Science.gov

Sample records for original layered structure

  1. Origin of interfacial perpendicular magnetic anisotropy in MgO/CoFe/metallic capping layer structures

    PubMed Central

    Peng, Shouzhong; Wang, Mengxing; Yang, Hongxin; Zeng, Lang; Nan, Jiang; Zhou, Jiaqi; Zhang, Youguang; Hallal, Ali; Chshiev, Mairbek; Wang, Kang L.; Zhang, Qianfan; Zhao, Weisheng

    2015-01-01

    Spin-transfer-torque magnetic random access memory (STT-MRAM) attracts extensive attentions due to its non-volatility, high density and low power consumption. The core device in STT-MRAM is CoFeB/MgO-based magnetic tunnel junction (MTJ), which possesses a high tunnel magnetoresistance ratio as well as a large value of perpendicular magnetic anisotropy (PMA). It has been experimentally proven that a capping layer coating on CoFeB layer is essential to obtain a strong PMA. However, the physical mechanism of such effect remains unclear. In this paper, we investigate the origin of the PMA in MgO/CoFe/metallic capping layer structures by using a first-principles computation scheme. The trend of PMA variation with different capping materials agrees well with experimental results. We find that interfacial PMA in the three-layer structures comes from both the MgO/CoFe and CoFe/capping layer interfaces, which can be analyzed separately. Furthermore, the PMAs in the CoFe/capping layer interfaces are analyzed through resolving the magnetic anisotropy energy by layer and orbital. The variation of PMA with different capping materials is attributed to the different hybridizations of both d and p orbitals via spin-orbit coupling. This work can significantly benefit the research and development of nanoscale STT-MRAM. PMID:26656721

  2. Origin of interfacial perpendicular magnetic anisotropy in MgO/CoFe/metallic capping layer structures.

    PubMed

    Peng, Shouzhong; Wang, Mengxing; Yang, Hongxin; Zeng, Lang; Nan, Jiang; Zhou, Jiaqi; Zhang, Youguang; Hallal, Ali; Chshiev, Mairbek; Wang, Kang L; Zhang, Qianfan; Zhao, Weisheng

    2015-01-01

    Spin-transfer-torque magnetic random access memory (STT-MRAM) attracts extensive attentions due to its non-volatility, high density and low power consumption. The core device in STT-MRAM is CoFeB/MgO-based magnetic tunnel junction (MTJ), which possesses a high tunnel magnetoresistance ratio as well as a large value of perpendicular magnetic anisotropy (PMA). It has been experimentally proven that a capping layer coating on CoFeB layer is essential to obtain a strong PMA. However, the physical mechanism of such effect remains unclear. In this paper, we investigate the origin of the PMA in MgO/CoFe/metallic capping layer structures by using a first-principles computation scheme. The trend of PMA variation with different capping materials agrees well with experimental results. We find that interfacial PMA in the three-layer structures comes from both the MgO/CoFe and CoFe/capping layer interfaces, which can be analyzed separately. Furthermore, the PMAs in the CoFe/capping layer interfaces are analyzed through resolving the magnetic anisotropy energy by layer and orbital. The variation of PMA with different capping materials is attributed to the different hybridizations of both d and p orbitals via spin-orbit coupling. This work can significantly benefit the research and development of nanoscale STT-MRAM. PMID:26656721

  3. Origin of Structural Transformation in Mono- and Bi-Layered Molybdenum Disulfide

    NASA Astrophysics Data System (ADS)

    Sun, Xiaoli; Wang, Zhiguo; Li, Zhijie; Fu, Y. Q.

    2016-05-01

    Mono- and multi-layered molybdenum disulfide (MoS2) is considered to be one of the next generation anode materials for rechargeable ion batteries. Structural transformation from trigonal prismatic (2H) to octahedral (1T) upon lithium or sodium intercalation has been in-situ observed experimentally using transmission electron microscope during studies of their electrochemical dynamics processes. In this work, we explored the fundamental mechanisms of this structural transformation in both mono- and bi-layered MoS2 using density functional theory. For the intercalated MoS2, the Li and Na donate their electrons to the MoS2. Based on the theoretical analysis, we confirmed that, for the first time, electron transfer is dominant in initiating this structural transformation, and the results provide an in-depth understanding of the transformation mechanism induced by the electron doping. The critical values of electron concentrations for this structural transformation are decreased with increasing the layer thickness.

  4. Origin of Structural Transformation in Mono- and Bi-Layered Molybdenum Disulfide

    PubMed Central

    Sun, Xiaoli; Wang, Zhiguo; Li, Zhijie; Fu, Y. Q.

    2016-01-01

    Mono- and multi-layered molybdenum disulfide (MoS2) is considered to be one of the next generation anode materials for rechargeable ion batteries. Structural transformation from trigonal prismatic (2H) to octahedral (1T) upon lithium or sodium intercalation has been in-situ observed experimentally using transmission electron microscope during studies of their electrochemical dynamics processes. In this work, we explored the fundamental mechanisms of this structural transformation in both mono- and bi-layered MoS2 using density functional theory. For the intercalated MoS2, the Li and Na donate their electrons to the MoS2. Based on the theoretical analysis, we confirmed that, for the first time, electron transfer is dominant in initiating this structural transformation, and the results provide an in-depth understanding of the transformation mechanism induced by the electron doping. The critical values of electron concentrations for this structural transformation are decreased with increasing the layer thickness. PMID:27225416

  5. Origin of Structural Transformation in Mono- and Bi-Layered Molybdenum Disulfide.

    PubMed

    Sun, Xiaoli; Wang, Zhiguo; Li, Zhijie; Fu, Y Q

    2016-01-01

    Mono- and multi-layered molybdenum disulfide (MoS2) is considered to be one of the next generation anode materials for rechargeable ion batteries. Structural transformation from trigonal prismatic (2H) to octahedral (1T) upon lithium or sodium intercalation has been in-situ observed experimentally using transmission electron microscope during studies of their electrochemical dynamics processes. In this work, we explored the fundamental mechanisms of this structural transformation in both mono- and bi-layered MoS2 using density functional theory. For the intercalated MoS2, the Li and Na donate their electrons to the MoS2. Based on the theoretical analysis, we confirmed that, for the first time, electron transfer is dominant in initiating this structural transformation, and the results provide an in-depth understanding of the transformation mechanism induced by the electron doping. The critical values of electron concentrations for this structural transformation are decreased with increasing the layer thickness. PMID:27225416

  6. Origins of Igneous Layering

    NASA Astrophysics Data System (ADS)

    Marsh, Bruce

    Anyone who has ever seen a photo of a layered intrusion, let alone visited one first hand, or even seen a thin section from one, cannot help but be impressed by the stunning record of crystal growth and deposition. Such bodies stand as majestic monuments of undeniable evidence that intricate magmatic processes exist, processes that couple crystallization, convection, and crystal sorting to form rocks so highly ordered and beautiful that they are a wonder to behold. These are the altars to which petrologists must carry their conceived petrologic processes for approval.Although significant in number, the best layered intrusions seem to be found almost always in remote places. Their names, Bushveld, Muskox, Kiglapait, Stillwater, Duke Island, Skaergaard, Rhum, ring through igneous petrology almost as historic military battles (Saratoga, Antietam, Bull Run, Manassas, Gettysburg) do through American history. People who have worked on such bodies are almost folk heros: Wager, Deer, Brown, Jackson, Hess, Irvine, McBirney, Morse; these names are petrologic household words. Yet with all this fanfare and reverence, layered instrusions are nearly thought of as period pieces, extreme examples of what can happen, but not generally what does. This is now all changing with the increasing realization that these bodies are perhaps highly representative of all magmatic bodies. They are simply more dynamically complete, containing more of the full range of interactions, and of course, exposing a more complete record. They are one end of a spectrum containing lava flows, lava lakes, large sills, plutons, and layered intrusions. This book uniquely covers this range with an abundance of first-hand field observations and a good dose of process conceptualization, magma physics, and crystal growth kinetics.

  7. 'Blueberry' Layers Indicate Watery Origins

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This microscopic image, taken at the outcrop region dubbed 'El Capitan' near the Mars Exploration Rover Opportunity's landing site, reveals millimeter-scale (.04 inch-scale) layers in the lower portion. This same layering is hinted at by the fine notches that run horizontally across the sphere-like grain or 'blueberry' in the center left. The thin layers do not appear to deform around the blueberry, indicating that these geologic features are concretions and not impact spherules or ejected volcanic material called lapilli. Concretions are balls of minerals that form in pre-existing wet sediments. This image was taken by the rover's microscopic imager on the 29th martian day, or sol, of its mission. The observed area is about 3 centimeters (1.2 inches) across.

  8. Structured luminescence conversion layer

    DOEpatents

    Berben, Dirk; Antoniadis, Homer; Jermann, Frank; Krummacher, Benjamin Claus; Von Malm, Norwin; Zachau, Martin

    2012-12-11

    An apparatus device such as a light source is disclosed which has an OLED device and a structured luminescence conversion layer deposited on the substrate or transparent electrode of said OLED device and on the exterior of said OLED device. The structured luminescence conversion layer contains regions such as color-changing and non-color-changing regions with particular shapes arranged in a particular pattern.

  9. On the origin of rhythmic layering in layered gabbros

    NASA Astrophysics Data System (ADS)

    Wang, Z.; Zhang, J.

    2015-12-01

    Rhythmic layering of silicates (plagioclase, pyroxene and olivine), ilmenite and magnitite is a common feature in mafic-ultramafic intrusions. The origin of rhythmic layering has been hotly debated in the literatures. Proposed mechanisms include gravity differentiation, double-diffusive convection, oscillatory crystallization of magma, repeated injection and supplement of magma, etc. Here we provide detailed FTIR and EBSD studies on the water content and deformation microstructure of gabbros from the Panzhihua intrusion and experimentally deformed synthetic gabrros and magnetite aggregates with a volume ratio of 6:4. The FTIR analyses revealed a significant amount of hydroxyls in both clinopyroxene (411-775 ppm) and plagioclase (328-716 ppm), suggesting a high water content mantle plume source. The EBSD analyses show similar fabrics in constitutent minerals of natural and experimental specimens: a weak clinopyroxene fabric of (100) parallel to foliation and [001] parallel to lineation; a strong plagioclase fabric of (010) parallel to foliation and [100] parallel to lineation, a weak ilmenite fabric of (001) parallel to foliation and [hk0] parallel to lieantion; and a near random magnitite fabric. There is an obvious rhythmic layering in sheared gabrros and magnetite aggregates similar to natural observations. Our results revealed strong layer-parallel shearing deformation during the formation of the Panxi layered intructions. There is a significant strength contrast between gabbro and Fe-Ti oxides. We propose that the formation of the rhythmic layering in mafic-ultramafic intrusions is caused mainly by rheological stratification of Fe-Ti oxides and gabbros.

  10. The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials.

    PubMed

    Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander; Malik, Rahul; Kang, ShinYoung; Ceder, Gerbrand

    2016-07-01

    Lithium-ion batteries are now reaching the energy density limits set by their electrode materials, requiring new paradigms for Li(+) and electron hosting in solid-state electrodes. Reversible oxygen redox in the solid state in particular has the potential to enable high energy density as it can deliver excess capacity beyond the theoretical transition-metal redox-capacity at a high voltage. Nevertheless, the structural and chemical origin of the process is not understood, preventing the rational design of better cathode materials. Here, we demonstrate how very specific local Li-excess environments around oxygen atoms necessarily lead to labile oxygen electrons that can be more easily extracted and participate in the practical capacity of cathodes. The identification of the local structural components that create oxygen redox sets a new direction for the design of high-energy-density cathode materials. PMID:27325096

  11. Structural Origin of Overcharge-Induced Thermal Instability of Ni-Containing Layered-Cathodes for High-Energy-Density Lithium Batteries

    SciTech Connect

    Wu, L.; Nam, K.-W.; Wang, X.; Zhou, Y.; Zheng, J.-C.; Yang, X.-Q.; Zhu, Y.

    2011-08-04

    Using a combination of time-resolved X-ray diffraction (XRD), in situ transmission electron microscopy (TEM), and first principles calculations, we explore the structural origin of the overcharge induced thermal instability of two cathode materials, LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} and LiNi{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2}, which exhibit significant difference in thermal stabilities. Detailed TEM analysis reveals, for the first time, a complex core-shell-surface structure of the particles in both materials that was not previously detected by XRD. Structural comparison indicates that the overcharged Li{sub x}Ni{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} (x < 0.15) particles consist of a rhombohedral core, a spinel shell, and a rock-salt structure at the surface, while the overcharged Li{sub x}Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2} consists of a similar core-shell-surface structure but a very different CdI{sub 2}-type surface structure. The thermal instability of Li{sub x}Ni{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} can be attributed to the release of oxygen because of the rapid growth of the rock-salt-type structure on the surface during heating. In contrast, the CdI{sub 2}-type surface structure of the overcharged Li{sub x}Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2} particles delays the oxygen-release reaction to a much higher temperature resulting in better stability. These results gave deep insight into the relationship between the local structural changes and the thermal stability of cathode materials, which is vital to the development of new cathode materials for the next generation of lithium-ion batteries.

  12. Origin of hysteresis between charge and discharge processes in lithium-rich layer-structured cathode material for lithium-ion battery

    NASA Astrophysics Data System (ADS)

    Konishi, Hiroaki; Hirano, Tatsumi; Takamatsu, Daiko; Gunji, Akira; Feng, Xiaoliang; Furutsuki, Sho

    2015-12-01

    There is large hysteresis between charge and discharge curves in lithium-rich layer-structured cathode material, Li1.2Ni0.13Mn0.54Co0.13O2. The mechanism for hysteresis was examined by X-ray diffraction (XRD) and X-ray absorption fine structure (XAFS) measurement as a first step in solving this issue. XRD measurements clarified that there was hysteresis in the lattice parameter between charge and discharge processes. XAFS spectra indicated that transition metals were oxidized and reduced in the same potential region during charge and discharge processes. Oxygen was oxidized at higher potential than transition metals during charge process; however, the former was reduced at lower potential than the latter during discharge process. Therefore, large hysteresis of potential between charge and discharge processes in Li1.2Ni0.13Mn0.54Co0.13O2 was mainly related to the reaction which is compensated with redox of oxygen.

  13. Planetary Origin Evolution and Structure

    NASA Technical Reports Server (NTRS)

    Stevenson, David J.

    2005-01-01

    This wide-ranging grant supported theoretical modeling on many aspects of the formation, evolution and structure of planets and satellites. Many topics were studied during this grant period, including the evolution of icy bodies; the origin of magnetic fields in Ganymede; the thermal histories of terrestrial planets; the nature of flow inside giant planets (especially the coupling to the magnetic field) and the dynamics of silicate/iron mixing during giant impacts and terrestrial planet core formation. Many of these activities are ongoing and have not reached completion. This is the nature of this kind of research.

  14. Layered tektites - A multiple impact origin for the Australasian tektites

    NASA Astrophysics Data System (ADS)

    Wasson, J. T.

    1991-02-01

    The mechanisms proposed for the origin of tektites from the Australasian field are examined using neutron activation data for twenty layered tektites and six splash tektites of known and widely separated sites of a field greater than 1140 km in length. Evidence is presented indicating that the layered tektites formed as sheets or pools of melt. It is argued that their distribution across a field greater than 1140 km in length is inconsistent with their formation in a single crater, and that many impact craters are required to account for their distribution across such a large field.

  15. Tomographic reconstruction of layered tissue structures

    NASA Astrophysics Data System (ADS)

    Hielscher, Andreas H.; Azeez-Jan, Mohideen; Bartel, Sebastian

    2001-11-01

    In recent years the interest in the determination of optical properties of layered tissue structure has resurfaced. Applications include, for example, studies on layered skin tissue and underlying muscles, imaging of the brain underneath layers of skin, skull, and meninges, and imaging of the fetal head in utero beneath the layered structures of the maternal abdomen. In this work we approach the problem of layered structures in the framework of model-based iterative image reconstruction schemes. These schemes are currently developed to determine the optical properties inside tissue from measurement on the surface. If applied to layered structure these techniques yield substantial improvements over currently available semi-analytical approaches.

  16. Buffer layer for thin film structures

    DOEpatents

    Foltyn, Stephen R.; Jia, Quanxi; Arendt, Paul N.; Wang, Haiyan

    2006-10-31

    A composite structure including a base substrate and a layer of a mixture of strontium titanate and strontium ruthenate is provided. A superconducting article can include a composite structure including an outermost layer of magnesium oxide, a buffer layer of strontium titanate or a mixture of strontium titanate and strontium ruthenate and a top-layer of a superconducting material such as YBCO upon the buffer layer.

  17. Buffer layer for thin film structures

    DOEpatents

    Foltyn, Stephen R.; Jia, Quanxi; Arendt, Paul N.; Wang, Haiyan

    2010-06-15

    A composite structure including a base substrate and a layer of a mixture of strontium titanate and strontium ruthenate is provided. A superconducting article can include a composite structure including an outermost layer of magnesium oxide, a buffer layer of strontium titanate or a mixture of strontium titanate and strontium ruthenate and a top-layer of a superconducting material such as YBCO upon the buffer layer.

  18. The origin of rhythmic layering in the Cape Neddick Plutonic Complex, Maine

    SciTech Connect

    Shipley, J. . Dept. of Geology)

    1993-03-01

    The Cape Neddick Plutonic Complex located along the southwestern coast of Maine is a small layered gabbroic body. It contains four concentric gabbros of differing composition, From the center to the exterior these are Cortlandtitic, Anorthositic, Normal, and Pegmatitic gabbros. They vary slightly in the proportion of essential minerals; plagioclase, clinopyroxene, hornblende, and biotite [+-] opaques and olivine. Rhythmic layering is seen in all four gabbros. This layering is also concentric around the center of the complex. The best exposure of the layering is along the coast where non-graded and graded rhythmic layering is seen extensively in the Normal gabbro. Only non-graded layering is seen in the Anorthositic gabbro. Non-graded layers were sampled at two localities. One locality is on Cape Nubble Island in the Normal gabbro. The second locality is in the Anorthositic gabbro along the northern coast. The layers are roughly 5--8 cm in width and are continuous around the complex. They are identified on weathered surfaces as alternating bands of felsic and mafic minerals. Layers are not obvious in hand sample. Approximately 15--20 layers were sampled perpendicular to layering. Petrographic and geochemical studies will help constrain the origin of rhythmic layering in the Cape Neddick Complex. Crystal settling or structural processes seem highly unlikely due to the small distance between the layers and the fact that they are not graded. Possible models include multiple pulses of magma within the same magma chamber, density currents, or in situ fractionation by a nucleation-diffusion process. Modal and chemical analysis of mineral phases within individual layers will allow comparison of the bulk composition of each layer. Analysis of coexisting pyroxene and plagioclase can be used to estimate compositional variations in the parent liquid.

  19. Radiative Impacts of Elevated Aerosol Layers from Different Origins

    NASA Astrophysics Data System (ADS)

    Sauer, D. N.; Weinzierl, B.; Gasteiger, J.; Heimerl, K.

    2014-12-01

    Aerosol particles are omnipresent in the Earth's atmosphere and have important impacts on weather and climate by their effects on the atmospheric radiative balance. With the advent of more and more sophisticated representations of atmospheric processes in earth system models, the lack of reliable input data on aerosols leads to significant uncertainties in the prediction of future climate scenarios. In recent years large discrepancies in radiative forcing estimates from aerosol layers in modeling studies have been revealed emphasizing the need for detailed and systematic observations of aerosols. Airborne in-situ measurements represent an important pillar for validating both model results and retrievals of aerosol distributions and properties from remote sensing methods on global scales. However, detailed observations are challenging and therefore are subject to substantial uncertainties themselves. Here we use data from airborne in-situ measurements of elevated aerosol layers from various field experiments in different regions of the world. The data set includes Saharan mineral dust layers over Africa, the Atlantic Ocean and the Caribbean from the SALTRACE and the SAMUM campaigns as well as long-range transported biomass burning aerosol layers from wild fires in the Sahel region and North America measured over the tropical Atlantic Ocean, Europe and the Arctic detected during SAMUM2, CONCERT2011, DC3 and ACCESS 2012. We aim to characterize the effects of the measured aerosol layers, in particular with respect to ageing, mixing state and vertical structure, on the overall atmospheric radiation budget as well as local heating and cooling rates. We use radiative transfer simulations of short and long-wave radiation and aerosol optical properties derived in a consistent way from the in-situ observations of microphysical properties using T-matrix calculations. The results of this characterization will help to improve the parameterization of the effects of elevated

  20. Understanding the Origin of Enhanced Performances in Core-Shell and Concentration-Gradient Layered Oxide Cathode Materials.

    PubMed

    Song, Dawei; Hou, Peiyu; Wang, Xiaoqing; Shi, Xixi; Zhang, Lianqi

    2015-06-17

    Core-shell and concentration-gradient layered oxide cathode materials deliver superior electrochemical properties such as long cycle life and outstanding thermal stability. However, the origin of enhanced performance is not clear and seldom investigated until now. Here, a specific structured layered oxide (LiNi0.5Co0.2Mn0.3O2) consisting of concentration-gradient core, transition layer, and stable outer shell, is designed and achieved from double-shelled precursors to overcome the great challenge by comparison with the normal layered LiNi0.5Co0.2Mn0.3O2. As expected, the specific structured layered oxide displays excellent cycle life and thermal stability. After numerous cycles, the valence state of Ni and Co at normal layered oxide surface tends to a higher oxidation state than that of the specific structured oxide, and the spinel phase is observed on particle surface of normal layered oxide. Also, the deficient spinel/layered mixed phases lead to high surface film and charge-transfer resistance for normal layered oxide, whereas the specific structured one still remains a layered structure. Those results first illustrate the origin of improved electrochemical performance of layered core-shell and concentration-gradient cathode materials for lithium-ion batteries. PMID:26017733

  1. Layer like porous materials with hierarchical structure.

    PubMed

    Roth, Wieslaw J; Gil, Barbara; Makowski, Wacław; Marszalek, Bartosz; Eliášová, Pavla

    2016-06-13

    Many chemical compositions produce layered solids consisting of extended sheets with thickness not greater than a few nanometers. The layers are weakly bonded together in a crystal and can be modified into various nanoarchitectures including porous hierarchical structures. Several classes of 2-dimensional (2D) materials have been extensively studied and developed because of their potential usefulness as catalysts and sorbents. They are discussed in this review with focus on clays, layered transition metal oxides, silicates, layered double hydroxides, metal(iv) phosphates and phosphonates, especially zirconium, and zeolites. Pillaring and delamination are the primary methods for structural modification and pore tailoring. The reported approaches are described and compared for the different classes of materials. The methods of characterization include identification by X-ray diffraction and microscopy, pore size analysis and activity assessment by IR spectroscopy and catalytic testing. The discovery of layered zeolites was a fundamental breakthrough that created unprecedented opportunities because of (i) inherent strong acid sites that make them very active catalytically, (ii) porosity through the layers and (iii) bridging of 2D and 3D structures. Approximately 16 different types of layered zeolite structures and modifications have been identified as distinct forms. It is also expected that many among the over 200 recognized zeolite frameworks can produce layered precursors. Additional advances enabled by 2D zeolites include synthesis of layered materials by design, hierarchical structures obtained by direct synthesis and top-down preparation of layered materials from 3D frameworks. PMID:26489452

  2. Two layer structure for reinforcing pothole repair

    NASA Astrophysics Data System (ADS)

    Yuan, Wei; Yuan, Kuo-Yao; Zou, Linhua; Yang, Jenn-Ming; Ju, Jiann-Wen; Kao, Wei; Carlson, Larry

    2013-04-01

    We have applied dicyclopentadiene (DCPD) resin for reinforcing pothole patch materials due to its unique properties - low cost, low viscosity at beginning and ultra-toughness after curing, chemical compatibility with tar, tunable curing profile through catalyst design. In this paper, we have designed a two layer structure - well compacted base layer and DCPD reinforced 1-1.5" top layer - for pothole repair. By choosing two graded asphalt mixes, a porous top layer and fully compacted base layer was prepared after compaction and ready for DCPD resin infiltration. The DCPD curing and infiltration profile within this porous top layer was measured with thermocouples. The rutting resistance was tested with home-made wheel rutter. The cage effect due to the p-DCPD wrapping was characterized with wheel penetration test. The results showed that this two layer structure pothole repair has greatly improved properties and can be used for pothole repair to increase the service life.

  3. Simulation of plasma double-layer structures

    NASA Technical Reports Server (NTRS)

    Borovsky, J. E.; Joyce, G.

    1982-01-01

    Electrostatic plasma double layers are numerically simulated by means of a magnetized 2 1/2 dimensional particle in cell method. The investigation of planar double layers indicates that these one dimensional potential structures are susceptible to periodic disruption by instabilities in the low potential plasmas. Only a slight increase in the double layer thickness with an increase in its obliqueness to the magnetic field is observed. Weak magnetization results in the double layer electric field alignment of accelerated particles and strong magnetization results in their magnetic field alignment. The numerical simulations of spatially periodic two dimensional double layers also exhibit cyclical instability. A morphological invariance in two dimensional double layers with respect to the degree of magnetization implies that the potential structures scale with Debye lengths rather than with gyroradii. Electron beam excited electrostatic electron cyclotron waves and (ion beam driven) solitary waves are present in the plasmas adjacent to the double layers.

  4. Simulation of Sintering of Layered Structures

    SciTech Connect

    OLEVSKY,EUGENE; TIKARE,VEENA; GARINO,TERRY J.; BRAGINSKY,MICHAEL V.

    2000-11-22

    An integrated approach, combining the continuum theory of sintering and Potts model based mesostructure evolution analysis, is used to solve the problem of bi-layered structure sintering. Two types of bi-layered structures are considered: layers of the same material with different initial porosity, and layers of two different materials. The effective sintering stress for the bi-layer powder sintering is derived, both at the meso- and the macroscopic levels. Macroscopic shape distortions and spatial distributions of porosity are determined as functions of the dimensionless specific time of sintering. The effect of the thickness of the layers on shrinkage, warpage, and pore-grain structure is studied. Ceramic ZnO powders are employed as a model experimental system to assess the model predictions.

  5. The Kinematics of Turbulent Boundary Layer Structure

    NASA Technical Reports Server (NTRS)

    Robinson, Stephen Kern

    1991-01-01

    The long history of research into the internal structure of turbulent boundary layers has not provided a unified picture of the physics responsible for turbulence production and dissipation. The goals of the present research are to: (1) define the current state of boundary layer structure knowledge; and (2) utilize direct numerical simulation results to help close the unresolved issues identified in part A and to unify the fragmented knowledge of various coherent motions into a consistent kinematic model of boundary layer structure. The results of the current study show that all classes of coherent motion in the low Reynolds number turbulent boundary layer may be related to vortical structures, but that no single form of vortex is representative of the wide variety of vortical structures observed. In particular, ejection and sweep motions, as well as entrainment from the free-streem are shown to have strong spatial and temporal relationships with vortical structures. Disturbances of vortex size, location, and intensity show that quasi-streamwise vortices dominate the buffer region, while transverse vortices and vortical arches dominate the wake region. Both types of vortical structure are common in the log region. The interrelationships between the various structures and the population distributions of vortices are combined into a conceptual kinematic model for the boundary layer. Aspects of vortical structure dynamics are also postulated, based on time-sequence animations of the numerically simulated flow.

  6. Structure of the low latitude boundary layer

    NASA Technical Reports Server (NTRS)

    Sckopke, N.; Paschmann, G.; Haerendel, G.; Sonnerup, B. U. O.; Bame, S. J.; Forbes, T. G.; Hones, E. W., Jr.; Russell, C. T.

    1980-01-01

    Observations at high temporal resolution of the frontside magnetopause and plasma boundary layer, made with the LASL/MPE fast plasma analyzer onboard the ISEE 1 and 2 spacecraft, revealed a complex quasiperiodic structure of some of the observed boundary layers. A cool tailward streaming boundary layer plasma was seen intermittently, with intervening periods of hot tenuous plasma which has properties similar to the magnetospheric population. While individual encounters with the boundary layer plasma last only a few minutes, the total observation time may extend over one hour or more.

  7. Structure and origin of cometary nuclei

    NASA Technical Reports Server (NTRS)

    Donn, B.; Rahe, J.

    1981-01-01

    There is strong evidence that a comet nucleus consists of a single object whose basic structure is Whipple's icy conglomerate. A number of cometary phenomena indicate that the nucleus is a low density, fragile object with a large degree of radial uniformity in structure and composition. Details of the ice-dust pattern are more uncertain. A working model is proposed which is based on theories of accumulation of larger objects from grains. This nucleus is a distorted spherical aggregate of a hierarchy of ice-dust cometesimals. These cometesimals retain some separate identity which lead to comet fragmentation when larger components break off. The outer layers of new comets were modified by cosmic ray irradiation in the Oort Cloud. The evidence for meteorite-comet association is steill controversial. Current dynamical studies do not seem to require a cometary source of meteorites.

  8. Origin of voltage decay in high-capacity layered oxide electrodes

    NASA Astrophysics Data System (ADS)

    Sathiya, M.; Abakumov, A. M.; Foix, D.; Rousse, G.; Ramesha, K.; Saubanère, M.; Doublet, M. L.; Vezin, H.; Laisa, C. P.; Prakash, A. S.; Gonbeau, D.; Vantendeloo, G.; Tarascon, J.-M.

    2015-02-01

    Although Li-rich layered oxides (Li1+xNiyCozMn1-x-y-zO2 > 250 mAh g-1) are attractive electrode materials providing energy densities more than 15% higher than today’s commercial Li-ion cells, they suffer from voltage decay on cycling. To elucidate the origin of this phenomenon, we employ chemical substitution in structurally related Li2RuO3 compounds. Li-rich layered Li2Ru1-yTiyO3 phases with capacities of ~240 mAh g-1 exhibit the characteristic voltage decay on cycling. A combination of transmission electron microscopy and X-ray photoelectron spectroscopy studies reveals that the migration of cations between metal layers and Li layers is an intrinsic feature of the charge-discharge process that increases the trapping of metal ions in interstitial tetrahedral sites. A correlation between these trapped ions and the voltage decay is established by expanding the study to both Li2Ru1-ySnyO3 and Li2RuO3; the slowest decay occurs for the cations with the largest ionic radii. This effect is robust, and the finding provides insights into new chemistry to be explored for developing high-capacity layered electrodes that evade voltage decay.

  9. Origins of serotonin innervation of forebrain structures

    NASA Technical Reports Server (NTRS)

    Kellar, K. J.; Brown, P. A.; Madrid, J.; Bernstein, M.; Vernikos-Danellis, J.; Mehler, W. R.

    1977-01-01

    The tryptophan hydroxylase activity and high-affinity uptake of (3H) serotonin ((3H)5-HT) were measured in five discrete brain regions of rats following lesions of the dorsal or median raphe nuclei. Dorsal raphe lesions reduced enzyme and uptake activity in the striatum only. Median raphe lesions reduced activities in the hippocampus, septal area, frontal cortex, and, to a lesser extent, in the hypothalamus. These data are consistent with the suggestion that the dorsal and median raphe nuclei are the origins of two separate ascending serotonergic systems - one innervating striatal structures and the other mesolimbic structures, predominantly. In addition, the data suggest that measurements of high-affinity uptake of (3H)5-HT may be a more reliable index of innervation than either 5-HT content or tryptophan hydroxylase activity.

  10. Structure of relaminarizing turbulent boundary layers

    NASA Astrophysics Data System (ADS)

    Ramesh, O.; Patwardhan, Saurabh

    2014-11-01

    Relaminarization of a turbulent boundary layer in a strongly accelerated flow has received a great attention in recent times. It has been found that such relaminarization is a general and regularly occurring phenomenon in the leading-edge region of a swept wing of an airplane (van Dam et al., 1993). In this work, we investigate the effect of initial Reynolds number on the process of relaminarization in turbulent boundary layers. The experimental and numerical investigation of relaminarizing turbulent boundary layers undergoing same history reveals that the boundary layer with higher initial Reynolds number relaminarizes at a lower pressure gradient value compared to the one with lower Reynolds number. This effect can be explained on the inviscid theory proposed earlier in the literature. Further, various parameter criteria proposed to predict relaminarization, are assessed and the structure of relaminarizing boundary layers is investigated. A mechanism for stabilization of near-wall low speed streaks is proposed.

  11. Some new aspects of the transient ionization layer of comet Siding Spring origin in the Martian upper atmosphere

    NASA Astrophysics Data System (ADS)

    Venkateswara Rao, N.; ManasaMohana, P.; Jayaraman, A.; Rao, S. V. B.

    2016-04-01

    The close encounter of comet Siding Spring with Mars resulted in the formation of a dense transient ionization layer in the Martian upper atmosphere at altitudes between 80 and 120 km. Instruments on three spacecraft orbiting Mars detected the presence of this layer, as reported in previous publications. In this study, we reanalyzed the ionograms of the Mars Advanced Radar for Subsurface and Ionospheric Sounding (MARSIS) instrument on Mars Express to get further insight about the recurrence of the layer. For this purpose, data from three periapsis passes of MARSIS that took place 5 h, 12 h, and 19 h after peak dust deposition are used. We found that the transient ionization layer was sustained at least for 19 h on the nightside and 12 h on the dayside. While the peak density of the layer on the nightside gradually decreases from orbit to orbit, it does not change much on the dayside. Some ionograms in all three orbits show two transient ionization layers that are separated by ~60 km in apparent altitude. These double layers occur preferentially in regions of strong vertical magnetic fields. The bottom layer of the double structure is probably an oblique echo due to reflections from ionization bulges (formed in regions of vertical magnetic fields) at altitudes of the transient ionization layer. Horizontal bifurcation of the original layer is considered as another plausible mechanism for explaining the double-layer structure.

  12. Nanomanufacturing : nano-structured materials made layer-by-layer.

    SciTech Connect

    Cox, James V.; Cheng, Shengfeng; Grest, Gary Stephen; Tjiptowidjojo, Kristianto; Reedy, Earl David, Jr.; Fan, Hongyou; Schunk, Peter Randall; Chandross, Michael Evan; Roberts, Scott A.

    2011-10-01

    Large-scale, high-throughput production of nano-structured materials (i.e. nanomanufacturing) is a strategic area in manufacturing, with markets projected to exceed $1T by 2015. Nanomanufacturing is still in its infancy; process/product developments are costly and only touch on potential opportunities enabled by growing nanoscience discoveries. The greatest promise for high-volume manufacturing lies in age-old coating and imprinting operations. For materials with tailored nm-scale structure, imprinting/embossing must be achieved at high speeds (roll-to-roll) and/or over large areas (batch operation) with feature sizes less than 100 nm. Dispersion coatings with nanoparticles can also tailor structure through self- or directed-assembly. Layering films structured with these processes have tremendous potential for efficient manufacturing of microelectronics, photovoltaics and other topical nano-structured devices. This project is designed to perform the requisite R and D to bring Sandia's technology base in computational mechanics to bear on this scale-up problem. Project focus is enforced by addressing a promising imprinting process currently being commercialized.

  13. Origin and consequences of silicate glass passivation by surface layers

    NASA Astrophysics Data System (ADS)

    Gin, Stéphane; Jollivet, Patrick; Fournier, Maxime; Angeli, Frédéric; Frugier, Pierre; Charpentier, Thibault

    2015-02-01

    Silicate glasses are durable materials, but are they sufficiently durable to confine highly radioactive wastes for hundreds of thousands years? Addressing this question requires a thorough understanding of the mechanisms underpinning aqueous corrosion of these materials. Here we show that in silica-saturated solution, a model glass of nuclear interest corrodes but at a rate that dramatically drops as a passivating layer forms. Water ingress into the glass, leading to the congruent release of mobile elements (B, Na and Ca), is followed by in situ repolymerization of the silicate network. This material is at equilibrium with pore and bulk solutions, and acts as a molecular sieve with a cutoff below 1 nm. The low corrosion rate resulting from the formation of this stable passivating layer enables the objective of durability to be met, while progress in the fundamental understanding of corrosion unlocks the potential for optimizing the design of nuclear glass-geological disposal.

  14. Origin and consequences of silicate glass passivation by surface layers

    PubMed Central

    Gin, Stéphane; Jollivet, Patrick; Fournier, Maxime; Angeli, Frédéric; Frugier, Pierre; Charpentier, Thibault

    2015-01-01

    Silicate glasses are durable materials, but are they sufficiently durable to confine highly radioactive wastes for hundreds of thousands years? Addressing this question requires a thorough understanding of the mechanisms underpinning aqueous corrosion of these materials. Here we show that in silica-saturated solution, a model glass of nuclear interest corrodes but at a rate that dramatically drops as a passivating layer forms. Water ingress into the glass, leading to the congruent release of mobile elements (B, Na and Ca), is followed by in situ repolymerization of the silicate network. This material is at equilibrium with pore and bulk solutions, and acts as a molecular sieve with a cutoff below 1 nm. The low corrosion rate resulting from the formation of this stable passivating layer enables the objective of durability to be met, while progress in the fundamental understanding of corrosion unlocks the potential for optimizing the design of nuclear glass-geological disposal. PMID:25695377

  15. Origin and consequences of silicate glass passivation by surface layers.

    PubMed

    Gin, Stéphane; Jollivet, Patrick; Fournier, Maxime; Angeli, Frédéric; Frugier, Pierre; Charpentier, Thibault

    2015-01-01

    Silicate glasses are durable materials, but are they sufficiently durable to confine highly radioactive wastes for hundreds of thousands years? Addressing this question requires a thorough understanding of the mechanisms underpinning aqueous corrosion of these materials. Here we show that in silica-saturated solution, a model glass of nuclear interest corrodes but at a rate that dramatically drops as a passivating layer forms. Water ingress into the glass, leading to the congruent release of mobile elements (B, Na and Ca), is followed by in situ repolymerization of the silicate network. This material is at equilibrium with pore and bulk solutions, and acts as a molecular sieve with a cutoff below 1 nm. The low corrosion rate resulting from the formation of this stable passivating layer enables the objective of durability to be met, while progress in the fundamental understanding of corrosion unlocks the potential for optimizing the design of nuclear glass-geological disposal. PMID:25695377

  16. Electronic structure of bacterial surface protein layers

    SciTech Connect

    Maslyuk, Volodymyr V.; Mertig, Ingrid; Bredow, Thomas; Mertig, Michael; Vyalikh, Denis V.; Molodtsov, Serguei L.

    2008-01-15

    We report an approach for the calculation of the electronic density of states of the dried two-dimensional crystalline surface protein layer (S layer) of the bacterium Bacillus sphaericus NCTC 9602. The proposed model is based on the consideration of individual amino acids in the corresponding conformation of the peptide chain which additively contribute to the electronic structure of the entire protein complex. The derived results agree well with the experimental data obtained by means of photoemission (PE), resonant PE, and near-edge x-ray absorption spectroscopy.

  17. Identifying layers in random multiphase structures

    NASA Astrophysics Data System (ADS)

    Mader, Kevin; Stampanoni, Marco

    2016-01-01

    X-Ray microscopic methods, benefiting from the large penetration depth of X-rays in many materials, enable 3D investigation of a wide variety of samples. This allows for a wide variety of physical, chemical, and biological structures to be seen and explored, in some cases even in real time. Such measurements have lead to insights into paleontology, vulcanology, genetics, and material science. The ability to see and visualize complex systems can provide otherwise unobtainable information on structure, interactions, mechanical behavior, and evolution. The field has, however, led to a massive amount of new, heterogenous, difficult to process data. We present a general, model-free approach for characterizing multiphase 3D systems and show how the method can be applied to experimental X-ray microscopy data to better understand and quantify layer structure in two typical systems: investigation of layered fibers and clay samples.

  18. Persistent Structures in the Turbulent Boundary Layer

    NASA Technical Reports Server (NTRS)

    Palumbo, Dan; Chabalko, Chris

    2005-01-01

    Persistent structures in the turbulent boundary layer are located and analyzed. The data are taken from flight experiments on large commercial aircraft. An interval correlation technique is introduced which is able to locate the structures. The Morlet continuous wavelet is shown to not only locates persistent structures but has the added benefit that the pressure data are decomposed in time and frequency. To better understand how power is apportioned among these structures, a discrete Coiflet wavelet is used to decompose the pressure data into orthogonal frequency bands. Results indicate that some structures persist a great deal longer in the TBL than would be expected. These structure contain significant power and may be a primary source of vibration energy in the airframe.

  19. Origin and effect of nonlocality in a layered composite.

    SciTech Connect

    Silling, Stewart Andrew

    2014-01-01

    A simple demonstration of nonlocality in a heterogeneous material is presented. By analysis of the microscale deformation of a two-component layered medium, it is shown that nonlocal interactions necessarily appear in a homogenized model of the system. Explicit expressions for the nonlocal forces are determined. The way these nonlocal forces appear in various nonlocal elasticity theories is derived. The length scales that emerge involve the constituent material properties as well as their geometrical dimen- sions. A peridynamic material model for the smoothed displacement eld is derived. It is demonstrated by comparison with experimental data that the incorporation of non- locality in modeling dramatically improves the prediction of the stress concentration in an open hole tension test on a composite plate.

  20. Multi-Layer Laminated Thin Films for Inflatable Structures

    NASA Technical Reports Server (NTRS)

    Yavrouian, Andre; Plett, Gary; Mannella, Jerami

    2005-01-01

    Special-purpose balloons and other inflatable structures would be constructed as flexible laminates of multiple thin polymeric films interspersed with layers of adhesive, according to a proposal. In the original intended application, the laminate would serve as the envelope of the Titan Aerobot a proposed robotic airship for exploring Titan (one of the moons of Saturn). Potential terrestrial applications for such flexible laminates could include blimps and sails. In the original application, the multi-layered laminate would contain six layers of 0.14-mil (0.0036-mm)-thick Mylar (or equivalent) polyethylene terephthalate film with a layer of adhesive between each layer of Mylar . The overall thickness and areal density of this laminate would be nearly the same as those of 1-mil (0.0254-mm)-thick monolayer polyethylene terephthalate sheet. However, the laminate would offer several advantages over the monolayer sheet, especially with respect to interrelated considerations of flexing properties, formation of pinholes, and difficulty or ease of handling, as discussed next. Most of the damage during flexing of the laminate would be localized in the outermost layers, where the radii of bending in a given bend would be the largest and, hence, the bending stress would be the greatest. The adverse effects of formation of pinholes would be nearly completely mitigated in the laminate because a pinhole in a given layer would not propagate to adjacent layers. Hence, the laminate would tend to remain effective as a barrier to retain gas. Similar arguments can be made regarding cracks: While a crack could form as a result of stress or a defect in the film material, a crack would not propagate into adjacent layers, and the adjacent layer(s) would even arrest propagation of the crack. In the case of the monolayer sheet, surface damage (scratches, dents, permanent folds, pinholes, and the like) caused by handling would constitute or give rise to defects that could propagate through

  1. Tracing Heliospheric Structures to Their Solar Origin

    NASA Astrophysics Data System (ADS)

    Wimmer-Schweingruber, R. F.

    2014-12-01

    The solar wind creates a giant plasma bubble in our immediate, very local interstellar medium (VLISM), the heliosphere. As is true for every physical system, its structure is determined by dynamic processes and by the boundary conditions at the Sun and in the VLISM. Because of the supersonic expansion of the solar wind the structure of the inner (several AU) heliosphere is (nearly) exclusively determined by the Sun. As simple as this may all appear, the problem of linking heliospheric structure to solar features is remarkably complex and has so far eluded satisfactory solutions. ESA and NASA have implemented the Solar Orbiter and Solar Probe Plus missions to tackle and solve the mystery of how the Sun creates and controls the heliosphere. Previous missions, especially the twin Helios mission, lacked two crucial elements, remote-sensing of solar features and their dynamics, and composition measurements of the solar plasma, wind, and energetic particles. Solar Orbiter has both elements in its highly sophisticated payload and will allow us to link solar features to the solar wind sampled in situ by using composition and energetic particles as tracers. The composition of the solar wind is altered from its photospheric origin by two processes very probably acting at different altitudes in the solar atmosphere. Elemental composition of the solar wind appears to be fractionated by its First Ionization Potential (FIP) or time (FIT), indicating that some mechanism separates neutral atoms from ions. This requires temperatures low enough to allow a substantial neutral fraction of the solar plasma and therefore the FIP-effect is believed to act primarily in the chromosphere. Charge states on the other hand are determined by the expansion and acceleration of the solar wind and the electron temperature high in the corona. Solar Orbiter will allow remote-sensing measurements of the elemental composition of solar features and comparison with that measured in situ after the solar

  2. Plane mixing layer vortical structure kinematics

    NASA Technical Reports Server (NTRS)

    Leboeuf, Richard L.

    1993-01-01

    The objective of the current project was to experimentally investigate the structure and dynamics of the streamwise vorticity in a plane mixing layer. The first part of this research program was intended to clarify whether the observed decrease in mean streamwise vorticity in the far-field of mixing layers is due primarily to the 'smearing' caused by vortex meander or to diffusion. Two-point velocity correlation measurements have been used to show that there is little spanwise meander of the large-scale streamwise vortical structure. The correlation measurements also indicate a large degree of transverse meander of the streamwise vorticity which is not surprising since the streamwise vorticity exists in the inclined braid region between the spanwise vortex core regions. The streamwise convection of the braid region thereby introduces an apparent transverse meander into measurements using stationary probes. These results corroborated with estimated secondary velocity profiles in which the streamwise vorticity produces a signature which was tracked in time.

  3. A challenging interpretation of a hexagonally layered protein structure

    SciTech Connect

    Thompson, Michael C.; Yeates, Todd O.

    2014-01-01

    The authors describe the structure determination of a hexagonally layered protein structure that suffered from a complicated combination of translational non-crystallographic symmetry and hemihedral twinning. This case serves as a reminder that broken crystallographic symmetry resulting from doubling of a unit-cell axis often requires a new choice of origin. The carboxysome is a giant protein complex that acts as a metabolic organelle in cyanobacteria and some chemoautotrophs. Its outer structure is formed by the assembly of thousands of copies of hexameric shell protein subunits into a molecular layer. The structure determination of a CcmK1 shell protein mutant (L11K) from the β-carboxysome of the cyanobacterium Synechocystis PCC6803 led to challenges in structure determination. Twinning, noncrystallographic symmetry and packing of hexameric units in a special arrangement led to initial difficulties in space-group assignment. The correct space group was clarified after initial model refinement revealed additional symmetry. This study provides an instructive example in which broken symmetry requires a new choice of unit-cell origin in order to identify the highest symmetry space group. An additional observation related to the packing arrangement of molecules in this crystal suggests that these hexameric shell proteins might have lower internal symmetry than previously believed.

  4. DUAL ORIGIN OF AEROSOLS IN TITAN'S DETACHED HAZE LAYER

    SciTech Connect

    Cours, T.; Burgalat, J.; Rannou, P.; Rodriguez, S.; Brahic, A.

    2011-11-10

    We have analyzed scattered light profiles from the Cassini Imaging Science Subsystem, taken at the limb and at several large phase angles. We also used results from an occultation observed by Ultraviolet Imaging Spectrograph in the ultraviolet. We found that particles responsible for the scattering in the detached haze have an effective radius around 0.15 {mu}m and the aerosol size distribution follows a power law (exponent about -4.5). We discuss these results along with microphysical constraints and thermal equilibrium of the detached haze, and we conclude that only a strong interaction with atmospheric dynamics can explain such a structure.

  5. 1. Building #3, original structure and first addition, north side, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Building #3, original structure and first addition, north side, looking south. Photo shows (from left) the original 1911 structure, the 1939 infill addition, and the 1934 structure. - S. W. Shattuck Chemical Company, Incorporated, Building No. 3, 1805 South Bannock Street, Denver, Denver County, CO

  6. Fungal catalases: function, phylogenetic origin and structure.

    PubMed

    Hansberg, Wilhelm; Salas-Lizana, Rodolfo; Domínguez, Laura

    2012-09-15

    Most fungi have several monofunctional heme-catalases. Filamentous ascomycetes (Pezizomycotina) have two types of large-size subunit catalases (L1 and L2). L2-type are usually induced by different stressors and are extracellular enzymes; those from the L1-type are not inducible and accumulate in asexual spores. L2 catalases are important for growth and the start of cell differentiation, while L1 are required for spore germination. In addition, pezizomycetes have one to four small-size subunit catalases. Yeasts (Saccharomycotina) do not have large-subunit catalases and generally have one peroxisomal and one cytosolic small-subunit catalase. Small-subunit catalases are inhibited by substrate while large-subunit catalases are activated by H(2)O(2). Some small-subunit catalases bind NADPH preventing inhibition by substrate. We present a phylogenetic analysis revealing one or two events of horizontal gene transfers from Actinobacteria to a fungal ancestor before fungal diversification, as the origin of large-size subunit catalases. Other possible horizontal transfers of small- and large-subunit catalases genes were detected and one from bacteria to the fungus Malassezia globosa was analyzed in detail. All L2-type catalases analyzed presented a secretion signal peptide. Mucorales preserved only L2-type catalases, with one containing a secretion signal if two or more are present. Basidiomycetes have only L1-type catalases, all lacking signal peptide. Fungal small-size catalases are related to animal catalases and probably evolved from a common ancestor. However, there are several groups of small-size catalases. In particular, a conserved group of fungal sequences resemble plant catalases, whose phylogenetic origin was traced to a group of bacteria. This group probably has the heme orientation of plant catalases and could in principle bind NADPH. From almost a hundred small-subunit catalases only one fourth has a peroxisomal localization signal and in fact many fungi lack

  7. Phase decorrelation of coherent structures in a free shear layer

    NASA Technical Reports Server (NTRS)

    Ho, Chih-Ming; Zohar, Yitshak; Foss, Judith K.; Buell, Jeffrey C.

    1991-01-01

    The vortices near the origin of an initially laminar mixing layer have a single frequency with a well-defined phase; i.e., there is little phase jitter. Further downstream, however, the phase jitter increases suddenly. Even when the flow is forced, this same transition is observed. The forcing partially loses its influence because of the decorrelation of the phase between the forcing signal and the passing coherent structures. In the present investigation, this phenomenon is documented and the physical mechanism responsible for the phase decorrelation is identified.

  8. Damage modes in dental layer structures.

    PubMed

    Jung, Y G; Wuttiphan, S; Peterson, I M; Lawn, B R

    1999-04-01

    Natural teeth (enamel/dentin) and most restorations are essentially layered structures. This study examines the hypothesis that coating thickness and coating/substrate mismatch are key factors in the determination of contact-induced damage in clinically relevant bilayer composites. Accordingly, we study crack patterns in two model "coating/substrate" bilayer systems conceived to simulate crown and tooth structures, at opposite extremes of elastic/plastic mismatch: porcelain on glass-infiltrated alumina ("soft/hard"); and glass-ceramic on resin composite ("hard/soft"). Hertzian contacts are used to investigate the evolution of fracture damage in the coating layers, as functions of contact load and coating thickness. The crack patterns differ radically in the two bilayer systems: In the porcelain coatings, cone cracks initiate at the coating top surface; in the glass-ceramic coatings, cone cracks again initiate at the top surface, but additional, upward-extending transverse cracks initiate at the internal coating/substrate interface, with the latter dominant. The substrate is thereby shown to have a profound influence on the damage evolution to ultimate failure in the bilayer systems. However, the cracks are highly stabilized in both systems, with wide ranges between the loads to initiate first cracking and to cause final failure, implying damage-tolerant structures. Finite element modeling is used to evaluate the tensile stresses responsible for the different crack types. The clinical relevance of these observations is considered. PMID:10326733

  9. Crystal Structure of the Eukaryotic Origin Recognition Complex

    PubMed Central

    Bleichert, Franziska; Botchan, Michael R.; Berger, James M.

    2015-01-01

    Initiation of cellular DNA replication is tightly controlled to sustain genomic integrity. In eukaryotes, the heterohexameric origin recognition complex (ORC) is essential for coordinating replication onset. The 3.5 Å resolution crystal structure of Drosophila ORC reveals that the 270 kDa initiator core complex comprises a two-layered notched ring in which a collar of winged-helix domains from the Orc1-5 subunits sits atop a layer of AAA+ ATPase folds. Although canonical inter-AAA+ domain interactions exist between four of the six ORC subunits, unanticipated features are also evident, including highly interdigitated domain-swapping interactions between the winged-helix folds and AAA+ modules of neighboring protomers, and a quasi-spiral arrangement of DNA binding elements that circumnavigate a ~20 Å wide channel in the center of the complex. Comparative analyses indicate that ORC encircles DNA, using its winged-helix domain face to engage the MCM2-7 complex during replicative helicase loading; however, an observed >90° out-of-plane rotation for the Orc1 AAA+ domain disrupts interactions with catalytic amino acids in Orc4, narrowing and sealing off entry into the central channel. Prima facie, our data indicate that Drosophila ORC can switch between active and autoinhibited conformations, suggesting a novel means for cell cycle and/or developmental control of ORC functions. PMID:25762138

  10. Origins of microspherules from the Permian-Triassic boundary event layers in South China

    NASA Astrophysics Data System (ADS)

    Zhang, Hua; Shen, Shu-zhong; Cao, Chang-qun; Zheng, Quan-feng

    2014-09-01

    Volcanism and impact scenarios are two of the most plausible ways of interpreting the causes of the largest biological mass extinction at the end-Permian. Microspherules have previously been widely reported from tens of different Permian-Triassic boundary (PTB) sections in South China and some other regions. These microspherules have been interpreted as either the product of volcanic eruptions or an impact event. In order to test these scenarios, we collected 60 samples from 12 intensively-studied PTB sections in South China. In addition, four soil samples close to these PTB layers were also collected for comparison. Our investigation indicates that abundant microspherules with mosaic or dot shape crystals on rounded surface are present in the surface samples in the PTB layers at Meishan, Meili, and Shatian sections and most soil background samples in South China. Those microspherules consist of four different types based on their main chemical composition, surface features, and internal structure including iron, magnetite-silicate, glassy, pyrite microspherules and framboids. In contrast, microspherules have not been found in a few sections in remote areas such as the Selong Xishan section in Tibet and the Dalongkou section in Xinjiang, Northwest China, in the deeply-excavated samples at the Shangsi section and the hard tuff layers around the PTB at the Xiaochehe Section in Guiyang. Microspherules decrease in abundance with depth in PTB clay beds. All these microspherules except the pyrite microspherules and framboids are found in both the PTB layers and the nearby soil background samples. The iron microspherules are pure iron oxides such as magnetite, hematite or maghemite and contain low concentrations of nickel and chromium, and lack an Ni-Fe core and general extraterrestrial mineral wüstite. All these external and chemical characteristics suggest that most of iron microspherules previously reported from PTB sections in South China are modern industrial fly

  11. What is the Age and Origin of the Spherule Bearing Layer in some Ross Sea Cores?

    NASA Astrophysics Data System (ADS)

    Yeh, C.; Abbott, D. H.; Anders, M. H.; Breger, D.

    2012-12-01

    L.P. Khyranina (1985) was the first to suggest that there were two structures present on the Antarctic continental shelf beneath the Ross Sea. One was the ~100 km Bowers impact crater candidate. However, there was no solid evidence that proved an extraterrestrial impact produced the Bowers structure. Debate has ensued for decades on whether the Bowers structure was an impact crater. Now we have come close to finding an answer. We used core samples taken near the crater and sieved into four size fractions (>250,>125,>63,>38 μm). Impact ejecta candidates were then picked from cores ELT 32-08, ELT 32-03, ELT 32-43, ELT 32-06, DSDP 273, DSDP 274, and NPB 95-01 39KC and were analyzed for chemical composition and physical features. All but DSDP site 274 contain pure SiO2 glasses that resemble tektites. We also found candidates for flow textured impact glass and shocked quartz. This led us to conclude that the origin of the spherule-bearing layer was from an impact. With the use of dated core NBP 95-01 39KC, we have constrained the age to lie between 7,305±80 BP and 11,150±95 BP (corrected radiocarbon ages) (Cunningham et al., 1999).

  12. The nature and origin of lateral composition modulations in short-period strained-layer superlattices

    SciTech Connect

    NORMAN,A.G.; AHRENKIEL,S.P.; MOUTINHO,H.R.; BALLIF,C.; ALJASSIM,M.M.; MASCARENHAS,A.; FOLLSTAEDT,DAVID M.; LEE,STEPHEN R.; RENO,JOHN L.; JONES,ERIC D.; MIRECKI-MILLUNCHICK,J.; TWESTEN,R.D.

    2000-01-27

    The nature and origin of lateral composition modulations in (AlAs){sub m}(InAs){sub n} SPSs grown by MBE on InP substrates have been investigated by XRD, AFM, and TEM. Strong modulations were observed for growth temperatures between {approx} 540 and 560 C. The maximum strength of modulations was found for SPS samples with InAs mole fraction x (=n/(n+m)) close to {approx} 0.50 and when n {approx} m {approx} 2. The modulations were suppressed at both high and low values of x. For x >0.52 (global compression) the modulations were along the <100> directions in the (001) growth plane. For x < 0.52 (global tension) the modulations were along the two <310> directions rotated {approx} {+-} 27{degree} from [110] in the growth plane. The remarkably constant wavelength of the modulations, between {approx} 20--30 nm, and the different modulation directions observed, suggest that the origin of the modulations is due to surface roughening associated with the high misfit between the individual SPS layers and the InP substrate. Highly uniform unidirectional modulations have been grown, by control of the InAs mole fraction and growth on suitably offcut substrates, which show great promise for application in device structures.

  13. Structure-property Relationships of Layered Oxypnictides

    NASA Astrophysics Data System (ADS)

    Muir, Sean W.

    Investigating the structure-property relationships of solid state materials can help improve many of the materials we use each day in life. It can also lead to the discovery of materials with interesting and unforeseen properties. In this work the structure property relationships of newly discovered layered oxypnictide phases are presented and discussed. There has generally been worldwide interest in layered oxypnictide materials following the discovery of superconductivity up to 55 K for iron arsenides such as LnFeAsO 1-xFx (where Ln = Lanthanoid). This work presents efforts to understand the structure and physical property changes which occur to LnFeAsO materials when Fe is replaced with Rh or Ir and when As is replaced with Sb. As part of this work the solid solution between LaFeAsO and LaRhAsO was examined and superconductivity is observed for low Rh content with a maximum critical temperature of 16 K. Ln RhAsO and LnIrAsO compositions are found to be metallic; however Ce based compositions display a resistivity temperature dependence which is typical of Kondo lattice materials. At low temperatures a sudden drop in resistivity occurs for both CeRhAsO and CeIrAsO compositions and this drop coincides with an antiferromagnetic transition. The Kondo scattering temperatures and magnetic transition temperatures observed for these materials can be rationalized by considering the expected difference in N(EF) J parameters between them, where N(EF) is the density of states at the Fermi level and J represents the exchange interaction between the Ce 4f1 electrons and the conduction electrons. In addition to studying these 4d and 5d substituted systems the LaFeSbO compositional system was investigated. While LaFeSbO has not been successfully synthesized the transition metal free layered oxypnictide composition La2SbO 2 was discovered and its structural and physical properties have been examined along with the properties of La2BiO2. Density functional theory was used to

  14. The Levantine Basin—crustal structure and origin

    NASA Astrophysics Data System (ADS)

    Netzeband, G. L.; Gohl, K.; Hübscher, C. P.; Ben-Avraham, Z.; Dehghani, G. A.; Gajewski, D.; Liersch, P.

    2006-06-01

    The origin of the Levantine Basin in the Southeastern Mediterranean Sea is related to the opening of the Neo-Tethys. The nature of its crust has been debated for decades. Therefore, we conducted a geophysical experiment in the Levantine Basin. We recorded two refraction seismic lines with 19 and 20 ocean bottom hydrophones, respectively, and developed velocity models. Additional seismic reflection data yield structural information about the upper layers in the first few kilometers. The crystalline basement in the Levantine Basin consists of two layers with a P-wave velocity of 6.0-6.4 km/s in the upper and 6.5-6.9 km/s in the lower crust. Towards the center of the basin, the Moho depth decreases from 27 to 22 km. Local variations of the velocity gradient can be attributed to previously postulated shear zones like the Pelusium Line, the Damietta-Latakia Line and the Baltim-Hecateus Line. Both layers of the crystalline crust are continuous and no indication for a transition from continental to oceanic crust is observed. These results are confirmed by gravity data. Comparison with other seismic refraction studies in prolongation of our profiles under Israel and Jordan and in the Mediterranean Sea near Greece and Sardinia reveal similarities between the crust in the Levantine Basin and thinned continental crust, which is found in that region. The presence of thinned continental crust under the Levantine Basin is therefore suggested. A β-factor of 2.3-3 is estimated. Based on these findings, we conclude that sea-floor spreading in the Eastern Mediterranean Sea only occurred north of the Eratosthenes Seamount, and the oceanic crust was later subducted at the Cyprus Arc.

  15. Boundary-Layer Origin for Jets, and Non-Existence of the Boundary Layer in Young Jet-Producing Protostars

    NASA Astrophysics Data System (ADS)

    Williams, Peter T.

    2016-01-01

    Twenty-five years ago, Pringle suggested a boundary-layer origin for jets from YSOs. The jets were driven by a toroidal magnetic field generated by strong shear in the accretion boundary layer. Such a mechanism is clearly non-magnetocentrifugal in nature.Nearly fifteen years ago, we suggested a cartoon of the jet-launching mechanism in protostars in which shear, acting upon MHD turbulence generated by the magnetorotational instability (MRI), generated a tangled, toroidal magnetic field capable of driving a jet. This picture, which is also manifestly non-magnetocentrifugal in nature, relied upon a novel model for MRI-driven MHD turbulence based on a viscoelastic, rather than a viscous, prescription for the turbulent stress. Our hypothesis has some clear similarities to Pringle's mechanism, but it relied upon a large envelope surrounding the central star.An accretion boundary layer has long been recognized as a promising source for protostellar jets in good part because in a standard thin disk, matter loses circa half of all its accretion energy in this layer, but it is problematic to drive a well-collimated outflow from a boundary layer in a thin disk. In this presentation, we argue paradoxically that the "boundary layer" can drive jets when a true boundary layer, like the thin disk, does not exist. This changes the inner boundary condition for viscous angular momentum flux in the disk.The standard argument for a thin boundary layer is, we argue, circular. In high accretion-rate systems, or when the gas cannot cool efficiently, there is no reason to suspect the turbulent viscosity in this boundary layer to be small, and therefore neither is the boundary layer. When the boundary layer becomes larger than the central accretor itself, it is arguably no longer a boundary layer, but rather an envelope. It is still, however, a substantial source of power and toroidal MRI-driven magnetic fields.It is, again, only in relatively hot or high-accretion rate systems in which

  16. Origin and Structure of Dynamic Cooperative Networks

    PubMed Central

    Wardil, Lucas; Hauert, Christoph

    2014-01-01

    Societies are built on social interactions among individuals. Cooperation represents the simplest form of a social interaction: one individual provides a benefit to another one at a cost to itself. Social networks represent a dynamical abstraction of social interactions in a society. The behaviour of an individual towards others and of others towards the individual shape the individual's neighbourhood and hence the local structure of the social network. Here we propose a simple theoretical framework to model dynamic social networks by focussing on each individual's actions instead of interactions between individuals. This eliminates the traditional dichotomy between the strategy of individuals and the structure of the population and easily complements empirical studies. As a consequence, altruists, egoists and fair types are naturally determined by the local social structures, while globally egalitarian networks or stratified structures arise. Cooperative interactions drive the emergence and shape the structure of social networks. PMID:25030202

  17. Origin and Structure of Dynamic Cooperative Networks

    NASA Astrophysics Data System (ADS)

    Wardil, Lucas; Hauert, Christoph

    2014-07-01

    Societies are built on social interactions among individuals. Cooperation represents the simplest form of a social interaction: one individual provides a benefit to another one at a cost to itself. Social networks represent a dynamical abstraction of social interactions in a society. The behaviour of an individual towards others and of others towards the individual shape the individual's neighbourhood and hence the local structure of the social network. Here we propose a simple theoretical framework to model dynamic social networks by focussing on each individual's actions instead of interactions between individuals. This eliminates the traditional dichotomy between the strategy of individuals and the structure of the population and easily complements empirical studies. As a consequence, altruists, egoists and fair types are naturally determined by the local social structures, while globally egalitarian networks or stratified structures arise. Cooperative interactions drive the emergence and shape the structure of social networks.

  18. Tracing heliospheric structures to their solar origin

    NASA Astrophysics Data System (ADS)

    Wimmer-Schweingruber, Robert F.; Hassler, Donald M.

    2016-03-01

    The composition of the solar wind serves as an excellent tracer of the solar/coronal origin of the solar wind. We summarize various processes which affect the composition of the solar wind as it expands from the Sun into the heliosphere. As it leaves the well-mixed photosphere, the solar wind is fractionated according to First Ionization Potential (FIP) or First Ionization Time (FIT) in the highly evolving chromosphere/transition region. Its charge states are further modified as it moves through the dynamic environment of the corona.

  19. Characteristic Lifelength of Coherent Structure in the Turbulent Boundary Layer

    NASA Technical Reports Server (NTRS)

    Palumbo, Daniel L.

    2006-01-01

    A characteristic lifelength is defined by which a Gaussian distribution is fit to data correlated over a 3 sensor array sampling streamwise sidewall pressure. The data were acquired at subsonic, transonic and supersonic speeds aboard a Tu-144. Lifelengths are estimated using the cross spectrum and are shown to compare favorably with Efimtsov's prediction of correlation space scales. Lifelength distributions are computed in the time/frequency domain using an interval correlation technique on the continuous wavelet transform of the original time data. The median values of the lifelength distributions are found to be very close to the frequency averaged result. The interval correlation technique is shown to allow the retrieval and inspection of the original time data of each event in the lifelength distribution, thus providing a means to locate and study the nature of the coherent structure in the turbulent boundary layer. The lifelength data can be converted to lifetimes using the convection velocity. The lifetime of events in the time/frequency domain are displayed in Lifetime Maps. The primary purpose of the paper is to validate these new analysis techniques so that they can be used with confidence to further characterize coherent structure in the turbulent boundary layer.

  20. The structural origin of metabolic quantitative diversity.

    PubMed

    Koshiba, Seizo; Motoike, Ikuko; Kojima, Kaname; Hasegawa, Takanori; Shirota, Matsuyuki; Saito, Tomo; Saigusa, Daisuke; Danjoh, Inaho; Katsuoka, Fumiki; Ogishima, Soichi; Kawai, Yosuke; Yamaguchi-Kabata, Yumi; Sakurai, Miyuki; Hirano, Sachiko; Nakata, Junichi; Motohashi, Hozumi; Hozawa, Atsushi; Kuriyama, Shinichi; Minegishi, Naoko; Nagasaki, Masao; Takai-Igarashi, Takako; Fuse, Nobuo; Kiyomoto, Hideyasu; Sugawara, Junichi; Suzuki, Yoichi; Kure, Shigeo; Yaegashi, Nobuo; Tanabe, Osamu; Kinoshita, Kengo; Yasuda, Jun; Yamamoto, Masayuki

    2016-01-01

    Relationship between structural variants of enzymes and metabolic phenotypes in human population was investigated based on the association study of metabolite quantitative traits with whole genome sequence data for 512 individuals from a population cohort. We identified five significant associations between metabolites and non-synonymous variants. Four of these non-synonymous variants are located in enzymes involved in metabolic disorders, and structural analyses of these moderate non-synonymous variants demonstrate that they are located in peripheral regions of the catalytic sites or related regulatory domains. In contrast, two individuals with larger changes of metabolite levels were also identified, and these individuals retained rare variants, which caused non-synonymous variants located near the catalytic site. These results are the first demonstrations that variant frequency, structural location, and effect for phenotype correlate with each other in human population, and imply that metabolic individuality and susceptibility for diseases may be elicited from the moderate variants and much more deleterious but rare variants. PMID:27528366

  1. The structural origin of metabolic quantitative diversity

    PubMed Central

    Koshiba, Seizo; Motoike, Ikuko; Kojima, Kaname; Hasegawa, Takanori; Shirota, Matsuyuki; Saito, Tomo; Saigusa, Daisuke; Danjoh, Inaho; Katsuoka, Fumiki; Ogishima, Soichi; Kawai, Yosuke; Yamaguchi-Kabata, Yumi; Sakurai, Miyuki; Hirano, Sachiko; Nakata, Junichi; Motohashi, Hozumi; Hozawa, Atsushi; Kuriyama, Shinichi; Minegishi, Naoko; Nagasaki, Masao; Takai-Igarashi, Takako; Fuse, Nobuo; Kiyomoto, Hideyasu; Sugawara, Junichi; Suzuki, Yoichi; Kure, Shigeo; Yaegashi, Nobuo; Tanabe, Osamu; Kinoshita, Kengo; Yasuda, Jun; Yamamoto, Masayuki

    2016-01-01

    Relationship between structural variants of enzymes and metabolic phenotypes in human population was investigated based on the association study of metabolite quantitative traits with whole genome sequence data for 512 individuals from a population cohort. We identified five significant associations between metabolites and non-synonymous variants. Four of these non-synonymous variants are located in enzymes involved in metabolic disorders, and structural analyses of these moderate non-synonymous variants demonstrate that they are located in peripheral regions of the catalytic sites or related regulatory domains. In contrast, two individuals with larger changes of metabolite levels were also identified, and these individuals retained rare variants, which caused non-synonymous variants located near the catalytic site. These results are the first demonstrations that variant frequency, structural location, and effect for phenotype correlate with each other in human population, and imply that metabolic individuality and susceptibility for diseases may be elicited from the moderate variants and much more deleterious but rare variants. PMID:27528366

  2. Origin of auroral electric potential structures

    NASA Astrophysics Data System (ADS)

    Chiu, Y. T.

    Available observational data and theoretical models of the formation of auroral electric potential structures are reviewed. It is shown that the principle of arc formation in the aurora can also be applied to other geomagnetic configurations, in order to construct a comprehensive theory of discrete auroral arcs. According to the theory, the completion of the field-aligned current circuit in the aurora can lead to downward parallel electric fields in the return current from the central region of discrete arc potential. It is pointed out that evidence for downward parallel electric field signatures has been collected within the last year.

  3. Mars: New evidence for origin of some Valles Marineris layered deposits

    NASA Technical Reports Server (NTRS)

    Scott, David H.

    1993-01-01

    The discovery of layered deposits in the walls of a deep trough in Lunae Planum has implications for the origin of similar-appearing deposits in some canyons of Valles Marineris. Although layering is visible in the competent, cliff-forming upper walls of the canyons, the dissimilarity in appearance between canyon walls and soft rounded hills of layered deposits on canyon floors, as well as their contrasting patterns of erosion, has been considered strong evidence that their modes of origin were different. Most workers agree that the wall rocks are volcanic flows derived from fissure vents and other volcanic sources in the region. However, several hypotheses have been advanced to account for the softer-appearing stratified floor deposits. Chief among them is the proposal that the floor deposits are waterlaid sediments that accumulated in large lakes within the canyons and include materials eroded from canyon walls, eolian deposits, and subaqueous volcanic eruptives.

  4. Origin of ferromagnetism enhancement in bi-layer chromium-doped indium zinc oxides

    SciTech Connect

    Hsu, C. Y.

    2012-08-06

    This work demonstrates that by controlling the rapid thermal annealing temperature, amorphous chromium-doped indium zinc oxide films develop an amorphous-crystalline bi-layer structure and show magnetization up to {approx}30 emu/cm{sup 3}. The crystalline layer arises from significant out-diffusion of Zn from surfaces, leading to a large difference in the Zn:In ratio in amorphous and crystalline layers. Doped Cr ions in amorphous and crystalline layers form different valence configurations, creating a charge reservoir which transfers electrons through amorphous-crystalline interfaces and in turn enhances ferromagnetism.

  5. Crystal structure of the eukaryotic origin recognition complex.

    PubMed

    Bleichert, Franziska; Botchan, Michael R; Berger, James M

    2015-03-19

    Initiation of cellular DNA replication is tightly controlled to sustain genomic integrity. In eukaryotes, the heterohexameric origin recognition complex (ORC) is essential for coordinating replication onset. Here we describe the crystal structure of Drosophila ORC at 3.5 Å resolution, showing that the 270 kilodalton initiator core complex comprises a two-layered notched ring in which a collar of winged-helix domains from the Orc1-5 subunits sits atop a layer of AAA+ (ATPases associated with a variety of cellular activities) folds. Although canonical inter-AAA+ domain interactions exist between four of the six ORC subunits, unanticipated features are also evident. These include highly interdigitated domain-swapping interactions between the winged-helix folds and AAA+ modules of neighbouring protomers, and a quasi-spiral arrangement of DNA binding elements that circumnavigate an approximately 20 Å wide channel in the centre of the complex. Comparative analyses indicate that ORC encircles DNA, using its winged-helix domain face to engage the mini-chromosome maintenance 2-7 (MCM2-7) complex during replicative helicase loading; however, an observed out-of-plane rotation of more than 90° for the Orc1 AAA+ domain disrupts interactions with catalytic amino acids in Orc4, narrowing and sealing off entry into the central channel. Prima facie, our data indicate that Drosophila ORC can switch between active and autoinhibited conformations, suggesting a novel means for cell cycle and/or developmental control of ORC functions. PMID:25762138

  6. Origins of Structure in Planetary Systems

    NASA Astrophysics Data System (ADS)

    Murray-Clay, Ruth

    2016-01-01

    Observations confirm that planet formation is a ubiquitous process that produces a diversity of planetary systems. However, a class of solar system analogs has yet to be identified among the thousands of currently known planets and candidates, the overwhelming majority of which are more easily detectable than direct counterparts of the Sun's worlds. To understand whether our solar system's history was unusual and, more generally, to properly characterize the galactic population of extrasolar planets, we must identify how differences in formation environment translate into different planetary system architectures. In this talk, I will consider our solar system in the context of theoretical advances in planet formation driven by the study of extrasolar planets. Along the way, I will discuss several examples of physical processes operating at different stages of planet formation that imprint observable structures on the dynamical and compositional demographics of planetary systems.

  7. Structure and morphology of submarine slab slides: clues to origin and behavior

    USGS Publications Warehouse

    O'Leary, D. W.

    1991-01-01

    Geologic features suggest that some slab slides probably result from long-term strength degradation of weak layers deep in the homoclinal section. Time-dependent strain in clay-rich layers can create potential slide surfaces of low frictional strength. Competent layers are weak in tension and probably fragment in the first instance of, or even prior to, translation, and the allochthonous mass is readily transformed into a high-momentum debris flow. The structure and geomorphology of slab slides provide important clues to their origin and behavior. -from Author

  8. Origin and population structure of the Icelanders.

    PubMed

    Williams, J T

    1993-04-01

    The Norse and Celtic contributions to the founding population of Iceland have been estimated previously on a pan-Icelandic basis using gene frequency data for the entire island. Accounts of the settlement of Iceland, however, suggest that different regions received different proportions of Norse and Celtic settlers, indicating the need to incorporate geographic variation into Icelandic admixture studies. A formal likelihood ratio test rejects the null hypothesis of regional homogeneity in admixture proportions. Here, regional admixture estimates for Iceland are reported; they are in agreement with the settlement pattern inferred from historical accounts. The western, northern, and southern regions of Iceland exhibit a moderate Celtic component, consistent with historical indications that these regions were settled by Norse Vikings from the British Isles, accompanied by Celtic wives and slaves. Eastern Iceland, believed to have been settled chiefly by Vikings from Scandinavia, is characterized by a large Norse component of admixture. The northwestern peninsula is also found to be predominantly Norse. Regional genetic data are used to elucidate the contemporary population structure of Iceland. The observed structure correlates well with patterns of Icelandic geography, history, economy, marriage, urbanization, and internal migration. The northeastern region is strongly isolated, the urbanized areas of the north and southwest are representative of the overall population, and the remaining regions exhibit small-scale variation about the genetic central tendency. A high level of genetic homogeneity is indicated (RST = 0.0005), consistent with the high internal migration rate of the Icelanders. A regression of mean per-locus heterozygosity on distance from the gene frequency centroid reveals a greater than average external gene flow into the eastern region, whereas the northwestern peninsula has received less than average external gene flow. Iceland is compared with

  9. Structure of the surface layer of the methanogenic archaean Methanosarcina acetivorans

    SciTech Connect

    Arbing, Mark A.; Chan, Sum; Shin, Annie; Phan, Tung; Ahn, Christine J.; Rohlin, Lars; Gunsalus, Robert P.

    2012-09-05

    Archaea have a self-assembling proteinaceous surface (S-) layer as the primary and outermost boundary of their cell envelopes. The S-layer maintains structural rigidity, protects the organism from adverse environmental elements, and yet provides access to all essential nutrients. We have determined the crystal structure of one of the two 'homologous' tandem polypeptide repeats that comprise the Methanosarcina acetivorans S-layer protein and propose a high-resolution model for a microbial S-layer. The molecular features of our hexameric S-layer model recapitulate those visualized by medium resolution electron microscopy studies of microbial S-layers and greatly expand our molecular view of S-layer dimensions, porosity, and symmetry. The S-layer model reveals a negatively charged molecular sieve that presents both a charge and size barrier to restrict access to the cell periplasmic-like space. The {beta}-sandwich folds of the S-layer protein are structurally homologous to eukaryotic virus envelope proteins, suggesting that Archaea and viruses have arrived at a common solution for protective envelope structures. These results provide insight into the evolutionary origins of primitive cell envelope structures, of which the S-layer is considered to be among the most primitive: it also provides a platform for the development of self-assembling nanomaterials with diverse functional and structural properties.

  10. Structural Characterization of Layered Morphologies in Precise Copolymers

    NASA Astrophysics Data System (ADS)

    Trigg, Edward; Gaines, Taylor; Wagener, Kenneth; Winey, Karen

    2015-03-01

    Layered morphologies have been observed in precise polyethylene-based copolymers that contain acid, charged, or polar functional groups precisely spaced along a linear alkane chain. Sufficiently long alkane segments form structures resembling orthorhombic polyethylene crystals, while the functional groups form 2-D layers that disrupt the alkane crystal structure to varying degrees. Here, layered morphologies in precise copolymers containing acrylic acid, phosphonic acid, imidazolium bromide, and sulfone groups are studied via X-ray scattering. Specifically, the composition profiles of the layered structures are obtained by Fourier synthesis, and the coherence length is investigated using peak width analysis. This analysis indicates that the layers of functional groups are frequently bordered by two crystallites, which suggests different dynamics relative to layers bordered by one crystalline and one amorphous microdomain. Detailed understanding of the structure of the layered morphologies will allow for a systematic investigation of proton and ion conductivity mechanisms, which are expected to occur through the high-dielectric layers.

  11. 77. Photocopy of original structural shop drawing, Passaic Rolling Mill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    77. Photocopy of original structural shop drawing, Passaic Rolling Mill Company, 1892/1893, (original in possession of New York City Department of Transportation), lattice girder elevation & details - girder G1 - Macombs Dam Bridge, Spanning Harlem River Between 155th Street Viaduct, Jerome Avenue, & East 162nd Street, Bronx, Bronx County, NY

  12. 80. Photocopy of original structural shop drawing, Passaic Rolling Mill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    80. Photocopy of original structural shop drawing, Passaic Rolling Mill Company, 1892/1893, (original in possession of New York City Department of Transportation), lattice girder elevation & details - girder G2 - Macombs Dam Bridge, Spanning Harlem River Between 155th Street Viaduct, Jerome Avenue, & East 162nd Street, Bronx, Bronx County, NY

  13. 78. Photocopy of original structural shop drawing, Passaic Rolling Mill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    78. Photocopy of original structural shop drawing, Passaic Rolling Mill Company, 1892/1893, (original in possession of New York City Department of Transportation), lattice girder elevation & details - girder G2 - Macombs Dam Bridge, Spanning Harlem River Between 155th Street Viaduct, Jerome Avenue, & East 162nd Street, Bronx, Bronx County, NY

  14. 79. Photocopy of original structural shop drawing, Passaic Rolling Mill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    79. Photocopy of original structural shop drawing, Passaic Rolling Mill Company, 1892/1893, (original in possession of New York City Department of Transportation), lattice girder elevation & details - girder G2 - Macombs Dam Bridge, Spanning Harlem River Between 155th Street Viaduct, Jerome Avenue, & East 162nd Street, Bronx, Bronx County, NY

  15. 75. Photocopy of original structural shop drawing, Passaic Rolling Mill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    75. Photocopy of original structural shop drawing, Passaic Rolling Mill Company, 1892/1893, (original in possession of New York City Department of Transportation), lattice girder elevation & details - girder G1 - Macombs Dam Bridge, Spanning Harlem River Between 155th Street Viaduct, Jerome Avenue, & East 162nd Street, Bronx, Bronx County, NY

  16. 76. Photocopy of original structural shop drawing, Passaic Rolling Mill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    76. Photocopy of original structural shop drawing, Passaic Rolling Mill Company, 1892/1893, (original in possession of New York City Department of Transportation), lattice girder elevation & details - girder G1 - Macombs Dam Bridge, Spanning Harlem River Between 155th Street Viaduct, Jerome Avenue, & East 162nd Street, Bronx, Bronx County, NY

  17. 2. VIEW LOOKING WEST SHOWING STRUCTURE WHICH WAS ORIGINALLY A ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. VIEW LOOKING WEST SHOWING STRUCTURE WHICH WAS ORIGINALLY A METHODIST CHURCH AND ONCE THE GARFIELD REFRACTORIES COMPANY OFFICE ON WASHINGTON STREET. - Town of Bolivar, Bolivar, Westmoreland County, PA

  18. Investigating the origin of intense photoluminescence in Si capping layer on Ge1-xSnx nanodots by transmission electron microscopy

    NASA Astrophysics Data System (ADS)

    Kikkawa, Jun; Nakamura, Yoshiaki; Fujinoki, Norihito; Ichikawa, Masakazu

    2013-02-01

    The authors investigated the annealing effects on atomic structures and elemental compositions in a stacking structure, Si capping layer on Ge1-xSnx nanodots on Si substrate covered with ultrathin SiO2 film, to clarify the origin of intense photoluminescence at ˜0.8 eV from the structure, using transmission electron microscopy. After the annealing, it was found that decay of Ge1-xSnx nanodots, formation of SiOx precipitates embedded in Si-rich Si1-xGex layer at the Si cap/Si substrate interface, formation of SnO2 nanoparticles on the oxidized surface of the Si capping layer, and morphological change of dislocations in the Si capping layer occur. Reaction products that appear as a result of the movement of dislocations can be related to the origin of intense photoluminescence.

  19. Hydrogen in magnesium palladium thin layer structures

    NASA Astrophysics Data System (ADS)

    Kruijtzer, G. L.

    2008-02-01

    In this thesis, the study of hydrogen storage, absorption and desorption in magnesium layers is described. The magnesium layers have a thickness of 50-500 nm and are covered by a palladium layer which acts as a hydrogen dissociation/association catalyst. The study was preformed under ultra high vacuum conditions to avoid oxygen contamination. The main analysis techniques were RBS, ERD and TDS.

  20. Origin and evolution of the layered deposits in the Valles Marineris, Mars

    NASA Technical Reports Server (NTRS)

    Nedell, Susan S.; Squyres, Steven W.; Andersen, David W.

    1987-01-01

    Four hypotheses are discussed concerning the origin of the layered deposits in the Martian Valles Marineris, whose individual thicknesses range from about 70 to 300 m. The hypothesized processes are: (1) aeolian deposition; (2) deposition of remnants of the material constituting the canyon walls; (3) deposition of volcanic eruptions; and (4) deposition in standing bodies of water. The last process is chosen as most consistent with the rhythm and lateral continuity of the layers, as well as their great thickness and stratigraphic relationship with other units in the canyons. Attention is given to ways in which the sediments could have entered an ice-covered lake; several geologically feasible mechanisms are identified.

  1. Boron-Based Layered Structures for Energy Storage

    SciTech Connect

    Zhao, Y.; Wei, S. H.

    2012-01-01

    Based on Density Functional Theory simulations, we have studied the boron-based graphite-like materials, i.e., LiBC and MgB2 for energy storage. First, when half of the Li-ions in the LiBC are removed, the BC layered structure is still preserved. The Li intercalation potential (equilibrium lithium-insertion voltage of 2.3-2.4 V relative to lithium metal) is significantly higher than that in graphite, allowing Li0.5BC to function as a cathode material. The reversible electrochemical reaction, LiBC = Li0.5BC + 0.5Li, enables a specific energy density of 1088 Wh/kg and a volumetric energy density of 2463 Wh/L. Second, 75% of the Mg ions in MgB2 can be removed and reversibly inserted with the layered boron structures being preserved through an in-plane topological transformation between the hexagonal lattice domains and triangular domains. The mechanism of such a charge-driven transformation originates from the versatile valence state of boron in its planar form.

  2. Do large structures control their own growth in a mixing layer? - An assessment

    NASA Technical Reports Server (NTRS)

    Kaul, Upender K.

    1988-01-01

    Two different two-dimensional free shear layers, the T-layer developing in time from an initial tangential velocity discontinuity separating the two half-spaces, and the S-layer which develops downstream of the origin where two uniform streams of unequal velocity are brought into tangential contact, are compared. Calculations are performed in order to determine to what extent the perturbations induced upstream by large concentrations of vorticity found downstream hasten or retard the subharmonic instability that leads to the formations of these large structures. The results show that the elliptic influence, or the feedback, in a mixing layer is relatively small for small velocity ratios.

  3. Endoscopic treatments for small gastric subepithelial tumors originating from muscularis propria layer

    PubMed Central

    Zhang, Yu; Ye, Li-Ping; Mao, Xin-Li

    2015-01-01

    Minimally invasive endoscopic resection has become an increasingly popular method for patients with small (less than 3.5 cm in diameter) gastric subepithelial tumors (SETs) originating from the muscularis propria (MP) layer. Currently, the main endoscopic therapies for patients with such tumors are endoscopic muscularis excavation, endoscopic full-thickness resection, and submucosal tunneling endoscopic resection. Although these endoscopic techniques can be used for complete resection of the tumor and provide an accurate pathological diagnosis, these techniques have been associated with several negative events, such as incomplete resection, perforation, and bleeding. This review provides detailed information on the technical details, likely treatment outcomes, and complications associated with each endoscopic method for treating/removing small gastric SETs that originate from the MP layer. PMID:26327758

  4. Evidence for the biogenic origin of manganese-enriched layers in Lake Superior sediments.

    PubMed

    Palermo, Christine; Dittrich, Maria

    2016-04-01

    Manganese (Mn) and iron (Fe)-enriched sediment layers were discovered in Lake Superior within, above and below the oxic-anoxic interface. While the role of bacteria in redox reactions with Mn is known to be significant, little information exists about indigenous microbial communities in many freshwater environments. This study examined the bacterial communities of Mn-enriched layers in Lake Superior to identify the potential Mn(II) oxidizers responsible for the formation of Mn oxides. Anaerobic Mn(II) oxidation occurring in the Mn-enriched layers at the oxic-anoxic interface was investigated using Mn(II)-enriched cultures. High-resolution microscopic and spectroscopic investigations provided evidence of the biogenic formation of Mn oxides on cell surfaces. Spectroscopic mapping confirmed high levels of Mn in structures resembling biogenic Mn oxides. These structures were observed in enrichment cultures and in Mn-enriched layer sediment samples, indicating the significance of biogenic Mn oxidation occurring in situ. 16S ribosomal DNA pyrosequencing was used to identify the bacteria potentially responsible for Mnoxide formation in the enrichment cultures and Mn-enriched layers, revealing that the Mn-enriched layer contains classes with known Mn(II)-oxidizing members. Pyrosequencing of bacterial cultures suggested that these bacteria may be Bacillus strains, and that anaerobic microbial-mediated Mn(II) oxidation contributes to the formation of the layers. PMID:26636960

  5. Composite S-layer lipid structures.

    PubMed

    Schuster, Bernhard; Sleytr, Uwe B

    2009-10-01

    Designing and utilization of biomimetic membrane systems generated by bottom-up processes is a rapidly growing scientific and engineering field. Elucidation of the supramolecular construction principle of archaeal cell envelopes composed of S-layer stabilized lipid membranes led to new strategies for generating highly stable functional lipid membranes at meso- and macroscopic scale. In this review, we provide a state of the art survey how S-layer proteins, lipids, and polysaccharides may be used as basic building blocks for the assembly of S-layer supported lipid membranes. These biomimetic membrane systems are distinguished by a nanopatterned fluidity, enhanced stability and longevity and thus, provide a dedicated reconstitution matrix for membrane-active peptides and transmembrane proteins. Exciting areas for application of composite S-layer membrane systems concern sensor systems involving specific membrane functions. PMID:19303933

  6. Composite S-layer lipid structures

    PubMed Central

    Schuster, Bernhard; Sleytr, Uwe B.

    2010-01-01

    Designing and utilization of biomimetic membrane systems generated by bottom-up processes is a rapidly growing scientific and engineering field. Elucidation of the supramolecular construction principle of archaeal cell envelopes composed of S-layer stabilized lipid membranes led to new strategies for generating highly stable functional lipid membranes at meso- and macroscopic scale. In this review, we provide a state of the art survey how S-layer proteins, lipids, and polysaccharides may be used as basic building blocks for the assembly of S-layer supported lipid membranes. These biomimetic membrane systems are distinguished by a nanopatterned fluidity, enhanced stability and longevity and thus, provide a dedicated reconstitution matrix for membrane-active peptides and transmembrane proteins. Exciting areas for application of composite S-layer membrane systems concern sensor systems involving specific membrane functions. PMID:19303933

  7. Doubly slanted layer structures in holographic gelatin emulsions: solar concentrators

    NASA Astrophysics Data System (ADS)

    Hung, Jenny; Chan, Po Shan; Sun, Caiming; Wing Ho, Choi; Tam, Wing Yim

    2010-04-01

    We have fabricated doubly slanted layer structures in holographic gelatin emulsions using a double-exposure two-beam interference from two light sources with different wavelengths. The doubly slanted layers, with different spacings and overlapping with each other, are fabricated such that they are slanted in opposite directions making a 30° angle with the holographic plate. The doubly slanted layer structures exhibit photonic stop bands corresponding to the two layered structures. More importantly, diffracted light beams from the slanted layers travel in different directions and emerge, through internal reflections, at the opposite edges of the gelatin plate. The doubly slanted layer structures could be used as solar concentrators such that sunlight is separated into different components and steered directly to photovoltaics with the corresponding wavelength sensitivities to enhance energy conversion efficiency.

  8. Preservation of Archaeal Surface Layer Structure During Mineralization

    PubMed Central

    Kish, Adrienne; Miot, Jennyfer; Lombard, Carine; Guigner, Jean-Michel; Bernard, Sylvain; Zirah, Séverine; Guyot, François

    2016-01-01

    Proteinaceous surface layers (S-layers) are highly ordered, crystalline structures commonly found in prokaryotic cell envelopes that augment their structural stability and modify interactions with metals in the environment. While mineral formation associated with S-layers has previously been noted, the mechanisms were unconstrained. Using Sulfolobus acidocaldarius a hyperthermophilic archaeon native to metal-enriched environments and possessing a cell envelope composed only of a S-layer and a lipid cell membrane, we describe a passive process of iron phosphate nucleation and growth within the S-layer of cells and cell-free S-layer “ghosts” during incubation in a Fe-rich medium, independently of metabolic activity. This process followed five steps: (1) initial formation of mineral patches associated with S-layer; (2) patch expansion; (3) patch connection; (4) formation of a continuous mineral encrusted layer at the cell surface; (5) early stages of S-layer fossilization via growth of the extracellular mineralized layer and the mineralization of cytosolic face of the cell membrane. At more advanced stages of encrustation, encrusted outer membrane vesicles are formed, likely in an attempt to remove damaged S-layer proteins. The S-layer structure remains strikingly well preserved even upon the final step of encrustation, offering potential biosignatures to be looked for in the fossil record. PMID:27221593

  9. Preservation of Archaeal Surface Layer Structure During Mineralization.

    PubMed

    Kish, Adrienne; Miot, Jennyfer; Lombard, Carine; Guigner, Jean-Michel; Bernard, Sylvain; Zirah, Séverine; Guyot, François

    2016-01-01

    Proteinaceous surface layers (S-layers) are highly ordered, crystalline structures commonly found in prokaryotic cell envelopes that augment their structural stability and modify interactions with metals in the environment. While mineral formation associated with S-layers has previously been noted, the mechanisms were unconstrained. Using Sulfolobus acidocaldarius a hyperthermophilic archaeon native to metal-enriched environments and possessing a cell envelope composed only of a S-layer and a lipid cell membrane, we describe a passive process of iron phosphate nucleation and growth within the S-layer of cells and cell-free S-layer "ghosts" during incubation in a Fe-rich medium, independently of metabolic activity. This process followed five steps: (1) initial formation of mineral patches associated with S-layer; (2) patch expansion; (3) patch connection; (4) formation of a continuous mineral encrusted layer at the cell surface; (5) early stages of S-layer fossilization via growth of the extracellular mineralized layer and the mineralization of cytosolic face of the cell membrane. At more advanced stages of encrustation, encrusted outer membrane vesicles are formed, likely in an attempt to remove damaged S-layer proteins. The S-layer structure remains strikingly well preserved even upon the final step of encrustation, offering potential biosignatures to be looked for in the fossil record. PMID:27221593

  10. Topologic connection between 2-D layered structures and 3-D diamond structures for conventional semiconductors

    NASA Astrophysics Data System (ADS)

    Wang, Jianwei; Zhang, Yong

    2016-04-01

    When coming to identify new 2D materials, our intuition would suggest us to look from layered instead of 3D materials. However, since graphite can be hypothetically derived from diamond by stretching it along its [111] axis, many 3D materials can also potentially be explored as new candidates for 2D materials. Using a density functional theory, we perform a systematic study over the common Group IV, III–V, and II–VI semiconductors along different deformation paths to reveal new structures that are topologically connected to but distinctly different from the 3D parent structure. Specifically, we explore two major phase transition paths, originating respectively from wurtzite and NiAs structure, by applying compressive and tensile strain along the symmetry axis, and calculating the total energy changes to search for potential metastable states, as well as phonon spectra to examine the structural stability. Each path is found to further split into two branches under tensile strain–low buckled and high buckled structures, which respectively lead to a low and high buckled monolayer structure. Most promising new layered or planar structures identified include BeO, GaN, and ZnO on the tensile strain side, Ge, Si, and GaP on the compressive strain side.

  11. Topologic connection between 2-D layered structures and 3-D diamond structures for conventional semiconductors

    PubMed Central

    Wang, Jianwei; Zhang, Yong

    2016-01-01

    When coming to identify new 2D materials, our intuition would suggest us to look from layered instead of 3D materials. However, since graphite can be hypothetically derived from diamond by stretching it along its [111] axis, many 3D materials can also potentially be explored as new candidates for 2D materials. Using a density functional theory, we perform a systematic study over the common Group IV, III–V, and II–VI semiconductors along different deformation paths to reveal new structures that are topologically connected to but distinctly different from the 3D parent structure. Specifically, we explore two major phase transition paths, originating respectively from wurtzite and NiAs structure, by applying compressive and tensile strain along the symmetry axis, and calculating the total energy changes to search for potential metastable states, as well as phonon spectra to examine the structural stability. Each path is found to further split into two branches under tensile strain–low buckled and high buckled structures, which respectively lead to a low and high buckled monolayer structure. Most promising new layered or planar structures identified include BeO, GaN, and ZnO on the tensile strain side, Ge, Si, and GaP on the compressive strain side. PMID:27090430

  12. Topologic connection between 2-D layered structures and 3-D diamond structures for conventional semiconductors.

    PubMed

    Wang, Jianwei; Zhang, Yong

    2016-01-01

    When coming to identify new 2D materials, our intuition would suggest us to look from layered instead of 3D materials. However, since graphite can be hypothetically derived from diamond by stretching it along its [111] axis, many 3D materials can also potentially be explored as new candidates for 2D materials. Using a density functional theory, we perform a systematic study over the common Group IV, III-V, and II-VI semiconductors along different deformation paths to reveal new structures that are topologically connected to but distinctly different from the 3D parent structure. Specifically, we explore two major phase transition paths, originating respectively from wurtzite and NiAs structure, by applying compressive and tensile strain along the symmetry axis, and calculating the total energy changes to search for potential metastable states, as well as phonon spectra to examine the structural stability. Each path is found to further split into two branches under tensile strain-low buckled and high buckled structures, which respectively lead to a low and high buckled monolayer structure. Most promising new layered or planar structures identified include BeO, GaN, and ZnO on the tensile strain side, Ge, Si, and GaP on the compressive strain side. PMID:27090430

  13. Experimentally excellent beaming in a two-layer dielectric structure

    SciTech Connect

    Tasolamprou, Anna C.; Zhang, Lei; Kafesaki, Maria; Koschny, Thomas; Soukoulis, Costas M.

    2014-09-15

    We demonstrate both experimentally and theoretically that a two-layer dielectric structure can provide collimation and enhanced transmission of a Gaussian beam passing through it. This is due to formation of surface localized states along the layered structure and the coupling of these states to outgoing propagating waves. As a result, a system of multiple cascading two-layers can sustain the beaming for large propagation distances.

  14. Electroluminescent apparatus having a structured luminescence conversion layer

    DOEpatents

    Krummacher, Benjamin Claus

    2008-09-02

    An apparatus such as a light source is disclosed which has an OLED device and a structured luminescence conversion layer disposed on the substrate or transparent electrode of said OLED device and on the exterior of said OLED device. The structured luminescence conversion layer contains color-changing and non-color-changing regions arranged in a particular pattern.

  15. Multi-layer laminate structure and manufacturing method

    DOEpatents

    Keenihan, James R.; Cleereman, Robert J.; Eurich, Gerald; Graham, Andrew T.; Langmaid, Joe A.

    2012-04-24

    The present invention is premised upon a multi-layer laminate structure and method of manufacture, more particularly to a method of constructing the multi-layer laminate structure utilizing a laminate frame and at least one energy activated flowable polymer.

  16. Multi-layer laminate structure and manufacturing method

    SciTech Connect

    Keenihan, James R.; Cleereman, Robert J.; Eurich, Gerald; Graham, Andrew T.; Langmaid, Joe A.

    2013-01-29

    The present invention is premised upon a multi-layer laminate structure and method of manufacture, more particularly to a method of constructing the multi-layer laminate structure utilizing a laminate frame and at least one energy activated flowable polymer.

  17. Surface double-layer structure in (110) oriented BiFeO{sub 3} thin film

    SciTech Connect

    Yang, Tieying; Zhang, Xingmin; Gao, Xingyu; Li, Zhong; Li, Xiaolong; Wang, Can; Feng, Yu; Guo, Haizhong; Jin, Kuijuan

    2014-11-17

    Surface double-layer structure different from the interior was found in BiFeO{sub 3} thin film grown on SrRuO{sub 3} covered SrTiO{sub 3} (110) substrate by pulsed laser deposition. It was shown that BiFeO{sub 3} film exhibits epitaxial phase with single domain. X-ray reflectivity and X-ray photoelectron spectroscopy results revealed a skin layer of less than 1 nm with a reduced electron density and different surface state. Grazing incidence x-ray diffraction convinced a surface multi-domain structure of several nm beneath the surface skin layer. The double-layer near surface structure would be originated from the large depolarization field produced by the single-domain structure with strain.

  18. What Are the Origins of Detached Layers of Dust on Mars ? Investigation with Global Climate Model

    NASA Astrophysics Data System (ADS)

    Bertrand, T.; Spiga, A.; Forget, F.

    2014-12-01

    The climate on Mars is strongly controlled by the amount of dust lifted and transported in the atmosphere, which causes fluctuations of air opacity and affects temperatures and winds. Recently, observations of the vertical dust distribution of the Martian atmosphere by the Mars Climate Sounder on board the Mars Reconnaissance Orbiter revealed a phenomenon which is still poorly understood: the formation of detached layers of dust. These detached layers, also confirmed by the Thermal Emission Spectrometer on-board the Mars Global Surveyor, reside above the planetary boundary layer typically at altitudes between 20 and 40 km and have been mostly observed at low latitudes. These detached layers of dust are not reproduced by Global Climate Models (GCM) and different atmospheric processes are discussed and can be combined to explain their origin, such as small-scale lifting, upslope topographic winds, scavenging by water ice clouds, dust storms… Here we use the Martian GCM developed at the Laboratoire de Météorologie Dynamique (LMD) to simulate the formation of detached layers of dust. To start, we developed a new implementation of the water cycle, taking into account nucleation on dust particles, ice particle growth, and scavenging of dust particles due to the condensation of ice. However, this method didn't yield to satisfying results in the GCM. Then, we performed the parameterization in the GCM of the so-called "rocket dust storms", governed by deep convection and able to inject dust at high altitudes in the Martian troposphere. By coupling this new parameterization with general circulation of the GCM, we succeed to model detached layers of dust. Here we present this parameterization and we discuss about the spatial and temporal variability of the detached layers of dust, in comparison with observations.

  19. Intercalation compounds involving inorganic layered structures

    PubMed

    Constantino; Barbosa; Bizeto; Dias

    2000-01-01

    Two-dimensional inorganic networks can shown intracrystalline reactivity, i.e., simple ions, large species as Keggin ions, organic species, coordination compounds or organometallics can be incorporated in the interlayer region. The host-guest interaction usually causes changes in their chemical, catalytic, electronic and optical properties. The isolation of materials with interesting properties and making use of soft chemistry routes have given rise the possibility of industrial and technological applications of these compounds. We have been using several synthetic approaches to intercalate porphyrins and phthalocyanines into inorganic materials: smectite clays, layered double hydroxides and layered niobates. The isolated materials have been characterized by elemental and thermal analysis, X-ray diffraction, surface area measurements, scanning electronic microscopy, electronic and resonance Raman spectroscopies and EPR. The degree of layer stacking and the charge density of the matrices as well their acid-base nature were considered in our studies on the interaction between the macrocycles and inorganic hosts. PMID:10932103

  20. Interply layer degradation effects on composite structural response

    NASA Technical Reports Server (NTRS)

    Chamis, C. C.; Williams, G. C.

    1983-01-01

    Recent research activities at NASA Lewis Research Center to computationally evaluate the effects of interply layer progressive weakening (degradation) on the structural response of a composite beam are summarized. The structural responses of interest include: (1) bending, (2) buckling, (3) free vibrations, (4) periodic excitation, and (5) impact. Finite element analysis was used for the computational evaluations. The interply layer degradation effects on the various structural responses were determined and assessed as a function of the interply layer modulus varying from 1 million psi down to 1000 psi and even lower for some limiting cases. The results obtained show that the interply layer degradation has generally negligible effects on composite structural response and, therefore, structural integrity, unless the interply layer modulus degrades to about 10,000 psi or less.

  1. High-pressure layered structure of carbon disulfide

    NASA Astrophysics Data System (ADS)

    Naghavi, S. Shahab; Crespo, Yanier; MartoÅák, Roman; Tosatti, Erio

    2015-06-01

    Solid CS2 is superficially similar to CO2, with the same C m c a molecular crystal structure at low pressures, which has suggested similar phases also at high pressures. We carried out an extensive first-principles evolutionary search in order to identify the zero-temperature lowest-enthalpy structures of CS2 for increasing pressure up to 200 GPa. Surprisingly, the molecular C m c a phase does not evolve into β -cristobalite as in CO2 but transforms instead into phases HP2 and HP1, both recently described in high-pressure SiS2. HP1 in particular, with a wide stability range, is a layered P 21/c structure characterized by pairs of edge-sharing tetrahedra and is theoretically more robust than all other CS2 phases discussed so far. Its predicted Raman spectrum and pair correlation function agree with experiment better than those of β -cristobalite, and further differences are predicted between their respective IR spectra. The band gap of HP1-CS2 is calculated to close under pressure, yielding an insulator-metal transition near 50 GPa, in agreement with experimental observations. However, the metallic density of states remains modest above this pressure, suggesting a different origin for the reported superconductivity.

  2. Hybrid inorganic–organic superlattice structures with atomic layer deposition/molecular layer deposition

    SciTech Connect

    Tynell, Tommi; Yamauchi, Hisao; Karppinen, Maarit

    2014-01-15

    A combination of the atomic layer deposition (ALD) and molecular layer deposition (MLD) techniques is successfully employed to fabricate thin films incorporating superlattice structures that consist of single layers of organic molecules between thicker layers of ZnO. Diethyl zinc and water are used as precursors for the deposition of ZnO by ALD, while three different organic precursors are investigated for the MLD part: hydroquinone, 4-aminophenol and 4,4′-oxydianiline. The successful superlattice formation with all the organic precursors is verified through x-ray reflectivity studies. The effects of the interspersed organic layers/superlattice structure on the electrical and thermoelectric properties of ZnO are investigated through resistivity and Seebeck coefficient measurements at room temperature. The results suggest an increase in carrier concentration for small concentrations of organic layers, while higher concentrations seem to lead to rather large reductions in carrier concentration.

  3. An experimental study of forced streamwise vortical structures in a plane mixing layer

    NASA Technical Reports Server (NTRS)

    Mehta, Rabindra D.; Bell, James H.

    1989-01-01

    Streamwise structures have been shown to ride among the primary spanwise vortices in past flow visualization investigations of plane mixing layers. More recently, quantitative measurements were obtained which showed the origin and evolution of streamwise vortices within a mixing layer. In the present study, the effects of perturbing the mixing layer using two different mechanisms are investigated. A serration on the splitter plate trailing edge was found to have a relatively small effect, confined to the near-field development of the streamwise structures. The installation of cylindrical pegs in the high-speed side boundary layer, however, not only generated a regular array of vortex pairs, but also affected the mean development of the mixing layer far downstream. In both cases, the mean streamwise vorticity was found to decay rapidly with increasing downstream distance.

  4. An experimental study of forced streamwise vortical structures in a plane mixing layer

    NASA Astrophysics Data System (ADS)

    Mehta, Rabindra D.; Bell, James H.

    Streamwise structures have been shown to ride among the primary spanwise vortices in past flow visualization investigations of plane mixing layers. More recently, quantitative measurements were obtained which showed the origin and evolution of streamwise vortices within a mixing layer. In the present study, the effects of perturbing the mixing layer using two different mechanisms are investigated. A serration on the splitter plate trailing edge was found to have a relatively small effect, confined to the near-field development of the streamwise structures. The installation of cylindrical pegs in the high-speed side boundary layer, however, not only generated a regular array of vortex pairs, but also affected the mean development of the mixing layer far downstream. In both cases, the mean streamwise vorticity was found to decay rapidly with increasing downstream distance.

  5. Oblique along path toward structures at rear of parcel. Original ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Oblique along path toward structures at rear of parcel. Original skinny mosaic path along edge of structures was altered (delineation can be seen in concrete) path was widened with a newer mosaic to make access to the site safer. Structures (from right) edge of Round House (with "Spring Garden"), Pencil house, Shell House, School House, wood lattice is attached to chain-link fence along north (rear) property line. These structures were all damaged by the 1994 Northridge earthquake. Camera facing northeast. - Grandma Prisbrey's Bottle Village, 4595 Cochran Street, Simi Valley, Ventura County, CA

  6. A New View on Origin, Role and Manipulation of Large Scales in Turbulent Boundary Layers

    NASA Technical Reports Server (NTRS)

    Corke, T. C.; Nagib, H. M.; Guezennec, Y. G.

    1982-01-01

    The potential of passive 'manipulators' for altering the large scale turbulent structures in boundary layers was investigated. Utilizing smoke wire visualization and multisensor probes, the experiment verified that the outer scales could be suppressed by simple arrangements of parallel plates. As a result of suppressing the outer scales in turbulent layers, a decrease in the streamwise growth of the boundary layer thickness was achieved and was coupled with a 30 percent decrease in the local wall friction coefficient. After accounting for the drag on the manipulator plates, the net drag reduction reached a value of 20 percent within 55 boundary layer thicknesses downstream of the device. No evidence for the reoccurrence of the outer scales was present at this streamwise distance thereby suggesting that further reductions in the net drag are attainable. The frequency of occurrence of the wall events is simultaneously dependent on the two parameters, Re2 delta sub 2 and Re sub x. As a result of being able to independently control the inner and outer boundary layer characteristics with these manipulators, a different view of these layers emerged.

  7. An origin of marginal reversal of the Fongen-Hyllingen layered intrusion by prolonged magma emplacement

    NASA Astrophysics Data System (ADS)

    Egorova, V.; Latypov, R.

    2012-04-01

    The ~100 m thick marginal zone of the Fongen-Hyllingen Intrusion (FHI) consists of nonlayered, highly iron-enriched ferrodiorites that are overlain by a ~6 km thick layered sequence of gabbroic to dioritic rocks of the Layered Series. From the base upwards the marginal zone become more primitive as exemplified by a significant increase in whole-rock MgO, Mg-number, and normative An. The reverse trends are also evident from an upward increase in An-content of plagioclase (from ~30 to ~43 at.%) and Mg-number of amphibole (from ~9 to ~23 at.%) and clinopyroxene (from ~23 to ~37 at.%). The marginal zone is abruptly terminated at the contact with the overlying Layered Series as is evident from a step-like increase in Mg-number of mafic minerals and An-content of plagioclase, as well as a sharp increase in whole-rock MgO and Mg-number in overlying olivine gabbronorites of the Layered Series. Based on these features the marginal zone of the FHI can be interpreted as an aborted marginal reversal. Reverse trends in whole-rock and mineral compositions, as well as a sharp break in these parameters are indicative of its formation in an open system with the involvement of the prolonged emplacement of magma that became increasingly more primitive. Such development of the marginal reversal was interrupted by the emplacement of a major influx of more primitive magma that produced the Layered Series. The open system evolution of a basaltic magma chamber may represent a general mechanism for the origin of marginal reversals in mafic sills and layered intrusions.

  8. Failure modes and materials design for biomechanical layer structures

    NASA Astrophysics Data System (ADS)

    Deng, Yan

    Ceramic materials are finding increasing usage in the area of biomechanical replacements---dental crowns, hip and bone implants, etc.---where strength, wear resistance, biocompatibility, chemical durability and even aesthetics are critical issues. Aesthetic ceramic crowns have been widely used in dentistry to replace damaged or missing teeth. However, the failure rates of ceramic crowns, especially all-ceramic crowns, can be 1%˜6% per year, which is not satisfactory to patients. The materials limitations and underlying fracture mechanisms of these prostheses are not well understood. In this thesis, fundamental fracture and damage mechanisms in model dental bilayer and trilayer structures are studied. Principle failure modes are identified from in situ experimentation and confirmed by fracture mechanics analysis. In bilayer structures of ceramic/polycarbonate (representative of ceramic crown/dentin structure), three major damage sources are identified: (i) top-surface cone cracks or (ii) quasiplasticity, dominating in thick ceramic bilayers; (iii) bottom-surface radial cracks, dominating in thin ceramic bilayers. Critical load P for each damage mode are measured in six dental ceramics: Y-TZP zirconia, glass-infiltrated zirconia and alumina (InCeram), glass-ceramic (Empress II), Porcelain (Mark II and Empress) bonded to polymer substrates, as a function of ceramic thickness d in the range of 100 mum to 10 mm. P is found independent of d for mode (i) and (ii), but has a d 2 relations for mode (iii)---bottom surface radial cracking. In trilayer structures of glass/core-ceramic/polycarbonate (representing veneer porcelain/core/dentin structures), three inner fracture origins are identified: radial cracks from the bottom surface in the (i) first and (ii) second layers; and (iii) quasiplasticity in core-ceramic layer. The role of relative veneer/core thickness, d1/d 2 and materials properties is investigated for three core materials with different modulus (114--270GPa

  9. Air-mass origin in the tropical lower stratosphere: The influence of Asian boundary layer air

    NASA Astrophysics Data System (ADS)

    Orbe, Clara; Waugh, Darryn W.; Newman, Paul A.

    2015-05-01

    A climatology of air-mass origin in the tropical lower stratosphere is presented for the Goddard Earth Observing System Chemistry Climate Model. During late boreal summer and fall, air-mass fractions reveal that as much as 20% of the air in the tropical lower stratosphere last contacted the planetary boundary layer (PBL) over Asia; by comparison, the air-mass fractions corresponding to last PBL contact over North America and over Europe are negligible. Asian air reaches the extratropical tropopause within a few days of leaving the boundary layer and is quasi-horizontally transported into the tropical lower stratosphere, where it persists until January. The rapid injection of Asian air into the lower stratosphere—and its persistence in the deep tropics through late (boreal) winter—is important as industrial emissions over East Asia continue to increase. Hence, the Asian monsoon may play an increasingly important role in shaping stratospheric composition.

  10. 52. Humbug Creek Diversion Dam showing original masonry structure at ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    52. Humbug Creek Diversion Dam showing original masonry structure at right and concrete weir at left added later. Photographer James Eastwood, 1986. Source: Salt River Project. - Waddell Dam, On Agua Fria River, 35 miles northwest of Phoenix, Phoenix, Maricopa County, AZ

  11. 10. KIDNER BRIDGE STRUCTURAL STEEL DETAIL SHEET (original plan sheet ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    10. KIDNER BRIDGE STRUCTURAL STEEL DETAIL SHEET (original plan sheet is in possession of Ball State University, Drawings and Documents Archive, COllege of Architecture and Planing, Ball State University, Muncie, Indiana, 47306 - Kidner Bridge, Spanning Mississinewa River at County Road 700 South, Upland, Grant County, IN

  12. Classification of structures in the stable boundary layer

    NASA Astrophysics Data System (ADS)

    Belusic, Danijel

    2015-04-01

    Ubiquitous but generally unknown flow structures populate the stable boundary layer at scales larger than turbulence. They introduce nonstationarity, affect the generation of turbulence and induce fluxes. Classification of the structures into clusters based on a similarity measure could reduce their apparent complexity and lead to better understanding of their characteristics and mechanisms. Here we explore different approaches to detect and classify structures, the usefulness of those approaches, and their potential to provide better understanding of the stable boundary layer.

  13. Six-layer structure for genomics and its applications.

    PubMed

    Kamatani, Naoyuki

    2016-03-01

    The term 'genetics' was coined before an understanding of DNA sequence data was achieved, and it is now insufficient to describe the broad areas in which DNA data have important roles. The term genomics is more broadly descriptive, but it does not provide a satisfactory conceptual framework that scientists can share. Here I propose a six-layer structure that describes the entire scientific field for 'genomics'. The proposed layers are 'life' as the uppermost layer, followed by 'species', 'population', 'family', 'individual' and finally 'cell' as the bottommost layer. In each pair of adjacent layers, each member of the upper layer comprises a set of members of the lower layer. In each layer, we can define consistent partial orders of members based on genomic data in the forms of phylogenic and pedigree trees. Although total orders such as those defined for time and space in physics cannot be defined in biology, defining consistent partial orders allows mathematical analysis to be performed. I will show that mathematical genetics studies can be understood as attempts to bridge gaps between layers of the proposed six-layer structure, while genetic tests can be understood as procedures to differentiate among members of each layer by using genomic data. PMID:26559752

  14. Chasma Australe Mars: Structural Framework for a Catastrophic Outflow Origin

    NASA Technical Reports Server (NTRS)

    Anguita, F.; Babin, R.; Benito, G.; Collado, A.; Gomez, D.; Rice, J. W.

    1998-01-01

    Chasma Australe is the most remarkable of the martian south pole erosional reentrants carved in the polar layered deposits. Ms chasma originates near the south pole and runs across the polar troughs over a distance of about 500 km. Its width varies between 20 and 80 km and, with a depth up to 1000 m, it reaches the bedrock. Following an idea put forward originally for Chasma Boreale, we propose for the genesis of Chasma Australe a mechanism of catastrophic outflow preceded by a tectonically induced powerful sapping process. A detailed geomorphological analysis of Chasma Australe shows erosional and depositional features that can be interpreted as produced by the motion of a fluid. Like other polar reentrants, Chasma Australe is clearly assymetric, with a steep eastern margin where basal and lateral erosion prevailed, and a gentler western side, where the stepped topography and bedrock spurs favored deposition.

  15. Original size of the Vredefort structure, South Africa

    NASA Technical Reports Server (NTRS)

    Therriault, A. M.; Reid, A. M.; Reimold, W. U.

    1993-01-01

    The Vredefort structure is located approximately 120 km southwest of Johannesburg, South Africa, and is deeply eroded. Controversies remain on the origin of this structure with the most popular hypotheses being: (1) by impact cratering about 2.0 Ga; (2) as a cryptoexplosion structure about 2.0 Ga; and (3) by purely tectonic processes starting at about 3.0 Ga and ending with the Vredefort event at 2.0 Ga. In view of recent work in which the granophyre dikes are interpreted as the erosional remants of a more extensive impact melt sheet, injected downward into the underlying country rocks, the impact origin hypothesis for Vredefort is adopted. In order to estimate the original dimensions of the Vredefort impact structure, it is assumed that the structure was initially circular, that its predeformation center corresponds to the center of the granitic core, and that the pre-Vredefort geology of the area prior to approximately 2.0 Ga ago is as suggested by Fletcher and Reimold. The spatial relationship between shock metamorphic effects, the shock pressures they record, and the morphological features of the crater were established for a number of large terrestrial craters. The principles of crater formation at large complex impact structures comparable in size to Vredefort were also established, although many details remain unresolved. An important conclusion is that the transient crater, which is formed directly by excavation and displacement by the shock-induced cratering flow-field (i.e., the particle velocity flow field existing in the region of the transient crater but behind the initial outgoing shock front), is highly modified during the late stage processes. The original transient crater diameter lies well within the final rim of the crater, which is established by structural movements during late-stage cavity modification.

  16. 2-DE combined with two-layer feature selection accurately establishes the origin of oolong tea.

    PubMed

    Chien, Han-Ju; Chu, Yen-Wei; Chen, Chi-Wei; Juang, Yu-Min; Chien, Min-Wei; Liu, Chih-Wei; Wu, Chia-Chang; Tzen, Jason T C; Lai, Chien-Chen

    2016-11-15

    Taiwan is known for its high quality oolong tea. Because of high consumer demand, some tea manufactures mix lower quality leaves with genuine Taiwan oolong tea in order to increase profits. Robust scientific methods are, therefore, needed to verify the origin and quality of tea leaves. In this study, we investigated whether two-dimensional gel electrophoresis (2-DE) and nanoscale liquid chromatography/tandem mass spectroscopy (nano-LC/MS/MS) coupled with a two-layer feature selection mechanism comprising information gain attribute evaluation (IGAE) and support vector machine feature selection (SVM-FS) are useful in identifying characteristic proteins that can be used as markers of the original source of oolong tea. Samples in this study included oolong tea leaves from 23 different sources. We found that our method had an accuracy of 95.5% in correctly identifying the origin of the leaves. Overall, our method is a novel approach for determining the origin of oolong tea leaves. PMID:27283647

  17. Impact origin of the Sudbury structure: Evolution of a theory

    NASA Technical Reports Server (NTRS)

    Lowman, Paul D., Jr.

    1992-01-01

    This paper reviews the origin, development, and present status of the widely accepted theory, proposed by Robert S. Dietz in 1962, that the Sudbury structure was formed by meteoritic or asteroidal impact. The impact theory for the origin of the Sudbury structure seems supported by a nearly conclusive body of evidence. However, even assuming an impact origin to be correct, at least three major questions require further study: (1) the original size and shape of the crater, before tectonic deformation and erosion; (2) the source of the melt now forming the Sudbury Igneous Complex; and (3) the degree, if any, to which the Ni-Cu-platinum group elements are meteoritic. The history of the impact theory illustrates several under-appreciated aspects of scientific research: (1) the importance of cross-fertilization between space research and terrestrial geology; (2) the role of the outsider in stimulating thinking by insiders; (3) the value of small science, at least in the initial stages of an investigation, Dietz's first field work having been at his own expense; and (4) the value of analogies (here, between the Sudbury Igneous Complex and the maria), which although incorrect in major aspects, may trigger research on totally new lines. Finally, the Sudbury story illustrates the totally unpredictable and, by implication, unplannable nature of basic research, in that insight to the origin of the world's then-greatest Ni deposit came from the study of tektites and the Moon.

  18. Elastodynamic behavior of the three dimensional layer-by-layer metamaterial structure

    SciTech Connect

    Aravantinos-Zafiris, N.; Sigalas, M. M.; Economou, E. N.

    2014-10-07

    In this work, we numerically investigate for the first time the elastodynamic behavior of a three dimensional layer-by-layer rod structure, which is easy to fabricate and has already proved to be very efficient as a photonic crystal. The Finite Difference Time Domain method was used for the numerical calculations. For the rods, several materials were examined and the effects of all the geometric parameters of the structure were also numerically investigated. Additionally, two modifications of the structure were included in our calculations. The results obtained here (for certain geometric parameters), exhibiting a high ratio of longitudinal over transverse sound velocity and therefore a close approach to ideal pentamode behavior over a frequency range, clearly show that the layer-by-layer rod structure, besides being an efficient photonic crystal, is a very serious contender as an elastodynamic metamaterial.

  19. New Evidence for the Origin of Layered Deposits in Valles Marineris

    NASA Astrophysics Data System (ADS)

    Murchie, S.; Seelos, F.; Roach, L.; Mustard, J.; Milliken, R.; Arvidson, R.; Wiseman, S.; Lichtenberg, K.; Andrews-Hanna, J.; Bibring, J.; Bishop, J.; Parente, M.; Morris, R.

    2008-12-01

    Results from CRISM, HiRISE, and CTX on MRO provide new insights into the origin of interior layered deposits (ILDs) in Valles Marineris. A well-exposed, thick sequence in western Candor Chasma has spectral properties consistent with basaltic sand mixed with nanophase iron oxide-rich dust, with the addition of sulfates and crystalline ferric oxides. Most of the deposit is dominated spectrally by the dust component. Monohydrated and polyhydrated sulfates are concentrated in separate, interbedded layers, which in some cases are traceable over tens of kilometers. Monhydrated sulfates dominate the lower part of the deposits whereas polyhydrated sulfates are more common in upper strata. The deposits are partially mantled by low- albedo eolian ripples that contain pyroxenes similar in composition to what is found on the surrounding plateau, plus sulfates predominantly in monohydrated form. The dark ripples originate from discrete, friable layers. Similar dark, erodible layers elsewhere on Mars have been interpreted as buried eolian sand. Crystalline ferric oxides are concentrated in the sulfate-rich layers, and mass wasting has accumulated them at the base of steep slopes to form the deposits of gray hematite detected by TES. The persistence of monohydrated sulfates in debris shows that alteration of monohydrated to polyhydrated sulfates, proposed as an important weathering process, takes long compared to formation of the thin layer that dominates reflectance properties. The observed stratification of sulfate compositions implies differences in the abundance of liquid water or brine chemistry during deposition or early chemical modification of sediments. Inferred mineralogy and compositional stratification are similar to what is observed in sulfate-rich sediments in the Meridiani and Aram Chaos regions. The Meridiani deposits were proposed to accumulate where evaporites formed in areas of groundwater discharge and cemented eolian sediments, in which coarse- grained

  20. Prolonged reorganization of thiol-capped Au nanoparticles layered structures

    NASA Astrophysics Data System (ADS)

    Kundu, Sarathi; Das, Kaushik; Konovalov, Oleg

    2013-09-01

    Prolonged reorganization behaviour of mono-, di-, tri- and multi-layer films of Au nanoparticles prepared by Langmuir-Blodgett method on hydrophobic Si(001) substrates have been studied by using X-ray scattering techniques. Out-of-plane study shows that although at the initial stage the reorganization occurs through the compaction of the films keeping the layered structure unchanged but finally all layered structures modify to monolayer structure. Due to this reorganization the Au density increases within the nanometer thick films. In-plane study shows that inside the reorganized films Au nanoparticles are distributed randomly and the particle size modifies as the metallic core of Au nanoparticles coalesces.

  1. Origin of the F-Layer by ``Snowfall'' in the Earth's Core

    NASA Astrophysics Data System (ADS)

    Hernlund, J. W.; Li, J.; Armentrout, M. M.; Buono, A. S.; Chen, B.; Durand, S.; Gaeman, J.; Pigott, J. S.; Waszek, L.; Zheng, Z.

    2010-12-01

    Recent seismological observations of phases reflecting (PKiKP), diffracting (PKPdiff), or going through the inner core (PKIKP) called for modification of PREM at the top of the Inner Core Boundary (ICB). Both the AK135 and PREM2 models proposed a flattened P-wave velocity gradient relative to PREM in the ~200 km region above the ICB, often referred to as the F-layer. This reduced velocity gradient implies density stratification, which may reflect a gradient in the light element concentration decreasing from the top of the F-layer to the ICB. Here we propose a mechanism to generate a chemical stratification in the F-layer through crystallization of solid iron “snow” at the top of the F-layer, which then precipitates, partially dissolves, and eventually accumulates at the ICB to produce the F-layer and contribute to the growth of the inner core. The formation of iron “snow” in the outer core (OC) requires that the core geotherm intercepts the FeX liquidus, where X is an alloying light element, to create a region of stability for solid iron at the base of the OC. This study examines two potential scenarios in which iron “snowfall” might occur in the F-layer. The first scenario involves the FeX liquidus gradient decreasing or even changing sign such that a region of solid stability is created at the top of the F-layer. This behavior is observed in the Fe-S binary system at lower pressures and has been proposed to cause “snowing” in the interiors of Mercury and Ganymede. In the second case, the outer core temperature may increase relative to the FeX liquidus near the ICB due to viscomagnetic heating. Results based on mineral physics calculations of an iron-sulfur binary system show that an F-layer composition ranging from 7.2 wt% S at the top of the F-layer to 5.7 wt% S at the ICB is sufficient to explain the Vp structure of the F-layer in AK135. In these calculations, the density and bulk modulus as a function of depth were determined using the 3rd

  2. Origin of Martian Interior Layered Deposits (ILDs) by atmospherically driven processes

    NASA Astrophysics Data System (ADS)

    Michalski, J. R.; Niles, P. B.

    2011-12-01

    Since the first photogeologic exploration of Mars, vast mounds of layered sediments found within the Valles Marineris canyon system (Interior Layered Deposits or ILDs) have remained unexplained. Recent spectroscopic results showing that these materials contain coarse-grained hematite [1] and sulfate [2-8] suggest that they are fundamentally similar to layered sulfate deposits seen elsewhere on Mars [3], and are therefore a key piece of Mars' global aqueous history. Layered sulfate deposits (including ILDs) are often considered to have formed in association with transient, wet surface environments caused by groundwater upwelling [9] in the Hesperian. Here, we use spectroscopic mapping along with geomorphic observations and mass balance calculations to demonstrate that the sulfate-bearing ILDs likely did not form due to groundwater upwelling or any similar playa-lacustrine scenario. Instead, the ILDs likely formed from atmospherically driven processes in a configuration similar to that observed today. We suggest that Hesperian layered sulfate deposits formed in response to massive amounts of pyroclastic volcanism and SO2-outgassing that peaked near 3.5-3.7 Ga in a Martian climate that was largely cold and dry. This origin for the ILDs is also applicable to other layered terrain of similar age and characteristics, including sulphate-bearing crater fill, chaos terrains, and the Meridiani Planum sediments. [1] Weitz, C. M., Lane, M. D., Staid, M. & Dobrea, E. N. Gray hematite distribution and formation in Ophir and Candor chasmata. Journal of Geophysical Research-Planets 113, doi:E02016 10.1029/2007je002930 (2008). [2] Wendt, L. et al. Sulfates and iron oxides in Ophir Chasma, Mars, based on OMEGA and CRISM observations. Icarus 213, 86-103, doi:10.1016/j.icarus.2011.02.013 (2011). [3] Murchie, S. et al. Evidence for the origin of layered deposits in Candor Chasma, Mars, from mineral composition and hydrologic modeling. Journal of Geophysical Research-Planets 114, doi

  3. Origin of structures in disc galaxies: internal or external processes?

    NASA Astrophysics Data System (ADS)

    Athanassoula, E.

    2015-03-01

    Disc galaxies have a number of structures, such as bars, spirals, rings, discy bulges, m = 1 asymmetries, thick discs, warps etc. I will summarise what is known about their origin and in particular whether it is due to an external or an internal process. The former include interactions, major or minor mergers etc, while the latter include instabilities, or driving by another component of the same galaxy, as e.g. the bar or the halo. In cases where more than one process is eligible, I will analyse whether it is possible to distinguish between different origins, and what it would take to do so. This discussion will show that, at least in some cases, it is difficult to distinguish between an internal and an external origin.

  4. Photothermal characterization of solid two-layer spherical structures

    NASA Astrophysics Data System (ADS)

    Xie, Guangxi; Chen, Zhifeng; Wang, Chinhua; Mandelis, Andreas

    2010-03-01

    A theoretical model for evaluating 2-layer solid spherical samples that are heated by a modulated light is presented using the Green function method. The specific Green's function corresponding to the composite structure has been derived. The characteristics of the thermal-wave field with respect to the thermophysical properties of the material and the geometrical factors are presented. Experimental results obtained with laser infrared photothermal radiometry show the capability of the model for characterizing the spherical layered structures.

  5. The origin of layered gabbros from the mid lower ocean crust, Hess Deep, East Pacific Rise

    NASA Astrophysics Data System (ADS)

    Cheadle, M. J.; Brown, T. C.; Ceuleneer, G.; Meyer, R.

    2014-12-01

    IODP Exp. 345 Holes U1415 I & J cored a ~30m thick unit of conspicuously layered gabbroic rocks from the lower plutonic crust at Hess Deep. These rocks likely come from >1500m below the dike gabbro transition and thus provide an unique opportunity to study the origin of layering and the formation of relatively deep, fast spread plutonic crust formed at the EPR. Here we report the initial results of a comprehensive high-resolution petrologic, geochemical and petrographic study of this unit, which focuses on a fairly continuous 1.5m long section recovered at Hole I. The rocks consist of opx-bearing olivine gabbro, olivine gabbro and gabbro and exhibit 1-10cm scale modal layering. Some layers host spectacular 2-3 cm diameter cpx oikocrysts encapsulating partially resorbed plagioclase laths. Downhole variations in mineral chemistry are complicated. Olivine, cpx and opx Mg#'s partly reflect equilibration and show a subtle metre-scale variation (1-2 Mg#), whereas, for example, plagioclase anorthite, and cpx TiO2 contents reveal a more complicated 10-20 cm-scale variation (2-4 An, and 0.2 TiO2). Mineral zonation, for all but Mg# in equilibrated olivine, is of higher magnitude than downhole variations in average mineral compositions. Trace element geochemistry reveals rather homogeneous plagioclase and opx compositions; however cpx exhibits variation at the mineral scale. Cpx shows an increased range of, and highest REE concentrations, in the more olivine rich, near cotectic, composition gabbros, whereas the more plagioclase rich, cumulates show no variation of, and low REE, concentrations.Plagioclase fabrics are moderate to weak and partially modally controlled, but the strength of the plagioclase crystallographic preferred orientation (CPO) varies dramatically, within the 1.5m core showing a significant part of the variation recorded by Oman ophiolite plutonic crust. Plagioclase shape preferred orientation and CPO match well suggesting that diffusion enabled compaction

  6. Origin of the Vredefort structure, South Africa: Impact model

    NASA Technical Reports Server (NTRS)

    Therriault, A. M.; Reid, A. M.; Reimold, W. U.

    1993-01-01

    A model is presented for the evolution of the Vredefort structure, based on reasoned constraints on the original size of the Vredefort structure from observational data and comparison with other terrestrial impact craters. The models for complex craters (ring and multi-ring basins) of Croft, Grieve, and co-workers, and Schultz and co-workers, were used to reconstruct the Vredefort impact event, using a final crater diameter of 300 km, as estimated by Therriault. The sequence of events (stages 2-5) is illustrated diagramatically. The stages are: initial penetration, excavation and compression, dynamic rebound and uplift, maximum radial growth and collapse, and final crater form.

  7. Design of layered structure for thermal cloak with complex shape

    NASA Astrophysics Data System (ADS)

    Yuan, Xuebo; Lin, Guochang; Wang, Youshan

    2016-07-01

    Thermal cloaks have potential applications in thermal protection and sensing, and those cloaks with complex shapes are much more efficient in application. Layered discretization is a valid way to realize thermal cloaks designed through spatial transformation which are usually nonhomogeneous and anisotropic. However, previous studies are limited to two-dimensional cylindrical ones. Based on the theories of spatial transformation and effective medium, a four-step design method for layered structure of thermal cloak with complex shape is proposed. It is expected to realize the designed layered structure by utilizing the existing regular materials. According to the numerical simulations, the thermal cloaking performances of layered structures are good and close to that of the perfect thermal cloaks. This study has provided an effective way for realizing thermal cloak with complex shape.

  8. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOEpatents

    Murduck, James M.; Lepetre, Yves J.; Schuller, Ivan K.; Ketterson, John B.

    1989-01-01

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources.

  9. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOEpatents

    Murduck, J.M.; Lepetre, Y.J.; Schuller, I.K.; Ketterson, J.B.

    1989-07-04

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources. 8 figs.

  10. Geological structure, composition and evolution of crustal layers of the Japan Sea

    NASA Astrophysics Data System (ADS)

    Karp, Boris Ya.; Lelikov, Eugene P.

    1990-09-01

    Seismic refraction data have shown that the crustal thickness in the Japan Sea basins (Japan Basin and Yamato Basin) is 12-16 km, but the crustal thickness under the Yamato Rise has not been determined, although it seems to be considerably larger. The crustal thickness in the Asian continental slope and shelf reaches 26 km. All crustal structure studied has a similar seismic layering: a sedimentary layer, a layer 2 (or intermediate layer) and a layer 3 (or the lower crustal layer). The velocities and ranges of velocity variations in the layers are almost similar. The greatest difference in crustal thickness is between layer 2 and layer 3. The thickness of layer 2 in the deep-sea basins is 1.5-5.3 km, beneath the Yamato Rise it is 6.0-7.5 km and beneath the shelf and continental slope it is 9.8-11.7 km. The composition of layer 2 beneath the topographic highs and the continental slope has been studied by bottom sampling. Proterozoic to Paleogene granitic rocks and Archean-Proterozoic metamorphic rocks are the most common rock types. These rocks were formed at great and medium crustal depths, presumably in crust with a thickness of 30-40 km containing a layer 2 with a thickness of 10-15 km. The discrepancy between original and present crustal thickness suggests that the continental crust was thinned during the formation of the Japan Sea basin. Magmatic erosion of the intermediate layer during the ascent of mantle masses is proposed as a probable mechanism of this process. The result of this process could be a replacement of the sialic layer of the crust by basaltic rocks, which resulted in the formation of acid and alkahne melts erupted onto the surface during Oligocene-Early Miocene time.

  11. Origins of large critical temperature variations in single-layer cuprates

    SciTech Connect

    Palczewski, A.D.; Kondo, T.; Khasanov, R.; Kolesikov, N.N.; Timonina; Rotenberg, E.; Ohta, T.; Bendounan, A.; Sassa, Y.; Fedorov, A.; Paihes, S.; Santander-Syro, A.F.; Chang, J.; Shi, M.; Mesot, J.; Fretwell, H.M.; Kaminski, A.

    2008-08-26

    We study the electronic structures of two single-layer superconducting cuprates, Tl{sub 2}Ba{sub 2}CuO{sub 6+{delta}} (Tl2201) and (Bi{sub 1.35}Pb{sub 0.85}) (Sr{sub 1.47}La{sub 0.38}) CuO{sub 6+{delta}} (Bi2201) which have very different maximum critical temperatures (90 K and 35 K, respectively) using angular-resolved photoemission spectroscopy (ARPES). We are able to identify two main differences in their electronic properties. First, the shadow band that is present in double-layer and low T{sub c,max} single-layer cuprates is absent in Tl2201. Recent studies have linked the shadow band to structural distortions in the lattice and the absence of these in Tl2201 may be a contributing factor in its T{sub c,max}. Second, Tl2201's Fermi surface (FS) contains long straight parallel regions near the antinode, while in Bi2201 the antinodal region is much more rounded. Since the size of the superconducting gap is largest in the antinodal region, differences in the band dispersion at the antinode may play a significant role in the pairing and therefore affect the maximum transition temperature.

  12. Structure and properties of ITQ-8: a hydrous layer silicate with microporous silicate layers.

    PubMed

    Marler, Bernd; Müller, Melanie; Gies, Hermann

    2016-06-21

    ITQ-8 is a new hydrous layer silicate (HLS) with a chemical composition of [C4H8(C7H13N)2]8 [Si64O128(OH)16]·48H2O per unit cell. The synthesis of ITQ-8 was first described in 2002 by Díaz-Cabañas et al., the structure of this material, however, remained unsolved at that time. Physico-chemical characterization using solid-state NMR spectroscopy, SEM, TG-DTA, and FTIR spectroscopy confirmed that ITQ-8 is a layer silicate. The XRD powder pattern was indexed in the monoclinic system with lattice parameters of a0 = 35.5168(5) Å, b0 = 13.3989(2) Å, c0 = 16.0351(2) Å, β = 106.74(2)°. The crystal structure was solved by simulated annealing. Rietveld refinement of the structure in space group C2/c converged to residual values of RBragg = 0.023, RF = 0.022 and chi(2) = 2.3 confirming the structure model. The structure of ITQ-8 contains silicate layers with a topology that resembles a (11-1) section of the framework of zeolite levyne. So far, this layer topology is unique among layer silicates. The layer can be regarded as made up of 4-, 6-, double-six and 8-rings which are interconnected to form cup-like "half-cages". Unlike other HLSs, which possess impermeable silicate layers, ITQ-8 contains 8-rings pores with a free diameter of 3.5 Å × 3.4 Å and can be regarded as a "small-pore layer silicate". In the crystal structure, the organic cations, 1,4-diquiniclidiniumbutane, used as structure directing agents during synthesis are intercalated between the silicate layers. Clusters (bands) of water molecules which are hydrogen bonded to each other and to the terminal Si-OH/Si-O(-) groups are located between the organic cations and interconnect the silicate layers. ITQ-8 is a very interesting material as precursor for the synthesis of microporous framework silicates by topotactic condensation or interlayer expansion reactions leading to 3D micro-pore systems which may be useful in applications as e.g. catalysts, catalyst supports and adsorbents of for separation. PMID

  13. Manipulation by exchange coupling in layered magnetic structures

    SciTech Connect

    Moskalenko, M. A.; Uzdin, V. M.; Zabel, H.

    2014-02-07

    Exchange coupling in magnetic heterostructures can be modified via introduction of additional magnetic spacer layers at the interfaces. The magnetic characteristics and the spacer layer thickness determine the functional properties of the whole system. We show that the hysteresis loop area of trilayer spring magnets with two different soft magnetic layers (s1, s2) and one hard magnetic layer (h) with the sequence s1/s2/h can be increased as compared to both bilayer structures s1/h and s2/h with the same total thickness of the soft layers and for definite thickness ratios of the soft layers and their sequences. For ferrimagnetic spin valves, the perpendicular exchange bias effect can be tuned via the thickness of non-magnetic spacer layers at the interface, which determine the exchange coupling between ferrimagnets. A simple quasi one-dimensional phenomenological model is able to describe the magnetic hysteresis of even complex layered structures and to predict optimal geometrical and magnetic parameters of such heterostructures.

  14. Origin of superconductivity in layered centrosymmetric LaNiGa{sub 2}

    SciTech Connect

    Tütüncü, H. M.; Srivastava, G. P.

    2014-01-13

    We have examined the origin of superconductivity in layered centrosymmetric LaNiGa{sub 2} by employing a linear response approach based on the density functional perturbation theory. Our results indicate that this material is a conventional electron-phonon superconductor with intermediate level of coupling strength, with the electron-phonon coupling parameter of 0.70, and the superconducting critical temperature of 1.90 K in excellent accordance with experimental value of 1.97 K. The largest contribution to the electron-phonon coupling comes from the La d and Ga p electrons near the Fermi energy and the B{sub 3g} phonon branch resulting from vibrations of these atoms along the Γ-Z symmetry line in the Brillouin zone.

  15. Structure analysis of layer-by-layer multilayer films of colloidal particles

    NASA Astrophysics Data System (ADS)

    Batys, Piotr; Nosek, Magdalena; Weroński, Paweł

    2015-03-01

    We have mimicked the layer-by-layer self-assembling process of monodisperse colloidal particles at a solid-liquid interface using the extended random sequential adsorption model of hard spheres. We have studied five multilayer structures of similar thickness, each created at a different single-layer surface coverage. For each multilayer, we have determined its particle volume fraction as a function of distance from the interface. Additionally, we have characterized the film structure in terms of 2D and 3D pair-correlation functions. We have found that the coverage of about 0.3 is optimal for producing a uniform, constant-porosity multilayer in a minimum number of adsorption cycles. The single-layer coverage has also a significant effect on the primary maximum of 2D radial distribution function. In the case of multilayer with the coverage lower than 0.30 the 2D pair-correlation functions of even layers exhibit maxima decreasing with the increase in the layer number. We have verified our theoretical predictions experimentally. We have used fluorescence microscopy to determine the 2D pair-correlation functions for the second, third, and fourth layers of multilayer formed of micron-sized spherical latex particles. We have found a good agreement between our theoretical and experimental results, which confirms the validity of the extended RSA model.

  16. RBS analysis of heteroepitaxial layered structures

    NASA Astrophysics Data System (ADS)

    Flagmeyer, R.

    1992-05-01

    Rutherford backscattering and channeling of energetic ions is applied to III-V semiconductor epitaxial systems. Grazing incidence RBS is employed to observed in-depth profiles of chemical composition, especially the well width Lz, of AlGaAs/GaAs and InGaAs/InP single quantum well (SQW) structures. In case of highly lattice-mismatched materials, RBS/channeling analyses reveal the pseudomorphic or relaxed state of the corresponding crystal lattices. Some new aspects in determining the elastic strain and in locating the misfit dislocation array in InGaAs/GaAs single heterostructures and superlattices are discussed. Finally, attention is drawn to the "internal" lattice distortion in epilayers of pseudobinary alloys, and the high sensibility of dechanneling to the intrinsic atomic displacements is demonstrated.

  17. Energy dissipating structures in turbulent boundary layers

    NASA Astrophysics Data System (ADS)

    Farge, Marie; Nguyen van Yen, Romain; Schneider, Kai

    2011-11-01

    We present numerical experiments of a dipole crashing into a wall, a generic event in two-dimensional incompressible flows with solid boundaries. The Reynolds number Re is varied from 985 to 7880, and no-slip boundary conditions are approximated by Navier boundary conditions with a slip length proportional to Re-1 . Energy dissipation is shown to first set up within a vorticity sheet of thickness proportional to Re-1 in the neighborhood of the wall, and to continue as this sheet rolls up into a spiral and detaches from the wall. The energy dissipation rate integrated over these regions appears to converge towards Rey -independent values, indicating the existence of energy dissipating structures that persist in the vanishing viscosity limit. Details can be found in Nguyen van yen, Farge and Schneider, PRL, 106, 184502 (2011).

  18. Impact origin of the Newporte structure, Williston basin, North Dakota

    SciTech Connect

    Forsman, N.F.; Gerlach, T.R.; Anderson, N.L.

    1996-05-01

    The Newporte field is located just south of the United States-Canada border in Renville County, North Dakota, in the north-central portion of the Williston basin. Integration of seismic, well-log, and core data supports the interpretation of an impact origin for the Newporte structure. The structure involves both Precambrian basement and lower Paleozoic sedimentary units. Oil and gas production began in 1977 from brecciated basement rocks along the rim of the 3.2-km-diameter circular structure. Both well logs and seismic data were used to determine thickness changes of sedimentary units overlying the structure. Resulting isopach maps reveal a circular, bowl-shaped feature with a recognizable rim. Microscopic shock metamorphic features in quartz and feldspar are visible in basement clasts that form a mixed breccia with Cambrian Deadwood sandstone within the western rim of the structure. A Late Cambrian-Early Ordovician age is suggested for the structure because of the presence of flatlying Deadwood sandstone overlying mixed basement/sandstone breccia along portions of the rim. Identification of the Newporte structure as an impact crater adds to the growing base of evidence revealing the relevance of impact craters to petroleum exploration.

  19. Development of a dual layered dielectric-loaded accelerating structure.

    SciTech Connect

    Gai, W.; Liu, W.; Jing, C.; Kanareykin, A.; Antipov, S.; Nenasheva, E.; Schoessow, P.; High Energy Physics; Euclid Techlabs, LLC; Illinois Inst. of Tech.; KEK

    2008-09-01

    Due to the high magnetic field-induced surface currents on its conducting sleeve, a conventional single layer Dielectric-Loaded Accelerating (DLA) structure exhibits a relatively high RF loss. One possible way to solve this problem is to use multilayered DLA structures. In these devices, the RF power attenuation is reduced by making use of the Bragg Fiber concept: the EM fields are well confined by multiple reflections from multiple dielectric layers. This paper presents the design of an X-band dual layer DLA structure as well as the results of bench tests of the device. We will also present results on the design, numerical modeling, and fabrication of structures for coupling RF into multilayer DLAs such as a novel TM{sub 03} mode launcher and a TM{sub 01}-TM{sub 03} mode converter using dielectric-loaded corrugated waveguide.

  20. The simulation of coherent structures in a laminar boundary layer

    NASA Technical Reports Server (NTRS)

    Breuer, Kenny; Landahl, Marten T.; Spalart, Philippe R.

    1987-01-01

    Coherent structures in turbulent shear flows were studied extensively by several techniques, including the VITA technique which selects rapidly accelerating or decelerating regions in the flow. The evolution of a localized disturbance in a laminar boundary layer shows strong similarity to the evolution of coherent structures in a turbulent-wall bounded flow. Starting from a liftup-sweep motion, a strong shear layer develops which shares many of the features seen in conditionally-sampled turbulent velocity fields. The structure of the shear layer, Reynolds stress distribution, and wall pressure footprint are qualitatively the same, indicating that the dynamics responsible for the structure's evolution are simple mechanisms dependent only on the presence of a high mean shear and a wall and independent of the effects of local random fluctuations and outer flow effects. As the disturbance progressed, the development of streak-like-high- and low-speed regions associated with the three-dimensionality.

  1. Two-Dimensional Layered Oxide Structures Tailored by Self-Assembled Layer Stacking via Interfacial Strain.

    PubMed

    Zhang, Wenrui; Li, Mingtao; Chen, Aiping; Li, Leigang; Zhu, Yuanyuan; Xia, Zhenhai; Lu, Ping; Boullay, Philippe; Wu, Lijun; Zhu, Yimei; MacManus-Driscoll, Judith L; Jia, Quanxi; Zhou, Honghui; Narayan, Jagdish; Zhang, Xinghang; Wang, Haiyan

    2016-07-01

    Study of layered complex oxides emerge as one of leading topics in fundamental materials science because of the strong interplay among intrinsic charge, spin, orbital, and lattice. As a fundamental basis of heteroepitaxial thin film growth, interfacial strain can be used to design materials that exhibit new phenomena beyond their conventional forms. Here, we report a strain-driven self-assembly of bismuth-based supercell (SC) with a two-dimensional (2D) layered structure. With combined experimental analysis and first-principles calculations, we investigated the full SC structure and elucidated the fundamental growth mechanism achieved by the strain-enabled self-assembled atomic layer stacking. The unique SC structure exhibits room-temperature ferroelectricity, enhanced magnetic responses, and a distinct optical bandgap from the conventional double perovskite structure. This study reveals the important role of interfacial strain modulation and atomic rearrangement in self-assembling a layered singe-phase multiferroic thin film, which opens up a promising avenue in the search for and design of novel 2D layered complex oxides with enormous promise. PMID:27295399

  2. Original Size and Shape of the Sudbury Structure

    NASA Technical Reports Server (NTRS)

    Lowman, P. D., Jr.

    1997-01-01

    This paper presents new evidence bearing on the original size and shape of the Sudbury impact structure. Current opinion is almost unanimous that the structure is a multiring basin with an original diameter of about 200 km and a circular shape that has since been shortened in a northwest-southeast direction by Penokean deformation Evidence for this interpretation, collected chiefly from north of the Sudbury Igneous Complex (SIC), includes supposed outer rings on Landsat imagery, distant occurrences of "Sudbury breccia" (generally defined as pseudotachylite), shatter cone occurrences, and outliers of Huronian sedimentary rock thought to be down-faulted rings. New data from imaging radar and field work north of the SIC, however, contradict this evidence. Radar imagery shows no signs of the supposed outer rings mapped by earlier workers on Landsat images. The most prominent ring has been found to be a chance alignment of two independent fracture sets. Radar imagery from the CCRS Convair 580, with look direction almost normal to the north rim of the SIC, shows no evidence of the rings despite strong look azimuth highlighting. Radar imagery has shown many unmapped diabase dikes north of the SIC. Several exposures of supposed Sudbury breccia are associated with these dikes or with Nipissing diabase intrusions, in some cases actually inside the dikes or directly continuous with them. They appear to be igneous intrusion breccias with no relation to impact. Shock-wave interaction at lithologic contacts cannot be invoked for most of these, because they are part of a northwest trending swarm cutting the SIC in the North Range, and hence too young for an impact origin. Similar diabase-related breccias and pseudotachylite-like veins have been found far outside the Sudbury area between Chapleau and Thessalon. Shatter cones north of the SIC are few and poorly developed, perhaps due to the coarse-grained Footwall rock, and cannot be considered a continuous zone analogous to their

  3. Origin of weak layer contraction in de Vries smectic liquid crystals

    NASA Astrophysics Data System (ADS)

    Agra-Kooijman, Dena M.; Yoon, HyungGuen; Dey, Sonal; Kumar, Satyendra

    2014-03-01

    Structural investigations of the de Vries smectic-A (SmA) and smectic-C (SmC) phases of four mesogens containing a trisiloxane end segment reveal a linear molecular conformation in the SmA phase and a bent conformation resembling a hockey stick in the SmC phase. The siloxane and the hydrocarbon parts of the molecule tilt at different angles relative to the smectic layer normal and are oriented along different directions. For the compounds investigated, the shape of orientational distribution function (ODF) is found to be sugarloaf shaped and not the widely expected volcano like with positive orientational order parameters: ⟨P2⟩ = 0.53-0.78, ⟨P4⟩ = 0.14-0.45, and ⟨P6⟩˜0.10. The increase in the effective molecular length, and consequently in the smectic layer spacing caused by reduced fluctuations and the corresponding narrowing of the ODF, counteracts the effect of molecular tilt and significantly reduces the SmC layer contraction. Maximum tilt of the hydrocarbon part of the molecule lies between approximately 18° and 25° and between 6° and 12° for the siloxane part. The critical exponent of the tilt order parameter, β˜0.25, is in agreement with tricritical behavior at the SmA-SmC transition for two compounds and has lower value for first-order transition in the other compounds with finite enthalpy of transition.

  4. Turbulence structures in a strongly decelerated boundary layer

    NASA Astrophysics Data System (ADS)

    Gungor, Ayse G.; Maciel, Yvan; Simens, Mark P.

    2014-11-01

    The characteristics of three-dimensional intense Reynolds shear stress structures (Qs) are presented from a direct numerical simulation of an adverse pressure gradient boundary layer at Reθ = 1500 -2175. The intense Q2 (ejections) and Q4 (sweeps) structures separate into two groups: wall-attached and wall-detached structures. In the region where turbulent activity is maximal, between 0 . 2 δ and 0 . 6 δ , 94 % of the structures are detached structures. In comparison to canonical wall flows, the large velocity defect turbulent boundary layers are less efficient in extracting turbulent energy from the mean flow. There is, furthermore, much less turbulence activity and less velocity coherence near the wall. Additionally, the wall-detached structures are more frequent and carry a much larger amount of Reynolds shear stress. Funded in part by ITU, NSERC of Canada, and Multiflow program of the ERC.

  5. Guided waves in a multi-layered optical structure

    NASA Astrophysics Data System (ADS)

    Torres, Pedro J.

    2006-09-01

    Motivated by the study of the propagation of electromagnetic waves through a multi-layered optical medium, we prove the existence of two different kinds of homoclinic solutions to the origin in a Schrödinger equation with a nonlinear term. We use a Krasnoselskii fixed point theorem together with a compactness criterion due to Zima. The main results are illustrated with concrete examples of practical interest such as self-focusing nonlinearities of Kerr and non-Kerr type.

  6. Structure of Non-Equilibrium Adsorbed Polymer Layers

    NASA Astrophysics Data System (ADS)

    O'Shaughnessy, Ben; Vavylonis, Dimitrios

    2004-03-01

    Equilibrium polymer adsorption has been widely studied theoretically. Many experiments however implicate strong non-equilibrium effects for monomer sticking energies somewhat larger than kT, the most common case. The structure and slow dynamics in these layers is not understood. We analyze theoretically non-equilibrium layers from dilute solutions in the limit of irreversible monomer adsorption. We find the density profile ˜ z-4/3 and loop distribution ˜ s-11/5 of the resulting layer are no different to equilibrium. However, single chain statistics are radically different: the layer consists of a flat inner portion of fully collapsed chains plus an outer part whose chains make only fN surface contacts where N is chain length. The contact fractions f follow a broad distribution, P(f) ˜ f-4/5, consistent with experiment [H. M. Schneider et al, Langmuir 12, 994 (1996)], and the lateral size R of adsorbed chains is of order the bulk coil size, R ˜ N^3/5. For equilibrium layers, by contrast, P has a unique peak at a value of f of order unity, while R ˜ N^1/2 is significantly less. The relaxation of a non-equilibrium layer towards equilibrium thus entails chain shrinkage and tighter binding. We speculate that the observed decrease of bulk-layer chain exchange rates with increasing aging reflects these internal layer dynamics.

  7. 3D outflow jets originating from turbulence in the reconnection current layer

    NASA Astrophysics Data System (ADS)

    Fujimoto, Keizo

    2016-07-01

    Satellite observations in the Earth's magnetosphere and in solar flares have suggested that the reconnection outflow jets are fully three dimensional, consisting of a series of narrow channels. The jet structure is important in evaluating the energy and flux transport in the reconnection process. Previous theoretical models based on fluid simulations have relied on patchy reconnection where reconnection takes place predominantly in patchy portions of the current layer. The problem of the previous models is that the gross reconnection rate is much smaller than that in the 2D reconnection case. The present study shows a large-scale 3D PIC simulation revealing that the 3D outflow jets are generated through the 3D flux ropes formed in the turbulent electron current layer around the x-line. Reconnection proceeds almost uniformly along the x-line, so that the gross reconnection rate is comparable to that in the 2D reconnection case. The flux ropes and resultant outflow channels have a typical current-aligned scale provided by the wavelength of an electron shear mode that is much larger than the typical kinetic scales. It is found that the structure of the 3D outflow jets obtained in the simulation is consistent with the bursty bulk flow observed in the Earth's magnetotail.

  8. Lactobacillus helveticus MIMLh5-specific antibodies for detection of S-layer protein in Grana Padano protected-designation-of-origin cheese.

    PubMed

    Stuknyte, Milda; Brockmann, Eeva-Christine; Huovinen, Tuomas; Guglielmetti, Simone; Mora, Diego; Taverniti, Valentina; Arioli, Stefania; De Noni, Ivano; Lamminmäki, Urpo

    2014-01-01

    Single-chain variable-fragment antibodies (scFvs) have considerable potential in immunological detection and localization of bacterial surface structures. In this study, synthetic phage-displayed antibody libraries were used to select scFvs against immunologically active S-layer protein of Lactobacillus helveticus MIMLh5. After three rounds of panning, five relevant phage clones were obtained, of which four were specific for the S-layer protein of L. helveticus MIMLh5 and one was also capable of binding to the S-layer protein of L. helveticus ATCC 15009. All five anti-S-layer scFvs were expressed in Escherichia coli XL1-Blue, and their specificity profiles were characterized by Western blotting. The anti-S-layer scFv PolyH4, with the highest specificity for the S-layer protein of L. helveticus MIMLh5, was used to detect the S-layer protein in Grana Padano protected-designation-of-origin (PDO) cheese extracts by Western blotting. These results showed promising applications of this monoclonal antibody for the detection of immunomodulatory S-layer protein in dairy (and dairy-based) foods. PMID:24242242

  9. Enhanced columnar structure in CsI layer by substrate patterning

    SciTech Connect

    Jing, T.; Cho, G.; Drewery, J.; Kaplan, S.N.; Mireshghi, A.; Perez-Mendez, V.; Wildermuth, D.; Fujieda, I.

    1991-10-01

    Columnar structure in evaporated CsI layers can be controlled by patterning substrates as well as varying evaporation conditions. Mesh-patterned substrates with various dimensions were created by spin-coating polyimide on glass or amorphous silicon substrates and defining patterns with standard photolithography technique. CsI(Tl) layers 200--1000 {mu}m were evaporated. Scintillation properties of these evaporated layers, such as light yield and speed, were equivalent to those of the source materials. Spatial resolution of X-ray detectors consisting of these layers and a linear array of X-ray detectors consisting of these layers and a linear array of Si photodiodes was evaluated by exposing them to a 25{mu}m narrow beam of X-ray. The results obtained with 200{mu}m thick CsI layers coupled to a linear photodiode array with 20 dots/mm resolution showed that the spatial resolution of CsI(Tl) evaporated on patterned substrates was about 75 {mu}m FWHM, whereas that on CsI(Tl) on flat substrates was about 230 {mu}m FWHM. Micrographs taken by SEM revealed that these layers retained the well-defined columnar structure originating from substrate patterns. Adhesion and light transmission of CsI(Tl) were also improved by patterning the substrate.

  10. Local layer structures in circular domains of an achiral bent-core mesogen observed by x-ray microbeam diffraction

    NASA Astrophysics Data System (ADS)

    Takanishi, Yoichi; Ogasawara, Toyokazu; Ishikawa, Ken; Takezoe, Hideo; Watanabe, Junji; Takahashi, Yumiko; Iida, Atsuo

    2003-07-01

    The local layer structures have been investigated by x-ray microbeam diffraction in the circular domains of the SmCP phase of a banana-shaped molecule. Originally, the molecules form tilted layers with a certain tilt angle as well as nontilted ones. The application of a low electric field induces a tilted layer with a continuous change of the tilt angle; i.e., the tilted layer gradually changes the tilt angle, finally being upright at the center of circular domains. Upon application of a high electric field, the smectic layer forms a cylindrical-type structure. The layer structure changes from cylindrical to onionlike after turning off the high field.

  11. Structural origin of slow diffusion in protein folding.

    PubMed

    Chung, Hoi Sung; Piana-Agostinetti, Stefano; Shaw, David E; Eaton, William A

    2015-09-25

    Experimental, theoretical, and computational studies of small proteins suggest that interresidue contacts not present in the folded structure play little or no role in the self-assembly mechanism. Non-native contacts can, however, influence folding kinetics by introducing additional local minima that slow diffusion over the global free-energy barrier between folded and unfolded states. Here, we combine single-molecule fluorescence with all-atom molecular dynamics simulations to discover the structural origin for the slow diffusion that markedly decreases the folding rate for a designed α-helical protein. Our experimental determination of transition path times and our analysis of the simulations point to non-native salt bridges between helices as the source, which provides a quantitative glimpse of how specific intramolecular interactions influence protein folding rates by altering dynamics and not activation free energies. PMID:26404828

  12. Coherent X-ray radiation by relativistic electron in a structure “amorphous layer-vacuum-periodic layered medium”

    NASA Astrophysics Data System (ADS)

    Blazhevich, S. V.; Gladkikh, J. P.; Nemtsev, S. N.; Zagorodnyuk, R. A.; Noskov, A. V.

    2016-07-01

    The dynamic theory of coherent X-ray radiation by relativistic electron crossing a three-layer structure consisting of an amorphous substance layer, a layer of vacuum and a layer with artificial periodic structure has been developed. The process of radiation and propagation of X-ray waves in an artificial periodic structure have been considered based on two-wave approximation of dynamic diffraction theory in Laue scattering geometry.

  13. Proposal of interband tunneling structures with strained layers

    NASA Astrophysics Data System (ADS)

    Ru, Guoping; Li, Aizhen

    1994-09-01

    A type of interband tunneling structure with strained layers is proposed. In(x)Ga(1 - x)Sb/In(x)Al(1 - x)Sb/InAs/In(x)Al(1 - x)Sb/In(x)Ga(1 - x)Sb strained resonant interband tunneling structures are theoretically studied by calculating current-voltage characteristics using realistic band structure and making comparisons to analogous unstrained structures. The results show that the interband tunneling windows of strained structures can be expanded by the introduction of strain in the InAs quantum-well layer. With a wider interband tunneling window, the peak current density is enhanced due to the broader tunneling transmission spectrum and higher bias required for resonant interband tunneling. The peak current density is also examined as a function of InAs well width for different InAlSb barrier widths.

  14. Evolutionary geometry of Lagrangian structures in a transitional boundary layer

    NASA Astrophysics Data System (ADS)

    Zheng, Wenjie; Yang, Yue; Chen, Shiyi

    2016-03-01

    We report a geometric study of Lagrangian structures in a weakly compressible, spatially evolving transitional boundary layer at the Mach number 0.7. The Lagrangian structures in the transition process are extracted from the Lagrangian scalar field by a sliding window filter at a sequence of reference times. The multi-scale and multi-directional geometric analysis is applied to characterize the geometry of spatially evolving Lagrangian structures, including the averaged inclination and sweep angles at different scales ranging from one half of the boundary layer thickness to several viscous length scales. Here, the inclination angle is on the plane of the streamwise and wall-normal directions, and the sweep angle is on the plane of the streamwise and spanwise directions. In general, the averaged inclination angle is increased and the sweep angle is decreased with the reference time. The variation of the angles for large-scale structures is smaller than that for small-scale structures. Before the transition, the averaged inclination and sweep angles are only slightly altered for all the scales. As the transition occurs, averaged inclination angles increase and sweep angles decrease rapidly for small-scale structures. In the late transitional stage, the averaged inclination angle of small-scale structures with 30 viscous length scales is approximately 42°, and the averaged sweep angle in the logarithm law region is approximately 30°. Additionally, the geometry of Lagrangian structures in transitional boundary layer flow is compared with that in the fully developed turbulent channel flow.

  15. TEMPERATURE STRUCTURE OF PROTOPLANETARY DISKS UNDERGOING LAYERED ACCRETION

    SciTech Connect

    Lesniak, M. V.; Desch, S. J.

    2011-10-20

    We calculate the temperature structures of protoplanetary disks (PPDs) around T Tauri stars heated by both incident starlight and viscous dissipation. We present a new algorithm for calculating the temperatures in disks in hydrostatic and radiative equilibrium, based on Rybicki's method for iteratively calculating the vertical temperature structure within an annulus. At each iteration, the method solves for the temperature at all locations simultaneously, and converges rapidly even at high (>>10{sup 4}) optical depth. The method retains the full frequency dependence of the radiation field. We use this algorithm to study for the first time disks evolving via the magnetorotational instability. Because PPD midplanes are weakly ionized, this instability operates preferentially in their surface layers, and disks will undergo layered accretion. We find that the midplane temperatures T{sub mid} are strongly affected by the column density {Sigma}{sub a} of the active layers, even for fixed mass accretion rate M-dot . Models assuming uniform accretion predict midplane temperatures in the terrestrial planet forming region several x 10{sup 2} K higher than our layered accretion models do. For M-dot < 10{sup -7} M{sub sun} yr{sup -1} and the column densities {Sigma}{sub a} < 10 g cm{sup -2} associated with layered accretion, disk temperatures are indistinguishable from those of a passively heated disk. We find emergent spectra are insensitive to {Sigma}{sub a}, making it difficult to observationally identify disks undergoing layered versus uniform accretion.

  16. Structural templating of multiple polycrystalline layers in organic photovoltaic cells

    SciTech Connect

    Lassiter, Brian E; Lunt, Richard R; Renshaw, Kyle; Forrest, Stephen R.

    2010-09-01

    We demonstrate that organic photovoltaic cell performance is influenced by changes in the crystalline orientation of composite layer structures. A 1.5 nm thick self-organized, polycrystalline template layer of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) orients subsequently deposited layers of a diindenoperylene exciton blocking layer, and the donor, copper phthalocyanine (CuPc). Control over the crystalline orientation of the CuPc leads to changes in its frontier energy levels, absorption coefficient, and surface morphology, resulting in an increase of power conversion efficiency at 1 sun from 1.42 ± 0.04% to 2.19 ± 0.05% for a planar heterojunction and from 1.89 ± 0.05% to 2.49 ± 0.03% for a planar-mixed heterojunction.

  17. Structural templating of multiple polycrystalline layers in organic photovoltaic cells.

    PubMed

    Lassiter, Brian E; Lunt, Richard R; Renshaw, C Kyle; Forrest, Stephen R

    2010-09-13

    We demonstrate that organic photovoltaic cell performance is influenced by changes in the crystalline orientation of composite layer structures. A 1.5 nm thick self-organized, polycrystalline template layer of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) orients subsequently deposited layers of a diindenoperylene exciton blocking layer, and the donor, copper phthalocyanine (CuPc). Control over the crystalline orientation of the CuPc leads to changes in its frontier energy levels, absorption coefficient, and surface morphology, resulting in an increase of power conversion efficiency at 1 sun from 1.42 ± 0.04% to 2.19 ± 0.05% for a planar heterojunction and from 1.89 ± 0.05% to 2.49 ± 0.03% for a planar-mixed heterojunction. PMID:21165074

  18. The structure and evolution of boundary layers in stratified convection

    NASA Astrophysics Data System (ADS)

    Anders, Evan H.; Brown, Benjamin; Brandenburg, Axel; Rast, Mark

    2016-05-01

    Solar convection is highly stratified, and the density in the Sun increases by many orders of magnitude from the photosphere to the base of the convection zone. The photosphere is an important boundary layer, and interactions between the surface convection and deep convection may lie at the root of the solar convection conundrum, where observed large-scale velocities are much lower than predicted by full numerical simulations. Here, we study the structure and time evolution of boundary layers in numerical stratified convection. We study fully compressible convection within plane-parallel layers using the Dedalus pseudospectral framework. Within the context of polytropic stratification, we study flows from low (1e-3) to moderately high (0.1) Mach number, and at moderate to high Rayleigh number to study both laminar and turbulent convective transport. We aim to characterize the thickness and time variation of velocity and thermal (entropy) boundary layers at the top and bottom boundaries of the domain.

  19. Novel layer-by-layer structured nanofibrous mats coated by protein films for dermal regeneration.

    PubMed

    Xin, Shangjing; Li, Xueyong; Wang, Qun; Huang, Rong; Xu, Xiaoli; Lei, Zhanjun; Deng, Hongbing

    2014-05-01

    Layer-by-layer coating technique is effective in modifying the surface of nanofibrous mats, but overmuch film-coating makes the mats less porous to hardly suit the condition for tissue engineering. We developed novel nanofibrous mats layer-by-layer coated by silk fibroin and lysozyme on the cellulose electrospun template via electrostatic interaction. The film-coating assembled on the mats was not excessive because the charge of the proteins varied in the coating process due to different pH value. In addition, pure nature materials made the mats nontoxic, biodegradable and low-cost. The morphology and composition variation during layer-by-layer coating process was investigated and the results showed that the structure and thickness of film-coatings could be well-controlled. The antibacterial assay and in vitro cell experiments indicated that the mats could actively inhibit bacteria and exhibit excellent biocompatibility. In vivo implant assay further verified the mats cultured with human epidermal cells could promote wound healing and avoid wound infection. Therefore, these mats showed promising prospects when performed for dermal reconstruction. PMID:24734533

  20. Origin of weak layer contraction in de Vries smectic liquid crystals.

    PubMed

    Agra-Kooijman, Dena M; Yoon, HyungGuen; Dey, Sonal; Kumar, Satyendra

    2014-03-01

    Structural investigations of the de Vries smectic-A (SmA) and smectic-C (SmC) phases of four mesogens containing a trisiloxane end segment reveal a linear molecular conformation in the SmA phase and a bent conformation resembling a hockey stick in the SmC phase. The siloxane and the hydrocarbon parts of the molecule tilt at different angles relative to the smectic layer normal and are oriented along different directions. For the compounds investigated, the shape of orientational distribution function (ODF) is found to be sugarloaf shaped and not the widely expected volcano like with positive orientational order parameters: ⟨P2⟩ = 0.53-0.78, ⟨P4⟩ = 0.14-0.45, and ⟨P6⟩∼0.10. The increase in the effective molecular length, and consequently in the smectic layer spacing caused by reduced fluctuations and the corresponding narrowing of the ODF, counteracts the effect of molecular tilt and significantly reduces the SmC layer contraction. Maximum tilt of the hydrocarbon part of the molecule lies between approximately 18° and 25° and between 6° and 12° for the siloxane part. The critical exponent of the tilt order parameter, β∼0.25, is in agreement with tricritical behavior at the SmA-SmC transition for two compounds and has lower value for first-order transition in the other compounds with finite enthalpy of transition. PMID:24730863

  1. Deep structure and origin of active volcanoes in China

    NASA Astrophysics Data System (ADS)

    Zhao, D.

    2010-12-01

    Recent geophysical studies have provided important constraints on the deep structure and origin of the active intraplate volcanoes in Mainland China. Magmatism in the western Pacific arc and back-arc areas is caused by the corner flow in the mantle wedge and dehydration of the subducting slab (e.g., Zhao et al., 2009a), while the intraplate magmatism in China has different origins. The active volcanoes in Northeast China (such as the Changbai and Wudalianchi) are caused by hot upwelling in the big mantle wedge (BMW) above the stagnant slab in the mantle transition zone and deep slab dehydration as well (Zhao et al., 2009b). The Tengchong volcano in Southwest China is caused by a similar process in the BMW above the subducting Burma microplate (or Indian plate) (Lei et al., 2009a). The Hainan volcano in southernmost China is a hotspot fed by a lower-mantle plume which may be associated with the Pacific and Philippine Sea slabs' deep subduction in the east and Indian slab's deep subduction in the west down to the lower mantle (Lei et al., 2009b; Zhao, 2009). The stagnant slab finally collapses down to the bottom of the mantle, which can trigger the upwelling of hot mantle materials from the lower mantle to the shallow mantle beneath the subducting slabs and may cause the slab-plume interactions (Zhao, 2009). References Lei, J., D. Zhao, Y. Su, 2009a. Insight into the origin of the Tengchong intraplate volcano and seismotectonics in southwest China from local and teleseismic data. J. Geophys. Res. 114, B05302. Lei, J., D. Zhao, B. Steinberger et al., 2009b. New seismic constraints on the upper mantle structure of the Hainan plume. Phys. Earth Planet. Inter. 173, 33-50. Zhao, D., 2009. Multiscale seismic tomography and mantle dynamics. Gondwana Res. 15, 297-323. Zhao, D., Z. Wang, N. Umino, A. Hasegawa, 2009a. Mapping the mantle wedge and interplate thrust zone of the northeast Japan arc. Tectonophysics 467, 89-106. Zhao, D., Y. Tian, J. Lei, L. Liu, 2009b. Seismic

  2. Ternary metal-rich sulfide with a layered structure

    DOEpatents

    Franzen, Hugo F.; Yao, Xiaoqiang

    1993-08-17

    A ternary Nb-Ta-S compound is provided having the atomic formula, Nb.sub.1.72 Ta.sub.3.28 S.sub.2, and exhibiting a layered structure in the sequence S-M3-M2-M1-M2-M3-S wherein S represents sulfur layers and M1, M2, and M3 represent Nb/Ta mixed metal layers. This sequence generates seven sheets stacked along the [001] direction of an approximate body centered cubic crystal structure with relatively weak sulfur-to-sulfur van der Waals type interactions between adjacent sulfur sheets and metal-to-metal bonding within and between adjacent mixed metal sheets.

  3. Strained layer superlattice focal plane array having a planar structure

    DOEpatents

    Kim, Jin K; Carroll, Malcolm S; Gin, Aaron; Marsh, Phillip F; Young, Erik W; Cich, Michael J

    2012-10-23

    An infrared focal plane array (FPA) is disclosed which utilizes a strained-layer superlattice (SLS) formed of alternating layers of InAs and In.sub.xGa.sub.1-xSb with 0.ltoreq.x.ltoreq.0.5 epitaxially grown on a GaSb substrate. The FPA avoids the use of a mesa structure to isolate each photodetector element and instead uses impurity-doped regions formed in or about each photodetector for electrical isolation. This results in a substantially-planar structure in which the SLS is unbroken across the entire width of a 2-D array of the photodetector elements which are capped with an epitaxially-grown passivation layer to reduce or eliminate surface recombination. The FPA has applications for use in the wavelength range of 3-25 .mu.m.

  4. Internal structure of the Martian south polar layered deposits

    NASA Astrophysics Data System (ADS)

    Byrne, S.; Ivanov, A. B.

    2004-11-01

    We investigate the three-dimensional (3-D) stratigraphic structure of the south polar layered deposits (SPLD) on Mars. Prominent bench-forming layers exposed on SPLD scarps were observed and mapped in three dimensions using high-resolution topographic and imaging data sets. Using the 3-D location of exposures of one of these strata, we can accurately describe the shape of that layer using simple mathematical functions. Analysis of these functions and the surface topography can be used to reliably predict where on other scarps this layer is exposed. In general this bench-forming layer (and its surrounding strata) is not flat and is well approximated as a parabolic dome near the center of the SPLD. Its curvature indicates that when deposited it was draped over a topographic dome similar in size to that of the present day. The scarps in which this layer is exposed must have formed subsequently and have not been significantly modified by flow processes. The basement topography exercises some control over the shape of the interior strata in extreme cases. Our successful layer-fitting technique illustrates the regional uniformity in layer formation and the lack of major internal defects (such as faulting) within the SPLD. We have mapped exposures of what appear to be this layer in scarps farther from the center of the deposits. The position of these exposures can be used to modify the modeled parabolic shape at the periphery of the SPLD. These peripheral elevations provide constraints on the role of flow in the overall shaping of the SPLD.

  5. Morphological transitions of elastic domain structures in constrained layers

    NASA Astrophysics Data System (ADS)

    Slutsker, J.; Artemev, A.; Roytburd, A. L.

    2002-06-01

    The phase transformation in a constrained layer is the subject of this article. The formation and evolution of polydomain microstructure under external stress in the constrained layer are investigated by phase-field simulation and analytically using homogeneous approximation. As a result of simulation, it has been shown that the three-domain hierarchical structure can be formed in the epitaxial films. Under external stress there are two types of morphological transitions: from the three-domain structure to the two-domain one and from the hierarchical three-domain structure to the cellular three-domain structure. The results of phase-field simulation are compared with conclusions of homogenous theory and with available experimental data.

  6. Coherent structures in compressible free-shear-layer flows

    SciTech Connect

    Aeschliman, D.P.; Baty, R.S.; Kennedy, C.A.; Chen, J.H.

    1997-08-01

    Large scale coherent structures are intrinsic fluid mechanical characteristics of all free-shear flows, from incompressible to compressible, and laminar to fully turbulent. These quasi-periodic fluid structures, eddies of size comparable to the thickness of the shear layer, dominate the mixing process at the free-shear interface. As a result, large scale coherent structures greatly influence the operation and efficiency of many important commercial and defense technologies. Large scale coherent structures have been studied here in a research program that combines a synergistic blend of experiment, direct numerical simulation, and analysis. This report summarizes the work completed for this Sandia Laboratory-Directed Research and Development (LDRD) project.

  7. Nature, Origin, Potential Composition, and Climate Impact of the Asian Tropopause Aerosol Layer (ATAL)

    NASA Technical Reports Server (NTRS)

    Fairlie, T. D.; Vernier, J.-P.; Thomason, L. W.; Natarajan, M.; Bedka, K.; Wienhold, F.; Bian J.; Martinsson, B.

    2015-01-01

    Satellite observations from SAGE II and CALIPSO indicate that summertime aerosol extinction has more than doubled in the Asian Tropopause Aerosol Layer (ATAL) since the late 1990s. Here we show remote and in-situ observations, together with results from a chemical transport model (CTM), to explore the likely composition, origin, and radiative forcing of the ATAL. We show in-situ balloon measurements of aerosol backscatter, which support the high levels observed by CALIPSO since 2006. We also show in situ measurements from aircraft, which indicate a predominant carbonaceous contribution to the ATAL (Carbon/Sulfur ratios of 2- 10), which is supported by the CTM results. We show that the peak in ATAL aerosol lags by 1 month the peak in CO from MLS, associated with deep convection over Asia during the summer monsoon. This suggests that secondary formation and growth of aerosols in the upper troposphere on monthly timescales make a significant contribution to ATAL. Back trajectory calculations initialized from CALIPSO observations provide evidence that deep convection over India is a significant source for ATAL through the vertical transport of pollution to the upper troposphere.

  8. High {Tc} trilayer tunneling and Josephson junction structures made using atomic layer by layer growth

    SciTech Connect

    Eckstein, J.N.; Bozovic, I.; Virshup, G.F.

    1994-12-31

    Very precise artificial structuring of high {Tc} heterostructures is possible using atomic layer-by-layer molecular beam epitaxy (ALL-MBE). Cuprates are combined with other oxides, such as titanates, to make atomically precise heterostructures for studying transport and interfacial effects. Titanate slabs as thin as one unit cell thick can be grown without pinholes and provide tunneling barriers for c-axis transport. Single doped unit cells of BSCCO-2212 can also be used as barriers. These give SNS Josephson junctions at temperatures as high as 65 K. Since the crystallographic structure of the barrier is identical to the structure of the 2212 electrode material, it is easily possible to stack more than junction in close proximity. This results in phase-locked operation of two junctions together.

  9. Atomistic origin of an ordered superstructure induced superconductivity in layered chalcogenides

    NASA Astrophysics Data System (ADS)

    Ang, R.; Wang, Z. C.; Chen, C. L.; Tang, J.; Liu, N.; Liu, Y.; Lu, W. J.; Sun, Y. P.; Mori, T.; Ikuhara, Y.

    2015-01-01

    Interplay among various collective electronic states such as charge density wave and superconductivity is of tremendous significance in low-dimensional electron systems. However, the atomistic and physical nature of the electronic structures underlying the interplay of exotic states, which is critical to clarifying its effect on remarkable properties of the electron systems, remains elusive, limiting our understanding of the superconducting mechanism. Here, we show evidence that an ordering of selenium and sulphur atoms surrounding tantalum within star-of-David clusters can boost superconductivity in a layered chalcogenide 1T-TaS2-xSex, which undergoes a superconducting transition in the nearly commensurate charge density wave phase. Advanced electron microscopy investigations reveal that such an ordered superstructure forms only in the x area, where the superconductivity manifests, and is destructible to the occurrence of the Mott metal-insulator transition. The present findings provide a novel dimension in understanding the relationship between lattice and electronic degrees of freedom.

  10. Interfacial Atomic Structure of Twisted Few-Layer Graphene

    PubMed Central

    Ishikawa, Ryo; Lugg, Nathan R.; Inoue, Kazutoshi; Sawada, Hidetaka; Taniguchi, Takashi; Shibata, Naoya; Ikuhara, Yuichi

    2016-01-01

    A twist in bi- or few-layer graphene breaks the local symmetry, introducing a number of intriguing physical properties such as opening new bandgaps. Therefore, determining the twisted atomic structure is critical to understanding and controlling the functional properties of graphene. Combining low-angle annular dark-field electron microscopy with image simulations, we directly determine the atomic structure of twisted few-layer graphene in terms of a moiré superstructure which is parameterized by a single twist angle and lattice constant. This method is shown to be a powerful tool for accurately determining the atomic structure of two-dimensional materials such as graphene, even in the presence of experimental errors. Using coincidence-site-lattice and displacement-shift-complete theories, we show that the in-plane translation state between layers is not a significant structure parameter, explaining why the present method is adequate not only for bilayer graphene but also a few-layered twisted graphene. PMID:26888259

  11. Layered structures and nanosheets of pyrimidinethiolate coordination polymers.

    PubMed

    Beldon, P J; Tominaka, S; Singh, P; Saha Dasgupta, T; Bithell, E G; Cheetham, A K

    2014-04-18

    We report the synthesis, crystal structure and exfoliation of a new member of an important family of layered compounds: lamellar pyrimidinethiolate coordination polymers. Conductivity measurements and DFT calculations of iron(II) pyrimidine-2-thiolate show that this material and a related compound are insulators. PMID:24599380

  12. Using Layer-Cake Geology to Illustrate Structural Topographic Relationships.

    ERIC Educational Resources Information Center

    Wagner, John Robert

    1987-01-01

    Discusses some of the difficulties of visualizing underlying geologic structural patterns by using maps or wooden blocks. Suggests the use of a modified layer cake to show dipping beds, folds, faults and differential erosion, as well as the relationships of stream valleys to outcrop patterns. (TW)

  13. Interfacial Atomic Structure of Twisted Few-Layer Graphene.

    PubMed

    Ishikawa, Ryo; Lugg, Nathan R; Inoue, Kazutoshi; Sawada, Hidetaka; Taniguchi, Takashi; Shibata, Naoya; Ikuhara, Yuichi

    2016-01-01

    A twist in bi- or few-layer graphene breaks the local symmetry, introducing a number of intriguing physical properties such as opening new bandgaps. Therefore, determining the twisted atomic structure is critical to understanding and controlling the functional properties of graphene. Combining low-angle annular dark-field electron microscopy with image simulations, we directly determine the atomic structure of twisted few-layer graphene in terms of a moiré superstructure which is parameterized by a single twist angle and lattice constant. This method is shown to be a powerful tool for accurately determining the atomic structure of two-dimensional materials such as graphene, even in the presence of experimental errors. Using coincidence-site-lattice and displacement-shift-complete theories, we show that the in-plane translation state between layers is not a significant structure parameter, explaining why the present method is adequate not only for bilayer graphene but also a few-layered twisted graphene. PMID:26888259

  14. Nonlinear dynamics and collective excitations in layered superconducting structures

    NASA Astrophysics Data System (ADS)

    Zel'Tser, A. S.; Kivshar', Iu. S.; Soboleva, T. K.

    1991-06-01

    Nonlinear excitations in layered superconducting structures representing a system of interacting extended Josephson junctions are investigated theoretically. The possibility of the propagation of dynamic supersolitons, localized vortex lattice density excitations, in such a system is demonstrated. Particular attention is given to soliton excitations of two types: kinks and envelope solitons. The relaxation of dynamic kinks is investigated numerically.

  15. Initial condition effects on large scale structure in numerical simulations of plane mixing layers

    NASA Astrophysics Data System (ADS)

    McMullan, W. A.; Garrett, S. J.

    2016-01-01

    In this paper, Large Eddy Simulations are performed on the spatially developing plane turbulent mixing layer. The simulated mixing layers originate from initially laminar conditions. The focus of this research is on the effect of the nature of the imposed fluctuations on the large-scale spanwise and streamwise structures in the flow. Two simulations are performed; one with low-level three-dimensional inflow fluctuations obtained from pseudo-random numbers, the other with physically correlated fluctuations of the same magnitude obtained from an inflow generation technique. Where white-noise fluctuations provide the inflow disturbances, no spatially stationary streamwise vortex structure is observed, and the large-scale spanwise turbulent vortical structures grow continuously and linearly. These structures are observed to have a three-dimensional internal geometry with branches and dislocations. Where physically correlated provide the inflow disturbances a "streaky" streamwise structure that is spatially stationary is observed, with the large-scale turbulent vortical structures growing with the square-root of time. These large-scale structures are quasi-two-dimensional, on top of which the secondary structure rides. The simulation results are discussed in the context of the varying interpretations of mixing layer growth that have been postulated. Recommendations are made concerning the data required from experiments in order to produce accurate numerical simulation recreations of real flows.

  16. Origins.

    ERIC Educational Resources Information Center

    Online-Offline, 1999

    1999-01-01

    Provides an annotated list of resources dealing with the theme of origins of life, the universe, and traditions. Includes Web sites, videos, books, audio materials, and magazines with appropriate grade levels and/or subject disciplines indicated; professional resources; and learning activities. (LRW)

  17. Terpenoid hydrocarbons in Hula peat: Structure and origins

    NASA Astrophysics Data System (ADS)

    Venkatesan, M. I.; Ruth, E.; Kaplan, I. R.

    1986-06-01

    Tri- and tetracyclic diterpenoid and pentacyclic triterpenoid hydrocarbons have been identified in the lipid extracts of three peat samples from the Hula Basin, Israel. Tentative structures for the diterpenoids have been proposed based on mass spectral studies and on extrapolation of known mass spectral fragmentation patterns of most probable biological precursors. The identification of ent-kaurenes in one peat sample appears to be a unique observation. Kaurenes most likely originated from higher plant resins. The triterpenoids in the three samples consist mainly of 17β-hopanes and hopenes, derived from recent biogenic activity. The preponderance of the 17β(H)-hopanes indicates the geological immaturity of the samples and implies that they have undergone only a mild thermal history.

  18. Turbulent boundary-layer structure of flows over freshwater biofilms

    NASA Astrophysics Data System (ADS)

    Walker, J. M.; Sargison, J. E.; Henderson, A. D.

    2013-12-01

    The structure of the turbulent boundary-layer for flows over freshwater biofilms dominated by the diatom Tabellaria flocculosa was investigated. Biofilms were grown on large test plates under flow conditions in an Australian hydropower canal for periods up to 12 months. Velocity-profile measurements were obtained using LDV in a recirculating water tunnel for biofouled, smooth and artificially sandgrain roughened surfaces over a momentum thickness Reynolds number range of 3,000-8,000. Significant increases in skin friction coefficient of up to 160 % were measured over smooth-wall values. The effective roughnesses of the biofilms, k s, were significantly higher than their physical roughness measured using novel photogrammetry techniques and consisted of the physical roughness and a component due to the vibration of the biofilm mat. The biofilms displayed a k-type roughness function, and a logarithmic relationship was found between the roughness function and roughness Reynolds number based on the maximum peak-to-valley height of the biofilm, R t. The structure of the boundary layer adhered to Townsend's wall-similarity hypothesis even though the scale separation between the effective roughness height and the boundary-layer thickness was small. The biofouled velocity-defect profiles collapsed with smooth and sandgrain profiles in the outer region of the boundary layer. The Reynolds stresses and quadrant analysis also collapsed in the outer region of the boundary layer.

  19. Structure of reconnection boundary layers in incompressible MHD

    SciTech Connect

    Sonnerup, B.U.Oe.; Wang, D.J. )

    1987-08-01

    The incompressible MHD equations with nonvanishing viscosity and resistivity are simplified by use of the boundary layer approximation to describe the flow and magnetic field in the exit flow regions of magnetic field reconnection configurations when the reconnection rate is small. The conditions are derived under which self-similar solutions exist of the resulting boundary layer equations. For the case of zero viscosity and resistivity, the equations describing such self-similar layers are then solved in terms of quadratures, and the resulting flow and field configurations are described. Symmetric solutions, relevant, for example, to reconnection in the geomagnetic tail, as well as asymmetric solutions, relevant to reconnection at the earth's magnetopause, are found to exist. The nature of the external solutions to which the boundary layer solutions should be matched is discussed briefly, but the actual matching, which is to occur at Alfven-wave characteristic curves in the boundary layer solutions, is not carried out. Finally, it is argued that the solutions obtained may also be used to describe the structure of the intense vortex layers observed to occur at magnetic separatrices in computer simulations and in certain analytical models of the reconnection process.

  20. Mixing layers and coherent structures in vegetated aquatic flows

    NASA Astrophysics Data System (ADS)

    Ghisalberti, Marco; Nepf, Heidi M.

    2002-02-01

    To date, flow through submerged aquatic vegetation has largely been viewed as perturbed boundary layer flow, with vegetative drag treated as an extension of bed drag. However, recent studies of terrestrial canopies demonstrate that the flow structure within and just above an unconfined canopy more strongly resembles a mixing layer than a boundary layer. This paper presents laboratory measurements, obtained from a scaled seagrass model, that demonstrate the applicability of the mixing layer analogy to aquatic systems. Specifically, all vertical profiles of mean velocity contained an inflection point, which makes the flow susceptible to Kelvin-Helmholtz instability. This instability leads to the generation of large, coherent vortices within the mixing layer (observed in the model at frequencies between 0.01 and 0.11 Hz), which dominate the vertical transport of momentum through the layer. The downstream advection of these vortices is shown to cause the progressive, coherent waving of aquatic vegetation, known as the monami. When the monami is present, the turbulent vertical transport of momentum is enhanced, with turbulent stresses penetrating an additional 30% of the plant height into the canopy.

  1. In situ processing of silicon carbide layer structures

    SciTech Connect

    Padture, N.P.; Pender, D.C.; Wuttiphan, S.; Lawn, B.R.

    1995-11-01

    A novel route to low-cost processing of silicon carbide (SiC) layer structures is described. The processing involves pressureless liquid-phase cosintering of compacted powder layers of SiC, containing alumina (Al{sub 2}O{sub 3}) and yttria (Y{sub 2}O{sub 3}) sintering additives to yield a yttrium aluminum garnet (YAG) second phase. By adjusting the {beta}:{alpha} SiC phase ratios in the individual starting powders, alternate layers with distinctly different microstructures are produced: (i) homogeneous microstructures, with fine equiaxed SiC grains, designed for high strength; and (ii) heterogeneous microstructures with coarse and elongate SiC grains, designed for high toughness. By virtue of the common SiC and YAG phases, the interlayer interfaces are chemically compatible and strongly bonded. Exploratory Hertzian indentation tests across a bilayer interface confirm the capacity of the tough heterogeneous layer to inhibit potentially dangerous cracks propagating through the homogeneous layer. The potential for application of this novel processing approach to other layer architectures and other ceramic systems is considered.

  2. One-Seeded Fruits in the Core Caryophyllales: Their Origin and Structural Diversity

    PubMed Central

    Sukhorukov, Alexander P.; Mavrodiev, Evgeny V.; Struwig, Madeleen; Nilova, Maya V.; Dzhalilova, Khalima Kh.; Balandin, Sergey A.; Erst, Andrey; Krinitsyna, Anastasiya A.

    2015-01-01

    The core Caryophyllales consist of approximately 30 families (12 000 species) distributed worldwide. Many members evolved one-seeded or conjoined fruits, but their origin and structural diversity have not been investigated. A comparative anatomical investigation of the one-seeded fruits within the core Caryophyllales was conducted. The origin of the one-seeded fruits and the evolutionary reconstructions of some carpological characters were traced using a tree based on rbcl and matK data in order to understand the ancestral characters and their changes. The one-seeded fruit type is inferred to be an ancestral character state in core Caryophyllales, with a subsequent increase in the seed number seen in all major clades. Most representatives of the ‘Earlier Diverging’ clade are distinguished in various carpological traits. The organization of the pericarp is diverse in many groups, although fruits with a dry, many-layered pericarp, consisting of sclerenchyma as outer layers and a thin-walled parenchyma below, with seeds occupying a vertical embryo position, are likely ancestral character states in the core Caryophyllales clade. Several carpological peculiarities in fruit and seed structure were discovered in obligate one-seeded Achatocarpaceae, Chenopodiaceae, Nyctaginaceae, Seguieriaceae and Sarcobataceae. The horizontal embryo evolved in only certain groups of Chenopodiaceae. The bar-thickening of endotegmen cells appears to be an additional character typical of core Caryophyllales. The syncarpy-to-lysicarpy paradigm in Caryophyllaceae needs to be reinterpreted. PMID:25710481

  3. One-seeded fruits in the core Caryophyllales: their origin and structural diversity.

    PubMed

    Sukhorukov, Alexander P; Mavrodiev, Evgeny V; Struwig, Madeleen; Nilova, Maya V; Dzhalilova, Khalima Kh; Balandin, Sergey A; Erst, Andrey; Krinitsyna, Anastasiya A

    2015-01-01

    The core Caryophyllales consist of approximately 30 families (12,000 species) distributed worldwide. Many members evolved one-seeded or conjoined fruits, but their origin and structural diversity have not been investigated. A comparative anatomical investigation of the one-seeded fruits within the core Caryophyllales was conducted. The origin of the one-seeded fruits and the evolutionary reconstructions of some carpological characters were traced using a tree based on rbcl and matK data in order to understand the ancestral characters and their changes. The one-seeded fruit type is inferred to be an ancestral character state in core Caryophyllales, with a subsequent increase in the seed number seen in all major clades. Most representatives of the 'Earlier Diverging' clade are distinguished in various carpological traits. The organization of the pericarp is diverse in many groups, although fruits with a dry, many-layered pericarp, consisting of sclerenchyma as outer layers and a thin-walled parenchyma below, with seeds occupying a vertical embryo position, are likely ancestral character states in the core Caryophyllales clade. Several carpological peculiarities in fruit and seed structure were discovered in obligate one-seeded Achatocarpaceae, Chenopodiaceae, Nyctaginaceae, Seguieriaceae and Sarcobataceae. The horizontal embryo evolved in only certain groups of Chenopodiaceae. The bar-thickening of endotegmen cells appears to be an additional character typical of core Caryophyllales. The syncarpy-to-lysicarpy paradigm in Caryophyllaceae needs to be reinterpreted. PMID:25710481

  4. An experimental study on the preparation of tochilinite-originated intercalation compounds comprised of Fe 1-xS host layers and various kinds of guest layers

    NASA Astrophysics Data System (ADS)

    Peng, Yiya; Xi, Guangcheng; Zhong, Chang; Wang, Linping; Lu, Jun; Sun, Ximeng; Zhu, Lu; Han, Qikun; Chen, Lin; Shi, Lei; Sun, Mei; Li, Qianrong; Yu, Min; Yin, Mingwen

    2009-08-01

    Tochilinite represents a mineral group of ordered mixed-layer structures containing alternating Fe 1-xS layers with mackinawite-like structure and metal hydroxide layers with Mg(OH) 2-like structure. In this article, we report the preparation of a series of tochilinite-originated (or Fe 1-xS-based) intercalation compounds (ICs). According to their preparation procedures, these ICs can be divided into four kinds. The first kind of IC was sodium tochilinite (Na-tochilinite), which was prepared by the hydrothermal reaction of metallic Fe particles with concentrated Na 2S·9H 2O aqueous solutions. The hydroxide layer of the Na-tochilinite was a mixed hydroxide of Na + ions along with a certain amount of Fe 2+ ions. When the hydroxide layer of the Na-tochilinite completely dissolved in aqueous solutions, a Fe-deficient mackinawite-like phase Fe 1-xS was obtained, which was probably an electron-deficient p-type conductor. The second kind of ICs was prepared by 'low-temperature direct intercalation in aqueous solutions, using Na-tochilinite as a parental precursor. When the Na-tochilinite was ultrasonicated in aqueous solutions containing Lewis basic complexing agents (like NH 3, N 2H 4, 2,2'-bipyridine (bipy), and 1,10-phenanthroline (phen)), the Na + ions of the Na-tochilinite were removed and the Lewis basic complexing agents entered the hydroxide layer of the Na-tochilinite and became coordinated with the Fe 2+ ions, and the second kind of ICs was thus produced. The second kind of ICs includes NH 3 IC, N 2H 4 IC, N 2H 4-NH 3 IC, [Fe(bipy) 3] 2+-containing IC and [Fe(phen) 3] 2+-containing IC. The third kind of ICs, which includes NH 3 IC, N 2H 4-NH 3 IC and N 2H 4-LiOH (NaOH) IC, was prepared by the hydrothermal reaction of metallic Fe particles with (NH 4) 2S aqueous solution, S (elemental) + N 2H 4·H 2O aqueous solution, and S + N 2H 4·H 2O + LiOH (NaOH) aqueous solution, respectively. The third kind of ICs has a close relationship with the second kind of ICs both

  5. Design of a three-dimensional photonic crystal nanocavity based on a \\langle 110\\rangle -layered diamond structure

    NASA Astrophysics Data System (ADS)

    Tajiri, Takeyoshi; Takahashi, Shun; Tandaechanurat, Aniwat; Iwamoto, Satoshi; Arakawa, Yasuhiko

    2014-01-01

    We design a three-dimensional (3D) photonic crystal (PC) nanocavity based on a \\langle 110\\rangle -layered diamond structure. The designed structure, comprised of self-sustainable layers, is suitable for fabrication by layer stacking techniques. Quality factors (Q-factors) of nanocavities were calculated for the \\langle 110\\rangle -layered diamond and a commonly-used woodpile structures, both of which are generated from the same diamond lattice with a lattice constant adiamond. The Q-factor of the designed nanocavity can reach as high as 230,000 with 35 stacked layers and a square in-plane PC area of the length of one side of 5\\sqrt{2} a^{\\text{diamond}}. This is 1.5 times higher than that of a 3D PC nanocavity based on the woodpile structure with the same in-plane PC size and with the same number of stacked layers. The higher Q-factor in the \\langle 110\\rangle -layered diamond structure originates from its stronger in-plane light confinement over the woodpile structure. The \\langle 110\\rangle -layered diamond structure will be beneficial for improving experimentally attainable Q-factors of 3D PC nanocavities particularly fabricated by a micromanipulation method.

  6. Seismic Structure and Origin of the Hainan Plume

    NASA Astrophysics Data System (ADS)

    Huang, J.

    2012-12-01

    This study presents P and S wave tomographic image and mantle transition zone structure beneath the Hainan and adjacent areas. The teleseismic events used in this study were recorded by Eighty-eight seismic stations which belong to three regional seismic networks of Hainan, Guangdong , and Guangxi, respectively . We used 165 teleseismic events with magnitudes larger than M 5.4 and manually picked up 10873 P and 9147 S arrivals. Prior to inversion we made the crustal corrections using the crustal model CRUST2.0. We then applied the tomgoraphic method of Zhao et al. (1994) to the corrected relative travel time residuals for determining the three dimensional P and S wave velocity structure down to 700 km beneath the study region. Our results show obvious low-velocity (low-V) anomaly is visible beneath Hainan hotspot and northeast portion, such a pattern extends down to 700 km depth though the amplitude of the velocity anomaly is reduced at the bottom of the model. From surface to mantle transition zone, this low-V anomaly gradually extents toward northeast direction and may represent high temperature or even partial melt materials under Hainan hotspot, its diameter ranges from about 100km in shallow depth to 200km in the mantle transition zone. We also analyze teleseismic waveform by using receive function and obtained the upper mantle discontinuities structure and mantle transition zone thickness beneath the Hainan and adjacent areas. These results revealed a relatively complicated 410, which depress to 447km locally, but a structurally simple 660 beneath the region, with the depth around 670km. The mantle transition zone is thinned anomalously by 25±5km within an area approximately 200km in diameter centered, this anomaly is equivalent to an excess temperature of 180 degrees. The area of mantle transition zone thinning is roughly consistent with scope of low-V zone from seismic tomography in the upper mantle. After a comprehensive analysis results from seismic

  7. Stable single-layer honeycomblike structure of silica.

    PubMed

    Özçelik, V Ongun; Cahangirov, S; Ciraci, S

    2014-06-20

    Silica or SiO(2), the main constituent of Earth's rocks has several 3D complex crystalline and amorphous phases, but it does not have a graphitelike layered structure in 3D. Our theoretical analysis and numerical calculations from the first principles predict a single-layer honeycomblike allotrope, hα silica, which can be viewed to be derived from the oxidation of silicene and it has intriguing atomic structure with reentrant bond angles in hexagons. It is a wide band gap semiconductor, which attains remarkable electromechanical properties showing geometrical changes under an external electric field. In particular, it is an auxetic metamaterial with a negative Poisson's ratio and has a high piezoelectric coefficient. While it can form stable bilayer and multilayer structures, its nanoribbons can show metallic or semiconducting behavior depending on their chirality. Coverage of dangling Si orbitals by foreign adatoms can attribute new functionalities to hα silica. In particular, Si(2)O(5), where Si atoms are saturated by oxygen atoms from top and bottom sides alternatingly can undergo a structural transformation to make silicatene, another stable, single layer structure of silica. PMID:24996101

  8. Stable Single-Layer Honeycomblike Structure of Silica

    NASA Astrophysics Data System (ADS)

    Özçelik, V. Ongun; Cahangirov, S.; Ciraci, S.

    2014-06-01

    Silica or SiO2, the main constituent of Earth's rocks has several 3D complex crystalline and amorphous phases, but it does not have a graphitelike layered structure in 3D. Our theoretical analysis and numerical calculations from the first principles predict a single-layer honeycomblike allotrope, hα silica, which can be viewed to be derived from the oxidation of silicene and it has intriguing atomic structure with reentrant bond angles in hexagons. It is a wide band gap semiconductor, which attains remarkable electromechanical properties showing geometrical changes under an external electric field. In particular, it is an auxetic metamaterial with a negative Poisson's ratio and has a high piezoelectric coefficient. While it can form stable bilayer and multilayer structures, its nanoribbons can show metallic or semiconducting behavior depending on their chirality. Coverage of dangling Si orbitals by foreign adatoms can attribute new functionalities to hα silica. In particular, Si2O5, where Si atoms are saturated by oxygen atoms from top and bottom sides alternatingly can undergo a structural transformation to make silicatene, another stable, single layer structure of silica.

  9. Optimization of SMA layers in composite structures to enhance damping

    NASA Astrophysics Data System (ADS)

    Haghdoust, P.; Cinquemani, S.; Lecis, N.; Bassani, P.

    2016-04-01

    The performance of lightweight structures can be severely affected by vibration. New design concepts leading to lightweight, slender structural components can increase the vulnerability of the components to failure due to excessive vibration. The intelligent approach to address the problem would be the use of materials which are more capable in dissipating the energy due to their high value of loss factor. Among the different materials available to achieve damping, much attention has been attached to the use of shape memory alloys (SMAs) because of their unique microstructure, leading to good damping capacity. This work describes the design and optimization of a hybrid layered composite structure for the passive suppression of flexural vibrations in slender and light structures. Embedding the SMA layers in composite structure allows to combine different properties: the lightness of the base composite (e.g. fiber glass), the mechanical strength of the insert of metallic material and the relevant damping properties of SMA, in the martensitic phase. In particular, we put our attention on embedding the CuZnAl in the form of thin sheet in a layered composite made by glass fiber reinforced epoxy. By appropriately positioning of the SMA sheets so that they are subjected to the maximum curvature, the damping of the hybrid system can be considerably enhanced. Accordingly analytical method for evaluating the energy dissipation of the thin sheets with different shapes and patterns is developed and is followed by a shape optimization based on genetic algorithm. Eventually different configurations of the hybrid beam structure with different patterns of SMA layer are proposed and compared in the term of damping capacity.

  10. Structural characterisation of a layered double hydroxide nanosheet

    NASA Astrophysics Data System (ADS)

    Funnell, Nicholas P.; Wang, Qiang; Connor, Leigh; Tucker, Matthew G.; O'Hare, Dermot; Goodwin, Andrew L.

    2014-06-01

    We report the atomic-scale structure of a Zn2Al-borate layered double hydroxide (LDH) nanosheet, as determined by reverse Monte Carlo (RMC) modelling of X-ray total scattering data. This study involves the extension of the RMC method to enable structural refinement of two-dimensional nanomaterials. The refined LDH models show the intra-layer geometry in this highly-exfoliated phase to be consistent with that observed in crystalline analogues, with the reciprocal-space scattering data suggesting a disordered arrangement of the Zn2+ and Al3+ cations within the nanosheet. The approach we develop is generalisable and so offers a method of characterising the structures of arbitrary nanosheet phases, including systems that support complex forms of disorder within the nanosheets themselves.We report the atomic-scale structure of a Zn2Al-borate layered double hydroxide (LDH) nanosheet, as determined by reverse Monte Carlo (RMC) modelling of X-ray total scattering data. This study involves the extension of the RMC method to enable structural refinement of two-dimensional nanomaterials. The refined LDH models show the intra-layer geometry in this highly-exfoliated phase to be consistent with that observed in crystalline analogues, with the reciprocal-space scattering data suggesting a disordered arrangement of the Zn2+ and Al3+ cations within the nanosheet. The approach we develop is generalisable and so offers a method of characterising the structures of arbitrary nanosheet phases, including systems that support complex forms of disorder within the nanosheets themselves. Electronic supplementary information (ESI) available. See DOI: 10.1039/c4nr01265h

  11. Multi-functional layered structure having structural and radiation shielding attributes

    NASA Technical Reports Server (NTRS)

    Kaul, Raj K. (Inventor); Barghouty, Abdulnasser Fakhri (Inventor); Penn, Benjamin G. (Inventor); Hulcher, Anthony Bruce (Inventor)

    2010-01-01

    A cosmic and solar radiation shielding structure that also has structural attributes is comprised of three layers. The first layer is 30-42 percent by volume of ultra-high molecular weight (UHMW) polyethylene fibers, 18-30 percent by volume of graphite fibers, and a remaining percent by volume of an epoxy resin matrix. The second layer is approximately 68 percent by volume of UHMW polyethylene fibers and a remaining percent by volume of a polyethylene matrix. The third layer is a ceramic material.

  12. Some new aspects of the transient ionization layer of comet Siding Spring origin in the Martian upper atmosphere

    NASA Astrophysics Data System (ADS)

    Mohana Manasa, P.; Jayaraman, Achuthan; Rao Narukull, Venkateswara; Vijaya Bhaskara Rao, Sarangam

    2016-07-01

    On 19 October 2014, comet Siding Spring passed near to the Mars and deposited a large amount of dust on the Martian upper atmosphere. This resulted in the formation of a dense transient ionization layer on Mars at altitudes between 80 and 120 km. Gurnett et al., [2014] reported the detection of this layer with Mars Advanced Radar for Subsurface and Ionospheric Sounding (MARSIS) instrument aboard Mars Express spacecraft. In this study, we re-analyzed the ionograms obtained by this instrument to get further insight on the recurrence of the layer. Data from three orbital passes of MARSIS that took place 5 h, 12 h, and 19 h after peak dust deposition are used in this analysis. We found that the transient ionization layer sustained at least for 19 hours on the nightside and 12 hours on the dayside. While the peak density of the layer on the nightside gradually decreases from orbit-to-orbit, it does not change much on the dayside. Some ionograms in all the three orbits show two transient ionization layers that are separated by several kilometers in apparent altitude. We propose two mechanisms to explain this double layer structure. The first one assumes a horizontal bifurcation of the layer in which specular reflections from the two horizontal parts result in a double layer structure in ionograms. In the second mechanism, we assume specular reflections from ionization bulges (formed in regions of vertical magnetic fields) at altitudes of transient ionization layer give rise to oblique echoes that form the bottom layer of the double layer structure.

  13. Structural origin of resistance drift in amorphous GeTe

    NASA Astrophysics Data System (ADS)

    Zipoli, Federico; Krebs, Daniel; Curioni, Alessandro

    2016-03-01

    We used atomistic simulations to study the origin of the change of resistance over time in the amorphous phase of GeTe, a prototypical phase-change material (PCM). Understanding the cause of resistance drift is one of the biggest challenges to improve multilevel storage technology. For this purpose, we generated amorphous structures via classical molecular-dynamics simulations under conditions as close as possible to the experimental operating ones of such memory devices. Moreover, we used the replica-exchange technique to generate structures comparable with those obtained in the experiment after long annealing that show an increase of resistance. This framework allowed us to overcome the main limitation of previous simulations, based on density-functional theory, that suffered from being computationally too expensive therefore limited to the nanosecond time scale. We found that resistance drift is caused by consumption of Ge atom clusters in which the coordination of at least one Ge atom differs from that of the crystalline phase and by removal of stretched bonds in the amorphous network, leading to a shift of the Fermi level towards the middle of the band gap. These results show that one route to design better memory devices based on current chalcogenide alloys is to reduce the resistance drift by increasing the rigidity of the amorphous network.

  14. The motor origins of human and avian song structure.

    PubMed

    Tierney, Adam T; Russo, Frank A; Patel, Aniruddh D

    2011-09-13

    Human song exhibits great structural diversity, yet certain aspects of melodic shape (how pitch is patterned over time) are widespread. These include a predominance of arch-shaped and descending melodic contours in musical phrases, a tendency for phrase-final notes to be relatively long, and a bias toward small pitch movements between adjacent notes in a melody [Huron D (2006) Sweet Anticipation: Music and the Psychology of Expectation (MIT Press, Cambridge, MA)]. What is the origin of these features? We hypothesize that they stem from motor constraints on song production (i.e., the energetic efficiency of their underlying motor actions) rather than being innately specified. One prediction of this hypothesis is that any animals subject to similar motor constraints on song will exhibit similar melodic shapes, no matter how distantly related those animals are to humans. Conversely, animals who do not share similar motor constraints on song will not exhibit convergent melodic shapes. Birds provide an ideal case for testing these predictions, because their peripheral mechanisms of song production have both notable similarities and differences from human vocal mechanisms [Riede T, Goller F (2010) Brain Lang 115:69-80]. We use these similarities and differences to make specific predictions about shared and distinct features of human and avian song structure and find that these predictions are confirmed by empirical analysis of diverse human and avian song samples. PMID:21876156

  15. Crystallographic structure and superconductive properties of Nb-Ti films with an artificially layered structure

    SciTech Connect

    Sato, N. )

    1990-06-15

    Artificially layered niobium-titanium (Nb-Ti) films with various thickness ratios (3/1--1/3) and periodicities (2--100 A) are made in an argon or in a mixed argon/nitrogen atmosphere by a dc magnetron sputtering method. Films with small periodicities (less than 30 A) have an artificial superlattice structure (ASL) with crystallographic coherence between constituent layers, where Nb and Ti grow epitaxially on the closest planes. The crystallographic structures of films are bcc with the (110) plane parallel to the film for films with the same or a thicker Nb layer than a Ti layer, and hcp with the (001) plane parallel to the film for films with a thinner Nb layer than a Ti layer. Films with large periodicities have an artificial superstructure (ASS) with only periodic stacking of constituent layers. Films deposited in the Ar/N atmosphere also have the artificially layered structures of ASL or ASS. The artificially layered structure is thermally stable at temperatures up to 500 {degree}C. The superconducting properties of the films depend strongly on the periodicity and thickness ratio of Nb and Ti layers. The dependence of the transition temperature on the periodicity and thickness ratio is qualitatively explained by a proximity effect with a three-region model. Films with periodicities less than 20 A, composed of the same or a thicker Nb layer than a Ti layer, show high transition temperatures (above 9.3 K). The highest {ital T}{sub {ital c}} of about 13.6 K is obtained in the film composed of monatomic layers of constituents deposited in an Ar atmosphere including 30 vol % N.

  16. Microemulsions: Structures, surfactant layer properties and wetting transitions

    NASA Astrophysics Data System (ADS)

    Abillon, O.; Lee, L. T.; Langevin, D.; Wong, K.

    1991-03-01

    We review briefly the basic known features of microemulsion structures, emphasizing the importance of the surfactant layer bending elasticity. The results for water-alkane-nonionic-surfactant systems, confirming the close relationship between the maximum characteristic size in the microemulsion and the persistence length of the surfactant layer, are presented. We show that microemulsions are formed when the surfactant layer bending moduli are in a well defined range: if the bending modulus is too large, ordered lamellar phases are obtained, while if it is too small, the surfactant film cannot form, and the medium is a structureless molecular mixture. The evolution between microemulsions and molecular mixtures is continuous; its relationship with the wetting transition between the microemulsion and the two excess phases is discussed.

  17. Bound States in the Continuum in double layer structures

    PubMed Central

    Li, LiangSheng; Yin, Hongcheng

    2016-01-01

    We have theoretically investigated the reflectivity spectrums of single- and double-layer photonic crystal slabs and the dielectric multilayer stack. It is shown that light can be perfectly confined in a single-layer photonic crystal slab at a given incident angle by changing the thickness, permittivity or hole radius of the structure. With a tunable double-layer photonic crystal slab, we demonstrate that the occurrence of tunable bound states in the continuum is dependent on the spacing between two slabs. Moreover, by analytically investigating the Drude lossless multilayer stack model, the spacing dependence of bound states in the continuum is characterized as the phase matching condition that illuminates these states can occur at any nonzero incident angles by adjusting the spacing. PMID:27245435

  18. Bound States in the Continuum in double layer structures.

    PubMed

    Li, LiangSheng; Yin, Hongcheng

    2016-01-01

    We have theoretically investigated the reflectivity spectrums of single- and double-layer photonic crystal slabs and the dielectric multilayer stack. It is shown that light can be perfectly confined in a single-layer photonic crystal slab at a given incident angle by changing the thickness, permittivity or hole radius of the structure. With a tunable double-layer photonic crystal slab, we demonstrate that the occurrence of tunable bound states in the continuum is dependent on the spacing between two slabs. Moreover, by analytically investigating the Drude lossless multilayer stack model, the spacing dependence of bound states in the continuum is characterized as the phase matching condition that illuminates these states can occur at any nonzero incident angles by adjusting the spacing. PMID:27245435

  19. Bound States in the Continuum in double layer structures

    NASA Astrophysics Data System (ADS)

    Li, Liangsheng; Yin, Hongcheng

    2016-06-01

    We have theoretically investigated the reflectivity spectrums of single- and double-layer photonic crystal slabs and the dielectric multilayer stack. It is shown that light can be perfectly confined in a single-layer photonic crystal slab at a given incident angle by changing the thickness, permittivity or hole radius of the structure. With a tunable double-layer photonic crystal slab, we demonstrate that the occurrence of tunable bound states in the continuum is dependent on the spacing between two slabs. Moreover, by analytically investigating the Drude lossless multilayer stack model, the spacing dependence of bound states in the continuum is characterized as the phase matching condition that illuminates these states can occur at any nonzero incident angles by adjusting the spacing.

  20. Dynamiical layering in mantle convection - impact on the viscoisity structure

    NASA Astrophysics Data System (ADS)

    Hansen, Ulrich; Stein, Claudia; Dude, Sabine

    2016-04-01

    Thermal boundary layers play a key role for the dynamics of the Earth's mantle. They mark the transition between the core and the mantle and , at least locally and transient, the transition between the upper- and the lower mantle at a depth of 670 km. There is much evidence that these boundary layers do not resemble the picture of a simple thermal boundary layer, as known from thermal convection at high Rayleigh number. Especially the lower boundary seems to be of complex structure, possible induced by compositionally dense material. Present models of mantle convection, aiming at simulating the complex structure and dynamics of the lower boundary layer require several ad hoc assumptions. Especially the density excess and the mass of compositionally distinct need to be assumed. Both conditions are critical for the dynamics but hardly constrained. The internal boundary at 670 is usually implemented by specifying a density jump through a phase boundary, We have developed models where the internal boundary as well as a thermochemical CMB , displaying topography which result from compositionally distinct piles , develop self consistently without the named ad hoc assumptions. As a starting condition we assume that a chemically stratified mantle, as resulting from fractional crystallization in an early magma ocean , is heated by the hot core. Double diffusive convection in material with strongly temperature dependent viscosity leads then to layering and, in a later state to the formation of a rough lower thermochemical boundary layer. Especially the viscosity profiles, as emerging from this configuration are investigated and compared with recent results from inversion studies.

  1. Layered structures of organic/inorganic hybrid halide perovskites

    NASA Astrophysics Data System (ADS)

    Huan, Tran Doan; Tuoc, Vu Ngoc; Minh, Nguyen Viet

    2016-03-01

    Organic-inorganic hybrid halide perovskites, in which the A cations of an ABX3 perovskite are replaced by organic cations, may be used for photovoltaic and solar thermoelectric applications. In this contribution, we systematically study three lead-free hybrid perovskites, i.e., methylammonium tin iodide CH3NH3SnI3 , ammonium tin iodide NH4SnI3 , and formamidnium tin iodide HC (NH2)2SnI3 by first-principles calculations. We find that in addition to the commonly known motif in which the corner-shared SnI6 octahedra form a three-dimensional network, these materials may also favor a two-dimensional (layered) motif formed by alternating layers of the SnI6 octahedra and the organic cations. These two motifs are nearly equal in free energy and are separated by low barriers. These layered structures features many flat electronic bands near the band edges, making their electronic structures significantly different from those of the structural phases composed of three-dimension networks of SnI6 octahedra. Furthermore, because the electronic structures of HC (NH2)2SnI3 are found to be rather similar to those of CH3NH3SnI3 , formamidnium tin iodide may also be promising for the applications of methylammonium tin iodide.

  2. Polymer layered silicate nanocomposites: Structure, morphology, and properties

    NASA Astrophysics Data System (ADS)

    Nawani, Pranav

    Layered silicates are important fillers for improving various mechanical, flame retardant, and barrier properties of polymers, which can be attributed to their sheet-like morphology. Layered silicates can be modified with organic surfactants to render them compatible with polymer matrices. Organically modified silicates (organoclays) having large surface areas are very cost-efficient non-toxic nanofillers effective at very low loads and are readily available. Upon amalgamation of organoclays with polymer matrix nanocomposites, polymer chains can penetrate in between the silicate layers and result in an intercalated structure where the clay stack remains intact but the interlayer spacing is increased. When penetration becomes more severe, disintegration of clay stacks can occur, resulting in an exfoliated structure. It has often been observed that exfoliation is not complete down to the level of isolated silicate layers; rather, the large clay stacks are broken up into shorter stacks termed 'tactoids' together with a few individual silicate layers, resulting in a kind of mixed intercalated-exfoliated structure. Organoclay particles are mostly intercalated, having a preferred orientation with the clay gallery planes being preferentially parallel to the plane of the pressed film. Preferential orientation of organoclays affects the barrier properties of polymer membranes. Additional fillers like carbon black can induce a change in the orientation of organoclays. The effect of carbon black on the orientation of organoclays was elucidated and a relationship between orientation and permeability of air through such membranes was established. We have also investigated the flammability properties of a series of polymer nanocomposites, containing various Transition Metal Ion (TMI) modified organoclays. The improved fire retardation in nanocomposites with TMI-modified organoclays can be attributed to enhanced carbonaceous char formation during combustion, i.e., charring

  3. Electronic structure origins of the extremely large magnetoresistance in tungsten ditelluride

    NASA Astrophysics Data System (ADS)

    Pletikosic, Ivo; Ali, Mazhar; Cava, Robert; Valla, Tonica

    2015-03-01

    WTe2 is a layered transition metal dichalcogenide showing a structural reduction to one-dimensional tellurium-surrounded tungsten chains. The material exhibits an extremely large positive anisotropic magnetoresistance of a few million percent that increases as the square of the field and shows no saturation up to 60 T. We explored the possible electronic structure origins of the magnetoresistance by means of angle-resolved photoelectron spectroscopy (ARPES) and found electron and hole pockets of equal size along the direction of tungsten chains, forming a highly anisotropic quasi-twodimensional Fermi surface. The perfect carrier compensation at low temperatures has been identified as the primary source of the magnetoresistive effect, and the change of the Fermi surface shape as well as a high-density-of-states band slightly below the Fermi level recognized as the cause of its diminishing at rising temperatures.

  4. Boundary Layer Dynamical Structure During Secondary Eyewall Formation

    NASA Astrophysics Data System (ADS)

    Abarca, S. F.; Montgomery, M. T.; McWilliams, J. C.

    2014-12-01

    Secondary eyewall formation (SEF) is widely recognized as an important research problem in the dynamics of mature tropical cyclones. It has been shown that the development of the wind maxima in SEF occurs within the boundary layer and that it follows a chain of events initiated by a substantial radial expansion of the tangential wind field. In this context, there is not yet a consensus on the phenomenon's essential physics. It has been proposed that the boundary-layer dynamics of a maturing hurricane vortex is an important controlling element in SEF. However, recent literature also argues that hurricane boundary layers and the related coupling with the interior flow can be described through an Ekman-like balance and that shock-like structures are relevant in the swirling boundary layer of the inner core of mature storms. We analyze the radial and vertical structure of the specific forces and accelerations in in the boundary layer in a mature hurricane that includes a canonical eyewall replacement cycle. The case occurred in a mesoscale, convection-permitting numerical simulation of a tropical cyclone, integrated from an initial weak mesoscale vortex in an idealized quiescent environment. The simulation has been studied extensively in the literature. We find that momentum advection is almost everywhere important (some of it is associated with asymmetric eddies). We discuss the implication of our findings on the proposed importance of Ekman-like balance dynamics during SEF. Finally, our analysis does not support the recently proposed idea that the radial advection of radial momentum, and shock-like structures, are closely related to the supergradient wind phenomena observed during SEF.

  5. Nonlinear Stability and Structure of Compressible Reacting Mixing Layers

    NASA Technical Reports Server (NTRS)

    Day, M. J.; Mansour, N. N.; Reynolds, W. C.

    2000-01-01

    The parabolized stability equations (PSE) are used to investigate issues of nonlinear flow development and mixing in compressible reacting shear layers. Particular interest is placed on investigating the change in flow structure that occurs when compressibility and heat release are added to the flow. These conditions allow the 'outer' instability modes- one associated with each of the fast and slow streams-to dominate over the 'central', Kelvin-Helmholtz mode that unaccompanied in incompressible nonreacting mixing layers. Analysis of scalar probability density functions in flows with dominant outer modes demonstrates the ineffective, one-sided nature of mixing that accompany these flow structures. Colayer conditions, where two modes have equal growth rate and the mixing layer is formed by two sets of vortices, offer some opportunity for mixing enhancement. Their extent, however, is found to be limited in the mixing layer's parameter space. Extensive validation of the PSE technique also provides a unique perspective on central- mode vortex pairing, further supporting the view that pairing is primarily governed perspective sheds insight on how linear stability theory is able to provide such an accurate prediction of experimentally-observed, fully nonlinear flow phenomenon.

  6. Layer structure: The oxides A 3Ti 5MO 14

    NASA Astrophysics Data System (ADS)

    Hervieu, M.; Rebbah, H.; Desgardin, G.; Raveau, B.

    1980-11-01

    Five new oxides, K 3Ti 5MO 14, Rb 3Ti 5MO 14 ( M = Ta, Nb), and Tl 3Ti 5NbO 14, have been synthesized. The structure of these oxides consists of octahedral layers similar to those observed for Na 2Ti 3O 7 and held together by monovalent ions; the sheets consist of blocks of 2 × 3 edge-sharing octahedra, which are then joined to each other by the corners of the octahedra. The relative disposition of the layers is similar to that observed for Tl 2Ti 4O 9. These oxides can be considered as the member n = 3 of a series of closely related structures with formula AnB2 nO 4 n+2 , where n indicates the number of octahedra which determines the width of the blocks of 2 × n octahedra.

  7. Atomistic origin of an ordered superstructure induced superconductivity in layered chalcogenides.

    PubMed

    Ang, R; Wang, Z C; Chen, C L; Tang, J; Liu, N; Liu, Y; Lu, W J; Sun, Y P; Mori, T; Ikuhara, Y

    2015-01-01

    Interplay among various collective electronic states such as charge density wave and superconductivity is of tremendous significance in low-dimensional electron systems. However, the atomistic and physical nature of the electronic structures underlying the interplay of exotic states, which is critical to clarifying its effect on remarkable properties of the electron systems, remains elusive, limiting our understanding of the superconducting mechanism. Here, we show evidence that an ordering of selenium and sulphur atoms surrounding tantalum within star-of-David clusters can boost superconductivity in a layered chalcogenide 1T-TaS2-xSex, which undergoes a superconducting transition in the nearly commensurate charge density wave phase. Advanced electron microscopy investigations reveal that such an ordered superstructure forms only in the x area, where the superconductivity manifests, and is destructible to the occurrence of the Mott metal-insulator transition. The present findings provide a novel dimension in understanding the relationship between lattice and electronic degrees of freedom. PMID:25625438

  8. Structure of the magnetopause current layer at the subsolar point

    SciTech Connect

    Okuda, H.

    1991-12-01

    A one-dimensional electromagnetic particle simulation model developed for the magnetopause current layer between the shocked solar wind and the dipole magnetic field at the subsolar point has been extended to include the interplanetary magnetic field (IMF) in the solar wind. Interaction of the solar wind with the vacuum dipole field as well as the dipole field filled with a low density magnetospheric plasma are studied. It is found that the width and the structure of the magnetopause current layer differ markedly depending on the direction of the IMF. When the IMF is pointing southward, the current layer between the solar wind and the dipole field is narrow and the magnetic field has a single ramp structure caused by the reflection of the solar wind at that point. The current layer becomes several times wider and the magnetic field developes a multiple ramp structure when the IMF is northward. This broadening of the current layer is caused by the multiple reflection of the solar wind by the magnetic field. For the northward IMF, the magnetic field does not change its sign across the current layer so that the E {times} B drift of the solar wind electrons remains the same direction while for the southward IMF, it reverses the sign. This results in a single reflection of the solar wind for the southward IMF and multiple reflections for the northward IMF. When a low density mangetospheric plasma is present in the dipole magnetic field, a small fraction of the solar wind ions are found to penetrate into the dipole magnetic field beyond the reflection point of the solar wind electrons. The width of the ion current layer is of the order of the solar wind ion gyroradius, however, the current associated with the ions remains much smaller than the electron current so long as the density of the magnetospheric plasma is much smaller than the density of the solar wind. Comparisons of our simulation results with the magnetopause crossing near the subsolar point are provided.

  9. Turbulence Structure in Rough and Smooth Wall Boundary Layers

    NASA Astrophysics Data System (ADS)

    Volino, Ralph; Schultz, Michael; Flack, Karen

    2006-11-01

    The outer region structure of turbulent boundary layers on smooth and rough walls was studied experimentally. Turbulence spectra were computed from LDV data. Velocity fields were computed from PIV data. Instantaneous swirl strength fields were computed from the velocity fields. The heads of hairpin vortices grouped as packets were visible in the streamwise wall normal plane, and the legs of these vortices were visible along the length of low speed streaks in streamwise spanwise planes at y/δ=0.1 and 0.4. These structures, observed previously in smooth wall boundary layers, were qualitatively similar in the rough and smooth wall cases. Two point correlations of the velocity and swirl strength were quantitatively similar for the smooth and rough walls. The turbulence spectra and probability density functions of the turbulence and swirl strength also showed quantitative similarity between the rough and smooth wall cases when the results were normalized using the friction velocity and the boundary layer thickness. This similarity in turbulence structure is in agreement with the similarity in turbulence statistics reported previously.

  10. Characteristics of turbulent structures in the unstable atmospheric surface layer

    NASA Astrophysics Data System (ADS)

    Schols, J. L. J.; Jansen, A. E.; Krom, J. G.

    1985-10-01

    An atmospheric surface-layer (ASL) experiment conducted at a meteorological site in the Oostelijk-Flevoland polder of the Netherlands is described. Turbulent fluctuations of wind velocity, air temperature and static pressure were measured, using three 10 m towers. Simultaneous turbulent signals at several heights on the towers were used to investigate the properties of the turbulent structures which contribute most significantly to the turbulent vertical transports in the unstable ASL. These turbulent structures produce between 30 and 50% of the mean turbulent vertical transport of horizontal alongwind momentum and they contribute to between 40 and 50% of the mean turbulent vertical heat transport; in both cases this occurs during 15 to 20% of the total observation time. The translation speed of the turbulent structures equals the wind speed averaged over the depth of the ASL, which scales on the surface friction velocity. The inclination angle of the temperature interface at the upstream edge of the turbulent structures to the surface is significantly smaller than that of the internal shear layer, which is associated with the temperature interface. The turbulent structures in the unstable ASL are determined by a large-scale temperature field: Convective motions, which encompass the whole depth of the planetary boundary layer (PBL), penetrate into the ASL. The curvature of the vertical profile of mean horizontal alongwind velocity forces the alignment of the convective cells in the flow direction (Kuettner, 1971), which have an average length of several hundreds of metres and an average width of a few tens of metres. This mechanism leads to the formation of turbulent structures, which extend throughout the depth of the ASL.

  11. Structural Investigation of Layered Niobates by DFT Calculations

    NASA Astrophysics Data System (ADS)

    Adhikari Subin, Jhashanath

    Layered forms of inorganic niobates have been used for various applications, such as charge transport and storage, photo-catalysis, solid acids, magnetic materials, superconductors, magneto-resistors and photo-luminescence devices. The layered niobates exists in different geometrical forms and composition with variation in the packing of oxide lattice by the constituting monovalent, divalent/trivalent and pentavalent cations. Four different types of lamellar niobates are studied in this research by theoretical methods, namely the all-electron full-potential DFT method using plane wave and periodic boundary conditions. A common feature of all the layered niobates is that the basic building block, NbO6 octahedral units are shared with each other at the corners and edges forming a covalent network and that the sharing is terminated in a particular direction. These octahedral units get modulated along with the geometry of interlayer interface with the change in the composition of the material. The macroscopic structure change is reflected by the alteration of the unit cell axes whereas the local change at various sites in the structure is revealed by the variation of the atomic distances and angles/tilt. The different properties of the layered compounds are a function of these structural variations and thus understanding the mechanism and the characteristics requires atomic level analysis. Calculations reveal the local bonding details and the bulk geometry of a material and can be compared to that obtained from powder diffraction methods. The EFG tensor which is a sensitive probe of the electronic environment around a quadrupolar nucleus can be used to monitor the minor changes in the bond lengths and angles in various structures. Among the configurations lying in the minima of the potential energy surfaces, the one representing the real material would be the one matching with the EFG tensor calculated from DFT methods with that determined from the SSNMR experiments

  12. Toward the origin of exciton electronic structure in phycobiliproteins

    NASA Astrophysics Data System (ADS)

    Womick, Jordan M.; Miller, Stephen A.; Moran, Andrew M.

    2010-07-01

    Femtosecond laser spectroscopies are used to examine the electronic structures of two proteins found in the phycobilisome antenna of cyanobacteria, allophycocyanin (APC) and C-phycocyanin (CPC). The wave function composition involving the pairs of phycocyanobilin pigments (i.e., dimers) found in both proteins is the primary focus of this investigation. Despite their similar geometries, earlier experimental studies conducted in our laboratory and elsewhere observe clear signatures of exciton electronic structure in APC but not CPC. This issue is further investigated here using new experiments. Transient grating (TG) experiments employing broadband quasicontinuum probe pulses find a redshift in the signal spectrum of APC, which is almost twice that of CPC. Dynamics in the TG signal spectra suggest that the sub-100 fs dynamics in APC and CPC are respectively dominated by internal conversion and nuclear relaxation. A specialized technique, intraband electronic coherence spectroscopy (IECS), photoexcites electronic and nuclear coherences with nearly full suppression of signals corresponding to electronic populations. The main conclusion drawn by IECS is that dephasing of intraband electronic coherences in APC occurs in less than 25 fs. This result rules out correlated pigment fluctuations as the mechanism enabling exciton formation in APC and leads us to propose that the large Franck-Condon factors of APC promote wave function delocalization in the vibronic basis. For illustration, we compute the Hamiltonian matrix elements involving the electronic origin of the α84 pigment and the first excited vibronic level of the β84 pigment associated with a hydrogen out-of-plane wagging mode at 800 cm-1. For this pair of vibronic states, the -51 cm-1 coupling is larger than the 40 cm-1 energy gap, thereby making wave function delocalization a feasible prospect. By contrast, CPC possesses no pair of vibronic levels for which the intermolecular coupling is larger than the energy

  13. Plasmon and exciton superconductivity mechanisms in layered structures

    NASA Technical Reports Server (NTRS)

    Gabovich, A. M.; Pashitskiy, E. A.; Uvarova, S. K.

    1977-01-01

    Plasmon and exciton superconductivity mechanisms are discussed. Superconductivity in a three layer metal semiconductor metal and insulator semimetal insulator sandwich structure was described in terms of the temperature dependent Green function of the longitudinal (Coulomb) field. The dependences of the superconducting transition temperature on structure parameters were obtained. In a semiconducting film, as a result of interactions of degenerate free carriers with excitons, superconductivity exists only in a certain range of parameter values, and the corresponding critical temperature is much lower than in the plasmon mechanism of superconductivity.

  14. Coherent structures in stratocumulus-topped boundary layer

    NASA Astrophysics Data System (ADS)

    Davini, Paolo; D'Andrea, Fabio; Park, Seungbu; Gentine, Pierre

    2016-04-01

    Coherent structures as updraft, downdraft, ascendance and subsidence are analyzed in stratocumulus-topped boundary layers using a new classification method, based on an octant analysis. This is performed using high-resolution Large Eddy Simulations (LES) simulations for both an idealized case (SMOKE) and a realistic configuration case (DYCOMS-II RF01). The analysis shows symmetry between downdrafts and updrafts, with the former driven by the radiative cooling and the second one initiated by the mechanical bouncing on the surface. The characteristics of the different structures (e.g. temperature, humidity, mass and turbulent fluxes, areal fractions) are described.

  15. Local structure determination in strained-layer semiconductors

    NASA Astrophysics Data System (ADS)

    Woicik, Joseph C.

    The theory of elasticity accurately describes the deformations of macroscopic bodies under the action of applied stress [1]. In this review, we examine the internal mechanisms of elasticity for strained-layer semiconductor heterostructures. In particular, we present extended x-ray-absorption fine structure (EXAFS) and x-ray diffraction (XRD) measurements to show how the bond lengths and bond angles in semiconductor thin-alloy films change with strain when they are grown coherently on substrates with different lattice constants. The structural distortions measured by experiment are compared to valence-force field (VFF) calculations and other theoretical models. Atomic switching and interfacial strain at buried interfaces are also discussed.

  16. The origin of SH-wave resonance frequencies in sedimentary layers

    NASA Astrophysics Data System (ADS)

    van der Baan, Mirko

    2009-09-01

    Resonance frequencies are often analysed in geo-engineering studies to evaluate seismic risk and microzonation in urban areas. The Nakamura technique constitutes a popular approach that computes the spectral ratio of horizontal-to-vertical ground motion in ambient noise recordings to reveal the existence of any site resonance frequencies. Its theoretical basis remains however unclear with some authors arguing that the method de-emphasizes any Rayleigh-wave contributions and that the resonance frequencies are solely caused by vertically incident SH waves. Other authors explain the same resonance frequencies by the ellipticity of the fundamental Rayleigh wave. Recent numerical simulations reveal that the magnitude of the peak frequency is proportional to the relative portion of Love waves present. This study demonstrates that Love waves alone can be responsible for any observed resonance frequencies in sedimentary layers. Yet sharp SH-wave resonance frequencies are only excited by a source in the bedrock. These resonance frequencies are caused by inhomogeneous waves excited by the bedrock source that tunnel through the high-velocity bedrock to emerge in the low-velocity sediments with a very reduced range of slownesses. The resulting SH waves are then free to interfere constructively thereby creating the observed resonance frequencies. This general trigger mechanism leads to resonances that are almost offset independent. The resulting resonance frequencies map onto points of maximum curvature in the Love-wave phase-velocity dispersion curves at or just beyond the critical horizontal slowness. They can be analysed with the quarter-wavelength law if a large velocity contrast exists between the unconsolidated sediments and the bedrock. A minor modification of the quarter-wavelength law provides more accurate predictions, also for smaller velocity contrasts. Multisource simulations show that site amplification factors as determined by horizontal-over-vertical (H

  17. Modeling a Possible Volcanic Origin for Interior Layered Deposits on Mars

    NASA Astrophysics Data System (ADS)

    Chapman, M. G.; Kneissl, T.

    2011-12-01

    This study was undertaken to examine the valid range of temperatures required for sub-ice volcanic origin of interior layered deposits (ILDs) in Valles Marineris. To this end, using GIS the volume estimates of Ophir Chasma and its 4 ILDs were mapped and measured. The GIS volumes in this study are based on high-res HRSC topography overlain on MOLA. We determined the void space of Ophir Chasma sans ILDs to be 92,319 km3. Volumes for each ILD mound were determined to be 6,185 km3, 4,833 km3, 2,628 km3, and 0.2 km3 (negligible); totaling 13,642 km3. A sub-ice volcano requires eruption beneath an existing ice sheet or ponded ice. If during the formation of a sub-ice volcano the associated unstable englacial meltwater lake is drained by jökulhlaups or if the volcano rises above the meltwater, effused subaerial lava will cap the tuff cone forming resistant sheet lavas. Hence, the lava cap horizon can be used to estimate the minimum height of ice. Three resistant ILD caprock locales (found only on the 2 largest ILDs) were mapped and the hypothetical ice volumes measured beneath their elevations are 77,391 km3, 79,899 km3, and 51,695 km3. Following the equation from Chapman et al. (2003), if the known ILDs in Ophir are assumed to be basaltic subice volcanoes, calorimetry can be used to estimate the volumes of meltwater generated by their eruption [Allen, 1980; Björnsson, 1988; Gudmundsson and Björnsson, 1991; Gudmundsson et al., 1997; Höskuldsson and Sparks, 1997]. These estimates are based on (1) the volume and likely mound density, (2) the heat content of basaltic magmas, and (3) the specific heat capacity and the latent heat of fusion for ice. The ice that can be melted by a mass of magma as it solidifies and cools can be calculated by equating the heat content of the magma with the heat used for melting. Two possible end member cases were used. In the first case it is assumed that the chasma contained ice at its melting point of 273 K and in the other case the

  18. Enzymatic Degradation of Polysaccharide-Based Layer-by-Layer Structures.

    PubMed

    Cardoso, Matias J; Caridade, Sofia G; Costa, Rui R; Mano, João F

    2016-04-11

    The lack of knowledge on the degradation of layer-by-layer structures is one of the causes hindering its translation to preclinical assays. The enzymatic degradation of chitosan/hyaluronic acid films in the form of ultrathin films, freestanding membranes, and microcapsules was studied resorting to hyaluronidase. The reduction of the thickness of ultrathin films was dependent on the hyaluronidase concentration, leading to thickness and topography variations. Freestanding membranes exhibited accelerated weight loss up to 120 h in the presence of the enzyme, achieving complete degradation. Microcapsules with around 5 μm loaded simultaneously with FITC-BSA and hyaluronidase showed that the coencapsulation of such enzyme and protein mixture led to a FITC-BSA release four times higher than in the absence of hyaluronidase. The results suggest that the degradation of LbL devices may be tuned via embedded enzymes, namely, in the controlled release of active agents in biomedical applications. PMID:26957012

  19. Effect of layered composite meta-structures on the optical activity and ellipticity of structural biomolecules

    NASA Astrophysics Data System (ADS)

    Khoo, E. H.; Hor, Y. Li; Leong, Eunice S. P.; Liu, Y. J.

    2014-09-01

    In this paper, we design layered composite meta-structures to investigate its' effect on the optical activity and circular dichroism (CD). The layered composite meta-structures consist of thin gammadion nanostructure with thickness λ/10, where λ is the incident wavelength. The layered meta-structures are alternate between a dielectric and gold (AU) material. Each layered composite meta-gammadion is arranged together in an array of pitch 700 nm. In the first case, 3 layers of meta-gammadion, with metal-insulator-metal (MIM) and insulator-metal-insulator (IMI) configuration are simulated with material properties from optical hand book. There are 3 modes in the CD spectrum, which can be characterized into Bloch CD mode and hybrid CD modes. Compared with the CD spectrum of whole structure of gammadion in gold with same total height, the CD of the MIM layered composite are larger. When the number layer increase to 5, it is observed that the CD is reduced by 30% and there is a red shift in the Bloch CD mode and a slight blue shift in the hybrid CD modes. By further increasing the number of layers to 7, we observed further CD increment and larger wavelength shift in the CD modes. The layered composite meta-gammadion is fabricated using template stripping method. Experimental results also show excellent agreement with the simulation results for CD and wavelength shift. We submerge the layered meta-gammadion into a solution of chiral molecules. The CD spectrum of the meta-gammadion shows a larger wavelength shift compared to pure metal structures. This indicate a more sensitive and robust detection of chiral molecules.

  20. Morphology control of layer-structured gallium selenide nanowires.

    PubMed

    Peng, Hailin; Meister, Stefan; Chan, Candace K; Zhang, Xiao Feng; Cui, Yi

    2007-01-01

    Layer-structured group III chalcogenides have highly anisotropic properties and are attractive materials for stable photocathodes and battery electrodes. We report the controlled synthesis and characterization of layer-structured GaSe nanowires via a catalyst-assisted vapor-liquid-solid (VLS) growth mechanism during GaSe powder evaporation. GaSe nanowires consist of Se-Ga-Ga-Se layers stacked together via van der Waals interactions to form belt-shaped nanowires with a growth direction along the [11-20], width along the [1-100], and height along the [0001] direction. Nanobelts exhibit a variety of morphologies including straight, zigzag, and saw-tooth shapes. These morphologies are realized by controlling the growth temperature and time so that the actual catalysts have a chemical composition of Au, Au-Ga alloy, or Ga. The participation of Ga in the VLS catalyst is important for achieving different morphologies of GaSe. In addition, GaSe nanotubes are also prepared by a slow growth process. PMID:17212464

  1. Two new barium sulfonates with pillared layered structures

    NASA Astrophysics Data System (ADS)

    Yang, Jin; Li, Li; Ma, Jian-Fang; Liu, Ying-Ying; Ma, Ji-Cheng

    2006-08-01

    The reactions of BaCl 2·2H 2O with NaHL a and K 3L b (H 2L a=4-hydroxybenzenesulfonic acid, H 3L b=4-hydroxy-5-nitro-1,3-benzenedisulfonic acid) gave two pillared layered coordination polymers: Ba(HL a)(Cl) 1 and KBaL b(H 2O) 32, respectively. The crystal structures were determined by X-ray diffraction method and refined by full-matrix least-squares methods to R=0.0509 and wR=0.1216 using 1455 reflections with I>2 σ( I) for 1; and R=0.0288 and wR=0.0727 using 2661 reflections with I>2 σ( I) for 2. The interesting feature of compound 1 is the coordination actions of chloride anions, which help to form the polymeric layers by bridging barium cations. In compound 2 the Lb3- anion acts as an unusual dodecadente ligand to form a coordination polymer with pillared layered structure.

  2. Two new barium sulfonates with pillared layered structures

    NASA Astrophysics Data System (ADS)

    Yang, Jin; Li, Li; Ma, Jian-Fang; Liu, Ying-Ying; Ma, Ji-Cheng

    2006-05-01

    The reactions of BaCl 2·2H 2O with NaHL a and K 3L b (H 2L a=4-hydroxybenzenesulfonic acid, H 3L b=4-hydroxy-5-nitro-1,3-benzenedisulfonic acid) gave two pillared layered coordination polymers: Ba(HL a)(Cl) 1 and KBaL b(H 2O) 32, respectively. The crystal structures were determined by X-ray diffraction method and refined by full-matrix least-squares methods to R=0.0509 and wR=0.1216 using 1455 reflections with I>2 σ( I) for 1; and R=0.0288 and wR=0.0727 using 2661 reflections with I>2 σ( I) for 2. The interesting feature of compound 1 is the coordination actions of chloride anions, which help to form the polymeric layers by bridging barium cations. In compound 2 the Lb3- anion acts as an unusual dodecadente ligand to form a coordination polymer with pillared layered structure.

  3. Elastic properties of nanostructured materials with layered grain boundary structure

    NASA Astrophysics Data System (ADS)

    Karakasidis, T. E.; Charitidis, C. A.; Skarakis, D.; Chouliaras, F.

    2007-08-01

    Atomistic calculations of the elastic constants for a bulk nanostructured material that consists of a layered structure where alternating layers meet along high angle grain boundaries and where atoms interact via a Lennard-Jones potential are presented. The calculations of the elastic constants were performed in the frame of homogeneous deformations for a wide range of layer widths ranging from 2.24 up to 74.62 nm. The results showed that the relaxation of the atomic structure affects the elastic constants for the cases where more than 5% of atoms are located in the GB region. Also it was found that the way that external stresses are applied on the system affects the values of the obtained elastic properties, with the elastic constants related to the characteristic directions of the grain boundary being the most affected ones. The findings of this work are of interest for the fabrication methods of nanostructured materials, the measurement methods of their elastic properties as well as multiscale modeling schemes of nanostructured materials.

  4. Thermal structure, radial anisotropy, and dynamics of oceanic boundary layers

    NASA Astrophysics Data System (ADS)

    Auer, Ludwig; Becker, Thorsten W.; Boschi, Lapo; Schmerr, Nicholas

    2015-11-01

    Defining the oceanic lithosphere as a thermal boundary layer allows to explain, to first order, age-dependent bathymetry and isotropic wave speeds. In contrast, SS precursors and receiver functions suggest a subhorizontal interface within this layer, on top of a radially anisotropic zone. Comparing a suite of geodynamic scenarios against surface wave dispersion data and seismic discontinuities, we find that only weak age dependency of the radially anisotropic zone is compatible with observations. We show that this zone is confined from below by a second weaker seismic interface. While observed azimuthal anisotropy is consistent with lattice-preferred orientation of olivine due to asthenospheric flow underneath the lithosphere, radial anisotropy requires additional contributions, perhaps from petrological fabrics or melt ponding. This implies that seismic reflectors previously associated with the base of the lithosphere are instead associated with preserved structures embedded in it. They carry information about plate formation but have little control on plate deformation.

  5. Materials design of ceramic-based layer structures for crowns.

    PubMed

    Lawn, B R; Deng, Y; Lloyd, I K; Janal, M N; Rekow, E D; Thompson, V P

    2002-06-01

    Radial cracking has been identified as the primary mode of failure in all-ceramic crowns. This study investigates the hypothesis that critical loads for radial cracking in crown-like layers vary explicitly as the square of ceramic layer thickness. Experimental data from tests with spherical indenters on model flat laminates of selected dental ceramics bonded to clear polycarbonate bases (simulating crown/dentin structures) are presented. Damage initiation events are video-recorded in situ during applied loading, and critical loads are measured. The results demonstrate an increase in the resistance to radial cracking for zirconia relative to alumina and for alumina relative to porcelain. The study provides simple a priori predictions of failure in prospective ceramic/substrate bilayers and ranks ceramic materials for best clinical performance. PMID:12097438

  6. Vortical structure in a forced plane mixing layer

    NASA Technical Reports Server (NTRS)

    Leboeuf, Richard L.

    1993-01-01

    The objective of this phase of an ongoing study is to obtain detailed three dimensional phase-averaged measurements of forced mixing layer vorticity development and evolution. Acoustic forcing is being used to phase-lock the initial development and subsequent pairing of the span wise vortical structures. Phase averaged measurements of the three velocity components will permit the study of three dimensional vorticity distributions without invoking Taylor's hypothesis which is known to introduce uncertainty. Currently two sine waves, one at the fundamental roll-up frequency and the second, its subharmonic, are being used to force the initial roll-up and first pairing of the span wise rollers. The two dimensional measurements described in this report were obtained in order to determine the best operating conditions for the detailed three dimensional study of the mixing layer undergoing pairing via various pairing mechanisms.

  7. Single and Few Layer Silicene: Structural, Electronic and Transport Properties

    NASA Astrophysics Data System (ADS)

    Carey, J. David; Roome, Nathanael

    Single layer silicene has weaker π bonding that graphene resulting in buckling of the Si atoms in different sub-lattices. Despite the loss of planarity, a linear bandstructure emerges where we find a Fermi velocity of about 5.3 x 105 m/s. Determination of the phonon dispersion characteristics reveals a Γ point optical phonon with an energy of 69 meV and a K point optical phonon with an energy of 62 meV. In graphene these phonons play important role in scattering electrons, and in Raman spectroscopy, but have larger energies of 194 and 166 meV, respectively. The lower phonon energies in silicene, arising from the higher atomic masses, would be expected to scatter carriers efficiently and limit carrier mobility. We have calculated, however, that the electron-optical phonon coupling matrix elements are about a factor of 25 times smaller than in graphene and this important result will help with the further development of silicene based devices due to reduced phonon scattering. The two stable stacking configurations of bilayer silicene, AA and AB, now have to account of the position of the atomic buckling in the two layers, leading to four possible atomic configurations with the buckling between the layers being in- or out-of-phase with each other. We find that in contrast to graphene, the two stable configurations are based on AA type stacking being about 70 meV per atom more stable than AB stacking. The potential for elemental layered materials beyond graphene for device applications will also be discussed. Single and Few Layer Silicene: Structural, Electronic and Transport Properties.

  8. LiNiFe-based layered structure oxide and composite for advanced single layer fuel cells

    NASA Astrophysics Data System (ADS)

    Zhu, Bin; Fan, Liangdong; Deng, Hui; He, Yunjune; Afzal, Muhammad; Dong, Wenjing; Yaqub, Azra; Janjua, Naveed K.

    2016-06-01

    A layered structure metal oxide, LiNi0.1Fe0.90O2-δ (LNF), is explored for the advanced single layer fuel cells (SLFCs). The temperature dependent impedance profiles and concentration cells (hydrogen concentration, oxygen concentration, and H2/air atmospheres) tests prove LNF to be an intrinsically electronic conductor in air while mixed electronic and proton conductor in H2/air environment. SLFCs constructed by pure LNF materials show significant short circuiting reflected by a low device OCV and power output (175 mW cm-2 at 500 °C) due to high intrinsic electronic conduction. The power output is improved up to 640 and 760 mW cm-2, respectively at 500 and 550 °C by compositing LNF with ion conducting material, e.g., samarium doped ceria (SDC), to balance the electronic and ionic conductivity; both reached at 0.1 S cm-1 level. Such an SLFC gives super-performance and simplicity over the conventional 3-layer (anode, electrolyte and cathode) FCs, suggesting strong scientific and commercial impacts.

  9. Identification of lagrangian coherent structures in the turbulent boundary layer

    NASA Astrophysics Data System (ADS)

    Pan, Chong; Wang, Jinjun; Zhang, Cao

    2009-02-01

    Using Finite-Time Lyapunov Exponents (FTLE) method, Lagrangian coherent structures (LCSs) in a fully developed flat-plate turbulent boundary layer are successfully identified from a two-dimensional (2D) velocity field obtained by time-resolved 2D PIV measurement. The typical LCSs in the turbulent boundary layer are hairpin-like structures, which are characterized as legs of quasi-streamwise vortices extending deep into the near wall region with an inclination angle θ to the wall, and heads of the transverse vortex tube located in the outer region. Statistical analysis on the characteristic shape of typical LCS reveals that the probability density distribution of θ accords well with t-distribution in the near wall region, but presents a bimodal distribution with two peaks in the outer region, corresponding to the hairpin head and the hairpin neck, respectively. Spatial correlation analysis of FTLE field is implemented to get the ensemble-averaged inclination angle θ R of typical LCS. θ R first increases and then decreases along the wall-normal direction, similar to that of the mean value of θ. Moreover, the most probable value of θ saturates at y +=100 with the maximum value of about 24°, suggesting that the most likely position where hairpins transit from the neck to the head is located around y +=100. The ensemble- averaged convection velocity U c of typical LCS is finally calculated from temporal-spatial correlation analysis of FTLE field. It is found that the wall-normal profile of the convection velocity U c( y) accords well with the local mean velocity profile U( y) beyond the buffer layer, evidencing that the downstream convection of hairpins determines the transportation properties of the turbulent boundary layer in the log-region and beyond.

  10. Flexural strength and failure modes of layered ceramic structures

    PubMed Central

    Borba, Márcia; de Araújo, Maico D.; de Lima, Erick; Yoshimura, Humberto N.; Cesar, Paulo F.; Griggs, Jason A.; Bona, Álvaro Della

    2011-01-01

    Objective to evaluate the effect of the specimen design on the flexural strength (σf) and failure mode of ceramic structures, testing the hypothesis that the ceramic material under tension controls the mechanical performance of the structure. Methods Three ceramics used as framework materials for fixed partial dentures (YZ - Vita In-Ceram YZ; IZ - Vita In-Ceram Zirconia; AL - Vita In-Ceram AL) and two veneering porcelains (VM7 and VM9) were studied. Bar-shaped specimens were produced in three different designs (n=10): monolithic, two layers (porcelain-framework) and three layers (TRI) (porcelain-framework-porcelain). Specimens were tested for three-point flexural strength at 1 MPa/s in 37°C artificial saliva. For bi-layered design, the specimens were tested in both conditions: with porcelain (PT) or framework ceramic (FT) layer under tension. Fracture surfaces were analyzed using stereomicroscope and scanning electron microscopy (SEM). Young’s modulus (E) and Poisson’s ratio (ν) were determined using ultrasonic pulse-echo method. Results were statistically analyzed by Kruskal-Wallis and Student-Newman-Keuls tests. Results Except for VM7 and VM9, significant differences were observed for E values among the materials. YZ showed the highest ν value followed by IZ and AL. YZ presented the highest σf. There was no statistical difference in the σf value between IZ and IZ-FT and between AL and AL-FT. σf values for YZ-PT, IZ-PT, IZ-TRI, AL-PT, AL-TRI were similar to the results obtained for VM7 and VM9. Two types of fracture mode were identified: total and partial failure. Significance The mechanical performance of the specimens was determined by the material under tension during testing, confirming the study hypothesis. PMID:21982199

  11. Electrical breakdown of graphene and few-layer graphene structures

    NASA Astrophysics Data System (ADS)

    Sundararajan, Abhishek; Hunley, D. Patrick; Strachan, Douglas. R.

    2012-02-01

    The electrical breakdown of graphene and few-layer graphene (FLG) structures are investigated. To better understand the dynamics of these nano-scale thermal effects, we investigate graphene and FLG structures of various dimensions and find that significant joule heating occurs inducing the structures to evolve. A distinct change in the behavior during electrical stressing indicates that different mechanisms and geometrical effects occur at the various stages of evolution. The results could have implications on the development of high current carrying nanoscale graphene devices. Supported in part by NSF Award No. DMR-0805136, the Kentucky NSF EPSCoR program through award EPS-0814194, and the University of Kentucky Center for Advanced Materials.

  12. Electrical breakdown of graphene and few-layer graphene structures

    NASA Astrophysics Data System (ADS)

    Sundararajan, Abhishek; Johnson, Stephen; Hunley, D. Patrick; Flores, Roel; Johnson, A. T. Charlie; Strachan, Douglas

    2011-03-01

    The electrical breakdown of graphene and few-layer graphene (FLG) structures are investigated. To better understand the dynamics of these nano-scale thermal effects, we investigate graphene and FLG nanowires of various dimensions and find that significant joule heating occurs inducing the structures to evolve. A distinct change in the behavior during electrical stressing indicates that different mechanisms occur at the various stages of evolution. The results are compared to detailed thermal modeling of our structures and could have implications on the development of high current carrying nanoscale graphene devices. Supported in part by NSF Award No. DMR-0805136, the Kentucky NSF EPSCoR program, the University of Kentucky Center for Advanced Materials, and the University of Kentucky Center for Nanoscale Science and Engineering.

  13. Tracking Coherent Structures in a Mach 4 Turbulent Boundary Layer

    NASA Astrophysics Data System (ADS)

    Subbareddy, Pramod; Moss, Alin; Marusic, Ivan; Candler, Graham

    2000-11-01

    We describe a study of different criteria for the detection and tracking of coherent vortical structures in a turbulent compressible boundary layer. Several vortex identification methods are presented, with special attention to methods based on the eigenvalues of the velocity gradient tensor. We find that for the Mach 4 compressible flow, the discriminant of the characteristic polynomial of the tensor is most suitable in the sense that the near wall coherent features are better defined. The vortex connection/reconnection process that we observe is tracked in time and studied. The visualizations are done using a classical ray-casting volume renderer which makes it possible to color-fill specific structures and follow their motion through the flow field. A qualitative comparison with an incompressible wall turbulence is also made. The long term goal of this study is to develop feature extraction tools which can track the evolution of structures in large data sets efficiently.

  14. Origin of the Mackenzie large igneous province and sourcing of flood basalts from layered intrusions

    NASA Astrophysics Data System (ADS)

    Day, J. M.; Pearson, D.

    2013-12-01

    The 1.27 Ga Coppermine continental flood basalt (CFB) in northern Canada represents the extrusive manifestation of the Mackenzie large igneous province (LIP) that includes the Mackenzie dyke swarm and the Muskox layered intrusion. New Re-Os isotope and highly siderophile element (HSE: Re, Pd, Pt, Ru, Ir, Os) abundance data are reported together with whole-rock major- and trace-element abundances and Nd isotopes to examine the behaviour of the HSE during magmatic differentiation and to place constraints on the extent of crustal interaction with mantle-derived melts. Mineral-chemical data are also reported for an unusual andesite glass flow (4.9 wt.% MgO) found in proximity to newly recognised picrites (>20 wt.% MgO) in the lowermost stratigraphy of the Coppermine CFB. Compositions of mineral phases in the andesite are similar to equivalent phases found in Muskox Intrusion chromitites and the melt composition is identical to Muskox chromite melt inclusions. Elevated HSE contents (e.g., 3.8 ppb Os) and the mantle-like initial Os isotope composition of this andesitic glass contrast strongly with oxygen isotope and lithophile element evidence for extensive crustal contamination. These signatures implicate an origin for the glass as a magma mingling product formed within the Muskox Intrusion during chromitite genesis. The combination of crust and mantle signatures define roles for both these reservoirs in chromitite genesis, but the HSE appear to be dominantly mantle-sourced. Combined with Nd isotope data that places the feeder for lower Coppermine CFB picrites and basalts within the Muskox Intrusion, this provides the strongest evidence yet for direct processing of some CFB within upper-crustal magma chambers. Modeling of absolute and relative HSE abundances in CFB reveal that HSE concentrations decrease with increasing fractionation for melts with <8×1 wt.% MgO in the Coppermine CFB, with picrites (>13.5wt.% MgO) from CFB having higher Os abundances than ocean island

  15. Platinum-induced structural collapse in layered oxide polycrystalline films

    SciTech Connect

    Wang, Jianlin; Liu, Changhui; Huang, Haoliang; Fu, Zhengping; Peng, Ranran E-mail: yllu@ustc.edu.cn; Zhai, Xiaofang; Lu, Yalin E-mail: yllu@ustc.edu.cn

    2015-03-30

    Effect of a platinum bottom electrode on the SrBi{sub 5}Fe{sub 1−x}Co{sub x}Ti{sub 4}O{sub 18} layered oxide polycrystalline films was systematically studied. The doped cobalt ions react with the platinum to form a secondary phase of PtCoO{sub 2}, which has a typical Delafossite structure with a weak antiferromagnetism and an exceptionally high in-plane electrical conductivity. Formation of PtCoO{sub 2} at the interface partially consumes the cobalt dopant and leads to the structural collapsing from 5 to 4 layers, which was confirmed by X-ray diffraction and high resolution transmission electron microscopy measurements. Considering the weak magnetic contribution from PtCoO{sub 2}, the observed ferromagnetism should be intrinsic of the Aurivillius compounds. Ferroelectric properties were also indicated by the piezoresponse force microscopy. In this work, the platinum induced secondary phase at the interface was observed, which has a strong impact on Aurivillius structural configuration and thus the ferromagnetic and ferroelectric properties.

  16. Structure of rough-wall turbulent boundary layers

    NASA Technical Reports Server (NTRS)

    Bandyopadhyay, Promode R.; Watson, Ralph D.

    1988-01-01

    Recent experiments have shown that, in rough-wall turbulent boundary layers, drag varies systematically with the spanwise aspect ratio lambda(z) (span/height) of roughness elements. In this paper, the effect of lambda(z) on turbulence structure has been examined. Based on lambda(z), the roughness in a transversely grooved surface with lambda(z) much greater than 1 is the opposite extreme of model plant canopies with lambda(z) much less than 1, studied in wind tunnels, whereas sandgrain is an intermediate type. Second-, third-, and fourth-order turbulence moments have been measured in turbulent boundary layers over transversely grooved and smooth surfaces and compared with available turbulence structure measurements over other types of surfaces. The near-wall turbulence structure is found to vary with lambda(z). The instantaneous motions involved in the flux of shear stress near the wall in smooth and transversely grooved surfaces are opposite in sign to those in three-dimensional roughness. The former is explained in terms of hairpin vortices alone, while the latter group is modeled to have an additional vortex (the so-called necklace vortex which straddles a three-dimensional roughness element near its base).

  17. Platinum-induced structural collapse in layered oxide polycrystalline films

    NASA Astrophysics Data System (ADS)

    Wang, Jianlin; Huang, Haoliang; Liu, Changhui; Fu, Zhengping; Zhai, Xiaofang; Peng, Ranran; Lu, Yalin

    2015-03-01

    Effect of a platinum bottom electrode on the SrBi5Fe1-xCoxTi4O18 layered oxide polycrystalline films was systematically studied. The doped cobalt ions react with the platinum to form a secondary phase of PtCoO2, which has a typical Delafossite structure with a weak antiferromagnetism and an exceptionally high in-plane electrical conductivity. Formation of PtCoO2 at the interface partially consumes the cobalt dopant and leads to the structural collapsing from 5 to 4 layers, which was confirmed by X-ray diffraction and high resolution transmission electron microscopy measurements. Considering the weak magnetic contribution from PtCoO2, the observed ferromagnetism should be intrinsic of the Aurivillius compounds. Ferroelectric properties were also indicated by the piezoresponse force microscopy. In this work, the platinum induced secondary phase at the interface was observed, which has a strong impact on Aurivillius structural configuration and thus the ferromagnetic and ferroelectric properties.

  18. Characterization of structural response to hypersonic boundary-layer transition

    DOE PAGESBeta

    Riley, Zachary B.; Deshmukh, Rohit; Miller, Brent A.; McNamara, Jack J.; Casper, Katya M.

    2016-05-24

    The inherent relationship between boundary-layer stability, aerodynamic heating, and surface conditions makes the potential for interaction between the structural response and boundary-layer transition an important and challenging area of study in high-speed flows. This paper phenomenologically explores this interaction using a fundamental two-dimensional aerothermoelastic model under the assumption of an aluminum panel with simple supports. Specifically, an existing model is extended to examine the impact of transition onset location, transition length, and transitional overshoot in heat flux and fluctuating pressure on the structural response of surface panels. Transitional flow conditions are found to yield significantly increased thermal gradients, and theymore » can result in higher maximum panel temperatures compared to turbulent flow. Results indicate that overshoot in heat flux and fluctuating pressure reduces the flutter onset time and increases the strain energy accumulated in the panel. Furthermore, overshoot occurring near the midchord can yield average temperatures and peak displacements exceeding those experienced by the panel subject to turbulent flow. Lastly, these results suggest that fully turbulent flow does not always conservatively predict the thermo-structural response of surface panels.« less

  19. Changes in the turbulent boundary layer structure associated with net drag reduction by outer layer manipulators

    NASA Technical Reports Server (NTRS)

    Rashidnia, N.; Falco, R. E.

    1987-01-01

    A specially designed wind tunnel was used to examine the effects of tandemly arranged parallel plate manipulators (TAPPMs) on a turbulent boundary-layer structure and the associated drag. Momentum balances, as well as measurements of the local shear stress from the velocity gradient near the wall, were used to obtain the net drag and local skin friction changes. Two TAPPMs, identical except for the thickness of their plates, were used in the study. Results with .003 inch plates were a maximum net drag reduction of 10 percent at 58 beta sub o (using a momentum balance). At 20 beta sub o, simultaneous laser sheet flow visualization and hot-wire anemometry data showed that the Reynolds stress in the large eddies was significantly reduced, as were the streamwise and normal velocity components. Using space-time correlations the reductions were again identified. Furthermore, quantitative flow visualization showed that the outward normal velocity of the inner region was also significantly decreased in the region around 20 beta sub o. However, throughout the first 130 beta sub o, the measured sublayer thickness with the TAPPMs in place was 15 to 20 percent greater. The data showed that the skin friction, as well as the structure of the turbulence, was strongly modified in the first 35 beta sub o, but that they both significantly relaxed toward unmanipulated boundary layer values by 50 beta sub o.

  20. Ion mixing of III-V compound semiconductor layered structures

    SciTech Connect

    Xia, W.; Pappert, S.A.; Zhu, B.; Clawson, A.R.; Yu, P.K.L.; Lau, S.S. ); Poker, D.B.; White, C.W. ); Schwarz, S.A. )

    1992-03-15

    Compositional disordering of III-V compound superlattice structures has received considerable attention recently due to its potential application for photonic devices. The conventional method to induce compositional disorder in a layered structure is to implant a moderate dose of impurity ions ({similar to}10{sup 15}/cm{sup 2}) into the structure at room temperature, followed by a high-temperature annealing step (this process is referred to as IA here). Ion irradiation at room temperature alone does not cause any significant intermixing of layers. The subsequent high-temperature annealing step tends to restrict device processing flexibility. Ion mixing (IM) is capable of enhancing compositional disordering of layers at a rate which increases exponentially with the ion irradiation temperature. As a processing technique to planarize devices, ion mixing appears to be an attractive technology. In this work, we investigate compositional disordering in the AlGaAs/GaAs and the InGaAs/InP systems using ion mixing. We found that the ion mixing behavior of these two systems shows a thermally activated regime as well as an athermal regime, similar to that observed for metal-metal and metal-semiconductor systems. Ion mixing is observed to induce compositional disordering at significantly lower temperatures than that for the IA process. We have compared the two processes in terms of five parameters: (1) irradiation temperature, (2) dose dependence, (3) dose rate dependence, (4) annealing, and (5) ion dependence (including electrical effects and mass dependence). We found that the IM process is more efficient in utilizing the defects generated by ion irradiation to cause disordering. Both the physical mechanism of ion mixing and possible device implications will be discussed.

  1. Compressive failure of delamination-embedded layered structures

    NASA Astrophysics Data System (ADS)

    Wu, Li-Chun

    1997-11-01

    Various failure mechanisms involving both local and global deformation mechanisms of layered structures, consisting of differently oriented orthotropic laminae, are investigated with a large deformation finite element analysis. The aim of this study is to identify the dominant mode which leads to the structural failure under a given boundary condition and geometrical shape. It is assumed that these structures contain initial interlaminar flaws represented by embedded delaminations. Such flaws can play a significant role in defining overall structural integrity and deformation mechanisms. The energy release rate, mixed-mode stress intensity factors and phase angle are computed to quantify the crack driving force and used to measure likelihood of delamination growth in two-dimensional and three- dimensional composite structures. In the first part, two composite structures with distinguished shapes, consisting of four laminae are considered in two-dimensional analysis. One is a flat panel under compressive load and the other structure is a cylindrical shell subjected to external pressure. In the flat panel model, two buckling modes, a global and a local ligament, are observed under quasi-static loading conditions. The interaction of these two modes produces an unstable post-buckling behavior. It is found that the energy release rate exceeds experimentally estimated fracture toughness values only after buckling occurs. In the cylindrical shell study, lower critical buckling loads are observed for models with longer interlaminar delamination as in the flat panel model. However, unlike the flat panel case, the energy release rate surpasses the critical toughness well before the applied pressure reaches the buckling load of the flawed cylindrical shell. This behavior implies that a shell containing an embedded defect along an interface can fail by delamination growth and therefore has a failure load lower than its critical buckling load. Also for thicker cylindrical

  2. Nanosized Ni–Al layered double hydroxides—Structural characterization

    SciTech Connect

    Jitianu, Mihaela; Gunness, Darren C.; Aboagye, Doreen E.; Zaharescu, Maria; Jitianu, Andrei

    2013-05-15

    Highlights: ► The takovite anionic clays were obtained using the sol–gel method. ► The effect of samples’ composition on the structural and textural characteristics has been investigated. ► X-ray analysis. ► FTIR spectroscopy evidenced a disordered interlayer structure. ► FESEM and TEM analysis showed that the samples have high porosity. - Abstract: Takovite, a natural mineral with the formula Ni{sub 6}Al{sub 2}(OH){sub 6}CO{sub 3}·5H{sub 2}O belongs to the large class of layered double hydroxides (LDHs) and contains positively charged Ni(II) and Al(III) layers alternating with layers containing carbonate ions and water molecules. Mesoporous takovite-type layered double hydroxides (LDH) of the general formula [Ni{sub 1−x}Al{sub x}(OH){sub 2}]{sup x+}(CO{sub 3}{sup 2−}){sub x/2}·nH{sub 2}O with different Ni/Al molar ratios (1.9–2.8) have been successfully synthesized by the sol–gel method, followed by anionic exchange using nickel acetylacetonate and aluminum isopropylate as cation precursors. A single LDH phase and an anisotropic growth of very small crystallites (below 4 nm) have been evidenced by X-ray diffraction. The effect of samples’ composition on their structural and textural characteristics has been investigated. The BET surface area values are in the range of 100–122 m{sup 2}/g. BJH pore radius decreased with increase in the Al(III) content in the LDHs. FESEM micrographs show large aggregates of highly porous LDH particles, while TEM analysis reveals irregular agglomerates of crystallites, among which some of them displayed a developing hexagonal shape. The average particle size variation with the Al(III) content in the samples follows the same trend as the pore radius, the sample with the highest Ni/Al ratio displaying also the smallest particle size. This sample becomes even more interesting, since TEM analysis shows agglomerates with inside circular structures, feature not observed for the other Ni/Al ratios investigated.

  3. Surface-plasmons lasing in double-graphene-layer structures

    SciTech Connect

    Dubinov, A. A.; Aleshkin, V. Ya.; Ryzhii, V.; Shur, M. S.; Otsuji, T.

    2014-01-28

    We consider the concept of injection terahertz lasers based on double-graphene-layer (double-GL) structures with metal surface-plasmon waveguide and study the conditions of their operation. The laser under consideration exploits the resonant radiative transitions between GLs. This enables the double-GL laser room temperature operation and the possibility of voltage tuning of the emission spectrum. We compare the characteristics of the double-GL lasers with the metal surface-plasmon waveguides with those of such laser with the metal-metal waveguides.

  4. Electronic structure and properties of layered gallium telluride

    NASA Astrophysics Data System (ADS)

    Shenoy, U. Sandhya; Gupta, Uttam; Narang, Deepa S.; Late, Dattatray J.; Waghmare, Umesh V.; Rao, C. N. R.

    2016-05-01

    Layer-dependent electronic structure and properties of gallium monochalcogenides, GaX where X = S, Se, Te, have been investigated using first-principles calculations based on various functionals, with a motivation to assess their use in photocatalytic water splitting. Since hydrogen evolution by water splitting using visible light provides a promising way for solar energy conversion, both theoretical and experimental studies have been carried out on the photochemical hydrogen evolution by GaTe. We also present the Raman spectra of GaTe examined by both theory and experiment.

  5. MOS structures based on epitaxial HgCdTe layers

    SciTech Connect

    Antonov, V.V.; Belashov, Y.G.; Kazak, E.P.; Mezentseva, M.P.; Voitsekhovskii, A.V.

    1985-08-01

    The authors present the results of a study of the dependence of the surface photoelectromotive force at wavelengths of 3.39 and 10.6 micrometers on the field electrode for MOS structures prepared from epitaxial Hg /SUB 1-x/ Cd /SUB x/ Te layers (x=0.20-0.25). They analyze the nature of the inhomogeneities in the region near the surface of semiconducting samples prepared under various heat treatment conditions and present their findings in a series of three charts.

  6. Thickness-induced structural phase transformation of layered gallium telluride.

    PubMed

    Zhao, Q; Wang, T; Miao, Y; Ma, F; Xie, Y; Ma, X; Gu, Y; Li, J; He, J; Chen, B; Xi, S; Xu, L; Zhen, H; Yin, Z; Li, J; Ren, J; Jie, W

    2016-07-28

    The thickness-dependent electronic states and physical properties of two-dimensional materials suggest great potential applications in electronic and optoelectronic devices. However, the enhanced surface effect in ultra-thin materials might significantly influence the structural stability, as well as the device reliability. Here, we report a spontaneous phase transformation of gallium telluride (GaTe) that occurred when the bulk was exfoliated to a few layers. Transmission electron microscopy (TEM) results indicate a structural variation from a monoclinic to a hexagonal structure. Raman spectra suggest a critical thickness for the structural transformation. First-principle calculations and thermodynamic analysis show that the surface energy and the interlayer interaction compete to dominate structural stability in the thinning process. A two-stage transformation process from monoclinic (m) to tetragonal (T) and then from tetragonal to hexagonal (h) is proposed to understand the phase transformation. The results demonstrate the crucial role of interlayer interactions in the structural stability, which provides a phase engineering strategy for device applications. PMID:27198938

  7. Detection of mycoloylglycerol by thin-layer chromatography as a tool for the rapid inclusion of corynebacteria of clinical origin in the genus Corynebacterium.

    PubMed

    Yagüe, G; Segovia, M; Valero-Guillén, P L

    2000-01-28

    A chemotaxonomic study of some corynebacteria isolated from clinical samples revealed characteristic thin-layer chromatographic patterns for meso-diaminopimelic acid containing species included in the genera Corynebacterium, Dermabacter and Brevibacterium. Notably, a specific compound was consistently detected in mycolic acid containing species of the genus Corynebacterium. This compound was composed by glycerol and mycolic acids and structural analyses carried out by fast atom bombardment mass spectrometry in C. minutissimum confirmed its identification as mycoloylglycerol. The chain length of mycoloyl groups in this molecule ranged from 28 to 34 carbon atoms, being mono-, di- or triunsaturated. Detection of mycoloylglycerol by thin-layer chromatography may be thus useful for the rapid inclusion of a great variety of corynebacteria of clinical origin in the genus Corynebacterium in laboratories employing chromatographic techniques as an adjunct for the identification of these microorganisms. PMID:10778941

  8. S4 : A free electromagnetic solver for layered periodic structures

    NASA Astrophysics Data System (ADS)

    Liu, Victor; Fan, Shanhui

    2012-10-01

    We describe S4, a free implementation of the Fourier modal method (FMM), which has also been commonly referred to as rigorous coupled wave analysis (RCWA), for simulating electromagnetic propagation through 3D structures with 2D periodicity. We detail design aspects that allow S4 to be a flexible platform for these types of simulations. In particular, we highlight the ability to select different FMM formulations, user scripting, and extensibility of program capabilities for eigenmode computations. Program summary Program title: S4 Catalogue identifier: AEMO_v1_0. Program summary URL: http://cpc.cs.qub.ac.uk/summaries/AEMO_v1_0..html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: GNU General Public License, version 2 No. of lines in distributed program, including test data, etc.: 56910 No. of bytes in distributed program, including test data, etc.: 433883 Distribution format: Programming language: C, C++. Computer: Any computer with a Unix-like environment and a C++ compiler. Developed on 2.3 GHz AMD Phenom 9600. Operating system: Any Unix-like environment; developed under MinGW32 on Windows 7. Has the code been vectorized or parallelized?: Yes. Parallelized using MPI. RAM: Problem dependent (linearly proportional to number of layers and quadratic in number of Fourier components). A single layer calculation with approximately 100 Fourier components uses approximately 10 MB. Classification: 10. Electrostatics and Electromagnetics. External routines: Lua [1] and optionally exploits additional free software packages: FFTW [2], CHOLMOD [3], MPI message-passing interface [4], LAPACK and BLAS linear-algebra software [5], and Kiss FFT [6]. Nature of problem: Time-harmonic electromagnetism in layered bi-periodic structures. Solution method: The Fourier modal method (rigorous coupled wave analysis) and the scattering matrix method. Running time: Problem dependent and highly dependent on quality of the BLAS

  9. Vertical structure of aeolian turbulence in a boundary layer with sand transport

    NASA Astrophysics Data System (ADS)

    Lee, Zoe S.; Baas, Andreas C. W.

    2016-04-01

    Recently we have found that Reynolds shear stress shows a significant variability with measurement height (Lee and Baas, 2016), and so an alternative parameter for boundary layer turbulence may help to explain the relationship between wind forcing and sediment transport. We present data that were collected during a field study of boundary layer turbulence conducted on a North Atlantic beach. High-frequency (50 Hz) 3D wind velocity measurements were collected using ultrasonic anemometry at thirteen different measurement heights in a tight vertical array between 0.11 and 1.62 metres above the surface. Thanks to the high density installation of sensors a detailed analysis of the boundary layer flow can be conducted using methods more typically used in studies where data is only available from one or just a few measurement heights. We use quadrant analysis to explore the vertical structure of turbulence and track the changes in quadrant signatures with measurement elevation and over time. Results of quadrant analysis, at the 'raw' 50 Hz timescale, demonstrates the tendency for event clustering across all four quadrants, which implies that at-a-point quadrant events are part of larger-scale turbulent structures. Using an HSV colour model, applied to the quadrant analysis data and plotted in series, we create colour maps of turbulence, which can provide a clear visualisation of the clustering of event activity at each height and illustrate the shape of the larger coherent flow structures that are present within the boundary layer. By including a saturation component to the colour model, the most significant stress producing sections of the data are emphasised. This results in a 'banded' colour map, which relates to clustering of quadrant I (Outward Interaction) and quadrant IV (Sweep) activity, separate from clustering of quadrant II (Burst) and quadrant III (Inward Interaction). Both 'sweep-type' and 'burst-type' sequences are shown to have a diagonal structure

  10. Structure change, layer sliding, and metallization in high-pressure MoS2

    NASA Astrophysics Data System (ADS)

    Tosatti, Erio; Hromadova, Liliana; Martonak, Roman

    2013-03-01

    Based on ab initio calculations and metadynamics simulations, we predict that 2H-MoS2, a layered insulator, will metallize under pressures in excess of 20-30 GPa. In the same pressure range, simulations and enthalpy optimization predict a structural transition. Reminiscent of this material's frictional properties, free mutual sliding of layers takes place at this transition, where the original 2Hc stacking changes to a 2Ha stacking typical of 2H-NbSe2, a transformation which explains for the first time previously mysterious X-ray diffraction data. Phonon and electron phonon calculations suggest that metallic pristine MoS2 will require ultrahigh pressures in order to develop superconductivity. Supported by EU-Japan Project LEMSUPER, by a SNF Sinergia Project, and by the Slovak Research and Development Agency

  11. Layered manganites : magnetic structure at extreme doping levels.

    SciTech Connect

    Mitchell, J. F.

    1998-09-11

    We report powder neutron diffraction results on the crystal and magnetic structures of the bilayer Ruddlesden-Popper phase Sr{sub 3}Mn{sub 2}O{sub 7{minus}{delta}} ({delta} = 0.0, 0.45) and correlate these structures with their magnetic and transport properties. The {delta} = 0.45 compound contains a large number of oxygen vacancies that are disordered in the MnO{sub 2} planes. As a result of this disordered vacancy structure, Sr{sub 3}Mn{sub 2}O{sub 6.55} is a nonmagnetic insulator. Sr{sub 3}Mn{sub 2}O{sub 7.0} ({delta} = 0) is an antiferromagnetic insulator whose magnetic structure is related to that of the SrMnO{sub 3} perovskite. Comparison of this end-member compound to its doped congeners in the La{sub 2{minus}2x}Sr{sub 1+2x}Mn{sub 2}O{sub 7} series highlights the extreme sensitivity of magnetic structure to dopant concentration in these layered materials.

  12. Perpendicular magnetic anisotropy in FePt/AlN layered structure

    NASA Astrophysics Data System (ADS)

    Zhang, Cong; Sannomiya, Takumi; Muraishi, Shinji; Shi, Ji; Nakamura, Yoshio

    2014-09-01

    FePt/AlN layered structures were deposited onto fused quartz substrate by magnetron sputtering method and found to show in-plane anisotropy. However, annealing of the films leads to a transition of magnetic anisotropy from in-plane to perpendicular direction, and the perpendicular anisotropy gets stronger as the annealing temperature increases. Structural analysis shows that the FePt and AlN layers are textured with (111) and (002) orientations, respectively, along the film normal, and no ordering transformation is found for FePt alloy. To study the origin of the developed anisotropy, stress condition was analyzed with an equal biaxial stress model using X-ray diffraction 2 θ- ω scan method and interface quality was evaluated by X-ray reflectivity measurement and transmission electron microscopy observation. The results reveal that perpendicular magnetic anisotropy of the annealed FePt/AlN layered structure can be attributed to the enhanced interface anisotropy, which is due to flattening of the interfaces through annealing.

  13. Model-based damage evaluation of layered CFRP structures

    NASA Astrophysics Data System (ADS)

    Munoz, Rafael; Bochud, Nicolas; Rus, Guillermo; Peralta, Laura; Melchor, Juan; Chiachío, Juan; Chiachío, Manuel; Bond, Leonard J.

    2015-03-01

    An ultrasonic evaluation technique for damage identification of layered CFRP structures is presented. This approach relies on a model-based estimation procedure that combines experimental data and simulation of ultrasonic damage-propagation interactions. The CFPR structure, a [0/90]4s lay-up, has been tested in an immersion through transmission experiment, where a scan has been performed on a damaged specimen. Most ultrasonic techniques in industrial practice consider only a few features of the received signals, namely, time of flight, amplitude, attenuation, frequency contents, and so forth. In this case, once signals are captured, an algorithm is used to reconstruct the complete signal waveform and extract the unknown damage parameters by means of modeling procedures. A linear version of the data processing has been performed, where only Young modulus has been monitored and, in a second nonlinear version, the first order nonlinear coefficient β was incorporated to test the possibility of detection of early damage. The aforementioned physical simulation models are solved by the Transfer Matrix formalism, which has been extended from linear to nonlinear harmonic generation technique. The damage parameter search strategy is based on minimizing the mismatch between the captured and simulated signals in the time domain in an automated way using Genetic Algorithms. Processing all scanned locations, a C-scan of the parameter of each layer can be reconstructed, obtaining the information describing the state of each layer and each interface. Damage can be located and quantified in terms of changes in the selected parameter with a measurable extension. In the case of the nonlinear coefficient of first order, evidence of higher sensitivity to damage than imaging the linearly estimated Young Modulus is provided.

  14. Wintertime Boundary Layer Structure in the Grand Canyon.

    NASA Astrophysics Data System (ADS)

    Whiteman, C. David; Zhong, Shiyuan; Bian, Xindi

    1999-08-01

    Wintertime temperature profiles in the Grand Canyon exhibit a neutral to isothermal stratification during both daytime and nighttime, with only rare instances of actual temperature inversions. The canyon warms during daytime and cools during nighttime more or less uniformly through the canyon's entire depth. This weak stability and temperature structure evolution differ from other Rocky Mountain valleys, which develop strong nocturnal inversions and exhibit convective and stable boundary layers that grow upward from the valley floor. Mechanisms that may be responsible for the different behavior of the Grand Canyon are discussed, including the possibility that the canyon atmosphere is frequently mixed to near-neutral stratification when cold air drains into the top of the canyon from the nearby snow-covered Kaibab Plateau. Another feature of canyon temperature profiles is the sharp inversions that often form near the canyon rims. These are generally produced when warm air is advected over the canyon in advance of passing synoptic-scale ridges.Wintertime winds in the main canyon are not classical diurnal along-valley wind systems. Rather, they are driven along the canyon axis by the horizontal synoptic-scale pressure gradient that is superimposed along the canyon's axis by passing synoptic-scale weather disturbances. They may thus bring winds into the canyon from either end at any time of day.The implications of the observed canyon boundary layer structure for air pollution dispersion are discussed.

  15. Emission enhancement of microlens on OLED with different layer structures

    NASA Astrophysics Data System (ADS)

    Ho, Yu-Hsuan; Fang, Jheng-Hao; Lee, Jiun-Haw; Wei, Mao-Kuo; Lin, Hoang-Yan

    2008-04-01

    Low out-coupling efficiency is one of the most critical problems in organic light-emitting device (OLED) application. Only 20~30% of the emitting light from OLED can propagate into air [1]. Therefore, several methods have been utilized to extract more light from device. Here, we use the microlens array attached on device to couple out wave-guiding mode in the glass substrate. We found that, the luminous enhancement behavior has great dependence on OLED structure. When light emitted in the layered structure of OLED, the wide angle interference and multi-beam interference occurred, and far-field emission profile change simultaneously. For different emission profile, microlens array film shows a different enhancement behavior. For a conventional OLED device, the most critical interference will occur at the electron transport layer (ETL). We fabricated a series of OLEDs with different ETL thicknesses to investigate the influence to the optical properties, such as spectrum, CIE coordinate change, and emission profile at different view angles. By controlling the emission dipole position, we investigate the relation between the emission profile and the efficiency enhancement by microlens array attachment. When increasing the ETL thicknesses from 30nm to 150nm, the weaker micro cavity effect results in broader spectrum and more light extracted. In these devices, the luminous enhancement varies from 25.1% to 51.3%.

  16. Radial transmission line analysis of multi-layer structures

    SciTech Connect

    Hahn, H.; Hammons, L.

    2011-03-28

    The analysis of multi-layer beam tubes is a standard problem and involves axially propagating waves. This treatment is ill suited to a short multi-layer structure such as the present example of a ferrite covered ceramic break in the beam tube at the ERL photo-cathode electron gun. This paper demonstrates that such structure can better be treated by radial wave propagation. The theoretical method is presented and numerical results are compared with measured network analyser data and Microwave Studio generated simulations. The results confirm the concept of radial transmission lines as a valid analytical method. An Energy Recovery Linac (ERL) is being constructed at this laboratory for the purpose of research towards an envisioned Electron Ion Collider. One of the pertinent topics is damping of Higher Order Modes (HOM). In this ERL, the damping is provided by ferrite absorbers in the beam tube. A modified version thereof, a ceramic break surrounded by ferrite, is planed for the superconducting electron gun. The damper here is located at room temperature just outside of the gun. If used in a cavity chain, the ceramic break is in the vacuum tube at helium temperature whereas the ferrite is moved into the cryostat insulating vacuum allowing higher temperatures. The general properties of the ferrite HOM dampers have been published but are more detailed in this paper.

  17. Structural distortions in few-layer graphene creases.

    PubMed

    Robertson, Alex W; Bachmatiuk, Alicja; Wu, Yimin A; Schäffel, Franziska; Büchner, Bernd; Rümmeli, Mark H; Warner, Jamie H

    2011-12-27

    Folds and creases are frequently found in graphene grown by chemical vapor deposition (CVD), due to the differing thermal expansion coefficients of graphene from the growth catalyst and the flexibility of the sheet during transfer from the catalyst. The structure of a few-layer graphene (FLG) crease is examined by aberration-corrected high-resolution transmission electron microscopy (AC-HRTEM). A study of 2D fast Fourier transforms (FFTs) taken about the region of the crease allowed for the crystal stacking structure of the system to be elucidated. It was found that strain-induced stacking faults were created in the AB Bernal-stacked FLG bulk around the region proximal to the crease termination; this is of interest as the stacking order of FLG is known to have an effect on its electronic properties and thus should be considered when transferring CVD-grown FLG to alternate substrates for electronic device fabrication. The FFTs, along with analysis of the real space images, were used to determine the configuration of the layers in the crease itself and were corroborated by multislice atomistic TEM simulations. The termination of the crease part way through the FLG sheet is also examined and is found to show strong out of plane distortions in the area about it. PMID:22122696

  18. Composite structure of plumes in stratus-topped boundary layers

    SciTech Connect

    Moeng, C.H. ); Schumann, U. )

    1991-10-15

    Knowledge of convective plumes within the clear convective boundary layer (CBL) is quite advanced owing to direct measurements, tank experiments, and large-eddy simulation studies. As a result, modeling of the CBL is relatively successful. Progress for the stratus-topped boundary layer (STBL), however, is slow. This study compares the plume structure of the surface-heated CBL with that of the cloud-top-cooled STBL in the hope of extending knowledge of the CBL to the STBL. A conditional sampling technique is applied to the STBL flow fields that are generated through large-eddy simulations, so that the structures of typical updrafts and downdrafts may be derived. For the purpose of comparing the surface-heated CBL and the cloud-top-cooled STBL, an idealized STBL, the compensating updrafts are nearly as strong as the top-cooling-generated downdrafts, and they contribute a significant amount to the heat, moisture, and momentum transports. This differs very much from the CBL, where the compensating downdrafts are much weaker than the surface-heating-generated updrafts and contribute much less to the transports. The mechanism that results in such an asymmetry between the CBL and STBL is examined, and suggestions on how the asymmetry affects the entrainment process are made. 25 refs., 26 figs.

  19. Structure of the upper mantle boundaries in North Eurasia and their origin

    NASA Astrophysics Data System (ADS)

    Pavlenkova, Ninel

    2016-04-01

    confirms such origin of the lower velocity layers and seismic boundaries: in many regions they are characterized by higher electrical conductivity. In the Siberian craton the most xenoliths come from the depths of these boundaries. That characterizes these boundaries as high strain zones. These xenoliths have often indications of film melting. At the boundaries N and L the clear changes are observed in the lithosphere mechanical properties. In many regions above the N boundary the lithosphere has complex block structure, which disappears at the larger depth. That indicates the lithosphere to be more plastic at the depth over 100 km and cannot preserve its own inhomogeneity. The change of the rheology, which may be interpreted as the lithosphere bottom, is visible beneath the L boundary where the Q factor and the velocity-depth gradient decrease.

  20. Self-Healing Textile: Enzyme Encapsulated Layer-by-Layer Structural Proteins.

    PubMed

    Gaddes, David; Jung, Huihun; Pena-Francesch, Abdon; Dion, Genevieve; Tadigadapa, Srinivas; Dressick, Walter J; Demirel, Melik C

    2016-08-10

    Self-healing materials, which enable an autonomous repair response to damage, are highly desirable for the long-term reliability of woven or nonwoven textiles. Polyelectrolyte layer-by-layer (LbL) films are of considerable interest as self-healing coatings due to the mobility of the components comprising the film. In this work mechanically stable self-healing films were fabricated through construction of a polyelectrolyte LbL film containing squid ring teeth (SRT) proteins. SRTs are structural proteins with unique self-healing properties and high elastic modulus in both dry and wet conditions (>2 GPa) due to their semicrystalline architecture. We demonstrate LbL construction of multilayers containing native and recombinant SRT proteins capable of self-healing defects. Additionally, we show these films are capable of utilizing functional biomolecules by incorporating an enzyme into the SRT multilayer. Urease was chosen as a model enzyme of interest to test its activity via fluorescence assay. Successful construction of the SRT films demonstrates the use of mechanically stable self-healing coatings, which can incorporate biomolecules for more complex protective functionalities for advanced functional fabrics. PMID:27419265

  1. The Electronic Structure of Single-Layer Graphene

    NASA Astrophysics Data System (ADS)

    Siegel, David Alan

    Single-layer graphene has been widely researched in recent years due to its perceived technological applicability and its scientific importance as a unique model system with relativistic Dirac Fermions. Because of its unique geometric and electronic structure, the properties of graphene can be tuned or manipulated in several ways. This tunability is important for technological applications in its own right, and it also allows us to study the fundamental properties of Dirac Fermions, including unique many-body interactions and the nature of the quasiparticles at half-filling. This thesis is a detailed examination of the electronic and structural properties of graphene, studied with angle-resolved photoemission spectroscopy (ARPES) and other surface science techniques like low-energy electron microscopy and diffraction. This thesis is organized as follows. Chapter 1 gives an introduction to the electronic and structural properties of single-layer graphene. It provides a brief historical overview of major theoretical and experimental milestones and sets the stage for the important theoretical and experimental questions that this thesis addresses. Chapters 2 and 3 describe the experimental setup. Chapter 2 discusses the experimental techniques used in this thesis with particular focus on the mechanics of ARPES. Chapter 3 discusses the different graphene growth techniques that were used to create our sample with particular focus on our characterization of epitaxial graphene on SiC(0001). Chapters 4 and 5 form the meat of this thesis: they provide a thorough discussion of the electronic properties of graphene as studied by ARPES. Chapter 4 describes how various perturbations can result in the manipulation of the bare electronic band structure, including the deposition of atomic or molecular species on top of an epitaxial graphene sheet as well as the interactions between graphene and its substrate. Chapter 5 describes the many-body physics in single-layer graphene. It

  2. Double-Layer ULVZ Shear Velocity Structure Imaged With Stacked ScS Data

    NASA Astrophysics Data System (ADS)

    Avants, M.; Lay, T.; Garnero, E.

    2005-12-01

    The ultra-low velocity zone (ULVZ) has been imaged as a thin (5-40 km thick) layer just above the core-mantle boundary (CMB), with P and S velocities reduced by up to 10 and 30%, respectively. Accurate characterization of the ULVZ is important, as it may relate to, for example, the role of the lowermost mantle in Earth's evolution, mantle and outer core convection, the geodynamo, and heat flux into the mantle. A direct measurement of S velocity in the ULVZ, independent of the P-wave velocity, is needed to better constrain ULVZ properties. We establish tangential component ScS data as a new probe of ULVZ shear velocity properties. Lowermost mantle structure beneath the central Pacific is studied using data from 38 deep focus Tonga-Fiji earthquakes, recorded by dense broadband seismic networks in western North America. Our data set consists of 442 instrument-deconvolved displacement seismograms, which are additionally deconvolved by average source-time functions (source wavelets) constructed for each event, in order to equalize the signals and to extend the signal bandwidth to high frequencies. The resulting traces are used in a double-beam stacking approach to enhance the signal-to-noise ratio of any coherent precursory reflections of the wide-angle transverse component ScS data, which should be detectable if ULVZ structure is present beneath our central Pacific study region. Our stacks reveal two distinct ScS precursors, which indicate a double layer ULVZ structure in this region. Both layers show strong lateral variations in shear velocity reduction (dVs) and thickness. The deeper ULVZ layer is well modeled by dVs drops varying from 3.3-7.4% (relative to PREM) with a thickness range of 24-30 km. The overlying layer has dVs reductions from 0.8-2.0% (relative to PREM), and 60-86 km thickness. Thus the imaged 2-layered ULVZ has dVs reductions far milder than previous studies (10-30%), which have argued for a partial melt origin to the ULVZ. Finer subdivisions of data

  3. Stratigraphy, Structure, and Origin; A Geophysical Survey of the Mendeleev Ridge

    NASA Astrophysics Data System (ADS)

    Dove, D.; Coakley, B.; Hopper, J.

    2006-12-01

    The Mendeleev Ridge is a broad, aseismic ridge that extends from the Siberian Shelf into the central Arctic Ocean. While it is continuous with the Alpha Ridge and is inferred to be an oceanic plateau, it may have had a distinct and separate history. The origin of the Mendeleev ridge has only rarely been visited and, as a result, understanding the history of this region has largely been based on the presumption of a common origin for both features. In late summer 2005, a geophysical survey was conducted from USCGC Healy over the Mendeleev Ridge as part of a trans-arctic crossing. During this survey ~730 km of seismic reflection data was recovered over the ridge along with co-registered gravity and bathymetry data and seismic refraction profiles. The seismic source was two 250 cu in G-guns. The streamer length was limited by ice conditions to 300 meters. Wear and tear caused by towing the streamer through the ice pack eliminated hydrophones, so the number of active channels ranged from 24 to as few as 11. The seismic reflection data requires significant trace editing to eliminate random electrical noise and frequency-wave number filtering to eliminate low velocity noise caused by the streamer traveling through heavy ice. After trace editing the data are stacked and migrated with constant water velocity. Stacking velocities are used as input into initial ray tracing models. Derived boundary velocities from ray tracing models will be reapplied to the migration of reflection data and are converted through empirical relationships into densities, and used as input into gravity models. Brute stacked reflection images of the Mendeleev Ridge reveal pervasive extensional faulting of the basement and lower sediment layers, and a continuous, undeformed pelagic sediment layer mantling the ridge, indicative of recent tectonic inactivity. The age of the unconformity underlying this layer should date the end of significant deformation of the Alpha and Mendeleev Ridges. Consistency

  4. Growth of high quality GaN layer on carbon nanotube-graphene network structure as intermediate layer

    NASA Astrophysics Data System (ADS)

    Seo, Taeo Hoon; Park, Ah Hyun; Park, Sungchan; Kim, Myung Jong; Suh, Eun-Kyung

    2015-03-01

    In general, high-quality GaN layers are synthesized on low-temperature (LT) GaN buffer layer on a single crystal sapphire substrate. However, large differences in fundamental properties such as lattice constants and thermal expansion coefficients between GaN layer and sapphire substrate generate high density of threading dislocation (TD) that leads to deterioration of optical and structural properties. Graphene has been attracting much attention due to its excellent physical properties However, direct epitaxial growth of GaN film onto graphene layer on substrates is not easily accessible due to the lack of chemical reactivity on graphene which consisted of C-C bond of sp2 hexagonally arranged carbon atoms with no dangling bonds. In this work, an intermediate layer for the GaN growth on sapphire substrate was constructed by inserting carbon nanotubes and graphene hybrid structure (CGH) Optical and structural properties of GaN layer grown on CGH were compared with those of GaN layer directly grown on sapphire CNTs act as nucleation sites and play a crucial role in the growth of single crystal high-quality GaN on graphene layer. Also, graphene film acts as a mask for epitaxial lateral overgrowth of GaN layer, which can effectively reduce TD density. A grant from the Korea Institute of Science and Technology (KIST) institutional program.

  5. Do The Concentrations Of Platinum Group Elements In The Younger Dryas Black Layer Really Support An Extraterrestrial Origin?

    NASA Astrophysics Data System (ADS)

    Claeys, P.; Paquay, F.; Goderis, S.; Vanhaecke, F.

    2008-12-01

    An enigmatic carbon-rich black layer, of possible worldwide occurrence, is interpreted to indicate an extraterrestrial impact around 12.9 ka, a period coeval with the Younger Dryas (YD) environmental changes (Firestone et al. 2007, PNAS 104). This interpretation is based on the possible identification of a series of markers postulated to be of impact origin, such as magnetic grains and microspherules, charcoal, soot, C- spherules, nanodiamonds, fullerenes with extraterrestrial He and elevated concentrations of Ir. Among these markers, only the elevated Ir concentration is a non-ambiguous impact indicator. In early 2007, one of us (PC) measured the concentration of platinum group elements (including Ir) in 4 samples of this black layer. Allen West provided the samples along with their Ir concentrations. The samples originated from Howard Bay, NC (level HB-11D2) and Blackwater Draw, NM (levels BW-DT, D/C and BW-B/A), and were supposed to contain 15 ng/g Ir (<150 micron magnetic fraction), 2.0 ng/g Ir (bulk sediment), 2.25 ng/g Ir (bulk sediment) and <0.1 ng/g Ir (bulk sediment) respectively. In Table 1 of Firestone et al. (2007) the Blackwater Draw sample contains 2.3 ng/g Ir, and the separated magnetic fraction rises up 24 ng/g. The obtained results showed that none of the 4 samples yielded PGE concentrations above 0.5 ng/g. Considering the attention the claim of a possible YD impact has generated in the last year, we are currently reanalyzing these 4 samples of the black layer using high precision NiS fire-assay preconcentration combined with ICP-MS analyses. On proven crater melt rocks or impact layers, the quantitation limits reach: 0.06 ng/g Ru, 0.01 ng/g Rh, 0.14 ng/g Pd, 0.06 ng/g Ir, and 0.1 ng/g Pt, far below the Ir values claimed by Firestone et al. (2007). In addition, these 4 samples are being analyzed for Os isotopes, known to be most sensitive for the detection of minute amounts of extraterrestrial components (%<%%<%0.05 wt%) in impact layers. The

  6. Layered Double Hydroxides: Proposal of a One-Layer Cation-Ordered Structure Model of Monoclinic Symmetry.

    PubMed

    Jayanthi, K; Nagendran, Supreeth; Kamath, P Vishnu

    2015-09-01

    Layered double hydroxides are obtained by partial isomorphous substitution of divalent metal ions by trivalent metal ions in the structure of mineral brucite, Mg(OH)2. The widely reported three-layer polytype of rhombohedral symmetry, designated as polytype 3R1, is actually a one-layer polytype of monoclinic symmetry (space group C2/m, a = 5.401 Å, b = 9.355 Å, c = 11.02 Å, β = 98.89°). This structure has a cation-ordered metal hydroxide layer defined by a supercell a = √3 × a0; b = 3 × a0 (a0 = cell parameter of the cation-disordered rhombohedral cell). Successive layers are translated by (1/3, 0, 1) relative to one another. When successive metal hydroxide layers are translated by (2/3, 0, 1) relative to one another, the resultant crystal, also of monoclinic symmetry, generates a powder pattern corresponding to the polytype hitherto designated as 3R2. This structure model not only removes all the anomalies intrinsic to the widely accepted cation-disordered structure but also abides by Pauling's rule that forbids trivalent cations from occupying neighboring sites and suggests that it is unnecessary to invoke rhombohedral symmetry when the metal hydroxide layer is cation ordered. These results have profound implications for the correct description of polytypism in this family of layered compounds. PMID:26267263

  7. Fabrication of luminescent porous silicon with stain etches and evidence that luminescence originates in amorphous layers

    NASA Technical Reports Server (NTRS)

    Fathauer, R. W.; George, T.; Ksendzov, A.; Lin, T. L.; Pike, W. T.; Vasquez, R. P.; Wu, Z.-C.

    1992-01-01

    Simple immersion of Si in stain etches of HF:HNO3:H2O or NaNO2 in aqueous HF was used to produce films exhibiting luminescence in the visible similar to that of anodically-etched porous Si. All of the luminescent samples consist of amorphous porous Si in at least the near surface region. No evidence was found for small crystalline regions within these amorphous layers.

  8. Origin of photogenerated carrier recombination at the metal-active layer interface in polymer solar cells.

    PubMed

    Kumar, Mukesh; Dubey, Ashish; Reza, Khan Mamun; Adhikari, Nirmal; Qiao, Qiquan; Bommisetty, Venkat

    2015-11-01

    The role of the metal-active layer interface in photogenerated recombination has been investigated using nanoscale current sensing atomic force microscopy (CS-AFM) and intensity modulated photocurrent spectroscopy (IMPS) in as-deposited, pre-annealed and post-annealed bulk heterojunction (BHJ) solar cells. Aluminum (Al) confined post-annealed BHJ solar cells exhibited a significantly improved device efficiency compared to pre-annealed BHJ solar cells having similar photocarrier harvesting ability in the active layer. The nanoscale topography and CS-AFM results indicate a uniform PCBM rich phase at the metal-active layer interface in the post-annealed cells, but PCBM segregation in the pre-annealed cells. These two different annealing processes showed different carrier dynamics revealed using IMPS under various light intensities. The IMPS results suggest reduced photo generated carrier recombination in uniform PCBM rich post-annealed BHJ solar cells. This study reveals the importance of the metal-bend interface in BHJ solar cells in order to obtain efficient charge carrier extraction for high efficiency. PMID:26431263

  9. Origin and reduction of impurities at GaAs epitaxial layer-substrate interfaces

    NASA Astrophysics Data System (ADS)

    Kanber, H.; Yang, H. T.; Zielinski, T.; Whelan, J. M.

    1988-09-01

    Surface cleaning techniques used for semi-insulating GaAs substrates prior to epitaxial growth can have an important and sometimes detrimental effect on the quality and characteristics of epitaxial layers that are grown on them. We observe that a HF rinse followed by a 5:1:1 H 2SO 4:H 2O 2:H 2O etch and H 2O rinse drastically reduced the maximum concentrations and total amount of both SIMS detected S and Si for MOCVD grown GaAs undoped epitaxial layers. Subsequent final HCl and H 2O reduced the S interfacial residues to the SIMS detection limit. Total amounts of residual Si are estimated to be equivalent to 10 -2 to 10 -3 monolayers. Residual S is less. Alternately the S residue can be comparable reduced by a HF rinse followed by a NH 4OH:H 2O 2:H 2O etch and H 2O rinse. Hot aqueous HCl removes S but not Si residues. The Si residue is not electrically active and most likely exists as islands of SiO 2. The relative significance of the impurity residues is most pronounced for halide VPE, smaller for MBE and least for MOCVD grown GaAs epitaxial layers.

  10. Geophysical characterization of two circular structures at Bajada del Diablo (Patagonia, Argentina): Indication of impact origin

    NASA Astrophysics Data System (ADS)

    Prezzi, Claudia B.; Orgeira, María Julia; Acevedo, Rogelio D.; Ponce, Juan Federico; Martinez, Oscar; Rabassa, Jorge O.; Corbella, Hugo; Vásquez, Carlos; González-Guillot, Mauricio; Subías, Ignacio

    2012-02-01

    An impact origin has been proposed for the circular structures found in Bajada del Diablo, Patagonia, Argentina. Taking into account its extension and the number of impact structures, Bajada del Diablo would be the largest meteoritic impact areas known on Earth, being an extremely interesting area for the research of impact events and processes. Moreover, the global distribution of known impact structures shows a surprising asymmetry. Particularly, South America has only seven described areas. It is evident that this situation is an artifact, highlighting the importance of intensifying the research in the least studied areas such as Argentina. Circular structures in Bajada del Diablo have been identified on two rock types: the Quiñelaf eruptive complex and Pampa Sastre Formation. In the first case, circular structures are placed in olivine basalts. On the other hand, Pampa Sastre Formation (late Pliocene/early Pleistocene) corresponds to conglomerate layers with basalt clasts boulder and block in size in a coarse sandy matrix. With the aim of further the investigation of the proposed impact origin for these circular structures, we carried out detailed topographic, magnetic and electromagnetic ground surveys in two circular structures ("8" and "A") found in Pampa Sastre conglomerates. Both circular structures are simple, bowl-shaped with rim diameters of 300 m and maximum depths of 10 m. They have been partially filled in by debris flows from the rims and wind-blown sands. Two preliminary magnetic profiles have also been carried out in circular structure "G" found in Quiñelaf basalts. The magnetic anomalies show a circular pattern with a slightly negative and relatively flat signal in the circular structures' bases. Furthermore in the circular structures' rims, high-amplitude, conspicuous and localized (short wavelength) anomalies are observed. Such large amplitude and short wavelength anomalies are not detected outside the circular structures. For all used

  11. Stratigraphy, mineralogy, and origin of layered deposits inside Terby crater, Mars

    NASA Astrophysics Data System (ADS)

    Ansan, V.; Loizeau, D.; Mangold, N.; Le Mouélic, S.; Carter, J.; Poulet, F.; Dromart, G.; Lucas, A.; Bibring, J.-P.; Gendrin, A.; Gondet, B.; Langevin, Y.; Masson, Ph.; Murchie, S.; Mustard, J. F.; Neukum, G.

    2011-01-01

    The 174 km diameter Terby impact crater (28.0°S-74.1°E) located on the northern rim of the Hellas basin displays anomalous inner morphology, including a flat floor and light-toned layered deposits. An analysis of these deposits was performed using multiple datasets from Mars Global Surveyor, Mars Odyssey, Mars Express and Mars Reconnaissance Orbiter missions, with visible images for interpretation, near-infrared data for mineralogical mapping, and topography for geometry. The geometry of layered deposits was consistent with that of sediments that settled mainly in a sub-aqueous environment, during the Noachian period as determined by crater counts. To the north, the thickest sediments displayed sequences for fan deltas, as identified by 100 m to 1 km long clinoforms, as defined by horizontal beds passing to foreset beds dipping by 6-10° toward the center of the Terby crater. The identification of distinct sub-aqueous fan sequences, separated by unconformities and local wedges, showed the accumulation of sediments from prograding/onlapping depositional sequences, due to lake level and sediment supply variations. The mineralogy of several layers with hydrated minerals, including Fe/Mg phyllosilicates, supports this type of sedimentary environment. The volume of fan sediments was estimated as >5000 km 3 (a large amount considering classical martian fan deltas such as Eberswalde (6 km 3)) and requires sustained liquid water activity. Such a large sedimentary deposition in Terby crater is characteristic of the Noachian/Phyllosian period during which the environment favored the formation of phyllosilicates. The latter were detected by spectral data in the layered deposits of Terby crater in three distinct layer sequences. During the Hesperian period, the sediments experienced strong erosion, possibly enhanced by more acidic conditions, forming the current morphology with three mesas and closed depressions. Small fluvial valleys and alluvial fans formed subsequently

  12. Aliphatic structure of humic acids; a clue to their origin

    USGS Publications Warehouse

    Hatcher, P.G.; Maciel, G.E.; Dennis, L.W.

    1981-01-01

    Nuclear magnetic resonance spectra (both 1H and 13C) of humic acids from diverse depositional environments indicate the presence of aromatic chemical structures, most likely derived from lignin of vascular plants, and complex, paraffinic structures, most likely derived from algal or microbial sources. The latter components account for a major fraction of humic acid structures in both terrestrial and aquatic environments, suggesting that algae or microbes play a large role in humification of organic remains from both systems. ?? 1981.

  13. Modified silicas with different structure of grafted methylphenylsiloxane layer.

    PubMed

    Bolbukh, Yuliia; Terpiłowski, Konrad; Kozakevych, Roman; Sternik, Dariusz; Deryło-Marczewska, Anna; Tertykh, Valentin

    2016-12-01

    The method of a chemical assembly of the surface polymeric layer with high contents of the modifying agent was developed. Powders of nanodispersed silica with chemisorbed polymethylphenylsiloxane (PMPS) were synthesized by solvent-free chemical assembly technique with a dimethyl carbonate (DMC) as scission agent. Samples were characterized using FTIR spectroscopy, transmission electron microscopy (TEM), atomic force microscopy (AFM), and elemental analysis (CHN analysis). Coating microstructure, morphology, and hydrophilic-hydrophobic properties of nanoparticles were estimated. The results indicate a significant effect of the PMPS/DMC ratio at each modification stage on hydrophobic properties of modified silicas. Modification with a similar composition of the PMPS/DMC mixture, even with different polymer amount at each stage, provides the worst hydrophobicity. Results suggest that the highest hydrophobicity (contact angle θ = 135°-140°) is achieved in the case when silica modified with the PMPS/DMC mixture using multistage approach that providing a formation of the monomolecular layer of polysiloxane at the first modification step. The characteristics of surface structure were interpreted in terms of density of polymer-silica bonds at the interfaces that, usually, are reduced for modified surfaces, in a coupling with conformation model that accented the shape of chains (arch- and console-like) adsorbed on solid surfaces. PMID:27295258

  14. Modified silicas with different structure of grafted methylphenylsiloxane layer

    NASA Astrophysics Data System (ADS)

    Bolbukh, Yuliia; Terpiłowski, Konrad; Kozakevych, Roman; Sternik, Dariusz; Deryło-Marczewska, Anna; Tertykh, Valentin

    2016-06-01

    The method of a chemical assembly of the surface polymeric layer with high contents of the modifying agent was developed. Powders of nanodispersed silica with chemisorbed polymethylphenylsiloxane (PMPS) were synthesized by solvent-free chemical assembly technique with a dimethyl carbonate (DMC) as scission agent. Samples were characterized using FTIR spectroscopy, transmission electron microscopy (TEM), atomic force microscopy (AFM), and elemental analysis (CHN analysis). Coating microstructure, morphology, and hydrophilic-hydrophobic properties of nanoparticles were estimated. The results indicate a significant effect of the PMPS/DMC ratio at each modification stage on hydrophobic properties of modified silicas. Modification with a similar composition of the PMPS/DMC mixture, even with different polymer amount at each stage, provides the worst hydrophobicity. Results suggest that the highest hydrophobicity (contact angle θ = 135°-140°) is achieved in the case when silica modified with the PMPS/DMC mixture using multistage approach that providing a formation of the monomolecular layer of polysiloxane at the first modification step. The characteristics of surface structure were interpreted in terms of density of polymer-silica bonds at the interfaces that, usually, are reduced for modified surfaces, in a coupling with conformation model that accented the shape of chains (arch- and console-like) adsorbed on solid surfaces.

  15. Bose-Einstein condensation in low dimensional layered structures

    NASA Astrophysics Data System (ADS)

    Salas, Patricia; Solis, M. A.

    2008-03-01

    Bose-Einstein condensation critical temperature, among other thermodynamic properties are reported for an ideal boson gas inside layered structures created by trapping potential of the Kronig-Penney type. We start with a big box where we introduce the Kronig-Penney potential in three directions to get a honey comb of cubes of side a size and walls of variable penetrability (P=mV0ab/^2), with bosons instead of bees. We are able to reduce the dimensions of the cubes to simulate bosons inside quantum dots. The critical temperature, starting from that of an ideal boson gas inside the big box, decreases as the small cube wall impenetrability increases arriving to a tiny but different from zero when the penetrability is zero (P-->∞). We also calculate the internal energy and the specific heat, and compare them to the ones obtained for the case of the same Kronig-Penney potential in one direction (simulating layers), and two directions (nanotubes).

  16. Investigation of turbulent boundary layer structures using Tomographic PIV

    NASA Astrophysics Data System (ADS)

    Saikrishnan, Neelakantan; Longmire, Ellen; Wieneke, Bernd

    2008-11-01

    Tomographic particle image velocimetry (TPIV) data were acquired in the logarithmic region of a zero pressure gradient turbulent boundary layer flow at friction Reynolds number Reτ = 1160. Experiments were conducted in a suction type wind tunnel seeded with olive oil particles of diameter ˜ 1μm. The volume of interest was illuminated by two Nd:YAG laser beams expanded with appropriate optics into sheets of 8mm thickness in the wall-normal direction (z). Images were acquired by four 2k x 2k pixel cameras, and correlation of reconstructed fields provided the full velocity gradient tensor in a volume of 0.7δ x 0.7δ x 0.07δ, which resolved the region z^+ = 70-150 in the log layer. Various vortex identification techniques, such as Galilean decomposition and iso-surfaces of two- and three-dimensional swirl, were utilized to visualize and analyze the eddy structures present in instantaneous fields. The results of the present study will be compared to results from earlier experimental studies that relied on planar PIV data only to identify vortices and vortex packets as well as from a direct numerical simulation of fully developed channel flow at comparable Reτ.

  17. Contact damage and fracture of ceramic layer structures

    NASA Astrophysics Data System (ADS)

    Wuttiphan, Sataporn

    Contact damage and fracture of ceramic layer structures are studied in this thesis. Hertzian indentation is used to generate contact damage in hard coatings on soft substrates in a wide range of material combinations: ceramic/ceramic, ceramic/metal, and ceramic/filled-polymer. Specimen preparation methods for each system and experimental procedures for contact damage and fracture analysis are described. Test variables studied include elastic-plastic mismatch (controlled by changing material combinations) and coating thickness. The evolution of mechanical damage within the coating and substrate layers is studied. Upon loading, "quasi-plasticity" occurs in the ceramic substrates, plasticity in the metal substrates, and visco-plasticity in the filled-polymer substrates. During loading, fracture occurs in the coatings in ceramic/ceramic and ceramic/filled-polymer systems: cone cracks initiate at the top surface and propagate downward, while inverted cones initiate at the coating/substrate interface and propagate upward. In ceramic/metal systems quasi-plasticity occurs in the coating. Finite element analyses of the stress fields in contact loading reveal direct correlations between the damage patterns and appropriate stress components: tensile stresses in the case of fracture, and shear stresses in the case of plasticity or quasi-plasticity.

  18. Structure of the nocturnal boundary layer over a complex terrain

    SciTech Connect

    Parker, M.J.; Raman, S.

    1992-08-01

    The complex nature of the nocturnal boundary layer (NBL) has been shown extensively in the literature Project STABLE was conducted in 1988 to study NBL turbulence and diffusion over the complex terrain of the Savannah River Site (SRS) near Augusta, Georgia. The third night of the study was particularly interesting because of the unusual phenomena observed in the structure of the NBL. Further analyses of microscale and mesoscale data from this night are presented using data from SRS network of eight 61 m towers over 900 km{sup 2}, from six launches of an instrumented tethersonde, from permanent SRL meteorological instrumentation at seven levels of the 304 m (1,000 ft) WJBF-TV tower near SRS, and additional data collected at 36 m (CC) by North Carolina State University (NCSU) including a one dimensional sonic anemometer, fine wire thermocouple, and a three dimensional propeller anemometer. Also, data from the nearby Plant Vogtle nuclear power plant observation tower and the National Weather Service at Augusta`s Bush Field (AGS) are presented. The passage of a mesoscale phenomenon, defined as a microfront (with an explanation of the nomenclature used), and a vertical composite schematic of the NBL which shows dual low level wind maxima, dual inversions, and a persistent, elevated turbulent layer over a complex terrain are described.

  19. Structure of the nocturnal boundary layer over a complex terrain

    SciTech Connect

    Parker, M.J. ); Raman, S. . Dept. of Marine, Earth and Atmospheric Sciences)

    1992-01-01

    The complex nature of the nocturnal boundary layer (NBL) has been shown extensively in the literature Project STABLE was conducted in 1988 to study NBL turbulence and diffusion over the complex terrain of the Savannah River Site (SRS) near Augusta, Georgia. The third night of the study was particularly interesting because of the unusual phenomena observed in the structure of the NBL. Further analyses of microscale and mesoscale data from this night are presented using data from SRS network of eight 61 m towers over 900 km{sup 2}, from six launches of an instrumented tethersonde, from permanent SRL meteorological instrumentation at seven levels of the 304 m (1,000 ft) WJBF-TV tower near SRS, and additional data collected at 36 m (CC) by North Carolina State University (NCSU) including a one dimensional sonic anemometer, fine wire thermocouple, and a three dimensional propeller anemometer. Also, data from the nearby Plant Vogtle nuclear power plant observation tower and the National Weather Service at Augusta's Bush Field (AGS) are presented. The passage of a mesoscale phenomenon, defined as a microfront (with an explanation of the nomenclature used), and a vertical composite schematic of the NBL which shows dual low level wind maxima, dual inversions, and a persistent, elevated turbulent layer over a complex terrain are described.

  20. Coherent structures in the Es layer and neutral middle atmosphere

    NASA Astrophysics Data System (ADS)

    Mošna, Zbyšek; Knížová, Petra Koucká; Potužníková, Kateřina

    2015-12-01

    The present paper shows results from the summer campaign performed during geomagnetically quiet period from June 1 to August 31, 2009. Within time-series of stratospheric and mesospheric temperatures at pressure levels 10-0.1 hPa, mesospheric winds measured in Collm, Germany, and the sporadic E-layer parameters foEs and hEs measured at the Pruhonice station we detected specific coherent wave-bursts in planetary wave domain. Permanent wave-like activity is observed in all analyzed data sets. However, the number of wave-like structures persistent in large range of height from the stratosphere to lower ionosphere is limited. The only coherent modes that are detected on consequent levels of the atmosphere are those corresponding to eigenmodes of planetary waves.

  1. Homogeneous optical cloak constructed with uniform layered structures.

    PubMed

    Zhang, Jingjing; Liu, Liu; Luo, Yu; Zhang, Shuang; Mortensen, Niels Asger

    2011-04-25

    The prospect of rendering objects invisible has intrigued researchers for centuries. Transformation optics based invisibility cloak design is now bringing this goal from science fictions to reality and has already been demonstrated experimentally in microwave and optical frequencies. However, the majority of the invisibility cloaks reported so far have a spatially varying refractive index which requires complicated design processes. Besides, the size of the hidden object is usually small relative to that of the cloak device. Here we report the experimental realization of a homogenous invisibility cloak with a uniform silicon grating structure. The design strategy eliminates the need for spatial variation of the material index, and in terms of size it allows for a very large obstacle/cloak ratio. A broadband invisibility behavior has been verified at near-infrared frequencies, opening up new opportunities for using uniform layered medium to realize invisibility at any frequency ranges, where high-quality dielectrics are available. PMID:21643114

  2. The role of layer structure in tin oxidation kinetics

    NASA Astrophysics Data System (ADS)

    Duhalde, S.; Arcondo, B.; Sirkin, H.

    1991-11-01

    Tin exhibits different oxidation kinetics which are composition dependent, when it forms intermetallic compounds with the chalcogenides S and Se. This phenomenon is related to the layer compounds SnS2 and SnSe2 crystalline structure. These minerals have anisotropic bonding characteristics, due to Van der Waals bonds presence between chalcogenides adjoining planes. The mentioned weak bonds allow the oxygen diffusion to the bulk, favouring the reaction with the inner tin atoms. In this work we study samples of Sn-S alloy with different thermal treatment by XRD and Mössbauer spectroscopy. Results are discussed and compared with those obtained for Sn-Se alloy in an early work [1].

  3. Modified endoscopic submucosal dissection with enucleation for treatment of gastric subepithelial tumors originating from the muscularis propria layer

    PubMed Central

    2012-01-01

    Background Gastric subepithelial tumors are usually asymptomatic and observed incidentally during endoscopic examination. Although most of these tumors are considered benign, some have a potential for malignant transformation, particularly those originating from the muscularis propria layer. For this type of tumor, surgical resection is the standard treatment of choice. With recent advent of endoscopic resection techniques and devices, endoscopic submucosal dissection (ESD) has been considered as an alternative way of treatment. The aim of this study is to demonstrate the feasibility of a modified ESD technique with enucleation for removal of gastric subepithelial tumors originating from the muscularis propria layer, and to evaluate its efficacy and safety. Methods From November 2009 to May 2011, a total of 16 patients received a modified ESD with enucleation for their subepithelial tumors. All tumors were smaller than 5 cm and originated from the muscularis propria layer of the stomach, as shown by endoscopic ultrasonography (EUS). The procedure was conducted with an insulated-tip knife 2. Patient’s demographics, tumor size and pathological diagnosis, procedure time, procedure-related complication, and treatment outcome were reviewed. Results Fifteen of the sixteen tumors were successful complete resection. The mean tumor size measured by EUS was 26.1 mm (range: 20–42 mm). The mean procedure time was 52 minutes (range: 30–120 minutes). Endoscopic features of the 4 tumors were pedunculated and 12 were sessile. Their immunohistochemical diagnosis was c-kit (+) stromal tumor in 14 patients and leiomyoma in 2 patients. There was no procedure-related perforation or overt bleeding. During a mean follow up duration of 14.8 months (range: 6–22 months), there was no tumor recurrence or metastasis. Conclusions Using a modified ESD with enucleation for treatment of gastric subepithelial tumors originating from the muscularis propria layer and larger

  4. Computer-originated polarizing holographic optical element recorded in photopolymerizable layers.

    PubMed

    Carré, C; Habraken, S; Roose, S

    1993-05-01

    The photosensitive system that is used in most cases to produce holographic optical holograms is dichromated gelatin. Other materials may be used, in particular, photopolymerizable layers. In the present investigation, we set out to use the polymer developed in the Laboratoire de Photochimie Générale in Mulhouse in order to duplicate a computer-generated hologram. Our technique is intended to generate polarizing properties. We took into account the fact that no wet chemistry processing is required; grating fringe spacings are not distorted through chemical development. PMID:19802257

  5. Corrosion detection in multi-layered rotocraft structures

    SciTech Connect

    ROACH,DENNIS P.; WALKINGTON,PHILLIP D.; HOHMAN,ED; MARSHALL,GREG

    2000-04-25

    Rotorcraft structures do not readily lend themselves to quantifiable inspection methods due to airframe construction techniques. Periodic visual inspections are a common practice for detecting corrosion. Unfortunately, when the telltale signs of corrosion appear visually, extensive repair or refurbishment is required. There is a need to nondestructively evaluate airframe structures in order to recognize and quantify corrosion before visual indications are present. Nondestructive evaluations of rotorcraft airframes face inherent problems different from those of the fixed wing industry. Most rotorcraft lap joints are very narrow, contain raised fastener heads, may possess distortion, and consist of thinner gage materials ({approximately}0.012--0.125 inches). In addition the structures involve stack-ups of two and three layers of thin gage skins that are separated by sealant of varying thickness. Industry lacks the necessary data techniques, and experience to adequately perform routine corrosion inspection of rotorcraft. In order to address these problems, a program is currently underway to validate the use of eddy current inspection on specific rotorcraft lap joints. Probability of detection (POD) specimens have been produced that simulate two lap joint configurations on a model TH-57/206 helicopter. The FAA's Airworthiness Assurance Center (AANC) at Sandia Labs and Bell Helicopter have applied single and dual frequency eddy current (EC) techniques to these test specimens. The test results showed enough promise to justify beta site testing of the eddy current methods evolved in this study. The technique allows users to distinguish between corrosion signals and those caused by varying gaps between the assembly of skins. Specific structural joints were defined as prime corrosion areas and a series of corrosion specimens were produced with 5--20% corrosion distributed among the layers of each joint. Complete helicopter test beds were used to validate the laboratory

  6. Structure Identification Within a Transitioning Swept-Wing Boundary Layer

    NASA Technical Reports Server (NTRS)

    Chapman, Keith; Glauser, Mark

    1996-01-01

    Extensive measurements are made in a transitioning swept-wing boundary layer using hot-film, hot-wire and cross-wire anemometry. The crossflow-dominated flow contains stationary vortices that breakdown near mid-chord. The most amplified vortex wavelength is forced by the use of artificial roughness elements near the leading edge. Two-component velocity and spanwise surface shear-stress correlation measurements are made at two constant chord locations, before and after transition. Streamwise surface shear stresses are also measured through the entire transition region. Correlation techniques are used to identify stationary structures in the laminar regime and coherent structures in the turbulent regime. Basic techniques include observation of the spatial correlations and the spatially distributed auto-spectra. The primary and secondary instability mechanisms are identified in the spectra in all measured fields. The primary mechanism is seen to grow, cause transition and produce large-scale turbulence. The secondary mechanism grows through the entire transition region and produces the small-scale turbulence. Advanced techniques use Linear Stochastic Estimation (LSE) and Proper Orthogonal Decomposition (POD) to identify the spatio-temporal evolutions of structures in the boundary layer. LSE is used to estimate the instantaneous velocity fields using temporal data from just two spatial locations and the spatial correlations. Reference locations are selected using maximum RMS values to provide the best available estimates. POD is used to objectively determine modes characteristic of the measured flow based on energy. The stationary vortices are identified in the first laminar modes of each velocity component and shear component. Experimental evidence suggests that neighboring vortices interact and produce large coherent structures with spanwise periodicity at double the stationary vortex wavelength. An objective transition region detection method is developed using

  7. Cap structures as diagnostic indicators of silcrete origin

    NASA Astrophysics Data System (ADS)

    Ullyott, J. Stewart; Nash, David J.; Huggett, Jennifer M.

    2015-07-01

    Cap structures within silcretes have long been used as a diagnostic indicator of pedogenic silicification. However, a growing number of studies of the micromorphology of non-pedogenic silcretes indicate that this may no longer be appropriate. This paper presents the first systematic investigation of the micro-fabric, geochemistry and mineralogy of cap structures in groundwater silcretes, through an analysis of conglomeratic varieties (puddingstones) from the southern UK. Our results suggest that cap structures in groundwater silcretes fall within a spectrum of types, related to the degree of sorting in the inter-gravel host sediment. At one end of this spectrum are well-defined caps within otherwise well-sorted, overgrowth-dominated silcretes. These caps exhibit a grain-supported fabric, are cemented by micro- and/or cryptocrystalline silica, and contain floating silt-sized quartz and Ti-oxide grains. We propose that these structures developed mainly as a result of in-washing of fine sediments that were subsequently silicified. At the other end of the spectrum are silcretes with caps defined by concentrations of Ti-oxide grains, as opposed to cement type and grain size. These formed mainly as a result of the remobilisation and precipitation of Ti during the silicification of gravels containing interstitial clay-rich sandy sediment. Between these end-members are silcretes with cap structures formed by a combination of in-washing and redistribution of fines plus some local remobilisation of Ti. Overall, the cap structures in this study exhibit a simple micromorphology, lacking the alternating Ti- and silica-rich lamellae typical of pedogenic silcrete. We conclude that the presence of cap structures alone should not be considered diagnostic of pedogenic silicification unless accompanied by other indicators such as a differentiated profile and abundant, complex, way-up structures within the micro-fabric.

  8. Origin of coal seam structures, Sullivan County, Indiana

    SciTech Connect

    Adams, S.C.; Kullerud, G.

    1983-09-01

    Structures of Pennsylvanian coal seams in Sullivan County, Indiana, reflect deeper structural components, of which regional dip is dominant. Other components of structure result form differential compaction. The effects of these components are characterized by their closure, size, shape, and orientation. (1) The Mississippian unconformity surface is characterized by parallel valley with up to 300 ft (91 m) of local relief. (2) The composite lower Pennsylvanian section below the Seelyville Coal has variable sandstone content. Some paleovalleys are filled with multistory sandstones, and others with claystone. (3) Silurian pinnacle reefs from small, circular features with a diameter of 1 to 2 mi (1.5 to 3 km) and closures of 25 tio 50 ft (8 to 15 m) on Pennsylvanian coal seams, 50 ft (15 m) on the Aux Vases Shale, and 150 ft (45 m) on the New Albany Shale. (4) The distributions and standard deviations of thicknesses, dips, and grain size of the sedimentary rocks between the coal seams demonstrate that seams above the Seelyville Coal were deposited in parallel and have concordant modern structures. Specific facies between seams have limited influence on the overall structure. Coal structures in the Illinois basin can be defined by a drilling program that penetrates only 150 ft (45 m) of Pennsylvanian strata. Below the Seelyville Coal, units examined demonstrate basin-margin convergence.

  9. THE STRUCTURE AND ORIGIN OF SOLAR PLUMES: NETWORK PLUMES

    SciTech Connect

    Gabriel, A.; Tison, E.; Bely-Dubau, F.; Wilhelm, K.

    2009-07-20

    This study is based upon plumes seen close to the solar limb within coronal holes in the emission from ions formed in the temperature region of 1 MK, in particular, the band of Fe IX 171 A from EIT on the Solar and Heliospheric Observatory. It is shown, using geometric arguments, that two distinct classes of structure contribute to apparently similar plume observations. Quasi-cylindrical structures are anchored in discrete regions of the solar surface (beam plumes), and faint extended structures require integration along the line of sight (LOS) in order to reproduce the observed brightness. This second category, sometimes called 'curtains', are ubiquitous within the polar holes and are usually more abundant than the beam plumes, which depend more on the enhanced magnetic structures detected at their footpoints. It is here proposed that both phenomena are based on plasma structures in which emerging magnetic loops interact with ambient monopolar fields, involving reconnection. The important difference is in terms of physical scale. It is proposed that curtains are composed of a large number of microplumes, distributed along the LOS. The supergranule network provides the required spatial structure. It is shown by modeling that the observations can be reproduced if microplumes are concentrated within some 5 Mm of the cell boundaries. For this reason, we propose to call this second population 'network plumes'. The processes involved could represent a major contribution to the heating mechanism of the solar corona.

  10. On the origins of the mitotic shift in proliferating cell layers

    PubMed Central

    2014-01-01

    Background During plant and animal development, monolayer cell sheets display a stereotyped distribution of polygonal cell shapes. In interphase cells these shapes range from quadrilaterals to decagons, with a robust average of six sides per cell. In contrast, the subset of cells in mitosis exhibits a distinct distribution with an average of seven sides. It remains unclear whether this ‘mitotic shift’ reflects a causal relationship between increased polygonal sidedness and increased division likelihood, or alternatively, a passive effect of local proliferation on cell shape. Methods We use a combination of probabilistic analysis and mathematical modeling to predict the geometry of mitotic polygonal cells in a proliferating cell layer. To test these predictions experimentally, we use Flp-Out stochastic labeling in the Drosophila wing disc to induce single cell clones, and confocal imaging to quantify the polygonal topologies of these clones as a function of cellular age. For a more generic test in an idealized cell layer, we model epithelial sheet proliferation in a finite element framework, which yields a computationally robust, emergent prediction of the mitotic cell shape distribution. Results Using both mathematical and experimental approaches, we show that the mitotic shift derives primarily from passive, non-autonomous effects of mitoses in neighboring cells on each cell’s geometry over the course of the cell cycle. Computationally, we predict that interphase cells should passively gain sides over time, such that cells at more advanced stages of the cell cycle will tend to have a larger number of neighbors than those at earlier stages. Validating this prediction, experimental analysis of randomly labeled epithelial cells in the Drosophila wing disc demonstrates that labeled cells exhibit an age-dependent increase in polygonal sidedness. Reinforcing these data, finite element simulations of epithelial sheet proliferation demonstrate in a generic framework

  11. A structural origin for the cantaloupe terrain of Triton

    NASA Technical Reports Server (NTRS)

    Boyce, Joseph M.

    1993-01-01

    Cantaloupe terrain is unique to Triton. It is Triton's oldest terrain and includes about 250,000 km sq. region displaying sparsely cratered, closely spaced, nearly circular dimples about 30-40 km across. This terrain is found on no other planet because, only on Triton the final major global thermal pulse (1) caused completed (or nearly) interior melting resulting in a cooling history where large thermal stresses shattered and contorted a thin, weak lithosphere, and (2) occurred after heavy bombardment so that the surface features were preserved. The cantaloupe terrain is composed of intersecting sets of structures (folds and/or faults) that have developed as a result of global compression generated by volumetric changes associated with cooling of Triton's interior. Further, it is proposed that these structures developed after the period of heavy bombardment, and resulted from the last major global thermal epoch in Triton's unique history (either caused by tidal or radio metric heating). Initially, as the body cooled and the structures formed, their surface topography was most likely modified by thermal relaxation of the warm surface ices. In other bodies like Mercury, thermal stresses generated from global cooling and contraction have resulted in widely spaced thrust faults, whereas on Triton, thermal stresses produced more closely-spaced folds and faults sets. This difference in structural style is probably due to differences in lithospheric properties (thickness, strength, etc.), the magnitude of stress (directly dependent on the thermal history), and when the structures formed, relative to the period of heavy bombardment.

  12. Structure of Greyhound hemoglobin: origin of high oxygen affinity.

    PubMed

    Bhatt, Veer S; Zaldívar-López, Sara; Harris, David R; Couto, C Guillermo; Wang, Peng G; Palmer, Andre F

    2011-05-01

    This study presents the crystal structure of Greyhound hemoglobin (GrHb) determined to 1.9 Å resolution. GrHb was found to crystallize with an α₁β₁ dimer in the asymmetric unit and belongs to the R2 state. Oxygen-affinity measurements combined with the fact that GrHb crystallizes in the R2 state despite the high-salt conditions used for crystallization strongly indicate that GrHb can serve as a model high-oxygen-affinity hemoglobin (Hb) for higher mammals, especially humans. Structural analysis of GrHb and its comparison with the R2-state of human Hb revealed several regions that can potentially contribute to the high oxygen affinity of GrHb and serve to rationalize the additional stability of the R2-state of GrHb. A previously well studied hydrophobic cluster of bar-headed goose Hb near α119 was also incorporated in the comparison between GrHb and human Hb. Finally, a structural comparison with generic dog Hb and maned wolf Hb was conducted, revealing that in contrast to GrHb these structures belong to the R state of Hb and raising the intriguing possibility of an additional allosteric factor co-purifying with GrHb that can modulate its quaternary structure. PMID:21543841

  13. A structural origin for the cantaloupe terrain of Triton

    NASA Astrophysics Data System (ADS)

    Boyce, Joseph M.

    1993-03-01

    Cantaloupe terrain is unique to Triton. It is Triton's oldest terrain and includes about 250,000 km sq. region displaying sparsely cratered, closely spaced, nearly circular dimples about 30-40 km across. This terrain is found on no other planet because, only on Triton the final major global thermal pulse (1) caused completed (or nearly) interior melting resulting in a cooling history where large thermal stresses shattered and contorted a thin, weak lithosphere, and (2) occurred after heavy bombardment so that the surface features were preserved. The cantaloupe terrain is composed of intersecting sets of structures (folds and/or faults) that have developed as a result of global compression generated by volumetric changes associated with cooling of Triton's interior. Further, it is proposed that these structures developed after the period of heavy bombardment, and resulted from the last major global thermal epoch in Triton's unique history (either caused by tidal or radio metric heating). Initially, as the body cooled and the structures formed, their surface topography was most likely modified by thermal relaxation of the warm surface ices. In other bodies like Mercury, thermal stresses generated from global cooling and contraction have resulted in widely spaced thrust faults, whereas on Triton, thermal stresses produced more closely-spaced folds and faults sets. This difference in structural style is probably due to differences in lithospheric properties (thickness, strength, etc.), the magnitude of stress (directly dependent on the thermal history), and when the structures formed, relative to the period of heavy bombardment.

  14. Intercalation of cellulase enzyme into a hydrotalcite layer structure

    NASA Astrophysics Data System (ADS)

    Zou, N.; Plank, J.

    2015-01-01

    A new inorganic-organic hybrid material whereby cellulase enzyme is incorporated into a hydrotalcite type layered double hydroxide (LDH) structure is reported. The Mg2Al-cellulase-LDH was synthesized via co-precipitation from Mg/Al nitrate at pH=9.6. Characterization was performed using X-ray powder diffraction (XRD), small angle X-ray scattering (SAXS), elemental analysis, infrared spectroscopy (IR) and thermogravimetry (TG). From XRD and SAXS measurements, a d-value of ~5.0 nm was identified for the basal spacing of the Mg2Al-cellulase-LDH. Consequently, the cellulase enzyme (hydrodynamic diameter ~6.6 nm) attains a slightly compressed conformation when intercalated. Formation of the LDH hybrid was also confirmed via scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Mg2Al-cellulase-LDH phases appear as ~20 nm thin foils which are intergrown to flower-like aggregates. Activity of the enzyme was retained after deintercalation from the Mg2Al-LDH framework using anion exchange. Accordingly, cellulase is not denatured during the intercalation process, and LDH presents a suitable host structure for time-controlled release of the biomolecule.

  15. Dynamical Origin and the Pole Structure of X(3872)

    SciTech Connect

    Danilkin, I. V.; Simonov, Yu. A.

    2010-09-03

    The dynamical mechanism of channel coupling with the decay channels is applied to the case of coupled charmonium--DD{sup *} states with J{sup PC}=1{sup ++}. A pole analysis is done and the DD{sup *} production cross section is calculated in qualitative agreement with experiment. The sharp peak at the D{sub 0}D{sub 0}{sup *} threshold and flat background are shown to be due to Breit-Wigner resonance, shifted by channel coupling from the original position of 3954 MeV for the 2{sup 3}P{sub 1}, QQ state. A similar analysis, applied to the n=2, {sup 3}P{sub 2}, {sup 1}P{sub 1}, {sup 3}P{sub 0}, allows us to associate the first one with the observed Z(3930) J=2 and explains the destiny of {sup 3}P{sub 0}.

  16. Exploring the origin of ultralow thermal conductivity in layered BiOCuSe

    NASA Astrophysics Data System (ADS)

    Saha, S. K.

    2015-07-01

    Using first-principles density functional theory calculations, a systematic study of the lattice dynamics and related (e.g., dielectric and anharmonic) properties of BiOCuSe (bismuth-copper oxyselenide), along with a comparison with its isostructural analog LaOCuSe, is performed to find the origin of the ultralow thermal conductivity κ in BiOCuSe. From the marked differences in some of these properties of the two materials, the reasons why BiOCuSe is a better thermal insulator than LaOCuSe are elucidated. For this class of oxychalcogenide thermoelectrics, phonon frequencies with symmetries, characters, spectroscopic activities, displacement patterns, and pressure coefficients of different zone-center modes, dielectric constants, dynamical charges, and phonon and Grüneisen dispersions are also determined.

  17. The structural origin of anomalous properties of liquid water

    PubMed Central

    Nilsson, Anders; Pettersson, Lars G. M.

    2015-01-01

    Water is unique in its number of unusual, often called anomalous, properties. When hot it is a normal simple liquid; however, close to ambient temperatures properties, such as the compressibility, begin to deviate and do so increasingly on further cooling. Clearly, these emerging properties are connected to its ability to form up to four well-defined hydrogen bonds allowing for different local structural arrangements. A wealth of new data from various experiments and simulations has recently become available. When taken together they point to a heterogeneous picture with fluctuations between two classes of local structural environments developing on temperature-dependent length scales. PMID:26643439

  18. The Development of Layered Photonic Band Gap Structures Using a Micro-Transfer Molding Technique

    SciTech Connect

    Kevin Jerome Sutherland

    2001-05-01

    Photonic band gap (PBG) crystals are periodic dielectric structures that manipulate electromagnetic radiation in a manner similar to semiconductor devices manipulating electrons. Whereas a semiconductor material exhibits an electronic band gap in which electrons cannot exist, similarly, a photonic crystal containing a photonic band gap does not allow the propagation of specific frequencies of electromagnetic radiation. This phenomenon results from the destructive Bragg diffraction interference that a wave propagating at a specific frequency will experience because of the periodic change in dielectric permitivity. This gives rise to a variety of optical applications for improving the efficiency and effectiveness of opto-electronic devices. These applications are reviewed later. Several methods are currently used to fabricate photonic crystals, which are also discussed in detail. This research involves a layer-by-layer micro-transfer molding ({mu}TM) and stacking method to create three-dimensional FCC structures of epoxy or titania. The structures, once reduced significantly in size can be infiltrated with an organic gain media and stacked on a semiconductor to improve the efficiency of an electronically pumped light-emitting diode. Photonic band gap structures have been proven to effectively create a band gap for certain frequencies of electro-magnetic radiation in the microwave and near-infrared ranges. The objective of this research project was originally two-fold: to fabricate a three dimensional (3-D) structure of a size scaled to prohibit electromagnetic propagation within the visible wavelength range, and then to characterize that structure using laser dye emission spectra. As a master mold has not yet been developed for the micro transfer molding technique in the visible range, the research was limited to scaling down the length scale as much as possible with the current available technology and characterizing these structures with other methods.

  19. The origin of CDR H3 structural diversity

    PubMed Central

    Weitzner, Brian D.; Dunbrack, Roland L.; Gray, Jeffrey J.

    2014-01-01

    Antibody CDR H3 loops are critical for adaptive immunological functions. Although the other five CDR loops adopt predictable canonical structures, H3 conformations have proven unclassifiable, other than an unusual C-terminal “kink” present in most antibodies. To determine why the majority of H3 loops are kinked and to learn whether non-antibody proteins have loop structures similar to H3, we searched a set of 15,679 high-quality non-antibody structures for regions geometrically similar to the residues immediately surrounding the loop. By incorporating the kink into our search, we identified 1,030 H3-like loops from 632 protein families. Some protein families, including PDZ domains, appear to use the identified region for recognition and binding. Our results suggest the kink is conserved in the immunoglobulin heavy chain fold because it disrupts the β-strand pairing at the base of the loop. Thus, the kink is a critical driver of the observed structural diversity in CDR H3. PMID:25579815

  20. The Origins of African-American Family Structure.

    ERIC Educational Resources Information Center

    Ruggles, Steven

    1994-01-01

    Uses the Integrated Public Use Microdata Series to trace race differences in African American family structure between 1880 and 1980. Confirms a long-standing high incidence rate of single parenthood and children residing without their parents. Data also show blacks have had a consistently higher percentage of extended households than have whites.…

  1. Layered structure in the interaction of thin foil with two laser pulses

    SciTech Connect

    Yu, Yahong; Shen, Baifei E-mail: jill@siom.ac.cn; Yu, Wei; Wang, Wenpeng; Zhang, Xiaomei; Ji, Liangliang E-mail: jill@siom.ac.cn; Zhao, Xueyan; Wang, Xiaofeng; Yi, Longqing; Shi, Yin; Xu, Tongjun; Zhang, Lingang; Wen, Meng

    2014-02-15

    An interesting layered structure of multiple high density layers are formed when two counter-propagating circularly polarized laser pulses with the same polarization direction irradiate on an ultra-thin foil. This structure changes periodically. For light atoms most of which electrons may be fully ionized, this layered structure can keep for dozens of laser periods after the laser-foil interaction. This interesting structure may have potential applications.

  2. The Development of Layered Photonic Band Gap Structures Using a Micro-Transfer Molding Technique

    SciTech Connect

    Kevin Jerome Sutherland

    2001-06-27

    Over the last ten years, photonic band gap (PBG) theory and technology have become an important area of research because of the numerous possible applications ranging from high-efficiency laser diodes to optical circuitry. This research concentrates on reducing the length scale in the fabrication of layered photonic band gap structures and developing procedures to improve processing consistency. Various procedures and materials have been used in the fabrication of layered PBG structures. This research focused on an economical micro transfer molding approach to create the final PBG structure. A poly dimethylsiloxane (PDMS) rubber mold was created from a silicon substrate. It was filled with epoxy and built layer-by-layer to create a 3-D epoxy structure. This structure was infiltrated with nanoparticle titania or a titania sol-gel, then fired to remove the polymer mold, leaving a monolithic ceramic inverse of the epoxy structure. The final result was a lattice of titania rolds that resembles a face-centered tetragonal structure. The original intent of this research was to miniaturize this process to a bar size small enough to create a photonic band gap for wavelengths of visible electro-magnetic radiation. The factor limiting progress was the absence of a silicon master mold of small enough dimensions. The Iowa State Microelectronics Research Center fabricated samples with periodicities of 2.5 and 1.0 microns with the existing technology, but a sample was needed on the order of 0.3 microns or less. A 0.4 micron sample was received from Sandia National Laboratory, which was made through an electron beam lithography process, but it contained several defects. The results of the work are primarily from the 2.5 and 1.0 micron samples. Most of the work focused on changing processing variables in order to optimize the infiltration procedure for the best results. Several critical parameters were identified, ranging from the ambient conditions to the specifics of the

  3. The Origin of a Layer of Subcircular Mudflakes in the Ross Sandstone Formation of County Clare, Ireland

    NASA Astrophysics Data System (ADS)

    Robinson, K. H.; Kackstaetter, U. R.

    2015-12-01

    The west coast of Ireland in County Clare is famous for its Paleozoic stratigraphy containing spectacular exposures of deposits from carbonate shelf, deep marine, slope and deltaic environments, exposed at several distinctive and well-known locations including the Burren, Cliffs of Moher, and Bridges of Ross. Underlying the silty sandstones of the Gull Island Formation and overlying the Clare Shale, the Carboniferous Ross Sandstone Formation comprises a series of fine-grained sandstone and mudstone deep water turbidite deposits. Approximately a half-kilometer northeast of the Bridges of Ross and about 15 meters below the upper boundary of the Ross Formation is a particular stratum exhibiting an assemblage of unique circular to ovoid impressions. These features densely cover an exposed horizontal surface of approximately 100 square meters, positioned about 5 meters above and adjacent to a cluster of sand volcanoes. The impressions frequently overlap and completely cover the exposed surface of the rock unit and continue along the same plane of the buried portion of the stratum. Diameters of the impressions range between 2 and 20 centimeters, and many contain clasts of pale grey shale or claystone material. Samples were collected from the layer of interest as well as from subjacent and superjacent strata, spanning a total thickness of just over 1 meter. Thin sections were created and analyzed to determine both composition and estimated porosity of the rock in a continuous vertical cross-section through the series of strata surrounding the impressions. Characteristics of each stratum were examined to explore possible depositional relationships of each layer to the others and to indicate likely diagenetic processes of the subcircular features. Two broad possible origins are discussed: a primary sedimentary origin, i.e. turbidite channel mudflake conglomerate; or a post-depositional soft sediment deformation origin due to either (i) sediment loading and dewatering, (ii

  4. Electronic structure of the layered diboride dicarbide superconductor Y B2C2

    NASA Astrophysics Data System (ADS)

    Khmelevskyi, S.; Mohn, P.; Redinger, J.; Michor, H.

    2005-04-01

    The electronic structure of the layered diboride dicarbide superconductor Y B2C2 is calculated using the full potential LAPW method within the framework of ab initio density functional theory. Our results confirm that the crystal structure with P4/mbm symmetry is more stable than the originally claimed P\\overline {4}2c structure, which is in accordance with recent interpretations of the diffraction patterns of other related compounds of LaB2C2-type. It is found that the metallic conductivity in the stable P4/mbm structure is due to Y d-bands partially hybridized with pz-states from the B-C planes. Thus the structure of the conduction bands differs from those found in MgB2. However, a large portion of the Fermi surface of Y B2C2 exhibits distinctive two-dimensional features, which can make this compound interesting for experimental studies on superconductivity connected to effects of strong electronic structure anisotropy.

  5. Noise and vibration level reduction by covering metal structures with layers of damping materials. [considering viscoelastic insulation layers

    NASA Technical Reports Server (NTRS)

    Rugina, I.; Paven, H. T. O.

    1974-01-01

    One of the most important methods of reducing the noise and vibration level is the damping of the secondary sources, such as metal plates, often used in vehicle structures, by means of covering materials with high internal viscosity. Damping layers are chosen at an optimum thickness corresponding to the frequency and temperature range in which a certain structure works. The structure's response corresponding to various real situations is analyzed by means of a measuring chain including electroacoustical or electromechanical transducers. The experimental results provide the dependence of the loss factor and damping transmission coefficient as a function of the damping layer thickness or of the frequency for various viscoelastic covering materials.

  6. The Origins of Magnetic Structure in the Corona and Wind

    NASA Technical Reports Server (NTRS)

    Antiochos, Spiro K.

    2010-01-01

    One of the most important and most puzzling features of the coronal magnetic field is that it appears to have smooth magnetic structure with little evidence for non-potentiality except at two special locations: photospheric polarity inversions lines. (non-potentiality observed as a filament channel) and coronal hole boundaries, (observed as the slow solar wind). This characteristic feature of the closed-field corona is highly unexpected given that its magnetic field is continuously tangled by photospheric motions. Although reconnection can eliminate some of the injected structure, it cannot destroy the helicity, which should build up to produce observable complexity. I propose that an inverse cascade process transports the injected helicity from the interior of closed flux regions to their boundaries inversion lines and coronal holes, creating both filament channels and the slow wind. We describe how the helicity is injected and transported and calculate the relevant rates. I argue that one process, helicity transport, can explain both the observed lack and presence of structure in the coronal magnetic field. This work has been supported by the NASA HTP, SR&T, and LWS programs.

  7. Substrate Structures For Growth Of Highly Oriented And/Or Epitaxial Layers Thereon

    DOEpatents

    Arendt, Paul N.; Foltyn, Stephen R.; Groves, James R.; Jia, Quanxi

    2005-07-26

    A composite substrate structure including a substrate, a layer of a crystalline metal oxide or crystalline metal oxynitride material upon the substrate, a layer of an oriented cubic oxide material having a rock-salt-like structure upon the crystalline metal oxide or crystalline metal oxynitride material layer is provided together with additional layers such as one or more layers of a buffer material upon the oriented cubic oxide material layer. Jc's of 2.3×106 A/cm2 have been demonstrated with projected Ic's of 320 Amperes across a sample 1 cm wide for a superconducting article including a flexible polycrystalline metallic substrate, an inert oxide material layer upon the surface of the flexible polycrystalline metallic substrate, a layer of a crystalline metal oxide or crystalline metal oxynitride material upon the layer of the inert oxide material, a layer of an oriented cubic oxide material having a rock-salt-like structure upon the crystalline metal oxide or crystalline metal oxynitride material layer, a layer of a buffer material upon the oriented cubic oxide material layer, and, a top-layer of a high temperature superconducting material upon the layer of a buffer material.

  8. Self-organization of local magnetoplasma structures in the upper layers of the solar convection zone

    SciTech Connect

    Chumak, O. V.

    2013-08-15

    Self-organization and evolution of magnetoplasma structures in the upper layers of the solar convection zone are discussed as a process of diffuse aggregation of magnetic flux tubes. Equations describing the tube motion under the action of magnetic interaction forces, hydrodynamic forces, and random forces are written explicitly. The process of aggregation of magnetic flux tubes into magnetic flux clusters of different shapes and dimensions is simulated numerically. The obtained structures are compared with the observed morphological types of sunspot groups. The quantitative comparison with the observational data was performed by comparing the fractal dimensions of the photospheric magnetic structures observed in solar active regions with those of structures obtained in the numerical experiment. The model has the following free parameters: the numbers of magnetic flux tubes with opposite polarities on the considered area element (Nn and Ns), the average radius of the cross section of the magnetic flux tube (a), its effective length (l), the twist factor of the tube field (k), and the absolute value of the average velocity of chaotic tube displacements (d). Variations in these parameters in physically reasonable limits leads to the formation of structures (tube clusters of different morphological types) having different fractal dimensions. Using the NOAA 10488 active region, which appeared and developed into a complicated configuration near the central meridian, as an example, it is shown that good quantitative agreement between the fractal dimensions is achieved at the following parameters of the model: Nn = Ns = 250 ± 50; a = 150 ± 50 km; l ∼ 5000 km, and d = 80 ± 10 m/s. These results do not contradict the observational data and theoretical estimates obtained in the framework of the Parker “spaghetti” model and provide new information on the physical processes resulting in the origin and evolution of local magnetic plasma structures in the near

  9. Self-organization of local magnetoplasma structures in the upper layers of the solar convection zone

    NASA Astrophysics Data System (ADS)

    Chumak, O. V.

    2013-08-01

    Self-organization and evolution of magnetoplasma structures in the upper layers of the solar convection zone are discussed as a process of diffuse aggregation of magnetic flux tubes. Equations describing the tube motion under the action of magnetic interaction forces, hydrodynamic forces, and random forces are written explicitly. The process of aggregation of magnetic flux tubes into magnetic flux clusters of different shapes and dimensions is simulated numerically. The obtained structures are compared with the observed morphological types of sunspot groups. The quantitative comparison with the observational data was performed by comparing the fractal dimensions of the photospheric magnetic structures observed in solar active regions with those of structures obtained in the numerical experiment. The model has the following free parameters: the numbers of magnetic flux tubes with opposite polarities on the considered area element ( Nn and Ns), the average radius of the cross section of the magnetic flux tube ( a), its effective length ( l), the twist factor of the tube field ( k), and the absolute value of the average velocity of chaotic tube displacements ( d). Variations in these parameters in physically reasonable limits leads to the formation of structures (tube clusters of different morphological types) having different fractal dimensions. Using the NOAA 10488 active region, which appeared and developed into a complicated configuration near the central meridian, as an example, it is shown that good quantitative agreement between the fractal dimensions is achieved at the following parameters of the model: Nn = Ns = 250 ± 50; a = 150 ± 50 km; l ˜ 5000 km, and d = 80 ± 10 m/s. These results do not contradict the observational data and theoretical estimates obtained in the framework of the Parker "spaghetti" model and provide new information on the physical processes resulting in the origin and evolution of local magnetic plasma structures in the near

  10. Structure and Origin of the Columbia Hills, Gusev Crater, Mars

    NASA Astrophysics Data System (ADS)

    McCoy, Timothy; Sims, M.; Crumpler, L. S.; Cohen, B. A.; Blaney, D. L.; Schmidt, M. E.; Treguier, E.; d'Uston, C.; Rice, J. W.; Tornabene, L. L.; Squyres, S. W.; Arvidson, R. E.; Haldemann, A.

    2007-10-01

    The Mars Exploration Rover Spirit has yielded profound insights into features at millimeter to decimeter scales. However, the origin of the Columbia Hills has remained enigmatic given the traverse across one peak [1]. We present a geologic history of the Hills consistent with their morphology, bedding attitudes, and stratigraphy. The Columbia Hills form a triangle 4.2 by 2.3 km, are bounded by linear to slightly concave margins, lie near the center of Gusev Crater, and have peaks rising to 90 m. Bedding dips away from a NNE-SSW axis cutting the Tennessee Valley. Husband Hill dips (15-32°) are steeper than local topography ( 8-10°) and those on West Spur are conformable with greater scatter in strike and shallower dips (7-15°). Husband Hill is cored by volcaniclastic rocks and impact breccias altered to various extents (Wishstone, Watchtower and Descartes classes), ringed by ultramafic volcaniclastic rocks and sulfate-cemented sands (Algonquin and Peace classes), ringed by localized impact breccias and volcaniclastic deposits (West Spur and Home Plate) [2]. The Columbia Hills likely formed by (1) Uplift of the Gusev Crater central peak, raising the Hills to 3 km above the crater floor, assuming the Hills are deeply-rooted and subsequently buried. Uplift by overlapping crater rims is inconsistent with bedding attitudes, but may have modified the margins of the Hills. (2) Draping by impact and volcaniclastic rocks and sands with localized alteration and cementation. Fragile rocks (Peace) and in situ soils (Paso Robles) would not have survived Gusev Crater formation. (3) Mass wasting of the Tennessee Valley removed tens of meters from the peak of the Hills, exposing older units in the core, (4) Plains (Adirondack) basalts surrounded and embayed the Hills, and (5) Small impacts redistributed rocks. [1] Rice J.W. (2004) Fall AGU, #P23B-03. [2] Squyres S.W. et al. (2006) JGR 111, E02S11.

  11. Localised Ag+ vibrations at the origin of ultralow thermal conductivity in layered thermoelectric AgCrSe2

    PubMed Central

    Damay, F.; Petit, S.; Rols, S.; Braendlein, M.; Daou, R.; Elkaïm, E.; Fauth, F.; Gascoin, F.; Martin, C.; Maignan, A.

    2016-01-01

    In materials science, the substructure approach consists in imagining complex materials in which a particular property is associated with a distinct structural feature, so as to combine different chosen physical characteristics, which otherwise have little chance to coexist. Applied to thermoelectric materials, it has been used to achieve simultaneously phonon-glass and electron-crystal properties. Mostly studied for its superionic conductivity, AgCrSe2 is a naturally layered compound, which achieves very low thermal conductivity, ~0.4 W.K−1.m−1 at RT (room temperature), and is considered a promising thermoelectric. The Cr atoms of the [CrSe2]∞ layer bear a spin S = 3/2, which orders below TN = 55 K. Here we report low temperature inelastic neutron scattering experiments on AgCrSe2, alongside the magnetic field evolution of its thermal and electrical transport. We observe a very low frequency mode at 3 meV, ascribed to large anharmonic displacements of the Ag+ ions in the [Ag]∞ layer, and 2D magnetic fluctuations up to 3 TN in the chromium layer. The low thermal conductivity of AgCrSe2 is attributed to acoustic phonon scattering by a regular lattice of Ag+ oscillating in quasi-2D potential wells. These findings highlight a new way to achieve localised phonon modes in a perfectly crystalline solid. PMID:27000414

  12. Structural origin of low temperature glassy relaxation in magnetic nanoparticles

    NASA Astrophysics Data System (ADS)

    Laha, Suvra; Regmi, Rajesh; Lawes, Gavin

    2013-03-01

    Magnetic nanoparticles often exhibit glass-like relaxation features at low temperatures. Here we discuss the effects of doping boron, cobalt, gadolinium and lanthanum on the low temperature magnetic properties of Fe3O4 nanoparticles. We investigated the structure of the nanoparticles using both X-ray diffraction and Raman studies, and find evidence for secondary phase formation in certain samples. We acquired Transmission Electron Microscopic images to give direct information on the morphology and microstructure of these doped nanoparticles. We measured the ac out-of-phase susceptibility (χ//) vs temperature (T) to parameterize the low temperature glassy magnetic relaxation. All samples show low temperature magnetic relaxation, but the amplitude of the signal increases dramatically for certain dopants. We attribute these low temperature frequency-dependent magnetic relaxation features to structural defects, which are enhanced in some of the doped Fe3O4 nanoparticles. These studies also confirm that the low temperature relaxation in nanoparticles arises from single particle effects and are not associated with interparticle interactions.

  13. Investigation of Boundary Layer Structure by Dual-Plane PIV

    NASA Astrophysics Data System (ADS)

    Longmire, E. K.; Ganapathisubramani, B.; Marusic, I.

    2004-11-01

    Dual-plane PIV was employed in a turbulent boundary layer at Re_τ ˜ 1100 to study the nature of the vortical structures there. Laser sheets separated by 1 mm were aligned in streamwise-spanwise (x,y) planes, and the scattered light was captured by three cameras: two in a stereo configuration and one in a normal configuration. All velocity gradient components were determined for fields in the log (z^+ = 125) and outer (z/δ = 0.5) regions. Three-dimensional swirl strength was used to isolate vortex cores, and the vorticity direction of individual swirl centers was determined. Instantaneous fields in the log region reveal signatures of hairpin vortex packets consistent with previous results. The packets contain evidence of smaller hairpin heads embedded within the long low-speed regions surrounded by larger hairpins. The data set at z^+ = 125 yielded a most probable hairpin inclination angle of 32^rc and an average inclination angle of 57^rc. In the presentation, these results will be contrasted with those at z/δ = 0.5.

  14. Dynamics of generalized Gaussian polymeric structures in random layered flows.

    PubMed

    Katyal, Divya; Kant, Rama

    2015-04-01

    We develop a formalism for the dynamics of a flexible branched polymer with arbitrary topology in the presence of random flows. This is achieved by employing the generalized Gaussian structure (GGS) approach and the Matheron-de Marsily model for the random layered flow. The expression for the average square displacement (ASD) of the center of mass of the GGS is obtained in such flow. The averaging is done over both the thermal noise and the external random flow. Although the formalism is valid for branched polymers with various complex topologies, we mainly focus here on the dynamics of the flexible star and dendrimer. We analyze the effect of the topology (the number and length of branches for stars and the number of generations for dendrimers) on the dynamics under the influence of external flow, which is characterized by their root-mean-square velocity, persistence flow length, and flow exponent α. Our analysis shows two anomalous power-law regimes, viz., subdiffusive (intermediate-time polymer stretching and flow-induced diffusion) and superdiffusive (long-time flow-induced diffusion). The influence of the topology of the GGS is unraveled in the intermediate-time regime, while the long-time regime is only weakly dependent on the topology of the polymer. With the decrease in the value of α, the magnitude of the ASD decreases, while the temporal exponent of the ASD increases in both the time regimes. Also there is an increase in both the magnitude of the ASD and the crossover time (from the subdiffusive to the superdiffusive regime) with an increase in the total mass of the polymeric structure. PMID:25974520

  15. Dynamics of generalized Gaussian polymeric structures in random layered flows

    NASA Astrophysics Data System (ADS)

    Katyal, Divya; Kant, Rama

    2015-04-01

    We develop a formalism for the dynamics of a flexible branched polymer with arbitrary topology in the presence of random flows. This is achieved by employing the generalized Gaussian structure (GGS) approach and the Matheron-de Marsily model for the random layered flow. The expression for the average square displacement (ASD) of the center of mass of the GGS is obtained in such flow. The averaging is done over both the thermal noise and the external random flow. Although the formalism is valid for branched polymers with various complex topologies, we mainly focus here on the dynamics of the flexible star and dendrimer. We analyze the effect of the topology (the number and length of branches for stars and the number of generations for dendrimers) on the dynamics under the influence of external flow, which is characterized by their root-mean-square velocity, persistence flow length, and flow exponent α . Our analysis shows two anomalous power-law regimes, viz., subdiffusive (intermediate-time polymer stretching and flow-induced diffusion) and superdiffusive (long-time flow-induced diffusion). The influence of the topology of the GGS is unraveled in the intermediate-time regime, while the long-time regime is only weakly dependent on the topology of the polymer. With the decrease in the value of α , the magnitude of the ASD decreases, while the temporal exponent of the ASD increases in both the time regimes. Also there is an increase in both the magnitude of the ASD and the crossover time (from the subdiffusive to the superdiffusive regime) with an increase in the total mass of the polymeric structure.

  16. Molecular analysis of neocortical layer structure in the ferret

    PubMed Central

    Rowell, Joanna J.; Mallik, Atul K.; Dugas-Ford, Jennifer; Ragsdale, Clifton W.

    2010-01-01

    Molecular markers that distinguish specific layers of rodent neocortex are increasingly employed to study cortical development and the physiology of cortical circuits. The extent to which these markers represent general features of neocortical cell type identity across mammals is, however, unknown. To assess the conservation of layer markers more broadly, we isolated orthologs for fifteen layer-enriched genes in the ferret, a carnivore with a large, gyrencephalic brain, and analyzed their patterns of neocortical gene expression. Our major findings are: (1) Many but not all layer markers tested show similar patterns of layer-specific gene expression between mouse and ferret cortex, supporting the view that layer-specific cell type identity is conserved at a molecular level across mammalian superorders; (2) Our panel of deep layer markers (ER81/ETV1, SULF2, PCP4, FEZF2/ZNF312, CACNA1H, KCNN2/SK2, SYT6, FOXP2, CTGF) provides molecular evidence that the specific stratifications of layer 5 and 6 into 5a, 5b, 6a and 6b are also conserved between rodents and carnivores. (3) Variations in layer-specific gene expression are more pronounced across areas of ferret cortex than between homologous areas of mouse and ferret cortex; (4) This variation of area gene expression was clearest with the superficial layer markers studied (SERPINE2, MDGA1, CUX1, UNC5D, RORB/NR1F2, EAG2/KCNH5). Most dramatically, the layer 4 markers RORB and EAG2 disclosed a molecular sublamination to ferret visual cortex and demonstrated a molecular dissociation among the so-called agranular areas of the neocortex. Our findings establish molecular markers as a powerful complement to cytoarchitecture for neocortical layer and cell-type comparisons across mammals. PMID:20575059

  17. Mirror instability and origin of morningside auroral structure

    NASA Technical Reports Server (NTRS)

    Chiu, Y. T.; Schulz, M.; Fennell, J. F.; Kishi, A. M.

    1983-01-01

    Auroral optical imagery shows marked differences between auroral features of the evening and morning sectors: the separation between diffuse and discrete auroras in the evening sector is not distinct in the morning sector, which is dominated by auroral patches and multiple banded structures aligned along some direction. Plasma distribution function signatures also show marked differences: downward electron beams and inverted-V signatures prefer the evening sector, while the electron spectra on the morning sector are similar to the diffuse aurora. A theory of morningside auroras consistent with these features was constructed. The theory is based on modulation of the growth rates of electron cyclotron waves by the mirror instability, which is in turn driven by inward-convected ions that have become anisotropic. This modulation produces alternating bands of enhanced and reduced electron precipitation which approximate the observed multiple auroral bands and patches of the morning sector.

  18. Structural Origin of Circularly Polarized Iridescence in Jeweled Beetles

    NASA Astrophysics Data System (ADS)

    Sharma, Vivek; Crne, Matija; Park, Jung Ok; Srinivasarao, Mohan

    2009-07-01

    The iridescent metallic green beetle, Chrysina gloriosa, which selectively reflects left circularly polarized light, possesses an exoskeleton decorated by hexagonal cells (~10 μm) that coexist with pentagons and heptagons. The fraction of hexagons decreases with an increase in curvature. In bright field microscopy, each cell contains a bright yellow core, placed in a greenish cell with yellowish border, but the core disappears in dark field. With use of confocal microscopy, we observe that these cells consist of nearly concentric nested arcs that lie on the surface of a shallow cone. We infer that the patterns are structurally and optically analogous to the focal conic domains formed spontaneously on the free surface of a cholesteric liquid crystal. These textures provide the basis for the morphogenesis as well as key insights for emulating the intricate optical response of the exoskeleton of scarab beetles.

  19. Structural origin of circularly polarized iridescence in jeweled beetles

    NASA Astrophysics Data System (ADS)

    Crne, Matija; Sharma, Vivek; Park, Jung O.; Srinivasarao, Mohan

    2010-03-01

    The iridescent metallic green beetle, Chrysina gloriosa, selectively reflects left circularly polarized light. The exoskeleton is decorated by hexagonal cells (˜10 micron) that coexist with pentagons and heptagons. We find that the fraction of hexagons decreases with an increase in curvature. In bright field microscopy, each cell contains a bright yellow core, placed in a greenish cell with yellowish border, but the core disappears in the dark field. Using confocal microscopy, we observe that these cells consist of nearly concentric, nested arcs that lie on surface of a shallow cone. We infer that the patterns are structurally and optically analogous to the focal conic domains formed spontaneously on the free surface of a cholesteric liquid crystal. The microstructure provides the bases for the morphogenesis as well as key insights for emulating the intricate optical response the exoskeleton of scarab beetles.

  20. Mirror instability and the origin of morningside auroral structure

    SciTech Connect

    Chiu, Y.T.; Schulz, M.; Fennell, J.F.; Kishi, A.M.

    1983-05-01

    Auroral optical imagery shows marked differences between auroral features of the evening and morning sectors: The separation between diffuse and discrete auroras in the evening sector is not distinct in the morning sector, which is dominated by auroral patches and multiple banded structures aligned along some direction. Plasma distribution function signatures also show marked differences: downward electron beams and inverted-V signatures prefer the evening sector, while the electron spectra on the morning sector are similar to the diffuse aurora. We have constructed a theory of morningside auroras consistent with these features. The theory is based on modulation of the growth rates of electron cyclotron waves by the mirror instability, which is in turn driven by inward-convected ions that have become anisotropic. This modulation produces alternating bands of enhanced and reduced electron precipitation which approximate the observed multiple auroral bands and patches of the morning sector.

  1. Origin of Permeability and Structure of Flows in Fractured Media

    NASA Astrophysics Data System (ADS)

    De Dreuzy, J.; Darcel, C.; Davy, P.; Erhel, J.; Le Goc, R.; Maillot, J.; Meheust, Y.; Pichot, G.; Poirriez, B.

    2013-12-01

    After more than three decades of research, flows in fractured media have been shown to result from multi-scale geological structures. Flows result non-exclusively from the damage zone of the large faults, from the percolation within denser networks of smaller fractures, from the aperture heterogeneity within the fracture planes and from some remaining permeability within the matrix. While the effect of each of these causes has been studied independently, global assessments of the main determinisms is still needed. We propose a general approach to determine the geological structures responsible for flows, their permeability and their organization based on field data and numerical modeling [de Dreuzy et al., 2012b]. Multi-scale synthetic networks are reconstructed from field data and simplified mechanical modeling [Davy et al., 2010]. High-performance numerical methods are developed to comply with the specificities of the geometry and physical properties of the fractured media [Pichot et al., 2010; Pichot et al., 2012]. And, based on a large Monte-Carlo sampling, we determine the key determinisms of fractured permeability and flows (Figure). We illustrate our approach on the respective influence of fracture apertures and fracture correlation patterns at large scale. We show the potential role of fracture intersections, so far overlooked between the fracture and the network scales. We also demonstrate how fracture correlations reduce the bulk fracture permeability. Using this analysis, we highlight the need for more specific in-situ characterization of fracture flow structures. Fracture modeling and characterization are necessary to meet the new requirements of a growing number of applications where fractures appear both as potential advantages to enhance permeability and drawbacks for safety, e.g. in energy storage, stimulated geothermal energy and non-conventional gas productions. References Davy, P., et al. (2010), A likely universal model of fracture scaling and

  2. Quantification of layered patterns with structural anisotropy: a comparison of biological and geological systems.

    PubMed

    Smolyar, I; Bromage, T; Wikelski, M

    2016-03-01

    Large-scale patterns evident from satellite images of aeolian landforms on Earth and other planets; those of intermediate scale in marine and terrestrial sand ripples and sediment profiles; and small-scale patterns such as lamellae in the bones of vertebrates and annuli in fish scales are each represented by layers of different thicknesses and lengths. Layered patterns are important because they form a record of the state of internal and external factors that regulate pattern formation in these geological and biological systems. It is therefore potentially possible to recognize trends, periodicities, and events in the history of the formation of these systems among the incremental sequences. Though the structures and sizes of these 2-D patterns are typically scale-free, they are also characteristically anisotropic; that is, the number of layers and their absolute thicknesses vary significantly during formation. The aim of the present work is to quantify the structure of layered patterns and to reveal similarities and differences in the processing and interpretation of layered landforms and biological systems. To reach this goal we used N-partite graph and Boolean functions to quantify the structure of layers and plot charts for "layer thickness vs. layer number" and "layer area vs. layer number". These charts serve as a source of information about events in the history of formation of layered systems. The concept of synchronization of layer formation across a 2-D plane is introduced to develop the procedure for plotting "layer thickness vs. layer number" and "layer area vs. layer number", which takes into account the structural anisotropy of layered patterns and increase signal-to-noise ratio in charts. Examples include landforms on Mars and Earth and incremental layers in human and iguana bones. PMID:27441261

  3. Enhancement of perpendicular magnetic anisotropy and transmission of spin-Hall-effect-induced spin currents by a Hf spacer layer in W/Hf/CoFeB/MgO layer structures

    SciTech Connect

    Pai, Chi-Feng; Nguyen, Minh-Hai; Vilela-Leão, Luis Henrique; Buhrman, R. A.; Belvin, Carina; Ralph, D. C.

    2014-02-24

    We report that strong perpendicular magnetic anisotropy of the ferromagnetic layer in a W/CoFeB/MgO multilayer structure can be established by inserting a Hf layer as thin as 0.25 nm between the W and CoFeB layers. The Hf spacer also allows transmission of spin currents generated by an in-plane charge current in the W layer to apply strong spin torque on the CoFeB, thereby enabling current-driven magnetic switching. The antidamping-like and field-like components of the spin torque exerted on a 1 nm CoFeB layer are of comparable magnitudes in this geometry. Both components originate from the spin Hall effect in the underlying W layer.

  4. Tunable Photonic Devices in Ferroelectric-Based Layered Structures

    NASA Astrophysics Data System (ADS)

    Xin, Jianzhuo

    This thesis presents the studies on the optical properties of perovskite ferroelectric thin films, as well as the preparation and applications of ferroelectrics in tunable photonic devices. Ba(Zr,Ti)O3 (BZT) thin films with different Zr concentration were grown on MgO substrates by pulsed laser deposition, and their structural and optical properties in the visible range were systematically characterized, including the out-of-plane lattice constant, grain size, refractive index, optical band gap energy, electro-optic coefficient, optical loss and absorption coefficient. The obtained results provide information for the design of BZT thin film-based optical devices. One-dimensional photonic crystal filter working in the terahertz (THz) range was studied. The transmission properties of SrTiO3 (STO) crystals were first characterized by THz time-domain spectroscopy. Si/STO multilayers with different STO defect thicknesses were designed by the transfer matrix method and then constructed by polishing and stacking. The shift of defect mode was observed and comparable with the calculations. Two-dimensional photonic structures in the optical and infra-red range were then attempted. A combination of nanoimprint lithography and inductively coupled plasma etching were investigated on (Ba,Sr)TiO3 thin films. Then, in order to simplify the nanoimprint process and allow thick metal sacrificial layer deposition for high aspect-ratio etching, a transfer imprint lithography technique was developed. Finally, surface plasmon resonance (SPR) tuning via thermally-induced refractive index changes in ferroelectrics was investigated. Ag stripes with periodicity 750 nm were fabricated on flat BST surface by nanoimprint lithography and subsequent lift-off. (-1), (2) and (-2) SP modes from Ag/BST interface were observed in visible range. Red shift of the modes up to 3.9 nm was obtained with increasing temperature. Then continuous Au film on corrugated BST surface with periodicity of 1 mum was

  5. [ICNP- International Classification of Nursing Practice: origin, structure and development].

    PubMed

    Marucci, Anna Rita; De Caro, Walter; Petrucci, Cristina; Lancia, Loreto; Sansoni, Julita

    2015-01-01

    ICNP is a standardized nursing terminology included within acknowledged terminologies by WHO, it is a relevant aspect of ICN programs and strategies. This paper aims to describe structure and characteristics of ICNP terminology as well as to highlight how this tool can be useful both in practice and in terms of nursing professional development. This version looks like a pyramid with seven axes describing different areas of nursing and related interventions, enriched by two special axes related to pre-coordinated Diagnosis / Outcomes (DC) and Operations (IC) which facilitate daily use in practice. In order to clarify how this tool can be actually be used in daily nursing practice some examples are provided, clarifying how adopting the current version of ICNP terminology (2015 release) Diagnosis/Outcomes and Interventions can be built. The ICNP Italian Centre is committed to introduce it to Italian nurses as a tool for sharing and disseminating terminology in our Country, having as main final aim to achieve even in Italy, professional visibility objectives promoted in different ways by the International Council of Nurses. PMID:26402233

  6. THE STRUCTURE, ORIGIN, AND EVOLUTION OF INTERSTELLAR HYDROCARBON GRAINS

    SciTech Connect

    Chiar, J. E.; Ricca, A.; Tielens, A. G. G. M.; Adamson, A. J. E-mail: Alessandra.Ricca@1.nasa.gov E-mail: aadamson@gemini.edu

    2013-06-10

    Many materials have been considered for the carrier of the hydrocarbon absorption bands observed in the diffuse interstellar medium (ISM). In order to refine the model for ISM hydrocarbon grains, we analyze the observed aromatic (3.28, 6.2 {mu}m) and aliphatic (3.4 {mu}m) hydrocarbon absorption features in the diffuse ISM along the line of sight toward the Galactic center Quintuplet Cluster. Observationally, sp {sup 2} bonds can be measured in astronomical spectra using the 6.2 {mu}m CC aromatic stretch feature, whereas the 3.4 {mu}m aliphatic feature can be used to quantify the fraction of sp {sup 3} bonds. The fractional abundance of these components allows us to place the Galactic diffuse ISM hydrocarbons on a ternary phase diagram. We conclude that the Galactic hydrocarbon dust has, on average, a low H/C ratio and sp {sup 3} content and is highly aromatic. We have placed the results of our analysis within the context of the evolution of carbon dust in the ISM. We argue that interstellar carbon dust consists of a large core of aromatic carbon surrounded by a thin mantle of hydrogenated amorphous carbon (a-C:H), a structure that is a natural consequence of the processing of stardust grains in the ISM.

  7. Communication: Origin of the contributions to DNA structure in phages

    PubMed Central

    Myers, Christopher G.; Pettitt, B. Montgomery

    2013-01-01

    Cryo electron microscopy (cryo-EM) data of the interior of phages show ordering of the interior DNA that has been interpreted as a nearly perfectly ordered polymer. We show surface-induced correlations, excluded volume, and electrostatic forces are sufficient to predict most of the major features of the current structural data for DNA packaged within viral capsids without additional ordering due to elastic bending forces for the polymer. Current models assume highly-ordered, even spooled, hexagonally packed conformations based on interpretation of cryo-EM density maps. We show herein that the surface induced packing of short (6mer), unconnected DNA polymer segments is the only necessary ingredient in creating ringed densities consistent with experimental density maps. This implies the ensemble of possible conformations of polymeric DNA within the capsid that are consistent with cryo-EM data may be much larger than implied by traditional interpretations where such rings can only result from highly-ordered spool-like conformations. This opens the possibility of a more disordered, entropically-driven view of phage packaging thermodynamics. We also show the electrostatics of the DNA contributes a large portion of the internal hydrostatic and osmotic pressures of a phage virion, suggesting that nonlinear elastic anomalies might reduce the overall elastic bending enthalpy of more disordered conformations to have allowable free energies. PMID:23444988

  8. Communication: Origin of the contributions to DNA structure in phages

    NASA Astrophysics Data System (ADS)

    Myers, Christopher G.; Pettitt, B. Montgomery

    2013-02-01

    Cryo electron microscopy (cryo-EM) data of the interior of phages show ordering of the interior DNA that has been interpreted as a nearly perfectly ordered polymer. We show surface-induced correlations, excluded volume, and electrostatic forces are sufficient to predict most of the major features of the current structural data for DNA packaged within viral capsids without additional ordering due to elastic bending forces for the polymer. Current models assume highly-ordered, even spooled, hexagonally packed conformations based on interpretation of cryo-EM density maps. We show herein that the surface induced packing of short (6mer), unconnected DNA polymer segments is the only necessary ingredient in creating ringed densities consistent with experimental density maps. This implies the ensemble of possible conformations of polymeric DNA within the capsid that are consistent with cryo-EM data may be much larger than implied by traditional interpretations where such rings can only result from highly-ordered spool-like conformations. This opens the possibility of a more disordered, entropically-driven view of phage packaging thermodynamics. We also show the electrostatics of the DNA contributes a large portion of the internal hydrostatic and osmotic pressures of a phage virion, suggesting that nonlinear elastic anomalies might reduce the overall elastic bending enthalpy of more disordered conformations to have allowable free energies.

  9. Contrasting 1D tunnel-structured and 2D layered polymorphs of V2O5: relating crystal structure and bonding to band gaps and electronic structure.

    PubMed

    Tolhurst, Thomas M; Leedahl, Brett; Andrews, Justin L; Marley, Peter M; Banerjee, Sarbajit; Moewes, Alexander

    2016-06-21

    New V2O5 polymorphs have risen to prominence as a result of their open framework structures, cation intercalation properties, tunable electronic structures, and wide range of applications. The application of these materials and the design of new, useful polymorphs requires understanding their defining structure-property relationships. We present a characterization of the band gap and electronic structure of nanowires of the novel ζ-phase and the orthorhombic α-phase of V2O5 using X-ray spectroscopy and density functional theory calculations. The band gap is found to decrease from 1.90 ± 0.20 eV in the α-phase to 1.50 ± 0.20 eV in the ζ-phase, accompanied by the loss of the α-phase's characteristic split-off dxy band in the ζ-phase. States of dxy origin continue to dominate the conduction band edge in the new polymorph but the inequivalence of the vanadium atoms and the increased local symmetry of [VO6] octahedra results in these states overlapping with the rest of the V 3d conduction band. ζ-V2O5 exhibits anisotropic conductivity along the b direction, defining a 1D tunnel, in contrast to α-V2O5 where the anisotropic conductivity is along the ab layers. We explain the structural origins of the differences in electronic properties that exist between the α- and ζ-phase. PMID:27230816

  10. Inhibition of structural changes in the simian virus 40 core origin of replication by mutation of essential origin sequences.

    PubMed Central

    Borowiec, J A

    1992-01-01

    Mutation of the simian virus 40 (SV40) origin of replication (ori) has revealed the presence of three critical domains needed for DNA replication. The outer two domains, the AT tract and early palindrome element (EP), colocalize with DNA regions that become structurally altered in the presence of the SV40 large tumor antigen (T antigen) and ATP. Mutations within each domain were examined for their effect on the distortion of ori DNA by T antigen, as assayed by the sensitivity of DNA to KMnO4 oxidation. We have found that mutations in the AT tract that inhibit SV40 DNA replication also inhibit the distortion of the AT tract. Similarly, mutations in the EP inhibited the generation of structural changes in this element by T antigen. Although AT-tract mutations or mutations on the late side of ori affected structural changes only in the AT tract, certain EP mutations or mutations on the early side of ori also inhibited AT-tract distortion. Mutation of the flanking regions did not significantly affect either the affinity of T antigen for ori or the rate of binding to ori. We conclude from these results that the primary function of the flanking ori domains is to undergo structural changes required during the initiation of SV40 DNA replication. Moreover, our results suggest that the efficiency of replication initiation is significantly affected by the degree to which the flanking elements undergo a structural transition. Images PMID:1323692

  11. Effect of low-temperature annealing on the electronic- and band-structures of (Ga,Mn)As epitaxial layers

    NASA Astrophysics Data System (ADS)

    Yastrubchak, O.; Wosinski, T.; Gluba, L.; Andrearczyk, T.; Domagala, J. Z.; Żuk, J.; Sadowski, J.

    2014-01-01

    The effect of outdiffusion of Mn interstitials from (Ga,Mn)As epitaxial layers, caused by post-growth low-temperature annealing, on their electronic- and band-structure properties has been investigated by modulation photoreflectance (PR) spectroscopy. The annealing-induced changes in structural and magnetic properties of the layers were examined with high-resolution X-ray diffractometry and superconducting quantum interference device magnetometry, respectively. They confirmed an outdiffusion of Mn interstitials from the layers and an enhancement in their hole concentration, which were more efficient for the layer covered with a Sb cap acting as a sink for diffusing Mn interstitials. The PR results demonstrating a decrease in the band-gap-transition energy in the as-grown (Ga,Mn)As layers, with respect to that in the reference GaAs one, are interpreted by assuming a merging of the Mn-related impurity band with the GaAs valence band. Whereas an increase in the band-gap-transition energy caused by the annealing treatment of the (Ga,Mn)As layers is interpreted as a result of annealing-induced enhancement of the free-hole concentration and the Fermi level location within the valence band. The experimental results are consistent with the valence-band origin of itinerant holes mediating ferromagnetic ordering in (Ga,Mn)As, in agreement with the Zener model for ferromagnetic semiconductors.

  12. Effect of low-temperature annealing on the electronic- and band-structures of (Ga,Mn)As epitaxial layers

    SciTech Connect

    Yastrubchak, O. Gluba, L.; Żuk, J.; Wosinski, T. Andrearczyk, T.; Domagala, J. Z.; Sadowski, J.

    2014-01-07

    The effect of outdiffusion of Mn interstitials from (Ga,Mn)As epitaxial layers, caused by post-growth low-temperature annealing, on their electronic- and band-structure properties has been investigated by modulation photoreflectance (PR) spectroscopy. The annealing-induced changes in structural and magnetic properties of the layers were examined with high-resolution X-ray diffractometry and superconducting quantum interference device magnetometry, respectively. They confirmed an outdiffusion of Mn interstitials from the layers and an enhancement in their hole concentration, which were more efficient for the layer covered with a Sb cap acting as a sink for diffusing Mn interstitials. The PR results demonstrating a decrease in the band-gap-transition energy in the as-grown (Ga,Mn)As layers, with respect to that in the reference GaAs one, are interpreted by assuming a merging of the Mn-related impurity band with the GaAs valence band. Whereas an increase in the band-gap-transition energy caused by the annealing treatment of the (Ga,Mn)As layers is interpreted as a result of annealing-induced enhancement of the free-hole concentration and the Fermi level location within the valence band. The experimental results are consistent with the valence-band origin of itinerant holes mediating ferromagnetic ordering in (Ga,Mn)As, in agreement with the Zener model for ferromagnetic semiconductors.

  13. Origin, Internal Structure and Evolution of 4 Vesta

    NASA Astrophysics Data System (ADS)

    Zuber, Maria T.; McSween, Harry Y.; Binzel, Richard P.; Elkins-Tanton, Linda T.; Konopliv, Alexander S.; Pieters, Carle M.; Smith, David E.

    2011-12-01

    Asteroid 4 Vesta is the only preserved intact example of a large, differentiated protoplanet like those believed to be the building blocks of terrestrial planet accretion. Vesta accreted rapidly from the solar nebula in the inner asteroid belt and likely melted due to heat released due to the decay of 26Al. Analyses of meteorites from the howardite-eucrite-diogenite (HED) suite, which have been both spectroscopically and dynamically linked to Vesta, lead to a model of the asteroid with a basaltic crust that overlies a depleted peridotitic mantle and an iron core. Vesta’s crust may become more mafic with depth and might have been intruded by plutons arising from mantle melting. Constraints on the asteroid’s moments of inertia from the long-wavelength gravity field, pole position and rotation, informed by bulk composition estimates, allow tradeoffs between mantle density and core size; cores of up to half the planetary radius can be consistent with plausible mantle compositions. The asteroid’s present surface is expected to consist of widespread volcanic terrain, modified extensively by impacts that exposed the underlying crust or possibly the mantle. Hemispheric heterogeneity has been observed by poorly resolved imaging of the surface that suggests the possibility of a physiographic dichotomy as occurs on other terrestrial planets. Vesta might have had an early magma ocean but details of the early thermal structure are far from clear owing to model uncertainties and paradoxical observations from the HEDs. Petrological analysis of the eucrites coupled with thermal evolution modeling recognizes two possible mechanisms of silicate-metal differentiation leading to the formation of the basaltic achondrites: equilibrium partial melting or crystallization of residual liquid from the cooling magma ocean. A firmer understanding the plethora of complex physical and chemical processes that contribute to melting and crystallization will ultimately be required to

  14. Charge carrier transport properties in layer structured hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Doan, T. C.; Li, J.; Lin, J. Y.; Jiang, H. X.

    2014-10-01

    Due to its large in-plane thermal conductivity, high temperature and chemical stability, large energy band gap (˜ 6.4 eV), hexagonal boron nitride (hBN) has emerged as an important material for applications in deep ultraviolet photonic devices. Among the members of the III-nitride material system, hBN is the least studied and understood. The study of the electrical transport properties of hBN is of utmost importance with a view to realizing practical device applications. Wafer-scale hBN epilayers have been successfully synthesized by metal organic chemical deposition and their electrical transport properties have been probed by variable temperature Hall effect measurements. The results demonstrate that undoped hBN is a semiconductor exhibiting weak p-type at high temperatures (> 700 °K). The measured acceptor energy level is about 0.68 eV above the valence band. In contrast to the electrical transport properties of traditional III-nitride wide bandgap semiconductors, the temperature dependence of the hole mobility in hBN can be described by the form of μ ∝ (T/T0)-α with α = 3.02, satisfying the two-dimensional (2D) carrier transport limit dominated by the polar optical phonon scattering. This behavior is a direct consequence of the fact that hBN is a layer structured material. The optical phonon energy deduced from the temperature dependence of the hole mobility is ħω = 192 meV (or 1546 cm-1), which is consistent with values previously obtained using other techniques. The present results extend our understanding of the charge carrier transport properties beyond the traditional III-nitride semiconductors.

  15. Inner Plasma Structure of the Low-Latitude Reconnection Layer

    NASA Technical Reports Server (NTRS)

    Zhang, Q.-H.; Dunlop, M. W.; Lockwood, M.; Lavraud, B.; Bogdanova, Y. V.; Hasegawa, H.; Yang, H. -G.; Liu, R. -Y.; Hu, H. -Q.; Zhang, B. -C.; Pu, Z. -Y.; Yang, Z. -W.; Wang, J.; Taylor, M. G. G. T.; Berchem, J.; Constantinescu, D.; Volwerk, M.; Frey, H.; Fazakerley, A. N.; Shen, C.; Shi, J. -K.; Sibeck, D.; Escoubet, P.; Wild, J. A.

    2012-01-01

    We report a clear transition through a reconnection layer at the low-latitude magnetopause which shows a complete traversal across all reconnected field lines during northwestward interplanetary magnetic field (IMF) conditions. The associated plasma populations confirm details of the electron and ion mixing and the time history and acceleration through the current layer. This case has low magnetic shear with a strong guide field and the reconnection layer contains a single density depletion layer on the magnetosheath side which we suggest results from nearly field-aligned magnetosheath flows. Within the reconnection boundary layer, there are two plasma boundaries, close to the inferred separatrices on the magnetosphere and magnetosheath sides (Ssp and Ssh) and two boundaries associated with the Alfvén waves (or Rotational Discontinuities, RDsp and RDsh). The data are consistent with these being launched from the reconnection site and the plasma distributions are well ordered and suggestive of the time elapsed since reconnection of the field lines observed. In each sub-layer between the boundaries the plasma distribution is different and is centered around the current sheet, responsible for magnetosheath acceleration. We show evidence for a velocity dispersion effect in the electron anisotropy that is consistent with the time elapsed since reconnection. In addition, new evidence is presented for the occurrence of partial reflection of magnetosheath electrons at the magnetopause current layer.

  16. Structure of turbulence in three-dimensional boundary layers

    NASA Technical Reports Server (NTRS)

    Subramanian, Chelakara S.

    1993-01-01

    This report provides an overview of the three dimensional turbulent boundary layer concepts and of the currently available experimental information for their turbulence modeling. It is found that more reliable turbulence data, especially of the Reynolds stress transport terms, is needed to improve the existing modeling capabilities. An experiment is proposed to study the three dimensional boundary layer formed by a 'sink flow' in a fully developed two dimensional turbulent boundary layer. Also, the mean and turbulence field measurement procedure using a three component laser Doppler velocimeter is described.

  17. Surface ozone-aerosol behaviour and atmospheric boundary layer structure in Saharan dusty scenario

    NASA Astrophysics Data System (ADS)

    Adame, Jose; Córdoba-Jabonero, Carmen; Sorrribas, Mar; Gil-Ojeda, Manuel; Toledo, Daniel; Yela, Margarita

    2016-04-01

    A research campaign was performed for the AMISOC (Atmospheric Minor Species relevant to the Ozone Chemistry) project at El Arenosillo observatory (southwest Spain) in May-June 2012. The campaign focused on the impact of Saharan dust intrusions at the Atmospheric Boundary Layer (ABL) and ozone-aerosol interactions. In-situ and remote-sensing techniques for gases and aerosols were used moreover to modelling analyses. Meteorology features, ABL structures and evolution, aerosol profiling distributions and aerosol-ozone interactions on the surface were analysed. Two four-day periods were selected according to non-dusty (clean conditions) and dusty (Saharan dust) situations. In both scenarios, sea-land breezes developed in the lower atmosphere, but differences were found in the upper levels. Results show that surface temperatures were greater than 3°C and humidity values were lower during dusty conditions than non-dusty conditions. Thermal structures on the surface layer (estimated using an instrument on a 100 m tower) show differences, mainly during nocturnal periods with less intense inversions under dusty conditions. The mixing layer during dusty days was 400-800 m thick, less than observed on non-dusty days. Dust also disturbed the typical daily ABL evolution. Stable conditions were observed during the early evening during intrusions. Aerosol extinction on dusty days was 2-3 times higher, and the dust was confined between 1500 and 5500 m. Back trajectory analyses confirmed that the dust had an African origin. On the surface, the particle concentration was approximately 3.5 times higher during dusty events, but the local ozone did not exhibit any change. The arrival of Saharan dust in the upper levels impacted the meteorological surface, inhibited the daily evolution of the ABL and caused an increase in aerosol loading on the surface and at higher altitudes; however, no dust influence was observed on surface ozone.

  18. Origin and evolution of protein fold designs inferred from phylogenomic analysis of CATH domain structures in proteomes.

    PubMed

    Bukhari, Syed Abbas; Caetano-Anollés, Gustavo

    2013-01-01

    The spatial arrangements of secondary structures in proteins, irrespective of their connectivity, depict the overall shape and organization of protein domains. These features have been used in the CATH and SCOP classifications to hierarchically partition fold space and define the architectural make up of proteins. Here we use phylogenomic methods and a census of CATH structures in hundreds of genomes to study the origin and diversification of protein architectures (A) and their associated topologies (T) and superfamilies (H). Phylogenies that describe the evolution of domain structures and proteomes were reconstructed from the structural census and used to generate timelines of domain discovery. Phylogenies of CATH domains at T and H levels of structural abstraction and associated chronologies revealed patterns of reductive evolution, the early rise of Archaea, three epochs in the evolution of the protein world, and patterns of structural sharing between superkingdoms. Phylogenies of proteomes confirmed the early appearance of Archaea. While these findings are in agreement with previous phylogenomic studies based on the SCOP classification, phylogenies unveiled sharing patterns between Archaea and Eukarya that are recent and can explain the canonical bacterial rooting typically recovered from sequence analysis. Phylogenies of CATH domains at A level uncovered general patterns of architectural origin and diversification. The tree of A structures showed that ancient structural designs such as the 3-layer (αβα) sandwich (3.40) or the orthogonal bundle (1.10) are comparatively simpler in their makeup and are involved in basic cellular functions. In contrast, modern structural designs such as prisms, propellers, 2-solenoid, super-roll, clam, trefoil and box are not widely distributed and were probably adopted to perform specialized functions. Our timelines therefore uncover a universal tendency towards protein structural complexity that is remarkable. PMID:23555236

  19. The current structure of stratified tidal planetary boundary layer flow

    SciTech Connect

    Myrhaug, D.; Slaattelid, O.H.

    1995-12-31

    The paper presents the bottom shear stress and velocity profiles in stratified tidal planetary boundary layer flow by using similarity theory. For a given seabed roughness length, free stream current velocity components, frequency of tidal oscillation, Coriolis parameter and stratification parameter the maximum bottom shear stress is determined for flow conditions in the rough, smooth and transitional smooth-to-rough turbulent regime. Further, the direction of the bottom shear stress and the velocity profiles are given. Comparison is made with data from field measurements of time-independent as well as tidal planetary boundary layer flow for neutral conditions, and the agreement between the predictions and the data is generally good. Further, an example of application for stable stratification is given, and qualitatively the predictions show, as expected, that the bottom shear stress and the thickness of the boundary layer become smaller for stable than for neutral stratification. Other features of the tidal planetary boundary layer flow are also discussed.

  20. Structure and Growth of the Marine Boundary Layer

    NASA Technical Reports Server (NTRS)

    Mccumber, M.

    1984-01-01

    LANDSAT visible imagery and a one-dimensional Lagrangian boundary layer model were used to hypothesize the nature and the development of the marine boundary layer during a winter episode of strong seaward cold air advection. Over-water heating and moistening of the cold, dry continental air is estimable from linear relations involving horizontal gradients of the near-surface air temperature and humidity. A line of enhanced convection paralleling the Atlantic U.S. coast from south of New York Bay to the vicinity of Virginia Beach, VA was attributed to stronger convergence at low levels. This feature was characterized as a mesoscale front. With the assistance of a three-dimensional mesoscale boundary layer model, initialized with data obtained from the MASEX, the marine boundary layer can be mapped over the entire Atlantic coastal domain and the evolution of the boundary layer can be studied as a function of different characteristics of important surface level forcings. The effects on boundary layer growth due to the magnitude and pattern of sea surface temperature, to the shape of the coastline, and to atmospheric conditions, such as the orientation of the prevailing wind are examined.

  1. Origin of non-spherical particles in the boundary layer over Beijing, China: based on balloon-borne observations.

    PubMed

    Chen, Bin; Yamada, Maromu; Iwasaka, Yasunobu; Zhang, Daizhou; Wang, Hong; Wang, Zhenzhu; Lei, Hengchi; Shi, Guangyu

    2015-10-01

    Vertical structures of aerosols from the ground to about 1,000 m altitude in Beijing were measured with a balloon-borne optical particle counter. The results showed that, in hazy days, there were inversions at approximately 500-600 m, below which the particulate matters were well mixed vertically, while the concentration of particles decreased sharply above the mixing layer. Electron microscopic observation of the particles collected with the balloon-borne impactor indicates that the composition of particles is different according to weather conditions in the boundary mixing layer of Beijing city and suggests that dust particles are always dominant in coarse-mode particles. Interestingly, sea-salt particles are frequently identified, suggesting the importance of marine air inflow to the Beijing area even in summer. The Ca-rich spherical particles are also frequently identified, suggesting chemical modification of dust particle by NOx or emission of CaO and others from local emission. Additionally, those types of particles showed higher concentration above the mixing layer under the relatively calm weather condition of summer, suggesting the importance of local-scale convection found in summer which rapidly transported anthropogenic particles above the mixing layer. Lidar extinction profiles qualitatively have good consistency with the balloon-borne measurements. Attenuation effects of laser pulse intensity are frequently observed due to high concentration of particulate matter in the Beijing atmosphere, and therefore quantitative agreement of lidar return and aerosol concentration can be hardly observed during dusty condition. Comparing the depolarization ratio obtained from the lidar measurements with the balloon-borne measurements, the contribution of the dry sea-salt particles, in addition to the dust particles, is suggested as an important factor causing depolarization ratio in the Beijing atmosphere. PMID:25537163

  2. Acoustic double layer structures in dense magnetized electron-positron-ion plasmas

    SciTech Connect

    Akhtar, N.; Mahmood, S.

    2011-11-15

    The acoustic double layer structures are studied using quantum hydrodynamic model in dense magnetized electron-positron-ion plasmas. The extended Korteweg-de Vries is derived using reductive perturbation method. It is found that increase in the ion concentration in dense magnetized electron-positron plasmas increases the amplitude as well as the steepness of the double layer structure. However, increase in the magnetic field strength and decrease in the obliqueness of the nonlinear acoustic wave enhances only the steepness of the double layer structures. The numerical results have also been shown by using the data of the outer layer regions of white dwarfs given in the literature.

  3. The Time-Dependent Structure of the Electron Reconnection Layer

    NASA Technical Reports Server (NTRS)

    Hesse, Michael; Zenitani, Seiji; Kuznetsova, Masha; Klimas, Alex

    2009-01-01

    Collisionless magnetic reconnection is often associated with time-dependent behavior. Specifically, current layers in the diffusion region can become unstable to tearing-type instabilities on one hand, or to instabilities with current-aligned wave vectors on the other. In the former case, the growth of tearing instabilities typically leads to the production of magnetic islands, which potentially provide feedback on the reconnection process itself, as well as on the rate of reconnection. The second class of instabilities tend to modulate the current layer along the direction of the current flow, for instance generating kink-type perturbations, or smaller-scale turbulence with the potential to broaden the current layer. All of these processes contribute to rendering magnetic reconnection time-dependent. In this presentation, we will provide a summary of these effects, and a discussion of how much they contribute to the overall magnetic reconnection rate.

  4. Electromagnetic structure of the magnetopause and boundary layer

    NASA Technical Reports Server (NTRS)

    Sonnerup, B. U. O.; Ledley, B. G.

    1979-01-01

    After a review of the properties and predictions of the closed and open models of the magnetopause, OGO-5 magnetometer data are used to illustrate various observed signatures of the magnetopause current layer and the adjacent plasma boundary layer. Among the topics touched upon are: fluctuations, diamagnetic effects, and field aligned currents in the boundary layer; one dimensionality of the magnetopause; presence and absence of a magnetic field component perpendicular to the magnetopause; finite ion gyroradius effects. A brief summary is given of existing Vlasov theory for the description of tangential, rotational, and contact discontinuities. Special attention is paid to the tangential momentum balance and the jump conditions at a rotational discontinuity. Low frequency fluctuations are discussed with emphasis on the signatures of the tearing mode.

  5. Porous Materials with Tunable Structure and Mechanical Properties via Templated Layer-by-Layer Assembly.

    PubMed

    Ziminska, Monika; Dunne, Nicholas; Hamilton, Andrew R

    2016-08-31

    The deposition of stiff and strong coatings onto porous templates offers a novel strategy for fabricating macroscale materials with controlled architectures at the micro- and nanoscale. Here, layer-by-layer assembly is utilized to fabricate nanocomposite-coated foams with highly customizable properties by depositing polymer-nanoclay coatings onto open-cell foam templates. The compressive mechanical behavior of these materials evolves in a predictable manner that is qualitatively captured by scaling laws for the mechanical properties of cellular materials. The observed and predicted properties span a remarkable range of density-stiffness space, extending from regions of very soft elastomer foams to very stiff, lightweight honeycomb and lattice materials. PMID:27513218

  6. The origin of oil in the Cretaceous succession from the South Pars Oil Layer of the Persian Gulf

    NASA Astrophysics Data System (ADS)

    Rahmani, Omeid; Aali, Jafar; Junin, Radzuan; Mohseni, Hassan; Padmanabhan, Eswaran; Azdarpour, Amin; Zarza, Sahar; Moayyed, Mohsen; Ghazanfari, Parviz

    2013-07-01

    The origin of the oil in Barremian-Hauterivian and Albian age source rock samples from two oil wells (SPO-2 and SPO-3) in the South Pars oil field has been investigated by analyzing the quantity of total organic carbon (TOC) and thermal maturity of organic matter (OM). The source rocks were found in the interval 1,000-1,044 m for the Kazhdumi Formation (Albian) and 1,157-1,230 m for the Gadvan Formation (Barremian-Hauterivian). Elemental analysis was carried out on 36 samples from the source rock candidates (Gadvan and Kazhdumi formations) of the Cretaceous succession of the South Pars Oil Layer (SPOL). This analysis indicated that the OM of the Barremian-Hauterivian and Albian samples in the SPOL was composed of kerogen Types II and II-III, respectively. The average TOC of analyzed samples is less than 1 wt%, suggesting that the Cretaceous source rocks are poor hydrocarbon (HC) producers. Thermal maturity and Ro values revealed that more than 90 % of oil samples are immature. The source of the analyzed samples taken from Gadvan and Kazhdumi formations most likely contained a content high in mixed plant and marine algal OM deposited under oxic to suboxic bottom water conditions. The Pristane/nC17 versus Phytane/nC18 diagram showed Type II-III kerogen of mixture environments for source rock samples from the SPOL. Burial history modeling indicates that at the end of the Cretaceous time, pre-Permian sediments remained immature in the Qatar Arch. Therefore, lateral migration of HC from the nearby Cretaceous source rock kitchens toward the north and south of the Qatar Arch is the most probable origin for the significant oils in the SPOL.

  7. The secondary structure and the thermal unfolding parameters of the S-layer protein from Lactobacillus salivarius.

    PubMed

    Lighezan, Liliana; Georgieva, Ralitsa; Neagu, Adrian

    2016-09-01

    Surface layer (S-layer) proteins have been identified in the cell envelope of many organisms, such as bacteria and archaea. They self-assemble, forming monomolecular crystalline arrays. Isolated S-layer proteins are able to recrystallize into regular lattices, which proved useful in biotechnology. Here we investigate the structure and thermal unfolding of the S-layer protein isolated from Lactobacillus salivarius 16 strain of human origin. Using circular dichroism (CD) spectroscopy, and the software CDSSTR from DICHROWEB, CONTINLL from CDPro, as well as CDNN, we assess the fractions of the protein's secondary structural elements at temperatures ranging between 10 and 90 °C, and predict the tertiary class of the protein. To study the thermal unfolding of the protein, we analyze the temperature dependence of the CD signal in the far- and near-UV domains. Fitting the experimental data by two- and three-state models of thermal unfolding, we infer the midpoint temperatures, the temperature dependence of the changes in Gibbs free energy, enthalpy, and entropy of the unfolding transitions in standard conditions, and the temperature dependence of the equilibrium constant. We also estimate the changes in heat capacity at constant pressure in standard conditions. The results indicate that the thermal unfolding of the S-layer protein from L. salivarius is highly cooperative, since changes in the secondary and tertiary structures occur simultaneously. The thermodynamic analysis predicts a "cold" transition, at about -3 °C, of both the secondary and tertiary structures. Our findings may be important for the use of S-layer proteins in biotechnology and in biomedical applications. PMID:26992716

  8. On the origin of mixed-layered clay minerals from the San Andreas Fault at 2.5-3 km vertical depth (SAFOD drillhole at Parkfield, California)

    NASA Astrophysics Data System (ADS)

    Schleicher, A. M.; Warr, L. N.; van der Pluijm, B. A.

    2009-02-01

    A detailed mineralogical study is presented of the matrix of mudrocks sampled from spot coring at three key locations along the San Andreas Fault Observatory at depth (SAFOD) drill hole. The characteristics of authigenic illite-smectite (I-S) and chlorite-smectite (C-S) mixed-layer mineral clays indicate a deep diagenetic origin. A randomly ordered I-S mineral with ca. 20-25% smectite layers is one of the dominant authigenic clay species across the San Andreas Fault zone (sampled at 3,066 and 3,436 m measured depths/MD), whereas an authigenic illite with ca. 2-5% smectite layers is the dominant phase beneath the fault (sampled at 3,992 m MD). The most smectite-rich mixed-layered assemblage with the highest water content occurs in the actively deforming creep zone at ca. 3,300-3,353 m (true vertical depth of ca. 2.7 km), with I-S (70:30) and C-S (50:50). The matrix of all mudrock samples show extensive quartz and feldspar (both plagioclase and K-feldspar) dissolution associated with the crystallization of pore-filling clay minerals. However, the effect of rock deformation in the matrix appears only minor, with weak flattening fabrics defined largely by kinked and fractured mica grains. Adopting available kinetic models for the crystallization of I-S in burial sedimentary environments and the current borehole depths and thermal structure, the conditions and timing of I-S growth can be evaluated. Assuming a typical K+ concentration of 100-200 ppm for sedimentary brines, a present-day geothermal gradient of 35°C/km and a borehole temperature of ca. 112°C for the sampled depths, most of the I-S minerals can be predicted to have formed over the last 4-11 Ma and are probably still in equilibrium with circulating fluids. The exception to this simple burial pattern is the occurrence of the mixed layered phases with higher smectite content than predicted by the burial model. These minerals, which characterize the actively creeping section of the fault and local thin film

  9. Turbine airfoil with dual wall formed from inner and outer layers separated by a compliant structure

    DOEpatents

    Campbell; Christian X. , Morrison; Jay A.

    2011-12-20

    A turbine airfoil usable in a turbine engine with a cooling system and a compliant dual wall configuration configured to enable thermal expansion between inner and outer layers while eliminating stress formation is disclosed. The compliant dual wall configuration may be formed a dual wall formed from inner and outer layers separated by a compliant structure. The compliant structure may be configured such that the outer layer may thermally expand without limitation by the inner layer. The compliant structure may be formed from a plurality of pedestals positioned generally parallel with each other. The pedestals may include a first foot attached to a first end of the pedestal and extending in a first direction aligned with the outer layer, and may include a second foot attached to a second end of the pedestal and extending in a second direction aligned with the inner layer.

  10. Local structure of Fe in Fe-doped misfit-layered calcium cobaltite: An X-ray absorption spectroscopy study

    SciTech Connect

    Prasoetsopha, Natkrita; Pinitsoontorn, Supree; Bootchanont, Atipong; Kidkhunthod, Pinit; Srepusharawoot, Pornjuk; Kamwanna, Teerasak; Amornkitbamrung, Vittaya; Kurosaki, Ken; Yamanaka, Shinsuke

    2013-08-15

    Polycrystalline Ca{sub 3}Co{sub 4−x}Fe{sub x}O{sub 9+δ} ceramics (x=0, 0.01, 0.03, 0.05) were fabricated using a simple thermal hydro-decomposition method and a spark plasma sintering technique. Thermoelectric property measurements showed that increasing Fe concentration resulted in a decrease in electrical resistivity, thermopower and thermal conductivity, leading to an improvement in the dimensionless figure-of-merit, >35% for x=0.05 at 1073 K. An X-ray absorption spectroscopy technique was used to investigate the local structure of Fe ions in the Ca{sub 3}Co{sub 4−x}Fe{sub x}O{sub 9+δ} structure for the first time. By fitting data from the extended X-ray absorption fine structure (EXAFS) spectra and analyzing the X-ray absorption near-edge structure (XANES) spectra incorporated with first principle simulation, it was shown that Fe was substituted for Co in the the Ca{sub 2}CoO{sub 3} (rocksalt, RS) layer rather than in the CoO{sub 2} layer. Variation in the thermoelectric properties as a function of Fe concentration was attributed to charge transfer between the CoO{sub 2} and the RS layers. The origin of the preferential Fe substitution site was investigated considering the ionic radii of Co and Fe and the total energy of the system. - Graphical abstract: The Fe K-edge XANES spectra of: (a) experimental result in comparison to the simulated spectra when Fe atoms were substituted in the RS layer; (b) with magnetic moment; (c) without magnetic moment, and in the CoO{sub 2} layer; (d) with magnetic moment and (e) without magnetic moment. Highlights: • Synthesis, structural studies, and thermoelectric properties of Ca{sub 3}Co{sub 4−x}Fe{sub x}O{sub 9+δ}. • Direct evidence for the local structure of the Fe ions in the Ca{sub 3}Co{sub 4−x}Fe{sub x}O{sub 9+δ} using XAS analysis. • EXAFS and XANES analysis showed that Fe was likely to be situated in the RS layer structure. • Changes in TE property with Fe content was due to charge transfer between

  11. Bathymetry, controlled source seismic and gravity observations of the Mendeleev ridge; implications for ridge structure, origin, and regional tectonics

    NASA Astrophysics Data System (ADS)

    Dove, Dayton; Coakley, Bernard; Hopper, John; Kristoffersen, Yngve

    2010-11-01

    Multichannel seismic (MCS), seismic refraction, and gravity data collected down the flank of the Chukchi Plateau, but predominantly over the Mendeleev Ridge have been processed and interpreted to describe the crustal style of the ridge, as well as the structural history. These results provide constraints on the origin of the ridge, and the tectonic evolution of the Amerasian Basin. MCS images reveal two primary sediment sequences separated by an unconformity that persists across the entire Mendeleev Ridge. The basement and lower sediment sequence exhibit pervasive normal faulting. The upper sequence is laterally conformable and not effected by faulting, thus the regional unconformity dividing the two sequences is interpreted to mark the end of extensional deformation. Modeling of sonobuoy seismic refraction data reveals upper crustal P-wave velocities ranging from 3.5 to 6.4kms-1 approximately 5km into the basement. The velocity structure of the Mendeleev Ridge is consistent with either a volcanic rifted continental margin, or an oceanic plateau origin. Observed gravity anomalies over the ridge are reproduced by a model consisting of bathymetry, sediment and basement horizons from the MCS data and a single crustal layer of 2.86gcm-3. This result is consistent with homogeneous, mafic crust. The similar velocity and density structures of the Mendeleev and Alpha ridges is consistent with a model where the two ridges are contiguous and share a common geological origin. Gravity modelling over the transition between the Chukchi Plateau and the Mendeleev Ridge suggests the two features have differing compositions and distinct emplacement histories. Three tectonic models are presented for the origin of the Alpha Mendeleev Ridge (AMR) that satisfy constraints set by this and previous studies: (1) a rifted volcanic continental margin, (2) an oceanic plateau formed at a spreading centre-perpendicular to the AMR and (3) an oceanic plateau formed at a spreading centre

  12. Intrusive origin of the Sudbury Igneous Complex: Structural and sedimentological evidence

    NASA Technical Reports Server (NTRS)

    Cowan, E. J.; Schwerdtner, W. M.

    1992-01-01

    In recent years, many geoscientists have come to believe that the Sudbury event was exogenic rather than endogenic. Critical to a recent exogenic hypothesis is the impact melt origin of the Sudbury Igneous Complex (SIC). Such origin implies that the SIC was emplaced before deposition of the Whitewater Group, in contrast to origins in which the SIC postdates the lithification of the Onaping Formation. Structural and sedimentological evidence is summarized herein that supports an intrusion of the SIC after lithification of all Whitewater Group strata, and conflicts with the hypothesis advanced by other researchers.

  13. Towards a unified model of passive drug permeation I: origins of the unstirred water layer with applications to ionic permeation.

    PubMed

    Ghosh, Avijit; Scott, Dennis O; Maurer, Tristan S

    2014-02-14

    In this work, we provide a unified theoretical framework describing how drug molecules can permeate across membranes in neutral and ionized forms for unstirred in vitro systems. The analysis provides a self-consistent basis for the origin of the unstirred water layer (UWL) within the Nernst-Planck framework in the fully unstirred limit and further provides an accounting mechanism based simply on the bulk aqueous solvent diffusion constant of the drug molecule. Our framework makes no new assumptions about the underlying physics of molecular permeation. We hold simply that Nernst-Planck is a reasonable approximation at low concentrations and all physical systems must conserve mass. The applicability of the derived framework has been examined both with respect to the effect of stirring and externally applied voltages to measured permeability. The analysis contains data for 9 compounds extracted from the literature representing a range of permeabilities and aqueous diffusion coefficients. Applicability with respect to ionized permeation is examined using literature data for the permanently charged cation, crystal violet, providing a basis for the underlying mechanism for ionized drug permeation for this molecule as being due to mobile counter-current flow. PMID:24211511

  14. Osmium isotope ratios of PGM grains associated with the Freetown Layered Complex, Sierra Leone, and their origin

    NASA Astrophysics Data System (ADS)

    Hattori, Keiko; Cabri, Louis J.; Hart, Stanley R.

    1991-03-01

    Osmium isotope ratios for two types of platinum group mineral (PGM) nuggets of eluvial (residual) origin, associated with the Freetown Layered Gabbro Complex, were determined in-situ using an ion microprobe. The values for erlichmanite nuggets are ≈1.08. Those for PGM inclusions in Pt-Fe alloy nuggets are higher, ranging from 1.2 to 2.1. Ratios of187Os/186Os vary between the nuggets, but they are consistent within individual nuggest. The data suggest early formation of the erlichmanite nuggets, prior to a postulated substantial contribution of crustal Os. The Pt-Fe alloy nuggets, on the other hand, were formed later in a residual melt which was contaminated by crustal Os due to the assimilation (<10%) or the gaseous/fluid transport of Os from Archaean host rocks into the magma. The lack of systematic mineralogical and chemical changes of the Complex and extensive granulitization in the adjacent host rocks and xenoliths may favor the latter process. The lack of high187Os/186Os ratios, consistent187Os/186Os values within individual nuggets and their textures and mineralogy suggest that the studied PGM nuggets were not formed during lateritization or in low-temperature depositional environments.

  15. Inversion of thicknesses of multi-layered structures from eddy current testing measurements.

    PubMed

    Huang, Ping-jie; Wu, Zhao-tong

    2004-01-01

    Luquire et al.'s impedance change model of a rectangular cross section probe coil above a structure with an arbitrary number of parallel layers was used to study the principle of measuring thicknesses of multi-layered structures in terms of eddy current testing voltage measurements. An experimental system for multi-layered thickness measurement was developed and several fitting models to formulate the relationships between detected impedance/voltage measurements and thickness are put forward using least square method. The determination of multi-layered thicknesses was investigated after inversing the voltage outputs of the detecting system. The best fitting and inversion models are presented. PMID:14663858

  16. Ferromagnetism and the electronic band structure in (Ga,Mn)(Bi,As) epitaxial layers

    SciTech Connect

    Yastrubchak, O.; Sadowski, J.; Domagala, J. Z.; Andrearczyk, T.; Wosinski, T.

    2014-08-18

    Impact of Bi incorporation into (Ga,Mn)As layers on their electronic- and band-structures as well as their magnetic and structural properties has been studied. Homogenous (Ga,Mn)(Bi,As) layers of high structural perfection have been grown by the low-temperature molecular-beam epitaxy technique. Post-growth annealing treatment of the layers results in an improvement of their structural and magnetic properties and an increase in the hole concentration in the layers. The modulation photoreflectance spectroscopy results are consistent with the valence-band model of hole-mediated ferromagnetism in the layers. This material combines the properties of (Ga,Mn)As and Ga(Bi,As) ternary compounds and offers the possibility of tuning its electrical and magnetic properties by controlling the alloy composition.

  17. Ovarian carcinoma patient derived xenografts reproduce their tumor of origin and preserve an oligoclonal structure

    PubMed Central

    Colombo, Pierre-Emmanuel; du Manoir, Stanislas; Orsetti, Béatrice; Bras-Gonçalves, Rui; Lambros, Mario B.; MacKay, Alan; Nguyen, Tien-Tuan; Boissiére, Florence; Pourquier, Didier; Bibeau, Frédéric; Reis-Filho, Jorge S.; Theillet, Charles

    2015-01-01

    Advanced Epithelial Ovarian Cancer (EOC) patients frequently relapse by 24 months and develop resistant disease. Research on EOC therapies relies on cancer cell lines established decades ago making Patient Derived Xenografts (PDX) attractive models, because they are faithful representations of the original tumor. We established 35 ovarian cancer PDXs resulting from the original graft of 77 EOC samples onto immuno-compromised mice. PDXs covered the diversity of EOC histotypes and graft take was correlated with early patient death. Fourteen PDXs were characterized at the genetic and histological levels. PDXs reproduced phenotypic features of the ovarian tumors of origin and conserved the principal characteristics of the original copy number change (CNC) profiles over several passages. However, CNC fluctuations in specific subregions comparing the original tumor and the PDXs indicated the oligoclonal nature of the original tumors. Detailed analysis by CGH, FISH and exome sequencing of one case, for which several tumor nodules were sampled and grafted, revealed that PDXs globally maintained an oligoclonal structure. No overgrowth of a particular subclone present in the original tumor was observed in the PDXs. This suggested that xenotransplantation of ovarian tumors and growth as PDX preserved at least in part the clonal diversity of the original tumor. We believe our data reinforce the potential of PDX as exquisite tools in pre-clinical assays. PMID:26334103

  18. Spectral and total temperature-dependent emissivities of few-layer structures on a metallic substrate.

    PubMed

    Blandre, Etienne; Chapuis, Pierre-Olivier; Vaillon, Rodolphe

    2016-01-25

    We investigate the thermal radiative emission of few-layer structures deposited on a metallic substrate and its dependence on temperature with the Fluctuational Electrodynamics approach. We highlight the impact of the variations of the optical properties of metallic layers on their temperature-dependent emissivity. Fabry-Pérot spectral selection involving at most two transparent layers and one thin reflective layer leads to well-defined peaks and to the amplification of the substrate emission. For a single Fabry-Pérot layer on a reflective substrate, an optimal thickness that maximizes the emissivity of the structure can be determined at each temperature. A thin lossy layer deposited on the previous structure can enhance interference phenomena, and the analysis of the participation of each layer to the emission shows that the thin layer is the main source of emission. Eventually, we investigate a system with two Fabry-Pérot layers and a metallic thin layer, and we show that an optimal architecture can be found. The total hemispherical emissivity can be increased by one order of magnitude compared to the substrate emissivity. PMID:26832589

  19. Dynamics of coherent structures in a plane mixing layer

    NASA Technical Reports Server (NTRS)

    Hussain, Fazle; Moser, R. D.; Colonius, T.; Moin, P.; Rogers, M. M.

    1988-01-01

    An incompressible, time developing 3-D mixing layer with idealized initial conditions was simulated numerically. Consistent with the suggestions from experimental measurements, the braid region between the dominant spanwise vortices or rolls develops longitudinal vortices or ribs, which are aligned upstream and downstream of a roll and produce spanwise distortion of the rolls. The process by which this distortion occurs is explained by studying a variety of quantities of dynamic importance (e.g., production of enstrophy, vortex stretching). Other quantities of interest (dissipation, helicity density) are also computed and discussed. The currently available simulation only allows the study of the early evolution (before pairing) of the mixing layer. New simulations in progress will relieve this restriction.

  20. Structure investigations of nonpolar GaN layers.

    PubMed

    Neumann, W; Mogilatenko, A; Wernicke, T; Richter, E; Weyers, M; Kneissl, M

    2010-03-01

    The microstructure of nonpolar m-plane (1100) oriented GaN layers deposited on (100)gamma-LiAlO(2) was analysed by transmission electron microscopy. This study shows that the films contain a large number of defects. The most dominant defects in the m-plane GaN are intrinsic I(1) basal plane stacking faults (approximately 10(4) cm(-1)), threading dislocations (approximately 10(9) cm(-2)) as well as a complex defect network consisting of planar defects located on prismatic {1010} GaN and differently inclined pyramidal planes. A large number of the stacking faults nucleate at the GaN/LiAlO(2) interface. Furthermore, the inclined planar defects act as additional nucleation sites for the basal plane stacking faults. A decreasing crystal quality with an increasing layer thickness can be explained by this defect formation mechanism. PMID:20500386

  1. Radiation effects in strained-layer superlattice (SLS) structures

    SciTech Connect

    Barnes, C.E.; Samara, G.A.; Biefeld, R.M.; Zipperian, T.E.; Osbourn, G.C.

    1984-01-01

    The effects of gamma and neutron irradiation on GaP/GaAsP strained-layer superlattices (SLS's) have been studied and compared with results on similar non-SLS alloys. The carrier removal rate was significantly greater in the non-SLS samples for both types of radiation. Gamma irradiation resulted in layer-dependent removal rates which produced oscillations in the doping profile. Gamma-induced introduction rates of two prominent traps were the same in the various SLS samples, and in the non-SLS alloy. Thermal annealing was also similar in all the samples with the shallower (0.3 eV) trap recovering sharply in a stage at 175/sup 0/C. This was accompanied by a disappearance of the carrier removal oscillations at a somewhat higher annealing temperature. In contrast, the degree of recombination-enhanced annealing, and its variation with applied hydrostatic pressure, was strongly dependent on sample characteristics. This type of recovery was much stronger in the non-SLS samples, and was dependent on the layer thicknesses in the SLS samples. Hydrostatic pressure was found to enhance this process in the non-SLS samples, but had no significant effect on recombination-enhanced annealing in the SLS samples.

  2. Key Role of Rutile Structure for Layered Magnetism in Chromium Compounds

    NASA Astrophysics Data System (ADS)

    Kondo, Yasuhiro; Hotta, Takashi

    CrCl2 and CrF2 with the distorted Rutile-type crystal structure are known to exhibit different antiferromagnetic (AF) structures at low temperatures. CrF2 has a simple N_eel structure in common with other uorides, whereas CrCl2 exhibits a characteristic layered AF structure. We provide a simple scenario to understand the emergence of such layered AF structure on the basis of an orbital degenerate double-exchange model on the Rutile-type structure lattice.

  3. Solvent-free synthesis of new metal phosphites with double-layered, pillared-layered, and framework structures

    NASA Astrophysics Data System (ADS)

    Liu, Lin; Zhang, Wei; Shi, Zhonghua; Chen, Yaoqiang; Lin, Zhien

    2014-12-01

    Three new metal phosphites, formulated as (H3O)2·Mn2(HPO3)3 (1), Co(bpy) (H2O) (HPO3) (2), and H2tmpda·Zn3(HPO3)4 (3), have been synthesized under solvent-free conditions, where bpy = 4,4‧-bipyridine, and tmpda = N,N,N‧,N‧-tetramethyl-1,3-propanediamine. Compound 1 has a double-layered structure with a thickness of 5.68 Å. Compound 2 has an inorganic-organic hybrid framework with cobalt phosphite layers pillared by bpy ligands. Compound 3 has a three-dimensional open-framework structure containing 8-ring channels. The temperature dependence of the magnetic susceptibility of compounds 1 and 2 were also investigated.

  4. Origin of Degradation Phenomenon under Drain Bias Stress for Oxide Thin Film Transistors using IGZO and IGO Channel Layers

    PubMed Central

    Bak, Jun Yong; Kang, Youngho; Yang, Shinhyuk; Ryu, Ho-Jun; Hwang, Chi-Sun; Han, Seungwu; Yoon, Sung-Min

    2015-01-01

    Top-gate structured thin film transistors (TFTs) using In-Ga-Zn-O (IGZO) and In-Ga-O (IGO) channel compositions were investigated to reveal a feasible origin for degradation phenomenon under drain bias stress (DBS). DBS-driven instability in terms of VTH shift, deviation of the SS value, and increase in the on-state current were detected only for the IGZO-TFT, in contrast to the IGO-TFT, which did not demonstrate VTH shift. These behaviors were visually confirmed via nanoscale transmission electron microscopy and energy-dispersive x-ray spectroscopy observations. To understand the degradation mechanism, we performed ab initio molecular dynamic simulations on the liquid phases of IGZO and IGO. The diffusivities of Ga and In atoms were enhanced in IGZO, confirming the degradation mechanism to be increased atomic diffusion. PMID:25601183

  5. Electronic structure of a dual-layered organic charge transfer salt

    NASA Astrophysics Data System (ADS)

    Jeschke, Harald; Altmeyer, Michaela; Valenti, Roser

    2015-03-01

    We examine the electronic properties of polymorphs of (BEDT-TTF)2Ag(CF3)4(TCE) (1,1,2-trichloroethane) within density functional theory (DFT). While a phase with low superconducting transition temperature Tc = 2 . 6 K exhibits a κ packing motif, two high Tc phases are layered structures consisting of α' and κ packed layers. We determine the electronic structures and discuss the influence of the insulating α' layer on the conducting κ layer. We find that the stripes of high and low charge in the α' layer correspond to a stripe pattern of hopping parameters in the κ layer. This finding is the basis for studying the effect of the different underlying Hamiltonians on the superconducting properties. Research funded within DFG Transregio 49.

  6. Direct intervention of hairpin structures for turbulent boundary-layer control

    NASA Astrophysics Data System (ADS)

    Kang, Yong-Duck; Choi, Kwing-So; Chun, Ho Hwan

    2008-10-01

    Direct intervention of large-scale, outer-layer structures of a turbulent boundary layer has been carried out by counteracting the upwash motion of hairpin vortices with jets issued from a nozzle placed outside the boundary layer. The methodology of this turbulent boundary-layer control is similar in concept to the opposition control of near-wall turbulence, where the induced velocity field of vortical motion during the turbulence activities is opposed by suction and blowing at the wall. Unlike wall-based turbulence control techniques whose time and length scales reduce with an increase in the Reynolds number, scales of the proposed control are those of the outer layer, making this control technique highly practical. Here we show some results from a direct intervention of hairpin structures in a turbulent boundary layer, demonstrating that this is a promising technique for turbulence control.

  7. Effects of interfacial layer structures on crystal structural properties of ZnO films

    SciTech Connect

    Park, J. S.; Minegishi, T.; Lee, S. H.; Im, I. H.; Park, S. H.; Hanada, T.; Goto, T.; Cho, M. W.; Yao, T.; Hong, S. K.; Chang, J. H.

    2008-01-15

    Single crystalline ZnO films were grown on Cr compound buffer layers on (0001) Al{sub 2}O{sub 3} substrates by plasma assisted molecular beam epitaxy. In terms of lattice misfit reduction between ZnO and substrate, the CrN and Cr{sub 2}O{sub 3}/CrN buffers are investigated. The structural and optical qualities of ZnO films suggest the feasibility of Cr compound buffers for high-quality ZnO films growth on (0001) Al{sub 2}O{sub 3} substrates. Moreover, the effects of interfacial structures on selective growth of different polar ZnO films are investigated. Zn-polar ZnO films are grown on the rocksalt CrN buffer and the formation of rhombohedral Cr{sub 2}O{sub 3} results in the growth of O-polar films. The possible mechanism of polarity conversion is proposed. By employing the simple patterning and regrowth procedures, a periodical polarity converted structure in lateral is fabricated. The periodical change of the polarity is clearly confirmed by the polarity sensitive piezo response microscope images and the opposite hysteretic characteristic of the piezo response curves, which are strict evidences for the validity of the polarity controlling method as well as the successful fabrication of the periodical polarity controlled ZnO structure.

  8. Wet-chemical synthesis and applications of non-layer structured two-dimensional nanomaterials

    PubMed Central

    Tan, Chaoliang; Zhang, Hua

    2015-01-01

    Non-layer structured nanomaterials with single- or few-layer thickness have two-dimensional sheet-like structures and possess intriguing properties. Recent years have seen major advances in development of a host of non-layer structured ultrathin two-dimensional nanomaterials such as noble metals, metal oxides and metal chalcogenides. The wet-chemical synthesis has emerged as the most promising route towards high-yield and mass production of such nanomaterials. These nanomaterials are now finding increasing applications in a wide range of areas including catalysis, energy production and storage, sensor and nanotherapy, to name but a few. PMID:26303763

  9. Layered structure of bacterial aggregates produced in an upflow anaerobic sludge bed and filter reactor

    SciTech Connect

    MacLeod, F.A.; Guiot, S.R.; Costerton, J.W. )

    1990-06-01

    The ultrastructure of bacterial granules that were maintained in an upflow anaerobic sludge bed and filter reactor was examined. The reactor was fed a sucrose medium, and it was operated at 35{degrees}C. Scanning and transmission electron microscopy revealed that the granular aggregates were three-layered structures. The exterior layer of the granule contained a very heterogeneous population that included rods, cocci, and filaments of various sizes. The middle layer consisted of a slightly less heterogeneous population than the exterior layer. A more ordered arrangement, made up predominantly of bacterial rods, was evident in this second layer. The third layer formed the internal core of the granules. It consisted of large numbers of Methanothrix-like cells. Large cavities, indicative of vigorous gas production, were evident in the third layer. On the basis of these ultrastructural results, a model that presents a possible explanation of granule development is offered.

  10. Differential PIXE for investigating the layer structure of paintings

    NASA Astrophysics Data System (ADS)

    Mandò, P. A.; Fedi, M. E.; Grassi, N.; Migliori, A.

    2005-09-01

    This paper reports an example of how the differential PIXE technique can be successfully applied to the investigation of wood or canvas paintings. The work analysed is a famous wood painting by Leonardo da Vinci, the "Madonna dei fusi" (ex-Reford version, 1501), chosen for a pilot study in a wide international project aimed at analysing Leonardo's works of art by means of non-destructive techniques. While illustrating the results obtained concerning the identification of pigments and the discrimination of the stratigraphy of layers, the merits and limits of differential PIXE in general are pointed out.

  11. A Long-Lived Tracer Perspective on the Origin of Air in the Tropical Tropopause Layer during ATTREX

    NASA Astrophysics Data System (ADS)

    Hintsa, E. J.; Moore, F.; Dutton, G. S.; Hall, B. D.; Nance, J. D.; Elkins, J. W.; Gao, R.; Rollins, D. W.; Thornberry, T. D.; Watts, L.; Fahey, D. W.; Daube, B. C.; Pittman, J. V.; Wofsy, S. C.; Atlas, E. L.; Navarro, M. A.; Dessler, A. E.; Mahoney, M.

    2013-12-01

    The origin of air in the tropical tropopause layer (TTL) and the subsequent transport pathways of these air masses play a critical role in the delivery of trace gases, including ozone depleting substances and water vapor, to the stratosphere. The Airborne Tropical Tropopause Experiment (ATTREX) is designed to study this transport and processing in the TTL over the Pacific Ocean, including how dehydration occurs in this region and how trace gases involved in ozone depletion and climate reach the tropical lower stratosphere. For this mission, the NASA Global Hawk aircraft is carrying a suite of in situ and remote sensing instruments for trace gases, aerosols, radiation, and meteorology. Two deployments have occurred from NASA/Dryden Flight Research Center, with flights to the eastern and central tropical Pacific. Two more deployments, targeting the western equatorial Pacific, are planned for 2014 from Guam and one other location. Over 100 vertical profiles from about 14 to 18 km have now been obtained from the tropics to midlatitudes, as well as long sections at nearly constant altitude. Results are shown here from the UAS Chromatograph for Atmospheric Trace Species (UCATS) instrument and other sensors. UCATS was configured to measure the long-lived tracers N2O, SF6, H2, and CH4, as well as water vapor, CO, and ozone. Results thus far have shown a mix of midlatitude and tropical air in the tropical and subtropical lower stratosphere, particularly for flights in November 2011. Recent results from February 2013 indicate much more homogeneous air masses in the TTL during this period. This homogeneity may be related to fact that these flights occurred in the middle of (northern) winter rather than fall, or to the 'sudden stratospheric warming' in January 2013, with sinking motion in the Arctic polar region and a corresponding rising motion and cooling in the tropics. Data will be presented in the context of trajectory model calculations of the origin and fate of the air

  12. Structure of a Magnetic Flux Annihilation Layer Formed by the Collision of Supersonic, Magnetized Plasma Flows.

    PubMed

    Suttle, L G; Hare, J D; Lebedev, S V; Swadling, G F; Burdiak, G C; Ciardi, A; Chittenden, J P; Loureiro, N F; Niasse, N; Suzuki-Vidal, F; Wu, J; Yang, Q; Clayson, T; Frank, A; Robinson, T S; Smith, R A; Stuart, N

    2016-06-01

    We present experiments characterizing the detailed structure of a current layer, generated by the collision of two counterstreaming, supersonic and magnetized aluminum plasma flows. The antiparallel magnetic fields advected by the flows are found to be mutually annihilated inside the layer, giving rise to a bifurcated current structure-two narrow current sheets running along the outside surfaces of the layer. Measurements with Thomson scattering show a fast outflow of plasma along the layer and a high ion temperature (T_{i}∼Z[over ¯]T_{e}, with average ionization Z[over ¯]=7). Analysis of the spatially resolved plasma parameters indicates that the advection and subsequent annihilation of the inflowing magnetic flux determines the structure of the layer, while the ion heating could be due to the development of kinetic, current-driven instabilities. PMID:27314720

  13. Modification in drag of turbulent boundary layers resulting from manipulation of large-scale structures

    NASA Technical Reports Server (NTRS)

    Corke, T. C.; Guezennec, Y.; Nagib, H. M.

    1981-01-01

    The effects of placing a parallel-plate turbulence manipulator in a boundary layer are documented through flow visualization and hot wire measurements. The boundary layer manipulator was designed to manage the large scale structures of turbulence leading to a reduction in surface drag. The differences in the turbulent structure of the boundary layer are summarized to demonstrate differences in various flow properties. The manipulator inhibited the intermittent large scale structure of the turbulent boundary layer for at least 70 boundary layer thicknesses downstream. With the removal of the large scale, the streamwise turbulence intensity levels near the wall were reduced. The downstream distribution of the skin friction was also altered by the introduction of the manipulator.

  14. Experimental observation of multi-layer excitation structure in capacitively coupled SF6 plasmas

    NASA Astrophysics Data System (ADS)

    Liu, Yong-Xin; Gao, Fei; Song, Yuan-Hong; Li, Xue-Chun; Wang, You-Nian

    2015-09-01

    Electron excitation dynamics in capacitively coupled SF6 plasmas driven at 9 MHz ~ 16 MHz are studied by using phase resolved optical emission spectroscopy (PROES) of trace rare gas. Multi-layer excitation structure inside the bulk plasma of capacitive discharges operating in SF6 is experimentally observed for the first time. Experimental results show that with the decrease of the rf power and/or the increase of the pressure, the multi-layer excitation structure becomes noticeable while the gap between two adjacent layers is almost kept constant. By increasing the driving frequency with a constant electrode gap, however, the number of layers increases while the layer gap decreases. The layer structure disappears at the driving frequency larger than 16 MHz. The electrode gap is found to have a negligible effect on the gap between two adjacent excitation layers, nevertheless only the number of excitation layers is increased when enlarging the electrode gap. The multi-layer formation may be due to a large modulation of the F- negative-ion density throughout the bulk plasma, and is more pronounced at intermediate and low frequencies, since F- negative ions do not respond to the time-varying electric field at high frequencies (>16 MHz). This work was supported by the National Natural Science Foundation of China (NSFC) (Grant No. 11335004) and (Grant No.11405018), and the International Science & Technology Cooperation Program of China (Grant No. 2012DFG02150).

  15. The elasticity of lawsonite at high pressure and the origin of low velocity layers in subduction zones

    NASA Astrophysics Data System (ADS)

    Chantel, Julien; Mookherjee, Mainak; Frost, Daniel J.

    2012-10-01

    Subduction zones exhibit faster seismic wave velocities compared to the surrounding mantle due to the recycling of relatively cold oceanic lithosphere. In certain subduction zones, however, a 5-10 km thick low velocity layer (LVL) has been inferred to exist along the top surface of the subducting slab at depths of up to 250 km. Shear-wave velocities, in particular, within these layers have been estimated as up to 10% slower than the surrounding mantle. We have conducted high-pressure ultrasonic interferometric measurements to gain insight into the elastic properties of lawsonite [CaAl2(Si2O7)(OH)2·H2O], a hydrous mineral phase stabilized under cold subduction zone conditions. In addition, we have computed the full elastic constant tensor at elevated pressures and temperature, using static electronic structure calculations and molecular dynamics simulations. The bulk and shear modulus obtained from theory and experiments are in good agreement. We find that lawsonite has an unusually low shear modulus at high pressure and its formation in subducted oceanic crust can explain some seismic evidence for LVL at depths exceeding 100 km. To approach estimated LVL velocities requires lawsonite to form in the subducting crust as a result of a fluid influx due to the breakdown of other hydrous minerals such as serpentine. The formation of lawsonite additionally lowers seismic velocities because it forms at the expense of garnet, a mineral with relatively fast seismic velocities. LVL observations may therefore be used to place constraints on the amount of H2O subducted into the deep mantle.

  16. Boundary layer structure over areas of heterogeneous heat fluxes

    SciTech Connect

    Doran, J.C. ); Barnes, F.J. ); Coulter, R.L. ); Crawford, T.L. . Air Resources Lab. Atmospheric Turbulence and Diffusion Div.)

    1993-01-01

    In general circulation models (GCMs), some properties of a grid element are necessarily considered homogeneous. That is, for each grid volume there is associated a particular combination of boundary layer depth, vertical profiles of wind and temperature, surface fluxes of sensible and latent heat, etc. In reality, all of these quantities may exhibit significant spatial variations the grid area, and the larger the area the greater the likely variations. In balancing the benefits of higher resolution against increased computational time and expense, it is useful to consider what the consequences of such subgrid-scale variability may be. Moreover, in interpreting the results of a simulation, one must be able to define an appropriate average value over a grid. There are two aspects of this latter problem: (1) in observations, how does one take a set of discrete or volume-averaged measurements and relate these to properties of the entire domain, and (2) in computations, how can subgrid-scale features be accounted for in the model parameterizations To address these and related issues, two field campaigns were carried out near Boardman, Oregon, in June 1991 and 1992. These campaigns were designed to measure the surface fluxes of latent and sensible heat over adjacent areas with strongly contrasting surface types and to measure the response of the boundary layer to those fluxes. This paper discusses some initial findings from those campaigns.

  17. Boundary layer structure over areas of heterogeneous heat fluxes

    SciTech Connect

    Doran, J.C.; Barnes, F.J.; Coulter, R.L.; Crawford, T.L.

    1993-04-01

    In general circulation models (GCMs), some properties of a grid element are necessarily considered homogeneous. That is, for each grid volume there is associated a particular combination of boundary layer depth, vertical profiles of wind and temperature, surface fluxes of sensible and latent heat, etc. In reality, all of these quantities may exhibit significant spatial variations within the grid area, and the larger the area the greater the likely variations. In balancing the benefits of higher resolution against increased computational time and expense, it is useful to consider what the consequences of such subgrid-scale variability may be. Moveover, in interpreting the results of a simulation, one must be able to define an appropriate average value over a grid. There are two aspects of this latter problem: (1) in observations, how does one take a set of discrete or volume-averaged measurements and relate these to properties of the entire domain, and (2) in computations, how can subgrid-scale features be accounted for in the model parameterizations? To address these and related issues, two field campaigns were carried out near Boardman, Oregon, in June 1991 and 1992. These campaigns were designed to measure the surface fluxes of latent and sensible heat over adjacent areas with strongly contrasting surface types and to measure the response of the boundary layer to those fluxes. This paper discuses some initial findings from those campaigns.

  18. Boundary layer structure over areas of heterogeneous heat fluxes

    SciTech Connect

    Doran, J.C.; Barnes, F.J.; Coulter, R.L.; Crawford, T.L.

    1993-01-01

    In general circulation models (GCMs), some properties of a grid element are necessarily considered homogeneous. That is, for each grid volume there is associated a particular combination of boundary layer depth, vertical profiles of wind and temperature, surface fluxes of sensible and latent heat, etc. In reality, all of these quantities may exhibit significant spatial variations the grid area, and the larger the area the greater the likely variations. In balancing the benefits of higher resolution against increased computational time and expense, it is useful to consider what the consequences of such subgrid-scale variability may be. Moreover, in interpreting the results of a simulation, one must be able to define an appropriate average value over a grid. There are two aspects of this latter problem: (1) in observations, how does one take a set of discrete or volume-averaged measurements and relate these to properties of the entire domain, and (2) in computations, how can subgrid-scale features be accounted for in the model parameterizations? To address these and related issues, two field campaigns were carried out near Boardman, Oregon, in June 1991 and 1992. These campaigns were designed to measure the surface fluxes of latent and sensible heat over adjacent areas with strongly contrasting surface types and to measure the response of the boundary layer to those fluxes. This paper discusses some initial findings from those campaigns.

  19. Boundary layer structure over areas of heterogeneous heat fluxes

    SciTech Connect

    Doran, J.C. ); Barnes, F.J. ); Coulter, R.L. ); Crawford, T.L. . Air Resources Lab. Atmospheric Turbulence and Diffusion Div.)

    1993-01-01

    In general circulation models (GCMs), some properties of a grid element are necessarily considered homogeneous. That is, for each grid volume there is associated a particular combination of boundary layer depth, vertical profiles of wind and temperature, surface fluxes of sensible and latent heat, etc. In reality, all of these quantities may exhibit significant spatial variations within the grid area, and the larger the area the greater the likely variations. In balancing the benefits of higher resolution against increased computational time and expense, it is useful to consider what the consequences of such subgrid-scale variability may be. Moveover, in interpreting the results of a simulation, one must be able to define an appropriate average value over a grid. There are two aspects of this latter problem: (1) in observations, how does one take a set of discrete or volume-averaged measurements and relate these to properties of the entire domain, and (2) in computations, how can subgrid-scale features be accounted for in the model parameterizations To address these and related issues, two field campaigns were carried out near Boardman, Oregon, in June 1991 and 1992. These campaigns were designed to measure the surface fluxes of latent and sensible heat over adjacent areas with strongly contrasting surface types and to measure the response of the boundary layer to those fluxes. This paper discuses some initial findings from those campaigns.

  20. Role of metallic substrate on the plasmon modes in double-layer graphene structures

    NASA Astrophysics Data System (ADS)

    Cruz, G. Gonzalez de la

    2015-07-01

    Novel heterostructures combining different layered materials offer new opportunities for applications and fundamental studies of collective excitations driven by interlayer Coulomb interactions. In this work, we have investigated the influence of the metallic-like substrate on the plasmon spectrum of a double layer graphene system and a structure consisting of conventional two-dimensional electron gas (2DEG) immersed in a semiconductor quantum well and a graphene sheet with an interlayer separation of d. Long-range Coulomb interactions between substrate and graphene layered systems lead a new set of spectrum plasmons. At long wavelengths (q→0) the acoustic modes (ω~q) depend, besides on the carrier density in each layer, on the distance between the first carrier layer and the substrate in both structures. Furthermore, in the relativistic/nonrelativistic layered structure an undamped acoustic mode emerges for a certain interlayer critical distance dc. On the other hand, the optical plasmon modes emerging from the coupling of the double-layer systems and the substrate, both start at finite frequency at q=0 in contrast to the collective excitation spectrum ω~q1/2 reported in the literature for double-layer graphene structures.

  1. A class of unsteady, three-dimensional flow structures in turbulent boundary layers

    NASA Technical Reports Server (NTRS)

    Ash, R. L.

    1981-01-01

    A restricted class of mathematically admissible, unsteady, three dimensional flows was identified which may constitute part of the structure observed in turbulent boundary layers. The development of the model and some general results are discussed. The resulting solution has characteristics which suggest how upwelling low speed flow can trigger a downward jetting of irrotational high speed fluid into the boundary layer.

  2. Shear Induced Structures in Lamellar Systems ---From Layers to Onions to Onions and Layers---

    NASA Astrophysics Data System (ADS)

    Koschoreck, S.; Fujii, S.; Richtering, W.

    Shear flow induces the formation of multilamellar vesicles (MLV, also termed ``onions") in the lamellar phase of the nonionic surfactant C_{10}E_{3} in water. Depending on the applied shear rate, one can reach a state of polydisperse MLV (at intermediate shear rates) or densely packed monodisperse MLV at high shear rates. In this contribution we investigated the structure evolution when the shear rate is reduced by means of rheo-microscopy as well as rheo-small angle light and neutron scattering (SALS, SANS). Different shear quenches within the MLV structure region of 40 wt% C_{10}E_{3} reveal two different MLV size growth mechanisms: (i) a continuous and (ii) a discontinuous MLV size growth. In the later case, a part of the initial MLV structure transforms into planar lamellar domains leading to shear thinning. The lamellar domains perform a re-orientation process from parallel oriented lamellae into MLV in coexistence with the initial MLV structure. The pathway of the transformation of the parallel lamellae to MLV is the same as in start-up experiments, i.e. from a homeotropically aligned lamellar phase.

  3. Origin and tectonic significance of a Mesozoic multi-layer over-thrust system within the Yangtze Block (South China)

    NASA Astrophysics Data System (ADS)

    Yan, Dan-Ping; Zhou, Mei-Fu; Song, Hong-Lin; Wang, Xin-Wen; Malpas, John

    2003-01-01

    In the Yangtze Block (South China), a well-developed Mesozoic thrust system extends through the Xuefeng and Wuling mountains in the southeast to the Sichuan basin in the northwest. The system comprises both thin- and thick-skinned thrust units separated by a boundary detachment fault, the Dayin fault. To the northwest, the thin-skinned belt is characterized by either chevron anticlines and box synclines to the northwest or chevron synclines to the southeast. The former structural style displays narrow exposures for the cores of anticlines and wider exposures for the cores of synclines. Thrust detachments occur along Silurian (Fs) and Lower Cambrian (Fc) strata and are dominantly associated with the anticlines. To the southeast, this style of deformation passes gradually into one characterized by chevron synclines with associated principal detachment faults along Silurian (Fs), Cambrian (Fc) and Lower Sinian (Fz) strata. There are, however, numerous secondary back thrusts. Therefore, the thin-skinned belt is like the Valley and Ridge Province of the North American Applachian Mountains. The thick-skinned belt structurally overlies the thin-skinned belt and is characterized by a number of klippen including the Xuefeng and Wuling nappes. It is thus comparable to the Blue Ridge Province of Appalachia. The structural pattern of this thrust system in South China can be explained by a model involving detachment faulting along various stratigraphic layers at different stages of its evolution. The system was developed through a northwest stepwise progression of deformation with the earliest delamination along Lower Sinian strata (Fz). Analyses of balanced geological cross-sections yield about 18.1-21% (total 88 km) shortening for the thin-skinned unit and at least this amount of shortening for the thick-skinned unit. The compressional deformation from southeast to northwest during Late Jurassic to Cretaceous time occurred after the westward progressive collision of the

  4. Deriving Lifetime Maps in the Time/Frequency Domain of Coherent Structures in the Turbulent Boundary Layer

    NASA Technical Reports Server (NTRS)

    Palumbo, Dan

    2008-01-01

    The lifetimes of coherent structures are derived from data correlated over a 3 sensor array sampling streamwise sidewall pressure at high Reynolds number (> 10(exp 8)). The data were acquired at subsonic, transonic and supersonic speeds aboard a Tupolev Tu-144. The lifetimes are computed from a variant of the correlation length termed the lifelength. Characteristic lifelengths are estimated by fitting a Gaussian distribution to the sensors cross spectra and are shown to compare favorably with Efimtsov s prediction of correlation space scales. Lifelength distributions are computed in the time/frequency domain using an interval correlation technique on the continuous wavelet transform of the original time data. The median values of the lifelength distributions are found to be very close to the frequency averaged result. The interval correlation technique is shown to allow the retrieval and inspection of the original time data of each event in the lifelength distributions, thus providing a means to locate and study the nature of the coherent structure in the turbulent boundary layer. The lifelength data are converted to lifetimes using the convection velocity. The lifetime of events in the time/frequency domain are displayed in Lifetime Maps. The primary purpose of the paper is to validate these new analysis techniques so that they can be used with confidence to further characterize the behavior of coherent structures in the turbulent boundary layer.

  5. Ab initio study of the origin of the dead magnetic Ni layers at the Ni/Pt( 1 1 1 ) interface

    NASA Astrophysics Data System (ADS)

    Lounis, S.; Benakki, M.; Bouarab, S.; Demangeat, C.

    2002-10-01

    Two recent experimental works based on X-ray magnetic circular dichroism and superconducting quantum interference on Ni/Pt(1 1 1) superlattices have displayed very different magnetic behavior. One reports evidence of magnetically "dead" layers whereas in further work, no magnetically dead Ni layers were found. These magnetically different behavior can be explained by density functional calculations on various structural configurations at the interface. One Ni buried layer at the interface gives a good description of the magnetic profile reported experimentally on one hand, whereas two or three NiPt alloyed layers at the interface confirm the magnetic dead Ni atoms measured on the other hand.

  6. Effects of physical processes on structure and transport of thin zooplankton layers in the coastal ocean

    USGS Publications Warehouse

    McManus, M.A.; Cheriton, O.M.; Drake, P.J.; Holliday, D.V.; Storlazzi, C.D.; Donaghay, P.L.; Greenlaw, C.F.

    2005-01-01

    Thin layers of plankton are recurrent features in a variety of coastal systems. These layers range in thickness from a few centimeters to a few meters. They can extend horizontally for kilometers and have been observed to persist for days. Densities of organisms found within thin layers are far greater than those above or below the layer, and as a result, thin layers may play an important role in the marine ecosystem. The paramount objective of this study was to understand the physical processes that govern the dynamics of thin layers of zooplankton in the coastal ocean. We deployed instruments to measure physical processes and zooplankton distribution in northern Monterey Bay; during an 11 d period of persistent upwelling-favorable winds, 7 thin zooplankton layers were observed. These zooplankton layers persisted throughout daylight hours, but were observed to dissipate during evening hours. These layers had an average vertical thickness of 1.01 m. No layers were found in regions where the Richardson number was <0.25. In general, when the Richardson number is <0.25 the water column is unstable, and incapable of supporting thin layers. Thin zooplankton layers were also located in regions of reduced flow. In addition, our observations show that the vertical depth distribution of thin zooplankton layers is modulated by high-frequency internal waves, with periods of 18 to 20 min. Results from this study clearly show an association between physical structure, physical processes and the presence of thin zooplankton layers in Monterey Bay. With this new understanding we may identify other coastal regions that have a high probability of supporting thin layers. ?? Inter-Research 2005.

  7. Metallic layered composite materials produced by explosion welding: Structure, properties, and structure of the transition zone

    NASA Astrophysics Data System (ADS)

    Mal'tseva, L. A.; Tyushlyaeva, D. S.; Mal'tseva, T. V.; Pastukhov, M. V.; Lozhkin, N. N.; Inyakin, D. V.; Marshuk, L. A.

    2014-10-01

    The structure, morphology, and microhardness of the transition zone in multilayer metallic composite joints are studied, and the cohesion strength of the plates to be joined, the mechanical properties of the formed composite materials, and fracture surfaces are analyzed. The materials to be joined are plates (0.1-1 mm thick) made of D16 aluminum alloy, high-strength maraging ZI90-VI (03Kh12N9K4M2YuT) steel, BrB2 beryllium bronze, and OT4-1 titanium alloy. Composite materials made of different materials are shown to be produced by explosion welding. The dependence of the interface shape (smooth or wavelike) on the physicomechanical properties of the materials to be joined is found. The formation of a wavelike interface is shown to result in the formation of intense-mixing regions in transition zones. Possible mechanisms of layer adhesion are discussed.

  8. Complex Adaptive Systems and the Origins of Adaptive Structure: What Experiments Can Tell Us

    ERIC Educational Resources Information Center

    Cornish, Hannah; Tamariz, Monica; Kirby, Simon

    2009-01-01

    Language is a product of both biological and cultural evolution. Clues to the origins of key structural properties of language can be found in the process of cultural transmission between learners. Recent experiments have shown that iterated learning by human participants in the laboratory transforms an initially unstructured artificial language…

  9. Protein folding, protein structure and the origin of life: Theoretical methods and solutions of dynamical problems

    NASA Technical Reports Server (NTRS)

    Weaver, D. L.

    1982-01-01

    Theoretical methods and solutions of the dynamics of protein folding, protein aggregation, protein structure, and the origin of life are discussed. The elements of a dynamic model representing the initial stages of protein folding are presented. The calculation and experimental determination of the model parameters are discussed. The use of computer simulation for modeling protein folding is considered.

  10. Structure A, steel shelving. Drawing no. H3300. Original drawing by ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Structure A, steel shelving. Drawing no. H3-300. Original drawing by Black & Veatch, Consulting Engineers, Kansas City, Missouri, prepared for the U.S. Department of the Army, Office of Engineers, Military Construction Division, Washington D.C. dated November 5, 1951. - Travis Air Force Base, Building No. 925, W Street, Fairfield, Solano County, CA

  11. Structure A, reinforcing details. Drawing No. H2302, as built, Original ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Structure A, reinforcing details. Drawing No. H2-302, as built, Original drawing by Black & Veatch, Consulting Engineers, Kansas City, Missouri, prepared for the U.S. Department of the Army, Office of Engineers, Military Construction Division, Washington, D.C. dated October 1, 1951. - Travis Air Force Base, Building No. 925, W Street, Fairfield, Solano County, CA

  12. 11. 22'X34' original blueprint, VariableAngle Launcher, 'CONTROL STATION STRUCTURAL DETAILS' ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    11. 22'X34' original blueprint, Variable-Angle Launcher, 'CONTROL STATION STRUCTURAL DETAILS' drawn at 1 1/2'=1'-0'. (BUORD Sketch # 208401). - Variable Angle Launcher Complex, Control Station, CA State Highway 39 at Morris Reservior, Azusa, Los Angeles County, CA

  13. First-principles study of homologous series of layered Bi-Sb-Te-Se and Sn-O structures

    NASA Astrophysics Data System (ADS)

    Govaerts, Kirsten

    In the first part of the thesis, we present a systematic study of the stable layered structures at T = 0 K for the Bi-Sb-Te-Se system by means of a combination of the Cluster Expansion (CE) method and first-principles electronic structure calculations. In order to account for the existence of long-periodic layered structures and the strong structural relaxations we have developed a one-dimensional CE with occupation variables explicitly accounting for the fact that Bi or Sb atoms are part of an even or odd number of layers. For the binary systems A1-xQx (A = Sb, Bi; Q = Te, Se) the resulting (meta)stable structures are the homologous series (A2) n(A2Q3)m built up from successive bilayers A 2 and quintuple units A2Q3. The Bi1-xSb x system is found to be an almost ideal solution. The CE for the ternary Bi-Sb-Te system not only reproduces the binary stable structures but also finds stable ternary layered compounds with an arbitrary stacking of Sb 2Te3, Bi2Te3 and Te-Bi-Te-Sb-Te quintuple units, optionally separated by mixed Bi/Sb bilayers. We also investigate the electronic properties of the newly found ground state structures, and in particular the effect of Bi bilayers on the electronic structure of the topological insulator Bi2Se3. Due to the charge transfer from the Bi bilayers to the quintuple layers, the top- and bottom-surface Dirac cones shift down in energy. Also the Rashba-split conduction band states shift down, resulting in a new Dirac cone. The bands of the additional Bi bilayer are just ordinary Rashba-split states originating from the dipole built up by the charge transfer. These results offer new insight in experimental results, where cones are not always correctly identified. In a second part of the thesis, we investigate the Sn-O system. First we show that a combination of current van der Waals-corrected functionals and many-body calculations within the GW approximation provide accurate values for both structural and electronic properties of Sn

  14. Structure of a mushy layer at the inner core boundary

    NASA Astrophysics Data System (ADS)

    Deguen, R.; Huguet, L.; Bergman, M. I.; Labrosse, S.; Alboussiere, T.

    2015-12-01

    We present experimental results on the solidification of ammonium chloride from an aqueous solution, yielding a mushy zone, under hyper-gravity. A commercial centrifuge has been equipped with a slip-ring so that electric power, temperature and ultrasonic signals could be transmitted between the experimental setup and the laboratory. A Peltier element provides cooling at the bottom of the cell. Probes monitor the temperature along the height of the cell. Ultrasound measurements (2 to 6 MHz) is used to detect the position of the front of the mushy zone and to determine attenuation in the mush. A significant increase of solid fraction (or decrease of mushy layer thickness) and attenuation in the mush is observed as gravity is increased. Kinetic undercooling is significant in our experiments and has been included in a macroscopic mush model. The other ingredients of the model are conservation of energy and chemical species, along with heat/species transfer between the mush and the liquid phase: boundary-layer exchanges at the top of the mush and bulk convection within the mush (formation of chimneys). The outputs of the model compare well with our experiments. We have then run the model in a range of parameters suitable for the Earth's inner core, which has shown the role of bulk mush convection for the inner core and the reason why a solid fraction very close to unity should be expected. We have also run melting experiments: after crystallization of a mush, the liquid has been heated from above until the mush started to melt, while the bottom cold temperature was maintained. These melting experiments were motivated by the possible local melting at the inner core boundary that has been invoked to explain the formation of the anomalously slow F-layer at the bottom of the outer core or inner core hemispherical asymmetry. Oddly, the consequences of melting are an increase in solid fraction and a decrease in attenuation. It is hence possible that surface seismic velocity

  15. Structural vs electronic origin of renormalized band widths in TTF-TCNQ: An angular dependent NEXAFS study

    NASA Astrophysics Data System (ADS)

    Sing, M.; Meyer, J.; Hoinkis, M.; Glawion, S.; Blaha, P.; Gavrila, G.; Jacobsen, C. S.; Claessen, R.

    2007-12-01

    We have performed angle-dependent near-edge x-ray absorption fine structure measurements in the Auger electron yield mode on the correlated quasi-one-dimensional organic conductor tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ) in order to determine the orientation of the molecules in the topmost surface layer. We find that the tilt angles of the molecules with respect to the one-dimensional axis are essentially the same as in the bulk. Thus, we can rule out surface relaxation as the origin of the renormalized band widths which were inferred from the analysis of photoemission data within the one-dimensional Hubbard model. Thereby, recent theoretical results are corroborated which invoke long-range Coulomb repulsion as alternative explanation to understand the spectral dispersions of TTF-TCNQ quantitatively within an extended Hubbard model.

  16. Structural vs electronic origin of renormalized band widths in TTF-TCNQ: An angular dependent NEXAFS study

    SciTech Connect

    Sing, M.; Meyer, J.; Glawion, S.; Claessen, R.; Hoinkis, M.; Blaha, P.; Gavrila, G.; Jacobsen, C. S.

    2007-12-15

    We have performed angle-dependent near-edge x-ray absorption fine structure measurements in the Auger electron yield mode on the correlated quasi-one-dimensional organic conductor tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ) in order to determine the orientation of the molecules in the topmost surface layer. We find that the tilt angles of the molecules with respect to the one-dimensional axis are essentially the same as in the bulk. Thus, we can rule out surface relaxation as the origin of the renormalized band widths which were inferred from the analysis of photoemission data within the one-dimensional Hubbard model. Thereby, recent theoretical results are corroborated which invoke long-range Coulomb repulsion as alternative explanation to understand the spectral dispersions of TTF-TCNQ quantitatively within an extended Hubbard model.

  17. Bias-dependent molecular-level structure of electrical double layer in ionic liquid on graphite

    SciTech Connect

    Black, Jennifer M; Walters, Deron; Labuda, Aleksander; Feng, Guang; Hillesheim, Patrick C; Dai, Sheng; Cummings, Peter T; Kalinin, Sergei V; Proksch, Roger; Balke, Nina

    2013-01-01

    Bias-dependent structure of electrochemical double layers at liquid-solid interfaces underpin a multitude of phenomena in virtually all areas of scientific enquiry ranging from energy storage and conversion systems, biology, to geophysics and geochemistry. Here we report the bias-evolution of the electric double layer structure of an ionic liquid on highly ordered pyrolytic graphite as a model system for carbon-based electrodes for electrochemical supercapacitors measured by atomic force microscopy. Matching the observed structures to molecular dynamics simulations allows us to resolve steric effects due to cation and anion layers. We observe reconfiguration under applied bias and the orientational transitions in the Stern layer. The synergy between molecular dynamics simulation and experiment provides a comprehensive picture of structural phenomena and long- and short range interactions. This insight will improve understanding of the mechanism of charge storage in electrochemical capacitors on a molecular level which can be used to enhance their electrochemical performance.

  18. Three-dimensional visualization of large structures in the turbulent boundary layer

    NASA Astrophysics Data System (ADS)

    Hoyt, J. W.; Sellin, R. H. J.

    A new method of visualizing the coherent structures in the boundary layer is used to develop insight into how these structures form and to provide information on the relative frequency of typical shapes noticed in the near-wall flow. These results were achieved in a water channel using a recently developed tracer which remains as a moving dye streak while conforming to the convoluted motions in the boundary layer. The tracer is formulated from a surfactant-polymer-emulsion mixture which retains its capabilities as a marker of evolving flow motions in the boundary layer for a meter or more before eventually dispersing. Three-dimensional, continuous visualization of the structures can be obtained as they move along a flat plate. Photos and video frames demonstrate the evolution and properties of the most widely discussed boundary-layer structure, the Theodorsen (horseshoe) vortex.

  19. Controllable synthesis of layered Co-Ni hydroxide hierarchical structures for high-performance hybrid supercapacitors

    NASA Astrophysics Data System (ADS)

    Yuan, Peng; Zhang, Ning; Zhang, Dan; Liu, Tao; Chen, Limiao; Ma, Renzhi; Qiu, Guanzhou; Liu, Xiaohe

    2016-01-01

    A facile solvothermal method is developed for synthesizing layered Co-Ni hydroxide hierarchical structures by using hexamethylenetetramine (HMT) as alkaline reagent. The electrochemical measurements reveal that the specific capacitances of layered bimetallic (Co-Ni) hydroxides are generally superior to those of layered monometallic (Co, Ni) hydroxides. The as-prepared Co0.5Ni0.5 hydroxide hierarchical structures possesses the highest specific capacitance of 1767 F g-1 at a galvanic current density of 1 A g-1 and an outstanding specific capacitance retention of 87% after 1000 cycles. In comparison with the dispersed nanosheets of Co-Ni hydroxide, layered hydroxide hierarchical structures show much superior electrochemical performance. This study provides a promising method to construct hierarchical structures with controllable transition-metal compositions for enhancing the electrochemical performance in hybrid supercapacitors.

  20. Photovoltaic structures having a light scattering interface layer and methods of making the same

    SciTech Connect

    Liu, Xiangxin; Compaan, Alvin D.; Paudel, Naba Raj

    2015-10-13

    Photovoltaic (PV) cell structures having an integral light scattering interface layer configured to diffuse or scatter light prior to entering a semiconductor material and methods of making the same are described.

  1. Study of the effect of bolt diameter and washer on damping in layered and jointed structures

    NASA Astrophysics Data System (ADS)

    Nanda, B. K.

    2006-03-01

    In the present work, the mechanism of damping in layered and jointed structures with connecting bolts and washers have been extensively studied. A lot of experiments have been conducted on a number of specimens with connecting bolts of various diameters to study its effect on the damping capacity of the layered and jointed structures and to establish the authenticity of the theory developed. Intensity of interface pressure, diameter of the connecting bolts, washers, number of layers, kinematic coefficient of friction at the interfaces and frequency and amplitude of excitation are found to play a major role on the damping capacity of such structures. It is established that the damping capacity of structures jointed with connecting bolts can be improved substantially by increasing the number of layers connected with bolts of smaller diameters along with use of washers.

  2. Bevel Depth Profiling SIMS for Analysis of Layer Structures

    NASA Astrophysics Data System (ADS)

    Gillen, Greg; Wight, Scott; Chi, Peter; Fahey, Albert; Verkouteren, Jennifer; Windsor, Eric; Fenner, D. B.

    2003-09-01

    We are evaluating the use of bevel depth profiling Secondary Ion Mass Spectrometry (SIMS) for the characterization of layered semiconductor materials. In this procedure, a sub-degree angle bevel is cut into the analytical sample with an oxygen or cesium primary ion beam in a commercial SIMS instrument. The elemental distribution of the resulting bevel surface is then imaged with a focused ion beam in the same instrument. This approach offers maximum flexibility for depth profiling analysis. The primary beam energy, incident angle and species used to cut the bevel can be optimized to minimize ion beam mixing and surface topography independent of the conditions used for secondary ion analysis. In some cases, depth resolution can be greater than available from conventional depth profiling. Removal of residual surface damage/topography created during beveling has also been investigated by the cleaning of the bevel surfaces using gas-cluster ion beam sputtering before imaging analysis.

  3. Modeling basic features of biogeochemical structure of water column, bottom boundary layer and benthic boundary layer in changeable redox conditions

    NASA Astrophysics Data System (ADS)

    Yakushev, Evgeniy

    2013-04-01

    Climate Change affects oxygen depletion and leads to spreading of the bottom areas with hypoxic and anoxic conditions in the coastal areas of the seas and inland waters. This work aimed in estimation of a role of changes of redox conditions in the biogeochemical structure there. We use a 1-dimensional C-N-P-Si-O-S-Mn-Fe vertical transport-reaction model describing the water column, bottom boundary layer and benthic boundary layer with biogeochemical block simulating redox conditions changeability. A biogeochemical block is based on ROLM (RedOx Layer Model), that was constructed to simulate basic features of the water column biogeochemical structure changes in oxic, anoxic and changeable conditions (Yakushev et al., 2007). Organic matter formation and decay, reduction and oxidation of species of nitrogen, sulfur, manganese, iron, and the transformation of phosphorus species are parameterized in the model. ROLM includes a simplified ecological model with phytoplankton, zooplankton, aerobic autotrophic and heterotrophic bacteria, anaerobic autotrophic and heterotrophic bacteria. We simulate changes in the parameters distributions and fluxes connected with the vertical displacement of redox interface from the sediments to the water.

  4. Fabrication of multi-layered absorption structure for high quantum efficiency photon detectors

    SciTech Connect

    Fujii, Go; Fukuda, Daiji; Numata, Takayuki; Yoshizawa, Akio; Tsuchida, Hidemi; Fujino, Hidetoshi; Ishii, Hiroyuki; Itatani, Taro; Zama, Tatsuya; Inoue, Shuichiro

    2009-12-16

    We report on some efforts to improve a quantum efficiency of titanium-based optical superconducting transition edge sensors using the multi-layered absorption structure for maximizing photon absorption in the Ti layer. Using complex refractive index values of each film measured by a Spectroscopic Ellipsometry, we designed and optimized by a simulation code. An absorption measurement of fabricated structure was in good agreement with the design and was higher than 99% at optimized wavelength of 1550 nm.

  5. Perfect tunneling of obliquely-incident wave through a structure with a double-negative layer

    NASA Astrophysics Data System (ADS)

    Afanas'ev, S. A.; Sementsov, D. I.; Yakimov, Y. V.

    2016-06-01

    The oblique incidence of TE-polarized plane electromagnetic wave on a three-layered lossless structure containing the layer of double-negative medium is discussed. The resonant values of the angle of incidence are obtained, for which the perfect tunneling of electromagnetic power through the structure can be achieved. The results of exact numerical analysis are compared with approximate solution based on the model of symmetrical slab waveguide.

  6. PHYSICAL FOUNDATIONS OF QUANTUM ELECTRONICS: Multiple reflection method for electromagnetic waves in layered dielectric structures

    NASA Astrophysics Data System (ADS)

    Morozov, G. V.; Maev, R. G.; Drake, G. W. F.

    2001-09-01

    Reflection and transmission of a plane electromagnetic wave propagating in a layered dielectric structure with an arbitrary number of layers of various thicknesses are investigated. For the general case of oblique incidence of the wave on this structure, the reflection and transmission coefficients are calculated for both TE and TM waves using a multiple reflection method. An algorithm to apply the obtained formulas for numerical and analytical calculations is suggested.

  7. Effects of heat release on the large-scale structure in turbulent mixing layers

    NASA Astrophysics Data System (ADS)

    McMurtry, P. A.; Riley, J. J.; Metcalfe, R. W.

    1989-02-01

    The effects of chemical heat release on the large-scale structure in a chemically reacting turbulent mixing layer have been studied using three-dimensional time-dependent simulations. Moderate heat release is found to slow the development of the large-scale structures and to shift their wavelengths to larger scales. The results suggest that previously unexplained anomalies observed in the mean velocity profiles of reacting jets and mixing layers may be the result of vorticity generation by baroclinic torques.

  8. Controlling Structure from the Bottom-Up: Structural and Optical Properties of Layer-by-Layer Assembled Palladium Coordination-Based Multilayers

    SciTech Connect

    Altman,M.; Shukla, A.; Zubkov, T.; Evmenenko, G.; Dutta, P.; van der Boom, M.

    2006-01-01

    Layer-by-layer assembly of two palladium coordination-based multilayers on silicon and glass substrates is presented. The new assemblies consist of rigid-rod chromophores connected by terminal pyridine moieties to palladium centers. Both colloidal palladium and PdCl{sub 2}(PhCN){sub 2} were used in order to determine the effect of the metal complex precursor on multilayer structure and optical properties. The multilayers were formed by an iterative wet-chemical deposition process at room temperature in air on a siloxane-based template layer. Twelve consecutive deposition steps have been demonstrated resulting in structurally regular assemblies with an equal amount of chromophore and palladium added in each molecular bilayer. The optical intensity characteristics of the metal-organic films are clearly a function of the palladium precursor employed. The colloid-based system has a UV-vis absorption maximum an order of magnitude stronger than that of the PdCl{sub 2}-based multilayer. The absorption maximum of the PdCl{sub 2}-based film exhibits a significant red shift of 23 nm with the addition of 12 layers. Remarkably, the structure and physiochemical properties of the submicron scale PdCl{sub 2}-based structures are determined by the configuration of the {approx}15 Angstrom thick template layer. The refractive index of the PdCl2-based film was determined by spectroscopic ellipsometry. Well-defined three-dimensional structures, with a dimension of 5 m, were obtained using photopatterned template monolayers. The properties and microstructure of the films were studied by UV-vis spectroscopy, spectroscopic ellipsometry, atomic force microscopy (AFM), X-ray reflectivity (XRR), scanning electron microscopy (SEM), and aqueous contact angle measurements (CA).

  9. Fuselage Structure Response to Boundary Layer, Tonal Sound, and Jet Noise

    NASA Technical Reports Server (NTRS)

    Maestrello, L.

    2004-01-01

    Experiments have been conducted to study the response of curved aluminum and graphite-epoxy fuselage structures to flow and sound loads from turbulent boundary layer, tonal sound, and jet noise. Both structures were the same size. The aluminum structure was reinforced with tear stoppers, while the graphite-epoxy structure was not. The graphite-epoxy structure weighed half as much as the aluminum structure. Spatiotemporal intermittence and chaotic behavior of the structural response was observed, as jet noise and tonal sound interacted with the turbulent boundary layer. The fundamental tone distributed energy to other components via wave interaction with the turbulent boundary layer. The added broadband sound from the jet, with or without a shock, influenced the responses over a wider range of frequencies. Instantaneous spatial correlation indicates small localized spatiotemporal regions of convected waves, while uncorrelated patterns dominate the larger portion of the space. By modifying the geometry of the tear stoppers between panels and frame, the transmitted and reflected waves of the aluminum panels were significantly reduced. The response level of the graphite-epoxy structure was higher, but the noise transmitted was nearly equal to that of the aluminum structure. The fundamental shock mode is between 80 deg and 150 deg and the first harmonic is between 20 deg and 80 deg for the underexpanded supersonic jet impinging on the turbulent boundary layer influencing the structural response. The response of the graphite-epoxy structure due to the fundamental mode of the shock impingement was stabilized by an externally fixed oscillator.

  10. Cooperation in group-structured populations with two layers of interactions.

    PubMed

    Zhang, Yanling; Fu, Feng; Chen, Xiaojie; Xie, Guangming; Wang, Long

    2015-01-01

    Recently there has been a growing interest in studying multiplex networks where individuals are structured in multiple network layers. Previous agent-based simulations of games on multiplex networks reveal rich dynamics arising from interdependency of interactions along each network layer, yet there is little known about analytical conditions for cooperation to evolve thereof. Here we aim to tackle this issue by calculating the evolutionary dynamics of cooperation in group-structured populations with two layers of interactions. In our model, an individual is engaged in two layers of group interactions simultaneously and uses unrelated strategies across layers. Evolutionary competition of individuals is determined by the total payoffs accrued from two layers of interactions. We also consider migration which allows individuals to move to a new group within each layer. An approach combining the coalescence theory with the theory of random walks is established to overcome the analytical difficulty upon local migration. We obtain the exact results for all "isotropic" migration patterns, particularly for migration tuned with varying ranges. When the two layers use one game, the optimal migration ranges are proved identical across layers and become smaller as the migration probability grows. PMID:26632251

  11. Cooperation in group-structured populations with two layers of interactions

    PubMed Central

    Zhang, Yanling; Fu, Feng; Chen, Xiaojie; Xie, Guangming; Wang, Long

    2015-01-01

    Recently there has been a growing interest in studying multiplex networks where individuals are structured in multiple network layers. Previous agent-based simulations of games on multiplex networks reveal rich dynamics arising from interdependency of interactions along each network layer, yet there is little known about analytical conditions for cooperation to evolve thereof. Here we aim to tackle this issue by calculating the evolutionary dynamics of cooperation in group-structured populations with two layers of interactions. In our model, an individual is engaged in two layers of group interactions simultaneously and uses unrelated strategies across layers. Evolutionary competition of individuals is determined by the total payoffs accrued from two layers of interactions. We also consider migration which allows individuals to move to a new group within each layer. An approach combining the coalescence theory with the theory of random walks is established to overcome the analytical difficulty upon local migration. We obtain the exact results for all “isotropic” migration patterns, particularly for migration tuned with varying ranges. When the two layers use one game, the optimal migration ranges are proved identical across layers and become smaller as the migration probability grows. PMID:26632251

  12. The impact of horizontal model grid resolution on the boundary layer structure over an idealized valley

    NASA Astrophysics Data System (ADS)

    Wagner, Johannes; Gohm, Alexander; Rotach, Mathias; Leukauf, Daniel; Posch, Christian

    2014-05-01

    The role of horizontal model grid resolution on the development of the daytime boundary layer over mountainous terrain is studied. A simple idealized valley topography with a cross-valley width of 20~km, a valley depth of 1.5~km and a constant surface heat flux forcing is used to generate upslope flows in a warming valley boundary layer. The goal of this study is to investigate differences in the upslope flow and boundary layer structure of the valley when its topography is either fully resolved, smoothed or not resolved by the numerical model. This is done by performing both large-eddy (LES) and kilometer-scale simulations with mesh sizes of 50, 1000, 2000, 4000, 5000 and 10000~m. In LES mode a valley inversion layer develops, which separates two vertically stacked circulation cells in an upper and lower boundary layer. These structures weaken with decreasing horizontal model grid resolution and change to a convective boundary layer similar to the one over an elevated flat plain when the valley is no longer resolved. Mean profiles of the LES run, which are obtained by horizontal averaging over the valley show a three-layer thermal structure and a secondary heat flux maximum at ridge height. Strong smoothing of the valley topography prevents the development of a valley inversion layer with stacked circulation cells and leads to higher valley temperatures due to smaller valley volumes. This investigation shows that a parameterization is needed in coarse resolution models to capture exchange processes over mountainous terrain.

  13. A perspective on coherent structures and conceptual models for turbulent boundary layer physics

    NASA Technical Reports Server (NTRS)

    Robinson, Stephen K.

    1990-01-01

    Direct numerical simulations of turbulent boundary layers have been analyzed to develop a unified conceptual model for the kinematics of coherent motions in low Reynolds number canonical turbulent boundary layers. All classes of coherent motions are considered in the model, including low-speed streaks, ejections and sweeps, vortical structures, near-wall and outer-region shear layers, sublayer pockets, and large-scale outer-region eddies. The model reflects the conclusions from the study of the simulated boundary layer that vortical structures are directly associated with the production of turbulent shear stresses, entrainment, dissipation of turbulence kinetic energy, and the fluctuating pressure field. These results, when viewed from the perspective of the large body of published work on the subject of coherent motions, confirm that vortical structures may be considered the central dynamic element in the maintenance of turbulence in the canonical boundary layer. Vortical structures serve as a framework on which to construct a unified picture of boundary layer structure, providing a means to relate the many known structural elements in a consistent way.

  14. Effect of electron collecting metal oxide layer in normal and inverted structure polymer solar cells

    NASA Astrophysics Data System (ADS)

    Ng, A.; Liu, X.; Sun, Y. C.; Djurišić, A. B.; Ng, A. M. C.; Chan, W. K.

    2013-12-01

    We performed a systematic study of the effect of electron collecting metal oxide layer on the performance of P3HT: PCBM solar cells. Zinc oxide (ZnO) or titanium dioxide (TiO2) buffer layers were prepared by either e-beam evaporation or solution processing method. We also compared the photovoltaic performance of inserting the buffer layer between indium tin oxide (ITO) and the polymer layer for the inverted structure (ITO/ ZnO or TiO2/P3HT:PCBM/V2O5/Au) as well as inserting the buffers layers between the polymer and the aluminum electrode for the conventional structure (ITO/V2O5/P3HT:PCBM/ZnO or TiO2/Al). The results are shown in detail.

  15. Effect of electron collecting metal oxide layer in normal and inverted structure polymer solar cells

    SciTech Connect

    Ng, A.; Liu, X.; Sun, Y. C.; Djurišić, A. B.; Ng, A. M. C.; Chan, W. K.

    2013-12-04

    We performed a systematic study of the effect of electron collecting metal oxide layer on the performance of P3HT: PCBM solar cells. Zinc oxide (ZnO) or titanium dioxide (TiO{sub 2}) buffer layers were prepared by either e-beam evaporation or solution processing method. We also compared the photovoltaic performance of inserting the buffer layer between indium tin oxide (ITO) and the polymer layer for the inverted structure (ITO/ ZnO or TiO{sub 2}/P3HT:PCBM/V{sub 2}O{sub 5}/Au) as well as inserting the buffers layers between the polymer and the aluminum electrode for the conventional structure (ITO/V{sub 2}O{sub 5}/P3HT:PCBM/ZnO or TiO{sub 2}/Al). The results are shown in detail.

  16. Structure of a Magnetic Flux Annihilation Layer Formed by the Collision of Supersonic, Magnetized Plasma Flows

    NASA Astrophysics Data System (ADS)

    Suttle, L. G.; Hare, J. D.; Lebedev, S. V.; Swadling, G. F.; Burdiak, G. C.; Ciardi, A.; Chittenden, J. P.; Loureiro, N. F.; Niasse, N.; Suzuki-Vidal, F.; Wu, J.; Yang, Q.; Clayson, T.; Frank, A.; Robinson, T. S.; Smith, R. A.; Stuart, N.

    2016-06-01

    We present experiments characterizing the detailed structure of a current layer, generated by the collision of two counterstreaming, supersonic and magnetized aluminum plasma flows. The antiparallel magnetic fields advected by the flows are found to be mutually annihilated inside the layer, giving rise to a bifurcated current structure—two narrow current sheets running along the outside surfaces of the layer. Measurements with Thomson scattering show a fast outflow of plasma along the layer and a high ion temperature (Ti˜Z ¯ Te , with average ionization Z ¯=7 ). Analysis of the spatially resolved plasma parameters indicates that the advection and subsequent annihilation of the inflowing magnetic flux determines the structure of the layer, while the ion heating could be due to the development of kinetic, current-driven instabilities.

  17. Ordered mixed-layer structures in the Mighei carbonaceous chondrite matrix

    NASA Technical Reports Server (NTRS)

    Mackinnon, I. D. R.

    1982-01-01

    High resolution transmission electron microscopy of the Mighei carbonaceous chondrite matrix has revealed the presence of a new mixed layer structure material. This mixed-layer material consists of an ordered arrangement of serpentine-type (S) and brucite-type (B) layers in the sequence SBBSBB. Electron diffraction and imaging techniques show that the basal periodicity is approximately 17 A. Discrete crystals of SBB-type material are typically curved, of small size (less than 1 micron) and show structural variations similar to the serpentine group minerals. Mixed-layer material also occurs in association with planar serpentine. Characteristics of SBB-type material are not consistent with known terrestrial mixed-layer clay minerals. Evidence for formation by a condensation event or by subsequent alteration of pre-existing material is not yet apparent.

  18. Structural analysis of infinite layer superlattices grown by pulsed laser deposition

    NASA Astrophysics Data System (ADS)

    Del Vecchio, A.; Tapfer, L.; Aruta, C.; Balestrino, G.; Petrocelli, G.

    1996-07-01

    In this work we investigate the structural properties of SrCuO2/CaCuO2 infinite layer superlattices by high-resolution x-ray diffraction and x-ray specular reflectivity measurements. The infinite layer superlattices are grown by pulsed laser deposition on slightly misoriented (001) SrTiO3 substrates. We demonstrate that good quality superlattices with few monolayers thick constituent SrCuO2 and CaCuO2 layers can be grown having an interface roughness of less than 3-4 Å. A strain analysis of the epitaxial film shows that the SrCuO2 layers are completely relaxed with respect to the substrate. However, the CaCuO2 layers are elastically strained with respect to the SrCuO2 layer. The Poisson ratio of the CaCuO2 is estimated to be 0.40±0.08.

  19. The investigation of hydrogenation influence on structure changes of zirconium with nickel layer

    NASA Astrophysics Data System (ADS)

    Kudiiarov, V. N.; Bordulev, Yu S.; Laptev, R. S.; Pushilina, N. S.; Kashkarov, E. B.; Syrtanov, M. S.

    2016-06-01

    The results of experimental investigation of hydrogenation influence on structure changes of zirconium alloy (Zr-1%Nb) with thin nickel layer have presented in this work. Nickel layer was formed by magnetron sputter deposition. Hydrogenation was carried out at gas atmosphere at constant temperature. Different hydrogen concentrations were obtained by varying time of hydrogenation. Defect and phase structure was studied by means of X-ray diffraction, glow discharge optical emission spectroscopy, positron lifetime and Doppler broadening spectroscopies. New experimental data about the evolution of the positron annihilation parameters depending on hydrogen concentration in Zr-1Nb alloy with nickel layer was obtained.

  20. An experimental study of combustion: The turbulent structure of a reacting shear layer formed at a rearward-facing step. Ph.D. Thesis. Final Report

    NASA Technical Reports Server (NTRS)

    Pitz, R. W.

    1981-01-01

    A premixed propane-air flame is stabilized in a turbulent free shear layer formed at a rearward-facing step. The mean and rms averages of the turbulent velocity flow field were determined by LDV for both reacting and non-reacting flows. The reaching flow was visualized by high speed schlieren photography. Large scale structures dominate the reacting shear layer. The growth of the large scale structures is tied to the propagation of the flame. The linear growth rate of the reacting shear layer defined by the mean velocity profiles is unchanged by combustion but the virtual origin is shifted downstream. The reacting shear layer based on the mean velocity profiles is shifted toward the recirculation zone and the reattachments lengths are shortened by 30%.

  1. On the structural origins of ferroelectricity in HfO{sub 2} thin films

    SciTech Connect

    Sang, Xiahan; Grimley, Everett D.; LeBeau, James M.; Schenk, Tony; Schroeder, Uwe

    2015-04-20

    Here, we present a structural study on the origin of ferroelectricity in Gd doped HfO{sub 2} thin films. We apply aberration corrected high-angle annular dark-field scanning transmission electron microscopy to directly determine the underlying lattice type using projected atom positions and measured lattice parameters. Furthermore, we apply nanoscale electron diffraction methods to visualize the crystal symmetry elements. Combined, the experimental results provide unambiguous evidence for the existence of a non-centrosymmetric orthorhombic phase that can support spontaneous polarization, resolving the origin of ferroelectricity in HfO{sub 2} thin films.

  2. Layered CMR manganites: Structure, properties, and unconventional magnetism

    SciTech Connect

    Mitchell, J.F.; Argyriou, D.N.; Potter, C.D.; Jorgensen, J.D.; Hinks, D.G.; Bader, S.D.

    1996-12-31

    Neutron powder diffraction studies of the layered compounds R{sub 1.2}Sr{sub 1.8}Mn{sub 2}O{sub 7}, (R = La, Pr, Nd), RSr{sub 2}Mn{sub 2}O{sub 7} (R = Pr, Nd), and La{sub 1.4}Sr{sub 1.6}Mn{sub 2}O{sub 7} show that the degree of distortion of the MnO{sub 6} octahedra do not correlate with the appearance of a metal-insulator (MI) transition in these compounds. Instead, the in-plane Mn-O bond length appears to be a better indicator of the electronic behavior. Detailed bulk magnetization studies on single crystal La{sub 1.2}Sr{sub 1.8}Mn{sub 2}O{sub 7} show that there are three magnetic regimes as a function of temperature: paramagnetic insulator, short-range ordered (SRO) ferromagnet, and long-range ordered (LRO) ferromagnet. Scaling analysis indicates that a 2D finite-size XY model is an appropriate description of the magnetic state in the SRO regime.

  3. Sliding Contact Fatigue Damage in Layered Ceramic Structures

    PubMed Central

    Kim, Jae-Won; Kim, Joo-Hyung; Thompson, Van P.; Zhang, Yu

    2016-01-01

    Porcelain veneered restorations often chip and fracture from repeated occlusal loading, making fatigue studies relevant. Most fatigue studies are limited to uniaxial loading without sliding motion. We hypothesize that biaxial loading (contact-load-slide-liftoff, simulating a masticatory cycle) as compared to uniaxial loading accelerates the fatigue of layered ceramics. Monolithic glass plates were epoxy joined to polycarbonate substrates as a transparent model for an all-ceramic crown on dentin. Uniaxial and biaxial cyclic contact was applied through a hard sphere in water with a mouth-motion machine. The uniaxial (contact-load-hold-liftoff) and traditional R-ratio fatigue (indenter never leaves the specimen surface) produced a similar lifespan, while biaxial fatigue was more severe. The accelerated crack growth rate in biaxial fatigue is attributed to enhanced tensile stresses at the trailing edges of a moving indenter. Fracture mechanics descriptions for damage evolution in brittle materials loaded repeatedly with a sliding sphere are provided. Clinical relevance is addressed. PMID:17959894

  4. A multi-layered vascular scaffold with symmetrical structure by bi-directional gradient electrospinning.

    PubMed

    Wu, Tong; Huang, Chen; Li, Dawei; Yin, Anlin; Liu, Wei; Wang, Jing; Chen, Jianfeng; Ei-Hamshary, Hany; Al-Deyab, Salem S; Mo, Xiumei

    2015-09-01

    Multi-layered scaffolds are advantageous in vascular tissue engineering, in consideration of better combination of biomechanics, biocompatibility and biodegradability than the scaffolds with single structure. In this study, a bi-directional gradient electrospinning method was developed to fabricate poly(l-lactide-co-caprolactone) (P(LLA-CL)), collagen and chitosan based tubular scaffold with multi-layered symmetrical structure. The multi-layered composite scaffold showed improved mechanical property and biocompatibility, in comparison to the blended scaffold using the same proportion of raw materials. Endothelialization on the multi-layered scaffold was accelerated owing to the bioactive surface made of pure natural materials. hSMCs growth showed the similar results because of its better biocompatibility. Additionally, fibers morphology change, pH value balance and long term mechanical support results showed that the gradient structure effectively improved biodegradability. PMID:26101818

  5. Electronic structures of single- and multi-layer epitaxial graphene on SiC (0001)

    NASA Astrophysics Data System (ADS)

    Kim, Seungchul; Ihm, Jisoon; Son, Young-Woo

    2009-03-01

    The electronic structures of single- and multi-layered epitaxial graphene on silicon carbide (0001) surface are studied theoretically. To calculate energy bands of the systems, we construct the simple Hamiltonian with tight-binding approximations. We confirm that the present simple model do give identical electronic structure to the previous ab-initio study on the single layer case [1]. We extend the model up to four epitaxial graphene layers to explain various interesting experimental findings. The roles of the coupling between graphenes and the buffer layer, and their large scale reconstructions to the electronic structures are also investigated. [1] S. Kim, J. Ihm, H. J. Choi, Y.-W. Son, Phys. Rev. Lett. 100, 176802 (2008).

  6. Coherent structures in a turbulent mixing layer - A comparison between direct numerical simulations and experiments

    NASA Technical Reports Server (NTRS)

    Metcalfe, R. W.; Menon, S.; Hussain, A. K. M. F.

    1985-01-01

    An eduction scheme has been developed in an attempt to determine the characteristics of large-scale vortical structures in a turbulent mixing layer. This analysis scheme has been applied to a set of experimental data taken in a new, larger mixing layer facility designed to minimize boundary and resonance effects. A similar scheme has been developed to apply to the results of a direct numerical simulation of a temporally growing mixing layer. A comparison of the two approaches shows important similarities in the coherent structures. The numerical simulations indicate that low levels of coherent forcing can dramatically change the evolution of the mixing layer. In the absence of such forcing, the numerical simulations and experiments show a lack of regularity in the transverse position, spacing, amplitude, shape and spanwise coherence of the large-scale vortical structures.

  7. Paleocene and Early Eocene volcanic ash layers in the Schlieren Flysch, Switzerland: U-Pb dating and Hf-isotopes of zircons, pumice geochemistry and origin

    NASA Astrophysics Data System (ADS)

    Koch, Simone; Winkler, Wilfried; Von Quadt, Albrecht; Ulmer, Peter

    2015-11-01

    Thin mm to cm thick bentonite layers of Paleocene to Early Eocene age in the Tonsteinschichten of the Schlieren Flysch represent volcanic ash layers. Heavy mineral analysis of the layers indicates basic to acidic volcanic sources. U/Pb dating of single zircon crystals of a Paleocene layer (WW1948) by LA-ICP-MS points to an eruption at 59.87 ± 0.41 Ma, whereas ID-TIMS shows an eruption age of 60.96 ± 0.07 Ma. Taking into account the external precision of LA-ICP-MS analyses of 1-2% both ages are overlapping and indicate an apparent minimal durations of zircon crystallization of 350 ka. Hf-isotope analysis of the same zircon crystals reveals the hybrid character of the source magma. The geochemical composition of the pumice grains of all bentonite layers is strongly affected by alteration. Nevertheless, the original character of the volcanic source can be evaluated. The Paleocene ashes (Lower Tonsteinschichten, LT) show a more fractionated multi-element pattern than the ashes of Early Eocene (Upper Tonsteinschichten, UT). The LT ash series are of rhyodacite to dacite character whereas the UT ashes fall in the field of alkali basalts. Both ash series seem to originate from a within-plate volcanic setting according to their trace element concentrations. Geochemical and temporary counterparts can be found in ash layers from Anthering (Austria) and the Danish Basin. As proposed for those ashes, volcanism connected to the opening of the North Atlantic might be the source as well for the ashes in the Schlieren Flysch. By comparison of the composition of rocks from the British Paleogene Igneous Province BPIP and the Schlieren Flysch ashes many correlations can be drawn which supports the suggestion of a North Atlantic origin of the Alpine ashes.

  8. Experiments on near-wall structure of three-dimensional boundary layers

    NASA Technical Reports Server (NTRS)

    Flack, Karen A.; Johnston, J. P.

    1993-01-01

    Investigations of three-dimensional turbulent boundary layers have shown basic differences between two- and three-dimensional flows. These differences can significantly impact the modeling of three-dimensional flows since many flow models are based on results from two-dimensional boundary layers. In many cases the shear stress vector direction has been shown to lag relative to the direction of the mean velocity gradient as the cross flow grows downstream. Coincidence of these vectors is necessary for a scalar eddy viscosity modeling assumption. A second effect is a reduction in magnitude of the shear stress and/or the shear stress to turbulence energy ratio, a(sub 1). This reduction has been observed in several experiments. Recent numerical simulations also indicate wall-layer structural differences between two- and three-dimensional boundary layers. The differences in structure between two- and three-dimensional boundary layers was also addressed in the experiment of Littell & Eaton. The experiment used two-point correlations to investigate the vortical structures in a three dimensional boundary layer on a spinning disk. It was found that each sign of longitudinal vortex is equally likely to exist, but one sign of vorticity is associated with a structure which is better at producing ejections. The goal of the current investigation is to study the structure of the inner layers. Among other questions, the differences between the effects deduced from the three-dimensional flow simulations and the effects seen in experiments can be examined. The research concentrates on the structure of the wall-layer through flow visualization and direct turbulence measurements down to y(+) = 5.

  9. Solution structure of the origin DNA-binding domain of SV40 T-antigen.

    PubMed

    Luo, X; Sanford, D G; Bullock, P A; Bachovchin, W W

    1996-12-01

    The structure of the domain from simian virus 40 (SV40) large T-antigen that binds to the SV40 origin of DNA replication (T-ag-OBD131-260) has been determined by nuclear magnetic resonance spectroscopy. The overall fold, consisting of a central five-stranded antiparallel beta-sheet flanked by two alpha-helices on one side and one alpha-helix and one 3(10)-helix on the other, is a new one. Previous mutational analyses have identified two elements, termed A (approximately 152-155) and B2 (203-207), as essential for origin-specific recognition. These elements form two closely juxtaposed loops that define a continuous surface on the protein. The addition of a duplex oligonucleotide containing the origin recognition pentanucleotide GAGGC induces chemical shift changes and slows amide proton exchange in resonances from this region, indicating that this surface directly contacts the DNA. PMID:8946857

  10. Turbulent Structures and Coherence in the Atmospheric Surface Layer

    NASA Astrophysics Data System (ADS)

    Träumner, K.; Damian, Th.; Stawiarski, Ch.; Wieser, A.

    2015-01-01

    Organized structures in turbulent flow fields are a well-known and still fascinating phenomenon. Although these so-called coherent structures are obvious from visual inspection, quantitative assessment is a challenge and many aspects e.g., formation mechanisms and contribution to turbulent fluxes, are discussed controversially. During the "High Definition Clouds and Precipitation for Advancing Climate Prediction" Observational Prototype Experiment (HOPE) from April to May 2013, an advanced dual Doppler lidar technique was used to image the horizontal wind field near the surface for approximately 300 h. A visual inspection method, as well as a two-dimensional integral length scale analysis, were performed to characterize the observations qualitatively and quantitatively. During situations with forcing due to shear, the wind fields showed characteristic patterns in the form of clearly bordered, elongated areas of enhanced or reduced wind speed, which can be associated with near-surface streaks. During calm situations with strong buoyancy forcing, open cell patterns in the horizontal divergence field were observed. The measurement technique used enables the calculation of integral length scales of both horizontal wind components in the streamwise and cross-stream directions. The individual length scales varied considerably during the observation period but were on average shorter during situations with compared to strongly stable situations. During unstable situations, which were dominated by wind fields with structures, the streamwise length scales increased with increasing wind speed, whereas the cross-stream length scales decreased. Consequently, the anisotropy increased from 1 for calm situations to values of 2-3 for wind speeds of 8-10. During neutral to stable situations, the eddies were on average quite isotropic in the horizontal plane.

  11. Structure and friction-reducing property of the sulfide layer produced by ion sulfuration

    SciTech Connect

    Ning, Z.; Da-Ming, Z.; Yan-Hua, W.; Jia-Jun, L.; Xiao-Dong, F.; Ming-Xi, G.

    2000-04-01

    Sulfide layers with a certain thickness were made on the surface of 1045 and 52100 steels by means of the low-temperature ion sulfuration technique. Metallography, scanning electron microscope (SEM) + energy-dispersive x-ray analysis (EDX), and x-ray diffraction (XRD) were adopted to analyze the structure of sulfide layers; the tribological properties of the layers lubricated by paraffin oil were also investigated on a reciprocating tester. The results showed that sulfide layer is porous, and its structure is mainly composed of FeS, FeS{sub 2}, and substrate phases. The sulfide layer possessed a remarkable friction-reducing effect; its friction coefficient was lower on average, by about 50%, than that of the surface without layer. With the increase of layer thickness, its friction coefficient was unchanged, and under low load conditions, its operational period was prolonged. Under the same experimental conditions, the operational period of sulfide layer on 52100 steel was longer than that on 1045 steel, and its friction coefficient was lower as well.

  12. Instantaneous Wavenumber Estimation for Damage Quantification in Layered Plate Structures

    NASA Technical Reports Server (NTRS)

    Mesnil, Olivier; Leckey, Cara A. C.; Ruzzene, Massimo

    2014-01-01

    This paper illustrates the application of instantaneous and local wavenumber damage quantification techniques for high frequency guided wave interrogation. The proposed methodologies can be considered as first steps towards a hybrid structural health monitoring/ nondestructive evaluation (SHM/NDE) approach for damage assessment in composites. The challenges and opportunities related to the considered type of interrogation and signal processing are explored through the analysis of numerical data obtained via EFIT simulations of damage in CRFP plates. Realistic damage configurations are modeled from x-ray CT scan data of plates subjected to actual impacts, in order to accurately predict wave-damage interactions in terms of scattering and mode conversions. Simulation data is utilized to enhance the information provided by instantaneous and local wavenumbers and mitigate the complexity related to the multi-modal content of the plate response. Signal processing strategies considered for this purpose include modal decoupling through filtering in the frequency/wavenumber domain, the combination of displacement components, and the exploitation of polarization information for the various modes as evaluated through the dispersion analysis of the considered laminate lay-up sequence. The results presented assess the effectiveness of the proposed wavefield processing techniques as a hybrid SHM/NDE technique for damage detection and quantification in composite, plate-like structures.

  13. The plasma structure of coronal hole solar wind: Origins and evolution

    NASA Astrophysics Data System (ADS)

    Borovsky, Joseph E.

    2016-06-01

    Whereas slow solar wind is known to be highly structured, the fast (coronal hole origin) wind is usually considered to be homogeneous. Using measurements from Helios 1 + 2, ACE, Wind, and Ulysses, structure in the coronal hole origin solar wind is examined from 0.3 AU to 2.3 AU. Care is taken to collect and analyze intervals of "unperturbed coronal hole plasma." In these intervals, solar wind structure is seen in the proton number density, proton temperature, proton specific entropy, magnetic field strength, magnetic field to density ratio, electron heat flux, helium abundance, heavy-ion charge-state ratios, and Alfvenicity. Typical structure amplitudes are factors of 2, far from homogeneous. Variations are also seen in the solar wind radial velocity. Using estimates of the motion of the solar wind origin footpoint on the Sun for the various spacecraft, the satellite time series measurements are converted to distance along the photosphere. Typical variation scale lengths for the solar wind structure are several variations per supergranule. The structure amplitude and structure scale sizes do not evolve with distance from the Sun from 0.3 to 2.3 AU. An argument is quantified that these variations are the scale expected for solar wind production in open magnetic flux funnels in coronal holes. Additionally, a population of magnetic field foldings (switchbacks, reversals) in the coronal hole plasma is examined: this population evolves with distance from the Sun such that the magnetic field is mostly Parker spiral aligned at 0.3 AU and becomes more misaligned with distance outward.

  14. Ion beam-based characterization of multicomponent oxide thin films and thin film layered structures

    SciTech Connect

    Krauss, A.R.; Rangaswamy, M.; Lin, Yuping; Gruen, D.M.; Schultz, J.A.; Schmidt, H.K.; Chang, R.P.H.

    1992-11-01

    Fabrication of thin film layered structures of multi-component materials such as high temperature superconductors, ferroelectric and electro-optic materials, and alloy semiconductors, and the development of hybrid materials requires understanding of film growth and interface properties. For High Temperature Superconductors, the superconducting coherence length is extremely short (5--15 {Angstrom}), and fabrication of reliable devices will require control of film properties at extremely sharp interfaces; it will be necessary to verify the integrity of thin layers and layered structure devices over thicknesses comparable to the atomic layer spacing. Analytical techniques which probe the first 1--2 atomic layers are therefore necessary for in-situ characterization of relevant thin film growth processes. However, most surface-analytical techniques are sensitive to a region within 10--40 {Angstrom} of the surface and are physically incompatible with thin film deposition and are typically restricted to ultra high vacuum conditions. A review of ion beam-based analytical methods for the characterization of thin film and multi-layered thin film structures incorporating layers of multicomponent oxides is presented. Particular attention will be paid to the use of time-of-flight techniques based on the use of 1- 15 key ion beams which show potential for use as nondestructive, real-time, in-situ surface diagnostics for the growth of multicomponent metal and metal oxide thin films.

  15. Layers: A molecular surface peeling algorithm and its applications to analyze protein structures

    PubMed Central

    Karampudi, Naga Bhushana Rao; Bahadur, Ranjit Prasad

    2015-01-01

    We present an algorithm ‘Layers’ to peel the atoms of proteins as layers. Using Layers we show an efficient way to transform protein structures into 2D pattern, named residue transition pattern (RTP), which is independent of molecular orientations. RTP explains the folding patterns of proteins and hence identification of similarity between proteins is simple and reliable using RTP than with the standard sequence or structure based methods. Moreover, Layers generates a fine-tunable coarse model for the molecular surface by using non-random sampling. The coarse model can be used for shape comparison, protein recognition and ligand design. Additionally, Layers can be used to develop biased initial configuration of molecules for protein folding simulations. We have developed a random forest classifier to predict the RTP of a given polypeptide sequence. Layers is a standalone application; however, it can be merged with other applications to reduce the computational load when working with large datasets of protein structures. Layers is available freely at http://www.csb.iitkgp.ernet.in/applications/mol_layers/main. PMID:26553411

  16. Structural and magnetic properties of Co films on highly textured and randomly oriented C60 layers

    NASA Astrophysics Data System (ADS)

    Kim, Dong-Ok; Choi, Jun Woo; Lee, Dong Ryeol

    2016-03-01

    The structural and magnetic properties of Co/C60/pentacene and Co/C60 thin film structures were investigated. Atomic force microscopy and x-ray reflectivity analysis show that the presence or absence of a pentacene buffer layer leads to a highly textured or randomly oriented C60 layer, respectively. A Co film deposited on a randomly oriented C60 layer penetrates into the C60 layer when it is deposited at a slow deposition rate. The Co penetration can be minimized, regardless of the Co deposition rate, by growth on a highly textured and nanostructured C60/pentacene layer. Vibrating sample magnetometry measurements show that the saturation magnetization of Co/C60/pentacene is significantly reduced compared to that of Co/C60. On the other hand, the Co penetration does not seem to have an effect on the magnetic properties, suggesting that the structural properties of the Co and C60 layer, rather than the Co penetration into the organic C60 layer, are critical to the magnetic properties of the Co/C60.

  17. Layers: A molecular surface peeling algorithm and its applications to analyze protein structures

    NASA Astrophysics Data System (ADS)

    Karampudi, Naga Bhushana Rao; Bahadur, Ranjit Prasad

    2015-11-01

    We present an algorithm ‘Layers’ to peel the atoms of proteins as layers. Using Layers we show an efficient way to transform protein structures into 2D pattern, named residue transition pattern (RTP), which is independent of molecular orientations. RTP explains the folding patterns of proteins and hence identification of similarity between proteins is simple and reliable using RTP than with the standard sequence or structure based methods. Moreover, Layers generates a fine-tunable coarse model for the molecular surface by using non-random sampling. The coarse model can be used for shape comparison, protein recognition and ligand design. Additionally, Layers can be used to develop biased initial configuration of molecules for protein folding simulations. We have developed a random forest classifier to predict the RTP of a given polypeptide sequence. Layers is a standalone application; however, it can be merged with other applications to reduce the computational load when working with large datasets of protein structures. Layers is available freely at http://www.csb.iitkgp.ernet.in/applications/mol_layers/main.

  18. The ancient history of the structure of ribonuclease P and the early origins of Archaea

    PubMed Central

    2010-01-01

    Background Ribonuclease P is an ancient endonuclease that cleaves precursor tRNA and generally consists of a catalytic RNA subunit (RPR) and one or more proteins (RPPs). It represents an important macromolecular complex and model system that is universally distributed in life. Its putative origins have inspired fundamental hypotheses, including the proposal of an ancient RNA world. Results To study the evolution of this complex, we constructed rooted phylogenetic trees of RPR molecules and substructures and estimated RPP age using a cladistic method that embeds structure directly into phylogenetic analysis. The general approach was used previously to study the evolution of tRNA, SINE RNA and 5S rRNA, the origins of metabolism, and the evolution and complexity of the protein world, and revealed here remarkable evolutionary patterns. Trees of molecules uncovered the tripartite nature of life and the early origin of archaeal RPRs. Trees of substructures showed molecules originated in stem P12 and were accessorized with a catalytic P1-P4 core structure before the first substructure was lost in Archaea. This core currently interacts with RPPs and ancient segments of the tRNA molecule. Finally, a census of protein domain structure in hundreds of genomes established RPPs appeared after the rise of metabolic enzymes at the onset of the protein world. Conclusions The study provides a detailed account of the history and early diversification of a fundamental ribonucleoprotein and offers further evidence in support of the existence of a tripartite organismal world that originated by the segregation of archaeal lineages from an ancient community of primordial organisms. PMID:20334683

  19. Origin of the 'dike-like' structure and transitions in eruptive styles at Colton Crater, northern Arizona: San Francisco Volcanic Field REU

    NASA Astrophysics Data System (ADS)

    Witter, M. R.; Ort, M. H.; Leudemann, L. A.

    2013-12-01

    Colton Crater, located within the San Francisco Volcanic Field (SFVF) in northern Arizona, is one of over 600 scoria cones in the field. Unlike most other volcanoes in the SFVF, Colton Crater is characterized as a hybrid volcano that had Strombolian, Hawaiian, and Surtseyan explosions. Surtseyan explosions led to the excavation of the center of the volcano, creating a large 1.3-km-diameter crater with a 30-m post-phreatomagmatic scoria cone at its center. A vertical erosion-resistant feature along the northern rim of the crater, originally mapped as a dike, provides valuable information about the sequence and timing of the transition to phreatomagmatic eruptions because it disrupts the otherwise continuous spatter layers deposited just prior to that change. Stratigraphic sections and paleomagnetic analysis of Colton Crater reveal the origin and timing of emplacement of this vertical structure and its place in the transitional eruptive history. The prominent upper layers in the crater walls show some variation throughout the crater, but generally are composed of agglutinated spatter, welded scoria and bombs, and rootless lava flows. The uppermost portion of the outward-dipping spatter layers that lie between the two saddles on the northern rim closely match the layers observed in the vertical structure, revealing that the structure is a section of rotated spatter. The characteristic remanent magnetization (ChRM), identified using alternating field (AF) demagnetization, shows the timing of the displacement of sections of the agglutinated spatter and welded cinder. Sites along the vertical structure yield ChRMs statistically identical to non-rotated sites, which indicates that rotation of the vertical structure occurred before the ChRM had been set, i.e., the layers were above the Curie temperature during rotation. The eruption started as Strombolian and Hawaiian perhaps because the flux of magma overpowered the influx of water from local aquifer formations, creating

  20. Design study of double-layer beam trajectory accelerator based on the Rhodotron structure

    NASA Astrophysics Data System (ADS)

    Jabbari, Iraj; Poursaleh, Ali Mohammad; Khalafi, Hossein

    2016-08-01

    In this paper, the conceptual design of a new structure of industrial electron accelerator based on the Rhodotron accelerator is presented and its properties are compared with those of Rhodotron-TT200 accelerator. The main goal of this study was to reduce the power of RF system of accelerator at the same output electron beam energy. The main difference between the new accelerator structure with the Rhodotron accelerator is the length of the coaxial cavity that is equal to the wavelength at the resonant frequency. Also two sets of bending magnets were used around the acceleration cavity in two layers. In the new structure, the beam crosses several times in the coaxial cavity by the bending magnets around the cavity at the first layer and then is transferred to the second layer using the central bending magnet. The acceleration process in the second layer is similar to the first layer. Hence, the energy of the electron beam will be doubled. The electrical power consumption of the RF system and magnet system were calculated and simulated for the new accelerator structure and TT200. Comparing the calculated and simulated results of the TT200 with those of experimental results revealed good agreement. The results showed that the overall electrical power consumption of the new accelerator structure was less than that of the TT200 at the same energy and power of the electron beam. As such, the electrical efficiency of the new structure was improved.

  1. Analysis of mixed-layer clay mineral structures

    USGS Publications Warehouse

    Bradley, W.F.

    1953-01-01

    Among the enormously abundant natural occurrences of clay minerals, many examples are encountered in which no single specific crystallization scheme extends through a single ultimate grain. The characterization of such assemblages becomes an analysis of the distribution of matter within such grains, rather than the simple identification of mineral species. It having become established that the particular coordination complex typified by mica is a common component of many natural subcrystalline assemblages, the opportunity is afforded to analyze scattering from random associations of these complexes with other structural units. Successful analyses have been made of mixed hydration states of montmorillonite, of montmorillonite with mica, of vermiculite with mica, and of montmorillonite with chlorite, all of which are variants of the mica complex, and of halloysite with hydrated halloysite.

  2. Polar cap F layer patches: structure and dynamics

    SciTech Connect

    Weber, E.J.; Klobuchar, J.A.; Buchau, J.; Carlson, H.C.; Livingston, R.C.

    1986-11-01

    Coordinated measurements of F-region plasma patches were conducted on February 3/4, 1984, from Thule and Sondrestrom, Greenland. Optical, ionsonde, amplitude scintillation, total electron content (TEC), and incoherent scatter radar measurements were combined to reveal several new aspects of the structure and transport of these localized regions of enhanced F region ionization. For the first time, these patches were directly tracked flowing in the antisunward direction over distances of 3000 km from the center of the polar cap to the poleward edge of the auroral oval. Quantative measurements of TEC show increases of 10-15 TEC units within the patches, above a background polar cap value of 5 TEC units. Amplitude scintillation measurements show the presence of ionospheric irregularities through the entire patch, with a weak indication of stronger scintillation on the trailing (or E x B unstable) edge.

  3. Polar cap F layer patches: structure and dynamics

    SciTech Connect

    Weber, E.J.; Klobuchar, J.A.; Buchau, J.; Carlson H.C. Jr.; Livingston, R.C.; De La Beaujardiere, O.; McCready, M.; Moore, J.G.; Bishop, G.J.

    1986-11-01

    Coordinated measurements of F region plasma patches were conducted on February 3/4, 1984, from Thule and Sondrestrom, Greenland. Optical, ionosonde, amplitude scintillation, total electron content (TEC), and incoherent scatter radar measurements were combined to reveal several new aspects of the structure and transport of these localized regions of enhanced F region ionization. For the first time these patches were directly tracked flowing in the antisunward direction over distances of 3000 km from the center of the polar cap to the poleward edge of the auroral oval. Quantitative measurements of TEC show increases of 10--15 TEC units within the patches, above a background polar cap value of 5 TEC units. Amplitude scintillation measurements show the presence of ionospheric irregularities through the entire patch, with a weak indication of stronger scintillation on the trailing (or E x B unstable) edge.

  4. Saturn layered structure and homogeneous evolution models with different EOSs

    NASA Astrophysics Data System (ADS)

    Nettelmann, Nadine; Püstow, Robert; Redmer, Ronald

    2013-07-01

    The core mass of Saturn is commonly assumed to be 10-25M⊕ as predicted by interior models with various equations of state (EOSs) and the Voyager gravity data, and hence larger than that of Jupiter (0-10M⊕). We here re-analyze Saturn's internal structure and evolution by using more recent gravity data from the Cassini mission and different physical equations of state: the ab initio LM-REOS which is rather soft in Saturn's outer regions but stiff at high pressures, the standard Sesame-EOS which shows the opposite behavior, and the commonly used SCvH-i EOS. For all three EOS we find similar core mass ranges, i.e. of 0-20M⊕ for SCvH-i and Sesame EOS and of 0-17M⊕ for LM-REOS. Assuming an atmospheric helium mass abundance of 18%, we find maximum atmospheric metallicities, Zatm of 7× solar for SCvH-i and Sesame-based models and a total mass of heavy elements, MZ of 25-30M⊕. Some models are Jupiter-like. With LM-REOS, we find MZ = 16-20M⊕, less than for Jupiter, and Zatm ≲ 3× solar. For Saturn, we compute moment of inertia values λ = 0.2355(5). Furthermore, we confirm that homogeneous evolution leads to cooling times of only ˜2.5 Gyr, independent on the applied EOS. Our results demonstrate the need for accurately measured atmospheric helium and oxygen abundances, and of the moment of inertia for a better understanding of Saturn's structure and evolution.

  5. The structure of nanoscale polaron correlations in the layered manganites

    NASA Astrophysics Data System (ADS)

    Campbell, Branton

    2002-03-01

    Recent x-ray and neutron scattering experiments have uncovered nanoscale polaron correlations that play an essential role in the colossal magnetoresistive (CMR) behavior of the perovskite manganites. Short-range polaronic order decreases the charge-carrier mobility of the high-temperature paramagnetic state, and subsequently becomes unstable at the ferromagnetic transition, contributing to a pronounced resistivity decrease at T_C. In the bilayered perovskite system La_2-2xSr_1+2xMn_2O7 (0.3 < x < 0.5), weak x-ray diffuse scattering maxima reveal a one-dimensional incommensurate structural modulation with wavevector q = (0.3, 0, ± 1) and a correlation length of 10 to 30 Angstroms. A crystallographic analysis of the diffuse satellite intensities yields a longitudinal Jahn-Teller stretch mode suggestive of charge-density-wave fluctuations. Within the correlated regions, polaronic eg electrons form a striped pattern of occupied d(3x^2-r^2) orbitals. Dynamic polaron correlations of the zig-zag orbital type are also observed above TC and exhibit distinctly glassy behavior. These structures provide unique insights into the nature of strongly correlated polaronic systems. Collaborators: R. Osborn, D.N. Argyriou, S. Rosenkranz, L. Vasiliu-Doloc, J.F. Mitchell, S.K. Sinha, J.W. Lynn, C.D. Ling, Z. Islam, U. Ruett, and A. Berger. This work was supported by the U.S. DOE Office of Science contract No. W-31-109-ENG-38.

  6. Origins of Dirac cones and parity dependent electronic structures of α-graphyne derivatives and silagraphynes.

    PubMed

    Qin, Xuming; Liu, Yi; Chi, Baoqian; Zhao, Xinluo; Li, Xiaowu

    2016-08-18

    Compared with graphene, graphyne and its derivatives possess more diversified atomic configurations and richer electronic structures including Dirac cones (DCs) and metallic features depending on the parity of the number of sp carbon atoms of graphynes. This report described conceptually the process of DC formation of α-graphyne within a tight-binding framework parameterized from density functional calculations. We propose a "triple coupling" mechanism elucidating the DC formation and some flat bands of α-graphynes where the couplings among the three sp carbon chain atoms are critical. The extension of this mechanism further explains the origins of DCs of silagraphynes and the parity dependent electronic structures of α-graphyne derivatives with extended sp carbon chains. Understanding these origins helps in tuning electronic properties in the design of C or C-Si based nanoelectronic devices. PMID:27485886

  7. The effects of vortex structure and vortex translation on the tropical cyclone boundary layer wind field

    NASA Astrophysics Data System (ADS)

    Williams, Gabriel J.

    2015-03-01

    The effects of vortex translation and radial vortex structure in the distribution of boundary layer winds in the inner core of mature tropical cyclones are examined using a high-resolution slab model and a multilevel model. It is shown that the structure and magnitude of the wind field (and the corresponding secondary circulation) depends sensitively on the radial gradient of the gradient wind field above the boundary layer. Furthermore, it is shown that vortex translation creates low wave number asymmetries in the wind field that rotate anticyclonically with height. A budget analysis of the steady state wind field for both models was also performed in this study. Although the agradient force drives the evolution of the boundary layer wind field for both models, it is shown that the manner in which the boundary layer flow responds to this force differs between the two model representations. In particular, the inner core boundary layer flow in the slab model is dominated by the effects of horizontal advection and horizontal diffusion, leading to the development of shock structures in the model. Conversely, the inner core boundary layer flow in the multilevel model is primarily influenced by the effects of vertical advection and vertical diffusion, which eliminates shock structures in this model. These results further indicate that special care is required to ensure that qualitative applications from slab models are not unduly affected by the neglect of vertical advection. This article was corrected on 31 MAR 2015. See the end of the full text for details.

  8. Cation Effects on the Layer Structure of Biogenic Mn-Oxides

    SciTech Connect

    Zhu, M.; Ginder-Vogel, M; Parikh, S; Feng, X; Sparks, D

    2010-01-01

    Biologically catalyzed Mn(II) oxidation produces biogenic Mn-oxides (BioMnO{sub x}) and may serve as one of the major formation pathways for layered Mn-oxides in soils and sediments. The structure of Mn octahedral layers in layered Mn-oxides controls its metal sequestration properties, photochemistry, oxidizing ability, and topotactic transformation to tunneled structures. This study investigates the impacts of cations (H{sup +}, Ni(II), Na{sup +}, and Ca{sup 2+}) during biotic Mn(II) oxidation on the structure of Mn octahedral layers of BioMnO{sub x} using solution chemistry and synchrotron X-ray techniques. Results demonstrate that Mn octahedral layer symmetry and composition are sensitive to previous cations during BioMnO{sub x} formation. Specifically, H{sup +} and Ni(II) enhance vacant site formation, whereas Na{sup +} and Ca{sup 2+} favor formation of Mn(III) and its ordered distribution in Mn octahedral layers. This study emphasizes the importance of the abiotic reaction between Mn(II) and BioMnO{sub x} and dependence of the crystal structure of BioMnO{sub x} on solution chemistry.

  9. Layered structure and related magnetic properties for annealed Fe/Ir(111) ultrathin films

    SciTech Connect

    Jiang, Pei-Cheng; Chen, Wei-Hsiang; Hsieh, Chen-Yuan; Tsay, Jyh-Shen

    2015-05-07

    After annealing treatments for fcc-Fe/Ir(111) below 600 K, the surface layers remain pseudomorphic. The Ir(111) substrate plays an important role on the expanded Fe lattice. At temperatures between 750 and 800 K, the surface composition shows a stable state and a c(2 × 4) structure is observed. We discover a layered structure composed of some Fe atoms on the top of a Fe{sub 0.5}Ir{sub 0.5} interfacial alloy supported on the Ir(111) substrate. The competition between the negative formation heat of Fe{sub 0.5}Ir{sub 0.5} and surface free energy of Fe causes the formation of layered structure. The existence of ferromagnetic dead layer coincides with the formation of fcc-Fe for ultrathin Fe on Fe{sub 0.5}Ir{sub 0.5}/Ir(111). For Fe films thicker than three monolayers, the linear increase of the Kerr intensity versus the Fe coverage is related to the growing of bcc-Fe on the surface where the Fe layer is incoherent to the underlying Fe{sub 0.5}Ir{sub 0.5}/Ir(111). These results emphasize the importance of the substrate induced strain and layered structure of Fe/Fe{sub 0.5}Ir{sub 0.5}/Ir(111) on the magnetic properties and provide valuable information for future applications.

  10. S-layers at second glance? Altiarchaeal grappling hooks (hami) resemble archaeal S-layer proteins in structure and sequence

    PubMed Central

    Perras, Alexandra K.; Daum, Bertram; Ziegler, Christine; Takahashi, Lynelle K.; Ahmed, Musahid; Wanner, Gerhard; Klingl, Andreas; Leitinger, Gerd; Kolb-Lenz, Dagmar; Gribaldo, Simonetta; Auerbach, Anna; Mora, Maximilian; Probst, Alexander J.; Bellack, Annett; Moissl-Eichinger, Christine

    2015-01-01

    The uncultivated “Candidatus Altiarchaeum hamiconexum” (formerly known as SM1 Euryarchaeon) carries highly specialized nano-grappling hooks (“hami”) on its cell surface. Until now little is known about the major protein forming these structured fibrous cell surface appendages, the genes involved or membrane anchoring of these filaments. These aspects were analyzed in depth in this study using environmental transcriptomics combined with imaging methods. Since a laboratory culture of this archaeon is not yet available, natural biofilm samples with high Ca. A. hamiconexum abundance were used for the entire analyses. The filamentous surface appendages spanned both membranes of the cell, which are composed of glycosyl-archaeol. The hami consisted of multiple copies of the same protein, the corresponding gene of which was identified via metagenome-mapped transcriptome analysis. The hamus subunit proteins, which are likely to self-assemble due to their predicted beta sheet topology, revealed no similiarity to known microbial flagella-, archaella-, fimbriae- or pili-proteins, but a high similarity to known S-layer proteins of the archaeal domain at their N-terminal region (44–47% identity). Our results provide new insights into the structure of the unique hami and their major protein and indicate their divergent evolution with S-layer proteins. PMID:26106369

  11. Measured response of a complex structure to supersonic turbulent boundary layers

    NASA Technical Reports Server (NTRS)

    Maestrello, L.; Monteith, J. H.; Manning, J. C.; Smith, D. L.

    1976-01-01

    Measurements of the response of a large frame-stringer panel excited by supersonic turbulent boundary layer are reported. The statistical description of the wall pressure fluctuations in terms of the mean flow parameters governing the turbulent boundary layer is given. These results can be used in the development of design criteria on the response of sidewall structure of a large airplane in supersonic flight, since both forcing field and structure are realistic. Results indicate the significant importance of the modal coupling and the acoustic damping. The acoustic damping plays a major role in the response of the structure.

  12. Layers and tubes of fluorographene C4F: Stability, structural and electronic properties from DFTB calculations

    NASA Astrophysics Data System (ADS)

    Enyashin, A. N.; Ivanovskii, A. L.

    2013-06-01

    By means of the DFTB band structure calculations we have explored the layers' isomerism of fluorographene C4F. The relative stability, structural and electronic properties of the C4F layers and nanotubes have been revealed depending on the possible types of fluorine coverage: single-sided, double-sided or so-called non-uniform variants. Our main finding is that the aforementioned types of fluorine coverage are crucial for the morphology of these materials. At the non-uniform or single-sided coverage types the C4F structures aspire to the spontaneous folding in order to minimize their surface tension.

  13. Electronic Structure and the Properties of Phosphorene and Few-Layer Black Phosphorus

    NASA Astrophysics Data System (ADS)

    Fukuoka, Shuhei; Taen, Toshihiro; Osada, Toshihito

    2015-12-01

    A single atomic layer of black phosphorus, phosphorene, was experimentally realized in 2014. It has a puckered honeycomb lattice structure and a semiconducting electronic structure. In the first part of this paper, we use a simple LCAO model, and qualitatively discuss the electronic structure of phosphorene systems under electric and magnetic fields, especially noting their midgap edge states. The next part is devoted to the review of the progress in research on phosphorene over the past one year since its realization in 2014. Phosphorene has been a typical material to study the semiconductor physics in atomic layers.

  14. Enhanced Magnetoelectric Coupling in Layered Structure of Piezoelectric Bimorph and Metallic Alloy

    NASA Astrophysics Data System (ADS)

    Petrov, V. M.; Bichurin, M. I.; Lavrentyeva, K. V.; Leontiev, V. S.

    2016-08-01

    We have investigated the enhanced magnetoelectric (ME) coupling in a layered structure of piezoelectric bimorph and magnetostrictive metallic alloy. The observed ME coefficient in the piezoelectric bimorph-based structure was found to be two times higher than in the traditional piezoelectric/magnetostrictive bilayer. The observed enhancement in ME coupling strength is related to equal signs of induced voltage in both lead zirconate titanate layers with opposite poling directions due to the flexural deformations. The piezoelectric bimorph-based structure has promising potential for sensor and technological applications.

  15. Wavevector filtering through single-layer and bilayer graphene with magnetic barrier structures

    NASA Astrophysics Data System (ADS)

    Masir, M. Ramezani; Vasilopoulos, P.; Peeters, F. M.

    2008-12-01

    We show that the angular range of the transmission through magnetic barrier structures can be efficiently controlled in single-layer and bilayer graphenes and this renders the structure's efficient wavevector filters. As the number of magnetic barriers increases, this range shrinks, the gaps in the transmission versus energy become wider, and the conductance oscillates with the Fermi energy.

  16. Preparation and crystal structure of U3Fe2C5: An original uranium-iron carbide

    NASA Astrophysics Data System (ADS)

    Henriques, M. S.; Paixão, J. A.; Henriques, M. S. C.; Gonçalves, A. P.

    2015-09-01

    The U3Fe2C5 compound was prepared from the elements by arc-melting, followed by an heat-treatment in an induction furnace, at 1250 °C for 1 h and 1300 °C for 2 h. The crystal structure of this phase was determined by direct methods from single crystal X-ray diffraction data. U3Fe2C5 crystallizes in an original tetragonal crystal structure, with space group I4/mmm, a = 3.4980(3) Å and c = 19.8380(15) Å as lattice constants and two formula units per cell. This new type structure is characterized by the simultaneous presence of isolated and pairs of carbon atoms, the interatomic distances in the pairs being similar to a typical carbon-carbon double bond length found in a molecule. U3Fe2C5 is closely related to UC and UFeC2, and can be seen as build from two (distorted) UFeC2 unit cells and a UC layer.

  17. Analysis of Structure Functions for the Turbulent Ekman Layer Direct Simulation

    NASA Astrophysics Data System (ADS)

    Waggy, Scott; Biringen, Sedat

    2010-11-01

    A direct numerical simulation of the low-Reynolds number turbulent Ekman layer was performed to assess the validity of Kolmogorov similarity laws in rotating turbulent flows. The three dimensional mean flow exhibited by the Ekman layer offers complex energy transfers not encountered in simple two-dimensional turbulent flows with one main mean shear direction. Time averaged 2nd order velocity structure functions were calculated to determine the extent of the inertial subrange at low Reynolds numbers. In addition, the constant C2, a universal constant of the structure functions, was compared with non-rotating boundary layers to analyze its applicability to different flows. The degree to which higher order structure functions abide by Kolmogorov's scaling was also analyzed for 3rd and 4th order structures.

  18. Microporous structure with layered interstitial surface treatment, and method and apparatus for preparation thereof

    NASA Technical Reports Server (NTRS)

    Koontz, Steven L. (Inventor)

    1992-01-01

    A microporous structure with layered interstitial surface treatments, and the method and apparatus for its preparation are disclosed. The structure is prepared by sequentially subjecting a uniformly surface treated structure to atomic oxygen treatment to remove an outer layer of surface treatment to a generally uniform depth, and then surface treating the so exposed layer with another surface treating agent. The atomic oxygen/surface treatment steps may optionally be repeated, each successive time to a lesser depth, to produce a microporous structure having multilayered surface treatments. The apparatus employs at least one side arm from a main oxygen-containing chamber. The side arm has characteristic relaxation times such that a uniform atomic oxygen dose rate is delivered to a specimen positioned transversely in the side arm spaced from the main gas chamber.

  19. Microporous structure with layered interstitial surface treatment, and method and apparatus for preparation thereof

    NASA Technical Reports Server (NTRS)

    Koontz, Steven L. (Inventor)

    1994-01-01

    A microporous structure with layered interstitial surface treatments, and method and apparatus for preparation thereof is presented. The structure is prepared by sequentially subjecting a uniformly surface-treated structure to atomic oxygen treatment to remove an outer layer of surface treatment to a generally uniform depth, and then surface treating the so exposed layer with another surface treating agent. The atomic oxygen/surface treatment steps may optionally be repeated, each successive time to a lesser depth, to produce a microporous structure having multilayered surface treatments. The apparatus employs at least one side arm from a main atomic oxygen-containing chamber. The side arm has characteristic relaxation times such that a uniform atomic oxygen dose rate is delivered to a specimen positioned transversely in the side arm spaced from the main gas chamber.

  20. Strengthening of polymer ordered porous materials based on a layered nanocomposite internal structure.

    PubMed

    Heng, Liping; Guo, Xieyou; Guo, Tianqi; Wang, Bin; Jiang, Lei

    2016-07-21

    Ordered porous polymeric films attract more and more attention because they have many advantages and broad application prospects in many fields. But because of their large flexibility and poor mechanical properties, some of the scope for application is greatly limited. Inspired by the ordered pore structure of the honeycomb and the layered structure of natural nacre, we prepared an ordered porous polymer film with a layered structure in the pore wall by the solvent-evaporation-restriction assisted hard template method. Compared with other samples, this kind of film with the layered structure showed both excellent mechanical properties and good stability. This kind of film with high mechanical strength, is considered to have wide applications in the areas of separation, biomedicine, precision instruments, aerospace, environmental protection and so on. PMID:27355160

  1. Local structures surrounding Zr in nanostructurally stabilized cubic zirconia: Structural origin of phase stability

    SciTech Connect

    Soo, Y. L.; Chen, P. J.; Huang, S. H.; Shiu, T. J.; Tsai, T. Y.; Chow, Y. H.; Lin, Y. C.; Weng, S. C.; Chang, S. L.; Wang, G.; Cheung, C. L.; Sabirianov, R. F.; Mei, W. N.; Namavar, F.; Haider, H.; Garvin, K. L.; Lee, J. F.; Lee, H. Y.; Chu, P. P.

    2008-12-01

    Local environment surrounding Zr atoms in the thin films of nanocrystalline zirconia (ZrO{sub 2}) has been investigated by using the extended x-ray absorption fine structure (EXAFS) technique. These films prepared by the ion beam assisted deposition exhibit long-range structural order of cubic phase and high hardness at room temperature without chemical stabilizers. The local structure around Zr probed by EXAFS indicates a cubic Zr sublattice with O atoms located on the nearest tetragonal sites with respect to the Zr central atoms, as well as highly disordered locations. Similar Zr local structure was also found in a ZrO{sub 2} nanocrystal sample prepared by a sol-gel method. Variations in local structures due to thermal annealing were observed and analyzed. Most importantly, our x-ray results provide direct experimental evidence for the existence of oxygen vacancies arising from local disorder and distortion of the oxygen sublattice in nanocrystalline ZrO{sub 2}. These oxygen vacancies are regarded as the essential stabilizing factor for the nanostructurally stabilized cubic zirconia.

  2. Enhanced Detectability of Community Structure in Multilayer Networks through Layer Aggregation

    NASA Astrophysics Data System (ADS)

    Taylor, Dane; Shai, Saray; Stanley, Natalie; Mucha, Peter J.

    2016-06-01

    Many systems are naturally represented by a multilayer network in which edges exist in multiple layers that encode different, but potentially related, types of interactions, and it is important to understand limitations on the detectability of community structure in these networks. Using random matrix theory, we analyze detectability limitations for multilayer (specifically, multiplex) stochastic block models (SBMs) in which L layers are derived from a common SBM. We study the effect of layer aggregation on detectability for several aggregation methods, including summation of the layers' adjacency matrices for which we show the detectability limit vanishes as O (L-1 /2) with increasing number of layers, L . Importantly, we find a similar scaling behavior when the summation is thresholded at an optimal value, providing insight into the common—but not well understood—practice of thresholding pairwise-interaction data to obtain sparse network representations.

  3. Enhanced Detectability of Community Structure in Multilayer Networks through Layer Aggregation.

    PubMed

    Taylor, Dane; Shai, Saray; Stanley, Natalie; Mucha, Peter J

    2016-06-01

    Many systems are naturally represented by a multilayer network in which edges exist in multiple layers that encode different, but potentially related, types of interactions, and it is important to understand limitations on the detectability of community structure in these networks. Using random matrix theory, we analyze detectability limitations for multilayer (specifically, multiplex) stochastic block models (SBMs) in which L layers are derived from a common SBM. We study the effect of layer aggregation on detectability for several aggregation methods, including summation of the layers' adjacency matrices for which we show the detectability limit vanishes as O(L^{-1/2}) with increasing number of layers, L. Importantly, we find a similar scaling behavior when the summation is thresholded at an optimal value, providing insight into the common-but not well understood-practice of thresholding pairwise-interaction data to obtain sparse network representations. PMID:27314740

  4. Tuning the magnetic anisotropy in single-layer crystal structures

    NASA Astrophysics Data System (ADS)

    Torun, E.; Sahin, H.; Bacaksiz, C.; Senger, R. T.; Peeters, F. M.

    2015-09-01

    The effect of an applied electric field and the effect of charging are investigated on the magnetic anisotropy (MA) of various stable two-dimensional (2D) crystals such as graphene, FeCl2, graphone, fluorographene, and MoTe2 using first-principles calculations. We found that the magnetocrystalline anisotropy energy of Co-on-graphene and Os-doped-MoTe2 systems change linearly with electric field, opening the possibility of electric field tuning MA of these compounds. In addition, charging can rotate the easy-axis direction of Co-on-graphene and Os-doped-MoTe2 systems from the out-of-plane (in-plane) to in-plane (out-of-plane) direction. The tunable MA of the studied materials is crucial for nanoscale electronic technologies such as data storage and spintronics devices. Our results show that controlling the MA of the mentioned 2D crystal structures can be realized in various ways, and this can lead to the emergence of a wide range of potential applications where the tuning and switching of magnetic functionalities are important.

  5. Structure prediction of an S-layer protein by the mean force method

    NASA Astrophysics Data System (ADS)

    Horejs, C.; Pum, D.; Sleytr, U. B.; Tscheliessnig, R.

    2008-02-01

    S-layer proteins have a wide range of application potential due to their characteristic features concerning self-assembling, assembling on various surfaces, and forming of isoporous structures with functional groups located on the surface in an identical position and orientation. Although considerable knowledge has been experimentally accumulated on the structure, biochemistry, assemble characteristics, and genetics of S-layer proteins, no structural model at atomic resolution has been available so far. Therefore, neither the overall folding of the S-layer proteins—their tertiary structure—nor the exact amino acid or domain allocations in the lattices are known. In this paper, we describe the tertiary structure prediction for the S-layer protein SbsB from Geobacillus stearothermophilus PV72/p2. This calculation was based on its amino acid sequence using the mean force method (MF method) achieved by performing molecular dynamic simulations. This method includes mainly the thermodynamic aspects of protein folding as well as steric constraints of the amino acids and is therefore independent of experimental structure analysis problems resulting from biochemical properties of the S-layer proteins. Molecular dynamic simulations were performed in vacuum using the simulation software NAMD. The obtained tertiary structure of SbsB was systematically analyzed by using the mean force method, whereas the verification of the structure is based on calculating the global free energy minimum of the whole system. This corresponds to the potential of mean force, which is the thermodynamically most favorable conformation of the protein. Finally, an S-layer lattice was modeled graphically using CINEMA4D and compared with scanning force microscopy data down to a resolution of 1nm. The results show that this approach leads to a thermodynamically favorable atomic model of the tertiary structure of the protein, which could be verified by both the MF Method and the lattice model.

  6. Strengthening of polymer ordered porous materials based on a layered nanocomposite internal structure

    NASA Astrophysics Data System (ADS)

    Heng, Liping; Guo, Xieyou; Guo, Tianqi; Wang, Bin; Jiang, Lei

    2016-07-01

    Ordered porous polymeric films attract more and more attention because they have many advantages and broad application prospects in many fields. But because of their large flexibility and poor mechanical properties, some of the scope for application is greatly limited. Inspired by the ordered pore structure of the honeycomb and the layered structure of natural nacre, we prepared an ordered porous polymer film with a layered structure in the pore wall by the solvent-evaporation-restriction assisted hard template method. Compared with other samples, this kind of film with the layered structure showed both excellent mechanical properties and good stability. This kind of film with high mechanical strength, is considered to have wide applications in the areas of separation, biomedicine, precision instruments, aerospace, environmental protection and so on.Ordered porous polymeric films attract more and more attention because they have many advantages and broad application prospects in many fields. But because of their large flexibility and poor mechanical properties, some of the scope for application is greatly limited. Inspired by the ordered pore structure of the honeycomb and the layered structure of natural nacre, we prepared an ordered porous polymer film with a layered structure in the pore wall by the solvent-evaporation-restriction assisted hard template method. Compared with other samples, this kind of film with the layered structure showed both excellent mechanical properties and good stability. This kind of film with high mechanical strength, is considered to have wide applications in the areas of separation, biomedicine, precision instruments, aerospace, environmental protection and so on. Electronic supplementary information (ESI) available: SEM image of hexagonal silicon pillar templates, AFM images of clay platelets on a silicon substrate, photographs of free-standing gels, X-ray diffraction profiles for dried materials, FTIR and TGA of the samples, and

  7. Computing the origin and evolution of the ribosome from its structure — Uncovering processes of macromolecular accretion benefiting synthetic biology

    PubMed Central

    Caetano-Anollés, Gustavo; Caetano-Anollés, Derek

    2015-01-01

    Accretion occurs pervasively in nature at widely different timeframes. The process also manifests in the evolution of macromolecules. Here we review recent computational and structural biology studies of evolutionary accretion that make use of the ideographic (historical, retrodictive) and nomothetic (universal, predictive) scientific frameworks. Computational studies uncover explicit timelines of accretion of structural parts in molecular repertoires and molecules. Phylogenetic trees of protein structural domains and proteomes and their molecular functions were built from a genomic census of millions of encoded proteins and associated terminal Gene Ontology terms. Trees reveal a ‘metabolic-first’ origin of proteins, the late development of translation, and a patchwork distribution of proteins in biological networks mediated by molecular recruitment. Similarly, the natural history of ancient RNA molecules inferred from trees of molecular substructures built from a census of molecular features shows patchwork-like accretion patterns. Ideographic analyses of ribosomal history uncover the early appearance of structures supporting mRNA decoding and tRNA translocation, the coevolution of ribosomal proteins and RNA, and a first evolutionary transition that brings ribosomal subunits together into a processive protein biosynthetic complex. Nomothetic structural biology studies of tertiary interactions and ancient insertions in rRNA complement these findings, once concentric layering assumptions are removed. Patterns of coaxial helical stacking reveal a frustrated dynamics of outward and inward ribosomal growth possibly mediated by structural grafting. The early rise of the ribosomal ‘turnstile’ suggests an evolutionary transition in natural biological computation. Results make explicit the need to understand processes of molecular growth and information transfer of macromolecules. PMID:27096056

  8. Synthesis, structure and electrochemical properties of novel Li-Co-Mn-O epitaxial thin-film electrode using layer-by-layer deposition process

    NASA Astrophysics Data System (ADS)

    Lim, Jaemin; Lee, Soyeon; Suzuki, Kota; Kim, KyungSu; Kim, Sangryun; Taminato, Sou; Hirayama, Masaaki; Oshima, Yoshifumi; Takayanagi, Kunio; Kanno, Ryoji

    2015-04-01

    A novel epitaxial thin-film electrode for lithium batteries, with a composition of Li0.92Co0.65Mn1.35O4 and a cubic spinel structure, is fabricated on a SrTiO3(111) single-crystal substrate. Fabrication is carried out by layer-by-layer pulsed laser deposition of LiCoO2 with a layered rock-salt structure and LiMn2O4 with a spinel structure. The electrode is found to exhibit unique disordering of the lithium (8a) and transition-metal (16d) sites, leading to a higher rate capability and cycle retention ratio than those for a thin-film electrode with the same composition prepared by a conventional single-step deposition process. The proposed layer-by-layer deposition method allows an expanded range of compositional and structural variations for lithium battery electrode materials.

  9. Use of heat treatment to modify the structure of a hard-faced layer

    NASA Astrophysics Data System (ADS)

    Borisov, M. D.; Kraev, G. V.; Poletika, I. M.

    1992-02-01

    The methods of metal physics and x-ray diffraction analysis are used to study the effect of heat treatments (quenching, tempering, high-temperature tempering) on the structure and properties (hardness, wear resistance) of a layer composed of an electroslag hard-facing alloyed with boron carbide and chromium. It is shown that the most effective heat treatment for increasing the hardness and wear resistance of the layer is one which includes high-temperature tempering, quenching, and low-temperature tempering.

  10. Structural origins of redox potentials in Fe-S proteins: electrostatic potentials of crystal structures.

    PubMed Central

    Swartz, P D; Beck, B W; Ichiye, T

    1996-01-01

    Redox potentials often differ dramatically for homologous proteins that have identical redox centers. For two types of iron-sulfur proteins, the rubredoxins and the high-potential iron-sulfur proteins (HiPIPs), no structural explanations for these differences have been found. We calculated the classical electrostatic potential at the redox site using static crystal structures of four rubredoxins and four HiPIPs to identify important structural determinants of their redox potentials. The contributions from just the backbone and polar side chains are shown to explain major features of the experimental redox potentials. For instance, in the rubredoxins, the presence of Val 44 versus Ala 44 causes a backbone shift that explains a approximately 50 mV lower redox potential in one of the four rubredoxins. This result is consistent with experimental redox potentials of five additional rubredoxins with known sequence. Also, we attribute the unusually lower redox potentials of two of the HiPIPs studied to a less positive electrostatic environment around their redox sites. Finally, molecular dynamics simulations of solvent around static rubredoxin crystal structures indicate that water alone is a major factor in dampening the contribution of charged side chains, in accord with experiments showing that mutations of surface charges produce relatively little effect on redox potentials. Images FIGURE 1 FIGURE 3 FIGURE 4 FIGURE 5 FIGURE 6 PMID:8968568

  11. Structure and field emission of graphene layers on top of silicon nanowire arrays

    NASA Astrophysics Data System (ADS)

    Huang, Bohr-Ran; Chan, Hui-Wen; Jou, Shyankay; Chen, Guan-Yu; Kuo, Hsiu-An; Song, Wan-Jhen

    2016-01-01

    Monolayer graphene was grown on copper foils and then transferred on planar silicon substrates and on top of silicon nanowire (SiNW) arrays to form single- to quadruple-layer graphene films. The morphology, structure, and electron field emission (FE) of these graphene films were investigated. The graphene films on the planar silicon substrates were continuous. The single- to triple-layer graphene films on the SiNW arrays were discontinuous and while the quadruple-layer graphene film featured a mostly continuous area. The Raman spectra of the graphene films on the SiNW arrays showed G and Gʹ bands with a singular-Lorentzian shape together with a weak D band. The D band intensity decreased as the number of graphene layers increased. The FE efficiency of the graphene films on the planar silicon substrates and the SiNW arrays varied with the number of graphene layers. The turn-on field for the single- to quadruple-layer graphene films on planar silicon substrates were 4.3, 3.7, 3.5 and 3.4 V/μm, respectively. The turn-on field for the single- to quadruple-layer graphene films on SiNW arrays decreased to 3.9, 3.3, 3.0 and 3.3 V/μm, respectively. Correlation of the FE with structure and morphology of the graphene films is discussed.

  12. Bi-layered calcium phosphate cement-based composite scaffold mimicking natural bone structure

    NASA Astrophysics Data System (ADS)

    He, Fupo; Ye, Jiandong

    2013-08-01

    In this study, a core/shell bi-layered calcium phosphate cement (CPC)-based composite scaffold with adjustable compressive strength, which mimicked the structure of natural cortical/cancellous bone, was fabricated. The dense tubular CPC shell was prepared by isostatic pressing CPC powder with a specially designed mould. A porous CPC core with unidirectional lamellar pore structure was fabricated inside the cavity of dense tubular CPC shell by unidirectional freeze casting, followed by infiltration of poly(lactic-co-glycolic acid) and immobilization of collagen. The compressive strength of bi-layered CPC-based composite scaffold can be controlled by varying thickness ratio of dense layer to porous layer. Compared to the scaffold without dense shell, the pore interconnection of bi-layered scaffold was not obviously compromised because of its high unidirectional interconnectivity but poor three dimensional interconnectivity. The in vitro results showed that the rat bone marrow stromal cells attached and proliferated well on the bi-layered CPC-based composite scaffold. This novel bi-layered CPC-based composite scaffold is promising for bone repair.

  13. Electronic band structure imaging of three layer twisted graphene on single crystal Cu(111)

    SciTech Connect

    Marquez Velasco, J.; Kelaidis, N.; Xenogiannopoulou, E.; Tsoutsou, D.; Tsipas, P.; Speliotis, Th.; Pilatos, G.; Likodimos, V.; Falaras, P.; Dimoulas, A.; Raptis, Y. S.

    2013-11-18

    Few layer graphene (FLG) is grown on single crystal Cu(111) by Chemical Vapor Deposition, and the electronic valence band structure is imaged by Angle-Resolved Photo-Emission Spectroscopy. It is found that graphene essentially grows polycrystalline. Three nearly ideal Dirac cones are observed along the Cu Γ{sup ¯}K{sup ¯} direction in k-space, attributed to the presence of ∼4° twisted three layer graphene with negligible interlayer coupling. The number of layers and the stacking order are compatible with Raman data analysis demonstrating the complementarity of the two techniques for a more accurate characterization of FLG.

  14. Al{sub 2}O{sub 3} multi-density layer structure as a moisture permeation barrier deposited by radio frequency remote plasma atomic layer deposition

    SciTech Connect

    Jung, Hyunsoo; Jeon, Heeyoung; Choi, Hagyoung; Ham, Giyul; Shin, Seokyoon; Jeon, Hyeongtag

    2014-02-21

    Al{sub 2}O{sub 3} films deposited by remote plasma atomic layer deposition have been used for thin film encapsulation of organic light emitting diode. In this study, a multi-density layer structure consisting of two Al{sub 2}O{sub 3} layers with different densities are deposited with different deposition conditions of O{sub 2} plasma reactant time. This structure improves moisture permeation barrier characteristics, as confirmed by a water vapor transmission rate (WVTR) test. The lowest WVTR of the multi-density layer structure was 4.7 × 10{sup −5} gm{sup −2} day{sup −1}, which is one order of magnitude less than WVTR for the reference single-density Al{sub 2}O{sub 3} layer. This improvement is attributed to the location mismatch of paths for atmospheric gases, such as O{sub 2} and H{sub 2}O, in the film due to different densities in the layers. This mechanism is analyzed by high resolution transmission electron microscopy, elastic recoil detection, and angle resolved X-ray photoelectron spectroscopy. These results confirmed that the multi-density layer structure exhibits very good characteristics as an encapsulation layer via location mismatch of paths for H{sub 2}O and O{sub 2} between the two layers.

  15. Fine Seismic Velocity Structure of the Lowermost Outer Core (F-layer) Beneath the Eastern Pacific

    NASA Astrophysics Data System (ADS)

    Ohtaki, T.; Kaneshima, S.

    2014-12-01

    Solidification or melting at the inner core boundary, the phenomena that have been suggested to occur reflecting the dynamical processes either of the inner core or of the outer core, might cause a Fe-rich or Fe-poor layer in the lowermost outer core (F-layer). Such a compositional anomaly might be detectable by investigating fine seismic structure of the F-layer. In our previous study we determined the overall Vp structure near the inner core boundary beneath Antarctica using differential traveltimes between PKIKP and PKPbc, waveform modeling of PKIKP and PKiKP, and amplitude ratios between PKIKP and PKPbc. But the fine structure of the F-layer remained poorly constrained.In this presentation, we examined the Vp structure of the F-layer beneath the eastern Pacific using differential traveltimes between PKiKP and PKPbc as well as frequency dependence of differential traveltimes between PKIKP and PKPbc, because these two analyses are particularly sensitive to the F-layer structure. We analyzed broadband seismograms of South American earthquakes observed at HI-NET in Japan. The differential traveltime residuals (observed minus calculated) between PKiKP and PKPbc are sensitive to the Vp excess relative to the reference model that is summed over the F-layer below the turning depth of PKPbc. For between 147 and 150 degrees the observed differential residuals show larger negative values and no noticeable dependence on distance compared to that for AK135. PREM that has larger Vp values in the F-layer than AK135 gives smaller differentials than the observations. On the other hand frequency dependence of differential traveltimes between PKIKP and PKPbc has unique sensitivity to the Vp slope in the F-layer, and low sensitivity to the Vp value on the ICB. We measured differential traveltimes for two different frequency bands for between 150 and 157 degrees, and then calculated the difference of the differentials between the two frequency bands. The observed differences show

  16. Effect of layered structures on the location of emissive regions in organic electroluminescent devices

    NASA Astrophysics Data System (ADS)

    Aminaka, Ei-ichiro; Tsutsui, Tetsuo; Saito, Shogo

    1996-06-01

    Effect of layered structures on the location of emissive regions was studied in four types of organic electroluminescent (EL) devices: a single-layered (SL) device consisting only of an emissive layer (EML), two types of double-layered (DL-H and DL-E) devices in which a hole-transport layer (HTL) or an electron-transport layer (ETL) is attached to an EML, and a triple-layered (TL) device in which an EML is sandwiched between a HTL and an ETL. As EML, HTL and ETL material, 9, 10-bis[4-(diphenylamino)styryl]anthracene, 4,4'-bis[(3-methylphenyl)phenylamino]biphenyl and 1,3-bis[(4-tert-butylphenyl)-1,3,4-oxadiazolyl]phenylene, respectively, were used. Within EML layers, a thin sensing layer doped with a squarilium dye, 2,4-bis[4-diethylamino)-2- hydroxyphenyl]cycrobutenediylium-1,3-dioxide was inserted. The change in emission intensity from the dopant, when the location of the sensing layer was systematically varied, gave information on emissive regions in each type of EL device. The emissive region in the SL device extended through the EML, and that in the DL-H device resided near the HTL/EML boundary. On the contrary, those in the DL-E and TL devices were located within a 10-nm-wide region adjacent to the EML/ETL boundary. Moreover, the emission efficiencies of the DL-E and TL devices were found to be higher than those of the SL and DL-H devices. It was experimentally demonstrated that the carrier recombination within the narrow region adjacent to the EML/carrier transport layer boundary gave high emission efficiency.

  17. First-principles study of the structure of water layers on flat and stepped Pb electrodes

    PubMed Central

    Lin, Xiaohang; Evers, Ferdinand

    2016-01-01

    Summary On the basis of perodic density functional theory (DFT) calculations, we have addressed the geometric structures and electronic properties of water layers on flat and stepped Pb surfaces. In contrast to late d-band metals, on Pb(111) the energy minimum structure does not correspond to an ice-like hexagonal arrangement at a coverage of 2/3, but rather to a distorted structure at a coverage of 1 due to the larger lattice constant of Pb. At stepped Pb surfaces, the water layers are pinned at the step edge and form a complex network consisting of rectangles, pentagons and hexagons. The thermal stability of the water layers has been studied by using ab initio molecular dynamics simulations (AIMD) at a temperature of 140 K. Whereas the water layer on Pb(111) is already unstable at this temperature, the water layers on Pb(100), Pb(311), Pb(511) and Pb(711) exhibit a higher stability because of stronger water–water interactions. The vibrational spectra of the water layers at the stepped surfaces show a characteristic splitting into three modes in the O–H stretch region. PMID:27335744

  18. Semiconductor structures having electrically insulating and conducting portions formed from an AlSb-alloy layer

    DOEpatents

    Spahn, Olga B.; Lear, Kevin L.

    1998-01-01

    A semiconductor structure. The semiconductor structure comprises a plurality of semiconductor layers formed on a substrate including at least one layer of a III-V compound semiconductor alloy comprising aluminum (Al) and antimony (Sb), with at least a part of the AlSb-alloy layer being chemically converted by an oxidation process to form superposed electrically insulating and electrically conducting portions. The electrically insulating portion formed from the AlSb-alloy layer comprises an oxide of aluminum (e.g. Al.sub.2 O.sub.3), while the electrically conducting portion comprises Sb. A lateral oxidation process allows formation of the superposed insulating and conducting portions below monocrystalline semiconductor layers for forming many different types of semiconductor structures having particular utility for optoelectronic devices such as light-emitting diodes, edge-emitting lasers, vertical-cavity surface-emitting lasers, photodetectors and optical modulators (waveguide and surface normal), and for electronic devices such as heterojunction bipolar transistors, field-effect transistors and quantum-effect devices. The invention is expected to be particularly useful for forming light-emitting devices for use in the 1.3-1.6 .mu.m wavelength range, with the AlSb-alloy layer acting to define an active region of the device and to effectively channel an electrical current therein for efficient light generation.

  19. Morphological Control of Cells on 3-Dimensional Multi-Layer Nanotopographic Structures.

    PubMed

    Jeong, Heon-Ho; Noh, Young-Mu; Song, Hwan-Moon; Lee, Sang-Ho; Park, Jin-Sung; Lee, Chang-Soo

    2015-05-01

    The extracellular matrix (ECM) environment is known to play an important role in the process of various cell regulatory mechanisms. We have investigated the ability of 3-dimensional ECM geometries to induce morphological changes in cells. Bi-layer polymeric structures with submicron scale stripe patterns were fabricated using a two-step nano-imprinting technique, and the orientation angle (θ(α)) of the upper layer was controlled by changing its alignment with respect to the orientation of the bottom layer. When cells were grown on the mono-layer stripe structure with a single orientation, they elongated along the direction of the stripe pattern. On bi-layer polymer structures, the cell morphologies gradually changed and became rounded, with an increase of θα up to 90 degrees, but the polarities of these cells were still aligned along the orientation of the upper layer. As a result, we show that the polarity and the roundness of cells can be independently regulated by adjusting the orientation of 3-dimensional hierarchical ECM topography. PMID:26505024

  20. Differential induction of structural changes in the simian virus 40 origin of replication by T antigen.

    PubMed Central

    Borowiec, J A; Dean, F B; Hurwitz, J

    1991-01-01

    The ATP-dependent binding of the simian virus 40 (SV40) large tumor antigen (T antigen) to the SV40 origin of replication (ori) results in the structural distortion of two critical elements within flanking regions of ori and the untwisting of the DNA helix. We examined the effect of changes in temperature, ATP concentration, and other reaction parameters on the generation of these DNA structural changes. We found that induction of the two localized structural transitions were highly and differentially sensitive to reaction conditions. Significant distortion of the early palindrome element, shown previously to result from DNA melting, required low levels of ATP (10 to 30 microM) but temperatures above 25 degrees C. Distortion of the AT tract occurred at low temperatures (5 degrees C) but required relatively high concentrations of ATP (greater than 300 microM). Thus, T antigen can induce structural changes within one critical element of ori without generating significant structural distortion within the second element. The response of ori untwisting to reaction conditions generally increased in parallel with or fell intermediate between the inductions of localized structural transitions. We suggest that ori untwisting and localized structural distortions are interdependent consequences of T-antigen binding to ori. These results suggest a model for the structural events occurring during the initial steps of SV40 DNA replication. Images PMID:1847451

  1. The adenovirus terminal protein influences binding of replication proteins and changes the origin structure.

    PubMed Central

    Pronk, R; van der Vliet, P C

    1993-01-01

    The adenovirus terminal protein (TP) is covalently linked to the 5' ends of the adenovirus genome and enhances DNA replication in vitro by increasing template activity. To study the effect of TP in more detail we isolated short origin fragments containing functional TP using anion exchange chromatography. These fragments were highly active as templates for DNA replication in a reconstituted system. Employing band-shift assays we found that the affinity of the precursor terminal protein-DNA polymerase complex for the TP-containing origin was increased 2 to 3-fold. Binding affinities of two other replication stimulating proteins, NFI and Oct-1, were not influenced by the terminal protein. Upon DNaseI footprinting we observed, unexpectedly, that the breakdown pattern had changed at various positions in the origin, notably in the area 3-6 and 41-51 by the presence of TP. Some differences in the footprint pattern of NFI and Oct-1 were also found. Our results indicate that TP induces subtle changes in the origin structure that influence the interaction of other replication proteins. Images PMID:8506126

  2. Enhancement of effective electromechanical coupling factor by mass loading in layered surface acoustic wave device structures

    NASA Astrophysics Data System (ADS)

    Tang, Gongbin; Han, Tao; Teshigahara, Akihiko; Iwaki, Takao; Hashimoto, Ken-ya

    2016-07-01

    This paper describes a drastic enhancement of the effective coupling factor K\\text{e}2 by mass loading in layered surface acoustic wave (SAW) device structures such as the ScAlN film/Si substrate structure. This phenomenon occurs when the piezoelectric layer exhibits a high acoustic wave velocity. The mass loading decreases the SAW velocity and causes SAW energy confinement close to the top surface where an interdigital transducer is placed. It is shown that this phenomenon is obvious even when an amorphous SiO2 film is deposited on the top surface for temperature compensation. This K\\text{e}2 enhancement was also found in various combinations of electrode, piezoelectric layer, and/or substrate materials. The existence of this phenomenon was verified experimentally using the ScAlN film/Si substrate structure.

  3. Fabrication and atomic structure of size-selected, layered MoS2 clusters for catalysis.

    PubMed

    Cuddy, Martin J; Arkill, Kenton P; Wang, Zhi Wei; Komsa, Hannu-Pekka; Krasheninnikov, Arkady V; Palmer, Richard E

    2014-11-01

    Well defined MoS2 nanoparticles having a layered structure and abundant edges would be of considerable interest for applications including photocatalysis. We report the atomic structure of MoS2 size-selected clusters with mass in a range all the way from 50 to ∼2000 MoS2 units. The clusters were prepared by magnetron sputtering and gas condensation prior to size selection and soft landing on carbon supports. Aberration-corrected scanning transmission electron microscopy (STEM) in high-angle annular dark-field (HAADF) mode reveals a layered structure and Mo-Mo spacing similar to the bulk material. The mean number of layers in these lamellar clusters increases from one to three with increasing mass, consistent with density functional theory calculations of the balance between edge energies and interlayer binding. PMID:25226541

  4. Control of the crystalline structure of inkjet-printed semiconductor layers using overlap condition and surface wettability

    NASA Astrophysics Data System (ADS)

    Kang, Byung Ju; Oh, Je Hoon

    2015-05-01

    We demonstrate the effects of overlap condition and surface wettability of dielectric layers on the drying process and crystalline structure of inkjet-printed semiconductor layers. 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS pentacene) was utilized to inkjet-print the semiconductor layer. Using various overlap conditions, semiconductor layers were inkjet-printed on dielectric layers with different surface wettabilities. It is observed that crystal growth and the resulting crystalline structures in inkjet-printed semiconductor layers are primarily determined by evaporation behavior, particularly the contact line movement of the drying semiconductor layers, which can be controlled via the overlap condition. With inappropriate overlap conditions, randomly oriented TIPS pentacene crystalline structures are generated in the semiconductor layer through irregular contact line recession. One-dimensionally oriented TIPS pentacene crystal structures can be obtained using the optimized overlap condition of 50% as a result of the uniform contact line movement. Relatively hydrophobic dielectric layers help to generate good crystallinity in the semiconductor layer. All-inkjet-printed organic thin film transistors (OTFTs) with well-oriented TIPS pentacene crystalline structures in the semiconductor layer show a high field effect mobility of ~0.1 cm2 V-1s-1, suggesting that, when printing inkjet semiconductor layers, the overlap condition and surface wettability of the dielectric layer are important factors for generating a well-oriented crystalline structure and thereby fabricating high-performance all-inkjet-printed OTFTs.

  5. Carbonaceous structures in the Tissint Martian Meteorite: evidence of a biogenetic origin

    NASA Astrophysics Data System (ADS)

    Wallis, Jamie; Wickramasinghe, N. C.; Wallis, Daryl H.; Miyake, Nori; Wallis, M. K.; Hoover, Richard B.

    2015-09-01

    We report for the first time in situ observations of 5-50μm spherical carbonaceous structures in the Tissint Martian meteorite comprising of pyrite (FeS2) cores and carbonaceous outer coatings. The structures are characterized as smooth immiscible spheres with curved boundaries occasionally following the contours of the pyrite inclusion. The structures bear striking resemblance to similar-sized immiscible carbonaceous spheres found in hydrothermal calcite vein deposits in the Mullaghwornia Quarry in central Ireland. Similar structures have been reported in Proterozoic and Ordovician sandstones from Canada as well as in a variety of astronomical sources including carbonaceous chondrites, chondritic IDPs and primitive chondritic meteorites. SEM and X-Ray elemental mapping confirmed the presence of organic carbon filling the crack and cleavage space in the pyroxene substrate, with further evidence of pyrite acting as an attractive substrate for the collection of organic matter. The detection of precipitated carbon collecting around pyrite grains is at variance with an igneous origin as proposed for the reduced organic component in Tissint, and is more consistent with a biogenetic origin.

  6. Structural design of a double-layered porous hydrogel for effective mass transport

    PubMed Central

    Kim, Hyejeong; Kim, Hyeon Jeong; Huh, Hyung Kyu; Hwang, Hyung Ju; Lee, Sang Joon

    2015-01-01

    Mass transport in porous materials is universal in nature, and its worth attracts great attention in many engineering applications. Plant leaves, which work as natural hydraulic pumps for water uptake, have evolved to have the morphological structure for fast water transport to compensate large water loss by leaf transpiration. In this study, we tried to deduce the advantageous structural features of plant leaves for practical applications. Inspired by the tissue organization of the hydraulic pathways in plant leaves, analogous double-layered porous models were fabricated using agarose hydrogel. Solute transport through the hydrogel models with different thickness ratios of the two layers was experimentally observed. In addition, numerical simulation and theoretical analysis were carried out with varying porosity and thickness ratio to investigate the effect of structural factors on mass transport ability. A simple parametric study was also conducted to examine unveiled relations between structural factors. As a result, the porosity and thickness ratio of the two layers are found to govern the mass transport ability in double-layered porous materials. The hydrogel models with widely dispersed pores at a fixed porosity, i.e., close to a homogeneously porous structure, are mostly turned out to exhibit fast mass transport. The present results would provide a new framework for fundamental design of various porous structures for effective mass transport. PMID:25825619

  7. Understanding the Internal Structure of Layered Organic Compounds deposited on mineral surface using Neutron Reflectivity

    NASA Astrophysics Data System (ADS)

    Ambaye, Haile; Jagadamma, Sindhu; Petridis, Loukas; Mayes, Melanie; Lauter, Valeria

    2013-03-01

    Organic carbon (OC) stabilization in soils plays a significant role in the global C cycle, therefore the understanding of the structure and function of the OC-soil mineral interface is of high importance. To study the internal structure, films with different combination of simple OC compounds, natural organic matter (NOM), Bi-layers of SA (Stearic Acid) on Glucose and NOM/Hydrophilic-NOM/Hydrophobic-NOM were deposited onto sapphire using spin coating. The phobic and phylic fractions of the NOM are operationally separated by exchange resins. We obtained detailed structural depth profile of the films using the depth-sensitive technique of the neutron reflectometry. The neutron reflectivity data were collected at the MAGICS Reflectometer at Spallation Neutron Source at the ORNL. Self-assembled ordering of SA in a repeating bi-layer structure was observed when it was deposited on NOM, phylic-NOM and Glucose. However, when SA was added to phobic-NOM no ordering of SA was detected. The formation of distinct, immiscible layers is due to insolubility of SA with NOM/Hydrophilic-NOM and Glucose. Our results reveal that the OC-mineral interface form complex layering and that the sequence of the layering depends on the compounds. The work was supported by ORNL (LDRD), BES and DOE.

  8. Very-Large-Scale Coherent Structures in the Wall Pressure Field Beneath a Supersonic Turbulent Boundary Layer

    NASA Astrophysics Data System (ADS)

    Beresh, Steven; Henfling, John; Spillers, Russell; Pruett, Brian

    2010-11-01

    Previous wind tunnel experiments up to Mach 3 have provided fluctuating wall-pressure spectra beneath a supersonic turbulent boundary layer, which essentially are flat at low frequency and do not exhibit the theorized φ^2 dependence. The flat portion of the spectrum extends over two orders of magnitude and represents structures reaching at least 100 δ in scale, raising questions about their physical origin. The spatial coherence required over these long lengths may arise from very-large-scale structures that have been detected in turbulent boundary layers due to groupings of hairpin vortices. To address this hypothesis, data have been acquired from a dense spanwise array of fluctuating wall pressure sensors, then invoking Taylor's Hypothesis and low-pass filtering the data allows the temporal signals to be converted into a spatial map of the wall pressure field. This reveals streaks of instantaneously correlated pressure fluctuations elongated in the streamwise direction and exhibiting spanwise alternation of positive and negative events that meander somewhat in tandem. As the low-pass filter cutoff is lowered, the fluctuating pressure magnitude of the coherent structures diminishes while their length increases.

  9. Very-large-scale coherent structures in the wall pressure field beneath a supersonic turbulent boundary layer.

    SciTech Connect

    Beresh, Steven Jay; Spillers, Russell Wayne; Henfling, John Francis; Pruett, Brian Owen Matthew

    2010-11-01

    Previous wind tunnel experiments up to Mach 3 have provided fluctuating wall-pressure spectra beneath a supersonic turbulent boundary layer, which essentially are flat at low frequency and do not exhibit the theorized {psi}{sup 2} dependence. The flat portion of the spectrum extends over two orders of magnitude and represents structures reaching at least 100 {delta} in scale, raising questions about their physical origin. The spatial coherence required over these long lengths may arise from very-large-scale structures that have been detected in turbulent boundary layers due to groupings of hairpin vortices. To address this hypothesis, data have been acquired from a dense spanwise array of fluctuating wall pressure sensors, then invoking Taylor's Hypothesis and low-pass filtering the data allows the temporal signals to be converted into a spatial map of the wall pressure field. This reveals streaks of instantaneously correlated pressure fluctuations elongated in the streamwise direction and exhibiting spanwise alternation of positive and negative events that meander somewhat in tandem. As the low-pass filter cutoff is lowered, the fluctuating pressure magnitude of the coherent structures diminishes while their length increases.

  10. Spectroscopic and computational investigations on the origin of charge transfer between included neutral guest molecules and a functionalized anionic layered host.

    PubMed

    Dutta, Dipak; Tummanapelli, Anil Kumar

    2016-08-10

    Layered double hydroxides (LDHs) or anionic clays are an important class of ion-exchange materials, well known for drug and gene delivery and several other applications including catalysis, bioactive nanocomposite, electroactive and photoactive materials. Their structure is based on positively charged brucite-like inorganic sheets with the interlamellar space being occupied by charge-compensating exchangeable anions. In spite of having a vast scope many of the applications of LDHs are restricted as their host-guest chemistry is limited to ion-exchange reactions. Recently we have shown for the first time that charge-transfer interactions can be used as a driving force for the insertion of neutral guest molecules (ortho- and para-chloranil) within the galleries of an Mg-Al LDH by forming a charge-transfer complex with aniline pre-intercalated as p-aminobenzoate anion. Here, we have performed quantum chemical calculations in combination with molecular dynamics simulations to elucidate the nature of interactions, arrangement and the evaluation of electronic and Raman spectral signatures of the chloranil charge-transfer complex included within the galleries of the Mg-Al LDH. The natural bond orbital (NBO) analysis has been used to understand the nature and origin of the unidirectional charge-transfer that lead to the unusual insertion of chloranil in the galleries of the Mg-Al LDH. The NBO analysis reveals that a considerable amount of electronic charge redistribution occurs from the p-aminobenzoate to the chloranil during latter's insertion within the LDH galleries with a very negligible amount of back donation. This work is expected to pave the way for understanding the host-guest chemistry and targeted and controlled delivery of poorly soluble drugs. PMID:27461409

  11. Coherent structures in a zero-pressure-gradient and a strongly decelerated boundary layer

    NASA Astrophysics Data System (ADS)

    Simens, Mark P.; Gungor, Ayse G.; Maciel, Yvan

    2016-04-01

    Coherent structures in a strongly decelerated large-velocity-defect turbulent boundary layer (TBL) and a zero pressure gradient (ZPG) boundary layer are analysed by direct numerical simulation (DNS). The characteristics of the one-point velocity stastistics are also considered. The adverse pressure gradient (APG) TBL simulation is a new one carried out by the present authors. The APG TBL begins as a zero pressure gradient boundary layer, decelerates under a strong adverse pressure gradient, and separates near the end of the domain in the form of a very thin separation bubble. The one-point velocity statistics in the outer region of this large-defect boundary layer are compared to those of two other large-velocity-defect APG TBLs (one in dynamic equilibrium, the other in disequilibrium) and a mixing layer. In the upper half of the large-defect boundary layers, the velocity statistics are similar to those of the mixing layer. The dominant peaks of turbulence production and Reynolds stresses are located in the middle of the boundary layers. Three-dimensional spatial correlations of (u, u) and (u, v) show that coherence is lost in the streamwise and spanwise directions as the velocity defect increases. Near-wall streaks tend to disappear in the large-defect zone of the flow to be replaced by more disorganized u motions. Near-wall sweeps and ejections are also less numerous. In the outer region, the u structures tend to be shorter, less streaky, and more inclined with respect to the wall than in the ZPG TBL. The sweeps and ejections are generally bigger with respect to the boundary layer thickness in the large-defect boundary layer, even if the biggest structures are found in the ZPG TBL. Large sweeps and ejections that reach the wall region (wall-attached) are less streamwise elongated and they occupy less space than in the ZPG boundary layer. The distinction between wall-attached and wall-detached structures is not as pronounced in the large-defect TBL.

  12. A Comparison of Aerosol-Layer and Convective Boundary-Layer Structure over a Mountain Range during STAAARTE '97

    SciTech Connect

    De Wekker, Stephan; Steyn, D. G.; Nyeki, Stephan

    2004-11-01

    The temporal evolution and spatial structure of the aerosol layer (AL) height as observed with an airborne downlooking lidar over the Swiss Alps was investigated with a three dimensional mesoscale numerical model and a particle dispersion model. Convective boundary layer (CBL) heights were derived from the mesoscale model output, and the behavior of surface-released particles was investigated with the particle dispersion model. While a previous investigation, using data from the same field study, equated the observed AL height with the CBL height, the results of the current investigation indicate that there is a considerable difference between AL and CBL heights caused by mixing and transport processes between the CBL and the free atmosphere. CBL heights show a more terrain-following behavior and are lower than AL heights. We argue that processes causing the difference between AL and CBL heights are common over mountainous terrain and that the AL height is a length scale that needs t o be considered in air pollution studies in mountainous terrain.

  13. Engineering meniscus structure and function via multi-layered mesenchymal stem cell-seeded nanofibrous scaffolds.

    PubMed

    Fisher, Matthew B; Henning, Elizabeth A; Söegaard, Nicole; Bostrom, Marc; Esterhai, John L; Mauck, Robert L

    2015-06-01

    Despite advances in tissue engineering for the knee meniscus, it remains a challenge to match the complex macroscopic and microscopic structural features of native tissue, including the circumferentially and radially aligned collagen bundles essential for mechanical function. To mimic this structural hierarchy, this study developed multi-lamellar mesenchymal stem cell (MSC)-seeded nanofibrous constructs. Bovine MSCs were seeded onto nanofibrous scaffolds comprised of poly(ε-caprolactone) with fibers aligned in a single direction (0° or 90° to the scaffold long axis) or circumferentially aligned (C). Multi-layer groups (0°/0°/0°, 90°/90°/90°, 0°/90°/0°, 90°/0°/90°, and C/C/C) were created and cultured for a total of 6 weeks under conditions favoring fibrocartilaginous tissue formation. Tensile testing showed that 0° and C single layer constructs had stiffness values several fold higher than 90° constructs. For multi-layer groups, the stiffness of 0°/0°/0° constructs was higher than all other groups, while 90°/90°/90° constructs had the lowest values. Data for collagen content showed a general positive interactive effect for multi-layers relative to single layer constructs, while a positive interaction for stiffness was found only for the C/C/C group. Collagen content and cell infiltration occurred independent of scaffold alignment, and newly formed collagenous matrix followed the scaffold fiber direction. Structural hierarchies within multi-lamellar constructs dictated biomechanical properties, and only the C/C/C constructs with non-orthogonal alignment within layers featured positive mechanical reinforcement as a consequence of the layered construction. These multi-layer constructs may serve as functional substitutes for the meniscus as well as test beds to understand the complex mechanical principles that enable meniscus function. PMID:25817333

  14. Formation of the seed layers for layer-transfer process silicon solar cells by zone-heating recrystallization of porous silicon structures

    NASA Astrophysics Data System (ADS)

    Lukianov, A.; Murakami, K.; Takazawa, C.; Ihara, M.

    2016-05-01

    Thin-film crystalline silicon is promising for photovoltaic application to reduce the cost of photovoltaic energy. Porous silicon structures have been intensively studied as a seed layer for epitaxial growth of thin Si film and layer-transfer process (LTP). In this article, another approach for LTP has been proposed. The seed layers for epitaxial silicon growth have been formed by zone-heating recrystallization of double-layer por-Si structures. The influence of annealing parameters on porous silicon structures was studied. The transformation of por-Si layer to crystalline Si was observed with the formation of smooth continuous surface with the roughness 0.3 nm, peak-to-valley distance around 3.5 nm, and reduced density of pores. The mechanism of the transformation of por-Si surface due to the action of hydrogen in the passivated pores with preventing surface oxidation was proposed.

  15. Chemical and structural composition of organic carbonaceous structures in Tissint: evidence for a biogenetic origin

    NASA Astrophysics Data System (ADS)

    Wallis, Jamie; Wickramasinghe, N. C.; Wallis, Daryl H.; Miyake, Nori; Wallis, M. K.; Hoover, Richard B.

    2015-09-01

    Earlier studies of the Tissint Martian meteorite identified the presence of a number of 5-50μm carbonaceous spherical structures. SEM and EDS elemental spectra for 11 selected structures confirmed that they comprise of a carbonaceous outer coating with a inner core of FeS2 (pyrite) and are characterised as immiscible globules with curved boundaries. Here we report on the results of Raman spectroscopic studies that unambiguously confirm the mantle as comprising of `disordered carbonaceous material'. R1 = ID/IG against ΓD (cm-1) band parameter plots of the carbonaceous coatings imply a complex precursor carbon inventory comparable to the precursor carbon component of materials of known biotic source (plants, algae, fungi, crustaceans, prokaryotes). Correlation between peak metamorphic temperatures and Raman D-band (ΓD) parameters further indicate the carbonaceous component was subjected to a peak temperature of ~250 OC suggesting a possible link with the hydrothermal precipitation processes responsible for the formation of similar globules observed in hydrothermal calcite veins in central Ireland. Ω G (cm-1), ΓG (cm-1), Ω D (cm-1) and ΓD (cm-1) parameters further imply a level of crystallinity and disorder of the carbon component consistent with carbonaceous material recovered from a variety of non-terrestrial sources. Cl, N, O and S to C elemental ratios are typical of high volatility bituminous coals and distinctly higher than equivalent graphite standards.

  16. A two-layer structure prediction framework for microscopy cell detection.

    PubMed

    Xu, Yan; Wu, Weiying; Chang, Eric I-Chao; Chen, Danny; Mu, Jian; Lee, Peter P; Blenman, Kim R M; Tu, Zhuowen

    2015-04-01

    The task of microscopy cell detection is of great biological and clinical importance. However, existing algorithms for microscopy cell detection usually ignore the large variations of cells and only focus on the shape feature/descriptor design. Here we propose a new two-layer model for cell centre detection by a two-layer structure prediction framework, which is respectively built on classification for the cell centres implicitly using rich appearances and contextual information and explicit structural information for the cells. Experimental results demonstrate the efficiency and effectiveness of the proposed method over competing state-of-the-art methods, providing a viable alternative for microscopy cell detection. PMID:25082065

  17. Mointoring Thickness Deviations in Planar Multi-Layered Elastic Structures Using Impedance Signatures

    SciTech Connect

    Fisher, K A

    2007-01-26

    In this letter, a low frequency ultrasonic resonance technique that operates in the (20 - 80 kHz) regime is presented that demonstrates detection of thickness changes on the order of +/- 10{micro}m. This measurement capability is a result of the direct correlation between the electrical impedance of an electro-acoustic transducer and the mechanical loading it experiences when placed in contact with a layered elastic structure. The relative frequency shifts of the resonances peaks can be estimated through a simple one-dimensional transmission model. Separate experimental measurements confirm this technique to be sensitive to subtle changes in the underlying layered elastic structure.

  18. Cell-of-Origin-Specific 3D Genome Structure Acquired during Somatic Cell Reprogramming

    PubMed Central

    Krijger, Peter Hugo Lodewijk; Di Stefano, Bruno; de Wit, Elzo; Limone, Francesco; van Oevelen, Chris; de Laat, Wouter; Graf, Thomas

    2016-01-01

    Summary Forced expression of reprogramming factors can convert somatic cells into induced pluripotent stem cells (iPSCs). Here we studied genome topology dynamics during reprogramming of different somatic cell types with highly distinct genome conformations. We find large-scale topologically associated domain (TAD) repositioning and alterations of tissue-restricted genomic neighborhoods and chromatin loops, effectively erasing the somatic-cell-specific genome structures while establishing an embryonic stem-cell-like 3D genome. Yet, early passage iPSCs carry topological hallmarks that enable recognition of their cell of origin. These hallmarks are not remnants of somatic chromosome topologies. Instead, the distinguishing topological features are acquired during reprogramming, as we also find for cell-of-origin-dependent gene expression patterns. PMID:26971819

  19. Function and Evolutionary Origin of Unicellular Camera-Type Eye Structure

    PubMed Central

    Hayakawa, Shiho; Takaku, Yasuharu; Hwang, Jung Shan; Horiguchi, Takeo; Suga, Hiroshi; Ikeo, Kazuho; Gojobori, Takashi

    2015-01-01

    The ocelloid is an extraordinary eyespot organelle found only in the dinoflagellate family Warnowiaceae. It contains retina- and lens-like structures called the retinal body and the hyalosome. The ocelloid has been an evolutionary enigma because of its remarkable resemblance to the multicellular camera-type eye. To determine if the ocelloid is functionally photoreceptive, we investigated the warnowiid dinoflagellate Erythropsidinium. Here, we show that the morphology of the retinal body changed depending on different illumination conditions and the hyalosome manifests the refractile nature. Identifying a rhodopsin gene fragment in Erythropsidinium ESTs that is expressed in the retinal body by in situ hybridization, we also show that ocelloids are actually light sensitive photoreceptors. The rhodopsin gene identified is most closely related to bacterial rhodopsins. Taken together, we suggest that the ocelloid is an intracellular camera-type eye, which might be originated from endosymbiotic origin. PMID:25734540

  20. The structure and chemical layering of Proterozoic stromatolites in the Mojave Desert

    NASA Astrophysics Data System (ADS)

    Douglas, Susanne; Perry, Meredith E.; Abbey, William J.; Tanaka, Zuki; Chen, Bin; McKay, Christopher P.

    2015-07-01

    The Proterozoic carbonate stromatolites of the Pahrump Group from the Crystal Spring formation exhibit interesting layering patterns. In continuous vertical formations, there are sections of chevron-shaped stromatolites alternating with sections of simple horizontal layering. This apparent cycle of stromatolite formation and lack of formation repeats several times over a vertical distance of at least 30 m at the locality investigated. Small representative samples from each layer were taken and analysed using X-ray diffraction (XRD), X-ray fluorescence (XRF), environmental scanning electron microscopy - energy dispersive X-ray spectrometry, and were optically analysed in thin section. Optical and spectroscopic analyses of stromatolite and of non-stromatolite samples were undertaken with the objective of determining the differences between them. Elemental analysis of samples from within each of the four stromatolite layers and the four intervening layers shows that the two types of layers are chemically and mineralogically distinct. In the layers that contain stromatolites the Ca/Si ratio is high; in layers without stromatolites the Ca/Si ratio is low. In the high Si layers, both K and Al are positively correlated with the presence and levels of Si. This, together with XRD analysis, suggested a high K-feldspar (microcline) content in the non-stromatolitic layers. This variation between these two types of rocks could be due to changes in biological growth rates in an otherwise uniform environment or variations in detrital influx and the resultant impact on biology. The current analysis does not allow us to choose between these two alternatives. A Mars rover would have adequate resolution to image these structures and instrumentation capable of conducting a similar elemental analysis.