Conversion of nitrogen oxides in N2:O2:CO2 and N2:O2:CO2:NO2 mixtures subjected to a dc corona discharge

NASA Astrophysics Data System (ADS)

Dors, Mirosław; Mizeraczyk, Jerzy

1996-10-01

This paper concerns the influence of a direct current (dc) corona discharge on production and reduction of NO, NO2 and N2O in N2:O2:CO2 and N2:O2:CO2:NO2 mixtures. The corona discharge was generated in a needle-to-plate reactor. The positively polarized electrode consisted of 7 needles. The grounded electrode was a stainless steel plate. The gas flow rate through the reactor was varied from 28 to 110 cm3/s. The time-averaged discharge current ranged from 0 to 6 mA. It was found that in the N2:O2:CO2 mixture the corona discharge produced NO, NO2 and N2O. In the N2:O2:CO2:NO2 mixture the reduction of NO2 was between 6-56%, depending on the concentration of O2, gas flow rate and corona discharge current. The NO2 reduction was accompanied by production of NO and N2O. The results show that efficient reduction of nitrogen oxides by a corona discharge cannot be expected in the mixtures containing N2 and O2 if reducing additives are not employed.

Reduced gas seepages in serpentinized peridotite complexes: Evidences for multiple origins of the H2-CH4-N2 gas mixtures

NASA Astrophysics Data System (ADS)

Deville, E.; Vacquand, C.; Beaumont, V.; Francois, G.; Sissmann, O.; Pillot, D.; Arcilla, C. A.; Prinzhofer, A.

2017-12-01

A comparative study of reduced gas seepages associated to serpentinized ultrabasic rocks was conducted in the ophiolitic complexes of Oman, the Philippines, Turkey and New Caledonia. This study is based on analyzes of the gas chemical composition, noble gases contents, and stable isotopes of carbon, hydrogen and nitrogen. These gas seepages are mostly made of mixtures of three main components which are H2, CH4 and N2 in various proportions. The relative contents of the three main gas components show 4 distinct families of gas mixtures (H2-rich, N2-rich, N2-H2-CH4 and H2-CH4). These families are interpreted as reflecting different zones of gas generation within or below the ophiolitic complexes. In the H2-rich family associated noble gases display signatures close to the value of air. In addition to the atmospheric component, mantle and crustal contributions are present in the N2-rich, N2-H2-CH4 and H2-CH4 families. H2-bearing gases are either associated to ultra-basic (pH 10-12) spring waters or they seep directly in fracture systems from the ophiolitic rocks. In ophiolitic contexts, ultrabasic rocks provide an adequate environment with available Fe2+ and high pH conditions that favor H2 production. CH4 is produced either directly by reaction of dissolved CO2 with basic-ultrabasic rocks during the serpentinization process or in a second step by H2-CO2 interaction. H2 is present in the gas when no more carbon is available in the system to generate CH4 (conditions of strong carbon restriction). The N2-rich family is associated with relatively high contents of crustal 4He. In this family N2 is interpreted as issued mainly from sediments located below the ophiolitic units.

Gas flow through rough microchannels in the transition flow regime.

PubMed

Deng, Zilong; Chen, Yongping; Shao, Chenxi

2016-01-01

A multiple-relaxation-time lattice Boltzmann model of Couette flow is developed to investigate the rarified gas flow through microchannels with roughness characterized by fractal geometry, especially to elucidate the coupled effects of roughness and rarefaction on microscale gas flow in the transition flow regime. The results indicate that the surface roughness effect on gas flow behavior becomes more significant in rarefied gas flow with the increase of Knudsen number. We find the gas flow behavior in the transition flow regime is more sensitive to roughness height than that in the slip flow regime. In particular, the influence of fractal dimension on rarefied gas flow behavior is less significant than roughness height.

Rarefied gas flow simulations using high-order gas-kinetic unified algorithms for Boltzmann model equations

NASA Astrophysics Data System (ADS)

Li, Zhi-Hui; Peng, Ao-Ping; Zhang, Han-Xin; Yang, Jaw-Yen

2015-04-01

This article reviews rarefied gas flow computations based on nonlinear model Boltzmann equations using deterministic high-order gas-kinetic unified algorithms (GKUA) in phase space. The nonlinear Boltzmann model equations considered include the BGK model, the Shakhov model, the Ellipsoidal Statistical model and the Morse model. Several high-order gas-kinetic unified algorithms, which combine the discrete velocity ordinate method in velocity space and the compact high-order finite-difference schemes in physical space, are developed. The parallel strategies implemented with the accompanying algorithms are of equal importance. Accurate computations of rarefied gas flow problems using various kinetic models over wide ranges of Mach numbers 1.2-20 and Knudsen numbers 0.0001-5 are reported. The effects of different high resolution schemes on the flow resolution under the same discrete velocity ordinate method are studied. A conservative discrete velocity ordinate method to ensure the kinetic compatibility condition is also implemented. The present algorithms are tested for the one-dimensional unsteady shock-tube problems with various Knudsen numbers, the steady normal shock wave structures for different Mach numbers, the two-dimensional flows past a circular cylinder and a NACA 0012 airfoil to verify the present methodology and to simulate gas transport phenomena covering various flow regimes. Illustrations of large scale parallel computations of three-dimensional hypersonic rarefied flows over the reusable sphere-cone satellite and the re-entry spacecraft using almost the largest computer systems available in China are also reported. The present computed results are compared with the theoretical prediction from gas dynamics, related DSMC results, slip N-S solutions and experimental data, and good agreement can be found. The numerical experience indicates that although the direct model Boltzmann equation solver in phase space can be computationally expensive

Stability of Buoyancy-Driven Gas Flow: Visualization of Coherent and Incoherent Gas Flow Patterns and Capillary Trapping

NASA Astrophysics Data System (ADS)

Geistlinger, H. W.; Samani, S.; Pohlert, M.; Jia, R.; Lazik, D.

2009-12-01

sequestration mechanisms. In order to investigate the stability of buoyancy-driven gas flow and the transition between coherent flow, incoherent flow, and their correlation to capillary trapping, we conducted high-resolution optical bench scale experiments. We observed a grain-size (dk) - and flow-rate (Q) dependent transition from incoherent to coherent flow. Based on core-annular flow (= cooperative pore-body filling), we propose a dynamic stability criterion that could describe our experimental results. Our experimental results for vertical gas flow support the experimental results by Lenormand et al. [1983] obtained for horizontal flow, if one takes into account that gravity leads to more unstable flow conditions. Our main results, which are in strong contradiction to the accepted conceptual model of the sloped aquifer, are: (1) Capillary Trapping can already occur during injection and at the front of the plume [Lazik et al., 2008] (2) Gas clusters or bubbles can be mobile (incoherent gas flow) and immobile (capillary trapping), and (3) Incoherent gas flow can not be described by a generalized Darcy law [Geistlinger et al., 2006, 2009].

Real-Gas Flow Properties for NASA Langley Research Center Aerothermodynamic Facilities Complex Wind Tunnels

NASA Technical Reports Server (NTRS)

Hollis, Brian R.

1996-01-01

A computational algorithm has been developed which can be employed to determine the flow properties of an arbitrary real (virial) gas in a wind tunnel. A multiple-coefficient virial gas equation of state and the assumption of isentropic flow are used to model the gas and to compute flow properties throughout the wind tunnel. This algorithm has been used to calculate flow properties for the wind tunnels of the Aerothermodynamics Facilities Complex at the NASA Langley Research Center, in which air, CF4. He, and N2 are employed as test gases. The algorithm is detailed in this paper and sample results are presented for each of the Aerothermodynamic Facilities Complex wind tunnels.

Integrated CO2 capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow

NASA Astrophysics Data System (ADS)

Vishwakarma, Niraj K.; Singh, Ajay K.; Hwang, Yoon-Ho; Ko, Dong-Hyeon; Kim, Jin-Oh; Babu, A. Giridhar; Kim, Dong-Pyo

2017-03-01

Simultaneous capture of carbon dioxide (CO2) and its utilization with subsequent work-up would significantly enhance the competitiveness of CO2-based sustainable chemistry over petroleum-based chemistry. Here we report an interfacial catalytic reaction platform for an integrated autonomous process of simultaneously capturing/fixing CO2 in gas-liquid laminar flow with subsequently providing a work-up step. The continuous-flow microreactor has built-in silicon nanowires (SiNWs) with immobilized ionic liquid catalysts on tips of cone-shaped nanowire bundles. Because of the superamphiphobic SiNWs, a stable gas-liquid interface maintains between liquid flow of organoamines in upper part and gas flow of CO2 in bottom part of channel. The intimate and direct contact of the binary reagents leads to enhanced mass transfer and facilitating reactions. The autonomous integrated platform produces and isolates 2-oxazolidinones and quinazolines-2,4(1H,3H)-diones with 81-97% yields under mild conditions. The platform would enable direct CO2 utilization to produce high-valued specialty chemicals from flue gases without pre-separation and work-up steps.

Integrated CO2 capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow.

PubMed

Vishwakarma, Niraj K; Singh, Ajay K; Hwang, Yoon-Ho; Ko, Dong-Hyeon; Kim, Jin-Oh; Babu, A Giridhar; Kim, Dong-Pyo

2017-03-06

Simultaneous capture of carbon dioxide (CO 2 ) and its utilization with subsequent work-up would significantly enhance the competitiveness of CO 2 -based sustainable chemistry over petroleum-based chemistry. Here we report an interfacial catalytic reaction platform for an integrated autonomous process of simultaneously capturing/fixing CO 2 in gas-liquid laminar flow with subsequently providing a work-up step. The continuous-flow microreactor has built-in silicon nanowires (SiNWs) with immobilized ionic liquid catalysts on tips of cone-shaped nanowire bundles. Because of the superamphiphobic SiNWs, a stable gas-liquid interface maintains between liquid flow of organoamines in upper part and gas flow of CO 2 in bottom part of channel. The intimate and direct contact of the binary reagents leads to enhanced mass transfer and facilitating reactions. The autonomous integrated platform produces and isolates 2-oxazolidinones and quinazolines-2,4(1H,3H)-diones with 81-97% yields under mild conditions. The platform would enable direct CO 2 utilization to produce high-valued specialty chemicals from flue gases without pre-separation and work-up steps.

CO2 Capture by Injection of Flue Gas or CO2-N2 Mixtures into Hydrate Reservoirs: Dependence of CO2 Capture Efficiency on Gas Hydrate Reservoir Conditions.

PubMed

Hassanpouryouzband, Aliakbar; Yang, Jinhai; Tohidi, Bahman; Chuvilin, Evgeny; Istomin, Vladimir; Bukhanov, Boris; Cheremisin, Alexey

2018-04-03

Injection of flue gas or CO 2 -N 2 mixtures into gas hydrate reservoirs has been considered as a promising option for geological storage of CO 2 . However, the thermodynamic process in which the CO 2 present in flue gas or a CO 2 -N 2 mixture is captured as hydrate has not been well understood. In this work, a series of experiments were conducted to investigate the dependence of CO 2 capture efficiency on reservoir conditions. The CO 2 capture efficiency was investigated at different injection pressures from 2.6 to 23.8 MPa and hydrate reservoir temperatures from 273.2 to 283.2 K in the presence of two different saturations of methane hydrate. The results showed that more than 60% of the CO 2 in the flue gas was captured and stored as CO 2 hydrate or CO 2 -mixed hydrates, while methane-rich gas was produced. The efficiency of CO 2 capture depends on the reservoir conditions including temperature, pressure, and hydrate saturation. For a certain reservoir temperature, there is an optimum reservoir pressure at which the maximum amount of CO 2 can be captured from the injected flue gas or CO 2 -N 2 mixtures. This finding suggests that it is essential to control the injection pressure to enhance CO 2 capture efficiency by flue gas or CO 2 -N 2 mixtures injection.

The RealGas and RealGasH2O options of the TOUGH+ code for the simulation of coupled fluid and heat flow in tight/shale gas systems

EPA Science Inventory

We developed two new EOS additions to the TOUGH+ family of codes, the RealGasH2O and RealGas. The RealGasH2O EOS option describes the non-isothermal two-phase flow of water and a real gas mixture in gas reservoirs, with a particular focus in ultra-tight (such as tight-sand and sh...

Flow Simulation of N2B Hybrid Wing Body Configuration

NASA Technical Reports Server (NTRS)

Kim, Hyoungjin; Liou, Meng-Sing

2012-01-01

The N2B hybrid wing body aircraft was conceptually designed to meet environmental and performance goals for the N+2 generation transport set by the subsonic fixed wing project. In this study, flow fields around the N2B configuration is simulated using a Reynolds-averaged Navier-Stokes flow solver using unstructured meshes. Boundary conditions at engine fan face and nozzle exhaust planes are provided by response surfaces of the NPSS thermodynamic engine cycle model. The present flow simulations reveal challenging design issues arising from boundary layer ingestion offset inlet and nacelle-airframe interference. The N2B configuration can be a good test bed for application of multidisciplinary design optimization technology.

Laser cross-flow gas system

DOEpatents

Duncan, David B.

1992-01-01

A method and laser apparatus are disclosed which provide for a cross-flow of gas near one end of a laser discharge tube. The cross-flow of gas causes a concentration gradient which affects diffusion of contaminants in the discharge tube towards the cross-flow of the gas, which contaminants are then withdrawn from the discharge tube.

Laser cross-flow gas system

DOEpatents

Duncan, D.B.

1992-11-24

A method and laser apparatus are disclosed which provide for a cross-flow of gas near one end of a laser discharge tube. The cross-flow of gas causes a concentration gradient which affects diffusion of contaminants in the discharge tube towards the cross-flow of the gas, which contaminants are then withdrawn from the discharge tube. 1 figure.

N = 1 Deformations and RG flows of N = 2 SCFTs, part II: non-principal deformations

DOE PAGES

Agarwal, Prarit; Maruyoshi, Kazunobu; Song, Jaewon

2016-12-20

We continue to investigate the N = 1 deformations of four-dimensional N = 2 superconformal field theories (SCFTs) labeled by a nilpotent element of the flavor symmetry [1]. This triggers a renormalization group (RG) flow to an N = 1 SCFT. We systematically analyze all possible deformations of this type for certain classes of N = 2 SCFTs: conformal SQCDs, generalized Argyres-Douglas theories and the E 6 SCFT. We find a number of examples where the amount of supersymmetry gets enhanced to N = 2 at the end point of the RG flow. Most notably, we find that the SU(N)more » and Sp(N) conformal SQCDs can be deformed to flow to the Argyres-Douglas (AD) theories of type (A 1,D 2 N-1) and (A 1,D 2 N) respectively. This RG flow therefore allows us to compute the full superconformal index of the (A 1,D N) class of AD theories. Moreover, we find an infrared duality between N = 1 theories where the fixed point is described by an N = 2 AD theory. We observe that the classes of examples that exhibit supersymmetry enhancement saturate certain bounds for the central charges implied by the associated two-dimensional chiral algebra.« less

N = 1 Deformations and RG flows of N = 2 SCFTs, part II: non-principal deformations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Agarwal, Prarit; Maruyoshi, Kazunobu; Song, Jaewon

We continue to investigate the N = 1 deformations of four-dimensional N = 2 superconformal field theories (SCFTs) labeled by a nilpotent element of the flavor symmetry [1]. This triggers a renormalization group (RG) flow to an N = 1 SCFT. We systematically analyze all possible deformations of this type for certain classes of N = 2 SCFTs: conformal SQCDs, generalized Argyres-Douglas theories and the E 6 SCFT. We find a number of examples where the amount of supersymmetry gets enhanced to N = 2 at the end point of the RG flow. Most notably, we find that the SU(N)more » and Sp(N) conformal SQCDs can be deformed to flow to the Argyres-Douglas (AD) theories of type (A 1,D 2 N-1) and (A 1,D 2 N) respectively. This RG flow therefore allows us to compute the full superconformal index of the (A 1,D N) class of AD theories. Moreover, we find an infrared duality between N = 1 theories where the fixed point is described by an N = 2 AD theory. We observe that the classes of examples that exhibit supersymmetry enhancement saturate certain bounds for the central charges implied by the associated two-dimensional chiral algebra.« less

Applying Alkyl-Chain Surface Functionalizations in Mesoporous Inorganic Structures: Their Impact on Gas Flow and Selectivity Depending on Temperature.

PubMed

Besser, Benjamin; Ahmed, Atiq; Baune, Michael; Kroll, Stephen; Thöming, Jorg; Rezwan, Kurosch

2016-10-12

Porous inorganic capillary membranes are prepared to serve as model structures for the experimental investigation of the gas transport in functionalized mesopores. The porous structures possess a mean pore diameter of 23 nm which is slightly reduced to 20 nm after immobilizing C 16 -alkyl chains on the surface. Gas permeation measurements are performed at temperatures ranging from 0 to 80 °C using Ar, N 2 , and CO 2 . Nonfunctionalized structures feature a gas transport according to Knudsen diffusion with regard to gas flow and selectivity. After C 16 -functionalization, the gas flow is reduced by a factor of 10, and the ideal selectivities deviate from the Knudsen theory. CO 2 adsorption measurements show a decrease in total amount of adsorbed gas and isosteric heat of adsorption. It is hypothesized that the immobilized C 16 -chains sterically influence the gas transport behavior without a contribution from adsorption effects. The reduced gas flow derives from an additional surface resistance caused by the C 16 -chains spacially limiting the adsorption and desorption directions for gas molecules propagating through the structure, resulting in longer diffusion paths. In agreement, the gas flow is found to correlate with the molecular diameter of the gas species (CO 2 < Ar < N 2 ) increasing the resistance for larger molecules. This affects the ideal selectivities with the relation [Formula: see text]. The influence on selectivity increases with increasing temperature which leads to the conclusion that the temperature induced movement of the C 16 -chains is responsible for the stronger interaction between gas molecules and surface functional groups.

The carrier gas pressure effect in a laminar flow diffusion chamber, homogeneous nucleation of n-butanol in helium.

PubMed

Hyvärinen, Antti-Pekka; Brus, David; Zdímal, Vladimír; Smolík, Jiri; Kulmala, Markku; Viisanen, Yrjö; Lihavainen, Heikki

2006-06-14

Homogeneous nucleation rate isotherms of n-butanol+helium were measured in a laminar flow diffusion chamber at total pressures ranging from 50 to 210 kPa to investigate the effect of carrier gas pressure on nucleation. Nucleation temperatures ranged from 265 to 280 K and the measured nucleation rates were between 10(2) and 10(6) cm(-3) s(-1). The measured nucleation rates decreased as a function of increasing pressure. The pressure effect was strongest at pressures below 100 kPa. This negative carrier gas effect was also temperature dependent. At nucleation temperature of 280 K and at the same saturation ratio, the maximum deviation between nucleation rates measured at 50 and 210 kPa was about three orders of magnitude. At nucleation temperature of 265 K, the effect was negligible. Qualitatively the results resemble those measured in a thermal diffusion cloud chamber. Also the slopes of the isothermal nucleation rates as a function of saturation ratio were different as a function of total pressure, 50 kPa isotherms yielded the steepest slopes, and 210 kPa isotherms the shallowest slopes. Several sources of inaccuracies were considered in the interpretation of the results: uncertainties in the transport properties, nonideal behavior of the vapor-carrier gas mixture, and shortcomings of the used mathematical model. Operation characteristics of the laminar flow diffusion chamber at both under-and over-pressure were determined to verify a correct and stable operation of the device. We conclude that a negative carrier gas pressure effect is seen in the laminar flow diffusion chamber and it cannot be totally explained with the aforementioned reasons.

Numerical Simulation and Industrial Experimental Research on the Coherent Jet with "CH4 + N2" Mixed Fuel Gas

NASA Astrophysics Data System (ADS)

Hu, Shaoyan; Zhu, Rong; Dong, Kai; Liu, Runzao

2018-06-01

Coherent jet technology is widely used in the electric arc furnace (EAF) steelmaking process to deliver more energy and momentum into the molten steel bath. Meanwhile, the characteristics of a coherent jet using pure CH4 as the fuel gas have been well investigated in previous studies. To reduce the consumption of CH4, coherent jet technology using "CH4 + N2" mixed fuel gas instead of pure CH4 was proposed and studied in detail by numerical simulation in the present work. The Eddy Dissipation Concept model, which has detailed chemical kinetic mechanisms, was adopted to model the fuel gas combustion reactions. Experimental measurements were carried out to validate the accuracy of the computational model. The present study shows that the jet characteristics of the main oxygen improve along with the increase of the CH4 ratio in fuel gas and with the increase of the flow rate of fuel gas. When the CH4 ratio in the fuel gas is 25 pct, the fuel gas flow rate only has a limited influence on the jet characteristics, unlike the rest of the fuel gas compositions, because a high N2 proportion deteriorates the combustion performance and leads to severe incomplete combustion. Moreover, a false potential core phenomenon was observed and explained in the present study. Based on the average values, the jet length of a coherent jet with 75 pct CH4 can achieve 89.8 pct of that with 100 pct CH4. Finally, an industrial experiment was carried out on a commercial 100t EAF using coherent jet with 75 pct CH4, showing that the average CH4 consumption was reduced from 3.84 to 3.05 Nm3 t-1 under the premise of no obvious changes in the other production indexes.

Non Lyapunov stability of a constant spatially developing 2-D gas flow

NASA Astrophysics Data System (ADS)

Balint, Agneta M.; Balint, Stefan; Tanasie, Loredana

2017-01-01

Different types of stabilities (global, local) and instabilities (global absolute, local convective) of the constant spatially developing 2-D gas flow are analyzed in a particular phase space of continuously differentiable functions, endowed with the usual algebraic operations and the topology generated by the uniform convergence on the plane. For this purpose the Euler equations linearized at the constant flow are used. The Lyapunov stability analysis was presented in [1] and this paper is a continuation of [1].

$$ \\mathcal{N}=1 $$ deformations and RG flows of $$ \\mathcal{N}=2 $$ SCFTs

DOE PAGES

Maruyoshi, Kazunobu; Song, Jaewon

2017-02-14

Here, we study certainmore » $$ \\mathcal{N}=1 $$ preserving deformations of four-dimensional $$ \\mathcal{N}=2 $$ superconformal field theories (SCFTs) with non-abelian flavor symmetry. The deformation is described by adding an $$ \\mathcal{N}=1 $$ chiral multiplet transforming in the adjoint representation of the flavor symmetry with a superpotential coupling, and giving a nilpotent vacuum expectation value to the chiral multiplet which breaks the flavor symmetry. This triggers a renormalization group flow to an infrared SCFT. Remarkably, we find classes of theories flow to enhanced $$ \\mathcal{N}=2 $$ supersymmetric fixed points in the infrared under the deformation. They include generalized Argyres-Douglas theories and rank-one SCFTs with non-abelian flavor symmetries. Most notably, we find renormalization group flows from the deformed conformal SQCDs to the ( A1,An) Argyres-Douglas theories. From these "Lagrangian descriptions," we compute the full superconformal indices of the ( A1,An) theories and find agreements with the previous results. Furthermore, we study the cases, including the TN and R0,N theories of class S and some of rank-one SCFTs, where the deformation gives genuine $$ \\mathcal{N}=1 $$ fixed points.« less

$$ \\mathcal{N}=1 $$ deformations and RG flows of $$ \\mathcal{N}=2 $$ SCFTs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maruyoshi, Kazunobu; Song, Jaewon

Here, we study certainmore » $$ \\mathcal{N}=1 $$ preserving deformations of four-dimensional $$ \\mathcal{N}=2 $$ superconformal field theories (SCFTs) with non-abelian flavor symmetry. The deformation is described by adding an $$ \\mathcal{N}=1 $$ chiral multiplet transforming in the adjoint representation of the flavor symmetry with a superpotential coupling, and giving a nilpotent vacuum expectation value to the chiral multiplet which breaks the flavor symmetry. This triggers a renormalization group flow to an infrared SCFT. Remarkably, we find classes of theories flow to enhanced $$ \\mathcal{N}=2 $$ supersymmetric fixed points in the infrared under the deformation. They include generalized Argyres-Douglas theories and rank-one SCFTs with non-abelian flavor symmetries. Most notably, we find renormalization group flows from the deformed conformal SQCDs to the ( A1,An) Argyres-Douglas theories. From these "Lagrangian descriptions," we compute the full superconformal indices of the ( A1,An) theories and find agreements with the previous results. Furthermore, we study the cases, including the TN and R0,N theories of class S and some of rank-one SCFTs, where the deformation gives genuine $$ \\mathcal{N}=1 $$ fixed points.« less

Project Rulison gas flow analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montan, D.N.

1971-01-01

An analysis of the well performance was attempted by fitting a simple model of the chimney, gas sands, and explosively created fracturing to the 2 experimentally measured variables, flow rate, and chimney pressure. The gas-flow calculations for various trial models were done by a finite difference solution to the nonlinear partial differential equation for radial Darcy flow. The TRUMP computer program was used to perform the numerical calculations. In principle, either the flow rate or the chimney pressure could be used as the independent variable in the calculations. In the present case, the flow rate was used as the independentmore » variable, since chimney pressure measurements were not made until after the second flow period in early Nov. 1970. Furthermore, the formation pressure was not accurately known and, hence, was considered a variable parameter in the modeling process. The chimney pressure was assumed equal to the formation pressure at the beginning of the flow testing. The model consisted of a central zone, representing the chimney, surrounded by a number of concentric zones, representing the formation. The effect of explosive fracturing was simulated by increasing the permeability in the zones near the central zone.« less

Gas flow path for a gas turbine engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Montgomery, Matthew D.; Charron, Richard C.; Snyder, Gary D.

A duct arrangement in a can annular gas turbine engine. The gas turbine engine has a gas delivery structure for delivering gases from a plurality of combustors to an annular chamber that extends circumferentially and is oriented concentric to a gas turbine engine longitudinal axis for delivering the gas flow to a first row of blades A gas flow path is formed by the duct arrangement between a respective combustor and the annular chamber for conveying gases from each combustor to the first row of turbine blades The duct arrangement includes at least one straight section having a centerline thatmore » is misaligned with a centerline of the combustor.« less

Laboratory Study of the Displacement Coalbed CH4 Process and Efficiency of CO2 and N2 Injection

PubMed Central

Wang, Liguo; Wang, Yongkang

2014-01-01

ECBM displacement experiments are a direct way to observe the gas displacement process and efficiency by inspecting the produced gas composition and flow rate. We conducted two sets of ECBM experiments by injecting N2 and CO2 through four large parallel specimens (300 × 50 × 50 mm coal briquette). N2 or CO2 is injected at pressures of 1.5, 1.8, and 2.2 MPa and various crustal stresses. The changes in pressure along the briquette and the concentration of the gas mixture flowing out of the briquette were analyzed. Gas injection significantly enhances CBM recovery. Experimental recoveries of the original extant gas are in excess of 90% for all cases. The results show that the N2 breakthrough occurs earlier than the CO2 breakthrough. The breakthrough time of N2 is approximately 0.5 displaced volumes. Carbon dioxide, however, breaks through at approximately 2 displaced volumes. Coal can adsorb CO2, which results in a slower breakthrough time. In addition, ground stress significantly influences the displacement effect of the gas injection. PMID:24741346

Influence of Nitrogen Flow Rate on Friction Coefficient and Surface Roughness of TiN Coatings Deposited on Tool Steel Using Arc Method

NASA Astrophysics Data System (ADS)

Hamzah, Esah; Ourdjini, Ali; Ali, Mubarak; Akhter, Parvez; Hj. Mohd Toff, Mohd Radzi; Abdul Hamid, Mansor

In the present study, the effect of various N2 gas flow rates on friction coefficient and surface roughness of TiN-coated D2 tool steel was examined by a commercially available cathodic arc physical vapor deposition (CAPVD) technique. A Pin-on-Disc test was carried out to study the Coefficient of friction (COF) versus sliding distance. A surface roughness tester measured the surface roughness parameters. The minimum values for the COF and surface roughness were recorded at a N2 gas flow rate of 200 sccm. The increase in the COF and surface roughness at a N2 gas flow rate of 100 sccm was mainly attributed to an increase in both size and number of titanium particles, whereas the increase at 300 sccm was attributed to a larger number of growth defects generated during the coating process. These ideas make it possible to optimize the coating properties as a function of N2 gas flow rate for specific applications, e.g. cutting tools for automobiles, aircraft, and various mechanical parts.

Paraelectric gas flow accelerator

NASA Technical Reports Server (NTRS)

Sherman, Daniel M. (Inventor); Wilkinson, Stephen P. (Inventor); Roth, J. Reece (Inventor)

2001-01-01

A substrate is configured with first and second sets of electrodes, where the second set of electrodes is positioned asymmetrically between the first set of electrodes. When a RF voltage is applied to the electrodes sufficient to generate a discharge plasma (e.g., a one-atmosphere uniform glow discharge plasma) in the gas adjacent to the substrate, the asymmetry in the electrode configuration results in force being applied to the active species in the plasma and in turn to the neutral background gas. Depending on the relative orientation of the electrodes to the gas, the present invention can be used to accelerate or decelerate the gas. The present invention has many potential applications, including increasing or decreasing aerodynamic drag or turbulence, and controlling the flow of active and/or neutral species for such uses as flow separation, altering heat flow, plasma cleaning, sterilization, deposition, etching, or alteration in wettability, printability, and/or adhesion.

Removal of NO in NO/N2, NO/N2/O2, NO/CH4/N2, and NO/CH4/O2/N2 systems by flowing microwave discharges.

PubMed

Hueso, José L; Gonzalez-Elipe, Agustín R; Cotrino, José; Caballero, Alfonso

2007-02-15

In this paper, continuing previous work, we report on experiments carried out to investigate the removal of NO from simulated flue gas in nonthermal plasmas. The plasma-induced decomposition of small concentrations of NO in N2 used as the carrier gas and O2 and CH4 as minority components has been studied in a surface wave discharge induced with a surfatron launcher. The reaction products and efficiency have been monitored by mass spectrometry as a function of the composition of the mixture. NO is effectively decomposed into N2 and O2 even in the presence of O2, provided always that enough CH4 is also present in the mixture. Other majority products of the plasma reactions under these conditions are NH3, CO, and H2. In the absence of O2, decomposition of NO also occurs, although in that case HCN accompanies the other reaction products as a majority component. The plasma for the different reaction mixtures has been characterized by optical emission spectroscopy. Intermediate excited species of NO*, C*, CN*, NH*, and CH* have been monitored depending on the gas mixture. The type of species detected and their evolution with the gas composition are in agreement with the reaction products detected in each case. The observations by mass spectrometry and optical emission spectroscopy are in agreement with the kinetic reaction models available in literature for simple plasma reactions in simple reaction mixtures.

Integral Field Spectroscopy of Markarian 273: Mapping High-Velocity Gas Flows and an Off-Nucleus Seyfert 2 Nebula.

PubMed

Colina; Arribas; Borne

1999-12-10

Integral field optical spectroscopy with the INTEGRAL fiber-based system is used to map the extended ionized regions and gas flows in Mrk 273, one of the closest ultraluminous infrared galaxies. The Hbeta and [O iii] lambda5007 maps show the presence of two distinct regions separated by 4&arcsec; (3.1 kpc) along position angle (P.A.) 240 degrees. The northeastern region coincides with the optical nucleus of the galaxy and shows the spectral characteristics of LINERs. The southwestern region is dominated by [O iii] emission and is classified as a Seyfert 2. Therefore, in the optical, Mrk 273 is an ultraluminous infrared galaxy with a LINER nucleus and an extended off-nucleus Seyfert 2 nebula. The kinematics of the [O iii] ionized gas shows (1) the presence of highly disturbed gas in the regions around the LINER nucleus, (2) a high-velocity gas flow with a peak-to-peak amplitude of 2.4x103 km s-1, and (3) quiescent gas in the outer regions (at 3 kpc). We hypothesize that the high-velocity flow is the starburst-driven superwind generated in an optically obscured nuclear starburst and that the quiescent gas is directly ionized by a nuclear source, similar to the ionization cones typically seen in Seyfert galaxies.

Distribution of E/N and N sub e in a cross-flow electric discharge laser

NASA Technical Reports Server (NTRS)

Dunning, J. W., Jr.; Lancashire, R. B.; Manista, E. J.

1976-01-01

The spatial distribution of the ratio of electric field to neutral gas density on a flowing gas, multiple pin-to-plane discharge was measured in a high-power, closed loop laser. The laser was operated at a pressure of 140 torr (1:7:20, CO2, N2, He) with typically a 100 meter/second velocity in the 5 x 8 x 135 centimeter discharge volume. E/N ratios ranged from 2.7 x 10 to the minus 16th power to 1.4 x 10 to the minus 16th power volts/cu cm along the discharge while the electron density ranged from 2.8 x 10 to the 10th power to 1.2 x 10 to the 10th power cm/3.

Swirling flow of a dissociated gas

NASA Technical Reports Server (NTRS)

Wolfram, W. R., Jr.; Walker, W. F.

1975-01-01

Most physical applications of the swirling flow, defined as a vortex superimposed on an axial flow in the nozzle, involve high temperatures and the possibility of real gas effects. The generalized one-dimensional swirling flow in a converging-diverging nozzle is analyzed for equilibrium and frozen dissociation using the ideal dissociating gas model. Numerical results are provided to illustrate the major effects and to compare with results obtained for a perfect gas with constant ratio of specific heats. It is found that, even in the case of real gases, perfect gas calculations can give a good estimate of the reduction in mass flow due to swirl.

Asymptotic research of transonic gas flows

NASA Astrophysics Data System (ADS)

Velmisov, Petr A.; Tamarova, Yuliya A.

2017-12-01

The article is dedicated to the development asymptotic theory of gas flowing at speed next to sound velocity, particularly of gas transonic flows, i.e. the flows, containing both, subsonic and supersonic areas. The main issue, when styding such flows, are nonlinearity and combined type of equations, describing the transonic flow. Based on asymptotic nonlinear equation obtained in the article, the gas transonic flows is studied, considering transverse disturbance with respect to the main flow. The asymptotic conditions at shock-wave front and conditions on the streamlined surface are found. Moreover, the equation of sound surface and asymptotic formula defining the pressure are recorded. Several exact particular solutions of such equation are given, and their application to solve several tasks of transonic aerodynamics is indicated. Specifically, the polynomial form solution describing gas axisymmetric flows in Laval nozzles with constant acceleration in direction of the nozzle's axis and flow swirling is obtained. The solutions describing the unsteady flow along the channels between spinning surfaces are presented. The asymptotic equation is obtained, describing the flow, appearing during non-separated and separated flow past, closely approximated to cylindrical one. Specific solutions are given, based on which the examples of steady flow are formed.

Coupling compositional liquid gas Darcy and free gas flows at porous and free-flow domains interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Masson, R., E-mail: roland.masson@unice.fr; Team COFFEE INRIA Sophia Antipolis Méditerranée; Trenty, L., E-mail: laurent.trenty@andra.fr

This paper proposes an efficient splitting algorithm to solve coupled liquid gas Darcy and free gas flows at the interface between a porous medium and a free-flow domain. This model is compared to the reduced model introduced in [6] using a 1D approximation of the gas free flow. For that purpose, the gas molar fraction diffusive flux at the interface in the free-flow domain is approximated by a two point flux approximation based on a low-frequency diagonal approximation of a Steklov–Poincaré type operator. The splitting algorithm and the reduced model are applied in particular to the modelling of the massmore » exchanges at the interface between the storage and the ventilation galleries in radioactive waste deposits.« less

The contamination of commercial 15N2 gas stocks with 15N-labeled nitrate and ammonium and consequences for nitrogen fixation measurements.

PubMed

Dabundo, Richard; Lehmann, Moritz F; Treibergs, Lija; Tobias, Craig R; Altabet, Mark A; Moisander, Pia H; Granger, Julie

2014-01-01

We report on the contamination of commercial 15-nitrogen (15N) N2 gas stocks with 15N-enriched ammonium, nitrate and/or nitrite, and nitrous oxide. 15N2 gas is used to estimate N2 fixation rates from incubations of environmental samples by monitoring the incorporation of isotopically labeled 15N2 into organic matter. However, the microbial assimilation of bioavailable 15N-labeled N2 gas contaminants, nitrate, nitrite, and ammonium, is liable to lead to the inflation or false detection of N2 fixation rates. 15N2 gas procured from three major suppliers was analyzed for the presence of these 15N-contaminants. Substantial concentrations of 15N-contaminants were detected in four Sigma-Aldrich 15N2 lecture bottles from two discrete batch syntheses. Per mole of 15N2 gas, 34 to 1900 µmoles of 15N-ammonium, 1.8 to 420 µmoles of 15N-nitrate/nitrite, and ≥21 µmoles of 15N-nitrous oxide were detected. One 15N2 lecture bottle from Campro Scientific contained ≥11 µmoles of 15N-nitrous oxide per mole of 15N2 gas, and no detected 15N-nitrate/nitrite at the given experimental 15N2 tracer dilutions. Two Cambridge Isotopes lecture bottles from discrete batch syntheses contained ≥0.81 µmoles 15N-nitrous oxide per mole 15N2, and trace concentrations of 15N-ammonium and 15N-nitrate/nitrite. 15N2 gas equilibrated cultures of the green algae Dunaliella tertiolecta confirmed that the 15N-contaminants are assimilable. A finite-differencing model parameterized using oceanic field conditions typical of N2 fixation assays suggests that the degree of detected 15N-ammonium contamination could yield inferred N2 fixation rates ranging from undetectable, <0.01 nmoles N L(-1) d(-1), to 530 nmoles N L(-1) d(-1), contingent on experimental conditions. These rates are comparable to, or greater than, N2 fixation rates commonly detected in field assays. These results indicate that past reports of N2 fixation should be interpreted with caution, and demonstrate that the purity of commercial 15N2

Flowing gas, non-nuclear experiments on the gas core reactor

NASA Technical Reports Server (NTRS)

Kunze, J. F.; Suckling, D. H.; Copper, C. G.

1972-01-01

Flow tests were conducted on models of the gas core (cavity) reactor. Variations in cavity wall and injection configurations were aimed at establishing flow patterns that give a maximum of the nuclear criticality eigenvalue. Correlation with the nuclear effect was made using multigroup diffusion theory normalized by previous benchmark critical experiments. Air was used to simulate the hydrogen propellant in the flow tests, and smoked air, argon, or freon to simulate the central nuclear fuel gas. All tests were run in the down-firing direction so that gravitational effects simulated the acceleration effect of a rocket. Results show that acceptable flow patterns with high volume fraction for the simulated nuclear fuel gas and high flow rate ratios of propellant to fuel can be obtained. Using a point injector for the fuel, good flow patterns are obtained by directing the outer gas at high velocity along the cavity wall, using louvered or oblique-angle-honeycomb injection schemes.

Reduction of gas flow nonuniformity in gas turbine engines by means of gas-dynamic methods

NASA Astrophysics Data System (ADS)

Matveev, V.; Baturin, O.; Kolmakova, D.; Popov, G.

2017-08-01

Gas flow nonuniformity is one of the main sources of rotor blade vibrations in the gas turbine engines. Usually, the flow circumferential nonuniformity occurs near the annular frames, located in the flow channel of the engine. This leads to the increased dynamic stresses in blades and as a consequence to the blade damage. The goal of the research was to find an acceptable method of reducing the level of gas flow nonuniformity as the source of dynamic stresses in the rotor blades. Two different methods were investigated during this research. Thus, this study gives the ideas about methods of improving the flow structure in gas turbine engine. On the basis of existing conditions (under development or existing engine) it allows the selection of the most suitable method for reducing gas flow nonuniformity.

Gas-Dynamic Methods to Reduce Gas Flow Nonuniformity from the Annular Frames of Gas Turbine Engines

NASA Astrophysics Data System (ADS)

Kolmakova, D.; Popov, G.

2018-01-01

Gas flow nonuniformity is one of the main sources of rotor blade vibrations in the gas turbine engines. Usually, the flow circumferential nonuniformity occurs near the annular frames, located in the flow channel of the engine. This leads to the increased dynamic stresses in blades and consequently to the blade damage. The goal of the research was to find an acceptable method of reducing the level of gas flow nonuniformity. Two different methods were investigated during this research. Thus, this study gives the ideas about methods of improving the flow structure in gas turbine engine. Based on existing conditions (under development or existing engine) it allows the selection of the most suitable method for reducing gas flow nonuniformity.

Apparatus for focusing flowing gas streams

DOEpatents

Nogar, N.S.; Keller, R.A.

1985-05-20

Apparatus for focusing gas streams. The principle of hydrodynamic focusing is applied to flowing gas streams in order to provide sample concentration for improved photon and sample utilization in resonance ionization mass spectrometric analysis. In a concentric nozzle system, gas samples introduced from the inner nozzle into the converging section of the outer nozzle are focused to streams 50-250-..mu..m in diameter. In some cases diameters of approximately 100-..mu..m are maintained over distances of several centimeters downstream from the exit orifice of the outer nozzle. The sheath gas employed has been observed to further provide a protective covering around the flowing gas sample, thereby isolating the flowing gas sample from possible unwanted reactions with nearby surfaces. A single nozzle variation of the apparatus for achieving hydrodynamic focusing of gas samples is also described.

Measurement of gas yields and flow rates using a custom flowmeter

USGS Publications Warehouse

Circone, S.; Kirby, S.H.; Pinkston, J.C.; Stern, L.A.

2001-01-01

A simple gas collection apparatus based on the principles of a Torricelli tube has been designed and built to measure gas volume yields and flow rates. This instrument is routinely used to monitor and collect methane gas released during methane hydrate dissociation experiments. It is easily and inexpensively built, operates at ambient pressures and temperatures, and measures gas volumes of up to 7 L to a precision of about 15 ml (about 0.0025 mol). It is capable of measuring gas flow rates varying from more than 103 to less than 10-1 ml/min during gas evolution events that span minutes to several days. We have obtained a highly reproducible hydrate number of n=5.891 with a propagated uncertainty of ??0.020 for synthetic methane hydrate. ?? 2001 American Institute of Physics.

Large-Flow-Area Flow-Selective Liquid/Gas Separator

NASA Technical Reports Server (NTRS)

Vasquez, Arturo; Bradley, Karla F.

2010-01-01

This liquid/gas separator provides the basis for a first stage of a fuel cell product water/oxygen gas phase separator. It can separate liquid and gas in bulk in multiple gravity environments. The system separates fuel cell product water entrained with circulating oxygen gas from the outlet of a fuel cell stack before allowing the gas to return to the fuel cell stack inlet. Additional makeup oxygen gas is added either before or after the separator to account for the gas consumed in the fuel cell power plant. A large volume is provided upstream of porous material in the separator to allow for the collection of water that does not exit the separator with the outgoing oxygen gas. The water then can be removed as it continues to collect, so that the accumulation of water does not impede the separating action of the device. The system is designed with a series of tubes of the porous material configured into a shell-and-tube heat exchanger configuration. The two-phase fluid stream to be separated enters the shell-side portion of the device. Gas flows to the center passages of the tubes through the porous material and is then routed to a common volume at the end of the tubes by simple pressure difference from a pumping device. Gas flows through the porous material of the tubes with greater ease as a function of the ratio of the dynamic viscosity of the water and gas. By careful selection of the dimensions of the tubes (wall thickness, porosity, diameter, length of the tubes, number of the tubes, and tube-to-tube spacing in the shell volume) a suitable design can be made to match the magnitude of water and gas flow, developed pressures from the oxygen reactant pumping device, and required residual water inventory for the shellside volume.

High gas flow alpha detector

DOEpatents

Bolton, Richard D.; Bounds, John A.; Rawool-Sullivan, Mohini W.

1996-01-01

An alpha detector for application in areas of high velocity gas flows, such as smokestacks and air vents. A plurality of spaced apart signal collectors are placed inside an enclosure, which would include smokestacks and air vents, in sufficient numbers to substantially span said enclosure so that gas ions generated within the gas flow are electrostatically captured by the signal collector means. Electrometer means and a voltage source are connected to the signal collectors to generate an electrical field between adjacent signal collectors, and to indicate a current produced through collection of the gas ions by the signal collectors.

High gas flow alpha detector

DOEpatents

Bolton, R.D.; Bounds, J.A.; Rawool-Sullivan, M.W.

1996-05-07

An alpha detector for application in areas of high velocity gas flows, such as smokestacks and air vents. A plurality of spaced apart signal collectors are placed inside an enclosure, which would include smokestacks and air vents, in sufficient numbers to substantially span said enclosure so that gas ions generated within the gas flow are electrostatically captured by the signal collector means. Electrometer means and a voltage source are connected to the signal collectors to generate an electrical field between adjacent signal collectors, and to indicate a current produced through collection of the gas ions by the signal collectors. 4 figs.

Methylation of 2-Naphthol Using Dimethyl Carbonate under Continuous-Flow Gas-Phase Conditions

ERIC Educational Resources Information Center

Tundo, Pietro; Rosamilia, Anthony E.; Arico, Fabio

2010-01-01

This experiment investigates the methylation of 2-naphthol with dimethyl carbonate. The volatility of the substrates, products, and co-products allows the reaction to be performed using a continuous-flow gas-phase setup at ambient pressure. The reaction uses catalytic quantities of base, achieves high conversion, produces little waste, and…

A Gas-Kinetic Scheme for Reactive Flows

NASA Technical Reports Server (NTRS)

Lian,Youg-Sheng; Xu, Kun

1998-01-01

In this paper, the gas-kinetic BGK scheme for the compressible flow equations is extended to chemical reactive flow. The mass fraction of the unburnt gas is implemented into the gas kinetic equation by assigning a new internal degree of freedom to the particle distribution function. The new variable can be also used to describe fluid trajectory for the nonreactive flows. Due to the gas-kinetic BGK model, the current scheme basically solves the Navier-Stokes chemical reactive flow equations. Numerical tests validate the accuracy and robustness of the current kinetic method.

Modeling of flowing gas diode pumped alkali lasers: dependence of the operation on the gas velocity and on the nature of the buffer gas.

PubMed

Barmashenko, B D; Rosenwaks, S

2012-09-01

A simple, semi-analytical model of flowing gas diode pumped alkali lasers (DPALs) is presented. The model takes into account the rise of temperature in the lasing medium with increasing pump power, resulting in decreasing pump absorption and slope efficiency. The model predicts the dependence of power on the flow velocity in flowing gas DPALs and checks the effect of using a buffer gas with high molar heat capacity and large relaxation rate constant between the 2P3/2 and 2P1/2 fine-structure levels of the alkali atom. It is found that the power strongly increases with flow velocity and that by replacing, e.g., ethane by propane as a buffer gas the power may be further increased by up to 30%. Eight kilowatt is achievable for 20 kW pump at flow velocity of 20  m/s.

Gas flow rate dependence of the discharge characteristics of a helium atmospheric pressure plasma jet interacting with a substrate

NASA Astrophysics Data System (ADS)

Yan, Wen; Economou, Demetre J.

2017-10-01

A 2D (axisymmetric) computational study of the discharge characteristics of an atmospheric pressure plasma jet as a function of gas flow rate was performed. The helium jet emerged from a dielectric tube, with an average gas flow velocity in the range 2.5-20 m s-1 (1 atm, 300 K) in a nitrogen ambient, and impinged on a substrate a short distance dowstream. The effect of the substrate conductivity (conductror versus insulator) was also studied. Whenever possible, simulation predictions were compared with published experimental observations. Discharge ignition and propagation in the dielectric tube were hardly affected by the He gas flow velocity. Most properties of the plasma jet, however, depended sensitively on the He gas flow velocity, which determined the concentration distributions of helium and nitrogen in the mixing layer forming in the gap between the tube exit and the substrate. At low gas flow velocity, the plasma jet evolved from a hollow (donut-shaped) feature to one where the maximum of electron density was on axis. When the gas flow velocity was high, the plasma jet maintained its hollow structure until it struck the substrate. For a conductive substrate, the radial ion fluxes to the surface were relatively uniform over a radius of ~0.4-0.8 mm, and the dominant ion flux was that of He+. For a dielectric substrate, the radial ion fluxes to the surface peaked on the symmetry axis at low He gas flow velocity, but a hollow ion flux distribution was observed at high gas flow velocity. At the same time, the main ion flux switched from N2+ to He2+ as the He gas flow velocity increased from a low to a high value. The diameter of the plasma ‘footprint’ on the substrate first increased with increasing He gas flow velocity, and eventually saturated with further increases in velocity.

Diffusion Monte Carlo simulations of gas phase and adsorbed D2-(H2)n clusters

NASA Astrophysics Data System (ADS)

Curotto, E.; Mella, M.

2018-03-01

We have computed ground state energies and analyzed radial distributions for several gas phase and adsorbed D2(H2)n and HD(H2)n clusters. An external model potential designed to mimic ionic adsorption sites inside porous materials is used [M. Mella and E. Curotto, J. Phys. Chem. A 121, 5005 (2017)]. The isotopic substitution lowers the ground state energies by the expected amount based on the mass differences when these are compared with the energies of the pure clusters in the gas phase. A similar impact is found for adsorbed aggregates. The dissociation energy of D2 from the adsorbed clusters is always much higher than that of H2 from both pure and doped aggregates. Radial distributions of D2 and H2 are compared for both the gas phase and adsorbed species. For the gas phase clusters, two types of hydrogen-hydrogen interactions are considered: one based on the assumption that rotations and translations are adiabatically decoupled and the other based on nonisotropic four-dimensional potential. In the gas phase clusters of sufficiently large size, we find the heavier isotopomer more likely to be near the center of mass. However, there is a considerable overlap among the radial distributions of the two species. For the adsorbed clusters, we invariably find the heavy isotope located closer to the attractive interaction source than H2, and at the periphery of the aggregate, H2 molecules being substantially excluded from the interaction with the source. This finding rationalizes the dissociation energy results. For D2-(H2)n clusters with n ≥12 , such preference leads to the desorption of D2 from the aggregate, a phenomenon driven by the minimization of the total energy that can be obtained by reducing the confinement of (H2)12. The same happens for (H2)13, indicating that such an effect may be quite general and impact on the absorption of quantum species inside porous materials.

Epitaxial growth of GaN by radical-enhanced metalorganic chemical vapor deposition (REMOCVD) in the downflow of a very high frequency (VHF) N2/H2 excited plasma - effect of TMG flow rate and VHF power

NASA Astrophysics Data System (ADS)

Lu, Yi; Kondo, Hiroki; Ishikawa, Kenji; Oda, Osamu; Takeda, Keigo; Sekine, Makoto; Amano, Hiroshi; Hori, Masaru

2014-04-01

Gallium nitride (GaN) films have been grown by using our newly developed Radical-Enhanced Metalorganic Chemical Vapor Deposition (REMOCVD) system. This system has three features: (1) application of very high frequency (60 MHz) power in order to increase the plasma density, (2) introduction of H2 gas together with N2 gas in the plasma discharge region to generate not only nitrogen radicals but also active NHx molecules, and (3) radical supply under remote plasma arrangement with suppression of charged ions and photons by employing a Faraday cage. Using this new system, we have studied the effect of the trimethylgallium (TMG) source flow rate and of the plasma generation power on the GaN crystal quality by using scanning electron microscopy (SEM) and double crystal X-ray diffraction (XRD). We found that this REMOCVD allowed the growth of epitaxial GaN films of the wurtzite structure of (0001) orientation on sapphire substrates with a high growth rate of 0.42 μm/h at a low temperature of 800 °C. The present REMOCVD is a promising method for GaN growth at relatively low temperature and without using costly ammonia gas.

N loss to drain flow and N2O emissions from a corn-soybean rotation with winter rye.

PubMed

Gillette, K; Malone, R W; Kaspar, T C; Ma, L; Parkin, T B; Jaynes, D B; Fang, Q X; Hatfield, J L; Feyereisen, G W; Kersebaum, K C

2018-03-15

Anthropogenic perturbation of the global nitrogen cycle and its effects on the environment such as hypoxia in coastal regions and increased N 2 O emissions is of increasing, multi-disciplinary, worldwide concern, and agricultural production is a major contributor. Only limited studies, however, have simultaneously investigated NO 3 - losses to subsurface drain flow and N 2 O emissions under corn-soybean production. We used the Root Zone Water Quality Model (RZWQM) to evaluate NO 3 - losses to drain flow and N 2 O emissions in a corn-soybean system with a winter rye cover crop (CC) in central Iowa over a nine year period. The observed and simulated average drain flow N concentration reductions from CC were 60% and 54% compared to the no cover crop system (NCC). Average annual April through October cumulative observed and simulated N 2 O emissions (2004-2010) were 6.7 and 6.0kgN 2 O-Nha -1 yr -1 for NCC, and 6.2 and 7.2kgNha -1 for CC. In contrast to previous research, monthly N 2 O emissions were generally greatest when N loss to leaching were greatest, mostly because relatively high rainfall occurred during the months fertilizer was applied. N 2 O emission factors of 0.032 and 0.041 were estimated for NCC and CC using the tested model, which are similar to field results in the region. A local sensitivity analysis suggests that lower soil field capacity affects RZWQM simulations, which includes increased drain flow nitrate concentrations, increased N mineralization, and reduced soil water content. The results suggest that 1) RZWQM is a promising tool to estimate N 2 O emissions from subsurface drained corn-soybean rotations and to estimate the relative effects of a winter rye cover crop over a nine year period on nitrate loss to drain flow and 2) soil field capacity is an important parameter to model N mineralization and N loss to drain flow. Published by Elsevier B.V.

Gas flows in S-E binary systems of galaxies

NASA Technical Reports Server (NTRS)

Sotnikova, N. YA.

1990-01-01

Tidal interaction between the galaxies in binary systems leads to important consequences. Some peculiarities in galactic morphology as well as the transfer of matter from one galaxy to another may be due to this factor. In particular, gas flows in intergalactic space may be formed. Such flows enriching one component with gas from the other may play a substantial role in the evolution of mixed (S-E) pairs. One can mention several facts corroborating the possibility of the gas transfer from the spiral to the elliptical galaxy. High HI content (10(exp 7) to 10(exp 9) solar mass) is detected in nearly 40 E galaxies (Bottinelli and Gougenheim, 1979; Knapp et al., 1985). Such galaxies are often members of pairs or of multiple systems including an S galaxy, which may be the source of gas (Smirnov and Komberg, 1980). Moreover, the gas kinematics and its distribution also indicate an external origin for this gas (Knapp et al., 1985). In many cases there is an outer gaseous disk. The directions of the disk and of stellar rotation don't always coincide (van Gorkom et al., 1985; Varnas et al., 1987). The galaxy colors in S-E pairs are correlated (the Holmberg effect): bluer ellipticals have spiral components that are usually bluer (Demin et al., 1984). The fraction of E galaxies with emission lines (N sub em) in S-E pairs showing traces of tidal interaction is twice as large (N sub em approx. equals 0.24) as in pairs without interaction (N sub em approx. equals 0.12) (Sotnikova, 1988b). Since the presence of emission lines in a galaxy spectrum strongly depends on gas content, this fact also leads to the conclusion that ellipticals in interacting S-E pairs are enriched with gas. These facts may be considered as a serious indication of the existence of gas transfer. Hence, investigation of this process is of interest.

A low temperature investigation of the gas-phase N(2D) + NO reaction. Towards a viable source of N(2D) atoms for kinetic studies in astrochemistry.

PubMed

Nuñez-Reyes, Dianailys; Hickson, Kevin M

2018-06-18

The gas-phase reaction of metastable atomic nitrogen N(2D) with nitric oxide has been investigated over the 296-50 K temperature range using a supersonic flow reactor. As N(2D) could not be produced photolytically in the present work, these excited state atoms were generated instead through the C(3P) + NO → N(2D) + CO reaction while C(3P) atoms were created in situ by the 266 nm pulsed laser photolysis of CBr4 precursor molecules. The kinetics of N(2D) atoms were followed on-resonance by vacuum ultraviolet laser induced fluorescence at 116.7 nm. The measured rate constants for the N(2D) + NO reaction are in excellent agreement with most of the earlier work at room temperature and represent the only available kinetic data for this process below 296 K. The rate constants are seen to increase slightly as the temperature falls to 100 K with a more substantial increase at even lower temperature; a finding which is not reproduced by theoretical work. The prospects for using this chemical source of N(2D) atoms in future studies of a wide range of N(2D) atom reactions are discussed.

Distribution of E/N and N/e/ in a cross-flow electric discharge laser. [electric field to neutral gas density and electron number density

NASA Technical Reports Server (NTRS)

Dunning, J. W., Jr.; Lancashire, R. B.; Manista, E. J.

1976-01-01

Measurements have been conducted of the effect of the convection of ions and electrons on the discharge characteristics in a large scale laser. The results are presented for one particular distribution of ballast resistance. Values of electric field, current density, input power density, ratio of electric field to neutral gas density (E/N), and electron number density were calculated on the basis of measurements of the discharge properties. In a number of graphs, the E/N ratio, current density, power density, and electron density are plotted as a function of row number (downstream position) with total discharge current and gas velocity as parameters. From the dependence of the current distribution on the total current, it appears that the electron production in the first two rows significantly affects the current flowing in the succeeding rows.

Modeling of heavy-gas effects on airfoil flows

NASA Technical Reports Server (NTRS)

Drela, Mark

1992-01-01

Thermodynamic models were constructed for a calorically imperfect gas and for a non-ideal gas. These were incorporated into a quasi one dimensional flow solver to develop an understanding of the differences in flow behavior between the new models and the perfect gas model. The models were also incorporated into a two dimensional flow solver to investigate their effects on transonic airfoil flows. Specifically, the calculations simulated airfoil testing in a proposed high Reynolds number heavy gas test facility. The results indicate that the non-idealities caused significant differences in the flow field, but that matching of an appropriate non-dimensional parameter led to flows similar to those in air.

Slip length measurement of gas flow.

PubMed

Maali, Abdelhamid; Colin, Stéphane; Bhushan, Bharat

2016-09-16

In this paper, we present a review of the most important techniques used to measure the slip length of gas flow on isothermal surfaces. First, we present the famous Millikan experiment and then the rotating cylinder and spinning rotor gauge methods. Then, we describe the gas flow rate experiment, which is the most widely used technique to probe a confined gas and measure the slip. Finally, we present a promising technique using an atomic force microscope introduced recently to study the behavior of nanoscale confined gas.

Ethylene Trace-gas Techniques for High-speed Flows

NASA Technical Reports Server (NTRS)

Davis, David O.; Reichert, Bruce A.

1994-01-01

Three applications of the ethylene trace-gas technique to high-speed flows are described: flow-field tracking, air-to-air mixing, and bleed mass-flow measurement. The technique involves injecting a non-reacting gas (ethylene) into the flow field and measuring the concentration distribution in a downstream plane. From the distributions, information about flow development, mixing, and mass-flow rates can be dtermined. The trace-gas apparatus and special considerations for use in high-speed flow are discussed. A description of each application, including uncertainty estimates is followed by a demonstrative example.

Effects of gas flow on oxidation reaction in liquid induced by He/O{sub 2} plasma-jet irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nakajima, Atsushi; Uchida, Giichiro, E-mail: uchida@jwri.osaka-u.ac.jp; Takenaka, Kosuke

We present here analysis of oxidation reaction in liquid by a plasma-jet irradiation under various gas flow patterns such as laminar and turbulence flows. To estimate the total amount of oxidation reaction induced by reactive oxygen species (ROS) in liquid, we employ a KI-starch solution system, where the absorbance of the KI-starch solution near 600 nm behaves linear to the total amount of oxidation reaction in liquid. The laminar flow with higher gas velocity induces an increase in the ROS distribution area on the liquid surface, which results in a large amount of oxidation reaction in liquid. However, a much fastermore » gas flow conversely results in a reduction in the total amount of oxidation reaction in liquid under the following two conditions: first condition is that the turbulence flow is triggered in a gas flow channel at a high Reynolds number of gas flow, which leads to a marked change of the spatial distribution of the ROS concentration in gas phase. Second condition is that the dimpled liquid surface is formed by strong gas flow, which prevents the ROS from being transported in radial direction along the liquid surface.« less

Droplet breakup in accelerating gas flows. Part 2: Secondary atomization

NASA Technical Reports Server (NTRS)

Zajac, L. J.

1973-01-01

An experimental investigation to determine the effects of an accelerating gas flow on the atomization characteristics of liquid sprays was conducted. The sprays were produced by impinging two liquid jets. The liquid was molten wax and the gas was nitrogen. The use of molten wax allowed for a quantitative measure of the resulting dropsize distribution. The results of this study, indicate that a significant amount of droplet breakup will occur as a result of the action of the gas on the liquid droplets. Empirical correlations are presented in terms of parameters that were found to affect the mass median dropsize most significantly, the orifice diameter, the liquid injection velocity, and the maximum gas velocity. An empirical correlation for the normalized dropsize distribution is also presented. These correlations are in a form that may be incorporated readily into existing combustion model computer codes for the purpose of calculating rocket engine combustion performance.

Collisional Removal of OH (X (sup 2)Pi, nu=7) by O2, N2, CO2, and N2O

NASA Technical Reports Server (NTRS)

Knutsen, Karen; Dyer, Mark J.; Copeland, Richard A.

1996-01-01

Collisional removal rate constants for the OH (X 2PI, nu = 7) radical are measured for the colliders O2, CO2, and N2O, and an upper limit is established for N2. OH(nu = 4) molecules, generated in a microwave discharge flow cell by the reaction of hydrogen atoms with ozone, are excited to v = 7 by the output of a pulsed infrared laser via direct vibrational overtone excitation. The temporal evolution of the P = 7 population is probed as a function of the collider gas partial pressure by a time-delayed pulsed ultraviolet laser. Fluorescence from the B 21 + state is detected in the visible spectral region.

Influence of ammonia flow rate for improving properties of polycrystalline GaN

NASA Astrophysics Data System (ADS)

Ariff, A.; Ahmad, M. A.; Hassan, Z.; Zainal, N.

2018-06-01

Post-annealing treatment in ammonia ambient is widely accepted for GaN material, but less works have been done to investigate the influence of the ammonia (NH3) flow rate for reducing the N-deficiency as well as improving the quality of the material. In this work, we investigated the influence of NH3 flow rate at 1, 2, 3, and 4 slm in improving properties of a ∼1 μm thick polycrystalline GaN layer. Our simulation work suggested that the uniformity of temperature and pressure gradient of the NH3 gas did not lead to the reduction of N-deficiency of the polycrystalline GaN layer. Instead, it was found that the mitigation of the N-deficiency was strongly influenced by the fluid velocity of the NH3 gas, which had passed over the layer. Either at lower or higher fluid velocity, the chance for the active N atoms to incorporate into the GaN lattice structure was low. Therefore, the N-deficiency on the polycrystalline GaN layer could not be minimized under these conditions. As measured by EDX, the N atoms incorporation was the most effective when the NH3 flow rate at 3 slm, suggesting the flow rate significantly improved the N-deficiency of the polycrystalline GaN layer. Furthermore, it favored the formation of larger hexagonal faceted grains, with the smallest FWHM of XRD peaks from the GaN diffractions in (10 1 bar 0), (0002) and (10 1 bar 1) orientations, while allowing the polycrystalline GaN layer to show sharp and intense emissions peak of NBE in a PL spectrum.

40 CFR 89.416 - Raw exhaust gas flow.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw exhaust gas flow. 89.416 Section 89.416 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Procedures § 89.416 Raw exhaust gas flow. The exhaust gas flow shall be determined by one of the methods...

40 CFR 89.416 - Raw exhaust gas flow.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw exhaust gas flow. 89.416 Section 89.416 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Procedures § 89.416 Raw exhaust gas flow. The exhaust gas flow shall be determined by one of the methods...

Simple model for vibration-translation exchange at high temperatures: effects of multiquantum transitions on the relaxation of a N2 gas flow behind a shock.

PubMed

Aliat, A; Vedula, P; Josyula, E

2011-02-01

In this paper a simple model is proposed for computation of rate coefficients related to vibration-translation transitions based on the forced harmonic oscillator theory. This model, which is developed by considering a quadrature method, provides rate coefficients that are in very good agreement with those found in the literature for the high temperature regime (≳10,000 K). This model is implemented to study a one-dimensional nonequilibrium inviscid N(2) flow behind a plane shock by considering a state-to-state approach. While the effects of ionization and chemical reactions are neglected in our study, our results show that multiquantum transitions have a great influence on the relaxation of the macroscopic parameters of the gas flow behind the shock, especially on vibrational distributions of high levels. All vibrational states are influenced by multiquantum processes, but the effective number of transitions decreases inversely according to the vibrational quantum number. For the initial conditions considered in this study, excited electronic states are found to be weakly populated and can be neglected in modeling. Moreover, the computing time is considerably reduced with the model described in this paper compared to others found in the literature. ©2011 American Physical Society

Simultaneous improvement of waste gas purification and nitrogen removal using a novel aerated vertical flow constructed wetland.

PubMed

Zhang, Xinwen; Hu, Zhen; Ngo, Huu Hao; Zhang, Jian; Guo, Wenshan; Liang, Shuang; Xie, Huijun

2018-03-01

Insufficient oxygen supply is identified as one of the major factors limiting organic pollutant and nitrogen (N) removal in constructed wetlands (CWs). This study designed a novel aerated vertical flow constructed wetland (VFCW) using waste gas from biological wastewater treatment systems to improve pollutant removal in CWs, its potential in purifying waste gas was also identified. Compared with unaerated VFCW, the introduction of waste gas significantly improved NH 4 + -N and TN removal efficiencies by 128.48 ± 3.13% and 59.09 ± 2.26%, respectively. Furthermore, the waste gas ingredients, including H 2 S, NH 3 , greenhouse gas (N 2 O) and microbial aerosols, were remarkably reduced after passing through the VFCW. The removal efficiencies of H 2 S, NH 3 and N 2 O were 77.78 ± 3.46%, 52.17 ± 2.53%, and 87.40 ± 3.89%, respectively. In addition, the bacterial and fungal aerosols in waste gas were effectively removed with removal efficiencies of 42.72 ± 3.21% and 47.89 ± 2.82%, respectively. Microbial analysis results revealed that the high microbial community abundance in the VFCW, caused by the introduction of waste gas from the sequencing batch reactor (SBR), led to its optimized nitrogen transformation processes. These results suggested that the VFCW intermittently aerated with waste gas may have potential application for purifying wastewater treatment plant effluent and waste gas, simultaneously. Copyright © 2017 Elsevier Ltd. All rights reserved.

The ideal oxygen/nitrous oxide fresh gas flow sequence with the Anesthesia Delivery Unit machine.

PubMed

Hendrickx, Jan F A; Cardinael, Sara; Carette, Rik; Lemmens, Hendrikus J M; De Wolf, Andre M

2007-06-01

To determine whether early reduction of oxygen and nitrous oxide fresh gas flow from 6 L/min to 0.7 L/min could be accomplished while maintaining end-expired nitrous oxide concentration > or =50% with an Anesthesia Delivery Unit anesthesia machine. Prospective, randomized clinical study. Large teaching hospital in Belgium. 53 ASA physical status I and II patients requiring general endotracheal anesthesia and controlled mechanical ventilation. Patients were randomly assigned to one of 4 groups depending on the duration of high oxygen/nitrous oxide fresh gas flow (two and 4 L/min, respectively) before lowering total fresh gas flow to 0.7 L/min (0.3 and 0.4 L/min oxygen and nitrous oxide, respectively): one, two, three, or 5 minutes (1-minute group, 2-minute group, 3-minute group, and 5-minute group), with n = 10, 12, 13, and 8, respectively. The course of the end-expired nitrous oxide concentration and bellows volume deficit at end-expiration was compared among the 4 groups during the first 30 minutes. At the end of the high-flow period the end-expired nitrous oxide concentration was 35.6 +/- 6.2%, 48.4 +/- 4.8%, 53.7 +/- 8.7%, and 57.3 +/- 1.6% in the 4 groups, respectively. Thereafter, the end-expired nitrous oxide concentration decreased to a nadir of 36.1 +/- 4.5%, 45.4 +/- 3.8%, 50.9 +/- 6.1%, and 55.4 +/- 2.8% after three, 4, 6, and 8 minutes after flows were lowered in the 1- to 5-minute groups, respectively. A decrease in bellows volume was observed in most patients, but was most pronounced in the 2-minute group. The bellows volume deficit gradually faded within 15 to 20 minutes in all 4 groups. A 3-minute high-flow period (oxygen and nitrous oxide fresh gas flow of 2 and 4 L/min, respectively) suffices to attain and maintain end-expired nitrous oxide concentration > or =50% and ensures an adequate bellows volume during the ensuing low-flow period.

An evaluation of 2 new devices for nasal high-flow gas therapy.

PubMed

Waugh, Jonathan B; Granger, Wesley M

2004-08-01

The traditional nasal cannula with bubble humidifier is limited to a maximum flow of 6 L/min to minimize the risk of complications. We conducted a bench study of 2 new Food and Drug Administration-approved nasal cannula/humidifier products designed to deliver at flows> 6 L/min. Using a digital psychrometer we measured the relative humidity and temperature of delivered gas from each device, at 5 L/min increments over the specified functional high-flow range. The Salter Labs unit achieved 72.5-78.7% relative humidity (5-15 L/min range) at ambient temperature (21-23 degrees C). The Vapotherm device achieved 99.9% relative humidity at a temperature setting of 37 degrees C (5-40 L/min). Both devices meet minimum humidification standards and offer practical new treatment options. The patient-selection criteria are primarily the severity of the patient's condition and cost.

TiN films fabricated by reactive gas pulse sputtering: A hybrid design of multilayered and compositionally graded structures

NASA Astrophysics Data System (ADS)

Yang, Jijun; Zhang, Feifei; Wan, Qiang; Lu, Chenyang; Peng, Mingjing; Liao, Jiali; Yang, Yuanyou; Wang, Lumin; Liu, Ning

2016-12-01

Reactive gas pulse (RGP) sputtering approach was used to prepare TiN thin films through periodically changing the N2/Ar gas flow ratio. The obtained RGPsbnd TiN film possessed a hybrid architecture containing compositionally graded and multilayered structures, composed of hcp Ti-phase and fcc TiN-phase sublayers. Meanwhile, the RGP-TiN film exhibited a composition-oscillation along the film thickness direction, where the Ti-phase sublayer had a compositional gradient and the TiN-phase retained a constant stoichiometric ratio of Ti:N ≈ 1. The film modulation ratio λ (the thicknesses ratio of the Ti and TiN-phase sublayer) can be effectively tuned by controlling the undulation behavior of the N2 partial flow rate. Detailed analysis showed that this hybrid structure originated from a periodic transition of the film growth mode during the reactive sputtering process.

Fundamental Insulation Characteristics of Air, N2, CO2, N2/O2 and SF6/N2 Mixed Gases

NASA Astrophysics Data System (ADS)

Rokunohe, Toshiaki; Yagihashi, Yoshitaka; Endo, Fumihiro; Oomori, Takashi

SF6 gas has excellent dielectric strength and interruption performance. For these reasons, it has been widely used for gas insulated switchgear (GIS). However, use of SF6 gas has become regulated under agreements set at the 1997 COP3. Presently, development of a gas circuit breaker (GCB) using CO2 gas and development of a high voltage vacuum circuit breaker (VCB) are being pursued. GIS consists of disconnectors (DS), earthing switches (ES) and buses in addition to GCB. Since the interruption performance is not an important requirement for DS, ES and BUS, use of a gas with high dielectric strength is better than use of a gas with good interruption performance. Air and N2 are not greenhouse gases, and their dielectric strengths are higher than those of other SF6 alternative gases, but only about one-third of the dielectric strength of SF6 gas. This paper deals with a suitable insulation gas which has no greenhouse effect as an SF6 alternative gas. The N2/O2 mixed gas was investigated by changing the ratio of O2. Moreover, the effect of an insulation coating was investigated and compared with the dielectric strength of SF6/N2 mixed gas. The dielectric strength of air under the coating condition was equal to that of 10%SF6/N2 mixed gas.

A novel aerated surface flow constructed wetland using exhaust gas from biological wastewater treatment: Performance and mechanisms.

PubMed

Zhang, Xinwen; Hu, Zhen; Zhang, Jian; Fan, Jinlin; Ngo, Huu Hao; Guo, Wenshan; Zeng, Chujun; Wu, Yiwen; Wang, Siyuan

2018-02-01

In this study, a novel aerated surface flow constructed wetland (SFCW) using exhaust gas from biological wastewater treatment was investigated. Compared with un-aerated SFCW, the introduction of exhaust gas into SFCW significantly improved NH 4 + -N, TN and COD removal efficiencies by 68.30 ± 2.06%, 24.92 ± 1.13% and 73.92 ± 2.36%, respectively. The pollutants removal mechanism was related to the microbial abundance and the highest microbial abundance was observed in the SFCW with exhaust gas because of the introduction of exhaust gas from sequencing batch reactor (SBR), and thereby optimizing nitrogen transformation processes. Moreover, SFCW would significantly mitigate the risk of exhaust gas pollution. SFCW removed 20.00 ± 1.23%, 34.78 ± 1.39%, and 59.50 ± 2.33% of H 2 S, NH 3 and N 2 O in the exhaust gas, respectively. And 31.32 ± 2.23% and 32.02 ± 2.86% of bacterial and fungal aerosols in exhaust gas were also removed through passing SFCW, respectively. Copyright © 2017. Published by Elsevier Ltd.

Spark gap switch with spiral gas flow

DOEpatents

Brucker, John P.

1989-01-01

A spark gap switch having a contaminate removal system using an injected gas. An annular plate concentric with an electrode of the switch defines flow paths for the injected gas which form a strong spiral flow of the gas in the housing which is effective to remove contaminates from the switch surfaces. The gas along with the contaminates is exhausted from the housing through one of the ends of the switch.

Gas and Oil Flow through Wellbore Flaws

NASA Astrophysics Data System (ADS)

Hatambeigi, M.; Anwar, I.; Reda Taha, M.; Bettin, G.; Chojnicki, K. N.; Stormont, J.

2017-12-01

We have measured gas and oil flow through laboratory samples that represent two important potential flow paths in wellbores associated with the Strategic Petroleum Reserve (SPR): cement-steel interfaces (microannuli) and cement fractures. Cement fractures were created by tensile splitting of cement cores. Samples to represent microannuli were created by placing thin steel sheets within split cement cores so flow is channeled along the cement-steel interface. The test sequence included alternating gas and oil flow measurements. The test fluids were nitrogen and silicone oil with properties similar to a typical crude oil stored in the SPR. After correcting for non-linear (inertial) flow when necessary, flows were interpreted as effective permeability and hydraulic aperture using the cubic law. For both samples with cement fractures and those with cement-steel interfaces, initial gas and oil permeabilities were comparable. Once saturated with oil, a displacement pressure had to be overcome to establish gas flow through a sample, and the subsequent gas permeability were reduced by more than 50% compared to its initial value. Keywords: wellbore integrity, leakage, fracture, microannulus, SPR. Sandia National Laboratories is a multi-mission laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of NTESS/Honeywell, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2017-8168 A

Infrared photodissociation spectroscopy of M(N2)n(+) (M = Y, La, Ce; n = 7-8) in the gas phase.

PubMed

Xie, Hua; Shi, Lei; Xing, Xiaopeng; Tang, Zichao

2016-02-14

M(N2)n(+) (M = Y, La, Ce; n = 7-8) complexes have been studied by infrared photodissociation (IRPD) spectroscopy and density functional theory (DFT) calculations. The experimental results indicate that the N-N stretching vibrational frequencies are red-shifted from the gas-phase N2 value. The π back-donation is found to be a main contributor in these systems. IRPD spectra and DFT calculations reveal the coexistence of two isomers in the seven-coordinate M(N2)7(+) and eight-coordinate M(N2)8(+) complexes, respectively. The present studies on these metal-nitrogen complexes shed light on the interactions and coordinations toward N2 with transition and lanthanide metals.

Growth of a Massive Young Stellar Object Fed by a Gas Flow from a Companion Gas Clump

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Xi; Shen, Zhiqiang; Ren, Zhiyuan

We present a Submillimeter Array (SMA) observation toward the young massive double-core system G350.69-0.49. This system consists of a northeast (NE) diffuse gas bubble and a southwest (SW) massive young stellar object (MYSO), both clearly seen in the Spitzer images. The SMA observations reveal a gas flow between the NE bubble and the SW MYSO in a broad velocity range from 5 to 30 km s{sup −1} with respect to the system velocity. The gas flow is well confined within the interval between the two objects and traces a significant mass transfer from the NE gas bubble to the SWmore » massive core. The transfer flow can supply the material accreted onto the SW MYSO at a rate of 4.2×10{sup −4} M{sub ⊙} yr{sup −1}. The whole system therefore suggests a mode for the mass growth in the MYSO from a gas transfer flow launched from its companion gas clump, despite the driving mechanism of the transfer flow not being fully determined from the current data.« less

Statistic characteristics of the gas-liquid flow in a vertical minichannel

NASA Astrophysics Data System (ADS)

Kozulin, I. A.; Kuznetsov, V. V.

2010-03-01

The gas-liquid upward flow was studied in a rectangular minichannel of 1.75×3.8 mm and length of 0.7 m. The experiments were carried out within the range of the gas superficial velocity from 0.1 to 10 m/s and the liquid superficial velocity from 0.07 to 0.7 m/s for the co-current H2O/CO2 flow under the conditions of saturation. The method for the two-beam laser scanning of structure and determination of statistic characteristics of the two-phase flow was worked through. The slug-bubble, slug, transitional, churn, and annular flows were distinguished. The statistics characteristics of liquid and gas phases motion in a minichannel were obtained for the first time including the velocities of phase motion.

The flow dynamics of an extremely large volume pyroclastic flow, the 2.08-Ma Cerro Galán Ignimbrite, NW Argentina, and comparison with other flow types

USGS Publications Warehouse

Cas, Ray A.F.; Wright, Heather M.; Folkes, Christopher B.; Lesti, Chiara; Porreca, Massimiliano; Giordano, Guido; Viramonte, Jose G.

2011-01-01

The 2.08-Ma Cerro Galán Ignimbrite (CGI) represents a >630-km3 dense rock equivalent (VEI 8) eruption from the long-lived Cerro Galán magma system (∼6 Ma). It is a crystal-rich (35–60%), pumice (<10% generally) and lithic-poor (<5% generally) rhyodacitic ignimbrite, lacking a preceding plinian fallout deposit. The CGI is preserved up to 80 km from the structural margins of the caldera, but almost certainly was deposited up to 100 km from the caldera in some places. Only one emplacement unit is preserved in proximal to medial settings and in most distal settings, suggesting constant flow conditions, but where the pyroclastic flow moved into a palaeotopography of substantial valleys and ridges, it interacted with valley walls, resulting in flow instabilities that generated multiple depositional units, often separated by pyroclastic surge deposits. The CGI preserves a widespread sub-horizontal fabric, defined by aligned elongate pumice and lithic clasts, and minerals (e.g. biotite). A sub-horizontal anisotropy of magnetic susceptibility fabric is defined by minute magnetic minerals in all localities where it has been analysed. The CGI is poor in both vent-derived (‘accessory’) lithics and locally derived lithics from the ground surface (‘accidental’) lithics. Locally derived lithics are small (<20 cm) and were not transported far from source points. All data suggest that the pyroclastic flow system producing the CGI was characterised throughout by high sedimentation rates, resulting from high particle concentration and suppressed turbulence at the depositional boundary layer, despite being a low aspect ratio ignimbrite. Based on these features, we question whether high velocity and momentum are necessary to account for extensive flow mobility. It is proposed that the CGI was deposited by a pyroclastic flow system that developed a substantial, high particle concentration granular under-flow, which flowed with suppressed turbulence. High particle

Controlling Gas-Flow Mass Ratios

NASA Technical Reports Server (NTRS)

Morris, Brian G.

1990-01-01

Proposed system automatically controls proportions of gases flowing in supply lines. Conceived for control of oxidizer-to-fuel ratio in new gaseous-propellant rocket engines. Gas-flow control system measures temperatures and pressures at various points. From data, calculates control voltages for electronic pressure regulators for oxygen and hydrogen. System includes commercially available components. Applicable to control of mass ratios in such gaseous industrial processes as chemical-vapor depostion of semiconductor materials and in automotive engines operating on compressed natural gas.

Reactions of CH3SH and CH3SSCH3 with gas-phase hydrated radical anions (H2O)n(•-), CO2(•-)(H2O)n, and O2(•-)(H2O)n.

PubMed

Höckendorf, Robert F; Hao, Qiang; Sun, Zheng; Fox-Beyer, Brigitte S; Cao, Yali; Balaj, O Petru; Bondybey, Vladimir E; Siu, Chi-Kit; Beyer, Martin K

2012-04-19

The chemistry of (H(2)O)(n)(•-), CO(2)(•-)(H(2)O)(n), and O(2)(•-)(H(2)O)(n) with small sulfur-containing molecules was studied in the gas phase by Fourier transform ion cyclotron resonance mass spectrometry. With hydrated electrons and hydrated carbon dioxide radical anions, two reactions with relevance for biological radiation damage were observed, cleavage of the disulfide bond of CH(3)SSCH(3) and activation of the thiol group of CH(3)SH. No reactions were observed with CH(3)SCH(3). The hydrated superoxide radical anion, usually viewed as major source of oxidative stress, did not react with any of the compounds. Nanocalorimetry and quantum chemical calculations give a consistent picture of the reaction mechanism. The results indicate that the conversion of e(-) and CO(2)(•-) to O(2)(•-) deactivates highly reactive species and may actually reduce oxidative stress. For reactions of (H(2)O)(n)(•-) with CH(3)SH as well as CO(2)(•-)(H(2)O)(n) with CH(3)SSCH(3), the reaction products in the gas phase are different from those reported in the literature from pulse radiolysis studies. This observation is rationalized with the reduced cage effect in reactions of gas-phase clusters. © 2012 American Chemical Society

A program for calculating expansion-tube flow quantities for real-gas mixtures and comparison with experimental results

NASA Technical Reports Server (NTRS)

Miller, C. G., III

1972-01-01

A computer program written in FORTRAN 4 language is presented which determines expansion-tube flow quantities for real test gases CO2 N2, O2, Ar, He, and H2, or mixtures of these gases, in thermochemical equilibrium. The effects of dissociation and first and second ionization are included. Flow quantities behind the incident shock into the quiescent test gas are determined from the pressure and temperature of the quiescent test gas in conjunction with: (1) incident-shock velocity, (2) static pressure immediately behind the incident shock, or (3) pressure and temperature of the driver gas (imperfect hydrogen or helium). The effect of the possible existence of a shock reflection at the secondary diaphragm of the expansion tube is included. Expansion-tube test-section flow conditions are obtained by performing an isentropic unsteady expansion from the conditions behind the incident shock or reflected shock to either the test-region velocity or the static pressure. Both a thermochemical-equilibrium expansion and a frozen expansion are included. Flow conditions immediately behind the bow shock of a model positioned at the test section are also determined. Results from the program are compared with preliminary experimental data obtained in the Langley 6-inch expansion tube.

Ignition and Combustion of Pulverized Coal and Biomass under Different Oxy-fuel O2/N2 and O2/CO2 Environments

NASA Astrophysics Data System (ADS)

Khatami Firoozabadi, Seyed Reza

This work studied the ignition and combustion of burning pulverized coals and biomasses particles under either conventional combustion in air or oxy-fuel combustion conditions. Oxy-fuel combustion is a 'clean-coal' process that takes place in O2/CO2 environments, which are achieved by removing nitrogen from the intake gases and recirculating large amounts of flue gases to the boiler. Removal of nitrogen from the combustion gases generates a high CO2-content, sequestration-ready gas at the boiler effluent. Flue gas recirculation moderates the high temperatures caused by the elevated oxygen partial pressure in the boiler. In this study, combustion of the fuels took place in a laboratory laminar-flow drop-tube furnace (DTF), electrically-heated to 1400 K, in environments containing various mole fractions of oxygen in either nitrogen or carbon-dioxide background gases. The experiments were conducted at two different gas conditions inside the furnace: (a) quiescent gas condition (i.e., no flow or inactive flow) and, (b) an active gas flow condition in both the injector and furnace. Eight coals from different ranks (anthracite, semi-snthracite, three bituminous, subbituminous and two lignites) and four biomasses from different sources were utilized in this work to study the ignition and combustion characteristics of solid fuels in O2/N2 or O2/CO2 environments. The main objective is to study the effect of replacing background N2 with CO2, increasing O2 mole fraction and fuel type and rank on a number of qualitative and quantitative parameters such as ignition/combustion mode, ignition temperature, ignition delay time, combustion temperatures, burnout times and envelope flame soot volume fractions. Regarding ignition, in the quiescent gas condition, bituminous and sub-bituminous coal particles experienced homogeneous ignition in both O2/N 2 and O2/CO2 atmospheres, while in the active gas flow condition, heterogeneous ignition was evident in O2/CO 2. Anthracite, semi

Fluid simulation of species concentrations in capacitively coupled N2/Ar plasmas: Effect of gas proportion

NASA Astrophysics Data System (ADS)

Liang, Ying-Shuang; Liu, Gang-Hu; Xue, Chan; Liu, Yong-Xin; Wang, You-Nian

2017-05-01

A two-dimensional self-consistent fluid model and the experimental diagnostic are employed to investigate the dependencies of species concentrations on the gas proportion in the capacitive N2/Ar discharges operated at 60 MHz, 50 Pa, and 140 W. The results indicate that the N2/Ar proportion has a considerable impact on the species densities. As the N2 fraction increases, the electron density, as well as the Ar+ and Arm densities, decreases remarkably. On the contrary, the N2 + density is demonstrated to increase monotonically with the N2 fraction. Moreover, the N density is observed to increase significantly with the N2 fraction at the N2 fractions below 40%, beyond which it decreases slightly. The electrons are primarily generated via the electron impact ionization of the feed gases. The electron impact ionization of Ar essentially determines the Ar+ density. For the N2 + production, the charge transition process between the Ar+ ions and the feed gas N2 dominates at low N2 fraction, while the electron impact ionization of N2 plays the more important role at high N2 fraction. At any gas mixtures, more than 60% Arm atoms are generated through the radiative decay process from Ar(4p). The dissociation of the feed gas N2 by the excited Ar atoms and by the electrons is responsible for the N formation at low N2 fraction and high N2 fraction, respectively. To validate the simulation results, the floating double probe and the optical emission spectroscopy are employed to measure the total positive ion density and the emission intensity originating from Ar(4p) transitions, respectively. The results from the simulation show a qualitative agreement with that from the experiment, which indicates the reliable model.

Natural gas flow through critical nozzles

NASA Technical Reports Server (NTRS)

Johnson, R. C.

1969-01-01

Empirical method for calculating both the mass flow rate and upstream volume flow rate through critical flow nozzles is determined. Method requires knowledge of the composition of natural gas, and of the upstream pressure and temperature.

Gas transfer in a bubbly wake flow

NASA Astrophysics Data System (ADS)

Karn, A.; Gulliver, J. S.; Monson, G. M.; Ellis, C.; Arndt, R. E. A.; Hong, J.

2016-05-01

The present work reports simultaneous bubble size and gas transfer measurements in a bubbly wake flow of a hydrofoil, designed to be similar to a hydroturbine blade. Bubble size was measured by a shadow imaging technique and found to have a Sauter mean diameter of 0.9 mm for a reference case. A lower gas flow rate, greater liquid velocities, and a larger angle of attack all resulted in an increased number of small size bubbles and a reduced weighted mean bubble size. Bubble-water gas transfer is measured by the disturbed equilibrium technique. The gas transfer model of Azbel (1981) is utilized to characterize the liquid film coefficient for gas transfer, with one scaling coefficient to reflect the fact that characteristic turbulent velocity is replaced by cross-sectional mean velocity. The coefficient was found to stay constant at a particular hydrofoil configuration while it varied within a narrow range of 0.52-0.60 for different gas/water flow conditions.

Heterogeneous interaction of SiO2 with N2O5: aerosol flow tube and single particle optical levitation-Raman spectroscopy studies.

PubMed

Tang, M J; Camp, J C J; Rkiouak, L; McGregor, J; Watson, I M; Cox, R A; Kalberer, M; Ward, A D; Pope, F D

2014-09-25

Silica (SiO2) is an important mineral present in atmospheric mineral dust particles, and the heterogeneous reaction of N2O5 on atmospheric aerosol is one of the major pathways to remove nitrogen oxides from the atmosphere. The heterogeneous reaction of N2O5 with SiO2 has only been investigated by two studies previously, and the reported uptake coefficients differ by a factor of >10. In this work two complementary laboratory techniques were used to study the heterogeneous reaction of SiO2 particles with N2O5 at room temperature and at different relative humidities (RHs). The uptake coefficients of N2O5, γ(N2O5), were determined to be (7.2 ± 0.6) × 10(-3) (1σ) at 7% RH and (5.3 ± 0.8) × 10(-3) (1σ) at 40% RH for SiO2 particles, using the aerosol flow tube technique. We show that γ(N2O5) determined in this work can be reconciled with the two previous studies by accounting for the difference in geometric and BET derived aerosol surface areas. To probe the particle phase chemistry, individual micrometer sized SiO2 particles were optically levitated and exposed to a continuous flow of N2O5 at different RHs, and the composition of levitated particles was monitored online using Raman spectroscopy. This study represents the first investigation into the heterogeneous reactions of levitated individual SiO2 particles as a surrogate for mineral dust. Relative humidity was found to play a critical role: while no significant change of particle composition was observed by Raman spectroscopy during exposure to N2O5 at RH of <2%, increasing the RH led to the formation of nitrate species on the particle surface which could be completely removed after decreasing the RH back to <2%. This can be explained by the partitioning of HNO3 between the gas and adsorbed phases. The atmospheric implications of this work are discussed.

Annual Greenhouse Gas (CO2, CH4, and N2O) Fluxes Via Ebullition from a Temperate Emergent Wetland

NASA Astrophysics Data System (ADS)

Mcnicol, G.; Sturtevant, C. S.; Knox, S. H.; Baldocchi, D. D.; Silver, W. L.

2014-12-01

Quantifying wetland greenhouse gas exchange is necessary to evaluate their potential for mitigating climate change via carbon sequestration. However measuring greenhouse gas fluxes of carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) in wetlands is difficult due to high spatial and temporal variability, and multiple transport pathways of emission. Transport of biogenic soil gas via highly sporadic ebullition (bubbling) events is often ignored or quantified poorly in wetland greenhouse gas budgets, but can rapidly release large volumes of gas to the atmosphere. To quantify a robust annual ebullition flux we measured rates continuously for a year (2013-2014) using custom-built chambers deployed in a restored emergent wetland located in the Sacramento-San Joaquin Delta, CA. We combined ebullition flux rates with observations of gas concentrations to estimate annual ebullition emissions of CO2, CH4, and N2O and compare flux rates to whole-ecosystem exchange of CO2 and CH4 measured simultaneously by eddy covariance.Mean ebullition flux rates were 18.3 ± 5.6 L m-2 yr-1. Ebullition CH4 concentrations were very high and ranged from 23-76 % with a mean of 47 ± 2.9 %; CO2 concentrations were lower and ranged from 0.7-6.6 % with a mean of 2.8 ± 0.3 %; N2O concentrations were below atmospheric concentrations and ranged from 130-389 ppb(v) with a mean of 257 ± 13 ppb(v). We calculated well-constrained annual ebullition fluxes of: 6.2 ± 1.9 g CH4 m-2 yr-1, 1.0 ± 0.3 g CO2 m-2 yr-1 and 9.3 ± 2.8 mg N2O m-2 yr-1. Methane emissions via ebullition were very large, representing 15-25 % of total wetland CH4 emissions measured at this site, whereas ebullition released only relatively small quantities of CO2 and N2O. Our results demonstrate that large releases of CH4 via ebullition from open water surfaces can be a significant component of restored wetland greenhouse gas budgets.

Exhaust plume impingement of chemically reacting gas-particle flows

NASA Technical Reports Server (NTRS)

Smith, S. D.; Penny, M. M.; Greenwood, T. F.; Roberts, B. B.

1975-01-01

A series of computer codes has been developed to predict gas-particle flows and resulting impingement forces, moments and heating rates to surfaces immersed in the flow. The gas-particle flow solution is coupled via heat transfer and drag between the phases with chemical effects included in the gas phase. The flow solution and impingement calculations are discussed. Analytical results are compared with test data obtained to evaluate gas-particle effects on the Space Shuttle thermal protection system during the staging maneuver.

Flow-pattern identification and nonlinear dynamics of gas-liquid two-phase flow in complex networks.

PubMed

Gao, Zhongke; Jin, Ningde

2009-06-01

The identification of flow pattern is a basic and important issue in multiphase systems. Because of the complexity of phase interaction in gas-liquid two-phase flow, it is difficult to discern its flow pattern objectively. In this paper, we make a systematic study on the vertical upward gas-liquid two-phase flow using complex network. Three unique network construction methods are proposed to build three types of networks, i.e., flow pattern complex network (FPCN), fluid dynamic complex network (FDCN), and fluid structure complex network (FSCN). Through detecting the community structure of FPCN by the community-detection algorithm based on K -mean clustering, useful and interesting results are found which can be used for identifying five vertical upward gas-liquid two-phase flow patterns. To investigate the dynamic characteristics of gas-liquid two-phase flow, we construct 50 FDCNs under different flow conditions, and find that the power-law exponent and the network information entropy, which are sensitive to the flow pattern transition, can both characterize the nonlinear dynamics of gas-liquid two-phase flow. Furthermore, we construct FSCN and demonstrate how network statistic can be used to reveal the fluid structure of gas-liquid two-phase flow. In this paper, from a different perspective, we not only introduce complex network theory to the study of gas-liquid two-phase flow but also indicate that complex network may be a powerful tool for exploring nonlinear time series in practice.

Pt-decorated GaN nanowires with significant improvement in H2 gas-sensing performance at room temperature.

PubMed

Abdullah, Q N; Yam, F K; Hassan, Z; Bououdina, M

2015-12-15

Superior sensitivity towards H2 gas was successfully achieved with Pt-decorated GaN nanowires (NWs) gas sensor. GaN NWs were fabricated via chemical vapor deposition (CVD) route. Morphology (field emission scanning electron microscopy and transmission electron microscopy) and crystal structure (high resolution X-ray diffraction) characterizations of the as-synthesized nanostructures demonstrated the formation of GaN NWs having a wurtzite structure, zigzaged shape and an average diameter of 30-166nm. The Pt-decorated GaN NWs sensor shows a high response of 250-2650% upon exposure to H2 gas concentration from 7 to 1000ppm respectively at room temperature (RT), and then increases to about 650-4100% when increasing the operating temperature up to 75°C. The gas-sensing measurements indicated that the Pt-decorated GaN NWs based sensor exhibited efficient detection of H2 at low concentration with excellent sensitivity, repeatability, and free hysteresis phenomena over a period of time of 100min. The large surface-to-volume ratio of GaN NWs and the catalytic activity of Pt metal are the most influential factors leading to the enhancement of H2 gas-sensing performances through the improvement of the interaction between the target molecules (H2) and the sensing NWs surface. The attractive low-cost, low power consumption and high-performance of the resultant decorated GaN NWs gas sensor assure their uppermost potential for H2 gas sensor working at low operating temperature. Copyright © 2015 Elsevier Inc. All rights reserved.

Gas Flow Detection System

NASA Technical Reports Server (NTRS)

Moss, Thomas; Ihlefeld, Curtis; Slack, Barry

2010-01-01

This system provides a portable means to detect gas flow through a thin-walled tube without breaking into the tubing system. The flow detection system was specifically designed to detect flow through two parallel branches of a manifold with only one inlet and outlet, and is a means for verifying a space shuttle program requirement that saves time and reduces the risk of flight hardware damage compared to the current means of requirement verification. The prototype Purge Vent and Drain Window Cavity Conditioning System (PVD WCCS) Flow Detection System consists of a heater and a temperature-sensing thermistor attached to a piece of Velcro to be attached to each branch of a WCCS manifold for the duration of the requirement verification test. The heaters and thermistors are connected to a shielded cable and then to an electronics enclosure, which contains the power supplies, relays, and circuit board to provide power, signal conditioning, and control. The electronics enclosure is then connected to a commercial data acquisition box to provide analog to digital conversion as well as digital control. This data acquisition box is then connected to a commercial laptop running a custom application created using National Instruments LabVIEW. The operation of the PVD WCCS Flow Detection System consists of first attaching a heater/thermistor assembly to each of the two branches of one manifold while there is no flow through the manifold. Next, the software application running on the laptop is used to turn on the heaters and to monitor the manifold branch temperatures. When the system has reached thermal equilibrium, the software application s graphical user interface (GUI) will indicate that the branch temperatures are stable. The operator can then physically open the flow control valve to initiate the test flow of gaseous nitrogen (GN2) through the manifold. Next, the software user interface will be monitored for stable temperature indications when the system is again at

Electrical characterization of the flowing afterglow of N{sub 2} and N{sub 2}/O{sub 2} microwave plasmas at reduced pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Afonso Ferreira, J.; Stafford, L., E-mail: luc.stafford@umontreal.ca; Leonelli, R.

2014-04-28

A cylindrical Langmuir probe was used to analyze the spatial distribution of the number density of positive ions and electrons as well as the electron energy distribution function (EEDF) in the flowing afterglow of a 6 Torr N{sub 2} and N{sub 2}/O{sub 2} plasma sustained by a propagating electromagnetic surface wave in the microwave regime. In pure N{sub 2} discharges, ion densities were in the mid 10{sup 14} m{sup −3} in the pink afterglow and in the mid 10{sup 12} m{sup −3} early in the late afterglow. In both pink and late afterglows, the ion population was much higher than the electron population,more » indicating non-macroscopically neutral media. The EEDF was close to a Maxwellian with an electron temperature of 0.5 ± 0.1 eV, except in the pink afterglow where the temperature rose to 1.1 ± 0.2 eV. This latter behavior is ascribed to N{sub 2} vibration-vibration pumping in the pink afterglow that increases the concentration of high N{sub 2} vibrational states and thus rises the electron temperature by vibration-electron collisions. After addition of small amounts of O{sub 2} in the nominally pure N{sub 2} discharge, the charged particles densities and average electron energy first strongly increased and then decreased with increasing O{sub 2} concentration. Based on these data and the evolution of the N{sub 2}{sup +}(B) band emission intensities, it is concluded that a significant change in the positive ion composition of the flowing afterglow occurs, going from N{sub 2}{sup +} in nominally pure N{sub 2} discharges to NO{sup +} after addition of trace amounts of O{sub 2} in N{sub 2}.« less

Quantifying N2O reduction to N2 based on N2O isotopocules - validation with independent methods (helium incubation and 15N gas flux method)

NASA Astrophysics Data System (ADS)

Lewicka-Szczebak, Dominika; Augustin, Jürgen; Giesemann, Anette; Well, Reinhard

2017-02-01

Stable isotopic analyses of soil-emitted N2O (δ15Nbulk, δ18O and δ15Nsp = 15N site preference within the linear N2O molecule) may help to quantify N2O reduction to N2, an important but rarely quantified process in the soil nitrogen cycle. The N2O residual fraction (remaining unreduced N2O, rN2O) can be theoretically calculated from the measured isotopic enrichment of the residual N2O. However, various N2O-producing pathways may also influence the N2O isotopic signatures, and hence complicate the application of this isotopic fractionation approach. Here this approach was tested based on laboratory soil incubations with two different soil types, applying two reference methods for quantification of rN2O: helium incubation with direct measurement of N2 flux and the 15N gas flux method. This allowed a comparison of the measured rN2O values with the ones calculated based on isotopic enrichment of residual N2O. The results indicate that the performance of the N2O isotopic fractionation approach is related to the accompanying N2O and N2 source processes and the most critical is the determination of the initial isotopic signature of N2O before reduction (δ0). We show that δ0 can be well determined experimentally if stable in time and then successfully applied for determination of rN2O based on δ15Nsp values. Much more problematic to deal with are temporal changes of δ0 values leading to failure of the approach based on δ15Nsp values only. For this case, we propose here a dual N2O isotopocule mapping approach, where calculations are based on the relation between δ18O and δ15Nsp values. This allows for the simultaneous estimation of the N2O-producing pathways' contribution and the rN2O value.

Relaxation of heavy species and gas temperature in the afterglow of a N2 microwave discharge

NASA Astrophysics Data System (ADS)

Pintassilgo, Carlos D.; Guerra, Vasco

2017-10-01

In this paper we present a self-consistent kinetic model to study the temporal variation of the gas temperature in the afterglow of a 440 Pa microwave nitrogen discharge operating at 433 MHz in a 3.8 cm diameter tube. The initial conditions in the afterglow are determined by a kinetic model that solves the electron Boltzmann equation coupled to the gas thermal balance equation and a system of rate-balance equations for N2(X 1∑g+, v) molecules, electronically excited states of N2, ground and excited states of atomic nitrogen and the main positive ions. Once the initial concentrations of the heavy species and gas temperature are known, their relaxation in the afterglow is obtained from the solutions to the corresponding time-dependent equations. Modelling predictions are found to be in good agreement with previously measured values for the concentrations of N(4S) atoms and N2(A 3∑u+) molecules, and the radially averaged gas temperature Tg along the afterglow of a microwave discharge in N2 under the same working conditions. It is shown that gas heating in the afterglow comes essentially from the energy transfer involving non-resonant vibration-vibration (V-V) collisions between vibrationally excited nitrogen molecules, as well as from energy exchanges in vibration-translation (V-T) on N2-N collisions. Contribution to the topical issue "Plasma Sources and Plasma Processes (PSPP)", edited by Luis Lemos Alves, Thierry Belmonte and Tiberiu Minea

Long-term flow monitoring of submarine gas emanations

NASA Astrophysics Data System (ADS)

Spickenbom, K.; Faber, E.; Poggenburg, J.; Seeger, C.

2009-04-01

One of the Carbon Capture and Storage (CCS) strategies currently under study is the sequestration of CO2 in sub-seabed geological formations. Even after a thorough review of the geological setting, there is the possibility of leaks from the reservoirs. As part of the EU-financed project CO2ReMoVe (Research, Monitoring, Verification), which aims to develop innovative research and technologies for monitoring and verification of carbon dioxide geological storage, we are working on the development of submarine long-term gas flow monitoring systems. Technically, however, these systems are not limited to CO2 but can be used for monitoring of any free gas emission (bubbles) on the seafloor. The basic design of the gas flow sensor system was derived from former prototypes developed for monitoring CO2 and CH4 on mud volcanoes in Azerbaijan. This design was composed of a raft floating on the surface above the gas vent to collect the bubbles. Sensors for CO2 flux and concentration and electronics for data storage and transmission were mounted on the raft, together with battery-buffered solar panels for power supply. The system was modified for installation in open sea by using a buoy instead of a raft and a funnel on the seafloor to collect the gas, which is then guided above water level through a flexible tube. Besides some technical problems (condensed water in the tube, movement of the buoys due to waves leading to biased measurement of flow rates), this setup provides a cost-effective solution for shallow waters. However, a buoy interferes with ship traffic, and it is also difficult to adapt this design to greater water depths. These requirements can best be complied by a completely submersed system. To allow unattended long-term monitoring in a submarine environment, such a system has to be extremely durable. Therefore, we focussed on developing a mechanically and electrically as simple setup as possible, which has the additional advantage of low cost. The system

Multiscale Computational Analysis of Nitrogen and Oxygen Gas-Phase Thermochemistry in Hypersonic Flows

NASA Astrophysics Data System (ADS)

Bender, Jason D.

Understanding hypersonic aerodynamics is important for the design of next-generation aerospace vehicles for space exploration, national security, and other applications. Ground-level experimental studies of hypersonic flows are difficult and expensive; thus, computational science plays a crucial role in this field. Computational fluid dynamics (CFD) simulations of extremely high-speed flows require models of chemical and thermal nonequilibrium processes, such as dissociation of diatomic molecules and vibrational energy relaxation. Current models are outdated and inadequate for advanced applications. We describe a multiscale computational study of gas-phase thermochemical processes in hypersonic flows, starting at the atomic scale and building systematically up to the continuum scale. The project was part of a larger effort centered on collaborations between aerospace scientists and computational chemists. We discuss the construction of potential energy surfaces for the N4, N2O2, and O4 systems, focusing especially on the multi-dimensional fitting problem. A new local fitting method named L-IMLS-G2 is presented and compared with a global fitting method. Then, we describe the theory of the quasiclassical trajectory (QCT) approach for modeling molecular collisions. We explain how we implemented the approach in a new parallel code for high-performance computing platforms. Results from billions of QCT simulations of high-energy N2 + N2, N2 + N, and N2 + O2 collisions are reported and analyzed. Reaction rate constants are calculated and sets of reactive trajectories are characterized at both thermal equilibrium and nonequilibrium conditions. The data shed light on fundamental mechanisms of dissociation and exchange reactions -- and their coupling to internal energy transfer processes -- in thermal environments typical of hypersonic flows. We discuss how the outcomes of this investigation and other related studies lay a rigorous foundation for new macroscopic models for

Flowmeter for gas-entrained solids flow

DOEpatents

Porges, Karl G.

1990-01-01

An apparatus and method for the measurement of solids feedrate in a gas-entrained solids flow conveyance system. The apparatus and method of the present invention include a vertical duct connecting a source of solids to the gas-entrained flow conveyance system, a control valve positioned in the vertical duct, and a capacitive densitometer positioned along the duct at a location a known distance below the control valved so that the solid feedrate, Q, of the gas entrained flow can be determined by Q=S.rho..phi.V.sub.S where S is the cross sectional area of the duct, .rho. is the density of the solid, .phi. is the solid volume fraction determined by the capacitive densitometer, and v.sub.S is the local solid velocity which can be inferred from the konown distance of the capacitive densitometer below the control valve.

Greenhouse gas budget (CO2, CH4 and N2O) of intensively managed grassland following restoration.

PubMed

Merbold, Lutz; Eugster, Werner; Stieger, Jacqueline; Zahniser, Mark; Nelson, David; Buchmann, Nina

2014-06-01

The first full greenhouse gas (GHG) flux budget of an intensively managed grassland in Switzerland (Chamau) is presented. The three major trace gases, carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) were measured with the eddy covariance (EC) technique. For CO2 concentrations, an open-path infrared gas analyzer was used, while N2O and CH4 concentrations were measured with a recently developed continuous-wave quantum cascade laser absorption spectrometer (QCLAS). We investigated the magnitude of these trace gas emissions after grassland restoration, including ploughing, harrowing, sowing, and fertilization with inorganic and organic fertilizers in 2012. Large peaks of N2O fluxes (20-50 nmol m(-2) s(-1) compared with a <5 nmol m(-2) s(-1) background) were observed during thawing of the soil after the winter period and after mineral fertilizer application followed by re-sowing in the beginning of the summer season. Nitrous oxide (N2O) fluxes were controlled by nitrogen input, plant productivity, soil water content and temperature. Management activities led to increased variations of N2O fluxes up to 14 days after the management event as compared with background fluxes measured during periods without management (<5 nmol m(-2) s(-1)). Fluxes of CO2 remained small until full plant development in early summer 2012. In contrast, methane emissions showed only minor variations over time. The annual GHG flux budget was dominated by N2O (48% contribution) and CO2 emissions (44%). CH4 flux contribution to the annual budget was only minor (8%). We conclude that recently developed multi-species QCLAS in an EC system open new opportunities to determine the temporal variation of N2O and CH4 fluxes, which further allow to quantify annual emissions. With respect to grassland restoration, our study emphasizes the key role of N2O and CO2 losses after ploughing, changing a permanent grassland from a carbon sink to a significant carbon source. © 2014 John Wiley & Sons Ltd.

Industrial 30-kW CO2 laser with fast axial gas flow and rf excitation

NASA Astrophysics Data System (ADS)

Habich, Uwe; Loosen, Peter; Hertzler, Christoph; Wollermann-Windgasse, Reinhard

1996-03-01

A CO2 laser with fast axial gas flow was set up and operated with a maximum cw output power above 30 kW. The laser makes use of 8 rf-excited discharges which were optimized regarding to the gas-flow, to the discharge homogeneity and to the optical properties of the gain medium. Results of experimental investigation of these topics are described as well as performance characteristics of the laser system equipped with a stable and an unstable resonator, respectively. With an unstable resonator and an aerodynamic window for the extraction of the beam the laser system gives a beam quality which is close to the diffraction limit for this type of resonator. Disregarding the difficulties which are related to the definition and measurement of beam quality for unstable resonators, the beam quality could be described as M2 equals 3. Measured far field intensity profiles in the focal plane of a focusing optics are presented as well as the beam propagation behavior near focus. First results of applications in materials processing are discussed.

Characteristics of surface-wave plasma with air-simulated N2 O2 gas mixture for low-temperature sterilization

NASA Astrophysics Data System (ADS)

Xu, L.; Nonaka, H.; Zhou, H. Y.; Ogino, A.; Nagata, T.; Koide, Y.; Nanko, S.; Kurawaki, I.; Nagatsu, M.

2007-02-01

Sterilization experiments using low-pressure air discharge plasma sustained by the 2.45 GHz surface-wave have been carried out. Geobacillus stearothermoplilus spores having a population of 3.0 × 106 were sterilized for only 3 min using air-simulated N2-O2 mixture gas discharge plasma, faster than the cases of pure O2 or pure N2 discharge plasmas. From the SEM analysis of plasma-irradiated spores and optical emission spectroscopy measurements of the plasmas, it has been found that the possible sterilization mechanisms of air-simulated plasma are the chemical etching effect due to the oxygen radicals and UV emission from the N2 molecules and NO radicals in the wavelength range 200-400 nm. Experiment suggested that UV emission in the wavelength range less than 200 nm might not be significant in the sterilization. The UV intensity at 237.0 nm originated from the NO γ system (A 2Σ+ → X 2Π) in N2-O2 plasma as a function of the O2 percentage added to N2-O2 mixture gas has been investigated. It achieved its maximum value when the O2 percentage was roughly 10-20%. This result suggests that air can be used as a discharge gas for sterilization, and indeed we have confirmed a rapid sterilization with the actual air discharge at a sample temperature of less than 65 °C.

Estimation of Flow Channel Parameters for Flowing Gas Mixed with Air in Atmospheric-pressure Plasma Jets

NASA Astrophysics Data System (ADS)

Yambe, Kiyoyuki; Saito, Hidetoshi

2017-12-01

When the working gas of an atmospheric-pressure non-equilibrium (cold) plasma flows into free space, the diameter of the resulting flow channel changes continuously. The shape of the channel is observed through the light emitted by the working gas of the atmospheric-pressure plasma. When the plasma jet forms a conical shape, the diameter of the cylindrical shape, which approximates the conical shape, defines the diameter of the flow channel. When the working gas flows into the atmosphere from the inside of a quartz tube, the gas mixes with air. The molar ratio of the working gas and air is estimated from the corresponding volume ratio through the relationship between the diameter of the cylindrical plasma channel and the inner diameter of the quartz tube. The Reynolds number is calculated from the kinematic viscosity of the mixed gas and the molar ratio. The gas flow rates for the upper limit of laminar flow and the lower limit of turbulent flow are determined by the corresponding Reynolds numbers estimated from the molar ratio. It is confirmed that the plasma jet length and the internal plasma length associated with strong light emission increase with the increasing gas flow rate until the rate for the upper limit of laminar flow and the lower limit of turbulent flow, respectively. Thus, we are able to explain the increasing trend in the plasma lengths with the diameter of the flow channel and the molar ratio by using the cylindrical approximation.

Integrated CO2 capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow

PubMed Central

Vishwakarma, Niraj K.; Singh, Ajay K.; Hwang, Yoon-Ho; Ko, Dong-Hyeon; Kim, Jin-Oh; Babu, A. Giridhar; Kim, Dong-Pyo

2017-01-01

Simultaneous capture of carbon dioxide (CO2) and its utilization with subsequent work-up would significantly enhance the competitiveness of CO2-based sustainable chemistry over petroleum-based chemistry. Here we report an interfacial catalytic reaction platform for an integrated autonomous process of simultaneously capturing/fixing CO2 in gas–liquid laminar flow with subsequently providing a work-up step. The continuous-flow microreactor has built-in silicon nanowires (SiNWs) with immobilized ionic liquid catalysts on tips of cone-shaped nanowire bundles. Because of the superamphiphobic SiNWs, a stable gas–liquid interface maintains between liquid flow of organoamines in upper part and gas flow of CO2 in bottom part of channel. The intimate and direct contact of the binary reagents leads to enhanced mass transfer and facilitating reactions. The autonomous integrated platform produces and isolates 2-oxazolidinones and quinazolines-2,4(1H,3H)-diones with 81–97% yields under mild conditions. The platform would enable direct CO2 utilization to produce high-valued specialty chemicals from flue gases without pre-separation and work-up steps. PMID:28262667

Malignant human cell transformation of Marcellus Shale gas drilling flow back water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yao, Yixin; Department of Environmental Medicine, New York University School of Medicine, Tuxedo, NY 10987; Chen, Tingting

The rapid development of high-volume horizontal hydraulic fracturing for mining natural gas from shale has posed potential impacts on human health and biodiversity. The produced flow back waters after hydraulic stimulation are known to carry high levels of saline and total dissolved solids. To understand the toxicity and potential carcinogenic effects of these wastewaters, flow back waters from five Marcellus hydraulic fracturing oil and gas wells were analyzed. The physicochemical nature of these samples was analyzed by inductively coupled plasma mass spectrometry and scanning electron microscopy/energy dispersive X-ray spectroscopy. A cytotoxicity study using colony formation as the endpoint was carriedmore » out to define the LC{sub 50} values of test samples using human bronchial epithelial cells (BEAS-2B). The BEAS-2B cell transformation assay was employed to assess the carcinogenic potential of the samples. Barium and strontium were among the most abundant metals in these samples and the same metals were found to be elevated in BEAS-2B cells after long-term treatment. BEAS-2B cells treated for 6 weeks with flow back waters produced colony formation in soft agar that was concentration dependent. In addition, flow back water-transformed BEAS-2B cells show better migration capability when compared to control cells. This study provides information needed to assess the potential health impact of post-hydraulic fracturing flow back waters from Marcellus Shale natural gas mining. - Highlights: • This is the first report of potential cytotoxicity and transforming activity of Marcellus shale gas mining flow back to mammalian cells. • Barium and Strontium were elevated in flow back water exposed cells. • Flow back water malignantly transformed cells and formed tumor in athymic nude mice. • Flow back transformed cells exhibited altered transcriptome with dysregulated cell migration pathway and adherent junction pathway.« less

PREFACE: 1st European Conference on Gas Micro Flows (GasMems 2012)

NASA Astrophysics Data System (ADS)

Frijns, Arjan; Valougeorgis, Dimitris; Colin, Stéphane; Baldas, Lucien

2012-05-01

The aim of the 1st European Conference on Gas Micro Flows is to advance research in Europe and worldwide in the field of gas micro flows as well as to improve global fundamental knowledge and to enable technological applications. Gas flows in microsystems are of great importance and touch almost every industrial field (e.g. fluidic microactuators for active control of aerodynamic flows, vacuum generators for extracting biological samples, mass flow and temperature micro-sensors, pressure gauges, micro heat-exchangers for the cooling of electronic components or for chemical applications, and micro gas analyzers or separators). The main characteristic of gas microflows is their rarefaction, which for device design often requires modelling and simulation both by continuous and molecular approaches. In such flows various non-equilibrium transport phenomena appear, while the role played by the interaction between the gas and the solid device surfaces becomes essential. The proposed models of boundary conditions often need an empirical adjustment strongly dependent on the micro manufacturing technique. The 1st European Conference on Gas Micro Flows is organized under the umbrella of the recently established GASMEMS network (www.gasmems.eu/) consisting of 13 participants and six associate members. The main objectives of the network are to structure research and train researchers in the fields of micro gas dynamics, measurement techniques for gaseous flows in micro experimental setups, microstructure design and micro manufacturing with applications in lab and industry. The conference takes place on June 6-8 2012, at the Skiathos Palace Hotel, on the beautiful island of Skiathos, Greece. The conference has received funding from the European Community's Seventh Framework Programme FP7/2007-2013 under grant agreement ITN GASMEMS no. 215504. It owes its success to many people. We would like to acknowledge the support of all members of the Scientific Committee and of all

Determination of respiratory gas flow by electrical impedance tomography in an animal model of mechanical ventilation

PubMed Central

2014-01-01

Background A recent method determines regional gas flow of the lung by electrical impedance tomography (EIT). The aim of this study is to show the applicability of this method in a porcine model of mechanical ventilation in healthy and diseased lungs. Our primary hypothesis is that global gas flow measured by EIT can be correlated with spirometry. Our secondary hypothesis is that regional analysis of respiratory gas flow delivers physiologically meaningful results. Methods In two sets of experiments n = 7 healthy pigs and n = 6 pigs before and after induction of lavage lung injury were investigated. EIT of the lung and spirometry were registered synchronously during ongoing mechanical ventilation. In-vivo aeration of the lung was analysed in four regions-of-interest (ROI) by EIT: 1) global, 2) ventral (non-dependent), 3) middle and 4) dorsal (dependent) ROI. Respiratory gas flow was calculated by the first derivative of the regional aeration curve. Four phases of the respiratory cycle were discriminated. They delivered peak and late inspiratory and expiratory gas flow (PIF, LIF, PEF, LEF) characterizing early or late inspiration or expiration. Results Linear regression analysis of EIT and spirometry in healthy pigs revealed a very good correlation measuring peak flow and a good correlation detecting late flow. PIFEIT = 0.702 · PIFspiro + 117.4, r2 = 0.809; PEFEIT = 0.690 · PEFspiro-124.2, r2 = 0.760; LIFEIT = 0.909 · LIFspiro + 27.32, r2 = 0.572 and LEFEIT = 0.858 · LEFspiro-10.94, r2 = 0.647. EIT derived absolute gas flow was generally smaller than data from spirometry. Regional gas flow was distributed heterogeneously during different phases of the respiratory cycle. But, the regional distribution of gas flow stayed stable during different ventilator settings. Moderate lung injury changed the regional pattern of gas flow. Conclusions We conclude that the presented method is able to determine

N2 and CO2 capillary breakthrough experiments on Opalinus Clay

NASA Astrophysics Data System (ADS)

Amann, Alexandra; Busch, Andreas; Krooss, Bernhard M.

2013-04-01

The aim of this project was to identify the critical capillary pressures on the drainage and the imbibition path for clay-rich rocks, at a burial depth of 1500 m (30 MPa confining pressure, 45°C). The experiments were performed on fully water-saturated sample plugs of 38 mm diameter and 5 to 20 mm length. The capillary breakthrough pressure was determined by step-wise increase of the differential pressure (drainage), the capillary snap-off pressure was determined from the final pressure difference at the end of a spontaneous imbibition phase. The confining pressure was kept constant throughout the experiment, which resulted in a continuous change of effective stress. The measurements were performed in a closed system and the pressure response was interpreted in terms of different flow mechanisms (diffusion-controlled vs. viscous flow). In total, four breakthrough experiments with N2 and five experiments with CO2 were conducted. Because of very low flow rates and high critical capillary pressures the experiments took rather long. In some cases the experiments were allowed to run for half a year (drainage experiments). Substantial differences were observed between gas breakthrough (drainage) and snap-off (imbibition) pressures. As expected, breakthrough pressures were always higher than the snap-off pressures. For three samples a pbreakthrough/psnap-off ratio of 1.6 to 1.9 was observed, for one sample a ratio of 4. A clear permeability-capillary pressure relationship could not be identified. Based on (omnidirectional) Hg-injection porosimetry results, and assuming perfectly water wet mineral surfaces, gas breakthrough pressures were predicted to occur at approximately 16 MPa for N2 and 5.7 MPa for CO2. The gas breakthrough experiments, however, produced different results. Even though a relatively homogeneous sample set was chosen, with permeability coefficients ranging between 1E-21 and 6E-21 m², the critical capillary breakthrough pressures for nitrogen ranged

Role of rough surface topography on gas slip flow in microchannels.

PubMed

Zhang, Chengbin; Chen, Yongping; Deng, Zilong; Shi, Mingheng

2012-07-01

We conduct a lattice Boltzmann simulation of gas slip flow in microchannels incorporating rough surface effects as characterized by fractal geometry with a focus on gas-solid interaction. The gas slip flow in rough microchannels, which is characterized by Poiseuille number and mass flow rate, is evaluated and compared with smooth microchannels. The effects of roughness height, surface fractal dimension, and Knudsen number on slip behavior of gas flow in microchannels are all investigated and discussed. The results indicate that the presence of surface roughness reduces boundary slip for gas flow in microchannels with respect to a smooth surface. The gas flows at the valleys of rough walls are no-slip while velocity slips are observed over the top of rough walls. We find that the gas flow behavior in rough microchannels is insensitive to the surface topography irregularity (unlike the liquid flow in rough microchannels) but is influenced by the statistical height of rough surface and rarefaction effects. In particular, decrease in roughness height or increase in Knudsen number can lead to large wall slip for gas flow in microchannels.

Chemically Reacting One-Dimensional Gas-Particle Flows

NASA Technical Reports Server (NTRS)

Tevepaugh, J. A.; Penny, M. M.

1975-01-01

The governing equations for the one-dimensional flow of a gas-particle system are discussed. Gas-particle effects are coupled via the system momentum and energy equations with the gas assumed to be chemically frozen or in chemical equilibrium. A computer code for calculating the one-dimensional flow of a gas-particle system is discussed and a user's input guide presented. The computer code provides for the expansion of the gas-particle system from a specified starting velocity and nozzle inlet geometry. Though general in nature, the final output of the code is a startline for initiating the solution of a supersonic gas-particle system in rocket nozzles. The startline includes gasdynamic data defining gaseous startline points from the nozzle centerline to the nozzle wall and particle properties at points along the gaseous startline.

Micro/Nano-pore Network Analysis of Gas Flow in Shale Matrix

PubMed Central

Zhang, Pengwei; Hu, Liming; Meegoda, Jay N.; Gao, Shengyan

2015-01-01

The gas flow in shale matrix is of great research interests for optimized shale gas extraction. The gas flow in the nano-scale pore may fall in flow regimes such as viscous flow, slip flow and Knudsen diffusion. A 3-dimensional nano-scale pore network model was developed to simulate dynamic gas flow, and to describe the transient properties of flow regimes. The proposed pore network model accounts for the various size distributions and low connectivity of shale pores. The pore size, pore throat size and coordination number obey normal distribution, and the average values can be obtained from shale reservoir data. The gas flow regimes were simulated using an extracted pore network backbone. The numerical results show that apparent permeability is strongly dependent on pore pressure in the reservoir and pore throat size, which is overestimated by low-pressure laboratory tests. With the decrease of reservoir pressure, viscous flow is weakening, then slip flow and Knudsen diffusion are gradually becoming dominant flow regimes. The fingering phenomenon can be predicted by micro/nano-pore network for gas flow, which provides an effective way to capture heterogeneity of shale gas reservoir. PMID:26310236

Micro/Nano-pore Network Analysis of Gas Flow in Shale Matrix.

PubMed

Zhang, Pengwei; Hu, Liming; Meegoda, Jay N; Gao, Shengyan

2015-08-27

The gas flow in shale matrix is of great research interests for optimized shale gas extraction. The gas flow in the nano-scale pore may fall in flow regimes such as viscous flow, slip flow and Knudsen diffusion. A 3-dimensional nano-scale pore network model was developed to simulate dynamic gas flow, and to describe the transient properties of flow regimes. The proposed pore network model accounts for the various size distributions and low connectivity of shale pores. The pore size, pore throat size and coordination number obey normal distribution, and the average values can be obtained from shale reservoir data. The gas flow regimes were simulated using an extracted pore network backbone. The numerical results show that apparent permeability is strongly dependent on pore pressure in the reservoir and pore throat size, which is overestimated by low-pressure laboratory tests. With the decrease of reservoir pressure, viscous flow is weakening, then slip flow and Knudsen diffusion are gradually becoming dominant flow regimes. The fingering phenomenon can be predicted by micro/nano-pore network for gas flow, which provides an effective way to capture heterogeneity of shale gas reservoir.

Energy transfer model and its applications of ultrasonic gas flow-meter under static and dynamic flow rates

NASA Astrophysics Data System (ADS)

Fang, Min; Xu, Ke-Jun; Zhu, Wen-Jiao; Shen, Zi-Wen

2016-01-01

Most of the ultrasonic gas flow-meters measure the gas flow rate by calculating the ultrasonic transmission time difference between the downstream and upstream. Ultrasonic energy attenuation occurs in the processes of the ultrasonic generation, conversion, transmission, and reception. Additionally, at the same time, the gas flow will also affect the ultrasonic propagation during the measurement, which results in the ultrasonic energy attenuation and the offset of ultrasonic propagation path. Thus, the ultrasonic energy received by the transducer is weaker. When the gas flow rate increases, this effect becomes more apparent. It leads to the measurement accuracy reduced, and the measurement range narrowed. An energy transfer model, where the ultrasonic gas flow-meter under without/with the gas flow, is established by adopting the statistical analysis and curve fitting based on a large amount of experimental data. The static sub model without the gas flow expresses the energy conversion efficiency of ultrasonic gas transducers, and the dynamic sub model with the gas flow reflects the energy attenuation pattern following the flow rate variations. The mathematical model can be used to determine the minimum energy of the excitation signal for meeting the requirement of specific measurement range, and predict the maximum measurable flow rate in the case of fixed energy of excitation signal. Based on the above studies, a method to enhance the excitation signal energy is proposed under the output power of the transmitting circuit being a finite value so as to extend the measurement rage of ultrasonic gas flow-meter.

Simulation of gas flow in micro-porous media with the regularized lattice Boltzmann method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Junjian; Kang, Qinjun; Wang, Yuzhu

One primary challenge for prediction of gas flow in the unconventional gas reservoir at the pore-scale such as shale and tight gas reservoirs is the geometric complexity of the micro-porous media. In this paper, a regularized multiple-relaxation-time (MRT) lattice Boltzmann (LB) model is applied to analyze gas flow in 2-dimensional micro-porous medium reconstructed by quartet structure generation set (QSGS) on pore-scale. In this paper, the velocity distribution inside the porous structure is presented and analyzed, and the effects of the porosity and specific surface area on the rarefied gas flow and apparent permeability are examined and investigated. The simulation resultsmore » indicate that the gas exhibits different flow behaviours at various pressure conditions and the gas permeability is strongly related to the pressure. Finally, the increased porosity or the decreased specific surface area leads to the increase of the gas apparent permeability, and the gas flow is more sensitive to the pore morphological properties at low-pressure conditions.« less

Simulation of gas flow in micro-porous media with the regularized lattice Boltzmann method

DOE PAGES

Wang, Junjian; Kang, Qinjun; Wang, Yuzhu; ...

2017-06-01

One primary challenge for prediction of gas flow in the unconventional gas reservoir at the pore-scale such as shale and tight gas reservoirs is the geometric complexity of the micro-porous media. In this paper, a regularized multiple-relaxation-time (MRT) lattice Boltzmann (LB) model is applied to analyze gas flow in 2-dimensional micro-porous medium reconstructed by quartet structure generation set (QSGS) on pore-scale. In this paper, the velocity distribution inside the porous structure is presented and analyzed, and the effects of the porosity and specific surface area on the rarefied gas flow and apparent permeability are examined and investigated. The simulation resultsmore » indicate that the gas exhibits different flow behaviours at various pressure conditions and the gas permeability is strongly related to the pressure. Finally, the increased porosity or the decreased specific surface area leads to the increase of the gas apparent permeability, and the gas flow is more sensitive to the pore morphological properties at low-pressure conditions.« less

Generating Breathable Air Through Dissociation of N2O

NASA Technical Reports Server (NTRS)

Zubrin, Robert; Frankie, Brian

2006-01-01

A nitrous oxide-based oxygen-supply system (NOBOSS) is an apparatus in which a breathable mixture comprising 2/3 volume parts of N2 and 1/3 volume part of O2 is generated through dissociation of N2O. The NOBOSS concept can be adapted to a variety of applications in which there are requirements for relatively compact, lightweight systems to supply breathable air. These could include air-supply systems for firefighters, divers, astronauts, and workers who must be protected against biological and chemical hazards. A NOBOSS stands in contrast to compressed-gas and cryogenic air-supply systems. Compressed-gas systems necessarily include massive tanks that can hold only relatively small amounts of gases. Alternatively, gases can be stored compactly in greater quantities and at low pressures when they are liquefied, but then cryogenic equipment is needed to maintain them in liquid form. Overcoming the disadvantages of both compressed-gas and cryogenic systems, the NOBOSS exploits the fact that N2O can be stored in liquid form at room temperature and moderate pressure. The mass of N2O that can be stored in a tank of a given mass is about 20 times the mass of compressed air that can be stored in a tank of equal mass. In a NOBOSS, N2O is exothermically dissociated to N2 and O2 in a main catalytic reactor. In order to ensure the dissociation of N2O to the maximum possible extent, the temperature of the reactor must be kept above 400 C. At the same time, to minimize concentrations of nitrogen oxides (which are toxic), it is necessary to keep the reactor temperature at or below 540 C. To keep the temperature within the required range throughout the reactor and, in particular, to prevent the formation of hot spots that would be generated by local concentrations of the exothermic dissociation reaction, the N2O is introduced into the reactor through an injector tube that features carefully spaced holes to distribute the input flow of N2O widely throughout the reactor. A NOBOSS

Flow behaviour and transitions in surfactant-laden gas-liquid vertical flows

NASA Astrophysics Data System (ADS)

Zadrazil, Ivan; Chakraborty, Sourojeet; Matar, Omar; Markides, Christos

2016-11-01

The aim of this work is to elucidate the effect of surfactant additives on vertical gas-liquid counter-current pipe flows. Two experimental campaigns were undertaken, one with water and one with a light oil (Exxsol D80) as the liquid phase; in both cases air was used as the gaseous phase. Suitable surfactants were added to the liquid phase up to the critical micelle concentration (CMC); measurements in the absence of additives were also taken, for benchmarking. The experiments were performed in a 32-mm bore and 5-m long vertical pipe, over a range of superficial velocities (liquid: 1 to 7 m/s, gas: 1 to 44 m/s). High-speed axial- and side-view imaging was performed at different lengths along the pipe, together with pressure drop measurements. Flow regime maps were then obtained describing the observed flow behaviour and related phenomena, i.e., downwards/upwards annular flow, flooding, bridging, gas/liquid entrainment, oscillatory film flow, standing waves, climbing films, churn flow and dryout. Comparisons of the air-water and oil-water results will be presented and discussed, along with the role of the surfactants in affecting overall and detailed flow behaviour and transitions; in particular, a possible mechanism underlying the phenomenon of flooding will be presented. EPSRC UK Programme Grant EP/K003976/1.

Study of DC Circuit Breaker of H2-N2 Mixture Gas for High Voltage

NASA Astrophysics Data System (ADS)

Shiba, Yuji; Morishita, Yukinaga; Kaneko, Shuhei; Okabe, Shigemitsu; Mizoguchi, Hitoshi; Yanabu, Satoru

Global warming caused by CO2 etc. is a field where the concern is very high. Especially, automobile emissions are problem for it. Therefore, the hybrid car is widely development and used recently. Hybrid car used electric power and gasoline. So, the car reduces CO2. Hybrid car has engine and motor. To rotate the motor, hybrid car has battery. This battery is large capacity. Therefore, the relay should interrupt high DC current for the switch of the motor and the engine. So, hybrid car used hydrogen gas filling relay We studied interruption test for the research of a basic characteristic of hydrogen gas. DC current has not current zero point. So, it is necessary to make the current zero by high arc voltage and forcible current zero point. The loss coefficient and arc voltage of hydrogen is high. Therefore, we studied interruption test for used high arc voltage. We studied interruption test and dielectric breakdown test of air, pure Hydrogen, and Hydrogen- nitrogen mixture gas. As a result, we realized H2-N2(80%-20%) is the best gas.

A physical-based gas-surface interaction model for rarefied gas flow simulation

NASA Astrophysics Data System (ADS)

Liang, Tengfei; Li, Qi; Ye, Wenjing

2018-01-01

Empirical gas-surface interaction models, such as the Maxwell model and the Cercignani-Lampis model, are widely used as the boundary condition in rarefied gas flow simulations. The accuracy of these models in the prediction of macroscopic behavior of rarefied gas flows is less satisfactory in some cases especially the highly non-equilibrium ones. Molecular dynamics simulation can accurately resolve the gas-surface interaction process at atomic scale, and hence can predict accurate macroscopic behavior. They are however too computationally expensive to be applied in real problems. In this work, a statistical physical-based gas-surface interaction model, which complies with the basic relations of boundary condition, is developed based on the framework of the washboard model. In virtue of its physical basis, this new model is capable of capturing some important relations/trends for which the classic empirical models fail to model correctly. As such, the new model is much more accurate than the classic models, and in the meantime is more efficient than MD simulations. Therefore, it can serve as a more accurate and efficient boundary condition for rarefied gas flow simulations.

Dynamic Modeling Strategy for Flow Regime Transition in Gas-Liquid Two-Phase Flows

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xia Wang; Xiaodong Sun; Benjamin Doup

In modeling gas-liquid two-phase flows, the concept of flow regimes has been widely used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are flow regime dependent. Current nuclear reactor safety analysis codes, such as RELAP5, classify flow regimes using flow regime maps or transition criteria that were developed for steady-state, fully-developed flows. As twophase flows are dynamic in nature, it is important to model the flow regime transitions dynamically to more accurately predict the two-phase flows. The present workmore » aims to develop a dynamic modeling strategy to determine flow regimes in gas-liquid two-phase flows through introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation of the interfacial area, fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation, and the destruction of the interfacial area, fluid particle coalescence and condensation. For flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shapes, namely group-1 and group-2 bubbles. A preliminary approach to dynamically identify the flow regimes is discussed, in which discriminator s are based on the predicted information, such as the void fraction and interfacial area concentration. The flow regime predicted with this method shows good agreement with the experimental observations.« less

Isothermal gas-liquid flow at reduced gravity

NASA Technical Reports Server (NTRS)

Dukler, A. E.

1990-01-01

Research on adiabatic gas-liquid flows under reduced gravity condition is presented together with experimental data obtained using a NASA-Lewis RC 100-ft drop tower and in a LeRC Learjet. It is found that flow patterns and characteristics remain unchanged after the first 1.5 s into microgravity conditions and that the calculated time for a continuity wave to traverse the test section is less than 1.2 s. It is also found that the dispersed bubbles move at the same velocity as that of the front of the slug and that the transition between bubbly and slug flow is insensitive to diameter. Both the bubbly and the slug flows are suggested to represent a continuum of the same physical process. The characteristics of annular, slug, and bubbly flows are compared.

PIV Measurements of Gas Flow Fields from Burning End

NASA Astrophysics Data System (ADS)

Huang, Yifei; Wu, Junzhang; Zeng, Jingsong; Tang, Darong; Du, Liang

2017-12-01

To study the influence of cigarette gas on the environment, it is necessary to know the cigarette gas flow fields from burning end. By using PIV technique, in order to reveal velocity characteristics of gas flow fields, the velocities of cigarette gas flow fields was analyzed with different stepping motor frequencies corresponding to suction pressures, and the trend of velocity has been given with image fitting. The results shows that the velocities of the burning end increased with suction pressures; Between velocities of the burning end and suction pressures, the relations present polynomial rule; The cigarette gas diffusion in combustion process is faster than in the smoldering process.

Gas flow means for improving efficiency of exhaust hoods

DOEpatents

Gadgil, Ashok J.

1994-01-01

Apparatus for inhibiting the flow of contaminants in an exhaust enclosure toward an individual located adjacent an opening into the exhaust enclosure by providing a gas flow toward a source of contaminants from a position in front of an individual to urge said contaminants away from the individual toward a gas exit port. The apparatus comprises a gas mani-fold which may be worn by a person as a vest. The manifold has a series of gas outlets on a front face thereof facing away from the individual and toward the contaminants to thereby provide a flow of gas from the front of the individual toward the contaminants.

Gas flow means for improving efficiency of exhaust hoods

DOEpatents

Gadgil, A.J.

1994-01-11

Apparatus is described for inhibiting the flow of contaminants in an exhaust enclosure toward an individual located adjacent an opening into the exhaust enclosure by providing a gas flow toward a source of contaminants from a position in front of an individual to urge said contaminants away from the individual toward a gas exit port. The apparatus comprises a gas manifold which may be worn by a person as a vest. The manifold has a series of gas outlets on a front face thereof facing away from the individual and toward the contaminants to thereby provide a flow of gas from the front of the individual toward the contaminants. 15 figures.

The grapevine root-specific aquaporin VvPIP2;4N controls root hydraulic conductance and leaf gas exchange under well-watered conditions but not under water stress.

PubMed

Perrone, Irene; Gambino, Giorgio; Chitarra, Walter; Vitali, Marco; Pagliarani, Chiara; Riccomagno, Nadia; Balestrini, Raffaella; Kaldenhoff, Ralf; Uehlein, Norbert; Gribaudo, Ivana; Schubert, Andrea; Lovisolo, Claudio

2012-10-01

We functionally characterized the grape (Vitis vinifera) VvPIP2;4N (for Plasma membrane Intrinsic Protein) aquaporin gene. Expression of VvPIP2;4N in Xenopus laevis oocytes increased their swelling rate 54-fold. Northern blot and quantitative reverse transcription-polymerase chain reaction analyses showed that VvPIP2;4N is the most expressed PIP2 gene in root. In situ hybridization confirmed root localization in the cortical parenchyma and close to the endodermis. We then constitutively overexpressed VvPIP2;4N in grape 'Brachetto', and in the resulting transgenic plants we analyzed (1) the expression of endogenous and transgenic VvPIP2;4N and of four other aquaporins, (2) whole-plant, root, and leaf ecophysiological parameters, and (3) leaf abscisic acid content. Expression of transgenic VvPIP2;4N inhibited neither the expression of the endogenous gene nor that of other PIP aquaporins in both root and leaf. Under well-watered conditions, transgenic plants showed higher stomatal conductance, gas exchange, and shoot growth. The expression level of VvPIP2;4N (endogenous + transgene) was inversely correlated to root hydraulic resistance. The leaf component of total plant hydraulic resistance was low and unaffected by overexpression of VvPIP2;4N. Upon water stress, the overexpression of VvPIP2;4N induced a surge in leaf abscisic acid content and a decrease in stomatal conductance and leaf gas exchange. Our results show that aquaporin-mediated modifications of root hydraulics play a substantial role in the regulation of water flow in well-watered grapevine plants, while they have a minor role upon drought, probably because other signals, such as abscisic acid, take over the control of water flow.

High pressure gas flow, storage, and displacement in fractured rock—Experimental setup development and application

NASA Astrophysics Data System (ADS)

Hadi Mosleh, M.; Turner, M.; Sedighi, M.; Vardon, P. J.

2017-01-01

This paper presents the design, development, and application of a laboratory setup for the experimental investigations of gas flow and reactions in a fractured rock. The laboratory facility comprises (i) a high pressure manometric sorption apparatus, where equilibrium and kinetic phenomena of adsorption and desorption can be examined, (ii) a high pressure triaxial core flooding system where the chemical reactive transport properties or processes can be explored, and (iii) an ancillary system including pure and mixed gas supply and analysis units. Underground conditions, in terms of pore pressure, confining pressure, and temperature, can be replicated using the triaxial core flooding system developed for depths up to 2 km. Core flooding experiments can be conducted under a range of gas injection pressures up to 20 MPa and temperatures up to 338 K. Details of the design considerations and the specification for the critical measuring instruments are described. The newly developed laboratory facility has been applied to study the adsorption of N2, CH4, and CO2 relevant to applications in carbon sequestration in coal and enhanced coalbed methane recovery. Under a wide range of pressures, the flow of helium in a core sample was studied and the evolution of absolute permeability at different effective stress conditions has been investigated. A comprehensive set of high resolution data has been produced on anthracite coal samples from the South Wales coalfield, using the developed apparatus. The results of the applications provide improved insight into the high pressure flow and reaction of various gas species in the coal samples from the South Wales coalfield.

Schlieren flow visualization of helium atmospheric plasma jet and influence of the gas flow rate and applied voltage frequency

NASA Astrophysics Data System (ADS)

Borghei, S. M.; Vaziri, N.; Alibabaei, S.

2018-03-01

We used schlieren photography to visualize the influence of gas flow rates of 1, 2.5, 5, 10 L/min and of the applied voltage frequency on a helium atmospheric plasma jet induced at the nozzle of a capillary tube. The expansion of the gas in the surrounding medium (air) was analyzed in the two different modes – plasma on/plasma off. Changes in the above parameters affect the gas flow regime and the hydrodynamics of the jet.

Probe measures gas and liquid mass flux in high mass flow ratio two-phase flows

NASA Technical Reports Server (NTRS)

Burick, R. J.

1972-01-01

Deceleration probe constructed of two concentric tubes with separator inlet operates successfully in flow fields where ratio of droplet flow rate to gas flow rate ranges from 1.0 to 20, and eliminates problems of local flow field disturbances and flooding. Probe is effective tool for characterization of liquid droplet/gas spray fields.

Flow-switching device for comprehensive two-dimensional gas chromatography.

PubMed

Bueno, Pedro A; Seeley, John V

2004-02-20

A simple flow-switching device has been developed as a differential flow modulator for comprehensive two-dimensional gas chromatography (GC x GC). The device is assembled from tubing, four tee unions, and a solenoid valve. The solenoid valve is located outside the oven of the gas chromatograph and is not in the sample path. The modulation technique has no inherent temperature restrictions and passes 100% of the primary column effluent to the secondary column(s). Secondary peaks are produced with widths at half maximum less than 100 ms when operating in GC x 2GC mode with a 2.0 s modulation period. The efficacy of this approach is demonstrated through the analysis of a standard mixture of volatile organic compounds (VOCs) and diesel fuel.

Method and system for gas flow mitigation of molecular contamination of optics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delgado, Gildardo; Johnson, Terry; Arienti, Marco

A computer-implemented method for determining an optimized purge gas flow in a semi-conductor inspection metrology or lithography apparatus, comprising receiving a permissible contaminant mole fraction, a contaminant outgassing flow rate associated with a contaminant, a contaminant mass diffusivity, an outgassing surface length, a pressure, a temperature, a channel height, and a molecular weight of a purge gas, calculating a flow factor based on the permissible contaminant mole fraction, the contaminant outgassing flow rate, the channel height, and the outgassing surface length, comparing the flow factor to a predefined maximum flow factor value, calculating a minimum purge gas velocity and amore » purge gas mass flow rate from the flow factor, the contaminant mass diffusivity, the pressure, the temperature, and the molecular weight of the purge gas, and introducing the purge gas into the semi-conductor inspection metrology or lithography apparatus with the minimum purge gas velocity and the purge gas flow rate.« less

The Three-D Flow Structures of Gas and Liquid Generated by a Spreading Flame Over Liquid Fuel

NASA Technical Reports Server (NTRS)

Tashtoush, G.; Ito, A.; Konishi, T.; Narumi, A.; Saito, K.; Cremers, C. J.

1999-01-01

We developed a new experimental technique called: Combined laser sheet particle tracking (LSPT) and laser holographic interferometry (HI), which is capable of measuring the transient behavior of three dimensional structures of temperature and flow both in liquid and gas phases. We applied this technique to a pulsating flame spread over n-butanol. We found a twin vortex flow both on the liquid surface and deep in the liquid a few mm below the surface and a twin vortex flow in the gas phase. The first twin vortex flow at the liquid surface was observed previously by NASA Lewis researchers, while the last two observations are new. These observations revealed that the convective flow structure ahead of the flame leading edge is three dimensional in nature and the pulsating spread is controlled by the convective flow of both liquid and gas.

The Contamination of Commercial 15N2 Gas Stocks with 15N–Labeled Nitrate and Ammonium and Consequences for Nitrogen Fixation Measurements

PubMed Central

Dabundo, Richard; Lehmann, Moritz F.; Treibergs, Lija; Tobias, Craig R.; Altabet, Mark A.; Moisander, Pia H.; Granger, Julie

2014-01-01

We report on the contamination of commercial 15-nitrogen (15N) N2 gas stocks with 15N-enriched ammonium, nitrate and/or nitrite, and nitrous oxide. 15N2 gas is used to estimate N2 fixation rates from incubations of environmental samples by monitoring the incorporation of isotopically labeled 15N2 into organic matter. However, the microbial assimilation of bioavailable 15N-labeled N2 gas contaminants, nitrate, nitrite, and ammonium, is liable to lead to the inflation or false detection of N2 fixation rates. 15N2 gas procured from three major suppliers was analyzed for the presence of these 15N-contaminants. Substantial concentrations of 15N-contaminants were detected in four Sigma-Aldrich 15N2 lecture bottles from two discrete batch syntheses. Per mole of 15N2 gas, 34 to 1900 µmoles of 15N-ammonium, 1.8 to 420 µmoles of 15N-nitrate/nitrite, and ≥21 µmoles of 15N-nitrous oxide were detected. One 15N2 lecture bottle from Campro Scientific contained ≥11 µmoles of 15N-nitrous oxide per mole of 15N2 gas, and no detected 15N-nitrate/nitrite at the given experimental 15N2 tracer dilutions. Two Cambridge Isotopes lecture bottles from discrete batch syntheses contained ≥0.81 µmoles 15N-nitrous oxide per mole 15N2, and trace concentrations of 15N-ammonium and 15N-nitrate/nitrite. 15N2 gas equilibrated cultures of the green algae Dunaliella tertiolecta confirmed that the 15N-contaminants are assimilable. A finite-differencing model parameterized using oceanic field conditions typical of N2 fixation assays suggests that the degree of detected 15N-ammonium contamination could yield inferred N2 fixation rates ranging from undetectable, <0.01 nmoles N L−1 d−1, to 530 nmoles N L−1 d−1, contingent on experimental conditions. These rates are comparable to, or greater than, N2 fixation rates commonly detected in field assays. These results indicate that past reports of N2 fixation should be interpreted with caution, and demonstrate that the purity of commercial 15N2

The preparation of calcium superoxide in a flowing gas stream and fluidized bed

NASA Technical Reports Server (NTRS)

Wood, P. C.; Ballou, E. V.; Spitze, L. A.; Wydeven, T.

1980-01-01

Superoxides can be used as sources of chemically stored oxygen in emergency breathing apparatus. The work reported here describes the use of a low-pressure nitrogen gas sweep through the reactant bed, for temperature control and water vapor removal. For a given set of gas temperature, bed thickness, and reaction time values, the highest purity calcium superoxide, Ca(O2)2, was obtained at the highest space velocity of the nitrogen gas sweep. The purity of the product was further increased by flow conditions that resulted in the fluidization of the reactant bed. However, scale-up of the low-pressure fluidized bed process was limited to the formation of agglomerates of reactant particles, which hindered thermal control by the flowing gas stream. A radiofrequency flow discharge inside the reaction chamber prevented agglomeration, presumably by dissipation of the static charges on the fluidized particles.

Hot gas ingestion characteristics and flow visualization of a vectored thrust STOVL concept

NASA Technical Reports Server (NTRS)

Johns, Albert L.; Neiner, George H.; Bencic, Timothy J.; Flood, Joseph D.; Amuedo, Kurt C.; Strock, Thomas W.; Williams, Ben R.

1990-01-01

A 9.2 percent scale short takeoff and vertical landing (STOVL) hot gas ingestion model was designed and built by McDonnell Douglas Corporation (MCAIR) and tested in the NASA Lewis Research Center 9- by 15-Foot Low Speed Wind Tunnel (LSWT). Hot gas ingestion, the entrainment of heated engine exhaust into the inlet flow field, is a key development issue for advanced short takeoff and vertical landing aircraft. The Phase 1 test program, conducted by NASA Lewis and McDonnell Douglas Corporation, evaluated the hot ingestion phenomena and control techniques and Phase 2 test program which was conducted by NASA Lewis are both reported. The Phase 2 program was conducted at exhaust nozzles temperatures up to 1460 R and utilized a sheet laser system for flow visualization of the model flow field in and out of ground effects. Hot gas ingestion levels were measured for the several forward nozzle splay configurations and with flow control/lift improvement devices which reduced the hot gas ingestion. The model support system had four degrees of freedom, heated high pressure air for nozzle flow, and a suction system exhaust for inlet flow. The headwind (freestream) velocity for Phase 1 was varied from 8 to 90 kn, with primary data taken in the 8 to 23 kn headwind velocity range. Phase 2 headwind velocity varied from 10 to 23 kn. Results of both Phase 1 and 2 are presented. A description of the model, facility, a new model support system, and a sheet laser illumination system are also provided. Results are presented over a range of main landing gear height (model height) above the ground plane at a 10 kn headwind velocity. The results contain the compressor face pressure and temperature distortions, total pressure recovery, compressor face temperature rise, and the environmental effects of the hot gas. The environmental effects include the ground plane temperature and pressure distributions, model airframe heating, and the location of the ground flow separation. Results from the

Stripped interstellar gas in cluster cooling flows

NASA Technical Reports Server (NTRS)

Soker, Noam; Bregman, Joel N.; Sarazin, Craig L.

1991-01-01

It is suggested that nonlinear perturbations which lead to thermal instabilities in cooling flows might start as blobs of interstellar gas which are stipped out of cluster galaxies. Assuming that most of the gas produced by stellar mass loss in cluster galaxies is stripped from the galaxies, the total rate of such stripping is roughly 100 solar masses/yr, which is similar to the rates of cooling in cluster cooling flows. It is possible that a substantial portion of the cooling gas originates as blobs of interstellar gas stripped from galaxies. The magnetic fields within and outside of the low-entropy perturbations may help to maintain their identities by suppressing both thermal conduction and Kelvin-Helmholtz instabilities. These density fluctuations may disrupt the propagation of radio jets through the intracluster gas, which may be one mechanism for producing wideangle-tail radio galaxies.

Flow chemistry: intelligent processing of gas-liquid transformations using a tube-in-tube reactor.

PubMed

Brzozowski, Martin; O'Brien, Matthew; Ley, Steven V; Polyzos, Anastasios

2015-02-17

reactive gas in a given reaction mixture. We have developed a tube-in-tube reactor device consisting of a pair of concentric capillaries in which pressurized gas permeates through an inner Teflon AF-2400 tube and reacts with dissolved substrate within a liquid phase that flows within a second gas impermeable tube. This Account examines our efforts toward the development of a simple, unified methodology for the processing of gaseous reagents in flow by way of development of a tube-in-tube reactor device and applications to key C-C, C-N, and C-O bond forming and hydrogenation reactions. We further describe the application to multistep reactions using solid-supported reagents and extend the technology to processes utilizing multiple gas reagents. A key feature of our work is the development of computer-aided imaging techniques to allow automated in-line monitoring of gas concentration and stoichiometry in real time. We anticipate that this Account will illustrate the convenience and benefits of membrane tube-in-tube reactor technology to improve and concomitantly broaden the scope of gas/liquid/solid reactions in organic synthesis.

Viewing inside Pyroclastic Flows - Large-scale Experiments on hot pyroclast-gas mixture flows

NASA Astrophysics Data System (ADS)

Breard, E. C.; Lube, G.; Cronin, S. J.; Jones, J.

2014-12-01

Pyroclastic density currents are the largest threat from volcanoes. Direct observations of natural flows are persistently prevented because of their violence and remain limited to broad estimates of bulk flow behaviour. The Pyroclastic Flow Generator - a large-scale experimental facility to synthesize hot gas-particle mixture flows scaled to pyroclastic flows and surges - allows investigating the physical processes behind PDC behaviour in safety. The ability to simulate natural eruption conditions and to view and measure inside the hot flows allows deriving validation and calibration data sets for existing numerical models, and to improve the constitutive relationships necessary for their effective use as powerful tools in hazard assessment. We here report on a systematic series of large-scale experiments on up to 30 ms-1 fast, 2-4.5 m thick, 20-35 m long flows of natural pyroclastic material and gas. We will show high-speed movies and non-invasive sensor data that detail the internal structure of the analogue pyroclastic flows. The experimental PDCs are synthesized by the controlled 'eruption column collapse' of variably diluted suspensions into an instrumented channel. Experiments show four flow phases: mixture acceleration and dilution during free fall; impact and lateral blasting; PDC runout; and co-ignimbrite cloud formation. The fully turbulent flows reach Reynolds number up to 107 and depositional facies similar to natural deposits. In the PDC runout phase, the shear flows develop a four-partite structure from top to base: a fully turbulent, strongly density-stratified ash cloud with average particle concentrations <<1vol%; a transient, turbulent dense suspension region with particle concentrations between 1 and 10 vol%; a non-turbulent, aerated and highly mobile dense underflows with particle concentrations between 40 and 50 vol%; and a vertically aggrading bed of static material. We characterise these regions and the exchanges of energy and momentum

Partial wetting gas-liquid segmented flow microreactor.

PubMed

Kazemi Oskooei, S Ali; Sinton, David

2010-07-07

A microfluidic reactor strategy for reducing plug-to-plug transport in gas-liquid segmented flow microfluidic reactors is presented. The segmented flow is generated in a wetting portion of the chip that transitions downstream to a partially wetting reaction channel that serves to disconnect the liquid plugs. The resulting residence time distributions show little dependence on channel length, and over 60% narrowing in residence time distribution as compared to an otherwise similar reactor. This partial wetting strategy mitigates a central limitation (plug-to-plug dispersion) while preserving the many attractive features of gas-liquid segmented flow reactors.

Performance of different PEEP valves and helmet outlets at increasing gas flow rates: a bench top study.

PubMed

Isgrò, S; Zanella, A; Giani, M; Abd El Aziz El Sayed Deab, S; Pesenti, A; Patroniti, N

2012-10-01

Aim of the paper was to assess the performance of different expiratory valves and the resistance of helmet outlet ports at increasing gas flow rates. A gas flow-meter was connected to 10 different expiratory peep valves: 1 water-seal valve, 4 precalibrated fixed PEEP valves and 5 adjustable PEEP valves. Three new valves of each brand, set at different pressure levels (5-7.5-10-12.5-15 cmH(2)O, if available), were tested at increasing gas flow rates (from 30 to 150 L/min). We measured the pressure generated just before the valves. Three different helmets sealed on a mock head were connected at the inlet port with a gas flow-meter while the outlet was left clear. We measured the pressure generated inside the helmet (due to the flow-resistance of the outlet port) at increasing gas flow rates. Adjustable valves showed a variable degree flow-dependency (increasing difference between the measured and the expected pressure at increasing flow rates), while pre-calibrated valves revealed a flow-independent behavior. Water seal valve showed low degree flow-dependency. The pressures generated by the outlet port of the tested helmets ranged from 0.02 to 2.29 cmH(2)O at the highest gas flow rate. Adjustable PEEP valves are not suggested for continuous-flow CPAP systems as their flow-dependency can lead to pressures higher than expected. Precalibrated and water seal valves exhibit the best performance. Different helmet outlet ports do not significantly affect the pressure generated during helmet CPAP. In order to avoid iatrogenic complications gas flow and pressure delivered during helmet CPAP must always be monitored.

Renormalizability of the gradient flow in the 2D O(N) non-linear sigma model

NASA Astrophysics Data System (ADS)

Makino, Hiroki; Suzuki, Hiroshi

2015-03-01

It is known that the gauge field and its composite operators evolved by the Yang-Mills gradient flow are ultraviolet (UV) finite without any multiplicative wave function renormalization. In this paper, we prove that the gradient flow in the 2D O(N) non-linear sigma model possesses a similar property: The flowed N-vector field and its composite operators are UV finite without multiplicative wave function renormalization. Our proof in all orders of perturbation theory uses a (2+1)-dimensional field theoretical representation of the gradient flow, which possesses local gauge invariance without gauge field. As an application of the UV finiteness of the gradient flow, we construct the energy-momentum tensor in the lattice formulation of the O(N) non-linear sigma model that automatically restores the correct normalization and the conservation law in the continuum limit.

Numerical Computation of Flame Spread over a Thin Solid in Forced Concurrent Flow with Gas-phase Radiation

NASA Technical Reports Server (NTRS)

Jiang, Ching-Biau; T'ien, James S.

1994-01-01

Excerpts from a paper describing the numerical examination of concurrent-flow flame spread over a thin solid in purely forced flow with gas-phase radiation are presented. The computational model solves the two-dimensional, elliptic, steady, and laminar conservation equations for mass, momentum, energy, and chemical species. Gas-phase combustion is modeled via a one-step, second order finite rate Arrhenius reaction. Gas-phase radiation considering gray non-scattering medium is solved by a S-N discrete ordinates method. A simplified solid phase treatment assumes a zeroth order pyrolysis relation and includes radiative interaction between the surface and the gas phase.

Controlled nitric oxide production via O(1D) + N2O reactions for use in oxidation flow reactor studies

NASA Astrophysics Data System (ADS)

Lambe, Andrew; Massoli, Paola; Zhang, Xuan; Canagaratna, Manjula; Nowak, John; Daube, Conner; Yan, Chao; Nie, Wei; Onasch, Timothy; Jayne, John; Kolb, Charles; Davidovits, Paul; Worsnop, Douglas; Brune, William

2017-06-01

Oxidation flow reactors that use low-pressure mercury lamps to produce hydroxyl (OH) radicals are an emerging technique for studying the oxidative aging of organic aerosols. Here, ozone (O3) is photolyzed at 254 nm to produce O(1D) radicals, which react with water vapor to produce OH. However, the need to use parts-per-million levels of O3 hinders the ability of oxidation flow reactors to simulate NOx-dependent secondary organic aerosol (SOA) formation pathways. Simple addition of nitric oxide (NO) results in fast conversion of NOx (NO + NO2) to nitric acid (HNO3), making it impossible to sustain NOx at levels that are sufficient to compete with hydroperoxy (HO2) radicals as a sink for organic peroxy (RO2) radicals. We developed a new method that is well suited to the characterization of NOx-dependent SOA formation pathways in oxidation flow reactors. NO and NO2 are produced via the reaction O(1D) + N2O → 2NO, followed by the reaction NO + O3 → NO2 + O2. Laboratory measurements coupled with photochemical model simulations suggest that O(1D) + N2O reactions can be used to systematically vary the relative branching ratio of RO2 + NO reactions relative to RO2 + HO2 and/or RO2 + RO2 reactions over a range of conditions relevant to atmospheric SOA formation. We demonstrate proof of concept using high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) measurements with nitrate (NO3-) reagent ion to detect gas-phase oxidation products of isoprene and α-pinene previously observed in NOx-influenced environments and in laboratory chamber experiments.

Controlled Nitric Oxide Production via O(1D) + N2O Reactions for Use in Oxidation Flow Reactor Studies

NASA Technical Reports Server (NTRS)

Lambe, Andrew; Massoli, Paola; Zhang, Xuan; Canagaratna, Manjula; Nowak, John; Daube, Conner; Yan, Chao; Nie, Wei; Onasch, Timothy; Jayne, John;

Turbine exhaust diffuser with region of reduced flow area and outer boundary gas flow

DOEpatents

Orosa, John

2014-03-11

An exhaust diffuser system and method for a turbine engine. The outer boundary may include a region in which the outer boundary extends radially inwardly toward the hub structure and may direct at least a portion of an exhaust flow in the diffuser toward the hub structure. At least one gas jet is provided including a jet exit located on the outer boundary. The jet exit may discharge a flow of gas downstream substantially parallel to an inner surface of the outer boundary to direct a portion of the exhaust flow in the diffuser toward the outer boundary to effect a radially outward flow of at least a portion of the exhaust gas flow toward the outer boundary to balance an aerodynamic load between the outer and inner boundaries.

Flow and criticality in the open cycle gas core.

NASA Technical Reports Server (NTRS)

Kunze, J. F.; Lofthouse, J. H.

1971-01-01

A series of flowing gas experiments using air, argon, and freon has been conducted in Idaho. The purpose is to study methods of obtaining flow patterns which would create maximum possible system reactivity consistent with an acceptably low uranium to coolant-gas loss ratio. These have been conducted on both ?two-dimensional' and truly three-dimensional spherical configurations of diameters 18 to 42 inches. The larger diameter is that proposed for a minimum cost flowing gas critical experiment, and the size extremes make extrapolations to the large 6 and 8 foot diameter configurations more reliable. Results show that large enough inner gas (fuel) volume fractions can be achieved to attain criticality.

System for controlling the flow of gas into and out of a gas laser

DOEpatents

Alger, Terry; Uhlich, Dennis M.; Benett, William J.; Ault, Earl R.

1994-01-01

A modularized system for controlling the gas pressure within a copper vapor or like laser is described herein. This system includes a gas input assembly which serves to direct gas into the laser in a controlled manner in response to the pressure therein for maintaining the laser pressure at a particular value, for example 40 torr. The system also includes a gas output assembly including a vacuum pump and a capillary tube arrangement which operates within both a viscous flow region and a molecular flow region for drawing gas out of the laser in a controlled manner.

Effects of flow rate and gas mixture on the welfare of weaned and neonate pigs during gas euthanasia.

PubMed

Sadler, L J; Hagen, C D; Wang, C; Widowski, T M; Johnson, A K; Millman, S T

2014-02-01

The objectives of this study were to assess efficacy and welfare implications of gas euthanasia when applied to weaned and neonate pigs. Parameters associated with welfare, which were measured before loss of consciousness, included open-mouth breathing, ataxia, righting response, and escape attempts. Two age groups (weaned and neonate) were assessed in 9 gas treatments arranged in a 2 × 4 factorial design, with 2 gas types (CO2 = 100% CO2 and 50:50 = 50:50 CO2:argon) and 4 flow rates (box volume exchange/min: slow = 20%; medium = 35%; fast = 50%; prefill = prefilled followed by 20%) and a control treatment in which ambient air was passed through the box. Pig pairs (10/treatment) were placed in a modified Euthanex AgPro system (Euthanex Corp., Palmer, PA). Behavioral and physiological responses were observed directly and from video recordings for latency, duration, prevalence (percent of pigs affected), and frequency (number of occurrences/pig). Data were analyzed as linear mixed models or with a Cox proportional hazard model as appropriate. Piglet pair was the experimental unit. For the weaned pig, welfare was superior with CO2 relative to 50:50 within 1 or more flow rates on the basis of reduced duration of open-mouth breathing, duration of ataxia, frequency of escape attempts, and duration and frequency of righting response (P < 0.05). No measured parameters indicated superior welfare with the use of 50:50, whereas latencies to loss of posture and last movement favored CO2 (P < 0.05). Faster flow rates were associated with reduced (P < 0.05) duration or frequency of open-mouth breathing, ataxia, and righting response, as well as superior (P < 0.05) indicators of efficacy, including latencies to loss of posture, gasping, and last movement, relative to slower flow rates. Weaned pigs were more likely to defecate (P < 0.01), display nasal discharge (P < 0.05), and display longer (P < 0.001) latencies to loss of posture and last movement than neonates. Duration of

Ionization and current growth in N/sub 2/ at very high electric field to gas density ratios

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gylys, V.T.; Jelenkovic, B.M.; Phelps, A.V.

1989-05-01

Measurements and analyses have been made of electron impact ionization and of current growth in pulsed, low-current, prebreakdown discharges in parallel-plane geometry in N/sub 2/ at very high electric field to gas density ratios E/n and low products of the gas density n and electrode separation d. The E/n range and nd ranges were 1

Uniform rovibrational collisional N2 bin model for DSMC, with application to atmospheric entry flows

NASA Astrophysics Data System (ADS)

Torres, E.; Bondar, Ye. A.; Magin, T. E.

2016-11-01

A state-to-state model for internal energy exchange and molecular dissociation allows for high-fidelity DSMC simulations. Elementary reaction cross sections for the N2 (v, J)+ N system were previously extracted from a quantum-chemical database, originally compiled at NASA Ames Research Center. Due to the high computational cost of simulating the full range of inelastic collision processes (approx. 23 million reactions), a coarse-grain model, called the Uniform RoVibrational Collisional (URVC) bin model can be used instead. This allows to reduce the original 9390 rovibrational levels of N2 to 10 energy bins. In the present work, this reduced model is used to simulate a 2D flow configuration, which more closely reproduces the conditions of high-speed entry into Earth's atmosphere. For this purpose, the URVC bin model had to be adapted for integration into the "Rarefied Gas Dynamics Analysis System" (RGDAS), a separate high-performance DSMC code capable of handling complex geometries and parallel computations. RGDAS was developed at the Institute of Theoretical and Applied Mechanics in Novosibirsk, Russia for use by the European Space Agency (ESA) and shares many features with the well-known SMILE code developed by the same group. We show that the reduced mechanism developed previously can be implemented in RGDAS, and the results exhibit nonequilibrium effects consistent with those observed in previous 1D-simulations.

Pulsatile pressure driven rarefied gas flow in long rectangular ducts

NASA Astrophysics Data System (ADS)

Tsimpoukis, Alexandros; Valougeorgis, Dimitris

2018-04-01

The pulsatile pressure driven fully developed flow of a rarefied gas through an orthogonal duct is investigated, based on the time-dependent linear Bhatnagar, Gross, and Krook equation, by decomposing the flow into its steady and oscillatory parts. The investigation is focused on the oscillatory part, which is characterized by the gas rarefaction and oscillation parameters, the duct aspect ratio, and the accommodation coefficient. As the oscillation frequency is increased, the amplitude of all macroscopic quantities is decreased, while their phase angle lag is increased reaching the limiting value of π/2. As the gas becomes more rarefied, higher frequencies are needed to trigger this behavior. At small and moderate frequencies, there is a critical degree of gas rarefaction, where a maximum flow rate is obtained. As the duct aspect ratio is decreased and tends to zero, the flow rate and mean wall shear stress amplitudes are increased, while their phase angle lags are slightly affected. The accommodation coefficient has a significant effect on the amplitude and a very weak one on the phase angle of the macroscopic quantities. The computation of the inertia and viscous forces clarifies when the flow consists of only one oscillating viscous region or of two regions, namely, the inviscid piston flow in the core and the oscillating Stokes layer at the wall with the velocity overshooting. Finally, the time average oscillatory pumping power is increased as the oscillation frequency is reduced and its maximum value is one half of the corresponding steady one.

Variable flow gas turbine engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stroem, S.

1986-11-25

This patent describes a variable flow gas turbine engine of the type having a combustor for generating combustion gases and a turbine rotor for receiving and expanding the hot combustion gases, comprising: duct means for defining a channel for directing the flow of combustion gases from the combustor to the rotor; vane means in the channel forming at least one throat; means for varying the effective flow area for combustion gases flowing through the throat and impinging on the rotor. The varying means includes winglet means fixedly mounted in the throat for separating the gases flowing through the throat intomore » first and second streams; and means for injecting high pressure fluid into the throat for varying the flow of combustion gases in one of the streams.« less

Close entrainment of massive molecular gas flows by radio bubbles in the central galaxy of Abell 1795

NASA Astrophysics Data System (ADS)

Russell, H. R.; McNamara, B. R.; Fabian, A. C.; Nulsen, P. E. J.; Combes, F.; Edge, A. C.; Hogan, M. T.; McDonald, M.; Salomé, P.; Tremblay, G.; Vantyghem, A. N.

2017-12-01

We present new ALMA observations tracing the morphology and velocity structure of the molecular gas in the central galaxy of the cluster Abell 1795. The molecular gas lies in two filaments that extend 5-7 kpc to the N and S from the nucleus and project exclusively around the outer edges of two inner radio bubbles. Radio jets launched by the central active galactic nucleus have inflated bubbles filled with relativistic plasma into the hot atmosphere surrounding the central galaxy. The N filament has a smoothly increasing velocity gradient along its length from the central galaxy's systemic velocity at the nucleus to -370 km s^{-1}, the average velocity of the surrounding galaxies, at the furthest extent. The S filament has a similarly smooth but shallower velocity gradient and appears to have partially collapsed in a burst of star formation. The close spatial association with the radio lobes, together with the ordered velocity gradients and narrow velocity dispersions, shows that the molecular filaments are gas flows entrained by the expanding radio bubbles. Assuming a Galactic XCO factor, the total molecular gas mass is 3.2 ± 0.2 × 109 M⊙. More than half lies above the N radio bubble. Lifting the molecular clouds appears to require an infeasibly efficient coupling between the molecular gas and the radio bubble. The energy required also exceeds the mechanical power of the N radio bubble by a factor of 2. Stimulated feedback, where the radio bubbles lift low-entropy X-ray gas that becomes thermally unstable and rapidly cools in situ, provides a plausible model. Multiple generations of radio bubbles are required to lift this substantial gas mass. The close morphological association then indicates that the cold gas either moulds the newly expanding bubbles or is itself pushed aside and shaped as they inflate.

Cascading Tesla Oscillating Flow Diode for Stirling Engine Gas Bearings

NASA Technical Reports Server (NTRS)

Dyson, Rodger

2012-01-01

Replacing the mechanical check-valve in a Stirling engine with a micromachined, non-moving-part flow diode eliminates moving parts and reduces the risk of microparticle clogging. At very small scales, helium gas has sufficient mass momentum that it can act as a flow controller in a similar way as a transistor can redirect electrical signals with a smaller bias signal. The innovation here forces helium gas to flow in predominantly one direction by offering a clear, straight-path microchannel in one direction of flow, but then through a sophisticated geometry, the reversed flow is forced through a tortuous path. This redirection is achieved by using microfluid channel flow to force the much larger main flow into this tortuous path. While microdiodes have been developed in the past, this innovation cascades Tesla diodes to create a much higher pressure in the gas bearing supply plenum. In addition, the special shape of the leaves captures loose particles that would otherwise clog the microchannel of the gas bearing pads.

42 CFR 84.94 - Gas flow test; closed-circuit apparatus.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 42 Public Health 1 2011-10-01 2011-10-01 false Gas flow test; closed-circuit apparatus. 84.94...-Contained Breathing Apparatus § 84.94 Gas flow test; closed-circuit apparatus. (a) Where oxygen is supplied... rated service time of the apparatus. (b) Where constant flow is used in conjunction with demand flow...

42 CFR 84.94 - Gas flow test; closed-circuit apparatus.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 42 Public Health 1 2010-10-01 2010-10-01 false Gas flow test; closed-circuit apparatus. 84.94...-Contained Breathing Apparatus § 84.94 Gas flow test; closed-circuit apparatus. (a) Where oxygen is supplied... rated service time of the apparatus. (b) Where constant flow is used in conjunction with demand flow...

Gas Flow and Ion Transfer in Heated ESI Capillary Interfaces

NASA Astrophysics Data System (ADS)

Bernier, Laurent; Pinfold, Harry; Pauly, Matthias; Rauschenbach, Stephan; Reiss, Julius

2018-02-01

Transfer capillaries are the preferred means to transport ions, generated by electrospray ionization, from ambient conditions to vacuum. During the transfer of ions through the narrow, long tubes into vacuum, substantial losses are typical. However, recently it was demonstrated that these losses can be avoided altogether. To understand the experimental observation and provide a general model for the ion transport, here, we investigate the ion transport through capillaries by numerical simulation of interacting ions. The simulation encompasses all relevant factors, such as space charge, diffusion, gas flow, and heating. Special attention is paid to the influence of the gas flow on the transmission and especially the change imposed by heating. The gas flow is modeled by a one-dimensional gas dynamics description. A large number of ions are treated as point particles in this gas flow. This allows to investigate the influence of the capillary heating on the gas flow and by this on the ion transport. The results are compared with experimental findings. [Figure not available: see fulltext.

On the Divergence of the Velocity Vector in Real-Gas Flow

NASA Technical Reports Server (NTRS)

Bellan, Josette

2009-01-01

A theoretical study was performed addressing the degree of applicability or inapplicability, to a real gas, of the occasionally stated belief that for an ideal gas, incompressibility is synonymous with a zero or very low Mach number. The measure of compressibility used in this study is the magnitude of the divergence of the flow velocity vector [V(bar) (raised dot) u (where u is the flow velocity)]. The study involves a mathematical derivation that begins with the governing equations of flow and involves consideration of equations of state, thermodynamics, and fluxes of heat, mass, and the affected molecular species. The derivation leads to an equation for the volume integral of (V(bar) (raised dot) u)(sup 2) that indicates contributions of several thermodynamic, hydrodynamic, and species-flux effects to compressibility and reveals differences between real and ideal gases. An analysis of the equation leads to the conclusion that for a real gas, incompressibility is not synonymous with zero or very small Mach number. Therefore, it is further concluded, the contributions to compressibility revealed by the derived equation should be taken into account in simulations of real-gas flows.

Gas flows in radial micro-nozzles with pseudo-shocks

NASA Astrophysics Data System (ADS)

Kiselev, S. P.; Kiselev, V. P.; Zaikovskii, V. N.

2018-07-01

In the present paper, results of an experimental and numerical study of supersonic gas flows in radial micro-nozzles are reported. A distinguishing feature of such flows is the fact that two factors, the nozzle divergence and the wall friction force, exert a substantial influence on the flow structure. Under the action of the wall friction force, in the micro-nozzle there forms a pseudo-shock that separates the supersonic from subsonic flow region. The position of the pseudo-shock can be evaluated from the condition of flow blockage in the nozzle exit section. A detailed qualitative and quantitative analysis of gas flows in radial micro-nozzles is given. It is shown that the gas flow in a micro-nozzle is defined by the complicated structure of the boundary layer in the micro-nozzle, this structure being dependent on the width-to-radius ratio of the nozzle and its inlet-to-outlet pressure ratio.

Gas flow means for improving efficiency of exhaust hoods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gadgil, A.J.

1994-01-11

Apparatus is described for inhibiting the flow of contaminants in an exhaust enclosure toward an individual located adjacent an opening into the exhaust enclosure by providing a gas flow toward a source of contaminants from a position in front of an individual to urge said contaminants away from the individual toward a gas exit port. The apparatus comprises a gas manifold which may be worn by a person as a vest. The manifold has a series of gas outlets on a front face thereof facing away from the individual and toward the contaminants to thereby provide a flow of gasmore » from the front of the individual toward the contaminants. 15 figures.« less

N2 glacial flow on and onto Sputnik Planum

NASA Astrophysics Data System (ADS)

Umurhan, O. M.; Moore, J. M.; Howard, A. D.; McKinnon, W. B.; Nimmo, F.; Schenk, P.; White, O. L.; Grundy, W. M.; Stern, A.; Olkin, C.; Weaver, H. A., Jr.; Young, L. A.; Ennico Smith, K.

2015-12-01

Sputnik Planum (SP)[1,2] is the high albedo crater-free western portion of Tombaugh Regio imaged in July by the New Horizons LORRI instrument. The relatively high resolution (400 m/pix) LORRI mosaics of the northern portions of the planum bordered by the Cousteau Rupes (CR) scarp reveal surface patterns highly suggestive of viscous flow dynamics. Spectroscopic measurements of SP taken by the New Horizons LEISA instrument also indicate that SP is a region containing (among others) a significant amount of N2 [2]. Taken together these observations suggest the possibility that the high albedo material on SP is glacial N2 ice atop a bedrock-like substrate and the notable lack of craters on SP means that these processes are acting on relatively fast geologic timescales. Using the known properties of N2 ice in the temperature range of interest, we formulate and implement a numerical landform evolution model in order to examine a number of hypothetical evolutionary scenarios for SP and its environs. [1] All place names on Pluto and Charon are informally known as such as of the writing of this abstract. [2] Stern, S. A et al. 2015 Science.

Emission Spectroscopy of the 4X Source Discharge With and Without N 2 Gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Horace Vernon

2016-01-14

This tech note summarizes the December, 1988 emission spectroscopy measurements made on the 4X source discharge with and without N₂ gas added to the H + Cs discharge. This study is motivated by the desire to understand why small amounts of N₂ gas added to the source discharge results in a reduction in the H⁻ beam noise. The beneficial effect of N₂ gas on H⁻ beam noise was first discovered by Bill Ingalls and Stu Orbesen on the ATS SAS source. For the 4X source the observed effect is that when N2 gas is added to the discharge the H⁻more » beam noise is reduced about a factor of 2.« less

Design and Feasibility Analysis of a Self-Sustaining Biofiltration System for Removal of Low Concentration N2O Emitted from Wastewater Treatment Plants.

PubMed

Yoon, Hyun; Song, Min Joon; Yoon, Sukhwan

2017-09-19

N 2 O is a potent greenhouse gas and ozone-depletion agent. In this study, a biofiltration system was designed for removal of N 2 O emitted at low concentrations (<200 ppmv) from wastewater treatment plants. The proposed biofiltration system utilizes untreated wastewater from the primary sedimentation basin as the source of electron donor and nutrients and energy requirement is minimized by utilizing gravitational force and pressure differential to direct liquid medium and gas through the biofilter. The experiments performed with laboratory-scale biofilter in two different configurations confirmed the feasibility of the biofiltration system. The biofilter operated with cycling of raw wastewater exhibited up to 94% and 53% removal efficiency with 100 ppmv N 2 O in N 2 and air, respectively, as the feed gas, corroborating that untreated wastewater can serve as a robust source of electron donor and nutrients. The laboratory-scale biofilter operated with a continuous flow-through of synthetic wastewater attained >99.9% removal of N 2 O from N 2 background at the gas flow rate up to 2,000 mL·min -1 and >50% N 2 O removal from air background at the gas flow rate of 200 mL·min -1 . nosZ-containing bacterial genera including Flavobacterium (5.92%), Pseudomonas (4.26%) and Bosea (2.39%) were identified in the biofilm samples collected from the oxic biofilter, indicating these organisms were responsible for N 2 O removal.

Elliptic flow in heavy-ion collisions at energies √{sN N}=2.7 - 39 GeV

NASA Astrophysics Data System (ADS)

Ivanov, Yu. B.; Soldatov, A. A.

2015-02-01

The transverse-momentum-integrated elliptic flow of charged particles at midrapidity, v2(charged), and that of identified hadrons from Au +Au collisions are computed in a wide range of incident energies 2.7 ≤√{sN N}≤ 39 GeV. The simulations are performed within a three-fluid model by employing three different equations of state (EoSs): a purely hadronic EoS and two versions of the EoS involving the deconfinement transition—a first-order phase transition and a smooth crossover one. The present simulations demonstrate low sensitivity of v2(charged) to the EoS. All considered scenarios equally well reproduce recent STAR data on v2(charged) for mid-central Au +Au collisions and properly describe its change of sign at the incident energy decrease below √{sN N}≈ 3.5 GeV. The predicted integrated elliptic flow of various species exhibits a stronger dependence on the EoS. A noticeable sensitivity to the EoS is found for antibaryons and, to a lesser extent, for K- mesons. In particular, the v2 excitation functions of antibaryons exhibit a nonmonotonicity within the deconfinement scenarios that was predicted by Kolb, Sollfrank, and Heinz. However, low multiplicities of antibaryons at √{sN N}≤ 10 GeV result in large fluctuations of their v2, which may wash out this nonmonotonicity.

42 CFR 84.93 - Gas flow test; open-circuit apparatus.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 42 Public Health 1 2011-10-01 2011-10-01 false Gas flow test; open-circuit apparatus. 84.93...-Contained Breathing Apparatus § 84.93 Gas flow test; open-circuit apparatus. (a) A static-flow test will be performed on all open-circuit apparatus. (b) The flow from the apparatus shall be greater than 200 liters...

42 CFR 84.93 - Gas flow test; open-circuit apparatus.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 42 Public Health 1 2010-10-01 2010-10-01 false Gas flow test; open-circuit apparatus. 84.93...-Contained Breathing Apparatus § 84.93 Gas flow test; open-circuit apparatus. (a) A static-flow test will be performed on all open-circuit apparatus. (b) The flow from the apparatus shall be greater than 200 liters...

Development of N_2O-MTV for low-speed flow and in-situ deployment to an integral effect test facility

NASA Astrophysics Data System (ADS)

André, Matthieu A.; Burns, Ross A.; Danehy, Paul M.; Cadell, Seth R.; Woods, Brian G.; Bardet, Philippe M.

2018-01-01

A molecular tagging velocity (MTV) technique is developed to non-intrusively measure velocity in an integral effect test (IET) facility simulating a high-temperature helium-cooled nuclear reactor in accident scenarios. In these scenarios, the velocities are expected to be low, on the order of 1 m/s or less, which forces special requirements on the MTV tracer selection. Nitrous oxide (N_2O) is identified as a suitable seed gas to generate NO tracers capable of probing the flow over a large range of pressure, temperature, and flow velocity. The performance of N_2O-MTV is assessed in the laboratory at temperature and pressure ranging from 295 to 781 K and 1 to 3 atm. MTV signal improves with a temperature increase, but decreases with a pressure increase. Velocity precision down to 0.004 m/s is achieved with a probe time of 40 ms at ambient pressure and temperature. Measurement precision is limited by tracer diffusion, and absorption of the tag laser beam by the seed gas. Processing by cross-correlation of single-shot images with high signal-to-noise ratio reference images improves the precision by about 10% compared to traditional single-shot image correlations. The instrument is then deployed to the IET facility. Challenges associated with heat, vibrations, safety, beam delivery, and imaging are addressed in order to successfully operate this sensitive instrument in-situ. Data are presented for an isothermal depressurized conduction cooldown. Velocity profiles from MTV reveal a complex flow transient driven by buoyancy, diffusion, and instability taking place over short (<1 s) and long (>30 min) time scales at sub-meter per second speed. The precision of the in-situ results is estimated at 0.027, 0.0095, and 0.006 m/s for a probe time of 5, 15, and 35 ms, respectively.

Simulation of granular and gas-solid flows using discrete element method

NASA Astrophysics Data System (ADS)

Boyalakuntla, Dhanunjay S.

2003-10-01

In recent years there has been increased research activity in the experimental and numerical study of gas-solid flows. Flows of this type have numerous applications in the energy, pharmaceuticals, and chemicals process industries. Typical applications include pulverized coal combustion, flow and heat transfer in bubbling and circulating fluidized beds, hopper and chute flows, pneumatic transport of pharmaceutical powders and pellets, and many more. The present work addresses the study of gas-solid flows using computational fluid dynamics (CFD) techniques and discrete element simulation methods (DES) combined. Many previous studies of coupled gas-solid flows have been performed assuming the solid phase as a continuum with averaged properties and treating the gas-solid flow as constituting of interpenetrating continua. Instead, in the present work, the gas phase flow is simulated using continuum theory and the solid phase flow is simulated using DES. DES treats each solid particle individually, thus accounting for its dynamics due to particle-particle interactions, particle-wall interactions as well as fluid drag and buoyancy. The present work involves developing efficient DES methods for dense granular flow and coupling this simulation to continuum simulations of the gas phase flow. Simulations have been performed to observe pure granular behavior in vibrating beds. Benchmark cases have been simulated and the results obtained match the published literature. The dimensionless acceleration amplitude and the bed height are the parameters governing bed behavior. Various interesting behaviors such as heaping, round and cusp surface standing waves, as well as kinks, have been observed for different values of the acceleration amplitude for a given bed height. Furthermore, binary granular mixtures (granular mixtures with two particle sizes) in a vibrated bed have also been studied. Gas-solid flow simulations have been performed to study fluidized beds. Benchmark 2D

Gas-liquid mass transfer and flow phenomena in the Peirce-Smith converter: a water model study

NASA Astrophysics Data System (ADS)

Zhao, Xing; Zhao, Hong-liang; Zhang, Li-feng; Yang, Li-qiang

2018-01-01

A water model with a geometric similarity ratio of 1:5 was developed to investigate the gas-liquid mass transfer and flow characteristics in a Peirce-Smith converter. A gas mixture of CO2 and Ar was injected into a NaOH solution bath. The flow field, volumetric mass transfer coefficient per unit volume ( Ak/V; where A is the contact area between phases, V is the volume, and k is the mass transfer coefficient), and gas utilization ratio ( η) were then measured at different gas flow rates and blow angles. The results showed that the flow field could be divided into five regions, i.e., injection, strong loop, weak loop, splashing, and dead zone. Whereas the Ak/V of the bath increased and then decreased with increasing gas flow rate, and η steadily increased. When the converter was rotated clockwise, both Ak/V and η increased. However, the flow condition deteriorated when the gas flow rate and blow angle were drastically increased. Therefore, these parameters must be controlled to optimal conditions. In the proposed model, the optimal gas flow rate and blow angle were 7.5 m3·h-1 and 10°, respectively.

Fast gas heating and radial distribution of active species in nanosecond capillary discharge in pure nitrogen and N2:O2 mixtures

NASA Astrophysics Data System (ADS)

Lepikhin, N. D.; Popov, N. A.; Starikovskaia, S. M.

2018-05-01

Fast gas heating is studied experimentally and numerically using pulsed nanosecond capillary discharge in pure nitrogen and N2:O2 mixtures under the conditions of high specific deposited energy (up to 1 eV/molecule) and high reduced electric fields (100–300 Td). Deposited energy, electric field and gas temperature are measured as functions of time. The radial distribution of active species is analyzed experimentally. The roles of processes involving {{{N}}}2({{B}}) ={{{N}}}2({{{B}}}3{{{\\Pi }}}{{g}},{{{W}}}3{{{Δ }}}{{u}},{{B}}{{\\prime} }3{{{Σ }}}{{u}}-), {{{N}}}2({{{A}}}3{{{Σ }}}{{u}}+) and N(2D) excited nitrogen species leading to heat release are analyzed using numerical modeling in the framework of 1D axial approximation.

Gas entrapment and microbial N2O reduction reduce N2O emissions from a biochar-amended sandy clay loam soil

PubMed Central

Harter, Johannes; Guzman-Bustamante, Ivan; Kuehfuss, Stefanie; Ruser, Reiner; Well, Reinhard; Spott, Oliver; Kappler, Andreas; Behrens, Sebastian

2016-01-01

Nitrous oxide (N2O) is a potent greenhouse gas that is produced during microbial nitrogen transformation processes such as nitrification and denitrification. Soils represent the largest sources of N2O emissions with nitrogen fertilizer application being the main driver of rising atmospheric N2O concentrations. Soil biochar amendment has been proposed as a promising tool to mitigate N2O emissions from soils. However, the underlying processes that cause N2O emission suppression in biochar-amended soils are still poorly understood. We set up microcosm experiments with fertilized, wet soil in which we used 15N tracing techniques and quantitative polymerase chain reaction (qPCR) to investigate the impact of biochar on mineral and gaseous nitrogen dynamics and denitrification-specific functional marker gene abundance and expression. In accordance with previous studies our results showed that biochar addition can lead to a significant decrease in N2O emissions. Furthermore, we determined significantly higher quantities of soil-entrapped N2O and N2 in biochar microcosms and a biochar-induced increase in typical and atypical nosZ transcript copy numbers. Our findings suggest that biochar-induced N2O emission mitigation is based on the entrapment of N2O in water-saturated pores of the soil matrix and concurrent stimulation of microbial N2O reduction resulting in an overall decrease of the N2O/(N2O + N2) ratio. PMID:28008997

Effect of corona discharge on the gas composition of the sample flow in a Gas Particle Partitioner.

PubMed

Asbach, Christof; Kuhlbusch, Thomas A J; Fissan, Heinz

2005-09-01

A Gas Particle Partitioner (GPP) that allows highly efficient separation of gas and particles with no effect on the thermodynamic conditions and substantially no change of the gas composition has been developed. The GPP is a coaxial arrangement with inner and outer electrodes and utilizes a corona discharge to electrically charge the particles and a strong electric field to remove them from the sample flow. Several measures were taken to avoid an influence of the corona discharge on the gas composition. The GPP can be applied for various applications. This paper focuses on the use of the GPP as a pre-filter for gas analyzers, where zero pressure drop and a minimization of the influence of the corona discharge on the gas composition are the main objective. Due to its design, the GPP introduces no changes to the thermodynamic conditions. However, corona discharge is known to produce significant amounts of ozone and oxides of nitrogen. The effect of the corona on the gas composition of the sample flow was determined under various conditions. The gas concentrations strongly depended on several aspects, such as material and diameter of the corona wire and polarity of the corona voltage. Due to the measures taken to minimize an effect on the gas composition, the concentrations of these gases could effectively be reduced. Along with the maximum gas-particle separation efficiency of near 100%, the additional O3 concentration was 42 ppbV and the additional NO2 concentration 15 ppbV. If an efficiency of 95% is acceptable, the added concentrations can be as low as 2.5 ppbV (O3) and 0.5 ppbV (NO2), respectively.

Malignant human cell transformation of Marcellus shale gas drilling flow back water

PubMed Central

Yao, Yixin; Chen, Tingting; Shen, Steven S.; Niu, Yingmei; DesMarais, Thomas L; Linn, Reka; Saunders, Eric; Fan, Zhihua; Lioy, Paul; Kluz, Thomas; Chen, Lung-Chi; Wu, Zhuangchun; Costa, Max

2015-01-01

The rapid development of high-volume horizontal hydraulic fracturing for mining natural gas from shale has posed potential impacts on human health and biodiversity. The produced flow back waters after hydraulic stimulation is known to carry high levels of saline and total dissolved solids. To understand the toxicity and potential carcinogenic effects of these waste waters, flow back water from five Marcellus hydraulic fracturing oil and gas wells were analyzed. The physicochemical nature of these samples was analyzed by inductively coupled plasma mass spectrometry and scanning electron microscopy / energy dispersive X-ray spectroscopy. A cytotoxicity study using colony formation as the endpoint was carried out to define the LC50 values of test samples using human bronchial epithelial cells (BEAS-2B). The BEAS-2B cell transformation assay was employed to assess the carcinogenic potential of the samples. Barium and strontium were among the most abundant metals in these samples and the same metals were found elevated in BEAS-2B cells after long-term treatment. BEAS-2B cells treated for 6 weeks with flow back waters produced colony formation in soft agar that was concentration dependant. In addition, flow back water-transformed BEAS-2B cells show a better migration capability when compared to control cells. This study provides information needed to assess the potential health impact of post-hydraulic fracturing flow back waters from Marcellus Shale natural gas mining. PMID:26210350

Malignant human cell transformation of Marcellus Shale gas drilling flow back water.

PubMed

Yao, Yixin; Chen, Tingting; Shen, Steven S; Niu, Yingmei; DesMarais, Thomas L; Linn, Reka; Saunders, Eric; Fan, Zhihua; Lioy, Paul; Kluz, Thomas; Chen, Lung-Chi; Wu, Zhuangchun; Costa, Max; Zelikoff, Judith

2015-10-01

The rapid development of high-volume horizontal hydraulic fracturing for mining natural gas from shale has posed potential impacts on human health and biodiversity. The produced flow back waters after hydraulic stimulation are known to carry high levels of saline and total dissolved solids. To understand the toxicity and potential carcinogenic effects of these wastewaters, flow back waters from five Marcellus hydraulic fracturing oil and gas wells were analyzed. The physicochemical nature of these samples was analyzed by inductively coupled plasma mass spectrometry and scanning electron microscopy/energy dispersive X-ray spectroscopy. A cytotoxicity study using colony formation as the endpoint was carried out to define the LC50 values of test samples using human bronchial epithelial cells (BEAS-2B). The BEAS-2B cell transformation assay was employed to assess the carcinogenic potential of the samples. Barium and strontium were among the most abundant metals in these samples and the same metals were found to be elevated in BEAS-2B cells after long-term treatment. BEAS-2B cells treated for 6weeks with flow back waters produced colony formation in soft agar that was concentration dependent. In addition, flow back water-transformed BEAS-2B cells show better migration capability when compared to control cells. This study provides information needed to assess the potential health impact of post-hydraulic fracturing flow back waters from Marcellus Shale natural gas mining. Copyright © 2015 Elsevier Inc. All rights reserved.

Controlled nitric oxide production via O( 1D)+N 2O reactions for use in oxidation flow reactor studies

DOE PAGES

Lambe, Andrew; Massoli, Paola; Zhang, Xuan; ...

2017-06-22

Oxidation flow reactors that use low-pressure mercury lamps to produce hydroxyl (OH) radicals are an emerging technique for studying the oxidative aging of organic aerosols. Here, ozone (O 3) is photolyzed at 254 nm to produce O( 1D) radicals, which react with water vapor to produce OH. However, the need to use parts-per-million levels of O 3 hinders the ability of oxidation flow reactors to simulate NO x-dependent secondary organic aerosol (SOA) formation pathways. Simple addition of nitric oxide (NO) results in fast conversion of NO x (NO+NO 2) to nitric acid (HNO 3), making it impossible to sustain NOmore » x at levels that are sufficient to compete with hydroperoxy (HO 2) radicals as a sink for organic peroxy (RO 2) radicals. We developed a new method that is well suited to the characterization of NO x-dependent SOA formation pathways in oxidation flow reactors. NO and NO 2 are produced via the reaction O( 1D) + N 2O → 2NO, followed by the reaction NO + O 3 → NO 2+O 2. Laboratory measurements coupled with photochemical model simulations suggest that O( 1D) + N 2O reactions can be used to systematically vary the relative branching ratio of RO 2 + NO reactions relative to RO 2 + HO 2 and/or RO 2 + RO 2 reactions over a range of conditions relevant to atmospheric SOA formation. We demonstrate proof of concept using high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) measurements with nitrate (NO 3 -) reagent ion to detect gas-phase oxidation products of isoprene and α-pinene previously observed in NO x-influenced environments and in laboratory chamber experiments.« less

Controlled nitric oxide production via O( 1D)+N 2O reactions for use in oxidation flow reactor studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lambe, Andrew; Massoli, Paola; Zhang, Xuan

Oxidation flow reactors that use low-pressure mercury lamps to produce hydroxyl (OH) radicals are an emerging technique for studying the oxidative aging of organic aerosols. Here, ozone (O 3) is photolyzed at 254 nm to produce O( 1D) radicals, which react with water vapor to produce OH. However, the need to use parts-per-million levels of O 3 hinders the ability of oxidation flow reactors to simulate NO x-dependent secondary organic aerosol (SOA) formation pathways. Simple addition of nitric oxide (NO) results in fast conversion of NO x (NO+NO 2) to nitric acid (HNO 3), making it impossible to sustain NOmore » x at levels that are sufficient to compete with hydroperoxy (HO 2) radicals as a sink for organic peroxy (RO 2) radicals. We developed a new method that is well suited to the characterization of NO x-dependent SOA formation pathways in oxidation flow reactors. NO and NO 2 are produced via the reaction O( 1D) + N 2O → 2NO, followed by the reaction NO + O 3 → NO 2+O 2. Laboratory measurements coupled with photochemical model simulations suggest that O( 1D) + N 2O reactions can be used to systematically vary the relative branching ratio of RO 2 + NO reactions relative to RO 2 + HO 2 and/or RO 2 + RO 2 reactions over a range of conditions relevant to atmospheric SOA formation. We demonstrate proof of concept using high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) measurements with nitrate (NO 3 -) reagent ion to detect gas-phase oxidation products of isoprene and α-pinene previously observed in NO x-influenced environments and in laboratory chamber experiments.« less

Breakdown characteristics of atmospheric dielectric barrier discharge in gas flow condition

NASA Astrophysics Data System (ADS)

Fan, Zhihui; Yan, Huijie; Wang, Yuying; Liu, Yidi; Guo, Hongfei; Ren, Chunsheng

2018-05-01

Experimental investigations of the breakdown characteristics of plate-to-plate dielectric barrier discharge excited by an AC source at different gas flow conditions are carried out. The ignition voltage for the appearance of the very first discharge filament and the breakdown voltage in each discharge half cycle in continuous operation are examined. As revealed by the results of the indoor air experiment, the ignition voltage manifests a monotonous increase with the increase in the gas flow rate, while the breakdown voltage has a marked decline at the low gas flow rate and increases slightly as the gas flow rate is higher than 10 m/s. As regards the obvious decreases in the ignition voltage and breakdown voltage, the decrease in the humidity with the increase in the gas flow rate plays a dominant role. As regards the increase in breakdown voltage, the memory effect from the preceding discharge is considered. The losses of metastable particles, together with particles having high translational energy in the gas flow, are considered to be the most critical factors.

Effect of particle inertia on fluid turbulence in gas-solid disperse flow

NASA Astrophysics Data System (ADS)

Mito, Yoichi

2016-11-01

The effect of particle inertia on the fluid turbulence in gas-solid disperse flow through a vertical channel has been examined by using a direct numerical simulation, to calculate the gas velocities seen by the particles, and a simplified non-stationary flow model, in which a uniform distribution of solid spheres of density ratio of 1000 are added into the fully-developed turbulent gas flow in an infinitely wide channel. The gas flow is driven downward with a constant pressure gradient. The frictional Reynolds number defined with the frictional velocity before the addition of particles, v0*, is 150. The feedback forces are calculated using a point force method. Particle diameters of 0.95, 1.3 and 1.9, which are made dimensionless with v0* and the kinematic viscosity, and volume fractions, ranging from 1 ×10-4 to 2 ×10-3 , in addition to the one-way coupling cases, are considered. Gravitational effect is not clearly seen where the fluid turbulence is damped by feedback effect. Gas flow rate increases with the decrease in particle inertia, that causes the increase in feedback force. Fluid turbulence decreases with the increase in particle inertia, that causes the increase in diffusivity of feedback force and of fluid turbulence. This work was supported by JSPS KAKENHI Grant Number 26420097.

Study on optical emission analysis of AC air water discharges under He, Ar and N2 environments

NASA Astrophysics Data System (ADS)

Park, J. Y.; Kostyuk, P. V.; Han, S. B.; Kim, J. S.; Vu, C. N.; Lee, H. W.

2006-09-01

In this paper, hybrid air-water discharges were used to develop an optimal condition for providing a high level of water decomposition for hydrogen evolution. Electrical and optical phenomena accompanying the discharges were investigated along with feeding gases, flow rates and point-to-plane electrode gap distance. The experiments were primarily focused on the optical emission of the near UV range, providing a sufficient energy threshold for water dissociation and excitation. The OH(A 2Σ+ → X 2Π, Δν = 0) band optical emission intensity indicated the presence of plasma chemical reactions involving hydrogen formation. Despite the fact that energy input was high, the OH(A-X) optical emission was found to be negligible at the zero gap distance between the tip of the metal rod and water surface. In the gas atmosphere saturated with water vapour the OH(A-X) intensity was relatively high compared with the liquid and transient phases although the optical emission strongly depended on the flow rate and type of feeding gas. The gas phase was found to be more favourable because of less energy consumption in the cases of He and Ar carrier gases, and quenching mechanisms of oxygen in the N2 carrier gas atmosphere, preventing hydrogen from recombining with oxygen. In the gas phase the discharge was at a steady state, in contrast to the other phases, in which bubbles interrupted propagation of the plasma channel. Optical emission intensity of OH(A-X) band increased according to the flow rate or residence time of the He feeding gas. Nevertheless, a reciprocal tendency was acquired for N2 and Ar carrier gases. The peak value of OH(A-X) band optical emission intensity was observed near the water surface; however in the cases of Ar and N2 with a 0.5 SLM flow rate, it was shifted below the water surface. Rotational temperature was estimated to be in the range of 900-3600 K, according to the carrier gas and flow rate, which is sufficient for hydrogen production.

Effects of argon gas flow rate on laser-welding.

PubMed

Takayama, Yasuko; Nomoto, Rie; Nakajima, Hiroyuki; Ohkubo, Chikahiro

2012-01-01

The purpose of this study was to evaluate the effects of the rate of argon gas flow on joint strength in the laser-welding of cast metal plates and to measure the porosity. Two cast plates (Ti and Co-Cr alloy) of the same metal were abutted and welded together. The rates of argon gas flow were 0, 5 and 10 L/min for the Co-Cr alloy, and 5 and 10 L/min for the Ti. There was a significant difference in the ratio of porosity according to the rate of argon gas flow in the welded area. Argon shielding had no significant effect on the tensile strength of Co-Cr alloy. The 5 L/min specimens showed greater tensile strength than the 10 L/min specimens for Ti. Laser welding of the Co-Cr alloy was influenced very little by argon shielding. When the rate of argon gas flow was high, joint strength decreased for Ti.

Transport coefficients in nonequilibrium gas-mixture flows with electronic excitation.

PubMed

Kustova, E V; Puzyreva, L A

2009-10-01

In the present paper, a one-temperature model of transport properties in chemically nonequilibrium neutral gas-mixture flows with electronic excitation is developed. The closed set of governing equations for the macroscopic parameters taking into account electronic degrees of freedom of both molecules and atoms is derived using the generalized Chapman-Enskog method. The transport algorithms for the calculation of the thermal-conductivity, diffusion, and viscosity coefficients are proposed. The developed theoretical model is applied for the calculation of the transport coefficients in the electronically excited N/N(2) mixture. The specific heats and transport coefficients are calculated in the temperature range 50-50,000 K. Two sets of data for the collision integrals are applied for the calculations. An important contribution of the excited electronic states to the heat transfer is shown. The Prandtl number of atomic species is found to be substantially nonconstant.

Nitrogen gas flushing can be bactericidal: the temperature-dependent destiny of Bacillus weihenstephanensis KBAB4 under a pure N2 atmosphere.

PubMed

Munsch-Alatossava, Patricia; Alatossava, Tapani

2014-01-01

Gram-negative Pseudomonas and Gram-positive Bacillus are the most common spoilage bacteria in raw and pasteurized milk, respectively. In previous studies, nitrogen (N2) gas flushing treatments of raw and pasteurized milk at cold chain-temperatures inhibited bacterial spoilage and highlighted different susceptibilities to the N2 treatment with the exclusion of certain bacterial types. Here, we investigated the effects of pure N2 gas flushing on representative strains of these genera grown in mono- or co-cultures at 15 and 25°C. Bacillus weihenstephanensis, a frequent inhabitant of fluid dairy products, is represented by the genome-sequenced KBAB4 strain. Among Pseudomonas, P. tolaasii LMG 2342(T) and strain C1, a raw milk psychrotroph, were selected. The N2 gas flushing treatment revealed: (1) temperature-dependent responses; (2) inhibition of the growth of both pseudomonads; (3) emergence of small colony variants (SCVs) for B. weihenstephanensis strain KBAB4 at 15°C induced by the N2 treatment or when grown in co-culture with Pseudomonas strains; (4) N2 gas flushing modulates (suppressed or stimulated) bacterial antagonistic reactions in co-cultures; (5) most importantly, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses revealed that at 25°C the majority of the KBAB4 cells were killed by pure N2 gas flushing. This observation constitutes the first evidence that N2 gas flushing has bactericidal effects.

Custom ultrasonic instrumentation for flow measurement and real-time binary gas analysis in the CERN ATLAS experiment

NASA Astrophysics Data System (ADS)

Alhroob, M.; Battistin, M.; Berry, S.; Bitadze, A.; Bonneau, P.; Boyd, G.; Crespo-Lopez, O.; Degeorge, C.; Deterre, C.; Di Girolamo, B.; Doubek, M.; Favre, G.; Hallewell, G.; Katunin, S.; Lombard, D.; Madsen, A.; McMahon, S.; Nagai, K.; O'Rourke, A.; Pearson, B.; Robinson, D.; Rossi, C.; Rozanov, A.; Stanecka, E.; Strauss, M.; Vacek, V.; Vaglio, R.; Young, J.; Zwalinski, L.

2017-01-01

The development of custom ultrasonic instrumentation was motivated by the need for continuous real-time monitoring of possible leaks and mass flow measurement in the evaporative cooling systems of the ATLAS silicon trackers. The instruments use pairs of ultrasonic transducers transmitting sound bursts and measuring transit times in opposite directions. The gas flow rate is calculated from the difference in transit times, while the sound velocity is deduced from their average. The gas composition is then evaluated by comparison with a molar composition vs. sound velocity database, based on the direct dependence between sound velocity and component molar concentration in a gas mixture at a known temperature and pressure. The instrumentation has been developed in several geometries, with five instruments now integrated and in continuous operation within the ATLAS Detector Control System (DCS) and its finite state machine. One instrument monitors C3F8 coolant leaks into the Pixel detector N2 envelope with a molar resolution better than 2ṡ 10-5, and has indicated a level of 0.14 % when all the cooling loops of the recently re-installed Pixel detector are operational. Another instrument monitors air ingress into the C3F8 condenser of the new C3F8 thermosiphon coolant recirculator, with sub-percent precision. The recent effect of the introduction of a small quantity of N2 volume into the 9.5 m3 total volume of the thermosiphon system was clearly seen with this instrument. Custom microcontroller-based readout has been developed for the instruments, allowing readout into the ATLAS DCS via Modbus TCP/IP on Ethernet. The instrumentation has many potential applications where continuous binary gas composition is required, including in hydrocarbon and anaesthetic gas mixtures.

Method of introducing additive into a reaction gas flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Michelfelder, S.; Chughtai, M.Y.

1984-04-03

A method of continuously introducing additive, which is conveyed by gaseous and/or liquid carriers, into a turbulent reaction gas flow in the combustion chamber of a steam generator having dry ash withdrawal for selective removal, in a dry manner, of environmentally harmful gaseous noxious materials, such as sulfur, chlorine, and chlorine compounds, which are contained in a hot reaction gas flow which results after a complete or incomplete flame combustion of solid, liquid, or gaseous fuels. Depending upon the additive introduced, heat is stored and/or used for decomposition reactions. The additive, is first introduced at one or more input locations,more » due to locally different pressure conditions in the combustion chamber, into one or more recirculation flows which are within the system and are closed. The additive is subsequently withdrawn from these recirculation flows and is introduced into the reaction gas flow.« less

Gas liquid flow at microgravity conditions - Flow patterns and their transitions

NASA Technical Reports Server (NTRS)

Dukler, A. E.; Fabre, J. A.; Mcquillen, J. B.; Vernon, R.

1987-01-01

The prediction of flow patterns during gas-liquid flow in conduits is central to the modern approach for modeling two phase flow and heat transfer. The mechanisms of transition are reasonably well understood for flow in pipes on earth where it has been shown that body forces largely control the behavior observed. This work explores the patterns which exist under conditions of microgravity when these body forces are suppressed. Data are presented which were obtained for air-water flow in tubes during drop tower experiments and Learjet trajectories. Preliminary models to explain the observed flow pattern map are evolved.

DYNAMIC MODELING STRATEGY FOR FLOW REGIME TRANSITION IN GAS-LIQUID TWO-PHASE FLOWS

DOE Office of Scientific and Technical Information (OSTI.GOV)

X. Wang; X. Sun; H. Zhao

In modeling gas-liquid two-phase flows, the concept of flow regime has been used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are often flow regime dependent. Currently, the determination of the flow regimes is primarily based on flow regime maps or transition criteria, which are developed for steady-state, fully-developed flows and widely applied in nuclear reactor system safety analysis codes, such as RELAP5. As two-phase flows are observed to be dynamic in nature (fully-developed two-phase flows generally do notmore » exist in real applications), it is of importance to model the flow regime transition dynamically for more accurate predictions of two-phase flows. The present work aims to develop a dynamic modeling strategy for determining flow regimes in gas-liquid two-phase flows through the introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation and destruction of the interfacial area, such as the fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation; and fluid particle coalescence and condensation, respectively. For the flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shape (which are correlated), namely small bubbles and large bubbles. A preliminary approach to dynamically identifying the flow regimes is provided, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration of small bubble and large bubble groups. This method is expected to be applied to computer codes to improve their predictive capabilities of gas-liquid two-phase flows, in particular for the

Design and Uncertainty Analysis for a PVTt Gas Flow Standard

PubMed Central

Wright, John D.; Johnson, Aaron N.; Moldover, Michael R.

2003-01-01

A new pressure, volume, temperature, and, time (PVTt) primary gas flow standard at the National Institute of Standards and Technology has an expanded uncertainty (k = 2) of between 0.02 % and 0.05 %. The standard spans the flow range of 1 L/min to 2000 L/min using two collection tanks and two diverter valve systems. The standard measures flow by collecting gas in a tank of known volume during a measured time interval. We describe the significant and novel features of the standard and analyze its uncertainty. The gas collection tanks have a small diameter and are immersed in a uniform, stable, thermostatted water bath. The collected gas achieves thermal equilibrium rapidly and the uncertainty of the average gas temperature is only 7 mK (22 × 10−6 T). A novel operating method leads to essentially zero mass change in and very low uncertainty contributions from the inventory volume. Gravimetric and volume expansion techniques were used to determine the tank and the inventory volumes. Gravimetric determinations of collection tank volume made with nitrogen and argon agree with a standard deviation of 16 × 10−6 VT. The largest source of uncertainty in the flow measurement is drift of the pressure sensor over time, which contributes relative standard uncertainty of 60 × 10−6 to the determinations of the volumes of the collection tanks and to the flow measurements. Throughout the range 3 L/min to 110 L/min, flows were measured independently using the 34 L and the 677 L collection systems, and the two systems agreed within a relative difference of 150 × 10−6. Double diversions were used to evaluate the 677 L system over a range of 300 L/min to 1600 L/min, and the relative differences between single and double diversions were less than 75 × 10−6. PMID:27413592

Magnetic roller gas gate employing transonic sweep gas flow to isolate regions of differing gaseous composition or pressure

DOEpatents

Doehler, Joachim

1994-12-20

Disclosed herein is an improved gas gate for interconnecting regions of differing gaseous composition and/or pressure. The gas gate includes a narrow, elongated passageway through which substrate material is adapted to move between said regions and inlet means for introducing a flow of non-contaminating sweep gas into a central portion of said passageway. The gas gate is characterized in that the height of the passageway and the flow rate of the sweep gas therethrough provides for transonic flow of the sweep gas between the inlet means and at least one of the two interconnected regions, thereby effectively isolating one region, characterized by one composition and pressure, from another region, having a differing composition and/or pressure, by decreasing the mean-free-path length between collisions of diffusing species within the transonic flow region. The gas gate preferably includes a manifold at the juncture point where the gas inlet means and the passageway interconnect.

Klinkenberg effect in hydrodynamics of gas flow through anisotropic porous materials

NASA Astrophysics Data System (ADS)

Wałowski, Grzegorz; Filipczak, Gabriel

2017-10-01

This study discusses results of experiments on hydrodynamic assessment of gas flow through backbone (skeletal) porous materials with an anisotropic structure. The research was conducted upon materials of diversified petrographic characteristics, both natural origin (rocky, pumice) and process materials (char and coke). The study was conducted for a variety of hydrodynamic conditions, using air, as well as for nitrogen and carbon dioxide. The basis for assessing hydrodynamics of gas flow through porous material was a gas stream that results from the pressure forcing such flow. The results of measurements indicate a clear impact of the type of material on the gas permeability, and additionally - as a result of their anisotropic internal structure - to a significant effect of the flow direction on the value of gas stream.

Generalized second-order slip boundary condition for nonequilibrium gas flows

NASA Astrophysics Data System (ADS)

Guo, Zhaoli; Qin, Jishun; Zheng, Chuguang

2014-01-01

It is a challenging task to model nonequilibrium gas flows within a continuum-fluid framework. Recently some extended hydrodynamic models in the Navier-Stokes formulation have been developed for such flows. A key problem in the application of such models is that suitable boundary conditions must be specified. In the present work, a generalized second-order slip boundary condition is developed in which an effective mean-free path considering the wall effect is used. By combining this slip scheme with certain extended Navier-Stokes constitutive relation models, we obtained a method for nonequilibrium gas flows with solid boundaries. The method is applied to several rarefied gas flows involving planar or curved walls, including the Kramers' problem, the planar Poiseuille flow, the cylindrical Couette flow, and the low speed flow over a sphere. The results show that the proposed method is able to give satisfied predictions, indicating the good potential of the method for nonequilibrium flows.

Enhanced ozone production in a pulsed dielectric barrier discharge plasma jet with addition of argon to a He-O2 flow gas

NASA Astrophysics Data System (ADS)

Sands, Brian; Ganguly, Biswa; Scofield, James

2013-09-01

Ozone production in a plasma jet DBD driven with a 20-ns risetime unipolar pulsed voltage can be significantly enhanced using helium as the primary flow gas with an O2 coflow. The overvolted discharge can be sustained with up to a 5% O2 coflow at <20 kHz pulse repetition frequency at 13 kV applied voltage. Ozone production scales with the pulse repetition frequency up to a ``turnover frequency'' that depends on the O2 concentration, total gas flow rate, and applied voltage. For example, peak ozone densities >1016 cm-3 were measured with 3% O2 admixture and <3 W input power at a 12 kHz turnover frequency. A further increase in the repetition frequency results in increased discharge current and 777 nm O(5 P) emission, but decreased ozone production and is followed by a transition to a filamentary discharge mode. The addition of argon at concentrations >=5% reduces the channel conductivity and shifts the turnover frequency to higher frequencies. This results in increased ozone production for a given applied voltage and gas flow rate. Time-resolved Ar(1s5) and He(23S1) metastable densities were acquired along with discharge current and ozone density measurements to gain insight into the mechanisms of optimum ozone production.

Sterilization/disinfection of medical devices using plasma: the flowing afterglow of the reduced-pressure N2-O2 discharge as the inactivating medium

NASA Astrophysics Data System (ADS)

Moisan, Michel; Boudam, Karim; Carignan, Denis; Kéroack, Danielle; Levif, Pierre; Barbeau, Jean; Séguin, Jacynthe; Kutasi, Kinga; Elmoualij, Benaïssa; Thellin, Olivier; Zorzi, Willy

2013-07-01

Potential sterilization/disinfection of medical devices (MDs) is investigated using a specific plasma process developed at the Université de Montréal over the last decade. The inactivating medium of the microorganisms is the flowing afterglow of a reduced-pressure N2-O2 discharge, which provides, as the main biocidal agent, photons over a broad ultraviolet (UV) wavelength range. The flowing afterglow is considered less damaging to MDs than the discharge itself. Working at gas pressures in the 400—700 Pa range (a few torr) ensures, through species diffusion, the uniform filling of large volume chambers with the species outflowing from the discharge, possibly allowing batch processing within them. As a rule, bacterial endospores are used as bio-indicators (BI) to validate sterilization processes. Under the present operating conditions, Bacillus atrophaeus is found to be the most resistant one and is therefore utilized as BI. The current paper reviews the main experimental results concerning the operation and characterization of this sterilizer/disinfector, updating and completing some of our previously published papers. It uses modeling results as guidelines, which are particularly useful when the corresponding experimental data are not (yet) available, hopefully leading to more insight into this plasma afterglow system. The species flowing out of the N2-O2 discharge can be divided into two groups, depending on the time elapsed after they left the discharge zone as they move toward the chamber, namely the early afterglow and the late afterglow. The early flowing afterglow from a pure N2 discharge (also called pink afterglow) is known to be comprised of N2+ and N4+ ions. In the present N2-O2 mixture discharge, NO+ ions are additionally generated, with a lifetime that extends over a longer period than that of the nitrogen molecular ions. We shall suppose that the disappearance of the NO+ ions marks the end of the early afterglow regime, thereby stressing our intent

40 CFR 92.117 - Gas meter or flow instrumentation calibration, particulate measurement.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Gas meter or flow instrumentation... ENGINES Test Procedures § 92.117 Gas meter or flow instrumentation calibration, particulate measurement. (a) Sampling for particulate emissions requires the use of gas meters or flow instrumentation to...

40 CFR 92.117 - Gas meter or flow instrumentation calibration, particulate measurement.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 20 2014-07-01 2013-07-01 true Gas meter or flow instrumentation... ENGINES Test Procedures § 92.117 Gas meter or flow instrumentation calibration, particulate measurement. (a) Sampling for particulate emissions requires the use of gas meters or flow instrumentation to...

40 CFR 92.117 - Gas meter or flow instrumentation calibration, particulate measurement.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 21 2012-07-01 2012-07-01 false Gas meter or flow instrumentation... ENGINES Test Procedures § 92.117 Gas meter or flow instrumentation calibration, particulate measurement. (a) Sampling for particulate emissions requires the use of gas meters or flow instrumentation to...

40 CFR 92.117 - Gas meter or flow instrumentation calibration, particulate measurement.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 21 2013-07-01 2013-07-01 false Gas meter or flow instrumentation... ENGINES Test Procedures § 92.117 Gas meter or flow instrumentation calibration, particulate measurement. (a) Sampling for particulate emissions requires the use of gas meters or flow instrumentation to...

40 CFR 92.117 - Gas meter or flow instrumentation calibration, particulate measurement.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Gas meter or flow instrumentation... ENGINES Test Procedures § 92.117 Gas meter or flow instrumentation calibration, particulate measurement. (a) Sampling for particulate emissions requires the use of gas meters or flow instrumentation to...

[Removal of CO2 from simulated flue gas of power plants by membrane-based gas absorption processes].

PubMed

Yang, Ming-Fen; Fang, Meng-Xiang; Zhang, Wei-Feng; Wang, Shu-Yuan; Xu, Zhi-Kang; Luo, Zhong-Yang; Cen, Ke-Fa

2005-07-01

Three typical absorbents such as aqueous of aminoacetic acid potassium (AAAP), monoethanolamine (MEA) and methyldiethanolamine(MDEA) are selected to investigate the performance of CO2 separation from flue gas via membrane contactors made of hydrophobic hollow fiber polypropylene porous membrane. Impacts of absorbents, concentrations and flow rates of feeding gas and absorbent solution, cyclic loading of CO2 on the removal rate and the mass transfer velocity of CO2 are discussed. The results demonstrate that the mass transfer velocity was 7.1 mol x (m2 x s)(-1) for 1 mol x L(-1) MEA with flow rate of 0.1 m x s(-1) and flue gas with that of 0.211 m x s(-1). For 1 mol L(-1) AAAP with flow rate of 0.05 m x s(-1) and flue gas of 0.211 m x s(-1), CO2 removal rate (eta) was 93.2 % and eta was 98% for 4 mol x L(-1) AAAP under the same conditions. AAAP being absorbent, eta was higher than 90% in a wider range of concentrations of CO2. It indicates that membrane-based absorption process is a widely-applied and promising way of CO2 removal from flue gas of power plants, which not only appropriates for CO2 removal of flue gas of widely-used PF and NGCC, but also for that of flue gas of IGCC can be utilized widely in future.

Device accurately measures and records low gas-flow rates

NASA Technical Reports Server (NTRS)

Branum, L. W.

1966-01-01

Free-floating piston in a vertical column accurately measures and records low gas-flow rates. The system may be calibrated, using an adjustable flow-rate gas supply, a low pressure gage, and a sequence recorder. From the calibration rates, a nomograph may be made for easy reduction. Temperature correction may be added for further accuracy.

Noble gas loss may indicate groundwater flow across flow barriers in southern Nevada

USGS Publications Warehouse

Thomas, J.M.; Bryant, Hudson G.; Stute, M.; Clark, J.F.

2003-01-01

Average calculated noble gas temperatures increase from 10 to 22oC in groundwater from recharge to discharge areas in carbonate-rock aquifers of southern Nevada. Loss of noble gases from groundwater in these regional flow systems at flow barriers is the likely process that produces an increase in recharge noble gas temperatures. Emplacement of low permeability rock into high permeability aquifer rock and the presence of low permeability shear zones reduce aquifer thickness from thousands to tens of meters. At these flow barriers, which are more than 1,000 m lower than the average recharge altitude, noble gases exsolve from the groundwater by inclusion in gas bubbles formed near the barriers because of greatly reduced hydrostatic pressure. However, re-equilibration of noble gases in the groundwater with atmospheric air at the low altitude spring discharge area, at the terminus of the regional flow system, cannot be ruled out. Molecular diffusion is not an important process for removing noble gases from groundwater in the carbonate-rock aquifers because concentration gradients are small.

Stability of Gas Hydrates on Continental Margins: Implications of Subsurface Fluid Flow

NASA Astrophysics Data System (ADS)

Nunn, J. A.

2008-12-01

Gas hydrates are found at or just below the sediment-ocean interface in continental margins settings throughout the world. They are also found on land in high latitude regions such as the north slope of Alaska. While gas hydrate occurrence is common, gas hydrates are stable under a fairly restricted range of temperatures and pressures. In a purely conductive thermal regime, near surface temperatures depend on basal heat flow, thermal conductivity of sediments, and temperature at the sediment-water or sediment-air interface. Thermal conductivity depends on porosity and sediment composition. Gas hydrates are most stable in areas of low heat flow and high thermal conductivity which produce low temperature gradients. Older margins with thin continental crust and coarse grained sediments would tend to be colder. Another potentially important control on subsurface temperatures is advective heat transport by recharge/discharge of groundwater. Upward fluid flow depresses temperature gradients over a purely conductive regime with the same heat flow which would make gas hydrates more stable. Downward fluid flow would have the opposite effect. However, regional scale fluid flow may substantially increase heat flow in discharge areas which would destabilize gas hydrates. For example, discharge of topographically driven groundwater along the coast in the Central North Slope of Alaska has increased surface heat flow in some areas by more than 50% over a purely conductive thermal regime. Fluid flow also alters the pressure regime which can affect gas hydrate stability. Modeling results suggest a positive feedback between gas hydrate formation/disassociation and fluid flow. Disassociation of gas hydrates or permafrost due to global warming could increase permeability. This could enhance fluid flow and associated heat transport causing a more rapid and/or more spatially extensive gas hydrate disassociation than predicted solely from conductive propagation of temporal changes in

Flux flow induced microwave absorption in high temperature superconductor Bi 2-XPb XSr 2Ca N-1Cu NO 4+2N

NASA Astrophysics Data System (ADS)

Owens, F. J.

1990-12-01

Direct measurements of microwave absorption without use of rf H field modulation in granular composites of the 115 K superconductor Bi 2-XPb XSr 2Ca N-1Cu NO 4+2N as a function of magnetic field above 0.1 T reveal a continuing increase of absorption of microwave energy increasing magnetic field. The temperature and magnetic field dependence of the absorption are very different from the low magnetic field (<0.01 T) absorption arising from weak links in the material. The magnetic field and temperature dependence are consistent with the behavior of thermally activated flux flow resistance suggesting the absorption is due to flux creep.

Numerical Simulation of Multiphase Flow in Nanoporous Organic Matter With Application to Coal and Gas Shale Systems

NASA Astrophysics Data System (ADS)

Song, Wenhui; Yao, Jun; Ma, Jingsheng; Sun, Hai; Li, Yang; Yang, Yongfei; Zhang, Lei

2018-02-01

Fluid flow in nanoscale organic pores is known to be affected by fluid transport mechanisms and properties within confined pore space. The flow of gas and water shows notably different characteristics compared with conventional continuum modeling approach. A pore network flow model is developed and implemented in this work. A 3-D organic pore network model is constructed from 3-D image that is reconstructed from 2-D shale SEM image of organic-rich sample. The 3-D pore network model is assumed to be gas-wet and to contain initially gas-filled pores only, and the flow model is concerned with drainage process. Gas flow considers a full range of gas transport mechanisms, including viscous flow, Knudsen diffusion, surface diffusion, ad/desorption, and gas PVT and viscosity using a modified van der Waals' EoS and a correlation for natural gas, respectively. The influences of slip length, contact angle, and gas adsorption layer on water flow are considered. Surface tension considers the pore size and temperature effects. Invasion percolation is applied to calculate gas-water relative permeability. The results indicate that the influences of pore pressure and temperature on water phase relative permeabilities are negligible while gas phase relative permeabilities are relatively larger in higher temperatures and lower pore pressures. Gas phase relative permeability increases while water phase relative permeability decreases with the shrinkage of pore size. This can be attributed to the fact that gas adsorption layer decreases the effective flow area of the water phase and surface diffusion capacity for adsorbed gas is enhanced in small pore size.

Efficient Boron Nitride Nanotube Formation via Combined Laser-Gas Flow Levitation

NASA Technical Reports Server (NTRS)

Whitney, R. Roy (Inventor); Jordan, Kevin (Inventor); Smith, Michael W. (Inventor)

2014-01-01

A process for producing boron nitride nanotubes and/or boron-carbon-nitrogen nanotubes of the general formula B(sub x)C(sub y)N(sub z) The process utilizes a combination of laser light and nitrogen gas flow to support a boron ball target during heating of the boron ball target and production of a boron vapor plume which reacts with nitrogen or nitrogen and carbon to produce boron nitride nanotubes and/or boron-carbon-nitrogen nanotubes of the general formula B(sub x)C(sub y)N(sub z).

Efficient boron nitride nanotube formation via combined laser-gas flow levitation

DOEpatents

Whitney, R. Roy; Jordan, Kevin; Smith, Michael

2014-03-18

A process for producing boron nitride nanotubes and/or boron-carbon-nitrogen nanotubes of the general formula B.sub.xC.sub.yN.sub.z. The process utilizes a combination of laser light and nitrogen gas flow to support a boron ball target during heating of the boron ball target and production of a boron vapor plume which reacts with nitrogen or nitrogen and carbon to produce boron nitride nanotubes and/or boron-carbon-nitrogen nanotubes of the general formula B.sub.xC.sub.yN.sub.z.

Determination of gas & liquid two-phase flow regime transitions in wellbore annulus by virtual mass force coefficient when gas cut

NASA Astrophysics Data System (ADS)

Qu, Junbo; Yan, Tie; Sun, Xiaofeng; Chen, Ye; Pan, Yi

2017-10-01

With the development of drilling technology to deeper stratum, overflowing especially gas cut occurs frequently, and then flow regime in wellbore annulus is from the original drilling fluid single-phase flow into gas & liquid two-phase flow. By using averaged two-fluid model equations and the basic principle of fluid mechanics to establish the continuity equations and momentum conservation equations of gas phase & liquid phase respectively. Relationship between pressure and density of gas & liquid was introduced to obtain hyperbolic equation, and get the expression of the dimensionless eigenvalue of the equation by using the characteristic line method, and analyze wellbore flow regime to get the critical gas content under different virtual mass force coefficients. Results show that the range of equation eigenvalues is getting smaller and smaller with the increase of gas content. When gas content reaches the critical point, the dimensionless eigenvalue of equation has no real solution, and the wellbore flow regime changed from bubble flow to bomb flow. When virtual mass force coefficients are 0.50, 0.60, 0.70 and 0.80 respectively, the critical gas contents are 0.32, 0.34, 0.37 and 0.39 respectively. The higher the coefficient of virtual mass force, the higher gas content in wellbore corresponding to the critical point of transition flow regime, which is in good agreement with previous experimental results. Therefore, it is possible to determine whether there is a real solution of the dimensionless eigenvalue of equation by virtual mass force coefficient and wellbore gas content, from which we can obtain the critical condition of wellbore flow regime transformation. It can provide theoretical support for the accurate judgment of the annular flow regime.

A novel pump-driven veno-venous gas exchange system during extracorporeal CO2-removal.

PubMed

Hermann, Alexander; Riss, Katharina; Schellongowski, Peter; Bojic, Andja; Wohlfarth, Philipp; Robak, Oliver; Sperr, Wolfgang R; Staudinger, Thomas

2015-10-01

Pump-driven veno-venous extracorporeal CO2-removal (ECCO2-R) increasingly takes root in hypercapnic lung failure to minimize ventilation invasiveness or to avoid intubation. A recently developed device (iLA activve(®), Novalung, Germany) allows effective decarboxylation via a 22 French double lumen cannula. To assess determinants of gas exchange, we prospectively evaluated the performance of ECCO2-R in ten patients receiving iLA activve(®) due to hypercapnic respiratory failure. Sweep gas flow was increased in steps from 1 to 14 L/min at constant blood flow (phase 1). Similarly, blood flow was gradually increased at constant sweep gas flow (phase 2). At each step gas transfer via the membrane as well as arterial blood gas samples were analyzed. During phase 1, we observed a significant increase in CO2 transfer together with a decrease in PaCO2 levels from a median of 66 mmHg (range 46-85) to 49 (31-65) mmHg from 1 to 14 L/min sweep gas flow (p < 0.0001), while arterial oxygenation deteriorated with high sweep gas flow rates. During phase 2, oxygen transfer significantly increased leading to an increase in PaO2 from 67 (49-87) at 0.5 L/min to 117 (66-305) mmHg at 2.0 L/min (p < 0.0001). Higher blood flows also significantly enhanced decarboxylation (p < 0.0001). Increasing sweep gas flow results in effective CO2-removal, which can be further reinforced by raising blood flow. The clinically relevant oxygenation effect in this setting could broaden the range of indications of the system and help to set up an individually tailored configuration.

Comprehensive two-dimensional gas chromatography using partial modulation via a pulsed flow valve with a short modulation period.

PubMed

Freye, Chris E; Bahaghighat, H Daniel; Synovec, Robert E

2018-01-15

Partial modulation via a pulsed flow valve for comprehensive two-dimensional (2D) gas chromatography (GC × GC) is demonstrated, producing narrow peak widths, 2 W b , on the secondary separation dimension, 2 D, coupled with short modulation periods, P M , thus producing a high peak capacity on the 2 D dimension, 2 n c . The GC × GC modulator is a pulse flow valve that injects a pulse of carrier gas at the specified P M , at the connection between the primary, 1 D, column and the 2 D column. Using a commercially available pulse flow valve, this injection technique performs a combination of vacancy chromatography and frontal analysis, whereby each pulse disturbance in the analyte concentration profile as it exits the 1 D column results in data that is readily converted into a 2 D separation. A three-step process converts the raw data into a format analogous to a GC × GC separation, incorporating signal differentiation, baseline correction and conversion to a GC × GC chromatogram representation. A 115-component test mixture with a wide range of boiling points (36-372°C) of nine compound classes is demonstrated using modulation periods of P M = 50, 100, 250, and 500ms, respectively. For the test mixture with a P M of 250ms, peak shapes on 2 D are symmetric with apparent 2 W b ranging from 12 to 45ms producing a 2 n c of ~ 10. Based on the average peak width of 0.93s on the 1 D separation for a time window of 400s, the 1 D peak capacity is 1 n c ∼ 430. Thus, the ideal 2D peak capacity n c,2D is 4300 or a peak capacity production of 650 peaks/min using the P M of 250ms. Additionally, for a P M of 50, 100 and 500ms, the 2 n c are 4, 7, and 12, respectively. Retention times on 2 D, 2 t R , are reproducible having standard deviations less than 1ms. Finally, the processed data is shown to be quantitative, with an average RSD of 4.7% for test analytes. Copyright © 2017 Elsevier B.V. All rights reserved.

Gas-liquid-liquid three-phase flow pattern and pressure drop in a microfluidic chip: similarities with gas-liquid/liquid-liquid flows.

PubMed

Yue, Jun; Rebrov, Evgeny V; Schouten, Jaap C

2014-05-07

We report a three-phase slug flow and a parallel-slug flow as two major flow patterns found under the nitrogen-decane-water flow through a glass microfluidic chip which features a long microchannel with a hydraulic diameter of 98 μm connected to a cross-flow mixer. The three-phase slug flow pattern is characterized by a flow of decane droplets containing single elongated nitrogen bubbles, which are separated by water slugs. This flow pattern was observed at a superficial velocity of decane (in the range of about 0.6 to 10 mm s(-1)) typically lower than that of water for a given superficial gas velocity in the range of 30 to 91 mm s(-1). The parallel-slug flow pattern is characterized by a continuous water flow in one part of the channel cross section and a parallel flow of decane with dispersed nitrogen bubbles in the adjacent part of the channel cross section, which was observed at a superficial velocity of decane (in the range of about 2.5 to 40 mm s(-1)) typically higher than that of water for each given superficial gas velocity. The three-phase slug flow can be seen as a superimposition of both decane-water and nitrogen-decane slug flows observed in the chip when the flow of the third phase (viz. nitrogen or water, respectively) was set at zero. The parallel-slug flow can be seen as a superimposition of the decane-water parallel flow and the nitrogen-decane slug flow observed in the chip under the corresponding two-phase flow conditions. In case of small capillary numbers (Ca ≪ 0.1) and Weber numbers (We ≪ 1), the developed two-phase pressure drop model under a slug flow has been extended to obtain a three-phase slug flow model in which the 'nitrogen-in-decane' droplet is assumed as a pseudo-homogeneous droplet with an effective viscosity. The parallel flow and slug flow pressure drop models have been combined to obtain a parallel-slug flow model. The obtained models describe the experimental pressure drop with standard deviations of 8% and 12% for the

Interannual Variability in Soil Trace Gas (CO2, N2O, NO) Fluxes and Analysis of Controllers

NASA Technical Reports Server (NTRS)

Potter, C.; Klooster, S.; Peterson, David L. (Technical Monitor)

1997-01-01

Interannual variability in flux rates of biogenic trace gases must be quantified in order to understand the differences between short-term trends and actual long-term change in biosphere-atmosphere interactions. We simulated interannual patterns (1983-1988) of global trace gas fluxes from soils using the NASA Ames model version of CASA (Carnegie-Ames-Stanford Approach) in a transient simulation mode. This ecosystem model has been recalibrated for simulations driven by satellite vegetation index data from the NOAA Advanced Very High Resolution Radiometer (AVHRR) over the mid-1980s. The predicted interannual pattern of soil heterotropic CO2 emissions indicates that relatively large increases in global carbon flux from soils occurred about three years following the strong El Nino Southern Oscillation (ENSO) event of 1983. Results for the years 1986 and 1987 showed an annual increment of +1 Pg (1015 g) C-CO2 emitted from soils, which tended to dampen the estimated global increase in net ecosystem production with about a two year lag period relative to plant carbon fixation. Zonal discrimination of model results implies that 80-90 percent of the yearly positive increments in soil CO2 emission during 1986-87 were attributable to soil organic matter decomposition in the low-latitudes (between 30 N and 30 S). Soils of the northern middle-latitude zone (between 30 N and 60 N) accounted for the residual of these annual increments. Total annual emissions of nitrogen trace gases (N2O and NO) from soils were estimated to vary from 2-4 percent over the time period modeled, a level of variability which is consistent with predicted interannual fluctuations in global soil CO2 fluxes. Interannual variability of precipitation in tropical and subtropical zones (30 N to 20 S appeared to drive the dynamic inverse relationship between higher annual emissions of NO versus emissions of N2O. Global mean emission rates from natural (heterotrophic) soil sources over the period modeled (1983

Multiphase flowmeter successfully measures three-phase flow at extremely high gas-volume fractions -- Gulf of Suez, Egypt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leggett, R.B.; Borling, D.C.; Powers, B.S.

1998-02-01

A multiphase flowmeter (MPFM) installed in offshore Egypt has accurately measured three-phase flow in extremely gassy flow conditions. The meter is completely nonintrusive, with no moving parts, requires no flow mixing before measurement, and has no bypass loop to remove gas before multiphase measurement. Flow regimes observed during the field test of this meter ranged from severe slugging to annular flow caused by the dynamics of gas-lift gas in the production stream. Average gas-volume fraction ranged from 93 to 98% during tests conducted on seven wells. The meter was installed in the Gulf of Suez on a well protector platformmore » in the Gulf of Suez Petroleum Co. (Gupco) October field, and was placed in series with a test separator located on a nearby production platform. Wells were individually tested with flow conditions ranging from 1,300 to 4,700 B/D fluid, 2.4 to 3.9 MMscf/D of gas, and water cuts from 1 to 52%. The meter is capable of measuring water cuts up to 100%. Production was routed through both the MPFM and the test separator simultaneously as wells flowed with the assistance of gas-lift gas. The MPFM measured gas and liquid rates to within {+-} 10% of test-separator reference measurement flow rates, and accomplished this at gas-volume fractions from 93 to 96%. At higher gas-volume fractions up to 98%, accuracy deteriorated but the meter continued to provide repeatable results.« less

Measurement of Gas-Liquid Two-Phase Flow in Micro-Pipes by a Capacitance Sensor

PubMed Central

Ji, Haifeng; Li, Huajun; Huang, Zhiyao; Wang, Baoliang; Li, Haiqing

2014-01-01

A capacitance measurement system is developed for the measurement of gas-liquid two-phase flow in glass micro-pipes with inner diameters of 3.96, 2.65 and 1.56 mm, respectively. As a typical flow regime in a micro-pipe two-phase flow system, slug flow is chosen for this investigation. A capacitance sensor is designed and a high-resolution and high-speed capacitance measurement circuit is used to measure the small capacitance signals based on the differential sampling method. The performance and feasibility of the capacitance method are investigated and discussed. The capacitance signal is analyzed, which can reflect the voidage variation of two-phase flow. The gas slug velocity is determined through a cross-correlation technique using two identical capacitance sensors. The simulation and experimental results show that the presented capacitance measurement system is successful. Research work also verifies that the capacitance sensor is an effective method for the measurement of gas liquid two-phase flow parameters in micro-pipes. PMID:25587879

Measurement of gas-liquid two-phase flow in micro-pipes by a capacitance sensor.

PubMed

Ji, Haifeng; Li, Huajun; Huang, Zhiyao; Wang, Baoliang; Li, Haiqing

2014-11-26

A capacitance measurement system is developed for the measurement of gas-liquid two-phase flow in glass micro-pipes with inner diameters of 3.96, 2.65 and 1.56 mm, respectively. As a typical flow regime in a micro-pipe two-phase flow system, slug flow is chosen for this investigation. A capacitance sensor is designed and a high-resolution and high-speed capacitance measurement circuit is used to measure the small capacitance signals based on the differential sampling method. The performance and feasibility of the capacitance method are investigated and discussed. The capacitance signal is analyzed, which can reflect the voidage variation of two-phase flow. The gas slug velocity is determined through a cross-correlation technique using two identical capacitance sensors. The simulation and experimental results show that the presented capacitance measurement system is successful. Research work also verifies that the capacitance sensor is an effective method for the measurement of gas liquid two-phase flow parameters in micro-pipes.

Time distribution of adsorption entropy of gases on heterogeneous surfaces by reversed-flow gas chromatography.

PubMed

Katsanos, Nicholas A; Kapolos, John; Gavril, Dimitrios; Bakaoukas, Nicholas; Loukopoulos, Vassilios; Koliadima, Athanasia; Karaiskakis, George

2006-09-15

The reversed-flow gas chromatography (RF-GC) technique has been applied to measure the adsorption entropy over time, when gaseous pentane is adsorbed on the surface of two solids (gamma-alumina and a silica supported rhodium catalyst) at 393.15 and 413.15K, respectively. Utilizing experimental chromatographic data, this novel methodology also permits the simultaneous measurement of the local adsorption energy, epsilon, local equilibrium adsorbed concentration, c(s)(*), and local adsorption isotherm, theta(p, T, epsilon) in a time resolved way. In contrast with other inverse gas chromatographic methods, which determine the standard entropy at zero surface coverage, the present method operates over a wide range of surface coverage taking into account not only the adsorbate-adsorbent interaction, but also the adsorbate-adsorbate interaction. One of the most interesting observations of the present work is the fact that the interaction of n-pentane is spontaneous on the Rh/SiO(2) catalyst for a very short time interval compared to that on gamma-Al(2)O(3). This can explain the different kinetic behavior of each particular gas-solid system, and it can be attributed to the fact that large amounts of n-C(5)H(12) are present on the active sites of the Rh/SiO(2) catalyst compared to those on gamma-Al(2)O(3), as the local equilibrium adsorbed concentration values, c(s)(*), indicate.

Numerical Analysis of Dusty-Gas Flows

NASA Astrophysics Data System (ADS)

Saito, T.

2002-02-01

This paper presents the development of a numerical code for simulating unsteady dusty-gas flows including shock and rarefaction waves. The numerical results obtained for a shock tube problem are used for validating the accuracy and performance of the code. The code is then extended for simulating two-dimensional problems. Since the interactions between the gas and particle phases are calculated with the operator splitting technique, we can choose numerical schemes independently for the different phases. A semi-analytical method is developed for the dust phase, while the TVD scheme of Harten and Yee is chosen for the gas phase. Throughout this study, computations are carried out on SGI Origin2000, a parallel computer with multiple of RISC based processors. The efficient use of the parallel computer system is an important issue and the code implementation on Origin2000 is also described. Flow profiles of both the gas and solid particles behind the steady shock wave are calculated by integrating the steady conservation equations. The good agreement between the pseudo-stationary solutions and those from the current numerical code validates the numerical approach and the actual coding. The pseudo-stationary shock profiles can also be used as initial conditions of unsteady multidimensional simulations.

Electron energy deposition in N2 gas

NASA Technical Reports Server (NTRS)

Fox, J. L.; Victor, G. A.

1988-01-01

The processes by which energetic electrons lose energy in a weakly ionized gas of molecular nitrogen are analyzed and calculations are carried out taking into account the discrete nature of the excitation processes. The excitation, ionization, dissociation and heating efficiencies are computed for energies up to 200 eV absorbed in a gas with fractional ionizations varying from 10(-6) to 10(-2). Individual vibrational excitations up to the seventh vibrational level are presented.

Structural isomers of C2N(+) - A selected-ion flow tube study

NASA Technical Reports Server (NTRS)

Knight, J. S.; Petrie, S. A. H.; Freeman, C. G.; Mcewan, M. J.; Mclean, A. D.

1988-01-01

Reactivities of the structural isomers CCN(+) and CNC(+) were examined in a selected-ion flow tube at 300 + or - 5 K. The less reactive CNC(+) isomer was identified as the product of the reactions of C(+) + HCN and C(+) + C2N2; in these reactions only CNC(+) can be produced because of energy constraints. Rate coefficients and branching ratios are reported for the reactions of each isomer with H2, CH4, NH3, H2O, C2H2, HCN, N2, O2, N2O, and CO2. Ab initio calculations are presented for CCN(+) and CNC(+); a saddle point for the reaction CCN(+) yielding CNC(+) is calculated to be 195 kJ/mol above CNC(+). The results provide evidence that the more reactive CCN(+) isomer is unlikely to be present in measurable densities in interstellar clouds.

Propagation characteristics of pulverized coal and gas two-phase flow during an outburst.

PubMed

Zhou, Aitao; Wang, Kai; Fan, Lingpeng; Tao, Bo

2017-01-01

Coal and gas outbursts are dynamic failures that can involve the ejection of thousands tons of pulverized coal, as well as considerable volumes of gas, into a limited working space within a short period. The two-phase flow of gas and pulverized coal that occurs during an outburst can lead to fatalities and destroy underground equipment. This article examines the interaction mechanism between pulverized coal and gas flow. Based on the role of gas expansion energy in the development stage of outbursts, a numerical simulation method is proposed for investigating the propagation characteristics of the two-phase flow. This simulation method was verified by a shock tube experiment involving pulverized coal and gas flow. The experimental and simulated results both demonstrate that the instantaneous ejection of pulverized coal and gas flow can form outburst shock waves. These are attenuated along the propagation direction, and the volume fraction of pulverized coal in the two-phase flow has significant influence on attenuation of the outburst shock wave. As a whole, pulverized coal flow has a negative impact on gas flow, which makes a great loss of large amounts of initial energy, blocking the propagation of gas flow. According to comparison of numerical results for different roadway types, the attenuation effect of T-type roadways is best. In the propagation of shock wave, reflection and diffraction of shock wave interact through the complex roadway types.

Propagation characteristics of pulverized coal and gas two-phase flow during an outburst

PubMed Central

Zhou, Aitao; Wang, Kai; Fan, Lingpeng; Tao, Bo

2017-01-01

Coal and gas outbursts are dynamic failures that can involve the ejection of thousands tons of pulverized coal, as well as considerable volumes of gas, into a limited working space within a short period. The two-phase flow of gas and pulverized coal that occurs during an outburst can lead to fatalities and destroy underground equipment. This article examines the interaction mechanism between pulverized coal and gas flow. Based on the role of gas expansion energy in the development stage of outbursts, a numerical simulation method is proposed for investigating the propagation characteristics of the two-phase flow. This simulation method was verified by a shock tube experiment involving pulverized coal and gas flow. The experimental and simulated results both demonstrate that the instantaneous ejection of pulverized coal and gas flow can form outburst shock waves. These are attenuated along the propagation direction, and the volume fraction of pulverized coal in the two-phase flow has significant influence on attenuation of the outburst shock wave. As a whole, pulverized coal flow has a negative impact on gas flow, which makes a great loss of large amounts of initial energy, blocking the propagation of gas flow. According to comparison of numerical results for different roadway types, the attenuation effect of T-type roadways is best. In the propagation of shock wave, reflection and diffraction of shock wave interact through the complex roadway types. PMID:28727738

Gas-Liquid Flow in Pipelines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thomas J. Hanratty

A research program was carried out at the University of Illinois in which develops a scientific approach to gas-liquid flows that explains their macroscopic behavior in terms of small scale interactions. For simplicity, fully-developed flows in horizontal and near-horizontal pipes. The difficulty in dealing with these flows is that the phases can assume a variety of configurations. The specific goal was to develop a scientific understanding of transitions from one flow regime to another and a quantitative understanding of how the phases distribute for a give regime. These basic understandings are used to predict macroscopic quantities of interest, such asmore » frictional pressure drop, liquid hold-up, entrainment in annular flow and frequency of slugging in slug flows. A number of scientific issues are addressed. Examples are the rate of atomization of a liquid film, the rate of deposition of drops, the behavior of particles in a turbulent field, the generation and growth of interfacial waves. The use of drag-reducing polymers that change macroscopic behavior by changing small scale interactions was explored.« less

Numerical modeling of Stokes flows over a superhydrophobic surface containing gas bubbles

NASA Astrophysics Data System (ADS)

Ageev, A. I.; Golubkina, I. V.; Osiptsov, A. N.

2017-10-01

This paper continues the numerical modeling of Stokes flows near cavities of a superhydrophobic surface, occupied by gas bubbles, based on the Boundary Element Method (BEM). The aim of the present study is to estimate the friction reduction (pressure drop) in a microchannel with a bottom superhydrophobic surface, the texture of which is formed by a periodic system of striped rectangular microcavities containing compressible gas bubbles. The model proposed takes into account the streamwise variation of the bubble shift into the cavities, caused by the longitudinal pressure gradient in the channel flow. The solution for the macroscopic (averaged) flow in the microchannel, constructed using an effective slip boundary condition on the superhydrophobic bottom wall, is matched with the solution of the Stokes problem at the microscale of a single cavity containing a gas bubble. The 2D Stokes problems of fluid flow over single cavities containing curved phase interfaces with the condition of zero shear stress are reduced to the boundary integral equations which are solved using the BEM method.

Numerical Prediction of Radiation Measurements Taken in the X2 Facility for Mars and Titan Gas Mixtures

NASA Technical Reports Server (NTRS)

Palmer, Grant; Prabhu, Dinesh; Brandis, Aaron; McIntyre, Timothy J.

2011-01-01

Thermochemical relaxation behind a normal shock in Mars and Titan gas mixtures is simulated using a CFD solver, DPLR, for a hemisphere of 1 m radius; the thermochemical relaxation along the stagnation streamline is considered equivalent to the flow behind a normal shock. Flow simulations are performed for a Titan gas mixture (98% N2, 2% CH4 by volume) for shock speeds of 5.7 and 7.6 km/s and pressures ranging from 20 to 1000 Pa, and a Mars gas mixture (96% CO2, and 4% N2 by volume) for a shock speed of 8.6 km/s and freestream pressure of 13 Pa. For each case, the temperatures and number densities of chemical species obtained from the CFD flow predictions are used as an input to a line-by-line radiation code, NEQAIR. The NEQAIR code is then used to compute the spatial distribution of volumetric radiance starting from the shock front to the point where thermochemical equilibrium is nominally established. Computations of volumetric spectral radiance assume Boltzmann distributions over radiatively linked electronic states of atoms and molecules. The results of these simulations are compared against experimental data acquired in the X2 facility at the University of Queensland, Australia. The experimental measurements were taken over a spectral range of 310-450 nm where the dominant contributor to radiation is the CN violet band system. In almost all cases, the present approach of computing the spatial variation of post-shock volumetric radiance by applying NEQAIR along a stagnation line computed using a high-fidelity flow solver with good spatial resolution of the relaxation zone is shown to replicate trends in measured relaxation of radiance for both Mars and Titan gas mixtures.

Equations and simulations for multiphase compressible gas-dust flows

NASA Astrophysics Data System (ADS)

Oran, Elaine; Houim, Ryan

2014-11-01

Dust-gas multiphase flows are important in physical scenarios such as dust explosions in coal mines, asteroid impact disturbing lunar regolith, and soft aircraft landings dispersing desert or beach sand. In these cases, the gas flow regime can range from highly subsonic and nearly incompressible to supersonic and shock-laden flow, the grain packing can range from fully packed to completely dispersed, and both the gas and the dust can range from chemically inert to highly exothermic. To cover the necessary parameter range in a single model, we solve coupled sets of Navier-Stokes equations describing the background gas and the dust. As an example, a reactive-dust explosion that results in a type of shock-flame complex is described and discussed. Sponsored by the University of Maryland through Minta Martin Endowment Funds in the Department of Aerospace Engineering, and through the Glenn L. Martin Institute Chaired Professorship at the A. James Clark School of Engineering.

Dual-phase gas-permeation flow-injection thermometric analysis for the determination of carbon dioxide.

PubMed

Liu, S J; Tubino, M

1998-11-01

A flow-injection configuration based on a dual-phase gas-permeation system from a liquid donor to a gas acceptor stream with a thermistor flow-through detector is proposed for the direct analysis of the gas in the acceptor. This system was applied for the determination of carbon dioxide (in the form of carbonate) using the following chemical reaction: CO(2)(g)+2NH(3)(g)+H(2)O(g)=(NH(4))(2)CO(3)(s), with a linear response from 1x10(-3) to 50x10(-3) mol l(-1) of CO(3)(2-). Carbon dioxide was produced in the liquid donor and permeated into the gaseous acceptor stream of air/water vapor. The detection limit is 1x10(-3) mol l(-1) of carbonate, and a sampling frequency of 60 h(-1) is achieved with a relative standard deviation of 4.1% for replicate injections. The dual-phase gas-permeation flow-injection manifold, along with the membrane and phase separations, as well as the chemical reaction, provides enhanced selectivity when compared with the system employing a liquid acceptor stream, as serious interferents in this system, for instance, acetate and formate, among others, do not interfere in the proposed system.

Method and apparatus for cold gas reinjection in through-flow and reverse-flow wave rotors

NASA Technical Reports Server (NTRS)

Nalim, M. Razi (Inventor); Paxson, Daniel E. (Inventor)

1999-01-01

A method and apparatus for cold gas reinjection in through-flow and reverse-flow wave rotors having a plurality of channels formed around a periphery thereof. A first port injects a supply of cool air into the channels. A second port allows the supply of cool air to exit the channels and flow to a combustor. A third port injects a supply of hot gas from the combustor into the channels. A fourth port allows the supply of hot gas to exit the channels and flow to a turbine. A diverting port and a reinjection port are connected to the second and third ports, respectively. The diverting port diverts a portion of the cool air exiting through the second port as reinjection air. The diverting port is fluidly connected to the reinjection port which reinjects the reinjection air back into the channels. The reinjection air evacuates the channels of the hot gas resident therein and cools the channel walls, a pair of end walls of the rotor, ducts communicating with the rotor and subsequent downstream components. In a second embodiment, the second port receives all of the cool air exiting the channels and the diverting port diverts a portion of the cool air just prior to the cool air flowing to the combustor.

The evolution of cooling flows. I - Self-similar cluster flows. [of gas in intergalactic medium

NASA Technical Reports Server (NTRS)

Chevalier, Roger A.

1987-01-01

The evolution of a cooling flow from an initial state of hydrostatic equilibrium in a cluster of galaxies is investigated. After gas mass and energy are injected into the cluster at an early phase, the gas approaches hydrostatic equilibrium over most of the cluster and cooling becomes important in the dense central regions. As time passes, cooling strongly affects an increasing amount of gas. The effects of mass removal from the flow, the inclusion of magnetic or cosmic-ray pressure, and heat conduction are considered individually.

High quality and uniformity GaN grown on 150 mm Si substrate using in-situ NH3 pulse flow cleaning process

NASA Astrophysics Data System (ADS)

Ji, Panfeng; Yang, Xuelin; Feng, Yuxia; Cheng, Jianpeng; Zhang, Jie; Hu, Anqi; Song, Chunyan; Wu, Shan; Shen, Jianfei; Tang, Jun; Tao, Chun; Pan, Yaobo; Wang, Xinqiang; Shen, Bo

2017-04-01

By using in-situ NH3 pulse flow cleaning method, we have achieved the repeated growth of high quality and uniformity GaN and AlGaN/GaN high electron mobility transistors (HEMTs) on 150 mm Si substrate. The two dimensional electron gas (2DEG) mobility is 2200 cm2/Vs with an electron density of 7.3 × 1012 cm-2. The sheet resistance is 305 ± 4 Ω/□ with ±1.3% variation. The achievement is attributed to the fact that this method can significantly remove the Al, Ga, etc. metal droplets coating on the post growth flow flange and reactor wall which are difficult to clean by normal bake process under H2 ambient.

The flows structure in unsteady gas flow in pipes with different cross-sections

NASA Astrophysics Data System (ADS)

Plotnikov, Leonid; Nevolin, Alexandr; Nikolaev, Dmitrij

2017-10-01

The results of numerical simulation and experimental study of the structure of unsteady flows in pipes with different cross sections are presented in the article. It is shown that the unsteady gas flow in a circular pipe is axisymmetric without secondary currents. Steady vortex structures (secondary flows) are observed in pipes with cross sections in the form of a square and an equilateral triangle. It was found that these secondary flows have a significant impact on gas flows in pipes of complex configuration. On the basis of experimental researches it is established that the strong oscillatory phenomena exist in the inlet pipe of the piston engine arising after the closing of the intake valve. The placement of the profiled plots (with a cross section of a square or an equilateral triangle) in the intake pipe leads to the damping of the oscillatory phenomena and a more rapid stabilization of pulsating flow. This is due to the stabilizing effect of the vortex structures formed in the corners of this configuration.

Performance of PEM fuel cells stack as affected by number of cell and gas flow-rate

NASA Astrophysics Data System (ADS)

Syampurwadi, A.; Onggo, H.; Indriyati; Yudianti, R.

2017-03-01

The proton exchange membrane fuel cell (PEMFC) is a promising technology as an alternative green energy due to its high power density, low operating temperatures, low local emissions, quiet operation and fast start up-shutdown. In order to apply fuel cell as portable power supply, the performance investigation of small number of cells is needed. In this study, PEMFC stacks consisting of 1, 3, 5 and 7-cells with an active area of 25 cm2 per cell have been designed and developed. Their was evaluated in variation of gas flow rate. The membrane electrode assembly (MEA) was prepared by hot-pressing commercial gas diffusion electrodes (Pt loading 0.5 mg/cm2) on pre-treated Nafion 117 membrane. The stacks were constructed using bipolar plates in serpentine pattern and Z-type gas flow configuration. The experimental results were presented as polarization and power output curves which show the effects of varying number of cells and H2/O2 flow-rates on the PEMFC performance. The experimental results showed that not only number of cells and gas flow-rates affected the fuel cells performance, but also the operating temperature as a result of electrochemistry reaction inside the cell.

Triboelectric-based harvesting of gas flow energy and powerless sensing applications

NASA Astrophysics Data System (ADS)

Taghavi, Majid; Sadeghi, Ali; Mazzolai, Barbara; Beccai, Lucia; Mattoli, Virgilio

2014-12-01

In this work, we propose an approach that can convert gas flow energy to electric energy by using the triboelectric effect, in a structure integrating at least two conductive parts (i.e. electrodes) and one non-conductive sheet. The gas flow induces vibration of the cited parts. Therefore, the frequent attaching and releasing between a non-conductive layer with at least one electrode generates electrostatic charges on the surfaces, and then an electron flow between the two electrodes. The effect of blown gas on the output signals is studied to evaluate the gas flow sensing. We also illustrate that the introduced system has an ability to detect micro particles driven by air into the system. Finally we show how we can use this approach for a self sustainable system demonstrating smoke detection and LED lightening.

Stability Analysis of High-Speed Boundary-Layer Flow with Gas Injection

DTIC Science & Technology

2014-06-01

Vitaly G. Soudakov; Ivett A Leyva 5e. TASK NUMBER 5f. WORK UNIT NUMBER Q0AF 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) 8. PERFORMING...cases of low injection rates in which the N -factors in the near field region are below the critical level, shaping can produce a significant...distribution unlimited Stability analysis of high-speed boundary-layer flow with gas injection Alexander V. Fedorov* and Vitaly G. Soudakov

Parents of two-phase flow and theory of "gas-lift"

NASA Astrophysics Data System (ADS)

Zitek, Pavel; Valenta, Vaclav

2014-03-01

This paper gives a brief overview of types of two-phase flow. Subsequently, it deals with their mutual division and problems with accuracy boundaries among particular types. It also shows the case of water flow through a pipe with external heating and the gradual origination of all kinds of flow. We have met it in solution of safety condition of various stages in pressurized and boiling water reactors. In the MSR there is a problem in the solution of gas-lift using helium as a gas and its secondary usage for clearing of the fuel mixture from gaseous fission products. Theory of gas-lift is described.

Computations of ideal and real gas high altitude plume flows

NASA Technical Reports Server (NTRS)

Feiereisen, William J.; Venkatapathy, Ethiraj

1988-01-01

In the present work, complete flow fields around generic space vehicles in supersonic and hypersonic flight regimes are studied numerically. Numerical simulation is performed with a flux-split, time asymptotic viscous flow solver that incorporates a generalized equilibrium chemistry model. Solutions to generic problems at various altitude and flight conditions show the complexity of the flow, the equilibrium chemical dissociation and its effect on the overall flow field. Viscous ideal gas solutions are compared against equilibrium gas solutions to illustrate the effect of equilibrium chemistry. Improved solution accuracy is achieved through adaptive grid refinement.

Decay of the 3D inviscid liquid-gas two-phase flow model

NASA Astrophysics Data System (ADS)

Zhang, Yinghui

2016-06-01

We establish the optimal {Lp-L2(1 ≤ p < 6/5)} time decay rates of the solution to the Cauchy problem for the 3D inviscid liquid-gas two-phase flow model and analyze the influences of the damping on the qualitative behaviors of solution. Compared with the viscous liquid-gas two-phase flow model (Zhang and Zhu in J Differ Equ 258:2315-2338, 2015), our results imply that the friction effect of the damping is stronger than the dissipation effect of the viscosities and enhances the decay rate of the velocity. Our proof is based on Hodge decomposition technique, the {Lp-L2} estimates for the linearized equations and an elaborate energy method.

Study of gas-liquid flow in model porous media for heterogeneous catalysis

NASA Astrophysics Data System (ADS)

Francois, Marie; Bodiguel, Hugues; Guillot, Pierre; Laboratory of the Future Team

2015-11-01

Heterogeneous catalysis of chemical reactions involving a gas and a liquid phase is usually achieved in fixed bed reactors. Four hydrodynamic regimes have been observed. They depend on the total flow rate and the ratio between liquid and gas flow rate. Flow properties in these regimes influence transfer rates. Rather few attempts to access local characterization have been proposed yet, though these seem to be necessary to better describe the physical mechanisms involved. In this work, we propose to mimic slices of reactor by using two-dimensional porous media. We have developed a two-dimensional system that is transparent to allow the direct observation of the flow and the phase distribution. While varying the total flow rate and the gas/liquid flow rate ratio, we observe two hydrodynamic regimes: at low flow rate, the gaseous phase is continuous (trickle flow), while it is discontinuous at higher flow rate (pulsed flow). Thanks to some image analysis techniques, we are able to quantify the local apparent liquid saturation in the system. Its fluctuations in time are characteristic of the transition between the two regimes: at low liquid flow rates, they are negligible since the liquid/gas interface is fixed, whereas at higher flow rates we observe an alternation between liquid and gas. This transition between trickle to pulsed flow is in relative good agreement with the existing state of art. However, we report in the pulsed regime important flow heterogeneities at the scale of a few pores. These heterogeneities are likely to have a strong influence on mass transfers. We acknowledge the support of Solvay.

CO2 conversion in non-thermal plasma and plasma/g-C3N4 catalyst hybrid processes

NASA Astrophysics Data System (ADS)

Lu, Na; Sun, Danfeng; Zhang, Chuke; Jiang, Nan; Shang, Kefeng; Bao, Xiaoding; Li, Jie; Wu, Yan

2018-03-01

Carbon dioxide conversion at atmosphere pressure and low temperature has been studied in a cylindrical dielectric barrier discharge (DBD) reactor. Pure CO2 feed flows to the discharge zone and typical filamentary discharges were obtained in each half-cycle of the applied voltage. The gas temperature increased with discharge time and discharge power, which was found to affect the CO2 decomposition deeply. As the DBD reactor was cooled to ambient temperature, both the conversion of CO2 and the CO yield were enhanced. Especially the energy efficiencies changed slightly with the increase of discharge power and were much higher in cooling condition comparing to those without cooling. At a discharge power of 40 W, the energy efficiency under cooling condition was approximately six times more than that without cooling. Gas flow rate was observed to affect CO2 conversion and 0.1 L min-1 was obtained as optimum gas flow rate under cooling condition. In addition, the CO2 conversion rate in plasma/g-C3N4 catalyst hybrid system was twice times as that in plasma-alone system. In case of cooling, the existence of g-C3N4 catalyst contributed to a 47% increase of CO2 conversion compared to the sole plasma process. The maximum energy-efficiency with g-C3N4 was 0.26 mmol kJ-1 at 20 W, which increased by 157% compared to that without g-C3N4. The synergistic effect of DBD plasma with g-C3N4 on pure CO2 conversion was verified.

Gas dispersion and immobile gas volume in solid and porous particle biofilter materials at low air flow velocities.

PubMed

Sharma, Prabhakar; Poulsen, Tjalfe G

2010-07-01

Gas-phase dispersion in granular biofilter materials with a wide range of particle sizes was investigated using atmospheric air and nitrogen as tracer gases. Two types of materials were used: (1) light extended clay aggregates (LECA), consisting of highly porous particles, and (2) gravel, consisting of solid particles. LECA is a commercial material that is used for insulation, as a soil conditioner, and as a carrier material in biofilters for air cleaning. These two materials were selected to have approximately the same particle shape. Column gas transport experiments were conducted for both materials using different mean particle diameters, different particle size ranges, and different gas flow velocities. Measured breakthrough curves were modeled using the advection-dispersion equation modified for mass transfer between mobile and immobile gas phases. The results showed that gas dispersivity increased with increasing mean particle diameter for LECA but was independent of mean particle diameter for gravel. Gas dispersivity also increased with increasing particle size range for both media. Dispersivities in LECA were generally higher than for gravel. The mobile gas content in both materials increased with increasing gas flow velocity but it did not show any strong dependency on mean particle diameter or particle size range. The relative fraction of mobile gas compared with total porosity was highest for gravel and lowest for LECA likely because of its high internal porosity.

Solution of weakly compressible isothermal flow in landfill gas collection networks

NASA Astrophysics Data System (ADS)

Nec, Y.; Huculak, G.

2017-12-01

Pipe networks collecting gas in sanitary landfills operate under the regime of a weakly compressible isothermal flow of ideal gas. The effect of compressibility has been traditionally neglected in this application in favour of simplicity, thereby creating a conceptual incongruity between the flow equations and thermodynamic equation of state. Here the flow is solved by generalisation of the classic Darcy-Weisbach equation for an incompressible steady flow in a pipe to an ordinary differential equation, permitting continuous variation of density, viscosity and related fluid parameters, as well as head loss or gain due to gravity, in isothermal flow. The differential equation is solved analytically in the case of ideal gas for a single edge in the network. Thereafter the solution is used in an algorithm developed to construct the flow equations automatically for a network characterised by an incidence matrix, and determine pressure distribution, flow rates and all associated parameters therein.

Production of simplex RNS and ROS by nanosecond pulse N2/O2 plasma jets with homogeneous shielding gas for inducing myeloma cell apoptosis

NASA Astrophysics Data System (ADS)

Liu, Zhijie; Xu, Dehui; Liu, Dingxin; Cui, Qingjie; Cai, Haifeng; Li, Qiaosong; Chen, Hailan; Kong, Michael G.

2017-05-01

In this paper, atmospheric pressure N2/O2 plasma jets with homogeneous shielding gas excited by nanosecond pulse are obtained to generate simplex reactive nitrogen species (RNS) and reactive oxygen species (ROS), respectively, for the purpose of studying the simplex RNS and ROS to induce the myeloma cell apoptosis with the same discharge power. The results reveal that the cell death rate by the N2 plasma jet with N2 shielding gas is about two times that of the O2 plasma jet with O2 shielding gas for the equivalent treatment time. By diagnosing the reactive species of ONOO-, H2O2, OH and \\text{O}2- in medium, our findings suggest the cell death rate after plasma jets treatment has a positive correlation with the concentration of ONOO-. Therefore, the ONOO- in medium is thought to play an important role in the process of inducing myeloma cell apoptosis.

A bubble-based microfluidic gas sensor for gas chromatographs.

PubMed

Bulbul, Ashrafuzzaman; Kim, Hanseup

2015-01-07

We report a new proof-of-concept bubble-based gas sensor for a gas chromatography system, which utilizes the unique relationship between the diameters of the produced bubbles with the gas types and mixture ratios as a sensing element. The bubble-based gas sensor consists of gas and liquid channels as well as a nozzle to produce gas bubbles through a micro-structure. It utilizes custom-developed software and an optical camera to statistically analyze the diameters of the produced bubbles in flow. The fabricated gas sensor showed that five types of gases (CO2, He, H2, N2, and CH4) produced (1) unique volumes of 0.44, 0.74, 1.03, 1.28, and 1.42 nL (0%, 68%, 134%, 191%, and 223% higher than that of CO2) and (2) characteristic linear expansion coefficients (slope) of 1.38, 2.93, 3.45, 5.06, and 5.44 nL/(kPa (μL s(-1))(-1)). The gas sensor also demonstrated that (3) different gas mixture ratios of CO2 : N2 (100 : 0, 80 : 20, 50 : 50, 20 : 80 and 0 : 100) generated characteristic bubble diameters of 48.95, 77.99, 71.00, 78.53 and 99.50 μm, resulting in a linear coefficient of 10.26 μm (μL s(-1))(-1). It (4) successfully identified an injection (0.01 μL) of pentane (C5) into a continuous carrier gas stream of helium (He) by monitoring bubble diameters and creating a chromatogram and demonstrated (5) the output stability within only 5.60% variation in 67 tests over a month.

Method for measuring changes in the atmospheric O2/N2 ratio by a gas chromatograph equipped with a thermal conductivity detector

NASA Astrophysics Data System (ADS)

Tohjima, Yasunori

2000-06-01

We present a method for measuring changes in the atmospheric O2/N2 ratio based on data from a gas chromatograph (GC) equipped with a thermal conductivity detector (TCD). In this method, O2 and N2 in an air sample are separated on a column filled with molecular sieve 5A with H2 carrier gas. Since the separated O2 includes Ar, which has a retention time similar to that of O2, the (O2+Ar)/N2 ratio is actually measured. The change in the measured (O2+Ar)/N2 ratio can be easily converted to that in the O2/N2 ratio with a very small error based on the fact that the atmospheric Ar/N2 ratio is almost constant. The improvements to achieve the high-precision measurement include stabilization of the pressure at the GC column head and at the outlets of the TCD and the sample loop. Additionally, the precision is improved statistically by repeating alternate analyses of sample and a reference gas. The standard deviation of the replicate cycles of reference and sample analyses is about 18 per meg (corresponding to 3.8 parts per million (ppm) O2 in air). This means that the standard error is about 7 per meg (1.5 ppm O2 in air) for seven cycles of alternate analyses, which takes about 70 min. The response of this method is likely to have a 2% nonlinearity. Ambient air samples are collected under pressure in glass flasks equipped with two stopcocks sealed by Viton O-rings at both ends. Pressure depletion in the flask during the O2/N2 measurement does not cause any detectable change in the O2/N2 ratio, but the O2/N2 ratio in the flask was found to gradually decrease during the storage period. We also present preliminary results from air samples collected at Hateruma Island (latitude 24°03'N, longitude 123°49') from July 1997 through March 1999. The observed O2/N2 ratios clearly show a seasonal variation, increasing in spring and summer and decreasing in autumn and winter.

Chlorobium limicola forma thiosulfatophilum: Biocatalyst in the Production of Sulfur and Organic Carbon from a Gas Stream Containing H2S and CO2

PubMed Central

Cork, Douglas J.; Garunas, Ruta; Sajjad, Ashfaq

1983-01-01

Chlorobium limicola forma thiosulfatophilum (ATCC 17092) was grown in a 1-liter continuously stirred tank reactor (800-ml liquid volume) at pH 6.8, 30°C, saturated light intensity, and a gas flow rate of 23.6 ml/min from a gas cylinder blend consisting of 3.9 mol% H2S, 9.2 mol% CO2, 86.4 mol% N2, and 0.5 mol% H2. This is the first demonstration of photoautotrophic growth of a Chlorobium sp. on a continuous inorganic gas feed. A significant potential exists for applying this photoautotrophic process to desulfurization and CO2 fixation of gases containing acidic components (H2S and CO2). PMID:16346255

Numerical simulation of gas-phonon coupling in thermal transpiration flows.

PubMed

Guo, Xiaohui; Singh, Dhruv; Murthy, Jayathi; Alexeenko, Alina A

2009-10-01

Thermal transpiration is a rarefied gas flow driven by a wall temperature gradient and is a promising mechanism for gas pumping without moving parts, known as the Knudsen pump. Obtaining temperature measurements along capillary walls in a Knudsen pump is difficult due to extremely small length scales. Meanwhile, simplified analytical models are not applicable under the practical operating conditions of a thermal transpiration device, where the gas flow is in the transitional rarefied regime. Here, we present a coupled gas-phonon heat transfer and flow model to study a closed thermal transpiration system. Discretized Boltzmann equations are solved for molecular transport in the gas phase and phonon transport in the solid. The wall temperature distribution is the direct result of the interfacial coupling based on mass conservation and energy balance at gas-solid interfaces and is not specified a priori unlike in the previous modeling efforts. Capillary length scales of the order of phonon mean free path result in a smaller temperature gradient along the transpiration channel as compared to that predicted by the continuum solid-phase heat transfer. The effects of governing parameters such as thermal gradients, capillary geometry, gas and phonon Knudsen numbers and, gas-surface interaction parameters on the efficiency of thermal transpiration are investigated in light of the coupled model.

N 2 gas is an effective fertilizer for bioethanol production by Zymomonas mobilis

DOE PAGES

Kremer, Timothy A.; LaSarre, Breah; Posto, Amanda L.; ...

2015-02-02

A nascent cellulosic ethanol industry is struggling to become cost-competitive against corn ethanol and gasoline. Millions of dollars are spent on nitrogen supplements to make up for the low nitrogen content of the cellulosic feedstock. In this paper, we show for the first time to our knowledge that the ethanol-producing bacterium, Zymomonas mobilis, can use N 2 gas in lieu of traditional nitrogen supplements. Despite being an electron-intensive process, N 2 fixation by Z. mobilis did not divert electrons away from ethanol production, as the ethanol yield was greater than 97% of the theoretical maximum. In a defined medium, Z.more » mobilis produced ethanol 50% faster per cell and generated half the unwanted biomass when supplied N 2 instead of ammonium. In a cellulosic feedstock-derived medium, Z. mobilis achieved a similar cell density and a slightly higher ethanol yield when supplied N 2 instead of the industrial nitrogen supplement, corn steep liquor. Finally, we estimate that N 2-utilizing Z. mobilis could save a cellulosic ethanol production facility more than $1 million/y.« less

N2 gas is an effective fertilizer for bioethanol production by Zymomonas mobilis

PubMed Central

Kremer, Timothy A.; LaSarre, Breah; Posto, Amanda L.; McKinlay, James B.

2015-01-01

A nascent cellulosic ethanol industry is struggling to become cost-competitive against corn ethanol and gasoline. Millions of dollars are spent on nitrogen supplements to make up for the low nitrogen content of the cellulosic feedstock. Here we show for the first time to our knowledge that the ethanol-producing bacterium, Zymomonas mobilis, can use N2 gas in lieu of traditional nitrogen supplements. Despite being an electron-intensive process, N2 fixation by Z. mobilis did not divert electrons away from ethanol production, as the ethanol yield was greater than 97% of the theoretical maximum. In a defined medium, Z. mobilis produced ethanol 50% faster per cell and generated half the unwanted biomass when supplied N2 instead of ammonium. In a cellulosic feedstock-derived medium, Z. mobilis achieved a similar cell density and a slightly higher ethanol yield when supplied N2 instead of the industrial nitrogen supplement, corn steep liquor. We estimate that N2-utilizing Z. mobilis could save a cellulosic ethanol production facility more than $1 million/y. PMID:25646422

Development of a Molecular Tagging Velocimetry Technique for Non-Intrusive Velocity Measurements in Low-Speed Gas Flows

NASA Technical Reports Server (NTRS)

Andre, M. A.; Bardet, P. M.; Cadell, S. R.; Woods, B.; Burns, R. A.; Danehy, P. M.

2017-01-01

N2O molecular tagging velocimetry (N2O-MTV) is developed for use in very-high-temperature reactor environments. Tests were carried out to determine the optimum excitation wavelength, tracer concentration, and timing parameters for the laser system. Using NO tracers obtained from photo-dissociation of N2O, velocity profiles are successfully obtained in air, nitrogen, and helium for a large range of parameters: temperature from 295 to 781 K, pressure from 1 to 3 bars, with a velocity precision of 0.01 m/s. Furthermore, by using two read pulses at adjustable time delays, the velocity dynamic range can be increased. An unprecedented dynamic range of 5,000 has been obtained to successfully resolve the flow during a helium blowdown from 1000 m/s down to 0.2 m/s. This technique is also applied to the high-temperature test facility (HTTF) at Oregon State University (OSU) during a depressurized condition cooldown (DCC) event. Details of these measurements are presented in a companion paper. This technique shows a strong potential for fundamental understanding of gas flows in nuclear reactors and to provide benchmark experimental data to validate numerical simulations.

Efficient boron-carbon-nitrogen nanotube formation via combined laser-gas flow levitation

DOEpatents

Whitney, R Roy; Jordan, Kevin; Smith, Michael W

2015-03-24

A process for producing boron nitride nanotubes and/or boron-carbon-nitrogen nanotubes of the general formula B.sub.xC.sub.yN.sub.z. The process utilizes a combination of laser light and nitrogen gas flow to support a boron ball target during heating of the boron ball target and production of a boron vapor plume which reacts with nitrogen or nitrogen and carbon to produce boron nitride nanotubes and/or boron-carbon-nitrogen nanotubes of the general formula B.sub.xC.sub.yN.sub.z.

Liter-scale production of uniform gas bubbles via parallelization of flow-focusing generators.

PubMed

Jeong, Heon-Ho; Yadavali, Sagar; Issadore, David; Lee, Daeyeon

2017-07-25

Microscale gas bubbles have demonstrated enormous utility as versatile templates for the synthesis of functional materials in medicine, ultra-lightweight materials and acoustic metamaterials. In many of these applications, high uniformity of the size of the gas bubbles is critical to achieve the desired properties and functionality. While microfluidics have been used with success to create gas bubbles that have a uniformity not achievable using conventional methods, the inherently low volumetric flow rate of microfluidics has limited its use in most applications. Parallelization of liquid droplet generators, in which many droplet generators are incorporated onto a single chip, has shown great promise for the large scale production of monodisperse liquid emulsion droplets. However, the scale-up of monodisperse gas bubbles using such an approach has remained a challenge because of possible coupling between parallel bubbles generators and feedback effects from the downstream channels. In this report, we systematically investigate the effect of factors such as viscosity of the continuous phase, capillary number, and gas pressure as well as the channel uniformity on the size distribution of gas bubbles in a parallelized microfluidic device. We show that, by optimizing the flow conditions, a device with 400 parallel flow focusing generators on a footprint of 5 × 5 cm 2 can be used to generate gas bubbles with a coefficient of variation of less than 5% at a production rate of approximately 1 L h -1 . Our results suggest that the optimization of flow conditions using a device with a small number (e.g., 8) of parallel FFGs can facilitate large-scale bubble production.

Effect of simulated coal-derived gas composition on H{sub 2}S poisoning behavior evaluated using a disaggregation scheme

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, T.S.; Miao, H.; Chen, T.

2009-07-01

H{sub 2}S poisoning is an important issue for solid oxide fuel cells (SOFCs) operated with syngas. The effect of simulated coal-derived gas composition on H{sub 2}S poisoning behavior was evaluated using a disaggregation scheme where the influence of H{sub 2} content was determined separately using a typical anode-supported SOFC operated with a N2/H{sub 2} mixture gas, while the effect of other compositions (CO, CO{sub 2}, and H{sub 2}O) was investigated with simulated coal-derived gas having constant H{sub 2} and CO flow rates balanced by a H{sub 2}/N2 mixture gas (83% H{sub 2} and 17% N2). The results indicated that themore » extent of H{sub 2}S poisoning was not pertinent to H{sub 2} content when the cell was tested galvanostatically with a current density of 0.3 A/cm{sup 2} at 800{sup o}C using a N2/H{sub 2} mixture gas containing 10 ppm H{sub 2}S, and the H{sub 2}S poisoning impact can be completely removed by switching to sulfur-free gas. The CO, CO{sub 2}, and high water vapor content aggravated the H{sub 2}S poisoning effect, and the performance was almost irrecoverable when the cell was tested with a 35% H{sub 2}-46% CO-16% N2-3% H{sub 2}O mixture gas containing 12.5 ppm H{sub 2}S. However, the introduction of 10% CO{sub 2} and an increase in H{sub 2}O content from 3 to 10% in the mixture gas can promote the performance recoverability to a larger extent.« less

Non-contact ultrasonic gas flow metering using air-coupled leaky Lamb waves.

PubMed

Fan, Zichuan; Jiang, Wentao; Wright, William M D

2018-04-23

This paper describes a completely non-contact ultrasonic method of gas flow metering using air-coupled leaky Lamb waves. To show proof of principle, a simplified representation of gas flow in a duct, comprising two separated thin isotropic plates with a gas flowing between them, has been modelled and investigated experimentally. An airborne compression wave emitted from an air-coupled capacitive ultrasonic transducer excited a leaky Lamb wave in the first plate in a non-contact manner. The leakage of this Lamb wave crossed the gas flow at an angle between the two plates as a compression wave, and excited a leaky Lamb wave in the second plate. An air-coupled capacitive ultrasonic transducer on the opposite side of this second plate then detected the airborne compression wave leakage from the second Lamb wave. As the gas flow shifted the wave field between the two plates, the point of Lamb wave excitation in the second plate was displaced in proportion to the gas flow rate. Two such measurements, in opposite directions, formed a completely non-contact contra-propagating Lamb wave flow meter, allowing measurement of the flow velocity between the plates. A COMSOL Multiphysics® model was used to visualize the wave fields, and accurately predicted the time differences that were then measured experimentally. Experiments using different Lamb wave frequencies and plate materials were also similarly verified. This entirely non-contact airborne approach to Lamb wave flow metering could be applied in place of clamp-on techniques in thin-walled ducts or pipes. Copyright © 2018 Elsevier B.V. All rights reserved.

Rotational Energy Transfer of N2 Gas Determined Using a New Ab Initio Potential Energy Surface

NASA Technical Reports Server (NTRS)

Huo, Winifred M.; Stallcop, James R.; Partridge, Harry; Langhoff, Stephen R. (Technical Monitor)

1997-01-01

Rotational energy transfer between two N2 molecules is a fundamental process of some importance. Exchange is expected to play a role, but its importance is somewhat uncertain. Rotational energy transfer cross sections of N2 also have applications in many other fields including modeling of aerodynamic flows, laser operations, and linewidth analysis in nonintrusive laser diagnostics. A number of N2-N2 rigid rotor potential energy surface (PES) has been reported in the literature.

The role of unstable NH3 in the formation of nitrogen-rich alpha-U2N(3+x) by the reaction of UC or U with NH3

NASA Astrophysics Data System (ADS)

Katsura, Masahiro; Hirota, Masayuki; Miyake, Masanobu

1994-10-01

Reactions of U or UC with a stream of NH3 or N2 were carried out at 600 and 900 C. It has been found that in high temperature reactions of U or UC with flowing NH3, the catalytic decomposition of NH3 proceeds in parallel with the nitridation reaction of U or UC by action of NH3, which leads to the formation alpha-U2N(3+x), and eventually a steady state is established where the partial pressures of NH3, H2 and N2 (PNH3, PH2, and PN2) in the flowing gas and the N:U ratio of alpha-U2N(3+x) are all uniquely determined. The nitrogen activity a(sub N) of the flowing gas may be increased by suppressing the decomposition of NH3 into H2 and N2. The N:U ratio of alpha-U2N(3+x) increases as the extent of dissociation of NH3, alpha, decreases.

Cryogenic and Simulated Fuel Jet Breakup in Argon, Helium and Nitrogen Gas Flows

NASA Technical Reports Server (NTRS)

Ingebo, Robert D.

1995-01-01

Two-phase flow atomization of liquid nitrogen jets was experimentally investigated. They were co-axially injected into high-velocity gas flows of helium, nitrogen and argon, respectively, and atomized internally inside a two-fluid fuel nozzle. Cryogenic sprays with relatively high specific surface areas were produced, i.e., ratios of surface area to volume were fairly high. This was indicated by values of reciprocal Sauter mean diameters, RSMD's, as measured with a scattered- light scanning instrument developed at NASA Lewis Research Center. Correlating expressions were derived for the three atomizing gases over a gas temperature range of 111 to 422 K. Also, the correlation was extended to include waterjet breakup data that had been previously obtained in simulating fuel jet breakup in sonic velocity gas flow. The final correlating expression included a new dimensionless molecular-scale acceleration group. It was needed to correlate RSMD data, for LN2 and H2O sprays, with the fluid properties of the liquid jets and atomizing gases used in this investigation.

One-dimensional flows of an imperfect diatomic gas

NASA Technical Reports Server (NTRS)

1959-01-01

With the assumptions that Berthelot's equation of state accounts for molecular size and intermolecular force effects, and that changes in the vibrational heat capacities are given by a Planck term, expressions are developed for analyzing one-dimensional flows of a diatomic gas. The special cases of flow through normal and oblique shocks in free air at sea level are investigated. It is found that up to a Mach number 10 pressure ratio across a normal shock differs by less than 6 percent from its ideal gas value; whereas at Mach numbers above 4 the temperature rise is considerable below and hence the density rise is well above that predicted assuming ideal gas behavior. It is further shown that only the caloric imperfection in air has an appreciable effect on the pressures developed in the shock process considered. The effects of gaseous imperfections on oblique shock-flows are studied from the standpoint of their influence on the life and pressure drag of a flat plate operating at Mach numbers of 10 and 20. The influence is found to be small. (author)

Discharge characteristics and hydrodynamics behaviors of atmospheric plasma jets produced in various gas flow patterns

NASA Astrophysics Data System (ADS)

Setsuhara, Yuichi; Uchida, Giichiro; Nakajima, Atsushi; Takenaka, Kosuke; Koga, Kazunori; Shiratani, Masaharu

2015-09-01

Atmospheric nonequilibrium plasma jets have been widely employed in biomedical applications. For biomedical applications, it is an important issue to understand the complicated mechanism of interaction of the plasma jet with liquid. In this study, we present analysis of the discharge characteristics of a plasma jet impinging onto the liquid surface under various gas flow patterns such as laminar and turbulence flows. For this purpose, we analyzed gas flow patters by using a Schlieren gas-flow imaging system in detail The plasma jet impinging into the liquid surface expands along the liquid surface. The diameter of the expanded plasma increases with gas flow rate, which is well explained by an increase in the diameter of the laminar gas-flow channel. When the gas flow rate is further increased, the gas flow mode transits from laminar to turbulence in the gas flow channel, which leads to the shortening of the plasm-jet length. Our experiment demonstrated that the gas flow patterns strongly affect the discharge characteristics in the plasma-jet system. This study was partly supported by a Grant-in-Aid for Scientific Research on Innovative Areas ``Plasma Medical Innovation'' (24108003) from the Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT).

Fluid Flow Patterns During Production from Gas Hydrates in the Laboratory compared to Field Settings: LARS vs. Mallik

NASA Astrophysics Data System (ADS)

Strauch, B.; Heeschen, K. U.; Priegnitz, M.; Abendroth, S.; Spangenberg, E.; Thaler, J.; Schicks, J. M.

2015-12-01

The GFZ's LArge Reservoir Simulator LARS allows for the simulation of the 2008 Mallik gas hydrate production test and the comparison of fluid flow patterns and their driving forces. Do we see the gas flow pattern described for Mallik [Uddin, M. et al., J. Can. Petrol Tech, 50, 70-89, 2011] in a pilot scale test? If so, what are the driving forces? LARS has a network of temperature sensors and an electric resistivity tomography (ERT) enabling a good spatial resolution of gas hydrate occurrences, water and gas distribution, and changes in temperature in the sample. A gas flow meter and a water trap record fluid flow patterns and a backpressure valve has controlled the depressurization equivalent to the three pressure stages (7.0 - 5.0 - 4.2 MPa) applied in the Mallik field test. The environmental temperature (284 K) and confining pressure (13 MPa) have been constant. The depressurization induced immediate endothermic gas hydrate dissociation until re-establishment of the stability conditions by a consequent temperature decrease. Slight gas hydrate dissociation continued at the top and upper lateral border due to the constant heat input from the environment. Here transport pathways were short and permeability higher due to lower gas hydrate saturation. At pressures of 7.0 and 5.0 MPa the LARS tests showed high water flow rates and short irregular spikes of gas production. The gas flow patterns at 4.2 MPa and 3.0MPa resembled those of the Mallik test. In LARS the initial gas surges overlap with times of hydrate instability while water content and lengths of pathways had increased. Water production was at a minimum. A rapidly formed continuous gas phase caused the initial gas surges and only after gas hydrate dissociation decreased to a minimum the single gas bubbles get trapped before slowly coalescing again. In LARS, where pathways were short and no additional water was added, a transport of microbubbles is unlikely to cause a gas surge as suggested for Mallik.

Generalized self-similar unsteady gas flows behind the strong shock wave front

NASA Astrophysics Data System (ADS)

Bogatko, V. I.; Potekhina, E. A.

2018-05-01

Two-dimensional (plane and axially symmetric) nonstationary gas flows behind the front of a strong shock wave are considered. All the gas parameters are functions of the ratio of Cartesian coordinates to some degree of time tn, where n is a self-similarity index. The problem is solved in Lagrangian variables. It is shown that the resulting system of partial differential equations is suitable for constructing an iterative process. ¢he "thin shock layer" method is used to construct an approximate analytical solution of the problem. The limit solution of the problem is constructed. A formula for determining the path traversed by a gas particle in the shock layer along the front of a shock wave is obtained. A system of equations for determining the first approximation corrections is constructed.

The Development of a Gas-Liquid Two-Phase Flow Sensor Applicable to CBM Wellbore Annulus.

PubMed

Wu, Chuan; Wen, Guojun; Han, Lei; Wu, Xiaoming

2016-11-18

The measurement of wellbore annulus gas-liquid two-phase flow in CBM (coalbed methane) wells is of great significance for reasonably developing gas drainage and extraction processes, estimating CBM output, judging the operating conditions of CBM wells and analyzing stratum conditions. Hence, a specially designed sensor is urgently needed for real-time measurement of gas-liquid two-phase flow in CBM wellbore annulus. Existing flow sensors fail to meet the requirements of the operating conditions of CBM wellbore annulus due to such factors as an inapplicable measurement principle, larger size, poor sealability, high installation accuracy, and higher requirements for fluid media. Therefore, based on the principle of a target flowmeter, this paper designs a new two-phase flow sensor that can identify and automatically calibrate different flow patterns of two-phase flows. Upon the successful development of the new flow sensor, lab and field tests were carried out, and the results show that the newly designed sensor, with a measurement accuracy of ±2.5%, can adapt to the operating conditions of CBM wells and is reliable for long-term work.

Mathematical modeling of non-stationary gas flow in gas pipeline

NASA Astrophysics Data System (ADS)

Fetisov, V. G.; Nikolaev, A. K.; Lykov, Y. V.; Duchnevich, L. N.

2018-03-01

An analysis of the operation of the gas transportation system shows that for a considerable part of time pipelines operate in an unsettled regime of gas movement. Its pressure and flow rate vary along the length of pipeline and over time as a result of uneven consumption and selection, switching on and off compressor units, shutting off stop valves, emergence of emergency leaks. The operational management of such regimes is associated with difficulty of reconciling the operating modes of individual sections of gas pipeline with each other, as well as with compressor stations. Determining the grounds that cause change in the operating mode of the pipeline system and revealing patterns of these changes determine the choice of its parameters. Therefore, knowledge of the laws of changing the main technological parameters of gas pumping through pipelines in conditions of non-stationary motion is of great importance for practice.

Real Time Mud Gas Logging During Drilling of DFDP-2B

NASA Astrophysics Data System (ADS)

Mathewson, L. A.; Toy, V.; Menzies, C. D.; Zimmer, M.; Erzinger, J.; Niedermann, S.; Cox, S.

2015-12-01

The Deep Fault Drilling Project (DFDP) aims to improve our understanding of the Alpine Fault Zone, a tectonically active mature fault system in New Zealand known to rupture in large events, by deep scientific drilling. The borehole DFDP-2B approached the Alpine Fault at depth, reaching a final depth of 892 m (820 m true vertical depth). Online gas analysis (OLGA) while drilling tracked changes in the composition of gases extracted from the circulating drill mud. The composition of fluids from fault zones can provide information about their origins, flow rates and -paths, fluid-rock interactions along these paths, and the permeability structure of the faulted rock mass. Apart from an atmospheric input, the gases in drilling mud derive from the pore space of rock, crushed at the drill bit, and from permeable layers intersected by the borehole. The rapid formation of mud wall cake seals the borehole from further fluid inflow, hence formation-derived gases enter mostly at the depth of the drill bit. OLGA analyses N2, O2, Ar, CO2, CH4, He, and H2 on a mass spectrometer, hydrocarbons CH4, C2H6, C3H8, i-C4H10, and n-C4H10 on a gas chromatograph, and Rn using a lucas-cell detector. Gas was sampled for offline analyses on noble gas and stable isotopes to complement the OLGA dataset. The principle formation-derived gases found in drilling mud during drilling of DFDP-2 were CO2 and CH4, with smaller component of H2 and He2. High radon activity is interpreted to reflect intervals of active fluid flow through highly fractured and faulted rock. 3He/4He values in many samples were extremely air-contaminated, i.e. there was almost no excess of non-atmospheric He. The 3He/4He values measured at 236 m and 610 m, which are the only analyses with uncertainties <100%, are very similar to those measured in hot springs along the Alpine Fault, e.g. Fox River (0.64 Ra), Copland (0.42 Ra), Lower Wanganui (0.81 Ra). We will compare these data to those gathered using OLGA and discuss the

Discrete unified gas kinetic scheme for all Knudsen number flows. III. Binary gas mixtures of Maxwell molecules

NASA Astrophysics Data System (ADS)

Zhang, Yue; Zhu, Lianhua; Wang, Ruijie; Guo, Zhaoli

2018-05-01

Recently a discrete unified gas kinetic scheme (DUGKS) in a finite-volume formulation based on the Boltzmann model equation has been developed for gas flows in all flow regimes. The original DUGKS is designed for flows of single-species gases. In this work, we extend the DUGKS to flows of binary gas mixtures of Maxwell molecules based on the Andries-Aoki-Perthame kinetic model [P. Andries et al., J. Stat. Phys. 106, 993 (2002), 10.1023/A:1014033703134. A particular feature of the method is that the flux at each cell interface is evaluated based on the characteristic solution of the kinetic equation itself; thus the numerical dissipation is low in comparison with that using direct reconstruction. Furthermore, the implicit treatment of the collision term enables the time step to be free from the restriction of the relaxation time. Unlike the DUGKS for single-species flows, a nonlinear system must be solved to determine the interaction parameters appearing in the equilibrium distribution function, which can be obtained analytically for Maxwell molecules. Several tests are performed to validate the scheme, including the shock structure problem under different Mach numbers and molar concentrations, the channel flow driven by a small gradient of pressure, temperature, or concentration, the plane Couette flow, and the shear driven cavity flow under different mass ratios and molar concentrations. The results are compared with those from other reliable numerical methods. The results show that the proposed scheme is an effective and reliable method for binary gas mixtures in all flow regimes.

Scaling analysis of gas-liquid two-phase flow pattern in microgravity

NASA Technical Reports Server (NTRS)

Lee, Jinho

1993-01-01

A scaling analysis of gas-liquid two-phase flow pattern in microgravity, based on the dominant physical mechanism, was carried out with the goal of predicting the gas-liquid two-phase flow regime in a pipe under conditions of microgravity. The results demonstrated the effect of inlet geometry on the flow regime transition. A comparison of the predictions with existing experimental data showed good agreement.

Comparative study of the discrete velocity and lattice Boltzmann methods for rarefied gas flows through irregular channels

NASA Astrophysics Data System (ADS)

Su, Wei; Lindsay, Scott; Liu, Haihu; Wu, Lei

2017-08-01

Rooted from the gas kinetics, the lattice Boltzmann method (LBM) is a powerful tool in modeling hydrodynamics. In the past decade, it has been extended to simulate rarefied gas flows beyond the Navier-Stokes level, either by using the high-order Gauss-Hermite quadrature, or by introducing the relaxation time that is a function of the gas-wall distance. While the former method, with a limited number of discrete velocities (e.g., D2Q36), is accurate up to the early transition flow regime, the latter method (especially the multiple relaxation time (MRT) LBM), with the same discrete velocities as those used in simulating hydrodynamics (i.e., D2Q9), is accurate up to the free-molecular flow regime in the planar Poiseuille flow. This is quite astonishing in the sense that less discrete velocities are more accurate. In this paper, by solving the Bhatnagar-Gross-Krook kinetic equation accurately via the discrete velocity method, we find that the high-order Gauss-Hermite quadrature cannot describe the large variation in the velocity distribution function when the rarefaction effect is strong, but the MRT-LBM can capture the flow velocity well because it is equivalent to solving the Navier-Stokes equations with an effective shear viscosity. Since the MRT-LBM has only been validated in simple channel flows, and for complex geometries it is difficult to find the effective viscosity, it is necessary to assess its performance for the simulation of rarefied gas flows. Our numerical simulations based on the accurate discrete velocity method suggest that the accuracy of the MRT-LBM is reduced significantly in the simulation of rarefied gas flows through the rough surface and porous media. Our simulation results could serve as benchmarking cases for future development of the LBM for modeling and simulation of rarefied gas flows in complex geometries.

Comparative study of the discrete velocity and lattice Boltzmann methods for rarefied gas flows through irregular channels.

PubMed

Su, Wei; Lindsay, Scott; Liu, Haihu; Wu, Lei

2017-08-01

Rooted from the gas kinetics, the lattice Boltzmann method (LBM) is a powerful tool in modeling hydrodynamics. In the past decade, it has been extended to simulate rarefied gas flows beyond the Navier-Stokes level, either by using the high-order Gauss-Hermite quadrature, or by introducing the relaxation time that is a function of the gas-wall distance. While the former method, with a limited number of discrete velocities (e.g., D2Q36), is accurate up to the early transition flow regime, the latter method (especially the multiple relaxation time (MRT) LBM), with the same discrete velocities as those used in simulating hydrodynamics (i.e., D2Q9), is accurate up to the free-molecular flow regime in the planar Poiseuille flow. This is quite astonishing in the sense that less discrete velocities are more accurate. In this paper, by solving the Bhatnagar-Gross-Krook kinetic equation accurately via the discrete velocity method, we find that the high-order Gauss-Hermite quadrature cannot describe the large variation in the velocity distribution function when the rarefaction effect is strong, but the MRT-LBM can capture the flow velocity well because it is equivalent to solving the Navier-Stokes equations with an effective shear viscosity. Since the MRT-LBM has only been validated in simple channel flows, and for complex geometries it is difficult to find the effective viscosity, it is necessary to assess its performance for the simulation of rarefied gas flows. Our numerical simulations based on the accurate discrete velocity method suggest that the accuracy of the MRT-LBM is reduced significantly in the simulation of rarefied gas flows through the rough surface and porous media. Our simulation results could serve as benchmarking cases for future development of the LBM for modeling and simulation of rarefied gas flows in complex geometries.

Impact of waves on the circulation flow in the Iguasu gas centrifuge

NASA Astrophysics Data System (ADS)

Bogovalov, S.; Kislov, V.; Tronin, I.

2017-01-01

2D axisymmetric transient flow induced by a pulsed braking force in the Iguasu gas centrifuge (GC) is simulated numerically. The simulation is performed for two cases: transient and stationary. The braking forces averaged over the period of rotation are equal to each other in both cases. The transient case is compared with the stationary case where the flow is excited by the stationary braking force.Two models of the gas cenrifuge is simulated. There are two cameras in the first model and three cameras in the second one. In the transient case for the two cameras model pulsations almost doubles the axial circulation flux in the working camera. In the transient case for the three cameras model the gas flux through the gap in the bottom baffle exceeds on 15 % the same flux in the stationary case for the same gas content and temperature at the walls of the rotor. We argue that the waves can reduce the gas content in the GC on the same 15 %.

Stability investigations of relaxing molecular gas flows. Results and perspectives

NASA Astrophysics Data System (ADS)

Grigor'ev, Yurii N.; Ershov, Igor V.

2017-10-01

This article presents results of systematic investigations of a dissipative effect which manifests itself as the growth of hydrodynamic stability and suppression of turbulence in relaxing molecular gas flows. The effect can be a new way for control stability and laminar turbulent transition in aerodynamic flows. The consideration of suppression of inviscid acoustic waves in 2D shear flows is presented. Nonlinear evolution of large-scale vortices and Kelvin — Helmholtz waves in relaxing shear flows are studied. Critical Reynolds numbers in supersonic Couette flows are calculated analytically and numerically within the framework of both classical linear and nonlinear energy hydrodynamic stability theories. The calculations clearly show that the relaxation process can appreciably delay the laminar-turbulent transition. The aim of this article is to show the new dissipative effect, which can be used for flow control and laminarization.

Study on Gas-liquid Falling Film Flow in Internal Heat Integrated Distillation Column

NASA Astrophysics Data System (ADS)

Liu, Chong

2017-10-01

Gas-liquid internally heat integrated distillation column falling film flow with nonlinear characteristics, study on gas liquid falling film flow regulation control law, can reduce emissions of the distillation column, and it can improve the quality of products. According to the distribution of gas-liquid mass balance internally heat integrated distillation column independent region, distribution model of heat transfer coefficient of building internal heat integrated distillation tower is obtained liquid distillation falling film flow in the saturated vapour pressure of liquid water balance, using heat transfer equation and energy equation to balance the relationship between the circulating iterative gas-liquid falling film flow area, flow parameter information, at a given temperature, pressure conditions, gas-liquid flow falling film theory makes the optimal parameters to achieve the best fitting value with the measured values. The results show that the geometric gas-liquid internally heat integrated distillation column falling film flow heat exchange area and import column thermostat, the average temperature has significant. The positive correlation between the heat exchanger tube entrance due to temperature difference between inside and outside, the heat flux is larger, with the increase of internal heat integrated distillation column temperature, the slope decreases its temperature rise, which accurately describes the internal gas-liquid heat integrated distillation tower falling film flow regularity, take appropriate measures to promote the enhancement of heat transfer. It can enhance the overall efficiency of the heat exchanger.

A Physical Model Study of Two-Phase Gas-Liquid Flows in a Ladle Shroud

NASA Astrophysics Data System (ADS)

Singh, Prince K.; Mazumdar, Dipak

2018-06-01

Argon-steel flows inside a ladle shroud during teeming from a ladle to a tundish have been modelled physically. To this end, full-scale Perspex models of bloom as well as slab casting shrouds (BCS and SCS), operating with air and water, have been applied. Both open to air as well as immersed conditions were investigated with and without gas injection. Flows inside a ladle shroud under open to air and immersed conditions were found to be substantially different with a strong function of gas and liquid flow rates, collector nozzle and shroud diameters. Depending on the volumetric gas injection rate relative to liquid flow rate, different flow regimes have been observed in an immersed shroud [ i.e., 0 < ( ds/L_{s} ) ≤ 0.24 ]. At extremely low gas flow rates, [ i.e., ( Qg/Q_{L} ) ≤ 0.02 ], injected gas is completely entrained as bubbles by the down-flowing liquid resulting in a bubbly two-phase flow over the entire length of a shroud. However, with an increasing gas flow rate, two distinctly different regions start to develop within the shroud body: a free liquid jet in the upper part and a gas-liquid mixing zone below. The length of the free jet increases with an increasing gas flow rate and at significantly higher gas to liquid flow rates [ viz., ( Qg/Q_{L} )_{BCS} ≥ 0.42 ] and [ viz., ( Qg/Q_{L} )_{SCS} ≥ 0.30 ] , and the free jet is found to prevail over the entire length of the shroud. Within the range of conditions studied, it is observed that the free jet length or the line of demarcation between the jetting and two-phase mixing zone depends on gas and liquid flow rates and is specific to a particular shroud-collector nozzle system. Physical model results further indicate that a sufficiently large free jet length ( shroud length) tends to create a high pressure region inside a shroud and prevent ingression of air. Possible implications of the present findings with reference to industrial teeming practices are also discussed in the text.

Field calibration of orifice meters for natural gas flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ting, V.C.; Shen, J.J.S.

1989-03-01

This paper presents the orifice calibration results for nominal 15.24, 10.16, and 5.08-cm (6,4,2-in.) orifice meters conducted at the Chevron's Sand Hills natural gas flow measurement facility in Crane, Texas. Over 200 test runs were collected in a field environment to study the accuracy of the orifice meters. Data were obtained at beta ratios ranging from 0.12 to 0.74 at the nominal conditions of 4576 kPa and 27{sup 0}C (650 psig and 80{sup 0}F) with a 0.57 specific gravity processed, pipeline quality natural gas. A bank of critical flow nozzles was used as the flow rate proving device to calibratemore » the orifice meters. Orifice discharge coefficients were computed with ANSI/API 2530-1985 (AGA3) and ISO 5167/ASME MFC-3M-1984 equations for every set of data points. With the orifice bore Reynolds numbers ranging from 1 to 9 million, the Sand Hills calibration data bridge the gap between the Ohio State water data at low Reynolds numbers and Chevron's high Reynolds number test data taken at a large test facility in Venice, Louisiana. The test results also successfully demonstrate that orifice meters can be accurately proved with critical flow nozzles under realistic field conditions.« less

A pressure-driven flow analysis of gas trapping behavior in nanocomposite thermite films

NASA Astrophysics Data System (ADS)

Sullivan, K. T.; Bastea, S.; Kuntz, J. D.; Gash, A. E.

2013-10-01

This article is in direct response to a recently published article entitled Electrophoretic deposition and mechanistic studies of nano-Al/CuO thermites (K. T. Sullivan et al., J. Appl. Phys., 112(2), 2012), in which we introduced a non-dimensional parameter as the ratio of gas production to gas escape within a thin porous thermite film. In our original analysis, we had treated the problem as Fickian diffusion of gases through the porous network. However, we believe a more physical representation of the problem is to treat this as pressure-driven flow of gases in a porous medium. We offer a new derivation of the non-dimensional parameter which calculates gas velocity using the well-known Poiseuille's Law for pressure-driven flow in a pipe. This updated analysis incorporates the porosity, gas viscosity, and pressure gradient into the equation.

Characterization of annular two-phase gas-liquid flows in microgravity

NASA Technical Reports Server (NTRS)

Bousman, W. Scott; Mcquillen, John B.

1994-01-01

A series of two-phase gas-liquid flow experiments were developed to study annular flows in microgravity using the NASA Lewis Learjet. A test section was built to measure the liquid film thickness around the perimeter of the tube permitting the three dimensional nature of the gas-liquid interface to be observed. A second test section was used to measure the film thickness, pressure drop and wall shear stress in annular microgravity two-phase flows. Three liquids were studied to determine the effects of liquid viscosity and surface tension. The result of this study provide insight into the wave characteristics, pressure drop and droplet entrainment in microgravity annular flows.

Effects of Mass Flow Rate on the Thermal-Flow Characteristics of Microwave CO2 Plasma.

PubMed

Hong, Chang-Ki; Na, Young-Ho; Uhm, Han-Sup; Kim, Youn-Jea

2015-03-01

In this study, the thermal-flow characteristics of atmospheric pressure microwave CO2 plasma were numerically investigated by simulation. The electric and gas flow fields in the reaction chamber with a microwave axial injection torch operated at 2.45 GHz were simulated. The microwave launcher had the standard rectangular waveguide WR340 geometry. The simulation was performed by using the COMSOL Multiphysics plasma model with various mass flow rates of CO2. The electric fields, temperature profiles and the density of electrons were graphically depicted for different CO2 inlet mass flow rates.

Theoretical gain optimization studies in 10. 6. mu. m CO/sub 2/--N/sub 2/ gasdynamic lasers. IV. Further results of parametric study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reddy, K.P.J.; Reddy, N.M.

1984-01-01

Based on a method proposed by Reddy and Shanmugasundaram, similar solutions have been obtained for the steady inviscid quasi-one-dimensional nonreacting flow in the supersonic nozzle of CO/sub 2/--N/sub 2/--H/sub 2/O and CO/sub 2/--N/sub 2/--He gasdynamic laser systems. Instead of using the correlations of a nonsimilar function N/sub S/ for pure N/sub 2/ gas, as is done in previous publications, the N/sub S/ correlations are computed here for the actual gas mixtures used in the gasdynamic lasers. Optimum small-signal optical gain and the corresponding optimum values of the operating parameters like reservoir pressure and temperature and nozzle area ratio are computedmore » using these correlations. The present results are compared with the previous results and the main differences are discussed.« less

Pore-scale mechanisms of gas flow in tight sand reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Silin, D.; Kneafsey, T.J.; Ajo-Franklin, J.B.

2010-11-30

Tight gas sands are unconventional hydrocarbon energy resource storing large volume of natural gas. Microscopy and 3D imaging of reservoir samples at different scales and resolutions provide insights into the coaredo not significantly smaller in size than conventional sandstones, the extremely dense grain packing makes the pore space tortuous, and the porosity is small. In some cases the inter-granular void space is presented by micron-scale slits, whose geometry requires imaging at submicron resolutions. Maximal Inscribed Spheres computations simulate different scenarios of capillary-equilibrium two-phase fluid displacement. For tight sands, the simulations predict an unusually low wetting fluid saturation threshold, at whichmore » the non-wetting phase becomes disconnected. Flow simulations in combination with Maximal Inscribed Spheres computations evaluate relative permeability curves. The computations show that at the threshold saturation, when the nonwetting fluid becomes disconnected, the flow of both fluids is practically blocked. The nonwetting phase is immobile due to the disconnectedness, while the permeability to the wetting phase remains essentially equal to zero due to the pore space geometry. This observation explains the Permeability Jail, which was defined earlier by others. The gas is trapped by capillarity, and the brine is immobile due to the dynamic effects. At the same time, in drainage, simulations predict that the mobility of at least one of the fluids is greater than zero at all saturations. A pore-scale model of gas condensate dropout predicts the rate to be proportional to the scalar product of the fluid velocity and pressure gradient. The narrowest constriction in the flow path is subject to the highest rate of condensation. The pore-scale model naturally upscales to the Panfilov's Darcy-scale model, which implies that the condensate dropout rate is proportional to the pressure gradient squared. Pressure gradient is the greatest near

Flow fields of low pressure vent exhausts

NASA Technical Reports Server (NTRS)

Scialdone, John J.

1990-01-01

The flow field produced by low pressure gas vents are described based on experimental data obtained from tests in a large vacuum chamber. The gas density, pressure, and flux at any location in the flow field are calculated based on the vent plume description and the knowledge of the flow rate and velocity of the venting gas. The same parameters and the column densities along a specified line of sight traversing the plume are also obtained and shown by a computer generated graphical representation. The fields obtained with a radically scanning Pitot probe within the exhausting gas are described by a power of the cosine function, the mass rate, and the distance from the exit port. The field measurements were made for gas at pressures ranging from 2 to 50 torr venting from pipe fittings with diameters to 3/16 to 1-1/2 inches I.D. (4.76 to 38.1 mm). The N2 mass flow rates ranged from 2E-4 to 3.7E-1 g/s.