failure mode and effects analysis.

    PubMed

    Chen, Ying-Chu; Wu, Wen-Fang

    2015-12-01

    Municipal solid waste in Taiwan is a valuable source of renewable energy. Phases of municipal solid waste lifecycle (classification, disposal, storage, collection and transportation) before incineration or landfilled face various potential failures. Applying a proper technique to eliminate or decrease potential failures is desirable and needed. Failure Modes and Effects Analysis to municipal solid waste lifecycle was found in literature. This study utilized the Failure Modes and Effects Analysis as a convenient technique for determining, classifying and analyzing common failures in the municipal solid waste lifecycle. As a result, an appropriate risk scoring of severity, occurrence, and detection of failure modes and computing the Risk Priority Number for identifying the high potential failure modes were made. Nineteen failure modes were identified, and nine of them were ranked as the priority items for improvement. Recommended actions for all failure modes were suggested. Occurrences of failures were remarkably reduced after implementing the procedure for six months. The results of this study have minimized potential failures and brought continuous improvement, thus achieving a better protection of the environment. PMID:26372404

  8. Computer Communication Modes and Their Effect on Student Attitudes Towards Programming.

    ERIC Educational Resources Information Center

    Boillot, Michel

    The effect of different communicating modes to computers on students' attitudes toward programing was studied. In a computer-related course, 13 students used batch processing mode to solve problems on the computer, while 12 other students used conversational mode to solve the same problems. It was found that those students accessing the computer…

  9. Chunking Method of Teaching and Studying (III): Test Effects.

    ERIC Educational Resources Information Center

    Furukawa, James M.; Cohen, Nancy

    The effects of specific testing procedures on learning were studied, using the chunking method of teaching and studying, which involves the learning of small units of information. The size of the unit is related to the student's cognitive processing capacity (CPC)--the amount of material recalled after a brief exposure. Subjects were undergraduate…

  10. REVIEWS OF THE ENVIRONMENTAL EFFECTS OF POLLUTANTS: III. CHROMIUM

    EPA Science Inventory

    The report is a review of the scientific literature on the biological and environmental effects of chromium. Included in the review are a general summary and a comprehensive discussion of the following topics as related to chromium and specific chromium compounds: physical and ch...

  11. Effect of chirality on domain wall dynamics in molecular ferrimagnet [MnII(HL-pn)(H2O)][MnIII(CN)6]·2H2O

    NASA Astrophysics Data System (ADS)

    Mushenok, F.; Koplak, O.; Morgunov, R.

    2011-11-01

    In this paper we distinguish the contributions of switching, slide, creep and Debye relaxation modes of the domain wall dynamics to the low-frequency magnetic properties of chiral and racemic [MnII(HL-pn)(H2O)][MnIII(CN)6]·2H2O molecular ferrimagnets. We demonstrate that crystal and spin chirality affects the characteristic transition temperatures between different modes. In chiral crystals, transitions to the creep and Debye relaxation modes were observed at T = 7 K and 5 K, whereas in racemic crystals the same transitions occurred at higher temperatures T = 13 K and 9 K, respectively. Difference of the Peierls relief in chiral and racemic crystals is a possible reason of the chirality effect on the domain walls dynamics.

  12. Effective band structure of random III-V alloys

    NASA Astrophysics Data System (ADS)

    Popescu, Voicu; Zunger, Alex

    2010-03-01

    Random substitutional alloys have no long range order (LRO) or translational symmetry so rigorously speaking they have no E(k) band structure or manifestations thereof. Yet, many experiments on alloys are interpreted using the language of band theory, e.g. inferring Van Hove singularities, band dispersion and effective masses. Many standard alloy theories (VCA- or CPA-based) have the LRO imposed on the alloy Hamiltonian, assuming only on-site disorder, so they can not be used to judge the extent of LRO that really exists. We adopt the opposite way, by using large (thousand atom) randomly generated supercells in which chemically identical alloy atoms are allowed to have different local environments (a polymorphous representation). This then drives site-dependent atomic relaxation as well as potential fluctuations. The eigenstates from such supercells are then mapped onto the Brillouin zone (BZ) of the primitive cell, producing effective band dispersion. Results for (In,Ga)X show band-like behaviour only near the centre and faces of the BZ but rapidly lose such characteristics away from γ or for higher bands. We further analyse the effects of stoichiometry variation, internal relaxation, and short-range order on the alloy band structure.

  13. Exponential synchronization of coupled switched neural networks with mode-dependent impulsive effects.

    PubMed

    Wenbing Zhang; Yang Tang; Qingying Miao; Wei Du

    2013-08-01

    This paper investigates the synchronization problem of coupled switched neural networks (SNNs) with mode-dependent impulsive effects and time delays. The main feature of mode-dependent impulsive effects is that impulsive effects can exist not only at the instants coinciding with mode switching but also at the instants when there is no system switching. The impulses considered here include those that suppress synchronization or enhance synchronization. Based on switching analysis techniques and the comparison principle, the exponential synchronization criteria are derived for coupled delayed SNNs with mode-dependent impulsive effects. Finally, simulations are provided to illustrate the effectiveness of the results. PMID:24808570

  14. FMEA, the alternative process hazard method. [Failure Mode Effects Analysis

    SciTech Connect

    Goyal, R.K. )

    1993-05-01

    Failure mode effects analysis (FMEA) is an old reliability/assurance tool finding its way into the HPI. Not popular yet, this hazard technique has some viable applications that can improve hazard assessment data. Notably, FMEA studies can identify possible areas for improvement that may have not been discovered using other methods. Also, FMEA is not as labor intensive and costly as other process hazard analysis (PHA) methods. PSHA 1910.119 set in place an informational structure whose main purpose is the reduction of potential accidents and minimizing risks in the event of an accident. Consequently, HPI operators must evaluate their process systems and identify potential major hazards, such as fires, explosions and accidental release of toxic/hazardous chemicals, and protect their facilities, employees, the public and the environment. But, which PHA method(s) apply to a particular plant or process still remains a difficult question. This paper describes what FMEA is; types of FMEA; how to conduct a FMEA study; comparison with HAZOP (hazard and operability study); computer software; applicability of FMEA; and examples of its use.

  15. The Worker Exposure Failure Modes and Effects Analysis

    SciTech Connect

    Cadwallader, L.C.

    2005-05-15

    The Worker Exposure Failure Modes and Effects Analysis (WE-FMEA) is a new approach to quantitatively evaluate worker risks from possible failures of co-located equipment in the complex environment of a magnetic or inertial fusion experiment. For next-step experiments such as the International Thermonuclear Experimental Reactor (ITER) or the National Ignition Facility (NIF), the systems and equipment will be larger, handle more throughput or power, and will, in general, be more robust than past experiments. These systems and equipment are necessary to operate the machine, but the rooms are congested with equipment, piping, and cables, which poses a new level of hazard for workers who will perform hands-on maintenance. The WE-FMEA systematically analyzes the nearby equipment and the work environment for equipment failure or inherent hazards, and then develops exposure scenarios. Once identified, the exposure scenarios are evaluated for the worker hazards and quantitative worker risk is calculated. Then risk scenarios are quantitatively compared to existing statistical data on worker injuries; high-risk scenarios can be identified and addressed in more detail to determine the proper means to reduce, mitigate, or protect against the hazard. The WE-FMEA approach is described and a cooling system maintenance example is given.

  16. Photophysical effects of metal-carbon sigma bonds in ortho-metalated complexes of Ir(III) and Rh(III)

    SciTech Connect

    Sprouse, S.; King, K.A.; Spellane, P.J.; Watts, R.J.

    1984-10-31

    Dichloro-bridged dimers of the type (M(L)/sub 2/Cl)/sub 2/, where L is 2-phenylpyridine (ppy) or benzo(h)quinoline (bzq) and M is Rh(III) or Ir(III), have been characterized by /sup 13/C and /sup 1/H NMR spectroscopies and by absorption and emission spectroscopies. The NMR results confirm previous formulations of the complexes as dichloro-bridged ortho-metalated dimers in halocarbon solvents but indicate that they are cleaved to monomeric species of the type M(L)/sub 2/CIS in ligating solvents such as dimethylformamide (S = solvent). The absorption spectra of each of the complexes contain several low-energy bands which are assigned as metal-to-ligand charge-transfer (MLCT) transitions. All four of the dimers emit light following photoexcitation of their glassy solutions at 77 K. Their emission spectra and lifetimes lead to assignments of their emitting states as intraligand for the Rh(III) dimers and MLCT for the Ir(III) dimers. The Ir(III) dimers are also found to emit light following excitation at 295 K in deaerated dichloromethane. No emission is seen from the Rh(III) dimers under these conditions. Comparison of these results with previous results from studies of similar Rh(III) and Ir(III) complexes of 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) indicates that the ortho-metalated ligands are considerably higher than bpy and phen in the spectrochemical series. In addition to raising the energy of ligand field excited states in their complexes, relative to similar bpy and phen species, they induce lower energy charge-transfer transitions. These effects are consistent with the synergistic function of the ortho-metalated ligands as both strong sigma donors and ..pi.. acceptors.

  17. THE EFFECTS OF CURRENT FLOW ON BIOELECTRIC POTENTIAL : III. NITELLA.

    PubMed

    Blinks, L R

    1936-11-20

    String galvanometer records show the effect of current flow upon the bioelectric potential of Nitella cells. Three classes of effects are distinguished. 1. Counter E.M.F'S, due either to static or polarization capacity, probably the latter. These account for the high effective resistance of the cells. They record as symmetrical charge and discharge curves, which are similar for currents passing inward or outward across the protoplasm, and increase in magnitude with increasing current density. The normal positive bioelectric potential may be increased by inward currents some 100 or 200 mv., or to a total of 300 to 400 mv. The regular decrease with outward current flow is much less (40 to 50 mv.) since larger outward currents produce the next characteristic effect. 2. Stimulation. This occurs with outward currents of a density which varies somewhat from cell to cell, but is often between 1 and 2 microa/cm.(2) of cell surface. At this threshold a regular counter E.M.F. starts to develop but passes over with an inflection into a rapid decrease or even disappearance of positive P.D., in a sigmoid curve with a cusp near its apex. If the current is stopped early in the curve regular depolarization occurs, but if continued a little longer beyond the first inflection, stimulation goes on to completion even though the current is then stopped. This is the "action current" or negative variation which is self propagated down the cell. During the most profound depression of P.D. in stimulation, current flow produces little or no counter E.M.F., the resistance of the cell being purely ohmic and very low. Then as the P.D. begins to recover, after a second or two, counter E.M.F. also reappears, both becoming nearly normal in 10 or 15 seconds. The threshold for further stimulation remains enhanced for some time, successively larger current densities being needed to stimulate after each action current. The recovery process is also powerful enough to occur even though the original

  18. Selective Recovery of Chromium from Precipitates Containing d Elements and Actinides: III. Effect of S2O8 2-

    SciTech Connect

    Fedoseev, A. M.; Shilov, V. P.; Budantseva, N. A.; Yusov, A. B.; Delegard, Calvin H.

    2002-07-15

    The interaction of Cr(III) hydroxides and mixed Fe(III)-Cr(III) and Ni(II)-Cr(III) hydroxides with persulfate ions has been investigated in alkaline media by a spectrophotometric method. The stoichiometric yield of Cr(VI) corresponds to a molar ratio of S2O82-:Cr(III) close to 1.5. The initial rate of the reaction is described by the equation d[Cr(III)]/dt = k[Cr(III)][S2O82-][NaOH]. The activation energy in the range 41.5-95?C is 53 kJ/mole. The V0 value is higher than the rate of thermal decomposition of persulfate; i.e. Cr(III) hydroxide reacts directly with S2O82-. The oxidation of NiCr2O4?nH2O and mixed Fe(III)-Cr(III) hydroxides proceeds faster than oxidation of pure Cr(III) hydroxide. The acceleration is explained by the catalytic effect of Fe(III) and Ni(II). Additions of Co(II) and Cu(II) also accelerate the oxidation. Pu(IV) in alkaline media is oxidized to higher more soluble states by persulfate but may be reduced by the action of appropriate reducing agents.

  19. Collisionless microtearing modes in hot tokamaks: Effect of trapped electrons

    SciTech Connect

    Swamy, Aditya K.; Ganesh, R.; Brunner, S.; Vaclavik, J.; Villard, L.

    2015-07-15

    Collisionless microtearing modes have recently been found linearly unstable in sharp temperature gradient regions of large aspect ratio tokamaks. The magnetic drift resonance of passing electrons has been found to be sufficient to destabilise these modes above a threshold plasma β. A global gyrokinetic study, including both passing electrons as well as trapped electrons, shows that the non-adiabatic contribution of the trapped electrons provides a resonant destabilization, especially at large toroidal mode numbers, for a given aspect ratio. The global 2D mode structures show important changes to the destabilising electrostatic potential. The β threshold for the onset of the instability is found to be generally downshifted by the inclusion of trapped electrons. A scan in the aspect ratio of the tokamak configuration, from medium to large but finite values, clearly indicates a significant destabilizing contribution from trapped electrons at small aspect ratio, with a diminishing role at larger aspect ratios.

  20. Effect of material perception on mode of color appearance.

    PubMed

    Kuriki, Ichiro

    2015-01-01

    The mode of color appearance (mode) is a concept suggesting that variations in a medium that emits, transmits, or reflects light can cause differences in color appearance. For example, the same light beams that appear brown (or gray) when reflected from a given object surface may appear orange (or white) when emitted from a light source. The present study investigated the relationships between material perception and perceived mode, especially in terms of luminosity. In the experiment, a rotating spheroid was presented with surrounds of various luminance levels. The surface texture of the spheroid was either matte gray (three surface reflectance levels) or one of two fabrics. The participants were asked to evaluate the luminosity (mode) and perceived reflectance of the object. The results show that the mode perception is clearly different from the lightness perception. The luminosity was fit with a linear function of the lightness scale in CIE (Commission Internationale de l'Éclairage) L* value of the object surface, unless the material of the surface was identifiable. To conclude, the luminosity (mode) perception can be strongly affected by the material percept, and the luminosity perception of the same object can vary when its surface property is ambiguous. PMID:26057547

  1. The effect of magnetopause motion on fast mode resonance

    NASA Astrophysics Data System (ADS)

    Hartinger, M. D.; Welling, D.; Viall, N. M.; Moldwin, M. B.; Ridley, A.

    2014-10-01

    The Earth's magnetosphere supports several types of ultralow frequency (ULF) waves. These include fast mode resonance (FMR): cavity modes, waveguide modes, and tunneling modes/virtual resonance. The magnetopause, often treated as the outer boundary for cavity/waveguide modes in the dayside magnetosphere, is not stationary. A rapidly changing outer boundary condition—e.g., due to rapid magnetopause motion—is not favorable for FMR generation and may explain the sparseness of FMR observations in the outer magnetosphere. We examine how magnetopause motion affects the dayside magnetosphere's ability to sustain FMR with idealized Space Weather Modeling Framework (SWMF) simulations using the BATS-R-US global magnetohydrodynamic (MHD) code coupled with the Ridley Ionosphere Model (RIM). We present observations of FMR in BATS-R-US, reproducing results from other global MHD codes. We further show that FMR is present for a wide range of solar wind conditions, even during periods with large and rapid magnetopause displacements. We compare our simulation results to FMR observations in the dayside magnetosphere, finding that FMR occurrence does not depend on solar wind dynamic pressure, which can be used as a proxy for dynamic pressure fluctuations and magnetopause perturbations. Our results demonstrate that other explanations besides a nonstationary magnetopause—such as the inability to detect FMR in the presence of other ULF wave modes with large amplitudes—are required to explain the rarity of FMR observations in the outer magnetosphere.

  2. Effects of PECS Phase III Application Training on Independent Mands in Young Children with Autism

    ERIC Educational Resources Information Center

    Love, Jessica June

    2013-01-01

    The purpose of this study was to examine the effects of PECS phase III application training on independent mands in young children with autism. Participants were five children with autism ranging from ages 2 to 4 years old. A multiple baseline across participants was used to evaluate acquisition of independent correct mands across baseline and…

  3. The competitive effects of Ca(II) on Eu(III) sorption to goethite

    SciTech Connect

    Gall, E.J.; Snyder, L.I.; Bryce, A.L.

    1995-12-01

    Predictive modeling of the transport of trivalent rare earth and actinide elements in the geosphere is difficult as the mechanism of lanthanide sorption in natural systems is not well understood. Experimental data demonstrating rare earth sorption to soil components under environmentally realistic conditions is lacking. In this presentation, we report on the competitive effects of the presence of a major cation, Ca(II), on the sorption of Eu(III) to goethite. pH sorption edges and isotherms will be presented for both of these elements. Variables considered are ionic strength as well as Ca(II) and Eu(III) concentrations. Finally, mechanisms of lanthanide sorption will be discussed.

  4. Oxygen effect in the radiolysis of proteins. III. Haemoglobin.

    PubMed

    Puchała, M; Schuessler, H

    1993-08-01

    Radiolysis of haemoglobin was carried out in phosphate buffer under air, N2 or N2O and with and without ethanol. Radiation products were separated by SDS-PAGE. The loss of subunits and simultaneous aggregation and fragmentation of haemoglobin was measured, if OH-radicals were unscavenged. There was no sensitizing effect of oxygen on the degradation process. Radiation-induced fragmentation was not a random process, but produced specific fragments. The estimated molecular weights of these fragments gave further support to the assumption that the aminoacyl-proline peptide group is the preferential breaking site if OH radicals react with proteins in the presence of oxygen. In contrast with lactate dehydrogenase and bovine serum albumin such fragmentation was observed not only after aerobic radiolysis but also under anaerobic conditions. This difference must be caused by the Feporphyrin system which reacts with H2O2 under release of oxygen. If haemoglobin was irradiated under air the yield of aggregates was much lower than under N2O or N2. PMID:8103537

  5. Influence of retrieval mode on effects of production: Evidence for costs in free recall.

    PubMed

    Mama, Yaniv; Icht, Michal

    2016-06-01

    Study modality (visual, auditory) of words as well as production mode (reading aloud, writing down) have been shown to influence the production effect (PE). When study words are presented visually, reading them aloud yields superior memory. However, when the same study words are presented aurally, writing them down leads to superior memory. Missing in PE studies is the variable of retrieval mode (written, aloud), which was addressed in the present study. In a pair of experiments, we manipulated the 3 variables-study modality, production mode, and retrieval mode-in a factorial fashion. With visual study, aloud production mode (vocalizing) was found to be superior to written production, in both retrieval modes (written and aloud). However, the difference between the productions was significantly smaller in the aloud retrieval mode relative to the written retrieval mode. With auditory study, written production mode was superior to aloud production mode, in the written as well as in the aloud retrieval modes. Here, the difference between the productions was significantly smaller in the written relative to the aloud retrieval mode. In other words, the difference between productions was smaller for the retrieval mode that matched the superior production. We interpret these findings using a retrieval-cost account. (PsycINFO Database Record PMID:27244359

  6. Effects of Fe(III) and organic matter additions on methanogenic activity and Fe(III) reduction in boreal lake and wetland sediments

    NASA Astrophysics Data System (ADS)

    Karvinen, Anu; Lehtinen, Lotta; Kankaala, Paula

    2013-04-01

    We studied potential methane production and Fe(III) reduction activity in lake sediments and wetland peat sampled from 14 sites in southern and eastern Finland. The concentration of total iron in the sediments and peat varied between 0.5 and 1200 ppm and their organic matter content (loss of ignition) varied between 1-98% of dry weight. Also the effects of added amorphous Fe(III) oxyhydroxide and organic matter (ammoniumacetate and/or sodiumacetate) on methanogenic and Fe(III) reduction activities were studied in anaerobic laboratory incubations (in vitro) lasting 5-20 days at 15 °C in darkness. Potential methane production and the effects of iron and acetate additions were highly variable between lake and peatland sites. The highest methanogenic potential was generally measured in productive littoral sites, especially in those dominated by Phragmites australis vegetation stands. In these sediments the total iron concentrations were high and acetate additions clearly increased methane production whereas Fe(III) additions decreased it. Our results demonstrate that microbial Fe(III) reduction plays an important role in the anaerobic organic matter decomposition in many boreal lakes.

  7. Effects of travel mode on exposures to particulate air pollution.

    PubMed

    Briggs, David J; de Hoogh, Kees; Morris, Chloe; Gulliver, John

    2008-01-01

    Monitoring was carried out of particulate concentrations whilst simultaneously walking and driving 48 routes in London, UK. Monitoring was undertaken during May and June 2005. Route lengths ranged from 601 to 1351 m, and most routes were travelled in both directions. Individual journey times ranged from 1.5 to 15 min by car (average 3.7 min) and 7.3 to 30 min (average 12.8 min) whilst walking; car trips were therefore repeated up to 5 times for each single walking trip and the results averaged for the route. Car trips were made with windows closed and the ventilation system on a moderate setting. Results show that mean exposures while walking are greatly in excess of those while driving, by a factor 4.7 for the coarse particle mass (PM10-PM2.5), 2.2 for the fine particle mass (PM2.5-PM1), 1.9 for the very fine particle mass (mode from car to walking in response to policies aimed at encouraging a modal shift in travel behavior are thus likely to experience considerably increased journey-time personal exposures to traffic-related air pollution. More effort is consequently needed to increase separation between road vehicles and pedestrians if negative effects of these policies are to be avoided. PMID:17688949

  8. Mixed-mode fracture of ceramics

    SciTech Connect

    Petrovic, J.J.

    1985-01-01

    The mixed-mode fracture behavior of ceramic materials is of importance for monolithic ceramics in order to predict the onset of fracture under generalized loading conditions and for ceramic composites to describe crack deflection toughening mechanisms. Experimental data on surface flaw mixed-mode fracture in various ceramics indicate that the flaw-plane normal stress at fracture decreases with increasing in-flaw-plane shear stress, although present data exhibit a fairly wide range in details of this sigma - tau relationship. Fracture from large cracks suggests that Mode II has a greater effect on Mode I fracture than Mode III. A comparison of surface flaw and large crack mixed-mode I-II fracture responses indicated that surface flaw behavior is influenced by shear resistance effects.

  9. Alpha-particle effects on ballooning flute modes in tokamaks

    SciTech Connect

    Andrushchenko, Z.N.; Bijko, A.Y.; Cheremnykh, O.K. )

    1990-11-01

    In this paper a more accurate dispersion equation for ideal ballooning flute modes in a plasma with alpha particles is obtained. It is shown that circulating and trapped alpha particles generate the eigenbranches of the mode oscillations with frequencies {omega} {approx lt} {omega}{sub *i}, where {omega}{sub *i}, is the ion drift frequency. The relevant growth rates and frequencies are found. It is ascertained that in the frequency range {omega}{sub *i} {lt} {omega} {lt} {bar {omega}{sub Db}}, where {bar {omega}{sub Db}} is the magnetic drift frequency average over a bounce period, trapped alpha particles may generate forced oscillations that influence the ideal ballooning flute mode stability boundary. It is shown that the stability may be improved for certain plasma parameters and trapped alpha-particle pressures.

  10. EFFECTS OF A DEEP MIXED SHELL ON SOLAR g-MODES, p-MODES, AND NEUTRINO FLUX

    SciTech Connect

    Wolff, Charles L.

    2009-08-10

    A mixed-shell model that reflects g-modes away from the Sun's center is developed further by calibrating its parameters and evaluating a mixing mechanism: buoyancy. The shell roughly doubles g-mode oscillation periods and would explain why there is no definitive detection of their periods. But the shell has only minor effects on most p-modes. The model provides a mechanism for causing short-term fluctuations in neutrino flux and makes plausible the correlations between this flux and solar activity levels. Relations are derived for a shell heated asymmetrically by transient increases in nuclear burning in small 'hot spots'. The size of these spots and the timing of a heating event are governed by sets(l) of standing asymptotic g-modes, coupled by a maximal principle that greatly enhances their excitation and concentrates power toward the equator, assisting the detection of higher-l sets. Signals from all sets, except one, in the range 2 {<=} l {<=} 8 are identified by difference periods between consecutive radial states using the method of Garcia et al. and reinterpreting their latest spectrum. This confirms two detections of sets in a similar range of l by their rotation rates. The mean radius of shell mixing is r{sub m} = 0.16 R{sub sun}, which improves an earlier independent estimate of 0.18 by the author. The shell may cause the unexplained dip in measured sound speed at its location. Another sound speed error, centered near 0.67 R{sub sun}, and reversing flows in the same place with a period originally near 1.3 yr suggest that the g-modes are depositing there about 3% of the solar luminosity. That implies the shell at r{sub m} is receiving a similar magnitude of power, which would be enough energy to mix the corresponding shell in a standard solar model in <<10{sup 7} yr.

  11. Strain-effect transistors: Theoretical study on the effects of external strain on III-nitride high-electron-mobility transistors on flexible substrates

    SciTech Connect

    Shervin, Shahab; Asadirad, Mojtaba; Kim, Seung-Hwan; Ravipati, Srikanth; Lee, Keon-Hwa; Bulashevich, Kirill; Ryou, Jae-Hyun

    2015-11-09

    This paper presents strain-effect transistors (SETs) based on flexible III-nitride high-electron-mobility transistors (HEMTs) through theoretical calculations. We show that the electronic band structures of InAlGaN/GaN thin-film heterostructures on flexible substrates can be modified by external bending with a high degree of freedom using polarization properties of the polar semiconductor materials. Transfer characteristics of the HEMT devices, including threshold voltage and transconductance, are controlled by varied external strain. Equilibrium 2-dimensional electron gas (2DEG) is enhanced with applied tensile strain by bending the flexible structure with the concave-side down (bend-down condition). 2DEG density is reduced and eventually depleted with increasing compressive strain in bend-up conditions. The operation mode of different HEMT structures changes from depletion- to enchantment-mode or vice versa depending on the type and magnitude of external strain. The results suggest that the operation modes and transfer characteristics of HEMTs can be engineered with an optimum external bending strain applied in the device structure, which is expected to be beneficial for both radio frequency and switching applications. In addition, we show that drain currents of transistors based on flexible InAlGaN/GaN can be modulated only by external strain without applying electric field in the gate. The channel conductivity modulation that is obtained by only external strain proposes an extended functional device, gate-free SETs, which can be used in electro-mechanical applications.

  12. Strain-effect transistors: Theoretical study on the effects of external strain on III-nitride high-electron-mobility transistors on flexible substrates

    NASA Astrophysics Data System (ADS)

    Shervin, Shahab; Kim, Seung-Hwan; Asadirad, Mojtaba; Ravipati, Srikanth; Lee, Keon-Hwa; Bulashevich, Kirill; Ryou, Jae-Hyun

    2015-11-01

    This paper presents strain-effect transistors (SETs) based on flexible III-nitride high-electron-mobility transistors (HEMTs) through theoretical calculations. We show that the electronic band structures of InAlGaN/GaN thin-film heterostructures on flexible substrates can be modified by external bending with a high degree of freedom using polarization properties of the polar semiconductor materials. Transfer characteristics of the HEMT devices, including threshold voltage and transconductance, are controlled by varied external strain. Equilibrium 2-dimensional electron gas (2DEG) is enhanced with applied tensile strain by bending the flexible structure with the concave-side down (bend-down condition). 2DEG density is reduced and eventually depleted with increasing compressive strain in bend-up conditions. The operation mode of different HEMT structures changes from depletion- to enchantment-mode or vice versa depending on the type and magnitude of external strain. The results suggest that the operation modes and transfer characteristics of HEMTs can be engineered with an optimum external bending strain applied in the device structure, which is expected to be beneficial for both radio frequency and switching applications. In addition, we show that drain currents of transistors based on flexible InAlGaN/GaN can be modulated only by external strain without applying electric field in the gate. The channel conductivity modulation that is obtained by only external strain proposes an extended functional device, gate-free SETs, which can be used in electro-mechanical applications.

  13. Coherence Effects of Caroli-de Gennes-Matricon Modes in Nodal Topological Superconductors

    NASA Astrophysics Data System (ADS)

    Tsutsumi, Yasumasa; Kato, Yusuke

    2016-05-01

    Coherence effects by the impurity scattering of Caroli-de Gennes-Matricon (CdGM) modes in a vortex for nodal topological superconductors have been studied. The coherence effects reflect a topological number defined on a particular momentum space avoiding the superconducting gap nodes. First, we analytically derived the eigenvalue and eigenfunction of the CdGM modes, including the zero-energy modes, in a nodal topological superconducting state without impurities, where we focused on a possible superconducting state of UPt3 as an example. Then, we studied impurity effects on the CdGM modes by introducing the impurity self-energy, which are dominated by the coherence factor depending on the eigenfunction of the CdGM modes. For the zero-energy CdGM modes, the coherence factor vanishes in a certain momentum range, which is guaranteed by topological invariance characterized by the one-dimensional winding number.

  14. Increasing Facilitator Effectiveness by Bridging Two Modes of Consciousness.

    ERIC Educational Resources Information Center

    Alperson, Erma Dosamantes

    To fully explore the range of our human consciousness, we must have access to all available modes of experiencing: the bodily-implicit and the rational-explicit. To the extent that we become alienated from our bodily-felt side, we respond solely in terms of what the external situation demands. We lose sight of our own feelings and needs and…

  15. The effect of reactor geometry on frontal polymerization spin modes

    NASA Astrophysics Data System (ADS)

    Pojman, John A.; Masere, Jonathan; Petretto, Enrico; Rustici, Mauro; Huh, Do-Sung; Kim, Min Suk; Volpert, Vladimir

    2002-03-01

    Using reactors of different sizes and geometries the dynamics of the frontal polymerization of 1,6-hexanediol diacrylate (HDDA) and pentaerythritol tetraacrylate (PETAC), with ammonium persulfate as the initiator were studied. For this system, the frontal polymerization exhibits complex behavior that depends on the ratio of the monomers. For a particular range of monomers concentration, the polymerization front becomes nonplanar, and spin modes appear. By varying the reactor diameter, we experimentally confirmed the expected shift of the system to a greater number of "hot spots" for larger diameters. For square test tubes a "zig-zag" mode was observed for the first time in frontal polymerization. We confirmed the viscosity-dependence of the spin mode instabilities. We also observed novel modes in cylinder-inside-cylinder reactors. Lastly, using a conical reactor with a continuously varying diameter, we observed what may be evidence for bistability depending on the direction of propagation. We discuss these finding in terms of the standard linear stability analysis for propagating fronts.

  16. Failure mode and effects analysis outputs: are they valid?

    PubMed Central

    2012-01-01

    Background Failure Mode and Effects Analysis (FMEA) is a prospective risk assessment tool that has been widely used within the aerospace and automotive industries and has been utilised within healthcare since the early 1990s. The aim of this study was to explore the validity of FMEA outputs within a hospital setting in the United Kingdom. Methods Two multidisciplinary teams each conducted an FMEA for the use of vancomycin and gentamicin. Four different validity tests were conducted: · Face validity: by comparing the FMEA participants’ mapped processes with observational work. · Content validity: by presenting the FMEA findings to other healthcare professionals. · Criterion validity: by comparing the FMEA findings with data reported on the trust’s incident report database. · Construct validity: by exploring the relevant mathematical theories involved in calculating the FMEA risk priority number. Results Face validity was positive as the researcher documented the same processes of care as mapped by the FMEA participants. However, other healthcare professionals identified potential failures missed by the FMEA teams. Furthermore, the FMEA groups failed to include failures related to omitted doses; yet these were the failures most commonly reported in the trust’s incident database. Calculating the RPN by multiplying severity, probability and detectability scores was deemed invalid because it is based on calculations that breach the mathematical properties of the scales used. Conclusion There are significant methodological challenges in validating FMEA. It is a useful tool to aid multidisciplinary groups in mapping and understanding a process of care; however, the results of our study cast doubt on its validity. FMEA teams are likely to need different sources of information, besides their personal experience and knowledge, to identify potential failures. As for FMEA’s methodology for scoring failures, there were discrepancies between the teams’ estimates

  17. Effects of Composition Mode and Self-Perceived Computer Skills on Essay Scores of Sixth Graders

    ERIC Educational Resources Information Center

    Burke, Jennifer N.; Cizek, Gregory J.

    2006-01-01

    This study was conducted to gather evidence regarding effects of the mode of writing (handwritten vs. word-processed) on compositional quality in a sample of sixth grade students. Questionnaire data and essay scores were gathered to examine the effect of composition mode on essay scores of students of differing computer skill levels. The study was…

  18. Refractive index sensing characteristic of single-mode-multimode-single-mode fiber structure based on self-imaging effect

    NASA Astrophysics Data System (ADS)

    Bai, Xuekun; Wang, Haotian; Wang, Shaofei; Pu, Shengli; Zeng, Xianglong

    2015-10-01

    We research the refractive index (RI) sensing characteristic based on the bandpass spectrum caused by the self-imaging effect in the single-mode-multimode-single-mode (SMS) fiber structure theoretically and experimentally. A new selectable parameter, i.e., no-core fiber (NCF) length, is investigated for improving the sensitivity of the sensor. The results show that the sensor's sensitivity will be enhanced by shortening the NCF length when the self-imaging number remains constant. Experimentally, a maximum sensitivity of 1923 nm/RIU (RI unit) has been achieved when the RI ranges from 1.334 to 1.434. This work demonstrates a method to improve the sensitivity of SMS-fiber-structure-based RI sensors featuring a low cost, compact size, low insert loss, and high sensitivity optical fiber RI sensor.

  19. Phosphorylation by PKA and Cdk5 Mediates the Early Effects of Synapsin III in Neuronal Morphological Maturation.

    PubMed

    Piccini, Alessandra; Perlini, Laura E; Cancedda, Laura; Benfenati, Fabio; Giovedì, Silvia

    2015-09-23

    central role in early stages of neuronal development involving neuronal survival, polarization, and neuritic growth and that these effects are dependent on phosphorylation by cAMP-dependent protein kinase and cyclin-dependent protein kinase-5. These results explain the recently described neurodevelopmental defects in the migration and orientation of Synapsin III-depleted cortical neurons and support the potential association of Synapsin III with neurodevelopmental disorders such as schizophrenia. PMID:26400944

  20. Effect of tris(3-hydroxy-4-pyridinonate) iron(III) complexes on iron uptake and storage in soybean (Glycine max L.).

    PubMed

    Santos, Carla S; Carvalho, Susana M P; Leite, Andreia; Moniz, Tânia; Roriz, Mariana; Rangel, António O S S; Rangel, Maria; Vasconcelos, Marta W

    2016-09-01

    Iron deficiency chlorosis (IDC) is a serious environmental problem affecting the growth of several crops in the world. The application of synthetic Fe(III) chelates is still one of the most common measures to correct IDC and the search for more effective Fe chelates remains an important issue. Herein, we propose a tris(3-hydroxy-4-pyridinonate) iron(III) complex, Fe(mpp)3, as an IDC corrector. Different morphological, biochemical and molecular parameters were assessed as a first step towards understanding its mode of action, compared with that of the commercial fertilizer FeEDDHA. Plants treated with the pyridinone iron(III) complexes were significantly greener and had increased biomass. The total Fe content was measured using ICP-OES and plants treated with pyridinone complexes accumulated about 50% more Fe than those treated with the commercial chelate. In particular, plants supplied with compound Fe(mpp)3 were able to translocate iron from the roots to the shoots and did not elicit the expression of the Fe-stress related genes FRO2 and IRT1. These results suggest that 3,4-HPO iron(III) chelates could be a potential new class of plant fertilizing agents. PMID:27156133

  1. Anharmonicity effects in the frictionlike mode of graphite

    NASA Astrophysics Data System (ADS)

    Menéndez, C.; Lobato, A.; Abbasi-Pérez, D.; Fernández-Núñez, J.; Baonza, V. G.; Recio, J. M.

    2016-04-01

    Graphite is a prototypical solid lubricant demanding a thorough understanding of its low-friction behavior. The E2 g(1) Raman active vibrational mode of graphite is associated with the rigid-layer relative movement of its graphene sheets. Thus, this mode can provide a good means of exploring the low resistance of graphene layers to slip with respect to each other. To take advantage of this fact, the anharmonicity of the E2 g(1) mode has to be carefully characterized and evaluated since the atomic arrangement of carbon atoms in the ambient condition ABA stacking of graphite evidences potential asymmetry. The calculated one-dimensional energetic profile of the E2 g(1) mode reveals this local anisotropy around the energy minima and can be microscopically interpreted in terms of electron density interactions. Morse-type potentials accurately fit the energetic profiles at different interlayer separations, and provide simple analytical expressions for evaluating harmonic and anharmonic contributions to the Γ -point E2 g(1) frequency ωE2g(1 ) under a perturbative algebraic treatment. We quantify how the anharmonic contribution increases with the available energy (E ) at zero pressure, and how this contribution decreases as hydrostatic pressure (p ) or uniaxial stress is applied for a given available energy. The calculated ωE2g(1 )-p and ωE2g(1 )-E trends indicate an increasing (decreasing) of frictional forces in graphite with pressure (temperature). Our conclusions are supported by the good agreement of the calculated frequencies with existing Raman experiments under hydrostatic pressure conditions.

  2. Effect of Deformation Mode on the Wear Behavior of NiTi Shape Memory Alloys

    NASA Astrophysics Data System (ADS)

    Yan, Lina; Liu, Yong

    2016-06-01

    Owing to good biocompatibility, good fatigue resistance, and excellent superelasticity, various types of bio-medical devices based on NiTi shape memory alloy (SMA) have been developed. Due to the complexity in deformation mode in service, for example NiTi implants, accurate assessment/prediction of the surface wear process is difficult. This study aims at providing a further insight into the effect of deformation mode on the wear behavior of NiTi SMA. In the present study, two types of wear testing modes were used, namely sliding wear mode and reciprocating wear mode, to investigate the effect of deformation mode on the wear behavior of NiTi SMA in both martensitic and austenitic states. It was found that, when in martensitic state and under high applied loads, sliding wear mode resulted in more surface damage as compared to that under reciprocating wear mode. When in austenitic state, although similar trends in the coefficient of friction were observed, the coefficient of friction and surface damage in general is less under reciprocating mode than under sliding mode. These observations were further discussed in terms of different deformation mechanisms involved in the wear tests, in particular, the reversibility of martensite variant reorientation and stress-induced phase transformation, respectively.

  3. Effect of Deformation Mode on the Wear Behavior of NiTi Shape Memory Alloys

    NASA Astrophysics Data System (ADS)

    Yan, Lina; Liu, Yong

    2016-05-01

    Owing to good biocompatibility, good fatigue resistance, and excellent superelasticity, various types of bio-medical devices based on NiTi shape memory alloy (SMA) have been developed. Due to the complexity in deformation mode in service, for example NiTi implants, accurate assessment/prediction of the surface wear process is difficult. This study aims at providing a further insight into the effect of deformation mode on the wear behavior of NiTi SMA. In the present study, two types of wear testing modes were used, namely sliding wear mode and reciprocating wear mode, to investigate the effect of deformation mode on the wear behavior of NiTi SMA in both martensitic and austenitic states. It was found that, when in martensitic state and under high applied loads, sliding wear mode resulted in more surface damage as compared to that under reciprocating wear mode. When in austenitic state, although similar trends in the coefficient of friction were observed, the coefficient of friction and surface damage in general is less under reciprocating mode than under sliding mode. These observations were further discussed in terms of different deformation mechanisms involved in the wear tests, in particular, the reversibility of martensite variant reorientation and stress-induced phase transformation, respectively.

  4. Quantum cascade emission in the III-nitride material system designed with effective interface grading

    SciTech Connect

    Song, Alex Y. Huang, Tzu-Yung; Zah, Chung-En; Gmachl, Claire F.; Bhat, Rajaram; Wang, Jie; Allerman, Andrew A.

    2015-09-28

    We report the realization of quantum cascade (QC) light emission in the III-nitride material system, designed with effective interface grading (EIG). EIG induces a continuous transition between wells and barriers in the quantum confinement, which alters the eigenstate system and even delocalizes the states with higher energy. Fully transverse-magnetic spontaneous emission is observed from the fabricated III-nitride QC structure, with a center wavelength of ∼4.9 μm and a full width at half maximum of ∼110 meV, both in excellent agreement with theoretical predictions. A multi-peak photo-response spectrum is also measured from the QC structure, which again agrees well with theoretical calculations and verifies the effects of EIG.

  5. Gd(III) complexes for electron-electron dipolar spectroscopy: Effects of deuteration, pH and zero field splitting.

    PubMed

    Garbuio, Luca; Zimmermann, Kaspar; Häussinger, Daniel; Yulikov, Maxim

    2015-10-01

    Spectral parameters of Gd(III) complexes are intimately linked to the performance of the Gd(III)-nitroxide or Gd(III)-Gd(III) double electron-electron resonance (DEER or PELDOR) techniques, as well as to that of relaxation induced dipolar modulation enhancement (RIDME) spectroscopy with Gd(III) ions. These techniques are of interest for applications in structural biology, since they can selectively detect site-to-site distances in biomolecules or biomolecular complexes in the nanometer range. Here we report relaxation properties, echo detected EPR spectra, as well as the magnitude of the echo reduction effect in Gd(III)-nitroxide DEER for a series of Gadolinium(III) complexes with chelating agents derived from tetraazacyclododecane. We observed that solvent deuteration does not only lengthen the relaxation times of Gd(III) centers but also weakens the DEER echo reduction effect. Both of these phenomena lead to an improved signal-to-noise ratios or, alternatively, longer accessible distance range in pulse EPR measurements. The presented data enrich the knowledge on paramagnetic Gd(III) chelate complexes in frozen solutions, and can help optimize the experimental conditions for most types of the pulse measurements of the electron-electron dipolar interactions. PMID:26342680

  6. Gd(III) complexes for electron-electron dipolar spectroscopy: Effects of deuteration, pH and zero field splitting

    NASA Astrophysics Data System (ADS)

    Garbuio, Luca; Zimmermann, Kaspar; Häussinger, Daniel; Yulikov, Maxim

    2015-10-01

    Spectral parameters of Gd(III) complexes are intimately linked to the performance of the Gd(III)-nitroxide or Gd(III)-Gd(III) double electron-electron resonance (DEER or PELDOR) techniques, as well as to that of relaxation induced dipolar modulation enhancement (RIDME) spectroscopy with Gd(III) ions. These techniques are of interest for applications in structural biology, since they can selectively detect site-to-site distances in biomolecules or biomolecular complexes in the nanometer range. Here we report relaxation properties, echo detected EPR spectra, as well as the magnitude of the echo reduction effect in Gd(III)-nitroxide DEER for a series of Gadolinium(III) complexes with chelating agents derived from tetraazacyclododecane. We observed that solvent deuteration does not only lengthen the relaxation times of Gd(III) centers but also weakens the DEER echo reduction effect. Both of these phenomena lead to an improved signal-to-noise ratios or, alternatively, longer accessible distance range in pulse EPR measurements. The presented data enrich the knowledge on paramagnetic Gd(III) chelate complexes in frozen solutions, and can help optimize the experimental conditions for most types of the pulse measurements of the electron-electron dipolar interactions.

  7. 75 FR 11530 - Crystal Lake Wind III, LLC, et al.; Notice of Effectiveness of Exempt Wholesale Generator Status

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-11

    ... Energy Regulatory Commission Crystal Lake Wind III, LLC, et al.; Notice of Effectiveness of Exempt Wholesale Generator Status March 4, 2010. Docket Nos. Crystal Lake Wind III, LLC EG10-6-000 GardenGarden Wind, LLC EG10-7-000 Star Point Wind Project LLC EG10-8-000 Nacogdoches Power, LLC EG10-9-000...

  8. Effect of substrate discontinuities on the propagating surface plasmon polariton modes in gold nanobars

    NASA Astrophysics Data System (ADS)

    Johns, Paul; Yu, Kuai; Devadas, Mary Sajini; Li, Zhongming; Major, Todd A.; Hartland, Gregory V.

    2014-11-01

    The surface plasmon polariton (SPP) modes of gold nanobars (nanowires with rectangular dimensions) have been investigated by scanning pump-probe microscopy. In these experiments the nanobars were suspended over trenches cut in glass coverslips, and propagating SPP modes were launched in the supported portion of the nanobar by focusing a near-IR pump laser beam at the end of the nanobar. Transient absorption images were then collected by scanning the probe laser over the nanobar using a galvo-mirror system. The images show that the trench has a large effect on the SPP modes, specifically, for approximately half the nanowires the propagation length is significantly reduced after the trench. Finite element calculations were performed to understand this effect. The calculations show that the pump laser excites bound and leaky modes (modes that have their fields localized at the nanobar/glass or nanobar/air interfaces, respectively) in the supported portions of the nanobars. These modes propagate along the nanobar. When they meet the trench their field distributions are altered. The modes that derive from the bound mode are strongly damped over the trench. Thus, the bound mode is not reconstituted on the opposite side of the trench, and only the leaky mode contributes to the signal. Because the bound and leaky modes can have different propagation lengths, the propagation lengths measured in our experiments can change from one side of the trench to the other. The results show how the substrate can be engineered to control the SPP modes in metal nanostructures.The surface plasmon polariton (SPP) modes of gold nanobars (nanowires with rectangular dimensions) have been investigated by scanning pump-probe microscopy. In these experiments the nanobars were suspended over trenches cut in glass coverslips, and propagating SPP modes were launched in the supported portion of the nanobar by focusing a near-IR pump laser beam at the end of the nanobar. Transient absorption images

  9. Curvature effect on tearing modes in presence of neoclassical friction

    SciTech Connect

    Maget, Patrick; Mellet, Nicolas; Meshcheriakov, Dmytro; Garbet, Xavier; Lütjens, Hinrich

    2013-11-15

    Neoclassical physics (here associated to the poloidal variation of the magnetic field strength along field lines in a tokamak) is well known for driving self-generated plasma current and nonlinear magnetic islands associated to it in high performance, ITER relevant plasma discharges. It is demonstrated that the neoclassical friction between a magnetic perturbation and plasma flow already impacts magnetic islands in the linear regime, by inducing a weakening of curvature stabilization for tearing modes. This conclusion holds in particular for regimes where convection is influencing the pressure dynamics, as shown using a simple analytical model and confirmed in full Magneto-Hydro-Dynamics simulations.

  10. A destabilizing effect of rotation shear on magnetohydrodynamic ballooning modes

    SciTech Connect

    Connor, J. W.; Hastie, R. J.; Webster, A. J.

    2007-04-15

    The destabilization of ideal magnetohydrodynamic ballooning modes at finite rotation shear is demonstrated for the model s-{alpha} equilibrium by exploiting low magnetic shear, s, to simplify the two-dimensional stability problem to a one-dimensional eigenvalue problem. This simpler calculation captures the same features as exhibited by a full two-dimensional treatment, namely that stable values in the s-{alpha} stability diagram become unstable above a critical rotation shear. The first and second stability boundaries at low s are calculated as functions of rotation shear.

  11. The Effect of Plasma Shape on H-Mode Pedestal Characteristics on DIII-D

    SciTech Connect

    T.H. Osborne; J.R. Ferron; R.J. Groebner; L.L. Lao; A.W. Leonard; R. Maingi; R.L. Miller; A.D. Turnbull; M.R. Wade; J.G. Watkins

    1999-12-01

    The characteristics of the H-mode are studied in discharges with varying triangularity and squareness. The pressure at the top of the H-mode pedestal increases strongly with triangularity primarily due to an increase in the margin by which the edge pressure gradient exceeds the ideal ballooning mode first stability limit. Two models are considered for how the edge may exceed the ballooning mode limit. In one model [1], access to the ballooning mode second stable regime allows the edge pressure gradient and associated bootstrap current to continue to increase until an edge localized, low toroidal mode number, ideal kink mode is destabilized. In the second model [2], the finite width of the H-mode transport barrier, and diamagnetic effects raise the pressure gradient limit above the ballooning mode limit. We observe a weak inverse dependence of the width of the H-mode transport barrier, {Delta}, on triangularity relative to the previously obtained [3] scaling {Delta} {infinity} ({beta}{sub P}{sup PED}){sup 1/2}. The energy loss for Type I ELMs increases with triangularity in proportion to the pedestal energy increase. The temperature profile is found to respond stiffly to changes in T{sup PED} at low temperature, while at high temperature the response is additive. The response of the density profile is also found to play a role in the response of the total stored energy to changes in the W{sup PED}.

  12. Global particle-in-cell simulations of plasma pressure effects on Alfvenic modes

    SciTech Connect

    Mishchenko, Alexey; Koenies, Axel; Hatzky, Roman

    2011-01-15

    Global linear gyrokinetic particle-in-cell simulations of electromagnetic modes in realistic tokamak geometry are reported. The effect of plasma pressure on Alfvenic modes is studied. It is shown that the fast-particle pressure can considerably affect the shear Alfven wave continuum structure and hence the toroidicity-induced gap in the continuum. It is also found that the energetic ions can substantially reduce the growth rate of the ballooning modes (and perhaps completely stabilize them in a certain parameter range). Ballooning modes are found to be the dominant instabilities if the bulk-plasma pressure gradient is large enough.

  13. Finite Larmor radius effects on the (m = 2, n = 1) cylindrical tearing mode

    NASA Astrophysics Data System (ADS)

    Chen, Y.; Chowdhury, J.; Parker, S. E.; Wan, W.

    2015-04-01

    New field solvers are developed in the gyrokinetic code GEM [Chen and Parker, J. Comput. Phys. 220, 839 (2007)] to simulate low-n modes. A novel discretization is developed for the ion polarization term in the gyrokinetic vorticity equation. An eigenmode analysis with finite Larmor radius effects is developed to study the linear resistive tearing mode. The mode growth rate is shown to scale with resistivity as γ ˜ η1/3, the same as the semi-collisional regime in previous kinetic treatments [Drake and Lee, Phys. Fluids 20, 1341 (1977)]. Tearing mode simulations with gyrokinetic ions are verified with the eigenmode calculation.

  14. The effect of lanthanum(III) and cerium(III) ions between layers of manganese oxide on water oxidation.

    PubMed

    Najafpour, Mohammad Mahdi; Isaloo, Mohsen Abbasi; Hołyńska, Małgorzata; Shen, Jian-Ren; Allakhverdiev, Suleyman I; Allakhverdiev, Suleyman

    2015-12-01

    Manganese oxide structure with lanthanum(III) or cerium(III) ions between the layers was synthesized by a simple method. The ratio of Mn to Ce or La in samples was 0.00, 0.04, 0.08, 0.16, 0.32, 0.5, 0.82, or 1.62. The compounds were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction studies, and atomic absorption spectroscopy. The compounds show efficient catalytic activity of water oxidation in the presence of cerium(IV) ammonium nitrate with a turnover frequency of 1.6 mmol O2/mol Mn.s. In contrast to the water-oxidizing complex in Photosystem II, calcium(II) has no specific role to enhance the water-oxidizing activity of the layered manganese oxides and other cations can be replaced without any significant decrease in water-oxidizing activities of these layered Mn oxides. Based on this and previously reported results from oxygen evolution in the presence of H 2 (18) O, we discuss the mechanism and the important factors influencing the water-oxidizing activities of the manganese oxides. PMID:25701552

  15. Effect of toroidal magnetic field on n = 1 mode stability in rotamak plasmas

    SciTech Connect

    Yang, X.; Goss, J.; Kalaria, D.; Huang, T. S.

    2011-08-15

    To study the effect of toroidal magnetic field on n = 1 mode stability, a series of experiments with linearly ramping the axial current I{sub z}, which makes field-reversed configuration (FRC) to spherical tokamak (ST) transition, have been conducted in rotamak. Results clearly demonstrate that the tilt mode can be completely suppressed by small I{sub z} around 0.4 kA (in comparison with 2.0 kA plasma current). An unknown new mode with larger magnetic perturbations is triggered when I{sub z} reaches 0.5 kA. This instability mode keeps saturation while plasma current is boosted when I{sub z} is in the range of 0.6-1.4 kA. When I{sub z} exceeds 1.6 kA, the new mode suddenly disappears and discharge is free from instability modes.

  16. A study of the relative effectiveness and cost of computerized information retrieval in the interactive mode

    NASA Technical Reports Server (NTRS)

    Smetana, F. O.; Furniss, M. A.; Potter, T. R.

    1974-01-01

    Results of a number of experiments to illuminate the relative effectiveness and costs of computerized information retrieval in the interactive mode are reported. It was found that for equal time spent in preparing the search strategy, the batch and interactive modes gave approximately equal recall and relevance. The interactive mode however encourages the searcher to devote more time to the task and therefore usually yields improved output. Engineering costs as a result are higher in this mode. Estimates of associated hardware costs also indicate that operation in this mode is more expensive. Skilled RECON users like the rapid feedback and additional features offered by this mode if they are not constrained by considerations of cost.

  17. Effect of Pulse Duration on Polytetrafluoroethylene Shocked above the Crystalline Phase II-Iii Transition

    NASA Astrophysics Data System (ADS)

    Brown, E. N.; Gray, G. T.; Rae, P. J.; Trujillo, C. P.; Bourne, N. K.

    2007-12-01

    We present an experimental study of crystalline structure evolution of polytetrafluoroethylene (PTFE) due to pressure-induced phase transitions in a semi-crystalline polymer using soft-recovery, shock-loading techniques coupled with mechanical and chemical post-shock analysis. Gas-launched, plate impact experiments have been performed on pedigreed PTFE 7C, mounted in momentum-trapped, shock assemblies, with impact pressures above and below the phase II to phase III crystalline transition. Below the phase transition only subtle changes were observed in the crystallinity, microstructure, and mechanical response of PTFE. Shock loading of PTFE 7C above the phase II-III transition was seen to cause both an increase in crystallinity from 38% to ˜53% and a finer crystalline microstructure, and changed the yield and flow stress behavior. We particularly focus on the effect of pulse duration on the microstructure evolution.

  18. Shock Pulse Effects in PTFE Shocked Through the Crystalline Phase II--III Transition

    NASA Astrophysics Data System (ADS)

    Brown, Eric N.; Gray, George T., III; Rae, Philip J.; Bourne, Neil K.

    2008-03-01

    We present an experimental study of crystalline structure evolution of polytetrafluoroethylene (PTFE) due to pressure-induced phase transitions in a semi-crystalline polymer using soft-recovery, shock-loading techniques coupled with mechanical and chemical post-shock analysis. Gas-launched, plate impact experiments have been performed on pedigreed PTFE 7C, mounted in momentum-trapped, shock assemblies, with impact pressures above and below the phase II to phase III crystalline transition. Below the phase transition only subtle changes were observed in the crystallinity, microstructure, and mechanical response of PTFE. Shock loading of PTFE 7C above the phase II--III transition was seen to cause both an increase in crystallinity from 38% to ˜53% (by Differential Scanning Calorimetry, DSC) and a finer crystalline microstructure, and changed the yield and flow stress behavior. We particularly focus on the effect of pulse duration on the microstructure evolution.

  19. Effect of Pulse Duration on Polytetrafluoroethylene Shocked Above the Crystalline Phase II--III Transition

    NASA Astrophysics Data System (ADS)

    Brown, Eric N.; Gray, George T., III; Rae, Philip J.; Trujillo, Carl P.; Bourne, Neil K.

    2007-06-01

    We present an experimental study of crystalline structure evolution of polytetrafluoroethylene (PTFE) due to pressure-induced phase transitions in a semi-crystalline polymer using soft-recovery, shock-loading techniques coupled with mechanical and chemical post-shock analysis. Gas-launched, plate impact experiments have been performed on pedigreed PTFE 7C, mounted in momentum-trapped, shock assemblies, with impact pressures above and below the phase II to phase III crystalline transition. Below the phase transition only subtle changes were observed in the crystallinity, microstructure, and mechanical response of PTFE. Shock loading of PTFE 7C above the phase II--III transition was seen to cause both an increase in crystallinity from 38% to ˜53% (by Differential Scanning Calorimetry, DSC) and a finer crystalline microstructure, and changed the yield and flow stress behavior. We particularly focus on the effect of pulse duration on the microstructure evolution.

  20. Anion Effects on Lanthanide(III) Tetrazole-1-acetate Dinuclear Complexes Showing Slow Magnetic Relaxation and Photofluorescent Emission.

    PubMed

    Lu, Ying-Bing; Jiang, Xiao-Ming; Zhu, Shui-Dong; Du, Zi-Yi; Liu, Cai-Ming; Xie, Yong-Rong; Liu, Liang-Xian

    2016-04-18

    Three types of lanthanide complexes based on the tetrazole-1-acetic acid ligand and the 2,2'-bipyridine coligand were prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analyses; the formulas of these complexes are [Ln2(1-tza)4(NO3)2(2,2'-bipy)2] (Ln = Sm (1), Eu (2), Gd (3), Tb (4), Dy (5)), [Dy2(1-tza)4Cl2(2,2'-bipy)2] (6), and [Yb2(1-tza)4(NO3)2(2,2'-bipy)2] (7) (1-tza = tetrazole-1-acetate and 2,2'-bipy = 2,2'-bipyridine). They are dinuclear complexes possessing similar structures but different lanthanide(III) ion coordination geometries because of the distinction of peripheral anions (such as NO3(-) and Cl(-)) and the effect of lanthanide contraction. The variable-temperature magnetic susceptibilities of 1-6 were measured. Both Dy(III) complexes (5 and 6) display field-induced single-molecule magnet behaviors. Ab initio calculations revealed that the Dy(III) complex 6 possesses a more anisotropic Dy(III) ion in comparison to that in 5. The room-temperature photoluminescence spectra of Sm(III) (1), Eu(III) (2), Tb(III) (4), and Dy(III) (5 and 6) complexes exhibit strong characteristic emissions in the visible region, whereas the Yb(III) (7) complex shows near-infrared (NIR) luminescence. PMID:27023680

  1. Effect of substrate discontinuities on the propagating surface plasmon polariton modes in gold nanobars.

    PubMed

    Johns, Paul; Yu, Kuai; Devadas, Mary Sajini; Li, Zhongming; Major, Todd A; Hartland, Gregory V

    2014-11-01

    The surface plasmon polariton (SPP) modes of gold nanobars (nanowires with rectangular dimensions) have been investigated by scanning pump-probe microscopy. In these experiments the nanobars were suspended over trenches cut in glass coverslips, and propagating SPP modes were launched in the supported portion of the nanobar by focusing a near-IR pump laser beam at the end of the nanobar. Transient absorption images were then collected by scanning the probe laser over the nanobar using a galvo-mirror system. The images show that the trench has a large effect on the SPP modes, specifically, for approximately half the nanowires the propagation length is significantly reduced after the trench. Finite element calculations were performed to understand this effect. The calculations show that the pump laser excites bound and leaky modes (modes that have their fields localized at the nanobar/glass or nanobar/air interfaces, respectively) in the supported portions of the nanobars. These modes propagate along the nanobar. When they meet the trench their field distributions are altered. The modes that derive from the bound mode are strongly damped over the trench. Thus, the bound mode is not reconstituted on the opposite side of the trench, and only the leaky mode contributes to the signal. Because the bound and leaky modes can have different propagation lengths, the propagation lengths measured in our experiments can change from one side of the trench to the other. The results show how the substrate can be engineered to control the SPP modes in metal nanostructures. PMID:25321926

  2. Neoclassical effects on the stabilization of tearing mode by current modulation

    SciTech Connect

    Yang, Xiaoqing Wang, Shaojie; Yang, Weihong

    2014-02-15

    The neoclassical effects on the stabilization of tearing modes by current modulation have been investigated. Neoclassical effects enhance the resistivity and reduce the resistive diffusion time of the modulation current. Therefore, the oscillating current can penetrate deeper into the plasma. With an oscillating loop voltage, the plasma oscillates radially at the Ware-pinch velocity. These neoclassical effects improve the efficiency of tearing mode stabilization by the current modulation.

  3. Effect of density gradients in confined supersonic shear layers. Part 2: 3-D modes

    NASA Technical Reports Server (NTRS)

    Peroomian, Oshin; Kelly, R. E.

    1994-01-01

    The effect of basic flow density gradients on the supersonic wall modes were investigated in Part 1 of this analysis. In that investigation only the 2-D modes were studied. Tam and Hu investigated the 3-D modes in a confined vortex sheet and reported that the first 2-D Class A mode (A01) had the highest growth rate compared to all other 2-D and 3-D modes present in the vortex sheet for that particular set of flow patterns. They also showed that this result also held true for finite thickness shear layers with delta(sub w) less than 0.125. For free shear layers, Sandham and Reynolds showed that the 3-D K-H mode became the dominant mode for M(sub c) greater than 0.6. Jackson and Grosch investigated the effect of crossflow and obliqueness on the slow and fast odes present in a M(sub c) greater than 1 environment and showed that for certain combination of crossflow and wave angles the growth rates could be increased by up to a factor of 2 with respect to the 2-D case. The case studied here is a confined shear layer shown in Part 1. All solution procedures and basic low profiles are the same as in Part 1. The effect of density gradients on the 3-D modes present in the density ratios considered in Part 1 are investigated.

  4. The gallium(III)-salicylidene acylhydrazide complex shows synergistic anti-biofilm effect and inhibits toxin production by Pseudomonas aeruginosa.

    PubMed

    Rzhepishevska, Olena; Hakobyan, Shoghik; Ekstrand-Hammarström, Barbro; Nygren, Yvonne; Karlsson, Torbjörn; Bucht, Anders; Elofsson, Mikael; Boily, Jean-François; Ramstedt, Madeleine

    2014-09-01

    Bacterial biofilms cause a range of problems in many areas and especially in health care. Biofilms are difficult to eradicate with traditional antibiotics and consequently there is a need for alternative ways to prevent and/or remove bacterial biofilms. Furthermore, the emergence of antibiotic resistance in bacteria creates a challenge to find new types of antibiotics with a lower evolutionary pressure for resistance development. One route to develop such drugs is to target the so called virulence factors, i.e. bacterial systems used when bacteria infect a host cell. This study investigates synergy effects between Ga(III) ions, previously reported to suppress biofilm formation and growth in bacteria, and salicylidene acylhydrazides (hydrazones) that have been proposed as antivirulence drugs targeting the type three secretion system used by several Gram-negative pathogens, including Pseudomonas aerugionosa, during bacterial infection of host cells. A library of hydrazones was screened for: Fe(III) binding, enhanced anti-biofilm effect with Ga(III) on P. aeruginosa, and low cytotoxicity to mammalian cells. The metal coordination for the most promising ligand, 2-Oxo-2-[N-(2,4,6-trihydroxy-benzylidene)-hydrazino]-acetamide (ME0163) with Ga(III) was investigated using extended X-ray absorption fine structure spectroscopy as well as density functional theory. The results showed that Ga(III) chelates the hydrazone with 5- and 6-membered chelating rings, and that the Ga(III)-ME0163 complex enhanced the antibiofilm effect of Ga(III) while suppressing the type three secretion system in P. aeruginosa. The latter effect was not observed for the hydrazone alone and was similar for Ga(III)-citrate and Ga(III)-ME0163 complexes, indicating that the inhibition of virulence was caused by Ga(III). PMID:24837331

  5. Mass effect of redox reactions: A novel mode for surface plasmon resonance-based bioanalysis.

    PubMed

    Yuan, Pei-Xin; Deng, Sheng-Yuan; Xin, Peng; Ji, Xu-Bo; Shan, Dan; Cosnier, Serge

    2015-12-15

    The pursuit of more specific and sensitive response is a perpetual goal for modern bioassays. This work proposed a novel label-free strategy about redox-related mass effect based on the surface plasmon resonance (SPR) technique for ultrasensitive determination of DNA. The protocol starts with the modification of SPR gilded disk with the capture DNA (cDNA). After the conjugation of immobilized cDNA with the target DNA (tDNA), the hybridization chain reaction was triggered by the introduction of mutual partial complementary primers to elongate the terminal into a nanoscale duplex. As it is reported that porphyrin could intercalate into the grooves of the double-stranded DNA (dsDNA) scaffold, multiple positive-charged Fe(III)meso-tetra(N-methyl-4-pyridyl) porphine (FeTMPyP) with symmetric structure were uptaken for in situ formation of porphyrin-dsDNA complex. Given FeTMPyP a highly efficient catalysis for the peroxide reduction, its presence as a biomimetic cofactor was validated via circular dichroism and UV-vis spectroscopy, demonstrating a tight binding as well as high catalytic activity and stability. Using 4-chloro-1-naphthol as a proton donor, the catalytic reduction of H2O2 would oxidize it into insoluble benzo-4-chloro-hexadienone, which simultaneously deposited on the heterogeneous interface, leading to a significant amplification in both SPR response and topological height profile. The signal increment was proportional to the concentration of tDNA, thus an ultrasensitive SPR-based DNA assay was developed with a linear range over four orders of magnitudes and a sub-femtomolar detection limit of 0.73 fM. The developed methodology exemplifies a different way of thinking about mass-sensing modes, extending conventional SPR-based DNA analysis to relevant biomedical applications. PMID:26141105

  6. Matrix resin effects in composite delamination - Mode I fracture aspects

    NASA Technical Reports Server (NTRS)

    Hunston, Donald L.; Moulton, Richard J.; Johnston, Norman J.; Bascom, Willard D.

    1987-01-01

    A number of thermoset, toughened thermoset, and thermoplastic resin matrix systems were characterized for Mode I critical strain energy release rates, and their composites were tested for interlaminar critical strain energy release rates using the double cantilever beam method. A clear correlation is found between the two sets of data. With brittle resins, the interlaminar critical strain energy release rates are somewhat larger than the neat resin values due to a full transfer of the neat resin toughness to the composite and toughening mechanisms associated with crack growth. With tougher matrices, the higher critical strain energy release rates are only partially transferred to the composites, presumably because the fibers restrict the crack-tip deformation zones.

  7. Effect of Pressure Anisotropy on Relativistic Slow-Mode Shocks

    NASA Astrophysics Data System (ADS)

    Tenbarge, Jason; Hazeltine, Richard; Mahajan, Swadesh

    2009-11-01

    Shock mediated reconnection is a possible source for the high-energy non-thermal emissions observed in astrophysical systems such as pulsars and magnetars, gamma-ray bursts, and active galactic nuclei. In such strongly magnetized environments, strong gyrotropic anisotropy in the pressure is expected to occur due to synchrotron emission and various instabilities. A newly developed covariant fluid modelfootnotetextJ. M. TenBarge, R. D. Hazeltine, and S. M. Mahajan, Phys. Plasmas 15, 062112 (2008). for magnetized plasmas, incorporating pressure anisotropy but neglecting heat flow, is used to study Petschek type reconnection in a pair plasma governed by slow-mode shocks. The plasma parameters are found to be strongly modified by anisotropy on both sides of the shock.

  8. Failure modes and effects analysis of fusion magnet systems

    SciTech Connect

    Zimmermann, M; Kazimi, M S; Siu, N O; Thome, R J

    1988-12-01

    A failure modes and consequence analysis of fusion magnet system is an important contributor towards enhancing the design by improving the reliability and reducing the risk associated with the operation of magnet systems. In the first part of this study, a failure mode analysis of a superconducting magnet system is performed. Building on the functional breakdown and the fault tree analysis of the Toroidal Field (TF) coils of the Next European Torus (NET), several subsystem levels are added and an overview of potential sources of failures in a magnet system is provided. The failure analysis is extended to the Poloidal Field (PF) magnet system. Furthermore, an extensive analysis of interactions within the fusion device caused by the operation of the PF magnets is presented in the form of an Interaction Matrix. A number of these interactions may have significant consequences for the TF magnet system particularly interactions triggered by electrical failures in the PF magnet system. In the second part of this study, two basic categories of electrical failures in the PF magnet system are examined: short circuits between the terminals of external PF coils, and faults with a constant voltage applied at external PF coil terminals. An electromagnetic model of the Compact Ignition Tokamak (CIT) is used to examine the mechanical load conditions for the PF and the TF coils resulting from these fault scenarios. It is found that shorts do not pose large threats to the PF coils. Also, the type of plasma disruption has little impact on the net forces on the PF and the TF coils. 39 refs., 30 figs., 12 tabs.

  9. Linear and nonlinear effect of sheared plasma flow on resistive tearing modes

    SciTech Connect

    Hu, Qiming Hu, Xiwei; Yu, Q.

    2014-12-15

    The effect of sheared plasma flow on the m/n = 2/1 tearing mode is studied numerically (m and n are the poloidal and toroidal mode numbers). It is found that in the linear phase the plasma flow with a weak or moderate shear plays a stabilizing effect on tearing mode. However, the mode is driven to be more unstable by sufficiently strong sheared flow when approaching the shear Alfvén resonance (AR). In the nonlinear phase, a moderate (strong) sheared flow leads to a smaller (larger) saturated island width. The stabilization of tearing modes by moderate shear plasma flow is enhanced for a larger plasma viscosity and a lower Alfvén velocity. It is also found that in the nonlinear phase AR accelerates the plasma rotation around the 2/1 rational surface but decelerates it at the AR location, and the radial location satisfying AR spreads inwards towards the magnetic axis.

  10. The Hall dynamo effect and nonlinear mode coupling during sawtooth magnetic reconnection

    SciTech Connect

    Ding, W. X.; Brower, D. L.; Deng, B. H.; Almagri, A. F.; Craig, D.; Fiksel, G.; Mirnov, V.; Prager, S. C.; Sarff, J. S.; Svidzinski, V.

    2006-11-15

    During magnetic reconnection associated with sawtooth activity in a reversed field pinch, we observe a large fluctuation-induced Hall electromotive force, <{delta}Jx{delta}B>/n{sub e}e, which is capable of modifying the equilibrium current. This Hall dynamo effect is determined in the hot plasma core by laser Faraday rotation which measures equilibrium and fluctuating magnetic field and current density. We find that the Hall dynamo is strongest when nonlinear mode coupling between three spatial Fourier modes of the resistive tearing instability is present. Mode coupling alters the phase relation between magnetic and current density fluctuations for individual Fourier modes leading to a finite Hall effect. Detailed measurements of the spatial and temporal dynamics for the dominant core resonant mode under various plasma configurations are described providing evidence regarding the origin of the Hall dynamo.

  11. Zero-mode clad waveguides for performing spectroscopy with confined effective observation volumes

    DOEpatents

    Levene, Michael J.; Korlach, Jonas; Turner, Stephen W.; Craighead, Harold G.; Webb, Watt W.

    2005-07-12

    The present invention is directed to a method and an apparatus for analysis of an analyte. The method involves providing a zero-mode waveguide which includes a cladding surrounding a core where the cladding is configured to preclude propagation of electromagnetic energy of a frequency less than a cutoff frequency longitudinally through the core of the zero-mode waveguide. The analyte is positioned in the core of the zero-mode waveguide and is then subjected, in the core of the zero-mode waveguide, to activating electromagnetic radiation of a frequency less than the cut-off frequency under conditions effective to permit analysis of the analyte in an effective observation volume which is more compact than if the analysis were carried out in the absence of the zero-mode waveguide.

  12. Effect of Buckling Modes on the Fatigue Life and Damage Tolerance of Stiffened Structures

    NASA Technical Reports Server (NTRS)

    Davila, Carlos G.; Bisagni, Chiara; Rose, Cheryl A.

    2015-01-01

    The postbuckling response and the collapse of composite specimens with a co-cured hat stringer are investigated experimentally and numerically. These specimens are designed to evaluate the postbuckling response and the effect of an embedded defect on the collapse load and the mode of failure. Tests performed using controlled conditions and detailed instrumentation demonstrate that the damage tolerance, fatigue life, and collapse loads are closely tied with the mode of the postbuckling deformation, which can be different between two nominally identical specimens. Modes that tend to open skin/stringer defects are the most damaging to the structure. However, skin/stringer bond defects can also propagate under shearing modes. In the proposed paper, the effects of initial shape imperfections on the postbuckling modes and the interaction between different postbuckling deformations and the propagation of skin/stringer bond defects under quasi-static or fatigue loads will be examined.

  13. Tricarboxylate-based Gd(III) coordination polymers exhibiting large magnetocaloric effects.

    PubMed

    Liu, Sui-Jun; Cao, Chen; Xie, Chen-Chao; Zheng, Teng-Fei; Tong, Xiao-Lan; Liao, Jin-Sheng; Chen, Jing-Lin; Wen, He-Rui; Chang, Ze; Bu, Xian-He

    2016-05-31

    Two Gd(III) coordination polymers with the formula [Gd(cit)(H2O)]∞ () and [Gd(nta)(H2O)2]∞ () (H4cit = citric acid, H3nta = nitrilotriacetic acid) have been successfully prepared under hydrothermal conditions. Complex exhibits a three-dimensional (3D) structure based on carboxylate-bridged layers, while complex is a double-layer structure containing eight-coordinated Gd(III). Magnetic investigations reveal that weak antiferromagnetic couplings between adjacent Gd(III) ions in both and with different Weiss values result in large cryogenic magnetocaloric effects. It is notable that the maximum entropy changes (-ΔS) of and reach 31.3 J kg(-1) K(-1) and 32.2 J kg(-1) K(-1) at 2 K for a moderate field change (ΔH = 3 T), and a remarkable -ΔS (41.5 J kg(-1) K(-1) for and 42.0 J kg(-1) K(-1) for ) could be obtained for ΔH = 7 T. PMID:27171744

  14. Effect of Aspect Ratio on H-mode and ELM Characteristics

    NASA Astrophysics Data System (ADS)

    Thome, K. E.; Bodner, G. M.; Bongard, M. W.; Burke, M. G.; Fonck, R. J.; Kriete, D. M.

    2015-11-01

    The H-mode confinement regime is achieved at near-unity aspect ratio (A < 1 . 2) in the Pegasus Toroidal Experiment via high-field-side fueling and low edge recycling. Ohmic H-mode is attained in both limited and diverted magnetic topologies. This regime is characterized by: reduced Dα emissions; increased core rotation; increased central heating; formation of edge current and pressure pedestals; and measured energy confinement consistent with the ITER98pb(y,2) scaling. The H-mode power threshold, PLH , behaves quite differently at low- A when compared with high- A operations. PLH /PLH_ITPA 08 increases sharply as A is lowered and no difference in PLH for limited and diverted plasmas is observed at A ~ 1 . 2 . No minimum in PLH with density is observed. Some of these results are consistent with the FM3 model for the L-H transition. Two classes of ELMs have been observed. Small, Type III-like ELMs are present at low input power and have n <= 4 . At POH >>PLH , they transition to large, Type-I-like ELMs with intermediate 5 < n < 15 . The Type III ELM magnetic structures behave opposite that of high- A plasmas, with n much higher, presumably due to the naturally higher J / B peeling mode drive at low- A . Long-sought measurements of the Jedge (R , t) pedestal collapse during an ELM event show a complex, multimodal pedestal collapse and the subsequent ejection of a current-carrying filament. Work supported by US DOE grant DE-FG02-96ER54375.

  15. Effects of collective excitations on the G-band and RBM modes in the Raman spectra of metallic unfilled and filled carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Gayen, Saurabh; Behera, Surjyo; Bose, Shyamalendu

    2006-03-01

    The Raman spectra of a single-wall carbon nanotube (SWNT) consist of three types of modes; (i) the high frequency G-mode arising out of tangential oscillations of carbon atoms, (ii) D-mode due to the defects in the nanotube and (iii) the low frequency radial breathing mode (RBM) resulting out of radial oscillations of the carbon atoms. In this paper we theoretically investigate the effects of collective oscillations of electrons (plasmons) on the G and RBM modes in the Raman spectra of a filled and unfilled metallic SWNT. Inclusion of plasmon and the filling (rattler) atom produces four peaks in the Raman spectra in general. The positions and relative strengths of the Raman peaks [1] depend upon phonon frequencies of the nanotube and that of the filling atoms, the plasmon frequency, the strength of the electron-phonon interaction, strength of the interactions between the nanotube phonons and rattler phonon and radius of the nanotube [2]. Usually the intensity of the G-mode is higher than that of RBM. For heavier filling atoms the frequency of the rattler phonon is lower in value, which may broaden the peak to such an extent that it may disappear in the background spectrum altogether. 1.S.M. Bose et al., Physica B 351, 129 (2004) 2. S.M. Bose, S.Gayen and S. Behera, Phys. Rev. B 72, 153402 (2005).

  16. Effects of Tempo, Musical Experience, and Listening Modes on Tempo Modulation Perception.

    ERIC Educational Resources Information Center

    Sheldon, Deborah A.

    1994-01-01

    Reports on the effects of tempo direction, listening mode, and level of musical experience on speed and accuracy in tempo change among 160 music majors and nonmajors. Finds that music majors more accurately detected tempo changes than did nonmajors. (CFR)

  17. The genome of an Encephalitozoon cuniculi type III strain reveals insights into the genetic diversity and mode of reproduction of a ubiquitous vertebrate pathogen.

    PubMed

    Pelin, A; Moteshareie, H; Sak, B; Selman, M; Naor, A; Eyahpaise, M-È; Farinelli, L; Golshani, A; Kvac, M; Corradi, N

    2016-05-01

    Encephalitozoon cuniculi is a model microsporidian species with a mononucleate nucleus and a genome that has been extensively studied. To date, analyses of genome diversity have revealed the existence of four genotypes in E. cuniculi (EcI, II, III and IV). Genome sequences are available for EcI, II and III, and are all very divergent, possibly diploid and genetically homogeneous. The mechanisms that cause low genetic diversity in E. cuniculi (for example, selfing, inbreeding or a combination of both), as well as the degree of genetic variation in their natural populations, have been hard to assess because genome data have been so far gathered from laboratory-propagated strains. In this study, we aim to tackle this issue by analyzing the complete genome sequence of a natural strain of E. cuniculi isolated in 2013 from a steppe lemming. The strain belongs to the EcIII genotype and has been designated EcIII-L. The EcIII-L genome sequence harbors genomic features intermediate to known genomes of II and III lab strains, and we provide primers that differentiate the three E. cuniculi genotypes using a single PCR. Surprisingly, the EcIII-L genome is also highly homogeneous, harbors signatures of heterozygosity and also one strain-specific single-nucleotide polymorphism (SNP) that introduces a stop codon in a key meiosis gene, Spo11. Functional analyses using a heterologous system demonstrate that this SNP leads to a deficient meiosis in a model fungus. This indicates that EcIII-L meiotic machinery may be presently broken. Overall, our findings reveal previously unsuspected genome diversity in E. cuniculi, some of which appears to affect genes of primary importance for the biology of this pathogen. PMID:26837273

  18. Competitive effect of iron(III) on metal complexation by humic substances: characterisation of ageing processes.

    PubMed

    Lippold, H; Evans, N D M; Warwick, P; Kupsch, H

    2007-03-01

    Aiming at an assessment of counteractive effects on colloid-borne migration of actinides in the event of release from an underground repository, competition by Fe(III) in respect of metal complexation by dissolved organic matter was investigated for the example of Eu(III) as an analogue of trivalent actinides. Complexation with different humic materials was examined in cation exchange experiments, using (59)Fe and (152)Eu as radioactive tracers for measurements in dilute systems as encountered in nature. Competitive effects proved to be significant when Fe is present at micromolar concentrations. Flocculation as a limiting process was attributed to charge compensation of humic colloids. Fe fractions bound to humic acids (HA) were higher than 90%, exceeding the capacity of binding sites at high Fe concentrations. It is thus concluded that the polynuclear structure of hydrolysed Fe(III) is maintained when bound to HA, which is also inferred from UV-Vis spectrometry. The competitive effect was found to be enhanced if Fe and HA were in contact before Eu was added. Depending on the time of Fe/HA pre-equilibration, Eu complexation decreased asymptotically over a time period of several weeks, the amount of bound Fe being unchanged. Time-dependent observations of UV-Vis spectra and pH values revealed that the ageing effect was due to a decline in Fe hydrolysis rather than structural changes within HA molecules. Fe polycations are slowly degraded in contact with humic colloids, and more binding sites are occupied as a consequence of dispersion. The extent of degradation as derived from pH shifts depended on the Fe/HA ratio. PMID:17140629

  19. Effect of axial load on mode shapes and frequencies of beams

    NASA Technical Reports Server (NTRS)

    Shaker, F. J.

    1975-01-01

    An investigation of the effect of axial load on the natural frequencies and mode shapes of uniform beams and of a cantilevered beam with a concentrated mass at the tip is presented. Characteristic equations which yield the frequencies and mode shape functions for the various cases are given. The solutions to these equations are presented by a series of graphs so that frequency as a function of axial load can readily be determined. The effect of axial load on the mode shapes are also depicted by another series of graphs.

  20. Overview of the effect of Title III of the 1990 Clean Air Act Amendments on the natural gas industry

    SciTech Connect

    Child, C.J.

    1995-12-31

    The regulation of hazardous air pollutants by Title III of the Clean Air Act Amendments of 1990 has a potential wide-ranging impact for the natural gas industry. Title III includes a list of 189 hazardous air pollutants (HAPs) which are targeted for reduction. Under Title III, HAP emissions from major sources will be reduced by the implementation of maximum achievable control technology (MACT) standards. If the source is defined as a major source, it must also comply with Title V (operating permit) and Title VII (enhanced monitoring) requirements. This presentation will review Title III`s effect on the natural gas industry by discussing the regulatory requirements and schedules associated with MACT as well as the control technology options available for affected sources.

  1. Nitric oxide interacts with mitochondrial complex III producing antimycin-like effects.

    PubMed

    Iglesias, Darío E; Bombicino, Silvina S; Valdez, Laura B; Boveris, Alberto

    2015-12-01

    The effect of NO between cytochromes b and c of the mitochondrial respiratory chain were studied using submitochondrial particles (SMP) from bovine heart and GSNO and SPER-NO as NO sources. Succinate-cytochrome c reductase (complex II-III) activity (222 ± 4 nmol/min. mg protein) was inhibited by 51% in the presence of 500 μM GSNO and by 48% in the presence of 30 μM SPER-NO, in both cases at ~1.25 μM NO. Neither GSNO nor SPER-NO were able to inhibit succinate-Q reductase activity (complex II; 220 ± 9 nmol/min. mg protein), showing that NO affects complex III. Complex II-III activity was decreased (36%) when SMP were incubated with l-arginine and mtNOS cofactors, indicating that this effect is also produced by endogenous NO. GSNO (500 μM) reduced cytochrome b562 by 71%, in an [O2] independent manner. Hyperbolic increases in O2(•-) (up to 1.3 ± 0.1 nmol/min. mg protein) and H2O2 (up to 0.64 ± 0.05 nmol/min. mg protein) productions were observed with a maximal effect at 500 μM GSNO. The O2(•-)/H2O2 ratio was 1.98 in accordance with the stoichiometry of the O2(•-) disproportionation. Moreover, H2O2 production was increased by 72-74% when heart coupled mitochondria were exposed to 500 μM GSNO or 30 μM SPER-NO. SMP incubated in the presence of succinate showed an EPR signal (g=1.99) compatible with a stable semiquinone. This EPR signal was increased not only by antimycin but also by GSNO and SPER-NO. These signals were not modified under N2 atmosphere, indicating that they are not a consequence to the effect of NOx species on complex III area. These results show that NO interacts with ubiquinone-cytochrome b area producing antimycin-like effects. This behaviour comprises the inhibition of electron transfer, the interruption of the oxidation of cytochromes b, and the enhancement of [UQH(•)]ss which, in turn, leads to an increase in O2(•-) and H2O2 mitochondrial production rates. PMID:26456055

  2. Molecular-level modes of As binding to Fe(III) (oxyhydr)oxides precipitated by the anaerobic nitrate-reducing Fe(II)-oxidizing Acidovorax sp. strain BoFeN1

    NASA Astrophysics Data System (ADS)

    Hohmann, Claudia; Morin, Guillaume; Ona-Nguema, Georges; Guigner, Jean-Michel; Brown, Gordon E.; Kappler, Andreas

    2011-09-01

    Sorption of contaminants such as arsenic (As) to natural Fe(III) (oxyhydr)oxides is very common and has been demonstrated to occur during abiotic and biotic Fe(II) oxidation. The molecular mechanism of adsorption- and co-precipitation of As has been studied extensively for synthetic Fe(III) (oxyhydr)oxide minerals but is less documented for biogenic ones. In the present study, we used Fe and As K-edge X-ray Absorption Near Edge Structure (XANES), extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, Mössbauer spectroscopy, XRD, and TEM in order to investigate the interactions of As(V) and As(III) with biogenic Fe(III) (oxyhydr)oxide minerals formed by the nitrate-reducing Fe(II)-oxidizing bacterium Acidovorax sp. strain BoFeN1. The present results show the As immobilization potential of strain BoFeN1 as well as the influence of As(III) and As(V) on biogenic Fe(III) (oxyhydr)oxide formation. In the absence of As, and at low As loading (As:Fe ≤ 0.008 mol/mol), goethite (Gt) formed exclusively. In contrast, at higher As/Fe ratios (As:Fe = 0.020-0.067), a ferrihydrite (Fh) phase also formed, and its relative amount systematically increased with increasing As:Fe ratio, this effect being stronger for As(V) than for As(III). Therefore, we conclude that the presence of As influences the type of biogenic Fe(III) (oxyhydr)oxide minerals formed during microbial Fe(II) oxidation. Arsenic-K-edge EXAFS analysis of biogenic As-Fe-mineral co-precipitates indicates that both As(V) and As(III) form inner-sphere surface complexes at the surface of the biogenic Fe(III) (oxyhydr)oxides. Differences observed between As-surface complexes in BoFeN1-produced Fe(III) (oxyhydr)oxide samples and in abiotic model compounds suggest that associated organic exopolymers in our biogenic samples may compete with As oxoanions for sorption on Fe(III) (oxyhydr)oxides surfaces. In addition HRTEM-EDXS analysis suggests that As(V) preferentially binds to poorly crystalline phases, such as

  3. Fast Particle Effects on the Internal Kink, Fishbone and Alfven Modes

    SciTech Connect

    N.N. Gorelenkov; S. Bernabei; C.Z. Cheng; G.Y. Fu; K. Hill; S. Kaye; G.J. Kramer; Y. Kusama; K. Shinohara; R. Nazikian; T. Ozeki; W. Park

    2000-11-15

    The issues of linear stability of low frequency perturbative and nonperturbative modes in advanced tokamak regimes are addressed based on recent developments in theory, computational methods, and progress in experiments. Perturbative codes NOVA and ORBIT are used to calculate the effects of TAEs on fast particle population in spherical tokamak NSTX. Nonperturbative analysis of chirping frequency modes in experiments on TFTR and JT-60U is presented using the kinetic code HINST, which identified such modes as a separate branch of Alfven modes - resonance TAE (R-TAE). Internal kink mode stability in the presence of fast particles is studied using the NOVA code and hybrid kinetic-MHD nonlinear code M3D.

  4. Inversed Vernier effect based single-mode laser emission in coupled microdisks

    PubMed Central

    Li, Meng; Zhang, Nan; Wang, Kaiyang; Li, Jiankai; Xiao, Shumin; Song, Qinghai

    2015-01-01

    Recently, on-chip single-mode laser emissions in coupled microdisks have attracted considerable research attention due to their wide applications. While most of single-mode lasers in coupled microdisks or microrings have been qualitatively explained by either Vernier effect or inversed Vernier effect, none of them have been experimentally confirmed. Here, we studied the mechanism of single-mode laser operation in coupled microdisks. We found that the mode numbers had been significantly reduced to nearly single-mode within a large pumping power range from threshold to gain saturation. The detail laser spectra showed that the largest gain and the first lasing peak were mainly generated by one disk and the laser intensity was proportional to the wavelength detuning of two set of modes. The corresponding theoretical analysis showed that the experimental observations were dominated by internal coupling within one cavity, which was similar to the recently explored inversed Vernier effect in two coupled microrings. We believe our finding will be important for understanding the previous experimental findings and the development of on-chip single-mode laser. PMID:26330218

  5. Effects of the variation of fundamental constants on Pop III stellar evolution

    SciTech Connect

    Coc, A.; Descouvemont, P.; Uzan, J.-Ph.; Vangioni, E.

    2010-08-12

    The effect of variations of the fundamental constants on the thermonuclear rate of the triple alpha reaction, {sup 4}He({alpha}{alpha}, {gamma}){sup 12}C, that bridges the gap between {sup 4}He and {sup 12}C is investigated. We have followed the evolution of 15 and 60 M{center_dot} zero metallicity stellar models, up to the end of core helium burning. They are assumed to be representative of the first (Population III) stars. The calculated oxygen carbon abundances resulting from helium burning can then be used to constrain the variation of the fundamental constants.

  6. Resonance-mode effect on microcantilever mass-sensing performance in air.

    PubMed

    Xia, Xiaoyuan; Li, Xinxin

    2008-07-01

    This research investigates the air drag damping effect of the micromachined cantilevers in different resonance modes on the quality factor, which are operated in ambient air. Based on a simplified dish-string model for air drag force acting on the resonant cantilever, the air drag damping properties of the cantilevers vibrating in different modes are analyzed with theoretic vibration mechanics, which is complemented and further confirmed with finite-element simulation. Four kinds of integrated cantilevers, which resonate in the first flexural mode, the second flexural mode, the first torsional mode, and the second torsional mode, respectively, are designed and fabricated by using micromachining techniques. Finally, biomolecular sensing experiments are carried out to verify the theoretical results obtained before. From both the modeling and experimental results, it can be seen that damping characteristics of the torsional cantilever resonators are generally better than that of the flexural ones, and quality factor of the cantilever resonator in a higher-frequency mode is always superior to that in a lower-frequency one. Among the four kinds of microcantilever resonators operated in our experiments, the one operated in the second flexural modes exhibits the highest Q factor and the best biomass sensing performance. PMID:18681721

  7. Effects of Presentation Mode and Pace Control on Performance in Image Classification.

    PubMed

    van der Corput, Paul; van Wijk, Jarke J

    2014-12-01

    A common task in visualization is to quickly find interesting items in large sets. When appropriate metadata is missing, automatic queries are impossible and users have to inspect all elements visually. We compared two fundamentally different, but obvious display modes for this task and investigated the difference with respect to effectiveness, efficiency, and satisfaction. The static mode is based on the page metaphor and presents successive pages with a static grid of items. The moving mode is based on the conveyor belt metaphor and lets a grid of items slide though the screen in a continuous flow. In our evaluation, we applied both modes to the common task of browsing images. We performed two experiments where 18 participants had to search for certain target images in a large image collection. The number of shown images per second (pace) was predefined in the first experiment, and under user control in the second one. We conclude that at a fixed pace, the mode has no significant impact on the recall. The perceived pace is generally slower for moving mode, which causes users to systematically choose for a faster real pace than in static mode at the cost of recall, keeping the average number of target images found per second equal for both modes. PMID:26356944

  8. Crystallinity effects on scaling properties of photoinduced modes in silver nanoprisms

    SciTech Connect

    Ng, Ming-Yaw; Ho, I-Lin; Chang, Yia-Chung

    2015-02-21

    The crystallinity effects on scaling properties of photoinduced modes in crystalline silver nanoprisms with C{sub 3v} symmetry are studied using a realistic atomistic model and group theory. Among all vibrational modes, photoinduced modes can be identified as those vibrational modes which possess larger in-phase radial atomic displacement and can be projected out by the projected density of states method. We found that the properties of vibrations in silver nanoprisms strongly depend on the particle’s aspect ratio (bisector length over thickness). By considering crystallinity of silver nanoprisms, the dominant modes with the in-plane oscillation become several closely spaced modes, and become obvious for nanoprisms with a smaller aspect ratio. The oscillation spectra show that the dominant planar modes are insensitive to thickness change. On the contrary, the atomic displacements show significantly different patterns for nanoprisms of different thicknesses. We also found that, for nanoprisms with same aspect ratio that is larger than 4, the vibrational properties of dominant modes exhibit scaling similarity. By using a simple linear transformation, the vibration frequencies for large-sized nanoprisms of aspect ratio 6 can be obtained by a corresponding scaling factor. The calculated results are in good agreement with experimental data.

  9. Resonance-mode effect on microcantilever mass-sensing performance in air

    SciTech Connect

    Xia Xiaoyuan; Li Xinxin

    2008-07-15

    This research investigates the air drag damping effect of the micromachined cantilevers in different resonance modes on the quality factor, which are operated in ambient air. Based on a simplified dish-string model for air drag force acting on the resonant cantilever, the air drag damping properties of the cantilevers vibrating in different modes are analyzed with theoretic vibration mechanics, which is complemented and further confirmed with finite-element simulation. Four kinds of integrated cantilevers, which resonate in the first flexural mode, the second flexural mode, the first torsional mode, and the second torsional mode, respectively, are designed and fabricated by using micromachining techniques. Finally, biomolecular sensing experiments are carried out to verify the theoretical results obtained before. From both the modeling and experimental results, it can be seen that damping characteristics of the torsional cantilever resonators are generally better than that of the flexural ones, and quality factor of the cantilever resonator in a higher-frequency mode is always superior to that in a lower-frequency one. Among the four kinds of microcantilever resonators operated in our experiments, the one operated in the second flexural modes exhibits the highest Q factor and the best biomass sensing performance.

  10. Rotational shear effects on edge harmonic oscillations in DIII-D quiescent H-mode discharges

    NASA Astrophysics Data System (ADS)

    Chen, Xi; Burrell, K. H.; Ferraro, N. M.; Osborne, T. H.; Austin, M. E.; Garofalo, A. M.; Groebner, R. J.; Kramer, G. J.; Luhmann, N. C., Jr.; McKee, G. R.; Muscatello, C. M.; Nazikian, R.; Ren, X.; Snyder, P. B.; Solomon, W. M.; Tobias, B. J.; Yan, Z.

    2016-07-01

    In the quiescent H-mode (QH-mode) regime, edge harmonic oscillations (EHOs) play an important role in avoiding transient edge localized mode (ELM) power fluxes by providing benign and continuous edge particle transport. A detailed theoretical, experimental and modeling comparison has been made of low-n (n  ⩽  5) EHO in DIII-D QH-mode plasmas. The calculated linear eigenmode structure from the extended magentoohydrodynamics (MHD) code M3D-C1 matches closely the coherent EHO properties from external magnetics data and internal measurements using the ECE, BES, ECE-Imaging and microwave imaging reflectometer (MIR) diagnostics, as well as the kink/peeling mode properties found by the ideal MHD code ELITE. Numerical investigations indicate that the low-n EHO-like solutions from M3D-C1 are destabilized by rotation and/or rotational shear while high-n modes are stabilized. This effect is independent of the rotation direction, suggesting that EHOs can be destabilized in principle with rotation in either direction. The modeling results are consistent with observations of EHO, support the proposed theory of the EHO as a low-n kink/peeling mode destabilized by edge E  ×  B rotational shear, and improve our understanding and confidence in creating and sustaining QH-mode in present and future devices.

  11. Media Presentation Mode, English Listening Comprehension and Cognitive Load in Ubiquitous Learning Environments: Modality Effect or Redundancy Effect?

    ERIC Educational Resources Information Center

    Chang, Chi-Cheng; Lei, Hao; Tseng, Ju-Shih

    2011-01-01

    Although ubiquitous learning enhances students' access to learning materials, it is crucial to find out which media presentation modes produce the best results for English listening comprehension. The present study examined the effect of media presentation mode (sound and text versus sound) on English listening comprehension and cognitive load.…

  12. Mode Summation Approach to Casimir Effect Between Two Objects

    NASA Astrophysics Data System (ADS)

    Teo, L. P.

    2012-10-01

    In the last few years, several approaches have been developed to compute the exact Casimir interaction energy between two nonplanar objects, all lead to the same functional form, which is called the TGTG formula. In this paper, we explore the TGTG formula from the perspective of mode summation approach. Both scalar fields and electromagnetic fields are considered. In this approach, one has to first solve the equation of motion to find a wave basis for each object. The two T's in the TGTG formula are T-matrices representing the Lippmann-Schwinger T-operators, one for each of the objects. Each T-matrix can be found by matching the boundary conditions imposed on the object, and it is independent of the other object. However, it depends on whether the object is interacting with an object outside it, or an object inside it. The two G's in the TGTG formula are the translation matrices, relating the wave basis of an object to the wave basis of the other object. These translation matrices only depend on the wave basis chosen for each object, and they are independent of the boundary conditions on the objects. After discussing the general theory, we apply the prescription to derive the explicit formulas for the Casimir energies for the sphere-sphere, sphere-plane, cylinder-cylinder and cylinder-plane interactions. First the T-matrices for a plane, a sphere and a cylinder are derived for the following cases: the object is imposed with Dirichlet, Neumann or general Robin boundary conditions; the object is semitransparent; and the object is a magnetodielectric object immersed in a magnetodielectric media. Then the operator approach developed by R. C. Wittman [IEEE Trans. Antennas Propag.36, 1078 (1988)] is used to derive the translation matrices. From these, the explicit TGTG formula for each of the scenarios can be written down. On the one hand, we have summarized all the TGTG formulas that have been derived so far for the sphere-sphere, cylinder-cylinder, sphere-plane and

  13. Effective Identification of Bacterial Type III Secretion Signals Using Joint Element Features

    PubMed Central

    Wang, Yejun; Sun, Ming’an; Bao, Hongxia; Zhang, Qing; Guo, Dianjing

    2013-01-01

    Type III secretion system (T3SS) plays important roles in bacteria and host cell interactions by specifically translocating type III effectors into the cytoplasm of the host cells. The N-terminal amino acid sequences of the bacterial type III effectors determine their specific secretion via type III secretion conduits. It is still unclear as to how the N-terminal sequences guide this specificity. In this work, the amino acid composition, secondary structure, and solvent accessibility in the N-termini of type III and non-type III secreted proteins were compared and contrasted. A high-efficacy mathematical model based on these joint features was developed to distinguish the type III proteins from the non-type III ones. The results indicate that secondary structure and solvent accessibility may make important contribution to the specific recognition of type III secretion signals. Analysis also showed that the joint feature of the N-terminal 6th–10th amino acids are especially important for guiding specific type III secretion. Furthermore, a genome-wide screening was performed to predict Salmonella type III secreted proteins, and 8 new candidates were experimentally validated. Interestingly, type III secretion signals were also predicted in gram-positive bacteria and yeasts. Experimental validation showed that two candidates from yeast can indeed be secreted through Salmonella type III secretion conduit. This research provides the first line of direct evidence that secondary structure and solvent accessibility contain important features for guiding specific type III secretion. The new software based on these joint features ensures a high accuracy (general cross-validation sensitivity of ∼96% at a specificity of ∼98%) in silico identification of new type III secreted proteins, which may facilitate our understanding about the specificity of type III secretion and the evolution of type III secreted proteins. PMID:23593149

  14. Theory of energetic/alpha particle effects on magnetohydrodynamic modes in tokamaks

    SciTech Connect

    Chen, L.; White, R.B.; Rewoldt, G.; Colestock, P.; Rutherford, P.H.; Chen, Y.P.; Ke, F.J.; Tsai, S.T.; Bussac, M.N.

    1989-01-01

    The presence of energetic particles is shown to qualitatively modify the stability properties of ideal as well as resistive magnetohydrodynamic (MHD) modes in tokamaks. Specifically, we demonstrate that, consistent with highpower ICRF heating experiments in JET, high energy trapped particles can effectively stabilize the sawtooth mode, providing a possible route to stable high current tokamak operation. An alternative stabilization scheme employing barely circulating energetic particles is also proposed. Finally, we present analytical and numerical studies on the excitations of high-n MHD modes via transit resonances with circulating alpha particles. 14 refs., 3 figs.

  15. Bi-fluid and neoclassical effect on a Double-Tearing mode in Tore Supra

    SciTech Connect

    Maget, Patrick Garbet, Xavier; Février, Olivier; Ségui, Jean-Luc; Lütjens, Hinrich; Luciani, Jean-François

    2014-06-15

    Tearing modes associated to hollow current profiles are prone to grow in moderate performance plasmas and often constrain the realization of non-inductive discharges in the Tore Supra tokamak, where long pulse duration is performed using Lower Hybrid waves for providing most of the plasma current. The prediction of MHD boundaries in such scenarios is complicated by the importance of diamagnetic effects, combined with curvature stabilization, which determine the stability of these modes. We show that diamagnetic effects, as well as neoclassical forces, are playing a key role in the linear and nonlinear regimes of Double-Tearing Modes on q = 5/3 and q = 2 in these experimental conditions. Detailed comparison with experimental measurements, combined with a scaling in plasma resistivity, give constraints about the experimental equilibrium. Resistive-Interchange Modes destabilized by diamagnetic rotation could also play a role in degrading the energy confinement in the negative magnetic shear region.

  16. A Tool To Support Failure Mode And Effects Analysis Based On Causal Modelling And Reasoning

    NASA Astrophysics Data System (ADS)

    Underwood, W. E.; Laib, S. L.

    1987-05-01

    A prototype knowledge-based system has been developed that supports Failure Mode & Effects Analysis (FMEA). The knowledge base consists of causal models of components and a representation for coupling these components into assemblies and systems. The causal models are qualitative models. They allow reasoning as to whether variables are increasing, decreasing or steady. The analysis strategies used by the prototype allow it to determine the effects of failure modes on the function of the part, the failure effect on the assembly the part is contained in, and the effect on the subsystem containing the assembly.

  17. Low levels of DNA ligases III and IV sufficient for effective NHEJ.

    PubMed

    Windhofer, Frank; Wu, Wenqi; Iliakis, George

    2007-11-01

    Cells of higher eukaryotes rejoin double strand breaks (DSBs) in their DNA predominantly by a non-homologous DNA end joining (NHEJ) pathway that utilizes the products of DNA-PKcs, Ku, LIG4, XRCC4, XLF/Cernunnos, Artemis as well as DNA polymerase lambda (termed D-NHEJ). Mutants with defects in these proteins remove a large proportion of DSBs from their genome utilizing an alternative pathway of NHEJ that operates as a backup (B-NHEJ). While D-NHEJ relies exclusively on DNA ligase IV, recent work points to DNA ligase III as a component of B-NHEJ. Here, we use RNA interference (RNAi) to further investigate the activity requirements for DNA ligase III and IV in the pathways of NHEJ. We report that 70-80% knock down of LIG3 expression has no detectable effect on DSB rejoining, either in D-NHEJ proficient cells, or in cells where D-NHEJ has been chemically or genetically compromised. Surprisingly, also LIG4 knock down has no effect on repair proficient cells, but inhibits DSB rejoining in a radiosensitive cell line with a hypomorphic LIG4 mutation that severely compromises its activity. The results suggest that complete coverage for D-NHEJ or B-NHEJ is afforded by very low ligase levels and demonstrate residual end joining by DNA ligase IV in cells of patients with mutations in LIG4. PMID:17492771

  18. ANAEROBIC DIGESTION OF ANIMAL WASTE: EFFECT OF MODE OF MIXING

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Laboratory-scale digesters were operated to study the effect of mixing (via biogas recirculation, impeller mixing, and slurry recirculation) on biogas production. Three sets of experiments were performed using cow manure slurry feed with either 50, 100, or 150 g/L total solids (TS) concentrations (r...

  19. Interactive TV: An Effective Instructional Mode for Adult Learners

    ERIC Educational Resources Information Center

    Chen, Li-Ling; Iris, Carole

    2004-01-01

    The inclusion of interactive television (iTV) programs for learning is an emerging genre in education. Literature has concluded that any aspect of learning requires some form of interaction or feedback to be most effective. As television (TV) evolves from being a passive to an active medium, it has the potential to engage learners and reach a mass…

  20. Effects of strain on the band structure of group-III nitrides

    NASA Astrophysics Data System (ADS)

    Yan, Qimin; Rinke, Patrick; Janotti, Anderson; Scheffler, Matthias; Van de Walle, Chris G.

    2014-09-01

    We present a systematic study of strain effects on the electronic band structure of the group-III-nitrides (AlN, GaN and InN) in the wurtzite phase. The calculations are based on density functional theory with band-gap-corrected approaches including the Heyd-Scuseria-Ernzerhof hybrid functional (HSE) and quasiparticle G0W0 methods. We study strain effects under realistic strain conditions, hydrostatic pressure, and biaxial stress. The strain-induced modification of the band structures is found to be nonlinear; transition energies and crystal-field splittings show a strong nonlinear behavior under biaxial stress. For the linear regime around the experimental lattice parameters, we present a complete set of deformation potentials (acz, act, D1, D2, D3, D4, D5, D6) that allows us to predict the band positions of group-III nitrides and their alloys (InGaN and AlGaN) under realistic strain conditions. The benchmarking G0W0 results for GaN agree well with the HSE data and indicate that HSE provides an appropriate description for the band structures of nitrides. We present a systematic study of strain effects on the electronic band structure of the group-III nitrides (AlN, GaN, and InN). We quantify the nonlinearity of strain effects by introducing a set of bowing parameters. We apply the calculated deformation potentials to the prediction of strain effects on transition energies and valence-band structures of InGaN alloys and quantum wells (QWs) grown on GaN, in various orientations (including c-plane, m-plane, and semipolar). The calculated band gap bowing parameters, including the strain effect for c-plane InGaN, agree well with the results obtained by hybrid functional alloy calculations. For semipolar InGaN QWs grown in (202¯1), (303¯1), and (303¯1¯) orientations, our calculated deformation potentials have provided results for polarization ratios in good agreement with the experimental observations, providing further confidence in the accuracy of our values.

  1. Effects of Field-Aligned Flows on Standing Kink and Sausage Modes Supported by Coronal Loops

    NASA Astrophysics Data System (ADS)

    Chen, S.-X.; Li, B.; Xia, L.-D.; Chen, Y.-J.; Yu, H.

    2014-05-01

    Fundamental standing modes and their overtones play an important role in coronal seismology. We examine the effects of a significant field-aligned flow on standing modes that are supported by coronal loops, which are modeled here as cold magnetic slabs. Of particular interest are the period ratios of the fundamental to its ( n-1)th overtone [ P 1/ nP n ] for kink and sausage modes, and the threshold half-width-to-length ratio for sausage modes. For standing kink modes, the flow significantly reduces P 1/ nP n in general, the effect being particularly strong for higher n and weaker density contrast [] between loops and their surroundings. That said, even when approaches infinity, this effect is still substantial, reducing the minimal P 1/ nP n by up to 13.7 % (24.5 %) for n=2 ( n=4) relative to the static case, when the Alfvén Mach number [ M A] reaches 0.8, where M A measures the loop flow speed in units of the internal Alfvén speed. Although it is not negligible for standing sausage modes, the flow effect in reducing P 1/ nP n is not as strong. However, the threshold half-width-to-length ratio is considerably higher in the flowing case than in its static counterpart. For in the range [9,1024] and M A in the range [0,0.5], an exhaustive parameter study yields that this threshold is well fitted by , which involves the two parameters in a simple way. This allows one to analytically constrain the combination for a loop with a known width-to-length ratio when a standing sausage oscillation is identified. It also allows one to examine the idea of partial sausage modes in more detail, and the flow is found to significantly reduce the spatial extent where partial modes are allowed.

  2. Effects of instruction presentation mode in comparative judgments.

    PubMed

    Shaki, Samuel; Leth-Steensen, Craig; Petrusic, William M

    2006-01-01

    In each of two experiments, the comparative instructions in a symbolic comparison task were either varied randomly from trial to trial (mixed blocks) or left constant (pure blocks) within blocks of trials. In the first experiment, every stimulus was compared with every other stimulus. The symbolic distance effect (DE) was enhanced, and the semantic congruity effect (SCE) was significantly larger, when the instructions were randomized than when they were blocked. In a second experiment, each stimulus was paired with only one other stimulus. The SCE was again larger when instructions were randomized than when they were blocked. The enhanced SCE and DE with randomized instructions follow naturally from evidence accrual views of comparative judgments. PMID:16686118

  3. The growth of the tearing mode - Boundary and scaling effects

    NASA Technical Reports Server (NTRS)

    Steinolfson, R. S.; Van Hoven, G.

    1983-01-01

    A numerical model of resistive magnetic tearing is developed in order to verify and relate the results of the principal approximations used in analytic analyses and to investigate the solutions and their growth-rate scalings over a large range of primary parameters which include parametric values applicable to the solar atmosphere. The computations cover the linear behavior for a variety of boundary conditions, emphasizing effects which differentiate magnetic tearing in astrophysical situations from that in laboratory devices. Eigenfunction profiles for long and short wavelengths are computed and the applicability of the 'constant psi' approximation is investigated. The growth rate is computed for values of the magnetic Reynolds number up to a trillion and of the dimensionless wavelength parameter down to 0.001. The analysis predicts significant effects due to differing values of the magnetic Reynolds number.

  4. Effect Of Clock Mode On Radiation Hardness Of An ADC

    NASA Technical Reports Server (NTRS)

    Lee, Choon I.; Rax, Bernie G.; Johnston, Allan H.

    1995-01-01

    Report discusses techniques for testing and evaluating effects of total dosages of ionizing radiation on performances of high-resolution successive-approximation analog-to-digital converters (ADCs), without having to test each individual bit or transition. Reduces cost of testing by reducing tests to few critical parametric measurements, from which one determines approximate radiation failure levels providing good approximations of responses of converters for purpose of total-dose-radiation evaluations.

  5. Pleiotropic neuroprotective and metabolic effects of Actovegin's mode of action.

    PubMed

    Machicao, Fausto; Muresanu, Dafin Fior; Hundsberger, Harald; Pflüger, Maren; Guekht, Alla

    2012-11-15

    This article reviews the mechanisms of action of Actovegin in the context of its preclinical effects and new concepts in the pharmacological treatment of neurological disorders. Actovegin is an ultrafiltrate of calf blood, composed of more than 200 biological substances. The drug is used for a broad spectrum of diseases, including disturbances of peripheral and cerebral blood circulation, burns, impaired wound healing, radiation-induced damage and diabetic polyneuropathy. Actovegin is composed of small molecules present under normal physiological conditions, therefore pharmacokinetic and pharmacodynamic studies to determine its active substance are not feasible. Preclinical data have revealed that it improves metabolic balance by increasing glucose uptake and improving oxygen uptake under conditions of ischemia. Actovegin also resists the effects of gamma-irradiation and stimulates wound healing. More recent preclinical studies have suggested that anti-oxidative and anti-apoptotic mechanisms of action specifically underlie the neuroprotective properties of Actovegin. The drug has been found to exert these beneficial effects experimentally, in primary rat hippocampal neurons and in an STZ-rat model of diabetic polyneuropathy, while also providing evidence that it positively affects the functional recovery of neurons. Latest data suggest that Actovegin also has a positive influence on the NF-κB pathway, but many molecular and cellular pathways remain unexplored. In particular, Actovegin's influence on neuroplasticity, neurogenesis and neurotrophicity are questions that ideally should be answered by future research. Nevertheless, it is clear that the multifactorial and complex nature of Actovegin underlies its pleiotropic neuroprotective mechanisms of action and positive effect on clinical outcomes. PMID:22910148

  6. Effect of dynamical friction on nonlinear energetic particle modes

    SciTech Connect

    Lilley, M. K.; Breizman, B. N.; Sharapov, S. E.

    2010-09-15

    A fully nonlinear model is developed for the bump-on-tail instability including the effects of dynamical friction (drag) and velocity space diffusion on the energetic particles driving the wave. The results show that drag provides a destabilizing effect on the nonlinear evolution of waves. Specifically, in the early nonlinear phase of the instability, the drag facilitates the explosive scenario of the wave evolution, leading to the creation of phase space holes and clumps that move away from the original eigenfrequency. Later in time, the electric field associated with a hole is found to be enhanced by the drag, whereas for a clump it is reduced. This leads to an asymmetry of the frequency evolution between holes and clumps. The combined effect of drag and diffusion produces a diverse range of nonlinear behaviors including hooked frequency chirping, undulating, and steady state regimes. An analytical model is presented, which explains the aforementioned diversity. A continuous production of hole-clump pairs in the absence of collisions is also observed.

  7. Effect of flexural modes on squeeze film damping in MEMS cantilever resonators

    NASA Astrophysics Data System (ADS)

    Pandey, Ashok Kumar; Pratap, Rudra

    2007-12-01

    We present an analytical model that gives the values of squeeze film damping and spring coefficients for MEMS cantilever resonators taking into account the effect of flexural modes of the resonator. We use the exact mode shapes of a 2D cantilever plate to solve for pressure in the squeeze film and then derive the equivalent damping and spring coefficient relations from the back force calculations. The relations thus obtained can be used for any flexural mode of vibration of the resonators. We validate the analytical formulae by comparing the results with numerical simulations carried out using coupled finite element analysis in ANSYS, as well as experimentally measured values from MEMS cantilever resonators of various sizes vibrating in different modes. The analytically predicted values of damping are, in the worst case, within less than 10% of the values obtained experimentally or numerically. We also compare the results with previously reported analytical formulae based on approximate flexural mode shapes and show that the current results give much better estimates of the squeeze film damping. From the analytical model presented here, we find that the squeeze film damping drops by 84% from the first mode to the second mode in a cantilever resonator, thus improving the quality factor by a factor of 6 to 7. This result has significant implications in using cantilever resonators for mass detection where a significant increase in the quality factor is obtained by using a vacuum.

  8. Effect of laser parameters and mode on pulp surgery outcome

    NASA Astrophysics Data System (ADS)

    Wilder-Smith, Petra B. B.; Arrastia-Jitosho, Anna-Marie A.; Peavy, George M.; Kurosaki, Tom

    1997-05-01

    The objective of this study was to determine the effectiveness of localized laser pulp surgery in the canine model. Effects of laser parameters on treatment outcome were also investigated. Pulpal exposure 3 mm in diameter were prepared in healthy teeth and left open to infection from the oral cavity for 72 hours. Pulpal tissue was then removed using high speed handpiece with sterile irrigation, or a CO2 laser. Teeth were monitored clinically, radiographically for 3 months. Results for each criterion were evaluated on a scale of 0-(-2). After sacrifice, histological assessment was made soft and hard tissue response. Results for each category were evaluated on a standard scale of 0-(-2). All evaluations were performed by 1 blinded, pre-standardized clinician. Statistical assessment using the chi-square test and Fisher's Exact Test associated laser treatment with a significantly better clinical, radiographic and histological treatment outcome. NIH RRO1192, seed grant funding form Loma Linda University, the Edna P. Jacobsen Charitable Trust for Animals, Inc.

  9. Gadolinium(III)-hydroxy ladders trapped in succinate frameworks with optimized magnetocaloric effect.

    PubMed

    Chen, Yan-Cong; Guo, Fu-Sheng; Zheng, Yan-Zhen; Liu, Jun-Liang; Leng, Ji-Dong; Tarasenko, Róbert; Orendáč, Martin; Prokleška, Jan; Sechovský, Vladimír; Tong, Ming-Liang

    2013-09-27

    Two kinds of inorganic gadolinium(III)-hydroxy "ladders", [2×n] and [3×n], were successfully trapped in succinate (suc) coordination polymers, [Gd2(OH)2(suc)2(H2O)]n·2nH2O (1) and [Gd6(OH)8(suc)5(H2O)2 ]n·4n H2O (2), respectively. Such coordination polymers could be regarded as alternating inorganic-organic hybrid materials with relatively high density. Magnetic and heat capacity studies reveal a large cryogenic magnetocaloric effect (MCE) in both compounds, namely (ΔH=70 kG) 42.8 J kg(-1) K(-1) for complex 1 and 48.0 J kg(-1) K(-1) for complex 2. The effect of the high density is evident, which gives very large volumetric MCEs up to 120 and 144 mJ cm(-3) K(-1) for complexes 1 and 2, respectively. PMID:23959529

  10. Effect of Coupling between Fundamental and Cladding Modes on Bending Losses in Single-Polarization Single-Mode Photonic Crystal Fiber

    NASA Astrophysics Data System (ADS)

    Balvedi, Gláucia C.; Franco, Marcos A. R.

    2008-10-01

    In this paper we study the effect of bending on the performance of a single-polarization single-mode (SPSM) photonic crystal fiber previously reported in the literature. The optical fiber consists of a photonic crystal fiber with hexagonal lattice of circular air-holes with an elliptical core formed by eight enlarged holes surrounding the central region of the fiber. Numerical analysis based on full-vector finite element method (VFEM) with a cylindrical perfectly matched layer (PML) was applied to evaluate the bending loss and the confinement loss of the fiber. For the straight fiber only the fundamental slow axis mode (x-polarization) exist because of the very high confinement loss of the fundamental fast axis mode (y-polarization). However, for the bent fiber the fast axis mode and the slow axis mode couple with the gallery of the cladding modes. These coupling prevent the fast axis mode to reach the cutoff. As a consequence, the bending loss curve as a function of the wavelength presents oscillations related with these coupled modes. Our simulations demonstrate that the analyzed fiber does not maintain its single-polarization single-mode characteristics when it is bent with a small curvature radius of 10 mm. However, for a small wavelength range (1.50 μm to 1.53 μm) the fundamental slow axis mode presents values of bending loss lower then 0.1 dB/km while the fast axis mode reach losses of about 150 dB/km, what can be useful for some application.

  11. [Gold antirheumatic drug: desired and adverse effects of Au(I) and Au(III) [corrected] on the immune system.

    PubMed

    Griem, P; Gleichmann, E

    1996-01-01

    Three new findings are reviewed that help to understand the mechanisms of action of anti-rheumatic gold drugs, such as disodium aurothiomalate (Na2Au(I)TM): i) We found that Na2Au(I)TM selectively inhibits T-cell receptor-mediated antigen recognition by murine CD4+ T-cell hybridomas specific for antigenic peptides containing at least two cysteine residues. Presumably, Au(I) acts as a chelating agent forming linear complexes (Cys-Au(I)-Cys) which prevents correct antigen-processing and/or peptide recognition by the T-cell receptor, ii) We were able to show that Au(I) is oxidized to Au(III) in mononuclear phagocytes, such as macrophages. Because Au(III) rapidly oxidizes protein and itself is re-reduced to Au(I), this may introduce an Au(I)/Au(III) redox system into phagocytes which scavenges reactive oxygen species, such as hypochlorous acid (HOCl) and inactivates lysosomal enzymes, iii) Pretreatment with Au(III) of a model protein antigen, bovine ribonuclease A (RNase A), induced novel antigenic determinants recognized by CD4+ T lymphocytes. Analysis of the fine specificity of these "Au(III)-specific" T-cells revealed that they react to RNase peptides that are not presented to T-cells when the native protein, i.e., not treated with Au(III), is used as antigen. The T-cell recognition of these cryptic peptides did not require the presence of gold. This finding has important implications for understanding the pathogenesis of allergic and autoimmune responses induced by gold drugs. Taken together, our findings indicate that Au(I) and Au(III) each exert specific effects on several distinct functions of macrophages and the activation of T-cells. These effects may explain both the desired anti-inflammatory and the adverse effects of antirheumatic gold drugs. PMID:9036720

  12. Mode-selective quantization and multimodal effective models for spherically layered systems

    NASA Astrophysics Data System (ADS)

    Dzsotjan, D.; Rousseaux, B.; Jauslin, H. R.; des Francs, G. Colas; Couteau, C.; Guérin, S.

    2016-08-01

    We propose a geometry-specific, mode-selective quantization scheme in coupled field-emitter systems which makes it easy to include material and geometrical properties, and intrinsic losses, as well as the positions of an arbitrary number of quantum emitters. The method is presented through the example of a spherically symmetric, nonmagnetic, arbitrarily layered system. We follow it up by a framework to project the system on simpler, effective cavity QED models. Maintaining a well-defined connection to the original quantization, we derive the emerging effective quantities from the full, mode-selective model in a mathematically consistent way. We discuss the uses and limitations of these effective models.

  13. Assessment of the effects of As(III) treatment on cyanobacteria lipidomic profiles by LC-MS and MCR-ALS.

    PubMed

    Marques, Aline S; Bedia, Carmen; Lima, Kássio M G; Tauler, Romà

    2016-08-01

    Cyanobacteria are a group of photosynthetic, nitrogen-fixing bacteria present in a wide variety of habitats such as freshwater, marine, and terrestrial ecosystems. In this work, the effects of As(III), a major toxic environmental pollutant, on the lipidomic profiles of two cyanobacteria species (Anabaena and Planktothrix agardhii) were assessed by means of a recently proposed method based on the concept of regions of interest (ROI) in liquid chromatography mass spectroscopy (LC-MS) together with multivariate curve resolution alternating least squares (MCR-ALS). Cyanobacteria were exposed to two concentrations of As(III) for a week, and lipid extracts were analyzed by ultrahigh-performance liquid chromatography/time-of-flight mass spectrometry in full scan mode. The data obtained were compressed by means of the ROI strategy, and the resulting LC-MS data sets were analyzed by the MCR-ALS method. Comparison of profile peak areas resolved by MCR-ALS in control and exposed samples allowed the discrimination of lipids whose concentrations were changed due to As(III) treatment. The tentative identification of these lipids revealed an important reduction of the levels of some galactolipids such as monogalactosyldiacylglycerol, the pigment chlorophyll a and its degradation product, pheophytin a, as well as carotene compounds such as 3-hydroxycarotene and carotene-3,3'-dione, all of these compounds being essential in the photosynthetic process. These results suggested that As(III) induced important changes in the composition of lipids of cyanobacteria, which were able to compromise their energy production processes. Graphical abstract Steps of the proposed LC-MS + MCR-ALS procedure. PMID:27311955

  14. Scheme for on-chip verification of transverse mode entanglement using the electro-optic effect.

    PubMed

    Bharadwaj, Divya; Thyagarajan, K; Jachura, Michał; Karpiński, Michał; Banaszek, Konrad

    2015-12-28

    A key ingredient in emerging quantum-enhanced technologies is the ability to coherently manipulate and detect superpositions of basis states. In integrated optics implementations, transverse spatial modes supported by multimode structures offer an attractive carrier of quantum superpositions. Here we propose an integrated dynamic mode converter based on the electro-optic effect in nonlinear channel waveguides for deterministic transformations between mutually non-orthogonal bases of spatial modes. We theoretically show its capability to demonstrate a violation of a Bell-type Clauser-Horne-Shimony-Holt inequality by measuring spatially mode-entangled photon pairs generated by an integrated photon pair source. The proposed configuration, numerically studied for the potassium titanyl phosphate (KTP) material, can be easily implemented using standard integrated optical fabrication technology. PMID:26831977

  15. Dipole-fiber systems: radiation field patterns, effective magnetic dipoles, and induced cavity modes

    NASA Astrophysics Data System (ADS)

    Atakaramians, Shaghik; Miroshnichenko, Andrey E.; Shadrivov, Ilya V.; Monro, Tanya M.; Kivshar, Yuri S.; Afshar, Shahraam V.

    2015-12-01

    We study the radiation patterns produced by a dipole placed at the surface of a nanofiber and oriented perpendicular to it, either along the radial (r-oriented) or azimuthal (Φ-oriented) directions. We find that the dipole induces an effective circular cavity-like leaky mode in the nanofiber. The first radiation peak of the Φ-oriented dipole contributes only to TE radiation modes, while the radiation of the r-oriented dipole is composed of both TE and TM radiation modes, with relative contribution depending on the refractive index of the nanofiber. We reveal that the field pattern of the first resonance of a Φ-oriented dipole is associated with a magnetic dipole mode and strong magnetic response of an optical nanofiber.

  16. Effective action approach and Carlson-Goldman mode in d-wave superconductors

    NASA Astrophysics Data System (ADS)

    Sharapov, Sergei G.; Beck, Hans

    2002-04-01

    We theoretically investigate the Carlson-Goldman (CG) mode in two-dimensional clean d-wave superconductors using the effective ``phase-only'' action formalism. In conventional s-wave superconductors, it is known that the CG mode is observed as a peak in the structure factor of the pair susceptibility S(Ω,K) only just below the transition temperature Tc and only in dirty systems. On the other hand, our analytical results support the statement by Ohashi and Takada [Phys. Rev. B 62, 5971 (2000)] that in d-wave superconductors the CG mode can exist in clean systems down to much lower temperatures, T~0.1Tc. We also consider the manifestations of the CG mode in the density-density and current-current correlators and discuss the gauge independence of the obtained results.

  17. Evaluation of Safety in a Radiation Oncology Setting Using Failure Mode and Effects Analysis

    SciTech Connect

    Ford, Eric C. Gaudette, Ray; Myers, Lee; Vanderver, Bruce; Engineer, Lilly; Zellars, Richard; Song, Danny Y.; Wong, John; DeWeese, Theodore L.

    2009-07-01

    Purpose: Failure mode and effects analysis (FMEA) is a widely used tool for prospectively evaluating safety and reliability. We report our experiences in applying FMEA in the setting of radiation oncology. Methods and Materials: We performed an FMEA analysis for our external beam radiation therapy service, which consisted of the following tasks: (1) create a visual map of the process, (2) identify possible failure modes; assign risk probability numbers (RPN) to each failure mode based on tabulated scores for the severity, frequency of occurrence, and detectability, each on a scale of 1 to 10; and (3) identify improvements that are both feasible and effective. The RPN scores can span a range of 1 to 1000, with higher scores indicating the relative importance of a given failure mode. Results: Our process map consisted of 269 different nodes. We identified 127 possible failure modes with RPN scores ranging from 2 to 160. Fifteen of the top-ranked failure modes were considered for process improvements, representing RPN scores of 75 and more. These specific improvement suggestions were incorporated into our practice with a review and implementation by each department team responsible for the process. Conclusions: The FMEA technique provides a systematic method for finding vulnerabilities in a process before they result in an error. The FMEA framework can naturally incorporate further quantification and monitoring. A general-use system for incident and near miss reporting would be useful in this regard.

  18. The detection rate of inspiral and quasi-normal modes of Population III binary black holes which can confirm or refute the general relativity in the strong gravity region

    NASA Astrophysics Data System (ADS)

    Kinugawa, Tomoya; Miyamoto, Akinobu; Kanda, Nobuyuki; Nakamura, Takashi

    2016-02-01

    Using our population synthesis code, we found that the typical chirp mass defined by (m1m2)3/5/(m1 + m2)1/5 of Population III (Pop III) binary black holes (BH-BHs) is ˜30 M⊙ with the total mass of ˜60 M⊙ so that the inspiral chirp signal as well as quasi-normal mode (QNM) of the merging black hole (BH) are interesting targets of KAGRA. The detection rate of the coalescing Pop III BH-BHs is ˜180 events yr- 1 (SFRp/(10-2.5 M⊙ yr-1 Mpc-3))([fb/(1 + fb)]/0.33)Errsys in our standard model, where SFRp, fb and Errsys are the peak value of the Pop III star formation rate, the binary fraction and the systematic error with Errsys = 1 for our standard model, respectively. To evaluate the robustness of chirp mass distribution and the range of Errsys, we examine the dependence of the results on the unknown parameters and the distribution functions in the population synthesis code. We found that the chirp mass has a peak at ˜30 M⊙ in most of parameters and distribution functions as well as Errsys ranges from 0.046 to 4. Therefore, the detection rate of the coalescing Pop III BH-BHs ranges about 8.3-720 events yr- 1(SFRp/(10- 2.5 M⊙ yr- 1 Mpc- 3))([fb/(1 + fb)]/0.33). The minimum rate corresponds to the worst model which we think unlikely so that unless (SFRp/(10- 2.5 M⊙ yr- 1 Mpc- 3))([fb/(1 + fb)]/0.33) ≪ 0.1, we expect the Pop III BH-BHs merger rate of at least one event per year by KAGRA. Nakano, Tanaka & Nakamura show that if signal-to-noise ratio (S/N) of QNM is larger than 35, we can confirm or refute the general relativity (GR) more than 5σ level. In our standard model, the detection rate of Pop III BH-BHs whose S/N is larger than 35 is 3.2 events yr- 1 (SFRp/(10- 2.5 M⊙ yr- 1 Mpc- 3))([fb/(1 + fb)]/0.33)Errsys. Thus, there is a good chance to check whether GR is correct or not in the strong gravity region.

  19. Nonlinear dynamics of the tearing mode with two-fluid and curvature effects in tokamaks

    SciTech Connect

    Meshcheriakov, Dmytro; Maget, Patrick; Garbet, Xavier; Lütjens, Hinrich; Beyer, Peter

    2014-01-15

    Curvature and diamagnetic effects are both known to have an influence on tearing mode dynamics. In this paper, we investigate the impact of these effects on the nonlinear stability and saturation of a (2, 1) island using non-linear two-fluid MHD simulations and we apply our results to Tore Supra experiments, where its behavior is not well understood from the single fluid MHD model. Simulations show that a metastable state induced by diamagnetic effect exists for this mode and that it also produces a reduction of the saturated island size, in presence of toroidal curvature. The mode is found to be nonlinearly destabilized by a seed island and it saturates at a macroscopic level causing a significant confinement degradation. The interpretation of dual states, with either no island on q = 2 or a large one, observed on discharges with high non inductive current source on Tore Supra, is revisited.

  20. Observing mesoscale eddy effects on mode-water subduction and transport in the North Pacific

    PubMed Central

    Xu, Lixiao; Li, Peiliang; Xie, Shang-Ping; Liu, Qinyu; Liu, Cong; Gao, Wendian

    2016-01-01

    While modelling studies suggest that mesoscale eddies strengthen the subduction of mode waters, this eddy effect has never been observed in the field. Here we report results from a field campaign from March 2014 that captured the eddy effects on mode-water subduction south of the Kuroshio Extension east of Japan. The experiment deployed 17 Argo floats in an anticyclonic eddy (AC) with enhanced daily sampling. Analysis of over 3,000 hydrographic profiles following the AC reveals that potential vorticity and apparent oxygen utilization distributions are asymmetric outside the AC core, with enhanced subduction near the southeastern rim of the AC. There, the southward eddy flow advects newly ventilated mode water from the north into the main thermocline. Our results show that subduction by eddy lateral advection is comparable in magnitude to that by the mean flow—an effect that needs to be better represented in climate models. PMID:26829888

  1. Observing mesoscale eddy effects on mode-water subduction and transport in the North Pacific.

    PubMed

    Xu, Lixiao; Li, Peiliang; Xie, Shang-Ping; Liu, Qinyu; Liu, Cong; Gao, Wendian

    2016-01-01

    While modelling studies suggest that mesoscale eddies strengthen the subduction of mode waters, this eddy effect has never been observed in the field. Here we report results from a field campaign from March 2014 that captured the eddy effects on mode-water subduction south of the Kuroshio Extension east of Japan. The experiment deployed 17 Argo floats in an anticyclonic eddy (AC) with enhanced daily sampling. Analysis of over 3,000 hydrographic profiles following the AC reveals that potential vorticity and apparent oxygen utilization distributions are asymmetric outside the AC core, with enhanced subduction near the southeastern rim of the AC. There, the southward eddy flow advects newly ventilated mode water from the north into the main thermocline. Our results show that subduction by eddy lateral advection is comparable in magnitude to that by the mean flow--an effect that needs to be better represented in climate models. PMID:26829888

  2. The effect of an anisotropic pressure of thermal particles on resistive wall mode stability

    SciTech Connect

    Berkery, J. W. Sabbagh, S. A.; Betti, R.; Guazzotto, L.; Manickam, J.

    2014-11-15

    The effect of an anisotropic pressure of thermal particles on resistive wall mode stability in tokamak fusion plasmas is derived through kinetic theory and assessed through calculation with the MISK code [B. Hu et al., Phys. Plasmas 12, 0 57301 (2005)]. The fluid anisotropy is treated as a small perturbation on the plasma equilibrium and modeled with a bi-Maxwellian distribution function. A complete stability treatment without an assumption of high frequency mode rotation leads to anisotropic kinetic terms in the dispersion relation in addition to anisotropy corrections to the fluid terms. With the density and the average pressure kept constant, when thermal particles have a higher temperature perpendicular to the magnetic field than parallel, the fluid pressure-driven ballooning destabilization term is reduced. Additionally, the stabilizing kinetic effects of the trapped thermal ions can be enhanced. Together these two effects can lead to a modest increase in resistive wall mode stability.

  3. Cancellation of environmental effects in resonant mass sensors based on resonance mode and effective mass

    SciTech Connect

    Naeli, Kianoush; Brand, Oliver

    2009-06-15

    A novel technique is developed to cancel the effect of environmental parameters, e.g., temperature and humidity, in resonant mass sensing. Utilizing a single resonator, the environmental cancellation is achieved by monitoring a pair of resonant overtones and the effective sensed mass in those overtones. As an eminent advantage, especially compared to dual-mode temperature compensation techniques, the presented technique eliminates any need for previously measured look-up tables or fitting the measurement data. We show that a resonant cantilever beam is an appropriate platform for applying this technique, and derive an analytical expression to relate the actual and effective sensed masses on a cantilever beam. Thereby, it is shown that in applying the presented technique successfully, the effective sensed masses must not be the same in the investigated pair of resonance overtones. To prove the feasibility of the proposed technique, flexural resonance frequencies of a silicon cantilever are measured before and after loading with a strip of photoresist. Applying the presented technique shows significant reductions in influence of environmental parameters, with the temperature and humidity coefficients of frequency being improved from -19.5 to 0.2 ppm deg. C{sup -1} and from 0.7 to -0.03 ppm %RH{sup -1}, respectively.

  4. Effect of functionalization and charging on resonance energy and radial breathing modes of metallic carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Öberg, S.; Adjizian, J.-J.; Erbahar, D.; Rio, J.; Humbert, B.; Dossot, M.; Soldatov, A.; Lefrant, S.; Mevellec, J.-Y.; Briddon, P.; Rayson, M. J.; Ewels, C. P.

    2016-01-01

    While changes in resonant Raman scattering measurements are commonly used to measure the effect of chemical functionalization on single-walled carbon nanotubes, the precise effects of functionalization on these spectra have yet to be clearly identified. In this density functional theory study, we explore the effects of functionalization on both the nanotube resonance energy and frequency shifts in radial breathing mode. Charge transfer effects cause a shift in the first Van Hove singularity spacings, and hence resonance excitation energy, and lead to a decrease in the radial breathing mode frequency, notably when the Fermi level decreases. By varying stochastically the effective mass of carbon atoms in the tube, we simulate the mass effect of functionalization on breathing mode frequency. Finally, full density functional calculations are performed for different nanotubes with varying functional group distribution and concentration using fluorination and hydrogenation, allowing us to determine overall effect on radial breathing mode and charge transfer. The results concur well with experiment, and we discuss the importance when using Raman spectroscopy to interpret experimental functionalization treatments.

  5. Explanation of non-additive effects in mixtures of similar mode of action chemicals.

    PubMed

    Kamo, Masashi; Yokomizo, Hiroyuki

    2015-09-01

    Many models have been developed to predict the combined effect of drugs and chemicals. Most models are classified into two additive models: independent action (IA) and concentration addition (CA). It is generally considered if the modes of action of chemicals are similar then the combined effect obeys CA; however, many empirical studies report nonlinear effects deviating from the predictions by CA. Such deviations are termed synergism and antagonism. Synergism, which leads to a stronger toxicity, requires more careful management, and hence it is important to understand how and which combinations of chemicals lead to synergism. In this paper, three types of chemical reactions are mathematically modeled and the cause of the nonlinear effects among chemicals with similar modes of action was investigated. Our results show that combined effects obey CA only when the modes of action are exactly the same. Contrary to existing knowledge, combined effects are generally nonlinear even if the modes of action of the chemicals are similar. Our results further show that the nonlinear effects vanish out when the chemical concentrations are low, suggesting that the current management procedure of assuming CA is rarely inappropriate because environmental concentrations of chemicals are generally low. PMID:26134580

  6. Effect of III-V on insulator structure on quantum well intermixing

    NASA Astrophysics Data System (ADS)

    Takashima, Seiya; Ikku, Yuki; Takenaka, Mitsuru; Takagi, Shinichi

    2016-04-01

    To achieve the monolithic active/passive integration on the III-V CMOS photonics platform, quantum well intermixing (QWI) on III-V on insulator (III-V-OI) is studied for fabricating multi-bandgap III-V-OI wafers. By optimizing the QWI condition for a 250-nm-thick III-V layer, which contains a five-layer InGaAsP-based multi-quantum well (MQW) with 80-nm-thick indium phosphide (InP) cladding layers, we have successfully achieved a photoluminescence (PL) peak shift of over 100 nm on the III-V-OI wafer. We have also found that the progress of QWI on the III-V-OI wafer is slower than that on the InP bulk wafer regardless of the buried oxide (BOX) thickness, bonding interface materials, and handle wafers. We have also found that the progress of QWI on the III-V-OI wafer is slower than that on the InP bulk wafer regardless of the buried oxide (BOX) thickness, bonding interface materials, and bulk support wafers on which the III-V-OI structure is formed (handle wafers). By comparing between the measured PL shift and simulated diffusions of phosphorus vacancies and interstitials during QWI, we have found that the slow QWI progress in the III-V-OI wafer is probably attributed to the enhanced recombination of vacancies and interstitials by the diffusion blocking of vacancies and interstitials at the BOX interface.

  7. Importance of centrifugal effects for the internal kink mode stability in toroidally rotating tokamak plasmas

    SciTech Connect

    Wahlberg, C.

    2009-11-15

    Analytical theory and two different magnetohydrodynamical stability codes are used in a study of the effects of toroidal plasma rotation on the stability of the ideal, internal kink mode in tokamaks. The focus of the paper is on the role that the centrifugal effects on the plasma equilibrium play for the stability of this mode, and results from one code where centrifugal effects are self-consistently included (CASTOR-FLOW) [E. Strumberger et al., Nucl. Fusion 45, 1156 (2005)] are compared with the results from another code where such effects are not taken into account (MISHKA-F) [I. T. Chapman et al., Phys. Plasmas 13, 062511 (2006)]. It is found that, even at rather modest flow speeds, the centrifugal effects are very important for the stability of the internal kink mode. While the results from the two codes can be quite similar for certain profiles in the plasma, completely opposite results are obtained for other profiles. A very good agreement between analytical theory and the numerical results are, both for inconsistent and consistent equilibria, found for plasmas with large aspect ratio. From the analytical theory, the distinctly different stability properties of equilibria with and without centrifugal effects included can be traced to the stabilizing effect of the geodesic acoustic mode (GAM) induced by the plasma rotation. This GAM exists solely as a consequence of the nonuniform plasma density and pressure created by the centrifugal force on the flux surfaces, and a stabilizing coupling of the internal kink instability to this mode cannot therefore take place if the centrifugal effects are not included in the equilibrium. In addition to the GAM stabilization, the effects of the radial profiles of the plasma density and rotation velocity are also found to be significant, and the importance of these effects increases with decreasing aspect ratio.

  8. Modeling framework for materials capable of solid-solid phase transformation: application to the analytical solution of the semi-infinite mode III crack problem in an idealized shape memory alloy

    NASA Astrophysics Data System (ADS)

    Zaki, Wael; Moumni, Ziad

    2015-04-01

    We propose two frameworks for the derivation of constitutive models for solids undergoing phase transformations. The first is based on the assumption that solid phases within the material are finely mixed whereas the second considers the material as a heterogeneous solution of phase fragments and uses the homogenization theory to derive equilibrium conditions for displacement fields and phase distributions. It is shown that in the case of reversible phase transformation, the energy of the material can be obtained by taking the convex envelope of the energy functions of the constituent phases. As an application, a schematic model is derived for an idealized shape memory alloy and used to obtain a novel analytical solution for the problem of semi-infinite mode III crack in this material. The derivation of the analytical solution uses the hodograph method to map Cartesian coordinates into the hodograph plane. The resulting boundary-value problem for the mode III crack considered becomes analytically tractable for the idealized shape memory alloy considered and leads to closed-form expressions for the displacement and phase volume fraction fields near the crack tip as well as for the boundaries between different phase regions.

  9. Effect of phosphate and sulfate on Ni repartitioning during Fe(II)-catalyzed Fe(III) oxide mineral recrystallization

    NASA Astrophysics Data System (ADS)

    Hinkle, Margaret A. G.; Catalano, Jeffrey G.

    2015-09-01

    Dissolved Fe(II) activates coupled oxidative growth and reductive dissolution of Fe(III) oxide minerals, causing recrystallization and the repartitioning of structurally-compatible trace metals. Phosphate and sulfate, two ligands common to natural aquatic systems, alter Fe(II) adsorption onto Fe(III) oxides and affect Fe(III) oxide dissolution and precipitation. However, the effect of these oxoanions on trace metal repartitioning during Fe(II)-catalyzed Fe(III) oxide recrystallization is unclear. The effects of phosphate and sulfate on Ni adsorption and Ni repartitioning during Fe(II)-catalyzed Fe(III) oxide recrystallization were investigated as such repartitioning may be affected by both Fe(II)-oxoanion and metal-oxoanion interactions. In most systems examined, phosphate alters Ni repartitioning during Fe(II)-catalyzed recrystallization to a larger extent than sulfate. Phosphate substantially enhances Ni adsorption onto hematite but decreases (nearly inhibiting) Fe(II)-catalyzed Ni incorporation into and release from this mineral. In the goethite system, however, phosphate suppresses Ni release but enhances Ni incorporation in the presence of aqueous Fe(II). In contrast, sulfate has little effect on macroscopic Ni adsorption and release of Ni from Fe(III) oxides, but substantially enhances Ni incorporation into goethite. This demonstrates that phosphate and sulfate have unique, mineral-specific interactions with Ni during Fe(II)-catalyzed Fe(III) oxide recrystallization. This research suggests that micronutrient bioavailability at redox interfaces in hematite-dominated systems may be especially suppressed by phosphate, while both oxoanions likely have limited effects in goethite-rich soils or sediments. Phosphate may also exert a large control on contaminant fate at redox interfaces, increasing Ni retention on iron oxide surfaces. These results further indicate that trace metal retention by iron oxides during lithification and later repartitioning during

  10. T3_MM: A Markov Model Effectively Classifies Bacterial Type III Secretion Signals

    PubMed Central

    Wang, Yejun; Sun, Ming'an; Bao, Hongxia; White, Aaron P.

    2013-01-01

    Motivation Type III Secretion Systems (T3SSs) play important roles in the interaction between gram-negative bacteria and their hosts. T3SSs function by translocating a group of bacterial effector proteins into the host cytoplasm. The details of specific type III secretion process are yet to be clarified. This research focused on comparing the amino acid composition within the N-terminal 100 amino acids from type III secretion (T3S) signal sequences or non-T3S proteins, specifically whether each residue exerts a constraint on residues found in adjacent positions. We used these comparisons to set up a statistic model to quantitatively model and effectively distinguish T3S effectors. Results In this study, the amino acid composition (Aac) probability profiles conditional on its sequentially preceding position and corresponding amino acids were compared between N-terminal sequences of T3S and non-T3S proteins. The profiles are generally different. A Markov model, namely T3_MM, was consequently designed to calculate the total Aac conditional probability difference, i.e., the likelihood ratio of a sequence being a T3S or a non-T3S protein. With T3_MM, known T3S and non-T3S proteins were found to well approximate two distinct normal distributions. The model could distinguish validated T3S and non-T3S proteins with a 5-fold cross-validation sensitivity of 83.9% at a specificity of 90.3%. T3_MM was also shown to be more robust, accurate, simple, and statistically quantitative, when compared with other T3S protein prediction models. The high effectiveness of T3_MM also indicated the overall Aac difference between N-termini of T3S and non-T3S proteins, and the constraint of Aac exerted by its preceding position and corresponding Aac. Availability An R package for T3_MM is freely downloadable from: http://biocomputer.bio.cuhk.edu.hk/softwares/T3_MM. T3_MM web server: http://biocomputer.bio.cuhk.edu.hk/T3DB/T3_MM.php. PMID:23472154

  11. The formation of Population III stars and their effect on cosmological structure in the early universe

    NASA Astrophysics Data System (ADS)

    O'Shea, Brian William

    2005-11-01

    The first generation of stars to form in the universe have a profound impact on their environment. These stars are responsible for beginning the universe's transition from a "cosmic dark age" where no sources of visible light existed; to the bright universe seen today. Additionally, these stars were believed to be the first sources of all elements heavier than lithium, which strongly affected the ability of gas to cool and permanently changed how star formation occurred. In this dissertation I present results from numerical simulations of the formation of the first generation of stars to form in the universe ("Population III" stars) and their effects on later structure formation. I compare Enzo, the adaptive mesh refinement cosmology code used to perform all of the simulations in this work, to GADGET, a smoothed particle hydrodynamics cosmology code. Nearly identical results can be obtained when using two extremely different numerical methods, which helps to verify the correctness of both codes and strengthen the confidence of predictions made with these tools. I perform high dynamical range calculations of the formation of an ensemble of Population III stars, varying multiple simulation parameters, in a standard cold dark matter cosmology as well as with a soft ultraviolet background and in a generic warm dark matter cosmology. I find that the accretion rates of primordial protostars have been systematically overestimated by previously published work, which has profound implications for later structure formation and the reionization of the universe. Additionally, the presence of a soft ultraviolet background and warm dark matter serves to delay the onset of star formation. I propose limits on the possible mass of a warm dark matter particle. I also present results of simulations which demonstrate the effects of the HII regions and metal enrichment from Population III stars. It appears that HII regions from these stars may hasten the formation of later generations

  12. Effects of locomotion mode recognition errors on volitional control of powered above-knee prostheses.

    PubMed

    Zhang, Fan; Liu, Ming; Huang, He

    2015-01-01

    Recent studies have reported various methods that recognize amputees' intent regarding locomotion modes, which is potentially useful for volitional control of powered artificial legs. However, occasional errors in locomotion mode recognition are inevitable. When these intent recognition decisions are used for volitional prosthesis control, the effects of the decision errors on the operation of the prosthesis and user's task performance is unknown. Hence, the goals of this study were to 1) systematically investigate the effects of locomotion mode recognition errors on volitional control of powered prosthetic legs and the user's gait stability, and 2) identify the critical mode recognition errors that impact safe and confident use of powered artificial legs in lower limb amputees. Five able-bodied subjects and two above-knee (AK) amputees were recruited and tested when wearing a powered AK prosthesis. Four types of locomotion mode recognition errors with different duration and at different gait phases were purposely applied to the prosthesis control. The subjects' gait stabilities were subjectively and objectively quantified. The results showed that not all of the mode recognition errors in volitional prosthesis control disturb the subjects' gait stability. The effects of errors on the user's balance depended on 1) the gait phase when the errors happened and 2) the amount of mechanical work change applied on the powered knee caused by the errors. Based on the study results, "critical errors" were defined and suggested as a new index to evaluate locomotion mode recognition algorithms for artificial legs. The outcome of this study might aid the future design of volitionally-controlled powered prosthetic legs that are reliable and safe for practice. PMID:25486645

  13. Hydrogen effects in dilute III-N-V alloys: From defect engineering to nanostructuring

    SciTech Connect

    Pettinari, G.; Felici, M.; Capizzi, M.; Polimeni, A.; Trotta, R.

    2014-01-07

    The variation of the band gap energy of III-N-V semiconductors induced by hydrogen incorporation is the most striking effect that H produces in these materials. A special emphasis is given here to the combination of N-activity passivation by hydrogen with H diffusion kinetics in dilute nitrides. Secondary ion mass spectrometry shows an extremely steep (smaller than 5 nm/decade) forefront of the H diffusion profile in Ga(AsN) under appropriate hydrogenation conditions. This discovery prompts the opportunity for an in-plane nanostructuring of hydrogen incorporation and, hence, for a modulation of the material band gap energy at the nanoscale. The properties of quantum dots fabricated by a lithographically defined hydrogenation are presented, showing the zero-dimensional character of these novel nanostructures. Applicative prospects of this nanofabrication method are finally outlined.

  14. Comments on the somatic effects section of the BEIR III report

    SciTech Connect

    Rossi, H.H.

    1980-12-01

    The recent report of the BEIR Committee of the National Academy of Sciences presents a wide range of risk estimates for radiogenic cancer. The values that can be considered to be most plausible on the basis of radiobiological and epidemiological evidence are given little emphasis and they are presented as lower bounds of the probable risk. The upper bound is said to be provided by estimates based on the so-called linear hypothesis. The preferred analysis in BEIR III requires an arbitrary choice of a critical parameter. This results in estimates that differ little from those given in BEIR I and that may be too high by an order of magnitude. It also refuses to speculate on any health effects of background radiation. It thus does not support the validity of those concepts of radiation protection that are based on linearity.

  15. Atom-mediated effective interactions between modes of a bimodal cavity

    SciTech Connect

    Prado, F. O.; Luiz, F. S.; Villas-Boas, J. M.; Alcalde, A. M.; Duzzioni, E. I.; Sanz, L.

    2011-11-15

    We show a procedure for engineering effective interactions between two modes in a bimodal cavity. Our system consists of one or more two-level atoms, excited by a classical field, interacting with both modes. The two effective Hamiltonians have forms similar to beam-splitter and quadratic beam-splitter interactions. We also demonstrate that the nonlinear Hamiltonian can be used to prepare an entangled coherent state, also known as a multidimensional entangled coherent state, which has been pointed out as an important entanglement resource. We show that the nonlinear interaction parameter can be enhanced considering N independent atoms trapped inside a high-finesse optical cavity.

  16. Application of failure mode and effect analysis in an assisted reproduction technology laboratory.

    PubMed

    Intra, Giulia; Alteri, Alessandra; Corti, Laura; Rabellotti, Elisa; Papaleo, Enrico; Restelli, Liliana; Biondo, Stefania; Garancini, Maria Paola; Candiani, Massimo; Viganò, Paola

    2016-08-01

    Assisted reproduction technology laboratories have a very high degree of complexity. Mismatches of gametes or embryos can occur, with catastrophic consequences for patients. To minimize the risk of error, a multi-institutional working group applied failure mode and effects analysis (FMEA) to each critical activity/step as a method of risk assessment. This analysis led to the identification of the potential failure modes, together with their causes and effects, using the risk priority number (RPN) scoring system. In total, 11 individual steps and 68 different potential failure modes were identified. The highest ranked failure modes, with an RPN score of 25, encompassed 17 failures and pertained to "patient mismatch" and "biological sample mismatch". The maximum reduction in risk, with RPN reduced from 25 to 5, was mostly related to the introduction of witnessing. The critical failure modes in sample processing were improved by 50% in the RPN by focusing on staff training. Three indicators of FMEA success, based on technical skill, competence and traceability, have been evaluated after FMEA implementation. Witnessing by a second human operator should be introduced in the laboratory to avoid sample mix-ups. These findings confirm that FMEA can effectively reduce errors in assisted reproduction technology laboratories. PMID:27282213

  17. Realizing mode conversion and optical diode effect by coupling photonic crystal waveguides with cavity

    NASA Astrophysics Data System (ADS)

    Ye, Han; Zhang, Jin-Qian-Nan; Yu, Zhong-Yuan; Wang, Dong-Lin; Chen, Zhi-Hui

    2015-09-01

    We propose a novel two-dimensional photonic crystal structure consisting of two line defect waveguides and a cavity to realize mode conversion based on the coupling effect. The W1/cavity/W2 structure breaks the spatial symmetry and successfully converts the even (odd) mode to the odd (even) mode in the W2 waveguide during the forward (backward) transmission. When considering the incidence of only the even mode, the optical diode effect emerges and achieves approximate 35 dB unidirectionality at the resonant frequency. Moreover, owing to the narrow bandpass feature and the flexibility of the tuning cavity, utilization of the proposed structure as a wavelength filter is demonstrated in a device with a Y-branch splitter. Here, we provide a heuristic design for a mode converter, optical diode, and wavelength filter derived from the coupling effect between a cavity and adjacent waveguides, and expect that the proposed structure can be applied as a building block in future all-optical integrated circuits. Project supported by the National Natural Science Foundation of China (Grant Nos. 61372037 and 61307069), Beijing Excellent Ph. D. Thesis Guidance Foundation, China (Grant No. 20131001301), and the Natural Science Foundation of Shanxi Province, China (Grant No. 2013021017-3).

  18. Effect of desferrioxamine B and Suwannee River fulvic acid on Fe(III) release and Cr(III) desorption from goethite

    NASA Astrophysics Data System (ADS)

    Stewart, Angela G.; Hudson-Edwards, Karen A.; Dubbin, William E.

    2016-04-01

    Siderophores are biogenic chelating ligands that facilitate the solubilisation of Fe(III) and form stable complexes with a range of contaminant metals and therefore may significantly affect their biogeochemical cycling. Desferrioxamine B (DFOB) is a trihydroxamate siderophore that acts synergistically with fulvic acid and low molecular weight organic ligands to release Fe from Fe(III) oxides. We report the results of batch dissolution experiments in which we determine the rates of Cr(III) desorption and Fe(III) release from Cr(III)-treated synthetic goethite as influenced by DFOB, by fulvic acid, and by the two compounds in combination. We observed that adsorbed Cr(III) at 3% surface coverage significantly reduced Fe(III) release from goethite for all combinations of DFOB and fulvic acid. When DFOB (270 μM) was the only ligand present, dissolved Fe(III) and Cr(III) increased approximately 1000-fold and 16-fold, respectively, as compared to the ligand-free system, a difference we attribute to the slow rate of water exchange of Cr(III). Suwannee River fulvic acid (SRFA) acts synergistically with DFOB by (i) reducing the goethite surface charge leading to increased HDFOB+ surface excess and by (ii) forming aqueous Fe(III)-SRFA species whose Fe(III) is subsequently removed by DFOB to yield aqueous Fe(III)-DFOB complexes. These observations shed new light on the synergistic relationship between DFOB and fulvic acid and reveal the mechanisms of Fe(III) acquisition available to plants and micro-organisms in Cr(III) contaminated environments.

  19. Effects of Failure Modes on Strength of Aluminum Resistance Spot Welds

    SciTech Connect

    Sun, Xin; Stephens, Elizabeth V.; Davies, Richard W.; Khaleel, Mohammad A.; Spinella, Donald J.

    2005-04-01

    This paper examines the effects of failure modes on the static strength and total energy absorption of aluminum spot-welded samples using experimental, statistical, and analytical approaches. The main failure modes for aluminum spot welds are nugget pullout and interfacial fracture. Two populations of aluminum spot welds were studied. Within each population, coupon configurations of lap shear, cross tension and coach peel were considered. Thirty replicate static strength tests were performed for each coupon configuration. The resulted peak load and energy absorption level associated with each failure mode was studied using statistical models. Next, an analytical model was developed to determine the failure mode of an aluminum resistance spot weld based on stress analysis. It is found that weld size, sheet thickness, and level of weld porosity and defects are the main factors determining the cross tension failure mode for an aluminum spot weld. The peak load and energy absorption levels for the cross tension and coach peel samples tested are found not to be very sensitive to the failure modes under static loading.

  20. Effects of load voltage on voltage breakdown modes of electrical exploding aluminum wires in air

    SciTech Connect

    Wu, Jian; Li, Xingwen Yang, Zefeng; Wang, Kun; Chao, Youchuang; Shi, Zongqian; Jia, Shenli; Qiu, Aici

    2015-06-15

    The effects of the load voltage on the breakdown modes are investigated in exploding aluminum wires driven by a 1 kA, 0.1 kA/ns pulsed current in air. From laser probing images taken by laser shadowgraphy, schlieren imaging, and interferometry, the position of the shockwave front, the plasma channel, and the wire core edge of the exploding product can be determined. The breakdown mode makes a transition from the internal mode, which involves breakdown inside the wire core, to the shunting mode, which involves breakdown in the compressed air, with decreasing charging voltage. The breakdown electrical field for a gaseous aluminum wire core of nearly solid density is estimated to be more than 20 kV/cm, while the value for gaseous aluminum of approximately 0.2% solid density decreases to 15–20 kV/cm. The breakdown field in shunting mode is less than 20 kV/cm and is strongly affected by the vaporized aluminum, the desorbed gas, and the electrons emitted from the wire core during the current pause. Ohmic heating during voltage collapses will induce further energy deposition in the current channel and thus will result in different expansion speeds for both the wire core and the shockwave front in the different modes.

  1. Effects of load voltage on voltage breakdown modes of electrical exploding aluminum wires in air

    NASA Astrophysics Data System (ADS)

    Wu, Jian; Li, Xingwen; Yang, Zefeng; Wang, Kun; Chao, Youchuang; Shi, Zongqian; Jia, Shenli; Qiu, Aici

    2015-06-01

    The effects of the load voltage on the breakdown modes are investigated in exploding aluminum wires driven by a 1 kA, 0.1 kA/ns pulsed current in air. From laser probing images taken by laser shadowgraphy, schlieren imaging, and interferometry, the position of the shockwave front, the plasma channel, and the wire core edge of the exploding product can be determined. The breakdown mode makes a transition from the internal mode, which involves breakdown inside the wire core, to the shunting mode, which involves breakdown in the compressed air, with decreasing charging voltage. The breakdown electrical field for a gaseous aluminum wire core of nearly solid density is estimated to be more than 20 kV/cm, while the value for gaseous aluminum of approximately 0.2% solid density decreases to 15-20 kV/cm. The breakdown field in shunting mode is less than 20 kV/cm and is strongly affected by the vaporized aluminum, the desorbed gas, and the electrons emitted from the wire core during the current pause. Ohmic heating during voltage collapses will induce further energy deposition in the current channel and thus will result in different expansion speeds for both the wire core and the shockwave front in the different modes.

  2. Effects of Caramel Colour III on the number of blood lymphocytes: a human study on Caramel Colour III immunotoxicity and a comparison of the results with data from rat studies.

    PubMed

    Houben, G F; van Dokkum, W; van Loveren, H; Penninks, A H; Seinen, W; Spanhaak, S; Ockhuizen, T

    1992-05-01

    Administration of the colour additive Ammonia Caramel Colour (Caramel Colour III) to rats has been associated with decreased lymphocyte counts, specifically in rats fed a diet low in vitamin B6. This effect is rapidly reversible and is caused by an imidazole derivative (THI) in Caramel Colour III. In the present paper, the conduct of a human study with Caramel Colour III is outlined and the results of blood lymphocyte counts are presented. No decrease in the number of blood lymphocytes occurred in marginally vitamin B6-deficient humans who consumed Caramel Colour III at the acceptable daily intake level (200 mg/kg body weight/day) for 7 days. These data are discussed in relation to the effects of Caramel Colour III and THI on blood lymphocyte numbers in rats. PMID:1644384

  3. Where is the breathing mode? High voltage Hall effect thruster studies with EMD method

    SciTech Connect

    Kurzyna, J.; Makowski, K.; Mazouffre, S.; Peradzynski, Z.; Lazurenko, A.; Dudeck, M.

    2008-03-19

    Discharge current and local plasma oscillations are studied in a high voltage Hall effect thruster PPS registered -X000. Characteristic time scales that appear in different operating conditions are resolved with the use of Hilbert-Huang spectra (HHS) which display time dependenc of instantaneous frequency and power. Sets of intrinsic mode functions (imfs) that are used for HHS calculation result due to application of empirical mode decomposition method (EMD) to nonstationary multicomponent signals. In the experiment the signals are captured in the electric circuit of the thruster as well locally, in the vicinity of the thruster exhaust region. Classical electric probes spaced along the azimuth and/or thruster axis let us study correlations of signals which were captured in different locations. In this way azimuthal and axial propagation of disturbances is inspected. The discharge voltage is varied in the range of 200 divide 900 V while xenon mas flow rate of 5 divide 9 mg/s. LF, MF, and HF characteristic bands that are known from previous studies of PPS registered -100 thruster have been also detected here. However, expanding discharge current onto a set of intrinsic modes we can resolve MF mode more reliably than before. Moreover, for higher discharge voltages, this irregular mode turns into more regular waveform and tends to dominate in the discharge current masking almost completely the breathing mode (LF oscillations of the discharge current). In such a case triggering of HF oscillations is correlated with the phase of MF mode while in the case of PPS registered -100 thruster it was correlated with the appropriate phase of the breathing mode (LF band). Regular HF emission that can be unambiguously interpreted as azimuthal electrostatic wave now is observed only in the specific operating conditions of the thruster. However, even if irregular HF emission is observed the time delay of cross-correlated signals which are captured in different azimuthal locations

  4. Effectiveness and cost of failure mode and effects analysis methodology to reduce neurosurgical site infections.

    PubMed

    Hover, Alexander R; Sistrunk, William W; Cavagnol, Robert M; Scarrow, Alan; Finley, Phillip J; Kroencke, Audrey D; Walker, Judith L

    2014-01-01

    Mercy Hospital Springfield is a tertiary care facility with 32 000 discharges and 15 000 inpatient surgeries in 2011. From June 2009 through January 2011, a stable inpatient elective neurosurgery infection rate of 2.15% was observed. The failure mode and effects analysis (FMEA) methodology to reduce inpatient neurosurgery infections was utilized. Following FMEA implementation, overall elective neurosurgery infection rates were reduced to 1.51% and sustained through May 2012. Compared with baseline, the post-FMEA deep-space and organ infection rate was reduced by 41% (P = .052). Overall hospital inpatient clean surgery infection rates for the same time frame did not decrease to the same extent, suggesting a specific effect of the FMEA. The study team believes that the FMEA interventions resulted in 14 fewer expected infections, $270 270 in savings, a 168-day reduction in expected length of stay, and 22 fewer readmissions. Given the serious morbidity and cost of health care-associated infections, the study team concludes that FMEA implementation was clinically cost-effective. PMID:24101683

  5. Subchronic administration of riparin III induces antidepressive-like effects and increases BDNF levels in the mouse hippocampus.

    PubMed

    Vasconcelos, Auriana S; Oliveira, Iris C M; Vidal, Laura T M; Rodrigues, Gabriel C; Gutierrez, Stanley J C; Barbosa-Filho, José M; Vasconcelos, Silvânia M M; de França Fonteles, Marta M; Gaspar, Danielle M; de Sousa, Francisca C F

    2015-08-01

    Riparin III (Rip III) is an alcamide isolated from Aniba riparia that has presented effects of antidepressant and anxiolytic activities in acute stress behavioral models. The trial's goal was to investigate the activity of Rip III in mice exposed to corticosterone-induced chronic depression model. Swiss female mice, 22-25 g, were distributed in following experimental groups: control group (vehicle1: saline containing 0.1% dimethyl sulfoxide and 0.1% Tween-80, SC+ vehicle 2: distilled water emulsified with 2% Tween-80, PO); stressed group (corticosterone, 20 mg/kg, SC, + vehicle 2, orally); Rip III group (50 mg/kg, orally); and fluvoxamine (Flu) group (50 mg/kg, orally). The mice were exposed to the behavioral tests, and posteriorly, Brain-derived neurotrophic factor protein levels were assessed in hippocampal samples. Statistical analysis of the data was performed by one-way anova, followed by Newman-Keuls test. Both administrations of Rip III and Flu significantly reduced the immobility time in tail suspension and forced swimming tests after 21 days without affecting locomotor function. There was also an increase in BDNF protein levels in the mice hippocampus. These findings further support the hypothesis that Rip III could be a new pharmacological target for the treatment of mood disorders. PMID:25846646

  6. Effects of dissimilatory sulfate reduction on FeIII (hydr)oxide reduction and microbial community development

    NASA Astrophysics Data System (ADS)

    Kwon, Man Jae; Boyanov, Maxim I.; Antonopoulos, Dionysios A.; Brulc, Jennifer M.; Johnston, Eric R.; Skinner, Kelly A.; Kemner, Kenneth M.; O'Loughlin, Edward J.

    2014-03-01

    Although dissimilatory iron and sulfate reduction (DIR and DSR) profoundly affect the biogeochemical cycling of C, Fe, and S in subsurface systems, the dynamics of DIR and DSR in the presence of both FeIII (hydr)oxides and sulfate have not been well-studied with mixed microbial populations. This study examined the response of native microbial communities in subsurface sediment from the U.S. Department of Energy’s Integrated Field Research Challenge site in Rifle, CO to the availability of sulfate and specific FeIII (hydr)oxide minerals in experimental systems containing lactate as the electron donor, with ferrihydrite, goethite, or lepidocrocite and high (10.2 mM) or low (0.2 mM) sulfate as electron acceptors. We observed rapid fermentation of lactate to acetate and propionate. FeIII reduction was slow and limited in the presence of low-sulfate, but the extent of FeIII reduction increased more than 10 times with high-sulfate amendments. Furthermore, the extent of FeIII reduction was higher in ferrihydrite or lepidocrocite incubations than in goethite incubations. Propionate produced during fermentation of lactate was used as the electron donor for DSR. The concurrence of sulfate reduction and FeII production suggests that FeII production was driven primarily by reduction of FeIII by biogenic sulfide. X-ray absorption fine-structure analysis confirmed the formation of ferrous sulfide and the presence of O-coordinated ferrous species. 16S rRNA-based microbial community analysis revealed the development of distinct communities with different FeIII (hydr)oxides. These results highlight the highly coupled nature of C, Fe, and S biogeochemical cycles during DIR and DSR and provide new insight into the effects of electron donor utilization, sulfate concentration, and the presence of specific FeIII (hydr)oxide phases on microbial community development.

  7. Teeter-totter effect of terahertz dual modes in C-shaped complementary split-ring resonators

    NASA Astrophysics Data System (ADS)

    Song, Zhiqiang; Zhao, Zhenyu; Zhao, Hongwei; Peng, Wei; He, Xiaoyong; Shi, Wangzhou

    2015-07-01

    A teeter-totter effect of terahertz (THz) resonant modes in C-shaped complementary split-ring resonators (CSRRs) is observed. The dual resonant mode transmission enhancement was investigated using THz time-domain spectroscopy. The intensity of the lower-frequency resonance modes increases monotonically with the CSSR gap width, which is accompanied by a monotonic decrease in the intensity of the higher-frequency resonance modes. The origin of the dual resonant modes is numerically explained by the electromagnetic energy density distribution and surface current analysis. The inductive-capacitive resonance dominates the lower frequency mode, while the dipole oscillation dominates the higher frequency mode. By tuning the gap of the CSRR, an equilibrant transmittance of above dual resonance modes can be designed. This teeter-totter effect promises a possible application of CSSRs as potential dual-bandpass filters in the THz-region.

  8. Passive mode locking of thin-disk lasers: effects of spatial hole burning

    NASA Astrophysics Data System (ADS)

    Paschotta, R.; Aus der Au, J.; Spühler, G. J.; Erhard, S.; Giesen, A.; Keller, U.

    We recently demonstrated that passive mode locking of a thin-disk Yb:YAG laser is possible and that this concept leads to sources of femtosecond pulses with very high average power. Here we discuss in detail the effect of spatial hole burning on the mode-locking behavior of such lasers. We have developed an efficient numerical model and arrive at quantitative stability criteria which agree well with experimental data. The main result is that stable soliton mode locking can in general be obtained only in a certain range of pulse durations. We use our model to investigate the influence of various cavity parameters and the situation for different gain media. We also consider several methods to reduce the effect of spatial hole burning in order to expand the range of possible pulse durations.

  9. Optical and mechanical mode tuning in an optomechanical crystal with light-induced thermal effects

    SciTech Connect

    Navarro-Urrios, D.; Gomis-Bresco, J.; Alzina, F.; Capuj, N. E.; Griol, A.; Puerto, D.; Martínez, A.; Sotomayor-Torres, C. M.

    2014-09-07

    We report on the modification of the optical and mechanical properties of a silicon 1D optomechanical crystal cavity due to thermo-optic effects in a high phonon/photon population regime. The cavity heats up due to light absorption in a way that shifts the optical modes towards longer wavelengths and the mechanical modes to lower frequencies. By combining the experimental optical results with finite-difference time-domain simulations, we establish a direct relation between the observed wavelength drift and the actual effective temperature increase of the cavity. By assuming that the Young's modulus decreases accordingly to the temperature increase, we find a good agreement between the mechanical mode drift predicted using a finite element method and the experimental one.

  10. Mode-coupling effects in anisotropic flow in heavy-ion collisions

    NASA Astrophysics Data System (ADS)

    Qian, Jing; Heinz, Ulrich; Liu, Jia

    2016-06-01

    Higher-order anisotropic flows in heavy-ion collisions are affected by nonlinear mode coupling effects. It has been suggested that the associated nonlinear hydrodynamic response coefficients probe the transport properties and are largely insensitive to the spectrum of initial density fluctuations of the medium created in these collisions. To test this suggestion, we explore nonlinear mode coupling effects in event-by-event viscous fluid dynamics, using two different models for the fluctuating initial density profiles, and compare the nonlinear coupling coefficients between the initial eccentricity vectors before hydrodynamic expansion and the final flow vectors after the expansion. For several mode coupling coefficients we find significant sensitivity to the initial fluctuation spectrum. They all exhibit strong sensitivity to the specific shear viscosity at freeze-out, but only weak dependence on the shear viscosity during hydrodynamic evolution.

  11. High relaxivity Gd(III)-DNA gold nanostars: investigation of shape effects on proton relaxation.

    PubMed

    Rotz, Matthew W; Culver, Kayla S B; Parigi, Giacomo; MacRenaris, Keith W; Luchinat, Claudio; Odom, Teri W; Meade, Thomas J

    2015-03-24

    Gadolinium(III) nanoconjugate contrast agents (CAs) have distinct advantages over their small-molecule counterparts in magnetic resonance imaging. In addition to increased Gd(III) payload, a significant improvement in proton relaxation efficiency, or relaxivity (r1), is often observed. In this work, we describe the synthesis and characterization of a nanoconjugate CA created by covalent attachment of Gd(III) to thiolated DNA (Gd(III)-DNA), followed by surface conjugation onto gold nanostars (DNA-Gd@stars). These conjugates exhibit remarkable r1 with values up to 98 mM(-1) s(-1). Additionally, DNA-Gd@stars show efficient Gd(III) delivery and biocompatibility in vitro and generate significant contrast enhancement when imaged at 7 T. Using nuclear magnetic relaxation dispersion analysis, we attribute the high performance of the DNA-Gd@stars to an increased contribution of second-sphere relaxivity compared to that of spherical CA equivalents (DNA-Gd@spheres). Importantly, the surface of the gold nanostar contains Gd(III)-DNA in regions of positive, negative, and neutral curvature. We hypothesize that the proton relaxation enhancement observed results from the presence of a unique hydrophilic environment produced by Gd(III)-DNA in these regions, which allows second-sphere water molecules to remain adjacent to Gd(III) ions for up to 10 times longer than diffusion. These results establish that particle shape and second-sphere relaxivity are important considerations in the design of Gd(III) nanoconjugate CAs. PMID:25723190

  12. Hybrid simulation of energetic particle effects on tearing modes in tokamak plasmas

    SciTech Connect

    Cai Huishan; Fu Guoyong

    2012-07-15

    The effects of energetic ions on stability of tearing mode are investigated by global kinetic/MHD hybrid simulations in a low beta tokamak plasma. The kinetic effects of counter circulating energetic ions from the non-adiabatic response are found to be strongly destabilizing while the effects from the adiabatic response are stabilizing. The net effect with both adiabatic and non-adiabatic contributions is destabilizing. On the other hand, the kinetic effects of co-circulating energetic ions from the non-adiabatic response are calculated to be weakly stabilizing while the corresponding adiabatic contribution is destabilizing for small energetic ion beta. The net effect is weakly stabilizing. The dependence of kinetic effects on energetic ion beta, gyroradius, and speed is studied systematically and the results agree in large part with the previous analytic results for the kinetic effects of circulating particles. For trapped energetic ions, their effects on tearing mode stability are dominated by the adiabatic response due to large banana orbit width and strong poloidal variation of particle pressure. The net effect of trapped energetic particles on tearing modes is much more destabilizing as compared to that of counter circulating particles at the same beta value.

  13. The effect of truncating the normal mode coupling equations on synthetic spectra

    NASA Astrophysics Data System (ADS)

    Akbarashrafi, F.; Valentine, A. P.; Al-Attar, D.; Trampert, J.

    2015-12-01

    The free oscillations, or normal modes, of the Earth provide important constraints on the long-wavelength structure of our planet. Calculations using normal modes are also necessary if the effects of gravity are to be fully modeled in seismic waveforms, which becomes important at low frequencies. To implement these calculations, we typically initially compute the normal modes (eigenfunctions) of a spherically-symmetric model such as PREM. These form a complete set of basis functions, which may then be used to describe the seismic response of laterally heterogeneous models. This procedure is known as 'mode coupling'. In order to implement the calculation, it is necessary to select a finite subset of modes (invariably defined by a frequency range) to be considered. This truncation of the infinite-dimensional equations necessarily introduces an error into the results. Here, we consider the fundamental question: if we wish to calculate synthetic spectra in a given frequency range, how many modes must we couple for the resulting spectra to be sufficiently accurate? To investigate this question, we compute spectra in the 3D model S20RTS up to 2mHz, but allowing coupling with all modes up to 5mHz. We then explore how the spectra change as we reduce the upper frequency used in the coupling. We compare this to the effects introduced by altering the 3D density structure of the model. Clearly, if we wish to image Earth's density structure accurately, it is important that the truncation error is small compared to this signal.

  14. Effects of type III antifreeze protein on sperm and embryo cryopreservation in rabbit.

    PubMed

    Nishijima, Kazutoshi; Tanaka, Mai; Sakai, Yusuke; Koshimoto, Chihiro; Morimoto, Masatoshi; Watanabe, Teruo; Fan, Jianglin; Kitajima, Shuji

    2014-08-01

    We investigated the effects of antifreeze protein (AFP) III supplementation on the cryopreservation of rabbit sperm cells and embryos. Ejaculated semen was collected from male Japanese white (JW) rabbits and divided into four AFP-supplemented groups (0.1 μg/ml, 1 μg/ml, 10 μg/ml, 100 μg/ml) and one control group with no AFP-supplementation. The semen samples were treated with egg-yolk HEPES extender containing 6% acetamide before the sperm was cooled from room temperature to 5 °C, then packed into sperm straws. The straws were frozen in steam of liquid nitrogen (LN2) and then preserved in the LN2. The motility of the sperm after thawing in 37 °C water was analyzed. The percentage of rapidly motile sperm in the 1 μg/ml AFP group was significantly higher than in the control group. Morulae were collected from female JW rabbits and divided into three AFP-supplemented groups (100 ng/ml, 500 ng/ml, 1000 ng/ml) and one control group. The morulae, immersed in an embryo-freezing solution (M199-HEPES containing 20% ethylene glycol, 20% dimethylsulfoxide, 10% fetal bovine serum and 0.25 M sucrose), were packed into open pulled embryo straws and vitrified in LN2. The frozen embryos were thawed in the embryo-freezing solution, and the rates of embryo survival and development to blastocyte stage were analyzed after incubation for 72 h. The development rate of the embryos in the 500 ng/ml AFP group was significantly higher than in the control group, but that in the 1000 ng/ml AFP group was significantly lower. In conclusion, the appropriate dose of AFP III increased the number of rapidly motile sperm and embryo survival following freezing and thawing. The results suggest that supplementation with AFP III can increase the efficiency of cryopreservation of rabbit sperm cells and embryos. PMID:24809634

  15. Techniques for setting modes of thermal and deformation effect at combined hardening and finishing operations

    NASA Astrophysics Data System (ADS)

    Rakhimyanov, Kh M.; Rakhimyanov, K. Kh; Rakhimyanov, A. Kh; Kutyshkin, A. V.

    2016-04-01

    This paper considers the issues of setting the modes of thermal and deformation effects in the basic schemes at combined hardening and finishing operations. On the basis of solving the thermal physical problem of material high rate heating, the parameters of a thermohardened layer were determined within the range of the investigated modes. An algorithm for setting the mode parameters of high rate heating responsible for the hardening effect at the combined processing was proposed. The analysis of the mathematical model for forming a surface microrelief at ultrasonic deformation showed that the sizes, the form of fragments and the density of a microrelief were determined by the processing kinematic parameters. An algorithm for setting the rotation speed and feeding at ultrasonic deformation according to microrelief characteristics was developed. The conditions to form a completely regular microrelief on the processed surface that represent the ratio between a single imprint diameter at the ultrasonic deformation and the processing kinematic parameters were determined. The complex of the algorithms suggested for setting the mode parameters of high rate heating and ultrasonic deformation constitutes the techniques for setting the modes of combined hardening and finishing operations.

  16. Altered effective connectivity patterns of the default mode network in Alzheimer's disease: an fMRI study.

    PubMed

    Zhong, Yufang; Huang, Liyu; Cai, Suping; Zhang, Yun; von Deneen, Karen M; Ren, Aifeng; Ren, Junchan

    2014-08-22

    The aim of this work is to investigate the differences of effective connectivity of the default mode network (DMN) in Alzheimer's disease (AD) patients and normal controls (NC). The technique of independent component analysis (ICA) was applied to identify DMN components and multivariate Granger causality analysis (mGCA) was used to explore an effective connectivity pattern. We found that: (i) connections in AD were decreased than those in NC, in terms of intensity and quantity. Posterior cingulated cortex (PCC) exhibited significant activity in NC as it connected with most of the other regions within the DMN. Besides, the PCC was the convergence center which only received interactions from other regions; (ii) right inferior temporal cortex (rITC) in the NC exhibited stronger interactions with other regions within the DMN compared with AD patients; and (iii) interactions between medial prefrontal cortex (MPFC) and bilateral inferior parietal cortex (IPC) in the NC were weaker than those in AD patients. These findings may implicate a brain dysfunction in AD patients and reveal more pathophysiological characteristics of AD. PMID:24996191

  17. Implications of the Differential Toxicological Effects of III-V Ionic and Particulate Materials for Hazard Assessment of Semiconductor Slurries.

    PubMed

    Jiang, Wen; Lin, Sijie; Chang, Chong Hyun; Ji, Zhaoxia; Sun, Bingbing; Wang, Xiang; Li, Ruibin; Pon, Nanetta; Xia, Tian; Nel, André E

    2015-12-22

    Because of tunable band gaps, high carrier mobility, and low-energy consumption rates, III-V materials are attractive for use in semiconductor wafers. However, these wafers require chemical mechanical planarization (CMP) for polishing, which leads to the generation of large quantities of hazardous waste including particulate and ionic III-V debris. Although the toxic effects of micron-sized III-V materials have been studied in vivo, no comprehensive assessment has been undertaken to elucidate the hazardous effects of submicron particulates and released III-V ionic components. Since III-V materials may contribute disproportionately to the hazard of CMP slurries, we obtained GaP, InP, GaAs, and InAs as micron- (0.2-3 μm) and nanoscale (<100 nm) particles for comparative studies of their cytotoxic potential in macrophage (THP-1) and lung epithelial (BEAS-2B) cell lines. We found that nanosized III-V arsenides, including GaAs and InAs, could induce significantly more cytotoxicity over a 24-72 h observation period. In contrast, GaP and InP particulates of all sizes as well as ionic GaCl3 and InCl3 were substantially less hazardous. The principal mechanism of III-V arsenide nanoparticle toxicity is dissolution and shedding of toxic As(III) and, to a lesser extent, As(V) ions. GaAs dissolves in the cell culture medium as well as in acidifying intracellular compartments, while InAs dissolves (more slowly) inside cells. Chelation of released As by 2,3-dimercapto-1-propanesulfonic acid interfered in GaAs toxicity. Collectively, these results demonstrate that III-V arsenides, GaAs and InAs nanoparticles, contribute in a major way to the toxicity of III-V materials that could appear in slurries. This finding is of importance for considering how to deal with the hazard potential of CMP slurries. PMID:26549624

  18. Failure modes and effects criticality analysis and accelerated life testing of LEDs for medical applications

    NASA Astrophysics Data System (ADS)

    Sawant, M.; Christou, A.

    2012-12-01

    While use of LEDs in Fiber Optics and lighting applications is common, their use in medical diagnostic applications is not very extensive. Since the precise value of light intensity will be used to interpret patient results, understanding failure modes [1-4] is very important. We used the Failure Modes and Effects Criticality Analysis (FMECA) tool to identify the critical failure modes of the LEDs. FMECA involves identification of various failure modes, their effects on the system (LED optical output in this context), their frequency of occurrence, severity and the criticality of the failure modes. The competing failure modes/mechanisms were degradation of: active layer (where electron-hole recombination occurs to emit light), electrodes (provides electrical contact to the semiconductor chip), Indium Tin Oxide (ITO) surface layer (used to improve current spreading and light extraction), plastic encapsulation (protective polymer layer) and packaging failures (bond wires, heat sink separation). A FMECA table is constructed and the criticality is calculated by estimating the failure effect probability (β), failure mode ratio (α), failure rate (λ) and the operating time. Once the critical failure modes were identified, the next steps were generation of prior time to failure distribution and comparing with our accelerated life test data. To generate the prior distributions, data and results from previous investigations were utilized [5-33] where reliability test results of similar LEDs were reported. From the graphs or tabular data, we extracted the time required for the optical power output to reach 80% of its initial value. This is our failure criterion for the medical diagnostic application. Analysis of published data for different LED materials (AlGaInP, GaN, AlGaAs), the Semiconductor Structures (DH, MQW) and the mode of testing (DC, Pulsed) was carried out. The data was categorized according to the materials system and LED structure such as AlGaInP-DH-DC, Al

  19. Evaluation of Global Anthropogenic Aerosol Indirect Effects in the GISS Model III

    NASA Astrophysics Data System (ADS)

    Chen, W.; Nenes, A.; Liao, H.; Adams, P. J.; Seinfeld, J. H.

    2008-12-01

    In this study the implementation of the aerosol indirect effect in the 23-layer Goddard Institute for Space Studies (GISS) Global Climate Middle Atmosphere Model III is described. Explicit dependence on cloud droplet number concentrations (Nc) is introduced in the calculations of cloud optical depths and autoconversion rates in liquid-phase stratiform clouds to account for both first and second indirect effects. To diagnose Nc, correlation with concentrations of aerosol soluble ions is developed separately for each model grid and in each month, to reflect seasonal and spatial variations in aerosol-cloud interactions. Based on estimates of pre-industrial, present-day (year 2000), and future (year 2100) concentrations of sulfate, nitrate, ammonium, sea salt, and organic aerosols from the fully coupled Caltech unified model, corresponding offline, monthly averaged Nc were derived and applied to equilibrium climate simulations. Modeled present-day global distributions of Nc, droplet size, cloud cover, and radiative balance are in good agreement with satellite-retrieved climatology. A global anthropogenic indirect forcing of -1.7 W m-2, with a decrease in mean droplet radius of 0.8 μm, and an increase in total liquid water path of 0.2 g cm-2, from pre-industrial to year 2000 is estimated. Future climate responses to aerosol direct and indirect effects are also analyzed and compared to previous studies that consider chemistry- aerosol-climate coupling, revealing the influences of this coupling on climate predictions.

  20. The Relative Effects of Explicit Correction and Recasts on Two Target Structures via Two Communication Modes

    ERIC Educational Resources Information Center

    Yilmaz, Yucel

    2012-01-01

    This study investigated the effects of negative feedback type (i.e., explicit correction vs. recasts), communication mode (i.e., face-to-face communication vs. synchronous computer-mediated communication), and target structure salience (i.e., salient vs. nonsalient) on the acquisition of two Turkish morphemes. Forty-eight native speakers of…

  1. Comparative Effects of Two Modes of Computer-Assisted Instructional Package on Solid Geometry Achievement

    ERIC Educational Resources Information Center

    Gambari, Isiaka Amosa; Ezenwa, Victoria Ifeoma; Anyanwu, Romanus Chogozie

    2014-01-01

    The study examined the effects of two modes of computer-assisted instructional package on solid geometry achievement amongst senior secondary school students in Minna, Niger State, Nigeria. Also, the influence of gender on the performance of students exposed to CAI(AT) and CAI(AN) packages were examined. This study adopted a pretest-posttest…

  2. The Mode Effect: A Literature Review of Human and Technological Issues in Computerized Testing

    ERIC Educational Resources Information Center

    Leeson, Heidi V.

    2006-01-01

    In addition to the potential that computer-based testing (CBT) offers, empirical evidence has found that identical computerized and paper-and-pencil tests have not produced equivalent test-taker performance. Referred to as the "mode effect," previous literature has identified many factors that may be responsible for such differential performance.…

  3. Effects of Presentation Mode and Computer Familiarity on Summarization of Extended Texts

    ERIC Educational Resources Information Center

    Yu, Guoxing

    2010-01-01

    Comparability studies on computer- and paper-based reading tests have focused on short texts and selected-response items via almost exclusively statistical modeling of test performance. The psychological effects of presentation mode and computer familiarity on individual students are under-researched. In this study, 157 students read extended…

  4. Cognitive Processing Capacity and Learning-Mode Effects in Prose Learning

    ERIC Educational Resources Information Center

    Furukawa, James M.

    1977-01-01

    High cognitive processing capacity (CPC) students were superior to low-CPC students in prose learning. Of the four learning modes--programmed instruction (PI), control, chunking study outline, and adjunct questions--PI was the most effective. Substantial CPC and performance correlations and poor long-term retention suggested that PI was not best…

  5. The Effect of Different Modes of Task Orientation on Observational Attainment in Practical Chemistry

    ERIC Educational Resources Information Center

    Kempa, R. F.; Ward, J. E.

    1975-01-01

    Examines the effect of three different modes of task orientation on observational attainment in practical chemistry. Results include the overall performance on the chemistry observation test and an analysis of the influence of the complexity of observational tasks on observational attainment. (Author/GS)

  6. The Effects of Frequency, Distribution, Mode of Presentation, and First Language on Learning an Artificial Language

    ERIC Educational Resources Information Center

    Miyata, Munehiko

    2011-01-01

    This dissertation presents results from a series of experiments investigating adult learning of an artificial language and the effects that input frequency (high vs. low token frequency), frequency distribution (skewed vs. balanced), presentation mode (structured vs. scrambled), and first language (English vs. Japanese) have on such learning.…

  7. Effects Of Three-Dimensional Conducting Structures On Resistive Wall Modes

    SciTech Connect

    Villone, Fabio

    2008-11-01

    This paper illustrates the effect of three-dimensional conducting structures on the evolution of Resistive Wall Modes (RWM) occurring in toroidal fusion devices. The CarMa code is used to derive the model, which then is used to design a feedback controller of RWMs. Some examples of application to the ITER geometry are reported.

  8. Learning with Summaries: Effects of Representation Mode and Type of Learning Activity on Comprehension and Transfer

    ERIC Educational Resources Information Center

    Leopold, Claudia; Sumfleth, Elke; Leutner, Detlev

    2013-01-01

    The purpose of the experiment was to examine whether students better understand a science text when they are asked to self-generate summaries or to study predefined summaries. Furthermore, we tested the effects of verbal and pictorial summaries. The experiment followed a 2 x 2 design with representation mode (verbal vs. pictorial) and learning…

  9. The Effects of Communication Mode on Negotiation of Meaning and Its Noticing

    ERIC Educational Resources Information Center

    Yuksel, Dogan; Inan, Banu

    2014-01-01

    This study examined the effects of communication mode ("i.e.", face to face versus computer mediated communication) on the instances of negotiation of meaning (NofM) and its level of noticing by learners. Sixty-four participants (32 dyads) completed two jigsaw tasks in two different mediums (one in each) and four days after the tasks…

  10. HEALTH EFFECTS OF FINE- AND COARSE-MODE PARTICULATE MATTER: EXPOSURES BY INHALATION AND INTRATRACHEAL INSTILLATION

    EPA Science Inventory

    Because coarse mode particles are rarely studied in their existing size ranges (greatest mass about 5-7 micrometers, aerodynamic diameter), the authors investigate the effects of four such particles, quartz, ferric oxide, calcium carbonate, and sodium feldspar, on host defenses a...

  11. EFFECTS OF INTRATRACHEALLY ADMINISTERED COARSE MODE PARTICLES ON RESPIRATORY TRACT INFECTION IN MICE

    EPA Science Inventory

    Because coarse mode particles are rarely studied in their existing size ranges (greatest mass about 5-7 micrometers, aerodynamic diameter), the authors investigated the effects of four such particles, quartz, ferric oxide, calcium carbonate, and sodium feldspar, on host defenses ...

  12. The Effects of Mode and Rate of Presentation on Evaluative Encoding in Children's Memory

    ERIC Educational Resources Information Center

    Douglas, Joan Delahanty; Corsale, Kathleen

    1977-01-01

    The release-from-proactive-inhibition technique was used to assess the effects of mode of presentation and presentation rate on the development of elementary school children's ability to use the evaluative dimension of the Semantic Differential as an encoding device in short-term memory. (Author/JMB)

  13. An Analysis of Mode Effects in the 2010 Course Experience Questionnaire

    ERIC Educational Resources Information Center

    Carroll, David

    2011-01-01

    Historically, responses to the Course Experience Questionnaire (CEQ) were required to be collected by self-administered paper or online questionnaire to be eligible for official analysis. CEQ responses collected by telephone were excluded from the final analysis file to minimise the potential for bias due to mode effects: systematic variation in…

  14. Willingness to Request Help from Others: Effects of Mode of Interaction and Size of Request.

    ERIC Educational Resources Information Center

    Shapiro, E. Gary

    This study investigated the willingness of persons to ask others for help. It examined the effect of modes of interaction (asking for help by letter, phone, or in person) and the size of the request (whether they asked for a small or large favor). The sample consisted of 96 male and female undergraduates in introductory sociology classes. The…

  15. The Effect of Sequential Patterns and Modes of Presentation on the Evaluation of Music Teaching.

    ERIC Educational Resources Information Center

    Yarbrough, Cornelia; And Others

    1994-01-01

    Reports on a study of 614 experienced music teachers, non-music teachers, college-level music students, and non-music students on the effect of sequential patterns and different modes of presentation of music teaching. Finds that experienced teachers' evaluations were significantly higher than those of university students. (CFR)

  16. Effect of surface modes on coupling to fast waves in the LHRF

    SciTech Connect

    Pinsker, R.I.; Colestock, P.L.

    1990-09-16

    The effect of surface modes of propagation on coupling to fast waves in the LHRF is studied theoretically and experimentally. The previously reported up-down' poloidal phasing asymmetry for coupling to a uniform plasma is shown to be due to the properties of a mode which carries energy along the plasma-conducting wall interface. Comparison of the theory with coupling experiments performed on the PLT tokamak with a phased array of twelve dielectric-loaded waveguides at 800 MHz shows that the observed dependence of the net reflection coefficient on toroidal phase angle can be explained only if the surface wave is taken into account. 43 refs., 10 figs.

  17. Effect of finite substrate width on higher-order mode generation of electrically shielded symmetric microstrip

    NASA Astrophysics Data System (ADS)

    Tseng, J.-D.; Tzuang, C.-K. C.

    1992-01-01

    The effect of finite substrate width on the higher-order mode generation of an electrically shielded microstrip is investigated. By employing the full-wave mixed potential mode-matching method the microstrip on a finite-width substrate can be accurately analyzed. The dispersion characteristics of microstrip on two different substrate widths were compared in the frequency range of interest. The results indicated that the use of conventional three-dimensional simulators assuming homogeneous layered (stratified) multi-dielectric substrates may not work well above the first cutoff frequency of microstrip on a finite-width substrate.

  18. Model-OA wind turbine generator - Failure modes and effects analysis

    NASA Technical Reports Server (NTRS)

    Klein, William E.; Lali, Vincent R.

    1990-01-01

    The results failure modes and effects analysis (FMEA) conducted for wind-turbine generators are presented. The FMEA was performed for the functional modes of each system, subsystem, or component. The single-point failures were eliminated for most of the systems. The blade system was the only exception. The qualitative probability of a blade separating was estimated at level D-remote. Many changes were made to the hardware as a result of this analysis. The most significant change was the addition of the safety system. Operational experience and need to improve machine availability have resulted in subsequent changes to the various systems, which are also reflected in this FMEA.

  19. Sludge-Derived Biochar for Arsenic(III) Immobilization: Effects of Solution Chemistry on Sorption Behavior.

    PubMed

    Zhang, Weihua; Zheng, Juan; Zheng, Pingping; Tsang, Daniel C W; Qiu, Rongliang

    2015-07-01

    Recycling sewage sludge by pyrolysis has attracted increasing attention for pollutant removal from wastewater and soils. This study scrutinized As(III) sorption behavior on sludge-derived biochar (SDBC) under different pyrolysis conditions and solution chemistry. The SDBC pyrolyzed at a higher temperature showed a lower As(III) sorption capacity and increasingly nonlinear isotherm due to loss of surface sites and deoxygenation-dehydrogenation. The Langmuir sorption capacity on SDBC (3.08-6.04 mg g) was comparable to other waste-derived sorbents, with the highest As(III) sorption on SDBC pyrolyzed at 400°C for 2 h. The As(III) sorption kinetics best fit with the pseudo-second-order equation, thus suggesting the significance of the availability of surface sites and initial concentration. Sorption of As(III) was faster than that of Cr(VI) but slower than that of Pb(II), which was attributed to their differences in molar volume (correlated to diffusion coefficients) and sorption mechanisms. The X-ray photoelectron spectra revealed an increase of oxide oxygen (O) with a decrease of sorbed water, indicative of ligand exchange with hydroxyl groups on SDBC surfaces. The As(III) sorption was not pH dependent in acidic-neutral range (pH < 8) due to the buffering capacity and surface characteristics of the SDBC; however, sorption was promoted by increasing pH in the alkaline range (pH > 8) because of As(III) speciation in solution. An increasing ionic strength (0.001-0.1 mol L) facilitated As(III) sorption, indicating the predominance of ligand exchange over electrostatic interactions, while high concentrations (0.1 mol L) of competing anions (fluoride, sulfate, carbonate, and phosphate) inhibited As(III) sorption. These results suggest that SDBC is applicable for As(III) immobilization in most environmentally relevant conditions. PMID:26437093

  20. On the interplay effects with proton scanning beams in stage III lung cancer

    SciTech Connect

    Li, Yupeng; Kardar, Laleh; Liao, Li; Lim, Gino; Li, Xiaoqiang; Li, Heng; Zhu, Ronald X.; Sahoo, Narayan; Gillin, Michael; Zhang, Xiaodong; Cao, Wenhua; Chang, Joe Y.; Liao, Zhongxing; Komaki, Ritsuko; Cox, James D.

    2014-02-15

    Purpose: To assess the dosimetric impact of interplay between spot-scanning proton beam and respiratory motion in intensity-modulated proton therapy (IMPT) for stage III lung cancer. Methods: Eleven patients were sampled from 112 patients with stage III nonsmall cell lung cancer to well represent the distribution of 112 patients in terms of target size and motion. Clinical target volumes (CTVs) and planning target volumes (PTVs) were defined according to the authors' clinical protocol. Uniform and realistic breathing patterns were considered along with regular- and hypofractionation scenarios. The dose contributed by a spot was fully calculated on the computed tomography (CT) images corresponding to the respiratory phase that the spot is delivered, and then accumulated to the reference phase of the 4DCT to generate the dynamic dose that provides an estimation of what might be delivered under the influence of interplay effect. The dynamic dose distributions at different numbers of fractions were compared with the corresponding 4D composite dose which is the equally weighted average of the doses, respectively, computed on respiratory phases of a 4DCT image set. Results: Under regular fractionation, the average and maximum differences in CTV coverage between the 4D composite and dynamic doses after delivery of all 35 fractions were no more than 0.2% and 0.9%, respectively. The maximum differences between the two dose distributions for the maximum dose to the spinal cord, heart V40, esophagus V55, and lung V20 were 1.2 Gy, 0.1%, 0.8%, and 0.4%, respectively. Although relatively large differences in single fraction, correlated with small CTVs relative to motions, were observed, the authors' biological response calculations suggested that this interfractional dose variation may have limited biological impact. Assuming a hypofractionation scenario, the differences between the 4D composite and dynamic doses were well confined even for single fraction. Conclusions: Despite

  1. Communication: Effects of thermionic-gun parameters on operating modes in ultrafast electron microscopy.

    PubMed

    Kieft, Erik; Schliep, Karl B; Suri, Pranav K; Flannigan, David J

    2015-09-01

    Ultrafast electron microscopes with thermionic guns and LaB6 sources can be operated in both the nanosecond, single-shot and femtosecond, single-electron modes. This has been demonstrated with conventional Wehnelt electrodes and absent any applied bias. Here, by conducting simulations using the General Particle Tracer code, we define the electron-gun parameter space within which various modes may be optimized. The properties of interest include electron collection efficiency, temporal and energy spreads, and effects of laser-pulse duration incident on the LaB6 source. We find that collection efficiencies can reach 100% for all modes, despite there being no bias applied to the electrode. PMID:26798820

  2. Communication: Effects of thermionic-gun parameters on operating modes in ultrafast electron microscopy

    PubMed Central

    Kieft, Erik; Schliep, Karl B.; Suri, Pranav K.; Flannigan, David J.

    2015-01-01

    Ultrafast electron microscopes with thermionic guns and LaB6 sources can be operated in both the nanosecond, single-shot and femtosecond, single-electron modes. This has been demonstrated with conventional Wehnelt electrodes and absent any applied bias. Here, by conducting simulations using the General Particle Tracer code, we define the electron-gun parameter space within which various modes may be optimized. The properties of interest include electron collection efficiency, temporal and energy spreads, and effects of laser-pulse duration incident on the LaB6 source. We find that collection efficiencies can reach 100% for all modes, despite there being no bias applied to the electrode. PMID:26798820

  3. Jamming effects on code synchronization of burst-mode frequency-hop spread-spectrum

    NASA Astrophysics Data System (ADS)

    van Grouw, Mike G.; Wicker, Mark A.

    The authors characterize the performance of a multiple-dwell FHSS (frequency-hopping spread-spectrum) code synchronization scheme in the presence of channel dynamics. Random hop jamming is assumed. The coarse acquisition system uses both passive and active correlation to implement a serial search of the code-uncertainty region. The in-lock monitoring is accomplished using a two-dwell active correlator with a relatively long integration time. Both burst- and continuous-mode communications links are considered. Appropriate performance parameters are developed, and design considerations are discussed. Performance curves are given for the various cases considered. Although a fixed-threshold multiple-dwell synchronization scheme adequately mitigates the effects of dynamic jamming in a continuous-mode communications link, it is shown to be inadequate for a burst-mode communications link.

  4. The use of failure mode effect and criticality analysis in a medication error subcommittee.

    PubMed

    Williams, E; Talley, R

    1994-04-01

    Failure Mode Effect and Criticality Analysis (FMECA) is the systematic assessment of a process or product that enables one to determine the location and mechanism of potential failures. It has been used by engineers, particularly in the aerospace industry, to identify and prioritize potential failures during product development when there is a lack of data but an abundance of expertise. The Institute for Safe Medication Practices has recommended its use in analyzing the medication administration process in hospitals and in drug product development in the pharamceutical industry. A medication error subcommittee adopted and modified FMECA to identify and prioritize significant failure modes in its specific medication administration process. Based on this analysis, the subcommittee implemented solutions to four of the five highest ranked failure modes. FMECA provided a method for a multidisciplinary group to address the most important medication error concerns based upon the expertise of the group members. It also facilitated consensus building in a group with varied perceptions. PMID:10133462

  5. Rotational Shear Effects on Edge Harmonic Oscillations in DIII-D Quiescent H-mode Discharges

    NASA Astrophysics Data System (ADS)

    Chen, Xi; Burrell, K. H.; Ferraro, N. M.; Osborne, T. H.; Austin, M. E.; Garofalo, A. M.; Groebner, R. J.; Kramer, G. J.; Luhmann, N. C., Jr.; McKee, G. R.; Muscatello, C. M.; Nazikian, R.; Ren, X.; Snyder, P. B.; Solomon, Wm.; Tobias, B. J.; Yan, Z.

    2015-11-01

    In quiescent H-mode (QH) regime, the edge harmonic oscillations (EHO) play an important role in avoiding the transient ELM power fluxes by providing benign and continuous edge particle transport. A detailed theoretical, experimental and modeling comparison has been made of low-n (n <= 5) EHO in DIII-D QH-mode plasmas. The calculated linear eigenmode structure from the extended MHD code M3D-C1 matches closely the coherent EHO properties from external magnetics data and internal measurements using the ECE, BES, ECE-I and MIR diagnostics, as well as the kink/peeling mode properties of the ideal MHD code ELITE. The numerical investigations indicate that the low-n EHO-like solutions from M3D-C1 are destabilized by the toroidal rotational shear while high-n modes are stabilized. This effect is independent of the rotation direction, suggesting that the low-n EHO can be destabilized in principle with rotation in both directions. These modeling results are consistent with experimental observations of the EHO and support the proposed theory of the EHO as a rotational shear driven kink/peeling mode.

  6. Non-Markovian reduced dynamics based upon a hierarchical effective-mode representation

    SciTech Connect

    Burghardt, Irene; Martinazzo, Rocco; Hughes, Keith H.

    2012-10-14

    A reduced dynamics representation is introduced which is tailored to a hierarchical, Mori-chain type representation of a bath of harmonic oscillators which are linearly coupled to a subsystem. We consider a spin-boson system where a single effective mode is constructed so as to absorb all system-environment interactions, while the residual bath modes are coupled bilinearly to the primary mode and among each other. Using a cumulant expansion of the memory kernel, correlation functions for the primary mode are obtained, which can be suitably approximated by truncated chains representing the primary-residual mode interactions. A series of reduced-dimensional bath correlation functions is thus obtained, which can be expressed as Fourier-Laplace transforms of spectral densities that are given in truncated continued-fraction form. For a master equation which is second order in the system-bath coupling, the memory kernel is re-expressed in terms of local-in-time equations involving auxiliary densities and auxiliary operators.

  7. An improved method for risk evaluation in failure modes and effects analysis of CNC lathe

    NASA Astrophysics Data System (ADS)

    Rachieru, N.; Belu, N.; Anghel, D. C.

    2015-11-01

    Failure mode and effects analysis (FMEA) is one of the most popular reliability analysis tools for identifying, assessing and eliminating potential failure modes in a wide range of industries. In general, failure modes in FMEA are evaluated and ranked through the risk priority number (RPN), which is obtained by the multiplication of crisp values of the risk factors, such as the occurrence (O), severity (S), and detection (D) of each failure mode. However, the crisp RPN method has been criticized to have several deficiencies. In this paper, linguistic variables, expressed in Gaussian, trapezoidal or triangular fuzzy numbers, are used to assess the ratings and weights for the risk factors S, O and D. A new risk assessment system based on the fuzzy set theory and fuzzy rule base theory is to be applied to assess and rank risks associated to failure modes that could appear in the functioning of Turn 55 Lathe CNC. Two case studies have been shown to demonstrate the methodology thus developed. It is illustrated a parallel between the results obtained by the traditional method and fuzzy logic for determining the RPNs. The results show that the proposed approach can reduce duplicated RPN numbers and get a more accurate, reasonable risk assessment. As a result, the stability of product and process can be assured.

  8. Theory of magnetoelectric effect in multilayer nanocomposites on a substrate: Resonant bending-mode response

    NASA Astrophysics Data System (ADS)

    Krantz, Matthias C.; Gerken, Martina

    2013-05-01

    Resonant bending-mode magnetoelectric (ME) coefficients of magnetostrictive-piezoelectric multilayer cantilevers are calculated analytically using a model developed for arbitrary multilayers on a substrate. Without quality factor effects the ME coefficient maxima in the four-dimensional parameter space of layer numbers, layer sequences, piezoelectric volume fractions, and substrate thicknesses are found to be essentially constant for nonzero substrate thickness. Global maxima occur for bilayers without substrates. Vanishing magnetoelectric response regions result from voltage cancellation in piezoelectric layers or absence of bending-mode excitation. They are determined by the neutral plane position in the multilayer stack. With Q-factor effects dominated by viscous air damping ME coefficients strongly increase with cantilever thickness primarily due to increasing resonance frequencies. The results yield a layer specific prediction of ME coefficients, resonance frequencies, and Q-factors in arbitrary multilayers and thus distinction of linear-coupling and Q-factor effects from exchange interaction, interface, or nonlinear ME effects.

  9. Correcting Text Production Errors: Isolating the Effects of Writing Mode from Error Span, Input Mode, and Lexicality

    ERIC Educational Resources Information Center

    Leijten, Marielle; Van Waes, Luuk; Ransdell, Sarah

    2010-01-01

    Error analysis involves detecting, diagnosing, and correcting discrepancies between the text produced so far (TPSF) and the writers mental representation of what the text should be. The use of different writing modes, like keyboard-based word processing and speech recognition, causes different type of errors during text production. While many…

  10. The Blazhko Effect and Additional Excited Modes in RR Lyrae Stars

    NASA Astrophysics Data System (ADS)

    Benkő, J. M.; Szabó, R.

    2015-08-01

    Recent photometric space missions, such as CoRoT and Kepler, revealed that many RR Lyrae stars pulsate—beyond their main radial pulsation mode—in low-amplitude modes. Space data seem to indicate a clear trend that, namely, overtone (RRc) stars and modulated fundamental (RRab) RR Lyrae stars ubiquitously show additional modes, while non-Blazhko RRab stars never do. Two Kepler stars (V350 Lyr and KIC 7021124), however, apparently seemed to break this rule: they were classified as non-Blazhko RRab stars showing additional modes. We processed Kepler pixel photometric data of these stars. We detected a small amplitude (but significant) Blazhko effect for both stars by using the resulting light curves and O-C diagrams. This finding strengthens the apparent connection between the Blazhko effect and the excitation of additional modes. In addition, it yields a potential tool for detecting Blazhko stars through the additional frequency patterns, even if we have only short but accurate time series observations. V350 Lyr shows the smallest amplitude multiperiodic Blazhko effect ever detected.

  11. MHD stability of ITER H-mode confinement with pedestal bootstrap current effects taken into account

    NASA Astrophysics Data System (ADS)

    Zheng, L. J.; Kotschenreuther, M. T.; Valanju, P.; Mahajan, S. M.; Hatch, D.; Liu, X.

    2015-11-01

    We have shown that the bootstrap current can have significant effects both on tokamak equilibrium and stability (Nucl. Fusion 53, 063009 (2013)). For ITER H-mode discharges pedestal density is low and consequently bootstrap current is large. We reconstruct numerically ITER equilibria with bootstrap current taken into account. Especially, we have considered a more realistic scenario in which density and temperature profiles can be different. The direct consequence of bootstrap current effects on equilibrium is the modification of local safety factor profile at pedestal. This results in a dramatic change of MHD mode behavior. The stability of ITER numerical equilibria is investigated with AEGIS code. Both low-n and peeling-ballooning modes are investigated. Note that pressure gradient at pedestal is steep. High resolution computation is needed. Since AEGIS code is an adaptive code, it can well handle this problem. Also, the analytical continuation technique based on the Cauchy-Riemann condition of dispersion relation is applied, so that the marginal stability conditions can be determined. Both numerical scheme and results will be presented. The effects of different density and temperature profiles on ITER H-mode discharges will be discussed. This research is supported by U. S. Department of Energy, Office of Fusion Energy Science: Grant No. DE-FG02-04ER-54742.

  12. Effect of phase III cardiac rehabilitation and relaxation on the quality of life in patients with cardiac syndrome X

    PubMed Central

    Feizi, Aram; Ghaderi, Chiman; Dehghani, Mohammad R.; Khalkhali, Hamid R.; Sheikhi, Siamak

    2012-01-01

    Background: Cardiac syndrome X is a relatively common disorder, and still not much is known about the causative factors or its pathophysiology, which makes it difficult to cure. Due to its chronic nature and debilitating symptoms, many patients have significantly reduced quality of life (QOL).The purpose of this study was to assess the impact of phase III cardiac rehabilitation (CR) and relaxation on the QOL of patients. Materials and Methods: This research is a randomized clinical trial study. Forty eligible and consenting women (age 30-65 years) were randomly assigned to four groups. In the first group (n = 11), progressive muscle relaxation (PMR); in the second group (n = 11), phase III CR; and in the third group (n = 11), PMR along with phase III CR were performed for 8 weeks at home. The fourth group (n = 7) was used as the control group. Short form of QOL questionnaire (SF-36) was used for data gathering. Data analysis was performed using χ2, Kruskal-Wallis, and rank sum difference tests. Results: After phase III CR, relaxation, and combination of CR and relaxation, patients demonstrated improved QOL (P < 0.001). The results of post-test multiple comparisons showed that there were statistically significant differences between control and all intervention groups (P < 0.05). There was also statistically significant difference between relaxation and combination of phase III CR and relaxation groups (P < 0.5). Conclusions: An 8-week phase III CR program together with relaxation improved QOL of patients with cardiac syndrome X. We suggest phase III CR program together with relaxation as an effective treatment in these patients. PMID:23922604

  13. Immunotoxic effects of the color additive caramel color III: immune function studies in rats.

    PubMed

    Houben, G F; Penninks, A H; Seinen, W; Vos, J G; Van Loveren, H

    1993-01-01

    Administration of the color additive caramel color III (AC) may cause a reduction in total white blood cell counts in rats due to reduced lymphocyte counts. Beside lymphopenia, several other effects in rat have been described. The effects are caused by the imidazole derivative 2-acetyl-4(5)-(1,2,3,4-tetrahydroxybutyl)imidazole (THI) and occur in rats fed a diet low in vitamin B6. In the present paper, immune function studies on AC and THI with rats fed a diet low, but not deficient in vitamin B6 are presented and discussed. Rats were exposed to 0.4 or 4% AC or to 5.72 ppm THI in drinking water during and for 28 days prior to the start of immune function assays. Resistance to Trichinella spiralis was examined in an oral infection model and clearance of Listeria monocytogenes upon an intravenous infection was studied. In addition, natural cell-mediated cytotoxicity of splenic and nonadherent peritoneal cells and the antibody response to sheep red blood cells were studied. From the results it is concluded that exposure of rats to AC or THI influenced various immune function parameters. Thymus-dependent immunity was suppressed, while parameters of the nonspecific resistance were also affected, as shown by a decreased natural cell-mediated cytotoxicity in the spleen and an enhanced clearance of L. monocytogenes. PMID:8432426

  14. Bismuth(III) deferiprone effectively inhibits growth of Desulfovibrio desulfuricans ATCC 27774.

    PubMed

    Barton, Larry L; Lyle, Daniel A; Ritz, Nathaniel L; Granat, Alex S; Khurshid, Ali N; Kherbik, Nada; Hider, Robert; Lin, Henry C

    2016-04-01

    Sulfate-reducing bacteria have been implicated in inflammatory bowel diseases and ulcerative colitis in humans and there is an interest in inhibiting the growth of these sulfide-producing bacteria. This research explores the use of several chelators of bismuth to determine the most effective chelator to inhibit the growth of sulfate-reducing bacteria. For our studies, Desulfovibrio desulfuricans ATCC 27774 was grown with nitrate as the electron acceptor and chelated bismuth compounds were added to test for inhibition of growth. Varying levels of inhibition were attributed to bismuth chelated with subsalicylate or citrate but the most effective inhibition of growth by D. desulfuricans was with bismuth chelated by deferiprone, 3-hydroxy-1,2-dimethyl-4(1H)-pyridone. Growth of D. desulfuricans was inhibited by 10 μM bismuth as deferiprone:bismuth with either nitrate or sulfate respiration. Our studies indicate deferiprone:bismuth has bacteriostatic activity on D. desulfuricans because the inhibition can be reversed following exposure to 1 mM bismuth for 1 h at 32 °C. We suggest that deferiprone is an appropriate chelator for bismuth to control growth of sulfate-reducing bacteria because deferiprone is relatively nontoxic to animals, including humans, and has been used for many years to bind Fe(III) in the treatment of β-thalassemia. PMID:26896170

  15. Evaluation of antibacterial effect and mode of Coptidis rhizoma by microcalorimetry coupled with chemometric techniques.

    PubMed

    Kong, Weijun; Wang, Jiabo; Xiao, Xiaohe; Chen, Shilin; Yang, Meihua

    2012-01-01

    In this study, the antibacterial effect and mode of Coptidis rhizoma on Escherichia coli was evaluated by microcalorimetry coupled with chemometric techniques. Using an isothermal microcalorimeter, the metabolic profiles of E. coli growth at 37 °C affected by 15 batches of C. rhizoma were measured. Through principal component analysis (PCA) on nine quantitative thermo-kinetic parameters obtained from the metabolic power-time profiles of E. coli, the antibacterial effects of C. rhizoma from various sources could be easily evaluated by analyzing the change of the two main thermo-kinetic parameters, growth rate constant k(2) and maximum heat-output power P(2)(m), in the second exponential phase of E. coli growth. Then, hierarchical clustering analysis (HCA) was carried out on the two parameters to distinguish those C. rhizoma samples in respect to their antibacterial effects. Clear results were obtained to show that all 15 C. rhizoma samples with different antibacterial effects could be successfully grouped in accordance with their origins. Ranked in decreasing order, the antibacterial mode of C. rhizoma samples that were from Sichuan province had the strongest antibacterial effects, followed by samples from Chongqing city and Hubei province. Our results revealed that the developed microcalorimetry with chemometric techniques had the potential perspective for evaluating the effect and mode of Coptidis rhizoma and other Chinese materia medicas. PMID:22059231

  16. An Examination of the Effect of Coach Leadership Behaviors on the Psychosocial Development of Division III College Football Players

    ERIC Educational Resources Information Center

    Williams, Gary P.

    2010-01-01

    This study explores the relationship between student athlete development and coach leadership behaviors in NCAA Division III football players. Three key elements support this study. The first, Thelma Horn's model of coaching effectiveness, provided the framework for the impact of coaching behaviors on student athlete development. The second,…

  17. Ionic Strength Effect on the Rate of Reduction of Hexacyanoferrate (III) by Ascorbic Acid: A Physical Chemistry Laboratory Experiment.

    ERIC Educational Resources Information Center

    Watkins, Kenneth W.; Olson, June A.

    1980-01-01

    Describes a physical chemistry experiment that allows students to test the effect of ionic strength on the rates of a reaction between ions. The reduction of hexacyanoferrate III by ascorbic acid is detailed. Comparisons with the iodine clock reaction are made. (CS)

  18. Talents and Type Iiis: The Effects of the Talents Unlimited Model on Creative Productivity in Gifted Youngsters

    ERIC Educational Resources Information Center

    Newman, Jane L.

    2005-01-01

    This study examined a set of lessons that integrate the Talents Unlimited Model (TU; C. L. Schlichter, 1986) with the 10 steps of completing a Type III activity (J. S. Renzulli & S. M. Reis, 1985) to determine the effects of these lessons on the quality of students' creative products and on the number of students who completed their products.…

  19. High Relaxivity Gd(III)–DNA Gold Nanostars: Investigation of Shape Effects on Proton Relaxation

    PubMed Central

    Rotz, Matthew W.; Culver, Kayla S. B.; Parigi, Giacomo; MacRenaris, Keith W.; Luchinat, Claudio; Odom, Teri W.; Meade, Thomas J.

    2015-01-01

    Gadolinium(III) nanoconjugate contrast agents (CAs) have distinct advantages over their small-molecule counterparts in magnetic resonance imaging. In addition to increased Gd(III) payload, a significant improvement in proton relaxation efficiency, or relaxivity (r1), is often observed. In this work, we describe the synthesis and characterization of a nanoconjugate CA created by covalent attachment of Gd(III) to thiolated DNA (Gd(III)–DNA), followed by surface conjugation onto gold nanostars (DNA–Gd@stars). These conjugates exhibit remarkable r1 with values up to 98 mM−1 s−1. Additionally, DNA–Gd@stars show efficient Gd(III) delivery and biocompatibility in vitro and generate significant contrast enhancement when imaged at 7 T. Using nuclear magnetic relaxation dispersion analysis, we attribute the high performance of the DNA–Gd@stars to an increased contribution of second-sphere relaxivity compared to that of spherical CA equivalents (DNA–Gd@spheres). Importantly, the surface of the gold nanostar contains Gd(III)–DNA in regions of positive, negative, and neutral curvature. We hypothesize that the proton relaxation enhancement observed results from the presence of a unique hydrophilic environment produced by Gd(III)–DNA in these regions, which allows second-sphere water molecules to remain adjacent to Gd(III) ions for up to 10 times longer than diffusion. These results establish that particle shape and second-sphere relaxivity are important considerations in the design of Gd(III) nanoconjugate CAs. PMID:25723190

  20. Interaction of locust apolipophorin III with lipoproteins and phospholipid vesicles: effect of glycosylation.

    PubMed

    Weers, P M; Van Der Horst, D J; Ryan, R O

    2000-03-01

    Apolipophorin III (apoLp-III) from Locusta migratoria is an exchangeable apolipoprotein that binds reversibly to lipoprotein surfaces. The native protein is glycosylated at Asn-18 and Asn-85. Variable attachment of five distinct oligosaccharide moieties at the two glycosylation sites results in molecular weight heterogeneity, as seen by mass spectrometry. The main mass peak of 20,488 Da decreases to 17,583 Da after removal of carbohydrate, indicating that apoLp-III carbohydrate mass is approximately 14% by weight. Deglycosylated apoLp-III induced clearance of dimyristoylphosphatidylcholine and dimyristoylphosphatidylglycerol vesicles at a faster rate than glycosylated apoLp-III. However, in lipoprotein binding assays, in which apoLp-III interacts with surface-localized diacylglycerol, only minor differences in binding were observed. The fluorescence properties of 1-anilinonaphthalene-8-sulfonate were unaffected by the glycosylation state of apoLp-III, indicating that no changes in the relative amount of exposed hydrophobic surface occurred as a result of carbohydrate removal. We propose that glycosyl moieties affect the ability of apoLp-III to transform phospholipid bilayer vesicles into disc-like complexes by steric hindrance. This is due to the requirement that apoLp-III penetrate the bilayer substrate prior to conformational opening of the helix bundle. On the other hand, the glycosyl moieties do not affect lipoprotein binding interactions as it does not involve deep protein penetration into the lipid milieu. Rather, lipoprotein binding is based on oriented protein contact with the lipid surface followed by opening of the helix bundle, which allows formation of a stable interaction with surface exposed hydrophobic sites. PMID:10706589

  1. Effect of aluminum (III) on the conversion of dopachrome in the melanin synthesis pathway

    NASA Astrophysics Data System (ADS)

    Di, Junwei; Bi, Shuping

    2003-06-01

    The effect of aluminum ions on the kinetics and mode of the conversion of dopachrome (DC) in acidic environment has been studied using UV-Vis spectrophotometric and cyclic voltammetric methods. The DC conversion step is an important reaction in melanogenesis. Aluminum ions catalyze greatly the decarboxylative transformation of DC to give 5,6-dihydroxyindole (DHI) rather than 5,6-dihydroxyindole-2-carboxylic acid (DHICA) at pH 5.5, which enhance the ratio of formation DHI/DHICA in melanin synthesis pathway. The kinetics of DC conversion catalyzed by aluminum ions is dependent on the concentration of DC and aluminum ions. These results provide evidence that aluminum ions could play a role in the synthesis of melanin pathway in acidic condition through catalyzing the DC decarboxylative transformation to yield DHI and influence the melanin structure and properties.

  2. Unbiased estimation in seamless phase II/III trials with unequal treatment effect variances and hypothesis-driven selection rules.

    PubMed

    Robertson, David S; Prevost, A Toby; Bowden, Jack

    2016-09-30

    Seamless phase II/III clinical trials offer an efficient way to select an experimental treatment and perform confirmatory analysis within a single trial. However, combining the data from both stages in the final analysis can induce bias into the estimates of treatment effects. Methods for bias adjustment developed thus far have made restrictive assumptions about the design and selection rules followed. In order to address these shortcomings, we apply recent methodological advances to derive the uniformly minimum variance conditionally unbiased estimator for two-stage seamless phase II/III trials. Our framework allows for the precision of the treatment arm estimates to take arbitrary values, can be utilised for all treatments that are taken forward to phase III and is applicable when the decision to select or drop treatment arms is driven by a multiplicity-adjusted hypothesis testing procedure. © 2016 The Authors. Statistics in Medicine Published by John Wiley & Sons Ltd. PMID:27103068

  3. Global Hybrid Simulations of Energetic Particle Effects on the n=1 Mode in Tokamaks: Internal Kink and Fishbone Instability

    SciTech Connect

    G.Y. Fu; W. Park; H.R. Strauss; J. Breslau; J. Chen; S. Jardin; L.E. Sugiyama

    2005-08-09

    Global hybrid simulations of energetic particle effects on the n=1 internal kink mode have been carried out for tokamaks. For the International Thermonuclear Experimental Reactor (ITER) [ITER Physics Basis Editors et al., Nucl. Fusion 39:2137 (1999)], it is shown that alpha particle effects are stabilizing for the internal kink mode. However, the elongation of ITER reduces the stabilization effects significantly. Nonlinear simulations of the precessional drift fishbone instability for circular tokamak plasmas show that the mode saturates due to flattening of the particle distribution function near the resonance region. The mode frequency chirps down rapidly as the flattening region expands radially outward. Fluid nonlinearity reduces the saturation level.

  4. LETTER: Empirical scaling law for the effective heat diffusivity in ELMy H mode plasmas

    NASA Astrophysics Data System (ADS)

    Becker, G.

    1996-04-01

    Predictive code simulations of high density scenarios of ITER and other reactor-grade devices require an experimentally validated scaling relation for the one-fluid effective heat diffusivity chi in the ELMy H mode regime. A comprehensive empirical chi scaling compatible with the ITERH92-P ELMy H mode scaling of the thermal energy confinement time is presented. It follows from a power law ansatz for chi and integration of the single-fluid energy equation and recovers all the exponents of the global confinement law. The numerical factor of the global scaling is used to calibrate the heat diffusivity. The dependences of chi on the temperature and temperature gradient, connected with the power degradation of confinement, are inferred from profile information of a high density H mode discharge. The scaling law obtained is successfully tested against JET, ASDEX and ASDEX Upgrade H mode discharges covering a wide parameter range. It is found to predict the strong rise of the experimental chi profiles with increasing effective radius

  5. Performance improvement through proactive risk assessment: Using failure modes and effects analysis

    PubMed Central

    Yarmohammadian, Mohammad Hossein; Abadi, Tahereh Naseri Boori; Tofighi, Shahram; Esfahani, Sekine Saghaeiannejad

    2014-01-01

    Introduction: Cognizance of any error-prone professional activities has a great impact on the continuity of professional organizations in the competitive atmosphere, particularly in health care industry where every second has critical value in patients’ life saving. Considering invaluable functions of medical record department — as legal document and continuity of health care — “failure mode and effects analysis (FMEA)” utilized to identify the ways a process can fail, and how it can be made safer. Materials and Methods: The structured approach involved assembling a team of experts, employing a trained facilitator, introducing the rating scales and process during team orientation and collectively scoring failure modes. The probability of the failure-effect combination was related to the frequency of occurrence, potential severity, and likelihood of detection before causing any harm to the staff or patients. Frequency, severity and detectability were each given a score from 1 to 10. Risk priority numbers were calculated. Results: In total 56 failure modes were identified and in subsets of Medical Record Department including admission unit dividing emergency, outpatient and inpatient classes, statististic, health data organizing and data processing and Medical Coding units. Although most failure modes were classified as a high risk group, limited resources were, as an impediment to implement recommended actions at the same time. Conclusion: Proactive risk assessment methods, such as FMEA enable health care administrators to identify where and what safeguards are needed to protect against a bad outcome even when an error does occur. PMID:25013821

  6. Heat flux effects on the dispersion relation for geodesic modes in rotating plasmas

    NASA Astrophysics Data System (ADS)

    Duarte, V. N.; Sgalla, R. J. F.; Elfimov, A. G.; Galvão, R. M. O.

    2015-03-01

    The MHD theory of the effect of toroidal and poloidal rotations on the dynamics of Zonal Flows - ZFs and Geodesic Acoustic Modes - GAMs in axisymmetric magnetic confinement configurations is revisited. The MHD model has an arbitrariness regarding the energy conservation equation and previous works on the effect of rotation on ZFs and GAMs adopted an adiabatic law, or other simplifying assumptions, to treat this problem. However, in fusion grade plasmas, the heat transport along the magnetic field lines is rather fast and, therefore, a somewhat more appropriate model is to assume isothermal flux surfaces. This implies to take into account the heat transport equation in the model and, in the presence of rotation, this leads to an increase in the degree of the dispersion relation for these modes, giving rise to a low-frequency third branch of these modes. This has been previously obtained by Elfimov, Galvão and Sgalla [1] employing a model of circular flux surfaces from the outset. In this paper, the theoretical development is generalized by using flux coordinates, following the method of Ilgisonis et al [2]. This allows a better assessment of the applicability of the results and to investigate the relevance of the low frequency mode in non-circular tokamaks. Specific results for the TCABR tokamak are presented.

  7. Effect of stress and temperature on mode of fracture after reheat cracking

    SciTech Connect

    Ferraresi, V.A.; Exaltacao Trevisan, R. da

    1996-12-01

    The phenomenon of stress-relief cracking or reheat cracking can occur in the heat affected zones (HAZ) or weld fillet during Post Weld Heat Treatment (PWHT). The parts of the HAZ most susceptible to reheat cracking are the coarse-grained regions which result from heating at elevated temperatures in the austenitic region. The aim of the research is to study the effect of stress and temperature during PWHT for stress relief on modes of fractures in High Strength Low Alloy (HSLA) steel produced commercially. The Modified Implant Test was applied along with simulation of thermal cycles typically used for stress-relief treatment of welded components. Basically two different modes of fracture have been identified on basis of fracture appearance. For the temperature range of 500 to 600C, under conditions of high and low stresses, a low-ductility intergranular fracture mode (brittle decohesion) was observed and fracture surfaces were characterized by almost featureless facets. At higher temperatures (680 C) and lower stresses, the fractures were slightly more ductile and occurred by creep cavitation on the grain boundaries. Although intergranular, these fractures were basically dimpled due to coalescence of individual creep cavities. Surfaces of fractures were examined by scanning electron microscopy. Tests with varying initial loads and different heat-treatment temperatures were realized in order to render separation of stress and temperature effects. It was observed that fracture mode depends mainly on the temperature level rather than on stress range.

  8. Spin-State Energetics of Fe(III) and Ru(III) Aqua Complexes: Accurate ab Initio Calculations and Evidence for Huge Solvation Effects.

    PubMed

    Radoń, Mariusz; Gąssowska, Katarzyna; Szklarzewicz, Janusz; Broclawik, Ewa

    2016-04-12

    Aqua complexes of transition metals are useful models for understanding the electronic structure of metal-oxide species relevant in photocatalytic water splitting. Moreover, spin-forbidden d-d transitions of aqua complexes provide valuable experimental data of spin-state energetics, which can be used for benchmarking of computational methods. Here, low-energy spin states of Fe(III) and Ru(III) aqua complexes are studied with an array of DFT and high-level wave function methods (CASPT2, RASPT2, NEVPT2, CCSD(T)-F12, and other coupled cluster methods up to full CCSDT). The results from single-reference and multireference methods are cross-checked, and the amount of multireference character for both considered spin states of [Fe(H2O)6](3+) is carefully analyzed. In addition to small [M(H2O)6](3+) clusters (M = Fe, Ru), we also employ larger models [M(H2O)6·(H2O)12](3+), with explicit water molecules in the second coordination sphere, to describe the situation in aqueous solution. By comparing the results for both types of models, our calculations evidence large and systematic solvation effects on the spin-state energetics. It is found that, due to the interaction with hydrogen-bonded water molecules in the second coordination sphere, the first coordination sphere undergoes a noticeable contraction and deformation. In consequence, the presence of solvation shell affects the relative energies of spin states by as much as 3-4 × 10(3) cm(-1) (∼10 kcal/mol). Once this solvation effect is accounted for, the spin-state energetics from CCSD(T) and NEVPT2 calculations turn out to be in an excellent agreement with the experimental estimates, which was not the case for isolated [M(H2O)6](3+) species is gas phase. We thus postulate that significant discrepancies between theory and experimental data for [Fe(H2O)6](3+) that were previously reported in the literature may be plausibly resolved and attributed to the neglect of explicit solvation effects and also, to some extent, to

  9. Effects of electron cyclotron current drive on the evolution of double tearing mode

    SciTech Connect

    Sun, Guanglan Dong, Chunying; Duan, Longfang

    2015-09-15

    The effects of electron cyclotron current drive (ECCD) on the double tearing mode (DTM) in slab geometry are investigated by using two-dimensional compressible magnetohydrodynamics equations. It is found that, mainly, the double tearing mode is suppressed by the emergence of the secondary island, due to the deposition of driven current on the X-point of magnetic island at one rational surface, which forms a new non-complete symmetric magnetic topology structure (defined as a non-complete symmetric structure, NSS). The effects of driven current with different parameters (magnitude, initial time of deposition, duration time, and location of deposition) on the evolution of DTM are analyzed elaborately. The optimal magnitude or optimal deposition duration of driven current is the one which makes the duration of NSS the longest, which depends on the mutual effect between ECCD and the background plasma. Moreover, driven current introduced at the early Sweet-Parker phase has the best suppression effect; and the optimal moment also exists, depending on the duration of the NSS. Finally, the effects varied by the driven current disposition location are studied. It is verified that the favorable location of driven current is the X-point which is completely different from the result of single tearing mode.

  10. Anharmonic effects in the optical and acoustic bending modes of graphene

    NASA Astrophysics Data System (ADS)

    Ramírez, R.; Chacón, E.; Herrero, C. P.

    2016-06-01

    The out-of-plane fluctuations of carbon atoms in a graphene sheet have been studied by means of classical molecular dynamic simulations with an empirical force field as a function of temperature. The Fourier analysis of the out-of-plane fluctuations often applied to characterize the acoustic bending mode of graphene is extended to the optical branch, whose polarization vector is perpendicular to the graphene layer. This observable is inaccessible in a continuous elastic model of graphene but it is readily obtained by the atomistic treatment. Our results suggest that the long-wavelength limit of the acoustic out-of-plane fluctuations of a free layer without stress is qualitatively similar to that predicted by a harmonic model under a tensile stress. This conclusion is a consequence of the anharmonicity of both in-plane and out-of-plane vibrational modes of the lattice. The most striking anharmonic effect is the presence of a linear term, ωA=vAk , in the dispersion relation of the acoustic bending band of graphene at long wavelengths (k →0 ). This term implies a strong reduction of the amplitude of out-of-plane oscillations in comparison to a flexural mode with a k2 dependence in the long-wavelength limit. Our simulations show an increase of the sound velocity associated to the bending mode, as well as an increase of its bending constant, κ , as the temperature increases. Moreover, the frequency of the optical bending mode, ωO(Γ ), also increases with the temperature. Our results are in agreement with recent analytical studies of the bending modes of graphene using either perturbation theory or an adiabatic approximation in the framework of continuous layer models.

  11. Effects of the colour additive caramel colour III on the immune system: a study with human volunteers.

    PubMed

    Houben, G F; Abma, P M; van den Berg, H; van Dokkum, W; van Loveren, H; Penninks, A H; Seinen, W; Spanhaak, S; Vos, J G; Ockhuizen, T

    1992-09-01

    Administration of the colour additive Caramel Colour III to rats has been associated with decreased numbers of lymphocytes and several other changes in the immune system, as well as in immune function parameters, specifically in animals fed a diet with a relatively low vitamin B6 content. The effects are caused by the imidazole derivative 2-acetyl-4(5)-tetrahydroxybutylimidazole (THI). Caramel Colour III is commonly used in food products such as bakery products, soya-bean sauces, brown sauces, gravies, soup aromas, brown (dehydrated) soups, brown malt caramel blend for various applications, vinegars and beers, and effects in humans on dietary intake cannot be excluded. Elderly male volunteers with a marginal deficit in vitamin B6 were considered a relevant and potentially sensitive group to study possible effects of Caramel Colour III on blood lymphocyte numbers (total and within subsets) or on proliferative responses of lymphocytes to mitogenic stimulation. In addition, several other haematological parameters, as well as serum immunoglobulin levels and immunoglobulin production in vitro by pokeweed mitogen-stimulated mononuclear blood cells were studied. The results of this double-blind intervention study demonstrated that in a selected test group of apparently healthy elderly male volunteers with a biochemically marginally deficient vitamin B6 status, Caramel Colour III containing 23 (commercial sample) or 143 (research sample) ppm THI and administered at the level of the current acceptable daily intake of 200 mg/kg body weight/day for 7 days did not affect any of the factors investigated. PMID:1427513

  12. Effects of sediment characteristics on the toxicity of chromium(III) and chromium(VI) to the amphipod, Hyalella azteca

    USGS Publications Warehouse

    Besser, J.M.; Brumbaugh, W.G.; Kemble, N.E.; May, T.W.; Ingersoll, C.G.

    2004-01-01

    We evaluated the influence of sediment characteristics, acid-volatile sulfide (AVS) and organic matter (OM), on the toxicity of chromium (Cr) in freshwater sediments. We conducted chronic (28-42-d) toxicity tests with the amphipod Hyalella azteca exposed to Cr(VI) and Cr(III) in water and in spiked sediments. Waterborne Cr(VI) caused reduced survival of amphipods with a median lethal concentration (LC50) of 40 ??g/L. Cr(VI) spiked into test sediments with differing levels of AVS resulted in graded decreases in AVS and sediment OM. Only Cr(VI)-spiked sediments with low AVS concentrations (<1 ??mol/g) caused significant amphipod mortality. Waterborne Cr(III) concentrations near solubility limits caused decreased survival of amphipods at pH 7 and pH 8 but not at pH 6. Sediments spiked with high levels of Cr(III) did not affect amphipod survival but had minor effects on growth and inconsistent effects on reproduction. Pore waters of some Cr(III)-spiked sediments contained measurable concentrations of Cr(VI), but observed toxic effects did not correspond closely to Cr concentrations in sediment or pore waters. Our results indicate that risks of Cr toxicity are low in freshwater sediments containing substantial concentrations of AVS.

  13. Effect of sodium hexanitrocobaltate (III) decomposition on its staining of intracellular potassium ions.

    PubMed

    Green, D B; Dodge, S M; Lee, J R; Tallman, G

    1990-01-01

    The effect was examined of the chemical decomposition of the potassium stain sodium hexanitrocobaltate (III) (SHC), on its ability to produce stain granules of consistent size that could be used to estimate the K+ contents of stomatal guard cells. Stomata in detached epidermis from leaves of Vicia faba (fava bean) were stimulated to accumulate K+ by treating them with fusicoccin. Stomatal apertures and the fraction of guard cell area covered by K+ precipitate granules (K+ score) were measured by digitizing photographic enlargements, and K+ scores were correlated with the age of stain that had been stored either in open or closed containers. The ability of stain aged in open containers to produce consistent fractional cell coverage was compared to 1) the ability of identically treated stain to precipitate K+ from solutions of KCI, and to 2) the kinetics of decomposition of SHC. It was found that the fractional coverage of guard cells of stomata opened to the same apertures decreased with a first order rate constant of 2.3 x 10(-5)/sec. The mass of precipitate formed by treatment of KCl solutions was unchanged for 2 hr after initial preparation of the SHC, and decreased thereafter with a first order rate constant of 1.0 x 10(-5)/sec. When stored in tightly sealed containers, nearly 100 hr were required for an occasionally opened bottle of SHC to decay to the same efficacy as a solution left open to the air for 8 hr. PMID:1694311

  14. Effective Collision Strengths for Electron Impact Excitation of Inelastic Transitions in S III

    NASA Technical Reports Server (NTRS)

    Tayal, S. S.

    1997-01-01

    We have calculated electron collisional excitation strengths for all electric dipole forbidden, semi-forbidden, and allowed transitions among the lowest 17 LS states 3s(exp 2)3p(exp 2) P-3, D-1, S-1, 3s3p(exp 3)S-5(exp 0), D-3(exp 0), P-3(exp 0), P-1(exp 0), S-3(exp 0), D-1(exp 0), 3S(exp 2)3p3d D-1(exp 0), F-3(exp 0), P-3(exp 0), D-3(exp 0), F-3(exp 0), P-1(exp 0), and 3S(exp 2)3p4S P-3(exp 0), P-l(exp 0) of S III using the R-matrix method. These S m states are represented by fairly extensive configuration-interaction wave functions that yield excited state energies in close agreement with recent laboratory measurements. Rydberg series of resonances converging to the excited state thresholds are explicitly included in the scattering calculation. The effective collision strengths are determined assuming Maxwellian distribution of electron energies. These are listed over a wide temperature range ([0.5-10] x 10(exp 4) K) and compared, where possible, with other available calculations. Subject headings: atomic data - atomic processes

  15. Automated failure mode effects and criticality analyses for reliability prediction of multibody mechanical systems

    NASA Astrophysics Data System (ADS)

    Chiang, Alex Chih-Chien

    Reliability is important to ensure both serviceability and safety of a mechanical system. A method for simulation-based Failure Mode Effects and Criticality Analysis (FMECA) for reliability prediction of mechanical systems is presented. This approach integrates recursive formulation for dynamic analysis, failure criteria for failure determination, graphics techniques for collision detection, and new techniques for modifying dynamics model during the simulation. The automated FMECA method developed consists of three libraries and a graphics collision detection technique. First, a library of mechanical failure modes is created using cause-effect relationships for mechanical failure modes. Second, a library of component failure criteria is constructed by collecting different material test data. Third, a library of simulation algorithms and supporting techniques is built by developing simulation technologies to perform FMECA for mechanical failure modes. In addition, the automated FMECA method uses the developed graphics software VDS for collision detection. Finally, this approach is used to investigate the consequences of four failure modes of a vehicle system. The difficulty in formulating mathematical expressions for a damaged mechanical system is resolved by manipulating the number of cut joint constraints and generalized coordinates to implicitly update the original system topology. Formulations for virtual joints are derived, as well as other new techniques to permit multiple failures during a dynamic simulation. A near-minimum set of generalized coordinates is thus retained throughout the dynamic simulation. Four general-purpose dynamics codes are implemented and effects of four mechanical failure modes of a mechanical system are investigated; suspension failure, joint degradation and breakage, joint stiction, and component yielding and breakage. Failure histories as well as Mean Time Between Failure (MTBF) and Mean Time To Failure (MTTF) are obtained. The

  16. The effect of holes in the dispersion relation of propagative surface plasmon modes of nanoperforated semitransparent metallic films

    SciTech Connect

    Kekesi, R. Meneses-Rodríguez, D.; García-Pérez, F.; González, M. U.; García-Martín, A.; Cebollada, A.; Armelles, G.

    2014-10-07

    We have analysed the effect that holes have on the properties of propagative surface plasmon modes in semitransparent nanoperforated Au films. The modes have been excited in Kretschmann configuration. Contrary to continuous films, where only one mode is excited, two modes are observed in Au nanohole array. The origin of this different behavior is discussed using effective optical properties for the nanoperforated films. The presence of the holes affects the effective optical constants of the membranes in two ways: it changes the contribution of the free electrons, and it gives rise to a localized transition due to a hole induced plasmon resonance. This localized transition interacts with the propagative surface plasmon modes, originating the two detected modes.

  17. Modelling and analytic studies of sheared flow effects on tearing modes

    NASA Astrophysics Data System (ADS)

    Chandra, D.; Thyagaraja, A.; Sen, A.; Ham, C. J.; Hender, T. C.; Hastie, R. J.; Connor, J. W.; Kaw, P.; Mendonca, J.

    2015-05-01

    The effects of flow shear on the stability of a (2,1) tearing mode are examined using numerical and analytic studies on a number of model systems. For a cylindrical reduced magnetohydrodynamic (MHD) model, linear computations using the CUTIE code show that sheared axial flows have a destabilizing effect, while sheared poloidal flows tend to reduce the growth rate of the mode. These effects are independent of the direction of the flow. For helical flows the sign of the shear in the flow matters. This symmetry breaking is also seen in the nonlinear regime where the island saturation level is found to depend on the sign of the flows. In the absence of flow, the CUTIE simulations show that the linear mode is more stable in a two fluid as compared to a single fluid model. However, in the presence of sheared axial flows a negative sheared flow is more destabilizing while a positive sheared flow is more stabilizing, compared to the single fluid model. In contrast to the cylindrical model, simulations in a toroidal model, using the MHD code NEAR, always show a stabilizing effect in the presence of a sheared toroidal flow. This is understood analytically in terms of a flow induced ‘Shafranov’ like shift in the profiles of the equilibrium current that results in a stabilizing change in Δ‧ and the saturated island size.

  18. Design of experiments based variation mode and effect analysis of a conceptual air launched SLV

    NASA Astrophysics Data System (ADS)

    Rafique, Amer Farhan; Zeeshan, Qasim; Kamran, Ali

    2014-12-01

    Conceptual design stage is where the knowledge about the variation in system is still quite vague and herein we intend to analyze and compare various probable design concepts for Air Launched SLV by the use of basic variation mode and effect analysis. In this paper we present a methodology for the Variation Mode and Effect Analysis using Latin Hypercube Sampling based Design of Experiments for the conceptual Air launched Satellite Launch Vehicle. Variations are induced in the Control Variables based on knowledge and experience. The methodology is used to quantify the effect of Noise Factors on the performance of a conceptual Air Launched SLV. The insertion altitude of the Air Launched SLV is the Key Performance Indicator. Preliminary results of the performance and analysis for the simulated experiments are presented here. The performance of the proposed procedure has been tested and, thus, validated by the Air Launched SLV design problem. The Design of Experiment based Variation mode and effect analysis approach is intended for initial conceptual design purposes, thus, providing an immediate insight to the performance of the system in general and quantification of the sensitivity of the key performance indicator in particular, subject to the variations in noise factors prior to the detailed design phase.

  19. Does response mode affect amount recalled or the magnitude of the testing effect?

    PubMed

    Putnam, Adam L; Roediger, Henry L

    2013-01-01

    The testing effect is the finding that retrieval practice can enhance recall on future tests. One unanswered question is whether first-test response mode (writing or speaking the answer) affects final-test performance (and whether final-test response mode itself matters). An additional unsettled issue is whether written and oral recall lead to differences in the amount recalled. In three experiments, we examined these issues: whether subjects can recall more via typing or speaking; whether typing or speaking answers on a first test can lead to better final-test performance (and whether an interaction occurs with final-test response mode) and whether any form of overt response leads to better final-test performance as compared to covert retrieval (thinking of the answer but not producing it). Subjects studied paired associates; took a first test by typing, speaking, or thinking about responses; and then took a second test in which the answers were either spoken or typed. The results revealed few differences between typing and speaking during recall, and no difference in the size of the testing effect on the second test. Furthermore, an initial covert retrieval yielded roughly the same benefit to future test performance as did overt retrieval. Thus, the testing effect was quite robust across these manipulations. The practical implication for learning is that covert retrieval provides as much benefit to later retention as does overt retrieval and that both can be effective study strategies. PMID:22898928

  20. Single-molecule magnetism in a family of {Co(III)2Dy(III)2} butterfly complexes: effects of ligand replacement on the dynamics of magnetic relaxation.

    PubMed

    Langley, Stuart K; Ungur, Liviu; Chilton, Nicholas F; Moubaraki, Boujemaa; Chibotaru, Liviu F; Murray, Keith S

    2014-05-01

    The synthesis and structural characterization of four related heterometallic complexes of formulas [Dy(III)2Co(III)2(OMe)2(teaH)2(O2CPh)4(MeOH)4](NO3)2·MeOH·H2O (1a) and [Dy(III)2Co(III)2(OMe)2(teaH)2(O2CPh)4(MeOH)2(NO3)2]·MeOH·H2O (1b), [Dy(III)2Co(III)2(OMe)2(dea)2(O2CPh)4(MeOH)4](NO3)2 (2), [Dy(III)2Co(III)2(OMe)2(mdea)2(O2CPh)4(NO3)2] (3), and [Dy(III)2Co(III)2(OMe)2(bdea)2(O2CPh)4(MeOH)4](NO3)2·0.5MeOH·H2O (4a) and [Dy(III)2Co(III)2(OMe)2(bdea)2(O2CPh)4(MeOH)2(NO3)2]·MeOH·1.5H2O (4b) are reported (teaH3 = triethanolamine, deaH2 = diethanolamine, mdeaH2 = N-methyldiethanolamine, and bdeaH2 = N-n-butyldiethanolamine). Compounds 1 (≡ 1a and 1b) and 4 (≡ 4a and 4b) both display two unique molecules within the same crystal and all compounds display a butterfly type core, with the Dy(III) ions occupying the central body positions and the diamagnetic Co(III) ions the outer wing-tip sites. Compounds 1-4 were investigated via direct current and alternating current magnetic susceptibility measurements, and it was found that each complex displayed single-molecule magnet (SMM) behavior. All four compounds display unique coordination and geometric environments around the Dy(III) ions and it was found that each displays a different anisotropy barrier. Ab initio calculations were performed on 1-4 and these determined the low lying electronic structure of each Dy(III) ion and the magnetic interactions for each cluster. It was found that there was a strong correlation between the calculated energy gap between the ground and first excited states of the single-ion ligand-field split Dy(III) levels and the experimentally observed anisotropy barrier. Furthermore, the transverse g factors found for the Dy(III) ions, defining the tunnelling rates within the ground Kramers doublets, are largest for 1, which agrees with the experimental observation of the shortest relaxation time in the high-temperature domain for this complex. The magnetic exchange between the Dy(III

  1. TESTING MASS LOSS IN LARGE MAGELLANIC CLOUD CEPHEIDS USING INFRARED AND OPTICAL OBSERVATIONS. II. PREDICTIONS AND TESTS OF THE OGLE-III FUNDAMENTAL-MODE CEPHEIDS

    SciTech Connect

    Neilson, Hilding R.; Ngeow, Chow-Choong; Kanbur, Shashi M.; Lester, John B.

    2010-06-20

    In this paper, we test the hypothesis that Cepheids have infrared excesses due to mass loss. We fit a model using the mass-loss rate and the stellar radius as free parameters to optical observations from the OGLE-III survey and infrared observations from the Two Micron All Sky Survey and SAGE data sets. The sample of Cepheids has predicted minimum mass-loss rates ranging from 0 to 10{sup -8} M{sub sun} yr{sup -1}, where the rates depend on the chosen dust properties. We use the predicted radii to compute the period-radius relation for LMC Cepheids and to estimate the uncertainty caused by the presence of infrared excess for determining angular diameters with the infrared surface brightness technique. Finally, we calculate the linear and nonlinear period-luminosity (P-L) relations for the LMC Cepheids at VIJHK + IRAC wavelengths and find that the P-L relations are consistent with being nonlinear at infrared wavelengths contrary to previous results.

  2. Cancellation of drift kinetic effects between thermal and energetic particles on the resistive wall mode stabilization

    NASA Astrophysics Data System (ADS)

    Guo, S. C.; Liu, Y. Q.; Xu, X. Y.; Wang, Z. R.

    2016-07-01

    Drift kinetic stabilization of the resistive wall mode (RWM) is computationally investigated using MHD-kinetic hybrid code MARS-K following the non-perturbative approach (Liu et al 2008 Phys. Plasmas 15 112503), for both reversed field pinch (RFP) and tokamak plasmas. Toroidal precessional drift resonance effects from trapped energetic ions (EIs) and various kinetic resonances between the mode and the guiding center drift motions of thermal particles are included into the self-consistent toroidal computations. The results show cancellation effects of the drift kinetic damping on the RWM between the thermal particles and EIs contributions, in both RFP and tokamak plasmas, even though each species alone can provide damping and stabilize RWM instability by respective kinetic resonances. The degree of cancellation generally depends on the EIs equilibrium distribution, the particle birth energy, as well as the toroidal flow speed of the plasma.

  3. Thermo-optical effects in Tm-doped large mode area photonic crystal fibers

    NASA Astrophysics Data System (ADS)

    Molardi, Carlo; Coscelli, Enrico; Cucinotta, Annamaria; Selleri, Stefano

    2014-03-01

    Designs of Tm-doped photonic crystal fibers for laser operation must take in account the strong thermo-optical effects due to the Tm quantum defect and the consequent corruption of the single mode guiding properties. A new fiber design with a ˜ 80 μm core diameter, based on the cladding mirror symmetry reduction is proposed and analyzed using a full-vector FEM-based modal solver. The thermal effects are investigated using a computationally efficient model. A large pitch fiber with similar core diameter, which represents the actual state-of-art of Tm-doped laser technology, has been investigated in order to have a basis of comparison. Optimizing some key parameters of the new symmetry free fiber, the possibility to achieve a wide band single mode operation under an heavy heat load of over 300 W/m is demonstrated. In particular a very high modal discrimination value larger than 0.5 is obtained.

  4. Effect of relativistic acceleration on localized two-mode Gaussian quantum states

    NASA Astrophysics Data System (ADS)

    Ahmadi, Mehdi; Lorek, Krzysztof; Checińska, Agata; Smith, Alexander R. H.; Mann, Robert B.; Dragan, Andrzej

    2016-06-01

    We study how an arbitrary Gaussian state of two localized wave packets, prepared in an inertial frame of reference, is described by a pair of uniformly accelerated observers. We explicitly compute the resulting state for arbitrarily chosen proper accelerations of the observers and independently tuned distance between them. To do so, we introduce a generalized Rindler frame of reference and analytically derive the corresponding state transformation as a Gaussian channel. Our approach provides several new insights into the phenomenon of vacuum entanglement such as the highly nontrivial effect of spatial separation between the observers including sudden death of entanglement. We also calculate the fidelity of the two-mode channel for nonvacuum Gaussian states and obtain bounds on classical and quantum capacities of a single-mode channel. Our framework can be directly applied to any continuous variable quantum information protocol in which the effects of acceleration or gravity cannot be neglected.

  5. Linear stability of the tearing mode with two-fluid and curvature effects in tokamaks

    SciTech Connect

    Meshcheriakov, Dmytro; Maget, Patrick; Garbet, Xavier; Luetjens, Hinrich; Beyer, Peter

    2012-09-15

    Curvature and diamagnetic effects are both recognized to have a stabilizing influence on tearing modes in the linear regime. In this paper, we investigate the impact of these effects on the linear stability of a (2, 1) magnetic island using non-linear two-fluid MHD simulations and we apply our results to Tore Supra experiments where its stability is not well understood from the single fluid MHD model. Simulations show an initial increase of the linear growth rate and then its reduction until full stability as diamagnetic frequency increases. This mechanism is therefore a plausible explanation for experimental observations where the (2, 1) mode was not observed although the single fluid model predicted its growth. Our simulations also show the importance of curvature for an efficient stabilization. A simple analytical model is derived to support the numerical results.

  6. Spectral analysis of Hall-effect thruster plasma oscillations based on the empirical mode decomposition

    SciTech Connect

    Kurzyna, J.; Mazouffre, S.; Lazurenko, A.; Albarede, L.; Bonhomme, G.; Makowski, K.; Dudeck, M.; Peradzynski, Z.

    2005-12-15

    Hall-effect thruster plasma oscillations recorded by means of probes located at the channel exit are analyzed using the empirical mode decomposition (EMD) method. This self-adaptive technique permits to decompose a nonstationary signal into a set of intrinsic modes, and acts as a very efficient filter allowing to separate contributions of different underlying physical mechanisms. Applying the Hilbert transform to the whole set of modes allows to identify peculiar events and to assign them a range of instantaneous frequency and power. In addition to 25 kHz breathing-type oscillations which are unambiguously identified, the EMD approach confirms the existence of oscillations with instantaneous frequencies in the range of 100-500 kHz typical for ion transit-time oscillations. Modeling of high-frequency modes ({nu}{approx}10 MHz) resulting from EMD of measured wave forms supports the idea that high-frequency plasma oscillations originate from electron-density perturbations propagating azimuthally with the electron drift velocity.

  7. Effect of Temperature Gradient Direction in the Catalyst Nanoparticle on CNTs Growth Mode

    NASA Astrophysics Data System (ADS)

    Lo, An-Ya; Liu, Shang-Bin; Kuo, Cheng-Tzu

    2010-09-01

    To improve the understanding on CNT growth modes, the various processes, including thermal CVD, MP-CVD and ECR-CVD, have been used to deposit CNTs on nanoporous SBA-15 and Si wafer substrates with C2H2 and H2 as reaction gases. The experiments to vary process parameter of Δ T, defined as the vector quantities of temperature at catalyst top minus it at catalyst bottom, were carried out to demonstrate its effect on the CNT growth mode. The TEM and TGA analyses were used to characterize their growth modes and carbon yields of the processes. The results show that Δ T can be used to monitor the temperature gradient direction across the catalyst nanoparticle during the growth stage of CNTs. The results also indicate that the tip-growth CNTs, base-growth CNTs and onion-like carbon are generally fabricated under conditions of Δ T > 0, <0 and ~0, respectively. Our proposed growth mechanisms can be successfully adopted to explain why the base- and tip-growth CNTs are common in thermal CVD and plasma-enhanced CVD processes, respectively. Furthermore, our experiments have also successfully demonstrated the possibility to vary Δ T to obtain the desired growth mode of CNTs by thermal or plasma-enhanced CVD systems for different applications.

  8. Equivalent circuit effects on mode transitions in H{sub 2} inductively coupled plasmas

    SciTech Connect

    Xu, Hui-Jing; Zhao, Shu-Xia Zhang, Yu-Ru; Gao, Fei; Li, Xue-Chun; Wang, You-Nian

    2015-04-15

    It is well known experimentally that the circuit matching network plays an important role in the mode transition behavior of inductively coupled plasmas. To date, however, there have been no reports of numerical models being used to study the role of the matching circuit in the transition process. In this paper, a new two-dimensional self-consistent fluid model that couples the components of an equivalent circuit module is developed to investigate the effects of the equivalent circuit on the mode transition characteristics of an inductively coupled, hydrogen plasma. The equivalent circuit consists of a current source, impedance matching network, reactor impedance, and plasma transferred impedance. The nonlinear coupling of the external circuit with the internal plasma is investigated by adjusting the matching capacitance at a fixed input current. The electron density and temperature as well as the electromagnetic fields all change suddenly, and the E to H mode transition occurs abruptly at a certain matching capacitance as the impedance matching of the external circuit is varied. We also analyze the fields and the plasma characteristics during the transition process, especially for the case of the capacitive E mode.

  9. Long-wavelength asymptotics of unstable crossflow modes, including the effect of surface curvature

    NASA Technical Reports Server (NTRS)

    Choudhari, Meelan

    1994-01-01

    Stationary vortex instabilities with wavelengths significantly larger than the thickness of the underlying three-dimensional boundary layer are studied with asymptotic methods. The long-wavelength Rayleigh modes are locally neutral and are aligned with the direction of the local inviscid streamline. For a spanwise wave number Beta much less than 1, the spatial growth rate of these vortices is O(Beta(exp 3/2)). When Beta becomes O(R(exp -1/7)), the viscous correction associated with a thin sublayer near the surface modifies the inviscid growth rate to the leading order. As Beta is further decreased through this regime, viscous effects assume greater significance and dominate the growth-rate behavior. The spatial growth rate becomes comparable to the real part of the wave number when Beta = O(R(exp -1/4)). At this stage, the disturbance structure becomes fully viscous-inviscid interactive and is described by the triple-deck theory. For even smaller values of Beta, the vortex modes become nearly neutral again and align themselves with the direction of the wall-shear stress. Thus, the study explains the progression of the crossflow-vortex structure from the inflectional upper branch mode to nearly neutral long-wavelength modes that are aligned with the wall-shear direction.

  10. Effect of Temperature Gradient Direction in the Catalyst Nanoparticle on CNTs Growth Mode

    PubMed Central

    2010-01-01

    To improve the understanding on CNT growth modes, the various processes, including thermal CVD, MP-CVD and ECR-CVD, have been used to deposit CNTs on nanoporous SBA-15 and Si wafer substrates with C2H2 and H2 as reaction gases. The experiments to vary process parameter of ΔT, defined as the vector quantities of temperature at catalyst top minus it at catalyst bottom, were carried out to demonstrate its effect on the CNT growth mode. The TEM and TGA analyses were used to characterize their growth modes and carbon yields of the processes. The results show that ΔT can be used to monitor the temperature gradient direction across the catalyst nanoparticle during the growth stage of CNTs. The results also indicate that the tip-growth CNTs, base-growth CNTs and onion-like carbon are generally fabricated under conditions of ΔT > 0, <0 and ~0, respectively. Our proposed growth mechanisms can be successfully adopted to explain why the base- and tip-growth CNTs are common in thermal CVD and plasma-enhanced CVD processes, respectively. Furthermore, our experiments have also successfully demonstrated the possibility to vary ΔT to obtain the desired growth mode of CNTs by thermal or plasma-enhanced CVD systems for different applications. PMID:20730080

  11. Radiation effects in III-V semiconductors and heterojunction bipolar transistors

    NASA Astrophysics Data System (ADS)

    Shatalov, Alexei

    The electron, gamma and neutron radiation degradation of III-V semiconductors and heterojunction bipolar transistors (HBTs) is investigated in this thesis. Particular attention is paid to InP and InGaAs materials and InP/InGaAs abrupt single HBTs (SHBTs). Complete process sequences for fabrication of InP/ InGaAs HBTs are developed and subsequently employed to produce the devices, which are then electrically characterized and irradiated with the different types of radiation. A comprehensive analytical HBT model is developed and radiation damage calculations are performed to model the observed radiation-induced degradation of SHBTs. The most pronounced radiation effects found in SHBTs include reduction of the common-emitter DC current gain, shift of the collector-emitter (CE) offset voltage and increase of the emitter, base and collector parasitic resistances. Quantitative analysis performed using the developed model demonstrates that increase of the neutral bulk and base-emitter (BE) space charge region (SCR) components of the base current are responsible for the observed current gain degradation. The rise of the neutral bulk recombination is attributed to decrease in a Shockley-Read-Hall (SRH) carrier lifetime, while the SCR current increase is caused by rising SCR SRH recombination and activation of a tunneling-recombination mechanism. On the material level these effects are explained by displacement defects produced in a semiconductor by the incident radiation. The second primary change of the SHBT characteristics, CE offset voltage shift, is induced by degradation of the base- collector (BC) junction. The observed rise of the BC current is brought on by diffusion and recombination currents which increase as more defects are introduced in a semiconductor. Finally, the resistance degradation is attributed to deterioration of low-doped layers of a transistor, and to degradation of the device metal contacts.

  12. ACRIM III

    Atmospheric Science Data Center

    2015-12-30

    ACRIM III Data and Information Active Cavity Radiometer Irradiance ... the ACRIMSAT spacecraft on December 20, 1999. ACRIM III data are reprocessed every 90 days to utilize instrument recalibration.   ... ACRIM III Instrument Team Page ACRIM II Data Sets SCAR-B Block:  SCAR-B Products ...

  13. Field and dilution effects on the magnetic relaxation behaviours of a 1D dysprosium(iii)-carboxylate chain built from chiral ligands.

    PubMed

    Han, Tian; Leng, Ji-Dong; Ding, You-Song; Wang, Yanyan; Zheng, Zhiping; Zheng, Yan-Zhen

    2015-08-14

    A one-dimensional dysprosium(iii)-carboxylate chain in which the Dy(III) ions sit in a pseudo D(2d)-symmetry environment is synthesized and shows different slow magnetic relaxation behaviours depending on the field and dilution effects. Besides, the chiral ligand introduces the additional functions of the Cotton effect and polarization for this compound. PMID:26159885

  14. Effect of the oral contraceptive pill on protein S and antithrombin-III levels in Malaysian women.

    PubMed

    Wong, K K; Ng, S C; Koong, P L

    Studies focusing on the relationship between oral contraceptive (OC) usage and occurrence of thromboembolism have been conducted for over 3 decades. Those studies centered on the effects OC use has on blood proteins and on measurable physiological changes that occurred in women with venous thrombosis. This article reports the findings of a study that investigated the effects of OC use on the levels of the anticoagulants antithrombin-III (AT-III), protein C (PC), and protein S (PS) in a group of Asian women. Previous studies had mostly been based on Caucasian women. Of the 21 women studied, 16 were Malaysian, 3 were Chinese, and 2 were Indian. Low-dose OCs containing 30 mcg of ethinyl estradiol and 150 mcg of either desogestrel or levonorgestrel were used. Blood was tested before OC use and 3 and 6 months after starting OC use. Levels of AT-III and PS were measured using the Laurell rocket immunoelectrophoresis technique. Statistical analysis was performed using the paired Student's t-test and an analysis of variance test. No statistically significant differences were found for the mean levels of AT-III and total PS when comparing the pre-OC with the 3- and 6-month post-OC values. Earlier studies based mostly on Caucasian women have reported lower levels of both total PS and free PS in OC users. PMID:12288974

  15. Photodegradation of parabens by Fe(III)-citrate complexes at circumneutral pH: matrix effect and reaction mechanism.

    PubMed

    Feng, Xiaonan; Chen, Yong; Fang, Yuan; Wang, Xiaoyue; Wang, Zongping; Tao, Tao; Zuo, Yuegang

    2014-02-15

    The photodegradation of four parabens including methyl-, ethyl-, propyl-, and butyl-paraben in the presence of Fe(III)-citrate complexes under simulated sunlight was investigated. The degradation of parabens increased with decreasing pH within the range of 5.0-8.0 at the Fe(III)-to-citrate ratio of 10:150 (μM). The addition of low-molecular-weight carboxylic acids showed different effects on the photodegradation of methylparaben. The low-photoreactive carboxylic acids inhibited the photodegradation of methylparaben in the order of formic acid>succinic acid>acetic acid>malonic acid. In contrast, oxalic acid enhanced the photodegradation and exhibited appreciable synergistic effect with Fe(III)-citrate at concentration higher than 500 μM. Up to 99.0% of substrate was degraded after 30 min at pH6.0 in the Fe(III)-citrate-oxalate system. The various fractions of fulvic acid inhibited the photodegradation of methylparaben. The inhibition increased with increasing nominal molecular weight of fractionated fulvic acid. Moreover, the photodegradation of methylparaben was inhibited in natural waters in the order of Liangzi Lake

  16. Band structure effects on resonant tunneling in III-V quantum wells versus two-dimensional vertical heterostructures

    NASA Astrophysics Data System (ADS)

    Campbell, Philip M.; Tarasov, Alexey; Joiner, Corey A.; Ready, W. Jud; Vogel, Eric M.

    2016-01-01

    Since the invention of the Esaki diode, resonant tunneling devices have been of interest for applications including multi-valued logic and communication systems. These devices are characterized by the presence of negative differential resistance in the current-voltage characteristic, resulting from lateral momentum conservation during the tunneling process. While a large amount of research has focused on III-V material systems, such as the GaAs/AlGaAs system, for resonant tunneling devices, poor device performance and device-to-device variability have limited widespread adoption. Recently, the symmetric field-effect transistor (symFET) was proposed as a resonant tunneling device incorporating symmetric 2-D materials, such as transition metal dichalcogenides (TMDs), separated by an interlayer barrier, such as hexagonal boron-nitride. The achievable peak-to-valley ratio for TMD symFETs has been predicted to be higher than has been observed for III-V resonant tunneling devices. This work examines the effect that band structure differences between III-V devices and TMDs has on device performance. It is shown that tunneling between the quantized subbands in III-V devices increases the valley current and decreases device performance, while the interlayer barrier height has a negligible impact on performance for barrier heights greater than approximately 0.5 eV.

  17. Risk assessment of the emergency processes: Healthcare failure mode and effect analysis

    PubMed Central

    Taleghani, Yasamin Molavi; Rezaei, Fatemeh; Sheikhbardsiri, Hojat

    2016-01-01

    BACKGROUND: Ensuring about the patient’s safety is the first vital step in improving the quality of care and the emergency ward is known as a high-risk area in treatment health care. The present study was conducted to evaluate the selected risk processes of emergency surgery department of a treatment-educational Qaem center in Mashhad by using analysis method of the conditions and failure effects in health care. METHODS: In this study, in combination (qualitative action research and quantitative cross-sectional), failure modes and effects of 5 high-risk procedures of the emergency surgery department were identified and analyzed according to Healthcare Failure Mode and Effects Analysis (HFMEA). To classify the failure modes from the “nursing errors in clinical management model (NECM)”, the classification of the effective causes of error from “Eindhoven model” and determination of the strategies to improve from the “theory of solving problem by an inventive method” were used. To analyze the quantitative data of descriptive statistics (total points) and to analyze the qualitative data, content analysis and agreement of comments of the members were used. RESULTS: In 5 selected processes by “voting method using rating”, 23 steps, 61 sub-processes and 217 potential failure modes were identified by HFMEA. 25 (11.5%) failure modes as the high risk errors were detected and transferred to the decision tree. The most and the least failure modes were placed in the categories of care errors (54.7%) and knowledge and skill (9.5%), respectively. Also, 29.4% of preventive measures were in the category of human resource management strategy. CONCLUSION: “Revision and re-engineering of processes”, “continuous monitoring of the works”, “preparation and revision of operating procedures and policies”, “developing the criteria for evaluating the performance of the personnel”, “designing a suitable educational content for needs of employee”,

  18. Effects due to nonlinear modification of driven current on tearing mode stabilization

    NASA Astrophysics Data System (ADS)

    Dong, Ge; Reiman, Allan; Fisch, Nathaniel

    2015-11-01

    Neoclassical tearing modes (NTMs) can be destabilized by a helical perturbation in the boostrap current, and can result in large magnetic islands which are detrimental to confinement in toroidal plasma devices. NTM stability properties and dynamics can be strongly affected by current drive in various scenarios. The modified Rutherford equation is generally used to calculate the contributions from the current drive, without considering the self- consistent change in the driven current associated with the nonlinear effects. In this study, we evaluated the importance of such nonlinear effects as the effect of the change in Te on the current drive efficiency, and the nonlinear interaction of the current drive and the electric field.

  19. Effect of water vapor on the performance of glass RPCs in avalanche mode operation

    NASA Astrophysics Data System (ADS)

    Raveendrababu, K.; Behera, P. K.; Satyanarayana, B.; Mukhopadhayay, S.; Majumdar, N.

    2016-08-01

    We studied the effect of water vapor on the performance of glass Resistive Plate Chambers (RPCs) in the avalanche mode operation. Controlled amount of water vapor was added to the RPC gas mixture that has C2H2F4 as the major component. The deterioration in the performance of RPC was observed while operating with the wet gas and recovered after switching to the standard gas.

  20. Polarization mode coupling and related effects in fiber Bragg grating inscribed in polarization maintaining fiber.

    PubMed

    Zhao, Yanshuang; Sun, Bo; Liu, Yanlei; Ren, Jing; Zhang, Jianzhong; Yang, Jun; Canning, John; Peng, G D; Yuan, Libo

    2016-01-11

    Polarization mode coupling (PMC) and related effects from writing fiber Bragg gratings in polarization maintaining fiber (FBGs-in-PMF) are observed experimentally for the first time by optical fiber coherence domain polarimetry (OCDP) using a broadband light source. PMC is another useful aspect of FBG-in-PMF besides Bragg wavelength and its possible potential is evaluated and discussed. A localized and long range temperature measurement based on the PMC and Bragg wavelength is given as an example. PMID:26832291

  1. Using causal reasoning for automated failure modes and effects analysis (FMEA)

    NASA Astrophysics Data System (ADS)

    Bell, Daniel; Cox, Lisa; Jackson, Steve; Schaefer, Phil

    The authors have developed a tool that automates the reasoning portion of a failure modes and effects analysis (FMEA). It is built around a flexible causal reasoning module that has been adapted to the FMEA procedure. The approach and software architecture have been proven. A prototype tool has been created and successfully passed a test and evaluation program. The authors are expanding the operational capability and adapting the tool to various CAD/CAE (computer-aided design and engineering) platforms.

  2. Preliminary Failure Modes and Effects Analysis of the US Massive Gas Injection Disruption Mitigation System Design

    SciTech Connect

    Lee C. Cadwallader

    2013-10-01

    This report presents the results of a preliminary failure modes and effects analysis (FMEA) of a candidate design for the ITER Disruption Mitigation System. This candidate is the Massive Gas Injection System that provides machine protection in a plasma disruption event. The FMEA was quantified with “generic” component failure rate data as well as some data calculated from operating facilities, and the failure events were ranked for their criticality to system operation.

  3. Preliminary Failure Modes and Effects Analysis of the US DCLL Test Blanket Module

    SciTech Connect

    Lee C. Cadwallader

    2007-08-01

    This report presents the results of a preliminary failure modes and effects analysis (FMEA) of a small tritium-breeding test blanket module design for the International Thermonuclear Experimental Reactor. The FMEA was quantified with “generic” component failure rate data, and the failure events are binned into postulated initiating event families and frequency categories for safety assessment. An appendix to this report contains repair time data to support an occupational radiation exposure assessment for test blanket module maintenance.

  4. Preliminary Failure Modes and Effects Analysis of the US DCLL Test Blanket Module

    SciTech Connect

    Lee C. Cadwallader

    2010-06-01

    This report presents the results of a preliminary failure modes and effects analysis (FMEA) of a small tritium-breeding test blanket module design for the International Thermonuclear Experimental Reactor. The FMEA was quantified with “generic” component failure rate data, and the failure events are binned into postulated initiating event families and frequency categories for safety assessment. An appendix to this report contains repair time data to support an occupational radiation exposure assessment for test blanket module maintenance.

  5. The effect of periodic wavy profile on suppressing window multipactor under arbitrary electromagnetic mode

    SciTech Connect

    Chang, C.; Liu, Y. S.; Chen, C. H.; Guo, L. T.; Li, S.; Wu, X. L.; Verboncoeur, J.

    2015-01-05

    The three-dimensional periodic ripple profile with each unit of rotational symmetric surface is proposed to suppress multipactor for arbitrary electromagnetic mode with any polarization. The field distribution and multipactor electron dynamics on the wavy surface are studied to illustrate the multipactor inhibition mechanism. High power microwave experiment was conducted to demonstrate the effect of wavy surface on significantly improving the window power capacity.

  6. Understanding the effect of resonant magnetic perturbations on tearing mode dynamics

    SciTech Connect

    Hu, Qiming; Rao, Bo; Ding, Yonghua; Zhuang, Ge; Jin, Wei; Hu, Xiwei; Yu, Q.

    2013-09-15

    Numerical understandings of the effect of resonant magnetic perturbations (RMPs) on 2/1 tearing mode (TM) dynamics observed on J-TEXT tokamak (Hu et al. Nucl. Fusion 52, 083011 (2012)) are presented in this paper. The non-uniform mode rotation frequency, modulated by electromagnetic force (F{sub em}) and viscous force (F{sub vs}), results in the applied RMPs contributing both net stabilizing and braking effect on TM. Numerical evaluation based on analytical theory shows the applied RMP contributes a dominant stabilizing effect, which is responsible for the suppression of TM. The dynamics of the first discovered small locked island are investigated. It is found that the island is locked at the stabilizing phase and the saturated island width is less than the linear layer width. The simulated Mirnov signal indicates the small locked island is likely to be the complete suppression case observed in experiments. Associated with the application of RMP, the shape of Mirnov signal deviates from sinusoidal before mode locking, which is explained by numerical modeling. The comparisons between the numerical and experimental results are in good agreement phenomenally.

  7. Failure mode and effects analysis using intuitionistic fuzzy hybrid weighted Euclidean distance operator

    NASA Astrophysics Data System (ADS)

    Liu, Hu-Chen; Liu, Long; Li, Ping

    2014-10-01

    Failure mode and effects analysis (FMEA) has shown its effectiveness in examining potential failures in products, process, designs or services and has been extensively used for safety and reliability analysis in a wide range of industries. However, its approach to prioritise failure modes through a crisp risk priority number (RPN) has been criticised as having several shortcomings. The aim of this paper is to develop an efficient and comprehensive risk assessment methodology using intuitionistic fuzzy hybrid weighted Euclidean distance (IFHWED) operator to overcome the limitations and improve the effectiveness of the traditional FMEA. The diversified and uncertain assessments given by FMEA team members are treated as linguistic terms expressed in intuitionistic fuzzy numbers (IFNs). Intuitionistic fuzzy weighted averaging (IFWA) operator is used to aggregate the FMEA team members' individual assessments into a group assessment. IFHWED operator is applied thereafter to the prioritisation and selection of failure modes. Particularly, both subjective and objective weights of risk factors are considered during the risk evaluation process. A numerical example for risk assessment is given to illustrate the proposed method finally.

  8. Failure mode and effects analysis of witnessing protocols for ensuring traceability during IVF.

    PubMed

    Rienzi, Laura; Bariani, Fiorenza; Dalla Zorza, Michela; Romano, Stefania; Scarica, Catello; Maggiulli, Roberta; Nanni Costa, Alessandro; Ubaldi, Filippo Maria

    2015-10-01

    Traceability of cells during IVF is a fundamental aspect of treatment, and involves witnessing protocols. Failure mode and effects analysis (FMEA) is a method of identifying real or potential breakdowns in processes, and allows strategies to mitigate risks to be developed. To examine the risks associated with witnessing protocols, an FMEA was carried out in a busy IVF centre, before and after implementation of an electronic witnessing system (EWS). A multidisciplinary team was formed and moderated by human factors specialists. Possible causes of failures, and their potential effects, were identified and risk priority number (RPN) for each failure calculated. A second FMEA analysis was carried out after implementation of an EWS. The IVF team identified seven main process phases, 19 associated process steps and 32 possible failure modes. The highest RPN was 30, confirming the relatively low risk that mismatches may occur in IVF when a manual witnessing system is used. The introduction of the EWS allowed a reduction in the moderate-risk failure mode by two-thirds (highest RPN = 10). In our experience, FMEA is effective in supporting multidisciplinary IVF groups to understand the witnessing process, identifying critical steps and planning changes in practice to enable safety to be enhanced. PMID:26292780

  9. Impurity Effects on Caroli-de Gennes-Matricon Mode in Vortex Core in Superconductors

    NASA Astrophysics Data System (ADS)

    Masaki, Yusuke; Kato, Yusuke

    2016-01-01

    We have developed a scheme of Gor'kov Green's functions to treat the impurity effects on the Caroli-de Gennes-Matricon (CdGM) mode in superconductors (SCs) by improving the Kopnin-Kravtsov scheme with respect to the coherence factors and applicability to various SCs. We can study the impurity effects while keeping the discreteness of the energy spectrum, in contrast to the quasiclassical theory. We can thus apply this scheme to SCs with a small quasiclassical parameter kFξ0 (which is the product of the Fermi wavenumber kF and the coherence length ξ0 in a pure SC at zero temperature) and/or in the superclean regime Δ miniτ ≫ 1 (Δmini and τ denote, respectively, the level spacing of the CdGM mode called the minigap and the relaxation time for the CdGM mode and we take ħ = 1). We investigate the impurity effects as a white noise for a vortex in an s-wave SC and two types of vortex in a chiral p-wave SC for various values of the quasiclassical parameter and impurity strength (from the moderately clean regime to the superclean regime) and confirm the validity of this scheme.

  10. An Investigation of Effective Discharge for Suspended Sediment by Level III Ecoregion

    NASA Astrophysics Data System (ADS)

    Heins, A.; Simon, A.

    2002-12-01

    for seven ecoregions: Coast Range (1) Sierra Nevada (5), Snake River Basin (12), Arizona-New Mexico Plateau (22), Flint Hills (28), Central Irregular Plains (40) and the Mississippi Valley Loess Plains (74). Mean daily flow data for a substantial period of record were divided into 33 logarithmic classes and the percentage occurrence of each of these was computed. The total annual suspended sediment transport was then calculated for each class, using suspended-sediment rating equations generated through regression of instantaneous discharge and suspended sediment concentration historic sample data. The geometric midpoint of the class transporting the greatest annual sediment load was considered to be the effective discharge. Results to date demonstrate in environments as diverse the Sierra Nevada Mountains and the Mississippi Valley Loess Plains, the effective discharge for suspended sediment is close to the 1.5 year flow. In the former ecoregion, the mean recurrence interval of suspended sediment effective discharge was 1.526 years. The eventual aim of this project is to calculate effective discharges for all 2929 USGS gaging stations with sufficient instantaneous suspended sediment and associated discharges measurements. These sites cover all 84 level III ecoregions, permitting environmental and geographic patterns of effective discharge recurrence interval. Calculations will be repeated using higher temporal resolution (15 minute) flow data.

  11. Ion wake field effects on the dust-ion-acoustic surface mode in a semi-bounded Lorentzian dusty plasma

    NASA Astrophysics Data System (ADS)

    Lee, Myoung-Jae; Jung, Young-Dae

    2016-03-01

    The dispersion relation for the dust ion-acoustic surface waves propagating at the interface of semi-bounded Lorentzian dusty plasma with supersonic ion flow has been kinetically derived to investigate the nonthermal property and the ion wake field effect. We found that the supersonic ion flow creates the upper and the lower modes. The increase in the nonthermal particles decreases the wave frequency for the upper mode whereas it increases the frequency for the lower mode. The increase in the supersonic ion flow velocity is found to enhance the wave frequency for both modes. We also found that the increase in nonthermal plasmas is found to enhance the group velocity of the upper mode. However, the nonthermal particles suppress the lower mode group velocity. The nonthermal effects on the group velocity will be reduced in the limit of small or large wavelength limit.

  12. Modeling the Effect of Multiple Matrix Cracking Modes on Cyclic Hysteresis Loops of 2D Woven Ceramic-Matrix Composites

    NASA Astrophysics Data System (ADS)

    Longbiao, Li

    2016-08-01

    In this paper, the effect of multiple matrix cracking modes on cyclic loading/unloading hysteresis loops of 2D woven ceramic-matrix composites (CMCs) has been investigated. The interface slip between fibers and the matrix existed in matrix cracking mode 3 and mode 5, in which matrix cracking and interface debonding occurred in longitudinal yarns, are considered as the major reason for hysteresis loops of 2D woven CMCs. The effects of fiber volume content, peak stress, matrix crack spacing, interface properties, matrix cracking mode proportion and interface wear on interface slip and hysteresis loops have been analyzed. The cyclic loading/unloading hysteresis loops of 2D woven SiC/SiC composite corresponding to different peak stresses have been predicted using the present analysis. It was found that the damage parameter, i.e., the proportion of matrix cracking mode 3 in the entire cracking modes of the composite, increases with increasing peak stress.

  13. Modeling the Effect of Multiple Matrix Cracking Modes on Cyclic Hysteresis Loops of 2D Woven Ceramic-Matrix Composites

    NASA Astrophysics Data System (ADS)

    Longbiao, Li

    2016-02-01

    In this paper, the effect of multiple matrix cracking modes on cyclic loading/unloading hysteresis loops of 2D woven ceramic-matrix composites (CMCs) has been investigated. The interface slip between fibers and the matrix existed in matrix cracking mode 3 and mode 5, in which matrix cracking and interface debonding occurred in longitudinal yarns, are considered as the major reason for hysteresis loops of 2D woven CMCs. The effects of fiber volume content, peak stress, matrix crack spacing, interface properties, matrix cracking mode proportion and interface wear on interface slip and hysteresis loops have been analyzed. The cyclic loading/unloading hysteresis loops of 2D woven SiC/SiC composite corresponding to different peak stresses have been predicted using the present analysis. It was found that the damage parameter, i.e., the proportion of matrix cracking mode 3 in the entire cracking modes of the composite, increases with increasing peak stress.

  14. Noncanonical Effects of IRF9 in Intestinal Inflammation: More than Type I and Type III Interferons

    PubMed Central

    Rauch, Isabella; Rosebrock, Felix; Hainzl, Eva; Heider, Susanne; Majoros, Andrea; Wienerroither, Sebastian; Strobl, Birgit; Stockinger, Silvia; Kenner, Lukas; Müller, Mathias

    2015-01-01

    The interferon (IFN)-stimulated gene factor 3 (ISGF3) transcription factor with its Stat1, Stat2, and interferon regulatory factor 9 (IRF9) subunits is employed for transcriptional responses downstream of receptors for type I interferons (IFN-I) that include IFN-α and IFN-β and type III interferons (IFN-III), also called IFN-λ. Here, we show in a murine model of dextran sodium sulfate (DSS)-induced colitis that IRF9 deficiency protects animals, whereas the combined loss of IFN-I and IFN-III receptors worsens their condition. We explain the different phenotypes by demonstrating a function of IRF9 in a noncanonical transcriptional complex with Stat1, apart from IFN-I and IFN-III signaling. Together, Stat1 and IRF9 produce a proinflammatory activity that overrides the benefits of the IFN-III response on intestinal epithelial cells. Our results further suggest that the CXCL10 chemokine gene is an important mediator of this proinflammatory activity. We thus establish IFN-λ as a potentially anticolitogenic cytokine and propose an important role for IRF9 as a component of noncanonical Stat complexes in the development of colitis. PMID:25918247

  15. Tip Effect of the Tapping Mode of Atomic Force Microscope in Viscous Fluid Environments.

    PubMed

    Shih, Hua-Ju; Shih, Po-Jen

    2015-01-01

    Atomic force microscope with applicable types of operation in a liquid environment is widely used to scan the contours of biological specimens. The contact mode of operation allows a tip to touch a specimen directly but sometimes it damages the specimen; thus, a tapping mode of operation may replace the contact mode. The tapping mode triggers the cantilever of the microscope approximately at resonance frequencies, and so the tip periodically knocks the specimen. It is well known that the cantilever induces extra liquid pressure that leads to drift in the resonance frequency. Studies have noted that the heights of protein surfaces measured via the tapping mode of an atomic force microscope are ~25% smaller than those measured by other methods. This discrepancy may be attributable to the induced superficial hydrodynamic pressure, which is worth investigating. In this paper, we introduce a semi-analytical method to analyze the pressure distribution of various tip geometries. According to our analysis, the maximum hydrodynamic pressure on the specimen caused by a cone-shaped tip is ~0.5 Pa, which can, for example, pre-deform a cell by several nanometers in compression before the tip taps it. Moreover, the pressure calculated on the surface of the specimen is 20 times larger than the pressure without considering the tip effect; these results have not been motioned in other papers. Dominating factors, such as surface heights of protein surface, mechanical stiffness of protein increasing with loading velocity, and radius of tip affecting the local pressure of specimen, are also addressed in this study. PMID:26225979

  16. Effects of compression on the vibrational modes of marginally jammed solids

    NASA Astrophysics Data System (ADS)

    Wyart, Matthieu; Silbert, Leonardo E.; Nagel, Sidney R.; Witten, Thomas A.

    2005-11-01

    Glasses have a large excess of low-frequency vibrational modes in comparison with most crystalline solids. We show that such a feature is a necessary consequence of the weak connectivity of the solid, and that the frequency of modes in excess is very sensitive to the pressure. We analyze, in particular, two systems whose density D(ω) of vibrational modes of angular frequency ω display scaling behaviors with the packing fraction: (i) simulations of jammed packings of particles interacting through finite-range, purely repulsive potentials, comprised of weakly compressed spheres at zero temperature and (ii) a system with the same network of contacts, but where the force between any particles in contact (and therefore the total pressure) is set to zero. We account in the two cases for the observed (a) convergence of D(ω) toward a nonzero constant as ω→0 , (b) appearance of a low-frequency cutoff ω* , and (c) power-law increase of ω* with compression. Differences between these two systems occur at a lower frequency. The density of states of the modified system displays an abrupt plateau that appears at ω* , below which we expect the system to behave as a normal, continuous, elastic body. In the unmodified system, the pressure lowers the frequency of the modes in excess. The requirement of stability despite the destabilizing effect of pressure yields a lower bound on the number of extra contact per particle δz:δz⩾p1/2 , which generalizes the Maxwell criterion for rigidity when pressure is present. This scaling behavior is observed in the simulations. We finally discuss how the cooling procedure can affect the microscopic structure and the density of normal modes.

  17. Normal mode calculation for triple helical DNA, stability and hydration effects

    NASA Astrophysics Data System (ADS)

    Dadarlat, Voichita Maria

    The effective field model for the dynamics of the triple helix d(T)n - d(A)n - d(T)n DNA polymer in solution has been applied to determine the vibrational normal modes of the system for both A and B conformation. The effect of site-bound counterions as compared to the area-bound counterions has been considered specifically by explicitly introducing degrees of freedom for the three counterions associated with a unit cell and coupling these to the DNA degrees of freedom via appropriate interactions. Stability of the system for all vibrational modes (positive eigenvalues for the solution of the dynamics problem) was used as a criterion to find possible equilibrium positions of the site-bound counterions in specific conditions of weak covalent bonding between the counterions and the phosphate free oxygens and distance dependent dielectric constants. Normal mode calculation for the A conformation shows that this type of triple helix is not stable in aqueous solutions unless the counterions are site-bound in certain positions close to the phosphate groups. The equilibrium domains for the positions of the counterions in both conformations have been determined. Free energy calculations for the two triple helices show that the B conformation is more stable than the A conformation. Our calculated normal modes match reasonably well with the experimental IR spectra. The effect of adding structural waters to the triplex DNA in the B conformation have been studied. The results clearly show that there is an inverse proportional relationship between the degree of boundness of the water molecules to the atoms in the triple helix and the relative humidity (RH) of the samples.

  18. Application of Failure Mode and Effects Analysis to Intraoperative Radiation Therapy Using Mobile Electron Linear Accelerators

    SciTech Connect

    Ciocca, Mario; Cantone, Marie-Claire; Veronese, Ivan; Cattani, Federica; Pedroli, Guido; Molinelli, Silvia; Vitolo, Viviana; Orecchia, Roberto

    2012-02-01

    Purpose: Failure mode and effects analysis (FMEA) represents a prospective approach for risk assessment. A multidisciplinary working group of the Italian Association for Medical Physics applied FMEA to electron beam intraoperative radiation therapy (IORT) delivered using mobile linear accelerators, aiming at preventing accidental exposures to the patient. Methods and Materials: FMEA was applied to the IORT process, for the stages of the treatment delivery and verification, and consisted of three steps: 1) identification of the involved subprocesses; 2) identification and ranking of the potential failure modes, together with their causes and effects, using the risk probability number (RPN) scoring system, based on the product of three parameters (severity, frequency of occurrence and detectability, each ranging from 1 to 10); 3) identification of additional safety measures to be proposed for process quality and safety improvement. RPN upper threshold for little concern of risk was set at 125. Results: Twenty-four subprocesses were identified. Ten potential failure modes were found and scored, in terms of RPN, in the range of 42-216. The most critical failure modes consisted of internal shield misalignment, wrong Monitor Unit calculation and incorrect data entry at treatment console. Potential causes of failure included shield displacement, human errors, such as underestimation of CTV extension, mainly because of lack of adequate training and time pressures, failure in the communication between operators, and machine malfunctioning. The main effects of failure were represented by CTV underdose, wrong dose distribution and/or delivery, unintended normal tissue irradiation. As additional safety measures, the utilization of a dedicated staff for IORT, double-checking of MU calculation and data entry and finally implementation of in vivo dosimetry were suggested. Conclusions: FMEA appeared as a useful tool for prospective evaluation of patient safety in radiotherapy. The

  19. Energetic Particle Effects Can Explain the Low Frequency of Alfvin Modes in the DIII-D Tokamak

    SciTech Connect

    Gorelenkov, N.N.; Heidbrink, W.W.

    2001-01-31

    During beam injection in the DIII-D tokamak, modes with lower frequencies than expected for toroidicity-induced Alfvin eigenmodes (TAE) are often observed. We present the analysis of one of these ''beta-induced Alfvin eigenmodes'' (BAE) with a high-n stability code HINST that includes the effect of the energetic ions on the mode frequency. It shows that the ''BAE'' could be the theoretically predicted resonant-TAE (RTAE), which is also called an energetic-particle mode (EPM).

  20. Direct observation of lanthanide(III)-phthalocyanine molecules on Au(111) by using scanning tunneling microscopy and scanning tunneling spectroscopy and thin-film field-effect transistor properties of Tb(III)- and Dy(III)-phthalocyanine molecules.

    PubMed

    Katoh, Keiichi; Yoshida, Yusuke; Yamashita, Masahiro; Miyasaka, Hitoshi; Breedlove, Brian K; Kajiwara, Takashi; Takaishi, Shinya; Ishikawa, Naoto; Isshiki, Hironari; Zhang, Yan Feng; Komeda, Tadahiro; Yamagishi, Masakazu; Takeya, Jun

    2009-07-29

    The crystal structures of double-decker single molecule magnets (SMM) LnPc(2) (Ln = Tb(III) and Dy(III); Pc = phthalocyanine) and non-SMM YPc(2) were determined by using X-ray diffraction analysis. The compounds are isomorphous to each other. The compounds have metal centers (M = Tb(3+), Dy(3+), and Y(3+)) sandwiched by two Pc ligands via eight isoindole-nitrogen atoms in a square-antiprism fashion. The twist angle between the two Pc ligands is 41.4 degrees. Scanning tunneling microscopy was used to investigate the compounds adsorbed on a Au(111) surface, deposited by using the thermal evaporation in ultrahigh vacuum. Both MPc(2) with eight lobes and MPc with four lobes, which has lost one Pc ligand, were observed. In the scanning tunneling spectroscopy images of TbPc molecules at 4.8 K, a Kondo peak with a Kondo temperature (T(K)) of approximately 250 K was observed near the Fermi level (V = 0 V). On the other hand, DyPc, YPc, and MPc(2) exhibited no Kondo peak. To understand the observed Kondo effect, the energy splitting of sublevels in a crystal field should be taken into consideration. As the next step in our studies on the SMM/Kondo effect in Tb-Pc derivatives, we investigated the electronic transport properties of Ln-Pc molecules as the active layer in top- and bottom-contact thin-film organic field effect transistor devices. Tb-Pc molecule devices exhibit p-type semiconducting properties with a hole mobility (mu(H)) of approximately 10(-4) cm(2) V(-1) s(-1). Interestingly, the Dy-Pc based devices exhibited ambipolar semiconducting properties with an electron mobility (mu(e)) of approximately 10(-5) and a mu(H) of approximately 10(-4) cm(2) V(-1) s(-1). This behavior has important implications for the electronic structure of the molecules. PMID:19569681

  1. Cytotoxic effects of Mn(III) N-alkylpyridylporphyrins in the presence of cellular reductant, ascorbate

    PubMed Central

    Ye, Xiaodong; Fels, Diane; Tovmasyan, Artak; Aird, Katherine M.; Dedeugd, Casey; Allensworth, Jennifer L.; Kos, Ivan; Park, Won; Spasojevic, Ivan; Devi, Gayathri R.; Dewhirst, Mark W.; Leong, Kam W.; Batinic-Haberle, Ines

    2012-01-01

    Due to the ability to easily accept and donate electrons Mn(III) N-alkylpyridylporphyrins (MnPs) can dismute O2˙−, reduce peroxynitrite, but also generate reactive species and behave as pro-oxidants if conditions favour such action. Herein two ortho isomers, MnTE-2-PyP5+, MnTnHex-2-PyP5+, and a meta isomer MnTnHex-3-PyP5+, which differ greatly with regard to their metal-centered reduction potential, E1/2 (MnIIIP/MnIIP) and lipophilicity, were explored. Employing MnIIIP/MnIIP redox system for coupling with ascorbate, these MnPs catalyze ascorbate oxidation and thus peroxide production. Consequently, cancer oxidative burden may be enhanced, which in turn would suppress its growth. Cytotoxic effects on Caco-2, Hela, 4T1, HCT116 and SUM149 were studied. When combined with ascorbate, MnPs killed cancer cells via peroxide produced outside of the cell. MnTE-2-PyP5+ was the most efficacious catalyst for peroxide production, while MnTnHex-3-PyP5+ is most prone to oxidative degradation with H2, and thus the least efficacious. A 4T1 breast cancer mouse study of limited scope and success was conducted. The tumour oxidative stress was enhanced and its microvessel density reduced when mice were treated either with ascorbate or MnP/ascorbate; the trend towards tumour growth suppression was detected. PMID:21859376

  2. Kinetic effects on geodesic acoustic mode from combined collisions and impurities

    SciTech Connect

    Yang, Shangchuan; Xie, Jinlin Liu, Wandong

    2015-04-15

    The dispersion relation for geodesic acoustic mode (GAM) is derived by applying a gyrokinetic model that accounts for the effects from both collisions and impurities. Based on the dispersion relation, an analysis is performed for the non-monotonic behavior of GAM damping versus the characteristic collision rate at various impurity levels. As the effective charge increases, the maximum damping rate is found to shift towards lower collision rates, nearer to the parameter range of a typical tokamak edge plasma. The relative strengths of ion-ion and impurity-induced collision effects, which are illustrated by numerical calculations, are found to be comparable. Impurity-induced collisions help decrease the frequency of GAM, while their effects on the damping rate are non-monotonic, resulting in a weaker total damping in the high collision regime. The results presented suggest considering collision effects as well as impurity effects in GAM analysis.

  3. Novel phosphate halides BaMnIII[PO4]FCl and BaMnIII[PO4]F2: Effects of mixed halides on crystal structures and magnetic properties

    NASA Astrophysics Data System (ADS)

    Pei, Da-Ting; Sun, Wei; Huang, Ya-Xi; Sun, Zhi-Mei; Pan, Yuanming; Mi, Jin-Xiao

    2016-02-01

    Two new phosphate halides BaMnIII[PO4]FCl (1) and BaMnIII[PO4]F2 (2), have been synthesized under hydrothermal conditions. Structural characterizations show that both new compounds adopt layered structures but with different polyhedral linkages. Introduction of Cl into Compound (1) results in isolated hemimorphic [MnO4FCl] octahedra, different from the chain of [MnO4F2]/[MnO2F4] octahedra in Compound (2). These compounds have significantly different molecular vibration modes and thermal stabilities. Magnetic measurements reveal that Compound (2) has larger antiferromagnetic interactions than Compound (1), because the former has strong interactions between Mn3+-Mn3+ ions within corner-shared Mn3+-octahedral chains whereas the latter only possesses isolated Mn3+-octahedra. Both compounds transform to a new orthorhombic compound BaMnII(PO4)F (3) after thermal decomposition.

  4. Immunomodulatory and clinical effects of the "tiaomian III decoction" in patients with blood blocking antibody deficiency and recurrent spontaneous abortion.

    PubMed

    Gao, H Y; Tao, E X; Wang, Y; Yue, Q A; Ren, C E; Yan, L F

    2015-01-01

    We studied the immunomodulatory and clinical effects of the empirical formula "tiaomian III decoction" on maternal blood blocking antibody deficiency and recurrent spontaneous abortion. Sixty-one patients with blocking antibody deficiency were divided in the experimental group (N = 31), who took tiaomian III decoction, and the control group (N = 30), who received active immunotherapy with paternal lymphocytes; both treatments lasted 3 months. Blocking antibodies, anti-idiotypic antibodies, interleukin, T-lymphocyte subsets, and macrophage colony-stimulating factor (M-CSF) were tested. After treatment, the positive conversion rate reached 87.1 and 86.7% in the experimental and control groups, respectively. After treatment, CD4 levels decreased while CD8 levels increased in both groups. The CD4/CD8 ratio was higher than normal and increased significantly from pre-treatment (P < 0.05). IL-10 and M-CSF levels increased significantly in both groups (P < 0.05). The 1-year conception rates of the experimental and control groups were 58.1 and 46.7%, respectively (P < 0.05). The results show the tiaomian III decoction can increase the positive conversion rate of maternal blocking antibodies and promote the production of IL-10 and M-CSF. Thus, it strengthens the maternal body's protection of the fetus and maintenance of conception. The higher conception rate of the experimental group demonstrates the positive clinic efficacy of the tiaomian III decoction on maternal blood blocking antibody deficiency and recurrent spontaneous abortion. PMID:25966108

  5. Failure modes and effects analysis of a coal-slurry preheater

    SciTech Connect

    Mitchell, H.A.; Parsly, L.F.; Smith, A.N.

    1981-09-01

    The Fossil Energy performance assurance program is concerned with the application of reliability, safety, and quality assurance techniques in the design and operation of the pilot plants and demonstration plants that exist or are being planned as part of the US Department of Energy fossil energy conversion programs. This report involves the application of one technique, failure modes and effects analysis (FMEA), on the safety and reliability analysis of the coal slurry preheater, a critical component in a typical coal direct liquefaction plant. The analysis identifies 55 potential failure modes. Fourteen of these events, if they should occur, would result in losses of sufficient magnitude to require special consideration in the design or operating phase to assure control of risk at an acceptable level. The report concludes that the FMEA could be a valuable tool in the identification of critical components for coal conversion systems. For maximum effect, FMEA needs to be used during the initial design phase. Its principal value is to determine high-risk failure modes, which could have unacceptable impacts on system safety and reliability/availability. The usefulness of FMEA will be improved if it is supplemented by the development of a failure data base; this data base could also be of value in selected cases as input to a more detaled technique such as fault-tree analysis.

  6. Effect of set size, age, and mode of stimulus presentation on information-processing speed.

    NASA Technical Reports Server (NTRS)

    Norton, J. C.

    1972-01-01

    First, second, and third grade pupils served as subjects in an experiment designed to show the effect of age, mode of stimulus presentation, and information value on recognition time. Stimuli were presented in picture and printed word form and in groups of 2, 4, and 8. The results of the study indicate that first graders are slower than second and third graders who are nearly equal. There is a gross shift in reaction time as a function of mode of stimulus presentation with increase in age. The first graders take much longer to identify words than pictures, while the reverse is true of the older groups. With regard to set size, a slope appears in the pictures condition in the older groups, while for first graders, a large slope occurs in the words condition and only a much smaller one for pictures.

  7. Dispersing artifacts in FT-STS: a comparison of set point effects across acquisition modes.

    PubMed

    Macdonald, A J; Tremblay-Johnston, Y-S; Grothe, S; Chi, S; Dosanjh, P; Johnston, S; Burke, S A

    2016-10-14

    Fourier-transform scanning tunnelling spectroscopy (FT-STS), or quasiparticle interference, has become an influential tool for the study of a wide range of important materials in condensed matter physics. However, FT-STS in complex materials is often challenging to interpret, requiring significant theoretical input in many cases, making it crucial to understand potential artifacts of the measurement. Here, we compare the most common modes of acquiring FT-STS data and show through both experiment and simulations that artifact features can arise that depend on how the tip height is stabilized throughout the course of the measurement. The most dramatic effect occurs when a series of dI/dV maps at different energies are acquired with simultaneous constant current feedback; here a feature that disperses in energy appears that is not observed in other measurement modes. Such artifact features are similar to those arising from real physical processes in the sample and are susceptible to misinterpretation. PMID:27607539

  8. Effect of heating mode on sinterability of Fe-Ni steels.

    PubMed

    Annamalai, A Raja; Kumar, Rajiv; Upadhyaya, Anish; Agrawal, Dinesh

    2011-01-01

    The present study examines the effect of heating mode on the densification, microstructure, and mechanical properties of iron-nickel steel with graphite and phosphorus addition. The compacts were sintered in conventional (radiatively-heated) and microwave (2.45 GHz, multimode) furnaces at 1120 degrees C for 1 hour in forming gas (dissociated ammonia atmosphere, 95% N2-5% H2). The experimental results show that microwave sintered alloy has better properties compared with the conventionally sintered counterparts. Detailed analyses by using optical microscopy and scanning electron microscopy (SEM) reveal that microwave sintered sample has finer microstructure. SEM examination of the fractured surfaces indicate that a mixed mode fracture containing both, ductile and brittle types, is present in microwave sintered alloy, in contrast with the brittle fracture only in conventional sintered counterpart. PMID:24428106

  9. Effective dipole moment for the mode coupling instability: Mapping of self-consistent wake models

    SciTech Connect

    Roecker, T. B.; Zhdanov, S. K.; Ivlev, A. V.; Morfill, G. E.; Lampe, M.; Joyce, G.

    2012-07-15

    The theory of the mode coupling instability operating in two-dimensional plasma crystals is generalized, by employing the linear plasma response formalism to describe the interparticle interactions self-consistently. In this approach, the underlying ion distribution function is calculated from first principles. Subthermal and suprathermal regimes of the ion flow are considered. A mapping procedure is proposed, which relates the self-consistent coupling coefficients to the effective dipole moment of the wake-the parameter which characterizes the mode coupling in the framework of the conventionally used Yukawa/point-wake model. The importance of the self-consistent approach is demonstrated by comparing the theoretically obtained dipole moments with the values deduced from experiments.

  10. Enhanced magnetoelectric effect in longitudinal-longitudinal mode laminate with cofired interdigitated electrodes

    NASA Astrophysics Data System (ADS)

    Yan, Yongke; Zhou, Yuan; Priya, Shashank

    2014-01-01

    In this letter, we describe a low-temperature cofiring technique to embed the interdigitated electrodes (IDE) inside the piezoelectric ceramic layer to achieve longitudinally (L) poled magnetoelectric (ME) laminates. The ME voltage coefficient of this L-L mode composite was found to be 4.41 V cm-1 Oe-1 at 1 kHz, which is 340% higher than that of L-T (transversal) mode. IDE based longitudinal poling and piezoelectric response was evaluated by impedance changes and piezoresponse force microscopy, illustrating the effect of inactive/ineffective zone in the range beneath and above the fingers with vanishing fields. At an electric field of 50 V/cm, the composite was found to generate magnetic field on the order of 175 μG at 1 kHz.

  11. Model OA Wind Turbine Generator FEMA (Failure Modes and Effects Analysis)

    SciTech Connect

    Klein, W.E. . Plum Brook Station); Lalli, V.R. . Lewis Research Center)

    1989-10-01

    This report presents the results of Failure Modes and Effects Analysis (FMEA) conducted for the Wind Turbine Generators. The FMEA was performed for the functional modes of each system, subsystem, or component. The single-point failures were eliminated for most of the systems. The blade system was the only exception. The qualitative probability of a blade separating was estimated at Level D-remote. Many changes were made to the hardware as a result of this analysis. The most significant change was the addition of the safety system. Operational experience and need to improve machine availability have resulted in subsequent changes to the various systems which are also reflected in this FMEA. 2 refs., 3 figs.

  12. Using Failure Mode and Effects Analysis to design a comfortable automotive driver seat.

    PubMed

    Kolich, Mike

    2014-07-01

    Given enough time and use, all designs will fail. There are no fail-free designs. This is especially true when it comes to automotive seating comfort where the characteristics and preferences of individual customers are many and varied. To address this problem, individuals charged with automotive seating comfort development have, traditionally, relied on iterative and, as a result, expensive build-test cycles. Cost pressures being placed on today's vehicle manufacturers have necessitated the search for more efficient alternatives. This contribution aims to fill this need by proposing the application of an analytical technique common to engineering circles (but new to seating comfort development), namely Design Failure Mode and Effects Analysis (DFMEA). An example is offered to describe how development teams can use this systematic and disciplined approach to highlight potential seating comfort failure modes, reduce their risk, and bring capable designs to life. PMID:24529532

  13. Arc-discharge effects on residual stress and refractive index in single-mode optical fibers.

    PubMed

    Wang, Pengfei; Jenkins, Micah H; Gaylord, Thomas K

    2016-03-20

    Arc-discharge effects on the residual stress and refractive index in single-mode optical fibers are investigated using a previously developed three-dimensional concurrent stress-index measurement method. Using commercial optical fibers and a commercial fusion splicer, the residual stress and refractive index perturbations caused by weak electrical arc discharges in single-mode fibers were measured. Refractive index changes greater than 10-4 and longitudinal perturbation lengths of less than 500 μm were shown to be possible. The subsequent prospects for arc-induced long-period fiber gratings are analyzed, and a typical transmission resonance is predicted to have a depth of 56 dB and a bandwidth of 0.08 nm at a wavelength of 1585 nm. The results of this investigation will be useful in modeling device performance and optimization of arc-induced long-period fiber grating fabrication. PMID:27140587

  14. Finite ballooning angle effects on ion temperature gradient driven mode in gyrokinetic flux tube simulations

    SciTech Connect

    Singh, Rameswar; Brunner, S.; Ganesh, R.; Jenko, F.

    2014-03-15

    This paper presents effects of finite ballooning angles on linear ion temperature gradient (ITG) driven mode and associated heat and momentum flux in Gyrokinetic flux tube simulation GENE. It is found that zero ballooning angle is not always the one at which the linear growth rate is maximum. The ITG mode acquires a short wavelength (SW) branch (k{sub ⊥}ρ{sub i} > 1) when growth rates maximized over all ballooning angles are considered. However, the SW branch disappears on reducing temperature gradient showing characteristics of zero ballooning angle SWITG in case of extremely high temperature gradient. Associated heat flux is even with respect to ballooning angle and maximizes at nonzero ballooning angle while the parallel momentum flux is odd with respect to the ballooning angle.

  15. [Effect of nucleation modes on the induced crystallization process for copper contained wastewater treatment].

    PubMed

    Xiong, Ya; Yan, Zhong; Zhang, Guo-Chen; Zheng, Ming-Xia; Wang, Kai-Jun

    2011-10-01

    The effect of nucleation modes on the induced crystallization process for copper contained wastewater treatment was studied. Tests were undertaken to observe the difference of copper removal efficiency and the crystal growth with homogeneous and heterogeneous nucleation. When the influent copper concentration was 50 mg x L(-1), copper removal efficiency could achieve 98.0% with the heterogeneous and 26.3% with homogeneous nucleation. And the SEM-EDS showed that the growth of crystals with heterogeneous nucleation was better and the purity of the crystals was higher than that with homogeneous nucleation. It is obvious that the homogeneous nucleation was an unfavorable condition on the induced crystallization process. Then the research devoted to discuss the process of induced crystallization with the two different nucleation mode and analysis the influencing mechanism of the homogeneous nucleation on the induced crystallization. PMID:22279909

  16. Effects of bandwidth-limiting tuning elements in synchronously pumped mode-locked lasers

    SciTech Connect

    Zandi, B.; Casperson, L.W.; MacFarlane, D.L. )

    1990-03-01

    A description of bandwidth-limiting tuning filters is introduced into a semiclassical model for synchronously pumped mode-locked dye lasers. The finite phase memory of the molecular wave functions is included as are the isotropic molecular distribution and the finite vibrational relaxation times. The new set of equations has been solved numerically using the best available values for the various parameters. The results have been compared with experimental data obtained using a rhodamine 6G dye laser, which is synchronously pumped using an acousto-optically mode-locked argon laser. Tuning element effects have been studied using two- and three-plate birefringent filters and a tuning wedge, and the experimental results agree with the numerical solutions.

  17. Effect of wind tunnel acoustic modes on linear oscillating cascade aerodynamics

    NASA Technical Reports Server (NTRS)

    Buffum, Daniel H.; Fleeter, Sanford

    1993-01-01

    The aerodynamics of a biconvex airfoil cascade oscillating in torsion is investigated using the unsteady aerodynamic influence coefficient technique. For subsonic flow and reduced frequencies as large as 0.9, airfoil surface unsteady pressures resulting from oscillation of one of the airfoils are measured using flush-mounted high-frequency-response pressure transducers. The influence coefficient data are examined in detail and then used to predict the unsteady aerodynamics of a cascade oscillating at various interblade phase angles. These results are correlated with experimental data obtained in the traveling-wave mode of oscillation and linearized analysis predictions. It is found that the unsteady pressure disturbances created by an oscillating airfoil excite wind tunnel acoustic modes which have detrimental effects on the experimental data. Acoustic treatment is proposed to rectify this problem.

  18. Effect of wind tunnel acoustic modes on linear oscillating cascade aerodynamics

    NASA Technical Reports Server (NTRS)

    Buffum, D. H.; Fleeter, S.

    1994-01-01

    The aerodynamics of a biconvex airfoil cascade oscillating in torsion is investigated using the unsteady aerodynamic influence coefficient technique. For subsonic flow and reduced frequencies as large as 0.9, airfoil surface unsteady pressures resulting from oscillation of one of the airfoils are measured using flush-mounted high-frequency-response pressure transducers. The influence coefficient data are examined in detail and then used to predict the unsteady aerodynamics of a cascade oscillating at various interblade phase angles. These results are correlated with experimental data obtained in the traveling-wave mode of oscillation and linearized analysis predictions. It is found that the unsteady pressure disturbances created by an oscillating airfoil excite wind tunnel acoustic modes, which have detrimental effects on the experimental results. Acoustic treatment is proposed to rectify this problem.

  19. Wall thickness effect on the resistive wall mode stability in toroidal plasmas

    SciTech Connect

    Zheng, L.-J.; Kotschenreuther, M.T.

    2005-07-15

    The effect of finite wall thickness on the stability of n=1 resistive wall modes in toroidal plasmas is investigated. A fusion reactor-relevant configuration is examined. The investigation employs a novel ideal-magnetohydrodynamics adaptive shooting code for axisymmetric plasmas, extended to take into account the wall thickness. Although finite wall thickness generally reduces the growth rate of the resistive wall modes, no contribution to stabilization is found to be made by the portion of the wall that is located beyond the critical position for perfectly conducting wall stabilization. Thus, when the inner side of the wall lies near the critical wall position, the scaling of the growth rate versus wall thickness in the realistic thick-wall calculation is significantly different from that of the usual thin-wall theory. The thin-wall estimate is relevant only when the wall is brought very close to the plasma and is not too thick.

  20. Long wave infrared tunable filter based on guided mode resonant effect

    NASA Astrophysics Data System (ADS)

    Mirotznik, Mark S.; Gupta, Neelam; McElhiney, Morgan; Carey, Victoria

    2016-05-01

    We describe here a tunable long wave infrared (LWIR) band filter based on the guided mode resonant filter (GMRF) effect. The device consists of a subwavelength dielectric grating sandwiched between planar layers of contrasting dielectric materials. Using a rigorous electromagnetic design and analysis method we demonstrate how a strong narrow band reflectance can be induced. Moreover, the resonant wavelength can be easily tuned over the entire 8-12 micron band by mechanically tilting the device with respect to the optical axis. Simulation and experimental results are presented demonstrating the effectiveness of the device.

  1. Plasma shape and finite {beta} effects on stability thresholds of the ion temperature gradient modes

    SciTech Connect

    Jhowry, B.; Andersson, J.; Dastgeer, S.

    2004-12-01

    The stability of electromagnetic ion temperature gradient driven modes with emphasis on the lower and upper stability thresholds is investigated by a collisionless magnetized plasma in both circular and noncircular geometry. The stability properties are discussed and the results are compared for finite {beta} effects, arbitrary elongation, and Shafranov shift rate parameters. It has been found that the lower stability thresholds are weakly dependent on the (combined) effects of Shafranov shift rate, finite {beta}, and elongation whereas the second (upper) stability regime shows substantial dependence depending on parameter regimes.

  2. Hall current effect on tearing mode instability. [possible cause of magnetic field reconnection in space

    NASA Technical Reports Server (NTRS)

    Terasawa, T.

    1983-01-01

    From a linear 2-D eigenmode analysis, it is found that the Hall current effect on collisional tearing mode instability becomes important for the thin magnetic reversal layer whose width is comparable to the ion inertia length; Hall currents produce a three-dimensional field structure and increase the reconnection (growth) rate. Since the magnetaic reversal layer widths both in the magnetopause and in the magnetotail are reported to become as thin as the ion inertial length (several hundred km) when the reconnection process is supposed to occur, the Hall current effect may explain the appearance of the dawn-dusk component of the magnetic field in the magnetotail reconnection region.

  3. Effective second-order susceptibility in photonic crystals mode of centrosymmetric materials

    NASA Astrophysics Data System (ADS)

    Feigel, A.; Kotler, Z.; Sfez, B.

    2002-02-01

    A technique for obtaining efficient bulk second-order susceptibility in noncentrosymmetric photonic crystals (PC) made of centrosymmetric materials is discussed. The effect is based on the electric quadrupole effect, strong electromagnetic mode deformation, and nonhomogeneous contribution to volume polarization from different parts of the PC. The required symmetry breaking is introduced on the macroscale of the PC unit cell. The obtained structural χ(2)str is comparable with the second-order susceptibility of ordinary nonlinear materials. Phase matching can be achieved by introducing symmetry modulation (quasi-phase-matching) during fabrication of the PC.

  4. Laser-induced hydrodynamics in water-saturated tissue: III. Optoacoustic effects

    NASA Astrophysics Data System (ADS)

    Yusupov, V. I.; Bulanov, V. V.; Chudnovskii, V. M.; Bagratashvili, V. N.

    2014-01-01

    Studied in this work are specific features of acoustic vibrations generated at the hot blackened tip of an optical fiber (the so-called hot tip) delivering moderate-power (1-10 W) CW laser radiation in contact with water or a water-saturated biotissue. Generated upon such contact is a wideband acoustic signal whose characteristics largely depend on the object exposed and treatment scheme. Placing the hot tip in an acoustic resonator is demonstrated to cause distinct amplitude modulation of the acoustic noise. The formation of laser channels in an intervertebral disc or the intramedullary cavity of a bovine thighbone gives rise to the emission of a quasiperiodic train of pulses associated with the explosive growth and collapse of steam-gas bubbles in the hot-tip-to-biotissue contact region. The resultant pressure pulses, 20 ± 15 MPa in amplitude, cause damage to the adjacent tissue and facilitate the production of a laser channel at a rate of some 0.4-5 mm s-1. During the course of laser treatment the biotissue gradually gets saturated with steam-gas bubbles, which results in the development of low-frequency pressure oscillations in the range 0.1-10 Hz and a gradual pressure rise to around 200 kPa, leading to reduction of the natural frequencies of the resonance modes of the biotissue. The possible effect of these acoustic vibrations on the biotissue is discussed.

  5. Modes of reproduction and the accumulation of deleterious mutations with multiplicative fitness effects.

    PubMed Central

    Haccou, Patsy; Schneider, Maria Victoria

    2004-01-01

    Mutational load depends not only on the number and nature of mutations but also on the reproductive mode. Traditionally, only a few specific reproductive modes are considered in the search of explanations for the maintenance of sex. There are, however, many alternatives. Including these may give radically different conclusions. The theory on deterministic deleterious mutations states that in large populations segregation and recombination may lead to a lower load of deleterious mutations, provided that there are synergistic interactions. Empirical research suggests that effects of deleterious mutations are often multiplicative. Such situations have largely been ignored in the literature, since recombination and segregation have no effect on mutation load in the absence of epistasis. However, this is true only when clonal reproduction and sexual reproduction with equal male and female ploidy are considered. We consider several alternative reproductive modes that are all known to occur in insects: arrhenotoky, paternal genome elimination, apomictic thelytoky, and automictic thelytoky with different cytological mechanisms to restore diploidy. We give a method that is based on probability-generating functions, which provides analytical and numerical results on the distributions of deleterious mutations. Using this, we show that segregation and recombination do make a difference. Furthermore, we prove that a modified form of Haldane's principle holds more generally for thelytokous reproduction. We discuss the implications of our results for evolutionary transitions between different reproductive modes in insects. Since the strength of Muller's ratchet is reduced considerably for several forms of automictic thelytoky, many of our results are expected to be also valid for initially small populations. PMID:15020489

  6. Chaotic dynamics of cardioventilatory coupling in humans: effects of ventilatory modes

    PubMed Central

    Mangin, Laurence; Clerici, Christine; Similowski, Thomas; Poon, Chi-Sang

    2009-01-01

    Cardioventilatory coupling (CVC), a transient temporal alignment between the heartbeat and inspiratory activity, has been studied in animals and humans mainly during anesthesia. The origin of the coupling remains uncertain, whether or not ventilation is a main determinant in the CVC process and whether the coupling exhibits chaotic behavior. In this frame, we studied sedative-free, mechanically ventilated patients experiencing rapid sequential changes in breathing control during ventilator weaning during a switch from a machine-controlled assistance mode [assist-controlled ventilation (ACV)] to a patient-driven mode [inspiratory pressure support (IPS) and unsupported spontaneous breathing (USB)]. Time series were computed as R to start inspiration (RI) and R to the start of expiration (RE). Chaos was characterized with the noise titration method (noise limit), largest Lyapunov exponent (LLE) and correlation dimension (CD). All the RI and RE time series exhibit chaotic behavior. Specific coupling patterns were displayed in each ventilatory mode, and these patterns exhibited different linear and chaotic dynamics. When switching from ACV to IPS, partial inspiratory loading decreases the noise limit value, the LLE, and the correlation dimension of the RI and RE time series in parallel, whereas decreasing intrathoracic pressure from IPS to USB has the opposite effect. Coupling with expiration exhibits higher complexity than coupling with inspiration during mechanical ventilation either during ACV or IPS, probably due to active expiration. Only 33% of the cardiac time series (RR interval) exhibit complexity either during ACV, IPS, or USB making the contribution of the cardiac signal to the chaotic feature of the coupling minimal. We conclude that 1) CVC in unsedated humans exhibits a complex dynamic that can be chaotic, and 2) ventilatory mode has major effects on the linear and chaotic features of the coupling. Taken together these findings reinforce the role of

  7. Thermoelectric effect in the Kondo dot side-coupled to a Majorana mode

    NASA Astrophysics Data System (ADS)

    Khim, Heunghwan; López, Rosa; Lim, Jong Soo; Lee, Minchul

    2015-06-01

    We investigate the linear thermoelectric response of an interacting quantum dot side-coupled by one of two Majorana modes hosted by a topological superconducting wire. We employ the numerical renormalization group technique to obtain the thermoelectrical conductance L in the Kondo regime while the background temperature T, the Majorana-dot coupling Γm, and the overlap ɛm between the two Majorana modes are tuned. We distinguish two transport regimes in which L displays different features: the weak- (ΓmTK) regimes, where TK is the Kondo temperature. For an infinitely long nanowire where the Majorana modes do not overlap (ɛm = 0), the thermoelectrical conductance in the weak-coupling regime exhibits a peak at T ~ Γmmodes restores the Kondo effect in a smaller energy scale Γ'm and gives rise to an additional peak in Γ ~ Γ'm, whose sign is opposite to that at T ~ Γm. In the strong-coupling regime this additional peak can cause a non-monotonic behavior of L with respect to the dot gate. Finally, in order to identify the fingerprint of Majorana physics, we compare the Majorana case with its counterpart in which the Majorana bound states are replaced by a (spin-polarized) ordinary bound state and find that the thermoelectric features for finite ɛm are the genuine effect of the Majorana physics.

  8. Global fine-mode aerosol radiative effect, as constrained by comprehensive observations

    NASA Astrophysics Data System (ADS)

    Chung, Chul E.; Chu, Jung-Eun; Lee, Yunha; van Noije, Twan; Jeoung, Hwayoung; Ha, Kyung-Ja; Marks, Marguerite

    2016-07-01

    Aerosols directly affect the radiative balance of the Earth through the absorption and scattering of solar radiation. Although the contributions of absorption (heating) and scattering (cooling) of sunlight have proved difficult to quantify, the consensus is that anthropogenic aerosols cool the climate, partially offsetting the warming by rising greenhouse gas concentrations. Recent estimates of global direct anthropogenic aerosol radiative forcing (i.e., global radiative forcing due to aerosol-radiation interactions) are -0.35 ± 0.5 W m-2, and these estimates depend heavily on aerosol simulation. Here, we integrate a comprehensive suite of satellite and ground-based observations to constrain total aerosol optical depth (AOD), its fine-mode fraction, the vertical distribution of aerosols and clouds, and the collocation of clouds and overlying aerosols. We find that the direct fine-mode aerosol radiative effect is -0.46 W m-2 (-0.54 to -0.39 W m-2). Fine-mode aerosols include sea salt and dust aerosols, and we find that these natural aerosols result in a very large cooling (-0.44 to -0.26 W m-2) when constrained by observations. When the contribution of these natural aerosols is subtracted from the fine-mode radiative effect, the net becomes -0.11 (-0.28 to +0.05) W m-2. This net arises from total (natural + anthropogenic) carbonaceous, sulfate and nitrate aerosols, which suggests that global direct anthropogenic aerosol radiative forcing is less negative than -0.35 W m-2.

  9. The costs and effectiveness of large Phase III pre-licensure vaccine clinical trials.

    PubMed

    Black, Steven

    2015-01-01

    Prior to the 1980s, most vaccines were licensed based upon safety and effectiveness studies in several hundred individuals. Beginning with the evaluation of Haemophilus influenzae type b conjugate vaccines, much larger pre-licensure trials became common. The pre-licensure trial for Haemophilus influenzae oligosaccharide conjugate vaccine had more than 60,000 children and that of the seven-valent pneumococcal conjugate vaccine included almost 38,000 children. Although trial sizes for both of these studies were driven by the sample size required to demonstrate efficacy, the sample size requirements for safety evaluations of other vaccines have subsequently increased. With the demonstration of an increased risk of intussusception following the Rotashield brand rotavirus vaccine, this trend has continued. However, routinely requiring safety studies of 20,000-50,000 or more participants has two major downsides. First, the cost of performing large safety trials routinely prior to licensure of a vaccine is very large, with some estimates as high at US$200 million euros for one vaccine. This high financial cost engenders an opportunity cost whereby the number of vaccines that a company is willing or able to develop to meet public health needs becomes limited by this financial barrier. The second downside is that in the pre-licensure setting, such studies are very time consuming and delay the availability of a beneficial vaccine substantially. One might argue that in some situations, this financial commitment is warranted such as for evaluations of the risk of intussusception following newer rotavirus vaccines. However, it must be noted that while an increased risk of intussusception was not identified in large pre-licensure studies, in post marketing evaluations an increased risk of this outcome has been identified. Thus, even the extensive pre-licensure evaluations conducted did not identify an associated risk. The limitations of large Phase III trials have also been

  10. Ferrimagnetic ordering behaviors and compensation temperatures in the FeIIFeIII bimetallic oxalates: Effective-field theory

    NASA Astrophysics Data System (ADS)

    Shi, Xiaoling; Qi, Yang

    2016-08-01

    A mixed spin-2 (FeII) and spin-5/2 (FeIII) ferrimagnetic Ising model on a honeycomb lattice was built to describe the FeII FeIII bimetallic oxalates, and the ferrimagnetic ordering behaviors and compensation temperatures were investigated through the effective-field theory based on Glauber-type stochastic dynamic. It was found that the effects of the interlayer coupling and the single-ion anisotropy contributed to the increase of the critical temperature with growing layer separation and the existence of compensation temperature depending on the organic cation. In particular, the magnetization of the system may show a small discontinuous jump in a certain range of the single-ion anisotropy.

  11. Spatiotemporal Patterns of a Predator-Prey System with an Allee Effect and Holling Type III Functional Response

    NASA Astrophysics Data System (ADS)

    Li, Yuanyuan; Wang, Jinfeng

    A diffusive Gause type predator-prey system with Allee effect in prey growth and Holling type III response subject to Neumann boundary conditions is investigated. Existence of nonconstant positive steady state solutions is proved by Leray-Schauder degree theory and bifurcation theory. Global stability of the positive equilibrium of the system is also investigated. Moreover, bifurcations of spatially homogeneous and nonhomogeneous periodic solutions are analyzed. Our rigorous results justify some recent ecological observations.

  12. Metal complexes of 3-(4-bromophenyl)-1-pyridin-2-ylprop-2-en-1-one thiosemicarbazone: cytotoxic activity and investigation on the mode of action of the gold(III) complex.

    PubMed

    Sâmia, Luciana B P; Parrilha, Gabrieli L; Da Silva, Jeferson G; Ramos, Jonas P; Souza-Fagundes, Elaine M; Castelli, Silvia; Vutey, Venn; Desideri, Alessandro; Beraldo, Heloisa

    2016-06-01

    Complexes [Au(PyCT4BrPh)Cl]Cl (1), [Pt(PyCT4BrPh)Cl]0.5KCl (2), and [Pd(PyCT4BrPh)Cl]KCl (3) were obtained with 3-(4-bromophenyl)-1-pyridin-2-ylprop-2-en-1-one thiosemicarbazone (HPyCT4BrPh). Although complexes (2) and (3) did not exhibit potent cytotoxic activity, HPyCT4BrPh and its gold(III) complex (1) proved to be highly cytotoxic against HL-60 (human promyelocytic leukemia) and THP-1 (human monocytic leukemia) cells, and against MDA-MB 231 and MCF-7 (human breast adenocarcinoma) solid tumor cells. Except for HL-60 cells, upon coordination to gold(III) a 2- to 3-fold increase in the cytotoxic effect was observed. An investigation on the possible biological targets of the gold(III) complex was carried out. Complex (1) but not the free thiosemicarbazone inhibits the enzymatic activity of thioredoxin reductase (TrxR). The affinity of 1 for TrxR suggests metal binding to a selenol residue in the active site of the enzyme. While HPyCT4BrPh was inactive, 1 was able to inhibit topoisomerase IB (Topo IB) activity. Hence, inhibition of TrxR and Topo IB could contribute to the mechanism of cytotoxic action of complex (1). PMID:27091443

  13. REVISITING THE FIRST GALAXIES: THE EFFECTS OF POPULATION III STARS ON THEIR HOST GALAXIES

    SciTech Connect

    Muratov, Alexander L.; Gnedin, Oleg Y.; Zemp, Marcel; Gnedin, Nickolay Y.

    2013-08-01

    We revisit the formation and evolution of the first galaxies using new hydrodynamic cosmological simulations with the adaptive refinement tree code. Our simulations feature a recently developed model for H{sub 2} formation and dissociation, and a star formation recipe that is based on molecular rather than atomic gas. Here, we develop and implement a recipe for the formation of metal-free Population III (Pop III) stars in galaxy-scale simulations that resolve primordial clouds with sufficiently high density. We base our recipe on the results of prior zoom-in simulations that resolved the protostellar collapse in pre-galactic objects. We find the epoch during which Pop III stars dominated the energy and metal budget of the first galaxies to be short-lived. Galaxies that host Pop III stars do not retain dynamical signatures of their thermal and radiative feedback for more than 10{sup 8} years after the lives of the stars end in pair-instability supernovae, even when we consider the maximum reasonable efficiency of the feedback. Though metals ejected by the supernovae can travel well beyond the virial radius of the host galaxy, they typically begin to fall back quickly, and do not enrich a large fraction of the intergalactic medium. Galaxies with a total mass in excess of 3 Multiplication-Sign 10{sup 6} M{sub Sun} re-accrete most of their baryons and transition to metal-enriched Pop II star formation.

  14. Complexation Effect on Redox Potential of Iron(III)-Iron(II) Couple: A Simple Potentiometric Experiment

    ERIC Educational Resources Information Center

    Rizvi, Masood Ahmad; Syed, Raashid Maqsood; Khan, Badruddin

    2011-01-01

    A titration curve with multiple inflection points results when a mixture of two or more reducing agents with sufficiently different reduction potentials are titrated. In this experiment iron(II) complexes are combined into a mixture of reducing agents and are oxidized to the corresponding iron(III) complexes. As all of the complexes involve the…

  15. The Effects of Helmet Weight on Hybrid III Head and Neck Responses by Comparing Unhelmeted and Helmeted Impacts.

    PubMed

    Jadischke, Ron; Viano, David C; McCarthy, Joe; King, Albert I

    2016-10-01

    Most studies on football helmet performance focus on lowering head acceleration-related parameters to reduce concussions. This has resulted in an increase in helmet size and mass. The objective of this paper was to study the effect of helmet mass on head and upper neck responses. Two independent test series were conducted. In test series one, 90 pendulum impact tests were conducted with four different headform and helmet conditions: unhelmeted Hybrid III headform, Hybrid III headform with a football helmet shell, Hybrid III headform with helmet shell and facemask, and Hybrid III headform with the helmet and facemask with mass added to the shell (n = 90). The Hybrid III neck was used for all the conditions. For all the configurations combined, the shell only, shell and facemask, and weighted helmet conditions resulted in 36%, 43%, and 44% lower resultant head accelerations (p < 0.0001), respectively, when compared to the unhelmeted condition. Head delta-V reductions were 1.1%, 4.5%, and 4.4%, respectively. In contrast, the helmeted conditions resulted in 26%, 41%, and 49% higher resultant neck forces (p < 0.0001), respectively. The increased neck forces were dominated by neck tension. In test series two, testing was conducted with a pneumatic linear impactor (n = 178). Fourteen different helmet makes and models illustrate the same trend. The increased neck forces provide a possible explanation as to why there has not been a corresponding reduction in concussion rates despite improvements in helmets ability to reduce head accelerations. PMID:27456840

  16. Microcalorimetric study of the effect of Ce(III) on metabolic activity of mitochondria isolated from indice rice 9311.

    PubMed

    Dai, Jie; Zhang, Ye-Zhong; Liu, Yi; Li, Qiang-Guo

    2008-07-01

    Rare earth elements (REEs) have beneficial influence on plant growth and are widely used in agriculture practice, but little is known about behavior of the REEs on mitochondria in plant cells. Thermogenic metabolic curves were determined by the ampoule method at 303 K using a TAM air isothermal microcalorimeter in mitochondria isolated from indice rice 9311 (Oryza sativa L.), and the effect of Ce(III) on mitochondrial metabolism was investigated. By analyzing the obtained heat flux curves, the crucial parameters such as activity recovery rate constant (k) and maximum heat power (P(m)) were investigated. Application of Ce3+ in concentrations ranging from 0 to 120 microg/ml significantly increased k and P(m) values, with the maximum reaching 261 and 180% of the control, respectively. Concentrations from 140 to 150 microg/ml had the opposite effect. These results were consistent with previous reports on the effects of REEs on plant growth. It was concluded that the Ce(III)-induced change of mitochondrial metabolic activity is a possible mechanism by which Ce(III) influenced indice rice 9311 growth. PMID:18649319

  17. Magnetic zenith effect in the ionospheric modification by an X-mode HF heater wave

    NASA Astrophysics Data System (ADS)

    Blagoveshchenskaya, N. F.; Borisova, T. D.; Haggstrom, I.; Rietveld, M. T.; Yeoman, T. K.

    2013-12-01

    We report experimental results aimed at an investigation of the magnetic zenith effect in the high latitude ionosphere F region from ionospheric modification by powerful HF heater wave with X-polarization. The ionospheric modification was produced by the HF heating facility at Tromsø (Norway) using the phased array with a narrow beam with of 6 degrees. Effective radiated power was varied between 450 and 1000 MW. The HF pump wave radiated in different directions relative to the magnetic field from 90 degrees (vertical) to 78 degrees (magnetic zenith) at frequencies near or above the ordinary-mode critical frequency. The response of the ionosphere plasma to the HF pump wave impact was checked by the UHF incoherent scatter radar located in the immediate vicinity of the HF heater. UHF radar was probing the plasma parameters, such as electron density and temperature (Ne and Te), HF-induced plasma and ion lines in the altitude range from 90 to 600 km. It was running in a scanning mode when UHF radar look angles were changed from 74 to 90 degrees by 1 or 2 degree step. It was clearly demonstrated that the strongest heater-induced effects took place in the magnetic field-aligned direction when HF pointing was also to the magnetic zenith. It was found that strong Ne enhancement of up to 80 % along magnetic field (artificial density ducts) were excited only under HF pumping towards magnetic zenith. The width of the artificial ducts comes to only 2 degrees. The Ne increases were accompanied by the Te enhancements of up to about 50 %. Less pronounced Te increases were also observed in the directions of 84 and 90 degrees. Strong Ne enhancements can be accompanied by excitation of strong HF-induced plasma and ion lines. Thus experimental results obtained points to the strong magnetic zenith effect due to self-focusing powerful HF radio wave with X-mode polarization.

  18. Current/Pressure Profile Effects on Tearing Mode Stability in DIII-D Hybrid Discharges

    NASA Astrophysics Data System (ADS)

    Kim, K.; Park, J. M.; Murakami, M.; La Haye, R. J.; Na, Yong-Su

    2015-11-01

    It is important to understand the onset threshold and the evolution of tearing modes (TMs) for developing a high-performance steady state fusion reactor. As initial and basic comparisons to determine TM onset, the measured plasma profiles (such as temperature, density, rotation) were compared with the calculated current profiles between a pair of discharges with/without n=1 mode based on the database for DIII-D hybrid plasmas. The profiles were not much different, but the details were analyzed to determine their characteristics, especially near the rational surface. The tearing stability index calculated from PEST3, Δ' tends to increase rapidly just before the n=1 mode onset for these cases. The modeled equilibrium with varying pressure or current profiles parametrically based on the reference discharge is reconstructed for checking the onset dependency on Δ' or neoclassical effects such as bootstrap current. Simulations of TMs with the modeled equilibrium using resistive MHD codes will also be presented and compared with experiments to determine the sensibility for predicting TM onset. Work supported by US DOE under DE-FC02-04ER54698 and DE-AC52-07NA27344.

  19. Thick-wall effects in the theory of resistive wall modes

    SciTech Connect

    Pustovitov, V. D.

    2012-06-15

    Magnetic interaction of the plasma perturbations with the nearby resistive wall is considered as a resistive wall mode (RWM) problem, but with two essential differences from the traditional thin-wall approach. First, the wall is treated as magnetically thick, which means that the skin depth is not assumed larger than the wall thickness. Second, the plasma is allowed to enter the region where the RWM must be deeply unstable without rotation. The latter corresponds to the plasma operation above the no-wall stability limit demonstrated in the DIII-D tokamak [E. J. Strait et al., Phys. Plasmas 11, 2505 (2004)]. It is shown that the rotational stabilization observed in these experiments can be reproduced in this model if the mode is forced to rotate with a frequency above a critical level. The analytical estimates show that this effect (absent in the model based on the thin-wall approximation) is strong at realistic parameters. The model also predicts that the locking of the rotationally stabilized mode gives rise to instability with a growth rate much larger than its thin-wall estimate.

  20. Mode locking effects on the playing frequency for fork fingerings on the clarinet.

    PubMed

    Nederveen, C J; Dalmont, J-P

    2012-01-01

    The non-linear excitation of wind instruments generates higher harmonics of the playing frequency. These higher harmonics are coupled to resonances in the pipe. This is called mode locking. When the pipe modes are not harmonic, the playing frequency shifts away from the fundamental in order to maximize the output. It may go up or down, depending on the position of the modes and the amplitude. The effect is especially manifest for fork fingerings. Three fork fingerings on a clarinet were investigated. They were artificially blown between the threshold and extinction pressure. A time domain simulation was carried out based on a lumped model of the excitation coupled to an input impedance calculated from the instrument dimensions. At low amplitudes the fundamental frequency dominates and the playing frequency is governed by the position of the first peak in the input impedance spectra. At higher blowing pressures the playing frequency shifts. For both blowing and simulation this follows the same pattern. The frequencies predicted by the calculations are higher than the values found by blowing, which may be due to inadequacies in the model description, to uncertainties of the various parameters, as reed stiffness, moving reed area, and the properties of the slit flow. PMID:22280690

  1. [Effect of afforestation modes on soil microbial community and nitrogen functional genes in Hippophae rhamnoides plantation].

    PubMed

    Yang, Dan; Yu, Xuan; Liu, Xu; Liu, Jin-liana; Zhang, Shun-xiang; Yu, Ze-qun

    2015-12-01

    The study aimed to assess the effect of different afforestation modes on microbial composition and nitrogen functional genes in soil. Soil samples from a pure Hippophae rhamnoides stand (SS) and three mixed stands, namely, H. rhamnoides and Pinus tabuliformis (SY), H. rhamnoides and Platycladus orientalis (SB), H. rhamnoides and Robinia pseucdoacacia (SC) were selected. The results showed that the total PLFA (TPLFA), bacterial PLFA, gram positive bacterial PLFA (G⁺PLFA) were significantly higher in soil samples from other three stands than those of the pure one. However, no significant difference was found for fungal PLFA among them. The abundance of nifH, amoA, nirK and narG genes were higher in SY and SC than in SS. The TPLFA, G⁺PLFA, gram negative bacterial PLFA (G⁻PLFA), and all of the detected gene abundance were significantly and positively correlated with soil pH, total organic carbon, total nitrogen, ammonium nitrogen and available potassium. Afforestation modes affected indirectly soil microbial composition and functional genes through soil properties. Mixing P. tabuliformis or P. orientalis with H. rhamnoides might be suitable afforestation modes, which might improve soil quality. PMID:27111999

  2. Effects of driving mode on the performance of multiple-chamber piezoelectric pumps with multiple actuators

    NASA Astrophysics Data System (ADS)

    Zhang, Zhonghua; Kan, Junwu; Wang, Shuyun; Wang, Hongyun; Ma, Jijie; Jiang, Yonghua

    2015-09-01

    Due to the limited output capability of piezoelectric diaphragm pumps, the driving voltage is frequently increased to obtain the desired output. However, the excessive voltage application may lead to a large deformation in the piezoelectric ceramics, which could cause it to breakdown or become damaged. Therefore, increasing the number of chambers to obtain the desired output is proposed. Using a check-valve quintuple-chamber pump with quintuple piezoelectric actuators, the characteristics of the pump under different driving modes are investigated through experiments. By changing the number and connection mode of working actuators, pump performances in terms of flow rate and backpressure are tested at a voltage of 150 V with a frequency range of 60 Hz -400 Hz. Experiment results indicate that the properties of the multiple-chamber pump change significantly with distinct working chambers even though the number of pumping chambers is the same. Pump performance declines as the distance between the working actuators increases. Moreover, pump performance declines dramatically when the working piezoelectric actuator closest to the outlet is involved. The maximum backpressures of the pump with triple, quadruple, and quintuple actuators are increased by 39%, 83%, and 128%, respectively, compared with the pump with double working actuators; the corresponding maximum flow rates of the pumps are simply increased by 25.9%, 49.2%, and 67.8%, respectively. The proposed research offers practical guidance for the effective utilization of the multiple-chamber pumps under different driving modes.

  3. Self-recovery effect of orbital angular momentum mode of circular beam in weak non-Kolmogorov turbulence.

    PubMed

    Zhang, Tao; Liu, Yi-Dong; Wang, Jiandong; Liu, Pusheng; Yang, Yuanjie

    2016-09-01

    It is generally true that the orbital angular momentum (OAM) mode persistently degenerate when a vortex beam propagates in the atmospheric turbulence. Here, however, we unveil an interesting self-recovery effect of OAM mode of the circular beam (CiB) in weak non-Kolmogorov turbulence. We show that the CiB displays the self-focusing effect and has clear focus in the weak non-Kolmogorov turbulence if we choose proper complex parameters, and the detection probability of the original OAM mode reaches the maximum at the focus. Our study proposes a method to alleviate the turbulent effects on OAM-based communication. PMID:27607655

  4. Application of failure mode and effect analysis in a radiology department.

    PubMed

    Thornton, Eavan; Brook, Olga R; Mendiratta-Lala, Mishal; Hallett, Donna T; Kruskal, Jonathan B

    2011-01-01

    With increasing deployment, complexity, and sophistication of equipment and related processes within the clinical imaging environment, system failures are more likely to occur. These failures may have varying effects on the patient, ranging from no harm to devastating harm. Failure mode and effect analysis (FMEA) is a tool that permits the proactive identification of possible failures in complex processes and provides a basis for continuous improvement. This overview of the basic principles and methodology of FMEA provides an explanation of how FMEA can be applied to clinical operations in a radiology department to reduce, predict, or prevent errors. The six sequential steps in the FMEA process are explained, and clinical magnetic resonance imaging services are used as an example for which FMEA is particularly applicable. A modified version of traditional FMEA called Healthcare Failure Mode and Effect Analysis, which was introduced by the U.S. Department of Veterans Affairs National Center for Patient Safety, is briefly reviewed. In conclusion, FMEA is an effective and reliable method to proactively examine complex processes in the radiology department. FMEA can be used to highlight the high-risk subprocesses and allows these to be targeted to minimize the future occurrence of failures, thus improving patient safety and streamlining the efficiency of the radiology department. PMID:20980666

  5. NON-WKB MODELS OF THE FIRST IONIZATION POTENTIAL EFFECT: THE ROLE OF SLOW MODE WAVES

    SciTech Connect

    Laming, J. Martin

    2012-01-10

    A model for element abundance fractionation between the solar chromosphere and corona is further developed. The ponderomotive force due to Alfven waves propagating through or reflecting from the chromosphere in solar conditions generally accelerates chromospheric ions, but not neutrals, into the corona. This gives rise to what has become known as the first ionization potential effect. We incorporate new physical processes into the model. The chromospheric ionization balance is improved and the effect of different approximations is discussed. We also treat the parametric generation of slow mode waves by the parallel propagating Alfven waves. This is also an effect of the ponderomotive force, arising from the periodic variation of the magnetic pressure driving an acoustic mode, which adds to the background longitudinal pressure. This can have subtle effects on the fractionation, rendering it quasi-mass independent in the lower regions of the chromosphere. We also briefly discuss the change in the fractionation with Alfven wave frequency, relative to the frequency of the overlying coronal loop resonance.

  6. U(SMes*)n, (n = 3, 4) and Ln(SMes*)3 (Ln = La, Ce, Pr, Nd): lanthanide(III)/actinide(III) differentiation in agostic interactions and an unprecedented eta3 ligation mode of the arylthiolate ligand, from X-ray diffraction and DFT analysis.

    PubMed

    Roger, Mathieu; Barros, Noémi; Arliguie, Thérèse; Thuéry, Pierre; Maron, Laurent; Ephritikhine, Michel

    2006-07-12

    Reaction of U(NEt(2))(4) with HS-2,4,6-(t)Bu(3)C(6)H(2) (HSMes) gave U(SMes)(3)(NEt(2))(py) (1), whereas similar treatment of U[N(SiMe(3))SiMe(2)CH(2)][N(SiMe(3))(2)](2) afforded U(SMes)[N(SiMe(3))(2)](3) (2) and U(SMes)(3)[N(SiMe(3))(2)]. The first neutral homoleptic uranium(IV) thiolate to have been crystallographically characterized, U(SMes)(4) (4), was isolated from the reaction of U(BH(4))(4) and KSMes. The first homoleptic thiolate complex of uranium(III), U(SMes)(3) (5), was synthesized by protonolysis of U[N(SiMe(3))(2)](3) with HSMes in cyclohexane. The crystal structure of 5 exhibits the novel eta(3) ligation mode for the arylthiolate ligand. Comparison of the crystal structure of 5 with those of the isomorphous lanthanide congeners Ln(SMes)(3) (Ln = La, Ce, Pr, and Nd) indicates that the U-S, U-C(ipso)(), and U-C(ortho)() bond lengths are shorter than the corresponding ones in the 4f-element analogues, when taking into account the variation in the ionic radii of the metals. The distance between the uranium and the carbon atoms involved in the U...H-C epsilon agostic interaction of each thiolate ligand is shorter, by approximately 0.05 A, than that expected from a purely ionic bonding model. The lanthanide(III)/actinide(III) differentiation was analyzed by density functional theory (DFT). The nature of the M-S bond is shown to be ionic strongly polarized at the sulfur for M = U and iono-covalent (i.e. strongly ionic with low orbital interaction), for M = Ln. The strength of the U...H-C epsilon agostic interaction is proposed to be controlled by the maximization of the interaction between U(+) and S(-) under steric constraints. The eta(3) ligation mode of the arylthiolate ligand is also obtained from DFT. PMID:16819872

  7. Environmental influence on the single-molecule magnet behavior of [Mn(III)6Cr(III)]3+: molecular symmetry versus solid-state effects.

    PubMed

    Hoeke, Veronika; Heidemeier, Maik; Krickemeyer, Erich; Stammler, Anja; Bögge, Hartmut; Schnack, Jürgen; Postnikov, Andrei; Glaser, Thorsten

    2012-10-15

    The structural, spectroscopic, and magnetic properties of a series of [Mn(III)(6)Cr(III)](3+) (= [{(talen(t-Bu(2)))Mn(III)(3)}(2){Cr(III)(CN)(6)}](3+)) compounds have been investigated by single-crystal X-ray diffraction (XRD), Fourier transform infrared (FT-IR) and electronic absorption spectroscopy, elemental analysis, electro spray ionization-mass spectrometry (ESI-MS) and matrix-assisted laser desorption ionization-mass spectrometry (MALDI-MS), cyclic voltammetry, AC and DC magnetic measurements, as well as theoretical analysis. The crystal structures obtained with [Cr(III)(CN)(6)](3-) as a counterion exhibit (quasi-)one-dimensional (1D) chains formed by hydrogen-bonded (1) or covalently linked (2) trications and trianions. The rod-shaped anion lactate enforces a rod packing of the [Mn(III)(6)Cr(III)](3+) complexes in the highly symmetric space group R3[overline] (3) with a collinear arrangement of the molecular S(6) axes. Incorporation of the spherical anion BPh(4)(-) leads to less-symmetric crystal structures (4-6) with noncollinear orientations of the [Mn(III)(6)Cr(III)](3+) complexes, as evidenced by the angle between the approximate molecular C(3) axes taking no specific values in the range of 2°-69°. AC magnetic measurements on freshly isolated crystals (1a and 3a-6a), air-dried crystals (3b-6b), and vacuum-dried powder samples (3c-6c) indicate single-molecule magnet (SMM) behavior for all samples with U(eff) values up to 28 K. The DC magnetic data are analyzed by a full-matrix diagonalization of the appropriate spin-Hamiltonian including isotropic exchange, zero-field splitting, and Zeeman interaction, taking into account the relative orientation of the D-tensors. Simulations for 3a-6a and 3c-6c indicate a weak antiferromagnetic exchange between the Mn(III) ions in the trinuclear subunits (J(Mn-Mn) = -0.70 to -0.85 cm(-1), Ĥ(ex) = -2∑(i

  8. The properties of the extraordinary mode and surface plasmon modes in the three-dimensional magnetized plasma photonic crystals based on the magneto-optical Voigt effects

    NASA Astrophysics Data System (ADS)

    Zhang, Hai-Feng; Liu, Shao-Bin; Tang, Yi-Jun

    2014-06-01

    In this paper, the properties of the extraordinary mode and surface plasmon modes in the three-dimensional (3D) magnetized plasma photonic crystals (MPPCs) with face-centered-cubic lattices that are composed of the core tellurium (Te) spheres with surrounded by the homogeneous magnetized plasma shells inserted in the air, are theoretically investigated in detail by the plane wave expansion method, as the magneto-optical Voigt effects of magnetized plasma are considered (the incidence electromagnetic wave vector is perpendicular to the external magnetic field at any time). The optical switching or wavelength division multiplexer can be realized by the proposed 3D MPPCs. Our analyses demonstrate that the complete photonic band gaps (PBGs) and two flatbands regions for the extraordinary mode can be observed obviously. PBGs can be tuned by the radius of core Te sphere, the plasma density and the external magnetic field. The flatbands regions are determined by the existence of surface plasmon modes. Numerical simulations also show that if the thickness of magnetized plasma shell is larger than a threshold value, the band structures of the extraordinary mode will be similar to those obtained from the same structure containing the pure magnetized plasma spheres. In this case, the band structures also will not be affected by the inserted core spheres. It is also provided that the upper edges of two flatbands regions will not depend on the topology of lattice. However, the frequencies of lower edges of two flatbands regions will be convergent to the different constants for different lattices, as the thickness of magnetized plasma shell is close to zero.

  9. The properties of the extraordinary mode and surface plasmon modes in the three-dimensional magnetized plasma photonic crystals based on the magneto-optical Voigt effects

    SciTech Connect

    Zhang, Hai-Feng E-mail: lsb@nuaa.edu.cn; Liu, Shao-Bin E-mail: lsb@nuaa.edu.cn; Tang, Yi-Jun

    2014-06-15

    In this paper, the properties of the extraordinary mode and surface plasmon modes in the three-dimensional (3D) magnetized plasma photonic crystals (MPPCs) with face-centered-cubic lattices that are composed of the core tellurium (Te) spheres with surrounded by the homogeneous magnetized plasma shells inserted in the air, are theoretically investigated in detail by the plane wave expansion method, as the magneto-optical Voigt effects of magnetized plasma are considered (the incidence electromagnetic wave vector is perpendicular to the external magnetic field at any time). The optical switching or wavelength division multiplexer can be realized by the proposed 3D MPPCs. Our analyses demonstrate that the complete photonic band gaps (PBGs) and two flatbands regions for the extraordinary mode can be observed obviously. PBGs can be tuned by the radius of core Te sphere, the plasma density and the external magnetic field. The flatbands regions are determined by the existence of surface plasmon modes. Numerical simulations also show that if the thickness of magnetized plasma shell is larger than a threshold value, the band structures of the extraordinary mode will be similar to those obtained from the same structure containing the pure magnetized plasma spheres. In this case, the band structures also will not be affected by the inserted core spheres. It is also provided that the upper edges of two flatbands regions will not depend on the topology of lattice. However, the frequencies of lower edges of two flatbands regions will be convergent to the different constants for different lattices, as the thickness of magnetized plasma shell is close to zero.

  10. Effects of commuting mode on air pollution exposure and cardiovascular health among young adults in Taipei, Taiwan.

    PubMed

    Liu, Wen-Te; Ma, Chih-Ming; Liu, I-Jung; Han, Bor-Cheng; Chuang, Hsiao-Chi; Chuang, Kai-Jen

    2015-05-01

    The association between traffic-related air pollution and adverse cardiovascular effects has been well documented; however, little is known about whether different commuting modes can modify the effects of air pollution on the cardiovascular system in human subjects in urban areas with heavy traffic. We recruited 120 young, healthy subjects in Taipei, Taiwan. Each participant was classified with different commuting modes according to his/her own commuting style. Three repeated measurements of heart rate variability (HRV) indices {standard deviation of NN intervals (SDNN) and the square root of the mean of the sum of the squares of differences between adjacent NN intervals (r-MSSD)}, particulate matter with an aerodynamic diameter ≤ 2.5 μm (PM2.5), temperature, humidity and noise level were conducted for each subject during 1-h morning commutes (0900-1000 h) in four different commuting modes, including an electrically powered subway, a gas-powered bus, a gasoline-powered car, and walking. Linear mixed-effects models were used to investigate the association of PM2.5 with HRV indices. The results showed that decreases in the HRV indices were associated with increased levels of PM2.5. The personal exposure levels to PM2.5 were the highest in the walking mode. The effects of PM2.5 on cardiovascular endpoints were the lowest in the subway mode compared to the effects in the walking mode. The participants in the car and bus modes had reduced effects on their cardiovascular endpoints compared to the participants in the walking mode. We concluded that traffic-related PM2.5 is associated with autonomic alteration. Commuting modes can modify the effects of PM2.5 on HRV indices among young, healthy subjects. PMID:25638696

  11. Effects of gelatin sponge combined with moist wound-healing nursing intervention in the treatment of phase III bedsore

    PubMed Central

    LI, YANLING; YAO, MEIYING; WANG, XIA; ZHAO, YANQING

    2016-01-01

    Pressure sore pertains to tissue damage or necrosis that occurs due to lack of adequate nutrition following long-term exposure to pressure and decreased blood circulation. The aim of the study was to examine the effects of gelatin sponge combined with moist wound-healing nursing intervention in the treatment of phase III bedsore. In total, 50 patients with phase III bedsore were included in the present study. The patients were randomly divided into the control (n=25) and observation (n=25) groups. Patients in the control group received conventional nursing, while those in the observation group received gelatin sponge combined with moist wound healing nursing. The effects of the two nursing methods were compared and analyzed. The results showed that the improvement rate of the observation group was significantly higher than that of the control group (P<0.05). The Branden score and area of pressure sore of the observation group were significantly lower than those of the control group (P<0.05). The frequency and time of dressing change and the average cost of hospitalization of the observation group were significantly lower than those of the control group (P<0.001). In conclusion, gelatin sponge combined with moist wound-healing nursing intervention may significantly improve the treatment of phase III bedsore. PMID:27313666

  12. Ligand steric effects on the photophysics of bis- and tris(2,2'-bipyridine) complexes of rhodium(III)

    SciTech Connect

    Nishizawa, M.; Suzuki, T.M.; Sprouse, S.; Watts, R.J.; Ford, P.C.

    1984-06-20

    The effects of 3,3'-dimethyl steric interactions on the luminescence of 2,2'-bipyridine complexes of rhodium(III) have been investigated. The tris complex, Rh(dmbpy)/sub 3//sup 3 +/, is found is display both metal-centered and ligand-centered emissions. The metal-centered emission is the dominant luminescence feature at 77 K, but the ligand-centered emission is enhanced relative to the metal-centered luminescence in fluid solutions. The bis complex, Rh(dmbpy)/sub 2/Cl/sub 2//sup +/, displays a dominant ligand field emission under all conditions that were studied. Reinvestigation of the luminescence of the tris(1,10-phenanthroline) and tris(2,2'-bipyridine) complexes of Rh(III) in fluid solutions indicates that these species emit only from ligand-centered excited states. Comparison of the 3,3'-dimethyl-2,2'-bipyridine and unsubstituted 2,2'-bipyridine complexes of Rh(III) indicates that both ligand-centered and metal-centered excited states have lower energies for the methyl-substituted complexes but the effect if larger for the metal-centered states. 21 references, 7 figures, 1 table.

  13. Proteomic and metabolomic analysis on the toxicological effects of As (III) and As (V) in juvenile mussel Mytilus galloprovincialis.

    PubMed

    Yu, Deliang; Ji, Chenglong; Zhao, Jianmin; Wu, Huifeng

    2016-05-01

    Inorganic arsenic (As) is a known pollutant including two chemical forms (arsenite (As III) and arsenate (As V)), in marine and coastal environment. Marine mussel Mytilus galloprovincialis is an important environmental monitoring species around the world. In this study, we focused on valence-specific responses of As in juvenile mussel M. galloprovincialis using a combined proteomic and metabolomic approach. Metabolic responses indicated that As (III) mainly caused disturbance in osmotic regulation in juvenile mussels. As (V) caused disturbances in both osmotic regulation and energy metabolism marked by different metabolic responses, including betaine, taurine, glucose and glycogen. Proteomic responses exhibited that As (III) had a significant negative effect on cytoskeleton and cell structure (actin and collagen alpha-6(VI) chain). As (V) affected some key enzymes involved in energy metabolism (cytosolic malate dehydrogenase, cMDH) and cell development (ornithine aminotransferase and astacin). Overall, all these results confirmed the valence-specific responses in juvenile mussels to As exposures. These findings demonstrate that a combined metabolomic and proteomic approach could provide an important insight into the toxicological effects of environmental pollutants in organisms. PMID:26901476

  14. The confounding effects of light, sonication, and Mn(III)TBAP on quantitation of superoxide using hydroethidine.

    PubMed

    Zielonka, Jacek; Vasquez-Vivar, Jeannette; Kalyanaraman, B

    2006-10-01

    Previously, we showed that hydroethidine (HE) reacts with intracellular superoxide radical anion (O2-*) to form a unique fluorescent marker product, 2-hydroxyethidium cation (2-OH-E+), that was not formed from HE reaction with other biologically relevant oxidants (H. Zhao et al. Proc. Natl. Acad. Sci. USA102:5727-5732; 2005). Here we rigorously assessed the confounding effects of light, sonication, and Mn(III)TBAP on 2-OH-E+, the HE/O2-* reaction product. Results indicate that continuous exposure to visible light induced photo-oxidation of HE to ethidium cation (E+) by a 2-OH-E+ -dependent mechanism. Treatment of HE with ultrasound, a frequently used technique to lyse cell membranes, induced 2-OH-E+ from in situ generation of O2-*. Mn(III)TBAP, a cell-permeable metal-porphyrin complex used as a catalytic antioxidant, reacts with HE to form E+. This finding provides an alternative interpretation for Mn(III)TBAP effects during the HE/O2-* reaction. In order to correctly interpret the HE reaction with O2-* in cells, it is therefore imperative that HE and HE-derived products be measured by HPLC. A new and improved HPLC-electrochemical (HPLC-EC) detection has been developed for analysis of intracellular O2-*. The HPLC-EC method is at least 10 times more sensitive than the HPLC-fluorescence technique for detecting O2-* in cells. PMID:16962930

  15. A Review of Healthcare Failure Mode and Effects Analysis (HFMEA) in Radiotherapy.

    PubMed

    Giardina, M; Cantone, M C; Tomarchio, E; Veronese, I

    2016-10-01

    This paper presents a review of risk analyses in radiotherapy (RT) processes carried out by using Healthcare Failure Mode Effect Analysis (HFMEA) methodology, a qualitative method that proactively identifies risks to patients and corrects medical errors before they occur. This literature review was performed to provide an overview of how to approach the development of HFMEA applications in modern RT procedures, comparing recently published research conducted to support proactive programs to identify risks. On the basis of the reviewed literature, the paper suggests HFMEA shortcomings that need to be addressed. PMID:27575344

  16. Effects of range and mode on lifting capability and lifting time.

    PubMed

    Lee, Tzu-Hsien

    2012-01-01

    This study examined the effects of 3 lifting ranges and 3 lifting modes on maximum lifting capability and total lifting time. The results demonstrated that the maximum lifting capability for FK (from floor to knuckle height) was greater than that for KS (from knuckle height to shoulder height) or FS (from floor to shoulder height). Additionally, asymmetric lifting with initial trunk rotation decreased maximum lifting capability compared with symmetric lifting or asymmetric lifting with final trunk rotation. The difference in total lifting time between KS and FS was not significant, while FK increased total lifting time by ~20% compared with FS even though the travel distance was 50% shorter. PMID:22995136

  17. Bonding and Anti-bonding Modes of Plasmon Coupling Effects in TiO2-Ag Core-shell Dimers

    NASA Astrophysics Data System (ADS)

    Li, Quanshui; Zhang, Zhili

    2016-01-01

    Bonding and anti-bonding modes of plasmon coupling effects are numerically investigated in TiO2-Ag core-shell nano dimers. First, splitting phenomena of the coupled anti-bonding modes are observed under the longitudinal polarization when the distance between the monomers decreases to a certain level. Second, one of the split resonance modes is identified to be formed by the dipole anti-bonding mode of the monomers from charge density distribution patterns. Those split modes have similar redshift behaviors as the coupled dipole bonding modes in the same situations. Furthermore, the intensities of those anti-bonding modes weaken with decreasing distance between the monomers, because of the interaction of the induced dipole moment in the monomers and the charge distribution variation on the facing surfaces of the gap by the coulomb attraction. Other split bands are the higher-order mode (octupole-like or triakontadipole-like), which do not have obvious peak-shift behavior, and the intensities have very little attenuation with decreasing distance. Finally, the coupling of the bonding and anti-bonding modes under the longitudinal polarization is symmetric (bonding).

  18. Bonding and Anti-bonding Modes of Plasmon Coupling Effects in TiO2-Ag Core-shell Dimers

    PubMed Central

    Li, Quanshui; Zhang, Zhili

    2016-01-01

    Bonding and anti-bonding modes of plasmon coupling effects are numerically investigated in TiO2-Ag core-shell nano dimers. First, splitting phenomena of the coupled anti-bonding modes are observed under the longitudinal polarization when the distance between the monomers decreases to a certain level. Second, one of the split resonance modes is identified to be formed by the dipole anti-bonding mode of the monomers from charge density distribution patterns. Those split modes have similar redshift behaviors as the coupled dipole bonding modes in the same situations. Furthermore, the intensities of those anti-bonding modes weaken with decreasing distance between the monomers, because of the interaction of the induced dipole moment in the monomers and the charge distribution variation on the facing surfaces of the gap by the coulomb attraction. Other split bands are the higher-order mode (octupole-like or triakontadipole-like), which do not have obvious peak-shift behavior, and the intensities have very little attenuation with decreasing distance. Finally, the coupling of the bonding and anti-bonding modes under the longitudinal polarization is symmetric (bonding). PMID:26763719

  19. Environmental context effects on episodic memory are dependent on retrieval mode and modulated by neuropsychological status.

    PubMed

    Barak, Ohr; Vakil, Eli; Levy, Daniel A

    2013-01-01

    Contextual change or constancy between occasions of memory formation and retrieval are commonly assumed to affect retrieval success, yet such effects may be inconsistent, and the processes leading to the pattern of effects are still not well understood. We conducted a systematic investigation of environmental context effects on memory, using a range of materials (common objects, pictures of familiar and unfamiliar faces, words, and sentences), and four types of retrieval (free recall, cued recall, recognition, and order memory), all assessed within participants. Additionally, we examined the influence of mnemonic challenge on context effects by examining both healthy participants and a group of patients in rehabilitation following traumatic brain injury (TBI). We found no effects of contextual factors on tests of recognition for either group of participants, but effects did emerge for cued and free recall, with the most prominent effects being on memory for objects. Furthermore, while patients' memory abilities in general were impaired relative to the comparison group, they exhibited greater influences of contextual reinstatement on several recall tasks. These results support suggestions that environmental context effects on memory are dependent on retrieval mode and on the extent to which retrieval is challenging because of neurocognitive status. Additionally, findings of environmental context effects in memory-impaired TBI patients suggest that by harnessing such preserved indirect memory (e.g., using reminder technologies), it may be possible to ameliorate TBI patients' difficulties in explicit remembering. PMID:23480476

  20. Size and Geometry Effects on Rock Fracture Toughness: Mode I Fracture

    NASA Astrophysics Data System (ADS)

    Ayatollahi, M. R.; Akbardoost, J.

    2014-03-01

    In this paper, the effects of specimen size and geometry on the apparent mode I fracture toughness ( K c) of an Iranian white marble (Neyriz) are studied. A number of fracture tests were conducted on center-cracked circular disk (CCCD) specimens with different radii to investigate the size effects on K c. The experimental results demonstrate that the apparent fracture toughness increases in bigger specimens. In order to explain the experimental results, the modified maximum tangential stress (MMTS) criterion is used, where higher order terms of the Williams' series expansion are included in the maximum tangential stress criterion. It is shown that the MMTS criterion provides good estimates for the apparent fracture toughness of Neyriz marble, obtained from fracture tests of edge-cracked triangular specimens. It is, therefore, concluded that the proposed criterion is able to account for the size and geometry effects on the fracture resistance of rocks simultaneously.