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Sample records for news emulsion liquid

  1. Research News: Emulsion Liquid Membrane Extraction in a Hollow-Fiber Contactor

    NASA Technical Reports Server (NTRS)

    Wiencek, John M.; Hu, Shih-Yao

    2000-01-01

    This article describes how ELMs (emulsion liquid membranes) can be used for extraction. The article addresses the disadvantages of ELM extraction in a stirred contactor, and the advantages of SELMs (supported emulsion liquid membranes). The introduction of the article provides background information on liquid-liquid solvent extraction and dispersion-free solvent extraction.

  2. NEWS: Nuclear emulsion WIMP search

    NASA Astrophysics Data System (ADS)

    Alexandrov, A.; Asada, T.; D'Ambrosio, N.; De Lellis, G.; Di Crescenzo, A.; Di Marco, N.; Furuya, S.; Gentile, V.; Hakamata, K.; Ishikawa, M.; Katsuragawa, T.; Kuwabara, K.; Machii, S.; Naka, T.; Pupilli, F.; Sirignano, C.; Tawara, Y.; Tioukov, V.; Umemoto, A.; Yoshimoto, M.

    2015-01-01

    The most convincing candidate as main constituent of the dark matter in the Universe consists of Weakly Interacting Massive Particles (WIMPs). WIMPs must be electrically neutral and interact with a very low cross-section ( σ<10^{-40} cm2) which makes them detectable in direct searches only through the observation of nuclear recoils induced by the WIMP rare scatterings. In the experiments carried out so far, recoiled nuclei are searched for as a signal over a background produced by Compton electrons and neutron scatterings. Signal found by some experiments have not been confirmed by other techniques. We propose an R&D program for a new experimental method able to observe the track of the scattered nucleus based on new developments in the nuclear emulsion technique. Nuclear emulsions would act both as the WIMP target and as the tracking detector able to reconstruct the direction of the recoiled nucleus. This unique characteristic would provide a new and unambiguous signature of the presence of the dark matter in our galaxy.

  3. NEWS: Nuclear Emulsions for WIMP Search

    NASA Astrophysics Data System (ADS)

    Di Marco, Natalia; NEWS Collaboration

    2016-05-01

    In the field of direct Dark Matter search a different and promising approach is the directionality: the observation of the incoming apparent direction of WIMPs would in fact provide a new and unambiguous signature. The NEWS project is a very innovative approach for a high sensitivity experiment aiming at the directional detection of WIMPs: the detector is based on a novel emulsion technology called NIT (Nano Imaging Trackers) acting both as target and tracking device. In this paper we illustrate the features of a NIT-based detector and the newly developed read-out systems allowing to reach a spatial resolution of the order of 10 nm. We present the background studies and the experimental design. Finally we report about the time schedule of the experiment and the expected sensitivity for DM searches.

  4. Evaporation from an ionic liquid emulsion.

    PubMed

    Friberg, Stig E

    2007-03-15

    The conditions during evaporation in a liquid crystal-in-ionic liquid microemulsion (LC/microEm) were estimated using the phase diagram of the system. The equations for selected tie lines were established and the coordinates calculated for the sites, at which the evaporation lines crossed the tie lines. These values combined with the coordinates for the phases connecting the tie lines were used to calculate the amounts and the composition of the fractions of the two phases present in the emulsion during the evaporation. One of the emulsion phases was a lamellar liquid crystal and high energy emulsification would lead to the liquid crystal being disrupted to form vesicles. Such a system tenders a unique opportunity to study the interaction between vesicles and normal micelles, which gradually change to inverse micelles over bi-continuous structures. The amount of vesicles in the liquid phase versus the fraction liquid crystal was calculated for two extreme cases of vesicle core size and shell thickness. The limit of evaporation while retaining the vesicle structure was calculated for emulsions of different original compositions assuming the minimum continuous liquid phase to be 50% of the emulsion. PMID:17207810

  5. Rejuvenation of Spent Media via Supported Emulsion Liquid Membranes

    NASA Technical Reports Server (NTRS)

    Wiencek, John M.

    2002-01-01

    The overall goal of this project was to maximize the reuseability of spent fermentation media. Supported emulsion liquid membrane separation, a highly efficient extraction technique, was used to remove inhibitory byproducts during fermentation; thus, improve the yield while reducing the need for fresh water. The key objectives of this study were: (1) Develop an emulsion liquid membrane system targeting low molecular weight organic acids which has minimal toxicity on a variety of microbial systems. (2) Conduct mass transfer studies to allow proper modeling and design of a supported emulsion liquid membrane system. (3) Investigate the effect of gravity on emulsion coalescence within the membrane unit. (4) Access the effect of water re-use on fermentation yields in a model microbial system. and (5) Develop a perfusion-type fermentor utilizing a supported emulsion liquid membrane system to control inhibitory fermentation byproducts (not completed due to lack of funds)

  6. Synthetic Polymers at Interfaces: Monodisperse Emulsions Multiple Emulsions and Liquid Marbles

    NASA Astrophysics Data System (ADS)

    Sun, Guanqing

    The adsorption of polymeric materials at interfaces is an energetically favorable process which is investigated in much diversified fields, such as emulsions, bubbles, foams, liquid marbles. Pickering emulsion, which is emulsion stabilized by solid particles has been investigated for over one century and preparation of Pickering emulsion with narrow size distribution is crucial for both the theoretical study of the stabilization mechanism and practical application, such as templated fabrication of colloidosomes. The precise control over the size and functionality of polymer latices allows the preparation of monodisperse Pickering emulsions with desired sizes through SPG membrane emulsification at rather rapid rate compared to microfludic production. Double or multiple emulsions have long been investigated but its rapid destabilization has always been a major obstacle in applying them into practical applications. The modern living polymerization techniques allow us to prepare polymers with designed structure of block copolymers which makes it possible to prepare ultra-stable multiple emulsions. The precise tuning of the ratio of hydrophobic part over the hydrophilic can unveil the stabilization mechanism. Liquid marble is a new type of materials of which liquid droplets are coated by dry particles. The coating of an outer layer of dry particles renders the liquid droplets non-sticky at solid surface which is useful in transportation of small amount of liquid without leakage at extreme low friction force. The property of liquid marbles relies largely on the stabilizers and the drying condition of polymeric latices is shown to have great influence on the property of liquid marbles. Firstly, an introduction to the interfacial and colloidal science with special attention to topics on emulsions, multiple emulsion and liquid marbles is given in Chapter 1. The unique features of an interface and a discussion on the definition of colloids are introduced prior to the

  7. Rejuvenation of Spent Media via Supported Emulsion Liquid Membranes

    NASA Technical Reports Server (NTRS)

    Wiencek, John M.

    2002-01-01

    The overall goal of this project is to maximize the reuseability of spent fermentation media. Supported emulsion liquid membrane separation, a highly efficient extraction technique, is used to remove inhibitory byproducts during fermentation; thus, improving the yield while reducing the need for fresh water. The key objectives of this study are: Develop an emulsion liquid membrane system targeting low molecular weight organic acids which has minimal toxicity on a variety of microbial systems; Conduct mass transfer studies to allow proper modeling and design of a supported emulsion liquid membrane system; Investigate the effect of gravity on emulsion coalescence within the membrane unit; Access the effect of water re-use on fermentation yields in a model microbial system; Develop a perfusion-type fermentor utilizing a supported emulsion liquid membrane system to control inhibitory fermentation byproducts; Work for the coming year will focus on the determination of toxicity of various solvents, selection of the emulsifying agents, as well as characterizing the mass transfer of hollow-fiber contactors.

  8. Removal of pesticides from aqueous solutions using liquid membrane emulsions

    SciTech Connect

    Norwood, V.M. III

    1991-12-31

    Extractive liquid membrane technology is based on a water-in-oil emulsion as the vehicle to effect separation. An aqueous internal reagent phase is emulsified into an organic phase containing a surfactant and optional complexing agents. The emulsion, presenting a large membrane surface area, is then dispersed in an aqueous continuous phase containing the species to be removed. The desired species is transferred from the continuous, phase through the organic liquid membrane and concentrated in the internal reagent phase. Extraction and stripping occur simultaneously rather than sequentially as in conventional solvent extraction. Experiments were conducted to assess the feasibility of using liquid membranes to extract pesticides from rinsewaters typical of those generated by fertilizer/agrichemical dealers. A liquid membrane emulsion containing 10% NaOH as the internal reagent phase was used to extract herbicides from aqueous solution at a continuous phase:emulsion ratio of 5:1. Removals of 2,4-D, MCPA, Carbaryl, Diazinon, and Atrazine were investigated.

  9. Removal of pesticides from aqueous solutions using liquid membrane emulsions

    SciTech Connect

    Norwood, V.M. III.

    1991-01-01

    Extractive liquid membrane technology is based on a water-in-oil emulsion as the vehicle to effect separation. An aqueous internal reagent phase is emulsified into an organic phase containing a surfactant and optional complexing agents. The emulsion, presenting a large membrane surface area, is then dispersed in an aqueous continuous phase containing the species to be removed. The desired species is transferred from the continuous, phase through the organic liquid membrane and concentrated in the internal reagent phase. Extraction and stripping occur simultaneously rather than sequentially as in conventional solvent extraction. Experiments were conducted to assess the feasibility of using liquid membranes to extract pesticides from rinsewaters typical of those generated by fertilizer/agrichemical dealers. A liquid membrane emulsion containing 10% NaOH as the internal reagent phase was used to extract herbicides from aqueous solution at a continuous phase:emulsion ratio of 5:1. Removals of 2,4-D, MCPA, Carbaryl, Diazinon, and Atrazine were investigated.

  10. Hierarchical Organization in Liquid Crystal-in-Liquid Crystal Emulsions

    PubMed Central

    Mushenheim, Peter C.

    2014-01-01

    We report the formation and characterization of hierarchical ordering in systems comprised of micrometer-sized droplets of thermotropic nematic liquid crystals (LCs) dispersed in continuous nematic phases of a lyotropic chromonic LC (disodium cromoglycate (DSCG)). Significantly, we find the orientations of the two LC phases to be coupled, with nematic droplets of 4′-pentyl-4-cyanobiphenyl (5CB) exhibiting a bipolar configuration with an axis of symmetry aligned orthogonal to the far-field director of the DSCG phase. We determine that this coupling of orientations does not result from either anisometric LC droplet shape or interfacial ionic phenomena but rather is consistent with the influence of van der Waals interactions that arise from the anisotropic polarizabilities of nematic 5CB (Δn = + 0.18) and DSCG (Δn = − 0.02) phases. We also find that it is possible to rotate and uniformly align the nematic droplets by using a weak magnetic field (B ∼ 0.3 T). An analysis of the dynamics of relaxation of the orientations of the 5CB droplets following removal of the magnetic field reveals the DSCG and 5CB droplets to be coupled by energies of ∼104kT, consistent with a simple theoretical estimate of the influence of anisotropic van der Waals interactions. We also observed the nematic 5CB droplets to form dimers and larger assemblies mediated by the elasticity of the nematic DSCG. Overall, these results reveal that LC-in-LC emulsions define a new class of hierarchically ordered soft matter in which both thermotropic and lyotropic LCs are coupled in their ordering. PMID:25278032

  11. Hierarchical organization in liquid crystal-in-liquid crystal emulsions.

    PubMed

    Mushenheim, Peter C; Abbott, Nicholas L

    2014-11-21

    We report the formation and characterization of hierarchical ordering in systems comprised of micrometer-sized droplets of thermotropic nematic liquid crystals (LCs) dispersed in continuous nematic phases of a lyotropic chromonic LC (disodium cromoglycate (DSCG)). Significantly, we find the orientations of the two LC phases to be coupled, with nematic droplets of 4'-pentyl-4-cyanobiphenyl (5CB) exhibiting a bipolar configuration with an axis of symmetry aligned orthogonal to the far-field director of the DSCG phase. We determine that this coupling of orientations does not result from either anisometric LC droplet shape or interfacial ionic phenomena but rather is consistent with the influence of van der Waals interactions that arise from the anisotropic polarizabilities of nematic 5CB (Δn = +0.18) and DSCG (Δn = -0.02) phases. We also find that it is possible to rotate and uniformly align the nematic droplets by using a weak magnetic field (B ∼ 0.3 T). An analysis of the dynamics of relaxation of the orientations of the 5CB droplets following removal of the magnetic field reveals the DSCG and 5CB droplets to be coupled by energies of ∼10(4) kT, consistent with a simple theoretical estimate of the influence of anisotropic van der Waals interactions. We also observed the nematic 5CB droplets to form dimers and larger assemblies mediated by the elasticity of the nematic DSCG. Overall, these results reveal that LC-in-LC emulsions define a new class of hierarchically ordered soft matter in which both thermotropic and lyotropic LCs are coupled in their ordering. PMID:25278032

  12. Feasibility of Surfactant-Free Supported Emulsion Liquid Membrane Extraction

    NASA Technical Reports Server (NTRS)

    Hu, Shih-Yao B.; Li, Jin; Wiencek, John M.

    2001-01-01

    Supported emulsion liquid membrane (SELM) is an effective means to conduct liquid-liquid extraction. SELM extraction is particularly attractive for separation tasks in the microgravity environment where density difference between the solvent and the internal phase of the emulsion is inconsequential and a stable dispersion can be maintained without surfactant. In this research, dispersed two-phase flow in SELM extraction is modeled using the Lagrangian method. The results show that SELM extraction process in the microgravity environment can be simulated on earth by matching the density of the solvent and the stripping phase. Feasibility of surfactant-free SELM (SFSELM) extraction is assessed by studying the coalescence behavior of the internal phase in the absence of the surfactant. Although the contacting area between the solvent and the internal phase in SFSELM extraction is significantly less than the area provided by regular emulsion due to drop coalescence, it is comparable to the area provided by a typical hollow-fiber membrane. Thus, the stripping process is highly unlikely to become the rate-limiting step in SFSELM extraction. SFSELM remains an effective way to achieve simultaneous extraction and stripping and is able to eliminate the equilibrium limitation in the typical solvent extraction processes. The SFSELM design is similar to the supported liquid membrane design in some aspects.

  13. Stabilization of Pickering emulsions by generating complex colloidal layers at liquid-liquid interfaces.

    PubMed

    Lee, Geun Ju; Son, Han Am; Cho, Jang Woo; Choi, Sang Koo; Kim, Hyun Tae; Kim, Jin Woong

    2014-01-01

    Typical Pickering emulsions accumulate particles to form a robust colloidal layer at an immiscible liquid-liquid interface. However, if the particles are smaller than tens of nanometers, they have a tendency toward coming off from the interface, thereby destabilizing emulsion drops. To solve this problem, a technique that can make the adsorbed nanoparticles stay at the interface should be developed. This study introduces a practical method that allows us to obtain a mechanically stable Pickering emulsions; n-decane was emulsified to form an oil-in-water emulsion of which interface was stabilized with a complex colloidal layer consisting of 12 nm-sized silica nanoparticles, a poly(vinyl alcohol) binder, and an alkyl-chained silane coupling agent. We have found that in the conditions of high salinity, the emulsion drops attract each other and form an emulsion gel phase. However, even in such harsh conditions, the complex silica layer maintains its original structure at the interface, thus stabilizing the emulsion drop against coalescence. PMID:24183436

  14. Emulsion-templated liquid core-polymer shell microcapsule formation.

    PubMed

    Ao, Zhuo; Yang, Zhi; Wang, Jianfang; Zhang, Guangzhao; Ngai, To

    2009-03-01

    The fabrication of hollow microspheres to encapsulate functional molecules, such as drugs, insecticides, and proteins, is of ever-increasing importance. Many chemical and physicochemical methods have been tested for various specific encapsulations, but most of them have not been developed into an industrial process. In this work, we present a straightforward method to prepare liquid core-polymer shell microcapsules by first templating an oil-in-water emulsion stabilized by an interfacial monolayer of polystyrene latex particles (often referred to as "Pickering emulsion"), and subsequently locking the assembled particles into a robust polymeric shell through the precipitation of a biodegradable polymer poly(lactic-co-glycolic acid) (PLGA) at the interface. The resultant microcapsules that have a solid polymeric enveloped around the oil droplets are stable and retain their integrity during the drying in air. Therefore, they should have great potential to serve as vehicles for encapsulating functional molecules especially hydrophobic in nature. PMID:19437681

  15. Counter current "emulsion flow" extractor for continuous liquid-liquid extraction from suspended solutions.

    PubMed

    Yanase, Nobuyuki; Naganawa, Hirochika; Nagano, Tetsushi; Noro, Junji

    2011-01-01

    A single current "emulsion flow" liquid-liquid extraction apparatus has a head with a number of holes from which micrometer-sized droplets of an aqueous phase spout into an organic phase to mix the two liquid phases. For practical use, however, a fatal problem can occur when particulate components in the aqueous phase plug the holes. In the present study, we have succeeded in solving the problem by applying a counter current-type emulsion flow extractor where micrometer-sized droplets of the organic phase are generated. PMID:21415518

  16. Controllable gas/liquid/liquid double emulsions in a dual-coaxial microfluidic device.

    PubMed

    Xu, Jian-Hong; Chen, Ran; Wang, Yun-Dong; Luo, Guang-Sheng

    2012-05-01

    This article presents a simple and novel approach to prepare monodispersed gas-in-oil-in-water (G/O/W) and gas-in-water-in-oil (G/W/O) double-emulsions in the same dual-coaxial microfluidic device. The effects of three phase flow rates on the sizes of microbubbles and droplets and the number of the encapsulated microbubbles were systematically studied. We successfully synthesized two different types of gas/liquid/liquid (G/L/L) double emulsions with different inner structures in the same geometry by adjusting the flow rates sequentially. Mathematical models were developed to predict the size and structures of the double emulsions. This simple approach gives a new idea for preparing hollow and porous microspheres with microbubbles as the direct core/pores templates. PMID:22508390

  17. Role of asphaltenes in stabilizing thin liquid emulsion films.

    PubMed

    Tchoukov, Plamen; Yang, Fan; Xu, Zhenghe; Dabros, Tadeusz; Czarnecki, Jan; Sjöblom, Johan

    2014-03-25

    Drainage kinetics, thickness, and stability of water-in-oil thin liquid emulsion films obtained from asphaltenes, heavy oil (bitumen), and deasphalted heavy oil (maltenes) diluted in toluene are studied. The results show that asphaltenes stabilize thin organic liquid films at much lower concentrations than maltenes and bitumen. The drainage of thin organic liquid films containing asphaltenes is significantly slower than the drainage of the films containing maltenes and bitumen. The films stabilized by asphaltenes are much thicker (40-90 nm) than those stabilized by maltenes (∼10 nm). Such significant variation in the film properties points to different stabilization mechanisms of thin organic liquid films. Apparent aging effects, including gradual increase of film thickness, rigidity of oil/water interface, and formation of submicrometer size aggregates, were observed for thin organic liquid films containing asphaltenes. No aging effects were observed for films containing maltenes and bitumen in toluene. The increasing stability and lower drainage dynamics of asphaltene-containing thin liquid films are attributed to specific ability of asphaltenes to self-assemble and form 3D network in the film. The characteristic length of stable films is well beyond the size of single asphaltene molecules, nanoaggregates, or even clusters of nanoaggregates reported in the literature. Buildup of such 3D structure modifies the rheological properties of the liquid film to be non-Newtonian with yield stress (gel like). Formation of such network structure appears to be responsible for the slower drainage of thin asphaltenes in toluene liquid films. The yield stress of liquid film as small as ∼10(-2) Pa is sufficient to stop the drainage before the film reaches the critical thickness at which film rupture occurs. PMID:24564447

  18. Influence of PEG-12 Dimethicone addition on stability and formation of emulsions containing liquid crystal.

    PubMed

    Andrade, F F; Santos, O D H; Oliveira, W P; Rocha-Filho, P A

    2007-06-01

    Oil/water emulsions, containing liquid crystals, were developed employing Andiroba oil, PEG-12 Dimethicone and Crodafos CES. It was evaluated the influence of silicone surfactants on the emulsions stability and on the formation of liquid crystalline phases and therefore, physicochemical characteristics, such as rheology and zeta potential, were evaluated. Emulsions were prepared by the emulsions phase inversion method. All the formulations presented lamellar liquid crystalline phases. The PEG-12 Dimethicone addition did not change microscopically the liquid crystalline phases. The emulsions containing silicone demonstrated lower viscosity than those without the additive. This is an important feature, as the silicone did not change the rheological profile; however, the addition of silicone still can be used as a viscosity controller. The formulations had their viscosity increased 15 and 150 days after their preparation. This characteristic shows that the emulsions have their organization increased along the storing time. In the analysis of zeta potential, we could verify that all formulations presented negative values between -39.7 and -70.0 mV. Within this range of values, the emulsion physical stability is high (Fig. 10). It was concluded that the addition of PEG-12 Dimethicone kept the liquid crystalline phase of the emulsion obtained with Crodafos CES, influencing in a positive way in the system stability. PMID:18489351

  19. Liquid crystal Janus emulsion droplets: preparation, tumbling, and swimming.

    PubMed

    Jeong, Joonwoo; Gross, Adam; Wei, Wei-Shao; Tu, Fuquan; Lee, Daeyeon; Collings, Peter J; Yodh, A G

    2015-09-14

    This study introduces liquid crystal (LC) Janus droplets. We describe a process for the preparation of these droplets, which consist of nematic LC and polymer compartments. The process employs solvent-induced phase separation in emulsion droplets generated by microfluidics. The droplet morphology was systematically investigated and demonstrated to be sensitive to the surfactant concentration in the background phase, the compartment volume ratio, and the possible coalescence of multiple Janus droplets. Interestingly, the combination of a polymer and an anisotropic LC introduces new functionalities into Janus droplets, and these properties lead to unusual dynamical behaviors. The different densities and solubilities of the two compartments produce gravity-induced alignment, tumbling, and directional self-propelled motion of Janus droplets. LC Janus droplets with remarkable optical properties and dynamical behaviors thus offer new avenues for applications of Janus colloids and active soft matter. PMID:26171829

  20. Emulsion-liquid-membrane extraction of copper using a hollow-fiber contactor

    SciTech Connect

    Hu, S.Y.B.; Wiencek, J.M.

    1998-03-01

    A novel extraction technique using an emulsion liquid membrane within a hollow-fiber contactor was developed and utilized to extract copper using LIX 84 extractant. Emulsion liquid membranes are capable of extracting metals from dilute waste streams to levels much below those possible by equilibrium-limited solvent extraction. Utilizing an emulsion liquid membrane within a hollow-fiber contactor retains the advantages of emulsion-liquid-membrane extraction, namely, simultaneous extraction and stripping, while eliminating problems encountered in dispersive contacting methods, such as swelling and leakage of the liquid membrane. Mathematical models for extraction in hollow-fiber contactors were developed. The models satisfactorily predict the outcome of both simple solvent extraction and emulsion-liquid-membrane extraction of copper by LIX 84 in a hollow-fiber contactor over a wide range of conditions. Emulsion-liquid-membrane extraction performs exceptionally well when the extraction is close to equilibrium limit. It is also capable of extracting a solute f/rom very dilute solutions. Stability of the liquid membrane is not crucial when used in hollow-fiber contactors; the surfactant in liquid membrane can be reduced or even eliminated without severely impairing the performance.

  1. Micro magnetofluidics: droplet manipulation of double emulsions based on paramagnetic ionic liquids.

    PubMed

    Misuk, Viktor; Mai, Andreas; Giannopoulos, Konstantinos; Alobaid, Falah; Epple, Bernd; Loewe, Holger

    2013-12-01

    The ability to control and manipulate discrete fluid droplets by magnetic fields offers new opportunities in microfluidics. A surfactant-free and easy to realize technique for the continuous generation of double emulsion droplets, composed of an organic solvent and a paramagnetic ionic liquid, is applied. The inner phase of the emulsion droplet consists of imidazolium-based ionic liquids with either iron, manganese, nickel or dysprosium containing anions which provide paramagnetic behaviour. The double emulsion droplets are dispersed in a continuous phase of FC-40. All substances - the organic phase, the paramagnetic ionic liquid and the continuous phase -are immiscible. The magnetic properties of ionic liquids allow, through the influence of external magnetic fields, the manipulation of individual emulsion droplets such as capture and release, rotation and distortion. Arrays of magnets allow a coalescence of emulsion droplets and their subsequent mixing by flowing through an alternating permanent magnetic field. In addition, the double emulsion droplets can be split and reunified, or continuously separated into their original phases. PMID:24108233

  2. Study on removal of cadmium from wastewater by emulsion liquid membrane.

    PubMed

    Mortaheb, Hamid R; Kosuge, Hitoshi; Mokhtarani, Babak; Amini, Mohammad H; Banihashemi, Hamid R

    2009-06-15

    Removal of cadmium from wastewater using emulsion liquid membrane (ELM) is studied in the present study. A polyamine-type surfactant was used for stabilizing the emulsion phase. Tri-iso-octyl amine (TIOA) has been used as a carrier for transferring of cadmium through the membrane. The results show good performance in the separation process. To determine the optimum operation conditions, the effect of several parameters such as surfactant concentration, carrier concentration, pH of external and internal phases, oil to internal phase volume ratio, emulsion to external phase volume ratio, solvent type, solute concentration, presence of iodide and chloride in external phase, and mixing conditions have been investigated. PMID:19036507

  3. Non-aqueous emulsions stabilized by block copolymers: application to liquid disinfectant-filled elastomeric films.

    PubMed

    Riess, Gérard; Cheymol, André; Hoerner, Pierre; Krikorian, Raffi

    2004-05-20

    The emulsifying and stabilization efficiency of polybutadiene-b-poly(ethylene oxide) and poly(ter butylstyrene)-poly(ethylene oxide) diblock copolymers is examined in non-aqueous emulsions. These emulsions are formed by a dispersion of polyethylene glycol mixed with a cationic surfactant acting as a biocide, in a continuous phase of a thermoplastic elastomer (SEBS) dissolved in methylcyclohexane. Emulsions with controlled droplet size and excellent stability could be obtained, which by solvent evaporation lead to elastomeric films containing droplets of confined disinfecting liquids. PMID:15072927

  4. Fertigation with liquid fish emulsion for organic production of highbush blueberry

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Liquid fish emulsion is a common fertilizer used for organic production of highbush blueberry. The product is often applied by hand or with a sprayer but can also be injected through a drip irrigation system, otherwise referred to as fertigation. Fertigation is more efficient and less labor-intensiv...

  5. ASSESSMENT OF LIQUID EMULSION MEMBRANE FOR CLEAN UP OF AQUEOUS WASTE EFFLUENTS FROM HAZARDOUS ELEMENTS

    SciTech Connect

    El-Reefy, Sohair A.; Selim, Y.T.; Hassan, M.A.; Aly, H.F.

    2003-02-27

    Four liquid emulsion membrane (LEM) systems are given to remove different hazardous elements such as uranium, thorium, cobalt, copper, lead, and cadmium from different aqueous waste effluents. The optimum conditions for use of these systems are deduced. The potentiality of LEM for removal of hazardous pollutants from aqueous waste solutions is given.

  6. Phase and Topological Behavior of Lyotropic Chromonic Liquid Crystals in Double Emulsions

    NASA Astrophysics Data System (ADS)

    Davidson, Zoey S.; Jeong, Joonwoo; Tu, Fuquan; Lohr, Matt; Lee, Daeyeon; Collings, Peter J.; Lubensky, Tom C.; Yodh, A. G.

    2013-03-01

    Lyotropic chromonic liquid crystals, assembled by non-covalent interactions, have fascinating temperature- and concentration-dependent phase behavior. Using water-oil-water double emulsions, we are able control the inner droplet chromonic phase concentration by osmosis through the oil phase. We then study the configurations of the chromonic liquid crystal phases in droplets by varying the oil types, oil soluble surfactants, and inner droplet diameter. We employ polarization microscopy to observe resulting nematic and columnar phases of Sunset Yellow FCF, and we deduce the liquid crystal configuration of both phases within the droplets. Simulations based on Jones matrices confirm droplet appearance, and preliminary observations of chromonic liquid crystal shells in oil-water-oil double emulsions are reported. Supported by UPenn MRSEC DMR 11-20901 and NSF DMR 12-05463

  7. Application of Liquid Emulsion Membrane Technique for the Removal of As(V) from Aqueous Solutions

    NASA Astrophysics Data System (ADS)

    Binnal, Prakash; Hiremath, Poornima G.

    2012-08-01

    Liquid emulsion membrane technique was used to remove As(V) from synthetic aqueous solutions. The emulsion was composed of Aliquat 336 as an extractant, commercial kerosene as a diluent and Span 80 (Sorbiton monooleate) as an emulsifying agent. Different types of internal phases were used, namely, sodium hydroxide, sodium carbonate, ammonium bicarbonate, sodium sulphate and sodium chloride. The effect of process parameters affecting extraction efficiency, such as, initial concentration of As(V) in feed solution, pH of feed solution, concentrations of Aliquat 336 and Span 80 in membrane phase, volume ratio of stripping phase to membrane phase, concentration of internal phase, type of internal phase, volume ratio of emulsion to feed, agitation speed during extraction and time of extraction was investigated. The optimum conditions for the extraction were determined. A maximum As(V) removal rate of 97.8 was observed under optimum conditions.

  8. Optimization of cyanide extraction from wastewater using emulsion liquid membrane system by response surface methodology.

    PubMed

    Xue, Juan Qin; Liu, Ni Na; Li, Guo Ping; Dang, Long Tao

    2016-01-01

    To solve the disposal problem of cyanide wastewater, removal of cyanide from wastewater using a water-in-oil emulsion type of emulsion liquid membrane (ELM) was studied in this work. Specifically, the effects of surfactant Span-80, carrier trioctylamine (TOA), stripping agent NaOH solution and the emulsion-to-external-phase-volume ratio on removal of cyanide were investigated. Removal of total cyanide was determined using the silver nitrate titration method. Regression analysis and optimization of the conditions were conducted using the Design-Expert software and response surface methodology (RSM). The actual cyanide removals and the removals predicted using RSM analysis were in close agreement, and the optimal conditions were determined to be as follows: the volume fraction of Span-80, 4% (v/v); the volume fraction of TOA, 4% (v/v); the concentration of NaOH, 1% (w/v); and the emulsion-to-external-phase volume ratio, 1:7. Under the optimum conditions, the removal of total cyanide was 95.07%, and the RSM predicted removal was 94.90%, with a small exception. The treatment of cyanide wastewater using an ELM is an effective technique for application in industry. PMID:27533852

  9. Extraction of anionic dye from aqueous solutions by emulsion liquid membrane.

    PubMed

    Dâas, Attef; Hamdaoui, Oualid

    2010-06-15

    In this work, the extraction of Congo red (CR), an anionic disazo direct dye, from aqueous solutions by emulsion liquid membrane (ELM) was investigated. The important operational parameters governing emulsion stability and extraction behavior of dye were studied. The extraction of CR was influenced by a number of variables such as surfactant concentration, stirring speed, acid concentration in the feed solution and volume ratios of internal phase to organic phase and of emulsion to feed solution. Under most favorable conditions, practically all the CR molecules present in the feed phase were extracted even in the presence of salt (NaCl). At the optimum experimental conditions, total removal of antharaquinonic dye Acid Blue 25 was attained after only 10 min. Influence of sodium carbonate concentration as internal receiving phase on the stripping efficiency of CR was examined. The best sodium carbonate concentration in the internal phase that conducted to excellent stripping efficiency (>99%) and emulsion stability was 0.1N. The membrane recovery was total and the permeation of CR was not decreased up to seven runs. ELM process is a promising alternative to conventional methods and should increase awareness of the potential for recovery of anionic dyes. PMID:20211520

  10. 4-nitrophenol removal from aqueous solutions by emulsion liquid membranes using type I facilitation.

    PubMed

    León, G; Guzmán, M A; Miguel, B

    2013-01-01

    Nitrophenols are common organic pollutants that enter the environment during the manufacture and processing of a variety of industrial products. The removal of 4-nitrophenol (4NP) from aqueous solutions by emulsion liquid membranes using the type I facilitated transport mechanism is investigated in this paper. The liquid membrane consisted of kerosene as the organic diluent, sorbitan monooleate as the emulsifying agent and sodium hydroxide as the stripping agent. The most important operational variables governing the emulsion stability and the 4NP removal process--such as the stripper agent and surfactant concentrations, the volume ratios of membrane phase/internal phase and emulsion phase/feed phase and stirring speed - were studied and the optimal conditions of the removal process were experimentally determined. Apparent initial permeabilities of the transport process in the different operational conditions were also obtained. Ninety-eight per cent of4NP was removed in 10 minutes and an apparent initial permeability of 1.2986 min(-1) was obtained in those optimal conditions. PMID:24350486

  11. Water-in-water emulsions stabilized by non-amphiphilic interactions: polymer-dispersed lyotropic liquid crystals.

    PubMed

    Simon, Karen A; Sejwal, Preeti; Gerecht, Ryan B; Luk, Yan-Yeung

    2007-01-30

    Emulsion systems involving surfactants are mainly driven by the separation of the hydrophobic interactions of the aliphatic chains from the hydrophilic interactions of amphiphilic molecules in water. In this study, we report an emulsion system that does not include amphiphilic molecules but molecules with functional groups that are completely solvated in water. These functional groups give rise to molecular interactions including hydrogen bonding, pi stacking, and salt bridging and are segregated into a dispersion of droplets forming a water-in-water emulsion. This water-in-water emulsion consists of dispersing droplets of a water-solvated biocompatible liquid crystal--disodium cromoglycate (DSCG)--in a continuous aqueous solution containing specific classes of water-soluble polymers. Whereas aqueous solutions of polyols support the formation of emulsions of spherical droplets consisting of lyotropic liquid crystal DSCG with long-term stability (for at least 30 days), aqueous solutions of polyamides afford droplets of DSCG in the shape of prolate ellipsoids that are stable for only 2 days. The DSCG liquid crystal in spherical droplets assumes a radial configuration in which the optical axis of the liquid crystal aligns perpendicular to the surface of the droplets but assumes a tangential configuration in prolate ellipsoids in which the optical axis of the liquid crystal aligns parallel to the surface of the droplet. Other classes of water-soluble polymers including polyethers, polycations, and polyanions do not afford a stable emulsion of DSCG droplets. Both the occurrence and the stability of this unique emulsion system can be rationalized on the basis of the functional groups of the polymer. The different configurations of the liquid crystal (DSCG) droplets were also found to correlate with the strength of the hydrogen bonding that can be formed by the functional groups on the polymer. PMID:17241072

  12. Liquid clay emulsion--alternate daily cover and erosion

    SciTech Connect

    Martell, L.

    1995-12-31

    Formula 480 Biodegradable Clay Based Product, developed in 1985, is a non-toxic liquid bentonite clay product that comes in concentrate form for dilution with water and/or leachate. The concentrate allows this product y to be used for erosion and dust control, grass seeding, as well as a daily or intermediate cover for landfills. It inhibits the activities of birds and vectors, while controlling dust, erosion, odor, and blowing debris. By varying the dilution of Formula 480, the product can be set up from porous and flexible, to durable and waterproof. Having a clay base, high cation exchange capacity offers nutrient stabilization for grass seeding. When using leachate for product dilution, it will percolate, waterproof, and be recycled back into the surface as a solid. The product is economical at $.03 to $.08/sq.ft., depending on thickness of application, smoothness of surface or compaction ratio. Application is done with a self-contained sprayer developed specifically for Formula 480. It can be sprayed with a high volume handgun or an economical and efficient spray boom. This product is cleared for use in over 15 states and is currently being used on hazardous and non-hazardous fills throughout the U.S. and Germany. Ease of application, economy, and effectiveness warrants people to look at this product for many uses.

  13. Recovery of kraft lignin from pulping wastewater via emulsion liquid membrane process.

    PubMed

    Ooi, Zing-Yi; Harruddin, Norlisa; Othman, Norasikin

    2015-01-01

    Kraft lignin (KL) is a renewable source of many valuable intermediate biochemical products currently derived from petroleum. An excessive of lignin comes from pulping wastewater caused an adverse pollution problems hence affecting human and aquatic life. A comprehensive study pertaining to emulsion liquid membrane (ELM) extraction of lignin from pulping wastewater was presented. ELM formulation contains Aliquat 336 as carrier, kerosene as diluent, sodium bicarbonate (NaHCO3 ) as stripping agent and Span 80 as surfactant. The emulsion stability was investigated at different surfactant concentrations, homogenizer speed and emulsification time. Modifier (2-ethyl-1-hexanol) was added to avoid segregation of third phase while improving the emulsion stability. At optimum conditions, 95% and 56% of lignin were extracted and recovered, respectively at 10 min of extraction time, 0.007 M of Aliquat 336, 0.1 M of NaHCO3 and 1:5 of treat ratio. Additional of modifier was contributed to highest recovery up to 98%. The ELM process was found to be equally feasible and quite effective in the recovery of KL from real pulping wastewater. Therefore, ELM process provides a promising alternative technology to recover KL from pulping wastewater while solving the environmental problems simultaneously. PMID:26101101

  14. Development of a Supported Emulsion Liquid Membrane System for Propionic Acid Separation in a Microgravity Environment

    NASA Technical Reports Server (NTRS)

    Li, Jin; Hu, Shih-Yao B.; Wiencek, John M.

    2001-01-01

    Perstractive fermentation is a good way to increase the productivity of bioreactors. Using Propionibacteria as the model system, the feasibility of using supported emulsion liquid membrane (SELM) for perstractive fermentation is assessed in this study. Five industrial solvents were considered as the solvent for preparing the SELM. The more polar a solvent is, the higher the partition coefficient. However, toxicity of a solvent also increases with its polarity. CO-1055 (industrial decanol/octanol blend) has the highest partition coefficient toward propionic acid among the solvents that has no molecular toxicity toward Propionibacteria. A preliminary extraction study was conducted using tetradecane as solvent in a hydrophobic hollow fiber contactor. The result confirmed that SELM eliminates the equilibrium limitation of conventional liquid-liquid extraction, and allows the use of a non-toxic solvent with low partition coefficient.

  15. Bursting of Dilute Emulsion-Based Liquid Sheets Driven by a Marangoni Effect

    NASA Astrophysics Data System (ADS)

    Vernay, Clara; Ramos, Laurence; Ligoure, Christian

    2015-11-01

    We study the destabilization mechanism of thin liquid sheets expanding in air and show that dilute oil-in-water emulsion-based sheets disintegrate through the nucleation and growth of holes that perforate the sheet. The velocity and thickness fields of the sheet outside the holes are not perturbed by holes, and hole opening follows the Taylor-Culick law. We find that a prehole, which widens and thins out the sheet with time, systematically precedes the hole nucleation. The growth dynamics of the prehole follows the law theoretically predicted for a liquid spreading on another liquid of higher surface tension due to Marangoni stresses. Classical Marangoni spreading experiments quantitatively corroborate our findings.

  16. News

    NASA Astrophysics Data System (ADS)

    2004-03-01

    Italy’s Physics Olympiad creates greater interest and motivation House of Experiments: 'humour helps in the teaching of science' Science takes stage in Germany PPARC news: guide and awards Schools newspaper competition focuses on Venus Website offers practical advice SHAP workshop will sharpen up teachers' skills Students will soon use Faulkes Telescope North to see the stars Talk takes a tour of the universe ASE 2004 Welsh physicists share secrets Switch students on to physics Teachers Awards 2004 recognize quality of teaching AAPT spends winter in Miami sun Schools Physics Group meeting will take place at Rugby School

  17. News

    NASA Astrophysics Data System (ADS)

    2001-07-01

    AWARDS Presentations to top students; PHYSICS IN PRIMARY SCIENCE Amaze and inspire; WEB RESOURCES PhysicsClub goes live; EVENTS GIREP develops thinking; RESEARCH FRONTIERS Carbon dating may not run to time; CURRICULUM DEVELOPMENT Vocational qualifications; CURRICULUM DEVELOPMENT Flanders gears up for curriculum change; EXHIBITIONS Building the Universe; EVENTS Physics Discipline Network VII; SPECIAL NEWS FEATURE Progress in UK post-16 courses; Teaching Advancing Physics... the story so far; An outside observer's view of Advancing Physics; Student views of SHAP; Results from the SHAP pilot: successful and girl-friendly; AWARDS Royal visit to publisher;

  18. News

    NASA Astrophysics Data System (ADS)

    2001-09-01

    EPS AWARD WINNERS Award for outreach to Physics Education authors; TEACHER TRAINING Helping teachers specialize in physics; AAPT SUMMER MEETING The science of light; AAPT SUMMER MEETING Do you believe in skepticism?; E-LEARNING Massive investment in Swedish online learning; UK SCIENCE YEAR News from Science Year; 11-16 CURRICULUM Naming the energy parts; TEACHER TRAINING Electronic Discussion Group for Trainee Teachers; PUBLICATIONS Physics on Course 2002; WALES Physics in Powys; HIGHER EDUCATION HE solutions to the physics teacher shortage; SCOTLAND The 27th Scottish Stirling Meeting; NORTHERN IRELAND Belfast physics teachers' meeting; SCOTLAND Physics Summer School, Edinburgh 2001; AAPT SUMMER MEETING Physics education research: massive growth; AAPT SUMMER MEETING Just-In-Time Teaching;

  19. Rheology of a viscoelastic emulsion with a liquid crystalline polymer dispersed phase

    SciTech Connect

    Lee, H.S.; Denn, M.M. |

    1999-11-01

    The steady-shear viscosity and first normal stress difference and the dynamic storage and loss moduli have been measured for a blend consisting of a thermotropic liquid crystalline polymer dispersed in a thermoplastic fluoropolymer matrix. The components are immiscible and nonreacting. Consistency with the Palierne emulsion theory for viscoelastic blends is possible if and only if the interfacial tension contribution is negligible for droplets that are comparable in size to a liquid crystalline domain or smaller, while retaining the effect for larger droplets. Steady shear results are approximately described by the scaling of the Doi{endash}Ohta theory, but there is a significant reduction in the excess shear stress over a finite shear-rate range for the lowest concentration, which contains the smallest droplets. {copyright} {ital 1999 Society of Rheology.}

  20. Biopolymer-based structuring of liquid oil into soft solids and oleogels using water-continuous emulsions as templates.

    PubMed

    Patel, Ashok R; Rajarethinem, Pravin S; Cludts, Nick; Lewille, Benny; De Vos, Winnok H; Lesaffer, Ans; Dewettinck, Koen

    2015-02-24

    Physical trapping of a hydrophobic liquid oil in a matrix of water-soluble biopolymers was achieved using a facile two-step process by first formulating a surfactant-free oil-in-water emulsion stabilized by biopolymers (a protein and a polysaccharide) followed by complete removal of the water phase (by either high- or low-temperature drying of the emulsion) resulting in structured solid systems containing a high concentration of liquid oil (above 97 wt %). The microstructure of these systems was revealed by confocal and cryo-scanning electron microscopy, and the effect of biopolymer concentrations on the consistency of emulsions as well as the dried product was evaluated using a combination of small-amplitude oscillatory shear rheometry and large deformation fracture studies. The oleogel prepared by shearing the dried product showed a high gel strength as well as a certain degree of thixotropic recovery even at high temperatures. Moreover, the reversibility of the process was demonstrated by shearing the dried product in the presence of water to obtain reconstituted emulsions with rheological properties comparable to those of the fresh emulsion. PMID:25133865

  1. Recovery of uranium from dilute solution using liquid emulsion membrane system

    SciTech Connect

    Mukhopadhyay, S.; Ghosh, S.K.; Juvekar, V.A.

    2008-07-01

    The liquid emulsion membrane (LEM) technique has great potential for application in the nuclear industry for large interfacial area, low consumption of organics, and high recovery from dilute streams. A LEM system composed DEHPA-kerosene-SPAN80-HNO{sub 3} has been developed for recovery of uranium from dilute nitrate solution, which gives 98% extraction and 88% stripping in a single stage. An attempt has been made to understand the mechanism of the LEM process, in which phenomena like per-traction, occlusion, swelling, and leakage occur simultaneously. The effect of various parameters on these phenomena has been described with a mathematical model, which is able to explain the experimental findings. (authors)

  2. Carbonate-coordinated metal complexes precede the formation of liquid amorphous mineral emulsions of divalent metal carbonates.

    PubMed

    Wolf, Stephan E; Müller, Lars; Barrea, Raul; Kampf, Christopher J; Leiterer, Jork; Panne, Ulrich; Hoffmann, Thorsten; Emmerling, Franziska; Tremel, Wolfgang

    2011-03-01

    During the mineralisation of metal carbonates MCO3 (M=Ca, Sr, Ba, Mn, Cd, Pb) liquid-like amorphous intermediates emerge. These intermediates that form via a liquid/liquid phase separation behave like a classical emulsion and are stabilized electrostatically. The occurrence of these intermediates is attributed to the formation of highly hydrated networks whose stability is mainly based on weak interactions and the variability of the metal-containing pre-critical clusters. Their existence and compositional freedom are evidenced by electrospray ionization mass spectrometry (ESI-MS). Liquid intermediates in non-classical crystallisation pathways seem to be more common than assumed. PMID:21218241

  3. Carbonate-coordinated metal complexes precede the formation of liquid amorphous mineral emulsions of divalent metal carbonates†

    PubMed Central

    Wolf, Stephan E.; Müller, Lars; Barrea, Raul; Kampf, Christopher J.; Leiterer, Jork; Panne, Ulrich; Hoffmann, Thorsten

    2011-01-01

    During the mineralisation of metal carbonates MCO3 (M = Ca, Sr, Ba, Mn, Cd, Pb) liquid-like amorphous intermediates emerge. These intermediates that form via a liquid/liquid phase separation behave like a classical emulsion and are stabilized electrostatically. The occurrence of these intermediates is attributed to the formation of highly hydrated networks whose stability is mainly based on weak interactions and the variability of the metal-containing pre-critical clusters. Their existence and compositional freedom are evidenced by electrospray ionization mass spectrometry (ESI-MS). Liquid intermediates in non-classical crystallisation pathways seem to be more common than assumed. PMID:21218241

  4. A New Emulsion Liquid Membrane Based on a Palm Oil for the Extraction of Heavy Metals

    PubMed Central

    Björkegren, Sanna; Fassihi Karimi, Rose; Martinelli, Anna; Jayakumar, Natesan Subramanian; Hashim, Mohd Ali

    2015-01-01

    The extraction efficiency of hexavalent chromium, Cr(VI), from water has been investigated using a vegetable oil based emulsion liquid membrane (ELM) technique. The main purpose of this study was to create a novel ELM formulation by choosing a more environmentally friendly and non-toxic diluent such as palm oil. The membrane phase so formulated includes the mobile carrier tri-n-octylmethylammonium chloride (TOMAC), to facilitate the metal transport, and the hydrophilic surfactant Tween 80 to facilitate the dispersion of the ELM phase in the aqueous solution. Span 80 is used as surfactant and butanol as co-surfactant. Our results demonstrate that this novel ELM formulation, using the vegetable palm oil as diluent, is useful for the removal of hexavalent chromium with an efficiency of over 99% and is thus competitive with the already existing, yet less environmentally friendly, ELM formulations. This result was achieved with an optimal concentration of 0.1 M NaOH as stripping agent and an external phase pH of 0.5. Different water qualities have also been investigated showing that the type of water (deionized, distilled, or tap water) does not significantly influence the extraction rate. PMID:25915191

  5. A new emulsion liquid membrane based on a palm oil for the extraction of heavy metals.

    PubMed

    Björkegren, Sanna; Karimi, Rose Fassihi; Martinelli, Anna; Jayakumar, Natesan Subramanian; Hashim, Mohd Ali

    2015-01-01

    The extraction efficiency of hexavalent chromium, Cr(VI), from water has been investigated using a vegetable oil based emulsion liquid membrane (ELM) technique. The main purpose of this study was to create a novel ELM formulation by choosing a more environmentally friendly and non-toxic diluent such as palm oil. The membrane phase so formulated includes the mobile carrier tri-n-octylmethylammonium chloride (TOMAC), to facilitate the metal transport, and the hydrophilic surfactant Tween 80 to facilitate the dispersion of the ELM phase in the aqueous solution. Span 80 is used as surfactant and butanol as co-surfactant. Our results demonstrate that this novel ELM formulation, using the vegetable palm oil as diluent, is useful for the removal of hexavalent chromium with an efficiency of over 99% and is thus competitive with the already existing, yet less environmentally friendly, ELM formulations. This result was achieved with an optimal concentration of 0.1 M NaOH as stripping agent and an external phase pH of 0.5. Different water qualities have also been investigated showing that the type of water (deionized, distilled, or tap water) does not significantly influence the extraction rate. PMID:25915191

  6. Carbonate-coordinated metal complexes precede the formation of liquid amorphous mineral emulsions of divalent metal carbonates

    NASA Astrophysics Data System (ADS)

    Wolf, Stephan E.; Müller, Lars; Barrea, Raul; Kampf, Christopher J.; Leiterer, Jork; Panne, Ulrich; Hoffmann, Thorsten; Emmerling, Franziska; Tremel, Wolfgang

    2011-03-01

    During the mineralisation of metal carbonates MCO3 (M = Ca, Sr, Ba, Mn, Cd, Pb) liquid-like amorphous intermediates emerge. These intermediates that form via a liquid/liquid phase separation behave like a classical emulsion and are stabilized electrostatically. The occurrence of these intermediates is attributed to the formation of highly hydrated networks whose stability is mainly based on weak interactions and the variability of the metal-containing pre-critical clusters. Their existence and compositional freedom are evidenced by electrospray ionization mass spectrometry (ESI-MS). Liquid intermediates in non-classical crystallisation pathways seem to be more common than assumed.During the mineralisation of metal carbonates MCO3 (M = Ca, Sr, Ba, Mn, Cd, Pb) liquid-like amorphous intermediates emerge. These intermediates that form via a liquid/liquid phase separation behave like a classical emulsion and are stabilized electrostatically. The occurrence of these intermediates is attributed to the formation of highly hydrated networks whose stability is mainly based on weak interactions and the variability of the metal-containing pre-critical clusters. Their existence and compositional freedom are evidenced by electrospray ionization mass spectrometry (ESI-MS). Liquid intermediates in non-classical crystallisation pathways seem to be more common than assumed. Electronic supplementary information (ESI) available: (S1 and S5) TEM at higher magnifications and of crystallizations conducted at pH = 6.0, 9.0 and 11.3; (S2) sketch of a spreading liquid particle on a TEM grid; (S3) wide-angle scattering of BaCO3 and CdCO3; (S4 and S6-S9) ESI-MS spectra of a solution of carbon dioxide and of bicarbonates of Sr, Ba, Pb, Mn and Cd. See DOI: 10.1039/c0nr00761g

  7. Water transport in water-in-oil-in-water liquid emulsion membrane system for the separation of lactic acid

    SciTech Connect

    Mok, Y.S.; Lee, W.K. )

    1994-03-01

    Liquid emulsion membranes (LEMs) were applied to the separation of lactic acid from an aqueous feed phase, and water transport (swelling) was investigated during the separation. Considering that as lactic acid was extracted into the internal stripping phase, osmotic pressure difference across the membrane was varied, the water transfer coefficient was evaluated. The water transfer coefficient was larger at higher carrier concentration and initial lactic acid concentration, which means that emulsion swelling can also be mediated by solute/carrier complexes although it is, in general, osmotically induced. The appropriate LEM formulation was given for separation and concentration of lactic acid. If both separation and concentration are desired, evidently emulsion swelling should be considered in conjunction with the transport rate of lactic acid. It was observed that the separated solute concentration in the internal phase was lowered due to swelling during the operation. Nevertheless, lactic acid could be concentrated in the internal phase more than 6 times in specific conditions, indicating that as the volume ratio of external phase to internal phase is increased, a still higher concentration in the internal phase can be obtained. 22 refs., 10 figs., 4 tabs.

  8. Penicillin G extraction from model media using an emulsion liquid membrane: a theoretical model of product decomposition.

    PubMed

    Lee, K H; Lee, S C; Lee, W K

    1994-04-01

    To confirm the applicability for the extraction of penicillin G by an emulsion liquid membrane (ELM), the degree of decomposition of penicillin G during extraction was theoretically calculated. Decomposition was less than 1% provided that the initial sodium carbonate concentration in the internal phase was correctly determined, which proved the applicability of the ELM process. The procedure to determine the initial carbonate concentration in the internal phase was also described in order that the pH in the internal phase should be within the relatively stable range for penicillin G at the end of the extraction. PMID:7764816

  9. Microfluidics with Gel Emulsions

    NASA Astrophysics Data System (ADS)

    Priest, Craig; Surenjav, Enkhtuul; Herminghaus, Stephan; Seemann, Ralf

    2006-03-01

    Microfluidic processing is usually achieved using single phase liquids. Instead, we use monodisperse emulsions to compartment liquids within microchannel geometries. At low continuous phase volume fractions, droplets self-organize to form well-defined arrangements, analogous to foam. While it is well-known that confined geometries can induce rearrangement of foam compartments at the millimeter-scale, similar dynamics are also expected for gel emulsions. We have studied online generation, organization and manipulation of gel emulsions using a variety of microchannel geometries. ``Passive'' reorganization, based on fixed channel geometries, can be supplemented by ``active'' manipulation by incorporating a ferrofluid phase. A ferromagnetic phase facilitates reorganization of liquid compartments on demand using an electromagnetic trigger. Moreover, coalescence between adjacent compartments within a gel emulsion can be induced using electrical potential. Microfluidics using gel emulsions will be well-suited for combinatorial chemistry, DNA sequencing, drug screening and protein crystallizations.

  10. Liquid Fuel Emulsion Jet-in-Crossflow Penetration and Dispersion Under High Pressure Conditions

    NASA Astrophysics Data System (ADS)

    Gomez, Guillermo Andres

    The current work focuses on the jet-in-crossflow penetration and dispersion behavior of water-in-oil emulsions in a high pressure environment. Both fuel injection strategies of using a water-in-oil emulsion and a jet-in-crossflow have demonstrated unique benefits in improving gas turbine performance from an emissions and efficiency standpoint. A jet-in-crossflow is very practical for use in gas turbine engines, rocket propulsion, and aircraft engines since it utilizes already available crossflow air to atomize fuel. Injecting water into a combustion chamber in the form of a water-in-oil emulsion allows for pollutant emissions reduction while reducing efficiency loses that may result from using a separate water or steam injection circuit. Dispersion effects on oil droplets are expected, therefore investigating the distribution of both oil and water droplets in the crossflow is an objective in this work. Understanding the synchronization and injection behavior of the two strategies is of key interest due to their combined benefits. A water-to-oil ratio and an ambient pressure parameter are developed for emulsion jet-in-crossflow trajectories. To this end, a total of 24 emulsion jet-in-crossflow tests were performed with varying ambient pressures of 2-8 atm and momentum flux ratios of 50, 85, and 120. Sobel edge filtering was applied to each averaged image obtained from a high speed video of each test case. Averaged and filtered images were used to resolve top and bottom edges of the trajectory in addition to the overall peak intensity up to 40 mm downstream of the injection point. An optimized correlation was established and found to differ from literature based correlations obtained under atmospheric pressure conditions. Overall it was found that additional parameters were not necessary for the top edge and peak intensity correlations, but a need for a unique emulsion bottom edge and width trajectory correlation was recognized. In addition to investigating emulsion

  11. Equilibrium orientations of non-spherical and chemically anisotropic particles at liquid-liquid interfaces and the effect on emulsion stability.

    PubMed

    Ballard, Nicholas; Bon, Stefan A F

    2015-06-15

    The effective stabilization of emulsions by solid particles, a phenomenon known as Pickering stabilization, is well known to be highly dependent on the wettability and the adhesion energy of the stabilizer employed at the liquid-liquid interface. We present a user-friendly computational model that can be used to determine equilibrium orientations and the adhesion energy of colloidal particles at interfaces. The model determines the free energy profile of particle adsorption at liquid-liquid interfaces using a triangular tessellation scheme. We demonstrate the use of the model, using a variety of anisotropic particles and demonstrate its ability to predict and explain experimental observations of particle behaviour at interfaces. In particular, we show that the concept of hydrophilic lipophilic balance commonly applied to molecular surfactants is insufficient to explain the complexity of the activity of colloidal particles at interfaces. In addition, we show the importance of the knowledge of the free energy adsorption profile of single particles at interfaces and the impact on overall free energy of emulsification of packed ensembles of particles. The delicate balance between optimization of adhesion energy, adsorption dynamics and particle packing is shown to be of great importance in the formation of thermodynamically stable emulsions. In order to use the model, the code is implemented by freely available software that can be readily deployed on personal computers. PMID:25792476

  12. Effect of emulsifiers and their liquid crystalline structures in emulsions on dermal and transdermal delivery of hydroquinone, salicylic acid and octadecenedioic acid.

    PubMed

    Otto, A; Wiechers, J W; Kelly, C L; Dederen, J C; Hadgraft, J; du Plessis, J

    2010-01-01

    This study investigated the effect of emulsifiers and their liquid crystalline structures on the dermal and transdermal delivery of hydroquinone (HQ), salicylic acid (SA) and octadecenedioic acid (DIOIC). Emulsions containing liquid crystalline phases were compared with an emulsion without liquid crystals. Skin permeation experiments were performed using Franz-type diffusion cells and human abdominal skin dermatomed to a thickness of 400 mum. The results indicate that emulsifiers arranging in liquid crystalline structures in the water phase of the emulsion enhanced the skin penetration of the active ingredients with the exception of SA. SA showed a different pattern of percutaneous absorption, and no difference in dermal and transdermal delivery was observed between the emulsions with and without liquid crystalline phases. The increase in skin penetration of HQ and DIOIC could be attributed to an increased partitioning of the actives into the skin. It was hypothesized that the interaction between the different emulsifiers and active ingredients in the formulations varied and, therefore, the solubilization capacities of the various emulsifiers and their association structures. PMID:20484969

  13. Ocean sequestration of carbon dioxide: modeling the deep ocean release of a dense emulsion of liquid Co2-in-water stabilized by pulverized limestone particles.

    PubMed

    Golomb, D; Pennell, S; Ryan, D; Barry, E; Swett, P

    2007-07-01

    The release into the deep ocean of an emulsion of liquid carbon dioxide-in-seawater stabilized by fine particles of pulverized limestone (CaCO3) is modeled. The emulsion is denser than seawater, hence, it will sink deeper from the injection point, increasing the sequestration period. Also, the presence of CaCO3 will partially buffer the carbonic acid that results when the emulsion eventually disintegrates. The distance that the plume sinks depends on the density stratification of the ocean, the amount of the released emulsion, and the entrainment factor. When released into the open ocean, a plume containing the CO2 output of a 1000 MW(el) coal-fired power plant will typically sink hundreds of meters below the injection point. When released from a pipe into a valley on the continental shelf, the plume will sink about twice as far because of the limited entrainment of ambient seawater when the plume flows along the valley. A practical system is described involving a static mixer for the in situ creation of the CO2/seawater/pulverized limestone emulsion. The creation of the emulsion requires significant amounts of pulverized limestone, on the order of 0.5 tons per ton of liquid CO2. That increases the cost of ocean sequestration by about $13/ ton of CO2 sequestered. However, the additional cost may be compensated by the savings in transportation costs to greater depth, and because the release of an emulsion will not acidify the seawater around the release point. PMID:17695916

  14. Interaction forces in thin liquid films stabilized by hydrophobically modified inulin polymeric surfactant. 2. Emulsion films.

    PubMed

    Exerowa, D; Gotchev, G; Kolarov, T; Khristov, Khr; Levecke, B; Tadros, Th

    2007-02-13

    The interaction forces in emulsion films stabilized using hydrophobically modified inulin (INUTEC SP1) were investigated by measuring the disjoining pressure of a microscopic horizontal film between two macroscopic emulsion drops of isoparaffinic oil (Isopar M). A special measuring cell was used for this purpose whereby the disjoining pressure Pi was measured as a function of the equivalent film thickness hw. The latter was determined using an interferometric method. In this way Pi-hw curves were established at a constant INUTEC SP1 concentration of 2x10(-5) mol.dm-3 and at various NaCl concentrations. At a constant disjoining pressure of 36 Pa, a constant temperature of 22 degrees C, and a film radius of 100 microm, hw decreased with an increase in the NaCl concentration, Cel, and reached a constant value of 11 nm at Cel=5x10(-2) mol.dm-3. This reduction in film thickness is due to the compression of the electrical double layer, and at the above critical NaCl concentration any electrostatic repulsion is removed and only steric interaction remains. This critical electrolyte concentration represents the transition from electrostatic to steric interaction. At a NaCl concentration of 2x10(-4) mol.dm-3 the Pi-hw isotherms showed a gradual decrease in hw with an increase in capillary pressure, after which there was a jump in hw from approximately 30 to approximately 7.2 nm when Pi reached a high value of 2-5.5 kPa. This jump is due to the formation of a Newton black film (NBF), giving a layer thickness of the polyfructose loops of approximately 3.6 nm. The film thickness did not change further when the pressure reached 45 kPa, indicating the high stability of the film. Pi-hw isotherms were obtained at various NaCl concentrations, namely, 5x10(-2), 5x10(-1), 1.0, and 2.0 mol.dm-3. The initial thicknesses are within the range 9-11 nm, after which a transition zone starts, corresponding to a pressure of about 0.5 kPa. In this zone all films transform to an NBF with a jump

  15. In vitro oxidation of i.v. lipid emulsions in different all-in-one admixture bags assessed by an iodometric assay and gas-liquid chromatography.

    PubMed

    Steger, P J; Mühlebach, S F

    1997-02-01

    Polyunsaturated fatty acids (FAs) of intravenous (IV) lipid emulsions can peroxidize to potentially harmful lipid hydroperoxides. In order to assess in vitro peroxidation of IV fat emulsions in all-in-one (AIO) admixture bags, an iodometric titration to determine lipid hydroperoxide content expressed by the peroxide value (PV) and a gas-liquid chromatographic (GLC) assay to determine changes of the FA pattern were established. A long-chain triglyceride (LCT) and medium-chain triglyceride-LCT emulsion were compared for the PV and the pH during storage at room temperature and daylight in AIO bags made of ethylvinylacetate (EVA) and polypropylene:polyamide 7:3 (V90). In contrast to storage in glass bottles, significant peroxidation was detected in both emulsions with 0.5-3.4 mmol peroxides/L after 28 d (150 times the control PV). A pH drop of at least 0.3 (EVA) and 1.2 (V90) units was measured. Initial PVs and peroxidation kinetics of the emulsions were different; V90 material showed better barrier properties against oxygen. PV was increased by higher temperature and light exposure. The FA pattern of an LCT emulsion with a PV > 6 (storage: 40 degrees C in a dark room for 28 d in AIO bags) assayed by GLC remained unchanged. The iodometric peroxide and the GLC assay were reproducible and easy to handle. Only the iodometric method was sensitive enough to detect peroxidation effects (detection limit: 0.02 mmol peroxides/L). IV fat emulsions can be checked for lipid hydroperoxide content with the rapid iodometric assay to guarantee optimal quality of IV lipids used for AIO admixtures. To prevent peroxidation, lipids in AIO bags should be stored light-protected in a refrigerator an oxygen-tight overwrap is mandatory for extended periods. PMID:9106791

  16. Effects of layer order on the mobility of mesogenic molecules in SmA liquid-crystalline emulsions

    NASA Astrophysics Data System (ADS)

    Bono, Shinji; Takanishi, Yoichi; Yamamoto, Jun

    2016-03-01

    We fabricate smectic-A liquid-crystalline emulsions (SmA-LCEs) in which monodisperse 8CB-swollen micelles are dispersed in water. Synchrotron X-ray measurements reveal that the correlation length of the layer order in LCEs cannot diverge at the nematic (N)-SmA transition, and the saturated length linearly increases with the increase in the diameter of LC-swollen micelles. Moreover, we investigate the permeation of 7CB N molecules into 8CB SmA-LCEs by measuring the enhancement of the depolarized light scattering intensity due to the shift of the SmA-N phase transition, and confirm that the layer order suppresses the mobility of LC molecules in LCEs similar to the bulk state of SmA LCs. The mobility drastically accelerates near the SmA-N transition temperature due to the continuous extinction of the smectic layer order. The slow permeation process of 7CB is also confirmed via synchrotron X-ray diffraction examining the shrinkage of the smectic layer repeat distance, caused by intercalation of 7CB.

  17. Removal of non-steroidal anti-inflammatory drugs ibuprofen and ketoprofen from water by emulsion liquid membrane.

    PubMed

    Dâas, Attef; Hamdaoui, Oualid

    2014-02-01

    In this work, the removal of the worldwide non-steroidal anti-inflammatory drugs ibuprofen (IBP) and ketoprofen (KTP) by emulsion liquid membrane (ELM) was carried out. An ELM system is made up of hexane as diluent, Span 80 as the surfactant and sodium carbonate as the inner aqueous solution. Effect of experimental conditions that affect the extraction of IBP such as surfactant concentration, emulsification time, sulfuric acid concentration in external phase, acid type in external phase, internal phase concentration, type of internal phase, stirring speed, volume ratio of internal phase to membrane phase, treatment ratio, IBP initial concentration, diluent type and salt was investigated. The obtained results showed that by appropriate selection of the operational parameters, it was possible to extract nearly all of IBP molecules from the feed solution even in the presence of high concentration of salt. Under optimum operating conditions, the efficiencies of IBP removal from distilled water (99.3 %), natural mineral water (97.3 %) and sea water (94.0 %) were comparable, which shows that the ELM treatment process represents a very interesting advanced separation process for the removal of IBP from complex matrices such as natural and sea waters. Under the optimized experimental conditions, approximately 97.4 % KTP was removed in less than 20 min of contact time. PMID:24037298

  18. Phase behavior and rheological analysis of reverse liquid crystals and W/I2 and W/H2 gel emulsions using an amphiphilic block copolymer.

    PubMed

    May, Anna; Aramaki, Kenji; Gutiérrez, José María

    2011-03-15

    This article reports the phase behavior determi-nation of a system forming reverse liquid crystals and the formation of novel disperse systems in the two-phase region. The studied system is formed by water, cyclohexane, and Pluronic L-121, an amphiphilic block copolymer considered of special interest due to its aggregation and structural properties. This system forms reverse cubic (I2) and reverse hexagonal (H2) phases at high polymer concentrations. These reverse phases are of particular interest since in the two-phase region, stable high internal phase reverse emulsions can be formed. The characterization of the I2 and H2 phases and of the derived gel emulsions was performed with small-angle X-ray scattering (SAXS) and rheometry, and the influence of temperature and water content was studied. The H2 phase experimented a thermal transition to an I2 phase when temperature was increased, which presented an Fd3m structure. All samples showed a strong shear thinning behavior from low shear rates. The elastic modulus (G') in the I2 phase was around 1 order of magnitude higher than in the H2 phase. G' was predominantly higher than the viscous modulus (G''). In the gel emulsions, G' was nearly frequency-independent, indicating their gel type nature. Contrarily to water-in-oil (W/O) normal emulsions, in W/I2 and W/H2 gel emulsions, G', the complex viscosity (|η*|), and the yield stress (τ0) decreased with increasing water content, since the highly viscous microstructure of the continuous phase was responsible for the high viscosity and elastic behavior of the emulsions, instead of the volume fraction of dispersed phase and droplet size. A rheological analysis, in which the cooperative flow theory, the soft glass rheology model, and the slip plane model were analyzed and compared, was performed to obtain one single model that could describe the non-Maxwellian behavior of both reverse phases and highly concentrated emulsions and to characterize their microstructure with

  19. Recovery of synthetic dye from simulated wastewater using emulsion liquid membrane process containing tri-dodecyl amine as a mobile carrier.

    PubMed

    Othman, N; Zailani, S N; Mili, N

    2011-12-30

    The extraction of Red 3BS reactive dye from aqueous solution was studied using emulsion liquid membrane (ELM). ELM is one of the processes that have very high potential in treating industrial wastewater consisting of dyes. In this research, Red 3BS reactive dye was extracted from simulated wastewater using tridodecylamine (TDA) as the carrier agent, salicyclic acid (SA) to protonate TDA, sodium chloride as the stripping agent, kerosene as the diluent and SPAN 80 as emulsifier. Experimental parameters investigated were salicyclic acid concentration, extraction time, SPAN 80 concentration, sodium chloride concentration, TDA concentration, agitation speed, homogenizer speed, emulsifying time and treat ratio. The results show almost 100% of Red 3BS was removed and stripped in the receiving phase at the optimum condition in this ELM system. High voltage coalesce was applied to break the emulsion hence, enables recovery of Red 3BS in the receiving phase. PMID:22023906

  20. Emulsions for interfacial filtration.

    SciTech Connect

    Grillet, Anne Mary; Bourdon, Christopher Jay; Souza, Caroline Ann; Welk, Margaret Ellen; Hartenberger, Joel David; Brooks, Carlton, F.

    2006-11-01

    We have investigated a novel emulsion interfacial filter that is applicable for a wide range of materials, from nano-particles to cells and bacteria. This technology uses the interface between the two immiscible phases as the active surface area for adsorption of targeted materials. We showed that emulsion interfaces can effectively collect and trap materials from aqueous solution. We tested two aqueous systems, a bovine serum albumin (BSA) solution and coal bed methane produced water (CBMPW). Using a pendant drop technique to monitor the interfacial tension, we demonstrated that materials in both samples were adsorbed to the liquid-liquid interface, and did not readily desorb. A prototype system was built to test the emulsion interfacial filter concept. For the BSA system, a protein assay showed a progressive decrease in the residual BSA concentration as the sample was processed. Based on the initial prototype operation, we propose an improved system design.

  1. Separation study of cadmium through an emulsion liquid membrane using triisooctylamine as mobile carrier.

    PubMed

    Li, Q M; Liu, Q; Zhang, Q F; Wei, X J; Guo, J Z

    1998-08-01

    A study of the transport of Cd(2+) ions through a triisooctylamine (TIOA)-sorbitan monooleate (Span 80)-dimethylbenzene liquid membrane has been performed with varying concentrations of HCl, KI, TIOA, Span 80 and NaOH in the feed, membrane and stripping solutions. Maximum transport was observed with 0.025 M HCl, 0.01 M KI, 0.02 M TIOA, 3% (w/v) Span 80 and 0.05 M NaOH. With this system cadmium could be completely separated with Cu(2+), Zn(2+), Fe(2+), Co(2+), Ni(2+), Mn(2+), Cr(3+) and Al(3+). The transport mechanism of this metal ions through the membrane has been discussed. PMID:18967215

  2. Thermocapillary Motion in an Emulsion

    NASA Technical Reports Server (NTRS)

    Pukhnachov, Vladislav V.; Voinov, Oleg V.

    1996-01-01

    The phenomenological model for the motion of an emulsion or a gas-liquid mixture exposed to thermocapillary forces and micro-acceleration is formulated. The analytical and numerical investigation of one-dimensional flows for these media is fulfilled, the structure of discontinuous motion is studied. The stability conditions of a space-uniform state and of the interface between an emulsion and a pure liquid are obtained.

  3. Water with low concentration of surfactant in dispersed solvent-assisted emulsion dispersive liquid-liquid microextraction for the determination of organochlorine pesticides in aqueous samples.

    PubMed

    Li, Yee; Chen, Pai-Shan; Huang, Shang-Da

    2013-07-26

    A novel sample preparation method, "water with low concentration of surfactant in dispersed solvent-assisted emulsion dispersive liquid-liquid microextraction (WLSEME)", coupled with gas chromatography using an electron capture detector (GC-ECD) was developed for the analysis of the organochlorine pesticides (OCPs), heptachlor, α-endosulfan, 4,4-DDE, 2,4-DDD and endrin, in aqueous samples. A microsyringe is used to withdrew and discharge 10-12μL of the extraction solvent and 60-120μL of water as the dispersed solvent (containing 1mgL(-1), Tween 80) 4 times within 10s to form a cloudy emulsified solution in the syringe. This is then injected into an 8mL aqueous sample spiked with all above OCPs. Dodecyl acetate and 2-dodecanol were both selected as extraction solvents to optimize their conditions separately. The total extraction time was about 0.5min. Under optimum conditions, using dodecyl acetate (12μL) as extraction solvent, the linear range of the method was 10-1000ngL(-1) for all OCPs, and the the limits of detection (LODs) ranged from 1 to 5ngL(-1). The absolute recoveries and relative recoveries were from 20.8 to 43.5% and 83.2 to 109.8% for lake water, and 19.9-49.2% and 85.4-115.9% for seawater respectively. In the second method, 2-dodecanol as extraction solvent, the linear range was from 5 to 5000ngL(-1) for the target compounds, and the LODs were between 0.5 and 2ngL(-1). The absolute recoveries and relative recoveries ranged from 25.7 to 42.2% and 96.3-111.2% for sea water, and 22.4-41.9% and 90.7-107.9% for stream water. This could solve several problems, which commonly occur in ultrasound-assisted emulsification micro-extraction (USAEME), dispersive liquid-liquid micro-extraction (DLLME) and other assisted emulsification methods. These problems include analyte degradation, increased solubility of the extraction solvent and analyte, and high toxicity and large volume of the organic solvent used. PMID:23566919

  4. Research News

    MedlinePlus

    Research News - National Multiple Sclerosis Society Skip to navigation Skip to content Menu Navigation National Multiple Sclerosis ... Email Home Research Research News & Progress Research News Research News Share Smaller Text Larger Text Print Read ...

  5. Programmed emulsions for sodium reduction in emulsion based foods.

    PubMed

    Chiu, Natalie; Hewson, Louise; Fisk, Ian; Wolf, Bettina

    2015-05-01

    In this research a microstructure approach to reduce sodium levels in emulsion based foods is presented. If successful, this strategy will enable reduction of sodium without affecting consumer satisfaction with regard to salty taste. The microstructure approach comprised of entrapment of sodium in the internal aqueous phase of water-in-oil-in-water emulsions. These were designed to destabilise during oral processing when in contact with the salivary enzyme amylase in combination with the mechanical manipulation of the emulsion between the tongue and palate. Oral destabilisation was achieved through breakdown of the emulsion that was stabilised with a commercially modified octenyl succinic anhydride (OSA)-starch. Microstructure breakdown and salt release was evaluated utilising in vitro, in vivo and sensory methods. For control emulsions, stabilised with orally inert proteins, no loss of structure and no release of sodium from the internal aqueous phase was found. The OSA-starch microstructure breakdown took the initial form of oil droplet coalescence. It is hypothesised that during this coalescence process sodium from the internalised aqueous phase is partially released and is therefore available for perception. Indeed, programmed emulsions showed an enhancement in saltiness perception; a 23.7% reduction in sodium could be achieved without compromise in salty taste (p < 0.05; 120 consumers). This study shows a promising new approach for sodium reduction in liquid and semi-liquid emulsion based foods. PMID:25865459

  6. High-internal-phase-emulsion polymeric monolith coupled with liquid chromatography-electrospray tandem mass spectrometry for enrichment and sensitive detection of trace cytokinins in plant samples.

    PubMed

    Du, Fuyou; Sun, Lin; Zhen, Xian; Nie, Honggang; Zheng, Yanjie; Ruan, Guihua; Li, Jianping

    2015-08-01

    High-internal-phase-emulsion polymers (polyHIPEs) show great promise as solid-phase-extraction (SPE) materials because of the tremendous porosity and highly interconnected framework afforded by the high-internal-phase-emulsion (HIPE) technique. In this work, polyHIPE monolithic columns as novel SPE materials were prepared and applied to trace enrichment of cytokinins (CKs) from complex plant samples. The polyHIPE monoliths were synthesized via the in-situ polymerization of the continuous phase of a HIPE containing styrene (STY) and divinylbenzene (DVB) in a stainless column, and revealed highly efficient and selective enrichment ability for aromatic compounds. Under the optimized experimental conditions, a method using a monolithic polyHIPE column combined with liquid chromatography-electrospray tandem mass spectrometry (LC-MS-MS) was developed for the simultaneous extraction and sensitive determination of trans-zeatin (tZ), meta-topolin (mT), kinetin (K), and kinetin riboside (KR). The proposed method had good linearity, with correlation coefficients (R (2)) from 0.9957 to 0.9984, and low detection limits (LODs, S/N = 3) in the range 2.4-47 pg mL(-1) for the four CKs. The method was successfully applied to the determination of CKs in real plant samples, and obtained good recoveries ranging from 68.8 % to 103.0 % and relative standard deviations (RSDs) lower than 16 %. PMID:26025552

  7. Strong stabilization of amorphous calcium carbonate emulsion by ovalbumin: gaining insight into the mechanism of 'polymer-induced liquid precursor' processes.

    PubMed

    Wolf, Stephan E; Leiterer, Jork; Pipich, Vitaliy; Barrea, Raul; Emmerling, Franziska; Tremel, Wolfgang

    2011-08-17

    The impact of the ovo proteins ovalbumin and lysozyme--present in the first stage of egg shell formation--on the homogeneous formation of the liquid amorphous calcium carbonate (LACC) precursor, was studied by a combination of complementing methods: in situ WAXS, SANS, XANES, TEM, and immunogold labeling. Lysozyme (pI = 9.3) destabilizes the LACC emulsion whereas the glycoprotein ovalbumin (pI = 4.7) extends the lifespan of the emulsified state remarkably. In the light of the presented data: (a) Ovalbumin is shown to behave commensurable to the 'polymer-induced liquid precursor' (PILP) process proposed by Gower et al. Ovalbumin can be assumed to take a key role during eggshell formation where it serves as an effective stabilization agent for transient precursors and prevents undirected mineralization of the eggshell. (b) It is further shown that the emulsified LACC carries a negative surface charge and is electrostatically stabilized. (c) We propose that the liquid amorphous calcium carbonate is affected by polymers by depletion stabilization and de-emulsification rather than 'induced' by acidic proteins and polymers during a so-called polymer-induced liquid-precursor process. The original PILP coating effect, first reported by Gower et al., appears to be a result of a de-emulsification process of a stabilized LACC phase. The behavior of the liquid amorphous carbonate phase and the polymer-induced liquid-precursor phase itself can be well described by colloid chemical terms: electrostatic and depletion stabilization and de-emulsification by depletion destabilization. PMID:21736300

  8. Coal desulfurization during the combustion of coal/oil/water emulsions: an economic alternative clean liquid fuel. Final report

    SciTech Connect

    Not Available

    1983-04-01

    This report presents the Phase II results of a combustion program designed to assess the feasibility of utilizing coal/oil/water (COW) emulsions as a fuel for fire tube package boilers. Also examined was the effect of the addition of alkaline absorbents to the fuel for sulfur dioxide capture. Presented are the findings of testing involving optimizing sulfur dioxide removal while still maintaining a rheologically favorable fuel. Overall performance of COW as a boiler fuel was evaluated over long term operation. Emphasis was placed on burner design as well as coal characteristics. Three different bituminous coals were used during this program. Results indicate that COW emulsions may be a feasible alternative for oil in industrial fire tube boilers if the major problem, deposition buildup, can be resolved. This appears possible with a proper soot blower design. Soda ash is a viable means for obtaining at least 80% removal, using a 1:1 molar ratio. However, the deposition problem with soda ash indicated that stack injection may be a more feasible approach.

  9. Altering Emulsion Stability with Heterogeneous Surface Wettability.

    PubMed

    Meng, Qiang; Zhang, Yali; Li, Jiang; Lammertink, Rob G H; Chen, Haosheng; Tsai, Peichun Amy

    2016-01-01

    Emulsions-liquid droplets dispersed in another immiscible liquid-are widely used in a broad spectrum of applications, including food, personal care, agrochemical, and pharmaceutical products. Emulsions are also commonly present in natural crude oil, hampering the production and quality of petroleum fuels. The stability of emulsions plays a crucial role in their applications, but controlling the stability without external driving forces has been proven to be difficult. Here we show how heterogeneous surface wettability can alter the stability and dynamics of oil-in-water emulsions, generated by a co-flow microfluidic device. We designed a useful methodology that can modify a micro-capillary of desired heterogeneous wettability (e.g., alternating hydrophilic and hydrophobic regions) without changing the hydraulic diameter. We subsequently investigated the effects of flow rates and heterogeneous wettability on the emulsion morphology and motion. The experimental data revealed a universal critical timescale of advective emulsions, above which the microfluidic emulsions remain stable and intact, whereas below they become adhesive or inverse. A simple theoretical model based on a force balance can be used to explain this critical transition of emulsion dynamics, depending on the droplet size and the Capillary number-the ratio of viscous to surface effects. These results give insight into how to control the stability and dynamics of emulsions in microfluidics with flow velocity and different wettability. PMID:27256703

  10. Double emulsions in a microfluidic device

    NASA Astrophysics Data System (ADS)

    Pannacci, Nicolas; Lockhart, Thibaut; Willaime, Hervé; Tabeling, Patrick

    2007-11-01

    Double emulsions (emulsion of two liquids dispersed in a third liquid phase) are widely used in cosmetics, medicine or food industry. We are interested in producing very well controlled double emulsions in a microfluidic device and predicting the morphology (complete engulfing, non-engulfing or partial engulfing called ``janus'') from classical energetic considerations. We use a double flow focusing geometry with a 100 micrometers cross section for the PDMS microsystem. We compare theoretical and experimental morphologies flowing thirty triplets of immiscible fluids. We observe quite a good agreement and show that microfluidic technology may permit to get non standard objects.

  11. New insight into microgel-stabilized emulsions using transmission X-ray microscopy: nonuniform deformation and arrangement of microgels at liquid interfaces.

    PubMed

    Geisel, Karen; Henzler, Katja; Guttmann, Peter; Richtering, Walter

    2015-01-13

    Microgel-covered interfaces, e.g., in emulsions, have attracted much interest lately. Different imaging techniques have been used to image these interfaces, either flat or curved, to investigate their properties and appearance. Techniques such as cryogenic scanning electron microscopy (cryo-SEM) and confocal microscopy have provided valuable insight into microgel-covered systems but still have some disadvantages such as part of the microgels being trapped in vitrified liquid or the need for fluorescent markers. Some of these disadvantages can be overcome by using transmission X-ray microscopy (TXM), which has the advantage of allowing the investigation of adsorbed and free microgels simultaneously. We used TXM to acquire tomographic image series of microgel-covered droplets and calculated 3D reconstructions from these image stacks. As a result, we could show that microgels deform anisotropically and penetrate the oil droplets in the hydrated state. Additionally, 3D reconstruction gives an idea of the arrangement of microgels adsorbed to oil droplets and reveals that droplet stabilization is possible without full coverage of the interface with polymer segments. PMID:25496214

  12. Self-Assembly of Metal-Oxide Nanoparticles into Hierarchically Patterned Porous Architectures using Ionic Liquid/Oil Emulsions

    SciTech Connect

    Zhou, Shenghu; Ma, Zhen; Baker, Gary A; Rondinone, Adam Justin; Zhu, Qing; Luo, Huimin; Wu, Zili; Dai, Sheng

    2009-01-01

    Hierarchically patterned macroporous TiO2 structures can be fabricated via the spontaneous self-assembly of TiO2 nanoparticles prepared using a mixture of 1-octadecene (ODE) and an ODE-immiscible 1-alkyl-3-methylimidazolium-based ionic liquid as the reaction medium. A study of the influence of side chain lengths of ionic liquids (n = 4, 8, or 16) reveals that this parameter can be further used to fine-tune the morphologies of the products. This synthetic methodology can also be extended to the formation of patterned macroporous ZrO2 and Fe3O4 structures. Finally, the potential reasons for the formation of hierarchical structures are discussed and the implications to further research are proposed.

  13. The atomization of water-oil emulsions

    SciTech Connect

    Broniarz-Press, L.; Ochowiak, M.; Rozanski, J.; Woziwodzki, S.

    2009-09-15

    The paper presents the results of experimental studies on atomization of the emulsions flowing through twin-fluid atomizers obtained by the use of the digital microphotography method. The main elements of the test installation were: nozzle, reservoir, pump and measurement units of liquid flow. The photographs were taken by a digital camera with automatic flash at exposure time of 1/8000 s and subsequently analyzed using Image Pro-Plus. The oils used were mineral oils 20-90, 20-70, 20-50 and 20-30. The studies were performed at flow rates of liquid phase changed from 0.0014 to 0.011 (dm{sup 3}/s) and gas phase changed from 0.28 to 1.4 (dm{sup 3}/s), respectively. The analysis of photos shows that the droplets being formed during the liquid atomization have very different sizes. The smallest droplets have diameters of the order of 10 {mu}m. The experimental results showed that the changes in physical properties of a liquid phase lead to the significant changes in the spray characteristics. The analysis of the photos of water and emulsions atomization process showed that the droplet sizes are dependent on gas and liquid flow rates, construction of nozzle and properties of liquid. The differences between characteristics of atomization for water and emulsions have been observed. Analysis of photos on forming the droplets in air-water and air-emulsions systems showed that droplets are bigger in air-emulsion system (at the same value of gas to liquid mass ratio). The values of Sauter mean diameter (SMD) increased with increase of volume fraction of oil in emulsion. The droplet size increased with emulsion viscosity. (author)

  14. Altering Emulsion Stability with Heterogeneous Surface Wettability

    PubMed Central

    Meng, Qiang; Zhang, Yali; Li, Jiang; Lammertink, Rob G. H.; Chen, Haosheng; Tsai, Peichun Amy

    2016-01-01

    Emulsions–liquid droplets dispersed in another immiscible liquid–are widely used in a broad spectrum of applications, including food, personal care, agrochemical, and pharmaceutical products. Emulsions are also commonly present in natural crude oil, hampering the production and quality of petroleum fuels. The stability of emulsions plays a crucial role in their applications, but controlling the stability without external driving forces has been proven to be difficult. Here we show how heterogeneous surface wettability can alter the stability and dynamics of oil-in-water emulsions, generated by a co-flow microfluidic device. We designed a useful methodology that can modify a micro-capillary of desired heterogeneous wettability (e.g., alternating hydrophilic and hydrophobic regions) without changing the hydraulic diameter. We subsequently investigated the effects of flow rates and heterogeneous wettability on the emulsion morphology and motion. The experimental data revealed a universal critical timescale of advective emulsions, above which the microfluidic emulsions remain stable and intact, whereas below they become adhesive or inverse. A simple theoretical model based on a force balance can be used to explain this critical transition of emulsion dynamics, depending on the droplet size and the Capillary number–the ratio of viscous to surface effects. These results give insight into how to control the stability and dynamics of emulsions in microfluidics with flow velocity and different wettability. PMID:27256703

  15. Altering Emulsion Stability with Heterogeneous Surface Wettability

    NASA Astrophysics Data System (ADS)

    Meng, Qiang; Zhang, Yali; Li, Jiang; Lammertink, Rob G. H.; Chen, Haosheng; Tsai, Peichun Amy

    2016-06-01

    Emulsions–liquid droplets dispersed in another immiscible liquid–are widely used in a broad spectrum of applications, including food, personal care, agrochemical, and pharmaceutical products. Emulsions are also commonly present in natural crude oil, hampering the production and quality of petroleum fuels. The stability of emulsions plays a crucial role in their applications, but controlling the stability without external driving forces has been proven to be difficult. Here we show how heterogeneous surface wettability can alter the stability and dynamics of oil-in-water emulsions, generated by a co-flow microfluidic device. We designed a useful methodology that can modify a micro-capillary of desired heterogeneous wettability (e.g., alternating hydrophilic and hydrophobic regions) without changing the hydraulic diameter. We subsequently investigated the effects of flow rates and heterogeneous wettability on the emulsion morphology and motion. The experimental data revealed a universal critical timescale of advective emulsions, above which the microfluidic emulsions remain stable and intact, whereas below they become adhesive or inverse. A simple theoretical model based on a force balance can be used to explain this critical transition of emulsion dynamics, depending on the droplet size and the Capillary number–the ratio of viscous to surface effects. These results give insight into how to control the stability and dynamics of emulsions in microfluidics with flow velocity and different wettability.

  16. Emulsions on demand using microsturctured devices

    NASA Astrophysics Data System (ADS)

    Mahe, Christian; Tranchant, Jean Francois; Tromeur, Melanie; Schwesinger, Norbert

    2003-01-01

    Emulsions are very common in the field of cosmetics. Unfortunately, most emulsions contain ineffective substances to increase the stability of the products for a long time. These stabilizers can cause some severe healthy problems in several cases. One possible solution is the production of emulsions on demand to prevent the use of stabilizers. Stable emulsion can be achieved if the diameters of the droplets of one solution surrounded by a second solution are smaller than 1μm. Microstructured devices are suited in principle to generate such droplet distributions. Basic task of the development was a micro emulsifier that can be integrated into cosmetic flacons and that can deliver emulsions on demand by pressing a human fingertip onto a part of the flacon. Standardized cosmetic flacons have been used as basic devices. They consist of two separate glass bottles for two different liquid phases and two mechanical pumps integrated in a multifunctional cap. Regarding the viscosity ranges of the two liquids different microemulsifier structures have been developed. External dimensions and connections of the device have been chosen in a way that allows an integration of the devices into the cap. The second design conists of several streaming paths in parallel that allow a reduction of the pressure drop. Furthermore, it consists of three structured silicon chips bonded together. Emulsions with a stability of about 15-30 min have been achieved without any stabilizers. External forces of less than 10N were sufficient to generate emulsions on demand.

  17. Polymerization in emulsion microdroplet reactors

    NASA Astrophysics Data System (ADS)

    Carroll, Nick J.

    The goal of this research project is to utilize emulsion droplets as chemical reactors for execution of complex polymerization chemistries to develop unique and functional particle materials. Emulsions are dispersions of immiscible fluids where one fluid usually exists in the form of drops. Not surprisingly, if a liquid-to-solid chemical reaction proceeds to completion within these drops, the resultant solid particles will possess the shape and relative size distribution of the drops. The two immiscible liquid phases required for emulsion polymerization provide unique and complex chemical and physical environments suitable for the engineering of novel materials. The development of novel non-ionic fluorosurfactants allows fluorocarbon oils to be used as the continuous phase in a water-free emulsion. Such emulsions enable the encapsulation of almost any hydrocarbon compound in droplets that may be used as separate compartments for water-sensitive syntheses. Here, we exemplify the promise of this approach by suspension polymerization of polyurethanes (PU), in which the liquid precursor is emulsified into droplets that are then converted 1:1 into polymer particles. The stability of the droplets against coalescence upon removal of the continuous phase by evaporation confirms the formation of solid PU particles. These results prove that the water-free environment of fluorocarbon based emulsions enables high conversion. We produce monodisperse, cross-linked, and fluorescently labeled PU-latexes with controllable mesh size through microfluidic emulsification in a simple one-step process. A novel method for the fabrication of monodisperse mesoporous silica particles is presented. It is based on the formation of well-defined equally sized emulsion droplets using a microfluidic approach. The droplets contain the silica precursor/surfactant solution and are suspended in hexadecane as the continuous oil phase. The solvent is then expelled from the droplets, leading to

  18. Emulsion Droplet Combustion in Microgravity: Water/Heptane Emulsions

    NASA Technical Reports Server (NTRS)

    Avedisian, C. Thomas

    1997-01-01

    This presentation reviews a series of experiments to further examine parametric effects on sooting processes of droplet flames in microgravity. The particular focus is on a fuel droplet emulsified with water, specifically emulsions of n-heptane as the fuel-phase and water as the dispersed phase. Water was selected as the additive because of its anticipated effect on soot formation, and the heptane fuel phase was chosen to theoretically reduce the likelihood of microexplosions because its boiling point is nearly the same as that of water: 100 C for water and 98 C for heptane. The water content was varied while the initial droplet diameter was kept within a small range. The experiments were carried out in microgravity to reduce the effects of buoyancy and to promote spherical symmetry in the burning process. Spherically symmetric droplet burning is a convenient starting point for analysis, but experimental data are difficult to obtain for this situation as evidenced by the fact that no quantitative data have been reported on unsupported emulsion droplet combustion in a convection-free environment. The present study improves upon past work carried out on emulsion droplet combustion in microgravity which employed emulsion droplets suspended from a fiber. The fiber can be instrusive to the emulsion droplet burning process as it can promote coalescence of the dispersed water phase and heterogeneous nucleation on the fiber. Prior work has shown that the presence of water in liquid hydrocarbons can have both beneficial and detrimental effects on the combustion process. Water is known to reduce soot formation and radiation heat transfer to combustor walls Gollahalli (1979) reduce flame temperatures and thereby NOx emissions, and encourage secondary droplet atomization or microexplosion. Water also tends to retard ignition and and promote early extinction. The former effect restricted the range of water volume fractions as discussed below.

  19. Recent Emulsion Technologies

    SciTech Connect

    Ariga, A.

    2011-10-06

    Emulsion technologies are very much developed in the last decade and still developing in both the emulsion gel and the data taking. Emulsion detectors are suitable for the neutrino experiments because they can distinguish all 3 flavors of neutrino. The OPERA experiment, a recent pillar in the emulsion experiments aiming at the first observation of the neutrino oscillation in CNGS beam in appearance mode, is running, showing the good capability to separate 3 flavor neutrino interactions. In this poster, the recent developments and prospects of the emulsions for the next generation experiments are reported.

  20. Zero-Valent Metal Emulsion for Reductive Dehalogenation of DNAPLs

    NASA Technical Reports Server (NTRS)

    Reinhart, Debra R. (Inventor); Clausen, Christian (Inventor); Gelger, Cherie L. (Inventor); Quinn, Jacqueline (Inventor); Brooks, Kathleen (Inventor)

    2006-01-01

    A zero-valent metal emulsion is used to dehalogenate solvents, such as pooled dense non-aqueous phase liquids (DNAPLs), including trichloroethylene (TCE). The zero-valent metal emulsion contains zero-valent metal particles, a surfactant, oil and water, The preferred zero-valent metal particles are nanoscale and microscale zero-valent iron particles.

  1. Zero-Valent Metal Emulsion for Reductive Dehalogenation of DNAPLS

    NASA Technical Reports Server (NTRS)

    Reinhart, Debra R. (Inventor); Clausen, Christian (Inventor); Geiger, Cherie L. (Inventor); Quinn, Jacqueline (Inventor); Brooks, Kathleen (Inventor)

    2003-01-01

    A zero-valent metal emulsion is used to dehalogenate solvents, such as pooled dense non-aqueous phase liquids (DNAPLs), including trichloroethylene (TCE). The zero-valent metal emulsion contains zero-valent metal particles, a surfactant, oil and water. The preferred zero-valent metal particles are nanoscale and microscale zero-valent iron particles

  2. Tuneable Rheological Properties of Fluorinated Pickering Emulsions

    NASA Astrophysics Data System (ADS)

    Chacon Orellana, Laura Andreina; Riechers, Birte; Caen, Ouriel; Baret, Jean-Christophe

    Pickering emulsions are an appealing approach to stabilize liquid-liquid dispersions without surfactants. Recently, amphiphilic silica nanoparticles have been proposed as an alternative to surfactants for droplet microfluidics applications, where aqueous drops are stabilized in fluorinated oils. This system, proved to be effective in preventing the leakage of resorufin, a model dye that was known to leak in surfactant-stabilized drops. The overall capabilities of droplet-based microfluidics technology is highly dependent on the dynamic properties of droplets, interfaces and emulsions. Therefore, fluorinated pickering emulsions dynamic properties need to be characterized, understood and controlled to be used as a substitute of already broadly studied emulsions for droplet microfluidics applications. In this study, fluorinated pickering emulsions have been found to behave as a Herschel Bulkley fluid, representing a challenge for common microfluidic operations as re-injection and sorting of droplets. We found that this behavior is controlled by the interaction between the interfacial properties of the particle-laden interface and the bulk properties of the two phases

  3. Simple and double emulsions via electrospray

    NASA Astrophysics Data System (ADS)

    Barrero, Antonio; Loscertales, Ignacio G.

    2005-11-01

    Generation of nanoemulsions is of great interest in medical and pharmaceutical applications; drug delivery or antiviral emulsions are typical examples. The use of electrosprays for dispersing liquids inside liquid insulator baths have been recently reported, (Barrero et al. J. Colloid Interf. Sci. 272, 104, 2004). Capsules, nanotubes and coaxial nanofibers have been obtained from electrified coaxial jets (Loscertales et al. Science 295, n. 5560, 1695, 2002; J. American Chem. Soc. 126, 5376, 2004). Here we present a method for making double emulsions (both water-oil-water and o/w/o) based on the generation of compound electrosprays inside insulator liquid baths. Basically, a conducting liquid injected throughout a capillary needle is electroatomized in cone-jet mode inside a dielectric liquid bath. A third insulating liquid is injected inside the Taylor cone to form a second meniscus. Then, a steady coaxial jet, in which the insulating liquid is coated by the conducting one, develops. A double emulsion forms as a result of the jet breaking up into compound droplets electrically charged. Experimental results carried out with glycerine and different oils in a bath of heptane are reported.

  4. Method of breaking and emulsion and an emulsion-emulsion breaker composition

    SciTech Connect

    Salathiel, W. M.

    1985-05-14

    This invention relates to a composition of matter and to a method for producing a controllable, residue-free break of an emulsion or a dispersion of a water-in-oil emulsion. An emulsion breaker is incorporated into the emulsion. It is temporarily-protected (deactivated) so that breaking of the emulsion is initially avoided. By removing the protection, the breaker becomes active, and it acts to break the emulsion into its separate phases.

  5. NEWS: Institute news

    NASA Astrophysics Data System (ADS)

    2000-07-01

    Department of Physics and Astronomy at the University of Leeds. Physics at Work Exhibition: 12-14 September, University of Cambridge The year 2000 Exhibition will be the 16th organized by Brenda Jennison. The exhibition will be held at the Cavendish Laboratory and further details can be obtained from Brenda at the University (tel: 01223 332888, fax: 01223 332894 or e-mail: bmj10@cam.ac.uk). News on GNVQ science The Institute of Physics and the Royal Society of Chemistry are currently financing the compilation of a directory of resources to assist teachers in identifying and selecting suitable materials for teaching the new GNVQ science specifications. Work on the first part of the directory will soon be completed and it is hoped to publish the material in both print and electronic forms before the end of the summer term. This first part covers resources - all evaluated by practising GNVQ teachers - supporting the teaching of the compulsory units for Advanced GNVQ Science. A small team comprising a physics teacher, a chemistry teacher and a biology teacher, all involved with GNVQ programmes and led by Dr Ken Gadd, has carried out the work. They have established a network of teachers around the country to help with the evaluation of curriculum materials. The next part of the project will be to examine the feasibility of providing a similar listing for the optional units at this level. Future development, depending on the availability of funds, will extend the project to Intermediate level programmes in science, including the Part One, once its structure has been agreed at QCA. Further information about the Directory and the next phase of development will be available in the autumn. Activities Physics on Stage The future of science, technology and the ensuing wealth creation potential for Britain will depend on the quality of science education in schools today. Yet the numbers studying physics, which underpins science and engineering, are falling. This problem is currently

  6. Society News

    NASA Astrophysics Data System (ADS)

    Williams, Stuart; Goward, Ken; Davenhall, Clive

    2005-03-01

    Council Meeting, February; The Antiquarian Astronomer; Joint WHS/SHA meeting in Bath, Saturday 5 March 2005; Future meetings; Spring conference and AGM; Summer picnic; Sir Robert Ball Library News; New SHA Library manual; Formal opening of the Sir Robert Ball Library; Visit to the ROE Library.

  7. What's News?

    ERIC Educational Resources Information Center

    Hobbs, Renee

    2005-01-01

    News analysis and entertainment media is part of a media literacy that helps students access, analyze, evaluate and create messages using media in various forms. Media literacy is a key asset in a democracy as well as a bridge to reading comprehension, as skillful media use and script-reading activities can support the English acquisition skills,…

  8. Computer News

    ERIC Educational Resources Information Center

    Science Activities: Classroom Projects and Curriculum Ideas, 2007

    2007-01-01

    This article presents several news stories about computers and technology. (1) Applied Science Associates of Narragansett, Rhode Island is providing computer modeling technology to help locate the remains to the USS Bonhomme Richard, which sank in 1779 after claiming a Revolutionary War victory. (2) Whyville, the leading edu-tainment virtual world…

  9. Rheology of emulsions.

    PubMed

    Derkach, Svetlana R

    2009-10-30

    The review is devoted to the historical and modern understanding of rheological properties of emulsions in a broad range of concentration. In the limiting case of dilute emulsions, the discussion is based on the analogy and differences in properties of suspensions and emulsions. For concentrated emulsions, the main peculiarities of their rheological behaviour are considered. Different approaches to understand the concentration dependencies of viscosity are presented and compared. The effects of non-Newtonian flow curves and the apparent transition to yielding with increasing concentration of the dispersed phase are discussed. The problem of droplet deformation in shear fields is touched. The highly concentrated emulsions (beyond the limit of closest packing of spherical particles) are treated as visco-plastic media, and the principle features of their rheology (elasticity, yielding, concentration and droplet size dependencies) are considered. A special attention is paid to the problem of shear stability of drops of an internal phase starting from the theory of the single drop behaviour, including approaches for the estimation of drops' stability in concentrated emulsions. Polymer blends are also treated as emulsions, though taking into account their peculiarities due to the coexistence of two interpenetrated phases. Different theoretical models of deformation of polymer drops were discussed bearing in mind the central goal of predictions of the visco-elastic properties of emulsions as functions of the properties of individual components and the interfacial layer. The role of surfactants is discussed from the point of view of stability of emulsions in time and their special influence on the rheology of emulsions. PMID:19683219

  10. Cationic bituminous emulsions and emulsion aggregate slurries

    SciTech Connect

    Schilling, P.

    1986-07-01

    A cationic bituminous emulsion is described which consists of from about 30% to about 80% by weight of bitumen, from about 0.1% to about 10% by weight of an emulsifier selected from the group consisting of reaction products of a polyamine reacted with a member of the group consisting of epoxidized unsaturated fatty acids of chain lengths between C/sub 8/ and C/sub 22/ and the esters thereof and adding water to make up 100% by weight, the emulsion having a pH in the range of from 2-7.

  11. Simulation of Non-Newtonian Emulsion Flows in Microchannels

    NASA Astrophysics Data System (ADS)

    Malanichev, I. V.; Akhmadiev, F. G.

    2015-11-01

    Simulation of emulsion flows in differently shaped microchannels to reproduce the choking of such flows as a result of the effect of dynamic blocking has been made. A model of a highly concentrated emulsion as a structure of tightly packed deformed droplets surrounded by elastic shells is considered. The motion of liquid was determined by the method of the lattice Boltzmann equations together with the immersed boundary method. The influence of the non-Newtonian properties and of elastic turbulence of the indicated emulsion, as well as of the elasticity of the shells of its droplets and of the interaction of these shells on the emulsion motion in a microchannel, has been investigated. It is shown that the flow of this emulsion can be slowed down substantially only due to the mutual attraction of the shells of its droplets.

  12. Nanoscale and Microscale Iron Emulsions for Treating DNAPL

    NASA Technical Reports Server (NTRS)

    Geiger, Cherie L.

    2002-01-01

    This study demonstrated the feasibility of using emulsified nanoscale and microscale iron particles to enhance dehalogenation of (Dense Non-Aqueous Phase Liquid) DNAPL free-phase. The emulsified system consisted of a surfactant-stabilized, biodegradable oil-in-water emulsion with nanoscale or microscale iron particles contained within the emulsion droplets. It was demonstrated that DNAPLs, such as trichloroethene (TCE), diffuse through the oil membrane of the emulsion particle whereupon they reach an aqueous interior and the surface of an iron particle where dehalogenation takes place. The hydrocarbon reaction by-products of the dehalogenation reaction, primarily ethene (no chlorinated products detected), diffuse out of the emulsion droplet. This study also demonstrated that an iron-emulsion system could be delivered in-situ to the DNAPL pool in a soil matrix by using a simulated push well technique. Iron emulsions degraded pure TCE at a rate comparable to the degradation of dissolved phase TCE by iron particles, while pure iron had a very low degradation rate for free-phase TCE. The iron-emulsion systems can be injected into a sand matrix where they become immobilized and are not moved by flowing water. It has been documented that surfactant micelles possess the ability to pull pooled TCE into emulsion droplets where degradation of TCE takes place.

  13. Polymerization in emulsion microdroplet reactors

    NASA Astrophysics Data System (ADS)

    Carroll, Nick J.

    The goal of this research project is to utilize emulsion droplets as chemical reactors for execution of complex polymerization chemistries to develop unique and functional particle materials. Emulsions are dispersions of immiscible fluids where one fluid usually exists in the form of drops. Not surprisingly, if a liquid-to-solid chemical reaction proceeds to completion within these drops, the resultant solid particles will possess the shape and relative size distribution of the drops. The two immiscible liquid phases required for emulsion polymerization provide unique and complex chemical and physical environments suitable for the engineering of novel materials. The development of novel non-ionic fluorosurfactants allows fluorocarbon oils to be used as the continuous phase in a water-free emulsion. Such emulsions enable the encapsulation of almost any hydrocarbon compound in droplets that may be used as separate compartments for water-sensitive syntheses. Here, we exemplify the promise of this approach by suspension polymerization of polyurethanes (PU), in which the liquid precursor is emulsified into droplets that are then converted 1:1 into polymer particles. The stability of the droplets against coalescence upon removal of the continuous phase by evaporation confirms the formation of solid PU particles. These results prove that the water-free environment of fluorocarbon based emulsions enables high conversion. We produce monodisperse, cross-linked, and fluorescently labeled PU-latexes with controllable mesh size through microfluidic emulsification in a simple one-step process. A novel method for the fabrication of monodisperse mesoporous silica particles is presented. It is based on the formation of well-defined equally sized emulsion droplets using a microfluidic approach. The droplets contain the silica precursor/surfactant solution and are suspended in hexadecane as the continuous oil phase. The solvent is then expelled from the droplets, leading to

  14. Magnetoresistive Emulsion Analyzer

    PubMed Central

    Lin, Gungun; Baraban, Larysa; Han, Luyang; Karnaushenko, Daniil; Makarov, Denys; Cuniberti, Gianaurelio; Schmidt, Oliver G.

    2013-01-01

    We realize a magnetoresistive emulsion analyzer capable of detection, multiparametric analysis and sorting of ferrofluid-containing nanoliter-droplets. The operation of the device in a cytometric mode provides high throughput and quantitative information about the dimensions and magnetic content of the emulsion. Our method offers important complementarity to conventional optical approaches involving ferrofluids, and paves the way to the development of novel compact tools for diagnostics and nanomedicine including drug design and screening. PMID:23989504

  15. Magnetoresistive emulsion analyzer.

    PubMed

    Lin, Gungun; Baraban, Larysa; Han, Luyang; Karnaushenko, Daniil; Makarov, Denys; Cuniberti, Gianaurelio; Schmidt, Oliver G

    2013-01-01

    We realize a magnetoresistive emulsion analyzer capable of detection, multiparametric analysis and sorting of ferrofluid-containing nanoliter-droplets. The operation of the device in a cytometric mode provides high throughput and quantitative information about the dimensions and magnetic content of the emulsion. Our method offers important complementarity to conventional optical approaches involving ferrofluids, and paves the way to the development of novel compact tools for diagnostics and nanomedicine including drug design and screening. PMID:23989504

  16. Emulsions Containing Perfluorocarbon Support Cell Cultures

    NASA Technical Reports Server (NTRS)

    Ju, Lu-Kwang; Lee, Jaw Fang; Armiger, William B.

    1990-01-01

    Addition of emulsion containing perfluorocarbon liquid to aqueous cell-culture medium increases capacity of medium to support mammalian cells. FC-40 Fluorinert (or equivalent) - increases average density of medium so approximately equal to that of cells. Cells stay suspended in medium without mechanical stirring, which damages them. Increases density enough to prevent cells from setting, and increases viscosity of medium so oxygen bubbled through it and nutrients stirred in with less damage to delicate cells.

  17. Researching Television News Archives.

    ERIC Educational Resources Information Center

    Wilhoit, Frances Goins

    To demonstrate the uses and efficiency of major television news archives, a study was conducted to describe major archival programs and to compare the Vanderbilt University Television News Archives and the CBS News Index. Network coverage of an annual news event, the 1983 State of the Union address, is traced through entries in both. The findings…

  18. Measuring News Media Literacy

    ERIC Educational Resources Information Center

    Maksl, Adam; Ashley, Seth; Craft, Stephanie

    2015-01-01

    News media literacy refers to the knowledge and motivations needed to identify and engage with journalism. This study measured levels of news media literacy among 500 teenagers using a new scale measure based on Potter's model of media literacy and adapted to news media specifically. The adapted model posits that news media literate individuals…

  19. Magnetofluid emulsion: New magnetocontrolled media

    NASA Astrophysics Data System (ADS)

    Bashtovoi, Victor G.; Yarmolchik, Yuri P.

    1994-03-01

    This study has shown that flow dynamics of emulsion consisting of magnetic and nonmagnetic fluids depends on applied magnetic field. So these emulsions may be considered as a magnetic field controlled medium, and in particular as a magnetic field controlled heat carrier. The new dates on rheological properties of these emulsions in the presence of magnetic field are described.

  20. News & Announcements

    NASA Astrophysics Data System (ADS)

    2001-09-01

    Helge H. Wehmeier, President and Chief Executive Office of Bayer Corporation, is the recipient of the 2001 Leadership in Education Award from the Keystone Center. Wehmeier was cited for his support in spearheading ongoing education and volunteer efforts such as Bayer's Making Science Make Sense program, which, in partnership with NSF, advances science literacy through hands-on, inquiry-based science learning.

    You are invited to send contributions to the News & Announcements column. They should be sent to Elizabeth A. Moore, Associate Editor, by email or by mail at Journal of Chemical Education, 209 N. Brooks St., Madison, WI 53715-1116. Contributions should be concise, to the point, and appropriate for the Journal's audience. They may be edited for clarity, timeliness, appropriateness, or length.

  1. Development of High Sensitivity Nuclear Emulsion and Fine Grained Emulsion

    NASA Astrophysics Data System (ADS)

    Kawahara, H.; Asada, T.; Naka, T.; Naganawa, N.; Kuwabara, K.; Nakamura, M.

    2014-08-01

    Nuclear emulsion is a particle detector having high spacial resolution and angular resolution. It became useful for large statistics experiment thanks to the development of automatic scanning system. In 2010, a facility for emulsion production was introduced and R&D of nuclear emulsion began at Nagoya university. In this paper, we present results of development of the high sensitivity emulsion and fine grained emulsion for dark matter search experiment. Improvement of sensitivity is achieved by raising density of silver halide crystals and doping well-adjusted amount of chemicals. Production of fine grained emulsion was difficult because of unexpected crystal condensation. By mixing polyvinyl alcohol (PVA) to gelatin as a binder, we succeeded in making a stable fine grained emulsion.

  2. Pickering emulsions stabilized by paraffin wax and Laponite clay particles.

    PubMed

    Li, Caifu; Liu, Qian; Mei, Zhen; Wang, Jun; Xu, Jian; Sun, Dejun

    2009-08-01

    Emulsions containing wax in dispersed droplets stabilized by disc-like Laponite clay particles are prepared. Properties of the emulsions prepared at different temperatures are examined using stability, microscopy and droplet-size analysis. At low temperature, the wax crystals in the oil droplets can protrude through the interface, leading to droplet coalescence. But at higher temperatures, the droplet size decreases with wax concentration. Considering the viscosity of the oil phase and the interfacial tension, we conclude that the wax is liquid-like during the high temperature emulsification process, but during cooling wax crystals appear around the oil/water interface and stabilize the droplets. The oil/water ratio has minimal effect on the emulsions between ratios of 3:7 and 7:3. The Laponite is believed to stabilize the emulsions by increasing the viscosity of the continuous phase and also by adsorbing at the oil/water interface, thus providing a physical barrier to coalescence. PMID:19428022

  3. Chitosan macroporous foams obtained in highly concentrated emulsions as templates.

    PubMed

    Miras, Jonathan; Vílchez, Susana; Solans, Conxita; Esquena, Jordi

    2013-11-15

    Emulsion templating is an effective route for the preparation of macroporous polymer foams, with well-defined pore structures. This kind of material is usually obtained by polymerization or crosslinking in the external phase of highly concentrated emulsions. The present article describes the synthesis of macroporous foams based on a cationic polymer, chitosan, crosslinked with genipin, a natural crosslinker. The phase behavior was used to study the influence of chitosan on surfactant self-aggregation. Hexagonal and lamellar liquid crystalline structures could be obtained in the presence of chitosan, and polymer did not greatly influence the geometric lattice parameters of these self-aggregates. O/W highly concentrated emulsions were obtained in the presence of chitosan in the continuous phase, which allowed reducing both droplet size and polydispersity. The emulsions were stable during the time required for crosslinking, obtaining macroporous foams with high pore volume and degree of crosslinking. PMID:24011788

  4. Dynamically reconfigurable complex emulsions via tunable interfacial tensions

    PubMed Central

    Zarzar, Lauren D.; Sresht, Vishnu; Sletten, Ellen M.; Kalow, Julia A.; Blankschtein, Daniel; Swager, Timothy M.

    2015-01-01

    Emulsification is a powerful, well-known technique for mixing and dispersing immiscible components within a continuous liquid phase. Consequently, emulsions are central components of medicine, food and performance materials. Complex emulsions, including multiple emulsions and Janus droplets which contain hemispheres of differing material, are of increasing importance1 in pharmaceuticals and medical diagnostics2, in the fabrication of microparticles and capsules3–5 for food6, in chemical separations7, in cosmetics8, and in dynamic optics9. Because complex emulsion properties and functions are related to the droplet geometry and composition, the development of rapid, simple fabrication approaches allowing precise control over the droplets’ physical and chemical characteristics is critical. Significant advances in the fabrication of complex emulsions have been made using a number of procedures, ranging from large-scale, less precise techniques that give compositional heterogeneity using high-shear mixers and membranes10, to small-volume but more precise microfluidic methods11,12. However, such approaches have yet to create droplet morphologies that can be controllably altered after emulsification. Reconfigurable complex liquids potentially have greatly increased utility as dynamically tunable materials. Here we describe an approach to the one-step fabrication of three- and four-phase complex emulsions with highly controllable and reconfigurable morphologies. The fabrication makes use of the temperature-sensitive miscibility of hydrocarbon, silicone and fluorocarbon liquids, and is applied to both the microfluidic and the scalable batch production of complex droplets. We demonstrate that droplet geometries can be alternated between encapsulated and Janus configurations by varying the interfacial tensions using hydrocarbon and fluorinated surfactants including stimuli-responsive and cleavable surfactants. This yields a generalizable strategy for the fabrication of

  5. Dynamically reconfigurable complex emulsions via tunable interfacial tensions

    NASA Astrophysics Data System (ADS)

    Zarzar, Lauren D.; Sresht, Vishnu; Sletten, Ellen M.; Kalow, Julia A.; Blankschtein, Daniel; Swager, Timothy M.

    2015-02-01

    Emulsification is a powerful, well-known technique for mixing and dispersing immiscible components within a continuous liquid phase. Consequently, emulsions are central components of medicine, food and performance materials. Complex emulsions, including Janus droplets (that is, droplets with faces of differing chemistries) and multiple emulsions, are of increasing importance in pharmaceuticals and medical diagnostics, in the fabrication of microparticles and capsules for food, in chemical separations, in cosmetics, and in dynamic optics. Because complex emulsion properties and functions are related to the droplet geometry and composition, the development of rapid, simple fabrication approaches allowing precise control over the droplets' physical and chemical characteristics is critical. Significant advances in the fabrication of complex emulsions have been made using a number of procedures, ranging from large-scale, less precise techniques that give compositional heterogeneity using high-shear mixers and membranes, to small-volume but more precise microfluidic methods. However, such approaches have yet to create droplet morphologies that can be controllably altered after emulsification. Reconfigurable complex liquids potentially have great utility as dynamically tunable materials. Here we describe an approach to the one-step fabrication of three- and four-phase complex emulsions with highly controllable and reconfigurable morphologies. The fabrication makes use of the temperature-sensitive miscibility of hydrocarbon, silicone and fluorocarbon liquids, and is applied to both the microfluidic and the scalable batch production of complex droplets. We demonstrate that droplet geometries can be alternated between encapsulated and Janus configurations by varying the interfacial tensions using hydrocarbon and fluorinated surfactants including stimuli-responsive and cleavable surfactants. This yields a generalizable strategy for the fabrication of multiphase emulsions with

  6. National Cancer Institute News

    MedlinePlus

    ... Workshop NCI Annual Fact Book NCI Visuals Online Social Media @NCIMedia NCI YouTube Subscribe to NCI News Releases ... posts Subscribe Events Scientific Meetings and Lectures Conferences Social Media Events News Archive 2015 2014 2013 2012 2011 ...

  7. Double Emulsion Templated Celloidosomes

    NASA Astrophysics Data System (ADS)

    Arriaga, Laura R.; Marquez, Samantha M.; Kim, Shin-Hyun; Chang, Connie; Wilking, Jim; Monroy, Francisco; Marquez, Manuel; Weitz, David A.

    2012-02-01

    We present a novel approach for fabricating celloidosomes, which represent a hollow and spherical three-dimensional self-assembly of living cells encapsulating an aqueous core. Glass- capillary microfluidics is used to generate monodisperse water-in-oil-in-water double emulsion templates using lipids as stabilizers. Such templates allow for obtaining single but also double concentric celloidosomes. In addition, after a solvent removal step the double emulsion templates turn into monodisperse lipid vesicles, whose membrane spontaneously phase separates when choosing the adequate lipid composition, providing the adequate scaffold for fabricating Janus-celloidosomes. These structures may find applications in the development of bioreactors in which the synergistic effects of two different types of cells selectively adsorbed on one of the vesicle hemispheres may be exploited.

  8. FINE GRAIN NUCLEAR EMULSION

    DOEpatents

    Oliver, A.J.

    1962-04-24

    A method of preparing nuclear track emulsions having mean grain sizes less than 0.1 microns is described. The method comprises adding silver nitrate to potassium bromide at a rate at which there is always a constant, critical excess of silver ions. For minimum size grains, the silver ion concentration is maintained at the critical level of about pAg 2.0 to 5.0 during prectpitation, pAg being defined as the negative logarithm of the silver ion concentration. It is preferred to eliminate the excess silver at the conclusion of the precipitation steps. The emulsion is processed by methods in all other respects generally similar to the methods of the prior art. (AEC)

  9. Formulation, stability and degradation kinetics of intravenous cinnarizine lipid emulsion.

    PubMed

    Shi, Shuai; Chen, Hao; Cui, Yue; Tang, Xing

    2009-05-21

    Cinnarizine was loaded in the lipid emulsion to develop an intravenous formulation with good physical and chemical stability. High-pressure homogenization was used to prepare the lipid emulsion. The factors influencing the stability of cinnarizine lipid emulsion, such as different drug loading methods, pH, temperature, sterilization methods and sterilization time were monitored by high-performance liquid chromatograph. The degradation of cinnarizine in aqueous solution and lipid emulsion both followed apparent first-order kinetics. A possible degradation mechanism was postulated by the bell-shaped pH-rate profile of cinnarizine. Localization of the drug in the interfacial lecithin layer significantly improved the chemical stability of cinnarizine and its stabilizing mechanism was thoroughly discussed and proved. The activation energy of cinnarizine in lipid emulsion was calculated to be 51.27 kJ/mol which was similar to that in aqueous solution. This indicates that the stabilizing effect of the drug carrier on cinnarizine was not an alteration of the degradation reaction. In addition, shelf-life of cinnarizine in lipid emulsion was estimated to be 1471.6 days at 4 degrees C, which is much longer compared with 19.8 days in aqueous solution. The final products were stable enough to resist a 121 degrees C rotating steam sterilization for 15 min. PMID:19429300

  10. News: A Consumer's Guide.

    ERIC Educational Resources Information Center

    Doig, Ivan; Doig, Carol

    A guide to news media, this book describes how to tell when a report is biased; provides tips on spotting hoaxes and public relations ploys in the news; gives standards to judge expert opinion and reliable sources; lists critics and other sources of help for the news consumer; discusses the endless contest among politicians, newsmen, and…

  11. Pickering emulsions with controllable stability.

    PubMed

    Melle, Sonia; Lask, Mauricio; Fuller, Gerald G

    2005-03-15

    We prepare solid-stabilized emulsions using paramagnetic particles at an oil/water interface that can undergo macroscopic phase separation upon application of an external magnetic field. A critical field strength is found for which emulsion droplets begin to translate into the continuous-phase fluid. At higher fields, the emulsions destabilize, leading to a fully phase-separated system. This effect is reversible, and long-term stability can be recovered by remixing the components with mechanical agitation. PMID:15752002

  12. News & Announcements

    NASA Astrophysics Data System (ADS)

    2001-08-01

    News from Journal House

    National Chemistry Week (NCW)

    National Chemistry Week Celebrating Chemistry and Art is the theme of NCW 2001, to be held November 4-10, 2001. As you make plans for participating in the celebrations in your area, keep in mind that JCE is developing special materials on this theme, which will appear in our October issue: Classroom Activities, a comprehensive Illustrated Resource Paper, Report from Online, specially written brief articles illustrated in color, articles related to the theme, and CLIPs (Chemical Laboratory Information Profiles).

    Awards Announced

    Passer Award

    Passer Award recipients from the April 1 closing date are:
    • George Bennett, Millikin University, Decatur, IL
    • Daniel Berger, Bluffton College, Bluffton, OH
    • Karen Dunlap, Sierra College, Rocklin, CA
    • Myung-Hoon Kim, Georgia Perimeter College, Dunwoody, GA
    • Cheryl Longfellow, Philadelphia University, Philadelphia, PA
    • Jerry Maas, Oakton Community College, Des Plaines, IL
    • Tim Royappa, University of West Florida, Pensacola, FL

    Visiting Scientist Award, Western Connecticut Section

    Diane Bunce, The Catholic University of America, has been selected as the 2001 Visiting Scientist of the Western Connecticut Section of the ACS. The award, presented annually since 1967, brings an outstanding chemical educator to visit high schools in Fairfield County, CT. In May, Bunce visited three high schools, Christian Heritage School, Fairfield High School, and Greenwich High School, where she interacted with teachers and students and presented lectures and demonstrations to several chemistry classes. She was also keynote speaker at the ACS local section's Education Night. The awardee is selected by a committee of university and high school teachers, industrial chemists, and the previous Visiting Scientist

  13. Formation and stability of polychlorinated biphenyl Pickering emulsions

    NASA Astrophysics Data System (ADS)

    Roy-Perreault, Andréanne; Kueper, Bernard H.; Rawson, Jim

    2005-03-01

    An emulsion stabilized by colloidal suspensions of finely divided solids is known as a Pickering emulsion. The potential for polychlorinated biphenyls (PCBs) to form Pickering emulsions ex situ when in contact with powdered solids, such as clays and metal oxides, is investigated here. Bentonite, iron oxide and magnesium oxide dispersions proved to be robust Pickering emulsion stabilizers, whereas manganese oxide dispersions were not. Batch experiments revealed that emulsions can be formed using a moderately low energy input and can be stabilized with solid concentrations as low as 0.5 wt.%. For the base conditions (volumetric oil fraction ( ϕoil)=30 vol.%; solid concentration ( χ)=2 wt.%), the formed emulsions were indefinitely stable and the initial average droplet diameters varied from 80 to 258 μm, depending on the solid used in the colloidal dispersion. The average droplet size varied at early time, but for most conditions stabilized to a steady-state value 1 week after preparation. The effect of Ostwald ripening was limited. At greater than 0.5 wt.% concentration, the efficiency of the solid dispersion as a stabilizer was dependant on the volumetric oil fraction but not on the solid concentration. Generally, systems with volumetric oil fractions outside of the 20-70 vol.% range were unstable. The emulsions' droplet stability, average droplet size and size distribution were observed to vary as a function of the amount of energy provided to the system, the volumetric oil fraction, and the concentration of the solid in the aqueous dispersion. It is hypothesized that drilling through fractured rock in the immediate vicinity of dense, non-aqueous phase liquid (DNAPL) PCBs may provide both the energy and solid material necessary to form Pickering emulsions.

  14. E-Cig Liquid Nicotine Containers Often Mislabeled

    MedlinePlus

    ... medlineplus.gov/news/fullstory_160108.html E-Cig Liquid Nicotine Containers Often Mislabeled Also, many aren't ... July 27, 2016 (HealthDay News) -- Containers that hold liquid nicotine for electronic cigarettes may not be labeled ...

  15. News & Announcements

    NASA Astrophysics Data System (ADS)

    2001-08-01

    News from Journal House

    National Chemistry Week (NCW)

    National Chemistry Week Celebrating Chemistry and Art is the theme of NCW 2001, to be held November 4-10, 2001. As you make plans for participating in the celebrations in your area, keep in mind that JCE is developing special materials on this theme, which will appear in our October issue: Classroom Activities, a comprehensive Illustrated Resource Paper, Report from Online, specially written brief articles illustrated in color, articles related to the theme, and CLIPs (Chemical Laboratory Information Profiles).

    Awards Announced

    Passer Award

    Passer Award recipients from the April 1 closing date are:
    • George Bennett, Millikin University, Decatur, IL
    • Daniel Berger, Bluffton College, Bluffton, OH
    • Karen Dunlap, Sierra College, Rocklin, CA
    • Myung-Hoon Kim, Georgia Perimeter College, Dunwoody, GA
    • Cheryl Longfellow, Philadelphia University, Philadelphia, PA
    • Jerry Maas, Oakton Community College, Des Plaines, IL
    • Tim Royappa, University of West Florida, Pensacola, FL

    Visiting Scientist Award, Western Connecticut Section

    Diane Bunce, The Catholic University of America, has been selected as the 2001 Visiting Scientist of the Western Connecticut Section of the ACS. The award, presented annually since 1967, brings an outstanding chemical educator to visit high schools in Fairfield County, CT. In May, Bunce visited three high schools, Christian Heritage School, Fairfield High School, and Greenwich High School, where she interacted with teachers and students and presented lectures and demonstrations to several chemistry classes. She was also keynote speaker at the ACS local section's Education Night. The awardee is selected by a committee of university and high school teachers, industrial chemists, and the previous Visiting Scientist

  16. News & Announcements

    NASA Astrophysics Data System (ADS)

    2000-01-01

    News from Journal House

    Guidelines for Submission The Journal's current Guide to Submissions can be found on pages 29-30 of this issue. They have been streamlined a bit and also include a handy check list. This information is also available on JCE Online at http://jchemed.chem.wisc.edu/Journal/Authors/. Wanted: Demo Checkers The Tested Demonstrations column needs people who like to try out demos. Column editor Ed Vitz is looking for additional volunteers to serve as "checkers" for manuscripts that have been submitted to the Journal for possible publication as Tested Demonstrations. A checker is expected to perform two functions: to review the manuscript for accuracy and novelty, and to attempt to perform the demonstration according to the procedure supplied by the author. Checkers may suggest important improvements in demonstration procedures, and for their efforts they are cited in the byline when the manuscript is published. For instance, the demo showing the yellow cascading precipitates (lead iodide) made from potassium iodide and lead nitrate was submitted by Wobbe de Vos and checked by Kim Kostka. The (yellow) cascading precipitates are from "Using Large Glass Cylinders To Demonstrate Chemical Reactions" that appeared in the April 1999 issue of JCE. We prefer that checkers begin the review process (which may in some cases involve procuring supplies) very soon after being contacted so that their review can be completed in the timely manner that authors deserve. Checkers are usually teachers who routinely present lecture demonstrations in their classes in either high school or colleges. We try not to call on checkers more often than once a year, which is one of the reasons for this request. Another is that we lose many highly valued, experienced checkers to retirement or other endeavors. Prospective checkers may want to look at a copy of the JCE Tested Demonstration Evaluation Form. It can be found on the Web at http://www.kutztown.edu/ vitz

  17. News & Announcements

    NASA Astrophysics Data System (ADS)

    2000-01-01

    News from Journal House

    Guidelines for Submission The Journal's current Guide to Submissions can be found on pages 29-30 of this issue. They have been streamlined a bit and also include a handy check list. This information is also available on JCE Online at http://jchemed.chem.wisc.edu/Journal/Authors/. Wanted: Demo Checkers The Tested Demonstrations column needs people who like to try out demos. Column editor Ed Vitz is looking for additional volunteers to serve as "checkers" for manuscripts that have been submitted to the Journal for possible publication as Tested Demonstrations. A checker is expected to perform two functions: to review the manuscript for accuracy and novelty, and to attempt to perform the demonstration according to the procedure supplied by the author. Checkers may suggest important improvements in demonstration procedures, and for their efforts they are cited in the byline when the manuscript is published. For instance, the demo showing the yellow cascading precipitates (lead iodide) made from potassium iodide and lead nitrate was submitted by Wobbe de Vos and checked by Kim Kostka. The (yellow) cascading precipitates are from "Using Large Glass Cylinders To Demonstrate Chemical Reactions" that appeared in the April 1999 issue of JCE. We prefer that checkers begin the review process (which may in some cases involve procuring supplies) very soon after being contacted so that their review can be completed in the timely manner that authors deserve. Checkers are usually teachers who routinely present lecture demonstrations in their classes in either high school or colleges. We try not to call on checkers more often than once a year, which is one of the reasons for this request. Another is that we lose many highly valued, experienced checkers to retirement or other endeavors. Prospective checkers may want to look at a copy of the JCE Tested Demonstration Evaluation Form. It can be found on the Web at http://www.kutztown.edu/ vitz

  18. Produced fluid emulsions. Final report

    SciTech Connect

    Hurley, C.F.; Himmelblau, A.; Trom, L.

    1984-09-01

    Emulsion production and stabilization may be due to one or more of several phenomenon including water-oil ratio, oil and brine chemistry, and surfactant and polymer type and concentration. They may influence emulsification either independently or with dependence on one or more of the other factors. Task One has tried to define which factors are dominant and what effect variations in them will have on the emulsion characteristics for each of the fields investigated. Emulsions were produced using a hand homogenizer at a fixed setting for a specific length of time to ensure all samples were produced uniformly. A du Nouy apparatus was used to measure surface and interfacial tensions and a binocular microscope was used in the micro-visual studies. The emulsions were treated in a similar manner with a wide variety of materials to not only break them, but also to help define which mechanisms are responsible for the stabilization of a particular emulsion. Core floods in Task Two utilized a six-foot sand-pack for a mixing medium. A six-inch long Berea core which followed, provided shear similar to that of the reservoir. The choice of oil, brine, surfactant and polymer were chosen to correlate to the Task One studies. Similarities and differences in the results between the bench-top and core flood studies are noted. The conditions of emulsion production and characteristics and the effectiveness of emulsion breakers are compared to help determine the mechanism of emulsion stabilization. 8 figures, 85 tables.

  19. News & Announcements

    NASA Astrophysics Data System (ADS)

    2000-02-01

    News from Journal House

    Journal Ambassadors, 1999 What do the people listed below have in common? A search of our records indicates that each has been a participant in our Journal Ambassador program during 1999.
    • Guy Anderson
    • Jim Becvar
    • Jerry Bell
    • Jim Birk
    • Diane Bunce
    • Ann Cartwright
    • Thomas Clark
    • Jane Crosby
    • Maria Dean
    • Art Ellis
    • Donald Elswick
    • Tommy Franklin
    • Babu George
    • Paul Heath
    • Angela Hoffman
    • Lynn Hogue
    • J. J. Lagowski
    • Frank Lambert
    • Dorothy Lehmkuhl
    • George Lelevre
    • Scott Luaders
    • Jane McMullen
    • Marci Merritt
    • Carl Minnier
    • Richard Narske
    • Ron Perkins
    • Gabriel Pinto
    • Dick Potts
    • Herb Retcofsky
    • Jerry Sarquis
    • Elke Schoffers
    • Sara Selfe
    • Uni Susskind
    • J. Mark Tolman
    • John Varine
    • Dawn Wakeley
    • Marla White
    Those who are a part of this program take materials about the Journal to workshops, outreach programs, seminars, regional meetings, award nights, short courses, and other events at home and abroad, places where people who are interested in chemical education gather. Given about three weeks notice, we can outfit you with a variety of materials that will help others get tuned in to the good things that are happening in chemical education. We can send you an assortment of Journal issues, subscription forms, our Publications/Software Catalog, reprints from the Viewpoints series, copies of Classroom Activities, or JCE Gift Award Certificates, assuming that supplies are available. Of course we can arrange for the group to have temporary access to JCE Online. We can send you a brochure about the Ambassador program or answer any questions - just ask: email to jce@chem.wisc.edu; phone 1-800-991-5534 (U.S.) or 608-262-5153 (non-U.S.); fax 608-265-8094. If by chance you were a Journal Ambassador in 1999 but your name was not included, just let us know so that you can be recognized in a future column. Gift

  20. News & Announcements

    NASA Astrophysics Data System (ADS)

    1999-08-01

    News from Journal House Perspective on JCE Online Recently a reader asked us for a perspective on JCE Onlinehow the chemical education community is receiving it and how the Journal staff itself views it. We share our responses below. Subscriber Numbers How many people subscribe to JCE Online+? As of June 1, 1999, our records show that 13% of individual JCE subscriptions in the USA include JCE Online+. This percentage has increased significantly during the past year- in June 1998 it was approximately 4% and December 1998 about 7%. Almost all subscribers to JCE Online subscribe to print as well. Since JCE Online has only very recently been made available to institutional subscribers, there are no numbers to report. There has been considerable interest in online from libraries. Given that JCE Online+ is a fairly recent subscriber option and that many subscribers have a wait-and-see approach to any new option, we feel that the numbers above are quite high. The steady growth is encouraging. Online Usage How many people visit our Web site? Statistics for the period January 1, 1999, through May 31, 1999, that may be of interest include:

    Total Pages Served 361,115

    Total Visits 138,377

    Total Unique Visitors 51,744

    Total Repeat Visitors 11,536

    Average Visit Length 03:05

    Average Requests/Visit 10.8

    Average Pages/Visit 2.6

    Average Daily Visits 916 Online Rationale and Expectations JCE Online is a very important part of the whole Journal, but we do not expect it to supplant print: online and print are very different media. Usage of JCE Online is growing steadily; our subscribers are realizing what we have learned: it is not possible to deliver the Journal in the print medium alone- print is no longer adequate to accomplish our mission. Examples of things not possible in print include:

    ·JCE Index to all 76

  1. "Good News" Tune Makes Discussion of "Bad News" Sing.

    ERIC Educational Resources Information Center

    Sneed, Don

    1984-01-01

    Recommends playing Anne Murray's recording of "A Little Good News" to promote discussion about the nature of news and Bobbie Gentry's "Ode to Billy Joe" for discussion on writing news stories about suicides. (CRH)

  2. Stabilization of Oil-in-Water Emulsions with Noninterfacially Adsorbed Particles.

    PubMed

    Pilapil, Brandy K; Jahandideh, Heidi; Bryant, Steven L; Trifkovic, Milana

    2016-07-19

    Classical (surfactant stabilized) and Pickering (particle stabilized) type emulsions have been widely studied to elucidate the mechanisms by which emulsion stabilization is achieved. In Pickering emulsions, a key defining factor is that the stabilizing particles reside at the liquid-liquid interface providing a mechanical barrier to droplet coalescence. This interfacial adsorption is achieved through the use of nanoparticles that are partially wet by both liquid phases, often through covalent surface modification of or surfactant adsorption to the nanoparticle surfaces. Herein, we demonstrate particle-induced stabilization of an oil-in-water emulsion with fully water wet nanoparticles (no interfacial adsorption) via synergistic interaction with low concentrations of surfactants. Laser scanning confocal microscopy analysis allows for unique and vital insights into the properties of these emulsions via both three-dimensional imaging and real-time monitoring of particle dynamics at the oil-water interface. Investigation of these "non-Pickering" particle stabilized emulsions suggests that the nonadsorbed particles impart stability to the emulsion primarily via entropic forces imparted by the accumulation of silica nanoparticles in the coherent phase between dispersed oil droplets. PMID:27351486

  3. News & Announcements

    NASA Astrophysics Data System (ADS)

    1999-08-01

    News from Journal House Perspective on JCE Online Recently a reader asked us for a perspective on JCE Onlinehow the chemical education community is receiving it and how the Journal staff itself views it. We share our responses below. Subscriber Numbers How many people subscribe to JCE Online+? As of June 1, 1999, our records show that 13% of individual JCE subscriptions in the USA include JCE Online+. This percentage has increased significantly during the past year- in June 1998 it was approximately 4% and December 1998 about 7%. Almost all subscribers to JCE Online subscribe to print as well. Since JCE Online has only very recently been made available to institutional subscribers, there are no numbers to report. There has been considerable interest in online from libraries. Given that JCE Online+ is a fairly recent subscriber option and that many subscribers have a wait-and-see approach to any new option, we feel that the numbers above are quite high. The steady growth is encouraging. Online Usage How many people visit our Web site? Statistics for the period January 1, 1999, through May 31, 1999, that may be of interest include:

    Total Pages Served 361,115

    Total Visits 138,377

    Total Unique Visitors 51,744

    Total Repeat Visitors 11,536

    Average Visit Length 03:05

    Average Requests/Visit 10.8

    Average Pages/Visit 2.6

    Average Daily Visits 916 Online Rationale and Expectations JCE Online is a very important part of the whole Journal, but we do not expect it to supplant print: online and print are very different media. Usage of JCE Online is growing steadily; our subscribers are realizing what we have learned: it is not possible to deliver the Journal in the print medium alone- print is no longer adequate to accomplish our mission. Examples of things not possible in print include:

    ·JCE Index to all 76

  4. Protein Fibrils Induce Emulsion Stabilization.

    PubMed

    Peng, Jinfeng; Simon, Joana Ralfas; Venema, Paul; van der Linden, Erik

    2016-03-01

    The behavior of an oil-in-water emulsion was studied in the presence of protein fibrils for a wide range of fibril concentrations by using rheology, diffusing wave spectroscopy, and confocal laser scanning microscopy. Results showed that above a minimum fibril concentration depletion flocculation occurred, leading to oil droplet aggregation and enhanced creaming of the emulsion. Upon further increasing the concentration of the protein fibrils, the emulsions were stabilized. In this stable regime both aggregates of droplets and single droplets are present, and these aggregates are smaller than the aggregates in the flocculated emulsion samples at the lower fibril concentrations. The size of the droplet aggregates in the stabilized emulsions is independent of fibril concentration. In addition, the droplet aggregation was reversible upon dilution both by a pH 2 HCl solution and by a fibril solution at the same concentration. The viscosity of the emulsions containing fibrils was comparable to that of the pure fibril solution. Neither fibril networks nor droplet gel networks were observed in our study. The stabilization mechanism of emulsions containing long protein fibrils at high protein fibril concentrations points toward the mechanism of a kinetic stabilization. PMID:26882086

  5. Freeze-thaw stability of water-in-oil emulsions.

    PubMed

    Ghosh, S; Rousseau, D

    2009-11-01

    Factors influencing water-in-oil emulsion stability during freeze/thaw-cycling, namely interfacial crystallization vs. network crystallization and the sequence of crystallization events (i.e., dispersed vs. continuous phase or vice versa), are assessed. We show that destabilization is most apparent with a liquid-state emulsifier and a continuous oil phase that solidifies prior to the dispersed phase. Emulsions stable to F/T-cycling are obtained when the emulsifier crystallizes at the oil-water interface or in emulsions where the continuous phase crystallizes after the dispersed aqueous phase. The materials used are two food-grade oil-soluble emulsifiers - polyglycerol polyricinoleate (PGPR) and glycerol monostearin (GMS) and two continuous oil phases with differing crystallization temperatures - canola oil and coconut oil. Emulsion stability is assessed with pulsed field gradient NMR droplet size analysis, sedimentation, microscopy and differential scanning calorimetry. This study demonstrates the sequence of crystallization events and the physical state of the surfactant at the oil-water interface strongly impact the freeze-thaw stability of water-in-oil emulsions. PMID:19683718

  6. Double emulsion formation through hierarchical flow-focusing microchannel

    NASA Astrophysics Data System (ADS)

    Azarmanesh, Milad; Farhadi, Mousa; Azizian, Pooya

    2016-03-01

    A microfluidic device is presented for creating double emulsions, controlling their sizes and also manipulating encapsulation processes. As a result of three immiscible liquids' interaction using dripping instability, double emulsions can be produced elegantly. Effects of dimensionless numbers are investigated which are Weber number of the inner phase (Wein), Capillary number of the inner droplet (Cain), and Capillary number of the outer droplet (Caout). They affect the formation process, inner and outer droplet size, and separation frequency. Direct numerical simulation of governing equations was done using volume of fluid method and adaptive mesh refinement technique. Two kinds of double emulsion formation, the two-step and the one-step, were simulated in which the thickness of the sheath of double emulsions can be adjusted. Altering each dimensionless number will change detachment location, outer droplet size and droplet formation period. Moreover, the decussate regime of the double-emulsion/empty-droplet is observed in low Wein. This phenomenon can be obtained by adjusting the Wein in which the maximum size of the sheath is discovered. Also, the results show that Cain has significant influence on the outer droplet size in the two-step process, while Caout affects the sheath in the one-step formation considerably.

  7. Sensory evaluation of sodium chloride-containing water-in-oil emulsions.

    PubMed

    Rietberg, Matthew R; Rousseau, Dérick; Duizer, Lisa

    2012-04-25

    The sensory perception of water-in-oil emulsions containing a saline-dispersed aqueous phase was investigated. Manipulating saltiness perception was achieved by varying the mass fraction aqueous phase (MFAP), initial salt load, and surfactant concentration [(polyglycerol polyricinoleate (PgPr)] of the emulsions, with formulations based on a central composite design. Saltiness and emulsion thickness were evaluated using a trained sensory panel, and collected data were analyzed using response surface analysis. Emulsion MFAP was the most important factor correlated with increased salt taste intensity. Emulsifier concentration and interactions between NaCl and PgPr had only minor effects. Emulsions more prone to destabilization were perceived as saltier irrespective of their initial salt load. The knowledge gained from this study provides a powerful tool for the development of novel sodium-reduced liquid-processed foods. PMID:22463684

  8. News & Announcements

    NASA Astrophysics Data System (ADS)

    2000-02-01

    News from Journal House

    Journal Ambassadors, 1999 What do the people listed below have in common? A search of our records indicates that each has been a participant in our Journal Ambassador program during 1999.
    • Guy Anderson
    • Jim Becvar
    • Jerry Bell
    • Jim Birk
    • Diane Bunce
    • Ann Cartwright
    • Thomas Clark
    • Jane Crosby
    • Maria Dean
    • Art Ellis
    • Donald Elswick
    • Tommy Franklin
    • Babu George
    • Paul Heath
    • Angela Hoffman
    • Lynn Hogue
    • J. J. Lagowski
    • Frank Lambert
    • Dorothy Lehmkuhl
    • George Lelevre
    • Scott Luaders
    • Jane McMullen
    • Marci Merritt
    • Carl Minnier
    • Richard Narske
    • Ron Perkins
    • Gabriel Pinto
    • Dick Potts
    • Herb Retcofsky
    • Jerry Sarquis
    • Elke Schoffers
    • Sara Selfe
    • Uni Susskind
    • J. Mark Tolman
    • John Varine
    • Dawn Wakeley
    • Marla White
    Those who are a part of this program take materials about the Journal to workshops, outreach programs, seminars, regional meetings, award nights, short courses, and other events at home and abroad, places where people who are interested in chemical education gather. Given about three weeks notice, we can outfit you with a variety of materials that will help others get tuned in to the good things that are happening in chemical education. We can send you an assortment of Journal issues, subscription forms, our Publications/Software Catalog, reprints from the Viewpoints series, copies of Classroom Activities, or JCE Gift Award Certificates, assuming that supplies are available. Of course we can arrange for the group to have temporary access to JCE Online. We can send you a brochure about the Ambassador program or answer any questions - just ask: email to jce@chem.wisc.edu; phone 1-800-991-5534 (U.S.) or 608-262-5153 (non-U.S.); fax 608-265-8094. If by chance you were a Journal Ambassador in 1999 but your name was not included, just let us know so that you can be recognized in a future column. Gift

  9. Institute news

    NASA Astrophysics Data System (ADS)

    1999-11-01

    : Heriot-Watt University 4 Nov: Strathclyde University 17 Nov: York University 24 Nov: Bristol University 1 Dec: Open University 7 Dec: Kent University 14 Dec: Cardiff University 15 Dec: University of Wales, Swansea 24 Jan: Reading University 10 Feb: Abingdon School 16 Feb: Plymouth University 2 Mar: Sheffield University 7 Mar: CLRC Daresbury Laboratory 8 Mar: Liverpool University 9 Mar: Manchester 10 Mar: Lancaster University 15 Mar: Surrey University 16 Mar: Brighton University 17 Mar: St Vincent College, Gosport 22 Mar: Leeds University 23 Mar: Loughborough Grammar School 24 Mar: Oakham School 30 Mar: St Peter's School, Wolverhampton 18 May: University of Hertfordshire 11 Jul: Science Museum 12 Jul: Royal Institution The assistance of the Engineering and Physical Sciences Research Council, CLRC Daresbury Laboratory and DERA Malvern is acknowledged in staging this year's events. Courses, lectures and competitions `Physics in perspective', the study course for sixth-formers and college students, will take place in London on 6 - 8 February 2000, offering insights into many different aspects of physics. The programme commences during the afternoon of Sunday 6 February at King's College London with a Balloon debate, followed by Brian O'Rourke's talk on the `Physics of Formula 1 cars'. On Monday 7 February at the Royal Institution, John Avison (former Honorary Editor of Physics Education) will develop the `Thinking physics' theme by presenting the audience with varied topics in an unusual and challenging way. The second talk of the afternoon, by Professor Roy Sambles, will cover `Lasers, light and liquid crystals'. On the final day (Tuesday 8 February), again at the Royal Institution, Sara Ellison will lead the audience in `Heavenly pursuits', whilst later Dr Colin Wright will entertain with `Juggling - theory and practice'. Futher information and bookings for the course can be made by contacting Mrs Leila Solomon at The Institute of Physics, 76 Portland Place, London W1N 3DH

  10. With News Search Engines

    ERIC Educational Resources Information Center

    Gunn, Holly

    2005-01-01

    Although there are many news search engines on the Web, finding the news items one wants can be challenging. Choosing appropriate search terms is one of the biggest challenges. Unless one has seen the article that one is seeking, it is often difficult to select words that were used in the headline or text of the article. The limited archives of…

  11. Absorption of morphine from a slow-release emulsion used to induce morphine dependence in rats.

    PubMed

    Salem, A; Hope, W

    1998-10-01

    This study was performed to measure absorption of morphine from the injection site following treatment of rats with slow-release emulsions formulated with morphine hydrochloride and morphine base. Samples of emulsion were collected from the injection site of halothane anesthetized animals at 24 and 48 h following emulsion treatment and concentrations of morphine remaining in the emulsion were analyzed using high-performance liquid chromatography (HPLC). In another group of morphine-treated rats, at times equivalent to collecting samples of emulsion, the intensity of naloxone-precipitated withdrawal behaviors was monitored. Both morphine base- and hydrochloride-containing emulsions induced a high degree of physical dependence in animals treated over 48 h. Release of morphine from emulsions containing morphine base was slower than that from the hydrochloride formulations. In the 24-h morphine base-treated animals, approximately 45% was absorbed from the injection site as opposed to 99% in the 24-h morphine hydrochloride-treated animals. These results suggest that morphine base containing emulsions provide a more sustained exposure to the opioid. PMID:10334632

  12. Water-oil Janus emulsions: microfluidic synthesis and morphology design.

    PubMed

    Ge, Xue-Hui; Huang, Jin-Pei; Xu, Jian-Hong; Chen, Jian; Luo, Guang-Sheng

    2016-04-14

    In this work we developed a facile method to prepare water-oil Janus emulsions in situ with tunable morphologies by using a double-bore capillary microfluidic device. In addition, by combining the theory model and our liquids' properties, we propose a method to design the morphology of water-oil Janus emulsions. To systematically research Janus morphologies we combined the theory model and the fluids' properties. Under the model guidance, we carefully selected the liquids system where only the interfacial tension between the water phase and the continuous phase changed while keeping the other two interfacial tensions unchanged. Thus we could adjust the Janus morphology by changing the surfactant mass fraction in the continuous phase. In addition, with the double-bore capillary, we prepared water-oil Janus emulsions with a large flow ratio range. By adjusting the flow ratio and the surfactant mass fraction, we successfully prepared Janus emulsions with gradual morphology changes, which would be meaningful in fields that have a high demand for morphology designing of amphiphilic Janus particles. PMID:26947622

  13. Characterization of flaxseed oil emulsions.

    PubMed

    Lee, Pei-En; Choo, Wee-Sim

    2015-07-01

    The emulsifying capacity of surfactants (polysorbate 20, polysorbate 80 and soy lecithin) and proteins (soy protein isolate and whey protein isolate) in flaxseed oil was measured based on 1 % (w/w) of emulsifier. Surfactants showed significantly higher emulsifying capacity compared to the proteins (soy protein isolate and whey protein isolate) in flaxseed oil. The emulsion stability of the flaxseed oil emulsions with whey protein isolate (10 % w/w) prepared using a mixer was ranked in the following order: 1,000 rpm (58 min) ≈ 1,000 rpm (29 min) ≈ 2,000 rpm (35 min) >2,000 rpm (17.5 min). The emulsion stability of the flaxseed oil emulsions with whey protein isolate (10 % w/w) prepared using a homogenizer (Ultra Turrax) was independent of the speed and mixing time. The mean particle size of the flaxseed oil emulsions prepared using the two mixing devices ranged from 23.99 ± 1.34 μm to 47.22 ± 1.99 μm where else the particle size distribution and microstructure of the flaxseed oil emulsions demonstrated using microscopic imaging were quite similar. The flaxseed oil emulsions had a similar apparent viscosity and exhibited shear thinning (pseudoplastic) behavior. The flaxseed oil emulsions had L* value above 70 and was in the red-yellow color region (positive a* and b* values). PMID:26139903

  14. The Origins of Borrowed News.

    ERIC Educational Resources Information Center

    Riffe, Daniel

    A study was conducted to assess the indications in print of news borrowing (reporting news distributed by second hand or government controlled sources) in the 1970s, and to examine the relationship between borrowed news and the restrictions and reductions in newspapers' overseas news staff. The "New York Times" and the "Chicago Tribune" were…

  15. Water Power Program News

    SciTech Connect

    2012-01-19

    News stories about conventional hydropower and marine and hydrokinetic technologies from the U.S. Department of Energy, the Office of Energy Efficiency and Renewable Energy, the Wind and Water Power Program, and other federal agencies.

  16. National PKU News

    MedlinePlus

    ... and History Staff & Board How Much Phe Guthrie-Koch Scholarship Books Resources Support Us Contact Us Donors ... new Amino Acid Analysis Results This Year’s Guthrie-Koch PKU Scholarship Winners © 2016 National PKU News

  17. In the News.

    ERIC Educational Resources Information Center

    Reece, Lauren

    2000-01-01

    A board member in an Iowa district explains the importance of presenting 4-minute summaries of educational news and trends at board meetings. In choosing items for presentation, she considers relevance, context, perspective, terminology, awareness, and national political developments. (MLH)

  18. Turning News into Literature.

    ERIC Educational Resources Information Center

    Otten, Nick; Stelmach, Majorie

    1987-01-01

    Suggests young people can respond to news stories and political issues they feel strongly about through poetry, and presents one student's effective use of satire which lets his emotions "leak through" to the reader. (NH)

  19. Understanding Health News

    MedlinePlus

    ... U V W X Y Z Know the Science: The Facts About Health News Stories Understanding Health ... only on animals without explaining that such basic science may have little immediate significance to people. For ...

  20. Viscoelastic properties of sterically stabilised emulsions and their stability.

    PubMed

    Tadros, Tharwat

    2015-08-01

    The interaction forces between emulsion droplets containing adsorbed polymeric surfactants and the theory of steric stabilisation are briefly described. The results for the viscoelastic properties of O/W emulsions that are stabilised with partially hydrolysed poly(vinyl acetate) that is commonly referred to as poly(vinyl alcohol) (PVA) with 4% vinyl acetate are given. The effect of the oil volume fraction, addition of electrolytes and increasing temperature is described. This allows one to obtain various parameters such as the adsorbed layer thickness, the critical flocculation concentration of electrolyte (CFC) and critical flocculation temperature (CFT) at constant electrolyte concentration. The viscoelastic properties of O/W emulsions stabilised with an A-B-A block copolymer of polyethylene oxide (A) and polypropylene oxide (B) are described. These emulsions behave as viscoelastic liquids showing a cross-over-point between G' (the elastic component of the complex modulus) and G″ (the viscous component of the complex modulus) at a characteristic frequency. Plots of G' and G″ versus oil volume fraction ϕ show the transition from predominantly viscous to predominantly elastic response at a critical volume fraction ϕ(c). The latter can be used to estimate the adsorbed layer thickness of the polymeric surfactants. Results are also shown for W/O emulsions stabilised with an A-B-A block copolymer of polyhydroxystearic acid (PHS, A) and polyethylene oxide (PEO, B). The viscosity volume fraction curves could be fitted to the Dougherty-Krieger equation for hard-spheres. The results could be applied to give an estimate of the adsorbed layer thickness Δ which shows a decrease with increase of the water volume fraction. This is due to the interpenetration and/or compression of the PHS layers on close approach of the water droplets on increasing the water volume fraction. The last section of the review gives an example of O/W emulsion stability using an AB(n) graft

  1. Influence of Steam Injection and Water-in-Oil Emulsions on Diesel Fuel Combustion Performance

    NASA Astrophysics Data System (ADS)

    Sung, Meagan

    Water injection can be an effective strategy for reducing NOx because water's high specific heat allows it to absorb heat and lower system temperatures. Introducing water as an emulsion can potentially be more effective at reducing emissions than steam injection due to physical properties (such as microexplosions) that can improve atomization and increase mixing. Unfortunately, the immiscibility of emulsions makes them difficult to work with so they must be mixed properly. In this effort, a method for adequately mixing surfactant-free emulsions was established and verified using high speed cinematography. As the water to fuel mass ratio (W/F) increased, emulsion atomization tests showed little change in droplet size and spray angle, but a shorter overall breakup point. Dual-wavelength planar laser induced fluorescence (D-PLIF) patternation showed an increase in water near the center of the spray. Steam injection flames saw little change in reaction stability, but emulsion flames experienced significant losses in stability that limited reaction operability at higher W/F. Emulsions were more effective at reducing NOx than steam injection, likely because of liquid water's latent heat of vaporization and the strategic injection of water into the flame core. OH* chemiluminescence showed a decrease in heat release for both methods, though the decrease was greater for emulsions. Both methods saw decreases in flame length for W/F 0.15. Lastly, flame imaging showed a shift towards a redder appearance with the addition or more water, as well as a reduction in flame flares.

  2. BACLOFEN, RACLOPRIDE, AND NALTREXONE DIFFERENTIALLY REDUCE SOLID FAT EMULSION INTAKE UNDER LIMITED ACCESS CONDITIONS

    PubMed Central

    RE, Rao; FHE, Wojnicki; J, Coupland; S, Ghosh; RLW, Corwin

    2009-01-01

    Previous work in rats has demonstrated that an Intermittent (Monday, Wednesday, Friday) schedule of access promotes binge-type consumption of 100% vegetable shortening during a 1-hour period of availability. The present study used novel shortening-derived stable solid emulsions of various fat concentrations. These emulsions were the consistency of pudding and did not demonstrate oil and water phase separation previously reported with oil-based liquid emulsions. Male Sprague-Dawley rats were grouped according to schedule of access (Daily or Intermittent) to one of three concentrations (18%, 32%, 56%) of solid fat emulsion. There were no significant Intermittent vs. Daily differences in amount consumed, due to high intakes in all groups. This indicated the acceptability of the emulsions. Baclofen (GABA-B agonist) and raclopride (D2-like antagonist) both significantly reduced emulsion intake in all Daily groups, but only in the 56% fat Intermittent group. Naltrexone (opioid antagonist), in contrast, significantly reduced 32% and 56% fat emulsion intake in the Intermittent, as well as the Daily groups. These results indicate that the fat intake reducing effects of GABAB activation and D2 blockade depend upon fat concentration and schedule of fat access, while the fat intake reducing effects of opioid blockade depend upon fat concentration but not schedule of access. PMID:18353432

  3. Rosmarinus officinalis L. extract and some of its active ingredients as potential emulsion stabilizers: a new approach to the formation of multiple (W/O/W) emulsion.

    PubMed

    Cizauskaite, Ugne; Ivanauskas, Liudas; Jakštas, Valdas; Marksiene, Ruta; Jonaitiene, Laimute; Bernatoniene, Jurga

    2016-09-01

    Nowadays, novel topical formulations loaded with natural functional actives are under intense investigations. Therefore, the aim of our study was to evaluate how the rosemary extract and some of its active ingredients [rosmarinic acid (RA), ursolic acid (UA) and oleanolic acid (OA)] affect technological characteristics of multiple emulsion. Formulation has been prepared by adding investigated solutions (10%) in water/oil/water (W/O/W) multiple emulsion consisting of different lipophilic phases: olive oil and liquid paraffin, with 0.5% emulsifying agent (complex of sodium polyacrylate and polysorbate 20) under constant stirring with mechanical stirrer at room temperature. The emulsion parameters were evaluated using centrifugation test, freeze-thaw cycle test, microscopical and texture analyses. Rosemary's triterpenic saponins UA and OA showed the highest emulsion stabilizing properties: they decreased CI from 3.26% to 10.23% (p < 0.05). According to obtained interfacial tension data, the effect of rosemary active ingredients is not surfactant-like. Even though emulsifier itself at low concentration intends to form directly the multiple emulsion, the obtained results indicate that rosemary extract containing active ingredients does not only serve as functional cosmetic agent due to a number of biological activities, but also offer potential advantages as a stabilizer and an enhancer of W/O/W emulsions formation for dermopharmaceutical and cosmetic preparations. PMID:26000558

  4. Emulsion Chamber Technology Experiment (ECT)

    NASA Technical Reports Server (NTRS)

    Gregory, John C.; Takahashi, Yoshiyuki

    1996-01-01

    The experimental objective of Emulsion Chamber Technology (ECT) was to develop space-borne emulsion chamber technology so that cosmic rays and nuclear interactions may subsequently be studied at extremely high energies with long exposures in space. A small emulsion chamber was built and flown on flight STS-62 of the Columbia in March 1994. Analysis of the several hundred layers of radiation-sensitive material has shown excellent post-flight condition and suitability for cosmic ray physics analysis at much longer exposures. Temperature control of the stack was 20 +/-1 C throughout the active control period and no significant deviations of temperature or pressure in the chamber were observed over the entire mission operations period. The unfortunate flight attitude of the orbiter (almost 90% Earth viewing) prevented any significant number of heavy particles (Z greater than or equal to 10) reaching the stack and the inverted flow of shower particles in the calorimeter has not allowed evaluation of absolute primary cosmic ray-detection efficiency nor of the practical time limits of useful exposure of these calorimeters in space to the level of detail originally planned. Nevertheless, analysis of the observed backgrounds and quality of the processed photographic and plastic materials after the flight show that productive exposures of emulsion chambers are feasible in low orbit for periods of up to one year or longer. The engineering approaches taken in the ECT program were proven effective and no major environmental obstacles to prolonged flight are evident.

  5. Controlling molecular transport in minimal emulsions

    PubMed Central

    Gruner, Philipp; Riechers, Birte; Semin, Benoît; Lim, Jiseok; Johnston, Abigail; Short, Kathleen; Baret, Jean-Christophe

    2016-01-01

    Emulsions are metastable dispersions in which molecular transport is a major mechanism driving the system towards its state of minimal energy. Determining the underlying mechanisms of molecular transport between droplets is challenging due to the complexity of a typical emulsion system. Here we introduce the concept of ‘minimal emulsions', which are controlled emulsions produced using microfluidic tools, simplifying an emulsion down to its minimal set of relevant parameters. We use these minimal emulsions to unravel the fundamentals of transport of small organic molecules in water-in-fluorinated-oil emulsions, a system of great interest for biotechnological applications. Our results are of practical relevance to guarantee a sustainable compartmentalization of compounds in droplet microreactors and to design new strategies for the dynamic control of droplet compositions. PMID:26797564

  6. Controlling molecular transport in minimal emulsions

    NASA Astrophysics Data System (ADS)

    Gruner, Philipp; Riechers, Birte; Semin, Benoît; Lim, Jiseok; Johnston, Abigail; Short, Kathleen; Baret, Jean-Christophe

    2016-01-01

    Emulsions are metastable dispersions in which molecular transport is a major mechanism driving the system towards its state of minimal energy. Determining the underlying mechanisms of molecular transport between droplets is challenging due to the complexity of a typical emulsion system. Here we introduce the concept of `minimal emulsions', which are controlled emulsions produced using microfluidic tools, simplifying an emulsion down to its minimal set of relevant parameters. We use these minimal emulsions to unravel the fundamentals of transport of small organic molecules in water-in-fluorinated-oil emulsions, a system of great interest for biotechnological applications. Our results are of practical relevance to guarantee a sustainable compartmentalization of compounds in droplet microreactors and to design new strategies for the dynamic control of droplet compositions.

  7. Controlling molecular transport in minimal emulsions.

    PubMed

    Gruner, Philipp; Riechers, Birte; Semin, Benoît; Lim, Jiseok; Johnston, Abigail; Short, Kathleen; Baret, Jean-Christophe

    2016-01-01

    Emulsions are metastable dispersions in which molecular transport is a major mechanism driving the system towards its state of minimal energy. Determining the underlying mechanisms of molecular transport between droplets is challenging due to the complexity of a typical emulsion system. Here we introduce the concept of 'minimal emulsions', which are controlled emulsions produced using microfluidic tools, simplifying an emulsion down to its minimal set of relevant parameters. We use these minimal emulsions to unravel the fundamentals of transport of small organic molecules in water-in-fluorinated-oil emulsions, a system of great interest for biotechnological applications. Our results are of practical relevance to guarantee a sustainable compartmentalization of compounds in droplet microreactors and to design new strategies for the dynamic control of droplet compositions. PMID:26797564

  8. Synthesis of nanocrystalline CeO{sub 2} particles by different emulsion methods

    SciTech Connect

    Supakanapitak, Sunisa; Boonamnuayvitaya, Virote; Jarudilokkul, Somnuk

    2012-05-15

    Cerium oxide nanoparticles were synthesized using three different methods of emulsion: (1) reversed micelle (RM); (2) emulsion liquid membrane (ELM); and (3) colloidal emulsion aphrons (CEAs). Ammonium cerium nitrate and polyoxyethylene-4-lauryl ether (PE4LE) were used as cerium and surfactant sources in this study. The powder was calcined at 500 Degree-Sign C to obtain CeO{sub 2}. The effect of the preparation procedure on the particle size, surface area, and the morphology of the prepared powders were investigated. The obtained powders are highly crystalline, and nearly spherical in shape. The average particle size and the specific surface area of the powders from the three methods were in the range of 4-10 nm and 5.32-145.73 m{sup 2}/g, respectively. The CeO{sub 2} powders synthesized by the CEAs are the smallest average particle size, and the highest surface area. Finally, the CeO{sub 2} prepared by the CEAs using different cerium sources and surfactant types were studied. It was found that the surface tensions of cerium solution and the type of surfactant affect the particle size of CeO{sub 2}. - Graphical Abstract: The emulsion droplet size distribution and the TEM images of CeO{sub 2} prepared by different methods: reversed micelle (RM), emulsion liquid membrane (ELM) and colloidal emulsion aphrons (CEAs). Highlights: Black-Right-Pointing-Pointer Nano-sized CeO{sub 2} was successfully prepared by three different emulsion methods. Black-Right-Pointing-Pointer The colloidal emulsion aphrons method producing CeO{sub 2} with the highest surface area. Black-Right-Pointing-Pointer The surface tensions of a cerium solution have slightly effect on the particle size. Black-Right-Pointing-Pointer The size control could be interpreted in terms of the adsorption of the surfactant.

  9. The emulsion chamber technology experiment

    NASA Technical Reports Server (NTRS)

    Gregory, John C.

    1992-01-01

    Photographic emulsion has the unique property of recording tracks of ionizing particles with a spatial precision of 1 micron, while also being capable of deployment over detector areas of square meters or 10's of square meters. Detectors are passive, their cost to fly in Space is a fraction of that of instruments of similar collecting. A major problem in their continued use has been the labor intensiveness of data retrieval by traditional microscope methods. Two factors changing the acceptability of emulsion technology in space are the astronomical costs of flying large electronic instruments such as ionization calorimeters in Space, and the power and low cost of computers, a small revolution in the laboratory microscope data-taking. Our group at UAH made measurements of the high energy composition and spectra of cosmic rays. The Marshall group has also specialized in space radiation dosimetry. Ionization calorimeters, using alternating layers of lead and photographic emulsion, to measure particle energies up to 10(exp 15) eV were developed. Ten balloon flights were performed with them. No such calorimeters have ever flown in orbit. In the ECT program, a small emulsion chamber was developed and will be flown on the Shuttle mission OAST-2 to resolve the principal technological questions concerning space exposures. These include assessments of: (1) pre-flight and orbital exposure to background radiation, including both self-shielding and secondary particle generation; the practical limit to exposure time in space can then be determined; (2) dynamics of stack to optimize design for launch and weightlessness; and (3) thermal and vacuum constraints on emulsion performance. All these effects are cumulative and affect our ability to perform scientific measurements but cannot be adequately predicted by available methods.

  10. Science News of the Year.

    ERIC Educational Resources Information Center

    Science News, 1982

    1982-01-01

    Highlights major science news stories of 1982 reported in "Science News." Categories include space/astronomy, biology, chemistry, medicine, energy, physics, anthropology/paleontology, earth sciences, technology, behavior, science/society, and the environment. (JN)

  11. Science News of the Year.

    ERIC Educational Resources Information Center

    Science News, 1983

    1983-01-01

    Highlights important 1983 news stories reported in Science News. Stories are categorized under: anthropology/paleontology; behavior; biology; chemistry; earth sciences; energy; environment; medicine; physics; science and society; space sciences and astronomy; and technology and computers. (JN)

  12. News | Division of Cancer Prevention

    Cancer.gov

    News about scientific advances in cancer prevention, program activities, and new projects are included here in NCI press releases and fact sheets, articles from the NCI Cancer Bulletin, and Clinical Trial News from the NCI website.

  13. Perplexity Analysis of Obesity News Coverage

    PubMed Central

    McFarlane, Delano J.; Elhadad, Noémie; Kukafka, Rita

    2009-01-01

    An important task performed during the analysis of health news coverage is the identification of news articles that are related to a specific health topic (e.g. obesity). This is often done using a combination of keyword searching and manual encoding of news content. Statistical language models and their evaluation metric, perplexity, may help to automate this task. A perplexity study of obesity news was performed to evaluate perplexity as a measure of the similarity of news corpora to obesity news content. The results of this study showed that perplexity increased as news coverage became more general relative to obesity news (obesity news ≈ 187, general health news ≈ 278, general news ≈ 378, general news across multiple publishers ≈ 382). This indicates that language model perplexity can measure the similarity news content to obesity news coverage, and could be used as the basis for an automated health news classifier. PMID:20351893

  14. PLGA microdevices for retinoids sustained release produced by supercritical emulsion extraction: continuous versus batch operation layouts.

    PubMed

    Porta, Giovanna Della; Campardelli, Roberta; Falco, Nunzia; Reverchon, Ernesto

    2011-10-01

    Retinyl acetate (RA) was selected as a model compound to be entrapped in poly(lactic-co-glycolic)acid (PLGA) microspheres using supercritical emulsion extraction (SEE). Several oil-in-water emulsions prepared using acetone and aqueous glycerol (80% glycerol, 20% water) were processed using supercritical carbon dioxide (SC-CO2 ) to extract the oily phase and to induce microspheres formation. The characteristics of the microspheres obtained by conventional liquid emulsion extraction and SEE were also compared: SEE produced spherical and free flowing microspheres, whereas the conventional liquid-liquid extraction showed large intraparticles aggregation. Emulsion extraction by SC-CO2 technology was tested using two different operation layouts: batch (SEE-B) and continuous (SEE-C). SEE-C was performed using a packed tower to produce emulsion/SC-CO2 contact in countercurrent mode, allowing higher microsphere recovery and process efficiencies. Operating at 80 bar and 36°C, SEE-C produced PLGA/RA microspheres with mean sizes between 3.3 and 4.5 μm with an excellent encapsulation efficiency of 80%-90%. Almost all the drug was released in about 6 days when charged at 2.7% (w/w), whereas only 40% and 10% of RA were released in the same period of time when the charge was 5.2% and 8.8% (w/w), respectively. Release kinetics constants calculated from the experimental data, using a mathematical model, were also proposed and discussed. PMID:21638283

  15. The Sources of Radio News.

    ERIC Educational Resources Information Center

    Whitney, D. Charles

    To examine the production of programing material in a radio newsroom, a study was undertaken of the sources presented to the newsroom, of sources within the sources, of sources actively sought by the news staff, of degrees of processing of news items, and of the sources comprising the news output. Information in each of these areas was collected…

  16. TV News Flow Studies Revisited.

    ERIC Educational Resources Information Center

    Hjarvard, Stig

    1995-01-01

    Compares different theoretical approaches to the study of international news. Finds many comparative studies of the foreign news output of national broadcasters and few studies analyzing the actual flow of television news between actors at the wholesale level and the flow between wholesale and retail level. Suggests a better framework for the…

  17. Science News of the Year

    ERIC Educational Resources Information Center

    Science News, 1976

    1976-01-01

    Presented is a review of important science news stories reported in Science News during 1976. Most items include a volume and page number reference to the issue of Science News in which the article appeared. Items are grouped under general major headings such as: space, astronomy, medicine, chemistry, etc. (SL)

  18. Political News and Political Consciousness

    ERIC Educational Resources Information Center

    Schertges, Claudia

    2007-01-01

    This article deals with mass media in modern democratic societies, using the example of Israeli news reports in German television (TV) news. Central to this interest are processes of mediating politics: political socialisation and education; that is to say, empowering citizens via TV news to participate in democratic processes. The article…

  19. Breaking Bad News to Parents.

    ERIC Educational Resources Information Center

    Miller, Susan A.

    1996-01-01

    Discusses the difficulty of breaking bad news to parents, whether the news pertains to center policy or a child's behavior. Provides strategies for presenting news and for helping parents to overcome difficult situations, including gathering facts in advance, arranging an appropriate time, and having resource materials available for parents. (MOK)

  20. Automatic Association of News Items.

    ERIC Educational Resources Information Center

    Carrick, Christina; Watters, Carolyn

    1997-01-01

    Discussion of electronic news delivery systems and the automatic generation of electronic editions focuses on the association of related items of different media type, specifically photos and stories. The goal is to be able to determine to what degree any two news items refer to the same news event. (Author/LRW)

  1. The Trouble with Bad News.

    ERIC Educational Resources Information Center

    Haskins, Jack B.

    1981-01-01

    Subjective comments from veteran news reporters, media critics, and the public give the impression that bad or negative news is becoming a major problem in this country. This impression raises major questions concerning how much is really known about bad news, including whether the media present an accurate or distorted picture of reality in…

  2. Monolithic microextraction tips by emulsion photopolymerization.

    PubMed

    Liang, Shih-Shin; Chen, Shu-Hui

    2009-03-20

    Monoliths formed by photopolymerization are excellent means for fabricating functional elements in miniaturized microdevices such as microextraction tips which are becoming important for sample preparation. Various silica-based and polymer-based materials have been used to fabricate monoliths with through pores of several nm to 4 microm. However, the back pressure created by such methods is still considered to be high for microtips that use suction forces to deliver the liquid. In this study, we demonstrated that emulsion techniques such as oil-in-water can be used to form monoliths with large through pores (>20 microm), and with rigid structures on small (10 microL) and large (200 microL) pipette tips by photopolymerization. We further showed that, with minor modifications, various functionalized particles (5-20 microm) can be added to form stable emulsions and successfully encapsulated into the monoliths for qualitative and quantitative solid-phase microextractions for a diverse application. Due to high permeability and large surface area, quick equilibration can be achieved by pipetting to yield high recovery rates. Using tryptic digests of ovalbumin as the standard, we obtained a recovery yield of 90-109% (RSD: 10-16%) with a loading capacity of 3 mug for desalting tips immobilized with C18 beads. Using tryptic digests of beta-casein and alpha-casein as standards, we showed that phosphopeptides were substantially enriched by tips immobilized with immobilized metal affinity chromatography or TiO(2) materials. Using estrogenic compounds as standards, we obtained a recovery yield of 95-108% (RSD: 10-12%) and linear calibration curves ranging from 5 to 100 ng (R(2)>0.99) for Waters Oasis HLB tips immobilized with hydrophilic beads. PMID:19203757

  3. Analysis of emulsion stability in acrylic dispersions

    NASA Astrophysics Data System (ADS)

    Ahuja, Suresh

    2012-02-01

    Emulsions either micro or nano permit transport or solubilization of hydrophobic substances within a water-based phase. Different methods have been introduced at laboratory and industrial scales: mechanical stirring, high-pressure homogenization, or ultrasonics. In digital imaging, toners may be formed by aggregating a colorant with a latex polymer formed by batch or semi-continuous emulsion polymerization. Latex emulsions are prepared by making a monomer emulsion with monomer like Beta-carboxy ethyl acrylate (β-CEA) and stirring at high speed with an anionic surfactant like branched sodium dodecyl benzene sulfonates , aqueous solution until an emulsion is formed. Initiator for emulsion polymerization is 2-2'- azobis isobutyramide dehydrate with chain transfer agent are used to make the latex. If the latex emulsion is unstable, the resulting latexes produce a toner with larger particle size, broader particle size distribution with relatively higher latex sedimentation, and broader molecular weight distribution. Oswald ripening and coalescence cause droplet size to increase and can result in destabilization of emulsions. Shear thinning and elasticity of emulsions are applied to determine emulsion stability.

  4. Steroidal Compounds in Commercial Parenteral Lipid Emulsions

    PubMed Central

    Xu, Zhidong; Harvey, Kevin A.; Pavlina, Thomas; Dutot, Guy; Hise, Mary; Zaloga, Gary P.; Siddiqui, Rafat A.

    2012-01-01

    Parenteral nutrition lipid emulsions made from various plant oils contain steroidal compounds, called phytosterols. During parenteral administration of lipid emulsions, phytosterols can reach levels in the blood that are many fold higher than during enteral administration. The elevated phytosterol levels have been associated with the development of liver dysfunction and the rare development of liver failure. There is limited information available in the literature related to phytosterol concentrations in lipid emulsions. The objective of the current study was to validate an assay for steroidal compounds found in lipid emulsions and to compare their concentrations in the most commonly used parenteral nutrition lipid emulsions: Liposyn® II, Liposyn® III, Lipofundin® MCT, Lipofundin® N, Structolipid®, Intralipid®, Ivelip® and ClinOleic®. Our data demonstrates that concentrations of the various steroidal compounds varied greatly between the eight lipid emulsions, with the olive oil-based lipid emulsion containing the lowest levels of phytosterols and cholesterol, and the highest concentration of squalene. The clinical impression of greater incidences of liver dysfunction with soybean versus MCT/LCT and olive/soy lipid emulsions may be reflective of the levels of phytosterols in these emulsions. This information may help guide future studies and clinical care of patients with lipid emulsion-associated liver dysfunction. PMID:23016123

  5. Delivering bad news to patients.

    PubMed

    Monden, Kimberley R; Gentry, Lonnie; Cox, Thomas R

    2016-01-01

    When physicians lack proper training, breaking bad news can lead to negative consequences for patients, families, and physicians. A questionnaire was used to determine whether a didactic program on delivering bad news was needed at our institution. Results revealed that 91% of respondents perceived delivering bad news as a very important skill, but only 40% felt they had the training to effectively deliver such news. We provide a brief review of different approaches to delivering bad news and advocate for training physicians in a comprehensive, structured model. PMID:26722188

  6. E News: Report highlights

    SciTech Connect

    1995-01-01

    Three technologies are highlighted in this issue: a rooftop ice storage system for small commercial loads; chlorofluorocarbon-free electric chillers and their expected market; and the FlashBake oven, a commercial-sized oven that uses high intensity quartz lamps to cook food quickly. Regular columns on Member News and Work in Progress are included.

  7. News of the Year.

    ERIC Educational Resources Information Center

    St. Lifer, Evan; Olson, Renee; Milliot, Jim; Bing, Jonathan

    1998-01-01

    Reviews library news for 1997. Highlights public library budgets, examined by number of patrons served; Internet filters and censorship; librarians and the media; private and government funding sources; outsourcing; expectations for growth in the publishing industry, emphasizing the Asian economic crisis; and new ideas from the next generation of…

  8. Smart Start News, 1999.

    ERIC Educational Resources Information Center

    Harris, Monica, Ed.

    1999-01-01

    Smart Start is a comprehensive public-private initiative to help all North Carolina children enter school healthy and ready to succeed, and provides children from birth to age five access to high-quality and affordable child care, health care, and other critical services. This document comprises the first two issues of "Smart Start News," a…

  9. Parent News Offline, 1999.

    ERIC Educational Resources Information Center

    Robertson, Anne S., Ed.

    1999-01-01

    This document is comprised of the two issues published in volume 1 (1999) of "Parent News Offline," a newsletter of the National Parent Information Network (NPIN), designed to introduce those without Internet access to the activities and information available through NPIN. The spring 1999 issue contains the following articles: (1) "Child Care: How…

  10. NewsWire, 2002.

    ERIC Educational Resources Information Center

    Byrom, Elizabeth, Ed.; Bingham, Margaret, Ed.; Bowman, Gloria, Ed.; Shoemaker, Dan, Ed.

    2002-01-01

    This document presents the 3 2002 issues of the newsletter "NewsWire," (volume 5). Issue Number One focuses on collaborative Web projects. This issue begins with descriptions of four individual projects: "iEARN"; "Operation RubyThroat"; "Follow the Polar Huskies!"; and "Log in Your Animal Roadkill!" Features that follow include: "Bringing the…

  11. News & Issues, 1999.

    ERIC Educational Resources Information Center

    Oshinsky, Carole J., Ed.

    1999-01-01

    This publication is comprised of the two 1999 issues of "News and Issues," a newsletter devoted to identifying and promoting strategies to reduce the young child poverty rate, and to improve the life chances of children still living in poverty. The Winter/Spring issue includes the following articles: (1) "Innovative Strategies Help Families Cope…

  12. The News, Fall 2002.

    ERIC Educational Resources Information Center

    Giles, Ray, Ed.

    2002-01-01

    This fall 2002 newsletter from the Community College League of California contains several articles, news stories, and the brochure from the 2002 Annual Convention, "Celebrating the Way California LEARNS." Articles include: (1) "Nursing Shortage Poses Dilemma for Colleges: Access vs. Efficiency," a discussion of the debate over how to increase the…

  13. New Suncook News.

    ERIC Educational Resources Information Center

    Kanehl, Bob

    The newspaper program at the New Suncook School, Lovell, Maine, is a multi-level, language arts based unit designed to develop in students strong writing and interpersonal relationship skills, and to bring relevance to writing. The monthly newspaper features interviews, surveys, news, and some fiction stories written by students. The newspaper is…

  14. News of the Year.

    ERIC Educational Resources Information Center

    St. Lifer, Evan; And Others

    1994-01-01

    This section includes three articles that review library news from the past year. Highlights include public library budgets, examined by geographic regions; government programs; flood damage; library school closings; school library media programs; publishing industry concerns, including mergers, broadening markets, and on-demand printing; and…

  15. Parent News Offline, 2000.

    ERIC Educational Resources Information Center

    Robertson, Anne S., Ed.

    2000-01-01

    This document is comprised of the two issues in volume 2 of "Parent News Offline," a publication of the National Parent Information Network (NPIN) designed to introduce those without Internet access to the activities and information available through NPIN. The Spring 2000 issue contains the following articles: (1) "'Zero Tolerance': What Parents…

  16. Inexpensive News Sources.

    ERIC Educational Resources Information Center

    Briscoe, Ellen D.; Wall, Catherine

    1992-01-01

    Describes consumer or business-oriented online services that provide access to current news information and offers a less expensive alternative to standard online databases. Online clipping services are discussed, their costs are examined, and profiles of five services are compared: CompuServe, CompuServe as a gateway to IQuest, DELPHI, DIALCOM,…

  17. Improved stability of w/o/w multiple emulsions by addition of hydrophilic colloid components in the aqueous phases.

    PubMed

    Vaziri, A; Warburton, B

    1995-01-01

    To improve the stability of w/o/w multiple emulsions of arachis and olive oil the stabilizing effect of cherry gum, in combination with acacia and gelatin, was examined. The outstanding film-forming properties of this gum having already been noted; the effect of its addition to the aqueous phases was measured by the coalescence of emulsion globules. The enhanced stability, as compared to controls, was achieved at a minimum concentration which liquid crystal-bearing interfacial films seem to appear. Creation of more coherent interfaces, inhibiting transfer of phases, could be the basis of the improved stability of the emulsion. PMID:7730952

  18. Changing Emulsion Dynamics with Heterogeneous Surface Wettability

    NASA Astrophysics Data System (ADS)

    Tsai, Peichun Amy; Meng, Qiang; Zhang, Yali; Li, Jiang; Lammertink, Rob; Chen, Haosheng

    2015-11-01

    We elucidate the effect of heterogeneous surface wettability on the morphology and dynamics of microfluidic emulsions, generated by a co-flowing device. We first design a useful methodology of modifying a micro-capillary with desired heterogeneous wettability, such as alternating hydrophilic and hydrophobic regions. Subsequently, the effects of flow rates and heterogeneous wettability on the emulsion morphology and motion in the micro-capillary are investigated. Our experimental data reveal a universal critical time scale of advective emulsions, above which the microfluidic emulsions remain intact, whereas below this time-scale emulsions become adhesive or inverse. A simple model based on a force balance can be used to explain this critical transition. These results show a control of emulsion dynamics by tuning the droplet size and the Capillary number, the ratio of viscous to surface effects, with heterogeneous surface wettability.

  19. Intravenous Lipid Emulsions in Parenteral Nutrition.

    PubMed

    Fell, Gillian L; Nandivada, Prathima; Gura, Kathleen M; Puder, Mark

    2015-09-01

    Fat is an important macronutrient in the human diet. For patients with intestinal failure who are unable to absorb nutrients via the enteral route, intravenous lipid emulsions play a critical role in providing an energy-dense source of calories and supplying the essential fatty acids that cannot be endogenously synthesized. Over the last 50 y, lipid emulsions have been an important component of parenteral nutrition (PN), and over the last 10-15 y many new lipid emulsions have been manufactured with the goal of improving safety and efficacy profiles and achieving physiologically optimal formulations. The purpose of this review is to provide a background on the components of lipid emulsions, their role in PN, and to discuss the lipid emulsions available for intravenous use. Finally, the role of parenteral fat emulsions in the pathogenesis and management of PN-associated liver disease in PN-dependent pediatric patients is reviewed. PMID:26374182

  20. Experiment S009: Nuclear Emulsion

    NASA Technical Reports Server (NTRS)

    Odell, F. W.; Shapiro, M. M.; Silberberg, R.; Stiller, B.; Tsao, C. H.; Durgaprasad, N.; Fichtel, C. E.; Guss, D. E.; Reames, D. V.

    1971-01-01

    The first exposure on a spacecraft of a nuclear emulsion apparatus designed to collect 1000 high quality tracks of heavy nuclei under a negligible thickness of matter (0.07 g/sq cm) is described. The cosmic ray detector consisted of a stack of nuclear emulsions that were designed to register at least 400 heavy nuclei tracks for each 10 hours of useful exposure. The spacecraft had to be oriented in a heads-up attitude during the 10-hour period to eliminate atmospheric albedo particles. The results are as follows: (1) a definite odd-even effect, with low abundances for elements of atomic number 7, 9, and 11; (2) a ratio O/C approximately 0.9; (3) Ne/C, Mg/C, and Si/C ratios between 0.2 and 0.3; (4) an abundance gap in the region 15 less than or equal to Z less than or equal to 19; and (5) a ratio (20 less than or equal to Z less than or equal to 28)/C 0.2, with a large concentration at Z = 26. These results are indicative that successful exposures of nuclear emulsions were obtained on the Gemini 11 mission.

  1. Pickering emulsions for skin decontamination.

    PubMed

    Salerno, Alicia; Bolzinger, Marie-Alexandrine; Rolland, Pauline; Chevalier, Yves; Josse, Denis; Briançon, Stéphanie

    2016-08-01

    This study aimed at developing innovative systems for skin decontamination. Pickering emulsions, i.e. solid-stabilized emulsions, containing silica (S-PE) or Fuller's earth (FE-PE) were formulated. Their efficiency for skin decontamination was evaluated, in vitro, 45min after an exposure to VX, one of the most highly toxic chemical warfare agents. Pickering emulsions were compared to FE (FE-W) and silica (S-W) aqueous suspensions. PE containing an oil with a similar hydrophobicity to VX should promote its extraction. All the formulations reduced significantly the amount of VX quantified on and into the skin compared to the control. Wiping the skin surface with a pad already allowed removing more than half of VX. FE-W was the less efficient (85% of VX removed). The other formulations (FE-PE, S-PE and S-W) resulted in more than 90% of the quantity of VX removed. The charge of particles was the most influential factor. The low pH of formulations containing silica favored electrostatic interactions of VX with particles explaining the better elimination from the skin surface. Formulations containing FE had basic pH, and weak interactions with VX did not improve the skin decontamination. However, these low interactions between VX and FE promote the transfer of VX into the oil droplets in the FE-PE. PMID:27021875

  2. Impact of acoustic cavitation on food emulsions.

    PubMed

    Krasulya, Olga; Bogush, Vladimir; Trishina, Victoria; Potoroko, Irina; Khmelev, Sergey; Sivashanmugam, Palani; Anandan, Sambandam

    2016-05-01

    The work explores the experimental and theoretical aspects of emulsification capability of ultrasound to deliver stable emulsions of sunflower oil in water and meat sausages. In order to determine optimal parameters for direct ultrasonic emulsification of food emulsions, a model was developed based on the stability of emulsion droplets in acoustic cavitation field. The study is further extended to investigate the ultrasound induced changes to the inherent properties of raw materials under the experimental conditions of sono-emulsification. PMID:26603612

  3. Spreading of Emulsions on Glass Substrates

    NASA Astrophysics Data System (ADS)

    Mohammad Karim, Alireza; Kavehpour, Pirouz

    2012-11-01

    The wettability of emulsions is an important factor with explicit influence in an extensive variety of industrial applications ranging from the petroleum to food industries. Surprisingly, there is no comprehensive study of emulsion spreading to date; this is due to the complexity of the structure of the emulsions and non-homogeneity of the dispersed phase bubbles in size as well as distribution through the emulsion. The spreading of water/silicone oil emulsions on glass substrates was investigated. The emulsions were prepared with varying volume fractions of water dispersed in silicone oil, with addition of small amounts of surfactant to stabilize the emulsion structure. The time dependent variation of dynamic contact angle, base diameter, and the spreading rate of the droplets of an emulsion are different from a pure substance. The effect of water/silicone oil weight percentage as well as the droplet size and dispersed phase bubble size were also investigated. The weight percentage of water/silicone oil emulsion and droplet size did not have significant influence on the spreading dynamics; however the dispersed phase drop size affected the spreading dynamics substantially.

  4. Deactivation efficiency of stabilized bactericidal emulsions.

    PubMed

    Vyhnalkova, Renata; Eisenberg, Adi; van de Ven, Theo G M

    2011-09-20

    Biocide emulsions stabilized with various stabilizing agents were prepared and characterized, and their efficiency in bacteria deactivation was evaluated. A number of stabilizing agents were tested for their stabilizing effect on emulsions of thiocyanomethylthiobenzothiazole (TCMTB) biocide. Two agents, the most successful in stabilizing the biocide, were chosen for further studies: high molecular weight polyethyleneimine (PEI) and an amphiphilic block copolymer of poly(caprolactone)-b-poly(acrylic acid) (PCL(33)-b-PAA(33)). The emulsion droplet sizes varied between 325 and 500 nm. Deactivation of bacteria was studied by exposing E. coli ATCC 11229 bacteria dispersions to emulsions stabilized by positively charged PEI or negatively charged PCL-b-PAA micelles and by measuring their absorbance; E. coli do not grow with time in the presence of biocide emulsions. PEI molecules alone act as biocide and deactivate the bacteria. PCL-b-PAA micelles as stabilizing agent do not affect the growth of the E. coli ; bacteria are deactivated by TCMTB released from the emulsion droplets. The kinetics of emulsion dissolution studies revealed for both stabilizing agents a decrease in droplet size with time while the emulsions were subjected to dialysis. The biocide was released from the emulsions within ∼250 min; the droplet shells consist mostly of PEI or PCL-b-PAA insoluble complexes with the biocide, which do not dissolve during dialysis. SEM images confirm the presence of residual crumbled shells with holes after 24 h of dialysis. PMID:21823610

  5. An NMR study of diffusion in surfactant-free emulsions and molten triglyceride mixtures

    NASA Astrophysics Data System (ADS)

    MacLean, Duncan A.

    Nuclear magnetic resonance (NMR) diffusion measurements have become extensively used analytical techniques, with applications in many fields. In this thesis these measurements have been employed to elucidate a mechanism of emulsion stabilization and to examine mobility of a mixture of substances at the molecular level. Emulsions (liquid-in-liquid mixtures) have widespread applications (pharmaceutical, food science, petrochemical, agrochemical), therefore it is important to understand what governs emulsion stability. It has been previously demonstrated that a degassing process stabilizes oil-in-water emulsions, however the mechanism behind this is debated. In this thesis the Cotts 13-interval NMR sequence was used to examine the effects of degassing, establishing which of two suggested mechanisms is responsible for producing stable emulsions. Triglyceride mixtures are commonly separated before characterisation, however, NMR measurements of diffusion in molten trilaurin-trimyristin mixes have been made. This sheds light on the behaviour of these mixtures and assisted in developing new methods for their characterisation. These applications illustrate the versatility of NMR diffusion measurements.

  6. Heat Transfer in Boiling Dilute Emulsion with Strong Buoyancy

    NASA Astrophysics Data System (ADS)

    Freeburg, Eric Thomas

    Little attention has been given to the boiling of emulsions compared to that of boiling in pure liquids. The advantages of using emulsions as a heat transfer agent were first discovered in the 1970s and several interesting features have since been studied by few researchers. Early research focuses primarily on pool and flow boiling and looks to determine a mechanism by which the boiling process occurs. This thesis looks at the boiling of dilute emulsions in fluids with strong buoyant forces. The boiling of dilute emulsions presents many favorable characteristics that make it an ideal agent for heat transfer. High heat flux electronics, such as those seen in avionics equipment, produce high heat fluxes of 100 W/cm2 or more, but must be maintained at low temperatures. So far, research on single phase convection and flow boiling in small diameter channels have yet to provide an adequate solution. Emulsions allow the engineer to tailor the solution to the specific problem. The fluid can be customized to retain the high thermal conductivity and specific heat capacity of the continuous phase while enhancing the heat transfer coefficient through boiling of the dispersed phase component. Heat transfer experiments were carried out with FC-72 in water emulsions. FC-72 has a saturation temperature of 56 °C, far below that of water. The parameters were varied as follows: 0% ≤ epsilon ≤ 1% and 1.82 x 1012 ≤ RaH ≤ 4.42 x 1012. Surface temperatures along the heated surface reached temperature that were 20 °C in excess of the dispersed phase saturation temperature. An increase of ˜20% was seen in the average Nusselt numbers at the highest Rayleigh numbers. Holography was used to obtain images of individual and multiple FC-72 droplets in the boundary layer next to the heated surface. The droplet diameters ranged from 0.5 mm to 1.3 mm. The Magnus effect was observed when larger individual droplets were injected into the boundary layer, causing the droplets to be pushed

  7. Emulsion-templated fully reversible protein-in-oil gels.

    PubMed

    Romoscanu, Alexandre I; Mezzenga, Raffaele

    2006-08-29

    We have developed a new method allowing us to transform low-viscous apolar fluids into elastic solids with a shear elastic modulus of the order of 10(3)-10(5) Pa. The elasticity of the elastic solid is provided by a percolating 3D network of proteins, which are originally adsorbed at the interface of an oil-in-water emulsion template. By cross-linking the protein films at the interface and upon removal of water, the template is driven into a structure resembling a dry foam where the protein interfaces constitute the walls of the foam and the air is replaced by oil confined within polyhedral, closely packed droplets. Depending on the density of the protein network, the final material consists of chemically unmodified oil in a proportion of 95 to 99.9%. The physical properties of the elastic solid obtained can be tuned by changing either the average diameter size of the emulsion template or the cross-linking process of the protein film. However, the original low-viscosity emulsion can be restored by simply rehydrating the solidified fluid. Therefore, the present procedure offers an appealing strategy to build up solid properties for hydrophobic liquids while preserving the low viscosity and ease of manufacturing. PMID:16922568

  8. Contact: Releasing the news

    NASA Astrophysics Data System (ADS)

    Pinotti, Roberto

    The problem of mass behavior after man's future contacts with other intelligences in the universe is not only a challenge for social scientists and political leaders all over the world, but also a cultural time bomb as well. In fact, since the impact of CETI (Contact with Extraterrestrial Intelligence) on human civilization, with its different cultures, might cause a serious socio-anthropological shock, a common and predetermined worldwide strategy is necessary in releasing the news after the contact, in order to keep possible manifestations of fear, panic and hysteria under control. An analysis of past studies in this field and of parallel historical situations as analogs suggests a definite "authority crisis" in the public as a direct consequence of an unexpected release of the news, involving a devastating "chain reaction" process (from both the psychological and sociological viewpoints) of anomie and maybe the collapse of today's society. The only way to prevent all this is to prepare the world's public opinion concerning contact before releasing the news, and to develop a long-term strategy through the combined efforts of scientists, political leaders, intelligence agencies and the mass media, in order to create the cultural conditions in which a confrontation with ETI won't affect mankind in a traumatic way. Definite roles and tasks in this multi-level model are suggested.

  9. Metallic nanoshells on porphyrin-stabilized emulsions

    DOEpatents

    Wang, Haorong; Song, Yujiang; Shelnutt, John A; Medforth, Craig J

    2013-10-29

    Metal nanostructures formed by photocatalytic interfacial synthesis using a porphyrin-stabilized emulsion template and the method for making the nanostructures. Catalyst-seeded emulsion droplets are employed as templates for hollow-nanoshell growth. The hollow metal nanospheres may be formed with or without inclusions of other materials.

  10. Dynamic modeling of emulsion polymerization reactors

    SciTech Connect

    Penlidis, A.; Hamielec, A.E.; MacGregor, J.F.

    1985-06-01

    This paper is a survey of recent published works on the dynamic and steady state modeling of emulsion homo- and copolymerization in batch, semicontinuous , and continuous latex reactors. Contributions to our understanding of diffusion-controlled termination and propagation reactions, molecular weight, long chain branching and crosslinking development, polymer particle nucleation, and of the dynamics of continuous emulsion polymerization are critically reviewed.

  11. Flows of Wet Foamsand Concentrated Emulsions

    NASA Technical Reports Server (NTRS)

    Nemer, Martin B.

    2005-01-01

    The aim of this project was is to advance a microstructural understanding of foam and emulsion flows. The dynamics of individual surfactant-covered drops and well as the collective behavior of dilute and concentrated was explored using numerical simulations. The long-range goal of this work is the formulation of reliable microphysically-based statistical models of emulsion flows.

  12. Suppression of Ostwald ripening in active emulsions.

    PubMed

    Zwicker, David; Hyman, Anthony A; Jülicher, Frank

    2015-07-01

    Emulsions consisting of droplets immersed in a fluid are typically unstable since they coarsen over time. One important coarsening process is Ostwald ripening, which is driven by the surface tension of the droplets. Stability of emulsions is relevant not only in complex fluids but also in biological cells, which contain liquidlike compartments, e.g., germ granules, Cajal bodies, and centrosomes. Such cellular systems are driven away from equilibrium, e.g., by chemical reactions, and thus can be called active emulsions. In this paper, we study such active emulsions by developing a coarse-grained description of the droplet dynamics, which we analyze for two different chemical reaction schemes. We first consider the simple case of first-order reactions, which leads to stable, monodisperse emulsions in which Ostwald ripening is suppressed within a range of chemical reaction rates. We then consider autocatalytic droplets, which catalyze the production of their own droplet material. Spontaneous nucleation of autocatalytic droplets is strongly suppressed and their emulsions are typically unstable. We show that autocatalytic droplets can be nucleated reliably and their emulsions stabilized by the help of chemically active cores, which catalyze the production of droplet material. In summary, different reaction schemes and catalytic cores can be used to stabilize emulsions and to control their properties. PMID:26274171

  13. Suppression of Ostwald ripening in active emulsions

    NASA Astrophysics Data System (ADS)

    Zwicker, David; Hyman, Anthony A.; Jülicher, Frank

    2015-07-01

    Emulsions consisting of droplets immersed in a fluid are typically unstable since they coarsen over time. One important coarsening process is Ostwald ripening, which is driven by the surface tension of the droplets. Stability of emulsions is relevant not only in complex fluids but also in biological cells, which contain liquidlike compartments, e.g., germ granules, Cajal bodies, and centrosomes. Such cellular systems are driven away from equilibrium, e.g., by chemical reactions, and thus can be called active emulsions. In this paper, we study such active emulsions by developing a coarse-grained description of the droplet dynamics, which we analyze for two different chemical reaction schemes. We first consider the simple case of first-order reactions, which leads to stable, monodisperse emulsions in which Ostwald ripening is suppressed within a range of chemical reaction rates. We then consider autocatalytic droplets, which catalyze the production of their own droplet material. Spontaneous nucleation of autocatalytic droplets is strongly suppressed and their emulsions are typically unstable. We show that autocatalytic droplets can be nucleated reliably and their emulsions stabilized by the help of chemically active cores, which catalyze the production of droplet material. In summary, different reaction schemes and catalytic cores can be used to stabilize emulsions and to control their properties.

  14. Treatment of oil-in-water emulsions

    SciTech Connect

    Presley, C.T.; Harrison, R.J.

    1980-01-08

    Petroleum is separated from an oil-in-water emulsion containing water-soluble polymer such as polyacrylamide prior to refining by adding amphoteric metal cations (Zn, Al, Sn, and Co) to the emulsion to form a flocculate and then treating the resulting flocculate with a strong base to recover the oil and metal. 11 claims.

  15. Treatment of oil-in-water emulsions

    SciTech Connect

    Harrison, R.J.; Presley, C.T.

    1980-01-08

    Petroleum is separated from an ''oil-in-water'' emulsion containing water-soluble polymer prior to refining by adding amphoteric metal cations to the emulsion to form a flocculate and then treating the resulting flocculate with a strong base to recover the oil and metal.

  16. Emulsion based cast booster - a priming system

    SciTech Connect

    Gupta, R.N.; Mishra, A.K.

    2005-07-01

    This paper explores the potential of emulsion based cast booster to be used as primer to initiate bulk delivered emulsion explosives used in mines. An attempt has been made for comparative study between conventional cast booster and emulsion based cast booster in terms of the initiation process developed and their capability to develop and maintain the stable detonation process in the column explosives. The study has been conducted using a continuous velocity of detonation (VOD) measuring instrument. During this study three blasts have been monitored. In each blast two holes have been selected for study, the first hole being initiated with conventional cast booster while the other one with emulsion based cast booster. The findings of the study advocates that emulsion based cast booster is capable of efficient priming of bulk delivered column explosive with stable detonation process in the column. Further, the booster had advantages over the conventional PETN/TNT based cast booster. 5 refs., 2 figs., 1 tab., 1 photo.

  17. Cocoa particles for food emulsion stabilisation.

    PubMed

    Gould, Joanne; Vieira, Josélio; Wolf, Bettina

    2013-09-01

    Emulsifying properties of cocoa particles have been investigated in systems containing purified sunflower oil (PSO) and water at varying pH, concentration and source of cocoa particles including cocoa powders (CP), cocoa fibre (CF) and cocoa mass (CM). The effect of cocoa particle source, pH and cocoa particle concentration on emulsion stability was evaluated by following changes in characteristic droplet diameter. Size distributions acquired on the emulsions and aqueous cocoa particle suspensions overlapped. Based on cryo-SEM imaging of the emulsions, isolation of cocoa particle fines and a process of washing the cocoa particles to remove any water soluble molecules, it was concluded that the cocoa particle fines not captured by the small angle laser diffraction method employed for sizing, act as Pickering particles. This research has demonstrated a universal nature of a natural food particle to stabilise oil-in-water emulsions not requiring particle modification or adjusting of the solution properties of the emulsion phases. PMID:23851644

  18. Non-aqueous Isorefractive Pickering Emulsions.

    PubMed

    Thompson, Kate L; Lane, Jacob A; Derry, Matthew J; Armes, Steven P

    2015-04-21

    Non-aqueous Pickering emulsions of 16-240 μm diameter have been prepared using diblock copolymer worms with ethylene glycol as the droplet phase and an n-alkane as the continuous phase. Initial studies using n-dodecane resulted in stable emulsions that were significantly less turbid than conventional water-in-oil emulsions. This is attributed to the rather similar refractive indices of the latter two phases. By utilizing n-tetradecane as an alternative oil that almost precisely matches the refractive index of ethylene glycol, almost isorefractive ethylene glycol-in-n-tetradecane Pickering emulsions can be prepared. The droplet diameter and transparency of such emulsions can be systematically varied by adjusting the worm copolymer concentration. PMID:25844544

  19. Non-aqueous Isorefractive Pickering Emulsions

    PubMed Central

    2015-01-01

    Non-aqueous Pickering emulsions of 16–240 μm diameter have been prepared using diblock copolymer worms with ethylene glycol as the droplet phase and an n-alkane as the continuous phase. Initial studies using n-dodecane resulted in stable emulsions that were significantly less turbid than conventional water-in-oil emulsions. This is attributed to the rather similar refractive indices of the latter two phases. By utilizing n-tetradecane as an alternative oil that almost precisely matches the refractive index of ethylene glycol, almost isorefractive ethylene glycol-in-n-tetradecane Pickering emulsions can be prepared. The droplet diameter and transparency of such emulsions can be systematically varied by adjusting the worm copolymer concentration. PMID:25844544

  20. International News Bowwowing: A Trend Analysis.

    ERIC Educational Resources Information Center

    Riffe, Daniel

    1984-01-01

    Concludes that the increased "borrowing" of news from foreign news agencies may not be due to the declining number of United States foreign correspondents but to Third World restrictions on access to news. (FL)

  1. A Survey of Electronic News Gathering and Television News Coverage.

    ERIC Educational Resources Information Center

    Stone, Vernon A.; DiCioccio, John P.

    A 1977 national survey of 216 television stations that use electronic news gathering (ENG) and of 224 stations that still use only film for camera reporting showed little difference in the types of news the two kinds of operations covered, although stations using ENG shot more stories than did those still using only film. The persons making…

  2. Arresting relaxation in Pickering Emulsions

    NASA Astrophysics Data System (ADS)

    Atherton, Tim; Burke, Chris

    2015-03-01

    Pickering emulsions consist of droplets of one fluid dispersed in a host fluid and stabilized by colloidal particles absorbed at the fluid-fluid interface. Everyday materials such as crude oil and food products like salad dressing are examples of these materials. Particles can stabilize non spherical droplet shapes in these emulsions through the following sequence: first, an isolated droplet is deformed, e.g. by an electric field, increasing the surface area above the equilibrium value; additional particles are then adsorbed to the interface reducing the surface tension. The droplet is then allowed to relax toward a sphere. If more particles were adsorbed than can be accommodated by the surface area of the spherical ground state, relaxation of the droplet is arrested at some non-spherical shape. Because the energetic cost of removing adsorbed colloids exceeds the interfacial driving force, these configurations can remain stable over long timescales. In this presentation, we present a computational study of the ordering present in anisotropic droplets produced through the mechanism of arrested relaxation and discuss the interplay between the geometry of the droplet, the dynamical process that produced it, and the structure of the defects observed.

  3. Physical Properties of Polyester Fabrics Treated with Nano, Micro and Macro Emulsion Silicones

    NASA Astrophysics Data System (ADS)

    Parvinzadeh, M.; Hajiraissi, R.

    2007-08-01

    The processing of textile to achieve a particular handle is one of the most important aspects of finishing technology. Fabrics softeners are liquid composition added to washing machines during the rinse cycle to make clothes feel better to the touch. The first fabric softeners were developed by the textile industry during the early twentieth century. In this research polyester fabrics were treated with nano, micro and macro emulsion silicone softeners. Some of the physical properties of the treated fabric samples are discussed. The drapeability of treated samples was improved after treatment with nano silicone softeners. The colorimetric measurement of softener-treated fabrics is evaluated with a reflectance spectrophotometer. Moisture regain of treated samples is increased due to coating of silicone softeners. There is some increase in the weight of softener-treated samples. Samples treated with nano emulsion silicones gave better results compared to micro- and macro-emulsion treated ones.

  4. Science News of the Year.

    ERIC Educational Resources Information Center

    Science News, 1984

    1984-01-01

    Reviews important science news stories reported during 1984 in "Science News" magazine. These stories are in the categories of: anthropology and paleontology; behavior; biology; chemistry; computers; mathematics; earth science; the environment; medicine; physics; science and society; space sciences and astronomy; and technology. (JN)

  5. What Turns Events into News?

    ERIC Educational Resources Information Center

    Tukachinsky, Riva

    2013-01-01

    "The New York Times" is known for its slogan ''All the News That's Fit to Print.'' But how do gatekeepers decide which events meet this criterion? Although some individuals might believe that the news constitutes an undistorted reflection of the social reality, students in communication courses have the…

  6. Science News of the Year.

    ERIC Educational Resources Information Center

    Science News, 1987

    1987-01-01

    Provides a review of science news stories reported in "Science News" during 1987. References each item to the volume and page number in which the subject was addressed. Contains references on astronomy, behavior, biology, biomedicine, chemistry, earth sciences, environment, mathematics and computers, paleontology and anthropology, physics, science…

  7. Latest Developments in Nuclear Emulsion Technology

    NASA Astrophysics Data System (ADS)

    Morishima, Kunihiro

    Nuclear emulsion is high sensitive photographic film used for detection of three-dimensional trajectory of charged particles. These trajectories are recorded as tracks consist of a lot of silver grains. The size of silver grain is about 1 μm, so that nuclear emulsion has submicron three-dimensional spatial resolution, which gives us a few mrad three-dimensional angular resolution. The important technical progress was speed-up of the read-out technique of nuclear emulsions built with optical microscope system. We succeeded in developing a high-speed three-dimensional read-out system named Super Ultra Track Selector (S-UTS) with the operating read-out speed of approximately 50 cm2/h. Nowadays we are developing the nuclear emulsion gel independently in Nagoya University by introducing emulsion gel production machine. Moreover, we are developing nuclear emulsion production technologies (gel production, poring and mass production). In this paper, development of nuclear emulsion technologies for the OPERA experiment, applications by the technologies and current development are described.

  8. High acyl gellan as an emulsion stabilizer.

    PubMed

    Vilela, Joice Aline Pires; da Cunha, Rosiane Lopes

    2016-03-30

    High acyl gellan (0.01-0.2% w/w) was used as stabilizer in oil in water emulsions containing 30% (w/w) of sunflower oil and prepared under different process conditions. Stable emulsions to phase separation could be obtained using high acyl gellan (HA) content above 0.05% (w/w), while low acyl gellan (LA) prepared at the same conditions could not stabilize emulsions. Emulsions properties depended on the process used to mix the oil and gellan dispersion since high pressure homogenization favored stabilization while very high energy density applied by ultrasound led to systems destabilization. Emulsions prepared using high pressure homogenization showed zeta potential values ranging from -50 up to -59 mV, suggesting that electrostatic repulsion could be contributing to the systems stability. Rheological properties of continuous phase were also responsible for emulsions stabilization, since HA gellan dispersions showed high viscosity and gel-like behavior. The high viscosity of the continuous phase could be associated to the presence of high acyl gellan microgels/aggregates. Disentanglement of these aggregates performed by ultrasound strongly decreased the viscosity and consequently affected the emulsions behavior, reducing the stability to phase separation. PMID:26794954

  9. Kinetic Release of Alkalinity from Particle-Containing Oil-in-Water Emulsions

    NASA Astrophysics Data System (ADS)

    Muller, K.; Chapra, S. C.; Ramsburg, A.

    2014-12-01

    Oil-in-water emulsions are typically employed during remediation to promote biotic reduction of contaminants. Emulsions, however, hold promise for encapsulated delivery of many types of active ingredients required for successful site remediation or long-term site stewardship. Our research is currently focused on using alkalinity-containing particles held within oil-in-water emulsions to sustain control of subsurface pH. Here we describe results from laboratory experiments and mathematical modeling conducted to quantify the kinetics associated with the emulsion delivery and alkalinity release process. Kinetically stable oil-in-water emulsions containing (~60 nmCaCO3 or ~100 nm MgO particles) were previously developed using soybean oil and Gum Arabic as a stabilizing agent. Batch and column experiments were employed to assess the accessibility and release of the alkalinity from the emulsion. Successive additions of HCl were used in batch systems to produce several pH responses (pH rebounds) that were subsequently modeled to elucidate release mechanisms and rates for varying emulsion compositions and particle types. Initial results suggest that a linear-driving-force model is generally able to capture the release behavior in the batch system when the temporally-constant, lumped mass-transfer coefficient is scaled by the fraction of particle mass remaining within the droplets. This result suggests that the rate limiting step in the release process may be the interphase transfer of reactive species at the oil-water interface. 1-d column experiments were also completed in order to quantify the extent and rate of alkalinity release from emulsion droplets retained in a sandy medium. Alkalinity release from the retained droplets treated a pH 4 influent water for 25-60 pore volumes (the duration depended on particle type and mass loading), and the cessation in treatment corresponded to exhaustion of the particle mass held within the oil. Column experiments were simulated

  10. Electrocoagulation of cutting oil emulsions using aluminium plate electrodes.

    PubMed

    Bensadok, K; Benammar, S; Lapicque, F; Nezzal, G

    2008-03-21

    The treatment of very concentrated oil-water emulsions by electrocoagulation (EC) was experimentally investigated as a pre-treatment step prior to a membrane process. The oil-water emulsion was prepared from a cutting mineral oil B22 currently used for drilling and machining operations. The electrocoagulation progress was followed by the measurement of COD, turbidity and pH in a batch process with recirculation of the liquid. This study is mainly focused on the effects of operating parameters such as initial pH, current density, oil concentration and recirculation rate, on the de-emulsification efficiency. Kinetic curves showed that the EC process exhibits two phases: a "reactive phase" during which the COD and the turbidity removals increase with electrolysis, and a stationary phase for which further aluminium dissolution is useless in the pollution abatement. The results showed that the treatment efficiency increases with increasing current density, but decreases with oil concentration. It appears that treatment of the considered cutting oil is completed through dissolution of around 10mgAl/g oil, with a slight positive effect of the liquid flow rate. Best results are also obtained with initial pH near 7. PMID:17706345

  11. Breaking of double emulsions based on electrohydrodynamics principles.

    PubMed

    Spasic, Aleksandar M; Jovanovic, Jovan M; Manojlovic, Vaso; Jovanovic, Mica

    2016-10-01

    This research focuses on the modeling of the liquid-liquid dispersed system, including particular insight on the electrocoalescence (EC) process that occurs during the breaking of double emulsions. The representative system, used in this work, was taken from the pilot plant for solvent extraction of uranium from wet phosphoric acid. The chosen framework required for elucidation of the EC process is based on the electrohydrodynamic (EHD) principles. During the model development it was necessary to consider several theoretical concepts for easier understanding and description of the related events. The first is the concept of entities, and corresponding classification of finely dispersed systems. The second concept is an introduction of almost forgotten basic electrodynamics element the memdiode or memristor as a current controlled device, and corresponding memristive systems. Hence, the conclusions that may be withdrawn from the presented results and findings could enable easier designing of the solutions for a breaking of double emulsions problems, that is, the entrainment problems that may arise in some pilot or industrial plants. Finally, the perspectives and the remaining challenges, considering the here discussed concepts and model based on the EHD principles, are mentioned. PMID:27388130

  12. Gelation of Soy Milk with Hagfish Exudate Creates a Flocculated and Fibrous Emulsion- and Particle Gel

    PubMed Central

    Böni, Lukas; Rühs, Patrick A.; Windhab, Erich J.; Fischer, Peter; Kuster, Simon

    2016-01-01

    Hagfish slime is an ultra dilute, elastic and cohesive hydrogel that deploys within milliseconds in cold seawater from a glandularly secreted exudate. The slime is made of long keratin-like fibers and mucin-like glycoproteins that span a network which entraps water and acts as a defense mechanism against predators. Unlike other hydrogels, the slime only confines water physically and is very susceptible to mechanical stress, which makes it unsuitable for many processing operations and potential applications. Despite its huge potential, little work has been done to improve and functionalize the properties of this hydrogel. To address this shortcoming, hagfish exudate was mixed with a soy protein isolate suspension (4% w/v) and with a soy emulsion (commercial soy milk) to form a more stable structure and combine the functionalities of a suspension and emulsion with those of the hydrogel. Hagfish exudate interacted strongly with the soy systems, showing a markedly increased viscoelasticity and water retention. Hagfish mucin was found to induce a depletion and bridging mechanism, which caused the emulsion and suspension to flocculate, making “soy slime”, a cohesive and cold-set emulsion- and particle gel. The flocculation network increases viscoelasticity and substantially contributes to liquid retention by entrapping liquid in the additional confinements between aggregated particles and protein fibers. Because the mucin-induced flocculation resembles the salt- or acid-induced flocculation in tofu curd production, the soy slime was cooked for comparison. The cooked soy slime was similar to conventional cooked tofu, but possessed a long-range cohesiveness from the fibers. The fibrous, cold-set, and curd-like structure of the soy slime represents a novel way for a cold coagulation and fiber incorporation into a suspension or emulsion. This mechanism could be used to efficiently gel functionalized emulsions or produce novel tofu-like structured food products. PMID

  13. Gelation of Soy Milk with Hagfish Exudate Creates a Flocculated and Fibrous Emulsion- and Particle Gel.

    PubMed

    Böni, Lukas; Rühs, Patrick A; Windhab, Erich J; Fischer, Peter; Kuster, Simon

    2016-01-01

    Hagfish slime is an ultra dilute, elastic and cohesive hydrogel that deploys within milliseconds in cold seawater from a glandularly secreted exudate. The slime is made of long keratin-like fibers and mucin-like glycoproteins that span a network which entraps water and acts as a defense mechanism against predators. Unlike other hydrogels, the slime only confines water physically and is very susceptible to mechanical stress, which makes it unsuitable for many processing operations and potential applications. Despite its huge potential, little work has been done to improve and functionalize the properties of this hydrogel. To address this shortcoming, hagfish exudate was mixed with a soy protein isolate suspension (4% w/v) and with a soy emulsion (commercial soy milk) to form a more stable structure and combine the functionalities of a suspension and emulsion with those of the hydrogel. Hagfish exudate interacted strongly with the soy systems, showing a markedly increased viscoelasticity and water retention. Hagfish mucin was found to induce a depletion and bridging mechanism, which caused the emulsion and suspension to flocculate, making "soy slime", a cohesive and cold-set emulsion- and particle gel. The flocculation network increases viscoelasticity and substantially contributes to liquid retention by entrapping liquid in the additional confinements between aggregated particles and protein fibers. Because the mucin-induced flocculation resembles the salt- or acid-induced flocculation in tofu curd production, the soy slime was cooked for comparison. The cooked soy slime was similar to conventional cooked tofu, but possessed a long-range cohesiveness from the fibers. The fibrous, cold-set, and curd-like structure of the soy slime represents a novel way for a cold coagulation and fiber incorporation into a suspension or emulsion. This mechanism could be used to efficiently gel functionalized emulsions or produce novel tofu-like structured food products. PMID:26808048

  14. Influence of emulsification process on the properties of Pickering emulsions stabilized by layered double hydroxide particles.

    PubMed

    Zhang, Nana; Zhang, Li; Sun, Dejun

    2015-04-28

    This paper reports the influence of emulsification process on the packing of layered double hydroxide (LDH) particles at the aqueous/oil phase interface and the properties of the resulting Pickering emulsions. Emulsions prepared by ultrasonication display superior long-term stability and gel-like characteristics at the dispersed phase volume fraction well below the random close packing limit, whereas emulsions with same compositions prepared by vortex mixing show some extent of sedimentation and liquid-like behaviors. Rheological measurements demonstrate that the zero-shear elastic modulus and yield stress of gel-like emulsions exhibit power-law dependences on particle concentration and independence on aqueous/oil phase ratio. The microstructural origin of this behavior is investigated by optical microscopy, revealing the droplets become strongly adhesive and a heterogeneous percolating network is formed among neighboring droplets. Fluorescent confocal microscopy measurements further confirm that the droplet adhesion is due to particle layers bridging opposite interfaces. In contrast, homogeneous, isolated, and densely packed droplets are present in emulsions prepared by vortex mixing, which results in these systems being dominantly viscous like the suspending fluid. This study shows that the emulsification process can be used as a trigger to modify long-term stability and rheology of solid-stabilized multiphase mixtures, which greatly expands their potential technological applications. PMID:25853297

  15. Electric field-driven, magnetically-stabilized ferro-emulsion phase contactor

    DOEpatents

    Scott, Timothy C.

    1990-01-01

    Methods and systems for interfacial surface area contact between a dispersed phase liquid and a continuous phase liquid in counter-current flow for purposes such as solvent extraction. Initial droplets of a dispersed phase liquid material containing ferromagnetic particles functioning as a "packing" are introduced to a counter-current flow of the continuous phase. A high intensity pulsed electric field is applied so as to shatter the initial droplets into a ferromagnetic emulsion comprising many smaller daughter droplets having a greater combined total surface area than that of the initial droplets in contact with the continuous phase material. A magnetic field is applied to control the position of the ferromagnetic emulsion for enhanced coalescence of the daughter droplets into larger reformed droplets.

  16. Electric field-driven, magnetically-stabilized ferro-emulsion phase contactor

    DOEpatents

    Scott, T.C.

    1990-07-17

    Methods and systems are disclosed for interfacial surface area contact between a dispersed phase liquid and a continuous phase liquid in counter-current flow for purposes such as solvent extraction. Initial droplets of a dispersed phase liquid material containing ferromagnetic particles functioning as a packing'' are introduced to a counter-current flow of the continuous phase. A high intensity pulsed electric field is applied so as to shatter the initial droplets into a ferromagnetic emulsion comprising many smaller daughter droplets having a greater combined total surface area than that of the initial droplets in contact with the continuous phase material. A magnetic field is applied to control the position of the ferromagnetic emulsion for enhanced coalescence of the daughter droplets into larger reformed droplets. 2 figs.

  17. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    SciTech Connect

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30

    This project involves the use of an innovative new invention Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude

  18. International News Flows in the Post-Cold War World: Mapping the News and the News Producers.

    ERIC Educational Resources Information Center

    Sreberny-Mohammadi, Annabelle

    1995-01-01

    Reviews the global political environment, major global news providers, and technologies of global news production. Argues for a multinational comparative mapping of international news representation in the 1990s. Outlines a major international venture to update and elaborate the 1979 UNESCO/IAMCR study of foreign news in the media of 29 countries,…

  19. Hydrodynamic model for drying emulsions

    NASA Astrophysics Data System (ADS)

    Feng, Huanhuan; Sprakel, Joris; van der Gucht, Jasper

    2015-08-01

    We present a hydrodynamic model for film formation in a dense oil-in-water emulsion under a unidirectional drying stress. Water flow through the plateau borders towards the drying end leads to the buildup of a pressure gradient. When the local pressure exceeds the critical disjoining pressure, the water films between droplets break and the droplets coalesce. We show that, depending on the critical pressure and the evaporation rate, the coalescence can occur in two distinct modes. At low critical pressures and low evaporation rates, coalescence occurs throughout the sample, whereas at high critical pressures and high evaporation rate, coalescence occurs only at the front. In the latter case, an oil layer develops on top of the film, which acts as a diffusive barrier and slows down film formation. Our findings, which are summarized in a state diagram for film formation, are in agreement with recent experimental findings.

  20. MedlinePlus FAQ: News Coverage

    MedlinePlus

    ... medlineplus/faq/news.html Question: I saw a news article on MedlinePlus but now I can't ... this page, please enable JavaScript. Answer: The health news page displays the most recent news. MedlinePlus displays ...

  1. LATIN--Latin American Regional News Agency.

    ERIC Educational Resources Information Center

    Nichols, John Spicer

    The establishment of a regional news agency for Latin America to improve the balance of news flow and increase the transmission of news more applicable to regional problems has often been proposed. Despite wide acceptance of the concept, the birth of the Third World's first regional news agency, Agencia Latinoamericana de Informacion (LATIN), has…

  2. Index to NASA News Releases 1995

    NASA Technical Reports Server (NTRS)

    1996-01-01

    This issue of the index to NASA News Releases contains a listing of news releases distributed by the Office of Public Affairs, NASA Headquarters, during 1995. The index is arranged in six sections: Subject index, Personal name index, News release number index, Accession number index, Speeches, and News releases.

  3. Television News and the Miners' Strike.

    ERIC Educational Resources Information Center

    Cumberbatch, Guy; And Others

    A content analysis was performed on all of the BBC (British Broadcasting Corporation) Nine O'Clock News and ITV (Independent Television) News at Ten programs that were broadcast during Britain's year-long miners' strike--March 1984-March 1985--and a four-month sample of Channel 4 news to examine how television news covered a protracted story of…

  4. 7 CFR 28.904 - Market news.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 2 2014-01-01 2014-01-01 false Market news. 28.904 Section 28.904 Agriculture..., TESTING, AND STANDARDS Cotton Classification and Market News Service for Producers Classification and Market News Services § 28.904 Market news. The Director shall cause to be distributed to producers...

  5. 7 CFR 28.904 - Market news.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 2 2012-01-01 2012-01-01 false Market news. 28.904 Section 28.904 Agriculture..., TESTING, AND STANDARDS Cotton Classification and Market News Service for Producers Classification and Market News Services § 28.904 Market news. The Director shall cause to be distributed to producers...

  6. 7 CFR 28.904 - Market news.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 2 2013-01-01 2013-01-01 false Market news. 28.904 Section 28.904 Agriculture..., TESTING, AND STANDARDS Cotton Classification and Market News Service for Producers Classification and Market News Services § 28.904 Market news. The Director shall cause to be distributed to producers...

  7. 7 CFR 28.904 - Market news.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 2 2011-01-01 2011-01-01 false Market news. 28.904 Section 28.904 Agriculture..., TESTING, AND STANDARDS Cotton Classification and Market News Service for Producers Classification and Market News Services § 28.904 Market news. The Director shall cause to be distributed to producers...

  8. 7 CFR 28.904 - Market news.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 2 2010-01-01 2010-01-01 false Market news. 28.904 Section 28.904 Agriculture..., TESTING, AND STANDARDS Cotton Classification and Market News Service for Producers Classification and Market News Services § 28.904 Market news. The Director shall cause to be distributed to producers...

  9. MedlinePlus FAQ: News Coverage

    MedlinePlus

    ... gov/faq/news.html Question: I saw a news article on MedlinePlus but now I can't ... this page, please enable JavaScript. Answer: The health news page displays the most recent news. MedlinePlus displays ...

  10. Scientific Sources' Perception of Network News Accuracy.

    ERIC Educational Resources Information Center

    Moore, Barbara; Singletary, Michael

    Recent polls seem to indicate that many Americans rely on television as a credible and primary source of news. To test the accuracy of this news, a study examined three networks' newscasts of science news, the attitudes of the science sources toward reporting in their field, and the factors related to accuracy. The Vanderbilt News Archives Index…

  11. The Diffusion of "Shocking" Good News.

    ERIC Educational Resources Information Center

    Haroldsen, Edwin O.; Harvey, Kenneth

    1979-01-01

    A study of the diffusion of news about the Mormon Church's approval of Blacks for the priesthood revealed that "shocking" good news can ignite the interpersonal communications system, that news has more credibility when obtained from media than when obtained interpersonally, and that people use mass media to verify news obtained interpersonally.…

  12. Emulsion formation at the Pore-Scale

    NASA Astrophysics Data System (ADS)

    Armstrong, R. T.; Van Den Bos, P.; Berg, S.

    2012-12-01

    The use of surfactant cocktails to produce ultra-low interfacial tension between water and oil is an enhanced oil recovery method. In phase behavior tests three distinct emulsion phases are observed: (1) oil-in-water emulsion; (2) microemulsion; and (3) water-in-oil emulsion. However, it is unknown how phase behavior manifests at the pore-scale in a porous media system. What is the time scale needed for microemulsion formation? Where in the pore-space do the microemulsions form? And in what order do the different emulsion phases arrange during oil bank formation? To answer these questions micromodel experiments were conducted. These experiments are used to build a conceptual model for phase behavior at the pore-scale.

  13. Aging properties of Kodak type 101 emulsions

    NASA Technical Reports Server (NTRS)

    Dohne, B.; Feldman, U.; Neupert, W.

    1984-01-01

    Aging tests for several batches of Kodak type 101 emulsion show that storage conditions significantly influence how well the film will maintain its sensitometric properties, with sensitivity and density increasing to a maximum during this period. Any further aging may result in higher fog levels and sensitivity loss. It is noted that storage in an environment free of photographically active compounds allows film property optimization, and that film batches with different sensitivities age differently. Emulsions with maximum 1700-A sensitivity are 2.5 times faster than those at the low end of the sensitivity scale. These sensitive emulsions exhibit significantly accelerated changes in aging properties. Their use in space applications requires careful consideration of time and temperature profiles, encouraging the use of less sensitive emulsions when the controllability of these factors is limited.

  14. Concentrated emulsion pathway to novel composite polymeric membranes and their use in pervaporation

    SciTech Connect

    Ruckenstein, E.; Sun, F.

    1995-10-01

    Pervaporation is becoming recognized as an energy-efficient alternative to distillation and other separation methods of liquid mixtures, especially in cases in which the traditional separation techniques are not efficient, such as the separation of azeotropic mixtures, close-boiling-point components, isomeric components, and recovery or removal of trace organic substances from aqueous solutions. Novel composite polymeric membranes have been prepared, using concentrated emulsions as precursors, and employed in the pervaporation of various liquid mixtures. In order to improve the stability of the concentrated emulsion, the hydrophilicity and/or the hydrophobicity of the phases involved must be increased by replacing them with their solutions in water and/or in a hydrocarbon, respectively. Another possibility of improving the stability is to increase the viscosity of the phases, by partial polymerization of one or both phases before preparing the concentrated emulsion. The emulsion gel was subsequently transformed into a polymer composite by polymerizing both phases. The dispersed phase should be selected to yield a hydrophobic (hydrophilic) polymer which is compatible with the components selected for separation and incompatible with the other components, while the continuous phase should be selected to yield a hydrophilic (hydrophobic) polymer which is incompatible with all of the components of the mixture, and thus it can ensure the integrity of the membrane. As examples, several composite polymeric membranes were designed, prepared, and employed in the separation by pervaporation of water-ethanol,aromatics-paraffinics, and aromatics-alcohol mixtures.

  15. Liquid Biopsy May Help Doctors Track Changes in Tumors

    MedlinePlus

    ... page: https://medlineplus.gov/news/fullstory_159208.html Liquid Biopsy May Help Doctors Track Changes in Tumors ... Now, researchers report that a new blood-based "liquid biopsy" could be a groundbreaking alternative. Doctors used ...

  16. The effect of butter grains on physical properties of butter-like emulsions.

    PubMed

    Rønholt, Stine; Buldo, Patrizia; Mortensen, Kell; Andersen, Ulf; Knudsen, Jes C; Wiking, Lars

    2014-01-01

    Milk fat exists as globules in its natural state in milk. The potential of using globular fat to modulate the rheological properties and crystallization behavior in butter-like emulsions was studied in the present work. We conducted a comparative study of butter-like emulsions, with a fat phase consisting of 0, 10, 25, 50, or 100% anhydrous milk fat (AMF), the remaining fat being butter grains, and all samples containing 20% water, to obtain systematic variation in the ratio of globular fat. All emulsions were studied over 4wk of storage at 5°C. By combining small and large deformation rheology, we conducted a detailed characterization of the rheological behavior of butter-like emulsions. We applied differential scanning calorimetry to monitor thermal behavior, confocal laser scanning microscopy for microstructural analysis, and low-field pulsed nuclear magnetic resonance spectrometry to measure solid fat content. By combining these techniques, we determined that increasing the fraction of globular fat (by mixing with butter grains) decreases the hardness of butter-like emulsions up to an order of magnitude at d 1. However, no difference was observed in thermal behavior as a function of butter grain content, as all emulsions containing butter grains revealed 2 endothermal peaks corresponding to the high (32.7°C ± 0.6) and medium (14.6°C ± 0.1) melting fractions of fatty acids. In terms of microstructure, decreasing the amount of butter grains in the emulsions resulted in formation of a denser fat crystal network, corresponding to increased hardness. Moreover, microstructural analysis revealed that the presence of butter grains resulted in faster formation of a continuous fat crystal network compared with the 100% AMF sample, which was dominated by crystal clusters surrounded by liquid oil. During storage, hardness remained stable and no changes in thermal behavior were observed, despite an increase in solid fat content of up to 5%. After 28d of storage, we

  17. Two-dimensional materials as emulsion stabilizers: interfacial thermodynamics and molecular barrier properties.

    PubMed

    Creighton, Megan A; Ohata, Yuzo; Miyawaki, Jin; Bose, Arijit; Hurt, Robert H

    2014-04-01

    A new application for two-dimensional (2D) materials is emulsification, where they can serve as ultrathin platelike interfacial stabilizers in two-liquid systems. We present a first detailed thermodynamic analysis of atomically thin 2D materials at organic-aqueous liquid-liquid interfaces and derive expressions for the transfer free energies of emulsion stabilization that account for material geometry, van der Waals transparency or opacity, and variable hydrophobicity. High mass potency is shown to be an intrinsic property of the 2D geometry, which at the atomically thin limit places every atom in contact with both liquid phases, resulting in unit atom efficiency. The thermodynamic model successfully predicts that graphene oxide but not pristine graphene has a favorable hydrophobic-hydrophilic balance for oil-water emulsion stabilization. Multilayer tiling is predicted to occur by the passivation of droplet surface patches left uncovered by packing inefficiencies in the first monolayer, and complete multilayer coverage is confirmed by cryogenic scanning electron microscopy. The molecular barrier function of graphene interfacial films causes a significant suppression of dispersed-phase evaporation rates with potential applications in controlled release. Finally, these emulsions can be used as templates for creating solid graphene foams or graphene microsacks filled with lipophilic cargos. Emerging 2D materials are promising as dispersants or emulsifiers where high mass potency and multifunctional properties are desired. PMID:24625132

  18. Method for treating tar sands emulsion and apparatus therefor

    SciTech Connect

    Bialek, R.F.

    1986-04-15

    A method is described for resolving a hot bitumen emulsion comprised primarily of bitumen, water and chemical diluents. The method consists of: providing separate but communicated emulsion mixing, and emulsion settling chamber, passing the hot bitumen emulsion through a first elongated mixing passage in the mixing chamber wherein a rapidly flowing stream of recycled emulsion is combined with a minor portion of unrecycled bitumen emulsion, to form a combined bitumen emulsion stream, thereafter passing the combined bitumen emulsion stream into an elongated discontinuous mixing passage comprised of vertically arranged and interconnected mixing passages within the emulsion mixer, where in the combined bitumen emulsion stream passes at a slower rate than in the first elongated mixing passage, passing the combined bitumen emulsion stream into an overflow passage communicated with the second elongated mixing passage, introducing a part of the combined emulsion stream from the overflow passage into the emulsion settling chamber, recycling the remainder of the combined emulsion stream from the overflow passage into the first elongated mixing passage, and removing separated flows of bitumen and water from the settling chamber.

  19. Effect of soybean lecithin on iron-catalyzed or chlorophyll-photosensitized oxidation of canola oil emulsion.

    PubMed

    Choe, Jeesu; Oh, Boyoung; Choe, Eunok

    2014-11-01

    The effect of soybean lecithin addition on the iron-catalyzed or chlorophyll-photosensitized oxidation of emulsions consisting of purified canola oil and water (1:1, w/w) was studied based on headspace oxygen consumption using gas chromatography and hydroperoxide production using the ferric thiocyanate method. Addition levels of iron sulfate, chlorophyll, and soybean lecithin were 5, 4, and 350 mg/kg, respectively. Phospholipids (PLs) during oxidation of the emulsions were monitored by high performance liquid chromatography. Addition of soybean lecithin to the emulsions significantly reduced and decelerated iron-catalyzed oil oxidation by lowering headspace oxygen consumption and hydroperoxide production. However, soybean lecithin had no significant antioxidant effect on chlorophyll-photosensitized oxidation of the emulsions. PLs in soybean lecithin added to the emulsions were degraded during both oxidation processes, although there was little change in PL composition. Among PLs in soybean lecithin, phosphatidylethanolamine and phosphatidylinositol were degraded the fastest in the iron-catalyzed and the chlorophyll-photosensitized oxidation, respectively. The results suggest that addition of soybean lecithin as an emulsifier can also improve the oxidative stability of oil in an emulsion. PMID:25312008

  20. Fabrication and characterization of Pickering emulsions and oil gels stabilized by highly charged zein/chitosan complex particles (ZCCPs).

    PubMed

    Wang, Li-Juan; Yin, Shou-Wei; Wu, Lei-Yan; Qi, Jun-Ru; Guo, Jian; Yang, Xiao-Quan

    2016-12-15

    Herein, we reported a facile method to fabricate ultra-stable, surfactant- and antimicrobial-free Pickering emulsions by designing and modulating emulsions' interfaces via zein/chitosan colloid particles (ZCCPs). Highly charged ZCCPs with neutral wettability were produced by a facile anti-solvent procedure. The ZCCPs were shown to be effective Pickering emulsifiers because the emulsions formed were highly resistant to coalescence over a 9-month storage period. The ZCCPs were adsorbed irreversibly at the interface during emulsification, forming a hybrid network framework in which zein particles were embedded within the chitosan network, yielding ultra-stable food-grade zein/chitosan colloid particles stabilized Pickering emulsions (ZCCPEs). Moreover, stable surfactant-free oil gels were obtained by a one-step freeze-drying process of the precursor ZCCPEs. This distinctive interfacial architecture accounted for the favourable physical performance, and potentially oxidative and microbial stability of the emulsions and/or oil gels. This work opens up a promising route via a food-grade Pickering emulsion-template approach to transform liquid oil into solid-like fats with zero trans-fat formation. PMID:27451205

  1. Increasing Learning from TV News.

    ERIC Educational Resources Information Center

    Perloff, Richard M.; And Others

    1982-01-01

    Describes an experiment that manipulated two variables, repetition and pausing for viewer "digestion" of information in a news telecast. Concludes that the use of repetition increased viewers' retention of information, but that pauses did not. (FL)

  2. Microbial Control News - November 2011

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This is the first of a column in the Society for Invertebrate Pathology Newsletter. Entitled "Microbial Control News" this article summarizes regulatory actions in the U.S. and Canada regarding microbial insect pest control agents....

  3. Good News About Childhood Cancer

    MedlinePlus

    ... Home Current Issue Past Issues Good News About Childhood Cancer Past Issues / Spring 2008 Table of Contents ... 85 percent for the most common form of childhood cancer (acute lymphoblastic leukemia or ALL). During the ...

  4. 40 CFR 467.20 - Applicability; description of the rolling with emulsions subcategory.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... rolling with emulsions subcategory. 467.20 Section 467.20 Protection of Environment ENVIRONMENTAL... Rolling With Emulsions Subcategory § 467.20 Applicability; description of the rolling with emulsions... the rolling with emulsions subcategory....

  5. The Myth of Television News.

    ERIC Educational Resources Information Center

    Stevenson, Robert L.; White, Kathryn P.

    After critiquing the usual estimates of the importance of television as a source of news, the national audience for television news over a two-week period is identified from the 1974-1975 W.R. Simmons study (which uses a diary technique for gathering data). Analysis showed that, in the two-week period, 49% of the adult population did not watch a…

  6. Simple, reversible emulsion system switched by pH on the basis of chitosan without any hydrophobic modification.

    PubMed

    Liu, Hao; Wang, Chaoyang; Zou, Shengwen; Wei, Zengjiang; Tong, Zhen

    2012-07-31

    Chitosan without hydrophobic modification is not a good emulsifier itself. However, it has a pH-tunable sol-gel transition due to free amino groups along its backbone. In the present work, a simple reversible Pickering emulsion system based on the pH-tunable sol-gel transition of chitosan was developed. At pH > 6.0, as adjusted by NaOH, chitosan was insoluble in water. Chitosan nanoparticles or micrometer-sized floccular precipitates were formed in situ. These chitosan aggregates could adsorb at the interface of oil and water to stabilize the o/w emulsions, so-called Pickering emulsions. At pH < 6.0, as adjusted by HCl, chitosan was soluble in water. Demulsification happened. Four organic solvents (liquid paraffin, n-hexane, toluene, and dichloromethane) were chosen as the oil phase. Reversible emulsions were formed for all four oils. Chitosan-based Pickering emulsions could undergo five cycles of emulsification-demulsification with only a slight increase in the emulsion droplet size. They also had good long-term stability for more than 2 months. Herein, we give an example of chitosan without any hydrophobic modification to act as an effective emulsifier for various oil-water systems. From the results, we have determined that natural polymers with a stimulus-responsive sol-gel transition should be a good particulate emulsifier. The method for in situ formation of pH-responsive Pickering emulsions based on chitosan will open up a new route to the preparation of a wide range of reversible emulsions. PMID:22762435

  7. Emulsion Mapping in Pork Meat Emulsion Systems with Various Lipid Types and Brown Rice Fiber.

    PubMed

    Choi, Yun-Sang; Kim, Young-Boong; Kim, Hyun-Wook; Hwang, Ko-Eun; Song, Dong-Heon; Jeong, Tae-Jun; Park, Jinhee; Kim, Cheon-Jei

    2015-01-01

    This study was conducted to evaluate emulsion mapping between emulsion stability and cooking yields, apparent viscosity, and hardness of reduced-fat pork emulsion systems. The reduced-fat emulsion systems were supplemented with different lipid types and brown rice bran fiber (BRF) concentrations. Compared to the control with 30% back fat, lower emulsion stability and higher cooking yield of meat emulsion systems were observed in T1 (30% back fat+1% BRF), T2 (30% back fat+2% BRF), T3 (30% back fat+3% BRF), T4 (30% back fat+6% BRF), and T15 (10% back fat+10% canola oil+2% BRF). Lower emulsion stability and higher apparent viscosity were observed in T1, T2, T3, T4, and T8 (20% back fat+3% BRF) compared to the control. Lower emulsion stability and higher hardness was detected in all treatments compared with the control, except T5 (20% back fat), T10 (10% back fat+10% canola oil+2% BRF), T11 (10% back fat+10% olive oil+2% BRF), T12 (10% back fat+10% grape seed oil+2% BRF), and T13 (10% back fat+10% soybean oil+2% BRF). This approach has been found particularly useful for highlighting differences among the emulsified properties in emulsion meat products. Thus, the results obtained with emulsion mapping are useful in making emulsified meat products of desired quality characteristics, partially replacing pork back fat with a mix of 10% back fat, 10% canola oil and 2% BRF was most similar to the control with 30% pork back fat. PMID:26761836

  8. Emulsion Mapping in Pork Meat Emulsion Systems with Various Lipid Types and Brown Rice Fiber

    PubMed Central

    Choi, Yun-Sang; Kim, Young-Boong; Park, Jinhee

    2015-01-01

    This study was conducted to evaluate emulsion mapping between emulsion stability and cooking yields, apparent viscosity, and hardness of reduced-fat pork emulsion systems. The reduced-fat emulsion systems were supplemented with different lipid types and brown rice bran fiber (BRF) concentrations. Compared to the control with 30% back fat, lower emulsion stability and higher cooking yield of meat emulsion systems were observed in T1 (30% back fat+1% BRF), T2 (30% back fat+2% BRF), T3 (30% back fat+3% BRF), T4 (30% back fat+6% BRF), and T15 (10% back fat+10% canola oil+2% BRF). Lower emulsion stability and higher apparent viscosity were observed in T1, T2, T3, T4, and T8 (20% back fat+3% BRF) compared to the control. Lower emulsion stability and higher hardness was detected in all treatments compared with the control, except T5 (20% back fat), T10 (10% back fat+10% canola oil+2% BRF), T11 (10% back fat+10% olive oil+2% BRF), T12 (10% back fat+10% grape seed oil+2% BRF), and T13 (10% back fat+10% soybean oil+2% BRF). This approach has been found particularly useful for highlighting differences among the emulsified properties in emulsion meat products. Thus, the results obtained with emulsion mapping are useful in making emulsified meat products of desired quality characteristics, partially replacing pork back fat with a mix of 10% back fat, 10% canola oil and 2% BRF was most similar to the control with 30% pork back fat. PMID:26761836

  9. Biodegradable and magnetic core-shell composite particle prepared by emulsion solvent diffusion method

    NASA Astrophysics Data System (ADS)

    Oka, Chiemi; Ushimaru, Kazunori; Horiishi, Nanao; Tsuge, Takeharu; Kitamoto, Yoshitaka

    2016-02-01

    The present paper describes optimization of preparation conditions of a core-shell composite particle, and its heat generation by alternating magnetic fields. The composite particles are prepared with a modified emulsion solvent diffusion method, which is combined with Pickering emulsion stabilized by magnetic nanoparticles. In this method, the magnetic nanoparticles act as an emulsifier, and its amount and size are crucial to morphology of the composite particles. The magnetic nanoparticles of 8-9 nm would be strongly adsorbed at a liquid-liquid interface rather than the larger nanoparticles. At the optimized concentration of the magnetic nanoparticle’s suspension for the preparation, small and uniform composite particles are obtained since the amount of the nanoparticles is enough to prevent coalescence of droplets during the formation of the composites. The heat generation by alternating magnetic fields emerged certainly. This result suggests the composite particles have a property as a heat-generating carrier for hyperthermia treatment.

  10. LET dependence of bubbles evaporation pulses in superheated emulsion detectors

    NASA Astrophysics Data System (ADS)

    Di Fulvio, Angela; Huang, Jean; Staib, Lawrence; d'Errico, Francesco

    2015-06-01

    Superheated emulsion detectors are suspensions of metastable liquid droplets in a compliant inert medium. Upon interaction with ionizing radiation, the droplets evaporate, generating visible bubbles. Bubble expansion associated with the boiling of the droplets is accompanied by pressure pulses in both the sonic and ultrasonic frequency range. In this work, we analyzed the signal generated by bubble evaporation in the frequency and time domain. We used octafluoropropane (R-218) based emulsions, sensitive to both photons and neutrons. The frequency content of the detected pulses appears to extend well into the hundreds of kHz, beyond the range used in commercial devices to count bubbles as they are formed (typically 1-10 kHz). Kilohertz components characterize the early part of the waveforms, potentially containing information about the energetics of the explosive bubble initial growth phase. The power spectral density of the acoustic signal produced by neutron-induced evaporation shows a characteristic frequency pattern in the 200-400 kHz range, which is not observed when bubbles evaporate upon gamma ray-induced irradiation. For practical applications, detection of ultrasonic pulses associated with the boiling of the superheated drops can be exploited as a fast readout method, negligibly affected by mechanical ambient noise.

  11. Encapsulation of emulsion droplets by organo-silica shells.

    PubMed

    Zoldesi, C I; Steegstra, P; Imhof, A

    2007-04-01

    Surfactant-stabilized emulsion droplets were used as templates for the synthesis of hollow colloidal particles. Monodisperse silicone oil droplets were prepared by hydrolysis and polymerization of dimethyldiethoxysiloxane monomer, in the presence of surfactant: sodium dodecyl sulphate (SDS, anionic) or Triton X-100 (non-ionic). A sharp decrease in the average droplet radius with increasing surfactant concentration was found, with a linear dependence of the droplet radius on the logarithm of the surfactant concentration. The surfactant-stabilized oil droplets were then encapsulated with a solid shell using tetraethoxysilane, and hollow particles were obtained by exchange of the liquid core. The size and polydispersity of the oil droplets and the thickness of the shell were determined using static light scattering, and hollow particles were characterized by electron microscopy. Details on the composition of the shell material were obtained from energy-dispersive X-ray analysis. In the case of sodium dodecyl sulphate, the resulting shells were relatively thin and rough, while when Triton X-100 was used, smooth shells were obtained which could be varied in thickness from very thick ( approximately 150 nm) to very thin shells ( approximately 17 nm). Finally, hexane droplets were encapsulated using the same procedure, showing that our method can in principle be extended to a wide range of emulsions. PMID:17240392

  12. Disjoining pressure isotherms of water-in-bitumen emulsion films.

    PubMed

    Taylor, Shawn D; Czarnecki, Jan; Masliyah, Jacob

    2002-08-01

    In the oil sands industry, undesirable water-in-oil emulsions are often formed during the bitumen recovery process where water is used to liberate bitumen from sand grains. Nearly all of the water is removed except for a small percentage (approximately 1 to 2%), which remains in the solvent-diluted bitumen as micrometer-sized droplets. Knowledge of the colloidal forces that stabilized these water droplets would help to increase our understanding of how these emulsions are stabilized. In this study, the thin liquid film-pressure balance technique has been used to measure isotherms of disjoining pressure in water/toluene-diluted bitumen/water films at five different toluene-bitumen mass ratios. Even though a broad range of mass ratios was studied, only two isotherms are obtained, indicating a possible change in the molecular orientation of surfactant molecules at the bitumen/water interfaces. At low toluene-bitumen mass ratios, the film stability appears to be due to a strong, short-range steric repulsion created by a surfactant bilayer. Similar isotherms were obtained for water/toluene-diluted asphaltene/water films, indicating that the surface active material at the interface probably originated from the asphaltene fraction of the bitumen. However, unlike the bitumen films, films of toluene-diluted asphaltenes often formed very rigid interfaces similar to the "protective skin" described by other researcher. PMID:16290773

  13. Dynamic film and interfacial tensions in emulsion and foam systems

    SciTech Connect

    Kim, Y.H.; Koczo, K.; Wasan, D.T.

    1997-03-01

    In concentrated fluid dispersions the liquid films are under dynamic conditions during film rupture or drainage. Aqueous foam films stabilized with sodium decylsulfonate and aqueous emulsion films stabilized with the nonionic Brij 58 surfactant were formed at the tip of a capillary and the film tension was measured under static and dynamic conditions. In the stress relaxation experiments the response of the film tension to a sudden film area expansion was studied. These experiments also allowed the direct measurement of the Gibbs film elasticity. In the dynamic film tension experiments, the film area was continuously increased by a constant rate and the dynamic film tension was monitored. The measured film tensions were compared with the interfacial tensions of the respective single air/water and oil/water interfaces, which were measured using the same radius of curvature, relative expansion, and expansion rate as in the film studies. It was found that under dynamic conditions the film tension is higher than twice the single interfacial tension (IFT) and a mechanism was suggested to explain the difference. When the film, initially at equilibrium, is expanded and the interfacial area increases, a substantial surfactant depletion occurs inside the film. As a result, the surfactant can be supplied only from the adjoining meniscus (Plateau border) by surface diffusion, and the film tension is controlled by the diffusion and adsorption of surfactant in the meniscus. The results have important implications for the stability and rheology of foams and emulsions with high dispersed phase ratios (polyhedral structure).

  14. Location and Influence of Added Block Copolymers on the Droplet Size in Oil-in-Oil Emulsions.

    PubMed

    Asano, Itaru; So, Soonyong; Lodge, Timothy P

    2015-07-14

    We have investigated the effect of added polystyrene-b-poly(ethylene oxide) (SO) copolymer on the stability of oil-in-oil (O/O) emulsions containing polystyrene (PS) and poly(ethylene glycol) (PEG) in chloroform (CHCl3) and directly visualized the location of SO in the emulsions by using dye-labeled SO (SO*) with confocal laser scanning microscopy (CLSM). The emulsion formed by PS/PEG/CHCl3 = 14/6/80 (wt %) consisted of a droplet phase of PS in CHCl3 and a continuous phase containing PEG in CHCl3. SO*s with various molecular weights (Mn,SO) and volume fractions of the PS block in SO (fPS) were prepared via living anionic polymerization and subsequent end-esterification. The effect of SO on the droplet size in the emulsions was investigated as a function of both Mn,SO and fPS. Increasing Mn,SO and decreasing fPS were effective at reducing the droplet size down to less than 1 μm, which is 100 times smaller than in the absence of SO. The location of SO*s in the O/O emulsions was further investigated by CLSM. We found that the location of SO*s changed from the droplet interior to the liquid-liquid interface and then to the continuous phase with decreasing fPS. We discuss the possible mechanism in terms of the relation of SO* location to the droplet size. PMID:26134549

  15. The physicochemical stability and in vitro bioaccessibility of beta-carotene in oil-in- water sodium caseinate emulsions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Beta-carotene (BC), the most important dietary source of provitamin A, is necessary for optimum human health. BC is insoluble or only slightly soluble in most liquids but its bioavailability improves when ingested with fat. Therefore lipid emulsions are ideal matrices for BC delivery. BC (0.1%) in ...

  16. Minimizing liquid contaminants in natural gas liquids

    SciTech Connect

    Brown, R.L.; Wines, T.H.; Williamson, K.M.

    1996-12-31

    In processing natural gas liquids, significant contamination occurs with liquid dispersions and emulsions. Natural gas liquids (NGL) and liquid petroleum gas (LPG) streams are treated with caustic to remove residual organic sulfur compounds such as mercaptans and with amines to remove hydrogen sulfide. In both cases a liquid/liquid contactor is used. Significant amounts of the caustic or amine can be carried over into the product stream in process units that are running at rates above design capacity, are treating high sulfur feed stocks, or have other operational problems. The carried over liquid results in off-spec products, excessive loses of caustic or amine, and can cause operating problems in downstream processes. In addition, water is a significant contaminant which can cause LPG and natural gasoline to be off-specification. This paper discusses a new technique for separating very stable liquid dispersions of caustic, amine, or water from natural gas liquids using liquid/liquid cartridge coalescers constructed with specially formulated polymer and fluoropolymer medium with enhanced surface properties. In addition, factors influencing the coalescer mechanism will be discussed including interfacial tension, concentration of surface active compounds, steric repulsion, and electrostatic charge affects. Results from field tests, operating data from commercial installations, and economic benefits will also be presented.

  17. High pressure-resistant nonincendive emulsion explosive

    DOEpatents

    Ruhe, Thomas C.; Rao, Pilaka P.

    1994-01-01

    An improved emulsion explosive composition including hollow microspheres/bulking agents having high density and high strength. The hollow microspheres/bulking agents have true particle densities of about 0.2 grams per cubic centimeter or greater and include glass, siliceous, ceramic and synthetic resin microspheres, expanded minerals, and mixtures thereof. The preferred weight percentage of hollow microspheres/bulking agents in the composition ranges from 3.0 to 10.0 A chlorinated paraffin oil, also present in the improved emulsion explosive composition, imparts a higher film strength to the oil phase in the emulsion. The emulsion is rendered nonincendive by the production of sodium chloride in situ via the decomposition of sodium nitrate, a chlorinated paraffin oil, and sodium perchlorate. The air-gap sensitivity is improved by the in situ formation of monomethylamine perchlorate from dissolved monomethylamine nitrate and sodium perchlorate. The emulsion explosive composition can withstand static pressures to 139 bars and dynamic pressure loads on the order of 567 bars.

  18. Emulsifying potency of new amino acid-type surfactant (II): stable water-in-oil (W/O) emulsions containing 85 wt% inner water phase.

    PubMed

    Yokoyama, S; Kouchi, J; Tabohashi, T; Harusawa, F; Yamaguchi, A; Sakai, H; Abe, M

    2001-10-01

    The ternary phase diagram for N-[3-lauryloxy-2-hydroxypropyl]-L-arginine L-glutamate (C12HEA-Glu), a new amino acid-type surfactant, /oleic acid (OA)/water system was established. The liquid crystal and gel complex formations between C12HEA-Glu and OA were applied to a preparation of water-in-oil (W/O) emulsions. Stable W/O emulsions containing liquid paraffin (LP) as the oil and a mixture of C12HEA-Glu and OA as the emulsifier were formed. The preparation of stable W/O emulsions containing 85 wt% water phase was also possible, in which water droplets would be polygonally transformed and closely packed, since the maximum percentage of inner phase is 74% assuming uniformly spherical droplets. Water droplets would be taken into the liquid crystalline phase (or the gel complex) and the immovable water droplets would stabilize the W/O emulsion system. The viscosity of emulsions abruptly increased above the 75 wt% water phase (dispersed phase). The stability of W/O emulsions with a lower weight ratio of OA to C12HEA-Glu and a higher ratio of water phase was greater. This unusual phenomenon may be related to the formation of a liquid crystalline phase between C12HEA-Glu and OA, and the stability of the liquid crystal at a lower ratio of oil (continuous phase). W/O and oil-in-water (O/W) emulsions containing LP were selectively prepared using a mixture of C12HEA-Glu and OA since the desirable hydrophile-lipophile balance (HLB) number for the emulsification was obtainable by mixing the two emulsifiers. PMID:11605664

  19. Aging mechanism in model Pickering emulsion.

    PubMed

    Fouilloux, Sarah; Malloggi, Florent; Daillant, Jean; Thill, Antoine

    2016-01-21

    We study the stability of a model Pickering emulsion system using fluorinated oil and functionalized silica nanoparticles. A special counter-flow microfluidic set-up was used to prepare monodisperse oil droplets in water. The wettability of the monodisperse silica nanoparticles (NPs) could be tuned by surface grafting and the surface coverage of the droplets was controlled using the microfluidic setup. For surface coverage as low as 23%, we observed a regime of Pickering emulsion stability where the surface coverage of emulsion droplets of constant size increases with time, coexisting with an excess of oil phase. Our results demonstrate that the previously observed limited coalescence regime where surface coverage tends to control the average size of the final droplets must be put in a broader perspective. PMID:26549639

  20. Development of cetyl dimethicone based water-in-oil emulsion containing botanicals: Physical characteristics and stability.

    PubMed

    Waqas, Muhammad Khurram; Akhtar, Naveed; Shah, Pervaiz Akhtar; Danish, Muhammad Zeeshan; Shah, Arshad Ali; Braga, Valdir de Andrade; Khan, Barkat Ali

    2016-01-01

    The aim of current research was to develop a water-in-oil emulsion containing grape seed extract for application in cosmeceuticals. Finally grinded dried grape seeds powder was extracted with hydro alcoholic mixture. Emulsions consisting of different concentrations of cetyl dimethicone (Abile EM90), the nonionic emulsifier, liquid paraffin as oily phase and water as aqueous phase were developed. Color, odor, pH, viscosity, liquefaction, phase separation, centrifugation and thermal stability of the formulated emulsions were observed at various storage temperatures i.e. 8±0.5°C, 25±0.5°C, 40±0.5°C and 40°C±0.5°C with 70% RH. The stable formulation consist of 16% mineral oil, 4% of ABIL EM 90(®), 4% grape seeds extract, 1% rose oil and 75% distilled water. All the results derived from this study showed good stability over the three months study period which indicates w/o emulsion can be used as carrier of 4% grape seeds extract to enhance desired effects when applied topically. PMID:26826810

  1. Improved physical stability and injectability of non-aqueous in situ PLGA microparticle forming emulsions.

    PubMed

    Voigt, M; Koerber, M; Bodmeier, R

    2012-09-15

    The goal of this study was to obtain physically stable non-aqueous in situ forming microparticle (ISM) emulsions capable of forming biodegradable microparticles upon injection. ISM emulsions consist of a biocompatible organic PLGA solution dispersed in a continuous oil phase prepared in a two-syringe/connector system prior to administration. A variety of parenteral approved excipients were tested for a stability-enhancing effect and possible stabilization mechanisms evaluated. Glycerol monostearate (GMS) showed superior stabilizing potential prolonging the emulsion stability from a few minutes to more than 12h. Flow behavior analysis, differential scanning calorimetry, polarized light- and Cryo-electron microscopy revealed, that the stabilization was caused by an immediate, more than 5-fold viscosity increase in the continuous phase after emulsification and by a stabilized interface through a liquid crystalline GMS layer around the polymer solution droplets. Despite the viscosity increase the injectability of the stabilized ISM emulsion was improved by about 30% compared to the corresponding highly viscous PLGA solution (in situ implant) due to a pronounced shear thinning of the GMS containing oil phase. The injectability improvement allows a faster administration or enables the use of thinner needles and hence reduced patient discomfort. PMID:22677417

  2. In Situ Assembly of Hydrophilic and Hydrophobic Nanoparticles at Oil-Water Interfaces as a Versatile Strategy To Form Stable Emulsions.

    PubMed

    Saha, Amitesh; John, Vijay T; Bose, Arijit

    2015-09-30

    We report a conceptually new strategy for forming particle-stabilized emulsions. We begin with stable, dilute suspensions of highly hydrophilic nanoparticles in water and hydrophobic nanoparticles in oil. When the two suspensions are mixed, attractive interactions between the hydrophilic and hydrophobic particles cause them to assemble at the oil-water interfaces into partially wettable or Janus-like clusters that effectively stabilize emulsions. By tuning the ratio of hydrophilic to hydrophobic particles in the clusters, both water-in-oil as well as oil-in-water emulsions can be formed. The van der Waals interaction energy between two particle types across an aqueous-organic interface provide a systematic guide to particle and liquid combinations that can form stable emulsions using our strategy, or identify when emulsions will not form. Our experiments and analysis provide a new platform for the formation of particle-stabilized emulsions and can be used to combine particles of different functionalities at emulsion droplet surfaces for generating novel materials. PMID:26372053

  3. Biodegradation of news inks

    SciTech Connect

    Erhan, S.Z.; Bagby, M.O.

    1995-12-01

    Printing ink vehicles that require no petroleum components were prepared by modifying vegetable oil. Physical properties of inks formulated with these vehicles meet or exceed the industry standards for lithographic and letterpress newsprint applications. Elimination of petroleum-based resin and reduced pigment requirements, due to the light vehicle color, provide a competitively priced alternative to petroleum-based inks of equal quality. These ink vehicles, made exclusively from soybean oil, were subjected to biodegradation, and the results were compared with those obtained with commercial vehicles. Results show that they degrade faster and more completely than commercial hybrid (partial) soy or mineral oil based vehicles. Fermentations were allowed to proceed for 5, 12, and 25 days. Both mono-and mixed cultures of microorganisms commonly found in soil were used. In 25 days, commercial mineral oil based vehicles degraded 17-27%, while commercial hybrid soy oil based vehicles degraded 58-68% and our 100% soy oil based vehicles degrade 82-92%. Similar studies were conducted with commercial news inks consisting of soy or mineral oil with petroleum resins along with the four colored pigments and USDA`s 100% soy oil based ink consisting of modified soybean oil and pigment. Results show that pigment slowed the degradation of ink vehicles; however, neither time nor type of pigment played a significant role. Also these inks were degraded by using {open_quotes}Modified Sturm Test{close_quotes} (Organization for Economic Cooperation and Development). In this method, test organisms were obtained from activated sludge, and the extent of degradation was determined by measuring carbon dioxide evolution. In all cases USDA`s ink degraded faster and more completely (for all four colors) than either hybrid soy oil based or petroleum based inks.

  4. Electrodynamic treatment of reversed-type emulsions

    SciTech Connect

    Skachkov, A.E.; Lavrov, I.S.; Timonov, S.M.

    1985-11-01

    The authors have produced an inhomogeneous electric field in processing reversed emulsions by using the oscillations of conducting spheres in an electric field; this is known as the electrical pendulum effect. The apparatus for the electrodynamic treatment of reversed-type emulsion is shown and the physical characteristics (density, kinematic viscosity, dielectric constant) are shown for the hydrocarbons used: hexane, octane, hexadecane and diesel fuel. It is shown that there is a minimum in the dependence of the residual water content after electrodynamic treatment on the external field strength; the minimum shifts to larger external field strength as the viscosity increases.

  5. In the News: Current Events Websites.

    ERIC Educational Resources Information Center

    Byerly, Greg; Brodie, Carolyn S.

    2002-01-01

    Reviews Web sites for current events news that are appropriate for students of various ages. Discusses the possibilities for second language learning and curriculum connections and lists television sites, news magazines, classroom magazines, newspapers, and lesson plans. (LRW)

  6. Professionalism and Awards in Television News Photography.

    ERIC Educational Resources Information Center

    Smith, Conrad; Hubbard, Tom

    1987-01-01

    Tests the hypothesis that photojournalists with high professionalism scores are more likely to win news photography awards. Suggests that television news photography awards recognize skills gained through experience rather than specific professional values. (MM)

  7. Society for the History of Psychology News.

    PubMed

    Lee, Shayna Fox

    2016-05-01

    Presents the Society for the History of Psychology News column. This column records miscellaneous publication news, announcements, research notes, reviews of books, and conference information, as well as references that support their writings. (PsycINFO Database Record PMID:27100928

  8. Optical Long Baseline Interferometry News

    NASA Astrophysics Data System (ADS)

    Lawson, P. R.; Malbet, F.

    2005-12-01

    The Optical Long Baseline Interferometry News is a website and forum for scientists, engineers, and students who share an interest in long baseline stellar interferometry. It was established in 1995 and is the focus of activity of the IAU Working Group on Optical/Infrared Interferometry. Here you will find links to projects devoted to stellar interferometry, news items, recent papers and preprints, and resources for further research. The email news forum was established in 2001 to complement the website and to facilitate exchanges and collaborations. The forum includes an email exploder and an archived list of discussions. You are invited to explore the forum and website at http://olbin.jpl.nasa.gov. Work by PRL was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under contract with the National Aeronautics and Space Administration.

  9. Phase behavior and formation of o/w nano-emulsion in vegetable oil/ mixture of polyglycerol polyricinoleate and polyglycerin fatty acid ester/water systems.

    PubMed

    Wakisaka, Satoshi; Nakanishi, Masami; Gohtani, Shoichi

    2014-01-01

    It is reported that mixing polyglycerol polyricinoleate (PGPR) and polyglycerol laurilester has a great emulsifying capacity, and consequently fine oil-in-water (o/w) emulsions can be formed. However, the role of PGPR is not clear. The objective of this research is to investigate the phase behavior of vegetable oil/mixture of PGPR and polyglycerol fatty acid ester/water systems, and to clarify the role of PGPR in making a fine emulsion. Phase diagrams were constructed to elucidate the optimal process for preparing fine emulsions. In all the systems examined in this study, the phases, including the liquid crystal phase (L(c)) and sponge phase (L(3)), spread widely in the phase diagrams. We examined droplet size of the emulsions prepared from each phase and found that o/w nano-emulsions with droplet sizes as small as 50 nm were formed by emulsifying either from a single L(3) phase or a two-phase region, L(c) + L(3). These results indicate that a sponge phase L(3) or liquid crystal phase L(c) or both is necessary to form an o/w nano-emulsion whose average droplet diameter is less than 50 nm for PGPR and polyglycerin fatty acid ester mixtures used as surfactant. PMID:24521844

  10. Perceptions of Advertising Influence on Broadcast News.

    ERIC Educational Resources Information Center

    Brown, Hubert W.; Barnes, Beth E.

    2001-01-01

    Finds that while students (studying broadcast journalism or advertising) and practitioners (station news directors and agency media directors) were in agreement on the majority of opinion statements discussing advertising's influence on broadcast news content, except students were less bothered by advertising's influence on news content than were…

  11. Making the News: Jobs in TV Journalism

    ERIC Educational Resources Information Center

    Csorny, Lauren

    2009-01-01

    What do TV news workers do each day? For many of them, contributing to daily news broadcasts has changed greatly over the years. This evolution will likely continue for years to come. And more changes to news production are expected, according to Tom Weir, an associate professor at the University of South Carolina's School of Journalism and Mass…

  12. Making Your News Service More Effective.

    ERIC Educational Resources Information Center

    Berger, Joel S., Ed.

    "CASE Currents" and "Techniques" articles, materials written especially for this manual, and papers from the 1976 CASE News/Information Special Conference make up this updated handbook on how to make a college news service more effective. Part I, "Managing the News Service" contains nine papers dealing with such issues as managing, staffing,…

  13. Network Evening News Coverage of Environmental Risk.

    ERIC Educational Resources Information Center

    Greenberg, Michael R.; And Others

    Focusing on ABC, NBC, and CBS's evening news broadcasts from January 1984 through February 1986, a study examined network news coverage of environmental risk--defined as manmade chemical, biological, and physical agents that create risk in the indoor, outdoor, and occupational environments. Using the Vanderbilt University "Television News Index…

  14. An Economic Theory of News Selection.

    ERIC Educational Resources Information Center

    McManus, John

    Over the years, journalists, social scientists, and government commissions have defined news in a variety of ways, but their definitions consistently lack the notion that, above all, news is a commodity and must sell. Within the journalism profession, and particularly in television news, the potential for conflict between a media corporation's…

  15. Technology: News Readers and Other Handy Utilities

    ERIC Educational Resources Information Center

    Van Horn, Royal

    2004-01-01

    In this article, the author discusses how there are advantages and disadvantages to using an Internet News Reader instead of a Web browser. The major advantage is that one can read the headlines and short summaries of news articles from dozens of sources quickly. Another advantage the author points out to news readers is that one gets a short…

  16. News Resources on the World Wide Web.

    ERIC Educational Resources Information Center

    Notess, Greg R.

    1996-01-01

    Describes up-to-date news sources that are presently available on the Internet and World Wide Web. Highlights include electronic newspapers; AP (Associated Press) sources and Reuters; sports news; stock market information; New York Times; multimedia capabilities, including CNN Interactive; and local and regional news. (LRW)

  17. [Perfluorocarbon emulsions and other corpuscular systems influence on neutrophil activity].

    PubMed

    Shekhtman, D G; Safronova, V G; Sklifas, A N; Alovskaia, A A; Gapeev, A B; Obraztsov, V V; Chemeris, N K

    1997-01-01

    Influence of perfluorodecalin, perfluoromethilcyclohexylpiperidine, perfluorotributylamine emulsions on active oxygen form (AOF) generation by neutrophils has been studied. All investigated emulsions stabilized both proxanol 268 and egg yolk phospholipids inhibited PMA-stimulated neutrophil activity. Castor oil emulsion also inhibited the neutrophil activity. Neutrophil response for chemotactic peptide, was unchanged in the presence of all tested emulsions. We suppose that fast hydrophobic attachment of inert submicrone emulsion particles to cell surface provokes alteration of neutrophil plasma membrane function resulting in a decrease of AOF generation. PMID:9490112

  18. Performance of automatic scanning microscope for nuclear emulsion experiments

    SciTech Connect

    Güler, A. Murat; Altınok, Özgür

    2015-12-31

    The impressive improvements in scanning technology and methods let nuclear emulsion to be used as a target in recent large experiments. We report the performance of an automatic scanning microscope for nuclear emulsion experiments. After successful calibration and alignment of the system, we have reached 99% tracking efficiency for the minimum ionizing tracks that penetrating through the emulsions films. The automatic scanning system is successfully used for the scanning of emulsion films in the OPERA experiment and plan to use for the next generation of nuclear emulsion experiments.

  19. Does lactobionic acid affect the colloidal structure and skin moisturizing potential of the alkyl polyglucoside-based emulsion systems?

    PubMed

    Tasic-Kostov, M Z; Reichl, S; Lukic, M Z; Jaksic, I N; Savic, S D

    2011-11-01

    Moisturizing creams are the most prescribed products in dermatology, essential in maintaining healthy skin as well as in the topical treatment of some diseases. The irritation potential of commonly used emulsifiers and moisturizing ingredients, but also their mutual interactions, could affect the functionality and safety of those dermopharmaceutics. The aim of this study was to promote moisturizing alkyl polyglucoside (APG)-based emulsion as vehicle for lactobionic acid (LA), advantageous representative of the alphahydroxyacids (AHAs)-multifunctional moisturizers, assessing the safety for use (in vitro acute skin irritation test using cytotoxicity assay compared with in vivo data obtained using skin bioengineering methods) and in vivo moisturizing capacity (bioengineering of the skin). In order to investigate possible interactions between APG mild natural emulsifier-based emulsion and LA, a deeper insight into the colloidal structure of the placebo and the emulsion with LA was given using polarization and transmission electron microscopy, rheology, thermal and texture analysis. This study showed that APG-based emulsions could be promoted as safe cosmetic/dermopharmaceutical vehicles and carriers for extremely acidic and hygroscopic AHA class of actives (specifically LA); prospective safety for human use of both APG and LA with the correlation between in vivo and in vitro findings was shown. However, it was revealed that LA strongly influenced the colloidal structure of the emulsion based on APGs and promoted the formation of lamellar structures which reflects onto the mode of water distribution within the cream. The advantageous skin hydrating potential of LA-containing emulsion vs. placebo was unlikely to be achieved, pointing that emulsions stabilized by lamellar liquid crystalline structures probably are not satisfying carriers for highly hygroscopic actives in order to reach the full moisturizing potential. Safe and effective use on dry skin is presumed. PMID

  20. Liquid membrane extraction of cadmium

    SciTech Connect

    Berends, A.M.; Breembroek, G.R.M.; Witkamp, G.J.; Rosmalen, G.M van

    1996-12-31

    Three Liquid Membrane extraction designs are compared by their experimental extraction performance of cadmium ions from an aqueous phase with tri-laurylamine dissolved in an aliphatic kerosene. The compared designs are Emulsion Liquid Membrane (ELM), Flat Sheet Supported Liquid Membrane (FSSLM) and Hollow Fiber Supported Liquid Membrane (HFSLM4) extraction units. The results demonstrated that ELM possesses the best extraction performance per volume of equipment, but that HFSLM is a good alternative because of its less complicated design and greater flexibility. 2 refs., 7 figs.

  1. Emulsions stabilised by whey protein microgel particles: towards food-grade Pickering emulsions.

    PubMed

    Destribats, Mathieu; Rouvet, Martine; Gehin-Delval, Cécile; Schmitt, Christophe; Binks, Bernard P

    2014-09-28

    We have investigated a new class of food-grade particles, whey protein microgels, as stabilisers of triglyceride-water emulsions. The sub-micron particles stabilized oil-in-water emulsions at all pH with and without salt. All emulsions creamed but exhibited exceptional resistance to coalescence. Clear correlations exist between the properties of the microgels in aqueous dispersion and the resulting emulsion characteristics. For conditions in which the particles were uncharged, fluid emulsions with relatively large drops were stabilised, whereas emulsions stabilized by charged particles contained smaller flocculated drops. A combination of optical microscopy of the drops and spectrophotometry of the resolved aqueous phase allowed us to estimate the interfacial adsorption densities of the particles using the phenomenon of limited coalescence. We deduce two classes of particle arrangement. Complete adsorption of the particles was obtained when they were neutral or when their charges were screened by salt resulting in at least one particle monolayer at the interface. By contrast, only around 50% of the particles adsorbed when they were charged with emulsion drops being covered by less than half a monolayer. These findings were supported by direct visualization of drop interfaces using cryo-scanning electron microscopy. Uncharged particles were highly aggregated and formed a continuous 2-D network at the interface. Otherwise particles organized as individual aggregates separated by particle-free regions. In this case, we suggest that some particles spread at the interface leading to the formation of a continuous protein membrane. Charged particles displayed the ability to bridge opposing interfaces of neighbouring drops to form dense particle disks protecting drops against coalescence; this is the main reason for the flocculation and stability of emulsions containing sparsely covered drops. PMID:24675994

  2. Phase inversion of ionomer-stabilized emulsions to form high internal phase emulsions (HIPEs).

    PubMed

    Zhang, Tao; Xu, Zhiguang; Cai, Zengxiao; Guo, Qipeng

    2015-06-28

    Herein, we report the phase inversion of ionomer-stabilized emulsions to form high internal phase emulsions (HIPEs) induced by salt concentration and pH changes. The ionomers are sulfonated polystyrenes (SPSs) with different sulfonation degrees. The emulsion types were determined by conductivity measurements, confocal microscopy and optical microscopy, and the formation of HIPE organogels was verified by the tube-inversion method and rheological measurements. SPSs with high sulfonation degrees (water-soluble) and low sulfonation degrees (water-insoluble) can stabilize oil-in-water emulsions; these emulsions were transformed into water-in-oil HIPEs by varying salt concentrations and/or changing the pH. SPS, with a sulfonation degree of 11.6%, is the most efficient, and as low as 0.2 (w/v)% of the organic phase is enough to stabilize the HIPEs. Phase inversion of the oil-in-water emulsions occurred to form water-in-oil HIPEs by increasing the salt concentration in the aqueous phase. Two phase inversion points from oil-in-water emulsions to water-in-oil HIPEs were observed at pH 1 and 13. Moreover, synergetic effects between the salt concentration and pH changes occurred upon the inversion of the emulsion type. The organic phase can be a variety of organic solvents, including toluene, xylene, chloroform, dichloroethane, dichloromethane and anisole, as well as monomers such as styrene, butyl acrylate, methyl methacrylate and ethylene glycol dimethacrylate. Poly(HIPEs) were successfully prepared by the polymerization of monomers as the continuous phase in the ionomer-stabilized HIPEs. PMID:26028420

  3. Nuclear Emulsion - Skylab Experiment S009

    NASA Technical Reports Server (NTRS)

    1970-01-01

    This photograph shows Skylab's Nuclear Emulsion experiment, a Skylab science facility that was mounted inside the Multiple Docking Adapter used to record the relative abundance of primary, high-energy heavy nuclei outside the Earth's atmosphere. The Marshall Space Flight Center had program management responsibility for the development of Skylab hardware and experiments.

  4. Surface active agent for emulsion fuel

    SciTech Connect

    Aoki, Y.; Furuyama, Y.; Moriyama, N.

    1980-01-08

    A method is claimed for preparing a water-in-oil emulsion fuel which comprises emulsifying water in oil, in the presence of an emulsifying agency. The improvement comprises using as the emulsifying agent, a surfactant. The formula of this surfactant is presented.

  5. Probing Interfacial Emulsion Stability Controls using Electrorheology

    NASA Astrophysics Data System (ADS)

    Wang, Xiuyu; Brandvik, Amy; Alvarado, Vladimir

    2010-11-01

    The stability of water-in-oil emulsions is controlled by interfacial mechanisms that include oil film rheology of approaching drops and the strength of drop interfaces. Film drainage is mainly a function of the continuous phase rheology. Temperature is used to regulate the viscosity of the continuous phase and hence determine its effect on emulsion stability through film drainage, in contrast with interfacial strength. In this study, one crude oil is used to formulate water-in-oil emulsions. Oil-water interfacial tension is measured to gauge other interfacial changes with temperature. The critical field value, used as proxy of emulsion stability, approaches a plateau value for each crude oil- aqueous solution pair, at sufficiently high temperature (50 ^oC), which is interpreted to reflect the intrinsic drop-coating film resistance to coalescence. Interfacial tension does vary significantly with either aqueous phase composition or temperature. From comparison with previous results, we speculate that drop coating film is composed of a fraction of asphaltic compunds.

  6. Radiation dosimetry and spectrometry with superheated emulsions

    NASA Astrophysics Data System (ADS)

    d'Errico, Francesco

    2001-09-01

    Detectors based on emulsions of overexpanded halocarbon droplets in tissue equivalent aqueous gels or soft polymers, known as "superheated drop detectors" or "bubble (damage) detectors", have been used in radiation detection, dosimetry and spectrometry for over two decades. Recent technological advances have led to the introduction of several instruments for individual and area monitoring: passive integrating meters based on the optical or volumetric registration of the bubbles, and active counters detecting bubble nucleations acoustically. These advances in the instrumentation have been matched by the progress made in the production of stable and well-specified emulsions of superheated droplets. A variety of halocarbons are employed in the formulation of the detectors, and this permits a wide range of applications. In particular, halocarbons with a moderate degree of superheat, i.e. a relatively small difference between their operating temperature and boiling point, can be used in neutron dosimetry and spectrometry since they are only nucleated by energetic heavy ions such as those produced by fast neutrons. More recently, halocarbons with an elevated degree of superheat have been utilised to produce emulsions that nucleate with much smaller energy deposition and detect low linear energy transfer radiations, such as photons and electrons. This paper reviews the detector physics of superheated emulsions and their applications in radiation measurements, particularly in neutron dosimetry and spectrometry.

  7. Particle-Stabilized Powdered Water-in-Oil Emulsions.

    PubMed

    Binks, Bernard P; Tyowua, Andrew T

    2016-04-01

    The preparation of powdered water-in-oil (w/o) emulsions by gentle aeration of w/o emulsions stabilized by hydrophobic fumed silica particles in the presence of oleophobic fluorinated clay particles is reported for an alkane and a triglyceride oil. The resultant powders consist of water drops dispersed in oil globules themselves dispersed in air (w/o/a). They contain ∼80 wt % of the precursor w/o emulsion and were stable to phase separation for over 1 year but release oil and water when sheared on a substrate. Above a certain ratio of w/o emulsion:fluorinated clay particles, the powdered emulsions partially invert to an emulsion paste, composed of air bubbles and water droplets dispersed in oil. The tap density and angle of repose of the powdered emulsions were measured and compared with those of the corresponding powdered oils making up the continuous phase of the precursor emulsions. The contact angles of water droplets under oil on glass slides spin coated with silica particles and oil drops and w/o emulsion droplets in air on compressed disks of fluorinated clay particles are consistent with the stabilization of w/o emulsions and powdered emulsions, respectively. PMID:27002604

  8. Pickering w/o emulsions: drug release and topical delivery.

    PubMed

    Frelichowska, Justyna; Bolzinger, Marie-Alexandrine; Valour, Jean-Pierre; Mouaziz, Hanna; Pelletier, Jocelyne; Chevalier, Yves

    2009-02-23

    The skin absorption from Pickering emulsions as a new dosage form was investigated for the first time. Pickering emulsions are stabilized by adsorbed solid particles instead of emulsifier molecules. They are promising dosage forms that significantly differ from classical emulsions within several features. The skin permeation of a hydrophilic model penetrant (caffeine) was investigated from a w/o Pickering emulsion and compared to a w/o classical emulsion stabilized with an emulsifier. Both emulsions had the same composition and physicochemical properties in order to focus on the effect of the interfacial layer on the drug release and skin absorption processes. The highest permeation rates were obtained from the Pickering emulsion with a pseudo-steady state flux of 25 microg cm(-2)h(-1), threefold higher than from a classical emulsion (9.7 microg cm(-2)h(-1)). After 24h exposure, caffeine was mostly in the receptor fluid and in the dermis; cumulated amounts of caffeine were higher for the Pickering emulsion. Several physicochemical phenomena were investigated for clearing up the mechanisms of enhanced permeation from the Pickering emulsion. Among them, higher adhesion of Pickering emulsion droplets to skin surface was disclosed. The transport of caffeine adsorbed on silica particles was also considered relevant since skin stripping showed that aggregates of silica particles entered deeply the stratum corneum. PMID:18992799

  9. Characteristics of Nano-emulsion for Cold Thermal Storage

    NASA Astrophysics Data System (ADS)

    Fumoto, Koji; Kawaji, Masahiro; Kawanami, Tsuyoshi

    Phase change emulsion (PCE) is novel kind of heat storage and heat transfer fluids. It has characteristics as follows; greater apparent specific heat and higher heat transfer abilities in the phase change temperature range than conventional single phase heat transfer fluid. In this paper, a phase change emulsion, which has droplet diameter distribution of nanometer, were prepared. The Nano-emulsion was formed by low energy emulsification methods, as known the phase inversion temperature (PIT) method. Physical properties, such as viscosity, diameter and its distribution of emulsion were investigated. Especially, the relationships between preparation method and the concentration of surfactant have been discussed in detail. The results show that the viscosity of the Nano-emulsion is lower than the micro-emulsion, which was made by same mixing ratio of surfactant and concentration of phase change material. In addition, the Nano-emulsion clarified that stability was higher than microemulsions.

  10. [The enhancement effect of emulsion in flame atomic absorption spectrometry].

    PubMed

    Liu, Li-hang; Shen, Chun-yu

    2002-08-01

    A enhancement method of FAAS with emulsion as enhancement agent has been developed. The enhancement effect of emulsion made of three organic solvents (benzene, benzene-propanone, xylene), one organic reagent (dibutyl phthalate) and three emulsifiers (Tween-80, Triton X-100, OP) for iron, nickel, zinc, manganese and lead was studied. The results indicated that the enhancement is satisfactory. The emulsion with maximum enhancement percentage are respectively emulsion of benzene-OP-dibutyl phthalate with 89%, emulsion of xylene-Trition-100-dibutyl phthal with 34%, emulsion of benzene-Trition-100 with 121%, emulsion of benzene-Trition-100-dibutyl phthalate with 38% and 69% in sequence of the above elements. PMID:12938401

  11. Improved Capacitive Liquid Sensor

    NASA Technical Reports Server (NTRS)

    Waldman, Francis A.

    1992-01-01

    Improved capacitive sensor used to detect presence and/or measure thickness of layer of liquid. Electrical impedance or admittance of sensor measured at prescribed frequency, and thickness of liquid inferred from predetermined theoretical or experimental relationship between impedance and thickness. Sensor is basically a three-terminal device. Features interdigitated driving and sensing electrodes and peripheral coplanar ground electrode that reduces parasitic effects. Patent-pending because first to utilize ground plane as "shunting" electrode. System less expensive than infrared, microwave, or refractive-index systems. Sensor successfully evaluated in commercial production plants to characterize emulsions, slurries, and solutions.

  12. Wettability modification of rock cores by fluorinated copolymer emulsion for the enhancement of gas and oil recovery

    NASA Astrophysics Data System (ADS)

    Feng, Chunyan; Kong, Ying; Jiang, Guancheng; Yang, Jinrong; Pu, Chunsheng; Zhang, Yuzhong

    2012-07-01

    The fluorine-containing acrylate copolymer emulsion was prepared with butyl acrylate, methacrylic acid and 1H, 1H, 2H, 2H-perfluorooctyl acrylate as monomers. Moreover, the structure of the copolymer was verified by Fourier transform infrared (FTIR), nuclear magnetic resonance (1H NMR and 19F NMR) and X-ray photoelectron spectroscopy (XPS) analyses. The results showed that all the monomers had been copolymerized and the presence of fluorine moieties. The contact angle (CA) analyses, capillary rise and imbibition spontaneous tests were used to estimate the influence of the copolymer emulsion on the wettability of gas reservoirs. It was observed that the rock surface was of large contact angles of water, oilfield sewage, hexadecane and crude oil after treatment with the emulsion. The capillary rise results indicated that the contact angles of water/air and oil/air systems increased from 60° and 32° to 121° and 80°, respectively, due to the emulsion treatment. Similarly, because of wettability alteration by the fluoropolymer, the imbibition of water and oil in rock core decreased significantly. Experimental results demonstrated that the copolymer emulsion can alter the wettability of porous media from strong liquid-wetting to gas-wetting. This work provides a cost-effective method to prepare the fluoropolymer which can increase gas deliverability by altering the wettability of gas-condensate reservoirs and mitigating the water block effect.

  13. Showing Emulsion Properties with Common Dairy Foods

    NASA Astrophysics Data System (ADS)

    Bravo-Diaz, Carlos; Gonzalez-Romero, Elisa

    1996-09-01

    Foods are mixtures of different chemical compounds, and the quality we sense (taste, texture, color, etc.) are all manifestations of its chemical properties. Some of them can be visualized with the aid of simple, safe and inexpensive experiments using dairy products that can be found in any kitchen and using almost exclusively kitchen utensils. In this paper we propose some of them related with food emulsions. Food emulsions cover an extremely wide area of daily-life applications such as milk, sauces, dressings and beverages. Experimentation with some culinary recipes to prepare them and the analyisis of the observed results is close to ideal subject for the introduction of chemical principles, allowing to discuss about the nature and composition of foods, the effects of additives, etc. At the same time it allows to get insights into the scientific reasons that underlie on the recipes (something that it is not usually found in most cookbooks). For example, when making an emulsion like mayonnaise, why the egg yolks and water are the first materials in the bowl , and the oil is added to them rather than in the other way around? How you can "rescue" separate emulsions (mayonnaise)? Which parameters affect emulsion stability? Since safety, in its broad sense, is the first requisite for any food, concerns about food exist throughout the world and the more we are aware of our everyday life, the more likely we will be to deal productively with the consequences. On the other hand, understanding what foods are and how cooking works destroys no delightful mystery of the art of cuisine, instead the mystery expands.

  14. Shear flow behaviour and emulsion-stabilizing effect of natural polysaccharide-protein gum in aqueous system and oil/water (O/W) emulsion.

    PubMed

    Amid, Bahareh Tabatabaee; Mirhosseini, Hamed

    2013-03-01

    The main objective of the current work was to characterize the shear rheological flow behaviour and emulsifying properties of the natural biopolymer from durian seed. The present study revealed that the extraction condition significantly affected the physical and functional characteristics of the natural biopolymer from durian seed. The dynamic oscillatory test indicated that the biopolymer from durian seed showed more gel (or solid) like behaviour than the viscous (or liquid) like behaviour (G'>G″) at a relatively high concentration (20%) in the fixed frequency (0.1 Hz). This might be explained by the fact that the gum coils disentangle at low frequencies during the long period of oscillation, thus resulting in more gel like behaviour than the viscous like behaviour. The average droplet size of oil in water (O/W) emulsions stabilized by durian seed gum significantly varied from 0.42 to 7.48 μm. The results indicated that O/W emulsions showed significant different stability after 4 months storage. This might be interpreted by the considerable effect of the extraction condition on the chemical and molecular structure of the biopolymer, thus affecting its emulsifying capacity. The biopolymer extracted by using low water to seed (W/S) ratio at the low temperature under the alkaline condition showed a relatively high emulsifying activity in O/W emulsion. PMID:23261563

  15. Campus Child Care News, 1998.

    ERIC Educational Resources Information Center

    Newton, Marion F., Ed.

    1998-01-01

    This document is comprised of the three 1998 issues of a newsletter disseminating information on the National Coalition for Campus Child Care Centers (NCCCC) and providing a forum for news, research, and information concerning campus child care centers. The February issue contains stories on the White House Conference on Child Care, registration…

  16. Broadcast News: An Interdisciplinary Project.

    ERIC Educational Resources Information Center

    Nielsen, Carol; Sassi, Brenda

    Fourth graders in the Meroby School, Mexico, Maine, produce a weekly news program that is transmitted to all classrooms via closed circuit television. The classroom teacher is in charge of day-to-day preparation, working on the writing and the necessary skills with students. Teachers and students use their creativity to come up with new…

  17. Science News of the Year.

    ERIC Educational Resources Information Center

    Science News, 1985

    1985-01-01

    Highlights important 1985 science stories appearing in "Science News" under these headings: anthropology and paleontology, astronomy, behavior, biology, biomedicine, chemistry, computers and mathematics, earth sciences, environment, physics, science and society, space sciences, and technology. Each entry includes the volume and page number in…

  18. Guess Who's in the News.

    ERIC Educational Resources Information Center

    Wassom, Julie

    1996-01-01

    Examines the power of positive publicity as cost-effective child-care marketing. Suggests that getting positive press can make marketing easier, less expensive, and fun. Notes that by creating news stories and developing a working relationship with targeted media, child-care-center directors can inform, educate, and create new prospects and…

  19. Science News of the Year

    ERIC Educational Resources Information Center

    Science News, 1974

    1974-01-01

    Presents a review of important science articles of 1974 as reported in the pages of "Science News." References are given relating to the volume and page number in which the main article appeared. Life-sciences, physical sciences, earth science, environmental science, humanities and technology research are reviewed. (EB)

  20. How to Tell Bad News

    ERIC Educational Resources Information Center

    Long, Nicholas J.

    2012-01-01

    Therapists, physicians, police officers, and emergency staff often are the messengers of bad news. They have to tell a patient, a parent, or a loved one about a death, an accident, a school shooting, a life-threatening diagnosis, a terrorist attack, or a suicide. Usually the messenger bears a heavy responsibility but has little training and seeks…

  1. Capillary interactions in Pickering emulsions

    NASA Astrophysics Data System (ADS)

    Guzowski, J.; Tasinkevych, M.; Dietrich, S.

    2011-09-01

    The effective capillary interaction potentials for small colloidal particles trapped at the surface of liquid droplets are calculated analytically. Pair potentials between capillary monopoles and dipoles, corresponding to particles floating on a droplet with a fixed center of mass and subjected to external forces and torques, respectively, exhibit a repulsion at large angular separations and an attraction at smaller separations, with the latter resembling the typical behavior for flat interfaces. This change of character is not observed for quadrupoles, corresponding to free particles on a mechanically isolated droplet. The analytical results are compared with the numerical minimization of the surface free energy of the droplet in the presence of spherical or ellipsoidal particles.

  2. Temporal and Cross Correlations in Business News

    NASA Astrophysics Data System (ADS)

    Mizuno, T.; Takei, K.; Ohnishi, T.; Watanabe, T.

    We empirically investigate temporal and cross correlations inthe frequency of news reports on companies, using a dataset of more than 100 million news articles reported in English by around 500 press agencies worldwide for the period 2003--2009. Our first finding is that the frequency of news reports on a company does not follow a Poisson process, but instead exhibits long memory with a positive autocorrelation for longer than one year. The second finding is that there exist significant correlations in the frequency of news across companies. Specifically, on a daily time scale or longer the frequency of news is governed by external dynamics, while on a time scale of minutes it is governed by internal dynamics. These two findings indicate that the frequency of news reports on companies has statistical properties similar to trading volume or price volatility in stock markets, suggesting that the flow of information through company news plays an important role in price dynamics in stock markets.

  3. Measuring Interfacial Tension Between Immiscible Liquids

    NASA Technical Reports Server (NTRS)

    Rashidnia, Nasser; Balasubramaniam, R.; Delsignore, David M.

    1995-01-01

    Glass capillary tube technique measures interfacial tension between two immiscible liquids. Yields useful data over fairly wide range of interfacial tensions, both for pairs of liquids having equal densities and pairs of liquids having unequal densities. Data on interfacial tensions important in diverse industrial chemical applications, including enhanced extraction of oil; printing; processing foods; and manufacture of paper, emulsions, foams, aerosols, detergents, gel encapsulants, coating materials, fertilizers, pesticides, and cosmetics.

  4. Emulsion properties of casein and whey protein hydrolysates and the relation with other hydrolysate characteristics.

    PubMed

    van der Ven, C; Gruppen, H; de Bont, D B; Voragen, A G

    2001-10-01

    Casein and whey protein were hydrolyzed using 11 different commercially available enzyme preparations. Emulsion-forming ability and emulsion stability of the digests were measured as well as biochemical properties with the objective to study the relations between hydrolysate characteristics and emulsion properties. All whey protein hydrolysates formed emulsions with bimodal droplet size distributions, signifying poor emulsion-forming ability. Emulsion-forming ability of some casein hydrolysates was comparable to that of intact casein. Emulsion instability was caused by creaming and coalescence. Creaming occurred mainly in whey hydrolysate emulsions and in casein hydrolysate emulsions containing large emulsion droplets. Coalescence was dominant in casein emulsions with a broad particle size distribution. Emulsion instability due to coalescence was related to apparent molecular weight distribution of hydrolysates; a relative high amount of peptides larger than 2 kDa positively influences emulsion stability. PMID:11600059

  5. Liquid Crystalline Microemulsions

    NASA Astrophysics Data System (ADS)

    Huang, Chien-Yueh; Petschek, Rolfe G.

    2000-03-01

    If an isotropic component of an emulsion is replaced by one having liquid crystalline (e.g. nematic) order the equilibrium behavior can change dramatically. There are long range enthalpic effects which can result in either repulsive or attractive interactions between the surfaces of an emulsion and entropic effects which generally result in an attractive interaction between these surfaces. We review briefly the possibility of stable blue-phase like microemulsions in mixtures of chiral nematics, appropriate surfactants and an incompatible isotropic solvent. We discuss the entropic effects in a lamellar phase, including the effects of changes in elastic constants and surface-nematic coupling. The effects of fluctuations on blue phases will be briefly discussed.

  6. News and Announcements

    NASA Astrophysics Data System (ADS)

    1999-05-01

    and faithful supporter of this Journal, died February 25, 1999, at his home in Lafayette, California, at the age of 86. At the Fall 1998 ACS Meeting in Boston he suffered a serious fall following a stroke, from which he never recovered. One of his last photographs, taken the previous day at a Journal luncheon, appears on page 1360 of the November 1998 issue. His commentary on his long career in chemistry and education appears on page 1520 of the December 1998 issue. Seaborg was a Nobel laureate, discoverer of elements, scientific advisor to presidents, former chancellor of the University of California, former chairman of the Atomic Energy Commission, chairman of the steering committee of the CHEM Study project, founder of Lawrence Hall of Science, , the list goes on and on. He was at the same time a passionate supporter of education. Seaborg published fourteen articles in the Journal between 1951 and 1998. He was interviewed in 1975 by David Ridgway as part of the Impact series (JCE 1975, 52, 70), and that interview is highly recommended reading (see supplement to this article). He received the 1994 ACS George C. Pimentel Award in Chemical Education; his award address was published in the ACS Division of Chemical Education's CHED Newsletter, Fall 1995. Memorial articles with details of his life and his scientific contributions have appeared in The New York Times (Saturday, February 27, 1999, page 1) and Chemical & Engineering News (March 8, 1999, page 29). But there is also the spirit of the man, what he believed in, what he tried to do, what he hoped he had accomplished. A sense of that can be gained from the excerpts that are reprinted below, taken first from the Impact interview and then from the award address. Ridgway: On reflection, now, out of your many contributions to chemistry, is there one that you feel has had more of an impact than others? Seaborg: The discovery of plutonium would answer that question. The impact th

  7. News and Announcements

    NASA Astrophysics Data System (ADS)

    1999-02-01

    News from Journal House Conceptual Questions and Challenge Problems Many readers are trying to modify the way they teach and in so doing are trying to write new types of questions and problems. The Journal has a new online resource, the JCE Internet Conceptual Questions and Challenge Problems Web site, http://jchemed.chem.wisc.edu/JCEWWW/Resources/CQandChP/index.html . The site is a source of questions and problems that can be used in teaching and assessing conceptual understanding and problem solving in chemistry. Here you can find a library of free-response and multiple-choice conceptual questions and challenge problems, tips for writing these questions and problems, and a discussion of types of concept questions. This site is intended to be a means of sharing conceptual questions and challenge problems among chemical educators. It will be as inclusive as possible, and to achieve this readers need to share their questions and alert the authors to references or Web sites. The screen captures shown below should provide a feeling for what you will find when you visit the site. The authors, William R. Robinson and Susan C. Nurrenbern, welcome additions to the library of conceptual questions or other comments or suggestions. Contact them by email, fax, or regular mail. William R. Robinson and Susan C. Nurrenbern, Department of Chemistry, Purdue University, West Lafayette, IN 47907-1393. Bill: phone: 765/494-5453; fax: 765/494-0239; email: wrrobin@purdue.edu. Sue: phone: 765/494-0823; fax: 765/494-0239; email: nurrenbe@purdue.edu. fax: 765/494-0239. 1998 Ford Foundation Fellowships The National Research Council has announced the recipients of the 1998 fellowships for minority scholars. Three categories of fellowships were awarded: 50 to beginning graduate students, 33 to students writing their dissertations, and 28 to recent Ph.D. recipients. There were about 1,000 applicants. For information about the next competition contact the Fellowship Office of the National

  8. The simulation of the response of superheated emulsion to alpha particles

    NASA Astrophysics Data System (ADS)

    Seth, Susnata; Das, Mala

    2016-04-01

    The response of superheated emulsion of liquid perfluorobutane (C4F10; b.p.: ‑1.7o C) to alpha particle has been studied by performing the simulation using GEANT3.21 toolkit. The simulations have been performed to generate two different experimental situations. In one case, the alpha contamination is present only in polymer and in another case, the alpha contamination is present both in polymer and active liquid. The value of the nucleation parameter, k, for bubble nucleation induced by alpha particle in superheated emulsion detector is determined by comparing the simulated normalized count rates with the available experimental results. The results show that the nucleation parameter for alpha particle in C4F10 liquid is about 0.19. The energy and position of alpha particle are not able to change the response of the alpha particle in C4F10 liquid. The recoiling nuclei associated with the alpha decay chain are responsible for making the detector sensitive at lower threshold temperatures.

  9. Crocin loaded nano-emulsions: Factors affecting emulsion properties in spontaneous emulsification.

    PubMed

    Mehrnia, Mohammad-Amin; Jafari, Seid-Mahdi; Makhmal-Zadeh, Behzad S; Maghsoudlou, Yahya

    2016-03-01

    Spontaneous emulsification may be used for encapsulating bioactive compounds in food and pharmaceutical industry. It has several advantages over high energy and other low energy methods including, protecting sensitive compounds against severe conditions of high energy method and its ability to minimize surfactant, removal of cosurfactant and thermal stability compared with other low energy methods. In this study, we examined possibility of encapsulating highly soluble crocin in W/O micro-emulsions using spontaneous method which further could be used for making double emulsions. Nonionic surfactants of Span 80 and polyglycerol polyricinoleate (PGPR) were used for making micro-emulsions that showed the high potential of PGPR for spontaneous method. Surfactant to water ratio (SWR%) was evaluated to find the highest amount of aqueous phase which can be dispersed in organic phase. Droplet size decreased by increasing SWR toward the SWR=100% which had the smallest droplet size and then increased at higher levels of surfactant. By increasing SWR, shear viscosity increased which showed the high effect of PGPR on rheological properties. This study shows in addition to W/O micro-emulsions, spontaneous method could be used for preparing stable O/W micro-emulsions. PMID:26708427

  10. Ultrasonication-assisted preparation and characterization of emulsions and emulsion gels for topical drug delivery.

    PubMed

    Singh, Vinay K; Behera, Baikuntha; Pramanik, Krishna; Pal, Kunal

    2015-03-01

    The current study describes the use of ultrasonication for the preparation of biphasic emulsions and emulsion gels for topical drug delivery. Sorbitan monostearate (SMS) was used as the surfactant for stabilizing the interface of sesame oil (apolar phase) and water (polar phase). Emulsions were formed at lower concentrations of SMS, whereas emulsion gels were formed at higher concentrations of SMS. The formulations were characterized by fluorescent microscopy, X-ray diffraction, viscosity, stress relaxation, spreadability, and differential scanning calorimetry studies. Fluorescence microscopy suggested formation of oil-in-water type of formulations. There was an increase in the viscosity, bulk resistance, and firmness of the formulations as the proportions of SMS was increased. The emulsion gels were viscoelastic in nature. Thermal studies suggested higher thermodynamic stability at higher proportions of either SMS or water. Metronidazole, a model antimicrobial drug, was incorporated within the formulations. The release of the drug from the formulations was found to be diffusion mediated. The drug-loaded formulations showed sufficient antimicrobial efficiency to be used as carriers for topical antimicrobial drug delivery. PMID:25470664

  11. Emulsion characteristics, chemical and textural properties of meat systems produced with double emulsions as beef fat replacers.

    PubMed

    Serdaroğlu, Meltem; Öztürk, Burcu; Urgu, Müge

    2016-07-01

    In recent years, double emulsions are stated to have a promising potential in low-fat food production, however, there are very few studies on their possible applications in meat matrices. We aimed to investigate the quality of beef emulsion systems in which beef fat was totally replaced by double emulsions (W1/O/W2) prepared with olive oil and sodium caseinate (SC) by two-step emulsification procedure. Incorporation of W1/O/W2 emulsion resulted in reduced lipid, increased protein content, and modified fatty acid composition. W1/O/W2 emulsion treatments had lower jelly and fat separation, higher water-holding capacity and higher emulsion stability than control samples with beef fat. Increased concentrations of W1/O/W2 emulsions resulted in significant changes in texture parameters. TBA values were lower in W1/O/W2 emulsion treatments than control treatment after 60days of storage. In conclusion, our study confirms that double emulsions had promising impacts on modifying fatty acid composition and developing both technologically and oxidatively stable beef emulsion systems. PMID:26995773

  12. A comparative study of the physicochemical properties of a virgin coconut oil emulsion and commercial food supplement emulsions.

    PubMed

    Khor, Yih Phing; Koh, Soo Peng; Long, Kamariah; Long, Shariah; Ahmad, Sharifah Zarah Syed; Tan, Chin Ping

    2014-01-01

    Food manufacturers are interested in developing emulsion-based products into nutritional foods by using beneficial oils, such as fish oil and virgin coconut oil (VCO). In this study, the physicochemical properties of a VCO oil-in-water emulsion was investigated and compared to other commercial oil-in-water emulsion products (C1, C2, C3, and C4). C3 exhibited the smallest droplet size of 3.25 µm. The pH for the emulsion samples ranged from 2.52 to 4.38 and thus were categorised as acidic. In a texture analysis, C2 was described as the most firm, very adhesive and cohesive, as well as having high compressibility properties. From a rheological viewpoint, all the emulsion samples exhibited non-Newtonian behaviour, which manifested as a shear-thinning property. The G'G'' crossover illustrated by the VCO emulsion in the amplitude sweep graph but not the other commercial samples illustrated that the VCO emulsion had a better mouthfeel. In this context, the VCO emulsion yielded the highest zeta potential (64.86 mV), which was attributed to its strong repulsive forces, leading to a good dispersion system. C2 comprised the highest percentage of fat among all emulsion samples, followed by the VCO emulsion, with 18.44% and 6.59%, respectively. PMID:24988188

  13. Heavy crude oils/particle stabilized emulsions.

    PubMed

    Kralova, Iva; Sjöblom, Johan; Øye, Gisle; Simon, Sébastien; Grimes, Brian A; Paso, Kristofer

    2011-12-12

    Fluid characterization is a key technology for success in process design for crude oil mixtures in the future offshore. In the present article modern methods have been developed and optimized for crude oil applications. The focus is on destabilization processes in w/o emulsions, such as creaming/sedimentation and flocculation/coalescence. In our work, the separation technology was based on improvement of current devices to promote coalescence of the emulsified systems. Stabilizing properties based on particles was given special attention. A variety of particles like silica nanoparticles (AEROSIL®), asphalthenes, wax (paraffin) were used. The behavior of these particles and corresponding emulsion systems was determined by use of modern analytical equipment, such as SARA fractionation, NIR, electro-coalescers (determine critical electric field), Langmuir technique, pedant drop technique, TG-QCM, AFM. PMID:22047991

  14. Analytical applications of emulsions and microemulsions.

    PubMed

    Burguera, José Luis; Burguera, Marcela

    2012-07-15

    Dispersion systems like emulsions and microemulsions are able to solubilize both polar and non-polar substances due to the special arrangement of the oil and aqueous phases. The main advantages of using emulsions or microemulsions in analytical chemistry are that they do not require the previous destruction of the sample matrix or the use of organic solvents as diluents, and behave similarly to aqueous solutions, frequently allowing the use of aqueous standard solutions for calibration. However, it appears that there are many contradictory concepts and misunderstandings often related to terms definition when referring to such systems. The main aim of this review is to outline the differences between these two aggregates and to give an overview of the most recent advances on their analytical applications with emphasis on the potentiality of the on-line emulsification processes. PMID:22817921

  15. OPERA experiment and its releted emulsion techniques

    SciTech Connect

    Ariga, Akitaka

    2008-02-21

    The OPERA experiment is designed to clarify neutrino oscillation by detecting appearance of {nu}{sub {tau}} in pure {nu}{sub {mu}} beam through a long baseline method (CNGS beam from cern to the Gran Sasso laboratory). The key technique is the use of emulsion films and their scanning. We developed a new high speed scanning system with speed of 50 cm{sup 2}/h and it was successfully demonstrated in 2006 CNGS commissioning. The new scanning system is not only meant for the OPERA experiment, but it has large potential of applications. For example, measurement of {nu}{sub e} with strong separation power against {pi}{sup 0}. Or a compact emulsion spectrometer for future neutrino experiments.

  16. How to Write News for Broadcast and Print Media.

    ERIC Educational Resources Information Center

    Dary, David

    This book is a primer on the techniques of news writing and the application of those principles to print and broadcast journalism. Chapters include: "The News Media," which presents a brief history of journalism and the foundations on which it is based; "What Is News?"; "Gathering News," which discusses news beats, reporters' qualifications, and…

  17. To Kill a Messenger; Television News and the Real World.

    ERIC Educational Resources Information Center

    Small, William

    From his vantage point as News Director of CBS News in Washington, the author examines the role of television news in our society and gives an insider's view of the day-to-day process of selecting and presenting news. Highlighting the book are in-depth discussions of past and recent news events. The Nixon "Checkers" speech, John Kennedy's fight to…

  18. Large area emulsion chamber experiments for the Space Shuttle

    NASA Technical Reports Server (NTRS)

    Parnell, T. A.

    1985-01-01

    Emulsion-chamber experiments employing nuclear-track emulsions, etchable plastic detectors, metal plates, and X-ray films continue to demonstrate high productivity and potential in the study of cosmic-ray primaries and their interactions. Emulsions, with unsurpassed track-recording capability, provide an appropriate medium for the study of nucleus-nucleus interactions at high energy, which will likely produce observations of a phase change in nuclear matter. The many advantages of emulsion chambers (excellent multitrack recording capability, large geometry factor, low apparatus cost, simplicity of design and construction) are complemented by the major advantages of the Space Shuttle as an experiment carrier. A Shuttle experiment which could make a significant advance in both cosmic-ray primary and nucleus-nucleus interaction studies is described. Such an experiment would serve as a guide for use of emulsions during the Space Station era. Some practical factors that must be considered in planning a Shuttle exposure of emulsion chambers are discussed.

  19. Turbulent flow of oil-water emulsions with polymer additives

    NASA Astrophysics Data System (ADS)

    Manzhai, V. N.; Monkam Clovis Le Grand, Monkam; Abdousaliamov, A. V.

    2014-08-01

    The article outlines direct and reverse oil-water emulsions. Microphotography study of these emulsions was carried out. The effect of water-soluble and oil soluble polymers on the emulsion structure and their turbulent flow velocity in cylindrical channel was investigated. It has been experimentally proven that if the fluid being transported is not homogeneous, but a two-phase oil-water emulsion, only the polymer that is compatible with dispersion medium and capable of dissolving in this medium can reduce the hydrodynamic resistance of the fluid flow. Thus, the resistance in direct emulsions can be reduced by water- soluble polyacrylamide, while oil-soluble polyhexene can be applied for reverse emulsions.

  20. [Multiple emulsions; bioactive compounds and functional foods].

    PubMed

    Jiménez-Colmenero, Francisco

    2013-01-01

    The continued appearance of scientific evidence about the role of diet and/or its components in health and wellness, has favored the emergence of functional foods which currently constitute one of the chief factors driving the development of new products. The application of multiple emulsions opens new possibilities in the design and development of functional foods. Multiple emulsions can be used as an intermediate product (food ingredient) into technological strategies normally used in the optimization of the presence of bioactive compounds in healthy and functional foods. This paper presents a summary of the types, characteristics and formation of multiple emulsions, possible location of bioactive compounds and their potential application in the design and preparation of healthy and functional foods. Such applications are manifested particularly relevant in relation to quantitative and qualitative aspects of lipid material (reduced fat/calories and optimization of fatty acid profile), encapsulation of bioactive compounds mainly hydrophilic and sodium reduction. This strategy offers interesting possibilities regarding masking flavours and improving sensory characteristics of foods. PMID:24160194

  1. Lipid Emulsion for Local Anesthetic Systemic Toxicity

    PubMed Central

    Ciechanowicz, Sarah; Patil, Vinod

    2012-01-01

    The accidental overdose of local anesthetics may prove fatal. The commonly used amide local anesthetics have varying adverse effects on the myocardium, and beyond a certain dose all are capable of causing death. Local anesthetics are the most frequently used drugs amongst anesthetists and although uncommon, local anaesthetic systemic toxicity accounts for a high proportion of mortality, with local anaesthetic-induced cardiac arrest particularly resistant to standard resuscitation methods. Over the last decade, there has been convincing evidence of intravenous lipid emulsions as a rescue in local anesthetic-cardiotoxicity, and anesthetic organisations, over the globe have developed guidelines on the use of this drug. Despite this, awareness amongst practitioners appears to be lacking. All who use local anesthetics in their practice should have an appreciation of patients at high risk of toxicity, early symptoms and signs of toxicity, preventative measures when using local anesthetics, and the initial management of systemic toxicity with intravenous lipid emulsion. In this paper we intend to discuss the pharmacology and pathophysiology of local anesthetics and toxicity, and the rationale for lipid emulsion therapy. PMID:21969824

  2. Method for purifying solids-stabilized emulsions

    SciTech Connect

    Knowlton, H.E.

    1987-08-25

    A method is described for purifying oil contaminated with both solids and water capable of forming a solids-stabilized emulsion layer which comprises: (a) settling the contaminated oil essentially without agitation in a first vessel, at a temperature of between 50/sup 0/C and 95/sup 0/C, to form an upper partially purified oil layer, an intermediate first oil cuff layer including a solids-stabilized emulsion of oil and 5 to 80 weight percent of solids and water, and a lower first water layer, and withdrawing water from the first water layer; (b) settling the partially purified oil essentially without agitation in a second vessel, at a temperature of between 50/sup 0/C and 95/sup 0/C, to form an upper purified oil layer, an intermediate second oil cuff layer including a solids-stabilized emulsion of oil and 5 to 80 weight percent of solids and water, and a lower second water layer, and providing purified oil containing not more than 2 weight percent of solids and water from the purified oil layer; and (c) settling the intermediate first and second oil cuff layers essentially without agitation in a third vessel, at a temperature between 50/sup 0/C and 95/sup 0/C , to form an upper layer including oil and 5 to 80 weight percent of solids and water and a lower third water layer.

  3. STS-99 Crew News Conference

    NASA Technical Reports Server (NTRS)

    2000-01-01

    The Shuttle Crew (Mission Commander Kevin R. Kregel, Pilot Dominic L. Pudwill Gorie, Mission Specialists Janet L. Kavandi, Janice E. Voss, Mamoru Mohri, and Gerhard P.J. Thiele) are shown in a live news conference presenting the mission objectives of STS-99. The main objective is to obtain the most complete high-resolution digital topographic database of Earth. This project is named the Shuttle Radar Topography Mission (SRTM).

  4. Using the News: An Examination of the Value and Use of News Sources in CMC.

    ERIC Educational Resources Information Center

    Jones, Steve

    1997-01-01

    Investigates how members of a Usenet newsgroup value and use news sources. Finds that electronic news sources predominated and that media use was not tied to the user's geographic locale. Raises several questions for future research. (RS)

  5. Implicit Operational Definitions of Economic News Literacy in the Printed News Media.

    ERIC Educational Resources Information Center

    VanSickle, Ronald L.

    1981-01-01

    Describes study which focused on the economic vocabulary used in national and international news magazines and papers. Compares findings with definitions of economic literacy proposed by economists and suggests that economics courses include economic news literacy. (KC)

  6. News and Announcements

    NASA Astrophysics Data System (ADS)

    1999-02-01

    News from Journal House Conceptual Questions and Challenge Problems Many readers are trying to modify the way they teach and in so doing are trying to write new types of questions and problems. The Journal has a new online resource, the JCE Internet Conceptual Questions and Challenge Problems Web site, http://jchemed.chem.wisc.edu/JCEWWW/Resources/CQandChP/index.html . The site is a source of questions and problems that can be used in teaching and assessing conceptual understanding and problem solving in chemistry. Here you can find a library of free-response and multiple-choice conceptual questions and challenge problems, tips for writing these questions and problems, and a discussion of types of concept questions. This site is intended to be a means of sharing conceptual questions and challenge problems among chemical educators. It will be as inclusive as possible, and to achieve this readers need to share their questions and alert the authors to references or Web sites. The screen captures shown below should provide a feeling for what you will find when you visit the site. The authors, William R. Robinson and Susan C. Nurrenbern, welcome additions to the library of conceptual questions or other comments or suggestions. Contact them by email, fax, or regular mail. William R. Robinson and Susan C. Nurrenbern, Department of Chemistry, Purdue University, West Lafayette, IN 47907-1393. Bill: phone: 765/494-5453; fax: 765/494-0239; email: wrrobin@purdue.edu. Sue: phone: 765/494-0823; fax: 765/494-0239; email: nurrenbe@purdue.edu. fax: 765/494-0239. 1998 Ford Foundation Fellowships The National Research Council has announced the recipients of the 1998 fellowships for minority scholars. Three categories of fellowships were awarded: 50 to beginning graduate students, 33 to students writing their dissertations, and 28 to recent Ph.D. recipients. There were about 1,000 applicants. For information about the next competition contact the Fellowship Office of the National

  7. News and Announcements

    NASA Astrophysics Data System (ADS)

    1999-05-01

    and faithful supporter of this Journal, died February 25, 1999, at his home in Lafayette, California, at the age of 86. At the Fall 1998 ACS Meeting in Boston he suffered a serious fall following a stroke, from which he never recovered. One of his last photographs, taken the previous day at a Journal luncheon, appears on page 1360 of the November 1998 issue. His commentary on his long career in chemistry and education appears on page 1520 of the December 1998 issue. Seaborg was a Nobel laureate, discoverer of elements, scientific advisor to presidents, former chancellor of the University of California, former chairman of the Atomic Energy Commission, chairman of the steering committee of the CHEM Study project, founder of Lawrence Hall of Science, , the list goes on and on. He was at the same time a passionate supporter of education. Seaborg published fourteen articles in the Journal between 1951 and 1998. He was interviewed in 1975 by David Ridgway as part of the Impact series (JCE 1975, 52, 70), and that interview is highly recommended reading (see supplement to this article). He received the 1994 ACS George C. Pimentel Award in Chemical Education; his award address was published in the ACS Division of Chemical Education's CHED Newsletter, Fall 1995. Memorial articles with details of his life and his scientific contributions have appeared in The New York Times (Saturday, February 27, 1999, page 1) and Chemical & Engineering News (March 8, 1999, page 29). But there is also the spirit of the man, what he believed in, what he tried to do, what he hoped he had accomplished. A sense of that can be gained from the excerpts that are reprinted below, taken first from the Impact interview and then from the award address. Ridgway: On reflection, now, out of your many contributions to chemistry, is there one that you feel has had more of an impact than others? Seaborg: The discovery of plutonium would answer that question. The impact there is probably nearly as great as any

  8. The Changing Landscape of Science News

    NASA Astrophysics Data System (ADS)

    Riordon, James

    2011-03-01

    Social media are revolutionizing the ways that people communicate and the ways they get their news. Traditional news outlets are in decline, and no subject area is declining faster than science news. Every day there are fewer professional science journalists working in traditional media. On the other hand, ever greater numbers of scientists, science enthusiasts, and online journalists are turning to blogs, podcasts, eBooks, twitter feeds, and social media sites like Facebook and Tumbler to spread news about science. I will present an overview of the state of science journalism and speculate on the likely directions it seems to be heading. I will also offer some general guidelines to help scientists understand what makes a good science news story, as well as suggesting ways that they can get their work in the news.

  9. Delivering difficult news in psychiatric settings.

    PubMed

    Cleary, Michelle; Hunt, Glenn E; Horsfall, Jan

    2009-01-01

    Communication research and investigations into the delivery of bad news are uncommon in psychiatry versus other medical specialties. The question of delivering "bad" diagnostic news in psychiatry has been focused on dementia rather than actual psychiatric disorders and their sequelae. Common problems are that psychiatrists avoid dealing with patients' emotional reactions to bad news and that they avoid providing a clear diagnosis for fear that patients or carers will be distressed. This article aims to provide an overview of key elements of the "breaking bad news" literature, teasing out factors that are relevant to psychiatric practice. Topics explored include: definitions; clinical considerations for delivering difficult news within medical and psychiatric settings; protocols and guidelines; evidence about patient information needs and communication preferences; research into actual delivery of such news; and areas for future education and research. PMID:19832045

  10. News and the overloaded consumer: factors influencing information overload among news consumers.

    PubMed

    Holton, Avery E; Chyi, Hsiang Iris

    2012-11-01

    News producers continue to increase their volume of production and delivery platforms in an effort to reach and maintain news consumers. However, consumers may not necessarily find more news desirable. Previous studies have suggested that information surplus can lead to negative outcomes for consumers, but research of outcomes related to news production and consumption has been scant. This study explores novel areas of news surplus and overload, empirically examining factors associated with the degree of perceived overload across a broad spectrum of news delivery platforms. The findings reveal that the majority of today's news consumers feel overloaded with the amount of news they are confronted with. Gender, news interest, and the use of specific news platforms and outlets predict the degree of that overload. News access through platforms and outlets such as computers, e-readers, and Facebook is positively associated with overload, whereas other platforms such as television and the iPhone are negatively associated with overload. Implications for media psychology and news consumption are discussed. PMID:23020743

  11. News: Good chemical manufacturing process criteria

    EPA Science Inventory

    This news column covers topics relating to manufacturing criteria, machine to machine technology, novel process windows, green chemistry indices, business resilience, immobilized enzymes, and Bt crops.

  12. Phospholipid hydrolysis in a pharmaceutical emulsion assessed by physicochemical parameters and a new analytical method.

    PubMed

    Rabinovich-Guilatt, Laura; Dubernet, Catherine; Gaudin, Karen; Lambert, Gregory; Couvreur, Patrick; Chaminade, Pierre

    2005-09-01

    The aim of this work was to develop a simple high-performance liquid chromatography (HPLC) technique with evaporative light scattering detection (ELSD) for the separation and quantification of the major phospholipid (PL) and lysophospholipid (LPL) classes contained in a pharmaceutical phospholipid-based emulsion. In the established method, phosphatidylcholine (PC), phosphatidylethanolamine (PE), sphingomyeline (SM), lysophosphatidylcholine (LPC) and lysophosphatidylethanolamine (LPE) were separated with a PVA-Sil stationary phase and a binary gradient from pure chloroform to methanol:water (94:6 v/v) at 3.4%/min. The ELSD detection was enhanced using 0.1% triethylamine and formic acid in each gradient mobile phases. Factors such as stationary phase and ELSD drift tube temperature were optimized, concluding in optimal temperatures of 25 degrees C for separation and 50 degrees C for evaporation. This HPLC-ELSD method was then applied to a PL-emulsion exposed to autoclaving and accelerated thermal conditions at 50 degrees C. Hydrolysis of PC and PE followed first-order kinetics, representing only 45% of the total lipid mass after 3 months. The chemical stability was correlated to commonly measured formulation physical and physico-chemical parameters such as droplet size, emulsion pH and zeta-potential. PMID:15913973

  13. Nozzleless Fabrication of Oil-Core Biopolymeric Microcapsules by the Interfacial Gelation of Pickering Emulsion Templates.

    PubMed

    Leong, Jun-Yee; Tey, Beng-Ti; Tan, Chin-Ping; Chan, Eng-Seng

    2015-08-01

    Ionotropic gelation has been an attractive method for the fabrication of biopolymeric oil-core microcapsules due to its safe and mild processing conditions. However, the mandatory use of a nozzle system to form the microcapsules restricts the process scalability and the production of small microcapsules (<100 μm). We report, for the first time, a nozzleless and surfactant-free approach to fabricate oil-core biopolymeric microcapsules through ionotropic gelation at the interface of an O/W Pickering emulsion. This approach involves the self-assembly of calcium carbonate (CaCO3) nanoparticles at the interface of O/W emulsion droplets followed by the addition of a polyanionic biopolymer into the aqueous phase. Subsequently, CaCO3 nanoparticles are dissolved by pH reduction, thus liberating Ca(2+) ions to cross-link the surrounding polyanionic biopolymer to form a shell that encapsulates the oil droplet. We demonstrate the versatility of this method by fabricating microcapsules from different types of polyanionic biopolymers (i.e., alginate, pectin, and gellan gum) and water-immiscible liquid cores (i.e., palm olein, cyclohexane, dichloromethane, and toluene). In addition, small microcapsules with a mean size smaller than 100 μm can be produced by selecting the appropriate conventional emulsification methods available to prepare the Pickering emulsion. The simplicity and versatility of this method allows biopolymeric microcapsules to be fabricated with ease by ionotropic gelation for numerous applications. PMID:26148344

  14. Experimental study on bi-phase flow Air-Oil in Water Emulsion

    NASA Astrophysics Data System (ADS)

    Arnone, Davide; Poesio, Pietro

    2015-11-01

    Bi-phase slug flow oil-in-water emulsion [5%-20%] and air through a horizontal pipe (inner diameter 22mm) is experimentally studied. A test with water and air has been performed as comparison. First we create and analyze the flow pattern map to identify slug flow liquid and air inlet conditions. Flow maps are similar for all the used liquid. A video analysis procedure using an high speed camera has been created to obtain all the characteristics of unit slugs: slug velocity, slug length, bubble velocity, bubbles length and slug frequency. We compare translational velocity and frequency with models finding a good agreement. We calculate the pdfs of the lengths to find the correlations between mean values and STD on different air and liquid superficial velocities. We also perform pressure measurements along the pipe. We conclude that the percentage of oil-in- water has no influence on results in terms of velocity, lengths, frequency and pressure drop.

  15. Mathematical modeling of a water-in-oil emulsion droplet behavior under the microwave impact

    NASA Astrophysics Data System (ADS)

    Fatkhullina, Y. I.; Musin, A. A.; Kovaleva, L. A.; Akhatov, I. S.

    2015-01-01

    The problem of microwave (MW) electromagnetic radiation impact on a single water-in-oil droplet is considered. The system of heat equations within the droplet and in the surrounding liquid, incompressible Navier-Stokes equations within the droplet and in the surrounding liquid, and equation of state are considered. The formulated problem is solved numerically using TDMA (Tri-diagonal-matrix algorithm), SIMPLE algorithm and VOF method (volume of fluid method for the dynamics of free boundaries) in Euler coordinates. The results in the form of the dependence of the temperature within the droplet and in the surrounding liquid on the time of microwave impact and streamlines thermal convection are represented; dependence of the velocity of droplet's moving on the power of the of the microwave impact is shown. The obtained results can help to establish criteria for the efficient applicable of the microwave method for the water-in-oil emulsions destruction.

  16. Crude oil emulsions containing a compatible fluorochemical surfactant

    SciTech Connect

    Karydas, A.; Rodgers, J.

    1991-02-19

    This patent describes a crude oil in water emulsion, which is stable to both breakdown and phase inversion up to at least about 50{degrees} C., the emulsion containing an effective, compatible, emulsion stabilizing amount of a fluorochemical surfactant of the formula (R{sub {ital f}}){sub {ital n}}A{sub {ital m}}Q wherein R{sub {ital f}} is an inert, stable, oleophobic and hydrophobic fluoroaliphatic group having up to about 20 carbon atoms; n is an integer from 1 to 3; A is a direct bond or an organic linking group and is covalently bonded to both R{sub {ital f}} and Q; Q is an anionic, nonionic or amphoteric group; and m is an integer from 1 to 3; wherein the amount of weight of the fluorochemical surfactant present in the emulsion being between about 0.001 and 1% by weight of the emulsion, in the presence of absence of up to about 2% by weight of a crude oil emulsion promoting hydrocarbon surfactant, with the proviso that at least about 0.005% by weight total fluorochemical and hydrocarbon surfactant is present, based upon the weight of emulsion, and wherein the emulsion contains bout 15 to about 90 percent by weight water, based upon the weight of emulsion, such that the viscosity of the emulsion is less than about 50% of the viscosity of the crude oil, and wherein the emulsion spontaneously breaks down into an aqueous and crude oil phase at a temperature between about 55{degrees} and 75{degrees} C.

  17. Double inversion of emulsions induced by salt concentration.

    PubMed

    Zhang, Jingchun; Li, Lu; Wang, Jun; Sun, Haigang; Xu, Jian; Sun, Dejun

    2012-05-01

    The effects of salt on emulsions containing sorbitan oleate (Span 80) and Laponite particles were investigated. Surprisingly, a novel double phase inversion was induced by simply changing the salt concentration. At fixed concentration of Laponite particles in the aqueous phase and surfactant in paraffin oil, emulsions are oil in water (o/w) when the concentration of NaCl is lower than 5 mM. Emulsions of water in oil (w/o) are obtained when the NaCl concentration is between 5 and 20 mM. Then the emulsions invert to o/w when the salt concentration is higher than 50 mM. In this process, different emulsifiers dominate the composition of the interfacial layer, and the emulsion type is correspondingly controlled. When the salt concentration is low in the aqueous dispersion of Laponite, the particles are discrete and can move to the interface freely. Therefore, the emulsions are stabilized by particles and surfactant, and the type is o/w as particles are in domination. At intermediate salt concentrations, the aqueous dispersions of Laponite are gel-like, the viscosity is high, and the transition of the particles from the aqueous phase to the interface is inhibited. The emulsions are stabilized mainly by lipophilic surfactant, and w/o emulsions are obtained. For high salt concentration, flocculation occurs and the viscosity of the dispersion is reduced; thus, the adsorption of particles is promoted and the type of emulsions inverts to o/w. Laser-induced fluorescent confocal micrographs and cryo transmission electron microscopy clearly confirm the adsorption of Laponite particles on the surface of o/w emulsion droplets, whereas the accumulation of particles at the w/o emulsion droplet surfaces was not observed. This mechanism is also supported by the results of rheology and interfacial tension measurements. PMID:22475400

  18. Carbon dioxide in ionic liquid microemulsions.

    PubMed

    Zhang, Jianling; Han, Buxing; Li, Jianshen; Zhao, Yueju; Yang, Guanying

    2011-10-10

    Tailor-made emulsion: a CO(2) -in-ionic-liquid microemulsion was produced for the first time. The CO(2)-swollen micelles are "tunable" because the micellar size can be easily adjusted by changing the pressure of CO(2). The microemulsion has potential applications in materials synthesis, chemical reactions, and extraction. PMID:21898733

  19. Media Literacy, News Literacy, or News Appreciation? A Case Study of the News Literacy Program at Stony Brook University

    ERIC Educational Resources Information Center

    Fleming, Jennifer

    2014-01-01

    This case study provides practical and theoretical insights into the Stony Brook news literacy program, which is one of the most ambitious and well-funded curricular experiments in modern journalism education and media literacy. Analysis of document, interview, and observation data indicates that news literacy educators sought to teach students…

  20. Glycosylated polyacrylate nanoparticles by emulsion polymerization.

    PubMed

    Abeylath, Sampath C; Turos, Edward

    2007-08-01

    A selection of glycosylated polyacrylate nanoparticles has been prepared by radical-initiated emulsion polymerization in aqueous media. Using ethyl acrylate as a co-monomer, carbohydrate acrylates were incorporated into the poly(ethyl acrylate) framework to give stable emulsions of glyconanoparticles with an average particle size of around 40 nm. Using this technique a variety of glyconanoparticles were prepared from 3-O-acryloyl-1,2:5,6-di-O-isopropylidene-alpha-D-glucofuranose, 1-O-acryloyl-2,3:5,6-di-O-isopropylidene-alpha-D-mannofuranose, 6-O-acryloyl-1,2:3,4-di-O-isopropylidene-alpha-D-galactopyranose, 2-N-acryloyl-1,3,4,6-tetra-O-acetyl-beta-D-glucosamine, 5-O-acryloyl-2,3-isopropylidene-1-methoxy-beta-D-ribofuranose and 4-N-acetyl-5'-O-acryloyl-2',3'-O-isopropylidene cytidine. Scanning electron microscopy, dynamic light scattering and proton NMR analysis of the emulsions indicated essentially 100% incorporation of the carbohydrate acrylate monomer into the polymer with the exception of O-benzyl- and O-benzoyl-protected carbohydrate acrylates, which gave incomplete incorporation. Formation of larger glyconanoparticles of ~80nm with (unprotected) 3-O-acryloyl-D-glucose and 5-O-acryloyl-1-methoxy-beta-D-ribofuranose revealed the influence of free hydroxyl groups in the monomer on the particle size during polymerization, a feature which is also apparently dependent on the amount of carbohydrate in the matrix. This methodology allows for a new, simple route to the synthesis of polymeric glyconanoparticles with potential applications in targeted drug delivery and materials development. PMID:18677404

  1. Emulsion design to improve the delivery of functional lipophilic components.

    PubMed

    McClements, David Julian

    2010-01-01

    The food industry has used emulsion science and technology for many years to create a diverse range of food products, such as milk, cream, soft drinks, nutritional beverages, dressings, mayonnaise, sauces, dips, deserts, ice cream, margarine, and butter. The majority of these food products are conventional oil-in-water (O/W) or water-in-oil (W/O) type emulsions. Recently, there has been increasing interest within the food industry in either improving or extending the functional performance of foods using novel structured emulsions. This article reviews recent developments in the creation of structured emulsions that could be used by the food and other industries, including nanoemulsions, multiple emulsions, multilayer emulsions, solid lipid particles, and filled hydrogel particles. These structured emulsions can be produced from food-grade [generally recognized as safe (GRAS)] ingredients (e.g., lipids, proteins, polysaccharides, surfactants, and minerals), using simple processing operations (e.g., mixing, homogenizing, and thermal processing). The structure, production, performance, and potential applications of each type of structured emulsion system are discussed. PMID:22129337

  2. Silicone oil emulsions stabilized by polymers and solid particles.

    PubMed

    Kawaguchi, Masami

    2016-07-01

    Silicone oil emulsions stabilized by various emulsifiers such as polymers, solid particles alone, and solid particles with pre-adsorbed surfactants or polymers are reviewed, focusing on their emulsion stability and rheological properties as a function of the emulsifier concentration. An increase in the concentration of the emulsifier leads to a decrease in the droplet size and an increase in the emulsion stability, irrespective of the emulsifier. Moreover, the overlapping concentration of polymer can be regarded as a criterion for the preparation of emulsions using polymeric emulsifiers. Changes in the emulsion stability and rheological responses of the emulsions prepared by the solid particles with pre-adsorbed polymers are discussed in terms of the amounts of the emulsifiers adsorbed. For emulsions prepared from hydrophilic silica particles with pre-adsorbed polymers, a decrease in the droplet size of an order of magnitude can be controlled by an increase in the concentration of polymer, whereas hydrophilic silica particles alone cannot produce stable silicone oil emulsions. PMID:26170165

  3. Synthesis of metallic nanoshells on porphyrin-stabilized emulsions

    DOEpatents

    Wang, Haorong; Song, Yujiang; Shelnutt, John A.; Medforth, Craig J.

    2011-12-13

    Metal nanostructures formed by photocatalytic interfacial synthesis using a porphyrin-stabilized emulsion template and the method for making the nanostructures. Catalyst-seeded emulsion droplets are employed as templates for hollow-nanoshell growth. The hollow metal nanospheres may be formed with or without inclusions of other materials.

  4. Linear oil displacement by the emulsion entrapment process. [Dissertation

    SciTech Connect

    Schmidt, D.P.

    1982-01-01

    Lack of mobility control is one of the major impediments to successful enhanced oil recovery, especially for high viscosity oils. This work presents experimental and theoretical results for linear secondary oil displacements using dilute, stable suspensions of oil drops. The major hypothesis is that emulsions provide mobility control through entrapment or local permeability reduction, not through viscosity ratio improvement. In order to describe the displacement process, previous emulsion filtration theory is extended to longer cores and to two-phase flow. Quantitative agreement between theory and experiment is satisfactory for continuous secondary oil displacement with various drop-size emulsions in unconsolidated sand packs of permeabilities ranging from 0.7 ..mu..m/sup 2/ to 3.3 ..mu..m/sup 2/. Linear emulsion floods are shown to be most effective when the mean drop-size to pore-size ratio is in the region between straining and interception at the emulsion shock. Floods are more effective when the emulsion concentration is high which minimizes retention lag. Additionally, a parallel flooding apparatus is utilized to determine qualitatively the macroscopic benefits of emulsion mobility control. Direct analogies are established between augmented oil recovery with dilute emulsions and with entrapping polymers.

  5. 21 CFR 524.802 - Enrofloxacin, silver sulfadiazine emulsion.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Enrofloxacin, silver sulfadiazine emulsion. 524... ANIMAL DRUGS § 524.802 Enrofloxacin, silver sulfadiazine emulsion. (a) Specifications. Each milliliter contains 5 milligrams (mg) enrofloxacin and 10 mg silver sulfadiazine. (b) Sponsor. See No. 000859 in §...

  6. 21 CFR 524.802 - Enrofloxacin, silver sulfadiazine emulsion.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 6 2011-04-01 2011-04-01 false Enrofloxacin, silver sulfadiazine emulsion. 524... ANIMAL DRUGS § 524.802 Enrofloxacin, silver sulfadiazine emulsion. (a) Specifications. Each milliliter contains 5 milligrams (mg) enrofloxacin and 10 mg silver sulfadiazine. (b) Sponsor. See No. 000859 in §...

  7. 21 CFR 524.802 - Enrofloxacin, silver sulfadiazine emulsion.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 6 2013-04-01 2013-04-01 false Enrofloxacin, silver sulfadiazine emulsion. 524... ANIMAL DRUGS § 524.802 Enrofloxacin, silver sulfadiazine emulsion. (a) Specifications. Each milliliter contains 5 milligrams (mg) enrofloxacin and 10 mg silver sulfadiazine. (b) Sponsor. See No. 000859 in §...

  8. 21 CFR 524.802 - Enrofloxacin, silver sulfadiazine emulsion.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 6 2012-04-01 2012-04-01 false Enrofloxacin, silver sulfadiazine emulsion. 524... ANIMAL DRUGS § 524.802 Enrofloxacin, silver sulfadiazine emulsion. (a) Specifications. Each milliliter contains 5 milligrams (mg) enrofloxacin and 10 mg silver sulfadiazine. (b) Sponsor. See No. 000859 in §...

  9. Oilfield solids and water-in-oil emulsion stability.

    PubMed

    Sztukowski, Danuta M; Yarranton, Harvey W

    2005-05-15

    Model water-in-hydrocarbon emulsions consisting of toluene, heptane, water, asphaltenes, and native solids were used to investigate the role of native solids in the stability of oilfield emulsions. The solids were recovered from an oil-sands bitumen, a wellhead emulsion, and a refinery slop oil. The solids were clay platelets and fell into two size categories: (1) fine solids 50 to 500 nm in diameter and (2) coarse solids 1 to 10 microm in diameter. Emulsions stabilized by fine solids and asphaltenes were most stable at a 2:1 fractional area ratio of asphaltenes to solids. It appears that when the asphaltene surface coverage is high, insufficient solids remain to make an effective barrier. When the solids coverage is high, insufficient asphaltenes remain on the interface to immobilize the solids. Treatments that weaken the interface, such as toluene dilution, are recommended for emulsions stabilized by fine solids. Emulsions stabilized by coarse solids were unstable at low solids concentrations but became very stable at solids concentrations greater than 10 kg/m(3). At low concentrations, these solids may act as bridges between water droplets and promote coalescence. At high concentrations, layers of coarse solids may become trapped between water droplets and prevent coalescence. Treatments that flocculate the solids, such as heptane dilution, are recommended for emulsions stabilized by high concentrations of coarse solids. It is possible that emulsions containing both types of solids may require more than one treatment, or even process step, for effective water resolution. PMID:15837502

  10. Maximizing the stability of pyrolysis oil/diesel fuel emulsions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Several emulsions consisting of biomass pyrolysis oil (bio-oil) in diesel fuel were produced and analyzed for stability over time. An ultrasonic probe was used to generate microscopic droplets of bio-oil suspended in diesel fuel, and this emulsion was stabilized using surfactant chemicals. The most...

  11. Mannans as stabilizers of oil-in-water beverage emulsions

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Plant polysaccharides and gums such as gum arabic (GA) are commonly used as stabilizers of oil-in-water emulsions. O-acetyl-galactoglucomannan (GGM), a by-product from mechanical pulping of spruce wood, is able to stabilize colloidal wood resin emulsions (Hannuksela and Holmbom, 2004), but its use a...

  12. Rheological properties of heavy oils and heavy oil emulsions

    SciTech Connect

    Khan, M.R.

    1996-06-01

    In this study, the author investigated the effects of a number of process variables such as shear rate, measurement temperature, pressure, the influence of pretreatment, and the role of various amounts of added water on the rheology of the resulting heavy oil or the emulsion. Rheological properties of heavy oils and the corresponding emulsions are important from transportation and processing standpoints.

  13. A practical gas chromatography flame ionization detection method for the determination of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane in silicone emulsions.

    PubMed

    Brothers, Herbert M; Bovens, Eric; Bruni, Antonio; Habitz, Tanya M; Hamachi, Tadashi; Han, Yuanhua; Ji, Zhouhua; Kerbleski, Joel J; Letouche, Claude; Lu, Yi Dong; Nguyen, Regis; Rivard, Michelle L; Qi, Xiaoman; Shoji, Miki; Tanaka, Ken; Tecklenburg, Ronald E

    2016-04-01

    A gas chromatography with flame ionization detection (GC-FID) method for analysis of D4, D5, and D6 cyclic siloxanes in silicone emulsions is described. Sample preparation involves breaking the emulsion with methanol and hexanes, and then analyzing the hexanes phase after derivatization with hexamethyldisilazane (HMDS). Silylation is performed to reduce the potential for formation of cyclic siloxanes during the course of the GC analysis. The accuracy of the method was verified by performing analyses on samples spiked with known levels of D4, D5 and D6 and by comparison to a referee method using atmospheric pressure chemical ionization liquid chromatography with mass spectrometry detection (APCI-LC-MS). Absolute differences of the results obtained between the two techniques were 0.03 weight percent or less, and relative differences were 15% or less. The reproducibility and ruggedness of the method was demonstrated by performing a global round robin test at four different geographic sites on four different types of silicone emulsions. The %RSDs obtained were less than 10% for all analytes and all emulsions examined. PMID:26968230

  14. Listening to Monotony: All-News Radio.

    ERIC Educational Resources Information Center

    Woal, Michael

    A study analyzed statistically the monotony of all-news radio listening and identified stylistic figures that elicit attention in listeners. Subjects were 30 graduate students whose experience with radio news ranged from occasional listening over several months to regular listening five or seven days per week for several years. Respondents were…

  15. Computational Methods for Analyzing Health News Coverage

    ERIC Educational Resources Information Center

    McFarlane, Delano J.

    2011-01-01

    Researchers that investigate the media's coverage of health have historically relied on keyword searches to retrieve relevant health news coverage, and manual content analysis methods to categorize and score health news text. These methods are problematic. Manual content analysis methods are labor intensive, time consuming, and inherently…

  16. TV News Analysis Project Motivates Broadcast Class.

    ERIC Educational Resources Information Center

    Smith, James R.

    1980-01-01

    Describes the use of content analysis by a journalism class in studying television news. Indicates that the method is flexible, generates familiarity with quantitative approaches to the analysis of broadcast journalism, can result in increased awareness of the complexity of the broadcast news medium, and increases student motivation. (TJ)

  17. Television and the News: A Critical Appraisal.

    ERIC Educational Resources Information Center

    Skornia, Harry J.

    This book contains a documented critical analysis of the state of broadcast journalism in the United States. It also examines the conditions that prevent news broadcasting as a practice from being a profession, and suggests steps needed to achieve professionalism in providing the kind of news service the nation needs but is not getting. Some of…

  18. Kids, Crime, and Local Television News

    ERIC Educational Resources Information Center

    Yanich, Danilo

    2005-01-01

    The vast majority of crime reporting occurs on local television news and in newspapers. Although crimes are extraordinary events, they assume an ordinariness that only daily reporting can give them. The obvious question is what does the news tell us about crime. This article compares the coverage of adult crime and the coverage of what the author…

  19. Workforce Competitiveness Collection. "LINCS" Resource Collection News

    ERIC Educational Resources Information Center

    Literacy Information and Communication System, 2011

    2011-01-01

    This edition of "'LINCS' Resource Collection News" features the Workforce Competitiveness Collection, covering the topics of workforce education, English language acquisition, and technology. Each month Collections News features one of the three "LINCS" (Literacy Information and Communication System) Resource Collections--Basic Skills, Program…

  20. Television and Its News: A Discrepancy Examination.

    ERIC Educational Resources Information Center

    Melton, Gary Warren

    This exploratory endeavor utilized a functional discrepancy model of mass communication research to examine the audience experience with television generally and its news in particular. Specifically, gratifications sought from television in general and gratifications perceived as being obtained from television news are analyzed for a random sample…

  1. Satellite News Feeds: Protecting a Transient Interest.

    ERIC Educational Resources Information Center

    Atwater, Tony; And Others

    Satellite news gathering (SNG) has been widely adopted in broadcast journalism in recent years, and appears likely to grow in importance as local television news operations increase their reliance on it. However, because the technology for SNG is so new, information transmitted through SNG systems is not adequately protected under current laws.…

  2. News Research for Better Newspapers, Volume Five.

    ERIC Educational Resources Information Center

    Bush, Chilton R., Comp.

    The findings of research studies that come from a variety of sources and concern newspapers, some aspects of television news, and news media audiences are summarized briefly. Among the topics are audience characteristics, content of stories, readership, headlines and makeup, editorial policy, and editorial administration and personnel. Most of the…

  3. News Research for Better Newspapers. Volume 3.

    ERIC Educational Resources Information Center

    Bush, Chilton R., Ed.

    This volume is a compilation of the summaries of news-editorial research reported in the American Newspaper Publishers Association News Research Bulletins during 1967. Of the 44 studies reported in this volume, twenty were done by universities, ten by individuals, nine by research agencies, and five by other organizations. The studies are arranged…

  4. Library Media Specialists: Doing the News!

    ERIC Educational Resources Information Center

    Barron, Daniel D.

    2003-01-01

    Discusses Newspapers in Education (NIE) Week and how it can relate to school library media specialists. Highlights include the convergence of news media, including news on the Web; ERIC (Educational Resources Information Center) resources, including lesson plans; relevant books; Web sites; and Web journalism. (LRW)

  5. Developing a News Media Literacy Scale

    ERIC Educational Resources Information Center

    Ashley, Seth; Maksl, Adam; Craft, Stephanie

    2013-01-01

    Using a framework previously applied to other areas of media literacy, this study developed and assessed a measurement scale focused specifically on critical news media literacy. Our scale appears to successfully measure news media literacy as we have conceptualized it based on previous research, demonstrated through assessments of content,…

  6. Broadcast Journalism; An Introduction to News Writing.

    ERIC Educational Resources Information Center

    Hall, Mark W.

    The important features of writing news for radio and television are covered in this book. Ways to write colorful, accurate, and timely stories are explained with the emphasis on the differences between broadcast and newspaper stories. Other subjects treated are sources of news (including explanations of how the Associated Press copy works and how…

  7. Science News and the Science Classroom

    ERIC Educational Resources Information Center

    McCullough, Laura

    2006-01-01

    Using "Science News" as a teaching tool promotes writing about science, talking about science, and broadening students' views about what science is. This article describes an ongoing assignment in which students choose one article from "Science News" each week and write a brief summary and explanation of why they picked that article. (Contains 1…

  8. Creating Reality: How TV News Distorts Events.

    ERIC Educational Resources Information Center

    Altheide, David L.

    A three-year research project, including more than one year in a network affiliate station, provided the material for an analysis of current practices in television news programming. Based on the thesis that the organization of news encourages the oversimplification of events, this analysis traces the foundation of the bias called the "news…

  9. NIH News in Health: September 2006

    ERIC Educational Resources Information Center

    Wein, Harrison, Ed.

    2006-01-01

    News in Health, is a monthly newsletter that provides practical health news and information. As college students arrive on campus this fall, it is a time of new experiences, new friendships and making memories that will last a lifetime. Unfortunately for many, it can also be a time of excessive drinking and dealing with its aftermath--vandalism,…

  10. Mass News: Practices, Controversies, and Alternatives.

    ERIC Educational Resources Information Center

    Leroy, David J., Ed.; Sterling, Christopher H., Ed.

    This selection of readings, primarily intended for a college journalism course, discusses the strengths and weaknesses of the major sources of the public news--the wire services, newspapers, and television. The first part of the book deals with the context of mass news and serves as an introduction to some of the crucial ideas shaping thinking…

  11. Program Management Collection. "LINCS" Resource Collection News

    ERIC Educational Resources Information Center

    Literacy Information and Communication System, 2011

    2011-01-01

    This edition of "'LINCS' Resource Collection News" features the Program Management Collection, which covers the topics of Assessment, Learning Disabilities, and Program Improvement. Each month Collections News features one of the three "LINCS" (Literacy Information and Communication System) Resource Collections--Basic Skills, Program Management,…

  12. Scandal Clouds News Corporation's Move into Education

    ERIC Educational Resources Information Center

    Quillen, Ian

    2011-01-01

    When News Corporation announced last fall its entry into the education technology market, some observers said the media conglomerate led by Rupert Murdoch was a bad fit for education. Between the ownership of conservative-leaning outlets like Fox News and a reputation for identifying opportunities to generate lots of revenue very quickly, News…

  13. Quantitative morphological characterization of bicontinuous Pickering emulsions via interfacial curvatures.

    PubMed

    Reeves, Matthew; Stratford, Kevin; Thijssen, Job H J

    2016-05-14

    Bicontinuous Pickering emulsions (bijels) are a physically interesting class of soft materials with many potential applications including catalysis, microfluidics and tissue engineering. They are created by arresting the spinodal decomposition of a partially-miscible liquid with a (jammed) layer of interfacial colloids. Porosity L (average interfacial separation) of the bijel is controlled by varying the radius (r) and volume fraction (ϕ) of the colloids (L∝r/ϕ). However, to optimize the bijel structure with respect to other parameters, e.g. quench rate, characterizing by L alone is insufficient. Hence, we have used confocal microscopy and X-ray CT to characterize a range of bijels in terms of local and area-averaged interfacial curvatures; we further demonstrate that bijels are bicontinuous using an image-analysis technique known as 'region growing'. In addition, the curvatures of bijels have been monitored as a function of time, which has revealed an intriguing evolution up to 60 minutes after bijel formation, contrary to previous understanding. PMID:27035101

  14. [Effect of lipid emulsifiers on the properties of organoperfluorine emulsions].

    PubMed

    Oksinoĭd, O E; Romanova, M Zh; Afonin, N I

    1990-01-01

    The preparation and application of a new type of organoperfluorine (OPF) emulsions with lipids serving as emulsifiers, their biological and physicochemical properties are discussed. The first-generation emulsions with the nonionic emulsifier, ethylene and propylene oxide blockpolymer, were found to be complementary active and to affect the system's biological properties. Interactions between OPF and phospholipids are analysed. The compositions of the new type OPF emulsions are given, of which perfluoroctyl bromide and perfluoromethyl adamantine emulsions are shown to be currently of most interest, since they are stable at room temperature and exhibit somewhat superior physicochemical and biological parameters. A conclusion is derived that the developed lipid-based OPF emulsions have good clinical prospects. PMID:2275276

  15. Development of an Acoustic Droplet Vaporization, Ultrasound Drug Delivery Emulsion

    NASA Astrophysics Data System (ADS)

    Fabiilli, Mario L.; Sebastian, Ian E.; Fowlkes, J. Brian

    2010-03-01

    Many therapeutic applications of ultrasound (US) include the use of pefluorocarbon (PFC) microbubbles or emulsions. These colloidal systems can be activated in the presence of US, which in the case of emulsions, results in the production of bubbles—a process known as acoustic droplet vaporization (ADV). ADV can be used as a drug delivery mechanism, thereby yielding the localized release of toxic agents such a chemotherapeutics. In this work, emulsions that contain PFC and chlorambucil, a chemotherapy drug, are formulated using albumin or lipid shells. For albumin droplets, the oil phase—which contained CHL—clearly enveloped the PFC phase. The albumin emulsion also displayed better retention of CHL in the absence of US, which was evaluated by incubating Chinese hamster ovary cells with the various formulations. Thus, the developed emulsions are suitable for further testing in ADV-induced release of CHL.

  16. Space Shuttle Status News Conference

    NASA Technical Reports Server (NTRS)

    2005-01-01

    Richard Gilbech, External Tank "Tiger Team" Lead, begins this space shuttle news conference with detailing the two major objectives of the team. The objectives include: 1) Finding the root cause of the foam loss on STS-114; and 2) Near and long term improvements for the external tank. Wayne Hale, Space Shuttle Program Manager, presents a chart to explain the external tank foam loss during STS-114. He gives a possible launch date for STS-121 after there has been a repair to the foam on the External Tank. He further discusses the changes that need to be made to the surrounding areas of the plant in New Orleans, due to Hurricane Katrina. Bill Gerstemaier, NASA Associate Administrator for Space Operations, elaborates on the testing of the external tank foam loss. The discussion ends with questions from the news media about a fix for the foam, replacement of the tiles, foam loss avoidance, the root cause of foam loss and a possible date for a new external tank to be shipped to NASA Kennedy Space Center.

  17. The NEWS Water Cycle Climatology

    NASA Technical Reports Server (NTRS)

    Rodell, Matthew; Beaudoing, Hiroko Kato; L'Ecuyer, Tristan; William, Olson

    2012-01-01

    NASA's Energy and Water Cycle Study (NEWS) program fosters collaborative research towards improved quantification and prediction of water and energy cycle consequences of climate change. In order to measure change, it is first necessary to describe current conditions. The goal of the first phase of the NEWS Water and Energy Cycle Climatology project was to develop "state of the global water cycle" and "state of the global energy cycle" assessments based on data from modern ground and space based observing systems and data integrating models. The project was a multi-institutional collaboration with more than 20 active contributors. This presentation will describe the results of the water cycle component of the first phase of the project, which include seasonal (monthly) climatologies of water fluxes over land, ocean, and atmosphere at continental and ocean basin scales. The requirement of closure of the water budget (i.e., mass conservation) at various scales was exploited to constrain the flux estimates via an optimization approach that will also be described. Further, error assessments were included with the input datasets, and we examine these in relation to inferred uncertainty in the optimized flux estimates in order to gauge our current ability to close the water budget within an expected uncertainty range.

  18. Statistical physics of topological emulsions and expanding populations

    NASA Astrophysics Data System (ADS)

    Korolev, Kirill Sergeevich

    This thesis studies how microscopic interactions lead to large scale phenomena in two very different systems: two-dimensional liquid crystals and expanding populations. First, we explore the interactions among circular droplets embedded in a two-dimensional liquid crystal. The interactions arise due to anchoring boundary conditions on the surface of the inclusions and the elastic deformations of the orientational order parameter in the continuous phase. We analytically compute the texture around a single droplet and the far-field droplet-droplet pair potential. The near-field pair potential is computed numerically. We find that droplets attract at long separations and repel at short separations, which results in a well-defined preferred distance between the droplets and stabilization of the emulsion. Self-organization, barriers to coalescence, and the effects of thermal fluctuations are also discussed. Second, we study the role of randomness in the number of offspring on the evolutionary dynamics of expanding populations. Several equally fit genetic variants (alleles) are considered. We find that spatial expansion combined with demographic fluctuations leads to a substantial loss of genetic diversity and spatial segregation of the alleles. The effects of these processes on recurring mutations and selective sweeps are studied as well. Third, the competition between two alleles of different fitness is investigated. We find that the essential features of this competition can be captured by a non-linear reaction-diffusion equation. During a range expansion the fitter allele forms growing sectors that eventually engulf the less fit allele. The applications to measuring relative fitness in microbiological experiments are discussed. Finally, we analyze how a combination of strong stochasticity and weak competition affects the spreading of beneficial mutations in stationary, non-expanding, populations.

  19. ESR studies of semicontinuous emulsion polymerization

    SciTech Connect

    Lau, W.; Westmoreland, D.G.

    1993-12-31

    Electron spin resonance (ESR) is used in the detection and quantification of propagating radicals during a semicontinuous emulsion polymerization. The propagating radical concentration is crucial for the determination of kinetic parameters of the emulsion polymerization process. A flow reactor was built which involves a closed-loop flow system that circulates latex from the polymerization reactor through the ESR cavity for free-radical measurements and back to the reactor. With the continuous measurement of the radical concentrations during a polymerization of methyl methacrylate (MMA), {bar n} (average number of radicals per particle) and k{sub p} (propagating rate constant), are measured throughout the entire polymerization. For the polymerization of the MMA system studied, the authors observed a gradual increased in n and decrease in k{sub p} during the run, suggesting a diffusionally controlled process and that the polymerization is not occurring homogeneously throughout the polymer particles. In the glassy pMMA matrix, radicals can be {open_quotes}trapped{close_quotes} within a minimum volume and remain unterminated.

  20. News

    NASA Astrophysics Data System (ADS)

    2005-03-01

    Microscopy: Schools to gain remote access to Oxford University-based SEM Canada: Perimeter Institute calls international applicants to its 2005 summer school ASE: ASE 2005 refreshes the teaching parts that other conferences cannot reach Scotland: Glasgow hosts Kelvin exhibition Climate Analysis: Met Office sets up project to predict climate change Wales: Welsh teachers meet at Christ College, Brecon ESERA: ESERA 2005 unveils its conference programme Higher Education: Educators address school-university transition Christmas Lecture Series: Royal Institution supports Christmas Lecture series with interactive CD-ROM Events: UK’s Science Week kicks off in March Grants: PPARC and IOP to provide grants worth up to £400 Camera Competition: Congratulations go to camera winners Teachers’ TV: Teachers’ channel hits the small screen Physics and Music: Foster and Liebeck presentation combines physics and music Science on Stage: SOS gears up for Geneva festival Nanoworld: Hirsch lecture at Oxford focuses on the nanoworld GIREP: GIREP conference aims to raise physics’ profile Course: STELAR offers free radio-communication course

  1. News

    NASA Astrophysics Data System (ADS)

    2005-01-01

    Einstein year: Einstein is brought back to life for a year of educational events Workshop: Students reach out for the Moon Event: Masterclasses go with a bang Workshop: Students search for asteroids on Einstein's birthday Scotland: Curriculum for Excellence takes holistic approach Conference: Reporting from a mattress in Nachod Conference: 'Change' is key objective at ICPE conference 2005 Lecture: Institute of Physics Schools Lecture series Conference: Experience showcase science in Warwick National network: Science Learning Centre opens Meeting: 30th Stirling Physics Meeting breaks records Competition: Win a digital camera! Forthcoming Events

  2. News

    NASA Astrophysics Data System (ADS)

    2004-11-01

    Astronomy: Trust founder receives heavenly honour Africa: UK teaching methods make the difference in Rwandan schools Spaced Out: UK-based scale model places Jodrell Bank at the centre of our solar system Teaching Support: Teacher Network makes its mark in the classroom Correction Art on Stage: Galileo lacks momentum Meeting: Teachers are inspired by US gathering Online Study: PPLATO Foundation promotes new avenue to university study Conference: GIREP '04 creates atmosphere of 'curiosity and enthusiasm' Meeting: SonSD meeting allows exchange of teaching ideas Competition: Win a digital camera! Physics in Perspective: Events highlight how rewarding physics can be Meeting: ASE conference to deliver the best of Physics Education

  3. News

    NASA Astrophysics Data System (ADS)

    2001-11-01

    IRELAND New courses for high-tech Ireland; SCIENCE YEAR Science Year launched with a jump; THE NETHERLANDS School science teachers face uncertainty; KOREA Embedding physics in a cultural context; TEACHING RESOURCES Teacher, get your hook; ICT RESOURCES Stock-take of ICT progress; INTERNET Teachers to test-drive new physics gateway; NEW ZEALAND Physics is valued in New Zealand; JAPAN Advancing Physics in Japan; HIGHER EDUCATION Networking works in Cologne; INSTITUTE MATTERS IoP demands a better deal for physics teachers; AUSTRALIA Physics numbers decline: educators blame the low impact curriculum; SCIENCE FOR THE PUBLIC More than sixty seconds in Glasgow; INTERNET A gift selection of papers from IoP; TEACHING STYLES I know what you did last summer;

  4. News

    NASA Astrophysics Data System (ADS)

    Davenhall, Clive

    2010-07-01

    Webb-Share update; Astro-cymru update; Copernicus reburied; Tycho to be exhumed; Caledonian anniversary 1: chair of astronomy at Glasgow; Caledonian anniversary II: James Ferguson: Fifty years of weather satellites; H.G. Wells remembered.

  5. News

    NASA Astrophysics Data System (ADS)

    2001-03-01

    PHYSICS AT ASE Warm welcome for new-look Physics Education; TEACHING COMMUNITY Conference in the Netherlands; RESEARCH Evidence based practice; PHYSICS AT ASE Teacher of Physics Awards; PHYSICS AT ASE Festival encourages science teachers; AWARDS Bragg Medal; PHYSICS AT ASE Meteorites are cool! PUBLIC UNDERSTANDING March 2001 - a science odyssey; WEB RESOURCES New website launched to support the gifted and talented; PHYSICS TEACHING A Fun lesson; RESEARCH FRONTIERS Are cell phones safe? OBITUARY Roy Schofield 1924-2000

  6. News

    NASA Astrophysics Data System (ADS)

    2001-01-01

    MASTERCLASSES Researchers help motivate school students; HIGHER EDUCATION Undergraduate physics inquiry launched Sir Peter; PUBLIC UNDERSTANDING OF SCIENCE Chemists take the lead to get science groups pulling together; RESEARCH FRONTIERS Spintronic Chips; LOWER SECONDARY CURRICULUM Why do we teach physics? TEACHING COMMUNITY e-Teachers; AWARDS Nobel Prize; HIGHER EDUCATION Project Phoenics; PARTICLE PHYSICS LEP Closure; TEACHER TRAINING Training salary fails to attract recruits; EVENTS Physics moves into the spotlight

  7. News

    NASA Astrophysics Data System (ADS)

    Davenhall, Clive

    2011-09-01

    Townsend Observatory destroyed; BAA Lunar Section archives; Astro-Cymru; Royal star identified; Formation of Johannes Kepler Working Group; Tycho Brahe exhumed; Ancient observatory discovered in Iran...; ... and in Mexico; Calling all ex-occupants of interplanetary craft.

  8. News

    NASA Astrophysics Data System (ADS)

    2003-07-01

    Meetings: Physics Teachers@CERN 2003 Education Group Annual Conference: Observations by a first-time participant... Summer Workshop: Making Music Competition: Physics in the fast lane Bristol Festival of Physics: Ice cream ice-breakers Online Resources: Old favourites go online UK Curriculum: What does society want? UK Curriculum: Assessment of Science Learning 14-19 Forthcoming Events

  9. News

    NASA Astrophysics Data System (ADS)

    2004-07-01

    Physics on Stage: Física en Acción increases the public’s awareness of science Competition: Winner takes a trip to CERN Ireland: TruePhysics makes life simpler Czech Republic: Technology fun day highlights demand for new science centre Literary Festival: Physicists visit Hay while the Sun shines Science on Stage: Science takes stage in Germany National Convention: NSTA connects science to world Forthcoming Events

  10. News

    NASA Astrophysics Data System (ADS)

    2006-11-01

    International conference: GIREP conference welcomes all UK Symposium: Showcase Science opens its doors to sixth-formers from across the country Universities: Institute regrets the closure of physics department at Reading Scotland: Sun and exam success in Stirling CERN: Teachers to descend on CERN

  11. News

    NASA Astrophysics Data System (ADS)

    2005-11-01

    Spain: ESERA conference debates the teacher researcher relationship Media: Teachers’ TV Associates now launched Slovenia: GIREP seminar: ‘formal’ and ‘informal’ educators work together in Ljubljana Award: Faculty honours rollercoaster designer OECD: Global survey to assess school leavers’ abilities Competition: Opportunity to win revision aid for your class Scotland: Annual meeting UK: Humour and controversy at energy day Training: Teachers get to grips with telescopes Scotland: Educators flock to Stirling 2005

  12. News

    NASA Astrophysics Data System (ADS)

    2002-11-01

    Resources: First Faulkes Telescope on its way! Events: Everything under the Sun - GIREP 2002 Experiments: The most beautiful experiment, your favourite demonstration Science year: Planet Science takes off Resources: New CD packages Lecture: Fantastic Plastic Summer workshop: The Wright Stuff Resources: Amazing Space 14-16 curriculum: 21st century science ASE conference: ASE 2003 South Africa: Sasol SciFest Earth sciences: JESEI: the answer to all your Earthly problems

  13. News

    NASA Astrophysics Data System (ADS)

    2001-05-01

    LINKS WITH PRIMARY SCIENCE SAD Physics; PHYSICS RESEARCH In a hurry...; PHYSICS COMMUNITY Scottish Stirling Meeting; PHYSICS AT CONGRESS Global warming forecasts rise in skin cancer; EVENTS 2001 SET week; E-MAIL DISCUSSIONS Learning in science; STUDENT ACTIVITY Paperclip Physics; CURRICULUM DEVELOPMENT Perspectives on Science; AWARDS Award for causing chaos; PHYSICS AT CONGRESS Physics and public heath: Do electrical power lines cause cancer? HIGHER EDUCATION First-year course development; INTERSCHOOL COLLABORATION Monitoring geomagnetic storms; CURRICULUM DEVELOPMENT UK course goes international; PHYSICS IN SCIENCE YEAR Website launched

  14. News

    NASA Astrophysics Data System (ADS)

    2005-07-01

    Croatia: Rijeka’s 2005 science festival attracts an enthusiastic crowd The Middle East: METSMaC conference reaches out to teachers around the Gulf and beyond Spain: Física en Acción 5: a Spanish festival that will have you cycling the tightrope Czech Republic: Astronomy lessons for everyone Sussex Planetarium: Planetarium sets its sights high TV series: Einstein gets animated for C4 cartoon series Memorial: Honouring the great: memorial to Robert Hooke is unveiled at Westminster Abbey Awards: SHAP awards prizes for exceptional student work Group meeting: IOP’s Education Group to meet in September Forthcoming Events

  15. News

    NASA Astrophysics Data System (ADS)

    2002-05-01

    Physics on Stage: Physics on the political stage Women in Physics: Allez les girls! Curriculum: Students want ethics debate in school science Physics on Stage: Buzzing around the tulips Events: GIREP 2002 Competition: Schumacher in the shower! Higher Education: Universities consider conceptual physics courses Resources: Evaluation of Advancing Physics Research Frontiers: Physics Teachers @ CERN 2002 UK Curriculum: Preparing useful citizens China: Changing the approach NSTA Annual Convention: Innovations and simplicity Europe: European Community Science and Society Action Plan Citizenship: ASE-Wellcome Trust citizenship education initiative

  16. News

    NASA Astrophysics Data System (ADS)

    2008-11-01

    Particle Physics: LHC switch-on inspires pupils Science Fair: Science takes centre stage in Spain Conference: Czech and Slovak physicists get together Curriculum: UK needs independent curriculum body Conference: Edmonton enjoys a physics-show treat

  17. News

    NASA Astrophysics Data System (ADS)

    1998-04-01

    Nearly Complete Set: I have an almost complete set of J. Chem. Educ., lacking only 3-4 volumes from the early 1930's. It is in pristine condition, bound each year (except the last five years), and used gently only by myself. I am retired and willing to part with this collection for a reasonable offer - I cannot afford to donate them. Any library or individual who might have a serious interest should contact Robert Goldenberg, P. O. Box 412, Westside Station, Buffalo, NY 14213; phone: 905/871-1098; email: goldenbe@vaxxine.com.

  18. News

    NASA Astrophysics Data System (ADS)

    2008-07-01

    Radioactivity: Olympic Games: dirty and decaying? Awards: SciCast rewards the best in scientific short films Conference: Teachers conference is big in Boston Workshop: Experts and teachers mingle in Mexico Awards: Olympiad holds lavish ceremony Cinema: Indiana Jones has a skull full of physics Conference: ESERA announces Turkish delight for 2009 Forthcoming Events

  19. News

    NASA Astrophysics Data System (ADS)

    2004-09-01

    Meeting: Brecon hosts 'alternative-style' Education Group Conference Meeting: Schools' Physics Group meeting delivers valuable teaching update Saturn Mission: PPARC’s Saturn school resource goes online Funding: Grant scheme supports Einstein Year activities Meeting: Liverpool Teachers’ Conference revives enthusiasm for physics Loan Scheme: Moon samples loaned to schools Awards: Schoolnet rewards good use of ICT in learning Funding: PPARC provides cash for science projects Workshop: Experts in physics education research share knowledge at international event Bulgaria: Transit of Venus comes to town Conference: CERN weekend provides lessons in particle physics Summer School: Teachers receive the summer-school treatment

  20. News

    NASA Astrophysics Data System (ADS)

    2003-11-01

    Resources: Online schools video library GIREP Seminar: A seminar not a conference New Teaching Resource: Free living for teachers Space: NASA proposes MEER - Momentum Exchange Electrodynamic-Reboost Electronic Teaching Materials: Superconductivity motivates need for upper secondary curriculum subjects Gifted and Talented: Seminars seek challenges Space: Comet chasing Particle Physics: Playing with single electrons Physics on Stage: Teachers explore the meaning of life Physics on Stage: Greek national event Physics on Stage: Physics on the Slovak stage Physics on Stage: Clubbing in Germany Physics on Stage: The Sun's star performance Higher Education: Physics: so refreshing USA: Broadening the Base AAPT Summer Meeting: US teachers in good form Astronomy: High school astronomy in the Czech Republic Space: Express to Mars Particle Physics: Journey to the centre of the Earth? ASE 2004: Flight from the ASE Physics Songs: A powerful melody Teacher Training: European training looks for ideal model

  1. News

    NASA Astrophysics Data System (ADS)

    2004-05-01

    SHAP Awards: SHAP students come out on top APECS Seminar: Able Pupils Experience Challenging Science project gets support SHAP Awards : Teachers get awards too Institute Awards: Musical squares: musical pair continue to share their adventures in sound Meeting: Rugby School hosts Schools’ Physics Group Meeting Germany: German didactics group puts on a full programme for spring meeting Radio Communication: GB4FUN: mobile radio shack hits the airwaves and is a hit with schools Saturn: Cassini Huygens mission: Saturn here we come! World Year of Physics: Conference continues with its preparations for 2005 Resources: New resources on radioactive materials available JG was supported by KBN grant no 2 P03A 020 24.

  2. News

    NASA Astrophysics Data System (ADS)

    Davenhall, Clive

    2012-06-01

    Herschel papers catalogued and accessible; Maskelyne papers accepted for the nation; centenary of the Hamburg Observatory; oldest astrologer's board found; Groupe Flammarion sold; ancient sundial found; keeping time (modern folk song about John Harrison).

  3. News

    NASA Astrophysics Data System (ADS)

    2006-07-01

    Einstein Year: Argentina remembers Einstein’s visit Health and Beauty: The sweet smell of fragrant molecules Austria: Physics and society top the bill Canada: Innovative teaching strategies pave the way for modern physics Publications: New online journal lets young scientists speak for themselves Forthcoming Events

  4. News

    NASA Astrophysics Data System (ADS)

    2002-09-01

    11-14 Curriculum: Supporting Physics Teaching (11-14) Europe: Sci-tech couldn't be without it! Art-Science: Makrolab in Mountain Year Digital Curriculum: Should the BBC learn from the past? Scotland: Teachers get Rocket Science Malaysia: Controversy over the language medium for science teaching UK Science: Next stage of Science Year announced Special Educational Needs: Science for special needs students Folk Physics: Good vibrations Environment: IoM3 - a move towards sustainability? UK Primary Science: The threat of afternoon science

  5. O/W nano-emulsion formation using an isothermal low-energy emulsification method in a mixture of polyglycerol polyricinoleate and hexaglycerol monolaurate with glycerol system.

    PubMed

    Wakisaka, Satoshi; Nishimura, Takahisa; Gohtani, Shoichi

    2015-01-01

    We investigated how phase behavior changes by replacing water with glycerol in water/mixture of polyglycerol polyricinoleate (PGPR) and hexaglycerol monolaurate (HGML) /vegetable oil system, and studied the effect of glycerol on o/w nano-emulsion formation using an isothermal low-energy method. In the phase behavior study, the liquid crystalline phase (Lc) + the sponge phase (L3) expanded toward lower surfactant concentration when water was replaced with glycerol in a system containing surfactant HLP (a mixture of PGPR and HGML). O/W nano-emulsions were formed by emulsification of samples in a region of Lc + L3. In the glycerol/surfactant HLP/vegetable oil system, replacing water with glycerol was responsible for the expansion of a region containing Lc + L3 toward lower surfactant concentration, and as a result, in the glycerol/surfactant HLP/vegetable oil system, the region where o/w nano-emulsions or o/w emulsions could be prepared using an isothermal low-energy emulsification method was wide, and the droplet diameter of the prepared o/w emulsions was also smaller than that in the water/surfactant HLP/vegetable oil system. Therefore, glycerol was confirmed to facilitate the preparation of nano-emulsions from a system of surfactant HLP. Moreover, in this study, we could prepare o/w nano-emulsions with a simple one-step addition of water at room temperature without using a stirrer. Thus, the present technique is highly valuable for applications in several industries. PMID:25766932

  6. 31 CFR 515.573 - Transactions by news organizations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Transactions by news organizations... Licenses, Authorizations, and Statements of Licensing Policy § 515.573 Transactions by news organizations... operation of news bureaus in Cuba whose primary purpose is the gathering and dissemination of news to...

  7. 16 CFR 1012.6 - The news media.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 16 Commercial Practices 2 2013-01-01 2013-01-01 false The news media. 1012.6 Section 1012.6... PERSONNEL AND OUTSIDE PARTIES § 1012.6 The news media. The Agency recognizes that the news media occupy a... inherently public nature of the news media allows their activities to be exempt from the requirements of...

  8. 16 CFR 1012.6 - The news media.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 16 Commercial Practices 2 2012-01-01 2012-01-01 false The news media. 1012.6 Section 1012.6... PERSONNEL AND OUTSIDE PARTIES § 1012.6 The news media. The Agency recognizes that the news media occupy a... inherently public nature of the news media allows their activities to be exempt from the requirements of...

  9. 31 CFR 515.573 - Transactions by news organizations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Transactions by news organizations... Licenses, Authorizations, and Statements of Licensing Policy § 515.573 Transactions by news organizations... operation of news bureaus in Cuba whose primary purpose is the gathering and dissemination of news to...

  10. 16 CFR 1012.6 - The news media.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 16 Commercial Practices 2 2014-01-01 2014-01-01 false The news media. 1012.6 Section 1012.6... PERSONNEL AND OUTSIDE PARTIES § 1012.6 The news media. The Agency recognizes that the news media occupy a... inherently public nature of the news media allows their activities to be exempt from the requirements of...

  11. 31 CFR 515.573 - Transactions by news organizations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Transactions by news organizations... Licenses, Authorizations, and Statements of Licensing Policy § 515.573 Transactions by news organizations... operation of news bureaus in Cuba whose primary purpose is the gathering and dissemination of news to...

  12. Index to NASA news releases and speeches, 1993

    NASA Technical Reports Server (NTRS)

    1994-01-01

    This issue of the Index to NASA News Releases and Speeches contains a listing of news releases distributed by the Office of Public Affairs, NASA Headquarters, and a selected listing of speeches presented by members of the Headquarters staff during 1993. The index is arranged in six sections: subject index, personal names index, news release number index, accession number index, speeches, and news releases.

  13. Engagement with News Content in Online Social Networks

    ERIC Educational Resources Information Center

    Oeldorf-Hirsch, Anne

    2011-01-01

    Reports indicate that as the Internet is displacing traditional news sources, younger users continue to be disconnected from the news. Fortunately, the Internet provides new ways of sharing and discussing news stories with others through social networking sites such as Facebook, which may be important for engaging users in the news they read…

  14. 31 CFR 515.573 - Transactions by news organizations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Transactions by news organizations... Licenses, Authorizations, and Statements of Licensing Policy § 515.573 Transactions by news organizations... operation of news bureaus in Cuba whose primary purpose is the gathering and dissemination of news to...

  15. 31 CFR 515.573 - Transactions by news organizations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Transactions by news organizations... Licenses, Authorizations, and Statements of Licensing Policy § 515.573 Transactions by news organizations... operation of news bureaus in Cuba whose primary purpose is the gathering and dissemination of news to...

  16. 16 CFR 1012.6 - The news media.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false The news media. 1012.6 Section 1012.6... PERSONNEL AND OUTSIDE PARTIES § 1012.6 The news media. The Agency recognizes that the news media occupy a... inherently public nature of the news media allows their activities to be exempt from the requirements of...

  17. 16 CFR 1012.6 - The news media.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 16 Commercial Practices 2 2011-01-01 2011-01-01 false The news media. 1012.6 Section 1012.6... PERSONNEL AND OUTSIDE PARTIES § 1012.6 The news media. The Agency recognizes that the news media occupy a... inherently public nature of the news media allows their activities to be exempt from the requirements of...

  18. Index to NASA news releases and speeches, 1992

    NASA Technical Reports Server (NTRS)

    1993-01-01

    This issue of the Index to NASA News Releases and Speeches contains a listing of news releases distributed by the Office of Public Affairs, NASA Headquarters, and a selected listing of speeches presented by members of the Headquarters staff during 1992. The index is arranged in six sections: subject index, personal names index, news release number index, accession number index, speeches, and news releases.

  19. 26 CFR 49.4253-2 - Exemption for news services.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... collection of news for the public press or radio or television broadcasting or in the dissemination of news through the public press or by means of radio or television broadcasting; or (2) In the collection or..., press association, radio or television news broadcasting agency, or news ticker service, to any...

  20. Inter Press Service: News from the Third World.

    ERIC Educational Resources Information Center

    Giffard, C. Anthony

    A content analysis was undertaken of the files for one month of the Rome-based Inter Press Service (IPS), an international news agency specializing in the news relating to the Third World. The data suggested that IPS is indeed providing a different kind of news service from that of the traditional news agencies. More than three-quarters of the…

  1. The Role of Audiovisual Mass Media News in Language Learning

    ERIC Educational Resources Information Center

    Bahrani, Taher; Sim, Tam Shu

    2011-01-01

    The present paper focuses on the role of audio/visual mass media news in language learning. In this regard, the two important issues regarding the selection and preparation of TV news for language learning are the content of the news and the linguistic difficulty. Content is described as whether the news is specialized or universal. Universal…

  2. Uses and Values for News on Cable Television.

    ERIC Educational Resources Information Center

    Baldwin, Thomas F.; And Others

    1992-01-01

    Discusses cable television subscribers' perceptions and consumption patterns of television news and describes a survey that compared broadcast and cable television news viewing habits. Media dependency and media consumption are considered, attitudes toward news sources and the perceived monetary value of the Cable News Network (CNN) are studied,…

  3. Research of inverted emulsions properties on the base of new emulsifiers

    NASA Astrophysics Data System (ADS)

    Minaev, K.; Epikhin, A.; Novoseltsev, D.; Andropov, M.; Yanovsky, V.; Ulyanova, O.

    2014-08-01

    Emulsifiers on the base of tallol and ethanolamines derived acids have been researched in the paper. Electrical stability of emulsions drilling muds has been investigated. It is proved that synthesized emulsifiers according to emulsion stability can be divided into two groups. The first group is emulsifiers with high initial electrical stability but low emulsion stability under long-term storing, and the second group is emulsifiers with low electrical stability but with high emulsion stability. Emulsions flow characteristics have been researched. It is established that emulsifier on the base of ethanolamine provides better emulsion characteristics for drilling muds emulsions.

  4. Droplet migration in emulsion systems measured using MR methods.

    PubMed

    Hollingsworth, K G; Johns, M L

    2006-04-15

    The migration of emulsion droplets under shear flow remains a largely unexplored area of study, despite the existence of an extensive literature on the analogous problem of solid particle migration. A novel methodology is presented to track the shear-induced migration of emulsion droplets based on magnetic resonance imaging (MRI). The work is in three parts: first, single droplets of one Newtonian fluid are suspended in a second Newtonian fluid (water in silicone oil (PDMS)) and are tracked as they migrate within a Couette cell; second, the migration of emulsion droplets in Poiseuille flow is considered; third, water-in-silicone oil emulsions are sheared in a Couette cell. The effect of (a) rotational speed of the Couette, (b) the continuous phase viscosity, and (c) the droplet phase concentration are considered. The equilibrium extent of migration and rate of migration increase with rotational speed for two different emulsion systems and increased continuous phase viscosity, leads to a greater equilibrium extent of migration. The relationship between the droplet phase concentration and migration is however complex. These results for semi-concentrated emulsion systems and wide-gap Couette cells are not well described by existing models of emulsion droplet migration. PMID:16257005

  5. Stability of drug-carrier emulsions containing phosphatidylcholine mixtures.

    PubMed

    Trotta, Michele; Pattarino, Franco; Ignoni, Terenzio

    2002-03-01

    Lipid emulsion particles containing 10% of medium chain triglycerides were prepared using 2% w/w of a mixture 1:1 w/w of purified soya phosphatidylcholine and 2-hexanoyl phosphatidylcholine as emulsifier mixture, for use as drug carriers. The mean droplet sizes of emulsions, prepared using an Ultra Turrax or a high-pressure homogenizer, were about 288 and 158 nm, respectively, compared with 380 and 268 nm for emulsions containing lecithin, or 325 and 240 nm for those containing 6-phosphatidylcholine. The stability of the emulsions, determined by monitoring the decrease of a lipophilic marker at a specified level within the emulsion, and observing coalescence over time, was also greatly increased using the emulsifier mixture. The emulsion stability did not notably change in the presence of a model destabilizing drug, indomethacin. The use of a second hydrophilic surfactant to adjust the packing properties of the lecithin at the oil-water interface provided an increase in the stability of lipid emulsions, and this may be of importance in the formulation of drug delivery systems. PMID:11880004

  6. Nuclear research emulsion neutron spectrometry at the Little-Boy replica

    SciTech Connect

    Gold, R.; Roberts, J.H.; Preston, C.C.

    1985-10-01

    Nuclear research emulsions (NRE) have been used to characterize the neutron spectrum emitted by the Little-Boy replica. NRE were irradiated at the Little-Boy surface as well as approximately 2 m from the center of the Little-Boy replica using polar angles of 0/sup 0/, 30/sup 0/, 60/sup 0/ and 90/sup 0/. For the NRE exposed at 2 m, neutron background was determined using shadow shields of borated polyethylene. Emulsion scanning to date has concentrated exclusively on the 2-m, 0/sup 0/ and 2-m, 90/sup 0/ locations. Approximately 5000 proton-recoil tracks have been measured in NRE irradiated at each of these locations. Neutron spectra obtained from these NRE proton-recoil spectra are compared with both liquid scintillator neutron spectrometry and Monte Carlo calculations. NRE and liquid scintillator neutron spectra generally agree within experimental uncertainties at the 2-m, 90/sup 0/ location. However, at the 2-m, 0/sup 0/ location, the neutron spectra derived from these two independent experimental methods differ significantly. NRE spectra and Monte Carlo calculations exhibit general agreement with regard to both intensity as well as energy dependence. Better agreement is attained between theory and experiment at the 2-m, 90/sup 0/ location, where the neutron intensity is considerably higher. 14 refs., 18 figs., 11 tabs.

  7. Synthesis of Polystyrene-Silica Composite Particles via One-Step Nanoparticle-Stabilized Emulsion Polymerization

    NASA Astrophysics Data System (ADS)

    Dai, Lenore; Ma, Huan

    2009-03-01

    Polystyrene-silica core-shell composite particles are prepared by one-step emulsion polymerization with a nonionic initiator VA-086, solely stabilized by silica nanoparticles. The silica nanoparticles are successfully incorporated into as the shell, likely due to the fact that the nanoparticles are thermodynamically favorable to self-assemble and remain at the liquid-liquid interfaces during the emulsion polymerization. The silica content, determined by thermogravimetric analysis, is approximately 20 wt% in the composite particles. In addition, we further explore the polymerization mechanism by studying the particle growth as a function of initiator concentration and reaction time: when the silica/monomer ratio is increased from 0.83 wt% to 2.5 wt%, the particle size at 24 hour reaction time decreases for a fixed monomer amount, probably due to a larger number of nuclei at the initial stage of polymerization. Further increasing the initiator/monomer ratio to 4.2 wt% does not continually decrease the particle size, which may be limited by the stabilization provided by a fixed concentration of silica nanoparticles. The surface coverage also changes with initiator concentration and reaction time although the underlying mechanism is not fully understood.

  8. Development and validation of polymerized high internal phase emulsion monoliths coupled with HPLC and fluorescence detection for the determination of trace tetracycline antibiotics in environmental water samples.

    PubMed

    Du, Fuyou; Zheng, Xian; Sun, Lin; Qin, Qun; Guo, Lin; Ruan, Guihua

    2015-11-01

    A polymerized high internal phase emulsion monolith was used as a novel sorbent for solid-phase extraction coupled with high-performance liquid chromatography and fluorescence detection for the determination of oxytetracycline, tetracycline, doxycycline, and chlorotetracycline in environmental water samples. The polymerized high internal phase emulsion monolithic column was prepared by the in situ polymerization of the continuous phase of a high internal phase emulsion containing glycidyl methacrylate, styrene, and divinylbenzene in pipette tips, and then functionalized with iminodiacetic acid. The resulting monolith exhibited highly interconnected porosity and large surface areas, making it an excellent candidate as an solid-phase extraction sorbent for the enrichment of trace tetracycline antibiotics. Several factors affecting the extraction performance of polymerized high internal phase emulsion monoliths, including the pH of sample solution, the eluting solvents, the sample loading flow rate and volume, were investigated, respectively. Under the optimized conditions, the mean recoveries of oxytetracycline, tetracycline, doxycycline, and chlorotetracycline spiked in pond and farm wastewater samples ranged from 78.1 to 119.3% with relative standard deviation less than 15%. The detection limits (S/N = 3) of the proposed method were in the range of 51-137 pg/mL. This study demonstrated that the monolithic polymerized high internal phase emulsion would be promising solid-phase extraction sorbents in the extraction and proconcentration of trace analytes from complex samples. PMID:26331390

  9. Cold Heat Storage Characteristics of O/W-type Latent Heat Emulsion Including Continuum Phase of Water Treated with a Freezing Point Depression

    NASA Astrophysics Data System (ADS)

    Inaba, Hideo; Morita, Shin-Ichi

    This paper deals with flow and cold heat storage characteristics of the oil (tetradecane, C14H30, freezing point 278.9 K, Latent heat 229 kJ/kg)/water emulsion as a latent heat storage material having a low melting point. The test emulsion includes a water-urea solution as a continuum phase. The freezing point depression of the continuum phase permits enhancement of the heat transfer rate of the emulison, due to the large temperature difference between the latent heat storage material and water-urea solution. The velocity of emulsion flow and the inlet temperature of coolant in a coiled double tube heat exchanger are chosen as the experimental parameters. The pressure drop, the heat transfer coefficient of the emulsion in the coiled tube are measured in the temperture region over solid and liquid phase of the latent heat storage material. The finishing time of the cold heat storage is defined experimentally in the range of sensible and latent heat storage. It is clarified that the flow behavior of the emulsion as a non-Newtonian fluid has an important role in cold heat storage. The useful nondimentional correlation equations for the additional pressure loss coefficient, the heat transfer coefficient and the finishing time of the cold heat storage are derived in terms of Dean number and heat capacity ratio.

  10. Oil-in-oil emulsions stabilised solely by solid particles.

    PubMed

    Binks, Bernard P; Tyowua, Andrew T

    2016-01-21

    A brief review of the stabilisation of emulsions of two immiscible oils is given. We then describe the use of fumed silica particles coated with either hydrocarbon or fluorocarbon groups in acting as sole stabilisers of emulsions of various vegetable oils with linear silicone oils (PDMS) of different viscosity. Transitional phase inversion of emulsions, containing equal volumes of the two oils, from silicone-in-vegetable (S/V) to vegetable-in-silicone (V/S) occurs upon increasing the hydrophobicity of the particles. Close to inversion, emulsions are stable to coalescence and gravity-induced separation for at least one year. Increasing the viscosity of the silicone oil enables stable S/V emulsions to be prepared even with relatively hydrophilic particles. Predictions of emulsion type from calculated contact angles of a silica particle at the oil-oil interface are in agreement with experiment provided a small polar contribution to the surface energy of the oils is included. We also show that stable multiple emulsions of V/S/V can be prepared in a two-step procedure using two particle types of different hydrophobicity. At fixed particle concentration, catastrophic phase inversion of emulsions from V/S to S/V can be effected by increasing the volume fraction of vegetable oil. Finally, in the case of sunflower oil + 20 cS PDMS, the study is extended to particles other than silica which differ in chemical type, particle size and particle shape. Consistent with the above findings, we find that only sufficiently hydrophobic particles (clay, zinc oxide, silicone, calcium carbonate) can act as efficient V/S emulsion stabilisers. PMID:26549699

  11. Laboratory Investigations in Support of Carbon Dioxide-in-Water Emulsions Stabilized by Fine Particles for Ocean and Geologic Sequestration of Carbon Dioxide

    SciTech Connect

    Dan Golomb; David Ryan; Eugene Barry

    2007-01-08

    Since the submission of our last Semi-annual Report, dated September 2006, the research objectives of this Co-operative Agreement shifted toward geologic sequestration of carbon dioxide. In the period September 2006-February 2007, experiments were conducted in a High-Pressure Batch Reactor (HPBR) for creating emulsions of liquid carbon dioxide (/CO{sub 2})-in-water stabilized by fine particles for geologic sequestration of CO{sub 2}. Also, emulsions were created in water of a binary mixture of liquid carbon dioxide and liquid hydrogen sulfide (/H{sub 2}S), called Acid Gas (AG). This leads to the possibility of safe disposal of AG in deep geologic formations, such as saline aquifers. The stabilizing particles included pulverized limestone (CaCO{sub 3}), unprocessed flyash, collected by an electrostatic precipitator at a local coal-fired power plant, and pulverized siderite (FeCO{sub 3}). Particle size ranged from submicron to a few micrometers. The first important finding is that /CO{sub 2} and /H{sub 2}S freely mix as a binary liquid without phase separation. The next finding is that the mixture of /CO{sub 2} and /H{sub 2}S can be emulsified in water using fine particles as emulsifying agents. Such emulsions are stable over prolonged periods, so it should not be a problem to inject an emulsion into subterranean formations. The advantage of injecting an emulsion into subterranean formations is that it is denser than the pure liquid, therefore it is likely to disperse in the bottom of the geologic formation, rather than buoying upward (called fingering). In such a fashion, the risk of the liquids escaping from the formation, and possibly re-emerging into the atmosphere, is minimized. This is especially important for H{sub 2}S, because it is a highly toxic gas. Furthermore, the emulsion may interact with the surrounding minerals, causing mineral trapping. This may lead to longer sequestration periods than injecting the pure liquids alone.

  12. Metal-Silicate Differentiation from a Metal Pond Emulsion during Core Formation

    NASA Astrophysics Data System (ADS)

    Fleck, J.; Weeraratne, D. S.

    2011-12-01

    The terrestrial planets demonstrate a heavy bombardment of impacts in their early formation history. Impacts are violent, energetic collisions that may melt the surface and/or cause segregation of impactor material including silicates and liquid metal iron. Although theoretical studies have been done with conceptual models for metal diapir descent to form terrestrial planetary cores, physical or computer modeling studies are scarce due to the strong variations in physical properties between liquid metals and solid silicates. We use laboratory fluid experiments to study core formation processes using liquid metal gallium and high viscosity glucose syrup which provide the buoyancy ratios expected for planetary interiors and low Reynolds number flow dynamics. Preliminary results indicate that the physical process of sinking metal diapirs form trailing conduits that may drag low density surface magmatic material to the base of the mantle. The low density material collects, grows at the base of the box, and rises back to the surface. We compare two cases of a pond made of 1) liquid metal emulsion and 2) a smooth coalesced metal pond. We find that emulsion experiments entrain greater amounts of low density fluid to the base of the box. Once the metal diapir reaches the base, conduit material exhibits flow reversal to return buoyantly to the surface. In the case of coalesced liquid metal diapirs, low density conduit material returns to the surface through the pre-established conduit. In the emulsion diapir case, we observe the formation of a new thermo-chemical buoyant plume that grows, exits the conduit, and travels along a new pathway to the surface. Metal plume descent and chemical plume rise velocities are consistent with Stokes velocity. Estimates of metal-silicate plume sinking time and thermo-chemical plume rise time for terrestrial planetary interiors are provided. We suggest the observation of a thermo-chemical plume as a source for orogeny at the surface of

  13. High internal phase emulsion with double emulsion morphology and their templated porous polymer systems.

    PubMed

    Lei, Lei; Zhang, Qi; Shi, Shuxian; Zhu, Shiping

    2016-12-01

    This paper reports synthesis of the first high internal phase emulsion (HIPE) system with double emulsion (DE) morphology (HIPE-DE). HIPE is a highly concentrated but highly stable emulsion system, which has a dispersed/internal phase fraction over 74vol%. DE represents an emulsion system that hierarchically encapsulates two immiscible phases. The combination of HIPE and DE provides an efficient method for fabrication of complex structures. In this work, HIPE-DE having a water-in-oil-in-water (W/O/W) morphology has been prepared for the first time via a simple one-step emulsification method with poly(2-(diethylamino)ethyl methacrylate) (PDEA) microgel particles as Pickering stabilizer. An oil phase fraction up to 90vol% was achieved by optimizing the microgel concentration in aqueous phase. The mechanism of the DE formation has been elucidated. It was found that while PDEA microgels stabilized the oil droplets in water, small amount protonated DEA monomers acted as surfactant and formed water-containing micelles inside the oil droplets. It was demonstrated that the W/O/W HIPE-DE could be precisely converted into porous polymer structures. With styrene as the oil phase in W/O/W HIPE-DE, porous polystyrene particles were obtained upon polymerization. With dissolved acrylamide as the aqueous phase and toluene as the continuous phase, porous polyacrylamide matrixes were prepared. Elevating temperature required for polymerization did not change the W/O/W HIPE-DE morphologies. This simple approach provides a versatile platform for synthesis of a variety of porous polymer systems. PMID:27560496

  14. ATLAS-2 Video News Release

    NASA Technical Reports Server (NTRS)

    1993-01-01

    This NASA Kennedy Space Center (KSC) video presents a Marshall Space Flight Center-Television (MSFC-TV) news release describing the objectives of the Atmospheric Laboratory for Applications in Science-2 (ATLAS-2), which is being flown on STS-56. Dr. Tim Miller (Mission Scientist), Dr. Marsha Torr (Mission Scientist), and Teresa Vanhooser (Mission Manager) explain that the ATLAS-2 mission is being launched to study earth atmospheric interactions with the sun in general and how manmade chemicals and pollution are contributing to ozone depletion in our atmosphere in particular. Seven instruments comprise the core payload. ATLAS-2 is an integral part of the Spacelab contribution to NASA's Mission to Planet Earth and characterizes the chemical and physical components of Earth's middle atmosphere and the solar energy injected in the atmosphere, studies that began on ATLAS-1.

  15. ATLAS-1 Video News Release

    NASA Technical Reports Server (NTRS)

    1992-01-01

    Allen Kenitzer, from Marshall Space Flight Center (MSFC), narrates this NASA Kennedy Space Center video presenting a MSFC-Television news release describing the overall scientific objectives of the Atmospheric Laboratory for Applications in Science-1 (ATLAS-1) Spacelab mission. Byron Lichtenberg (NASA Science Astronaut) and Anthony O'Neil (ATLAS-1 Mission Manager) explain that the 13 sophisticated and complementary instruments carried in shuttle Atlantis' payload bay are designed to identify the chemical species in our atmosphere, to measure the Sun's energy falling on and entering the atmosphere, to study the behavior of charged particles in the electric and magnetic fields surrounding the earth, and to gather ultraviolet light from stars and galaxies. ATLAS-1 is the first Spacelab flight of the National Aeronautics and Space Administration's (NASA's) Mission to Planet Earth.

  16. Automated method of tracing proton tracks in nuclear emulsions

    NASA Astrophysics Data System (ADS)

    Ruan, Jin-lu; Li, Hong-yun; Song, Ji-wen; Zhang, Jian-fu; Chen, Liang; Zhang, Zhong-bing; Liu, Jin-liang; Liu, Lin-yue

    2015-07-01

    The low performance of the manual recognition of proton-recoil tracks in nuclear emulsions has limited its application to energy spectrum measurement of a pulsed neutron source. We developed an automated microscope system to trace proton-recoil tracks in nuclear emulsions. Given a start point on the proton track of interest, the microscope system can automatically trace and record the entire track using an image processing algorithm. Tests indicate that no interaction of the operator is needed in tracing the entire track. This automated microscope greatly reduces the labor of the operator and increases the efficiency of track data collection in nuclear emulsion.

  17. Protein Formulations for Emulsions and Solid-in-Oil Dispersions.

    PubMed

    Martins, Madalena; Loureiro, Ana; Azoia, Nuno G; Silva, Carla; Cavaco-Paulo, Artur

    2016-06-01

    Needs from medical and cosmetic areas have led to the design of novel nanosized emulsions and solid-in-oil dispersions of proteins. Here, we describe the production of those emulsions and dispersions using high-energy methodologies such as high-pressure homogenization or ultrasound. Recent work has resulted in new mechanistic insights related to the formation of protein emulsions and dispersions. The production method and composition of these formulations can determine major parameters such as size, stability, and functionality, and therefore their final application. Aqueous nanoemulsions of proteins can be used for drug delivery, while solid-in-oil dispersions are often used in transdermal applications. PMID:26996614

  18. Rheology and microstructure of magmatic emulsions - Theory and experiments

    NASA Technical Reports Server (NTRS)

    Stein, Daniel J.; Spera, Frank J.

    1992-01-01

    The rheological properties of a dilute mixture of melt plus vapor bubbles, referred to as emulsion, are investigated theoretically and in rheometric experiments on dilute viscous germanium dioxide emulsions at temperatures between 1100 and 1175 C and at 100 kPa pressure in a rotating rod rheometer at shear rates between 0.05/s and 7/s. The results indicate that the emulsions may be described by a power-law constitutive relation when observations cover a sufficient range of shear rates to resolve nonlinear flow.

  19. Powdery Emulsion Explosive: A New Excellent Industrial Explosive

    NASA Astrophysics Data System (ADS)

    Ni, Ouqi; Zhang, Kaiming; Yu, Zhengquan; Tang, Shujuan

    2012-07-01

    Powdery emulsion explosive (PEE), a new powdery industrial explosive with perfect properties, has been made using an emulsification-spray drying technique. PEE is composed of 91-92.5 wt% ammonium nitrate (AN), 4.5-6 wt% organic fuels, and 1.5-1.8 wt% water. Due to its microstructure as a water-in-oil (W/O) emulsion and low water content, it has excellent detonation performance, outstanding water resistance, reliable safety, and good application compared with other industrial explosives, such as ammonite, emulsion explosives, and ANFO.

  20. Transport and Retention of Emulsion Droplets in Sandy Porous Media

    NASA Astrophysics Data System (ADS)

    Esahani, S. G.; Muller, K.; Chapra, S. C.; Ramsburg, A.

    2014-12-01

    Emulsions are commonly used as amendments during remediation; yet, the processes controlling the distribution of droplets within the subsurface are not well understood. Given that inadequate spatial and/or temporal delivery of amendments often leads to ineffective treatment, there is a need to better understand emulsion transport. Experiments were conducted to evaluate the transport and retention of emulsion droplets in columns containing Ottawa sands. Breakthrough curves and deposition profiles from these experiments were interrogated using a mathematical model capable of describing attachment, detachment, and straining to begin to elucidate the physical processes controlling delivery. Emulsions were constructed by stabilizing soybean oil droplets within a continuous aqueous phase. Physical properties of the resulting oil-in-water emulsions were favorable for subsurface delivery (nominal properties: 1 g/mL density; 10 cP viscosity; and 1.5 μm droplet d50). Emulsions were introduced to the columns for approximately two pore volumes and followed by an extended flush of background solution. Effluent droplet size distributions did not vary significantly over the course of the experiment and remained similar to those measured for the influent emulsion. Emulsion breakthrough curves exhibited tailing, and deposition profiles were found to be hyper-exponential and unaffected by extended periods of background flow. Depending on emulsion composition and flow characteristics, 10-30% of the injected emulsion was retained on the sand suggesting a non-negligible influence on accessible porosity over the course of the experiment. Experimental results were further interpreted using a droplet transport model that accounts for temporal and spatial variation in porosity due to the retention of the emulsion droplets. At present the model assumes a uniform size distribution of inelastic emulsion droplets which are transported by advection and dispersion, and exchanged with the solid

  1. Process for emulsion flooding of petroleum reservoirs

    SciTech Connect

    Lepper, U.

    1984-12-18

    A process for emulsion flooding of petroleum reservoirs comprising injecting a thermodynamically stable microemulsion consisting of oil, a non-ionic surfactant and water which optionally contains salts dissolved in any desired concentrations, into an injection well; driving injected microemulsion bank through the reservoir by means of water which likewise may contain salts dissolved in any desired concentrations. The microemulsion bank in contact with the water driving the bank forms an excess phase with a high water content, a low surfactant content and low oil content, and has such a viscosity sufficient to prevent the penetration of the subsequent water into the microemulsion bank which would cause a decrease of its flowability and its ability to displace oil.

  2. Emulsion chamber observations and interpretation (HE 3)

    NASA Technical Reports Server (NTRS)

    Shibata, M.

    1986-01-01

    Experimental results from Emulsion Chamber (EC) experiments at mountain altitudes or at higher levels using flying carriers are examined. The physical interest in this field is concentrated on the strong interaction at the very high energy region exceeding the accelerator energy, also on the primary cosmic ray intensity and its chemical composition. Those experiments which observed cosmic ray secondaries gave information on high energy interaction characteristics through the analyses of secondary spectra, gamma-hadron families and C-jets (direct observation of the particle production occuring at the carbon target). Problems of scaling violation in fragmentation region, interaction cross section, transverse momentum of produced secondaries, and some peculiar features of exotic events are discussed.

  3. Recent applications of nuclear track emulsion

    NASA Astrophysics Data System (ADS)

    Mamatkulov, K. Z.; Ambřozová, I.; Artemenkov, D. A.; Bradnova, V.; Kamanin, D. V.; Kattabekov, R. R.; Majling, L.; Marey, A.; Ploc, O.; Rusakova, V. V.; Stanoeva, R.; Turek, K.; Zaitsev, A. A.; Zarubin, P. I.; Zarubina, I. G.

    2016-05-01

    Application of the nuclear track emulsion technique (NTE) in radioactivity and nuclear fission studies is discussed. It is suggested to use a HSP-1000 automated microscope for searching for a collinear cluster tri-partition of heavy nuclei implanted in NTE. Calibrations of α-particles and ion ranges in a novel NTE are carried out. Surface exposures of NTE samples to a Cf-252 source started. Planar events containing fragments and long-range α-particles as well as fragment triples only are studied. NTE samples are calibrated by ions Kr and Xe of energy of 1.2 and 3 A MeV. Use of the image recognition program "ImageJ" for obtaining characteristics of individual events and for events from the large scan area is presented.

  4. Electromagnetic Shower Reconstruction in Emulsion Cloud Chamber

    NASA Astrophysics Data System (ADS)

    Esposito, L. S.

    2006-04-01

    Atmospheric neutrino data from the MACRO, Soudan II and Super-Kamiokande experiments are consistent with the hypothesis of νμ → ντ oscillations. The OPERA experiment aims to prove definitively this hypothesis with the direct observation of ντ neutrinos in the νμ beam produced at CERN (CNGS). The apparatus, in construction at the Gran Sasso Underground Laboratory, is equipped with electronic detectors and a sensitive target. The target is highly segmented in units, bricks, composed of alternate nuclear emulsion plates and lead sheets. An algorithm to reconstruct electromagnetic showers in a brick was developed. The algorithm was optimized using experimental data from 1, 3 and 6 GeV electron exposures and cross-checked with detailed Monte Carlo simulations. Finally, a neural network was used as electron/pion separator.

  5. Wall slip and fluidity in emulsion flow

    NASA Astrophysics Data System (ADS)

    Paredes, José; Shahidzadeh, Noushine; Bonn, Daniel

    2015-10-01

    The microscopic origin of apparent wall slip is studied systematically using a confocal laser scanning microscope coupled to a rheometer. We obtain flow curves on a model emulsion from classical macroscopic measurements that are compared with flow curves obtained from microscopic measurements. By controlling the wetting properties of the shearing walls, we show that the characteristic length used in the so-called fluidity model, proposed by Goyon et al. [Nature (London) 454, 84 (2008), 10.1038/nature07026], can be understood in terms of roughness induced by adsorbed droplets on the surface. Additionally, we disentangle two different effects that contribute to the difference between micro- and macrorheology. Both effects manifest themselves as gap-dependent viscosities due to either the formation of a lubricating layer close to the shearing walls or cooperative effects when the flow is strongly confined. Finally, we show that the cooperative effects can also be translated into an effective slip velocity.

  6. Active Emulsions: Synchronization of Chemical Oscillators

    NASA Astrophysics Data System (ADS)

    Fraden, Seth

    2012-02-01

    We explore the dynamical behavior of emulsions consisting of nanoliter volume droplets of the oscillatory Belousov-Zhabotinsky (BZ) reaction separated by a continuous oil phase. Some of the aqueous BZ reactants partition into the oil leading to chemical coupling of the drops. We use microfluidics to vary the size, composition and topology of the drops in 1D and 2D. Addition of a light sensitive catalyst to the drops and illumination with a computer projector allows each drop to be individually perturbed. A variety of synchronous regimes are found that systematically vary with the coupling strength and whether coupling is dominated by activatory or inhibitory species. In 1D we observe in- and anti-phase oscillations, stationary Turing patterns in which drops stop oscillating, but form spatially periodic patterns of drops in the oxidized and reduced states, and more complex combinations of stationary and oscillatory drops. In 2D, the attractors are more complex and vary with network topology and coupling strength. For hexagonal lattices as a function of increasing coupling strength we observe right and left handed rotating oscillations, mixed oscillatory and Turing states and finally full Turing states. Reaction -- diffusion models based on a simplified description of the BZ chemistry and diffusion of messenger species reproduce a number of the experimental results. For a range of parameters, a simplified phase oscillator model provides an intuitive understanding of the complex synchronization patterns. [4pt] ``Coupled oscillations in a 1D emulsion of Belousov--Zhabotinsky droplets,'' Jorge Delgado, Ning Li, Marcin Leda, Hector O. Gonzalez-Ochoa, Seth Fraden and Irving R. Epstein, Soft Matter, 7, 3155 (2011).

  7. Physical chemistry of highly concentrated emulsions.

    PubMed

    Foudazi, Reza; Qavi, Sahar; Masalova, Irina; Malkin, Alexander Ya

    2015-06-01

    This review explores the physics underlying the rheology of highly concentrated emulsions (HCEs) to determine the relationship between elasticity and HCE stability, and to consider whether it is possible to describe all physicochemical properties of HCEs on the basis of a unique physical approach. We define HCEs as emulsions with a volume fraction above the maximum closest packing fraction of monodisperse spheres, φm=0.74, even if droplets are not of polyhedron shape. The solid-like rheological behavior of HCEs is characterized by yield stress and elasticity, properties which depend on droplet polydispersity and which are affected by caging at volume fractions about the jamming concentration, φj. A bimodal size distribution in HCEs diminishes caging and facilitates droplet movement, resulting in HCEs with negligible yield stress and no plateau in storage modulus. Thermodynamic forces automatically move HCEs toward the lowest free energy state, but since interdroplet forces create local minimums - points beyond which free energy temporarily increases before it reaches the global minimum of the system - the free energy of HCEs will settle at a local minimum unless additional energy is added. Several attempts have been undertaken to predict the elasticity of HCEs. In many cases, the elastic modulus of HCEs is higher than the one predicted from classical models, which only take into account spatial repulsion (or simply interfacial energy). Improved models based on free energy calculation should be developed to consider the disjoining pressure and interfacial rheology in addition to spatial repulsion. The disjoining pressure and interfacial viscoelasticity, which result in the deviation of elasticity from the classical model, can be regarded as parameters for quantifying the stability of HCEs. PMID:25869114

  8. Risk Analysis and the Construction of News.

    ERIC Educational Resources Information Center

    Wilkins, Lee; Patterson, Philip

    1987-01-01

    Explains that the news media commit fundamental errors of attribution in covering risk situations by (1) treating them as novelties, (2) failing to analyze the entire system, and (3) using insufficiently analytical language. (NKA)

  9. Market Size and TV News Values.

    ERIC Educational Resources Information Center

    Carroll, Raymond L.

    1989-01-01

    Compares the news values of small and major market television stations. Finds that major market stations place more emphasis on fires, crime, and accident, but also emphasize local government and politics. (MM)

  10. The TAO project: In the News

    Science.gov Websites

    05102016 Australian Broadcasting Corporation 05092016 AGU 05052016 BBC Radio 05022016 ScienceNews 04062016 Public Broadcasting System 03252016 Weather Underground 03...

  11. Emulsion Polymerization of Butyl Acrylate: Spin Trapping and EPR Study

    NASA Technical Reports Server (NTRS)

    Kim, S.; Westmoreland, D.

    1994-01-01

    The propagating radical in the emulsion polymerization reaction of butyl acrylate was detected by Electron Paramagnetic Resonance spectroscopy using two spin trapping agents, 2-methyl-2nitrosopropane and alpha -N-tert-butylnitrone.

  12. Stability and demulsification of emulsions stabilized by asphaltenes or resins.

    PubMed

    Xia, Lixin; Lu, Shiwei; Cao, Guoying

    2004-03-15

    Experimental data are presented to show the influence of asphaltenes and resins on the stability and demulsification of emulsions. It was found that emulsion stability was related to the concentrations of the asphaltene and resin in the crude oil, and the state of dispersion of the asphaltenes and resins (molecular vs colloidal) was critical to the strength or rigidity of interfacial films and hence to the stability of the emulsions. Based on this research, a possible emulsion minimization approach in refineries, which can be implemented utilizing microwave radiation, is also suggested. Comparing with conventional heating, microwave radiation can enhance the demulsification rate by an order of magnitude. The demulsification efficiency reaches 100% in a very short time under microwave radiation. PMID:14972628

  13. Dehydration of oil waste emulsions by means of flocculants

    SciTech Connect

    Gandurina, L.V.; Butseva, L.N.; Shtondina, V.S.

    1995-05-01

    Oil waste emulsions are formed in the course of pumping petroleum crudes and products and are collected from the surfaces of equipment in recirculating water systems and wastewater disposal facilities (oil separators, sand traps, oil traps, holding pits for accidental spills, settlers, ponds, sludge accumulators, and so on). Emulsions are also obtained in the course of cleaning equipment in crude oil desalting and dehydration units. Such emulsions are stable, structurized systems that are very resistant to dewatering by heating and settling in separator tanks. In order to break stabilized emulsions, i.e., in order to ensure complete coalescence of drops when they collide, it is not sufficient to increase the forces of mutual attraction of drops at the moment of collision; in addition, the protective shell must be either destroyed or weakened. Demulsifying agents, or surfactants, will displace the stabilizers. This report is concerned with demulsifier efficiency.

  14. Fluorescent-magnetic Janus particles prepared via seed emulsion polymerization.

    PubMed

    Kaewsaneha, Chariya; Bitar, Ahmad; Tangboriboonrat, Pramuan; Polpanich, Duangporn; Elaissari, Abdelhamid

    2014-06-15

    Anisotropic polymeric colloidal or Janus particles possessing simultaneous magnetic and fluorescent properties were successfully prepared via the swelling-diffusion or the in situ emulsion polymerization method. In the swelling-diffusion process, magnetic emulsions (an organic ferrofluid dispersed in aqueous medium) were synthesized and used for seeds of submicron magnetic Janus particles. After swelling the anisotropic particles obtained by 1-pyrene-carboxaldehyde fluorescent dye dissolved in tetrahydrofuran, well-defined fluorescent-magnetic Janus particles were produced. In the in situ emulsion polymerization, styrene monomer mixed with fluorescent dye monomers, i.e., 1-pyrenylmethyl methacrylate (PyMMA) or fluorescein dimethacrylate (FDMA), and an oil-soluble initiator (2,2'-azobis(2-isobutyronitrile)) were emulsified in the presence of magnetic seed emulsions. The confocal microscopic images showed the fluorescent-magnetic Janus particles with high fluorescent intensity when a fluorescent crosslinker monomer FDMA was employed. PMID:24767504

  15. Microfluidic production of multiple emulsions and functional microcapsules.

    PubMed

    Lee, Tae Yong; Choi, Tae Min; Shim, Tae Soup; Frijns, Raoul A M; Kim, Shin-Hyun

    2016-09-21

    Recent advances in microfluidics have enabled the controlled production of multiple-emulsion drops with onion-like topology. The multiple-emulsion drops possess an intrinsic core-shell geometry, which makes them useful as templates to create microcapsules with a solid membrane. High flexibility in the selection of materials and hierarchical order, achieved by microfluidic technologies, has provided versatility in the membrane properties and microcapsule functions. The microcapsules are now designed not just for storage and release of encapsulants but for sensing microenvironments, developing structural colours, and many other uses. This article reviews the current state of the art in the microfluidic-based production of multiple-emulsion drops and functional microcapsules. The three main sections of this paper discuss distinct microfluidic techniques developed for the generation of multiple emulsions, four representative methods used for solid membrane formation, and various applications of functional microcapsules. Finally, we outline the current limitations and future perspectives of microfluidics and microcapsules. PMID:27470590

  16. Chemical Demulsification of Water-in-Crude Oil Emulsions

    NASA Astrophysics Data System (ADS)

    Abdurahman; Nour, H.; Mohd Yunus, Rosli; Jemaat, Zulkifly

    Demulsification (emulsion breaking) is necessary in many practical applications such as the petroleum industry, painting and waste-water treatment in environmental technology. Chemical demulsification is the most widely applied method of treating water-in-crude oil emulsions and involves the use of chemical additives to accelerate the emulsion breaking process. The effect of chemical demulsification operations on the stability and properties of water-in-crude oil emulsions was assessed experimentally. In this regard, Amine Demulsifier, Polyhydric Alcohol, Acid and Polymeric demulsifiers were used. Using samples of w/o, the data presented for several commercial-type demulsifiers show a strong connection (correlation) between good performance (fast coalescence) and the demulsifiers. The relative rates of water separation were characterized via beaker tests. The amine group demulsifiers promoted best coalescence of droplets. In contrast, polymeric demulsifier group is the least in water separation.

  17. Characterization and Demulsification of Water-in-crude Oil Emulsions

    NASA Astrophysics Data System (ADS)

    Nour, Abdurahman H.; Abu Hassan, Mohd A.; Mohd Yunus, Rosli

    Many advances have been made in the field of emulsions in recent years. Emulsion behavior is largely controlled by the properties of the adsorbed layers that stabilized the oil-water surfaces. The effect of chemical demulsifiers in demulsification of water-in-crude oil emulsions were assessed experimentally. The relative rates of water separation were characterized via graduated beakers. Four groups of demulsifier with different functional groups were used in this work namely amines, polyhydric alcohol, sulphonate and polymer. The effect of alcohol addition on demulsification performance also studied. The results obtained in this study have exposed the capability of chemical demulsifiers in destabilization of water-in-crude oil emulsions. Further works are nevertheless required to provide deeper understanding of the mechanisms involved to facilitate the development of an optimum system applicable to the industry.

  18. Protective effect of polysaccharides on the stability of parenteral emulsions.

    PubMed

    Chai, Guihong; Sun, Feng; Shi, Jianli; Tian, Bin; Tang, Xing

    2013-05-01

    The main purpose of this study is to investigate the influence of two polysaccharides (dextran, hydroxyethyl starch) on the stability of parenteral emulsions. All parenteral emulsions were prepared by high-pressure homogenization. The influence of polysaccharides concentration was studied. The stabilities of autoclaving sterilization, centrifugation and freeze-thawing process were investigated extensively. Following the addition of polysaccharides, the stabilities of the parenteral emulsions were improved. A high-concentration polysaccharides solution (13%, w/v) produced better protection than a low one (1.3%, w/v), especially during freeze-thawing process. The protective mechanisms of polysaccharides were attributed to increasing systematic viscosity, non-frozen water absorbed by polysaccharides, formation of a linear bead-like structure and thicker mixed emulsifier film. Overall, polysaccharides can offer greatly increased protection for parenteral emulsions, and represent a novel protective strategy for improving the stability of this delivery system. PMID:22583006

  19. Reduced Fat Food Emulsions: Physicochemical, Sensory, and Biological Aspects.

    PubMed

    Chung, Cheryl; Smith, Gordon; Degner, Brian; McClements, David Julian

    2016-03-11

    Fat plays multiple important roles in imparting desirable sensory attributes to emulsion-based food products, such as sauces, dressings, soups, beverages, and desserts. However, there is concern that over consumption of fats leads to increased incidences of chronic diseases, such as obesity, coronary heart disease, and diabetes. Consequently, there is a need to develop reduced fat products with desirable sensory profiles that match those of their full-fat counterparts. The successful design of high quality reduced-fat products requires an understanding of the many roles that fat plays in determining the sensory attributes of food emulsions, and of appropriate strategies to replace some or all of these attributes. This paper reviews our current understanding of the influence of fat on the physicochemical and physiological attributes of food emulsions, and highlights some of the main approaches that can be used to create high quality emulsion-based food products with reduced fat contents. PMID:25748819

  20. Polymer single crystal membrane from liquid/liquid interface

    NASA Astrophysics Data System (ADS)

    Wang, Wenda; Li, Christopher; Soft Matter Research Group-Drexel University Team

    2013-03-01

    Vesicles, mimicking the structure of cell membrane at the molecular scale, are small membrane-enclosed sacks that can store or transport substances. The weak mechanical properties and the nature of environment-sensitivity of the current available vesicles: liposomes, polymersomes, colloidsomes limit their applications as an excellent candidate for targeting delivery of drugs/genes in biomedical engineering and treatment. Recently, we developed an emulsion-based method to grow curved polymer single crystals. Varying the polymer concentration and/or the emulsification conditions (such as surfactant concentration, water-oil volume ratio), curved crystals with different sizes and different openness could be obtained. This growing process was attributed to polymer crystal growth along the liquid/liquid interface. In addition, the liquid/liquid interfacial crystal growth is promising for synthesis of enclosed hollow sphere.

  1. New York Times Current News Physics Applications

    NASA Astrophysics Data System (ADS)

    Cise, John

    2010-03-01

    Since 2007 I have been using NYTimes current News articles rich in graphics and physics variables for developing edited one page web (http://CisePhysics.homestead.com/files/NYT.htm) physics questions based on current events in the news. The NYTimes home page listed above contains currently ten pages with about 40 one page current edited News related physics articles per page containing: rich graphics, graphic editions by the author, edited articles, introduction to a question, questions, and answers. I use these web pages to introduce new physics concepts to students with current applications of concepts in the news. I also use these one page physics applications as pop quizzes and extra credit for students. As news happens(e.g. the 2010 Vancouver Olympics) I find the physics applications in the NYTimes articles and generate applications and questions. These new one page applications with questions are added to the home page: http://CisePhysics.homestead.com/files/NYT.htm The newest pages start with page 10 and work back in time to 9, 8, etc. The ten web pages with about 40 news articles per page are arranged in the traditional manner: vectors, kinematics, projectiles, Newton, Work & Energy, properties of matter, fluids, temperature, heat, waves, and sound. This site is listed as a resource in AAPT's Compadre site.

  2. Tocopherol and tocotrienol homologs in parenteral lipid emulsions

    PubMed Central

    Xu, Zhidong; Harvey, Kevin A; Pavlina, Thomas M; Zaloga, Gary P; Siddiqui, Rafat A

    2015-01-01

    Parenteral lipid emulsions, which are made of oils from plant and fish sources, contain different types of tocopherols and tocotrienols (vitamin E homologs). The amount and types of vitamin E homologs in various lipid emulsions vary considerably and are not completely known. The objective of this analysis was to develop a quantitative method to determine levels of all vitamin E homologs in various lipid emulsions. An HPLC system was used to measure vitamin E homologs using a Pinnacle DB Silica normal phase column and an isocratic, n-hexane:1,4 dioxane (98:2) mobile phase. An optimized protocol was used to report vitamin E homolog concentrations in soybean oil-based (Intralipid®, Ivelip®, Lipofundin® N, Liposyn® III, and Liposyn® II), medium- and long-chain fatty acid-based (Lipofundin®, MCT and Structolipid®), olive oil-based (ClinOleic®), and fish oil-based (Omegaven®) and mixture of these oils-based (SMOFlipid®, Lipidem®) commercial parenteral lipid emulsions. Total content of all vitamin E homologs varied greatly between different emulsions, ranging from 57.9 to 383.9 µg/mL. Tocopherols (α, β, γ, δ) were the predominant vitamin E homologs for all emulsions, with tocotrienol content < 0.3%. In all of the soybean emulsions, except for Lipofundin® N, the predominant vitamin E homolog was γ-tocopherol, which ranged from 57–156 µg/mL. ClinOleic® predominantly contained α-tocopherol (32 µg/mL), whereas α-tocopherol content in Omegaven® was higher than most of the other lipid emulsions (230 µg/mL). Practical applications The information on the types and quantity of vitamin E homologs in various lipid emulsions will be extremely useful to physicians and healthcare personnel in selecting appropriate lipid emulsions that are exclusively used in patients with inadequate gastrointestinal function, including hospitalized and critically ill patients. Some emulsions may require vitamin E supplementation in order to meet minimal human requirements

  3. Development of Nuclear Emulsion Detector for Muon Radiography

    NASA Astrophysics Data System (ADS)

    Nishio, A.; Morishima, K.; Kuwabara, K.; Nakamura, M.

    Muon radiography is the non-destructive testing technique of large-scale constructions with cosmic ray muon. Cosmic ray muon has high penetrating power and it always comes from the whole sky. In the same way of taking a X-ray photograph, we can obtain integrated density of constructions which thickness are several tens to several hundreds. We had ever applied this technique to nuclear reactors, volcanos, and so on. Nuclear emulsion is three dimensional track detector with micrometric position accuracy. Thanks to high position resolution, Nuclear emulsion has mrad angular resolution. In addition, the features which require no power supply and can observe in a large area suitable for muon radiography. In Nagoya University, we launched emulsion manufacturing equipment at 2010. It has become possible to flexible development of our detector and succeeded to development of high sensitive nuclear emulsion film (Nagoya emulsion). An important factor is the temperature characteristic to withstand the outdoor observation as a detector to be used in the muon radiography. There is a phenomenon of a latent image fading, whichit is well known in the photographic industry, and this phenomenon is known that temperature and water are involved. So we examined temperature and humidity characteristic of latent image fading about Nagoya emulsion. As a result, we found latent image fading is strongly depends on both temperature and humidity. By dehydrating emulsion film in RH8%, over 95% (Grain Density>40) detection efficiency of muon track keeps over 3months in 25degree, for 2months in 35degree. Additionally it was showed in this test that increasing back ground noise "fog", which may have occurred by sealing emulsion film in a narrow space, is reduced by buffer space in the bag.

  4. Enhanced reductive dechlorination in columns treated with edible oil emulsion

    NASA Astrophysics Data System (ADS)

    Long, Cameron M.; Borden, Robert C.

    2006-09-01

    The effect of edible oil emulsion treatment on enhanced reductive dechlorination was evaluated in a 14 month laboratory column study. Experimental treatments included: (1) emulsified soybean oil and dilute HCl to inhibit biological activity; (2) emulsified oil only; (3) emulsified oil and anaerobic digester sludge; and (4) continuously feeding soluble substrate. A single application of emulsified oil was effective in generating strongly reducing, anaerobic conditions for over 14 months. PCE was rapidly reduced to cis-DCE in all three live columns. Bioaugmentation with a halorespiring enrichment culture resulted in complete dechlorination of PCE to ethene in the soluble substrate column (yeast extract and lactate). However, an additional treatment with a pulse of yeast extract and bioaugmentation culture was required to stimulate complete dechlorination in the emulsion treated columns. Once the dechlorinating population was established, the emulsion only column degraded PCE from 90-120 μM to below detection with concurrent ethene production in a 33 day contact time. The lower biodegradation rates in the emulsion treated columns compared to the soluble substrate column suggest that emulsified oil barriers may require a somewhat longer contact time for effective treatment. In the HCl inhibited column, partitioning of PCE to the retained oil substantially delayed PCE breakthrough. However, reduction of PCE to more soluble degradation products ( cis-DCE, VC and ethene) greatly reduced the impact of oil-water partitioning in live columns. There was only a small decline in the hydraulic conductivity ( K) of column #1 (low pH + emulsion, Kfinal/ Kinitial = 0.57) and column #2 (live + emulsion, Kfinal/ Kinitial = 0.73) indicating emulsion injection did not result in appreciable clogging of the clayey sand. However, K loss was greater in column #3 (sludge +emulsion, Kfinal/ Kinitial = 0.12) and column #4 (soluble substrate, Kfinal/ Kinitial = 0.03) indicating clogging due

  5. Emulsion detectors for the antihydrogen detection in AEgIS

    NASA Astrophysics Data System (ADS)

    Pistillo, C.; Aghion, S.; Amsler, C.; Ariga, A.; Ariga, T.; Belov, A.; Bonomi, G.; Bräunig, P.; Bremer, J.; Brusa, R. S.; Cabaret, L.; Caccia, M.; Caravita, R.; Castelli, F.; Cerchiari, G.; Chlouba, K.; Cialdi, S.; Comparat, D.; Consolati, G.; Demetrio, A.; Derking, H.; Di Noto, L.; Doser, M.; Dudarev, A.; Ereditato, A.; Ferragut, R.; Fontana, A.; Gerber, S.; Giammarchi, M.; Gligorova, A.; Gninenko, S.; Haider, S.; Hogan, S.; Holmestad, H.; Huse, T.; Jordan, E. J.; Kawada, J.; Kellerbauer, A.; Kimura, M.; Krasnický, D.; Lagomarsino, V.; Lehner, S.; Malbrunot, C.; Mariazzi, S.; Matveev, V.; Mazzotta, Z.; Nebbia, G.; Nédélec, P.; Oberthaler, M.; Pacifico, N.; Penasa, L.; Petráček, V.; Prelz, F.; Prevedelli, M.; Ravelli, L.; Riccardi, C.; Røhne, O.; Rosenberger, S.; Rotondi, A.; Sandaker, H.; Santoro, R.; Scampoli, P.; Simon, M.; Špaček, M.; Storey, J.; Strojek, I. M.; Subieta, M.; Testera, G.; Widmann, E.; Yzombard, P.; Zavatarelli, S.; Zmeskal, J.

    2015-08-01

    The AEgIS experiment at CERN aims to perform the first direct measurement of gravitational interaction between matter and antimatter by measuring the deviation of a cold antihydrogen beam in the Earth gravitational field. The design of the experiment has been recently updated to include emulsion films as position sensitive detector. The submicrometric position accuracy of emulsions leads indeed to a significant improvement of the experimental sensitivity. We present results of preliminary tests and discuss perspectives for the final measurement.

  6. Imaging contrast effects in alginate microbeads containing trapped emulsion droplets

    NASA Astrophysics Data System (ADS)

    Hester-Reilly, Holly J.; Shapley, Nina C.

    2007-09-01

    This study focuses on spherical microparticles made of cross-linked alginate gel and microcapsules composed of an oil-in-water emulsion where the continuous aqueous phase is cross-linked into an alginate gel matrix. We have investigated the use of these easily manufactured microbeads as contrast agents for the study of the flow properties of fluids using nuclear magnetic resonance imaging. Results demonstrate that combined spin-spin ( T2) relaxation and diffusion contrast in proton NMR imaging can be used to distinguish among rigid polymer particles, plain alginate beads, and alginate emulsion beads. Multi-echo CPMG spin-echo imaging indicates that the average spin-lattice ( T1) and spin-spin ( T2) relaxation times of the plain alginate and alginate emulsion beads are comparable. Meanwhile, diffusion-weighted imaging produces sharp contrast between the two types of alginate beads, due to restricted diffusion inside the embedded oil droplets of the alginate emulsion beads. While the signal obtained from most materials is severely attenuated under applied diffusion gradients, the alginate emulsion beads maintain signal strength. The alginate emulsion beads were added to a suspension and imaged in an abrupt, annular expansion flow. The emulsion beads could be clearly distinguished from the surrounding suspending fluid and rigid polystyrene particles, through either T2 relaxation or diffusion contrast. Such a capability allows future use of the alginate emulsion beads as tracer particles and as one particle type among many in a multimodal suspension where detailed concentration profiles or particle size separation must be quantified during flow.

  7. Imaging contrast effects in alginate microbeads containing trapped emulsion droplets.

    PubMed

    Hester-Reilly, Holly J; Shapley, Nina C

    2007-09-01

    This study focuses on spherical microparticles made of cross-linked alginate gel and microcapsules composed of an oil-in-water emulsion where the continuous aqueous phase is cross-linked into an alginate gel matrix. We have investigated the use of these easily manufactured microbeads as contrast agents for the study of the flow properties of fluids using nuclear magnetic resonance imaging. Results demonstrate that combined spin-spin (T(2)) relaxation and diffusion contrast in proton NMR imaging can be used to distinguish among rigid polymer particles, plain alginate beads, and alginate emulsion beads. Multi-echo CPMG spin-echo imaging indicates that the average spin-lattice (T(1)) and spin-spin (T(2)) relaxation times of the plain alginate and alginate emulsion beads are comparable. Meanwhile, diffusion-weighted imaging produces sharp contrast between the two types of alginate beads, due to restricted diffusion inside the embedded oil droplets of the alginate emulsion beads. While the signal obtained from most materials is severely attenuated under applied diffusion gradients, the alginate emulsion beads maintain signal strength. The alginate emulsion beads were added to a suspension and imaged in an abrupt, annular expansion flow. The emulsion beads could be clearly distinguished from the surrounding suspending fluid and rigid polystyrene particles, through either T(2) relaxation or diffusion contrast. Such a capability allows future use of the alginate emulsion beads as tracer particles and as one particle type among many in a multimodal suspension where detailed concentration profiles or particle size separation must be quantified during flow. PMID:17600742

  8. Tunable Pickering emulsions with polymer-grafted lignin nanoparticles (PGLNs).

    PubMed

    Silmore, Kevin S; Gupta, Chetali; Washburn, Newell R

    2016-03-15

    Lignin is an abundant biopolymer that has native interfacial functions but aggregates strongly in aqueous media. Polyacrylamide was grafted onto kraft lignin nanoparticles using reversible addition-fragmentation chain transfer (RAFT) chemistry to form polymer-grafted lignin nanoparticles (PGLNs) that tune aggregation strength while retaining interfacial activities in forming Pickering emulsions. Polymer graft density on the particle surface, ionic strength, and initial water and cyclohexane volume fractions were varied and found to have profound effects on emulsion characteristics, including emulsion volume fraction, droplet size, and particle interfacial concentration that were attributed to changes in lignin aggregation and hydrophobic interactions. In particular, salt concentration was found to have a significant effect on aggregation, zeta potential, and interfacial tension, which was attributed to changes in solubility of both the kraft lignin and the polyacrylamide grafts. Dynamic light scattering, UV-vis spectroscopy, optical microscopy, and tensiometry were used to quantify emulsion properties and nanoparticle behavior. Under all conditions, the emulsions exhibited relatively fast creaming but were stable against coalescence and Ostwald ripening for a period of months. All emulsions were also oil-in-water (o/w) emulsions, as predicted by the Bancroft rule, and no catastrophic phase inversions were observed for any nanoparticle compositions. We conclude that lower grafting density of polyacrylamide on a lignin core resulted in high levels of interfacial activity, as characterized by higher concentration at the water-cyclohexane interface with a corresponding decrease in interfacial tension. These results indicate that the interfacial properties of polymer-grafted lignin nanoparticles are primarily due to the native hydrophobic interactions of the lignin core. These results suggest that the forces that drive aggregation are also correlated with interfacial

  9. Preparation of Pickering double emulsions using block copolymer worms.

    PubMed

    Thompson, Kate L; Mable, Charlotte J; Lane, Jacob A; Derry, Mathew J; Fielding, Lee A; Armes, Steven P

    2015-04-14

    The rational formulation of Pickering double emulsions is described using a judicious combination of hydrophilic and hydrophobic block copolymer worms as highly anisotropic emulsifiers. More specifically, RAFT dispersion polymerization was utilized to prepare poly(lauryl methacrylate)-poly(benzyl methacrylate) worms at 20% w/w solids in n-dodecane and poly(glycerol monomethacrylate)-poly(2-hydroxypropyl methacrylate)-poly(benzyl methacrylate) worms at 13% w/w solids in water by polymerization-induced self-assembly (PISA). Water-in-oil-in-water (w/o/w) double emulsions can be readily prepared with mean droplet diameters ranging from 30 to 80 μm using a two-stage approach. First, a w/o precursor emulsion comprising 25 μm aqueous droplets is prepared using the hydrophobic worms, followed by encapsulation within oil droplets stabilized by the hydrophilic worms. The double emulsion droplet diameter and number of encapsulated water droplets can be readily varied by adjusting the stirring rate employed during the second stage. For each stage, the droplet volume fraction is relatively high at 0.50. The double emulsion nature of the final formulation was confirmed by optical and fluorescence microscopy studies. Such double emulsions are highly stable to coalescence, with little or no change in droplet diameter being detected over storage at 20 °C for 10 weeks as judged by laser diffraction. Preliminary experiments indicate that the complementary o/w/o emulsions can also be prepared using the same pair of worms by changing the order of homogenization, although somewhat lower droplet volume fractions were required in this case. Finally, we demonstrate that triple and even quadruple emulsions can be formulated using these new highly anisotropic Pickering emulsifiers. PMID:25834923

  10. Preparation of Pickering Double Emulsions Using Block Copolymer Worms

    PubMed Central

    2015-01-01

    The rational formulation of Pickering double emulsions is described using a judicious combination of hydrophilic and hydrophobic block copolymer worms as highly anisotropic emulsifiers. More specifically, RAFT dispersion polymerization was utilized to prepare poly(lauryl methacrylate)–poly(benzyl methacrylate) worms at 20% w/w solids in n-dodecane and poly(glycerol monomethacrylate)–poly(2-hydroxypropyl methacrylate)–poly(benzyl methacrylate) worms at 13% w/w solids in water by polymerization-induced self-assembly (PISA). Water-in-oil-in-water (w/o/w) double emulsions can be readily prepared with mean droplet diameters ranging from 30 to 80 μm using a two-stage approach. First, a w/o precursor emulsion comprising 25 μm aqueous droplets is prepared using the hydrophobic worms, followed by encapsulation within oil droplets stabilized by the hydrophilic worms. The double emulsion droplet diameter and number of encapsulated water droplets can be readily varied by adjusting the stirring rate employed during the second stage. For each stage, the droplet volume fraction is relatively high at 0.50. The double emulsion nature of the final formulation was confirmed by optical and fluorescence microscopy studies. Such double emulsions are highly stable to coalescence, with little or no change in droplet diameter being detected over storage at 20 °C for 10 weeks as judged by laser diffraction. Preliminary experiments indicate that the complementary o/w/o emulsions can also be prepared using the same pair of worms by changing the order of homogenization, although somewhat lower droplet volume fractions were required in this case. Finally, we demonstrate that triple and even quadruple emulsions can be formulated using these new highly anisotropic Pickering emulsifiers. PMID:25834923

  11. Generation of colloidal granules and capsules from double emulsion drops

    NASA Astrophysics Data System (ADS)

    Hess, Kathryn S.

    Assemblies of colloidal particles are extensively used in ceramic processing, pharmaceuticals, inks and coatings. In this project, the aim was to develop a new technique to fabricate monodispersed colloidal assemblies. The use of microfluidic devices and emulsion processing allows for the fabrication of complex materials that can be used in a variety of applications. A microfluidic device is used to create monodispersed water/oil/water (w/o/w) double emulsions with interior droplets of colloidal silica suspension ranging in size from tens to hundreds of microns. By tailoring the osmotic pressure using glycerol as a solute in the continuous and inner phases of the emulsion, we can control the final volume size of the monodispersed silica colloidal crystals that form in the inner droplets of the double emulsion. Modifying the ionic strength in the colloidal dispersion can be used to affect the particle-particle interactions and crystal formation of the final colloidal particle. This w/o/w technique has been used with other systems of metal oxide colloids and cellulose nanocrystals. Encapsulation of the colloidal suspension in a polymer shell for the generation of ceramic-polymer core-shell particles has also been developed. These core-shell particles have spawned new research in the field of locally resonant acoustic metamaterials. Systems and chemistries for creating cellulose hydrogels within the double emulsions have also been researched. Water in oil single emulsions and double emulsions have been used to create cellulose hydrogel spheres in the sub-100 micron diameter range. Oil/water/oil double emulsions allow us to create stable cellulose capsules. The addition of a second hydrogel polymer, such as acrylate or alginate, further strengthens the cellulose gel network and can also be processed into capsules and particles using the microfluidic device. This work could have promising applications in acoustic metamaterials, personal care products, pharmaceuticals

  12. A Comparative Study of Proton-Emulsion and Heavy-Ion-Emulsion Interactions at 4.5 GeV/c per Nucleon

    NASA Astrophysics Data System (ADS)

    Ghosh, D.; Sengupta, R.; Ghosh, A.; Mukhopadhyay, A.; Roy, J.

    This paper presents a comparative study of inelastic interactions of proton-Emulsion, 12C-Emulsion and 24Mg-Emulsion at 4.5 GeV/c per nucleon. The multiplicity distribution and their correlations have been studied. A strong correlation between ns and nh in case of 24Mg-Emulsion and 12C-Emulsion is observed which is not so in the case of proton-Emulsion interaction. It is also observed that ns increases with the increase of the projectile mass. The angular distribution of the target fragments in 24Mg-Emulsion and 12C-Emulsion interactions show massive forward collimations. Comparison is also made in the pseudorapidity distributions of 24Mg-Emulsion, 12C-Emulsion and proton-Emulsion interactions. The result shows many interesting features.Translated AbstractEine vergleichende Studie der Proton-Emulsion-Schwerionen-Emulsionwechselwirkung bei 4,5 GeV/c pro NucleonDie inelastischen Wechselwirkungen von Protonen, 12C- und 24Mg-Ionen mit Emulsionen werden verglichen. Dazu wird die Multiplizitätsverteilung und ihre Korrelationen untersucht. Es kann gezeigt werden, daß die Zahl der Schauerpartikel im Falle der 12C-, 24Mg-Emulsionwechselwirkungen fest zur Zahl der hochionisierenden Partikel korreliert ist und mit der Projektilmasse wächst. Die Schwerionenexperimente zeigen eine vorwärts collimierte, räumliche Verteilung der Targetfragmente. Die Pscudorapiditätsverteilung wird in allen Experimenten untersucht.

  13. Characterization of paraffin oil emulsions stabilized by hydroxypropyl methylcellulose.

    PubMed

    Futamura, Taiki; Kawaguchi, Masami

    2012-02-01

    To study the relationship between emulsion stability and polymer emulsifier concentration, the preparation of paraffin oil emulsions by hydroxypropyl methylcellulose (HPMC) was carried out with HPMC concentrations below the overlapping concentration (C(*)) of HPMC. The stability of the emulsions incorporating HPMC was investigated by measuring the creaming velocity, volume fraction of emulsified paraffin oil, oil droplet size, and some rheological responses such as the stress-strain sweep curve and strain and frequency dependences of dynamic viscoelastic moduli. The paraffin oil was almost emulsified by HPMC above C(*)/20: the volume fraction of paraffin oil in the emulsion was higher than 0.72. Increasing in the HPMC concentration led to decreases in both the average oil droplet size and creaming velocity and an increase in the yield stress. All emulsions behaved as solid-like viscoelastic matter. Additionally, the measured dynamic storage moduli were compared with those calculated from a relationship based on functions of the volume fraction of oil in the emulsions and Laplace pressure; good agreement between the measured and calculated moduli was obtained. On the other hand, at HPMC concentrations below C(*)/50, the emulsified paraffin oil became unstable and the oil and the HPMC solution eventually separated. PMID:22138268

  14. Evaluation on oxidative stability of walnut beverage emulsions.

    PubMed

    Liu, Shuang; Liu, Fuguo; Xue, Yanhui; Gao, Yanxiang

    2016-07-15

    Walnut beverage emulsions were prepared with walnut kernels, mixed nonionic emulsifiers and xanthan gum. The effects of food antioxidants on the physical stability and lipid oxidation of walnut beverage emulsions were investigated. The results showed that tea polyphenols could not only increase the droplet size of the emulsions, but also enhance physical stability during the thermal storage at 62 ± 1 °C. However, water-dispersed oil-soluble vitamin E and enzymatically modified isoquercitrin obviously decreased the physical stability of the emulsion system during the thermal storage. BHT and natural antioxidant extract had scarcely influenced on the physical stability of walnut beverage emulsions. Tea polyphenols and BHT could significantly retard lipid oxidation in walnut beverage emulsions against thermal and UV light exposure during the storage. Vitamin E exhibited the prooxidant effect during the thermal storage and the antioxidant attribute during UV light exposure. Other food antioxidants had no significant effect on retarding lipid oxidation during thermal or light storage. PMID:26948632

  15. Demulsification of Redox-Active Emulsions by Chemical Oxidation.

    PubMed

    Takahashi, Yutaka; Koizumi, Nanami; Kondo, Yukishige

    2016-08-01

    This article reports the influence of redox reactions on emulsions of n-octane and an aqueous solution of a ferrocene-containing surfactant (FTMA; (11-ferrocenylundecyl)trimethylammonium bromide). Above a certain surfactant concentration, stable O/W emulsions were formed from an aqueous solution of reduced FTMA; in contrast, mixtures of n-octane and an aqueous solution of oxidized FTMA did not form emulsions at any surfactant concentration. Furthermore, adding an oxidant to the stable O/W emulsions of reduced FTMA led to coalescence of the oil (octane) droplets in the emulsions, and subsequently, the oil and water (aqueous FTMA solution) phases fully separated from the emulsions, i.e., demulsification occurred. Equilibrated interfacial tension measurements indicate that oxidation of the ferrocenyl group in FTMA brings about an increase in the interfacial tension between the octane and aqueous surfactant solution phases. From these results, we concluded that the oxidation of reduced FTMA to oxidized FTMA led to the desorption of surfactant molecules adsorbed at the interface of the octane/aqueous surfactant solution, leading to demulsification. PMID:27402350

  16. Droplet-based microfluidics and the dynamics of emulsions

    NASA Astrophysics Data System (ADS)

    Baret, Jean-Christophe; Brosseau, Quentin; Semin, Benoit; Qu, Xiaopeng

    2012-02-01

    Emulsions are complex fluids already involved for a long time in a wide-range of industrial processes, such as, for example, food, cosmetics or materials synthesis [1]. More recently, applications of emulsions have been extended to new fields like biotechnology or biochemistry where the compartmentalization of compounds in emulsion droplets is used to parallelise (bio-) chemical reactions [2]. Interestingly, these applications pinpoint to fundamental questions dealing with surfactant dynamics, dynamic surface tension, hydrodynamic interactions and electrohydrodynamics. Droplet-based microfluidics is a very powerful tool to quantitatively study the dynamics of emulsions at the single droplet level or even at the single interface level: well-controlled emulsions are produced and manipulated using hydrodynamics, electrical forces, optical actuation and combination of these effects. We will describe here how droplet-based microfluidics is used to extract quantitative informations on the physical-chemistry of emulsions for a better understanding and control of the dynamics of these systems [3].[4pt] [1] J. Bibette et al. Rep. Prog. Phys., 62, 969-1033 (1999)[0pt] [2] A. Theberge et al., Angewandte Chemie Int. Ed. 49, 5846 (2010)[0pt] [3] J.-C. Baret et al., Langmuir, 25, 6088 (2009)

  17. Stabilization Mechanisms of Water-in-Crude Oil Emulsions

    NASA Astrophysics Data System (ADS)

    Nour, Abdurahman H.; Suliman, A.; Hadow, Mahmmoud M.

    During the lifting and production of crude oil, water/oil emulsions are created. They are stabilized by asphaltenes and resins which are colloidally dispersed in the crude oil. Asphaltenes consist mainly of polar heterocompounds. It is known that they decrease the interfacial tension between oil and water and form stable interfacial films. Both effects favour the formation and stabilization of emulsions. Resins are complex high-molecular-weight compounds that are not soluble in ethylacetate, but are soluble in n-heptane. Their interfacial activity is less than that of asphaltenes. The role of resins in stabilizing emulsions has also been debated in literature. This study reports the results of experimental investigation of various factors affecting the stability of emulsions which are considered to be undesirable for a number of reasons, including both up-stream and down-stream operation in the petroleum industry. It was found that, the (R/A) ratio affects the emulsion and dispersion stabilities. High resin/asphaltene ratios decrease the emulsion stability.

  18. Fat overload syndrome after the rapid infusion of SMOFlipid emulsion.

    PubMed

    Hojsak, Iva; Kolaček, Sanja

    2014-01-01

    Fat overload syndrome is a well-known complication of intravenous lipid emulsion therapy. It is characterized by headaches, fever, jaundice, hepatosplenomegaly, respiratory distress, and spontaneous hemorrhage. Other symptoms include anemia, leukopenia, thrombocytopenia, low fibrinogen levels, and coagulopathy. Several reports in the literature describe fat overload syndrome caused by rapid infusion of lipid emulsions, all with soybean-based lipid emulsions. We report fat overload syndrome in a 2-year-old girl with short bowel syndrome on home parenteral nutrition. Fat overload syndrome occurred as a result of accidental, very rapid infusion of a 20% soy oil, medium-chain triglyceride, olive and fish oil-based lipid emulsion (SMOFlipid) that showed the same complications seen with an earlier lipid emulsion (Intralipid). The patient was successfully treated with supportive care combining fluid infusion, transfusion of platelets, and substitution of serum albumin (0.5 g/kg/d) and fresh-frozen plasma (10 mL/kg). In the next couple of days, she received extra platelets, erythrocyte transfusion, and filgrastim (Neupogen; 5 µg/kg/d) due to a very low leukocyte count. To the best of our knowledge, this is the first case of fat overload syndrome caused by SMOFlipid emulsion described in the literature. PMID:23520135

  19. Nanoparticle coated emulsions as novel dermal delivery vehicles.

    PubMed

    Eskandar, Nasrin Ghouchi; Simovic, Spomenka; Prestidge, Clive A

    2009-08-01

    The dermal delivery characteristics of hydrophilic silica nanoparticle coated medium chain triglyceride oil-in-water emulsions are reported and correlated with the physicochemical and interfacial properties of the emulsion based drug carriers. The synergistic drug/stabiliser/nanoparticle interactions are demonstrated to be a function of the charge and concentration of the initial emulsion stabiliser; charge and initial loading phase of nanoparticles and physicochemical properties of the drug molecule. The improved physical stability of the emulsions and the chemical stability of two model lipophilic agents (all-trans-retinol and acridine orange 10-nonyl bromide) confirm that engineered nanoparticle layers can enhance the shelf-life of liable lipophilic agents. Nanoparticle coatings are shown to control the in-vitro release of active agents from emulsions and significantly promote skin retention. The lipophilic agents distributed into the deeper viable skin layers without permeation through full-thickness skin and hence systemic exposure. Nanoparticle-coated submicron oil-in-water emulsions can serve as novel dermal carriers with controlled release kinetics and targeted drug delivery. PMID:19534710

  20. Physical and antimicrobial properties of thyme oil emulsions stabilized by ovalbumin and gum arabic.

    PubMed

    Niu, Fuge; Pan, Weichun; Su, Yujie; Yang, Yanjun

    2016-12-01

    Natural biopolymer stabilized oil-in-water emulsions were formulated using ovalbumin (OVA), gum arabic (GA) solutions and their complexes. The influence of interfacial structure of emulsion (OVA-GA bilayer and OVA/GA complexes emulsions) on the physical properties and antimicrobial activity of thyme oil (TO) emulsion against Escherichia coli (E. coli) was evaluated. The results revealed that the two types of emulsions with different oil phase compositions remained stable during a long storage period. The oil phase composition had an appreciable influence on the mean particle diameter and retention of the TO emulsions. The stable emulsion showed a higher minimum inhibitory concentration (MIC), and the TO emulsions showed an improved long-term antimicrobial activity compared to the pure thyme oil, especially complexes emulsion at pH 4.0. These results provided useful information for developing protection and delivery systems for essential oil using biopolymer. PMID:27374517

  1. News Archives: One-Stop Shopping, Boutique Hopping and the Specialty News Search Site.

    ERIC Educational Resources Information Center

    Paul, Nora

    1998-01-01

    Examines options for the researcher who wants to narrow canvassing of Web accessible material to just news-related articles. Discusses scout pages, meta-search pages, and news-only searches from World Wide Web search sites, then notes the benefits and problems for each. (AEF)

  2. Television News and Sexist Language: A Study of Television News Effects.

    ERIC Educational Resources Information Center

    Gebhardt, Randall E.; Harless, James D.

    To test the hypothesis that use of sexist language in television newscasts cultivates images of women as immature, frivolous, or incompetent, two television news anchors (one male, one female) were asked to tape versions of a news story involving a 28-year-old female lottery winner. In one version, each anchor referred to this female as "woman,"…

  3. News From Nowhere: Sources of International News in the Pacific Islands.

    ERIC Educational Resources Information Center

    Richstad, Jim; Nnaemeka, Tony

    A study was undertaken to examine the sources of international news in the Pacific Island press in the light of J. Galtung's structural theory of imperialism and to explore the relationship between the remoteness and isolation of the Pacific press and its sources of news. The Galtungian concepts of center-periphery and dominance-dependency were…

  4. An Exploratory Study of Relationships, News Releases and the News Media.

    ERIC Educational Resources Information Center

    Covington, William, Jr.; And Others

    News media and public relations professionals have a unique relationship that paradoxically combines both mutual reliance and mutual distrust. An exploratory study utilized symbolic interactionism and in-depth interviewing with news media personnel from four sites (a newspaper, a radio station, a television station, and a university) and a public…

  5. News Media Adversary and Consensus Roles, and Legislator Use of News Media for Job Information.

    ERIC Educational Resources Information Center

    Riffe, Daniel

    A study examined how Alabama legislators' ratings of news media for job-relevant information correlate with their views on news media adversary and consensus agent roles. Eighty-two questionnaires (out of 140 mailed) were completed by Alabama state representatives and senators for a return rate of 59%. Results suggested that lawmakers who believe…

  6. When People See News from a Non-Western Perspective: Cable News Network's "World Report."

    ERIC Educational Resources Information Center

    Stewart, Robert K.

    Much of what Americans "see" of the world is focused through the prism of the American news media. Broadcast journalists, in particular, provide the images that help shape viewers' ideas of the world. The recent introduction on U.S. television of Cable News Network's (CNN) "World Report" now provides the opportunity for American viewers to watch…

  7. Polymer Crystallization at Curved Liquid/Liquid Interface

    NASA Astrophysics Data System (ADS)

    Wang, Wenda

    Liquid/liquid interface, either flat or curved, is a unique template for studying self-assembly of a variety of nanomaterials such as nanoparticles and nanorods. The resultant monolayer films can be ordered or disordered depending on the regularity of the nanomaterials. Integration of nanoparticles into two-dimensional structure leads to intriguing collective properties of the nanoparticles. Crystallization can also be guided by liquid/liquid interface. Due to the particular shape of the interface, crystallization can happen in a different manner comparing to the normal solution crystallization. In this dissertation, liquid/liquid interface is employed to guide the crystallization of polymers, mainly focusing on using curved liquid/liquid interface. Due to the unique shape of the interface and feasibility to control the curvature, polymer crystallization can take place in different manner and lead to the formation of curved or vesicular crystals. Curved liquid/liquid interface is typically created through o/w emulsions. With the presence of surfactant, the emulsions are controlled to be stable at least for the polymer crystallization periods. The difference to normal solution crystallization is: the nuclei will diffuse to the curved interface due to the Pickering effect and guide the crystallization along the curved liquid/liquid interface. If the supercooling can be controlled to be very small, crystal growth in the bulk droplets can be avoided. The advantages of this strategy are: 1) the formation process of vesicular type crystals can be monitored by controlling the polymer supply; 2) curved crystals, bowl-like structures and enclosed capsules can be easily obtained comparing to the self-assembly method for vesicle formation; 3) the obtained vesicles will be made of polymer crystals, which will possess the extraordinary mechanical properties. Based on the nucleation type, this dissertation is divided into two parts. The first part is focused on the self

  8. Chemistry Is in the News: Taxonomy of authentic news media-based learning activities1

    NASA Astrophysics Data System (ADS)

    Glaser, Rainer E.; Carson, Kathleen M.

    2005-09-01

    A brief history is given of approaches that aim at achieving a connectedness of the content of organic chemistry courses to real world issues. Recently, such approaches have relied more and more on online media resources, the tools of the Internet and the World Wide Web. We propose a six-level taxonomy of ‘authentic news media-based learning activities’ to provide a conceptual framework for the description and discussion of such approaches. The Chemistry Is in the News project was designed to allow students to draw explicit connections between the course content and real world issues in ways that engage the students in a full range of cognitive skills. The activities consisted in the study, creation, and peer review of news portfolios by student collaborative groups. A news portfolio consists of an authentic news article taken from the popular press with interpretive comments and questions.

  9. Superparamagnetic polymer emulsion particles from a soap-free seeded emulsion polymerization and their application for lipase immobilization.

    PubMed

    Cui, Yanjun; Chen, Xia; Li, Yanfeng; Liu, Xiao; Lei, Lin; Zhang, Yakui; Qian, Jiayu

    2014-01-01

    Using emulsion copolymer of styrene (St), glycidyl methacrylate (GMA) and 2-hydroxyethyl methacrylate (HEMA) as seed latexes, the superparamagnetic polymer emulsion particles were prepared by seeded emulsion copolymerization of butyl methacrylate (BMA), vinyl acetate (VAc) and ethylene glycol dimethacrylate in the presence of the seed latexes and superparamagnetic Fe3O4/SiOx nanoparticles (or Fe3O4-APTS nanoparticles) through a two-step process, without addition of any emulsifier. The magnetic emulsion particles named P(St-GMA-HEMA)/P(BMA-VAc) were characterized by transmission electron microscope and vibrating sample magnetometry. The results showed that the magnetic emulsion particles held a structure with a thinner shell (around 100 nm) and a bigger cavity (around 200 nm), and possessed a certain level of magnetic response. The resulting magnetic emulsion particles were employed in the immobilization of lipase by two strategies to immobilized lipase onto the resulting magnetic composites directly (S-1) or using glutaraldehyde as a coupling agent (S-2), thus, experimental data showed that the thermal stability and reusability of immobilized lipase based on S-2 were higher than that of S-1. PMID:24114322

  10. Asphaltene and solids-stabilized water-in-oil emulsions

    NASA Astrophysics Data System (ADS)

    Sztukowski, Danuta M.

    Water-in-crude oil emulsions are a problem in crude oil production, transportation, and processing. Many of these emulsions are stabilized by asphaltenes and native oilfield solids adsorbed at the oil-water interface. Design of effective emulsion treatments is hampered because there is a lack of understanding of the role asphaltenes and solids play in stabilizing these emulsions. In this work, the structural, compositional and rheological properties of water/hydrocarbon interfaces were determined for model emulsions consisting of water, toluene, heptane, asphaltenes and native oilfield solids. The characteristics of the interface were related to the properties of asphaltenes and native solids. Emulsion stability was correlated to interfacial rheology. A combination of vapour pressure osmometry, interfacial tension and emulsion gravimetric studies indicated that asphaltenes initially adsorb at the interface as a monolayer of self-associated molecular aggregates. It was demonstrated why it is necessary to account for asphaltene self-association when interpreting interfacial measurements. The interfacial area of Athabasca asphaltenes was found to be approximately 1.5 nm2 and did not vary with concentration or asphaltene self-association. Hence, more self-associated asphaltenes simply formed a thicker monolayer. The interfacial monolayer observed in this work varied from 2 to 9 nm in thickness. The asphaltene monolayer was shown to adsorb reversibly only at short interface aging times. The film gradually reorganizes at the interface to form a rigid, irreversibly adsorbed network. The elastic and viscous moduli can be modeled using the Lucassen-van den Tempel (LVDT) model when the aging time is less than 10 minutes. An increase in film rigidity can be detected with an increase in the total elastic modulus. Increased film rigidity was shown to reduce the rate of coalescence in an emulsion and increase overall emulsion stability (reduce free water resolution). The rate of

  11. Laboratory Investigations in Support of Carbon Dioxide-in-Water Emulsions Stabilized by Fine Particles for Ocean and Geologic Sequestration of Carbon Dioxide

    SciTech Connect

    Dan Golomb; Eugene Barry; David Ryan

    2006-07-08

    This semi-annual progress report includes our latest research on deep ocean sequestration of CO{sub 2}-in-Water (C/W) emulsions stabilized by pulverized limestone (CaCO{sub 3}). We describe a practical system that could be employed for the release of a dense C/W emulsion. The heart of the system is a Kenics-type static mixer. The testing and evaluation of a static mixer in the NETL High-Pressure Water Tunnel Facility was described in the previous semi-annual report. The release system could be deployed from a floating platform over the open ocean, or at the end of an off-shore pipe laying on the continental slope. Because the emulsion is much denser than ambient seawater, modeling shows that upon release the plume will sink much deeper from the injection point, increasing the sequestration time for CO{sub 2}. When released in the open ocean, a plume containing the output of a 500 MW{sub el} coal-fired power plant will typically sink hundreds of meters below the injection point. When released from a pipe on the continental shelf, the plume will sink about twice as much because of the limited entrainment of ambient seawater when the plume flows along the sloping seabed. Furthermore, the plume is slightly alkaline, not acidic. The disadvantage is that the creation of the emulsion requires significant amounts of pulverized limestone, on the order of 0.5-0.75 weight ratio of limestone to CO{sub 2}. While pulverized limestone with particle size appropriate for creating C/W emulsions can be purchased for $38 per ton, it is shown in this report that it may be more economic to purchase raw limestone from quarries and pulverize it in situ using grinding mills. In this case the major cost elements are the capital and operating costs of the grinding mills, resulting in a total cost of about $11 per ton of pulverized limestone, including the cost of raw material and shipping. Because we need approximately 0.75 ton of pulverized limestone per ton of liquid CO2 to create a stable

  12. Transport of ions through the oil phase of W(1)/O/W(2) double emulsions.

    PubMed

    Cheng, Jing; Chen, Jian-Feng; Zhao, Min; Luo, Qing; Wen, Li-Xiong; Papadopoulos, Kyriakos D

    2007-01-01

    Using a capillary video microscopy technique, the ion transport at liquid-liquid interfaces and through a surfactant-containing emulsion liquid membrane was visually studied by preparing a double emulsion globule within the confined space of a thin-walled, transparent, cylindrical microtube. NaCl and AgNO(3) were selected as the model reactants and were prepared to form a NaCl/AgNO(3) pair across the oil film. By observing and measuring the formed AgCl deposition, it was found that both Cl(-) and Ag(+) could transport through a thick oil film and Ag(+) was transported faster than Cl(-). Interestingly, the ion transport was significantly retarded when the oil film became extremely thin (<1 microm). The results suggested that the transport of ions mainly depends on the "reverse micelle transport" mechanism, in which reverse micelles with entrapped ions and water molecules can be formed in a thick oil film and their construction will get impeded if the oil film becomes extremely thin, leading to different ion transport rates in these two cases. The direction of ion transport depends on the direction of the osmotic pressure gradient across the oil film and the ion transport is independent of the oil film thickness in the investigated thick range. Ions with smaller Pauling radii are more easily entrapped into the formed reverse micelles and therefore will be transported faster through the oil film than bigger ions. Oil-soluble surfactants facilitate ion transport; however, too much surfactant in the oil film will slow down the ion migration. In addition, this study showed no support for the "molecular diffusion" mechanism of ion transport through oils. PMID:17064722

  13. Teachable Moments in the News - an Online Resource Solar System Science News

    NASA Astrophysics Data System (ADS)

    Vanhala, H. A. T.; Miller, E. A.; Goldstein, J. J.

    2004-12-01

    Teachable Moments in the News (www.challenger.org/tmn/) is an online resource developed at Challenger Center for Space Science Education that takes recent news stories related to Solar System science and places them in a context relevant to the grades K-12 science curriculum. Using stories such as the launch of the MESSENGER spacecraft to Mercury, Teachable Moments in the News is meant to provide a seamless pathway from the news desk to the classroom. For each news item, an overview of the story is provided, along with high-quality inquiry-based, standards-driven lessons and links to more in-depth articles. Teachable Moments in the News is also a great tool for scientists who wish to stay informed of the recent events in Solar System exploration. The archived back issues of the quarterly published Web digest allow for a quick refresher on the most important news stories over the past several months. The very accessible nature of the stories makes the resource valuable for college students, and even the general public, as a means to keep up-to-date about current developments in planetary astronomy. Furthermore, college and university teachers can easily adapt many of the lessons to fit into the curriculum of an undergraduate astronomy course. During the poster session, we welcome suggestions from the scientific community on ways to enhance the usefulness of Teachable Moments in the News. For example, researchers could form partnerships with Teachable Moments in the News to provide news stories on their current research to be featured on the Web site. We invite researchers interested in this education and public outreach tool to visit the poster and provide suggestions on how to make the resource work as effectively as possible.

  14. Fabrication of nano-emulsions by bursting bubble at a liquid-liquid interface

    NASA Astrophysics Data System (ADS)

    Feng, Jie; Roché, Matthieu; Vigolo, Daniele; Arnaudov, Luben; Stoyanov, Simeon; Stone, Howard A.

    2012-11-01

    Bubbles bursting at interfaces is a familiar everyday occurrence and plays a role in important processes of transport across interfaces. Here we demonstrate that the bursting of air bubbles at an air-oil-water interface in the presence of a surfactant and a co-surfactant leads to the dispersion of nano-droplets in water. Using high-speed imaging we investigate the mechanism for the dispersion of objects and show that small droplets detach from the boundary of the bubble towards the bulk water during collapse of the bubble. We also characterize the size and stability of the dispersed objects with dynamic light scattering and microscopy techniques. The observations indicate that a well-defined population of few-hundred-nm-sized droplets is produced by bubble bursting, along with a broad range of sizes above 1 μm. We propose that the dispersed objects are formed because of the rapid motion of the bubble interface during collapse. By varying experimental conditions, we show that the size of the droplets is influenced mainly by the amount of surfactant in the oil phase.

  15. Influence of the cooling liquid on surface quality characteristics in milling

    NASA Astrophysics Data System (ADS)

    Tampu, N. C.; Brabie, G.; Chirita, B. A.; Herghelegiu, E.; Radu, M. C.

    2015-11-01

    Cooling system and cooling liquid characteristics are among the main factors influencing surface quality and tool wear. The aim of this study is to analyse the effect of the cooling liquid, used in different concentrations and at different temperatures, on the quality of the surface layer processed by milling. In order to make this analysis a Minimum Quantity Lubrication (MQL) cooling device is used. Three different volumetric ratios were used to modify the concentration of the cooling fluid (25% water to 75% emulsion, 50% water to 50% emulsion, 75% water to 25% emulsion) and three different temperatures. The studies revealed that surface roughness can be correlated with the variation of the cooling liquid temperature while surface flatness can be correlated to both, cooling liquid temperature and concentration.

  16. The Morphology of Emulsion Polymerized Latex Particles

    DOE R&D Accomplishments Database

    Wignall, G. D.; Ramakrishnan, V. R.; Linne, M. A.; Klein, A.; Sperling, L. H.; Wai, M. P.; Gelman, R. A.; Fatica, M. G.; Hoerl, R. H.; Fisher, L. W.

    1987-11-01

    Under monomer starved feed conditions, emulsion polymerization of perdeuterated methyl methacrylate and styrene in the presence of preformed polymethylmethacrylate latexes resulted in particles with a core-shell morphology, as determined by small-angle neutron scattering (SANS) analysis for a hollow sphere. The locus of polymerization of the added deuterated monomer is therefore at the particle surface. In similar measurements a statistical copolymer of styrene and methyl methacrylate was used as seed particles for further polymerization of trideuteromethyl methacrylate. The resulting polymer latex was again shown to have a core-shell morphological structure as determined by SANS. SANS experiments were also undertaken on polystyrene latexes polymerized by equilibrium swelling methods, with deuterated polymer forming the first or second step. The experiments covered a molecular weight range of 6 x 10{sup 4} 10{sup 6} the molecular weights are consistent with the experimental errors, indicating that the deuterium labeled molecules are randomly distributed in the latex. These results led to the finding that the polymer chains were constrained in the latex particles by factors of 2 to 4 from the relaxed coil dimensions. For M < 10{sup 6} g/mol SANS gave zero angle scattering intensities much higher than expected on the basis of a random distribution of labeled molecules. Several models were examined, including the possible development of core-shell structures at lower molecular weights.

  17. The morphology of emulsion polymerized latex particles

    SciTech Connect

    Wignall, G.D.; Ramakrishnan, V.R.; Linne, M.A.; Klein, A.; Sperling, L.H.; Wai, M.P.; Gelman, R.A.; Fatica, M.G.; Hoerl, R.H.; Fisher, L.W.

    1987-11-01

    Under monomer starved feed conditions, emulsion polymerization of perdeuterated methyl methacrylate and styrene in the presence of preformed polymethylmethacrylate latexes resulted in particles with a core-shell morphology, as determined by small-angle neutron scattering (SANS) analysis for a hollow sphere. The locus of polymerization of the added deuterated monomer is therefore at the particle surface. In similar measurements a statistical copolymer of styrene and methyl methacrylate was used as seed particles for further polymerization of trideuteromethyl methacrylate. The resulting polymer latex was again shown to have a core-shell morphological structre as determined by SANS. SANS experiments were also undertaken on polystyrene latexes polymerized by equilibrium swelling methods, with deuterated polymer forming the first or second step. The experiments covered a molecular weight range of 6 x 10/sup 4/ < M < 6 x 10/sup 6/ g/mol. For M > 10/sup 6/ the molecular weights are consistent with the experimental errors, indicating that the deuterium labeled molecules are randomly distributed in the latex. These results led to the finding that the polymer chains were constrained in the latex particles by factors of 2 to 4 from the relaxed coil dimensions. For M < 10/sup 6/ g/mol SANS gave zero angle scattering intensities much higher than expected on the basis of a random distribution of labeled molecules. Several models were examined, including the possible development of core-shell structures at lower molecular weights. 25 refs., 6 figs., 3 tabs.

  18. Food-grade Pickering emulsions stabilised with solid lipid particles.

    PubMed

    Pawlik, Aleksandra; Kurukji, Daniel; Norton, Ian; Spyropoulos, Fotis

    2016-06-15

    Aqueous dispersions of tripalmitin particles (with a minimum size of 130 nm) were produced, via a hot sonication method, with and without the addition of food-grade emulsifiers. Depending on their relative size and chemistry, the emulsifiers altered the properties of the fat particles (e.g. crystal form, dispersion state and surface properties) by two proposed mechanisms. Firstly, emulsifiers modify the rate and/or extent of polymorphic transitions, resulting in the formation of fat crystals with a range of polarities. Secondly, the adsorption of emulsifiers at the particle interface modifies crystal surface properties. Such emulsifier-modified fat particles were then used to stabilise emulsions. As the behaviour of these particles was predisposed by the kind of emulsifier employed for their manufacture, the resulting particles showed different preferences to which of the emulsion phases (oil or water) became the continuous one. The polarity of the fat particles decreased as follows: Whey Protein Isolate > Soy Lecithin > Soy Lecithin + Tween 20 > Tween 20 > Polyglycerol Polyricinoleate > no emulsifier. Consequently, particles stabilised with WPI formed oil-in-water emulsions (O/W); particles stabilised solely with lecithin produced a highly unstable W/O emulsion; and particles stabilised with a mixture of lecithin and Tween 20 gave a stable W/O emulsion with drop size up to 30 μm. Coalescence stable, oil-continuous emulsions (W/O) with drop sizes between 5 and 15 μm were produced when the tripalmitin particles were stabilised with solely with Tween 20, solely with polyglycerol polyricinoleate, or with no emulsifier at all. It is proposed that the stability of the latter three emulsions was additionally enhanced by sintering of fat particles at the oil-water interface, providing a mechanical barrier against coalescence. PMID:27198879

  19. To Model Chemical Reactivity in Heterogeneous Emulsions, Think Homogeneous Microemulsions.

    PubMed

    Bravo-Díaz, Carlos; Romsted, Laurence Stuart; Liu, Changyao; Losada-Barreiro, Sonia; Pastoriza-Gallego, Maria José; Gao, Xiang; Gu, Qing; Krishnan, Gunaseelan; Sánchez-Paz, Verónica; Zhang, Yongliang; Dar, Aijaz Ahmad

    2015-08-25

    Two important and unsolved problems in the food industry and also fundamental questions in colloid chemistry are how to measure molecular distributions, especially antioxidants (AOs), and how to model chemical reactivity, including AO efficiency in opaque emulsions. The key to understanding reactivity in organized surfactant media is that reaction mechanisms are consistent with a discrete structures-separate continuous regions duality. Aggregate structures in emulsions are determined by highly cooperative but weak organizing forces that allow reactants to diffuse at rates approaching their diffusion-controlled limit. Reactant distributions for slow thermal bimolecular reactions are in dynamic equilibrium, and their distributions are proportional to their relative solubilities in the oil, interfacial, and aqueous regions. Our chemical kinetic method is grounded in thermodynamics and combines a pseudophase model with methods for monitoring the reactions of AOs with a hydrophobic arenediazonium ion probe in opaque emulsions. We introduce (a) the logic and basic assumptions of the pseudophase model used to define the distributions of AOs among the oil, interfacial, and aqueous regions in microemulsions and emulsions and (b) the dye derivatization and linear sweep voltammetry methods for monitoring the rates of reaction in opaque emulsions. Our results show that this approach provides a unique, versatile, and robust method for obtaining quantitative estimates of AO partition coefficients or partition constants and distributions and interfacial rate constants in emulsions. The examples provided illustrate the effects of various emulsion properties on AO distributions such as oil hydrophobicity, emulsifier structure and HLB, temperature, droplet size, surfactant charge, and acidity on reactant distributions. Finally, we show that the chemical kinetic method provides a natural explanation for the cut-off effect, a maximum followed by a sharp reduction in AO efficiency with

  20. Foam, emulsion and wetting films stabilized by polyoxyalkylated diethylenetriamine (DETA) polymeric surfactants.

    PubMed

    Khristov, Khr; Petkova, H; Alexandrova, L; Nedyalkov, M; Platikanov, D; Exerowa, D; Beetge, J

    2011-10-14

    This review explores three (A, B, C) polyoxyalkylated diethylenetriamine (DETA) polymeric surfactants belonging to the group of star-like polymers. They have a similar structure, differing only in the number of polymeric branches (4, 6 and 9 in the mentioned order). The differences in these surfactants' ability to stabilize foam, o/w/o and w/o/w emulsion and wetting films are evaluated by a number of methods summarized in Section 2. Results from the studies indicate that differences in polymeric surfactants' molecular structure affect the properties exhibited at air/water, oil/water and water/solid interfaces, such as the value of surface tension, interfacial tension, critical micelle concentration, degree of hydrophobicity of solid surface, etc. Foam, emulsion and wetting films stabilized by such surfactants also show different behavior regarding some specific parameters, such as critical electrolyte concentration, surfactant concentration for obtaining a stable film, film thickness value, etc. These observations give reasons to believe that model studies can support a comprehensive understanding of how the change in polymeric surfactant structure can impact thin liquid films properties. This may enable a targeted design of the macromolecular architecture depending on the polymeric surfactants application purpose. PMID:21807358