DEMONSTRATION BULLETIN: THE PYRETRON OXYGEN BURNER, AMERICAN COMBUSTION TECHNOLOGIES, INC.

EPA Science Inventory

The Pyretron is a burner which is designed to allow for the injection of oxygen into the combustion air stream for the purpose of increasing the efficiency of a hazardous waste incinerator. The SITE demonstration of the Pyretron took place at the U.S. EPA's Combustion Re...

Quantitative Measurement of Oxygen in Microgravity Combustion

NASA Technical Reports Server (NTRS)

Silver, Joel A.

1997-01-01

A low-gravity environment, in space or in ground-based facilities such as drop towers, provides a unique setting for studying combustion mechanisms. Understanding the physical phenomena controlling the ignition and spread of flames in microgravity has importance for space safety as well as for better characterization of dynamical and chemical combustion processes which are normally masked by buoyancy and other gravity-related effects. Due to restrictions associated with performing measurements in reduced gravity, diagnostic methods which have been applied to microgravity combustion studies have generally been limited to capture of flame emissions on film or video, laser Schlieren imaging and (intrusive) temperature measurements using thermocouples. Given the development of detailed theoretical models, more sophisticated diagnostic methods are needed to provide the kind of quantitative data necessary to characterize the properties of microgravity combustion processes as well as provide accurate feedback to improve the predictive capabilities of the models. When the demands of space flight are considered, the need for improved diagnostic systems which are rugged, compact, reliable, and operate at low power becomes apparent. The objective of this research is twofold. First, we want to develop a better understanding of the relative roles of diffusion and reaction of oxygen in microgravity combustion. As the primary oxidizer species, oxygen plays a major role in controlling the observed properties of flames, including flame front speed (in solid or liquid flames), extinguishment characteristics, flame size and flame temperature. The second objective is to develop better diagnostics based on diode laser absorption which can be of real value in both microgravity combustion research and as a sensor on-board Spacelab as either an air quality monitor or as part of a fire detection system. In our prior microgravity work, an eight line-of-sight fiber optic system measured

Experimental and theoretical study of iron and mild steel combustion in oxygen flows

NASA Astrophysics Data System (ADS)

El-Rabii, Hazem; Kazakov, Kirill A.; Muller, Maryse

2017-03-01

The effects of oxygen flow speed and pressure on the iron and mild steel combustion are investigated experimentally and theoretically. The studied specimens are vertical cylindrical rods subjected to an axial oxygen flow and ignited at the upper end by laser irradiation. Three main stages of the combustion process have been identified experimentally: (1) induction period, during which the rod is heated until an intensive metal oxidation begins at its upper end; (2) static combustion, during which a laminar liquid "cap'' slowly grows on the upper rod end, and, after the liquid cap detachment from the sample; (3) dynamic combustion, which is characterized by a rapid metal consumption and turbulent liquid motions. An analytical description of these stages is given. In particular, a model of the dynamic combustion is constructed based on the turbulent oxygen transport through the liquid metal-oxide flow. This model yields a simple expression for the fraction of metal burned in the process and allows one to calculate the normal propagation speed of the solid metal-liquid interface as a function of the oxygen flow speed and pressure. A comparison of the theory with the experimental results is made, and its potential application is mentioned.

Carbon dioxide remediation via oxygen-enriched combustion using dense ceramic membranes

DOEpatents

Balachandran, Uthamalingam; Bose, Arun C.; McIlvried, Howard G.

2001-01-01

A method of combusting pulverized coal by mixing the pulverized coal and an oxidant gas to provide a pulverized coal-oxidant gas mixture and contacting the pulverized coal-oxidant gas mixture with a flame sufficiently hot to combust the mixture. An oxygen-containing gas is passed in contact with a dense ceramic membrane of metal oxide material having electron conductivity and oxygen ion conductivity that is gas-impervious until the oxygen concentration on one side of the membrane is not less than about 30% by volume. An oxidant gas with an oxygen concentration of not less than about 30% by volume and a CO.sub.2 concentration of not less than about 30% by volume and pulverized coal is contacted with a flame sufficiently hot to combust the mixture to produce heat and a flue gas. One dense ceramic membrane disclosed is selected from the group consisting of materials having formulae SrCo.sub.0.8 Fe.sub.0.2 O.sub.x, SrCo.sub.0.5 FeO.sub.x and La.sub.0.2 Sr.sub.0.8 Co.sub.0.4 Fe.sub.0.6 O.sub.x.

Investigation of reactions in a fluidized bed reactor during chemical looping combustion of coal/steam with copper oxide-iron oxide-alumina oxygen carrier

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siriwardane, Ranjani; Benincosa, William; Riley, Jarrett

This paper presents data on conversion of two different coals with a chemical looping oxygen carrier, CuO-Fe 2O 3-alumina, and over a range of conditions including steam and various levels of reduction of the oxygen carrier. Reactions of coal/steam/CuO-Fe 2O 3-alumina oxygen carrier and coal/steam/partially reduced CuO-Fe 2O 3-alumina oxygen carrier were investigated with Wyodak coal and Illinois #6 coal in a fluidized bed reactor. Temperature programmed reaction studies indicated that the oxygen carrier enhanced the steam gasification/combustion rates of both coals. Rates of gasification/combustion were higher with Wyodak coal (sub bituminous) than that with Illinois #6 coal (bituminous). Inmore » addition to the increase in reaction rates, the total moles of carbon that were gasified and combusted from coal/steam increased in the presence of the oxygen carrier. The reduced oxygen carrier promoted the water-gas shift reaction when reacted with synthesis gas in the presence of steam, but the reverse water gas shift reaction was observed when steam was not present. The partially reduced oxygen carrier enhanced the production of H 2 from coal/steam, which was different from the observations with un-reduced oxygen carrier. Water splitting reaction to produce H 2 was also observed with the reduced oxygen carrier. CuO-Fe 2O 3-alumina reacted with coal during the temperature ramp to 850 °C even in the absence of steam due to the chemical-looping oxygen uncoupling (CLOU) reaction. Here, the fourier transform infra-red (FTIR) analysis indicated the presence of volatile aromatics during the temperature ramp and these may have also contributed to the reactions with the oxygen carrier in the absence of steam. Increasing steam concentration had a negative effect on the CLOU reaction.« less

Investigation of reactions in a fluidized bed reactor during chemical looping combustion of coal/steam with copper oxide-iron oxide-alumina oxygen carrier

DOE PAGES

Siriwardane, Ranjani; Benincosa, William; Riley, Jarrett; ...

2016-10-06

This paper presents data on conversion of two different coals with a chemical looping oxygen carrier, CuO-Fe 2O 3-alumina, and over a range of conditions including steam and various levels of reduction of the oxygen carrier. Reactions of coal/steam/CuO-Fe 2O 3-alumina oxygen carrier and coal/steam/partially reduced CuO-Fe 2O 3-alumina oxygen carrier were investigated with Wyodak coal and Illinois #6 coal in a fluidized bed reactor. Temperature programmed reaction studies indicated that the oxygen carrier enhanced the steam gasification/combustion rates of both coals. Rates of gasification/combustion were higher with Wyodak coal (sub bituminous) than that with Illinois #6 coal (bituminous). Inmore » addition to the increase in reaction rates, the total moles of carbon that were gasified and combusted from coal/steam increased in the presence of the oxygen carrier. The reduced oxygen carrier promoted the water-gas shift reaction when reacted with synthesis gas in the presence of steam, but the reverse water gas shift reaction was observed when steam was not present. The partially reduced oxygen carrier enhanced the production of H 2 from coal/steam, which was different from the observations with un-reduced oxygen carrier. Water splitting reaction to produce H 2 was also observed with the reduced oxygen carrier. CuO-Fe 2O 3-alumina reacted with coal during the temperature ramp to 850 °C even in the absence of steam due to the chemical-looping oxygen uncoupling (CLOU) reaction. Here, the fourier transform infra-red (FTIR) analysis indicated the presence of volatile aromatics during the temperature ramp and these may have also contributed to the reactions with the oxygen carrier in the absence of steam. Increasing steam concentration had a negative effect on the CLOU reaction.« less

A Preliminary Study on the Toxic Combustion Products Testing of Polymers Used in High-Pressure Oxygen Systems

NASA Technical Reports Server (NTRS)

Hshieh, Fu-Yu; Beeson, Harold D.

2004-01-01

One likely cause of polymer ignition in a high-pressure oxygen system is adiabatic-compression heating of polymers caused by pneumatic impact. Oxidative _ pyrolysis or combustion of polymers in a high-pressure oxygen system could generate toxic gases. This paper reports the preliminary results of toxic combustion product testing of selected polymers in a pneumatic-impact test system. Five polymers commonly used in high-pressure oxygen systems, Nylon 6/6, polychlorotrifluoroethylene (CTFE), polytetrafluoroethylene (PTFE), fluoroelastomer (Viton(TradeMark) A), and nitrile rubber (Buna N), were tested in a pneumatic-impact test system at 2500- or 3500-psia oxygen pressure. The polymers were ignited and burned, then combustion products were collected in a stainless-steel sample bottle and analyzed by GC/MS/IRD, GC/FID, and GC/Methanizer/FID. The results of adiabatic-compression tests show that combustion of hydrocarbon polymers, nitrogen-containing polymers, and halogenated polymers in high-pressure oxygen systems are relatively complete. Toxicity of the combustion product gas is presumably much lower than the combustion product gas generated from ambient-pressure oxygen (or air) environments. The NASA-Lewis equilibrium code was used to determine the composition of combustion product gas generated from a simulated, adiabatic-compression test of nine polymers. The results are presented and discussed.

A Brief Study on Toxic Combustion Products of the Polymers Used in High-Pressure Oxygen Systems

NASA Technical Reports Server (NTRS)

Hshieh, Fu-Yu; Beeson, Harold D.

2005-01-01

One likely cause of polymer ignition in a high-pressure oxygen system is the adiabatic-compression heating of polymers caused by pneumatic impact. Oxidative pyrolysis or combustion of polymers in a high-pressure oxygen system could generate toxic gases. This paper investigates the feasibility of using the NASA pneumatic-impact system to conduct adiabatic-compression combustion tests and determines the toxic combustion products produced from the burning of five selected polymers. Five polymers commonly used in high-pressure oxygen systems, Zytel(Registered TradeMark) 42 (Nylon 6/6), Buna N (nitrile rubber), Witon(Registered TradeMark) A (copolymer of vinylidene fluoride and hexafluoropropylene), Neoflon(Registered TradeMark) (polychlorotrifluoroethylene), and Teflon(Registered TradeMark) (polytetrafluoroethylene), were tested in the NASA pneumatic-impact test system at 17.2-MPa oxygen pressure. The polymers were ignited and burned; combustion products were collected in a stainless-steel sample bottle and analyzed using various methods. The results show that the NASA pneumatic-impact system is an appropriate test system to conduct adiabatic-compression combustion tests and to collect combustion products for further chemical analysis. The composition of the combustion product gas generated from burning the five selected polymers are presented and discussed.

Intrinsic and metal-doped gallium oxide based high-temperature oxygen sensors for combustion processes

NASA Astrophysics Data System (ADS)

Rubio, Ernesto Javier

Currently, there is enormous interest in research, development and optimization of the combustion processes for energy harvesting. Recent statistical and economic analyses estimated that by improving the coal-based firing/combustion processes in the power plants, savings up to $450-500 million yearly can be achieved. Advanced sensors and controls capable of withstanding extreme environments such as high temperatures, highly corrosive atmospheres, and high pressures are critical to such efficiency enhancement and cost savings. For instance, optimization of the combustion processes in power generation systems can be achieved by sensing, monitoring and control of oxygen, which is a measure of the completeness of the process and can lead to enhanced efficiency and reduced greenhouse gas emissions. However, despite the fact that there exists a very high demand for advanced sensors, the existing technologies suffer from poor 'response and recovery times' and 'long-term stability.' Motivated by the aforementioned technological challenges, the present work was focused on high-temperature (≥700 °C) oxygen sensors for application in power generation systems. The objective of the present work is to investigate nanostructured gallium oxide (2O3) based sensors for oxygen sensing, where we propose to conduct in-depth exploration of the role of refractory metal (tungsten, W, in this case) doping into 2O 3 to enhance the sensitivity, selectivity, stability ("3S" criteria) and reliability of such sensors while keeping cost economical. Tungsten (W) doped gallium oxide (2O3) thin films were deposited via rf-magnetron co-sputtering of W-metal and Ga2O3-ceramic targets. Films were produced by varying the sputtering power applied to the W-target in order to achieve variable W content into 2O3 films while substrate temperature was kept constant at 500 °C. Chemical composition, chemical valence states, microstructure and crystal structure of as-grown and post-annealed W-doped 2O3

Engine Valve Actuation For Combustion Enhancement

DOEpatents

Reitz, Rolf Deneys; Rutland, Christopher J.; Jhavar, Rahul

2004-05-18

A combustion chamber valve, such as an intake valve or an exhaust valve, is briefly opened during the compression and/or power strokes of a 4-stroke combustion cycle in an internal combustion engine (in particular, a diesel or CI engine). The brief opening may (1) enhance mixing withing the combustion chamber, allowing more complete oxidation of particulates to decrease engine emissions; and/or may (2) delay ignition until a more desirable time, potentially allowing a means of timing ignition in otherwise difficult-to-control conditions, e.g., in HCCI (Homogeneous Charge Compression Ignition) conditions.

Engine valve actuation for combustion enhancement

DOEpatents

Reitz, Rolf Deneys [Madison, WI; Rutland, Christopher J [Madison, WI; Jhavar, Rahul [Madison, WI

2008-03-04

A combustion chamber valve, such as an intake valve or an exhaust valve, is briefly opened during the compression and/or power strokes of a 4-strokes combustion cycle in an internal combustion engine (in particular, a diesel or CI engine). The brief opening may (1) enhance mixing withing the combustion chamber, allowing more complete oxidation of particulates to decrease engine emissions; and/or may (2) delay ignition until a more desirable time, potentially allowing a means of timing ignition in otherwise difficult-to-control conditions, e.g., in HCCI (Homogeneous Charge Compression Ignition) conditions.

Combustion and Performance Analyses of Coaxial Element Injectors with Liquid Oxygen/Liquid Methane Propellants

NASA Technical Reports Server (NTRS)

Hulka, J. R.; Jones, G. W.

2010-01-01

Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in a flight-qualified engine system, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented activities with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, the NASA Marshall Space Flight Center has conducted combustion, performance, and combustion stability analyses of several of the configurations. This paper summarizes the analyses of combustion and performance as a follow-up to a paper published in the 2008 JANNAF/LPS meeting. Combustion stability analyses are presented in a separate paper. The current paper includes test and analysis results of coaxial element injectors using liquid oxygen and liquid methane or gaseous methane propellants. Several thrust chamber configurations have been modeled, including thrust chambers with multi-element swirl coax element injectors tested at the NASA MSFC, and a uni-element chamber with shear and swirl coax injectors tested at The Pennsylvania State University. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interaction Design and Analysis (ROCCID), and the Coaxial Injector Combustion Model (CICM). Significant effort was applied to show how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied or developed in the future. This paper describes the test hardware configurations, presents the results of all the analyses, and compares the results from the two analytical methods

NOx reduction in combustion with concentrated coal streams and oxygen injection

DOEpatents

Kobayashi, Hisashi; Bool, III, Lawrence E.; Snyder, William J.

2004-03-02

NOx formation in the combustion of solid hydrocarbonaceous fuel such as coal is reduced by obtaining, from the incoming feed stream of fuel solids and air, a stream having a ratio of fuel solids to air that is higher than that of the feed steam, and injecting the thus obtained stream and a small amount of oxygen to a burner where the fuel solids are combusted.

Oxygen index: An approximate value for the evaluation of combustion characteristics

NASA Technical Reports Server (NTRS)

Zartmann, I.; Reinwardt, D.; Franke, A.

1986-01-01

The oxygen index has gained international recognition for the determination of combustion characteristics of plastic material. The amounts of oxygen and nitrogen were more accurately determined for existing test equipment in order to specify the oxygen index as precisely and as reproducible as possible. Parameters are outlined such as the size of the ignition flame, ignition of test pieces, test piece sizes and test temperature. The minimum oxygen index was determined by the dimension and duration of the fire. The results are sufficiently accurate for factory operating conditions and are also reproducible.

Powdered aluminum and oxygen rocket propellants: Subscale combustion experiments

NASA Technical Reports Server (NTRS)

Meyer, Mike L.

1993-01-01

Aluminum combined with oxygen has been proposed as a potential lunar in situ propellant for ascent/descent and return missions for future lunar exploration. Engine concepts proposed to use this propellant have not previously been demonstrated, and the impact on performance from combustion and two-phase flow losses could only be estimated. Therefore, combustion tests were performed for aluminum and aluminum/magnesium alloy powders with oxygen in subscale heat-sink rocket engine hardware. The metal powder was pneumatically injected, with a small amount of nitrogen, through the center orifice of a single element O-F-O triplet injector. Gaseous oxygen impinged on the fuel stream. Hot-fire tests of aluminum/oxygen were performed over a mixture ratio range of 0.5 to 3.0, and at a chamber pressure of approximately 480 kPa (70 psia). The theoretical performance of the propellants was analyzed over a mixture ratio range of 0.5 to 5.0. In the theoretical predictions the ideal one-dimensional equilibrium rocket performance was reduced by loss mechanisms including finite rate kinetics, two-dimensional divergence losses, and boundary layer losses. Lower than predicted characteristic velocity and specific impulse performance efficiencies were achieved in the hot-fire tests, and this was attributed to poor mixing of the propellants and two-phase flow effects. Several tests with aluminum/9.8 percent magnesium alloy powder did not indicate any advantage over the pure aluminum fuel.

Injection Principles from Combustion Studies in a 200-Pound-Thrust Rocket Engine Using Liquid Oxygen and Heptane

NASA Technical Reports Server (NTRS)

Heidmann, M. F.; Auble, C. M.

1955-01-01

The importance of atomizing and mixing liquid oxygen and heptane was studied in a 200-pound-thrust rocket engine. Ten injector elements were used with both steel and transparent chambers. Characteristic velocity was measured over a range of mixture ratios. Combustion gas-flow and luminosity patterns within the chamber were obtained by photographic methods. The results show that, for efficient combustion, the propellants should be both atomized and mixed. Heptane atomization controlled the combustion rate to a much larger extent than oxygen atomization. Induced mixing, however, was required to complete combustion in the smallest volume. For stable, high-efficiency combustion and smooth engine starts, mixing after atomization was most promising.

Coal Combustion Behavior in New Ironmaking Process of Top Gas Recycling Oxygen Blast Furnace

NASA Astrophysics Data System (ADS)

Zhou, Zhenfeng; Xue, Qingguo; Tang, Huiqing; Wang, Guang; Wang, Jingsong

2017-10-01

The top gas recycling oxygen blast furnace (TGR-OBF) is a new ironmaking process which can significantly reduce the coke ratio and emissions of carbon dioxide. To better understand the coal combustion characteristics in the TGR-OBF, a three dimensional model was developed to simulate the lance-blowpipe-tuyere-raceway of a TGR-OBF. The combustion characteristics of pulverized coal in TGR-OBF were investigated. Furthermore, the effects of oxygen concentration and temperature were also analyzed. The simulation results show that the coal burnout increased by 16.23% compared to that of the TBF. The oxygen content has an obvious effect on the burnout. At 70% oxygen content, the coal burnout is only 21.64%, with a decrease of 50.14% compared to that of TBF. Moreover, the effect of oxygen temperature is also very obvious.

Importance of atomic oxygen in preheating zone in plasma-assisted combustion of a steady-state premixed burner flame

NASA Astrophysics Data System (ADS)

Zaima, K.; Akashi, H.; Sasaki, K.

2015-09-01

It is widely believed that electron impact processes play essential roles in plasma-assisted combustion. However, the concrete roles of high-energy electrons have not been fully understood yet. In this work, we examined the density of atomic oxygen in a premixed burner flame with the superposition of dielectric barrier discharge (DBD). The density of atomic oxygen in the reaction zone was not affected by the superposition of DBD, indicating that the amount of atomic oxygen produced by combustion reactions was much larger than that produced by electron impact processes. On the other hand, in the preheating zone, we observed high-frequency oscillation of the density of atomic oxygen at the timings of the pulsed current of DBD. The oscillation suggests the rapid consumption of additional atomic oxygen by combustion reactions. A numerical simulation using Chemkin indicates the shortened ignition delay time when adding additional atomic oxygen in the period of low-temperature oxidation. The present results reveals the importance of atomic oxygen, which is produced by the effect of high-energy electrons, in the preheating zone in plasma-assisted combustion of the steady-state premixed burner flame.

Combustion Dynamics and Stability Modeling of a Liquid Oxygen/RP-2 Oxygen-Rich Staged Combustion Preburner and Thrust Chamber Assembly with Gas-Centered Swirl Coaxial Injector Elements

NASA Technical Reports Server (NTRS)

Casiano, M. J.; Kenny, R. J.; Protz, C. S.; Garcia, C. P.; Simpson, S. P.; Elmore, J. L.; Fischbach, S. R.; Giacomoni, C. B.; Hulka, J. R.

2016-01-01

The Combustion Stability Tool Development (CSTD) project, funded by the Air Force Space and Missile Systems Center, began in March 2015 supporting a renewed interest in the development of a liquid oxygen/hydrocarbon, oxygen-rich combustion engine. The project encompasses the design, assembly, and hot-fire testing of the NASA Marshall Space Flight Center 40-klbf Integrated Test Rig (MITR). The test rig models a staged-combustion configuration by combining an oxygen-rich preburner (ORPB), to generate hot gas, with a thrust chamber assembly (TCA) using gas-centered swirl coaxial injector elements. There are five separately designed interchangeable injectors in the TCA that each contain 19- or 27- injector elements. A companion paper in this JANNAF conference describes the design characteristics, rationale, and fabrication issues for all the injectors. The data acquired from a heavily instrumented rig encompasses several injectors, several operating points, and stability bomb tests. Another companion paper in this JANNAF conference describes this test program in detail. In this paper, dynamic data from the hot-fire testing is characterized and used to identify the responses in the ORPB and TCA. A brief review of damping metrics are discussed and applied as a measure of stability margin for damped acoustic modes. Chug and longitudinal combustion stability models and predictions are described which includes new dynamic models for compressible flow through an orifice and a modification to incorporate a third feed line for inclusion of the fuel-film coolant. Flow-acoustics finite element modeling is used to investigate the anticipated TCA acoustics, the effects of injector element length on stability margin, and the potential use of an ORPB orifice trip ring for improving longitudinal stability margin.

Performance and Stability Analyses of Rocket Combustion Devices Using Liquid Oxygen/Liquid Methane Propellants

NASA Technical Reports Server (NTRS)

Hulka, James R.; Jones, G. W.

2010-01-01

Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in flight-qualified engine systems, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented programs with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, NASA Marshall Space Flight Center has conducted combustion, performance, and combustion stability analyses of several of the configurations on these programs. This paper summarizes these analyses. Test and analysis results of impinging and coaxial element injectors using liquid oxygen and liquid methane propellants are included. Several cases with gaseous methane are included for reference. Several different thrust chamber configurations have been modeled, including thrust chambers with multi-element like-on-like and swirl coax element injectors tested at NASA MSFC, and a unielement chamber with shear and swirl coax injectors tested at The Pennsylvania State University. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interaction Design and Analysis (ROCCID), and the Coaxial Injector Combustion Model (CICM). Significant effort was applied to show how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied or developed in the future. This paper describes the test hardware configurations, presents the results of all the analyses, and compares the results from the two analytical methods.

Leaner Lifted-Flame Combustion Enabled by the Use of an Oxygenated Fuel in an Optical CI Engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gehmlich, Ryan K.; Dumitrescu, Cosmin E.; Wang, Yefu

Leaner lifted-flame combustion (LLFC) is a mixing-controlled combustion strategy for compression-ignition engines that does not produce soot because the equivalence ratio at the lift-off length, Φ(H), is less than or equal to approximately two. In addition to preventing soot formation, LLFC can simultaneously control emissions of nitrogen oxides because it is tolerant to the use of exhaust-gas recirculation for lowering in-cylinder temperatures. LLFC can be achieved through the use of oxygenated fuels and enhanced fuel/charge-gas mixing upstream of the lift-off length. Enhanced mixing can be obtained via higher injection pressures, smaller injector orifice diameters, lower intake-manifold and coolant temperatures, and/ormore » more retarded injection timings. This study focuses on the effects of an oxygenated fuel blend (T50) made up of 50% by volume tri-propylene glycol mono-methyl ether with a #2 ULSD emissions-certification fuel (CFA), compared against baseline testing of the CFA fuel without the oxygenate. Experimental measurements include crank-angle resolved natural luminosity (NL) and chemiluminescence (CL) imaging diagnostics. EGR is simulated by adding nitrogen and carbon dioxide to the intake charge to produce a 16% intake-oxygen mole fraction (XO2), and results are compared against cases with no charge dilution (i.e., 21% XO2). Initial experiments with a two-hole tip achieved soot-free LLFC at low loads with the T50 fuel, 240 MPa injection pressure, 50 °C intake-manifold temperature (IMT), 95 °C coolant temperature, and -5 crank-angle degree (CAD) after top-dead-center (ATDC) start of combustion (SOC) timing. The strategy was extended to more moderate loads by employing a 6-hole injector tip, where lowering the IMT to 30 °C, reducing the coolant temperature to 85 °C, and retarding the SOC timing to +5 CAD ATDC resulted in sustained LLFC at both 21% and 16% XO2 at up to 6.2 bar gross indicated mean effective pressure (gIMEP) with T50. The

Leaner Lifted-Flame Combustion Enabled by the Use of an Oxygenated Fuel in an Optical CI Engine

DOE PAGES

Gehmlich, Ryan K.; Dumitrescu, Cosmin E.; Wang, Yefu; ...

2016-04-05

Leaner lifted-flame combustion (LLFC) is a mixing-controlled combustion strategy for compression-ignition engines that does not produce soot because the equivalence ratio at the lift-off length, Φ(H), is less than or equal to approximately two. In addition to preventing soot formation, LLFC can simultaneously control emissions of nitrogen oxides because it is tolerant to the use of exhaust-gas recirculation for lowering in-cylinder temperatures. LLFC can be achieved through the use of oxygenated fuels and enhanced fuel/charge-gas mixing upstream of the lift-off length. Enhanced mixing can be obtained via higher injection pressures, smaller injector orifice diameters, lower intake-manifold and coolant temperatures, and/ormore » more retarded injection timings. This study focuses on the effects of an oxygenated fuel blend (T50) made up of 50% by volume tri-propylene glycol mono-methyl ether with a #2 ULSD emissions-certification fuel (CFA), compared against baseline testing of the CFA fuel without the oxygenate. Experimental measurements include crank-angle resolved natural luminosity (NL) and chemiluminescence (CL) imaging diagnostics. EGR is simulated by adding nitrogen and carbon dioxide to the intake charge to produce a 16% intake-oxygen mole fraction (XO2), and results are compared against cases with no charge dilution (i.e., 21% XO2). Initial experiments with a two-hole tip achieved soot-free LLFC at low loads with the T50 fuel, 240 MPa injection pressure, 50 °C intake-manifold temperature (IMT), 95 °C coolant temperature, and -5 crank-angle degree (CAD) after top-dead-center (ATDC) start of combustion (SOC) timing. The strategy was extended to more moderate loads by employing a 6-hole injector tip, where lowering the IMT to 30 °C, reducing the coolant temperature to 85 °C, and retarding the SOC timing to +5 CAD ATDC resulted in sustained LLFC at both 21% and 16% XO2 at up to 6.2 bar gross indicated mean effective pressure (gIMEP) with T50. The

New type of microengine using internal combustion of hydrogen and oxygen

NASA Astrophysics Data System (ADS)

Svetovoy, Vitaly B.; Sanders, Remco G. P.; Ma, Kechun; Elwenspoek, Miko C.

2014-03-01

Microsystems become part of everyday life but their application is restricted by lack of strong and fast motors (actuators) converting energy into motion. For example, widespread internal combustion engines cannot be scaled down because combustion reactions are quenched in a small space. Here we present an actuator with the dimensions 100 × 100 × 5 μm3 that is using internal combustion of hydrogen and oxygen as part of its working cycle. Water electrolysis driven by short voltage pulses creates an extra pressure of 0.5-4 bar for a time of 100-400 μs in a chamber closed by a flexible membrane. When the pulses are switched off this pressure is released even faster allowing production of mechanical work in short cycles. We provide arguments that this unexpectedly fast pressure decrease is due to spontaneous combustion of the gases in the chamber. This actuator is the first step to truly microscopic combustion engines.

Chemicl-looping combustion of coal with metal oxide oxygen carriers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siriwardane, R.; Tian, H.; Richards, G.

2009-01-01

The combustion and reoxidation properties of direct coal chemical-looping combustion (CLC) over CuO, Fe2O3, Co3O4, NiO, and Mn2O3 were investigated using thermogravimetric analysis (TGA) and bench-scale fixed-bed flow reactor studies. When coal is heated in either nitrogen or carbon dioxide (CO2), 50% of weight loss was observed because of partial pyrolysis, consistent with the proximate analysis. Among various metal oxides evaluated, CuO showed the best reaction properties: CuO can initiate the reduction reaction as low as 500 °C and complete the full combustion at 700 °C. In addition, the reduced copper can be fully reoxidized by air at 700 °C.more » The combustion products formed during the CLC reaction of the coal/metal oxide mixture are CO2 and water, while no carbon monoxide was observed. Multicycle TGA tests and bench-scale fixed-bed flow reactor tests strongly supported the feasibility of CLC of coal by using CuO as an oxygen carrier. Scanning electron microscopy (SEM) images of solid reaction products indicated some changes in the surface morphology of a CuO-coal sample after reduction/oxidation reactions at 800 °C. However, significant surface sintering was not observed. The interactions of fly ash with metal oxides were investigated by X-ray diffraction and thermodynamic analysis. Overall, the results indicated that it is feasible to develop CLC with coal by metal oxides as oxygen carriers.« less

Combustion Stability Analyses of Coaxial Element Injectors with Liquid Oxygen/Liquid Methane Propellants

NASA Technical Reports Server (NTRS)

Hulka, J. R.

2010-01-01

Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in a flight-qualified engine system, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented activities with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, the NASA Marshall Space Flight Center has conducted combustion stability analyses of several of the configurations. This paper presents test data and analyses of combustion stability from the recent PCAD-funded test programs at the NASA MSFC. These test programs used swirl coaxial element injectors with liquid oxygen and liquid methane propellants. Oxygen was injected conventionally in the center of the coaxial element, and swirl was provided by tangential entry slots. Injectors with 28-element and 40-element patterns were tested with several configurations of combustion chambers, including ablative and calorimeter spool sections, and several configurations of fuel injection design. Low frequency combustion instability (chug) occurred with both injectors, and high-frequency combustion instability occurred at the first tangential (1T) transverse mode with the 40-element injector. In most tests, a transition between high-amplitude chug with gaseous methane flow and low-amplitude chug with liquid methane flow was readily observed. Chug analyses of both conditions were conducted using techniques from Wenzel and Szuch and from the Rocket Combustor Interactive Design and Analysis (ROCCID) code. The 1T mode instability occurred in several tests and was apparent by high-frequency pressure measurements as well as dramatic increases in calorimeter-measured heat flux

Regenerable mixed copper-iron-inert support oxygen carriers for solid fuel chemical looping combustion process

DOEpatents

Siriwardane, Ranjani V.; Tian, Hanjing

2016-12-20

The disclosure provides an oxygen carrier for a chemical looping cycle, such as the chemical looping combustion of solid carbonaceous fuels, such as coal, coke, coal and biomass char, and the like. The oxygen carrier is comprised of at least 24 weight % (wt %) CuO, at least 10 wt % Fe2O3, and an inert support, and is typically a calcine. The oxygen carrier exhibits a CuO crystalline structure and an absence of iron oxide crystalline structures under XRD crystallography, and provides an improved and sustained combustion reactivity in the temperature range of 600.degree. C.-1000.degree. C. particularly for solid fuels such as carbon and coal.

SnO2 promoted by alkali metal oxides for soot combustion: The effects of surface oxygen mobility and abundance on the activity

NASA Astrophysics Data System (ADS)

Rao, Cheng; Shen, Jiating; Wang, Fumin; Peng, Honggen; Xu, Xianglan; Zhan, Hangping; Fang, Xiuzhong; Liu, Jianjun; Liu, Wenming; Wang, Xiang

2018-03-01

In this study, SnO2-based catalysts promoted by different alkali metal oxides with a Sn/M (M = Li, Na, K, Cs) molar ratio of 9/1 have been prepared for soot combustion. In comparison with the un-modified SnO2 support, the activity of the modified catalysts has been evidently enhanced, following the sequence of CsSn1-9 > KSn1-9 > NaSn1-9 > LiSn1-9 > SnO2. As testified by Raman, H2-TPR, soot-TPR-MS, XPS and O2-TPD results, the incorporation of various alkali metal oxides can induce the formation of more abundant and mobile oxygen species on the surface of the catalysts. Moreover, quantified results have proved that the amount of the surface active oxygen species is nearly proportional to the activity of the catalysts. CsSn1-9, the catalyst promoted by cesium oxide, owns the largest amount of surface mobile oxygen species, thus having the highest activity among all the studied catalysts. It is concluded that the amount of surface active and mobile oxygen species is the major factor determining the activity of the catalysts for soot combustion.

Chemical-Looping Combustion and Gasification of Coals and Oxygen Carrier Development: A Brief Review

DOE PAGES

Wang, Ping; Means, Nicholas; Shekhawat, Dushyant; ...

2015-09-24

Chemical-looping technology is one of the promising CO 2 capture technologies. It generates a CO 2 enriched flue gas, which will greatly benefit CO 2 capture, utilization or sequestration. Both chemical-looping combustion (CLC) and chemical-looping gasification (CLG) have the potential to be used to generate power, chemicals, and liquid fuels. Chemical-looping is an oxygen transporting process using oxygen carriers. Recently, attention has focused on solid fuels such as coal. Coal chemical-looping reactions are more complicated than gaseous fuels due to coal properties (like mineral matter) and the complex reaction pathways involving solid fuels. The mineral matter/ash and sulfur in coalmore » may affect the activity of oxygen carriers. Oxygen carriers are the key issue in chemical-looping processes. Thermogravimetric analysis (TGA) has been widely used for the development of oxygen carriers (e.g., oxide reactivity). Two proposed processes for the CLC of solid fuels are in-situ Gasification Chemical-Looping Combustion (iG-CLC) and Chemical-Looping with Oxygen Uncoupling (CLOU). The objectives of this review are to discuss various chemical-looping processes with coal, summarize TGA applications in oxygen carrier development, and outline the major challenges associated with coal chemical-looping in iG-CLC and CLOU.« less

Exhaust heated hydrogen and oxygen producing catalytic converter for combustion engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schreiber, E.T.

1977-07-26

A steam generator is provided in operative association with a source of water and the exhaust system of a combustion engine including an air induction system provided with primary fuel inlet structure and supplemental fuel inlet structure. The steam generator derives its heat for converting water into steam from the exhaust system of the combustion engine and the steam generator includes a steam outlet communicated with and opening into one end of an elongated tubular housing disposed in good heat transfer relation with the exhaust system of the combustion engine and having a gas outlet at its other end communicatedmore » with the supplemental fuel inlet of the induction system. The tubular housing has iron filings disposed therein and is in such heat transfer relation with the exhaust system of the combustion engine so as to elevate the temperature of steam passing therethrough and to heat the iron filings to the extent that passage of the heated steam over the heated filings will result in hydrogen and oxygen gas being produced in the tubular housing for subsequent passage to the supplemental fuel inlet of the combustion engine induction system.« less

Pressurized chemical-looping combustion of coal with an iron ore-based oxygen carrier

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiao, Rui; Song, Min; Zhang, Shuai

2010-06-15

Chemical-looping combustion (CLC) is a new combustion technology with inherent separation of CO{sub 2}. Most of the previous investigations on CLC of solid fuels were conducted under atmospheric pressure. A pressurized CLC combined cycle (PCLC-CC) system is proposed as a promising coal combustion technology with potential higher system efficiency, higher fuel conversion, and lower cost for CO{sub 2} sequestration. In this study pressurized CLC of coal with Companhia Valedo Rio Doce (CVRD) iron ore was investigated in a laboratory fixed bed reactor. CVRD iron ore particles were exposed alternately to reduction by 0.4 g of Chinese Xuzhou bituminous coal gasifiedmore » with 87.2% steam/N{sub 2} mixture and oxidation with 5% O{sub 2} in N{sub 2} at 970 C. The operating pressure was varied between 0.1 MPa and 0.6 MPa. First, control experiments of steam coal gasification over quartz sand were performed. H{sub 2} and CO{sub 2} are the major components of the gasification products, and the operating pressure influences the gas composition. Higher concentrations of CO{sub 2} and lower fractions of CO, CH{sub 4}, and H{sub 2} during the reduction process with CVRD iron ore was achieved under higher pressures. The effects of pressure on the coal gasification rate in the presence of the oxygen carrier were different for pyrolysis and char gasification. The pressurized condition suppresses the initial coal pyrolysis process while it also enhances coal char gasification and reduction with iron ore in steam, and thus improves the overall reaction rate of CLC. The oxidation rates and variation of oxygen carrier conversion are higher at elevated pressures reflecting higher reduction level in the previous reduction period. Scanning electron microscope and energy-dispersive X-ray spectroscopy (SEM-EDX) analyses show that particles become porous after experiments but maintain structure and size after several cycles. Agglomeration was not observed in this study. An EDX analysis

Photographic Study of Combustion in a Rocket Engine I : Variation in Combustion of Liquid Oxygen and Gasoline with Seven Methods of Propellant Injection

NASA Technical Reports Server (NTRS)

Bellman, Donald R; Humphrey, Jack C

1948-01-01

Motion pictures at camera speeds up to 3000 frames per second were taken of the combustion of liquid oxygen and gasoline in a 100-pound-thrust rocket engine. The engine consisted of thin contour and injection plates clamped between two clear plastic sheets forming a two-dimensional engine with a view of the entire combustion chamber and nozzle. A photographic investigation was made of the effect of seven methods of propellant injection on the uniformity of combustion. From the photographs, it was found that the flame front extended almost to the faces of the injectors with most of the injection methods, all the injection systems resulted in a considerable nonuniformity of combustion, and luminosity rapidly decreased in the divergent part of the nozzle. Pressure vibration records indicated combustion vibrations that approximately corresponded to the resonant frequencies of the length and the thickness of the chamber. The combustion temperature divided by the molecular weight of the combustion gases as determined from the combustion photographs was about 50 to 70 percent of the theoretical value.

PROGRESS IN DETAILED KINETIC MODELING OF THE COMBUSTION OF OXYGENATED COMPONENTS OF BIOFUELS

PubMed Central

Sy Tran, Luc; Sirjean, Baptiste; Glaude, Pierre-Alexandre; Fournet, René; Battin-Leclerc, Frédérique

2013-01-01

Due to growing environmental concerns and diminishing petroleum reserves, a wide range of oxygenated species has been proposed as possible substitutes to fossil fuels: alcohols, methyl esters, acyclic and cyclic ethers. After a short review the major detailed kinetic models already proposed in the literature for the combustion of these molecules, the specific classes of reactions considered for modeling the oxidation of acyclic and cyclic oxygenated molecules respectively, are detailed. PMID:23700355

An analysis of combustion studies in shock expansion tunnels and reflected shock tunnels

NASA Technical Reports Server (NTRS)

Jachimowski, Casimir J.

1992-01-01

The effect of initial nonequilibrium dissociated air constituents on the combustion of hydrogen in high-speed flows for a simulated Mach 17 flight condition was investigated by analyzing the results of comparative combustion experiments performed in a reflected shock tunnel test gas and in a shock expansion tunnel test gas. The results were analyzed and interpreted with a one-dimensional quasi-three-stream combustor code that includes finite rate combustion chemistry. The results of this study indicate that the combustion process is kinetically controlled in the experiments in both tunnels and the presence of the nonequilibrium partially dissociated oxygen in the reflected shock tunnel enhances the combustion. Methods of compensating for the effect of dissociated oxygen are discussed.

FIELD DEMONSTRATION OF THE LINDE OXYGEN COMBUSTION SYSTEM ON THE EPA MOBILE INCINERATOR

EPA Science Inventory

This paper summarizes the various system performance tests and the long-term operating experience of the LINDE Oxygen Combustion System installed on the U.S. Environmental Protection Agency's Mobile Incineration System (MIS) when it was in operation at the Denney Farm site in sou...

Burning of solids in oxygen-rich environments in normal and reduced gravity. [combustion of cellulose acetates

NASA Technical Reports Server (NTRS)

Andracchio, C. R.; Cochran, T. H.

1974-01-01

An experimental program was conducted to investigate the combustion characteristics of solids burning in a weightless environment. The combustion characteristics of thin cellulose acetate material were obtained from specimens burned in supercritical as well as in low pressure oxygen atmospheres. Flame spread rates were measured and found to depend on material thickness and pressure in both normal gravity (1-g) and reduced gravity (0-g). A gravity effect on the burning process was also observed; the ratio of 1-g to 0-g flame spread rate becomes larger with increasing material thickness. Qualitative results on the combustion characteristics of metal screens (stainless steel, Inconel, copper, and aluminum) burning in supercritical oxygen and normal gravity are also presented. Stainless steel (300 sq mesh) was successfully ignited in reduced gravity; no apparent difference in the flame spread pattern was observed between 1-g and 0-g.

Measurement and modelling of oxygenated organic compounds from smoldering combustion of biomass

DOE Office of Scientific and Technical Information (OSTI.GOV)

McKenzie, L.M.; Richards, G.N.

Biomass fires emit a myriad of compounds, some of which are toxic and/or globally significant as photochemically reactive, tropospheric trace gases, greenhouse gases and precursors to stratospheric ozone-destroying radicals. 35 oxygenated organic compounds in condensed (-45{degrees}C) smoke from 29 bench scale fires of ponderosa pine sapwood, needles, bark, litter, duff, and humus have been identified and quantified. These fires ranged from flaming to low intensity smoldering. In addition, five low intensity fires of intact ponderosa pine forest floor (litter, duff, and humus) were carried out on a larger scale in a combustion chamber. The condensates were analyzed by gas chromatography/massmore » spectrometry and the gas phase was analyzed by gas chromatography/flame ionization detection. Acetic acid, vinyl acetate and acetol were major condensable emissions. The dependence of oxygenated organic emissions on fuel chemistry and combustion efficiency has been investigated, along with correlations between emissions. Molar emission ratios of individual compounds to CO have been calculated and used to estimate possible exposure levels for wildland firefighters.« less

Methanol Droplet Combustion in Oxygen-Inert Environments in Microgravity

NASA Technical Reports Server (NTRS)

Nayagam, Vedha; Dietrich, Daniel L.; Hicks, Michael C.; Williams, Forman A.

2013-01-01

The Flame Extinguishment (FLEX) experiment that is currently underway in the Combustion Integrated Rack facility onboard the International Space Station is aimed at understanding the effects of inert diluents on the flammability of condensed phase fuels. To this end, droplets of various fuels, including alkanes and alcohols, are burned in a quiescent microgravity environment with varying amounts of oxygen and inert diluents to determine the limiting oxygen index (LOI) for these fuels. In this study we report experimental observations of methanol droplets burning in oxygen-nitrogen-carbon dioxide and oxygen-nitrogen-helium gas mixtures at 0.7 and 1 atmospheric pressures. The initial droplet size varied between approximately 1.5 mm and 4 mm to capture both diffusive extinction brought about by insufficient residence time at the flame and radiative extinction caused by excessive heat loss from the flame zone. The ambient oxygen concentration varied from a high value of 30% by volume to as low as 12%, approaching the limiting oxygen index for the fuel. The inert dilution by carbon dioxide and helium varied over a range of 0% to 70% by volume. In these experiments, both freely floated and tethered droplets were ignited using symmetrically opposed hot-wire igniters and the burning histories were recorded onboard using digital cameras, downlinked later to the ground for analysis. The digital images yielded droplet and flame diameters as functions of time and subsequently droplet burning rate, flame standoff ratio, and initial and extinction droplet diameters. Simplified theoretical models correlate the measured burning rate constant and the flame standoff ratio reasonably well. An activation energy asymptotic theory accounting for time-dependent water dissolution or evaporation from the droplet is shown to predict the measured diffusive extinction conditions well. The experiments also show that the limiting oxygen index for methanol in these diluent gases is around 12% to

A mechanistic investigation of the oxygen fixation hypothesis and oxygen enhancement ratio.

PubMed

Grimes, David Robert; Partridge, Mike

2015-12-04

The presence of oxygen in tumours has substantial impact on treatment outcome; relative to anoxic regions, well-oxygenated cells respond better to radiotherapy by a factor 2.5-3. This increased radio-response is known as the oxygen enhancement ratio. The oxygen effect is most commonly explained by the oxygen fixation hypothesis, which postulates that radical-induced DNA damage can be permanently 'fixed' by molecular oxygen, rendering DNA damage irreparable. While this oxygen effect is important in both existing therapy and for future modalities such a radiation dose-painting, the majority of existing mathematical models for oxygen enhancement are empirical rather than based on the underlying physics and radiochemistry. Here we propose a model of oxygen-enhanced damage from physical first principles, investigating factors that might influence the cell kill. This is fitted to a range of experimental oxygen curves from literature and shown to describe them well, yielding a single robust term for oxygen interaction obtained. The model also reveals a small thermal dependency exists but that this is unlikely to be exploitable.

A System for Controlling the Oxygen Content of a Gas Produced by Combustion

NASA Technical Reports Server (NTRS)

Singh, J. J.; Davis, W. T.; Puster, R. L. (Inventor)

1984-01-01

A mixture of air, CH4 and OH(2) is burned in a combustion chamber to produce a product gas in the test section. The OH(2) content of the product gas is compared with the OH(2) content of reference air in an OH(2) sensor. If there is a difference an error signal is produced at the output of a control circuit which by the means of a solenoid valve, regulates the flow of OH(2) into the combustion chamber to make the error signal zero. The product gas in the test section has the same oxygen content as air.

Algorithmic Enhancements for Unsteady Aerodynamics and Combustion Applications

NASA Technical Reports Server (NTRS)

Venkateswaran, Sankaran; Olsen, Michael (Technical Monitor)

2001-01-01

Research in the FY01 focused on the analysis and development of enhanced algorithms for unsteady aerodynamics and chemically reacting flowfields. The research was performed in support of NASA Ames' efforts to improve the capabilities of the in-house computational fluid dynamics code, OVERFLOW. Specifically, the research was focused on the four areas: (1) investigation of stagnation region effects; (2) unsteady preconditioning dual-time procedures; (3) dissipation formulation for combustion; and (4) time-stepping methods for combustion.

Hot-Fire Test Results of an Oxygen/RP-2 Multi-Element Oxidizer-Rich Staged-Combustion Integrated Test Article

NASA Technical Reports Server (NTRS)

Hulka, J. R.; Protz, C. S.; Garcia, C. P.; Casiano, M. J.; Parton, J. A.

2016-01-01

As part of the Combustion Stability Tool Development project funded by the Air Force Space and Missile Systems Center, the NASA Marshall Space Flight Center was contracted to assemble and hot-fire test a multi-element integrated test article demonstrating combustion characteristics of an oxygen/hydrocarbon propellant oxidizer-rich staged-combustion engine thrust chamber. Such a test article simulates flow through the main injectors of oxygen/kerosene oxidizer-rich staged combustion engines such as the Russian RD-180 or NK-33 engines, or future U.S.-built engine systems such as the Aerojet-Rocketdyne AR-1 engine or the Hydrocarbon Boost program demonstration engine. For the thrust chamber assembly of the test article, several configurations of new main injectors, using relatively conventional gas-centered swirl coaxial injector elements, were designed and fabricated. The design and fabrication of these main injectors are described in a companion paper at this JANNAF meeting. New ablative combustion chambers were fabricated based on hardware previously used at NASA for testing at similar size and pressure. An existing oxygen/RP-1 oxidizer-rich subscale preburner injector from a previous NASA-funded program, along with existing and new inter-connecting hot gas duct hardware, were used to supply the oxidizer-rich combustion products to the oxidizer circuit of the main injector of the thrust chamber. Results from independent hot-fire tests of the preburner injector in a combustion chamber with a sonic throat are described in companion papers at this JANNAF conference. The resulting integrated test article - which includes the preburner, inter-connecting hot gas duct, main injector, and ablative combustion chamber - was assembled at Test Stand 116 at the East Test Area of the NASA Marshall Space Flight Center. The test article was well instrumented with static and dynamic pressure, temperature, and acceleration sensors to allow the collected data to be used for

Combustibles sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pebler, A.R.

1980-02-26

A gaseous mixture of oxygen and fuel (Combustibles) is supplied to first and second electrodes disposed on opposite surfaces of an oxygen ion conductive solid electrolyte member wherein the electrodes are composed of different materials each exhibiting a different catalytic action on the gaseous mixture at a given temperature. The difference in oxygen potentials established at the respective electrodes as a result of the dissimilar catalytic action produces oxygen ion conductivity in the solid electrolyte cell which produces an electrical signal the magnitude of which is indicative of the combustible present in the mixture, I.E., methane, hydrogen, carbon monoxide, etc.

Fabrication and processing of next-generation oxygen carrier materials for chemical looping combustion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nadarajah, Arunan

Among numerous methods of controlling the global warming effect, Chemical Looping Combustion is known to be the most viable option currently. A key factor to a successful chemical looping process is the presence of highly effective oxygen carriers that enable fuel combustion by going through oxidation and reduction in the presence of air and fuel respectively. In this study, CaMnO 3-δ was used as the base material and doped on the A-site (Sr or La) and B-site (Fe, Ti, Zn and Al) by 10 mol % of dopants. Solid state reaction followed by mechanical extrusion (optimized paste formula) was usedmore » as the preparation method A series of novel doped perovskite-type oxygen carrier particles (Ca xLa (Or Sa) 1-x Mn 1-yByO 3-δ (B-site = Fe, Ti, Al, or Zr)) were synthesized by the proposed extrusion formula. The produced samples were characterized with XRD, SEM, BET and TGA techniques. According to the results obtained from TGA analysis, the oxygen capacity of the samples ranged between 1.2 for CLMZ and 1.75 for CSMF. Reactivity and oxygen uncoupling behaviors of the prepared samples were also evaluated using a fluidized bed chemical looping reactor using methane as the fuel at four different temperatures (800, 850, 900, 950 °C). All of the oxygen carriers showed oxygen uncoupling behavior and they were able to capture and release oxygen. Mass-based conversion of the perovskites was calculated and temperature increase proved to increase the mass-based conversion rate in all of the samples under study. Gas yield was calculated at 950 °C as well, and results showed that CLMZ, CM and CSMF showed 100% gas yields and CLMF and CSMZ showed approximately 85% yield in fluidized bed reactor, which is a high and acceptable quantity. Based on extended reactor tests the modified calcium manganese perovskite structures (CSMF) can be a good candidate for future pilot tests.« less

High-pressure calorimeter chamber tests for liquid oxygen/kerosene (LOX/RP-1) rocket combustion

NASA Technical Reports Server (NTRS)

Masters, Philip A.; Armstrong, Elizabeth S.; Price, Harold G.

1988-01-01

An experimental program was conducted to investigate the rocket combustion and heat transfer characteristics of liquid oxygen/kerosene (LOX/RP-1) mixtures at high chamber pressures. Two water-cooled calorimeter chambers of different combustion lengths were tested using 37- and 61-element oxidizer-fuel-oxidizer triplet injectors. The tests were conducted at nominal chamber pressures of 4.1, 8.3, and 13.8 MPa abs (600, 1200, and 2000 psia). Heat flux Q/A data were obtained for the entire calorimeter length for oxygen/fuel mixture ratios of 1.8 to 3.3. Test data at 4.1 MPa abs compared favorably with previous test data from another source. Using an injector with a fuel-rich outer zone reduced the throat heat flux by 47 percent with only a 4.5 percent reduction in the characteristic exhaust velocity efficiency C* sub eff. The throat heat transfer coefficient was reduced approximately 40 percent because of carbon deposits on the chamber wall.

Dilute Oxygen Combustion Phase IV Final Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riley, M.F.

2003-04-30

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the costmore » of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space

Sooting Limits Of Diffusion Flames With Oxygen-Enriched Air And Diluted Fuel

NASA Technical Reports Server (NTRS)

Sunderland, P. B.; Urban, D. L.; Stocker, D. P.; Chao, B. H.; Axelbaum, R. L.

2003-01-01

Oxygen-enhanced combustion permits certain benefits and flexibility that are not otherwise available in the design of practical combustors, as discussed by Baukal. The cost of pure and enriched oxygen has declined to the point that oxygen-enhanced combustion is preferable to combustion in air for many applications. Carbon sequestration is greatly facilitated by oxygen enrichment because nitrogen can be eliminated from the product stream. For example, when natural gas (or natural gas diluted with CO2) is burned in pure oxygen, the only significant products are water and CO2. Oxygen-enhanced combustion also has important implications for soot formation, as explored in this work. We propose that soot inception in nonpremixed flames requires a region where C/O ratio, temperature, and residence time are above certain critical values. Soot does not form at low temperatures, with the threshold in nonpremixed flames ranging from about 1250-1650 K, a temperature referred to here as the critical temperature for soot inception, Tc. Soot inception also can be suppressed when residence time is short (equivalently, when the strain rate in counterflow flames is high). Soot induction times of 0.8-15 ms were reported by Tesner and Shurupov for acetylene/nitrogen mixtures at 1473 K. Burner stabilized spherical microgravity flames are employed in this work for two main reasons. First, this configuration offers unrestricted control over convection direction. Second, in steady state these flames are strain-free and thus can yield intrinsic sooting limits in diffusion flames, similar to the way past work in premixed flames has provided intrinsic values of C/O ratio associated with soot inception limits.

An investigation of co-combustion municipal sewage sludge with biomass in a 20kW BFB combustor under air-fired and oxygen-enriched condition.

PubMed

Kumar, Rajesh; Singh, Ravi Inder

2017-12-01

The behavior of municipal sewage sludge (MSS) with biomass (Guar stalks (GS), Mustard Husk (MH), Prosopis Juliflora Wood (PJW)) has been investigated in a 20kW bubbling fluidized bed (BFB) combustor under both air-fired (A-F) and oxygen-enriched (O-E) conditions. The work presented is divided into three parts, first part cover the thermogravimetric analysis (TGA), second part cover the experimental investigation of BFB combustor, and third part covers the ash analysis. TGA was performed with a ratio of 50%MSS/50%biomass (GS, MH, PJW) and results show that 50%MSS/50%GS has highest combustion characteristic factor (CCF). The experimental investigation of BFB combustor was performed for two different ratios of MSS/biomass (50%/50% and 25%/75%) and the combustion characteristics of blends were distinctive under both A-F and O-E condition. Despite 50%MSS/50%GS showing the highest combustion performance in TGA analysis, it formed agglomerates during burning in BFB. Due to this formation of large amount of agglomerates, de-fluidization was observed in the combustor bed after 65-75min in A-F conditions. The rate of de-fluidization increased under O-E condition. The de-fluidization problem disappeared when the share of MSS was reduced to 25%, but small amounts of the agglomerate were still present in the bed. With oxygen enhancement, the combustion efficiency of BFB combustor was improved and flue gasses were found within permissible limit. The maximum conceivable combustion efficiency (97.1%) for BFB combustor was accomplished by using 50% MSS/50%PJW under O-E condition. Results show that a ratio of 25%MSS/75%biomass combusted successfully inside the BFB combustor and extensive work is required for efficient utilization of significant share of MSS with biomass. SEM/EDS analyses were performed for agglomerate produced and for the damaged heater to study the surface morphology and compositions. The elemental heterogeneity of fly ash generated during MSS/biomass combustion

Carbon and oxygen isotopic composition of coal and carbon dioxide derived from laboratory coal combustion: A preliminary study

USGS Publications Warehouse

Warwick, Peter D.; Ruppert, Leslie F.

2016-01-01

The concentration of carbon dioxide (CO2) in the atmosphere has dramatically increased from the start of the industrial revolution in the mid-1700s to present levels exceeding 400 ppm. Carbon dioxide derived from fossil fuel combustion is a greenhouse gas and a major contributor to on-going climate change. Carbon and oxygen stable isotope geochemistry is a useful tool to help model and predict the contributions of anthropogenic sources of CO2 in the global carbon cycle. Surprisingly few studies have addressed the carbon and oxygen isotopic composition of CO2 derived from coal combustion. The goal of this study is to document the relationships between the carbon and oxygen isotope signatures of coal and signatures of the CO2 produced from laboratory coal combustion in atmospheric conditions.Six coal samples were selected that represent various geologic ages (Carboniferous to Tertiary) and coal ranks (lignite to bituminous). Duplicate splits of the six coal samples were ignited and partially combusted in the laboratory at atmospheric conditions. The resulting coal-combustion gases were collected and the molecular composition of the collected gases and isotopic analyses of δ13C of CO2, δ13C of CH4, and δ18O of CO2 were analysed by a commercial laboratory. Splits (~ 1 g) of the un-combusted dried ground coal samples were analyzed for δ13C and δ18O by the U.S. Geological Survey Reston Stable Isotope Laboratory.The major findings of this preliminary work indicate that the isotopic signatures of δ13C (relative to the Vienna Pee Dee Belemnite scale, VPDB) of CO2 resulting from coal combustion are similar to the δ13CVPDB signature of the bulk coal (− 28.46 to − 23.86 ‰) and are not similar to atmospheric δ13CVPDB of CO2 (~ − 8 ‰, see http://www.esrl.noaa.gov/gmd/outreach/isotopes/c13tellsus.html). The δ18O values of bulk coal are strongly correlated to the coal dry ash yields and appear to have little or no influence on the δ18O values of CO2

Unique phase identification of trimetallic copper iron manganese oxygen carrier using simultaneous differential scanning calorimetry/thermogravimetric analysis during chemical looping combustion reactions with methane

DOE PAGES

Benincosa, William; Siriwardane, Ranjani; Tian, Hanjing; ...

2017-07-05

Chemical looping combustion (CLC) is a promising combustion technology that generates heat and sequestration-ready carbon dioxide that is undiluted by nitrogen from the combustion of carbonaceous fuels with an oxygen carrier, or metal oxide. This process is highly dependent on the reactivity and stability of the oxygen carrier. The development of oxygen carriers remains one of the major barriers for commercialization of CLC. Synthetic oxygen carriers, consisting of multiple metal components, have demonstrated enhanced performance and improved CLC operation compared to single metal oxides. However, identification of the complex mixed metal oxide phases that form after calcination or during CLCmore » reactions has been challenging. Without an understanding of the dominant metal oxide phase, it is difficult to determine reaction parameters and the oxygen carrier reduction pathway, which are necessary for CLC reactor design. This is particularly challenging for complex multi-component oxygen carriers such as copper iron manganese oxide (CuFeMnO 4). This study aims to differentiate the unique phase formation of a highly reactive, complex trimetallic oxygen carrier, CuFeMnO 4, from its single and bimetallic counterparts using thermochemical and reaction data obtained from simultaneous differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) during temperature programmed reductions (TPR) with methane. DSC/TGA experiments during TPR with methane provides heat flow data and corresponding reaction rate data that can be used to determine reaction routes and mechanisms during methane reduction. Furthermore, non-isothermal TPR data provides the advantage of distinguishing reactions that may not be observable in isothermal analysis. The detailed thermochemical and reaction data, obtained during TPR with methane, distinguished a unique reduction pathway for CuFeMnO 4 that differed from its single and bimetallic counterparts. This is remarkable since X

Unique phase identification of trimetallic copper iron manganese oxygen carrier using simultaneous differential scanning calorimetry/thermogravimetric analysis during chemical looping combustion reactions with methane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benincosa, William; Siriwardane, Ranjani; Tian, Hanjing

Chemical looping combustion (CLC) is a promising combustion technology that generates heat and sequestration-ready carbon dioxide that is undiluted by nitrogen from the combustion of carbonaceous fuels with an oxygen carrier, or metal oxide. This process is highly dependent on the reactivity and stability of the oxygen carrier. The development of oxygen carriers remains one of the major barriers for commercialization of CLC. Synthetic oxygen carriers, consisting of multiple metal components, have demonstrated enhanced performance and improved CLC operation compared to single metal oxides. However, identification of the complex mixed metal oxide phases that form after calcination or during CLCmore » reactions has been challenging. Without an understanding of the dominant metal oxide phase, it is difficult to determine reaction parameters and the oxygen carrier reduction pathway, which are necessary for CLC reactor design. This is particularly challenging for complex multi-component oxygen carriers such as copper iron manganese oxide (CuFeMnO 4). This study aims to differentiate the unique phase formation of a highly reactive, complex trimetallic oxygen carrier, CuFeMnO 4, from its single and bimetallic counterparts using thermochemical and reaction data obtained from simultaneous differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) during temperature programmed reductions (TPR) with methane. DSC/TGA experiments during TPR with methane provides heat flow data and corresponding reaction rate data that can be used to determine reaction routes and mechanisms during methane reduction. Furthermore, non-isothermal TPR data provides the advantage of distinguishing reactions that may not be observable in isothermal analysis. The detailed thermochemical and reaction data, obtained during TPR with methane, distinguished a unique reduction pathway for CuFeMnO 4 that differed from its single and bimetallic counterparts. This is remarkable since X

Thermite combustion enhancement resulting from biomodal luminum distribution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moore, K. M.; Pantoya, M.; Son, S. F.

2004-01-01

In recent years many studies that incorporated nano-scale or ultrafine aluminum (Al) as part of an energetic formulation and demonstrated significant performance enhancement. Decreasing the fuel particle size from the micron to nanometer range alters the material's chemical and thermal-physical properties. The result is increased particle reactivity that translates to an increase in the combustion wave speed and ignition sensitivity. Little is known, however, about the critical level of nano-sized fuel particles needed to enhance the performance of the energetic composite. Ignition sensitivity and combustion wave speed experiments were performed using a thermite composite of Al and MoO{sub 3} pressedmore » to a theoretical maximum density of 50% (2 g/cm{sup 3}). A bimodal Al particle size distribution was prepared using 4 or 20 {mu}m Al fuel particles that were replaced in 10% increments by 80 nm Al particles until the fuel was 100% 80 nm Al. These bimodal distributions allow the unique characteristics of nano-scale materials to be better understood. The pellets were ignited using a 50W CO{sub 2} laser. High speed imaging diagnostics were used to measure the ignition delay time and combustion wave speed.« less

Analytical chemical kinetic investigation of the effects of oxygen, hydrogen, and hydroxyl radicals on hydrogen-air combustion

NASA Technical Reports Server (NTRS)

Carson, G. T., Jr.

1974-01-01

Quantitative values were computed which show the effects of the presence of small amounts of oxygen, hydrogen, and hydroxyl radicals on the finite-rate chemical kinetics of premixed hydrogen-air mixtures undergoing isobaric autoignition and combustion. The free radicals were considered to be initially present in hydrogen-air mixtures at equivalence ratios of 0.2, 0.6, 1.0, and 1.2. Initial mixture temperatures were 1100 K, 1200 K, and 1500 K, and pressures were 0.5, 1.0, 2.0, and 4.0 atm. Of the radicals investigated, atomic oxygen was found to be the most effective for reducing induction time, defined as the time to 5 percent of the total combustion temperature rise. The reaction time, the time between 5 percent and 95 percent of the temperature rise, is not decreased by the presence of free radicals in the initial hydrogen-air mixture. Fuel additives which yield free radicals might be used to effect a compact supersonic combustor design for efficient operation in an otherwise reaction-limited combustion regime.

Metal ferrite oxygen carriers for chemical looping combustion of solid fuels

DOEpatents

Siriwardane, Ranjani V.; Fan, Yueying

2017-01-31

The disclosure provides a metal ferrite oxygen carrier for the chemical looping combustion of solid carbonaceous fuels, such as coal, coke, coal and biomass char, and the like. The metal ferrite oxygen carrier comprises MFe.sub.xO.sub.y on an inert support, where MFe.sub.xO.sub.y is a chemical composition and M is one of Mg, Ca, Sr, Ba, Co, Mn, and combinations thereof. For example, MFe.sub.xO.sub.y may be one of MgFe.sub.2O.sub.4, CaFe.sub.2O.sub.4, SrFe.sub.2O.sub.4, BaFe.sub.2O.sub.4, CoFe.sub.2O.sub.4, MnFeO.sub.3, and combinations thereof. The MFe.sub.xO.sub.y is supported on an inert support. The inert support disperses the MFe.sub.xO.sub.y oxides to avoid agglomeration and improve performance stability. In an embodiment, the inert support comprises from about 5 wt. % to about 60 wt. % of the metal ferrite oxygen carrier and the MFe.sub.xO.sub.y comprises at least 30 wt. % of the metal ferrite oxygen carrier. The metal ferrite oxygen carriers disclosed display improved reduction rates over Fe.sub.2O.sub.3, and improved oxidation rates over CuO.

Identification of combustion intermediates in low-pressure premixed pyridine/oxygen/argon flames.

PubMed

Tian, Zhenyu; Li, Yuyang; Zhang, Taichang; Zhu, Aiguo; Qi, Fei

2008-12-25

Combustion intermediates of two low-pressure premixed pyridine/oxygen flames with respective equivalence ratios of 0.56 (C/O/N = 1:4.83:0.20) and 2.10 (C/O/N = 1:1.29:0.20) have been identified with tunable synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam mass spectrometry techniques. About 80 intermediates in the rich flame and 60 intermediates in the lean flame, including nitrogenous, oxygenated, and hydrocarbon intermediates, have been identified by measurements of photoionization mass spectra and photoionization efficiency spectra. Some radicals and new nitrogenous intermediates are identified in the present work. The experimental results are useful for studying the conversion of volatile nitrogen compounds and understanding the formation mechanism of NO(x) in flames of nitrogenous fuels.

Coating Hydrostatic Bearings To Resist Ignition In Oxygen

NASA Technical Reports Server (NTRS)

Funkhouser, Merle E.

1993-01-01

Coats of superalloy MA754 plasma-sprayed onto occasionally rubbing surfaces of hydrostatic journal bearings operating in liquid and/or gaseous oxygen, according to proposal. Prevents ignition and combustion occurring when components made of stainless steels or other conventional bearing alloys rub against each other in oxygen. Eliminates need for runner and enhances control over critical bearing clearance.

Fuel properties to enable lifted-flame combustion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kurtz, Eric

The Fuel Properties to Enable Lifted-Flame Combustion project responded directly to solicitation DE-FOA-0000239 AOI 1A, Fuels and Lubricants for Advanced Combustion Regimes. This subtopic was intended to encompass clean and highly-efficient, liquid-fueled combustion engines to achieve extremely low engine-out nitrogen oxides (NOx) and particulate matter (PM) as a target and similar efficiency as state-of-the-art direct injection diesel engines. The intent of this project was to identify how fuel properties can be used to achieve controllable Leaner Lifted Flame Combustion (LLFC) with low NOx and PM emissions. Specifically, this project was expected to identify and test key fuel properties to enablemore » LLFC and their compatibility with current fuel systems and to enhance combustion models to capture the effect of fuel properties on advanced combustion. Successful demonstration of LLFC may reduce the need for after treatment devices, thereby reducing costs and improving thermal efficiency. The project team consisted of key technical personnel from Ford Motor Company (FMC), the University of Wisconsin-Madison (UW), Sandia National Laboratories (SNL) and Lawrence Livermore National Laboratories (LLNL). Each partner had key roles in achieving project objectives. FMC investigated fuel properties relating to LLFC and sooting tendency. Together, FMC and UW developed and integrated 3D combustion models to capture fuel property combustion effects. FMC used these modeling results to develop a combustion system and define fuel properties to support a single-cylinder demonstration of fuel-enabled LLFC. UW investigated modeling the flame characteristics and emissions behavior of different fuels, including those with different cetane number and oxygen content. SNL led spray combustion experiments to quantify the effect of key fuel properties on combustion characteristics critical for LLFC, as well as single cylinder optical engine experiments to improve fundamental

Torrefaction of empty fruit bunches under biomass combustion gas atmosphere.

PubMed

Uemura, Yoshimitsu; Sellappah, Varsheta; Trinh, Thanh Hoai; Hassan, Suhaimi; Tanoue, Ken-Ichiro

2017-11-01

Torrefaction of oil palm empty fruit bunches (EFB) under combustion gas atmosphere was conducted in a batch reactor at 473, 523 and 573K in order to investigate the effect of real combustion gas on torrefaction behavior. The solid mass yield of torrefaction in combustion gas was smaller than that of torrefaction in nitrogen. This may be attributed to the decomposition enhancement effect by oxygen and carbon dioxide in combustion gas. Under combustion gas atmosphere, the solid yield for torrefaction of EFB became smaller as the temperature increased. The representative products of combustion gas torrefaction were carbon dioxide and carbon monoxide (gas phase) and water, phenol and acetic acid (liquid phase). By comparing torrefaction in combustion gas with torrefaction in nitrogen gas, it was found that combustion gas can be utilized as torrefaction gas to save energy and inert gas. Copyright © 2017 Elsevier Ltd. All rights reserved.

Effect of temperature on reduction of CaSO{sub 4} oxygen carrier in chemical-looping combustion of simulated coal gas in a fluidized bed reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Song, Q.L.; Xiao, R.; Deng, Z.Y.

2008-12-15

Chemical-looping combustion (CLC) is a promising combustion technology for gaseous and solid fuel with efficient use of energy and inherent separation of CO{sub 2}. The concept of a coal-fueled CLC system using, calcium sulfate (CaSO{sub 4}) as oxygen carrier is proposed in this study. Reduction tests of CaSO{sub 4} oxygen carrier with simulated coal gas were performed in a laboratory-scale fluidized bed reactor in the temperature range of 890-950{degree}C. A high concentration of CO{sub 2} was obtained at the initial reduction period. CaSO{sub 4} oxygen carrier exhibited high reactivity initially and decreased gradually at the late period of reduction. Themore » sulfur release during the reduction of CaSO{sub 4} as oxygen carrier was also observed and analyzed. H{sub 2} and CO{sub 2} conversions were greatly influenced by reduction temperature. The oxygen carrier conversion and mass-based reaction rates during the reduction at typical temperatures were compared. Higher temperatures would enhance reaction rates and result in high conversion of oxygen carrier. An XRD patterns study indicated that CaS was the dominant product of reduction and the variation of relative intensity with temperature is in agreement with the solid conversion. ESEM analysis indicated that the surface structure of oxygen carrier particles changed significantly from impervious to porous after reduction. EDS analysis also demonstrated the transfer of oxygen from the oxygen carrier to the fuel gas and a certain amount of sulfur loss and CaO formation on the surface at higher temperatures. The reduction kinetics of CaSO{sub 4} oxygen carrier was explored with the shrinking unreacted-core model. The apparent kinetic parameters were obtained, and the kinetic equation well predicted the experimental data. Finally, some basic considerations on the use of CaSO{sub 4} oxygen carrier in a CLC system for solid fuels were discussed.« less

Carbon monoxide and oxygen combustion experiments: A demonstration of Mars in situ propellants

NASA Technical Reports Server (NTRS)

Linne, Diane L.

1991-01-01

The feasibility of using carbon monoxide and oxygen as rocket propellants was examined both experimentally and theoretically. The steady-state combustion of carbon monoxide and oxygen was demonstrated for the first time in a subscale rocket engine. Measurements of experimental characteristic velocity, vacuum specific impulse, and thrust coefficient efficiency were obtained over a mixture ratio range of 0.30 to 2.0 and a chamber pressures of 1070 and 530 kPa. The theoretical performance of the propellant combination was studied parametrically over the same mixture ratio range. In addition to one dimensional ideal performance predictions, various performance reduction mechanisms were also modeled, including finite-rate kinetic reactions, two-dimensional divergence effects and viscous boundary layer effects.

LOX/Hydrocarbon Combustion Instability Investigation

NASA Technical Reports Server (NTRS)

Jensen, R. J.; Dodson, H. C.; Claflin, S. E.

1989-01-01

The LOX/Hydrocarbon Combustion Instability Investigation Program was structured to determine if the use of light hydrocarbon combustion fuels with liquid oxygen (LOX) produces combustion performance and stability behavior similar to the LOX/hydrogen propellant combination. In particular methane was investigated to determine if that fuel can be rated for combustion instability using the same techniques as previously used for LOX/hydrogen. These techniques included fuel temperature ramping and stability bomb tests. The hot fire program probed the combustion behavior of methane from ambient to subambient temperatures. Very interesting results were obtained from this program that have potential importance to future LOX/methane development programs. A very thorough and carefully reasoned documentation of the experimental data obtained is contained. The hot fire test logic and the associated tests are discussed. Subscale performance and stability rating testing was accomplished using 40,000 lb. thrust class hardware. Stability rating tests used both bombs and fuel temperature ramping techniques. The test program was successful in generating data for the evaluation of the methane stability characteristics relative to hydrogen and to anchor stability models. Data correlations, performance analysis, stability analyses, and key stability margin enhancement parameters are discussed.

Particulate Formation from a Copper Oxide-Based Oxygen Carrier in Chemical Looping Combustion for CO2 Capture

EPA Science Inventory

Attrition behavior and particle loss of a copper oxide-based oxygen carrier from a methane chemical looping combustion (CLC) process was investigated in a fluidized bed reactor. The aerodynamic diameters of most elutriated particulates, after passing through a horizontal settling...

Variable oxygen/nitrogen enriched intake air system for internal combustion engine applications

DOEpatents

Poola, Ramesh B.; Sekar, Ramanujam R.; Cole, Roger L.

1997-01-01

An air supply control system for selectively supplying ambient air, oxygen enriched air and nitrogen enriched air to an intake of an internal combustion engine includes an air mixing chamber that is in fluid communication with the air intake. At least a portion of the ambient air flowing to the mixing chamber is selectively diverted through a secondary path that includes a selectively permeable air separating membrane device due a differential pressure established across the air separating membrane. The permeable membrane device separates a portion of the nitrogen in the ambient air so that oxygen enriched air (permeate) and nitrogen enriched air (retentate) are produced. The oxygen enriched air and the nitrogen enriched air can be selectively supplied to the mixing chamber or expelled to atmosphere. Alternatively, a portion of the nitrogen enriched air can be supplied through another control valve to a monatomic-nitrogen plasma generator device so that atomic nitrogen produced from the nitrogen enriched air can be then injected into the exhaust of the engine. The oxygen enriched air or the nitrogen enriched air becomes mixed with the ambient air in the mixing chamber and then the mixed air is supplied to the intake of the engine. As a result, the air being supplied to the intake of the engine can be regulated with respect to the concentration of oxygen and/or nitrogen.

Design and Fabrication of Oxygen/RP-2 Multi-Element Oxidizer-Rich Staged Combustion Thrust Chamber Injectors

NASA Technical Reports Server (NTRS)

Garcia, C. P.; Medina, C. R.; Protz, C. S.; Kenny, R. J.; Kelly, G. W.; Casiano, M. J.; Hulka, J. R.; Richardson, B. R.

2016-01-01

As part of the Combustion Stability Tool Development project funded by the Air Force Space and Missile Systems Center, the NASA Marshall Space Flight Center was contracted to assemble and hot-fire test a multi-element integrated test article demonstrating combustion characteristics of an oxygen/hydrocarbon propellant oxidizer-rich staged-combustion engine thrust chamber. Such a test article simulates flow through the main injectors of oxygen/kerosene oxidizer-rich staged combustion engines such as the Russian RD-180 or NK-33 engines, or future U.S.-built engine systems such as the Aerojet-Rocketdyne AR-1 engine or the Hydrocarbon Boost program demonstration engine. On the current project, several configurations of new main injectors were considered for the thrust chamber assembly of the integrated test article. All the injector elements were of the gas-centered swirl coaxial type, similar to those used on the Russian oxidizer-rich staged-combustion rocket engines. In such elements, oxidizer-rich combustion products from the preburner/turbine exhaust flow through a straight tube, and fuel exiting from the combustion chamber and nozzle regenerative cooling circuits is injected near the exit of the oxidizer tube through tangentially oriented orifices that impart a swirl motion such that the fuel flows along the wall of the oxidizer tube in a thin film. In some elements there is an orifice at the inlet to the oxidizer tube, and in some elements there is a sleeve or "shield" inside the oxidizer tube where the fuel enters. In the current project, several variations of element geometries were created, including element size (i.e., number of elements or pattern density), the distance from the exit of the sleeve to the injector face, the width of the gap between the oxidizer tube inner wall and the outer wall of the sleeve, and excluding the sleeve entirely. This paper discusses the design rationale for each of these element variations, including hydraulic, structural

Beryllium particle combustion

NASA Technical Reports Server (NTRS)

Prentice, J. L.

1972-01-01

A two-year study of the combustion efficiency of single beryllium droplets burning in a variety of oxidizers (primarily mixtures of oxygen/argon and oxygen/nitrogen) is summarized. An advanced laser heating technique was used to acquire systematic quantitative data on the burning of single beryllium droplets at atmospheric pressure. The research confirmed the sensitivity of beryllium droplet combustion to the chemistry of environmental species and provides experimental documentation for the nitrogen-induced droplet fragmentation of burning beryllium droplets.

Combined O2/combustibles solid electrolyte gas monitoring device

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hickam, W.M.; Lin, C.; Zomp, J.M.

1980-11-04

A circuit means in combination with a conventional oxygen ion conductive solid electrolyte cell establishes the cell in a voltage mode for the purposes of measuring excess oxygen and developing a voltage signal indicative thereof, and switching the cell to a current mode of operation in response to an excess combustible environment wherein current drawn by the cell to pump oxygen for combustible reaction with the excess combustibles environment is measured as an indication of the combustibles content of the gas.

BIOLOGICALLY ENHANCED OXYGEN TRANSFER IN THE ACTIVATED SLUDGE PROCESS (JOURNAL)

EPA Science Inventory

Biologically enhanced oxgyen transfer has been a hypothesis to explain observed oxygen transfer rates in activated sludge systems that were well above that predicted from aerator clean-water testing. The enhanced oxygen transfer rates were based on tests using BOD bottle oxygen ...

Detailed Kinetic Mechanism of the Combustion of Homogeneous Gaseous Mixtures with Participation of Oxygen-containing Oxidants

NASA Astrophysics Data System (ADS)

Baevich, V. Ya

1987-05-01

The kinetic mechanisms of the oxidation and combustion of hydrogen, methane, methyl alcohol, acetylene, ethylene, ethane, and methylamine, using oxygen as well as hydrogen peroxide and nitric acid as oxidants, are discussed. The calculated and experimental data obtained under static conditions, in a flow, during flame propagation, and in shock tubes are compared. The bibliography includes 184 references.

Internal and surface phenomena in metal combustion

NASA Technical Reports Server (NTRS)

Dreizin, Edward L.; Molodetsky, Irina E.; Law, Chung K.

1995-01-01

Combustion of metals has been widely studied in the past, primarily because of their high oxidation enthalpies. A general understanding of metal combustion has been developed based on the recognition of the existence of both vapor-phase and surface reactions and involvement of the reaction products in the ensuing heterogeneous combustion. However, distinct features often observed in metal particle combustion, such as brightness oscillations and jumps (spearpoints), disruptive burning, and non-symmetric flames are not currently understood. Recent metal combustion experiments using uniform high-temperature metal droplets produced by a novel micro-arc technique have indicated that oxygen dissolves in the interior of burning particles of certain metals and that the subsequent transformations of the metal-oxygen solutions into stoichiometric oxides are accompanied with sufficient heat release to cause observed brightness and temperature jumps. Similar oxygen dissolution has been observed in recent experiments on bulk iron combustion but has not been associated with such dramatic effects. This research addresses heterogeneous metal droplet combustion, specifically focusing on oxygen penetration into the burning metal droplets, and its influence on the metal combustion rate, temperature history, and disruptive burning. A unique feature of the experimental approach is the combination of the microgravity environment with a novel micro-arc Generator of Monodispersed Metal Droplets (GEMMED), ensuring repeatable formation and ignition of uniform metal droplets with controllable initial temperature and velocity. The droplet initial temperatures can be adjusted within a wide range from just above the metal melting point, which provides means to ignite droplets instantly upon entering an oxygen containing environment. Initial droplet velocity will be set equal to zero allowing one to organize metal combustion microgravity experiments in a fashion similar to usual microgravity

Phase Transformations of Cobalt Oxides in CoxOy-ZnO Multipod Nanostructures via Combustion from Thermopower Waves.

PubMed

Lee, Kang Yeol; Hwang, Hayoung; Choi, Wonjoon

2015-09-01

The study of combustion at the interfaces of materials and chemical fuels has led to developments in diverse fields such as materials chemistry and energy conversion. Recently, it has been suggested that thermopower waves can utilize chemical-thermal-electrical-energy conversion in hybrid structures comprising nanomaterials and combustible fuels to produce enhanced combustion waves with concomitant voltage generation. In this study, this is the first time that the direct phase transformation of Co-doped ZnO via instant combustion waves and its applications to thermopower waves is presented. It is demonstrated that the chemical combustion waves at the surfaces of Co3O4-ZnO multipod nanostructures (deep brown in color) enable direct phase transformations to newly formed CoO-ZnO(1-x) nanoparticles (olive green in color). The oxygen molecules are released from Co3O4-ZnO to CoO-ZnO(1-x) under high-temperature conditions in the reaction front regime in combustion, whereas the CoO-ZnO multipod nanoparticles do not undergo any transformations and thus do not experience any color change. This oxygen-release mechanism is applicable to thermopower waves, enhances the self-propagating combustion velocity, and forms lattice defects that interrupt the charge-carrier movements inside the nanostructures. The chemical transformation and corresponding energy transport observed in this study can contribute to diverse potential applications, including direct-combustion synthesis and energy conversion. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Plasma torch for ignition, flameholding and enhancement of combustion in high speed flows

NASA Technical Reports Server (NTRS)

O'Brien, Walter F. (Inventor); Billingsley, Matthew C. (Inventor); Sanders, Darius D. (Inventor); Schetz, Joseph A. (Inventor)

2009-01-01

Preheating of fuel and injection into a plasma torch plume fro adjacent the plasma torch plume provides for only ignition with reduced delay but improved fuel-air mixing and fuel atomization as well as combustion reaction enhancement. Heat exchange also reduced erosion of the anode of the plasma torch. Fuel mixing atomization, fuel mixture distribution enhancement and combustion reaction enhancement are improved by unsteady plasma torch energization, integral formation of the heat exchanger, fuel injection nozzle and plasma torch anode in a more compact, low-profile arrangement which is not intrusive on a highspeed air flow with which the invention is particularly effective and further enhanced by use of nitrogen as a feedstock material and inclusion of high pressure gases in the fuel to cause effervescence during injection.

The oxycoal process with cryogenic oxygen supply.

PubMed

Kather, Alfons; Scheffknecht, Günter

2009-09-01

ash or the deposits that form. In particular, detailed nitrogen and sulphur chemistry was investigated by combustion tests in a laboratory-scale facility. Oxidant staging, in order to reduce NO formation, turned out to work with similar effectiveness as for conventional air combustion. With regard to sulphur, a considerable increase in the SO2 concentration was found, as expected. However, the H2S concentration in the combustion atmosphere increased as well. Further results were achieved with a pilot-scale test facility, where acid dew points were measured and deposition probes were exposed to the combustion environment. Besides CO2 and water vapour, the flue gas contains impurities like sulphur species, nitrogen oxides, argon, nitrogen, and oxygen. The CO2 liquefaction is strongly affected by these impurities in terms of the auxiliary power requirement and the CO2 capture rate. Furthermore, the impurity of the liquefied CO2 is affected as well. Since the requirements on the liquid CO2 with regard to geological storage or enhanced oil recovery are currently undefined, the effects of possible flue gas treatment and the design of the liquefaction plant are studied over a wide range.

The oxycoal process with cryogenic oxygen supply

NASA Astrophysics Data System (ADS)

Kather, Alfons; Scheffknecht, Günter

2009-09-01

ash or the deposits that form. In particular, detailed nitrogen and sulphur chemistry was investigated by combustion tests in a laboratory-scale facility. Oxidant staging, in order to reduce NO formation, turned out to work with similar effectiveness as for conventional air combustion. With regard to sulphur, a considerable increase in the SO2 concentration was found, as expected. However, the H2S concentration in the combustion atmosphere increased as well. Further results were achieved with a pilot-scale test facility, where acid dew points were measured and deposition probes were exposed to the combustion environment. Besides CO2 and water vapour, the flue gas contains impurities like sulphur species, nitrogen oxides, argon, nitrogen, and oxygen. The CO2 liquefaction is strongly affected by these impurities in terms of the auxiliary power requirement and the CO2 capture rate. Furthermore, the impurity of the liquefied CO2 is affected as well. Since the requirements on the liquid CO2 with regard to geological storage or enhanced oil recovery are currently undefined, the effects of possible flue gas treatment and the design of the liquefaction plant are studied over a wide range.

Oxy-fuel combustion with integrated pollution control

DOEpatents

Patrick, Brian R [Chicago, IL; Ochs, Thomas Lilburn [Albany, OR; Summers, Cathy Ann [Albany, OR; Oryshchyn, Danylo B [Philomath, OR; Turner, Paul Chandler [Independence, OR

2012-01-03

An oxygen fueled integrated pollutant removal and combustion system includes a combustion system and an integrated pollutant removal system. The combustion system includes a furnace having at least one burner that is configured to substantially prevent the introduction of air. An oxygen supply supplies oxygen at a predetermine purity greater than 21 percent and a carbon based fuel supply supplies a carbon based fuel. Oxygen and fuel are fed into the furnace in controlled proportion to each other and combustion is controlled to produce a flame temperature in excess of 3000 degrees F. and a flue gas stream containing CO2 and other gases. The flue gas stream is substantially void of non-fuel borne nitrogen containing combustion produced gaseous compounds. The integrated pollutant removal system includes at least one direct contact heat exchanger for bringing the flue gas into intimated contact with a cooling liquid to produce a pollutant-laden liquid stream and a stripped flue gas stream and at least one compressor for receiving and compressing the stripped flue gas stream.

On-line measurement of heat of combustion

NASA Technical Reports Server (NTRS)

Chaturvedi, S. K.; Chegini, H.

1988-01-01

An experimental method for an on-line measurement of heat of combustion of a gaseous hydrocarbon fuel mixture of unknown composition is developed. It involves combustion of a test gas with a known quantity of air to achieve a predetermined oxygen concentration level in the combustion products. This is accomplished by a feedback controller which maintains the gas volumetric flow rate at a level consistent with the desired oxygen concentration in the products. The heat of combustion is determined from a known correlation with the gas volumetric flow rate. An on-line microcomputer accesses the gas volumetric flow data, and displays the heat of combustion values at desired time intervals.

TECHNOLOGY DEMONSTRATION SUMMARY: THE AMERICAN COMBUSTION PYRETRON THERMAL DESTRUCTION SYSTEM AT THE U.S. EPA'S COMBUSTION FACILITY

EPA Science Inventory

The American Combustion Pyretron Thermal Destruction System at the U.S. EPA's Combustion Research Facility. Under the auspices of the Superfund Innovative Technology Evaluation, or SITE, program, a critical assessment was made of the American Combustion Pyretron™ oxygen enha...

Enhanced oxygen storage capacity of cation-ordered cerium-zirconium oxide induced by titanium substitution.

PubMed

Goto, Yoshihiro; Morikawa, Akira; Iwasaki, Masaoki; Miura, Masahide; Tanabe, Toshitaka

2018-04-03

Herein, we report on the synthesis of Ce0.5Zr0.5-xTixO2 oxygen storage materials prepared via a solution combustion method. Ce0.5Zr0.4Ti0.1O2 showed an outstanding oxygen storage capacity (1310 μmol-O per g) at 200 °C compared to conventional κ-Ce2Zr2O8 (650 μmol-O per g) due to its cation ordering and the formation of weakly bound oxygen atoms induced by Ti substitution.

Pyrolysis reactor and fluidized bed combustion chamber

DOEpatents

Green, Norman W.

1981-01-06

A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.

Method and device for determining heats of combustion of gaseous hydrocarbons

NASA Technical Reports Server (NTRS)

Singh, Jag J. (Inventor); Sprinkle, Danny R. (Inventor); Puster, Richard L. (Inventor)

1988-01-01

A method and device is provided for a quick, accurate and on-line determination of heats of combustion of gaseous hydrocarbons. First, the amount of oxygen in the carrier air stream is sensed by an oxygen sensing system. Second, three individual volumetric flow rates of oxygen, carrier stream air, and hydrocrabon test gas are introduced into a burner. The hydrocarbon test gas is fed into the burner at a volumetric flow rate, n, measured by a flowmeter. Third, the amount of oxygen in the resulting combustion products is sensed by an oxygen sensing system. Fourth, the volumetric flow rate of oxygen is adjusted until the amount of oxygen in the combustion product equals the amount of oxygen previously sensed in the carrier air stream. This equalizing volumetric flow rate is m and is measured by a flowmeter. The heat of combustion of the hydrocrabon test gas is then determined from the ratio m/n.

Ames Hybrid Combustion Facility

NASA Technical Reports Server (NTRS)

Zilliac, Greg; Karabeyoglu, Mustafa A.; Cantwell, Brian; Hunt, Rusty; DeZilwa, Shane; Shoffstall, Mike; Soderman, Paul T.; Bencze, Daniel P. (Technical Monitor)

2003-01-01

The report summarizes the design, fabrication, safety features, environmental impact, and operation of the Ames Hybrid-Fuel Combustion Facility (HCF). The facility is used in conducting research into the scalability and combustion processes of advanced paraffin-based hybrid fuels for the purpose of assessing their applicability to practical rocket systems. The facility was designed to deliver gaseous oxygen at rates between 0.5 and 16.0 kg/sec to a combustion chamber operating at pressures ranging from 300 to 900. The required run times were of the order of 10 to 20 sec. The facility proved to be robust and reliable and has been used to generate a database of regression-rate measurements of paraffin at oxygen mass flux levels comparable to those of moderate-sized hybrid rocket motors.

Low Oxygen Tension Enhances Hepatitis C Virus Replication

PubMed Central

Kalliampakou, K. I.; Kotta-Loizou, I.; Befani, C.; Liakos, P.; Simos, G.; Mentis, A. F.; Kalliaropoulos, A.; Doumba, P. P.; Smirlis, D.; Foka, P.; Bauhofer, O.; Poenisch, M.; Windisch, M. P.; Lee, M. E.; Koskinas, J.; Bartenschlager, R.

2013-01-01

Low oxygen tension exerts a significant effect on the replication of several DNA and RNA viruses in cultured cells. In vitro propagation of hepatitis C virus (HCV) has thus far been studied under atmospheric oxygen levels despite the fact that the liver tissue microenvironment is hypoxic. In this study, we investigated the efficiency of HCV production in actively dividing or differentiating human hepatoma cells cultured under low or atmospheric oxygen tensions. By using both HCV replicons and infection-based assays, low oxygen was found to enhance HCV RNA replication whereas virus entry and RNA translation were not affected. Hypoxia signaling pathway-focused DNA microarray and real-time quantitative reverse transcription-PCR (qRT-PCR) analyses revealed an upregulation of genes related to hypoxic stress, glycolytic metabolism, cell growth, and proliferation when cells were kept under low (3% [vol/vol]) oxygen tension, likely reflecting cell adaptation to anaerobic conditions. Interestingly, hypoxia-mediated enhancement of HCV replication correlated directly with the increase in anaerobic glycolysis and creatine kinase B (CKB) activity that leads to elevated ATP production. Surprisingly, activation of hypoxia-inducible factor alpha (HIF-α) was not involved in the elevation of HCV replication. Instead, a number of oncogenes known to be associated with glycolysis were upregulated and evidence that these oncogenes contribute to hypoxia-mediated enhancement of HCV replication was obtained. Finally, in liver biopsy specimens of HCV-infected patients, the levels of hypoxia and anaerobic metabolism markers correlated with HCV RNA levels. These results provide new insights into the impact of oxygen tension on the intricate HCV-host cell interaction. PMID:23269812

Carbon deposition model for oxygen-hydrocarbon combustion, volume 1

NASA Technical Reports Server (NTRS)

Hernandez, R.; Ito, J. I.; Niiya, K. Y.

1987-01-01

Presented are details of the design, fabrication, and testing of subscale hardware used in the evaluation of carbon deposition characteristics of liquid oxygen and three hydrocarbon fuels for both main chamber and preburner/gas generator operating conditions. In main chamber conditions, the deposition of carbon on the combustion chamber wall was investigated at mixture ratios of 2.0 to 4.0 and at pressures of 1000 to 1500 psia. No carbon deposition on the chamber walls was detected at these main chamber mixture ratios. In preburner/gas generator operating conditions, the deposition of carbon on the turbine simulator tubes was evaluated at mixture ratios of 0.20 to 0.60 and at chamber pressures of 720 to 1650 psia. The results of the tests showed carbon deposition rate to be a strong function of mixture ratio and a weak function of chamber pressure. Further analyses evaluated the operational consequences of carbon deposition on preburner/gas generator performance. The report is in two volumes, of which this is Volume 1 covering the main body of the report plus Appendixes A through D.

Carbon Deposition Model for Oxygen-Hydrocarbon Combustion, Volume 2

NASA Technical Reports Server (NTRS)

Hernandez, R.; Ito, J. I.; Niiya, K. Y.

1987-01-01

Presented are details of the design, fabrication, and testing of subscale hardware used in the evaluation of carbon deposition characteristics of liquid oxygen and three hydrocarbon fuels for both main chamber and preburner/gas generator operating conditions. In main chamber conditions, the deposition of carbon on the combustion chamber wall was investigated at mixture ratios of 2.0 to 4.0 and at chamber pressures of 1000 to 1500 psia. No carbon deposition on chamber walls was detected at these main chamber mixture ratios. In preburner/gas generator operating conditions, the deposition of carbon on the turbine simulator tubes was evaluated at mixture ratios of 0.20 to 0.60 and at chamber pressures of 720 to 1650 psia. The results of the tests showed carbon deposition rate to be a strong function of mixture ratio and a weak function of chamber pressure. Further analyses evaluated the operational concequences of carbon deposition on preburner/gas generator performance. This is Volume 2 of the report, which contains data plots of all the test programs.

Effect of Structural Parameters on the Combustion Performance of Platelet Engines

NASA Astrophysics Data System (ADS)

Liang, Yin; Liu, Weiqiang

2017-12-01

Numerical simulation was adopted to determine its flow and combustion characteristics by using gaseous methane and oxygen as the main propellants, the effects of nozzle space and expanding angle are examined for the single element splash platelet injector. Navier-Stokes (N-S) equations were solved for the gas-gas flow field with a reduced mechanism involving 9 species and 1 reaction. Results indicated that large corner recirculation zones are produced in the combustor head. This phenomenon consequently enhances mixing and stabilizes combustion, but non-uniformity in temperature contour is observed in the combustor head. Recirculation zone decreases as nozzle space increases, which induces the decrease of maximum temperature and high temperature regions, but it has little influence on the combustion efficiency and combustion length. The combustion length and maximum temperature decrease initially and then increase as expanding angle increases. Conversely, a D value of 2.4 mm and γ value of 60° are selected for the future works because of the shortest combustion length and minimum temperature of the injector faceplate.

Reduced No.sub.x combustion method

DOEpatents

Delano, Mark A.

1991-01-01

A combustion method enabling reduced NO.sub.x formation wherein fuel and oxidant are separately injected into a combustion zone in a defined velocity relation, combustion gases are aspirated into the oxidant stream prior to intermixture with the fuel, and the fuel is maintained free from contact with oxygen until the intermixture.

Enhanced Combustion Low NOx Pulverized Coal Burner

DOE Office of Scientific and Technical Information (OSTI.GOV)

David Towle; Richard Donais; Todd Hellewell

2007-06-30

For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, withmore » typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for

In-water gas combustion for thrust production

NASA Astrophysics Data System (ADS)

Teslenko, V. S.; Drozhzhin, A. P.; Medvedev, R. N.

2017-07-01

The paper presents the results of experimental study for hydrodynamic processes occurring during combustion of a stoichiometric mixture propane-oxygen in combustion chambers with different configurations and submerged into water. The pulses of force acting upon a thrust wall were measured for different geometries: cylindrical, conic, hemispherical, including the case of gas combustion near a flat thrust wall. After a single charge of stoichiometric mixture propane-oxygen is burnt near the thrust wall, the process of cyclic generation of force pulses develops. The first pulse is generated due to pressure growth during gas combustion, and the following pulses are the result of hydrodynamic pulsations of the gaseous cavity. Experiments demonstrated that efficient generation of thrust occurs if all bubble pulsations are used during combustion of a single gas combustion. In the series of experiments, the specific impulse on the thrust wall was in the range 104-105 s (105-106 m/s) with account for positive and negative components of impulse.

Combustion Processes in the Aerospace Environment

NASA Technical Reports Server (NTRS)

Huggett, Clayton

1969-01-01

The aerospace environment introduces new and enhanced fire hazards because the special atmosphere employed may increase the frequency and intensity of fires, because the confinement associated with aerospace systems adversely affects the dynamics of fire development and control, and because the hostile external environments limit fire control and rescue operations. Oxygen enriched atmospheres contribute to the fire hazard in aerospace systems by extending the list of combustible fuels, increasing the probability of ignition, and increasing the rates of fire spread and energy release. A system for classifying atmospheres according to the degree of fire hazard, based on the heat capacity of the atmosphere per mole of oxygen, is suggested. A brief exploration of the dynamics of chamber fires shows that such fires will exhibit an exponential growth rate and may grow to dangerous size in a very short time. Relatively small quantities of fuel and oxygen can produce a catastrophic fire in a closed chamber.

Catalytic Effect of Pd Clusters in the Poly( N-vinyl-2-pyrrolidone) Combustion

NASA Astrophysics Data System (ADS)

Schiavo, L.; De Nicola, S.; Carotenuto, G.

2018-01-01

Pd(0) is able to catalyze oxygen-involving reactions because of its capability to convert molecular oxygen to the very reactive atomic form. Consequently, the embedding of a little amount of Pd(0) clusters in polymeric phases can be technologically exploited to enhance the incineration kinetic of these polymers. The effect of nanostructuration on the Pd(0) catalytic activity in the polymer incineration reaction has been studied using poly( N-vinyl-2-pyrrolidone) ( \\overline{Mw} = 10,000 gmol-1) as polymeric model system. A change in the PVP incineration kinetic mechanism with significant increase in the reaction rate was experimentally found. The kinetic of the Pd(0)-catalyzed combustion has been studied by isothermal thermogravimetric analysis. After a short induction time, the combustion in presence of Pd(0) clusters shifted to a zero-order kinetic from a second-order kinetic control, which is operative in pure PVP combustion reaction. In addition, the activation energy resulted much lowered compared to the pure PVP incineration case (from 300 to 260 kJ/mol).

Erythropoiesis-stimulating agents and other methods to enhance oxygen transport

PubMed Central

Elliott, S

2008-01-01

Oxygen is essential for life, and the body has developed an exquisite method to collect oxygen in the lungs and transport it to the tissues. Hb contained within red blood cells (RBCs), is the key oxygen-carrying component in blood, and levels of RBCs are tightly controlled according to demand for oxygen. The availability of oxygen plays a critical role in athletic performance, and agents that enhance oxygen delivery to tissues increase aerobic power. Early methods to increase oxygen delivery included training at altitude, and later, transfusion of packed RBCs. A breakthrough in understanding how RBC formation is controlled included the discovery of erythropoietin (Epo) and cloning of the EPO gene. Cloning of the EPO gene was followed by commercial development of recombinant human Epo (rHuEpo). Legitimate use of this and other agents that affect oxygen delivery is important in the treatment of anaemia (low Hb levels) in patients with chronic kidney disease or in cancer patients with chemotherapy-induced anaemia. However, competitive sports was affected by illicit use of rHuEpo to enhance performance. Testing methods for these agents resulted in a cat-and-mouse game, with testing labs attempting to detect the use of a drug or blood product to improve athletic performance (doping) and certain athletes developing methods to use the agents without being detected. This article examines the current methods to enhance aerobic performance and the methods to detect illicit use. PMID:18362898

Waste plastics as supplemental fuel in the blast furnace process: improving combustion efficiencies.

PubMed

Kim, Dongsu; Shin, Sunghye; Sohn, Seungman; Choi, Jinshik; Ban, Bongchan

2002-10-14

The possibility of using waste plastics as a source of secondary fuel in a blast furnace has been of recent interest. The success of this process, however, will be critically dependent upon the optimization of operating systems. For instance, the supply of waste plastics must be reliable as well as economically attractive compared with conventional secondary fuels such as heavy oil, natural gas and pulverized coal. In this work, we put special importance on the improvement of the combustibility of waste plastics as a way to enhance energy efficiency in a blast furnace. As experimental variables to approach this target, the effects of plastic particle size, blast temperature, and the level of oxygen enrichment were investigated using a custom-made blast model designed to simulate a real furnace. Lastly, the combustion efficiency of the mixture of waste plastics and pulverized coal was tested. The observations made from these experiments led us to the conclusion that with the increase of both blast temperature and the level of oxygen enrichment, and with a decrease in particle size, the combustibility of waste polyethylene could be improved at a given distance from the tuyere. Also it was found that the efficiency of coal combustion decreased with the addition of plastics; however, the combustion efficiency of mixture could be comparable at a longer distance from the tuyere.

Hyperbaric Oxygen Environment Can Enhance Brain Activity and Multitasking Performance

PubMed Central

Vadas, Dor; Kalichman, Leonid; Hadanny, Amir; Efrati, Shai

2017-01-01

Background: The Brain uses 20% of the total oxygen supply consumed by the entire body. Even though, <10% of the brain is active at any given time, it utilizes almost all the oxygen delivered. In order to perform complex tasks or more than one task (multitasking), the oxygen supply is shifted from one brain region to another, via blood perfusion modulation. The aim of the present study was to evaluate whether a hyperbaric oxygen (HBO) environment, with increased oxygen supply to the brain, will enhance the performance of complex and/or multiple activities. Methods: A prospective, double-blind randomized control, crossover trial including 22 healthy volunteers. Participants were asked to perform a cognitive task, a motor task and a simultaneous cognitive-motor task (multitasking). Participants were randomized to perform the tasks in two environments: (a) normobaric air (1 ATA 21% oxygen) (b) HBO (2 ATA 100% oxygen). Two weeks later participants were crossed to the alternative environment. Blinding of the normobaric environment was achieved in the same chamber with masks on while hyperbaric sensation was simulated by increasing pressure in the first minute and gradually decreasing to normobaric environment prior to tasks performance. Results: Compared to the performance at normobaric conditions, both cognitive and motor single tasks scores were significantly enhanced by HBO environment (p < 0.001 for both). Multitasking performance was also significantly enhanced in HBO environment (p = 0.006 for the cognitive part and p = 0.02 for the motor part). Conclusions: The improvement in performance of both single and multi-tasking while in an HBO environment supports the hypothesis which according to, oxygen is indeed a rate limiting factor for brain activity. Hyperbaric oxygenation can serve as an environment for brain performance. Further studies are needed to evaluate the optimal oxygen levels for maximal brain performance. PMID:29021747

Hyperbaric Oxygen Environment Can Enhance Brain Activity and Multitasking Performance.

PubMed

Vadas, Dor; Kalichman, Leonid; Hadanny, Amir; Efrati, Shai

2017-01-01

Background: The Brain uses 20% of the total oxygen supply consumed by the entire body. Even though, <10% of the brain is active at any given time, it utilizes almost all the oxygen delivered. In order to perform complex tasks or more than one task (multitasking), the oxygen supply is shifted from one brain region to another, via blood perfusion modulation. The aim of the present study was to evaluate whether a hyperbaric oxygen (HBO) environment, with increased oxygen supply to the brain, will enhance the performance of complex and/or multiple activities. Methods: A prospective, double-blind randomized control, crossover trial including 22 healthy volunteers. Participants were asked to perform a cognitive task, a motor task and a simultaneous cognitive-motor task (multitasking). Participants were randomized to perform the tasks in two environments: (a) normobaric air (1 ATA 21% oxygen) (b) HBO (2 ATA 100% oxygen). Two weeks later participants were crossed to the alternative environment. Blinding of the normobaric environment was achieved in the same chamber with masks on while hyperbaric sensation was simulated by increasing pressure in the first minute and gradually decreasing to normobaric environment prior to tasks performance. Results: Compared to the performance at normobaric conditions, both cognitive and motor single tasks scores were significantly enhanced by HBO environment ( p < 0.001 for both). Multitasking performance was also significantly enhanced in HBO environment ( p = 0.006 for the cognitive part and p = 0.02 for the motor part). Conclusions: The improvement in performance of both single and multi-tasking while in an HBO environment supports the hypothesis which according to, oxygen is indeed a rate limiting factor for brain activity. Hyperbaric oxygenation can serve as an environment for brain performance. Further studies are needed to evaluate the optimal oxygen levels for maximal brain performance.

Ignition delays, heats of combustion, and reaction rates of aluminum alkyl derivatives used as ignition and combustion enhancers for supersonic combustors

NASA Technical Reports Server (NTRS)

Ryan, T. W., III; Harlowe, W. W.; Schwab, S.

1992-01-01

The work was based on adapting an apparatus and procedure developed at Southwest Research Institute for rating the ignition quality of fuels for diesel engines. Aluminum alkyls and various Lewis-base adducts of these materials, both neat and mixed 50/50 with pure JP-10 hydrocarbon, were injected into the combustion bomb using a high-pressure injection system. The bomb was pre-charged with air that was set at various initial temperatures and pressures for constant oxygen density. The ignition delay times were determined for the test materials at these different initial conditions. The data are presented in absolute terms as well as comparisons with the parent alkyls. The relative heats of reaction of the various test materials were estimated based on a computation of the heat release, using the pressure data recorded during combustion in the bomb. In addition, the global reaction rates for each material were compared at a selected tmperature and pressure.

Improvement of AD Biosynthesis Response to Enhanced Oxygen Transfer by Oxygen Vectors in Mycobacterium neoaurum TCCC 11979.

PubMed

Su, Liqiu; Shen, Yanbing; Gao, Tian; Luo, Jianmei; Wang, Min

2017-08-01

In steroid biotransformation, soybean oil can improve the productivity of steroids by increasing substrate solubility and strengthen the cell membrane permeability. However, little is known of its role as oxygen carrier and its mechanism of promoting the steroid biotransformation. In this work, soybean oil used as oxygen vector for the enhancement of androst-4-ene-3,17-dione (AD) production by Mycobacterium neoaurum TCCC 11979 (MNR) was investigated. Upon the addition of 16% (v/v) soybean oil, the volumetric oxygen transfer coefficient (K L a) value increased by 44%, and the peak molar yield of AD (55.76%) was achieved. Analysis of intracellular cofactor levels showed high NAD + , ATP level, and a low NADH/NAD + ratio. Meanwhile, the two key enzymes of the tricarboxylic acid (TCA) cycle, namely, isocitrate dehydrogenase and α-ketoglutarate dehydrogenase, were upregulated after incubation with soybean oil. These enhancements induced by the increasing of oxygen supply showed positive effects on phytosterol (PS) bioconversion. Results could contribute to the understanding of effects of soybean oil as oxygen vector on steroid biotransformation and provided a convenient method for enhancing the efficiency of aerobic steroid biocatalysis.

Tripropellant combustion process

NASA Technical Reports Server (NTRS)

Kmiec, T. D.; Carroll, R. G.

1988-01-01

The addition of small amounts of hydrogen to the combustion of LOX/hydrocarbon propellants in large rocket booster engines has the potential to enhance the system stability. Programs being conducted to evaluate the effects of hydrogen on the combustion of LOX/hydrocarbon propellants at supercritical pressures are described. Combustion instability has been a problem during the development of large hydrocarbon fueled rocket engines. At the higher combustion chamber pressures expected for the next generation of booster engines, the effect of unstable combustion could be even more destructive. The tripropellant engine cycle takes advantage of the superior cooling characteristics of hydrogen to cool the combustion chamber and a small amount of the hydrogen coolant can be used in the combustion process to enhance the system stability. Three aspects of work that will be accomplished to evaluate tripropellant combustion are described. The first is laboratory demonstration of the benefits through the evaluation of drop size, ignition delay and burning rate. The second is analytical modeling of the combustion process using the empirical relationship determined in the laboratory. The third is a subscale demonstration in which the system stability will be evaluated. The approach for each aspect is described and the analytical models that will be used are presented.

Emissions of Parent, Nitro, and Oxygenated Polycyclic Aromatic Hydrocarbons from Residential Wood Combustion in Rural China

PubMed Central

SHEN, Guofeng; TAO, Shu; WEI, Siye; ZHANG, Yanyan; WANG, Rong; WANG, Bin; LI, Wei; SHEN, Huizhong; HUANG, Ye; CHEN, Yuanchen; CHEN, Han; YANG, Yifeng; WANG, Wei; WANG, Xilong; LIU, Wenxin; SIMONICH, Staci L. M.

2012-01-01

Residential wood combustion is one of the important sources of air pollution in developing countries. Among the pollutants emitted, parent polycyclic aromatic hydrocarbons (pPAHs) and their derivatives, including nitrated and oxygenated PAHs (nPAHs and oPAHs), are of concern because of their mutagenic and carcinogenic effects. In order to evaluate their impacts on regional air quality and human health, emission inventories, based on realistic emission factors (EFs), are needed. In this study, the EFs of 28 pPAHs (EFPAH28), 9 nPAHs (EFPAHn9) and 4 oPAHs (EFPAHo4) were measured for residential combustion of 27 wood fuels in rural China. The measured EFPAH28, EFPAHn9, and EFPAHo4 for brushwood were 86.7±67.6, 3.22±1.95×10−2, and 5.56±4.32 mg/kg, which were significantly higher than 12.7±7.0, 8.27±5.51×10−3, and 1.19±1.87 mg/kg for fuel wood combustion (p < 0.05). Sixteen U.S. EPA priority pPAHs contributed approximately 95% of the total of the 28 pPAHs measured. EFs of pPAHs, nPAHs, and oPAHs were positively correlated with one another. Measured EFs varied obviously depending on fuel properties and combustion conditions. The EFs of pPAHs, nPAHs, and oPAHs were significantly correlated with modified combustion efficiency and fuel moisture. Nitro-naphthalene and 9-fluorenone were the most abundant nPAHs and oPAHs identified. Both nPAHs and oPAHs showed relatively high tendencies to be present in the particulate phase than pPAHs due to their lower vapor pressures. The gas-particle partitioning of freshly emitted pPAHs, nPAHs and oPAHs was primarily controlled by organic carbon absorption. PMID:22765266

Neutrophil Leukocyte: Combustive Microbicidal Action and Chemiluminescence

PubMed Central

Allen, Robert C.

2015-01-01

Neutrophil leukocytes protect against a varied and complex array of microbes by providing microbicidal action that is simple, potent, and focused. Neutrophils provide such action via redox reactions that change the frontier orbitals of oxygen (O2) facilitating combustion. The spin conservation rules define the symmetry barrier that prevents direct reaction of diradical O2 with nonradical molecules, explaining why combustion is not spontaneous. In burning, the spin barrier is overcome when energy causes homolytic bond cleavage producing radicals capable of reacting with diradical O2 to yield oxygenated radical products that further participate in reactive propagation. Neutrophil mediated combustion is by a different pathway. Changing the spin quantum state of O2 removes the symmetry restriction to reaction. Electronically excited singlet molecular oxygen (1O2 *) is a potent electrophilic reactant with a finite lifetime that restricts its radius of reactivity and focuses combustive action on the target microbe. The resulting exergonic dioxygenation reactions produce electronically excited carbonyls that relax by light emission, that is, chemiluminescence. This overview of neutrophil combustive microbicidal action takes the perspectives of spin conservation and bosonic-fermionic frontier orbital considerations. The necessary principles of particle physics and quantum mechanics are developed and integrated into a fundamental explanation of neutrophil microbicidal metabolism. PMID:26783542

A simplified method for determining heat of combustion of natural gas

NASA Technical Reports Server (NTRS)

Singh, Jag J.; Chegini, Hoshang; Mall, Gerald H.

1987-01-01

A simplified technique for determination of the heat of combustion of natural gas has been developed. It is a variation of the previously developed technique wherein the carrier air, in which the test sample was burnt, was oxygen enriched to adjust the mole fraction of oxygen in the combustion product gases up to that in the carrier air. The new technique eliminates the need for oxygen enrichment of the experimental mixtures and natural gas samples and has been found to predict their heats of combustion to an uncertainty of the order of 1 percent.

Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pan, Wei-Ping; Cao, Yan

2012-11-30

Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked reactions are the oxidation of oxygen carriers in the air reactor using air, and the reduction of oxygen carriers in the fuel reactor using fuels (i.e. coal). Generally metal/metal oxides are used as oxygen carriers and operated in a cyclic mode. Chemical looping combustion significantly improves the energy conversion efficiency, in terms of the electricity generation, because it improvesmore » the reversibility of the fuel combustion process through two linked parallel processes, compared to the conventional combustion process, which is operated far away from its thermo-equilibrium. Under the current carbon-constraint environment, it has been a promising carbon capture technology in terms of fuel combustion for power generation. Its disadvantage is that it is less mature in terms of technological commercialization. In this DOE-funded project, accomplishment is made by developing a series of advanced copper-based oxygen carriers, with properties of the higher oxygen-transfer capability, a favorable thermodynamics to generate high purity of CO{sub 2}, the higher reactivity, the attrition-resistance, the thermal stability in red-ox cycles and the achievement of the auto-thermal heat balance. This will be achieved into three phases in three consecutive years. The selected oxygen carriers with final-determined formula were tested in a scaled-up 10kW coal-fueled chemical looping combustion facility. This scaled-up evaluation tests (2-day, 8-hour per day) indicated that, there was no tendency of agglomeration of copper-based oxygen carriers. Only trace-amount of coke or carbon deposits on the copper-based oxygen carriers in the fuel reactor. There was also no evidence to show the sulphidization of

National Combustion Code Parallel Performance Enhancements

NASA Technical Reports Server (NTRS)

Quealy, Angela; Benyo, Theresa (Technical Monitor)

2002-01-01

The National Combustion Code (NCC) is being developed by an industry-government team for the design and analysis of combustion systems. The unstructured grid, reacting flow code uses a distributed memory, message passing model for its parallel implementation. The focus of the present effort has been to improve the performance of the NCC code to meet combustor designer requirements for model accuracy and analysis turnaround time. Improving the performance of this code contributes significantly to the overall reduction in time and cost of the combustor design cycle. This report describes recent parallel processing modifications to NCC that have improved the parallel scalability of the code, enabling a two hour turnaround for a 1.3 million element fully reacting combustion simulation on an SGI Origin 2000.

Oxy Coal Combustion at the US EPA

EPA Science Inventory

Oxygen enriched coal (oxy-coal) combustion is a developing, and potentially a strategically key technology intended to accommodate direct CO2 recovery and sequestration. Oxy-coal combustion is also intended for retrofit application to existing power plants. During oxy-coal comb...

Combustion characteristics and air pollutant formation during oxy-fuel co-combustion of microalgae and lignite.

PubMed

Gao, Yuan; Tahmasebi, Arash; Dou, Jinxiao; Yu, Jianglong

2016-05-01

Oxy-fuel combustion of solid fuels is seen as one of the key technologies for carbon capture to reduce greenhouse gas emissions. The combustion characteristics of lignite coal, Chlorella vulgaris microalgae, and their blends under O2/N2 and O2/CO2 conditions were studied using a Thermogravimetric Analyzer-Mass Spectroscopy (TG-MS). During co-combustion of blends, three distinct peaks were observed and were attributed to C. vulgaris volatiles combustion, combustion of lignite, and combustion of microalgae char. Activation energy during combustion was calculated using iso-conventional method. Increasing the microalgae content in the blend resulted in an increase in activation energy for the blends combustion. The emissions of S- and N-species during blend fuel combustion were also investigated. The addition of microalgae to lignite during air combustion resulted in lower CO2, CO, and NO2 yields but enhanced NO, COS, and SO2 formation. During oxy-fuel co-combustion, the addition of microalgae to lignite enhanced the formation of gaseous species. Copyright © 2016 Elsevier Ltd. All rights reserved.

Enhanced efficiency of internal combustion engines by employing spinning gas.

PubMed

Geyko, V I; Fisch, N J

2014-08-01

The efficiency of the internal combustion engine might be enhanced by employing spinning gas. A gas spinning at near sonic velocities has an effectively higher heat capacity, which allows practical fuel cycles, which are far from the Carnot efficiency, to approach more closely the Carnot efficiency. A remarkable gain in fuel efficiency is shown to be theoretically possible for the Otto and Diesel cycles. The use of a flywheel, in principle, could produce even greater increases in efficiency.

Promoted Combustion Test Data Re-Examined

NASA Technical Reports Server (NTRS)

Lewis, Michelle; Jeffers, Nathan; Stoltzfus, Joel

2010-01-01

Promoted combustion testing of metallic materials has been performed by NASA since the mid-1980s to determine the burn resistance of materials in oxygen-enriched environments. As the technolo gy has advanced, the method of interpreting, presenting, and applying the promoted combustion data has advanced as well. Recently NASA changed the bum criterion from 15 cm (6 in.) to 3 cm (1.2 in.). This new burn criterion was adopted for ASTM G 124, Standard Test Method for Determining the Combustion Behavior- of Metallic Materials in Oxygen-Enriched Atmospheres. Its effect on the test data and the latest method to display the test data will be discussed. Two specific examples that illustrate how this new criterion affects the burn/no-bum thresholds of metal alloys will also be presented.

The oxygen sensitivity/compatibility ranking of several materials by different test methods

NASA Technical Reports Server (NTRS)

Lockhart, Billy J.; Bryan, Coleman J.; Hampton, Michael D.

1989-01-01

Eleven materials were evaluated for oxygen compatibility using the following test methods: heat of combustion (ASTM D 2015), liquid oxygen impact (ASTM D 2512), pneumatic impact (ASTM G 74), gaseous mechanical impact (ASTM G 86), autogenous ignition temperature by pressurized differential scanning calorimeter, and the determination of the 50 percent reaction level in liquid oxygen using silicon carbide as a reaction enhancer. The eleven materials evaluated were: Teflon TFE, Vespel SP-21, Krytox 240AC, Viton PLV5010B, Fluorel E2160, Kel F 81, Fluorogold, Fluorogreen E-600, Rulon A, Garlock 8573, nylon 6/6.

21 CFR 173.350 - Combustion product gas.

Code of Federal Regulations, 2011 CFR

2011-04-01

... FOR HUMAN CONSUMPTION (CONTINUED) SECONDARY DIRECT FOOD ADDITIVES PERMITTED IN FOOD FOR HUMAN CONSUMPTION Specific Usage Additives § 173.350 Combustion product gas. The food additive combustion product... this section for the purpose of removing and displacing oxygen in accordance with the following...

21 CFR 173.350 - Combustion product gas.

Code of Federal Regulations, 2012 CFR

2012-04-01

... FOR HUMAN CONSUMPTION (CONTINUED) SECONDARY DIRECT FOOD ADDITIVES PERMITTED IN FOOD FOR HUMAN CONSUMPTION Specific Usage Additives § 173.350 Combustion product gas. The food additive combustion product... this section for the purpose of removing and displacing oxygen in accordance with the following...

21 CFR 173.350 - Combustion product gas.

Code of Federal Regulations, 2013 CFR

2013-04-01

... FOR HUMAN CONSUMPTION (CONTINUED) SECONDARY DIRECT FOOD ADDITIVES PERMITTED IN FOOD FOR HUMAN CONSUMPTION Specific Usage Additives § 173.350 Combustion product gas. The food additive combustion product... this section for the purpose of removing and displacing oxygen in accordance with the following...

21 CFR 173.350 - Combustion product gas.

Code of Federal Regulations, 2010 CFR

2010-04-01

... FOR HUMAN CONSUMPTION (CONTINUED) SECONDARY DIRECT FOOD ADDITIVES PERMITTED IN FOOD FOR HUMAN CONSUMPTION Specific Usage Additives § 173.350 Combustion product gas. The food additive combustion product... this section for the purpose of removing and displacing oxygen in accordance with the following...

One-step solution combustion synthesis of pure Ni nanopowders with enhanced coercivity: The fuel effect

NASA Astrophysics Data System (ADS)

Khort, Alexander; Podbolotov, Kirill; Serrano-García, Raquel; Gun'ko, Yurii K.

2017-09-01

In this paper, we report a new modified one-step combustion synthesis technique for production of Ni metal nanoparticles. The main unique feature of our approach is the use of microwave assisted foam preparation. Also, the effect of different types of fuels (urea, citric acid, glycine and hexamethylenetetramine) on the combustion process and characteristics of resultant solid products were investigated. It is observed that the combination of microwave assisted foam preparation and using of hexamethylenetetramine as a fuel allows producing pure ferromagnetic Ni metal nanoparticles with enhanced coercivity (78 Oe) and high value of saturation magnetization (52 emu/g) by one-step solution combustion synthesis under normal air atmosphere without any post-reduction processing.

Radiation/Catalytic Augmented Combustion.

DTIC Science & Technology

1984-05-01

interest to compare the experimental results for the solid bluff body with a thuoretical result. Using simple argtinieiiLs from fluid mechanics " one...responsibility through completion. Dr. A. E. Cerkanowlcz assisted in writing this final report. Experimental studies on catalytic augmented combustion...as well as with other combustion species, lead to ignition and sustained combustion via chain reactions. Simple combustion enhancement without

Highly Efficient Oxygen-Storage Material with Intrinsic Coke Resistance for Chemical Looping Combustion-Based CO2 Capture.

PubMed

Imtiaz, Qasim; Kurlov, Alexey; Rupp, Jennifer Lilia Marguerite; Müller, Christoph Rüdiger

2015-06-22

Chemical looping combustion (CLC) and chemical looping with oxygen uncoupling (CLOU) are emerging thermochemical CO2 capture cycles that allow the capture of CO2 with a small energy penalty. Here, the development of suitable oxygen carrier materials is a key aspect to transfer these promising concepts to practical installations. CuO is an attractive material for CLC and CLOU because of its high oxygen-storage capacity (20 wt %), fast reaction kinetics, and high equilibrium partial pressure of oxygen at typical operating temperatures (850-1000 °C). However, despite its promising characteristics, its low Tammann temperature requires the development of new strategies to phase-stabilize CuO-based oxygen carriers. In this work, we report a strategy based on stabilization by co-precipitated ceria (CeO2-x ), which allowed us to increase the oxygen capacity, coke resistance, and redox stability of CuO-based oxygen carriers substantially. The performance of the new oxygen carriers was evaluated in detail and compared to the current state-of-the-art materials, that is, Al2 O3 -stabilized CuO with similar CuO loadings. We also demonstrate that the higher intrinsic oxygen uptake, release, and mobility in CeO2-x -stabilized CuO leads to a three times higher carbon deposition resistance compared to that of Al2 O3 -stabilized CuO. Moreover, we report a high cyclic stability without phase intermixing for CeO2-x -supported CuO. This was accompanied by a lower reduction temperature compared to state-of-the-art Al2 O3 -supported CuO. As a result of its high resistance towards carbon deposition and fast oxygen uncoupling kinetics, CeO2-x -stabilized CuO is identified as a very promising material for CLC- and CLOU-based CO2 capture architectures. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hybrid membrane--PSA system for separating oxygen from air

DOEpatents

Staiger, Chad L [Albuquerque, NM; Vaughn, Mark R [Albuquerque, NM; Miller, A Keith [Albuquerque, NM; Cornelius, Christopher J [Blackburg, VA

2011-01-25

A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

Predictive Evaluations of Oxygen-Rich Hydrocarbon Combustion Gas-Centered Swirl Coaxial Injectors using a Flamelet-Based 3-D CFD Simulation Approach

NASA Technical Reports Server (NTRS)

Richardson, Brian R.; Braman, Kalem; West, Jeff

2016-01-01

NASA Marshall Space Flight Center (MSFC) has embarked upon a joint project with the Air Force to improve the state-of-the-art of space application combustion device design and operational understanding. One goal of the project is to design, build and hot-fire test a 40,000 pound-thrust Oxygen/Rocket Propellant-2 (RP-2) Oxygen-Rich staged engine at MSFC. The overall project goals afford the opportunity to test multiple different injector designs and experimentally evaluate the any effect on the engine performance and combustion dynamics. To maximize the available test resources and benefits, pre-test, combusting flow, Computational Fluid Dynamics (CFD) analysis was performed on the individual injectors to guide the design. The results of the CFD analysis were used to design the injectors for specific, targeted fluid dynamic features and the analysis results also provided some predictive input for acoustic and thermal analysis of the main Thrust Chamber Assembly (TCA). MSFC has developed and demonstrated the ability to utilize a computationally efficient, flamelet-based combustion model to guide the pre-test design of single-element Gas Centered Swirl Coaxial (GCSC) injectors. Previous, Oxygen/RP-2 simulation models utilizing the Loci-STREAM flow solver, were validated using single injector test data from the EC-1 Air Force test facility. The simulation effort herein is an extension of the validated, CFD driven, single-injector design approach applied to single injectors which will be part of a larger engine array. Time-accurate, Three-Dimensional, CFD simulations were performed for five different classes of injector geometries. Simulations were performed to guide the design of the injector to achieve a variety of intended performance goals. For example, two GCSC injectors were designed to achieve stable hydrodynamic behavior of the propellant circuits while providing the largest thermal margin possible within the design envelope. While another injector was designed

Enhanced Efficiency of Internal Combustion Engines By Employing Spinning Gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Geyko, Vasily; Fisch, Nathaniel

2014-02-27

The efficiency of the internal combustion engine might be enhanced by employing spinning gas. A gas spinning at near sonic velocities has an effectively higher heat capacity, which allows practical fuel cycles, which are far from the Carnot efficiency, to approach more closely the Carnot efficiency. A gain in fuel efficiency of several percent is shown to be theoretically possible for the Otto and Diesel cycles. The use of a flywheel, in principle, could produce even greater increases in the efficiency.

Thermal Model of the Promoted Combustion Test

NASA Technical Reports Server (NTRS)

Jones, Peter D.

1996-01-01

Flammability of metals in high pressure, pure oxygen environments, such as rocket engine turbopumps, is commonly evaluated using the Promoted Combustion Test (PCT). The PCT emphasizes the ability of an ignited material to sustain combustion, as opposed to evaluating the sample's propensity to ignite in the first place. A common arrangement is a rod of the sample material hanging in a chamber in which a high pressure, pure oxygen environment is maintained. An igniter of some energetically combusting material is fixed to the bottom of the rod and fired. This initiates combustion, and the sample burns and melts at its bottom tip. A ball of molten material forms, and this ball detaches when it grows too large to be supported by surface tension with the rod. In materials which do not sustain combustion, the combustion then extinguishes. In materials which do sustain combustion, combustion re-initiates from molten residue left on the bottom of the rod, and the melt ball burns and grows until it detaches again. The purpose of this work is development of a PCT thermal simulation model, detailing phase change, melt detachment, and the several heat transfer modes. Combustion is modeled by a summary rate equation, whose parameters are identified by comparison to PCT results. The sensitivity of PCT results to various physical and geometrical parameters is evaluated. The identified combustion parameters may be used in design of new PCT arrangements, as might be used for flammability assessment in flow-dominated environments. The Haynes 214 nickel-based superalloy, whose PCT results are applied here, burns heterogeneously (fuel and oxidizer are of different phases; combustion takes place on the fuel surface). Heterogeneous combustion is not well understood. (In homogeneous combustion, the metal vaporizes, and combustion takes place in an analytically treatable cloud above the surface). Thermal modeling in heterogeneous combustion settings provides a means for linking test

Combustion synthesis of complex oxides

NASA Astrophysics Data System (ADS)

Ming, Qimin

Advanced ceramic materials have numerous applications in electronic engineering, chemical engineering, and semiconductor industry. The synthesis of these materials at an economical cost is the bottleneck in the application of these materials. Self-propagating High-temperature Synthesis (SHS) is a new technique for producing these materials for exothermic systems by a combustion wave that propagates and produces high purity products. The full potential of SHS to produce advanced materials has not yet been utilized. In this study, we used SHS to prepare two types of complex oxides: La 1-xSrxCrO3, La0.89Sr0.1 MnO3, powders, used to make interconnect and cathode of solid oxide fuel cells; and chromium- and gallium-doped La1-xSr xFeO3-delta, mixed ionic and electronic conductive powders used to manufacture ceramic membranes for oxygen separation. A thermodynamic feasibility analysis shows that the oxidation of Cr is the main source of heat generation of La1-xSrxCrO 3, which maintains a stable reaction front. Replacing part of the metallic Cr in the reaction mixture by its oxides decreases the combustion temperature and front propagating velocity and modifies the product morphology. The oxygen needed for the Cr oxidation is provided by the decomposition of CrO3 , SrO2, or NaClO4. The predicted and observed combustion temperatures are in reasonable agreement. TG/DTA analyses of La1-xSrxCrO3 indicated that SHS stability was strongly affected by the transport of oxygen between the two regions, in which oxygen was generated by the decomposition of either NaClO4 or CrO3 and that in which it was consumed by the oxidation of Cr. Partial melting at the high combustion temperature during SHS of La 1-xSrxMnO3 increased product homogeneity. The electrical conductivity at 1000°C in air of SHS-produced cathode material (of 180 O-1·cm-1) matches that of the commercial product made by other processes. However, the SHS process provides much higher productivity and decreases processing

Experimental investigation of a solid rocket combustion simulator

NASA Technical Reports Server (NTRS)

Frederick, Robert A., Jr.

1991-01-01

The response of solid rocket motor materials to high-temperature corrosive gases is usually accomplished by testing the materials in a subscale solid rocket motor. While this imposes the proper thermal and chemical environment, a solid rocket motor does not provide practical features that would enhance systematic evaluations such as: the ability to throttle for margin testing, on/off capability, low test cost, and a low-hazards test article. Solid Rocket Combustion Simulators (SRCS) are being evaluated by NASA to test solid rocket nozzle materials and incorporate these essential practical features into the testing of rocket materials. The SRCS is designed to generate the thermochemical environment of a solid rocket. It uses hybrid rocket motor technology in which gaseous oxygen (Gox) is injected into a chamber containing a solid fuel grain. Specific chemicals are injected in the aft mixing chamber so that the gases entering the test section match the temperature and a non-dimensional erosion factor B' to insure similarity with a solid motor. Because the oxygen flow can be controlled, this approach allows margin testing, the ability to throttle, and an on/off capability. The fuel grains are inert which makes the test article very safe to handle. The objective of this work was to establish the baseline operating characteristics of a Labscale Solid Rocket Combustion Simulator (LSRCS). This included establishing the baseline burning rates of plexiglass fuels and the evaluation of a combustion instability for hydroxy-terminated polybutadyene (HTPB) propellants. The scope of the project included: (1) activation of MSFC Labscale Hybrid Combustion Simulator; (2) testing of plexiglass fuel at Gox ranges from 0.025 to 0.200 lb/s; (3) burning HTPB fuels at a Gox rate of 0.200 lb/s using four different mixing chamber configurations; and (4) evaluating the fuel regression and chamber pressure responses of each firing.

National Combustion Code Used To Study the Hydrogen Injector Design for Gas Turbines

NASA Technical Reports Server (NTRS)

Iannetti, Anthony C.; Norris, Andrew T.; Shih, Tsan-Hsing

2005-01-01

Hydrogen, in the gas state, has been proposed to replace Jet-A (the fuel used for commercial jet engines) as a fuel for gas turbine combustion. For the combustion of hydrogen and oxygen only, water is the only product and the main greenhouse gas, carbon dioxide, is not produced. This is an obvious benefit of using hydrogen as a fuel. The situation is not as simple when air replaces oxygen in the combustion process. (Air is mainly a mixture of oxygen, nitrogen, and argon. Other components comprise a very small part of air and will not be mentioned.) At the high temperatures found in the combustion process, oxygen reacts with nitrogen, and this produces nitrogen oxide compounds, or NOx--the main component of atmospheric smog. The production of NOx depends mainly on two variables: the temperature at which combustion occurs, and the length of time that the products of combustion stay, or reside, in the combustor. Starting from a lean (excess air) air-to-fuel ratio, the goal of this research was to minimize hot zones caused by incomplete premixing and to keep the residence time short while producing a stable flame. The minimization of these two parameters will result in low- NOx hydrogen combustion.

Distributed combustion in a cyclonic burner

NASA Astrophysics Data System (ADS)

Sorrentino, Giancarlo; Sabia, Pino; de Joannon, Mara; Cavaliere, Antonio; Ragucci, Raffaele

2017-11-01

Distributed combustion regime occurs in several combustion technologies were efficient and environmentally cleaner energy conversion are primary tasks. For such technologies (MILD, LTC, etc…), working temperatures are enough low to boost the formation of several classes of pollutants, such as NOx and soot. To access this temperature range, a significant dilution as well as preheating of reactants is required. Such conditions are usually achieved by a strong recirculation of exhaust gases that simultaneously dilute and pre-heat the fresh reactants. However, the intersection of low combustion temperatures and highly diluted mixtures with intense pre-heating alters the evolution of the combustion process with respect to traditional flames, leading to significant features such as uniformity and distributed ignition. The present study numerically characterized the turbulence-chemistry and combustion regimes of propane/oxygen mixtures, highly diluted in nitrogen, at atmospheric pressure, in a cyclonic combustor under MILD Combustion operating conditions. The velocity and mixing fields were obtained using CFD with focus on mean and fluctuating quantities. The flow-field information helped differentiate between the impact of turbulence levels and dilution ones. The integral length scale along with the fluctuating velocity is critical to determine Damköhler and Karlovitz numbers. Together these numbers identify the combustion regime at which the combustor is operating. This information clearly distinguishes between conventional flames and distributed combustion. The results revealed that major controllers of the reaction regime are dilution and mixing levels; both are significantly impacted by lowering oxygen concentration through entrainment of hot reactive species from within the combustor, which is important in distributed combustion. Understanding the controlling factors of distributed regime is critical for the development and deployment of these novel combustion

On-Line Measurement of Heat of Combustion of Gaseous Hydrocarbon Fuel Mixtures

NASA Technical Reports Server (NTRS)

Sprinkle, Danny R.; Chaturvedi, Sushil K.; Kheireddine, Ali

1996-01-01

A method for the on-line measurement of the heat of combustion of gaseous hydrocarbon fuel mixtures has been developed and tested. The method involves combustion of a test gas with a measured quantity of air to achieve a preset concentration of oxygen in the combustion products. This method involves using a controller which maintains the fuel (gas) volumetric flow rate at a level consistent with the desired oxygen concentration in the combustion products. The heat of combustion is determined form a known correlation with the fuel flow rate. An on-line computer accesses the fuel flow data and displays the heat of combustion measurement at desired time intervals. This technique appears to be especially applicable for measuring heats of combustion of hydrocarbon mixtures of unknown composition such as natural gas.

Determination of fluorine, chlorine and bromine in household products by means of oxygen bomb combustion and ion chromatography.

PubMed

Zhang, Shuai; Zhao, Tianbo; Wang, Jia; Qu, Xiaoling; Chen, Wei; Han, Yin

2013-01-01

A method for routine determination of fluorine, chlorine and bromine in household products was developed and validated. In this work, halogen analyses were made based on oxygen bomb combustion followed by ion chromatography (IC). The chromatographic analysis was performed by an IonPac AS19 hydroxide-selective anion-exchange column, a reagent free ion chromatograph eluent generator and an anion self-regenerating suppressor in 10 min. The response was linear (r ≥ 0.9995) in the entire investigated domain. The limit of detection for the halogens was in the range of 2 to 9 × 10(-3) mg/L and the limit of quantification was lower than 8 mg/Kg with 20 µL of injection volume. The certified reference material of ERM-EC 681k was pretreated using an oxygen bomb combustion procedure to demonstrate the precision of the proposed method. The quantitative analysis results obtained by IC for the target elements were 797 ± 9 mg/Kg chlorine and 786 ± 25 mg/Kg bromine, which were in good agreement with the certified values of 800 ± 4 mg/Kg chlorine, 770 ± 5 mg/Kg bromine for ERM-EC 681k, respectively. This validated method was successfully applied for the analysis of fluorine, chlorine and bromine in household product samples, and the variation of halogen contained among the tested samples was remarkable.

Enhancing perovskite electrocatalysis through strain tuning of oxygen deficiency

DOE PAGES

Barron, Sara C.; Lee, Ho Nyung; Petrie, Jonathan R.; ...

2016-05-27

Oxygen vacancies in transition-metal oxides facilitate catalysis critical for energy storage and generation. However, promoting vacancies at the lower temperatures required for operation in devices such as metal–air batteries and portable fuel cells has proven elusive. Here we used thin films of perovskite-based strontium cobaltite (SrCoO x) to show that epitaxial strain is a powerful tool for manipulating the oxygen content under conditions consistent with the oxygen evolution reaction, yielding increasingly oxygen-deficient states in an environment where the cobaltite would normally be fully oxidized. The additional oxygen vacancies created through tensile strain enhance the cobaltite’s catalytic activity toward this importantmore » reaction by over an order of magnitude, equaling that of precious-metal catalysts, including IrO2. Lastly, our findings demonstrate that strain in these oxides can dictate the oxygen stoichiometry independent of ambient conditions, allowing unprecedented control over oxygen vacancies essential in catalysis near room temperature.« less

Water Vapor Adsorption on Biomass Based Carbons under Post-Combustion CO2 Capture Conditions: Effect of Post-Treatment

PubMed Central

Querejeta, Nausika; Plaza, Marta G.; Rubiera, Fernando; Pevida, Covadonga

2016-01-01

The effect of post-treatment upon the H2O adsorption performance of biomass-based carbons was studied under post-combustion CO2 capture conditions. Oxygen surface functionalities were partially replaced through heat treatment, acid washing, and wet impregnation with amines. The surface chemistry of the final carbon is strongly affected by the type of post-treatment: acid treatment introduces a greater amount of oxygen whereas it is substantially reduced after thermal treatment. The porous texture of the carbons is also influenced by post-treatment: the wider pore volume is somewhat reduced, while narrow microporosity remains unaltered only after acid treatment. Despite heat treatment leading to a reduction in the number of oxygen surface groups, water vapor adsorption was enhanced in the higher pressure range. On the other hand acid treatment and wet impregnation with amines reduce the total water vapor uptake thus being more suitable for post-combustion CO2 capture applications. PMID:28773488

Effect of diluted and preheated oxidizer on the emission of methane flameless combustion

NASA Astrophysics Data System (ADS)

Hosseini, Seyed Ehsan; Salehirad, Saber; Wahid, M. A.; Sies, Mohsin Mohd; Saat, Aminuddin

2012-06-01

In combustion process, reduction of emissions often accompanies with output efficiency reduction. It means, by using current combustion technique it is difficult to obtainlow pollution and high level of efficiency in the same time. In new combustion system, low NOxengines and burners are studied particularly. Recently flameless or Moderate and Intensive Low oxygen Dilution (MILD) combustion has received special attention in terms of low harmful emissions and low energy consumption. Behavior of combustion with highly preheated air was analyzed to study the change of combustion regime and the reason for the compatibility of high performance and low NOx production. Sustainability of combustion under low oxygen concentration was examined when; the combustion air temperature was above the self-ignition temperature of the fuel. This paper purposes to analyze the NOx emission quantity in conventional combustion and flameless combustion by Chemical Equilibrium with Applications (CEA) software.

Physics and chemistry of the influence of excited molecules on combustion enhancement

PubMed Central

Starik, A. M.; Loukhovitski, B. I.; Sharipov, A. S.; Titova, N. S

2015-01-01

The paper addresses detailed analysis of kinetic processes in the H2−O2, CO−O2 and CH4−O2-reactive systems upon the presence of singlet oxygen molecules O2(a1Δg) and and the influence of the activation of oxygen molecules in electric discharge on the acceleration of ignition in the H2−O2 and CH4−O2 mixtures. The possibility of the intensification of CO oxidation due to excitation of O2 and N2 molecule vibrations and generation of singlet oxygen molecules is also considered. It is shown that the effect of accelerating the ignition strongly depends on the reduced electric field and, as a consequence, on the composition of discharge plasma as well as on the features of chain mechanism development in oxy-fuel systems. It is revealed that the most effective approach for the intensification of CO oxidation both in the moist air and in the products of hydrocarbon combustion in air is the generation of O2(a1Δg) molecules by electric discharge. Computations showed that the presence of 1% O2(a1Δg) in the total oxygen allowed one to convert CO to CO2 even at the temperature T=850–900 K in the time of 10−2 s. The excitation of O2 and N2 molecule vibrations is less effective for such a conversion. PMID:26170425

Low oxygen tension enhances endothelial fate of human pluripotent stem cells.

PubMed

Kusuma, Sravanti; Peijnenburg, Elizabeth; Patel, Parth; Gerecht, Sharon

2014-04-01

A critical regulator of the developing or regenerating vasculature is low oxygen tension. Precise elucidation of the role of low oxygen environments on endothelial commitment from human pluripotent stem cells necessitates controlled in vitro differentiation environments. We used a feeder-free, 2-dimensional differentiation system in which we could monitor accurately dissolved oxygen levels during human pluripotent stem cell differentiation toward early vascular cells (EVCs). We found that oxygen uptake rate of differentiating human pluripotent stem cells is lower in 5% O2 compared with atmospheric conditions. EVCs differentiated in 5% O2 had an increased vascular endothelial cadherin expression with clusters of vascular endothelial cadherin+ cells surrounded by platelet-derived growth factor β+ cells. When we assessed the temporal effects of low oxygen differentiation environments, we determined that low oxygen environments during the early stages of EVC differentiation enhance endothelial lineage commitment. EVCs differentiated in 5% O2 exhibited an increased expression of vascular endothelial cadherin and CD31 along with their localization to the membrane, enhanced lectin binding and acetylated low-density lipoprotein uptake, rapid cord-like structure formation, and increased expression of arterial endothelial cell markers. Inhibition of reactive oxygen species generation during the early stages of differentiation abrogated the endothelial inductive effects of the low oxygen environments. Low oxygen tension during early stages of EVC derivation induces endothelial commitment and maturation through the accumulation of reactive oxygen species, highlighting the importance of regulating oxygen tensions during human pluripotent stem cell-vascular differentiation.

Density functional theory study the effects of oxygen-containing functional groups on oxygen molecules and oxygen atoms adsorbed on carbonaceous materials.

PubMed

Qi, Xuejun; Song, Wenwu; Shi, Jianwei

2017-01-01

Density functional theory was used to study the effects of different types of oxygen-containing functional groups on the adsorption of oxygen molecules and single active oxygen atoms on carbonaceous materials. During gasification or combustion reactions of carbonaceous materials, oxygen-containing functional groups such as hydroxyl(-OH), carbonyl(-CO), quinone(-O), and carboxyl(-COOH) are often present on the edge of graphite and can affect graphite's chemical properties. When oxygen-containing functional groups appear on a graphite surface, the oxygen molecules are strongly adsorbed onto the surface to form a four-member ring structure. At the same time, the O-O bond is greatly weakened and easily broken. The adsorption energy value indicates that the adsorption of oxygen molecules changes from physisorption to chemisorption for oxygen-containing functional groups on the edge of a graphite surface. In addition, our results indicate that the adsorption energy depends on the type of oxygen-containing functional group. When a single active oxygen atom is adsorbed on the bridge site of graphite, it gives rise to a stable epoxy structure. Epoxy can cause deformation of the graphite lattice due to the transition of graphite from sp2 to sp3 after the addition of an oxygen atom. For quinone group on the edge of graphite, oxygen atoms react with carbon atoms to form the precursor of CO2. Similarly, the single active oxygen atoms of carbonyl groups can interact with edge carbon atoms to form the precursor of CO2. The results show that oxygen-containing functional groups on graphite surfaces enhance the activity of graphite, which promotes adsorption on the graphite surface.

Density functional theory study the effects of oxygen-containing functional groups on oxygen molecules and oxygen atoms adsorbed on carbonaceous materials

PubMed Central

Song, Wenwu; Shi, Jianwei

2017-01-01

Density functional theory was used to study the effects of different types of oxygen-containing functional groups on the adsorption of oxygen molecules and single active oxygen atoms on carbonaceous materials. During gasification or combustion reactions of carbonaceous materials, oxygen-containing functional groups such as hydroxyl(-OH), carbonyl(-CO), quinone(-O), and carboxyl(-COOH) are often present on the edge of graphite and can affect graphite’s chemical properties. When oxygen-containing functional groups appear on a graphite surface, the oxygen molecules are strongly adsorbed onto the surface to form a four-member ring structure. At the same time, the O-O bond is greatly weakened and easily broken. The adsorption energy value indicates that the adsorption of oxygen molecules changes from physisorption to chemisorption for oxygen-containing functional groups on the edge of a graphite surface. In addition, our results indicate that the adsorption energy depends on the type of oxygen-containing functional group. When a single active oxygen atom is adsorbed on the bridge site of graphite, it gives rise to a stable epoxy structure. Epoxy can cause deformation of the graphite lattice due to the transition of graphite from sp2 to sp3 after the addition of an oxygen atom. For quinone group on the edge of graphite, oxygen atoms react with carbon atoms to form the precursor of CO2. Similarly, the single active oxygen atoms of carbonyl groups can interact with edge carbon atoms to form the precursor of CO2. The results show that oxygen-containing functional groups on graphite surfaces enhance the activity of graphite, which promotes adsorption on the graphite surface. PMID:28301544

The Tapioca Bomb: A Demonstration to Enhance Learning about Combustion and Chemical Safety

ERIC Educational Resources Information Center

Keeratichamroen, Wasana; Dechsri, Precharn; Panijpan, Bhinyo; Ruenwongsa, Pintip

2010-01-01

In any demonstration to students, producing light and sound usually ensures interest and can enhance understanding and retention of the concepts involved. A guided inquiry (Predict, Observe, Explain: POE) approach was used to involve the students actively in their learning about the explosive combustion of fine flour particles in air in the…

Analysis of the laser ignition of methane/oxygen mixtures in a sub-scale rocket combustion chamber

NASA Astrophysics Data System (ADS)

Wohlhüter, Michael; Zhukov, Victor P.; Sender, Joachim; Schlechtriem, Stefan

2017-06-01

The laser ignition of methane/oxygen mixtures in a sub-scale rocket combustion chamber has been investigated numerically and experimentally. The ignition test case used in the present paper was generated during the In-Space Propulsion project (ISP-1), a project focused on the operation of propulsion systems in space, the handling of long idle periods between operations, and multiple reignitions under space conditions. Regarding the definition of the numerical simulation and the suitable domain for the current model, 2D and 3D simulations have been performed. Analysis shows that the usage of a 2D geometry is not suitable for this type of simulation, as the reduction of the geometry to a 2D domain significantly changes the conditions at the time of ignition and subsequently the flame development. The comparison of the numerical and experimental results shows a strong discrepancy in the pressure evolution and the combustion chamber pressure peak following the laser spark. The detailed analysis of the optical Schlieren and OH data leads to the conclusion that the pressure measurement system was not able to capture the strong pressure increase and the peak value in the combustion chamber during ignition. Although the timing in flame development following the laser spark is not captured appropriately, the 3D simulations reproduce the general ignition phenomena observed in the optical measurement systems, such as pressure evolution and injector flow characteristics.

Reversed flow fluidized-bed combustion apparatus

DOEpatents

Shang, Jer-Yu; Mei, Joseph S.; Wilson, John S.

1984-01-01

The present invention is directed to a fluidized-bed combustion apparatus provided with a U-shaped combustion zone. A cyclone is disposed in the combustion zone for recycling solid particulate material. The combustion zone configuration and the recycling feature provide relatively long residence times and low freeboard heights to maximize combustion of combustible material, reduce nitrogen oxides, and enhance sulfur oxide reduction.

Effect of oxygen atoms dissociated by non-equilibrium plasma on flame of methane oxygen and argon pre-mixture gas

NASA Astrophysics Data System (ADS)

Akashi, Haruaki; Yoshinaga, Tomokazu; Sasaki, Koichi

2014-10-01

For more efficient way of combustion, plasma-assisted combustion has been investigated by many researchers. But it is very difficult to clarify the effect of plasma even on the flame of methane. Because there are many complex chemical reactions in combustion system. Sasaki et al. has reported that the flame length of methane and air premixed burner shortened by irradiating microwave power. They also measured emission from Second Positive Band System of nitrogen during the irradiation. The emission indicates existence of high energy electrons which are accelerated by the microwave. The high energy electrons also dissociate oxygen molecules easily and oxygen atom would have some effects on the flame. But the dissociation ratio of oxygen molecules by the non-equilibrium plasma is significantly low, compared to that in the combustion reaction. To clarify the effect of dissociated oxygen atoms on the flame, dependence of dissociation ratio of oxygen on the flame has been examined using CHEMKIN. It is found that in the case of low dissociation ratio of 10-6, the ignition of the flame becomes slightly earlier. It is also found that in the case of high dissociation ratio of 10-3, the ignition time becomes significantly earlier by almost half. This work was supported by KAKENHI (22340170).

New method for determining heats of combustion of gaseous hydrocarbons

NASA Technical Reports Server (NTRS)

Singh, J. J.; Sprinkle, D. R.; Puster, R. L.

1985-01-01

As a spin off of a system developed for monitoring and controlling the oxygen concentration in the Langley 8-foot High Temperature Tunnel, a highly accurate on-line technique was developed for determining heats of combustion of natural gas samples. It is based on measuring the ratio m/n, where m is the (volumetric) flowrate of oxygen required to enrich the carrier air in which the test gas flowing at the rate n is burned, such that the mole fraction of oxygen in the combustion product gases equals that in the carrier air. The m/n ratio is directly related to the heats of combustion of the saturated hydrocarbons present in the natural gas. A measurement of the m/n ratio for the test gas can provide a direct means of determination of its heat of combustion by using the calibration graph relating the m/n values for pure saturated hydrocarbons with their heats of combustion. The accuracy of the technique is determine solely by the accuracy with which the flowrates m and n can be measured and is of the order of 2 percent in the present study. The theoretical principles and experimental results are discussed.

Particle-bound reactive oxygen species (PB-ROS) emissions and formation pathways in residential wood smoke under different combustion and aging conditions

NASA Astrophysics Data System (ADS)

Zhou, Jun; Zotter, Peter; Bruns, Emily A.; Stefenelli, Giulia; Bhattu, Deepika; Brown, Samuel; Bertrand, Amelie; Marchand, Nicolas; Lamkaddam, Houssni; Slowik, Jay G.; Prévôt, André S. H.; Baltensperger, Urs; Nussbaumer, Thomas; El-Haddad, Imad; Dommen, Josef

2018-05-01

Wood combustion emissions can induce oxidative stress in the human respiratory tract by reactive oxygen species (ROS) in the aerosol particles, which are emitted either directly or formed through oxidation in the atmosphere. To improve our understanding of the particle-bound ROS (PB-ROS) generation potential of wood combustion emissions, a suite of smog chamber (SC) and potential aerosol mass (PAM) chamber experiments were conducted under well-determined conditions for different combustion devices and technologies, different fuel types, operation methods, combustion regimes, combustion phases, and aging conditions. The PB-ROS content and the chemical properties of the aerosols were quantified by a novel ROS analyzer using the DCFH (2',7'-dichlorofluorescin) assay and a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). For all eight combustion devices tested, primary PB-ROS concentrations substantially increased upon aging. The level of primary and aged PB-ROS emission factors (EFROS) were dominated by the combustion device (within different combustion technologies) and to a greater extent by the combustion regimes: the variability within one device was much higher than the variability of EFROS from different devices. Aged EFROS under bad combustion conditions were ˜ 2-80 times higher than under optimum combustion conditions. EFROS from automatically operated combustion devices were on average 1 order of magnitude lower than those from manually operated devices, which indicates that automatic combustion devices operated at optimum conditions to achieve near-complete combustion should be employed to minimize PB-ROS emissions. The use of an electrostatic precipitator decreased the primary and aged ROS emissions by a factor of ˜ 1.5 which is however still within the burn-to-burn variability. The parameters controlling the PB-ROS formation in secondary organic aerosol were investigated by employing a regression model, including the fractions of

Technology evaluation report: SITE (Superfund Innovative Technology Evaluation) program demonstration test. The American Combustion Pyretron Thermal Destruction System at the US EPA's (Environmental Protection Agency's) combustion research facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Waterland, L.; Lee, J.W.

1989-04-01

A series of demonstration tests of the American Combustion, Inc., Thermal Destruction System was performed under the SITE program. This oxygen-enhanced combustion system was retrofit to the rotary-kiln incinerator at EPA's Combustion Research Facility. The system's performance was tested firing contaminated soil from the Stringfellow Superfund Site, both alone and mixed with a coal tar waste (KO87). Comparative performance with conventional incinerator operation was also tested. Compliance with the incinerator performance standards of 99.99% principal organic hazardous constituents (POHC) destruction and removal efficiency and particulate emissions of less than 180 mg/dscm at 7% O2 was measured for all tests. Themore » Pyretron system was capable of in-compliance performance at double the mixed waste feedrate and at a 60% increase in batch waste charge mass than possible with conventional incineration. Scrubber blowdown and kiln ash contained no detectable levels of any of the POHCs chosen.« less

Laser Schlieren and ultraviolet diagnostics of rocket combustion

NASA Technical Reports Server (NTRS)

Fisher, S. C.

1985-01-01

A low pressure oxygen/hydrogen turbine drive combustor hot-fire test series was conducted on the Turbine Drive Combustor Technology Program. The first objective was to gather data on an axisymmetric combustion system to support anchoring of a new combustion/fluid dynamics computer code under development on the same contract. The second objective was to gain insight into low mixture ratio combustion characteristics of coaxial injector elements.

Long term analysis of the biomass content in the feed of a waste-to-energy plant with oxygen-enriched combustion air.

PubMed

Fellner, Johann; Cencic, Oliver; Zellinger, Günter; Rechberger, Helmut

2011-10-01

Thermal utilization of municipal solid waste and commercial wastes has become of increasing importance in European waste management. As waste materials are generally composed of fossil and biogenic materials, a part of the energy generated can be considered as renewable and is thus subsidized in some European countries. Analogously, CO(2) emissions of waste incinerators are only partly accounted for in greenhouse gas inventories. A novel approach for determining these fractions is the so-called balance method. In the present study, the implementation of the balance method on a waste-to-energy plant using oxygen-enriched combustion air was investigated. The findings of the 4-year application indicate on the one hand the general applicability and robustness of the method, and on the other hand the importance of reliable monitoring data. In particular, measured volume flows of the flue gas and the oxygen-enriched combustion air as well as corresponding O(2) and CO(2) contents should regularly be validated. The fraction of renewable (biogenic) energy generated throughout the investigated period amounted to between 27 and 66% for weekly averages, thereby denoting the variation in waste composition over time. The average emission factor of the plant was approximately 45 g CO(2) MJ(-1) energy input or 450 g CO(2) kg(-1) waste incinerated. The maximum error of the final result was about 16% (relative error), which was well above the error (<8%) of the balance method for plants with conventional oxygen supply.

Fate of hazardous air pollutants in oxygen-fired coal combustion with different flue gas recycling.

PubMed

Zhuang, Ye; Pavlish, John H

2012-04-17

Experiments were performed to characterize transformation and speciation of hazardous air pollutants (HAPs), including SO(2)/SO(3), NO(x), HCl, particulate matter, mercury, and other trace elements in oxygen-firing bituminous coal with recirculation flue gas (RFG) from 1) an electrostatic precipitator outlet or 2) a wet scrubber outlet. The experimental results showed that oxycombustion with RFG generated a flue gas with less volume and containing HAPs at higher levels, while the actual emissions of HAPs per unit of energy produced were much less than that of air-blown combustion. NO(x) reduction was achieved in oxycombustion because of the elimination of nitrogen and the destruction of NO in the RFG. The elevated SO(2)/SO(3) in flue gas improved sulfur self-retention. SO(3) vapor could reach its dew point in the flue gas with high moisture, which limits the amount of SO(3) vapor in flue gas and possibly induces material corrosion. Most nonvolatile trace elements were less enriched in fly ash in oxycombustion than air-firing because of lower oxycombustion temperatures occurring in the present study. Meanwhile, Hg and Se were found to be enriched on submicrometer fly ash at higher levels in oxy-firing than in air-blown combustion.

Molecular structure of photosynthetic microbial biofuels for improved engine combustion and emissions characteristics.

PubMed

Hellier, Paul; Purton, Saul; Ladommatos, Nicos

2015-01-01

The metabolic engineering of photosynthetic microbes for production of novel hydrocarbons presents an opportunity for development of advanced designer biofuels. These can be significantly more sustainable, throughout the production-to-consumption lifecycle, than the fossil fuels and crop-based biofuels they might replace. Current biofuels, such as bioethanol and fatty acid methyl esters, have been developed primarily as drop-in replacements for existing fossil fuels, based on their physical properties and autoignition characteristics under specific combustion regimes. However, advances in the genetic engineering of microalgae and cyanobacteria, and the application of synthetic biology approaches offer the potential of designer strains capable of producing hydrocarbons and oxygenates with specific molecular structures. Furthermore, these fuel molecules can be designed for higher efficiency of energy release and lower exhaust emissions during combustion. This paper presents a review of potential fuel molecules from photosynthetic microbes and the performance of these possible fuels in modern internal combustion engines, highlighting which modifications to the molecular structure of such fuels may enhance their suitability for specific combustion regimes.

Molecular Structure of Photosynthetic Microbial Biofuels for Improved Engine Combustion and Emissions Characteristics

PubMed Central

Hellier, Paul; Purton, Saul; Ladommatos, Nicos

2015-01-01

The metabolic engineering of photosynthetic microbes for production of novel hydrocarbons presents an opportunity for development of advanced designer biofuels. These can be significantly more sustainable, throughout the production-to-consumption lifecycle, than the fossil fuels and crop-based biofuels they might replace. Current biofuels, such as bioethanol and fatty acid methyl esters, have been developed primarily as drop-in replacements for existing fossil fuels, based on their physical properties and autoignition characteristics under specific combustion regimes. However, advances in the genetic engineering of microalgae and cyanobacteria, and the application of synthetic biology approaches offer the potential of designer strains capable of producing hydrocarbons and oxygenates with specific molecular structures. Furthermore, these fuel molecules can be designed for higher efficiency of energy release and lower exhaust emissions during combustion. This paper presents a review of potential fuel molecules from photosynthetic microbes and the performance of these possible fuels in modern internal combustion engines, highlighting which modifications to the molecular structure of such fuels may enhance their suitability for specific combustion regimes. PMID:25941673

Buoyancy and Pressure Effects on Bulk Metal-Oxygen Reactions

NASA Technical Reports Server (NTRS)

Abbud-Madrid, A.; McKnight, C.; Branch, M. C.; Daily, J. W.; Friedman, R. (Technical Monitor)

1998-01-01

The combustion behavior of metal-oxygen reactions if a weakly buoyant environment is studied to understand the rate-controlling mechanisms in the homogeneous and heterogeneous combustion of bulk metals. Cylindrical titanium and magnesium specimens are ignited in pure-oxygen at pressures ranging from 0.1 to 4.0 atm. Reduced gravity is obtained from an aircraft flying parabolic trajectories. A weakly buoyant environment is generated at low pressures under normal gravity and also at 1 atm under reduced gravity (0.01g). The similarity between these two experimental conditions comes from the p(exp 2)g buoyancy scale extracted from the Grashof number. Lower propagation rates of the molten interface on titanium samples are found at progressively lower pressures at 1 g. These rates are compared to theoretical results from heat conduction analyses with a diffusion/convection controlled reaction. The close agreement found between experimental and theoretical values indicate the importance values indicate the importance of natural convection enhanced oxygen transport on combustion rates. For magnesium, progressively longer burning times are experienced at lower pressures and 1 g. Under reduced gravity conditions at 1 atm, a burning time twice as long as in 1 g is exhibited. However, in this case, the validity of the p(exp 2)g buoyancy scale remains untested due to the inability to obtain steady gas-phase burning of the magnesium sample at 0.1 atm. Nevertheless, longer burning times and larger flame standoff distance at low pressures and at low gravity points to a diffusion/convection controlled reaction.

Enhancement of C2C12 differentiation by perfluorocarbon-mediated oxygen delivery.

PubMed

Fujita, Hideaki; Shimizu, Kazunori; Morioka, Yuki; Nagamori, Eiji

2010-09-01

We have studied the effect of enhanced oxygen delivery by perfluorocarbons on the differentiation of C2C12 cells. The extent of differentiation was assessed by means of phase contrast/fluorescence microscopy, active tension measurement and the glucose consumption/lactate production rates. We found that enhanced oxygen delivery is suitable for full differentiation of C2C12 cells. Copyright 2010 The Society for Biotechnology, Japan. All rights reserved.

Determination of Local Experimental Heat-Transfer Coefficients on Combustion Side of an Ammonia-Oxygen Rocket

NASA Technical Reports Server (NTRS)

Liebert, Curt H.; Ehlers, Robert C.

1961-01-01

Local experimental heat-transfer coefficients were measured in the chamber and throat of a 2400-pound-thrust ammonia-oxygen rocket engine with a nominal chamber pressure of 600 pounds per square inch absolute. Three injector configurations were used. The rocket engine was run over a range of oxidant-fuel ratio and chamber pressure. The injector that achieved the best performance also produced the highest rates of heat flux at design conditions. The heat-transfer data from the best-performing injector agreed well with the simplified equation developed by Bartz at the throat region. A large spread of data was observed for the chamber. This spread was attributed generally to the variations of combustion processes. The spread was least evident, however, with the best-performing injector.

Preparation of Pd supported on La(Sr)-Mn-O Perovskite by microwave Irradiation Method and Its Catalytic Performances for the Methane Combustion

PubMed Central

Wang, Wei; Yuan, Fulong; Niu, Xiaoyu; Zhu, Yujun

2016-01-01

In this work, a series of palladium supported on the La0.8Sr0.2MnO3.15 perovskite catalysts (Pd/LSM-x) with different Pd loading were prepared by microwave irradiation processing plus incipient wetness impregnation method and characterized by XRD, TEM, H2-TPR and XPS. These catalysts were evaluated on the lean CH4 combustion. The results show that the Pd/LSM-x samples prepared by microwave irradiation processing possess relative higher surface areas than LSM catalyst. The addition of Pd to the LSM leads to the increase in the oxygen vacancy content and the enhancement in the mobility of lattice oxygen which play an important role on the methane combustion. The Pd/LSM-3 catalysts with 4.2wt% Pd loading exhibited the best performance for CH4 combustion that temperature for 10% and 90% of CH4 conversion is 315 and 520 °C. PMID:26781628

Thermal analysis and kinetics of coal during oxy-fuel combustion

NASA Astrophysics Data System (ADS)

Kosowska-Golachowska, Monika

2017-08-01

The pyrolysis and oxy-fuel combustion characteristics of Polish bituminous coal were studied using non-isothermal thermogravimetric analysis. Pyrolysis tests showed that the mass loss profiles were almost similar up to 870°C in both N2 and CO2 atmospheres, while further mass loss occurred in CO2 atmosphere at higher temperatures due to char-CO2 gasification. Replacement of N2 in the combustion environment by CO2 delayed the combustion of bituminous coal. At elevated oxygen levels, TG/DTG profiles shifted through lower temperature zone, ignition and burnout temperatures decreased and mass loss rate significantly increased and complete combustion was achieved at lower temperatures and shorter times. Kinetic analysis for the tested coal was performed using Kissinger-Akahira-Sunose (KAS) method. The activation energies of bituminous coal combustion at the similar oxygen content in oxy-fuel with that of air were higher than that in air atmosphere. The results indicated that, with O2 concentration increasing, the activation energies decreased.

Combustion of liquid fuels in a flowing combustion gas environment at high pressures

NASA Technical Reports Server (NTRS)

Canada, G. S.; Faeth, G. M.

1975-01-01

The combustion of fuel droplets in gases which simulate combustion chamber conditions was considered both experimentally and theoretically. The fuel droplets were simulated by porous spheres and allowed to gasify in combustion gases produced by a burner. Tests were conducted for pressures of 1-40 atm, temperatures of 600-1500 K, oxygen concentrations of 0-13% (molar) and approach Reynolds numbers of 40-680. The fuels considered in the tests included methanol, ethanol, propanol-1, n-pentane, n-heptane and n-decane. Measurements were made of both the rate of gasification of the droplet and the liquid surface temperature. Measurements were compared with theory, involving various models of gas phase transport properties with a multiplicative correction for the effect of forced convection.

Oxygen transport enhancement by functionalized magnetic nanoparticles (FMP) in bioprocesses

NASA Astrophysics Data System (ADS)

Ataide, Filipe Andre Prata

The enhancement of fluid properties, namely thermal conductivity and mass diffusivity for a wide range of applications, through the use of nanosized particles' suspensions has been gathering increasing interest in the scientific community. In previous studies, Olle et al. (2006) showed an enhancement in oxygen absorption to aqueous solutions of up to 6-fold through the use of functionalized nanosized magnetic particles with oleic acid coating. Krishnamurthy et al. (2006) showed a remarkable 26-fold enhancement in dye diffusion in water. These two publications are landmarks in mass transfer enhancement in chemical systems through the use of nanoparticles. The central goal of this Ph.D. thesis was to develop functionalized magnetic nanoparticles to enhance oxygen transport in bioprocesses. The experimental protocol for magnetic nanoparticles synthesis and purification adopted in this thesis is a modification of that reported by Olle et al. (2006). This is facilitated by employing twice the quantity of ammonia, added at a slower rate, and by filtering the final nanoparticle solution in a cross-flow filtration modulus against 55 volumes of distilled water. This modification in the protocol resulted in improved magnetic nanoparticles with measurably higher mass transfer enhancement. Magnetic nanoparticles with oleic acid and Hitenol-BC coating were screened for oxygen transfer enhancement, since these particles are relatively inexpensive and easy to synthesize. A glass 0.5-liter reactor was custom manufactured specifically for oxygen transport studies in magnetic nanoparticles suspensions. The reactor geometry, baffles and Rushton impeller are of standard dimensions. Mass transfer tests were conducted through the use of the sulphite oxidation method, applying iodometric back-titration. A 3-factor central composite circumscribed design (CCD) was adopted for design of experiments in order to generate sufficiently informative data to model the effect of magnetic

Effects of mesh type on a non-premixed model in a flameless combustion simulation

NASA Astrophysics Data System (ADS)

Komonhirun, Seekharin; Yongyingsakthavorn, Pisit; Nontakeaw, Udomkiat

2018-01-01

Flameless combustion is a recently developed combustion system, which provides zero emission product. This phenomenon requires auto-ignition by supplying high-temperature air with low oxygen concentration. The flame is vanished and colorless. Temperature of the flameless combustion is less than that of a conventional case, where NOx reactions can be well suppressed. To design a flameless combustor, the computational fluid dynamics (CFD) is employed. The designed air-and-fuel injection method can be applied with the turbulent and non-premixed models. Due to the fact that nature of turbulent non-premixed combustion is based on molecular randomness, inappropriate mesh type can lead to significant numerical errors. Therefore, this research aims to numerically investigate the effects of mesh type on flameless combustion characteristics, which is a primary step of design process. Different meshes, i.e. tetrahedral, hexagonal are selected. Boundary conditions are 5% of oxygen and 900 K of air-inlet temperature for the flameless combustion, and 21% of oxygen and 300 K of air-inlet temperature for the conventional case. The results are finally presented and discussed in terms of velocity streamlines, and contours of turbulent kinetic energy and viscosity, temperature, and combustion products.

The effect of oxygen enrichment on soot formation and thermal radiation in turbulent, non-premixed methane flames

DOE PAGES

Shaddix, Christopher R.; Williams, Timothy C.

2016-07-12

Non-premixed oxy-fuel combustion of natural gas is used in industrial applications where high-intensity heat is required, such as glass manufacturing and metal forging and shaping. In these applications, the high flame temperatures achieved by oxy-fuel combustion increase radiative heat transfer to the surfaces of interest and soot formation within the flame is desired for further augmentation of radiation. However, the high cost of cryogenic air separation has limited the penetration of oxy-fuel combustion technologies. New approaches to air separation are being developed that may reduce oxygen production costs, but only for intermediate levels of oxygen enrichment of air. To determinemore » the influence of oxygen enrichment on soot formation and radiation, we developed a non-premixed coannular burner in which oxygen concentrations and oxidizer flow rates can be independently varied, to distinguish the effects of turbulent mixing intensity from oxygen enrichment on soot formation and flame radiation. Local radiation intensities, soot concentrations, and soot temperatures have been measured using a thin-film thermopile, planar laser-induced incandescence (LII), and two-color imaging pyrometry, respectively. The measurements show that soot formation increases as the oxygen concentration decreases from 100% to 50%, helping to moderate a decrease in overall flame radiation. An increase in turbulence intensity has a marked effect on flame height, soot formation and thermal radiation, leading to decreases in all of these. The soot temperature decreases with a decrease in the oxygen concentration and increases with an increase in turbulent mixing intensity. Altogether, the results suggest that properly designed oxygen-enriched burners that enhance soot formation for intermediate levels of oxygen purity may be able to achieve thermal radiation intensities as high as 85% of traditional oxy-fuel burners utilizing high-purity oxygen.« less

The effect of oxygen enrichment on soot formation and thermal radiation in turbulent, non-premixed methane flames

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shaddix, Christopher R.; Williams, Timothy C.

Non-premixed oxy-fuel combustion of natural gas is used in industrial applications where high-intensity heat is required, such as glass manufacturing and metal forging and shaping. In these applications, the high flame temperatures achieved by oxy-fuel combustion increase radiative heat transfer to the surfaces of interest and soot formation within the flame is desired for further augmentation of radiation. However, the high cost of cryogenic air separation has limited the penetration of oxy-fuel combustion technologies. New approaches to air separation are being developed that may reduce oxygen production costs, but only for intermediate levels of oxygen enrichment of air. To determinemore » the influence of oxygen enrichment on soot formation and radiation, we developed a non-premixed coannular burner in which oxygen concentrations and oxidizer flow rates can be independently varied, to distinguish the effects of turbulent mixing intensity from oxygen enrichment on soot formation and flame radiation. Local radiation intensities, soot concentrations, and soot temperatures have been measured using a thin-film thermopile, planar laser-induced incandescence (LII), and two-color imaging pyrometry, respectively. The measurements show that soot formation increases as the oxygen concentration decreases from 100% to 50%, helping to moderate a decrease in overall flame radiation. An increase in turbulence intensity has a marked effect on flame height, soot formation and thermal radiation, leading to decreases in all of these. The soot temperature decreases with a decrease in the oxygen concentration and increases with an increase in turbulent mixing intensity. Altogether, the results suggest that properly designed oxygen-enriched burners that enhance soot formation for intermediate levels of oxygen purity may be able to achieve thermal radiation intensities as high as 85% of traditional oxy-fuel burners utilizing high-purity oxygen.« less

Promoted Metals Combustion at Ambient and Elevated Temperatures

NASA Technical Reports Server (NTRS)

Engel, Carl D.; Herald, Stephen D.; Davis, S. Eddie

2005-01-01

Promoted combustion testing of materials, Test 17 of NASA STD-6001, has been used to assess metal propensity to burn in oxygen rich environments. An igniter is used at the bottom end of a rod to promote ignition, and if combustion is sustained, the burning progresses from the bottom to the top of the rod. The physical mechanisms are very similar to the upward flammability test, Test 1 of NASA STD-6001. The differences are in the normal environmental range of pressures, oxygen content, and sample geometry. Upward flammability testing of organic materials can exhibit a significant transitional region between no burning to complete quasi-state burning. In this transitional region, the burn process exhibits a probabilistic nature. This transitional region has been identified for metals using the promoted combustion testing method at ambient initial temperatures. The work given here is focused on examining the transitional region and the quasi-steady burning region both at conventional ambient testing conditions and at elevated temperatures. A new heated promoted combustion facility and equipment at Marshall Space Flight Center have just been completed to provide the basic data regarding the metals operating temperature limits in contact with oxygen rich atmospheres at high pressures. Initial data have been obtained for Stainless Steel 304L, Stainless Steel 321, Haynes 214, and Inconel 718 at elevated temperatures in 100-percent oxygen atmospheres. These data along with an extended data set at ambient initial temperature test conditions are examined. The pressure boundaries of acceptable, non-burning usage is found to be lowered at elevated temperature.

Update for combustion properties of wood components

Treesearch

Mark Dietenberger

2002-01-01

The combustion properties of various biomass and wood materials from various references and from our laboratory were reanalysed. The net heat of combustion for cellulosic materials was found to be 13.23 kJ/g times the ratio of stoichiometric oxygen mass to fuel mass, r[subscript]o, regardless of the material composition. Bomb calorimeter data for original, charred and...

Combustion-wave ignition for rocket engines

NASA Technical Reports Server (NTRS)

Liou, Larry C.

1992-01-01

The combustion wave ignition concept was experimentally studied in order to verify its suitability for application in baffled sections of a large booster engine combustion chamber. Gaseous oxygen/gaseous methane (GOX/GH4) and gaseous oxygen/gaseous hydrogen (GOX/GH2) propellant combinations were evaluated in a subscale combustion wave ignition system. The system included four element tubes capable of carrying ignition energy simultaneously to four locations, simulating four baffled sections. Also, direct ignition of a simulated Main Combustion Chamber (MCC) was performed. Tests were conducted over a range of mixture ratios and tube geometries. Ignition was consistently attained over a wide range of mixture ratios. And at every ignition, the flame propagated through all four element tubes. For GOX/GH4, the ignition system ignited the MCC flow at mixture ratios from 2 to 10 and for GOX/GH2 the ratios is from 2 to 13. The ignition timing was found to be rapid and uniform. The total ignition delay when using the MCC was under 11 ms, with the tube-to-tube, as well as the run-to-run, variation under 1 ms. Tube geometries were found to have negligible effect on the ignition outcome and timing.

Droplet Combustion Experiment movie

NASA Technical Reports Server (NTRS)

2003-01-01

The Droplet Combustion Experiment (DCE) was designed to investigate the fundamental combustion aspects of single, isolated droplets under different pressures and ambient oxygen concentrations for a range of droplet sizes varying between 2 and 5 mm. The DCE principal investigator was Forman Williams, University of California, San Diego. The experiment was part of the space research investigations conducted during the Microgravity Science Laboratory-1 mission (STS-83, April 4-8 1997; the shortened mission was reflown as MSL-1R on STS-94). Advanced combustion experiments will be a part of investigations plarned for the International Space Station. (1.1 MB, 12-second MPEG, screen 320 x 240 pixels; downlinked video, higher quality not available)A still JPG composite of this movie is available at http://mix.msfc.nasa.gov/ABSTRACTS/MSFC-0300164.html.

Attrition Rate of Oxygen Carriers in Chemical Looping Combustion Systems

NASA Astrophysics Data System (ADS)

Feilen, Harry Martin

This project developed an evaluation methodology for determining, accurately and rapidly, the attrition resistance of oxygen carrier materials used in chemical looping technologies. Existing test protocols, to evaluate attrition resistance of granular materials, are conducted under non-reactive and ambient temperature conditions. They do not accurately reflect the actual behavior under the unique process conditions of chemical looping, including high temperatures and cyclic operation between oxidizing and reducing atmospheres. This project developed a test method and equipment that represented a significant improvement over existing protocols. Experimental results obtained from this project have shown that hematite exhibits different modes of attrition, including both due to mechanical stresses and due to structural changes in the particles due to chemical reaction at high temperature. The test methodology has also proven effective in providing reactivity changes of the material with continued use, a property, which in addition to attrition, determines material life. Consumption/replacement cost due to attrition or loss of reactivity is a critical factor in the economic application of the chemical looping technology. This test method will allow rapid evaluation of a wide range of materials that are best suited for this technology. The most important anticipated public benefit of this project is the acceleration of the development of chemical looping technology for lowering greenhouse gas emissions from fossil fuel combustion.

A new bomb-combustion system for tritium extraction.

PubMed

Marsh, Richard I; Croudace, Ian W; Warwick, Phillip E; Cooper, Natasha; St-Amant, Nadereh

2017-01-01

Quantitative extraction of tritium from a sample matrix is critical to efficient measurement of the low-energy pure beta emitter. Oxidative pyrolysis using a tube furnace (Pyrolyser) has been adopted as an industry standard approach for the liberation of tritium (Warwick et al. in Anal Chim Acta 676:93-102, 2010) however pyrolysis of organic-rich materials can be problematic. Practically, the mass of organic rich sample combusted is typically limited to <1 g to minimise the possibility of incomplete combustion. This can have an impact on both the limit of detection that can be achieved and how representative the subsample is of the bulk material, particularly in the case of heterogeneous soft waste. Raddec International Ltd (Southampton, UK), in conjunction with GAU-Radioanalytical, has developed a new high-capacity oxygen combustion bomb (the Hyperbaric Oxidiser; HBO 2 ) to address this challenge. The system is capable of quantitatively combusting samples of 20-30 g under an excess of oxygen, facilitating rapid extraction of total tritium from a wide range sample types.

Peroxide-based oxygen generating topical wound dressing for enhancing healing of dermal wounds.

PubMed

Chandra, Prafulla K; Ross, Christina L; Smith, Leona C; Jeong, Seon S; Kim, Jaehyun; Yoo, James J; Harrison, Benjamin S

2015-01-01

Oxygen generating biomaterials represent a new trend in regenerative medicine that aims to generate and supply oxygen at the site of requirement, to support tissue healing and regeneration. To enhance the healing of dermal wounds, we have developed a highly portable, in situ oxygen generating wound dressings that uses sodium percarbonate (SPO) and calcium peroxide (CPO) as chemical oxygen sources. The dressing continuously generated oxygen for more than 3 days, after which it was replaced. In the in vivo testing on porcine full-thickness porcine wound model, the SPO/CPO dressing showed enhanced wound healing during the 8 week study period. Quantitative measurements of wound healing related parameters, such as wound closure, reepithelialization, epidermal thickness and collagen content of dermis showed that supplying oxygen topically using the SPO/CPO dressing significantly accelerated the wound healing. An increase in neovascularization, as determined using Von Willebrand factor (vWF) and CD31 staining, was also observed in the presence of SPO/CPO dressing. This novel design for a wound dressing that contains oxygen generating biomaterials (SPO/CPO) for supplying topical oxygen, may find utility in treating various types of acute to chronic wounds. © 2015 by the Wound Healing Society.

Combustion Of Porous Graphite Particles In Oxygen Enriched Air

NASA Technical Reports Server (NTRS)

Delisle, Andrew J.; Miller, Fletcher J.; Chelliah, Harsha K.

2003-01-01

Combustion of solid fuel particles has many important applications, including power generation and space propulsion systems. The current models available for describing the combustion process of these particles, especially porous solid particles, include various simplifying approximations. One of the most limiting approximations is the lumping of the physical properties of the porous fuel with the heterogeneous chemical reaction rate constants [1]. The primary objective of the present work is to develop a rigorous modeling approach that could decouple such physical and chemical effects from the global heterogeneous reaction rates. For the purpose of validating this model, experiments with porous graphite particles of varying sizes and porosity are being performed under normal and micro gravity.

Thermochemical conversion of biomass in smouldering combustion across scales: The roles of heterogeneous kinetics, oxygen and transport phenomena.

PubMed

Huang, Xinyan; Rein, Guillermo

2016-05-01

The thermochemical conversion of biomass in smouldering combustion is investigated here by combining experiments and modeling at two scales: matter (1mg) and bench (100g) scales. Emphasis is put on the effect of oxygen (0-33vol.%) and oxidation reactions because these are poorly studied in the literature in comparison to pyrolysis. The results are obtained for peat as a representative biomass for which there is high-quality experimental data published previously. Three kinetic schemes are explored, including various steps of drying, pyrolysis and oxidation. The kinetic parameters are found using the Kissinger-Genetic Algorithm method, and then implemented in a one-dimensional model of heat and mass transfer. The predictions are validated with thermogravimetric and bench-scale experiments and then analyzed to unravel the role of heterogeneous reaction. This is the first time that the influence of oxygen on biomass smouldering is explained in terms of both chemistry and transport phenomena across scales. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

Modeling of Plasma Assisted Combustion

NASA Astrophysics Data System (ADS)

Akashi, Haruaki

2012-10-01

Recently, many experimental study of plasma-assisted combustion has been done. However, numerous complex reactions in combustion of hydrocarbons are preventing from theoritical study for clarifying inside the plasma-assisted combustion, and the effect of plasma-assist is still not understood. Shinohara and Sasaki [1,2] have reported that the shortening of flame length by irradiating microwave without increase of gas temperature. And they also reported that the same phenomena would occur when applying dielectric barrier discharges to the flame using simple hydrocarbon, methane. It is suggested that these phenomena may result by the electron heating. To clarify this phenomena, electron behavior under microwave and DBD was examined. For the first step of DBD plasma-assisted combustion simulation, electron Monte Carlo simulation in methane, oxygen and argon mixture gas(0.05:0.14:0.81) [2] has been done. Electron swarm parameters are sampled and electron energy distribution function (EEDF)s are also determined. In the combustion, gas temperature is higher(>1700K), so reduced electric field E/N becomes relatively high(>10V/cm/Torr). The electrons are accelerated to around 14 eV. This result agree with the optical emission from argon obtained by the experiment of reference [2]. Dissociation frequency of methane and oxygens are obtained in high. This might be one of the effect of plasma-assist. And it is suggested that the electrons should be high enough to dissociate methane, but plasma is not needed.[4pt] [1] K. Shinohara et al, J. Phys. D:Appl. Phys., 42, 182008 (1-7) (2009).[0pt] [2] K. Sasaki, 64th Annual Gaseous Electronic Conference, 56, 15 CT3.00001(2011).

Oxide Protective Coats for Ir/Re Rocket Combustion Chambers

NASA Technical Reports Server (NTRS)

Fortini, Arthur; Tuffias, Robert H.

2003-01-01

An improved material system has been developed for rocket engine combustion chambers for burning oxygen/ hydrogen mixtures or novel monopropellants, which are highly oxidizing at operating temperatures. The baseline for developing the improved material system is a prior iridium/rhenium system for chambers burning nitrogen tetroxide/monomethyl hydrazine mixtures, which are less oxidizing. The baseline combustion chamber comprises an outer layer of rhenium that provides structural support, plus an inner layer of iridium that acts as a barrier to oxidation of the rhenium. In the improved material system, the layer of iridium is thin and is coated with a thermal fatigue-resistant refractory oxide (specifically, hafnium oxide) that serves partly as a thermal barrier to decrease the temperature and thus the rate of oxidation of the rhenium. The oxide layer also acts as a barrier against the transport of oxidizing species to the surface of the iridium. Tests in which various oxygen/hydrogen mixtures were burned in iridium/rhenium combustion chambers lined with hafnium oxide showed that the operational lifetimes of combustion chambers of the improved material system are an order of magnitude greater than those of the baseline combustion chambers.

New diagnostic methods for laser plasma- and microwave-enhanced combustion

PubMed Central

Miles, Richard B; Michael, James B; Limbach, Christopher M; McGuire, Sean D; Chng, Tat Loon; Edwards, Matthew R; DeLuca, Nicholas J; Shneider, Mikhail N; Dogariu, Arthur

2015-01-01

The study of pulsed laser- and microwave-induced plasma interactions with atmospheric and higher pressure combusting gases requires rapid diagnostic methods that are capable of determining the mechanisms by which these interactions are taking place. New rapid diagnostics are presented here extending the capabilities of Rayleigh and Thomson scattering and resonance-enhanced multi-photon ionization (REMPI) detection and introducing femtosecond laser-induced velocity and temperature profile imaging. Spectrally filtered Rayleigh scattering provides a method for the planar imaging of temperature fields for constant pressure interactions and line imaging of velocity, temperature and density profiles. Depolarization of Rayleigh scattering provides a measure of the dissociation fraction, and multi-wavelength line imaging enables the separation of Thomson scattering from Rayleigh scattering. Radar REMPI takes advantage of high-frequency microwave scattering from the region of laser-selected species ionization to extend REMPI to atmospheric pressures and implement it as a stand-off detection method for atomic and molecular species in combusting environments. Femtosecond laser electronic excitation tagging (FLEET) generates highly excited molecular species and dissociation through the focal zone of the laser. The prompt fluorescence from excited molecular species yields temperature profiles, and the delayed fluorescence from recombining atomic fragments yields velocity profiles. PMID:26170432

Oxygen concentration sensor for an internal combustion engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nakajima, T.; Okada, Y.; Mieno, T.

1988-09-29

This patent describes an oxygen concentration sensor, comprising: an oxygen ion conductive solid electrolyte member forming a gas diffusion restricted region into which a measuring gas is introduced; a pair of electrodes sandwiching the solid electrolyte member; pump current supply means applying a pump voltage to the pair of electrodes through a current detection element to generate a pump current; and a heater element connected to the solid electrolyte member for heating the solid electrolyte member for heating the solid electrolyte member when a heater current is supplied from a heater current source; wherein the oxygen concentration sensor detects anmore » oxygen concentration in the measuring gas in terms of a current value of the pump current supplied through the current detection element and controls oxygen concentration in the gas diffusion restricted region by conducting oxygen ions through the solid electrolyte member in accordance to the flow of the pump current; and wherein the current detection element is connected to the electrode of the pair of electrodes facing the gas diffusion restricted region for insuring that the current value is representative of the pump current and possible leakage current from the heater current.« less

An investigation of plasma enhanced combustion

NASA Astrophysics Data System (ADS)

Kim, Woo Kyung

This study examines the use of plasma discharges in flame stabilization. Three different types of plasma discharges are applied to a lifted jet diffusion flame in coflow, and evaluated for their abilities to enhance flame stabilization. A single electrode corona discharge (SECD) is found to maintain the flame at a 20 % higher coflow speed than that without the discharge. A dielectric barrier discharge (DBD) results in flame stabilization at up to 50 % higher coflow speed. Finally, an ultra short-pulsed repetitive discharge (USRD) is found to increase the stability limit by nearly ten-fold. The stabilization process is sensitive to the positioning of the discharge in the flow field, and the optimal position of the discharge is mapped into mixture fraction space. The result shows that the local mixture fraction at the optimal position is much leaner than that of a conventional lifted jet flame. Parametric studies are conducted in a plasma-assisted methane/air premixed flame system using USRD. Criteria for optimal electrode selection are suggested. Platinum provides the best result at low frequency operation (< 20 kHz) but tungsten shows better performance at high frequency operation (> 20 kHz). The increase in the flame stability limit is also investigated. The flame stability limit extends from an equivalence ratio of 0.7 to 0.47. Nitric oxide (NO) concentration in the premixed flame is measured. The discharge is a potential source of NO. Under certain conditions, we observed the presence of a cold pre-flame, located between the discharge and the main flame. It is found that the pre-flame partially consumes some NO. The flame kernel structure and ignition mechanism of plasma-assisted premixed combustion are discussed. It is observed that the pre-flame has an abundance of OH radicals. The key physics of the flame ignition is the diffusion of an OH stream (from the pre-flame) into the surrounding combustible mixture to form the main flame. Lastly, the proposed flame

Real gas CFD simulations of hydrogen/oxygen supercritical combustion

NASA Astrophysics Data System (ADS)

Pohl, S.; Jarczyk, M.; Pfitzner, M.; Rogg, B.

2013-03-01

A comprehensive numerical framework has been established to simulate reacting flows under conditions typically encountered in rocket combustion chambers. The model implemented into the commercial CFD Code ANSYS CFX includes appropriate real gas relations based on the volume-corrected Peng-Robinson (PR) equation of state (EOS) for the flow field and a real gas extension of the laminar flamelet combustion model. The results indicate that the real gas relations have a considerably larger impact on the flow field than on the detailed flame structure. Generally, a realistic flame shape could be achieved for the real gas approach compared to experimental data from the Mascotte test rig V03 operated at ONERA when the differential diffusion processes were only considered within the flame zone.

Weakly Bound Free Radicals in Combustion: "Prompt" Dissociation of Formyl Radicals and Its Effect on Laminar Flame Speeds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Labbe, Nicole J.; Sivaramakrishnan, Raghu; Goldsmith, C. Franklin

2016-01-07

Weakly bound free radicals have low-dissociation thresholds such that at high temperatures, timescales for dissociation and collisional relaxation become comparable, leading to significant dissociation during the vibrational-rotational relaxation process. Here we characterize this “prompt” dissociation of formyl (HCO), an important combustion radical, using direct dynamics calculations for OH + CH2O and H + CH2O (key HCO-forming reactions). For all other HCO-forming reactions, presumption of a thermal incipient HCO distribution was used to derive prompt dissociation fractions. Inclusion of these theoretically derived HCO prompt dissociation fractions into combustion kinetics models provides an additional source for H-atoms that feeds chain branching reactions.more » Simulations using these updated combustion models are therefore shown to enhance flame propagation in 1,3,5-trioxane and acetylene. The present results suggest that HCO prompt dissociation should be included when simulating flames of hydrocarbons and oxygenated molecules and that prompt dissociations of other weakly bound radicals may also impact combustion simulations« less

Heater for Combustible-Gas Tanks

NASA Technical Reports Server (NTRS)

Ingle, Walter B.

1987-01-01

Proposed heater for pressurizing hydrogen, oxygen, or another combustible liquid or gas sealed in immersion cup in pressurized tank. Firmly supported in finned cup, coiled rod transfers heat through liquid metal to gas tank. Heater assembly welded or bolted to tank flange.

Low-Dose Oxygen Enhances Macrophage-Derived Bacterial Clearance following Cigarette Smoke Exposure

PubMed Central

Bain, William G.; Tripathi, Ashutosh; Mandke, Pooja; Gans, Jonathan H.; D'Alessio, Franco R.; Sidhaye, Venkataramana K.; Aggarwal, Neil R.

2016-01-01

Background. Chronic obstructive pulmonary disease (COPD) is a common, smoking-related lung disease. Patients with COPD frequently suffer disease exacerbations induced by bacterial respiratory infections, suggestive of impaired innate immunity. Low-dose oxygen is a mainstay of therapy during COPD exacerbations; yet we understand little about whether oxygen can modulate the effects of cigarette smoke on lung immunity. Methods. Wild-type mice were exposed to cigarette smoke for 5 weeks, followed by intratracheal instillation of Pseudomonas aeruginosa (PAO1) and 21% or 35–40% oxygen. After two days, lungs were harvested for PAO1 CFUs, and bronchoalveolar fluid was sampled for inflammatory markers. In culture, macrophages were exposed to cigarette smoke and oxygen (40%) for 24 hours and then incubated with PAO1, followed by quantification of bacterial phagocytosis and inflammatory markers. Results. Mice exposed to 35–40% oxygen after cigarette smoke and PAO1 had improved survival and reduced lung CFUs and inflammation. Macrophages from these mice expressed less TNF-α and more scavenger receptors. In culture, macrophages exposed to cigarette smoke and oxygen also demonstrated decreased TNF-α secretion and enhanced phagocytosis of PAO1 bacteria. Conclusions. Our findings demonstrate a novel, protective role for low-dose oxygen following cigarette smoke and bacteria exposure that may be mediated by enhanced macrophage phagocytosis. PMID:27403445

Effect of cuprous oxide with different sizes on thermal and combustion behaviors of unsaturated polyester resin.

PubMed

Hou, Yanbei; Hu, Weizhao; Gui, Zhou; Hu, Yuan

2017-07-15

Cuprous oxide (Cu 2 O) as an effective catalyst has been applied to enhance the fire safety of unsaturated polyester resin (UPR), but the particle size influence on combustion behaviors has not been previously reported. Herein, the UPR/Cu 2 O composites (metal oxide particles with average particle-size of 10, 100, and 200nm) were successfully synthesized by thermosetting process. The effects of Cu 2 O with different sizes on thermostability and combustion behaviors of UPR were characterized by TGA, MCC, TG-IR, FTIR, and SSTF. The results revel that the addition of Cu 2 O contributes to sufficient decomposition of oxygen-containing compounds, which is beneficial to the release of nontoxic compounds. The smallest-sized Cu 2 O performs the excellent catalytic decomposition effect and promotes the complete combustion of UPR, which benefits the enhancement of fire safety. While the other additives retard pyrolysis process and yield more char residue, and thus the flame retardancy of UPR composites was improved. Therefore, catalysis plays a major role for smaller-sized particles during thermal decomposition of matrix, while flame retarded effect became gradual distinctly for the larger-sized additives. Copyright © 2017 Elsevier B.V. All rights reserved.

Radiation/Catalytic Augmented Combustion.

DTIC Science & Technology

1982-05-01

enhanced combustion processes, utilizing pulsed and continuous VUV light- serces . Similarly, the catalytic technique has provided efficient combustion...tures we had a pl /cx LiF lens with a focal length of 200 nm, and a MgF2 window 2 nmn in thickness. Although these materials are considered to be among

Vacancy–Vacancy Interaction Induced Oxygen Diffusivity Enhancement in Undoped Nonstoichiometric Ceria

DOE PAGES

Yuan, Fenglin; Zhang, Yanwen; Weber, William J.

2015-05-19

In this paper, molecular dynamics simulations and molecular static calculations have been used to systematically study oxygen vacancy transport in undoped nonstoichiometric ceria. A strong oxygen diffusivity enhancement appears in the vacancy concentration range of 2–4% over the temperature range from 1000 to 2000 K. An Arrhenius ion diffusion mechanism by vacancy hopping along the (100) direction is unambiguously identified, and an increasing trend of both the oxygen migration barrier and the prefactor with increasing vacancy concentration is observed. Within the framework of classical diffusion theory, a weak concentration dependence of the prefactor in oxygen vacancy migration is shown tomore » be crucial for explaining the unusual fast oxygen ion migration in the low concentration range and consequently the appearance of a maximum in oxygen diffusivity. Finally, a representative (100) direction interaction model is constructed to identify long-range vacancy–vacancy interaction as the structural origin of the positive correlation between oxygen migration barrier and vacancy concentration.« less

Fuels and Combustion | Transportation Research | NREL

Science.gov Websites

determining if and at what levels biomass-derived oxygenates may be commercially feasible in drop-in fuels experiments examine combustion across a wide range of temperatures, pressures, and levels of dilution, and

Flash X-ray with image enhancement applied to combustion events

NASA Astrophysics Data System (ADS)

White, K. J.; McCoy, D. G.

1983-10-01

Flow visualization of interior ballistic processes by use of X-rays has placed more stringent requirements on flash X-ray techniques. The problem of improving radiographic contrast of propellants in X-ray transparent chambers was studied by devising techniques for evaluating, measuring and reducing the effects of scattering from both the test object and structures in the test area. X-ray film and processing is reviewed and techniques for evaluating and calibrating these are outlined. Finally, after X-ray techniques were optimized, the application of image enhancement processing which can improve image quality is described. This technique was applied to X-ray studies of the combustion of very high burning rate (VHBR) propellants and stick propellant charges.

Chemical looping combustion: A new low-dioxin energy conversion technology.

PubMed

Hua, Xiuning; Wang, Wei

2015-06-01

Dioxin production is a worldwide concern because of its persistence and carcinogenic, teratogenic, and mutagenic effects. The pyrolysis-chemical looping combustion process of disposing solid waste is an alternative to traditional solid waste incineration developed to reduce the dioxin production. Based on the equilibrium composition of the Deacon reaction, pyrolysis gas oxidized by seven common oxygen carriers, namely, CuO, NiO, CaSO4, CoO, Fe2O3, Mn3O4, and FeTiO3, is studied and compared with the pyrolysis gas directly combusted by air. The result shows that the activity of the Deacon reaction for oxygen carriers is lower than that for air. For four typical oxygen carriers (CuO, NiO, Fe2O3, and FeTiO3), the influences of temperature, pressure, gas composition, and tar on the Deacon reaction are discussed in detail. According to these simulation results, the dioxin production in China, Europe, the United States, and Japan is predicted for solid waste disposal by the pyrolysis-chemical looping combustion process. Thermodynamic analysis results in this paper show that chemical looping combustion can reduce dioxin production in the disposal of solid waste. Copyright © 2015. Published by Elsevier B.V.

Numerical study of influence of molecular diffusion in the Mild combustion regime

NASA Astrophysics Data System (ADS)

Mardani, Amir; Tabejamaat, Sadegh; Ghamari, Mohsen

2010-09-01

In this paper, the importance of molecular diffusion versus turbulent transport in the moderate or intense low-oxygen dilution (Mild) combustion mode has been numerically studied. The experimental conditions of Dally et al. [Proc. Combust. Inst. 29 (2002) 1147-1154] were used for modelling. The EDC model was used to describe the turbulence-chemistry interaction. The DRM-22 reduced mechanism and the GRI 2.11 full mechanism were used to represent the chemical reactions of an H2/methane jet flame. The importance of molecular diffusion for various O2 levels, jet Reynolds numbers and H2 fuel contents was investigated. Results show that the molecular diffusion in Mild combustion cannot be ignored in comparison with the turbulent transport. Also, the method of inclusion of molecular diffusion in combustion modelling has a considerable effect on the accuracy of numerical modelling of Mild combustion. By decreasing the jet Reynolds number, decreasing the oxygen concentration in the airflow or increasing H2 in the fuel mixture, the influence of molecular diffusion on Mild combustion increases.

Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO 3 Perovskites

DOE PAGES

Petrie, Jonathan R.; Cooper, Valentino R.; Freeland, John W.; ...

2016-02-11

Strain is known to greatly influence low-temperature oxygen electrocatalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and metal-air batteries. Still, its catalytic impact on transition-metal oxide thin films, such as perovskites, is not widely understood. Here, we epitaxially strain the conducting perovskite LaNiO 3 to systematically determine its influence on both the oxygen reduction and oxygen evolution reaction. Uniquely, we found that compressive strain could significantly enhance both reactions, yielding a bifunctional catalyst that surpasses the performance of noble metals such as Pt. We attribute the improved bifunctionality to strain-induced splitting ofmore » the e g orbitals, which can customize orbital asymmetry at the surface. Lastly, analogous to strain-induced shifts in the d-band center of noble metals relative to the Fermi level, such splitting can dramatically affect catalytic activity in this perovskite and other potentially more active oxides.« less

Flow Field Measurements of Methane-Oxygen Turbulent Nonpremixed Flames at High Pressure

NASA Astrophysics Data System (ADS)

Iino, Kimio; Kikkawa, Hoshitaka; Akamatsu, Fumiteru; Katsuki, Masashi

We carried out the flow field measurement of methane-oxygen turbulent nonpremixed flame in non-combusting and combusting situations at high pressures using LDV. The main objectives are to study the influences of combustion on the turbulence structure at high pressures and to provide detailed data on which numerical predictions on such flows can rely. Direct observation and CH* chemiluminescence detection are conducted at high pressures up to 1.0MPa. It was found that the flame length at elevated pressures became constant. From flow field measurements, the following features of flames at elevated pressure were found: (1) the existence of flame suppressed turbulence in the upstream region of the jet and enhanced it in the downstream region with increasing pressure; (2) Turbulence in the flame was more anisotropic than in the corresponding cold jet in all regions of the flow with increasing pressure; (3) Reynolds shear stresses did not change at elevated pressure; (4) Combustion processes had a marked influence on the turbulence macroscale under high pressures, however, the turbulence macroscale was not changed even with the increase in pressure.

Effects of Enhanced Oxygen Delivery by Perfluorocarbons in Spinal Cord Injury

DTIC Science & Technology

2013-10-01

been established, linking post- traumatic ischemia to axonal dysfunction.8 Decreased oxygen level in severe traumatic injuries appears to be implicated...rodent weight drop traumatic spinal cord injury model; ( 2 ) determine if enhanced oxygen delivery in spinal cord injury spares cellular elements, white...shown that ischemia /hypoxia play crucial role in the devastating effects of the secondary injury following SCI which translates into worse neurological

Sulfur evolution in chemical looping combustion of coal with MnFe2O4 oxygen carrier.

PubMed

Wang, Baowen; Gao, Chuchang; Wang, Weishu; Zhao, Haibo; Zheng, Chuguang

2014-05-01

Chemical looping combustion (CLC) of coal has gained increasing attention as a novel combustion technology for its advantages in CO2 capture. Sulfur evolution from coal causes great harm from either the CLC operational or environmental perspective. In this research, a combined MnFe2O4 oxygen carrier (OC) was synthesized and its reaction with a typical Chinese high sulfur coal, Liuzhi (LZ) bituminous coal, was performed in a thermogravimetric analyzer (TGA)-Fourier transform infrared (FT-IR) spectrometer. Evolution of sulfur species during reaction of LZ coal with MnFe2O4 OC was systematically investigated through experimental means combined with thermodynamic simulation. TGA-FTIR analysis of the LZ reaction with MnFe2O4 indicated MnFe2O4 exhibited the desired superior reactivity compared to the single reference oxides Mn3O4 or Fe2O3, and SO2 produced was mainly related to oxidization of H2S by MnFe2O4. Experimental analysis of the LZ coal reaction with MnFe2O4, including X-ray diffraction and X-ray photoelectron spectroscopy analysis, verified that the main reduced counterparts of MnFe2O4 were Fe3O4 and MnO, in good agreement with the related thermodynamic simulation. The obtained MnO was beneficial to stabilize the reduced MnFe2O4 and avoid serious sintering, although the oxygen in MnO was not fully utilized. Meanwhile, most sulfur present in LZ coal was converted to solid MnS during LZ reaction with MnFe2O4, which was further oxidized to MnSO4. Finally, the formation of both MnS and such manganese silicates as Mn2SiO4 and MnSiO3 should be addressed to ensure the full regeneration of the reduced MnFe2O4. Copyright © 2014 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Combustion of solid fuel slabs with gaseous oxygen in a hybrid motor analog

NASA Technical Reports Server (NTRS)

Chiaverini, Martin J.; Harting, George C.; Lu, Yeu-Cherng; Kuo, Kenneth K.; Serin, Nadir; Johnson, David K.

1995-01-01

Using a high-pressure, two-dimensional hybrid motor, an experimental investigation was conducted on fundamental processes involved in hybrid rocket combustion. HTPB (Hydroxyl-terminated Polybutadiene) fuel cross-linked with diisocyanate was burned with gaseous oxygen (GOX) under various operating conditions. Large-amplitude pressure oscillations were encountered in earlier test runs. After identifying the source of instability and decoupling the GOX feed-line system and combustion chamber, the pressure oscillations were drastically reduced from plus or minus 20% of the localized mean pressure to an acceptable range of plus or minus 1.5%. Embedded fine--wire thermocouples indicated that the surface temperature of the burning fuel was around 1000 K depending upon axial locations and operating conditions. Also, except near the leading edge region, the subsurface thermal wave profiles in the upstream locations are thicker than those in the downstream locations since the solid-fuel regression rate, in general, increases with distance along the fuel slab. The recovered solid fuel slabs in the laminar portion of the boundary layer exhibited smooth surfaces, indicating the existence of a liquid melt layer on the burning fuel surface in the upstream region. After the transition section, which displayed distinct transverse striations, the surface roughness pattern became quite random and very pronounced in the downstream turbulent boundary-layer region. Both real-time X-ray radiography and ultrasonic pulse echo techniques were used to determine the instantaneous web thicknesses and instantaneous solid-fuel regression rates over certain portions of the fuel slabs. Globally averaged and axially dependent but time-averaged regression rates were also obtained and presented. Several tests were conducted using, simultaneously, one translucent fuel slab and one fuel slab processed with carbon black powder. The addition of carbon black did not affect the measured regression rates or

Performance and Stability Characteristics of a Uni-Element Swirl Injector for Oxygen-Rich Stage Combustion Cycles

NASA Technical Reports Server (NTRS)

Pal, S.; Kalitan, D.; Woodward, R. D.; Santoro, R. J.

2004-01-01

A uni-element liquid propellant combustion performance and instability study for liquid RP-1 and hot oxygen-rich pre-burner products was conducted, at a chamber pressure of about 1000 psi. using flush and recessed swirl injectors. High-frequency pressure transducer measurements were analyzed to yield the characteristic frequencies which were compared to expected frequencies of the chamber. Modes, which were discovered to be present within the main chamber included, the first longitudinal, detected at approximately 1950 Hz, and the second longitudinal mode at approximately 3800 Hz. An additional first longitudinal quarter wave mode was measured at a frequency of approximately 23000 Hz for the recessed swirl injector configuration. The characteristic instabilities resulting from these experiments were relatively weak averaging 0.2% to 0.3% of the chamber pressure.

Controlled temperature expansion in oxygen production by molten alkali metal salts

DOEpatents

Erickson, Donald C.

1985-06-04

A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power.

Controlled temperature expansion in oxygen production by molten alkali metal salts

DOEpatents

Erickson, D.C.

1985-06-04

A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power. 1 fig.

SOFT ROBOTICS. A 3D-printed, functionally graded soft robot powered by combustion.

PubMed

Bartlett, Nicholas W; Tolley, Michael T; Overvelde, Johannes T B; Weaver, James C; Mosadegh, Bobak; Bertoldi, Katia; Whitesides, George M; Wood, Robert J

2015-07-10

Roboticists have begun to design biologically inspired robots with soft or partially soft bodies, which have the potential to be more robust and adaptable, and safer for human interaction, than traditional rigid robots. However, key challenges in the design and manufacture of soft robots include the complex fabrication processes and the interfacing of soft and rigid components. We used multimaterial three-dimensional (3D) printing to manufacture a combustion-powered robot whose body transitions from a rigid core to a soft exterior. This stiffness gradient, spanning three orders of magnitude in modulus, enables reliable interfacing between rigid driving components (controller, battery, etc.) and the primarily soft body, and also enhances performance. Powered by the combustion of butane and oxygen, this robot is able to perform untethered jumping. Copyright © 2015, American Association for the Advancement of Science.

Reactive oxygen species enhance insulin sensitivity

PubMed Central

Loh, Kim; Deng, Haiyang; Fukushima, Atsushi; Cai, Xiaochu; Boivin, Benoit; Galic, Sandra; Bruce, Clinton; Shields, Benjamin J.; Skiba, Beata; Ooms, Lisa M.; Stepto, Nigel; Wu, Ben; Mitchell, Christina A.; Tonks, Nicholas K.; Watt, Matthew J.; Febbraio, Mark A.; Crack, Peter J.; Andrikopoulos, Sofianos; Tiganis, Tony

2010-01-01

SUMMARY Chronic reactive oxygen species (ROS) production by mitochondria may contribute to the development of insulin resistance, a primary feature of type 2 diabetes. In recent years it has become apparent that ROS generation in response to physiological stimuli such as insulin may also facilitate signaling by reversibly oxidizing and inhibiting protein tyrosine phosphatases (PTPs). Here we report that mice lacking one of the key enzymes involved in the elimination of physiological ROS, glutathione peroxidase 1 (Gpx1), were protected from high fat diet-induced insulin resistance. The increased insulin sensitivity in Gpx1−/− mice was attributed to insulin-induced phosphatidylinositol-3-kinase/Akt signaling and glucose uptake in muscle and could be reversed by the anti-oxidant N-acetylcysteine. Increased insulin signaling correlated with enhanced oxidation of the PTP family member PTEN, which terminates signals generated by phosphatidylinositol-3-kinase. These studies provide causal evidence for the enhancement of insulin signaling by ROS in vivo. PMID:19808019

Droplet Combustion Experiments Aboard the International Space Station

NASA Astrophysics Data System (ADS)

Dietrich, Daniel L.; Nayagam, Vedha; Hicks, Michael C.; Ferkul, Paul V.; Dryer, Frederick L.; Farouk, Tanvir; Shaw, Benjamin D.; Suh, Hyun Kyu; Choi, Mun Y.; Liu, Yu Cheng; Avedisian, C. Thomas; Williams, Forman A.

2014-10-01

This paper summarizes the first results from isolated droplet combustion experiments performed on the International Space Station (ISS). The long durations of microgravity provided in the ISS enable the measurement of droplet and flame histories over an unprecedented range of conditions. The first experiments were with heptane and methanol as fuels, initial droplet droplet diameters between 1.5 and 5.0 m m, ambient oxygen mole fractions between 0.1 and 0.4, ambient pressures between 0.7 and 3.0 a t m and ambient environments containing oxygen and nitrogen diluted with both carbon dioxide and helium. The experiments show both radiative and diffusive extinction. For both fuels, the flames exhibited pre-extinction flame oscillations during radiative extinction with a frequency of approximately 1 H z. The results revealed that as the ambient oxygen mole fraction was reduced, the diffusive-extinction droplet diameter increased and the radiative-extinction droplet diameter decreased. In between these two limiting extinction conditions, quasi-steady combustion was observed. Another important measurement that is related to spacecraft fire safety is the limiting oxygen index (LOI), the oxygen concentration below which quasi-steady combustion cannot be supported. This is also the ambient oxygen mole fraction for which the radiative and diffusive extinction diameters become equal. For oxygen/nitrogen mixtures, the LOI is 0.12 and 0.15 for methanol and heptane, respectively. The LOI increases to approximately 0.14 (0.14 O 2/0.56 N 2/0.30 C O 2) and 0.17 (0.17 O 2/0.63 N 2/0.20 C O 2) for methanol and heptane, respectively, for ambient environments that simulated dispersing an inert-gas suppressant (carbon dioxide) into a nominally air (1.0 a t m) ambient environment. The LOI is approximately 0.14 and 0.15 for methanol and heptane, respectively, when helium is dispersed into air at 1 atm. The experiments also showed unique burning behavior for large heptane droplets. After the

Handbook of infrared radiation from combustion gases

NASA Technical Reports Server (NTRS)

Ludwig, C. B.; Malkmus, W.; Reardon, J. E.; Thomson, J. A. L.; Goulard, R. (Editor)

1973-01-01

The treatment of radiant emission and absorption by combustion gases are discussed. Typical applications include: (1) rocket combustion chambers and exhausts, (2) turbojet engines and exhausts, and (3) industrial furnaces. Some mention is made of radiant heat transfer problems in planetary atmospheres, in stellar atmospheres, and in reentry plasmas. Particular consideration is given to the temperature range from 500K to 3000K and the pressure range from 0.001 atmosphere to 30 atmospheres. Strong emphasis is given to the combustion products of hydrocarbon fuels with oxygen, specifically to carbon dioxide, water vapor, and carbon monoxide. In addition, species such as HF, HC1, CN, OH, and NO are treated.

Oxygen "getter" effects on microstructure and carrier transport in low temperature combustion-processed a-InXZnO (X = Ga, Sc, Y, La) transistors.

PubMed

Hennek, Jonathan W; Smith, Jeremy; Yan, Aiming; Kim, Myung-Gil; Zhao, Wei; Dravid, Vinayak P; Facchetti, Antonio; Marks, Tobin J

2013-07-24

In oxide semiconductors, such as those based on indium zinc oxide (IXZO), a strong oxygen binding metal ion ("oxygen getter"), X, functions to control O vacancies and enhance lattice formation, hence tune carrier concentration and transport properties. Here we systematically study, in the IXZO series, the role of X = Ga(3+) versus the progression X = Sc(3+) → Y(3+) → La(3+), having similar chemical characteristics but increasing ionic radii. IXZO films are prepared from solution over broad composition ranges for the first time via low-temperature combustion synthesis. The films are characterized via thermal analysis of the precursor solutions, grazing incidence angle X-ray diffraction (GIAXRD), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and scanning transmission electron microscopy (STEM) with high angle annular dark field (HAADF) imaging. Excellent thin-film transistor (TFT) performance is achieved for all X, with optimal compositions after 300 °C processing exhibiting electron mobilities of 5.4, 2.6, 2.4, and 1.8 cm(2) V(-1) s(-1) for Ga(3+), Sc(3+), Y(3+), and La(3+), respectively, and with I(on)/I(off) = 10(7)-10(8). Analysis of the IXZO TFT positive bias stress response shows X = Ga(3+) to be superior with mobilities (μ) retaining >95% of the prestress values and threshold voltage shifts (ΔV(T)) of <1.6 V, versus <85% μ retention and ΔV(T) ≈ 20 V for the other trivalent ions. Detailed microstructural analysis indicates that Ga(3+) most effectively promotes oxide lattice formation. We conclude that the metal oxide lattice formation enthalpy (ΔH(L)) and metal ionic radius are the best predictors of IXZO oxygen getter efficacy.

Apparatus for photocatalytic destruction of internal combustion engine emissions during cold start

DOEpatents

Janata, Jiri; McVay, Gary L.; Peden, Charles H.; Exarhos, Gregory J.

1998-01-01

A method and apparatus for the destruction of emissions from an internal combustion engine wherein a substrate coated with TiO.sub.2 is exposed to a light source in the exhaust system of an internal combustion engine thereby catalyzing oxidation/reduction reactions between gaseous hydrocarbons, carbon monoxide, nitrogen oxides and oxygen in the exhaust of the internal combustion engine.

Oxygen Compatibility of Brass-Filled PTFE Compared to Commonly Used Fluorinated Polymers for Oxygen Systems

NASA Technical Reports Server (NTRS)

Herald, Stephen D.; Frisby, Paul M.; Davis, Samuel Eddie

2009-01-01

Safe and reliable seal materials for high-pressure oxygen systems sometimes appear to be extinct species when sought out by oxygen systems designers. Materials that seal well are easy to find, but these materials are typically incompatible with oxygen, especially in cryogenic liquid form. This incompatibility can result in seals that leak, or much worse, seals that easily ignite and burn during use. Materials that are compatible with oxygen are easy to find, such as the long list of compatible metals, but these metallic materials are limiting as seal materials. A material that seals well and is oxygen compatible has been the big game in the designer's safari. Scientists at the Materials Combustion Research Facility (MCRF), part of NASA/Marshall Space Flight Center (MSFC), are constantly searching for better materials and processes to improve the safety of oxygen systems. One focus of this effort is improving the characteristics of polymers used in the presence of an oxygen enriched environment. Very few systems can be built which contain no polymeric materials; therefore, materials which have good impact resistance, low heat of combustion, high auto-ignition temperature and that maintain good mechanical properties are essential. The scientists and engineers at the Materials Combustion Research Facility, in cooperation with seal suppliers, are currently testing a new formulation of polytetrafluoroethylene (PTFE) with Brass filler. This Brass-filled PTFE is showing great promise as a seal and seat material for high pressure oxygen systems. Early research has demonstrated very encouraging results, which could rank this material as one of the best fluorinated polymers ever tested. This paper will compare the data obtained for Brass-filled PTFE with other fluorinated polymers, such as TFE-Teflon (PTFE) , Kel-F 81, Viton A, Viton A-500, Fluorel , and Algoflon . A similar metal filled fluorinated polymer, Salox-M , was tested in comparison to Brass-filled PTFE to

Method and system for the removal of oxides of nitrogen and sulfur from combustion processes

DOEpatents

Walsh, John V.

1987-12-15

A process for removing oxide contaminants from combustion gas, and employing a solid electrolyte reactor, includes: (a) flowing the combustion gas into a zone containing a solid electrolyte and applying a voltage and at elevated temperature to thereby separate oxygen via the solid electrolyte, (b) removing oxygen from that zone in a first stream and removing hot effluent gas from that zone in a second stream, the effluent gas containing contaminant, (c) and pre-heating the combustion gas flowing to that zone by passing it in heat exchange relation with the hot effluent gas.

Microgravity Smoldering Combustion Takes Flight

NASA Technical Reports Server (NTRS)

1996-01-01

The Microgravity Smoldering Combustion (MSC) experiment lifted off aboard the Space Shuttle Endeavour in September 1995 on the STS-69 mission. This experiment is part of series of studies focused on the smolder characteristics of porous, combustible materials in a microgravity environment. Smoldering is a nonflaming form of combustion that takes place in the interior of combustible materials. Common examples of smoldering are nonflaming embers, charcoal briquettes, and cigarettes. The objective of the study is to provide a better understanding of the controlling mechanisms of smoldering, both in microgravity and Earth gravity. As with other forms of combustion, gravity affects the availability of air and the transport of heat, and therefore, the rate of combustion. Results of the microgravity experiments will be compared with identical experiments carried out in Earth's gravity. They also will be used to verify present theories of smoldering combustion and will provide new insights into the process of smoldering combustion, enhancing our fundamental understanding of this frequently encountered combustion process and guiding improvement in fire safety practices.

The Use of Molecular Oxygen in Pharmaceutical Manufacturing: Is Flow the Way to Go?

PubMed

Hone, Christopher A; Roberge, Dominique M; Kappe, C Oliver

2017-01-10

Molecular oxygen is arguably the greenest reagent available to the organic chemist. Most commonly, a diluted form of oxygen gas, consisting of less than 10 % O 2 in N 2 ("synthetic air"), is used in pharmaceutical and fine chemical batch manufacturing to effectively address safety concerns when handling molecular oxygen. Concentrations of O 2 in N 2 below 10 % are generally required to prevent the risk of combustions in the presence of flammable organic solvents ("limiting oxygen concentration"). Nonetheless, the use of pure oxygen is more efficient than using O 2 diluted with N 2 and can often provide enhanced reaction rates, resulting in significant improvements in product quality and process efficiency. This Concept takes into account recent studies to make the argument that, for liquid-phase aerobic oxidations, pure oxygen can indeed be handled safely on large scale by employing continuous-flow reactors, while also providing highly convincing synthetic and manufacturing benefits. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Performance of PAHs emission from bituminous coal combustion.

PubMed

Yan, Jian-Hua; You, Xiao-Fang; Li, Xiao-Dong; Ni, Ming-Jiang; Yin, Xue-Feng; Cen, Ke-Fa

2004-12-01

Carcinogenic and mutagenic polycyclic aromatic hydrocarbons (PAHs) generated in coal combustion have caused great environmental health concern. Seventeen PAHs (16 high priority PAHs recommended by USEPA plus Benzo[e]pyrene) present in five raw bituminous coals and released during bituminous coal combustion were studied. The effects of combustion temperature, gas atmosphere, and chlorine content of raw coal on PAHs formation were investigated. Two additives (copper and cupric oxide) were added when the coal was burned. The results indicated that significant quantities of PAHs were produced from incomplete combustion of coal pyrolysis products at high temperature, and that temperature is an important causative factor of PAHs formation. PAHs concentrations decrease with the increase of chlorine content in oxygen or in nitrogen atmosphere. Copper and cupric oxide additives can promote PAHs formation (especially the multi-ring PAHs) during coal combustion.

Droplet Combustion Experiment Operates

NASA Technical Reports Server (NTRS)

2003-01-01

Fuel ignites and burns in the Droplet Combustion Experiment (DCE) on STS-94 on July 12, 1997, MET:11/07:00 (approximate). DCE used various fuels -- in drops ranging from 1 mm (0.04 inches) to 5 mm (0.2 inches) -- and mixtures of oxidizers and inert gases to learn more about the physics of combustion in the simplest burning configuration, a sphere. The DCE was designed to investigate the fundamental combustion aspects of single, isolated droplets under different pressures and ambient oxygen concentrations for a range of droplet sizes varying between 2 and 5 mm. The experiment elapsed time is shown at the bottom of the composite image. The DCE principal investigator was Forman Williams, University of California, San Diego. The experiment was part of the space research investigations conducted during the Microgravity Science Laboratory-1R mission (STS-94, July 1-17 1997). Advanced combustion experiments will be a part of investigations plarned for the International Space Station. (119KB JPEG, 658 x 982 pixels; downlinked video, higher quality not available) The MPG from which this composite was made is available at http://mix.msfc.nasa.gov/ABSTRACTS/MSFC-0300171.html.

Radio-frequency oxygen-plasma-enhanced pulsed laser deposition of IGZO films

NASA Astrophysics Data System (ADS)

Chou, Chia-Man; Lai, Chih-Chang; Chang, Chih-Wei; Wen, Kai-Shin; Hsiao, Vincent K. S.

2017-07-01

We demonstrate the crystalline structures, optical transmittance, surface and cross-sectional morphologies, chemical compositions, and electrical properties of indium gallium zinc oxide (IGZO)-based thin films deposited on glass and silicon substrates through pulsed laser deposition (PLD) incorporated with radio-frequency (r.f.)-generated oxygen plasma. The plasma-enhanced pulsed laser deposition (PEPLD)-based IGZO thin films exhibited a c-axis-aligned crystalline (CAAC) structure, which was attributed to the increase in Zn-O under high oxygen vapor pressure (150 mTorr). High oxygen vapor pressure (150 mTorr) and low r.f. power (10 W) are the optimal deposition conditions for fabricating IGZO thin films with improved electrical properties.

Combustion process for synthesis of carbon nanomaterials from liquid hydrocarbon

DOEpatents

Diener, Michael D.; Alford, J. Michael; Nabity, James; Hitch, Bradley D.

2007-01-02

The present invention provides a combustion apparatus for the production of carbon nanomaterials including fullerenes and fullerenic soot. Most generally the combustion apparatus comprises one or more inlets for introducing an oxygen-containing gas and a hydrocarbon fuel gas in the combustion system such that a flame can be established from the mixed gases, a droplet delivery apparatus for introducing droplets of a liquid hydrocarbon feedstock into the flame, and a collector apparatus for collecting condensable products containing carbon nanomaterials that are generated in the combustion system. The combustion system optionally has a reaction zone downstream of the flame. If this reaction zone is present the hydrocarbon feedstock can be introduced into the flame, the reaction zone or both.

Vapor hydrogen and oxygen isotopes reflect water of combustion in the urban atmosphere.

PubMed

Gorski, Galen; Strong, Courtenay; Good, Stephen P; Bares, Ryan; Ehleringer, James R; Bowen, Gabriel J

2015-03-17

Anthropogenic modification of the water cycle involves a diversity of processes, many of which have been studied intensively using models and observations. Effective tools for measuring the contribution and fate of combustion-derived water vapor in the atmosphere are lacking, however, and this flux has received relatively little attention. We provide theoretical estimates and a first set of measurements demonstrating that water of combustion is characterized by a distinctive combination of H and O isotope ratios. We show that during periods of relatively low humidity and/or atmospheric stagnation, this isotopic signature can be used to quantify the concentration of water of combustion in the atmospheric boundary layer over Salt Lake City. Combustion-derived vapor concentrations vary between periods of atmospheric stratification and mixing, both on multiday and diurnal timescales, and respond over periods of hours to variations in surface emissions. Our estimates suggest that up to 13% of the boundary layer vapor during the period of study was derived from combustion sources, and both the temporal pattern and magnitude of this contribution were closely reproduced by an independent atmospheric model forced with a fossil fuel emissions data product. Our findings suggest potential for water vapor isotope ratio measurements to be used in conjunction with other tracers to refine the apportionment of urban emissions, and imply that water vapor emissions associated with combustion may be a significant component of the water budget of the urban boundary layer, with potential implications for urban climate, ecohydrology, and photochemistry.

Apparatus for photocatalytic destruction of internal combustion engine emissions during cold start

DOEpatents

Janata, J.; McVay, G.L.; Peden, C.H.; Exarhos, G.J.

1998-07-14

A method and apparatus are disclosed for the destruction of emissions from an internal combustion engine wherein a substrate coated with TiO{sub 2} is exposed to a light source in the exhaust system of an internal combustion engine thereby catalyzing oxidation/reduction reactions between gaseous hydrocarbons, carbon monoxide, nitrogen oxides and oxygen in the exhaust of the internal combustion engine. 4 figs.

Toxic-Waste Disposal by Combustion in Containers

NASA Technical Reports Server (NTRS)

Houseman, J.; Stephens, J. B.; Moynihan, P. I.; Compton, L. E.; Kalvinskas, J. J.

1986-01-01

Chemical wastes burned with minimal handling in storage containers. Technique for disposing of chemical munitions by burning them inside shells applies to disposal of toxic materials stored in drums. Fast, economical procedure overcomes heat-transfer limitations of conventional furnace designs by providing direct contact of oxygenrich combustion gases with toxic agent. No need to handle waste material, and container also decontaminated in process. Oxygen-rich torch flame cuts burster well and causes vaporization and combustion of toxic agent contained in shell.

Advanced research and technology program for advanced high pressure oxygen-hydrogen rocket propulsion

NASA Technical Reports Server (NTRS)

Marsik, S. J.; Morea, S. F.

1985-01-01

A research and technology program for advanced high pressure, oxygen-hydrogen rocket propulsion technology is presently being pursued by the National Aeronautics and Space Administration (NASA) to establish the basic discipline technologies, develop the analytical tools, and establish the data base necessary for an orderly evolution of the staged combustion reusable rocket engine. The need for the program is based on the premise that the USA will depend on the Shuttle and its derivative versions as its principal Earth-to-orbit transportation system for the next 20 to 30 yr. The program is focused in three principal areas of enhancement: (1) life extension, (2) performance, and (3) operations and diagnosis. Within the technological disciplines the efforts include: rotordynamics, structural dynamics, fluid and gas dynamics, materials fatigue/fracture/life, turbomachinery fluid mechanics, ignition/combustion processes, manufacturing/producibility/nondestructive evaluation methods and materials development/evaluation. An overview of the Advanced High Pressure Oxygen-Hydrogen Rocket Propulsion Technology Program Structure and Working Groups objectives are presented with highlights of several significant achievements.

Advanced research and technology programs for advanced high-pressure oxygen-hydrogen rocket propulsion

NASA Technical Reports Server (NTRS)

Marsik, S. J.; Morea, S. F.

1985-01-01

A research and technology program for advanced high pressure, oxygen-hydrogen rocket propulsion technology is presently being pursued by the National Aeronautics and Space Administration (NASA) to establish the basic discipline technologies, develop the analytical tools, and establish the data base necessary for an orderly evolution of the staged combustion reusable rocket engine. The need for the program is based on the premise that the USA will depend on the Shuttle and its derivative versions as its principal Earth-to-orbit transportation system for the next 20 to 30 yr. The program is focused in three principal areas of enhancement: (1) life extension, (2) performance, and (3) operations and diagnosis. Within the technological disciplines the efforts include: rotordynamics, structural dynamics, fluid and gas dynamics, materials fatigue/fracture/life, turbomachinery fluid mechanics, ignition/combustion processes, manufacturing/producibility/nondestructive evaluation methods and materials development/evaluation. An overview of the Advanced High Pressure Oxygen-Hydrogen Rocket Propulsion Technology Program Structure and Working Groups objectives are presented with highlights of several significant achievements.

Advanced research and technology programs for advanced high-pressure oxygen-hydrogen rocket propulsion

NASA Astrophysics Data System (ADS)

Marsik, S. J.; Morea, S. F.

1985-03-01

A research and technology program for advanced high pressure, oxygen-hydrogen rocket propulsion technology is presently being pursued by the National Aeronautics and Space Administration (NASA) to establish the basic discipline technologies, develop the analytical tools, and establish the data base necessary for an orderly evolution of the staged combustion reusable rocket engine. The need for the program is based on the premise that the USA will depend on the Shuttle and its derivative versions as its principal Earth-to-orbit transportation system for the next 20 to 30 yr. The program is focused in three principal areas of enhancement: (1) life extension, (2) performance, and (3) operations and diagnosis. Within the technological disciplines the efforts include: rotordynamics, structural dynamics, fluid and gas dynamics, materials fatigue/fracture/life, turbomachinery fluid mechanics, ignition/combustion processes, manufacturing/producibility/nondestructive evaluation methods and materials development/evaluation. An overview of the Advanced High Pressure Oxygen-Hydrogen Rocket Propulsion Technology Program Structure and Working Groups objectives are presented with highlights of several significant achievements.

Fluidized-bed calciner with combustion nozzle and shroud

DOEpatents

Wielang, Joseph A.; Palmer, William B.; Kerr, William B.

1977-01-01

A nozzle employed as a burner within a fluidized bed is coaxially enclosed within a tubular shroud that extends beyond the nozzle length into the fluidized bed. The open-ended shroud portion beyond the nozzle end provides an antechamber for mixture and combustion of atomized fuel with an oxygen-containing gas. The arrangement provides improved combustion efficiency and excludes bed particles from the high-velocity, high-temperature portions of the flame to reduce particle attrition.

Oil shale retorting and combustion system

DOEpatents

Pitrolo, Augustine A.; Mei, Joseph S.; Shang, Jerry Y.

1983-01-01

The present invention is directed to the extraction of energy values from l shale containing considerable concentrations of calcium carbonate in an efficient manner. The volatiles are separated from the oil shale in a retorting zone of a fluidized bed where the temperature and the concentration of oxygen are maintained at sufficiently low levels so that the volatiles are extracted from the oil shale with minimal combustion of the volatiles and with minimal calcination of the calcium carbonate. These gaseous volatiles and the calcium carbonate flow from the retorting zone into a freeboard combustion zone where the volatiles are burned in the presence of excess air. In this zone the calcination of the calcium carbonate occurs but at the expense of less BTU's than would be required by the calcination reaction in the event both the retorting and combustion steps took place simultaneously. The heat values in the products of combustion are satisfactorily recovered in a suitable heat exchange system.

Effects of streamwise vortex breakdown on supersonic combustion.

PubMed

Hiejima, Toshihiko

2016-04-01

This paper presents a numerical simulation study of the combustion structure of streamwise vortex breakdown at Mach number 2.48. Hydrogen fuel is injected into a combustor at sonic speed from the rear of a hypermixer strut that can generate streamwise vortices. The results show that the burning behavior is enhanced at the points of the shock waves that are incident on the vortex and therefore the vortex breakdown in the subsonic region occurs due to combustion. The breakdown domain in the mainstream is found to form a flame-holding region suited to combustion and to lead to a stable combustion field with detached flames. In this way, streamwise vortex breakdown has an essential role in combustion enhancement and the formation of flames that hold under supersonic inflow conditions. Finally, the combustion property defined here is shown to coincide with the produced-water mass flow. This property shows that the amount of combustion is saturated at equivalence ratios over 0.4, although there is a slight increase beyond 1.

Solid waste management of a chemical-looping combustion plant using Cu-based oxygen carriers.

PubMed

García-Labiano, Francisco; Gayán, Pilar; Adánez, Juan; De Diego, Luis F; Forero, Carmen R

2007-08-15

Waste management generated from a Chemical-Looping Combustion (CLC) plant using copper-based materials is analyzed by two ways: the recovery and recycling of the used material and the disposal of the waste. A copper recovery process coupled to the CLC plant is proposed to avoid the loss of active material generated by elutriation from the system. Solid residues obtained from a 10 kWth CLC prototype operated during 100 h with a CuO-Al2O3 oxygen carrier prepared by impregnation were used as raw material in the recovery process. Recovering efficiencies of approximately 80% were obtained in the process, where the final products were an eluate of Cu(NO3)2 and a solid. The eluate was used for preparation of new oxygen carriers by impregnation, which exhibited high reactivity for reduction and oxidation reactions as well as adequate physical and chemical properties to be used in a CLC plant. The proposed recovery process largely decreases the amount of natural resources (Cu and Al203) employed in a CLC power plant as well as the waste generated in the process. To determine the stability of the different solid streams during deposition in a landfill, these were characterized with respect to their leaching behavior according to the European Union normative. The solid residue finally obtained in the CLC plant coupled to the recovery process (composed by Al2O3 and CuAl2O4) can be classified as a stable nonreactive hazardous waste acceptable at landfills for nonhazardous wastes.

Vapor hydrogen and oxygen isotopes reflect water of combustion in the urban atmosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gorski, Galen; Strong, Courtenay; Good, Stephen P.

Anthropogenic modification of the water cycle involves a diversity of processes, many of which have been studied intensively using models and observations. Some effective tools for measuring the contribution and fate of combustion-derived water vapor in the atmosphere are lacking, however, and this flux has received relatively little attention. We provide theoretical estimates and a first set of measurements demonstrating that water of combustion is characterized by a distinctive combination of H and O isotope ratios. Furthermore, we show that during periods of relatively low humidity and/or atmospheric stagnation, this isotopic signature can be used to quantify the concentration ofmore » water of combustion in the atmospheric boundary layer over Salt Lake City. Combustion-derived vapor concentrations vary between periods of atmospheric stratification and mixing, both on multiday and diurnal timescales, and respond over periods of hours to variations in surface emissions. Our estimates suggest that up to 13% of the boundary layer vapor during the period of study was derived from combustion sources, and both the temporal pattern and magnitude of this contribution were closely reproduced by an independent atmospheric model forced with a fossil fuel emissions data product. These findings suggest potential for water vapor isotope ratio measurements to be used in conjunction with other tracers to refine the apportionment of urban emissions, and imply that water vapor emissions associated with combustion may be a significant component of the water budget of the urban boundary layer, with potential implications for urban climate, ecohydrology, and photochemistry.« less

Vapor hydrogen and oxygen isotopes reflect water of combustion in the urban atmosphere

DOE PAGES

Gorski, Galen; Strong, Courtenay; Good, Stephen P.; ...

2015-03-02

Anthropogenic modification of the water cycle involves a diversity of processes, many of which have been studied intensively using models and observations. Some effective tools for measuring the contribution and fate of combustion-derived water vapor in the atmosphere are lacking, however, and this flux has received relatively little attention. We provide theoretical estimates and a first set of measurements demonstrating that water of combustion is characterized by a distinctive combination of H and O isotope ratios. Furthermore, we show that during periods of relatively low humidity and/or atmospheric stagnation, this isotopic signature can be used to quantify the concentration ofmore » water of combustion in the atmospheric boundary layer over Salt Lake City. Combustion-derived vapor concentrations vary between periods of atmospheric stratification and mixing, both on multiday and diurnal timescales, and respond over periods of hours to variations in surface emissions. Our estimates suggest that up to 13% of the boundary layer vapor during the period of study was derived from combustion sources, and both the temporal pattern and magnitude of this contribution were closely reproduced by an independent atmospheric model forced with a fossil fuel emissions data product. These findings suggest potential for water vapor isotope ratio measurements to be used in conjunction with other tracers to refine the apportionment of urban emissions, and imply that water vapor emissions associated with combustion may be a significant component of the water budget of the urban boundary layer, with potential implications for urban climate, ecohydrology, and photochemistry.« less

Vapor hydrogen and oxygen isotopes reflect water of combustion in the urban atmosphere

PubMed Central

Gorski, Galen; Strong, Courtenay; Good, Stephen P.; Bares, Ryan; Ehleringer, James R.; Bowen, Gabriel J.

2015-01-01

Anthropogenic modification of the water cycle involves a diversity of processes, many of which have been studied intensively using models and observations. Effective tools for measuring the contribution and fate of combustion-derived water vapor in the atmosphere are lacking, however, and this flux has received relatively little attention. We provide theoretical estimates and a first set of measurements demonstrating that water of combustion is characterized by a distinctive combination of H and O isotope ratios. We show that during periods of relatively low humidity and/or atmospheric stagnation, this isotopic signature can be used to quantify the concentration of water of combustion in the atmospheric boundary layer over Salt Lake City. Combustion-derived vapor concentrations vary between periods of atmospheric stratification and mixing, both on multiday and diurnal timescales, and respond over periods of hours to variations in surface emissions. Our estimates suggest that up to 13% of the boundary layer vapor during the period of study was derived from combustion sources, and both the temporal pattern and magnitude of this contribution were closely reproduced by an independent atmospheric model forced with a fossil fuel emissions data product. Our findings suggest potential for water vapor isotope ratio measurements to be used in conjunction with other tracers to refine the apportionment of urban emissions, and imply that water vapor emissions associated with combustion may be a significant component of the water budget of the urban boundary layer, with potential implications for urban climate, ecohydrology, and photochemistry. PMID:25733906

Carbon deposition model for oxygen-hydrocarbon combustion. Task 6: Data analysis and formulation of an empirical model

NASA Technical Reports Server (NTRS)

Makel, Darby B.; Rosenberg, Sanders D.

1990-01-01

The formation and deposition of carbon (soot) was studied in the Carbon Deposition Model for Oxygen-Hydrocarbon Combustion Program. An empirical, 1-D model for predicting soot formation and deposition in LO2/hydrocarbon gas generators/preburners was derived. The experimental data required to anchor the model were identified and a test program to obtain the data was defined. In support of the model development, cold flow mixing experiments using a high injection density injector were performed. The purpose of this investigation was to advance the state-of-the-art in LO2/hydrocarbon gas generator design by developing a reliable engineering model of gas generator operation. The model was formulated to account for the influences of fluid dynamics, chemical kinetics, and gas generator hardware design on soot formation and deposition.

Methane combustion reactivity during the metal→metallic oxide transformation of Pd-Pt catalysts: Effect of oxygen pressure

NASA Astrophysics Data System (ADS)

Qi, Wenjie; Ran, Jingyu; Zhang, Zhien; Niu, Juntian; Zhang, Peng; Fu, Lijuan; Hu, Bo; Li, Qilai

2018-03-01

Density functional theory combined with kinetic models were used to probe different kinetics consequences by which methane activation on different oxygen chemical potential surfaces as oxygen pressure increased. The metallic oxide → metal transformation temperature of Pd-Pt catalysts increased with the increase of the Pd content or/and O2 pressure. The methane conversion rate on Pt catalyst increased and then decreased to a constant value when increasing the O2 pressure, and Pd catalyst showed a poor activity performance in the case of low O2 pressure. Moreover, its activity increased as the oxygen chemical potential for O2 pressure increased in the range of 2.5-10 KPa. For metal clusters, the Csbnd H bond and Odbnd O bond activation steps occurred predominantly on *-* site pairs. The methane conversion rate was determined by O2 pressure because the adsorbed O atoms were rapidly consumed by other adsorbed species in this kinetic regime. As the O2 pressure increased, the metallic active sites for methane activation were decreased and there was no longer lack of adsorbed O atoms, resulting in the decrease of the methane conversion rate. Furthermore, when the metallic surfaces were completely covered by adsorbed oxygen atoms at higher oxygen chemical potentials, Pt catalyst showed a poor activity due to a high Csbnd H bond activation barrier on O*sbnd O*. In the case of high O2 pressure, Pd atoms preferred to segregate to the active surface of Pd-Pt catalysts, leading to the formation of PdO surfaces. The increase of Pd segregation promoted a subsequent increase in active sites and methane conversion rate. The PdO was much more active than metallic and O* saturated surfaces for methane activation, inferred from the theory and experimental study. Pd-rich bimetallic catalyst (75% molar Pd) showed a dual high methane combustion activity on O2-poor and O2-rich conditions.

Simultaneous identification of multi-combustion-intermediates of alkanol-air flames by femtosecond filament excitation for combustion sensing

PubMed Central

Li, Helong; Chu, Wei; Xu, Huailiang; Cheng, Ya; Chin, See-Leang; Yamanouchi, Kaoru; Sun, Hong-Bo

2016-01-01

Laser filamentation produced by the propagation of intense laser pulses in flames is opening up new possibility in application to combustion diagnostics that can provide useful information on understanding combustion processes, enhancing combustion efficiency and reducing pollutant products. Here we present simultaneous identification of multiple combustion intermediates by femtosecond filament excitation for five alkanol-air flames fueled by methanol, ethanol, n-propanol, n-butanol, and n-pentanol. We experimentally demonstrate that the intensities of filament-induced photoemission signals from the combustion intermediates C, C2, CH, CN increase with the increasing number of carbons in the fuel molecules, and the signal ratios between the intermediates (CH/C, CH/C2, CN/C, CH/C2, CN/CH) are different for different alkanol combustion flames. Our observation provides a way for sensing multiple combustion components by femtosecond filament excitation in various combustion conditions that strongly depend on the fuel species. PMID:27250021

Simultaneous identification of multi-combustion-intermediates of alkanol-air flames by femtosecond filament excitation for combustion sensing.

PubMed

Li, Helong; Chu, Wei; Xu, Huailiang; Cheng, Ya; Chin, See-Leang; Yamanouchi, Kaoru; Sun, Hong-Bo

2016-06-02

Laser filamentation produced by the propagation of intense laser pulses in flames is opening up new possibility in application to combustion diagnostics that can provide useful information on understanding combustion processes, enhancing combustion efficiency and reducing pollutant products. Here we present simultaneous identification of multiple combustion intermediates by femtosecond filament excitation for five alkanol-air flames fueled by methanol, ethanol, n-propanol, n-butanol, and n-pentanol. We experimentally demonstrate that the intensities of filament-induced photoemission signals from the combustion intermediates C, C2, CH, CN increase with the increasing number of carbons in the fuel molecules, and the signal ratios between the intermediates (CH/C, CH/C2, CN/C, CH/C2, CN/CH) are different for different alkanol combustion flames. Our observation provides a way for sensing multiple combustion components by femtosecond filament excitation in various combustion conditions that strongly depend on the fuel species.

Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson

2011-12-22

The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnacemore » (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for

Method for providing oxygen ion vacancies in lanthanide oxides

DOEpatents

Kay, D. Alan R.; Wilson, William G.

1989-12-05

A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

Microgravity Combustion Diagnostics Workshop

NASA Technical Reports Server (NTRS)

Santoro, Gilbert J. (Editor); Greenberg, Paul S. (Editor); Piltch, Nancy D. (Editor)

1988-01-01

Through the Microgravity Science and Applications Division (MSAD) of the Office of Space Science and Applications (OSSA) at NASA Headquarters, a program entitled, Advanced Technology Development (ATD) was promulgated with the objective of providing advanced technologies that will enable the development of future microgravity science and applications experimental flight hardware. Among the ATD projects one, Microgravity Combustion Diagnostics (MCD), has the objective of developing advanced diagnostic techniques and technologies to provide nonperturbing measurements of combustion characteristics and parameters that will enhance the scientific integrity and quality of microgravity combustion experiments. As part of the approach to this project, a workshop was held on July 28 and 29, 1987, at the NASA Lewis Research Center. A small group of laser combustion diagnosticians met with a group of microgravity combustion experimenters to discuss the science requirements, the state-of-the-art of laser diagnostic technology, and plan the direction for near-, intermediate-, and long-term programs. This publication describes the proceedings of that workshop.

[Catalytic performance of Ce/Zr series catalysts on soot combustion].

PubMed

Zhu, Ling; Wang, Xue-Zhong; Hao, Zheng-Ping

2005-09-01

Catalytic performances of Ce/Zr series catalysts (Ce(x)Zr(1-x)O2) on soot combustion and the influence of feed gas were investigated by TG and TPO. The catalytic activity is high, and affects by the Ce/Zr ratio. The concentration of O2 affects the speed-limited step during the process of soot combustion. H2O showed no effect on the catalytic activity for soot combustion on Ce(0.5)Zr(0.5)O2. NO could promote soot combustion by presenting NO2, a more powerful oxidant than O2, and the ignition temperature of soot decreased 30 degrees C. Results of TG and TPO show that the beta species oxygen on the catalyst take part in the combustion process.

Combustion of solid carbon rods in zero and normal gravity

NASA Technical Reports Server (NTRS)

Spuckler, C. M.; Kohl, F. J.; Miller, R. A.; Stearns, C. A.; Dewitt, K. J.

1979-01-01

In order to investigate the mechanism of carbon combustion, spectroscopic carbon rods were resistance ignited and burned in an oxygen environment in normal and zero gravity. Direct mass spectrometric sampling was used in the normal gravity tests to obtain concentration profiles of CO2, CO, and O2 as a function of distance from the carbon surface. The experimental concentrations were compared to those predicted by a stagnant film model. Zero gravity droptower tests were conducted in order to assess the effect of convection on the normal gravity combustion process. The ratio of flame diameter to rod diameter as a function of time for oxygen pressures of 5, 10, 15, and 20 psia was obtained for three different diameter rods. It was found that this ratio was inversely proportional to both the oxygen pressure and the rod diameter.

Oxygen Vacancies in ZnO Nanosheets Enhance CO2 Electrochemical Reduction to CO.

PubMed

Geng, Zhigang; Kong, Xiangdong; Chen, Weiwei; Su, Hongyang; Liu, Yan; Cai, Fan; Wang, Guoxiong; Zeng, Jie

2018-05-22

As electron transfer to CO 2 is generally considered to be the critical step during the activation of CO 2 , it is important to develop approaches to engineer the electronic properties of catalysts to improve their performance in CO 2 electrochemical reduction. Herein, we developed an efficient strategy to facilitate CO 2 activation by introducing oxygen vacancies into electrocatalysts with electronic-rich surface. ZnO nanosheets rich in oxygen vacancies exhibited a current density of -16.1 mA cm -2 with a Faradaic efficiency of 83 % for CO production. Based on density functional theory (DFT) calculations, the introduction of oxygen vacancies increased the charge density of ZnO around the valence band maximum, resulting in the enhanced activation of CO 2 . Mechanistic studies further revealed that the enhancement of CO production by introducing oxygen vacancies into ZnO nanosheets originated from the increased binding strength of CO 2 and the eased CO 2 activation. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Highly time-resolved imaging of combustion and pyrolysis product concentrations in solid fuel combustion: NO formation in a burning cigarette.

PubMed

Zimmermann, Ralf; Hertz-Schünemann, Romy; Ehlert, Sven; Liu, Chuan; McAdam, Kevin; Baker, Richard; Streibel, Thorsten

2015-02-03

The highly dynamic, heterogeneous combustion process within a burning cigarette was investigated by a miniaturized extractive sampling probe (microprobe) coupled to photoionization mass spectrometry using soft laser single photon ionization (SPI) for online real-time detection of molecular ions of combustion and pyrolysis products. Research cigarettes smoked by a smoking machine are used as a reproducible model system for solid-state biomass combustion, which up to now is not addressable by current combustion-diagnostic tools. By combining repetitively recorded online measurement sequences from different sampling locations in an imaging approach, highly time- and space-resolved quantitative distribution maps of, e.g., nitrogen monoxide, benzene, and oxygen concentrations were obtained at a near microscopic level. The obtained quantitative distribution maps represent a time-resolved, movie-like imaging of the respective compound's formation and destruction zones in the various combustion and pyrolysis regions of a cigarette during puffing. Furthermore, spatially resolved kinetic data were ascertainable. The here demonstrated methodology can also be applied to various heterogenic combustion/pyrolysis or reaction model systems, such as fossil- or biomass-fuel pellet combustion or to a positional resolved analysis of heterogenic catalytic reactions.

Turbulence in a gaseous hydrogen-liquid oxygen rocket combustion chamber

NASA Technical Reports Server (NTRS)

Lebas, J.; Tou, P.; Ohara, J.

1975-01-01

The intensity of turbulence and the Lagrangian correlation coefficient for a LOX-GH2 rocket combustion chamber was determined from experimental measurements of tracer gas diffusion. A combination of Taylor's turbulent diffusion theory and a numerical method for solving the conservation equations of fluid mechanics was used to calculate these quantities. Taylor's theory was extended to consider the inhomogeneity of the turbulence field in the axial direction of the combustion chamber, and an exponential function was used to represent the Lagrangian correlation coefficient. The results indicate that the value of the intensity of turbulence reaches a maximum of 14% at a location about 7" downstream from the injector. The Lagrangian correlation coefficient associated with this value is given by the above exponential expression where alpha = 10,000/sec.

Asymmetric 3d Electronic Structure for Enhanced Oxygen Evolution Catalysis.

PubMed

Liu, Yang; Yin, Shibin; Shen, Pei Kang

2018-06-27

The oxygen evolution reaction (OER) is an essential process for renewable energy, and designing a bifunctional oxygen electrocatalyst with high catalytic performance plays a significant role. In this work, FeS, Ni 3 S 2 , Fe 5 Ni 4 S 8 , and N, O, S-doped meshy carbon base were successfully synthesized. The sample containing Fe 5 Ni 4 S 8 exhibited excellent OER performance. The density functional theory calculations indicate that the partial density of states for 3d electrons (3d-PDOS) of Fe and Ni atoms are changed from monometallic sulfide to bimetallic sulfide at the sulfur vacancy. The asymmetric 3d electronic structure optimizes the 3d-PDOS of Fe and Ni atoms, and leads to an enhanced OER activity. This work provides a new strategy to prepare a low-cost electrocatalyst for oxygen evolution with high-efficiency.

Smoldering Combustion Experiments in Microgravity

NASA Technical Reports Server (NTRS)

Walther, David C.; Fernandez-Pello, A. Carlos; Urban, David L.

1997-01-01

The Microgravity Smoldering Combustion (MSC) experiment is part of a study of the smolder characteristics of porous combustible materials in a microgravity environment. Smoldering is a non-flaming form of combustion that takes place in the interior of porous materials and takes place in a number of processes ranging from smoldering of porous insulation materials to high temperature synthesis of metals. The objective of the study is to provide a better understanding of the controlling mechanisms of smolder, both in microgravity and normal-gravity. As with many forms of combustion, gravity affects the availability of oxidizer and transport of heat, and therefore the rate of combustion. Microgravity smolder experiments, in both a quiescent oxidizing environment, and in a forced oxidizing flow have been conducted aboard the NASA Space Shuttle (STS-69 and STS-77 missions) to determine the effect of the ambient oxygen concentration and oxidizer forced flow velocity on smolder combustion in microgravity. The experimental apparatus is contained within the NASA Get Away Special Canister (GAS-CAN) Payload. These two sets of experiments investigate the propagation of smolder along the polyurethane foam sample under both diffusion driven and forced flow driven smoldering. The results of the microgravity experiments are compared with identical ones carried out in normal gravity, and are used to verify present theories of smolder combustion. The results of this study will provide new insights into the smoldering combustion process. Thermocouple histories show that the microgravity smolder reaction temperatures (Ts) and propagation velocities (Us) lie between those of identical normal-gravity upward and downward tests. These observations indicate the effect of buoyancy on the transport of oxidizer to the reaction front.

Study on the laser irradiation characteristics of NEPE propellant in different oxygen concentrations

NASA Astrophysics Data System (ADS)

Xiang, Hengsheng; Chen, Xiong; Zhou, Changsheng

2016-01-01

The ignition and combustion characteristics of nitrate ester plasticized polyether (NEPE) propellant in different oxygen concentrations ambient gases were studied by the application of CO2 laser, infrared thermometer and high speed camera. The flame intensity data of the propellant was collected by the photodiode; propellant flame temperature was measured by infrared thermometer. The experimental results show that the time which NEPE propellant spend to be stable combustion will get shorter with the increase of oxygen concentration; the flame peak temperature measured by infrared thermometer increases with the increase of oxygen concentration when the oxygen concentration is less than 30% by volume, then decreases with the increase of oxygen concentration.

Space Station Freedom combustion research

NASA Technical Reports Server (NTRS)

Faeth, G. M.

1992-01-01

spread of liquids, drop combustion, and quenching of panicle-air flames. Unfortunately, the same features that make microgravity attractive for fundamental combustion experiments, introduce new fire and explosion hazards that have no counterpart on earth. For example, microgravity can cause broader flammability limits, novel regimes of flame spread, enhanced effects of flame radiation, slower fire detector response, and enhanced combustion upon injecting fire extinguishing agents, among others. On the other hand, spacecraft provide an opportunity to use 'fire-safe' atmospheres due to their controlled environment. Investigation of these problems is just beginning, with specific fire safety experiments supplementing the space based fundamental experiments listed earlier; thus, much remains to be done to develop an adequate technology base for fire and explosion safety considerations for spacecraft.

Oxygen index evaluation of fire-retardant-treated wood

Treesearch

Robert H. White

1979-01-01

The applicability of using the oxygen index test (ASTM D 2863-76) to obtain an indication of the relative flammability of fire-retardant- treated wood products was investigated. The oxygen index is the minimum percentage oxygen that is required to maintain flaming combustion of a specimen under specified laboratory conditions. Within the plastics industry, the test is...

Flammability of Heterogeneously Combusting Metals

NASA Technical Reports Server (NTRS)

Jones, Peter D.

1998-01-01

Most engineering materials, including some metals, most notably aluminum, burn in homogeneous combustion. 'Homogeneous' refers to both the fuel and the oxidizer being in the same phase, which is usually gaseous. The fuel and oxidizer are well mixed in the combustion reaction zone, and heat is released according to some relation like q(sub c) = delta H(sub c)c[((rho/rho(sub 0))]exp a)(exp -E(sub c)/RT), Eq. (1) where the pressure exponent a is usually close to unity. As long as there is enough heat released, combustion is sustained. It is useful to conceive of a threshold pressure beyond which there is sufficient heat to keep the temperature high enough to sustain combustion, and beneath which the heat is so low that temperature drains away and the combustion is extinguished. Some materials burn in heterogeneous combustion, in which the fuel and oxidizer are in different phases. These include iron and nickel based alloys, which burn in the liquid phase with gaseous oxygen. Heterogeneous combustion takes place on the surface of the material (fuel). Products of combustion may appear as a solid slag (oxide) which progressively covers the fuel. Propagation of the combustion melts and exposes fresh fuel. Heterogeneous combustion heat release also follows the general form of Eq.(1), except that the pressure exponent a tends to be much less than 1. Therefore, the increase in heat release with increasing pressure is not as dramatic as it is in homogeneous combustion. Although the concept of a threshold pressure still holds in heterogeneous combustion, the threshold is more difficult to identify experimentally, and pressure itself becomes less important relative to the heat transfer paths extant in any specific application. However, the constants C, a, and E(sub c) may still be identified by suitable data reduction from heterogeneous combustion experiments, and may be applied in a heat transfer model to judge the flammability of a material in any particular actual

A Study on the Effect of Stratified Mixture Formation on Combustion Characteristics in a Constant Volume Combustion Chamber

NASA Astrophysics Data System (ADS)

Lee, Kihyung; Lee, Changhee; Jeoung, Haeyoung

It is well known that a lean burn engine caused by stratified mixture formation has many kinds of advantages to combustion characteristics, such as higher thermal efficiency and lower CO, NOx levels than conventional homogeneous mixture combustion. Although this combustion can achieve low fuel consumption, it produces much unburned hydrocarbon and soot because of inhomogeneity of the charge mixture in the combustion chamber. Therefore, it is necessary to investigate the effect of mixture formation on combustion characteristics in order to obtain the stable lean combustion. In this paper, fundamental studies for stratified combustion were carried out using a constant volume combustion chamber. The effect of mixture formation on the combustion characteristics in the chamber was examined experimentally. In addition, the effect of turbulence on stratified charge combustion process was observed by schlieren photography. From this study, as the swirl intensity increases, (Sv)max is rapidly enhanced and the period of combustion is shortened. We also find that the stratification degree can be quantified by using burning velocity and it was controlled by induced air pressure and turbulent intensity.

Combustion of diesel fuel from a toxicological perspective. I. Origin of incomplete combustion products.

PubMed

Scheepers, P T; Bos, R P

1992-01-01

Since the use of diesel engines is still increasing, the contribution of their incomplete combustion products to air pollution is becoming ever more important. The presence of irritating and genotoxic substances in both the gas phase and the particulate phase constituents is considered to have significant health implications. The quantity of soot particles and the particle-associated organics emitted from the tail pipe of a diesel-powered vehicle depend primarily on the engine type and combustion conditions but also on fuel properties. The quantity of soot particles in the emissions is determined by the balance between the rate of formation and subsequent oxidation. Organics are absorbed onto carbon cores in the cylinder, in the exhaust system, in the atmosphere and even on the filter during sample collection. Diesel fuel contains polycyclic aromatic hydrocarbons (PAHs) and some alkyl derivatives. Both groups of compounds may survive the combustion process. PAHs are formed by the combustion of crankcase oil or may be resuspended from engine and/or exhaust deposits. The conversion of parent PAHs to oxygenated and nitrated PAHs in the combustion chamber or in the exhaust system is related to the vast amount of excess combustion air that is supplied to the engine and the high combustion temperature. Whether the occurrence of these derivatives is characteristic for the composition of diesel engine exhaust remains to be ascertained. After the emission of the particles, their properties may change because of atmospheric processes such as aging and resuspension. The particle-associated organics may also be subject to (photo)chemical conversions or the components may change during sampling and analysis. Measurement of emissions of incomplete combustion products as determined on a chassis dynamometer provides knowledge of the chemical composition of the particle-associated organics. This knowledge is useful as a basis for a toxicological evaluation of the health hazards of

Diamagnetic levitation enhances growth of liquid bacterial cultures by increasing oxygen availability

PubMed Central

Dijkstra, Camelia E.; Larkin, Oliver J.; Anthony, Paul; Davey, Michael R.; Eaves, Laurence; Rees, Catherine E. D.; Hill, Richard J. A.

2011-01-01

Diamagnetic levitation is a technique that uses a strong, spatially varying magnetic field to reproduce aspects of weightlessness, on the Earth. We used a superconducting magnet to levitate growing bacterial cultures for up to 18 h, to determine the effect of diamagnetic levitation on all phases of the bacterial growth cycle. We find that diamagnetic levitation increases the rate of population growth in a liquid culture and reduces the sedimentation rate of the cells. Further experiments and microarray gene analysis show that the increase in growth rate is owing to enhanced oxygen availability. We also demonstrate that the magnetic field that levitates the cells also induces convective stirring in the liquid. We present a simple theoretical model, showing how the paramagnetic force on dissolved oxygen can cause convection during the aerobic phases of bacterial growth. We propose that this convection enhances oxygen availability by transporting oxygen around the liquid culture. Since this process results from the strong magnetic field, it is not present in other weightless environments, e.g. in Earth orbit. Hence, these results are of significance and timely to researchers considering the use of diamagnetic levitation to explore effects of weightlessness on living organisms and on physical phenomena. PMID:20667843

Diamagnetic levitation enhances growth of liquid bacterial cultures by increasing oxygen availability.

PubMed

Dijkstra, Camelia E; Larkin, Oliver J; Anthony, Paul; Davey, Michael R; Eaves, Laurence; Rees, Catherine E D; Hill, Richard J A

2011-03-06

Diamagnetic levitation is a technique that uses a strong, spatially varying magnetic field to reproduce aspects of weightlessness, on the Earth. We used a superconducting magnet to levitate growing bacterial cultures for up to 18 h, to determine the effect of diamagnetic levitation on all phases of the bacterial growth cycle. We find that diamagnetic levitation increases the rate of population growth in a liquid culture and reduces the sedimentation rate of the cells. Further experiments and microarray gene analysis show that the increase in growth rate is owing to enhanced oxygen availability. We also demonstrate that the magnetic field that levitates the cells also induces convective stirring in the liquid. We present a simple theoretical model, showing how the paramagnetic force on dissolved oxygen can cause convection during the aerobic phases of bacterial growth. We propose that this convection enhances oxygen availability by transporting oxygen around the liquid culture. Since this process results from the strong magnetic field, it is not present in other weightless environments, e.g. in Earth orbit. Hence, these results are of significance and timely to researchers considering the use of diamagnetic levitation to explore effects of weightlessness on living organisms and on physical phenomena.

Internal and Surface Phenomena in Heterogenous Metal Combustion

NASA Technical Reports Server (NTRS)

Dreizin, Edward L.

1997-01-01

The phenomenon of gas dissolution in burning metals was observed in recent metal combustion studies, but it could not be adequately explained by the traditional metal combustion models. The research reported here addresses heterogeneous metal combustion with emphasis on the processes of oxygen penetration inside burning metal and its influence on the metal combustion rate, temperature history, and disruptive burning. The unique feature of this work is the combination of the microgravity environment with a novel micro-arc generator of monodispersed metal droplets, ensuring repeatable formation and ignition of uniform metal droplets with a controllable initial temperature and velocity. Burning droplet temperature is measured in real time with a three wavelength pyrometer. In addition, particles are rapidly quenched at different combustion times, cross-sectioned, and examined using SEM-based techniques to retrieve the internal composition history of burning metal particles. When the initial velocity of a spherical particle is nearly zero, the microgravity environment makes it possible to study the flame structure, the development of flame nonsymmetry, and correlation of the flame shape with the heterogeneous combustion processes.

Self-enhanced catalytic activities of functionalized graphene sheets in the combustion of nitromethane: molecular dynamic simulations by molecular reactive force field.

PubMed

Zhang, Chaoyang; Wen, Yushi; Xue, Xianggui

2014-08-13

Functionalized graphene sheet (FGS) is a promising additive that enhances fuel/propellant combustion, and the determination of its mechanism has attracted much interest. In the present study, a series of molecular dynamic simulations based on a reactive force field (ReaxFF) are performed to explore the catalytic activity (CA) of FGS in the thermal decay of nitromethane (NM, CH3NO2). FGSs and pristine graphene sheets (GSs) are oxidized in hot NM liquid to increase their functionalities and subsequently show self-enhanced CAs during the decay. The CAs result from the interatomic exchanges between the functional groups on the sheets and the NM liquid, i.e., mainly between H and O atoms. CA is dependent on the density of NM, functionalities of sheets, and temperature. The GSs and FGSs that originally exhibit different functionalities tend to possess similar functionalities and consequently similar CAs as temperature increases. Other carbon materials and their oxides can accelerate combustion of other fuels/propellants similar to NM, provided that they can be dispersed and their key reaction steps in combustion are similar to NM.

Technique for in-place welding of aluminum backed up by a combustible material

NASA Technical Reports Server (NTRS)

Spagnuolo, A. C.

1971-01-01

Welding external aluminum jacket, tightly wrapped around inner layer of wood composition fiberboard, in oxygen free environment prevents combustion and subsequent damage to underlying fiberboard. Technique also applies to metal cutting in similar assemblies without disassembly to remove combustible materials from welding heat proximity.

Performance and Stability Analyses of Rocket Thrust Chambers with Oxygen/Methane Propellants

NASA Technical Reports Server (NTRS)

Hulka, James R.; Jones, Gregg W.

2010-01-01

Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for future in-space vehicles. This propellant combination has not been previously used in flight-qualified engine systems developed by NASA, so limited test data and analysis results are available at this stage of early development. As part of activities for the Propulsion and Cryogenic Advanced Development (PCAD) project funded under the Exploration Technology Development Program, the NASA Marshall Space Flight Center (MSFC) has been evaluating capability to model combustion performance and stability for oxygen and methane propellants. This activity has been proceeding for about two years and this paper is a summary of results to date. Hot-fire test results of oxygen/methane propellant rocket engine combustion devices for the modeling investigations have come from several sources, including multi-element injector tests with gaseous methane from the 1980s, single element tests with gaseous methane funded through the Constellation University Institutes Program, and multi-element injector tests with both gaseous and liquid methane conducted at the NASA MSFC funded by PCAD. For the latter, test results of both impinging and coaxial element injectors using liquid oxygen and liquid methane propellants are included. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interactive Design and Analysis code and the Coaxial Injector Combustion Model. Special effort was focused on how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied, improved or developed in the future. Low frequency combustion instability (chug) occurred, with frequencies ranging from 150 to 250 Hz, with several multi-element injectors with liquid/liquid propellants, and was modeled using

Projectile Combustion Effects on Ram Accelerator Performance

NASA Astrophysics Data System (ADS)

Chitale, Saarth Anjali

with projectiles operating in methane/oxygen/nitrogen propellants. Effects of projectile surface to volume ratio are also explored by applying the model to experimental results from smaller (Tohoku University, 25-mm-bore) and larger (Institute of Saint-Louis 90-mm-bore) bore ram accelerators. Due to lower surface-to-volume ratio, large diameter projectiles are predicted to need to reach higher Mach numbers than smaller diameter projectiles before thrust enhancement due to metal ablation and burning would be experienced. This proposition was supported by published experimental data. The theoretical modeling of projectile ablation, metal combustion, and subsequent ram accelerator thrust characteristics are presented along comparisons to experiments from three different sized ram accelerator facilities.

Constant-Pressure Combustion Charts Including Effects of Diluent Addition

NASA Technical Reports Server (NTRS)

Turner, L Richard; Bogart, Donald

1949-01-01

Charts are presented for the calculation of (a) the final temperatures and the temperature changes involved in constant-pressure combustion processes of air and in products of combustion of air and hydrocarbon fuels, and (b) the quantity of hydrocarbon fuels required in order to attain a specified combustion temperature when water, alcohol, water-alcohol mixtures, liquid ammonia, liquid carbon dioxide, liquid nitrogen, liquid oxygen, or their mixtures are added to air as diluents or refrigerants. The ideal combustion process and combustion with incomplete heat release from the primary fuel and from combustible diluents are considered. The effect of preheating the mixture of air and diluents and the effect of an initial water-vapor content in the combustion air on the required fuel quantity are also included. The charts are applicable only to processes in which the final mixture is leaner than stoichiometric and at temperatures where dissociation is unimportant. A chart is also included to permit the calculation of the stoichiometric ratio of hydrocarbon fuel to air with diluent addition. The use of the charts is illustrated by numerical examples.

Evaluation of char combustion models: measurement and analysis of variability in char particle size and density

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maloney, Daniel J; Monazam, Esmail R; Casleton, Kent H

Char samples representing a range of combustion conditions and extents of burnout were obtained from a well-characterized laminar flow combustion experiment. Individual particles from the parent coal and char samples were characterized to determine distributions in particle volume, mass, and density at different extent of burnout. The data were then compared with predictions from a comprehensive char combustion model referred to as the char burnout kinetics model (CBK). The data clearly reflect the particle- to-particle heterogeneity of the parent coal and show a significant broadening in the size and density distributions of the chars resulting from both devolatilization and combustion.more » Data for chars prepared in a lower oxygen content environment (6% oxygen by vol.) are consistent with zone II type combustion behavior where most of the combustion is occurring near the particle surface. At higher oxygen contents (12% by vol.), the data show indications of more burning occurring in the particle interior. The CBK model does a good job of predicting the general nature of the development of size and density distributions during burning but the input distribution of particle size and density is critical to obtaining good predictions. A significant reduction in particle size was observed to occur as a result of devolatilization. For comprehensive combustion models to provide accurate predictions, this size reduction phenomenon needs to be included in devolatilization models so that representative char distributions are carried through the calculations.« less

Particulate matter emissions, and metals and toxic elements in airborne particulates emitted from biomass combustion: The importance of biomass type and combustion conditions.

PubMed

Zosima, Angela T; Tsakanika, Lamprini-Areti V; Ochsenkühn-Petropoulou, Maria Th

2017-05-12

The aim of this study was to investigate the impact of biomass combustion with respect to burning conditions and fuel types on particulate matter emissions (PM 10 ) and their metals as well as toxic elements content. For this purpose, different lab scale burning conditions were tested (20 and 13% O 2 in the exhaust gas which simulate an incomplete and complete combustion respectively). Furthermore, two pellet stoves (8.5 and 10 kW) and one open fireplace were also tested. In all cases, 8 fuel types of biomass produced in Greece were used. Average PM 10 emissions ranged at laboratory-scale combustions from about 65 to 170 mg/m 3 with flow oxygen at 13% in the exhaust gas and from 85 to 220 mg/m 3 at 20% O 2 . At pellet stoves the emissions were found lower (35 -85 mg/m 3 ) than the open fireplace (105-195 mg/m 3 ). The maximum permitted particle emission limit is 150 mg/m 3 . Metals on the PM 10 filters were determined by several spectrometric techniques after appropriate digestion or acid leaching of the filters, and the results obtained by these two methods were compared. The concentration of PM 10 as well as the total concentration of the metals on the filters after the digestion procedure appeared higher at laboratory-scale combustions with flow oxygen at 20% in the exhaust gas and even higher at fireplace in comparison to laboratory-scale combustions with 13% O 2 and pellet stoves. Modern combustion appliances and appropriate types of biomass emit lower PM 10 emissions and lower concentration of metals than the traditional devices where incomplete combustion conditions are observed. Finally, a comparison with other studies was conducted resulting in similar results.

Particle behavior and char burnout mechanisms under pressurized combustion conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bauer, C.M.; Spliethoff, H.; Hein, K.R.G.

Combined cycle systems with coal-fired gas turbines promise highest cycle efficiencies for this fuel. Pressurized pulverized coal combustion, in particular, yields high cycle efficiencies due to the high flue gas temperatures possible. The main problem, however, is to ensure a flue gas clean enough to meet the high gas turbine standards with a dirty fuel like coal. On the one hand, a profound knowledge of the basic chemical and physical processes during fuel conversion under elevated pressures is required whereas on the other hand suitable hot gas cleaning systems need to be developed. The objective of this work was tomore » provide experimental data to enable a detailed description of pressurized coal combustion processes. A series of experiments were performed with two German hvb coals, Ensdorf and Goettelborn, and one German brown coal, Garzweiler, using a semi-technical scale pressurized entrained flow reactor. The parameters varied in the experiments were pressure, gas temperature and bulk gas oxygen concentration. A two-color pyrometer was used for in-situ determination of particle surface temperatures and particle sizes. Flue gas composition was measured and solid residue samples taken and subsequently analyzed. The char burnout reaction rates were determinated varying the parameters pressure, gas temperature and initial oxygen concentration. Variation of residence time was achieved by taking the samples at different points along the reaction zone. The most influential parameters on char burnout reaction rates were found to be oxygen partial pressure and fuel volatile content. With increasing pressure the burn-out reactions are accelerated and are mostly controlled by product desorption and pore diffusion being the limiting processes. The char burnout process is enhanced by a higher fuel volatile content.« less

Supercomputer modeling of hydrogen combustion in rocket engines

NASA Astrophysics Data System (ADS)

Betelin, V. B.; Nikitin, V. F.; Altukhov, D. I.; Dushin, V. R.; Koo, Jaye

2013-08-01

Hydrogen being an ecological fuel is very attractive now for rocket engines designers. However, peculiarities of hydrogen combustion kinetics, the presence of zones of inverse dependence of reaction rate on pressure, etc. prevents from using hydrogen engines in all stages not being supported by other types of engines, which often brings the ecological gains back to zero from using hydrogen. Computer aided design of new effective and clean hydrogen engines needs mathematical tools for supercomputer modeling of hydrogen-oxygen components mixing and combustion in rocket engines. The paper presents the results of developing verification and validation of mathematical model making it possible to simulate unsteady processes of ignition and combustion in rocket engines.

Guide for Oxygen Hazards Analyses on Components and Systems

NASA Technical Reports Server (NTRS)

Stoltzfus, Joel M.; Dees, Jesse; Poe, Robert F.

1996-01-01

Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite at lower temperatures in an oxygen-enriched environment than in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Many metals burn violently in an oxygen-enriched environment when ignited. Lubricants, tapes, gaskets, fuels, and solvents can increase the possibility of ignition in oxygen systems. However, these hazards do not preclude the use of oxygen. Oxygen may be safely used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. These ignition and combustion hazards necessitate a proper oxygen hazards analysis before introducing a material or component into oxygen service. The objective of this test plan is to describe the White Sands Test Facility oxygen hazards analysis to be performed on components and systems before oxygen is introduced and is recommended before implementing the oxygen component qualification procedure. The plan describes the NASA Johnson Space Center White Sands Test Facility method consistent with the ASTM documents for analyzing the hazards of components and systems exposed to an oxygen-enriched environment. The oxygen hazards analysis is a useful tool for oxygen-system designers, system engineers, and facility managers. Problem areas can be pinpointed before oxygen is introduced into the system, preventing damage to hardware and possible injury or loss of life.

Resonant enhanced multiphoton ionization studies of atomic oxygen

NASA Technical Reports Server (NTRS)

Dixit, S. N.; Levin, D.; Mckoy, V.

1987-01-01

In resonant enhanced multiphoton ionization (REMPI), an atom absorbs several photons making a transition to a resonant intermediate state and subsequently ionizing out of it. With currently available tunable narrow-band lasers, the extreme sensitivity of REMPI to the specific arrangement of levels can be used to selectively probe minute amounts of a single species (atom) in a host of background material. Determination of the number density of atoms from the observed REMPI signal requires a knowledge of the multiphoton ionization cross sections. The REMPI of atomic oxygen was investigated through various excitation schemes that are feasible with available light sources. Using quantum defect theory (QDT) to estimate the various atomic parameters, the REMPI dynamics in atomic oxygen were studied incorporating the effects of saturation and a.c. Stark shifts. Results are presented for REMPI probabilities for excitation through various 2p(3) (4S sup o) np(3)P and 2p(3) (4S sup o) nf(3)F levels.

Relationships between composition and pulmonary toxicity of prototype particles from coal combustion and pyrolysis

EPA Science Inventory

The hypothesis that health effects associated with coal combustion fly-ash particles are exacerbated by the simultaneous presence of iron and soot was tested through two sets of experiments. The first set created prototype particles from complete and partial combustion, or oxygen...

SITE PROGRAM APPLICATIONS ANALYSIS ASSESSMENT OF SUPERFUND APPLICATIONS FOR THE AMERICAN COMBUSTION INC. PYRETRON OXYGEN ENHANCED BURNER

EPA Science Inventory

Incineration is widely used to clean up Superfund sites. Modifications which improve the efficiency with which waste can be incinerated are therefore of interest to EPA. Oxygen/air burners are of interest because their installation on conventional incinerators can allow for signi...

Contrast enhancement for in vivo visible reflectance imaging of tissue oxygenation.

PubMed

Crane, Nicole J; Schultz, Zachary D; Levin, Ira W

2007-08-01

Results are presented illustrating a straightforward algorithm to be used for real-time monitoring of oxygenation levels in blood cells and tissue based on the visible spectrum of hemoglobin. Absorbance images obtained from the visible reflection of white light through separate red and blue bandpass filters recorded by monochrome charge-coupled devices (CCDs) are combined to create enhanced images that suggest a quantitative correlation between the degree of oxygenated and deoxygenated hemoglobin in red blood cells. The filter bandpass regions are chosen specifically to mimic the color response of commercial 3-CCD cameras, representative of detectors with which the operating room laparoscopic tower systems are equipped. Adaptation of this filter approach is demonstrated for laparoscopic donor nephrectomies in which images are analyzed in terms of real-time in vivo monitoring of tissue oxygenation.

Formation and emission of large furans and oxygenated hydrocarbons from flames.

PubMed

Johansson, K Olof; Dillstrom, Tyler; Monti, Matteo; El Gabaly, Farid; Campbell, Matthew F; Schrader, Paul E; Popolan-Vaida, Denisia M; Richards-Henderson, Nicole K; Wilson, Kevin R; Violi, Angela; Michelsen, Hope A

2016-07-26

Many oxygenated hydrocarbon species formed during combustion, such as furans, are highly toxic and detrimental to human health and the environment. These species may also increase the hygroscopicity of soot and strongly influence the effects of soot on regional and global climate. However, large furans and associated oxygenated species have not previously been observed in flames, and their formation mechanism and interplay with polycyclic aromatic hydrocarbons (PAHs) are poorly understood. We report on a synergistic computational and experimental effort that elucidates the formation of oxygen-embedded compounds, such as furans and other oxygenated hydrocarbons, during the combustion of hydrocarbon fuels. We used ab initio and probabilistic computational techniques to identify low-barrier reaction mechanisms for the formation of large furans and other oxygenated hydrocarbons. We used vacuum-UV photoionization aerosol mass spectrometry and X-ray photoelectron spectroscopy to confirm these predictions. We show that furans are produced in the high-temperature regions of hydrocarbon flames, where they remarkably survive and become the main functional group of oxygenates that incorporate into incipient soot. In controlled flame studies, we discovered ∼100 oxygenated species previously unaccounted for. We found that large alcohols and enols act as precursors to furans, leading to incorporation of oxygen into the carbon skeletons of PAHs. Our results depart dramatically from the crude chemistry of carbon- and oxygen-containing molecules previously considered in hydrocarbon formation and oxidation models and spearhead the emerging understanding of the oxidation chemistry that is critical, for example, to control emissions of toxic and carcinogenic combustion by-products, which also greatly affect global warming.

Formation and emission of large furans and oxygenated hydrocarbons from flames

PubMed Central

Johansson, K. Olof; Dillstrom, Tyler; Monti, Matteo; El Gabaly, Farid; Campbell, Matthew F.; Schrader, Paul E.; Popolan-Vaida, Denisia M.; Richards-Henderson, Nicole K.; Wilson, Kevin R.; Violi, Angela; Michelsen, Hope A.

2016-01-01

Many oxygenated hydrocarbon species formed during combustion, such as furans, are highly toxic and detrimental to human health and the environment. These species may also increase the hygroscopicity of soot and strongly influence the effects of soot on regional and global climate. However, large furans and associated oxygenated species have not previously been observed in flames, and their formation mechanism and interplay with polycyclic aromatic hydrocarbons (PAHs) are poorly understood. We report on a synergistic computational and experimental effort that elucidates the formation of oxygen-embedded compounds, such as furans and other oxygenated hydrocarbons, during the combustion of hydrocarbon fuels. We used ab initio and probabilistic computational techniques to identify low-barrier reaction mechanisms for the formation of large furans and other oxygenated hydrocarbons. We used vacuum-UV photoionization aerosol mass spectrometry and X-ray photoelectron spectroscopy to confirm these predictions. We show that furans are produced in the high-temperature regions of hydrocarbon flames, where they remarkably survive and become the main functional group of oxygenates that incorporate into incipient soot. In controlled flame studies, we discovered ∼100 oxygenated species previously unaccounted for. We found that large alcohols and enols act as precursors to furans, leading to incorporation of oxygen into the carbon skeletons of PAHs. Our results depart dramatically from the crude chemistry of carbon- and oxygen-containing molecules previously considered in hydrocarbon formation and oxidation models and spearhead the emerging understanding of the oxidation chemistry that is critical, for example, to control emissions of toxic and carcinogenic combustion by-products, which also greatly affect global warming. PMID:27410045

Soot agglomeration in isolated, free droplet combustion

NASA Technical Reports Server (NTRS)

Choi, M. Y.; Dryer, F. L.; Green, G. J.; Sangiovanni, J. J.

1993-01-01

Under the conditions of an isolated, free droplet experiment, hollow, carbonaceous structures, called soot spheres, were observed to form during the atmospheric pressure, low Reynolds number combustion of 1-methylnaphthalene. These structures which are agglomerates composed of smaller spheroidal units result from both thermophoretic effects induced by the envelope flame surrounding each drop and aerodynamic effects caused by changes in the relative gas/drop velocities. A chemically reacting flow model was used to analyze the process of sootshell formation during microgravity droplet combustion. The time-dependent temperature and gas property field surrounding the droplet was determined, and the soot cloud location for microgravity combustion of n-heptane droplets was predicted. Experiments showed that the sooting propensity of n-alkane fuel droplets can be varied through diluent substitution, oxygen-index variations, and ambient pressure reductions.

Transient combustion in hybrid rockets

NASA Astrophysics Data System (ADS)

Karabeyoglu, Mustafa Arif

1998-09-01

Hybrid rockets regained interest recently as an alternative chemical propulsion system due to their advantages over the solid and liquid systems that are currently in use. Development efforts on hybrids revealed two important problem areas: (1) low frequency instabilities and (2) slow transient response. Both of these are closely related to the transient behavior which is a poorly understood aspect of hybrid operation. This thesis is mainly involved with a theoretical study of transient combustion in hybrid rockets. We follow the methodology of identifying and modeling the subsystems of the motor such as the thermal lags in the solid, boundary layer combustion and chamber gasdynamics from a dynamic point of view. We begin with the thermal lag in the solid which yield the regression rate for any given wall heat flux variation. Interesting phenomena such as overshooting during throttling and the amplification and phase lead regions in the frequency domain are discovered. Later we develop a quasi-steady transient hybrid combustion model supported with time delays for the boundary layer processes. This is integrated with the thermal lag system to obtain the thermal combustion (TC) coupled response. The TC coupled system with positive delays generated low frequency instabilities. The scaling of the instabilities are in good agreement with actual motor test data. Finally, we formulate a gasdynamic model for the hybrid chamber which successfully resolves the filling/emptying and longitudinal acoustic behavior of the motor. The TC coupled system is later integrated to the gasdynamic model to obtain the overall response (TCG coupled system) of gaseous oxidizer motors with stiff feed systems. Low frequency instabilities were also encountered for the TCG coupled system. Apart from the transient investigations, the regression rate behavior of liquefying hybrid propellants such as solid cryogenic materials are also studied. The theory is based on the possibility of enhancement

Optofluidic reactors for reverse combustion photocatalytic production of hydrocarbons (Conference Presentation)

NASA Astrophysics Data System (ADS)

Schein, Perry; Erickson, David

2017-03-01

In combustion, hydrocarbon fuels are burned with oxygen to release energy, carbon dioxide and water vapor. Here, we introduce a photocatalytic reactor for reversing this process, when carbon dioxide and water are combined and using optical and thermal energy from the sun hydrocarbons are produced and oxygen is released. This allows for the sustainable production of hydrocarbon products from non-fossil sources, allowing for the development of "green" hydrocarbon products. Our reactors take the form of modular cells of 10 x 10 x 10 cm scale where light is delivered to nanostructured catalysts through the evanescent field around dielectric slab waveguides. The light distribution is optimized through the use of engineered scattering sites to enhance field uniformity. This is combined with integrated fluidic architecture to deliver a stream rich in water and carbon dioxide (such as exhaust from a natural gas burning plant) to the nanostructured catalyst particles in a narrow channel. Exhaust streams rich in oxygen and hydrocarbon products are collected at the outlet of the reactor cell. The cell is heated using solar thermal energy and temperatures of up to 200°C are achieved, enhancing reaction efficiency. Hydrocarbon products produced include methanol as well as other potentially useful molecules for fuel production or precursors to the manufacture of plastics. These reactors can be coupled to solar collectors to take advantage of the sun as a free source of heat and light, and the modular nature of the cells enables scaling to larger deployments.

Metallized Gelled Propellants: Oxygen/RP-1/aluminum Rocket Combustion Experiments

NASA Technical Reports Server (NTRS)

Palaszewski, Bryan; Zakany, James S.

1995-01-01

A series of combustion experiments were conducted to measure the specific impulse, Cstar-, and specific-impulse efficiencies of a rocket engine using metallized gelled liquid propellants. These experiments used a small 20- to 40-1bf (89- to 178-N) thrust, modular engine consisting of an injector, igniter, chamber and nozzle. The fuels used were traditional liquid RP-1 and gelled RP-1 with 0-, 5-, and 55-wt% loadings of aluminum and gaseous oxygen was the oxidizer. Ten different injectors were used during the testing: 6 for the baseline 02/RP-1 tests and 4 for the gelled fuel tests which covered a wide range of mixture ratios. At the peak of the Isp versus oxidizer-to-fuel ratio (O/F) data, a range of 93 to 99% Cstar efficiency was reached with ungelled 02/RP-1. A Cstar efficiency range of 75 to 99% was obtained with gelled RP-l (0-wt% RP-1/Al) while the metallized 5-wt% RP-1/Al delivered a Cstar efficiency of 94 to 99% at the peak Isp in the O/F range tested. An 88 to 99% Cstar efficiency was obtained at the peak Isp of the gelled RP1/Al with 55-wt% Al. Specific impulse efficiencies for the 55-wt% RP-1/Al of 67%-83% were obtained at a 2.4:1 expansion ratio. Injector erosion was evident with the 55-wt% testing, while there was little or no erosion seen with the gelled RP-1 with 0- and 5-wt% Al. A protective layer of gelled fuel formed in the firings that minimized the damage to the rocket injector face. This effect may provide a useful technique for engine cooling. These experiments represent a first step in characterizing the performance of and operational issues with gelled RP-1 fuels.

NOx Emission Reduction by Oscillating combustion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Institute of Gas Technology

2004-01-30

High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiencymore » for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

NOx Emission Reduction by Oscillating Combustion

DOE Office of Scientific and Technical Information (OSTI.GOV)

John C. Wagner

2004-03-31

High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiencymore » for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

Simulations of normal and inverse laminar diffusion flames under oxygen enhancement and gravity variation

NASA Astrophysics Data System (ADS)

Bhatia, P.; Katta, V. R.; Krishnan, S. S.; Zheng, Y.; Sunderland, P. B.; Gore, J. P.

2012-10-01

Steady-state global chemistry calculations for 20 different flames were carried out using an axisymmetric Computational Fluid Dynamics (CFD) code. Computational results for 16 flames were compared with flame images obtained at the NASA Glenn Research Center. The experimental flame data for these 16 flames were taken from Sunderland et al. [4] which included normal and inverse diffusion flames of ethane with varying oxidiser compositions (21, 30, 50, 100% O2 mole fraction in N2) stabilised on a 5.5 mm diameter burner. The test conditions of this reference resulted in highly convective inverse diffusion flames (Froude numbers of the order of 10) and buoyant normal diffusion flames (Froude numbers ∼0.1). Additionally, six flames were simulated to study the effect of oxygen enhancement on normal diffusion flames. The enhancement in oxygen resulted in increased flame temperatures and the presence of gravity led to increased gas velocities. The effect of gravity-variation and oxygen enhancement on flame shape and size of normal diffusion flames was far more pronounced than for inverse diffusion flames. For normal-diffusion flames, their flame-lengths decreased (1 to 2 times) and flames-widths increased (2 to 3 times) when going from earth-gravity to microgravity, and flame height decreased by five times when going from air to a pure oxygen environment.

Fuel/oxidizer-rich high-pressure preburners. [staged-combustion rocket engine

NASA Technical Reports Server (NTRS)

Schoenman, L.

1981-01-01

The analyses, designs, fabrication, and cold-flow acceptance testing of LOX/RP-1 preburner components required for a high-pressure staged-combustion rocket engine are discussed. Separate designs of injectors, combustion chambers, turbine simulators, and hot-gas mixing devices are provided for fuel-rich and oxidizer-rich operation. The fuel-rich design addresses the problem of non-equilibrium LOX/RP-1 combustion. The development and use of a pseudo-kinetic combustion model for predicting operating efficiency, physical properties of the combustion products, and the potential for generating solid carbon is presented. The oxygen-rich design addresses the design criteria for the prevention of metal ignition. This is accomplished by the selection of materials and the generation of well-mixed gases. The combining of unique propellant injector element designs with secondary mixing devices is predicted to be the best approach.

TG-FTIR analysis on pyrolysis and combustion of marine sediment

NASA Astrophysics Data System (ADS)

Oudghiri, Fatiha; Allali, Nabil; Quiroga, José María; Rodríguez-Barroso, María Rocío

2016-09-01

In this paper, the pyrolysis and combustion of sediment have been compared using thermogravimetric analysis (TG) coupled with Fourier transform infrared spectrometry (TG-FTIR) analysis. The TG results showed that both the pyrolysis and combustion of sediment presented four weight loss stages, each. The evolving gaseous products during pyrolysis were H2O, CO2 and hydrocarbons, while combustion yielded considerable amounts of CO2, in addition to H2O, CO, Cdbnd C, Cdbnd O and NH3. Comparing the pyrolysis and combustion TG-FTIR curves, it is possible to evaluate the effect of oxygen presence in the temperature range of 200-600 °C, which increases the volatilisation rate of organic matter in sediment. For the better detection of organic and inorganic matter in sediment by TG-FTIR analysis it is recommended to work in combustion mode of sediment.

Enhanced thermoelectric properties via oxygen non-stoichiometry in La2NiO4 and SrTiO3

NASA Astrophysics Data System (ADS)

Pardo, Victor; Botana, Antia S.; Bach, Paul M.; Leboran, Victor; Rivadulla, Francisco; Baldomir, Daniel

2013-03-01

We present the results of transport properties calculations and experiments on various oxides. A large enhancement of the thermoelectric properties is predicted[1] via ab initio calculations for La2NiO4+δ, with electronic-only thermoelectric figure of merit (zT) values exceeding unity for oxygen excess δ <= 0.10. The effects of lattice strain (caused, e.g. by growth of thin films on different substrates) enhance even further the thermoelectric response. A similar result is obtained at very low electron-doping in bulk SrTiO3 via oxygen removal. This is analyzed experimentally via thermal annealing that depletes oxygen (~ 1 oxygen vacancy per 106 unit cells). In both these systems, the increase in conductivity reached in the metallic limit retains a large thermopower, with the corresponding enhancement of zT . In the case of SrTiO3, experiments indicate[2] that such a small oxygen vacancy level reduces drastically the thermal conductivity by introducing random scattering centers. In the talk, we will discuss the electronic structure origin of the enhancement of the thermoelectric response and how this can be tuned. Results are general and applicable to other non-stoichiometric oxides.

Ignition and combustion of bulk metals in a microgravity environment

NASA Technical Reports Server (NTRS)

Branch, Melvyn C.; Daily, J. W.; Abbud-Madrid, Angel

1994-01-01

Knowledge of the oxidation, ignition, and combustion of bulk metals is important for fire safety in the production, management, and utilization of liquid and gaseous oxygen for ground based and space applications. This report summarizes research under NASA support to investigate the ignition and combustion characteristics of bulk metals under varying gravity conditions. Metal ignition and combustion have not been studied previously under these conditions and the results are important not only for improved fire safety but also to increase knowledge of basic ignition and combustion mechanisms. The studies completed to date have led to the development of a clean and reproducible ignition source and diagnostic techniques for combustion measurements and have provided normal gravity combustion data on ten different pure metals. Metal specimens were ignited using a xenon short-arc lamp and measurements were made of the radiant energy flux, surface temperature history, spectroscopy of surface and gas products, and surface morphology and chemistry. Elevated gravity was provided by the University of Colorado Geotechnical Centrifuge.

Compact Analyzer/Controller For Oxygen-Enrichment System

NASA Technical Reports Server (NTRS)

Puster, Richard L.; Singh, Jag J.; Sprinkle, Danny R.

1990-01-01

System controls hypersonic air-breathing engine tests. Compact analyzer/controller developed, built, and tested in small-scale wind tunnel prototype of the 8' HTT (High-Temperature Tunnel). Monitors level of oxygen and controls addition of liquid oxygen to enrich atmosphere for combustion. Ensures meaningful ground tests of hypersonic engines in range of speeds from mach 4 to mach 7.

Organic radicals for the enhancement of oxygen reduction reaction in Li-O2 batteries.

PubMed

Tesio, A Y; Blasi, D; Olivares-Marín, M; Ratera, I; Tonti, D; Veciana, J

2015-12-25

We examine for the first time the ability of inert carbon free-radicals as soluble redox mediators to catalyze and enhance the oxygen reduction reaction in a (TEGDME)-based electrolyte. We demonstrate that the tris(2,4,6-trichlorophenyl)methyl (TTM) radical is capable of chemically favoring the oxygen reduction reaction improving significantly the Li-O2 battery performance.

Oxygen and relative humidity monitoring with films tailored for enhanced photoluminescence

DOE PAGES

Cui, Weipan; Liu, Rui; Manna, Eeshita; ...

2014-10-31

In this study, approaches to generate porous or doped sensing films, which significantly enhance the photoluminescence (PL) of oxygen optical sensors, and thus improve the signal-to-noise (S/N) ratio, are presented. Tailored films, which enable monitoring the relative humidity (RH) as well, are also presented. Effective porous structures, in which the O 2-sensitive dye Pt octaethylporphyrin (PtOEP) or the Pd analog PdOEP was embedded, were realized by first generating blend films of polyethylene glycol (PEG) with polystyrene (PS) or with ethyl cellulose (EC), and then immersing the dried films in water to remove the water-soluble PEG. This approach creates pores (voids)more » in the sensing films. The dielectric contrast between the films’ constituents and the voids increases photon scattering, which in turn increases the optical path of the excitation light within the film, and hence light absorption by the dye, and its PL. Optimized sensing films with a PEG:PS ratio of 1:4 (PEG’s molecular weight M w ~8000) led to ~4.4× enhancement in the PL (in comparison to PS films). Lower M w ~200 PEG with a PEG:EC ratio of 1:1 led to a PL enhancement of ~4.7×. Film-dependent PL enhancements were observed at all oxygen concentrations. The strong PL enhancement enables (i) using lower dye (luminophore) concentrations, (ii) reducing power consumption and enhancing the sensor’s operational lifetime when using organic light emitting diodes (OLEDs) as excitation sources, (iii) improving performance when using compact photodetectors with no internal gain, and (iv) reliably extending the dynamic range.« less

Computational fluid dynamics study of pulverized coal combustion in blast furnace raceway

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Y.S.; Maldonado, D.; Guo, B.Y.

In this work, a numerical model is used to study the flow and coal combustion along the coal plume in a large-scale setting simulating the lance-blowpipe-tuyere-raceway region of a blast furnace. The model formulation is validated against the measurements in terms of burnout for both low and high volatile coals. The typical phenomena related to coal combustion along the coal plume are simulated and analyzed. The effects of some operational parameters on combustion behavior are also investigated. The results indicate that oxygen as a cooling gas gives a higher coal burnout than methane and air. The underlying mechanism of coalmore » combustion is explored. It is shown that under the conditions examined, coal burnout strongly depends on the availability of oxygen and residence time. Moreover, the influences of two related issues, i.e. the treatment of volatile matter (VM) and geometric setting in modeling, are investigated. The results show that the predictions of final burnouts using three different VM treatments are just slightly different, but all comparable to the measurements. However, the influence of the geometric setting is not negligible when numerically examining the combustion of pulverized coal under blast furnace conditions.« less

Subgrid Combustion Modeling for the Next Generation National Combustion Code

NASA Technical Reports Server (NTRS)

Menon, Suresh; Sankaran, Vaidyanathan; Stone, Christopher

2003-01-01

In the first year of this research, a subgrid turbulent mixing and combustion methodology developed earlier at Georgia Tech has been provided to researchers at NASA/GRC for incorporation into the next generation National Combustion Code (called NCCLES hereafter). A key feature of this approach is that scalar mixing and combustion processes are simulated within the LES grid using a stochastic 1D model. The subgrid simulation approach recovers locally molecular diffusion and reaction kinetics exactly without requiring closure and thus, provides an attractive feature to simulate complex, highly turbulent reacting flows of interest. Data acquisition algorithms and statistical analysis strategies and routines to analyze NCCLES results have also been provided to NASA/GRC. The overall goal of this research is to systematically develop and implement LES capability into the current NCC. For this purpose, issues regarding initialization and running LES are also addressed in the collaborative effort. In parallel to this technology transfer effort (that is continuously on going), research has also been underway at Georgia Tech to enhance the LES capability to tackle more complex flows. In particular, subgrid scalar mixing and combustion method has been evaluated in three distinctly different flow field in order to demonstrate its generality: (a) Flame-Turbulence Interactions using premixed combustion, (b) Spatially evolving supersonic mixing layers, and (c) Temporal single and two-phase mixing layers. The configurations chosen are such that they can be implemented in NCCLES and used to evaluate the ability of the new code. Future development and validation will be in spray combustion in gas turbine engine and supersonic scalar mixing.

Characteristic Study of Shenmu Bituminous Coal Combustion with Online TG-MS-FTIR

NASA Astrophysics Data System (ADS)

Pan, Guanfu

2018-01-01

The combustion characteristics of Shenmu bituminous pulverized coal (SBC) were comprehensively investigated with a combined TG-MS-FTIR system by considering the effect of particle size, heating rate and total flowrate. The combustion products were accurately quantified by normalization and numerical analysis of MS results. The results indicate that the decrease of the particle size, heating rate and total flowrate result in lower ignition and burnout temperatures. The activation energy tends to be lower with smaller particle size, lower heating rate and total flowrate. The MS and FTIR results demonstrate that lower concentrations of different products, such as NO, NO2, HCN, CH4 and SO2 were produced with smaller particle size, slower heating rate and lower total flowrate. The decrease of particle size would lead to more contact area with oxygen and slower heating rate could provide more sufficient time for the diffusion. High total flowrate would reduce the oxygen adsorbability on the coal particle surface and shorten the residence time of oxygen, which makes the ignition difficult to occur. This work will guide to understand the combustion kinetics of pulverized coals and be beneficial to control the formation of pollutants.

Mechanistic Models for Ignition and Combustion of Metallic Powders in Different Environments

DTIC Science & Technology

2010-09-17

relevant chemical species (e.g. oxygen inward or aluminum outward) using Eq. (8.1), which requires as coefficients a pre-exponent and an activation...same experimental configuration was employed to study ignition of aluminum particles in different oxidizers. For oxygen / nitrogen gas mixtures , both...different durations are shown for all environments. The profiles measured for Al combustion in oxygen / nitrogen mixtures are collected in Figs. 10.3

Mechanism of influence water vapor on combustion characteristics of propane-air mixture

NASA Astrophysics Data System (ADS)

Larionov, V. M.; Mitrofanov, G. A.; Sachovskii, A. V.; Kozar, N. K.

2016-01-01

The article discusses the results of an experimental study of the effect of water vapor at the flame temperature. Propane-butane mixture with air is burning on a modified Bunsen burner. Steam temperature was varied from 180 to 260 degrees. Combustion parameters changed by steam temperature and its proportion in the mixture with the fuel. The fuel-air mixture is burned in the excess air ratio of 0.1. It has been established that the injection of steam changes the characteristics of combustion fuel-air mixture and increase the combustion temperature. The concentration of CO in the combustion products is substantially reduced. Raising the temperature in the combustion zone is associated with increased enthalpy of the fuel by the added steam enthalpy. Reducing the concentration of CO is caused by decrease in the average temperature in the combustion zone by applying steam. Concentration of active hydrogen radicals and oxygen increases in the combustion zone. That has a positive effect on the process of combustion.

Enhanced oxygen permeability in membrane-bottomed concave microwells for the formation of pancreatic islet spheroids.

PubMed

Lee, GeonHui; Jun, Yesl; Jang, HeeYeong; Yoon, Junghyo; Lee, JaeSeo; Hong, MinHyung; Chung, Seok; Kim, Dong-Hwee; Lee, SangHoon

2018-01-01

Oxygen availability is a critical factor in regulating cell viability that ultimately contributes to the normal morphogenesis and functionality of human tissues. Among various cell culture platforms, construction of 3D multicellular spheroids based on microwell arrays has been extensively applied to reconstitute in vitro human tissue models due to its precise control of tissue culture conditions as well as simple fabrication processes. However, an adequate supply of oxygen into the spheroidal cellular aggregation still remains one of the main challenges to producing healthy in vitro spheroidal tissue models. Here, we present a novel design for controlling the oxygen distribution in concave microwell arrays. We show that oxygen permeability into the microwell is tightly regulated by varying the poly-dimethylsiloxane (PDMS) bottom thickness of the concave microwells. Moreover, we validate the enhanced performance of the engineered microwell arrays by culturing non-proliferated primary rat pancreatic islet spheroids on varying bottom thickness from 10 μm to 1050 μm. Morphological and functional analyses performed on the pancreatic islet spheroids grown for 14 days prove the long-term stability, enhanced viability, and increased hormone secretion under the sufficient oxygen delivery conditions. We expect our results could provide knowledge on oxygen distribution in 3-dimensional spheroidal cell structures and critical design concept for tissue engineering applications. In this study, we present a noble design to control the oxygen distribution in concave microwell arrays for the formation of highly functional pancreatic islet spheroids by engineering the bottom of the microwells. Our new platform significantly enhanced oxygen permeability that turned out to improve cell viability and spheroidal functionality compared to the conventional thick-bottomed 3-D culture system. Therefore, we believe that this could be a promising medical biotechnology platform to

Advancements in Dual-Pump Broadband CARS for Supersonic Combustion Measurements

NASA Technical Reports Server (NTRS)

Tedder, Sarah Augusta Umberger

2010-01-01

Space- and time-resolved measurements of temperature and species mole fractions of nitrogen, oxygen, and hydrogen were obtained with a dual-pump coherent anti-Stokes Raman spectroscopy (CARS) system in hydrogen-fueled supersonic combustion free jet flows. These measurements were taken to provide time-resolved fluid properties of turbulent supersonic combustion for use in the creation and verification of computational fluid dynamic (CFD) models. CFD models of turbulent supersonic combustion flow currently facilitate the design of air-breathing supersonic combustion ramjet (scramjet) engines. Measurements were made in supersonic axi-symmetric free jets of two scales. First, the measurement system was tested in a laboratory environment using a laboratory-scale burner (approx.10 mm at nozzle exit). The flow structures of the laboratory-burner were too small to be resolved with the CARS measurements volume, but the composition and temperature of the jet allowed the performance of the system to be evaluated. Subsequently, the system was tested in a burner that was approximately 6 times larger, whose length scales are better resolved by the CARS measurement volume. During both these measurements, weaknesses of the CARS system, such as sensitivity to vibrations and beam steering and inability to measure temperature or species concentrations in hydrogen fuel injection regions were indentified. Solutions were then implemented in improved CARS systems. One of these improved systems is a dual-pump broadband CARS technique called, Width Increased Dual-pump Enhanced CARS (WIDECARS). The two lowest rotational energy levels of hydrogen detectable by WIDECARS are H2 S(3) and H2 S(4). The detection of these lines gives the system the capability to measure temperature and species concentrations in regions of the flow containing pure hydrogen fuel at room temperature. WIDECARS is also designed for measurements of all the major species (except water) in supersonic combustion flows

Oxygenated drinking water enhances immune activity in broiler chicks and increases survivability against Salmonella Gallinarum in experimentally infected broiler chicks.

PubMed

Jung, Bock-Gie; Lee, Jin-A; Nam, Kyoung-Woo; Lee, Bong-Joo

2012-03-01

It has been suggested that drinking oxygenated water may improve oxygen availability, which may increase vitality and improving immune activity. The present study evaluated the immune enhancing effects of oxygenated drinking water in broiler chicks and demonstrated the protective efficacy of oxygenated drinking water against Salmonella Gallinarum in experimentally infected broiler chicks. Continuous drinking of oxygenated water markedly increased serum lysozyme activity, peripheral blood mononuclear cell proliferation and the CD4(+)/CD8(+) splenocyte ratio in broiler chicks. In the chicks experimentally infected with S. Gallinarum, oxygenated drinking water alleviated symptoms and increased survival. These findings suggest that oxygenated drinking water enhances immune activity in broiler chicks, and increases survivability against S. Gallinarum in experimentally infected broiler chicks.

Enhancement of photocatalytic activity of combustion-synthesized CeO2/C3N4 nanoparticles

NASA Astrophysics Data System (ADS)

Li, Dong-Feng; Yang, Ke; Wang, Xiao-qin; Ma, Ya-Li; Huang, Gui-Fang; Huang, Wei-Qing

2015-09-01

Nanocrystalline CeO2/C3N4 was synthesized via a one-step solution combustion method using urea as fuel for the first time. The effects of the molar ratio of urea to cerium chloride on the photocatalytic activity of the synthesized samples were investigated. The synthesized nanocrystalline CeO2/C3N4 shows small size and large surface exposure area. Photocatalytic degradation of methylene blue demonstrates that the synthesized nanocrystalline CeO2/C3N4 possesses enhanced photocatalytic activity. It is proposed that the enhanced photocatalytic activity might be related to the favorable morphology and structure, and the effective charge separation between C3N4 and CeO2 in the photocatalytic process.

A study of the current group evaporation/combustion theories

NASA Technical Reports Server (NTRS)

Shen, Hayley H.

1990-01-01

Liquid fuel combustion can be greatly enhanced by disintegrating the liquid fuel into droplets, an effect achieved by various configurations. A number of experiments carried out in the seventies showed that combustion of droplet arrays and sprays do not form individual flames. Moreover, the rate of burning in spray combustion greatly deviates from that of the single combustion rate. Such observations naturally challenge its applicability to spray combustion. A number of mathematical models were developed to evaluate 'group combustion' and the related 'group evaporation' phenomena. This study investigates the similarity and difference of these models and their applicability to spray combustion. Future work that should be carried out in this area is indicated.

Formation and emission of large furans and oxygenated hydrocarbons from flames

DOE PAGES

Johansson, K. Olof; Dillstrom, Tyler; Monti, Matteo; ...

2016-07-07

Many oxygenated hydrocarbon species formed during combustion, such as furans, are highly toxic and detrimental to human health and the environment. These species may also increase the hygroscopicity of soot and strongly influence the effects of soot on regional and global climate. However, large furans and associated oxygenated species have not previously been observed in flames, and their formation mechanism and interplay with polycyclic aromatic hydrocarbons (PAHs) are poorly understood. We report on a synergistic computational and experimental effort that elucidates the formation of oxygen-embedded compounds, such as furans and other oxygenated hydrocarbons, during the combustion of hydrocarbon fuels. Wemore » used ab initio and probabilistic computational techniques to identify low-barrier reaction mechanisms for the formation of large furans and other oxygenated hydrocarbons. We used vacuum-UV photoionization aerosol mass spectrometry and X-ray photoelectron spectroscopy to confirm these predictions. We show that fura ns are produced in the high- Temperature regions of hydrocarbon flames, where they remarkably survive and become the main functional group of oxygenates that incorporate into incipient soot. In controlled flame studies, we discovered ~100 oxygenated species previously unaccounted for. We found that large alcohols and enols act as precursors to furans, leading to incorporation of oxygen into the carbon skeletons of PAHs. Our results depart dramatically from the crude chemistry of carbonand oxygen-containing molecules previously considered in hydrocarbon formation and oxidation models and spearhead the emerging understanding of the oxidation chemistry that is critical, for example, to control emissions of toxic and carcinogenic combustion by-products, which also greatly affect global warming.« less

NASA Microgravity Combustion Science Program

NASA Technical Reports Server (NTRS)

King, Merrill K.

1997-01-01

Combustion is a key element of many critical technologies used by contemporary society. For example, electric power production, home heating, surface and air transportation, space propulsion, and materials synthesis all utilize combustion as a source of energy. Yet, although combustion technology is vital to our standard of living, it poses great challenges to maintaining a habitable environment. For example, pollutants, atmospheric change and global warming, unwanted fires and explosions, and the incineration of hazardous wastes are major problem areas which would benefit from improved understanding of combustion. Effects of gravitational forces impede combustion studies more than most other areas of science since combustion involves production of high-temperature gases whose low density results in buoyant motion, vastly complicating the execution and interpretation of experiments. Effects of buoyancy are so ubiquitous that their enormous negative impact on the rational development of combustion science is generally not recognized. Buoyant motion also triggers the onset of turbulence, yielding complicating unsteady effects. Finally, gravity forces cause particles and drops to settle, inhibiting deconvoluted studies of heterogeneous flames important to furnace, incineration and power generation technologies. Thus, effects of buoyancy have seriously limited our capabilities to carry out 'clean' experiments needed for fundamental understanding of flame phenomena. Combustion scientists can use microgravity to simplify the study of many combustion processes, allowing fresh insights into important problems via a deeper understanding of elemental phenomena also found in Earth-based combustion processes and to additionally provide valuable information concerning how fires behave in microgravity and how fire safety on spacecraft can be enhanced.

Direct-Coupled Plasma-Assisted Combustion Using a Microwave Waveguide Torch

DTIC Science & Technology

2011-12-01

enhance combustion by coupling an atmospheric plasma dis- charge to a premixed methane/air flame. The absorbed microwave power ranges from 60 to 150 W...The plasma system allows for complete access of the plasma- enhanced flame for laser and optical diagnostics 0093-3813/$26.00 © 2011 IEEE Report...microwave waveguide is used to initiate and enhance combustion by coupling an atmospheric plasma discharge to a premixed methane/air flame. The

Diffusion Limitation and Hyperoxic Enhancement of Oxygen Consumption in Zooxanthellate Sea Anemones, Zoanthids, and Corals.

PubMed

Shick, J M

1990-08-01

Depending on their size and morphology, anthozoan polyps and colonies may be diffusion-limited in their oxygen consumption, even under well-stirred, air-saturated conditions. This is indicated by an enhancement of oxygen consumption under steady-state hyperoxic conditions that simulate the levels of O2 produced photosynthetically by zooxanthellae in the hosts' tissues. Such hyperoxia in the tissues of zooxanthellate species negates the effect of the diffusive boundary layer, and increases the rate of oxygen consumption; thus, in many cases, the rate of respiration measured under normoxia in the dark may not be representative of the rate during the day when the zooxanthellae are photosynthesizing and when the supply of oxygen for respiration is in the tissues themselves, not from the environment. These results have implications in respirometric methodology and in calculating the rate of gross photosynthesis in energetic studies. The activity of cytochrome c oxidase is higher in aposymbiotic than in zooxanthellate specimens of the sea anemone Aiptasia pulchella, and this may indicate a compensation for the relative hypoxia in the tissues of the former, enhancing the delivery of oxygen to the mitochondria from the environment.

Ultrasound beam steering of oxygen nanobubbles for enhanced bladder cancer therapy.

PubMed

Bhandari, Pushpak; Novikova, Gloriia; Goergen, Craig J; Irudayaraj, Joseph

2018-02-15

New intravesical treatment approaches for bladder cancer are needed as currently approved treatments show several side effects and high tumor recurrence rate. Our study used MB49 murine urothelial carcinoma model to evaluate oxygen encapsulated cellulosic nanobubbles as a novel agent for imaging and ultrasound guided drug delivery. In this study, we show that oxygen nanobubbles (ONB) can be propelled (up to 40 mm/s) and precisely guided in vivo to the tumor by an ultrasound beam. Nanobubble velocity can be controlled by altering the power of the ultrasound Doppler beam, while nanobubble direction can be adjusted to different desired angles by altering the angle of the beam. Precise ultrasound beam steering of oxygen nanobubbles was shown to enhance the efficacy of mitomycin-C, resulting in significantly lower tumor progression rates while using a 50% lower concentration of chemotherapeutic drug. Further, dark field imaging was utilized to visualize and quantify the ONB ex vivo. ONBs were found to localize up to 500 µm inside the tumor using beam steering. These results demonstrate the potential of an oxygen nanobubble drug encapsulated system to become a promising strategy for targeted drug delivery because of its multimodal (imaging and oxygen delivery) and multifunctional (targeting and hypoxia programming) properties.

Droplet Combustion Experiment on STS-94

NASA Technical Reports Server (NTRS)

2003-01-01

Fuel ignites and burns in the Droplet Combustion Experiment (DCE) on STS-94 on July 12, 1997, MET:11/07:00 (approximate). DCE used various fuels -- in drops ranging from 1 mm (0.04 inches) to 5 mm (0.2 inches) -- and mixtures of oxidizers and inert gases to learn more about the physics of combustion in the simplest burning configuration, a sphere. The DCE was designed to investigate the fundamental combustion aspects of single, isolated droplets under different pressures and ambient oxygen concentrations for a range of droplet sizes varying between 2 and 5 mm. The experiment elapsed time is shown at the bottom of the composite image. The DCE principal investigator was Forman Williams, University of California, San Diego. The experiment was part of the space research investigations conducted during the Microgravity Science Laboratory-1R mission (STS-94, July 1-17 1997). Advanced combustion experiments will be a part of investigations plarned for the International Space Station. (1.3MB, 13-second MPEG, screen 320 x 240 pixels; downlinked video, higher quality not available) A still JPG composite of this movie is available at http://mix.msfc.nasa.gov/ABSTRACTS/MSFC-0300170.html.

Preburner of Staged Combustion Rocket Engine

NASA Technical Reports Server (NTRS)

Yost, M. C.

1978-01-01

A regeneratively cooled LOX/hydrogen staged combustion assembly system with a 400:1 expansion area ratio nozzle utilizing an 89,000 Newton (20,000 pound) thrust regeneratively cooled thrust chamber and 175:1 tubular nozzle was analyzed, assembled, and tested. The components for this assembly include two spark/torch oxygen-hydrogen igniters, two servo-controlled LOX valves, a preburner injector, a preburner combustor, a main propellant injector, a regeneratively cooled combustion chamber, a regeneratively cooled tubular nozzle with an expansion area ratio of 175:1, an uncooled heavy-wall steel nozzle with an expansion area ratio of 400:1, and interconnecting ducting. The analytical effort was performed to optimize the thermal and structural characteristics of each of the new components and the ducting, and to reverify the capabilities of the previously fabricated components. The testing effort provided a demonstration of the preburner/combustor chamber operation, chamber combustion efficiency and stability, and chamber and nozzle heat transfer.

Fireside corrosion in oxy-fuel combustion of coal

DOE PAGES

Holcomb, Gordon R.; Tylczak, Joseph; Meier, Gerald H.; ...

2011-08-01

Oxy-fuel combustion is based on burning fossil fuels in a mixture of recirculated flue gas and oxygen, rather than in air. An optimized oxy-combustion power plant will have ultra-low emissions since the flue gas that results from oxy-fuel combustion consists almost entirely of CO2 and water vapor. Once the water vapor is condensed, it is relatively easy to sequester the CO2 so that it does not escape into the atmosphere. A variety of laboratory tests comparing air-firing to oxy-firing conditions, and tests examining specific simpler combinations of oxidants, were conducted at 650-700 C. Alloys studied included model Fe-Cr and Ni-Crmore » alloys, commercial ferritic steels, austenitic steels, and nickel base superalloys. Furthermore, the observed corrosion behavior shows accelerated corrosion even with sulfate additions that remain solid at the tested temperatures, encapsulation of ash components in outer iron oxide scales, and a differentiation between oxy-fuel combustion flue gas recirculation choices.« less

Navier-Stokes Entropy Controlled Combustion Instability Analysis for Liquid Propellants

NASA Technical Reports Server (NTRS)

Chung, T. J.; Yoon, W. S.

1990-01-01

Navier-Stokes solutions are used to calculate oscillatory components of pressure, velocity, and density, which in turn provide necessary data to compute energy growth factors to determine combustion instability. It is shown that wave instabilities are associated with changes in entropy and the space and time averages of oscillatory components of pressure, velocity and density, together with the mean flow field in the energy equation. Compressible laminar and turbulent flows and reacting flows with hydrogen/oxygen combustion are considered. The SSME combustion/thrust chamber is used for illustration of the theory. The analysis shows that the increase of mean pressure and disturbances consistently results in the increase of instability. It is shown that adequate combustion instability analysis requires at least third order nonlinearity in energy growth or decay.

Gravity Effects on Combustion Synthesis of Glasses

NASA Technical Reports Server (NTRS)

Yi, H. C.; Guigne, J. Y.; Moore, J. J.; Robinson, L. A.; Manerbino, A. R.; Schowengerdt, F. D.; Gokoglu, S. (Technical Monitor)

2000-01-01

The Combustion Synthesis technique has been used to produce glasses based on B2O3-Al2O3-MgO and CaO-Al2O3. The combustion characteristics of these combustion synthesis reactions using both small cylindrical pellets (SCP) and large spherical pellets (LSP) are presented. Low density pellets (approx. 35% of their theoretical density) were used, which made synthesis of low exothermic combustion reactions possible. Microstructural analysis of reacted samples was carried out to identify the glass-forming compositions. The effects of gravity on the glass formation were studied aboard the KC-135 using SCP samples. Gravity seemed to have such obvious effects on the combustion characteristics that the wave velocity was lower and the Width of the combustion wave was larger under reduced gravity conditions. Samples produced under low gravity also had more enhanced vitrification than those on ground, while some systems also exhibited lower combustion temperatures. It was also found that the container significantly affects both the combustion characteristics and microstructure. Substantially more divitrification occurred at the area which was in contact with the support (container).

Oxygen-deficient photostable Cu2O for enhanced visible light photocatalytic activity.

PubMed

Singh, Mandeep; Jampaiah, Deshetti; Kandjani, Ahmad E; Sabri, Ylias M; Della Gaspera, Enrico; Reineck, Philipp; Judd, Martyna; Langley, Julien; Cox, Nicholas; van Embden, Joel; Mayes, Edwin L H; Gibson, Brant C; Bhargava, Suresh K; Ramanathan, Rajesh; Bansal, Vipul

2018-03-29

Oxygen vacancies in inorganic semiconductors play an important role in reducing electron-hole recombination, which may have important implications in photocatalysis. Cuprous oxide (Cu2O), a visible light active p-type semiconductor, is a promising photocatalyst. However, the synthesis of photostable Cu2O enriched with oxygen defects remains a challenge. We report a simple method for the gram-scale synthesis of highly photostable Cu2O nanoparticles by the hydrolysis of a Cu(i)-triethylamine [Cu(i)-TEA] complex at low temperature. The oxygen vacancies in these Cu2O nanoparticles led to a significant increase in the lifetimes of photogenerated charge carriers upon excitation with visible light. This, in combination with a suitable energy band structure, allowed Cu2O nanoparticles to exhibit outstanding photoactivity in visible light through the generation of electron-mediated hydroxyl (OH˙) radicals. This study highlights the significance of oxygen defects in enhancing the photocatalytic performance of promising semiconductor photocatalysts.

Heat of Combustion of the Product Formed by the Reaction of Acetylene, Ethylene, and Diborane

NASA Technical Reports Server (NTRS)

Tannenbaum, Stanley

1957-01-01

The net heat of combustion of the product formed by the reaction of diborane with a mixture of acetylene and ethylene was found to be 20,440 +/- 150 Btu per pound for the reaction of liquid fuel to gaseous carbon dioxide, gaseous water, and solid boric oxide. The measurements were made in a Parr oxygen-bomb calorimeter, and the combustion was believed to be 98 percent complete. The estimated net-heat of combustion for complete combustion would therefore be 20,850 +/- 150 Btu per pound.

Comparison of waste combustion and waste electrolysis - A systems analysis

NASA Technical Reports Server (NTRS)

Holtzapple, Mark T.; Little, Frank E.

1989-01-01

A steady state model of a closed environmental system has been developed which includes higher plant growth for food production, and is designed to allow wastes to be combusted or electrolyzed. The stoichiometric equations have been developed to evaluate various trash compositions, food items (both stored and produced), metabolic rates, and crew sizes. The advantages of waste electrolysis versus combustion are: (1) oxygen is not required (which reduces the load on the oxygen producing system); (2) the CO2 and H2 products are produced in pure form (reducing the load on the separators); and (3) nitrogen is converted to nitrate (which is directly usable by plants). Weight tradeoff studies performed using this model have shown that waste electrolysis reduces the life support weight of a 4-person crew by 1000 to 2000 kg.

Acoustically Forced Coaxial Hydrogen/Liquid Oxygen Jet Flames

DTIC Science & Technology

2016-05-15

Briefing Charts 3. DATES COVERED (From - To) 25 April 2016 - 15 May 2016 4. TITLE AND SUBTITLE Acoustically Forced Coaxial Hydrogen / Liquid Oxygen Jet...area code) N/A Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std. 239.18 1 Acoustically Forced Coaxial Hydrogen / Liquid Oxygen Jet Flames...propellants be stored in condensed form – e.g., kerosene, liquid oxygen in rockets • Combustion systems can no longer be designed to meet modern

RELATIONSHIPS BETWEEN COMPOSITION AND PULMONARY TOXICITY OF PROTOTYPE PARTICLES FROM COAL COMBUSTION AND PYROLYSIS (MONTREAL, CANADA)

EPA Science Inventory

The hypothesis that health effects associated with coal combustion fly-ash particles are exacerbated by the simultaneous presence of iron and soot was tested through two sets of experiments. The first set created prototype particles from complete and partial combustion, or oxygen...

Oxygen stabilization induced enhancement in superconducting characteristics of high-Tc oxides

NASA Technical Reports Server (NTRS)

Wu, M. K.; Chen, J. T.; Huang, C. Y.

1991-01-01

In an attempt to enhance the electrical and mechanical properties of the high temperature superconducting oxides, high T(sub c) composites were prepared composed of the 123 compounds and AgO. The presence of extra oxygen due to the decomposition of AgO at high temperature is found to stabilize the superconducting 123 phase. Ag is found to serve as clean flux for grain growth and precipitates as pinning center. Consequently, almost two orders of magnitude enhancement in critical current densities were also observed in these composites. In addition, these composites also show much improvement in workability and shape formation. On the other hand, proper oxygen treatment of Y5Ba6Cu11Oy was found to possibly stabilize superconducting phase with T(sub c) near 250 K. I-V, ac susceptibility, and electrical resistivity measurements indicate the existence of this ultra high T(sub c) phase in this compound. Detailed structure, microstructure, electrical, magnetic and thermal studies of the superconducting composites and the ultra high T(sub c) compound are presented and discussed.

Combustion characteristics of fine- and micro-pulverized coal in the mixture of O{sub 2}/CO{sub 2}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiangyong Huang; Xiumin Jiang; Xiangxin Han

The effects of oxygen concentration, particle size, and heating rate on the coal combustion characteristics under an O{sub 2}/CO{sub 2} atmosphere were investigated. The results indicated that the oxygen concentration played the most important role. As the oxygen concentration increases, the ignition and burnout temperatures decrease and the comprehensive combustion property index S increases. Moreover, the improvement of the oxygen concentration intensified the effects of the other factors. The ignition mechanism changes from hetero-homogeneous type to homogeneous type as the oxygen concentration increases. The ignition and burnout temperatures decrease slightly as the mean particle size decreases, and the index Smore » increases measurably as the mean particle size decreases. The heating rate has different effects on the ignition temperature, burnout temperature, and index S at different oxygen concentrations. 19 refs., 9 figs., 2 tabs.« less

Characterisation of acoustic energy content in an experimental combustion chamber with and without external forcing

NASA Astrophysics Data System (ADS)

Webster, S.; Hardi, J.; Oschwald, M.

2015-03-01

The influence of injection conditions on rocket engine combustion stability is investigated for a sub-scale combustion chamber with shear coaxial injection elements and the propellant combination hydrogen-oxygen. The experimental results presented are from a series of tests conducted at subcritical and supercritical pressures for oxygen and for both ambient and cryogenic temperature hydrogen. The stability of the system is characterised by the root mean squared amplitude of dynamic combustion chamber pressure in the upper part of the acoustic spectrum relevant for high frequency combustion instabilities. Results are presented for both unforced and externally forced combustion chamber configurations. It was found that, for both the unforced and externally forced configurations, the injection velocity had the strongest influence on combustion chamber stability. Through the use of multivariate linear regression the influence of hydrogen injection temperature and hydrogen injection mass flow rate were best able to explain the variance in stability for dependence on injection velocity ratio. For unforced tests turbulent jet noise from injection was found to dominate the energy content of the signal. For the externally forced configuration a non-linear regression model was better able to predict the variance, suggesting the influence of non-linear behaviour. The response of the system to variation of injection conditions was found to be small; suggesting that the combustion chamber investigated in the experiment is highly stable.

Technology for Transient Simulation of Vibration during Combustion Process in Rocket Thruster

NASA Astrophysics Data System (ADS)

Zubanov, V. M.; Stepanov, D. V.; Shabliy, L. S.

2018-01-01

The article describes the technology for simulation of transient combustion processes in the rocket thruster for determination of vibration frequency occurs during combustion. The engine operates on gaseous propellant: oxygen and hydrogen. Combustion simulation was performed using the ANSYS CFX software. Three reaction mechanisms for the stationary mode were considered and described in detail. The way for obtaining quick CFD-results with intermediate combustion components using an EDM model was found. The way to generate the Flamelet library with CFX-RIF was described. A technique for modeling transient combustion processes in the rocket thruster was proposed based on the Flamelet library. A cyclic irregularity of the temperature field like vortex core precession was detected in the chamber. Frequency of flame precession was obtained with the proposed simulation technique.

Effects of combustibles on internal quasi-static loads

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sandoval, N.R.; Hokanson, J.C.; Esparza, E.D.

1984-08-01

The phenomenon of quasi-static pressure enhancement produced when combustible materials are placed near HE sources has been recently discovered. The effects of placing solid and liquid combustible materials near detonating explosives on internal blast loading was measured during tests conducted in a one-eighth scale model of a containment structure. In many cases, dramatic increases in gas pressures resulted. Principal conclusions of this study are: combustible materials near explosives can markedly increase gas pressures in enclosed structures; there is a lack of data on HE-combustible combinations; quasi-static loading calculations should include estimates of contributions from the burning of combustible materials whenevermore » such materials are expected to be in intimate contact with HE sources; and effects of combustibles should be investigated further to determine methods for prediction. Variations in charge to combustible mass, charge type, structure volume, degree of venting and degree of contact between HE and combustible sbould be studied.« less

Combustion in a multiburner furnace with selective flow of oxygen

DOEpatents

Bool, III, Lawrence E.; Kobayashi, Hisashi

2004-03-02

Improved operational characteristics such as improved fuel efficiency, reduction of NOx formation, reduction of the amount of unburned carbon in the ash, and lessened tendency to corrosion at the tube wall, in a multi-burner furnace are obtained by reducing the flow rate of combustion air to the burners and selectively individually feeding oxidant to only some of the burners.

Influence of different types of coals and stoves on the emissions of parent and oxygenated PAHs from residential coal combustion in China.

PubMed

Wang, Yan; Xu, Yue; Chen, Yingjun; Tian, Chongguo; Feng, Yanli; Chen, Tian; Li, Jun; Zhang, Gan

2016-05-01

To evaluate the influence of coal property and stove efficiency on the emissions of parent polycyclic aromatic hydrocarbons (pPAHs) and oxygenated PAHs (oPAHs) during the combustion, fifteen coal/stove combinations were tested in this study, including five coals of different geological maturities in briquette and chunk forms burned in two residential stoves. The emission factors (EFs) of pPAHs and oPAHs were in the range of 0.129-16.7 mg/kg and 0.059-0.882 mg/kg, respectively. The geological maturity of coal significantly affected the emissions of pPAHs and oPAHs with the lower maturity coals yielding the higher emissions. The chunk-to-briquette transformation of coal dramatically increased the emissions of pPAHs and oPAHs during the combustion of anthracite, whereas this transformation only elevated the emissions of high molecular weight PAHs for bituminous coals. The influence of stove type on the emissions of pPAHs and oPAHs was also geological-maturity-dependent. High efficiency stove significantly reduced the emissions of PAHs from those relatively high-maturity coals, but its influences on low-maturity coals were inconstant. Copyright © 2016 Elsevier Ltd. All rights reserved.

Combustion of Coal Char Particles under Fluidized Bed Oxyfiring Conditions

NASA Astrophysics Data System (ADS)

Scala, Fabrizio; Chirone, Riccardo

In this work combustion of single coal char particles was studied at 850°C in a lab-scale fluidized bed under simulated oxyfiring conditions. The burning rate of the particles was followed as a function of time by continuously measuring the outlet CO and O2 concentrations. Some preliminary evaluations on the significance of homogeneous CO oxidation in the reactor and of carbon gasification by CO2 in the char were also carried out. Results showed that the carbon burning rate increases with oxygen concentration and char particle size. The particle temperature is approximately equal to the bed one up to an oxygen concentration of 2%, but it is considerably higher for larger oxygen concentrations. Both CO2 gasification of char and homogeneous CO oxidation are not negligible. The gasification reaction rate is slow and it is likely to be controlled by intrinsic kinetics. During purely gasification conditions the extent of carbon loss due to particle attrition by abrasion (estimated from the carbon mass balance) appears to be more important than under combustion conditions.

Microjet burners for molecular-beam sources and combustion studies

NASA Astrophysics Data System (ADS)

Groeger, Wolfgang; Fenn, John B.

1988-09-01

A novel microjet burner is described in which combustion is stabilized by a hot wall. The scale is so small that the entire burner flow can be passed through a nozzle only 0.2 mm or less in diameter into an evacuated chamber to form a supersonic free jet with expansion so rapid that all collisional processes in the jet gas are frozen in a microsecond or less. This burner can be used to provide high-temperature source gas for free jet expansion to produce intense beams of internally hot molecules. A more immediate use would seem to be in the analysis of combustion products and perhaps intermediates by various kinds of spectroscopies without some of the perturbation effects encountered in probe sampling of flames and other types of combustion devices. As an example of the latter application of this new tool, we present infrared emission spectra for jet gas obtained from the combustion of oxygen-hydrocarbon mixtures both fuel-rich and fuel-lean operation. In addition, we show results obtained by mass spectrometric analysis of the combustion products.

Heat of Combustion of the Product Formed by the Reaction of Acetylene and Diborane (LFPL-CZ-3)

NASA Technical Reports Server (NTRS)

Allen, Harrison, Jr.; Tannenbaum, Stanley

1957-01-01

The heat of combustion of the product formed by the reaction acetylene and diborane was found to be 20,100 +/- 100 Btu per pound for the reaction of liquid fuel to gaseous carbon dioxide, gaseous water, and solid boric oxide. The measurements were made in a Parr oxygen-bomb calorimeter, and chemical analyses both of the sample and of the combustion products indicated combustion in the bomb calorimeter to have been 97 percent complete. The estimated net heat of combustion for complete combustion would therefore be 20,700 +/- 100 Btu per pound.

Physiologic oxygen concentration enhances the stem-like properties of CD133+ human glioblastoma cells in vitro.

PubMed

McCord, Amy M; Jamal, Muhammad; Shankavaram, Uma T; Shankavarum, Uma T; Lang, Frederick F; Camphausen, Kevin; Tofilon, Philip J

2009-04-01

In vitro investigations of tumor stem-like cells (TSC) isolated from human glioblastoma (GB) surgical specimens have been done primarily at an atmospheric oxygen level of 20%. To determine whether an oxygen level more consistent with in situ conditions affects their stem cell-like characteristics, we compared GB TSCs grown under conditions of 20% and 7% oxygen. Growing CD133(+) cells sorted from three GB neurosphere cultures at 7% O(2) reduced their doubling time and increased the self-renewal potential as reflected by clonogenicity. Furthermore, at 7% oxygen, the cultures exhibited an enhanced capacity to differentiate along both the glial and neuronal pathways. As compared with 20%, growth at 7% oxygen resulted in an increase in the expression levels of the neural stem cell markers CD133 and nestin as well as the stem cell markers Oct4 and Sox2. In addition, whereas hypoxia inducible factor 1alpha was not affected in CD133(+) TSCs grown at 7% O(2), hypoxia-inducible factor 2alpha was expressed at higher levels as compared with 20% oxygen. Gene expression profiles generated by microarray analysis revealed that reducing oxygen level to 7% resulted in the up-regulation and down-regulation of a significant number of genes, with more than 140 being commonly affected among the three CD133(+) cultures. Furthermore, Gene Ontology categories up-regulated at 7% oxygen included those associated with stem cells or GB TSCs. Thus, the data presented indicate that growth at the more physiologically relevant oxygen level of 7% enhances the stem cell-like phenotype of CD133(+) GB cells.

Ignition and Combustion of Bulk Metals in a Microgravity Environment

NASA Technical Reports Server (NTRS)

Branch, M. C.; Daily, J. W.; Abbud-Madrid, A.

1996-01-01

This annual report summarizes the latest results obtained in a NASA-supported project to investigate the effect of gravity on the ignition and combustion of bulk metals. The experimental arrangement used for this purpose consists of a 1000-W xenon lamp that irradiates the top surface of cylindrical titanium and magnesium specimens, 4 mm in diameter and 4 mm in height, in a quiescent, pure-oxygen environment at 1 atm. Reduced gravity is obtained from the NASA LeRC DC-9 aircraft flying parabolic trajectories. Values of critical and ignition temperatures are obtained from thermocouple records. Qualitative observations and propagation rates are extracted from high-speed cinematography. Emission spectra of gas-phase reactions are obtained with an imaging spectrograph/diode array system. It was found that high applied heating rates and large internal conduction losses generate critical and ignition temperatures that are several hundred degrees above the values obtained from isothermal experiments. Because of high conduction and radiation heat losses, no appreciable effect on ignition temperatures with reduced convection in low gravity is detected. Lower propagation rates of the molten interface on titanium and of ignition waves on magnesium are obtained at reduced gravity. These rates are compared to theoretical results from heat conduction analyses with a diffusion/convection controlled reaction. The close agreement found between experimental and theoretical values indicates the importance of the influence of natural convection-enhanced oxygen transport on combustion rates. Lower oxygen flux and lack of oxide product removal in the absence of convective currents appear to be responsible for longer burning times of magnesium diffusion flames at reduced gravity. The accumulation of condensed oxide particles in the flame front at low gravity produces a previously unreported unsteady explosion phenomenon in bulk magnesium flames. This spherically symmetric explosion

Two phase exhaust for internal combustion engine

DOEpatents

Vuk, Carl T [Denver, IA

2011-11-29

An internal combustion engine having a reciprocating multi cylinder internal combustion engine with multiple valves. At least a pair of exhaust valves are provided and each supply a separate power extraction device. The first exhaust valves connect to a power turbine used to provide additional power to the engine either mechanically or electrically. The flow path from these exhaust valves is smaller in area and volume than a second flow path which is used to deliver products of combustion to a turbocharger turbine. The timing of the exhaust valve events is controlled to produce a higher grade of energy to the power turbine and enhance the ability to extract power from the combustion process.

Oxygen Compatibility Testing of Composite Materials

NASA Technical Reports Server (NTRS)

Engel, Carl D.; Watkins, Casey N.

2006-01-01

Composite materials offer significant weight-saving potential for aerospace applications in propellant and oxidizer tanks. This application for oxygen tanks presents the challenge of being oxygen compatible in addition to complying with the other required material characteristics. This effort reports on the testing procedures and data obtained in examining and selecting potential composite materials for oxygen tank usage. Impact testing of composites has shown that most of these materials initiate a combustion event when impacted at 72 ft-lbf in the presence of liquid oxygen, though testing has also shown substantial variability in reaction sensitivities to impact. Data for screening of 14 potential composites using the Bruceton method is given herein and shows that the 50-percent reaction frequencies range from 17 to 67 ft-lbf. The pressure and temperature rises for several composite materials were recorded to compare the energy releases as functions of the combustion reactions with their respective reaction probabilities. The test data presented are primarily for a test pressure of 300 psia in liquid oxygen. The impact screening process is compared with oxygen index and autogenous ignition test data for both the composite and the basic resin. The usefulness of these supplemental tests in helping select the most oxygen compatible materials is explored. The propensity for mechanical impact ignition of the composite compared with the resin alone is also examined. Since an ignition-free composite material at the peak impact energy of 72 ft-lbf has not been identified, composite reactivity must be characterized over the impact energy level and operating pressure ranges to provide data for hazard analyses in selecting the best potential material for liquid tank usage.

Apparatus and method for solid fuel chemical looping combustion

DOEpatents

Siriwardane, Ranjani V; Weber, Justin M

2015-04-14

The disclosure provides an apparatus and method utilizing fuel reactor comprised of a fuel section, an oxygen carrier section, and a porous divider separating the fuel section and the oxygen carrier section. The porous divider allows fluid communication between the fuel section and the oxygen carrier section while preventing the migration of solids of a particular size. Maintaining particle segregation between the oxygen carrier section and the fuel section during solid fuel gasification and combustion processes allows gases generated in either section to participate in necessary reactions while greatly mitigating issues associated with mixture of the oxygen carrier with char or ash products. The apparatus and method may be utilized with an oxygen uncoupling oxygen carrier such as CuO, Mn.sub.3O.sub.4, or Co.sub.3O.sub.4, or utilized with a CO/H.sub.2 reducing oxygen carrier such as Fe.sub.2O.sub.3.

Fuelling the palaeoatmospheric oxygen debate: how much atmospheric oxygen is required for ignition and propagation of smouldering fires?

NASA Astrophysics Data System (ADS)

Belcher, Claire M.; Hadden, Rory; McElwain, Jennifer C.; Rein, Guillermo

2010-05-01

Fire is a natural process integral to ecosystems at a wide range of temporal and spatial scales and is a key driver of change in the Earth system. Fire has been a major influence on Earth's systems since the Carboniferous. Whilst, climate is considered the ultimate control on global vegetation, fire is now known to play a key role in determining vegetation structure and composition, such that many of the world's ecosystems can be considered fire-dependant. Products of fire include chars, soots and aromatic hydrocarbon species all of which can be traced in ancient through to modern sediments. Atmospheric oxygen has played a key role in the development of life on Earth, with the rise of oxygen in the Precambrian being closely linked to biological evolution. Variations in the concentration of atmospheric oxygen throughout the Phanerozoic are predicted from models based on geochemical cycling of carbon and sulphur. Such models predict that low atmospheric oxygen concentrations prevailed in the Mesozoic (251-65ma) and have been hypothesised to be the primary driver of at least two of the ‘big five' mass extinction events in the Phanerozoic. Here we assess the levels of atmospheric oxygen required to ignite a fire and infer the likely levels of atmospheric oxygen to support smouldering combustion. Smouldering fire dynamics and its effects on ecosystems are very different from flaming fires. Smouldering fires propagate slowly, are usually low in temperature and represent a flameless form of combustion. These fires creep through organic layers of forest ground and peat lands and are responsible for a large fraction of the total biomass consumed in wildfires globally and are also a major contributor of carbon dioxide to the atmosphere. Once ignited, they can persist for long periods of time (months, years) spreading over very extensive areas of forest and deep into soil. Smouldering fires are therefore, the oldest continuously burning fires on Earth. We have combined

Premixed flame propagation in combustible particle cloud mixtures

NASA Technical Reports Server (NTRS)

Seshadri, K.; Yang, B.

1993-01-01

The structures of premixed flames propagating in combustible systems, containing uniformly distributed volatile fuel particles, in an oxidizing gas mixtures is analyzed. The experimental results show that steady flame propagation occurs even if the initial equivalence ratio of the combustible mixture based on the gaseous fuel available in the particles, phi(u) is substantially larger than unity. A model is developed to explain these experimental observations. In the model it is presumed that the fuel particles vaporize first to yield a gaseous fuel of known chemical composition which then reacts with oxygen in a one-step overall process. It is shown that the interplay of vaporization kinetics and oxidation process, can result in steady flame propagation in combustible mixtures where the value of phi(u) is substantially larger than unity. This prediction is in agreement with experimental observations.

Combustion characteristics and arsenic retention during co-combustion of agricultural biomass and bituminous coal.

PubMed

Zhou, Chuncai; Liu, Guijian; Wang, Xudong; Qi, Cuicui; Hu, Yunhu

2016-08-01

A combination of thermogravimetric analysis (TG) and laboratory-scale circulated fluidized bed combustion experiment was conducted to investigate the thermochemical, kinetic and arsenic retention behavior during co-combustion bituminous coal with typical agricultural biomass. Results shown that ignition performance and thermal reactivity of coal could be enhanced by adding biomass in suitable proportion. Arsenic was enriched in fly ash and associated with fine particles during combustion of coal/biomass blends. The emission of arsenic decreased with increasing proportion of biomass in blends. The retention of arsenic may be attributed to the interaction between arsenic and fly ash components. The positive correlation between calcium content and arsenic concentration in ash suggesting that the arsenic-calcium interaction may be regarded as the primary mechanism for arsenic retention. Copyright © 2016 Elsevier Ltd. All rights reserved.

Vertical migration of aggregated aerobic and anaerobic ammonium oxidizers enhances oxygen uptake in a stagnant water layer.

PubMed

Vlaeminck, Siegfried E; Dierick, Katleen; Boon, Nico; Verstraete, Willy

2007-07-01

Ammonium can be removed as dinitrogen gas by cooperating aerobic and anaerobic ammonium-oxidizing bacteria (AerAOB and AnAOB). The goal of this study was to verify putative mutual benefits for aggregated AerAOB and AnAOB in a stagnant freshwater environment. In an ammonium fed water column, the biological oxygen consumption rate was, on average, 76 kg O(2) ha(-1) day(-1). As the oxygen transfer rate of an abiotic control column was only 17 kg O(2) ha(-1) day(-1), biomass activity enhanced the oxygen transfer. Increasing the AnAOB gas production increased the oxygen consumption rate with more than 50% as a result of enhanced vertical movement of the biomass. The coupled decrease in dissolved oxygen concentration increased the diffusional oxygen transfer from the atmosphere in the water. Physically preventing the biomass from rising to the upper water layer instantaneously decreased oxygen and ammonium consumption and even led to the occurrence of some sulfate reduction. Floating of the biomass was further confirmed to be beneficial, as this allowed for the development of a higher AerAOB and AnAOB activity, compared to settled biomass. Overall, the results support mutual benefits for aggregated AerAOB and AnAOB, derived from the biomass uplifting effect of AnAOB gas production.

A review of oxygen removal from oxygen-bearing coal-mine methane.

PubMed

Zhao, Peiyu; Zhang, Guojie; Sun, Yinghui; Xu, Ying

2017-06-01

In this article, a comparison will be made concerning the advantages and disadvantages of five kinds of coal mine methane (CMM) deoxygenation method, including pressure swing adsorption, combustion, membrane separation, non-metallic reduction, and cryogenic distillation. Pressure swing adsorption has a wide range of application and strong production capacity. To achieve this goal, adsorbent must have high selectivity, adsorption capacity, and adequate adsorption/desorption kinetics, remain stable after several adsorption/desorption cycles, and possess good thermal and mechanical stabilities. Catalytic combustion deoxygenation is a high-temperature exothermic redox chemical reaction, which releases large amounts of thermal energy. So, the stable and accurate control of the temperature is not easy. Meanwhile partial methane is lost. The key of catalytic combustion deoxygenation lies in the development of high-efficiency catalyst. Membrane separation has advantages of high separation efficiency and low energy consumption. However, there are many obstacles, including higher costs. Membrane materials have the requirements of both high permeability and high selectivity. The development of new membrane materials is a key for membrane separation. Cryogenic distillation has many excellence advantages, such as high purity production and high recovery. However, the energy consumption increases with decreasing CH 4 concentrations in feed gas. Moreover, there are many types of operational security problems. And that several kinds of deoxygenation techniques mentioned above have an economic value just for oxygen-bearing CMM with methane content above 30%. Moreover, all the above methods are not applicable to deoxygenation of low concentration CMM. Non-metallic reduction method cannot only realize cyclic utilization of deoxidizer but also have no impurity gases generation. It also has a relatively low cost and low loss rate of methane, and the oxygen is removed thoroughly. In

Ignition characteristics of the nickel-based alloy UNS N07001 in pressurized oxygen

NASA Technical Reports Server (NTRS)

Bransford, J. W.; Billiard, P. A.

1990-01-01

The development of ignition and combustion in pressurized oxygen atmospheres was studied for the nickel-based alloy UNS N07001. Ignition of the alloy was achieved by heating the top surface of a cylindrical specimen with a continuous-wave CO2 laser. Two heating procedures were used. In the first, laser power was adjusted to maintain an approximately linear increase in surface temperature. In the second, laser power was periodically increased until autoheating (self-heating) was established. It was found that the alloy would autoheat to combustion from temperatures below the solidus temperature. In addition, the alloy had a tendency to develop combustion zones (hot spots) at high oxygen pressures when the incremental (step) heating test mode was used. Unique points on the temperature-time curves that describe certain events are defined and the temperatures at which these events occur are given for the oxygen pressure range of 1.72 to 13.8 MPa (250 to 2000 psia).

Process of afterburning combustible constituents of exhaust gases from rotary kilns

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schnabel, W.; Scheu, E.; Serbent, H.

1984-03-13

In order to avoid incrustation and an excessively strong thermal attack on the afterburning chamber, the exhaust gases which contain gaseous and solid constituents which are combustible are afterburned in a plurality of stages, which are connected in series. The rate at which oxygen is supplied to each stage is so controlled that part of the combustible constituents is afterburned in each stage. The gas which is about to enter each succeeding stage is cooled by injected water.

Two-Photon Antenna-Core Oxygen Probe with Enhanced Performance

PubMed Central

2015-01-01

Recent development of two-photon phosphorescence lifetime microscopy (2PLM) of oxygen enabled first noninvasive high-resolution measurements of tissue oxygenation in vivo in 3D, providing valuable physiological information. The so far developed two-photon-enhanced phosphorescent probes comprise antenna-core constructs, in which two-photon absorbing chromophores (antenna) capture and channel excitation energy to a phosphorescent core (metalloporphyrin) via intramolecular excitation energy transfer (EET). These probes allowed demonstration of the methods’ potential; however, they suffer from a number of limitations, such as partial loss of emissivity to competing triplet state deactivation pathways (e.g., electron transfer) and suboptimal sensitivity to oxygen, thereby limiting spatial and temporal resolution of the method. Here we present a new probe, PtTCHP-C307, designed to overcome these limitations. The key improvements include significant increase in the phosphorescence quantum yield, higher efficiency of the antenna-core energy transfer, minimized quenching of the phosphorescence by electron transfer and increased signal dynamic range. For the same excitation flux, the new probe is able to produce up to 6-fold higher signal output than previously reported molecules. Performance of PtTCHP-C307 was demonstrated in vivo in pO2 measurements through the intact mouse skull into the bone marrow, where all blood cells are made from hematopoietic stem cells. PMID:24848643

Methanol Droplet Extinction in Oxygen/Carbon-dioxide/Nitrogen Mixtures in Microgravity: Results from the International Space Station Experiments

NASA Technical Reports Server (NTRS)

Nayagam, Vedha; Dietrich, Daniel L.; Ferkul, Paul V.; Hicks, Michael C.; Williams, Forman A.

2012-01-01

Motivated by the need to understand the flammability limits of condensed-phase fuels in microgravity, isolated single droplet combustion experiments were carried out in the Combustion Integrated Rack Facility onboard the International Space Station. Experimental observations of methanol droplet combustion and extinction in oxygen/carbon-dioxide/nitrogen mixtures at 0.7 and 1 atmospheric pressure in quiescent microgravity environment are reported for initial droplet diameters varying between 2 mm to 4 mm in this study.The ambient oxygen concentration was systematically lowered from test to test so as to approach the limiting oxygen index (LOI) at fixed ambient pressure. At one atmosphere pressure, ignition and some burning were observed for an oxygen concentration of 13% with the rest being nitrogen. In addition, measured droplet burning rates, flame stand-off ratios, and extinction diameters are presented for varying concentrations of oxygen and diluents. Simplified theoretical models are presented to explain the observed variations in extinction diameter and flame stand-off ratios.

The influence of oxygen concentration on the combustion of a fuel/oxidizer mixture

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biteau, H.; Institut National de l'Environnement Industriel et des Risques, Parc Technologique Alata, Verneuil en Halatte; Fuentes, A.

2010-04-15

The aim of the present study is to investigate the influence of the O{sub 2} concentration on the combustion behaviour of a fuel/oxidizer mixture. The material tested is a ternary mixture of lactose, starch, and potassium nitrate, which has already been used in an attempt to estimate heat release rate using the FM-Global Fire Propagation Apparatus. It provides a well-controlled combustion chamber to study the evolution of the combustion products when varying the O{sub 2} concentration, between air and low oxidizer conditions. Different chemical behaviours have been exhibited. When the O{sub 2} concentration was reduced beyond 18%, large variations weremore » observed in the CO{sub 2} and CO concentrations. This critical O{sub 2} concentration seems to be the limit before which the material only uses its own oxidizer to react. On the other hand, mass loss did not highlight this change in chemical reactions and remained similar whatever the test conditions. This presumes that the oxidation of CO into CO{sub 2} are due to reactions occurring in the gas phase especially for large O{sub 2} concentrations. This actual behaviour can be verified using a simplified flammability limit model adapted for the current work. Finally, a sensitivity analysis has been carried out to underline the influence of CO concentration in the evaluation of heat release rate using typical calorimetric methods. The results of this study provide a critical basis for the investigation of the combustion of a fuel/oxidizer mixture and for the validation of future numerical models. (author)« less

Particulate Formation from a Copper Oxide-Based Oxygen ...

EPA Pesticide Factsheets

Attrition behavior and particle loss of a copper oxide-based oxygen carrier from a methane chemical looping combustion (CLC) process was investigated in a fluidized bed reactor. The aerodynamic diameters of most elutriated particulates, after passing through a horizontal settling duct, range between 2 and 5 μm. A notable number of submicron particulates are also identified. Oxygen carrier attrition was observed to lead to increased CuO loss resulting from the chemical looping reactions, i.e., Cu is enriched in small particles generated primarily from fragmentation in the size range of 10-75 μm. Cyclic reduction and oxidation reactions in CLC have been determined to weaken the oxygen carrier particles, resulting in increased particulate emission rates when compared to oxygen carriers without redox reactions. The generation rate for particulates < 10 μm was found to decrease with progressive cycles over as-prepared oxygen carrier particles and then reach a steady state. The surface of the oxygen carrier is also found to be coarsened due to a Kirkendall effect, which also explains the enrichment of Cu on particle surfaces and in small particles. As a result, it is important to collect and reprocess small particles generated from chemical looping processes to reduce oxygen carrier loss. The redox reactions associated with chemical looping combustion play an important role in particle attrition in the fluidized bed. Reaction-induced local stresses, due to the r

Enhancement of fine-scale mixing for fuel-rich plume combustion

NASA Astrophysics Data System (ADS)

Schadow, K. C.; Gutmark, E.; Parr, T. P.; Parr, D. M.; Wilson, K. J.; Ferrell, G. B.

1987-01-01

The effect of enhancing small-scale turbulent structures on the combustion intensity and flame stability was studied in nonreacting and reacting flows. Hot-wire anemometry was used to map the mean and turbulent flow fields of the nonreacting flows. Reacting flows were studied in a free flame and in a ducted gas-generator fuel-rich plume using Planar Laser Induced Fluorescence, a rake of thermocouples and high speed photography. A modified circular nozzle having several backward facing steps upstream of its exit was used to introduce numerous inflection points in the initial mean velocity profiles, thus producing multiple corresponding sources of small-scale turbulence generators. Cold flow tests showed turbulence increases of up to six times the initial turbulence level relative to a circular nozzle. The ensuing result was that the flame of this nozzle was more intense with a homogeneous heat release. The fuel-rich plume was stable even in supersonic speeds, and secondary ignition was obtained under conditions that prevented sustained afterburning using the circular nozzle.

Experimental evaluation of the ignition process of carbon monoxide and oxygen in a rocket engine

NASA Technical Reports Server (NTRS)

Linne, Diane L.

1996-01-01

Carbon monoxide and oxygen ignition boundaries were determined in a spark torch igniter as a function of propellant inlet temperatures. The oxygen temperature was varied from ambient to -258 F, and the carbon monoxide temperature was varied from ambient to -241 F. With the oxygen and carbon monoxide at -253 F and -219 F, respectively, they successfully ignited between mixture ratios of 2.42 and 3.10. Analysis of the results indicated that the lower ignition boundary was more sensitive to oxygen temperature than to carbon monoxide temperature. Another series of tests was performed in a small simulated rocket engine with oxygen at -197 F and carbon monoxide at -193 F. An oxygen/hydrogen flame was used to initiate combustion of the oxygen and carbon monoxide. Tests performed at the optimum operating mixture ratio of 0.55 obtained steady-state combustion in every test.

Fuel Droplet Burning During Droplet Combustion Experiment

NASA Technical Reports Server (NTRS)

2003-01-01

Fuel ignites and burns in the Droplet Combustion Experiment (DCE) on STS-94 on July 4 1997, MET:2/05:40 (approximate). The DCE was designed to investigate the fundamental combustion aspects of single, isolated droplets under different pressures and ambient oxygen concentrations for a range of droplet sizes varying between 2 and 5 mm. DCE used various fuels -- in drops ranging from 1 mm (0.04 inches) to 5 mm (0.2 inches) -- and mixtures of oxidizers and inert gases to learn more about the physics of combustion in the simplest burning configuration, a sphere. The experiment elapsed time is shown at the bottom of the composite image. The DCE principal investigator was Forman Williams, University of California, San Diego. The experiment was part of the space research investigations conducted during the Microgravity Science Laboratory-1R mission (STS-94, July 1-17 1997). Advanced combustion experiments will be a part of investigations plarned for the International Space Station. (1.4MB, 13-second MPEG, screen 320 x 240 pixels; downlinked video, higher quality not available)A still JPG composite of this movie is available at http://mix.msfc.nasa.gov/ABSTRACTS/MSFC-0300168.html.

Low-nitrogen oxides combustion of dried sludge using a pilot-scale cyclone combustor with recirculation.

PubMed

Shim, Sung Hoon; Jeong, Sang Hyun; Lee, Sang-Sup

2015-04-01

Recently, numerical and experimental studies have been conducted to develop a moderate or intense low-oxygen dilution (MILD) combustion technology for solid fuels. The study results demonstrated that intense recirculation inside the furnace by high-momentum air is a key parameter to achieve the MILD combustion of solid fuels. However, the high-velocity air requires a significant amount of electricity consumption. A cyclone-type MILD combustor was therefore designed and constructed in the authors' laboratory to improve the recirculation inside the combustor. The laboratory-scale tests yielded promising results for the MILD combustion of dried sewage sludge. To achieve pilot-scale MILD combustion of dried sludge in this study, the effects of geometric parameters such as the venturi tube configuration, the air injection location, and the air nozzle diameter were investigated. With the optimized geometric and operational conditions, the pilot-scale cyclone combustor demonstrated successful MILD combustion of dried sludge at a rate of 75 kg/hr with an excess air ratio of 1.05. A horizontal cyclone combustor with recirculation demonstrated moderate or intense low-oxygen dilution (MILD) combustion of dried sewage sludge at a rate of 75 kg/hr. Optimizing only geometric and operational conditions of the combustor reduced nitrogen oxide (NOx) emissions to less than 75 ppm. Because the operating cost of the MILD combustor is much lower than that of the selective catalytic reduction (SCR) applied to the conventional combustor, MILD combustion technology with the cyclone type furnace is an eligible option for reducing NOx emissions from the combustion of dried sewage sludge.

Metallized Gelled Propellants: Oxygen/RP-1/Aluminum Rocket Heat Transfer and Combustion Measurements

NASA Technical Reports Server (NTRS)

Palaszewski, Bryan; Zakany, James S.

1996-01-01

A series of rocket engine heat transfer experiments using metallized gelled liquid propellants was conducted. These experiments used a small 20- to 40-lb/f thrust engine composed of a modular injector, igniter, chamber and nozzle. The fuels used were traditional liquid RP-1 and gelled RP-1 with 0-, 5-, and 55-percentage by weight loadings of aluminum particles. Gaseous oxygen was used as the oxidizer. Three different injectors were used during the testing: one for the baseline O(2)/RP-1 tests and two for the gelled and metallized gelled fuel firings. Heat transfer measurements were made with a rocket engine calorimeter chamber and nozzle with a total of 31 cooling channels. Each chamber used a water flow to carry heat away from the chamber and the attached thermocouples and flow meters allowed heat flux estimates at each of the 31 stations. The rocket engine Cstar efficiency for the RP-1 fuel was in the 65-69 percent range, while the gelled 0 percent by weight RP-1 and the 5-percent by weight RP-1 exhibited a Cstar efficiency range of 60 to 62% and 65 to 67%, respectively. The 55-percent by weight RP-1 fuel delivered a 42-47% Cstar efficiency. Comparisons of the heat flux and temperature profiles of the RP-1 and the metallized gelled RP-1/A1 fuels show that the peak nozzle heat fluxes with the metallized gelled O2/RP-1/A1 propellants are substantially higher than the baseline O2/RP-1: up to double the flux for the 55 percent by weight RP-1/A1 over the RP-1 fuel. Analyses showed that the heat transfer to the wall was significantly different for the RP-1/A1 at 55-percent by weight versus the RP-1 fuel. Also, a gellant and an aluminum combustion delay was inferred in the 0 percent and 5-percent by weight RP-1/A1 cases from the decrease in heat flux in the first part of the chamber. A large decrease in heat flux in the last half of the chamber was caused by fuel deposition in the chamber and nozzle. The engine combustion occurred well downstream of the injector face

Enhanced singlet oxygen generation from PLGA loaded with verteporfin and gold nanoparticles

NASA Astrophysics Data System (ADS)

Deng, Wei; Kautzka, Zofia; Goldys, Ewa M.

2016-12-01

In this study, poly(lactic-co-glycolic acid) (PLGA) nanocomposites were developed by incorporating a photosensitizer, verteporfin and gold nanoparticles into this polymeric matrix and utilised for enhanced photoynamic therapy. Both enhanced fluorescence and singlet oxygen generation from verteporfin were observed in this new formulation under both 425nm LED and 405nm laser illumination. A maximum enhancement factor of 2.5 for fluorescence and 1.84 for 1O2 generation was obtained when the molar ratio of gold:VP was 5:1 and excited at 425 nm, compared with PLGA doped with verteporfin only. The experiment results could be explained by the local electric field enhancement of gold nanoparticles. Furthermore, in vitro cell-killing effect on human pancreatic cancer cells was also demonstrated by using this new formulation following light exposure, indicating the utility of these nanocomposites for enhanced photodynamic therapy.

Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream

DOEpatents

Kromer, Brian R.; Litwin, Michael M.; Kelly, Sean M.

2016-09-27

A method and system for generating electrical power in which a high pressure synthesis gas stream generated in a gasifier is partially oxidized in an oxygen transport membrane based reactor, expanded and thereafter, is combusted in an oxygen transport membrane based boiler. A low pressure synthesis gas slip stream is split off downstream of the expanders and used as the source of fuel in the oxygen transport membrane based partial oxidation reactors to allow the oxygen transport membrane to operate at low fuel pressures with high fuel utilization. The combustion within the boiler generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.

Core–Shell Au@Metal-Oxide Nanoparticle Electrocatalysts for Enhanced Oxygen Evolution

DOE PAGES

Strickler, Alaina L.; Escudero-Escribano, Marı́a; Jaramillo, Thomas F.

2017-09-25

Enhanced catalysis for electrochemical oxygen evolution is essential for the efficacy of many renewable energy technologies, including water electrolyzers and metal–air batteries. Recently, Au supports have been shown to enhance the activity of many 3d transition metal-oxide thin films for the oxygen evolution reaction (OER) in alkaline media. In this paper, we translate the beneficial impact of Au supports to high surface area, device-ready core–shell nanoparticles consisting of a Au-core and a metal-oxide shell (Au@M xO y where M = Ni, Co, Fe, and CoFe). Through a systematic evaluation, we establish trends in performance and illustrate the universal activity enhancementmore » when employing the Au-core in the 3d transition metal-oxide nanoparticles. Finally, the highest activity particles, Au@CoFeO x, demonstrate an overpotential of 328 ± 3 mV over a 2 h stability test at 10 mA cm –2, illustrating that strategically coupling Au support and mixed metal-oxide effects in a core–shell nanoparticle morphology is a promising avenue to achieve device-ready, high-performance OER catalysts.« less

Core–Shell Au@Metal-Oxide Nanoparticle Electrocatalysts for Enhanced Oxygen Evolution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strickler, Alaina L.; Escudero-Escribano, Marı́a; Jaramillo, Thomas F.

Enhanced catalysis for electrochemical oxygen evolution is essential for the efficacy of many renewable energy technologies, including water electrolyzers and metal–air batteries. Recently, Au supports have been shown to enhance the activity of many 3d transition metal-oxide thin films for the oxygen evolution reaction (OER) in alkaline media. In this paper, we translate the beneficial impact of Au supports to high surface area, device-ready core–shell nanoparticles consisting of a Au-core and a metal-oxide shell (Au@M xO y where M = Ni, Co, Fe, and CoFe). Through a systematic evaluation, we establish trends in performance and illustrate the universal activity enhancementmore » when employing the Au-core in the 3d transition metal-oxide nanoparticles. Finally, the highest activity particles, Au@CoFeO x, demonstrate an overpotential of 328 ± 3 mV over a 2 h stability test at 10 mA cm –2, illustrating that strategically coupling Au support and mixed metal-oxide effects in a core–shell nanoparticle morphology is a promising avenue to achieve device-ready, high-performance OER catalysts.« less

Fuel and oxygen addition for metal smelting or refining process

DOEpatents

Schlichting, M.R.

1994-11-22

A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

Cavity Coupled Aeroramp Injector Combustion Study

DTIC Science & Technology

2009-06-01

Fluorescence RC-18 Propulsion Research Cell 18 at Wright-Patterson Air Force Base Scramjet Supersonic Combustion Ramjet TDLAS Tunable Diode Laser...aerothrottle starting device. There were also mass flow meters on the vitiator oxygen and natural gas supplies. The ethylene fuel used in the DMSJ...PSI System 10 Hz Health Monitoring System ~0.75 Hz Sensors A/D Converters Buffer Database/Console 5 Hz 22 Figure 16: Nominal

Estimates of Optimal Operating Conditions for Hydrogen-Oxygen Cesium-Seeded Magnetohydrodynamic Power Generator

NASA Technical Reports Server (NTRS)

Smith, J. M.; Nichols, L. D.

1977-01-01

The value of percent seed, oxygen to fuel ratio, combustion pressure, Mach number, and magnetic field strength which maximize either the electrical conductivity or power density at the entrance of an MHD power generator was obtained. The working fluid is the combustion product of H2 and O2 seeded with CsOH. The ideal theoretical segmented Faraday generator along with an empirical form found from correlating the data of many experimenters working with generators of different sizes, electrode configurations, and working fluids, are investigated. The conductivity and power densities optimize at a seed fraction of 3.5 mole percent and an oxygen to hydrogen weight ratio of 7.5. The optimum values of combustion pressure and Mach number depend on the operating magnetic field strength.

Heat of Combustion of the Product Formed by the Reaction of Diborane with 1,3-Butadiene

NASA Technical Reports Server (NTRS)

Tannenbaum, Stanley; Allen, Harrison, Jr.

1953-01-01

The net heat of combustion of the product formed by the reaction of diborane with 1,3-butadiene was found to be 18,700+/-150 Btu per pound for the reaction of liquid fuel to gaseous carbon dioxide, gaseous water, and solid boric oxide. The measurements were made in a Parr oxygen-bomb calorimeter, and the combustion was believed to be 98 percent complete. The estimated net heat of combustion for complete combustion would therefore be 19,075+/-150 Btu per pound. Since this value is approximately the same as the heat of combustion of butadiene, it seems certain that the material is partially oxidized.

Oxygenation-Enhanced Radiation Therapy of Breast Tumors

DTIC Science & Technology

2011-11-01

development of stabilized perfluorocarbon emulsions as oxygen carriers, their characterization, and response to external triggers, including...elevated temperature, reduced pressure, and dwell time. Targeted oxygenation, perfluorocarbon emulsions, breast cancer 29 The University of Utah Salt...investigation of the proposed novel strategy of radio sensitization of hypoxic breast tumors by targeted oxygen release from perfluorocarbon oxygen

Pollutant formation in the pyrolysis and combustion of materials combining biomass and e-waste.

PubMed

Soler, Aurora; Conesa, Juan A; Iñiguez, María E; Ortuño, Nuria

2018-05-01

Combustion and pyrolysis runs at 850°C were carried out in a laboratory scale horizontal reactor with different materials combining biomass and waste electrical and electronic equipment (WEEE). Analyses are presented of the carbon oxides, light hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), polychlorinated benzenes (ClBzs), polychlorinated phenols (ClPhs), polybrominated phenols (BrPhs), polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Results showed that gas emissions were mainly composed of CO and CO 2 ; the high level of CO found in the pyrolytic runs was easily transformed into CO 2 by reaction with oxygen. The total amount of light hydrocarbons emitted was higher in the samples containing WEEE, methane being the most abundant light hydrocarbon in all the runs. However, the presence of WEEE reduced the emission of PAHs which decreased with the increase of the oxygen. The total amount of BrPhs increased in the decomposition of the samples containing WEEE, reaching its maximum in pyrolysis runs. Emission of PCDD/Fs was enhanced in pyrolytic conditions and easily decreased in the presence of oxygen. Copyright © 2017 Elsevier B.V. All rights reserved.

Amide and Ester-Functionalized Humic Acid for Fuel Combustion Enhancement

NASA Astrophysics Data System (ADS)

Riggs, Mark

. The modified humic acid samples were diluted with kerosene to identify the influence on combustion properties. Butyl-modified humic acid samples decreased the molar enthalpy of combustion. Hexyl, octyl, and decyl-modified humic acids improved the combustion values. Decyl amide-modified humic acid showed the largest improvement of these mixtures with a 0.9% increase from the expected molar enthalpy of combustion with a loading percentage of 0.36% in kerosene. Octyl amide-modified and octyl ester-modified humic acid mixtures were prepared in 0.05, 0.1, and 1% loading percentage dilutions to study the effect of modified humic acid loading percent on combustion properties. The 0.1% dilution showed the largest increase of the expected molar enthalpy of combustion by 1.14% and 0.4% for amide-modified HA and ester-modified HA, respectively.

Effect of oxygen on the ignition of liquid fuels

NASA Technical Reports Server (NTRS)

Pahl, H

1929-01-01

The ignition temperature, ignition lag, and ignition strength of simple and homogeneous fuels in combustion air of small oxygen content differ from what they are in air of greater oxygen content. In the case of small oxygen content, these fuels behave as if mixed unevenly. In the case of air with a definite oxygen content, the simple fuels have two ignition points, between which ignition takes place within a certain temperature range. The phenomena are explained by pyrogenous decomposition, comparison of the individual heat quantities, and the effect of the walls.

APPLICATION OF PULSE COMBUSTION TO SOLID AND HAZARDOUS WASTE INCINERATION

EPA Science Inventory

The paper discusses the application of pulse combustion to solid and hazardous waste incineration. otary kiln incinerator simulator was retrofitted with a frequency-tunable pulse combustor to enhance the efficiency of combustion. he pulse combustor excites pulsations in the kiln ...

Artist's concept of oxygen tanks of the Apollo 14 spacecraft

NASA Image and Video Library

1971-01-12

S71-16745 (January 1971) --- An artist's concept illustrating a cutaway view of one of the three oxygen tanks of the Apollo 14 spacecraft. This is the new Apollo oxygen tank design, developed since the Apollo 13 oxygen tank explosion. Apollo 14 has three oxygen tanks redesigned to eliminate ignition sources, minimize the use of combustible materials, and simplify the fabrication process. The third tank has been added to the Apollo 14 Service Module, located in the SM's sector one, apart from the pair of oxygen tanks in sector four. Arrows point out various features of the oxygen tank.

Dual-triggered oxygen self-supply black phosphorus nanosystem for enhanced photodynamic therapy.

PubMed

Liu, Jintong; Du, Ping; Mao, Hui; Zhang, Lei; Ju, Huangxian; Lei, Jianping

2018-07-01

Nonspecific distribution of photosensitizer and the intrinsic hypoxic condition in the tumor microenvironment are two key factors limiting the efficacy of O 2 -dependent photodynamic therapy (PDT). Herein, a dual-triggered oxygen self-supported nanosystem using black phosphorus nanosheet (BPNS) as both photosensitizer and nanocarrier was developed to enhance PDT for tumors within hypoxic microenvironment. The BPNS platform was functionalized with folate and a blocker DNA duplex of 5'-Cy5-aptamer-heme/3'-heme labeled oligonucleotides. The resulting heme dimer could passivate its peroxidase activity. After specific recognition of aptamer-target, the quenched fluorescence is "turned" on by cellular adenosine triphosphate. The passivated nanosystem then activates the catalytic function towards excessive intracellular H 2 O 2 to generate O 2 essential to sustain BPNS-mediated PDT, leading to 8.7-fold and 7.5-fold increase of PDT efficacy in treating the hypoxic cell and tumor, respectively. Therefore, the dual-triggered oxygen self-supply nanosystem not only exerts tumor microenvironment-associated stimulus for enhanced PDT but also surmounts hypoxia-associated therapy resistance. Copyright © 2018 Elsevier Ltd. All rights reserved.

HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chris Guenther; Bill Rogers

2001-09-15

The HPCCK project was initiated with a kickoff meeting held on June 12, 2001 in Morgantown, WV, which was attended by all project participants. SRI's existing g-RCFR reactor was reconfigured to a SRT-RCFR geometry (Task 1.1). This new design is suitable for performing the NBFZ experiments of Task 1.2. It was decided that the SRT-RCFR apparatus could be modified and used for the HPBO experiments. The purchase, assembly, and testing of required instrumentation and hardware is nearly complete (Task 1.1 and 1.2). Initial samples of PBR coal have been shipped from FWC to SRI (Task 1.1). The ECT device formore » coal flow measurements used at FWC will not be used in the SRI apparatus and a screw type feeder has been suggested instead (Task 5.1). NEA has completed a upgrade of an existing Fluent simulator for SRI's RCFR to a version that is suitable for interpreting results from tests in the NBFZ configuration (Task 1.3) this upgrade includes finite-rate submodels for devolatilization, secondary volatiles pyrolysis, volatiles combustion, and char oxidation. Plans for an enhanced version of CBK have been discussed and development of this enhanced version has begun (Task 2.5). A developmental framework for implementing pressure and oxygen effects on ash formation in an ash formation model (Task 3.3) has begun.« less

Additively Manufactured Metals in Oxygen Systems Project

NASA Technical Reports Server (NTRS)

Tylka, Jonathan

2015-01-01

Metals produced by additive manufacturing methods, such as Powder Bed Fusion Technology, are now mature enough to be considered for qualification in human spaceflight oxygen systems. The mechanical properties of metals produced through AM processes are being systematically studied. However, it is unknown whether AM metals in oxygen applications may present an increased risk of flammability or ignition as compared to wrought metals of the same metallurgical composition due to increased porosity. Per NASA-STD-6001B materials to be used in oxygen system applications shall be based on flammability and combustion test data, followed by a flammability assessment. Without systematic flammability and ignition testing in oxygen there is no credible method for NASA to accurately evaluate the risk of using AM metals in oxygen systems.

Combustion method for assay of biological materials labeled with carbon-14 or tritium, or double-labeled

NASA Technical Reports Server (NTRS)

Huebner, L. G.; Kisieleski, W. E.

1969-01-01

Dry catalytic combustion at high temperatures is used for assaying biological materials labeled carbon-14 and tritium, or double-labeled. A modified oxygen-flask technique is combined with standard vacuum-line techniques and includes convenience of direct in-vial collection of final combustion products, giving quantitative recovery of tritium and carbon-14.

Oxygen-hydrogen torch is a small-scale steam generator

NASA Technical Reports Server (NTRS)

Maskell, C. E.

1966-01-01

Standard oxygen-hydrogen torch generates steam for corrosion-rate analysis of various metals. The steam is generated through local combustion inside a test chamber under constant temperature and pressure control.

Ignition and combustion of lunar propellants

NASA Technical Reports Server (NTRS)

Burton, Rodney L.; Roberts, Ted A.; Krier, Herman

1993-01-01

The ignition and combustion of Al, Mg, and Al/Mg alloy particles in 99 percent O2/1 percent N2 mixtures is investigated at high temperatures and pressures for rocket engine applications. The 20 micron particles contain 0, 5, 10, 20, 40, 60, 80, and 100 weight percent Mg alloyed with Al, and are ignited in oxygen using the reflected shock in a shock tube near the endwall. Using this technique, the ignition delay and combustion times of the particles are measured at temperatures up to 3250 K as a function of Mg content for oxygen pressures of 8.5, 17, and 34 atm. An ignition model is developed which employs a simple lumped capacitance energy equation and temperature and pressure dependent particle and gas properties. Good agreement is achieved between the measured and predicted trends in the ignition delay times. For the particles investigated, the contribution of heterogeneous reaction to the heating of the particle is found to be significant at lower temperatures, but may be neglected as gas temperatures above 3000 K. As little as 10 percent Mg reduces the ignition delay time substantially at all pressures tested. The particle ignition delay times decrease with increasing Mg content, and this reduction becomes less pronounced as oxidizer temperature and pressure are increased.

Enhanced deep ocean ventilation and oxygenation with global warming

NASA Astrophysics Data System (ADS)

Froelicher, T. L.; Jaccard, S.; Dunne, J. P.; Paynter, D.; Gruber, N.

2014-12-01

Twenty-first century coupled climate model simulations, observations from the recent past, and theoretical arguments suggest a consistent trend towards warmer ocean temperatures and fresher polar surface oceans in response to increased radiative forcing resulting in increased upper ocean stratification and reduced ventilation and oxygenation of the deep ocean. Paleo-proxy records of the warming at the end of the last ice age, however, suggests a different outcome, namely a better ventilated and oxygenated deep ocean with global warming. Here we use a four thousand year global warming simulation from a comprehensive Earth System Model (GFDL ESM2M) to show that this conundrum is a consequence of different rates of warming and that the deep ocean is actually better ventilated and oxygenated in a future warmer equilibrated climate consistent with paleo-proxy records. The enhanced deep ocean ventilation in the Southern Ocean occurs in spite of increased positive surface buoyancy fluxes and a constancy of the Southern Hemisphere westerly winds - circumstances that would otherwise be expected to lead to a reduction in deep ocean ventilation. This ventilation recovery occurs through a global scale interaction of the Atlantic Meridional Overturning Circulation undergoing a multi-centennial recovery after an initial century of transient decrease and transports salinity-rich waters inform the subtropical surface ocean to the Southern Ocean interior on multi-century timescales. The subsequent upwelling of salinity-rich waters in the Southern Ocean strips away the freshwater cap that maintains vertical stability and increases open ocean convection and the formation of Antarctic Bottom Waters. As a result, the global ocean oxygen content and the nutrient supply from the deep ocean to the surface are higher in a warmer ocean. The implications for past and future changes in ocean heat and carbon storage will be discussed.

Improve Your Boiler's Combustion Efficiency: Office of Industrial Technologies (OIT) Steam Energy Tips No.4

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

2002-03-01

Operating your boiler with an optimum amount of excess air will minimize heat loss up the stack and improve combustion efficiency. Combustion efficiency is a measure of how effectively the heat content of a fuel is transferred into usable heat. The stack temperature and flue gas oxygen (or carbon dioxide) concentrations are primary indicators of combustion efficiency. Given complete mixing, a precise or stoichiometric amount of air is required to completely react with a given quantity of fuel. In practice, combustion conditions are never ideal, and additional or ''excess'' air must be supplied to completely burn the fuel. The correctmore » amount of excess air is determined from analyzing flue gas oxygen or carbon dioxide concentrations. Inadequate excess air results in unburned combustibles (fuel, soot, smoke, and carbon monoxide) while too much results in heat lost due to the increased flue gas flow--thus lowering the overall boiler fuel-to-steam efficiency. The table relates stack readings to boiler performance. On well-designed natural gas-fired systems, an excess air level of 10% is attainable. An often stated rule of thumb is that boiler efficiency can be increased by 1% for each 15% reduction in excess air or 40 F reduction in stack gas temperature.« less

Microwave-Assisted Ignition for Improved Internal Combustion Engine Efficiency

NASA Astrophysics Data System (ADS)

DeFilippo, Anthony Cesar

The ever-present need for reducing greenhouse gas emissions associated with transportation motivates this investigation of a novel ignition technology for internal combustion engine applications. Advanced engines can achieve higher efficiencies and reduced emissions by operating in regimes with diluted fuel-air mixtures and higher compression ratios, but the range of stable engine operation is constrained by combustion initiation and flame propagation when dilution levels are high. An advanced ignition technology that reliably extends the operating range of internal combustion engines will aid practical implementation of the next generation of high-efficiency engines. This dissertation contributes to next-generation ignition technology advancement by experimentally analyzing a prototype technology as well as developing a numerical model for the chemical processes governing microwave-assisted ignition. The microwave-assisted spark plug under development by Imagineering, Inc. of Japan has previously been shown to expand the stable operating range of gasoline-fueled engines through plasma-assisted combustion, but the factors limiting its operation were not well characterized. The present experimental study has two main goals. The first goal is to investigate the capability of the microwave-assisted spark plug towards expanding the stable operating range of wet-ethanol-fueled engines. The stability range is investigated by examining the coefficient of variation of indicated mean effective pressure as a metric for instability, and indicated specific ethanol consumption as a metric for efficiency. The second goal is to examine the factors affecting the extent to which microwaves enhance ignition processes. The factors impacting microwave enhancement of ignition processes are individually examined, using flame development behavior as a key metric in determining microwave effectiveness. Further development of practical combustion applications implementing microwave

Liquid Methane/Oxygen Injector Study for Mars Ascent Engines

NASA Technical Reports Server (NTRS)

Trinh, Huu Phuoc

1999-01-01

As a part of the advancing technology of the cryogenic propulsion system for the Mars exploration mission, this effort aims at evaluating propellant injection concepts for liquid methane/liquid oxygen (LOX) rocket engines. Split-triplet and unlike impinging injectors were selected for this study. A total of four injector configurations were tested under combustion conditions in a modular combustor test article (MCTA), equipped with optically accessible windows, at MSFC. A series of forty hot-fire tests, which covered a wide range of engine operating conditions with the chamber pressure ranging from 320 to 510 and the mixture ratio from 1.5 to 3.5, were conducted. The test matrix also included a variation in the combustion chamber length for the purpose of investigating its effects on the combustion performance and stability. Initial assessments of the test results showed that the injectors provided stable combustion and there were no injector face overheating problems under all operating conditions. The Raman scattering signal measurement method was successfully demonstrated for the hydrocarbon/oxygen reactive flow field. The near-injector face flow field was visually observed through the use of an infrared camera. Chamber wall temperature, high frequency chamber pressure, and average throat section heat flux were also recorded throughout the test series. Assessments of the injector performance are underway.

Enhanced Lithium Oxygen Battery Using a Glyme Electrolyte and Carbon Nanotubes.

PubMed

Carbone, Lorenzo; Moro, Paolo Tomislav; Gobet, Mallory; Munoz, Stephen; Devany, Matthew; Greenbaum, Steven G; Hassoun, Jusef

2018-05-16

The lithium oxygen battery has a theoretical energy density potentially meeting the challenging requirements of electric vehicles. However, safety concerns and short lifespan hinder its application in practical systems. In this work, we show a cell configuration, including a multiwalled carbon nanotube electrode and a low flammability glyme electrolyte, capable of hundreds of cycles without signs of decay. Nuclear magnetic resonance and electrochemical tests confirm the suitability of the electrolyte in a practical battery, whereas morphological and structural aspects revealed by electron microscopy and X-ray diffraction demonstrate the reversible formation and dissolution of lithium peroxide during the electrochemical process. The enhanced cycle life of the cell and the high safety of the electrolyte suggest the lithium oxygen battery herein reported as a viable system for the next generation of high-energy applications.

Effect of Electric Field in the Stabilized Premixed Flame on Combustion Process Emissions

NASA Astrophysics Data System (ADS)

Otto, Krickis

2017-10-01

The effect of the AC and DC electrical field on combustion processes has been investigated by various researchers. The results of these experiments do not always correlate, due to different experiment conditions and experiment equipment variations. The observed effects of the electrical field impact on the combustion process depends on the applied voltage polarity, flame speed and combustion physics. During the experiment was defined that starting from 1000 V the ionic wind takes the effect on emissions in flue gases, flame shape and combustion instabilities. Simulation combustion process in hermetically sealed chamber with excess oxygen amount 3 % in flue gases showed that the positive effect of electrical field on emissions lies in region from 30 to 400 V. In aforementioned voltage range carbon monoxide emissions were reduced by 6 % and at the same time the nitrogen oxide emissions were increased by 3.5 %.

Polycyclic Aromatic Hydrocarbons (PAHs) produced in the combustion of fatty acid alkyl esters from different feedstocks: Quantification, statistical analysis and mechanisms of formation.

PubMed

Llamas, Alberto; Al-Lal, Ana-María; García-Martínez, María-Jesús; Ortega, Marcelo F; Llamas, Juan F; Lapuerta, Magín; Canoira, Laureano

2017-05-15

Polycyclic Aromatic Hydrocarbons (PAHs) are pollutants of concern due to their carcinogenic and mutagenic activity. Their emissions are mainly related with the combustion or pyrolysis of the organic matter, such as in fossil fuels combustion. It is important to characterize PAHs in the combustions of biofuels due to their increasing importance in the actual energetic setting. There is a lot of research focused in PAHs emission due to the combustion in diesel engines; but only few of them have analyzed the effect of raw material and type of alcohol used in the transesterification process. Different raw materials (i.e. animal fat, palm, rapeseed, linseed, peanut, coconut, and soybean oils) have been used for obtaining FAME and FAEE. A method for measuring PAHs generated during combustion in a bomb calorimeter has been developed. Combustion was made at different oxygen pressures and the samples were taken from the bomb after each combustion. Samples were extracted and the PAHs amounts formed during combustion were analyzed by GC-MS. This research shows the statistical relationships among the 16 PAHs of concern, biodiesel composition and oxygen pressure during combustion. Copyright © 2017 Elsevier B.V. All rights reserved.

Fuel and oxygen addition for metal smelting or refining process

DOEpatents

Schlichting, Mark R.

1994-01-01

A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

How oxygen reacts with oxygen-tolerant respiratory [NiFe]-hydrogenases.

PubMed

Wulff, Philip; Day, Christopher C; Sargent, Frank; Armstrong, Fraser A

2014-05-06

An oxygen-tolerant respiratory [NiFe]-hydrogenase is proven to be a four-electron hydrogen/oxygen oxidoreductase, catalyzing the reaction 2 H2 + O2 = 2 H2O, equivalent to hydrogen combustion, over a sustained period without inactivating. At least 86% of the H2O produced by Escherichia coli hydrogenase-1 exposed to a mixture of 90% H2 and 10% O2 is accounted for by a direct four-electron pathway, whereas up to 14% arises from slower side reactions proceeding via superoxide and hydrogen peroxide. The direct pathway is assigned to O2 reduction at the [NiFe] active site, whereas the side reactions are an unavoidable consequence of the presence of low-potential relay centers that release electrons derived from H2 oxidation. The oxidase activity is too slow to be useful in removing O2 from the bacterial periplasm; instead, the four-electron reduction of molecular oxygen to harmless water ensures that the active site survives to catalyze sustained hydrogen oxidation.

Lance for fuel and oxygen injection into smelting or refining furnace

DOEpatents

Schlichting, M.R.

1994-12-20

A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figures.

Oxygenated drinking water enhances immune activity in pigs and increases immune responses of pigs during Salmonella typhimurium infection.

PubMed

Jung, Bock-Gie; Lee, Jin-A; Lee, Bong-Joo

2012-12-01

It has been considered that drinking oxygenated water improves oxygen availability, which may increase vitality and improve immune functions. The present study evaluated the effects of oxygenated drinking water on immune function in pigs. Continuous drinking of oxygenated water markedly increased peripheral blood mononuclear cell proliferation, interleukin-1β expression level and the CD4(+):CD8(+) cell ratio in pigs. During Salmonella Typhimurium infection, total leukocytes and relative cytokines expression levels were significantly increased in pigs consuming oxygenated water compared with pigs consuming tap water. These findings suggest that oxygenated drinking water enhances immune activity in pigs and increases immune responses of pigs during S. Typhimurium Infection.

Combustion Stability Characteristics of the Project Morpheus Liquid Oxygen / Liquid Methane Main Engine

NASA Technical Reports Server (NTRS)

Melcher, John C.; Morehead, Robert L.

2014-01-01

The project Morpheus liquid oxygen (LOX) / liquid methane (LCH4) main engine is a Johnson Space Center (JSC) designed 5,000 lbf-thrust, 4:1 throttling, pressure-fed cryogenic engine using an impinging element injector design. The engine met or exceeded all performance requirements without experiencing any in- ight failures, but the engine exhibited acoustic-coupled combustion instabilities during sea-level ground-based testing. First tangential (1T), rst radial (1R), 1T1R, and higher order modes were triggered by conditions during the Morpheus vehicle derived low chamber pressure startup sequence. The instability was never observed to initiate during mainstage, even at low power levels. Ground-interaction acoustics aggravated the instability in vehicle tests. Analysis of more than 200 hot re tests on the Morpheus vehicle and Stennis Space Center (SSC) test stand showed a relationship between ignition stability and injector/chamber pressure. The instability had the distinct characteristic of initiating at high relative injection pressure drop at low chamber pressure during the start sequence. Data analysis suggests that the two-phase density during engine start results in a high injection velocity, possibly triggering the instabilities predicted by the Hewitt stability curves. Engine ignition instability was successfully mitigated via a higher-chamber pressure start sequence (e.g., 50% power level vs 30%) and operational propellant start temperature limits that maintained \\cold LOX" and \\warm methane" at the engine inlet. The main engine successfully demonstrated 4:1 throttling without chugging during mainstage, but chug instabilities were observed during some engine shutdown sequences at low injector pressure drop, especially during vehicle landing.

Combustion Stability Characteristics of the Project Morpheus Liquid Oxygen/Liquid Methane Main Engine

NASA Technical Reports Server (NTRS)

Melcher, J. C.; Morehead, Robert L.

2014-01-01

The Project Morpheus liquid oxygen (LOX) / liquid methane rocket engines demonstrated acousticcoupled combustion instabilities during sea-level ground-based testing at the NASA Johnson Space Center (JSC) and Stennis Space Center (SSC). High-amplitude, 1T, 1R, 1T1R (and higher order) modes appear to be triggered by injector conditions. The instability occurred during the Morpheus-specific engine ignition/start sequence, and did demonstrate the capability to propagate into mainstage. However, the instability was never observed to initiate during mainstage, even at low power levels. The Morpheus main engine is a JSC-designed 5,000 lbf-thrust, 4:1 throttling, pressure-fed cryogenic engine using an impinging element injector design. Two different engine designs, named HD4 and HD5, and two different builds of the HD4 engine all demonstrated similar instability characteristics. Through the analysis of more than 200 hot fire tests on the Morpheus vehicle and SSC test stand, a relationship between ignition stability and injector/chamber pressure was developed. The instability has the distinct characteristic of initiating at high relative injection pressure drop (dP) at low chamber pressure (Pc); i.e., instabilities initiated at high dP/Pc at low Pc during the start sequence. The high dP/Pc during start results during the injector /chamber chill-in, and is enhanced by hydraulic flip in the injector orifice elements. Because of the fixed mixture ratio of the existing engine design (the main valves share a common actuator), it is not currently possible to determine if LOX or methane injector dP/Pc were individual contributors (i.e., LOX and methane dP/Pc typically trend in the same direction within a given test). The instability demonstrated initiation characteristic of starting at or shortly after methane injector chillin. Colder methane (e.g., sub-cooled) at the injector inlet prior to engine start was much more likely to result in an instability. A secondary effect of LOX

Testing metals and alloys for use in oxygen systems

NASA Technical Reports Server (NTRS)

Stoltzfus, Joel M.

1986-01-01

When oxygen is present in high concentrations or large quantities, as in oxygen-based life-support systems, the likelihood of combustion and the probable intensity of a conflagration increase, together with the severity of the damage caused. Even stainless steel will burn vigorously when ignited in a 1000-psi oxygen environment. The hazards involved in the use of oxygen increase with system operation at the elevated temperatures typical of propulsion systems. Fires in oxygen systems are generally catastrophic, causing a threat to life in manned vehicles. When mechanical components of a mechanism generate friction heat in the presence of oxygen, many commonly used metal alloys ignite and burn. Attention is presently given to frictional heating, particle impact, and flame propagation tests conducted in oxygen environments.

Spin glass formation in La0.9Sr0.1CoO3 catalyst for flameless combustion of methane.

PubMed

Oliva, C; Forni, L; Vishniakov, A V

2000-02-01

Two samples of composition La0.9M0.1CoO3 (M = Sr, Ce) have been compared as catalysts for the flameless combustion of methane. The former showed a lower activity than the latter and this difference was enhanced at lower temperature. Aiming at understanding the origin of this behaviour, EPR analysis was carried out at temperatures down to 100 K. At T < 245 K a zero-field intense feature appeared with the M = Sr sample only, characterized by opposite phase with respect to the g approximately 2 line. This zero-field line was attributed to microwave absorption by spin glass formed by cobalt- and oxygen-based paramagnetic ions. The tendency to strong interaction among these species could also be a reason of the low oxygen availability for the catalytic methane oxidation at higher temperature.

Guide for Oxygen Component Qualification Tests

NASA Technical Reports Server (NTRS)

Bamford, Larry J.; Rucker, Michelle A.; Dobbin, Douglas

1996-01-01

Although oxygen is a chemically stable element, it is not shock sensitive, will not decompose, and is not flammable. Oxygen use therefore carries a risk that should never be overlooked, because oxygen is a strong oxidizer that vigorously supports combustion. Safety is of primary concern in oxygen service. To promote safety in oxygen systems, the flammability of materials used in them should be analyzed. At the NASA White Sands Test Facility (WSTF), we have performed configurational tests of components specifically engineered for oxygen service. These tests follow a detailed WSTF oxygen hazards analysis. The stated objective of the tests was to provide performance test data for customer use as part of a qualification plan for a particular component in a particular configuration, and under worst-case conditions. In this document - the 'Guide for Oxygen Component Qualification Tests' - we outline recommended test systems, and cleaning, handling, and test procedures that address worst-case conditions. It should be noted that test results apply specifically to: manual valves, remotely operated valves, check valves, relief valves, filters, regulators, flexible hoses, and intensifiers. Component systems are not covered.

Pilot Plant Makes Oxygen Difluoride

NASA Technical Reports Server (NTRS)

Humphrey, Marshall F.; Lawton, Emil A.

1989-01-01

Pilot plant makes oxygen difluoride highly-energetic, space-storable oxidizer not made commercially. Designed to handle reactants, product, and byproduct, most of which highly reactive, corrosive, and toxic. Oxygen difluoride evolves continuously from reactor containing potassium hydroxide in water at 10 degree C. Collection tanks alternated; one filled while other drained to storage cylinder. Excess OF2 and F2 dissipated in combustion of charcoal in burn barrel. Toxic byproduct, potassium fluoride, reacted with calcium hydroxide to form nontoxic calcium fluoride and to regenerate potassium hydroxide. Equipment processes toxic, difficult-to-make substance efficiently and safely.

Generation of reactive oxygen species and charge carriers in plasmonic photocatalytic Au@TiO2 nanostructures with enhanced activity.

PubMed

He, Weiwei; Cai, Junhui; Jiang, Xiumei; Yin, Jun-Jie; Meng, Qingbo

2018-06-13

The combination of semiconductor and plasmonic nanostructures, endowed with high efficiency light harvesting and surface plasmon confinement, has been a promising way for efficient utilization of solar energy. Although the surface plasmon resonance (SPR) assisted photocatalysis has been extensively studied, the photochemical mechanism, e.g. the effect of SPR on the generation of reactive oxygen species and charge carriers, is not well understood. In this study, we take Au@TiO2 nanostructures as a plasmonic photocatalyst to address this critical issue. The Au@TiO2 core/shell nanostructures with tunable SPR property were synthesized by the templating method with post annealing thermal treatment. It was found that Au@TiO2 nanostructures exhibit enhanced photocatalytic activity in either sunlight or visible light (λ > 420 nm). Electron spin resonance spectroscopy with spin trapping and spin labeling was used to investigate the enhancing effect of Au@TiO2 on the photo-induced reactive oxygen species and charge carriers. The formation of Au@TiO2 core/shell nanostructures resulted in a dramatic increase in light-induced generation of hydroxyl radicals, singlet oxygen, holes and electrons, as compared with TiO2 alone. This enhancement under visible light (λ > 420 nm) irradiation may be dominated by SPR induced local electrical field enhancement, while the enhancement under sunlight irradiation is dominated by the higher electron transfer from TiO2 to Au. These results unveiled that the superior photocatalytic activity of Au@TiO2 nanostructures correlates with enhanced generation of reactive oxygen species and charge carriers.

Multicolor tunability and upconversion enhancement of fluoride nanoparticles by oxygen dopant

NASA Astrophysics Data System (ADS)

Niu, Wenbin; Wu, Suli; Zhang, Shufen; Su, Liap Tat; Tok, Alfred Iing Yoong

2013-08-01

The ability to manipulate the upconversion luminescence of lanthanide-ion doped fluoride upconversion nanoparticles (UCNPs) is particularly important and highly desired due to their wide applications in color displays, multiplexing bioassays and multicolor imaging. Here, we developed a strategy for simultaneously tuning color output and enhancing upconversion emission of Yb/Er doped fluoride UCNPs, based on adjusting the oxygen doping level. The synthesis of multicolored multifunctional NaGdF4:Yb,Er UCNPs was used as the model host system to demonstrate this protocol. Ammonium nitrate (NH4NO3) was used as the oxygen source and added into the reaction system at the beginning stage of nucleation and growth process of fluoride UCNPs, which facilitates the formation of enough oxygen atoms and the diffusion of these into the fluoride host matrix. The results revealed that multicolour output and upconversion enhancement mainly resulted from the variation of phonon energy and crystal field symmetry of the host lattice, respectively. This strategy can be further expanded to other fluoride host matrices. As an example of an application, multicolored UCNPs were used as a color converter in light emitting diodes, which can effectively convert near-infrared light into visible light. It is expected that these multicolored UCNPs will be promising for applications in multiplexing biodetection, bioimaging (optical and magnetic resonance imaging) and other optical technologies, and the present method for the control of O2- doping may also be used in other functional nanomaterials.The ability to manipulate the upconversion luminescence of lanthanide-ion doped fluoride upconversion nanoparticles (UCNPs) is particularly important and highly desired due to their wide applications in color displays, multiplexing bioassays and multicolor imaging. Here, we developed a strategy for simultaneously tuning color output and enhancing upconversion emission of Yb/Er doped fluoride UCNPs, based

Chemical Looping Combustion Reactions and Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sarofim, Adel; Lighty, JoAnn; Smith, Philip

2014-03-01

Chemical Looping Combustion (CLC) is one promising fuel-combustion technology, which can facilitate economic CO{sub 2} capture in coal-fired power plants. It employs the oxidation/reduction characteristics of a metal, or oxygen carrier, and its oxide, the oxidizing gas (typically air) and the fuel source may be kept separate. This topical report discusses the results of four complementary efforts: (5.1) the development of process and economic models to optimize important design considerations, such as oxygen carrier circulation rate, temperature, residence time; (5.2) the development of high-performance simulation capabilities for fluidized beds and the collection, parameter identification, and preliminary verification/uncertainty quantification; (5.3) themore » exploration of operating characteristics in the laboratoryscale bubbling bed reactor, with a focus on the oxygen carrier performance, including reactivity, oxygen carrying capacity, attrition resistance, resistance to deactivation, cost and availability; and (5.4) the identification of kinetic data for copper-based oxygen carriers as well as the development and analysis of supported copper oxygen carrier material. Subtask 5.1 focused on the development of kinetic expressions for the Chemical Looping with Oxygen Uncoupling (CLOU) process and validating them with reported literature data. The kinetic expressions were incorporated into a process model for determination of reactor size and oxygen carrier circulation for the CLOU process using ASPEN PLUS. An ASPEN PLUS process model was also developed using literature data for the CLC process employing an iron-based oxygen carrier, and the results of the process model have been utilized to perform a relative economic comparison. In Subtask 5.2, the investigators studied the trade-off between modeling approaches and available simulations tools. They quantified uncertainty in the high-performance computing (HPC) simulation tools for CLC bed applications

Combustion Products Monitor: Trade Study Testing

NASA Technical Reports Server (NTRS)

Wallace, William T.; Trowbridge, John B.

2011-01-01

Current combustion products monitoring on the International Space Station (ISS) uses a handheld device (Compound Specific Analyzer-Combustion Products, CSA-CP) containing electrochemical sensors used to measure the concentration of carbon monoxide (CO), hydrogen chloride (HCl), hydrogen cyanide (HCN), and oxygen (O2). The CO sensor in this device accounts for a well-known cross-sensitivity with hydrogen (H2), which is important, as ISS air can contain up to 100 ppm H2. Unfortunately, this current device is being discontinued, and due to space constraints, the new model cannot accommodate the size of the current CO sensor. Therefore, a trade study was conducted in order to determine which CO sensors on the market were available with compensation for H2, and which instruments used these sensors, while also measuring HCN, O2, and carbon dioxide (CO2). The addition of CO2 to the device is helpful, as current monitoring of this gas requires a second hand-held monitor. By providing a device that will monitor both combustion products and CO2, volume and up-mass can be reduced as these monitors are delivered to ISS.

­­Secondary organic aerosol formation from photo-oxidation of wood combustion emissions: Characterization of gas phase precursors and their link to SOA budget

NASA Astrophysics Data System (ADS)

Bhattu, D.; Stefenelli, G.; Zotter, P.; Zhou, J.; Nussbaumer, T.; Bertrand, A.; Marchand, N.; Termine-Roussel, B.; Baltensperger, U.; Slowik, J.; Prevot, A. S.; El-Haddad, I.; Dommen, J.

2016-12-01

Current legislation limits the emission of particulate matter, but does not regulate the precursors potentially forming secondary organic aerosol (SOA). Recent literature has shown that only 22 non-traditional SOA precursors from residential wood combustion explains 84-116% of the observed SOA mass whereas traditional precursors in the models account for only 3-27% of the SOA mass (Bruns et al., 2016). Investigation of gas phase emissions from wood combustion and their SOA formation potential have largely focused on single combustion devices with limited operating conditions. As, both primary emissions and SOA formation is a strong function of device type, load, fuel and operating conditions, we have performed a detailed chamber study investigating the gas-phase precursors from beech wood using three combustion devices namely a pellet boiler (combustion conditions: optimum, lack and excess of oxygen), an industrial wood chip grate boiler (30% and 100% power), and a log wood stove (varying fuel load and moisture content) using a potential aerosol mass reactor (PAM) with varying OH exposure. The short residence time in the reactor allowed a time resolved picture of SOA production potential and reduced wall losses. The main aim of this study is to characterize the primary and aged gaseous emissions and investigate their SOA formation potential depending on their mass yield, molecular structures, functional groups and OH reactivity in order to ascertain the contribution of residential wood burning in total carbonaceous OA budget. The physical and chemical effects of different OA aging conditions were monitored using an SMPS, an Aethalometer, an HR-ToF-AMS, as well as a PTR-ToF-MS and other gas monitors. In pellet boiler, significant SOA mass enhancement is observed in excess oxygen conditions compared to optimum and oxygen deprived conditions. Highest gas phase emissions from wood stove are observed at cold start (start of each burn cycle) and lowest in burn out phase

Hot-Fire Test Results of Liquid Oxygen/RP-2 Multi-Element Oxidizer-Rich Preburners

NASA Technical Reports Server (NTRS)

Protz, C. S.; Garcia, C. P.; Casiano, M. J.; Parton, J. A.; Hulka, J. R.

2016-01-01

As part of the Combustion Stability Tool Development project funded by the Air Force Space and Missile Systems Center, the NASA Marshall Space Flight Center was contracted to assemble and hot-fire test a multi-element integrated test article demonstrating combustion characteristics of an oxygen/hydrocarbon propellant oxidizer-rich staged-combustion engine thrust chamber. Such a test article simulates flow through the main injectors of oxygen/kerosene oxidizer-rich staged combustion engines such as the Russian RD-180 or NK-33 engines, or future U.S.-built engine systems such as the Aerojet-Rocketdyne AR-1 engine or the Hydrocarbon Boost program demonstration engine. To supply the oxidizer-rich combustion products to the main injector of the integrated test article, existing subscale preburner injectors from a previous NASA-funded oxidizer-rich staged combustion engine development program were utilized. For the integrated test article, existing and newly designed and fabricated inter-connecting hot gas duct hardware were used to supply the oxidizer-rich combustion products to the oxidizer circuit of the main injector of the thrust chamber. However, before one of the preburners was used in the integrated test article, it was first hot-fire tested at length to prove it could provide the hot exhaust gas mean temperature, thermal uniformity and combustion stability necessary to perform in the integrated test article experiment. This paper presents results from hot-fire testing of several preburner injectors in a representative combustion chamber with a sonic throat. Hydraulic, combustion performance, exhaust gas thermal uniformity, and combustion stability data are presented. Results from combustion stability modeling of these test results are described in a companion paper at this JANNAF conference, while hot-fire test results of the preburner injector in the integrated test article are described in another companion paper.

Heat of combustion of various southern pine materials

Treesearch

Elaine T. Howard

1972-01-01

As measured with an oxygen-bomb calorimeter, heats of combustion averaged about 8,600 Btu/ovendry lb. for stemwood, rootwood, and earlywood, and latewood. In stemwood, 54 percent of the variation was related to extractive content. Values for bark were greatest in samples from the base of the tree and decreased with increasing height in tree. Values for resinous wood...

Heat of combustion of various southern pine materials

Treesearch

E.T. Howard

1973-01-01

As measured with an oxygen-bomb calorimeter, heats of combustion averaged about 8,600 Btu/ovendry lb. for stemwood, rootwood, earlywood, and latewood. In stemwood, 54 percent of the variation was related to extractive content. Values for bark were greatest in samples from the base of the tree and decreased with increasing height in tree. Values for resinous wood varied...

Catalyzing the Combustion of Coal

NASA Technical Reports Server (NTRS)

Humphrey, M. F.; Dokko, W.

1982-01-01

Reaction rate of coal in air can be increased by contacting or coating coal with compound such as calcium acetate. The enhanced reaction rate generates more heat, reducing furnace size. Increase in combustion rate is about 26 percent, and internal pollutants in powerplant are reduced.

Effects of combustion temperature on PCDD/Fs formation in laboratory-scale fluidized-bed incineration.

PubMed

Hatanaka, T; Imagawa, T; Kitajima, A; Takeuchi, M

2001-12-15

Combustion experiments in a laboratory-scale fluidized-bed reactor were performed to elucidate the effects of combustion temperature on PCDD/Fs formation during incineration of model wastes with poly(vinyl chloride) or sodium chloride as a chlorine source and copper chloride as a catalyst. Each temperature of primary and secondary combustion zones in the reactor was set independently to 700, 800, and 900 degrees C using external electric heaters. The PCDD/Fs concentration is reduced as the temperature of the secondary combustion zone increases. It is effective to keep the temperature of the secondary combustion zone high enough to reduce their release during the waste incineration. On the other hand, as the temperature of the primary combustion zone rises, the PCDD/Fs concentration also increases. Lower temperature of the primary combustion zone results in less PCDD/Fs concentration in these experimental conditions. This result is probably related to the devolatilization rate of the solid waste in the primary combustion zone. The temperature decrease slows the devolatilization rate and promotes mixing of oxygen and volatile matters from the solid waste. This contributes to completing combustion reactions, resulting in reducing the PCDD/Fs concentration.

Ignition and Combustion of Bulk Metals in a Microgravity Environment

NASA Technical Reports Server (NTRS)

Branch, Melvyn C.; Daily, John W.; Abbud-Madrid, Angel

1999-01-01

Results of a study of heterogeneous and homogeneous combustion of metals in reduced gravity are presented. Cylindrical titanium and magnesium samples are radiatively ignited in pure-oxygen at 1 atm. Qualitative observations, propagation rates, and burning times are extracted from high-speed cinematography. Time-resolved emission spectra of gas-phase reactions are acquired with an imaging spectrograph. Lower propagation rates of the reacting mass on titanium and of ignition waves on magnesium are obtained at reduced gravity. These rates are compared to theoretical results from fire-spread analyses with a diffusion/convection controlled reaction. The close agreement found between experimental and theoretical propagation rates indicates the strong influence of natural-convection-enhanced oxygen transp6rt on burning rates. Lower oxygen flux and lack of condensed product removal appear to be responsible for longer burning times of magnesium gas-phase diffusion flames in reduced gravity. Spherically symmetric explosions in magnesium flames at reduced gravity (termed radiation-induced metal explosions, or RIME) may be driven by increased radiation heat transfer from accumulated condensed products to an evaporating metal core covered by a porous, flexible oxide coating. In titanium specimens, predominantly heterogeneous burning characterizes the initial steady propagation of the molten mass, while homogeneous gas-phase reactions are detected around particles ejected from the molten mixture. In magnesium specimens, band and line reversal of all the UV spectral systems of Mg and MgO are attributed to the interaction between small oxide particles and the principal gaseous emitters.

Influence of the microwave irradiation dewatering on the combustion characteristics of Chinese brown coals

NASA Astrophysics Data System (ADS)

Ge, Lichao; Feng, Hongcui; Xu, Chang; Zhang, Yanwei; Wang, Zhihua

2018-02-01

This study investigates the influence of microwave irradiation on coal composition, pore structure, coal rank, and combustion characteristics of typical brown coals in China. Results show that the upgrading process significantly decreased the inherent moisture, and increased calorific value and fixed carbon content. After upgrading, pore distribution extended to micropore region, oxygen functional groups were reduced and destroyed, and the apparent aromaticity increased suggesting an improvement in the coal rank. Based on thermogravimetric analysis, the combustion processes of upgraded coals were delayed toward the high temperature region, and the temperatures of ignition, peak and burnout increased. Based on the average combustion rate and comprehensive combustion parameter, the upgraded coals performed better compared with raw brown coals and a high rank coal. In ignition and burnout segments, the activation energy increased but exhibited a decrease in the combustion stage.

Combustion synthesized TiO{sub 2} for enhanced photocatalytic activity under the direct sunlight-optimization of titanylnitrate synthesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daya Mani, A.; Laporte, V.; Ghosal, P.

2012-09-15

Graphical abstract: Effect of oxidant on the combustion synthesis of TiO{sub 2} has been studied by preparing titanylnitrate in four different ways from Ti(IV) iso-propoxide. It is observed that oxidant preparation method has a significant effect on physico-chemical as well as photocatalytic properties of TiO{sub 2}. All the catalysts showed excellent photocatalytic activity than Degussa P-25 under direct sunlight for the degradation of a textile dye (methylene blue), without the need of external light sources, oxygen supply and reactor systems. Highlights: ► Optimized synthesis of titanylnitrate. ► Influence of titanylnitrate synthesis on the physico-chemical properties of TiO{sub 2} prepared bymore » combustion synthesis. ► Development of highly efficient TiO{sub 2} photocatalysts those are active under the direct sunlight in open atmosphere. ► Degradation of the textile dye (methylene blue) under direct sunlight. -- Abstract: Optimized synthesis of Ti-precursor ‘titanylnitrate’ for one step combustion synthesis of N- and C-doped TiO{sub 2} catalysts were reported and characterized by using powder X-ray diffraction (XRD), transmission electron microscopy (TEM), diffused reflectance UV–vis spectroscopy, N{sub 2} adsorption and X-ray photoelectron spectroscopy (XPS). XRD confirmed the formation of TiO{sub 2} anatase and nano-crystallite size which was further confirmed by TEM. UV-DRS confirmed the decrease in the band gap to less than 3.0 eV, which was assigned due to the presence of C and N in the framework of TiO{sub 2} as confirmed by X-ray photoelectron spectroscopy. Degradation of methylene blue in aqueous solution under the direct sunlight was carried out and typical results indicated the better performance of the synthesized catalysts than Degussa P-25.« less

From orbital debris capture systems through internal combustion engines on Mars

NASA Technical Reports Server (NTRS)

1991-01-01

The investigation and conceptualization of an orbital debris collector was the primary area of design. In addition, an alternate structural design for Space Station Freedom and systems supporting resource utilization at Mars and the moon were studied. Hardware for production of oxygen from simulate Mars atmosphere was modified to permit more reliable operation at low pressures (down to 10 mb). An internal combustion engine was altered to study how Mars atmosphere could be used as a diluent to control combustion temperatures and avoid excess Mars propellant production requirements that would result from either methane-rich or oxygen-rich, methane-oxygen combustion. An elastic loop traction system that could be used for lunar construction vehicles was refined to permit testing. A parabolic heat rejection radiator system was designed and built to determine whether it was capable of increasing heat rejection rates during lunar daytime operation. In addition, an alternate space station truss design, utilizing a pre-integrated concept, was studied and found to reduce estimate extravehicular activity (EVA) time and increase the structural integrity when compared to the original Warren truss concept. An orbital-debris-capturing spacecraft design which could be mated with the Orbital Maneuvering Vehicle was studied. The design identified Soviet C-1B boosters as the best targets of opportunity in Earth orbits between an altitude of 900 km and 1100 km and at an inclination of 82.9 deg. A dual robot pallet, which could be spun to match the tumbling rate of the C-1B booster, was developed as the conceptual design.

Thermodynamic analysis of in situ gasification-chemical looping combustion (iG-CLC) of Indian coal.

PubMed

Suresh, P V; Menon, Kavitha G; Prakash, K S; Prudhvi, S; Anudeep, A

2016-10-01

Chemical looping combustion (CLC) is an inherent CO 2 capture technology. It is gaining much interest in recent years mainly because of its potential in addressing climate change problems associated with CO 2 emissions from power plants. A typical chemical looping combustion unit consists of two reactors-fuel reactor, where oxidation of fuel occurs with the help of oxygen available in the form of metal oxides and, air reactor, where the reduced metal oxides are regenerated by the inflow of air. These oxides are then sent back to the fuel reactor and the cycle continues. The product gas from the fuel reactor contains a concentrated stream of CO 2 which can be readily stored in various forms or used for any other applications. This unique feature of inherent CO 2 capture makes the technology more promising to combat the global climate changes. Various types of CLC units have been discussed in literature depending on the type of fuel burnt. For solid fuel combustion three main varieties of CLC units exist namely: syngas CLC, in situ gasification-CLC (iG-CLC) and chemical looping with oxygen uncoupling (CLOU). In this paper, theoretical studies on the iG-CLC unit burning Indian coal are presented. Gibbs free energy minimization technique is employed to determine the composition of flue gas and oxygen carrier of an iG-CLC unit using Fe 2 O 3 , CuO, and mixed carrier-Fe 2 O 3 and CuO as oxygen carriers. The effect of temperature, suitability of oxygen carriers, and oxygen carrier circulation rate on the performance of a CLC unit for Indian coal are studied and presented. These results are analyzed in order to foresee the operating conditions at which economic and smooth operation of the unit is expected.

Intramolecular distribution of stable nitrogen and oxygen isotopes of nitrous oxide emitted during coal combustion.

PubMed

Ogawa, Mitsuteru; Yoshida, Naohiro

2005-11-01

The intramolecular distribution of stable isotopes in nitrous oxide that is emitted during coal combustion was analyzed using an isotopic ratio mass spectrometer equipped with a modified ion collector system (IRMS). The coal was combusted in a test furnace fitted with a single burner and the flue gases were collected at the furnace exit following removal of SO(x), NO(x), and H2O in order to avoid the formation of artifact nitrous oxide. The nitrous oxide in the flue gases proved to be enriched in 15N relative to the fuel coal. In air-staged combustion experiments, the staged air ratio was controlled over a range of 0 (unstaged combustion), 20%, and 30%. As the staged air ratio increased, the delta15N and delta18O of the nitrous oxide in the flue gases became depleted. The central nitrogen of the nitrous oxide molecule, N(alpha), was enriched in 15N relative to that occupying the end position of the molecule, N(beta), but this preference, expressed as delta15N(alpha)-delta15N(beta), decreased with the increase in the staged air ratio. Thermal decomposition and hydrogen reduction experiments carried out using a tube reactor allowed qualitative estimates of the kinetic isotope effects that occurred during the decomposition of the nitrous oxide and quantitative estimates of the extent to which the nitrous oxide had decomposed. The site preference of nitrous oxide increased with the extent of the decomposition reactions. Assuming that no site preference exists in nitrous oxide before decomposition, the behavior of nitrous oxide in the test combustion furnace was analyzed using the Rayleigh equation based on a single distillation model. As a result, the extent of decomposition of nitrous oxide was estimated as 0.24-0.26 during the decomposition reaction governed by the thermal decomposition and as 0.35-0.38 during the decomposition reaction governed by the hydrogen reduction in staged combustion. The intramolecular distribution of nitrous oxide can be a valuable

The Combustion Experiment on the Sample Analysis at Mars (SAM) Instrument Suite on the Curiosity Rover

NASA Technical Reports Server (NTRS)

Stern, J. C.; Malespin, C. A.; Eigenbrode, J.; Graham, H. V.; Archer, P. D.; Brunner, A.; Freissinet, C.; Franz, H. B.; Fuentes, J.; Glavin, D. P.;

Lance for fuel and oxygen injection into smelting or refining furnace

DOEpatents

Schlichting, Mark R.

1994-01-01

A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

Combustion characteristics of paper and sewage sludge in a pilot-scale fluidized bed.

PubMed

Yu, Yong-Ho; Chung, Jinwook

2015-01-01

This study characterizes the combustion of paper and sewage sludge in a pilot-scale fluidized bed. The highest temperature during combustion within the system was found at the surface of the fluidized bed. Paper sludge containing roughly 59.8% water was burned without auxiliary fuel, but auxiliary fuel was required to incinerate the sewage sludge, which contained about 79.3% water. The stability of operation was monitored based on the average pressure and the standard deviation of pressure fluctuations. The average pressure at the surface of the fluidized bed decreased as the sludge feed rate increased. However, the standard deviation of pressure fluctuations increased as the sludge feed rate increased. Finally, carbon monoxide (CO) emissions decreased as oxygen content increased in the flue gas, and nitrogen oxide (NOx) emissions were also tied with oxygen content.

Enhancement of oxidative vaporization of chromium (III) oxide and chromium by oxygen atoms

NASA Technical Reports Server (NTRS)

Fryburg, G. C.; Kohl, F. J.; Stearns, C. A.

1974-01-01

Rates of oxidative vaporization of Cr2O3 were found to be markedly enhanced in the presence of O atoms. Investigations were conducted over the temperature range 470 to 1520 K. For Cr2O3 the enhancement was about 10 to the 9th power at 820 K in oxygen containing 2.5 percent atoms. Rapid oxidative vaporization of bare chromium was observed below 1070 K, the rate being about one-half that of Cr2O3. Results are interpreted in terms of thermochemical analysis.

Performance of a Small Gas Generator Using Liquid Hydrogen and Liquid Oxygen

NASA Technical Reports Server (NTRS)

Acker, Loren W.; Fenn, David B.; Dietrich, Marshall W.

1961-01-01

The performance and operating problems of a small hot-gas generator burning liquid hydrogen with liquid oxygen are presented. Two methods of ignition are discussed. Injector and combustion chamber design details based on rocket design criteria are also given. A carefully fabricated showerhead injector of simple design provided a gas generator that yielded combustion efficiencies of 93 and 96 percent.

Laser-assisted ignition and combustion characteristics of consolidated aluminum nanoparticles

NASA Astrophysics Data System (ADS)

Saceleanu, Florin; Wen, John Z.; Idir, Mahmoud; Chaumeix, Nabiha

2016-11-01

Aluminum (Al) nanoparticles have drawn much attention due to their high energy density and tunable ignition properties. In comparison with their micronscale counterpart, Al nanoparticles possess large specific surface area and low apparent activation energy of combustion, which reduce ignition delay significantly. In this paper, ignition and subsequently burning of consolidated Al nanoparticle pellets are performed via a continuous wave (CW) argon laser in a closed spherical chamber filled with oxygen. Pellets are fabricated using two types of nanoparticle sizes of 40-60 and 60-80 nm, respectively. A photodiode is used to measure the ignition delay, while a digital camera captures the location of the flame front. It is found that for the 40-60-nm nanoparticle pellets, ignition delay reduces with increasing the oxygen pressure or using the higher laser power. Analysis of the flame propagation rate suggests that oxygen diffusion is an important mechanism during burning of these porous nanoparticle pellets. The combustion characteristics of the Al pellets are compared to a simplified model of the diffusion-controlled oxidation mechanism. While experimental measurements of pellets of 40-60 nm Al particles agree with the computed diffusion-limiting mechanism, a shifted behavior is observed from the pellets of 60-80 nm Al particles, largely due to the inhomogeneity of their porous structures.

Pretreatment of Parsley (Petroselinum crispum L.) Suspension Cultures with Methyl Jasmonate Enhances Elicitation of Activated Oxygen Species.

PubMed Central

Kauss, H.; Jeblick, W.; Ziegler, J.; Krabler, W.

1994-01-01

Suspension-cultured cells of parsley (Petroselinum crispum L.) were used to demonstrate an influence of jasmonic acid methyl ester (JAME) on the elicitation of activated oxygen species. Preincubation of the cell cultures for 1 d with JAME greatly enhanced the subsequent induction by an elicitor preparation from cell walls of Phytophtora megasperma f. sp. glycinea (Pmg elicitor) and by the polycation chitosan. Shorter preincubation times with JAME were less efficient, and the effect was saturated at about 5 [mu]M JAME. Treatment of the crude Pmg elicitor with trypsin abolished induction of activated oxygen species, an effect similar to that seen with elicitation of coumarin secretion. These results suggest that JAME conditioned the parsley suspension cells in a time-dependent manner to become more responsive to elicitation, reminiscent of developmental effects caused by JAME in whole plants. It is interesting that pretreatment of the parsley cultures with 2,6-dichloroisonicotinic and 5-chlorosalicylic acid only slightly enhanced the elicitation of activated oxygen species, whereas these substances greatly enhanced the elicitation of coumarin secretion. Therefore, these presumed inducers of systemic acquired resistance exhibit a specificity different from JAME. PMID:12232189

Reduced Gravity Studies of Soret Transport Effects in Liquid Fuel Combustion

NASA Technical Reports Server (NTRS)

Shaw, Benjamin D.

2004-01-01

Soret transport, which is mass transport driven by thermal gradients, can be important in practical flames as well as laboratory flames by influencing transport of low molecular weight species (e.g., monatomic and diatomic hydrogen). In addition, gas-phase Soret transport of high molecular weight fuel species that are present in practical liquid fuels (e.g., octane or methanol) can be significant in practical flames (Rosner et al., 2000; Dakhlia et al., 2002) and in high pressure droplet evaporation (Curtis and Farrell, 1992), and it has also been shown that Soret transport effects can be important in determining oxygen diffusion rates in certain classes of microgravity droplet combustion experiments (Aharon and Shaw, 1998). It is thus useful to obtain information on flames under conditions where Soret effects can be clearly observed. This research is concerned with investigating effects of Soret transport on combustion of liquid fuels, in particular liquid fuel droplets. Reduced-gravity is employed to provide an ideal (spherically-symmetrical) experimental model with which to investigate effects of Soret transport on combustion. The research will involve performing reduced-gravity experiments on combustion of liquid fuel droplets in environments where Soret effects significantly influence transport of fuel and oxygen to flame zones. Experiments will also be performed where Soret effects are not expected to be important. Droplets initially in the 0.5 to 1 mm size range will be burned. Data will be obtained on influences of Soret transport on combustion characteristics (e.g., droplet burning rates, droplet lifetimes, gas-phase extinction, and transient flame behaviors) under simplified geometrical conditions that are most amenable to theoretical modeling (i.e., spherical symmetry). The experiments will be compared with existing theoretical models as well as new models that will be developed. Normal gravity experiments will also be performed.

Cathodic current enhancement via manganese and oxygen related reactions in marine biofilms

NASA Astrophysics Data System (ADS)

Strom, Matthew James

Corrosion is a threat that has economic, and environmental impacts worldwide. Many types of corrosive attack are the subject of ongoing research. One of these areas of research is microbiologically influenced corrosion, which is the enhancement and/or initiation of corrosion events caused by microorganisms. It is well known that colonies of microorganisms can enhance cathodic currents through biofilm formation. The aim of the present work was to elucidate the role of manganese in enhancing cathodic currents in the presence of biofilms. Repeated polarizations conducted in Delaware Bay waters, on biofilm coated Cr identified potentially sustainable reduction reactions. The reduction of MnO2 and the enhancement of the oxygen reduction reaction (ORR) were proven to be factors that influence cathodic current enhancement. The removal of ambient oxygen during polarizations resulted in a shutdown of cathodic current enhancement. These field data led to an exploration of the synergistic relationship between MnO2 and the ORR. Laboratory studies of the catalysis of peroxide disproportionation by MnO2 were monitored using a hanging mercury drop electrode. Experiments were run at an ambient sweater pH of 8 and pH 9, which simulated the near-surface conditions typical of cathodes immersed in seawater. Rapid reoxidation at the more basic pH was shown to allow manganese to behave as a persistent catalyst under the typical electrochemical surface conditions of a cathode. As a result a mechanism for ORR enhancement by manganese was proposed as a unique mechanism for cathodic current enhancement in biofilms. A separate field study of Delaware biofilms on stainless steel coupled to a sacrificial Al anode was carried out to identify the ORR enhancement mechanism and sustainable redox reactions at the cathode. Chemical treatments of glutaraldehyde and formaldoxime were applied to cathodes with biofilms to distinguish between enzymatic and MnO2 related ORR enhancement. The results ruled

Ignition and Combustion of Pulverized Coal and Biomass under Different Oxy-fuel O2/N2 and O2/CO2 Environments

NASA Astrophysics Data System (ADS)

Khatami Firoozabadi, Seyed Reza

-anthracite and lignites mostly experienced heterogeneous ignition in either O2/N2 or O2/CO2 atmospheres in both flow conditions. Replacing the N2 by CO 2 slightly increased the ignition temperature (30--40K). Ignition temperatures increased with the enhancement of coal rank in either air or oxy-fuel combustion conditions. However, increasing oxygen mole fraction decreased the ignition temperature for all coals. The ignition delay of coal particles was prolonged in the slow-heating O2/CO2 atmospheres, relative to the faster-heating O2/N2 atmospheres, particularly at high-diluent mole fractions. At higher O2 mole fractions, ignition delays decreased in both environments. Higher rank fuels such as anthracite and semi-anthracite experienced higher ignition delays while lower rank fuels such as lignite and biomasses experienced lower igniton delay times. In combustion, fuel particles were observed to burn in different modes, such as two-mode, or in one-mode combustion, depending on their rank and the furnace conditions. Strong tendencies were observed for all fuels to burn in one-mode when N2 was replaced by CO2, and when O 2 mole fraction increased in both environments. Moreover, increasing the coal rank, from lignite to bituminous, enhanced the tendency of coal particles to exhibit a two-mode combustion behavior. Particle luminosity, fragmentation and deduced temperatures were higher in O2/N2 than in O2/CO2 atmospheres, and corresponding burnout times were shorter, at the same O2 mole fractions. Particle luminosity and temperatures increased with increasing O2 mole fractions in both N2 and in CO2 background gases, and corresponding burnout times decreased with increasing O2 mole fractions. Bituminous coal particles swelled, whereas sub-bituminous coal particles exhibited limited fragmentation prior to and during the early stages of combustion. Lignite coal particles fragmented extensively and burned in one-mode regardless of the O2 mole fraction and the background gas. The timing

Low-Flammability PTFE for High-Oxygen Environments

NASA Technical Reports Server (NTRS)

Walle, E.; Fallon, B.; Sheppard, A.

1986-01-01

Modified forming process removes volatile combustible materials. Flammability of cable-wrapping tape reduced by altering tape-manufacturing process. In new manufacturing process, tape formed by proprietary process of screw extrusion, followed by washing in solvent and drying. Tape then wrapped as before. Spectrogram taken after extrusion, washing, and drying shows lower hydrocarbon content. PTFE formed by new process suited to oxygen-rich environments. Safe in liquid oxygen of Space Shuttle tank and in medical uses; thin-wall shrinkable tubing in hospital test equipment, surgical instruments, and implants.

External combustion engine having a combustion expansion chamber

NASA Astrophysics Data System (ADS)

Duva, Anthony W.

1993-03-01

This patent application discloses an external combustion engine having a combustion expansion chamber. The engine includes a combustion chamber for generating a high-pressure, energized gas from a monopropellant fuel, and a cylinder for receiving the energized gas through a rotary valve to perform work on a cylinder disposed therein. A baffle plate is positioned between the combustion area and expansion area for reducing the pressure of the gas. The combustion area and expansion area are separated by a baffle plate having a flow area which is sufficiently large to eliminate the transmission of pressure pulsations from the combustion area to the expansion area while being small enough to provide for substantially complete combustion in the combustion area. The engine is particularly well suited for use in a torpedo.

Quantum Chemical Study of Supercritical Carbon Dioxide Effects on Combustion Kinetics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Masunov, Artëm E.; Wait, Elizabeth E.; Atlanov, Arseniy A.

In oxy-fuel combustion, the pure oxygen (O 2), diluted with CO 2 is used as oxidant instead air. Hence, the combustion products (CO 2 and H 2O) are free from pollution by nitrogen oxides. Moreover, high pressures results in the near-liquid density of CO 2 at supercritical state (sCO 2). Unfortunately, the effects of sCO 2 on the combustion kinetics are far from being understood. In order to assist in this understanding, in this work we are using quantum chemistry methods. Here we investigate potential energy surfaces of important combustion reactions in the presence of carbon dioxide melocule. All transitionmore » states, reactant and product complexes are reported for three reactions: H 2CO+HO 2→HCO+H 2O 2 (R1), 2HO 2→H 2O 2+O 2 (R2), and CO+OH→CO 2+H (R3). In the reaction R3, covalent binding of CO 2 to OH radical and then CO molecule opens a new pathway, including hydrogen transfer from oxygen to carbon atoms followed by CH bond dissociation. Compared to bimolecular OH+CO mechanism, this pathway reduces the activation barrier by 5 kcal/mol, and is expected to accelerate the reaction. This is the first report of autocatalytic effect in combustion. In case of hydroperoxyl self-reaction 2HO 2→H 2O 2+O 2 the intermediates, containing covalent bonds to CO 2 were found not to be competitive. However, the spectator CO 2 molecule is able to stabilize the cyclic transition state and lower the barrier by 3 kcal/mol. Formation of covalent intermediates was also discovered in H 2CO+HO 2→HCO+H 2O 2 reaction, but these specie lead to substantially higher activation barriers which makes them unlikely to play role in hydrogen transfer kinetics. The van der Waals complexation with carbon dioxide also stabilized transition state and reduces reaction barrier. Lastly, these results indicate that CO 2 environment is likely to have catalytic effect on combustion reactions, which needs to be included in kinetic combustion mechanisms in supercritical CO 2.« less

Quantum Chemical Study of Supercritical Carbon Dioxide Effects on Combustion Kinetics

DOE PAGES

Masunov, Artëm E.; Wait, Elizabeth E.; Atlanov, Arseniy A.; ...

2017-05-03

In oxy-fuel combustion, the pure oxygen (O 2), diluted with CO 2 is used as oxidant instead air. Hence, the combustion products (CO 2 and H 2O) are free from pollution by nitrogen oxides. Moreover, high pressures results in the near-liquid density of CO 2 at supercritical state (sCO 2). Unfortunately, the effects of sCO 2 on the combustion kinetics are far from being understood. In order to assist in this understanding, in this work we are using quantum chemistry methods. Here we investigate potential energy surfaces of important combustion reactions in the presence of carbon dioxide melocule. All transitionmore » states, reactant and product complexes are reported for three reactions: H 2CO+HO 2→HCO+H 2O 2 (R1), 2HO 2→H 2O 2+O 2 (R2), and CO+OH→CO 2+H (R3). In the reaction R3, covalent binding of CO 2 to OH radical and then CO molecule opens a new pathway, including hydrogen transfer from oxygen to carbon atoms followed by CH bond dissociation. Compared to bimolecular OH+CO mechanism, this pathway reduces the activation barrier by 5 kcal/mol, and is expected to accelerate the reaction. This is the first report of autocatalytic effect in combustion. In case of hydroperoxyl self-reaction 2HO 2→H 2O 2+O 2 the intermediates, containing covalent bonds to CO 2 were found not to be competitive. However, the spectator CO 2 molecule is able to stabilize the cyclic transition state and lower the barrier by 3 kcal/mol. Formation of covalent intermediates was also discovered in H 2CO+HO 2→HCO+H 2O 2 reaction, but these specie lead to substantially higher activation barriers which makes them unlikely to play role in hydrogen transfer kinetics. The van der Waals complexation with carbon dioxide also stabilized transition state and reduces reaction barrier. Lastly, these results indicate that CO 2 environment is likely to have catalytic effect on combustion reactions, which needs to be included in kinetic combustion mechanisms in supercritical CO 2.« less

Device for quickly sensing the amount of O2 in a combustion product gas

NASA Technical Reports Server (NTRS)

Singh, Jag J. (Inventor); Davis, William T. (Inventor); Puster, Richard L. (Inventor)

1990-01-01

A sensing device comprising an O2 sensor, a pump, a compressor, and a heater is provided to quickly sense the amount of O2 in a combustion product gas. A sample of the combustion product gas is compressed to a pressure slightly above one atmosphere by the compressor. Next, the heater heats the sample between 800 C and 900 C. Next, the pump causes the sample to be flushed against the electrode located in O2 sensor 6000 to 10,000 times per second. Reference air at approximately one atmosphere is provided to the electrode of O2 sensor. Accordingly, the O2 sensor produces a voltage which is proportional to the amount of oxygen in the combustion product gas. This voltage may be used to control the amount of O2 entering into the combustion chamber which produces the combustion product gas.

Mars in situ propellants: Carbon monoxide and oxygen ignition experiments

NASA Technical Reports Server (NTRS)

Linne, Diane L.; Roncace, James; Groth, Mary F.

1990-01-01

Carbon monoxide and oxygen were tested in a standard spark-torch igniter to identify the ignition characteristics of this potential Mars in situ propellant combination. The ignition profiles were determined as functions of mixture ratio, amount of hydrogen added to the carbon monoxide, and oxygen inlet temperature. The experiments indicated that the carbon monoxide and oxygen combination must have small amounts of hydrogen present to initiate reaction. Once the reaction was started, the combustion continued without the presence of hydrogen. A mixture ratio range was identified where ignition occurred, and this range varied with the oxygen inlet temperature.

How oxygen reacts with oxygen-tolerant respiratory [NiFe]-hydrogenases

PubMed Central

Wulff, Philip; Day, Christopher C.; Sargent, Frank; Armstrong, Fraser A.

2014-01-01

An oxygen-tolerant respiratory [NiFe]-hydrogenase is proven to be a four-electron hydrogen/oxygen oxidoreductase, catalyzing the reaction 2 H2 + O2 = 2 H2O, equivalent to hydrogen combustion, over a sustained period without inactivating. At least 86% of the H2O produced by Escherichia coli hydrogenase-1 exposed to a mixture of 90% H2 and 10% O2 is accounted for by a direct four-electron pathway, whereas up to 14% arises from slower side reactions proceeding via superoxide and hydrogen peroxide. The direct pathway is assigned to O2 reduction at the [NiFe] active site, whereas the side reactions are an unavoidable consequence of the presence of low-potential relay centers that release electrons derived from H2 oxidation. The oxidase activity is too slow to be useful in removing O2 from the bacterial periplasm; instead, the four-electron reduction of molecular oxygen to harmless water ensures that the active site survives to catalyze sustained hydrogen oxidation. PMID:24715724

Low Temperature ABC-Type Ru Atomic Layer Deposition through Consecutive Dissociative Chemisorption, Combustion, and Reduction Steps

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Junling; Elam, Jeffrey W.

Thermal atomic layer deposition (ALD) of noble metals is frequently performed using molecular oxygen as the nonmetal precursor to effect a combustion-type chemistry at relatively high temperatures of 300 °C. Bis(ethylcyclopentadienyl)ruthenium (Ru(EtCp)2) is one of the common used metal precursors for Ru ALD. Using Ru(EtCp)2 and oxygen as reactants, Ru ALD was acheived at near 300 °C. Here, we demonstrate that Ru ALD can proceed at as low as 150 °C by using successive exposures to oxygen and hydrogen as the co-reactants. In situ quartz crystal microbalance (QCM) and quadrupole mass spectroscopy (QMS) measurements both suggest that this ABC-type ALDmore » occurs through dissociative chemisorption, combustion, and reduction for the Ru(EtCp)2, oxygen and hydrogen steps, respectively, in a similar manner to processes using ozone and hydrogen as co-reactants reported previously. Moreover, we believe this molecular O2 and H2 based ABC-type ALD could be exploited for the ALD of other noble metals to decrease the deposition temperature and reduce oxygen impurities.« less

Modeling complex chemical effects in turbulent nonpremixed combustion

NASA Technical Reports Server (NTRS)

Smith, Nigel S. A.

1995-01-01

Virtually all of the energy derived from the consumption of combustibles occurs in systems which utilize turbulent fluid motion. Since combustion is largely related to the mixing of fluids and mixing processes are orders of magnitude more rapid when enhanced by turbulent motion, efficiency criteria dictate that chemically powered devices necessarily involve fluid turbulence. Where combustion occurs concurrently with mixing at an interface between two reactive fluid bodies, this mode of combustion is called nonpremixed combustion. This is distinct from premixed combustion where flame-fronts propagate into a homogeneous mixture of reactants. These two modes are limiting cases in the range of temporal lag between mixing of reactants and the onset of reaction. Nonpremixed combustion occurs where this lag tends to zero, while premixed combustion occurs where this lag tends to infinity. Many combustion processes are hybrids of these two extremes with finite non-zero lag times. Turbulent nonpremixed combustion is important from a practical standpoint because it occurs in gas fired boilers, furnaces, waste incinerators, diesel engines, gas turbine combustors, and afterburners etc. To a large extent, past development of these practical systems involved an empirical methodology. Presently, efficiency standards and emission regulations are being further tightened (Correa 1993), and empiricism has had to give way to more fundamental research in order to understand and effectively model practical combustion processes (Pope 1991). A key element in effective modeling of turbulent combustion is making use of a sufficiently detailed chemical kinetic mechanism. The prediction of pollutant emission such as oxides of nitrogen (NO(x)) and sulphur (SO(x)) unburned hydrocarbons, and particulates demands the use of detailed chemical mechanisms. It is essential that practical models for turbulent nonpremixed combustion are capable of handling large numbers of 'stiff' chemical species

Enhanced Photocatalytic Activity of Vacuum-activated TiO2 Induced by Oxygen Vacancies.

PubMed

Dong, Guoyan; Wang, Xin; Chen, Zhiwu; Lu, Zhenya

2018-05-01

TiO 2 (Degussa P25) photocatalysts harboring abundant oxygen vacancies (Vacuum P25) were manufactured using a simple and economic Vacuum deoxidation process. Control experiments showed that temperature and time of vacuum deoxidation had a significant effect on Vacuum P25 photocatalytic activity. After 240 min of visible light illumination, the optimal Vacuum P25 photocatalysts (vacuum deoxidation treated at 330 °C for 3 h) reach as high as 94% and 88% of photodegradation efficiency for rhodamine B (RhB) and tetracycline, respectively, which are around 4.5 and 4.9 times as that of pristine P25. The XPS, PL and EPR analyses indicated that the oxygen vacancies were produced in the Vacuum P25 during the vacuum deoxidation process. The oxygen vacancy states can produce vacancy energy level located below the conduction band minimum, which resulting in the bandgap narrowing, thus extending the photoresponse wavelength range of Vacuum P25. The positron annihilation analysis indicated that the concentrations ratio of bulk and surface oxygen vacancies could be adjusted by changing the vacuum deoxidation temperature and time. Decreasing the ratio of bulk and surface oxygen vacancies was shown to improve photogenerated electron-hole pair separation efficiency, which leads to an obvious enhancement of the visible photocatalytic activities of Vacuum P25. © 2017 The American Society of Photobiology.

The Combustion Experiment on the Sample Analysis at Mars (SAM) Instrument Suite on the Curiosity Rover

NASA Technical Reports Server (NTRS)

Stern, J. C.; Malespin, C. A.; Eigenbrode, J. L.; Graham, H. V.; Archer, P. D., Jr.; Brunner, A. E.; Freissinet, C.; Franz, H. B.; Fuentes, J.; Glavin, D. P.;

MSW oxy-enriched incineration technology applied in China: combustion temperature, flue gas loss and economic considerations.

PubMed

Fu, Zhe; Zhang, Shihong; Li, Xiangpeng; Shao, Jingai; Wang, Ke; Chen, Hanping

2015-04-01

To investigate the application prospect of MSW oxy-enriched incineration technology in China, the technical and economical analyses of a municipal solid waste (MSW) grate furnace with oxy-fuel incineration technology in comparison to co-incineration with coal are performed. The rated capacity of the grate furnace is 350 tonnes MSW per day. When raw MSW is burned, the amount of pure oxygen injected should be about 14.5 wt.% under 25% O2 oxy-fuel combustion conditions with the mode of oxygen supply determined by the actual situation. According to the isothermal combustion temperature (Ta), the combustion effect of 25% O2 oxy-enriched incineration (α = 1.43) is identical with that of MSW co-incineration with 20% mass ratio of coal (α = 1.91). However, the former is better than the latter in terms of plant cost, flue gas loss, and environmental impact. Despite the lower costs of MSW co-incineration with mass ratio of 5% and 10% coal (α = 1.91), 25% O2 oxy-enriched incineration (α = 1.43) is far more advantageous in combustion and pollutant control. Conventional combustion flue gas loss (q2) for co-incineration with 0% coal, 20% coal, 10% coal, 5% coal are around 17%, 13%, 14% and 15%, respectively, while that under the condition of 25% O2 oxy-enriched combustion is approximately 12% (α = 1.43). Clearly, q2 of oxy-enriched incineration is less than other methods under the same combustion conditions. High moisture content presents challenges for MSW incineration, therefore it is necessary to dry MSW prior to incineration, and making oxy-enriched incineration technology achieves higher combustion temperature and lower flue gas loss. In conclusion, based on technical and economical analysis, MSW oxy-enriched incineration retains obvious advantages and demonstrates great future prospects for MSW incineration in China. Copyright © 2015 Elsevier Ltd. All rights reserved.

Emergency response mobile robot for operations in combustible atmospheres

NASA Technical Reports Server (NTRS)

Stone, Henry W. (Inventor); Ohm, Timothy R. (Inventor)

1995-01-01

A mobile, self-powered, self-contained, and remote-controlled robot is presented. The robot is capable of safely operating in a combustible atmosphere and providing information about the atmosphere to the operator. The robot includes non-sparking and non-arcing electro-mechanical and electronic components designed to prevent the robot from igniting the combustible atmosphere. The robot also includes positively pressurized enclosures that house the electromechanical and electronic components of the robot and prevent intrusion of the combustible atmosphere into the enclosures. The enclosures are interconnected such that a pressurized gas injected into any one of the enclosures is routed to all the other enclosures through the interconnections. It is preferred that one or more sealed internal channels through structures intervening between the enclosures be employed. Pressure transducers for detecting if the pressure within the enclosures falls below a predetermined level are included. The robot also has a sensing device for determining the types of combustible substances in the surrounding atmosphere, as well as the concentrations of each type of substance relative to a pre-determined lower explosive limit (LEL). In addition, the sensing device can determine the percent level of oxygen present in the surrounding atmosphere.

Emergency response mobile robot for operations in combustible atmospheres

NASA Astrophysics Data System (ADS)

Stone, Henry W.; Ohm, Timothy R.

1995-08-01

A mobile, self-powered, self-contained, and remote-controlled robot is presented. The robot is capable of safely operating in a combustible atmosphere and providing information about the atmosphere to the operator. The robot includes non-sparking and non-arcing electro-mechanical and electronic components designed to prevent the robot from igniting the combustible atmosphere. The robot also includes positively pressurized enclosures that house the electromechanical and electronic components of the robot and prevent intrusion of the combustible atmosphere into the enclosures. The enclosures are interconnected such that a pressurized gas injected into any one of the enclosures is routed to all the other enclosures through the interconnections. It is preferred that one or more sealed internal channels through structures intervening between the enclosures be employed. Pressure transducers for detecting if the pressure within the enclosures falls below a predetermined level are included. The robot also has a sensing device for determining the types of combustible substances in the surrounding atmosphere, as well as the concentrations of each type of substance relative to a pre-determined lower explosive limit (LEL). In addition, the sensing device can determine the percent level of oxygen present in the surrounding atmosphere.

Enhancement of Electrical Conductivity of LiFePO4 by Controlled Solution Combustion Synthesis

NASA Astrophysics Data System (ADS)

Rajoba, S. J.; Jadhav, L. D.; Patil, P. S.; Tyagi, D. K.; Varma, S.; Wani, B. N.

2017-03-01

LiFePO4 has been synthesized by a solution combustion method at different oxidant-to-fuel ratios. At stoichiometric oxidant-to-fuel ratio (1:2), Fe2O3 formed in addition to LiFePO4 during combustion. Hence, reducing atmosphere was generated by increasing the ratio from stoichiometric to 1:4 and 1:8, named as 1-LFP, 2-LFP, and 4-LFP, respectively. Furthermore, as-prepared powders were calcined in inert atmosphere to avoid oxidation of LiFePO4 to Fe2O3 and Li3PO4, as confirmed by x-ray diffraction (XRD) and thermogravimetric and differential thermal analyses. The calcined powders were characterized by XRD analysis, Raman spectroscopy, scanning electron microscopy, and energy-dispersive x-ray spectroscopy. X-ray photoelectron spectroscopy ascertained oxidation state of +2 and +5 for Fe and P, respectively. With increasing oxidant-to-fuel ratio, the binding energies of 2 p 3/2 and 2 p 1/2 levels of Fe shifted downwards and showed increased splitting. According to Raman spectroscopy results, the residual carbon is amorphous with sp 2 C-C bond. The conductivity of 1-LFP, 2-LFP, and 4-LFP measured at 313 K was 0.15 × 10-6 S/cm, 8.46 × 10-6 S/cm, and 1.21 × 10-3 S/cm, respectively. The enhanced conductivity of 4-LFP is due to presence of residual carbon and Fe2P.

Orbit transfer rocket engine technology program: Oxygen materials compatibility testing

NASA Technical Reports Server (NTRS)

Schoenman, Leonard

1989-01-01

Particle impact and frictional heating tests of metals in high pressure oxygen, are conducted in support of the design of an advanced rocket engine oxygen turbopump. Materials having a wide range of thermodynamic properties including heat of combustion and thermal diffusivity were compared in their resistance to ignition and sustained burning. Copper, nickel and their alloys were found superior to iron based and stainless steel alloys. Some materials became more difficult to ignite as oxygen pressure was increased from 7 to 21 MPa (1000 to 3000 psia).

Renewable Energy Laboratory Development for Biofuels Advanced Combustion Studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Soloiu, Valentin A.

2012-03-31

The research advanced fundamental science and applied engineering for increasing the efficiency of internal combustion engines and meeting emissions regulations with biofuels. The project developed a laboratory with new experiments and allowed investigation of new fuels and their combustion and emissions. This project supports a sustainable domestic biofuels and automotive industry creating economic opportunities across the nation, reducing the dependence on foreign oil, and enhancing U.S. energy security. The one year period of research developed fundamental knowledge and applied technology in advanced combustion, emissions and biofuels formulation to increase vehicle's efficiency. Biofuels combustion was investigated in a Compression Ignition Directmore » Injection (DI) to develop idling strategies with biofuels and an Indirect Diesel Injection (IDI) intended for auxiliary power unit.« less