Science.gov

Sample records for municipal residue biomass

  1. Utilization of residual forest biomass

    SciTech Connect

    Hakkila, P.

    1989-01-01

    The first world-wide energy crisis in the early 1970s resulted in an explosive increase in both the number and diversity of studies on unmerchantable tree components such as tops, branches, foliage, stumps, and roots, and on whole small-sized trees. This book presents a synopsis and the latest information on forest biomass utilization and the potential of this renewable raw material resource, presented from an interdisciplinary viewpoint. This balanced review of scientific literature as well as recent practical developments and experience in forest biomass utilization covers various aspects of quantity and properties of the resource, harvesting and transport, ecological consequences of intensive biomass recovery, comminution and upgrading, utilization for pulp, paper, composite boards, fodder, and energy in solid, liquid, or gaseous form.

  2. Municipal wastewater treatment by a periodic biofilter with granular biomass.

    PubMed

    Di Iaconi, C; Del Moro, G; Lopez, A; De Sanctis, M; Ramadori, R

    2008-01-01

    The paper reports the results obtained during an experimental campaign aimed at transferring aerobic granulation to a demonstrative SBBGR system (i.e., a submerged biofilter that operates in a "fill and draw" mode) for the treatment of municipal wastewater by financial support of the European Commission, within the framework of Life-Environment Programme (PERBIOF Project; www.perbiof-europe.com). The results show that following the generation of granular biomass during the start-up period, the SBBGR was able to remove 80-90% of COD, total suspended solids and ammonia occurring in primary effluent from a municipal wastewater treatment plant even when the minimum hydraulic residence time (i.e., 4 h) was investigated. The process was characterised by a sludge production almost one magnitude order lower than commonly reported for conventional treatment plants. The granular biomass was characterised by a high density (i.e., 150 gTSS/L(biomass)) that allowed a biomass concentration as high as 35 kgTSS/m(3)(bed) to be achieved. Proteobacteria were found as main microbial components of the granular biomass by applying Fluorescence In Situ Hybridization (FISH). No significant changes in microbial composition were observed during reactor operation. PMID:19092218

  3. Winter crop and residue biomass potential in China

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This paper estimates the potential biomass production from winter crops and summer crop residues in China. Rye is used to represent winter crop production, and straw from corn, wheat and rice is used to represent residue potential. Biomass totals are intended for use as energy feedstocks and are ass...

  4. Gaseous emissions during concurrent combustion of biomass and non-recyclable municipal solid waste

    PubMed Central

    2011-01-01

    Background Biomass and municipal solid waste offer sustainable sources of energy; for example to meet heat and electricity demand in the form of combined cooling, heat and power. Combustion of biomass has a lesser impact than solid fossil fuels (e.g. coal) upon gas pollutant emissions, whilst energy recovery from municipal solid waste is a beneficial component of an integrated, sustainable waste management programme. Concurrent combustion of these fuels using a fluidised bed combustor may be a successful method of overcoming some of the disadvantages of biomass (high fuel supply and distribution costs, combustion characteristics) and characteristics of municipal solid waste (heterogeneous content, conflict with materials recycling). It should be considered that combustion of municipal solid waste may be a financially attractive disposal route if a 'gate fee' value exists for accepting waste for combustion, which will reduce the net cost of utilising relatively more expensive biomass fuels. Results Emissions of nitrogen monoxide and sulphur dioxide for combustion of biomass are suppressed after substitution of biomass for municipal solid waste materials as the input fuel mixture. Interactions between these and other pollutants such as hydrogen chloride, nitrous oxide and carbon monoxide indicate complex, competing reactions occur between intermediates of these compounds to determine final resultant emissions. Conclusions Fluidised bed concurrent combustion is an appropriate technique to exploit biomass and municipal solid waste resources, without the use of fossil fuels. The addition of municipal solid waste to biomass combustion has the effect of reducing emissions of some gaseous pollutants. PMID:21284885

  5. Partial stream digestion of residual municipal solid waste.

    PubMed

    De Baere, L

    2008-01-01

    Anaerobic digestion of residual municipal solid waste (MSW) has become more important than the digestion of source separated biowaste. More than 52% of the capacity available in Europe was designed for digestion of residual municipal waste by the end of 2006, while this was only 13% in 1998. Partial digestion of residual waste organics, by which only a part of the organics is digested, has been implemented to reduce the need for dewatering and subsequent wastewater treatment. The digestate coming from part of the organics is immediately mixed with the non-digested organic fraction. This organic fraction is drier and still contains a lot of energy which can be used to dry the digestate during the aerobic composting of the mixture of digested and undigested organics. Such a MBT-plant has been operating for over a year whereby 2/3 of the organics (including sludge cake) are digested (25,000 t/year) and mixed after digestion with the remaining 1/3 of the organics. Biogas production averages 125.7 Nm2 per ton fed and contained 56.2% of methane. The mixture of digestate and non-digested organics is aerated in tunnels during 4 to 6 weeks. The stabilized end product is landfilled, meeting the stringent German standards for inert landfills. By using a dry fermentation able to produce a digestate at 35% solids, there is no need for dewatering the digestate so that no wastewater is produced. PMID:18441435

  6. VITRIFICATION OF MUNICIPAL SOLID WASTE COMBUSTION AIR POLLUTION CONTROL RESIDUES USING CORNING, INC. PROCESS

    EPA Science Inventory

    A demonstration was conducted to vitrify municipal solid waste (MSW) combustor air pollution control residue (APC) under the USEPA Municipal Waste Innovative Technology Evaluation Program. uplicate demonstration was conducted using a process developed by Corning Inc. in a cold cr...

  7. Quantification and characterization of cotton crop biomass residue

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Cotton crop residual biomass remaining in the field after mechanical seed cotton harvest is not typically harvested and utilized off-site thereby generating additional revenue for producers. Recently, interest has increased in utilizing biomass materials as feedstock for the production of fuel and ...

  8. Effect of thermal pretreatment on the physical and chemical properties of municipal biomass waste.

    PubMed

    Liu, Xiao; Wang, Wei; Gao, Xingbao; Zhou, Yingjun; Shen, Renjie

    2012-02-01

    The effects of thermal pretreatment on the physical and chemical properties of three typical municipal biomass wastes (MBWs), kitchen waste (KW), vegetable/fruit residue (VFR), and waste activated sludge (WAS) were investigated. The results show that thermal pretreatment at 175 °C/60 min significantly decreases viscosity, improves the MBW dewatering performance, as well as increases soluble chemical oxygen demand, soluble sugar, soluble protein, and especially organic compounds with molecular weights >10 kDa. For KW, VFR and WAS, 59.7%, 58.5% and 25.2% of the organic compounds can be separated in the liquid phase after thermal treatment. WAS achieves a 34.8% methane potential increase and a doubled methane production rate after thermal pretreatment. In contrast, KW and VFR show 7.9% and 11.7% methane decrease because of melanoidin production. PMID:22030278

  9. EPA RE-Powering America's Lands: Kansas City Municipal Farm Site -- Biomass Power Analysis

    SciTech Connect

    Hunsberger, R.; Mosey, G.

    2015-01-01

    Through the RE-Powering America's Land initiative, the economic and technical feasibility of utilizing biomass at the Kansas City, Missouri, Municipal Farm site, a group of City-owned properties, is explored. The study that none of the technologies we reviewed--biomass heat, power and CHP--are economically viable options for the Municipal Farms site. However, if the site were to be developed around a future central biomass heating or CHP facility, biomass could be a good option for the site.

  10. COMPACTING BIOMASS AND MUNICIPAL SOLID WASTES TO FORM AND UPGRADED FUEL

    SciTech Connect

    Henry Liu; Yadong Li

    2000-11-01

    Biomass waste materials exist in large quantity in every city and in numerous industrial plants such as wood processing plants and waste paper collection centers. Through minimum processing, such waste materials can be turned into a solid fuel for combustion at existing coal-fired power plants. Use of such biomass fuel reduces the amount of coal used, and hence reduces the greenhouse effect and global warming, while at the same time it reduces the use of land for landfill and the associated problems. The carbon-dioxide resulting from burning biomass fuel is recycled through plant growth and hence does not contribute to global warming. Biomass fuel also contains little sulfur and hence does not contribute to acid rain problems. Notwithstanding the environmental desirability of using biomass waste materials, not much of them are used currently due to the need to densify the waste materials and the high cost of conventional methods of densification such as pelletizing and briquetting. The purpose of this project was to test a unique new method of biomass densification developed from recent research in coal log pipeline (CLP). The new method can produce large agglomerates of biomass materials called ''biomass logs'' which are more than 100 times larger and 30% denser than conventional ''pellets'' or ''briquettes''. The Phase I project was to perform extensive laboratory tests and an economic analysis to determine the technical and economic feasibility of the biomass log fuel (BLF). A variety of biomass waste materials, including wood processing residues such as sawdust, mulch and chips of various types of wood, combustibles that are found in municipal solid waste stream such as paper, plastics and textiles, energy crops including willows and switch grass, and yard waste including tree trimmings, fallen leaves, and lawn grass, were tested by using this new compaction technology developed at Capsule Pipeline Research Center (CPRC), University of Missouri-Columbia (MU

  11. Combined Municipal Solid Waste and biomass system optimization for district energy applications.

    PubMed

    Rentizelas, Athanasios A; Tolis, Athanasios I; Tatsiopoulos, Ilias P

    2014-01-01

    Municipal Solid Waste (MSW) disposal has been a controversial issue in many countries over the past years, due to disagreement among the various stakeholders on the waste management policies and technologies to be adopted. One of the ways of treating/disposing MSW is energy recovery, as waste is considered to contain a considerable amount of bio-waste and therefore can lead to renewable energy production. The overall efficiency can be very high in the cases of co-generation or tri-generation. In this paper a model is presented, aiming to support decision makers in issues relating to Municipal Solid Waste energy recovery. The idea of using more fuel sources, including MSW and agricultural residue biomass that may exist in a rural area, is explored. The model aims at optimizing the system specifications, such as the capacity of the base-load Waste-to-Energy facility, the capacity of the peak-load biomass boiler and the location of the facility. Furthermore, it defines the quantity of each potential fuel source that should be used annually, in order to maximize the financial yield of the investment. The results of an energy tri-generation case study application at a rural area of Greece, using mixed MSW and biomass, indicate positive financial yield of investment. In addition, a sensitivity analysis is performed on the effect of the most important parameters of the model on the optimum solution, pinpointing the parameters of interest rate, investment cost and heating oil price, as those requiring the attention of the decision makers. Finally, the sensitivity analysis is enhanced by a stochastic analysis to determine the effect of the volatility of parameters on the robustness of the model and the solution obtained. PMID:24140378

  12. Combined Municipal Solid Waste and biomass system optimization for district energy applications

    SciTech Connect

    Rentizelas, Athanasios A. Tolis, Athanasios I. Tatsiopoulos, Ilias P.

    2014-01-15

    Highlights: • Combined energy conversion of MSW and agricultural residue biomass is examined. • The model optimizes the financial yield of the investment. • Several system specifications are optimally defined by the optimization model. • The application to a case study in Greece shows positive financial yield. • The investment is mostly sensitive on the interest rate, the investment cost and the heating oil price. - Abstract: Municipal Solid Waste (MSW) disposal has been a controversial issue in many countries over the past years, due to disagreement among the various stakeholders on the waste management policies and technologies to be adopted. One of the ways of treating/disposing MSW is energy recovery, as waste is considered to contain a considerable amount of bio-waste and therefore can lead to renewable energy production. The overall efficiency can be very high in the cases of co-generation or tri-generation. In this paper a model is presented, aiming to support decision makers in issues relating to Municipal Solid Waste energy recovery. The idea of using more fuel sources, including MSW and agricultural residue biomass that may exist in a rural area, is explored. The model aims at optimizing the system specifications, such as the capacity of the base-load Waste-to-Energy facility, the capacity of the peak-load biomass boiler and the location of the facility. Furthermore, it defines the quantity of each potential fuel source that should be used annually, in order to maximize the financial yield of the investment. The results of an energy tri-generation case study application at a rural area of Greece, using mixed MSW and biomass, indicate positive financial yield of investment. In addition, a sensitivity analysis is performed on the effect of the most important parameters of the model on the optimum solution, pinpointing the parameters of interest rate, investment cost and heating oil price, as those requiring the attention of the decision makers

  13. Metallic elements fractionation in municipal solid waste incineration residues

    NASA Astrophysics Data System (ADS)

    Kowalski, Piotr R.; Kasina, Monika; Michalik, Marek

    2016-04-01

    Municipal solid waste incineration (MSWI) residues are represented by three main materials: bottom ash, fly ash and air pollution control (APC) residues. Among them ˜80 wt% is bottom ash. All of that materials are products of high temperature (>1000° C) treatment of waste. Incineration process allows to obtain significant reduction of waste mass (up to 70%) and volume (up to 90%) what is commonly used in waste management to reduce the amount need to be landfilled or managed in other way. Incineration promote accumulation non-combustible fraction of waste, which part are metallic elements. That type of concentration is object of concerns about the incineration residues impact on the environment and also gives the possibility of attempts to recover them. Metallic elements are not equally distributed among the materials. Several factors influence the process: melting points, volatility and place and forms of metallic occurrence in the incinerated waste. To investigate metallic elements distribution in MSWI residues samples from one of the biggest MSW incineration plant in Poland were collected in 2015. Chemical analysis with emphasis on the metallic elements content were performed using inductively coupled plasma optical emission (ICP-OES) and mass spectrometry (ICP-MS). The bottom ash was a SiO2-CaO-Al2O3-Fe2O3-Na2O rich material, whereas fly ash and APC residues were mostly composed of CaO and SiO2. All of the materials were rich in amorphous phase occurring together with various, mostly silicate crystalline phases. In a mass of bottom ash 11 wt% were metallic elements but also in ashes 8.5 wt% (fly ash) and ˜4.5 wt% (APC residues) of them were present. Among the metallic elements equal distribution between bottom and fly ash was observed for Al (˜3.85 wt%), Mn (770 ppm) and Ni (˜65 ppm). In bottom ash Fe (5.5 wt%), Cr (590 ppm) and Cu (1250 ppm) were concentrated. These values in comparison to fly ash were 5-fold higher for Fe, 3-fold for Cu and 1.5-fold for

  14. Potential of biomass residue availability; The case of Thailand

    SciTech Connect

    Bhattacharya, S.C.; Shrestha, R.M.; Ngamkajornvivat, S. )

    1989-01-01

    An acute shortage of fuel wood and charcoal prevails in many developing countries. A logical approach to the problem places emphasis on the development of alternative energy sources, including use of biomass residues. An assessment of the potential of biomass residues for energy and other uses calls for an estimation of their annual production. Also, because the residues are normally bulky they should be utilized near their place of origin whenever possible to avoid high transportation costs. Thus knowledge of the total national generation of residues per year does not provide enough information for planning residue utilization. This article illustrates a method of residue estimation that takes the case of Thailand as an example. It presents the annual generation of nine agricultural resides (paddy husk, paddy straw, bagasse, cotton stalk, corn cob, groundnut shell, cassava stalk and coconut husk and shell) and one forestry residue (sawdust) in different agroeconomic zones and regions of Thailand. The methodology used for the investigation of crop-to-residue ratios is outlined. The annual generation figures for the different residues along with observations about their traditional uses are presented.

  15. Biofuels and bioenergy production from municipal solid waste commingled with agriculturally-derived biomass

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The USDA in partnership with Salinas Valley Solid Waste Authority (SVSWA) and CR3, a technology holding company from Reno, NV, has introduced a biorefinery concept whereby agriculturally- derived biomass is commingled with municipal solid waste (MSW) to produce bioenergy. This team, which originally...

  16. Effect of Pretreatment on Biomass Residue Structure and the Application of Pyrolysed and Composted Biomass Residues in Soilless Culture

    PubMed Central

    Suo, Linna; Sun, Xiangyang; Jiang, Weijie

    2013-01-01

    The changes in the structural characteristics of biomass residues during pyrolysis and composting were investigated. The biomass residues particles were prepared by pyrolysing at temperatures ranging from 350 to 400. For soilless production of the ornamental plant Anthurium andraeanum, pure sphagnum peat moss (P) has traditionally been used as the growing medium. This use of P must be reduced, however, because P is an expensive and nonrenewable resource. The current study investigated the use of biomass residues as substitutes for P in A. andraeanum production. Plants were grown for 15 months in 10 soilless media that contained different proportions of pyrolysed corn cobs (PC), composted corn cobs (C), pyrolysed garden wastes (PG), and P. Although the media altered the plant nutrient content, A. andraeanum growth, development, and yield were similar with media consisting of 50% P+50% PC, 50% P+35% PC+15% PG, and 100% P. This finding indicates that, when pyrolysed, organic wastes, which are otherwise an environmental problem, can be used to reduce the requirement for peat in the soilless culture of A. andraeanum. PMID:23704995

  17. Potential for electricity generation from biomass residues in Cuba

    SciTech Connect

    Lora, E.S.

    1995-11-01

    The purpose of this paper is the study of the availability of major biomass residues in Cuba and the analysis of the electricity generation potential by using different technologies. An analysis of the changes in the country`s energy balance from 1988 up to date is presented, as well as a table with the availability study results and the energy equivalent for the following biomass residues: sugar cane bagasse and trash, rice and coffee husk, corn an cassava stalks and firewood. A total equivalent of 4.42 10{sup 6} tons/year of fuel-oil was obtained. Possible scenarios for the electricity production increase in the sugar industry are presented too. The analysis is carried out for a high stream parameter CEST and two BIG/GT system configurations. Limitations are introduced about the minimal milling capacity of the sugar mills for each technology. The calculated {open_quotes}real{close_quotes} electricity generation potential for BIG/GT systems, based on GE LM5000 CC gas turbines, an actual cane harvest of 58.0 10{sup 6} tons/year, half the available trash utilization and an specific steam consumption of 210 kg/tc, was 18601,0 GWh/year. Finally different alternatives are presented for low-scale electricity generation based on the other available agricultural residues.

  18. Accumulation and partitioning of biomass, nutrients, and trace elements in switchgrass for phytoremediation of municipal biosolids.

    PubMed

    Jeke, Nicholson N; Zvomuya, Francis; Ross, Lisette

    2016-09-01

    In situ phytoremediation of municipal biosolids is a promising alternative to the land spreading and landfilling of biosolids from end-of-life municipal lagoons. Accumulation and partitioning of dry matter, nitrogen (N), phosphorus (P), and trace elements were determined in aboveground biomass (AGB) and belowground biomass (BGB) of switchgrass (Panicum virgatum L.) to determine the harvest stage that maximizes phytoextraction of contaminants from municipal biosolids. Seedlings were transplanted into 15-L plastic pails containing 3.9 kg (dry wt.) biosolids. Biomass yield components and contaminant concentrations were assessed every 14 days for up to 161 days. Logistic model fits to biomass yield data indicated no significant differences in asymptotic yield between AGB and BGB. Switchgrass partitioned significantly more N and P to AGB than to BGB. Maximum uptake occurred 86 days after transplanting (DAT) for N and 102 DAT for P. Harvesting at peak aboveground element accumulation removed 5% of N, 1.6% of P, 0.2% of Zn, 0.05% of Cd, and 0.1% of Cr initially present in the biosolids. These results will contribute toward identification of the harvest stage that will optimize contaminant uptake and enhance in situ phytoremediation of biosolids using switchgrass. PMID:26940512

  19. Tracking persistent pharmaceutical residues from municipal sewage to drinking water

    NASA Astrophysics Data System (ADS)

    Heberer, Thomas

    2002-09-01

    In urban areas such as Berlin (Germany) with high municipal sewage water discharges and low surface water flows there is a potential risk of drinking water contamination by polar organic compounds when groundwater recharge is used in drinking water production. Thus, some pharmaceutically active compounds (PhACs) are not eliminated completely in the municipal sewage treatment plants (STPs) and they are discharged as contaminants into the receiving waters. In terms of several monitoring studies carried out in Berlin between 1996 and 2000, PhACs such as clofibric acid, diclofenac, ibuprofen, propyphenazone, primidone and carbamazepine were detected at individual concentrations up to the μg/l-level in influent and effluent samples from STPs and in all surface water samples collected downstream from the STPs. Under recharge conditions, several compounds were also found at individual concentrations up to 7.3 μg/l in samples collected from groundwater aquifers near to contaminated water courses. A few of the PhACs were also identified at the ng/l-level in Berlin tap water samples.

  20. Co-combustion of shredder residues and municipal solid waste in a Swedish municipal solid waste incinerator.

    PubMed

    Redin, L A; Hjelt, M; Marklund, S

    2001-12-01

    Incinerating automotive shredder residue (ASR) in order to increase the recovery from end of life vehicles (ELVs) is an attractive option when recycling this material. In this study, incineration combined with energy recovery, was investigated. The incineration experiments, where 20% shredder residue (SR) was burnt with conventional municipal solid waste (MSW), were conducted in a full-scale MSW horizontal grate incinerator. Measurements were made before, during and after the incineration. The results showed some minor increases in the emission levels of raw gases sampled after an electrostatic filter, but almost no significant differences when sampled after a wet scrubber. An increased level of 'non-toxic' metals was detected within the bottom ash. It was concluded that refined SR, in small quantities, is suitable to add to MSW. PMID:12201681

  1. Effects of lipid concentration on anaerobic co-digestion of municipal biomass wastes

    SciTech Connect

    Sun, Yifei; Wang, Dian; Yan, Jiao; Qiao, Wei; Wang, Wei; Zhu, Tianle

    2014-06-01

    Highlights: • Lipid in municipal biomass would not inhibited the anaerobic digestion process. • A lipid concentration of 65% of total VS was the inhibition concentration. • The amount of Brevibacterium decreased with the increasing of the lipid contents. • Long chain fatty acids stacked on the methanogenic bacteria and blocked the mass transfer process. - Abstract: The influence of the lipid concentration on the anaerobic co-digestion of municipal biomass waste and waste-activated sludge was assessed by biochemical methane potential (BMP) tests and by bench-scale tests in a mesophilic semi-continuous stirred tank reactor. The effect of increasing the volatile solid (VS) concentration of lipid from 0% to 75% was investigated. BMP tests showed that lipids in municipal biomass waste could enhance the methane production. The results of bench-scale tests showed that a lipids concentration of 65% of total VS was the inhibition concentration. Methane yields increased with increasing lipid concentration when lipid concentrations were below 60%, but when lipid concentration was set as 65% or higher, methane yields decreased sharply. When lipid concentrations were below 60%, the pH values were in the optimum range for the growth of methanogenic bacteria and the ratios of volatile fatty acid (VFA)/alkalinity were in the range of 0.2–0.6. When lipid concentrations exceeded 65%, the pH values were below 5.2, the reactor was acidized and the values of VFA/alkalinity rose to 2.0. The amount of Brevibacterium decreased with increasing lipid content. Long chain fatty acids stacked on the methanogenic bacteria and blocked the mass transfer process, thereby inhibiting anaerobic digestion.

  2. Improving material and energy recovery from the sewage sludge and biomass residues

    SciTech Connect

    Kliopova, Irina Makarskienė, Kristina

    2015-02-15

    Highlights: • SRF production from 10–40 mm fraction of pre-composted sludge and biomass residues. • The material and energy balance of compost and SRF production. • Characteristics of raw materials and classification of produced SRF. • Results of the efficiency of energy recovery, comparison analysis with – sawdust. - Abstract: Sewage sludge management is a big problem all over the world because of its large quantities and harmful impact on the environment. Energy conversion through fermentation, compost production from treated sludge for agriculture, especially for growing energetic plants, and treated sludge use for soil remediation are widely used alternatives of sewage sludge management. Recently, in many EU countries the popularity of these methods has decreased due to the sewage sludge content (heavy metals, organic pollutions and other hazards materials). This paper presents research results where the possibility of solid recovered fuel (SRF) production from the separate fraction (10–40 mm) of pre-composted materials – sewage sludge from municipal waste water treatment plant and biomass residues has been evaluated. The remaining fractions of pre-composted materials can be successfully used for compost or fertiliser production, as the concentration of heavy metals in the analysed composition is reduced in comparison with sewage sludge. During the experiment presented in this paper the volume of analysed biodegradable waste was reduced by 96%: about 20% of input biodegradable waste was recovered to SRF in the form of pellets with 14.25 MJ kg{sup −1} of the net calorific value, about 23% were composted, the rest – evaporated and discharged in a wastewater. The methods of material-energy balances and comparison analysis of experiment data have been chosen for the environmental impact assessment of this biodegradable waste management alternative. Results of the efficiency of energy recovery from sewage sludge by SRF production and burning

  3. Initial Effects of Differently Treated Biogas Residues from Municipal and Industrial Wastes on Spring Barley Yield Formation.

    PubMed

    Prays, Nadia; Kaupenjohann, Martin

    2016-01-01

    Soil application of biogas residues (BGRs) is important for closing nutrient cycles. This study examined the efficiency and impact on yields and yield formation of solid-liquid separated residues from biodegradable municipal and industrial wastes (bio-waste) in comparison to complete BGRs, nitrification inhibitor, agricultural BGRs, mineral fertilizer and unfertilized plots as control. The experiment was set up as a randomized block design on silt loam Cambisol. Biogas residues from four biogas plants were evaluated. Plants per m², ears per plant, grains per ear and thousand grain weight (TGW) were measured at harvest. Fertilization with BGRs resulted in similar biomass yields compared with mineral fertilizer. Mineral fertilizer (71 dt/ha) and plots fertilized with liquid fraction (59-62 dt/ha) indicated a trend to higher yields than solid fraction or complete BGR due to its high ammonia content. Liquid fractions and fraction with nitrification inhibitor induced fewer plants per m² than corresponding solid and complete variants due to a potential phytotoxicity of high NH4-N concentration during germination. However, barley on plots fertilized with liquid fraction compensated the disadvantages at the beginning during the vegetation period and induced higher grain yields than solid fraction. This was attributable to a higher number of ears per plant and grains per ear. In conclusion, BGRs from biodegradable municipal and industrial wastes can be used for soil fertilization and replace considerable amounts of mineral fertilizer. Our study showed that direct application of the liquid fraction of BGR is the most suitable strategy to achieve highest grain yields. Nevertheless potential phytotoxicity of the high NH4-N concentration in the liquid fraction should be considered. PMID:27116355

  4. Initial Effects of Differently Treated Biogas Residues from Municipal and Industrial Wastes on Spring Barley Yield Formation

    PubMed Central

    Prays, Nadia; Kaupenjohann, Martin

    2016-01-01

    Soil application of biogas residues (BGRs) is important for closing nutrient cycles. This study examined the efficiency and impact on yields and yield formation of solid-liquid separated residues from biodegradable municipal and industrial wastes (bio-waste) in comparison to complete BGRs, nitrification inhibitor, agricultural BGRs, mineral fertilizer and unfertilized plots as control. The experiment was set up as a randomized block design on silt loam Cambisol. Biogas residues from four biogas plants were evaluated. Plants per m², ears per plant, grains per ear and thousand grain weight (TGW) were measured at harvest. Fertilization with BGRs resulted in similar biomass yields compared with mineral fertilizer. Mineral fertilizer (71 dt/ha) and plots fertilized with liquid fraction (59–62 dt/ha) indicated a trend to higher yields than solid fraction or complete BGR due to its high ammonia content. Liquid fractions and fraction with nitrification inhibitor induced fewer plants per m² than corresponding solid and complete variants due to a potential phytotoxicity of high NH4-N concentration during germination. However, barley on plots fertilized with liquid fraction compensated the disadvantages at the beginning during the vegetation period and induced higher grain yields than solid fraction. This was attributable to a higher number of ears per plant and grains per ear. In conclusion, BGRs from biodegradable municipal and industrial wastes can be used for soil fertilization and replace considerable amounts of mineral fertilizer. Our study showed that direct application of the liquid fraction of BGR is the most suitable strategy to achieve highest grain yields. Nevertheless potential phytotoxicity of the high NH4-N concentration in the liquid fraction should be considered. PMID:27116355

  5. Pyrolytic characteristics of biomass acid hydrolysis residue rich in lignin.

    PubMed

    Huang, Yanqin; Wei, Zhiguo; Yin, Xiuli; Wu, Chuangzhi

    2012-01-01

    Pyrolytic characteristics of acid hydrolysis residue (AHR) of corncob and pinewood (CAHR, WAHR) were investigated using a thermo-gravimetric analyzer (TGA) and a self-designed pyrolysis apparatus. Gasification reactivity of CAHR char was then examined using TGA and X-ray diffractometer. Result of TGA showed that thermal degradation curves of AHR descended smoothly along with temperature increasing from 150 °C to 850 °C, while a "sharp mass loss stage" for original biomass feedstock (OBF) was observed. Char yield from AHR (42.64-30.35 wt.%) was found to be much greater than that from OBF (26.4-19.15 wt.%). In addition, gasification reactivity of CAHR char was lower than that of corncob char, and there was big difference in micro-crystallite structure. It was also found that CAHR char reactivity decreased with pyrolysis temperature, but increased with pyrolysis heating rate and gasification temperature at 850-950 °C. Furthermore, CAHR char reactivity performed better under steam atmosphere than under CO2 atmosphere. PMID:22055106

  6. Novel bioconversions of municipal effluent and CO₂ into protein riched Chlorella vulgaris biomass.

    PubMed

    Li, Changling; Yang, Hailin; Li, Yuji; Cheng, Luping; Zhang, Meng; Zhang, Ling; Wang, Wu

    2013-03-01

    Batch, modified semi-continuous and continuous cultivations of Chlorella vulgaris C9-JN 2010 cells in municipal effluent were performed and analyzed. The experiments were carried out in 7.5-L photo-bioreactors, to which 2% of CO2 was supplied. Biomass and specific growth rate of C. vulgaris were 0.528-0.760gl(-1) and 0.200-0.374d(-1), respectively. Meanwhile, it could efficiently remove ammonia-N, total nitrogen, total phosphorus, CODCr and BOD5 by around 98.0%, 90.9-93.6%, 89.9-91.8%, 60.7-90.0% and 83.4-88.4%, respectively. Algal protein content was 550±30.0mgg(-1) of the harvested biomass of C. vulgaris which was rich in eight kinds of essential amino acids (around 44.5% of the total). The processes of cultivation of C. vulgaris in municipal effluent could be proposed as dual-beneficial approaches, which could produce profitable byproducts and simultaneously reduce the contaminations to environment. PMID:23399495

  7. Effects of lipid concentration on anaerobic co-digestion of municipal biomass wastes.

    PubMed

    Sun, Yifei; Wang, Dian; Yan, Jiao; Qiao, Wei; Wang, Wei; Zhu, Tianle

    2014-06-01

    The influence of the lipid concentration on the anaerobic co-digestion of municipal biomass waste and waste-activated sludge was assessed by biochemical methane potential (BMP) tests and by bench-scale tests in a mesophilic semi-continuous stirred tank reactor. The effect of increasing the volatile solid (VS) concentration of lipid from 0% to 75% was investigated. BMP tests showed that lipids in municipal biomass waste could enhance the methane production. The results of bench-scale tests showed that a lipids concentration of 65% of total VS was the inhibition concentration. Methane yields increased with increasing lipid concentration when lipid concentrations were below 60%, but when lipid concentration was set as 65% or higher, methane yields decreased sharply. When lipid concentrations were below 60%, the pH values were in the optimum range for the growth of methanogenic bacteria and the ratios of volatile fatty acid (VFA)/alkalinity were in the range of 0.2-0.6. When lipid concentrations exceeded 65%, the pH values were below 5.2, the reactor was acidized and the values of VFA/alkalinity rose to 2.0. The amount of Brevibacterium decreased with increasing lipid content. Long chain fatty acids stacked on the methanogenic bacteria and blocked the mass transfer process, thereby inhibiting anaerobic digestion. PMID:24075452

  8. Effects of residues from municipal solid waste landfill on corn yield and heavy metal content

    SciTech Connect

    Prabpai, S. Charerntanyarak, L. Siri, B. Moore, M.R. Noller, Barry N.

    2009-08-15

    The effects of residues from municipal solid waste landfill, Khon Kaen Municipality, Thailand, on corn (Zea mays L.) yield and heavy metal content were studied. Field experiments with randomized complete block design with five treatments (0, 20, 40, 60 and 80% v/v of residues and soil) and four replications were carried out. Corn yield and heavy metal contents in corn grain were analyzed. Corn yield increased by 50, 72, 85 and 71% at 20, 40, 60 and 80% treatments as compared to the control, respectively. All heavy metals content, except cadmium, nickel and zinc, in corn grain were not significantly different from the control. Arsenic, cadmium and zinc in corn grain were strongly positively correlated with concentrations in soil. The heavy metal content in corn grain was within regulated limits for human consumption.

  9. Evaluating local crop residue biomass supply: Economic and environmental impacts

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The increasing interest in energy production from biomass requires a better understanding of potential local production and environmental impacts. This information is needed by local producers, biomass industry, and other stakeholders, and for larger scale analyses. This study models biomass product...

  10. Anaerobic digestion of municipal solid waste: Utility of process residues as a soil amendment

    SciTech Connect

    Rivard, C.J.; Nagle, N.J.; Kay, B.D.

    1995-12-31

    Tuna processing wastes (sludges high in fat, oil, and grease [FOG]) and municipal solid waste (MSW) generated on Tutuila Island, American Samoa, represent an ongoing disposal challenge. The biological conversion of the organic fraction of these wastes to useful products, including methane and fertilizer-grade residue, through anaerobic high-solids digestion is currently in scale-up development. The suitability of the anaerobic digestion residues as a soil amendment was evaluated through extensive chemical analysis and greenhouse studies using corn as an indicator crop. Additionally, native Samoan soil was used to evaluate the specific application rates for the compost. Experiments established that anaerobic residues increase crop yields in direct proportion to increases in the application rate. Additionally, nutrient saturation was not demonstrated within the range of application rates evaluated for the Samoan soil. Beyond nutrient supplementation, organic residue amendment to Samoan soil imparts enhanced water and nutrient-binding capacities.

  11. Vitrification of municipal solid waste incineration fly ash using biomass ash as additives.

    PubMed

    Alhadj-Mallah, Moussa-Mallaye; Huang, Qunxing; Cai, Xu; Chi, Yong; Yan, JianHua

    2015-01-01

    Thermal melting is an energy-costing solution for stabilizing toxic fly ash discharged from the air pollution control system in the municipal solid waste incineration (MSWI) plant. In this paper, two different types of biomass ashes are used as additives to co-melt with the MSWI fly ash for reducing the melting temperature and energy cost. The effects of biomass ashes on the MSWI fly ash melting characteristics are investigated. A new mathematical model has been proposed to estimate the melting heat reduction based on the mass ratios of major ash components and measured melting temperature. Experimental and calculation results show that the melting temperatures for samples mixed with biomass ash are lower than those of the original MSWI fly ash and when the mass ratio of wood ash reaches 50%, the deformation temperature (DT), the softening, hemisphere temperature (HT) and fluid temperature (FT) are, respectively, reduced by 189°C, 207°C, 229°C, and 247°C. The melting heat of mixed ash samples ranges between 1650 and 2650 kJ/kg. When 50% wood ash is mixed, the melting heat is reduced by more than 700 kJ/kg for the samples studied in this paper. Therefore, for the vitrification treatment of the fly ash from MSW or other waste incineration plants, wood ash is a potential fluxing assistant. PMID:25220259

  12. Physical and Chemical Correlates of Microbial Activity and Biomass in Composting Municipal Sewage Sludge

    PubMed Central

    McKinley, Vicky L.; Vestal, J. Robie

    1985-01-01

    Various physical and chemical parameters were monitored to evaluate their influence on the microbial communities present in composting municipal sewage sludge. Temperature, moisture content, depth, pH, protein content, total nitrogen, total carbon, lipid phosphate biomass, and the rates of microbial incorporation of substrates into lipids were measured at several times throughout the 17- to 19-day composting runs. Temperature was found to have the most consistent and dramatic effect on microbial activity and biomass. When temperatures exceeded 55 to 60°C, microbial activity fell dramatically, usually by more than 1 order of magnitude. Microbial activity was generally greatest in samples taken from the 35 to 50°C areas of the composting piles. Changes in the composition of the compost over time included increased pH, increased protein content, and decreased total organic content. The changes in these parameters appeared to reflect the microbial activity and biomass present. The results of this study indicate that the rate of composting may best be optimized by controlling the composting temperatures, provided that the other parameters fall within reasonable limits in the starting material. PMID:16346940

  13. Fine grain separation for the production of biomass fuel from mixed municipal solid waste.

    PubMed

    Giani, H; Borchers, B; Kaufeld, S; Feil, A; Pretz, T

    2016-01-01

    The main goal of the project MARSS (Material Advanced Sustainable Systems) is to build a demonstration plant in order to recover a renewable biomass fuel suitable for the use in biomass power plants out of mixed municipal solid waste (MMSW). The demonstration plant was constructed in Mertesdorf (Germany), working alongside an existing mechanical-biological treatment plant, where the MMSW is biological dried under aerobe conditions in rotting boxes. The focus of the presented sorting campaign was set on the processing of fine grain particles minor than 11.5mm which have the highest mass content and biogenic energy potential of the utilized grain size fractions. The objective was to produce a biomass fuel with a high calorific value and a low content of fossil (plastic, synthetic) materials while maximizing the mass recovery. Therefore, the biogenic components of the dried MMSW are separated from inert and fossil components through various classification and sifting processes. In three experimental process setups of different processing depths, the grain size fraction 4-11.5mm was sifted by the use of air sifters and air tables. PMID:26272710

  14. Catalytic gasification of oil-extracted residue biomass of Botryococcus braunii.

    PubMed

    Watanabe, Hideo; Li, Dalin; Nakagawa, Yoshinao; Tomishige, Keiichi; Watanabe, Makoto M

    2015-09-01

    Catalytic gasification of the oil-extracted residue biomass of Botryococcus braunii was demonstrated in a laboratory-scale continuous feeding dual bed reactor. Steam gasification at 1023 K over Ni-Fe/Mg/Al catalyst can completely reform tar derived from pyrolysis of the residue biomass into C1 gases and hydrogen, and has achieved 91%-C conversion to gaseous product (CO+CO2+CH4). Composition of product gas has higher contents of CO and H2 with their ratio (H2/CO) of around 2.4 which is slightly H2-rich syngas. Maximum hydrogen yield of 74.7 mmol g-biomass(-1) obtained in this work is much higher than that from gasification of other algal biomass reported in literature. The residue biomass of B. braunii can be a superior renewable source of syngas or hydrogen. PMID:25817421

  15. Environmental risks of utilizing crop and forest residues for biomass energy

    SciTech Connect

    Pimentel, D.; Fast, S.; Gallahan, D.; Moran, M.A.

    1983-08-01

    Crop and forest residues are a valuable biomass resource for natural, agricultural, and forest ecosystems. These residues are essential to protect the soil from erosion and rapid water runoff and to maintain soil organic matter and nutrients. Thus, only an estimated 20% of the total residues remaining after harvest can be utilized for conversion because of environmental limitations and the impracticality of harvesting residues on some lands. Although the potential contribution of biomass energy to U.S. energy needs is relatively small, it is renewable energy (assuming no environmental degradation) and therefore has some long term value to the nation's energy program.

  16. Energy recovery from automotive shredder residue through co-combustion with municipal solid waste

    SciTech Connect

    Mark, F.E.; Fisher, M.M.; Smith, K.A.

    1998-07-01

    This project was commissioned by the Association of Plastics Manufacturers in Europe (APME) and the American Plastics Council (APC) to evaluate the operational and environmental impacts associated with the co-combustion of automotive shredder residue (ASR) with municipal solid waste (MSW) in a modern, commercial waste-to-energy plant. This paper describes the shredding and combustion facilities utilized for the program, discusses study protocols and test results, and presents analytical results of ASR characterizations, raw and clean boiler gas sampling and solid residues sampling. The study concludes that cocombustion of ASR and MSW improved burnout, did not adversely impact boiler performance, stack emissions or disposal or the combustion residues (ash) and is, therefore, an environmentally sound method of recovering the energy value in ASR.

  17. TG-FTIR study on co-pyrolysis of municipal solid waste with biomass.

    PubMed

    Ren, Qiangqiang; Zhao, Changsui; Wu, Xin; Liang, Cai; Chen, Xiaoping; Shen, Jiezhong; Tang, Guoyong; Wang, Zheng

    2009-09-01

    Co-pyrolysis of cotton stalk, a representative agricultural biomass in China, mixed with municipal solid waste (MSW) with high ash content and low calorific value was carried out using a thermogravimetric analyzer (TGA) coupled with a Fourier transform infrared (FTIR) spectrometer in Ar atmosphere. Pyrolysis characteristic and pollutant emission performance from MSW and stalk blends at different mass proportions were studied. The results show that as the mass proportion of stalk added increases, the total weight loss of the blend during pyrolysis increases. The addition of stalk has substantial effects on the N-selectivity to HCN, NH(3) and HNCO. In the presence of stalk, lower concentrations of HCl are detected. PMID:19362817

  18. Environmentally-benign conversion of biomass residues to electricity

    NASA Astrophysics Data System (ADS)

    Davies, Andrew

    As petroleum resources are finite, it is imperative to use them wisely in energy conversion applications and, at the same time, develop alternative energy sources. Biomass is one of the renewable energy sources that can be used to partially replace fossil fuels. Biomass-based fuels can be produced domestically and can reduce dependency on fuel imports. Due to their abundant supply, and given that to an appreciable extent they can be considered carbon-neutral, their use for power generation is of technological interest. However, whereas biomasses can be directly burned in furnaces, such a conventional direct combustion technique is ill-controlled and typically produces considerable amounts of health-hazardous airborne compounds [1,2]. Thus, an alternative technology for biomass utilization is described herein to address increasing energy needs in an environmentally-benign manner. More specifically, a multi-step process/device is presented to accept granulated or pelletized biomass, and generate an easily-identifiable form of energy as a final product. To achieve low emissions of products of incomplete combustion, the biomass is gasified pyrolytically, mixed with air, ignited and, finally, burned in nominally premixed low-emission flames. Combustion is thus indirect, since the biomass is not directly burned, instead its gaseous pyrolyzates are burned upon mixing with air. Thereby, combustion is well-controlled and can be complete. A demonstration device has been constructed to convert the internal energy of plastics into "clean" thermal energy and, eventually to electricity.

  19. Hydrothermal carbonization of biomass residuals: A comparative review of the chemistry, processes and applications of wet and dry pyrolysis

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This paper reviews chemistry, processes and application of hydrothermcally carbonized biomass wastes. Potential feedstock for the hydrothermal carbonization (HTC) includes variety of the non-traditional renewable wet agricultural and municipal waste streams. Pyrolysis and HTC show a comparable calor...

  20. Recycling of air pollution control residues from municipal solid waste incineration into lightweight aggregates.

    PubMed

    Quina, Margarida J; Bordado, João M; Quinta-Ferreira, Rosa M

    2014-02-01

    This work focuses on the assessment of technological properties and on the leaching behavior of lightweight aggregates (LWA) produced by incorporating different quantities of air pollution control (APC) residues from municipal solid waste (MSW) incineration. Currently this hazardous waste has been mostly landfilled after stabilization/solidification. The LWA were produced by pelletizing natural clay, APC residues as-received from incineration plant, or after a washing treatment, a small amount of oil and water. The pellets were fired in a laboratory chamber furnace over calcium carbonate. The main technological properties of the LWA were evaluated, mainly concerning morphology, bulk and particle densities, compressive strength, bloating index, water adsorption and porosity. Given that APC residues do not own expansive (bloating) properties, the incorporation into LWA is only possible in moderate quantities, such as 3% as received or 5% after pre-washing treatment. The leaching behavior of heavy metals from sintered LWA using water or acid solutions was investigated, and despite the low acid neutralization capacity of the synthetic aggregates, the released quantities were low over a wide pH range. In conclusion, after a washing pre-treatment and if the percentage of incorporation is low, these residues may be incorporated into LWA. However, the recycling of APC residues from MSW incineration into LWA does not revealed any technical advantage. PMID:24238798

  1. Global and regional potential for bioenergy from agricultural and forestry residue biomass

    SciTech Connect

    Gregg, Jay S.; Smith, Steven J.

    2010-02-11

    As co-products, agricultural and forestry residues represent a potential low cost, low carbon, source for bioenergy. A method is developed method for estimating the maximum sustainable amount of energy potentially available from agricultural and forestry residues by converting crop production statistics into associated residue, while allocating some of this resource to remain on the field to mitigate erosion and maintain soil nutrients. Currently, we estimate that the world produces residue biomass that could be sustainably harvested and converted into over 50 EJ yr-1 of energy. The top three countries where this resource is estimated to be most abundant are currently net energy importers: China, the United States (US), and India. The global potential from residue biomass is estimated to increase to approximately 80-95 EJ yr-1 by mid- to late- century, depending on physical assumptions such as of future crop yields and the amount of residue sustainably harvestable. The future market for biomass residues was simulated using the Object-Oriented Energy, Climate, and Technology Systems Mini Climate Assessment Model (ObjECTS MiniCAM). Utilization of residue biomass as an energy source is projected for the next century under different climate policy scenarios. Total global use of residue biomass is estimated to increase to 70-100 EJ yr-1 by mid- to late- century in a central case, depending on the presence of a climate policy and the economics of harvesting, aggregating, and transporting residue. Much of this potential is in developing regions of the world, including China, Latin America, Southeast Asia, and India.

  2. Gasification of agricultural residues (biomass): Influence of inorganic constituents

    SciTech Connect

    DeGroot, W.F.; Kannan, M.P.; Richards, G.N. ); Theander, O. )

    1990-01-01

    Four different biomass samples are included in this study, viz., sphagnum peat, wheat straw, sugar beet pulp, and potato pulp. They were chosen to represent a wide range of plant origin and inorganic content. This paper represents a preliminary investigation of an approach based on pyrolysis of biomass to produce volatile products and chars, followed by gasification of the chars. The particular interest lies in the investigation of the influence of the indigenous metal ions on the rate of gasification. Carbon dioxide has been used for the gasification, and the biomass was analyzed for nine metals, uronic acids (which are implicated in the binding of inorganic counterions), protein, and Klason lignin. The highest individual metal ion content was 13,964 ppm of potassium in potato pulp, and the gasification rates, under constant conditions, covered up to a 20-fold range, with char from potato pulp being the most readily gasified and char from peat the most resistant. The correlation of gasification rates with content of the major metal ions (alkali metals and alkaline earths) was poor. However, a high level of correlation was observed when wheat straw was omitted. It is speculated that the latter biomass may be anomalous with respect to the other three because of its high silica content.

  3. Improving material and energy recovery from the sewage sludge and biomass residues.

    PubMed

    Kliopova, Irina; Makarskienė, Kristina

    2015-02-01

    Sewage sludge management is a big problem all over the world because of its large quantities and harmful impact on the environment. Energy conversion through fermentation, compost production from treated sludge for agriculture, especially for growing energetic plants, and treated sludge use for soil remediation are widely used alternatives of sewage sludge management. Recently, in many EU countries the popularity of these methods has decreased due to the sewage sludge content (heavy metals, organic pollutions and other hazards materials). This paper presents research results where the possibility of solid recovered fuel (SRF) production from the separate fraction (10-40 mm) of pre-composted materials--sewage sludge from municipal waste water treatment plant and biomass residues has been evaluated. The remaining fractions of pre-composted materials can be successfully used for compost or fertiliser production, as the concentration of heavy metals in the analysed composition is reduced in comparison with sewage sludge. During the experiment presented in this paper the volume of analysed biodegradable waste was reduced by 96%: about 20% of input biodegradable waste was recovered to SRF in the form of pellets with 14.25 MJ kg(-1) of the net calorific value, about 23% were composted, the rest--evaporated and discharged in a wastewater. The methods of material-energy balances and comparison analysis of experiment data have been chosen for the environmental impact assessment of this biodegradable waste management alternative. Results of the efficiency of energy recovery from sewage sludge by SRF production and burning, comparison analysis with widely used bio-fuel-sawdust and conclusions made are presented. PMID:25481696

  4. Effects of water washing on removing organic residues in bottom ashes of municipal solid waste incinerators.

    PubMed

    Lin, Yen-Ching; Panchangam, Sri Chandana; Wu, Chung-Hsin; Hong, Pui-Kwan Andy; Lin, Cheng-Fang

    2011-01-01

    Due to their potential toxicity and odourous nature, the residual organics in municipal solid waste incinerators are recently gaining attention as an important issue of resources recovery apart from their complex mixture of organic counterpart. Studies of the organic fractions in municipal solid waste incinerator residues have been limited. In this study, extended solid-phase extraction of the water-washed bottom ash and liquid-phase extraction of the washing water were carried out with regard to bottom ash samples from three mass-burning incinerators in Taipei County (Taiwan) during four consecutive seasons of year 2008-2009. Supercritical fluid extraction and Soxtec extraction techniques along with GC-MS were successfully used to characterize the residual organics in weathered and washed bottom ashes. Supercritical fluid extraction provided the quantification of aliphatics and aromatic compounds such as hexanoic acid and benzaldehyde, respectively. Soxtec extraction was useful for qualitative analysis of aromatic and aliphatic groups in the ashes and many of which were odourous and toxic compounds. By mixing one unit weight (g) bottom ash with two unit volume (mL) water for 15 min, total organic carbon in the bottom ash was greatly reduced (e.g., from 4.1 to 1.8 wt.%). Among the removed were foul odour-causing compounds such as pyridine and quinoline derivatives, while some aromatic compounds such as 4-hydroxybenzaldehyde and low-molecular-weight aliphatics such as hexanoic acid remained. The results here suggest that washing with water can be an effective pre-treatment step for removing odour-causing and environmental concerned organics. PMID:21112610

  5. Biomass conversion processes for energy and fuels

    NASA Astrophysics Data System (ADS)

    Sofer, S. S.; Zaborsky, O. R.

    The book treats biomass sources, promising processes for the conversion of biomass into energy and fuels, and the technical and economic considerations in biomass conversion. Sources of biomass examined include crop residues and municipal, animal and industrial wastes, agricultural and forestry residues, aquatic biomass, marine biomass and silvicultural energy farms. Processes for biomass energy and fuel conversion by direct combustion (the Andco-Torrax system), thermochemical conversion (flash pyrolysis, carboxylolysis, pyrolysis, Purox process, gasification and syngas recycling) and biochemical conversion (anaerobic digestion, methanogenesis and ethanol fermentation) are discussed, and mass and energy balances are presented for each system.

  6. Potential of Reduction in CO2 Emission by Biomass Power Generation with Thinning Residues

    NASA Astrophysics Data System (ADS)

    Makino, Yosuke; Kato, Takeyoshi; Suzuoki, Yasuo

    In Japan, forest thinning residues as woody biomass have potential to increase domestic primary energy supply, because there still remain many conifer plantations where thinning is not carried out. However, taking the reduction in carbon stock in forests into account, the additional thinning for energy supply may not contribute to the reduction in CO2 emission. Considering the change in the carbon stock in forests, this paper discusses the potential of reduction in CO2 emission by biomass power generation with thinning residues. As power generation systems with thinning residues, co-firing with coal in a utility's power station and a molten carbonate fuel cell (MCFC) with gasification system are taken into account. The results suggest that the co-firing of woody biomass supplied by the additional thinning at utilities' coal-fired power stations has a potential for reducing overall CO2 emission.

  7. Using a high biomass plant Pennisetum hydridum to phyto-treat fresh municipal sewage sludge.

    PubMed

    Hei, Liang; Lee, Charles C C; Wang, Hui; Lin, Xiao-Yan; Chen, Xiao-Hong; Wu, Qi-Tang

    2016-10-01

    The study was carried out to investigate the use of a high biomass plant, Pennisetum hydridum, to treat municipal sewage sludge (MSS). An experiment composed of plots with four treatments, soil, fresh sludge, soil-sludge mixture and phyto-treated sludge, was conducted. It showed that the plant could not survive directly in fresh MSS when cultivated from stem cuttings. The experiment transplanting the incubated cutting with nurse medium of P. hydridum in soil and fresh MSS, showed that the plants grew normally in fresh MSS. The pilot experiment of P. hydridum and Alocasia macrorrhiza showed that the total yield and nutrient amount of P. hydridum were 9.2 times and 3.6 times more than that of A. macrorrhiza. After plant treatment, MSS was dried, stabilized and suitable to be landfilled or incinerated, with a calorific value of about 5.6MJ/kg (compared to the initial value of 1.9MJ/kg fresh sludge). PMID:26897473

  8. Solid residues from Italian municipal solid waste incinerators: A source for "critical" raw materials.

    PubMed

    Funari, Valerio; Braga, Roberto; Bokhari, Syed Nadeem Hussain; Dinelli, Enrico; Meisel, Thomas

    2015-11-01

    The incineration of municipal solid wastes is an important part of the waste management system along with recycling and waste disposal, and the solid residues produced after the thermal process have received attention for environmental concerns and the recovery of valuable metals. This study focuses on the Critical Raw Materials (CRM) content in solid residues from two Italian municipal waste incinerator (MSWI) plants. We sampled untreated bottom ash and fly ash residues, i.e. the two main outputs of common grate-furnace incinerators, and determined their total elemental composition with sensitive analytical techniques such as XRF and ICP-MS. After the removal of a few coarse metallic objects from bottom ashes, the corresponding ICP solutions were obtained using strong digestion methods, to ensure the dissolution of the most refractory components that could host significant amounts of precious metals and CRM. The integration of accurate chemical data with a substance flow analysis, which takes into account the mass balance and uncertainties assessment, indicates that bottom and fly ashes can be considered as a low concentration stream of precious and high-tech metals. The magnesium, copper, antimony and zinc contents are close to the corresponding values of a low-grade ore. The distribution of the elements flow between bottom and fly ash, and within different grain size fractions of bottom ash, is appraised. Most elements are enriched in the bottom ash flow, especially in the fine grained fractions. However, the calculated transfer coefficients indicate that Sb and Zn strongly partition into the fly ashes. The comparison with available studies indicates that the CRM concentrations in the untreated solid residues are comparable with those residues that undergo post-treatment beneficiations, e.g. separation between ferrous and non-ferrous fractions. The suggested separate collection of "fresh" bottom ash, which could be processed for further mineral upgrading, can

  9. Characteristics of residual organics in municipal solid waste incinerator bottom ash.

    PubMed

    Lin, Yen-Ching; Yen, Jui-Hung; Lateef, Shaik Khaja; Hong, Pui-Kwan Andy; Lin, Cheng-Fang

    2010-10-15

    Although heavy metals in bottom ash have been a primary issue in resource recovery of municipal solid waste incinerator residues in past decades, less studied are potentially toxic and odorous organic fractions that exist as they have not been completely oxidized during the mass burn process. Using supercritical fluid extraction (SFE) and soxtec extraction (SE) techniques, this study investigated the characteristics of un-oxidized organic residues contained in bottom ash from three municipal solid waste incinerators in Taiwan during 2008-2009. All together 99 organics were identified in bottom ash samples using gas chromatography-mass spectrometry (GC-MS). Among the identified organics, aromatic compounds were most frequently detected. No polycyclic aromatic hydrocarbons were extracted by SFE or SE. Several phthalates (e.g., phthalic acid isobutyl tridec-2-yn-1-yl ester, dibutyl phthalate and 2-butoxyethyl butyl benzene-1,2-dicarboxylate), organic phosphates (e.g., octicizer and phosphoric acid isodecyl diphenyl ester), and aromatics and amines including pyridine, quinoline derivatives, chloro- and cyano-organics were successfully extracted. Aromatic amines (e.g., 1-nitro-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid diethylamide and 3-bromo-N-(4-bromo-2-chlorophenyl)-propanamide) and aromatic compounds (other than amines) (e.g., 7-chloro-4-methoxy-3-methylquinoline and 2,3-dihydro-N-hydroxy-4-methoxy-3,3-dimethyl indole-2-one) are probably the major odorous compounds in bottom ash. This work identifies organic pollutants in incinerated bottom ash that have received far less attention than their heavy metals counterpart. PMID:20605069

  10. Activity and growth of anammox biomass on aerobically pre-treated municipal wastewater.

    PubMed

    Laureni, Michele; Weissbrodt, David G; Szivák, Ilona; Robin, Orlane; Nielsen, Jeppe Lund; Morgenroth, Eberhard; Joss, Adriano

    2015-09-01

    Direct treatment of municipal wastewater (MWW) based on anaerobic ammonium oxidizing (anammox) bacteria holds promise to turn the energy balance of wastewater treatment neutral or even positive. Currently, anammox processes are successfully implemented at full scale for the treatment of high-strength wastewaters, whereas the possibility of their mainstream application still needs to be confirmed. In this study, the growth of anammox organisms on aerobically pre-treated municipal wastewater (MWW(pre-treated)), amended with nitrite, was proven in three parallel reactors. The reactors were operated at total N concentrations in the range 5-20 mg(N)∙L(-1), as expected for MWW. Anammox activities up to 465 mg(N)∙L(-1)∙d(-1) were reached at 29 °C, with minimum doubling times of 18 d. Lowering the temperature to 12.5 °C resulted in a marked decrease in activity to 46 mg(N)∙L(-1)∙d(-1) (79 days doubling time), still in a reasonable range for autotrophic nitrogen removal from MWW. During the experiment, the biomass evolved from a suspended growth inoculum to a hybrid system with suspended flocs and wall-attached biofilm. At the same time, MWW(pre-treated) had a direct impact on process performance. Changing the influent from synthetic medium to MWW(pre-treated) resulted in a two-month delay in net anammox growth and a two to three-fold increase in the estimated doubling times of the anammox organisms. Interestingly, anammox remained the primary nitrogen consumption route, and high-throughput 16S rRNA gene-targeted amplicon sequencing analyses revealed that the shift in performance was not associated with a shift in dominant anammox bacteria ("Candidatus Brocadia fulgida"). Furthermore, only limited heterotrophic denitrification was observed in the presence of easily biodegradable organics (acetate, glucose). The observed delays in net anammox growth were thus ascribed to the acclimatization of the initial anammox population or/and the development of a side

  11. Characterization of air pollution control residues produced in a municipal solid waste incinerator in Portugal.

    PubMed

    Quina, Margarida J; Santos, Regina C; Bordado, João C; Quinta-Ferreira, Rosa M

    2008-04-01

    This study is mainly related with the physical and chemical characterization of a solid waste, produced in a municipal solid waste (MSW) incineration process, which is usually referred as air pollution control (APC) residue. The moisture content, loss on ignition (LOI), particle size distribution, density, porosity, specific surface area and morphology were the physical properties addressed here. At the chemical level, total elemental content (TC), total availability (TA) and the leaching behaviour with compliance tests were determined, as well as the acid neutralization capacity (ANC). The main mineralogical crystalline phases were identified, and the thermal behaviour of the APC residues is also shown. The experimental work involves several techniques such as laser diffraction spectrometry, mercury porosimetry, helium pycnometry, gas adsorption, flame atomic absorption spectrometry (FAAS), ion chromatography, scanning electron microscopy (SEM), X-ray fluorescence (XRF), X-ray diffraction (XRD) and simultaneous thermal analysis (STA). The results point out that the APC residues do not comply with regulations in force at the developed countries, and therefore the waste should be considered hazardous. Among the considered heavy metals, lead, zinc and chromium were identified as the most problematic ones, and their total elemental quantities are similar for several samples collected in an industrial plant at different times. Moreover, the high amount of soluble salts (NaCl, KCl, calcium compounds) may constitute a major problem and should be taken into account for all management strategies. The solubility in water is very high (more than 24% for a solid/liquid ratio of 10) and thus the possible utilizations of this residue are very limited, creating difficulties also in the ordinary treatments, such as in solidification/stabilization with binders. PMID:17728059

  12. Illinois biomass resources: annual crops and residues; canning and food-processing wastes. Preliminary assessment

    SciTech Connect

    Antonopoulos, A A

    1980-06-01

    Illinois, a major agricultural and food-processing state, produces vast amounts of renewable plant material having potential for energy production. This biomass, in the form of annual crops, crop residues, and food-processing wastes, can be converted to alternative fuels (such as ethanol) and industrial chemicals (such as furfural, ethylene, and xylene). The present study provides a preliminary assessment of these Illinois biomass resources, including (a) an appraisal of the effects of their use on both agriculture and industry; (b) an analysis of biomass conversion systems; and (c) an environmental and economic evaluation of products that could be generated from biomass. It is estimated that, of the 39 x 10/sup 6/ tons of residues generated in 1978 in Illinois from seven main crops, about 85% was collectible. The thermal energy equivalent of this material is 658 x 10/sup 6/ Btu, or 0.66 quad. And by fermenting 10% of the corn grain grown in Illinois, some 323 million gallons of ethanol could have been produced in 1978. Another 3 million gallons of ethanol could have been produced in the same year from wastes generated by the state's food-processing establishments. Clearly, Illinois can strengthen its economy substantially by the development of industries that produce biomass-derived fuels and chemicals. In addition, a thorough evaluation should be made of the potential for using the state's less-exploitable land for the growing of additional biomass.

  13. Hydrolysate of lipid extracted microalgal biomass residue: An algal growth promoter and enhancer.

    PubMed

    Maurya, Rahulkumar; Paliwal, Chetan; Chokshi, Kaumeel; Pancha, Imran; Ghosh, Tonmoy; Satpati, Gour Gopal; Pal, Ruma; Ghosh, Arup; Mishra, Sandhya

    2016-05-01

    The present study demonstrates the utilization of the algal hydrolysate (AH) prepared from lipid extracted residual harmful bloom-forming cyanobacteria Lyngbya majuscula biomass, as a growth supplement for the cultivation of green microalgae Chlorella vulgaris. BG-11 replacements with AH in different proportions significantly affects the cell count, dry cell weight (DCW), biomass productivity (BP) and pigments concentration. Among all, 25% AH substitution in BG11 media was found to be optimum which enhanced DCW, BP and pigments content by 39.13%, 40.81% and 129.47%, respectively, compared to control. The lipid content (31.95%) was also significantly higher in the 25% AH replacement. The volumetric productivity of neutral lipids (ideal for biodiesel) and total protein content of the cells significantly increased in all AH substitutions. Thus, lipid extracted microalgal biomass residue (LMBR) hydrolysate can be a potential growth stimulating supplement for oleaginous microalgae C. vulgaris. PMID:26890794

  14. Collection, transportation, and storage of biomass residues in the Pacific Northwest

    SciTech Connect

    Inaba, L.K.; Eakin, D.E.

    1981-11-01

    This study was conducted to identify potential methods for the collection, transportation and storage of agricultural and forest residues in the Pacific Northwest. Information was gathered from available literature and through contacts with researchers, equipment manufacturers, and other individuals involved in forest and agricultural activities. This information was evaluated, combined, and adapted for situations existing in the Pacific Northwest. A number of methods for collection, transportation, and storage of biomass residues using currently available technology are described. Many of these methods can be applied to residue fuel materials along with their current uses in the forest and agricultural industries.

  15. Cost Methodology for Biomass Feedstocks: Herbaceous Crops and Agricultural Residues

    SciTech Connect

    Turhollow Jr, Anthony F; Webb, Erin; Sokhansanj, Shahabaddine

    2009-12-01

    This report describes a set of procedures and assumptions used to estimate production and logistics costs of bioenergy feedstocks from herbaceous crops and agricultural residues. The engineering-economic analysis discussed here is based on methodologies developed by the American Society of Agricultural and Biological Engineers (ASABE) and the American Agricultural Economics Association (AAEA). An engineering-economic analysis approach was chosen due to lack of historical cost data for bioenergy feedstocks. Instead, costs are calculated using assumptions for equipment performance, input prices, and yield data derived from equipment manufacturers, research literature, and/or standards. Cost estimates account for fixed and variable costs. Several examples of this costing methodology used to estimate feedstock logistics costs are included at the end of this report.

  16. Do biomass harvesting guidelines influence herpetofauna following harvests of logging residues for renewable energy?.

    PubMed

    Fritts, Sarah; Moorman, Christopher; Grodsky, Steven; Hazel, Dennis; Homyack, Jessica; Farrell, Chris; Castleberry, Steven

    2016-04-01

    Forests are a major supplier of renewable energy; however, gleaning logging residues for use as woody biomass feedstock could negatively alter habitat for species dependent on downed wood. Biomass Harvesting Guidelines (BHGs) recommend retaining a portion of woody biomass on the forest floor following harvest. Despite BHGs being developed to help ensure ecological sustainability, their contribution to biodiversity has not been evaluated experimentally at operational scales. We compared herpetofauanal evenness, diversity, and richness and abundance of Anaxyrus terrestris and Gastrophryne carolinensis among six treatments that varied in volume and spatial arrangement of woody biomass retained after clearcutting loblolly pine (Pinus taeda) plantations in North Carolina, USA (n = 4), 2011-2014 and Georgia (n = 4), USA 2011-2013. Treatments were: (1) biomass harvest with no BHGs, (2) 15% retention with biomass clustered, (3) 15% retention with biomass dispersed, (4) 30% retention with biomass clustered, (5) 30% retention with biomass dispersed, and (6) no biomass harvest. We captured individuals with drift fence arrays and compared evenness, diversity, and richness metrics among treatments with repeated-measure, linear mixed-effects models. We determined predictors of A. terrestris and G. carolinensis abundances using a priori candidate N-mixture models with woody biomass volume, vegetation structure, and groundcover composition as covariates. We had 206 captures of 25 reptile species and 8710 captures of 17 amphibian species during 53690 trap nights. Herpetofauna diversity, evenness, and richness were similar among treatments. A. terrestris abundance was negatively related to volume of retained woody biomass in treatment units in North Carolina in 2013. G. carolinensis abundance was positively related with volume of retained woody debris in treatment units in Georgia in 2012. Other relationships between A. terrestris and G. carolinensis abundances and habitat metrics

  17. The utilization of post-chlorinated municipal domestic wastewater for biomass and lipid production by Chlorella spp. under batch conditions.

    PubMed

    Mutanda, Taurai; Karthikeyan, Subburammu; Bux, Faizal

    2011-08-01

    South Africa has a rich microalgal biodiversity which has the potential to be used for renewable bio-fuel production in the region. Bioprospecting for oleaginous microalgae in KwaZulu Natal Province, South Africa, resulted in the establishment of a microalgal culture collection system for alternative energy research in the country. A potential hyper-lipid-producing Chlorella spp. strain was isolated, purified, and cultured in supplemented post-chlorinated wastewater for biomass and lipid production at the laboratory scale under batch mode. The microalgal strain was cultivated in different strengths of BG-11 media supplemented with wastewater from a local municipal domestic wastewater treatment plant. The Chlorella spp. was grown using ambient dissolved carbon dioxide in shake flasks under photosynthetically active radiation (±120 μmol m⁻² s⁻¹). Microalgal biomass and lipid productivity were monitored at 24-h intervals in the batch mode. The microalgal biomass was analyzed by direct light microscopy and indirectly by spectrophotometry at 600 nm, and the lipids were extracted and quantified. The growth rate of the Chlorella spp. was enhanced in post-chlorinated wastewater supplemented with 5 mM NaNO₃ with maximal biomass productivity. A dramatic increase in lipid yield was achieved with the post-chlorinated wastewater supplemented with 25 mM NaNO₃. Low dosages of free chlorine were found to enhance microalgal growth. These findings serve as a basis for further scale-up trials using municipal wastewater as a medium for microalgal biomass and lipid production. PMID:21347654

  18. Ecosystem biomass, carbon, and nitrogen five years after restoration with municipal solid waste

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Escalating municipal solid waste generation coupled with decreasing landfill space needed for disposal has increased the pressure on military installations to evaluate novel approaches to handle this waste. One approach to alleviating the amount of municipal solid waste being landfilled is the use o...

  19. Organic carbon, influent microbial diversity and temperature strongly influence algal diversity and biomass in raceway ponds treating raw municipal wastewater.

    PubMed

    Cho, Dae-Hyun; Ramanan, Rishiram; Heo, Jina; Kang, Zion; Kim, Byung-Hyuk; Ahn, Chi-Yong; Oh, Hee-Mock; Kim, Hee-Sik

    2015-09-01

    Algae based wastewater treatment coupled to biofuel production has financial benefits and practical difficulties. This study evaluated the factors influencing diversity and growth of indigenous algal consortium cultivated on untreated municipal wastewater in a high rate algal pond (HRAP) for a period of 1 year using multivariate statistics. Diversity analyses revealed the presence of Chlorophyta, Cyanophyta and Bacillariophyta. Dominant microalgal genera by biovolume in various seasons were Scenedesmus sp., Microcystis sp., and Chlorella sp. Scenedesmus sp., persisted throughout the year but none of three strains co-dominated with the other. The most significant factors affecting genus dominance were temperature, inflow cyanophyta and organic carbon concentration. Cyanophyta concentration affected microalgal biomass and diversity, whereas temperature impacted biomass. Preferred diversity of microalgae is not sustained in wastewater systems but is obligatory for biofuel production. This study serves as a guideline to sustain desired microalgal consortium in wastewater treatment plants for biofuel production. PMID:25746593

  20. Thermodynamic behavior of rare metals in the melting process of municipal solid waste (MSW) incineration residues.

    PubMed

    Jung, Chang-Hwan; Osako, Masahiro

    2007-09-01

    This study aims to identify the thermodynamic behavior of rare metal elements during the melting process of municipal solid waste incineration residues. The fate of several selected rare metal elements was investigated using two approaches: experimental and thermodynamic equilibrium calculation at two actual melting plants. The results revealed that Ag, Bi, Ga, Ge, In, Pd, Sb, Te, and Tl are readily volatilized as chloride and/or gaseous forms and then condensed in melting furnace fly ash. On the other hand, Cr, Ni, Ta, V, and Zr tend to mostly remain in molten slag. Sn is volatilized as SnS (g) under reducing conditions while volatilization is suppressed under oxidizing conditions. Thermodynamically, total volatilization of Mn as MnCl2 (g) occurred with highly available chlorine under oxidizing conditions. However, at the actual plants, only a small proportion was volatilized. As for Co, Mo, and W, no volatilization occurred at the actual plants although the calculations suggest that these elements can form volatile metal chloride and volatilize. Non-equilibrium and heterogeneity of the actual plant melting furnace could explain the discrepancy. This study provided a good qualitative view of the behavior of rare metals in the melting process, but further investigation is required to produce a more accurate simulation and to resolve the discrepancy. PMID:17524456

  1. Factors influencing the life cycle burdens of the recovery of energy from residual municipal waste.

    PubMed

    Burnley, Stephen; Coleman, Terry; Peirce, Adam

    2015-05-01

    A life cycle assessment was carried out to assess a selection of the factors influencing the environmental impacts and benefits of incinerating the fraction of municipal waste remaining after source-separation for reuse, recycling, composting or anaerobic digestion. The factors investigated were the extent of any metal and aggregate recovery from the bottom ash, the thermal efficiency of the process, and the conventional fuel for electricity generation displaced by the power generated. The results demonstrate that incineration has significant advantages over landfill with lower impacts from climate change, resource depletion, acidification, eutrophication human toxicity and aquatic ecotoxicity. To maximise the benefits of energy recovery, metals, particularly aluminium, should be reclaimed from the residual bottom ash and the energy recovery stage of the process should be as efficient as possible. The overall environmental benefits/burdens of energy from waste also strongly depend on the source of the power displaced by the energy from waste, with coal giving the greatest benefits and combined cycle turbines fuelled by natural gas the lowest of those considered. Regardless of the conventional power displaced incineration presents a lower environmental burden than landfill. PMID:25758908

  2. Bonding exterior grade structural panels with copolymer resins of biomass residue components, phenol, and formaldehyde

    SciTech Connect

    Chen, C.M.

    1993-12-31

    Components of various forest and agricultural residue biomass-including the polyphenolic compounds-were converted into aqueous solution and/or suspension by extraction and digestion. Some biomass components reacted vigorously under alkaline catalysis with formaldehyde and initially showed a high degree of exothermic reaction; however, other components did not react as vigorously under these conditions, indicating that different biomass materials require different methods to obtain optimum reactivity for the copolymerization with phenol. Our primary goal is to develop adhesives capable of producing acceptable bond quality, as determined by the wood products industries` standards, under a reasonable range of gluing conditions. Copolymer resins of phenol, formaldehyde, and biomass components were synthesized and evaluated for gluability of bonding exterior grade structural replaced with chemicals derived from peanut hulls, pecan shell flour, pecan pith, southern pine bark, and pine needle required shorter press times. These resins also tolerated a broader range of gluing conditions. In summary, it appears that the technology of the fast curing copolymer resins of biomass components as adhesives for wood products has been developed and is ready to be transferred to industrial practice.

  3. IMPACT OF DECISION-MAKING STRATEGIES AND COMMUNICATION PROCESSES ON THE PUBLIC ACCEPTABILITY OF MUNICIPAL WASTE COMBUSTION RESIDUE UTILIZATION IN THE UNITED STATES

    EPA Science Inventory

    Of the identified current and proposed construction projects in which municipal solid waste combustion residues replace traditionally used materials, approximately half are located on landfills or other property controlled by project sponsors, one third are in publicly accessible...

  4. Recycling the nutrients in residues from methane digesters of aquatic macrophytes for new biomass production

    NASA Astrophysics Data System (ADS)

    Hanisak, M. D.; Williams, L. D.; Ryther, J. H.

    1980-04-01

    The floating freshwater macrophyte Eichhornia crassipes (water hyacinth) was fermented anaerobically to produce 0.4 l of biogas/g volatile solids at 60% methane with a bioconversion efficiency of 47%. Both the liquid and solid digester residues were a rich source of nutrients that were recycled to produce additional biomass. An approximate balance of the nitrogen recycled through the culture-digester-culture system indicated that nitrogen was conserved within the digester. All of the nitrogen originally added to the digester in the form of shredded water hyacinths could be found in the liquid (48%) and solid (52%) residues; 65.5% of the nitrogen in these residues could be reassimilated by cultures of water hyacinths. This study indicated the potential of bioconversion of aquatic macrophytes to methane as a possible means of both producing and conserving energy.

  5. Effect of lake water on algal biomass and microbial community structure in municipal wastewater-based lab-scale photobioreactors.

    PubMed

    Krustok, I; Truu, J; Odlare, M; Truu, M; Ligi, T; Tiirik, K; Nehrenheim, E

    2015-08-01

    Photobioreactors are a novel environmental technology that can produce biofuels with the simultaneous removal of nutrients and pollutants from wastewaters. The aim of this study was to evaluate the effect of lake water inoculation on the production of algal biomass and phylogenetic and functional structure of the algal and bacterial communities in municipal wastewater-treating lab-scale photobioreactors. Inoculating the reactors with lake water had a significant benefit to the overall algal biomass growth and nutrient reduction in the reactors with wastewater and lake water (ratio 70/30 v/v). The metagenome-based survey showed that the most abundant algal phylum in these reactors was Chlorophyta with Scenedesmus being the most prominent genus. The most abundant bacterial phyla were Proteobacteria and Bacteroidetes with most dominant families being Sphingobacteriaceae, Cytophagaceae, Flavobacteriaceae, Comamonadaceae, Planctomycetaceae, Nocardiaceae and Nostocaceae. These photobioreactors were also effective in reducing the overall amount of pathogens in wastewater compared to reactors with wastewater/tap water mixture. Functional analysis of the photobioreactor metagenomes revealed an increase in relative abundance genes related to photosynthesis, synthesis of vitamins important for auxotrophic algae and decrease in virulence and nitrogen metabolism subsystems in lake water reactors. The results of the study indicate that adding lake water to the wastewater-based photobioreactor leads to an altered bacterial community phylogenetic and functional structure that could be linked to higher algal biomass production, as well as to enhanced nutrient and pathogen reduction in these reactors. PMID:25895091

  6. Nitrogen recycling from fuel-extracted algal biomass: residuals as the sole nitrogen source for culturing Scenedesmus acutus.

    PubMed

    Gu, Huiya; Nagle, Nick; Pienkos, Philip T; Posewitz, Matthew C

    2015-05-01

    In this study, the reuse of nitrogen from fuel-extracted algal residues was investigated. The alga Scenedesmus acutus was found to be able to assimilate nitrogen contained in amino acids, yeast extracts, and proteinaceous alga residuals. Moreover, these alternative nitrogen resources could replace nitrate in culturing media. The ability of S. acutus to utilize the nitrogen remaining in processed algal biomass was unique among the promising biofuel strains tested. This alga was leveraged in a recycling approach where nitrogen is recovered from algal biomass residuals that remain after lipids are extracted and carbohydrates are fermented to ethanol. The protein-rich residuals not only provided an effective nitrogen resource, but also contributed to a carbon "heterotrophic boost" in subsequent culturing, improving overall biomass and lipid yields relative to the control medium with only nitrate. Prior treatment of the algal residues with Diaion HP20 resin was required to remove compounds inhibitory to algal growth. PMID:25539998

  7. Optimization for the Production of Cellulase Enzyme from Municipal Solid Waste Residue by Two Novel Cellulolytic Fungi

    PubMed Central

    Gautam, S. P.; Bundela, P. S.; Pandey, A. K.; Khan, Jamaluddin; Awasthi, M. K.; Sarsaiya, S.

    2011-01-01

    The main purpose of this study is to reduce the production cost of cellulase by optimizing the production medium and using an alternative carbon source such as municipal solid waste residue. In the present investigation, we aim to isolate the two novel cellulase producing fungi (Aspergillus niger and Trichoderma sp.) from municipal solid waste. Municipal solid waste residue (4-5% (w/v)) and peptone and yeast extract (1.0% (w/v)) were found to be the best combination of carbon and nitrogen sources for the production of cellulase by A. niger and Trichoderma sp. Optimum temperature and pH of the medium for the cellulase production by A. niger were 40°C and 6-7, whereas those for the production of cellulase by Trichoderma sp. were 45°C and 6.5. Cellulase production from A. niger and Trichoderma sp. can be an advantage as the enzyme production rate is normally higher as compared to other fungi. PMID:21350668

  8. Changes in soil microbial biomass and residual indices as ecological indicators of land use change in temperate permanent grassland.

    PubMed

    Murugan, Rajasekaran; Loges, Ralf; Taube, Friedhelm; Sradnick, André; Joergensen, Rainer Georg

    2014-05-01

    The relationship between microbial biomass, residues and their contribution to microbial turnover is important to understand ecosystem C storage. The effects of permanent grassland (100 % ryegrass--PG), conversion to modified grassland (mixture of grass and clover--MG) or maize monoculture (MM) on the dynamics of soil organic C (SOC), microbial biomass, fungal ergosterol and microbial residues (bacterial muramic acid and fungal glucosamine) were investigated. Cattle slurry was applied to quantify the effects of fertilisation on microbial residues and functional diversity of microbial community across land use types. Slurry application significantly increased the stocks of microbial biomass C and S and especially led to a shift in microbial residues towards bacterial tissue. The MM treatment decreased the stocks of SOC, microbial biomass C, N and S and microbial residues compared with the PG and MG treatments at 0-40 cm depth. The MM treatment led to a greater accumulation of saprotrophic fungi, as indicated by the higher ergosterol-to-microbial biomass C ratio and lower microbial biomass C/S ratio compared with the grassland treatments. The absence of a white clover population in the PG treatment caused a greater accumulation of fungal residues (presumably arbuscular mycorrhizal fungi (AMF), which do not contain ergosterol but glucosamine), as indicated by the significantly higher fungal C-to-bacterial C ratio and lower ergosterol-to-microbial biomass C ratio compared with the MG treatment. In addition to these microbial biomass and residual indices, the community level physiological profiles (CLPP) demonstrated distinct differences between the PG and MG treatments, suggesting the potential of these measurements to act as an integrative indicator of soil functioning. PMID:24549746

  9. Processing of residues and municipal waste in circulating fluidized beds: Operating experience, design concepts and future developments

    SciTech Connect

    Plass, L.; Albrecht, J.; Loeffler, J.C.

    1997-12-31

    Based on experience on processing of unconventional fuels in commercial Circulating Fluidized Bed (CFB) gasifiers new plant concepts for thermal treatment of residues and municipal waste are presented. Particular emphasis is put on optimizing process efficiencies and environmental performance of the overall processes. The thermal treatment of waste is carried out in two steps: Gasification in a CFB-reactor is followed by a high temperature reactor for complete breakdown of gaseous condensable hydrocarbons and for slagging of dust entrained in the CFB product gas. Major details of the process alternatives are discussed in view of economical and ecological aspects.

  10. Economics of biomass fuels for electricity production: A case study with crop residues

    NASA Astrophysics Data System (ADS)

    Maung, Thein Aye

    In the United Sates and around the world, electric power plants are among the biggest sources of greenhouse gas emissions which the Intergovernmental Panel on Climate Change argued was the main cause of climate change and global warming. This dissertation explores the factors which may induce electricity producers to use biomass fuels for power generation and thereby mitigate the impact of greenhouse gas emissions. Analyses in this dissertation suggest that there are two important factors which will play a major role in determining the future degree of bioelectricity production: the price of coal and the future price of carbon emissions. Using The Forest and Agricultural Sector Optimization Model--Green House Gas version (FASOMGHG) in a case study examining the competitiveness of crop residues, this dissertation finds that crop residues currently cost much more than coal as an electricity generation feedstock because they have lower heat content and higher production/hauling costs. For them to become cost competitive with coal, the combined costs of production and hauling must be cut by more than half or the coal price needs to rise. In particular, for crop residues to have any role in electricity generation either the price of coal has to increase to about 43 per ton or the carbon equivalent price must rise to about 15 per ton. The simulation results also show that crop residues with higher heat content such as wheat residues will have greater opportunities in bioelectricity production than the residues with lower heat content. In addition, the analysis shows that improvements in crop yield do not have much impact on bioelectricity production. However, the energy recovery efficiency does have significant positive impact on the bioelectricity desirability but again only if the carbon equivalent price rises substantially. The analysis also shows the desirability of cofiring biomass as opposed to 100% replacement because this reduces haling costs and increases the

  11. Environmental impacts of residual municipal solid waste incineration: a comparison of 110 French incinerators using a life cycle approach.

    PubMed

    Beylot, Antoine; Villeneuve, Jacques

    2013-12-01

    Incineration is the main option for residual Municipal Solid Waste treatment in France. This study compares the environmental performances of 110 French incinerators (i.e., 85% of the total number of plants currently in activity in France) in a Life Cycle Assessment perspective, considering 5 non-toxic impact categories: climate change, photochemical oxidant formation, particulate matter formation, terrestrial acidification and marine eutrophication. Mean, median and lower/upper impact potentials are determined considering the incineration of 1 tonne of French residual Municipal Solid Waste. The results highlight the relatively large variability of the impact potentials as a function of the plant technical performances. In particular, the climate change impact potential of the incineration of 1 tonne of waste ranges from a benefit of -58 kg CO2-eq to a relatively large burden of 408 kg CO2-eq, with 294 kg CO2-eq as the average impact. Two main plant-specific parameters drive the impact potentials regarding the 5 non-toxic impact categories under study: the energy recovery and delivery rate and the NOx process-specific emissions. The variability of the impact potentials as a function of incinerator characteristics therefore calls for the use of site-specific data when required by the LCA goal and scope definition phase, in particular when the study focuses on a specific incinerator or on a local waste management plan, and when these data are available. PMID:23910245

  12. Valorization of residual bacterial biomass waste after polyhydroxyalkanoate isolation by hydrothermal treatment.

    PubMed

    Wei, Liqing; Liang, Shaobo; Coats, Erik R; McDonald, Armando G

    2015-12-01

    Hydrothermal treatment (HTT) was used to convert residual bacterial biomass (RBB), recovered from poly(3-hydroxybutyrate-co-3-hydroxyvalerate) production, into valuable bioproducts. The effect of processing temperatures (150, 200, and 250°C) on the bioproducts (water-solubles (WSs), bio-oil, insoluble residue, and gas) was investigated. The yields of bio-oil and gas were higher at higher temperatures. The maximum WS content (28 wt%) was obtained at 200°C. GCMS analysis showed higher content of aromatics and N-containing compounds with increasing temperature. ESI-MS revealed chemical compounds (e.g. protein, carbohydrate, lipids, and lignin) associated with RBB are fragmented into smaller molecules (monomers) at higher HTT temperatures. The WS fraction contained totally 838, 889 and 886mg/g acids and 160, 31 and 21 mg/g carbohydrate for HTT at 150, 200, and 250°C, respectively. The solid residues contain unconverted compounds, especially after HTT at 150°C. The WS products (acids and carbohydrates) could be used directly for PHA biosynthesis. PMID:26454039

  13. Environmental residuals and capital costs of energy recovery from municipal sludge and feedlot manure

    SciTech Connect

    Ballou, S W; Dale, L; Johnson, R; Chambers, W; Mittelhauser, H

    1980-09-01

    The capital and environmental cost of energy recovery from municipal sludge and feedlot manure is analyzed. Literature on waste processing and energy conversion and interviews with manufacturers were used for baseline data for construction of theoretical models using three energy conversion processes: anaerobic digestion, incineration, and pyrolysis. Process characteristics, environmental impact data, and capital costs are presented in detail for each conversion system. The energy recovery systems described would probably be sited near large sources of sludge and manure, i.e., metropolitan sewage treatment plants and large feedlots in cattle-raising states. Although the systems would provide benefits in terms of waste disposal as well as energy production, they would also involve additional pollution of air and water. Analysis of potential siting patterns and pollution conflicts is needed before energy recovery systems using municipal sludge can be considered as feasible energy sources.

  14. Leaching behavior and possible resource recovery from air pollution control residues of fluidized bed combustion of municipal solid waste

    SciTech Connect

    Abbas, Z.; Andersson, B.A.; Steenari, B.M.

    1999-07-01

    Ash residues are generated at several points during combustion of municipal solid waste (MSW), i.e., in cyclones, electrostatic precipitators and fabric filters. Such residues are of a complex physical and chemical nature and are often enriched in soluble salts and heavy metals such as Pb, Cd and Zn. Fluidized bed combustion (FBC) of MSW is a relatively new technique and very little information is available about the leaching behavior of its residues. In this study, the total elemental composition, mineralogy and leaching behavior of cyclone and bag-house filter ashes from a bubbling fluidized bed (BFB) boiler fired with municipal solid waste have been investigated. In addition, the possibilities of recovery heavy metals from these ashes were studied. The long-term leaching behavior of the ash constituents was evaluated using a two-step batch leaching test known as the CEN-test, whereas short and medium term leaching behavior was evaluated using a Column test. The extraction of elements from cyclone and filter ashes with various acidic solutions was also investigated. The leaching behavior of acid washed ashes was evaluated using the CEN test. The cyclone ash was mainly composed of aluminosilicate minerals, whereas the filter ash consisted of chlorides and hydroxides of alkali and alkaline earth metals. The concentration of heavy metals such as Zn, Cu, Cd and Pb was higher in the filter ash than in the cyclone ash. The leached amounts of sulfates and Pb from the cyclone ash decreased with leaching test contact time, indicating the formation of secondary mineral phases. Large amounts of chlorides, sulfates, Ca, Cu and Pb were leached from the filter ash. Acid extraction removed large amounts ({gt}50%) of Zn, Pb and Cu from the filter ash and approximately 56% of the total amount of Zn present in the cyclone ash. An efficient removal of heavy metal species from these types of ashes can probably be achieved by application of a recycling or multi-step process.

  15. Environmental impacts of residual Municipal Solid Waste incineration: A comparison of 110 French incinerators using a life cycle approach

    SciTech Connect

    Beylot, Antoine Villeneuve, Jacques

    2013-12-15

    Highlights: • 110 French incinerators are compared with LCA based on plant-specific data. • Environmental impacts vary as a function of plants energy recovery and NO{sub x} emissions. • E.g. climate change impact ranges from −58 to 408 kg CO{sub 2}-eq/tonne of residual MSW. • Implications for LCA of waste management in a decision-making process are detailed. - Abstract: Incineration is the main option for residual Municipal Solid Waste treatment in France. This study compares the environmental performances of 110 French incinerators (i.e. 85% of the total number of plants currently in activity in France) in a Life Cycle Assessment perspective, considering 5 non-toxic impact categories: climate change, photochemical oxidant formation, particulate matter formation, terrestrial acidification and marine eutrophication. Mean, median and lower/upper impact potentials are determined considering the incineration of 1 tonne of French residual Municipal Solid Waste. The results highlight the relatively large variability of the impact potentials as a function of the plant technical performances. In particular, the climate change impact potential of the incineration of 1 tonne of waste ranges from a benefit of −58 kg CO{sub 2}-eq to a relatively large burden of 408 kg CO{sub 2}-eq, with 294 kg CO{sub 2}-eq as the average impact. Two main plant-specific parameters drive the impact potentials regarding the 5 non-toxic impact categories under study: the energy recovery and delivery rate and the NO{sub x} process-specific emissions. The variability of the impact potentials as a function of incinerator characteristics therefore calls for the use of site-specific data when required by the LCA goal and scope definition phase, in particular when the study focuses on a specific incinerator or on a local waste management plan, and when these data are available.

  16. MANUAL OF PRACTICE: THE DISPOSAL OF COMBINED MUNICIPAL/INDUSTRIAL WASTEWATER RESIDUES (METALS)

    EPA Science Inventory

    This manual gives the processes and products where different metals are used in order that potential sources of metals in combined wastewater residues may be identified. Potential problems in disposal of these residues are identified. Most metals are toxic to plants or animals at...

  17. EVALUATION OF SOLIDIFICATION/STABILIZATION TREATMENT PROCESSES FOR MUNICIPAL WASTE COMBUSTION RESIDUES

    EPA Science Inventory

    Investigations were carried out to compare and evaluate solidification/stabilization (S/S) processes to treat residues from combustion (MWC). ull factorial experimental design was used to processes to treat bottom ash, air pollution control (APC) residue, The 5 S/S processes incl...

  18. Pyrolysis of chitin biomass: TG-MS analysis and solid char residue characterization.

    PubMed

    Qiao, Yan; Chen, Shuai; Liu, Ying; Sun, Haizhen; Jia, Shiyu; Shi, Junyan; Pedersen, Christian Marcus; Wang, Yingxiong; Hou, Xianglin

    2015-11-20

    The thermal degradation of chitin biomass with various molecular structures was investigated by thermogravimetric analysis (TG), and the gaseous products were analyzed by connected mass spectroscopy (MS). The chemical structure and morphology of char residues collected at 750°C using the model substrates GlcNH2 and GlcNAc, were characterized systematically. The experimental results disclosed that one main mass loss stage was observed for each substrate. Chitosan samples with high molecular weight shown the more thermal stability, and chitin showed the highest thermal stability. Additionally, it was found that catalysts play a significant role during the pyrolysis. The gaseous evolution components, including NH3, H2O, CO, and CO2 were observed by on line MS. The experimental results disclosed that the obtained carbonaceous materials had lost the original hydrocarbon structure totally, and transformed into an aromatic structure with high carbon and nitrogen content, which was identified by XPS and solid state NMR. PMID:26344268

  19. Comparison of biochar properties from biomass residues produced by slow pyrolysis at 500°C.

    PubMed

    Lee, Yongwoon; Park, Jinje; Ryu, Changkook; Gang, Ki Seop; Yang, Won; Park, Young-Kwon; Jung, Jinho; Hyun, Seunghun

    2013-11-01

    Application of biochar from biomass pyrolysis to soil is gaining greater interest; this can ameliorate the soil quality, reduce fertilizer consumption, and sequestrate carbon. This study compares the characteristics of biochar produced by slow pyrolysis at 500°C for agricultural residues: sugarcane bagasse, cocopeat, paddy straw, palm kernel shell (PKS) and umbrella tree. In the biochar yield, the influence of the inert and lignin contents was significant. The wood stem, bagasse and paddy straw had biochar yields of 24-28 wt.% from the organic fraction while cocopeat had 46 wt.%. The carbon content of biochar ranged from 84 wt.% to 89 wt.%, which corresponded to 43-63% of carbon in the biomass. The biochar from wood stem and bagasse had well-developed pores of various sizes with large surface areas. Although the surface area was significant, PKS biochar had dense matrix with few large pores. The elemental composition and pH of biochars were also compared. PMID:24047681

  20. Atmospheric Emissions from Forest Biomass Residues to Energy Supply Chain: A Case Study in Portugal

    PubMed Central

    Rafael, Sandra; Tarelho, Luis; Monteiro, Alexandra; Monteiro, Tânia; Gonçalves, Catarina; Freitas, Sylvio; Lopes, Myriam

    2015-01-01

    Abstract During the past decades, pressures on global environment and energy security have led to an increasing demand on renewable energy sources and diversification of the world's energy supply. The Portuguese energy strategy considers the use of Forest Biomass Residues (FBR) to energy as being essential to accomplish the goals established in the National Energy Strategy for 2020. However, despite the advantages pointing to FBR to the energy supply chain, few studies have evaluated the potential impacts on air quality. In this context, a case study was selected to estimate the atmospheric emissions of the FBR to the energy supply chain in Portugal. Results revealed that production, harvesting, and energy conversion processes are the main culprits for the biomass energy supply chain emissions (with a contribution higher than 90%), while the transport processes have a minor importance for all the pollutants. Compared with the coal-fired plants, the FBR combustion produces lower greenhouses emissions, on a mass basis of fuel consumed; the same is true for NOX and SO2 emissions. PMID:26064039

  1. Biogas Production from Vietnamese Animal Manure, Plant Residues and Organic Waste: Influence of Biomass Composition on Methane Yield

    PubMed Central

    Cu, T. T. T.; Nguyen, T. X.; Triolo, J. M.; Pedersen, L.; Le, V. D.; Le, P. D.; Sommer, S. G.

    2015-01-01

    Anaerobic digestion is an efficient and renewable energy technology that can produce biogas from a variety of biomasses such as animal manure, food waste and plant residues. In developing countries this technology is widely used for the production of biogas using local biomasses, but there is little information about the value of these biomasses for energy production. This study was therefore carried out with the objective of estimating the biogas production potential of typical Vietnamese biomasses such as animal manure, slaughterhouse waste and plant residues, and developing a model that relates methane (CH4) production to the chemical characteristics of the biomass. The biochemical methane potential (BMP) and biomass characteristics were measured. Results showed that piglet manure produced the highest CH4 yield of 443 normal litter (NL) CH4 kg−1 volatile solids (VS) compared to 222 from cows, 177 from sows, 172 from rabbits, 169 from goats and 153 from buffaloes. Methane production from duckweed (Spirodela polyrrhiza) was higher than from lawn grass and water spinach at 340, 220, and 110.6 NL CH4 kg−1 VS, respectively. The BMP experiment also demonstrated that the CH4 production was inhibited with chicken manure, slaughterhouse waste, cassava residue and shoe-making waste. Statistical analysis showed that lipid and lignin are the most significant predictors of BMP. The model was developed from knowledge that the BMP was related to biomass content of lipid, lignin and protein from manure and plant residues as a percentage of VS with coefficient of determination (R-square) at 0.95. This model was applied to calculate the CH4 yield for a household with 17 fattening pigs in the highlands and lowlands of northern Vietnam. PMID:25557826

  2. Biogas production from vietnamese animal manure, plant residues and organic waste: influence of biomass composition on methane yield.

    PubMed

    Cu, T T T; Nguyen, T X; Triolo, J M; Pedersen, L; Le, V D; Le, P D; Sommer, S G

    2015-02-01

    Anaerobic digestion is an efficient and renewable energy technology that can produce biogas from a variety of biomasses such as animal manure, food waste and plant residues. In developing countries this technology is widely used for the production of biogas using local biomasses, but there is little information about the value of these biomasses for energy production. This study was therefore carried out with the objective of estimating the biogas production potential of typical Vietnamese biomasses such as animal manure, slaughterhouse waste and plant residues, and developing a model that relates methane (CH4) production to the chemical characteristics of the biomass. The biochemical methane potential (BMP) and biomass characteristics were measured. Results showed that piglet manure produced the highest CH4 yield of 443 normal litter (NL) CH4 kg(-1) volatile solids (VS) compared to 222 from cows, 177 from sows, 172 from rabbits, 169 from goats and 153 from buffaloes. Methane production from duckweed (Spirodela polyrrhiza) was higher than from lawn grass and water spinach at 340, 220, and 110.6 NL CH4 kg(-1) VS, respectively. The BMP experiment also demonstrated that the CH4 production was inhibited with chicken manure, slaughterhouse waste, cassava residue and shoe-making waste. Statistical analysis showed that lipid and lignin are the most significant predictors of BMP. The model was developed from knowledge that the BMP was related to biomass content of lipid, lignin and protein from manure and plant residues as a percentage of VS with coefficient of determination (R-square) at 0.95. This model was applied to calculate the CH4 yield for a household with 17 fattening pigs in the highlands and lowlands of northern Vietnam. PMID:25557826

  3. Anaerobic co-digestion of municipal biomass wastes and waste activated sludge: dynamic model and material balances.

    PubMed

    Sun, Yifei; Wang, Dian; Qiao, Wei; Wang, Wei; Zhu, Tianle

    2013-10-01

    The organic matter degradation process during anaerobic co-digestion of municipal biomass waste (MBW) and waste-activated sludge (WAS) under different organic loading rates (OLRs) was investigated in bench-scale and pilot-scale semi-continuous stirred tank reactors. To better understand the degradation process of MBW and WAS co-digestion and provide theoretical guidance for engineering application, anaerobic digestion model No.1 was revised for the co-digestion of MBW and WAS. The results showed that the degradation of organic matter could be characterized into three different fractions, including readily hydrolyzable organics, easily degradable particulate organics, and recalcitrant particle organics. Hydrolysis was the rate-limiting step under lower OLRs, and methanogenesisis was the rate-limiting step for an OLR of 8.0 kg volatile solid (VS)/(m3 x day). The hydrolytic parameters of carbohydrate, protein, and lipids were 0.104, 0.083, and 0.084 kg chemical oxygen demand (COD)/(kg COD x hr), respectively, and the reaction rate parameters of lipid fermentation were 1 and 1.25 kg COD/(kg COD x hr) for OLRs of 4.0 and 6.0 kg VS/(m3 x day). A revised model was used to simulate methane yield, and the results fit well with the experimental data. Material balance data were acquired based on the revised model, which showed that 58.50% of total COD was converted to methane. PMID:24494499

  4. Characterization of biomass residues and their amendment effects on water sorption and nutrient leaching in sandy soil.

    PubMed

    Wang, Letian; Tong, Zhaohui; Liu, Guodong; Li, Yuncong

    2014-07-01

    In this study, we evaluated the efficiency of two types of biomass residues (fermentation residues from a bioethanol process, FB; brown mill residues from a papermaking process, BM) as amendments for a sandy soil. The characteristics of these residues including specific surface areas, morphologies and nutrient sorption capacity were measured. The effects of biorefinery residues on water and nutrient retention were investigated in terms of different particle sizes and loadings. The results indicated that bio-based wastes FB and BM were able to significantly improve water and nutrient retention of sandy soil. The residues with larger surface areas had better water and nutrient retention capability. Specifically, in the addition of 10% loading, FB and BM was able to improve water retention by approximately 150% and 300%, while reduce 99% of ammonium and phosphate concentration in the leachate compare to the soil control, respectively. PMID:24529394

  5. Remediation of inorganic contaminants and polycyclic aromatic hydrocarbons from soils polluted by municipal solid waste incineration residues.

    PubMed

    Jobin, Philippe; Coudert, Lucie; Taillard, Vincent; Blais, Jean-Francois; Mercier, Guy

    2016-08-01

    Three soils polluted by municipal solid waste (MSW) incineration residues and containing various concentrations of Cu, Pb, Sb, Sn and Zn were treated using magnetism, gravity separation (jig and shaking table) and flotation/leaching. The process removed between 18% and 39% of the contaminants present in soil 1, between 31% and 53% of the contaminants present in soil 2 and between 42% and 56% of the contaminants present in soil 3. Polycyclic aromatic hydrocarbons were present only in soil 3, and the process removed 64% of its PAHs total content. Magnetism seemed to be the most efficient technique to remove metals from contaminated soils, followed by gravity separation and finally flotation/leaching. The global efficiency of the process was higher when the initial contaminant concentrations were lower (smaller proportions of MSW incineration residues). The estimated costs of the process, including direct and indirect costs, varied from $82 to $88 per ton of treated soil depending on the proportion of MSW incineration residues mixed with the soil. PMID:26729603

  6. Anaerobic digestion of residual municipal solid waste using biological-mechanical pre-treatment: the plant of Varennes Jarcy.

    PubMed

    Fruteau de Laclos, H; Thiebaut, E; Saint-Joly, C

    2008-01-01

    Residual municipal solid waste can be treated by anaerobic digestion after a sorting process in order to remove the unwanted materials. After a mechanical sorting the quality of the final compost can hardly cope with requirements for agriculture use. In this way, a more efficient sorting process using a specific equipment that provides a combined biological and mechanical effect, has been implemented on the plant of Varennes Jarcy prior to anaerobic digestion. This paper presents the main results obtained on this plant. The reduction of biodegradable organics in particle lower than 10 mm allows a very efficient separation by screening. An additional ballistic sorting removes the remaining glass. The composition of the resulting sorted waste was close to a source-sorted organic fraction. The sorted waste exhibit methane yields comparable with raw biodegradable organics, showing that the pre-treatment had little impact on anaerobic digestion performance. PMID:18957758

  7. Production and characterization of biochar from agricultural by-products: Overview and use of cotton biomass residues

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biochar is a newly constructed scientific term for a porous carbonaceous solid produced by dry carbonization or pyrolysis and gasification of biomass. Crop residues and agricultural processing byproducts are major source materials for producing bioenergy (syngas and bio-oil) and biochar by pyrolys...

  8. A New Grain Harvesting System for Single Pass Grain Harvest, Biomass Collection, Crop Residue Sizing and Grain Segregation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A cereal grain harvesting system is introduced that combines existing technologies in a unique way to improve cereal grain harvest performance, profitability and efficiently collect biomass. The harvesting system is comprised of three machines – one to gather the crop and prepare the residue for no...

  9. A New Grain Harvesting System for Single-Pass Grain Harvest, Biomass Collection, Crop Residue Sizing, and Grain Segregation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A cereal grain harvesting system is introduced that combines existing technologies in a unique way to improve cereal grain harvest performance, profitability and efficiently collect biomass. The harvesting system is comprised of three machines – one to gather the crop and prepare the residue for no...

  10. Comparison of organochlorine residues in human adipose tissue autopsy samples from two Ontario municipalities

    SciTech Connect

    Williams, D.T.; LeBel, G.L.; Junkins, E.

    1984-01-01

    Human adipose tissue samples obtained during autopsies in a Canadian Great Lakes community, Kingston, Ontario, and a second community, Ottawa, Ontario, were analyzed for organochlorine pesticides, polychlorobiphenyls, chlorobenzenes, and chlorophenols. Significantly different levels of Dichlorodiphenyl-dichlorethane, mirex, hexachlorobenzene, and 2,3,4,6-tetrachlorophenol were found in Kingston adipose tissues compared to Ottawa tissues. Residue levels of oxychlordane, mirex, and polychlorinated biphenyls were significantly different in Kingston males versus Kingston females. The means and ranges of residue levels were contrasted with those reported in previous Canadian surveys.

  11. Determining pathogen and indicator levels in Class B municipal organic residuals used for land application

    EPA Science Inventory

    Biosolids are nutrient rich organic residuals that are currently in use to amend soils for food production. Treatment requirements to inactivate pathogens for production of Class A biosolids are energy intensive. One less energy intensive alternative is to treat biosolids to Cl...

  12. The influence of pH on the leaching behaviour of inorganic components from municipal solid waste APC residues

    SciTech Connect

    Quina, Margarida J. Bordado, Joao C.M.; Quinta-Ferreira, Rosa M.

    2009-09-15

    The influence of pH on the leaching behaviour of air pollution control (APC) residues produced in municipal solid waste incineration (MSWI) is addressed in this study. The residue is considered hazardous waste, and in accordance with their chemical properties, the leaching of contaminants into the environment is the main concern. Several leaching tests can be used for research studies or regulatory purposes, where a wide variety of conditions may be tested. Our work deals mainly with the leaching behaviour of toxic heavy metals (Pb, Cd, Zn, Cr, Ni, Cu) and inorganics associated with soluble salts (Na, K, Ca, Cl). The main goal is to obtain an overview of the leachability of APC residues produced in a Portuguese MSWI process. Among the different variables that may have influence on the leaching behaviour, pH of the leachant solution is the most important one, and was evaluated through pH static tests. The acid neutralization capacity (ANC) of the residue was also determined, which is in the range of 6.2-6.8 meq g{sup -1} (for pH = 7) and 10.1-11.6 meq g{sup -1} (for pH = 4). The analysis of the leaching behaviour is particularly important when the leaching is solubility controlled. The amphoteric behaviour of some elements was observed, namely for Pb and Zn, which is characterized through high solubilization at low and high pH and moderate or low solubility at neutral or moderate high pH. The solubility curves for Pb, Cd, Zn, Cr, Ni and Cu as a function of pH were obtained, which are very useful for predicting the leaching behaviour in different scenarios. The solubility of K and Na reveals to be nearly independent of the solution pH and the released amount is mainly availability-controlled. Moreover, the pH static test showed that Cl{sup -} is the most pH-independent species. The APC residue turns out to be a hazardous waste because of the high leaching of lead and chloride. On the other hand, leaching of elements like cadmium, nickel and copper is limited by the

  13. A pilot and field investigation on mobility of PCDDs/PCDFs in landfill site with municipal solid waste incineration residue.

    PubMed

    Osako, Masahiro; Kim, Yong-Jin; Lee, Dong-Hoon

    2002-09-01

    A field investigation by boring was carried out in a landfill site primarily with municipal solid waste incineration residue. From the collected core samples, vertical profiles of homologous content of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDDs/PCDFs) in the landfill layer were traced and the behavior of PCDDs/PCDFs was examined. In addition, a pilot-scale study was conducted on the PCDDs/PCDFs leached from incineration fly ash and the treated one using large landfill simulation columns (lysimeters) and the leaching behavior of PCDDs/PCDFs was examined. As a result, it was found that the coexistence of dissolved coloring constituents (DCCs), which might be composed of constituents like dissolved humic matters having strong affinity for hydrophobic organic pollutants, could enhance the leachability of PCDDs/PCDFs, thus contributing to the vertical movement and leaching behavior of PCDDs/PCDFs in the landfill layers of the incineration residue. Moreover, it is highly probable that DCCs derive from the unburned carbon in the bottom ash mixed and buried with the fly ash containing a high content of PCDDs/PCDFs. PMID:12222779

  14. Heat, electricity, or transportation? The optimal use of residual and waste biomass in Europe from an environmental perspective.

    PubMed

    Steubing, Bernhard; Zah, Rainer; Ludwig, Christian

    2012-01-01

    The optimal use of forest energy wood, industrial wood residues, waste wood, agricultural residues, animal manure, biowaste, and sewage sludge in 2010 and 2030 was assessed for Europe. An energy system model was developed comprising 13 principal fossil technologies for the production of heat, electricity, and transport and 173 bioenergy conversion routes. The net environmental benefits of substituting fossil energy with bioenergy were calculated for all approximately 1500 combinations based on life cycle assessment (LCA) results. An optimization model determines the best use of biomass for different environmental indicators within the quantified EU-27 context of biomass availability and fossil energy utilization. Key factors determining the optimal use of biomass are the conversion efficiencies of bioenergy technologies and the kind and quantity of fossil energy technologies that can be substituted. Provided that heat can be used efficiently, optimizations for different environmental indicators almost always indicate that woody biomass is best used for combined heat and power generation, if coal, oil, or fuel oil based technologies can be substituted. The benefits of its conversion to SNG or ethanol are significantly lower. For non-woody biomass electricity generation, transportation, and heating yield almost comparable benefits as long as high conversion efficiencies and optimal substitutions are assured. The shares of fossil heat, electricity, and transportation that could be replaced with bioenergy are also provided. PMID:22091634

  15. COSMOS-rice technology abrogates the biotoxic effects of municipal solid waste incinerator residues.

    PubMed

    Guarienti, Michela; Cardozo, Sdenka Moscoso; Borgese, Laura; Lira, Gloria Rodrigo; Depero, Laura E; Bontempi, Elza; Presta, Marco

    2016-07-01

    Fly ashes generated by municipal solid waste incinerator (MSWI) are classified as hazardous waste and usually landfilled. For the sustainable reuse of these materials is necessary to reduce the resulting impact on human health and environment. The COSMOS-rice technology has been recently proposed for the treatment of fly ashes mixed with rice husk ash, to obtain a low-cost composite material with significant performances. Here, aquatic biotoxicity assays, including daphnidae and zebrafish embryo-based tests, were used to assess the biosafety efficacy of this technology. Exposure to lixiviated MSWI fly ash caused dose-dependent biotoxic effects on daphnidae and zebrafish embryos with alterations of embryonic development, teratogenous defects and apoptotic events. On the contrary, no biotoxic effects were observed in daphnidae and zebrafish embryos exposed to lixiviated COSMOS-rice material. Accordingly, whole-mount in situ hybridization analysis of the expression of various tissue-specific genes in zebrafish embryos provided genetic evidence about the ability of COSMOS-rice stabilization process to minimize the biotoxic effects of MSWI fly ash. These results demonstrate at the biological level that the newly developed COSMOS-rice technology is an efficient and cost-effective method to process MSWI fly ash, producing a biologically safe and reusable material. PMID:27149148

  16. Stabilization/solidification of a municipal solid waste incineration residue using fly ash-based geopolymers.

    PubMed

    Luna Galiano, Y; Fernández Pereira, C; Vale, J

    2011-01-15

    The stabilization/solidification (S/S) of a municipal solid waste incineration (MSWI) fly ash containing hazardous metals such as Pb, Cd, Cr, Zn or Ba by means of geopolymerization technology is described in this paper. Different reagents such as sodium hydroxide, potassium hydroxide, sodium silicate, potassium silicate, kaolin, metakaolin and ground blast furnace slag have been used. Mixtures of MSWI waste with these kinds of geopolymeric materials and class F coal fly ash used as silica and alumina source have been processed to study the potential of geopolymers as waste immobilizing agents. To this end, the effects of curing conditions and composition have been tested. S/S solids are submitted to compressive strength and leaching tests to assess the results obtained and to evaluate the efficiency of the treatment. Compressive strength values in the range 1-9 MPa were easily obtained at 7 and 28 days. Concentrations of the metals leached from S/S products were strongly pH dependent, showing that the leachate pH was the most important variable for the immobilization of metals. Comparison of fly ash-based geopolymer systems with classical Portland cement stabilization methods has also been accomplished. PMID:20943314

  17. Residues of organochlorine pesticides and PCBs in some Brazilian municipal solid waste compost.

    PubMed

    Lourencetti, Carolina; Favoreto, Rodrigo; Marchi, Mary R R; Ribeiro, Maria L

    2007-08-01

    Persistent organic pollutants (POPs), organochlorine pesticides and polychlorinated biphenyls (PCBs), listed as per the Stockholm Convention (alpha -HCH, beta -HCH, gamma -HCH, p,p'-DDT, o,p'-DDT, p,p'-DDD, p,p'-DDE, aldrin, endrin, dieldrin, PCBs 28, 52, 118, 138, 153, and 180), were analyzed in municipal solid waste (MSW) compost samples from three different Brazilian composting plants located in three São Paulo State cities: Araras, Araraquara and São Paulo (Vila Leopoldinha). Quantitative and qualitative analyses were carried out using gas chromatography electron capture detection (GC-ECD) and gas chromatography mass spectrometry (GC-MS) (Ion Trap, electron impact ionization), respectively. The samples were analyzed in triplicate and the target POPs were not detected by GC-ECD. Twelve pollutants were identified in two samples when qualitative analysis (GC-MS) was used (beta -HCH, gamma -HCH, p,p'-DDT, o,p'-DDT, p,p'-DDD, and p,p'-DDE, PCBs 28, 118, 138, 153 and 180). The composting process has advantages such as urban solid waste reduction and landfill life-span increase, however the MSW compost quality, which can be utilized for agricultural purposes, should be evaluated and be controlled. This kind of study is the first step in making available information to answer questions regarding MSW compost for sustainable agricultural use, such as the pollutants accumulation in soil and in groundwater, and plants uptake. PMID:17701705

  18. Analysis of the lignocellulosic components of biomass residues for biorefinery opportunities.

    PubMed

    Rambo, M K D; Schmidt, F L; Ferreira, M M C

    2015-11-01

    The present study aims to identify the renewable resources available in Brazil such as açai seed, coconut husks, coffee husks, rice husks, eucalyptus sawdust, grass, soy peel, bamboo, banana stems and banana stalks. To identify such renewable energy sources, samples were examined for their physical and chemical characteristics using X-ray diffraction (XRD), proximate and ultimate analyses, thermogravimetric analysis (TGA), calorific value determination, near-infrared (NIR) spectroscopy, UV spectroscopy, high-pH anion-exchange chromatography (HPAEC-PAD) and accelerated solvent extraction (ASE). Among the biomasses, açai and coffee exhibited higher total sugar content, 67.70% and 62.55%, respectively. Sawdust exhibited low ash, along with the highest calorific value and lignin content. The highest glucose contents were observed in bamboo (44.65%) and sawdust (38.80%). The maximum yield for the bioproducts levulinic acid (LA), formic acid (FA) and furfural were estimated; açai exhibited the highest yield of LA and FA, while coffee exhibited the best furfural yield. All of these properties indicate that the residues are potential candidates for bioenergy production. PMID:26452879

  19. Environmental impact of APC residues from municipal solid waste incineration: Reuse assessment based on soil and surface water protection criteria

    SciTech Connect

    Quina, Margarida J.; Bordado, Joao C.M.; Quinta-Ferreira, Rosa M.

    2011-09-15

    Highlights: > The Dutch Building Material Decree (BMD) was used to APC residues from MSWI. > BMD is a straightforward tool to calculate expectable loads to the environment of common pollutants. > Chloride load to the environment lead to classification of building material not allowed. > At least a pre-treatment (e.g. washing) is required in order to remove soluble salts. > The stabilization with phosphates or silicates eliminate the problem of heavy metals. - Abstract: Waste management and environmental protection are mandatory requirements of modern society. In our study, air pollution control (APC) residues from municipal solid waste incinerators (MSWI) were considered as a mixture of fly ash and fine particulate solids collected in scrubbers and fabric filters. These are hazardous wastes and require treatment before landfill. Although there are a number of treatment options, it is highly recommended to find practical applications rather than just dump them in landfill sites. In general, for using a construction material, beyond technical specifications also soil and surface water criteria may be used to ensure environmental protection. The Dutch Building Materials Decree (BMD) is a valuable tool in this respect and it was used to investigate which properties do not meet the threshold criteria so that APC residues can be further used as secondary building material. To this end, some scenarios were evaluated by considering release of inorganic species from unmoulded and moulded applications. The main conclusion is that the high amount of soluble salts makes the APC residues a building material prohibited in any of the conditions tested. In case of moulding materials, the limits of heavy metals are complied, and their use in Category 1 would be allowed. However, also in this case, the soluble salts lead to the classification of 'building material not allowed'. The treatments with phosphates or silicates are able to solve the problem of heavy metals, but

  20. Ciprofloxacin Residues in Municipal Biosolid Compost Do Not Selectively Enrich Populations of Resistant Bacteria

    PubMed Central

    Youngquist, Caitlin P.; Liu, Jinxin; Orfe, Lisa H.; Jones, Stephen S.

    2014-01-01

    Biosolids and livestock manure are valuable high-carbon soil amendments, but they commonly contain antibiotic residues that might persist after land application. While composting reduces the concentration of extractable antibiotics in these materials, if the starting concentration is sufficiently high then remaining residues could impact microbial communities in the compost and soil to which these materials are applied. To examine this issue, ciprofloxacin was added to biosolid compost feedstock to achieve a total concentration of 19 ppm, approximately 5-fold higher than that normally detected by liquid chromatography-tandem mass spectrometry (LC-MS/MS) (1 to 3.5 ppm). This feedstock was placed into mesh bags that were buried in aerated compost bays. Once a week, a set of bags was removed and analyzed (treated and untreated, three replicates of each; 4 weeks). Addition of ciprofloxacin had no effect on the recovery of resistant bacteria at any time point (P = 0.86), and a separate bioassay showed that aqueous extractions from materials with an estimated 59 ppm ciprofloxacin had no effect on the growth of a susceptible strain of Escherichia coli (P = 0.28). Regression analysis showed that growth of the susceptible strain of E. coli can be reduced given a sufficiently high concentration of ciprofloxacin (P < 0.007), a result that is consistent with adsorption being the primary mechanism of sequestration. While analytical methods detected biologically significant concentrations of ciprofloxacin in the materials tested here, the culture-based methods were consistent with the materials having sufficient adsorptive capacity to prevent typical concentrations of ciprofloxacin residues from selectively enriching populations of resistant bacteria. PMID:25261519

  1. The good, the bad or the ugly: Microbial biomass of biogas residues as a contributor to soil carbon cycle

    NASA Astrophysics Data System (ADS)

    Coban, H.; Miltner, A.; Kaestner, M.

    2013-12-01

    Loss of soil organic matter is a recent problem in soils all over the world. This can be related to enhanced mineralization of the soil organic matter due to land use change, which is a source of anthropogenic carbon dioxide increase. For example, the carbon input from plant residues is reduced because of the increased cultivation of bioenergy crops. In order to avoid soil degradation, application of biogas residues is a common practice in such areas. Biogas residues are side products of biogas production and contain microbial biomass. Application of these residues as soil additive influences the soil microorganisms as well as the carbon cycle. We study this effect by incubating 13C-labeled biogas residues in an arable soil from the Static Fertilization Experiment in Bad Lauchstaedt, Germany. Labeled residues were produced via labeling of active microbial biomass by addition of KH13CO3 to biogas reactors. High enrichment in the various phospholipid fatty acids proved the successful labeling of the biomass. The labeled biogas residues are being long-term incubated in the soil. During incubation, we monitor the fate of the carbon by analyzing the label in phospholipid fatty acids, amino acids as well as carbon dioxide. This allows us to trace the fate of the biogas residues-derived C in soil and to quantify the effect on the transformation of the natural soil organic matter (e.g. negative effects such as priming effects). Also, microbial community dynamics will be determined using molecular biology tools such as denaturing gradient gel electrophoresis (DGGE) and real-time quantitative PCR (Q-PCR). In order to prevent potentially negative effects, various additives such as charred biomaterials, clays and chopped bark will be tested to improve the carbon storage in soil. In conclusion, this study investigates the fate and impact of biogas residues used as a soil additive on the soil microbial community and amount of soil organic matter. It is aimed to understand and

  2. Bioethanol production from carbohydrate-enriched residual biomass obtained after lipid extraction of Chlorella sp. KR-1.

    PubMed

    Lee, Ok Kyung; Oh, You-Kwan; Lee, Eun Yeol

    2015-11-01

    The residual biomass of Chlorella sp. KR-1 obtained after lipid extraction was used for saccharification and bioethanol production. The carbohydrate was saccharified using simple enzymatic and chemical methods using Pectinex at pH 5.5 and 45°C and 0.3N HCl at 121°C for 15min with 76.9% and 98.2% yield, respectively, without any pretreatment. The residual biomass contained 49.7% carbohydrate consisting of 82.4% fermentable sugar and 17.6% non-fermentable sugar, which is valuable for bioethanol fermentation. Approximately 98.2% of the total carbohydrate was converted into monosaccharide (fermentable+non-fermentable sugar) using dilute acid saccharification. The fermentable sugar was subsequently fermented to bioethanol through separate hydrolysis and fermentation with a fermentation yield of 79.3%. Overall, 0.4g ethanol/g fermentable sugar and 0.16g ethanol/g residual biomass were produced. PMID:26218538

  3. Physicochemical Characterization of various Vietnamese Biomass Residue-derived Biochars (wood, bamboo and risk husk)

    NASA Astrophysics Data System (ADS)

    Nguyen, Hien

    2016-04-01

    This study compares the physico-chemical characteristics of various biocchars produced from biomass residues in Vietnam such as fired wood, rice husk, and bamboo. Wood biochar (WBC), rice husk biochar (RHBC), and bamboo biochar (BBC) were produced under limited oxygen conditions using equipment available locally in Vietnam, known as a Top-Lift Updraft Drum (TLUD). The three biochars are alkaline with pH around 10, but were found to have quite significantly different physico-chemical characteristics. Surface areas (measured by BET) were found to be very significantly higher for WBC and BBC with 479.34 m2/g and 434.53 m2/g, respectively, compared to RHBC (3.29 m2/g). The SEM images correspond with the BET surface area, showing a smooth surface for RHBC, a hollow surface for BBC, and a rough surface for WBC. Total carbon (TC) of WBC and BBC are above 80%, while RHBC has only 47.95% TC. Despite having different TC, the content of hydrogen among the biochars is similar, ranging from 2.07% to 2.34%, and the ratio of H/C also follows the same trend. Thus, although the biochars are produced by the same method, the various feedstocks lead to different physico-chemical properties. Ongoing work is linking these physico-chemical properties to fertiliser efficiencies in terms of nitrate and ammonia adsorption and retention capacities, in order to design optimal biochar properties for use in fertilisation. Key words: physico-chemical characteristic, biochar, surface area, SEM, total carbon, feedstock

  4. CO2 emission and structural characteristics of two calcareous soils amended with municipal solid waste and plant residue

    NASA Astrophysics Data System (ADS)

    Yazdanpanah, N.

    2016-01-01

    This investigation examines the effect of different amendments on selected soil physical and biological properties over a 24-month period in two cropland fields. Urban municipal solid waste (MSW) compost and alfalfa residue (AR) were used as different organic amendments at the rates of 0 (control), 10 and 30 Mg ha-1 to a clay loam soil and a loamy sand soil in a semiarid region. Results showed that the soil improvement was controlled by the application rate and decomposability of amendments and soil type. The addition of organic amendments to the soils improved aggregate stability and consequently enhanced total porosity, especially macropore fraction. The increased soil organic carbon (SOC) and total porosity values as compared to the control treatment were greater in the loamy sand soil than in the clay loam soil. Moreover, compared to the microbial respiration of control plots, the application of MSW resulted in higher values of microbial respiration in the clay loam soil than in the loamy sand soil, whereas the reverse was found for AR. Linear and power functions were provided for the relationships between microbial respiration and SOC in the loamy sand and clay loam soils, respectively. Also, CO2 emission was stimulated significantly as power functions of the total porosity and the ratio of macroporosity to microporosity. However, the soil microbial respiration and carbon storage improved aggregate stability and pore size distribution, and as a response, soil porosity, especially the macropore fraction, controlled CO2 flux.

  5. CO2 emission and structural characteristics of two calcareous soils amended with municipal solid waste and plant residue

    NASA Astrophysics Data System (ADS)

    Yazdanpanah, N.

    2015-11-01

    This investigation examines the effect of different amendments on selected soil physical and biological properties over a twenty four month period in two cropland fields. Urban municipal solid waste (MSW) compost and alfalfa residue (AR) were used as different organic amendments at the rates of 0 (control), 10 and 30 Mg ha-1 to a clay loam soil and a loamy sand soil in a semiarid region. Result showed that the soil improvement was controlled by the application rate and decomposability of amendments and soil type. The addition of organic amendments to the soils improved aggregate stability and consequently enhanced total porosity, especially macro pores fraction. The increased soil organic carbon (SOC) and total porosity values as compared to the control treatment were greater in the loamy sand soil than in the clay loam soil. Moreover, compared to the microbial respiration of control plots, the application of MSW resulted in higher values of microbial respiration in the clay loam soil than in the loamy sand soil, whereas the reverse order was found for AR. Linear and power functions were provided for the relationships between microbial respiration and SOC in the loamy sand and clay loam soils, respectively. Also, CO2 emission was stimulated significantly as power functions of the total porosity and the ratio of macro to micro pores. However, the soil microbial respiration and carbon storage improved aggregate stability and pore size distribution, as a response, soil porosity especially macro pores fraction controlled CO2 flux.

  6. Investigation of 1,4-dioxane originating from incineration residues produced by incineration of municipal solid waste.

    PubMed

    Fujiwara, Taku; Tamada, Toru; Kurata, Yasundo; Ono, Yusaku; Kose, Tomohiro; Ono, Yoshiro; Nishimura, Fumitake; Ohtoshi, Kunio

    2008-03-01

    As a groundwater contaminant, 1,4-dioxane is of considerable concern because of its toxicity, refractory nature to degradation, and rapid migration within an aquifer. Although landfill leachate has been reported to contain significant levels of 1,4-dioxane, the origin of 1,4-dioxane in leachate has not been clarified until now. In this study, the origins of 1,4-dioxane in landfill leachate were investigated at 38 landfill sites and three incineration plants in Japan. Extremely high levels of 1,4-dioxane 89 and 340 microg l(-1), were detected in leachate from two of the landfill sites sampled. Assessments of leachate and measurement of 1,4-dioxane in incineration residues revealed the most likely source of 1,4-dioxane in the leachate to be the fly ash produced by municipal solid waste incinerators. Effective removal of 1,4-dioxane in leachate from fly ash was achieved using heating dechlorination systems. Rapid leaching of 1,4-dioxane observed from fly ash in a sequential batch extraction indicated that the incorporation of a waste washing process could also be effective for the removal of 1,4-dioxane in fly ash. PMID:18191439

  7. Determining pathogen and indicator levels in class B municipal organic residuals used for land application.

    PubMed

    Rhodes, Eric R; Boczek, Laura A; Ware, Michael W; McKay, Mary; Hoelle, Jill M; Schoen, Mary; Villegas, Eric N

    2015-01-01

    Biosolids are nutrient-rich organic residuals that are currently used to amend soils for food production. Treatment requirements to inactivate pathogens for production of Class A biosolids are energy intensive. One less energy intensive alternative is to treat biosolids to Class B standards, but it could result in higher pathogen loads. Quantitative microbial risk assessments models have been developed on land application of Class B biosolids but contain many uncertainties because of limited data on specific pathogen densities and the use of fecal indicator organisms as accurate surrogates of pathogen loads. To address this gap, a 12-mo study of the levels and relationships between , , and human adenovirus (HAdV) with fecal coliform, somatic, and F-RNA coliphage levels in Class B biosolids from nine wastewater treatment plants throughout the United States was conducted. Results revealed that fecal coliform, somatic, and F-RNA coliphage densities were consistent throughout the year. More important, results revealed that HAdV ( = 2.5 × 10 genome copies dry g) and ( = 4.14 × 10 cysts dry g) were in all biosolids samples regardless of treatment processes, location, or season. oocysts were also detected (38% positive; range: 0-1.9 × 10 oocysts dry g), albeit sporadically. Positive correlations among three fecal indicator organisms and HAdV, but not protozoa, were also observed. Overall, this study reveals that high concentrations of enteric pathogens (e.g., , , and HAdV) are present in biosolids throughout the United States. Microbial densities found can further assist management and policymakers in establishing more accurate risk assessment models associated with land application of Class B biosolids. PMID:25602342

  8. Chemical reaction engineering studies on cocracking of petroleum vacuum residue with coal, plastics, and biomass (bagasse and petrocrop)

    SciTech Connect

    Ahmaruzzaman, M.; Sharma, D.K.

    2007-07-01

    This article deals with the studies on cocracking of petroleum vacuum residue (XVR) with thermosetting plastic, I. e., bakelite (BL), Samla coal (SC), biomass, I. e., bagasse (BG) or C. procera (CL) and their binary, ternary, and quaternary mixtures in a thermogravimetric analyzer (TGA). The kinetic studies were performed using the Coats and Redfern kinetic modeling equation. The overall activation energies obtained were 25 kJ/mole for petroleum vacuum residue, 99 kJ/mole for polypropylene, 21 kJ/mole for coal, 23 kJ/mole for Calotropis procera, and 25 kJ/mole for the combination of these four materials. However, other models, such as van Krevelan et al. and Horowitz and Metzger have also been used in some cases to compare the results with those obtained by the Coats and Redfern kinetic models. In the present work, the effect of catalysts on the cracking of Basra vacuum residue (BVR) has also been reported.

  9. Lipid Extracted Microalgal Biomass Residue as a Fertilizer Substitute for Zea mays L.

    PubMed

    Maurya, Rahulkumar; Chokshi, Kaumeel; Ghosh, Tonmoy; Trivedi, Khanjan; Pancha, Imran; Kubavat, Denish; Mishra, Sandhya; Ghosh, Arup

    2015-01-01

    High volumes of lipid extracted microalgal biomass residues (LMBRs) are expected to be produced upon commencement of biodiesel production on a large scale, thus necessitating its value addition for sustainable development. LMBRs of Chlorella variabilis and Lyngbya majuscula were employed to substitute the nitrogen content of recommended rate of fertilizer (RRF) for Zea mays L. The pot experiment comprised of 10 treatments, i.e., T1 (No fertilizer); T2 (RRF-120 N: 60 P2O5: 40 K2O kg ha(-1)); T3 to T6-100, 75, 50, and 25% N through LMBR of the Chlorella sp., respectively; T7 to T10-100, 75, 50, and 25% N through LMBR of Lyngbya sp., respectively. It was found that all LMBR substitution treatments were at par to RRF with respect to grain yield production. T10 gave the highest grain yield (65.16 g plant(-1)), which was closely followed by that (63.48 g plant(-1)) under T5. T10 also recorded the highest phosphorus and potassium contents in grains. T4 was markedly superior over control in terms of dry matter accumulation (DMA) as well as carbohydrate content, which was ascribed to higher pigment content and photosynthetic activity in leaves. Even though considerably lower DMA was obtained in Lyngbya treatments, which might have been due to the presence of some toxic factors, no reduction in grain yield was apparent. The length of the tassel was significantly higher in either of the LMBRs at any substitution rates over RRF, except T6 and T7. The ascorbate peroxidase activity decreased with decreasing dose of Chlorella LMBR, while all the Lyngbya LMBR treatments recorded lower activity, which were at par with each other. Among the Chlorella treatments, only T5 recorded significantly higher values of glutathione reductase activity over RRF, while the rest were at par. There were significant increases in carbohydrate and crude fat, respectively, only in T4 and T3 over RRF, while no change was observed in crude protein due to LMBR treatments. Apparently, there was no

  10. Lipid Extracted Microalgal Biomass Residue as a Fertilizer Substitute for Zea mays L.

    PubMed Central

    Maurya, Rahulkumar; Chokshi, Kaumeel; Ghosh, Tonmoy; Trivedi, Khanjan; Pancha, Imran; Kubavat, Denish; Mishra, Sandhya; Ghosh, Arup

    2016-01-01

    High volumes of lipid extracted microalgal biomass residues (LMBRs) are expected to be produced upon commencement of biodiesel production on a large scale, thus necessitating its value addition for sustainable development. LMBRs of Chlorella variabilis and Lyngbya majuscula were employed to substitute the nitrogen content of recommended rate of fertilizer (RRF) for Zea mays L. The pot experiment comprised of 10 treatments, i.e., T1 (No fertilizer); T2 (RRF-120 N: 60 P2O5: 40 K2O kg ha−1); T3 to T6—100, 75, 50, and 25% N through LMBR of the Chlorella sp., respectively; T7 to T10—100, 75, 50, and 25% N through LMBR of Lyngbya sp., respectively. It was found that all LMBR substitution treatments were at par to RRF with respect to grain yield production. T10 gave the highest grain yield (65.16 g plant−1), which was closely followed by that (63.48 g plant−1) under T5. T10 also recorded the highest phosphorus and potassium contents in grains. T4 was markedly superior over control in terms of dry matter accumulation (DMA) as well as carbohydrate content, which was ascribed to higher pigment content and photosynthetic activity in leaves. Even though considerably lower DMA was obtained in Lyngbya treatments, which might have been due to the presence of some toxic factors, no reduction in grain yield was apparent. The length of the tassel was significantly higher in either of the LMBRs at any substitution rates over RRF, except T6 and T7. The ascorbate peroxidase activity decreased with decreasing dose of Chlorella LMBR, while all the Lyngbya LMBR treatments recorded lower activity, which were at par with each other. Among the Chlorella treatments, only T5 recorded significantly higher values of glutathione reductase activity over RRF, while the rest were at par. There were significant increases in carbohydrate and crude fat, respectively, only in T4 and T3 over RRF, while no change was observed in crude protein due to LMBR treatments. Apparently, there was no

  11. SERI Biomass Program

    NASA Astrophysics Data System (ADS)

    Bergeron, P. W.; Corder, R. E.; Hill, A. M.; Lindsey, H.; Lowenstein, M. Z.

    1983-02-01

    The biomass with which this report is concerned includes aquatic plants, which can be converted into liquid fuels and chemicals; organic wastes (crop residues as well as animal and municipal wastes), from which biogas can be produced via anerobic digestion; and organic or inorganic waste streams, from which hydrogen can be produced by photobiological processes. The Biomass Program Office supports research in three areas which, although distinct, all use living organisms to create the desired products. The Aquatic Species Program (ASP) supports research on organisms that are themselves processed into the final products, while the Anaerobic Digestion (ADP) and Photo/Biological Hydrogen Program (P/BHP) deals with organisms that transform waste streams into energy products. The P/BHP is also investigating systems using water as a feedstock and cell-free systems which do not utilize living organisms. This report summarizes the progress and research accomplishments of the SERI Biomass Program during FY 1982.

  12. Decreased PCDD/F formation when co-firing a waste fuel and biomass in a CFB boiler by addition of sulphates or municipal sewage sludge

    SciTech Connect

    Åmand, Lars-Erik; Kassman, Håkan

    2013-08-15

    Highlights: • Two strategies to reduce PCDD/F formation when co-firing solid recovered fuel (SRF) and biomass. • They were co-combustion with municipal sewage sludge (MSS) and addition of ammonium sulphate. • PCDD/Fs were significantly reduced for a biomass rich in chlorine when adding ammonium sulphate. • MSS had a suppressing effect on PCDD/F formation during co-combustion with SRF. • A link is presented between gaseous alkali chlorides, chlorine in deposits and PCDD/F formation. - Abstract: Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are formed during waste incineration and in waste-to-energy boilers. Incomplete combustion, too short residence times at low combustion temperatures (<700 °C), incineration of electronic waste and plastic waste containing chlorine are all factors influencing the formation of PCDD/Fs in boilers. The impact of chlorine and catalysing metals (such as copper and iron) in the fuel on PCDD/F formation was studied in a 12 MW{sub th} circulating fluidised bed (CFB) boiler. The PCDD/F concentrations in the raw gas after the convection pass of the boiler and in the fly ashes were compared. The fuel types were a so-called clean biomass with low content of chlorine, biomass with enhanced content of chlorine from supply of PVC, and solid recovered fuel (SRF) which is a waste fuel containing higher concentrations of both chlorine, and catalysing metals. The PCDD/F formation increased for the biomass with enhanced chlorine content and it was significantly reduced in the raw gas as well as in the fly ashes by injection of ammonium sulphate. A link, the alkali chloride track, is demonstrated between the level of alkali chlorides in the gas phase, the chlorine content in the deposits in the convection pass and finally the PCDD/F formation. The formation of PCDD/Fs was also significantly reduced during co-combustion of SRF with municipal sewage sludge (MSS) compared to when SRF was fired without MSS

  13. Environmental analysis of biomass-ethanol facilities

    SciTech Connect

    Corbus, D.; Putsche, V.

    1995-12-01

    This report analyzes the environmental regulatory requirements for several process configurations of a biomass-to-ethanol facility. It also evaluates the impact of two feedstocks (municipal solid waste [MSW] and agricultural residues) and three facility sizes (1000, 2000, and 3000 dry tons per day [dtpd]) on the environmental requirements. The basic biomass ethanol process has five major steps: (1) Milling, (2) Pretreatment, (3) Cofermentation, (4) Enzyme production, (5) Product recovery. Each step could have environmental impacts and thus be subject to regulation. Facilities that process 2000 dtpd of MSW or agricultural residues would produce 69 and 79 million gallons of ethanol, respectively.

  14. Pasture burning in Amazonia: Dynamics of residual biomass and the storage and release of aboveground carbon

    NASA Astrophysics Data System (ADS)

    Barbosa, Reinaldo Imbrózio; Fearnside, Philip M.

    1996-11-01

    Aboveground biomass in cattle pasture converted from tropical dense forest was studied both before and after reburning in Brazilian Amazonia. In a 7-year-old pasture studied in Apiaú, Roraima, the aboveground dry weight of biomass (live plus dead) exposed to burning consisted of 96.3 t ha-1 of original forest remains, 6.2 t ha-1 of secondary successional vegetation (woody invaders in the pasture), and 8.0 t ha-1 of pasture grass (carbon contents 48.2%, 45.4%, and 42.2%, respectively). In terms of carbon, burning efficiencies for these three categories were 13.2%, 66.7% and 94.6%, respectively. Net charcoal formation was 0.35 t C ha-1 or 0.63% of the carbon exposed to the reburn, while the total accumulated since conversion (including the initial burn) is estimated at 2.3 t ha-1 (1.82% of the predeforestation aboveground biomass carbon stock). The dynamics of the original forest remains were represented in simulations that included parameters such as charcoal formation, burning efficiency and carbon concentration in different biomass components. Releases from initial burning of the cleared forest (44.0 t C ha-1) plus releases over the course of the succeeding decade through combustion (12.5 t C ha-1) and decay (51.5 t C ha-1) total 92% of the original forest biomass carbon (126 t C ha-1). Of biomass carbon remaining after the initial burn (84.3 t C ha-1), 76.0% is released: 61.1% through decay and 14.9% through combustion in reburns, while 1.2% is net conversion to charcoal in the reburns. These results indicate an amount of charcoal accumulation that is smaller than some carbon calculations have assumed, therefore suggesting a greater impact on global warming from conversion of forest to pasture.

  15. Cellulosic butanol production from agricultural biomass and residues: Recent advances in technology

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This chapter details the recent advances made on bioconversion of lignocellulosic biomass to butanol, a superior biofuel that can be used in internal combustion engines or transportation industry. It should be noted that butanol producing cultures cannot tolerate or produce more than 20-30 g/L of ac...

  16. Lipid Production of Heterotrophic Chlorella sp. from Hydrolysate Mixtures of Lipid-Extracted Microalgal Biomass Residues and Molasses.

    PubMed

    Zheng, Hongli; Ma, Xiaochen; Gao, Zhen; Wan, Yiqin; Min, Min; Zhou, Wenguang; Li, Yun; Liu, Yuhuan; Huang, He; Chen, Paul; Ruan, Roger

    2015-10-01

    This study investigated the feasibility of lipid production of Chlorella sp. from waste materials. Lipid-extracted microalgal biomass residues (LMBRs) and molasses were hydrolyzed, and their hydrolysates were analyzed. Five different hydrolysate mixture ratios (w/w) of LMBRs/molasses (1/0, 1/1, 1/4, 1/9, and 0/1) were used to cultivate Chlorella sp. The results showed that carbohydrate and protein were the two main compounds in the LMBRs, and carbohydrate was the main compound in the molasses. The highest biomass concentration of 5.58 g/L, Y biomass/sugars of 0.59 g/g, lipid productivity of 335 mg/L/day, and Y lipids/sugars of 0.25 g/g were obtained at the hydrolysate mixture ratio of LMBRs/molasses of 1/4. High C/N ratio promoted the conversion of sugars into lipids. The lipids extracted from Chlorella sp. shared similar lipid profile of soybean oil and is therefore a potential viable biodiesel feedstock. These results showed that Chlorella sp. can utilize mixed sugars and amino acids from LMBRs and molasses to accumulate lipids efficiently, thus reducing the cost of microalgal biodiesel production and improving its economic viability. PMID:26234438

  17. Washington State biomass data book

    SciTech Connect

    Deshaye, J.A.; Kerstetter, J.D.

    1991-07-01

    This is the first edition of the Washington State Biomass Databook. It assess sources and approximate costs of biomass fuels, presents a view of current users, identifies potential users in the public and private sectors, and lists prices of competing energy resources. The summary describes key from data from the categories listed above. Part 1, Biomass Supply, presents data increasing levels of detail on agricultural residues, biogas, municipal solid waste, and wood waste. Part 2, Current Industrial and Commercial Use, demonstrates how biomass is successfully being used in existing facilities as an alternative fuel source. Part 3, Potential Demand, describes potential energy-intensive public and private sector facilities. Part 4, Prices of Competing Energy Resources, shows current suppliers of electricity and natural gas and compares utility company rates. 49 refs., 43 figs., 72 tabs.

  18. Critical analysis of the integration of residual municipal solid waste incineration and selective collection in two Italian tourist areas.

    PubMed

    Ranieri, Ezio; Rada, Elena Cristina; Ragazzi, Marco; Masi, Salvatore; Montanaro, Comasia

    2014-05-13

    Municipal solid waste management is not only a contemporary problem, but also an issue at world level. In detail, the tourist areas are more difficult to be managed. The dynamics of municipal solid waste production in tourist areas is affected by the addition of a significant amount of population equivalent during a few months. Consequences are seen in terms of the amount of municipal solid waste to be managed, but also on the quality of selective collection. In this article two case studies are analyzed in order to point out some strategies useful for a correct management of this problem, also taking into account the interactions with the sector of waste-to-energy. The case studies concern a tourist area in the north of Italy and another area in the south. Peak production is clearly visible during the year. Selective collection variations demonstrate that the tourists' behavior is not adequate to get the same results as with the resident population. PMID:24824166

  19. Properties of thermoplastic composites with cotton and guayule biomass residues as fiber fillers

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This study was conducted to evaluate the suitability of using residual plant fibers from agricultural waste streams as reinforcement in thermoplastic composites. Three groups of plant fibers evaluated included cotton burrs, sticks, and linters from cotton gin waste (CGW), guayule whole plant, and gu...

  20. Decreased PCDD/F formation when co-firing a waste fuel and biomass in a CFB boiler by addition of sulphates or municipal sewage sludge.

    PubMed

    Åmand, Lars-Erik; Kassman, Håkan

    2013-08-01

    Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are formed during waste incineration and in waste-to-energy boilers. Incomplete combustion, too short residence times at low combustion temperatures (<700 °C), incineration of electronic waste and plastic waste containing chlorine are all factors influencing the formation of PCDD/Fs in boilers. The impact of chlorine and catalysing metals (such as copper and iron) in the fuel on PCDD/F formation was studied in a 12 MW(th) circulating fluidised bed (CFB) boiler. The PCDD/F concentrations in the raw gas after the convection pass of the boiler and in the fly ashes were compared. The fuel types were a so-called clean biomass with low content of chlorine, biomass with enhanced content of chlorine from supply of PVC, and solid recovered fuel (SRF) which is a waste fuel containing higher concentrations of both chlorine, and catalysing metals. The PCDD/F formation increased for the biomass with enhanced chlorine content and it was significantly reduced in the raw gas as well as in the fly ashes by injection of ammonium sulphate. A link, the alkali chloride track, is demonstrated between the level of alkali chlorides in the gas phase, the chlorine content in the deposits in the convection pass and finally the PCDD/F formation. The formation of PCDD/Fs was also significantly reduced during co-combustion of SRF with municipal sewage sludge (MSS) compared to when SRF was fired without MSS as additional fuel. PMID:23684693

  1. Laboratory measurements of emissions of nonmethane volatile organic compounds from biomass burning in Chinese crop residues

    NASA Astrophysics Data System (ADS)

    Inomata, S.; Tanimoto, H.; PAN, X.; Taketani, F.; Komazaki, Y.; Miyakawa, T.; Kanaya, Y.; Wang, Z.

    2014-12-01

    The emission factors (EFs) of volatile organic compounds (VOCs) from the burning of Chinese crop residue were investigated as a function of modified combustion efficiency by the laboratory experiments. The VOCs including acetonitrile, aldehydes/ketones, furan, and aromatic hydrocarbons were monitored by proton-transfer-reaction mass spectrometry. Two samples, wheat straw and rape plant, were burned in dry conditions and for some experiments wheat straw was burned under wet conditions. We compared the present data to the field data reported by Kudo et al. [2014]. The agreement between the field and laboratory data was obtained for aromatics for relatively more smoldering data of dry samples but the field data were slightly underestimated compared with the laboratory data for oxygenated VOCs (OVOCs) and acetonitrile. When the EFs from the burning of wet samples were investigated, the underestimations for OVOCs and acetonitrile were improved compared with the data of dry samples. It may be a property of the burning of crop residue in the region of high temperature and high humidity that some inside parts of piled crop residue and/or the crop residue facing on the ground are still wet. But the ratios for acetic acid/glycolaldehyde was still lower than 1. This may suggest that strong loss processes of acetic acid/glycolaldehyde are present in the fresh plume.Kudo S., H. Tanimoto, S. Inomata, S. Saito, X. L. Pan, Y. Kanaya, F. Taketani, Z. F. Wang, H. Chen, H. Dong, M. Zhang, and K. Yamaji (2014), Emissions of nonmethane volatile organic compounds from open crop residue burning in Yangtze River Delta region, China, J. Geophys. Res. Atmos., 119, 7684-7698, doi: 10.1002/2013JD021044.

  2. Bio-oil production via fast pyrolysis of biomass residues from cassava plants in a fluidised-bed reactor.

    PubMed

    Pattiya, Adisak

    2011-01-01

    Biomass residues from cassava plants, namely cassava stalk and cassava rhizome, were pyrolysed in a fluidised-bed reactor for production of bio-oil. The aims of this work were to investigate the yields and properties of pyrolysis products produced from both feedstocks as well as to identify the optimum pyrolysis temperature for obtaining the highest organic bio-oil yields. Results showed that the maximum yields of the liquid bio-oils derived from the stalk and rhizome were 62 wt.% and 65 wt.% on dry basis, respectively. The pyrolysis temperatures that gave highest bio-oil yields for both feedstocks were in the range of 475-510 °C. According to the analysis of the bio-oils properties, the bio-oil derived from cassava rhizome showed better quality than that derived from cassava stalk as the former had lower oxygen content, higher heating value and better storage stability. PMID:20864338

  3. Harvesting residual biomass and swathe-felling with a mobile chipper

    SciTech Connect

    Koch, P.; Nicholson, T.W.

    1980-01-01

    A harvesting machine and auxiliary equipment are being developed to recover logging residues in the form of chips for fuel and fiber, and to deliver such wood into roadside piles at about $11.82/green ton including 30% pretax return on an equipment investment of number470,000. A 575-horsepower tracked mobile chipper equipped with a front-mounted felling bar arranged to cut 6 inches aboveground level across the 9-foot width of the machine fells standing trees (to 12 inches diameter at stump height) and delivers them, along with other logging residues into a three-knife, 550 rev./min. drum chipper mounted immediately behind the felling bar. The felling bar is a 100 to 600 rev./min., 16-inch-diameter, four-knife cylinder extending across the front of the machine near ground level. Chips emerging from the 48-inch-diameter, 47.5-inch-long drum chipper are blown to the rear of the moving machine into one of a pair of self-powered tracked vehicles each carrying a quick-dump chip bin with 10-ton holding capacity. Average speed of the mobile chipper should be one mile per hour over rock-free terrain of less than 30% slope that will support 9 p.s.i. ground pressure. At this speed the harvester will cover about one acre per hour on land averaging 25 tons (green weight) per acre of logging residues in the form of tops and limbs, standing cull trees, and stumps. About 85% of such residue should be recovered as chips. Gross weight of the harvester is about 60,000 pounds. (Refs.1).

  4. Pyrolysis Treatment of Chromite Ore Processing Residue by Biomass: Cellulose Pyrolysis and Cr(VI) Reduction Behavior.

    PubMed

    Zhang, Da-Lei; Zhang, Mei-Yi; Zhang, Chu-Hui; Sun, Ying-Jie; Sun, Xiao; Yuan, Xian-Zheng

    2016-03-15

    The pyrolysis treatment with biomass is a promising technology for the remediation of chromite-ore-processing residue (COPR). However, the mechanism of this process is still unclear. In this study, the behavior of pyrolysis reduction of Cr(VI) by cellulose, the main component of biomass, was elucidated. The results showed that the volatile fraction (VF) of cellulose, ie. gas and tar, was responsible for Cr(VI) reduction. All organic compounds, as well as CO and H2 in VF, potentially reduced Cr(VI). X-ray absorption near-edge structure (XANES) spectroscopy and extended X-ray absorption fine-structure (EXAFS) spectroscopy confirmed the reduction of Cr(VI) to Cr(III) and the formation of amorphous Cr2O3. The remnant Cr(VI) content in COPR can be reduced below the detection limit (2 mg/kg) by the reduction of COPR particle and extension of reaction time between VF and COPR. This study provided a deep insight on the co-pyrolysis of cellulose with Cr(VI) in COPR and an ideal approach by which to characterize and optimize the pyrolysis treatment for COPR by other organics. PMID:26862886

  5. Release of nitrogen precursors from coal and biomass residues in a bubbling fluidized bed

    SciTech Connect

    P. Abelha; I. Gulyurtlu; I. Cabrita

    2008-01-15

    This work was undertaken with the aim of quantifying the relative amounts of NH{sub 3} and HCN released from different residues during their devolatilization under fluidized bed conditions. The results were compared with data collected for bituminous coals of different origin. The relation between amounts of HCN and NH{sub 3} released and the levels of NOX and N{sub 2}O formed during cocombustion was also addressed. The partitioning of nitrogen between volatiles and char was also quantified. The pyrolysis studies were undertaken in a small fluidized bed reactor of 80 mm of ID and 500 mm high using an inert atmosphere (N{sub 2}). The HCN and NH{sub 3} were quantified by bubbling the pyrolysis gases in absorbing solutions which were subsequently analyzed with selective electrodes. The combustion studies were carried out on a pilot installation. The fluidized bed combustor is square in cross section with each side being 300 mm long. There is secondary air supply to the freeboard at different heights to deal with high volatile fuels as almost all waste materials are. The temperatures in the bed and in the freeboard and that of the flue gases leaving the reactor were continuously monitored. The results obtained suggest that, while coal releases nitrogen mostly as HCN, residues like RDF and sewage sludge give out fuel-N in greater quantities as NH{sub 3}. Residues at fluidized bed combustion (FBC) temperatures release more than 80% of the fuel-N with the volatiles. The NH{sub 3} evolved during pyrolysis acted as a reducing agent on NOX emissions. The presence of calcium significantly reduces the emission of N{sub 2}O probably by interfering with HCN chemistry. With high amounts of residues in the fuel mixture, the relative importance of char on the nitrogen chemistry substantially decreases. By using cocombustion, it is possible to reduce fuel-N conversion to NOX and N{sub 2}O, by tuning the amounts of coal and residue in the mixture. 29 refs., 18 figs., 3 tabs.

  6. Bioconversion of waste biomass to useful products

    DOEpatents

    Grady, James L.; Chen, Guang Jiong

    1998-01-01

    A process is provided for converting waste biomass to useful products by gasifying the biomass to produce synthesis gas and converting the synthesis gas substrate to one or more useful products. The present invention is directed to the conversion of biomass wastes including municipal solid waste, sewage sludge, plastic, tires, agricultural residues and the like, as well as coal, to useful products such as hydrogen, ethanol and acetic acid. The overall process includes the steps of gasifying the waste biomass to produce raw synthesis gas, cooling the synthesis gas, converting the synthesis gas to the desired product or products using anaerobic bioconversion, and then recovering the product or products. In accordance with a particular embodiment of the present invention, waste biomass is converted to synthesis gas containing carbon monoxide and, then, the carbon monoxide is converted to hydrogen by an anaerobic microorganism ERIH2, bacillus smithii ATCC No. 55404.

  7. Bioconversion of waste biomass to useful products

    DOEpatents

    Grady, J.L.; Chen, G.J.

    1998-10-13

    A process is provided for converting waste biomass to useful products by gasifying the biomass to produce synthesis gas and converting the synthesis gas substrate to one or more useful products. The present invention is directed to the conversion of biomass wastes including municipal solid waste, sewage sludge, plastic, tires, agricultural residues and the like, as well as coal, to useful products such as hydrogen, ethanol and acetic acid. The overall process includes the steps of gasifying the waste biomass to produce raw synthesis gas, cooling the synthesis gas, converting the synthesis gas to the desired product or products using anaerobic bioconversion, and then recovering the product or products. In accordance with a particular embodiment of the present invention, waste biomass is converted to synthesis gas containing carbon monoxide and, then, the carbon monoxide is converted to hydrogen by an anaerobic microorganism ERIH2, Bacillus smithii ATCC No. 55404. 82 figs.

  8. Oxidative torrefaction of biomass residues and densification of torrefied sawdust to pellets.

    PubMed

    Wang, Congwei; Peng, Jianghong; Li, Hui; Bi, Xiaotao T; Legros, Robert; Lim, C J; Sokhansanj, Shahab

    2013-01-01

    Oxidative torrefaction of sawdust with a carrier gas containing 3-6% O(2) was investigated in a TG and a fluidized bed reactor, with the properties of the torrefied sawdust and pellets compared with traditional torrefaction without any O(2), as well as the dry raw material. It is found that the oxidative torrefaction process produced torrefied sawdust and pellets of similar properties as normally torrefied sawdust and corresponding pellets, especially on the density, energy consumption for pelletization, higher heating value and energy yield. For moisture absorption and hardness of the torrefied pellets, the oxidative torrefaction process showed slightly poor but negligible performance. Therefore, it is feasible to use oxygen laden combustion flue gases as the carrier gas for torrefaction of biomass. Besides, torrefied sawdust can be made into dense and strong pellets of high hydrophobicity at a higher die temperature than normally used in the production of traditional control pellets. PMID:23131655

  9. Natural deep eutectic solvent mediated pretreatment of rice straw: bioanalytical characterization of lignin extract and enzymatic hydrolysis of pretreated biomass residue.

    PubMed

    Kumar, Adepu K; Parikh, Bhumika S; Pravakar, Mohanty

    2016-05-01

    The present investigation demonstrated pretreatment of lignocellulosic biomass rice straw using natural deep eutectic solvents (NADESs), and separation of high-quality lignin and holocellulose in a single step. Qualitative analysis of the NADES extract showed that the extracted lignin was of high purity (>90 %), and quantitative analysis showed that nearly 60 ± 5 % (w/w) of total lignin was separated from the lignocellulosic biomass. Addition of 5.0 % (v/v) water during pretreatment significantly enhanced the total lignin extraction, and nearly 22 ± 3 % more lignin was released from the residual biomass into the NADES extract. X-ray diffraction studies of the untreated and pretreated rice straw biomass showed that the crystallinity index ratio was marginally decreased from 46.4 to 44.3 %, indicating subtle structural alterations in the crystalline and amorphous regions of the cellulosic fractions. Thermogravimetric analysis of the pretreated biomass residue revealed a slightly higher T dcp (295 °C) compared to the T dcp (285 °C) of untreated biomass. Among the tested NADES reagents, lactic acid/choline chloride at molar ratio of 5:1 extracted maximum lignin of 68 ± 4 mg g(-1) from the rice straw biomass, and subsequent enzymatic hydrolysis of the residual holocellulose enriched biomass showed maximum reducing sugars of 333 ± 11 mg g(-1) with a saccharification efficiency of 36.0 ± 3.2 % in 24 h at 10 % solids loading. PMID:26032452

  10. Biomass Logistics

    SciTech Connect

    J. Richard Hess; Kevin L. Kenney; William A. Smith; Ian Bonner; David J. Muth

    2015-04-01

    Equipment manufacturers have made rapid improvements in biomass harvesting and handling equipment. These improvements have increased transportation and handling efficiencies due to higher biomass densities and reduced losses. Improvements in grinder efficiencies and capacity have reduced biomass grinding costs. Biomass collection efficiencies (the ratio of biomass collected to the amount available in the field) as high as 75% for crop residues and greater than 90% for perennial energy crops have also been demonstrated. However, as collection rates increase, the fraction of entrained soil in the biomass increases, and high biomass residue removal rates can violate agronomic sustainability limits. Advancements in quantifying multi-factor sustainability limits to increase removal rate as guided by sustainable residue removal plans, and mitigating soil contamination through targeted removal rates based on soil type and residue type/fraction is allowing the use of new high efficiency harvesting equipment and methods. As another consideration, single pass harvesting and other technologies that improve harvesting costs cause biomass storage moisture management challenges, which challenges are further perturbed by annual variability in biomass moisture content. Monitoring, sampling, simulation, and analysis provide basis for moisture, time, and quality relationships in storage, which has allowed the development of moisture tolerant storage systems and best management processes that combine moisture content and time to accommodate baled storage of wet material based upon “shelf-life.” The key to improving biomass supply logistics costs has been developing the associated agronomic sustainability and biomass quality technologies and processes that allow the implementation of equipment engineering solutions.

  11. A cost analysis of microalgal biomass and biodiesel production in open raceways treating municipal wastewater and under optimum light wavelength.

    PubMed

    Kang, Zion; Kim, Byung-Hyuk; Ramanan, Rishiram; Choi, Jong-Eun; Yang, Ji-Won; Oh, Hee-Mock; Kim, Hee-Sik

    2015-01-01

    Open raceway ponds are cost-efficient for mass cultivation of microalgae compared with photobioreactors. Although low-cost options like wastewater as nutrient source is studied to overcome the commercialization threshold for biodiesel production from microalgae, a cost analysis on the use of wastewater and other incremental increases in productivity has not been elucidated. We determined the effect of using wastewater and wavelength filters on microalgal productivity. Experimental results were then fitted into a model, and cost analysis was performed in comparison with control raceways. Three different microalgal strains, Chlorella vulgaris AG10032, Chlorella sp. JK2, and Scenedesmus sp. JK10, were tested for nutrient removal under different light wavelengths (blue, green, red, and white) using filters in batch cultivation. Blue wavelength showed an average of 27% higher nutrient removal and at least 42% higher chemical oxygen demand removal compared with white light. Naturally, the specific growth rate of microalgae cultivated under blue wavelength was on average 10.8% higher than white wavelength. Similarly, lipid productivity was highest in blue wavelength, at least 46.8% higher than white wavelength, whereas FAME composition revealed a mild increase in oleic and palmitic acid levels. Cost analysis reveals that raceways treating wastewater and using monochromatic wavelength would decrease costs from 2.71 to 0.73 $/kg biomass. We prove that increasing both biomass and lipid productivity is possible through cost-effective approaches, thereby accelerating the commercialization of low-value products from microalgae, like biodiesel. PMID:25341470

  12. Implications of nutrient removal and biomass production by native and augmented algal populations at a municipal wastewater treatment plant.

    PubMed

    Drexler, Ivy L C; Bekaan, Sascha; Eskandari, Yasmin; Yeh, Daniel H

    2014-01-01

    Algal monocultures (Chlorella sorokiniana and Botryococcus braunii) and algal communities native to clarifiers of a wastewater treatment plant were batch cultivated in (1) clarified effluent following a biochemical oxygen demand (BOD) removal reactor post-BOD removal clarified effluent (PBCE), (2) clarified effluent following a nitrification reactor post-nitrification clarified effluent (PNCE), and (3) a reference media (RM). After 12 days, all algal species achieved nitrogen removal between 68 and 82% in PBCE and 37 and 99% in PNCE, and phosphorus removal between 91 and 100% in PBCE and 60 and 100% in PNCE. The pH of the wastewater samples increased above 9.8 after cultivation of each species, which likely aided ammonia volatilization and phosphorus adsorption. Both monocultures grew readily with wastewater as a feedstock, but B. braunii experienced significant crowding from endemic fauna. In most cases, native algal species' nutrient removal efficiency was competitive with augmented algal monocultures, and in some cases achieved a higher biomass yield, demonstrating the potential to utilize native species for nutrient polishing and algal biomass production. PMID:25325538

  13. Pilot-scale anaerobic co-digestion of municipal biomass waste and waste activated sludge in China: Effect of organic loading rate

    SciTech Connect

    Liu Xiao; Wang Wei; Shi Yunchun; Zheng Lei; Gao Xingbao; Qiao Wei; Zhou Yingjun

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer Co-digestion of municipal biomass waste (MBW) and waste activated sludge (WAS) was examined on a pilot-scale reactor. Black-Right-Pointing-Pointer System performance and stability under OLR of 1.2, 2.4, 3.6, 4.8, 6.0 and 8.0 kg VS (m{sup 3} d){sup -1} were analyzed. Black-Right-Pointing-Pointer A maximum methane production rate of 2.94 m{sup 3} (m{sup 3} d){sup -1} was achieved at OLR of 8.0 kg VS (m{sup 3} d){sup -1} and HRT of 15d. Black-Right-Pointing-Pointer With the increasing OLRs, pH values, VS removal rate and methane concentration decreased and VFA increased. Black-Right-Pointing-Pointer The changing of biogas production rate can be a practical approach to monitor and control anaerobic digestion system. - Abstract: The effects of organic loading rate on the performance and stability of anaerobic co-digestion of municipal biomass waste (MBW) and waste activated sludge (WAS) were investigated on a pilot-scale reactor. The results showed that stable operation was achieved with organic loading rates (OLR) of 1.2-8.0 kg volatile solid (VS) (m{sup 3} d){sup -1}, with VS reduction rates of 61.7-69.9%, and volumetric biogas production of 0.89-5.28 m{sup 3} (m{sup 3} d){sup -1}. A maximum methane production rate of 2.94 m{sup 3} (m{sup 3} d){sup -1} was achieved at OLR of 8.0 kg VS (m{sup 3} d){sup -1} and hydraulic retention time of 15 days. With increasing OLRs, the anaerobic reactor showed a decrease in VS removal rate, average pH value and methane concentration, and a increase of volatile fatty acid concentration. By monitoring the biogas production rate (BPR), the anaerobic digestion system has a higher acidification risk under an OLR of 8.0 kg VS (m{sup 3} d){sup -1}. This result remarks the possibility of relating bioreactor performance with BPR in order to better understand and monitor anaerobic digestion process.

  14. CONCERNS WITH THE BENEFICIAL REUSE IN AGRICULTURE OF RESIDUALS FROM MUNICIPAL WASTEWATER TREATMENT AND ANIMAL FEEDING OPERATIONS

    EPA Science Inventory

    The pathogenic organisms that may be present in such residuals, processes commonly employed for controlling them; these processes' effectiveness and how extensively they are used; and issues and concerns with beneficial reuse will be discussed. Processes presently being researche...

  15. Improved energy recovery from municipal solid wastes in sanitary landfills by two-phase digestion of biomass

    SciTech Connect

    Onu, Chukwu.

    1990-01-01

    The concept under investigaton was the separation of the acidogenic and the methanogenic phases of anaerobic fermentation, converting the sanitary landfill into an acid reactor and using a separate upflow fixed-film anaerobic reactor for methanogenesis. Acidic leachate from the landfill simulator was used as the influent substrate to the anaerobic reactor. The goal of the study was to improve both methane yield and concentration through nutrient addition and two-phase digestion of MSW. Sewage sludge was utilized to provide moisture, buffering capacity, nutrients, and an adequate microbial population. Single-phase systems with other enhancement techniques were also compared to the two-phase with sludge addition. Data from this study indicated that gas produced in the anaerobic reactor had methane concentration as high as 80 Mole % at the fixed-bed reactor (FBR) hydraulic retention time (HRT) of 7 days. The system reached a cumulative methane production rate of 78.6 {ell}/kg dry waste at an estimated cumulative production rate of approximately 270 {ell}/kg/yr. This performance was better than that reported in the literature for a similar type of feed. This study has also indicated that sewage sludge addition appears to be a successful enhancement technique for methane gas production from municipal solid waste. The addition of mineral nutrients and buffer solutions appears to have influenced the development of a dominant population of methanogenic bacteria in the FBR as indicated by the COD removal efficiency of 90% and 100% conversion of all influent organic acids. In terms of the overall system performance, the two-phase system was superior to the one-phase technique currently in use for methane generation.

  16. Activated carbons from waste biomass: an alternative use for biodiesel production solid residues.

    PubMed

    Nunes, Anne A; Franca, Adriana S; Oliveira, Leandro S

    2009-03-01

    Defective coffee press cake, a residue from coffee oil biodiesel production, was evaluated as raw material for production of an adsorbent for removal of methylene blue (MB) from aqueous solution. Batch adsorption tests were performed at 25 degrees C and the effects of particle size, contact time, adsorbent dosage and pH were investigated. Preliminary adsorption tests indicated that thermal treatment is necessary in order to improve adsorption capacity. Adsorption kinetics was determined by fitting first and second-order kinetic models to the experimental data, with the second-order model providing the best description of MB adsorption onto the prepared adsorbent. The experimental adsorption equilibrium data were fitted to Langmuir, Freundlich and Temkin adsorption models, with the last two providing the best fits. The experimental data obtained in the present study indicated that this type of waste material is a suitable candidate for use in the production of adsorbents for removal of cationic dyes, thus contributing for the implementation of sustainable development in both the coffee and biodiesel production chains. PMID:18996006

  17. Thermogravimetric kinetic study of agricultural residue biomass pyrolysis based on combined kinetics.

    PubMed

    Wang, Xun; Hu, Mian; Hu, Wanyong; Chen, Zhihua; Liu, Shiming; Hu, Zhiquan; Xiao, Bo

    2016-11-01

    Pyrolytic kinetic of an agricultural residue (AR) feedstock, a mixture of plants (cotton, wheat, rich, corn) stems, was investigated based on combined kinetics. The most suitable mechanism for AR one-step pyrolysis was f(α)=(1-α)(1.1816)α(-1.8428) with kinetic parameters of: apparent activation energy 221.7kJ/mol, pre-exponential factor 4.17E16s(-1). Pyrolysis of AR feedstock could not be described by one-step reaction attributes to heterogeneous features of pyrolysis processes. Combined kinetics three-parallel-reaction (CK-TPR) model fitted the pyrolysis experimental data very well. Reaction mechanisms for pseudo hemicelluloses, cellulose, lignin in CK-TPR model was f(α)=(1-α)(1.6244)α(-0.3371)[-ln(1-α)](-0.0515), f(α)=(1-α)(1.0597)α(-0.6909)[-ln(1-α)](0.9026) and f(α)=(1-α)(2.9577)α(-4.7719), respectively. Apparent activation energy of three pseudo components followed the order of Elignin(197.3kJ/mol)>Ecellulose(176.3kJ/mol)>Ehemicelluloses (151.1kJ/mol). Mechanism of hemicelluloses pyrolysis could be further expressed as f(α)=(1-α)(1.4). The pyrolytic mechanism of cellulose met the Nucleation well. However, mechanism of lignin pyrolysis was complex, which possibly was the combined effects of Nucleation, Diffusion, Geometrical contraction, and Power law. PMID:27521788

  18. Biomass thermochemical conversion program. 1985 annual report

    SciTech Connect

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1986-01-01

    Wood and crop residues constitute a vast majority of the biomass feedstocks available for conversion, and thermochemical processes are well suited for conversion of these materials. The US Department of Energy (DOE) is sponsoring research on this conversion technology for renewable energy through its Biomass Thermochemical Conversion Program. The Program is part of DOE's Biofuels and Municipal Waste Technology Division, Office of Renewable Technologies. This report briefly describes the Thermochemical Conversion Program structure and summarizes the activities and major accomplishments during fiscal year 1985. 32 figs., 4 tabs.

  19. The Development of a Curriculum for Renewable Energy: A Case Study of Charcoal Briquettes from Agricultural Residues for Environmental Literacy of Secondary School Students at Samaki Wittaya Municipality School

    ERIC Educational Resources Information Center

    Klakayan, Jagree; Singseewo, Adisak

    2016-01-01

    This research aimed to (1) design a curriculum on Production of Charcoal Briquettes from Agricultural Residues, (2) implement the designed curriculum, and (3) study and compare the learning achievements of Matthayomsuksa 3 students at Samakee Wittaya Municipality School in terms of knowledge, learning skills, and participation in the production of…

  20. COMPARISON OF FIVE SOLIDIFICATION/STABILIZATION PROCESSES FOR TREATMENT OF MUNICIPAL WASTE COMBUSTION RESIDUES - PART I - PHYSICAL TESTING

    EPA Science Inventory

    This paper presents results from physical tests used to evaluate MWC residues treated by five S/S processes. he physical properties are especially important for determining utilization applications. onsiderable emphasis was placed on structural properties and long-term durability...

  1. Activated carbon derived from carbon residue from biomass gasification and its application for dye adsorption: Kinetics, isotherms and thermodynamic studies.

    PubMed

    Maneerung, Thawatchai; Liew, Johan; Dai, Yanjun; Kawi, Sibudjing; Chong, Clive; Wang, Chi-Hwa

    2016-01-01

    In this work, activated carbon (AC) as an effective and low-cost adsorbent was successfully prepared from carbon residue (or char, one of the by-products from woody biomass gasification) via physical activation. The surface area of char was significantly increased from 172.24 to 776.46m(2)/g after steam activation at 900°C. The obtained activated carbons were then employed for the adsorption of dye (Rhodamine B) and it was found that activated carbon obtained from steam activation exhibited the highest adsorption capability, which is mainly attributed to the higher surface area and the abundance of hydroxyl (-OH) and carboxyl (-COOH) groups on the activated carbon surface. Moreover, it was also found that the adsorption capability significantly increased under the basic condition, which can be attributed to the increased electrostatic interaction between the deprotonated (negatively charged) activated carbon and dye molecules. Furthermore, the equilibrium data were fitted into different adsorption isotherms and found to fit well with Langmuir model (indicating that dye molecules form monolayer coverage on activated carbon) with a maximum monolayer adsorption capability of 189.83mg/g, whereas the adsorption kinetics followed the pseudo-second-order kinetics. PMID:26512858

  2. Design and scale-up of a heavy-metals recovery process from municipal-solid-waste-incinerator residues

    SciTech Connect

    Legiec, I.A.

    1991-01-01

    Bottom ash, fly ash or fly ash and scrubber residue, and combined ash was obtained from three facilities and characterized for chemical composition and buffering capacities. Equilibrium extractions utilizing an acidic, inorganic salt solution investigated the leaching dependency on pH and provided insight to the structure of the ash. Sequential batch extractions were carried out to increase metallic and salt species concentrations by adding ash to recycled extract and to observe the solubility limitations and interaction of these species upon full recycle of an extract stream. A model was derived for the lead extraction dependency on equilibrium pH for three fly ash residuals. The extraction patterns were compared to the solubilization and chloride complexation of several complex lead minerals. The empirical rate of neutralization was also determined. Bottom and combined ash studies were carried out to evaluate separation and subsequent treatment processes. Another alternative process, soluble salts recovery from fly ash or fly ash and scrubber residue, also was investigated. A continuous laboratory scale pilot plant was designed and operated to treat ashes at a rate of 1 kilogram/hour. The pilot plant was operated in a single pass mode and the residence time distribution of the reactor was evaluated. A secondary investigation observed the effect of recycle streams on the extraction efficiency. Three conceptual processes were designed for heavy metals recovery from combustion residuals, separation and subsequent treatment of bottom or combined ash, and the soluble salts recovery from fly ash or fly ash scrubber residuals at the pilot scale of 20 tons per day. The primary economic analysis of all three processes are presented.

  3. [Effects of Different Residue Part Inputs of Corn Straws on CO2 Efflux and Microbial Biomass in Clay Loam and Sandy Loam Black Soils].

    PubMed

    Liu, Si-yi; Liang, Ai-zhen; Yang, Xue-ming; Zhang, Xiao-ping; Jia, Shu-xia; Chen, Xue-wen; Zhang, Shi-xiu; Sun, Bing-jie; Chen, Sheng-long

    2015-07-01

    The decomposed rate of crop residues is a major determinant for carbon balance and nutrient cycling in agroecosystem. In this study, a constant temperature incubation study was conducted to evaluate CO2 emission and microbial biomass based on four different parts of corn straw (roots, lower stem, upper stem and leaves) and two soils with different textures (sandy loam and clay loam) from the black soil region. The relationships between soil CO2 emission, microbial biomass and the ratio of carbon (C) to nitrogen (N) and lignin of corn residues were analyzed by the linear regression. Results showed that the production of CO2 was increased with the addition of different parts of corn straw to soil, with the value of priming effect (PE) ranged from 215. 53 µmol . g-1 to 335. 17 µmol . g -1. Except for corn leaves, the cumulative CO2 production and PE of clay loam soil were significantly higher than those in sandy loam soil. The correlation of PE with lignin/N was obviously more significant than that with lignin concentration, nitrogen concentration and C/N of corn residue. The addition of corn straw to soil increased the contents of MBC and MBN and decreased MBC/MBN, which suggested that more nitrogen rather than carbon was conserved in microbial community. The augmenter of microbial biomass in sandy loam soil was greater than that in clay loam soil, but the total dissolved nitrogen was lower. Our results indicated that the differences in CO2 emission with the addition of residues to soils were primarily ascribe to the different lignin/N ratio in different corn parts; and the corn residues added into the sandy loam soil could enhance carbon sequestration, microbial biomass and nitrogen holding ability relative to clay loam soil. PMID:26489342

  4. Leaching behaviour of elements and evaluation of pre-treatment methods for municipal solid waste incinerator residues in column leaching tests.

    PubMed

    Kim, Sang-Yul; Tanaka, Nobutoshi; Matsuto, Toshihiko; Tojo, Yasumasa

    2005-06-01

    Two new pre-treatment methods (water-washing/carbonation and carbonation/phosphate stabilization) of municipal solid waste (MSW) incinerator residues were evaluated by column leaching tests under aerobic conditions and anaerobic conditions (which were changed to aerobic conditions after 10 months). A mixture of bottom ash and fly ash (5:1 ratio) was pre-treated using each method. Shredded incombustible residues (SIR) were added to each ash preparation in proportions similar to the ratios present in landfills. For comparison, landfill wastes typical of Japan, namely, a mixture of bottom ash, chelating-pre-treated fly ash, and SIR, were also examined. Leachate samples were collected periodically and analysed over a 15-month period. When compared with chelating pretreatment, both water-washing/carbonation and carbonation/ phosphate stabilization reduced the leaching of Pb, Al, and Cu by about one to two orders of magnitude. Moreover, the initial concentrations of Ca and Pb in leachates from column of water-washing/carbonation were 56-57% and 84-96% less than those from the column of carbonation/phosphate stabilization. Therefore, water-washing/carbonation was considered to be a promising approach to obtain early waste stabilization and to reduce the release of heavy metals to near-negligible levels. The leaching behaviour of elements was also discussed. PMID:15988941

  5. Preliminary investigation on the production of fuels and bio-char from Chlamydomonas reinhardtii biomass residue after bio-hydrogen production.

    PubMed

    Torri, Cristian; Samorì, Chiara; Adamiano, Alessio; Fabbri, Daniele; Faraloni, Cecilia; Torzillo, Giuseppe

    2011-09-01

    The aim of this work was to investigate the potential conversion of Chlamydomonas reinhardtii biomass harvested after hydrogen production. The spent algal biomass was converted into nitrogen-rich bio-char, biodiesel and pyrolysis oil (bio-oil). The yield of lipids (algal oil), obtained by solvent extraction, was 15 ± 2% w/w(dry-biomass). This oil was converted into biodiesel with a 8.7 ± 1% w/w(dry-biomass) yield. The extraction residue was pyrolysed in a fixed bed reactor at 350 °C obtaining bio-char as the principal fraction (44 ± 1% w/w(dry-biomass)) and 28 ± 2% w/w(dry-biomass) of bio-oil. Pyrolysis fractions were characterized by elemental analysis, while the chemical composition of bio-oil was fully characterized by GC-MS, using various derivatization techniques. Energy outputs resulting from this approach were distributed in hydrogen (40%), biodiesel (12%) and pyrolysis fractions (48%), whereas bio-char was the largest fraction in terms of mass. PMID:21345670

  6. Energy Efficiency of Biogas Produced from Different Biomass Sources

    NASA Astrophysics Data System (ADS)

    Begum, Shahida; Nazri, A. H.

    2013-06-01

    Malaysia has different sources of biomass like palm oil waste, agricultural waste, cow dung, sewage waste and landfill sites, which can be used to produce biogas and as a source of energy. Depending on the type of biomass, the biogas produced can have different calorific value. At the same time the energy, being used to produce biogas is dependent on transportation distance, means of transportation, conversion techniques and for handling of raw materials and digested residues. An energy systems analysis approach based on literature is applied to calculate the energy efficiency of biogas produced from biomass. Basically, the methodology is comprised of collecting data, proposing locations and estimating the energy input needed to produce biogas and output obtained from the generated biogas. The study showed that palm oil and municipal solid waste is two potential sources of biomass. The energy efficiency of biogas produced from palm oil residues and municipal solid wastes is 1.70 and 3.33 respectively. Municipal solid wastes have the higher energy efficiency due to less transportation distance and electricity consumption. Despite the inherent uncertainties in the calculations, it can be concluded that the energy potential to use biomass for biogas production is a promising alternative.

  7. Biomass resources for electric generation in the Pacific Northwest

    SciTech Connect

    Kerstetter, J.D.

    1995-11-01

    Biomass fuels offer a unique energy resource for electric generation in the Pacific Northwest. They are produced as a coproduct from our needs for food, fiber, and structural materials. Many of the fuels are considered as waste products from the major manufacturing process and are available for the cost of transportation. About 1,055 PJ (1,000 TBtu) of biomass residues are generated each year in the Pacific Northwest. Traditional sources of biomass fuels include forest residues, wood manufacturing residues, agricultural field residues, and municipal solid waste (MSW). Woody residues have a long history of being used for electric generation, especially from cogeneration facilities located at pulp mills. MSW facilities were built in the 1980s but interest has declined with the availability of large regional landfills. Forest residues and agricultural field residues are not used in the region but are used in increasing amounts for electric generation in California. Other biomass resources include spent pulping liquors, biogas from animal manure and landfills, and residues from fiber plantations. A major question addressed in this paper is the future availability and cost of biomass fuels. Biomass fuels offer several environmental advantages. With the exception of MSW they are inherently clean burning. Their low sulfur and nitrogen content permits burning without the need for acid gas scrubbers. Their carbon dioxide emissions on an energy basis are comparable to coal but there is one important difference. The biological growth of biomass fuels consumes carbon dioxide as part of the photosynthetic process and thus their net contribution to global warming is zero. The utility industry has increased its interest in biomass fuels because of the carbon dioxide advantages.

  8. From municipal sewage to drinking water: fate and removal of pharmaceutical residues in the aquatic environment in urban areas.

    PubMed

    Heberer, Th; Reddersen, K; Mechlinski, A

    2002-01-01

    Recently, the occurrence and fate of pharmaceutically active compounds (PhACs) in the aquatic environment was recognized as one of the emerging issues in environmental chemistry and as a matter of public concern. Residues of PhACs have been found as contaminants in sewage, surface, and ground- and drinking water samples. Since June 2000, a new long-term monitoring program of sewage, surface, ground- and drinking water has been carried out in Berlin, Germany. Samples, collected periodically from selected sites in the Berlin area, are investigated for residues of PhACs and related contaminants. The purpose of this monitoring is to investigate these compounds over a long time period to get more reliable data on their occurrence and fate in the different aquatic compartments. Moreover, the surface water investigations allow the calculation of season-dependent contaminant loads in the Berlin waters. In the course of the monitoring program, PhACs and some other polar compounds were detected at concentrations up to the microg/L-level in all compartments of the Berlin water cycle. The monitoring is accompanied and supported by several other investigations such as laboratory column experiments and studies on bank filtration and drinking water treatment using conventional or membrane filtration techniques. PMID:12227607

  9. Impact of liming and drying municipal sewage sludge on the amount and availability of (14)C-acetyl sulfamethoxazole and (14)C-acetaminophen residues.

    PubMed

    Geng, Chunnu; Bergheaud, Valérie; Garnier, Patricia; Zhu, Yong-Guan; Haudin, Claire-Sophie

    2016-01-01

    Acetyl Sulfamethoxazole (AC-SMX) and acetaminophen (ACM) can be found in municipal sewage sludge, and their content and availability may be influenced by sludge treatments, such as drying and liming. A sludge similarly centrifuged with/without a flocculant was spiked with (14)C-labelled AC-SMX or ACM. Then, it was either limed (20% CaO) or/and dried under different laboratory conditions (1 week at ambient temperature; and 48 h at 40 or 80 °C). The total amount and distribution of the (14)C-compounds among several chemical fractions, based on the sludge floc definition, were assessed at the end of the treatments. All the (14)C-activity brought initially was recovered in the limed and/or dried sludges for AC-SMX but only between 44.4 and 84.9% for ACM, with the highest rate obtained for the limed sludge. Drying at 80 °C or liming increased the percentage of the sludge total organic carbon recovered in the extracts containing soluble extracellular polymeric substances (S-EPS) and the percentage of the total (14)C-activity extracted simultaneously. The non-extractable residues represented only 3.9-11.6% of the total (14)C-activity measured in the treated sludges for AC-SMX and 16.9-21.8% for ACM. The presence of AC-SMX and ACM residues in the treated sludges, after liming and drying under different conditions, was shown using some (14)C-labelled molecules. At this time scale and according to the extraction method selected, most of the (14)C-residues remained soluble and easily extractable for both compounds. This result implies that certain precautions should be taken when storing sludges before being spread on the field. Sludge piles, particularly the limed sludge, should be protected from rain to limit the production of lixiviates, which may contain residues of AC-SMX and ACM. PMID:26492342

  10. Stability, nutrient availability and hydrophobicity of biochars derived from manure, crop residues, and municipal solid waste for their use as soil amendments.

    PubMed

    Zornoza, R; Moreno-Barriga, F; Acosta, J A; Muñoz, M A; Faz, A

    2016-02-01

    We aimed to study the influence of feedstock properties, pyrolysis temperature and holding time on stability, nutrient contents and hydrophobicity of biochars derived from pig manure, crop residues and municipal solid waste. Biochars were prepared at 300 °C, 400 °C, 500 °C and 700 °C for 1 h, 2 h, 4 h and 5 h. All properties were influenced by feedstock except for pH and hydrophobicity. Temperature influenced all properties, whereas no effect of holding time was observed except for hydrophobicity and thermal stability. Increasing temperature increased aromatization and stability. Low temperatures provided higher cation exchange capacity and available nutrients, and lower salinity and alkalinity. Precipitation of phosphates and carbonates occurred with charring, explaining the decrease of available nutrients. Biochars produced at 300 °C showed high hydrophobity, which disappeared over 500 °C owing to the loss of labile aliphatic compounds. The high pH and carbonates contents at >500 °C resulted in suitable biochars for soil liming and decreasing soil metals availability. PMID:26347934

  11. Chemical and physical properties of cyclone fly ash from the grate-fired boiler incinerating forest residues at a small municipal district heating plant (6MW).

    PubMed

    Pöykiö, R; Rönkkömäki, H; Nurmesniemi, H; Perämäki, P; Popov, K; Välimäki, I; Tuomi, T

    2009-03-15

    In Finland, the new limit values for maximal allowable heavy metal concentrations for materials used as an earth construction agent came into force in July 2006. These limit values are applied if ash is utilized, e.g. in roads, cycling paths, pavements, car parks, sport fields, etc. In this study we have determined the most important chemical and physical properties of the cyclone fly ash originating from the grate-fired boiler incinerating forest residues (i.e. wood chips, sawdust and bark) at a small municipal district heating plant (6 MW), Northern Finland. This study clearly shows that elements are enriched in cyclone fly ash, since the total element concentrations in the cyclone fly ash were within 0.2-10 times higher than those in the bottom ash. The total concentrations of Cd (25 mg kg(-1); d.w.), Zn (3630 mg kg(-1); d.w.), Ba (4260 mg kg(-1); d.w.) and Hg (1.7 mg kg(-1); d.w.) exceeded the limit values, and therefore the cyclone fly ash cannot be used as an earth construction agent. According to the leached amounts of Cr (38 mg kg(-1); d.w.), Zn (51 mg kg(-1); d.w.) and sulphate (50,000 mg kg(-1); d.w.), the cyclone fly ash is classified as a hazardous waste, and it has to be deposited in a hazardous waste landfill. PMID:18603362

  12. Development Potentials and Policy Options of Biomass in China

    NASA Astrophysics Data System (ADS)

    Shen, Lei; Liu, Litao; Yao, Zhijun; Liu, Gang; Lucas, Mario

    2010-10-01

    Biomass, one of the most important renewable energies, is playing and will continue to play an important role in the future energy structure of the world. This article aims to analyze the position and role, assess the resource availability, discuss the geographic distribution, market scale and industry development, and present the policy options of biomass in China. The resource availability and geographical distribution of biomass byproducts are assessed in terms of crop residues, manure, forest and wood biomass byproducts, municipal waste and wastewater. The position of biomass use for power generation is just next to hydropower among types of renewable energy in China. The potential quantity of all biomass byproducts energy in 2004 is 3511 Mtce (Mtce is the abbreviation of million tons of coal equivalents and 1 Mtce is equal to106 tce.), while the acquirable quantity is 460 Mtce. Biomass energy plays a critical role in rural regions of China. The geographical distribution and quantity of biomass byproducts resources depends mainly on the relationship between ecological zones and climate conditions. Our estimation shows that the total quantity of crop residues, manure, forest and wood biomass byproducts, municipal waste and wastewater resources are 728, 3926, 2175, 155 and 48240 Mt (million tons), respectively. Crop residues come mainly from the provinces of Henan, Shandong, Heilongjiang, Jilin and Sichuan. All manure is mainly located in the provinces of Henan, Shandong, Sichuan, Hebei and Hunan. Forest and wood biomass byproducts are mainly produced in the provinces or autonomous regions of Tibet, Sichuan, Yunnan, Heilongjiang and Inner Mongolia, while most of municipal waste mainly comes from Guangdong, Shandong, Heilongjiang, Hubei and Jiangsu. Most of wastewater is largely discharged from advanced provinces like Guangdong, Jiangsu, Zhejiang, Shandong and Henan. Biomass byproducts’ energy distribution also varies from province to province in China. Based on

  13. Extraction of squalene as value-added product from the residual biomass of Schizochytrium mangrovei PQ6 during biodiesel producing process.

    PubMed

    Hoang, Minh Hien; Ha, Nguyen Cam; Thom, Le Thi; Tam, Luu Thi; Anh, Hoang Thi Lan; Thu, Ngo Thi Hoai; Hong, Dang Diem

    2014-12-01

    Today microalgae represent a viable alternative source of squalene for commercial application. The species Schizochytrium mangrovei, a heterotrophic microalga, has been widely studied and provides a high amount of squalene, polyunsaturated fatty acids and has good profiles for biodiesel production. Our work was aimed at examining the squalene contents in Vietnam's heterotrophic marine microalga S. mangrovei PQ6 biomass and residues of the biodiesel process from this strain. Thin-layer chromatography and high-performance liquid chromatography (HPLC) methods were successfully applied to the determination of squalene in S. mangrovei PQ6. The squalene content and production of S. mangrovei PQ6 reached 33.00 ± 0.02 and 33.04 ± 0.03 mg g(-1) of dry cell weight; and 0.992 g L(-1) and 1.019 g L(-1) in 30 and 150 L bioreactors, respectively after 96 h of fermentation. In addition, squalene was also detected in spent biomass (approximately 80.10 ± 0.03 mg g(-1) of spent biomass) from the S. mangrovei PQ6 biodiesel production process. The structure of squalene in residues of the biodiesel process was confirmed from its nuclear magnetic resonance spectra. The results obtained from our work suggest that there is tremendous potential in the exploitation of squalene as a value-added by-product besides biodiesel from S. mangrovei PQ6 to reduce biodiesel price. PMID:24973317

  14. COFIRING BIOMASS WITH LIGNITE COAL

    SciTech Connect

    Darren D. Schmidt

    2002-01-01

    The University of North Dakota Energy & Environmental Research Center, in support of the U.S. Department of Energy's (DOE) biomass cofiring program, completed a Phase 1 feasibility study investigating aspects of cofiring lignite coal with biomass relative to utility-scale systems, specifically focusing on a small stoker system located at the North Dakota State Penitentiary (NDSP) in Bismarck, North Dakota. A complete biomass resource assessment was completed, the stoker was redesigned to accept biomass, fuel characterization and fireside modeling tests were performed, and an engineering economic analysis was completed. In general, municipal wood residue was found to be the most viable fuel choice, and the modeling showed that fireside problems would be minimal. Experimental ash deposits from firing 50% biomass were found to be weaker and more friable compared to baseline lignite coal. Experimental sulfur and NO{sub x} emissions were reduced by up to 46%. The direct costs savings to NDSP, from cogeneration and fuel saving, results in a 15- to 20-year payback on a $1,680,000 investment, while the total benefits to the greater community would include reduced landfill burden, alleviation of fees for disposal by local businesses, and additional jobs created both for the stoker system as well as from the savings spread throughout the community.

  15. Characterization of fine and carbonaceous particles emissions from pelletized biomass-coal blends combustion: Implications on residential crop residue utilization in China

    NASA Astrophysics Data System (ADS)

    Xu, Yue; Wang, Yan; Chen, Yingjun; Tian, Chongguo; Feng, Yanli; Li, Jun; Zhang, Gan

    2016-09-01

    Bulk biofuel, biomass pellets and pelletized biomass-coal blends were combusted in a typical rural conventional household stove and a high-efficiency stove. Reductions in PM2.5, organic carbon (OC) and elemental carbon (EC) emissions were evaluated by comparing emission factors (EFs) among 19 combinations of biofuel/residential stove types measured using a dilution sampling system. In the low-efficiency stove, the average EFs of PM2.5, OC, and EC of biomass pellets were 2.64 ± 1.56, 0.42 ± 0.36, and 0.30 ± 0.11 g/kg, respectively, significantly lower than those burned in bulk form. EFPM2.5 and EFOC of pelletized biomass combustion in the high-efficiency stove were lower than those of the same biofuel burned in the low-efficiency stove. Furthermore, pelletized corn residue and coal blends burned in the high-efficiency stove could significantly decrease emissions. Compared with the bulk material burned in the low-efficiency stove, the reduction rates of PM2.5, OC and EC from pelletized blends in the high-efficiency stove can reach 84%, 96% and 93%, respectively. If the annually produced corn residues in 2010 had been blended with 10% anthracite coal powder and burnt as pellets, it would have reduced about 82% of PM2.5, 90-96% of OC and 81-92% of EC emission in comparison with burning raw materials in conventional household stoves. Given the low cost, high health benefit and reduction effect on atmospheric pollutants, pelletized blends could be a promising alternative to fossil fuel resources or traditional bulk biofuel.

  16. SERI biomass program annual technical report: 1982

    SciTech Connect

    Bergeron, P.W.; Corder, R.E.; Hill, A.M.; Lindsey, H.; Lowenstein, M.Z.

    1983-02-01

    The biomass with which this report is concerned includes aquatic plants, which can be converted into liquid fuels and chemicals; organic wastes (crop residues as well as animal and municipal wastes), from which biogas can be produced via anerobic digestion; and organic or inorganic waste streams, from which hydrogen can be produced by photobiological processes. The Biomass Program Office supports research in three areas which, although distinct, all use living organisms to create the desired products. The Aquatic Species Program (ASP) supports research on organisms that are themselves processed into the final products, while the Anaerobic Digestion (ADP) and Photo/Biological Hydrogen Program (P/BHP) deals with organisms that transform waste streams into energy products. The P/BHP is also investigating systems using water as a feedstock and cell-free systems which do not utilize living organisms. This report summarizes the progress and research accomplishments of the SERI Biomass Program during FY 1982.

  17. Ethanol from biomass: A status report

    SciTech Connect

    Walker, R.

    1996-12-31

    Programmatic and technical activities of SWAN Biomass, a company formed by Amoco Corporation and Stone & Webster, to convert non-grain biomass material to ethanol, are highlighted in this presentation. The potential ethanol markets identified are: (1) fuel oxygenate and octane additive, and (2) waste reduction in the agricultural and forestry industries and in municipal waste streams. Differences in the SWAN process from that used in corn-based ethanol facilities include more intense pretreatment of lignocellulosic biomass, different enzymes, hydrolysis and fermentation of sugar polymers is performed in the same vessel, and a typical solid residue of lignin. The major market and technical risks have been assessed as being manageable. 8 figs., 8 tabs.

  18. Effects of soil tillage and management of crop residues on soil properties: abundance, biomass and diversity of earthworms, soil structure and nutrient evolutions

    NASA Astrophysics Data System (ADS)

    lemtiri, Aboulkacem

    2013-04-01

    The living soil is represented by soil biota that interacts with aboveground biota and with the abiotic environment, soil structure, soil reaction, organic matter, nutrient contents, aso. Maintenance of soil organic matter through integrated soil fertility management is an important issue to conciliate soil quality and agricultural productivity. Earthworms are key actors in soil structure formation through the production of casts and the incorporation of soil organic matter in the soil. Research is still needed about the interactive effects of various tillage and crop residue management practices on earthworm populations and physical and chemical properties of soil. To investigate the impacts of two tillage management systems and two cropping systems on earthworm populations, soil structure evolution and nutrient dynamics, we carried out a three years study in an experimental field. The aims of this experimentation, were to assess the effects of the tillage systems (ploughing versus reduced tillage) and the availability of crop residues (export versus no export) on (i) the abundance, biomass and diversity of earthworms, on the soil structure and on the temporal variation of water extractable nutrients and organic carbon. The first results show that tillage management did significantly affect earthworm abundance and biomass. However, crop residue management did not affect abundance, biomass and diversity of earthworms. Regarding soil physical properties, the tillage affected the compaction profiles within the top 30cm. The analysis of nutrient and organic carbon dynamics show divergent trends (decrease of calcium and magnesium, increase of hot water extractable carbon and phosphorus…) but no clear effect of the studied factors could be identified. The question of the initial soil variability raised as a crucial point in the discussion.

  19. Energy from Biomass.

    ERIC Educational Resources Information Center

    Carioca, J. O. B.; And Others

    1987-01-01

    Discusses how biomass in the form of fuelwood, crop residues, and animal dung can be converted into fuels such as biogas and ethanol to replace or supplement fossil fuels. Argues for future decentralized, integrated biomass energy development. (TW)

  20. Polyhydroxyalkanoate (PHA) production from sludge and municipal wastewater treatment.

    PubMed

    Morgan-Sagastume, F; Valentino, F; Hjort, M; Cirne, D; Karabegovic, L; Gerardin, F; Johansson, P; Karlsson, A; Magnusson, P; Alexandersson, T; Bengtsson, S; Majone, M; Werker, A

    2014-01-01

    Polyhydroxyalkanoates (PHAs) are biodegradable polyesters with comparable properties to some petroleum-based polyolefins. PHA production can be achieved in open, mixed microbial cultures and thereby coupled to wastewater and solid residual treatment. In this context, waste organic matter is utilised as a carbon source in activated sludge biological treatment for biopolymer synthesis. Within the EU project Routes, the feasibility of PHA production has been evaluated in processes for sludge treatment and volatile fatty acid (VFA) production and municipal wastewater treatment. This PHA production process is being investigated in four units: (i) wastewater treatment with enrichment and production of a functional biomass sustaining PHA storage capacity, (ii) acidogenic fermentation of sludge for VFA production, (iii) PHA accumulation from VFA-rich streams, and (iv) PHA recovery and characterisation. Laboratory- and pilot-scale studies demonstrated the feasibility of municipal wastewater and solid waste treatment alongside production of PHA-rich biomass. The PHA storage capacity of biomass selected under feast-famine with municipal wastewater has been increased up to 34% (g PHA g VSS(-1)) in batch accumulations with acetate during 20 h. VFAs obtained from waste activated sludge fermentation were found to be a suitable feedstock for PHA production. PMID:24434985

  1. Catalytic Hydrothermal Gasification of Wet Biomass Feedstock

    SciTech Connect

    2006-04-01

    Industries and municipalities generate substantial amounts of biomass as high-moisture waste streams, such as animal manure, food processing sludge, stillage from ethanol production, and municipal wastewater sludge.

  2. Prioritizing pharmaceuticals in municipal wastewater

    EPA Science Inventory

    Oral presentation at SETAC North America 32nd annual meeting, describing our prioritization of active pharmaceutical ingredients (APIs), based on estimates of risks posed by API residues originating from municipal wastewater. Goals of this project include prioritization of APIs f...

  3. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor

    SciTech Connect

    Yan Cao; Hongcang Zhou; Junjie Fan; Houyin Zhao; Tuo Zhou; Pauline Hack; Chia-Chun Chan; Jian-Chang Liou; Wei-ping Pan

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150{sup o}C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650{sup o}C in the upper part of the fluidized bed combustor seemed to be responsible for the reduction of gaseous chlorine and, consequently, limited mercury emissions reduction during cofiring. 36 refs., 3 figs. 1 tab.

  4. Influence of Combustion Conditions on Yields of Solvent-Extractable Anhydrosugars and Lignin Phenols in Chars: Implications for Characterizations of Biomass Combustion Residues

    SciTech Connect

    Kuo, Li-Jung; Louchouarn, Patrick; Herbert, Bruce

    2011-10-01

    Anhydrosugars, such as levoglucosan and its isomers (mannosan, galactosan), as well as the solvent-extractable lignin phenols (methoxylated phenols) are thermal degradation products of cellulose/hemicellulos and lignin, respectively. These two groups of biomarkers are often used as unique tracers of combusted biomass inputs in diverse environmental media. However, detail characterization of the relative proportion and signatures of these compounds in highly heterogeneous plant-derived chars/charcoals are still scarce. Here we conducted a systematic study to investigate the yields of solvent-extractable anhydrosugars and lignin phenols in twenty-five lab-made chars produced from different plant materials under different combustion conditions. Solvent extractable anhydrosugars and lignin phenols were only observed in chars formed below 350 C and yields were variable across different combustion temperatures. The yields mannosan (M) and galactosan (G) decreased more rapidly than those of levoglucosan (L) under increasing combustion severity (temp. and duration), resulting in variable L/M and L/(M+G) ratios, two diagnostic ratios often used for identification of combustion sources (e.g. hardwoods vs. softwoods vs. grasses). On the other hand, the results of this study suggest that the ratios of the major solvent-extractable lignin phenols (vanillyls (V), syringyls (S), cinnamyls (C)) provide additional source reconstruction potential despite observed variations with combustion temperature. We thus propose using a property property plot (L/M vs. S/V) as an improved means for source characterization of biomass combustion residues. The L/M-S/V plot has shown to be effective in environmental samples (soil organic matter, atmospheric aerosols) receiving substantial inputs of biomass combustion residues.

  5. Biomass energy conversion in Hawaii

    NASA Astrophysics Data System (ADS)

    Ritschard, R. L.; Ghirardi, A.

    1981-06-01

    Materials and processes for producing liquid fuels from biomass are discussed. Direct combustion of biomass is discussed. The use of sugar industry products, tree crops, municipal solid wastes, and other biomass resources is discussed, as well as the environmental impacts of direct combustion systems.

  6. Global and Regional Potential for Biofuels From Residue and Waste

    NASA Astrophysics Data System (ADS)

    Gregg, J. S.; Smith, S. J.

    2007-12-01

    As co-products, agricultural and forestry residues as well as municipal solid waste (MSW) represent potential low cost lignocellulosic biomass feedstocks for the production of second generation biofuels. For agriculture, the maximum supply is a function of crop-specific attributes (harvest index and energy content of residue) and total crop production (yield and total harvested area). For forestry, two potential residue streams are considered: residue left from timber harvesting (tree tops and branches), and residue from mills (wood scraps and sawdust). The harvest index, milling efficiencies, and energy content of wood are used to estimate the total potential supply of forestry residues. MSW is predicted as a function of GDP and the proportional waste composition indicative of various regions. Limiting factors for supply of biomass feedstock from these sources include agricultural and forest productivity, residue required to prevent soil erosion and maintain soil nutrients, and cost of aggregation and transport. Using the ObjECTS MiniCAM Integrated Assessment Model, the global role of residue biomass as a feedstock for biofuels is modeled for the next century under different climate policy scenarios.

  7. Carbon decomposition process of the residual biomass in the paddy soil of a single-crop rice field

    NASA Astrophysics Data System (ADS)

    Okada, K.; Iwata, T.

    2014-12-01

    In cultivated fields, residual organic matter is plowed into soil after harvest and decaying in fallow season. Greenhouse gases such as CO2 and CH4 is generated by the decomposition of the substantial organic matter and released into the atmosphere. In some fields, open burning is carried out by tradition, when carbon in residual matter is released into atmosphere as CO2. However, burning effect on carbon budget between crop lands and atmosphere is not entirely considered yet. In this study, coarse organic matter (COM) in paddy soil of a single-crop rice field was sampled on regular intervals between January, 2011 and August, 2014 The amount of carbon release from residual matter was estimated by analyzing of the variations in carbon content of COM. Effects of soil temperature (Ts) and soil water content (SWC) at the paddy field on the rate of carbon decomposition was investigated. Though decreasing rate of COM was much smaller in winter season, it is accelerated at the warming season between April and June every year. Decomposition was resisted for next rice cultivated season despite of highest soil temperature. In addition, the observational field was divided into two areas, and three time open burning experiments were conducted in November, 2011, 2012, and 2013. In each year, three sampling surveys, or plants before harvest and residuals before and after the burning experiment, were done. From these surveys, it is suggested that about 48±2% of carbon contents of above-ground plant was yield out as grain by harvest, and about 27±2% of carbon emitted as CO2 by burning. Carbon content of residuals plowed into soil after the harvest was estimated 293±1 and 220±36gC/m2 in no-burned and burned area, respectively, based on three-years average. It is estimated that 70 and 60% of the first input amount of COM was decomposed after a year in no-burned and burned area, respectively.

  8. Biodrying for municipal solid waste: volume and weight reduction.

    PubMed

    Bilgin, Melayib; Tulun, Şevket

    2015-01-01

    Biodrying is a variation of aerobic decomposition used for the mechanical-biological treatment organic substances to dry and partially stabilize residual municipal waste. This study focuses on the volume and weight reduction biodegradation of the biodrying process using municipal solid waste and the appearance of a stable, final product. The materials were placed in a reactor with invariant airflow rates of 50 L/h and initial moisture contents of 48.49-50.00%. The laboratory-scale experiments were implemented using a 36-L biodrying reactor equipped with an air supply system, a biomass temperature sensor and air sensors. To determine the effect of temperature on biodrying, the process was repeated at various temperatures between 30 °C and 50 °C. The results obtained indicated that after 13 days, biodrying reduced the volume content of waste by 32% and the final product had a high calorific value (4680 kcal/kg). PMID:25571768

  9. Biothermal gasification of biomass

    SciTech Connect

    Chynoweth, D.P.; Srivastava, V.J.; Henry, M.P.; Tarman, P.B.

    1980-01-01

    The BIOTHERMGAS Process is described for conversion of biomass, organic residues, and peat to substitute natural gas (SNG). This new process, under development at IGT, combines biological and thermal processes for total conversion of a broad variety of organic feeds (regardless of water or nutrient content). The process employs thermal gasification for conversion of refractory digester residues. Ammonia and other inorganic nutrients are recycled from the thermal process effluent to the bioconversion unit. Biomethanation and catalytic methanation are presented as alternative processes for methanation of thermal conversion product gases. Waste heat from the thermal component is used to supply the digester heat requirements of the bioconversion component. The results of a preliminary systems analysis of three possible applications of this process are presented: (1) 10,000 ton/day Bermuda grass plant with catalytic methanation; (2) 10,000 ton/day Bermuda grass plant with biomethanation; and (3) 1000 ton/day municipal solid waste (MSW) sewage sludge plant with biomethanation. The results indicate that for these examples, performance is superior to that expected for biological or thermal processes used separately. The results of laboratory studies presented suggest that effective conversion of thermal product gases can be accomplished by biomethanation.

  10. Addressing the municipal market

    SciTech Connect

    Mullin, R.

    1993-05-12

    Most municipalities employ simple, fairly inexpensive water treatment regimes, which is why some large industrial treatment firms stay away from the municipal market, despite rapid growth in the sector. Of the $625 million/year spent for US wastewater treatment, 46% is for municipalities, up 14.5% from 1987. Waste treatment in general grew by 12% in that period, according to Kline Co. (Fairfield, NJ). Some of the challenges facing municipalities in the Clean Water Act reauthorization bills are metals-contaminated sediments and storm water containment and treatment. Bill Tullos, business manager for chlor-alkali at Elf Atochem North America, does not foresee a phaseout of chlorine-based products used as disinfectant in drinking water treatment by municipalities, or as a wastewater treatment in municipal and industrial use. [open quotes]Alternatives are not as effective and are more expensive,[close quotes] says Tullos. [open quotes]There was some promise with ozone, but unfortunately it tends to tear apart your corrosion and scale inhibitors. Chlorine also provides residual protection from contamination all along the water line system.[close quotes] Tullos adds that the formation of tetrahydromethane-one of the problems of using chlorine-based products-can be avoided by screening out the hydrocarbons first and then adding chlorine.

  11. First Characterization of Biomass Burning Smoke from Cooking Fires, Peat, Crop Residue and Other Fuels By High Resolution PTR-TOF Mass Spectrometry and FTIR

    NASA Astrophysics Data System (ADS)

    Stockwell, C.; Veres, P. R.; Williams, J.; Yokelson, R. J.

    2014-12-01

    Biomass burning (BB) is a major influence on Earth's atmosphere, but for many fire-types the emissions have only been measured for a few species. For all types of BB, progress has been limited by a lack of information on the emissions of semi-volatile organic gases that are precursors for secondary aerosol and ozone. During the Fourth Fire Lab at Missoula Experiment (FLAME-4), the BB emissions from 158 laboratory fires were quantified by ~40 scientists for an assortment of globally relevant fuels including rarely sampled sources such as US and Asian crop residue; Indonesian and extratropical peat; and cooking fires in traditional and advanced stoves. In this work, we present the primary emissions of gas-phase non-methane organic compounds (NMOCs) measured using an advanced Proton-Transfer-Reaction time-of-flight mass spectrometer (PTR-TOF-MS) in tandem with measurements of other major emissions by Fourier transform infrared (FTIR) spectroscopy. We developed a composition and mass dependent sensitivity and best assignments for many observed peaks. The known and tentatively assigned peaks together account for ~80-96% of total observed NMOC mass. Much of the NMOC mass is rarely measured or previously unmeasured high molecular mass compounds including ringed aromatic hydrocarbons, phenolic compounds, and furans, which are all secondary organic aerosol precursors. Large air quality benefits are demonstrated for more advanced cooking technologies. This work produced globally relevant emission ratios and emission factors to better represent biomass burning in current atmospheric models.

  12. WASTE ANALYSIS, SAMPLING, TESTING AND EVALUATION PROGRAM: EFFECT OF LEAD AND CADMIUM SPIKING OF MUNICIPAL SOLID WASTE ON THE CHARACTERISTICS OF MWS INCINERATOR RESIDUES

    EPA Science Inventory

    In June of 1991, the Waste Analysis, Sampling, Testing and Evaluation (WASTE) Program was initiated to identify the major source(s) of trace metals in the feed stream of a municipal solid waste (MSW) incinerator and to measure the partitioning of metals during the incineration pr...

  13. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor.

    PubMed

    Cao, Yan; Zhou, Hongcang; Fan, Junjie; Zhao, Houyin; Zhou, Tuo; Hack, Pauline; Chan, Chia-Chun; Liou, Jian-Chang; Pan, Wei-Ping

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150 degrees C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. This was also true when limestone was added while cofiring coal and chicken waste because the gaseous chlorine was reduced in the freeboard of the fluidized bed combustor, where the temperature was generally below 650 degrees C without addition of the secondary air. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650 degrees C in the upper part of the fluidized bed combustor seemed to be

  14. Comparative life cycle assessment (LCA) of construction and demolition (C&D) derived biomass and U.S. northeast forest residuals gasification for electricity production.

    PubMed

    Nuss, Philip; Gardner, Kevin H; Jambeck, Jenna R

    2013-04-01

    With the goal to move society toward less reliance on fossil fuels and the mitigation of climate change, there is increasing interest and investment in the bioenergy sector. However, current bioenergy growth patterns may, in the long term, only be met through an expansion of global arable land at the expense of natural ecosystems and in competition with the food sector. Increasing thermal energy recovery from solid waste reduces dependence on fossil- and biobased energy production while enhancing landfill diversion. Using inventory data from pilot processes, this work assesses the cradle-to-gate environmental burdens of plasma gasification as a route capable of transforming construction and demolition (C&D) derived biomass (CDDB) and forest residues into electricity. Results indicate that the environmental burdens associated with CDDB and forest residue gasification may be similar to conventional electricity generation. Land occupation is lowest when CDDB is used. Environmental impacts are to a large extent due to coal cogasified, coke used as gasifier bed material, and fuel oil cocombusted in the steam boiler. However, uncertainties associated with preliminary system designs may be large, particularly the heat loss associated with pilot scale data resulting in overall low efficiencies of energy conversion to electricity; a sensitivity analysis assesses these uncertainties in further detail. PMID:23496419

  15. Detoxification of Olive Mill Wastewater and Bioconversion of Olive Crop Residues into High-Value-Added Biomass by the Choice Edible Mushroom Hericium erinaceus.

    PubMed

    Koutrotsios, Georgios; Larou, Evangelia; Mountzouris, Konstantinos C; Zervakis, Georgios I

    2016-09-01

    Environmentally acceptable disposal of olive cultivation residues (e.g., olive prunings; olive pruning residues (OLPR)) and olive mill wastes is of paramount importance since they are generated in huge quantities within a short time. Moreover, olive mill wastewater (OMW) or sludge-like effluents ("alperujo"; two-phase olive mill waste (TPOMW)) are highly biotoxic. Hericium erinaceus is a white-rot fungus which produces choice edible mushrooms on substrates rich in lignocellulosics, and its suitability for the treatment of olive by-products was examined for the first time. Fungal growth resulted in a notable reduction of OMW's pollution parameters (i.e., 65 % decolorization, 47 % total phenolic reduction, and 52 % phytotoxicity decrease) and correlated with laccase and manganese peroxidase activities. Solid-state fermentation of various mixtures of OLPR, TPOMW, and beech sawdust (control) by H. erinaceus qualified OLPR in subsequent cultivation experiments, where it exhibited high mushroom yields and biological efficiency (31 %). Analyses of proximate composition and bioactive compound content revealed that mushrooms deriving from OLPR substrates showed significantly higher crude fat, total glucan, β-glucan, total phenolics, and ferric-reducing antioxidant potential values than the control. H. erinaceus demonstrated the potential to detoxify OMW and bioconvert OLPR into high-quality biomass, and hence, this fungus could be successfully exploited for the treatment of such by-products. PMID:27138726

  16. Biomass energy

    SciTech Connect

    Smil, V.

    1983-01-01

    This book offers a broad, interdisciplinary approach to assessing the factors that are key determinants to the use of biomass energies, stressing their limitations, complexities, uncertainties, links, and consequences. Considers photosynthesis, energy costs of nutrients, problems with monoculture, and the energy analysis of intensive tree plantations. Subjects are examined in terms of environmental and economic impact. Emphasizes the use and abuse of biomass energies in China, India, and Brazil. Topics include forests, trees for energy, crop residues, fuel crops, aquatic plants, and animal and human wastes. Recommended for environmental engineers and planners, and those involved in ecology, systematics, and forestry.

  17. Evaluation of the biomass potential for the production of lignocellulosic bioethanol from various agricultural residues in Austria and Worldwide

    NASA Astrophysics Data System (ADS)

    Kahr, Heike; Steindl, Daniel; Wimberger, Julia; Schürz, Daniel; Jäger, Alexander

    2013-04-01

    Due to the fact that the resources of fossil fuels are steadily decreasing, researchers have been trying to find alternatives over the past few years. As bioethanol of the first generation is based on potential food, its production has become an increasingly controversial topic. Therefore the focus of research currently is on the production of bioethanol of the second generation, which is made from cellulosic and lignocellulosic materials. However, for the production of bioethanol of the second generation the fibres have to be pre-treated. In this work the mass balances of various agricultural residues available in Austria were generated and examined in lab scale experiments for their bioethanol potential. The residues were pretreatment by means of state of the art technology (steam explosion), enzymatically hydrolysed and fermented with yeast to produce ethanol. Special attention was paid the mass balance of the overall process. Due to the pretreatment the proportion of cellulose increases with the duration of the pre-treatment, whereby the amount of hemicellulose decreases greatly. However, the total losses were increasing with the duration of the pre-treatment, and the losses largely consist of hemicellulose. The ethanol yield varied depending on the cellulose content of the substrates. So rye straw 200 °C 20 min reaches an ethanol yield of 169 kg/t, by far the largest yield. As result on the basis of the annual straw yield in Austria, approximately 210 000 t of bioethanol (266 million litres) could be produced from the straw of wheat (Triticum vulgare), rye (Secale cereale), oat (Avena sativa) and corn (Zea mays) as well as elephant grass (Miscanthus sinensis) using appropriate pre-treatment. So the greenhouse gas emissions produced by burning fossil fuels could be reduced significantly. About 1.8 million tons of motor gasoline are consumed in Austria every year. The needed quantity for a transition to E10 biofuels could thus be easily provided by bioethanol

  18. Characterization of biomass burning smoke from cooking fires, peat, crop residue and other fuels with high resolution proton-transfer-reaction time-of-flight mass spectrometry

    NASA Astrophysics Data System (ADS)

    Stockwell, C. E.; Veres, P. R.; Williams, J.; Yokelson, R. J.

    2014-08-01

    We deployed a high-resolution proton-transfer-reaction time-of-flight mass spectrometer (PTR-TOF-MS) to measure biomass burning emissions from peat, crop-residue, cooking fires, and many other fire types during the fourth Fire Lab at Missoula Experiment (FLAME-4) laboratory campaign. A combination of gas standards calibrations and composition sensitive, mass dependent calibration curves were applied to quantify gas-phase non-methane organic compounds (NMOCs) observed in the complex mixture of fire emissions. We used several approaches to assign best identities to most major "exact masses" including many high molecular mass species. Using these methods approximately 80-96% of the total NMOC mass detected by PTR-TOF-MS and FTIR was positively or tentatively identified for major fuel types. We report data for many rarely measured or previously unmeasured emissions in several compound classes including aromatic hydrocarbons, phenolic compounds, and furans; many of which are suspected secondary organic aerosol precursors. A large set of new emission factors (EFs) for a range of globally significant biomass fuels is presented. Measurements show that oxygenated NMOCs accounted for the largest fraction of emissions of all compound classes. In a brief study of various traditional and advanced cooking methods, the EFs for these emissions groups were greatest for open 3-stone cooking in comparison to their more advanced counterparts. Several little-studied nitrogen-containing organic compounds were detected from many fuel types that together accounted for 0.1-8.7% of the fuel nitrogen and some may play a role in new particle formation.

  19. Characterization of biomass burning emissions from cooking fires, peat, crop residue, and other fuels with high-resolution proton-transfer-reaction time-of-flight mass spectrometry

    NASA Astrophysics Data System (ADS)

    Stockwell, C. E.; Veres, P. R.; Williams, J.; Yokelson, R. J.

    2015-01-01

    We deployed a high-resolution proton-transfer-reaction time-of-flight mass spectrometer (PTR-TOF-MS) to measure biomass-burning emissions from peat, crop residue, cooking fires, and many other fire types during the fourth Fire Lab at Missoula Experiment (FLAME-4) laboratory campaign. A combination of gas standard calibrations and composition sensitive, mass-dependent calibration curves was applied to quantify gas-phase non-methane organic compounds (NMOCs) observed in the complex mixture of fire emissions. We used several approaches to assign the best identities to most major "exact masses", including many high molecular mass species. Using these methods, approximately 80-96% of the total NMOC mass detected by the PTR-TOF-MS and Fourier transform infrared (FTIR) spectroscopy was positively or tentatively identified for major fuel types. We report data for many rarely measured or previously unmeasured emissions in several compound classes including aromatic hydrocarbons, phenolic compounds, and furans; many of these are suspected secondary organic aerosol precursors. A large set of new emission factors (EFs) for a range of globally significant biomass fuels is presented. Measurements show that oxygenated NMOCs accounted for the largest fraction of emissions of all compound classes. In a brief study of various traditional and advanced cooking methods, the EFs for these emissions groups were greatest for open three-stone cooking in comparison to their more advanced counterparts. Several little-studied nitrogen-containing organic compounds were detected from many fuel types, that together accounted for 0.1-8.7% of the fuel nitrogen, and some may play a role in new particle formation.

  20. Energy conversion of biomass crops and agroindustrial residues by combined biohydrogen/biomethane system and anaerobic digestion.

    PubMed

    Corneli, Elisa; Dragoni, Federico; Adessi, Alessandra; De Philippis, Roberto; Bonari, Enrico; Ragaglini, Giorgio

    2016-07-01

    Aim of this study was to evaluate the suitability of ensiled giant reed, ensiled maize, ensiled olive pomace, wheat bran for combined systems (CS: dark fermentation+anaerobic digestion (AD)) producing hydrogen-rich biogas (biohythane), tested in batch under basic operational conditions (mesophilic temperatures, no pH control). Substrates were also analyzed under a single stage AD batch test, in order to investigate the effects of DF on estimated energy recovery (ER) in combined systems. In CS, maize and wheat bran exhibited the highest hydrogen potential (13.8 and 18.9NLkgVS(-1)) and wheat bran the highest methane potential (243.5NLkgVS(-1)). In one-stage AD, giant reed, maize and wheat bran showed the highest methane production (239.5, 267.3 and 260.0NLkgVS(-1)). Butyrate/acetate ratio properly described the dark fermentation, correlating with hydrogen production (r=0.92). Wheat bran proved to be a promising residue for CS in terms of hydrogen/methane potential and ER. PMID:27038259

  1. Northeast regional biomass program. Retrospective, 1983--1993

    SciTech Connect

    Savitt, S.; Morgan, S.

    1995-01-01

    Ten years ago, when Congress initiated the Regional Biomass Energy Program, biomass fuel use in the Northeast was limited primarily to the forest products industry and residential wood stoves. An enduring form of energy as old as settlement in the region, residential wood-burning now takes its place beside modern biomass combustion systems in schools and other institutions, industrial cogeneration facilities, and utility-scale power plants. Biomass today represents more than 95 percent of all renewable energy consumed in the Northeast: a little more than one-half quadrillion BTUs yearly, or five percent of the region`s total energy demand. Yet given the region`s abundance of overstocked forests, municipal solid waste and processed wood residues, this represents just a fraction of the energy potential the biomass resource has to offer.This report provides an account of the work of the Northeast Regional Biomass Program (NRBP) over it`s first ten years. The NRBP has undertaken projects to promote the use of biomass energy and technologies.

  2. Biomass energy: Sustainable solution for greenhouse gas emission

    NASA Astrophysics Data System (ADS)

    Sadrul Islam, A. K. M.; Ahiduzzaman, M.

    2012-06-01

    Biomass is part of the carbon cycle. Carbon dioxide is produced after combustion of biomass. Over a relatively short timescale, carbon dioxide is renewed from atmosphere during next generation of new growth of green vegetation. Contribution of renewable energy including hydropower, solar, biomass and biofuel in total primary energy consumption in world is about 19%. Traditional biomass alone contributes about 13% of total primary energy consumption in the world. The number of traditional biomass energy users expected to rise from 2.5 billion in 2004 to 2.6 billion in 2015 and to 2.7 billion in 2030 for cooking in developing countries. Residential biomass demand in developing countries is projected to rise from 771 Mtoe in 2004 to 818 Mtoe in 2030. The main sources of biomass are wood residues, bagasse, rice husk, agro-residues, animal manure, municipal and industrial waste etc. Dedicated energy crops such as short-rotation coppice, grasses, sugar crops, starch crops and oil crops are gaining importance and market share as source of biomass energy. Global trade in biomass feedstocks and processed bioenergy carriers are growing rapidly. There are some drawbacks of biomass energy utilization compared to fossil fuels viz: heterogeneous and uneven composition, lower calorific value and quality deterioration due to uncontrolled biodegradation. Loose biomass also is not viable for transportation. Pelletization, briquetting, liquefaction and gasification of biomass energy are some options to solve these problems. Wood fuel production is very much steady and little bit increase in trend, however, the forest land is decreasing, means the deforestation is progressive. There is a big challenge for sustainability of biomass resource and environment. Biomass energy can be used to reduce greenhouse emissions. Woody biomass such as briquette and pellet from un-organized biomass waste and residues could be used for alternative to wood fuel, as a result, forest will be saved and

  3. Co-gasification of sewage sludge and woody biomass in a fixed-bed downdraft gasifier: toxicity assessment of solid residues.

    PubMed

    Rong, Le; Maneerung, Thawatchai; Ng, Jingwen Charmaine; Neoh, Koon Gee; Bay, Boon Huat; Tong, Yen Wah; Dai, Yanjun; Wang, Chi-Hwa

    2015-02-01

    As the demand for fossil fuels and biofuels increases, the volume of ash generated will correspondingly increase. Even though ash disposal is now strictly regulated in many countries, the increasing volume of ash puts pressure on landfill sites with regard to cost, capacity and maintenance. In addition, the probability of environmental pollution from leakage of bottom ash leachate also increases. The main aim of this research is to investigate the toxicity of bottom ash, which is an unavoidable solid residue arising from biomass gasification, on human cells in vitro. Two human cell lines i.e. HepG2 (liver cell) and MRC-5 (lung fibroblast) were used to study the toxicity of the bottom ash as the toxins in the bottom ash may enter blood circulation by drinking the contaminated water or eating the food grown in bottom ash-contaminated water/soil and the toxic compounds may be carried all over the human body including to important organs such as lung, liver, kidney, and heart. It was found that the bottom ash extract has a high basicity (pH = 9.8-12.2) and a high ionic strength, due to the presence of alkali and alkaline earth metals e.g. K, Na, Ca and Mg. Moreover, it also contains concentrations of heavy metals (e.g. Zn, Co, Cu, Fe, Mn, Ni and Mo) and non-toxic organic compounds. Although human beings require these trace elements, excessive levels can be damaging to the body. From the analyses of cell viability (using MTS assay) and morphology (using fluorescence microscope), the high toxicity of the gasification bottom ash extract could be related to effects of high ionic strength, heavy metals or a combination of these two effects. Therefore, our results suggest that the improper disposal of the bottom ash wastes arising from gasification can create potential risks to human health and, thus, it has become a matter of urgency to find alternative options for the disposal of bottom ash wastes. PMID:25532673

  4. Quantification and kinetic characterization of soluble microbial products from municipal wastewater treatment plants.

    PubMed

    Xie, Wen-Ming; Ni, Bing-Jie; Sheng, Guo-Ping; Seviour, Thomas; Yu, Han-Qing

    2016-01-01

    Soluble microbial products (SMP) formed by microorganisms in wastewater treatment plants (WWTPs) adversely affect final effluent quality and treatment efficiency. It is difficult to distinguish SMP from residual proteins, lipids and carbohydrates present in the influent that may persist during treatment. No method is currently available to determine quantitatively the extent to which SMP contribute to organic discharges from municipal WWTPs. In this work a modeling approach is presented which allows the SMP fraction of the effluent of a municipal WWTP to be quantified and described. The model is validated, in terms of utilization-associated products, biomass-associated products and extracellular polymeric substances, using influent from a municipal WWTP. SMP was found to account for, on average, 27 mg/L of chemical oxygen demand (COD), or 61% of the total COD in the WWTP effluent. Over 90% of the SMP was comprised of biomass-associated products. Five main factors influencing SMP formation in WWTP were evaluated. Neither wastewater composition nor mixed liquor suspended solids concentration was found to affect SMP production. On the other hand, a positive correlation was observed for SMP formation with both solids retention time and influent COD concentration, and a negative correlation with hydraulic retention time. Thus, operating or designing WWTPs with short solids retention and long hydraulic retention times could be considered as solutions for minimizing SMP production. PMID:26580086

  5. Energy potential of residue from wood transformation industry in the central metropolitan area of the Principality of Asturias (northwest Spain).

    PubMed

    Paredes-Sánchez, José Pablo; Gutiérrez-Trashorras, Antonio José; Xiberta-Bernat, Jorge

    2014-03-01

    The development of modern cities favours the formation of metropolitan zones with urban and industrial areas. The central metropolitan area (CMA) of the Principality of Asturias (northwest Spain), takes up 9.6% of the territory and represents 78% of its population. The first and second wood transformation industries of the CMA generate rather large amounts of biomass residues suitable for both reclaim and energy valuation considering technical, economic, and environmental restrictions. The results obtained from the evaluation of the biomass and the bioenergy of these residues are 7.9 kt/year and 114.7 TJ/year, respectively. The location for the development of a densified solid biofuels plant to produce pellets from these available residues is proposed for the Siero municipality, which is in the CMA. The plant would have an annual potential production capacity for the conventional pelletization process equivalent to 10 MW of fuel output. PMID:24503526

  6. PYROLYSIS OF MUNICIPAL AND INDUSTRIAL WASTE

    EPA Science Inventory

    The paper provides a historical overview of some 21 U.S. research and development activities associated with municipal/industrial waste and biomass conversion-to-energy pyrolysis technologies. The history begins in the early 1970's and is brought forward to the present. Of the 21...

  7. 2007 Biomass Program Overview

    SciTech Connect

    none,

    2009-10-27

    The Biomass Program is actively working with public and private partners to meet production and technology needs. With the corn ethanol market growing steadily, researchers are unlocking the potential of non-food biomass sources, such as switchgrass and forest and agricultural residues. In this way, the Program is helping to ensure that cost-effective technologies will be ready to support production goals for advanced biofuels.

  8. Biomass Burning

    Atmospheric Science Data Center

    2015-07-27

    Projects:  Biomass Burning Definition/Description:  Biomass Burning: This data set represents the geographical and temporal distribution of total amount of biomass burned. These data may be used in general circulation models (GCMs) and ...

  9. Northeast Regional Biomass Program

    SciTech Connect

    Lusk, P.D.

    1992-12-01

    The Northeast Regional Biomass Program has been in operation for a period of nine years. During this time, state managed programs and technical programs have been conducted covering a wide range of activities primarily aim at the use and applications of wood as a fuel. These activities include: assessments of available biomass resources; surveys to determine what industries, businesses, institutions, and utility companies use wood and wood waste for fuel; and workshops, seminars, and demonstrations to provide technical assistance. In the Northeast, an estimated 6.2 million tons of wood are used in the commercial and industrial sector, where 12.5 million cords are used for residential heating annually. Of this useage, 1504.7 mw of power has been generated from biomass. The use of wood energy products has had substantial employment and income benefits in the region. Although wood and woodwaste have received primary emphasis in the regional program, the use of municipal solid waste has received increased emphasis as an energy source. The energy contribution of biomass will increase as potentia users become more familiar with existing feedstocks, technologies, and applications. The Northeast Regional Biomass Program is designed to support region-specific to overcome near-term barriers to biomass energy use.

  10. Environmental Implications of Biomass Removal

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biomass removal from the soil surface after harvest or as the harvest operation and then sued for energy production offers the potential for a significant energy resource. There are challenges that arise with biomass removal in cropping systems in which the crop residue has remained on the soil sur...

  11. Bacterial antibiotic resistance in soils irrigated with reclaimed municipal wastewater

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Wastewater reclamation for municipal irrigation and groundwater recharge is an increasingly attractive option for extending water supplies. However, public health concerns include the potential for development of antibiotic resistance (AR) in soil bacteria after exposure to residual chemicals in rec...

  12. Biomass -- A new assessment

    SciTech Connect

    Hartung, H.A.

    1999-07-01

    Photo-conversion of atmospheric CO{sub 2} to biomass by plants is the world's basic source of food, fiber, oxygen and fossil fuel; for many people and some industries, biomass combustion supplies a significant amount of the energy they need. Much ingenuity has been applied to developing strategies for recovering energy directly from biomass by cleaning burning, gasification and liquid fuel production; these processes generally have economic or ecological features that keep them out of the main stream of technological development. By contrast, fresh biomass can be digested anaerobically at high conversion, with stimulation, to methane-rich gas and a stabilized organic residue, using technology already at hand. As an example, methane can be produced from sugarcane at a total cost of about $.50/mcf. This process, originally devised to control the level of CO{sub 2} in the atmosphere, provides opportunities to contribute to that goal while supplying clean pipeline gas, electricity or petrochemicals.

  13. Biomass energies: resources, links, constraints

    SciTech Connect

    Smil, V.

    1983-01-01

    This book presents information on the following topics: radiation and photosynthesis; primary production and biomass; resources; wood for energy; silviculture; requirements and effects; crop residues; residues for energy conversion; sugar crops and grain; cassava; fuel crops; aquatic plants; freshwater plants; ocean algae; animal wastes; Chinese biogas generation; and ecodisasters.

  14. MTCI/Thermochem stream reforming process for biomass

    SciTech Connect

    Mansour, M.N.; Durai-Swamy, K.; Voelker, G.

    1995-11-01

    Manufacturing and Technology Conversion International, Inc. (MTCI) has developed a novel technology to convert solid fuels including biomass, coal, municipal solid waste (MSW) and wastewater sludges into usable syngas by steam reforming in an indirectly heated, fluid-bed reactor. MTCI has licensed and patented the technology to ThermoChem, Inc. Both MTCI and ThermoChem have built two modular commercial-scale demonstration units: one for recycle paper mill rejects (similar to refuse-derived fuel [RDF]), and another for chemical recovery of black liquor. ThermoChem has entered into an agreement with Ajinkyatara Cooperative Sugar Factory, India, for building a 10 MW combined cycle power generation facility based on bagasse & agro-residue gasification.

  15. Solid state fermentation of olive mill residues by wood- and dung-dwelling Agaricomycetes: effects on peroxidase production, biomass development and phenol phytotoxicity.

    PubMed

    Reina, Rocío; Liers, Christiane; Ocampo, Juan Antonio; García-Romera, Inmaculada; Aranda, Elisabet

    2013-10-01

    The in vivo conversion of dry olive mill residue (DOR) by wood- and dung-dwelling fungi - Auricularia auricula-judae, Bjerkandera adusta and Coprinellus radians - increases peroxidase secretion up to 3.2-3.5-fold (∼1.3, 3.5 and 7.0 Ug(-1) DOR for dye-decolorizing peroxidase, manganese peroxidase and aromatic peroxygenases, respectively). The incubation of DOR with these fungi produced a sharp decrease in total phenolic content (100% within 4 wk), a reduction in phytotoxicity as well as a certain degree of plant growth caused by the stimulating effect of fungal-treated DOR. These findings correlate with a characteristic shift in the fragmentation pattern of water-soluble aromatics (detected at 280 nm) from low (0.2, 1.5 and 2.2 kDa, respectively) to high molecular mass (35 to >200 kDa), which demonstrates the presence of a polymerization process. Phenol-rich agricultural residues are a useful tool for enzyme expression and production studies of peroxidase-producing Agaricomycetes which could make DOR a valuable organic fertilizer. PMID:23920362

  16. Regional assessment of nonforestry related biomass resources: Virginia

    SciTech Connect

    Not Available

    1988-11-01

    This document is a collection of spreadsheets detailing on a county by county basis the agricultural crop, agricultural wastes, municipal wastes, and industrial wastes of Virginia that are potential biomass energy sources.

  17. Regional assessment of nonforestry related biomass resources: North Carolina

    SciTech Connect

    Not Available

    1988-11-01

    This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes and industrial wastes of North Carolina that are potential biomass energy sources.

  18. Regional assessment of nonforestry related biomass resources: Alabama

    SciTech Connect

    Not Available

    1988-11-01

    This document is a collection of spreadsheets detailing on a county by county basis the agricultural crop, agricultural wastes, municipal wastes and industrial wastes of Alabama that are potential biomass energy sources.

  19. Regional assessment of nonforestry related biomass resources: Arkansas

    SciTech Connect

    Not Available

    1988-11-01

    This document consists of spreadsheets detailing in a county by county manner agricultural crop, agricultural waste, municipal waste and industrial waste in Arkansas that are potential biomass energy sources.

  20. Regional assessment of nonforestry related biomass resources: South Carolina

    SciTech Connect

    Not Available

    1988-11-01

    This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes, and industrial wastes of South Carolina that are potential biomass energy sources.

  1. Regional assessment of nonforestry related biomass resources: Georgia

    SciTech Connect

    Not Available

    1988-11-01

    This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes, and industrial wastes in Georgia that are potential biomass energy sources.

  2. BIOMASS UTILIZATION

    EPA Science Inventory

    The biomass utilization task consists of the evaluation of a biomass conversion technology including research and development initiatives. The project is expected to provide information on co-control of pollutants, as well as, to prove the feasibility of biomass conversion techn...

  3. Biomass pretreatment

    SciTech Connect

    Hennessey, Susan Marie; Friend, Julie; Elander, Richard T; Tucker, III, Melvin P

    2013-05-21

    A method is provided for producing an improved pretreated biomass product for use in saccharification followed by fermentation to produce a target chemical that includes removal of saccharification and or fermentation inhibitors from the pretreated biomass product. Specifically, the pretreated biomass product derived from using the present method has fewer inhibitors of saccharification and/or fermentation without a loss in sugar content.

  4. The effects of fuel composition and ammonium sulfate addition on PCDD, PCDF, PCN and PCB concentrations during the combustion of biomass and paper production residuals.

    PubMed

    Lundin, Lisa; Jansson, Stina

    2014-01-01

    The use of waste wood as an energy carrier has increased during the last decade. However, the higher levels of alkali metals and chlorine in waste wood compared to virgin biomass can promote the formation of deposits and organic pollutants. Here, the effect of fuel composition and the inhibitory effects of ammonium sulfate, (NH4)2SO4, on the concentrations of persistent organic pollutants (POPs) in the flue gas of a lab-scale combustor was investigated. Ammonium sulfate is often used as a corrosion-preventing additive and may also inhibit formation of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs). In addition to PCDDs and PCDFs, polychlorinated naphthalenes (PCN) and biphenyls (PCB) were also analyzed. It was found that the flue gas composition changed dramatically when (NH4)2SO4 was added: CO, SO2, and NH3 levels increased, while those of HCl decreased to almost zero. However, the additive's effects on POP formation were less pronounced. When (NH4)2SO4 was added to give an S:Cl ratio of 3, only the PCDF concentration was reduced, indicating that this ratio was not sufficient to achieve a general reduction in POP emissions. Conversely, at an S:Cl ratio of 6, significant reductions in the WHO-TEQ value and the PCDD and PCDF contents of the flue gas were observed. The effect on the PCDF concentration was especially pronounced. PCN formation seemed to be promoted by the elevated CO concentrations caused by adding (NH4)2SO4. PMID:24053941

  5. Possibilities of municipal solid waste incinerator fly ash utilisation.

    PubMed

    Hartmann, Silvie; Koval, Lukáš; Škrobánková, Hana; Matýsek, Dalibor; Winter, Franz; Purgar, Amon

    2015-08-01

    Properties of the waste treatment residual fly ash generated from municipal solid waste incinerator fly ash were investigated in this study. Six different mortar blends with the addition of the municipal solid waste incinerator fly ash were evaluated. The Portland cement replacement levels of the municipal solid waste incinerator fly ash used were 25%, 30% and 50%. Both, raw and washed municipal solid waste incinerator fly ash samples were examined. According to the mineralogical composition measurements, a 22.6% increase in the pozzolanic/hydraulic properties was observed for the washed municipal solid waste incinerator fly ash sample. The maximum replacement level of 25% for the washed municipal solid waste incinerator fly ash in mortar blends was established in order to preserve the compressive strength properties. Moreover, the leaching characteristics of the crushed mortar blend was analysed in order to examine the immobilisation of its hazardous contents. PMID:26060198

  6. Municipal waste processing apparatus

    DOEpatents

    Mayberry, J.L.

    1988-04-13

    This invention relates to apparatus for processing municipal waste, and more particularly to vibrating mesh screen conveyor systems for removing grit, glass, and other noncombustible materials from dry municipal waste. Municipal waste must be properly processed and disposed of so that it does not create health risks to the community. Generally, municipal waste, which may be collected in garbage trucks, dumpsters, or the like, is deposited in processing areas such as landfills. Land and environmental controls imposed on landfill operators by governmental bodies have increased in recent years, however, making landfill disposal of solid waste materials more expensive. 6 figs.

  7. IMPROVING BIOMASS LOGISTICS COST WITHIN AGRONOMIC SUSTAINABILITY CONSTRAINTS AND BIOMASS QUALITY TARGETS

    SciTech Connect

    J. Richard Hess; Kevin L. Kenney; Christopher T. Wright; David J. Muth; William Smith

    2012-10-01

    Equipment manufacturers have made rapid improvements in biomass harvesting and handling equipment. These improvements have increased transportation and handling efficiencies due to higher biomass densities and reduced losses. Improvements in grinder efficiencies and capacity have reduced biomass grinding costs. Biomass collection efficiencies (the ratio of biomass collected to the amount available in the field) as high as 75% for crop residues and greater than 90% for perennial energy crops have also been demonstrated. However, as collection rates increase, the fraction of entrained soil in the biomass increases, and high biomass residue removal rates can violate agronomic sustainability limits. Advancements in quantifying multi-factor sustainability limits to increase removal rate as guided by sustainable residue removal plans, and mitigating soil contamination through targeted removal rates based on soil type and residue type/fraction is allowing the use of new high efficiency harvesting equipment and methods. As another consideration, single pass harvesting and other technologies that improve harvesting costs cause biomass storage moisture management challenges, which challenges are further perturbed by annual variability in biomass moisture content. Monitoring, sampling, simulation, and analysis provide basis for moisture, time, and quality relationships in storage, which has allowed the development of moisture tolerant storage systems and best management processes that combine moisture content and time to accommodate baled storage of wet material based upon “shelf-life.” The key to improving biomass supply logistics costs has been developing the associated agronomic sustainability and biomass quality technologies and processes that allow the implementation of equipment engineering solutions.

  8. An evaluation of the bioconversion of woody biomass to calcium acetate deicing salt

    SciTech Connect

    Wise, D.L.; Augenstein, D. )

    1988-01-01

    A competitive process is described using local woody biomass residues, which may also include associated pulp and paper wastes, or municipal solid waste, as potential feedstocks for bioconversion to calcium acetate, an alternative deicing salt. The process first involves suppressed methane fermentation of these woody biomass residues in a packed bed fermentor for the production of acetic acid. In earlier experimental work, operation of conventional anaerobic digestion systems in this suppressed methane mode has yielded a product of over 85% acetic acid, the remainder primarily being other organic acids such as propionic and butyric acids; operation at thermophilic conditions (60{degree}C) yielded essentially all acetic acid. In the process described, recovery of the dilute organic acids (=3.5% acetic acid) will be by liquid ion exchange extraction. Production calcium acetate is formed by back extraction of liquid ion exchange with calcium hydroxide. After spray drying, this calcium acetate is ready for use as an organic deicing salt. Pretreatment of woody biomass may be by steam explosion or by mild alkali treatment to breakdown the lignin fraction for fermentation to acetic acid; however, if cellulosic wastes are used, no pretreatment step will be needed. Essentially, only technology transfer is involved in commercialization of this process, rather than the development of new technology. Their cost analysis, the objective of this present work, projects calcium acetate costs of 0.258 $US/kg ($0.117/lb) for a full-scale plant of 454 metric tons/day (500 US tons/day).

  9. Overview of IEA biomass combustion activities

    NASA Astrophysics Data System (ADS)

    Hustad, J. E.

    1994-07-01

    The objectives of the International Energy Agency (IEA) bioenergy program are: (1) to encourage cooperative research, development and use of energy and the increased utilization of alternatives to oil; and (2) to establish increased program and project cooperation between participants in the whole field of bioenergy. There are four Task Annexes to the Implementing Agreement during the period 1992-1994: Efficient and Environmentally Sound Biomass Production Systems; Harvesting and Supply of Woody Biomass for Energy; Biomass Utilization; and Conversion of Municipal Solid Waste Feedstock to Energy. The report describes the following biomass combustion activities during the period 1992-1994: Round robin test of a wood stove; Emissions from biomass combustion; A pilot project cofiring biomass with oil to reduce SO2 emissions; Small scale biomass chip handling; Energy from contaminated wood waste combustion; Modeling of biomass combustion; Wood chip cogeneration; Combustion of wet biomass feedstocks, ash reinjection and carbon burnout; Oxidation of wet biomass; Catalytic combustion in small wood burning appliances; Characterization of biomass fuels and ashes; Measurement techniques (FTIR).

  10. Incentives and barriers to siting biomass ethanol plants

    SciTech Connect

    Donovan, C.T.; Fehrs, J.E.

    1996-12-31

    Currently, there are 38 facilities in the United States with the capacity to produce approximately 1.5 billion gallons of ethanol annually. Most are located in the Midwest and use corn as feedstock. Others use other starch-rich residues or waste materials, such as cheese whey, potato processing waste, and waste beer as feedstock. Ethanol can also be produced from cellulose-rich materials, such as wood waste, paper sludge, municipal solid waste, and short rotation woody crops. However, the processes to convert cellulosic biomass to ethanol are less technologically mature, which is the primary reason why no commercial facilities produce ethanol from cellulosic materials. A number of technical, economic, and environmental factors indicate there are substantial opportunities for producing ethanol from cellulosic materials. In the 11-state Northeast region alone (from Maine to Maryland), the amount of biomass materials discarded in 1993 and potentially available from energy crops in the future could produce more than 2.7 billion gallons per year of ethanol. If priority were placed in encouraging the use of high ethanol fuels (such as E85) in public vehicle fleets alone, as much as 175 million gallons per year of fuel could be used. Theoretical analyses of air, ash, and wastewater emissions from hypothetical biomass ethanol plants indicate such plants should be able to meet existing environmental standards. Sensitivity analyses of various siting issues indicate that the availability of production incentives, the cost of capital, and feedstock cost have the greatest impact on the economic viability of a biomass ethanol plant.

  11. Suspended solids from industrial and municipal origins.

    PubMed

    Rosenwinkel, K H; Weichgrebe, D; Meyer, H; Wendler, D

    2001-10-01

    The origins of suspended solids are the effluents of municipal and industrial wastewater treatment plants and storm sewage treatment. This paper deals with the sources of industrial and municipal wastewater treatment and the single treatment of side streams. An overview of the common treatment processes is given and the main sinks for suspended solids are named and described. The food industry is based on the processing of organic matter (fruits, etc.). During the single processing steps three main fractions occur, inorganic material (e.g., from the washing step), organic residues (e.g., the peel), and suspended solids (SS) in the wastewater. Today higher rates of recycling (water and raw materials) can be found in all kinds of industrial processes. The principle is that avoidance should take precedence over utilization which should take precedence over disposal. Numerous possibilities of production-integrated measures exist, e.g., conveyance of production circuits, product recovery, and stepped cleaning. Despite and/or due to these efforts, huge amounts of residues occur. They are the main sink for suspended solids. Only seldom is landfilling used to treat these residues. Usually utilization as animal nourishment or biological (aerobic or anaerobic) or thermal (incineration) treatment methods are used. Huge capacities for a codigestion of agroindustrial residues (substrates) and wastewater sludge can be found in municipal digesters. As most of the food processing factories are indirect dischargers, the largest amount of the SS fraction in the wastewater is led to municipal wastewater treatment plants. Rarely, a connection between the SS concentrations in the influent and those in the effluent can be observed in conventional wastewater treatment. As a polishing step, filtration methods gain more and more importance with regard to suspended solids removal. PMID:11689029

  12. Biomass - chemicals

    SciTech Connect

    Kovaly, K.A.

    1982-08-01

    A host of industrial chemicals, specialty items, solvents, plastics, elastomers, fibers and films can be produced from agricultural crops, wood, paper mill wastes, food processing wastes, municipal waste and sewage. Existing chemical processes based on readily renewable plant materials are reviewed. These include ethanol and acetone-butanol fermentations, oilseed chemicals, furfural and cellulosics. (Refs. 16).

  13. Steam pressure disruption of municipal solid waste enhances anaerobic digestion kinetics and biogas yield.

    PubMed

    Liu, H W; Walter, H K; Vogt, G M; Vogt, H S; Holbein, B E

    2002-01-20

    Biomass waste, including municipal solid waste (MSW), contains lignocellulosic-containing fiber components that are not readily available as substrates for anaerobic digestion due to the physical shielding of cellulose imparted by the nondigestible lignin. Consequently, a substantial portion of the potentially available carbon is not converted to methane and the incompletely digested residues from anaerobic digestion generally require additional processing prior to their return to the environment. We investigated and developed steam pressure disruption as a treatment step to render lignocellulosic-rich biomass more digestible and as a means for increasing methane energy recovery. The rapid depressurization after steam heating (240 degrees C, 5 min.) of the nondigested residues following a 30-day primary digestion of MSW caused a visible disruption of fibers and release of soluble organic components. The disrupted material, after reinoculation, provided a rapid burst in methane production at rates double those observed in the initial digestion. This secondary digestion proceeded without a lag phase in gas production, provided approximately 40% additional methane yields, and was accompanied by a approximately 40% increase in volatile solids reduction. The secondary digestate was found to be enriched in lignin and significantly depleted in cellulose and hemi-cellulose components when compared to primary digestate. Thus, steam pressure disruption treatment rendered lignocellulosic substrates readily accessible to anaerobic digestion bacteria and improved both the kinetics of biogas production and the overall methane yield from MSW. Steam pressure disruption is central to a new anaerobic digestion process approach including sequential digestion stages and integrated energy recovery, to improve process yields, provide cogenerated energy for process needs, and to provide effective reuse and recycling of waste biomass materials. PMID:11753918

  14. Superheater Corrosion Produced By Biomass Fuels

    SciTech Connect

    Sharp, William; Singbeil, Douglas; Keiser, James R

    2012-01-01

    About 90% of the world's bioenergy is produced by burning renewable biomass fuels. Low-cost biomass fuels such as agricultural wastes typically contain more alkali metals and chlorine than conventional fuels. Although the efficiency of a boiler's steam cycle can be increased by raising its maximum steam temperature, alkali metals and chlorine released in biofuel boilers cause accelerated corrosion and fouling at high superheater steam temperatures. Most alloys that resist high temperature corrosion protect themselves with a surface layer of Cr{sub 2}O{sub 3}. However, this Cr{sub 2}O{sub 3} can be fluxed away by reactions that form alkali chromates or volatilized as chromic acid. This paper reviews recent research on superheater corrosion mechanisms and superheater alloy performance in biomass boilers firing black liquor, biomass fuels, blends of biomass with fossil fuels and municipal waste.

  15. Implementing District Energy Systems: Municipal Approaches To Overcoming Barriers

    NASA Astrophysics Data System (ADS)

    Simpson, Kevin George

    Climate change and energy security are issues facing municipalities throughout the world. Efficient, resilient, sustainable, community-based energy systems, such as district energy systems (DES), fuelled mostly by renewables, are an important tool for addressing both climate change and energy security at the municipal level. In spite of their benefits, DES are not widely adopted in Canada (CDEA, 2011). This is due to the complex nature of the barriers which project proponents face. This thesis examines the experience of the City of Prince George in adopting and implementing the Downtown DES. Using a case study methodology, data was collected through a review of relevant municipal documents and a series of semi-structured, open-ended interviews. A thematic analysis revealed unexpected barriers related to lack of adequate public consultation and negative perceptions regarding biomass as a fuel for the DES. These `lessons learned' were then developed into recommendations for other municipalities considering DES.

  16. Biomass Burning

    NASA Technical Reports Server (NTRS)

    Levine, Joel S.; Cofer, Wesley R., III; Pinto, Joseph P.

    1993-01-01

    Biomass burning may be the overwhelming regional or continental-scale source of methane (CH4) as in tropical Africa and a significant global source of CH4. Our best estimate of present methane emissions from biomass burning is about 51.9 Tg/yr, or 10% of the annual methane emissions to the atmosphere. Increased frequency of fires that may result as the Earth warms up may result in increases in this source of atmospheric methane.

  17. A comprehensive review of biomass resources and biofuel production in Nigeria: potential and prospects.

    PubMed

    Sokan-Adeaga, Adewale Allen; Ana, Godson R E E

    2015-01-01

    The quest for biofuels in Nigeria, no doubt, represents a legitimate ambition. This is so because the focus on biofuel production has assumed a global dimension, and the benefits that may accrue from such effort may turn out to be enormous if the preconditions are adequately satisfied. As a member of the global community, it has become exigent for Nigeria to explore other potential means of bettering her already impoverished economy. Biomass is the major energy source in Nigeria, contributing about 78% of Nigeria's primary energy supply. In this paper, a comprehensive review of the potential of biomass resources and biofuel production in Nigeria is given. The study adopted a desk review of existing literatures on major energy crops produced in Nigeria. A brief description of the current biofuel developmental activities in the country is also given. A variety of biomass resources exist in the country in large quantities with opportunities for expansion. Biomass resources considered include agricultural crops, agricultural crop residues, forestry resources, municipal solid waste, and animal waste. However, the prospects of achieving this giant stride appear not to be feasible in Nigeria. Although the focus on biofuel production may be a worthwhile endeavor in view of Nigeria's development woes, the paper argues that because Nigeria is yet to adequately satisfy the preconditions for such program, the effort may be designed to fail after all. To avoid this, the government must address key areas of concern such as food insecurity, environmental crisis, and blatant corruption in all quarters. It is concluded that given the large availability of biomass resources in Nigeria, there is immense potential for biofuel production from these biomass resources. With the very high potential for biofuel production, the governments as well as private investors are therefore encouraged to take practical steps toward investing in agriculture for the production of energy crops and the

  18. Fast pyrolysis of guayule biomass

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The sustainability of industrial crops like guayule, a domestic source of natural rubber, can be significantly enhanced by utilization of biomass residues. Guayule bagasse, a free-flowing solid, presents an attractive bioenergy feedstock due to its high energy content, small particle size, and high...

  19. BIOSEP: A NEW ETHANOL RECOVERY TECHNOLOGY FOR SMALL SCALE RURAL PRODUCTION OF ETHANOL FROM BIOMASS

    EPA Science Inventory

    Research activities on bioethanol have increased substantially as a result of the current concerns with energy security. Inexpensive biomass including forest residues, mill residues, agricultural residues, urban wood wastes and dedicated energy corps that exists in abundance acr...

  20. Urban tree residues: Results of the first national inventory

    SciTech Connect

    Whittier, J.; Rue, D.; Haase, S.

    1994-12-31

    The volume and characteristics of urban tree residues associated with tree pruning and other urban forestry activities have never been well documented, yet disposal of this residue is subject to increasing regulatory actions. The regulatory actions have a considerable impact on the activities of commercial, utility, and municipal tree care operations. This paper reports the results of the first national inventory of the volume and characteristics of urban tree residues. Residues are classified as follows: chips, logs, mixed wood, tops and brush, leaves, lawn clippings, and stumps. Generators of residues include the following: commercial tree care firms, municipal park and recreation departments, municipal tree care divisions, county tree care divisions, electric/telephone utility power line maintenance departments, nurseries, orchards, and landscapers. The national inventory assesses volume, characteristics, and disposal of the residues on both a regional basis as well as by size of metropolitan area. Finally, irregular residue inputs associated with natural disasters are discussed.

  1. YEAR 2 BIOMASS UTILIZATION

    SciTech Connect

    Christopher J. Zygarlicke

    2004-11-01

    This Energy & Environmental Research Center (EERC) Year 2 Biomass Utilization Final Technical Report summarizes multiple projects in biopower or bioenergy, transportation biofuels, and bioproducts. A prototype of a novel advanced power system, termed the high-temperature air furnace (HITAF), was tested for performance while converting biomass and coal blends to energy. Three biomass fuels--wood residue or hog fuel, corn stover, and switchgrass--and Wyoming subbituminous coal were acquired for combustion tests in the 3-million-Btu/hr system. Blend levels were 20% biomass--80% coal on a heat basis. Hog fuel was prepared for the upcoming combustion test by air-drying and processing through a hammer mill and screen. A K-Tron biomass feeder capable of operating in both gravimetric and volumetric modes was selected as the HITAF feed system. Two oxide dispersion-strengthened (ODS) alloys that would be used in the HITAF high-temperature heat exchanger were tested for slag corrosion rates. An alumina layer formed on one particular alloy, which was more corrosion-resistant than a chromia layer that formed on the other alloy. Research activities were completed in the development of an atmospheric pressure, fluidized-bed pyrolysis-type system called the controlled spontaneous reactor (CSR), which is used to process and condition biomass. Tree trimmings were physically and chemically altered by the CSR process, resulting in a fuel that was very suitable for feeding into a coal combustion or gasification system with little or no feed system modifications required. Experimental procedures were successful for producing hydrogen from biomass using the bacteria Thermotoga, a deep-ocean thermal vent organism. Analytical procedures for hydrogen were evaluated, a gas chromatography (GC) method was derived for measuring hydrogen yields, and adaptation culturing and protocols for mutagenesis were initiated to better develop strains that can use biomass cellulose. Fly ash derived from

  2. Field determination of biomass burning emission ratios and factors via open-path FTIR spectroscopy and fire radiative power assessment: headfire, backfire and residual smouldering combustion in African savannahs

    NASA Astrophysics Data System (ADS)

    Wooster, M. J.; Freeborn, P. H.; Archibald, S.; Oppenheimer, C.; Roberts, G. J.; Smith, T. E. L.; Govender, N.; Burton, M.; Palumbo, I.

    2011-02-01

    Biomass burning emissions factors are vital to quantifying trace gases releases from vegetation fires. Here we evaluate emissions factors for a series of savannah fires in Kruger National Park (KNP), South Africa using ground-based open path Fourier transform infrared (FTIR) spectroscopy and an infrared lamp separated by 150-250 m distance. Molecular abundances along the extended open path are retrieved using a spectral forward model coupled to a non-linear least squares fitting approach. We demonstrate derivation of trace gas column amounts for horizontal paths transecting the width of the advected plume, and find, for example, that CO mixing ratio changes of ~0.001 μmol mol-1 (~10 ppbv) can be detected across the relatively long optical paths used here. We focus analysis on five key compounds whose production is preferential during the pyrolysis (CH2O), flaming (CO2) and smoldering (CO, CH4, NH3) fire phases. We demonstrate that well constrained emissions ratios for these gases to both CO2 and CO can be derived for the backfire, headfire and residual smouldering combustion stages of these savannah fires, from which stage-specific emission factors can then be calculated. Headfires and backfires in general show similar emission ratios and emission factors, but those of the residual smouldering combustion stage can differ substantially (e.g., ERCH4/CO2 up to ~7 times higher than for the flaming stages). The timing of each fire stage was identified via airborne optical and thermal IR imagery and ground-observer reports, with the airborne IR imagery also used to derive estimates of fire radiative energy, thus allowing the relative amount of fuel burned in each stage to be calculated and the "fire averaged" emission ratios and emission factors to be determined. The derived "fire averaged" emission ratios are dominated by the headfire contribution, since the vast majority of the fuel is burned in this stage. Our fire averaged emission ratios and factors for CO2 and CH4

  3. Synthetic organic chemicals in earthworms from agriculture soil amended with municipal biosolids

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Introduction: Biosolids resulting from municipal wastewater treatment are known to contain residues of pharmaceuticals, personal care products (PPCPs) and other synthetic organic compounds. Many of these are contaminants of emerging concern for their potential endocrine disruption of fish and wildli...

  4. Solid-state anaerobic digestion of lignocellulosic biomass: Recent progress and perspectives.

    PubMed

    Ge, Xumeng; Xu, Fuqing; Li, Yebo

    2016-04-01

    Solid-state anaerobic digestion (SS-AD), which has gained popularity in the past decade as an environmentally friendly and cost-effective technology for extracting energy from various types of lignocellulosic biomass, is reviewed in this paper. According to data of biomass and methane yields of lignocellulosic feedstocks, crop residues have the highest methane production potential in the U.S., followed by the organic fraction of municipal solid waste (OFMSW), forestry waste, and energy crops. Methane yield and process stability of SS-AD can be improved by different strategies, such as co-digestion with other organic wastes, pretreatment of lignocellulosic biomass, and optimization of operating parameters. Different models for SS-AD have been developed, and insights into SS-AD processes have been obtained via microbial community analysis, microscope imaging, and tracer techniques. Future research and development in SS-AD, including feedstock identification and co-digestion, feedstock storage and pretreatment, SS-AD reactor development, digestate treatment, and value-added production, are recommended. PMID:26832395

  5. Biotechnology of biomass conversion

    SciTech Connect

    Wayman, M.; Parekh, S.R.

    1990-01-01

    This book covers: An introduction to biomass crops; The microbiology of fermentation processes; The production of ethanol from biomass crops, such as sugar cane and rubbers; The energy of biomass conversion; and The economics of biomass conversion.

  6. Biomass shock pretreatment

    DOEpatents

    Holtzapple, Mark T.; Madison, Maxine Jones; Ramirez, Rocio Sierra; Deimund, Mark A.; Falls, Matthew; Dunkelman, John J.

    2014-07-01

    Methods and apparatus for treating biomass that may include introducing a biomass to a chamber; exposing the biomass in the chamber to a shock event to produce a shocked biomass; and transferring the shocked biomass from the chamber. In some aspects, the method may include pretreating the biomass with a chemical before introducing the biomass to the chamber and/or after transferring shocked biomass from the chamber.

  7. Wind Power for Municipal Utilities

    SciTech Connect

    Not Available

    2002-10-01

    Wind Power for Municipal Utilities is a trifold brochure that strives to educate municipal utility owners and operators about the benefits of investing in wind power development. It provides examples of municipal utilities that have successful wind energy projects and supportive statements from industry members.

  8. Field determination of biomass burning emission ratios and factors via open-path FTIR spectroscopy and fire radiative power assessment: headfire, backfire and residual smouldering combustion in African savannahs

    NASA Astrophysics Data System (ADS)

    Wooster, M. J.; Freeborn, P. H.; Archibald, S.; Oppenheimer, C.; Roberts, G. J.; Smith, T. E. L.; Govender, N.; Burton, M.; Palumbo, I.

    2011-11-01

    Biomass burning emissions factors are vital to quantifying trace gas release from vegetation fires. Here we evaluate emissions factors for a series of savannah fires in Kruger National Park (KNP), South Africa using ground-based open path Fourier transform infrared (FTIR) spectroscopy and an IR source separated by 150-250 m distance. Molecular abundances along the extended open path are retrieved using a spectral forward model coupled to a non-linear least squares fitting approach. We demonstrate derivation of trace gas column amounts for horizontal paths transecting the width of the advected plume, and find for example that CO mixing ratio changes of ~0.01 μmol mol-1 [10 ppbv] can be detected across the relatively long optical paths used here. Though FTIR spectroscopy can detect dozens of different chemical species present in vegetation fire smoke, we focus our analysis on five key combustion products released preferentially during the pyrolysis (CH2O), flaming (CO2) and smoldering (CO, CH4, NH3) processes. We demonstrate that well constrained emissions ratios for these gases to both CO2 and CO can be derived for the backfire, headfire and residual smouldering combustion (RSC) stages of these savannah fires, from which stage-specific emission factors can then be calculated. Headfires and backfires often show similar emission ratios and emission factors, but those of the RSC stage can differ substantially. The timing of each fire stage was identified via airborne optical and thermal IR imagery and ground-observer reports, with the airborne IR imagery also used to derive estimates of fire radiative energy (FRE), allowing the relative amount of fuel burned in each stage to be calculated and "fire averaged" emission ratios and emission factors to be determined. These "fire averaged" metrics are dominated by the headfire contribution, since the FRE data indicate that the vast majority of the fuel is burned in this stage. Our fire averaged emission ratios and factors

  9. A-xylosidase enhanced conversion of plant biomass into fermentable sugars

    DOEpatents

    Walton, Jonathan D.; Scott-Craig, John S.; Borrusch, Melissa

    2016-08-02

    The invention relates to increasing the availability of fermentable sugars from plant biomass, such as glucose and xylose. As described herein, .alpha.-xylosidases can be employed with cellulases to enhance biomass conversion into free, fermentable sugar residues.

  10. Biofuel production by liquefaction of kenaf (Hibiscus cannabinus L.) biomass.

    PubMed

    Meryemoğlu, Bahar; Hasanoğlu, Arif; Irmak, Sibel; Erbatur, Oktay

    2014-01-01

    In this study, kenaf biomass, its dried hydrolysate residue (solid residue left after removing water from hydrolysate) and non-hydrolyzed kenaf residue (solid residue left after hydrolysis process) were liquefied at various temperatures. Hydrolysis of biomass was performed in subcritical water condition. The oil+gas yield of biomass materials increased as the temperature increased from 250 to 300°C. Increasing temperature to 350°C resulted in decreases in oil+gas contents for all biomass feeds studied. On the other hand, preasphaltene+asphaltene (PA+A) and char yields significantly decreased with increasing the process temperature. The use of carbon or activated carbon supported Ru catalyst in the process significantly decreased char and PA+A formations. Oils produced from liquefaction of kenaf, dried kenaf hydrolysate and non-hydrolyzed kenaf residue consist of fuel related components such as aromatic hydrocarbons, benzene and benzene derivative compounds, indane and trans/cis-decalin. PMID:24262837

  11. Residue management: Back to the roots

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Addressing the issues of climate change and sustainable biomass feedstocks have soil as a common theme. Managing crop residues is directly related to soil management. Understanding how soil and crop residue management interact provides insight on how to assure agricultural soil can serve as a carbon...

  12. Charging systems for municipal solid waste: experience from the Czech Republic.

    PubMed

    Sauer, Petr; Parízková, Libuse; Hadrabová, Alena

    2008-12-01

    The paper presents results of research into municipal waste treatment in the Czech Republic. Its special focus is on the impacts of various municipal solid waste charging systems on separating and recycling efforts of municipalities and households. The municipal solid waste charging systems are shortly described first, including the principles of the relevant Czech legislation. It shows that the Czech waste legislation provides space for implementing Pay-as-You-Throw (PAYT) models in the Czech Republic. The main results of representative surveys conducted by the authors within the EU PAYT project in 2003 in selected Czech municipalities and Prague households are shown. The survey confirmed that in municipalities that apply the PAYT charging system, citizens separate more waste and produce less residual waste. The survey data analysis has also shown which factors contributing to satisfactory waste separation are relevant and should be taken into the account when providing policy recommendations for introducing PAYT charging systems in other cities. PMID:18804364

  13. Life cycle assessment of disposal of residues from municipal solid waste incineration: recycling of bottom ash in road construction or landfilling in Denmark evaluated in the ROAD-RES model.

    PubMed

    Birgisdóttir, H; Bhander, G; Hauschild, M Z; Christensen, T H

    2007-01-01

    Two disposal methods for MSWI bottom ash were assessed in a new life cycle assessment (LCA) model for road construction and disposal of residues. The two scenarios evaluated in the model were: (i) landfilling of bottom ash in a coastal landfill in Denmark and (ii) recycling of bottom ash as subbase layer in an asphalted secondary road. The LCA included resource and energy consumption, and emissions associated with upgrading of bottom ash, transport, landfilling processes, incorporation of bottom ash in road, substitution of natural gravel as road construction material and leaching of heavy metals and salts from bottom ash in road as well as in landfill. Environmental impacts associated with emissions to air, fresh surface water, marine surface water, groundwater and soil were aggregated into 12 environmental impact categories: Global Warming, Photochemical Ozone Formation, Nutrient Enrichment, Acidification, Stratospheric Ozone Depletion, Human Toxicity via air/water/soil, Ecotoxicity in water/soil, and a new impact category, Stored Ecotoxicity to water/soil that accounts for the presence of heavy metals and very persistent organic compounds that in the long-term might leach. Leaching of heavy metals and salts from bottom ash was estimated from a series of laboratory leaching tests. For both scenarios, Ecotoxicity(water) was, when evaluated for the first 100 yr, the most important among the twelve impact categories involved in the assessment. Human Toxicity(soil) was also important, especially for the Road scenario. When the long-term leaching of heavy metals from bottom ash was evaluated, based on the total content of heavy metals in bottom ash, all impact categories became negligible compared to the potential Stored Ecotoxicity, which was two orders of magnitudes greater than Ecotoxicity(water). Copper was the constituent that gave the strongest contributions to the ecotoxicities. The most important resources consumed were clay as liner in landfill and the

  14. CALLA ENERGY BIOMASS COFIRING PROJECT

    SciTech Connect

    Unknown

    2003-07-01

    The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. GTI received supplemental authorization A002 from DOE for additional work to be performed under Phase I that will further extend the performance period until the end of February 2003. The additional scope of work is for GTI to develop the gasification characteristics of selected feedstock for the project. To conduct this work, GTI assembles an existing ''mini-bench'' unit to perform the gasification tests. The results of the test will be used to confirm or if necessary update the process design completed in Phase Task 1 During this Performance Period work efforts focused on conducting tests of biomass feedstock samples on the 2 inch mini-bench gasifier. The gasification tests were completed. The GTI U-GAS model was used to check some of the early test results against the model predictions. Additional modeling will be completed to further verify the model predictions and actual results.

  15. CALLA ENERGY BIOMASS COFIRING PROJECT

    SciTech Connect

    Francis S. Lau

    2003-09-01

    The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Natural gas and waste coal fines were evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. A design was developed for a cofiring combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures in a power generation boiler, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. Following the preliminary design, GTI evaluated the gasification characteristics of selected feedstocks for the project. To conduct this work, GTI assembled an existing ''mini-bench'' unit to perform the gasification tests. The results of the test were used to confirm the process design completed in Phase Task 1. As a result of the testing and modeling effort, the selected biomass feedstocks gasified very well, with a carbon conversion of over 98% and individual gas component yields that matched the RENUGAS{reg_sign} model. As a result of this work, the facility appears very attractive from a commercial standpoint. Similar facilities can be profitable if they have access to low cost fuels and have attractive wholesale or retail electrical rates for electricity sales. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. Phase II has not been approved for construction at this time.

  16. CALLA ENERGY BIOMASS COFIRING PROJECT

    SciTech Connect

    Unknown

    2002-12-31

    The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. GTI received supplemental authorization A002 from DOE for additional work to be performed under Phase I that will further extend the performance period until the end of February 2003. The additional scope of work is for GTI to develop the gasification characteristics of selected feedstock for the project. To conduct this work, GTI assembles an existing ''mini-bench'' unit to perform the gasification tests. The results of the test will be used to confirm or if necessary update the process design completed in Phase Task 1. During this Performance Period work efforts focused on conducting tests of biomass feedstock samples on the 2 inch mini-bench gasifier.

  17. Anaerobic digestion of municipal solid waste: Technical developments

    SciTech Connect

    Rivard, C.J.

    1996-01-01

    The anaerobic biogasification of organic wastes generates two useful products: a medium-Btu fuel gas and a compost-quality organic residue. Although commercial-scale digestion systems are used to treat municipal sewage wastes, the disposal of solid organic wastes, including municipal solid wastes (MSW), requires a more cost-efficient process. Modern biogasification systems employ high-rate, high-solids fermentation methods to improve process efficiency and reduce capital costs. The design criteria and development stages are discussed. These systems are also compared with conventional low-solids fermentation technology.

  18. CALLA ENERGY BIOMASS COFIRING PROJECT

    SciTech Connect

    Unknown

    2001-01-01

    This project is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to Design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications.

  19. Use of MRF residue as alternative fuel in cement production.

    PubMed

    Fyffe, John R; Breckel, Alex C; Townsend, Aaron K; Webber, Michael E

    2016-01-01

    Single-stream recycling has helped divert millions of metric tons of waste from landfills in the U.S., where recycling rates for municipal solid waste are currently over 30%. However, material recovery facilities (MRFs) that sort the municipal recycled streams do not recover 100% of the incoming material. Consequently, they landfill between 5% and 15% of total processed material as residue. This residue is primarily composed of high-energy-content non-recycled plastics and fiber. One possible end-of-life solution for these energy-dense materials is to process the residue into Solid Recovered Fuel (SRF) that can be used as an alternative energy resource capable of replacing or supplementing fuel resources such as coal, natural gas, petroleum coke, or biomass in many industrial and power production processes. This report addresses the energetic and environmental benefits and trade-offs of converting non-recycled post-consumer plastics and fiber derived from MRF residue streams into SRF for use in a cement kiln. An experimental test burn of 118 Mg of SRF in the precalciner portion of the cement kiln was conducted. The SRF was a blend of 60% MRF residue and 40% post-industrial waste products producing an estimated 60% plastic and 40% fibrous material mixture. The SRF was fed into the kiln at 0.9 Mg/h for 24h and then 1.8 Mg/h for the following 48 h. The emissions data recorded in the experimental test burn were used to perform the life-cycle analysis portion of this study. The analysis included the following steps: transportation, landfill, processing and fuel combustion at the cement kiln. The energy use and emissions at each step is tracked for the two cases: (1) The Reference Case, where MRF residue is disposed of in a landfill and the cement kiln uses coal as its fuel source, and (2) The SRF Case, in which MRF residue is processed into SRF and used to offset some portion of coal use at the cement kiln. The experimental test burn and accompanying analysis indicate

  20. Review of the Regional Biomass Energy Program: Technical projects

    SciTech Connect

    Lusk, P.

    1994-12-31

    This article summarizes technical projects of the regional Biomass Energy Program. Projects included are as follows: economic impact studies for renewable energy resources; alternative liquid fuels; Wood pellets fuels forum; residential fuel wood consumption; waste to energy decision-makers guide; fuel assessment for cogeneration facilities; municipal solid waste combustion characteristics.

  1. Physical availability of tree biomass for energy

    SciTech Connect

    Bones, J.T.; Wharton, E.H.

    1983-06-01

    The physical availability of tree biomass for energy is discussed. But first a profile of the US timberland is drawn. Land area, tree volume--by region, species group, and class of timber--and ownership of the land are calculated. Though the West clearly has the greatest volume, the North and the Southeast, with more hardwood, and considerably greater private ownership of land, are more important for wood energy. Wood manufacturing residues, logging residues, and byproducts of timber product harvesting are the major sources for tree biomass energy.

  2. Physical availability of tree biomass for energy

    SciTech Connect

    Bones, J.T.; Wharton, E.H.

    1983-06-01

    The physical availability of tree biomass for energy is discussed. But first a profile of the US timberland is drawn. Land area, tree volume--by region, species group, and class of timber--and ownership of the land are calculated. Though the west clearly has the greatest volume, the North and the Southeast, with more hardwood, and considerably greater private ownership of land, are more important for wood energy. Wood manufacturing residues, logging residues, and byproducts of timber product harvesting are the major sources for tree biomass energy.

  3. AL(0) in municipal waste incinerator ash

    NASA Astrophysics Data System (ADS)

    Stipp, S. L.; Ronsbo, J. G.; Zunic, T. B.; Christensen, T. H.

    2003-04-01

    Disposal of municipal waste is a challenge to society. Waste volume is substantially decreased by incineration but residual ash usually contains a number of toxic components which must be immobilised to insure environmental protection. One element, chromium, is mobile and toxic in its oxidised state as Cr(VI) but it can be reduced to Cr(III) and immobilised. Reduction can be promoted by ash treatment with Fe(0) or Fe(II), but recent evidence shows that at least some Cr(VI) is reduced spontaneously in the ash. Aspects of ash behaviour suggest metallic aluminium as the reducing agent, but no direct evidence of Al(0) has been found until now. We examined filter ash from an energy-producing, municipal-waste incinerator (Vest-forbrænding) near Copenhagen. X-ray diffraction (XRD) identified expected salts of Na, K and Ca such as halite, sylvite, calcite, anhydrite and gypsum as well as quartz, feldspar and some hematite. Wave-dispersive electron microprobe produced elemen-tal maps of the ash; Al-rich areas were analysed quantitatively by comparison with standards. We identified metallic Al particles, averaging 50 to 100 micrometers in di-ameter, often with a fractured, glassy border of aluminum oxide. The particles were porous, explaining fast Cr(VI) reduction and they contained thin exsolution lamellae of Al-alloys of Pb and Cu or Mn, Fe and Ag, which provide clues of the Al(0) origin in the waste. Sometimes Al(0) occurred inside glassy globes of Al2O3. Time-of-flight secondary ion mass spectroscopy (TOF-SIMS) and X-ray photoelectron spectroscopy (XPS) proved that surface Al concentrations on ash particles were below detection, confirming reactivity of the Al(0) bulk. The persistence of reduced Al through the highly oxidising combustion procedure comes as a surprise and is a benefit in the immobilisation of Cr(VI) from municipal-waste incineration residues.

  4. Agricultural policies and biomass fuels

    NASA Astrophysics Data System (ADS)

    Flaim, S.; Hertzmark, D.

    The potentials for biomass energy derived from agricultural products are examined. The production of energy feedstocks from grains is discussed for the example of ethanol production from grain, with consideration given to the beverage process and the wet milling process for obtaining fuel ethanol from grains and sugars, the nonfeedstock costs and energy requirements for ethanol production, the potential net energy gain from ethanol fermentation, the effect of ethanol fuel production on supplies of protein, oils and feed and of ethanol coproducts, net ethanol costs, and alternatives to corn as an ethanol feedstock. Biomass fuel production from crop residues is then considered; the constraints of soil fertility on crop residue removal for energy production are reviewed, residue yields with conventional practices and with reduced tillage are determined, technologies for the direct conversion of cellulose to ethanol and methanol are described, and potential markets for the products of these processes are identified. Implications for agricultural policy of ethanol production from grain and fuel and chemical production from crop residues are also discussed.

  5. Biomass torrefaction mill

    DOEpatents

    Sprouse, Kenneth M.

    2016-05-17

    A biomass torrefaction system includes a mill which receives a raw biomass feedstock and operates at temperatures above 400 F (204 C) to generate a dusty flue gas which contains a milled biomass product.

  6. Biomass Energy Research

    SciTech Connect

    Traylor, T.D.; Pitsenbarger, J.

    1996-03-01

    Biomass Energy Research announces on a bimonthly basis the current worldwide research and development (R&D) information available on biomass power systems, alternate feedstocks from biomass, and biofuels supply options.

  7. Moisture Effects on Nitrogen Availability in Municipal Biosolids from End-of-Life Municipal Lagoons.

    PubMed

    Jeke, Nicholson N; Zvomuya, Francis; Ross, Lisette

    2015-11-01

    Nitrogen (N) availability affects plant biomass yield and, hence, phytoextraction of contaminants during phytoremediation of end-of-life municipal lagoons. End-of-life lagoons are characterized by fluctuating moisture conditions, but the effects on biosolid N dynamics have not been adequately characterized. This 130-d laboratory incubation investigated effects of three moisture levels (30, 60, and 90% water-filled pore space [WFPS]) on N mineralization (N) in biosolids from a primary (PB) and a secondary (SB) municipal lagoon cell. Results showed a net increase in N with time at 60% WFPS and a net decrease at 90% WFPS in PB, while N at 30% WFPS did not change significantly. Moisture level and incubation time had no significant effect on N in SB. Nitrogen mineralization rate in PB followed three-half-order kinetics. Potentially mineralizable N (N) in PB was significantly greater at 60% WFPS (222 mg kg) than at 30% WFPS (30 mg kg), but rate constants did not differ significantly between the moisture levels. Nitrogen mineralization in SB followed first-order kinetics, with N significantly greater at 60% WFPS (68.4 mg kg) and 90% WFPS (94.1 mg kg) than at 30% WFPS (32 mg kg). Low N in SB suggests high-N-demanding plants may eventually have limited effectiveness to remediate biosolids in the secondary cell. While high N in PB would provide sufficient N to support high biomass yield, phytoextraction potential is reduced under dry and near-saturated conditions. These results have important implications on the management of moisture during phytoextraction of contaminants in end-of-life municipal lagoons. PMID:26641340

  8. Bioethanol production from dedicated energy crops and residues in Arkansas, USA

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Globally, one of the major technological goals is cost-effective lignocellulosic ethanol production from biomass feedstocks. Lignocellulosic biomass of five dedicated energy crops and two crops residues were tested for bioethanol production using cellulose solvent-based lignocellulose fractionation...

  9. My Biomass, Your Biomass, Our Solution

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The US is pursuing an array of renewable energy sources to reduce reliance on imported fossil fuels and reduce greenhouse gas emissions. Biomass energy and biomass ethanol are key components in the pursuit. The need for biomass feedstock to produce sufficient ethanol to meet any of the numerous stat...

  10. Municipal waste processing apparatus

    DOEpatents

    Mayberry, John L.

    1988-01-01

    Municipal waste materials are processed by crushing the materials so that pieces of noncombustible material are smaller than a selected size and pieces of combustible material are larger than the selected size. The crushed materials are placed on a vibrating mesh screen conveyor belt having openings which pass the smaller, noncombustible pieces of material, but do not pass the larger, combustible pieces of material. Pieces of material which become lodged in the openings of the conveyor belt may be removed by cylindrical deraggers or pressurized air. The crushed materials may be fed onto the conveyor belt by a vibrating feed plate which shakes the materials so that they tend to lie flat.

  11. Municipal waste processing apparatus

    DOEpatents

    Mayberry, John L.

    1989-01-01

    Municipal waste materials are processed by crushing the materials so that pieces of noncombustible material are smaller than a selected size and pieces of combustible material are larger than the selected size. The crushed materials are placed on a vibrating mesh screen conveyor belt having openings which pass the smaller, noncombustible pieces of material, but do not pass the larger, combustible pieces of material. Consecutive conveyors may be connected by an intermediate vibratory plate. An air knife can be used to further separate materials based on weight.

  12. Composted municipal waste effect on chosen properties of calcareous soil

    NASA Astrophysics Data System (ADS)

    Hamidpour, M.; Afyuni, M.; Khadivi, E.; Zorpas, A.; Inglezakis, V.

    2012-10-01

    A 3-year field study was conducted to assess effects of composted municipal waste on some properties, distribution of Zn, Cu in a calcareous soil and uptake of these metals by wheat. The treatments were 0, 25, 50 and 100 Mg ha-1 of municipal solidwastewhichwas applied in three consecutive years. The application of composted municipal waste increased the saturated hydraulic conductivity, the aggregate stability,the organic carbon content and electrical conductivity, whereas it slightly decreased the soil pH and bulk density. A significant increase in the concentration of Zn and Cu were observed with increasing number and rate of compost application. The distribution of Zn and Cu between the different fractions in untreated and treated soils showed that the majority of Zn and Cu were in the residual form. Finally, the levels of Zn and Cu were higher in grains of wheat grown in composttreated plots compared to that grown in the control plots.

  13. Health and safety implications of alternative energy technologies. I. Geothermal and biomass

    NASA Astrophysics Data System (ADS)

    Watson, A. P.; Etnier, E. L.

    1981-07-01

    An evaluation of potential occupational and public health aspects of geopressure, hydrothermal, hot dry rock, silviculture, crop and animal residues, fermentable plant products, municipal waste, and plantation energy technologies has been performed. Future development of these energy options in the United States will contain hazards that could easily be eliminated by safer equipment design and common-sense attention to operation and maintenance. Occupational exposure to hydrogen sulfide gas occurs near all geothermal sites and wherever organic matter decomposes anaerobically. Respiratory damage has occurred to laborers in geothermal fields, while farm workers have been fatally overcome when employed near agitating liquid manure systems. However, the most frequent and severe of reported injuries to geothermal workers is dermal exposure to caustic sludges produced by H2S abatement systems. Principal health and safety considerations of biomass pathways are directly related to the diffuse nature of solar energy fixation by photosynthesis and subsequent transfer to animal food chains. Since the potential fuel is in an unconcentrated form, cultivation, harvest, and transport are necessarily laborintensive. Thus, a significant potential for occupational injuries and fatalities exists. Of all biomass systems evaluated, direct burning of solid fuels presents the greatest public health risk. Data are presented to characterize the population at risk and the frequency and severity of injuries.

  14. Biomass analyses for four areas in the Tennessee Valley Authority

    SciTech Connect

    Perry, J.D.

    1985-04-01

    Analyses for four biomass procurement areas in the Tennessee Valley are presented. The Marlow and Perryville, Tennessee, sites can provide 38,000 dry tons of industrial residue annually. Mulberry Creek, Alabama, and Watts Bar, Tennessee, can annually provide 330,000 dry tons of industrial residue and/or forest biomass. Methanol can be produced at the Perryville and Marlow sites and ethanol at Mulberry Creek and Watts Bar. 5 figs., 9 tabs.

  15. Hydrothermal Liquefaction of Biomass

    SciTech Connect

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international collaboration with

  16. Advanced gasification-based biomass power generation

    SciTech Connect

    Williams, R.H.; Larson, E.D.

    1993-12-31

    A promising strategy for modernizing bioenergy is the production of electricity or the cogeneration of electricity and heat using gasified biomass with advanced conversion technologies. Major advances that have been made in coal gasification technology, to marry the gas turbine to coal, are readily adaptable to biomass applications. Integrating biomass gasifiers with aeroderivative gas turbines in particular makes it possible to achieve high efficiencies and low unit capital costs at the modest scales required for bioenergy systems. Electricity produced with biomass-integrated gasifier/gas turbine (BIG/GT) power systems not only offers major environmental benefits but also would be competitive with electricity produced from fossil fuels and nuclear energy under a wide range of circumstances. Initial applications will be with biomass residues generated in the sugarcane, pulp and paper, and other agro- and forest-product industries. Eventually, biomass grown for energy purposes on dedicated energy farms will also be used to fuel these gas turbine systems. Continuing improvements in jet engine and biomass gasification technologies will lead to further gains in the performance of BIG/GT systems over the next couple of decades. Fuel cells operated on gasified biomass offer the promise of even higher performance levels in the period beyond the turn of the century. 79 refs., 21 figs., 11 tabs.

  17. Biomass Estimates for Five Western States.

    SciTech Connect

    Howard, James O.

    1990-10-01

    The purpose of this report is to describe the woody biomass resource within US Department of Energy's Pacific Northwest and Alaska Regional Biomass Program, comprised of southeast Alaska, Idaho, Montana, Oregon, and Washington. In addition to the regional forest biomass assessment, information will be presented for logging residue, which represents current energy conversion opportunities. The information presented in the report is based on data and relationships already published. Regionally applicable biomass equations are generally not available for species occurring in the west. Because of this, a number of assumptions were made to develop whole-tree biomass tables. These assumptions are required to link algorithms from biomass studies to regional timber inventory data published by the Forest Inventory and Analysis Research Units (FIA), of the Pacific Northwest and Intermountain Research Stations, US Forest Service. These sources and assumptions will be identified later in this report. Tabular biomass data will be presented for 11 resource areas, identified in the FS inventory publications. This report does not include information for the vast area encompassing interior Alaska. Total tress biomass as defined in the report refers to the above ground weight of a tree above a 1.0 foot stump, and exclusive of foliage. A glossary is included that defines specific terms as used in the report. Inventory terminology is derived from forest inventory reports from Forest Inventory and Analysis units at the Intermountain and Pacific Northwest Research Stations. 39 refs., 15 figs., 23 tabs.

  18. Corn Stover to Sustain Organic Carbon Further Constrains Biomass Supply

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Sustainable aboveground crop biomass harvest estimates for cellulosic ethanol production, to date, have been limited by the need for stover or residue to control erosion. Recently, estimates of the amount of crop biomass needed to maintain soil carbon, which is responsible for favorable soil propert...

  19. Quantifying Total and Sustainable Agricultural Biomass Resources in South Dakota

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Conversion of biomass is considered the next major advance in biorenewable fuels, energy, and products. Wholesale conversion to biomass utilization could result in removal of current crop residues from agricultural fields or even implementation of different crops and cropping strategies (i.e., swit...

  20. Energy Management in Municipal Buildings.

    ERIC Educational Resources Information Center

    Massachusetts State Dept. of Community Affairs, Boston. Energy Conservation Project.

    This manual is written for the manager or supervisor responsible for instituting an energy management program for municipal buildings. An introduction discusses the management issues facing municipal government in dealing with the need to reduce energy consumption. The guide reviews methods for central coordination of activity to ensure that…

  1. Organic fraction of municipal solid waste from mechanical selection: biological stabilization and recovery options.

    PubMed

    Cesaro, Alessandra; Russo, Lara; Farina, Anna; Belgiorno, Vincenzo

    2016-01-01

    Although current trends address towards prevention strategies, the organic fraction of municipal solid waste is greatly produced, especially in high-income contexts. Its recovery-oriented collection is a common practice, but a relevant portion of the biodegradable waste is not source selected. Mechanical and biological treatments (MBT) are the most common option to sort and stabilize the biodegradable matter ending in residual waste stream. Following the changes of the framework around waste management, this paper aimed at analyzing the quality of the mechanically selected organic waste produced in MBT plants, in order to discuss its recovery options. The material performance was obtained by its composition as well as by its main chemical and physical parameters; biological stability was also assessed by both aerobic and anaerobic methods. On this basis, the effectiveness of an aerobic biostabilization process was assessed at pilot scale. After 21 days of treatment, results proved that the biomass had reached an acceptable biostabilization level, with a potential Dynamic Respirometric Index (DRIP) value lower than the limit required for its use as daily or final landfill cover material. However, the final stabilization level was seen to be influenced by scaling factors and the 21 days of treatment turned to be not so adequate when applied in the existing full-scale facility. PMID:26377969

  2. CALLA ENERGY BIOMASS COFIRING PROJECT

    SciTech Connect

    Unknown

    2003-03-31

    The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. GTI received supplemental authorization A002 from DOE for additional work to be performed under Phase I that will further extend the performance period until the end of February 2003. The additional scope of work is for GTI to develop the gasification characteristics of selected feedstock for the project. To conduct this work, GTI assembles an existing ''mini-bench'' unit to perform the gasification tests. The results of the test will be used to confirm or if necessary update the process design completed in Phase Task 1 During this Performance Period work efforts focused on conducting tests of biomass feedstock samples on the 2 inch mini-bench gasifier. GTI determined that the mini-bench feed system could not handle ''raw'' biomass samples. These clogged the fuel feed screw. GTI determined that palletized samples would operate well in the mini-bench unit. Two sources of this material were identified that had

  3. Biomass treatment method

    DOEpatents

    Friend, Julie; Elander, Richard T.; Tucker, III; Melvin P.; Lyons, Robert C.

    2010-10-26

    A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.

  4. Balancing crop biomass for bioenergy and conservation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Soil and water conservation benefits must be included in biomass assessments to prevent long-term environmental damage as the nation addresses short-term energy problems. Therefore, to develop an environmentally and economically sound bioenergy economy, the tradeoff between managing crop residues to...

  5. Producing biomass from sorghum by sudangrass hybrids

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biomass production systems for energy development that utilize cellulosic feedstocks from low-input systems such as Conservation Reserve Program acreage and agricultural residues available from row crop farming have been proposed and evaluated in numerous ways. In addition, dedicated cropping syst...

  6. Developing enzyme systems for biomass deconstruction

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The conversion of agricultural crops and residues to fermentable feedstock for the production of bioethanol represents a major source of renewable energy. The key to economically viable and effective biomass conversion includes the development of novel enzymes and enzyme systems to achieve total de...

  7. Lignocellulosic biomass conversion to ethanol by Saccharomyces

    Technology Transfer Automated Retrieval System (TEKTRAN)

    As interest in alternative energy sources rises, the concept of agriculture as an energy producer has become increasingly attractive (Outlaw et al. 2005). Renewable biomass, including lignocellulosic materials and agricultural residues, are low-cost materials for bioethanol production (Bothast and ...

  8. Biomass-based polyols through oxypropylation reaction.

    PubMed

    Aniceto, José P S; Portugal, Inês; Silva, Carlos M

    2012-08-01

    Biomass residues are a potential renewable source for the sustainable production of chemicals, materials, fuels, and energy embodying the so-called biorefinery concept. In this context, agro-forestry and agro-food industry by-products have attracted considerable interest of researchers in academia and industry as a renewable source of polymeric materials. The research developed to date on the valorization of biomass residues by converting them into polyols through oxypropylation is the subject of this review. These bio-based polyols exhibit properties similar to their petrochemical counterparts and, as such, can be used with economical advantage in the production of polyurethanes. The operating conditions of the oxypropylation reaction depend on the biomass and on the desired polyol properties. The discussion of their influence and the economic viability of the process are also presented. PMID:22807440

  9. A sustainable woody biomass biorefinery.

    PubMed

    Liu, Shijie; Lu, Houfang; Hu, Ruofei; Shupe, Alan; Lin, Lu; Liang, Bin

    2012-01-01

    Woody biomass is renewable only if sustainable production is imposed. An optimum and sustainable biomass stand production rate is found to be one with the incremental growth rate at harvest equal to the average overall growth rate. Utilization of woody biomass leads to a sustainable economy. Woody biomass is comprised of at least four components: extractives, hemicellulose, lignin and cellulose. While extractives and hemicellulose are least resistant to chemical and thermal degradation, cellulose is most resistant to chemical, thermal, and biological attack. The difference or heterogeneity in reactivity leads to the recalcitrance of woody biomass at conversion. A selection of processes is presented together as a biorefinery based on incremental sequential deconstruction, fractionation/conversion of woody biomass to achieve efficient separation of major components. A preference is given to a biorefinery absent of pretreatment and detoxification process that produce waste byproducts. While numerous biorefinery approaches are known, a focused review on the integrated studies of water-based biorefinery processes is presented. Hot-water extraction is the first process step to extract value from woody biomass while improving the quality of the remaining solid material. This first step removes extractives and hemicellulose fractions from woody biomass. While extractives and hemicellulose are largely removed in the extraction liquor, cellulose and lignin largely remain in the residual woody structure. Xylo-oligomers, aromatics and acetic acid in the hardwood extract are the major components having the greatest potential value for development. Higher temperature and longer residence time lead to higher mass removal. While high temperature (>200°C) can lead to nearly total dissolution, the amount of sugars present in the extraction liquor decreases rapidly with temperature. Dilute acid hydrolysis of concentrated wood extracts renders the wood extract with monomeric sugars

  10. Assessment of Biomass Resources in Afghanistan

    SciTech Connect

    Milbrandt, A.; Overend, R.

    2011-01-01

    Afghanistan is facing many challenges on its path of reconstruction and development. Among all its pressing needs, the country would benefit from the development and implementation of an energy strategy. In addition to conventional energy sources, the Afghan government is considering alternative options such as energy derived from renewable resources (wind, solar, biomass, geothermal). Biomass energy is derived from a variety of sources -- plant-based material and residues -- and can be used in various conversion processes to yield power, heat, steam, and fuel. This study provides policymakers and industry developers with information on the biomass resource potential in Afghanistan for power/heat generation and transportation fuels production. To achieve this goal, the study estimates the current biomass resources and evaluates the potential resources that could be used for energy purposes.

  11. Biomass Thermochemical Conversion Program: 1986 annual report

    SciTech Connect

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1987-01-01

    Wood and crop residues constitute a vast majority of the biomass feedstocks available for conversion, and thermochemical processes are well suited for conversion of these materials. Thermochemical conversion processes can generate a variety of products such as gasoline hydrocarbon fuels, natural gas substitutes, or heat energy for electric power generation. The US Department of Energy is sponsoring research on biomass conversion technologies through its Biomass Thermochemical Conversion Program. Pacific Northwest Laboratory has been designated the Technical Field Management Office for the Biomass Thermochemical Conversion Program with overall responsibility for the Program. This report briefly describes the Thermochemical Conversion Program structure and summarizes the activities and major accomplishments during fiscal year 1986. 88 refs., 31 figs., 5 tabs.

  12. New field-based agricultural biomass burning trace gas, PM2.5, and black carbon emission ratios and factors measured in situ at crop residue fires in Eastern China

    NASA Astrophysics Data System (ADS)

    Zhang, Tianran; Wooster, Martin J.; Green, David C.; Main, Bruce

    2015-11-01

    Despite policy attempts to limit or prevent agricultural burning, its use to remove crop residues either immediately after harvest (e.g. field burning of wheat stubble) or after subsequent crop processing (e.g. "bonfires" of rice straw and rapeseed residues) appears to remain widespread across parts of China. Emission factors for these types of small but highly numerous fire are therefore required to fully assess their impact on atmospheric composition and air pollution. Here we describe the design and deployment of a new smoke measurement system for the close-range sampling of key gases and particles within smoke from crop residue fires, using it to assess instantaneous mixing ratios of CO and CO2 and mass concentrations of black carbon (BC) and PM2.5 from wheat stubble, rice straw, and rapeseed residue fires. Using data of our new smoke sampling system, we find a strong linear correlation between the PM2.5 mass and BC, with very high PM2.5 to BC emission ratios found in the smouldering phase (up to 80.7 mg m-3.(mg m-3)-1) compared to the flaming phase (2.0 mg m-3.(mg m-3)-1). We conclude that the contribution of BC to PM2.5 mass was as high as 50% in the flaming phase of some burns, whilst during smouldering it sometimes decreased to little over one percent. A linear mixing model is used to quantify the relative contribution of each combustion phase to the overall measured smoke composition, and we find that flaming combustion dominated the total emission of most species assessed. Using time series of trace gas concentrations from different fire cases, we calculated 'fire integrated' trace gas emission factors (EFs) for wheat, rice and rapeseed residue burns as 1739 ± 19 g kg-1, 1761 ± 30 g kg-1and 1704 ± 27 g kg-1 respectively for CO2, and 60 ± 12 g kg-1, 47 ± 19 g kg-1 and 82 ± 17 g kg-1 respectively for CO. Where comparisons were possible, our EFs agreed well with those derived via a simultaneously-deployed open path Fourier transform infrared (OP

  13. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry

    SciTech Connect

    Downing, Mark; Eaton, Laurence M; Graham, Robin Lambert; Langholtz, Matthew H; Perlack, Robert D; Turhollow Jr, Anthony F; Stokes, Bryce; Brandt, Craig C

    2011-08-01

    The report, Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply (generally referred to as the Billion-Ton Study or 2005 BTS), was an estimate of 'potential' biomass based on numerous assumptions about current and future inventory, production capacity, availability, and technology. The analysis was made to determine if conterminous U.S. agriculture and forestry resources had the capability to produce at least one billion dry tons of sustainable biomass annually to displace 30% or more of the nation's present petroleum consumption. An effort was made to use conservative estimates to assure confidence in having sufficient supply to reach the goal. The potential biomass was projected to be reasonably available around mid-century when large-scale biorefineries are likely to exist. The study emphasized primary sources of forest- and agriculture-derived biomass, such as logging residues, fuel treatment thinnings, crop residues, and perennially grown grasses and trees. These primary sources have the greatest potential to supply large, reliable, and sustainable quantities of biomass. While the primary sources were emphasized, estimates of secondary residue and tertiary waste resources of biomass were also provided. The original Billion-Ton Resource Assessment, published in 2005, was divided into two parts-forest-derived resources and agriculture-derived resources. The forest resources included residues produced during the harvesting of merchantable timber, forest residues, and small-diameter trees that could become available through initiatives to reduce fire hazards and improve forest health; forest residues from land conversion; fuelwood extracted from forests; residues generated at primary forest product processing mills; and urban wood wastes, municipal solid wastes (MSW), and construction and demolition (C&D) debris. For these forest resources, only residues, wastes, and small-diameter trees were

  14. Cob biomass production in the western corn belt

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Corn residue is viewed as an abundant, inexpensive source of biomass that can be removed from fields for ethanol production without deleterious production or environmental effects if proper management is used according to some recent publications. Other publications indicate that corn residue needs ...

  15. Crop residues

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Crop residues [e.g., corn (Zea mays) stover and small grain straw] are sometimes excluded when discussing cellulosic energy crops per se, but because of the vast area upon which they are grown and their current role in the development of cellulosic energy systems. This chapter focuses on current cor...

  16. Mechanical durability and combustion characteristics of pellets from biomass blends.

    PubMed

    Gil, M V; Oulego, P; Casal, M D; Pevida, C; Pis, J J; Rubiera, F

    2010-11-01

    Biofuel pellets were prepared from biomass (pine, chestnut and eucalyptus sawdust, cellulose residue, coffee husks and grape waste) and from blends of biomass with two coals (bituminous and semianthracite). Their mechanical properties and combustion behaviour were studied by means of an abrasion index and thermogravimetric analysis (TGA), respectively, in order to select the best raw materials available in the area of study for pellet production. Chestnut and pine sawdust pellets exhibited the highest durability, whereas grape waste and coffee husks pellets were the least durable. Blends of pine sawdust with 10-30% chestnut sawdust were the best for pellet production. Blends of cellulose residue and coals (<20%) with chestnut and pine sawdusts did not decrease pellet durability. The biomass/biomass blends presented combustion profiles similar to those of the individual raw materials. The addition of coal to the biomass in low amounts did not affect the thermal characteristics of the blends. PMID:20605093

  17. DESIGN MANUAL: MUNICIPAL WASTEWATER DISINFECTION

    EPA Science Inventory

    This manual provides a comprehensive source of information to be used in the design of disinfection facilities for municipal wastewater treatment plants. he manual includes design information on halogenation/dehalogenation, ozonation, and ultraviolet radiation. he manual presents...

  18. MUNICIPAL WASTEWATER SLUDGE COMBUSTION TECHNOLOGY

    EPA Science Inventory

    The publication describes and evaluates the various municipal sludge combustion systems. It also emphasizes the necessity for considering and evaluating the costs involved in the total sludge management train, including dewatering, combustion, air pollution control, and ash dispo...

  19. Enduring values of municipal utilities

    SciTech Connect

    Telly, C.S.; Grove, J.F.

    1981-05-01

    The value of municipal utilities is assessed in terms of their social responsibility, the political responsiveness of the owners, and pricing policy - issues which conflict with the traditional concept of corporate responsibility to the shareholder and which reveal a growing demand for accountability. Although municipal utilities are only a small part of the economic, legal, and political setting, they contribute as a small, locally-controlled natural monopoly to the American goals of democracy and self-determination. (DCK)

  20. Optimal configuration and combination of multiple lignocellulosic biomass feedstocks delivery to a biorefinery.

    PubMed

    Sultana, Arifa; Kumar, Amit

    2011-11-01

    Biomass availability and transportation are major challenges in establishing a large-scale biorefinery. The objective of this study was to assess the delivery cost of different combinations of multiple forms of lignocellulosic feedstocks including agricultural and woody biomass. Three types of biomass i.e., wheat straw, corn stover and forest biomass were considered in different forms such as loose biomass, bales/bundles, chopped/chipped and pellets. It was found that the delivery cost of a combination of woody and agricultural biomass feedstocks is lower than that for a single type of biomass. The delivery of agricultural residues as bales and woody biomass as chips is an economically attractive option with optimal combination of 30% bales and 70% wood chips to a biorefinery of capacity 5000 dry tonnes per day. The anticipated traffic congestions resulting from biomass supply to a large facility could be significantly reduced by increasing the density of biomass. PMID:21917448

  1. Assessment of biomass open burning emissions in Indonesia and potential climate forcing impact

    NASA Astrophysics Data System (ADS)

    Permadi, Didin Agustian; Kim Oanh, Nguyen Thi

    2013-10-01

    This paper presents an emission inventory (EI) for biomass open burning (OB) sources including forest, agro-residue and municipal solid waste (MSW) in Indonesia for year 2007. The EI covered toxic air pollutants and greenhouse gases (GHGs) and was presented as annual and monthly average for every district, and further on a grid of 0.25° × 0.25°. A rigorous analysis of activity data and emission factor ranges was done to produce the low, best and high emission estimates for each species. Development of EI methodology for MSW OB which, to our best knowledge, has not been presented in detail in the literature was a focus of this paper. The best estimates of biomass OB emission of toxic air pollutants for the country, in Gg, were: 9.6 SO2; 98 NOx; 7411 CO; 335 NMVOC; 162 NH3; 439 PM10; 357 PM2.5; 24 BC; and 147 OC. The best emission estimates of GHGs, in Gg, were: 401 CH4, 57,247 CO2; and 3.6 N2O. The low and high values of the emission estimates for different species were found to range from -86% to +260% of the corresponding best estimates. Crop residue OB contributed more than 80% of the total biomass OB emissions, followed by forest fire of 2-12% (not including peat soil fire emission) and MSW (1-8%). An inter-annual active fires count for Indonesia showed relatively low values in 2007 which may be attributed to the high rainfall intensity under the influence of La Niña climate pattern in the year. Total estimated net climate forcing from OB in Indonesia was 110 (20 year horizon) and 73 (100 year horizon) Tg CO2 equivalents which is around 0.9-1.1% of that reported for the global biomass OB for both time horizons. The spatial distribution showed higher emissions in large urban areas in Java and Sumatra Island, while the monthly emissions indicated higher values during the dry months of August-October.

  2. Municipal landfill leachate management

    SciTech Connect

    Kusterer, T.; Willson, R.; Bruce, S.C.; Tissue, E. Lou, P.J.

    1998-12-31

    From 1995 to 1997, the Montgomery County Leachate Pretreatment Facility (MCLPF) has successfully pretreated in excess of 18,000,000 gallons of leachate generated by the county`s municipal solid waste landfill. The collection system directs leachate from the original landfill. The collection system directs leachate from the original landfill, the new lined section, and the ash cell to the leachate pump station. The leachate, prior to being pumped to the leachate pretreatment system, is equalized in two storage lagoons with a combined capacity of more than 5,000,000 gallons. The innovative leachate treatment system, incorporating a biological reactor system equipped with a submerged fixed-film reactor using a patented Matrix Biological Film (MBF) media, continues to provide excellent pretreatment results for the leachate generated at the Oaks Landfill in Montgomery County, Maryland. In 1995 and 1996, the system responded to the substantial challenges imposed by the changing characteristics of the material being landfilled and by the significant amounts of incinerator ash, received in 1995 from the county`s resource recovery facility (RRF), which influenced the influent leachate characteristics.

  3. Photovoltaics for municipal planners

    SciTech Connect

    Not Available

    1993-04-01

    This booklet is intended for city and county government personnel, as well as community organizations, who deal with supplying, regulating, or recommending electric power resources. Specifically, this document deals with photovoltaic (PV) power, or power from solar cells, which is currently the most cost-effective energy source for electricity requirements that are relatively small, located in isolated areas, or difficult to serve with conventional technology. Recently, PV has been documented to be more cost-effective than conventional alternatives (such as line extensions or engine generators) in dozens of applications within the service territories of electric, gas, and communications utilities. Here, we document numerous cost-effective urban applications, chosen by planners and utilities because they were the most cost-effective option or because they were appropriate for environmental or logistical reasons. These applications occur within various municipal departments, including utility, parks and recreation, traffic engineering, transportation, and planning, and they include lighting applications, communications equipment, corrosion protection, irrigation control equipment, remote monitoring, and even portable power supplies for emergency situations.

  4. Municipal water consumption forecast accuracy

    NASA Astrophysics Data System (ADS)

    Fullerton, Thomas M.; Molina, Angel L.

    2010-06-01

    Municipal water consumption planning is an active area of research because of infrastructure construction and maintenance costs, supply constraints, and water quality assurance. In spite of that, relatively few water forecast accuracy assessments have been completed to date, although some internal documentation may exist as part of the proprietary "grey literature." This study utilizes a data set of previously published municipal consumption forecasts to partially fill that gap in the empirical water economics literature. Previously published municipal water econometric forecasts for three public utilities are examined for predictive accuracy against two random walk benchmarks commonly used in regional analyses. Descriptive metrics used to quantify forecast accuracy include root-mean-square error and Theil inequality statistics. Formal statistical assessments are completed using four-pronged error differential regression F tests. Similar to studies for other metropolitan econometric forecasts in areas with similar demographic and labor market characteristics, model predictive performances for the municipal water aggregates in this effort are mixed for each of the municipalities included in the sample. Given the competitiveness of the benchmarks, analysts should employ care when utilizing econometric forecasts of municipal water consumption for planning purposes, comparing them to recent historical observations and trends to insure reliability. Comparative results using data from other markets, including regions facing differing labor and demographic conditions, would also be helpful.

  5. Biomass for Electricity Generation

    EIA Publications

    2002-01-01

    This paper examines issues affecting the uses of biomass for electricity generation. The methodology used in the National Energy Modeling System to account for various types of biomass is discussed, and the underlying assumptions are explained.

  6. Regional assessment of nonforestry-related biomass resources

    SciTech Connect

    Not Available

    1989-12-01

    The southeastern region of the United States can produce approximately the annual equivalent of 897 trillion Btu of energy from nonforestry wastes such as agriculture crop residues, animal excreta from confined feedlots, craps that could be grown on agricultural set-aside land, municipal solid wastes, and sewage sludge. This study developed county-level data for these resources.

  7. Biomass and nutrient distributions in central Oregon second-growth ponderosa pine ecosystems. Forest Service research paper

    SciTech Connect

    Little, S.N.; Shainsky, L.J.

    1995-03-01

    We investigated the distributioin of biomass and nurtrients in second-growth ponderosa pine (Pinus ponderosa Dougl. ex Laws.) ecosystems in central Oregon. Destructive sampling of aboveground and belowground tree biomass was carried out at six sites in the Deschutes National Forest; three of these sites also were intensively sampled for biomass and nutrient concentrations of the soil, forest floor, residue, and shrub components. Tree biomass equations were developed that related component biomass to diameter at breast height and total tree height.

  8. Pretreated densified biomass products

    SciTech Connect

    Dale, Bruce E; Ritchie, Bryan; Marshall, Derek

    2014-03-18

    A product comprising at least one densified biomass particulate of a given mass having no added binder and comprised of a plurality of lignin-coated plant biomass fibers is provided, wherein the at least one densified biomass particulate has an intrinsic density substantially equivalent to a binder-containing densified biomass particulate of the same given mass and h a substantially smooth, non-flakey outer surface. Methods for using and making the product are also described.

  9. EERC Center for Biomass Utilization 2005

    SciTech Connect

    Zygarlicke, C J; Schmidt, D D; Olson, E S; Leroux, K M; Wocken, C A; Aulich, T A; WIlliams, K D

    2008-07-28

    Biomass utilization is one solution to our nation’s addiction to oil and fossil fuels. What is needed now is applied fundamental research that will cause economic technology development for the utilization of the diverse biomass resources in the United States. This Energy & Environmental Research Center (EERC) applied fundamental research project contributes to the development of economical biomass utilization for energy, transportation fuels, and marketable chemicals using biorefinery methods that include thermochemical and fermentation processes. The fundamental and basic applied research supports the broad scientific objectives of the U.S. Department of Energy (DOE) Biomass Program, especially in the area of developing alternative renewable biofuels, sustainable bioenergy, technologies that reduce greenhouse gas emissions, and environmental remediation. Its deliverables include 1) identifying and understanding environmental consequences of energy production from biomass, including the impacts on greenhouse gas production, carbon emission abatement, and utilization of waste biomass residues and 2) developing biology-based solutions that address DOE and national needs related to waste cleanup, hydrogen production from renewable biomass, biological and chemical processes for energy and fuel production, and environmental stewardship. This project serves the public purpose of encouraging good environmental stewardship by developing biomass-refining technologies that can dramatically increase domestic energy production to counter current trends of rising dependence upon petroleum imports. Decreasing the nation’s reliance on foreign oil and energy will enhance national security, the economy of rural communities, and future competitiveness. Although renewable energy has many forms, such as wind and solar, biomass is the only renewable energy source that can be governed through agricultural methods and that has an energy density that can realistically compete with

  10. BIOMASS DRYING TECHNOLOGIES

    EPA Science Inventory

    The report examines the technologies used for drying of biomass and the energy requirements of biomass dryers. Biomass drying processes, drying methods, and the conventional types of dryers are surveyed generally. Drying methods and dryer studies using superheated steam as the d...

  11. Small Modular Biomass Systems

    SciTech Connect

    2002-12-01

    This fact sheet provides information about modular biomass systems. Small modular biomass systems can help supply electricity to rural areas, businesses, and the billions of people who live without power worldwide. These systems use locally available biomass fuels such as wood, crop waste, animal manures, and landfill gas.

  12. Biomass Program Biopower Factsheet

    SciTech Connect

    2010-03-01

    Generating electricity and thermal energy from biomass has the potential to help meet national goals for renewable energy. The forest products industry has used biomass for power and heat for many decades, yet widespread use of biomass to supply electricity to the U.S. power grid and other applications is relatively recent.

  13. Irradiation enhancement of biomass conversion

    NASA Astrophysics Data System (ADS)

    Smith, G. S.; Kiesling, H. E.; Galyean, M. L.; Bader, J. R.

    The vast supply of cellulosic agricultural residues and industrial by-products that is produced each year is a prospective resource of biomass suitable for conversion to useful products such as feedstock for the chemicals industry and feedstuffs for the livestock industry. Conversions of such biomass is poor at present, and utilization is inefficient, because of physio-chemical barriers to biological degradation and (or) anti-quality components such as toxicants that restrict biological usages. Improvements in biodegradability of ligno-cellulosic materials have been accomplished by gamma-ray and electron-beam irradiation at intermediate dosage (˜ 50 Mrad; .5 MGy); but applications of the technology have been hampered by questionable interpretations of results. Recent research with organic wastes such as sewage sludge and straw suggests opportunity for important applications of irradiation technology in enhancement of biomass conversion. Data from experiments using irradiated straw as feed for ruminants are presented and discussed in relation to research on prospective usage of sewage products as feed for ruminants. Findings are discussed in regard to prospective applications in industrial fermentation processes. Possible usage of irradiation technology for destruction of toxicants in exotic plants is considered in regard to prospective new feedstuffs.

  14. Engineered plant biomass feedstock particles

    DOEpatents

    Dooley, James H.; Lanning, David N.; Broderick, Thomas F.

    2012-04-17

    A new class of plant biomass feedstock particles characterized by consistent piece size and shape uniformity, high skeletal surface area, and good flow properties. The particles of plant biomass material having fibers aligned in a grain are characterized by a length dimension (L) aligned substantially parallel to the grain and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. In particular, the L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers, the W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers, and the L.times.W dimensions define a pair of substantially parallel top and bottom surfaces. The L.times.W surfaces of particles with L/H dimension ratios of 4:1 or less are further elaborated by surface checking between longitudinally arrayed fibers. The length dimension L is preferably aligned within 30.degree. parallel to the grain, and more preferably within 10.degree. parallel to the grain. The plant biomass material is preferably selected from among wood, agricultural crop residues, plantation grasses, hemp, bagasse, and bamboo.

  15. Babassu nut residues: potential for bioenergy use in the North and Northeast of Brazil.

    PubMed

    de Paula Protásio, Thiago; Fernando Trugilho, Paulo; da Silva César, Antônia Amanda; Napoli, Alfredo; Alves de Melo, Isabel Cristina Nogueira; Gomes da Silva, Marcela

    2014-01-01

    Babassu is considered the largest native oil resource worldwide and occurs naturally in Brazil. The purpose of this study was to evaluate the potential of babassu nut residues (epicarp, mesocarp and endocarp) for bioenergy use, especially for direct combustion and charcoal production. The material was collected in the rural area of the municipality of Sítio Novo do Tocantins, in the state of Tocantins, Brazil. Analyses were performed considering jointly the three layers that make up the babassu nut shell. The following chemical characterizations were performed: molecular (lignin, total extractives and holocellulose), elemental (C, H, N, S and O), immediate (fixed carbon, volatiles and ash), energy (higher heating value and lower heating value), physical (basic density and energy density) and thermal (thermogravimetry and differential thermal analysis), besides the morphological characterization by scanning electron microscopy. Babassu nut residues showed a high bioenergy potential, mainly due to their high energy density. The use of this biomass as a bioenergy source can be highly feasible, given their chemical and thermal characteristics, combined with a low ash content. Babassu nut shell showed a high basic density and a suitable lignin content for the sustainable production of bioenergy and charcoal, capable of replacing coke in Brazilian steel plants. PMID:24741469

  16. Assessment of secondary residues. Engineering and economic analysis. Final report

    SciTech Connect

    Leuschner, A.P.; West, C.E.; Ashare, E.

    1981-08-01

    Secondary agricultural residues are defined as those residues resulting from biomass processing to produce primary products; e.g., whey from cheese processing, vegetable processing wastes, and residues from pulp and paper processing. The analyses consist of specific case studies investigating the costs of converting liquid and/or solid residue streams to methane and/or ethanol. Several economically feasible examples were found: methane production from potato processing liquid residues, ethanol from potato processing solid residues, methane from cheese processing wastes, and methane from poultry processing liquid wastes. In facilities which operate year round, energy recovery is often feasible, whereas in seasonal operations, economic feasibility is not possible. Economic feasibility of energy production from secondary residues is strongly dependent on the current use of the solid and liquid residue. If the solid residue is sold as an animal feed, energy production is usually not economical. High solid and liquid residue disposal costs often make energy conversion economically feasible.

  17. Effect of stabilization on biomass activity.

    PubMed

    Cokgor, Emine Ubay; Okutman Tas, Didem; Zengin, Gulsum Emel; Insel, Guclu

    2012-02-20

    The study aimed to compare aerobic and aerobic/anoxic stabilization processes in terms of organic matter and the biomass removal efficiencies using a municipal sludge sample. The efficiency of stabilization process was assessed monitoring suspended solids (SS), volatile suspended solids (VSS), total and dissolved organic carbon (TOC, DOC), nitrate, nitrite, and phosphate parameters. The oxygen uptake rate (OUR) measurements were conducted to determine active biomass concentration. On the 30th day of the aerobic stabilization, the SS, VSS and TOC removal efficiencies were 22%, 28% and 55%, respectively. Under aerobic/anoxic conditions, removal efficiencies for SS, VSS and TOC were 25%, 27% and 67%. On the 17th day of the stabilization, SS and VSS removal rates were 60 mg SS/L day and 47 mg VSS/L day for aerobic and 102 mg SS/L day and 63 mg VSS/L day for aerobic/anoxic conditions, respectively. These findings reflected the higher stabilization performance of the aerobic/anoxic conditions. Based on respirometric results, the ratios of the active biomass were decreased to 30% and 24% for the 17th and 30th day of the aerobic stabilization, respectively. Such results have significant implications relative to the activity decrease quantification of the biomass as well as its further application potentials after aerobic or aerobic/anoxic sludge stabilization. PMID:21791229

  18. Aggregate stability in mine residues after reclamation with biochar

    NASA Astrophysics Data System (ADS)

    Moreno-Barriga, Fabián; Díaz, Vicente; Acosta, José; Faz, Ángel; Zornoza, Raúl

    2016-04-01

    This study aims to assess how the addition of biochar and marble waste to acidic mine residues affected aggregate stability (AS) and contributed to the improvement of soil texture. For this purpose, a lab incubation was carried out for 90 days. Biochars derived from pig manure (PM), crop residues (CR) and municipal solid waste (MSW) were added to the soil at a rate of 20 g kg-1. The marble waste (MW) was added at a rate of 200 g kg-1, with the aim of increasing pH from 3 to 8 (pH of the native soils of the area). Biochars and MW were applied independently and combined. A control treatment was used without application of amendments. The evolution of AS was periodically monitored at 2, 4, 7, 15, 30 and 90 days by the method of artificial rainfall. Results showed, at the end of the incubation, that the addition of MW alone did not significantly increased AS with comparison to CT (30%). However, the biochar, alone or together with MW, significantly increased AS, the treatment receiving CR derived biochar being the one with the highest values (46%). Increments in AS were significant from the day 30 of incubation. AS showed a significant correlation with the total organic carbon content, but was not correlated with organic carbon fractions (soluble, labile, recalcitrant), inorganic carbon, microbial biomass carbon, enzyme activities, exchangeable fraction of heavy metals (As, Cd, Cu, Pb, Zn), pH, electrical conductivity nor greenhouse gas emissions (NO₂, CH₄). Thus, the application of biochar (alone or in combination with MW as a source of calcium carbonate) significantly increased the formation of stable aggregates in former acidic mine residues, favoring the development of soil structure, essential to create a soil from residues. It seems that the total content of organic carbon is directly controlling aggregation, rather than other labile organic sources. Moreover, pH, salinity or the presence of exchangeable metals did not seem to affect soil aggregation

  19. Evaluation of environmental impacts from municipal solid waste management in the municipality of Aarhus, Denmark (EASEWASTE).

    PubMed

    Kirkeby, Janus T; Birgisdottir, Harpa; Hansen, Trine Lund; Christensen, Thomas H; Bhander, Gurbakhash Singh; Hauschild, Michael

    2006-02-01

    A new computer based life cycle assessment model (EASEWASTE) was used to evaluate a municipal solid waste system with the purpose of identifying environmental benefits and disadvantages by anaerobic digestion of source-separated household waste and incineration. The most important processes that were included in the study are optical sorting and pre-treatment, anaerobic digestion with heat and power recovery, incineration with heat and power recovery, use of digested biomass on arable soils and finally, an estimated surplus consumption of plastic in order to achieve a higher quality and quantity of organic waste to the biogas plant. Results showed that there were no significant differences in most of the assessed environmental impacts for the two scenarios. However, the use of digested biomass may cause a potential toxicity impact on human health due to the heavy metal content of the organic waste. A sensitivity analysis showed that the results are sensitive to the energy recovery efficiencies, to the extra plastic consumption for waste bags and to the content of heavy metals in the waste. A model such as EASEWASTE is very suitable for evaluating the overall environmental consequences of different waste management strategies and technologies, and can be used for most waste material fractions existing in household waste. PMID:16496867

  20. Biomass energy analysis for crop dehydration

    SciTech Connect

    Whittier, J.P.; Haase, S.G.; Quinn, M.W.

    1994-12-31

    In 1994, an agricultural processing facility was constructed in southern New Mexico for spice and herb dehydration. Annual operational costs are dominated by energy costs, due primarily to the energy intensity of dehydration. A feasibility study was performed to determine whether the use of biomass resources as a feedstock for a cogeneration system would be an economical option. The project location allowed access to unusual biomass feedstocks including cotton gin trash, pecan shells and in-house residues. A resource assessment of the immediate project area determined that approximately 120,000 bone dry tons of biomass feedstocks are available annually. Technology characterization for the plant energy requirements indicated gasification systems offer fuel flexibility advantages over combustion systems although vendor support and commercial experience are limited. Regulatory siting considerations introduce a level of uncertainty because of a lack of a precedent in New Mexico for gasification technology and because vendors of commercial gasifiers have little experience operating such a facility nor gathering emission data. A public opinion survey indicated considerable support for renewable energy use and biomass energy utilization. However, the public opinion survey also revealed limited knowledge of biomass technologies and concerns regarding siting of a biomass facility within the geographic area. The economic analysis conducted for the study is based on equipment vendor quotations, and indicates there will be difficulty competing with current prices of natural gas.

  1. Miscanthus as cellulosic biomass for bioethanol production.

    PubMed

    Lee, Wen-Chien; Kuan, Wei-Chih

    2015-06-01

    The members of the genus Miscanthus are potential feedstocks for biofuels because of the promising high yields of biomass per unit of planted area. This review addresses species, cultivation, and lignocellulose composition of Miscanthus, as well as pretreatment and enzyme saccharification of Miscanthus biomass for ethanol fermentation. The average cellulose contents in dried biomass of Miscanthus floridulus, Miscanthus sinensis, Miscanthus sacchariflorus, and Miscanthus × giganteus (M × G) are 37.2, 37.6, 38.9, and 41.1% wt/wt, respectively. A number of pretreatment methods have been applied in order to enhance digestibility of Miscanthus biomass for enzymatic saccharification. Pretreatment of Miscanthus using liquid hot water or alkaline results in a significant release of glucose; while glucose yields can be 90% or higher if a pretreatment like AFEX that combines both chemical and physical processes is used. As ethanol is produced by yeast fermentation of the hydrolysate from enzymatic hydrolysis of residual solids (pulp) after pretreatment, theoretical ethanol yields are 0.211-0.233 g/g-raw biomass if only cellulose is taken into account. Simultaneous saccharification and fermentation of pretreated M × G and M. lutarioriparius results in experimental ethanol yields of 0.13 and 0.15 g/g-raw biomass, respectively. Co-production of value-added products can reduce the overall production cost of bioethanol. PMID:26013948

  2. Understanding Biomass Feedstock Variability

    SciTech Connect

    Kevin L. Kenney; Garold L. Gresham; William A. Smith; Tyler L. Westover

    2013-01-01

    If the singular goal of biomass logistics and the design of biomass feedstock supply systems is to reduce the per-ton supply cost of biomass, these systems may very well develop with ultimate unintended consequences of highly variable and reduced quality biomass feedstocks. This paper demonstrates that, due to inherent species variabilities, production conditions and differing harvest, collection and storage practices, this is a very real scenario that biomass producers and suppliers as well as conversion developers should be aware of. Biomass feedstock attributes of ash, carbohydrates, moisture and particle morphology will be discussed. We will also discuss specifications for these attributes, inherent variability of these attributes in biomass feedstocks, and approaches and solutions for reducing variability for improving feedstock quality.

  3. Understanding Biomass Feedstock Variability

    SciTech Connect

    Kevin L. Kenney; William A. Smith; Garold L. Gresham; Tyler L. Westover

    2013-01-01

    If the singular goal of biomass logistics and the design of biomass feedstock supply systems is to reduce the per ton supply cost of biomass, these systems may very well develop with ultimate unintended consequences of highly variable and reduced quality biomass feedstocks. This paper demonstrates that due to inherent species variabilities, production conditions, and differing harvest, collection, and storage practices, this is a very real scenario that biomass producers and suppliers as well as conversion developers should be aware of. Biomass feedstock attributes of ash, carbohydrates, moisture, and particle morphology will be discussed. We will also discuss specifications for these attributes, inherent variability of these attributes in biomass feedstocks, and approaches and solutions for reducing variability for improving feedstock quality.

  4. Energy from Municipal Waste Program

    NASA Astrophysics Data System (ADS)

    1992-05-01

    Each year Americans throw away 3 quads of energy in the form of municipal waste and pay 6 billion dollars for the privilege. Only about 21 percent of our municipal wastes are used productively to generate electricity or produce new products by recycling. In 1990, waste-to-energy (WTE) plants and recycling efforts contributed roughly half a quad of energy in the form of electricity and reduced energy use. This productive use of waste avoided the disposal of about 50 million tons of wastes to landfills in that year. The Administration National Energy Strategy (NES) estimates that with proper Federal, State, local, and private action the electric generating capacity of WTE facilities could increase 600 percent by 2010 and by over 1200 percent by 2030, compared to 1990 capacity. This would result in about 55 gigawatts (GW) of capacity by 2030, up from roughly 4 GW today. The Department of Energy (DOE) supports an integrated approach to waste management that includes source reduction, WTE, recycling, and landfilling as complementary pieces of a solution to the municipal waste disposal problem. The Energy from Municipal Waste Program, described in this plan, seeks to minimize the productive use of municipal waste as an energy resource to improving its economic and environmental characteristics. While the Program focuses on WTE systems, it is conducted as part of a larger Federal effort that includes source reduction and recycling of wastes to save energy.

  5. Geotechnical hazards associated with closed municipal solid waste landfill sites

    NASA Astrophysics Data System (ADS)

    Powrie, W.; Richards, D.; Beaven, R.

    2015-09-01

    As pressure for new infrastructure and development grows, it is inevitable that building projects will encounter some of the c20,000 closed former solid waste landfills in the UK, many of which will have accepted municipal solid wastes (MSW). Construction on or across these sites brings a special set of geohazards associated with the potential for large and difficult to predict settlements, gas (and odour) release or generation, contaminated leachate and the breach of containment systems and other environmental controls. The presentation will discuss these issues with reference to recent research into understanding and predicting settlements in municipal solid waste landfills; assessing the total, current and residual gas potential of biodegradable wastes; the role of the hydraulic regime in the flushing of contaminants from the waste and the quality of leachate; and the need or otherwise for the long term integrity of engineered barriers and controls.

  6. Crop Residue Removal Effects on Production Costs and Soil Quality

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Crop residue has been identified as a near-term source of biomass for renewable fuel, heat, power, chemicals and other bio-materials. Our objective is to examine the potential impacts on the soil resource and nutrient replacement costs for different crop residue management strategies. Preliminary da...

  7. Bavarian program for using renewable energies (biomass-network)

    SciTech Connect

    Weber, T.

    1995-11-01

    In Bavaria biomass is the most important regenerated resource of energy besides water. For the energetic utilization of biomass the following groups of products should be developed: biogenic fuels (biodiesel, nature diesel), biogas and warmth, steam and electricity based on biomass in small heating plants, heating plants, heating and electricity plants and in combustions of biomass in connection with coal. In a long term the future percentage of biomass used as a resource of energy could be 12%. But in a first step only 5% of the primary energy requirement should be sufficiently supplied with biomass. Biomass as a combustible has a special importance in Bavaria. Therefore residues of forest work, of the utilization of wood, of landscape conservation works, and of the agriculture, such as straw and energy crops are used. For the reason of rationalization within the utilization of biomass a self propelling biotruck, that condenses biomass, was developed. In the next years the state funds of the utilization of biomass as a resource of energy are about 50 Mio DM, available from the Bavarian free state, the Federal Republic of Germany and the EU. These funds are especially assigned for technological furtherances. The funds are directed by CARMEN, an institution founded by the economy and the Bavarian free state for all matters concerning renewable resources. The production and utilization of renewable resources in Bavaria give new tasks to agricultural areas and create new jobs. Moreover many positive effects for the environment and the economic welfare are given.

  8. Co-firing coal and municipal solid waste

    SciTech Connect

    Demirbas, A.

    2008-07-01

    The aim of this study was to experimentally investigate how different the organic fraction of municipal solid waste (OFMSW) or municipal solid waste (MSW) utilizing strategies affects the gas emission in simple fluidized bed combustion (FBC) of biomass. In this study, ground OFMSW and pulverized coal (PC) were used for co-firing tests. The tests were carried out in a bench-scale bubbling FBC. Coal and bio-waste fuels are quite different in composition. Ash composition of the bio-waste fuels is fundamentally different from ash composition of the coal. Chlorine (Cl) in the MSW may affect operation by corrosion. Ash deposits reduce heat transfer and also may result in severe corrosion at high temperatures. Nitrogen (N) and carbon ) assessments can play an important role in a strategy to control carbon dioxide (CO{sub 2}) and nitrogen oxide (NOx) emissions while raising revenue. Regulations such as subsidies for oil, liquid petroleum gas (LPG) for natural gas powered vehicles, and renewables, especially biomass lines, to reduce emissions may be more cost-effective than assessments. Research and development (RD) resources are driven by energy policy goals and can change the competitiveness of renewables, especially solid waste. The future supply of co-firing depends on energy prices and technical progress, both of which are driven by energy policy priorities.

  9. Thermal decomposition dynamics and severity of microalgae residues in torrefaction.

    PubMed

    Chen, Wei-Hsin; Huang, Ming-Yueh; Chang, Jo-Shu; Chen, Chun-Yen

    2014-10-01

    To figure out the torrefaction characteristics and weight loss dynamics of microalgae residues, the thermogravimetric analyses of two microalgae (Chlamydomonas sp. JSC4 and Chlorella sorokiniana CY1) residues are carried out. A parameter of torrefaction severity index (TSI) in the range of 0-1, in terms of weight loss ratio between a certain operation and a reference operation, is defined to indicate the degree of biomass thermal degradation due to torrefaction. The TSI profiles of the two residues are similar to each other; therefore, the parameter may be used to describe the torrefaction extents of various biomass materials. The curvature of TSI profile along light torrefaction is slight, elucidating its slight impact on biomass thermal degradation. The sharp curvature along severe torrefaction in the initial pretreatment period reveals that biomass upgraded with high temperature and short duration is more effective than using low temperature with long duration. PMID:25058302

  10. Biofuel from biomass via photo-electrochemical reactions: An overview

    NASA Astrophysics Data System (ADS)

    Ibrahim, N.; Kamarudin, S. K.; Minggu, L. J.

    2014-08-01

    Biomass is attracting a great deal of attention as a renewable energy resource to reduce carbon dioxide (CO2) emissions. Converting biomass from municipal, agricultural and livestock into biofuel and electrical power has significant environmental and economic advantages. The conversion of biomass into practical energy requires elegant designs and further investigation. Thus, biomass is a promising renewable energy source due to its low production cost and simple manufacturing processes. Biofuel (hydrogen and methanol) from biomass will be possible to be used for transportation with near-zero air pollution, involves efficient uses of land and major contribution to reduce dependence on insecure source of petroleum. Photoelectrochemical (PEC) reactions study has potential pathway for producing fuel from biomass and bio-related compound in the near future. This review highlights recent work related to the PEC conversion of biomass and bio-related compounds into useful biofuels and electricity. This review covers different types of photochemical reaction cells utilizing various types of organic and inorganic waste. It also presents recent developments in photoelectrodes, photocatalysts and electrolytes as well as the production of different types of fuel from PEC cells and highlights current developments and problems in PEC reactions.

  11. Compacting biomass waste materials for co-firing with coal

    SciTech Connect

    Graham, J.; Kiesler, J.; Morgan, A.; Liu, H.; Marrero, T.R.

    1999-07-01

    The purpose of this study is to develop a process that allows for the optimum compaction of various biomass waste materials to form fuels that can be co-fired with coal in conventional coal-fired power plants. Previous studies have shown that the use of biomass fuels in conjunction with coal in power plants is beneficial for several reasons. The use of biomass fuels reduces the amount of harmful gases that are emitted into the atmosphere by the firing of coal alone. In addition, the biomass used is primarily waste products that would be placed in a municipal landfill. By using this waste material as a fuel, the volume of waste being disposed of in landfills can be decreased significantly. However, in an uncompacted state these biomass wastes are bulky and costly to handle and transport. Compacting the biomass will increase its density and decrease the difficulty in handling and shipping costs. Four biomass products, wood chips, sawdust, low quality waste paper, and tree trimmings were compacted at various pressures into 1.91-inch diameter logs. After compaction, the logs were subjected to ASTM standard tests for unconfined compressive strength and splitting tensile strength. Tumbling tests and drop tests were also performed according to ASTM standards. The logs were also subjected to a water absorption test. Finally, each log will be tested to determine its thermal characteristics, such as the heating value and the gases each log produces when burned.

  12. Anammox growth on pretreated municipal wastewater.

    PubMed

    Lotti, Tommaso; Kleerebezem, Robbert; van Erp Taalman Kip, Charlotte; Hendrickx, Tim L G; Kruit, Jans; Hoekstra, Maaike; van Loosdrecht, Mark C M

    2014-07-15

    Autotrophic nitrogen removal from municipal wastewater enables development of energy autarkic wastewater treatment plants. In this study we report the evaluation of the anammox process in a granular sludge fluidized bed lab-scale reactor continuously fed with the actual effluent of the A-stage of the WWTP of Dokhaven, Rotterdam. The reactor was anoxic, and nitrite was dosed continuously to support anammox activity only. The system was operated for more than ten months at temperatures between 20 and 10 °C. COD was also consumed during the process, but heterotrophs could not outcompete anammox bacteria. Volumetric N-removal rates obtained were comparable or higher than those of conventional N-removal systems, with values higher than 0.4 g-N L(-1) d(-1) when operated at 10 °C. The biomass specific N-removal rate at 10 °C was on average 50±7 mg-N g-VSS(-1) d(-1) during the last month of operations, almost two times higher than previously reported activities at this temperature. FISH analysis revealed that the dominant anammox species was Candidatus Brocadia Fulgida throughout the experimentation. Evidence for growth of anammox bacteria at mainstream conditions was demonstrated for the entire temperature range tested (10-20 °C), and new granules were shown to be actively formed and efficiently retained in the system. PMID:24927034

  13. Cofiring biomass with coal: Opportunities for Malaysia

    NASA Astrophysics Data System (ADS)

    Rahman, A. A.; Shamsuddin, A. H.

    2013-06-01

    Malaysia generated 108,175 GWh of electricity in 2010 where 39.51 % was sourced from coal. Coal power generation is also planned to overtake natural gas as the main fuel for electricity generation within the next two decades. Malaysia also has a vast biomass resource that is currently under-utilised for electricity generation. This paper studies the option of cofiring biomass in existing Malaysian coal power plants to increase the nation's renewable energy mix as well as to reduce its power sector carbon dioxide emission. Benefits of cofiring to the nation were discussed and agricultural residues from palm oil and paddy was identified as a potential source of biomass for cofiring. It was also found that there is a willingness for cofiring by stakeholders but barriers existed in the form of technical issues and lack of clear direction and mechanism.

  14. Residual Cap

    NASA Technical Reports Server (NTRS)

    2006-01-01

    10 May 2006 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows a summertime view of the south polar residual cap of Mars. In this image, mesas composed largely of solid carbon dioxide are separated from one another by irregularly-shaped depressions. The variation in brightness across this scene is a function of several factors including, but not limited to, varying proportions of dust and solid carbon dioxide, undulating topography, and differences in the roughness of the slopes versus the flat surfaces.

    Location near: 86.7oS, 343.3oW Image width: 3 km (1.9 mi) Illumination from: upper left Season: Southern Summer

  15. Gasification of Woody Biomass.

    PubMed

    Dai, Jianjun; Saayman, Jean; Grace, John R; Ellis, Naoko

    2015-01-01

    Interest in biomass to produce heat, power, liquid fuels, hydrogen, and value-added chemicals with reduced greenhouse gas emissions is increasing worldwide. Gasification is becoming a promising technology for biomass utilization with a positive environmental impact. This review focuses specifically on woody biomass gasification and recent advances in the field. The physical properties, chemical structure, and composition of biomass greatly affect gasification performance, pretreatment, and handling. Primary and secondary catalysts are of key importance to improve the conversion and cracking of tars, and lime-enhanced gasification advantageously combines CO2 capture with gasification. These topics are covered here, including the reaction mechanisms and biomass characterization. Experimental research and industrial experience are investigated to elucidate concepts, processes, and characteristics of woody biomass gasification and to identify challenges. PMID:26247289

  16. Complex pendulum biomass sensor

    DOEpatents

    Hoskinson, Reed L.; Kenney, Kevin L.; Perrenoud, Ben C.

    2007-12-25

    A complex pendulum system biomass sensor having a plurality of pendulums. The plurality of pendulums allow the system to detect a biomass height and density. Each pendulum has an angular deflection sensor and a deflector at a unique height. The pendulums are passed through the biomass and readings from the angular deflection sensors are fed into a control system. The control system determines whether adjustment of machine settings is appropriate and either displays an output to the operator, or adjusts automatically adjusts the machine settings, such as the speed, at which the pendulums are passed through the biomass. In an alternate embodiment, an entanglement sensor is also passed through the biomass to determine the amount of biomass entanglement. This measure of entanglement is also fed into the control system.

  17. Some employment and earnings implications of regional biomass energy utilization: New England and the Cornbelt States

    NASA Astrophysics Data System (ADS)

    Stevenson, W.; Bell, S. E.; Blair, L. M.; Gove, R. M.; Little, J. R.

    1981-08-01

    Because of their abundant forest and agricultural biomass resources, New England and the Cornbelt are likely to grow considerably in the development of biomass energy systems during the next decade or two. Forty thousand or more permanent jobs might be created in New England's wood energy industry by the end of the century. If alcohol-fuel use continues to grow, even greater potential for employment in biomass energy exists in the Cornbelt states. The associated earnings would be quite substantial for both regions. The direct combustion of wood and activities related to alcohol-fuel production are expected to be the major contributors to biomass energy production, employment, and earnings; but other biomass systems show potential as well. Energy extraction from municipal waste, anaerobic digestion of animal manure, and other biomass conversion systems will all generate employment as they grow in use.

  18. Comparative study of different waste biomass for energy application.

    PubMed

    Motghare, Kalyani A; Rathod, Ajit P; Wasewar, Kailas L; Labhsetwar, Nitin K

    2016-01-01

    Biomass is available in many varieties, consisting of crops as well as its residues from agriculture, forestry, and the agro-industry. These different biomass find their way as freely available fuel in rural areas but are also responsible for air pollution. Emissions from such solid fuel combustion to indoor, regional and global air pollution largely depend on fuel types, combustion device, fuel properties, fuel moisture, amount of air supply for combustion and also on climatic conditions. In both economic and environment point of view, gasification constitutes an attractive alternative for the use of biomass as a fuel, than the combustion process. A large number of studies have been reported on a variety of biomass and agriculture residues for their possible use as renewable fuels. Considering the area specific agriculture residues and biomass availability and related transportation cost, it is important to explore various local biomass for their suitability as a fuel. Maharashtra (India) is the mainstay for the agriculture and therefore, produces a significant amount of waste biomass. The aim of the present research work is to analyze different local biomass wastes for their proximate analysis and calorific value to assess their potential as fuel. The biomass explored include cotton waste, leaf, soybean waste, wheat straw, rice straw, coconut coir, forest residues, etc. mainly due to their abundance. The calorific value and the proximate analysis of the different components of the biomass helped in assessing its potential for utilization in different industries. It is observed that ash content of these biomass species is quite low, while the volatile matter content is high as compared to Indian Coal. This may be appropriate for briquetting and thus can be used as a domestic fuel in biomass based gasifier cook stoves. Utilizing these biomass species as fuel in improved cook-stove and domestic gasifier cook-stoves would be a perspective step in the rural energy and

  19. Energy from biomass and wastes: 1982 update

    SciTech Connect

    Klass, D.L.

    1983-01-01

    Although federal support of research to develop energy from biomass and wastes continued to decrease in 1982, other sources of funding are taking up some of the slack. The contribution of energy from biomass and wastes to US primary energy consumption has increased to about 2.7 quads or 3.5% of total consumption and is projected to grow to about 3.5 quads by 1985. A reassessment of future climatic changes because of the greenhouse effect has not found any new results that require revision of the first assessment conducted in 1979. It is therefore apropos to begin to incorporate methodologies into world energy and biomass management that take this effect into account before any adverse changes begin to occur. Extensive research programs have continued on biomass production for energy applications and on the gasification and liquefaction of biomass and wastes for fuels, energy, and chemicals. Commercialization of this technology appears to be increasing at a higher rate, particularly for combustion of wood, wood wastes, and municipal solid wastes for heat, steam, and electric production; anaerobic digestion of industrial wastes for combined waste disposal and methane production; and use of fermentation ethanol as a motor fuel. Ethanol-fuel usage more than doubled in 1982 in the United States as compared to 1981, and plant capacity is expanding rapidly. Methanol has not yet begun to compete with ethanol because of federal limitations on the concentration of methanol in blends with gasoline. Relaxation of these requirements and passage of tax-forgiveness laws for methanol now enjoyed by ethanol could provide the incentives to make methanol the dominant fuel for vehicles in the long term.

  20. BENEFITS OF MAINTAINING A CHLORINE RESIDUAL IN WATER SUPPLY SYSTEMS

    EPA Science Inventory

    The protection afforded the water consumer by the maintenance of a chlorine residual in water distribution systems was evaluated in laboratory holding tanks and reservoirs and existing municipal water distribution systems. In the laboratory studies, tap water, adjusted to the app...

  1. Process for treating biomass

    DOEpatents

    Campbell, Timothy J.; Teymouri, Farzaneh

    2015-08-11

    This invention is directed to a process for treating biomass. The biomass is treated with a biomass swelling agent within the vessel to swell or rupture at least a portion of the biomass. A portion of the swelling agent is removed from a first end of the vessel following the treatment. Then steam is introduced into a second end of the vessel different from the first end to further remove swelling agent from the vessel in such a manner that the swelling agent exits the vessel at a relatively low water content.

  2. Engine fuels from biomass

    NASA Astrophysics Data System (ADS)

    Parker, H. W.

    1981-01-01

    Sources of biomass fuels for engines are compared to other synfuels. Biomass can be converted to gaseous and liquid engine fuels by the same processes utilized for coal conversion such as gasification, direct liquefaction, and indirect liquefaction. Alternatively, biomass can be converted into liquid fuels by fermentation to methane or ethanol. The quantities of biomass derived engine fuels potentially available in the next decade are relatively small, and the anticipated costs are significantly greater than for liquid engine fuels made from coal or oil shale.

  3. Biomass Processing Photolibrary

    DOE Data Explorer

    Research related to bioenergy is a major focus in the U.S. as science agencies, universities, and commercial labs seek to create new energy-efficient fuels. The Biomass Processing Project is one of the funded projects of the joint USDA-DOE Biomass Research and Development Initiative. The Biomass Processing Photolibrary has numerous images, but there are no accompanying abstracts to explain what you are seeing. The project website, however, makes available the full text of presentations and publications and also includes an exhaustive biomass glossary that is being developed into an ASAE Standard.

  4. Process for treating biomass

    SciTech Connect

    Campbell, Timothy J; Teymouri, Farzaneh

    2015-11-04

    This invention is directed to a process for treating biomass. The biomass is treated with a biomass swelling agent within the vessel to swell or rupture at least a portion of the biomass. A portion of the swelling agent is removed from a first end of the vessel following the treatment. Then steam is introduced into a second end of the vessel different from the first end to further remove swelling agent from the vessel in such a manner that the swelling agent exits the vessel at a relatively low water content.

  5. Gasification-based biomass

    SciTech Connect

    None, None

    2009-01-18

    The gasification-based biomass section of the Renewable Energy Technology Characterizations describes the technical and economic status of this emerging renewable energy option for electricity supply.

  6. Municipal treatment plant sludge management

    SciTech Connect

    Not Available

    1986-01-01

    This book presents the papers given at a conference on the processing of municipal wastes. Topics considered at the conference included closed-loop thermal sludge processing, bioenergy, the Hyperion energy recovery system, sludge drying, fluidized bed sludge incineration with supplemental coal firing and power generation, a sludge to oil reactor system, and energy recovery from anaerobic digestion.

  7. Method for moving high tonnage biomass from field to furnace

    SciTech Connect

    Clayton, J.E.; Eiland, B.R.

    1984-08-01

    Sugar cane harvesting and transport equipment can be used for harvesting frozen sugar cane or alternate crops for biomass after the harvest for sugar production is completed. Use of a rotary rake for preparing windrows of sugarcane residue and use of a forage harvester and a sound baler for recovering the material is satisfactory. The field residue contained high amounts of sulfur and ash, which may cause pollution problems. Material baled with a round baler had twice the bulk density of forage chopped material. A hay crumper reduced the drying time of residue windrows so that the residue could be collected before the ratoon crop sprouted, thus avoiding crop damage by the equipment.

  8. BIOMASS TO BIO-OIL BY LIQUEFACTION

    SciTech Connect

    Wang, Huamin; Wang, Yong

    2013-01-10

    Significant efforts have been devoted to develop processes for the conversion of biomass, an abundant and sustainable source of energy, to liquid fuels and chemicals, in order to replace diminishing fossil fuels and mitigate global warming. Thermochemical and biochemical methods have attracted the most attention. Among the thermochemical processes, pyrolysis and liquefaction are the two major technologies for the direct conversion of biomass to produce a liquid product, often called bio-oil. This chapter focuses on the liquefaction, a medium-temperature and high-pressure thermochemical process for the conversion of biomass to bio-oil. Water has been most commonly used as a solvent and the process is known as hydrothermal liquefaction (HTL). Fundamentals of HTL process, key factors determining HTL behavior, role of catalyst in HTL, properties of produced bio-oil, and the current status of the technology are summarized. The liquefaction of biomass by using organic solvents, a process called solvolysis, is also discussed. A wide range of biomass feedstocks have been tested for liquefaction including wood, crop residues, algae, food processing waste, and animal manure.

  9. Biomass Research Program

    SciTech Connect

    Kenney, Kevin; Wright, Christopher; Shelton-Davis, Colleen

    2011-01-01

    INL's mission is to achieve DOE's vision of supplying high-quality raw biomass; preprocessing biomass into advanced bioenergy feedstocks; and delivering bioenergy commodities to biorefineries. You can learn more about research like this at the lab's facebook site http://www.facebook.com/idahonationallaboratory.

  10. Global biomass opportunities

    SciTech Connect

    Sheinkopf, K.

    1993-10-01

    Low cost and plentiful resources make biomass a viable choice for power projects worldwide. Nevertheless, the potential does not alleviate the development obstacles. The developing world appears to hold the greatest promise for using biomass technologies - primarily Latin America, Africa, China, and other parts of Asia and Oceania.

  11. Biomass Research Program

    ScienceCinema

    Kenney, Kevin; Wright, Christopher; Shelton-Davis, Colleen

    2013-05-28

    INL's mission is to achieve DOE's vision of supplying high-quality raw biomass; preprocessing biomass into advanced bioenergy feedstocks; and delivering bioenergy commodities to biorefineries. You can learn more about research like this at the lab's facebook site http://www.facebook.com/idahonationallaboratory.

  12. Bamboo: An Overlooked Biomass Resource?

    SciTech Connect

    Scurlock, J.M.O.

    2000-02-01

    Bamboo is the common term applied to a broad group (1250 species) of large woody grasses, ranging from 10 cm to 40 m in height. Already in everyday use by about 2.5 billion people, mostly for fiber and food within Asia, bamboo may have potential as a bioenergy or fiber crop for niche markets, although some reports of its high productivity seem to be exaggerated. Literature on bamboo productivity is scarce, with most reports coming from various parts of Asia. There is little evidence overall that bamboo is significantly more productive than many other candidate bioenergy crops, but it shares a number of desirable fuel characteristics with certain other bioenergy feedstocks, such as low ash content and alkali index. Its heating value is lower than many woody biomass feedstocks but higher than most agricultural residues, grasses and straws. Although non-fuel applications of bamboo biomass may be actually more profitable than energy recovery, there may also be potential for co-productio n of bioenergy together with other bamboo processing. A significant drawback is the difficulty of selective breeding, given the lack of knowledge of flowering physiology. Further research is also required on propagation techniques, establishment and stand management, and mechanized harvesting needs to be developed.

  13. Engineered plant biomass feedstock particles

    DOEpatents

    Dooley, James H.; Lanning, David N.; Broderick, Thomas F.

    2011-10-11

    A novel class of flowable biomass feedstock particles with unusually large surface areas that can be manufactured in remarkably uniform sizes using low-energy comminution techniques. The feedstock particles are roughly parallelepiped in shape and characterized by a length dimension (L) aligned substantially with the grain direction and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. The particles exhibit a disrupted grain structure with prominent end and surface checks that greatly enhances their skeletal surface area as compared to their envelope surface area. The L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers. The W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers. The L.times.W dimensions define a pair of substantially parallel top surfaces characterized by some surface checking between longitudinally arrayed fibers. The feedstock particles are manufactured from a variety of plant biomass materials including wood, crop residues, plantation grasses, hemp, bagasse, and bamboo.

  14. Engineered plant biomass feedstock particles

    DOEpatents

    Dooley, James H.; Lanning, David N.; Broderick, Thomas F.

    2011-10-18

    A novel class of flowable biomass feedstock particles with unusually large surface areas that can be manufactured in remarkably uniform sizes using low-energy comminution techniques. The feedstock particles are roughly parallelepiped in shape and characterized by a length dimension (L) aligned substantially with the grain direction and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. The particles exhibit a disrupted grain structure with prominent end and surface checks that greatly enhances their skeletal surface area as compared to their envelope surface area. The L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers. The W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers. The L.times.W dimensions define a pair of substantially parallel top surfaces characterized by some surface checking between longitudinally arrayed fibers. At least 80% of the particles pass through a 1/4 inch screen having a 6.3 mm nominal sieve opening but are retained by a No. 10 screen having a 2 mm nominal sieve opening. The feedstock particles are manufactured from a variety of plant biomass materials including wood, crop residues, plantation grasses, hemp, bagasse, and bamboo.

  15. Biomass power in transition

    SciTech Connect

    Marshall, D.K.

    1996-12-31

    Electricity production from biomass fuel has been hailed in recent years as an environmentally acceptable energy source that delivers on its promise of economically viable renewable energy. A Wall Street Journal article from three years ago proclaimed wood to be {open_quotes}moving ahead of costly solar panels and wind turbines as the leading renewable energy alternative to air-fouling fossils fuels and scary nuclear plants.{close_quotes} Biomass fuel largely means wood; about 90% of biomass generated electricity comes from burning waste wood, the remainder from agricultural wastes. Biomass power now faces an uncertain future. The maturing of the cogeneration and independent power plant market, restructuring of the electric industry, and technological advances with power equipment firing other fuels have placed biomass power in a competitive disadvantage with other power sources.

  16. Rheology of concentrated biomass

    NASA Astrophysics Data System (ADS)

    Samaniuk, J. R.; Wang, J.; Root, T. W.; Scott, C. T.; Klingenberg, D. J.

    2011-12-01

    Economic processing of lignocellulosic biomass requires handling the biomass at high solids concentration. This creates challenges because concentrated biomass behaves as a Bingham-like material with large yield stresses. Here we employ torque rheometry to measure the rheological properties of concentrated lignocellulosic biomass (corn stover). Yield stresses obtained using torque rheometry agree with those obtained using other rheometric methods, but torque rheometry can be used at much larger solids concentration (weight fractions of insoluble solids greater than 0.2). Yield stresses decrease with severity of hydrolysis, decrease when water-soluble polymers are added (for nonhydrolyzed biomass), and increase with particle length. Experimental results are qualitatively consistent with those obtained from particle-level simulations.

  17. Batteries called primary source of lead, cadmium in municipal waste

    SciTech Connect

    Not Available

    1989-04-01

    The US Environmental Protection Agency reports that lead-acid batteries, such as those used in automobiles, and rechargeable nickel-cadmium batteries used in consumer electronics equipment, are the primary sources of lead and cadmium in municipal trash and garbage. A report prepared for EPA analyzed existing data from 1970 to 1986 and made projections to the year 2000. Lead-acid batteries continue to constitute a major source of lead in garbage even though 80 percent of them are now recycled. As a result, EPA is calling for additional recycling of batteries. This study is an important step in implementing EPA's strategy for helping states and cities achieve the national goal of recycling and reducing 25 percent of all municipal garbage by 1992. The findings on batteries are the result of a study conducted for EPA because of concern over the levels of lead and cadmium found n ash (residue) from municipal waste incinerators. Lead and cadmium are two metals of particular concern in the solid waste stream. The metals can contaminate soil and groundwater when landfilled. They also may be found in some incinerator emissions.

  18. A mutli-factor analysis of sustainable agricultural residue removal potential

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Agricultural residues have significant potential as a near term source of cellulosic biomass for bioenergy production, but sustainable removal of agricultural residues requires consideration of the critical roles that residues play in the agronomic system. Previous work has developed an integrated m...

  19. Hydropyrolysis of biomass

    SciTech Connect

    Kobayashi, Atsushi; Steinberg, M.

    1992-01-01

    The pyrolysis and hydropyrolysis of biomass was investigated. Experimental runs using the biomass (Poplar wood sawdust) were performed using a tubular reactor of dimensions 1 inch inside diameter and 8 feet long heated at a temperature of 800 C and pressures between 450 and 750 psig. At low heat-up rate the reaction precedes in two steps. First pyrolysis takes place at temperatures of 300 to 400 c and subsequent hydropyrolysis takes place at 700 C and above. This is also confirmed by pressurized thermogravimetric analysis (PTGA). Under conditions of rapid heat-up at higher temperatures and higher hydrogen pressure gasification and hydrogasification of biomass is especially effective in producing carbon monoxide and methane. An overall conversion of 88 to 90 wt % of biomass was obtained. This value is in agreement with the previous work of flash pyrolysis and hydropyrolysis of biomass for rapid heat-up and short residence time. Initial rates of biomass conversion indicate that the rate increases significantly with increase in hydrogen pressure. At 800 C and 755 psig the initial rate of biomass conversion to gases is 0.92 1/min.

  20. Quantifying logging residue - before the fact

    SciTech Connect

    Bones, J.T.

    1982-06-01

    Tree biomass estimation, which is being integrated into the U.S. Forest Service Renewable Resources Evaluation Program, will give foresters the ability to estimate the amount of logging residues they might expect from harvested treetops and branches and residual rough, rotten, and small trees before the actual harvest. With planning, and increased demand for such timber products as pulpwood and fuelwood, product recovery could be increased by up to 43 percent in softwood stands and 99% in hardwoods. Recovery levels affect gross product receipts and site preparation costs. An example of product recovery and residue generation is presented for three harvesting options in Pennsylvania hardwood stands. Under the whole-tree harvesting option, 46% more product was recovered than in single product harvesting, and logging residue levels were reduced by 58%.

  1. Comprehensive Utilization of Biomass Process Residues Rich in Cellulose

    NASA Astrophysics Data System (ADS)

    Zhong, Mei; Li, Qiang; Yu, Jian; Dong, Li; Wang, Yin; Xu, Guangwen

    2010-11-01

    This article investigated the method preparing porous material (PM) with VL and SL. Applications of the prepared material was tested in removal aqueous phenol and COD in tarry water and as the catalyst support for selective catalytic reduction (SCR) of NO in flue gas. The results showed that the optimal activation condition in CO2 for the carbonized VL at 800° C was at 875° C for 1 h, which provided large BET surface area and micropore volume. This material exhibited the highest adsorption to aqueous phenol among all the tested materials including a commercial activated carbon made from coconut shell, showing the potential application of the VL-base porous material in wastewater treatment. The study demonstrated also that the vanadium-base selective catalytic reduction (SCR) catalyst supported on the VL-base porous material (V2O5/VL-PM) provided fairly good activity as well SO2 resistance at temperatures round 200° C for SCR of NO. The activation of the carbonized SL material in H2O was better than that in CO2 for developing the pore structure of the porous material. Steam can improve the formation of mesopore than CO2. This was confirmed by the conclusion that higher COD removal rate was occurred on the PM-1 from SL when H2O was used as an activator.

  2. Cultivation of Nannochloropsis oceanica biomass rich in eicosapentaenoic acid utilizing wastewater as nutrient resource.

    PubMed

    Mitra, Madhusree; Shah, Freny; Bharadwaj, S V Vamsi; Patidar, Shailesh Kumar; Mishra, Sandhya

    2016-10-01

    The eicosapentaenoic acid rich marine eustigmatophyte Nannochloropsis oceanica was grown in wastewaters sampled from four different industries (i.e. pesticides industry, pharmaceutical industry, activated sludge treatment plant of municipality sewage and petroleum (oil) industry). Under the wastewater based growth conditions used in this study, the biomass productivity ranged from 21.78±0.87 to 27.78±0.22mgL(-1)d(-1) in relation to freeze dried biomass, while the lipid productivity varied between 5.59±0.02 and 6.81±0.04mgL(-1)d(-1). Although comparatively higher biomass, lipid and EPA productivity was observed in Conway medium, the %EPA content was similarly observed in pesticides industry and municipal effluents. The results highlight the possibility of selectively using wastewater as a growth medium, demonstrating the elevated eicosapentaenoic acid content and biodiesel properties, that complies with the European standards for biodiesel. PMID:27472494

  3. Relative importance of P and N in macrophyte and epilithic algae biomass in a wastewater-impacted oligotrophic river.

    PubMed

    Taube, Nadine; He, Jianxun; Ryan, M Cathryn; Valeo, Caterina

    2016-08-01

    The role of nutrient loading on biomass growth in wastewater-impacted rivers is important in order to effectively optimize wastewater treatment to avoid excessive biomass growth in the receiving water body. This paper directly relates wastewater treatment plant (WWTP) effluent nutrients (including ammonia (NH3-N), nitrate (NO3-N) and total phosphorus (TP)) to the temporal and spatial distribution of epilithic algae and macrophyte biomass in an oligotrophic river. Annual macrophyte biomass, epilithic algae data and WWTP effluent nutrient data from 1980 to 2012 were statistically analysed. Because discharge can affect aquatic biomass growth, locally weighted scatterplot smoothing (LOWESS) was used to remove the influence of river discharge from the aquatic biomass (macrophytes and algae) data before further analysis was conducted. The results from LOWESS indicated that aquatic biomass did not increase beyond site-specific threshold discharge values in the river. The LOWESS-estimated biomass residuals showed a variable response to different nutrients. Macrophyte biomass residuals showed a decreasing trend concurrent with enhanced nutrient removal at the WWTP and decreased effluent P loading, whereas epilithic algae biomass residuals showed greater response to enhanced N removal. Correlation analysis between effluent nutrient concentrations and the biomass residuals (both epilithic algae and macrophytes) suggested that aquatic biomass is nitrogen limited, especially by NH3-N, at most sampling sites. The response of aquatic biomass residuals to effluent nutrient concentrations did not change with increasing distance to the WWTP but was different for P and N, allowing for additional conclusions about nutrient limitation in specific river reaches. The data further showed that the mixing process between the effluent and the river has an influence on the spatial distribution of biomass growth. PMID:27473108

  4. The effect of broiler litter, swine effluent, and municipal biosolids land application on small plot pathogen, antibiotic resistance, and nutrient levels

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Land applying agricultural and municipal wastes carries an inherent risk associated with nutrient and pathogen runoff and contamination, but with that risk comes a potentially sustainable process to reclaim otherwise residual waste material. Few studies compare the two residuals. The purpose of th...

  5. Catalytic Tar Reforming for Cleanup and Conditioning of Biomass-derived Syngas

    SciTech Connect

    Dayton, D. C.; Bain, R. L.; Phillips, S. D.; Magrini-Bair, K.; Feik, C. J.

    2006-01-01

    Biomass gasification is being investigated to produce clean syngas from biomass or biorefinery residues as an intermediate that can be used directly as a fuel for integrated heat and power production or further refined and upgraded by various processing technologies. Conditioning of biomass-derived syngas, with an emphasis on tar reforming, to make it a suitable feed for high temperature, pressurized liquid fuels synthesis is the goal of current research efforts.

  6. Polyhydroxyalkanoate (PHA) storage within a mixed-culture biomass with simultaneous growth as a function of accumulation substrate nitrogen and phosphorus levels.

    PubMed

    Valentino, Francesco; Karabegovic, Lamija; Majone, Mauro; Morgan-Sagastume, Fernando; Werker, Alan

    2015-06-15

    PHA content was attributed to interpreted differences in the biomass initial physiological state and not due to changes in feedstock nutrient loading. We found that the accumulation process production rates for mixed cultures can be sustained long after the maximum PHA content of the biomass was reached. Within the specific context of the applied fed-batch feed-on-demand methods, active biomass growth was interpreted to have been largely restricted to the PHA-storing phenotypic fraction of the biomass. This study suggests practical prospects for mixed culture PHA production using a wide range of volatile fatty acid (VFA) rich feedstocks. Such VFA sources derived from residual industrial or municipal organic wastes often naturally contain associated nutrients ranging in levels from limitation to excess. PMID:25846983

  7. Assessment of secondary crop residues. Final report

    SciTech Connect

    Ashare, E.; Leuschner, A.P.; West, C.E.; Langton, B.

    1981-03-01

    This report is the first of three reports assessing the feasibility of converting secondary agricultural residues to energy in the form of either methane gas or ethyl alcohol. Secondary agricultural residues are defined in this study as those residues resulting from biomass processing to produce primary products; e.g., whey from cheese processing, vegetable processing wastes, residues from paper pulping, etc. This report summarizes the first two phases of this study, data compilation, and evaluation. Subsequent reports will analyze the technical and economic feasibility of converting these residues to energy and the implementability of this technology. The industries for which data has been compiled in this report include vegetable, fruit, seafood, meat, poultry, and dairy processing and the pulp, paper, and paperboard industry. The data collected include raw product input, final processed product output, residue types, and quantity, residue concentration, biodegradability, seasonality of production, and geographic distribution of processing facilities. In general, these industries produce a relatively solid residue ranging in total solids concentration from 10 to 50% and a dilute liquid residue with an organic content (measured as COD or BOD) ranging from a few hundred to a few thousand mg/l. Due to the significant quantities of residues generated in each of the industries, it appears that the potential exists for generating a substantial quantity of energy. For a particular industry this quantity of energy can range from only one percent upwards to nearly thirty-five percent of the total processing energy required. The total processing energy required for the industries included in this study is approximately 2.5 quads per year. The potential energy which can be generated from these industrial residues will be 0.05 to 0.10 quads per year or approximately 2 to 4 percent of the total demand.

  8. Issues in the production and conversion of lignocellulosic biomass crops to ethanol

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The goal of replacing 30% of 2004 gasoline demand with biofuels by 2030 will require 1 billion tons of biomass annually. Ethanol from lignocellulosic biomass (crop residues and perennial energy crops) will contribute the lion's share of biofuel production. Among challenges to overcome is environment...

  9. Quantifying Total and Sustainable Agricultural Biomass Resources in South Dakota – A Preliminary Study

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Conversion of biomass is considered the next major advance in biorenewable fuels, energy, and products. Wholesale conversion to biomass utilization could result in removal of current crop residues from agricultural fields or even implementation of different crops and cropping strategies (i.e., swit...

  10. Enhancing biomass utilization for bioenergy-crop rotation systems and alternative conversion processes

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biomass for bioenergy has a great deal of potential for decreasing our dependence upon fossil fuels and decreasing the net CO2 accumulation in the atmosphere. Crop residues are often promoted as a means of meeting the total biomass goals to provide sufficient amounts of materials for liquid fuel pro...

  11. A national research & development strategy for biomass crop feedstocks

    SciTech Connect

    Wright, L.L.; Cushman, J.H.

    1997-07-01

    Planning was initiated in 1996 with the objective of reevaluating current biomass feedstock research and development strategies to: (1) assure that by 2005, one or more commercial lignocellulosic to ethanol projects will be able to acquire a dependable supply of biomass crop feedstocks; (2) assure that recently initiated demonstrations of crops to electricity will be successful and; (3) assure that the research base needed to support future biomass industry expansion is being developed. Multiple trends and analyses indicate that biomass energy research and development strategies must take into account the fact that competition for land will define the upper limits of available biomass energy crop supplies and will largely dictate the price of those supplies. Only crop production and utilization strategies which contribute profit to the farmer or landowner and to energy producers will be used commercially for biomass energy production. Strategies for developing biomass {open_quotes}energy{close_quotes} crop supplies must take into consideration all of the methods by which biomass crops will enter biomass energy markets. The lignocellulosic materials derived from crops can be available as primary residues or crop by-products; secondary residues or processing by-products; co-products (at both the crop production and processing stages); or, as dedicated energy crops. Basic research and development (R&D) leading to yield improvement continues to be recommended as a major long-term focus for dedicated energy crops. Many additional near term topics need attention, some of which are also applicable to by-products and co-products. Switchgrass R&D should be expanded and developed with greater collaboration of USDA and state extension groups. Woody crop research should continue with significant cost-share from industries developing the crops for other commercial products. Co-product options need more investigation.

  12. Municipal solid waste combustion: Fuel testing and characterization

    SciTech Connect

    Bushnell, D.J.; Canova, J.H.; Dadkhah-Nikoo, A.

    1990-10-01

    The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

  13. Fuels and chemicals from biomass using solar thermal energy

    NASA Astrophysics Data System (ADS)

    Giori, G.; Leitheiser, R.; Wayman, M.

    1981-05-01

    The significant nearer term opportunities for the application of solar thermal energy to the manufacture of fuels and chemicals from biomass are summarized, with some comments on resource availability, market potential and economics. Consideration is given to the production of furfural from agricultural residues, and the role of furfural and its derivatives as a replacement for petrochemicals in the plastics industry.

  14. Harvesting and transporting high-tonnage crops for biomass

    SciTech Connect

    Clayton, J.E.; Eiland, B.R.

    1984-01-01

    Forage and sugarcane harvesters were used for harvesting sweet sorghum and sugarcane for biomass. One system of field transport with capability for dumping into highway trucks was used. Two methods of drying, collecting, densifying and transporting sugarcane residue were tested for providing material for commerical boilers. A method of rapid field drying is needed.

  15. Fuels and chemicals from biomass using solar thermal energy

    NASA Technical Reports Server (NTRS)

    Giori, G.; Leitheiser, R.; Wayman, M.

    1981-01-01

    The significant nearer term opportunities for the application of solar thermal energy to the manufacture of fuels and chemicals from biomass are summarized, with some comments on resource availability, market potential and economics. Consideration is given to the production of furfural from agricultural residues, and the role of furfural and its derivatives as a replacement for petrochemicals in the plastics industry.

  16. Utilizing LEAF to increase biomass feedstock supplies from agricultural land

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The start-up of three full-scale corn stover bioenergy conversion facilities in 2014 will require a substantial increase in sustainable biomass feedstock. Supplying crop residues without having a negative impact on ecosystem services is indeed a “grand challenge” associated with sustainable food and...

  17. Microbial biomass as a significant source of soil organic matter

    NASA Astrophysics Data System (ADS)

    Miltner, Anja; Kindler, Reimo; Schweigert, Michael; Achtenhagen, Jan; Bombach, Petra; Fester, Thomas; Kästner, Matthias

    2014-05-01

    Soil organic matter (SOM) plays an important role for soil fertility and in the global carbon cycle. SOM management should be based on knowledge about the chemical composition as well as the spatial distribution of SOM and its individual components in soils. Both parameters strongly depend on the direct precursors of SOM. In the past, microbial biomass has been neglected as a potential source of SOM, mainly because of its small pool size. Recent studies, however, show that a substantial portion of SOM is derived from microbial biomass residues. We therefore investigated the fate of microbial biomass residues in soils by means of incubation experiments with 13C-labelled microbial biomass. For our studies, we selected model organisms representing the three types of soil microorganisms and their characteristic cell wall structures: Escherichia coli (a Gram-negative bacterium), Bacillus subtilis (a Gram-positive bacterium) and Laccaria bicolor (an ectomycorrhizal fungus). We labelled the organisms by growing them on 13C glucose and incubated them in soil. During incubation, we followed the mineralisation of the labelled C, its incorporation into microbial biomass, and its transformation to non-living SOM. We found that 50-65% of the microbial biomass C remained in the soil during incubation. However, only a small part remained in the microbial biomass, the majority was transformed to SOM. In particular, proteins seemed to be rather stable in our experiments. In addition, we used scanning electron microscopy to identify microbial residues in soils and, for comparison, in artificial groundwater microcosms. Scanning electron micrographs showed a low number of intact cells, but mainly fragments of about 200-500 nm size. Similar fragments were found in artificial groundwater microcosms where the only possible origin was microbial biomass residues. Based on the results obtained, we provide a mechanistic model which explains how microbial biomass residues are formed and

  18. Biomass cogeneration. A business assessment

    SciTech Connect

    Skelton, J.C.

    1981-11-01

    This guide serves as an overview of the biomass cogeneration area and provides direction for more detailed analysis. The business assessment is based in part on discussions with key officials from firms that have adopted biomass cogeneration systems and from organizations such as utilities, state and federal agencies, and banks that would be directly involved in a biomass cogeneration project. The guide is organized into five chapters: biomass cogeneration systems, biomass cogeneration business considerations, biomass cogeneration economics, biomass cogeneration project planning, and case studies.

  19. Phosphorus recovery from municipal solid waste incineration fly ash.

    PubMed

    Kalmykova, Yuliya; Fedje, K Karlfeldt

    2013-06-01

    The potential of phosphorus (P) recycling from municipal solid waste incineration (MSWI) residue is investigated. Vast and ever increasing amounts of incineration residues are produced worldwide; these are an environmental burden, but also a resource, as they are a major sink for the material flows of society. Due to strict environmental regulations, in combination with decreasing landfilling space, the disposal of the MSWI residues is problematic. At the same time, resource scarcity is recognized as a global challenge for the modern world, and even more so for future generations. This paper reports on the methods and efficiency of P extraction from MSWI fly ash by acid and base leaching and precipitation procedures. Phosphorus extracted from the MSWI residues generated each year could meet 30% of the annual demand for mineral phosphorus fertiliser in Sweden, given a recovery rate of 70% achieved in this initial test. The phosphorus content of the obtained product is slightly higher than in sewage sludge, but due to the trace metal content it is not acceptable for application to agricultural land in Sweden, whereas application in the rest of the EU would be possible. However, it would be preferable to use the product as a raw material to replace rock phosphate in fertilizer production. Further development is currently underway in relation to procedure optimization, purification of the phosphorus product, and the simultaneous recovery of other resources. PMID:23490361

  20. Composting of municipal solid waste.

    PubMed

    Kumar, Sunil

    2011-06-01

    This paper reviews the literature on the composting process, which is one of the technological options for the processing of municipal solid wastes (MSWs). The process assumes a great significance, particularly from the point of its economic viability, capability for recycling of nutrients and waste minimization with minimum environmental problems. A number of studies on various aspects of the composting process, including process control and monitoring parameters such as temperature, pH, moisture content, aeration, and porosity are reviewed. Salient observations on microbial properties of composting are described and details of vermicomposting, as well as a detailed analysis of patents on composting of MSW, are presented. PMID:20854128

  1. Ethanol from municipal cellulosic wastes

    NASA Astrophysics Data System (ADS)

    Parker, A. J., Jr.; Timbario, T. J.; Mulloney, J. A., Jr.

    This paper addresses the use of municipal cellulosic wastes as a feedstock for producing ethanol fuels, and describes the application of enzymatic hydrolysis technology for their production. The concept incorporates recent process technology developments within the framework of an existing industry familiar with large-scale ethanol fermentation (the brewing industry). Preliminary indications are that the cost of producing ethanol via enzymatic hydrolysis in an existing plant with minimal facility modifications (low capital investment) can be significantly less than that of ethanol from grain fermentation.

  2. Effects of solubility properties of solvents and biomass on biomass pretreatment.

    PubMed

    Weerachanchai, Piyarat; Kwak, Sang Kyu; Lee, Jong-Min

    2014-10-01

    Hildebrand solubility parameters of biomasses and pretreatment solvents were examined by a method of intrinsic viscosity. This is to be used as basic information in selecting a suitable solvent for biomass pretreatment processes. The effects of mixing1-ethyl-3-methylimidazolium acetate (EMIM-AC) and different solvents, lignin content in a pretreatment solvent, and biomass type on the Hildebrand solubility parameter and thermodynamic properties were carried out and calculated in this work. The Hildebrand solubility parameters of the mixtures are according to those of organic solvents: δH[EMIM-AC/DMA]=25.07<δH[EMIM-AC/DMF]=25.48<δH[EMIM-AC/DMSO]=26.10<δH[EMIM-AC/Ethanolamine]=26.95. The Hildebrand solubility parameters of biomass compositions (microcrystalline cellulose, xylan and alkali lignin) and biomasses (cassava pulp residue and rice straw) vary in the ranges of 25.14-26.13. The increases of lignin content in the pretreatment solvents lead to the Hildebrand solubility parameter becoming closer to that of lignin. PMID:25129231

  3. Medium term municipal solid waste generation prediction by autoregressive integrated moving average

    SciTech Connect

    Younes, Mohammad K.; Nopiah, Z. M.; Basri, Noor Ezlin A.; Basri, Hassan

    2014-09-12

    Generally, solid waste handling and management are performed by municipality or local authority. In most of developing countries, local authorities suffer from serious solid waste management (SWM) problems and insufficient data and strategic planning. Thus it is important to develop robust solid waste generation forecasting model. It helps to proper manage the generated solid waste and to develop future plan based on relatively accurate figures. In Malaysia, solid waste generation rate increases rapidly due to the population growth and new consumption trends that characterize the modern life style. This paper aims to develop monthly solid waste forecasting model using Autoregressive Integrated Moving Average (ARIMA), such model is applicable even though there is lack of data and will help the municipality properly establish the annual service plan. The results show that ARIMA (6,1,0) model predicts monthly municipal solid waste generation with root mean square error equals to 0.0952 and the model forecast residuals are within accepted 95% confident interval.

  4. Medium term municipal solid waste generation prediction by autoregressive integrated moving average

    NASA Astrophysics Data System (ADS)

    Younes, Mohammad K.; Nopiah, Z. M.; Basri, Noor Ezlin A.; Basri, Hassan

    2014-09-01

    Generally, solid waste handling and management are performed by municipality or local authority. In most of developing countries, local authorities suffer from serious solid waste management (SWM) problems and insufficient data and strategic planning. Thus it is important to develop robust solid waste generation forecasting model. It helps to proper manage the generated solid waste and to develop future plan based on relatively accurate figures. In Malaysia, solid waste generation rate increases rapidly due to the population growth and new consumption trends that characterize the modern life style. This paper aims to develop monthly solid waste forecasting model using Autoregressive Integrated Moving Average (ARIMA), such model is applicable even though there is lack of data and will help the municipality properly establish the annual service plan. The results show that ARIMA (6,1,0) model predicts monthly municipal solid waste generation with root mean square error equals to 0.0952 and the model forecast residuals are within accepted 95% confident interval.

  5. Electrolytic Removal of Nitrate From CELSS Crop Residues

    NASA Technical Reports Server (NTRS)

    Colon, Guillermo; Sager, John

    1996-01-01

    The controlled ecological life support system (CELSS) resource recovery system is a waste processing system using aerobic and anaerobic bioreactors to recover plant nutrients and secondary foods from inedible biomass. Crop residues contain significant amounts of nitrate which presents two problems: (1) both CELSS biomass production and resource recovery consume large quantities of nitric acid, (2) nitrate causes a variety of problems in both aerobic and anaerobic bioreactors. A technique was proposed to remove the nitrate from potato inedible biomass leachate and to satisfy the nitric acid demand using a four compartment electrolytic cell.

  6. Individual biomass facility reports. Supplement to some employment and earnings implications of regional biomass energy utilization: New England and the Cornbelt States

    NASA Astrophysics Data System (ADS)

    Little, J. R.; Bell, S. E.; Blair, L. M.; Gove, R. M.; Stevenson, W.; Tamura, R. F.

    1981-08-01

    Research was conducted to determine the direct employment and earnings implications of regional biomass energy utilization. Details of the primary data collected during the course of the investigation are provided. A case studies approach was used to observe and analyze various biomass energy systems. Visits were made to existing biomass facilities and data on their operation and employment requirements were collected. Information on planned or potential future facilities was also obtained. When this information was analyzed, a fairly accurate picture of the current situation as well as the rate and direction of future development in biomass was attained. Separate descriptions are included for each facility visited or for each interview obtained. The facility reports are organized according to fuel cycle (wood-fuel, alcohol-fuel, municipal solid waste facilities, others).

  7. Impact of torrefaction on the grindability and fuel characteristics of forest biomass.

    PubMed

    Phanphanich, Manunya; Mani, Sudhagar

    2011-01-01

    Thermal pretreatment or torrefaction of biomass under anoxic condition can produce an energy dense and consistent quality solid biomass fuel for combustion and co-firing applications. This paper investigates the fuel characteristics and grindability of pine chips and logging residues torrefied at temperatures ranging from 225 °C to 300 °C and 30 min residence time. Grinding performance of torrefied biomass evaluated by determining energy required for grinding, particle size distribution and average particle size were compared with raw biomass and coal. Specific energy required for grinding of torrefied biomass decreased significantly with increase in torrefaction temperatures. The grinding energy of torrefied biomass was reduced to as low as 24 kW h/t at 300 °C torrefaction temperature. The gross calorific value of torrefied chips increased with increase in torrefaction temperature. Torrefaction of biomass clearly showed the improved fuel characteristics and grinding properties closer to coal. PMID:20801023

  8. Mobility of organic carbon from incineration residues

    SciTech Connect

    Ecke, Holger Svensson, Malin

    2008-07-01

    Dissolved organic carbon (DOC) may affect the transport of pollutants from incineration residues when landfilled or used in geotechnical construction. The leaching of dissolved organic carbon (DOC) from municipal solid waste incineration (MSWI) bottom ash and air pollution control residue (APC) from the incineration of waste wood was investigated. Factors affecting the mobility of DOC were studied in a reduced 2{sup 6-1} experimental design. Controlled factors were treatment with ultrasonic radiation, full carbonation (addition of CO{sub 2} until the pH was stable for 2.5 h), liquid-to-solid (L/S) ratio, pH, leaching temperature and time. Full carbonation, pH and the L/S ratio were the main factors controlling the mobility of DOC in the bottom ash. Approximately 60 weight-% of the total organic carbon (TOC) in the bottom ash was available for leaching in aqueous solutions. The L/S ratio and pH mainly controlled the mobilization of DOC from the APC residue. About 93 weight-% of TOC in the APC residue was, however, not mobilized at all, which might be due to a high content of elemental carbon. Using the European standard EN 13 137 for determination of total organic carbon (TOC) in MSWI residues is inappropriate. The results might be biased due to elemental carbon. It is recommended to develop a TOC method distinguishing between organic and elemental carbon.

  9. BARRIER ISSUES TO THE UTILIZATION OF BIOMASS

    SciTech Connect

    Bruce C. Folkedahl; Jay R. Gunderson; Darren D. Schmidt; Greg F. Weber; Christopher J. Zygarlicke

    2002-09-01

    The Energy & Environmental Research Center (EERC) has completed a project to examine fundamental issues that could limit the use of biomass in small industrial steam/power systems in order to increase the future use of this valuable domestic resource. Specifically, the EERC attempted to elucidate the ash-related problems--grate clinkering and heat exchange surface fouling--associated with cofiring coal and biomass in grate-fired systems. Utilization of biomass in stoker boilers designed for coal can be a cause of concern for boiler operators. Boilers that were designed for low-volatile fuels with lower reactivities can experience problematic fouling when switched to higher-volatile and more reactive coal-biomass blends. Higher heat release rates at the grate can cause increased clinkering or slagging at the grate due to higher temperatures. Combustion and loss of volatile matter can start much earlier for biomass fuels compared to design fuel, vaporizing alkali and chlorides which then condense on rear walls and heat exchange tube banks in the convective pass of the stoker, causing noticeable increases in fouling. In addition, stoker-fired boilers that switch to biomass blends may encounter new chemical species such as potassium sulfates, various chlorides, and phosphates. These species in combination with different flue gas temperatures, because of changes in fuel heating value, can adversely affect ash deposition behavior. The goal of this project was to identify the primary ash mechanisms related to grate clinkering and heat exchange surface fouling associated with cofiring coal and biomass--specifically wood and agricultural residuals--in grate-fired systems, leading to future mitigation of these problems. The specific technical objectives of the project were: (1) Modification of an existing pilot-scale combustion system to simulate a grate-fired system. (2) Verification testing of the simulator. (3) Laboratory-scale testing and fuel characterization to

  10. BARRIER ISSUES TO THE UTILIZATION OF BIOMASS

    SciTech Connect

    Bruce C. Folkedahl; Darren D. Schmidt; Greg F. Weber; Christopher J. Zygarlicke

    2001-10-01

    The Energy & Environmental Research Center (EERC) is conducting a project to examine the fundamental issues limiting the use of biomass in small industrial steam/power systems in order to increase the future use of this valuable domestic resource. Specifically, the EERC is attempting to elucidate the ash-related problems--grate clinkering and heat exchange surface fouling--associated with cofiring coal and biomass in grate-fired systems. Utilization of biomass in stoker boilers designed for coal can be a cause of concern for boiler operators. Boilers that were designed for low volatile fuels with lower reactivities can experience damaging fouling when switched to higher volatile and more reactive lower-rank fuels, such as when cofiring biomass. Higher heat release rates at the grate can cause more clinkering or slagging at the grate because of higher temperatures. Combustion and loss of volatile matter can start too early for biomass fuels compared to the design fuel, vaporizing alkali and chlorides which then condense on rear walls and heat exchange tube banks in the convective pass of the stoker, causing noticeable increases in fouling. In addition, stoker-fired boilers that switch to biomass blends may encounter new chemical species such as potassium sulfates and various chlorides, in combination with different flue gas temperatures because of changes in fuel heating value which can adversely affect ash deposition behavior. The goal of this project is to identify the primary ash mechanisms related to grate clinkering and heat exchange surface fouling associated with cofiring coal and biomass--specifically wood and agricultural residuals--in grate-fired systems, leading to future mitigation of these problems. The specific technical objectives of the project are: Modification of an existing EERC pilot-scale combustion system to simulate a grate-fired system; Verification testing of the simulator; Laboratory-scale testing and fuel characterization to determine ash

  11. Biomass fuels update. TVAs biomass fuels program

    NASA Astrophysics Data System (ADS)

    1982-02-01

    Equipment was installed and tests were conducted on the ethanol from hardwood project. Location of hardwoods, to improve forest management, and to reduce the cost of harvesting woody biomass was assessed. Substantial underutilized cropland exists in the Valley, and a questionnaire survey was administered to supplement available cropland data. The potential liquid fuel yields and production management practices for alternative starch, sugar, and vegetable oil crops were determined to obtain benchmark data and to evaluate alcohol production from alternative agricultural feedstocks. Workshops were conducted to provide information on production of alcohol.

  12. Heavy metal partitioning in a municipal solid waste incinerator

    SciTech Connect

    Sorum, L.; Fossum, M.; Hustad, J.E.; Evensen, E.

    1997-12-01

    Norway has the following priorities for management of municipal solid waste (MSW) (1) Reduce waste generation and toxic components in waste, (2) Encourage re-use, recycling and energy recovery, and (3) Secure an environmentally safe management of residues. MSW consists of household waste and waste from the service and trade industry delivered to municipal waste treatment plants or recycling schemes. In 1995, a total of 2.7 million tons of MSW (1.26 million tons of household waste and 1.44 million tons of waste from service and trade industry) was handled as follows: 68% was deposited on landfills, 18% was combusted, 13% recycled and 1% composted. Combustion of MSW is handled in five larger plants with energy recovery located in different cities in Norway. In addition, a new incinerator for MSW is planned. This incinerator will have to meet the new emission regulations given by the European Union which are more stringent than the present regulations. Hence, Norway is moving towards more stringent regulations, leading to an increased interest in the environmental aspects of MSW incinerators. During 1995 Trondheim Energy Company carried out an investigation program to examine the residues from the incinerator. Primary attention was on the heavy metals in the bottom ash, fly ash and the landfill leacate. The program was conducted in order to establish more information about characteristics of the residues and thus be able to undertake a sounder evaluation of the environmental aspects of the final treatment of these products. This program was supplementary to the emission analysis done periodically for the flue gas and drain water. The objective of this work has been to establish knowledge about the partitioning of heavy metals through the incinerator and calculate the concentrations of heavy metal in the input MSW.

  13. Municipal solid waste recycling issues

    SciTech Connect

    Lave, L.B.; Hendrickson, C.T.; Conway-Schempf, N.M.; McMichael, F.C.

    1999-10-01

    Municipal solid waste (MSW) recycling targets have been set nationally and in many states. Unfortunately, the definitions of recycling, rates of recycling, and the appropriate components of MSW vary. MSW recycling has been found to be costly for most municipalities compared to landfill disposal. MSW recycling policy should be determined by the cost to the community and to society more generally. In particular, recycling is a good policy only if environmental impacts and the resources used to collect, sort, and recycle a material are less than the environmental impacts and resources needed to provide equivalent virgin material plus the resources needed to dispose of the postconsumer material safely. From a review of the existing economic experience with recycling and an analysis of the environmental benefits (including estimation of external social costs), the authors find that, for most communities, curbside recycling is only justifiable for some postconsumer waste, such as aluminum and other metals. They argue that alternatives to curbside recycling collection should be explored, including product takeback for products with a toxic content (such as batteries) or product redesign to permit more effective product remanufacture.

  14. Energy conversion of biomass in coping with global warming

    SciTech Connect

    Yokoyama, Shin-ya; Ogi, Tomoko; Minowa, Tomoaki

    1993-12-31

    The main purpose of the present paper is to propose energy conversion technologies of biomass in coping with global warming. Among thermochemical conversion, liquid fuel production by high pressure process is mainly introduced. Biomass is a term used to describe materials of biological origin, either purpose-grown or arising as by-products, residues or wastes from forestry, agriculture and food processing. Such biomass is a renewable energy sources dependent on solar energy. Through photosynthesis, plants converts carbon dioxide into organic materials used in their growth. Energy can be recovered from the plant materials by several processes, the simplest way is burning in air. As far as biomass is used in this way, there is no atmospheric accumulation of carbon dioxide making no effect on the Greenhouse Effect, provided that the cycle of regrowth and burning is sustained.

  15. Emergency Planning for Municipal Wastewater Treatment Facilities.

    ERIC Educational Resources Information Center

    Lemon, R. A.; And Others

    This manual for the development of emergency operating plans for municipal wastewater treatment systems was compiled using information provided by over two hundred municipal treatment systems. It covers emergencies caused by natural disasters, civil disorders and strikes, faulty maintenance, negligent operation, and accidents. The effects of such…

  16. CONVERSION OF MUNICIPAL SLUDGE TO OIL

    EPA Science Inventory

    Thermal conversion of municipal sludge to oil has been investigated as a viable alternative for ultimate sludge disposal due to generation of energy. The conversion process using water as a solvent was evaluated in a batch mode using primary and secondary municipal sludges. A wel...

  17. Orientation to Municipal Wastewater Treatment. Training Manual.

    ERIC Educational Resources Information Center

    Office of Water Program Operations (EPA), Cincinnati, OH. National Training and Operational Technology Center.

    Introductory-level material on municipal wastewater treatment facilities and processes is presented. Course topics include sources and characteristics of municipal wastewaters; objectives of wastewater treatment; design, operation, and maintenance factors; performance testing; plant staffing; and laboratory considerations. Chapter topics include…

  18. 40 CFR 40.115-4 - Municipality.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 1 2014-07-01 2014-07-01 false Municipality. 40.115-4 Section 40.115-4 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY GRANTS AND OTHER FEDERAL ASSISTANCE RESEARCH AND DEMONSTRATION GRANTS § 40.115-4 Municipality. (a) Under the Federal Water Pollution Control Act, a city, town, borough, county,...

  19. 40 CFR 40.115-4 - Municipality.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 1 2013-07-01 2013-07-01 false Municipality. 40.115-4 Section 40.115-4 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY GRANTS AND OTHER FEDERAL ASSISTANCE RESEARCH AND DEMONSTRATION GRANTS § 40.115-4 Municipality. (a) Under the Federal Water Pollution Control Act, a city, town, borough, county,...

  20. Alkali activation processes for incinerator residues management.

    PubMed

    Lancellotti, Isabella; Ponzoni, Chiara; Barbieri, Luisa; Leonelli, Cristina

    2013-08-01

    Incinerator bottom ash (BA) is produced in large amount worldwide and in Italy, where 5.1 millionstons of municipal solid residues have been incinerated in 2010, corresponding to 1.2-1.5 millionstons of produced bottom ash. This residue has been used in the present study for producing dense geopolymers containing high percentage (50-70 wt%) of ash. The amount of potentially reactive aluminosilicate fraction in the ash has been determined by means of test in NaOH. The final properties of geopolymers prepared with or without taking into account this reactive fraction have been compared. The results showed that due to the presence of both amorphous and crystalline fractions with a different degree of reactivity, the incinerator BA geopolymers exhibit significant differences in terms of Si/Al ratio and microstructure when reactive fraction is considered. PMID:23756039

  1. Municipal waste-to-energy technology assessment

    SciTech Connect

    Barrett, R.E.; Krause, H.H., Jr.; Engdahl, R.B.; Levy, A.; Oxley, J.H. )

    1992-01-01

    Two major technologies are available to burn municipal solid waste (MSW) to generate steam for the production of electricity: mass-burn and refuse-derived fuel (RDF) systems. Mass-burn systems process as-received waste directly in a combustor, such as a reciprocating, rotary, or roller-grate furnace, with only limited removal of undesirable objects. Refuse-derived-fuel (RDF) systems first process the waste to produce refuse-derived fuel via shredding and other operations before combustion in spreader-stoker, fluidized-bed, and other suitable combustors. Although mass-burn systems with specially designed grates are now considered proven technology, there is much interest in RDF systems, because RDF can be used in a wide range of combustors, including some utility power plants of conventional design. However, a number of technical issues remain for both mass-burn and RDF-firing systems, and further research is warranted. Disposal of the ash residues from the combustor and/or the waste from the air-pollution control equipment is a major issue preventing more widespread use of this technology. Selection of materials of construction is also an important issue. Continuous-emission-monitoring requirements may be exceeding the technical capabilities for reliable, long-term operation. The occasional receipt of biologically active waste or waste containing heavy metals is still a troublesome issue. Dioxin emissions seem to be a problem only in plants of early design, although the issue of dioxin emissions continues to be a major one in permit applications and public relations. 58 refs., 28 figs., 16 tabs.

  2. Sludge minimization in municipal wastewater treatment by polyhydroxyalkanoate (PHA) production.

    PubMed

    Valentino, Francesco; Morgan-Sagastume, Fernando; Fraraccio, Serena; Corsi, Giovanna; Zanaroli, Giulio; Werker, Alan; Majone, Mauro

    2015-05-01

    An innovative approach has been recently proposed in order to link polyhydroxyalkanoates (PHA) production with sludge minimization in municipal wastewater treatment, where (1) a sequencing batch reactor (SBR) is used for the simultaneous municipal wastewater treatment and the selection/enrichment of biomass with storage ability and (2) the acidogenic fermentation of the primary sludge is used to produce a stream rich in volatile fatty acids (VFAs) as the carbon source for the following PHA accumulation stage. The reliability of the proposed process has been evaluated at lab scale by using substrate synthetic mixtures for both stages, simulating a low-strength municipal wastewater and the effluent from primary sludge fermentation, respectively. Six SBR runs were performed under the same operating conditions, each time starting from a new activated sludge inoculum. In every SBR run, despite the low VFA content (10% chemical oxygen demand, COD basis) of the substrate synthetic mixture, a stable feast-famine regime was established, ensuring the necessary selection/enrichment of the sludge and soluble COD removal to 89%. A good process reproducibility was observed, as also confirmed by denaturing gradient gel electrophoresis (DGGE) analysis of the microbial community, which showed that a high similarity after SBR steady-state had been reached. The main variation factors of the storage properties among different runs were uncontrolled changes of settling properties which in turn caused variations of both sludge retention time and specific organic loading rate. In the following accumulation batch tests, the selected/enriched consortium was able to accumulate PHA with good rate (63 mg CODPHA g CODXa(-1) h(-1)) and yield (0.23 CODPHA CODΔS(-1)) in spite that the feeding solution was different from the acclimation one. Even though the PHA production performance still requires optimization, the proposed process has a good potential especially if coupled to minimization of

  3. 1990 Washington State directory of biomass energy facilities

    SciTech Connect

    Deshaye, J.A.; Kerstetter, J.D.

    1990-01-01

    This second edition is an update of biomass energy production and use in Washington State for 1989. The purpose of this directory is to provide a listing of known biomass users within the state and some basic information about their facilities. The data can be helpful to persons or organizations considering the use of biomass fuels. The directory is divided into three sections of biomass facilities with each section containing a map of locations and a data summary table. In addition, a conversion table, a glossary and an index are provided in the back of the directory. The first section deals with biogas production from wastewater treatment plants. The second section provides information on the wood combustion facilities in the state. This section is subdivided into two categories. The first is for facilities connected with the forest products industries. The second category include other facilities using wood for energy. The third section is composed of three different types of biomass facilities -- ethanol, municipal solid waste, and solid fuel processing. Biomass facilities included in this directory produce over 64 trillion Btu (British thermal units) per year. Wood combustion facilities account for 91 percent of the total. Biogas and ethanol facilities each produce close to 800 billion Btu per year, MSW facilities produce 1845 billion BTU, and solid fuel processing facilities produce 2321 billion Btu per year. To put these numbers in perspective, Washington's industrial section uses 200 trillion Btu of fuels per year. Therefore, biomass fuels used and/or produced by facilities listed in this directory account for nearly 32 percent of the state's total industrial fuel demand. This is a sizable contribution to the state's energy needs.

  4. 1990 Washington State directory of biomass energy facilities

    SciTech Connect

    Deshaye, J.A.; Kerstetter, J.D.

    1990-12-31

    This second edition is an update of biomass energy production and use in Washington State for 1989. The purpose of this directory is to provide a listing of known biomass users within the state and some basic information about their facilities. The data can be helpful to persons or organizations considering the use of biomass fuels. The directory is divided into three sections of biomass facilities with each section containing a map of locations and a data summary table. In addition, a conversion table, a glossary and an index are provided in the back of the directory. The first section deals with biogas production from wastewater treatment plants. The second section provides information on the wood combustion facilities in the state. This section is subdivided into two categories. The first is for facilities connected with the forest products industries. The second category include other facilities using wood for energy. The third section is composed of three different types of biomass facilities -- ethanol, municipal solid waste, and solid fuel processing. Biomass facilities included in this directory produce over 64 trillion Btu (British thermal units) per year. Wood combustion facilities account for 91 percent of the total. Biogas and ethanol facilities each produce close to 800 billion Btu per year, MSW facilities produce 1845 billion BTU, and solid fuel processing facilities produce 2321 billion Btu per year. To put these numbers in perspective, Washington`s industrial section uses 200 trillion Btu of fuels per year. Therefore, biomass fuels used and/or produced by facilities listed in this directory account for nearly 32 percent of the state`s total industrial fuel demand. This is a sizable contribution to the state`s energy needs.

  5. Combustion of Micropowdered Biomass

    NASA Astrophysics Data System (ADS)

    Geil, Ethan; Thorne, Robert

    2009-03-01

    Combustion of finely powdered biomass has the potential to replace heating oil, which accounts for a significant fraction of US oil consumption, in heating, cooling and local power generation applications. When ground to 30-150 micron powders and dispersed in air, wood and other biomass can undergo deflagrating combustion, as occurs with gaseous and dispersed liquid fuels. Combustion is very nearly complete, and in contrast to sugar/starch or cellulose-derived ethanol, nearly all of the available plant mass is converted to usable energy so the economics are much more promising. We are exploring the fundamental combustion science of biomass powders in this size range. In particular, we are examining how powder size, powder composition (including the fraction of volatile organics) and other parameters affect the combustion regime and the combustion products.

  6. Sustainable Biomass Supply Systems

    SciTech Connect

    Erin Searcy; Dave Muth; Erin Wilkerson; Shahab Sokansanj; Bryan Jenkins; Peter Titman; Nathan Parker; Quinn Hart; Richard Nelson

    2009-04-01

    The U.S. Department of Energy (DOE) aims to displace 30% of the 2004 gasoline use (60 billion gal/yr) with biofuels by 2030 as outlined in the Energy Independence and Security Act of 2007, which will require 700 million tons of biomass to be sustainably delivered to biorefineries annually. Lignocellulosic biomass will make an important contribution towards meeting DOE’s ethanol production goals. For the biofuels industry to be an economically viable enterprise, the feedstock supply system (i.e., moving the biomass from the field to the refinery) cannot contribute more that 30% of the total cost of the biofuel production. The Idaho National Laboratory in collaboration with Oak Ridge National Laboratory, University of California, Davis and Kansas State University are developing a set of tools for identifying economical, sustainable feedstocks on a regional basis based on biorefinery siting.

  7. Effects of biochar amendments on soil microbial biomass and activity.

    PubMed

    Zhang, H; Voroney, R P; Price, G W

    2014-11-01

    Environmental benefits reported in the literature of using biochar as a soil amendment are generally increased microbial activity and reduced greenhouse gas (GHG) emissions. This study determined the effects of amendment with biomass feedstocks (spent coffee grounds, wood pellets, and horse bedding compost) and that of biochars (700°C) produced from these feedstocks on soil microbial biomass (C and N) and activity. Soils were amended with these substrates at 0.75% by weight and incubated for up to 175 d under laboratory conditions. Biochar residual effects on soil microbial activity were also studied by amending these soils with either ammonium nitrate (NHNO, 35 mg N kg) or with glucose (864 mg C kg) plus NHNO. Soil microbial biomass C and N, net N mineralization, and CO, NO, and CH emissions were measured. Amendment with biomass feedstocks significantly increased soil microbial biomass and activity, whereas amendment with the biochars had no significant effect. Also, biochar amendment had no significant effect on either net N mineralization or NO and CH emissions from soil. These results indicate that production of biochars at this high temperature eliminated potential substrates. Microbial biomass C in biochar-amended and unamended soils was not significantly different following additions of NHNO or glucose plus NHNO, suggesting that microbial access to otherwise labile C and N was not affected. This study shows that biochars produced at 700°C, regardless of feedstock source, do not enhance soil microbial biomass or activity. PMID:25602227

  8. Biogas production from anaerobic digestion of Spirulina maxima algal biomass

    SciTech Connect

    Rejean Samson; Anh LeDuy

    1982-08-01

    Spirulina maxima algal biomass could be used as the sole nutrient for the production of biogas by anaerobic digestion process. It is relatively simple to adapt the municipal sewage sludge to this new substrate. The adapted sludge is very stable. Under nonoptimal conditions, the methane yield and productivity obtained were 0.26 m/sup 3//(kg VS added day) and 0.26 m/sup 3//(kg VS added day), respectively, with the semicontinuous, daily fed, anaerobic digestion having loading rate of 0.97 kg VS/(m/sup 3/ day), retention time of 33 days and temperature of 30/sup 0/C.

  9. Minimally refined biomass fuel

    DOEpatents

    Pearson, Richard K.; Hirschfeld, Tomas B.

    1984-01-01

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water solubilizes the carbohydrates; and the alcohol aids in the combustion of the carbohydrate and reduces the vicosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  10. Fixed Bed Biomass Gasifier

    SciTech Connect

    Carl Bielenberg

    2006-03-31

    The report details work performed by Gazogen to develop a novel biomass gasifier for producimg electricity from commercially available hardwood chips. The research conducted by Gazogen under this grant was intended to demonstrate the technical and economic feasibility of a new means of producing electricity from wood chips and other biomass and carbonaceous fuels. The technical feasibility of the technology has been furthered as a result of the DOE grant, and work is expected to continue. The economic feasibility can only be shown when all operational problems have been overocme. The technology could eventually provide a means of producing electricity on a decentralized basis from sustainably cultivated plants or plant by-products.

  11. Clean fuels from biomass

    NASA Technical Reports Server (NTRS)

    Hsu, Y.-Y.

    1976-01-01

    The paper discusses the U.S. resources to provide fuels from agricultural products, the present status of conversion technology of clean fuels from biomass, and a system study directed to determine the energy budget, and environmental and socioeconomic impacts. Conversion processes are discussed relative to pyrolysis and anaerobic fermentation. Pyrolysis breaks the cellulose molecules to smaller molecules under high temperature in the absence of oxygen, wheras anaerobic fermentation is used to convert biomass to methane by means of bacteria. Cost optimization and energy utilization are also discussed.

  12. Biomass production in Florida

    SciTech Connect

    Smith, W.H.; Dowd, M.L.

    1981-08-01

    Florida posseses climatic, land, and water resources favorable for abundant biomass production. Therefore, a statewide program has been initiated to determine adapted species for the available array of production sites. Plant resources under investigation include woody, aquatic, grasses, hydrocarbon, and root crop species. The goal is to produce a continuous stream of biomass for the various biofuel conversion options. Preliminary yields from energy cropping experiments range from about 10 to nearly 90 metric tons per hectare per year, depending on the crop and the production systems employed. (Refs. 15).

  13. Emissions from Biomass Burning in the Yucatan

    NASA Technical Reports Server (NTRS)

    Yokelson, R.; Crounse, J. D.; DeCarlo, P. F.; Karl, T.; Urbanski, S.; Atlas, E.; Campos, T.; Shinozuka, Y.; Kapustin, V.; Clarke, A. D.; Weinheimer, A.; Knapp, D. J.; Montzka, D. D.; Holloway, J.; Weibring, P.; Flocke, F.; Zheng, W.; Toohey, D.; Wennberg, P. O.; Wiedinmyer, C.; Mauldin, L.; Fried, A.; Richter, D.; Walega, J.; Jimenez, J. L.

    2009-01-01

    In March 2006 two instrumented aircraft made the first detailed field measurements of biomass burning (BB) emissions in the Northern Hemisphere tropics as part of the MILAGRO project. The aircraft were the National Center for Atmospheric Research C-130 and a University of Montana/US Forest Service Twin Otter. The initial emissions of up to 49 trace gas or particle species were measured from 20 deforestation and crop residue fires on the Yucatan peninsula. This included two trace gases useful as indicaters of BB (HCN and acetonitrile) and several rarely, or never before, measured species: OH, peroxyacetic acid, propanoic acid, hydrogen peroxide, methane sulfonic acid, and sulfuric acid. Crop residue fires emitted more organic acids and ammonia than deforestation fires, but the emissions from the main fire types were otherwise fairly similar. The Yucatan fires emitted unusually amounts of SO2 and particle chloride, likely due to a strong marine influence on the peninsula.

  14. Determination of saccharides and ethanol from biomass conversion using Raman spectroscopy: Effects of pretreatment and enzyme composition

    SciTech Connect

    Shih, Chien-Ju

    2010-01-01

    bioethanol from biomass, has grown significantly in the past decade due to the high demand and rising costs of fossil fuels. More than 3 percent of the energy consumption in the U.S. is derived from renewable biomass, mostly through industrial heat and steam production by the pulp and paper industry, and electricity generation from municipal solid waste (MSW) and forest industry residues. The utilization of food-based biomass to make fuels has been widely criticized because it may increase food shortages throughout the world and raise the cost of food. Thus, nonfood-based and plentiful lignocellulosic feedstocks, such as corn stover, perennial grass, bagasse, sorghum, wheat/rice straw, herbaceous and woody crops, have great potential to be new bio-renewable sources for energy production. Given that many varieties of biomass are available, there is need for a rapid, simple, high-throughput method to screen the conversion of many plant varieties. The most suitable species for each geographic region must be determined, as well as the optimal stage of harvest, impacts of environmental conditions (temperature, soil, pH, etc.). Various genetically modified plants should be studied in order to establish the desired biomass in bioethanol production. The main screening challenge, however, is the complexity of plant cell wall structures that make reliable and sensitive analysis difficult. To date, one of the most popular methods to produce lignocellulosic ethanol is to perform enzymatic hydrolysis followed by fermentation of the hydrolysate with yeast. There are several vital needs related to the field of chemistry that have been suggested as primary research foci needed to effectively improve lignocellulosic ethanol production. These topics include overcoming the recalcitrance of cellulosic biomass, the pervasiveness of pretreatment, advanced biological processing and better feedstocks. In this thesis, a novel approach using Raman spectroscopy has been developed to address important

  15. Method for pretreating lignocellulosic biomass

    SciTech Connect

    Kuzhiyil, Najeeb M.; Brown, Robert C.; Dalluge, Dustin Lee

    2015-08-18

    The present invention relates to a method for pretreating lignocellulosic biomass containing alkali and/or alkaline earth metal (AAEM). The method comprises providing a lignocellulosic biomass containing AAEM; determining the amount of the AAEM present in the lignocellulosic biomass; identifying, based on said determining, the amount of a mineral acid sufficient to completely convert the AAEM in the lignocellulosic biomass to thermally-stable, catalytically-inert salts; and treating the lignocellulosic biomass with the identified amount of the mineral acid, wherein the treated lignocellulosic biomass contains thermally-stable, catalytically inert AAEM salts.

  16. Plant Biomass Leaching for Nutrient Recovery in Closed Loop Systems Project

    NASA Technical Reports Server (NTRS)

    Zeitlin, Nancy P.; Wheeler, Raymond (Compiler); Lunn, Griffin

    2015-01-01

    Plants will be important for food and O2 production during long term human habitation in space. Recycling of nutrients (e.g., from waste materials) could reduce the resupply costs of fertilizers for growing these plants. Work at NASA's Kennedy Space Center has shown that ion exchange resins can extract fertilizer (plant essential nutrients) from human waste water, after which the residual brine could be treated with electrodialysis to recover more water and produce high value chemicals (e.g., acids and bases). In habitats with significant plant production, inedible biomass becomes a major source of solid waste. To "close the loop" we also need to recover useful nutrients and fertilizer from inedible biomass. We are investigating different approaches to retrieve nutrients from inedible plant biomass, including physical leaching with water, processing the biomass in bioreactors, changing the pH of leaching processing, and/or conducting multiple leaches of biomass residues.

  17. Prospects for the use of municipal solid wastes as secondary energy resources in Russia

    NASA Astrophysics Data System (ADS)

    Tugov, A. N.

    2013-09-01

    An analysis is made of both domestic and world experience in the field of energy recovery from municipal solid wastes (MSWs). The results are presented of an investigation of solid residues being formed in the process of thermal treatment of MSWs at the garbage-burning plants located in Moscow. The feasibility of utilization of ash and slag at thermal power plants incinerating MSW is shown.

  18. Biomass stakeholder views and concerns: Environmental groups and some trade association

    SciTech Connect

    Peelle, E.

    2000-01-01

    This exploratory study of the views and concerns of 25 environmental organizations found high interest and concern about which biomass feedstocks would be used and how these biomass materials would be converted to energy. While all favored renewable energy over fossil or nuclear energy, opinion diverged over whether energy crops, residues, or both should be the primary source of a biomass/bioenergy fuel cycle. About half of the discussants favored biomass ``in general'' as a renewable energy source, while the others were distributed about equally over five categories, from favor-with-conditions, uncertain, skeptical, opposed, to ``no organizational policy.''

  19. Municipal waste thermal oxidation system

    SciTech Connect

    Pope, G.M.; Kerr, D.F.

    1990-07-17

    This patent describes a municipal waste incinerator. It comprises: a primary combustion chamber for receiving waste materials to be burned to yield combustion gases; means for transporting the combustion gases to a secondary combustion unit for re-igniting the combustion gases; the secondary combustion unit including a chamber having a bottom feed opening for receiving the combustion gases, a top exhaust opening, and an intermediate choke and air mixing section; an air mixing means disposed in the air mixing section for supplying outside air from points around the periphery of the air mixing section, and being directed toward the center thereof; means for forming a flue gas cone having an upwardly directed apex, the cone forming means including the intermediate choke and the air-mixing means; and re-ignition burners.

  20. Biogasification of municipal solid wastes

    NASA Astrophysics Data System (ADS)

    Diaz, L. F.; Savage, G. M.; Trezek, G. J.; Golueke, C. G.

    1981-06-01

    A series of experiments on the anaerobic digestion of the organic fraction of municipal refuse was performed. The refuse fraction used in the study was one of the portions segregated in a resource recovery system developed at the University of California, Berkeley. The scale of experiments includes 4, 9, and 1600-L digesters. The refuse used as feed was enriched by the addition of raw sewage sludge in various ratios, i.e., from 0-100 percent of the total volatile solids. No other sources of nutrients or chemicals for pH control were introduced into the reactors. Organic loading rates ranging from 1.1-6.4 g of volatile solids/Ld were obtained. Typical hydraulic detention times were 15 to 30 days. Temperatures were kept within the range of 72-104 F (22-40 C). Digestion efficiency was based on energy conversion and gas production.

  1. Evaluation of Biomass Availability for Biogas Production at Regional Level

    NASA Astrophysics Data System (ADS)

    Dzene, I.; Bodescu, F.

    2009-01-01

    Currently available data were used in an integrated deterministic modelling approach to assess the total biomass availability. The conceptual approach of combining the benefits of relational database and GIS modelling was tested in two eastern European countries - in Latvia and Romania, both located in different bio-geographical regions. The developed system has proven its efficiency in dealing with heterogeneity in different levels of complexity regarding environmental and ecological structures. The overall approach of assessing the biomass resources was first to estimate the quantity of material generated from municipal waste and agricultural practices in each of research areas. The quantity of material that could be recovered from these practices was then taken into account and the technical and environmental constraints associated with other site factors were evaluated. As a result, the particular areas with high, medium and low potential in each country were identified.

  2. Bioenergy: Agricultural Crop Residues

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The increasing cost of fossil fuels especially natural gas and petroleum as well as a desire to curtail greenhouse gas emissions are driving the expansion of bioenergy. Plant biomass (woody, grain and nongrain) is a potential energy source. Prior to the Industrial Revolution, plant biomass was a maj...

  3. Hybrid biothermal conversion of biomass to methane

    SciTech Connect

    Srivastava, V.J.; Novil, M.; Tarman, P.B.; Chynoweth, D.P.

    1981-01-01

    Combining biochemical and thermochemical gasification in the Biothermgas process results in an economic process with a higher conversion efficiency and a greater choice of feedstocks that can be processed than biological or thermochemical processes used separately. The biogasification component can receive high mositure feeds, can convert major portions of feed at low temperature and pressure, and can be used for methanation of synthesis gas. The thermochemical gasifier converts refractory organic residues from the anaerobic digesters and provides gases than can be used for heating, mixing, and simulating methanogenesis in the biological component. The operating parameters for gasification of Bermuda grass by the Biothermgas process and for gasification of municipal solid waste-sewage sludge blend by the Biothermgas process with biomethanation are reported.

  4. Switchgrass for biomass energy

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Switchgrass (Panicum virgatum) is a native warm-season grass and is the model herbaceous perennial biomass energy feedstock for the USA. More than 75-years of experience confirm that switchgrass will be productive and sustainable on rain-fed marginally-productive cropland east of the 100th meridian....

  5. Biomass Scenario Model

    SciTech Connect

    2015-09-01

    The Biomass Scenario Model (BSM) is a unique, carefully validated, state-of-the-art dynamic model of the domestic biofuels supply chain which explicitly focuses on policy issues, their feasibility, and potential side effects. It integrates resource availability, physical/technological/economic constraints, behavior, and policy. The model uses a system dynamics simulation (not optimization) to model dynamic interactions across the supply chain.

  6. Sustainable biomass removal rates

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Crop non-grain biomass (straw or stover) is a potential bioenergy feedstock suitable for thermochemical (controlled combustion) or fermentation to ethanol platforms. It is critical to prevent soil degradation; thereby, maintain soil's capacity to produce food, feed, fiber and fuel. Overharvest of cr...

  7. Activated carbon from biomass

    NASA Astrophysics Data System (ADS)

    Manocha, S.; Manocha, L. M.; Joshi, Parth; Patel, Bhavesh; Dangi, Gaurav; Verma, Narendra

    2013-06-01

    Activated carbon are unique and versatile adsorbents having extended surface area, micro porous structure, universal adsorption effect, high adsorption capacity and high degree of surface reactivity. Activated carbons are synthesized from variety of materials. Most commonly used on a commercial scale are cellulosic based precursors such as peat, coal, lignite wood and coconut shell. Variation occurs in precursors in terms of structure and carbon content. Coir having very low bulk density and porous structure is found to be one of the valuable raw materials for the production of highly porous activated carbon and other important factor is its high carbon content. Exploration of good low cost and non conventional adsorbent may contribute to the sustainability of the environment and offer promising benefits for the commercial purpose in future. Carbonization of biomass was carried out in a horizontal muffle furnace. Both carbonization and activation were performed in inert nitrogen atmosphere in one step to enhance the surface area and to develop interconnecting porosity. The types of biomass as well as the activation conditions determine the properties and the yield of activated carbon. Activated carbon produced from biomass is cost effective as it is easily available as a waste biomass. Activated carbon produced by combination of chemical and physical activation has higher surface area of 2442 m2/gm compared to that produced by physical activation (1365 m2/gm).

  8. Biomass Program Factsheet

    SciTech Connect

    2010-03-01

    The emerging U.S. bioindustry is using a range of biomass resources to provide a secure and growing supply of transportation fuels and electric power. Displacing an increasing portion of our imported oil with renewable, domestic bioenergy will provide clear benefits:Reduced greenhouse gas (GHG) emissions; A cleaner, more secure energy future; Sustainable transportation fuels; Opportunities for economic growth

  9. Municipal sewage sludge as fertilizer. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    1996-06-01

    The bibliography contains citations concerning the use of sewage sludge as forestry and farm crop fertilizer. References discuss degassed biomass, fertilizer-grade residues, compost fertilizers, biological conversion of organic wastes, organic environmental pollution, and iron salts. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  10. Biomass Burning Data and Information

    Atmospheric Science Data Center

    2015-04-21

    ... of total amount of biomass burned. These data may be used in general circulation models (GCMs) and in photochemical models of the ... Biomass Burning Discipline:  Tropospheric Chemistry Field Campaigns Aerosols Platform:  ...

  11. Enzymes for improved biomass conversion

    DOEpatents

    Brunecky, Roman; Himmel, Michael E.

    2016-02-02

    Disclosed herein are enzymes and combinations of the enzymes useful for the hydrolysis of cellulose and the conversion of biomass. Methods of degrading cellulose and biomass using enzymes and cocktails of enzymes are also disclosed.

  12. Synfuels from biomass grow slowly

    SciTech Connect

    Black, J.; Wedlock, J.C.

    1982-01-01

    Current developments in the manufacture of synfuels are discussed with emphasis on the sources of biomass suitable for synfuels production, processes for converting biomass to synfuels, and the economics of the technology. The sources include wood, nonwood crops, root crops, aquatic biomass, and oils from plants such as soybean, safflower, and peanut. The biomass conversion processes discussed include pyrolysis, gasification, liquefaction, and aerobic and anaerobic digestion.

  13. Fungal bioconversion of lignocellulosic residues; opportunities & perspectives.

    PubMed

    Dashtban, Mehdi; Schraft, Heidi; Qin, Wensheng

    2009-01-01

    The development of alternative energy technology is critically important because of the rising prices of crude oil, security issues regarding the oil supply, and environmental issues such as global warming and air pollution. Bioconversion of biomass has significant advantages over other alternative energy strategies because biomass is the most abundant and also the most renewable biomaterial on our planet. Bioconversion of lignocellulosic residues is initiated primarily by microorganisms such as fungi and bacteria which are capable of degrading lignocellulolytic materials. Fungi such as Trichoderma reesei and Aspergillus niger produce large amounts of extracellular cellulolytic enzymes, whereas bacterial and a few anaerobic fungal strains mostly produce cellulolytic enzymes in a complex called cellulosome, which is associated with the cell wall. In filamentous fungi, cellulolytic enzymes including endoglucanases, cellobiohydrolases (exoglucanases) and beta-glucosidases work efficiently on cellulolytic residues in a synergistic manner. In addition to cellulolytic/hemicellulolytic activities, higher fungi such as basidiomycetes (e.g. Phanerochaete chrysosporium) have unique oxidative systems which together with ligninolytic enzymes are responsible for lignocellulose degradation. This review gives an overview of different fungal lignocellulolytic enzymatic systems including extracellular and cellulosome-associated in aerobic and anaerobic fungi, respectively. In addition, oxidative lignocellulose-degradation mechanisms of higher fungi are discussed. Moreover, this paper reviews the current status of the technology for bioconversion of biomass by fungi, with focus on mutagenesis, co-culturing and heterologous gene expression attempts to improve fungal lignocellulolytic activities to create robust fungal strains. PMID:19774110

  14. Fungal Bioconversion of Lignocellulosic Residues; Opportunities & Perspectives

    PubMed Central

    Dashtban, Mehdi; Schraft, Heidi; Qin, Wensheng

    2009-01-01

    The development of alternative energy technology is critically important because of the rising prices of crude oil, security issues regarding the oil supply, and environmental issues such as global warming and air pollution. Bioconversion of biomass has significant advantages over other alternative energy strategies because biomass is the most abundant and also the most renewable biomaterial on our planet. Bioconversion of lignocellulosic residues is initiated primarily by microorganisms such as fungi and bacteria which are capable of degrading lignocellulolytic materials. Fungi such as Trichoderma reesei and Aspergillus niger produce large amounts of extracellular cellulolytic enzymes, whereas bacterial and a few anaerobic fungal strains mostly produce cellulolytic enzymes in a complex called cellulosome, which is associated with the cell wall. In filamentous fungi, cellulolytic enzymes including endoglucanases, cellobiohydrolases (exoglucanases) and β-glucosidases work efficiently on cellulolytic residues in a synergistic manner. In addition to cellulolytic/hemicellulolytic activities, higher fungi such as basidiomycetes (e.g. Phanerochaete chrysosporium) have unique oxidative systems which together with ligninolytic enzymes are responsible for lignocellulose degradation. This review gives an overview of different fungal lignocellulolytic enzymatic systems including extracellular and cellulosome-associated in aerobic and anaerobic fungi, respectively. In addition, oxidative lignocellulose-degradation mechanisms of higher fungi are discussed. Moreover, this paper reviews the current status of the technology for bioconversion of biomass by fungi, with focus on mutagenesis, co-culturing and heterologous gene expression attempts to improve fungal lignocellulolytic activities to create robust fungal strains. PMID:19774110

  15. Enhanced nutrient removal from municipal wastewater assisted by mixotrophic microalgal cultivation using glycerol.

    PubMed

    Gupta, Prabuddha L; Choi, Hee Jeong; Lee, Seung-Mok

    2016-05-01

    In a present study, nutrient removal from municipal wastewater by Chlorella vulgaris and Nannochloropsis oculata was investigated by using mixotrophic cultivation with glycerol (0 to 5 g/L). Performance parameters were assessed by estimating the removal of total nitrogen, total phosphorus, chemical oxygen demand (COD), biomass growth, chlorophyll content, lipid yield, and fatty acids. With the addition of 2 g/L glycerol, a maximum biomass productivity of 56 mg/L/day was achieved in the mixotrophic culture of C. vulgaris within 12 days. The mixotrophic culture showed a 30-fold increase in biomass productivity compared to the wastewater without any glycerol. However, the highest total nitrogen removal (80.62 %), total phosphate removal (60.72 %), and COD removal (96.3 %) was observed in the N. oculata culture supplemented with 3, 5, and 1 g/L glycerol, respectively. These results suggest that mixotrophic cultivation using glycerol offers great potential in the production of renewable biomass, waste water treatment, and consequent production of high-value microalgal oil. Graphical Abstract Simultaneous biomass production and nutrient removal using microalgae cultivated in wastewater supplemented with glycerol. PMID:26867689

  16. Municipal waste management in Sicily: Practices and challenges

    SciTech Connect

    Messineo, Antonio Panno, Domenico

    2008-07-01

    There are numerous problems yet to be solved in waste management and although efforts towards waste recovery and recycling have been made, landfills are still the most common method used in the EU and many other industrialised countries. Thermal disposal, particularly incineration, is a tested and viable alternative. In 2004, only 11% of the annual waste production of Italy was incinerated. Sicily, with over five million inhabitants, is the second largest region in Italy where waste management is now a critical problem. The use of landfills can no longer be considered a satisfactory environmental solution; therefore, new methods have to be chosen and waste-to-energy plants could provide an answer. This paper gives details of municipal solid waste management in Sicily following a new Waste Management Plan. Four waste-to-energy plants will generate electricity through a steam cycle; the feedstock will become the residue after material recovery, which is calculated as 20-40% weight of the collected municipal solid waste.

  17. Municipal waste management in Sicily: practices and challenges.

    PubMed

    Messineo, Antonio; Panno, Domenico

    2008-01-01

    There are numerous problems yet to be solved in waste management and although efforts towards waste recovery and recycling have been made, landfills are still the most common method used in the EU and many other industrialised countries. Thermal disposal, particularly incineration, is a tested and viable alternative. In 2004, only 11% of the annual waste production of Italy was incinerated. Sicily, with over five million inhabitants, is the second largest region in Italy where waste management is now a critical problem. The use of landfills can no longer be considered a satisfactory environmental solution; therefore, new methods have to be chosen and waste-to-energy plants could provide an answer. This paper gives details of municipal solid waste management in Sicily following a new Waste Management Plan. Four waste-to-energy plants will generate electricity through a steam cycle; the feedstock will become the residue after material recovery, which is calculated as 20-40% weight of the collected municipal solid waste. PMID:17604152

  18. Heavy metals content of municipal wastewater and sludges in Kuwait.

    PubMed

    Al Enezi, G; Hamoda, M F; Fawzi, N

    2004-01-01

    Municipal wastewater may contain heavy metals, which are hazardous to the environment and humans. With stringent regulations concerning water reuse and sludge utilization in agriculture, there is a great need to determine levels of heavy metals in liquid wastes, sludges and agricultural crops. The state of Kuwait has programs to utilize waste sludge produced at wastewater treatment plants as soil conditioner and fertilizer for greenery and agricultural development projects and to reuse treated wastewater effluents in irrigation. The common metals found in Kuwait's raw wastewater and sludge are Cd, Cr, Cu, Hg, Ni, Pb, and Zn. The effects of accumulation of heavy metals in soil are long lasting and even permanent. In this study, the variations in the concentration levels of heavy metals were measured in wastewater and sludge produced at Ardiya municipal wastewater treatment plant in Kuwait. A relationship was observed between the concentrations of heavy metals in treated wastewater and sludge used for agriculture and the level of accumulated heavy metals found in residual tissues of some crops. PMID:15027823

  19. Reburn system with feedlot biomass

    DOEpatents

    Annamalai, Kalyan; Sweeten, John M.

    2005-12-13

    The present invention pertains to the use of feedlot biomass as reburn fuel matter to reduce NO.sub.x emissions. According to one embodiment of the invention, feedlot biomass is used as the reburn fuel to reduce NO.sub.x. The invention also includes burners and boiler in which feedlot biomass serves a reburn fuel.

  20. Potential soil quality impact of harvesting crop residues for biofuels

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Humankind is in the midst of one of the greatest technological, environmental and social transitions since the industrial revolution, as we strive to replace fossil energy with renewable biomass resources. This presentation will (1) briefly review increased public interest in harvesting crop residue...

  1. Enzymatic Conversion of Aromatic Compounds Obtained from Crop Residues

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biomass obtained from crop residues and the related processing wastes typically contain minor amounts of aromatic compounds such as ferulic and p-coumaric acids. These compounds occur as esters and ethers associated with plant cell wall structures and as components of lignin. These compounds exhibit...

  2. Honey Lake hybrid geothermal wood residue power project

    SciTech Connect

    Toland, J.

    1981-05-01

    The Honey Lake Hybrid Geothermal Wood Residue Power Project with a planned output of 50 MW is undergoing feasibility studies funded by GeoProducts Corporation, Department of Water Resources, State of California, US Department of Energy and the Forest Service, USDA. The outlook is optimistic. It is reliably estimated that the required volume of woody biomass can be made available without environmental degradation.

  3. Rail vs truck transport of biomass.

    PubMed

    Mahmudi, Hamed; Flynn, Peter C

    2006-01-01

    This study analyzes the economics of transshipping biomass from truck to train in a North American setting. Transshipment will only be economic when the cost per unit distance of a second transportation mode is less than the original mode. There is an optimum number of transshipment terminals which is related to biomass yield. Transshipment incurs incremental fixed costs, and hence there is a minimum shipping distance for rail transport above which lower costs/km offset the incremental fixed costs. For transport by dedicated unit train with an optimum number of terminals, the minimum economic rail shipping distance for straw is 170 km, and for boreal forest harvest residue wood chips is 145 km. The minimum economic shipping distance for straw exceeds the biomass draw distance for economically sized centrally located power plants, and hence the prospects for rail transport are limited to cases in which traffic congestion from truck transport would otherwise preclude project development. Ideally, wood chip transport costs would be lowered by rail transshipment for an economically sized centrally located power plant, but in a specific case in Alberta, Canada, the layout of existing rail lines precludes a centrally located plant supplied by rail, whereas a more versatile road system enables it by truck. Hence for wood chips as well as straw the economic incentive for rail transport to centrally located processing plants is limited. Rail transshipment may still be preferred in cases in which road congestion precludes truck delivery, for example as result of community objections. PMID:16915633

  4. Valorization of biomass: deriving more value from waste.

    PubMed

    Tuck, Christopher O; Pérez, Eduardo; Horváth, István T; Sheldon, Roger A; Poliakoff, Martyn

    2012-08-10

    Most of the carbon-based compounds currently manufactured by the chemical industry are derived from petroleum. The rising cost and dwindling supply of oil have been focusing attention on possible routes to making chemicals, fuels, and solvents from biomass instead. In this context, many recent studies have assessed the relative merits of applying different dedicated crops to chemical production. Here, we highlight the opportunities for diverting existing residual biomass--the by-products of present agricultural and food-processing streams--to this end. PMID:22879509

  5. Vehicular fuels and oxychemicals from biomass thermochemical tars

    SciTech Connect

    Soltes, E.J.; Lin, S.C.K.

    1983-01-01

    Catalytic hydroprocessing (hydrotreating and hydrocracking) of biomass thermochemical tars can yield mixtures of liquid hydrocarbons and alkyl aromatics of chemical compositions similar to those presently used in diesel and gasoline engine fuels. Phenolics can be coproduced. Compositions of hydroprocessed tars are similar regardless of biomass feedstock used, suggesting that the two-stage process of pyrolysis and hydroprocessing may afford a somewhat universal route to the generation of useful hydrocarbons and oxychemicals from a variety of agricultural and forestry residues. 26 references, 6 figures, 1 table.

  6. Radioactivity in municipal sewage and sludge.

    PubMed Central

    Martin, J E; Fenner, F D

    1997-01-01

    health concerns because sufficient decay occurs before it can reach the public however, incineration, which is done in winter months, directly releases the 131I from sewage sludge to the atmosphere, and even though exposures to both workers and the public were found to be considerably lower than 1% of natural background, incineration of sludge in a pathway for public exposure. Although 131I was readily measurable in sewage sludge, only about 1% of the radioione administered to patients was found in the sludge. The fate of the remaining radioactivity has not been established; some may be in secondary and tertiary residuals, but it is quite likely that most passed through the plant and was discharged in dilute concentrations in plant emissions. The behavior of radioiodine and other radioactive materials released into municipal seweage systems, such as those from large medical facilities, is not yet well understood. PMID:9258296

  7. An integrated process for the extraction of fuel and chemicals from marine macroalgal biomass

    PubMed Central

    Trivedi, Nitin; Baghel, Ravi S.; Bothwell, John; Gupta, Vishal; Reddy, C. R. K.; Lali, Arvind M.; Jha, Bhavanath

    2016-01-01

    We describe an integrated process that can be applied to biomass of the green seaweed, Ulva fasciata, to allow the sequential recovery of four economically important fractions; mineral rich liquid extract (MRLE), lipid, ulvan, and cellulose. The main benefits of our process are: a) its simplicity and b) the consistent yields obtained from the residual biomass after each successive extraction step. For example, dry Ulva biomass yields ~26% of its starting mass as MRLE, ~3% as lipid, ~25% as ulvan, and ~11% as cellulose, with the enzymatic hydrolysis and fermentation of the final cellulose fraction under optimized conditions producing ethanol at a competitive 0.45 g/g reducing sugar. These yields are comparable to those obtained by direct processing of the individual components from primary biomass. We propose that this integration of ethanol production and chemical feedstock recovery from macroalgal biomass could substantially enhance the sustainability of marine biomass use. PMID:27470705

  8. An integrated process for the extraction of fuel and chemicals from marine macroalgal biomass.

    PubMed

    Trivedi, Nitin; Baghel, Ravi S; Bothwell, John; Gupta, Vishal; Reddy, C R K; Lali, Arvind M; Jha, Bhavanath

    2016-01-01

    We describe an integrated process that can be applied to biomass of the green seaweed, Ulva fasciata, to allow the sequential recovery of four economically important fractions; mineral rich liquid extract (MRLE), lipid, ulvan, and cellulose. The main benefits of our process are: a) its simplicity and b) the consistent yields obtained from the residual biomass after each successive extraction step. For example, dry Ulva biomass yields ~26% of its starting mass as MRLE, ~3% as lipid, ~25% as ulvan, and ~11% as cellulose, with the enzymatic hydrolysis and fermentation of the final cellulose fraction under optimized conditions producing ethanol at a competitive 0.45 g/g reducing sugar. These yields are comparable to those obtained by direct processing of the individual components from primary biomass. We propose that this integration of ethanol production and chemical feedstock recovery from macroalgal biomass could substantially enhance the sustainability of marine biomass use. PMID:27470705

  9. Integrating the selection of PHA storing biomass and nitrogen removal via nitrite in the main wastewater treatment line.

    PubMed

    Basset, N; Katsou, E; Frison, N; Malamis, S; Dosta, J; Fatone, F

    2016-01-01

    A novel scheme was developed for the treatment of municipal wastewater integrating nitritation/denitritation with the selection of polyhydroxyalkanoates (PHA) storing biomass under an aerobic/anoxic, feast/famine regime. The process took place in a sequencing batch reactor (SBR) and the subsequent PHA accumulation in a batch reactor. The carbon source added during the selection and accumulation steps consisted of fermentation liquid from the organic fraction of municipal solids waste (OFMSW FL) (Period I) and OFMSW and primary sludge fermentation liquid (Period II). Selection of PHA storing biomass was successful and denitritation was driven by internally stored PHA during the famine phase. Under optimum conditions of SBR operation ammonia removal was 93%, reaching a maximum nitrite removal of 98%. The treated effluent met the nitrogen limits, while PHA-storing biomass was successfully selected. The maximum accumulation of PHA was 10.6% (wt.) since the nutrients present in the carbon source promoted bacterial growth. PMID:26587791

  10. ENERGY REQUIREMENTS FOR MUNICIPAL POLLUTION CONTROL FACILITIES

    EPA Science Inventory

    This report presents information on energy requirements in municipal pollution control facilities for several major areas of interest. (1) Pumping energy for filtration and granular carbon adsorption of secondary effluent - Pumping requirements are developed for all elements of t...

  11. Belgian MSWI fly ashes and APC residues: a characterisation study.

    PubMed

    De Boom, Aurore; Degrez, Marc

    2012-06-01

    Municipal Solid Waste Incineration (MSWI) produces different sorts of residues, bottom ash, fly ashes and Air Pollution Control (APC) residues. Generally, fly ashes and APC residues are mixed at the MSWI plant and manage as a sole residue. In this study, fly ashes and APC residues have been sampled separately at different Belgian MSWI plant and analysed by X-ray fluorescence in order to highlight the composition differences that may appear between the solids. Ca and Cl are found to be the major elements in most of the samples. Lithophilic elements, such as Al and Si, are richer in furnace and boiler ashes, as can be expected. Leaching tests also show differences between the residues; leachates from furnace and boiler ashes are alkaline while those from bag filter residues present a pH value of 6, which impacts the leaching of heavy metals (Pb and Zn). The results suggest that it could be advantageous to manage fly ashes and APC residues separately by adjusting the treatment to their specificities. PMID:22244614

  12. Alteration of municipal and industrial slags under atmospheric conditions

    NASA Astrophysics Data System (ADS)

    Rafał Kowalski, Piotr; Michalik, Marek

    2014-05-01

    The Waste Management System in Poland is being consequently built since 1998. After important changes in legislation, local governments have taken over the duty of waste collection. New points of selective collection of wastes have been opened and new sorting and composting plants were built. The last stage of introducing the Waste Management System is construction of waste incineration power plants. From nine installations which were planned, six are now under construction and they will start operating within the next two years. It is assumed that the consumption of raw wastes for these installations will reach 974 thousand tons per year. These investments will result in increased slags and ashes production. Now in Poland several local waste incinerators are operating and predominant amount of produced incineration residues is landfilled. These materials are exposed to atmospheric conditions in time of short term storage (just after incineration) and afterwards for a longer period of time on the landfill site. During the storage of slags low temperature mineral transformations and chemical changes may occur and also some components can be washed out. These materials are stored wet because of the technological processes. The aim of this study is to investigate the influence of storage in atmospheric conditions on slags from incineration of industrial and municipal wastes. The experiment started in January 2013. During this period slag samples from incineration of industrial and municipal wastes were exposed to atmospheric conditions. Samples were collected after 6 and 12 months. Within this time the pH value was measured monthly, and during the experimental period remained constant on the level of 9.5. After 6 months of exposure only slight changes in mineral compositions were observed in slags. The results of XRD analysis of municipal slags showed increase in content of carbonate minerals in comparison to the raw slag samples. In industrial slags, a decrease in

  13. Hydrolysis of biomass material

    DOEpatents

    Schmidt, Andrew J.; Orth, Rick J.; Franz, James A.; Alnajjar, Mikhail

    2004-02-17

    A method for selective hydrolysis of the hemicellulose component of a biomass material. The selective hydrolysis produces water-soluble small molecules, particularly monosaccharides. One embodiment includes solubilizing at least a portion of the hemicellulose and subsequently hydrolyzing the solubilized hemicellulose to produce at least one monosaccharide. A second embodiment includes solubilizing at least a portion of the hemicellulose and subsequently enzymatically hydrolyzing the solubilized hemicellulose to produce at least one monosaccharide. A third embodiment includes solubilizing at least a portion of the hemicellulose by heating the biomass material to greater than 110.degree. C. resulting in an aqueous portion that includes the solubilized hemicellulose and a water insoluble solids portion and subsequently separating the aqueous portion from the water insoluble solids portion. A fourth embodiment is a method for making a composition that includes cellulose, at least one protein and less than about 30 weight % hemicellulose, the method including solubilizing at least a portion of hemicellulose present in a biomass material that also includes cellulose and at least one protein and subsequently separating the solubilized hemicellulose from the cellulose and at least one protein.

  14. Residue Impacts on Runoff and Soil Erosion for Different Corn Plant Populations

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The year to year carry-over effects of biomass additions under different plant populations on runoff and erosion is unclear. The objective of this study was to quantify the impact of different plant populations on residue cover to elucidate the effects of residue cover on runoff and erosion. The res...

  15. Pyrethroid insecticides in municipal wastewater.

    PubMed

    Weston, Donald P; Ramil, Heather L; Lydy, Michael J

    2013-11-01

    Pyrethroids are widely used insecticides, but minimal information has been published on their presence in municipal wastewater in the United States. Pyrethroids in wastewater from the Sacramento, California, USA, area consisted of permethrin, bifenthrin, cypermethrin, and cyhalothrin, with a combined concentration of 200 ng/L to 500 ng/L. Sampling within the wastewater collection system leading to the treatment plant suggested pyrethroids did not originate primarily from urban runoff, but could be from any of several drain disposal practices. Wastewater from residential areas was similar in pyrethroid composition and concentration to that from the larger metropolitan area as a whole. Secondary treatment removed approximately 90% of pyrethroids, but those remaining exceeded concentrations acutely toxic to sensitive species. Toxicity to the amphipod, Hyalella azteca, was consistently evident in the final effluent. The large river into which this particular plant discharged provided sufficient dilution such that pyrethroids were undetected in the river, and there was only slight toxicity of unknown cause in 1 river sample, but effects in receiving waters elsewhere will be site-specific. PMID:23893650

  16. Assessment of municipal solid waste for energy production in the western United States

    SciTech Connect

    Goodman, B.J.; Texeira, R.H.

    1990-08-01

    Municipal solid waste (MSW) represents both a significant problem and an abundant resource for the production of energy. The residential, institutional, and industrial sectors of this country generate about 250 million tons of MSW each year. In this report, the authors have compiled data on the status of MSW in the 13-state western region, including economic and environmental issues. The report is designed to assist the members of the Western Regional Biomass Energy Program Ad Hoc Resource Committee in determining the potential for using MSW to produce energy in the region. 51 refs., 7 figs., 18 tabs.

  17. Assessment of municipal solid waste for energy production in the Western United States

    NASA Astrophysics Data System (ADS)

    Goodman, B. J.; Texeira, R. H.

    1990-08-01

    Municipal solid waste (MSW) represents both a significant problem and an abundant resource for the production of energy. The residential, institutional, and industrial sectors of this country generate about 250 million tons of MSW each year. Data were compiled on the status of MSW in the 13-state western region, including economic and environmental issues. The report is designed to assist the members of the Western Regional Biomass Energy Program Ad Hoc Resource Committee in determining the potential for using MSW to produce energy in the region.

  18. Biofuel from "humified" biomass

    NASA Astrophysics Data System (ADS)

    Kpogbemabou, D.; Lemée, L.; Amblès, A.

    2009-04-01

    In France, 26% of the emissions of greenhouse effect gas originate from transportation which depends for 87% on fossil fuels. Nevertheless biofuels can contribute to the fight against climate change while reducing energetic dependence. Indeed biomass potentially represents in France 30 Mtoe a year that is to say 15% national consumption. But 80% of these resources are made of lignocellulosic materials which are hardly exploitable. First-generation biofuels are made from sugar, starch, vegetable oil, or animal fats. Due to their competition with human food chain, first-generation biofuels could lead to food shortages and price rises. At the contrary second-generation biofuel production can use a variety of non food crops while using the lignocellulosic part of biomass [1]. Gasification, fermentation and direct pyrolysis are the most used processes. However weak yields and high hydrogen need are limiting factors. In France, the National Program for Research on Biofuels (PNRB) aims to increase mobilizable biomass resource and to develop lignocellulosic biomass conversion. In this context, the LIGNOCARB project studies the liquefaction of biodegraded biomass in order to lower hydrogen consumption. Our aim was to develop and optimize the biodegradation of the biomass. Once the reactor was achieved, the influence of different parameters (starting material, aeration, moisture content) on the biotransformation process was studied. The monitored parameters were temperature, pH and carbon /nitrogen ratio. Chemical (IHSS protocol) and biochemical (van Soest) fractionations were used to follow the maturity ("humic acid"/"fulvic acid" ratio) and the biological stability (soluble, hemicelluloses, celluloses, lignin) of the organic matter (OM). In example, the increase in lignin can be related to the stabilization since the OM becomes refractory to biodegradation whereas the increase in the AH/AF ratio traduces "humification". However, contrarily to the composting process, we do

  19. Harvesting forest biomass for energy in Minnesota: An assessment of guidelines, costs and logistics

    NASA Astrophysics Data System (ADS)

    Saleh, Dalia El Sayed Abbas Mohamed

    The emerging market for renewable energy in Minnesota has generated a growing interest in utilizing more forest biomass for energy. However, this growing interest is paralleled with limited knowledge of the environmental impacts and cost effectiveness of utilizing this resource. To address environmental and economic viability concerns, this dissertation has addressed three areas related to biomass harvest: First, existing biomass harvesting guidelines and sustainability considerations are examined. Second, the potential contribution of biomass energy production to reduce the costs of hazardous fuel reduction treatments in these trials is assessed. Third, the logistics of biomass production trials are analyzed. Findings show that: (1) Existing forest related guidelines are not sufficient to allow large-scale production of biomass energy from forest residue sustainably. Biomass energy guidelines need to be based on scientific assessments of how repeated and large scale biomass production is going to affect soil, water and habitat values, in an integrated and individual manner over time. Furthermore, such guidelines would need to recommend production logistics (planning, implementation, and coordination of operations) necessary for a potential supply with the least site and environmental impacts. (2) The costs of biomass production trials were assessed and compared with conventional treatment costs. In these trials, conventional mechanical treatment costs were lower than biomass energy production costs less income from biomass sale. However, a sensitivity analysis indicated that costs reductions are possible under certain site, prescriptions and distance conditions. (3) Semi-structured interviews with forest machine operators indicate that existing fuel reduction prescriptions need to be more realistic in making recommendations that can overcome operational barriers (technical and physical) and planning and coordination concerns (guidelines and communications

  20. 1994 Washington State directory of Biomass Energy Facilities

    SciTech Connect

    Deshaye, J.A.; Kerstetter, J.D.

    1994-03-01

    This is the fourth edition of the Washington Directory of Biomass Energy Facilities, the first edition was published in 1987. The purpose of this directory is to provide a listing of and basic information about known biomass producers and users within the state to help demonstrate the importance of biomass energy in fueling our state`s energy needs. In 1992 (latest statistical year), estimates show that the industrial sector in Washington consumed nearly 128 trillion Btu of electricity, nearly 49.5 trillion Btu of petroleum, over 82.2 trillion Btu of natural gas, and over 4.2 trillion Btu of coal. Facilities listed in this directory generated approximately 114 trillion Btu of biomass energy - 93 trillion were consumed from waste wood and spent chemicals. In the total industrial energy picture, wood residues and chemical cooking liquors placed second only to electricity. This directory is divided into four main sections biogas production, biomass combustion, ethanol production, and solid fuel processing facilities. Each section contains maps and tables summarizing the information for each type of biomass. Provided in the back of the directory for reference are a conversion table, a table of abbreviations, a glossary, and an index. Chapter 1 deals with biogas production from both landfills and sewage treatment plants in the state. Biogas produced from garbage and sewage can be scrubbed and used to generate electricity. At the present time, biogas collected at landfills is being flared on-site, however four landfills are investigating the feasibility of gas recovery for energy. Landfill biogas accounted for approximately 6 percent of the total biomass reported. Sewage treatment biogas accounted for 0.6 percent. Biogas generated from sewage treatment plants is primarily used for space and process heat, only one facility presently scrubs and sells methane. Together, landfill and sewage treatment plant biogas represented over 6.6 percent of the total biomass reported.

  1. Emissions of fine particle fluoride from biomass burning.

    PubMed

    Jayarathne, Thilina; Stockwell, Chelsea E; Yokelson, Robert J; Nakao, Shunsuke; Stone, Elizabeth A

    2014-11-01

    The burning of biomasses releases fluorine to the atmosphere, representing a major and previously uncharacterized flux of this atmospheric pollutant. Emissions of fine particle (PM2.5) water-soluble fluoride (F-) from biomass burning were evaluated during the fourth Fire Laboratory at Missoula Experiment (FLAME-IV) using scanning electron microscopy energy dispersive X-ray spectroscopy (SEM-EDX) and ion chromatography with conductivity detection. F- was detected in 100% of the PM2.5 emissions from conifers (n=11), 94% of emissions from agricultural residues (n=16), and 36% of the grasses and other perennial plants (n=14). When F- was quantified, it accounted for an average (±standard error) of 0.13±0.02% of PM2.5. F- was not detected in remaining samples (n=15) collected from peat burning, shredded tire combustion, and cook-stove emissions. Emission factors (EF) of F- emitted per kilogram of biomass burned correlated with emissions of PM2.5 and combustion efficiency, and also varied with the type of biomass burned and the geographic location where it was harvested. Based on recent evaluations of global biomass burning, we estimate that biomass burning releases 76 Gg F- yr(-1) to the atmosphere, with upper and lower bounds of 40-150 Gg F- yr(-1). The estimated F- flux from biomass burning is comparable to total fluorine emissions from coal combustion plus other anthropogenic sources. These data demonstrate that biomass burning represents a major source of fluorine to the atmosphere in the form of fine particles, which have potential to undergo long-range transport. PMID:25275955

  2. Development of an extruder-feeder biomass direct liquefaction process

    SciTech Connect

    White, D.H.; Wolf, D. . Dept. of Chemical Engineering)

    1991-10-01

    As an abundant, renewable, domestic energy resource, biomass could help the United States reduce its dependence on imported oil. Biomass is the only renewable energy technology capable of addressing the national need for liquid transportation fuels. Thus, there is an incentive to develop economic conversion processes for converting biomass, including wood, into liquid fuels. Through research sponsored by the US DOE's Biomass Thermochemical Conversion Program, the University of Arizona has developed a unique biomass direct liquefaction system. The system features a modified single-screw extruder capable of pumping solid slurries containing as high as 60 wt% wood flour in wood oil derived vacuum bottoms at pressures up to 3000 psi. The extruder-feeder has been integrated with a unique reactor by the University to form a system which offers potential for improving high pressure biomass direct liquefaction technology. The extruder-feeder acts simultaneously as both a feed preheater and a pumping device for injecting wood slurries into a high pressure reactor in the biomass liquefaction process. An experimental facility was constructed and following shakedown operations, wood crude oil was produced by mid-1985. By July 1988, a total of 57 experimental continuous biomass liquefaction runs were made using White Birch wood feedstock. Good operability was achieved at slurry feed rates up to 30 lb/hr, reactor pressures from 800 to 3000 psi and temperatures from 350{degree}C to 430{degree}C under conditions covering a range of carbon monoxide feed rates and sodium carbonate catalyst addition. Crude wood oils containing as little as 6--10 wt% residual oxygen were produced. 38 refs., 82 figs., 26 tabs.

  3. Development of an extruder-feeder biomass direct liquefaction process

    SciTech Connect

    White, D.H.; Wolf, D. . Dept. of Chemical Engineering)

    1991-10-01

    As an abundant, renewable, domestic energy resource, biomass could help the United States reduce its dependence on imported oil. Biomass is the only renewable energy technology capable of addressing the national need for liquid transportation fuels. Thus, there is an incentive to develop economic conversion processes for converting biomass, including wood, into liquid fuels. Through research sponsored by the US DOE's Biomass Thermochemical Conversion Program, the University of Arizona has developed a unique biomass direct liquefaction system. The system features a modified single-screw extruder capable of pumping solid slurries containing as high as 60 wt % wood flour in wood oil derived vacuum bottoms at pressures up to 3,000 psi. By comparison, conventional pumping systems are capable of pumping slurries containing only 10--20 wt % wood flour in wood oil under similar conditions. The extruder-feeder has been integrated with a unique reactor to form a system which offers potential for improving high pressure biomass direct liquefaction technology. The extruder-feeder acts simultaneously as both a feed preheater and a pumping device for injecting wood slurries into a 3,000 psi pressure reactor in the biomass liquefaction process. An experimental facility was constructed during 1983--84. Following shakedown operations, wood crude oil was produced by mid-1985. During the period January 1985 through July 1988, a total of 57 experimental continuous biomass liquefaction runs were made using White Birch wood feedstock. Good operability was achieved at slurry feed rates up to 30 lb/hr, reactor pressures from 800 to 3,000 psi and temperatures from 350{degrees}C to 430{degrees}C under conditions covering a range of carbon monoxide feed rates and sodium carbonate catalyst addition. Crude wood oils containing as little as 6--10 wt % residual oxygen were produced. 43 refs., 81 figs., 52 tabs.

  4. Two-stage dilute acid prehydrolysis of biomass

    DOEpatents

    Grohmann, Karel; Torget, Robert W.

    1992-01-01

    A two-stage dilute acid prehydrolysis process on xylan containing hemicellulose in biomass is effected by: treating feedstock of hemicellulosic material comprising xylan that is slow hydrolyzable and xylan that is fast hydrolyzable under predetermined low temperature conditions with a dilute acid for a residence time sufficient to hydrolyze the fast hydrolyzable xylan to xylose; removing said xylose from said fast hydrolyzable xylan and leaving a residue; and treating said residue having a slow hydrolyzable xylan with a dilute acid under predetermined high temperature conditions for a residence time required to hydrolyze said slow hydrolyzable xylan to xylose.

  5. Two-stage dilute acid prehydrolysis of biomass

    SciTech Connect

    Grohmann, K.; Torget, R.W.

    1992-06-30

    This patent describes a two-stage dilute acid prehydrolysis process on xylan containing hemicellulose in biomass. It comprises treating a feedstock of hemicellulosic material comprising xylan that is slow hydrolyzable and xylan that is fast hydrolyzable under predetermined low temperature conditions with a dilute acid for a residence time sufficient to hydrolyze the fast hydrolyzable xylan at temperatures between about 90 to about 180{degrees} C to xylose; removing the xylose from the fast hydrolyzable xylan and leaving a residue having slow hydrolyzable xylan; treating the residue having slow hydrolyzable xylan with a dilute acid under predetermined higher temperature conditions for a residence time sufficient to hydrolyze the slow hydroyzable xylan.

  6. Great Lakes Regional Biomass Energy Program: Quarterly report, September 1, 1986-November 30, 1986

    SciTech Connect

    Bancroft, D.

    1987-05-01

    Stressing near-term biomass feedstock production techniques and conversion processes, the objective of the program is to increase the use of biomass energy by the public and private sectors in the Great Lakes region including Illinois, Indiana, Iowa, Michigan, Minnesota, Ohio and Wisconsin. The Great Lakes Regional Biomass Energy Program is divided into three separate operational programs. The first is the State Grant Program, which provides resources to the seven state energy offices in the region to increase their capabilities in biomass energy. State-specific activities and interagency programs are emphasized in the State Grant Program. The second, the Subcontractor Program, involves the letting of subcontracts to private organizations to address regional biomass issues and needs. The third is the In-House Technology Transfer Program in which Council staff develop biomass energy publications and reports. The primary activity this quarter has been information transfer. The program spearheaded an effort to reach the private sector and inform people about a wide range of biomass technologies. In one of the most successful events, 35 cheese manufacturers traveled to the South Alma Cheese Factory to see a woodburner supporting the process steam needs of the facility. In addition, 20 workshops were conducted throughout the region focusing on industrial wood combustion, municipal waste to energy incineration and short rotation forestry. 1 fig.

  7. An advanced extruder-feeder biomass liquefaction reactor system

    NASA Astrophysics Data System (ADS)

    White, Don H.; Wolf, D.; Davenport, G.; Mathews, S.; Porter, M.; Zhao, Y.

    1987-11-01

    A unique method of pumping concentrated, viscous biomass slurries that are characteristic of biomass direct liquefaction systems was developed. A modified single-screw extruder was shown to be capable of pumping solid slurries as high as 60 weight percent wood flour in wood oil derived vacuum bottoms, as compared to only 10 to 20 weight percent wood flour in wood oil in conventional systems. During the period August, 1985 to April, 1987, a total of 18 experimental continuous biomass liquefaction runs were made using white birch feedstock. Good operability with feed rates up to 30 lb/hr covering a range of carbon monoxide, sodium carbonate catalyst, pressures from 800 to 3000 psi and temperatures from 350 C to 430 C was achieved. Crude wood oils containing 6 to 10 weight percent residual oxygen were obtained. Other wood oil characteristics are reported.

  8. Mechanism of lignin inhibition of enzymatic biomass deconstruction

    SciTech Connect

    Vermaas, Josh V.; Petridis, Loukas; Qi, Xianghong; Schulz, Roland; Lindner, Benjamin; Smith, Jeremy. C.

    2015-12-01

    The conversion of plant biomass to ethanol via enzymatic cellulose hydrolysis offers a potentially sustainable route to biofuel production. However, the inhibition of enzymatic activity in pretreated biomass by lignin severely limits the efficiency of this process. By performing atomic-detail molecular dynamics simulation of a biomass model containing cellulose, lignin, and cellulases (TrCel7A), we elucidate detailed lignin inhibition mechanisms. We find that lignin binds preferentially both to the elements of cellulose to which the cellulases also preferentially bind (the hydrophobic faces) and also to the specific residues on the cellulose-binding module of the cellulase that are critical for cellulose binding of TrCel7A (Y466, Y492, and Y493). In conclusion, lignin thus binds exactly where for industrial purposes it is least desired, providing a simple explanation of why hydrolysis yields increase with lignin removal.

  9. Mechanism of lignin inhibition of enzymatic biomass deconstruction

    DOE PAGESBeta

    Vermaas, Josh V.; Petridis, Loukas; Qi, Xianghong; Schulz, Roland; Lindner, Benjamin; Smith, Jeremy. C.

    2015-12-01

    The conversion of plant biomass to ethanol via enzymatic cellulose hydrolysis offers a potentially sustainable route to biofuel production. However, the inhibition of enzymatic activity in pretreated biomass by lignin severely limits the efficiency of this process. By performing atomic-detail molecular dynamics simulation of a biomass model containing cellulose, lignin, and cellulases (TrCel7A), we elucidate detailed lignin inhibition mechanisms. We find that lignin binds preferentially both to the elements of cellulose to which the cellulases also preferentially bind (the hydrophobic faces) and also to the specific residues on the cellulose-binding module of the cellulase that are critical for cellulose bindingmore » of TrCel7A (Y466, Y492, and Y493). In conclusion, lignin thus binds exactly where for industrial purposes it is least desired, providing a simple explanation of why hydrolysis yields increase with lignin removal.« less

  10. Gasification of pelletized biomass in a pilot scale downdraft gasifier.

    PubMed

    Simone, Marco; Barontini, Federica; Nicolella, Cristiano; Tognotti, Leonardo

    2012-07-01

    This work presents a pilot-scale investigation aimed at assessing the feasibility and reliability of biomass pellet gasification. Wood sawdust and sunflower seeds pellets were tested in a 200 kW downdraft gasifier operating with air as gasifying agent. The gasification of pelletized biomass led to rather high and unstable pressure drops, reducing the gasifier productivity and stability. Furthermore the generation of fine residues compromised the operation of wet ash removal systems. On the other hand, good syngas compositions (H(2) 17.2%, N(2) 46.0%, CH(4) 2.5%, CO 21.2%, CO(2) 12.6%, and C(2)H(4) 0.4%), specific gas production (2.2-2.4 N m(3) kg(-1)) and cold gas efficiency (67.7-70.0%) were achieved. For these reasons pelletized biomass should be considered only as complementary fuel in co-gasification with other feedstock. PMID:22537399

  11. Biosorption of lead and nickel by biomass of marine algae

    SciTech Connect

    Holan, Z.R.; Volesky, B. . Dept. of Chemical Engineering)

    1994-05-01

    Screening tests of different marine algae biomass types revealed a high passive biosorptive uptake of lead up to 270 mg Pb/g of biomass in some brown marine algae. Members of the order Fucales performed particularly well in this descending sequence: Fucus > Ascophyllum > Sargassum. Although decreasing the swelling of wetted biomass particles, their reinforcement by crosslinking may significantly affect the biosorption performance. Lead uptakes up to 370 mg Pb/g were observed in crosslinked Fucus vesiculosus and Ascophyllum nodosum. At low equilibrium residual concentrations of lead in solution, however, ion exchange resin Amberlite IR-120 had a higher lead uptake than the biosorbent materials. An order-of-magnitude lower uptake of nickel was observed in all of the sorbent materials examined.

  12. Pretreatment of Biomass by Aqueous Ammonia for Bioethanol Production

    NASA Astrophysics Data System (ADS)

    Kim, Tae Hyun; Gupta, Rajesh; Lee, Y. Y.

    The methods of pretreatment of lignocellulosic biomass using aqueous ammonia are described. The main effect of ammonia treatment of biomass is delignification without significantly affecting the carbohydrate contents. It is a very effective pretreatment method especially for substrates that have low lignin contents such as agricultural residues and herbaceous feedstock. The ammonia-based pretreatment is well suited for simultaneous saccharification and co-fermentation (SSCF) because the treated biomass retains cellulose as well as hemicellulose. It has been demonstrated that overall ethanol yield above 75% of the theoretical maximum on the basis of total carbohydrate is achievable from corn stover pretreated with aqueous ammonia by way of SSCF. There are two different types of pretreatment methods based on aqueous ammonia: (1) high severity, low contact time process (ammonia recycle percolation; ARP), (2) low severity, high treatment time process (soaking in aqueous ammonia; SAA). Both of these methods are described and discussed for their features and effectiveness.

  13. Protection of biomass from snail overgrazing in a trickling filter using sponge media as a biomass carrier: down-flow hanging sponge system.

    PubMed

    Onodera, Takashi; Syutsubo, Kazuaki; Yoochatchaval, Wilasinee; Sumino, Haruhiko; Mizuochi, Motoyuki; Harada, Hideki

    2015-01-01

    This study investigated down-flow hanging sponge (DHS) technology as a promising trickling filter (TF) using sponge media as a biomass carrier with an emphasis on protection of the biomass against macrofauna overgrazing. A pilot-scale DHS reactor fed with low-strength municipal sewage was operated under ambient temperature conditions for 1 year at a sewage treatment plant in Bangkok, Thailand. The results showed that snails (macrofauna) were present on the surface of the sponge media, but could not enter into it, because the sponge media with smaller pores physically protected the biomass from the snails. As a result, the sponge media maintained a dense biomass, with an average value of 22.3 gVSS/L sponge (58.1 gTSS/L sponge) on day 370. The snails could graze biomass on the surface of the sponge media. The DHS reactor process performance was also successful. The DHS reactor requires neither chemical treatments nor specific operations such as flooding for snail control. Overall, the results of this study indicate that the DHS reactor is able to protect biomass from snail overgrazing. PMID:25746642

  14. Is Municipal Solid Waste Recycling Economically Efficient?

    NASA Astrophysics Data System (ADS)

    Lavee, Doron

    2007-12-01

    It has traditionally been argued that recycling municipal solid waste (MSW) is usually not economically viable and that only when externalities, long-term dynamic considerations, and/or the entire product life cycle are taken into account, recycling becomes worthwhile from a social point of view. This article explores the results of a wide study conducted in Israel in the years 2000 2004. Our results reveal that recycling is optimal more often than usually claimed, even when externality considerations are ignored. The study is unique in the tools it uses to explore the efficiency of recycling: a computer-based simulation applied to an extensive database. We developed a simulation for assessing the costs of handling and treating MSW under different waste-management systems and used this simulation to explore possible cost reductions obtained by designating some of the waste (otherwise sent to landfill) to recycling. We ran the simulation on data from 79 municipalities in Israel that produce over 60% of MSW in Israel. For each municipality, we were able to arrive at an optimal method of waste management and compare the costs associated with 100% landfilling to the costs born by the municipality when some of the waste is recycled. Our results indicate that for 51% of the municipalities, it would be efficient to adopt recycling, even without accounting for externality costs. We found that by adopting recycling, municipalities would be able to reduce direct costs by an average of 11%. Through interviews conducted with representatives of municipalities, we were also able to identify obstacles to the utilization of recycling, answering in part the question of why actual recycling levels in Israel are lower than our model predicts they should be.

  15. Land application of organic residuals: Public health threat or environmental benefit

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Waste residuals consist of manure and biosolids produced by concentrated animal feeding operations and municipal waste water treatment plants. All wastes need to be disposed of in a proper manner, protecting public and environmental health, but also in a sustainable fashion to ensure that no system...

  16. Catalysis in biomass gasification

    SciTech Connect

    Baker, E.G.; Mudge, L.K.

    1984-06-01

    The objective of these studies is to evaluate the technical and economic feasibility of producing specific gas products by catalytic gasification of biomass. Catalyst performance is a key factor in the feasibility of catalytic gasification processes. The results of studies designed to gain a fundamental understanding of catalytic mechanisms and causes of deactivation, and discussion of the state-of-the-art of related catalytic processes are presented. Experiments with primary and secondary catalysts were conducted in a 5-cm-diameter, continuous-wood-feed, fixed-catalyst-bed reactor. The primary catalysts used in the experiments were alkali carbonates mixed with the biomass feed; the secondary catalysts included nickel or other transition metals on supports such as alumina, silica, or silica-alumina. The primary catalysts were found to influence wood pyrolysis as well as the char/steam reaction. Secondary catalysts were used in a fixed-bed configuration to direct gas phase reactions. Results of the performance of these catalysts are presented. Secondary catalysts were found to be highly effective for conversion of biomass to specific gas products: synthesis gases and methane-rich gas. With an active catalyst, equilibrium gas composition are obtained, and all liquid pyrolysis products are converted to gases. The major cause of catalyst deactivation was carbon deposition, or coking. Loss of surface area by sintering was also inportant. Catalyst deactivation by sulfur poisoning was observed when bagasse was used as the feedstock for catalytic gasification. Mechanisms of catalyst activity and deactivation are discussed. Model compounds (methane, ethylene, and phenol) were used to determine coking behavior of catalysts. Carbon deposition is more prevalent with ethylene and phenol than with methane. Catalyst formulations that are resistant to carbon deposition are presented. 60 references, 10 figures, 21 tables.

  17. Effect of fuel origin on synergy during co-gasification of biomass and coal in CO2.

    PubMed

    Zhang, Yan; Zheng, Yan; Yang, Mingjun; Song, Yongchen

    2016-01-01

    The effect of fuel origin on synergy in coal/biomass blends during co-gasification has been assessed using a congruent-mass thermogravimetry analysis (TGA) method. Results revealed that synergy occurs when ash residuals are formed, followed by an almost complete gasification of biomass. Potassium species in biomass ash play a catalytic role in promoting gasification reactivity of coal char, which is a direct consequence of synergy during co-gasification. The SEM-EDS spectra provided conclusive evidence that the transfer of potassium from biomass to the surface of coal char occurs during co-pyrolysis/gasification. Biomass ash rich in silica eliminated synergy in coal/biomass blends but not to the extent of inhibiting the reaction rate of the blended chars to make it slower than that of separated ones. The best result in terms of synergy was concluded to be the combination of low-ash coal and K-rich biomass. PMID:26580896

  18. Biomass process handbook

    SciTech Connect

    Not Available

    1983-01-01

    Descriptions are given of 42 processes which use biomass to produce chemical products. Marketing and economic background, process description, flow sheets, costs, major equipment, and availability of technology are given for each of the 42 processes. Some of the chemicals discussed are: ethanol, ethylene, acetaldehyde, butanol, butadiene, acetone, citric acid, gluconates, itaconic acid, lactic acid, xanthan gum, sorbitol, starch polymers, fatty acids, fatty alcohols, glycerol, soap, azelaic acid, perlargonic acid, nylon-11, jojoba oil, furfural, furfural alcohol, tetrahydrofuran, cellulose polymers, products from pulping wastes, and methane. Processes include acid hydrolysis, enzymatic hydrolysis, fermentation, distillation, Purox process, and anaerobic digestion.

  19. Fuels from biomass and wastes

    NASA Astrophysics Data System (ADS)

    Klass, D. L.; Emert, G. H.

    The production, use, and effects of fuels from biomass and waste energy sources are discussed. Biomass procurement from silviculture, including hybrid poplar and sycamore farms, in addition to the growth of mass algal culture and Jerusalem artichokes for fuels are considered. The conversion of biomass and solid waste materials through biological and thermal gasification, hydrolysis and extraction, and fermentation to produce ethanol, along with natural and thermal liquefaction processes involving euphorbia lathyris and cellulosic materials are elaborated. Environmental and health aspects of biomass and waste conversion systems are outlined, noting the large land surface areas needed for significant contributions to total demands from biomass, specific instances and case studies are reviewed for biomass use in Indiana, the Dominican Republic, the southeast U.S., and in small wood stoves.

  20. Use of metakaolin to stabilize sewage sludge ash and municipal solid waste incineration fly ash in cement-based materials.

    PubMed

    Cyr, M; Idir, R; Escadeillas, G

    2012-12-01

    The landfilling of municipal incineration residues is an expensive option for municipalities. This work evaluates an alternative way to render waste inert in cement-based materials by combining the reduction of waste content with the immobilization properties of metakaolin (MK). The functional and environmental properties of ternary and quaternary binders using cement, metakaolin, and two industrial by-products from combustion processes (MSWIFA - Municipal Solid Waste Incineration Fly Ash and SSA - Sewage Sludge Ash) were evaluated. The binders were composed of 75% cement, 22.5% metakaolin and 2.5% residue. Results on the impact of residues on the functional and environmental behavior of mortars showed that the mechanical, dimensional and leaching properties were not affected by the residues. In particular, the use of metakaolin led to a significant decrease in soluble fractions and heavy metals released from the binder matrix. The results are discussed in terms of classification of the leaching behavior, efficiency and role of metakaolin in the immobilization of heavy metals in of MSWIFA and SSA, and the pertinence of the dilution process. PMID:23122733

  1. Waste washing pre-treatment of municipal and special waste.

    PubMed

    Cossu, Raffaello; Lai, Tiziana; Pivnenko, Kostyantyn

    2012-03-15

    Long-term pollution potential in landfills is mainly related to the quality of leachate. Waste can be conveniently treated prior to landfilling with an aim to minimizing future emissions. Washing of waste represents a feasible pre-treatment method focused on controlling the leachable fraction of residues and relevant impact. In this study, non-recyclable plastics originating from source segregation, mechanical-biological treated municipal solid waste (MSW), bottom ash from MSW incineration and automotive shredder residues (ASR) were treated and the removal efficiency of washing pre-treatment prior to landfilling was evaluated. Column tests were performed to simulate the behaviour of waste in landfill under aerobic and anaerobic conditions. The findings obtained revealed how waste washing treatment (WWT) allowed the leachability of contaminants from waste to be reduced. Removal rates exceeding 65% were obtained for dissolved organic carbon (DOC), chemical oxygen demand (COD) and Total Kjeldahl Nitrogen (TKN). A percentage decrease of approximately 60% was reached for the leachable fraction of chlorides, sulphates, fluoride and metals, as proved by a reduction in electric conductivity values (70%). PMID:21968117

  2. Glass-ceramics from municipal incinerator fly ash

    SciTech Connect

    Boccaccini, A.R.; Petitmermet, M.; Wintermantel, E.

    1997-11-01

    In countries where the population density is high and the availability of space for landfilling is limited, such as the west-European countries and Japan, the significance of municipal solid waste incineration, as part of the waste management strategy, is continuously increasing. In Germany and Switzerland, for example, more than {approximately}40% of unrecycled waste is being or will be incinerated. Also, in other countries, including the US, the importance of waste incineration will increase in the next few years. Although incineration reduces the volume of the waste by {approximately} 90%, it leaves considerable amounts of solid residues, such as bottom and boiler ashes, and filter fly ashes. Consequently, new technological options for the decontamination and/or inertization of incinerator filter fly ash are being developed with the objective of rendering a product that can be reused or, at least, be deposited in standard landfill sites with no risk. The proposed alternatives include immobilization by cement-based techniques, wet chemical treatments and thermal treatments of vitrification. Of these, vitrification is the most promising solution, because, if residues are melted at temperatures > 1,300 C, a relatively inert glass is produced. In the present investigation, glass-ceramics were obtained by a controlled crystallization heat treatment of vitrified incinerator filter fly ashes. The mechanical and other technical properties of the products were measured with special emphasis on assessing their in vitro toxic potential.

  3. Impact of socioeconomic status on municipal solid waste generation rate.

    PubMed

    Khan, D; Kumar, A; Samadder, S R

    2016-03-01

    The solid waste generation rate was expected to vary in different socioeconomic groups due to many environmental and social factors. This paper reports the assessment of solid waste generation based on different socioeconomic parameters like education, occupation, income of the family, number of family members etc. A questionnaire survey was conducted in the study area to identify the different socioeconomic groups that may affect the solid waste generation rate and composition. The average waste generated in the municipality is 0.41 kg/capita/day in which the maximum waste was found to be generated by lower middle socioeconomic group (LMSEG) with average waste generation of 0.46 kg/capita/day. Waste characterization indicated that there was no much difference in the composition of wastes among different socioeconomic groups except ash residue and plastic. Ash residue is found to increase as we move lower down the socioeconomic groups with maximum (31%) in lower socioeconomic group (LSEG). The study area is a coal based city hence application of coal and wood as fuel for cooking in the lower socioeconomic group is the reason for high amount of ash content. Plastic waste is maximum (15%) in higher socioeconomic group (HSEG) and minimum (1%) in LSEG. Food waste is a major component of generated waste in almost every socioeconomic group with maximum (38%) in case of HSEG and minimum (28%) in LSEG. This study provides new insights on the role of various socioeconomic parameters on generation of household wastes. PMID:26831564

  4. Phytomining of valuable metals from waste incineration residues using hyperaccumulator plants

    NASA Astrophysics Data System (ADS)

    Rosenkranz, Theresa; Kisser, Johannes; Gattringer, Heinz; Iordanopoulos-Kisser, Monika; Puschenreiter, Markus

    2015-04-01

    Worldwide the availability of primary sources of certain economically important metals is decreasing, resulting in high supply risks and increasing prices for this materials. Therefore, an alternative way of retrieving these high valuable technical metals is the recycling and use of anthropogenic secondary sources, such as waste incineration residues. Phytomining offers an environmentally sound and cheap technology to recover such metals from secondary sources. Thus, the aim of our research work is to investigate the potential of phytomining from waste incineration slags by growing metal hyperaccumulating plants on this substrates and use the metal enriched biomass as a bio-ore. As a first stage, material from Vienna's waste incineration plants was sampled and analyzed. Residues from municipal wastes as well as residues from hazardous waste incineration and sewage sludge incineration were analyzed. In general, the slags can be characterized by a very high pH, high salinity and high heavy metal concentrations. Our work is targeting the so-called critical raw materials defined by the European Commission in 2014. Thus, the target metal species in our project are amongst others cobalt, chromium, antimony, tungsten, gallium, nickel and selected rare earth elements. This elements are present in the slags at moderate to low concentrations. In order to optimize the substrate for plant growth the high pH and salt content as well as the low nitrogen content in the slags need to be controlled. Thus, different combinations of amendments, mainly from the waste industry, as well as different acidifying agents were tested for conditioning the substrate. Washing the slags with diluted nitric acid turned out to be effective for lowering the pH. The acid treated substrate in combination with material from mechanical biological waste treatment and biochar, is currently under investigation in a greenhouse pot experiment. The experimental setup consists of a full factorial design

  5. Accelerated Sequestration of Terrestrial Plant Biomass in the Deep Ocean

    NASA Astrophysics Data System (ADS)

    Strand, S. E.

    2010-12-01

    One of the most efficient uses of aboveground agricultural residues to reduce atmospheric CO2 is burial in sites removed from contact with the atmosphere and in which degradation of lignocellulose is inhibited (Strand and Benford 2009). Similarly by burying forest residues greater benefits for atmospheric carbon accrue compared to incineration or bioethanol production. Accessible planetary sites that are most removed from contact with the atmosphere are primarily the deep ocean sediments. Many deep ocean sediment ecologies are acclimated to massive inputs of terrestrial plant biomass. Nonetheless, marine degradation rates of lignocellulose are slower than terrestrial rates (Keil et al. 2010). Additionally, anaerobic conditions are easily achieved in many deep ocean sediments, inhibiting lignocellulose degradation further, while the dominance of sulfate in the water column as electron acceptor prevents the release of methane from methanogenesis to the atmosphere. The potential benefit of massive removal of excess terrestrial biomass to the deep ocean will be estimated and compared to other uses including biochar and BECS. The impact of the biomass on the marine environment will be discussed and potential sequestration sites in the Gulf of Mexico and the Atlantic compared. Keil, R. G., J. M. Nuwer, et al. (2010). "Burial of agricultural byproducts in the deep sea as a form of carbon sequestration: A preliminary experiment." Marine Chemistry (In Press, online 6 August 2010). Strand, S. E. and G. Benford (2009). "Ocean sequestration of crop residue carbon: recycling fossil fuel carbon back to deep sediments." Environ. Sci. Technol. 43(4): 1000-1007.

  6. Enrichment and activity of methanotrophic microorganisms from municipal wastewater sludge.

    PubMed

    Siniscalchi, Luciene Alves Batista; Vale, Isabel Campante; Dell'Isola, Jéssica; Chernicharo, Carlos Augusto; Calabria Araujo, Juliana

    2015-01-01

    In this study, methanotrophic microorganisms were enriched from a municipal wastewater sludge taken from an Upflow Anaerobic Sludge Blanket reactor. The enrichment was performed in a sequencing batch reactor (SBR) with an autotrophic medium containing nitrite and nitrate. The microbial community composition of the inoculum and of the enrichment culture after 100 days of SBR operation was investigated and compared with the help of data obtained from 454 pyrosequencing analyses. The nitrite and nitrate removal efficiencies were 68% and 53%, respectively, probably due to heterotrophic denitrification. Archaeal cells of the anaerobic methanotrophic Archaic (ANME)-I and ANME-II groups were detected by polymerase chain reaction throughout the whole cultivation period. Pyrosequencing analysis showed that community composition was different among the two samples analysed. The dominant phyla found in the inoculum were Synergistestes, Firmicutes and Euryarchaeota, while Planctomycetes, Verrucomicrobia, Chloroflexi and Proteobacteria prevailed in the enriched biomass. The cultivation conditions decreased Methanobacterium abundance from 8% to 1%, and enriched for methanotrophic bacteria such as Methylocaldum, Methylocistis and Methylosinus. Sequences of Methylocaldum sp. accounted for 2.5% of the total reads. The presence and high predominance of Verrucomicrobia in the enriched biomass suggested that other unknown methanotrophic species related to that phylum might also have occurred in the reactor. Anaerobic methane oxidation activity was measured for both samples, and showed that the activity of the enrichment culture was nearly three times higher than the activity of the inoculum. Taken together, these results showed that the inoculum type and cultivation conditions were properly suited for methanotrophic enrichment. PMID:25495866

  7. The survival strategy of the soil microbial biomass

    NASA Astrophysics Data System (ADS)

    Brookes, Philip; Kemmitt, Sarah; Dungait, Jennifer; Xu, Jianming

    2014-05-01

    The soil microbial biomass (biomass) is defined as the sum of the masses of all soil microorganisms > 5000 µm3 (e.g. fungi, bacteria, protozoa, yeasts, actinomycetes and algae). Typically comprising about 1 to 3 % of total soil organic matter (SOM), the biomass might be though to live in a highly substrate-rich environment. However, the SOM is, normally, only exceedingly slowly available to the biomass. However the biomass can survive for months or even years on this meagre energy source. Not surprisingly, therefore, the biomass exhibits many features typical of a dormant or resting population. These include a very low rate of basal and specific respiration, a slow rate of cell division (about once every six months on average) and slow turnover rate. These are clearly adaptations to existing in an environment where substrate availability is very low. Yet, paradoxically, the biomass, in soils worldwide, has an adenosine triphosphate (ATP) concentration (around 10 to 12 µmol ATP g-1 biomass C), and an Adenylate Energy Charge (AEC = [(ATP) + (0.5 ADP)]/[(ATP)+(ADP) + (AMP)]) which are typical of microorganisms growing exponentially in a chemostat. This sets us several questions. Firstly, under the condition of extremely limited substrate availability in soil, why does the biomass not mainly exist as spores, becoming active, by increasing both its ATP concentration and AEC, when substrate (plant and animal residues) becomes available? We surmise that a spore strategy may put organisms at a competitive disadvantage, compared to others which are prepared to invest energy, maintaining high ATP and ATP, to take advantage of a 'food event' as soon as it becomes available. Secondly, since SOM is available (although only very slowly) to the biomass, why have some groups not evolved the ability to mineralize it faster, obtain more energy, and so gain a competitive advantage? We believe that the reason why organisms do not use this strategy is, simply, that they cannot. Our

  8. Polycyclic aromatic hydrocarbons (PAH) formation from the pyrolysis of different municipal solid waste fractions

    SciTech Connect

    Zhou, Hui; Wu, Chunfei; Onwudili, Jude A.; Meng, Aihong; Zhang, Yanguo; Williams, Paul T.

    2015-02-15

    Highlights: • PAH from pyrolysis of 9 MSW fractions was investigated. • Pyrolysis of plastics released more PAH than that of biomass. • Naphthalene was the most abundant PAH in the tar. • The mechanism of PAH release from biomass and plastics was proposed. - Abstract: The formation of 2–4 ring polycyclic aromatic hydrocarbons (PAH) from the pyrolysis of nine different municipal solid waste fractions (xylan, cellulose, lignin, pectin, starch, polyethylene (PE), polystyrene (PS), polyvinyl chloride (PVC), and polyethylene terephthalate (PET)) were investigated in a fixed bed furnace at 800 °C. The mass distribution of pyrolysis was also reported. The results showed that PS generated the most total PAH, followed by PVC, PET, and lignin. More PAH were detected from the pyrolysis of plastics than the pyrolysis of biomass. In the biomass group, lignin generated more PAH than others. Naphthalene was the most abundant PAH, and the amount of 1-methynaphthalene and 2-methynaphthalene was also notable. Phenanthrene and fluorene were the most abundant 3-ring PAH, while benzo[a]anthracene and chrysene were notable in the tar of PS, PVC, and PET. 2-ring PAH dominated all tar samples, and varied from 40 wt.% to 70 wt.%. For PS, PET and lignin, PAH may be generated directly from the aromatic structure of the feedstock.

  9. Biomass power for rural development

    SciTech Connect

    Shepherd, P.

    2000-06-02

    Biomass is a proven option for electricity generation. A diverse range of biopower producers includes electric utilities, independent power producers, and the pulp and paper industry. To help expand opportunities for biomass power production, the U.S. Department of Energy established the Biopower Program and is sponsoring efforts to increase the productivity of dedicated energy crops. The Program aims to double biomass conversion efficiencies, thus reducing biomass power generation costs. These efforts will promote industrial and agricultural growth, improve the environment, create jobs, increase U.S. energy security, and provide new export markets.

  10. Regulation possibilities of biomass combustion

    NASA Astrophysics Data System (ADS)

    Suzdalenko, Vera; Gedrovics, Martins; Zake, Maija; Barmina, Inesa

    2012-11-01

    The focus of the recent experimental research is to analyze the regulation possibilities of biomass combustion. Three possibilities were chosen as part of this research: a) biomass cofiring with propane, b) swirling flow with re-circulation zone, and c) use of a permanent magnet. The aim of the research is to provide stable, controllable and effective biomass combustion with minimum emissions. The special pilot device was created where biomass can be combusted separately and co-fired with propane. Wood pellets were used during the experiments.

  11. Fluorescence of crop residue: postmortem analysis of crop conditions

    NASA Astrophysics Data System (ADS)

    McMurtrey, James E., III; Kim, Moon S.; Daughtry, Craig S. T.; Corp, Lawrence A.; Chappelle, Emmett W.

    1997-07-01

    Fluorescence of crop residues at the end of the growing season may provide an indicator of the past crop's vegetative condition. Different levels of nitrogen (N) fertilization were applied to field grown corn and wheat at Beltsville, Maryland. The N fertilizer treatments produce a range of physiological conditions, pigment concentrations, biomass levels, and grain yields that resulted in varying growth and stress conditions in the living crops. After normal harvesting procedures the crop residues remained. The fluorescence spectral characteristics of the plant residues from crops grown under different levels of N nutrition were analyzed. The blue-green fluorescence response of in-vitro residue biomass of the N treated field corn had different magnitudes. A blue-green- yellow algorithm, (460/525)*600 nm, gave the best separations between prior corn growth conditions at different N fertilization levels. Relationships between total dry biomass, the grain yield, and fluorescence properties in the 400 - 670 nm region of the spectrum were found in both corn and wheat residues. The wheat residue was analyzed to evaluate the constituents responsible for fluorescence. A ratio of the blue-green, 450/550 nm, images gave the best separation among wheat residues at different N fertilization levels. Fluorescence of extracts from wheat residues showed inverse fluorescence intensities as a function of N treatments compared to that of the intact wheat residue or ground residue samples. The extracts also had an additional fluorescence emission peak in the red, 670 nm. Single band fluorescence intensity in corn and wheat residues is due mostly to the quantity of the material on the soil surface. Ratios of fluorescence bands varied as a result of the growth conditions created by the N treatments and are thought to be indicative of the varying concentrations of the plant residues fluorescing constituents. Estimates of the amount and cost effectiveness of N fertilizers to satisfy

  12. Clean fractionation of biomass

    SciTech Connect

    1995-09-01

    The US DOE Alternative Feedstocks (AF) program is forging new links between the agricultural community and the chemicals industry through support of research and development (R&D) that uses green feedstocks to produce chemicals. The program promotes cost-effective industrial use of renewable biomass as feedstocks to manufacture high-volume chemical building blocks. Industrial commercialization of such processes would stimulate the agricultural sector by increasing the demand of agricultural and forestry commodities. A consortium of five DOE national laboratories has been formed with the objectives of providing industry with a broad range of expertise and helping to lower the risk of new process development through federal cost sharing. The AF program is conducting ongoing research on a clean fractionation process, designed to convert biomass into materials that can be used for chemical processes and products. The focus of the clean fractionation research is to demonstrate to industry that one technology can successfully separate all types of feedstocks into predictable types of chemical intermediates.

  13. Energy production from biomass (Part 1): Overview of biomass.

    PubMed

    McKendry, Peter

    2002-05-01

    The use of renewable energy sources is becoming increasingly necessary, if we are to achieve the changes required to address the impacts of global warming. Biomass is the most common form of renewable energy, widely used in the third world but until recently, less so in the Western world. Latterly much attention has been focused on identifying suitable biomass species, which can provide high-energy outputs, to replace conventional fossil fuel energy sources. The type of biomass required is largely determined by the energy conversion process and the form in which the energy is required. In the first of three papers, the background to biomass production (in a European climate) and plant properties is examined. In the second paper, energy conversion technologies are reviewed, with emphasis on the production of a gaseous fuel to supplement the gas derived from the landfilling of organic wastes (landfill gas) and used in gas engines to generate electricity. The potential of a restored landfill site to act as a biomass source, providing fuel to supplement landfill gas-fuelled power stations, is examined, together with a comparison of the economics of power production from purpose-grown biomass versus waste-biomass. The third paper considers particular gasification technologies and their potential for biomass gasification. PMID:12058829

  14. Biomass in the Deregulated Marketplace: Current Issues for Biomass Power

    SciTech Connect

    Not Available

    1998-12-01

    This issue brief provides readers with a monthly review and analysis of electric utility deregulation as it impacts biomass power production and distribution. The topical areas to be routinely covered will include Federal activities, State activities, Current challenges, and Current opportunities. Additionally, a monthly highlighted topic will provide more in-depth analysis of current issue impacting biomass power.

  15. System and process for biomass treatment

    SciTech Connect

    Dunson, Jr., James B; Tucker, III, Melvin P; Elander, Richard T; Lyons, Robert C

    2013-08-20

    A system including an apparatus is presented for treatment of biomass that allows successful biomass treatment at a high solids dry weight of biomass in the biomass mixture. The design of the system provides extensive distribution of a reactant by spreading the reactant over the biomass as the reactant is introduced through an injection lance, while the biomass is rotated using baffles. The apparatus system to provide extensive assimilation of the reactant into biomass using baffles to lift and drop the biomass, as well as attrition media which fall onto the biomass, to enhance the treatment process.

  16. Technology assessment of solar energy systems: availability and impacts of woody biomass utilization in the Pacific Northwest

    SciTech Connect

    Hopp, W.J.; Chockie, A.D.; Allwine, K.J.

    1981-09-01

    The estimates of the biomass resource base in the Northwest are reviewed for comparison with scenarios used and a preliminary analysis of the issues involved in the collection and use of forest residues as an energy resource is presented. Four issues are reviewed that may serve to constrain the total amount of wood residues available for use as fuel. (MHR)

  17. Possible interactions between recirculated landfill leachate and the stabilized organic fraction of municipal solid waste.

    PubMed

    Calabrò, Paolo S; Mancini, Giuseppe

    2012-05-01

    The stabilized organic fraction of municipal solid waste (SOFMSW) is a product of the mechanical/biological treatment (MBT) of mixed municipal solid waste (MMSW). SOFMSW is considered a 'grey' compost and the presence of pollutants (particularly heavy metals) and residual glass and plastic normally prevents agricultural use, making landfills the typical final destination for SOFMSW. Recirculation of leachate in landfills can be a cost-effective management option, but the long-term sustainability of such a practice must be verified. Column tests were carried out to examine the effect of SOFMSW on leachate recirculation. The results indicate that organic matter may be biologically degraded and metals (copper and zinc) are effectively entrapped through a combination of physical (adsorption), biological (bacterial sulfate reduction), and chemical (precipitation of metal sulfides) processes, while other chemicals (i.e. ammonia nitrogen and chloride) are essentially unaffected by filtration through SOFMSW. PMID:22351654

  18. Heavy metal characterization of circulating fluidized bed derived biomass ash.

    PubMed

    Li, Lianming; Yu, Chunjiang; Bai, Jisong; Wang, Qinhui; Luo, Zhongyang

    2012-09-30

    Although the direct combustion of biomass for energy that applies circulating fluidized bed (CFB) technology is steadily expanding worldwide, only few studies have conducted an environmental assessment of biomass ash thus far. Therefore, this study aims to integrate information on the environmental effects of biomass ash. We investigated the concentration of heavy metal in biomass ash samples (bottom ash, cyclone ash, and filter ash) derived from a CFB boiler that combusted agricultural and forest residues at a biomass power plant (2×12 MW) in China. Ash samples were gathered for the digestion and leaching test. The heavy metal content in the solution and the leachate was studied via an inductively coupled plasma-mass spectrometer and a Malvern Mastersizer 2000 mercury analyzer. Measurements for the chemical composition, particle size distribution, and the surface morphology were carried out. Most of the metals in cyclone ash particles were enriched, whereas Ti and Hg were enriched in filter ash. Residence time contributed most to heavy metal enrichment. Under HJ/T 300 conditions, the heavy metals showed serious leaching characteristics. Under EN 12457-2 conditions, leaching behavior was hardly detected. PMID:22840499

  19. Spatial and temporal distribution of tropical biomass burning

    SciTech Connect

    Hao, W.M.; Liu, Mei-Huey

    1994-12-01

    A database for the spatial and temporal distribution of the amount of biomass burned in tropical America, Africa, and Asia during the late 1970s is presented with a resolution of 5{degrees} latitude x 5{degrees} longitude. The sources of burning in each grid cell have been quantified. Savanna fires, shifting cultivation, deforestation, fuel wood use, and burning of agricultural residues contribute about 50, 24, 10, 11, and 5%, respectively, of total biomass burned in the tropics. Savanna fires dominate in tropical Africa, and forest fires dominant in tropical Asia. A similar amount of biomass is burned from forest and savanna fires in tropical America. The distribution of biomass burned monthly during the dry season has been derived for each grid cell using the seasonal cycles of surface ozone concentrations. Land use changes during the last decade could have a profound impact on the amount of biomass burned and the amount of trace gases and aerosol particles emitted. 32 refs., 3 figs., 3 tabs.

  20. Integrated production of polyhydroxyalkanoates (PHAs) with municipal wastewater and sludge treatment at pilot scale.

    PubMed

    Morgan-Sagastume, F; Hjort, M; Cirne, D; Gérardin, F; Lacroix, S; Gaval, G; Karabegovic, L; Alexandersson, T; Johansson, P; Karlsson, A; Bengtsson, S; Arcos-Hernández, M V; Magnusson, P; Werker, A

    2015-04-01

    A pilot-scale process was operated over 22 months at the Brussels North Wastewater Treatment Plant (WWTP) in order to evaluate polyhydroxyalkanoate (PHA) production integration with services of municipal wastewater and sludge management. Activated sludge was produced with PHA accumulation potential (PAP) by applying feast-famine selection while treating the readily biodegradable COD from influent wastewater (average removals of 70% COD, 60% CODsol, 24% nitrogen, and 46% phosphorus). The biomass PAP was evaluated to be in excess of 0.4gPHA/gVSS. Batch fermentation of full-scale WWTP sludge at selected temperatures (35, 42 and 55 °C) produced centrate (6-9.4 gCODVFA/L) of consistent VFA composition, with optimal fermentation performance at 42 °C. Centrate was used to accumulate PHA up to 0.39 gPHA/gVSS. The centrate nutrients are a challenge to the accumulation process but producing a biomass with 0.5 gPHA/gVSS is considered to be realistically achievable within the typically available carbon flows at municipal waste management facilities. PMID:25638407

  1. Reduced Soil Tillage Affects the Concentration, Production and Stabilization of Microbial Biomass

    NASA Astrophysics Data System (ADS)

    van Groenigen, K.; Jones, M.

    2008-12-01

    Soil microbial communities dominated by fungi have been associated with reduced N losses and increased soil aggregation. Moreover, fungal residues have been found to degrade slower than bacterial residues. For these reasons, fungi-dominated communities may be more conducive to ecosystem C storage. In agricultural systems, a shift towards a fungal decomposition pathway might help to regain some of the soil C that was lost due to cultivation. However, measurements on standing microbial biomass alone do not fully reveal fungal and bacterial contributions to SOM dynamics. Therefore, we compared the effect of reduced and conventional tillage on both the growth and concentration of fungal and bacterial biomass, by using leucine and acetate incorporation techniques and epifluorescence microscopy. We also measured the concentration of fungal and bacterial residues, by quantifying amino sugars glucosamine, galactosamine and muramic acid. Soil samples were collected at two different depths from spring barley field plots that were under conventional vs. reduced tillage management for 7.5 growing seasons. Reduced tillage strongly increased both fungal and bacterial biomass in the top soil layer. However, microbial growth rates only showed small responses, suggesting a slower turnover of microbial biomass under reduced tillage. Across soil depths and tillage treatments, total amino sugar contents ranged between 440 and 560 mg C per kilo soil. Fungal derived amino sugars increased under reduced tillage, whereas bacterial residues remained unaffected. These results suggest that reduced tillage enhances the fungal contribution to SOM dynamics both by stimulating fungal growth and stabilization of fungal biomass.

  2. Roadmap for Agriculture Biomass Feedstock Supply in the United States

    SciTech Connect

    J. Richard Hess; Thomas D. Foust; Reed Hoskinson; David Thompson

    2003-11-01

    accomplished in a sustainable manner • Feedstock Infrastructure – An integrated feedstock supply system must be developed and implemented that can serve the feedstock needs of the biorefinery at the cost, quality, and consistency of the set targets • System Profitability – Economic profitability and sustainability need to be ensured for all required participants in the feedstock supply system. For each step in the biomass supply process—production, harvesting and collection, storage, preprocessing, system integration, and transportation—this roadmap addresses the current technical situations, performance targets, technical barriers, R&D needs, and R&D priorities to overcome technical barriers and achieve performance targets. Crop residue biomass is an attractive starting feedstock, which shows the best near-term promise as a biorefinery feedstock. Because crop residue is a by-product of grain production, it is an abundant, underutilized, and low cost biomass resource. Corn stover and cereal straw are the two most abundant crop residues available in the United States. Therefore, this roadmap focuses primarily on the R&D needed for using these biomass sources as viable biorefinery feedstocks. However, achieving the goal of 1 billion dry tons of lignocellulosic feedstock will require the use of other biomass sources such as dedicated energy crops. In the long term, the R&D needs identified in this roadmap will need to accommodate these other sources of biomass as well.

  3. Effect of static magnetic field on the oxygen production of Scenedesmus obliquus cultivated in municipal wastewater.

    PubMed

    Tu, Renjie; Jin, Wenbiao; Xi, Tingting; Yang, Qian; Han, Song-Fang; Abomohra, Abd El-Fatah

    2015-12-01

    Algal-bacterial symbiotic system, with biological synergism of physiological functions of both algae and bacteria, has been proposed for cultivation of microalgae in municipal wastewater for biomass production and wastewater treatment. The algal-bacterial symbiotic system can enhance dissolved oxygen production which enhances bacterial growth and catabolism of pollutants in wastewater. Therefore, the oxygen production efficiency of microalgae in algal-bacterial systems is considered as the key factor influencing the wastewater treatment efficiency. In the present study, we have proposed a novel approach which uses static magnetic field to enhance algal growth and oxygen production rate with low operational cost and non-toxic secondary pollution. The performance of oxygen production with the magnetic field was evaluated using Scenedesmus obliquus grown in municipal wastewater and was calculated based on the change in dissolved oxygen concentration. Results indicated that magnetic treatment stimulates both algal growth and oxygen production. Application of 1000 GS of magnetic field once at logarithmic growth phase for 0.5 h increased the chlorophyll-a content by 11.5% over the control after 6 days of growth. In addition, magnetization enhanced the oxygen production rate by 24.6% over the control. Results of the study confirmed that application of a proper magnetic field could reduce the energy consumption required for aeration during the degradation of organic matter in municipal wastewater in algal-bacterial symbiotic systems. PMID:26253865

  4. Municipal solid wastes and their disposal.

    PubMed Central

    Stone, R

    1978-01-01

    A brief overview is given of the sources, characteristics, and toxic constituents of municipal solid wastes. Several methods are presented for handling, treating, and disposal of solid wastes. Monitoring the landfill site is necessary; there has been a trend to recognize that municipal solid wastes may be hazardous and to provide separate secure handling, treatment, and disposal for their dangerous constituents. Under current state and Federal regulations, permits are being required to assure that proper handling of conventional solid wastes and more hazardous constituents are carefully managed. PMID:738240

  5. Biogeographical patterns of biomass allocation in leaves, stems, and roots in China's forests.

    PubMed

    Zhang, Hao; Wang, Kelin; Xu, Xianli; Song, Tongqing; Xu, Yanfang; Zeng, Fuping

    2015-01-01

    To test whether there are general patterns in biomass partitioning in relation to environmental variation when stand biomass is considered, we investigated biomass allocation in leaves, stems, and roots in China's forests using both the national forest inventory data (2004-2008) and our field measurements (2011-2012). Distribution patterns of leaf, stem, and root biomass showed significantly different trends according to latitude, longitude, and altitude, and were positively and significantly correlated with stand age and mean annual precipitation. Trade-offs among leaves, stems, and roots varied with forest type and origin and were mainly explained by stand biomass. Based on the constraints of stand biomass, biomass allocation was also influenced by forest type, origin, stand age, stand density, mean annual temperature, precipitation, and maximum temperature in the growing season. Therefore, after stand biomass was accounted for, the residual variation in biomass allocation could be partially explained by stand characteristics and environmental factors, which may aid in quantifying carbon cycling in forest ecosystems and assessing the impacts of climate change on forest carbon dynamics in China. PMID:26525117

  6. Biogeographical patterns of biomass allocation in leaves, stems, and roots in China’s forests

    PubMed Central

    Zhang, Hao; Wang, Kelin; Xu, Xianli; Song, Tongqing; Xu, Yanfang; Zeng, Fuping

    2015-01-01

    To test whether there are general patterns in biomass partitioning in relation to environmental variation when stand biomass is considered, we investigated biomass allocation in leaves, stems, and roots in China’s forests using both the national forest inventory data (2004–2008) and our field measurements (2011–2012). Distribution patterns of leaf, stem, and root biomass showed significantly different trends according to latitude, longitude, and altitude, and were positively and significantly correlated with stand age and mean annual precipitation. Trade-offs among leaves, stems, and roots varied with forest type and origin and were mainly explained by stand biomass. Based on the constraints of stand biomass, biomass allocation was also influenced by forest type, origin, stand age, stand density, mean annual temperature, precipitation, and maximum temperature in the growing season. Therefore, after stand biomass was accounted for, the residual variation in biomass allocation could be partially explained by stand characteristics and environmental factors, which may aid in quantifying carbon cycling in forest ecosystems and assessing the impacts of climate change on forest carbon dynamics in China. PMID:26525117

  7. Hydrogen production by gasification of municipal solid waste

    SciTech Connect

    Rogers, R. III

    1994-05-20

    As fossil fuel reserves run lower and lower, and as their continued widespread use leads toward numerous environmental problems, the need for clean and sustainable energy alternatives becomes ever clearer. Hydrogen fuel holds promise as such as energy source, as it burns cleanly and can be extracted from a number of renewable materials such as municipal solid waste (MSW), which can be considered largely renewable because of its high content of paper and biomass-derived products. A computer model is being developed using ASPEN Plus flow sheeting software to simulate a process which produces hydrogen gas from MSW; the model will later be used in studying the economics of this process and is based on an actual Texaco coal gasification plant design. This paper gives an overview of the complete MSW gasification process, and describes in detail the way in which MSW is modeled by the computer as a process material. In addition, details of the gasifier unit model are described; in this unit modified MSW reacts under pressure with oxygen and steam to form a mixture of gases which include hydrogen.

  8. Effect of recycling on residuals, processing, and properties of carbon and low-alloy steels

    NASA Astrophysics Data System (ADS)

    Stephenson, E. T.

    1983-02-01

    Because of the continuing increase in electric furnace steelmaking, which is a scrap-intensive process, and also in view of future new sources of scrap, such as municipal solid wastes, it is important to develop more knowledge about: (a) the effects of residual elements on steel, (b) processing strategies for producing high-residual steels, and (c) products in which residuals could be used to advantage. This review will first identify the important residual elements and the trends in their use and levels in steels. The effect of these elements on the processing phenomena and product properties of carbon and low-alloy steels will be discussed in detail. These phenomena and properties include hot shortness, scale adherence, room temperature tensile properties, impact resistance, and hardenability. Also discussed are examples of specific problems that residual elements present, both now and with emerging trends, for steel processing and applications, and the ways of using residuals to advantage.

  9. Biomass for energy in the European Union - a review of bioenergy resource assessments.

    PubMed

    Bentsen, Niclas Scott; Felby, Claus

    2012-01-01

    This paper reviews recent literature on bioenergy potentials in conjunction with available biomass conversion technologies. The geographical scope is the European Union, which has set a course for long term development of its energy supply from the current dependence on fossil resources to a dominance of renewable resources. A cornerstone in European energy policies and strategies is biomass and bioenergy. The annual demand for biomass for energy is estimated to increase from the current level of 5.7 EJ to 10.0 EJ in 2020. Assessments of bioenergy potentials vary substantially due to methodological inconsistency and assumptions applied by individual authors. Forest biomass, agricultural residues and energy crops constitute the three major sources of biomass for energy, with the latter probably developing into the most important source over the 21st century. Land use and the changes thereof is a key issue in sustainable bioenergy production as land availability is an ultimately limiting factor. PMID:22546368

  10. Analysis of Biomass Feedstock Availability and Variability for the Peace River Region of Alberta, Canada

    SciTech Connect

    Stephen, Jamie; Sokhansanj, Shahabaddine; Bi, X.T.; Sowlati, T.; Kloeck, T.; Townley-Smith, Lawrence; Stumborg, Mark

    2009-11-01

    Biorefineries or other biomass-dependent facilities require a predictable, dependable feedstock supplied over many years to justify capital investments. Determining inter-year variability in biomass availability is essential to quantifying the feedstock supply risk. Using a geographic information system (GIS) and historic crop yield data, average production was estimated for 10 sites in the Peace River region of Alberta, Canada. Four high-yielding potential sites were investigated for variability over a 20 year time-frame (1980 2000). The range of availability was large, from double the average in maximum years to nothing in minimum years. Biomass availability is a function of grain yield, the biomass to grain ratio, the cropping frequency, and residue retention rate to ensure future crop productivity. Storage strategies must be implemented and alternate feedstock sources identified to supply biomass processing facilities in low-yield years.

  11. Growing perennial forages for biomass

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Recent attention given to converting biomass into ethanol to fuel cars and trucks or burning it to generate electricity has captured society’s interest. There are three main routes for converting biomass into usable forms of energy or other chemical end products: (i) biochemical, (ii) thermochemical...

  12. Biomass Production and Soil Carbon

    Technology Transfer Automated Retrieval System (TEKTRAN)

    There is expanding interest in harvesting crop biomass for energy. Crop biomass such as corn stover, wheat straw, soybean straw or other crop straws can be used as feedstock to support several bioenergy platforms (cellulosic ethanol, gasification or pyrolysis). There are potential benefits for using...

  13. Process for concentrated biomass saccharification

    DOEpatents

    Hennessey, Susan M.; Seapan, Mayis; Elander, Richard T.; Tucker, Melvin P.

    2010-10-05

    Processes for saccharification of pretreated biomass to obtain high concentrations of fermentable sugars are provided. Specifically, a process was developed that uses a fed batch approach with particle size reduction to provide a high dry weight of biomass content enzymatic saccharification reaction, which produces a high sugars concentration hydrolysate, using a low cost reactor system.

  14. Enzymatic hydrolysis of biomass from wood.

    PubMed

    Álvarez, Consolación; Reyes-Sosa, Francisco Manuel; Díez, Bruno

    2016-03-01

    Current research and development in cellulosic ethanol production has been focused mainly on agricultural residues and dedicated energy crops such as corn stover and switchgrass; however, woody biomass remains a very important feedstock for ethanol production. The precise composition of hemicellulose in the wood is strongly dependent on the plant species, therefore different types of enzymes are needed based on hemicellulose complexity and type of pretreatment. In general, hardwood species have much lower recalcitrance to enzymes than softwood. For hardwood, xylanases, beta-xylosidases and xyloglucanases are the main hemicellulases involved in degradation of the hemicellulose backbone, while for softwood the effect of mannanases and beta-mannosidases is more relevant. Furthermore, there are different key accessory enzymes involved in removing the hemicellulosic fraction and increasing accessibility of cellulases to the cellulose fibres improving the hydrolysis process. A diversity of enzymatic cocktails has been tested using from low to high densities of biomass (2-20% total solids) and a broad range of results has been obtained. The performance of recently developed commercial cocktails on hardwoods and softwoods will enable a further step for the commercialization of fuel ethanol from wood. PMID:26833542

  15. Woody biomass phytoremediation of contaminated brownfield land.

    PubMed

    French, Christopher J; Dickinson, Nicholas M; Putwain, Philip D

    2006-06-01

    Economic and environmental regeneration of post-industrial landscapes frequently involves some element of re-afforestation or tree planting. We report field trials that evaluate whether woody biomass production is compatible with managing residual trace element contamination in brownfield soils. Large-scale mapping of contamination showed a heterogenous dispersion of metals and arsenic, and highly localised within-site hotspots. Yields of Salix, Populus and Alnus were economically viable, showing that short-rotation coppice has a potentially valuable role in community forestry. Mass balance modelling demonstrated that phytoextraction potentially could reduce contamination hotspots of more mobile elements (Cd and Zn) within a 25-30-year life cycle of the crops. Cd and Zn in stems and foliage of Salix were 4-13 times higher than EDTA-extractable soil concentrations. Lability of other trace elements (As, Pb, Cu, Ni) was not increased 3 years after planting the coppice; woody biomass may provide an effective reduction of exposure (phyto-stabilization) to these less mobile contaminants. PMID:16271426

  16. MUNICIPAL WATER POLLUTION CONTROL ABSTRACTS: NOVEMBER 1976-OCTOBER 1977

    EPA Science Inventory

    The Franklin Institute Research Laboratories, Science Information Services Department, prepared for the Environmental Protection Agency Volume 4 of the Municipal Technology Bulletin, a current-awareness abstracting bulletin covering methods of municipal waste water treatment, pro...

  17. MUNICIPAL WATER POLLUTION CONTROL ABSTRACTS: MAY-OCTOBER 1976

    EPA Science Inventory

    The Franklin Institute Research Laboratories, Science Information Services Department prepared for the Environmental Protection Agency, Volume 4 of a monthly current-awareness abstracting bulletin, Municipal Technology Bulletin, which dealt with methods of municipal waste water t...

  18. MUNICIPAL WATER POLLUTION CONTROL ABSTRACTS: APRIL 1975-MARCH 1976

    EPA Science Inventory

    The Franklin Institute Research Laboratories, Science Information Services Department prepared for the Environmental Protection Agency, Volume 3 of a monthly current-awareness abstracting bulletin, Municipal Technology Bulletin, which dealt with methods of municipal waste water t...

  19. 124. PLAN OF IMPROVEMENT, HUNTINGTON BEACH MUNICIPAL PIER: RAMP DETAILS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    124. PLAN OF IMPROVEMENT, HUNTINGTON BEACH MUNICIPAL PIER: RAMP DETAILS Sheet 6 of 11 (#3278) - Huntington Beach Municipal Pier, Pacific Coast Highway at Main Street, Huntington Beach, Orange County, CA

  20. 120. PLAN OF IMPROVEMENT, HUNTINGTON BEACH MUNICIPAL PIER: LAYOUT OF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    120. PLAN OF IMPROVEMENT, HUNTINGTON BEACH MUNICIPAL PIER: LAYOUT OF EXISTING PIER Sheet 2 of 11 (#3274) - Huntington Beach Municipal Pier, Pacific Coast Highway at Main Street, Huntington Beach, Orange County, CA